Single-particle detection of products from atomic and molecular reactions in a cryogenic ion storage ring

NASA Astrophysics Data System (ADS)

Krantz, C.; Novotný, O.; Becker, A.; George, S.; Grieser, M.; Hahn, R. von; Meyer, C.; Schippers, S.; Spruck, K.; Vogel, S.; Wolf, A.

2017-04-01

We have used a single-particle detector system, based on secondary electron emission, for counting low-energetic (∼keV/u) massive products originating from atomic and molecular ion reactions in the electrostatic Cryogenic Storage Ring (CSR). The detector is movable within the cryogenic vacuum chamber of CSR, and was used to measure production rates of a variety of charged and neutral daughter particles. In operation at a temperature of ∼ 6 K , the detector is characterised by a high dynamic range, combining a low dark event rate with good high-rate particle counting capability. On-line measurement of the pulse height distributions proved to be an important monitor of the detector response at low temperature. Statistical pulse-height analysis allows to infer the particle detection efficiency of the detector, which has been found to be close to unity also in cryogenic operation at 6 K.

The Muon g-2 Experiment overview and status as of June 2016

DOE PAGES

Holzbauer, J. L.

2016-12-09

The Muon g-2 Experiment at Fermilab will measure the anomalous magnetic moment of the muon to a precision of 140 parts per billion, which is a factor of four improvement over the previous E821 measurement at Brookhaven. The experiment will also extend the search for the electric dipole moment (EDM) of the muon by approximately two orders of magnitude, with a sensitivity down to 10 -21 e.cm. Both of these measurements are made by combining a precise measurement of the 1.45T storage ring magnetic field with an analysis of the modulation of the decay rate of higher-energy positrons (from anti-muons),more » recorded by 24 calorimeters and 3 straw tracking detectors. Furthermore, the recent progress in the alignment of the electrostatic quadrapole plates and the trolley rails inside the vacuum chambers, and in establishing the uniform storage ring magnetic field will be described.« less

The Muon g-2 Experiment Overview and Status as of June 2016

NASA Astrophysics Data System (ADS)

Holzbauer, J.

2016-11-01

The Muon g-2 Experiment at Fermilab will measure the anomalous magnetic moment of the muon to a precision of 140 parts per billion, which is a factor of four improvement over the previous E821 measurement at Brookhaven. The experiment will also extend the search for the electric dipole moment (EDM) of the muon by approximately two orders of magnitude, with a sensitivity down to 10-21 e.cm. Both of these measurements are made by combining a precise measurement of the 1.45T storage ring magnetic field with an analysis of the modulation of the decay rate of higher-energy positrons (from anti-muons), recorded by 24 calorimeters and 3 straw tracking detectors. The recent progress in the alignment of the electrostatic quadrapole plates and the trolley rails inside the vacuum chambers, and in establishing the uniform storage ring magnetic field will be described.

Electron molecular ion recombination: product excitation and fragmentation.

PubMed

Adams, Nigel G; Poterya, Viktoriya; Babcock, Lucia M

2006-01-01

Electron-ion dissociative recombination is an important ionization loss process in any ionized gas containing molecular ions. This includes the interstellar medium, circumstellar shells, cometary comae, planetary ionospheres, fusion plasma boundaries, combustion flames, laser plasmas and chemical deposition and etching plasmas. In addition to controlling the ionization density, the process generates many radical species, which can contribute to a parallel neutral chemistry. Techniques used to obtain rate data and product information (flowing afterglows and storage rings) are discussed and recent data are reviewed including diatomic to polyatomic ions and cluster ions. The data are divided into rate coefficients and cross sections, including their temperature/energy dependencies, and quantitative identification of neutral reaction products. The latter involve both ground and electronically excited states and including vibrational excitation. The data from the different techniques are compared and trends in the data are examined. The reactions are considered in terms of the basic mechanisms (direct and indirect processes including tunneling) and recent theoretical developments are discussed. Finally, new techniques are mentioned (for product identification; electrostatic storage rings, including single and double rings; Coulomb explosion) and new ways forward are suggested.

Free Electron Lasers

DTIC Science & Technology

1991-01-09

Linacs Duke a NIST/NRL UCSB Accelerator Storage ring race - track Electrostatic microtron Van de Graaf Status 1993 19 9 2 h 1990 Electron Energy 0.5-1... phase velocity slightly less than the electrons. This wave is called the "ponderomotive potential wave", which is generated by the beating of the...c is the speed of light. The beat wave has the same frequency as the radiation, but its wavenumber is k + k,. The phase velocity of the beat wave Vph

Software package for modeling spin–orbit motion in storage rings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zyuzin, D. V., E-mail: d.zyuzin@fz-juelich.de

2015-12-15

A software package providing a graphical user interface for computer experiments on the motion of charged particle beams in accelerators, as well as analysis of obtained data, is presented. The software package was tested in the framework of the international project on electric dipole moment measurement JEDI (Jülich Electric Dipole moment Investigations). The specific features of particle spin motion imply the requirement to use a cyclic accelerator (storage ring) consisting of electrostatic elements, which makes it possible to preserve horizontal polarization for a long time. Computer experiments study the dynamics of 10{sup 6}–10{sup 9} particles in a beam during 10{supmore » 9} turns in an accelerator (about 10{sup 12}–10{sup 15} integration steps for the equations of motion). For designing an optimal accelerator structure, a large number of computer experiments on polarized beam dynamics are required. The numerical core of the package is COSY Infinity, a program for modeling spin–orbit dynamics.« less

The cryogenic storage ring CSR

NASA Astrophysics Data System (ADS)

von Hahn, R.; Becker, A.; Berg, F.; Blaum, K.; Breitenfeldt, C.; Fadil, H.; Fellenberger, F.; Froese, M.; George, S.; Göck, J.; Grieser, M.; Grussie, F.; Guerin, E. A.; Heber, O.; Herwig, P.; Karthein, J.; Krantz, C.; Kreckel, H.; Lange, M.; Laux, F.; Lohmann, S.; Menk, S.; Meyer, C.; Mishra, P. M.; Novotný, O.; O'Connor, A. P.; Orlov, D. A.; Rappaport, M. L.; Repnow, R.; Saurabh, S.; Schippers, S.; Schröter, C. D.; Schwalm, D.; Schweikhard, L.; Sieber, T.; Shornikov, A.; Spruck, K.; Sunil Kumar, S.; Ullrich, J.; Urbain, X.; Vogel, S.; Wilhelm, P.; Wolf, A.; Zajfman, D.

2016-06-01

An electrostatic cryogenic storage ring, CSR, for beams of anions and cations with up to 300 keV kinetic energy per unit charge has been designed, constructed, and put into operation. With a circumference of 35 m, the ion-beam vacuum chambers and all beam optics are in a cryostat and cooled by a closed-cycle liquid helium system. At temperatures as low as (5.5 ± 1) K inside the ring, storage time constants of several minutes up to almost an hour were observed for atomic and molecular, anion and cation beams at an energy of 60 keV. The ion-beam intensity, energy-dependent closed-orbit shifts (dispersion), and the focusing properties of the machine were studied by a system of capacitive pickups. The Schottky-noise spectrum of the stored ions revealed a broadening of the momentum distribution on a time scale of 1000 s. Photodetachment of stored anions was used in the beam lifetime measurements. The detachment rate by anion collisions with residual-gas molecules was found to be extremely low. A residual-gas density below 140 cm-3 is derived, equivalent to a room-temperature pressure below 10-14 mbar. Fast atomic, molecular, and cluster ion beams stored for long periods of time in a cryogenic environment will allow experiments on collision- and radiation-induced fragmentation processes of ions in known internal quantum states with merged and crossed photon and particle beams.

The cryogenic storage ring CSR.

PubMed

von Hahn, R; Becker, A; Berg, F; Blaum, K; Breitenfeldt, C; Fadil, H; Fellenberger, F; Froese, M; George, S; Göck, J; Grieser, M; Grussie, F; Guerin, E A; Heber, O; Herwig, P; Karthein, J; Krantz, C; Kreckel, H; Lange, M; Laux, F; Lohmann, S; Menk, S; Meyer, C; Mishra, P M; Novotný, O; O'Connor, A P; Orlov, D A; Rappaport, M L; Repnow, R; Saurabh, S; Schippers, S; Schröter, C D; Schwalm, D; Schweikhard, L; Sieber, T; Shornikov, A; Spruck, K; Sunil Kumar, S; Ullrich, J; Urbain, X; Vogel, S; Wilhelm, P; Wolf, A; Zajfman, D

2016-06-01

An electrostatic cryogenic storage ring, CSR, for beams of anions and cations with up to 300 keV kinetic energy per unit charge has been designed, constructed, and put into operation. With a circumference of 35 m, the ion-beam vacuum chambers and all beam optics are in a cryostat and cooled by a closed-cycle liquid helium system. At temperatures as low as (5.5 ± 1) K inside the ring, storage time constants of several minutes up to almost an hour were observed for atomic and molecular, anion and cation beams at an energy of 60 keV. The ion-beam intensity, energy-dependent closed-orbit shifts (dispersion), and the focusing properties of the machine were studied by a system of capacitive pickups. The Schottky-noise spectrum of the stored ions revealed a broadening of the momentum distribution on a time scale of 1000 s. Photodetachment of stored anions was used in the beam lifetime measurements. The detachment rate by anion collisions with residual-gas molecules was found to be extremely low. A residual-gas density below 140 cm(-3) is derived, equivalent to a room-temperature pressure below 10(-14) mbar. Fast atomic, molecular, and cluster ion beams stored for long periods of time in a cryogenic environment will allow experiments on collision- and radiation-induced fragmentation processes of ions in known internal quantum states with merged and crossed photon and particle beams.

1985 Particle Accelerator Conference: Accelerator Engineering and Technology, 11th, Vancouver, Canada, May 13-16, 1985, Proceedings

NASA Astrophysics Data System (ADS)

Strathdee, A.

1985-10-01

The topics discussed are related to high-energy accelerators and colliders, particle sources and electrostatic accelerators, controls, instrumentation and feedback, beam dynamics, low- and intermediate-energy circular accelerators and rings, RF and other acceleration systems, beam injection, extraction and transport, operations and safety, linear accelerators, applications of accelerators, radiation sources, superconducting supercolliders, new acceleration techniques, superconducting components, cryogenics, and vacuum. Accelerator and storage ring control systems are considered along with linear and nonlinear orbit theory, transverse and longitudinal instabilities and cures, beam cooling, injection and extraction orbit theory, high current dynamics, general beam dynamics, and medical and radioisotope applications. Attention is given to superconducting RF structures, magnet technology, superconducting magnets, and physics opportunities with relativistic heavy ion accelerators.

Effect of nonlinear electrostatic forces on the dynamic behaviour of a capacitive ring-based Coriolis Vibrating Gyroscope under severe shock

NASA Astrophysics Data System (ADS)

Chouvion, B.; McWilliam, S.; Popov, A. A.

2018-06-01

This paper investigates the dynamic behaviour of capacitive ring-based Coriolis Vibrating Gyroscopes (CVGs) under severe shock conditions. A general analytical model is developed for a multi-supported ring resonator by describing the in-plane ring response as a finite sum of modes of a perfect ring and the electrostatic force as a Taylor series expansion. It is shown that the supports can induce mode coupling and that mode coupling occurs when the shock is severe and the electrostatic forces are nonlinear. The influence of electrostatic nonlinearity is investigated by numerically simulating the governing equations of motion. For the severe shock cases investigated, when the electrode gap reduces by ∼ 60 % , it is found that three ring modes of vibration (1 θ, 2 θ and 3 θ) and a 9th order force expansion are needed to obtain converged results for the global shock behaviour. Numerical results when the 2 θ mode is driven at resonance indicate that electrostatic nonlinearity introduces mode coupling which has potential to reduce sensor performance under operating conditions. Under some circumstances it is also found that severe shocks can cause the vibrating response to jump to another stable state with much lower vibration amplitude. This behaviour is mainly a function of shock amplitude and rigid-body motion damping.

Polarized deuterium internal target at AmPS (NIKHEF)

NASA Astrophysics Data System (ADS)

Ferro-Luzzi, M.; Zhou, Z.-L.; van den Brand, J. F. J.; Bulten, H. J.; Alarcon, R.; van Bakel, N.; Botto, T.; Bouwhuis, M.; van Buuren, L.; Comfort, J.; Doets, M.; Dolfini, S.; Ent, R.; Geurts, D.; Heimberg, P.; Higinbotham, D. W.; de Jager, C. W.; Lang, J.; de Lange, D. J.; Norum, B.; Passchier, I.; Poolman, H. R.; Six, E.; Steijger, J.; Szczerba, D.; Unal, O.; de Vries, H.

1998-01-01

We describe the polarized deuterium target internal to the NIKHEF medium-energy electron storage ring. Tensor polarized deuterium was produced in an atomic beam source and injected into a storage cell target. A Breit-Rabi polarimeter was used to monitor the injected atomic beam intensity and polarization. An electrostatic ion-extraction system and a Wien filter were utilized to measure on-line the atomic fraction of the target gas in the storage cell. This device was supplemented with a tensor polarization analyzer using the neutron anisotropy of the 3H(d,n)α reaction at 60 keV. This method allows determining the density-averaged nuclear polarization of the target gas, independent of spatial and temporal variations. We address issues important for polarized hydrogen/deuterium internal targets, such as the effects of spin-exchange collisions and resonant transitions induced by the RF fields of the charged particle beam.

Polarized deuterium internal target at AmPS (NIKHEF)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Norum, Blaine; De Jager, Cornelis; Geurts, D.

1997-08-01

We describe the polarized deuterium target internal to the NIKHEF medium-energy electron storage ring. Tensor polarized deuterium was produced in an atomic beam source and injected into a storage cell target. A Breit-Rabi polarimeter was used to monitor the injected atomic beam intensity and polarization. An electrostatic ion-extraction system and a Wien filter were utilized to measure on-line the atomic fraction of the target gas in the storage cell. This device was supplemented with a tensor polarization analyzer using the neutron anisotropy of the 3H(d,n)sigma reaction at 60 keV. This method allows determining the density-averaged nuclear polarization of the targetmore » gas, independent of spatial and temporal variations. We address issues important for polarized hydrogen/deuterium internal targets, such as the effects of spin-exchange collisions and resonant transitions induced by the RF fields of the charged particle beam.« less

Polarized deuterium internal target at AmPS (NIKHEF)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ferro-Luzzi, M.; NIKHEF, P.O. Box 41882, 1009 DB Amsterdam; Zhou, Z.-L.

1998-01-20

We describe the polarized deuterium target internal to the NIKHEF medium-energy electron storage ring. Tensor polarized deuterium was produced in an atomic beam source and injected into a storage cell target. A Breit-Rabi polarimeter was used to monitor the injected atomic beam intensity and polarization. An electrostatic ion-extraction system and a Wien filter were utilized to measure on-line the atomic fraction of the target gas in the storage cell. This device was supplemented with a tensor polarization analyzer using the neutron anisotropy of the {sup 3}H(d,n){alpha} reaction at 60 keV. This method allows determining the density-averaged nuclear polarization of themore » target gas, independent of spatial and temporal variations. We address issues important for polarized hydrogen/deuterium internal targets, such as the effects of spin-exchange collisions and resonant transitions induced by the RF fields of the charged particle beam.« less

Electrostatic turbulence in the earth's central plasma sheet produced by multiple-ring ion distributions

NASA Technical Reports Server (NTRS)

Huba, J. D.; Chen, J.; Anderson, R. R.

1992-01-01

Attention is given to a mechanism to generate a broad spectrum of electrostatic turbulence in the quiet time central plasma sheet (CPS) plasma. It is shown theoretically that multiple-ring ion distributions can generate short-wavelength (less than about 1), electrostatic turbulence with frequencies less than about kVj, where Vj is the velocity of the jth ring. On the basis of a set of parameters from measurements made in the CPS, it is found that electrostatic turbulence can be generated with wavenumbers in the range of 0.02 and 1.0, with real frequencies in the range of 0 and 10, and with linear growth rates greater than 0.01 over a broad range of angles relative to the magnetic field (5-90 deg). These theoretical results are compared with wave data from ISEE 1 using an ion distribution function exhibiting multiple-ring structures observed at the same time. The theoretical results in the linear regime are found to be consistent with the wave data.

Transverse-structure electrostatic charged particle beam lens

DOEpatents

Moran, M.J.

1998-10-13

Electrostatic particle-beam lenses using a concentric co-planar array of independently biased rings can be advantageous for some applications. Traditional electrostatic lenses often consist of axial series of biased rings, apertures, or tubes. The science of lens design has devoted much attention to finding axial arrangements that compensate for the substantial optical aberrations of the individual elements. Thus, as with multi-element lenses for light, a multi-element charged-particle lens can have optical behavior that is far superior to that of the individual elements. Transverse multiple-concentric-ring lenses achieve high performance, while also having advantages in terms of compactness and optical versatility. 7 figs.

Transverse-structure electrostatic charged particle beam lens

DOEpatents

Moran, Michael J.

1998-01-01

Electrostatic particle-beam lenses using a concentric co-planar array of independently biased rings can be advantageous for some applications. Traditional electrostatic lenses often consist of axial series of biased rings, apertures, or tubes. The science of lens design has devoted much attention to finding axial arrangements that compensate for the substantial optical aberrations of the individual elements. Thus, as with multi-element lenses for light, a multi-element charged-particle lens can have optical behavior that is far superior to that of the individual elements. Transverse multiple-concentric-ring lenses achieve high performance, while also having advantages in terms of compactness and optical versatility.

A theoretical investigation into the strength of N-NO2 bonds, ring strain and electrostatic potential upon formation of intermolecular H-bonds between HF and the nitro group in nitrogen heterocyclic rings C n H2n N-NO2 (n = 2-5), RDX and HMX.

PubMed

Wang, Bao-Guo; Ren, Fu-de; Shi, Wen-Jing

2015-11-01

Changes in N-NO2 bond strength, ring strain energy and electrostatic potential upon formation of intermolecular H-bonds between HF and the nitro group in nitrogen heterocyclic rings C n H2n N-NO2 (n = 2-5), RDX and HMX were investigated using DFT-B3LYP and MP2(full) methods with the 6-311++G(2df,2p) and aug-cc-pVTZ basis sets. Analysis of electron density shifts was also carried out. The results indicate that H-bonding energy correlates well with the increment of ring strain energy. Upon complex formation, the strength of the N-NO2 trigger-bond is enhanced, suggesting reduced sensitivity, while judged by the increased ring strain energy, sensitivity is increased. However, some features of the molecular surface electrostatic potential, such as a local maximum above the N-NO2 bond and ring, σ + (2) and electrostatic balance parameter ν, remain essentially unchanged upon complex formation, and only a small change in the impact sensitivity h 50 is suggested. It is not sufficient to determine sensitivity solely on the basis of trigger bond or ring strain; as a global feature of a molecule, the molecular surface electrostatic potential is available to help judge the change of sensitivity in H-bonded complexes. Graphical Abstract The strengthened N-NO2 bond suggests reduced sensitivity, while it is reverse by theincreased ring strain energy upon the complex formation. However, the molecular surfaceelectrostatic potential (V S) shows the little change of h 50. The V S should be taken into accountin the analysis of explosive sensitivity in the H-bonded complex.

The Stiffness Variation of a Micro-Ring Driven by a Traveling Piecewise-Electrode

PubMed Central

Li, Yingjie; Yu, Tao; Hu, Yuh-Chung

2014-01-01

In the practice of electrostatically actuated micro devices; the electrostatic force is implemented by sequentially actuated piecewise-electrodes which result in a traveling distributed electrostatic force. However; such force was modeled as a traveling concentrated electrostatic force in literatures. This article; for the first time; presents an analytical study on the stiffness variation of microstructures driven by a traveling piecewise electrode. The analytical model is based on the theory of shallow shell and uniform electrical field. The traveling electrode not only applies electrostatic force on the circular-ring but also alters its dynamical characteristics via the negative electrostatic stiffness. It is known that; when a structure is subjected to a traveling constant force; its natural mode will be resonated as the traveling speed approaches certain critical speeds; and each natural mode refers to exactly one critical speed. However; for the case of a traveling electrostatic force; the number of critical speeds is more than that of the natural modes. This is due to the fact that the traveling electrostatic force makes the resonant frequencies of the forward and backward traveling waves of the circular-ring different. Furthermore; the resonance and stability can be independently controlled by the length of the traveling electrode; though the driving voltage and traveling speed of the electrostatic force alter the dynamics and stabilities of microstructures. This paper extends the fundamental insights into the electromechanical behavior of microstructures driven by electrostatic forces as well as the future development of MEMS/NEMS devices with electrostatic actuation and sensing. PMID:25230308

The stiffness variation of a micro-ring driven by a traveling piecewise-electrode.

PubMed

Li, Yingjie; Yu, Tao; Hu, Yuh-Chung

2014-09-16

In the practice of electrostatically actuated micro devices; the electrostatic force is implemented by sequentially actuated piecewise-electrodes which result in a traveling distributed electrostatic force. However; such force was modeled as a traveling concentrated electrostatic force in literatures. This article; for the first time; presents an analytical study on the stiffness variation of microstructures driven by a traveling piecewise electrode. The analytical model is based on the theory of shallow shell and uniform electrical field. The traveling electrode not only applies electrostatic force on the circular-ring but also alters its dynamical characteristics via the negative electrostatic stiffness. It is known that; when a structure is subjected to a traveling constant force; its natural mode will be resonated as the traveling speed approaches certain critical speeds; and each natural mode refers to exactly one critical speed. However; for the case of a traveling electrostatic force; the number of critical speeds is more than that of the natural modes. This is due to the fact that the traveling electrostatic force makes the resonant frequencies of the forward and backward traveling waves of the circular-ring different. Furthermore; the resonance and stability can be independently controlled by the length of the traveling electrode; though the driving voltage and traveling speed of the electrostatic force alter the dynamics and stabilities of microstructures. This paper extends the fundamental insights into the electromechanical behavior of microstructures driven by electrostatic forces as well as the future development of MEMS/NEMS devices with electrostatic actuation and sensing.

A Versatile Ion Injector at KACST

NASA Astrophysics Data System (ADS)

El Ghazaly, M. O. A.; Behery, S. A.; Almuqhim, A. A.; Papash, A. I.; Welsch, C. P.

2011-10-01

A versatile ion-beam injector is presently being constructed at the National Centre for Mathematics and Physics (NCMP) at the King Abdul-Aziz City for Science and Technology (KACST), Saudi Arabia. This versatile injector will provide an electrostatic storage ring with high-quality ion beams of energies up to 30 keV per charge q. It will also allow for crossed-beams experiments in single-pass setups. The injector has been designed to include beams from two different ion sources, switched by a 90° deflection setup, and to allow for matching of the beam parameters to the Twiss parameters of the ring. The injector is equipped with two crossed beam-lines (inlets), with duplicated beam extraction and acceleration systems. As part of the initial setup, a simple electric discharge ion source has been developed for commissioning of the whole injector. In this paper, we report on the ion optics layout and the design parameters of the injector.

Investigation of critical parameters controlling the efficiency of associative ionization

NASA Astrophysics Data System (ADS)

Le Padellec, A.; Launoy, T.; Dochain, A.; Urbain, X.

2017-05-01

This paper compiles our merged-beam experimental findings for the associative ionization (AI) process from charged reactants, with the aim of guiding future investigations with e.g. the double electrostatic ion storage ring DESIREE in Stockholm. A reinvestigation of the isotopic effect in H-(D-) + He+ collisions is presented, along with a review of {{{H}}}3+ and NO+ production by AI involving ion pairs or excited neutrals, and put in perspective with the mutual neutralization and radiative association reactions. Critical parameters are identified and evaluated for their systematic role in controlling the magnitude of the cross section: isotopic substitution, exothermicity, electronic state density, and spin statistics.

Using Programmable Calculators to Solve Electrostatics Problems.

ERIC Educational Resources Information Center

Yerian, Stephen C.; Denker, Dennis A.

1985-01-01

Provides a simple routine which allows first-year physics students to use programmable calculators to solve otherwise complex electrostatic problems. These problems involve finding electrostatic potential and electric field on the axis of a uniformly charged ring. Modest programing skills are required of students. (DH)

Histidine in Continuum Electrostatics Protonation State Calculations

PubMed Central

Couch, Vernon; Stuchebruckhov, Alexei

2014-01-01

A modification to the standard continuum electrostatics approach to calculate protein pKas which allows for the decoupling of histidine tautomers within a two state model is presented. Histidine with four intrinsically coupled protonation states cannot be easily incorporated into a two state formalism because the interaction between the two protonatable sites of the imidazole ring is not purely electrostatic. The presented treatment, based on a single approximation of the interrelation between histidine’s charge states, allows for a natural separation of the two protonatable sites associated with the imidazole ring as well as the inclusion of all protonation states within the calculation. PMID:22072521

The source of Saturn electrostatic discharges: Atmospheric storms

NASA Technical Reports Server (NTRS)

Kaiser, M. L.; Connerney, J. E. P.; Desch, M. D.

1983-01-01

Important properties of the recently discovered Saturn electrostatic discharges are entirely consistent with an extended lightning storm system in Saturn's atmosphere. The presently favored B-ring location is ruled out.

Design Considerations for High Energy Electron -- Positron Storage Rings

DOE R&D Accomplishments Database

Richter, B.

1966-11-01

High energy electron-positron storage rings give a way of making a new attack on the most important problems of elementary particle physics. All of us who have worked in the storage ring field designing, building, or using storage rings know this. The importance of that part of storage ring work concerning tests of quantum electrodynamics and mu meson physics is also generally appreciated by the larger physics community. However, I do not think that most of the physicists working tin the elementary particle physics field realize the importance of the contribution that storage ring experiments can make to our understanding of the strongly interacting particles. I would therefore like to spend the next few minutes discussing the sort of things that one can do with storage rings in the strongly interacting particle field.

Regular threshold-energy increase with charge for neutral-particle emission in collisions of electrons with oligonucleotide anions.

PubMed

Tanabe, T; Noda, K; Saito, M; Starikov, E B; Tateno, M

2004-07-23

Electron-DNA anion collisions were studied using an electrostatic storage ring with a merging electron-beam technique. The rate of neutral particles emitted in collisions started to increase from definite threshold energies, which increased regularly with ion charges in steps of about 10 eV. These threshold energies were almost independent of the length and sequence of DNA, but depended strongly on the ion charges. Neutral particles came from breaks of DNAs, rather than electron detachment. The step of the threshold energy increase approximately agreed with the plasmon excitation energy. It is deduced that plasmon excitation is closely related to the reaction mechanism. Copyright 2004 The American Physical Society

The electrostatic properties of Fiber-Reinforced-Plastics double wall underground storage gasoline tanks

NASA Astrophysics Data System (ADS)

Li, Yipeng; Liu, Quanzhen; Meng, He; Sun, Lifu; Zhang, Yunpeng

2013-03-01

At present Fiber Reinforced Plastics (FRP) double wall underground storage gasoline tanks are wildly used. An FRP product with a resistance of more than 1011 Ω is a static non-conductor, so it is difficult for the static electricity in the FRP product to decay into the earth. In this paper an experimental system was built to simulate an automobile gasoline filling station. Some electrostatic parameters of the gasoline, including volume charge density, were tested when gasoline was unloaded into a FRP double wall underground storage tank. Measurements were taken to make sure the volume charge density in the oil-outlet was similar to the volume charge density in the tank. In most cases the volume charge density of the gasoline was more than 22.7 μC m-3, which is likely to cause electrostatic discharge in FRP double wall underground storage gasoline tanks. On the other hand, it would be hard to ignite the vapor by electrostatic discharge since the vapor pressure in the tanks is over the explosion limit. But when the tank is repaired or re-used, the operators must pay attention to the static electricity and some measurements should be taken to avoid electrostatic accident. Besides the relaxation time of charge in the FRP double wall gasoline storage tanks should be longer.

Electrostatically confined quantum rings in bilayer graphene.

PubMed

Zarenia, M; Pereira, J M; Peeters, F M; Farias, G A

2009-12-01

We propose a new system where electron and hole states are electrostatically confined into a quantum ring in bilayer graphene. These structures can be created by tuning the gap of the graphene bilayer using nanostructured gates or by position-dependent doping. The energy levels have a magnetic field (B(0)) dependence that is strikingly distinct from that of usual semiconductor quantum rings. In particular, the eigenvalues are not invariant under a B(0) --> -B(0) transformation and, for a fixed total angular momentum index m, their field dependence is not parabolic, but displays two minima separated by a saddle point. The spectra also display several anticrossings, which arise due to the overlap of gate-confined and magnetically confined states.

Transfer matrix calculation for ion optical elements using real fields

NASA Astrophysics Data System (ADS)

Mishra, P. M.; Blaum, K.; George, S.; Grieser, M.; Wolf, A.

2018-03-01

With the increasing importance of ion storage rings and traps in low energy physics experiments, an efficient transport of ion species from the ion source area to the experimental setup becomes essential. Some available, powerful software packages rely on transfer matrix calculations in order to compute the ion trajectory through the ion-optical beamline systems of high complexity. With analytical approaches, so far the transfer matrices are documented only for a few ideal ion optical elements. Here we describe an approach (using beam tracking calculations) to determine the transfer matrix for any individual electrostatic or magnetostatic ion optical element. We verify the procedure by considering the well-known cases and then apply it to derive the transfer matrix of a 90-degree electrostatic quadrupole deflector including its realistic geometry and fringe fields. A transfer line consisting of a quadrupole deflector and a quadrupole doublet is considered, where the results from the standard first order transfer matrix based ion optical simulation program implementing the derived transfer matrix is compared with the real field beam tracking simulations.

Longitudinal space charge compensation at PSR

NASA Astrophysics Data System (ADS)

Neri, Filippo

1998-11-01

The longitudinal space-charge force in neutron spallation source compressor ring or other high intensity proton storage rings can be compensated by introducing an insert in the ring. The effect of the inductor is to cancel all or part of the space charge potential, because it is capacitive. The Proton Storage Ring at Los Alamos National Laboratory is a compressor ring used to produce short pulses of spallation neutrons. Inductive inserts design for space charge compensation at the Los Alamos Proton Storage Ring is described.

Total water storage dynamics derived from tree-ring records and terrestrial gravity observations

NASA Astrophysics Data System (ADS)

Creutzfeldt, Benjamin; Heinrich, Ingo; Merz, Bruno

2015-10-01

For both societal and ecological reasons, it is important to understand past and future subsurface water dynamics but estimating subsurface water storage is notoriously difficult. In this pilot study, we suggest the reconstruction of subsurface water dynamics by a multi-disciplinary approach combining hydrology, dendrochronology and geodesy. In a first step, nine complete years of high-precision gravimeter observations are used to estimate water storage changes in the subsurface at the Geodetic Observatory Wettzell in the Bavarian Forest, Germany. The record is extended to 63 years by calibrating a hydrological model against the 9 years of gravimeter observations. The relationship between tree-ring growth and water storage changes is evaluated as well as that between tree-ring growth and supplementary hydro-meteorological data. Results suggest that tree-ring growth is influenced primarily by subsurface water storage. Other variables related to the overall moisture status (e.g., Standardized Precipitation Index, Palmer Drought Severity Index, streamflow) are also strongly correlated with tree-ring width. While these indices are all indicators of water stored in the landscape, water storage changes of the subsurface estimated by depth-integral measurements give us the unique opportunity to directly reconstruct subsurface water storage dynamics from records of tree-ring width. Such long reconstructions will improve our knowledge of past water storage variations and our ability to predict future developments. Finally, knowing the relationship between subsurface storage dynamics and tree-ring growth improves the understanding of the different signal components contained in tree-ring chronologies.

Retinal Photoisomerization in Rhodopsin: Electrostatic and Steric Catalysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tomasello, Gaia; Altoe, Piero; Stenta, Marco

2007-12-26

Excited state QM(CASPT2//CASSCF)/MM(GAFF) calculations, by our recently developed code COBRAMM (Computations at Bologna Relating Ab-initio and Molecular Mechanic Methods), were carried out in rhodopsin to investigate on the steric and electrostatic effects in retinal photoisomerization catalysis due to the {beta}-ionone ring and glutammate 181 (GLU 181), respectively. The excited state photoisomerization channel has been mapped and a new christallographyc structure (2.2 Aa resolution) has been used for this purpose. Two different set-ups have been used to evaluate the electrostatic effects of GLU 181 (which is very close to the central double bond of the chromophore): the first with a neutralmore » GLU 181 (as commonly accepted), the second with a negatively charged (i.e. deprotonated) GLU 181 (as very recent experimental findings seem to suggest). On the other hand, {beta}-ionone ring steric effects were evaluated by calculating the photoisomerization path of a modified chromophore, where the ring double bond has been saturated. Spectroscopic properties were calculated and compared with the available experimental data.« less

Electrostatic/magnetic ion acceleration through a slowly diverging magnetic nozzle between a ring anode and an on-axis hollow cathode

NASA Astrophysics Data System (ADS)

Sasoh, A.; Mizutani, K.; Iwakawa, A.

2017-06-01

Ion acceleration through a slowly diverging magnetic nozzle between a ring anode and a hollow cathode set on the axis of symmetry has been realized. Xenon was supplied as the propellant gas from an annular slit along the inner surface of the ring anode so that it was ionized near the anode, and the applied electric potential was efficiently transformed to an ion kinetic energy. As an electrostatic thruster, within the examined operation conditions, the thrust, F, almost scaled with the propellant mass flow rate; the discharge current, Jd, increased with the discharge voltage, Vd. An important characteristic was that the thrust also exhibited electromagnetic acceleration performance, i.e., the so-called "swirl acceleration," in which F ≅JdB Ra /√{2 }, where B and Ra were a magnetic field and an anode inner radius, respectively. Such a unique thruster performance combining both electrostatic and electromagnetic accelerations is expected to be useful as another option for in-space electric propulsion in its broad functional diversity.

Ion related problems for the XLS ring

NASA Astrophysics Data System (ADS)

Bozoki, Eva S.; Halama, Henry

1991-10-01

The electron beam in a storage ring collides with the residual gas in the vacuum chamber. As a consequence, low velocity positive ions are produced and trapped in the potential well of the electron beam. They perform stable or unstable oscillations around the beam under the repetitive Coulomb force of the bunches. If not cleared, the captured ions can lead to partial or total neutralization of the beam, causing both a decrease of lifetime and a change in the vertical tunes as well as an increase in the tune spread. It can also cause coherent and incoherent transverse instabilities. An electrostatic clearing electrodes system was designed to keep the neutralization below a desired limit. The location and the geometry of the clearing electrodes as well as the applied clearing voltage is based on the study of the ion production rate, longitudinal velocity of ions in field-free regions and in the dipoles, beam self-electric field, beam potential, critical mass for ion capture in the bunched beam and the bounce frequencies of the ions, tune shift and pressure rise due to trapped ions.

UV action spectroscopy of protonated PAH derivatives. Methyl substituted quinolines

NASA Astrophysics Data System (ADS)

Klærke, B.; Holm, A. I. S.; Andersen, L. H.

2011-08-01

Aims: We investigate the production of molecular photofragments upon UV excitation of PAH derivatives, relevant for the interstellar medium. Methods: The action absorption spectra of protonated gas-phase methyl-substituted quinolines (CH3 - C9H7NH+) have been recorded in the 215-338 nm spectral range using the electrostatic storage ring ELISA, an electrospray ion source and 3 ns UV laser pulses. Results: It is shown that the absorption profile is both redshifted and broadened when moving the methyl group from the heterocycle containing nitrogen to the homoatomic ring. The absorption profiles are explained by TD-DFT calculations. The dissociation time of the studied molecules is found to be of several milliseconds at 230 nm and it is shown that after redistribution of the absorbed energy the molecules dissociate in several channels. The dissociation time found is an order of magnitude faster than the estimated IR relaxation time. Photophysical properties of both nitrogen containing and methyl-substituted PAHs are interesting in an astrophysical context in connection with identifying the aromatic component of the interstellar medium.

Beam dynamics and expected performance of Sweden's new storage-ring light source: MAX IV

NASA Astrophysics Data System (ADS)

Leemann, S. C.; Andersson, Å.; Eriksson, M.; Lindgren, L.-J.; Wallén, E.; Bengtsson, J.; Streun, A.

2009-12-01

MAX IV will be Sweden’s next-generation high-performance synchrotron radiation source. The project has recently been granted funding and construction is scheduled to begin in 2010. User operation for a broad and international user community should commence in 2015. The facility is comprised of two storage rings optimized for different wavelength ranges, a linac-based short-pulse facility and a free-electron laser for the production of coherent radiation. The main radiation source of MAX IV will be a 528 m ultralow emittance storage ring operated at 3 GeV for the generation of high-brightness hard x rays. This storage ring was designed to meet the requirements of state-of-the-art insertion devices which will be installed in nineteen 5 m long dispersion-free straight sections. The storage ring is based on a novel multibend achromat design delivering an unprecedented horizontal bare lattice emittance of 0.33 nm rad and a vertical emittance below the 8 pm rad diffraction limit for 1 Å radiation. In this paper we present the beam dynamics considerations behind this storage-ring design and detail its expected unique performance.

Coarse-grained electrostatic interactions of coronene: Towards the crystalline phase

NASA Astrophysics Data System (ADS)

Heinemann, Thomas; Palczynski, Karol; Dzubiella, Joachim; Klapp, Sabine H. L.

2015-11-01

In this article, we present and compare two different, coarse-grained approaches to model electrostatic interactions of disc-shaped aromatic molecules, specifically coronene. Our study builds on our previous work [T. Heinemann et al., J. Chem. Phys. 141, 214110 (2014)], where we proposed, based on a systematic coarse-graining procedure starting from the atomistic level, an anisotropic effective (Gay-Berne-like) potential capable of describing van der Waals contributions to the interaction energy. To take into account electrostatics, we introduce, first, a linear quadrupole moment along the symmetry axis of the coronene disc. The second approach takes into account the fact that the partial charges within the molecules are distributed in a ring-like fashion. We then reparametrize the effective Gay-Berne-like potential such that it matches, at short distances, the ring-ring potential. To investigate the validity of these two approaches, we perform many-particle molecular dynamics simulations, focusing on the crystalline phase (karpatite) where electrostatic interaction effects are expected to be particularly relevant for the formation of tilted stacked columns. Specifically, we investigate various structural parameters as well as the melting transition. We find that the second approach yields consistent results with those from experiments despite the fact that the underlying potential decays with the wrong distance dependence at large molecule separations. Our strategy can be transferred to a broader class of molecules, such as benzene or hexabenzocoronene.

Coarse-grained electrostatic interactions of coronene: Towards the crystalline phase.

PubMed

Heinemann, Thomas; Palczynski, Karol; Dzubiella, Joachim; Klapp, Sabine H L

2015-11-07

In this article, we present and compare two different, coarse-grained approaches to model electrostatic interactions of disc-shaped aromatic molecules, specifically coronene. Our study builds on our previous work [T. Heinemann et al., J. Chem. Phys. 141, 214110 (2014)], where we proposed, based on a systematic coarse-graining procedure starting from the atomistic level, an anisotropic effective (Gay-Berne-like) potential capable of describing van der Waals contributions to the interaction energy. To take into account electrostatics, we introduce, first, a linear quadrupole moment along the symmetry axis of the coronene disc. The second approach takes into account the fact that the partial charges within the molecules are distributed in a ring-like fashion. We then reparametrize the effective Gay-Berne-like potential such that it matches, at short distances, the ring-ring potential. To investigate the validity of these two approaches, we perform many-particle molecular dynamics simulations, focusing on the crystalline phase (karpatite) where electrostatic interaction effects are expected to be particularly relevant for the formation of tilted stacked columns. Specifically, we investigate various structural parameters as well as the melting transition. We find that the second approach yields consistent results with those from experiments despite the fact that the underlying potential decays with the wrong distance dependence at large molecule separations. Our strategy can be transferred to a broader class of molecules, such as benzene or hexabenzocoronene.

Formation of fine dust on Saturn's rings as suggested by the presence of spokes

NASA Technical Reports Server (NTRS)

Smoluchowski, R.

1983-01-01

The common interpretation of spokes on the B ring of Saturn is that they are the result of light scattered by electrostatically levitated micrometer- and submicrometer-size dust particles. The origin of this dust in terms of radiation-induced thermal fatigue and collisions between the particles of the ring as well as meteoritic bombardment is investigated.

Water, gravity and trees: Relationship of tree-ring widths and total water storage dynamics

NASA Astrophysics Data System (ADS)

Creutzfeldt, B.; Heinrich, I.; Merz, B.; Blume, T.; Güntner, A.

2012-04-01

Water stored in the subsurface as groundwater or soil moisture is the main fresh water source not only for drinking water and food production but also for the natural vegetation. In a changing environment water availability becomes a critical issue in many different regions. Long-term observations of the past are needed to improve the understanding of the hydrological system and the prediction of future developments. Tree ring data have repeatedly proved to be valuable sources for reconstructing long-term climate dynamics, e.g. temperature, precipitation and different hydrological variables. In water-limited environments, tree growth is primarily influenced by total water stored in the subsurface and hence, tree-ring records usually contain information about subsurface water storage. The challenge is to retrieve the information on total water storage from tree rings, because a training dataset of water stored in the sub-surface is required for calibration against the tree-ring series. However, measuring water stored in the subsurface is notoriously difficult. We here present high-precision temporal gravimeter measurements which allow for the depth-integrated quantification of total water storage dynamics at the field scale. In this study, we evaluate the relationship of total water storage change and tree ring growth also in the context of the complex interactions of other meteorological forcing factors. A tree-ring chronology was derived from a Norway spruce stand in the Bavarian Forest, Germany. Total water storage dynamics were measured directly by the superconducting gravimeter of the Geodetic Observatory Wettzell for a 9-years period. Time series were extended to 63-years period by a hydrological model using gravity data as the only calibration constrain. Finally, water storage changes were reconstructed based on the relationship between the hydrological model and the tree-ring chronology. Measurement results indicate that tree-ring growth is primarily controlled by total water storage in the subsurface. But high uncertainties intervals of the correlation coefficient urges for the extension of the measurement period. This multi-disciplinary study, combining hydrology, dendrochronology and geodesy shows that temporal gravimeter measurements may give us the unique opportunity to retrieve the information of total water storage contained in tree-ring records to reconstruct total water storage dynamics. Knowing the relationship of water storage and tree-ring growth can also support the reconstruction of other climate records based on tree-ring series, help with hydrological model testing and can improve our knowledge of long-term variations of water storage in the past.

Planning and Prototyping for a Storage Ring Measurement of the Proton Electric Dipole Moment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Talman, Richard

2015-07-01

Electron and proton EDM's can be measured in "frozen spin" (with the beam polarization always parallel to the orbit, for example) storage rings. For electrons the "magic" kinetic energy at which the beam can be frozen is 14.5 MeV. For protons the magic kinetic energy is 230 MeV. The currently measured upper limit for the electron EDM is much smaller than the proton EDM upper limit, which is very poorly known. Nevertheless, because the storage ring will be an order of magnitude cheaper, a sensible plan is to first build an all-electric electron storage ring as a prototype. Such anmore » electron ring was successfully built at Brookhaven, in 1954, as a prototype for their AGS ring. This leaves little uncertainty concerning the cost and performance of such a ring. (This is documentedin one of the Physical Review papers mentioned above.)« less

Electrostatically screened, voltage-controlled electrostatic chuck

DOEpatents

Klebanoff, Leonard Elliott

2001-01-01

Employing an electrostatically screened, voltage-controlled electrostatic chuck particularly suited for holding wafers and masks in sub-atmospheric operations will significantly reduce the likelihood of contaminant deposition on the substrates. The electrostatic chuck includes (1) an insulator block having a outer perimeter and a planar surface adapted to support the substrate and comprising at least one electrode (typically a pair of electrodes that are embedded in the insulator block), (2) a source of voltage that is connected to the at least one electrode, (3) a support base to which the insulator block is attached, and (4) a primary electrostatic shield ring member that is positioned around the outer perimeter of the insulator block. The electrostatic chuck permits control of the voltage of the lithographic substrate; in addition, it provides electrostatic shielding of the stray electric fields issuing from the sides of the electrostatic chuck. The shielding effectively prevents electric fields from wrapping around to the upper or front surface of the substrate, thereby eliminating electrostatic particle deposition.

Storage-ring Electron Cooler for Relativistic Ion Beams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, Fanglei; Derbenev, Yaroslav; Douglas, David R.

Application of electron cooling at ion energies above a few GeV has been limited due to reduction of electron cooling efficiency with energy and difficulty in producing and accelerating a high-current high-quality electron beam. A high-current storage-ring electron cooler offers a solution to both of these problems by maintaining high cooling beam quality through naturally-occurring synchrotron radiation damping of the electron beam. However, the range of ion energies where storage-ring electron cooling can be used has been limited by low electron beam damping rates at low ion energies and high equilibrium electron energy spread at high ion energies. This papermore » reports a development of a storage ring based cooler consisting of two sections with significantly different energies: the cooling and damping sections. The electron energy and other parameters in the cooling section are adjusted for optimum cooling of a stored ion beam. The beam parameters in the damping section are adjusted for optimum damping of the electron beam. The necessary energy difference is provided by an energy recovering SRF structure. A prototype linear optics of such storage-ring cooler is presented.« less

Particle simulation of electromagnetic emissions from electrostatic instability driven by an electron ring beam on the density gradient

NASA Astrophysics Data System (ADS)

Horký, Miroslav; Omura, Yoshiharu; Santolík, Ondřej

2018-04-01

This paper presents the wave mode conversion between electrostatic and electromagnetic waves on the plasma density gradient. We use 2-D electromagnetic code KEMPO2 implemented with the generation of density gradient to simulate such a conversion process. In the dense region, we use ring beam instability to generate electron Bernstein waves and we study the temporal evolution of wave spectra, velocity distributions, Poynting flux, and electric and magnetic energies to observe the wave mode conversion. Such a conversion process can be a source of electromagnetic emissions which are routinely measured by spacecraft on the plasmapause density gradient.

Physics issues in diffraction limited storage ring design

NASA Astrophysics Data System (ADS)

Fan, Wei; Bai, ZhengHe; Gao, WeiWei; Feng, GuangYao; Li, WeiMin; Wang, Lin; He, DuoHui

2012-05-01

Diffraction limited electron storage ring is considered a promising candidate for future light sources, whose main characteristics are higher brilliance, better transverse coherence and better stability. The challenge of diffraction limited storage ring design is how to achieve the ultra low beam emittance with acceptable nonlinear performance. Effective linear and nonlinear parameter optimization methods based on Artificial Intelligence were developed for the storage ring physical design. As an example of application, partial physical design of HALS (Hefei Advanced Light Source), which is a diffraction limited VUV and soft X-ray light source, was introduced. Severe emittance growth due to the Intra Beam Scattering effect, which is the main obstacle to achieve ultra low emittance, was estimated quantitatively and possible cures were discussed. It is inspiring that better performance of diffraction limited storage ring can be achieved in principle with careful parameter optimization.

CLEARING MAGNET DESIGN FOR APS-U

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abliz, M.; Grimmer, J.; Jaski, Y.

2017-06-25

The Advanced Photon Source is in the process of developing an upgrade (APS-U) of the storage ring. The upgrade will be converting the current double bend achromat (DBA) lattice to a multi-bend achromat (MBA) lattice. In addition, the storage ring will be operated at 6 GeV and 200 mA with regular swap-out injection to keep the stored beam current constant [1]. The swap-out injection will take place with beamline shutters open. For radiation safety to ensure that no electrons can exit the storage ring, a passive method of protecting the beamline and containing the electrons inside the storage ring ismore » proposed. A clearing magnet will be located in all beamline front ends inside the storage ring tunnel. This article will discuss the features and design of the clearing magnet scheme for APS-U.« less

National Synchrotron Light Source II storage ring vacuum systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hseuh, Hsiao-Chaun, E-mail: hseuh@bnl.gov; Hetzel, Charles; Leng, Shuwei

2016-05-15

The National Synchrotron Light Source II, completed in 2014, is a 3-GeV synchrotron radiation (SR) facility at Brookhaven National Laboratory and has been in steady operation since. With a design electron current of 500 mA and subnanometer radians horizontal emittance, this 792-m circumference storage ring is providing the highest flux and brightness x-ray beam for SR users. The majority of the storage ring vacuum chambers are made of extruded aluminium. Chamber sections are interconnected using low-impedance radiofrequency shielded bellows. SR from the bending magnets is intercepted by water-cooled compact photon absorbers resided in the storage ring chambers. This paper presents themore » design of the storage ring vacuum system, the fabrication of vacuum chambers and other hardware, the installation, the commissioning, and the continuing beam conditioning of the vacuum systems.« less

Online optimization of storage ring nonlinear beam dynamics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huang, Xiaobiao; Safranek, James

2015-08-01

We propose to optimize the nonlinear beam dynamics of existing and future storage rings with direct online optimization techniques. This approach may have crucial importance for the implementation of diffraction limited storage rings. In this paper considerations and algorithms for the online optimization approach are discussed. We have applied this approach to experimentally improve the dynamic aperture of the SPEAR3 storage ring with the robust conjugate direction search method and the particle swarm optimization method. The dynamic aperture was improved by more than 5 mm within a short period of time. Experimental setup and results are presented.

High to ultra-high power electrical energy storage.

PubMed

Sherrill, Stefanie A; Banerjee, Parag; Rubloff, Gary W; Lee, Sang Bok

2011-12-14

High power electrical energy storage systems are becoming critical devices for advanced energy storage technology. This is true in part due to their high rate capabilities and moderate energy densities which allow them to capture power efficiently from evanescent, renewable energy sources. High power systems include both electrochemical capacitors and electrostatic capacitors. These devices have fast charging and discharging rates, supplying energy within seconds or less. Recent research has focused on increasing power and energy density of the devices using advanced materials and novel architectural design. An increase in understanding of structure-property relationships in nanomaterials and interfaces and the ability to control nanostructures precisely has led to an immense improvement in the performance characteristics of these devices. In this review, we discuss the recent advances for both electrochemical and electrostatic capacitors as high power electrical energy storage systems, and propose directions and challenges for the future. We asses the opportunities in nanostructure-based high power electrical energy storage devices and include electrochemical and electrostatic capacitors for their potential to open the door to a new regime of power energy.

Large diameter metal ring seal prevents gas leakage at 5000 psi

NASA Technical Reports Server (NTRS)

Middelkoop, J. H.

1966-01-01

Large metal ring seal prevents gas leakage in hydrogen, helium, or nitrogen storage bottles at pressures up to 5,000 psi. The grooved ring seal which contains elastomer O-rings is installed between the mating faces of the access cover and the storage bottle.

A Superconducting Magnet UCN Trap for Precise Neutron Lifetime Measurements.

PubMed

Picker, R; Altarev, I; Bröcker, J; Gutsmiedl, E; Hartmann, J; Müller, A; Paul, S; Schott, W; Trinks, U; Zimmer, O

2005-01-01

Finite-element methods along with Monte Carlo simulations were used to design a magnetic storage device for ultracold neutrons (UCN) to measure their lifetime. A setup was determined which should make it possible to confine UCN with negligible losses and detect the protons emerging from β-decay with high efficiency: stacked superconducting solenoids create the magnetic storage field, an electrostatic extraction field inside the storage volume assures high proton collection efficiency. Alongside with the optimization of the magnetic and electrostatic design, the properties of the trap were investigated through extensive Monte Carlo simulation.

National Synchrotron Light Source II storage ring vacuum systems

DOE PAGES

Hseuh, Hsiao-Chaun; Hetzel, Charles; Leng, Shuwei; ...

2016-04-05

The National Synchrotron Light Source II, completed in 2014, is a 3-GeV synchrotron radiation (SR) facility at Brookhaven National Laboratory and has been in steady operation since. With a design electron current of 500 mA and subnanometer radians horizontal emittance, this 792-m circumference storage ring is providing the highest flux and brightness x-ray beam for SR users. Also, the majority of the storage ring vacuum chambers are made of extruded aluminium. Chamber sections are interconnected using low-impedance radiofrequency shielded bellows. SR from the bending magnets is intercepted by water-cooled compact photon absorbers resided in the storage ring chambers. Finally, thismore » paper presents the design of the storage ring vacuum system, the fabrication of vacuum chambers and other hardware, the installation, the commissioning, and the continuing beam conditioning of the vacuum systems.« less

Front-end simulation of injector for terawatt accumulator.

PubMed

Kropachev, G N; Balabin, A I; Kolomiets, A A; Kulevoy, T V; Pershin, V I; Shumshurov, A V

2008-02-01

A terawatt accumulator (TWAC) accelerator/storage ring complex with the laser ion source is in progress at ITEP. The new injector I4 based on the radio frequency quadrupole (RFQ) and interdigital H-mode (IH) linear accelerator is under construction. The front end of the new TWAC injector consists of a laser ion source, an extraction system, and a low energy beam transport (LEBT). The KOBRA3-INP was used for the simulation and optimization of the ion source extraction system. The optimization parameter is the maximum brightness of the beam generated by the laser ion source. Also the KOBRA3-INP code was used for LEBT investigation. The LEBT based on electrostatic grid lenses is chosen for injector I4. The results of the extraction system and LEBT investigations for ion beam matching with RFQ are presented.

Duke storage rink UV/VUV FEL: Status and prospects

DOE Office of Scientific and Technical Information (OSTI.GOV)

Litvinenko, V.N.; Burnham, B.; Madey, J.M.J.

1995-12-31

The 1 GeV Duke storage ring was successfully commissioned with parameters exceeding initial specification. The OK-4 FEL has arrived at the Duke FEL laboratory from the Novosibirsk Institute of Nuclear Physics. The OK-4 installation and commissioning is in progress. In this paper we describe the up-to-date status of the Duke storage ring and the OK-4 FEL. The projected performance of the OK-4 UV/VUV FEL is presented based on the electron beam parameters achieved. Initial plans to operate the OK-4 UV/VUV FEL at the Duke 1 GeV storage ring are outlined. Future plans and prospects of both the OK-4 FEL andmore » the Duke storage ring are discussed.« less

A new storage-ring light source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chao, Alex

2015-06-01

A recently proposed technique in storage ring accelerators is applied to provide potential high-power sources of photon radiation. The technique is based on the steady-state microbunching (SSMB) mechanism. As examples of this application, one may consider a high-power DUV photon source for research in atomic and molecular physics or a high-power EUV radiation source for industrial lithography. A less challenging proof-of-principle test to produce IR radiation using an existing storage ring is also considered.

Dianion diagnostics in DESIREE: High-sensitivity detection of Cn2 - from a sputter ion source

NASA Astrophysics Data System (ADS)

Chartkunchand, K. C.; Stockett, M. H.; Anderson, E. K.; Eklund, G.; Kristiansson, M. K.; Kamińska, M.; de Ruette, N.; Blom, M.; Björkhage, M.; Källberg, A.; Löfgren, P.; Reinhed, P.; Rosén, S.; Simonsson, A.; Zettergren, H.; Schmidt, H. T.; Cederquist, H.

2018-03-01

A sputter ion source with a solid graphite target has been used to produce dianions with a focus on carbon cluster dianions, Cn2 -, with n = 7-24. Singly and doubly charged anions from the source were accelerated together to kinetic energies of 10 keV per atomic unit of charge and injected into one of the cryogenic (13 K) ion-beam storage rings of the Double ElectroStatic Ion Ring Experiment facility at Stockholm University. Spontaneous decay of internally hot Cn2 - dianions injected into the ring yielded Cn- anions with kinetic energies of 20 keV, which were counted with a microchannel plate detector. Mass spectra produced by scanning the magnetic field of a 90° analyzing magnet on the ion injection line reflect the production of internally hot C72 - - C242 - dianions with lifetimes in the range of tens of microseconds to milliseconds. In spite of the high sensitivity of this method, no conclusive evidence of C62 - was found while there was a clear C72 - signal with the expected isotopic distribution. This is consistent with earlier experimental studies and with theoretical predictions. An upper limit is deduced for a C62 - signal that is two orders-of-magnitude smaller than that for C72 -. In addition, CnO2- and CnCu2- dianions were detected.

Polarization Studies for the eRHIC Electron Storage Ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gianfelice-Wendt, Eliana; Tepikian, S.

A hadron/lepton collider with polarized beams has been under consideration by the scientific community since some years, in the U.S. and Europe. Among the various proposals, those by JLAB and BNL with polarized electron and proton beams are currently under closer study in the U.S. Experimenters call for the simultaneous storage of electron bunches with both spin helicity. In the BNL based Ring-Ring design, electrons are stored at top energy in a ring to be accommodated in the existing RHIC tunnel. The transversely polarized electron beam is injected into the storage ring at variable energies, between 5 and 18 GeV.more » Polarization is brought into the longitudinal direction at the IP by a couple of spin rotators. In this paper results of first studies of the attainable beam polarization level and lifetime in the storage ring at 18 GeV are presented.« less

Inertial energy storage device

DOEpatents

Knight, Jr., Charles E.; Kelly, James J.; Pollard, Roy E.

1978-01-01

The inertial energy storage device of the present invention comprises a composite ring formed of circumferentially wound resin-impregnated filament material, a flanged hollow metal hub concentrically disposed in the ring, and a plurality of discrete filament bandsets coupling the hub to the ring. Each bandset is formed of a pair of parallel bands affixed to the hub in a spaced apart relationship with the axis of rotation of the hub being disposed between the bands and with each band being in the configuration of a hoop extending about the ring along a chordal plane thereof. The bandsets are disposed in an angular relationship with one another so as to encircle the ring at spaced-apart circumferential locations while being disposed in an overlapping relationship on the flanges of the hub. The energy storage device of the present invention has the capability of substantial energy storage due to the relationship of the filament bands to the ring and the flanged hub.

Design of the transfer line from booster to storage ring at 3 GeV

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bayar, C., E-mail: cafer.bayar@cern.ch; Ciftci, A. K., E-mail: abbas.kenan.ciftci@cern.ch

The Synchrotron Booster Ring accelerates the e-beam up to 3 GeV and particles are transported from booster to storage ring by transfer line. In this study, two options are considered, the first one is a long booster which shares the same tunnel with storage ring and the second one is a compact booster. As a result, two transfer line are designed based on booster options. The optical design is constrained by the e-beam Twiss parameters entering and leaving the transfer line. Twiss parameters in the extraction point of booster are used for the entrance of transfer line and are matchedmore » in the exit of transfer line to the injection point of the storage ring.« less

An Inside Look: NSLS-II Storage Ring

ScienceCinema

Fries, Gregory

2018-06-12

Look inside the storage ring of the National Synchrotron Light Source II, under construction at Brookhaven Lab. Exactly 843 magnets now encircle the ring. Their job will be to steer, stabilize, and store electrons racing around at near light speed.

Diffraction-limited storage-ring vacuum technology

PubMed Central

Al-Dmour, Eshraq; Ahlback, Jonny; Einfeld, Dieter; Tavares, Pedro Fernandes; Grabski, Marek

2014-01-01

Some of the characteristics of recent ultralow-emittance storage-ring designs and possibly future diffraction-limited storage rings are a compact lattice combined with small magnet apertures. Such requirements present a challenge for the design and performance of the vacuum system. The vacuum system should provide the required vacuum pressure for machine operation and be able to handle the heat load from synchrotron radiation. Small magnet apertures result in the conductance of the chamber being low, and lumped pumps are ineffective. One way to provide the required vacuum level is by distributed pumping, which can be realised by the use of a non-evaporable getter (NEG) coating of the chamber walls. It may not be possible to use crotch absorbers to absorb the heat from the synchrotron radiation because an antechamber is difficult to realise with such a compact lattice. To solve this, the chamber walls can work as distributed absorbers if they are made of a material with good thermal conductivity, and distributed cooling is used at the location where the synchrotron radiation hits the wall. The vacuum system of the 3 GeV storage ring of MAX IV is used as an example of possible solutions for vacuum technologies for diffraction-limited storage rings. PMID:25177979

ONLINE MINIMIZATION OF VERTICAL BEAM SIZES AT APS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Yipeng

In this paper, online minimization of vertical beam sizes along the APS (Advanced Photon Source) storage ring is presented. A genetic algorithm (GA) was developed and employed for the online optimization in the APS storage ring. A total of 59 families of skew quadrupole magnets were employed as knobs to adjust the coupling and the vertical dispersion in the APS storage ring. Starting from initially zero current skew quadrupoles, small vertical beam sizes along the APS storage ring were achieved in a short optimization time of one hour. The optimization results from this method are briefly compared with the onemore » from LOCO (Linear Optics from Closed Orbits) response matrix correction.« less

Pushing the MAX IV 3 GeV storage ring brightness and coherence towards the limit of its magnetic lattice

NASA Astrophysics Data System (ADS)

Leemann, S. C.; Wurtz, W. A.

2018-03-01

The MAX IV 3 GeV storage ring is presently being commissioned and crucial parameters such as machine functions, emittance, and stored current have either already been reached or are approaching their design specifications. Once the baseline performance has been achieved, a campaign will be launched to further improve the brightness and coherence of this storage ring for typical X-ray users. During recent years, several such improvements have been designed. Common to these approaches is that they attempt to improve the storage ring performance using existing hardware provided for the baseline design. Such improvements therefore present more short-term upgrades. In this paper, however, we investigate medium-term improvements assuming power supplies can be exchanged in an attempt to push the brightness and coherence of the storage ring to the limit of what can be achieved without exchanging the magnetic lattice itself. We outline optics requirements, the optics optimization process, and summarize achievable parameters and expected performance.

Cabling design of booster and storage ring construction progress of TPS

NASA Astrophysics Data System (ADS)

Wong, Y.-S.; Liu, K.-B.; Liu, C.-Y.; Wang, b.-S.

2017-06-01

The 2012 Taiwan Photon Source (TPS) cable construction project started after 10 months to complete the cable laying and installation of power supply. The circumference of the booster ring (BR) is 496.8 m, whereas that of the storage ring (SR) is 518.4 m. Beam current is set to 500 mA at 3.3 GeV. The paper on grounding systems discusses the design of the ground wire (< 0.2 Ω) with low impedance, power supply of the accelerator and cabling tray. The flow and size of the ground current are carefully evaluated to avoid grounded current from flowing everywhere, which causes interference problems. In the design of the TPS, special shielding will be established to isolate the effects of electromagnetic interference on the magnet and ground current. Booster ring dipoles are connected by a series of 54-magnet bending dipole; the cable size of its stranded wire measures 250 mm2, with a total length of 5000 m. Booster ring and storage ring quadrupoles have 150 magnets; the cable size of their stranded wire is 250 mm2, with a total length of 17000 m. Storage ring dipole consists of 48 magnets; the cable size of its stranded wire is 325 mm2, with a total length of 6000 m. This study discusses the power supply cabling design of the storage ring and booster ring construction progress of TPS. The sections of this paper are divided into discussions of the construction of the control and instrument area, cabling layout of booster ring and storage ring, as well as the installation and commission machine. This study also discusses the use of a high-impedance meter to determine the effect of cabling insulation and TPS power supply machine on energy transfer to ensure the use of safe and correct magnet.

Electrostatically Levitated Ring-Shaped Rotational-Gyro/Accelerometer

NASA Astrophysics Data System (ADS)

Murakoshi, Takao; Endo, Yasuo; Fukatsu, Keisuke; Nakamura, Sigeru; Esashi, Masayoshi

2003-04-01

This paper reports an electrostatically levitated inertia measurement system which is based on the principle of a rotational gyro. The device has several advantages: the levitation of the rotor in a vacuum eliminates mechanical friction resulting in high sensitivity; the position control for the levitation allows accelerations to be sensed in the tri-axis; and the fabrication of the device by a micromachining technique has the cost advantages afforded by miniaturization. Latest measurements yield a noise floor of the gyro and that of the accelerometer as low as 0.15 deg/h1/2 and 30 μG/Hz1/2, respectively. This performance is achieved by a new sensor design. To further improve of the previous device, a ring-shaped structure is designed and fabricated by deep reactive ion etching using inductively coupled plasma. The rotor levitation is performed with capacitive detection and electrostatic actuation. Multiaxis closed-loop control is realized by differential capacitance sensing and frequency multiplying. The rotation of the micro gyro is based on the principle of a planar variable capacitance motor.

Effects of high-voltage electrostatic fields on the quality of tilapia meat during refrigeration.

PubMed

Hsieh, Chang-Wei; Lai, Cheng-Hung; Lee, Chia-Hsin; Ko, Wen-Ching

2011-08-01

Fresh fish is typically brought to market refrigerated at approximately 4 °C, R-storage. A storage method has been devised that combines refrigeration with a high-voltage electrostatic field (100 kV/m; E-storage). It was developed to improve the quality and prolong the shelf life of foods. This study investigated changes in the freshness of tilapia meat under E-storage conditions. The total viable count of tilapia reached 10⁷ CFU/g on the 7th d of refrigeration in R-storage. By the 6th d, K-value had increased from 20% to 61.7% for E-storage and to 94.7% for R-storage. Volatile basic nitrogen had increased from 12.54 mg/100 g to about 24.34 and 25.03 mg/100 g for R- and E-storage (on the 7th and 10th d), respectively. The sensory assessment also indicated that E-storage yielded an improvement in quality over that of R-storage. Practical application of the study model has the potential to prolong the freshness of fish. © 2011 Institute of Food Technologists®

Coupled beam motion in a storage ring with crab cavities

DOE PAGES

Huang, Xiaobiao

2016-02-16

We studied the coupled beam motion in a storage ring between the transverse and longitudinal directions introduced by crab cavities. Analytic form of the linear decoupling transformation is derived. Also, the equilibrium bunch distribution in an electron storage ring with a crab cavity is given, including contribution to the eigen-emittance induced by the crab cavity. Furthermore, application to the short pulse generation scheme using crab cavities [1] is considered.

RF System Requirements for a Medium-Energy Electron-Ion Collider (MEIC) at JLab

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rimmer, Robert A; Hannon, Fay E; Guo, Jiquan

2015-09-01

JLab is studying options for a medium energy electron-ion collider that could fit on the JLab site and use CEBAF as a full-energy electron injector. A new ion source, linac and booster would be required, together with collider storage rings for the ions and electrons. In order to achieve the maximum luminosity these will be high-current storage rings with many bunches. We present the high-level RF system requirements for the storage rings, ion booster ring and high-energy ion beam cooling system, and describe the technology options under consideration to meet them. We also present options for staging that might reducemore » the initial capital cost while providing a smooth upgrade path to a higher final energy. The technologies under consideration may also be useful for other proposed storage ring colliders or ultimate light sources.« less

Substituent Effects in the Benzene Dimer are Due to Direct Interactions of the Substituents with the Unsubstituted Benzene

PubMed Central

Wheeler, Steven E.; Houk, K. N.

2009-01-01

The prevailing views of substituent effects in the sandwich configuration of the benzene dimer are flawed. For example, in the polar/π model of Cozzi and co-workers (J. Am. Chem. Soc. 1992, 114, 5729), electron-withdrawing substituents enhance binding in the benzene dimer by withdrawing electron density from the π-cloud of the substituted ring, reducing the repulsive electrostatic interaction with the non-substituted benzene. Conversely, electron-donating substituents donate excess electrons into the π-system and diminish the π-stacking interaction. We present computed interaction energies for the sandwich configuration of the benzene dimer and 24 substituted dimers, as well as sandwich complexes of substituted benzenes with perfluorobenzene. While the computed interaction energies correlate well with σm values for the substituents, interaction energies for related model systems demonstrate that this trend is independent of the substituted ring. Instead, the observed trends are consistent with direct electrostatic and dispersive interactions of the substituents with the unsubstituted ring. PMID:18652453

Effects of CSR Generated from Upstream Bends in a Laser Plasma Storage Ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mitchell, C.; Qiang, J.; Venturini, M.

The recent proposal [1] of a Laser Plasma Storage Ring (LPSR) envisions the use of a laser-plasma (LP) acceleration module to inject an electron beam into a compact 500 MeV storage ring. Electron bunches generated by LP methods are naturally very short (tens of femtoseconds), presenting peak currents on the order of 10 kA or higher. Of obvious concern is the impact of collective effects and in particular Coherent Synchrotron Radiation (CSR) on the beam dynamics in the storage ring. Available simulation codes (e.g. Elegant [2]) usually include transient CSR effects but neglect the contribution of radiation emitted from trailingmore » magnets. In a compact storage ring, with dipole magnets close to each other, cross talking between different magnets could in principle be important.In this note we investigate this effect for the proposed LPSR and show that, in fact, this effect is relatively small. However our analysis also indicates that CSR effects in general would be quite strong and deserve a a careful study.« less

Ring profiler: a new method for estimating tree-ring density for improved estimates of carbon storage

Treesearch

David W. Vahey; C. Tim Scott; J.Y. Zhu; Kenneth E. Skog

2012-01-01

Methods for estimating present and future carbon storage in trees and forests rely on measurements or estimates of tree volume or volume growth multiplied by specific gravity. Wood density can vary by tree ring and height in a tree. If data on density by tree ring could be obtained and linked to tree size and stand characteristics, it would be possible to more...

Storage rings, internal targets and PEP

DOE Office of Scientific and Technical Information (OSTI.GOV)

Spencer, J.E.

Storage rings with internal targets are described, using PEP as an example. The difference between electrons and heavier particles such as protons, antiprotons, and heavy ions is also discussed because it raises possibilities of bypass insertions for more exotic experiments. PEP is compared to other rings in various contexts to verify the assertion that it is an ideal ring for many fundamental and practical applications that can be carried on simultaneously. (LEW)

Beam diagnostics at high-intensity storage rings

NASA Astrophysics Data System (ADS)

Plum, Mike

1994-10-01

Beam diagnostics at high-intensity facilities feature their own special set of problems and characteristics, issues peculiar to high-intensity storage rings include beam loss, beam halos, extraction efficiency, beam in the gap, clearing electrodes, and beam-profile measurement. The Los Alamos Proton Storage Ring (PSR) is a nice example of a high-intensity storage ring. I will discuss in some detail three diagnostic systems currently in use at the PSR: the beam-loss-monitor system, the electron-clearing system, and the beam-in-the-gap monitor. Much of our discussion is inspired by the problems we have encountered and the useful things we have learned while commissioning and developing the PSR. Another inspiration is our work on the next-generation neutron-spallation source, also known as the National Center for Neutron Research (NCNR).

Model-independent and fast determination of optical functions in storage rings via multiturn and closed-orbit data

NASA Astrophysics Data System (ADS)

Riemann, Bernard; Grete, Patrick; Weis, Thomas

2011-06-01

Multiturn (or turn-by-turn) data acquisition has proven to be a new source of direct measurements for Twiss parameters in storage rings. On the other hand, closed-orbit measurements are a long-known tool for analyzing closed-orbit perturbations with conventional beam position monitor (BPM) systems and are necessarily available at every storage ring. This paper aims at combining the advantages of multiturn measurements and closed-orbit data. We show that only two multiturn BPMs and four correctors in one localized drift space in the storage ring (diagnostic drift) are sufficient for model-independent and absolute measuring of β and φ functions at all BPMs, including the conventional ones, instead of requiring all BPMs being equipped with multiturn electronics.

Study of Storage Ring Free-Electron Laser Using Experimental and Simulation Approaches

NASA Astrophysics Data System (ADS)

Jia, Botao

2011-12-01

The Duke electron storage ring, first commissioned in November of 1994, has been developed as a dedicated driver for storage ring free-electron lasers (SRFELs) operating in a wide wavelength range from infrared, to visible, to ultraviolet (UV) and vacuum ultraviolet (VUV). The storage ring has a long straight section for various insertion devices and can be operated in a wide energy range (0.25 GeV to 1.15 GeV). Commissioned in 1995, the first free-electron laser (FEL) on the Duke storage ring was the OK-4 FEL, an optical klystron with two planar undulators sandwiching a buncher magnet. In 2005, the OK-5 FEL with two helical undulators was commissioned. Operating four undulators---two OK-4 and two OK-5 undulators, the world's first distributed optical klystron FEL was brought to operation in 2005. Via Compton scattering of FEL photons and electrons in the storage ring, the Duke FEL drives the world's most powerful, nearly monochromatic, and polarized Compton gamma-ray source, the High Intensity Gamma-ray Source (HIgammaS). Today, a variety of configurations of the storage ring FELs at Duke have been used in a wide range of research areas from nuclear physics to biophysics, from chemical and medical research to industrial applications. The capability of accurately measuring the storage ring electron beam energy spread is crucial for understanding the longitudinal beam dynamics and the dynamics of the storage ring FEL. In this dissertation, we have successfully developed a noninvasive, versatile, and accurate method to measure the energy spread using optical klystron radiation. Novel numerical methods based upon the Gauss-Hermite expansion have been developed to treat both spectral broadening and modulation on an equal footing. Through properly configuring the optical klystron, this energy spread measurement method has a large dynamic range. In addition, a model-based scheme has been developed for correcting the electron beam emittance related inhomogeneous spectral broadening effect, to further enhance the accuracy of measuring the electron beam energy spread. Taking advantage of the direct measurement method of the electron beam energy spread, we have developed another novel technique to simultaneously measure the FEL power, electron beam energy spread, and other beam parameters. This allowed us to study the FEL power in a systematic manner for the first time. Based on the experimental findings and results of the theoretical predictions, we have proposed a compact formula to predict the FEL power using only the knowledge of electron beam current, beam energy, and bunch length. As part of the dissertation work, we have developed a self-consistent numerical model to study the storage ring FEL. The simulation program models the electron beam propagation along the storage ring, multi-turn FEL interaction in the undulators, gradual intra-cavity optical power buildup, etc. This simulation code captures the main features of a storage ring FEL at different time and space scales. The simulated FEL gain has been benchmarked against measured gain and calculated gain with good agreement. The simulation package can provide comprehensive information about the FEL gain, optical pulse growth, electron beam properties, etc. In the near future, we plan to further improve the simulation model, by including additional physics effects such as microwave instability, to make it a more useful tool for FEL research.

Single-pass BPM system of the Photon Factory storage ring.

PubMed

Honda, T; Katoh, M; Mitsuhashi, T; Ueda, A; Tadano, M; Kobayashi, Y

1998-05-01

At the 2.5 GeV ring of the Photon Factory, a single-pass beam-position monitor (BPM) system is being prepared for the storage ring and the beam transport line. In the storage ring, the injected beam position during the first several turns can be measured with a single injection pulse. The BPM system has an adequate performance, useful for the commissioning of the new low-emittance lattice. Several stripline BPMs are being installed in the beam transport line. The continuous monitoring of the orbit in the beam transport line will be useful for the stabilization of the injection energy as well as the injection beam orbit.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Heinemann, Thomas, E-mail: thomas.heinemann@tu-berlin.de; Klapp, Sabine H. L., E-mail: klapp@physik.tu-berlin.de; Palczynski, Karol, E-mail: karol.palczynski@helmholtz-berlin.de

In this article, we present and compare two different, coarse-grained approaches to model electrostatic interactions of disc-shaped aromatic molecules, specifically coronene. Our study builds on our previous work [T. Heinemann et al., J. Chem. Phys. 141, 214110 (2014)], where we proposed, based on a systematic coarse-graining procedure starting from the atomistic level, an anisotropic effective (Gay-Berne-like) potential capable of describing van der Waals contributions to the interaction energy. To take into account electrostatics, we introduce, first, a linear quadrupole moment along the symmetry axis of the coronene disc. The second approach takes into account the fact that the partial chargesmore » within the molecules are distributed in a ring-like fashion. We then reparametrize the effective Gay-Berne-like potential such that it matches, at short distances, the ring-ring potential. To investigate the validity of these two approaches, we perform many-particle molecular dynamics simulations, focusing on the crystalline phase (karpatite) where electrostatic interaction effects are expected to be particularly relevant for the formation of tilted stacked columns. Specifically, we investigate various structural parameters as well as the melting transition. We find that the second approach yields consistent results with those from experiments despite the fact that the underlying potential decays with the wrong distance dependence at large molecule separations. Our strategy can be transferred to a broader class of molecules, such as benzene or hexabenzocoronene.« less

REQUIREMENTS AND GUIDELINES FOR NSLS EXPERIMENTAL BEAM LINE VACUUM SYSTEMS-REVISION B.

DOE Office of Scientific and Technical Information (OSTI.GOV)

FOERSTER,C.

Typical beam lines are comprised of an assembly of vacuum valves and shutters referred to as a ''front end'', optical elements to monochromatize, focus and split the photon beam, and an experimental area where a target sample is placed into the photon beam and data from the interaction is detected and recorded. Windows are used to separate sections of beam lines that are not compatible with storage ring ultra high vacuum. Some experimental beam lines share a common vacuum with storage rings. Sections of beam lines are only allowed to vent up to atmospheric pressure using pure nitrogen gas aftermore » a vacuum barrier is established to protect ring vacuum. The front end may only be bled up when there is no current in the machine. This is especially true on the VUV storage ring where for most experiments, windows are not used. For the shorter wavelength, more energetic photons of the x-ray ring, beryllium windows are used at various beam line locations so that the monochromator, mirror box or sample chamber may be used in a helium atmosphere or rough vacuum. The window separates ring vacuum from the environment of the downstream beam line components. The stored beam lifetime in the storage rings and the maintenance of desirable reflection properties of optical surfaces depend upon hydrocarbon-free, ultra-high vacuum systems. Storage ring vacuum systems will operate at pressures of {approximately} 1 x 10{sup {minus}10} Torr without beam and {approximately} 1 x 10{sup {minus}9} Torr with beam. Systems are free of hydrocarbons in the sense that no pumps, valves, etc. containing organics are used. Components are all-metal, chemically cleaned and bakeable. To the extent that beam lines share a common vacuum with the storage ring, the same criteria will hold for beam line components. The design philosophy for NSLS beam lines is to use all-metal, hydrocarbon-free front end components and recommend that experimenters use this approach for common vacuum hardware downstream of front ends. O-ring-sealed valves, if used, are not permitted upstream of the monochromator exit aperture. It will be the responsibility of users to demonstrate that their experiment will not degrade the pressure or quality of the storage ring vacuum. As a matter of operating policy, all beam lines will be monitored for prescribed pressure and the contribution of high mass gases to this pressure each time a beam line has been opened to ring vacuum.« less

Low-emittance tuning of storage rings using normal mode beam position monitor calibration

NASA Astrophysics Data System (ADS)

Wolski, A.; Rubin, D.; Sagan, D.; Shanks, J.

2011-07-01

We describe a new technique for low-emittance tuning of electron and positron storage rings. This technique is based on calibration of the beam position monitors (BPMs) using excitation of the normal modes of the beam motion, and has benefits over conventional methods. It is relatively fast and straightforward to apply, it can be as easily applied to a large ring as to a small ring, and the tuning for low emittance becomes completely insensitive to BPM gain and alignment errors that can be difficult to determine accurately. We discuss the theory behind the technique, present some simulation results illustrating that it is highly effective and robust for low-emittance tuning, and describe the results of some initial experimental tests on the CesrTA storage ring.

Electrostatic camera system functional design study

NASA Technical Reports Server (NTRS)

Botticelli, R. A.; Cook, F. J.; Moore, R. F.

1972-01-01

A functional design study for an electrostatic camera system for application to planetary missions is presented. The electrostatic camera can produce and store a large number of pictures and provide for transmission of the stored information at arbitrary times after exposure. Preliminary configuration drawings and circuit diagrams for the system are illustrated. The camera system's size, weight, power consumption, and performance are characterized. Tradeoffs between system weight, power, and storage capacity are identified.

Pseudo-single-bunch mode for a 100 MHz storage ring serving soft X-ray timing experiments

NASA Astrophysics Data System (ADS)

Olsson, T.; Leemann, S. C.; Georgiev, G.; Paraskaki, G.

2018-06-01

At many storage rings for synchrotron light production there is demand for serving both high-flux and timing users simultaneously. Today this is most commonly achieved by operating inhomogeneous fill patterns, but this is not preferable for rings that employ passive harmonic cavities to damp instabilities and increase Touschek lifetime. For these rings, inhomogeneous fill patterns could severely reduce the effect of the harmonic cavities. It is therefore of interest to develop methods to serve high-flux and timing users simultaneously without requiring gaps in the fill pattern. One such method is pseudo-single-bunch (PSB), where one bunch in the bunch train is kicked onto another orbit by a fast stripline kicker. The light emitted from the kicked bunch can then be separated by an aperture in the beamline. Due to recent developments in fast kicker design, PSB operation in multibunch mode is within reach for rings that operate with a 100 MHz RF system, such as the MAX IV and Solaris storage rings. This paper describes machine requirements and resulting performance for such a mode at the MAX IV 1.5 GeV storage ring. A solution for serving all beamlines is discussed as well as the consequences of beamline design and operation in the soft X-ray energy range.

A Model Describing Stable Coherent Synchrotron Radiation in Storage Rings

NASA Astrophysics Data System (ADS)

Sannibale, F.; Byrd, J. M.; Loftsdóttir, Á.; Venturini, M.; Abo-Bakr, M.; Feikes, J.; Holldack, K.; Kuske, P.; Wüstefeld, G.; Hübers, H.-W.; Warnock, R.

2004-08-01

We present a model describing high power stable broadband coherent synchrotron radiation (CSR) in the terahertz frequency region in an electron storage ring. The model includes distortion of bunch shape from the synchrotron radiation (SR), which enhances higher frequency coherent emission, and limits to stable emission due to an instability excited by the SR wakefield. It gives a quantitative explanation of several features of the recent observations of CSR at the BESSYII storage ring. We also use this model to optimize the performance of a source for stable CSR emission.

Construction and operation of a support facilities (Building 729) for operation/testing of a prototype accelerator/storage ring (XLS) and machine shop for the National Synchrotron Light Source at Brookhaven National Laboratory, Upton, New York

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-06-01

Proposed action is to construct at BNL a 5,600-ft[sup 2] support building, install and operate a prototypic 200 MeV accelerator and a prototypic 700 MeV storage ring within, and to construct and operate a 15 kV substation to power the building. The accelerator and storage ring would comprise the x-ray lithography source or XLS.

Construction and operation of a support facilities (Building 729) for operation/testing of a prototype accelerator/storage ring (XLS) and machine shop for the National Synchrotron Light Source at Brookhaven National Laboratory, Upton, New York. Environmental assessment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-06-01

Proposed action is to construct at BNL a 5,600-ft{sup 2} support building, install and operate a prototypic 200 MeV accelerator and a prototypic 700 MeV storage ring within, and to construct and operate a 15 kV substation to power the building. The accelerator and storage ring would comprise the x-ray lithography source or XLS.

High resolution monochromator for the VUV radiation from the DORIS storage ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saile, V.; Gurtler, P.; Koch, E.E.

1976-10-01

The unique properties of the DORIS storage ring at DESY as a synchroton radiation source are exploited for high resolution spectroscopy in the vacuum ultraviolet. We describe a new experimental set up with a 3-m normal incidence monochromator for wavelengths between 3000 A and 300 A (4 < or = h..omega.. < or = 40 eV) using a vertical dispersion plane. The storage ring provides a light flux intense and stable enough for rapid photoelectrical scanning of the spectra with a resolution of 0.03 A in first order. (AIP)

Design Study of an MBA Lattice for the Advanced Photon Source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Decker, Glenn

2014-11-02

Recent interest in ultra-low-emittance designs for storage-ring-based synchrotron light sources has spurred a focused design effort on a multi-bend achromat (MBA) storage ring replacement for the Advanced Photon Source (APS). The APS is relatively large (1104 m circumference) and, as such, an upgrade to a fourth-generation storage ring holds the potential for a two to three order of magnitude enhancement of X-ray brightness due to the approximate inverse cubic scaling of emittance with the number of dipole bend magnets.

ACCELERATORS: Preliminary application of turn-by-turn data analysis to the SSRF storage ring

NASA Astrophysics Data System (ADS)

Chen, Jian-Hui; Zhao, Zhen-Tang

2009-07-01

There is growing interest in utilizing the beam position monitor turn-by-turn (TBT) data to debug accelerators. TBT data can be used to determine the linear optics, coupled optics and nonlinear behaviors of the storage ring lattice. This is not only a useful complement to other methods of determining the linear optics such as LOCO, but also provides a possibility to uncover more hidden phenomena. In this paper, a preliminary application of a β function measurement to the SSRF storage ring is presented.

How to Reach a Thousand-Second in-Plane Polarization Lifetime with 0.97 - GeV / c Deuterons in a Storage Ring

DOE PAGES

Guidoboni, G.; Stephenson, E.; Andrianov, S.; ...

2016-07-28

Here, we observe a deuteron beam polarization lifetime near 1000 s in the horizontal plane of a magnetic storage ring (COSY). This long spin coherence time is maintained through a combination of beam bunching, electron cooling, sextupole field corrections, and the suppression of collective effects through beam current limits. This record lifetime is required for a storage ring search for an intrinsic electric dipole moment on the deuteron at a statistical sensitivity level approaching 10 -29 $e$ cm.

Dielectronic recombination experiments at the storage rings: From the present CSR to the future HIAF

NASA Astrophysics Data System (ADS)

Huang, Z. K.; Wen, W. Q.; Xu, X.; Wang, H. B.; Dou, L. J.; Chuai, X. Y.; Zhu, X. L.; Zhao, D. M.; Li, J.; Ma, X. M.; Mao, L. J.; Yang, J. C.; Yuan, Y. J.; Xu, W. Q.; Xie, L. Y.; Xu, T. H.; Yao, K.; Dong, C. Z.; Zhu, L. F.; Ma, X.

2017-10-01

Dielectronic recombination (DR) experiments of highly charged ions at the storage rings have been developed as a precision spectroscopic tool to investigate the atomic structure as well as nuclear properties of stable and unstable nuclei. The DR experiment on lithium-like argon ions was successfully performed at main Cooler Storage Ring (CSRm) at Heavy Ion Research Facility in Lanzhou (HIRFL) accelerator complex. The DR experiments on heavy highly charged ions and even radioactive ions are currently under preparation at the experimental Cooler Storage Ring (CSRe) at HIRFL. The current status of DR experiments at the CSRm and the preparation of the DR experiments at the CSRe are presented. In addition, an overview of DR experiments by employing an electron cooler and a separated ultra-cold electron target at the upcoming High Intensity heavy ion Accelerator Facility (HIAF) will be given.

Bruno Touschek: From Betatrons to Electron-Positron Colliders

NASA Astrophysics Data System (ADS)

Bernardini, Carlo; Pancheri, Giulia; Pellegrini, Claudio

Bruno Touschek's life as a physicist spanned the period from World War II to the 1970s. He was a key figure in the developments of electron-positron colliders and storage rings, and made important contributions to theoretical high energy physics. Storage rings, initially developed for high energy physics, are being widely used in many countries as synchrotron radiation sources and are a tool for research in physics, chemistry, biology, environmental sciences and cultural heritage studies. We describe Touschek's life in Austria, where he was born, in Germany, where he participated in the construction of a betatron during WWII, and in Italy, where he proposed and led to completion the first electron-positron storage ring in 1960, in Frascati. We highlight how his central European culture influenced his lifestyle and work, and his main contributions to physics, such as the discovery of the Touschek effect and beam instabilities in the larger storage ring ADONE.

Bruno Touschek: From Betatrons to Electron-Positron Colliders

NASA Astrophysics Data System (ADS)

Bernardini, Carlo; Pancheri, Giulia; Pellegrini, Claudio

Bruno Touschek’s life as a physicist spanned the period from World War II to the 1970s. He was a key figure in the developments of electron-positron colliders and storage rings, and made important contributions to theoretical high energy physics. Storage rings, initially developed for high energy physics, are being widely used in many countries as synchrotron radiation sources and are a tool for research in physics, chemistry, biology, environmental sciences and cultural heritage studies. We describe Touschek’s life in Austria, where he was born, in Germany, where he participated in the construction of a betatron during WWII, and in Italy, where he proposed and led to completion the first electron-positron storage ring in 1960, in Frascati. We highlight how his central European culture influenced his lifestyle and work, and his main contributions to physics, such as the discovery of the Touschek effect and beam instabilities in the larger storage ring ADONE.

High-energy accelerator for beams of heavy ions

DOEpatents

Martin, Ronald L.; Arnold, Richard C.

1978-01-01

An apparatus for accelerating heavy ions to high energies and directing the accelerated ions at a target comprises a source of singly ionized heavy ions of an element or compound of greater than 100 atomic mass units, means for accelerating the heavy ions, a storage ring for accumulating the accelerated heavy ions and switching means for switching the heavy ions from the storage ring to strike a target substantially simultaneously from a plurality of directions. In a particular embodiment the heavy ion that is accelerated is singly ionized hydrogen iodide. After acceleration, if the beam is of molecular ions, the ions are dissociated to leave an accelerated singly ionized atomic ion in a beam. Extraction of the beam may be accomplished by stripping all the electrons from the atomic ion to switch the beam from the storage ring by bending it in magnetic field of the storage ring.

Injection envelope matching in storage rings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Minty, M.G.; Spence, W.L.

1995-05-01

The shape and size of the transverse phase space injected into a storage ring can be deduced from turn-by-turn measurements of the transient behavior of the beam envelope in the ring. Envelope oscillations at 2 x the {beta}-tron frequency indicate the presence of a {beta}-mismatch, while envelope oscillations at the {beta}-tron frequency are the signature of a dispersion function mismatch. Experiments in injection optimization using synchrotron radiation imaging of the beam and a fast-gated camera at the SLC damping rings are reported.

Injection envelope matching in storage rings

NASA Astrophysics Data System (ADS)

Minty, M. G.; Spence, W. L.

1995-05-01

The shape and size of the transverse phase space injected into a storage ring can be deduced from turn-by-turn measurements of the transient behavior of the beam envelope in the ring. Envelope oscillations at 2 x the beta-tron frequency indicate the presence of a beta-mismatch, while envelope oscillations at the beta-tron frequency are the signature of a dispersion function mismatch. Experiments in injection optimization using synchrotron radiation imaging of the beam and a fast-gated camera at the SLC damping rings are reported.

MEMS tunable optical filter based on multi-ring resonator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dessalegn, Hailu, E-mail: hailudessalegn@yahoo.com, E-mail: tsrinu@ece.iisc.ernet.in; Srinivas, T., E-mail: hailudessalegn@yahoo.com, E-mail: tsrinu@ece.iisc.ernet.in

We propose a novel MEMS tunable optical filter with a flat-top pass band based on multi-ring resonator in an electrostatically actuated microcantilever for communication application. The filter is basically structured on a microcantilever beam and built in optical integrated ring resonator which is placed in one end of the beam to gain maximum stress on the resonator. Thus, when a DC voltage is applied, the beam will bend, that induces a stress and strain in the ring, which brings a change in refractive index and perimeter of the rings leading to change in the output spectrum shift, providing the tenabilitymore » as high as 0.68nm/μN and it is capable of tuning up to 1.7nm.« less

Status and outlook of the CRYRING@ESR project

NASA Astrophysics Data System (ADS)

Geithner, W.; Andelkovic, Z.; Beck, D.; Bräuning, H.; Bräuning-Demian, A.; Danared, H.; Dimopoulou, C.; Engström, M.; Fedotova, S.; Gorda, O.; Herfurth, F.; Hess, R.; Källberg, A.; Kleffner, C.; Kotovskiy, N.; Kraus, I.; Lestinsky, M.; Litvinov, S.; Nolden, F.; Reiter, A.; Sieber, T.; Steck, M.; Vorobyev, G.

2017-11-01

Once operational, CRYRING@ESR will store and decelerate ions delivered by the experimental storage ring ESR at energies well below those of ESR. In addition to that, CRYRING@ESR has an electron cooler operating with an ultracold electron beam, allowing to provide cooled ion beams for precision experiments. These ions will be delivered to a broad range of experiments presently in preparation; either in-ring or extracted to a dedicated beamline for experiments. An overview and status report of the installation and commissioning of the CRYRING-@ESR storage ring for highly charged ions at the GSI Helmholtzzentrum für Schwerionenforschung is presented. The installation of this storage ring started in 2014 and was completing end of 2016, when this publication was written.

Wave-Kinetic Simulations of the Nonlinear Generation of Electromagnetic VLF Waves through Velocity Ring Instabilities

NASA Astrophysics Data System (ADS)

Ganguli, G.; Crabtree, C. E.; Rudakov, L.; Mithaiwala, M.

2014-12-01

Velocity ring instabilities are a common naturally occuring magnetospheric phenomenon that can also be generated by man made ionospheric experiments. These instabilities are known to generate lower-hybrid waves, which generally cannot propagte out of the source region. However, nonlinear wave physics can convert these linearly driven electrostatic lower-hybrid waves into electromagnetic waves that can escape the source region. These nonlinearly generated waves can be an important source of VLF turbulence that controls the trapped electron lifetime in the radiation belts. We develop numerical solutions to the wave-kinetic equation in a periodic box including the effects of nonlinear (NL) scattering (nonlinear Landau damping) of Lower-hybrid waves giving the evolution of the wave-spectra in wavenumber space. Simultaneously we solve the particle diffusion equation of both the background plasma particles and the ring ions, due to both linear and nonlinear Landau resonances. At initial times for cold ring ions, an electrostatic beam mode is excited, while the kinetic mode is stable. As the instability progresses the ring ions heat, the beam mode is stabilized, and the kinetic mode destabilizes. When the amplitude of the waves becomes sufficient the lower-hybrid waves are scattered (by either nearly unmagnetized ions or magnetized electrons) into electromagnetic magnetosonic waves [Ganguli et al 2010]. The effect of NL scattering is to limit the amplitude of the waves, slowing down the quasilinear relaxation time and ultimately allowing more energy from the ring to be liberated into waves [Mithaiwala et al. 2011]. The effects of convection out of the instability region are modeled, additionally limiting the amplitude of the waves, allowing further energy to be liberated from the ring [Scales et al., 2012]. Results are compared to recent 3D PIC simulations [Winske and Duaghton 2012].

Analysis and correction of linear optics errors, and operational improvements in the Indus-2 storage ring

NASA Astrophysics Data System (ADS)

Husain, Riyasat; Ghodke, A. D.

2017-08-01

Estimation and correction of the optics errors in an operational storage ring is always vital to achieve the design performance. To achieve this task, the most suitable and widely used technique, called linear optics from closed orbit (LOCO) is used in almost all storage ring based synchrotron radiation sources. In this technique, based on the response matrix fit, errors in the quadrupole strengths, beam position monitor (BPM) gains, orbit corrector calibration factors etc. can be obtained. For correction of the optics, suitable changes in the quadrupole strengths can be applied through the driving currents of the quadrupole power supplies to achieve the desired optics. The LOCO code has been used at the Indus-2 storage ring for the first time. The estimation of linear beam optics errors and their correction to minimize the distortion of linear beam dynamical parameters by using the installed number of quadrupole power supplies is discussed. After the optics correction, the performance of the storage ring is improved in terms of better beam injection/accumulation, reduced beam loss during energy ramping, and improvement in beam lifetime. It is also useful in controlling the leakage in the orbit bump required for machine studies or for commissioning of new beamlines.

Quinoxaline-substituted chalcones as new inhibitors of breast cancer resistance protein ABCG2: polyspecificity at B-ring position

PubMed Central

Winter, Evelyn; Gozzi, Gustavo Jabor; Chiaradia-Delatorre, Louise Domeneghini; Daflon-Yunes, Nathalia; Terreux, Raphael; Gauthier, Charlotte; Mascarello, Alessandra; Leal, Paulo César; Cadena, Silvia M; Yunes, Rosendo Augusto; Nunes, Ricardo José; Creczynski-Pasa, Tania Beatriz; Di Pietro, Attilio

2014-01-01

A series of chalcones substituted by a quinoxaline unit at the B-ring were synthesized and tested as inhibitors of breast cancer resistance protein-mediated mitoxantrone efflux. These compounds appeared more efficient than analogs containing other B-ring substituents such as 2-naphthyl or 3,4-methylenedioxyphenyl while an intermediate inhibitory activity was obtained with a 1-naphthyl group. In all cases, two or three methoxy groups had to be present on the phenyl A-ring to produce a maximal inhibition. Molecular modeling indicated both electrostatic and steric positive contributions. A higher potency was observed when the 2-naphthyl or 3,4-methylenedioxyphenyl group was shifted to the A-ring and methoxy substituents were shifted to the phenyl B-ring, indicating preferences among polyspecificity of inhibition. PMID:24920885

Low emittance electron storage rings

NASA Astrophysics Data System (ADS)

Levichev, E. B.

2018-01-01

Low-emittance electron (positron) beams are essential for synchrotron light sources, linear collider damping rings, and circular Crab Waist colliders. In this review, the principles and methods of emittance minimization are discussed, prospects for developing relativistic electron storage rings with small beam phase volume are assessed, and problems related to emittance minimization are examined together with their possible solutions. The special features and engineering implementation aspects of various facilities are briefly reviewed.

Antiandrogenic steroidal sulfonyl heterocycles. Utility of electrostatic complementarity in defining bioisosteric sulfonyl heterocycles.

PubMed

Mallamo, J P; Pilling, G M; Wetzel, J R; Kowalczyk, P J; Bell, M R; Kullnig, R K; Batzold, F H; Juniewicz, P E; Winneker, R C; Luss, H R

1992-05-15

Complementarity of electrostatic potential surface maps was utilized in defining bioisosteric steroidal androgen receptor antagonists. Semiempirical and ab initio level calculations performed on a series of methanesulfonyl heterocycles indicated the requirement for a partial negative charge at the heteroatom attached to C-3 of the steroid nucleus to attain androgen receptor affinity. Synthesis and testing of six heterocycle A-ring-fused dihydroethisterone derivatives support this hypothesis, and we have identified two new androgen receptor antagonists of this class.

Protonmotive force: development of electrostatic drivers for synthetic molecular motors.

PubMed

Crowley, James D; Steele, Ian M; Bosnich, Brice

2006-12-04

Ferrocene has been investigated as a platform for developing protonmotive electrostatic drivers for molecular motors. When two 3-pyridine groups are substituted to the (rapidly rotating) cyclopentadienyl (Cp) rings of ferrocene, one on each Cp, it is shown that the (Cp) eclipsed, pi-stacked rotameric conformation is preferred both in solution and in the solid state. Upon quaternization of both of the pyridines substituents, either by protonation or by alkylation, it is shown that the preferred rotameric conformation is one where the pyridinium groups are rotated away from the fully pi-stacked conformation. Electrostatic calculations indicate that the rotation is caused by the electrostatic repulsion between the charges. Consistently, when the pi-stacking energy is increased pi-stacked population increases, and conversely when the electrostatic repulsion is increased pi-stacked population is decreased. This work serves to provide an approximate estimate of the amount of torque that the electrostatically driven ferrocene platform can generate when incorporated into a molecular motor. The overall conclusion is that the electrostatic interaction energy between dicationic ferrocene dipyridyl systems is similar to the pi-stacking interaction energy and, consequently, at least tricationic systems are required to fully uncouple the pi-stacked pyridine substituents.

Picosecond, tunable, high-brightness hard x-ray inverse Compton source at Duke storage ring

NASA Astrophysics Data System (ADS)

Litvinenko, Vladimir N.; Wu, Ying; Burnham, Bentley; Barnett, Genevieve A.; Madey, John M. J.

1995-09-01

We suggest a state-of-the art x-ray source using a compact electron storage ring with modest energy (less than 1 GeV) and a high power mm-wave as an undulator. A source of this type has x-ray energies and brightness comparable with third generation synchrotron light sources while it can be very compact and fit in a small university or industrial laboratory or hospital. We propose to operate an isochronous mm-wave FEL and a hard x-ray inverse Compton source at the Duke storage ring to test this concept. Resonant FEL conditions for the mm- wave will be provided by the off-axis interaction with an electromagnetic wave. A special optical resonator with holes for the e-beam is proposed for pumping a hard x-ray inverse Compton source with very high brightness. Simulation results of mm-wave FEL operation of the Duke storage ring are discussed. Expected performance of mm-wave FEL and hard x-ray inverse Compton source are presented.

High-accuracy mass spectrometry for fundamental studies.

PubMed

Kluge, H-Jürgen

2010-01-01

Mass spectrometry for fundamental studies in metrology and atomic, nuclear and particle physics requires extreme sensitivity and efficiency as well as ultimate resolving power and accuracy. An overview will be given on the global status of high-accuracy mass spectrometry for fundamental physics and metrology. Three quite different examples of modern mass spectrometric experiments in physics are presented: (i) the retardation spectrometer KATRIN at the Forschungszentrum Karlsruhe, employing electrostatic filtering in combination with magnetic-adiabatic collimation-the biggest mass spectrometer for determining the smallest mass, i.e. the mass of the electron anti-neutrino, (ii) the Experimental Cooler-Storage Ring at GSI-a mass spectrometer of medium size, relative to other accelerators, for determining medium-heavy masses and (iii) the Penning trap facility, SHIPTRAP, at GSI-the smallest mass spectrometer for determining the heaviest masses, those of super-heavy elements. Finally, a short view into the future will address the GSI project HITRAP at GSI for fundamental studies with highly-charged ions.

The Storage Ring Proton EDM Experiment

NASA Astrophysics Data System (ADS)

Semertzidis, Yannis; Storage Ring Proton EDM Collaboration

2014-09-01

The storage ring pEDM experiment utilizes an all-electric storage ring to store ~1011 longitudinally polarized protons simultaneously in clock-wise and counter-clock-wise directions for 103 seconds. The radial E-field acts on the proton EDM for the duration of the storage time to precess its spin in the vertical plane. The ring lattice is optimized to reduce intra-beam scattering, increase the statistical sensitivity and reduce the systematic errors of the method. The main systematic error is a net radial B-field integrated around the ring causing an EDM-like vertical spin precession. The counter-rotating beams sense this integrated field and are vertically shifted by an amount, which depends on the strength of the vertical focusing in the ring, thus creating a radial B-field. Modulating the vertical focusing at 10 kHz makes possible the detection of this radial B-field by a SQUID-magnetometer (SQUID-based BPM). For a total number of n SQUID-based BPMs distributed around the ring the effectiveness of the method is limited to the N = n /2 harmonic of the background radial B-field due to the Nyquist sampling theorem limit. This limitation establishes the requirement to reduce the maximum radial B-field to 0.1-1 nT everywhere around the ring by layers of mu-metal and aluminum vacuum tube. The metho's sensitivity is 10-29 e .cm , more than three orders of magnitude better than the present neutron EDM experimental limit, making it sensitive to SUSY-like new physics mass scale up to 300 TeV.

Single mask, simple structure micro rotational motor driven by electrostatic comb-drive actuators

NASA Astrophysics Data System (ADS)

Pham, Phuc Hong; Viet Dao, Dzung; Dang, Lam Bao; Sugiyama, Susumu

2012-01-01

We report a design and fabrication of a new micro rotational motor (MRM) using silicon micromachining technology with the overall diameter of 2.4 mm. This motor utilizes four silicon electrostatic comb-drive actuators to drive the outer ring (or rotor) through ratchet teeth. The novel design of the anti-reverse structure helps us to overcome the gap problem after deep reactive ion etching of silicon. The MRM was fabricated by using silicon on insulator wafer with the thickness of the device layer being 30 µm and one mask only. The motor was successfully tested for performance. It was driven by periodic voltage with different frequencies ranging from 1 to 50 Hz. The angular velocity of the outer ratchet ring was proportional to the frequency. Moreover, when the driving frequency is lower than 30 Hz, the experiment results perfectly match the theoretical calculation.

Dose estimates for the 1104 m APS storage ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moe, H.J.

1989-06-01

The estimated dose equivalent rates outside the shielded storage ring, and the estimated annual dose equivalent to members of the public due to direct radiation and skyshine from the ring, have been recalculated. The previous estimates found in LS-84 (MOE 87) and cited in the 1987 Conceptual Design Report of the APS (ANL 87) required revision because of changes in the ring circumference and in the proposed location of the ring with respect to the nearest site boundary. The values assumed for the neutron quality factors were also overestimated (by a factor of 2) in the previous computation, and themore » correct values have been used for this estimate. The methodology used to compute dose and dose rate from the storage ring is the same as that used in LS-90 (MOE 87a). The calculations assumed 80 cm thick walls of ordinary concrete (or the shielding equivalent of this) and a roof thickness of 1 meter of ordinary concrete. The circumference of the ring was increased to 1,104 m, and the closest distance to the boundary was taken as 140 m. The recalculation of the skyshine component used the same methodology as that used in LS-84.« less

Perspectives on micropole undulators in synchrotron radiation technology

NASA Astrophysics Data System (ADS)

Tatchyn, Roman; Csonka, Paul; Toor, Arthur

1989-07-01

Micropole undulators promise to advance synchrotron radiation (SR) technology in two distinct ways. The first is in the development of economical, low-energy storage rings, or linacs, as soft x-ray sources, and the second is in the opening up of gamma-ray spectral ranges on high-energy storage rings. In this paper the promise and current status of micropole undulator (MPU) technology are discussed, and a review of some practical obstacles to the implementation of MPU's on present-day storage rings is given. Some successful results of recent performance measurements of micropole undulators on the Lawrence Livermore National Laboratory linac are briefly summarized.

Data Access Based on a Guide Map of the Underwater Wireless Sensor Network

PubMed Central

Wei, Zhengxian; Song, Min; Yin, Guisheng; Wang, Hongbin; Cheng, Albert M. K.

2017-01-01

Underwater wireless sensor networks (UWSNs) represent an area of increasing research interest, as data storage, discovery, and query of UWSNs are always challenging issues. In this paper, a data access based on a guide map (DAGM) method is proposed for UWSNs. In DAGM, the metadata describes the abstracts of data content and the storage location. The center ring is composed of nodes according to the shortest average data query path in the network in order to store the metadata, and the data guide map organizes, diffuses and synchronizes the metadata in the center ring, providing the most time-saving and energy-efficient data query service for the user. For this method, firstly the data is stored in the UWSN. The storage node is determined, the data is transmitted from the sensor node (data generation source) to the storage node, and the metadata is generated for it. Then, the metadata is sent to the center ring node that is the nearest to the storage node and the data guide map organizes the metadata, diffusing and synchronizing it to the other center ring nodes. Finally, when there is query data in any user node, the data guide map will select a center ring node nearest to the user to process the query sentence, and based on the shortest transmission delay and lowest energy consumption, data transmission routing is generated according to the storage location abstract in the metadata. Hence, specific application data transmission from the storage node to the user is completed. The simulation results demonstrate that DAGM has advantages with respect to data access time and network energy consumption. PMID:29039757

Data Access Based on a Guide Map of the Underwater Wireless Sensor Network.

PubMed

Wei, Zhengxian; Song, Min; Yin, Guisheng; Song, Houbing; Wang, Hongbin; Ma, Xuefei; Cheng, Albert M K

2017-10-17

Underwater wireless sensor networks (UWSNs) represent an area of increasing research interest, as data storage, discovery, and query of UWSNs are always challenging issues. In this paper, a data access based on a guide map (DAGM) method is proposed for UWSNs. In DAGM, the metadata describes the abstracts of data content and the storage location. The center ring is composed of nodes according to the shortest average data query path in the network in order to store the metadata, and the data guide map organizes, diffuses and synchronizes the metadata in the center ring, providing the most time-saving and energy-efficient data query service for the user. For this method, firstly the data is stored in the UWSN. The storage node is determined, the data is transmitted from the sensor node (data generation source) to the storage node, and the metadata is generated for it. Then, the metadata is sent to the center ring node that is the nearest to the storage node and the data guide map organizes the metadata, diffusing and synchronizing it to the other center ring nodes. Finally, when there is query data in any user node, the data guide map will select a center ring node nearest to the user to process the query sentence, and based on the shortest transmission delay and lowest energy consumption, data transmission routing is generated according to the storage location abstract in the metadata. Hence, specific application data transmission from the storage node to the user is completed. The simulation results demonstrate that DAGM has advantages with respect to data access time and network energy consumption.

Compact Storage Ring for an X-Ray Source

NASA Astrophysics Data System (ADS)

Ovchinnikova, L.; Shvedunov, V.; Ivanov, K.

2017-12-01

We propose a new design of a compact storage ring for a source of X-ray radiation on the basis of reverse Thomson scattering of laser radiation by electrons with the energy of 35-50 MeV, which has small number of optical elements and a significant clear space for the placement of a beam injection-extraction system and a RF cavity. The original laser cavity layout has been considered. The ring dynamic aperture after correction of chromaticity and a second-order dispersion function is sufficient for the injection and stable circulation of an electron bunch in the ring.

Burton Richter, Storage Rings, and the J/psi Particle

Science.gov Websites

[SLAC's] Technical Director, [Richter] became Director ... from 1984 through 1999. During his tenure, SLAC Limits of Quantum Electro-dynamics, DOE Technical Report, June 1959 Design Considerations for High Energy Electron -- Positron Storage Rings, DOE Technical Report, November 1966 Inclusive Yields of pi+, pi-, K

Application of Ring-Closing Metathesis to Grb2 SH3 Domain-Binding Peptides | Center for Cancer Research

Cancer.gov

In silico-generated hypothetical interactions of a ring-closing metathesis-macrocylized peptide bound to the amino terminal SH3 domain of the growth factor receptor bound protein 2 (Grb2). The complex was derived from the NMR solution structure of the bound parent peptide, Ac-V-P-P-P-V-P-P-R-R-R-amide (Protein Data Bank: 3GBQ). The protein surface is shown as electrostatic

Interaction of the BKCa channel gating ring with dendrotoxins

PubMed Central

Takacs, Zoltan; Imredy, John P; Bingham, Jon-Paul; Zhorov, Boris S; Moczydlowski, Edward G

2014-01-01

Two classes of small homologous basic proteins, mamba snake dendrotoxins (DTX) and bovine pancreatic trypsin inhibitor (BPTI), block the large conductance Ca2+-activated K+ channel (BKCa, KCa1.1) by production of discrete subconductance events when added to the intracellular side of the membrane. This toxin-channel interaction is unlikely to be pharmacologically relevant to the action of mamba venom, but as a fortuitous ligand-protein interaction, it has certain biophysical implications for the mechanism of BKCa channel gating. In this work we examined the subconductance behavior of 9 natural dendrotoxin homologs and 6 charge neutralization mutants of δ-dendrotoxin in the context of current structural information on the intracellular gating ring domain of the BKCa channel. Calculation of an electrostatic surface map of the BKCa gating ring based on the Poisson-Boltzmann equation reveals a predominantly electronegative surface due to an abundance of solvent-accessible side chains of negatively charged amino acids. Available structure-activity information suggests that cationic DTX/BPTI molecules bind by electrostatic attraction to site(s) on the gating ring located in or near the cytoplasmic side portals where the inactivation ball peptide of the β2 subunit enters to block the channel. Such an interaction may decrease the apparent unitary conductance by altering the dynamic balance of open versus closed states of BKCa channel activation gating. PMID:25483585

Absorption spectrum of the firefly luciferin anion isolated in vacuo.

PubMed

Støchkel, Kristian; Milne, Bruce F; Brøndsted Nielsen, Steen

2011-03-24

The excited-state physics of the firefly luciferin anion depends on its chemical environment, and it is therefore important to establish the intrinsic behavior of the bare ion. Here we report electronic absorption spectra of the anion isolated in vacuo obtained at an electrostatic ion storage ring and an accelerator mass spectrometer where ionic dissociation is monitored on a long time scale (from 33 μs and up to 3 ms) and on a short time scale (0-3 μs), respectively. In the ring experiment the yield of all neutrals (mainly CO(2)) as a function of wavelength was measured whereas in the single pass experiment, the abundance of daughter ions formed after loss of CO(2) was recorded to provide action spectra. We find maxima at 535 and 265 nm, and that the band shape is largely determined by the sampling time interval, which is due to the kinetics of the dissociation process. Calculations at the TD-B3LYP/TZVPP++ level predict maximum absorption at 533 and 275 nm for the carboxylate isomer in excellent agreement with the experimental findings. The phenolate isomer lies higher in energy by 0.22 eV, and also its absorption maximum is calculated to be at 463 nm, which is far away from the experimental value. Our data serve to benchmark future theoretical models for bioluminescence from fireflies.

Electrostatic Self-Assembly Enabling Integrated Bulk and Interfacial Sodium Storage in 3D Titania-Graphene Hybrid

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xu, Gui-Liang; Xiao, Lisong; Sheng, Tian

Room temperature sodium-ion batteries have attracted increased attention for energy storage due to the natural abundance of sodium. However, it remains a huge challenge to develop versatile electrode materials with favorable properties, which requires smart structure design and good mechanistic understanding. Herein, we reported a general and scalable approach to synthesize 3D titania-graphene hybrid via electrostatic-interaction-induced self-assembly. Synchrotron X-ray probe, transmission electron microscopy and computational modeling revealed that the strong interaction between Titania and graphene through comparably strong van-der-Waals forces not only facilitates bulk Na+ intercalation but also enhances the interfacial sodium storage. As a result, the titania-graphene hybrid exhibitsmore » exceptional long-term cycle stability up to 5000 cycles, and ultrahigh rate capability up to 20 C for sodium storage. Furthermore, density function theory calculation indicated that the interfacial Li+, K+, Mg2+ and Al3+ storage can be enhanced as well. The proposed general strategy opens up new avenues to create versatile materials for advanced battery systems.« less

Electrostatic Self-Assembly Enabling Integrated Bulk and Interfacial Sodium Storage in 3D Titania-Graphene Hybrid.

PubMed

Xu, Gui-Liang; Xiao, Lisong; Sheng, Tian; Liu, Jianzhao; Hu, Yi-Xin; Ma, Tianyuan; Amine, Rachid; Xie, Yingying; Zhang, Xiaoyi; Liu, Yuzi; Ren, Yang; Sun, Cheng-Jun; Heald, Steve M; Kovacevic, Jasmina; Sehlleier, Yee Hwa; Schulz, Christof; Mattis, Wenjuan Liu; Sun, Shi-Gang; Wiggers, Hartmut; Chen, Zonghai; Amine, Khalil

2018-01-10

Room-temperature sodium-ion batteries have attracted increased attention for energy storage due to the natural abundance of sodium. However, it remains a huge challenge to develop versatile electrode materials with favorable properties, which requires smart structure design and good mechanistic understanding. Herein, we reported a general and scalable approach to synthesize three-dimensional (3D) titania-graphene hybrid via electrostatic-interaction-induced self-assembly. Synchrotron X-ray probe, transmission electron microscopy, and computational modeling revealed that the strong interaction between titania and graphene through comparably strong van der Waals forces not only facilitates bulk Na + intercalation but also enhances the interfacial sodium storage. As a result, the titania-graphene hybrid exhibits exceptional long-term cycle stability up to 5000 cycles, and ultrahigh rate capability up to 20 C for sodium storage. Furthermore, density function theory calculation indicated that the interfacial Li + , K + , Mg 2+, and Al 3+ storage can be enhanced as well. The proposed general strategy opens up new avenues to create versatile materials for advanced battery systems.

Don't kill canaries! Introducing a new test device to assess the electrostatic risk potential to photomasks

NASA Astrophysics Data System (ADS)

Sebald, Thomas

2008-10-01

Electrostatic protection is an issue for all masks, whether during mask production, shipping, storage, handling or inspection and exposure. Up to now, only manual electrostatic field measurements, or expensive and elaborate analyses with Canary reticles have given hints about the risks of pattern damage by ESD events. A new test device is being introduced, which consists of electrostatic field sensors, integrated INSIDE a closed fused quartz housing which has the outside dimensions of a 6 inch mask. This device can be handled and used like a normal 6 inch reticle. It can be handled and processed while recording the electrostatic charges on the chrome patterns created by friction or field induction just as a reticle would "see" during normal processing.

Dust Charging in Saturn's Rings: Observations and Theory

NASA Astrophysics Data System (ADS)

Horanyi, M.

2008-12-01

Saturn's rings show a variety of dusty plasma processes. The electrostatic charging and subsequent orbital dynamics of small grains can establish their size and spatial distributions, for example. Simultaneously, dust can alter the composition, density and temperature of the plasma surrounding it. The dynamics of charged dust particles can be surprisingly complex and fundamentally different from the well understood limits of gravitationally dominated motions of neutral particles or the adiabatic motion of electrons and ions in electromagnetic fields that dominate gravity. This talk will focus on recent Cassini observations at Saturn that are best explained by theories describing the effects of the magnetospheric fields and plasmas on the rings. As our best examples, we will discuss the physics describing the large-scale structure of the E-ring, and the formation of 'spokes' over the dense rings of Saturn.

Control of degreening in postharvest green sour citrus fruit by electrostatic atomized water particles.

PubMed

Yamauchi, Naoki; Takamura, Kohtaro; Shigyo, Masayoshi; Migita, Catharina Taiko; Masuda, Yukihiro; Maekawa, Tetsuya

2014-08-01

The effect of electrostatic atomized water particles (EAWP) on degreening of green sour citrus fruit during storage was determined. Superoxide anion and hydroxyl radicals included in EAWP were present on the surface of the fruit peel after the treatment. Hydrogen peroxide was formed from EAWP in an aqueous solution, which could indicate that a hydroxyl radical of EAWP turns to hydrogen peroxide in the fruit flavedo as well as in the aqueous solution. EAWP treatment effectively suppressed the degreening of green yuzu and Nagato-yuzukichi fruits during storage at 20°C. The enhancement in K+ ion leakage of both EAWP-treated fruits reduced in comparison with the control. In spite of EAWP treatment, total peroxide level in both fruits showed almost no changes during storage, suggesting that hydrogen peroxide formed by EAWP treatment could stimulate the activation of hydrogen peroxide scavenging system and control degreening of these fruits during storage. Copyright © 2014 Elsevier Ltd. All rights reserved.

Mechanical capacitor

NASA Technical Reports Server (NTRS)

Kirk, J. A.; Studer, P. A.; Evans, H. E.

1976-01-01

A new energy storage system (the mechanical capacitor), using a spokeless magnetically levitated composite ring rotor, is described and design formulas for sizing the components are presented. This new system is configured around a permanent magnet (flux biased) suspension which has active servo control in the radial direction and passive control in the axial direction. The storage ring is used as a moving rotor and electronic commutation of the stationary armature coils is proposed. There is no mechanical contact with the rotating spokeless ring; therefore, long life and near zero rundown losses are projected. A 7-kW h system is sized to demonstrate feasibility. A literature review of flywheel energy storage systems is also presented and general formulas are developed for comparing rotor geometries.

MULTI-OBJECTIVE ONLINE OPTIMIZATION OF BEAM LIFETIME AT APS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sun, Yipeng

In this paper, online optimization of beam lifetime at the APS (Advanced Photon Source) storage ring is presented. A general genetic algorithm (GA) is developed and employed for some online optimizations in the APS storage ring. Sextupole magnets in 40 sectors of the APS storage ring are employed as variables for the online nonlinear beam dynamics optimization. The algorithm employs several optimization objectives and is designed to run with topup mode or beam current decay mode. Up to 50\\% improvement of beam lifetime is demonstrated, without affecting the transverse beam sizes and other relevant parameters. In some cases, the top-upmore » injection efficiency is also improved.« less

National Synchrotron Light Source annual report 1991

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hulbert, S.L.; Lazarz, N.M.

1992-04-01

This report discusses the following research conducted at NSLS: atomic and molecular science; energy dispersive diffraction; lithography, microscopy and tomography; nuclear physics; UV photoemission and surface science; x-ray absorption spectroscopy; x-ray scattering and crystallography; x-ray topography; workshop on surface structure; workshop on electronic and chemical phenomena at surfaces; workshop on imaging; UV FEL machine reviews; VUV machine operations; VUV beamline operations; VUV storage ring parameters; x-ray machine operations; x-ray beamline operations; x-ray storage ring parameters; superconducting x-ray lithography source; SXLS storage ring parameters; the accelerator test facility; proposed UV-FEL user facility at the NSLS; global orbit feedback systems; and NSLSmore » computer system.« less

A method for simultaneous linear optics and coupling correction for storage rings with turn-by-turn beam position monitor data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Xi; Huang, Xiaobiao

2016-05-13

Here, we propose a method to simultaneously correct linear optics errors and linear coupling for storage rings using turn-by-turn (TbT) beam position monitor (BPM) data. The independent component analysis (ICA) method is used to isolate the betatron normal modes from the measured TbT BPM data. The betatron amplitudes and phase advances of the projections of the normal modes on the horizontal and vertical planes are then extracted, which, combined with dispersion measurement, are used to fit the lattice model. The fitting results are used for lattice correction. Finally, the method has been successfully demonstrated on the NSLS-II storage ring.

A method for simultaneous linear optics and coupling correction for storage rings with turn-by-turn beam position monitor data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Xi; Huang, Xiaobiao

2016-08-01

We propose a method to simultaneously correct linear optics errors and linear coupling for storage rings using turn-by-turn (TbT) beam position monitor (BPM) data. The independent component analysis (ICA) method is used to isolate the betatron normal modes from the measured TbT BPM data. The betatron amplitudes and phase advances of the projections of the normal modes on the horizontal and vertical planes are then extracted, which, combined with dispersion measurement, are used to fit the lattice model. Furthermore, the fitting results are used for lattice correction. Our method has been successfully demonstrated on the NSLS-II storage ring.

A method for simultaneous linear optics and coupling correction for storage rings with turn-by-turn beam position monitor data

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, Xi; Huang, Xiaobiao

2016-08-01

We propose a method to simultaneously correct linear optics errors and linear coupling for storage rings using turn-by-turn (TbT) beam position monitor (BPM) data. The independent component analysis (ICA) method is used to isolate the betatron normal modes from the measured TbT BPM data. The betatron amplitudes and phase advances of the projections of the normal modes on the horizontal and vertical planes are then extracted, which, combined with dispersion measurement, are used to fit the lattice model. The fitting results are used for lattice correction. The method has been successfully demonstrated on the NSLS-II storage ring.

NSLS-II storage ring insertion device and front-end commissioning and operation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, G., E-mail: gwang@bnl.gov; Shaftan, T.; Amundsen, C.

The National Synchrotron Light Source II (NSLS-II) is a state of the art 3 GeV third generation light source at Brookhaven National Laboratory. During spring/ summer of 2014, the storage ring was commissioned up to 50 mA without insertion devices. In the fall of 2014, we began commissioning of the project beamlines, which included seven insertion devices on six ID ports. Beamlines IXS, HXN, CSX-1, CSX-2, CHX, SRX, and XPD-1 consist of elliptically polarized undulator (EPU), damping wigglers (DW) and in-vacuum undulators (IVU) covering from VUV to hard x-ray range. In this paper, experience with commissioning and operation is discussed.more » We focus on reaching storage ring performance with IDs, including injection, design emittance, compensation of orbit distortions caused by ID residual field, source point stability, beam alignment and tools for control, monitoring and protection of the ring chambers from ID radiation.« less

Colliding or co-rotating ion beams in storage rings for EDM search

NASA Astrophysics Data System (ADS)

Koop, I. A.

2015-11-01

A new approach to search for and measure the electric dipole moment (EDM) of the proton, deuteron and some other light nuclei is presented. The idea of the method is to store two ion beams, circulating with different velocities, in a storage ring with crossed electric and magnetic guiding fields. One beam is polarized and its EDM is measured using the so-called ‘frozen spin’ method. The second beam, which is unpolarized, is used as a co-magnetometer, sensitive to the radial component of the ring’s magnetic field. The particle’s magnetic dipole moment (MDM) couples to the radial magnetic field and mimics the EDM signal. Measuring the relative vertical orbit separation of the two beams, caused by the presence of the radial magnetic field, one can control the unwanted MDM spin precession. Examples of the parameters for EDM storage rings for protons and other species of ions are presented. The use of crossed electric and magnetic fields helps to reduce the size of the ring by a factor of 10-20. We show that the bending radius of such an EDM storage ring could be about 2-3 m. Finally, a new method of increasing the spin coherence time, the so-called ‘spin wheel’, is proposed and its applicability to the EDM search is discussed.

Tree- Rings Link Climate and Carbon Storage in a Northern Mixed Hardwood Forest

NASA Astrophysics Data System (ADS)

Chiriboga, A.

2007-12-01

The terrestrial biosphere is a variable sink for atmospheric carbon dioxide. It is important to understand how carbon storage in trees is affected by natural climate variability to better characterize the sink. Quantifying the sensitivity of forest carbon storage to climate will improve carbon budgets and have implications for forest management practices. Here we explore how climate variability affects the ability of a northern mixed hardwood forest in Michigan to sequester atmospheric carbon dioxide in woody tissues. This site is ideal for studies of carbon sequestration; The University of Michigan Biological Station is an Ameriflux site, and has detailed meteorological and biometric records, as well as CO2 flux data. We have produced an 82- year aspen (Populus grandidentata) tree-ring chronology for this site, and measured ring widths at several heights up the bole. These measurements were used to estimate annual wood volume, which represents carbon allocated to aboveground carbon stores. Standard dendroclimatological techniques are used to identify environmental factors (e.g. temperature or precipitation) that drive tree-ring increment variability in the past century, and therefore annual carbon storage in this forest. Preliminary results show that marker years within the tree- ring chronology correspond with years that have cold spring temperatures. This suggests that trees at this site are temperature sensitive.

Beam Loss Measurements at the Los Alamos Proton Storage Ring

NASA Astrophysics Data System (ADS)

Spickermann, Thomas

2005-06-01

During normal operation the Los Alamos Proton Storage Ring (PSR) accumulates up to 4ṡ1013 protons over 625μs with a repetition rate of 20 Hz, corresponding to a current of 125μA to the Lujan Neutron Science Center. Beam losses in the ring as well as in the extraction beam line and the subsequent activation of material are a limiting factor at these currents. Careful tuning of injection, ring and extraction line is paramount to limiting losses to acceptable levels. Losses are typically not uniform around the ring, but occur in significantly higher levels in certain "hot spots". Here I will report on losses related to the stripper foil which are the dominant source of losses in the ring. First results of a comparison with simulations will also be presented.

Nitrile O-ring Cracking: A Case of Vacuum Flange O-ring Failures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dees, Craig

2016-07-01

A review of recent nitrile O-ring failures in ISO-KF vacuum flange connections in glovebox applications is presented. An investigation of a single “isolated” o-ring failure leads to the discovery of cracked nitrile o-rings in a glovebox atmospheric control unit. The initial cause of the o-ring failure is attributed to ozone degradation. However, additional investigation reveals nitrile o-ring cracking on multiple gloveboxes and general purpose piping, roughly 85% of the nitrile o-rings removed for inspection show evidence of visible cracking after being in service for 18 months or less. The results of material testing and ambient air testing is presented, elevatedmore » ozone levels are not found. The contributing factors of o-ring failure, including nitrile air sensitivity, inadequate storage practices, and poor installation techniques, are discussed. A discussion of nitrile o-ring material properties, the benefits and limitations, and alternate materials are discussed. Considerations for o-ring material selection, purchasing, storage, and installation are presented in the context of lessons learned from the nitrile o-ring cracking investigation. This paper can be presented in 20 minutes and does not require special accommodations or special audio visual devices.« less

An analog RF gap voltage regulation system for the Advanced Photon Source storage ring.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Horan, D.

1999-04-13

An analog rf gap voltage regulation system has been designed and built at Argonne National Laboratory to maintain constant total storage ring rf gap voltage, independent of beam loading and cavity tuning effects. The design uses feedback control of the klystron mod-anode voltage to vary the amount of rf power fed to the storage ring cavities. The system consists of two independent feedback loops, each regulating the combined rf gap voltages of eight storage ring cavities by varying the output power of either one or two rf stations, depending on the mode of operation. It provides full operator control andmore » permissive logic to permit feedback control of the rf system output power only if proper conditions are met. The feedback system uses envelope-detected cavity field probe outputs as the feedback signal. Two different methods of combining the individual field probe signals were used to generate a relative DC level representing one-half of the total storage ring rf voltage, an envelope-detected vector sum of the field probe rf signals, and the DC sum of individual field probe envelope detector outputs. The merits of both methods are discussed. The klystron high-voltage power supply (HVPS) units are fitted with an analog interface for external control of the mod-anode voltage level, using a four-quadrant analog multiplier to modulate the HVPS mod-anode voltage regulator set-point in response to feedback system commands.« less

Analysis of Methods to Excite Head-Tail Motion Within the Cornell Electron Storage Ring

NASA Astrophysics Data System (ADS)

Gendler, Naomi; Billing, Mike; Shanks, Jim

The main accelerator complex at Cornell consists of two rings around which electrons and positrons move: the synchrotron, where the particles are accelerated to 5 GeV, and the Storage Ring, where the particles circulate a ta Þxed energy, guided by quadrupole and dipole magnets, with a steady energy due to a sinusoidal voltage source. Keeping the beam stable in the Storage Ring is crucial for its lifetime. A long-lasting, invariable beam means more accurate experiments, as well as brighter, more focused X-rays for use in the Cornell High Energy Synchrotron Source (CHESS). The stability of the electron and positron beams in the Cornell Electron Storage Ring (CESR) is important for the development of accelerators and for usage of the beam in X-ray science and accelerator physics. Bunch oscillations tend to enlarge the beam's cross section, making it less stable. We believe that one such oscillation is ``head-tail motion,'' where the bunch rocks back and forth on a pivot located at the central particle. In this project, we write a simulation of the bunch that induces head-tail motion with a vertical driver. We also excite this motion physically in the storage ring, and observe a deÞnite head-tail signal. In the experiment, we saw a deÞnite persistence of the drive-damp signal within a small band around the head-tail frequency, indicating that the head-tail frequency is a natural vertical mode of the bunch that was being excited. The signal seen in the experiment matched the signal seen in the simulation to within an order of magnitude.

Characteristics of ring-cusp discharge chambers

NASA Technical Reports Server (NTRS)

Matossian, J. N.; Beattie, J. R.

1991-01-01

Measurements have been obtained for the operating characteristics of a 30 cm diameter ring-cusp ion thruster (RCIT), quantitatively comparing its performance parameters to those of a divergent-field J-series cluster of the same size. The high level of performance established for the RCIT is due to its maintenance of both a higher primary-electron population and Maxwellian-electron temperature, as the beam-ion production cost is reduced to its baseline value. Ion losses to the discharge-chamber walls can be reduced by an applied electrostatic field.

Beam vacuum system of Brookhaven`s muon storage ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hseuth, H.C.; Snydstrup, L.; Mapes, M.

1995-11-01

A storage ring with a circumference of 45 m is being built at Brookhaven to measure the g-2 value of the muons to an accuracy of 0.35 ppm.. The beam vacuum system of the storage ring will operate at 10{sup -7} Torr and has to be completely non-magnetic. It consists of twelve sector chambers. The chambers are constructed of aluminum and are approximately 3.5 m in length with a rectangular cross-section of 16.5 cm high by 45 cm at the widest point. The design features, fabrication techniques and cleaning methods for these chambers are described. The beam vacuum system willmore » be pumped by forty eight non-magnetic distributed ion pumps with a total pumping speed of over 2000 {ell}/sec. Monte Carlo simulations of the pressure distribution in the muon storage region are presented.« less

Electrostatic and conventional spraying of alginate-based edible coating with natural antimicrobials for preserving fresh strawberry quality

USDA-ARS?s Scientific Manuscript database

Microbial contamination and mold growth are common causes of strawberries deterioration during storage. The growing need for extending shelf-life while enhancing the overall quality of perishable fruits has generated increasing interest in the development of novel storage technologies. This study us...

ELECTROSTATIC MEMORY SYSTEM

DOEpatents

Chu, J.C.

1958-09-23

An improved electrostatic memory system is de scribed fer a digital computer wherein a plarality of storage tubes are adapted to operate in either of two possible modes. According to the present irvention, duplicate storage tubes are provided fur each denominational order of the several binary digits. A single discriminator system is provided between corresponding duplicate tubes to determine the character of the infurmation stored in each. If either tube produces the selected type signal, corresponding to binazy "1" in the preferred embodiment, a "1" is regenerated in both tubes. In one mode of operation each bit of information is stored in two corresponding tubes, while in the other mode of operation each bit is stored in only one tube in the conventional manner.

Corrections for a constant radial magnetic field in the muon \\varvec{g}-2 and electric-dipole-moment experiments in storage rings

NASA Astrophysics Data System (ADS)

Silenko, Alexander J.

2017-10-01

We calculate the corrections for constant radial magnetic field in muon {g}-2 and electric-dipole-moment experiments in storage rings. While the correction is negligible for the current generation of {g}-2 experiments, it affects the upcoming muon electric-dipole-moment experiment at Fermilab.

Loss-free method of charging accumulator rings

DOEpatents

Maschke, Alfred W.

1979-01-01

A method for the production of high current pulses of heavy ions having an atomic weight greater than 100. Also a linear accelerator based apparatus for carrying out said method. Pulses formed by the method of the subject invention are suitable for storage in a storage ring. The accumulated pulses may be used in inertial fusion apparatus.

National Synchrotron Light Source annual report 1991. Volume 1, October 1, 1990--September 30, 1991

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hulbert, S.L.; Lazarz, N.M.

1992-04-01

This report discusses the following research conducted at NSLS: atomic and molecular science; energy dispersive diffraction; lithography, microscopy and tomography; nuclear physics; UV photoemission and surface science; x-ray absorption spectroscopy; x-ray scattering and crystallography; x-ray topography; workshop on surface structure; workshop on electronic and chemical phenomena at surfaces; workshop on imaging; UV FEL machine reviews; VUV machine operations; VUV beamline operations; VUV storage ring parameters; x-ray machine operations; x-ray beamline operations; x-ray storage ring parameters; superconducting x-ray lithography source; SXLS storage ring parameters; the accelerator test facility; proposed UV-FEL user facility at the NSLS; global orbit feedback systems; and NSLSmore » computer system.« less

Low emittance lattice for the storage ring of the Turkish Light Source Facility TURKAY

NASA Astrophysics Data System (ADS)

Nergiz, Z.; Aksoy, A.

2015-06-01

The TAC (Turkish Accelerator Center) project aims to build an accelerator center in Turkey. The first stage of the project is to construct an Infra-Red Free Electron Laser (IR-FEL) facility. The second stage is to build a synchrotron radiation facility named TURKAY, which is a third generation synchrotron radiation light source that aims to achieve a high brilliance photon beam from a low emittance electron beam at 3 GeV. The electron beam parameters are highly dependent on the magnetic lattice of the storage ring. In this paper a low emittance storage ring for TURKAY is proposed and the beam dynamic properties of the magnetic lattice are investigated. Supported by Turkish Republic Ministry of Development (DPT2006K120470)

Terahertz metamaterial based on dual-band graphene ring resonator for modulating and sensing applications

NASA Astrophysics Data System (ADS)

Liu, Chenxi; Liu, Peiguo; Yang, Cheng; Bian, Lian

2017-11-01

A new design of terahertz (THz) metamaterial is proposed for modulating and sensing purposes. The metamaterial consists of two resonators based on periodical arrays of graphene rings with different radii. For each small ring, it is surrounded by four large rings, and vice versa. By varying the Fermi level through electrostatically gating, the transmission of the graphene metamaterial can be controlled dynamically and the maximum modulation depths can reach up to 86% and 73%. Especially, an electromagnetically induced transparency (EIT)-like phenomenon can be generated, which results from the weak hybridization between two nearest neighbor rings performed as bright modes induced by electric dipole. Consequently, frequency sensitivity of 830 GHz per refractive index unit and figure-of-merit of 17 can be realized at the transparency peak. Our work offers an additional opportunity to achieve an EIT-like effect and potential applications in designing active THz modulators and sensors.

Microgravity Storage Vessels and Conveying-Line Feeders for Cohesive Regolith

NASA Technical Reports Server (NTRS)

Walton, Otis R.; Vollmer, Hubert J.

2013-01-01

Under microgravity, the usual methods of placing granular solids into, or extracting them from, containers or storage vessels will not function. Alternative methods are required to provide a motive force to move the material. New configurations for microgravity regolith storage vessels that do not resemble terrestrial silos, hoppers, or tanks are proposed. The microgravity-compatible bulk-material storage vessels and exit feed configurations are designed to reliably empty and feed cohesive material to transfer vessels or conveying ducts or lines without gravity. A controllable motive force drives the cohesive material to the exit opening(s), and provides a reliable means to empty storage vessels and/or to feed microgravity conveying lines. The proposed designs will function equally well in vacuum, or inside of pressurized enclosures. Typical terrestrial granular solids handling and storage equipment will not function under microgravity, since almost all such equipment relies on gravity to at least move material to an exit location or to place it in the bottom of a container. Under microgravity, there effectively are no directions of up or down, and in order to effect movement of material, some other motive force must be applied to the material. The proposed storage vessels utilize dynamic centrifugal force to effect movement of regolith whenever material needs to be removed from the storage vessel. During simple storage, no dynamic motion or forces are required. The rotation rate during emptying can be controlled to ensure that material will move to the desired exit opening, even if the material is highly cohesive, or has acquired an electrostatic charge. The general concept of this Swirl Action Utilized for Centrifugal Ejection of Regolith (SAUCER) microgravity storage unit/dynamic feeder is to have an effective slot-hopper (based on the converging angles of the top and bottom conical section of the vessel) with an exit slot around the entire periphery of the SAUCER. The basic shape of such a unit is like two Chinese straw hats (douli) - one upside down, on the bottom, and another on top; or two wokpans, one upright on the bottom and another inverted on top, with a small gap between the upright and inverted pans or hats (around the periphery). A stationary outer ring, much like an unmounted bicycle tire, surrounds the gap between the two coaxial, nearly conical pieces, forming the top and bottom of the unit.

PEGASYS---A proposed internal target facility for the PEP storage ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Van Biber, K.

A proposal for an integral gas-jet target and forward spectrometer for the PEP storage ring is described. The beam structure, allowable, luminosity (L = 10/sup 33/ cm/sup /minus/2/s/sup /minus/1/ for H/sub 2/, D/sub 2/) and energy (E/sub e/ less than or equal to 15 GeV) make the ring ideal for multiparticle coincidence studies in the scaling regime, and where perturbative QCD may be an apt description of some exclusive and semi-inclusive reactions. 14 refs., 7 figs.

Infrared spectrum, structural and optical properties and molecular docking study of 3-(4-fluorophenyl)-5-phenyl-4,5-dihydro-1H-pyrazole-1-carbaldehyde.

PubMed

Mary, Y Sheena; Panicker, C Yohannan; Sapnakumari, M; Narayana, B; Sarojini, B K; Al-Saadi, Abdulaziz A; Van Alsenoy, C; War, Javeed Ahmad; Fun, H K

2015-03-05

The optimized molecular structure, vibrational frequencies, corresponding vibrational assignments of 3-(4-fluorophenyl)-5-phenyl-4,5-dihydro-1H-pyrazole-1-carbaldehyde have been investigated experimentally and theoretically. The title compound was optimized using at HF and DFT levels of calculations. The B3LYP/6-311++G(d,p) (5D,7F) results and in agreement with experimental infrared bands. The normal modes are assigned using potential energy distribution. The stability of the molecule arising from hyper-conjugative interaction and charge delocalization has been analyzed using natural bonding orbital analysis. The frontier molecular orbital analysis is used to determine the charge transfer within the molecule. From molecular electrostatic potential map, it is evident that the negative electrostatic potential regions are mainly localized over the carbonyl group and mono substituted phenyl ring and are possible sites for electrophilic attack and, positive regions are localized around all para substituted phenyl and pyrazole ring, indicating possible sites for nucleophilic attack. First hyperpolarizability is calculated in order to find its role in nonlinear optics. The geometrical parameters are in agreement with experimental data. From the molecular docking studies, it is evident that the fluorine atom attached to phenyl ring and the carbonyl group attached to pyrazole ring are crucial for binding and the results draw us to the conclusion that the compound might exhibit phosphodiesterase inhibitory activity. Copyright © 2014 Elsevier B.V. All rights reserved.

Electro-Mechanical Simulation of a Large Aperture MOEMS Fabry-Perot Tunable Filter

NASA Technical Reports Server (NTRS)

Kuhn, Jonathan L.; Barclay, Richard B.; Greenhouse, Matthew A.; Mott, D. Brent; Satyapal, Shobita; Powers, Edward I. (Technical Monitor)

2000-01-01

We are developing a micro-machined electrostatically actuated Fabry-Perot tunable filter with a large clear aperture for application in high through-put wide-field imaging spectroscopy and lidar systems. In the first phase of this effort, we are developing key components based on coupled electro-mechanical simulations. In particular, the movable etalon plate design leverages high coating stresses to yield a flat surface in drum-head tension over a large diameter (12.5 mm). In this approach, the cylindrical silicon movable plate is back etched, resulting in an optically coated membrane that is suspended from a thick silicon support ring. Understanding the interaction between the support ring, suspended membrane, and coating is critical to developing surfaces that are flat to within stringent etalon requirements. In this work, we present the simulations used to develop the movable plate, spring suspension system, and electrostatic actuation mechanism. We also present results from tests of fabricated proof of concept components.

BEAM DIAGNOSTICS USING BPM SIGNALS FROM INJECTED AND STORED BEAMS IN A STORAGE RING

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, G.M.; Shaftan; T.

2011-03-28

Many modern light sources are operating in top-off injection mode or are being upgraded to top-off injection mode. The storage ring always has the stored beam and injected beam for top-off injection mode. So the BPM data is the mixture of both beam positions and the injected beam position cannot be measured directly. We propose to use dedicated wide band BPM electronics in the NSLS II storage ring to retrieve the injected beam trajectory with the singular value decomposition (SVD) method. The beam position monitor (BPM) has the capability to measure bunch-by-bunch beam position. Similar electronics can be used tomore » measure the bunch-by-bunch beam current which is necessary to get the injection beam position. The measurement precision of current needs to be evaluated since button BPM sum signal has position dependence. The injected beam trajectory can be measured and monitored all the time without dumping the stored beam. We can adjust and optimize the injected beam trajectory to maximize the injection efficiency. We can also measure the storage ring acceptance by mapping the injected beam trajectory.« less

A double-cusp type electrostatic analyzer for high-cadence ring current ion measurements

NASA Astrophysics Data System (ADS)

Ogasawara, K.; Allegrini, F.; Burch, J. L.; Desai, M. I.; Ebert, R. W.; Goldstein, J.; John, J. M.; Livi, S. A.; McComas, D. J.

2015-12-01

Detailed observations of a variety of ion species at a sufficiently high temporal resolution are essential to understanding the loss and acceleration processes of ring current ions. For example, CRESS/MICS observations indicated that the energy density of suprathermal O+ exceeds that of H+ in large magnetic storms (Daglis et al., 1997), while the H+ energy density dominates under quiet conditions. However, the primary ion loss processes during the storm recovery phase are still incompletely understood. The mechanisms to accelerate upflowing ions, regularly observed with energies of a few keV at ~1000 km altitude, up to the 100s-keV range in the geospace are also not fully understood. Our novel electrostatic analyzer (ESA) employs a toroidal double-shell structure to cover the entire ring current ion range of ~3-250 keV/Q with high temporal resolution (<1 minute with a necessary counting statistics for the quiet time), while saving significant resources in mass and size. In this presentation, we discuss the operation principle and the proof of concept study of the ESA in terms of numerical calculations and ion beam calibration activities. This presentation comprehensively covers the expected sensor performance important for the in-flight capabilities, such as sensor parameters (G-factor, K-factor, and energy resolution), cross-shell contaminations, and UV background counts.

Microgravity

NASA Image and Video Library

1998-09-30

Optical ports ring the Electrostatic Levitator (ESL) vacuum chamber to admit light from the heating laser (beam passes through the window at left), positioning lasers (one port is at center), and lamps to allow diagnostic instruments to view the sample. The ESL uses static electricity to suspend an object (about 2-3 mm in diameter) inside a vacuum chamber while a laser heats the sample until it melts. This lets scientists record a wide range of physical properties without the sample contacting the container or any instruments, conditions that would alter the readings. The Electrostatic Levitator is one of several tools used in NASA's microgravity materials science program.

Beam position monitoring system at CESR

NASA Astrophysics Data System (ADS)

Billing, M. G.; Bergan, W. F.; Forster, M. J.; Meller, R. E.; Rendina, M. C.; Rider, N. T.; Sagan, D. C.; Shanks, J.; Sikora, J. P.; Stedinger, M. G.; Strohman, C. R.; Palmer, M. A.; Holtzapple, R. L.

2017-09-01

The Cornell Electron-positron Storage Ring (CESR) has been converted from a High Energy Physics electron-positron collider to operate as a dedicated synchrotron light source for the Cornell High Energy Synchrotron Source (CHESS) and to conduct accelerator physics research as a test accelerator, capable of studying topics relevant to future damping rings, colliders and light sources. Some of the specific topics that were targeted for the initial phase of operation of the storage ring in this mode, labeled CESRTA (CESR as a Test Accelerator), included 1) tuning techniques to produce low emittance beams, 2) the study of electron cloud development in a storage ring and 3) intra-beam scattering effects. The complete conversion of CESR to CESRTA occurred over a several year period and is described elsewhere. As a part of this conversion the CESR beam position monitoring (CBPM) system was completely upgraded to provide the needed instrumental capabilities for these studies. This paper describes the new CBPM system hardware, its function and representative measurements performed by the upgraded system.

Fundamental Studies Connected with Electrochemical Energy Storage

NASA Technical Reports Server (NTRS)

Buck, E.; Sen, R.

1974-01-01

Papers are presented which deal with electrochemical research activities. Emphasis is placed on electrochemical energy storage devices. Topics discussed include: adsorption of dendrite inhibitors on zinc; proton discharge process; electron and protron transfer; quantum mechanical formulation of electron transfer rates; and theory of electrochemical kinetics in terms of two models of activation; thermal and electrostatic.

Ion source based on the cathodic arc

DOEpatents

Sanders, David M.; Falabella, Steven

1994-01-01

A cylindrically symmetric arc source to produce a ring of ions which leave the surface of the arc target radially and are reflected by electrostatic fields present in the source to a point of use, such as a part to be coated. An array of electrically isolated rings positioned in the source serves the dual purpose of minimizing bouncing of macroparticles and providing electrical insulation to maximize the electric field gradients within the source. The source also includes a series of baffles which function as a filtering or trapping mechanism for any macroparticles.

Transport and Quantum Coherence in Graphene Rings: Aharonov-Bohm Oscillations, Klein Tunneling, and Particle Localization

NASA Astrophysics Data System (ADS)

Filusch, Alexander; Wurl, Christian; Pieper, Andreas; Fehske, Holger

2018-06-01

Simulating quantum transport through mesoscopic, ring-shaped graphene structures, we address various quantum coherence and interference phenomena. First, a perpendicular magnetic field, penetrating the graphene ring, gives rise to Aharonov-Bohm oscillations in the conductance as a function of the magnetic flux, on top of the universal conductance fluctuations. At very high fluxes, the interference gets suppressed and quantum Hall edge channels develop. Second, applying an electrostatic potential to one of the ring arms, nn'n- or npn-junctions can be realized with particle transmission due to normal tunneling or Klein tunneling. In the latter case, the Aharonov-Bohm oscillations weaken for smooth barriers. Third, if potential disorder comes in to play, both Aharonov-Bohm and Klein tunneling effects rate down, up to the point where particle localization sets in.

Substitution effects on the absorption spectra of nitrophenolate isomers.

PubMed

Wanko, Marius; Houmøller, Jørgen; Støchkel, Kristian; Suhr Kirketerp, Maj-Britt; Petersen, Michael Åxman; Nielsen, Mogens Brøndsted; Nielsen, Steen Brøndsted; Rubio, Angel

2012-10-05

Charge-transfer excitations highly depend on the electronic coupling between the donor and acceptor groups. Nitrophenolates are simple examples of charge-transfer systems where the degree of coupling differs between ortho, meta and para isomers. Here we report the absorption spectra of the isolated anions in vacuo to avoid the complications of solvent effects. Gas-phase action spectroscopy was done with two different setups, an electrostatic ion storage ring and an accelerator mass spectrometer. The results are interpreted on the basis of CC2 quantum chemical calculations. We identified absorption maxima at 393, 532, and 399 nm for the para, meta, and ortho isomer, respectively, with the charge-transfer transition into the lowest excited singlet state. In the meta isomer, this π-π* transition is strongly redshifted and its oscillator strength reduced, which is related to the pronounced charge-transfer character, as a consequence of the topology of the conjugated π-system. Each isomer's different charge distribution in the ground state leads to a very different solvent shift, which in acetonitrile is bathochromic for the para and ortho, but hypsochromic for the meta isomer.

Preliminary study of injection transients in the TPS storage ring

NASA Astrophysics Data System (ADS)

Chen, C. H.; Liu, Y. C.; Y Chen, J.; Chiu, M. S.; Tseng, F. H.; Fann, S.; Liang, C. C.; Huang, C. S.; Y Lee, T.; Y Chen, B.; Tsai, H. J.; Luo, G. H.; Kuo, C. C.

2017-07-01

An optimized injection efficiency is related to a perfect match between the pulsed magnetic fields in the storage ring and transfer line extraction in the TPS. However, misalignment errors, hardware output errors and leakage fields are unavoidable. We study the influence of injection transients on the stored TPS beam and discuss solutions to compensate these. Related simulations and measurements will be presented.

Vacuum system for room temperature X-ray lithography source (XLS)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schuchman, J.C.

1988-09-30

A prototype room-temperature X-Ray Lithography Source (XLS)was proposed to be built at Brookhaven National Laboratory as part of a technology-transfer- to-American-industry program. The overall machine comprises a full energy linac, a 170 meter long transport line, and a 39 meter circumference storage ring. The scope of this paper will be limited to describing the storage ring vacuum system. (AIP)

Vacuum system for room temperature X-ray lithography source (XLS)

NASA Astrophysics Data System (ADS)

Schuchman, J. C.

1988-09-01

A prototype room-temperature X-Ray Lithography Source (XLS)was proposed to be built at Brookhaven National Laboratory as part of a technology-transfer- to-American-industry program. The overall machine comprises a full energy linac, a 170 meter long transport line, and a 39 meter circumference storage ring. The scope of this paper will be limited to describing the storage ring vacuum system. (AIP)

Feasibility of a ring FEL at low emittance storage rings

NASA Astrophysics Data System (ADS)

Agapov, I.

2015-09-01

A scheme for generating coherent radiation at latest generation low emittance storage rings such as PETRA III at DESY (Balewski et al., 2004 [1]) is proposed. The scheme is based on focusing and subsequent defocusing of the electron beam in the longitudinal phase space at the undulator location. The expected performance characteristics are estimated for radiation in the wavelength range of 500-1500 eV. It is shown that the average brightness is increased by several orders of magnitude compared to spontaneous undulator radiation, which can open new perspectives for photon-hungry soft X-ray spectroscopy techniques.

PEGASYS: A proposed internal target-spectrometer facility for the PEP storage ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Van Bibber, K.

A proposal for an internal gas-jet target and forward spectrometer for the PEP storage ring is described. The beam structure, allowable luminosity (L=10/sup 33/ cm/sup /minus/2/s/sup /minus/1/ for H/sub 2/, D/sub 2/ decreasing as Z/sup /minus/1.75/ for nuclear targets) and energy (E/sub e/less than or equal to 15 GeV) make the ring ideal for multiparticle coincidence studies in the scaling regime, and where perturbative QCD may be an apt description of some exclusive and semi-inclusive reactions. 17 refs., 5 figs.

Future Synchrotron Light Sources Based on Ultimate Storage Rings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cai, Yunhai; /SLAC

2012-04-09

The main purpose of this talk is to describe how far one might push the state of the art in storage ring design. The talk will start with an overview of the latest developments and advances in the design of synchrotron light sources based on the concept of an 'ultimate' storage ring. The review will establish how bright a ring based light source might be, where the frontier of technological challenges are, and what the limits of accelerator physics are. Emphasis will be given to possible improvements in accelerator design and developments in technology toward the goal of achieving anmore » ultimate storage ring. An ultimate storage ring (USR), defined as an electron ring-based light source having an emittance in both transverse planes at the diffraction limit for the range of X-ray wavelengths of interest for a scientific community, would provide very high brightness photons having high transverse coherence that would extend the capabilities of X-ray imaging and probe techniques beyond today's performance. It would be a cost-effective, high-coherence 4th generation light source, competitive with one based on energy recovery linac (ERL) technology, serving a large number of users studying material, chemical, and biological sciences. Furthermore, because of the experience accumulated over many decades of ring operation, it would have the great advantage of stability and reliability. In this paper we consider the design of an USR having 10-pm-rad emittance. It is a tremendous challenge to design a storage ring having such an extremely low emittance, a factor of 100 smaller than those in existing light sources, especially such that it has adequate dynamic aperture and beam lifetime. In many ultra-low emittance designs, the injection acceptances are not large enough for accumulation of the electron beam, necessitating on-axis injection where stored electron bunches are completely replaced with newly injected ones. Recently, starting with the MAX-IV 7-bend achromatic cell, we have made significant progress with the design of PEP-X, a USR that would inhabit the decommissioned PEP-II tunnel at SLAC. The enlargement of the dynamic aperture is largely a result of the cancellations of the 4th-order resonances in the 3rd-order achromats and the effective use of lattice optimization programs. In this paper, we will show those cancellations of the 4th-order resonances using an analytical approach based on the exponential Lie operators and the Poisson brackets. Wherever possible, our analytical results will be compared with their numerical counterparts. Using the derived formulae, we will construct 4th-order geometric achromats and use them as modules for the lattice of the PEP-X USR, noting that only geometric terms are canceled to the 4th order.« less

The Beam Dynamics and Beam Related Uncertainties in Fermilab Muon $g-2$ Experiment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wu, Wanwei

The anomaly of the muon magnetic moment,more » $$a_{\\mu}\\equiv (g-2)/2$$, has played an important role in constraining physics beyond the Standard Model for many years. Currently, the Standard Model prediction for $$a_{\\mu}$$ is accurate to 0.42 parts per million (ppm). The most recent muon $g-2$ experiment was done at Brookhaven National Laboratory (BNL) and determined $$a_{\\mu}$$ to 0.54 ppm, with a central value that differs from the Standard Model prediction by 3.3-3.6 standard deviations and provides a strong hint of new physics. The Fermilab Muon $g-2$ Experiment has a goal to measure $$a_{\\mu}$$ to unprecedented precision: 0.14 ppm, which could provide an unambiguous answer to the question whether there are new particles and forces that exist in nature. To achieve this goal, several items have been identified to lower the systematic uncertainties. In this work, we focus on the beam dynamics and beam associated uncertainties, which are important and must be better understood. We will discuss the electrostatic quadrupole system, particularly the hardware-related quad plate alignment and the quad extension and readout system. We will review the beam dynamics in the muon storage ring, present discussions on the beam related systematic errors, simulate the 3D electric fields of the electrostatic quadrupoles and examine the beam resonances. We will use a fast rotation analysis to study the muon radial momentum distribution, which provides the key input for evaluating the electric field correction to the measured $$a_{\\mu}$$.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mcwilliams, A. J.; Daugherty, W. L.; Skidmore, T. E.

The 9975 Type B shipping package is used within the DOE complex for shipping special nuclear materials. This package is re-certified annually in accordance with Safety Analysis Report for Packaging (SARP) requirements. The package is also used at the Savannah River Site as part of the long-term storage configuration of special nuclear materials. As such, the packages do not undergo annual recertification during storage, with uncertainty as to how long some of the package components will meet their functional requirements in the storage environment. The packages are currently approved for up to 15 years storage, and work continues to providemore » a technical basis to extend that period. This report describes efforts by the Savannah River National Laboratory (SRNL) to extend the service life estimate of Viton® GLT and GLT-S fluoroelastomer O-rings used in the 9975 shipping package. O-rings of both GLT and GLT-S compositions are undergoing accelerated aging at elevated temperature, and are periodically tested for compression stress relaxation (CSR) behavior. The CSR behavior of O-rings was evaluated at temperatures from 175 to 400 °F. These collective data were used to develop predictive models for extrapolation of CSR behavior to relevant service temperatures (< 156 °F). The predictive model developed from the CSR data conservatively indicates a service life of approximately 37 years for Viton GLT O-rings at the maximum effective service temperature of 156 °F. The estimated service life for Viton GLT-S O-rings is significantly longer.« less

Ringing in the new physics: The politics and technology of electron colliders in the United States, 1956--1972

NASA Astrophysics Data System (ADS)

Paris, Elizabeth

The ``November Revolution'' of 1974 and the experiments that followed consolidated the place of the Standard Model in modern particle physics. Much of the evidence on which these conclusions depended was generated by a new type of tool: colliding beam storage rings, which had been considered physically unfeasible twenty years earlier. In 1956 a young experimentalist named Gerry O'Neill dedicated himself to demonstrating that such an apparatus could do useful physics. The storage ring movement encountered numerous obstacles before generating one of the standard machines for high energy research. In fact, it wasn't until 1970 that the U.S. finally broke ground on its first electron-positron collider. Drawing extensively on archival sources and supplementing them with the personal accounts of many of the individuals who took part, Ringing in the New Physics examines this instance of post-World War II techno-science and the new social, political and scientific tensions that characterize it. The motivations are twofold: first, that the chronicle of storage rings may take its place beside mathematical group theory, computer simulations, magnetic spark chambers, and the like as an important contributor to a view of matter and energy which has been the dominant model for the last twenty-five years. In addition, the account provides a case study for the integration of the personal, professional, institutional, and material worlds when examining an episode in the history or sociology of twentieth century science. The story behind the technological development of storage rings holds fascinating insights into the relationship between theory and experiment, collaboration and competition in the physics community, the way scientists obtain funding and their responsibilities to it, and the very nature of what constitutes ``successful'' science in the post- World War II era.

Toward a more complete understanding of noncovalent interactions involving aromatic rings.

PubMed

Wheeler, Steven E; Bloom, Jacob W G

2014-08-14

Noncovalent interactions involving aromatic rings, which include π-stacking interactions, anion-π interactions, and XH-π interactions, among others, are ubiquitous in chemical and biochemical systems. Despite dramatic advances in our understanding of these interactions over the past decade, many aspects of these noncovalent interactions have only recently been uncovered, with many questions remaining. We summarize our computational studies aimed at understanding the impact of substituents and heteroatoms on these noncovalent interactions. In particular, we discuss our local, direct interaction model of substituent effects in π-stacking interactions. In this model, substituent effects are dominated by electrostatic interactions of the local dipoles associated with the substituents and the electric field of the other ring. The implications of the local nature of substituent effects on π-stacking interactions in larger systems are discussed, with examples given for complexes with carbon nanotubes and a small graphene model, as well as model stacked discotic systems. We also discuss related issues involving the interpretation of electrostatic potential (ESP) maps. Although ESP maps are widely used in discussions of noncovalent interactions, they are often misinterpreted. Next, we provide an alternative explanation for the origin of anion-π interactions involving substituted benzenes and N-heterocycles, and show that these interactions are well-described by simple models based solely on charge-dipole interactions. Finally, we summarize our recent work on the physical nature of substituent effects in XH-π interactions. Together, these results paint a more complete picture of noncovalent interactions involving aromatic rings and provide a firm conceptual foundation for the rational exploitation of these interactions in a myriad of chemical contexts.

Experimental Evidence for the Los Alamos Proton Storage Ring Beam Instability

NASA Astrophysics Data System (ADS)

Plum, M.; Fitzgerald, D. H.; Macek, R.; Sander, O.; Thiessen, H. A.; Wang, T. S.; Wilkinson, C.

1997-05-01

Although the exact instability mechanism at the Proton Storage Ring (PSR) has not yet been conclusively identified, the evidence gathered to date is consistent with an e-p instability. We have recently acquired new data which shows that clearing electrodes significantly affect the instability threshold. A set of comprehensive measurements is also planned for the first months of 1997. In this paper we will present our latest data.

Fundamentals of Coherent Synchrotron Radiation in Storage Rings

NASA Astrophysics Data System (ADS)

Sannibale, F.; Byrd, J. M.; Loftsdottir, A.; Martin, M. C.; Venturini, M.

2004-05-01

We present the fundamental concepts for producing stable broadband coherent synchrotron radiation (CSR) in the terahertz frequency region in an electron storage ring. The analysis includes distortion of bunch shape from the synchrotron radiation (SR), enhancing higher frequency coherent emission and limits to stable emission due to a microbunching instability excited by the SR. We use these concepts to optimize the performance of a source for CSR emission.

Dusty plasma effects in Saturn's rings

NASA Astrophysics Data System (ADS)

Horanyi, M.; Morfill, G. E.

Saturn's rings show a variety of dusty plasma processes. The electrostatic charging and subsequent orbital dynamics of small grains can establish their size and spatial distributions, for example. Simultaneously, dust can alter the composition, density and temperature of the plasma surrounding it. The dynamics of charged dust particles can be surprisingly complex and fundamentally different from the well understood limits of gravitationally dominated motions of neutral particles or the adiabatic motion of electrons and ions in electromagnetic fields that dominate gravity. This talk will focus on recent Cassini observations at Saturn that are best explained by theories describing the effects of the magnetospheric fields and plasmas on the rings. As our best example, we will discuss the physics describing the formation of the `spokes' and their apparent lack to date (at the time of the submission of this abstract) in the Cassini images, as well as our expectations of their return (by the time this talk is presented). Spokes are intermittently appearing radial markings in Saturn's B ring which are believed to form when micron sized dust particles are levitated above the ring by electrostatic forces. First observed by the Voyagers, and subsequently by the Hubble space telescope, the spokes disappeared between October 1998 and September 2005, when the Cassini spacecraft saw them reappear. These observations show spokes that are much fainter and smaller than those seen by the Voyagers. We will review the original ideas of spoke formation dating back to the Voyager era. We will focus on the expected new observations that might be used to constrain and complete our ideas on the triggering mechanisms for spoke formation and their evolution. In particular we will point to outstanding issues related to: a) the properties of impact generated plasmas and their importance as a source of plasma in the magnetosphere; b) the role of the shadow region; c) the asymmetry between the sunlit side of the rings and the shadowed side underneath; d) the coupling of the rings to the ionosphere that ultimately limits the magnitude of the azimuthal electric field, which is thought to be responsible for the apparent radial propagation of the spokes.

Something old, something new: Why models need a multi-pool representation of storage reserves

NASA Astrophysics Data System (ADS)

Richardson, Andrew; Carbone, Mariah

2015-04-01

We know surprisingly little about processes regulating the allocation of photosynthetic assimilates to growth, storage, and other metabolic functions. Storage of nonstructural carbon (NSC, principally sugars and starch) is critically important for woody plants, because these reserves enable sessile, long-lived organisms to tolerate biotic and abiotic stress, including pests, disturbance, and drought. But, critical questions about the size and turnover of these reserves remain unanswered. Labeling studies have generally shown rapid use of new (labeled) NSC and inferred fast mixing between old and new NSC, both of which suggest quick turnover of storage reserves. However, recent studies have shown that some of the reserves stored in stem and root tissue are not only a decade old, but also still available to support new tissue growth following catastrophic disturbance. We characterized the distribution of NSC in the stemwood, branches, and roots of two temperate trees, and we used the continuous label offered by the radiocarbon (14C) bomb spike to estimate the mean age of NSC in different tissues of two temperate trees. NSC in branches and outermost stemwood growth rings had the 14C signature of the current growing season. However, NSC in older above- and below-ground tissues was enriched in 14C, indicating that it was produced from older assimilates. Radial patterns of 14C in stemwood NSC showed strong mixing of NSC across the youngest growth rings, with limited "mixing in" of younger NSC to older rings. Sugars in the outermost 5 growth rings, accounting for two-thirds of the stemwood pool, had a mean age < 1 y, whereas sugars in older growth rings had a mean age > 5 y. Thus, there is not a single, well-mixed "storage pool," and indeed "young" and "old" storage compounds appear to be physically isolated from each other. We will discuss the implications of these results for improving model representation of NSC storage and consumption by forest trees. We will suggest that there are conceptual similarities between modeling NSC pools and modeling soil C pools. We will propose future directions for modeling NSCs and also identify key questions that still need to be answered with new experimental work.

Ring-averaged ion velocity distribution function probe for laboratory magnetized plasma experiment

NASA Astrophysics Data System (ADS)

Kawamori, Eiichirou; Chen, Jinting; Lin, Chiahsuan; Lee, Zongmau

2017-10-01

Ring-averaged velocity distribution function of ions at a fixed guiding center position is a fundamental quantity in the gyrokinetic plasma physics. We have developed a diagnostic tool for the ring averaged velocity distribution function of ions for laboratory plasma experiments, which is named as the ring-averaged ion distribution function probe (RIDFP). The RIDFP is a set of ion collectors for different velocities. It is designed to be immersed in magnetized plasmas and achieves momentum selection of incoming ions by the selection of the ion Larmor radii. To nullify the influence of the sheath potential surrounding the RIDFP on the orbits of the incoming ions, the electrostatic potential of the RIDFP body is automatically adjusted to coincide with the space potential of the target plasma with the use of an emissive probe and a voltage follower. The developed RIDFP successfully measured the equilibrium ring-averaged velocity distribution function of a laboratory magnetized plasma, which was in accordance with the Maxwellian distribution having an ion temperature of 0.2 eV.

Crystal structure and Hirshfield analysis of the 4-(di-methyl-amino)-pyridine adduct of 4-meth-oxy-phenyl-borane.

PubMed

Shooter, Jesse; Allen, Caleb J; Tinsley, Colby W K; Zakharov, Lev N; Abbey, Eric R

2017-11-01

The title compound [systematic name: 4-(di-methyl-amino)-pyridine-4-meth-oxy-phenyl-borane (1/1)], C 14 H 19 BN 2 O, contains two independent mol-ecules in the asymmetric unit. Both molecules exhibit coplanar, mostly sp 2 -hybridized meth-oxy and di-methyl-amino substituents on their respective aromatic rings, consistent with π-donation into the aromatic systems. The B-H groups exhibit an intra-molecular close contact with a C-H group of the pyridine ring, which may be evidence of electrostatic attraction between the hydridic B-H and the electropositive aromatic C-H. There appears to be weak C-H⋯π(arene) inter-actions between two of the H atoms of an amino-methyl group and the meth-oxy-substituted benzene ring of the other independent mol-ecule, and another C-H⋯π (arene) inter-action between one of the pyridine ring H atoms and the same benzene ring.

Ring-averaged ion velocity distribution function probe for laboratory magnetized plasma experiment.

PubMed

Kawamori, Eiichirou; Chen, Jinting; Lin, Chiahsuan; Lee, Zongmau

2017-10-01

Ring-averaged velocity distribution function of ions at a fixed guiding center position is a fundamental quantity in the gyrokinetic plasma physics. We have developed a diagnostic tool for the ring averaged velocity distribution function of ions for laboratory plasma experiments, which is named as the ring-averaged ion distribution function probe (RIDFP). The RIDFP is a set of ion collectors for different velocities. It is designed to be immersed in magnetized plasmas and achieves momentum selection of incoming ions by the selection of the ion Larmor radii. To nullify the influence of the sheath potential surrounding the RIDFP on the orbits of the incoming ions, the electrostatic potential of the RIDFP body is automatically adjusted to coincide with the space potential of the target plasma with the use of an emissive probe and a voltage follower. The developed RIDFP successfully measured the equilibrium ring-averaged velocity distribution function of a laboratory magnetized plasma, which was in accordance with the Maxwellian distribution having an ion temperature of 0.2 eV.

Microgravity

NASA Image and Video Library

1998-09-30

Optical prots ring the Electrostatic Levitator (ESL) vacuum chamber to admit light from the heating laser (the beam passes through the window at left), poisitioning lasers (one port is at center), and lamps (such as the deuterium arc lamp at right), and to allow diagnostic instruments to view the sample. The ESL uses static electricity to suspend an object (about 2-3 mm in diameter) inside a vacuum chamber while a laser heats the sample until it melts. This lets scientists record a wide range of physical properties without the sample contacting the container or any instruments, conditions that would alter the readings. The Electrostatic Levitator is one of several tools used in NASA's microgravity materials science program.

Microgravity

NASA Image and Video Library

1998-09-30

Optical prots ring the Electrostatic Levitator (ESL) vacuum chamber to admit light from the heating laser (the beam passes through the window at left), poisitioning lasers (one port is at center), and lamps (arc lamp at right), and to allow diagnostic instruments to view the sample. The ESL uses static electricity to suspend an object (about 2-3 mm in diameter) inside a vacuum chamber while a laser heats the sample until it melts. This lets scientists record a wide range of physical properties without the sample contacting the container or any instruments, conditions that would alter the readings. The Electrostatic Levitator is one of several tools used in NASA's microgravity materials science program.

Saturn Conference, Tucson, AZ, May 11-15, 1982, Proceedings

NASA Astrophysics Data System (ADS)

1983-05-01

Topics on Saturn are discussed. The subjects addressed include: the microwave opacity at wavelengths of 3.6 and 13 cm and the particle size distributions in Saturn's rings from Voyager 1 radio occultations; W-shaped occultation signatures and an inference of entwined particle orbits in charged planetary ringlets; the evolution of spokes in Saturn's B ring; the ballistic transport process in collisional interactions of ring particles; and the formation of fine dust on Saturn's rings as suggested by the presence of spokes. Also considered are: Saturn's electrostatic discharges and lightning as their possible cause; thin-layer configurations for the zonal flow; the composition of the Saturnian stratosphere as determined with the IUE; optical properties of Saturn's atmosphere; internal gravity waves in Titan's atmosphere observed by Voyager radio occultation; Hyperion and the collisional disruption of a resonant satellite. For individual items see A83-35727 to A83-35739

The Potential-Well Distortion Effect and Coherent Instabilities of Electron Bunches in Storage Rings

NASA Astrophysics Data System (ADS)

Korchuganov, V. N.; Smygacheva, A. S.; Fomin, E. A.

2018-05-01

The effect of electromagnetic interaction between electron bunches and the vacuum chamber of a storage ring on the longitudinal motion of bunches is studied. Specifically, the potential-well distortion effect and the so-called coherent instabilities of coupled bunches are considered. An approximate analytical solution for the frequencies of incoherent oscillations of bunches distributed arbitrarily within the ring is obtained for a distorted potential well. A new approach to determining frequencies of coherent oscillations and an approximate analytical relation for estimating the stability of a system of bunches as a function of their distribution in the accelerator orbit are presented.

CH/π interactions in metal-porphyrin complexes with pyrrole and chelate rings as hydrogen acceptors.

PubMed

Medaković, Vesna B; Bogdanović, Goran A; Milčić, Miloš K; Janjić, Goran V; Zarić, Snežana D

2012-12-01

CH/π interactions in metal porphyrinato complexes were studied by analyzing data in crystal structures from the Cambridge Structural Database (CSD) and by quantum chemical calculations. The analysis of the data in the CSD shows that both five-membered pyrrole and six-membered chelate rings form CH/π interactions. The interactions occur more frequently with five-membered rings. The analysis of distances in crystal structures and calculated energies show stronger interactions with six-membered chelate rings, indicating that a larger number of interactions with five-membered rings are not the consequence of stronger interactions, but better accessibility of five-membered pyrrole rings. The calculated energies of the interactions with positions in six-membered rings are -2.09 to -2.83 kcal/mol, while the energies with five-membered rings are -2.05 to -2.26 kcal/mol. The results reveal that stronger interactions of six-membered rings are the consequence of stronger electrostatic interactions. Substituents on the porphyrin ring significantly strengthen the interactions. Substituents on the six-membered ring strengthen the interaction energy by about 20%. The results show that CH/π interactions play an important role in molecular recognition of metalloporphyrins. The significant influence of the substituents on interaction energies can be very important for the design of model systems in bioinorganic chemistry. Copyright © 2012 Elsevier Inc. All rights reserved.

Electrostatic lens to focus an ion beam to uniform density

DOEpatents

Johnson, Cleland H.

1977-01-11

A focusing lens for an ion beam having a gaussian or similar density profile is provided. The lens is constructed to provide an inner zero electrostatic field, and an outer electrostatic field such that ions entering this outer field are deflected by an amount that is a function of their distance from the edge of the inner field. The result is a beam that focuses to a uniform density in a manner analogous to that of an optical ring lens. In one embodiment, a conically-shaped network of fine wires is enclosed within a cylindrical anode. The wire net together with the anode produces a voltage field that re-directs the outer particles of the beam while the axial particles pass undeflected through a zero field inside the wire net. The result is a focused beam having a uniform intensity over a given target area and at a given distance from the lens.

The conversion of CESR to operate as the Test Accelerator, CesrTA. Part 1: overview

NASA Astrophysics Data System (ADS)

Billing, M. G.

2015-07-01

Cornell's electron/positron storage ring (CESR) was modified over a series of accelerator shutdowns beginning in May 2008, which substantially improves its capability for research and development for particle accelerators. CESR's energy span from 1.8 to 5.6 GeV with both electrons and positrons makes it ideal for the study of a wide spectrum of accelerator physics issues and instrumentation related to present light sources and future lepton damping rings. Additionally a number of these are also relevant for the beam physics of proton accelerators. This paper outlines the motivation, design and conversion of CESR to a test accelerator, CESRTA, enhanced to study such subjects as low emittance tuning methods, electron cloud (EC) effects, intra-beam scattering, fast ion instabilities as well as general improvements to beam instrumentation. While the initial studies of CESRTA focussed on questions related to the International Linear Collider (ILC) damping ring design, CESRTA is a very flexible storage ring, capable of studying a wide range of accelerator physics and instrumentation questions. This paper contains the outline and the basis for a set of papers documenting the reconfiguration of the storage ring and the associated instrumentation required for the studies described above. Further details may be found in these papers.

Theoretical study of hydrogen storage in a truncated triangular pyramid molecule consisting of pyridine and benzene rings bridged by vinylene groups

NASA Astrophysics Data System (ADS)

Ishikawa, Shigeru; Nemoto, Tetsushi; Yamabe, Tokio

2018-06-01

Hydrogen storage in a truncated triangular pyramid molecule C33H21N3, which consists of three pyridine rings and one benzene ring bridged by six vinylene groups, is studied by quantum chemical methods. The molecule is derived by substituting three benzene rings in a truncated tetrahedron hydrocarbon C36H24 with pyridine rings. The optimized molecular structure under C 3v symmetry shows no imaginary vibrational modes at the B3LYP/cc-pVTZ level of theory. The hydrogen storage process is investigated based on the MP2/cc-pVTZ method. Like the structure before substitution, the C33H21N3 molecule has a cavity that stores a hydrogen molecule with a binding energy of - 140 meV. The Langmuir isotherm shows that this cavity can store hydrogen at higher temperatures and lower pressures than usual physisorption materials. The C33H21N3 molecule has a kinetic advantage over the C36H24 molecule because the former molecule has a lower barrier (+ 560 meV) for the hydrogen molecule entering the cavity compared with the latter molecule (+ 730 meV) owing to the lack of hydrogen atoms narrowing the opening.

Electron-cloud updated simulation results for the PSR, and recent results for the SNS

NASA Astrophysics Data System (ADS)

Pivi, M.; Furman, M. A.

2002-05-01

Recent simulation results for the main features of the electron cloud in the storage ring of the Spallation Neutron Source (SNS) at Oak Ridge, and updated results for the Proton Storage Ring (PSR) at Los Alamos are presented in this paper. A refined model for the secondary emission process including the so called true secondary, rediffused and backscattered electrons has recently been included in the electron-cloud code.

BPM Breakdown Potential in the PEP-II B-factory Storage Ring Collider

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weathersby, Stephen; Novokhatski, Alexander; /SLAC

2010-02-10

High current B-Factory BPM designs incorporate a button type electrode which introduces a small gap between the button and the beam chamber. For achievable currents and bunch lengths, simulations indicate that electric potentials can be induced in this gap which are comparable to the breakdown voltage. This study characterizes beam induced voltages in the existing PEP-II storage ring collider BPM as a function of bunch length and beam current.

Multi-objective dynamic aperture optimization for storage rings

DOE PAGES

Li, Yongjun; Yang, Lingyun

2016-11-30

We report an efficient dynamic aperture (DA) optimization approach using multiobjective genetic algorithm (MOGA), which is driven by nonlinear driving terms computation. It was found that having small low order driving terms is a necessary but insufficient condition of having a decent DA. Then direct DA tracking simulation is implemented among the last generation candidates to select the best solutions. The approach was demonstrated successfully in optimizing NSLS-II storage ring DA.

Towards a 4{sup th} generation storage ring at the Canadian Light Source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dallin, Les; Wurtz, Ward

2016-07-27

Demands from beamline scientists for more brilliant sources of synchrotron radiation have resulted in the emergence of 4{sup th} generation (diffraction-limited) storage rings. The practical development of the multi-bend achromat (MBA) concept by MAX IV lab has spurred many synchrotron light sources around the world to develop similar machines. For existing facilities two options are available: upgrading existing machines or building a new structure. The Canadian Light Source (CLS) has explored both options. For a new low emittance source in the existing CLS tunnel a decrease in electron energy would be required. A machine similar to the ALS upgrade couldmore » be contemplated. To achieve low emittance at our present energy of 2.9 GeV a new storage ring is desirable. Several options have been investigated. These designs use extremely strong focusing magnets to achieve extremely low emittances in compact lattice achromats.« less

Preparing the MAX IV storage rings for timing-based experiments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stråhlman, C., E-mail: Christian.Strahlman@maxlab.lu.se; Olsson, T., E-mail: Teresia.Olsson@maxlab.lu.se; Leemann, S. C.

2016-07-27

Time-resolved experimental techniques are increasingly abundant at storage ring facilities. Recent developments in accelerator technology and beamline instrumentation allow for simultaneous operation of high-intensity and timing-based experiments. The MAX IV facility is a state-of-the-art synchrotron light source in Lund, Sweden, that will come into operation in 2016. As many storage ring facilities are pursuing upgrade programs employing strong-focusing multibend achromats and passive harmonic cavities (HCs) in high-current operation, it is of broad interest to study the accelerator and instrumentation developments required to enable timing-based experiments at such machines. In particular, the use of hybrid filling modes combined with pulse pickingmore » by resonant excitation or pseudo single bunch has shown promising results. These methods can be combined with novel beamline instrumentation, such as choppers and instrument gating. In this paper we discuss how these techniques can be implemented and employed at MAX IV.« less

Upgrading the Digital Electronics of the PEP-II Bunch Current Monitors at the Stanford Linear Accelerator Center

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kline, Josh; /SLAC

2006-08-28

The testing of the upgrade prototype for the bunch current monitors (BCMs) in the PEP-II storage rings at the Stanford Linear Accelerator Center (SLAC) is the topic of this paper. Bunch current monitors are used to measure the charge in the electron/positron bunches traveling in particle storage rings. The BCMs in the PEP-II storage rings need to be upgraded because components of the current system have failed and are known to be failure prone with age, and several of the integrated chips are no longer produced making repairs difficult if not impossible. The main upgrade is replacing twelve old (1995)more » field programmable gate arrays (FPGAs) with a single Virtex II FPGA. The prototype was tested using computer synthesis tools, a commercial signal generator, and a fast pulse generator.« less

A compact radiation source for digital subtractive angiography

NASA Astrophysics Data System (ADS)

Wiedemann, H.; Baltay, M.; Carr, R.; Hernandez, M.; Lavender, W.

1994-08-01

Beam requirements for 33 keV radiation used in digital subtraction angiography have been established through extended experimentation first at Stanford and later at the National Synchrotron Light Source in Brookhaven. So far research and development of this medical procedure to image coronary blood vessels have been undertaken on large high energy electron storage rings. With progress in this diagnostic procedure, it is interesting to look for an optimum concept for providing a 33 keV radiation source which would fit into the environment of a hospital. A variety of competing effects and technologies to produce 33 keV radiation are available, but none of these processes provides the combination of sufficient photon flux and monochromaticity except for synchrotron radiation from an electron storage ring. The conceptual design of a compact storage ring optimized to fit into a hospital environment and producing sufficient 33 keV radiation for digital subtraction radiography will be discussed.

X-ray nanoprobes and diffraction-limited storage rings: opportunities and challenges of fluorescence tomography of biological specimens

PubMed Central

de Jonge, Martin D.; Ryan, Christopher G.; Jacobsen, Chris J.

2014-01-01

X-ray nanoprobes require coherent illumination to achieve optic-limited resolution, and so will benefit directly from diffraction-limited storage rings. Here, the example of high-resolution X-ray fluorescence tomography is focused on as one of the most voracious demanders of coherent photons, since the detected signal is only a small fraction of the incident flux. Alternative schemes are considered for beam delivery, sample scanning and detectors. One must consider as well the steps before and after the X-ray experiment: sample preparation and examination conditions, and analysis complexity due to minimum dose requirements and self-absorption. By understanding the requirements and opportunities for nanoscale fluorescence tomography, one gains insight into the R&D challenges in optics and instrumentation needed to fully exploit the source advances that diffraction-limited storage rings offer. PMID:25177992

Collective electron driven linac for high energy physics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seeman, J.T.

1983-08-01

A linac design is presented in which an intense ultrarelativistic electron bunch is used to excite fields in a series of cavities and accelerate charged particles. The intense electron bunch is generated in a simple storage ring to have the required transverse and longitudinal dimensions. The bunch is then transferred to the linac. The linac structure can be inexpensively constructed of spacers and washers. The fields in the cells resulting from the bunch passage are calculated using the program BCI. The results show that certain particles within the driving bunch and also trailing particles of any sign charge can bemore » accelerated. With existing electron storage rings, accelerating gradients greater than 16 MV/m are possible. Examples of two accelerators are given: a 30 GeV electron/positron accelerator useful as an injector for a high energy storage ring and 2) a 110 GeV per beam electron-positron collider.« less

Modeling Systematic Error Effects for a Sensitive Storage Ring EDM Polarimeter

NASA Astrophysics Data System (ADS)

Stephenson, Edward; Imig, Astrid

2009-10-01

The Storage Ring EDM Collaboration has obtained a set of measurements detailing the sensitivity of a storage ring polarimeter for deuterons to small geometrical and rate changes. Various schemes, such as the calculation of the cross ratio [1], can cancel effects due to detector acceptance differences and luminosity differences for states of opposite polarization. Such schemes fail at second-order in the errors, becoming sensitive to geometrical changes, polarization magnitude differences between opposite polarization states, and changes to the detector response with changing data rates. An expansion of the polarimeter response in a Taylor series based on small errors about the polarimeter operating point can parametrize such effects, primarily in terms of the logarithmic derivatives of the cross section and analyzing power. A comparison will be made to measurements obtained with the EDDA detector at COSY-J"ulich. [4pt] [1] G.G. Ohlsen and P.W. Keaton, Jr., NIM 109, 41 (1973).

The Electrostatic Potential of a Uniformly Charged Ring

ERIC Educational Resources Information Center

Ciftja, Orion; Babineaux, Arica; Hafeez, Nadia

2009-01-01

When faced with mathematical methods, undergraduate students have difficulty in grasping the reality of various approaches and special functions. It is only when they take a more specialized course such as classical electromagnetism that they finally see the connection. A problem that we believe illustrates very well the depth and variety of…

A retrospective of the career of Ray Herb

NASA Astrophysics Data System (ADS)

Norton, G. A.; Ferry, J. A.; Daniel, R. E.; Klody, G. M.

1999-04-01

Ray Herb's career in the development of electrostatic accelerators spans 65 years. He began in 1933 by pressurizing a Van de Graaff generator, for the first time. Over the next six years, the group at the University of Wisconsin, under his direction, developed the fundamentals of equipotential rings, potential grading, corona triode control, and other basic mechanisms for the practical use of electrostatic accelerators while making fundamental contributions to experimental nuclear physics. This group held the world's record in sustaining potential difference of 4.5 MV. During World War II, he worked on radar at the Radiation Laboratory. After the war, Herb resumed his career with further fundamental contributions including metal/ceramic bonding, ultrahigh vacuum pumping, negative ion source development and metal charge carriers. The company, National Electrostatics, under his direction manufactured the accelerator which still holds the world's record for the highest sustained potential difference of 32±1.5 MV. Throughout his career he led teams which made the electrostatic accelerator a valuable tool for applications in a wide variety of scientific fields, well beyond nuclear physics.

Ion source based on the cathodic arc

DOEpatents

Sanders, D.M.; Falabella, S.

1994-02-01

A cylindrically symmetric arc source to produce a ring of ions which leave the surface of the arc target radially and are reflected by electrostatic fields present in the source to a point of use, such as a part to be coated, is described. An array of electrically isolated rings positioned in the source serves the dual purpose of minimizing bouncing of macroparticles and providing electrical insulation to maximize the electric field gradients within the source. The source also includes a series of baffles which function as a filtering or trapping mechanism for any macroparticles. 3 figures.

Symplectic orbit and spin tracking code for all-electric storage rings

NASA Astrophysics Data System (ADS)

Talman, Richard M.; Talman, John D.

2015-07-01

Proposed methods for measuring the electric dipole moment (EDM) of the proton use an intense, polarized proton beam stored in an all-electric storage ring "trap." At the "magic" kinetic energy of 232.792 MeV, proton spins are "frozen," for example always parallel to the instantaneous particle momentum. Energy deviation from the magic value causes in-plane precession of the spin relative to the momentum. Any nonzero EDM value will cause out-of-plane precession—measuring this precession is the basis for the EDM determination. A proposed implementation of this measurement shows that a proton EDM value of 10-29e -cm or greater will produce a statistically significant, measurable precession after multiply repeated runs, assuming small beam depolarization during 1000 s runs, with high enough precision to test models of the early universe developed to account for the present day particle/antiparticle population imbalance. This paper describes an accelerator simulation code, eteapot, a new component of the Unified Accelerator Libraries (ual), to be used for long term tracking of particle orbits and spins in electric bend accelerators, in order to simulate EDM storage ring experiments. Though qualitatively much like magnetic rings, the nonconstant particle velocity in electric rings gives them significantly different properties, especially in weak focusing rings. Like the earlier code teapot (for magnetic ring simulation) this code performs exact tracking in an idealized (approximate) lattice rather than the more conventional approach, which is approximate tracking in a more nearly exact lattice. The Bargmann-Michel-Telegdi (BMT) equation describing the evolution of spin vectors through idealized bend elements is also solved exactly—original to this paper. Furthermore the idealization permits the code to be exactly symplectic (with no artificial "symplectification"). Any residual spurious damping or antidamping is sufficiently small to permit reliable tracking for the long times, such as the 1000 s assumed in estimating the achievable EDM precision. This paper documents in detail the theoretical formulation implemented in eteapot. An accompanying paper describes the practical application of the eteapot code in the Universal Accelerator Libraries (ual) environment to "resurrect," or reverse engineer, the "AGS-analog" all-electric ring built at Brookhaven National Laboratory in 1954. Of the (very few) all-electric rings ever commissioned, the AGS-analog ring is the only relativistic one and is the closest to what is needed for measuring proton (or, even more so, electron) EDM's. The companion paper also describes preliminary lattice studies for the planned proton EDM storage rings as well as testing the code for long time orbit and spin tracking.

Instrumentation for the study of low emittance tuning and beam dynamics at CESR

NASA Astrophysics Data System (ADS)

Billing, M. G.; Dobbins, J. A.; Forster, M. J.; Kreinick, D. L.; Meller, R. E.; Peterson, D. P.; Ramirez, G. A.; Rendina, M. C.; Rider, N. T.; Sagan, D. C.; Shanks, J.; Sikora, J. P.; Stedinger, M. G.; Strohman, C. R.; Williams, H. A.; Palmer, M. A.; Holtzapple, R. L.; Flanagan, J.

2017-11-01

The Cornell Electron-positron Storage Ring (CESR) has been converted from a High Energy Physics electron-positron collider to operate as a dedicated synchrotron light source for the Cornell High Energy Synchrotron Source (CHESS) and to conduct accelerator physics research as a test accelerator, capable of studying topics relevant to future damping rings, colliders and light sources. Some of the specific topics that were targeted for the initial phase of operation of the storage ring in this mode for CESR as a Test Accelerator (CesrTA) included 1) tuning techniques to produce low emittance beams, 2) the study of electron cloud development in a storage ring and 3) intra-beam scattering effects. The complete conversion of CESR to CesrTA occurred over a several year period, described elsewhere [1-3]. In addition to instrumentation for the storage ring, which was created for CesrTA, existing instrumentation was modified to facilitate the entire range of investigations to support these studies. Procedures were developed, often requiring coordinated measurements among different instruments [4]. This paper describes the instruments utilized for the study of beam dynamics during the operation of CesrTA. The treatment of these instruments will remain fairly general in this paper as it focusses on an overview of the instruments themselves. Their interaction and inter-relationships during sequences of observations is found in a companion paper describing the associated measurement techniques. More detailed descriptions and detailed operational performance for some of the instrumentation may be found elsewhere and these will be referenced in the related sections of this paper.

Ionic tethering contributes to the conformational stability and function of complement C3b.

PubMed

López-Perrote, Andrés; Harrison, Reed E S; Subías, Marta; Alcorlo, Martín; Rodríguez de Córdoba, Santiago; Morikis, Dimitrios; Llorca, Oscar

2017-05-01

C3b, the central component of the alternative pathway (AP) of the complement system, coexists as a mixture of conformations in solution. These conformational changes can affect interactions with other proteins and complement regulators. Here we combine a computational model for electrostatic interactions within C3b with molecular imaging to study the conformation of C3b. The computational analysis shows that the TED domain in C3b is tethered ionically to the macroglobulin (MG) ring. Monovalent counterion concentration affects the magnitude of electrostatic forces anchoring the TED domain to the rest of the C3b molecule in a thermodynamic model. This is confirmed by observing NaCl concentration dependent conformational changes using single molecule electron microscopy (EM). We show that the displacement of the TED domain is compatible with C3b binding to Factor B (FB), suggesting that the regulation of the C3bBb convertase could be affected by conditions that promote movement in the TED domain. Our molecular model also predicts mutations that could alter the positioning of the TED domain, including the common R102G polymorphism, a risk variant for developing age-related macular degeneration. The common C3b isoform, C3bS, and the risk isoform, C3bF, show distinct energetic barriers to displacement in the TED that are related to a network of electrostatic interactions at the interface of the TED and MG-ring domains of C3b. These computational predictions agree with experimental evidence that shows differences in conformation observed in C3b isoforms purified from homozygous donors. Altogether, we reveal an ionic, reversible attachment of the TED domain to the MG ring that may influence complement regulation in some mutations and polymorphisms of C3b. Copyright © 2016 Elsevier Ltd. All rights reserved.

Capturing spiral radial growth of conifers using the superellipse to model tree-ring geometric shape

PubMed Central

Shi, Pei-Jian; Huang, Jian-Guo; Hui, Cang; Grissino-Mayer, Henri D.; Tardif, Jacques C.; Zhai, Li-Hong; Wang, Fu-Sheng; Li, Bai-Lian

2015-01-01

Tree-rings are often assumed to approximate a circular shape when estimating forest productivity and carbon dynamics. However, tree rings are rarely, if ever, circular, thereby possibly resulting in under- or over-estimation in forest productivity and carbon sequestration. Given the crucial role played by tree ring data in assessing forest productivity and carbon storage within a context of global change, it is particularly important that mathematical models adequately render cross-sectional area increment derived from tree rings. We modeled the geometric shape of tree rings using the superellipse equation and checked its validation based on the theoretical simulation and six actual cross sections collected from three conifers. We found that the superellipse better describes the geometric shape of tree rings than the circle commonly used. We showed that a spiral growth trend exists on the radial section over time, which might be closely related to spiral grain along the longitudinal axis. The superellipse generally had higher accuracy than the circle in predicting the basal area increment, resulting in an improved estimate for the basal area. The superellipse may allow better assessing forest productivity and carbon storage in terrestrial forest ecosystems. PMID:26528316

Capturing spiral radial growth of conifers using the superellipse to model tree-ring geometric shape.

PubMed

Shi, Pei-Jian; Huang, Jian-Guo; Hui, Cang; Grissino-Mayer, Henri D; Tardif, Jacques C; Zhai, Li-Hong; Wang, Fu-Sheng; Li, Bai-Lian

2015-01-01

Tree-rings are often assumed to approximate a circular shape when estimating forest productivity and carbon dynamics. However, tree rings are rarely, if ever, circular, thereby possibly resulting in under- or over-estimation in forest productivity and carbon sequestration. Given the crucial role played by tree ring data in assessing forest productivity and carbon storage within a context of global change, it is particularly important that mathematical models adequately render cross-sectional area increment derived from tree rings. We modeled the geometric shape of tree rings using the superellipse equation and checked its validation based on the theoretical simulation and six actual cross sections collected from three conifers. We found that the superellipse better describes the geometric shape of tree rings than the circle commonly used. We showed that a spiral growth trend exists on the radial section over time, which might be closely related to spiral grain along the longitudinal axis. The superellipse generally had higher accuracy than the circle in predicting the basal area increment, resulting in an improved estimate for the basal area. The superellipse may allow better assessing forest productivity and carbon storage in terrestrial forest ecosystems.

Inference of the ring current ion composition by means of charge exchange decay

NASA Technical Reports Server (NTRS)

Smith, P. H.; Hoffman, R. A.; Bewtra, N. K.

1981-01-01

The analysis of data from the Explorer 45 (S3-A) electrostatic analyzer in the energy range 5-30 keV has provided some new results on the ring current ion composition. It has been well established that the storm time ring current has a decay time of several days, during which the particle fluxes decrease nearly monotonically. By analyzing the measured ion fluxes during the several day storm recovery period and assuming that beside hydrogen other ions were present and that the decays were exponential in nature, three separate lifetimes for the ions were established. These fitted decay lifetimes are in excellent agreement with the expected charge exchange decay lifetimes for H(+), O(+) and He(+) in the energy and L value range of the data.

Resonant structure of low-energy H3+ dissociative recombination

NASA Astrophysics Data System (ADS)

Petrignani, Annemieke; Altevogt, Simon; Berg, Max H.; Bing, Dennis; Grieser, Manfred; Hoffmann, Jens; Jordon-Thaden, Brandon; Krantz, Claude; Mendes, Mario B.; Novotný, Oldřich; Novotny, Steffen; Orlov, Dmitry A.; Repnow, Roland; Sorg, Tobias; Stützel, Julia; Wolf, Andreas; Buhr, Henrik; Kreckel, Holger; Kokoouline, Viatcheslav; Greene, Chris H.

2011-03-01

High-resolution dissociative recombination rate coefficients of rotationally cool and hot H3+ in the vibrational ground state have been measured with a 22-pole trap setup and a Penning ion source, respectively, at the ion storage-ring TSR. The experimental results are compared with theoretical calculations to explore the dependence of the rate coefficient on ion temperature and to study the contributions of different symmetries to probe the rich predicted resonance spectrum. The kinetic energy release was investigated by fragment imaging to derive internal temperatures of the stored parent ions under differing experimental conditions. A systematic experimental assessment of heating effects is performed which, together with a survey of other recent storage-ring data, suggests that the present rotationally cool rate-coefficient measurement was performed at 380-130+50 K and that this is the lowest rotational temperature so far realized in storage-ring rate-coefficient measurements on H3+. This partially supports the theoretical suggestion that temperatures higher than assumed in earlier experiments are the main cause for the large gap between the experimental and the theoretical rate coefficients. For the rotationally hot rate-coefficient measurement a temperature of below 3250 K is derived. From these higher-temperature results it is found that increasing the rotational ion temperature in the calculations cannot fully close the gap between the theoretical and the experimental rate coefficients.

Storage Rings in the Sky: Gamma Ray Bursts and Galactic Gravitational Collapse Stored Energy

NASA Astrophysics Data System (ADS)

Greyber, H. D.

2004-05-01

The recent discovery of almost 100% polarization of the prompt gamma ray emission from GRB021206, (1), confirms my 44 year old ``Strong" Magnetic Field" model (SMF) for galactic dynamics. In SMF, Storage Ring particles were accelerated long ago during the original gravitational collapse of the pregalactic/prequasar plasma cloud that is permeated by an almost uniform primordial magnetic field (2,3) The enormous, intense, slender, relativistic, stable, completely coherent Storage Ring stores a very small fraction of the huge galactic gravitational collapse energy in an almost radiationless state, unless disturbed. The concept of an Astrophysical Storage Ring was introduced by me in l961. At first it was to explain galactic structure, but soon it proved useful to explain active galactic nuclei (AGN) and the dynamics of quasar/AGN jets. AGN and galactic morphology, energetics and dynamics vary as the ratio of magnetic energy to rotational energy in the particular object. Gamma ray bursts (GRB) are due simply to a ``rock". i.e. a white dwarf, ordinary star, neutron sstar, asteroid, planet, etc. falling rapidly through the Storage Ring and being almost instantly vaporized into a hot plasma fireball, causing an electromagnetic shower (2) Then the fireball speeds into the huge organized magnetic field surrounding the current ring, thus generating very highly polarized prompt gamma ray emission (as seen in GRB021206) from the synchrotron radiation process. The timing fits the GRB observations nicely. For instance, a ``rock" racing at 1000 kilometers per second across a 20,000 km. path in the beam would produce a twenty second burst. Other times, a target might track across a short chord for a short burst. Space missions have shown that often typical currents in space plasmas are made up of slender filaments. Thus the puzzling less than one millisecond spikes observed in some GRB are simply describing the structure of that particular ring current at that particular time. 1. W. Coburn and S.E. Boggs, Nature, 423, 415, (2003) 2. H. D. Greyber in a book, After the Dark Ages: When Galaxies Were Young, eds. S.S. Holt and E. P. Smith, AIP Conference Proceedings 470, 388-396. (1998) 3. H. D. Greyber in a Space Telescope Science Institute Report: Poster Papers from their 2001 Spring Symposium, ``The Dark Universe: Matter, Energy and Gravity," ed. Mario Livio, published March 2003, (34-39)

Beamline front end for in-vacuum short period undulator at the photon factory storage ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miyauchi, Hiroshi, E-mail: hiroshi.miyauchi@kek.jp; Department of Accelerator Science, School of High Energy Accelerator Science, SOKENDAI; Tahara, Toshihiro, E-mail: ttahara@post.kek.jp

The straight-section upgrade project of the Photon Factory created four new short straight sections capable of housing in-vacuum short period undulators. The first to fourth short period undulators SGU#17, SGU#03, SGU#01 and SGU#15 were installed at the 2.5-GeV Photon Factory storage ring in 2005, 2006, 2009 and 2013, respectively. The beamline front end for SGU#15 is described in this paper.

A storage ring experiment to detect a proton electric dipole moment

DOE PAGES

Anastassopoulos, V.; Andrianov, S.; Baartman, R.; ...

2016-11-29

We describe a new experiment to detect a permanent electric dipole moment of the proton with a sensitivity of 10 $-$29e cm by using polarized “magic” momentum 0.7 GeV/c protons in an all-electric storage ring. Systematic errors relevant to the experiment are discussed and techniques to address them are presented. The measurement is sensitive to new physics beyond the Standard Model at the scale of 3000 TeV.

A storage ring experiment to detect a proton electric dipole moment.

PubMed

Anastassopoulos, V; Andrianov, S; Baartman, R; Baessler, S; Bai, M; Benante, J; Berz, M; Blaskiewicz, M; Bowcock, T; Brown, K; Casey, B; Conte, M; Crnkovic, J D; D'Imperio, N; Fanourakis, G; Fedotov, A; Fierlinger, P; Fischer, W; Gaisser, M O; Giomataris, Y; Grosse-Perdekamp, M; Guidoboni, G; Hacıömeroğlu, S; Hoffstaetter, G; Huang, H; Incagli, M; Ivanov, A; Kawall, D; Kim, Y I; King, B; Koop, I A; Lazarus, D M; Lebedev, V; Lee, M J; Lee, S; Lee, Y H; Lehrach, A; Lenisa, P; Levi Sandri, P; Luccio, A U; Lyapin, A; MacKay, W; Maier, R; Makino, K; Malitsky, N; Marciano, W J; Meng, W; Meot, F; Metodiev, E M; Miceli, L; Moricciani, D; Morse, W M; Nagaitsev, S; Nayak, S K; Orlov, Y F; Ozben, C S; Park, S T; Pesce, A; Petrakou, E; Pile, P; Podobedov, B; Polychronakos, V; Pretz, J; Ptitsyn, V; Ramberg, E; Raparia, D; Rathmann, F; Rescia, S; Roser, T; Kamal Sayed, H; Semertzidis, Y K; Senichev, Y; Sidorin, A; Silenko, A; Simos, N; Stahl, A; Stephenson, E J; Ströher, H; Syphers, M J; Talman, J; Talman, R M; Tishchenko, V; Touramanis, C; Tsoupas, N; Venanzoni, G; Vetter, K; Vlassis, S; Won, E; Zavattini, G; Zelenski, A; Zioutas, K

2016-11-01

A new experiment is described to detect a permanent electric dipole moment of the proton with a sensitivity of 10 -29 e ⋅ cm by using polarized "magic" momentum 0.7 GeV/c protons in an all-electric storage ring. Systematic errors relevant to the experiment are discussed and techniques to address them are presented. The measurement is sensitive to new physics beyond the standard model at the scale of 3000 TeV.

A storage ring experiment to detect a proton electric dipole moment

NASA Astrophysics Data System (ADS)

Anastassopoulos, V.; Andrianov, S.; Baartman, R.; Baessler, S.; Bai, M.; Benante, J.; Berz, M.; Blaskiewicz, M.; Bowcock, T.; Brown, K.; Casey, B.; Conte, M.; Crnkovic, J. D.; D'Imperio, N.; Fanourakis, G.; Fedotov, A.; Fierlinger, P.; Fischer, W.; Gaisser, M. O.; Giomataris, Y.; Grosse-Perdekamp, M.; Guidoboni, G.; Hacıömeroǧlu, S.; Hoffstaetter, G.; Huang, H.; Incagli, M.; Ivanov, A.; Kawall, D.; Kim, Y. I.; King, B.; Koop, I. A.; Lazarus, D. M.; Lebedev, V.; Lee, M. J.; Lee, S.; Lee, Y. H.; Lehrach, A.; Lenisa, P.; Levi Sandri, P.; Luccio, A. U.; Lyapin, A.; MacKay, W.; Maier, R.; Makino, K.; Malitsky, N.; Marciano, W. J.; Meng, W.; Meot, F.; Metodiev, E. M.; Miceli, L.; Moricciani, D.; Morse, W. M.; Nagaitsev, S.; Nayak, S. K.; Orlov, Y. F.; Ozben, C. S.; Park, S. T.; Pesce, A.; Petrakou, E.; Pile, P.; Podobedov, B.; Polychronakos, V.; Pretz, J.; Ptitsyn, V.; Ramberg, E.; Raparia, D.; Rathmann, F.; Rescia, S.; Roser, T.; Kamal Sayed, H.; Semertzidis, Y. K.; Senichev, Y.; Sidorin, A.; Silenko, A.; Simos, N.; Stahl, A.; Stephenson, E. J.; Ströher, H.; Syphers, M. J.; Talman, J.; Talman, R. M.; Tishchenko, V.; Touramanis, C.; Tsoupas, N.; Venanzoni, G.; Vetter, K.; Vlassis, S.; Won, E.; Zavattini, G.; Zelenski, A.; Zioutas, K.

2016-11-01

A new experiment is described to detect a permanent electric dipole moment of the proton with a sensitivity of 10-29 e ṡ cm by using polarized "magic" momentum 0.7 GeV/c protons in an all-electric storage ring. Systematic errors relevant to the experiment are discussed and techniques to address them are presented. The measurement is sensitive to new physics beyond the standard model at the scale of 3000 TeV.

The Status of the Taiwan Photon Source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuo, C. C.; Wang, J. P.; Chen, J. R.

2010-06-23

NSRRC has been operating a 1.5 GeV synchrotron light source, the Taiwan Light Source (TLS), for over 15 years and has established a large user community. For the future development of synchrotron radiation research in Taiwan, a feasibility study report to construct a 3.0 GeV low-emittance storage ring, the Taiwan Photon Source (TPS), was issued in July 2005. The government approval of the TPS project was obtained in December 2007 and the machine will be built at current site of NSRRC. The project has progressed steadily since and reached several major milestones now: the architect firm has finished the sitemore » plan and civil design, the accelerator design has been fixed, and purchase of long-lead items begins its course. The TPS storage ring has a circumference of 518.4 meters with a concentric booster of 496.8 meters. The storage ring adopted a 24-cell double-bend structure with a 1.6 nm-rad natural emittance. There are six 12-m and eighteen 7-m ID straights. For user research, five new beamlines have been selected for the Phase I operations: the micro protein crystallography, the materials sub-micron diffraction, the inelastic soft x-ray scattering, the coherent x-ray scattering, and the nano probe beamlines. The civil construction is getting ready to start. The commissioning of the TPS storage ring is targeted for 2013.« less

Conditioning of BPM pickup signals for operations of the Duke storage ring with a wide range of single-bunch current

NASA Astrophysics Data System (ADS)

Xu, Wei; Li, Jing-Yi; Huang, Sen-Lin; Z. Wu, W.; Hao, H.; P., Wang; K. Wu, Y.

2014-10-01

The Duke storage ring is a dedicated driver for the storage ring based oscillator free-electron lasers (FELs), and the High Intensity Gamma-ray Source (HIGS). It is operated with a beam current ranging from about 1 mA to 100 mA per bunch for various operations and accelerator physics studies. High performance operations of the FEL and γ-ray source require a stable electron beam orbit, which has been realized by the global orbit feedback system. As a critical part of the orbit feedback system, the electron beam position monitors (BPMs) are required to be able to precisely measure the electron beam orbit in a wide range of the single-bunch current. However, the high peak voltage of the BPM pickups associated with high single-bunch current degrades the performance of the BPM electronics, and can potentially damage the BPM electronics. A signal conditioning method using low pass filters is developed to reduce the peak voltage to protect the BPM electronics, and to make the BPMs capable of working with a wide range of single-bunch current. Simulations and electron beam based tests are performed. The results show that the Duke storage ring BPM system is capable of providing precise orbit measurements to ensure highly stable FEL and HIGS operations.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Daugherty, W.; Mcwilliams, A.; Skidmore, E.

The 9975 Type B shipping package is used within the DOE complex for shipping special nuclear materials. This package is re-certified annually in accordance with Safety Analysis Report requirements. The package is also used at the Savannah River Site as part of the long-term storage configuration of special nuclear materials. As such, the packages do not undergo annual recertification during storage, with uncertainty as to how long some of the package components will meet their functional requirements in the storage environment. The packages are currently approved for up to 15 years storage, and work continues to provide a technical basismore » to extend that period. This paper describes efforts by the Savannah River National Laboratory (SRNL) to extend the service life estimate of Viton® GLT and GLT-S fluoroelastomer O-rings used in the 9975 shipping package. O-rings of both compositions are undergoing accelerated aging at elevated temperature, and are periodically tested for compression stress relaxation (CSR) behavior and leak performance. The CSR behavior of O-rings was evaluated at temperatures from 79 °C to 177 °C. These collective data were used to develop predictive models for extrapolation of CSR behavior to relevant service temperatures (< 75 °C). O-rings were also aged in Primary Containment Vessel (PCV) fixtures at temperatures ranging from 79 °C to 232 °C. The fixtures are helium leak tested periodically to determine if they remain leak-tight. The PCV fixture tests demonstrate that the 9975 O-rings will remain leak-tight at temperatures up to 149 °C for 3 years or more, and no leak failures have been observed with up to 8 years aging at 93 °C. Significantly longer periods of leak-tight service are expected at the lower temperatures actually experienced in the storage environment. The predictive model developed from the CSR data conservatively indicates a service life of more than 20 years at the bounding temperature of 75 °C. Although the relationship between CSR behavior and leak-tight performance has not been established for this design, the CSR predictions for this O-ring are conservative relative to leak-tight performance to date.« less

Electrostatic-Dipole (ED) Fusion Confinement Studies

NASA Astrophysics Data System (ADS)

Miley, George H.; Shrestha, Prajakti J.; Yang, Yang; Thomas, Robert

2004-11-01

The Electrostatic-Dipole (ED) concept significantly differs from a "pure" dipole confinement device [1] in that the charged particles are preferentially confined to the high-pressure region interior of the dipole coil by the assistance of a surrounding spherical electrostatic grid. In present ED experiments, a current carrying coil is embedded inside the grid of an IEC such as to produce a magnetic dipole field. Charged particles are injected axisymmetrically from an ion gun (or duo-plasmatron) into the center of the ED confinement grid/dipole ring where they oscillate along the magnetic field lines and pass the peak field region at the center of the dipole region. As particles begin accelerating away from the center region towards the outer electrostatic grid region, they encounter a strong electrostatic potential (order of 10's of kilovolts) retarding force. The particles then decelerate, reverse direction and re-enter the dipole field region where again magnetic confinement dominates. This process continues, emulating a complex harmonic oscillator motion. The resulting pressure profile averaged over the field curvature offers good plasma stability in the ED configuration. The basic concept and results from preliminary experiments will be described. [1] M.E. Mauel, et al. "Dipole Equilibrium and Stability," 18th IAEA Conference of Plasma Phys. and Control. Nuclear Fusion, Varenna, Italy 2000, IAEA-F1-CN-70/TH

Design of 3 GeV booster ring lattice

DOE Office of Scientific and Technical Information (OSTI.GOV)

Etisken, O., E-mail: ozgur.etisken@cern.ch; Ciftci, A. K., E-mail: abbas.kenan.ciftci@cern.ch

2016-03-25

The aim of this study is to design of a 3 GeV booster ring for the 3 GeV storage ring. Electrons are needed to be accelerated to 3.0 GeV from 0.15 GeV energy. In this frame, we studied on two options for booster ring; a compact booster and the booster that shares the same tunnel with the storage ring. The lattice type has been chosen FODO for both options, lattice parameters are calculated, sextupole magnets are used to decrease dynamic aperture problem and dynamic aperture calculations are also made with considering of the necessary conditions. After designing and calculating ofmore » the parameters, these designs have been compared with each other. In addition to this comparison, these booster design parameters have been compared with some world centers design parameters and the reliability of the booster design is seen. Beam optics, OPA and Elegant simulation programs have been used in the study calculations.« less

Spectroscopic, single crystal X-ray, Hirshfeld, in vitro and in silico biological evaluation of a new series of potent thiazole nucleus integrated with pyrazoline scaffolds

NASA Astrophysics Data System (ADS)

Salian, Vinutha V.; Narayana, Badiadka; Sarojini, Balladka K.; Kumar, Madan S.; Nagananda, Govinahalli S.; Byrappa, Kullaiah; Kudva, Avinash K.

2017-03-01

In the present study, the spectroscopic characterization of a new series of substituted thiazole linked pyrazoline scaffolds 4a-l was performed. The formation of 4a-l from the intermediate 3-(4-chlorophenyl)-5-[4-(propan-2-yl)phenyl]-4,5-dihydro-1H-pyrazole-1-carbothioamide 2 and substituted 2-bromo-1-phenylethanone 3a-l was evidenced through the changes in FTIR, 1H NMR, 13C NMR, LCMS data. The X-ray diffraction studies revealed that compound 2 and 4g crystallized in monoclinic crystal system with P21/n space group. Compound 4j crystallized in triclinic system, P1¯ space group with Z = 4. The percentage of intermolecular contacts and distribution of electrostatic potential of molecular crystal structures was resolved by Hirshfeld surface analysis with 2D finger plots and electrostatic potential map. The newly synthesized derivatives were screened for their in vitro antioxidant and antimicrobial activity. The single crystal studies revealed that, for compounds 2, 4g and 4j the isopropyl phenyl ring is positioned at near right angle with the other rings. Due to the lack of planarity of bulkier group substituted to phenyl ring (ring B), all the synthesized molecules showed weak to moderate radical scavenging capacity owing to the destabilization of the radical formed during oxidation. Also, on performing molecular docking studies to explore the interactions of ligand with the target pyrimidine nucleoside hydrolase YbeK with bound ribose complex (PNH, PDB ID-3GHW), disclosed that active compounds emerged for in vitro studies also bound to PNH more efficiently. The compounds with polar group substitution interacted through hydrogen bonding while other molecules with non-covalent interactions.

Design of an electrostatic phase shifting device for biological transmission electron microscopy.

PubMed

Koeck, Philip J B

2018-04-01

I suggest an electrostatic phase plate designed to broaden the contrast transfer function of a transmission electron microscope operated close to Scherzer defocus primarily in the low resolution direction. At higher defocus the low frequency behavior is equal to that close to Scherzer defocus, but CTF-correction becomes necessary to extend image interpretation to higher resolution. One simple realization of the phase plate consists of two ring shaped electrodes symmetrically surrounding the central beam. Since no physical components come into contact with the central beam and charge on the electrodes is controlled by an external voltage supply, problems with uncontrolled charging are expected to be reduced. Copyright © 2018 Elsevier B.V. All rights reserved.

Intra-Beam Scattering, Impedance, and Instabilities in Ultimate Storage Rings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bane, Karl; /SLAC

We have investigated collective effects in an ultimate storage ring, i.e. one with diffraction limited emittances in both planes, using PEP-X as an example. In an ultimate ring intra-beam scattering (IBS) sets the limit of current that can be stored. In PEP-X, a 4.5 GeV ring running round beams at 200 mA in 3300 bunches, IBS doubles the emittances to 11.5 pm at the design current. The Touschek lifetime is 11 hours. Impedance driven collective effects tend not to be important since the beam current is relatively low. We have investigated collective effects in PEP-X, an ultimate storage ring, i.e.more » one with diffraction limited emittances (at one angstrom wavelength) in both planes. In an ultimate ring intra-beam scattering (IBS) sets the limit of current that can be stored. In PEP-X, IBS doubles the emittances to 11.5 pm at the design current of 200 mA, assuming round beams. The Touschek lifetime is quite large in PEP-X, 11.6 hours, and - near the operating point - increases with decreasing emittance. It is, however, a very sensitive function of momentum acceptance. In an ultimate ring like PEP-X impedance driven collective effects tend not to be important since the beam current is relatively low. Before ultimate PEP-X can be realized, the question of how to run a machine with round beams needs serious study. For example, in this report we assumed that the vertical emittance is coupling dominated. It may turn out that using vertical dispersion is a preferable way to generate round beams. The choice will affect IBS and the Touschek effect.« less

Properties of the electron cloud in a high-energy positron and electron storage ring

DOE PAGES

Harkay, K. C.; Rosenberg, R. A.

2003-03-20

Low-energy, background electrons are ubiquitous in high-energy particle accelerators. Under certain conditions, interactions between this electron cloud and the high-energy beam can give rise to numerous effects that can seriously degrade the accelerator performance. These effects range from vacuum degradation to collective beam instabilities and emittance blowup. Although electron-cloud effects were first observed two decades ago in a few proton storage rings, they have in recent years been widely observed and intensely studied in positron and proton rings. Electron-cloud diagnostics developed at the Advanced Photon Source enabled for the first time detailed, direct characterization of the electron-cloud properties in amore » positron and electron storage ring. From in situ measurements of the electron flux and energy distribution at the vacuum chamber wall, electron-cloud production mechanisms and details of the beam-cloud interaction can be inferred. A significant longitudinal variation of the electron cloud is also observed, due primarily to geometrical details of the vacuum chamber. Furthermore, such experimental data can be used to provide realistic limits on key input parameters in modeling efforts, leading ultimately to greater confidence in predicting electron-cloud effects in future accelerators.« less

Status of NSLS-II Storage Ring Vacuum Systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Doom,L.; Hseuh,H.; Ferreira, M.

2009-05-04

National Synchrotron Light Source II (NSLS-II), being constructed at Brookhaven National Laboratory, is a 3-GeV, high-flux and high- brightness synchrotron radiation facility with a nominal current of 500 mA. The storage ring vacuum system will have extruded aluminium chambers with ante-chamber for photon fans and distributed NEG strip pumping. Discrete photon absorbers will be used to intercept the un-used bending magnet radiation. In-situ bakeout will be implemented to achieve fast conditioning during initial commissioning and after interventions.

Saw-tooth instability in storage rings: simulations and dynamical model

NASA Astrophysics Data System (ADS)

Migliorati, M.; Palumbo, L.; Dattoli, G.; Mezi, L.

1999-11-01

The saw-tooth instability in storage rings is studied by means of a time-domain simulation code which takes into account the self-induced wake fields. The results are compared with those from a dynamical heuristic model exploiting two coupled non-linear differential equations, accounting for the time behavior of the instability growth rate and for the anomalous growth of the energy spread. This model is shown to reproduce the characteristic features of the instability in a fairly satisfactory way.

A storage ring experiment to detect a proton electric dipole moment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anastassopoulos, V.; Andrianov, S.; Baartman, R.

2016-11-01

A new experiment is described to detect a permanent electric dipole moment of the proton with a sensitivity ofmore » $$10^{-29}e\\cdot$$cm by using polarized "magic" momentum $0.7$~GeV/c protons in an all-electric storage ring. Systematic errors relevant to the experiment are discussed and techniques to address them are presented. The measurement is sensitive to new physics beyond the Standard Model at the scale of 3000~TeV.« less

Storage rings for spin-polarized hydrogen

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thompson, D.; Lovelace, R.V.E.; Lee, D.

1989-11-01

A strong-focusing storage ring is proposed for the long-term magnetic confinement of a collisional gas of neutral spin-polarized hydrogen atoms in the Za{l arrow} and Zb{l arrow} hyperfine states. The trap uses the interaction of the magnetic moments of the gas atoms with a static magnetic field. Laser cooling and evaporative cooling can be utilized to enhance the confinement and to offset the influence of viscous heating. An important application of the trap is to the attainment of Bose--Einstein condensation.

A Paramagnetic Molecular Voltmeter

PubMed Central

Surek, Jack T.; Thomas, David D.

2008-01-01

We have developed a general electron paramagnetic resonance (EPR) method to measure electrostatic potential at spin labels on proteins to millivolt accuracy. Electrostatic potential is fundamental to energy-transducing proteins like myosin, because molecular energy storage and retrieval is primarily electrostatic. Quantitative analysis of protein electrostatics demands a site-specific spectroscopic method sensitive to millivolt changes. Previous electrostatic potential studies on macromolecules fell short in sensitivity, accuracy and/or specificity. Our approach uses fast-relaxing charged and neutral paramagnetic relaxation agents (PRAs) to increase nitroxide spin label relaxation rate solely through collisional spin exchange. These PRAs were calibrated in experiments on small nitroxides of known structure and charge to account for differences in their relaxation efficiency. Nitroxide longitudinal (R1) and transverse (R2) relaxation rates were separated by applying lineshape analysis to progressive saturation spectra. The ratio of measured R1 increases for each pair of charged and neutral PRAs measures the shift in local PRA concentration due to electrostatic potential. Voltage at the spin label is then calculated using the Boltzmann equation. Measured voltages for two small charged nitroxides agree with Debye-Hückel calculations. Voltage for spin-labeled myosin fragment S1 also agrees with calculation based on the pK shift of the reacted cysteine. PMID:17964835

Photoswitchable Dihydroazulene Macrocycles for Solar Energy Storage: The Effects of Ring Strain.

PubMed

Vlasceanu, Alexandru; Frandsen, Benjamin N; Skov, Anders B; Hansen, Anne Schou; Rasmussen, Mads Georg; Kjaergaard, Henrik G; Mikkelsen, Kurt V; Nielsen, Mogens Brøndsted

2017-10-06

Efficient energy storage and release are two major challenges of solar energy harvesting technologies. The development of molecular solar thermal systems presents one approach to address these issues by tuning the isomerization reactions of photo/thermoswitches. Here we show that the incorporation of photoswitches into macrocyclic structures is a particularly attractive solution for increasing the storage time. We present the synthesis and properties of a series of macrocycles incorporating two dihydroazulene (DHA) photoswitching subunits, bridged by linkers of varying chain length. Independent of ring size, all macrocycles exhibit stepwise, light-induced, ring-opening reactions (DHA-DHA to DHA-VHF to VHF-VHF; VHF = vinylheptafulvene) with the first DHA undergoing isomerization with a similar efficiency as the uncyclized parent system while the second (DHA-VHF to VHF-VHF) is significantly slower. The energy-releasing, VHF-to-DHA, ring closures also occur in a stepwise manner and are systematically found to proceed slower in the more strained (smaller) cycles, but in all cases with a remarkably slow conversion of the second VHF to DHA. We managed to increase the half-life of the second VHF-to-DHA conversion from 65 to 202 h at room temperature by simply decreasing the ring size. A computational study reveals the smallest macrocycle to have the most energetic VHF-VHF state and hence highest energy density.

Nitrile/Buna N Material Failure Assessment for an O-Ring used on the Gaseous Hydrogen Flow Control Valve (FCV) of the Space Shuttle Main Engine

NASA Technical Reports Server (NTRS)

Wingard, Doug

2006-01-01

After the rollout of Space Shuttle Discovery in April 2005 in preparation for return-to-flight, there was a failure of the Orbiter (OV-103) helium signature leak test in the gaseous hydrogen (GH2) system. Leakage was attributed to the Flow Control Valve (FCV) in Main Engine 3. The FCV determined to be the source of the leak for OV-103 is designated as LV-58. The nitrile/Buna N rubber O-ring seal was removed from LV-58, and failure analysis indicated radial cracks providing leak paths in one quadrant. Cracks were eventually found in 6 of 9 FCV O-rings among the three Shuttle Orbiters, though none were as severe as those for LV-58, OV-103. Testing by EM10 at MSFC on all 9 FCV O- rings included: laser dimensional, Shore A hardness and properties from a dynamic mechanical analyzer (DMA) and an Instron tensile machine. The following test data was obtained on the cracked quadrant of the LV-58, OV-103 O-ring: (1) the estimated compression set was only 9.5%, compared to none for the rest of the O-ring; (2) Shore A hardness for the O.D. was higher by almost 4 durometer points than for the rest of the O-ring; and (3) DMA data showed that the storage/elastic modulus E was almost 25% lower than for the rest of the O-ring. Of the 8 FCV O-rings tested on an Instron, 4 yielded tensile strengths that were below the MIL spec requirement of 1350 psi-a likely influence of rubber cracking. Comparisons were made between values of modulus determined by DNA (elastic) and Instron (Young s). Each nitrile/Buna N O-ring used in the FCV conforms to the MIL-P-25732C specification. A number of such O-rings taken from shelf storage at MSFC and Kennedy Space Center (KSC) were used to generate a reference curve of DMA glass transition temperature (Tg) vs. shelf storage time ranging from 8 to 26 years. A similar reference curve of TGA onset temperature (of rubber weight loss) vs. shelf storage time was also generated. The DMA and TGA data for the used FCV O-rings were compared to the reference curves. Correlations were also made between the DMA modulus (at 22 C) and Shore A hardness for all 9 of the FCV O-rings used among the three Shuttle Orbiters. The radial cracking in the FCV O-rings was determined to be due to ozone attack, as nitrile/Buna N rubber is susceptible to such attack. Nitrile/Buna N material under MIL-P25732C should be used in a hydraulic fluid environment to help protect it from cracking. However, the FCV O-rings were used in an air only environment. The FCV design has as much as a 9-mil gap that allows the O.D. of the O-ring to be directly exposed to ozone, pressurized air and some elevated temperatures, accelerating the weathering process that leads to O-ring cracking. Space Shuttle flights will likely not continue past 2010. Therefore, Shuttle management decided to continue using the nitrile/Buna N material for the FCVs, but have each O-ring replaced after 3 years to minimize any chances for crack initiation.

Flexible matrix composite laminated disk/ring flywheel

NASA Technical Reports Server (NTRS)

Gupta, B. P.; Hannibal, A. J.

1984-01-01

An energy storage flywheel consisting of a quasi-isotropic composite disk overwrapped by a circumferentially wound ring made of carbon fiber and a elastometric matrix is proposed. Through analysis it was demonstrated that with an elastomeric matrix to relieve the radial stresses, a laminated disk/ring flywheel can be designed to store a least 80.3 Wh/kg or about 68% more than previous disk/ring designs. at the same time the simple construction is preserved.

Electrostatic Interactions in Aminoglycoside-RNA Complexes

PubMed Central

Kulik, Marta; Goral, Anna M.; Jasiński, Maciej; Dominiak, Paulina M.; Trylska, Joanna

2015-01-01

Electrostatic interactions often play key roles in the recognition of small molecules by nucleic acids. An example is aminoglycoside antibiotics, which by binding to ribosomal RNA (rRNA) affect bacterial protein synthesis. These antibiotics remain one of the few valid treatments against hospital-acquired infections by Gram-negative bacteria. It is necessary to understand the amplitude of electrostatic interactions between aminoglycosides and their rRNA targets to introduce aminoglycoside modifications that would enhance their binding or to design new scaffolds. Here, we calculated the electrostatic energy of interactions and its per-ring contributions between aminoglycosides and their primary rRNA binding site. We applied either the methodology based on the exact potential multipole moment (EPMM) or classical molecular mechanics force field single-point partial charges with Coulomb formula. For EPMM, we first reconstructed the aspherical electron density of 12 aminoglycoside-RNA complexes from the atomic parameters deposited in the University at Buffalo Databank. The University at Buffalo Databank concept assumes transferability of electron density between atoms in chemically equivalent vicinities and allows reconstruction of the electron densities from experimental structural data. From the electron density, we then calculated the electrostatic energy of interaction using EPMM. Finally, we compared the two approaches. The calculated electrostatic interaction energies between various aminoglycosides and their binding sites correlate with experimentally obtained binding free energies. Based on the calculated energetic contributions of water molecules mediating the interactions between the antibiotic and rRNA, we suggest possible modifications that could enhance aminoglycoside binding affinity. PMID:25650932

Structural analysis and the effect of cyclo(His-Pro) dipeptide on neurotoxins--a dynamics and density functional theory study.

PubMed

Abiram, Angamuthu; Kolandaivel, Ponmalai

2010-02-01

The switching propensity and maximum probability of occurrence of the side chain imidazole group in the dipeptide cyclo(His-Pro) (CHP) were studied by applying molecular dynamics simulations and density functional theory. The atomistic behaviour of CHP with the neurotoxins glutamate (E) and paraquat (Pq) were also explored; E and Pq engage in hydrogen bond formation with the diketopiperazine (DKP) ring of the dipeptide, with which E shows a profound interaction, as confirmed further by NH and CO stretching vibrational frequencies. The effect of CHP was found to be greater on E than on Pq neurotoxin. A ring puckering study indicated a twist boat conformation for the six-membered DKP ring. Molecular electrostatic potential (MESP) mapping was also used to explore the hydrogen bond interactions prevailing between the neurotoxins and the DKP ring. The results of this study reveal that the DKP ring of the dipeptide CHP can be expected to play a significant role in reducing effects such as oxidative stress and cell death caused by neurotoxins.

Electric dipole moment planning with a resurrected BNL Alternating Gradient Synchrotron electron analog ring

NASA Astrophysics Data System (ADS)

Talman, Richard M.; Talman, John D.

2015-07-01

There has been much recent interest in directly measuring the electric dipole moments (EDM) of the proton and the electron, because of their possible importance in the present day observed matter/antimatter imbalance in the Universe. Such a measurement will require storing a polarized beam of "frozen spin" particles, 15 MeV electrons or 230 MeV protons, in an all-electric storage ring. Only one such relativistic electric accelerator has ever been built—the 10 MeV "electron analog" ring at Brookhaven National Laboratory in 1954; it can also be referred to as the "AGS analog" ring to make clear it was a prototype for the Alternating Gradient Synchrotron (AGS) proton ring under construction at that time at BNL. (Its purpose was to investigate nonlinear resonances as well as passage through "transition" with the newly invented alternating gradient proton ring design.) By chance this electron ring, long since dismantled and its engineering drawings disappeared, would have been appropriate both for measuring the electron EDM and to serve as an inexpensive prototype for the arguably more promising, but 10 times more expensive, proton EDM measurement. Today it is cheaper yet to "resurrect" the electron analog ring by simulating its performance computationally. This is one purpose for the present paper. Most existing accelerator simulation codes cannot be used for this purpose because they implicitly assume magnetic bending. The new ual/eteapot code, described in detail in an accompanying paper, has been developed for modeling storage ring performance, including spin evolution, in electric rings. Illustrating its use, comparing its predictions with the old observations, and describing new expectations concerning spin evolution and code performance, are other goals of the paper. To set up some of these calculations has required a kind of "archeological physics" to reconstitute the detailed electron analog lattice design from a 1991 retrospective report by Plotkin as well as unpublished notes of Courant describing machine studies performed in 1954-1955. This paper describes the practical application of the eteapot code and provides sample results, with emphasis on emulating lattice optics in the AGS analog ring for comparison with the historical machine studies and to predict the electron spin evolution they would have measured if they had polarized electrons and electron polarimetry. Of greater present day interest is the performance to be expected for a proton storage ring experiment. To exhibit the eteapot code performance and confirm its symplecticity, results are also given for 30 million turn proton spin tracking in an all-electric lattice that would be appropriate for a present day measurement of the proton EDM. The accompanying paper "Symplectic orbit and spin tracking code for all-electric storage rings" documents in detail the theoretical formulation implemented in eteapot, which is a new module in the Unified Accelerator Libraries (ual) environment.

Phase measurement for driven spin oscillations in a storage ring

NASA Astrophysics Data System (ADS)

Hempelmann, N.; Hejny, V.; Pretz, J.; Soltner, H.; Augustyniak, W.; Bagdasarian, Z.; Bai, M.; Barion, L.; Berz, M.; Chekmenev, S.; Ciullo, G.; Dymov, S.; Eversmann, D.; Gaisser, M.; Gebel, R.; Grigoryev, K.; Grzonka, D.; Guidoboni, G.; Heberling, D.; Hetzel, J.; Hinder, F.; Kacharava, A.; Kamerdzhiev, V.; Keshelashvili, I.; Koop, I.; Kulikov, A.; Lehrach, A.; Lenisa, P.; Lomidze, N.; Lorentz, B.; Maanen, P.; Macharashvili, G.; Magiera, A.; Mchedlishvili, D.; Mey, S.; Müller, F.; Nass, A.; Nikolaev, N. N.; Nioradze, M.; Pesce, A.; Prasuhn, D.; Rathmann, F.; Rosenthal, M.; Saleev, A.; Schmidt, V.; Semertzidis, Y.; Senichev, Y.; Shmakova, V.; Silenko, A.; Slim, J.; Stahl, A.; Stassen, R.; Stephenson, E.; Stockhorst, H.; Ströher, H.; Tabidze, M.; Tagliente, G.; Talman, R.; Thörngren Engblom, P.; Trinkel, F.; Uzikov, Yu.; Valdau, Yu.; Valetov, E.; Vassiliev, A.; Weidemann, C.; Wrońska, A.; Wüstner, P.; Zuprański, P.; Żurek, M.; JEDI Collaboration

2018-04-01

This paper reports the first simultaneous measurement of the horizontal and vertical components of the polarization vector in a storage ring under the influence of a radio frequency (rf) solenoid. The experiments were performed at the Cooler Synchrotron COSY in Jülich using a vector polarized, bunched 0.97 GeV /c deuteron beam. Using the new spin feedback system, we set the initial phase difference between the solenoid field and the precession of the polarization vector to a predefined value. The feedback system was then switched off, allowing the phase difference to change over time, and the solenoid was switched on to rotate the polarization vector. We observed an oscillation of the vertical polarization component and the phase difference. The oscillations can be described using an analytical model. The results of this experiment also apply to other rf devices with horizontal magnetic fields, such as Wien filters. The precise manipulation of particle spins in storage rings is a prerequisite for measuring the electric dipole moment (EDM) of charged particles.

EUTERPE, a small electron storage ring for XRF

NASA Astrophysics Data System (ADS)

Botman, J. I. M.; Mutsaers, P. H. A.; Hagedoorn, H. L.; De Voigt, M. J. A.

1990-04-01

A small-sized electron storage ring is under construction at the Eindhoven University of Technology which will cover the energy range of 15 to 400 MeV. At top energy the characteristic wavelength of the synchrotron radiation spectrum is 8.3 nm for the regular dipole magnets and 1.2 nm corresponding to 1.06 keV for a 10 T wiggler magnet. This will provide useful radiation for X-ray fluorescence (XRF) up to 3.2 keV. Alternatively, photon conversion with a high power CO 2 laser beam of 0.124 eV photons will generate X-rays for XRF with energies ranging from 0.5 to 300 keV, depending on the operating energy of the storage ring. This facility will provide an important extension to the activities of the Eindhoven group on PIXE, RBS and microbeam analysis. A short description of the macnine will be given together with applications and specific examples of the XRF method.

Magnetic Measurements of Storage Ring Magnets for the APS Upgrade Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Doose, C.; Dejus, R.; Jaski, M.

2017-06-01

Extensive prototyping of storage ring magnets is ongoing at the Advanced Photon Source (APS) in support of the APS Multi-Bend Achromat (MBA) upgrade project (APS-U) [1]. As part of the R&D activities four quadrupole magnets with slightly different geometries and pole tip materials, and one sextupole magnet with vanadium permendur (VP) pole tips were designed, built and tested. Magnets were measured individually using a rotating coil and a Hall probe for detailed mapping of the magnetic field. Magnets were then assembled and aligned relative to each other on a steel support plate and concrete plinth using precision machined surfaces tomore » gain experience with the alignment method chosen for the APS-U storage ring magnets. The required alignment of magnets on a common support structure is 30 μm rms. Measurements of magnetic field quality, strength and magnet alignment after subjecting the magnets and assemblies to different tests are presented.« less

Constrained multi-objective optimization of storage ring lattices

NASA Astrophysics Data System (ADS)

Husain, Riyasat; Ghodke, A. D.

2018-03-01

The storage ring lattice optimization is a class of constrained multi-objective optimization problem, where in addition to low beam emittance, a large dynamic aperture for good injection efficiency and improved beam lifetime are also desirable. The convergence and computation times are of great concern for the optimization algorithms, as various objectives are to be optimized and a number of accelerator parameters to be varied over a large span with several constraints. In this paper, a study of storage ring lattice optimization using differential evolution is presented. The optimization results are compared with two most widely used optimization techniques in accelerators-genetic algorithm and particle swarm optimization. It is found that the differential evolution produces a better Pareto optimal front in reasonable computation time between two conflicting objectives-beam emittance and dispersion function in the straight section. The differential evolution was used, extensively, for the optimization of linear and nonlinear lattices of Indus-2 for exploring various operational modes within the magnet power supply capabilities.

ACCELERATORS: Beam based alignment of the SSRF storage ring

NASA Astrophysics Data System (ADS)

Zhang, Man-Zhou; Li, Hao-Hu; Jiang, Bo-Cheng; Liu, Gui-Min; Li, De-Ming

2009-04-01

There are 140 beam position monitors (BPMs) in the Shanghai Synchrotron Radiation Facility (SSRF) storage ring used for measuring the closed orbit. As the BPM pickup electrodes are assembled directly on the vacuum chamber, it is important to calibrate the electrical center offset of the BPM to an adjacent quadrupole magnetic center. A beam based alignment (BBA) method which varies individual quadrupole magnet strength and observes its effects on the orbit is used to measure the BPM offsets in both the horizontal and vertical planes. It is a completely automated technique with various data processing methods. There are several parameters such as the strength change of the correctors and the quadrupoles which should be chosen carefully in real measurement. After several rounds of BBA measurement and closed orbit correction, these offsets are set to an accuracy better than 10 μm. In this paper we present the method of beam based calibration of BPMs, the experimental results of the SSRF storage ring, and the error analysis.

Symplectic orbit and spin tracking code for all-electric storage rings

DOE PAGES

Talman, Richard M.; Talman, John D.

2015-07-22

Proposed methods for measuring the electric dipole moment (EDM) of the proton use an intense, polarized proton beam stored in an all-electric storage ring “trap.” At the “magic” kinetic energy of 232.792 MeV, proton spins are “frozen,” for example always parallel to the instantaneous particle momentum. Energy deviation from the magic value causes in-plane precession of the spin relative to the momentum. Any nonzero EDM value will cause out-of-plane precession—measuring this precession is the basis for the EDM determination. A proposed implementation of this measurement shows that a proton EDM value of 10 –29e–cm or greater will produce a statisticallymore » significant, measurable precession after multiply repeated runs, assuming small beam depolarization during 1000 s runs, with high enough precision to test models of the early universe developed to account for the present day particle/antiparticle population imbalance. This paper describes an accelerator simulation code, eteapot, a new component of the Unified Accelerator Libraries (ual), to be used for long term tracking of particle orbits and spins in electric bend accelerators, in order to simulate EDM storage ring experiments. Though qualitatively much like magnetic rings, the nonconstant particle velocity in electric rings gives them significantly different properties, especially in weak focusing rings. Like the earlier code teapot (for magnetic ring simulation) this code performs exact tracking in an idealized (approximate) lattice rather than the more conventional approach, which is approximate tracking in a more nearly exact lattice. The Bargmann-Michel-Telegdi (BMT) equation describing the evolution of spin vectors through idealized bend elements is also solved exactly—original to this paper. Furthermore the idealization permits the code to be exactly symplectic (with no artificial “symplectification”). Any residual spurious damping or antidamping is sufficiently small to permit reliable tracking for the long times, such as the 1000 s assumed in estimating the achievable EDM precision. This paper documents in detail the theoretical formulation implemented in eteapot. An accompanying paper describes the practical application of the eteapot code in the Universal Accelerator Libraries (ual) environment to “resurrect,” or reverse engineer, the “AGS-analog” all-electric ring built at Brookhaven National Laboratory in 1954. Of the (very few) all-electric rings ever commissioned, the AGS-analog ring is the only relativistic one and is the closest to what is needed for measuring proton (or, even more so, electron) EDM’s. As a result, the companion paper also describes preliminary lattice studies for the planned proton EDM storage rings as well as testing the code for long time orbit and spin tracking.« less

Coordinated Research Program in Pulsed Power Physics.

DTIC Science & Technology

1984-12-20

heated array of Inductive energy storage is attractive in pulsed power 375-/am-diameter thoriated tungsten filaments. At a flia- applications because of...control system electrostatical- ly. It is positioned 0.6 cm above the control grid. The grids and cathode are connected to external power supplies through...energy storage density becomes even larger (by a factor of - 10). One should note that these comparisons do not account for power supplies , cooling

DOE Office of Scientific and Technical Information (OSTI.GOV)

Eriksson, Mikael

Not very long ago, the 3{sup rd} generation storage ring technology was judged as mature. Most of the 3{sup rd} generation storage rings used the Double-Bend Achromat (DBA) or Triple-Bend Achromat (TBA) concepts. It was however a well-known fact that increasing the number of magnet cells in the rings is a powerful way of decreasing the electron beam emittance and thus the source brilliance, but at the penalty of increasing the size and cost of the rings. Preserving the Dynamic Aperture (DA) in the rings became also an issue when increasing the number of magnet cells. The Multi-Bend Achromat (MBA)more » concept, including a miniaturization of the ring elements, has now drastically changed the picture. The MBA rings, now in construction or being planned, offer orders of magnitudes higher brilliance than rings of conventional designs. Several light sources around the world are now implementing or planning to implement this MBA concept. This article touches on the science drivers for higher brilliance. We will then describe the MBA concept with its advantages as well as its challenges. A short survey of the MBA activity around the world will also be presented. The author apologies for focusing on the MAX IV project regarding technical solutions. This is motivated by that MAX IV is the facility he knows best and it might be regarded as a fore-runner for the MBA concept.« less

The Abort Kicker System for the PEP-II Storage Rings at SLAC.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Delamare, Jeffrey E

2003-06-20

The PEP-II project has two storage rings. The HER (High Energy Ring) has up to 1.48 A of election beam at 9 GeV, and the LER (Low Energy Ring) has up to 2.14 A of positron beam at 3.1 GeV. To protect the HER and LER beam lines in the event of a ring component failure, each ring has an abort kicker system which directs the beam into a dump when a failure is detected. Due to the high current of the beams, the beam kick is tapered from 100% to 80% in 7.33 {micro}S (the beam transit time aroundmore » the ring). This taper distributes the energy evenly across the window which separates the ring from the beam dump such that the window is not damaged. The abort kicker trigger is synchronized with the ion clearing gap of the beam allowing for the kicker field to rise from 0-80% while there is no beam in the kicker magnet. Originally the kicker system was designed for a rise time of 370nS [1], but because the ion clearing gap was reduced in half, so was the rise time requirement for the kicker. This report discusses the design of the system interlocks, diagnostics, and modulator with the modifications necessary to accommodate an ion clearing gap of 185nS.« less

Optical to optical interface device

NASA Technical Reports Server (NTRS)

Oliver, D. S.; Vohl, P.; Nisenson, P.

1972-01-01

The development, fabrication, and testing of a preliminary model of an optical-to-optical (noncoherent-to-coherent) interface device for use in coherent optical parallel processing systems are described. The developed device demonstrates a capability for accepting as an input a scene illuminated by a noncoherent radiation source and providing as an output a coherent light beam spatially modulated to represent the original noncoherent scene. The converter device developed under this contract employs a Pockels readout optical modulator (PROM). This is a photosensitive electro-optic element which can sense and electrostatically store optical images. The stored images can be simultaneously or subsequently readout optically by utilizing the electrostatic storage pattern to control an electro-optic light modulating property of the PROM. The readout process is parallel as no scanning mechanism is required. The PROM provides the functions of optical image sensing, modulation, and storage in a single active material.

A Study of Single Pass Ion Effects at the ALS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Byrd, J.M.; Thomson, J.; /LBL, Berkeley

2011-09-13

We report the results of experiments on a 'fast beam-ion instability' at the Advanced Light Source (ALS). This ion instability, which can arise even when the ions are not trapped over multiple beam passages, will likely be important for many future accelerators. In our experiments, we filled the ALS storage ring with helium gas, raising the pressure approximately two orders of magnitude above the nominal pressure. With gaps in the bunch train large enough to avoid conventional (multi-turn) ion trapping, we observed a factor of 2-3 increase in the vertical beam size along with coherent beam oscillations which increased alongmore » the bunch train. Ion trapping has long been recognized as a potential limitation in electron storage rings. The ions, generated by beam-gas collisions, become trapped in the negative potential of the beam and accumulate over multiple beam passages. The trapped ions are then observed to cause a number of deleterious effects such as an increasing beam phase space, a broadening and shifting of the beam transverse oscillation frequencies (tunes), collective beam instabilities, and beam lifetime reductions. All of these effects are of concern for the next generation of accelerators, such as the B-factories or damping rings for future linear colliders, which will store high beam currents with closely spaced bunches and ultra-low beam emittances. One of the standard solutions used to prevent ion trapping is to include a gap in the bunch train which is long compared to the bunch spacing. In this case, the ions are first strongly-focused by the passing electron bunches and then over-focused in the gap. With a sufficiently large gap, the ions can be driven to large amplitudes where they form a diffuse halo and do not affect the beam. In this paper, we describe experiments that study a new regime of transient ion instabilities predicted to arise in future electron storage rings, and linacs with bunch trains. These future rings and linacs, which will be operated with higher beam currents, small transverse beam emittances, and long bunch trains, will use ion clearing gaps to prevent conventional ion trapping. But, while the ion clearing gap may suppress the conventional ion instabilities, it will not suppress a transient beam-ion instability where ions generated and trapped during the passage of a single train lead to a fast instability. While both conventional and transient ion instabilities have the same origin, namely ions produced by the beam, they have different manifestations and, more importantly, the new transient instability can arise even after the conventional ion instability is cured. This new instability is called the 'Fast Beam-Ion Instability' (FBII). In many future rings, the FBII is predicted to have very fast growth rates, much faster than the damping rates of existing and proposed transverse feedback systems, and thus is a potential limitation. To study the FBII, we performed experiments at the ALS, a 1.5 GeV electron storage ring. At the nominal ALS pressure of about 0.24 nTorr, the FBII is not evident. To study the instability, we intentionally added helium gas to the storage-ring vacuum system until the residual gas pressure was increased about 80 nTorr. This brought the predicted growth rate of the instability at least an order of magnitude above the growth rate of conventional multibunch instabilities driven by the RF cavities and above the damping rate of the transverse feedback system (TFB) in the ALS and, thereby, established conditions very similar to those in a future storage ring. We then filled the ring with a relatively short train of bunches, suppressing conventional ion instabilities. In the following, we will first briefly describe This paper describes the experiment and results in more detail.« less

Protein and peptide cross sections and mass spectra in an electrostatic ion beam trap

NASA Astrophysics Data System (ADS)

Fradkin, Z.; Strasser, D.; Heber, O.; Rappaport, M. L.; Sharon, M.; Thomson, B. A.; Rahinov, I.; Toker, Y.; Zajfman, D.

2017-05-01

Among the advantages of an electrostatic ion beam trap (EIBT), which is based on purely electrostatic fields, are mass-unlimited trapping and ease of operation. We have developed a new system that couples an electrospray ion source to an EIBT. Between the source and EIBT there is a Paul trap in which the ions are accumulated before being extracted and accelerated. After the ion bunch has entered the EIBT, the ions are trapped by rapidly raising the voltages on the entrance mirror. The oscillations of the bunch are detected by amplifying the charge induced on a pickup ring in the center of the trap, the ion mass being directly proportional to the square of the oscillation period. The trapping of biomolecules in the RF-bunching mode of the EIBT is used for measurement of mass spectra and collision cross sections. Coalescence of bunches of ions of nearby mass in the self-bunching mode is also demonstrated.

Thin film fabrication and system integration test run for a microactuator for a tuneable lens

NASA Astrophysics Data System (ADS)

Hoheisel, Dominik; Rissing, Lutz

2014-03-01

An electromagnetic microactuator, for controlling of a tuneable lens, with an integrated electrostatic element is fabricated by thin film technology. The actuator consists of two parts: the first part with microcoil and flux guide and the second part with a ring shaped back iron on a polyimide membrane. The back iron is additionally useable as electrode for electrostatic measurement of the air gap and for electrostatic actuation. By attracting the back iron an optical liquid is displaced and forms a liquid lens inside the back iron ring covered by the membrane. For testing the thin film fabrication sequence, up-scaled systems are generated in a test run. To fabricate the flux guide in an easy and quick way, a Ni-Fe foil with a thickness of 50 μm is laminated on the Si-wafer. This foil is also utilized in the following fabrication sequence as seed layer for electroplating. Compared to Ni-Fe structures deposited by electroplating, the foil is featuring better soft magnetic properties. The foil is structured by wet chemical etching and the backside of the wafer is structured by deep reactive ion etching (DRIE). For post fabrication thinning, the polyimide membrane is treated by oxygen plasma etching. To align the back iron to the microcoil and the flux guide, a flip-chip-bonder is used during test run of system integration. To adjust a constant air gap, a water solvable polymer is tested. A two component epoxy and a polyimide based glue are compared for their bonding properties of the actuator parts.

Stabilization of electrically conducting capillary bridges using feedback control of radial electrostatic stresses and the shapes of extended bridges

NASA Astrophysics Data System (ADS)

Marr-Lyon, Mark J.; Thiessen, David B.; Blonigen, Florian J.; Marston, Philip L.

2000-05-01

Electrically conducting, cylindrical liquid bridges in a density-matched, electrically insulating bath were stabilized beyond the Rayleigh-Plateau (RP) limit using electrostatic stresses applied by concentric ring electrodes. A circular liquid cylinder of length L and radius R in real or simulated zero gravity becomes unstable when the slenderness S=L/2R exceeds π. The initial instability involves the growth of the so-called (2, 0) mode of the bridge in which one side becomes thin and the other side rotund. A mode-sensing optical system detects the growth of the (2, 0) mode and an analog feedback system applies the appropriate voltages to a pair of concentric ring electrodes positioned near the ends of the bridge in order to counter the growth of the (2, 0) mode and prevent breakup of the bridge. The conducting bridge is formed between metal disks which are grounded. Three feedback algorithms were tested and each found capable of stabilizing a bridge well beyond the RP limit. All three algorithms stabilized bridges having S as great as 4.3 and the extended bridges broke immediately when feedback was terminated. One algorithm was suitable for stabilization approaching S=4.493… where the (3, 0) mode is predicted to become unstable for cylindrical bridges. For that algorithm the equilibrium shapes of bridges that were slightly under or over inflated corresponded to solutions of the Young-Laplace equation with negligible electrostatic stresses. The electrical conductivity of the bridge liquid need not be large. The conductivity was associated with salt added to the aqueous bridge liquid.

Thermal energy harvesters with piezoelectric or electrostatic transducer

NASA Astrophysics Data System (ADS)

Prokaryn, Piotr; Domański, Krzysztof; Marchewka, Michał; Tomaszewski, Daniel; Grabiec, Piotr; Puscasu, Onoriu; Monfray, Stéphane; Skotnicki, Thomas

2014-08-01

This paper describes the idea of the energy harvester which converts thermal gradient present in environment into electricity. Two kinds of such devices are proposed and their prototypes are shown and discussed. The main parts of harvesters are bimetallic spring, piezoelectric transducer or electrostatic transducer with electret. The applied piezomembrane was commercial available product but electrets was made by authors. In the paper a fabrication procedure of electrets formed by the corona discharge process is described. Devices were compared in terms of generated power, charging current, and the voltage across a storage capacitor.

Development of a Bunched Beam Electron Cooler based on ERL and Circulator Ring Technology for the Jefferson Lab Electron-Ion Collider

DOE Office of Scientific and Technical Information (OSTI.GOV)

Benson, Stephen V.; Derbenev, Yaroslav S.; Douglas, David R.

Jefferson Lab is in the process of designing an electron ion collider with unprecedented luminosity at a 45 GeV center-of-mass energy. This luminosity relies on ion cooling in both the booster and the storage ring of the accelerator complex. The cooling in the booster will use a conventional DC cooler similar to the one at COSY. The high-energy storage ring, operating at a momentum of up to 100 GeV/nucleon, requires novel use of bunched-beam cooling. There are two designs for such a cooler. The first uses a conventional Energy Recovery Linac (ERL) with a magnetized beam while the second usesmore » a circulating ring to enhance both peak and average currents experienced by the ion beam. This presentation will describe the design of both the Circulator Cooling Ring (CCR) design and that of the backup option using the stand-alone ERL operated at lower charge but higher repetition rate than the ERL injector required by the CCR-based design.« less

Solar wind interaction with dusty plasmas produces instabilities and solitary structures

NASA Astrophysics Data System (ADS)

Saleem, H.; Ali, S.

2017-12-01

It is pointed out that the solar wind interaction with dusty magnetospheres of the planets can give rise to purely growing instabilities as well as nonlinear electric field structures. Linear dispersion relation of the low frequency electrostatic ion-acoustic wave (IAW) is modified in the presence of stationary dust and its frequency becomes larger than its frequency in usual electron ion plasma even if ion temperature is equal to the electron temperature. This dust-ion-acoustic wave (DIAW) either becomes a purely growing electrostatic instability or turns out to be the modified dust-ion-acoustic wave (mDIAW) depending upon the magnitude of shear flow scale length and its direction. Growth rate of shear flow-driven electrostatic instability in a plasma having negatively charged stationary dust is larger than the usual D'Angelo instability of electron-ion plasma. It is shown that shear modified dust ion acoustic wave (mDIAW) produces electrostatic solitons in the nonlinear regime. The fluid theory predicts the existence of electrostatic solitons in the dusty plasmas in those regions where the inhomogeneous solar wind flow is parallel to the planetary or cometary magnetic field lines. The amplitude and width of the solitary structure depends upon dust density and magnitude of shear in the flow. This is a general theoretical model which is applied to dusty plasma of Saturn's F-ring for illustration.

Commissioning and Early Operation Experience of the NSLS-II Storage Ring RF System

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gao, F.; Rose, J.; Cupolo, J.

2015-05-03

The National Synchrotron Light Source II (NSLS-II) is a 3 GeV electron X-ray user facility commissioned in 2014. The storage ring RF system, essential for replenishing energy loss per turn of the electrons, consists of digital low level RF controllers, 310 kW CW klystron transmitters, CESR-B type superconducting cavities, as well as a supporting cryogenic system. Here we will report on RF commissioning and early operation experience of the system for beam current up to 200mA.

Mass Measurements of Proton-rich Nuclides at the Cooler Storage Ring at IMP

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zhang, Y. H.; Xu, H. S.; Wang, M.

2011-11-30

Recent results and progress of mass measurements of proton-rich nuclei using isochronous mass spectrometry (IMS) are reported. The nuclei under investigation were produced via fragmentation of relativistic energy heavy ions of {sup 78}Kr and {sup 58}Ni. After in-flight separation by the fragment separator RIBLL-2, the nuclei were injected and stored in the experimental storage ring CSRe, and their masses were determined from measurements of the revolution times. The impact of these measurements on the stellar nucleosynthesis in the rp-process is discussed.

Conditioning of the vacuum system of the TPS storage ring without baking in situ

NASA Astrophysics Data System (ADS)

Chan, C. K.; Chang, C. C.; Shueh, C.; Yang, I. C.; Wu, L. H.; Chen, B. Y.; Cheng, C. M.; Huang, Y. T.; Chuang, J. Y.; Cheng, Y. T.; Hsiao, Y. M.; Sheng, Albert

2017-04-01

To shorten the machine downtime, a maintenance procedure without baking in situ has been developed and applied to maintain and to upgrade the vacuum system of the TPS storage ring. The data of photon-stimulated desorption (PSD) reveal no obvious discrepancy between baking and not baking the vacuum system in situ. A beam-conditioning dose of extent only 11.8 A h is required to recover quickly the dynamic pressure of an unbaked vacuum system to its pre-intervention value according to the TPS maintenance experience.

Natural variation in expression of genes associated with carotenoid biosynthesis and accumulation in cassava (Manihot esculenta Crantz) storage root.

PubMed

Carvalho, Luiz Jcb; Agustini, Marco Av; Anderson, James V; Vieira, Eduardo A; de Souza, Claudia Rb; Chen, Songbi; Schaal, Barbara A; Silva, Joseane P

2016-06-10

Cassava (Manihot esculenta Crantz) storage root provides a staple food source for millions of people worldwide. Increasing the carotenoid content in storage root of cassava could provide improved nutritional and health benefits. Because carotenoid accumulation has been associated with storage root color, this study characterized carotenoid profiles, and abundance of key transcripts associated with carotenoid biosynthesis, from 23 landraces of cassava storage root ranging in color from white-to-yellow-to-pink. This study provides important information to plant breeding programs aimed at improving cassava storage root nutritional quality. Among the 23 landraces, five carotenoid types were detected in storage root with white color, while carotenoid types ranged from 1 to 21 in storage root with pink and yellow color. The majority of storage root in these landraces ranged in color from pale-to-intense yellow. In this color group, total β-carotene, containing all-E-, 9-Z-, and 13-Z-β-carotene isomers, was the major carotenoid type detected, varying from 26.13 to 76.72 %. Although no α-carotene was observed, variable amounts of a α-ring derived xanthophyll, lutein, was detected; with greater accumulation of α-ring xanthophylls than of β-ring xanthophyll. Lycopene was detected in a landrace (Cas51) with pink color storage root, but it was not detected in storage root with yellow color. Based on microarray and qRT-PCR analyses, abundance of transcripts coding for enzymes involved in carotenoid biosynthesis were consistent with carotenoid composition determined by contrasting HPLC-Diode Array profiles from storage root of landraces IAC12, Cas64, and Cas51. Abundance of transcripts encoding for proteins regulating plastid division were also consistent with the observed differences in total β-carotene accumulation. Among the 23 cassava landraces with varying storage root color and diverse carotenoid types and profiles, landrace Cas51 (pink color storage root) had low LYCb transcript abundance, whereas landrace Cas64 (intense yellow storage root) had decreased HYb transcript abundance. These results may explain the increased amounts of lycopene and total β-carotene observed in landraces Cas51 and Cas64, respectively. Overall, total carotenoid content in cassava storage root of color class representatives were associated with spatial patterns of secondary growth, color, and abundance of transcripts linked to plastid division. Finally, a partial carotenoid biosynthesis pathway is proposed.

The conversion of CESR to operate as the Test Accelerator, CesrTA. Part 3: Electron cloud diagnostics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Billing, M. G.; Conway, J. V.; Crittenden, J. A.

Cornell's electron/positron storage ring (CESR) was modified over a series of accelerator shutdowns beginning in May 2008, which substantially improves its capability for research and development for particle accelerators. CESR's energy span from 1.8 to 5.6 GeV with both electrons and positrons makes it ideal for the study of a wide spectrum of accelerator physics issues and instrumentation related to present light sources and future lepton damping rings. Additionally a number of these are also relevant for the beam physics of proton accelerators. This paper is the third in a series of four describing the conversion of CESR to themore » test accelerator, CESRTA. The first two papers discuss the overall plan for the conversion of the storage ring to an instrument capable of studying advanced accelerator physics issues [1] and the details of the vacuum system upgrades [2]. This paper focuses on the necessary development of new instrumentation, situated in four dedicated experimental regions, capable of studying such phenomena as electron clouds (ECs) and methods to mitigate EC effects. The fourth paper in this series describes the vacuum system modifications of the superconducting wigglers to accommodate the diagnostic instrumentation for the study of EC behavior within wigglers. Lastly, while the initial studies of CESRTA focused on questions related to the International Linear Collider damping ring design, CESRTA is a very versatile storage ring, capable of studying a wide range of accelerator physics and instrumentation questions.« less

The conversion of CESR to operate as the Test Accelerator, CesrTA. Part 3: Electron cloud diagnostics

DOE PAGES

Billing, M. G.; Conway, J. V.; Crittenden, J. A.; ...

2016-04-28

Cornell's electron/positron storage ring (CESR) was modified over a series of accelerator shutdowns beginning in May 2008, which substantially improves its capability for research and development for particle accelerators. CESR's energy span from 1.8 to 5.6 GeV with both electrons and positrons makes it ideal for the study of a wide spectrum of accelerator physics issues and instrumentation related to present light sources and future lepton damping rings. Additionally a number of these are also relevant for the beam physics of proton accelerators. This paper is the third in a series of four describing the conversion of CESR to themore » test accelerator, CESRTA. The first two papers discuss the overall plan for the conversion of the storage ring to an instrument capable of studying advanced accelerator physics issues [1] and the details of the vacuum system upgrades [2]. This paper focuses on the necessary development of new instrumentation, situated in four dedicated experimental regions, capable of studying such phenomena as electron clouds (ECs) and methods to mitigate EC effects. The fourth paper in this series describes the vacuum system modifications of the superconducting wigglers to accommodate the diagnostic instrumentation for the study of EC behavior within wigglers. Lastly, while the initial studies of CESRTA focused on questions related to the International Linear Collider damping ring design, CESRTA is a very versatile storage ring, capable of studying a wide range of accelerator physics and instrumentation questions.« less

A 1kW EUV source for lithography based on FEL emission in a compact storage ring

NASA Astrophysics Data System (ADS)

Feser, Michael; Ruth, Ron; Loewen, Rod

2017-10-01

EUV has long been hailed as the next generation lithography technology. Its adoption into high volume manufacturing (HVM), however, has been delayed several technology nodes due to technical issues, many of which can be attributed to the EUV source performance. Today's EUV lithography scanners are powered by laser produce plasma (LPP) sources. They have issues with power scaling beyond 300 W, reliability and contamination. Free Electron Lasers (FELs) have been considered as an alternative EUV source. Advantages of accelerator based sources are the maturity of the accelerator technology, lack of debris/contamination, and ability to provide high power. Industry turned away from this technology because of the requirement to feed up to 10 scanners from one linear FEL to make it economically feasible, the large footprint, and generation of radioactive byproducts. All of these issues are overcome in the presented concept using a compact storage ring with steady-state FEL lasing action. At 1 kW output power, comparable cost and footprint to an LPP source, this source is ideally suited for use on a single scanner and promises reliable, contamination free operation. FEL action in the storage ring is sustained by operating the FEL well below the saturation regime and preserving the equilibrium low emittance and energy distribution of the ring.

Measurement techniques for low emittance tuning and beam dynamics at CESR

NASA Astrophysics Data System (ADS)

Billing, M. G.; Dobbins, J. A.; Forster, M. J.; Kreinick, D. L.; Meller, R. E.; Peterson, D. P.; Ramirez, G. A.; Rendina, M. C.; Rider, N. T.; Sagan, D. C.; Shanks, J.; Sikora, J. P.; Stedinger, M. G.; Strohman, C. R.; Williams, H. A.; Palmer, M. A.; Holtzapple, R. L.; Flanagan, J.

2018-03-01

After operating as a High Energy Physics electron-positron collider, the Cornell Electron-positron Storage Ring (CESR) has been converted to become a dedicated synchrotron light source for the Cornell High Energy Synchrotron Source (CHESS). Over the course of several years CESR was adapted for accelerator physics research as a test accelerator, capable of studying topics relevant to future damping rings, colliders and light sources. Initially some specific topics were targeted for accelerator physic research with the storage ring in this mode, labeled CesrTA. These topics included 1) tuning techniques to produce low emittance beams, 2) the study of electron cloud (EC) development in a storage ring and 3) intra-beam scattering effects. The complete conversion of CESR to CesrTA occurred over a several year period, described elsewhere [1–3]. A number of specific instruments were developed for CesrTA. Much of the pre-existing instrumentation was modified to accommodate the scope of these studies and these are described in a companion paper [4]. To complete this research, a number of procedures were developed or modified, often requiring coordinated measurements among different instruments [5]. This paper provides an overview of types of measurements employed for the study of beam dynamics during the operation of CesrTA.

Beam measurements using visible synchrotron light at NSLS2 storage ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Weixing, E-mail: chengwx@bnl.gov; Bacha, Bel; Singh, Om

2016-07-27

Visible Synchrotron Light Monitor (SLM) diagnostic beamline has been designed and constructed at NSLS2 storage ring, to characterize the electron beam profile at various machine conditions. Due to the excellent alignment, SLM beamline was able to see the first visible light when beam was circulating the ring for the first turn. The beamline has been commissioned for the past year. Besides a normal CCD camera to monitor the beam profile, streak camera and gated camera are used to measure the longitudinal and transverse profile to understand the beam dynamics. Measurement results from these cameras will be presented in this paper.more » A time correlated single photon counting system (TCSPC) has also been setup to measure the single bunch purity.« less

Electrostatic instability of ring current protons beyond the plasmapause during injection events

NASA Technical Reports Server (NTRS)

Coroniti, F. V.; Fredricks, R. W.; White, R.

1972-01-01

The stability of ring current protons with an injection spectrum modeled by an m = 2 mirror distribution function was examined for typical ring current parameters. It was found that the high frequency loss cone mode can be excited at wave numbers K lambda sub Di about = to 0.1 to 0.5, at frequencies omega about = to (0.2 to 0.6) omega sub pi and with growth rates up to gamma/omega about = to 0.03. These waves interact with the main body of the proton distribution and propagate nearly perpendicular to the local magnetic field. Cold particle partial densities tend to reduce the growth rate so that the waves are quenched at or near to the plasmapause boundary. Wave e-folding lengths are comparable to 0.1 R sub e, compared to the value of about 4 R sub e found for ion cyclotron waves at the same plasma conditions.

The dusty ballerina skirt of Jupiter

NASA Astrophysics Data System (ADS)

Horanyi, M.; Morfill, G.; Gruen, E.

1993-12-01

We suggest a model to explain the unexpected recurrent dust events that were observed during the Jupiter encounter by the dust detector on board the Ulysses spacecraft. This model is based dust-magnetosphere interactions. Dust particles inside the Jovian magnetosphere collect electrostatic charges and their interaction with the magnetic and electric fields can lead to energization and subsequent ejection. We discuss the dusty regions (ring/halo, `gossamer' ring) and also Io as potential sources for the Ulysses events. This model favors Io as a source. The mass and velocity range of the escaping particles are compatible with the observations, and we also suggest internal periodicities to explain the recurrent nature of the Ulysses dust events.

Advanced Photon Source accelerator ultrahigh vacuum guide

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, C.; Noonan, J.

1994-03-01

In this document the authors summarize the following: (1) an overview of basic concepts of ultrahigh vacuum needed for the APS project, (2) a description of vacuum design and calculations for major parts of APS, including linac, linac waveguide, low energy undulator test line, positron accumulator ring (PAR), booster synchrotron ring, storage ring, and insertion devices, and (3) cleaning procedures of ultrahigh vacuum (UHV) components presently used at APS.

Emittance and lifetime measurement with damping wigglers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, G. M.; Shaftan, T., E-mail: shaftan@bnl.gov; Cheng, W. X.

National Synchrotron Light Source II (NSLS-II) is a new third-generation storage ring light source at Brookhaven National Laboratory. The storage ring design calls for small horizontal emittance (<1 nm-rad) and diffraction-limited vertical emittance at 12 keV (8 pm-rad). Achieving low value of the beam size will enable novel user experiments with nm-range spatial and meV-energy resolution. The high-brightness NSLS-II lattice has been realized by implementing 30-cell double bend achromatic cells producing the horizontal emittance of 2 nm rad and then halving it further by using several Damping Wigglers (DWs). This paper is focused on characterization of the DW effects inmore » the storage ring performance, namely, on reduction of the beam emittance, and corresponding changes in the energy spread and beam lifetime. The relevant beam parameters have been measured by the X-ray pinhole camera, beam position monitors, beam filling pattern monitor, and current transformers. In this paper, we compare the measured results of the beam performance with analytic estimates for the complement of the 3 DWs installed at the NSLS-II.« less

Higher-Order Systematic Effects in the Muon Beam-Spin Dynamics for Muon g-2

NASA Astrophysics Data System (ADS)

Crnkovic, Jason; Brown, Hugh; Krouppa, Brandon; Metodiev, Eric; Morse, William; Semertzidis, Yannis; Tishchenko, Vladimir

2016-03-01

The BNL Muon g-2 Experiment (E821) produced a precision measurement of the muon anomalous magnetic moment, where as the Fermilab Muon g-2 Experiment (E989) is an upgraded version of E821 that has a goal of producing a measurement with approximately 4 times more precision. Improving the precision requires a more detailed understanding of the experimental systematic effects, and so three higher-order systematic effects in the muon beam-spin dynamics have recently been found and estimated for E821. The beamline systematic effect originates from muon production in beamline spectrometers, as well as from muons traversing beamline bending magnets. The kicker systematic effect comes from a combination of the variation in time spent inside the muon storage ring across a muon bunch and the temporal structure of the storage ring kicker waveform. Finally, the detector systematic effect arises from a combination of the energy dependent muon equilibrium orbit in the storage ring, muon decay electron drift time, and decay electron detector acceptance effects. Brookhaven Natl Lab.

A 3D QSAR pharmacophore model and quantum chemical structure--activity analysis of chloroquine(CQ)-resistance reversal.

PubMed

Bhattacharjee, Apurba K; Kyle, Dennis E; Vennerstrom, Jonathan L; Milhous, Wilbur K

2002-01-01

Using CATALYST, a three-dimensional QSAR pharmacophore model for chloroquine(CQ)-resistance reversal was developed from a training set of 17 compounds. These included imipramine (1), desipramine (2), and 15 of their analogues (3-17), some of which fully reversed CQ-resistance, while others were without effect. The generated pharmacophore model indicates that two aromatic hydrophobic interaction sites on the tricyclic ring and a hydrogen bond acceptor (lipid) site at the side chain, preferably on a nitrogen atom, are necessary for potent activity. Stereoelectronic properties calculated by using AM1 semiempirical calculations were consistent with the model, particularly the electrostatic potential profiles characterized by a localized negative potential region by the side chain nitrogen atom and a large region covering the aromatic ring. The calculated data further revealed that aminoalkyl substitution at the N5-position of the heterocycle and a secondary or tertiary aliphatic aminoalkyl nitrogen atom with a two or three carbon bridge to the heteroaromatic nitrogen (N5) are required for potent "resistance reversal activity". Lowest energy conformers for 1-17 were determined and optimized to afford stereoelectronic properties such as molecular orbital energies, electrostatic potentials, atomic charges, proton affinities, octanol-water partition coefficients (log P), and structural parameters. For 1-17, fairly good correlation exists between resistance reversal activity and intrinsic basicity of the nitrogen atom at the tricyclic ring system, frontier orbital energies, and lipophilicity. Significantly, nine out of 11 of a group of structurally diverse CQ-resistance reversal agents mapped very well on the 3D QSAR pharmacophore model.

Effect of external electric and magnetic field on propagation of atmospheric pressure plasma jet

NASA Astrophysics Data System (ADS)

Zhu, Ping; Meng, Zhaozhong; Hu, Haixin; Ouyang, Jiting

2017-10-01

The behaviors of atmospheric pressure plasma jet produced by a coplanar dielectric barrier discharge (CDBD) in helium in external electrostatic and magnetic field are investigated experimentally. Time-resolved ICCD images of jet in electric field, magnetic field, and floating metal ring are recorded, respectively. The results show that the jet dynamics is affected significantly by a metal ring, an electric, and/or a magnetic field. In a transverse electric field, the jet shows behavior of deflection, broadening, and shortening according to the structure of electric field. In a transverse magnetic field, the jet deflects to up or down depending on the magnetic direction. The jet can be slowed down or obstructed by a floating metal ring on the jet path, but will still pass through the tube at higher applied voltages of DBD, without significant change in jet length or shape out of the tube compared with that without metal ring. A positive DC voltage on the metal ring helps to improve the jet length, but a negative voltage will reduce the length or completely stop the jet. The electric field to sustain the jet in helium is estimated to be about 24 ± 15 kV/cm from this experiment.

Cold atmospheric plasma jet in an axial DC electric field

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lin, Li, E-mail: lilin@gwu.edu, E-mail: keidar@gwu.edu; Keidar, Michael, E-mail: lilin@gwu.edu, E-mail: keidar@gwu.edu

2016-08-15

Cold atmospheric plasma (CAP) jet is currently intensively investigated as a tool for new and potentially transformative cancer treatment modality. However, there are still many unknowns about the jet behavior that requires attention. In this paper, a helium CAP jet is tested in an electrostatic field generated by a copper ring. Using Rayleigh microwave scattering method, some delays of the electron density peaks for different ring potentials are observed. Meanwhile, a similar phenomenon associated with the bullet velocity is found. Chemical species distribution along the jet is analyzed based on the jet optical emission spectra. The spectra indicate that amore » lower ring potential, i.e., lower DC background electric field, can increase the amount of excited N{sub 2}, N{sub 2}{sup +}, He, and O in the region before the ring, but can decrease the amount of excited NO and HO almost along the entire jet. Combining all the results above, we discovered that an extra DC potential mainly affects the temporal plasma jet properties. Also, it is possible to manipulate the chemical compositions of the jet using a ring with certain electric potentials.« less

Debye ring diffraction elucidation of 2D photonic crystal self-assembly and ordering at the air-water interface.

PubMed

Smith, N L; Coukouma, A; Dubnik, S; Asher, S A

2017-12-06

We fabricate 2D photonic crystals (2DPC) by spreading a dispersion of charged colloidal particles (diameters = 409, 570, and 915 nm) onto the surface of electrolyte solutions using a needle tip flow method. When the interparticle electrostatic interaction potential is large, particles self-assemble into highly ordered hexagonal close packed (hcp) monolayers. Ordered 2DPC efficiently forward diffract monochromatic light to produce a Debye ring on a screen parallel to the 2DPC. The diameter of the Debye ring is inversely proportional to the 2DPC particle spacing, while the Debye ring brightness and thickness depends on the 2DPC ordering. The Debye ring thickness increases as the 2DPC order decreases. The Debye ring ordering measurements of 2DPC attached to glass slides track measurements of the 2D pair correlation function order parameter calculated from SEM micrographs. The Debye ring method was used to investigate the 2DPC particle spacing, and ordering at the air-solution interface of NaCl solutions, and for 2DPC arrays attached to glass slides. Surprisingly, the 2DPC ordering does not monotonically decrease as the salt concentration increases. This is because of chloride ion adsorption onto the anionic particle surfaces. This adsorption increases the particle surface charge and compensates for the decreased Debye length of the electric double layer when the NaCl concentration is below a critical value.

The magnetic toroidal sector: a broad-band electron-positron pair spectrometer

NASA Astrophysics Data System (ADS)

Hagmann, Siegbert; Hillenbrand, Pierre-Michel; Litvinov, Yuri; Spillmann, Uwe

2016-05-01

At the future relativistic storage-ring HESR at FAIR the study of electron-positron pairs from non-nuclear, atomic processes will be one of the goals of the experimental program with kinematically complete experiments focusing on momentum spectroscopy of coincident emission of electrons and positrons from free-free pairs and corresponding recoil ions. The underlying production mechanisms belong to central topics of QED in strong fields. We present first results on the electron-optical properties of a magnetic toroidal sector configuration enabling coincident detection of free-free electron-positron pairs; this spectrometer is suitable for implementation into a storage ring with a supersonic jet target and covering a wide range of lepton emission into the forward hemisphere. The simulation calculations are performed using the OPERA code.

3 GeV Booster Synchrotron Conceptual Design Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wiedemann, Helmut

2009-06-02

Synchrotron light cna be produced from a relativistic particle beam circulating in a storage ring at extremely high intensity and brilliance over a large spectral region reaching from the far infrared regime to hard x-rays. The particles, either electrons or positrons, radiate as they are deflected in the fields of the storage ring bending magnets or of magnets specially optimized for the production of synchrotron light. The synchrotron light being very intense and well collimated in the forward direction has become a major tool in a large variety of research fields in physics, chemistry, material science, biology, and medicine.

Safe operating conditions for NSLS-II Storage Ring Frontends commissioning

DOE Office of Scientific and Technical Information (OSTI.GOV)

Seletskiy, S.; Amundsen, C.; Ha, K.

2015-04-02

The NSLS-II Storage Ring Frontends are designed to safely accept the synchrotron radiation fan produced by respective insertion device when the electron beam orbit through the ID is locked inside the predefined Active Interlock Envelope. The Active Interlock is getting enabled at a particular beam current known as AI safe current limit. Below such current the beam orbit can be anywhere within the limits of the SR beam acceptance. During the FE commissioning the beam orbit is getting intentionally disturbed in the particular ID. In this paper we explore safe operating conditions for the Frontends commissioning.

DESY II, a new injector for the DESY storage rings PETRA and DORIS II

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hemmie, G.

1983-08-01

There is a proposal to build a new 9 GeV electron synchrotron as a dedicated injector for the storage rings DORIS and PETRA. This machine will be housed in the old DESY-tunnel side-by-side with the original DESY-synchrotron. It is characterized by a separated function lattice, a 12.5 Hz repetition frequency, an all-metal vacuum chamber and a high shunt impedance rf-system. After commissioning of this new machine in 1984, the old DESY-synchrotron could be converted into a dedicated proton-accelerator as part of the injection chain for HERA.

Explicit symplectic orbit and spin tracking method for electric storage ring

DOE PAGES

Hwang, Kilean; Lee, S. Y.

2016-08-18

We develop a symplectic charged particle tracking method for phase space coordinates and polarization in all electric storage rings. Near the magic energy, the spin precession tune is proportional to the fractional momentum deviation δ m from the magic energy, and the amplitude of the radial and longitudinal spin precession is proportional to η/δ m, where η is the electric dipole moment for an initially vertically polarized beam. As a result, the method can be used to extract the electron electric dipole moment of a charged particle by employing narrow band frequency analysis of polarization around the magic energy.

Experience with Round Beam Operation at The Advanced Photon Source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiao, A.; Emery, L.; Sajaev, V.

2015-01-01

Very short Touschek lifetime becomes a common issue for next-generation ultra-low emittance storage ring light sources. In order to reach a longer beamlifetime, such amachine often requires operating with a vertical-to-horizontal emittance ratio close to an unity, i.e. a “round beam”. In tests at the APS storage ring, we determined how a round beam can be reached experimentally. Some general issues, such as beam injection, optics measurement and corrections, and orbit correction have been tested also. To demonstrate that a round beam was achieved, the beam size ratio is calibrated using beam lifetime measurement.

Three-dimensional ordering of cold ion beams in a storage ring: A molecular-dynamics simulation study

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yuri, Yosuke, E-mail: yuri.yosuke@jaea.go.jp

Three-dimensional (3D) ordering of a charged-particle beams circulating in a storage ring is systematically studied with a molecular-dynamics simulation code. An ion beam can exhibit a 3D ordered configuration at ultralow temperature as a result of powerful 3D laser cooling. Various unique characteristics of the ordered beams, different from those of crystalline beams, are revealed in detail, such as the single-particle motion in the transverse and longitudinal directions, and the dependence of the tune depression and the Coulomb coupling constant on the operating points.

Theory of the polarization of highly charged ions in storage rings: Production, preservation, observation and application to the search for a violation of the fundamental symmetries

NASA Astrophysics Data System (ADS)

Bondarevskaya, A.; Prozorov, A.; Labzowsky, L.; Plunien, G.; Liesen, D.; Bosch, F.

2011-10-01

Theoretical concepts for the production, preservation and control of polarized highly charged ion beams in storage rings are investigated. It is argued that hydrogen-like ions can be polarized efficiently by optical pumping of the Zeeman sublevels of ground state hyperfine levels and that the maximum achievable nuclear polarization exceeds 90%. In order to study the preservation of the polarization during the ion motion through the magnetic system of the ring, the concept of the instantaneous quantization axis is introduced. It is suggested that the employment of “Siberian snakes” may help to preserve the ion beam polarization in the ring. The control of the beam polarization can be achieved by different methods: by measuring the Stokes parameters for the emitted photons or by observing the angular dependence of the transition rates for polarized ions. The important motivation for the production of polarized ion beams is the possibility to observe parity nonconservation effects in the hyperfine-quenched transitions in helium-like highly charged ions, where these effects can reach an unprecedented high value for atomic physics. The possible observation of parity nonconservation effects connected with the nuclear anapole moment is also discussed. A method for the observation of the electric dipole moment of an electron in a storage ring with a polarized highly charged ion beam is proposed. This method allows, in principle, to improve the existing boundaries for the electric dipole moment of an electron. However, the requirements of the corresponding experiment are very stringent.

Coupling tree rings and eddy covariance to estimate long-term above and belowground carbon storage at the stand level

NASA Astrophysics Data System (ADS)

Dye, A.; Alexander, M. R.; Bishop, D.; Pederson, N.; Hessl, A. E.

2016-12-01

Storage of carbon in terrestrial plants and soils directly reduces atmospheric carbon concentration, and it is thereby imperative to improve our understanding of where carbon is being stored and released in an ecosystem and how storages and releases are changing over time. At data-rich sites, coupling alternative measurements of carbon flux can improve this understanding. Here, we present a methodology to inversely model stand-level net storage and release of above- and belowground carbon over a period of 1-2 decades using co-located tree-ring plots and eddy covariance towers at three eastern U.S. forests. We reconstructed annual aboveground wood production (aNPP) from tree rings collected near eddy covariance towers. We compared our aNPP reconstructions with annual tower NEE to address whether interannual variations are correlated. Despite modest correlation, we observed magnitude differences between both records that vary annually. We interpret these differences as indicative of changes in belowground carbon storage, i.e. an aNPP:NEE ratio > 1 indicates a net release of belowground carbon and a ratio < 1 a net storage of belowground carbon. For this interpretation, we assume the following: a) carbon not directed to above or belowground pools is insignificant, b) carbon not stored above ground is stored below ground, and c) mature trees do not add to a storage pool at a higher level every year. While the offset between biometric aNPP and tower NEE could partially be attributed to the diversion of assimilated carbon to nonstructural carbohydrates instead of growth, we argue that this becomes a less important factor over longer time scales in a mature tree. Our approach does not quantify belowground NPP or allocation, but we present a method for estimating belowground carbon storage and release at the stand level, an otherwise difficult task at this scale due to heterogeneity across the stand.

A rapid boundary integral equation technique for protein electrostatics

NASA Astrophysics Data System (ADS)

Grandison, Scott; Penfold, Robert; Vanden-Broeck, Jean-Marc

2007-06-01

A new boundary integral formulation is proposed for the solution of electrostatic field problems involving piecewise uniform dielectric continua. Direct Coulomb contributions to the total potential are treated exactly and Green's theorem is applied only to the residual reaction field generated by surface polarisation charge induced at dielectric boundaries. The implementation shows significantly improved numerical stability over alternative schemes involving the total field or its surface normal derivatives. Although strictly respecting the electrostatic boundary conditions, the partitioned scheme does introduce a jump artefact at the interface. Comparison against analytic results in canonical geometries, however, demonstrates that simple interpolation near the boundary is a cheap and effective way to circumvent this characteristic in typical applications. The new scheme is tested in a naive model to successfully predict the ground state orientation of biomolecular aggregates comprising the soybean storage protein, glycinin.

Investigation of dust transport on the lunar surface in laboratory plasmas

NASA Astrophysics Data System (ADS)

Wang, X.; Horanyi, M.; Robertson, S. H.

2009-12-01

There has been much evidence indicating dust levitation and transport on or near the lunar surface. Dust mobilization is likely to be caused by electrostatic forces acting on small lunar dust particles that are charged by UV radiation and solar wind plasma. To learn about the basic physical process, we investigated the dynamics of dust grains on a conducting surface in laboratory plasmas. The first experiment was conducted with a dust pile (JSC-Mars-1) sitting on a negatively biased surface in plasma. The dust pile spread and formed a diffusing dust ring. Dust hopping was confirmed by noticing grains on protruding surfaces. The electrostatic potential distributions measured above the dust pile show an outward pointing electrostatic force and a non-monotonic sheath above the dust pile, indicating a localized upward electrostatic force responsible for lifting dust off the surface. The second experiment was conducted with a dust pile sitting on an electrically floating conducting surface in plasma with an electron beam. Potential measurements show a horizontal electric field at the dust/surface boundary and an enhanced vertical electric field in the sheath above the dust pile when the electron beam current is set to be comparable to the Bohm ion current. Secondary electrons emitted from the surfaces play an important role in this case.

Maury Goodman

Science.gov Websites

the 29th International Cosmic Ray Conference, Pune India, August 10, 2005 Reactor Searches for Theta Rings, Bombay India, August 2, 2005 NOvA Presentation at the Workshop on Physics of Atmospheric Neutrinos and Neutrinos from Muon Storage Rings, Bombay India, August 2, 2005 The Double Chooz Double Fast

Sc-Decorated Porous Graphene for High-Capacity Hydrogen Storage: First-Principles Calculations.

PubMed

Chen, Yuhong; Wang, Jing; Yuan, Lihua; Zhang, Meiling; Zhang, Cairong

2017-08-02

The generalized gradient approximation (GGA) function based on density functional theory is adopted to investigate the optimized geometrical structure, electron structure and hydrogen storage performance of Sc modified porous graphene (PG). It is found that the carbon ring center is the most stable adsorbed position for a single Sc atom on PG, and the maximum number of adsorbed H₂ molecules is four with the average adsorption energy of -0.429 eV/H₂. By adding a second Sc atom on the other side of the system, the hydrogen storage capacity of the system can be improved effectively. Two Sc atoms located on opposite sides of the PG carbon ring center hole is the most suitable hydrogen storage structure, and the hydrogen storage capacity reach a maximum 9.09 wt % at the average adsorption energy of -0.296 eV/H₂. The adsorption of H₂ molecules in the PG system is mainly attributed to orbital hybridization among H, Sc, and C atoms, and Coulomb attraction between negatively charged H₂ molecules and positively charged Sc atoms.

Sc-Decorated Porous Graphene for High-Capacity Hydrogen Storage: First-Principles Calculations

PubMed Central

Chen, Yuhong; Wang, Jing; Yuan, Lihua; Zhang, Meiling

2017-01-01

The generalized gradient approximation (GGA) function based on density functional theory is adopted to investigate the optimized geometrical structure, electron structure and hydrogen storage performance of Sc modified porous graphene (PG). It is found that the carbon ring center is the most stable adsorbed position for a single Sc atom on PG, and the maximum number of adsorbed H2 molecules is four with the average adsorption energy of −0.429 eV/H2. By adding a second Sc atom on the other side of the system, the hydrogen storage capacity of the system can be improved effectively. Two Sc atoms located on opposite sides of the PG carbon ring center hole is the most suitable hydrogen storage structure, and the hydrogen storage capacity reach a maximum 9.09 wt % at the average adsorption energy of −0.296 eV/H2. The adsorption of H2 molecules in the PG system is mainly attributed to orbital hybridization among H, Sc, and C atoms, and Coulomb attraction between negatively charged H2 molecules and positively charged Sc atoms. PMID:28767084

Stem water storage in five coexisting temperate broad-leaved tree species: significance, temporal dynamics and dependence on tree functional traits.

PubMed

Köcher, Paul; Horna, Viviana; Leuschner, Christoph

2013-08-01

The functional role of internal water storage is increasingly well understood in tropical trees and conifers, while temperate broad-leaved trees have only rarely been studied. We examined the magnitude and dynamics of the use of stem water reserves for transpiration in five coexisting temperate broad-leaved trees with largely different morphology and physiology (genera Fagus, Fraxinus, Tilia, Carpinus and Acer). We expected that differences in water storage patterns would mostly reflect species differences in wood anatomy (ring vs. diffuse-porous) and wood density. Sap flux density was recorded synchronously at five positions along the root-to-branch flow path of mature trees (roots, three stem positions and branches) with high temporal resolution (2 min) and related to stem radius changes recorded with electronic point dendrometers. The daily amount of stored stem water withdrawn for transpiration was estimated by comparing the integrated flow at stem base and stem top. The temporal coincidence of flows at different positions and apparent time lags were examined by cross-correlation analysis. Our results confirm that internal water stores play an important role in the four diffuse-porous species with estimated 5-12 kg day(-1) being withdrawn on average in 25-28 m tall trees representing 10-22% of daily transpiration; in contrast, only 0.5-2.0 kg day(-1) was withdrawn in ring-porous Fraxinus. Wood density had a large influence on storage; sapwood area (diffuse- vs. ring-porous) may be another influential factor but its effect was not significant. Across the five species, the length of the time lag in flow at stem top and stem base was positively related to the size of stem storage. The stem stores were mostly exhausted when the soil matrix potential dropped below -0.1 MPa and daily mean vapor pressure deficit exceeded 3-5 hPa. We conclude that stem storage is an important factor improving the water balance of diffuse-porous temperate broad-leaved trees in moist periods, while it may be of low relevance in dry periods and in ring-porous species.

Communication: Origin of the contributions to DNA structure in phages

PubMed Central

Myers, Christopher G.; Pettitt, B. Montgomery

2013-01-01

Cryo electron microscopy (cryo-EM) data of the interior of phages show ordering of the interior DNA that has been interpreted as a nearly perfectly ordered polymer. We show surface-induced correlations, excluded volume, and electrostatic forces are sufficient to predict most of the major features of the current structural data for DNA packaged within viral capsids without additional ordering due to elastic bending forces for the polymer. Current models assume highly-ordered, even spooled, hexagonally packed conformations based on interpretation of cryo-EM density maps. We show herein that the surface induced packing of short (6mer), unconnected DNA polymer segments is the only necessary ingredient in creating ringed densities consistent with experimental density maps. This implies the ensemble of possible conformations of polymeric DNA within the capsid that are consistent with cryo-EM data may be much larger than implied by traditional interpretations where such rings can only result from highly-ordered spool-like conformations. This opens the possibility of a more disordered, entropically-driven view of phage packaging thermodynamics. We also show the electrostatics of the DNA contributes a large portion of the internal hydrostatic and osmotic pressures of a phage virion, suggesting that nonlinear elastic anomalies might reduce the overall elastic bending enthalpy of more disordered conformations to have allowable free energies. PMID:23444988

Communication: Origin of the contributions to DNA structure in phages.

PubMed

Myers, Christopher G; Pettitt, B Montgomery

2013-02-21

Cryo electron microscopy (cryo-EM) data of the interior of phages show ordering of the interior DNA that has been interpreted as a nearly perfectly ordered polymer. We show surface-induced correlations, excluded volume, and electrostatic forces are sufficient to predict most of the major features of the current structural data for DNA packaged within viral capsids without additional ordering due to elastic bending forces for the polymer. Current models assume highly-ordered, even spooled, hexagonally packed conformations based on interpretation of cryo-EM density maps. We show herein that the surface induced packing of short (6mer), unconnected DNA polymer segments is the only necessary ingredient in creating ringed densities consistent with experimental density maps. This implies the ensemble of possible conformations of polymeric DNA within the capsid that are consistent with cryo-EM data may be much larger than implied by traditional interpretations where such rings can only result from highly-ordered spool-like conformations. This opens the possibility of a more disordered, entropically-driven view of phage packaging thermodynamics. We also show the electrostatics of the DNA contributes a large portion of the internal hydrostatic and osmotic pressures of a phage virion, suggesting that nonlinear elastic anomalies might reduce the overall elastic bending enthalpy of more disordered conformations to have allowable free energies.

Electrostatic energy analyzer measurements of low energy zirconium beam parameters in a plasma sputter-type negative ion source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Malapit, Giovanni M.; Department of Physical Sciences, University of the Philippines Baguio, Baguio City 2600; Mahinay, Christian Lorenz S.

2012-02-15

A plasma sputter-type negative ion source is utilized to produce and detect negative Zr ions with energies between 150 and 450 eV via a retarding potential-type electrostatic energy analyzer. Traditional and modified semi-cylindrical Faraday cups (FC) inside the analyzer are employed to sample negative Zr ions and measure corresponding ion currents. The traditional FC registered indistinct ion current readings which are attributed to backscattering of ions and secondary electron emissions. The modified Faraday cup with biased repeller guard ring, cut out these signal distortions leaving only ringings as issues which are theoretically compensated by fitting a sigmoidal function into themore » data. The mean energy and energy spread are calculated using the ion current versus retarding potential data while the beam width values are determined from the data of the transverse measurement of ion current. The most energetic negative Zr ions yield tighter energy spread at 4.11 eV compared to the least energetic negative Zr ions at 4.79 eV. The smallest calculated beam width is 1.04 cm for the negative Zr ions with the highest mean energy indicating a more focused beam in contrast to the less energetic negative Zr ions due to space charge forces.« less

Long-range electrostatic screening in ionic liquids

PubMed Central

Gebbie, Matthew A.; Dobbs, Howard A.; Valtiner, Markus; Israelachvili, Jacob N.

2015-01-01

Electrolyte solutions with high concentrations of ions are prevalent in biological systems and energy storage technologies. Nevertheless, the high interaction free energy and long-range nature of electrostatic interactions makes the development of a general conceptual picture of concentrated electrolytes a significant challenge. In this work, we study ionic liquids, single-component liquids composed solely of ions, in an attempt to provide a novel perspective on electrostatic screening in very high concentration (nonideal) electrolytes. We use temperature-dependent surface force measurements to demonstrate that the long-range, exponentially decaying diffuse double-layer forces observed across ionic liquids exhibit a pronounced temperature dependence: Increasing the temperature decreases the measured exponential (Debye) decay length, implying an increase in the thermally driven effective free-ion concentration in the bulk ionic liquids. We use our quantitative results to propose a general model of long-range electrostatic screening in ionic liquids, where thermally activated charge fluctuations, either free ions or correlated domains (quasiparticles), take on the role of ions in traditional dilute electrolyte solutions. This picture represents a crucial step toward resolving several inconsistencies surrounding electrostatic screening and charge transport in ionic liquids that have impeded progress within the interdisciplinary ionic liquids community. More broadly, our work provides a previously unidentified way of envisioning highly concentrated electrolytes, with implications for diverse areas of inquiry, ranging from designing electrochemical devices to rationalizing electrostatic interactions in biological systems. PMID:26040001

CHARMM Drude Polarizable Force Field for Aldopentofuranoses and Methyl-aldopentofuranosides

PubMed Central

Jana, Madhurima; MacKerell, Alexander D.

2015-01-01

An empirical all-atom CHARMM polarizable force filed for aldopentofuranoses and methyl-aldopentofuranosides based on the classical Drude oscillator is presented. A single electrostatic model is developed for eight different diastereoisomers of aldopentofuranoses by optimizing the existing electrostatic and bonded parameters as transferred from ethers, alcohols and hexopyranoses to reproduce quantum mechanical (QM) dipole moments, furanose-water interaction energies and conformational energies. Optimization of selected electrostatic and dihedral parameters was performed to generate a model for methyl-aldopentofuranosides. Accuracy of the model was tested by reproducing experimental data for crystal intramolecular geometries and lattice unit cell parameters, aqueous phase densities, and ring pucker and exocyclic rotamer populations as obtained from NMR experiments. In most cases the model is found to reproduce both QM data and experimental observables in an excellent manner, while for the remainder the level of agreement is in the satisfactory regimen. In aqueous phase simulations the monosaccharides have significantly enhanced dipoles as compared to the gas phase. The final model from this study is transferrable for future studies on carbohydrates and can be used with the existing CHARMM Drude polarizable force field for biomolecules. PMID:26018564

Energy storage device including a redox-enhanced electrolyte

DOEpatents

Stucky, Galen; Evanko, Brian; Parker, Nicholas; Vonlanthen, David; Auston, David; Boettcher, Shannon; Chun, Sang-Eun; Ji, Xiulei; Wang, Bao; Wang, Xingfeng; Chandrabose, Raghu Subash

2017-08-08

An electrical double layer capacitor (EDLC) energy storage device is provided that includes at least two electrodes and a redox-enhanced electrolyte including two redox couples such that there is a different one of the redox couples for each of the electrodes. When charged, the charge is stored in Faradaic reactions with the at least two redox couples in the electrolyte and in a double-layer capacitance of a porous carbon material that comprises at least one of the electrodes, and a self-discharge of the energy storage device is mitigated by at least one of electrostatic attraction, adsorption, physisorption, and chemisorption of a redox couple onto the porous carbon material.

Kinetic Theory of quasi-electrostatic waves in non-gyrotropic plasmas

NASA Astrophysics Data System (ADS)

Arshad, K.; Poedts, S.; Lazar, M.

2017-12-01

The orbital angular momentum (OAM) is a trait of helically phased light or helical (twisted) electric field. Lasers carrying orbital angular momentum (OAM) revolutionized many scientific and technological paradigms like microscopy, imaging and ionospheric radar facility to analyze three dimensional plasma dynamics in ionosphere, ultra-intense twisted laser pulses, twisted gravitational waves and astrophysics. This trend has also been investigated in plasma physics. Laguerre-Gaussian type solutions are predicted for magnetic tornadoes and Alfvénic tornadoes which exhibit spiral, split and ring-like morphologies. The ring shape morphology is ideal to fit the observed solar corona, solar atmosphere and Earth's ionosphere. The orbital angular momentum indicates the mediation of electrostatic and electromagnetic waves in new phenomena like Raman and Brillouin scattering. A few years ago, some new effects have been included in studies of orbital angular momentum in plasma regimes such as wave-particle interaction in the presence of helical electric field. Therefore, kinetic studies are carried out to investigate the Landau damping of the waves and growth of the instabilities in the presence helical electric field carrying orbital angular momentum for the Maxwellian distributed plasmas. Recently, a well suited approach involving a kappa distribution function has been adopted to model the twisted space plasmas. This leads to the development of new theoretical grounds for the study of Lorentzian or kappa distributed twisted Langmuir, ion acoustic, dust ion acoustic and dust acoustic modes. The quasi-electrostatic twisted waves have been studied now for the non-gyrotropic dusty plasmas in the presence of the orbital angular momentum of the helical electric field using Generalized Lorentzian or kappa distribution function. The Laguerre-Gaussian (LG) mode function is employed to decompose the perturbed distribution function and electric field into planar (longitudinal) and non-planar (azimuthal) components. The modified Vlasov and Poisson equations are solved to obtain the dielectric function for quasi-electrostatic twisted modes the non-gyrotropic dusty plasmas. Some numerical and graphical analysis is also illustrated for the better understanding of the twisted non-gyrotropic plasmas.

Insight from first principles into the stability and magnetism of alkali-metal superoxide nanoclusters

NASA Astrophysics Data System (ADS)

Arcelus, Oier; Suaud, Nicolas; Katcho, Nebil A.; Carrasco, Javier

2017-05-01

Alkali-metal superoxides are gaining increasing interest as 2p magnetic materials for information and energy storage. Despite significant research efforts on bulk materials, gaps in our knowledge of the electronic and magnetic properties at the nanoscale still remain. Here, we focused on the role that structural details play in determining stability, electronic structure, and magnetic couplings of (MO2)n (M = Li, Na, and K, with n = 2-8) clusters. Using first-principles density functional theory based on the Perdew-Burke-Ernzerhof and Heyd-Scuseria-Ernzerhof functionals, we examined the effect of atomic structure on the relative stability of different polymorphs within each investigated cluster size. We found that small clusters prefer to form planar-ring structures, whereas non-planar geometries become more stable when increasing the cluster size. However, the crossover point depends on the nature of the alkali metal. Our analysis revealed that electrostatic interactions govern the highly ionic M-O2 bonding and ultimately control the relative stability between 2-D and 3-D geometries. In addition, we analyzed the weak magnetic couplings between superoxide molecules in (NaO2)4 clusters comparing model Hamiltonian methods based on Wannier function projections onto πg states with wave function-based multi-reference calculations.

CsI-Silicon Particle detector for Heavy ions Orbiting in Storage rings (CsISiPHOS)

NASA Astrophysics Data System (ADS)

Najafi, M. A.; Dillmann, I.; Bosch, F.; Faestermann, T.; Gao, B.; Gernhäuser, R.; Kozhuharov, C.; Litvinov, S. A.; Litvinov, Yu. A.; Maier, L.; Nolden, F.; Popp, U.; Sanjari, M. S.; Spillmann, U.; Steck, M.; Stöhlker, T.; Weick, H.

2016-11-01

A heavy-ion detector was developed for decay studies in the Experimental Storage Ring (ESR) at the GSI Helmholtz Centre for Heavy Ion Research in Darmstadt, Germany. This detector serves as a prototype for the in-pocket particle detectors for future experiments with the Collector Ring (CR) at FAIR (Facility for Antiproton and Ion Research). The detector includes a stack of six silicon pad sensors, a double-sided silicon strip detector (DSSD), and a CsI(Tl) scintillation detector. It was used successfully in a recent experiment for the detection of the β+-decay of highly charged 142Pm60+ ions. Based on the ΔE / E technique for particle identification and an energy resolution of 0.9% for ΔE and 0.5% for E (Full Width at Half Maximum (FWHM)), the detector is well-suited to distinguish neighbouring isobars in the region of interest.

Improvement of energy conversion effectiveness and maximum output power of electrostatic induction-type MEMS energy harvesters by using symmetric comb-electrode structures

NASA Astrophysics Data System (ADS)

Honma, H.; Mitsuya, H.; Hashiguchi, G.; Fujita, H.; Toshiyoshi, H.

2018-06-01

We introduce symmetric comb-electrode structures for the electrostatic vibrational MEMS energy harvester to lower the electrostatic constraint force attributed to the built-in electret potential, thereby allowing the harvester device to operate in a small acceleration range of 0.05 g or lower (1 g  =  9.8 m s‑2). Given the same device structure, two different potentials for the electret are tested to experimentally confirm that the output induction current is enhanced 4.2 times by increasing the electret potential from  ‑60 V to  ‑250 V. At the same time, the harvester effectiveness has been improved to as high as 93%. The device is used to swiftly charge a 470 µF storage capacitor to 3.3 V in 120 s from small sinusoidal vibrations of 0.6 g at 124 Hz.

Saturation of the laser-induced narrowband coherent synchrotron radiation process: Experimental observation at a storage ring

NASA Astrophysics Data System (ADS)

Hosaka, M.; Yamamoto, N.; Takashima, Y.; Szwaj, C.; Le Parquier, M.; Evain, C.; Bielawski, S.; Adachi, M.; Zen, H.; Tanikawa, T.; Kimura, S.; Katoh, M.; Shimada, M.; Takahashi, T.

2013-02-01

We study the efficiency limitation affecting laser-induced coherent synchrotron radiation (CSR) at high laser power. Experiments are made on the UVSOR-II storage ring in conditions of narrowband terahertz CSR emission. While, at moderate power, CSR power increases quadratically with laser power, a noticeable decrease in efficiency and eventually a decrease in CSR power is observed experimentally at high power. Details of the underlying process are analyzed numerically. As the saturation effect depends almost instantaneously on the laser intensity, the saturation occurs locally in longitudinal space. This has important consequences on the modulation pattern induced on the electron bunch.

Progress on the Design of the Storage Ring Vacuum System for the Advanced Photon Source Upgrade Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stillwell, B.; Billett, B.; Brajuskovic, B.

2017-06-20

Recent work on the design of the storage ring vacuum system for the Advanced Photon Source Upgrade project (APS-U) includes: revising the vacuum system design to accommodate a new lattice with reverse bend magnets, modifying the designs of vacuum chambers in the FODO sections for more intense incident synchrotron radiation power, modifying the design of rf-shielding bellows liners for better performance and reliability, modifying photon absorber designs to make better use of available space, and integrated planning of components needed in the injection, extraction and rf cavity straight sections. An overview of progress in these areas is presented.

Development and operating experience of a short-period superconducting undulator at the Advanced Photon Source

DOE PAGES

Ivanyushenkov, Y.; Harkay, K.; Abliz, M.; ...

2015-04-01

In this study, a decade-long effort at the Advanced Photon Source (APS) of Argonne National Laboratory (ANL) on development of superconducting undulators culminated in December 2012 with the installation of the first superconducting undulator “SCU0” into Sector 6 of the APS storage ring. The device was commissioned in January 2013 and has been in user operation since. This paper presents the magnetic and cryogenic design of the SCU0 together with the results of stand-alone cold tests. The initial commissioning and characterization of SCU0 as well as its operating experience in the APS storage ring are described.

Measurement of Tensor Analyzing Powers for Elastic Electron Scattering from a Polarized 2H Target Internal to a Storage Ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

M. Ferro-Luzzi; M. Bouwhuis; E. Passchier

1996-09-23

We report an absolute measurement of the tensor analyzing powers T20 and T22 in elastic electron-deuteron scattering at a momentum transfer of 1.6 fm{sup -1}. The novel approach of this measurement is the use of a tensor polarized 2H target internal to an electron storage ring, with in situ measurement of the polarization of the target gas. Scattered electrons and recoil deuterons were detected in coincidence with two large acceptance nonmagnetic detectors. The techniques demonstrated have broad applicability to further measurements of spin-dependent electron scattering.

Broadband impedance calculations and single bunch instabilities estimations of of the HLS-II storage ring

NASA Astrophysics Data System (ADS)

Zhang, Qing-Kun; Wang, Lin; Li, Wei-Min; Gao, Wei-Wei

2015-12-01

The upgrade project of the Hefei Light Source storage ring is under way. In this paper, the broadband impedances of resistive wall and coated ceramic vacuum chamber are calculated using the analytic formula, and the wake fields and impedances of other designed vacuum chambers are simulated by CST code, and then a broadband impedance model is obtained. Using the theoretical formula, longitudinal and transverse single bunch instabilities are discussed. With the carefully-designed vacuum chamber, we find that the thresholds of the beam instabilities are higher than the beam current goal. Supported by Natural Science Foundation of China (11175182, 11175180)

Transparent lattice characterization with gated turn-by-turn data of diagnostic bunch train

NASA Astrophysics Data System (ADS)

Li, Yongjun; Cheng, Weixing; Ha, Kiman; Rainer, Robert

2017-11-01

Methods of characterization of a storage ring's lattice have traditionally been intrusive to routine operations. More importantly, the lattice seen by particles can drift with the beam current due to collective effects. To circumvent this, we have developed a novel approach for dynamically characterizing a storage ring's lattice that is transparent to operations. Our approach adopts a dedicated filling pattern which has a short, separate diagnostic bunch train (DBT). Through the use of a bunch-by-bunch feedback system, the DBT can be selectively excited on demand. Gated functionality of a beam position monitor system is capable of collecting turn-by-turn data of the DBT, from which the lattice can then be characterized after excitation. As the DBT comprises only about one percent of the total operational bunches, the effects of its excitation are negligible to users. This approach allows us to localize the distributed quadrupolar wakefields generated in the storage ring vacuum chamber during beam accumulation. While effectively transparent to operations, our approach enables us to dynamically control the beta beat and phase beat, and unobtrusively optimize performance of the National Synchrotron Light Source-II accelerator during routine operations.

Upgrade of BPM Electronics for the SPring-8 Storage Ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sasaki, Shigeki; Fujita, Takahiro; Shoji, Masazumi

2006-11-20

SPring-8, a 3rd generation synchrotron light source, has operated since 1997. Improvement of BPM performance is required as a part of upgrading activities of the storage ring as a light source. We have developed new electronics circuits for signal processing of the storage ring BPM, with target performance of sub-{mu}m range resolution with sufficiently fast measurement speed and good long-term stability. A set of the new circuits consists of multiplexers, an RF amplifier, a mixer, an IF amplifier, and a local oscillator for analog signal processing. The IF amplifier outputs are sampled with 16-bit 2-MSPS ADC on ADC boards andmore » the data are sent to a DSP board. The sampled data are processed and converted to position information in the DSP. A multiplexing method was employed to have a better stability of the performance by cancellation of variation common to each channel. Evaluation of the performance by using a prototype shows that position resolution well into the sub-{mu}m range has been achieved with a bandwidth of 1 kHz, and long-term stability of within 1 {mu}m has also been achieved.« less

Transparent lattice characterization with gated turn-by-turn data of diagnostic bunch train

DOE PAGES

Li, Yongjun; Cheng, Weixing; Ha, Kiman; ...

2017-11-21

Methods of characterization of a storage ring's lattice have traditionally been intrusive to routine operations. More importantly, the lattice seen by particles can drift with the beam current due to collective effects. To circumvent this, we have developed a novel approach for dynamically characterizing a storage ring's lattice that is transparent to operations. Our approach adopts a dedicated filling pattern which has a short, separate Diagnostic Bunch-Train (DBT). Through the use of a bunch-by-bunch feedback system, the DBT can be selectively excited on-demand. Gated functionality of a beam position monitor system is capable of collecting turn-by-turn data of the DBT,more » from which the lattice can then be characterized after excitation. As the DBT comprises only about one percent of the total operational bunches, the effects of its excitation are negligible to users. Therefore, this approach allows us to localize the distributed quadrupolar wake fields generated in the storage ring vacuum chamber during beam accumulation. While effectively transparent to operations, our approach enables us to dynamically control the beta-beat and phase-beat, and unobtrusively optimize performance of National Synchrotron Light Source-II accelerator during routine operations.« less

Synchrotron oscillation effects on an rf-solenoid spin resonance

NASA Astrophysics Data System (ADS)

Benati, P.; Chiladze, D.; Dietrich, J.; Gaisser, M.; Gebel, R.; Guidoboni, G.; Hejny, V.; Kacharava, A.; Kamerdzhiev, V.; Kulessa, P.; Lehrach, A.; Lenisa, P.; Lorentz, B.; Maier, R.; Mchedlishvili, D.; Morse, W. M.; Öllers, D.; Pesce, A.; Polyanskiy, A.; Prasuhn, D.; Rathmann, F.; Semertzidis, Y. K.; Stephenson, E. J.; Stockhorst, H.; Ströher, H.; Talman, R.; Valdau, Yu.; Weidemann, Ch.; Wüstner, P.

2012-12-01

New measurements are reported for the time dependence of the vertical polarization of a 0.97GeV/c deuteron beam circulating in a storage ring and perturbed by an rf solenoid. The storage ring is the cooler synchrotron (COSY) located at the Forschungszentrum Jülich. The beam polarization was measured continuously using a 1.5 cm thick carbon target located at the edge of the circulating deuteron beam and the scintillators of the EDDA detector. An rf solenoid mounted on the ring was used to generate fields at and near the frequency of the 1-Gγ spin resonance. Measurements were made of the vertical beam polarization as a function of time with the operation of the rf solenoid in either fixed or continuously variable frequency mode. Using rf-solenoid strengths as large as 2.66×10-5revolutions/turn, slow oscillations (˜1Hz) were observed in the vertical beam polarization. When the circulating beam was continuously electron cooled, these oscillations completely reversed the polarization and showed no sign of diminishing in amplitude. But for the uncooled beam, the oscillation amplitude was damped to nearly zero within a few seconds. A simple spin-tracking model without the details of the COSY ring lattice was successful in reproducing these oscillations and demonstrating the sensitivity of the damping to the magnitude of the synchrotron motion of the beam particles. The model demonstrates that the characteristic features of measurements made in the presence of large synchrotron oscillations are distinct from the features of such measurements when made off resonance. These data were collected in preparation for a study of the spin coherence time, a beam property that needs to become long to enable a search for an electric dipole moment using a storage ring.

Ion Selectivity Mechanism in a Bacterial Pentameric Ligand-Gated Ion Channel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fritsch, Sebastian M; Ivanov, Ivaylo N; Wang, Hailong

2011-01-01

The proton-gated ion channel from Gloeobacter violaceus (GLIC) is a prokaryotic homolog of the eukaryotic nicotinic acetylcholine receptor (nAChR) that responds to the binding of neurotransmitter acetylcholine and mediates fast signal transmission. Recent emergence of a high resolution crystal structure of GLIC captured in a potentially open state allowed detailed, atomic-level insight into ion conduction and selectivity mechanisms in these channels. Herein, we have examined the barriers to ion conduction and origins of ion selectivity in the GLIC channel by the construction of potential of mean force (PMF) profiles for sodium and chloride ions inside the transmembrane region. Our calculationsmore » reveal that the GLIC channel is open for a sodium ion to transport, but presents a ~10 kcal/mol free energy barrier for a chloride ion, which arises primarily from the unfavorable interactions with a ring of negatively charged glutamate residues (E-2 ) at the intracellular end and a ring of hydrophobic residues (I9 ) in the middle of the transmembrane domain. Our collective findings further suggest that the charge selection mechanism can, to a large extent, be attributed to the narrow intracellular end and a ring of glutamate residues in this position their strong negative electrostatics and ability to bind cations. By contrast, E19 at the extracellular entrance only plays a minor role in ion selectivity of GLIC. In addition to electrostatics, both ion hydration and protein dynamics are found to be crucial for ion conduction as well, which explains why a chloride ion experiences a much greater barrier than a sodium ion in the hydrophobic region of the pore.« less

Intermolecular interactions between σ- and π-holes of bromopentafluorobenzene and pyridine: computational and experimental investigations.

PubMed

Yang, Fang-Ling; Yang, Xing; Wu, Rui-Zhi; Yan, Chao-Xian; Yang, Fan; Ye, Weichun; Zhang, Liang-Wei; Zhou, Pan-Pan

2018-04-25

The characters of σ- and π-holes of bromopentafluorobenzene (C6F5Br) enable it to interact with an electron-rich atom or group like pyridine which possesses an electron lone-pair N atom and a π ring. Theoretical studies of intermolecular interactions between C6F5Br and C5H5N have been carried out at the M06-2X/aug-cc-pVDZ level without and with the counterpoise method, together with single point calculations at M06-2X/TZVP, wB97-XD/aug-cc-pVDZ and CCSD(T)/aug-cc-pVDZ levels. The σ- and π-holes of C6F5Br exhibiting positive electrostatic potentials make these sites favorably interact with the N atom and the π ring of C5H5N with negative electrostatic potentials, leading to five different dimers connected by a σ-holen bond, a σ-holeπ bond or a π-holeπ bond. Their geometrical structures, characteristics, nature and spectroscopy behaviors were systematically investigated. EDA analyses reveal that the driving forces in these dimers are different. NCI, QTAIM and NBO analyses confirm the existence of intermolecular interactions formed via σ- and π-holes of C6F5Br and the N atom and the π ring of C5H5N. The experimental IR and Raman spectra gave us important information about the formation of molecular complexes between C6F5Br and C5H5N. We expect that the results could provide valuable insights into the investigation of intermolecular interactions involving σ- and π-holes.

Quantitative study of interactions between oxygen lone pair and aromatic rings: substituent effect and the importance of closeness of contact.

PubMed

Gung, Benjamin W; Zou, Yan; Xu, Zhigang; Amicangelo, Jay C; Irwin, Daniel G; Ma, Shengqian; Zhou, Hong-Cai

2008-01-18

Current models describe aromatic rings as polar groups based on the fact that benzene and hexafluorobenzene are known to have large and permanent quadrupole moments. This report describes a quantitative study of the interactions between oxygen lone pair and aromatic rings. We found that even electron-rich aromatic rings and oxygen lone pairs exhibit attractive interactions. Free energies of interactions are determined using the triptycene scaffold and the equilibrium constants were determined by low-temperature 1H NMR spectroscopy. An X-ray structure analysis for one of the model compounds confirms the close proximity between the oxygen and the center of the aromatic ring. Theoretical calculations at the MP2/aug-cc-pVTZ level corroborate the experimental results. The origin of attractive interactions was explored by using aromatic rings with a wide range of substituents. The interactions between an oxygen lone pair and an aromatic ring are attractive at van der Waals' distance even with electron-donating substituents. Electron-withdrawing groups increase the strength of the attractive interactions. The results from this study can be only partly rationalized by using the current models of aromatic system. Electrostatic-based models are consistent with the fact that stronger electron-withdrawing groups lead to stronger attractions, but fail to predict or rationalize the fact that weak attractions even exist between electron-rich arenes and oxygen lone pairs. The conclusion from this study is that aromatic rings cannot be treated as a simple quadrupolar functional group at van der Waals' distance. Dispersion forces and local dipole should also be considered.

In-space inertial energy storage design

NASA Technical Reports Server (NTRS)

Studer, P. A.; Evans, H. E.

1981-01-01

Flywheel energy storage is a means of significantly improving the performance of space power systems. Two study contracts have been completed to investigate the merits of a magnetically suspended, ironless armature, ring rotor 'Mechanical Capacitor' design. The design of a suitable energy storage system is evaluated, taking into account baseline requirements, the motor generator, details regarding the suspension design, power conditioning, the rotor, and an example design. It appears on the basis of this evaluation that the inertial (flywheel) energy storage design is feasible.

Distributed trace using central performance counter memory

DOEpatents

Satterfield, David L; Sexton, James C

2013-10-22

A plurality of processing cores, are central storage unit having at least memory connected in a daisy chain manner, forming a daisy chain ring layout on an integrated chip. At least one of the plurality of processing cores places trace data on the daisy chain connection for transmitting the trace data to the central storage unit, and the central storage unit detects the trace data and stores the trace data in the memory co-located in with the central storage unit.

Distributed trace using central performance counter memory

DOEpatents

Satterfield, David L.; Sexton, James C.

2013-01-22

A plurality of processing cores, are central storage unit having at least memory connected in a daisy chain manner, forming a daisy chain ring layout on an integrated chip. At least one of the plurality of processing cores places trace data on the daisy chain connection for transmitting the trace data to the central storage unit, and the central storage unit detects the trace data and stores the trace data in the memory co-located in with the central storage unit.

Heteroaromatic π-Stacking Energy Landscapes

PubMed Central

2014-01-01

In this study we investigate π-stacking interactions of a variety of aromatic heterocycles with benzene using dispersion corrected density functional theory. We calculate extensive potential energy surfaces for parallel-displaced interaction geometries. We find that dispersion contributes significantly to the interaction energy and is complemented by a varying degree of electrostatic interactions. We identify geometric preferences and minimum interaction energies for a set of 13 5- and 6-membered aromatic heterocycles frequently encountered in small drug-like molecules. We demonstrate that the electrostatic properties of these systems are a key determinant for their orientational preferences. The results of this study can be applied in lead optimization for the improvement of stacking interactions, as it provides detailed energy landscapes for a wide range of coplanar heteroaromatic geometries. These energy landscapes can serve as a guide for ring replacement in structure-based drug design. PMID:24773380

15. DETAILED VIEW OF ENRICHED URANIUM STORAGE TANK. THE ADDITION ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

15. DETAILED VIEW OF ENRICHED URANIUM STORAGE TANK. THE ADDITION OF THE GLASS RINGS SHOWN AT THE TOP OF THE TANK HELPS PREVENT THE URANIUM FROM REACHING CRITICALITY LIMITS. (4/12/62) - Rocky Flats Plant, General Manufacturing, Support, Records-Central Computing, Southern portion of Plant, Golden, Jefferson County, CO

A permanent-magnet rotor for a high-temperature superconducting bearing

NASA Astrophysics Data System (ADS)

Mulcahy, T. M.; Hull, J. R.; Uherka, K. L.; Abboud, R. G.; Wise, J. H.; Carnegie, D. W.

1995-06-01

Design, fabrication, and performance, of a 1/3-m dia., 10-kg flywheel rotor with only one bearing is discussed. To achieve low-loss energy storage, the rotor's segmented-ring permanent-magnet (PM) is optimized for levitation and circumferential homogeneity. The magnet's carbon composite bands enable practical energy storage.

First plasma wave observations at neptune.

PubMed

Gurnett, D A; Kurth, W S; Poynter, R L; Granroth, L J; Cairns, I H; Macek, W M; Moses, S L; Coroniti, F V; Kennel, C F; Barbosa, D D

1989-12-15

The Voyager 2 plasma wave instrument detected many familiar plasma waves during the encounter with Neptune, including electron plasma oscillations in the solar wind upstream of the bow shock, electrostatic turbulence at the bow shock, and chorus, hiss, electron cyclotron waves, and upper hybrid resonance waves in the inner magnetosphere. Low-frequency radio emissions, believed to be generated by mode conversion from the upper hybrid resonance emissions, were also observed propagating outward in a disklike beam along the magnetic equatorial plane. At the two ring plane crossings many small micrometer-sized dust particles were detected striking the spacecraft. The maximum impact rates were about 280 impacts per second at the inbound ring plane crossing, and about 110 impacts per second at the outbound ring plane crossing. Most of the particles are concentrated in a dense disk, about 1000 kilometers thick, centered on the equatorial plane. However, a broader, more tenuous distribution also extends many tens of thousands of kilometers from the equatorial plane, including over the northern polar region.

Optical nonlinearity and charge transfer analysis of pyrene adsorbed on silver: Computational and experimental investigations

NASA Astrophysics Data System (ADS)

Reeta Felscia, U.; Rajkumar, Beulah J. M.; Sankar, Pranitha; Philip, Reji; Briget Mary, M.

2017-09-01

The interaction of pyrene on silver has been investigated using both experimental and computational methods. Hyperpolarizabilities computed theoretically together with experimental nonlinear absorption from open aperture Z-scan measurements, point towards a possible use of pyrene adsorbed on silver in the rational design of NLO devices. Presence of a red shift in both simulated and experimental UV-Vis spectra confirms the adsorption on silver, which is due to the electrostatic interaction between silver and pyrene, inducing variations in the structural parameters of pyrene. Fukui calculations along with MEP plot predict the electrophilic nature of the silver cluster in the presence of pyrene, with NBO analysis revealing that the adsorption causes charge redistribution from the first three rings of pyrene towards the fourth ring, from where the 2p orbitals of carbon interact with the valence 5s orbitals of the cluster. This is further confirmed by the downshifting of ring breathing modes in both the experimental and theoretical Raman spectra.

Theoretical predictions of anti-corrosive properties of THAM and its derivatives.

PubMed

Malinowski, Szymon; Jaroszyńska-Wolińska, Justyna; Herbert, Tony

2017-12-04

We present quantum chemical theoretical estimations of the anti-corrosive properties of THAM (tris(hydroxymethyl)aminomethane) and three derivatives that differ in the number of benzene rings: THAM-1 (2-amino-3-hydroxy-2-(hydroxymethyl) propylobenzoate), THAM-2 (2-amino-2-(hydroxymetyl)prapan-1,3-diyldibenzoate) and THAM-3 (2-amino-propan-1,2,3-triyltribenzoate). Fourteen exchange-correlation functionals based on the density functional theory (DFT) were chosen for quantum chemical study of THAM derivatives. The objective was to examine the effect of benzene rings on potential anti-corrosive properties of THAM compounds. The results indicate that the addition of benzene rings in THAM derivatives is likely to significantly enhance electrostatic bonding of a THAM-based coating to a presented metal surface and, thus, its adhesion and long-term effect in corrosion inhibition. Whereas it is clear that all three derivatives appear to be superior in their bonding characteristics to pure THAM, the potential order of merit between the three is less clear, although THAM-3 presents as possibly superior.

Energy storage apparatus

NASA Technical Reports Server (NTRS)

Studer, P. A.; Evans, H. E. (Inventor)

1978-01-01

A high efficiency, flywheel type energy storage device which comprises an electronically commutated d.c. motor/generator unit having a massive flywheel rotor magnetically suspended around a ring shaped stator is presented. During periods of low energy demand, the storage devices were operated as a motor, and the flywheel motor was brought up to operating speed. Energy was drawn from the device functioning as a generator as the flywheel rotor rotated during high energy demand periods.

Overview of a flywheel stack energy storage system

NASA Technical Reports Server (NTRS)

Kirk, James A.; Anand, Davinder K.

1988-01-01

The concept of storing electrical energy in rotating flywheels provides an attractive substitute to batteries. To realize these advantages the critical technologies of rotor design, composite materials, magnetic suspension, and high efficiency motor/generators are reviewed in this paper. The magnetically suspended flywheel energy storage system, currently under development at the University of Maryland, consisting of a family of interference assembled rings, is presented as an integrated solution for energy storage.

Electrostatic acceleration of helicon plasma using a cusped magnetic field

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harada, S.; Mitsubishi Heavy Industry ltd., 16-5 Konan 2-chome, Minato-ku, Tokyo 108-8215; Baba, T.

2014-11-10

The electrostatic acceleration of helicon plasma is investigated using an electrostatic potential exerted between the ring anode at the helicon source exit and an off-axis hollow cathode in the downstream region. In the downstream region, the magnetic field for the helicon source, which is generated by a solenoid coil, is modified using permanent magnets and a yoke, forming an almost magnetic field-free region surrounded by an annular cusp field. Using a retarding potential analyzer, two primary ion energy peaks, where the lower peak corresponds to the space potential and the higher one to the ion beam, are detected in themore » field-free region. Using argon as the working gas with a helicon power of 1.5 kW and a mass flow rate of 0.21 mg/s, the ion beam energy is on the order of the applied acceleration voltage. In particular, with an acceleration voltage lower than 150 V, the ion beam energy even exceeds the applied acceleration voltage by an amount on the order of the electron thermal energy at the exit of the helicon plasma source. The ion beam energy profile strongly depends on the helicon power and the applied acceleration voltage. Since by this method the whole working gas from the helicon plasma source can, in principle, be accelerated, this device can be applied as a noble electrostatic thruster for space propulsion.« less

Electrostatic acceleration of helicon plasma using a cusped magnetic field

NASA Astrophysics Data System (ADS)

Harada, S.; Baba, T.; Uchigashima, A.; Yokota, S.; Iwakawa, A.; Sasoh, A.; Yamazaki, T.; Shimizu, H.

2014-11-01

The electrostatic acceleration of helicon plasma is investigated using an electrostatic potential exerted between the ring anode at the helicon source exit and an off-axis hollow cathode in the downstream region. In the downstream region, the magnetic field for the helicon source, which is generated by a solenoid coil, is modified using permanent magnets and a yoke, forming an almost magnetic field-free region surrounded by an annular cusp field. Using a retarding potential analyzer, two primary ion energy peaks, where the lower peak corresponds to the space potential and the higher one to the ion beam, are detected in the field-free region. Using argon as the working gas with a helicon power of 1.5 kW and a mass flow rate of 0.21 mg/s, the ion beam energy is on the order of the applied acceleration voltage. In particular, with an acceleration voltage lower than 150 V, the ion beam energy even exceeds the applied acceleration voltage by an amount on the order of the electron thermal energy at the exit of the helicon plasma source. The ion beam energy profile strongly depends on the helicon power and the applied acceleration voltage. Since by this method the whole working gas from the helicon plasma source can, in principle, be accelerated, this device can be applied as a noble electrostatic thruster for space propulsion.

Space-charge-sustained microbunch structure in the Los Alamos Proton Storage Ring

NASA Astrophysics Data System (ADS)

Cousineau, S.; Danilov, V.; Holmes, J.; Macek, R.

2004-09-01

We present experimental data from the Los Alamos Proton Storage Ring (PSR) showing long-lived linac microbunch structure during beam storage with no rf bunching. Analysis of the experimental data and particle-in-cell simulations of the experiments indicate that space charge, coupled with energy spread effects, is responsible for the sustained microbunch structure. The simulated longitudinal phase space of the beam reveals a well-defined separatrix in the phase space between linac microbunches, with particles executing unbounded motion outside of the separatrix. We show that the longitudinal phase space of the beam was near steady state during the PSR experiments, such that the separatrix persisted for long periods of time. Our simulations indicate that the steady state is very sensitive to the experimental conditions. Finally, we solve the steady-state problem in an analytic, self-consistent fashion for a set of periodic longitudinal space-charge potentials.

Computational Analysis on Performance of Thermal Energy Storage (TES) Diffuser

NASA Astrophysics Data System (ADS)

Adib, M. A. H. M.; Adnan, F.; Ismail, A. R.; Kardigama, K.; Salaam, H. A.; Ahmad, Z.; Johari, N. H.; Anuar, Z.; Azmi, N. S. N.

2012-09-01

Application of thermal energy storage (TES) system reduces cost and energy consumption. The performance of the overall operation is affected by diffuser design. In this study, computational analysis is used to determine the thermocline thickness. Three dimensional simulations with different tank height-to-diameter ratio (HD), diffuser opening and the effect of difference number of diffuser holes are investigated. Medium HD tanks simulations with double ring octagonal diffuser show good thermocline behavior and clear distinction between warm and cold water. The result show, the best performance of thermocline thickness during 50% time charging occur in medium tank with height-to-diameter ratio of 4.0 and double ring octagonal diffuser with 48 holes (9mm opening ~ 60%) acceptable compared to diffuser with 6mm ~ 40% and 12mm ~ 80% opening. The conclusion is computational analysis method are very useful in the study on performance of thermal energy storage (TES).

Structure of the torque ring of the flagellar motor and the molecular basis for rotational switching.

PubMed

Lee, Lawrence K; Ginsburg, Michael A; Crovace, Claudia; Donohoe, Mhairi; Stock, Daniela

2010-08-19

The flagellar motor drives the rotation of flagellar filaments at hundreds of revolutions per second, efficiently propelling bacteria through viscous media. The motor uses the potential energy from an electrochemical gradient of cations across the cytoplasmic membrane to generate torque. A rapid switch from anticlockwise to clockwise rotation determines whether a bacterium runs smoothly forward or tumbles to change its trajectory. A protein called FliG forms a ring in the rotor of the flagellar motor that is involved in the generation of torque through an interaction with the cation-channel-forming stator subunit MotA. FliG has been suggested to adopt distinct conformations that induce switching but these structural changes and the molecular mechanism of switching are unknown. Here we report the molecular structure of the full-length FliG protein, identify conformational changes that are involved in rotational switching and uncover the structural basis for the formation of the FliG torque ring. This allows us to propose a model of the complete ring and switching mechanism in which conformational changes in FliG reverse the electrostatic charges involved in torque generation.

Astrochemistry in TSR and CSR Ion Storage Rings

NASA Astrophysics Data System (ADS)

Novotny, Oldrich

2017-04-01

Dissociative recombination (DR) of molecular ions plays a key role in controlling the charge density and composition of the cold interstellar medium (ISM). Experimental data on DR are required in order to understand the chemical network in the ISM and related processes such as star formation from molecular clouds. Needed data include not only total reaction cross sections, but also the chemical composition and excitation states of the neutral products. Utilizing the TSR storage ring in Heidelberg, Germany, we have carried out DR measurements for astrophysically important molecular ions. We use a merged electron-ion beams technique combined with event-by-event fragment counting and fragment imaging. The count rate of detected neutral DR products yields the absolute DR rate coefficient. Imaging the distribution of fragment distances provides information on the kinetic energy released including the states of both the initial molecule and the final products. Additional kinetic energy sensitivity of the employed detector allows for identification of fragmentation channels by fragment-mass combination within each dissociation event. Such combined information is essential for studies on DR of polyatomic ions with multi-channel breakup. The recently commissioned Cryogenic Storage Ring (CSR) in Heidelberg, Germany, extends the experimental capabilities of TSR by operation at cryogenic temperatures down to 6 K. At these conditions residual gas densities down to 100 cm-3 can be reached resulting in beam storage times of several hours. Long storage in the cold environment allows the ions to relax down to their rotational ground state, thus mimicking well the conditions in the cold ISM. A variety of astrophysically relevant reactions will be investigated at these conditions, such as DR, electron impact excitation, ion-neutral collisions, etc. We report our TSR results on DR of HCl+ and D2Cl+. We also present first results from the CSR commissioning experiments.

Electric fields, electron production, and electron motion at the stripper foil in the Los Alamos Proton Storage Ring

NASA Astrophysics Data System (ADS)

Plum, M.

The beam instability at the Los Alamos Proton Storage Ring (PSR) most likely involves coupled oscillations between electrons and protons. For this instability to occur, there must be a strong source of electrons. Investigation of the various sources of electrons in the PSR had begun. Copious electron production is expected in the injection section because this section contains the stripper foil. This foil is mounted near the center of the beam pipe, and both circulating and injected protons pass through it, thus allowing ample opportunity for electron production. This paper discusses various mechanisms for electron production, beam-induced electric fields, and electron motion in the vicinity of the foil.

Lifetimes of relativistic heavy-ion beams in the High Energy Storage Ring of FAIR

NASA Astrophysics Data System (ADS)

Shevelko, V. P.; Litvinov, Yu. A.; Stöhlker, Th.; Tolstikhina, I. Yu.

2018-04-01

The High Energy Storage Ring, HESR, will be constructed at the Facility for Antiproton and Ion Research, FAIR, Darmstadt. For the first time, it will be possible to perform experiments with cooled high-intensity stable and radioactive heavy ions at highly relativistic energies. To design experiments at the HESR, realistic estimations of beam lifetimes are indispensable. Here we report calculated cross sections and lifetimes for typical U88+ , U90+ , U92+ , Sn49+ and Sn50+ ions in the energy range E = 400 MeV/u-5 GeV/u, relevant for the HESR. Interactions with the residual gas and with internal gas-jet targets are also considered.

Benchmarking of Touschek Beam Lifetime Calculations for the Advanced Photon Source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Xiao, A.; Yang, B.

2017-06-25

Particle loss from Touschek scattering is one of the most significant issues faced by present and future synchrotron light source storage rings. For example, the predicted, Touschek-dominated beam lifetime for the Advanced Photon Source (APS) Upgrade lattice in 48-bunch, 200-mA timing mode is only ~ 2 h. In order to understand the reliability of the predicted lifetime, a series of measurements with various beam parameters was performed on the present APS storage ring. This paper first describes the entire process of beam lifetime measurement, then compares measured lifetime with the calculated one by applying the measured beam parameters. The resultsmore » show very good agreement.« less

Emittance measurements in low energy ion storage rings

NASA Astrophysics Data System (ADS)

Hunt, J. R.; Carli, C.; Resta-López, J.; Welsch, C. P.

2018-07-01

The development of the next generation of ultra-low energy antiproton and ion facilities requires precise information about the beam emittance to guarantee optimum performance. In the Extra-Low ENergy Antiproton storage ring (ELENA) the transverse emittances will be measured by scraping. However, this diagnostic measurement faces several challenges: non-zero dispersion, non-Gaussian beam distributions due to effects of the electron cooler and various systematic errors such as closed orbit offsets and inaccurate rms momentum spread estimation. In addition, diffusion processes, such as intra-beam scattering might lead to emittance overestimates. Here, we present algorithms to efficiently address the emittance reconstruction in presence of the above effects, and present simulation results for the case of ELENA.

Development and operating experience of a 1.1-m-long superconducting undulator at the Advanced Photon Source

NASA Astrophysics Data System (ADS)

Ivanyushenkov, Y.; Harkay, K.; Borland, M.; Dejus, R.; Dooling, J.; Doose, C.; Emery, L.; Fuerst, J.; Gagliano, J.; Hasse, Q.; Kasa, M.; Kenesei, P.; Sajaev, V.; Schroeder, K.; Sereno, N.; Shastri, S.; Shiroyanagi, Y.; Skiadopoulos, D.; Smith, M.; Sun, X.; Trakhtenberg, E.; Xiao, A.; Zholents, A.; Gluskin, E.

2017-10-01

Development of superconducting undulators continues at the Advanced Photon Source (APS). Two years after successful installation and commissioning of the first relatively short superconducting undulator "SCU0" in Sector 6 of the APS storage ring, the second 1.1-m-long superconducting undulator "SCU1" was installed in Sector 1 of the APS. The device has been in user operation since its commissioning in May 2015. This paper describes the magnetic and cryogenic design of the SCU1 together with the results of stand-alone cold tests. The SCU1's magnetic and cryogenic performance as well as its operating experience in the APS storage ring are also presented.

The Effect of Gas Ion Bombardment on the Secondary Electron Yield of TiN, TiCN and TiZrV Coatings For Suppressing Collective Electron Effects in Storage Rings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Le Pimpec, F.; /PSI, Villigen; Kirby, R.E.

In many accelerator storage rings running positively charged beams, ionization of residual gas and secondary electron emission (SEE) in the beam pipe will give rise to an electron cloud which can cause beam blow-up or loss of the circulating beam. A preventative measure that suppresses electron cloud formation is to ensure that the vacuum wall has a low secondary emission yield (SEY). The SEY of thin films of TiN, sputter deposited Non-Evaporable Getters and a novel TiCN alloy were measured under a variety of conditions, including the effect of re-contamination from residual gas.

Search for the 1P 1 charmonium state in overlinepp annihilations at the CERN intersecting storage rings

NASA Astrophysics Data System (ADS)

Baglin, C.; Baird, S.; Bassompierre, G.; Borreani, G.; Brient, J.-C.; Broll, C.; Brom, J.-M.; Bugge, L.; Buran, T.; Burq, J.-P.; Bussière, A.; Buzzo, A.; Cester, R.; Chemarin, M.; Chevallier, M.; Escoubes, B.; Fay, J.; Ferroni, S.; Gracco, V.; Guillaud, J.-P.; Khan-Aronsen, E.; Kirsebom, K.; Kylling, A.; Ille, B.; Lambert, M.; Leistam, L.; Lundby, A.; Macri, M.; Marchetto, F.; Menichetti, E.; Mörch, Ch.; Mouellic, B.; Olsen, D.; Pastrone, N.; Petrillo, L.; Pia, M. G.; Poole, J.; Poulet, M.; Rinaudo, G.; Santroni, A.; Severi, M.; Skjevling, G.; Stapnes, S.; Stugu, B.; R704 Collaboration

1986-04-01

This experiment has been performed at the CERN Intersecting Storage Rings to study the direct formation of charmonium states in antiproton-proton annihilations. The experimental program has partly been devoted to an inclusive scan for overlinepp → J/ψ + X in the range 3520-3530 MeV/ c2. A cluster of five events has been observed in a narrow energy band, centred on the centre of gravity of the 3P J states where the 1P 1 is expected to be. When interpreted as a new resonace, these data yield a mass m = 3525.4±0.8 MeV/ c2.

IR spectra of Saturn's ring spokes and multiple shines in the Saturn-rings system

NASA Astrophysics Data System (ADS)

D'Aversa, Emiliano; Bellucci, Giancarlo; Filacchione, Gianrico; Cerroni, Priscilla; Nicholson, Phil D.; Carrozzo, Filippo G.; Altieri, Francesca; Oliva, Fabrizio; Geminale, Anna; Sindoni, Giuseppe; Hedman, Matthew M.

2017-04-01

During the last Saturn equinox, in 2009 August, spokes on the Saturn's B ring have been observed for the first time spectroscopically, at visible and infrared wavelengths. Measurements were obtained by Cassini-VIMS (Visual and Infrared Mapping Spectrometer) instrument in the 0.35-5.1 micron range. Spokes are either dark or bright features appearing on the B ring straddling the equinoxes, round to elongated in shape, lasting for minutes to hours, and moving partially pushed by Saturn's magnetic field. Previous spokes observations date back to the Voyager (1980 equinox,[1]), followed by a HST campaign (1995 equinox,[2]), and more recently Cassini-ISS images (2009 equinox,[3]). Theoretical models of spoke formation and evolution have been developed based on those observations, but there is not unanimous consensus on them. The most spread model considers the spoke as a cloud of very fine particles electrostatically levitating from the regolith of ring's boulders, and hovering on the ring plane while interacting with the ambient plasma until complete charge neutralization. The process triggering the grain charging is not yet clear (meteoroid bombardment, impacts of Saturn's lightnings electrons, etc.) but in any case a very small grain mass (high charge-to-mass ratio) is needed to allow electrostatic repulsion. From the observational point of view, small grain sizes (0.3-0.5 micron) have been retrieved by modeling the spoke reflectance in the visible spectral range (both Voyager, HST, and Cassini were equipped with multispectral imaging cameras). However, a first VIMS spoke observation ([4]) inferred a more spread size distribution (0.3 to 2.5 microns) to explain the high spoke contrast measured in the infrared. Here we will report about an analysis of two selected sets of spokes observed by VIMS. This selection aimed to include both high and low phase angle observations, and to take advantage from the highest spatial resolution data achieved in the infrared. We will highlight the importance of including illumination sources other than the Sun in the radiative transfer analysis, namely the Saturn-shine and the ring-shine. Their effect, more evident in the infrared range thanks to the deep water ice and methane bands, may bias the retrieval of spoke's micro-physics depending on the overall geometry of the scene. Possible debiasing and evaluation of consequences for visible retrievals will be illustrated. Acknowledgments - This work has been supported by Italian Space Agency (ASI) through Cassini contract. References - [1] Smith et al.,1981,Science,212,163. [2] McGhee et al.,2005,Icarus,173,508. [3] Mitchell et al.,2013,Icarus,225,446. [4] D'Aversa et al.,2010,Geoph.Res.Lett.,37,GL041427.

Gridless particle technique for the Vlasov-Poisson system in problems with high degree of symmetry

NASA Astrophysics Data System (ADS)

Boella, E.; Coppa, G.; D'Angola, A.; Peiretti Paradisi, B.

2018-03-01

In the paper, gridless particle techniques are presented in order to solve problems involving electrostatic, collisionless plasmas. The method makes use of computational particles having the shape of spherical shells or of rings, and can be used to study cases in which the plasma has spherical or axial symmetry, respectively. As a computational grid is absent, the technique is particularly suitable when the plasma occupies a rapidly changing space region.

Theoretical study of the bonding of the first-row transition-metal positive ions to ethylene

NASA Technical Reports Server (NTRS)

Sodupe, M.; Bauschlicher, Charles W., Jr.; Langhoff, Stephen R.; Partridge, Harry

1992-01-01

Ab initio calculations were performed to study the bonding of the first-row transition-metal ions with ethylene. While Sc(+) and Ti(+) insert into the pi bond of ethylene to form a three-membered ring, the ions V(+) through Cu(+) form an electrostatic complex with ethylene. The binding energies are compared with those from experiment and with those of comparable calculations performed previously for the metal-acetylene ion systems.

Transport of ions in presence of induced electric field and electrostatic turbulence - Source of ions injected into ring current

NASA Technical Reports Server (NTRS)

Cladis, J. B.; Francis, W. E.

1985-01-01

The transport of ions from the polar ionosphere to the inner magnetosphere during stormtime conditions has been computed using a Monte Carlo diffusion code. The effect of the electrostatic turbulence assumed to be present during the substorm expansion phase was simulated by a process that accelerated the ions stochastically perpendicular to the magnetic field with a diffusion coefficient proportional to the energization rate of the ions by the induced electric field. This diffusion process was continued as the ions were convected from the plasma sheet boundary layer to the double-spiral injection boundary. Inward of the injection boundary, the ions were convected adiabatically. By using as input an O(+) flux of 2.8 x 10 to the 8th per sq cm per s (w greater than 10 eV) and an H(+) flux of 5.5 x 10 to the 8th per sq cm per s (w greater than 0.63 eV), the computed distribution functions of the ions in the ring current were found to be in good agreement, over a wide range in L (4 to 8), with measurements made with the ISEE-1 satellite during a storm. This O(+) flux and a large part of the H(+) flux are consistent with the DE satellite measurements of the polar ionospheric outflow during disturbed times.

Modification of a liquid hydrogen tank for integrated refrigeration and storage

NASA Astrophysics Data System (ADS)

Swanger, A. M.; Jumper, K. M.; Fesmire, J. E.; Notardonato, W. U.

2015-12-01

The modification and outfitting of a 125,000-liter liquid hydrogen tank was performed to provide integrated refrigeration and storage capability. These functions include zero boil-off, liquefaction, and densification and therefore require provisions for sub-atmospheric tank pressures within the vacuum-jacketed, multilayer insulated tank. The primary structural modification was to add stiffening rings inside the inner vessel. The internal stiffening rings were designed, built, and installed per the ASME Boiler and Pressure Vessel Code, Section VIII, to prevent collapse in the case of vacuum jacket failure in combination with sub-atmospheric pressure within the tank. For the integrated refrigeration loop, a modular, skeleton-type heat exchanger, with refrigerant temperature instrumentation, was constructed using the stiffening rings as supports. To support the system thermal performance testing, three custom temperature rakes were designed and installed along the 21-meter length of the tank, once again using rings as supports. The temperature rakes included a total of 20 silicon diode temperature sensors mounted both vertically and radially to map the bulk liquid temperature within the tank. The tank modifications were successful and the system is now operational for the research and development of integrated refrigeration technology.

Development of silver/titanium dioxide/chitosan adipate nanocomposite as an antibacterial coating for fruit storage

USDA-ARS?s Scientific Manuscript database

A novel nanocomposite of silver/titanium dioxide/chitosan adipate (Ag/TiO2/CS) was developed through photochemical reduction using a chitosan adipate template. Chitosan served as a reducing agent for the metal ions, and anchored metal ions by forming Ag–N coordination bonds and electrostatic attract...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Burkel, L.; Dejus, R.; Maines, J.

This report is a description of the current status of the magnetic measurement facility and is a basic instructional manual for the operation of the facility and its components. Please refer to the appendices for more detailed information about specific components and procedures. The purpose of the magnetic measurement facility is to take accurate measurements of the magnetic field in the gay of the IDs in order to determine the effect of the ID on the stored particle beam and the emitted radiation. The facility will also play an important role when evaluating new ideas, novel devices, and inhouse prototypesmore » as part of the ongoing research and development program at the APS. The measurements will be performed with both moving search coils and moving Hall probes. The IDs will be evaluated by computer modeling of the emitted radiation for any given (measured) magnetic field map. The quality of the magnetic field will be described in terms of integrated multipoles for the effect on Storage Ring performance and in terms of the derived trajectories for the emitted radiation. Before being installed on the Storage Ring, every device will be measured and characterized to assure that it is compatible with Storage Ring requirements and radiation specifications. The accuracy that the APS needs to achieve for magnetic measurements will be based on these specifications.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Huamg, C. W., E-mail: huang.zw@nsrrc.org.tw; Hwang, C. S., E-mail: cshwang@nsrrc.org.tw; Department of Electrophysics, National Chiao Tung University, Hsinchu 300, Taiwan

The Taiwan Photon Source (TPS) has been successfully commissioned. However, the minimum emittance in the TPS lattice is 1.6 nm rad. In the existing TPS storage ring lattice, it is imperative to reduce the emittance to below 1 nm rad. Therefore, a feasibility study for reducing the effective emittance of the TPS storage ring by using a Robinson wiggler was launched; the reduction is necessary to enhance the photon brilliance. In this study, a permanent-magnet multiperiod Robinson wiggler (MRW) was developed for use instead of the single-period Robinson wiggler. In general, the quadruple field of a combined function magnet inmore » the storage ring is approximately few tesla per meter. According to beam dynamic analysis, we found that it is necessary to adopt a high gradient (40 T/m) combined-function MRW magnet to reduce the emittance effectively. Therefore, a high gradient field strength is required in the combined function MRW magnet. In this study, the quadrupole field strength of the MRW magnet was allowed to be approximately 40 T/m at a magnet gap of 20 mm. The period length of the MRW magnet was 300 mm and the period number was 16. The of MRWs is discussed in regard to the possibility of increasing the photon brilliance from IU22.« less

Electron cooling of a bunched ion beam in a storage ring

NASA Astrophysics Data System (ADS)

Zhao, He; Mao, Lijun; Yang, Jiancheng; Xia, Jiawen; Yang, Xiaodong; Li, Jie; Tang, Meitang; Shen, Guodong; Ma, Xiaoming; Wu, Bo; Wang, Geng; Ruan, Shuang; Wang, Kedong; Dong, Ziqiang

2018-02-01

A combination of electron cooling and rf system is an effective method to compress the beam bunch length in storage rings. A simulation code based on multiparticle tracking was developed to calculate the bunched ion beam cooling process, in which the electron cooling, intrabeam scattering (IBS), ion beam space-charge field, transverse and synchrotron motion are considered. Meanwhile, bunched ion beam cooling experiments have been carried out in the main cooling storage ring (CSRm) of the Heavy Ion Research Facility in Lanzhou, to investigate the minimum bunch length obtained by the cooling method, and study the dependence of the minimum bunch length on beam and machine parameters. The experiments show comparable results to those from simulation. Based on these simulations and experiments, we established an analytical model to describe the limitation of the bunch length of the cooled ion beam. It is observed that the IBS effect is dominant for low intensity beams, and the space-charge effect is much more important for high intensity beams. Moreover, the particles will not be bunched for much higher intensity beam. The experimental results in CSRm show a good agreement with the analytical model in the IBS dominated regime. The simulation work offers us comparable results to those from the analytical model both in IBS dominated and space-charge dominated regimes.

Magnetic field design for a Penning ion source for a 200 keV electrostatic accelerator

NASA Astrophysics Data System (ADS)

Fathi, A.; Feghhi, S. A. H.; Sadati, S. M.; Ebrahimibasabi, E.

2017-04-01

In this study, the structure of magnetic field for a Penning ion source has been designed and constructed with the use of permanent magnets. The ion source has been designed and constructed for a 200 keV electrostatic accelerator. With using CST Studio Suite, the magnetic field profile inside the ion source was simulated and an appropriate magnetic system was designed to improve particle confinement. Designed system consists of two ring magnets with 9 mm distance from each other around the anode. The ion source was constructed and the cylindrical magnet and designed magnetic system were tested on the ion source. The results showed that the ignition voltage for ion source with the designed magnetic system is almost 300 V lower than the ion source with the cylindrical magnet. Better particle confinement causes lower voltage discharge to occur.

Electrostatic wave heating and possible formation of self-generated high electric fields in a magnetized plasma

NASA Astrophysics Data System (ADS)

Mascali, D.; Celona, L.; Gammino, S.; Miracoli, R.; Castro, G.; Gambino, N.; Ciavola, G.

2011-10-01

A plasma reactor operates at the Laboratori Nazionali del Sud of INFN, Catania, and it has been used as a test-bench for the investigation of innovative mechanisms of plasma ignition based on electrostatic waves (ES-W), obtained via the inner plasma EM-to-ES wave conversion. Evidences of Bernstein wave (BW) generation will be shown. The Langmuir probe measurements have revealed a strong increase of the ion saturation current, where the BW are generated or absorbed, this being a signature of possible high energy ion flows. The results are interpreted through the Bernstein wave heating theory, which predicts the formation of high speed rotating layers of the plasma (a dense plasma ring is in fact observed). High intensity inner plasma self-generated electric fields (on the order of several tens of kV/cm) come out by our calculations.

Fermilab Tevatron and Pbar source status report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Edwards, H.

1986-08-01

The antiproton production cycle is enumerated, and the commissioning of the antiproton source is described, giving milestones and major obstacles. The Tevatron collider operation is described, including procedure to load the Tevatron with three bunches of protons and three bunches of antiprotons. Commissioning of the Main Ring and Tevatron for collider operation is described. Development and accelerator studies in four areas were necessary: main ring RF manipulations; controls and applications software support; Tevatron storage and low-beta squeeze sequence; and study of various beam transfers, storage steps, and sequences. Final tests are described. A long range upgrade program is presently undermore » evaluation to accomplish these goals: luminosity increase to 5 x 10/sup 31/ cm/sup -2/sec/sup -1/, production rates up to 4 x 10/sup 11/ antiprotons/hr, and intensity increase for fixed target operation. Beam quality is to be improved by the injector and main ring upgrades, and the luminosity goal is addressed by the Collider upgrade. (LEW)« less

Kicker field simulation and measurement for the muon g-2 experiment at FNAL

NASA Astrophysics Data System (ADS)

Chang, Seung Pyo; Kim, Young Im; Choi, Jihoon; Semertzidis, Yannis; muon g-2 experiment Collaboration

2017-01-01

In the Muon g-2 experiment, muon beam is injected to the storage ring in a slightly tilted orbit whose center is 77 mm away from the center of the ring. The kicker is needed to send the muon beam to the central orbit. The magnetic kicker is designed for the experiment and about 0.1 Tm field integral is needed. The peak current pulse is 4200 A to make this field integral. This strong kicker pulse could make unwanted eddy current occur. This eddy current could spoil the main magnetic field of the storage ring. This could be a critical threat to the precision of experiment. The kicker field simulation has done using OPERA to estimate the effects. Also the kicker field should be measured based on Faraday effect. The measurement has tested in the lab before install the experiment area. In this presentation, the simulation and measurement results will be discussed. This work was supported by IBS-R017-D1-2016-a00.

Nuclear-matter radius studies from 58Ni(α ,α ) experiments at the GSI Experimental Storage Ring with the EXL facility

NASA Astrophysics Data System (ADS)

Zamora, J. C.; Aumann, T.; Bagchi, S.; Bönig, S.; Csatlós, M.; Dillmann, I.; Dimopoulou, C.; Egelhof, P.; Eremin, V.; Furuno, T.; Geissel, H.; Gernhäuser, R.; Harakeh, M. N.; Hartig, A.-L.; Ilieva, S.; Kalantar-Nayestanaki, N.; Kiselev, O.; Kollmus, H.; Kozhuharov, C.; Krasznahorkay, A.; Kröll, Th.; Kuilman, M.; Litvinov, S.; Litvinov, Yu. A.; Mahjour-Shafiei, M.; Mutterer, M.; Nagae, D.; Najafi, M. A.; Nociforo, C.; Nolden, F.; Popp, U.; Rigollet, C.; Roy, S.; Scheidenberger, C.; von Schmid, M.; Steck, M.; Streicher, B.; Stuhl, L.; Thürauf, M.; Uesaka, T.; Weick, H.; Winfield, J. S.; Winters, D.; Woods, P. J.; Yamaguchi, T.; Yue, K.; Zenihiro, J.

2017-09-01

A novel method for measuring nuclear reactions in inverse kinematics with stored ion beams was successfully used to extract the nuclear-matter radius of 58Ni. The experiment was performed at the experimental heavy-ion storage ring at the GSI facility using a stored 58Ni beam at energies of 100 and 150 MeV/u and an internal helium gas-jet target. Elastically scattered α -recoils at low momentum transfers were measured with an in-ring detector system compatible with ultrahigh vacuum. Experimental angular distributions were fitted using density-dependent optical model potentials within the eikonal approximation. This permitted the extraction of the point-matter root-mean-square radius of 58Ni with an average value of 3.70(7) fm. Results from this work are in good agreement with several experiments performed in the past in normal kinematics. This pioneering experiment demonstrates a major breakthrough towards future investigations with far-from-stability stored beams using the present technique.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Talman, Richard M.; Talman, John D.

Proposed methods for measuring the electric dipole moment (EDM) of the proton use an intense, polarized proton beam stored in an all-electric storage ring “trap.” At the “magic” kinetic energy of 232.792 MeV, proton spins are “frozen,” for example always parallel to the instantaneous particle momentum. Energy deviation from the magic value causes in-plane precession of the spin relative to the momentum. Any nonzero EDM value will cause out-of-plane precession—measuring this precession is the basis for the EDM determination. A proposed implementation of this measurement shows that a proton EDM value of 10 –29e–cm or greater will produce a statisticallymore » significant, measurable precession after multiply repeated runs, assuming small beam depolarization during 1000 s runs, with high enough precision to test models of the early universe developed to account for the present day particle/antiparticle population imbalance. This paper describes an accelerator simulation code, eteapot, a new component of the Unified Accelerator Libraries (ual), to be used for long term tracking of particle orbits and spins in electric bend accelerators, in order to simulate EDM storage ring experiments. Though qualitatively much like magnetic rings, the nonconstant particle velocity in electric rings gives them significantly different properties, especially in weak focusing rings. Like the earlier code teapot (for magnetic ring simulation) this code performs exact tracking in an idealized (approximate) lattice rather than the more conventional approach, which is approximate tracking in a more nearly exact lattice. The Bargmann-Michel-Telegdi (BMT) equation describing the evolution of spin vectors through idealized bend elements is also solved exactly—original to this paper. Furthermore the idealization permits the code to be exactly symplectic (with no artificial “symplectification”). Any residual spurious damping or antidamping is sufficiently small to permit reliable tracking for the long times, such as the 1000 s assumed in estimating the achievable EDM precision. This paper documents in detail the theoretical formulation implemented in eteapot. An accompanying paper describes the practical application of the eteapot code in the Universal Accelerator Libraries (ual) environment to “resurrect,” or reverse engineer, the “AGS-analog” all-electric ring built at Brookhaven National Laboratory in 1954. Of the (very few) all-electric rings ever commissioned, the AGS-analog ring is the only relativistic one and is the closest to what is needed for measuring proton (or, even more so, electron) EDM’s. As a result, the companion paper also describes preliminary lattice studies for the planned proton EDM storage rings as well as testing the code for long time orbit and spin tracking.« less

Molecular Dynamics Simulations of PIP2 and PIP3 in Lipid Bilayers: Determination of Ring Orientation, and the Effects of Surface Roughness on a Poisson-Boltzmann Description

PubMed Central

Li, Zheng; Venable, Richard M.; Rogers, Laura A.; Murray, Diana; Pastor, Richard W.

2009-01-01

Abstract Molecular dynamics (MD) simulations of phosphatidylinositol (4,5)-bisphosphate (PIP2) and phosphatidylinositol (3,4,5)-trisphosphate (PIP3) in 1-palmitoyl 2-oleoyl phosphatidylcholine (POPC) bilayers indicate that the inositol rings are tilted ∼40° with respect to the bilayer surface, as compared with 17° for the P-N vector of POPC. Multiple minima were obtained for the ring twist (analogous to roll for an airplane). The phosphates at position 1 of PIP2 and PIP3 are within an Ångström of the plane formed by the phosphates of POPC; lipids in the surrounding shell are depressed by 0.5–0.8 Å, but otherwise the phosphoinositides do not substantially perturb the bilayer. Finite size artifacts for ion distributions are apparent for systems of ∼26 waters/lipid, but, based on simulations with a fourfold increase of the aqueous phase, the phosphoinositide positions and orientations do not show significant size effects. Electrostatic potentials evaluated from Poisson-Boltzmann (PB) calculations show a strong dependence of potential height and ring orientation, with the maxima on the −25 mV surfaces (17.1 ± 0.1 Å for PIP2 and 19.4 ± 0.3 Å for PIP3) occurring near the most populated orientations from MD. These surfaces are well above the background height of 10 Å estimated for negatively charged cell membranes, as would be expected for lipids involved in cellular signaling. PB calculations on microscopically flat bilayers yield similar maxima as the MD-based (microscopically rough) systems, but show less fine structure and do not clearly indicate the most probable regions. Electrostatic free energies of interaction with pentalysine are also similar for the rough and flat systems. These results support the utility of a rigid/flat bilayer model for PB-based studies of PIP2 and PIP3 as long as the orientations are judiciously chosen. PMID:19580753

An undulator based soft x-ray source for microscopy on the Duke electron storage ring

NASA Astrophysics Data System (ADS)

Johnson, Lewis Elgin

1998-09-01

This dissertation describes the design, development, and installation of an undulator-based soft x-ray source on the Duke Free Electron Laser laboratory electron storage ring. Insertion device and soft x-ray beamline physics and technology are all discussed in detail. The Duke/NIST undulator is a 3.64-m long hybrid design constructed by the Brobeck Division of Maxwell Laboratories. Originally built for an FEL project at the National Institute of Standards and Technology, the undulator was acquired by Duke in 1992 for use as a soft x-ray source for the FEL laboratory. Initial Hall probe measurements on the magnetic field distribution of the undulator revealed field errors of more than 0.80%. Initial phase errors for the device were more than 11 degrees. Through a series of in situ and off-line measurements and modifications we have re-tuned the magnet field structure of the device to produce strong spectral characteristics through the 5th harmonic. A low operating K has served to reduce the effects of magnetic field errors on the harmonic spectral content. Although rms field errors remained at 0.75%, we succeeded in reducing phase errors to less than 5 degrees. Using trajectory simulations from magnetic field data, we have computed the spectral output given the interaction of the Duke storage ring electron beam and the NIST undulator. Driven by a series of concerns and constraints over maximum utility, personnel safety and funding, we have also constructed a unique front end beamline for the undulator. The front end has been designed for maximum throughput of the 1st harmonic around 40A in its standard mode of operation. The front end has an alternative mode of operation which transmits the 3rd and 5th harmonics. This compact system also allows for the extraction of some of the bend magnet produced synchrotron and transition radiation from the storage ring. As with any well designed front end system, it also provides excellent protection to personnel and to the storage ring. A diagnostic beamline consisting of a transmission grating spectrometer and scanning wire beam profile monitor was constructed to measure the spatial and spectral characteristics of the undulator radiation. Test of the system with a circulating electron beam has confirmed the magnetic and focusing properties of the undulator, and verified that it can be used without perturbing the orbit of the beam.

The temporal distribution and carbon storage of large oak wood in streams and floodplain deposits

Treesearch

Richard P. Guyette; Daniel C. Dey; Michael C. Stambaugh

2008-01-01

We used tree-ring dating and 14C dating to document the temporal distribution and carbon storage of oak (Quercus spp.) wood in trees recruited and buried by streams and floodplains in northern Missouri, USA. Frequency distributions indicated that oak wood has been accumulating in Midwest streams continually since at least the...

A FODO racetrack ring for nuSTORM: design and optimization

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, A.; Bross, A.; Neuffer, D.

2017-07-01

The goal of nuSTORM is to provide well-defined neutrino beams for precise measurements of neutrino cross-sections and oscillations. The nuSTORM decay ring is a compact racetrack storage ring with a circumference of ~ 480 m that incorporates large aperture (60 cm diameter) magnets. There are many challenges in the design. In order to incorporate the Orbit Combination section (OCS), used for injecting the pion beam into the ring, a dispersion suppressor is needed adjacent to the OCS . Concurrently, in order to maximize the number of useful muon decays, strong bending dipoles are needed in the arcs to minimize the arcmore » length. These dipoles create strong chromatic effects, which need to be corrected by nonlinear sextupole elements in the ring. In this paper, a FODO racetrack ring design and its optimization using sextupolar fields via both a Genetic Algorithm (GA) and a Simulated Annealing (SA) algorithm will be discussed.« less

Sensory acceptability of squid rings gamma irradiated for shelf-life extension

NASA Astrophysics Data System (ADS)

Tomac, Alejandra; Cova, María C.; Narvaiz, Patricia; Yeannes, María I.

2017-01-01

The feasibility of extending the shelf-life of a squid product by gamma irradiation was analyzed. Illex argentinus rings were irradiated at 4 and 8 kGy; and stored at 4±1 °C during 77 days. No mesophilic bacteria, enterobacteriaceae and coliforms were detected in irradiated rings during storage. Psychrotrophic bacteria were significantly reduced by irradiation; their counts were fitted to a growth model which was further used for shelf-life estimations: 3 and 27 days for 0 and 4 kGy, respectively. Initially, non-irradiated as well as irradiated rings had very good sensory scores. The overall acceptability of 4 and 8 kGy rings did not decrease during 27 and 64 days, respectively, while control samples spoiled after 3 days. A radiation dose range for squid rings preservation was defined, which attained the technological shelf-life extension objective, without impairing sensory quality.

A first-principles study of hydrogen storage capacity based on Li-Na-decorated silicene.

PubMed

Sheng, Zhe; Wu, Shujing; Dai, Xianying; Zhao, Tianlong; Hao, Yue

2018-05-23

Surface decoration with alkali metal adatoms has been predicted to be promising for silicene to obtain high hydrogen storage capacity. Herein, we performed a detailed study of the hydrogen storage properties of Li and Na co-decorated silicene (Li-Na-decorated silicene) based on first-principles calculations using van der Waals correction. The hydrogen adsorption behaviors, including the adsorption order, the maximum capacity, and the corresponding mechanism were analyzed in detail. Our calculations show that up to three hydrogen molecules can firmly bind to each Li atom and six for each Na atom, respectively. The hydrogen storage capacity is estimated to be as high as 6.65 wt% with a desirable average adsorption energy of 0.29 eV/H2. It is confirmed that both the charge-induced electrostatic interaction and the orbital hybridizations play a great role in hydrogen storage. Our results may enhance our fundamental understanding of the hydrogen storage mechanism, which is of great importance for the practical application of Li-Na-decorated silicene in hydrogen storage.

Correction to AD/RHIC-47, Beam Transfer From AGS to RHIC

DOE Office of Scientific and Technical Information (OSTI.GOV)

Claus, J.; Foelsche, H.

1988-12-12

RHIC an acronym for Relativistic Heavy Ion Collider, is a facility for colliding heavy ions with each other, proposed for construction at Brookhaven National Laboratory. This facility and the motivation for building it, have been described. It consists of two intersecting storage rings and the purpose of this note is to describe how these two rings are to be filled with beam.

Simulation of emittance dilution in electron storage ring from Compton backscattering

NASA Astrophysics Data System (ADS)

Blumberg, L. N.; Blum, E.

A Monte-Carlo simulation of Compton backscattered kappa(sub L) = 3.2-micron photons from an IR-FEL on 75-MeV electrons in a storage ring yields an RMS electron energy spread of delta(sub E) = 11.9-keV for a sample of 10(exp 7) single scattering events. Electrons are sampled from a beam of natural energy spread sigma(sub E) = 5.6-keV and damped transverse angle spreads sigma(sub x)(prime) = .041-mrad and sigma(sub y)(prime) = .052-mrad (100%) coupling, scaled from the 200-MeV BNL XLS compact storage ring. The Compton-scattered x-rays are generated from an integral of the CM Klein-Nishina cross-section transformed to the lab. A tracking calculation has also been performed in 6-dimensional phase space. Initial electron coordinates are selected randomly from a Gaussian distribution of RMS spreads sigma(sub xo) = .102-mm, sigma(sub x(prime)o) = .041-mrad, sigma(sub yo) = .018-mm, sigma(sub y(prime)o) = .052-mrad, sigma(sub (phi)o) = 22-mrad and sigma(sub Eo) = 6-keV. A sample of 10000 electrons were each following for 40000 turns around the ring through an RF cavity of f(sub RF) = 211.54-MHz and peak voltage V(sub m)=300-keV. Preliminary results indicate that the resulting energy distribution is quite broad with an RMS width of delta(sub E) = 124-keV. The transverse widths are only slightly increased from their original values, i.e. delta(sub x) = .106-mm and delta(sub x)(prime) = .043 mrad. The scaled energy spread of delta(sub E) approximately = 360-keV for approximately 350,000 turns desired in a 10-msec x-ray angiography exposure is well within the RF bucket used here; even V(sub m) less than 50-kV is adequate. Further, the electron energy spread adds a negligible RMS x-ray energy spread of delta(sub Ex) = .32-keV. The electron energy damping time of tau(sub E) = 379-msec at 75-MeV in an XLS-type ring allows for damping this induced spread and top-off of the ring between heart cycles.

Phenylalanine 445 within oxidosqualene-lanosterol cyclase from Saccharomyces cerevisiae influences C-Ring cyclization and deprotonation reactions.

PubMed

Wu, Tung-Kung; Liu, Yuan-Ting; Chiu, Feng-Hsuan; Chang, Cheng-Hsiang

2006-10-12

[reaction: see text] We describe the Saccharomyces cerevisiae oxidosqualene-lanosterol cyclase Phe445 site-saturated mutants that generate truncated tricyclic and altered deprotonation product profiles. Among these mutants, only polar side-chain group substitutions genetically complemented yeast viability and produced spatially related product diversity, supporting the Johnson model that cation-pi interactions between a carbocationic intermediate and an enzyme can be replaced by an electrostatic or polar side chain to stabilize the cationic intermediate, but with product differentiation.

Patterns of Storage, Synthesis and Changing Light Levels Revealed by Carbon Isotope Microsampling within Eocene Metasequoia Tree Rings

NASA Astrophysics Data System (ADS)

Jahren, H.; Sternberg, L.

2005-12-01

Fossil tree rings from Axel Heiberg Island were microanalyzed for δ13C value in order to assess patterns of tree growth and carbon storage within the Middle Eocene (~45 Ma) Arctic paleoenvironment. Wood from four Metasequoia-type individuals was subsampled for analysis: each individual fossil consisted of between 4 and 10 large (~1 cm thick) consecutive tree rings. One of the fossils displayed an obvious concentric pattern, allowing for the determination of the direction of growth with isotopic pattern. Each ring was divided into ~1 mm thick subsamples, resulting in 5-10 δ13C value determinations per period of ring growth (i.e., growing season). All rings revealed a distinct pattern that was characteristic across growing seasons and across individual fossils. Early in the season, δ13C was at its highest value but descended systematically and sharply to its lowest value at the end of the growing season. Total decrease ranged between 3 and 5 ‰ over the course of each growing season. Identical patterns were observed in the δ13C value of alpha-cellulose isolated from each subsample, indicating that the trends observed did not represent changing levels of secondary metabolites, but rather a seasonal adjustment in the bulk source of carbon used during biosynthesis. Our results are consistent with the following annual pattern of wood synthesis 1.) complete dependence on the mobilization of stored carbon compounds early in the growing season; 2.) systematically increasing use of actively-acquired photosynthate during the growing season; 3.) complete reliance on active photosynthate by the end of the growing season. An additional and significant source of 13C discrimination is declining light levels late in the growing season, and likely contributes to the extreme pattern of δ13C decrease seen across each ring. Our results mimic those seen from modern broadleaf deciduous trees (Helle & Schlesser 2004), but differ from those seen in modern conifers (Barbour et al 2002), underlining the important influence of dormancy, storage and changing light levels on carbon cycling within the Paleogene polar forests. Helle & Schleser 2004: Plant, Cell and Environment 27:367-380. Barbour, Walcroft & Farquhar 2002: Plant, Cell and Environment 25: 1483-1499.

The design improvement of horizontal stripline kicker in TPS storage ring

NASA Astrophysics Data System (ADS)

Chou, P. J.; Chan, C. K.; Chang, C. C.; Hsu, K. T.; Hu, K. H.; Kuan, C. K.; Sheng, I. C.

2017-07-01

We plan to replace the existing horizontal stripline kicker of the transverse feedback system with an improved design. Large reflected power was observed at the downstream port of stripline kicker driven by the feedback amplifier. A rapid surge of vacuum pressure was observed when we tested the high current operation in TPS storage ring in April 2016. A burned feedthrough of the horizontal stripline kicker was discovered during a maintenance shutdown. The improved design is targeted to reduce the reflection of driving power from feedback system and to reduce beam induced RF heating. This major modification of the design is described. The results of RF simulation performed with the electromagnetic code GdfidL are reported as well.

Impact parameter sensitive study of inner-shell atomic processes in the experimental storage ring

NASA Astrophysics Data System (ADS)

Gumberidze, A.; Kozhuharov, C.; Zhang, R. T.; Trotsenko, S.; Kozhedub, Y. S.; DuBois, R. D.; Beyer, H. F.; Blumenhagen, K.-H.; Brandau, C.; Bräuning-Demian, A.; Chen, W.; Forstner, O.; Gao, B.; Gassner, T.; Grisenti, R. E.; Hagmann, S.; Hillenbrand, P.-M.; Indelicato, P.; Kumar, A.; Lestinsky, M.; Litvinov, Yu. A.; Petridis, N.; Schury, D.; Spillmann, U.; Trageser, C.; Trassinelli, M.; Tu, X.; Stöhlker, Th.

2017-10-01

In this work, we present a pilot experiment in the experimental storage ring (ESR) at GSI devoted to impact parameter sensitive studies of inner shell atomic processes for low-energy (heavy-) ion-atom collisions. The experiment was performed with bare and He-like xenon ions (Xe54+, Xe52+) colliding with neutral xenon gas atoms, resulting in a symmetric collision system. This choice of the projectile charge states was made in order to compare the effect of a filled K-shell with the empty one. The projectile and target X-rays have been measured at different observation angles for all impact parameters as well as for the impact parameter range of ∼35-70 fm.

Ultrashort high-brightness pulses from storage rings

NASA Astrophysics Data System (ADS)

Khan, Shaukat

2017-09-01

The brightness of short-wavelength radiation from accelerator-based sources can be increased by coherent emission in which the radiation intensity scales with the number of contributing electrons squared. This requires a microbunched longitudinal electron distribution, which is the case in free-electron lasers. The brightness of light sources based on electron storage rings was steadily improved, but could profit further from coherent emission. The modulation of the electron energy by a continuous-wave laser field may provide steady-state microbunching in the infrared regime. For shorter wavelengths, the energy modulation can be converted into a temporary density modulation by a dispersive chicane. One particular goal is coherent emission from a very short "slice" within an electron bunch in order to produce ultrashort radiation pulses with high brightness.

Astrochemistry at the Cryogenic Storage Ring

NASA Astrophysics Data System (ADS)

Kreckel, Holger; Becker, Arno; Blaum, Klaus; Breitenfeldt, Christian; George, Sebastian; Göck, Jürgen; Grieser, Manfred; Grussie, Florian; Guerin, Elisabeth; Heber, Oded; Karthein, Jonas; Krantz, Claude; Meyer, Christian; Mishra, Preeti; Novotny, Oldrich; O'Connor, Aodh; Saurabh, Sunny; Schippers, Stefan; Spruck, Kaija; Kumar, S. Sunil; Urbain, Xavier; Vogel, Stephen; von Hahn, Robert; Wilhelm, Patrick; Wolf, Andreas; Zajfman, Daniel

2017-01-01

Almost 200 different molecular species have been identified in space, and this number continues to grow steadily. This surprising molecular diversity bears witness to an active reaction network, in which molecular ions are the main drivers of chemistry in the gas phase. To study these reactions under controlled conditions in the laboratory is a major experimental challenge. The new Cryogenic Storage Ring (CSR) that has recently been commissioned at the Max Planck Institute for Nuclear Physics in Heidelberg will serve as an ideal testbed to study cold molecular ions in the gas phase. With residual gas densities of <140 cm-3 and temperatures below 10K, the CSR will allow for merged beams collision studies involving molecular ions, neutral atoms, free electrons and photons under true interstellar conditions.

Measurement of the Two-Photon Exchange Contribution to the Elastic e ± p Scattering Cross Sections at the VEPP-3 Storage Ring

DOE PAGES

Rachek, I. A.; Arrington, J.; Dmitriev, V. F.; ...

2015-02-12

The ratio of the elastic e +p to e –p scattering cross sections has been measured precisely, allowing the determination of the two-photon exchange contribution to these processes. This neglected contribution is believed to be the cause of the discrepancy between the Rosenbluth and polarization transfer methods of measuring the proton electromagnetic form factors. The experiment was performed at the VEPP-3 storage ring at beam energies of 1.6 and 1.0 GeV and at lepton scattering angles between 15° and 105°. The data obtained show evidence of a significant two-photon exchange effect. Furthermore, the results are compared with several theoretical predictions.

Measurement of Tensor Analyzing Powers for Elastic Electron Scattering from a Polarized {sup 2}H Target Internal to a Storage Ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ferro-Luzzi, M.; Bouwhuis, M.; Passchier, E.

1996-09-01

We report an absolute measurement of the tensor analyzing powers {ital T}{sub 20} and {ital T}{sub 22} in elastic electron-deuteron scattering at a momentum transfer of 1.6 fm{sup {minus}1}. The novel approach of this measurement is the use of a tensor polarized {sup 2}H target internal to an electron storage ring, with {ital in} {ital situ} measurement of the polarization of the target gas. Scattered electrons and recoil deuterons were detected in coincidence with two large acceptance nonmagnetic detectors. The techniques demonstrated have broad applicability to further measurements of spin-dependent electron scattering. {copyright} {ital 1996 The American Physical Society.}

ALS superbend magnet performance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marks, Steve; Zbasnik, John; Byrne, Warren

2001-12-10

The Lawrence Berkeley National Laboratory has been engaged in the design, construction and testing of four superconducting dipoles (Superbends) that are installed in three arcs of the Advanced Light Source (ALS), with the fourth magnet as a spare. This represents a major upgrade to the ALS providing an enhanced flux and brightness at photon energies above 10 keV. In preparation for installation, an extensive set of tests and measurements have been conducted to characterize the magnetic and cryogenic performance of the Superbends and to fiducialize them for accurate placement in the ALS storage ring. The magnets are currently installed, andmore » the storage ring is undergoing final commissioning. This paper will present the results of magnetic and cryogenic testing.« less

Research and Development on the Storage Ring Vacuum System for the APS Upgrade Project

DOE Office of Scientific and Technical Information (OSTI.GOV)

Stillwell, B.; Brajuskovic, B.; Carter, J.

A number of research and development activities are underway at Argonne National Laboratory to build confidence in the designs for the storage ring vacuum system required for the Advanced Photon Source Up-grade project (APS-U) [1]. The predominant technical risks are: excessive residual gas pressures during operation; insufficient beam position monitor stability; excessive beam impedance; excessive heating by induced electrical surface currents; and insufficient operational reliability. Present efforts to mitigate these risks include: building and evaluating mockup assemblies; performing mechanical testing of chamber weld joints; developing computational tools; investigating design alternatives; and performing electrical bench measurements. Status of these activities andmore » some of what has been learned to date will be shared.« less

Prospects of high-resolution resonant X-ray inelastic scattering studies on solid materials, liquids and gases at diffraction-limited storage rings.

PubMed

Schmitt, Thorsten; de Groot, Frank M F; Rubensson, Jan Erik

2014-09-01

The spectroscopic technique of resonant inelastic X-ray scattering (RIXS) will particularly profit from immensely improved brilliance of diffraction-limited storage rings (DLSRs). In RIXS one measures the intensities of excitations as a function of energy and momentum transfer. DLSRs will allow for pushing the achievable energy resolution, signal intensity and the sampled spot size to new limits. With RIXS one nowadays probes a broad range of electronic systems reaching from simple molecules to complex materials displaying phenomena like peculiar magnetism, two-dimensional electron gases, superconductivity, photovoltaic energy conversion and heterogeneous catalysis. In this article the types of improved RIXS studies that will become possible with X-ray beams from DLSRs are envisioned.

Low power interface IC's for electrostatic energy harvesting applications

NASA Astrophysics Data System (ADS)

Kempitiya, Asantha

The application of wireless distributed micro-sensor systems ranges from equipment diagnostic and control to real time structural and biomedical monitoring. A major obstacle in developing autonomous micro-sensor networks is the need for local electric power supply, since using a battery is often not a viable solution. This void has sparked significant interest in micro-scale power generators based on electrostatic, piezoelectric and electromagnetic energy conversion that can scavenge ambient energy from the environment. In comparison to existing energy harvesting techniques, electrostatic-based power generation is attractive as it can be integrated using mainstream silicon technologies while providing higher power densities through miniaturization. However the power output of reported electrostatic micro-generators to date does not meet the communication and computation requirements of wireless sensor nodes. The objective of this thesis is to investigate novel CMOS-based energy harvesting circuit (EHC) architectures to increase the level of harvested mechanical energy in electrostatic converters. The electronic circuits that facilitate mechanical to electrical energy conversion employing variable capacitors can either have synchronous or asynchronous architectures. The later does not require synchronization of electrical events with mechanical motion, which eliminates difficulties in gate clocking and the power consumption associated with complex control circuitry. However, the implementation of the EHC with the converter can be detrimental to system performance when done without concurrent optimization of both elements, an aspect mainly overlooked in the literature. System level analysis is performed to show that there is an optimum value for either the storage capacitor or cycle number for maximum scavenging of ambient energy. The analysis also shows that maximum power is extracted when the system approaches synchronous operation. However, there is a region of interest where the storage capacitor can be optimized to produce almost 70% of the ideal power taken as the power harvested with synchronous converters when neglecting the power consumption associated with synchronizing control circuitry. Theoretical predictions are confirmed by measurements on an asynchronous EHC implemented with a macro-scale electrostatic converter prototype. Based on the preceding analysis, the design of a novel ultra low power electrostatic integrated energy harvesting circuit is proposed for efficient harvesting of mechanical energy. The fundamental challenges of designing reliable low power sensing circuits for charge constrained electrostatic energy harvesters with capacity to self power its controller and driver stages are addressed. Experimental results are presented for a controller design implemented in AMI 0.7muM high voltage CMOS process using a macro-scale electrostatic converter prototype. The EHC produces 1.126muW for a power investment of 417nW with combined conduction and controller losses of 450nW which is a 20-30% improvement compared to prior art on electrostatic EHCs operating under charge constrain. Inherently dual plate variable capacitors harvest energy only during half of the mechanical cycle with the other half unutilized for energy conversion. To harvest mechanical energy over the complete mechanical vibration cycle, a low power energy harvesting circuit (EHC) that performs charge constrained synchronous energy conversion on a tri-plate variable capacitor for maximizing energy conversion is proposed. The tri-plate macro electrostatic generator with capacitor variation of 405pF to 1.15nF and 405pF to 1.07nF on two complementary adjacent capacitors is fabricated and used in the characterization of the designed EHC. The integrated circuit fabricated in AMI 0.7muM high voltage CMOS process, produces a total output power of 497nW to a 10muF reservoir capacitor from a 98Hz vibration signal. In summary, the thesis lays out the theoretical and experimental foundation for overcoming the main challenges associated with the design of charge constrained synchronous EHC's, making electrostatic converters a possible candidate for powering emerging communication transceivers and portable electronics.

FY2017 status report: Model 9975 O-ring fixture long-term leak performance

DOE Office of Scientific and Technical Information (OSTI.GOV)

Daugherty, W. L.

A series of experiments to monitor the aging performance of Viton® GLT and GLT-S O-rings used in the Model 9975 shipping package has been ongoing since 2004 at the Savannah River National Laboratory. One approach has been to periodically evaluate the leak performance of O-rings being aged in mock-up 9975 Primary Containment Vessels (PCVs) at elevated temperature. Other methods such as compression-stress relaxation (CSR) tests and field surveillance are also on-going to evaluate O-ring behavior. Seventy tests using PCV mock-ups with GLT O-rings were assembled and heated to temperatures ranging from 200 to 450 ºF. They were leak-tested initially andmore » have been tested periodically to determine if they continue to meet the leak-tightness criterion defined in ANSI standard N14.5-97. Due to material substitution, a smaller test matrix with fourteen additional tests was initiated in 2008 with GLT-S O-rings heated to temperatures ranging from 200 to 400 ºF. Leak test failures have been experienced in all of the GLT O-ring fixtures aging at 350 ºF and higher temperatures, and in 8 fixtures aging at 300 ºF. The 300 °F GLT O-ring fixtures failed after 2.8 to 5.7 years at temperature. The remaining GLT O-ring fixtures aging at 300 ºF were retired from testing following more than 5 years at temperature without failure. No failures have yet been observed in GLT O-ring fixtures aging at 200 ºF for 9 to 10.5 years, or in GLT O-ring fixtures aging at 270 ºF for 5.7 years. These aging temperatures bound O-ring temperatures anticipated during normal storage in K-Area Complex (KAC). Leak test failures have been experienced in all of the GLT-S O-ring fixtures aging at 300 ºF and above. No failures have yet been observed in GLT-S O-ring fixtures aging at 200 and 250 ºF for 6.9 to 7.5 years. Data from the O-ring fixtures are generally consistent with results from compression stress relaxation testing, and provide confidence in the predictive models based on those results. However, uncertainty still exists in extrapolating these elevated temperature results to the lower temperatures of interest for normal storage in KAC. Measurement of compression set in O-rings removed from failed fixtures, compared to that from KAC surveillance O-rings, indicates margin remains for O-rings still in service. Aging and periodic leak testing will continue for the remaining PCV fixtures.« less

Electrostatic Evaluation: SCAPE Suit Materials

NASA Technical Reports Server (NTRS)

Buhler, Charles; Calle, Carlos

2005-01-01

The surface resistivity tests are performed per the requirements of the ESD Association Standard Test Method ESD STM11.11*. These measurements are taken using a PRS-801 resistance system with an Electro Tech System (ETS) PRF-911 concentric ring resistance probe. The tests require a five pound weight on top of cylindrical electrodes and were conducted at both ambient and low humidity conditions. In order for materials to "pass" resistivity tests the surface of the materials must either be conductive or statically dissipative otherwise the materials "fail" ESD. Volume resistivity tests are also conducted to measure conductivity through the material as opposed to conductivity along the surface. These tests are conducted using the same PRS-801 resistance system with the Electro Tech System PRF-911 concentric ring resistance probe but are performed in accordance with ESD Association Standard Test Method ESD STM11.l2**.

Upgrades at the Duke Free Electron Laser Laboratory

NASA Astrophysics Data System (ADS)

Howell, Calvin R.

2004-11-01

Major upgrades to the storage-ring based photon sources at the Duke Free Electron Laser Laboratory (DFELL) are underway. The photon sources at the DFELL are well suited for research in the areas of medicine, biophysics, accelerator physics, nuclear physics and material science. These upgrades, which will be completed by the summer 2006, will significantly enhance the capabilities of the ultraviolet (UV) free-electron laser (FEL) and the high intensity gamma-ray source (HIGS). The HIGS is a relatively new research facility at the DFELL that is operated jointly by the DFELL and the Triangle Universities Nuclear Laboratory. The gamma-ray beam is produced by Compton back scattering of the UV photons inside the FEL optical cavity off the circulating electrons in the storage ring. The gamma-ray beam is 100% polarized and its energy resolution is selected by collimation. The capabilities of the upgraded facility will be described, the status of the upgrades will be summarized, and the proposed first-generation research program at HIGS will be presented.

Next Generation Muon g-2 Experiments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hertzog, David W.

2015-12-02

I report on the progress of two new muon anomalous magnetic moment experiments, which are in advanced design and construction phases. The goal of Fermilab E989 is to reduce the experimental uncertainty ofmore » $$a_\\mu$$ from Brookhaven E821 by a factor of 4; that is, $$\\delta a_\\mu \\sim 16 \\times 10^{-11}$$, a relative uncertainty of 140~ppb. The method follows the same magic-momentum storage ring concept used at BNL, and pioneered previously at CERN, but muon beam preparation, storage ring internal hardware, field measuring equipment, and detector and electronics systems are all new or upgraded significantly. In contrast, J-PARC E34 will employ a novel approach based on injection of an ultra-cold, low-energy, muon beam injected into a small, but highly uniform magnet. Only a small magnetic focusing field is needed to maintain storage, which distinguishes it from CERN, BNL and Fermilab. E34 aims to roughly match the previous BNL precision in their Phase~1 installation.« less

On intrinsic nonlinear particle motion in compact synchrotrons

NASA Astrophysics Data System (ADS)

Hwang, Kyung Ryun

Due to the low energy and small curvature characteristics of compact synchrotrons, there can be unexpected features that were not present or negligible in high energy accelerators. Nonlinear kinetics, fringe field effect, and space charge effect are those features which become important for low energy and small curvature accelerators. Nonlinear kinematics can limit the dynamics aperture for compact machine even if it consists of all linear elements. The contribution of the nonlinear kinematics on nonlinear optics parameters are first derived. As the dipole bending radius become smaller, the dipole fringe field effect become stronger. Calculation of the Lie map generator and corresponding mapping equation of dipole fringe field is presented. It is found that the higher order nonlinear potential is inverse proportional to powers of fringe field extent and correction to focusing and low order nonlinear potential is proportional to powers of fringe field extent. The fringe field also found to cause large closed orbit deviation for compact synchrotrons. The 2:1 and 4:1 space charge resonances are known to cause beam loss, emittance growth and halo formation for low energy high intensity beams. By numerical simulations, we observe a higher order 6:2 space charge resonance, which can successfully be understood by the concatenation of 2:1 and 4:1 resonances via canonical perturbation. We also develop an explicit symplectic tracking method for compact electrostatic storage rings and explore the feasibility of electric dipole moment (EDM) measurements.

In-depth study of in-trap high-resolution mass separation by transversal ion ejection from a multi-reflection time-of-flight device.

PubMed

Fischer, Paul; Knauer, Stefan; Marx, Gerrit; Schweikhard, Lutz

2018-01-01

The recently introduced method of ion separation by transversal ejection of unwanted species in electrostatic ion-beam traps and multi-reflection time-of-flight devices has been further studied in detail. As this separation is performed during the ion storage itself, there is no need for additional external devices such as ion gates or traps for either pre- or postselection of the ions of interest. The ejection of unwanted contaminant ions is performed by appropriate pulses of the potentials of deflector electrodes. These segmented ring electrodes are located off-center in the trap, i.e., between one of the two ion mirrors and the central drift tube, which also serves as a potential lift for capturing incoming ions and axially ejecting ions of interest after their selection. The various parameters affecting the selection effectivity and resolving power are illustrated with tin-cluster measurements, where isotopologue ion species provide mass differences down to a single atomic mass unit at ion masses of several hundred. Symmetric deflection voltages of only 10 V were found sufficient for the transversal ejection of ion species with as few as three deflection pulses. The duty cycle, i.e., the pulse duration with respect to the period of ion revolution, has been varied, resulting in resolving powers of up to several tens of thousands for this selection technique.

In-depth study of in-trap high-resolution mass separation by transversal ion ejection from a multi-reflection time-of-flight device

NASA Astrophysics Data System (ADS)

Fischer, Paul; Knauer, Stefan; Marx, Gerrit; Schweikhard, Lutz

2018-01-01

The recently introduced method of ion separation by transversal ejection of unwanted species in electrostatic ion-beam traps and multi-reflection time-of-flight devices has been further studied in detail. As this separation is performed during the ion storage itself, there is no need for additional external devices such as ion gates or traps for either pre- or postselection of the ions of interest. The ejection of unwanted contaminant ions is performed by appropriate pulses of the potentials of deflector electrodes. These segmented ring electrodes are located off-center in the trap, i.e., between one of the two ion mirrors and the central drift tube, which also serves as a potential lift for capturing incoming ions and axially ejecting ions of interest after their selection. The various parameters affecting the selection effectivity and resolving power are illustrated with tin-cluster measurements, where isotopologue ion species provide mass differences down to a single atomic mass unit at ion masses of several hundred. Symmetric deflection voltages of only 10 V were found sufficient for the transversal ejection of ion species with as few as three deflection pulses. The duty cycle, i.e., the pulse duration with respect to the period of ion revolution, has been varied, resulting in resolving powers of up to several tens of thousands for this selection technique.

Planetary radio astronomy observations from Voyager-2 near Saturn

NASA Technical Reports Server (NTRS)

Warwick, J. W.; Evans, D. R.; Romig, J. H.; Alexander, J. K.; Desch, M. D.; Kaiser, M. L.; Aubier, M.; Leblanc, Y.; Lecacheux, A.; Pedersen, B. M.

1981-01-01

Voyager-2 planetry radio astronomy measurements obtained near Saturn are discussed. They indicate that Saturnian kilometric radiation is emitted by a strong, dayside source at auroral latitudes in the northern hemisphere and by a weaker (by more than an order of magnitude) source at complementary latitudes in the southern hemisphere. These emissions are variable both due to Saturn's rotation and, on longer time scales, probably due to influences of the solar wind and the satellite Dione. The Saturn electrostatic discharge bursts first discovered by Voyager-1 and attributed to emissions from the B-ring were again observed with the same broadband spectral properties and a 10(h)11(m) + or - 5(m) episodic recurrence period but with an occurrence frequency of only of about 30 percent of that detected with Voyager-1. During the crossing of the ring plane at a distance of 2.88 R sub S, an intense noise event is interpreted to be consequence of the impact/vaporization/ionization of charged micron-size G-ring particles distributed over a total vertical thickness of about 1500 km.

Exploring hydride-π interactions and their tuning by σ-hole bonds: an ab initio study

NASA Astrophysics Data System (ADS)

Esrafili, Mehdi D.; Asadollahi, Soheila; Mousavian, Parisasadat

2018-01-01

In the present work, ab initio calculations are performed to investigate the geometry, interaction energy and bonding properties of binary complexes formed between metal-hydrides HMX (M = Be, Mg, Zn and X = H, F, CH3) and a series of π-acidic heteroaromatic rings. In all the resulting complexes, the heteroaromatic ring acts as a Lewis acid (electron acceptor), while the H atom of the HMX molecule acts as a Lewis base (electron donor). The nature of this interaction, called 'hydride-π' interaction, is explored in terms of molecular electrostatic potential, non-covalent interaction, quantum theory of atoms in molecules and natural bond orbital analyses. The results show that the interaction energies of these hydride-π interactions are between -1.24 and -2.72 kcal/mol. Furthermore, mutual influence between the hydride-π and halogen- or pnicogen-bonding interactions is studied in complexes in which these interactions coexist. For a given π-acidic ring, the formation of the pnicogen-bonding induces a larger enhancing effect on the strength of hydride-π bond than the halogen-bonding.

Near-infrared photoabsorption by C60 dianions in a storage ring.

PubMed

Kadhane, U; Andersen, J U; Bonderup, E; Concina, B; Hvelplund, P; Suhr Kirketerp, M-B; Liu, B; Nielsen, S Brøndsted; Panja, S; Rangama, J; Støchkel, K; Tomita, S; Zettergren, H; Hansen, K; Sundén, A E K; Canton, S E; Echt, O; Forster, J S

2009-07-07

We present a detailed study of the electronic structure and the stability of C(60) dianions in the gas phase. Monoanions were extracted from a plasma source and converted to dianions by electron transfer in a Na vapor cell. The dianions were then stored in an electrostatic ring, and their near-infrared absorption spectrum was measured by observation of laser induced electron detachment. From the time dependence of the detachment after photon absorption, we conclude that the reaction has contributions from both direct electron tunneling to the continuum and vibrationally assisted tunneling after internal conversion. This implies that the height of the Coulomb barrier confining the attached electrons is at least approximately 1.5 eV. For C(60)(2-) ions in solution electron spin resonance measurements have indicated a singlet ground state, and from the similarity of the absorption spectra we conclude that also the ground state of isolated C(60)(2-) ions is singlet. The observed spectrum corresponds to an electronic transition from a t(1u) lowest unoccupied molecular orbital (LUMO) of C(60) to the t(1g) LUMO+1 level. The electronic levels of the dianion are split due to Jahn-Teller coupling to quadrupole deformations of the molecule, and a main absorption band at 10,723 cm(-1) corresponds to a transition between the Jahn-Teller ground states. Also transitions from pseudorotational states with 200 cm(-1) and (probably) 420 cm(-1) excitation are observed. We argue that a very broad absorption band from about 11,500 cm(-1) to 13,500 cm(-1) consists of transitions to so-called cone states, which are Jahn-Teller states on a higher potential-energy surface, stabilized by a pseudorotational angular momentum barrier. A previously observed, high-lying absorption band for C(60)(-) may also be a transition to a cone state.

Enhancing electrical energy storage capability of dielectric polymer nanocomposites via the room temperature Coulomb blockade effect of ultra-small platinum nanoparticles.

PubMed

Wang, Liwei; Huang, Xingyi; Zhu, Yingke; Jiang, Pingkai

2018-02-14

Introducing a high dielectric constant (high-k) nanofiller into a dielectric polymer is the most common way to achieve flexible nanocomposites for electrostatic energy storage devices. However, the significant decrease of breakdown strength and large increase of dielectric loss has long been known as the bottleneck restricting the enhancement of practical energy storage capability of the nanocomposites. In this study, by introducing ultra-small platinum (<2 nm) nanoparticles, high-k polymer nanocomposites with high breakdown strength and low dielectric loss were prepared successfully. Core-shell structured polydopamine@BaTiO 3 (PDA@BT) and core-satellite ultra-small platinum decorated PDA@BT (Pt@PDA@BT) were used as nanofillers. Compared with PDA@BT nanocomposites, the maximum discharged energy density of the Pt@PDA@BT nanocomposites is increased by nearly 70% because of the improved energy storage efficiency. This research provides a simple, promising and unique way to enhance energy storage capability of high-k polymer nanocomposites.

Spin Pit Application of Image Derotated Holographic Interferometry.

DTIC Science & Technology

1980-09-01

temperatures resulting from induction heating of the test structuore through the interaction of the electromagnets and the magnetic ring. Subsequent...reference beam, and a Tektronix Model 7633 storage oscilloscope. When the laser is fired, a trigger signal from the laser power supply initiates the...rapid induction heating of the test structure due to the interaction of the electromagnets and the magnetic ring was evi(lent with the switch from dc to

Diagnostic Systems Plan for the Advanced Light Source Top-OffUpgrade

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barry, Walter; Chin, Mike; Robin, David

2005-05-10

The Advanced Light Source (ALS) will soon be upgraded to enable top-off operations [1], in which electrons are quasi-continuously injected to produce constant stored beam current. The upgrade is structured in two phases. First, we will upgrade our injector from 1.5 GeV to 1.9 GeV to allow full energy injection and will start top-off operations. In the second phase, we will upgrade the Booster Ring (BR) with a bunch cleaning system to allow high bunch purity top-off injection. A diagnostics upgrade will be crucial for success in both phases of the top-off project, and our plan for it is describedmore » in this paper. New booster ring diagnostics will include updated beam position monitor (BPM) electronics, a tune monitoring system, and a new scraper. Two new synchrotron light monitors and a beam stop will be added to the booster-to-storage ring transfer line (BTS), and all the existing beam current monitors along the accelerator chain will be integrated into a single injection efficiency monitoring application. A dedicated bunch purity monitor will be installed in the storage ring (SR). Together, these diagnostic upgrades will enable smooth commissioning of the full energy injector and a quick transition to high quality top-off operation at the ALS.« less

Experimental and analytical investigation of a modified ring cusp NSTAR engine

NASA Technical Reports Server (NTRS)

Sengupta, Anita

2005-01-01

A series of experimental measurements on a modified laboratory NSTAR engine were used to validate a zero dimensional analytical discharge performance model of a ring cusp ion thruster. The model predicts the discharge performance of a ring cusp NSTAR thruster as a function the magnetic field configuration, thruster geometry, and throttle level. Analytical formalisms for electron and ion confinement are used to predict the ionization efficiency for a given thruster design. Explicit determination of discharge loss and volume averaged plasma parameters are also obtained. The model was used to predict the performance of the nominal and modified three and four ring cusp 30-cm ion thruster configurations operating at the full power (2.3 kW) NSTAR throttle level. Experimental measurements of the modified engine configuration discharge loss compare well with the predicted value for propellant utilizations from 80 to 95%. The theory, as validated by experiment, indicates that increasing the magnetic strength of the minimum closed reduces maxwellian electron diffusion and electrostatically confines the ion population and subsequent loss to the anode wall. The theory also indicates that increasing the cusp strength and minimizing the cusp area improves primary electron confinement increasing the probability of an ionization collision prior to loss at the cusp.

The insertion device magnetic measurement facility: Prototype and operational procedures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Burkel, L.; Dejus, R.; Maines, J.

1993-03-01

This report is a description of the current status of the magnetic measurement facility and is a basic instructional manual for the operation of the facility and its components. Please refer to the appendices for more detailed information about specific components and procedures. The purpose of the magnetic measurement facility is to take accurate measurements of the magnetic field in the gay of the IDs in order to determine the effect of the ID on the stored particle beam and the emitted radiation. The facility will also play an important role when evaluating new ideas, novel devices, and inhouse prototypesmore » as part of the ongoing research and development program at the APS. The measurements will be performed with both moving search coils and moving Hall probes. The IDs will be evaluated by computer modeling of the emitted radiation for any given (measured) magnetic field map. The quality of the magnetic field will be described in terms of integrated multipoles for the effect on Storage Ring performance and in terms of the derived trajectories for the emitted radiation. Before being installed on the Storage Ring, every device will be measured and characterized to assure that it is compatible with Storage Ring requirements and radiation specifications. The accuracy that the APS needs to achieve for magnetic measurements will be based on these specifications.« less

Magnet design for a low-emittance storage ring

PubMed Central

Johansson, Martin; Anderberg, Bengt; Lindgren, Lars-Johan

2014-01-01

The MAX IV 3 GeV storage ring, currently under construction, pursues the goal of low electron beam emittance by using a multi-bend achromat magnet lattice, which is realised by having several consecutive magnet elements precision-machined out of a common solid iron block, 2.3–3.4 m long. With this magnet design solution, instead of having 1320 individual magnets, the MAX IV 3 GeV storage ring is built up using 140 integrated ‘magnet block’ units, containing all these magnet elements. Major features of this magnet block design are compactness, vibration stability and that the alignment of magnet elements within each unit is given by the mechanical accuracy of the CNC machining rather than individual field measurement and adjustment. This article presents practical engineering details of implementing this magnet design solution, and mechanical + magnetic field measurement results from the magnet production series. At the time of writing (spring 2014), the production series, which is totally outsourced to industry, is roughly half way through, with mechanical/magnetic QA conforming to specifications. It is the conclusion of the authors that the MAX IV magnet block concept, which has sometimes been described as new or innovative, is from a manufacturing point of view simply a collection of known mature production methods and measurement procedures, which can be executed at fixed cost with a low level of risk. PMID:25177980

Code comparison for accelerator design and analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Parsa, Z.

1988-01-01

We present a comparison between results obtained from standard accelerator physics codes used for the design and analysis of synchrotrons and storage rings, with programs SYNCH, MAD, HARMON, PATRICIA, PATPET, BETA, DIMAD, MARYLIE and RACE-TRACK. In our analysis we have considered 5 (various size) lattices with large and small angles including AGS Booster (10/degree/ bend), RHIC (2.24/degree/), SXLS, XLS (XUV ring with 45/degree/ bend) and X-RAY rings. The differences in the integration methods used and the treatment of the fringe fields in these codes could lead to different results. The inclusion of nonlinear (e.g., dipole) terms may be necessary inmore » these calculations specially for a small ring. 12 refs., 6 figs., 10 tabs.« less

TSR: A storage and cooling ring for HIE-ISOLDE

NASA Astrophysics Data System (ADS)

Butler, P. A.; Blaum, K.; Davinson, T.; Flanagan, K.; Freeman, S. J.; Grieser, M.; Lazarus, I. H.; Litvinov, Yu. A.; Lotay, G.; Page, R. D.; Raabe, R.; Siesling, E.; Wenander, F.; Woods, P. J.

2016-06-01

It is planned to install the heavy-ion, low-energy ring TSR, currently at the Max-Planck-Institute for Nuclear Physics in Heidelberg, at the HIE-ISOLDE facility in CERN, Geneva. Such a facility will provide a capability for experiments with stored, cooled secondary beams that is rich and varied, spanning from studies of nuclear ground-state properties and reaction studies of astrophysical relevance, to investigations with highly-charged ions and pure isomeric beams. In addition to experiments performed using beams recirculating within the ring, the cooled beams can be extracted and exploited by external spectrometers for high-precision measurements. The capabilities of the ring facility as well as some physics cases will be presented, together with a brief report on the status of the project.

Cassini Radio and Plasma Wave Observations at Saturn

NASA Technical Reports Server (NTRS)

Gurnett, D. A.; Kurth, W. S.; Hospodarsky, G. B.; Persoon, A. M.; Averkamp, T. F.; Ceccni, B.; Lecacheux, A.; Zarka, P.; Canu, P.; Cornilleau-Wehrlin, N.

2005-01-01

Results are presented from the Cassini radio and plasma wave instrument during the approach and first few orbits around Saturn. During the approach the intensity modulation of Saturn Kilometric Radiation (SKR) showed that the radio rotation period of Saturn has increased to 10 hr 45 min plus or minus 36 sec, about 6 min longer than measured by Voyager in 1980-81. Also, many intense impulsive radio signals called Saturn Electrostatic Discharges (SEDs) were detected from saturnian lightning, starting as far as 1.08 AU from Saturn, much farther than terrestrial lightning can be detected from Earth. Some of the SED episodes have been linked to cloud systems observed in Saturn s atmosphere by the Cassini imaging system. Within the magnetosphere plasma wave emissions have been used to construct an electron density profile through the inner region of the magnetosphere. With decreasing radial distance the electron density increases gradually to a peak of about 100 per cubic centimeter near the outer edge of the A ring, and then drops precipitously to values as low as .03 per cubic centimeter over the rings. Numerous nearly monochromatic whistler-mode emissions were observed as the spacecraft passed over the rings that are believed to be produced by meteoroid impacts on the rings. Whistlermode emissions, similar to terrestrial auroral hiss were also observed over the rings, indicating that an electrodynamic interaction, similar to auroral particle acceleration, may be occurring in or near the rings. During the Titan flybys Langmuir probe and plasma wave measurements provided observations of the density and temperature in Titan's ionosphere.

Structural Determinants of Improved Fluorescence in a Family of Bacteriophytochrome-Based Infrared Fluorescent Proteins: Insights from Continuum Electrostatic Calculations and Molecular Dynamics Simulations.

PubMed

Feliks, Mikolaj; Lafaye, Céline; Shu, Xiaokun; Royant, Antoine; Field, Martin

2016-08-09

Using X-ray crystallography, continuum electrostatic calculations, and molecular dynamics simulations, we have studied the structure, protonation behavior, and dynamics of the biliverdin chromophore and its molecular environment in a series of genetically engineered infrared fluorescent proteins (IFPs) based on the chromophore-binding domain of the Deinococcus radiodurans bacteriophytochrome. Our study suggests that the experimentally observed enhancement of fluorescent properties results from the improved rigidity and planarity of the biliverdin chromophore, in particular of the first two pyrrole rings neighboring the covalent linkage to the protein. We propose that the increases in the levels of both motion and bending of the chromophore out of planarity favor the decrease in fluorescence. The chromophore-binding pocket in some of the studied proteins, in particular the weakly fluorescent parent protein, is shown to be readily accessible to water molecules from the solvent. These waters entering the chromophore region form hydrogen bond networks that affect the otherwise planar conformation of the first three rings of the chromophore. On the basis of our simulations, the enhancement of fluorescence in IFPs can be achieved either by reducing the mobility of water molecules in the vicinity of the chromophore or by limiting the interactions of the nearby protein residues with the chromophore. Finally, simulations performed at both low and neutral pH values highlight differences in the dynamics of the chromophore and shed light on the mechanism of fluorescence loss at low pH.

Molecular and electronic structure, magnetotropicity and absorption spectra of benzene-trinuclear copper(I) and silver(I) trihalide columnar binary stacks.

PubMed

Tsipis, A C; Stalikas, A V

2012-02-20

The molecular and electronic structures, stabilities, bonding features, magnetotropicity and absorption spectra of benzene-trinuclear Cu(I) and Ag(I) trihalide columnar binary stacks with the general formula [c-M(3)(μ(2)-X)(3)](n)(C(6)H(6))(m) (M = Cu, Ag; X = halide; n, m ≤ 2) have been investigated by means of electronic structure calculation methods. The interaction of c-M(3)(μ(2)-X)(3) clusters with one and two benzene molecules yields 1:1 and 1:2 binary stacks, while benzene sandwiched 2:1 stacks are formed upon interaction of two c-M(3)(μ(2)-X)(3) clusters with one benzene molecule. In all binary stacks the plane of the alternating c-M(3)(μ(2)-X)(3) and benzene components adopts an almost parallel orientation. The separation distance between the centroids of the benzene and the proximal c-M(3)(μ(2)-X)(3) metallic cluster found in the range 2.97-3.33 Å at the B97D/Def2-TZVP level is indicative of a π···π stacking interaction mode, for the centroid separation distance is very close to the sum of the van der Waals radii of Cu···C (3.10 Å) and Ag···C (3.44 Å). Energy decomposition analysis (EDA) at the SSB-D/TZP level revealed that the dominant term in the c-M(3)(μ(2)-X)(3)···C(6)H(6) interaction arises from dispersion and electrostatic forces while the covalent interactions are predicted to be negligible. On the other hand, charge decomposition analysis (CDA) illustrated very small charge transfer from C(6)H(6) toward the c-M(3)(μ(2)-X)(3) clusters, thus reflecting weak π-base/π-acid interactions which are further corroborated by the respective electrostatic potentials and the fact that the total dipole moment vector points to the center of the metallic ring of the c-M(3)(μ(2)-X)(3) cluster. The absorption spectra of all aromatic columnar binary stacks simulated by means of TD-DFT calculations showed strong absorptions in the UV region. The main features of the simulated absorption spectra are thoroughly analyzed, and assignments of the contributing electronic transitions are given. The magnetotropicity of the binary stacks evaluated by the NICS(zz)-scan curves indicated an enhancement of the diatropicity of the inorganic ring upon interaction with the aromatic benzene molecule. Noteworthy is the slight enhancement of the diatropicity of the benzene ring, particularly in the region between the interacting rings, probably due to the superposition (coupling) of the diamagnetic ring currents of the interacting aromatic ring systems.

Binding of peptides with basic and aromatic residues to bilayer membranes: phenylalanine in the myristoylated alanine-rich C kinase substrate effector domain penetrates into the hydrophobic core of the bilayer.

PubMed

Zhang, Wenyi; Crocker, Evan; McLaughlin, Stuart; Smith, Steven O

2003-06-13

Electrostatic interactions with positively charged regions of membrane-associated proteins such as myristoylated alanine-rich C kinase substrate (MARCKS) may have a role in regulating the level of free phosphatidylinositol 4,5-bisphosphate (PI(4,5)P2) in plasma membranes. Both the MARCKS protein and a peptide corresponding to the effector domain (an unstructured region that contains 13 basic residues and 5 phenylalanines), MARCKS-(151-175), laterally sequester the polyvalent lipid PI(4,5)P2 in the plane of a bilayer membrane with high affinity. We used high resolution magic angle spinning NMR to establish the location of MARCKS-(151-175) in membrane bilayers, which is necessary to understand the sequestration mechanism. Measurements of cross-relaxation rates in two-dimensional nuclear Overhauser enhancement spectroscopy NMR experiments show that the five Phe rings of MARCKS-(151-175) penetrate into the acyl chain region of phosphatidylcholine bilayers containing phosphatidylglycerol or PI(4,5)P2. Specifically, we observed strong cross-peaks between the aromatic protons of the Phe rings and the acyl chain protons of the lipids, even for very short (50 ms) mixing times. The position of the Phe rings implies that the adjacent positively charged amino acids in the peptide are close to the level of the negatively charged lipid phosphates. The deep location of the MARCKS peptide in the polar head group region should enhance its electrostatic sequestration of PI(4,5)P2 by an "image charge" mechanism. Moreover, this location has interesting implications for membrane curvature and local surface pressure effects and may be relevant to a wide variety of other proteins with basic-aromatic clusters, such as phospholipase D, GAP43, SCAMP2, and the N-methyl-d-aspartate receptor.

Development and operating experience of a 1.1-m-long superconducting undulator at the Advanced Photon Source

DOE PAGES

Ivanyushenkov, Y.; Harkay, K.; Borland, M.; ...

2017-10-03

Development of superconducting undulators continues at the Advanced Photon Source (APS). Two years after successful installation and commissioning of the first relatively short superconducting undulator “SCU0” in Sector 6 of the APS storage ring, the second 1.1-m long superconducting undulator “SCU1” was installed in Sector 1 of the APS. The device has been in user operation since its commissioning in May 2015. This paper describes the magnetic and cryogenic design of the SCU1 together with the results of stand-alone cold tests. The SCU1’s magnetic and cryogenic performance as well as its operating experience in the APS storage ring are alsomore » presented.« less

Coupling control and optimization at the Canadian Light Source

NASA Astrophysics Data System (ADS)

Wurtz, W. A.

2018-06-01

We present a detailed study using the skew quadrupoles in the Canadian Light Source storage ring lattice to control the parameters of a coupled lattice. We calculate the six-dimensional beam envelop matrix and use it to produce a variety of objective functions for optimization using the Multi-Objective Particle Swarm Optimization (MOPSO) algorithm. MOPSO produces a number of skew quadrupole configurations that we apply to the storage ring. We use the X-ray synchrotron radiation diagnostic beamline to image the beam and we make measurements of the vertical dispersion and beam lifetime. We observe satisfactory agreement between the measurements and simulations. These methods can be used to adjust phase space coupling in a rational way and have applications to fine-tuning the vertical emittance and Touschek lifetime and measuring the gas scattering lifetime.

Prospects of high-resolution resonant X-ray inelastic scattering studies on solid materials, liquids and gases at diffraction-limited storage rings

PubMed Central

Schmitt, Thorsten; de Groot, Frank M. F.; Rubensson, Jan-Erik

2014-01-01

The spectroscopic technique of resonant inelastic X-ray scattering (RIXS) will particularly profit from immensely improved brilliance of diffraction-limited storage rings (DLSRs). In RIXS one measures the intensities of excitations as a function of energy and momentum transfer. DLSRs will allow for pushing the achievable energy resolution, signal intensity and the sampled spot size to new limits. With RIXS one nowadays probes a broad range of electronic systems reaching from simple molecules to complex materials displaying phenomena like peculiar magnetism, two-dimensional electron gases, superconductivity, photovoltaic energy conversion and heterogeneous catalysis. In this article the types of improved RIXS studies that will become possible with X-ray beams from DLSRs are envisioned. PMID:25177995

Development and operating experience of a 1.1-m-long superconducting undulator at the Advanced Photon Source

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ivanyushenkov, Y.; Harkay, K.; Borland, M.

Development of superconducting undulators continues at the Advanced Photon Source (APS). Two years after successful installation and commissioning of the first relatively short superconducting undulator “SCU0” in Sector 6 of the APS storage ring, the second 1.1-m long superconducting undulator “SCU1” was installed in Sector 1 of the APS. The device has been in user operation since its commissioning in May 2015. This paper describes the magnetic and cryogenic design of the SCU1 together with the results of stand-alone cold tests. The SCU1’s magnetic and cryogenic performance as well as its operating experience in the APS storage ring are alsomore » presented.« less

Time domain analysis of coherent terahertz synchrotron radiation

NASA Astrophysics Data System (ADS)

Hübers, H.-W.; Semenov, A.; Holldack, K.; Schade, U.; Wüstefeld, G.; Gol'tsman, G.

2005-10-01

The time structure of coherent terahertz synchrotron radiation at the electron storage ring of the Berliner Elektronensynchrotron und Speicherring Gesellschaft has been analyzed with a fast superconducting hot-electron bolometer. The emission from a single bunch of electrons was found to last ˜1500ps at frequencies around 0.4THz, which is much longer than the length of an electron bunch in the time domain (˜5ps). It is suggested that this is caused by multiple reflections at the walls of the beam line. The quadratic increase of the power with the number of electrons in the bunch as predicted for coherent synchrotron radiation and the transition from stable to bursting radiation were determined from a single storage ring fill pattern of bunches with different populations.

Experimental system for the control of surgically induced infections

NASA Technical Reports Server (NTRS)

Tevebaugh, M. D.

1971-01-01

The development tests to be performed on the experimental system are described in detail. The test equipment, conditions, and procedures are given. The portable clean room tests include assembly, collapsability, portability, and storage; laminar flow rate; static pressure; air flow pattern; and electrostatic buildup. The other tests are on the ventilation system, human factors evaluation, electrical subsystem, and material compatibility.

Structure and Bonding in Uranyl(VI) Peroxide and Crown Ether Complexes; Comparison of Quantum Chemical and Experimental Data.

PubMed

Vallet, Valérie; Grenthe, Ingmar

2017-12-18

The structure, chemical bonding, and thermodynamics of alkali ions in M[12-crown-4] + , M[15-crown-5] + , and M[18-crown-6] + , M[UO 2 (O 2 )(OH 2 ) 2 ] + 4,5 , and M[UO 2 (O 2 )(OH)(OH 2 )] n 1-n (n = 4, 5) complexes have been explored by using quantum chemical (QC) calculations at the ab initio level. The chemical bonding has been studied in the gas phase in order to eliminate solvent effects. QTAIM analysis demonstrates features that are very similar in all complexes and typical for electrostatic M-O bonds, but with the M-O bonds in the uranyl peroxide systems about 20 kJ mol -1 stronger than in the corresponding crown ether complexes. The regular decrease in bond strength with increasing M-O bond distance is consistent with predominantly electrostatic contributions. Energy decomposition of the reaction energies in the gas phase and solvent demonstrates that the predominant component of the total attractive (ΔE elec + ΔE orb ) energy contribution is the electrostatic component. There are no steric constraints for coordination of large cations to small rings, because the M + ions are located outside the ring plane, [O n ], formed by the oxygen donors in the ligands; coordination of ions smaller than the ligand cavity results in longer than normal M-O distances or in a change in the number of bonds, both resulting in weaker complexes. The Gibbs energies, enthalpies, and entropies of reaction calculated using the conductor-like screening model, COSMO, to account for solvent effects deviate significantly from experimental values in water, while those in acetonitrile are in much better agreement. Factors that might affect the selectivity are discussed, but our conclusion is that present QC methods are not accurate enough to describe the rather small differences in selectivity, which only amount to 5-10 kJ mol -1 . We can, however, conclude on the basis of QC and experimental data that M[crown ether] + complexes in the strongly coordinating water solvent are of outer-sphere type, [M(OH 2 ) n + ][crown ether], while those in weakly coordinating acetonitrile are of inner-sphere type, [M-crown ether] + . The observation that the M[UO 2 (O 2 )(OH)(OH 2 )] n 1-n complexes are more stable in solution than those of M[crown ether] + is an effect of the different charges of the rings.

Ferroelectric polymer dielectrics: Emerging materials for future electrostatic energy storage applications

NASA Astrophysics Data System (ADS)

Panda, Maheswar

2018-05-01

In this manuscript, the dielectric behavior of a variety of ferroelectric polymer dielectrics (FPD), which may bethe materials for future electrostatic energy storage application shave been discussed. The variety of polymer dielectrics, comprising of ferroelectric polymer[polyvinylidene fluoride (PVDF)]/non-polarpolymer [low density polyethylene (LDPE)] and different sizes of metal particles (Ni, quasicrystal of Al-Cu-Fe) as filler, were prepared through different process conditions (cold press/hot press) and are investigated experimentally. Very high values of effective dielectric constants (ɛeff) with low loss tangent (Tan δ) were observed forall the prepared FPD at their respective percolation thresholds (fc). The enhancement of ɛeff and Tan δ at the insulator to metal transition (IMT) is explained through the boundary layer capacitor effect and the percolation theory respectively. The non-universal fc/critical exponents across the IMT have been explained through percolation theory andis attributed to the fillerparticle size& shape, interaction between the components, method of their preparation, adhesiveness, connectivity and homogeneity, etc. of the samples. Recent results on developed FPD with high ɛeff and low Tan δ prepared through cold press have proven themselves to be the better candidates for low frequency and static dielectric applications.

Design of barrier bucket kicker control system

NASA Astrophysics Data System (ADS)

Ni, Fa-Fu; Wang, Yan-Yu; Yin, Jun; Zhou, De-Tai; Shen, Guo-Dong; Zheng, Yang-De.; Zhang, Jian-Chuan; Yin, Jia; Bai, Xiao; Ma, Xiao-Li

2018-05-01

The Heavy-Ion Research Facility in Lanzhou (HIRFL) contains two synchrotrons: the main cooler storage ring (CSRm) and the experimental cooler storage ring (CSRe). Beams are extracted from CSRm, and injected into CSRe. To apply the Barrier Bucket (BB) method on the CSRe beam accumulation, a new BB technology based kicker control system was designed and implemented. The controller of the system is implemented using an Advanced Reduced Instruction Set Computer (RISC) Machine (ARM) chip and a field-programmable gate array (FPGA) chip. Within the architecture, ARM is responsible for data presetting and floating number arithmetic processing. The FPGA computes the RF phase point of the two rings and offers more accurate control of the time delay. An online preliminary experiment on HIRFL was also designed to verify the functionalities of the control system. The result shows that the reference trigger point of two different sinusoidal RF signals for an arbitrary phase point was acquired with a matched phase error below 1° (approximately 2.1 ns), and the step delay time better than 2 ns were realized.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Plogmaker, Stefan; Johansson, Erik M. J.; Rensmo, Haakan

A novel light chopper system for fast timing experiments in the vacuum-ultraviolet (VUV) and x-ray spectral region has been developed. It can be phase-locked and synchronized with a synchrotron radiation storage ring, accommodating repetition rates in the range of {approx}8 to {approx}120 kHz by choosing different sets of apertures and subharmonics of the ring frequency (MHz range). Also the opening time of the system can be varied from some nanoseconds to several microseconds to meet the needs of a broad range of applications. Adjusting these parameters, the device can be used either for the generation of single light pulses ormore » pulse packages from a microwave driven, continuous He gas discharge lamp or from storage rings which are otherwise often considered as quasi-continuous light sources. This chopper can be utilized for many different kinds of experiments enabling, for example, unambiguous time-of-flight (TOF) multi-electron coincidence studies of atoms and molecules excited by a single light pulse as well as time-resolved visible laser pump x-ray probe electron spectroscopy of condensed matter in the valence and core level region.« less

Fabrication and test of model superconducting inflector for g-2 at FNAL

DOE PAGES

Krave, Steven; Kashikhin, Vladimir S.; Strauss, Thomas

2017-03-01

The new FNAL g-2 experiment is based on the muon storage ring previously used at BNL. The 1.45 T dipole magnetic field in the storage ring is required to have very high (1 ppm) homogeneity. The muon beam injected into the ring must be transported through the magnet yoke and the main superconducting coil cryostat with minimal distortions. The old inflector magnet shielded the main dipole fringe field inside the muon transport beam pipe, with an outer NbTi superconducting screen, and did not disturb the field in the area of circulating beam. Nevertheless, this magnet had coils with closed endsmore » in which a large fraction of muon beam particles were lost. A new magnet is envisioned utilizing the same cross section as the original with open ends for improved beam transport. A model magnet has been wound utilizing 3d printed parts to verify the magnetic behavior of the magnet at room temperature and validate winding of the complicated geometry required for the magnet ends. Finally, room temperature magnetic measurements have been performed and confirm the magnetic design« less

Long-range electrostatic complementarity governs substrate recognition by human chymotrypsin C, a key regulator of digestive enzyme activation.

PubMed

Batra, Jyotica; Szabó, András; Caulfield, Thomas R; Soares, Alexei S; Sahin-Tóth, Miklós; Radisky, Evette S

2013-04-05

Human chymotrypsin C (CTRC) is a pancreatic serine protease that regulates activation and degradation of trypsinogens and procarboxypeptidases by targeting specific cleavage sites within their zymogen precursors. In cleaving these regulatory sites, which are characterized by multiple flanking acidic residues, CTRC shows substrate specificity that is distinct from that of other isoforms of chymotrypsin and elastase. Here, we report the first crystal structure of active CTRC, determined at 1.9-Å resolution, revealing the structural basis for binding specificity. The structure shows human CTRC bound to the small protein protease inhibitor eglin c, which binds in a substrate-like manner filling the S6-S5' subsites of the substrate binding cleft. Significant binding affinity derives from burial of preferred hydrophobic residues at the P1, P4, and P2' positions of CTRC, although acidic P2' residues can also be accommodated by formation of an interfacial salt bridge. Acidic residues may also be specifically accommodated in the P6 position. The most unique structural feature of CTRC is a ring of intense positive electrostatic surface potential surrounding the primarily hydrophobic substrate binding site. Our results indicate that long-range electrostatic attraction toward substrates of concentrated negative charge governs substrate discrimination, which explains CTRC selectivity in regulating active digestive enzyme levels.

9975 Shipping package component long-term degradation rates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Daugherty, W. L.

Special nuclear materials are being stored in the K-Area Complex using 3013 containers that are held within Model 9975 shipping packages. The service life for these packages in storage was recently increased from 15 to 20 years, since some of these packages have been stored for nearly 15 years. A strategy is also being developed whereby such storage might be extended beyond 20 years. This strategy is based on recent calculations that support acceptable 9975 package performance for 20 years with internal heat loads up to 19 watts, and identifies a lower heat load limit for which the package componentsmore » should degrade at half the bounding rate or less, thus doubling the effective storage life for these lower wattage packages. The components of the 9975 package that are sensitive to aging under storage conditions are the fiberboard overpack and the O-ring seals, although some degradation of the lead shield and outer drum are also possible. This report summarizes degradation rates applicable to lower heat load storage conditions. In particular, the O-ring seals should provide leak-tight performance for more than 40 years in packages for which their maximum temperature is ≤135 °F. Similarly, the fiberboard should remain acceptable in performance of its required safety functions for up to 40 years in packages with a maximum fiberboard temperature ≤125 °F.« less

Assembly Architecture and DNA Binding of the Bacteriophage P22 Terminase Small Subunit

PubMed Central

Němeček, Daniel; Lander, Gabriel C.; Johnson, John E.; Casjens, Sherwood R.; Thomas, George J.

2008-01-01

Summary Morphogenesis of bacteriophage P22 involves the packaging of double-stranded DNA into a preassembled procapsid. DNA is translocated by a powerful virally-encoded molecular motor called terminase, which comprises large (gp2, 499 residues) and small (gp3, 162 residues) subunits. While gp2 contains the phosphohydrolase and endonuclease activities of terminase, the function of gp3 may be to regulate specific and nonspecific modes of DNA recognition as well as the enzymatic activities of gp2. Electron microscopy shows that wildtype gp3 self-assembles into a stable and monodisperse nonameric ring. A three-dimensional reconstruction at 18 Å resolution provides the first glimpse of P22 terminase architecture and implies two distinct modes of interaction with DNA – involving a central channel of 20 Å diameter and radial spikes separated by 34 Å. Electromobility shift assays indicate that the gp3 ring binds dsDNA nonspecifically in vitro via electrostatic interactions between the positively charged C-terminus of gp3 (residues 143–152) and phosphates of the DNA backbone. Raman spectra show that nonameric rings formed by subunits truncated at residue 142 retain the subunit fold, despite the loss of DNA-binding activity. Difference density maps between gp3 rings containing full-length and C-terminally truncated subunits are consistent with localization of residues 143–152 along the central channel of the nonameric ring. The results suggest a plausible molecular mechanism for gp3 function in DNA recognition and translocation. PMID:18775728

Hawaii Energy and Environmental Technologies Initiative 2010 (HEET10)

DTIC Science & Technology

2016-09-30

illustrated how local battery storage support of the lOMW Hawi wind farm can cause grid-wide issues. However, it was found that battery cycling can...capabilities pertaining to three different ex situ diagnostics were acquired and used under HEETlO. Focus was given to the catalyst (rotating ring ...cell. These capabilities are illustrated in Figure 9 1.1.1. Figure 1.1.1: (left) rotating ring /disc electrode; (middle) membrane conductivity cell

A FODO racetrack ring for nuSTORM: design and optimization

DOE PAGES

Liu, A.; Bross, A.; Neuffer, D.

2017-07-17

Here, the goal of nuSTORM is to provide well-defined neutrino beams for precise measurements of neutrino cross-sections and oscillations. The nuSTORM decay ring is a compact racetrack storage ring with a circumference of ~ 480 m that incorporates large aperture (60 cm diameter) magnets. There are many challenges in the design. In order to incorporate the Orbit Combination section (OCS), used for injecting the pion beam into the ring, a dispersion suppressor is needed adjacent to the OCS . Concurrently, in order to maximize the number of useful muon decays, strong bending dipoles are needed in the arcs to minimize themore » arc length. These dipoles create strong chromatic effects, which need to be corrected by nonlinear sextupole elements in the ring. In this paper, a FODO racetrack ring design and its optimization using sextupolar fields via both a Genetic Algorithm (GA) and a Simulated Annealing (SA) algorithm will be discussed.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shoup, R.W.; Long, F.; Martin, T.H.

Sandia is developing PBFA-Z, a 20-MA driver for z-pinch experiments by replacing the water lines, insulator stack, and MITLs on PBFA II with new hardware. The design of the vacuum insulator stack was dictated by the drive voltage, the electric field stress and grading requirements, the water line and MITL interface requirements, and the machine operations and maintenance requirements. The insulator stack will consist of four separate modules, each of a different design because of different voltage drive and hardware interface requirements. The shape of the components in each module, i.e., grading rings, insulator rings, flux excluders, anode and cathodemore » conductors, and the design of the water line and MITL interfaces, were optimized by using the electrostatic analysis codes, ELECTRO and JASON. The time dependent performance of the insulator stack was evaluated using IVORY, a 2-D PIC code. This paper will describe the insulator stack design and present the results of the ELECTRO and IVORY analyses.« less

A field-cancellation algorithm for constructing economical planar permanent magnet (PM) multipoles with large high-quality field apertures

NASA Astrophysics Data System (ADS)

Tatchyn, Roman

1997-05-01

In recent years studies have been initiated on a new class of multipole field generators consisting of cuboid planar permanent magnet (PM) pieces arranged in bi-planar arrays of 2-fold rotational symmetry(R. Tatchyn, "Planar Permanent Magnet Multipoles: for Particle Accelerator and Storage Ring Applications ," IEEE Trans. Mag. 30, 5050(1994).)(T. Cremer, R. Tatchyn, "Planar Permanent Magnet Multipoles: Measurements and Configurations," in Proceedings of the 1995 Particle Accelerator Conference, IEEE Catalog No. 95CH35843, paper FAQ-20.). These structures, first introduced for Free Electron Laser (FEL) applications(R. Tatchyn, "Selected applications of planar permanent magnet multipoles in FEL insertion device design," NIM A341, 449(1994).), are based on reducing the rotational symmetry of conventional N-pole field generators from N-fold to 2-fold. One consequence of this reduction is a large higher-multipole content in a planar PM multipole's field at distances relatively close to the structure's axis, making it generally unsuitable for applications requiring a large high-quality field aperture. In this paper we outline an economical field-cancellation algorithm that can substantially decrease the harmonic content of a planar PM's field without breaking its biplanar geometry or 2-fold rotational symmetry. This will enable planar PM multipoles to be employed in a broader range of applications than heretofore possible, in particular as distributed focusing elements installed in insertion device gaps on synchrotron storage rings. This accomplishment is expected to remove the conventional restriction of an insertion device's length to the scale of the local focusing beta, enabling short-period, small-gap undulators to be installed and operated as high-brightness sources on lower-energy storage rings(R. Tatchyn, P. Csonka, A. Toor, "Perspectives on micropole undulators in synchrotron radiation technology," Rev. Sci. Instrum. 60(7), 1796(1989).). Operation as ordinary focusing elements in storage ring magnetic lattices, as well as the performance of other high-quality multipole applications, should also becomes possible with the realization of the proposed structures.

ACCELERATORS: RF system design and measurement of HIRF-CSRe

NASA Astrophysics Data System (ADS)

Xu, Zhe; Zhao, Hong-Wei; Wang, Chun-Xiao; Xia, Jia-Wen; Zhan, Wen-Long; Bian, Zhi-Bin

2009-05-01

An RF system for the CSRe (cooling storage experimental ring) is designed and manufactured domestically. The present paper mainly describes the RF system design in five main sections: ferrite ring, RF cavity, RF generator, low level system and cavity cooling. The cavity is based on a type of coaxial resonator which is shorted at the end with one gap and loaded with domestic ferrite rings. The RF generator is designed in the push-pull mode and the low level control system is based on a DSP+FGPA+DDS+USB interface and has three feedback loops. Finally we give the results of the measurement on our system.

Tunable optical analog to electromagnetically induced transparency in graphene-ring resonators system.

PubMed

Wang, Yonghua; Xue, Chenyang; Zhang, Zengxing; Zheng, Hua; Zhang, Wendong; Yan, Shubin

2016-12-12

The analogue of electromagnetically induced transparency in optical ways has shown great potential in optical delay and quantum-information technology due to its flexible design and easy implementation. The chief drawback for these devices is the bad tunability. Here we demonstrate a tunable optical transparency system formed by graphene-silicon microrings which could control the transparent window by electro-optical means. The device consists of cascaded coupled ring resonators and a graphene/graphene capacitor which integrated on one of the rings. By tuning the Fermi level of the graphene sheets, we can modulate the round-trip ring loss so that the transparency window can be dynamically tuned. The results provide a new method for the manipulation and transmission of light in highly integrated optical circuits and quantum information storage devices.

DEVELOPMENT OF TITANIUM NITRIDE COATING FOR SNS RING VACUUM CHAMBERS.

DOE Office of Scientific and Technical Information (OSTI.GOV)

HE,P.; HSEUH,H.C.; MAPES,M.

2001-06-18

The inner surface of the ring vacuum chambers of the US Spallation Neutron Source (SNS) will be coated with {approximately}100 nm of Titanium Nitride (TiN). This is to minimize the secondary electron yield (SEY) from the chamber wall, and thus avoid the so-called e-p instability caused by electron multipacting as observed in a few high-intensity proton storage rings. Both DC sputtering and DC-magnetron sputtering were conducted in a test chamber of relevant geometry to SNS ring vacuum chambers. Auger Electron Spectroscopy (AES) and Rutherford Back Scattering (RBS) were used to analyze the coatings for thickness, stoichiometry and impurity. Excellent resultsmore » were obtained with magnetron sputtering. The development of the parameters for the coating process and the surface analysis results are presented.« less

Energy conversion in polyelectrolyte hydrogels

NASA Astrophysics Data System (ADS)

Olvera de La Cruz, Monica; Erbas, Aykut; Olvera de la Cruz Team

Energy conversion and storage have been an active field of research in nanotechnology parallel to recent interests towards renewable energy. Polyelectrolyte (PE) hydrogels have attracted considerable attention in this field due to their mechanical flexibility and stimuli-responsive properties. Ideally, when a hydrogel is deformed, applied mechanical work can be converted into electrostatic, elastic and steric-interaction energies. In this talk, we discuss the results of our extensive molecular dynamics simulations of PE hydrogels. We demonstrate that, on deformation, hydrogels adjust their deformed state predominantly by altering electrostatic interactions between their charged groups rather than excluded-volume and bond energies. This is due to the hydrogel's inherent tendency to preserve electro-neutrality in its interior, in combination with correlations imposed by backbone charges. Our findings are valid for a wide range of compression ratios and ionic strengths. The electrostatic-energy alterations that we observe in our MD simulations may induce pH or redox-potential changes inside the hydrogels. The resulting energetic difference can be harvested, for instance, analogously to a Carnot engine, or facilitated for sensor applications. Center for Bio-inspired Energy Science (CBES).

Self-surface charge exfoliation and electrostatically coordinated 2D hetero-layered hybrids

PubMed Central

Yang, Min-Quan; Xu, Yi-Jun; Lu, Wanheng; Zeng, Kaiyang; Zhu, Hai; Xu, Qing-Hua; Ho, Ghim Wei

2017-01-01

At present, the technological groundwork of atomically thin two-dimensional (2D) hetero-layered structures realized by successive thin film epitaxial growth is in principle constrained by lattice matching prerequisite as well as low yield and expensive production. Here, we artificially coordinate ultrathin 2D hetero-layered metal chalcogenides via a highly scalable self-surface charge exfoliation and electrostatic coupling approach. Specifically, bulk metal chalcogenides are spontaneously exfoliated into ultrathin layers in a surfactant/intercalator-free medium, followed by unconstrained electrostatic coupling with a dissimilar transition metal dichalcogenide, MoSe2, into scalable hetero-layered hybrids. Accordingly, surface and interfacial-dominated photocatalysis reactivity is used as an ideal testbed to verify the reliability of diverse 2D ultrathin hetero-layered materials that reveal high visible-light photoreactivity, efficient charge transfer and intimate contact interface for stable cycling and storage purposes. Such a synthetic approach renders independent thickness and composition control anticipated to advance the development of ‘design-and-build' 2D layered heterojunctions for large-scale exploration and applications. PMID:28146147

Simulation of emittance dilution in electron storage ring from Compton backscattering

DOE Office of Scientific and Technical Information (OSTI.GOV)

Blumberg, L.N.; Blum, E.

1993-07-01

A Monte-Carlo simulation of Compton backscattered {kappa}{sub L}=3.2-{mu}m photons from an IR-FEL on 75-MeV electrons in a storage ring yields an RMS electron energy spread of {Delta}{sub E}=11.9-keV for a sample of 10{sup 7} single scattering events. Electrons are sampled from a beam of natural energy spread {sigma}{sub E} = 5.6-keV and damped transverse angle spreads {sigma}{sub x}{prime}, = .041-mrad and {sigma}{sub y}{prime} = .052-mrad (100%) coupling, scaled from the 200-MeV BNL XLS compact storage ring. The Compton-scattered X-Rays are generated from an integral of the CM Klein-Nishina cross-section transformed to the lab. A tracking calculation has also been performedmore » in 6-dimensional phase space. Initial electron coordinates are selected randomly from a Gaussian distribution of RMS spreads {sigma}{sub xo}=.102-mm, {sigma}{sub x{prime}o}=.041-mrad, {sigma}{sub yo}=.018-mm, {sigma}{sub y{prime}o}=.052-mrad, {sigma}{sub {phi}o}=22-mrad and {sigma}{sub Eo}=6-keV. A sample of 10000 electrons were each following for 40000 turns around the ring through an RF cavity of f{sub rf}=211.54-MHz and peak voltage V{sub m}=300-keV. Preliminary results indicate that the resulting energy distribution is quite broad with an RMS width of {Delta}{sub E} = 124-keV. The transverse widths are only slightly increased from their original values, i.e. {Delta}{sub x} = .106-mm and {Delta}{sub x}{prime}=.043 mrad. The scaled energy spread of {Delta}{sub E} {approximately} 360-keV for {approximately} 350,000 turns desired in a 10-msec X-Ray angiography exposure is well within the RF bucket used here; even V{sub m} < 50-kV is adequate. Further, the electron energy spread adds a negligible RMS X-Ray energy spread of {Delta}{sub Ex}=.32-keV. The electron energy damping time of {tau}{sub E}=379-msec at 75-MeV in an XLS-type ring allows for damping this induced spread and top-off of the ring between heart cycles.« less

RNA folding: structure prediction, folding kinetics and ion electrostatics.

PubMed

Tan, Zhijie; Zhang, Wenbing; Shi, Yazhou; Wang, Fenghua

2015-01-01

Beyond the "traditional" functions such as gene storage, transport and protein synthesis, recent discoveries reveal that RNAs have important "new" biological functions including the RNA silence and gene regulation of riboswitch. Such functions of noncoding RNAs are strongly coupled to the RNA structures and proper structure change, which naturally leads to the RNA folding problem including structure prediction and folding kinetics. Due to the polyanionic nature of RNAs, RNA folding structure, stability and kinetics are strongly coupled to the ion condition of solution. The main focus of this chapter is to review the recent progress in the three major aspects in RNA folding problem: structure prediction, folding kinetics and ion electrostatics. This chapter will introduce both the recent experimental and theoretical progress, while emphasize the theoretical modelling on the three aspects in RNA folding.

Packaging films for electronic and space-related hardware

NASA Astrophysics Data System (ADS)

Shon, E. M.; Hamberg, O.

1985-08-01

Flexible packaging films are used to bag and/or wrap precision cleaned electronic or space hardware to protect them from environmental degradation during shipping and storage. Selection of packaging films depends on a knowledge of product requirements and packaging film characteristics. The literature presently available on protective packaging films has been updated to include new materials and to amplify space-related applications. Presently available packaging film materials are compared for their various characteristics: electrostatic discharge (ESD) control, flame retardancy, water vapor transmission rate, particulate shedding, molecular contamination, and transparency. The tradeoff between product requirements and the characteristics of the packaging films available are discussed. Selection considerations are given for the application of specific materials of space hardware-related applications. Applications for intimate, environmental, and electrostatic protective packaging are discussed.

Principles for timing at spallation neutron sources based on developments at LANSCE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Nelson, R. O.; Merl, R. B.; Rose, C. R.

2001-01-01

Due to AC-power-grid frequency fluctuations, the designers for accelerator-based spallation-neutron facilities have worked to optimize the conflicting demands of accelerator and neutron chopper performance. For the first time, we are able to quantitatively access the tradeoffs between these two constraints and design or upgrade a facility to optimize total system performance using powerful new simulation techniques. We have modeled timing systems that integrate chopper controllers and chopper hardware and built new systems. Thus, at LANSCE, we now operate multiple chopper systems and the accelerator as simple slaves to a single master-timing-reference generator. Based on this experience we recommend that spallationmore » neutron sources adhere to three principles. First, timing for pulsed sources should be planned starting with extraction at a fixed phase and working backwards toward the leading edge of the beam pulse. Second, accelerator triggers and storage ring extraction commands from neutron choppers offer only marginal benefits to accelerator-based spallation sources. Third, the storage-ring RF should be phase synchronized with neutron choppers to provide extraction without the one orbit timing uncertainty.« less

Space charge tune shift, fast resonance traversal, and current limits in circular accelerators

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rees, G.H.

1996-06-01

Space charge tune shifts, fast resonance traversals, and current limits are important design issues for low energy, high power circular accelerators. Areas of interest are accumulator rings and fast cycling synchrotrons, and typical applications are for pulsed spallation neutron sources, heavy ion fusion storage ring drivers, and booster injectors for high energy proton and ion facilities. Aspects of the three topics are discussed in the paper. {copyright} {ital 1996 American Institute of Physics.}

Preparation, one- and two-photon properties of carbazole derivatives containing nitrogen heterocyclic ring

NASA Astrophysics Data System (ADS)

Zhang, Yichi; Wang, Ping; Li, Liang; Chen, Zhimin; He, Chunying; Wu, Yiqun

Preparation of recording materials with high two-photon absorption activities is one of the important issues to superhigh- density two-photon absorption (TPA) three-dimensional (3D) optical data storage. In this paper, three new carbazole derivatives containing nitrogen heterocyclic ring with symmetric and asymmetric structures are prepared using ethylene as the π bridge between the carbazole unit and nitrogen heterocyclic ring, namely, 9-butyl-3-(2-(1,8- naphthyridin)vinyl)-carbazole (material 1), 9-butyl-3,6-bis(2-(1,8-naphthyl)vinyl)-carbazole (material 2) and 9-butyl-3,6- bis(2-(quinolin)vinyl)-carbazole (material 3). Their one photon properties including linear absorption spectra, fluorescence emission spectra, and fluorescence quantum yields are studied. The fluorescence excited by 120 fs pulse at 800 nm Ti: sapphire laser operating at 1 kHz repetition rate with different incident powers of 9-butyl-3-(2-(quinolin) vinyl)-carbazole (material 3) was investigated, and two-photon absorption cross-sections has been obtained. It is shown that material 3 containing quinoline rings as electron acceptor with symmetric structure exhibit high two-photon absorption activity. The result implies that material 3 (9-butyl-3-(2-(quinolin) vinyl)-carbazole) is a good candidate as a promising recording material for super-high-density two-photon absorption (TPA) three-dimensional (3D) optical data storage. The influence of chemical structure of the materials on the optical properties is discussed.

FIRST BEAM TESTS OF THE APS MBA UPGRADE ORBIT FEEDBACK CONTROLLER

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sereno, N. S.; Arnold, N.; Brill, A.

The new orbit feedback system required for the APS multi-bend acromat (MBA) ring must meet challenging beam stability requirements. The AC stability requirement is to correct rms beam motion to 10 % the rms beam size at the insertion device source points from 0.01 to 1000 Hz. The vertical plane represents the biggest challenge for AC stability which is required to be 400 nm rms for a 4 micron vertical beam size. In addition long term drift over a period of 7 days is required to be 1 micron or less at insertion de- vice BPMs and 2 microns formore » arc bpms. We present test re- sults of theMBA prototype orbit feedback controller (FBC) in the APS storage ring. In this test, four insertion device BPMs were configured to send data to the FBC for process- ing into four fast corrector setpoints. The configuration of four bpms and four fast correctors creates a 4-bump and the configuration of fast correctors is similar to what will be implemented in the MBA ring. We report on performance benefits of increasing the sampling rate by a factor of 15 to 22.6 kHz over the existing APS orbit feedback system, lim- itations due to existing storage ring hardware and extrapo- lation to theMBA orbit feedback design. FBC architecture, signal flow and processing design will also be discussed.« less

Calculations of the conditions for bunch leakage in the Los Alamos proton storage ring

NASA Astrophysics Data System (ADS)

Neuffer, D.; Ohmori, C.

1994-04-01

Observations are consistent with the possibility of an "ep" instability in the Los Alamos Proton Storage Ring (PSR) with both bunched and unbunched beam. The instability requires electrons to be trapped within the beam, and calculations have shown that such trapping requires leakage of beam into the interbunch gap. Observationally, leakage of beam into the gap appears necessary for the onset of the instability. In this paper we present results of studies of the longitudinal beam dynamics at PSR parameters. The studies indicate that the combined effects of the rf buncher, longitudinal space charge, and injection mismatch are sufficient to cause the observed bunch leakage. Simulation results are presented and compared with PSR observations. Variations of PSR performance parameters are considered, and methods of improving bunch confinement are suggested and studied.

STORAGE RING CROSS SECTION MEASUREMENTS FOR ELECTRON IMPACT IONIZATION OF Fe{sup 7+}

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hahn, M.; Novotný, O.; Savin, D. W.

2015-11-01

We have measured electron impact ionization for Fe{sup 7+} from the ionization threshold up to 1200 eV. The measurements were performed using the TSR heavy ion storage ring. The ions were stored long enough prior to measurements to remove most metastables, resulting in a beam of 94% ground-level ions. Comparing with the previously recommended atomic data, we find that the Arnaud and Raymond cross section is up to about 40% larger than our measurement, with the largest discrepancies below about 400 eV. The cross section of Dere agrees to within 10%, which is about the magnitude of the experimental uncertainties.more » The remaining discrepancies between our measurement and the Dere calculations are likely due to shortcomings in the theoretical treatment of the excitation-autoionization contribution.« less

Installation of a second superconducting wiggler at SAGA-LS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaneyasu, T., E-mail: kaneyasu@saga-ls.jp; Takabayashi, Y.; Iwasaki, Y.

The SAGA Light Source is a synchrotron radiation facility consisting of a 255 MeV injector linac and a 1.4 GeV storage ring with a circumference of 75.6 m. A superconducting wiggler (SCW) with a peak magnetic field of 4 T has been routinely operating for generating hard X-rays since its installation in 2010. In light of this success, it was decided to install a second SCW as a part of the beamline construction by Sumitomo Electric Industries. To achieve this, machine modifications including installation of a new magnet power supply, improvement of the magnet control system, and replacement of themore » vacuum chambers in the storage ring were carried out. Along with beamline construction, installation and commissioning of the second SCW are scheduled to take place in 2015.« less

Non-exponential decoherence of radio-frequency resonance rotation of spin in storage rings

NASA Astrophysics Data System (ADS)

Saleev, A.; Nikolaev, N. N.; Rathmann, F.; Hinder, F.; Pretz, J.; Rosenthal, M.

2017-08-01

Precision experiments, such as the search for electric dipole moments of charged particles using radio-frequency spin rotators in storage rings, demand for maintaining the exact spin resonance condition for several thousand seconds. Synchrotron oscillations in the stored beam modulate the spin tune of off-central particles, moving it off the perfect resonance condition set for central particles on the reference orbit. Here, we report an analytic description of how synchrotron oscillations lead to non-exponential decoherence of the radio-frequency resonance driven up-down spin rotations. This non-exponential decoherence is shown to be accompanied by a nontrivial walk of the spin phase. We also comment on sensitivity of the decoherence rate to the harmonics of the radio-frequency spin rotator and a possibility to check predictions of decoherence-free magic energies.

Development of a bunch-by-bunch longitudinal feedback system with a wide dynamic range for the HIGS facility

NASA Astrophysics Data System (ADS)

Wu, W. Z.; Kim, Y.; Li, J. Y.; Teytelman, D.; Busch, M.; Wang, P.; Swift, G.; Park, I. S.; Ko, I. S.; Wu, Y. K.

2011-03-01

Electron beam coupled-bunch instabilities can limit and degrade the performance of storage ring based light sources. A longitudinal feedback system has been developed for the Duke storage ring to suppress multi-bunch beam instabilities which prevent stable, high-current operation of the storage ring based free-electron lasers (FELs) and an FEL driven Compton gamma source, the high intensity gamma-ray source (HIGS) at Duke University. In this work, we report the development of a state-of-the-art second generation longitudinal feedback system which employs a field programmable gate array (FPGA) based processor, and a broadband, high shunt-impedance kicker cavity. With two inputs and two outputs, the kicker cavity was designed with a resonant frequency of 937 MHz, a bandwidth of 97 MHz, and a shunt impedance of 1530 Ω. We also developed an S-matrix based technique to fully characterize the performance of the kicker cavity in the cold test. This longitudinal feedback system has been commissioned and optimized to stabilize high-current electron beams with a wide range of electron beam energies (250 MeV to 1.15 GeV) and a number of electron beam bunch modes, including the single-bunch mode and all possible symmetric bunch modes. This feedback system has become a critical instrument to ensure stable, high-flux operation of HIGS to produce nearly monochromatic, highly polarized Compton gamma-ray beams.

Analysis of coupled-bunch instabilities for the NSLS-II storage ring with a 500MHz 7-cell PETRA-III cavity

DOE PAGES

Bassi, G.; Blednykh, A.; Cheng, W.; ...

2015-12-11

We present the NSLS-II storage ring that is designed to operate with superconducting RF-cavities with the aim to store an average current of 500 mA distributed in 1080 bunches, with a gap in the uniform filling for ion clearing. At the early stage of the commissioning (phase 1), characterized by a bare lattice without damping wigglers and without Landau cavities, a normal conducting 7-cell PETRA-III RF-cavity structure has been installed with the goal to store an average current of 25 mA. In this paper we discuss our analysis of coupled-bunch instabilities driven by the Higher Order Modes (HOMs) of themore » 7-cell PETRA-III RF-cavity. As a cure of the instabilities, we apply a well-known scheme based on a proper detuning of the HOMs frequencies based upon cavity temperature change, and the use of the beneficial effect of the slow head–tail damping at positive chromaticity to increase the transverse coupled-bunch instability thresholds. In addition, we discuss measurements of coupled-bunch instabilities observed during the phase 1 commissioning of the NSLS-II storage ring. In our analysis we rely, in the longitudinal case, on the theory of coupled-bunch instability for uniform fillings, while in the transverse case we complement our studies with numerical simulations with OASIS, a novel parallel particle tracking code for self-consistent simulations of collective effects driven by short and long-range wakefields.« less

NINTH INTERIM STATUS REPORT: MODEL 9975 PCV O-RING FIXTURE LONG-TERM LEAK PERFORMANCE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Daugherty, W.

2014-08-06

A series of experiments to monitor the aging performance of Viton® GLT O-rings used in the Model 9975 package has been ongoing since 2004 at the Savannah River National Laboratory. One approach has been to periodically evaluate the leak performance of O-rings being aged in mock-up 9975 Primary Containment Vessels (PCVs) at elevated temperatures. Other methods such as compression-stress relaxation (CSR) tests and field surveillance are also on-going to evaluate O-ring behavior. Seventy tests using PCV mock-ups were assembled and heated to temperatures ranging from 200 to 450 ºF. They were leak-tested initially and have been tested periodically to determinemore » if they continue to meet the leak-tightness criterion defined in ANSI standard N14.5-97. Due to material substitution, fourteen additional tests were initiated in 2008 with GLT-S O-rings heated to temperatures ranging from 200 to 400 ºF. High temperature aging continues for 23 GLT O-ring fixtures at 200 – 270 ºF. Room temperature leak test failures have been experienced in all of the GLT O-ring fixtures aging at 350 ºF and higher temperatures, and in 8 fixtures aging at 300 ºF. The earliest 300 °F GLT O-ring fixture failure was observed at 34 months. The remaining GLT O-ring fixtures aging at 300 ºF have been retired from testing following more than 5 years at temperature without failure. No failures have yet been observed in GLT O-ring fixtures aging at 200 ºF for 72 - 96 months, which bounds O-ring temperatures anticipated during storage in K-Area Complex (KAC). Based on expectations that the 200 ºF fixtures will remain leak-tight for a significant period yet to come, 2 additional fixtures began aging in 2011 at 270 ºF, with hopes that they may reach a failure condition before the 200 ºF fixtures, thus providing additional time to failure data. High temperature aging continues for 6 GLT-S O-ring fixtures at 200 – 300 ºF. Room temperature leak test failures have been experienced in all 8 of the GLT-S O-ring fixtures aging at 350 and 400 ºF. No failures have yet been observed in GLT-S O-ring fixtures aging at 200 - 300 ºF for 54 - 57 months. No additional O-ring failures have been observed since the last interim report was issued. Aging and periodic leak testing will continue for the remaining PCV fixtures. Additional irradiation of several fixtures is recommended to maintain a balance between thermal and radiation exposures similar to that experienced in storage, and to show the degree of consistency of radiation response between GLT and GLT-S O-rings.« less

Synthetic Motors and Nanomachines.

NASA Astrophysics Data System (ADS)

Flood, Amar

2006-03-01

A bistable and palindromically-constituted [3]rotaxane incorporating two mechanically-mobile rings interlocked around a linear dumbbell component, has been designed to operate like the sarcomeres of skeletal muscle. Contraction and extension occurs when the inter-ring distance of the two rings switch, ideally, between 4.2 and 1.4 nm upon redox stimulation either chemically or electrochemically in the solution phase. When the mobile rings of these artificial molecular muscles are bound onto the tops of gold-coated, micron-scale cantilever beams, their controllable nanometer motions have a chance to be amplified along the long axis of each cantilever. It turns out that ˜6 billion of the self-assembled [3]rotaxanes can bend the cantilevers in a bistable manner concomitant with the cycled addition of redox agents. The extent of bending is commensurate with 10's of pN of force per [3]rotaxane. Recent studies on a set of ``single-shot'' control [2]rotaxanes have provided additional evidence for the origins of the force generation as it arises from a molecule-based electrostatic repulsion energy of about 10 kcal/mol at 300 K. These findings will be presented in terms of the underlying thermodynamics and kinetics that have been utilized extensively to direct the design and synthesis of artificial molecular machines and which may also serve as a guide for the rational design of unidirectional molecular motors.

Deciphering Stability of Five-Membered Heterocyclic Radicals: Balancing Act Between Delocalization and Ring Strain.

PubMed

Sah, Chitranjan; Yadav, Ajit Kumar; Venkataramani, Sugumar

2018-06-21

Computational studies on five-membered heterocycles with single heteroatom and their isomeric dehydro-borole 1a-1c, cyclopentadiene 2a-2c, pyrrole 3a-3c, furan 4b-4c, phosphole 5a-5c, and thiophene 6b-6c radicals have been carried out. Geometrical aspects through ground state electronic structures and stability aspects using bond dissociation energies (BDE) and radical stabilization energies (RSE) have been envisaged in this regard. Spin densities, electrostatic potentials (ESP), and natural bond orbital (NBO) analysis unveiled the extent of spin delocalization. The estimated nucleus-independent chemical shifts (NICS) values revealed the difference in aromaticity characteristics of radicals. Particularly the heteroatom centered radicals exhibit odd electron π-delocalized systems with a quasi-antiaromatic character. Various factors such as, the relative position of the radical center with respect to heteroatoms, resonance, ring strain and orbital interactions influence the stability that follows the order: heteroatom centered > β-centered > α-centered radicals. Among the influences of various factors, we confirmed the existence of a competition between delocalization and the ring strain, and the interplay of both decides the overall stability order.

Particle-in-cell simulations of the lower-hybrid instability driven by an ion-ring distribution

NASA Astrophysics Data System (ADS)

Swanekamp, Stephen; Richardson, Steve; Mithaiwala, Manish; Crabtree, Chris

2013-10-01

Fully electromagnetic particle-in-cell simulations of the excitation of the lower-hybrid mode in a plasma driven by an ion-ring distribution using the Lsp code are presented. At early times the simulations agree with linear theory. The resulting wave evolution and non-linear plasma and ring-ion heating are compared with theoretical models [Mithaiwala et al. 2010; Crabtree et al., this meeting] and previous simulation results [Winske and Daughton, 2012]. 2D simulations show that when the magnetic field is perpendicular to the wave vector, k, the electrostatic potential fluctuations work in conjunction with the applied magnetic field causing a circular electron E ×B drift around a positively charged center. Similar phenomena are observed in 2D simulations of magnetic-field penetration into a spatially inhomogeneous unmagnetized plasma [Richardson et al., this meeting] where circular paramagnetic vortices are formed. These vortices are altered by the addition of a small, in-plane, component of magnetic field which allows electrons to stream along field lines effectively shorting out one component of the electric field. In this case, the vortex structures are no longer circular but elongated along the direction of the in-plane magnetic field component.

A drift chamber constructed of aluminized mylar tubes

NASA Astrophysics Data System (ADS)

Baringer, P.; Jung, C.; Ogren, H. O.; Rust, D. R.

1987-03-01

A thin reliable drift chamber has been constructed to be used near the interaction point of the PEP storage ring in the HRS detector. It is composed of individual drift tubes with aluminized mylar walls.

Diclofenac removal in urine using strong-base anion exchange polymer resins.

PubMed

Landry, Kelly A; Boyer, Treavor H

2013-11-01

One of the major sources of pharmaceuticals in the environment is wastewater effluent of which human urine contributes the majority of pharmaceuticals. Urine source separation has the potential to isolate pharmaceuticals at a higher concentration for efficient removal as well as produce a nutrient byproduct. This research investigated the efficacy of using strong-base anion exchange polymer resins to remove the widely detected and abundant pharmaceutical, diclofenac, from synthetic human urine under fresh and ureolyzed conditions. The majority of experiments were conducted using a strong-base, macroporous, polystyrene resin (Purolite A520E). Ion-exchange followed a two-step removal rate with rapid removal in 1 h and equilibrium removal in 24 h. Diclofenac removal was >90% at a resin dose of 8 mL/L in both fresh and ureolyzed urine. Sorption of diclofenac onto A520E resin was concurrent with desorption of an equivalent amount of chloride, which indicates the ion-exchange mechanism is occurring. The presence of competing ions such as phosphate and citrate did not significantly impact diclofenac removal. Comparisons of three polystyrene resins (A520E, Dowex 22, Dowex Marathon 11) as well as one polyacrylic resin (IRA958) were conducted to determine the major interactions between anion exchange resin and diclofenac. The results showed that polystyrene resins provide the highest level of diclofenac removal due to electrostatic interactions between quaternary ammonium functional groups of resin and carboxylic acid of diclofenac and non-electrostatic interactions between resin matrix and benzene rings of diclofenac. Diclofenac was effectively desorbed from A520E resin using a regeneration solution that contained 4.5% (m/m) NaCl in an equal-volume mixture of methanol and water. The greater regeneration efficiency of the NaCl/methanol-water mixture over the aqueous NaCl solution supports the importance of non-electrostatic interactions between resin matrix and benzene rings of diclofenac. Experiments with ketoprofen, in addition to diclofenac, suggest that polystyrene anion exchange resins can be used to selectively remove other acidic pharmaceuticals from urine. Copyright © 2013 Elsevier Ltd. All rights reserved.

Tunable optical analog to electromagnetically induced transparency in graphene-ring resonators system

PubMed Central

Wang, Yonghua; Xue, Chenyang; Zhang, Zengxing; Zheng, Hua; Zhang, Wendong; Yan, Shubin

2016-01-01

The analogue of electromagnetically induced transparency in optical ways has shown great potential in optical delay and quantum-information technology due to its flexible design and easy implementation. The chief drawback for these devices is the bad tunability. Here we demonstrate a tunable optical transparency system formed by graphene-silicon microrings which could control the transparent window by electro-optical means. The device consists of cascaded coupled ring resonators and a graphene/graphene capacitor which integrated on one of the rings. By tuning the Fermi level of the graphene sheets, we can modulate the round-trip ring loss so that the transparency window can be dynamically tuned. The results provide a new method for the manipulation and transmission of light in highly integrated optical circuits and quantum information storage devices. PMID:27941895

Spin Transparent Siberian Snake And Spin Rotator With Solenoids

DOE Office of Scientific and Technical Information (OSTI.GOV)

Koop, I. A.; Otboyev, A. V.; Shatunov, P. Yu.

2007-06-13

For intermediate energies of electrons and protons it happens that it is more convenient to construct Siberian snakes and spin rotators using solenoidal fields. Strong coupling caused by the solenoids is suppressed by a number of skew and normal quadrupole magnets. More complicate problem of the spin transparency of such devices also can be solved. This paper gives two examples: spin rotator for electron ring in the eRHIC project and Siberian snake for proton (antiproton) storage ring HESR, which cover whole machines working energy region.

The NUSTAR project at FAIR

NASA Astrophysics Data System (ADS)

Nilsson, Thomas; the NUSTAR Collaboration

2015-11-01

The FAIR facility, under construction at the GSI site in Darmstadt, will be addressing a wealth of outstanding questions within the realm of subatomic, atomic, plasma, bio-physics and applications through a combination of novel accelerators, storage rings and innovative experimental set-ups. One of the key installations is the fragment separator Super-FRS that will be able to deliver an unprecedented range of radioactive ion beams in the energy range of 0-1.5 GeV u-1. These beams will be distributed to three branches, each with its unique domain with respect to beam energies and properties. The high-energy branch will permit reactions with radioactive beams at relativistic energies, whereas the low-energy branch will supply decelerated beams for high-resolution spectroscopy, traps and laser spectroscopy. Finally, the ring branch will uniquely permit stored and cooled exotic beams for a range of methods only possible in a storage ring. Thus, by developing experimental set-ups tailored for these beams, there are several complementary possibilities to gain information on key nuclei and reaction, to further our understanding on contemporary questions within nuclear structure and nuclear astrophysics. This ambitious programme is to be exploited within the nuclear structure, astrophysics and reactions collaboration.

An Orbit And Dispersion Correction Scheme for the PEP II

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cai, Y.; Donald, M.; Shoaee, H.

2011-09-01

To achieve optimum luminosity in a storage ring it is vital to control the residual vertical dispersion. In the original PEP storage ring, a scheme to control the residual dispersion function was implemented using the ring orbit as the controlling element. The 'best' orbit not necessarily giving the lowest vertical dispersion. A similar scheme has been implemented in both the on-line control code and in the simulation code LEGO. The method involves finding the response matrices (sensitivity of orbit/dispersion at each Beam-Position-Monitor (BPM) to each orbit corrector) and solving in a least squares sense for minimum orbit, dispersion function ormore » both. The optimum solution is usually a subset of the full least squares solution. A scheme of simultaneously correcting the orbits and dispersion has been implemented in the simulation code and on-line control system for PEP-II. The scheme is based on the eigenvector decomposition method. An important ingredient of the scheme is to choose the optimum eigenvectors that minimize the orbit, dispersion and corrector strength. Simulations indicate this to be a very effective way to control the vertical residual dispersion.« less

Kinoform optics applied to X-ray photon correlation spectroscopy.

PubMed

Sandy, A R; Narayanan, S; Sprung, M; Su, J-D; Evans-Lutterodt, K; Isakovic, A F; Stein, A

2010-05-01

Moderate-demagnification higher-order silicon kinoform focusing lenses have been fabricated to facilitate small-angle X-ray photon correlation spectroscopy (XPCS) experiments. The geometric properties of such lenses, their focusing performance and their applicability for XPCS measurements are described. It is concluded that one-dimensional vertical X-ray focusing via silicon kinoform lenses significantly increases the usable coherent flux from third-generation storage-ring light sources for small-angle XPCS experiments.

Report of the New Rings Study Group

DOE Office of Scientific and Technical Information (OSTI.GOV)

Holmes, S.D.; Dugan, G.; Marriner, J.

1987-10-19

We have taken the approach here of trying to understand both the feasibility and practicality of varied options for new rings at Fermilab, rather than trying to produce a single detailed design. In other words, this document is not a design report and should not be construed as such. Our perception of the potential needs for new rings (in order of priority) is as follows: Antiproton Storage and/or Recovery: A facility for storing up to 4 x 10/sup 12/ antiprotons is needed. Recovery of antiprotons from the collider becomes a viable option if the luminosity is indeed dominated by emittancemore » dilution rather than beam loss. New or Post-Booster: The goal here would be to inject into the existing Main Ring above transition. Improved performance of the Main Ring would be anticipated. New Main Ring: Advantages would include better emittance preservation, a faster cycle time for antiproton production, and the removal of interference/backgrounds at the B0 and D0 detectors. We discuss in this paper various scenarios based on one or more combinations of the above possibilities. 14 figs., 10 tabs.« less

Long-range Electrostatic Complementarity Governs Substrate Recognition by Human Chymotrypsin C, a Key Regulator of Digestive Enzyme Activation*

PubMed Central

Batra, Jyotica; Szabó, András; Caulfield, Thomas R.; Soares, Alexei S.; Sahin-Tóth, Miklós; Radisky, Evette S.

2013-01-01

Human chymotrypsin C (CTRC) is a pancreatic serine protease that regulates activation and degradation of trypsinogens and procarboxypeptidases by targeting specific cleavage sites within their zymogen precursors. In cleaving these regulatory sites, which are characterized by multiple flanking acidic residues, CTRC shows substrate specificity that is distinct from that of other isoforms of chymotrypsin and elastase. Here, we report the first crystal structure of active CTRC, determined at 1.9-Å resolution, revealing the structural basis for binding specificity. The structure shows human CTRC bound to the small protein protease inhibitor eglin c, which binds in a substrate-like manner filling the S6-S5′ subsites of the substrate binding cleft. Significant binding affinity derives from burial of preferred hydrophobic residues at the P1, P4, and P2′ positions of CTRC, although acidic P2′ residues can also be accommodated by formation of an interfacial salt bridge. Acidic residues may also be specifically accommodated in the P6 position. The most unique structural feature of CTRC is a ring of intense positive electrostatic surface potential surrounding the primarily hydrophobic substrate binding site. Our results indicate that long-range electrostatic attraction toward substrates of concentrated negative charge governs substrate discrimination, which explains CTRC selectivity in regulating active digestive enzyme levels. PMID:23430245

High voltage pulse conditioning

DOEpatents

Springfield, Ray M.; Wheat, Jr., Robert M.

1990-01-01

Apparatus for conditioning high voltage pulses from particle accelerators in order to shorten the rise times of the pulses. Flashover switches in the cathode stalk of the transmission line hold off conduction for a determinable period of time, reflecting the early portion of the pulses. Diodes upstream of the switches divert energy into the magnetic and electrostatic storage of the capacitance and inductance inherent to the transmission line until the switches close.

Vibrational Stark effect spectroscopy reveals complementary electrostatic fields created by protein-protein binding at the interface of Ras and Ral.

PubMed

Walker, David M; Hayes, Ellen C; Webb, Lauren J

2013-08-07

Electrostatic fields at the interface of the GTPase H-Ras (Ras) docked with the Ras binding domain of the protein Ral guanine nucleoside dissociation stimulator (Ral) were measured with vibrational Stark effect (VSE) spectroscopy. Nine residues on the surface of Ras that participate in the protein-protein interface were systematically mutated to cysteine and subsequently converted to cyanocysteine in order to introduce a nitrile VSE probe into the protein-protein interface. The absorption energy of the nitrile was measured both on the surface of Ras in its monomeric state, then after incubation with the Ras binding domain of Ral to form the docked complex. Boltzmann-weighted structural snapshots of the nitrile-labeled Ras protein were generated both in monomeric and docked configurations from molecular dynamics simulations using enhanced sampling of the cyanocysteine side chain's χ2 dihedral angle. These snapshots were used to determine that on average, most of the nitrile probes were aligned along the Ras surface, parallel to the Ras-Ral interface. The average solvent-accessible surface areas (SASA) of the cyanocysteine side chain were found to be <60 Å(2) for all measured residues, and was not significantly different whether the nitrile was on the surface of the Ras monomer or immersed in the docked complex. Changes in the absorption energy of the nitrile probe at nine positions along the Ras-Ral interface were compared to results of a previous study examining this interface with Ral-based probes, and found a pattern of low electrostatic field in the core of the interface surrounded by a ring of high electrostatic field around the perimeter of the interface. These data are used to rationalize several puzzling features of the Ras-Ral interface.

Middle School Science Notes.

ERIC Educational Resources Information Center

School Science Review, 1980

1980-01-01

Outlines a variety of laboratory procedures, discussions, and demonstrations including Brownian motion, a synchronous motor, jet engine, atmospheric pressure vortex ring machines, solid chemical dispensing, testing household detergents, wallchart storage, pollution by industrial chemicals, an optical illusion, and buoyancy. (GS)

Spin Filtering in Storage Rings

NASA Astrophysics Data System (ADS)

Nikolaev, N. N.; Pavlov, F. F.

The spin filtering in storage rings is based on a multiple passage of a stored beam through a polarized internal gas target. Apart from the polarization by the spin-dependent transmission, a unique geometrical feature of interaction with the target in such a filtering process, pointed out by H.O. Meyer,1 is a scattering of stored particles within the beam. A rotation of the spin in the scattering process affects the polarization buildup. We derive here a quantum-mechanical evolution equation for the spin-density matrix of a stored beam which incorporates the scattering within the beam. We show how the interplay of the transmission and scattering within the beam changes from polarized electrons to polarized protons in the atomic target. After discussions of the FILTEX results on the filtering of stored protons,2 we comment on the strategy of spin filtering of antiprotons for the PAX experiment at GSI FAIR.3.

Direct Observation of Spatiotemporal Dynamics of Short Electron Bunches in Storage Rings

NASA Astrophysics Data System (ADS)

Evain, C.; Roussel, E.; Le Parquier, M.; Szwaj, C.; Tordeux, M.-A.; Brubach, J.-B.; Manceron, L.; Roy, P.; Bielawski, S.

2017-02-01

In recent synchrotron radiation facilities, the use of short (picosecond) electron bunches is a powerful method for producing giant pulses of terahertz coherent synchrotron radiation. Here we report on the first direct observation of these pulse shapes with a few picoseconds resolution, and of their dynamics over a long time. We thus confirm in a very direct way the theories predicting an interplay between two physical processes. Below a critical bunch charge, we observe a train of identical THz pulses (a broadband Terahertz comb) stemming from the shortness of the electron bunches. Above this threshold, a large part of the emission is dominated by drifting structures, which appear through spontaneous self-organization. These challenging single-shot THz recordings are made possible by using a recently developed photonic time stretch detector with a high sensitivity. The experiment has been realized at the SOLEIL storage ring.

The trigger system for the external target experiment in the HIRFL cooling storage ring

NASA Astrophysics Data System (ADS)

Li, Min; Zhao, Lei; Liu, Jin-Xin; Lu, Yi-Ming; Liu, Shu-Bin; An, Qi

2016-08-01

A trigger system was designed for the external target experiment in the Cooling Storage Ring (CSR) of the Heavy Ion Research Facility in Lanzhou (HIRFL). Considering that different detectors are scattered over a large area, the trigger system is designed based on a master-slave structure and fiber-based serial data transmission technique. The trigger logic is organized in hierarchies, and flexible reconfiguration of the trigger function is achieved based on command register access or overall field-programmable gate array (FPGA) logic on-line reconfiguration controlled by remote computers. We also conducted tests to confirm the function of the trigger electronics, and the results indicate that this trigger system works well. Supported by the National Natural Science Foundation of China (11079003), the Knowledge Innovation Program of the Chinese Academy of Sciences (KJCX2-YW-N27), and the CAS Center for Excellence in Particle Physics (CCEPP).

Dissociative recombination measurements of NH{sup +} using an ion storage ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Novotný, O.; Savin, D. W.; Berg, M.

We have investigated dissociative recombination (DR) of NH{sup +} with electrons using a merged beams configuration at the TSR heavy-ion storage ring located at the Max Planck Institute for Nuclear Physics in Heidelberg, Germany. We present our measured absolute merged-beams recombination rate coefficient for collision energies from 0 to 12 eV. From these data, we have extracted a cross section, which we have transformed to a plasma rate coefficient for the collisional plasma temperature range from T {sub pl} = 10 to 18,000 K. We show that the NH{sup +} DR rate coefficient data in current astrochemical models are underestimatedmore » by up to a factor of approximately nine. Our new data will result in predicted NH{sup +} abundances lower than those calculated by present models. This is in agreement with the sensitivity limits of all observations attempting to detect NH{sup +} in interstellar clouds.« less

Linear transformer driver for pulse generation

DOEpatents

Kim, Alexander A; Mazarakis, Michael G; Sinebryukhov, Vadim A; Volkov, Sergey N; Kondratiev, Sergey S; Alexeenko, Vitaly M; Bayol, Frederic; Demol, Gauthier; Stygar, William A

2015-04-07

A linear transformer driver includes at least one ferrite ring positioned to accept a load. The linear transformer driver also includes a first power delivery module that includes a first charge storage devices and a first switch. The first power delivery module sends a first energy in the form of a first pulse to the load. The linear transformer driver also includes a second power delivery module including a second charge storage device and a second switch. The second power delivery module sends a second energy in the form of a second pulse to the load. The second pulse has a frequency that is approximately three times the frequency of the first pulse. The at least one ferrite ring is positioned to force the first pulse and the second pulse to the load by temporarily isolating the first pulse and the second pulse from an electrical ground.

Note: Comparison of grazing incidence small angle x-ray scattering of a titania sponge structure at the beamlines BW4 (DORIS III) and P03 (PETRA III)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rawolle, M.; Koerstgens, V.; Ruderer, M. A.

2012-10-15

Grazing incidence small angle x-ray scattering (GISAXS) is a powerful technique for morphology investigation of nanostructured thin films. GISAXS measurements at the newly installed P03 beamline at the storage ring PETRA III in Hamburg, Germany, are compared to the GISAXS data from the beamline BW4 at the storage ring DORIS III, which had been used extensively for GISAXS investigations in the past. As an example, a titania thin film sponge structure is investigated. Compared to BW4, at beamline P03 the resolution of larger structures is slightly improved and a higher incident flux leads to a factor of 750 in scatteredmore » intensity. Therefore, the acquisition time in GISAXS geometry is reduced significantly at beamline P03.« less

A New Hard X-ray Wiggler for DORIS III

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tischer, M.; Gumprecht, L.; Pflueger, J.

2007-01-19

A 4 m long hard X-ray wiggler has been built and installed in the DORIS III storage ring at DESY. The device replaces an old wiggler especially designed for angiography studies. Future use of this beamline at the HARWI straight section has been dedicated to hard X-ray scattering and diffraction experiments for material science and geological investigations. The required energy range is from 30 keV to about 200 keV with emphasis on the {approx}100 keV spectral range. The magnet configuration corresponds to a hybrid structure with additional side magnets to achieve a 2 T peak field for the specified periodmore » length of 110 mm. The wiggler position in the storage ring has been moved 8 m upstream into the next cell which allowed for reduction of the minimum magnetic wiggler gap to 14 mm.« less

Fluorescence dynamics of biological systems using synchrotron radiation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gratton, E.; Mantulin, W.W.; Weber, G.

1996-09-01

A beamline for time-resolved fluorescence spectroscopy of biological systems is under construction at the Synchrotron Radiation Center. The fluorometer, operating in the frequency domain, will take advantage of the time structure of the synchrotron radiation light pulses to determine fluorescence lifetimes. Using frequency-domain techniques, the instrument can achieve an ultimate time resolution on the order of picoseconds. Preliminary experiments have shown that reducing the intensity of one of the fifteen electron bunches in the storage ring allows measurement of harmonic frequencies equivalent to the single-bunch mode. This mode of operation of the synchrotron significantly extends the range of lifetimes thatmore » can be measured. The wavelength range (encompassing the visible and ultraviolet), the range of measurable lifetimes, and the stability and reproducibility of the storage ring pulses should make this beamline a versatile tool for the investigation of the complex fluorescence decay of biological systems. {copyright} {ital 1996 American Institute of Physics.}« less

HIGH-ENERGY X-RAY PINHOLE CAMERA FOR HIGH-RESOLUTION ELECTRON BEAM SIZE MEASUREMENTS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yang, B.; Morgan, J.; Lee, S.H.

The Advanced Photon Source (APS) is developing a multi-bend achromat (MBA) lattice based storage ring as the next major upgrade, featuring a 20-fold reduction in emittance. Combining the reduction of beta functions, the electron beam sizes at bend magnet sources may be reduced to reach 5 – 10 µm for 10% vertical coupling. The x-ray pinhole camera currently used for beam size monitoring will not be adequate for the new task. By increasing the operating photon energy to 120 – 200 keV, the pinhole camera’s resolution is expected to reach below 4 µm. The peak height of the pinhole imagemore » will be used to monitor relative changes of the beam sizes and enable the feedback control of the emittance. We present the simulation and the design of a beam size monitor for the APS storage ring.« less

Storage ring two-color free-electron laser

DOE PAGES

Yan, J.; Hao, H.; Li, J. Y.; ...

2016-07-05

We report a systematic experimental study of a storage ring two-color free-electron laser (FEL) operating simultaneously in the infrared (IR) and ultraviolet (UV) wavelength regions. The two-color FEL lasing has been realized using a pair of dual-band high-reflectivity FEL mirrors with two different undulator configurations. We have demonstrated independent wavelength tuning in a wide range for each lasing color, as well as harmonically locked wavelength tuning when the UV lasing occurs at the second harmonic of the IR lasing. Precise power control of two-color lasing with good power stability has also been achieved. In addition, the impact of the degradationmore » of FEL mirrors on the two-color FEL operation is reported. Moreover, we have investigated the temporal structures of the two-color FEL beams, showing simultaneous two-color micropulses with their intensity modulations displayed as FEL macropulses.« less

Introduction to the magnet and vacuum systems of an electron storage ring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weng, W.T.

An accelerator or storage ring complex is a concerted interplay of various functional systems. For the convenience of discussion we can divide it into the following systems: injector, magnet, RF, vacuum, instrumentation and control. In addition, the conventional construction of the building and radiation safety consideration are also needed and finally the beam lines, detector, data acquisition and analysis set-ups for research programs. Dr. L. Teng has given a comprehensive review of the whole complex and the operation of such a facility. I concentrate on the description of magnet and vacuum systems. Only the general function of each system andmore » the basic design concepts will be introduced, no detailed engineering practice will be given which will be best done after a machine design is produced. For further understanding and references a table of bibliography is provided at the end of the paper.« less

Coulomb clusters in RETRAP

NASA Astrophysics Data System (ADS)

Steiger, J.; Beck, B. R.; Gruber, L.; Church, D. A.; Holder, J. P.; Schneider, D.

1999-01-01

Storage rings and Penning traps are being used to study ions in their highest charge states. Both devices must have the capability for ion cooling in order to perform high precision measurements such as mass spectrometry and laser spectroscopy. This is accomplished in storage rings in a merged beam arrangement where a cold electron beam moves at the speed of the ions. In RETRAP, a Penning trap located at Lawrence Livermore National Laboratory, a sympathetic laser/ion cooling scheme has been implemented. In a first step, singly charged beryllium ions are cooled electronically by a tuned circuit and optically by a laser. Then hot, highly charged ions are merged into the cold Be plasma. By collisions, their kinetic energy is reduced to the temperature of the Be plasma. First experiments indicate that the highly charged ions form a strongly coupled plasma with a Coulomb coupling parameter exceeding 1000.

Field Quality from Tolerance Stack-up In R&D Quadrupoles for the Advanced Photon Source Upgrade

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, J.; Jaski, M.; Dejus, R.

2016-10-01

The Advanced Photon Source (APS) at Argonne National Laboratory (ANL) is considering upgrading the current double-bend, 7-GeV, 3rd generation storage ring to a 6-GeV, 4th generation storage ring with a Multibend Achromat (MBA) lattice. In this study, a novel method is proposed to determine fabrication and assembly tolerances through a combination of magnetic and mechanical tolerance analyses. Mechanical tolerance stackup analyses using Teamcenter Variation Analysis are carried out to determine the part and assembly level fabrication tolerances. Finite element analyses using OPERA are conducted to estimate the effect of fabrication and assembly errors on the magnetic field of a quadrupolemore » magnet and to determine the allowable tolerances to achieve the desired magnetic performance. Finally, results of measurements in R&D quadrupole prototypes are compared with the analysis results.« less

Impedance computations and beam-based measurements: A problem of discrepancy

NASA Astrophysics Data System (ADS)

Smaluk, Victor

2018-04-01

High intensity of particle beams is crucial for high-performance operation of modern electron-positron storage rings, both colliders and light sources. The beam intensity is limited by the interaction of the beam with self-induced electromagnetic fields (wake fields) proportional to the vacuum chamber impedance. For a new accelerator project, the total broadband impedance is computed by element-wise wake-field simulations using computer codes. For a machine in operation, the impedance can be measured experimentally using beam-based techniques. In this article, a comparative analysis of impedance computations and beam-based measurements is presented for 15 electron-positron storage rings. The measured data and the predictions based on the computed impedance budgets show a significant discrepancy. Three possible reasons for the discrepancy are discussed: interference of the wake fields excited by a beam in adjacent components of the vacuum chamber, effect of computation mesh size, and effect of insufficient bandwidth of the computed impedance.

New beam-position monitor system for upgraded Photon Factory storage ring.

PubMed

Haga, K; Honda, T; Tadano, M; Obina, T; Kasuga, T

1998-05-01

Accompanying the brilliance-upgrading project at the Photon Factory storage ring, the beam-position monitor (BPM) system has been renovated. The new system was designed to enable precise and fast measurements to correct the closed-orbit distortion (COD), as well as to feed back the orbit position during user runs. There are 42 BPMs newly installed, amounting to a total of 65 BPMs. All of the BPMs are calibrated on the test bench using a coaxially strung metallic wire. The measured electrical offsets are typically 200 micro m in both directions, which is 1/2-1/3 of those of the old-type BPMs. In the signal-processing system, PIN diode switches are employed in order to improve reliability. In the fastest mode, this system is capable of measuring COD within about 10 ms; this fast acquisition will allow fast suppression of the beam movement for frequencies up to 50 Hz using a global feedback system.

Graphene oxide as an optimal candidate material for methane storage.

PubMed

Chouhan, Rajiv K; Ulman, Kanchan; Narasimhan, Shobhana

2015-07-28

Methane, the primary constituent of natural gas, binds too weakly to nanostructured carbons to meet the targets set for on-board vehicular storage to be viable. We show, using density functional theory calculations, that replacing graphene by graphene oxide increases the adsorption energy of methane by 50%. This enhancement is sufficient to achieve the optimal binding strength. In order to gain insight into the sources of this increased binding, that could also be used to formulate design principles for novel storage materials, we consider a sequence of model systems that progressively take us from graphene to graphene oxide. A careful analysis of the various contributions to the weak binding between the methane molecule and the graphene oxide shows that the enhancement has important contributions from London dispersion interactions as well as electrostatic interactions such as Debye interactions, aided by geometric curvature induced primarily by the presence of epoxy groups.

Interaction of Hydrogen with MOF-5.

PubMed

Bordiga, Silvia; Vitillo, Jenny G; Ricchiardi, Gabriele; Regli, Laura; Cocina, Donato; Zecchina, Adriano; Arstad, Bjørnar; Bjørgen, Morten; Hafizovic, Jasmina; Lillerud, Karl Petter

2005-10-06

Hydrogen storage is among the most demanding challenges in the hydrogen-based energy cycle. One proposed strategy for hydrogen storage is based on physisorption on high surface area solids such as metal-organic frameworks (MOFs). Within this class of materials, MOF-5 has been the first structure studied for hydrogen storage. The IR spectroscopy of adsorbed H2 performed at 15 K and ab initio calculations show that the adsorptive properties of this material are mainly due to dispersive interactions with the internal wall structure and to weak electrostatic forces associated with O13Zn4 clusters. Calculated and measured binding enthalpies are between 2.26 and 3.5 kJ/mol, in agreement with the H2 rotational barriers reported in the literature. A minority of binding sites with higher adsorption enthalpy (7.4 kJ/mol) is also observed. These species are probably associated with OH groups on the external surfaces present as termini of the microcrystals.

The MAX IV storage ring project

PubMed Central

Tavares, Pedro F.; Leemann, Simon C.; Sjöström, Magnus; Andersson, Åke

2014-01-01

The MAX IV facility, currently under construction in Lund, Sweden, features two electron storage rings operated at 3 GeV and 1.5 GeV and optimized for the hard X-ray and soft X-ray/VUV spectral ranges, respectively. A 3 GeV linear accelerator serves as a full-energy injector into both rings as well as a driver for a short-pulse facility, in which undulators produce X-ray pulses as short as 100 fs. The 3 GeV ring employs a multibend achromat (MBA) lattice to achieve, in a relatively short circumference of 528 m, a bare lattice emittance of 0.33 nm rad, which reduces to 0.2 nm rad as insertion devices are added. The engineering implementation of the MBA lattice raises several technological problems. The large number of strong magnets per achromat calls for a compact design featuring small-gap combined-function magnets grouped into cells and sharing a common iron yoke. The small apertures lead to a low-conductance vacuum chamber design that relies on the chamber itself as a distributed copper absorber for the heat deposited by synchrotron radiation, while non-evaporable getter (NEG) coating provides for reduced photodesorption yields and distributed pumping. Finally, a low main frequency (100 MHz) is chosen for the RF system yielding long bunches, which are further elongated by passively operated third-harmonic Landau cavities, thus alleviating collective effects, both coherent (e.g. resistive wall instabilities) and incoherent (intrabeam scattering). In this paper, we focus on the MAX IV 3 GeV ring and present the lattice design as well as the engineering solutions to the challenges inherent to such a design. As the first realisation of a light source based on the MBA concept, the MAX IV 3 GeV ring offers an opportunity for validation of concepts that are likely to be essential ingredients of future diffraction-limited light sources. PMID:25177978

Groundwater storage inferred from earthquake activities around East Asia and West Pacific Ocean

NASA Astrophysics Data System (ADS)

Shih, David Ching-Fang

2017-01-01

Groundwater is a necessary and indispensable resource in the gradual depletion of the amount in the world. Groundwater storage is an important indicator to evaluate the capability of volume of water can be released from the aquifer. This research highlights a new assessment to infer the storage of aquifer using earthquakes activated around East Asia and the ring of fire at West Pacific Ocean. Ten significant seismic events are used to evaluate the groundwater storage at an observation station. By analyzing the spectra of groundwater level and seismogram, it is evident that the period varied in 7-25 s of Rayleigh waves significantly dominate propagation from the epicenter of earthquakes to the observation station. The storage coefficient is then shown in the order of 10-4-10-3. The major innovation of this study suggests that to concretely deduce the groundwater storage by earthquake activity has become feasible.

Diagnostics of the ITER neutral beam test facility.

PubMed

Pasqualotto, R; Serianni, G; Sonato, P; Agostini, M; Brombin, M; Croci, G; Dalla Palma, M; De Muri, M; Gazza, E; Gorini, G; Pomaro, N; Rizzolo, A; Spolaore, M; Zaniol, B

2012-02-01

The ITER heating neutral beam (HNB) injector, based on negative ions accelerated at 1 MV, will be tested and optimized in the SPIDER source and MITICA full injector prototypes, using a set of diagnostics not available on the ITER HNB. The RF source, where the H(-)∕D(-) production is enhanced by cesium evaporation, will be monitored with thermocouples, electrostatic probes, optical emission spectroscopy, cavity ring down, and laser absorption spectroscopy. The beam is analyzed by cooling water calorimetry, a short pulse instrumented calorimeter, beam emission spectroscopy, visible tomography, and neutron imaging. Design of the diagnostic systems is presented.

Face-to-face stacks of trinuclear gold(I) trihalides with benzene, hexafluorobenzene, and borazine: impact of aromaticity on stacking interactions.

PubMed

Tsipis, Athanassios C; Stalikas, Alexandros V

2013-01-18

The interplay of electrostatics, charge transfer, and dispersion forces contributing to the interaction energies in 1:1, 1:2, and 2:1 binary stacks of the c-Au(3)(μ(2)-X)(3) (X = F, Cl, Br, I) clusters with benzene, hexafluorobenzene, or borazine were investigated by employing a multitude of electronic structure computational techniques. The molecular and electronic structures, stabilities, bonding features, and magnetotropicity of [c-Au(3)(μ(2)-X)(3)](n)(L)(m) (X = halide; L = C(6)H(6), C(6)F(6), B(3)N(3)H(6); n, m ≤ 2) columnar binary stacks have been investigated by DFT calculations employing the M05-2X functional. The novel binary stacks could be considered as the building blocks of extended columnar supramolecular assemblies formulated as {[c-Au(3)(μ(2)-X)(3)](C(6)H(6))}(∞), {[c-Au(3)(μ(2)-X)(3)](2)(C(6)F(6))}(∞), and {[c-Au(3)(μ(2)-X)(3)](B(3)N(3)H(6))(2)}(∞). In all binary stacks, with a few exceptions, the plane of the alternating c-Au(3)(μ(2)-X)(3) and L (C(6)H(6), C(6)F(6), B(3)N(3)H(6)) stacking participants adopt an almost parallel face-to-face (pff) orientation. The observed trends in the intermolecular distances R in the [c-Au(3)(μ(2)-X)(3)](n)(L)(m) (X = halide; L = C(6)H(6), C(6)F(6), B(3)N(3)H(6); n, m ≤ 2) columnar binary stacks are explained by the diverse intermolecular interactions characterizing the stacks, since the three ligands L and the c-Au(3)(μ(2)-X)(3) cyclic trinuclear clusters (CTCs) exhibit diverse physical properties being important determinants of the intermolecular interactions (consisting of covalent, electrostatic, and dispersion forces). The properties considered are the zz tensor components of quadrupole moment, Q(zz), polarizability, α(zz), nucleus-independent chemical shift, NICS(zz)(1), along with the molecular electrostatic potential, MEP(0), and surface area (S). Energy decomposition analysis (EDA) at the revPBE-D3/TZ2P level revealed that the dominant term in the stacking interactions arises mainly from dispersion and electrostatic forces, while the contribution of covalent interactions are predicted to be small. On the other hand, charge decomposition analysis (CDA) illustrated very small charge transfer from the L stacking participants toward the c-Au(3)(μ(2)-X)(3) clusters. Excellent linear correlations of the interaction energy, ΔE(int), and its components (ΔE(disp), ΔE(elstat), ΔE(orb), and ΔE(Pauli)) with calculated physical properties related to dispersion, covalent, and electrostatic forces have been established. The most important finding is the excellent linear relationship between ΔE(int) and the NICS(zz)(1) magnetic criterion of aromaticity, indicating that ΔE(int) is also affected by the coupling of the induced magnetic fields of the interacting stacking participants. The magnetotropicity of the binary stacks evaluated by the NICS(zz)-scan curves indicated an enhancement of the diatropicity in the space between the interacting inorganic and organic rings, probably due to the superposition of the diamagnetic ring currents of the interacting ring systems. The energy splitting in dimer (ESID) model was employed to estimate the charge transport of electrons and holes between the ligands L and the [c-Au(3)(μ(2)-X)(3)] clusters in [c-Au(3)(μ(2)-X)(3)](L) 1:1 binary stacks.

Magnetic bearing momentum wheels with magnetic gimballing capability for 3-axis active attitude control and energy storage

NASA Technical Reports Server (NTRS)

Sindlinger, R. S.

1977-01-01

A 3-axis active attitude control system with only one rotating part was developed using a momentum wheel with magnetic gimballing capability as a torque actuator for all three body axes. A brief description of magnetic bearing technology is given. It is concluded that based on this technology an integrated energy storage/attitude control system with one air of counterrotating rings could reduce the complexity and weight of conventional systems.

Suppressing the Coffee-Ring Effect in Semitransparent MnO2 Film for a High-Performance Solar-Powered Energy Storage Window.

PubMed

Jin, Huanyu; Qian, Jiasheng; Zhou, Limin; Yuan, Jikang; Huang, Haitao; Wang, Yu; Tang, Wing Man; Chan, Helen Lai Wa

2016-04-13

We introduce a simple and effective method to deposit a highly uniform and semitransparent MnO2 film without coffee-ring effect (CRE) by adding ethanol into MnO2 ink for transparent capacitive energy storage devices. By carefully controlling the amount of ethanol added in the MnO2 droplet, we could significantly reduce the CRE and thus improve the film uniformity. The electrochemical properties of supercapacitor (SC) devices using semitransparent MnO2 film electrodes with or without CRE were measured and compared. The SC device without CRE shows a superior capacitance, high rate capability, and lower contact resistance. The CRE-free device could achieve a considerable volumetric capacitance of 112.2 F cm(-3), resulting in a high volumetric energy density and power density of 10 mWh cm(-3) and 8.6 W cm(-3), respectively. For practical consideration, both flexible SC and large-area rigid SC devices were fabricated to demonstrate their potential for flexible transparent electronic application and capacitive energy-storage window application. Moreover, a solar-powered energy storage window which consists of a commercial solar cell and our studied semitransparent MnO2-film-based SCs was assembled. These SCs could be charged by the solar cell and light up a light emitting diode (LED), demonstrating their potential for self-powered systems and energy-efficient buildings.

National Synchrotron Light Source II

ScienceCinema

Steve Dierker

2017-12-09

The National Synchrotron Light Source II (NSLS-II) at the U.S. Department of Energy's Brookhaven National Laboratory is a proposed new state-of-the-art medium energy storage ring designed to deliver world-leading brightness and flux with top-off operation

Portable convertible blast effects shield

DOEpatents

Pastrnak, John W [Livermore, CA; Hollaway, Rocky [Modesto, CA; Henning, Carl D [Livermore, CA; Deteresa, Steve [Livermore, CA; Grundler, Walter [Hayward, CA; Hagler, Lisle B [Berkeley, CA; Kokko, Edwin [Dublin, CA; Switzer, Vernon A [Livermore, CA

2011-03-15

A rapidly deployable portable convertible blast effects shield/ballistic shield includes a set two or more frusto-conically-tapered telescoping rings operably connected to each other to convert between a telescopically-collapsed configuration for storage and transport, and a telescopically-extended upright configuration forming an expanded inner volume. In a first embodiment, the upright configuration provides blast effects shielding, such as against blast pressures, shrapnel, and/or fire balls. And in a second embodiment, the upright configuration provides ballistic shielding, such as against incoming weapons fire, shrapnel, etc. Each ring has a high-strength material construction, such as a composite fiber and matrix material, capable of substantially inhibiting blast effects and impinging projectiles from passing through the shield. And the set of rings are releasably securable to each other in the telescopically-extended upright configuration by the friction fit of adjacent pairs of frusto-conically-tapered rings to each other.

Model-independent analysis of the Fermilab Tevatron turn-by-turn beam position monitor measurements

NASA Astrophysics Data System (ADS)

Petrenko, A. V.; Valishev, A. A.; Lebedev, V. A.

2011-09-01

Coherent transverse beam oscillations in the Tevatron were analyzed with the model-independent analysis (MIA) technique. This allowed one to obtain the model-independent values of coupled betatron amplitudes, phase advances, and dispersion function around the ring from a single dipole kick measurement. In order to solve the MIA mode mixing problem which limits the accuracy of determination of the optical functions, we have developed a new technique of rotational MIA mode untangling. The basic idea is to treat each beam position monitor (BPM) as two BPMs separated in a ring by exactly one turn. This leads to a simple criterion of MIA mode separation: the betatron phase advance between any BPM and its counterpart shifted by one turn should be equal to the betatron tune and therefore should not depend on the BPM position in the ring. Furthermore, we describe a MIA-based technique to locate vibrating magnets in a storage ring.

Investigation of the heavy-ion mode in the FAIR High Energy Storage Ring

NASA Astrophysics Data System (ADS)

Kovalenko, O.; Dolinskii, O.; Litvinov, Yu A.; Maier, R.; Prasuhn, D.; Stöhlker, T.

2015-11-01

High energy storage ring (HESR) as a part of the future accelerator facility FAIR (Facility for Antiproton and Ion Research) will serve for a variety of internal target experiments with high-energy stored heavy ions (SPARC collaboration). Bare uranium is planned to be used as a primary beam. Since a storage time in some cases may be significant—up to half an hour—it is important to examine the high-order effects in the long-term beam dynamics. A new ion optics specifically for the heavy ion mode of the HESR is developed and is discussed in this paper. The subjects of an optics design, tune working point and a dynamic aperture are addressed. For that purpose nonlinear beam dynamics simulations are carried out. Also a flexibility of the HESR ion optical lattice is verified with regard to various experimental setups. Specifically, due to charge exchange reactions in the internal target, secondary beams, such as hydrogen-like and helium-like uranium ions, will be produced. Thus the possibility of separation of these secondary ions and the primary {{{U}}}92+ beam is presented with different internal target locations.

Strong CH/O interactions between polycyclic aromatic hydrocarbons and water: Influence of aromatic system size.

PubMed

Veljković, Dušan Ž

2018-03-01

Energies of CH/O interactions between water molecule and polycyclic aromatic hydrocarbons with a different number of aromatic rings were calculated using ab initio calculations at MP2/cc-PVTZ level. Results show that an additional aromatic ring in structure of polycyclic aromatic hydrocarbons significantly strengthens CH/O interactions. Calculated interaction energies in optimized structures of the most stable tetracene/water complex is -2.27 kcal/mol, anthracene/water is -2.13 kcal/mol and naphthalene/water is -1.97 kcal/mol. These interactions are stronger than CH/O contacts in benzene/water complex (-1.44 kcal/mol) while CH/O contacts in tetracene/water complex are even stronger than CH/O contacts in pyridine/water complexes (-2.21 kcal/mol). Electrostatic potential maps for different polycyclic aromatic hydrocarbons were calculated and used to explain trends in the energies of interactions. Copyright © 2017 Elsevier Inc. All rights reserved.

Structure of the Human FANCL RING-Ube2T Complex Reveals Determinants of Cognate E3-E2 Selection

PubMed Central

Hodson, Charlotte; Purkiss, Andrew; Miles, Jennifer Anne; Walden, Helen

2014-01-01

Summary The combination of an E2 ubiquitin-conjugating enzyme with an E3 ubiquitin-ligase is essential for ubiquitin modification of a substrate. Moreover, the pairing dictates both the substrate choice and the modification type. The molecular details of generic E3-E2 interactions are well established. Nevertheless, the determinants of selective, specific E3-E2 recognition are not understood. There are ∼40 E2s and ∼600 E3s giving rise to a possible ∼24,000 E3-E2 pairs. Using the Fanconi Anemia pathway exclusive E3-E2 pair, FANCL-Ube2T, we report the atomic structure of the FANCL RING-Ube2T complex, revealing a specific and extensive network of additional electrostatic and hydrophobic interactions. Furthermore, we show that these specific interactions are required for selection of Ube2T over other E2s by FANCL. PMID:24389026

Novel beta-cyclodextrin derivative functionalized polymethacrylate-based monolithic columns for enantioselective separation of ibuprofen and naproxen enantiomers in capillary electrochromatography.

PubMed

Tian, Yun; Zhong, Cheng; Fu, Enqin; Zeng, Zhaorui

2009-02-06

A novel enantioselective polymethacrylate-based monolithic column for capillary electrochromatography was prepared by ring-opening reaction of epoxy groups from poly(glycidyl methacrylate-co-ethylene dimethacrylate) monolith with a novel beta-cyclodextrin derivative bearing 4-dimethylamino-1,8-naphthalimide functionalities. Conditions for the ring-opening reaction with respect to different reaction parameters were thoroughly optimized to obtain high electroosmotic flow, separation efficiency and enantioselectivity for the analytes. The nonaqueous mobile phase composition regarding acetonitrile-methanol ratio and the concentration of electrolyte were examined to manipulate the hydrophobic inclusion and anion-exchange interaction between the analytes and chiral stationary phase. It was observed that in addition to beta-cyclodextrin cavity, the electrostatic interaction exhibited pronounced influence on the enantioseparation of acidic analytes. Acidic enantiomers (ibuprofen and naproxen) could be separated with separation factor (alpha) values up to 1.08 and a maximum separation efficiency of 86000 plates/m could be achieved.

Metering Wheel-Wire Track Wire Boom Deployment Mechanism

NASA Technical Reports Server (NTRS)

Granoff, Mark S.

2014-01-01

The NASA MMS Spin Plane Double Probe (SDP) Deployer utilizes a helical path, rotating Metering Wheel and a spring loaded Wire "Holding" Track to pay out a "fixed end" 57 meter x 1.5 mm diameter Wire Boom stored between concentric storage cylinders. Unlike rotating spool type storage devices, the storage cylinders remain stationary, and the boom wire is uncoiled along the length of the cylinder via the rotation of the Metering Wheel. This uncoiling action avoids the need for slip-ring contacts since the ends of the wire can remain stationary. Conventional fixed electrical connectors (Micro-D type) are used to terminate to operational electronics.

Electromagnetic Quasi-periodic Whistler-Mode Bursts during Ring Grazing Passes

NASA Astrophysics Data System (ADS)

Farrell, W. M.; Morooka, M. W.; Wahlund, J. E.; Kurth, W. S.; Hospodarsky, G.; MacDowall, R. J.; Mitchell, D. G.; Gurnett, D. A.; Krupp, N.; Roussos, E.; Kollmann, P.

2017-12-01

In the 2016-2017 time-frame, the Cassini spacecraft made a set of over 20 nearly identical Saturn orbital passes with closest approach at the outer edge of the F-ring. These passes are now called `Ring Grazing' orbits. During nearly every one of these orbits, quasi-periodic (QP) whistler-mode bursts were detected at mid-southern latitudes between -57o and -22o. During these ring grazing orbits, the spacecraft had an extended period of time where the trajectory 'hugged' the L 13 field line along its southern path when these bursts were detected. As such, we conclude that the 1 hr periodicity is not a spatial effect but a true temporal effect. In about 2/3 of the cases, there was wave activity observed above the local electron cyclotron frequency. We note that there have been previous reports of these QP whistler-mode burst in direct correlation with energetic auroral electron bursts, and we now also present the use of relativist electron cyclotron resonance theory to examine the wave-electron interactions. While in the past these waves have been considered a form of electrostatic auroral hiss, we suggest herein that the high energy of the electrons is more strongly coupled to the electromagnetic portion of the whistler-mode branch. In this presentation, we will provide more information on the wave character, and suggest the non-unique possibility that mode coupling is involved in creating emissions above the electron cyclotron frequency.

Computer-aided rational design of novel EBF analogues with an aromatic ring.

PubMed

Wang, Shanshan; Sun, Yufeng; Du, Shaoqing; Qin, Yaoguo; Duan, Hongxia; Yang, Xinling

2016-06-01

Odorant binding proteins (OBPs) are important in insect olfactory recognition. These proteins bind specifically to insect semiochemicals and induce their seeking, mating, and alarm behaviors. Molecular docking and molecular dynamics simulations were performed to provide computational insight into the interaction mode between AgamOBP7 and novel (E)-β-farnesene (EBF) analogues with an aromatic ring. The ligand-binding cavity in OBP7 was found to be mostly hydrophobic due to the presence of several nonpolar residues. The interactions between the EBF analogues and the hydrophobic residues in the binding cavity increased in strength as the distance between them decreased. The EBF analogues with an N-methyl formamide or ester linkage had higher docking scores than those with an amide linkage. Moreover, delocalized π-π and electrostatic interactions were found to contribute significantly to the binding between the ligand benzene ring and nearby protein residues. To design new compounds with higher activity, four EBF analogues D1-D4 with a benzene ring were synthesized and evaluated based on their docking scores and binding affinities. D2, which had an N-methyl formamide group linkage, exhibited stronger binding than D1, which had an amide linkage. D4 exhibited particularly strong binding due to multiple hydrophobic interactions with the protein. This study provides crucial foundations for designing novel EBF analogues based on the OBP structure. Graphical abstract The design strategy of new EBF analogues based on the OBP7 structure.

Mullite and Mullite Ceramics

DTIC Science & Technology

1994-01-01

possible. The here reported measurements were carried out with synchrotron radiation from the electron storage ring ELSA of the Bonn University. All...Physikalisches Institut der Universitdt Bonn , Bonn , Germany Measurements of X-ray absorption spectra near the absorption edge of a selected element (XANES

B factory plans at Cornell

NASA Astrophysics Data System (ADS)

Berkelman, Karl

1989-12-01

Recent upgrade project at the Cornell Electron Storage Ring is discussed. Modification was made to make B mesons factory design possible. The CLEO detector has been rebuilt with a new superconducting magnet and a high resolution electromagnetic calorimeter made of cesium iodide scintillators.(AIP)

Synthesis and fabrication of porous activated carbon/nano ZnO composite electrode for supercapacitor

NASA Astrophysics Data System (ADS)

P, Shabeeba; Thayyil, Mohammed Shahin; Pillai, M. P.

2017-05-01

Supercapacitors, also called as ultracapacitors, are electrochemical energy-storage devices that exploit the electrostatic interaction between high-surface-area nanoporous electrodes and electrolyte ions that combine properties of conventional batteries and conventional capacitors. A symmetrical ZnO-Activated Carbon (ZAC) electrode supercapacitor have been fabricated in a simple and inexpensive manner. The electrochemical characteristics of fabricated supercapacitor was analyzed using Cyclic Voltammetry (CV), galvanostatic charge discharge technique, and impedance spectroscopy methods. Capacitance of fabricated ZAC electrode were showed capacitance in the range of 60-70 F/g respectively. It has been found that the cells have excellent electro chemical reversibility, capacitive characteristics in electrolyte and stable in cyclings, which is promising for energy storage applications.

Understanding of assembly phenomena by aromatic-aromatic interactions: benzene dimer and the substituted systems.

PubMed

Lee, Eun Cheol; Kim, Dongwook; Jurecka, Petr; Tarakeshwar, P; Hobza, Pavel; Kim, Kwang S

2007-05-10

Interactions involving aromatic rings are important in molecular/biomolecular assembly and engineering. As a consequence, there have been a number of investigations on dimers involving benzene or other substituted pi systems. In this Feature Article, we examine the relevance of the magnitudes of their attractive and repulsive interaction energy components in governing the geometries of several pi-pi systems. The geometries and the associated binding energies were evaluated at the complete basis set (CBS) limit of coupled cluster theory with singles, doubles, and perturbative triples excitations [CCSD(T)] using a least biased scheme for the given data set. The results for the benzene dimer indicate that the floppy T-shaped structure (center-to-center distance: 4.96 A, with an axial benzene off-centered above the facial benzene) is isoenergetic in zero-point-energy (ZPE) corrected binding energy (D0) to the displaced-stacked structure (vertical interplanar distance: 3.54 A). However, the T-shaped structure is likely to be slightly more stable (D0 approximately equal to 2.4-2.5 kcal/mol) if quadruple excitations are included in the coupled cluster calculations. The presence of substituents on the aromatic ring, irrespective of their electron withdrawing or donating nature, leads to an increase in the binding energy, and the displaced-stacked conformations are more stabilized than the T-shaped conformers. This explains the wide prevalence of displaced stacked structures in organic crystals. Despite that the dispersion energy is dominating, the substituent as well as the conformational effects are correlated to the electrostatic interaction. This electrostatic origin implies that the substituent effect would be reduced in polar solution, but important in apolar media, in particular, for assembling processes.

Extending Halogen-based Medicinal Chemistry to Proteins

PubMed Central

El Hage, Krystel; Pandyarajan, Vijay; Phillips, Nelson B.; Smith, Brian J.; Menting, John G.; Whittaker, Jonathan; Lawrence, Michael C.; Meuwly, Markus; Weiss, Michael A.

2016-01-01

Insulin, a protein critical for metabolic homeostasis, provides a classical model for protein design with application to human health. Recent efforts to improve its pharmaceutical formulation demonstrated that iodination of a conserved tyrosine (TyrB26) enhances key properties of a rapid-acting clinical analog. Moreover, the broad utility of halogens in medicinal chemistry has motivated the use of hybrid quantum- and molecular-mechanical methods to study proteins. Here, we (i) undertook quantitative atomistic simulations of 3-[iodo-TyrB26]insulin to predict its structural features, and (ii) tested these predictions by X-ray crystallography. Using an electrostatic model of the modified aromatic ring based on quantum chemistry, the calculations suggested that the analog, as a dimer and hexamer, exhibits subtle differences in aromatic-aromatic interactions at the dimer interface. Aromatic rings (TyrB16, PheB24, PheB25, 3-I-TyrB26, and their symmetry-related mates) at this interface adjust to enable packing of the hydrophobic iodine atoms within the core of each monomer. Strikingly, these features were observed in the crystal structure of a 3-[iodo-TyrB26]insulin analog (determined as an R6 zinc hexamer). Given that residues B24–B30 detach from the core on receptor binding, the environment of 3-I-TyrB26 in a receptor complex must differ from that in the free hormone. Based on the recent structure of a “micro-receptor” complex, we predict that 3-I-TyrB26 engages the receptor via directional halogen bonding and halogen-directed hydrogen bonding as follows: favorable electrostatic interactions exploiting, respectively, the halogen's electron-deficient σ-hole and electronegative equatorial band. Inspired by quantum chemistry and molecular dynamics, such “halogen engineering” promises to extend principles of medicinal chemistry to proteins. PMID:27875310

Comprehensive Study of Microgel Electrode for On-Chip Electrophoretic Cell Sorting

NASA Astrophysics Data System (ADS)

Akihiro Hattori,; Kenji Yasuda,

2010-06-01

We have developed an on-chip cell sorting system and microgel electrode for applying electrostatic force in microfluidic pathways in the chip. The advantages of agarose electrodes are 1) current-driven electrostatic force generation, 2) stability against pH change and chemicals, and 3) no bubble formation caused by electrolysis. We examined the carrier ion type and concentration dependence of microgel electrode impedance, and found that CoCl2 has less than 1/10 of the impedance from NaCl, and the reduction of the impedance of NaCl gel electrode was plateaued at 0.5 M. The structure control of the microgel electrode exploiting the surface tension of sol-state agarose was also introduced. The addition of 1% (w/v) trehalose into the microgel electrode allowed the frozen storage of the microgel electrode chip. The experimental results demonstrate the potential of our system and microgel electrode for practical applications in microfluidic chips.

Quantum Mechanics/Molecular Mechanics Simulations Identify the Ring-Opening Mechanism of Creatininase.

PubMed

Jitonnom, Jitrayut; Mujika, Jon I; van der Kamp, Marc W; Mulholland, Adrian J

2017-12-05

Creatininase catalyzes the conversion of creatinine (a biosensor for kidney function) to creatine via a two-step mechanism: water addition followed by ring opening. Water addition is common to other known cyclic amidohydrolases, but the precise mechanism for ring opening is still under debate. The proton donor in this step is either His178 or a water molecule bound to one of the metal ions, and the roles of His178 and Glu122 are unclear. Here, the two possible reaction pathways have been fully examined by means of combined quantum mechanics/molecular mechanics simulations at the SCC-DFTB/CHARMM22 level of theory. The results indicate that His178 is the main catalytic residue for the whole reaction and explain its role as proton shuttle during the ring-opening step. In the first step, His178 provides electrostatic stabilization to the gem-diolate tetrahedral intermediate. In the second step, His178 abstracts the hydroxyl proton of the intermediate and delivers it to the cyclic amide nitrogen, leading to ring opening. The latter is the rate-limiting step with a free energy barrier of 18.5 kcal/mol, in agreement with the experiment. We find that Glu122 must be protonated during the enzyme reaction, so that it can form a stable hydrogen bond with its neighboring water molecule. Simulations of the E122Q mutant showed that this replacement disrupts the H-bond network formed by three conserved residues (Glu34, Ser78, and Glu122) and water, increasing the energy barrier. Our computational studies provide a comprehensive explanation for previous structural and kinetic observations, including why the H178A mutation causes a complete loss of activity but the E122Q mutation does not.

A DFT investigation of a bulky biomimetic model catalyzing the 5'-outer ring deiodination of thyroxine.

PubMed

Fortino, Mariagrazia; Marino, Tiziana; Russo, Nino; Sicilia, Emilia

2016-12-01

This paper illustrates the outcomes of a density functional theory investigation aimed at unraveling mechanistic aspects of the 5'-outer ring deiodination process of thyroxine (T4) assisted by the sterically protected organoselenol compound BpqSeH. BpqSeH, which was previously synthesized and tested for its deiodinase activity, is able to afford the active hormone 3,5,3'-tetraiodothyronine (T3) by selective outer-ring deiodination of T4, and to protect the SeH moiety inside the nano-sized molecular cavity from further reactivity, allowing its isolation and characterization. Calculations were also performed including an imidazole ring that, mimicking a His residue in the active site of the original enzyme, plays an crucial role in deprotonating the selenol moiety. Both the suggested enol/keto tautomerization and the previously proven formation of an intermediate whose main characteristic is the presence of a Se⋯I⋯C halogen bond, were examined along the pathway leading to 5'-outer ring deiodination. The calculated potential energy surface showed that neither the pathway encompassing enol/keto tautomerism nor the formation of a halogen bond paving the way to C-I bond breaking and chalcogen-I bond forming is viable. The exergonic formation of the final selenenyl iodide product confirms the stabilization effect of the molecular cavity. Graphical Abstract Computed free energy profile describing the 5'-outer deiodination of thyroxine assisted by the steric hindered organoselenol BpqSH compound. The molecular electrostatic potential map reoported for the INT1 intermediate shows the non-covalent Se-I interaction, due to the attraction between charges of opposite sign, that weakens the C-I bond and prepares the formation of the new Se-I bond.

Proton storage site in bacteriorhodopsin: new insights from QM/MM simulations of microscopic pKa and infrared spectra

PubMed Central

Goyal, Puja; Ghosh, Nilanjan; Phatak, Prasad; Clemens, Maike; Gaus, Michael; Elstner, Marcus; Cui, Qiang

2011-01-01

Identifying the group that acts as the proton storage/loading site is a challenging but important problem for understanding the mechanism of proton pumping in biomolecular proton pumps, such as bacteriorhodopsin (bR) and cytochrome c oxidase. Recent experimental studies of bR propelled the idea that the proton storage/release group (PRG) in bR is not an amino acid but a water cluster embedded in the protein. We argue that this idea is at odds with our knowledge of protein electrostatics, since invoking the water cluster as PRG would require the protein to raise the pKa of a hydronium by almost 11 pKa units, which is difficult considering known cases of pKa shifts in proteins. Our recent QM/MM simulations suggested an alternative “intermolecular proton bond” model in which the stored proton is shared between two conserved Glu residues (194 and 204). Here we show that this model leads to microscopic pKa values consistent with available experimental data and the functional requirement of a PRG. Extensive QM/MM simulations also show that, independent of a number of technical issues, such as the influence of QM region size, starting x-ray structure and nuclear quantum effects, the “intermolecular proton bond” model is qualitatively consistent with available spectroscopic data. Potential of mean force calculations show explicitly that the stored proton strongly prefers the pair of Glu residues over the water cluster. The results and analyses help highlight the importance of considering protein electrostatics and provide arguments for why the “intermolecular proton bond” model is likely applicable to PRG in biomolecular proton pumps in general. PMID:21761868

Capture, acceleration and bunching rf systems for the MEIC booster and storage rings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Shaoheng; Guo, Jiquan; Lin, Fanglei

2015-09-01

The Medium-energy Electron Ion Collider (MEIC), proposed by Jefferson Lab, consists of a series of accelerators. The electron collider ring accepts electrons from CEBAF at energies from 3 to 12 GeV. Protons and ions are delivered to a booster and captured in a long bunch before being ramped and transferred to the ion collider ring. The ion collider ring accelerates a small number of long ion bunches to colliding energy before they are re-bunched into a high frequency train of very short bunches for colliding. Two sets of low frequency RF systems are needed for the long ion bunch energymore » ramping in the booster and ion collider ring. Another two sets of high frequency RF cavities are needed for re-bunching in the ion collider ring and compensating synchrotron radiation energy loss in the electron collider ring. The requirements from energy ramping, ion beam bunching, electron beam energy compensation, collective effects, beam loading and feedback capability, RF power capability, etc. are presented. The preliminary designs of these RF systems are presented. Concepts for the baseline cavity and RF station configurations are described, as well as some options that may allow more flexible injection and acceleration schemes.« less

Electron cloud generation and trapping in a quadrupole magnet at the Los Alamos proton storage ring

NASA Astrophysics Data System (ADS)

Macek, Robert J.; Browman, Andrew A.; Ledford, John E.; Borden, Michael J.; O'Hara, James F.; McCrady, Rodney C.; Rybarcyk, Lawrence J.; Spickermann, Thomas; Zaugg, Thomas J.; Pivi, Mauro T. F.

2008-01-01

Recent beam physics studies on the two-stream e-p instability at the LANL proton storage ring (PSR) have focused on the role of the electron cloud generated in quadrupole magnets where primary electrons, which seed beam-induced multipacting, are expected to be largest due to grazing angle losses from the beam halo. A new diagnostic to measure electron cloud formation and trapping in a quadrupole magnet has been developed, installed, and successfully tested at PSR. Beam studies using this diagnostic show that the “prompt” electron flux striking the wall in a quadrupole is comparable to the prompt signal in the adjacent drift space. In addition, the “swept” electron signal, obtained using the sweeping feature of the diagnostic after the beam was extracted from the ring, was larger than expected and decayed slowly with an exponential time constant of 50 to 100μs. Other measurements include the cumulative energy spectra of prompt electrons and the variation of both prompt and swept electron signals with beam intensity. Experimental results were also obtained which suggest that a good fraction of the electrons observed in the adjacent drift space for the typical beam conditions in the 2006 run cycle were seeded by electrons ejected from the quadrupole.

Sperm storage, sperm translocation and genitalia formation in females of the terrestrial isopod Armadillidium vulgare (Crustacea, Peracarida, Isopoda).

PubMed

Ziegler, Andreas; Suzuki, Sachiko

2011-01-01

We investigated sperm storage, sperm transfer from the oviduct to the seminal receptacle, and formation of the cuticular genitalia in female Armadillidium vulgare using light and electron microscopy. Apolysis of the genitalia within the oviduct forms a circum-genital lumen. During insemination this space is filled with immobile spermatozoa. Sperm transfer into the seminal receptacle takes place before oviposition. Within a peculiar proximal neck region of the oviduct spermatozoa are bundled and enveloped by a folded epicuticular layer. The envelope tightly surrounds the spermatozoa probably forming a seal against the main part of the circum-genital lumen. We propose that hydrostatic pressure produced by the muscle cells surrounding the oviduct leads to sperm transfer into the seminal receptacle. Within the seminal receptacle the sperm bundle forms a ring just around the orifice to the oviduct. At one side sheath-like extensions of epithelial cells surround the ring of spermatozoa holding it in place. At the other side oocytes would have access to the sperm during oviposition, probably allowing for fertilisation when they pass right through the ring of spermatozoa. After oviposition the new genitalia are formed from epicuticular folds, and cuticle secreted by the epithelial cells. Copyright © 2010 Elsevier Ltd. All rights reserved.

New type of bonding formed from an overlap between pi aromatic and pi C=O molecular orbitals stabilizes the coexistence in one molecule of the ionic and neutral meso-ionic forms of imidazopyridine.

PubMed

Hoffmann, Marcin; Plutecka, Agnieszka; Rychlewska, Urszula; Kucybala, Zdzislaw; Paczkowski, Jerzy; Pyszka, Ilona

2005-05-26

New bis(imidazo)pyridine dye has been synthesized and tested as a potential photoinitaitor for free-radical polymerization induced with the visible emission of an argon ion laser. The X-ray analysis based on data collected at 170 and 130 K, as well as density functional theory (DFT) calculations, revealed the presence of two different forms of imidazopyridine rings within the same molecule. These two forms of the same moiety had not only different geometries but different electronic structures as well. One of the imidazopyridine rings was in the ionic form, while the other was in the meso-ionic form. DFT calculations provided an explanation for such an observed phenomena. The averaging of ionic and meso-ionic forms of imidazopyridine rings within the same molecule is hindered because of an attractive interaction between them. Analysis of electronic density revealed that, indeed, a new type of bonding is formed as the result of an overlap between pi aromatic and pi C=O molecular orbitals. This bonding, like the hydrogen bond, is primarily of electrostatic character, and its energy was estimated at 3.5 kcal/mol.

FT-IR and FT-Raman characterization and investigation of reactive properties of N-(3-iodo-4-methylphenyl)pyrazine-2-carboxamide by molecular dynamics simulations and DFT calculations

NASA Astrophysics Data System (ADS)

Ranjith, P. K.; Al-Abdullah, Ebtehal S.; Al-Omary, Fatmah A. M.; El-Emam, Ali A.; Anto, P. L.; Sheena, Mary Y.; Armaković, Stevan; Armaković, Sanja J.; Zitko, Jan; Dolezal, Martin; Van Alsenoy, C.

2017-05-01

The FT-IR and FT-Raman spectra of N-(3-iodo-4-methylphenyl)pyrazine-2-carboxamide were recorded and the experimentally observed wavenumbers are compared with the theoretically obtained wavenumbers. The redshift of the Nsbnd H stretching mode in the IR spectrum from the computed value indicated the weakening of the Nsbnd H bond. The ring breathing modes of the phenyl ring and pyrazine ring are assigned at 819 and 952 cm-1 theoretically. Using natural bond orbital analysis, the stability of the molecule arising from hyperconjugative interaction and charge delocalization has been analyzed. The most reactive sites in the molecule were identified by molecular electrostatic potential map. The calculations of the average local ionization energy (ALIE) were used for visualization and determination of molecule sites possibly prone to electrophilic attacks. Further information on possible reactive centers of title molecule has been obtained by calculations of Fukui functions. Vulnerability of title molecule towards autoxidation mechanism was investigated by calculations of bond dissociation energies (BDE), while vulnerability towards hydrolysis was investigated by calculations of radial distribution functions (RDF) as obtained after molecular dynamics (MD) simulations. Molecular docking studies suggest that the compound might exhibit inhibitory activity against mGluRs.

Monte Carlo calculation of skyshine'' neutron dose from ALS (Advanced Light Source)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moin-Vasiri, M.

1990-06-01

This report discusses the following topics on skyshine'' neutron dose from ALS: Sources of radiation; ALS modeling for skyshine calculations; MORSE Monte-Carlo; Implementation of MORSE; Results of skyshine calculations from storage ring; and Comparison of MORSE shielding calculations.

Computer Simulations Reveal Substrate Specificity of Glycosidic Bond Cleavage in Native and Mutant Human Purine Nucleoside Phosphorylase.

PubMed

Isaksen, Geir Villy; Hopmann, Kathrin Helen; Åqvist, Johan; Brandsdal, Bjørn Olav

2016-04-12

Purine nucleoside phosphorylase (PNP) catalyzes the reversible phosphorolysis of purine ribonucleosides and 2'-deoxyribonucleosides, yielding the purine base and (2'-deoxy)ribose 1-phosphate as products. While this enzyme has been extensively studied, several questions with respect to the catalytic mechanism have remained largely unanswered. The role of the phosphate and key amino acid residues in the catalytic reaction as well as the purine ring protonation state is elucidated using density functional theory calculations and extensive empirical valence bond (EVB) simulations. Free energy surfaces for adenosine, inosine, and guanosine are fitted to ab initio data and yield quantitative agreement with experimental data when the surfaces are used to model the corresponding enzymatic reactions. The cognate substrates 6-aminopurines (inosine and guanosine) interact with PNP through extensive hydrogen bonding, but the substrate specificity is found to be a direct result of the electrostatic preorganization energy along the reaction coordinate. Asn243 has previously been identified as a key residue providing substrate specificity. Mutation of Asn243 to Asp has dramatic effects on the substrate specificity, making 6-amino- and 6-oxopurines equally good as substrates. The principal effect of this particular mutation is the change in the electrostatic preorganization energy between the native enzyme and the Asn243Asp mutant, clearly favoring adenosine over inosine and guanosine. Thus, the EVB simulations show that this particular mutation affects the electrostatic preorganization of the active site, which in turn can explain the substrate specificity.

Radiological considerations for the operation of the Advanced Photon Source storage ring (revised).

DOE Office of Scientific and Technical Information (OSTI.GOV)

Moe, H. J.

2002-05-02

This report deals with the radiological considerations of operations using 7700-MeV positron and electron beams in the storage ring (SR) tunnel. The radiological considerations addressed include the following: prompt secondary radiation (bremsstrahlung, giant resonance neutrons, medium and high energy neutrons, and muons) produced by electrons/positrons interacting in a beam stop or by particle losses in the component structures; skyshine radiation, which produces a radiation field in nearby areas and at the nearest off-site location; radioactive gases produced by neutron irradiation of air in the vicinity of a particle loss site; noxious gases (ozone and others) produced in air by themore » escaping bremsstrahlung radiation that results from absorbing particles in the components or by synchrotron radiation escaping into the tunnel; activation of the storage ring components that results in a residual radiation field in the vicinity of these materials following shutdown; potential activation of water used for cooling the magnets and other purposes in the SR tunnel; evaluation of the radiation fields due to escaping synchrotron radiation and gas bremsstrahlung. Estimated dose rates outside of the tunnel, in the early assembly area (EAA), and in the Experiment Hall for several modes of operation (including potential safety envelope beam power, normal beam power, and MCI (maximum credible incident) conditions) have been computed. Shielding in the first optics enclosure (FOE) and for the photon beamlines is discussed in ANL/APS/TB-7 (IPE 93), but additional radiological considerations for the ASD diagnostic beamlines are contained in Appendix C. Although the calculations refer to positrons, electron operation would produce essentially the same effects for the identical assumptions.« less

Floodplain ecohydrology: Climatic, anthropogenic, and local physical controls on partitioning of water sources to riparian trees.

PubMed

Singer, Michael Bliss; Sargeant, Christopher I; Piégay, Hervé; Riquier, Jérémie; Wilson, Rob J S; Evans, Cristina M

2014-05-01

Seasonal and annual partitioning of water within river floodplains has important implications for ecohydrologic links between the water cycle and tree growth. Climatic and hydrologic shifts alter water distribution between floodplain storage reservoirs (e.g., vadose, phreatic), affecting water availability to tree roots. Water partitioning is also dependent on the physical conditions that control tree rooting depth (e.g., gravel layers that impede root growth), the sources of contributing water, the rate of water drainage, and water residence times within particular storage reservoirs. We employ instrumental climate records alongside oxygen isotopes within tree rings and regional source waters, as well as topographic data and soil depth measurements, to infer the water sources used over several decades by two co-occurring tree species within a riparian floodplain along the Rhône River in France. We find that water partitioning to riparian trees is influenced by annual (wet versus dry years) and seasonal (spring snowmelt versus spring rainfall) fluctuations in climate. This influence depends strongly on local (tree level) conditions including floodplain surface elevation and subsurface gravel layer elevation. The latter represents the upper limit of the phreatic zone and therefore controls access to shallow groundwater. The difference between them, the thickness of the vadose zone, controls total soil moisture retention capacity. These factors thus modulate the climatic influence on tree ring isotopes. Additionally, we identified growth signatures and tree ring isotope changes associated with recent restoration of minimum streamflows in the Rhône, which made new phreatic water sources available to some trees in otherwise dry years. Water shifts due to climatic fluctuations between floodplain storage reservoirsAnthropogenic changes to hydrology directly impact water available to treesEcohydrologic approaches to integration of hydrology afford new possibilities.