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Sample records for emission probabilities measurement

  1. New accurate measurements of neutron emission probabilities for relevant fission products

    NASA Astrophysics Data System (ADS)

    Agramunt, J.; Tain, J. L.; Albiol, F.; Algora, A.; Caballero-Folch, R.; Calviño, F.; Cortes, G.; Dillmann, I.; Eronen, T.; Garcia, A. R.; Ganioglu, E.; Gelletly, W.; Gorelov, D.; Guadilla, V.; Hakala, H.; Jokinen, A.; Kankainen, A.; Montaner, A.; Marta, M.; Mendoza, E.; Moore, I.; Nobs, C.; Orrigo, S.; Penttila, H.; Reponen, M.; Rinta-Antila, S.; Riego, A.; Rubio, B.; Saastamoinen, A.; Salvador-Castiñeira, P.; Tarifeño-Saldivia, A.; Tolosa, A.; Valencia, E.

    2017-09-01

    We have performed new accurate measurements of the beta-delayed neutron emission probability for ten isotopes of the elements Y, Sb, Te and I. These are fission products that either have a significant contribution to the fraction of delayed neutrons in reactors or are relatively close to the path of the astrophysical r process. The measurements were performed with isotopically pure radioactive beams using a constant and high efficiency neutron counter and a low noise beta detector. Preliminary results are presented for six of the isotopes and compared with previous measurements and theoretical calculations.

  2. Disintegration rate and gamma ray emission probability per decay measurement of 123I.

    PubMed

    Koskinas, M F; Gishitomi, K C; Brito, A B; Yamazaki, I M; Dias, M S

    2012-09-01

    A series of (123)I measurements have been carried out in a 4π(e(A),X)-γ coincidence system. The experimental extrapolation curve was determined and compared to Monte Carlo simulation, performed by code ESQUEMA. From the slope of the experimental curve, the total conversion coefficient for the 159 keV total gamma transition, α(159), was determined. All radioactive sources were also measured in an HPGe spectrometry system, in order to determine the gamma-ray emission probability per decay for several gamma transitions. All uncertainties involved and their correlations were analyzed applying the covariance matrix methodology and the measured parameters were compared with those from the literature. Copyright © 2012 Elsevier Ltd. All rights reserved.

  3. Direct measurement of alpha emission probabilities in the decay of (226)Ra.

    PubMed

    Marouli, M; Pommé, S; Van Ammel, R; García-Toraño, E; Crespo, T; Pierre, S

    2017-07-01

    High-resolution alpha-particle spectrometry was performed to determine the main alpha-particle emission probabilities in the decay of (226)Ra. Thin, homogeneous sources were prepared by electrodeposition on stainless steel disks. Alpha spectra with an energy resolution of 20keV were obtained in three laboratories and analysed with different deconvolution algorithms. In two set-ups, a magnet system was used to deflect conversion electrons to avoid their coincidental detection with the alpha particles. Spectra taken at close range without a magnet system yielded biased results which cannot be fully compensated by statistical corrections for coincidence summing. The derived emission probabilities of the three main alpha decays are 94.07 (1)%, 5.93 (1)%, and 0.0059 (15)%, respectively. They are in excellent agreement with calculated values derived from the P(γ+ce) decay scheme balance, which solves the existing discrepancy problem with two previous direct measurements published in literature. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

  4. Precise measurements of the absolute γ-ray emission probabilities of (223)Ra and decay progeny in equilibrium.

    PubMed

    Collins, S M; Pearce, A K; Regan, P H; Keightley, J D

    2015-08-01

    Precise measurements of the absolute γ-ray emission probabilities have been made of radiochemically pure solutions of (223)Ra in equilibrium with its decay progeny, which had been previously standardised by 4π(liquid scintillation)-γ digital coincidence counting techniques. Two high-purity germanium γ-ray spectrometers were used which had been accurately calibrated using a suite of primary and secondary radioactive standards. Comparison of the activity concentration determined by the primary technique against γ-ray spectrometry measurements using the nuclear data evaluations of the Decay Data Evaluation Project exhibited a range of ~18% in the most intense γ-ray emissions (>1% probability) of the (223)Ra decay series. Absolute γ-ray emission probabilities and standard uncertainties have been determined for the decay of (223)Ra, (219)Rn, (215)Po, (211)Pb, (211)Bi and (207)Tl in equilibrium. The standard uncertainties of the measured γ-ray emission probabilities quoted in this work show a significant improvement over previously reported γ-ray emission probabilities. Correlation coefficients for pairs of the measured γ-ray emission probabilities from the decays of the radionuclides (223)Ra, (219)Rn and (211)Pb have been determined and are presented. The α-transition probabilities of the (223)Ra have been deduced from P(γ+ce) balance using the γ-ray emission probabilities determined in this work with some agreement observed with the published experimental values of the α-emission probabilities. Crown Copyright © 2015. Published by Elsevier Ltd. All rights reserved.

  5. Disintegration rate, gamma-ray emission probabilities and metastable half-life measurements of ⁶⁷Ga.

    PubMed

    Dias, M S; Brancaccio, F; Toledo, F; Koskinas, M F

    2014-05-01

    The procedure for determining the (67)Ga disintegration rate by a primary method is described. The proposed triple 4πβ-γ coincidence system consists of a thin window gas-flow 4π proportional counter (PC) coupled to a NaI(Tl) scintillator and a HPGe crystal. Independent pulse height and occurrence time information is provided for the three detector outputs by means of a Software Coincidence System. Separate spectrometry measurements with a n-type reversed electrode coaxial Ge detector (REGe) were performed for obtaining gamma-ray emission probabilities per decay. Accurate values of disintegration rate, gamma-ray emission probabilities and the metastable half-life were achieved. © 2013 Published by Elsevier Ltd.

  6. Measurements of β-delayed neutron emission probabilities using a Paul trap

    NASA Astrophysics Data System (ADS)

    Scielzo, Nicholas

    2014-09-01

    Neutrons emitted following the β decay of neutron-rich isotopes play an important role in many fields of basic and applied science. Studies of these β-delayed neutrons are needed to better understand the structure of exotic nuclei and how the isotopes synthesized in r-process environments decay back to stability to produce the isotopic abundances observed today. In addition, precise studies of fission products provides valuable information for nuclear energy and stockpile stewardship applications. However, the data available today for individual nuclei is limited - for the vast majority of neutron emitters, the energy spectrum has not been measured and some recent measurements have uncovered discrepancies in β-delayed neutron branching ratios. Radioactive ions held in an ion trap are an appealing source of activity for improved studies of this β-delayed neutron emission process. When a radioactive ion decays in the trap, the recoil-daughter nucleus and emitted particles emerge from the approximately 1-mm3 trap volume with minimal scattering and propagate unobstructed through vacuum. These properties allow, for the first time, the momentum and energy of the emitted neutron to be precisely reconstructed from the nuclear recoil. By loading neutron-rich fission-product beams from the CARIBU facility at Argonne National Laboratory into a specially-designed radiofrequency quadrupole ion trap system, a program of β-delayed neutron spectroscopy in this largely unexplored region of the nuclear chart can be performed. This recoil-ion technique will be described and results from recent measurements at CARIBU and future prospects will be discussed. Neutrons emitted following the β decay of neutron-rich isotopes play an important role in many fields of basic and applied science. Studies of these β-delayed neutrons are needed to better understand the structure of exotic nuclei and how the isotopes synthesized in r-process environments decay back to stability to produce

  7. Investigation of the surrogate-reaction method via the simultaneous measurement of gamma-emission and fission probabilities

    NASA Astrophysics Data System (ADS)

    Jurado, B.; Marini, P.; Mathieu, L.; Aiche, M.; Czajkowski, S.; Tsekhanovich, I.; Audouin, L.; Boutoux, G.; Denis-Petit, D.; Guttormsen, M.; Kessedjian, G.; Lebois, M.; Méot, V.; Oberstedt, A.; Oberstedt, S.; Roig, O.; Sérot, O.; Tassan-Got, L.; Wilson, J. N.

    2017-09-01

    We present the results of two experiments where we have measured for the first time simultaneously the fission and gamma-decay probabilities induced by different surrogate reactions. In particular, we have investigated the 238U(d,p), 238U(3He,t) and 238U(3He,4He) reactions as surrogates for the neutron-induced n + 238U, n + 237Np and n + 236U reactions, respectively. In the region where gamma emission, neutron emission and fission compete, our results for the fission probabilities agree fairly well with the neutron-induced data, whereas our gamma-decay probabilities are significantly higher than the neutron-induced data. The interpretation of these results is not obvious and is discussed within the framework of the statistical model with preliminary results for calculated spin-parity distributions populated in surrogate reactions. We also present future plans for surrogate-reaction studies in inverse kinematics with radioactive-ion beams at storage rings.

  8. Photon emission probabilities of 201Tl

    NASA Astrophysics Data System (ADS)

    Kawada, Y.; Hino, Y.; Gatot, W.

    1990-01-01

    Precise measurements of the gamma- and X-ray emission probabilities per decay of 201Tl have been performed using a photon spectrometer with a reverse electrode Ge coaxial detector (LO-AX). The source activity was determined by the 4πβ-γ coincidence technique, and the influence of the coincidence sum effects between the K X-rays and the gamma rays was assessed. Radioactive impurities such as 200Tl and 202Tl were also taken into account.

  9. Determination of the gamma emission probabilities of 239Np

    NASA Astrophysics Data System (ADS)

    Jian-bo, Shang; li-li, Du; Tao, Bai; Yi-hua, Dai; Zhen-yuan, Zhong; Jie, Liu; Quan-lin, Shi

    2017-09-01

    239Np is an important nuclide as the decay daughter of 239U and it decays to 239Pu by emitting beta particles and gamma rays with a half life of 2.356 days. The data of the emission probabilities of its gamma-rays in the open references are consistent except for the main gamma-ray of 106.1 keV, the emission probability of which varies from 25.9% to 27.2%. To verify the emission probability of 106.1 keV gamma-ray of 239Np, a N-type coaxial HPGe detector was calibrated using 241Am, 133Ba, 60Co, 152Eu and 155Eu reference gamma sources to get the accurate efficiency of the 106.1 keV gamma-ray. 239Np was purified from solution containing 243Am, where 239Np is the alpha decay daughter of 243Am. The specific activity of 239Np solution was determined by a 4πβ (PC)-γ coincidence counting device. There were 6 gamma sources prepared to measure with the HPGe detector, and the activity of 239Np in each gamma source was calculated with the weights of the solution contained in it. The emission probability of 106.1 keV of 239Np is measured to be (25.4 ± 0.3)%, which is consistent with 25.34%, the value evaluated in 2014.

  10. Derivation of quantum probability from measurement

    NASA Astrophysics Data System (ADS)

    Herbut, Fedor

    2016-05-01

    To begin with, it is pointed out that the form of the quantum probability formula originates in the very initial state of the object system as seen when the state is expanded with the eigenprojectors of the measured observable. Making use of the probability reproducibility condition, which is a key concept in unitary measurement theory, one obtains the relevant coherent distribution of the complete-measurement results in the final unitary-measurement state in agreement with the mentioned probability formula. Treating the transition from the final unitary, or premeasurement, state, where all possible results are present, to one complete-measurement result sketchily in the usual way, the well-known probability formula is derived. In conclusion it is pointed out that the entire argument is only formal unless one makes it physical assuming that the quantum probability law is valid in the extreme case of probability-one (certain) events (projectors).

  11. Emissions & Measurements - Black Carbon

    EPA Science Inventory

    Emissions and Measurement (EM) research activities performed within the National Risk Management Research Lab NRMRL) of EPA's Office of Research and Development (ORD) support measurement and laboratory analysis approaches to accurately characterize source emissions, and near sour...

  12. Emissions & Measurements - Black Carbon

    EPA Science Inventory

    Emissions and Measurement (EM) research activities performed within the National Risk Management Research Lab NRMRL) of EPA's Office of Research and Development (ORD) support measurement and laboratory analysis approaches to accurately characterize source emissions, and near sour...

  13. Advances in the Measurement of Atomic Transition Probabilities

    NASA Astrophysics Data System (ADS)

    O'Brian, Thomas Raymond

    The technology for measuring absolute atomic transition probabilities is extended. Radiative lifetimes are measured by time-resolved laser-induced fluorescence on a slow atomic beam generated by a versatile hollow cathode discharge source. The radiative lifetimes are free from systematic error at the five percent level. Combined with branching fractions measured with emission or absorption sources, the lifetimes result in absolute transition probabilities usually accurate to 5-10 %. Three new developments in the lifetime and branching fraction technique are reported. Radiative lifetimes for 186 levels in neutral iron are measured, with the energy of the upper levels densely spanning the entire excitation range of neutral iron. Combined with branching fractions measured in emission with Fourier transform spectrophotometry, the level lifetimes directly yield absolute transition probabilities for 1174 transitions. An additional 640 transition probabilities are determined by interpolating level populations in an emission source. The dense energy spacing of the levels with directly measured lifetimes permits accurate population interpolation despite departures from local thermodynamic equilibrium. This technique has the potential to permit accurate absolute transition probability measurements for essentially every classified line in a spectrum. Radiative lifetime measurements are extended into the vacuum ultraviolet with a continuously tunable vacuum ultraviolet laser based on stimulated anti-Stokes Raman scattering. When used with the hollow cathode atomic beam source, accurate lifetimes are measured for 47 levels in neutral silicon and 8 levels in neutral boron, primarily in the vacuum ultraviolet spectral region. Transition probabilities are reported for many lines connected to these upper levels, using previously measured or calculated branching fractions. The hollow cathode beam source is developed for use with refractory non-metals. Intense atomic beams of boron

  14. Idempotent probability measures on ultrametric spaces

    NASA Astrophysics Data System (ADS)

    Hubal, Oleksandra; Zarichnyi, Mykhailo

    2008-07-01

    Following the construction due to Hartog and Vink we introduce a metric on the set of idempotent probability measures (Maslov measures) defined on an ultrametric space. This construction determines a functor on the category of ultrametric spaces and nonexpanding maps. We prove that this functor is the functorial part of a monad on this category. This monad turns out to contain the hyperspace monad.

  15. Determination of 198Au X-rays emission probabilities.

    PubMed

    Moreira, D S; Koskinas, M F; Dias, M S; Yamazaki, I M

    2010-01-01

    This work describes the measurements of the K X-ray and gamma-ray emission probabilities per decay of (198)Au performed at the Nuclear Metrology Laboratory (LMN) at the IPEN, São Paulo. The radioactive sample was obtained by means of (197)Au(n, gamma)(198)Au reaction irradiating an Au foil in a thermal neutron flux near the core of the IPEN 3.5 MW research reactor. The activity of samples was determined in a 4pibeta-gamma coincidence system, setting the gamma window at the 411.80 keV total energy absorption peak. The same samples were measured in two different spectrometers: a HPGe planar spectrometer with Be window, suitable for measurements in the low energy range and a coaxial REGe spectrometer. Both spectrometers were previously calibrated in a well defined geometry by means of standard sources calibrated in a 4pibeta-gamma coincidence system. MCNP4C Monte Carlo code was used for simulating the REGe spectrometer calibration curve, and a new version of code ESQUEMA was adopted for simulating the detection processes in the coincidence system, in order to predict the efficiency extrapolation curve. Copyright 2009 Elsevier Ltd. All rights reserved.

  16. Evaluation of the 1077 keV γ-ray emission probability from 68Ga decay

    NASA Astrophysics Data System (ADS)

    Huang, Xiao-Long; Jiang, Li-Yang; Chen, Xiong-Jun; Chen, Guo-Chang

    2014-04-01

    68Ga decays to the excited states of 68Zn through the electron capture decay mode. New recommended values for the emission probability of 1077 keV γ-ray given by the ENSDF and DDEP databases all use data from absolute measurements. In 2011, JIANG Li-Yang deduced a new value for 1077 keV γ-ray emission probability by measuring the 69Ga(n,2n) 68Ga reaction cross section. The new value is about 20% lower than values obtained from previous absolute measurements and evaluations. In this paper, the discrepancies among the measurements and evaluations are analyzed carefully and the new values are re-recommended. Our recommended value for the emission probability of 1077 keV γ-ray is (2.72±0.16)%.

  17. RCNP E398 {sup 16}O,{sup 12}C(p,p’) experiment: Measurement of the γ-ray emission probability from giant resonances in relation to {sup 16}O,{sup 12}C(ν,ν’) reactions

    SciTech Connect

    Ou, I.; Yamada, Y.; Mori, T.; Yano, T.; Sakuda, M.; Tamii, A.; Suzuki, T.; Yosoi, M.; Aoi, N.; Ideguchi, E.; Hashimoto, T.; Miki, K.; Ito, T.; Iwamoto, C.; Yamamoto, T.; Akimune, H.

    2015-05-15

    We propose to measure the γ-ray emission probability from excited states above 5 MeV including giant resonance of {sup 16}O and {sup 12}C as a function of excitation energy in 1-MeV step. Here, we measure both the excitation energy (E{sub x}=5-30MeV) at the forward scattering angles (0°-3°) of the {sup 16}O, {sup 12}C (p, p’) reaction using Grand-Raiden Spectrometer and the energy of γ-rays (E{sub γ}) using an array of NaI(Tl) counters. The purpose of the experiment is to provide the basic and important information not only for the γ-ray production from primary neutral-current neutrino-oxygen (-carbon) interactions but also for that from the secondary hadronic (neutron-oxygen and -carbon) interactions.

  18. Total variation denoising of probability measures using iterated function systems with probabilities

    NASA Astrophysics Data System (ADS)

    La Torre, Davide; Mendivil, Franklin; Vrscay, Edward R.

    2017-01-01

    In this paper we present a total variation denoising problem for probability measures using the set of fixed point probability measures of iterated function systems with probabilities IFSP. By means of the Collage Theorem for contraction mappings, we provide an upper bound for this problem that can be solved by determining a set of probabilities.

  19. Topology of spaces of probability measures

    NASA Astrophysics Data System (ADS)

    Banakh, T. O.; Radul, T. N.

    1997-08-01

    We study the space \\widehat P(X) of Radon probability measures on a metric space X and its subspaces P_c(X), P_d(X) and P_\\omega (X) of continuous measures, discrete measures, and finitely supported measures, respectively. It is proved that for any completely metrizable space X, the space \\widehat P(X) is homeomorphic to a Hilbert space. A topological classification is obtained for the pairs (\\widehat P(K),\\widehat P(X)), (\\widehat P(K),P_d(Y)) and (\\widehat P(K),P_c(Z)), where K is a metric compactum, X an everywhere dense Borel subset of K, Y an everywhere dense F_{\\sigma \\delta }-set of K, and Z an everywhere uncountable everywhere dense Borel subset of K of sufficiently high Borel class. Conditions on the pair (X,Y) are found that are necessary and sufficient for the pair (\\widehat P(X),P_\\omega (Y)) to be homeomorphic to (l^2(A),l^2_f(A)).

  20. Measures, Probability and Holography in Cosmology

    NASA Astrophysics Data System (ADS)

    Phillips, Daniel

    This dissertation compiles four research projects on predicting values for cosmological parameters and models of the universe on the broadest scale. The first examines the Causal Entropic Principle (CEP) in inhomogeneous cosmologies. The CEP aims to predict the unexpectedly small value of the cosmological constant Lambda using a weighting by entropy increase on causal diamonds. The original work assumed a purely isotropic and homogeneous cosmology. But even the level of inhomogeneity observed in our universe forces reconsideration of certain arguments about entropy production. In particular, we must consider an ensemble of causal diamonds associated with each background cosmology and we can no longer immediately discard entropy production in the far future of the universe. Depending on our choices for a probability measure and our treatment of black hole evaporation, the prediction for Lambda may be left intact or dramatically altered. The second related project extends the CEP to universes with curvature. We have found that curvature values larger than rho k = 40rhom are disfavored by more than $99.99% and a peak value at rhoLambda = 7.9 x 10-123 and rhok =4.3rho m for open universes. For universes that allow only positive curvature or both positive and negative curvature, we find a correlation between curvature and dark energy that leads to an extended region of preferred values. Our universe is found to be disfavored to an extent depending the priors on curvature. We also provide a comparison to previous anthropic constraints on open universes and discuss future directions for this work. The third project examines how cosmologists should formulate basic questions of probability. We argue using simple models that all successful practical uses of probabilities originate in quantum fluctuations in the microscopic physical world around us, often propagated to macroscopic scales. Thus we claim there is no physically verified fully classical theory of probability. We

  1. Transition probability measurement of several O II spectral lines

    NASA Astrophysics Data System (ADS)

    del Val, J. A.; Aparicio, J. A.; González, V. R.; Mar, S.

    2001-11-01

    This work reports atomic transition probabilities of 33 spectral lines belonging to 3s-3p, 3p-3d and 3d-4f multiplets of O II, all of them measured in the 405-465 nm spectral region in an emission experiment. Relative intensity measurements have been made on a pulsed discharge lamp and the absolute Aki-values have been obtained taking the NIST database as a reference in temperature diagnosis. The results of this work confirm the other recent available data measured by Veres and Wiese (Veres G and Wiese W L 1996 Phys. Rev. A 54 1999) with a different source and the calculations of Bell et al (Bell K L, Hibbert A, Stafford R P and McLaughlin B M 1994 Phys. Scr. 50 343) with a very satisfactory agreement (usually within 10%).

  2. Trending in Probability of Collision Measurements

    NASA Technical Reports Server (NTRS)

    Vallejo, J. J.; Hejduk, M. D.; Stamey, J. D.

    2015-01-01

    A simple model is proposed to predict the behavior of Probabilities of Collision (P(sub c)) for conjunction events. The model attempts to predict the location and magnitude of the peak P(sub c) value for an event by assuming the progression of P(sub c) values can be modeled to first order by a downward-opening parabola. To incorporate prior information from a large database of past conjunctions, the Bayes paradigm is utilized; and the operating characteristics of the model are established through a large simulation study. Though the model is simple, it performs well in predicting the temporal location of the peak (P(sub c)) and thus shows promise as a decision aid in operational conjunction assessment risk analysis.

  3. Inference of emission rates from multiple sources using Bayesian probability theory.

    PubMed

    Yee, Eugene; Flesch, Thomas K

    2010-03-01

    The determination of atmospheric emission rates from multiple sources using inversion (regularized least-squares or best-fit technique) is known to be very susceptible to measurement and model errors in the problem, rendering the solution unusable. In this paper, a new perspective is offered for this problem: namely, it is argued that the problem should be addressed as one of inference rather than inversion. Towards this objective, Bayesian probability theory is used to estimate the emission rates from multiple sources. The posterior probability distribution for the emission rates is derived, accounting fully for the measurement errors in the concentration data and the model errors in the dispersion model used to interpret the data. The Bayesian inferential methodology for emission rate recovery is validated against real dispersion data, obtained from a field experiment involving various source-sensor geometries (scenarios) consisting of four synthetic area sources and eight concentration sensors. The recovery of discrete emission rates from three different scenarios obtained using Bayesian inference and singular value decomposition inversion are compared and contrasted.

  4. Standardization and photon emission probabilities in the decay of 237Np/233Pa

    PubMed

    Schotzig; Schonfeld; Janszen

    2000-04-01

    The activity concentration of a 237Np solution was determined by 4pialpha counting, by alpha particle spectroscopy with defined solid angle and by liquid scintillation counting (LSC). These methods yielded results which differ by less than 0.1% from the mean, the relative standard uncertainties being 0.23% (4pialpha), 0.27% (LSC) and 0.5% (solid angle). X-ray and gamma-ray emission probabilities of several transitions were measured using semiconductor detectors.

  5. Experimental evidence for the reducibility of multifragment emission probabilities

    SciTech Connect

    Wozniak, G.J.; Tso, K.; Phair, L.

    1995-01-01

    Multifragmentation has been studied for {sup 36}Ar-induced reactions on a {sup 197}Au target at E/A = 80 and 110 MeV and for {sup 129}Xe-induced reactions on several targets ({sup nat}Cu, {sup 89}y, {sup 165}ho, {sup 197}Au) and E/A = 40, 50 and 60 MeV. The probability of emitting n intermediate-mass-fragments is shown to be binomial at each transversal energy and reducible to an elementary binary probability p. For each target and at each bombarding energy, this probability p shows a thermal nature by giving linear Arrhenius plots. For the {sup 129}Xe-induced reactions, a nearly universal linear Arrhenius plot is observed at each bombarding energy, indicating a large degree of target independence.

  6. Assault frequency and preformation probability of the {alpha} emission process

    SciTech Connect

    Zhang, H. F.; Royer, G.; Li, J. Q.

    2011-08-15

    A study of the assault frequency and preformation factor of the {alpha}-decay description is performed from the experimental {alpha}-decay constant and the penetration probabilities calculated from the generalized liquid-drop model (GLDM) potential barriers. To determine the assault frequency a quantum-mechanical method using a harmonic oscillator is introduced and leads to values of around 10{sup 21} s{sup -1}, similar to the ones calculated within the classical method. The preformation probability is around 10{sup -1}-10{sup -2}. The results for even-even Po isotopes are discussed for illustration. While the assault frequency presents only a shallow minimum in the vicinity of the magic neutron number 126, the preformation factor and mainly the penetrability probability diminish strongly around N=126.

  7. The ratios of emission probabilities of Auger electrons for 3d transition elements at 59,5 keV

    NASA Astrophysics Data System (ADS)

    Kündeyi, Kadriye; Aylıkcı, Nuray Küp; Tıraşoǧlu, Engin; Kahoul, Abdelhalim; Aylıkcı, Volkan

    2017-02-01

    The ratios of emission probabilities were determined by using the measured K shell X-ray intensity ratio values for elements from Sc to Zn. For the experimental measurements, the samples were excited by 59.5 keV γ rays from a 241Am annular radioactive source. The emitted K X-rays from the samples were counted by an Ultra-LEGe detector with a resolution of 150 eV at 5.9 keV. The ratios of emission probabilities were denoted as uand v which means p(KLX)/p(KLL) and p(KXY)/p(KLL) respectively. The extracted values from the measured intensity ratios and calculated intensity ratios were compared with the earlier studies. It was found that the ratios of emission probabilities that evaluated from the calculated intensity ratios were agree well with the earlier studies except for Zn.

  8. Measuring local context as context-word probabilities.

    PubMed

    Hahn, Lance W

    2012-06-01

    Context enables readers to quickly recognize a related word but disturbs recognition of unrelated words. The relatedness of a final word to a sentence context has been estimated as the probability (cloze probability) that a participant will complete a sentence with a word. In four studies, I show that it is possible to estimate local context-word relatedness based on common language usage. Conditional probabilities were calculated for sentences with published cloze probabilities. Four-word contexts produced conditional probabilities significantly correlated with cloze probabilities, but usage statistics were unavailable for some sentence contexts. The present studies demonstrate that a composite context measure based on conditional probabilities for one- to four-word contexts and the presence of a final period represents all of the sentences and maintains significant correlations (.25, .52, .53) with cloze probabilities. Finally, the article provides evidence for the effectiveness of this measure by showing that local context varies in ways that are similar to the N400 effect and that are consistent with a role for local context in reading. The Supplemental materials include local context measures for three cloze probability data sets.

  9. Are Einstein's transition probabilities for spontaneous emission constant in plasmas?

    NASA Technical Reports Server (NTRS)

    Griem, H. R.; Huang, Y. W.; Wang, J.-S.; Moreno, J. C.

    1991-01-01

    An investigation is conducted with a ruby laser to experimentally confirm the quenching of spontaneous emission coefficients and propose a mechanism for the phenomenon. Results of previous experiments are examined to determine the consistency and validity of interpretations of the spontaneous emissions. For the C IV 3s-3p and 2s-3p transitions, the line-intensity ratios are found to be dependent on the separation of the laser from the target. Density gradients and Stark broadening are proposed to interpret the results in a way that does not invalidate the Einstein A values. The interpretation is extended to C III and N V, both of which demonstrate similar changes in A values in previous experiments. The apparent quenching of Ar II by photon collisions is explained by Rabi oscillations and power broadening in the argon-ion laser cavity. It is concluded that the changes in A values cannot result from dense plasma effects.

  10. Are Einstein's transition probabilities for spontaneous emission constant in plasmas?

    NASA Technical Reports Server (NTRS)

    Griem, H. R.; Huang, Y. W.; Wang, J.-S.; Moreno, J. C.

    1991-01-01

    An investigation is conducted with a ruby laser to experimentally confirm the quenching of spontaneous emission coefficients and propose a mechanism for the phenomenon. Results of previous experiments are examined to determine the consistency and validity of interpretations of the spontaneous emissions. For the C IV 3s-3p and 2s-3p transitions, the line-intensity ratios are found to be dependent on the separation of the laser from the target. Density gradients and Stark broadening are proposed to interpret the results in a way that does not invalidate the Einstein A values. The interpretation is extended to C III and N V, both of which demonstrate similar changes in A values in previous experiments. The apparent quenching of Ar II by photon collisions is explained by Rabi oscillations and power broadening in the argon-ion laser cavity. It is concluded that the changes in A values cannot result from dense plasma effects.

  11. Behavioral measures of multisensory integration: bounds on bimodal detection probability.

    PubMed

    Colonius, Hans

    2015-01-01

    One way to test and quantify multisensory integration in a behavioral paradigm is to compare bimodal detection probability with bounds defined by some combination of the unimodal detection probabilities. Here we (1) improve on an upper bound recently suggested by Stevenson et al. (Brain Topogr 27(6):707-730, 2014), (2) present a lower bound, (3) interpret the bounds in terms of stochastic dependency between the detection probabilities, (4) discuss some additional assumptions required for the validity of any such bound, (5) suggest some potential applications to neurophysiologic measures, and point out some parallels to the 'race model inequality' for reaction times.

  12. Radiometric measurements of gap probability in conifer tree canopies

    NASA Technical Reports Server (NTRS)

    Albers, Bryan J.; Strahler, Alan H.; Li, Xiaowen; Liang, Shunlin; Clarke, Keith C.

    1990-01-01

    Measurements of gap probability were made for some moderate-sized, open-grown conifers of varying species. Results of the radiometric analysis show that the gap probability, which is taken as the mean of the binomial, fits well a negative exponential function of a path length. The conifer shadow, then, is an object of almost uniform darkness with some bright holes or gaps that are found near the shadow's edge and rapidly disappear toward the shadows center.

  13. Large -Delayed Neutron Emission Probabilities in the 78Ni Region

    SciTech Connect

    Winger, J. A.; Rykaczewski, Krzysztof Piotr; Gross, Carl J; Grzywacz, Robert Kazimierz; Shapira, Dan

    2009-01-01

    The -delayed neutron branching ratios (P n) for nuclei near doubly magic 78Ni have been directly measured using a new method combining high-resolution mass separation, reacceleration, and digital - spectroscopy of 238U fission products. The P n values for the very neutron-rich isotopes 76 78Cu and 83Ga were found to be much higher than previously reported and predicted. Revised calculations of the n process, accounting for new mass measurements and an inversion of the 2p3/2 and 1f5/2 orbitals, are in better agreement with these new experimental results.

  14. Comparing heteroscedastic measurement systems with the probability of agreement.

    PubMed

    Stevens, Nathaniel T; Steiner, Stefan H; MacKay, R Jock

    2017-01-01

    Deciding whether two measurement systems agree well enough to be used interchangeably is important in medical and clinical contexts. Recently, the probability of agreement was proposed as an alternative to comparison techniques such as correlation, regression, and the limits of agreement approach, when the systems' measurement errors are homoscedastic. However, in medical and clinical contexts, it is common for measurement variability to increase proportionally with the magnitude of measurement. In this article, we extend the probability of agreement analysis to accommodate heteroscedastic measurement errors, demonstrating the versatility of this simple metric. We illustrate its use with two examples: one involving the comparison of blood pressure measurement devices, and the other involving the comparison of serum cholesterol assays.

  15. Generating quantum-measurement probabilities from an optimality principle

    NASA Astrophysics Data System (ADS)

    Suykens, Johan A. K.

    2013-05-01

    An alternative formulation to the (generalized) Born rule is presented. It involves estimating an unknown model from a finite set of measurement operators on the state. An optimality principle is given that relates to achieving bounded solutions by regularizing the unknown parameters in the model. The objective function maximizes a lower bound on the quadratic Renyi classical entropy. The unknowns of the model in the primal are interpreted as transition witnesses. An interpretation of the Born rule in terms of fidelity is given with respect to transition witnesses for the pure state and the case of positive operator-valued measures (POVMs). The models for generating quantum-measurement probabilities apply to orthogonal projective measurements and POVM measurements, and to isolated and open systems with Kraus maps. A straightforward and constructive method is proposed for deriving the probability rule, which is based on Lagrange duality. An analogy is made with a kernel-based method for probability mass function estimation, for which similarities and differences are discussed. These combined insights from quantum mechanics, statistical modeling, and machine learning provide an alternative way of generating quantum-measurement probabilities.

  16. Gap probability - Measurements and models of a pecan orchard

    NASA Technical Reports Server (NTRS)

    Strahler, Alan H.; Li, Xiaowen; Moody, Aaron; Liu, YI

    1992-01-01

    Measurements and models are compared for gap probability in a pecan orchard. Measurements are based on panoramic photographs of 50* by 135 view angle made under the canopy looking upwards at regular positions along transects between orchard trees. The gap probability model is driven by geometric parameters at two levels-crown and leaf. Crown level parameters include the shape of the crown envelope and spacing of crowns; leaf level parameters include leaf size and shape, leaf area index, and leaf angle, all as functions of canopy position.

  17. Gap probability - Measurements and models of a pecan orchard

    NASA Technical Reports Server (NTRS)

    Strahler, Alan H.; Li, Xiaowen; Moody, Aaron; Liu, YI

    1992-01-01

    Measurements and models are compared for gap probability in a pecan orchard. Measurements are based on panoramic photographs of 50* by 135 view angle made under the canopy looking upwards at regular positions along transects between orchard trees. The gap probability model is driven by geometric parameters at two levels-crown and leaf. Crown level parameters include the shape of the crown envelope and spacing of crowns; leaf level parameters include leaf size and shape, leaf area index, and leaf angle, all as functions of canopy position.

  18. Integrated Emissivity And Temperature Measurement

    DOEpatents

    Poulsen, Peter

    2005-11-08

    A multi-channel spectrometer and a light source are used to measure both the emitted and the reflected light from a surface which is at an elevated temperature relative to its environment. In a first method, the temperature of the surface and emissivity in each wavelength is calculated from a knowledge of the spectrum and the measurement of the incident and reflected light. In the second method, the reflected light is measured from a reference surface having a known reflectivity and the same geometry as the surface of interest and the emitted and the reflected light are measured for the surface of interest. These measurements permit the computation of the emissivity in each channel of the spectrometer and the temperature of the surface of interest.

  19. Emissions & Measurements - Black Carbon | Science ...

    EPA Pesticide Factsheets

    Emissions and Measurement (EM) research activities performed within the National Risk Management Research Lab NRMRL) of EPA's Office of Research and Development (ORD) support measurement and laboratory analysis approaches to accurately characterize source emissions, and near source concentrations of air pollutants. They also support integrated Agency research programs (e.g., source to health outcomes) and the development of databases and inventories that assist Federal, state, and local air quality managers and industry implement and comply with air pollution standards. EM research underway in NRMRL supports the Agency's efforts to accurately characterize, analyze, measure and manage sources of air pollution. This pamphlet focuses on the EM research that NRMRL researchers conduct related to black carbon (BC). Black Carbon is a pollutant of concern to EPA due to its potential impact on human health and climate change. There are extensive uncertainties in emissions of BC from stationary and mobile sources. Emissions and Measurement (EM) research activities performed within the National Risk Management Research Lab NRMRL) of EPA's Office of Research and Development (ORD)

  20. Determination of ratios of Auger electrons emission probabilities and K-L shell vacancy transfer probability of Cr, Mn, Fe, Co, Ni, Cu and Zn compounds

    NASA Astrophysics Data System (ADS)

    Küçükönder, Adnan; Kavşut, Onur

    2017-02-01

    Ratios of emission probabilities of Auger electrons [u = p(KLX)/p(KLL), ν = p(KXY)/p(KLL)] and the vacancy transfer probabilities from K to L shell, ηKL for Cr, Mn, Fe, Co,Ni, Cu and Zn compounds were obtained using the experimental Kx-ray emission ratios and K-shell fluorescence yields. We were used the experimental Kβ/Kα intensity ratios and K shell fluorescence yields WK. Ratios of emission probabilities of Auger electrons and the vacancy transfer probabilities are changed by chemical effect for different for Cr, Mn, Fe, Co,Ni, Cu and Zn compounds.

  1. Three Experiments Involving Probability Measurement Procedures with Mathematics Test Items.

    ERIC Educational Resources Information Center

    Romberg, Thomas A.; And Others

    This is a report from the Project on Individually Guided Mathematics, Phase 2 Analysis of Mathematics Instruction. The report outlines some of the characteristics of probability measurement procedures for scoring objective tests, discusses hypothesized advantages and disadvantages of the methods, and reports the results of three experiments…

  2. Exact probability-density function for phase-measurement interferometry

    NASA Astrophysics Data System (ADS)

    Ho, Keang-Po; Kahn, Joseph M.

    1995-09-01

    Conventional analyses of the accuracy of phase-measurement interferometry derive a figure of merit that is either a variance or a signal-to-noise ratio. We derive the probability-density function of the phase-measurement output, so that the measurement confidence interval can be determined. We include both laser phase noise and additive Gaussian noise, and we consider both unmodulated interferometers and those employing phase or frequency modulation. For both unmodulated and modulated interferometers the confidence interval can be obtained by numerical integration of the probability-density function. For the modulated interferometer we derive a series summation for the confidence interval. For both unmodulated and modulated interferometers we derive approximate analytical expressions for the confidence interval, which we show to be extremely accurate at high signal-to-noise ratios.

  3. Probability distributions of continuous measurement results for conditioned quantum evolution

    NASA Astrophysics Data System (ADS)

    Franquet, A.; Nazarov, Yuli V.

    2017-02-01

    We address the statistics of continuous weak linear measurement on a few-state quantum system that is subject to a conditioned quantum evolution. For a conditioned evolution, both the initial and final states of the system are fixed: the latter is achieved by the postselection in the end of the evolution. The statistics may drastically differ from the nonconditioned case, and the interference between initial and final states can be observed in the probability distributions of measurement outcomes as well as in the average values exceeding the conventional range of nonconditioned averages. We develop a proper formalism to compute the distributions of measurement outcomes, and evaluate and discuss the distributions in experimentally relevant setups. We demonstrate the manifestations of the interference between initial and final states in various regimes. We consider analytically simple examples of nontrivial probability distributions. We reveal peaks (or dips) at half-quantized values of the measurement outputs. We discuss in detail the case of zero overlap between initial and final states demonstrating anomalously big average outputs and sudden jump in time-integrated output. We present and discuss the numerical evaluation of the probability distribution aiming at extending the analytical results and describing a realistic experimental situation of a qubit in the regime of resonant fluorescence.

  4. Measured quantum probability distribution functions for Brownian motion

    SciTech Connect

    Ford, G. W.; O'Connell, R. F.

    2007-10-15

    The quantum analog of the joint probability distributions describing a classical stochastic process is introduced. A prescription is given for constructing the quantum distribution associated with a sequence of measurements. For the case of quantum Brownian motion this prescription is illustrated with a number of explicit examples. In particular, it is shown how the prescription can be extended in the form of a general formula for the Wigner function of a Brownian particle entangled with a heat bath.

  5. Measurement of the Survival Probabilities for Hot Fusion Reactions

    NASA Astrophysics Data System (ADS)

    Yanez, R.; Loveland, W.; Yao, L.; Barrett, J. S.; Zhu, S.; Back, B. B.; Khoo, T. L.; Alcorta, M.; Albers, M.

    2014-04-01

    We have studied the fission-neutron emission competition in highly excited Hs274 (Z =108) (where the fission barrier is due to shell effects) formed by a hot fusion reaction. Matching cross bombardments (Mg26+Cm248 and Mg25+Cm248) were used to identify the properties of first chance fission of Hs274. A Harding-Farley analysis of the fission neutrons emitted in the Mg25,26+Cm248 was performed to identify the prescission and postscission components of the neutron multiplicities in each system. (Γn/Γt) for the first chance fission of Hs274 (E*=63 MeV) is 0.89±0.13; i.e., ˜90% of the highly excited nuclei survive. The high value of that survival probability is due to dissipative effects during deexcitation. A proper description of the survival probabilities of excited superheavy nuclei formed in hot fusion reactions requires consideration of both dynamic and static (shell-related) effects.

  6. Measurement of In-Flight Aircraft Emissions

    NASA Technical Reports Server (NTRS)

    Sokoloski, M.; Arnold, C.; Rider, D.; Beer, R.; Worden, H.; Glavich, T.

    1995-01-01

    Aircraft engine emission and their chemical and physical evolution can be measured in flight using high resolution infrared spectroscopy. The Airborne Emission Spectrometer (AES), designed for remote measure- ments of atmosphere emissions from an airborne platform, is an ideal tool for the evaluation of aircraft emissions and their evolution. Capabilities of AES will be discussed. Ground data will be given.

  7. Measurement of probability distributions for internal stresses in dislocated crystals

    SciTech Connect

    Wilkinson, Angus J.; Tarleton, Edmund; Vilalta-Clemente, Arantxa; Collins, David M.; Jiang, Jun; Britton, T. Benjamin

    2014-11-03

    Here, we analyse residual stress distributions obtained from various crystal systems using high resolution electron backscatter diffraction (EBSD) measurements. Histograms showing stress probability distributions exhibit tails extending to very high stress levels. We demonstrate that these extreme stress values are consistent with the functional form that should be expected for dislocated crystals. Analysis initially developed by Groma and co-workers for X-ray line profile analysis and based on the so-called “restricted second moment of the probability distribution” can be used to estimate the total dislocation density. The generality of the results are illustrated by application to three quite different systems, namely, face centred cubic Cu deformed in uniaxial tension, a body centred cubic steel deformed to larger strain by cold rolling, and hexagonal InAlN layers grown on misfitting sapphire and silicon carbide substrates.

  8. PABS: A Computer Program to Normalize Emission Probabilities and Calculate Realistic Uncertainties

    SciTech Connect

    Caron, D. S.; Browne, E.; Norman, E. B.

    2009-08-21

    The program PABS normalizes relative particle emission probabilities to an absolute scale and calculates the relevant uncertainties on this scale. The program is written in Java using the JDK 1.6 library. For additional information about system requirements, the code itself, and compiling from source, see the README file distributed with this program. The mathematical procedures used are given below.

  9. Measurements without probabilities in the final state proposal

    NASA Astrophysics Data System (ADS)

    Bousso, Raphael; Stanford, Douglas

    2014-02-01

    The black hole final state proposal reconciles the infalling vacuum with the unitarity of the Hawking radiation, but only for some experiments. We study experiments that first verify the exterior, then the interior purification of the same Hawking particle. (This is the same protocol that renders the firewall paradox operationally meaningful in standard quantum mechanics.) We show that the decoherence functional fails to be diagonal, even upon inclusion of external "pointer" systems. Hence, probabilities for outcomes of these measurements are not defined. We conclude that the final state proposal does not offer a consistent alternative to the firewall hypothesis.

  10. NOx emission calculations for bulk carriers by using engine power probabilities as weighting factors.

    PubMed

    Cheng, Chih-Wen; Hua, Jian; Hwang, Daw-Shang

    2017-10-01

    An important marine pollution issue identified by the International Maritime Organization (IMO) is NOx emissions; however, the stipulated method for determining the NOx certification value does not reflect the actual high emission factors of slow-speed two-stroke diesel engines over long-term slow steaming. In this study, an accurate method is presented for calculating the NOx emission factors and total amount of NOx emissions by using the actual power probabilities of the diesel engines in four types of bulk carriers. The proposed method is suitable for all types and purposes of diesel engines, is not restricted to any operating modes, and is highly accurate. Moreover, it is recommended that the IMO-stipulated certification value calculation method be modified accordingly to genuinely reduce the amount of NOx emissions. The successful achievement of this level of reduction will help improve the air quality, especially in coastal and port areas, and the health of local residents. As per the IMO, the NOx emission certification value of marine diesel engines having a rated power over 130 kW must be obtained using specified weighting factor (WF)-based calculation. However, this calculation fails to represent the current actual situation. Effective emission reductions of 6.91% (at sea) and 31.9% (in ports) were achieved using a mathematical model of power probability functions. Thus, we strongly recommend amending the certification value of NOx Technical Code 2008 (NTC 2008) by removing the WF constraints, such that the NOx emissions of diesel engines is lower than the Tier-limits at any load level to obtain genuine NOx emission reductions.

  11. A short course on measure and probability theories

    SciTech Connect

    Pebay, Philippe Pierre

    2004-02-01

    This brief Introduction to Measure Theory, and its applications to Probabilities, corresponds to the lecture notes of a seminar series given at Sandia National Laboratories in Livermore, during the spring of 2003. The goal of these seminars was to provide a minimal background to Computational Combustion scientists interested in using more advanced stochastic concepts and methods, e.g., in the context of uncertainty quantification. Indeed, most mechanical engineering curricula do not provide students with formal training in the field of probability, and even in less in measure theory. However, stochastic methods have been used more and more extensively in the past decade, and have provided more successful computational tools. Scientists at the Combustion Research Facility of Sandia National Laboratories have been using computational stochastic methods for years. Addressing more and more complex applications, and facing difficult problems that arose in applications showed the need for a better understanding of theoretical foundations. This is why the seminar series was launched, and these notes summarize most of the concepts which have been discussed. The goal of the seminars was to bring a group of mechanical engineers and computational combustion scientists to a full understanding of N. WIENER'S polynomial chaos theory. Therefore, these lectures notes are built along those lines, and are not intended to be exhaustive. In particular, the author welcomes any comments or criticisms.

  12. Directional spectral emissivity measurement system

    NASA Technical Reports Server (NTRS)

    Halyo, Nesim (Inventor); Pandey, Dhirendra K. (Inventor)

    1992-01-01

    Apparatus and process for determining the emissivity of a test specimen including an integrated sphere having two concentric walls with a coolant circulating therebetween, and disposed within a chamber which may be under ambient, vacuum or inert gas conditions. A reference sample is disposed within the sphere with a monochromatic light source in optical alignment therewith. A pyrometer is in optical alignment with the test sample for obtaining continuous test sample temperature measurements during a test. An arcuate slit port is provided through the spaced concentric walls of the integrating sphere with a movable monochromatic light source extending through and movable along the arcuate slit port. A detector system extends through the integrating sphere for continuously detecting an integrated signal indicative of all radiation within its field of view, as a function of the emissivity of the test specimen at various temperatures and various angle position of the monochromatic light source. A furnace for heating the test sample to approximately 3000 K. and control mechanism for transferring the heated sample from the furnace to the test sample port in the integrating sphere is also contained within the chamber.

  13. Predictions of active region flaring probability using subsurface helicity measurements

    NASA Astrophysics Data System (ADS)

    Reinard, A. A.; Komm, R.; Hill, F.

    2010-12-01

    Solar flares are responsible for a number of hazardous effects on the earth such as disabling high-frequency radio communications, interfering with GPS measurements, and disrupting satellites. However, forecasting flare occurrence is currently very difficult. One possible means for predicting flare occurrence lies in helioseismology, i.e. analysis of the region below the active region for signs of an impending flare. Time series helioseismic data collected by the Global Oscillation Network Group (GONG) has been analyzed for a subset of active regions that produce large flares and a subset with very high magnetic field strength that produce no flares. A predictive parameter has been developed and analyzed using discriminant analysis as well as traditional forecasting tools such as the Heidke skill score. Preliminary results show that this parameter predicts the flaring probability of an active region 2-3 days in advance with a relatively high degree of success.

  14. Furstenberg families, sensitivity and the space of probability measures

    NASA Astrophysics Data System (ADS)

    Li, Jie; Oprocha, Piotr; Wu, Xinxing

    2017-03-01

    In this paper we study relations of various types of sensitivity between a t.d.s. (X, T) and t.d.s. (M(X), T M ) induced by (X, T) on the space of probability measures. Among other results, we prove that F -sensitivity of (M(X), T M ) implies the same of (X, T) and the converse is also true when F is a filter. We show that (X, T) is multi-sensitive if and only if so is (M(X), T M ) and that (X, T) is F -sensitive if and only if ≤ft({{M}n}(X),{{T}M}\\right) is F -sensitive (for some/all n\\in {N} ). We finish the paper providing an example of a minimal syndetically sensitive t.d.s. or a Li–Yorke sensitive t.d.s. such that induced t.d.s. fails to be sensitive.

  15. Evaluation of Beta-Delayed Neutron Emission Probabilities and Half-Lives for Z = 2–28

    SciTech Connect

    Birch, M.; Singh, B.; Dillmann, I.; Abriola, D.; Johnson, T.D.; McCutchan, E.A.; Sonzogni, A.A.

    2015-09-15

    We present an evaluation and compilation of β-delayed neutron probabilities and half-lives for nuclei in the region Z = 2–28 ({sup 8}He–{sup 80}Ni). This article includes the recommended values of these quantities as well as a compiled list of experimental measurements for each nucleus in the region for which β-delayed neutron emission is possible. The literature cut-off for this work is August 15{sup th}, 2015. Some notable cases as well as new standards for β-delayed neutron measurements in this mass region are also discussed.

  16. PARTICULATE EMISSION MEASUREMENTS FROM CONTROLLED CONSTRUCTION ACTIVITIES

    EPA Science Inventory

    The report summarized the results of field testing of the effectiveness of control measures for sources of fugitive particulate emissions found at construction sites. The effectiveness of watering temporary, unpaved travel surfaces on emissions of particulate matter with aerodyna...

  17. PARTICULATE EMISSION MEASUREMENTS FROM CONTROLLED CONSTRUCTION ACTIVITIES

    EPA Science Inventory

    The report summarized the results of field testing of the effectiveness of control measures for sources of fugitive particulate emissions found at construction sites. The effectiveness of watering temporary, unpaved travel surfaces on emissions of particulate matter with aerodyna...

  18. Soil emissivity and reflectance spectra measurements.

    PubMed

    Sobrino, José A; Mattar, Cristian; Pardo, Pablo; Jiménez-Muñoz, Juan C; Hook, Simon J; Baldridge, Alice; Ibañez, Rafael

    2009-07-01

    We present an analysis of the laboratory reflectance and emissivity spectra of 11 soil samples collected on different field campaigns carried out over a diverse suite of test sites in Europe, North Africa, and South America from 2002 to 2008. Hemispherical reflectance spectra were measured from 2.0 to 14 microm with a Fourier transform infrared spectrometer, and x-ray diffraction analysis (XRD) was used to determine the mineralogical phases of the soil samples. Emissivity spectra were obtained from the hemispherical reflectance measurements using Kirchhoff's law and compared with in situ radiance measurements obtained with a CIMEL Electronique CE312-2 thermal radiometer and converted to emissivity using the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) temperature and emissivity separation algorithm. The CIMEL has five narrow bands at approximately the same positions as the ASTER. Results show a root mean square error typically below 0.015 between laboratory emissivity measurements and emissivity measurements derived from the field radiometer.

  19. Finite Orthoalgebras without Two-valued Probability Measures

    SciTech Connect

    Ruuge, Artur E.

    2007-02-21

    The Kochen-Specker theorem in quantum mechanics motivates the following combinatorial problem: how to construct a finite orthoalgebra which does not admit a two-valued probability measure? For example, the so-called 'Penrose's dodecahedron' (a projective configuration in C4) generates such an orthoalgebra. In this report one describes a new infinite family of examples of atomic coherent orthoalgebras with the mentioned properties which is intimately related to the geometry of the group's E8. The important features of the construction are the following: (1) the atomic elements are naturally indexed by the elements of a disjoint union of linear manifolds of codimension 1 of an N-dimensional vector space over F2; (2) the description of the orthogonality relation involves a pair of Z/2Z-valued functions on Z/4Z; (3) the symmetry of the construction is described in terms of an extension of GL(N, F2); (4) the whole construction works only if N is divisible by 4 (a phenomenon of periodicity)

  20. Determination of photon emission probabilities for the main gamma-rays of ²²³Ra in equilibrium with its progeny.

    PubMed

    Pibida, L; Zimmerman, B; Fitzgerald, R; King, L; Cessna, J T; Bergeron, D E

    2015-07-01

    The currently published (223)Ra gamma-ray emission probabilities display a wide variation in the values depending on the source of the data. The National Institute of Standards and Technology performed activity measurements on a (223)Ra solution that was used to prepare several sources that were used to determine the photon emission probabilities for the main gamma-rays of (223)Ra in equilibrium with its progeny. Several high purity germanium (HPGe) detectors were used to perform the gamma-ray spectrometry measurements.

  1. Photon assisted processes: Probability amplitudes for the absorption and emission of photons and dc-photocurrents

    SciTech Connect

    Micu, C.; Racolta, D.; Papp, E.

    2014-11-24

    In this paper one deals with the derivation of probability amplitudes characterizing the photon assisted injection of electrons in a two-terminal quantum conductor. For this purpose one accounts for spatially constant but time dependent periodic voltages applied on an Ohmic contact. Resorting to the discrete Fourier transform provides the probability amplitudes for the emission and absorption of photons in terms of squared Bessel functions of the first kind and integer order. Several kinds of ac-pulses like sinusoidal and dc+sinusoidal are assumed. Mean square values concerning photon numbers have been discussed in some more detail. Time averages of squared time dependent classical currents and leading corrections to the rescaled dc-photocurrent have also been accounted for.

  2. Assessment of Pneumatic Controller Emission Measurements ...

    EPA Pesticide Factsheets

    Oil and Natural Gas (ONG) production facilities have the potential to emit greenhouse gases such as methane (CH4) and other hydrocarbons (HCs) to the atmosphere. ONG production sites have multiple emission sources including storage tank venting, enclosed combustion devices, engine exhaust, pneumatic controllers and uncontrolled leaks. Accounting for up to 37.8 percent of CH4 emissions, pneumatic controllers are one of the most significant sources of CH4 in ONG production field operations. Recent measurement studies used the only commercially-available high volume sampling (HVS) technology (Bacharach Hi Flow Sampler, Bacharach, Inc., New Kensington, PA) to quantify CH4 emission rates of pneumatic devices on ONG production pads and compare to inventory estimates. Other studies indicate that this HVS may malfunction, causing underestimates of emissions in certain scenarios encountered in ONG production and should not be used for some sources such as heavy emissions from condensate storage tanks. The HVS malfunction can occur on relatively large emissions, where the measured leak concentrations exceed 5%, and is ascribed to a sensor transition failure in the instrument. The HVS malfunction is believed to be exacerbated by several factors (large emission rates, amount of non-CH4 HCs in the emission stream, non-optimal HVS calibration frequency, firmware, and emission measurement coupling geometries). The degree to which HVS measurements of emissions from pneumatic co

  3. Assessment of Pneumatic Controller Emission Measurements ...

    EPA Pesticide Factsheets

    Oil and Natural Gas (ONG) production facilities have the potential to emit greenhouse gases such as methane (CH4) and other hydrocarbons (HCs) to the atmosphere. ONG production sites have multiple emission sources including storage tank venting, enclosed combustion devices, engine exhaust, pneumatic controllers and uncontrolled leaks. Accounting for up to 37.8 percent of CH4 emissions, pneumatic controllers are one of the most significant sources of CH4 in ONG production field operations. Recent measurement studies used the only commercially-available high volume sampling (HVS) technology (Bacharach Hi Flow Sampler, Bacharach, Inc., New Kensington, PA) to quantify CH4 emission rates of pneumatic devices on ONG production pads and compare to inventory estimates. Other studies indicate that this HVS may malfunction, causing underestimates of emissions in certain scenarios encountered in ONG production and should not be used for some sources such as heavy emissions from condensate storage tanks. The HVS malfunction can occur on relatively large emissions, where the measured leak concentrations exceed 5%, and is ascribed to a sensor transition failure in the instrument. The HVS malfunction is believed to be exacerbated by several factors (large emission rates, amount of non-CH4 HCs in the emission stream, non-optimal HVS calibration frequency, firmware, and emission measurement coupling geometries). The degree to which HVS measurements of emissions from pneumatic co

  4. THE SEMIGROUP OF METRIC MEASURE SPACES AND ITS INFINITELY DIVISIBLE PROBABILITY MEASURES

    PubMed Central

    EVANS, STEVEN N.; MOLCHANOV, ILYA

    2015-01-01

    A metric measure space is a complete, separable metric space equipped with a probability measure that has full support. Two such spaces are equivalent if they are isometric as metric spaces via an isometry that maps the probability measure on the first space to the probability measure on the second. The resulting set of equivalence classes can be metrized with the Gromov–Prohorov metric of Greven, Pfaffelhuber and Winter. We consider the natural binary operation ⊞ on this space that takes two metric measure spaces and forms their Cartesian product equipped with the sum of the two metrics and the product of the two probability measures. We show that the metric measure spaces equipped with this operation form a cancellative, commutative, Polish semigroup with a translation invariant metric. There is an explicit family of continuous semicharacters that is extremely useful for, inter alia, establishing that there are no infinitely divisible elements and that each element has a unique factorization into prime elements. We investigate the interaction between the semigroup structure and the natural action of the positive real numbers on this space that arises from scaling the metric. For example, we show that for any given positive real numbers a, b, c the trivial space is the only space that satisfies a ⊞ b = c . We establish that there is no analogue of the law of large numbers: if X1, X2, … is an identically distributed independent sequence of random spaces, then no subsequence of 1n⊞k=1nXk converges in distribution unless each Xk is almost surely equal to the trivial space. We characterize the infinitely divisible probability measures and the Lévy processes on this semigroup, characterize the stable probability measures and establish a counterpart of the LePage representation for the latter class. PMID:28065980

  5. THE SEMIGROUP OF METRIC MEASURE SPACES AND ITS INFINITELY DIVISIBLE PROBABILITY MEASURES.

    PubMed

    Evans, Steven N; Molchanov, Ilya

    2017-01-01

    A metric measure space is a complete, separable metric space equipped with a probability measure that has full support. Two such spaces are equivalent if they are isometric as metric spaces via an isometry that maps the probability measure on the first space to the probability measure on the second. The resulting set of equivalence classes can be metrized with the Gromov-Prohorov metric of Greven, Pfaffelhuber and Winter. We consider the natural binary operation ⊞ on this space that takes two metric measure spaces and forms their Cartesian product equipped with the sum of the two metrics and the product of the two probability measures. We show that the metric measure spaces equipped with this operation form a cancellative, commutative, Polish semigroup with a translation invariant metric. There is an explicit family of continuous semicharacters that is extremely useful for, inter alia, establishing that there are no infinitely divisible elements and that each element has a unique factorization into prime elements. We investigate the interaction between the semigroup structure and the natural action of the positive real numbers on this space that arises from scaling the metric. For example, we show that for any given positive real numbers a, b, c the trivial space is the only space that satisfies a ⊞ b = c . We establish that there is no analogue of the law of large numbers: if X1, X2, … is an identically distributed independent sequence of random spaces, then no subsequence of [Formula: see text] converges in distribution unless each Xk is almost surely equal to the trivial space. We characterize the infinitely divisible probability measures and the Lévy processes on this semigroup, characterize the stable probability measures and establish a counterpart of the LePage representation for the latter class.

  6. Direct emissivity measurements of IR materials

    NASA Astrophysics Data System (ADS)

    Kisler, Yanina; Kupferberg, Lenn C.; Mackenzie, Gordon; Chen, Chia M.

    1999-07-01

    Emissivity measurements of ZnS, Sapphire, ALON, MgO, and Yttria were performed in 3.9-4.0 micrometers and 4.4-4.9 micrometers bands, for temperatures between 300 degrees C and 600 degrees C. The average radiance was measured over each waveband. Emissivity was calculated as the ratio of the radiance of the sample to that of a black body source at the same temperature. The results of the emissivity measurements for the above-mentioned materials will be reported. Measurement techniques that allowed increasing the dynamic range of the measurement and significantly reducing the noise will be discussed.

  7. Measurement of Fugitive Dust Emissions and Visible Emissions.

    ERIC Educational Resources Information Center

    McKee, Herbert C.

    The method of measuring fugitive dust emission utilized by the Texas Air Control Board is described in this presentation for the 12th Conference on Methods in Air Pollution and Industrial Hygiene Studies, University of Southern California, April, 1971. The measuring procedure, precautions, expected results, and legal acceptance of the method are…

  8. Measurement of Fugitive Dust Emissions and Visible Emissions.

    ERIC Educational Resources Information Center

    McKee, Herbert C.

    The method of measuring fugitive dust emission utilized by the Texas Air Control Board is described in this presentation for the 12th Conference on Methods in Air Pollution and Industrial Hygiene Studies, University of Southern California, April, 1971. The measuring procedure, precautions, expected results, and legal acceptance of the method are…

  9. Lidar Measurements of Industrial Benzene Emissions

    NASA Astrophysics Data System (ADS)

    Berkhout, A. J. C.; van der Hoff, G. R.; Gast, L. F. L.

    2016-06-01

    The ability to measure benzene concentrations was added to the RIVM mobile DIAL system. In a ten-days campaign, it was used to measure benzene emissions in the Rijnmond, a heavily industrialised area in the South-west of the Netherlands with petrochemical industry, petrochemical products storage and the port of Rotterdam. On two of the ten days, benzene emissions were found. Combined with measurements of wind speed and wind direction, the Lidar measurements indicated the possible origins of these emissions. This makes the Lidar a valuable tool, augmenting the data collected at fixed monitoring stations.

  10. Soil emissivity and reflectance spectra measurements

    SciTech Connect

    Sobrino, Jose A.; Mattar, Cristian; Pardo, Pablo; Jimenez-Munoz, Juan C.; Hook, Simon J.; Baldridge, Alice; Ibanez, Rafael

    2009-07-01

    We present an analysis of the laboratory reflectance and emissivity spectra of 11 soil samples collected on different field campaigns carried out over a diverse suite of test sites in Europe, North Africa, and South America from 2002 to 2008. Hemispherical reflectance spectra were measured from 2.0 to 14 {mu}m with a Fourier transform infrared spectrometer, and x-ray diffraction analysis (XRD) was used to determine the mineralogical phases of the soil samples. Emissivity spectra were obtained from the hemispherical reflectance measurements using Kirchhoff's law and compared with in situ radiance measurements obtained with a CIMEL Electronique CE312-2 thermal radiometer and converted to emissivity using the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) temperature and emissivity separation algorithm. The CIMEL has five narrow bands at approximately the same positions as the ASTER. Results show a root mean square error typically below 0.015 between laboratory emissivity measurements and emissivity measurements derived from the field radiometer.

  11. WOODSTOVE EMISSION MEASUREMENT METHODS COMPARISON AND EMISSION FACTORS UPDATE

    EPA Science Inventory

    This paper compares various field and laboratory woodstove emission measurement methods. n 1988, the U.S. EPA promulgated performance standards for residential wood heaters (woodstoves). ver the past several years, a number of field studies have been undertaken to determine the a...

  12. WOODSTOVE EMISSION MEASUREMENT METHODS COMPARISON AND EMISSION FACTORS UPDATE

    EPA Science Inventory

    This paper compares various field and laboratory woodstove emission measurement methods. n 1988, the U.S. EPA promulgated performance standards for residential wood heaters (woodstoves). ver the past several years, a number of field studies have been undertaken to determine the a...

  13. Two-temperature method for measuring emissivity

    USGS Publications Warehouse

    Watson, K.

    1992-01-01

    Spectral emissivity can be uniquely determined from radiance measurements if the object can be observed at two different temperatures. The advantage of this approach is that the spectral emissivity is determined without a priori assumptions about spectral shape. Because the different temperatures are obtained by observing the scene at two times in the diurnal cycle (optimally after midday and midnight), the method assumes that emissivity is temporally invariant. This is valid for rocks and dry soils, not well established for vegetation, and not true when changes in soil moisture occur between the measurements. Accurate image registration and satisfactory signal:noise are critical factors that limit extensive use of this method. ?? 1992.

  14. A New Approach to Estimating the Probability for β-delayed Neutron Emission

    SciTech Connect

    McCutchan, E.A.; Sonzogni, A.A.; Johnson, T.D.; Abriola, D.; Birch, M.; Singh, B.

    2014-06-15

    The probability for neutron emission following β decay, Pn, is a crucial property for a wide range of physics and applications including nuclear structure, r-process nucleosynthesis, the control of nuclear reactors, and the post-processing of nuclear fuel. Despite much experimental effort, knowledge of Pn values is still lacking in very neutron-rich nuclei, requiring predictions from either systematics or theoretical models. Traditionally, systematic predictions were made by investigating the Pn value as a function of the decay Q value and the neutron separation energy in the daughter nucleus. A new approach to Pn systematics is presented which incorporates the half-life of the decay and the Q value for β-delayed neutron emission. This prescription correlates the known data better, and thus improves the estimation of Pn values for neutron-rich nuclei. Such an approach can be applied to generate input values for r-process network calculations or in the modeling of advanced fuel cycles.

  15. Measuring light emission from LEDs

    NASA Astrophysics Data System (ADS)

    Young, Richard

    2006-09-01

    LEDs are used in many applications, and new applications are found every day. To address this market, LEDs often come in vastly different varieties, shapes, sizes, packages and modules. Measurement of these LEDs is required so that they can be compared and selected within a global market. This paper presents the different types of optical quantity that can be measured for these LEDs together with guidelines for measurement. In particular, the protocols for measuring Averaged LED Intensity, Partial LED Flux, luminance and illuminance are presented. Some of these quantities are new, and the reader may be unfamiliar with them. Definitions are provided where appropriate. Many LED measurements have associated standard measurement conditions, which apply to LEDs and not other sources. Other measurements depend critically on setup conditions but lack standardization and hence details of methods used must accompany results. Where standard conditions exist these are detailed and where they do not advice is provided on the best methodologies. Work in establishing standard conditions is on-going, especially in Commission Internationale de l'Eclairage (CIE) technical committees, and information on this work is provided.

  16. On-road particulate emission measurement

    NASA Astrophysics Data System (ADS)

    Mazzoleni, Claudio

    Particulate matter (PM) suspended in the atmosphere has harmful health effects, contributes to visibility impairment, and affects atmospheric radiative transfer, thereby contributing to global change. Vehicles contribute substantially to the ambient PM concentration in urban areas, yet the fraction of ambient PM originating from vehicle emissions is poorly characterized because suitable measurement methods have not been available. This dissertation describes the development and the use of a new vehicle emission remote sensing system (VERSS) for the on-road measurement of PM emission factors for vehicles. The PM VERSS measures PM by ultraviolet backscattering and transmission. PM backscattering and transmission mass efficiencies have been calculated from Mie theory based on an homogeneous spherical model for gasoline particles and on a two-layers, spherical model for diesel particles. The VERSS was used in a large-scale study in Las Vegas, NV. A commercial gaseous VERSS was used for the measurement of gaseous emission factors (i.e., carbon monoxide, hydrocarbons, and nitrogen oxide). Speed and acceleration were also measured for each vehicle. A video image of each vehicle's rear license plate was acquired and license plate numbers were matched with the Clark County department of motor vehicle database to retrieve vehicle information such as model year, vehicle weight category and engine ignition type. PM VERSS has precisely estimated PM fleet average emission factors and clearly shown the dependence of PM emission factors on vehicle model year. Under mostly hot-stabilized operation, diesel vehicle PM emission factors are about 25 times higher than those of gasoline vehicles. Furthermore, the fleet frequency distributions of PM emission factors are highly skewed, meaning that most of the fleet emission factor is accounted for by a small portion of the fleet. The PM VERSS can measure PM emission factors for these high emitting vehicles on an individual basis. PM

  17. Comparison of Field Measurements to Methane Emissions ...

    EPA Pesticide Factsheets

    Due to both technical and economic limitations, estimates of methane emissions from landfills rely primarily on models. While models are easy to implement, there is uncertainty due to the use of parameters that are difficult to validate. The objective of this research was to compare modeled emissions using several greenhouse gas (GHG) emissions reporting protocols including: (1) Intergovernmental Panel on Climate Change (IPCC); (2) U.S. Environmental Protection Agency Greenhouse Gas Reporting Program (EPA GHGRP); (3) California Air Resources Board (CARB); (4) Solid Waste Industry for Climate Solutions (SWICS); and (5) an industry model from the Dutch waste company Afvalzorg, with measured data collected over 3 calendar years from a young landfill with no gas collection system. By working with whole landfill measurements of fugitive methane emissions and methane oxidation, the collection efficiency could be set to zero, thus eliminating one source of parameter uncertainty. The models consistently overestimated annual methane emissions by a factor ranging from 4 – 32.Varying input parameters over reasonable ranges reduced this range to 1.3 - 8. Waste age at the studied landfill was less than four years and the results suggest the need for measurements at additional landfills to evaluate the accuracy of the tested models to young landfills. This is a submission to a peer reviewed journal. The paper discusses landfill emission measurements and models for a new la

  18. Probability distributions for measures of placental shape and morphology.

    PubMed

    Gill, J S; Woods, M P; Salafia, C M; Vvedensky, D D

    2014-03-01

    Birthweight at delivery is a standard cumulative measure of placental growth, but is a crude summary of other placental characteristics, such as, e.g., the chorionic plate size, and the shape and position of the umbilical cord insertion. Distributions of such measures across a cohort reveal information about the developmental history of the chorionic plate which is unavailable from an analysis based solely on the mean and standard deviation. Various measures were determined from digitized images of chorionic plates obtained from the pregnancy, infection, and nutrition study, a prospective cohort study of preterm birth in central North Carolina between 2002 and 2004. Centroids (geometric centers) and umbilical cord insertions were taken directly from the images. Chorionic plate outlines were obtained from an interpolation based on a Fourier series, while eccentricity (of the best-fit ellipse), skewness, and kurtosis were determined from the method of moments. Histograms of each variable were compared against the normal, lognormal, and Lévy distributions. Only a single measure (eccentricity) followed a normal distribution. All others followed lognormal or 'heavy-tailed' distributions for moderate to extreme deviations from the mean, where the relative likelihood far exceeded those of a normal distribution.

  19. Beta-decay rate and beta-delayed neutron emission probability of improved gross theory

    NASA Astrophysics Data System (ADS)

    Koura, Hiroyuki

    2014-09-01

    A theoretical study has been carried out on beta-decay rate and beta-delayed neutron emission probability. The gross theory of the beta decay is based on an idea of the sum rule of the beta-decay strength function, and has succeeded in describing beta-decay half-lives of nuclei overall nuclear mass region. The gross theory includes not only the allowed transition as the Fermi and the Gamow-Teller, but also the first-forbidden transition. In this work, some improvements are introduced as the nuclear shell correction on nuclear level densities and the nuclear deformation for nuclear strength functions, those effects were not included in the original gross theory. The shell energy and the nuclear deformation for unmeasured nuclei are adopted from the KTUY nuclear mass formula, which is based on the spherical-basis method. Considering the properties of the integrated Fermi function, we can roughly categorized energy region of excited-state of a daughter nucleus into three regions: a highly-excited energy region, which fully affect a delayed neutron probability, a middle energy region, which is estimated to contribute the decay heat, and a region neighboring the ground-state, which determines the beta-decay rate. Some results will be given in the presentation. A theoretical study has been carried out on beta-decay rate and beta-delayed neutron emission probability. The gross theory of the beta decay is based on an idea of the sum rule of the beta-decay strength function, and has succeeded in describing beta-decay half-lives of nuclei overall nuclear mass region. The gross theory includes not only the allowed transition as the Fermi and the Gamow-Teller, but also the first-forbidden transition. In this work, some improvements are introduced as the nuclear shell correction on nuclear level densities and the nuclear deformation for nuclear strength functions, those effects were not included in the original gross theory. The shell energy and the nuclear deformation for

  20. Measurement of light emission in scintillation vials

    SciTech Connect

    Duran Ramiro, M. Teresa; Garcia-Torano, Eduardo

    2005-09-15

    The efficiency and energy resolution of liquid scintillation counting (LSC) systems are strongly dependent on the optical characteristics of scintillators, vials, and reflectors. This article presents the results of measurements of the light-emission profile of scintillation vials. Two measurement techniques, autoradiographs and direct measurements with a photomultiplier tube, have been used to obtain light-emission distribution for standard vials of glass, etched glass and polyethylene. Results obtained with both techniques are in good agreement. For the first time, the effect of the meniscus in terms of light contribution has been numerically estimated. These results can help design LSC systems that are more efficient in terms of light collection.

  1. Laser-based measurement of transition probabilities of neon 2p 53s-2p 53p transitions

    NASA Astrophysics Data System (ADS)

    Fujimoto, Takashi; Goto, Chiaki; Uetani, Yasunori; Fukuda, Kuniya

    1985-01-01

    By using the magic-angle, pulsed-excitation method in the presence of a magnetic field, the authors have measured the branching ratios for 2p 53s-2p 53p transitions in neon. By combining values for the lifetime of the upper levels with the branching ratios, they have determined the transition probabilities of 31 transitions. The results are in good agreement with those from emission spectroscopy of a high-pressure are plasma by Bridges and Wiese.

  2. Assessment of Component-level Emission Measurements ...

    EPA Pesticide Factsheets

    Oil and natural gas (ONG) production facilities have the potential to emit a substantial amount of greenhouse gasses, hydrocarbons and hazardous air pollutants into the atmosphere. These emissions come from a wide variety of sources including engine exhaust, combustor gases, atmospheric venting from uncontrolled tanks and leaks. Engine exhaust, combustor gases and atmospheric tank venting are included in the initial estimation of a production facilities cumulative emissions. However, there is a large amount of uncertainty associated with magnitude and composition of leaks at these facilities. In order to understand the environmental impacts of these emissions we must first be able characterize the emission flow rate and chemical composition of these leaks/venting. A number of recent publications regarding emission flow rate measurements of components at ONG production facilities have brought into question the validity of such measurements and the sampling methodology. An accurate methodology for quantifying hydrocarbon leaks/venting is needed to support both emission inventories and environmental compliance. This interim report will summarize recent results from a small leak survey completed at ONG production facilities in Utah to characterize their flow rate and chemical composition using a suite of instruments using a high volume sampler (Bacharach Hi Flow Sampler; Bacharach, Inc.), as well as infrared (IR) cameras, a photoionization detector (PID), a fl

  3. Assessment of Component-level Emission Measurements ...

    EPA Pesticide Factsheets

    Oil and natural gas (ONG) production facilities have the potential to emit a substantial amount of greenhouse gasses, hydrocarbons and hazardous air pollutants into the atmosphere. These emissions come from a wide variety of sources including engine exhaust, combustor gases, atmospheric venting from uncontrolled tanks and leaks. Engine exhaust, combustor gases and atmospheric tank venting are included in the initial estimation of a production facilities cumulative emissions. However, there is a large amount of uncertainty associated with magnitude and composition of leaks at these facilities. In order to understand the environmental impacts of these emissions we must first be able characterize the emission flow rate and chemical composition of these leaks/venting. A number of recent publications regarding emission flow rate measurements of components at ONG production facilities have brought into question the validity of such measurements and the sampling methodology. An accurate methodology for quantifying hydrocarbon leaks/venting is needed to support both emission inventories and environmental compliance. This interim report will summarize recent results from a small leak survey completed at ONG production facilities in Utah to characterize their flow rate and chemical composition using a suite of instruments using a high volume sampler (Bacharach Hi Flow Sampler; Bacharach, Inc.), as well as infrared (IR) cameras, a photoionization detector (PID), a fl

  4. Measuring a fair and ambitious climate agreement using cumulative emissions

    NASA Astrophysics Data System (ADS)

    Peters, Glen P.; Andrew, Robbie M.; Solomon, Susan; Friedlingstein, Pierre

    2015-10-01

    Policy makers have called for a ‘fair and ambitious’ global climate agreement. Scientific constraints, such as the allowable carbon emissions to avoid exceeding a 2 °C global warming limit with 66% probability, can help define ambitious approaches to climate targets. However, fairly sharing the mitigation challenge to meet a global target involves human values rather than just scientific facts. We develop a framework based on cumulative emissions of carbon dioxide to compare the consistency of countries’ current emission pledges to the ambition of keeping global temperatures below 2 °C, and, further, compare two alternative methods of sharing the remaining emission allowance. We focus on the recent pledges and other official statements of the EU, USA, and China. The EU and US pledges are close to a 2 °C level of ambition only if the remaining emission allowance is distributed based on current emission shares, which is unlikely to be viewed as ‘fair and ambitious’ by others who presently emit less. China’s stated emissions target also differs from measures of global fairness, owing to emissions that continue to grow into the 2020s. We find that, combined, the EU, US, and Chinese pledges leave little room for other countries to emit CO2 if a 2 °C limit is the objective, essentially requiring all other countries to move towards per capita emissions 7 to 14 times lower than the EU, USA, or China by 2030. We argue that a fair and ambitious agreement for a 2 °C limit that would be globally inclusive and effective in the long term will require stronger mitigation than the goals currently proposed. Given such necessary and unprecedented mitigation and the current lack of availability of some key technologies, we suggest a new diplomatic effort directed at ensuring that the necessary technologies become available in the near future.

  5. MAX-DOAS measurements of shipping emissions

    NASA Astrophysics Data System (ADS)

    Seyler, André; Wittrock, Folkard; Kattner, Lisa; Mathieu-Üffing, Barbara; Peters, Enno; Richter, Andreas; Schmolke, Stefan; Theobald, Norbert; Burrows, John P.

    2015-04-01

    Air pollution from ships contributes to overall air quality problems and it has direct health effects on the population in particular in coastal regions, and in harbor cities. In order to reduce the emissions the International Maritime Organisation (IMO) have tightened the regulations for air pollution. E.g. Sulfur Emission Control Areas (SECA) have been introduced where the sulfur content of marine fuel is limited. Recently, on the 1st of January 2015, the allowed sulfur content of marine fuels inside Sulfur Emission Control Areas has been significantly decreased from 1.0% to 0.1%. However, up to now there is no regular monitoring system available to verify that ships are complying with the new regulations. Furthermore measurements of reactive trace gases in marine environments are in general sparse. The project MeSMarT (Measurements of shipping emissions in the marine troposphere, www.mesmart.de) has been established as a cooperation between the University of Bremen and the German Bundesamt für Seeschifffahrt und Hydrographie (Federal Maritime and Hydrographic Agency) with support of the Helmholtz Research Centre Geesthacht to estimate the influence of ship emissions on the chemistry of the atmospheric boundary layer and to establish a monitoring system for main shipping routes. Here we present MAX-DOAS observations of NO2 and SO2 carried out from two permanent sites close to the Elbe river (Wedel, Germany) and on the island Neuwerk close to the mouths of Elbe and Weser river since the year 2013. Mixing ratios of both trace gases have been retrieved using different approaches (pure geometric and taking into account the radiative transfer) and compared to in situ observations (see Kattner et al., Monitoring shipping fuel sulfur content regulations with in-situ measurements of shipping emissions). Furthermore, simple approaches have been used to calculate emission factors of NOx and SO2 for single ships.

  6. Interpretation of the results of statistical measurements. [search for basic probability model

    NASA Technical Reports Server (NTRS)

    Olshevskiy, V. V.

    1973-01-01

    For random processes, the calculated probability characteristic, and the measured statistical estimate are used in a quality functional, which defines the difference between the two functions. Based on the assumption that the statistical measurement procedure is organized so that the parameters for a selected model are optimized, it is shown that the interpretation of experimental research is a search for a basic probability model.

  7. LOW-CONCENTRATION NOX EMISSIONS MEASUREMENT

    EPA Science Inventory

    The paper gives results of a recent series of low-concentration nitrogen oxides (NOx) emission measurements, made by Midwest Research Institute (MRI) during U.S. EPA-sponsored Environmental Technology Verification (ETV) test of a NOx control system called Xonon (TM) Cool Combust...

  8. LOW-CONCENTRATION NOX EMISSIONS MEASUREMENT

    EPA Science Inventory

    The paper gives results of a recent series of low-concentration nitrogen oxides (NOx) emission measurements, made by Midwest Research Institute (MRI) during U.S. EPA-sponsored Environmental Technology Verification (ETV) test of a NOx control system called Xonon (TM) Cool Combust...

  9. Updated greenhouse gas and criteria air pollutant emission factors and their probability distribution functions for electricity generating units

    SciTech Connect

    Cai, H.; Wang, M.; Elgowainy, A.; Han, J.

    2012-07-06

    Greenhouse gas (CO{sub 2}, CH{sub 4} and N{sub 2}O, hereinafter GHG) and criteria air pollutant (CO, NO{sub x}, VOC, PM{sub 10}, PM{sub 2.5} and SO{sub x}, hereinafter CAP) emission factors for various types of power plants burning various fuels with different technologies are important upstream parameters for estimating life-cycle emissions associated with alternative vehicle/fuel systems in the transportation sector, especially electric vehicles. The emission factors are typically expressed in grams of GHG or CAP per kWh of electricity generated by a specific power generation technology. This document describes our approach for updating and expanding GHG and CAP emission factors in the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model developed at Argonne National Laboratory (see Wang 1999 and the GREET website at http://greet.es.anl.gov/main) for various power generation technologies. These GHG and CAP emissions are used to estimate the impact of electricity use by stationary and transportation applications on their fuel-cycle emissions. The electricity generation mixes and the fuel shares attributable to various combustion technologies at the national, regional and state levels are also updated in this document. The energy conversion efficiencies of electric generating units (EGUs) by fuel type and combustion technology are calculated on the basis of the lower heating values of each fuel, to be consistent with the basis used in GREET for transportation fuels. On the basis of the updated GHG and CAP emission factors and energy efficiencies of EGUs, the probability distribution functions (PDFs), which are functions that describe the relative likelihood for the emission factors and energy efficiencies as random variables to take on a given value by the integral of their own probability distributions, are updated using best-fit statistical curves to characterize the uncertainties associated with GHG and CAP emissions in life

  10. What the complex joint probabilities observed in weak measurements can tell us about quantum physics

    SciTech Connect

    Hofmann, Holger F.

    2014-12-04

    Quantummechanics does not permit joint measurements of non-commuting observables. However, it is possible to measure the weak value of a projection operator, followed by the precise measurement of a different property. The results can be interpreted as complex joint probabilities of the two non-commuting measurement outcomes. Significantly, it is possible to predict the outcome of completely different measurements by combining the joint probabilities of the initial state with complex conditional probabilities relating the new measurement to the possible combinations of measurement outcomes used in the characterization of the quantum state. We can therefore conclude that the complex conditional probabilities observed in weak measurements describe fundamental state-independent relations between non-commuting properties that represent the most fundamental form of universal laws in quantum physics.

  11. Emission Ratios from SCIAMACHY simultaneous measurements

    NASA Astrophysics Data System (ADS)

    Khlystova, Iryna; Richter, Andreas; Wittrock, Folkard; Burrows, John P.; Buchwitz, Michael; Bovensmann, Heinrich

    The spectra of reflected and backscattered solar radiation as measured by SCIAMACHY in nadir observation mode in the UV/visible/near-infrared/short-wave-infrared spectral region contain information on the vertical columns of numerous air pollutants and therefore provide a large-scale perspective on spacious and uncertain pollution sources like biomass burnings. It will be shown that under a number of reasonable assumptions we can obtain a quantitative charac-teristics of biomass burning emissions in terms of emission ratios (ER) using only the averages of the atmospheric gas columns retrieved from the space-based simultaneous measurements. Considering for example the SCIAMACHY carbon monoxide (CO), taken as a reference car-bon component, together with the SCIAMACHY formaldehyde (HCHO) and nitrogen dioxide (NO2) columns in the scope of a well established emission quantification method we calcu-late the emission ratios, CO/HCHO and CO/NO2, over large biomass burning events in 2004 (established with the help of the AATSR fire counts product). We show that the calculated ER values are in reasonable agreement with the values obtained locally over similar biomass burning events reported in the literature. In addition, we discuss the relatively large values over the boreal forest fires in Alaska and Siberia, where ER values from local measurements were not yet reported.

  12. “Comprehensive emission measurements from prescribed ...

    EPA Pesticide Factsheets

    Simultaneous aerial- and ground-based emission sampling was conducted during prescribed burns at Eglin Air Force Base in November 2012 on a short grass/shrub field and a pine forest. Cumulative emission samples for volatile organic comounds, elemental carbon, organic carbon, chlorinated dioxins and furans, and PM2.5 and continuous samples for black carbon, particle size, and CO2 were taken. Aerial instruments were lofted using a 5 m diameter, helium-filled aerostat that was maneuvered with two remotely-controlled tethers mounted on all-terrain vehicles. A parallel set of instruments on the ground made simultaneous measurements, allowing for a comparison of ground level versus elevated measurements. Ground instruments were supplemented by additional measurements of polycyclic aromatic hydrocarbons and particle aerosol absorption and light scattering. Raw biomass was also gathered on site and tested in a laboratory combustion facility using the same array of instruments. This work compares emissions derived from aerial and ground sampling as well as field and laboratory results. This abstract will likely be the first ever prescribed burn study to compare laboratory and field emission results with results from aerial and and ground sampling. As such it will inform sampling methods for future events and determine the ability of laboratory simulations to mimic events inthe field.

  13. Traffic accident and emission reduction through intermittent release measures for heavy fog weather

    NASA Astrophysics Data System (ADS)

    Shi, Jing; Tan, Jin-Hua

    2015-09-01

    Heavy fog weather can increase traffic accidents and lead to freeway closures which result in delays. This paper aims at exploring traffic accident and emission characteristics in heavy fog, as well as freeway intermittent release measures for heavy fog weather. A driving simulator experiment is conducted for obtaining driving behaviors in heavy fog. By proposing a multi-cell cellular automaton (CA) model based on the experimental data, the role of intermittent release measures on the reduction of traffic accidents and CO emissions is studied. The results show that, affected by heavy fog, when cellular occupancy ρ < 0.8, the probability of traffic accidents is much higher; and CO emissions increase significantly when ρ < 0.2. After an intermittent release measure is applied, the probability of traffic accidents and level of CO emissions become reasonable. Obviously, the measure can enhance traffic safety and reduce emissions.

  14. Infrared Emissivity Measurements of Building and Civil Engineering Materials: A New Device for Measuring Emissivity

    NASA Astrophysics Data System (ADS)

    Monchau, Jean-Pierre; Marchetti, Mario; Ibos, Laurent; Dumoulin, Jean; Feuillet, Vincent; Candau, Yves

    2014-10-01

    The knowledge of the infrared emissivity of materials used in buildings and civil engineering structures is useful for two specific approaches. First, quantitative diagnosis of buildings or civil engineering infrastructures by infrared thermography requires emissivity values in the spectral bandwidth of the camera used for measurements, in order to obtain accurate surface temperatures; for instance, emissivity in the band III domain is required when using cameras with uncooled detectors (such as micro-bolometer arrays). Second, setting up accurate thermal balances by numerical modeling requires the total emissivity value for a large wavelength domain; this is, for instance, the case for computing the road surface temperature to predict ice occurrence. Furthermore, periodical surveys of emissivity variations due to aging or soiling of surfaces could be useful in many situations such as thermal mapping of roads or building insulation diagnosis. The use of portable emissivity measurement devices is required for that purpose. A device using an indirect measurement method was previously developed in our lab; the method uses measurement of the reflectivity from a modulated IR source and requires calibration with a highly reflective surface. However, that device uses a low-frequency, thermal modulation well adapted to laboratory measurements but unfit for fast and in situ measurements. Therefore, a new, portable system which retains the principle of an indirect measurement but uses a faster-frequency, mechanical modulation more appropriate to outdoor measurements was developed. Both devices allow measurements in the broad m to m) and narrow m to m) bands. Experiments were performed on a large number of materials commonly used in buildings and civil engineering structures. The final objective of this work is to build a database of emissivity of these materials. A comparison of laboratory and on-site measurements of emissivity values obtained in both spectral bands will be

  15. OLED emission zone measurement with high accuracy

    NASA Astrophysics Data System (ADS)

    Danz, N.; MacCiarnain, R.; Michaelis, D.; Wehlus, T.; Rausch, A. F.; Wächter, C. A.; Reusch, T. C. G.

    2013-09-01

    Highly efficient state of the art organic light-emitting diodes (OLED) comprise thin emitting layers with thicknesses in the order of 10 nm. The spatial distribution of the photon generation rate, i.e. the profile of the emission zone, inside these layers is of interest for both device efficiency analysis and characterization of charge recombination processes. It can be accessed experimentally by reverse simulation of far-field emission pattern measurements. Such a far-field pattern is the sum of individual emission patterns associated with the corresponding positions inside the active layer. Based on rigorous electromagnetic theory the relation between far-field pattern and emission zone is modeled as a linear problem. This enables a mathematical analysis to be applied to the cases of single and double emitting layers in the OLED stack as well as to pattern measurements in air or inside the substrate. From the results, guidelines for optimum emitter - cathode separation and for selecting the best experimental approach are obtained. Limits for the maximum spatial resolution can be derived.

  16. A New Large Echelle Spectrometer for Measuring Atomic Transition Probabilities of Fe-group Ions

    NASA Astrophysics Data System (ADS)

    Wood, Michael; Lawler, J. E.

    2012-01-01

    Accurate atomic transition probabilities for weak lines connected to the ground and low metastable levels of Fe-group ions are needed for elemental abundance studies on metal-poor stars. Metal-poor stars represent the oldest observable stellar generation and offer a direct probe into the early history of nucleosynthesis and the chemical evolution of the Galaxy. Unexplained trends in relative Fe-group abundances, such as [Co/Cr], as a function of metallicity, or [Fe/H], have been observed. These trends may result from a breakdown in the local thermodynamic equilibrium (LTE) approximation used in traditional photosphere models underlying elemental abundance determinations. The ground and low metastable levels of Fe-group ions contain most of the Fe-group material in a stellar photosphere, and thus second spectra lines with low E.P.s are essentially immune to non-LTE effects. To improve lab data on important Fe-group lines we have developed a novel instrument based on a 3 meter focal length vacuum echelle spectrograph combined with an aberration corrected cross dispersion system and a UV sensitive CCD array. This spectrometer is capable of recording both emission and absorption spectra with high resolving power, very broad wavelength coverage, and high signal-to-noise. It is also free from the multiplex noise of a FTS, making it ideally suited for measuring branching fractions of very weak lines. The combination of very accurate branching fractions with radiative lifetimes from time-resolved laser-induced fluorescence will yield accurate absolute transition probabilities of weak second spectra lines with low E.P.s for the Fe-group elements. Instrument design and preliminary results will be presented. Supported by NASA Grant NNX09AL13G.

  17. An Inverse Problem for a Class of Conditional Probability Measure-Dependent Evolution Equations.

    PubMed

    Mirzaev, Inom; Byrne, Erin C; Bortz, David M

    2016-01-01

    We investigate the inverse problem of identifying a conditional probability measure in measure-dependent evolution equations arising in size-structured population modeling. We formulate the inverse problem as a least squares problem for the probability measure estimation. Using the Prohorov metric framework, we prove existence and consistency of the least squares estimates and outline a discretization scheme for approximating a conditional probability measure. For this scheme, we prove general method stability. The work is motivated by Partial Differential Equation (PDE) models of flocculation for which the shape of the post-fragmentation conditional probability measure greatly impacts the solution dynamics. To illustrate our methodology, we apply the theory to a particular PDE model that arises in the study of population dynamics for flocculating bacterial aggregates in suspension, and provide numerical evidence for the utility of the approach.

  18. An inverse problem for a class of conditional probability measure-dependent evolution equations

    NASA Astrophysics Data System (ADS)

    Mirzaev, Inom; Byrne, Erin C.; Bortz, David M.

    2016-09-01

    We investigate the inverse problem of identifying a conditional probability measure in measure-dependent evolution equations arising in size-structured population modeling. We formulate the inverse problem as a least squares problem for the probability measure estimation. Using the Prohorov metric framework, we prove existence and consistency of the least squares estimates and outline a discretization scheme for approximating a conditional probability measure. For this scheme, we prove general method stability. The work is motivated by partial differential equation models of flocculation for which the shape of the post-fragmentation conditional probability measure greatly impacts the solution dynamics. To illustrate our methodology, we apply the theory to a particular PDE model that arises in the study of population dynamics for flocculating bacterial aggregates in suspension, and provide numerical evidence for the utility of the approach.

  19. Field measurement of diesel particulate matter emissions.

    PubMed

    Volkwein, Jon C; Mischler, Steven E; Davies, Brian; Ellis, Clive

    2008-03-01

    A primary means to reduce environmental levels of diesel particulate matter (DPM) exposure to miners is to reduce the amount of DPM emission from the engine. A quick and economic method to estimate engine particulate emission levels has been developed. The method relies on the measurement of pressure increase across a filter element that is briefly used to collect a DPM sample directly from the engine exhaust. The method has been refined with the inclusion of an annular aqueous denuder to the tube which permits dry filter samples to be obtained without addition of dilution air. Tailpipe filter samples may then be directly collected in hot and water-supersaturated exhaust gas flows from water bath-cooled coal mine engines without the need for dilution air. Measurement of a differential pressure (DP) increase with time has been related to the mass of elemental carbon (EC) on the filter. Results for laboratory and field measurements of the method showed agreement between DP increase and EC collected on the filter with R(2) values >0.86. The relative standard deviation from replicate samples of DP and EC was 0.16 and 0.11, respectively. The method may also have applications beyond mining, where qualitative evaluation of engine emissions is desirable to determine if engine or control technology maintenance may be required.

  20. Understanding Coronal Heating with Emission Measure Distributions

    NASA Technical Reports Server (NTRS)

    Klimchik, James A.; Tripathi, Durgesh; Bradshaw, Stephen J.; Mason, Helen E.

    2011-01-01

    It is widely believed that the cross-field spatial scale of coronal heating is small, so that the fundamental plasma structures (loop strands) are spatially unresolved. We therefore must appeal to diagnostic techniques that are not strongly affected by spatial averaging. One valuable observable is the emission measure distribution, EM(T), which indicates how much material is present at each temperature. Using data from the Extreme-ultraviolet Imaging Spectrograph on the Hinode mission, we have determined emission measure distributions in the cores of two active regions. The distributions have power law slopes of approximately 2.4 coolward of the peak. We compare these slopes, as well as the amount of emission measure at very high temperature, with the predictions of a series of models. The models assume impulsive heating (nanoflares) in unresolved strands and take full account of non equilibrium ionization. A variety of nanoflare properties and initial conditions are considered. We also comment on the selection of spectral lines for upcoming missions like Solar Orbiter.

  1. Standardization and measurement of gamma-ray probability per decay of 177Lu.

    PubMed

    Dias, Mauro S; Silva, Fabrício F V; Koskinas, Marina F

    2010-01-01

    The procedure followed by the Nuclear Metrology Laboratory (LMN), at the Nuclear and Energy Research Institute (IPEN), for the primary standardization of (177)Lu is described. This radionuclide is widely used in radiopharmacy due to its convenient half-life and emitted beta ray energies. The (177)Lu solution was supplied during an international comparison sponsored by BIPM in 2009 and the primary standardization has been accomplished by the 4pibeta-gamma coincidence method using a proportional counter in 4pi geometry coupled with two NaI(Tl) scintillation counters. The beta efficiency was varied by placing Collodion and aluminum absorbers over and under the radioactive source. The (177)Lu calibrated sources were also measured in a previously calibrated HPGe spectrometer, in order to obtain the emission probability per decay for the selected gamma-ray transitions. The experimental extrapolation curves were also compared with Monte Carlo simulations by means of code ESQUEMA developed at the LMN. Copyright 2009 Elsevier Ltd. All rights reserved.

  2. Investigation of the 238U(d ,p ) surrogate reaction via the simultaneous measurement of γ -decay and fission probabilities

    NASA Astrophysics Data System (ADS)

    Ducasse, Q.; Jurado, B.; Aïche, M.; Marini, P.; Mathieu, L.; Görgen, A.; Guttormsen, M.; Larsen, A. C.; Tornyi, T.; Wilson, J. N.; Barreau, G.; Boutoux, G.; Czajkowski, S.; Giacoppo, F.; Gunsing, F.; Hagen, T. W.; Lebois, M.; Lei, J.; Méot, V.; Morillon, B.; Moro, A. M.; Renstrøm, T.; Roig, O.; Rose, S. J.; Sérot, O.; Siem, S.; Tsekhanovich, I.; Tveten, G. M.; Wiedeking, M.

    2016-08-01

    We investigated the 238U(d ,p ) reaction as a surrogate for the n +238U reaction. For this purpose we measured for the first time the γ -decay and fission probabilities of *239U simultaneously and compared them to the corresponding neutron-induced data. We present the details of the procedure to infer the decay probabilities, as well as a thorough uncertainty analysis, including parameter correlations. Calculations based on the continuum-discretized coupled-channels method and the distorted-wave Born approximation (DWBA) were used to correct our data from detected protons originating from elastic and inelastic deuteron breakup. In the region where fission and γ emission compete, the corrected fission probability is in agreement with neutron-induced data, whereas the γ -decay probability is much higher than the neutron-induced data. We have performed calculations of the decay probabilities with the statistical model and of the average angular momentum populated in the 238U(d ,p ) reaction with the DWBA to interpret these results.

  3. Measuring soot particles from automotive exhaust emissions

    NASA Astrophysics Data System (ADS)

    Andres, Hanspeter; Lüönd, Felix; Schlatter, Jürg; Auderset, Kevin; Jordan-Gerkens, Anke; Nowak, Andreas; Ebert, Volker; Buhr, Egbert; Klein, Tobias; Tuch, Thomas; Wiedensohler, Alfred; Mamakos, Athanasios; Riccobono, Francesco; Discher, Kai; Högström, Richard; Yli-Ojanperä, Jaakko; Quincey, Paul

    2014-08-01

    The European Metrology Research Programme participating countries and the European Union jointly fund a three year project to address the need of the automotive industry for a metrological sound base for exhaust measurements. The collaborative work on particle emissions involves five European National Metrology Institutes, the Tampere University of Technology, the Joint Research Centre for Energy and Transport and the Leibniz Institute for Tropospheric Research. On one hand, a particle number and size standard for soot particles is aimed for. Eventually this will allow the partners to provide accurate and comparable calibrations of measurement instruments for the type approval of Euro 5b and Euro 6 vehicles. Calibration aerosols of combustion particles, silver and graphite proof partially suitable. Yet, a consensus choice together with instrument manufactures is pending as the aerosol choice considerably affects the number concentration measurement. Furthermore, the consortium issued consistent requirements for novel measuring instruments foreseen to replace today's opacimeters in regulatory periodic emission controls of soot and compared them with European legislative requirements. Four partners are conducting a metrological validation of prototype measurement instruments. The novel instruments base on light scattering, electrical, ionisation chamber and diffusion charging sensors and will be tested at low and high particle concentrations. Results shall allow manufacturers to further improve their instruments to comply with legal requirements.

  4. Nonorthogonal projective positive-operator-value measurement of photon polarization states with unit probability of success

    SciTech Connect

    Ahnert, S.E.; Payne, M.C.

    2004-01-01

    In this paper we describe a scheme for performing a nonorthogonal projective positive-operator-value measurement of any arbitrary single-photon polarization input state with unit probability of success. While this probability is reached in the limit of infinite cycles of states through the apparatus, only one actual physical setup is required for a feasible implementation. Specifically, our setup implements a set of three nonorthogonal measurement operators at angles of 120 deg. to each other.

  5. Determination of the 121Te gamma emission probabilities associated with the production process of radiopharmaceutical NaI[123I

    NASA Astrophysics Data System (ADS)

    de Araújo, M. T. F.; Poledna, R.; Delgado, J. U.; de Almeida, M. C. M.; Lopes, R. T.; Silva, R. L.; Cagido, A. C. F.

    2016-07-01

    The 123I is widely used in radiodiagnostic procedures in nuclear medicine. According to Pharmacopoeia care should be taken during its production process, since radionuclidic impurities may be generated. The 121Te is an impurity that arises during the 123I production and determining their gamma emission probabilities (Pγ) is important in order to obtain more information about its decay. Activities were also obtained by absolute standardization using the sum-peak method and these values were compared to the efficiency curve method.

  6. β-decay half-lives and β-delayed neutron emission probabilities of nuclei in the region A≲110, relevant for the r process

    NASA Astrophysics Data System (ADS)

    Pereira, J.; Hennrich, S.; Aprahamian, A.; Arndt, O.; Becerril, A.; Elliot, T.; Estrade, A.; Galaviz, D.; Kessler, R.; Kratz, K.-L.; Lorusso, G.; Mantica, P. F.; Matos, M.; Möller, P.; Montes, F.; Pfeiffer, B.; Schatz, H.; Schertz, F.; Schnorrenberger, L.; Smith, E.; Stolz, A.; Quinn, M.; Walters, W. B.; Wöhr, A.

    2009-03-01

    Measurements of β-decay properties of A≲110 r-process nuclei have been completed at the National Superconducting Cyclotron Laboratory at Michigan State University. β-decay half-lives for Y105, Zr106,107, and Mo111, along with β-delayed neutron emission probabilities of Y104, Mo109,110 and upper limits for Y105, Zr103-107, and Mo108,111 have been measured for the first time. Studies on the basis of the quasi-random-phase approximation are used to analyze the ground-state deformation of these nuclei.

  7. {beta}-decay half-lives and {beta}-delayed neutron emission probabilities of nuclei in the region A < or approx. 110, relevant for the r process

    SciTech Connect

    Pereira, J.; Galaviz, D.; Matos, M.; Montes, F.; Hennrich, S.; Kessler, R.; Schertz, F.; Aprahamian, A.; Quinn, M.; Woehr, A.; Arndt, O.; Pfeiffer, B.; Becerril, A.; Elliot, T.; Estrade, A.; Lorusso, G.; Schatz, H.; Kratz, K.-L.; Mantica, P. F.; Moeller, P.

    2009-03-15

    Measurements of {beta}-decay properties of A < or approx. 110 r-process nuclei have been completed at the National Superconducting Cyclotron Laboratory at Michigan State University. {beta}-decay half-lives for {sup 105}Y, {sup 106,107}Zr, and {sup 111}Mo, along with {beta}-delayed neutron emission probabilities of {sup 104}Y, {sup 109,110}Mo and upper limits for {sup 105}Y, {sup 103-107}Zr, and {sup 108,111}Mo have been measured for the first time. Studies on the basis of the quasi-random-phase approximation are used to analyze the ground-state deformation of these nuclei.

  8. Achromatic Emission Velocity Measurements in Luminous Flows

    NASA Technical Reports Server (NTRS)

    Schneider, S. J.; Fulghum, S. F.; Rostler, P. S.

    1997-01-01

    A new velocity measurement instrument for luminous flows was developed by Science Research Laboratory for NASA. The SIEVE (Segmented Image Emission VElocimeter) instrument uses broadband light emitted by the flow for the velocity measurement. This differs from other velocimetry techniques in that it does not depend on laser illumination and/or light scattering from particles in the flow. The SIEVE is a passive, non-intrusive diagnostic. By moving and adjusting the imaging optics, the SIEVE can provide three-dimensional mapping of a flow field and determine turbulence scale size. A SIEVE instrument was demonstrated on an illuminated rotating disk to evaluate instrument response and noise and on an oxy-acetylene torch to measure flame velocities. The luminous flow in rocket combustors and plumes is an ideal subject for the SIEVE velocity measurement technique.

  9. Atomic Oscillator Strengths by Emission Spectroscopy and Lifetime Measurements

    NASA Astrophysics Data System (ADS)

    Wiese, W. L.; Griesmann, U.; Kling, R.; Musielok, J.

    2002-11-01

    Over the last seven years, we have carried out numerous oscillator strength measurements for some light and medium heavy elements (Musielok et al. 1995, 1996, 1997, 1999, 2000; Veres & Wiese 1996; Griesmann et al. 1997; Bridges & Wiese 1998; Kling et al. 2001; Kling & Gries- mann 2000; Bridges & Wiese to be published). Most recently we have determined numerous transitions of Mu II (Kling et al. 2001; Kling & Griesmann 2000) and are now working on Cl I (Bridges & Wiese to be published). See the summary statement at the end of the text. For the emission measurements, we have applied either a high-current wall-stabilized arc (described for example, in Musielok et al. (1999)), or a high-current hollow cathode, or a Penning discharge. The latter two sources were used for branching ratio measurements from common upper 1ev- els, while the wall-stabilized arc was operated at atmospheric pressure under the condition of partial local thermodynamic equilibrium, which allows the measurement of relative transition probabilities. Absolute data were obtained by combining the emission results with lifetime data measured by other research groups, especially the University of Hannover, with which we have closely collaborated. This group uses the laser induced fluorescence (LIF) technique. Our emission spectra were recorded for the light elements with a 2 m grating spectrometer, or, for Mu II, with an FT 700 vacuum ultraviolet Fourier transform spectrometer. The radiometric calibration was carried out with a tungsten strip lamp for the visible part of the spectrum and with a deuterium lamp for the ultraviolet. All measurements were made under optically thin conditions, which was checked by doubling the path length with a focusing mirror setup. Typical uncertainties of the measured oscillator strengths are estimated to be in the range 15%-20% (one-standard deviation). However, discrepancies with advanced atomic structure theories are sometimes much larger. In Tables 1-3 and Fig. 1, we

  10. Measuring acoustic emissions in an avalanche slope

    NASA Astrophysics Data System (ADS)

    Reiweger, Ingrid; Schweizer, Jürg

    2014-05-01

    Measurements of acoustic emissions are a common technique for monitoring damage and predicting imminent failure of a material. Within natural hazards it has already been used to successfully predict the break-off of a hanging glacier. To explore the applicability of the acoustic emission (AE) technique for avalanche prediction, we installed two acoustic sensors (with 30 kHz and 60 kHz resonance frequency) in an avalanche prone slope at the Mittelgrat in the Parsenn ski area above Davos, Switzerland. The slope is north-east facing, frequently wind loaded, and approximately 35° steep. The AE signals - in particular the event energy and waiting time distributions - were compared with slope stability. The latter was determined by observing avalanche activity. The results of two winter's measurements yielded that the exponent β of the inverse cumulative distribution of event energy showed a significant drop (from a value of 3.5 to roughly 2.5) at very unstable conditions, i.e. on the three days during our measurement periods when spontaneous avalanches released on our study slope.

  11. Measured emissivities of uranium and tungsten plasmas.

    NASA Technical Reports Server (NTRS)

    Miller, M. H.

    1971-01-01

    Uranium and tungsten absorption coefficients between 2,500-8500 A were measured as functions of thermodynamic variables. A gas-driven shock tube was used to obtain plasma temperatures, heavy metal partial pressures, and total pressures in the ranges 7,000-12,000 K, 0.02-1.0 atm, and 3.0-48 atm, respectively. Emission and absorption data were recorded both photographically and photoelectrically. The spectral distributions, thermal dependence and line-to-continuum ratios of the uranium and tungsten radiation differ distinctly. The uranium data are compared with theoretical predictions and with results from other experiments.

  12. Measured emissivities of uranium and tungsten plasmas.

    NASA Technical Reports Server (NTRS)

    Miller, M. H.

    1971-01-01

    Uranium and tungsten absorption coefficients between 2,500-8500 A were measured as functions of thermodynamic variables. A gas-driven shock tube was used to obtain plasma temperatures, heavy metal partial pressures, and total pressures in the ranges 7,000-12,000 K, 0.02-1.0 atm, and 3.0-48 atm, respectively. Emission and absorption data were recorded both photographically and photoelectrically. The spectral distributions, thermal dependence and line-to-continuum ratios of the uranium and tungsten radiation differ distinctly. The uranium data are compared with theoretical predictions and with results from other experiments.

  13. Investigating and improving student understanding of the probability distributions for measuring physical observables in quantum mechanics

    NASA Astrophysics Data System (ADS)

    Marshman, Emily; Singh, Chandralekha

    2017-03-01

    A solid grasp of the probability distributions for measuring physical observables is central to connecting the quantum formalism to measurements. However, students often struggle with the probability distributions of measurement outcomes for an observable and have difficulty expressing this concept in different representations. Here we first describe the difficulties that upper-level undergraduate and PhD students have with the probability distributions for measuring physical observables in quantum mechanics. We then discuss how student difficulties found in written surveys and individual interviews were used as a guide in the development of a quantum interactive learning tutorial (QuILT) to help students develop a good grasp of the probability distributions of measurement outcomes for physical observables. The QuILT strives to help students become proficient in expressing the probability distributions for the measurement of physical observables in Dirac notation and in the position representation and be able to convert from Dirac notation to position representation and vice versa. We describe the development and evaluation of the QuILT and findings about the effectiveness of the QuILT from in-class evaluations.

  14. Subjects of discussion in radiated emission measurements above 1 GHz

    NASA Astrophysics Data System (ADS)

    Battermann, S.; Garbe, H.

    2008-05-01

    Some emission and susceptibility EMC standards already require measurements above 1 GHz or test site validations (IEC 2006, CISPR 2006). A simple assignment of the established measurement methods below 1 GHz to the frequency range above 1 GHz bears some risks. The ratio between the physical size of the equipment under test (EUT) and the wave-length rises with frequency. This increases the electrical size of the EUT. The directivity may become larger and the radiation pattern of the EUT is getting more complex which reduces the probability to detect the maximum emission with a simple planar cut scan. To analyse these effects in more detail this paper shows radiation characteristics of an exemplary EUT. The influence of a receiving antenna height scan and the angle increment of the turntable scan on the detection of the maximum of the electrical field strength will be discussed. As a result some ideas will be given to reduce the measurement time but keeping the reliability of the measurement results constant.

  15. Measuring attention using the Posner cuing paradigm: the role of across and within trial target probabilities

    PubMed Central

    Hayward, Dana A.; Ristic, Jelena

    2013-01-01

    Numerous studies conducted within the recent decades have utilized the Posner cuing paradigm for eliciting, measuring, and theoretically characterizing attentional orienting. However, the data from recent studies suggest that the Posner cuing task might not provide an unambiguous measure of attention, as reflexive spatial orienting has been found to interact with extraneous processes engaged by the task's typical structure, i.e., the probability of target presence across trials, which affects tonic alertness, and the probability of target presence within trials, which affects voluntary temporal preparation. To understand the contribution of each of these two processes to the measurement of attentional orienting we assessed their individual and combined effects on reflexive attention elicited by a spatially nonpredictive peripheral cue. Our results revealed that the magnitude of spatial orienting was modulated by joint changes in the global probability of target presence across trials and the local probability of target presence within trials, while the time course of spatial orienting was susceptible to changes in the probability of target presence across trials. These data thus raise important questions about the choice of task parameters within the Posner cuing paradigm and their role in both the measurement and theoretical attributions of the observed attentional effects. PMID:23730280

  16. Evaluation of mobile emissions contributions to Mexico City's emissions inventory using on-road and cross-road emission measurements and ambient data

    NASA Astrophysics Data System (ADS)

    Zavala, M.; Herndon, S. C.; Wood, E. C.; Onasch, T. B.; Knighton, W. B.; Marr, L. C.; Kolb, C. E.; Molina, L. T.

    2009-09-01

    Mobile emissions represent a significant fraction of the total anthropogenic emissions burden in the Mexico City Metropolitan Area (MCMA) and, therefore, it is crucial to use top-down techniques informed by on-road exhaust measurements to evaluate and improve traditional bottom-up official emissions inventory (EI) for the city. We present the measurements of on-road fleet-average emission factors obtained using the Aerodyne mobile laboratory in the MCMA in March 2006 as part of the MILAGRO/MCMA-2006 field campaign. A comparison of our on-road emission measurements with those obtained in 2003 using essentially the same measurement techniques and analysis methods indicates that, in the three year span, NO emission factors remain within the measured variability ranges whereas emission factors of aldehydes and aromatics species were reduced for all sampled driving conditions. We use a top-down fuel-based approach to evaluate the mobile emissions from the gasoline fleet estimated in the bottom-up official 2006 MCMA mobile sources. Within the range of measurement uncertainties, we found probable slight overpredictions of mean EI estimates on the order of 20-28% for CO and 14-20% for NO. However, we identify a probable EI discrepancy of VOC mobile emissions between 1.4 and 1.9; although estimated benzene and toluene mobile emissions in the inventory seem to be well within the uncertainties of the corresponding emissions estimates. Aldehydes mobile emissions in the inventory, however, seem to be underpredicted by factors of 3 for HCHO and 2 for CH3CHO. Our on-road measurement-based estimate of annual emissions of organic mass from PM1 particles suggests a severe underprediction (larger than a factor of 4) of PM2.5 mobile emissions in the inventory. Analyses of ambient CO, NOx and CO/NOx concentration trends in the MCMA indicate that the early morning ambient CO/NOx ratio has decreased at a rate of about 1.9 ppm/ppm/year over the last two decades due to reductions in CO

  17. Evaluation of mobile emissions contributions to Mexico City's emissions inventory using on-road and cross-road emission measurements and ambient data

    NASA Astrophysics Data System (ADS)

    Zavala, M.; Herndon, S. C.; Wood, E. C.; Onasch, T. B.; Knighton, W. B.; Kolb, C. E.; Molina, L. T.

    2009-03-01

    Mobile emissions represent a significant fraction of the total anthropogenic emissions burden in the Mexico City Metropolitan Area (MCMA) and, therefore, it is crucial to use top-down techniques informed by on-road exhaust measurements to evaluate and improve traditional bottom-up official emissions inventory (EI) for the city. We present the measurements of on-road fleet-average emission factors obtained using the Aerodyne mobile laboratory in the MCMA in March 2006 as part of the MILAGRO/MCMA-2006 field campaign. A comparison of our on-road emission measurements with those obtained in 2003 using essentially the same measurement techniques and analysis methods indicates that, in the three year span, NO emission factors remain within the measured variability ranges whereas emission factors of aldehydes and aromatics species were reduced for all sampled driving conditions. We use a top-down fuel-based approach to evaluate the mobile emissions from the gasoline fleet estimated in the bottom-up official 2006 MCMA mobile sources. Within the range of measurement uncertainties, we found probable slight overpredictions of mean EI estimates on the order of 20-28% for CO and 14-20% for NO. However, we identify a probable EI underprediction of VOC mobile emissions between 1.4 and 1.9; although estimated benzene and toluene mobile emissions in the inventory seem to be well within the uncertainties of the corresponding emissions estimates. Aldehydes mobile emissions in the inventory, however, seem to be under predicted by factors of 3 for HCHO and 2 for CH3CHO. Our on-road measurement based estimate of annual emissions of organic mass from PM1 particles suggests a severe underprediction (larger than a factor of 4) of PM2.5 mobile emissions in the inventory. Analyses of ambient CO, NOx and CO/NOx concentration trends in the MCMA indicate that the early morning ambient CO/NOx ratio has decreased at a rate of about 1.9 ppm/ppm/year over the last two decades and that the decrease

  18. Approximation by Absolutely Continuous Invariant Measures of Iterated Function Systems with Place-Dependent Probabilities

    NASA Astrophysics Data System (ADS)

    Islam, Md Shafiqul; Chandler, Stephen

    2015-10-01

    Let S be the attractor (fractal) of a contractive iterated function system (IFS) with place-dependent probabilities. An IFS with place-dependent probabilities is a random map T = {τ1(x),τ2(x),…,τK(x); p1(x),p2(x),…,pK(x)}, where the probabilities p1(x),p2(x),…,pK(x) of switching from one transformation to another are functions of positions, that is, at each step, the random map T moves the point x to τk(x) with probability pk(x). If the random map T has a unique invariant measure μ, then the support of μ is the attractor S. For a bounded region X ⊆ ℝN, we prove the existence of a sequence {T0,n∗} of IFSs with place-dependent probabilities whose invariant measures {μn} are absolutely continuous with respect to Lebesgue measure. Moreover, if X is a compact metric space, we prove that μn converges weakly to μ as n →∞. We present examples with computations.

  19. Measurement of gas and aerosol agricultural emissions

    USDA-ARS?s Scientific Manuscript database

    Studies of air quality indicate that agricultural emissions may impact particulate mass concentrations through both primary and secondary processes. Agriculture impacts can include primary dust emission, on-facility combustion from vehicles or seasonal field burning, and gaseous emissions from waste...

  20. 40 CFR 92.127 - Emission measurement accuracy.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Emission measurement accuracy. 92.127 Section 92.127 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... Emission measurement accuracy. (a) Good engineering practice dictates that exhaust emission sample...

  1. Mercury Emission Measurement at a CFB Plant

    SciTech Connect

    John Pavlish; Jeffrey Thompson; Lucinda Hamre

    2009-02-28

    In response to pending regulation to control mercury emissions in the United States and Canada, several projects have been conducted to perform accurate mass balances at pulverized coal (pc)-fired utilities. Part of the mercury mass balance always includes total gaseous mercury as well as a determination of the speciation of the mercury emissions and a concentration bound to the particulate matter. This information then becomes useful in applying mercury control strategies, since the elemental mercury has traditionally been difficult to control by most technologies. In this instance, oxidation technologies have proven most beneficial for increased capture. Despite many years of mercury measurement and control projects at pc-fired units, far less work has been done on circulating fluidized-bed (CFB) units, which are able to combust a variety of feedstocks, including cofiring coal with biomass. Indeed, these units have proven to be more problematic because it is very difficult to obtain a reliable mercury mass balance. These units tend to have very different temperature profiles than pc-fired utility boilers. The flexibility of CFB units also tends to be an issue when a mercury balance is determined, since the mercury inputs to the system come from the bed material and a variety of fuels, which can have quite variable chemistry, especially for mercury. In addition, as an integral part of the CFB operation, the system employs a feedback loop to circulate the bed material through the combustor and the solids collection system (the primary cyclone), thereby subjecting particulate-bound metals to higher temperatures again. Despite these issues, CFB boilers generally emit very little mercury and show good native capture. The Energy & Environmental Research Center is carrying out this project for Metso Power in order to characterize the fate of mercury across the unit at Rosebud Plant, an industrial user of CFB technology from Metso. Appropriate solids were collected, and

  2. Linear Polarization Measurements of Chromospheric Emission Lines

    NASA Technical Reports Server (NTRS)

    Sheeley, N. R., Jr.; Keller, C. U.

    2003-01-01

    We have used the Zurich Imaging Stokes Polarimeter (ZIMPOL I) with the McMath-Pierce 1.5 m main telescope on Kitt Peak to obtain linear polarization measurements of the off-limb chromosphere with a sensitivity better than 1 x 10(exp -5). We found that the off-disk observations require a combination of good seeing (to show the emission lines) and a clean heliostat (to avoid contamination by scattered light from the Sun's disk). When these conditions were met, we obtained the following principal results: 1. Sometimes self-reversed emission lines of neutral and singly ionized metals showed linear polarization caused by the transverse Zeeman effect or by instrumental cross talk from the longitudinal Zeeman effect in chromospheric magnetic fields. Otherwise, these lines tended to depolarize the scattered continuum radiation by amounts that ranged up to 0.2%. 2. Lines previously known to show scattering polarization just inside the limb (such as the Na I lambda5889 D2 and the He I lambda5876 D3 lines) showed even more polarization above the Sun's limb, with values approaching 0.7%. 3. The O I triplet at lambda7772, lambda7774, and lambda7775 showed a range of polarizations. The lambda7775 line, whose maximum intrinsic polarizability, P(sub max), is less than 1%, revealed mainly Zeeman contributions from chromospheric magnetic fields. However, the more sensitive lambda7772 (P(sub max) = 19%) and lambda7774 (P(sub max) = 29%) lines had relatively strong scattering polarizations of approximately 0.3% in addition to their Zeeman polarizations. At times of good seeing, the polarization spectra resolve into fine structures that seem to be chromospheric spicules.

  3. Linear Polarization Measurements of Chromospheric Emission Lines

    NASA Technical Reports Server (NTRS)

    Sheeley, N. R., Jr.; Keller, C. U.

    2003-01-01

    We have used the Zurich Imaging Stokes Polarimeter (ZIMPOL I) with the McMath-Pierce 1.5 m main telescope on Kitt Peak to obtain linear polarization measurements of the off-limb chromosphere with a sensitivity better than 1 x 10(exp -5). We found that the off-disk observations require a combination of good seeing (to show the emission lines) and a clean heliostat (to avoid contamination by scattered light from the Sun's disk). When these conditions were met, we obtained the following principal results: 1. Sometimes self-reversed emission lines of neutral and singly ionized metals showed linear polarization caused by the transverse Zeeman effect or by instrumental cross talk from the longitudinal Zeeman effect in chromospheric magnetic fields. Otherwise, these lines tended to depolarize the scattered continuum radiation by amounts that ranged up to 0.2%. 2. Lines previously known to show scattering polarization just inside the limb (such as the Na I lambda5889 D2 and the He I lambda5876 D3 lines) showed even more polarization above the Sun's limb, with values approaching 0.7%. 3. The O I triplet at lambda7772, lambda7774, and lambda7775 showed a range of polarizations. The lambda7775 line, whose maximum intrinsic polarizability, P(sub max), is less than 1%, revealed mainly Zeeman contributions from chromospheric magnetic fields. However, the more sensitive lambda7772 (P(sub max) = 19%) and lambda7774 (P(sub max) = 29%) lines had relatively strong scattering polarizations of approximately 0.3% in addition to their Zeeman polarizations. At times of good seeing, the polarization spectra resolve into fine structures that seem to be chromospheric spicules.

  4. Precise determination of photon emission probabilities for the main X- and gamma-rays of 226Ra in equilibrium with daughters.

    PubMed

    Morel, J; Sepman, S; Rasko, M; Terechtchenko, E; Delgado, J U

    2004-01-01

    Within the context of a joint project between VNIIM (D.I. Mendeleyev Institute for Metrology) and LNHB (Laboratoire National Henri Becquerel), special 226Ra sources were prepared by VNIIM in order to determine as accurately as possible the absolute photon emission probabilities for the main X- and gamma-rays following the decay of 226Ra and daughters. The main purpose of this work was to supplement a previous joint study by Laboratorio Nacional de Metrologia das Radiaçoes Ionizantes (LNMRI) and LNHB to determine their relative values. Some specific point sources were produced for alpha-spectrometry measurements that were undertaken at VNIIM and also for gamma-ray spectrometry studies at VNIIM and LNHB. The 226Ra activity for the gamma-spectrometric sources was measured relative to the alpha-spectrometric sources by comparing the counts of the main gamma-rays. The total uncertainty of the activity for these sources was 0.2% (k = 1). Using calibrated germanium detectors, several X- and gamma-ray spectra were analyzed to determine the absolute photon emission probabilities of 226Ra in radioactive equilibrium with daughters. The results are presented and compared to other published values.

  5. Quantization of probability distributions under norm-based distortion measures II: Self-similar distributions

    NASA Astrophysics Data System (ADS)

    Delattre, Sylvain; Graf, Siegfried; Luschgy, Harald; Pages, Gilles

    2006-06-01

    For a probability measure P on and consider where the infimum is taken over all subsets [alpha] of with card([alpha])[less-than-or-equals, slant]n and V is a nondecreasing function. Under certain conditions on V, we derive the precise n-asymptotics of en for self-similar distributions P and we find the asymptotic performance of optimal quantizers using weighted empirical measures.

  6. Measurements of gas hydrate formation probability distributions on a quasi-free water droplet

    NASA Astrophysics Data System (ADS)

    Maeda, Nobuo

    2014-06-01

    A High Pressure Automated Lag Time Apparatus (HP-ALTA) can measure gas hydrate formation probability distributions from water in a glass sample cell. In an HP-ALTA gas hydrate formation originates near the edges of the sample cell and gas hydrate films subsequently grow across the water-guest gas interface. It would ideally be desirable to be able to measure gas hydrate formation probability distributions of a single water droplet or mist that is freely levitating in a guest gas, but this is technically challenging. The next best option is to let a water droplet sit on top of a denser, immiscible, inert, and wall-wetting hydrophobic liquid to avoid contact of a water droplet with the solid walls. Here we report the development of a second generation HP-ALTA which can measure gas hydrate formation probability distributions of a water droplet which sits on a perfluorocarbon oil in a container that is coated with 1H,1H,2H,2H-Perfluorodecyltriethoxysilane. It was found that the gas hydrate formation probability distributions of such a quasi-free water droplet were significantly lower than those of water in a glass sample cell.

  7. Segmentation and automated measurement of chronic wound images: probability map approach

    NASA Astrophysics Data System (ADS)

    Ahmad Fauzi, Mohammad Faizal; Khansa, Ibrahim; Catignani, Karen; Gordillo, Gayle; Sen, Chandan K.; Gurcan, Metin N.

    2014-03-01

    estimated 6.5 million patients in the United States are affected by chronic wounds, with more than 25 billion US dollars and countless hours spent annually for all aspects of chronic wound care. There is need to develop software tools to analyze wound images that characterize wound tissue composition, measure their size, and monitor changes over time. This process, when done manually, is time-consuming and subject to intra- and inter-reader variability. In this paper, we propose a method that can characterize chronic wounds containing granulation, slough and eschar tissues. First, we generate a Red-Yellow-Black-White (RYKW) probability map, which then guides the region growing segmentation process. The red, yellow and black probability maps are designed to handle the granulation, slough and eschar tissues, respectively found in wound tissues, while the white probability map is designed to detect the white label card for measurement calibration purpose. The innovative aspects of this work include: 1) Definition of a wound characteristics specific probability map for segmentation, 2) Computationally efficient regions growing on 4D map; 3) Auto-calibration of measurements with the content of the image. The method was applied on 30 wound images provided by the Ohio State University Wexner Medical Center, with the ground truth independently generated by the consensus of two clinicians. While the inter-reader agreement between the readers is 85.5%, the computer achieves an accuracy of 80%.

  8. Measurements of gas hydrate formation probability distributions on a quasi-free water droplet.

    PubMed

    Maeda, Nobuo

    2014-06-01

    A High Pressure Automated Lag Time Apparatus (HP-ALTA) can measure gas hydrate formation probability distributions from water in a glass sample cell. In an HP-ALTA gas hydrate formation originates near the edges of the sample cell and gas hydrate films subsequently grow across the water-guest gas interface. It would ideally be desirable to be able to measure gas hydrate formation probability distributions of a single water droplet or mist that is freely levitating in a guest gas, but this is technically challenging. The next best option is to let a water droplet sit on top of a denser, immiscible, inert, and wall-wetting hydrophobic liquid to avoid contact of a water droplet with the solid walls. Here we report the development of a second generation HP-ALTA which can measure gas hydrate formation probability distributions of a water droplet which sits on a perfluorocarbon oil in a container that is coated with 1H,1H,2H,2H-Perfluorodecyltriethoxysilane. It was found that the gas hydrate formation probability distributions of such a quasi-free water droplet were significantly lower than those of water in a glass sample cell.

  9. Quantifying aluminum and semiconductor industry perfluorocarbon emissions from atmospheric measurements

    NASA Astrophysics Data System (ADS)

    Kim, Jooil; Fraser, Paul J.; Li, Shanlan; Mühle, Jens; Ganesan, Anita L.; Krummel, Paul B.; Steele, L. Paul; Park, Sunyoung; Kim, Seung-Kyu; Park, Mi-Kyung; Arnold, Tim; Harth, Christina M.; Salameh, Peter K.; Prinn, Ronald G.; Weiss, Ray F.; Kim, Kyung-Ryul

    2014-07-01

    The potent anthropogenic perfluorocarbon greenhouse gases tetrafluoromethane (CF4) and hexafluoroethane (C2F6) are emitted to the atmosphere mainly by the aluminum and semiconductor industries. Global emissions of these perfluorocarbons (PFCs) calculated from atmospheric measurements are significantly greater than expected from reported national and industry-based emission inventories. In this study, in situ measurements of the two PFCs in the Advanced Global Atmospheric Gases Experiment network are used to show that their emission ratio varies according to the relative regional presence of these two industries, providing an industry-specific emission "signature" to apportion the observed emissions. Our results suggest that underestimated emissions from the global semiconductor industry during 1990-2010, as well as from China's aluminum industry after 2002, account for the observed differences between emissions based on atmospheric measurements and on inventories. These differences are significant despite the large uncertainties in emissions based on the methodologies used by these industries.

  10. Experimental estimation of the photons visiting probability profiles in time-resolved diffuse reflectance measurement.

    PubMed

    Sawosz, P; Kacprzak, M; Weigl, W; Borowska-Solonynko, A; Krajewski, P; Zolek, N; Ciszek, B; Maniewski, R; Liebert, A

    2012-12-07

    A time-gated intensified CCD camera was applied for time-resolved imaging of light penetrating in an optically turbid medium. Spatial distributions of light penetration probability in the plane perpendicular to the axes of the source and the detector were determined at different source positions. Furthermore, visiting probability profiles of diffuse reflectance measurement were obtained by the convolution of the light penetration distributions recorded at different source positions. Experiments were carried out on homogeneous phantoms, more realistic two-layered tissue phantoms based on the human skull filled with Intralipid-ink solution and on cadavers. It was noted that the photons visiting probability profiles depend strongly on the source-detector separation, the delay between the laser pulse and the photons collection window and the complex tissue composition of the human head.

  11. Experimental estimation of the photons visiting probability profiles in time-resolved diffuse reflectance measurement

    NASA Astrophysics Data System (ADS)

    Sawosz, P.; Kacprzak, M.; Weigl, W.; Borowska-Solonynko, A.; Krajewski, P.; Zolek, N.; Ciszek, B.; Maniewski, R.; Liebert, A.

    2012-12-01

    A time-gated intensified CCD camera was applied for time-resolved imaging of light penetrating in an optically turbid medium. Spatial distributions of light penetration probability in the plane perpendicular to the axes of the source and the detector were determined at different source positions. Furthermore, visiting probability profiles of diffuse reflectance measurement were obtained by the convolution of the light penetration distributions recorded at different source positions. Experiments were carried out on homogeneous phantoms, more realistic two-layered tissue phantoms based on the human skull filled with Intralipid-ink solution and on cadavers. It was noted that the photons visiting probability profiles depend strongly on the source-detector separation, the delay between the laser pulse and the photons collection window and the complex tissue composition of the human head.

  12. β -decay half-lives and β -delayed neutron emission probabilities for several isotopes of Au, Hg, Tl, Pb, and Bi, beyond N =126

    NASA Astrophysics Data System (ADS)

    Caballero-Folch, R.; Domingo-Pardo, C.; Agramunt, J.; Algora, A.; Ameil, F.; Ayyad, Y.; Benlliure, J.; Bowry, M.; Calviño, F.; Cano-Ott, D.; Cortès, G.; Davinson, T.; Dillmann, I.; Estrade, A.; Evdokimov, A.; Faestermann, T.; Farinon, F.; Galaviz, D.; García, A. R.; Geissel, H.; Gelletly, W.; Gernhäuser, R.; Gómez-Hornillos, M. B.; Guerrero, C.; Heil, M.; Hinke, C.; Knöbel, R.; Kojouharov, I.; Kurcewicz, J.; Kurz, N.; Litvinov, Yu. A.; Maier, L.; Marganiec, J.; Marta, M.; Martínez, T.; Montes, F.; Mukha, I.; Napoli, D. R.; Nociforo, C.; Paradela, C.; Pietri, S.; Podolyák, Zs.; Prochazka, A.; Rice, S.; Riego, A.; Rubio, B.; Schaffner, H.; Scheidenberger, Ch.; Smith, K.; Sokol, E.; Steiger, K.; Sun, B.; Taín, J. L.; Takechi, M.; Testov, D.; Weick, H.; Wilson, E.; Winfield, J. S.; Wood, R.; Woods, P. J.; Yeremin, A.

    2017-06-01

    Background: There have been measurements on roughly 230 nuclei that are β -delayed neutron emitters. They range from 8He up to 150La. Apart from 210Tl, with a branching ratio of only 0.007%, no other neutron emitter has been measured beyond A =150 . Therefore, new data are needed, particularly in the region of heavy nuclei around N =126 , in order to guide theoretical models and help understand the formation of the third r -process peak at A ˜195 . Purpose: To measure both β -decay half-lives and neutron branching ratios of several neutron-rich Au, Hg, Tl, Pb, and Bi isotopes beyond N =126 . Method: Ions of interest were produced by fragmentation of a 238U beam, selected and identified via the GSI-FRS fragment separator. A stack of segmented silicon detectors (SIMBA) was used to measure ion implants and β decays. An array of 30 3He tubes embedded in a polyethylene matrix (BELEN) was used to detect neutrons with high efficiency and selectivity. A self-triggered digital system is employed to acquire data and to enable time correlations. The latter were analyzed with an analytical model and results for the half-lives and neutron-branching ratios were derived by using the binned maximum-likelihood method. Results: Twenty new β -decay half-lives are reported for Au-206204, Hg-211208,Tl-216211,Pb-218215 , and Bi-220218, nine of them for the first time. Neutron emission probabilities are reported for Hg,211210 and Tl-216211. Conclusions: The new β -decay half-lives are in good agreement with previous measurements on nuclei in this region. The measured neutron emission probabilities are comparable to or smaller than values predicted by global models such as relativistic Hartree Bogoliubov plus the relativistic quasi-particle random phase approximation (RHB + RQRPA).

  13. Wolf Attack Probability: A Theoretical Security Measure in Biometric Authentication Systems

    NASA Astrophysics Data System (ADS)

    Une, Masashi; Otsuka, Akira; Imai, Hideki

    This paper will propose a wolf attack probability (WAP) as a new measure for evaluating security of biometric authentication systems. The wolf attack is an attempt to impersonate a victim by feeding “wolves” into the system to be attacked. The “wolf” means an input value which can be falsely accepted as a match with multiple templates. WAP is defined as a maximum success probability of the wolf attack with one wolf sample. In this paper, we give a rigorous definition of the new security measure which gives strength estimation of an individual biometric authentication system against impersonation attacks. We show that if one reestimates using our WAP measure, a typical fingerprint algorithm turns out to be much weaker than theoretically estimated by Ratha et al. Moreover, we apply the wolf attack to a finger-vein-pattern based algorithm. Surprisingly, we show that there exists an extremely strong wolf which falsely matches all templates for any threshold value.

  14. Estimation of (n,f) Cross-Sections by Measuring Reaction Probability Ratios

    SciTech Connect

    Plettner, C; Ai, H; Beausang, C W; Bernstein, L A; Ahle, L; Amro, H; Babilon, M; Burke, J T; Caggiano, J A; Casten, R F; Church, J A; Cooper, J R; Crider, B; Gurdal, G; Heinz, A; McCutchan, E A; Moody, K; Punyon, J A; Qian, J; Ressler, J J; Schiller, A; Williams, E; Younes, W

    2005-04-21

    Neutron-induced reaction cross-sections on unstable nuclei are inherently difficult to measure due to target activity and the low intensity of neutron beams. In an alternative approach, named the 'surrogate' technique, one measures the decay probability of the same compound nucleus produced using a stable beam on a stable target to estimate the neutron-induced reaction cross-section. As an extension of the surrogate method, in this paper they introduce a new technique of measuring the fission probabilities of two different compound nuclei as a ratio, which has the advantage of removing most of the systematic uncertainties. This method was benchmarked in this report by measuring the probability of deuteron-induced fission events in coincidence with protons, and forming the ratio P({sup 236}U(d,pf))/P({sup 238}U(d,pf)), which serves as a surrogate for the known cross-section ratio of {sup 236}U(n,f)/{sup 238}U(n,f). IN addition, the P({sup 238}U(d,d{prime}f))/P({sup 236}U(d,d{prime}f)) ratio as a surrogate for the {sup 237}U(n,f)/{sup 235}U(n,f) cross-section ratio was measured for the first time in an unprecedented range of excitation energies.

  15. Method and means for measuring acoustic emissions

    DOEpatents

    Renken, Jr., Claus J.

    1976-01-06

    The detection of acoustic emissions emanating from an object is achieved with a capacitive transducer coupled to the object. The capacitive transducer is charged and then allowed to discharge with the rate of discharge being monitored. Oscillations in the rate of discharge about the normally exponential discharge curve for the capacitive transducer indicate the presence of acoustic emissions.

  16. Deducing dust emission mechanisms from field measurements

    USDA-ARS?s Scientific Manuscript database

    Field observations are needed to both develop and test theories on dust emission for use in global modeling systems. The mechanism of dust emission (aerodynamic entrainment, saltation bombardment, aggregate disintegration) and the amount and particle-size distribution of emitted dust may vary under ...

  17. The use of positive matrix factorization with conditional probability functions in air quality studies: An application to hydrocarbon emissions in Houston, Texas

    NASA Astrophysics Data System (ADS)

    Xie, Yulong; Berkowitz, Carl M.

    In this paper, we describe two advanced statistical techniques suited to address the following questions: which source categories of emissions affect given areas and where do these source categories come from? A source category is defined as a combination of volatile organic compounds (VOCs) associated with a specific industrial process. A discussion of the positive matrix factorization (PMF) multivariate receptor model is presented, and this PMF technique applied to hourly average concentrations of VOCs measured at five Photochemical Assessment Monitoring Stations (PAMS) located near the emission-rich Houston Ship Channel region in Texas. The observations were made between June and October 2003, and the PMF analysis was limited to nighttime measurements (21:00-06:00 CDT) to remove the complexity of photochemical processing and associated changes in the concentrations of primary and secondary VOCs. Six to eight VOCs source categories were identified for the five Ship Channel sites. Specific geographic areas associated with each source category were identified through the use of conditional probability functions that identify source regions when superimposed on maps of VOC emissions.

  18. Aircraft measurements of microwave emission from Arctic Sea Ice

    NASA Technical Reports Server (NTRS)

    Wilheit, T. T.; Blinn, J.; Campbell, W. J.; Edgerton, A. T.; Nordberg, W.

    1971-01-01

    Measurements of the microwave emission from Arctic Sea ice were made with aircraft at 8 wavelengths ranging from 0.510 cm to 2.81 cm. The expected contrast in emissivities between ice and water was observed at all wavelengths. Distributions of sea ice and open water were mapped from altitudes up to 11 km in the presence of dense cloud cover. Different forms of ice also exhibited strong contrasts in emissivity. Emissivity differences of up to 0.2 were observed between two types of ice at 0.811 cm wavelength. The higher emissivity ice type is tentatively identified as having been formed more recently than the lower emissivity ice.

  19. Spectral Discrete Probability Density Function of Measured Wind Turbine Noise in the Far Field

    PubMed Central

    Ashtiani, Payam; Denison, Adelaide

    2015-01-01

    Of interest is the spectral character of wind turbine noise at typical residential set-back distances. In this paper, a spectral statistical analysis has been applied to immission measurements conducted at three locations. This method provides discrete probability density functions for the Turbine ONLY component of the measured noise. This analysis is completed for one-third octave sound levels, at integer wind speeds, and is compared to existing metrics for measuring acoustic comfort as well as previous discussions on low-frequency noise sources. PMID:25905097

  20. Spectral discrete probability density function of measured wind turbine noise in the far field.

    PubMed

    Ashtiani, Payam; Denison, Adelaide

    2015-01-01

    Of interest is the spectral character of wind turbine noise at typical residential set-back distances. In this paper, a spectral statistical analysis has been applied to immission measurements conducted at three locations. This method provides discrete probability density functions for the Turbine ONLY component of the measured noise. This analysis is completed for one-third octave sound levels, at integer wind speeds, and is compared to existing metrics for measuring acoustic comfort as well as previous discussions on low-frequency noise sources.

  1. 40 CFR 86.1338-2007 - Emission measurement accuracy.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 19 2011-07-01 2011-07-01 false Emission measurement accuracy. 86.1338... Procedures § 86.1338-2007 Emission measurement accuracy. (a) Minimum limit. (1) The minimum limit of an... measurement must be made to ensure the accuracy of the calibration curve to within ±2 percent of...

  2. 40 CFR 86.1338-2007 - Emission measurement accuracy.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 20 2012-07-01 2012-07-01 false Emission measurement accuracy. 86.1338... Procedures § 86.1338-2007 Emission measurement accuracy. (a) Minimum limit. (1) The minimum limit of an... measurement must be made to ensure the accuracy of the calibration curve to within ±2 percent of point...

  3. Measurement and prediction of enteric methane emission.

    PubMed

    Sejian, Veerasamy; Lal, Rattan; Lakritz, Jeffrey; Ezeji, Thaddeus

    2011-01-01

    The greenhouse gas (GHG) emissions from the agricultural sector account for about 25.5% of total global anthropogenic emission. While CO(2) receives the most attention as a factor relative to global warming, CH(4), N(2)O and chlorofluorocarbons (CFCs) also cause significant radiative forcing. With the relative global warming potential of 25 compared with CO(2), CH(4) is one of the most important GHGs. This article reviews the prediction models, estimation methodology and strategies for reducing enteric CH(4) emissions. Emission of CH(4) in ruminants differs among developed and developing countries, depending on factors like animal species, breed, pH of rumen fluid, ratio of acetate:propionate, methanogen population, composition of diet and amount of concentrate fed. Among the ruminant animals, cattle contribute the most towards the greenhouse effect through methane emission followed by sheep, goats and buffalos, respectively. The estimated CH(4) emission rate per cattle, buffaloe, sheep and goat in developed countries are 150.7, 137, 21.9 and 13.7 (g/animal/day) respectively. However, the estimated rates in developing countries are significantly lower at 95.9 and 13.7 (g/animal/day) per cattle and sheep, respectively. There exists a strong interest in developing new and improving the existing CH(4) prediction models to identify mitigation strategies for reducing the overall CH(4) emissions. A synthesis of the available literature suggests that the mechanistic models are superior to empirical models in accurately predicting the CH(4) emission from dairy farms. The latest development in prediction model is the integrated farm system model which is a process-based whole-farm simulation technique. Several techniques are used to quantify enteric CH(4) emissions starting from whole animal chambers to sulfur hexafluoride (SF6) tracer techniques. The latest technology developed to estimate CH(4) more accurately is the micrometeorological mass difference technique. Because

  4. Measurement and prediction of enteric methane emission

    NASA Astrophysics Data System (ADS)

    Sejian, Veerasamy; Lal, Rattan; Lakritz, Jeffrey; Ezeji, Thaddeus

    2011-01-01

    The greenhouse gas (GHG) emissions from the agricultural sector account for about 25.5% of total global anthropogenic emission. While CO2 receives the most attention as a factor relative to global warming, CH4, N2O and chlorofluorocarbons (CFCs) also cause significant radiative forcing. With the relative global warming potential of 25 compared with CO2, CH4 is one of the most important GHGs. This article reviews the prediction models, estimation methodology and strategies for reducing enteric CH4 emissions. Emission of CH4 in ruminants differs among developed and developing countries, depending on factors like animal species, breed, pH of rumen fluid, ratio of acetate:propionate, methanogen population, composition of diet and amount of concentrate fed. Among the ruminant animals, cattle contribute the most towards the greenhouse effect through methane emission followed by sheep, goats and buffalos, respectively. The estimated CH4 emission rate per cattle, buffaloe, sheep and goat in developed countries are 150.7, 137, 21.9 and 13.7 (g/animal/day) respectively. However, the estimated rates in developing countries are significantly lower at 95.9 and 13.7 (g/animal/day) per cattle and sheep, respectively. There exists a strong interest in developing new and improving the existing CH4 prediction models to identify mitigation strategies for reducing the overall CH4 emissions. A synthesis of the available literature suggests that the mechanistic models are superior to empirical models in accurately predicting the CH4 emission from dairy farms. The latest development in prediction model is the integrated farm system model which is a process-based whole-farm simulation technique. Several techniques are used to quantify enteric CH4 emissions starting from whole animal chambers to sulfur hexafluoride (SF6) tracer techniques. The latest technology developed to estimate CH4 more accurately is the micrometeorological mass difference technique. Because the conditions under which

  5. Direct measurement of the percolation probability in carbon nanofiber-polyimide nanocomposites.

    SciTech Connect

    Wang, David H.; Trionfi, Aaron; Vaia, Richard A.; Hsu, Julia W. P.; Jacobs, J. David; Tan, L.-Seng

    2008-11-01

    We present the first experimental measurement of the geometric critical exponent {beta} associated with the percolation probability, the probability a metallic filler belongs to the conducting network, of an electrical composite. The technique employs conducting-tip atomic force microscopy to obtain a conducting areal density, and is demonstrated on polyimide nanocomposites containing different concentrations of carbon nanofibers. We find {beta} {approx} 1 and t (the exponent for bulk conductivity) {approx} 3. These values are consistent with the predictions for the Bethe lattice and larger than the values predicted in the 3D lattice percolation model. Hence, this electrical composite likely belongs to the same universality class as the Bethe lattice. The ability to measure geometric and transport critical exponents on the same material is critical to drawing this conclusion.

  6. Measurement of two- and three-nucleon short-range correlation probabilities in nuclei.

    PubMed

    Egiyan, K S; Dashyan, N B; Sargsian, M M; Strikman, M I; Weinstein, L B; Adams, G; Ambrozewicz, P; Anghinolfi, M; Asavapibhop, B; Asryan, G; Avakian, H; Baghdasaryan, H; Baillie, N; Ball, J P; Baltzell, N A; Batourine, V; Battaglieri, M; Bedlinskiy, I; Bektasoglu, M; Bellis, M; Benmouna, N; Biselli, A S; Bonner, B E; Bouchigny, S; Boiarinov, S; Bradford, R; Branford, D; Brooks, W K; Bültmann, S; Burkert, V D; Bultuceanu, C; Calarco, J R; Careccia, S L; Carman, D S; Carnahan, B; Chen, S; Cole, P L; Coltharp, P; Corvisiero, P; Crabb, D; Crannell, H; Cummings, J P; De Sanctis, E; DeVita, R; Degtyarenko, P V; Denizli, H; Dennis, L; Dharmawardane, K V; Djalali, C; Dodge, G E; Donnelly, J; Doughty, D; Dragovitsch, P; Dugger, M; Dytman, S; Dzyubak, O P; Egiyan, H; Elouadrhiri, L; Empl, A; Eugenio, P; Fatemi, R; Fedotov, G; Feuerbach, R J; Forest, T A; Funsten, H; Gavalian, G; Gevorgyan, N G; Gilfoyle, G P; Giovanetti, K L; Girod, F X; Goetz, J T; Golovatch, E; Gothe, R W; Griffioen, K A; Guidal, M; Guillo, M; Guler, N; Guo, L; Gyurjyan, V; Hadjidakis, C; Hardie, J; Hersman, F W; Hicks, K; Hleiqawi, I; Holtrop, M; Hu, J; Huertas, M; Hyde-Wright, C E; Ilieva, Y; Ireland, D G; Ishkhanov, B S; Ito, M M; Jenkins, D; Jo, H S; Joo, K; Juengst, H G; Kellie, J D; Khandaker, M; Kim, K Y; Kim, K; Kim, W; Klein, A; Klein, F J; Klimenko, A; Klusman, M; Kramer, L H; Kubarovsky, V; Kuhn, J; Kuhn, S E; Kuleshov, S; Lachniet, J; Laget, J M; Langheinrich, J; Lawrence, D; Lee, T; Livingston, K; Maximon, L C; McAleer, S; McKinnon, B; McNabb, J W C; Mecking, B A; Mestayer, M D; Meyer, C A; Mibe, T; Mikhailov, K; Minehart, R; Mirazita, M; Miskimen, R; Mokeev, V; Morrow, S A; Mueller, J; Mutchler, G S; Nadel-Turonski, P; Napolitano, J; Nasseripour, R; Niccolai, S; Niculescu, G; Niculescu, I; Niczyporuk, B B; Niyazov, R A; O'Relly, G V; Osipenko, M; Ostrovidov, A I; Park, K; Pasyuk, E; Peterson, C; Pierce, J; Pivnyuk, N; Pocanic, D; Pogorelko, O; Polli, E; Pozdniakov, S; Preedom, B M; Price, J W; Prok, Y; Protopopescu, D; Qin, L M; Raue, B A; Riccardi, G; Ricco, G; Ripani, M; Ritchie, B G; Ronchetti, F; Rosner, G; Rossi, P; Rowntree, D; Rubin, P D; Sabatié, F; Salgado, C; Santoro, J P; Sapunenko, V; Schumacher, R A; Serov, V S; Sharabian, Y G; Shaw, J; Smith, E S; Smith, L C; Sober, D I; Stavinsky, A; Stepanyan, S; Stokes, B E; Stoler, P; Strauch, S; Suleiman, R; Taiuti, M; Taylor, S; Tedeschi, D J; Thompson, R; Tkabladze, A; Tkachenko, S; Todor, L; Tur, C; Ungaro, M; Vineyard, M F; Vlassov, A V; Weygand, D P; Williams, M; Wolin, E; Wood, M H; Yegneswaran, A; Yun, J; Zana, L; Zhang, J

    2006-03-03

    The ratios of inclusive electron scattering cross sections of 4He, 12C, and 56Fe to 3He have been measured at 1 < xB <. At Q2 > 1.4 GeV2, the ratios exhibit two separate plateaus, at 1.5 < xB < 2 and at xB > 2.25. This pattern is predicted by models that include 2- and 3-nucleon short-range correlations (SRC). Relative to A = 3, the per-nucleon probabilities of 3-nucleon SRC are 2.3, 3.1, and 4.4 times larger for A = 4, 12, and 56. This is the first measurement of 3-nucleon SRC probabilities in nuclei.

  7. Measuring the emissions of passing cars

    SciTech Connect

    Bishop, G.A.; Stedman, D.H.

    1996-10-01

    Here, in situ sensing of the emissions from motor vehicles is reviewed. The role of thermodynamics, chemical reaction kinetics, stoichiometry of reactions, heat transfer, and fluid flow are considered. 27 refs., 5 figs.

  8. Measurement of spin-flip probabilities for ultracold neutrons interacting with nickel phosphorus coated surfaces

    DOE PAGES

    Tang, Zhaowen; Adamek, Evan Robert; Brandt, Aaron; ...

    2016-04-26

    In this paper, we report a measurement of the spin-flip probabilities for ultracold neutrons interacting with surfaces coated with nickel phosphorus. For 50 μm thick nickel phosphorus coated on stainless steel, the spin-flip probability per bounce was found to be βNiP on SS = (3.3 +1.8, -5.6) X 10-6. For 50 μm thick nickel phosphorus coated on aluminum, the spin-flip probability per bounce was found to be βNiP on Al = (3.6 +2.1, -5.9) X 10-6. For the copper guide used as reference, the spin flip probability per bounce was found to be βCu = (6.7 + 5.0, -2.5) Xmore » 10-6. The results on the nickel phosphorus-coated surfaces may be interpreted as upper limits, yielding βNiP on SS < 6.2 X 10-6 (90% C.L.) and βNiP on Al < 7.0 X 10-6 (90% C.L.) for 50 μm thick nickel phosphorus coated on stainless steel and 50 μm thick nickel phosphorus coated on aluminum, respectively. Finally, nickel phosphorus coated stainless steel or aluminum provides a solution when low-cost, mechanically robust, and non-depolarizing UCN guides with a high Fermi potential are needed.« less

  9. Measuring and Modeling Fault Density for Plume-Fault Encounter Probability Estimation

    SciTech Connect

    Jordan, P.D.; Oldenburg, C.M.; Nicot, J.-P.

    2011-05-15

    Emission of carbon dioxide from fossil-fueled power generation stations contributes to global climate change. Storage of this carbon dioxide within the pores of geologic strata (geologic carbon storage) is one approach to mitigating the climate change that would otherwise occur. The large storage volume needed for this mitigation requires injection into brine-filled pore space in reservoir strata overlain by cap rocks. One of the main concerns of storage in such rocks is leakage via faults. In the early stages of site selection, site-specific fault coverages are often not available. This necessitates a method for using available fault data to develop an estimate of the likelihood of injected carbon dioxide encountering and migrating up a fault, primarily due to buoyancy. Fault population statistics provide one of the main inputs to calculate the encounter probability. Previous fault population statistics work is shown to be applicable to areal fault density statistics. This result is applied to a case study in the southern portion of the San Joaquin Basin with the result that the probability of a carbon dioxide plume from a previously planned injection had a 3% chance of encountering a fully seal offsetting fault.

  10. Characterizing particulate polycyclic aromatic hydrocarbon emissions from diesel vehicles using a portable emissions measurement system.

    PubMed

    Zheng, Xuan; Wu, Ye; Zhang, Shaojun; Hu, Jingnan; Zhang, K Max; Li, Zhenhua; He, Liqiang; Hao, Jiming

    2017-08-30

    Particulate polycyclic aromatic hydrocarbons (p-PAHs) emitted from diesel vehicles are of concern because of their significant health impacts. Laboratory tests, road tunnel and roadside experiments have been conducted to measure p-PAH emissions. While providing valuable information, these methods have limited capabilities of characterizing p-PAH emissions either from individual vehicles or under real-world conditions. We employed a portable emissions measurement (PEMS) to measure real-world emission factors of priority p-PAHs for diesel vehicles representative of an array of emission control technologies. The results indicated over 80% reduction in p-PAH emission factors comparing the China V and China II emission standard groups (113 μg kg(-1) vs. 733 μg kg(-1)). The toxicity abatement in terms of Benzo[a]pyrene equivalent emissions was substantial because of the large reductions in highly toxic components. By assessing real traffic conditions, the p-PAH emission factors on freeways were lower than on local roads by 52% ± 24%. A significant correlation (R(2)~0.85) between the p-PAH and black carbon emissions was identified with a mass ratio of approximately 1/2000. A literature review indicated that diesel p-PAH emission factors varied widely by engine technology, measurement methods and conditions, and the molecular diagnostic ratio method for source apportionment should be used with great caution.

  11. Characteristic Functional of a Probability Measure Absolutely Continuous with Respect to a Gaussian Radon Measure

    DTIC Science & Technology

    1984-08-01

    1962) 372-390. 5. J. Neveu, "Martingales a temps discret." Masson et Cie. Paris. 1972. 6. H. Sato and Y. Okazaki, Separabilities of a Gaussian Radon measure. Ann. Inst. Henri Poincare , 11 (1975) 287-298.

  12. NO2 DOAS Measurements of Traffic Emissions by Chasing Cars

    NASA Astrophysics Data System (ADS)

    Zhu, Ying; Lipkowitsch, Ivo; Chan, Ka Lok; Bräu, Melanie; Wenig, Mark

    2016-04-01

    On this poster we present NO2 measurements using a Cavity-Enhanced DOAS on a measurement bus which we used to chase other vehicles to measure their NO2 emissions. Emissions of nitrogen oxides from on-road vehicles have received highly attention recently due to the increasing trend of ambient NOx level. It is particularly important to identify and quantify the direct emission and secondary formation of NO2 contributed by traffic emissions, in order to study the impact to the local air quality. We sampled on-road emissions in different environments and different driving conditions (e.g. urban, highway, different speeds). We analyse the data set in terms of spatial and temporal variability to search for temporal and spatial patterns. We present mean values sorted for different vehicle types, distance to the target car and travelling speeds to provide an emission data base from this measurement study.

  13. Direct comparison of defect ensembles extracted from damage probability and raster scan measurements

    NASA Astrophysics Data System (ADS)

    BatavičiÅ«tÄ--, G.; Ščiuka, M.; Melninkaitis, A.

    2015-09-01

    The presented study addresses the characterization of nanometer sized defects acting as damage precursors in nanosecond laser pulse duration regime. Two approaches are used to extract distributions of localized damage precursors, namely, damage probability and damage density measurements. Testing is performed on uncoated and SiO2 monolayer film deposited fused silica substrate exposed with pulsed UV irradiation (355 nm, 4.8 ns). Then, a direct comparison of damage precursor ensembles obtained from both methods is carried out. Our analysis indicates apparent differences between both methods that are discussed in detail. Contamination by ablation products is identified as one of the key factors that influence damage density measurements.

  14. Far-infrared emissivity measurements of reflective surfaces

    NASA Technical Reports Server (NTRS)

    Xu, J.; Lange, A. E.; Bock, J. J.

    1996-01-01

    An instrument developed to measure the emissivity of reflective surfaces by comparing the thermal emission of a test sample to that of a reference surface is reported. The instrument can accurately measure the emissivity of mirrors made from lightweight thermally insulating materials such as glass and metallized carbon fiber reinforced plastics. Far infrared measurements at a wavelength of 165 micrometers are reported. The instrument has an absolute accuracy of Delta epsilon = 9 x 10(exp -4) and can reproducibly measure an emissivity of as small as 2 x 10(exp -4) between flat reflective surfaces. The instrument was used to measure mirror samples for balloon-borne and spaceborne experiments. An emissivity of (6.05 +/- 1.24) x 10(exp -3) was measured for gold evaporated on glass, and (6.75 +/- 1.17) x 10(exp -3) for aluminum evaporated on glass.

  15. Comparative use of different emission measurement approaches to determine methane emissions from a biogas plant.

    PubMed

    Reinelt, Torsten; Delre, Antonio; Westerkamp, Tanja; Holmgren, Magnus A; Liebetrau, Jan; Scheutz, Charlotte

    2017-06-16

    A sustainable anaerobic biowaste treatment has to mitigate methane emissions from the entire biogas production chain, but the exact quantification of these emissions remains a challenge. This study presents a comparative measurement campaign carried out with on-site and ground-based remote sensing measurement approaches conducted by six measuring teams at a Swedish biowaste treatment plant. The measured emissions showed high variations, amongst others caused by different periods of measurement performance in connection with varying operational states of the plant. The overall methane emissions measured by ground-based remote sensing varied from 5 to 25kgh(-1) (corresponding to a methane loss of 0.6-3.0% of upgraded methane produced), depending on operating conditions and the measurement method applied. Overall methane emissions measured by the on-site measuring approaches varied between 5 and 17kgh(-1) (corresponding to a methane loss of 0.6 and 2.1%) from team to team, depending on the number of measured emission points, operational state during the measurements and the measurement method applied. Taking the operational conditions into account, the deviation between different approaches and teams could be explained, in that the two largest methane-emitting sources, contributing about 90% of the entire site's emissions, were found to be the open digestate storage tank and a pressure release valve on the compressor station. Copyright © 2017. Published by Elsevier Ltd.

  16. Simple methodologies for spectral emissivity measurement of rocks

    NASA Astrophysics Data System (ADS)

    Danov, Miroslav; Borisova, Denitsa; Stoyanov, Dimitar; Petkov, Doyno

    Presented investigation is focused on the measurement of spectral emissivity in the spectral interval of 8-14µm performed by ground-based technique. This spectral interval is generally used for investigation of vegetation, rock and water surfaces. The amount of radiated energy is a function of the object's temperature and its emissivity. For this reason the emissivity data is very useful for object's temperature assessment in thermal imaging process. We have developed and compared two simplified methodologies for measurement of spectral emissivity of rock and mineral samples, avoiding additional heating or grinding of the samples that accompanied other techniques. The first of them is related to the measurements of the hemispherical spectral emissivity, while the second one concerns the measurement of the directional spectral emissivity of samples. Both methodologies are suitable for laboratory and field measurements of samples with small active area (10cm2 ). As an illustration of the hemispherical spectral emissivity approach, the emissivity spectrum of limestone is presented. Most frequently the emissivity is referred to the normal emissivity. However, the directionality of the emissivity has an important effect on the measurements, for example when the land surface temperature is deduced. A simple methodology for measuring of the directional emissivity is proposed and developed. It is based on the emission of a collimated infrared (IR) source irradiating the investigated sample. The IR radiation is reflected by the sample and collected by a lithium tantalite pyroelectric detector. The spectral resolution of the reflected by the sample emission is provided by a set of 30 narrow-band transmission filters. Phase sensitive detection technique is used to enhance the signal/noise. The registered data are processed by a PC. The measuring process will be discussed and the experimentally measured directional emissivity spectra will be presented, related to some rock

  17. 40 CFR 86.1837-01 - Rounding of emission measurements.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 19 2014-07-01 2014-07-01 false Rounding of emission measurements. 86.1837-01 Section 86.1837-01 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR..., and Complete Otto-Cycle Heavy-Duty Vehicles § 86.1837-01 Rounding of emission measurements. (a) Unless...

  18. 40 CFR 86.1837-01 - Rounding of emission measurements.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 20 2013-07-01 2013-07-01 false Rounding of emission measurements. 86.1837-01 Section 86.1837-01 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...-Duty Trucks, and Complete Otto-Cycle Heavy-Duty Vehicles § 86.1837-01 Rounding of emission measurements...

  19. 40 CFR 86.1837-01 - Rounding of emission measurements.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 20 2012-07-01 2012-07-01 false Rounding of emission measurements. 86.1837-01 Section 86.1837-01 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...-Duty Trucks, and Complete Otto-Cycle Heavy-Duty Vehicles § 86.1837-01 Rounding of emission measurements...

  20. Measuring SO2 ship emissions with an ultraviolet imaging camera

    NASA Astrophysics Data System (ADS)

    Prata, A. J.

    2014-05-01

    Over the last few years fast-sampling ultraviolet (UV) imaging cameras have been developed for use in measuring SO2 emissions from industrial sources (e.g. power plants; typical emission rates ~ 1-10 kg s-1) and natural sources (e.g. volcanoes; typical emission rates ~ 10-100 kg s-1). Generally, measurements have been made from sources rich in SO2 with high concentrations and emission rates. In this work, for the first time, a UV camera has been used to measure the much lower concentrations and emission rates of SO2 (typical emission rates ~ 0.01-0.1 kg s-1) in the plumes from moving and stationary ships. Some innovations and trade-offs have been made so that estimates of the emission rates and path concentrations can be retrieved in real time. Field experiments were conducted at Kongsfjord in Ny Ålesund, Svalbard, where SO2 emissions from cruise ships were made, and at the port of Rotterdam, Netherlands, measuring emissions from more than 10 different container and cargo ships. In all cases SO2 path concentrations could be estimated and emission rates determined by measuring ship plume speeds simultaneously using the camera, or by using surface wind speed data from an independent source. Accuracies were compromised in some cases because of the presence of particulates in some ship emissions and the restriction of single-filter UV imagery, a requirement for fast-sampling (> 10 Hz) from a single camera. Despite the ease of use and ability to determine SO2 emission rates from the UV camera system, the limitation in accuracy and precision suggest that the system may only be used under rather ideal circumstances and that currently the technology needs further development to serve as a method to monitor ship emissions for regulatory purposes. A dual-camera system or a single, dual-filter camera is required in order to properly correct for the effects of particulates in ship plumes.

  1. RELATIVISTIC CALCULATION OF TRANSITION PROBABILITIES FOR 557.7 nm AND 297.2 nm EMISSION LINES IN OXYGEN

    SciTech Connect

    Chantler, C. T.; Nguyen, T. V. B.; Lowe, J. A.; Grant, I. P.

    2013-05-20

    The 557.7 nm green line and the 297.2 nm ultraviolet line in oxygen have been studied extensively due to their importance in astrophysics and atmospheric science. Despite the enormous effort devoted to these two prominent transition lines over 30 years, and in fact going back to 1934, the ratio of their transition probabilities remains a subject of major discrepancies amongst various theoretical calculations for many decades. Moreover, theoretical results are inconsistent with available laboratory results, as well as recent spacecraft measurements of Earth's airglow. This work presents new relativistic theoretical calculations of the transition probabilities of these two photoemission lines from neutral oxygen using the multi-configuration Dirac-Hartree-Fock method. Our calculations were performed in both length and velocity gauges in order to check for accuracy and consistency, with agreement to 8%. Whilst remaining a challenging computation, these results directly bear upon interpretations of plasma processes and ionization regimes in the universe.

  2. MEASUREMENT OF METHANE EMISSIONS FROM UNDERGROUND DISTRIBUTION MAINS AND SERVICES

    EPA Science Inventory

    The paper reports results of measurements of methane emissions from underground distribution mains and services. In the program, leakage from underground distribution systems is estimated by combining leak measurements with historical leak record data and the length of undergroun...

  3. MEASUREMENT OF METHANE EMISSIONS FROM UNDERGROUND DISTRIBUTION MAINS AND SERVICES

    EPA Science Inventory

    The paper reports results of measurements of methane emissions from underground distribution mains and services. In the program, leakage from underground distribution systems is estimated by combining leak measurements with historical leak record data and the length of undergroun...

  4. Measurement of Angular-Momentum-Dependent Fission Probabilities of 240Pu

    NASA Astrophysics Data System (ADS)

    Koglin, Johnathon; Burke, Jason; Jovanovic, Igor

    2016-09-01

    An experimental technique using the surrogate reaction method has been developed to measure fission probabilities of actinides as a function of angular momentum state of the fissioning nucleus near the fission barrier. In this work, the 240Pu (α ,α' f) reaction was used as a surrogate for 239Pu (n , f) . An array of 12 silicon telescopes positioned at 10 degree intervals from 40 to 140 degrees detect the outgoing reaction particle for identification and measurement of the excitation energy. The angular momentum state is determined by measuring the angular distribution of fission fragments. The expected distributions are predicted from the Wigner d function. An array of 50 photovoltaic (solar) cells detects fission fragments with 10-degree granularity. The solar cells are sensitive to fission fragments but have no response to light ions. Relative contributions from different angular momentum states are extracted from the measured distributions and compared across all α particle scattering angles to determine fission probability at a specific angular momentum state. The first experiment using this technique was recently completed using 37 MeV α particles incident on 240Pu. First results will be discussed. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. This material is based upon work supported by the U.S. Department of Homeland Security under Grant Award Nu.

  5. Methane emissions measured directly from grazing livestock in New Zealand

    NASA Astrophysics Data System (ADS)

    Lassey, Keith R.; Ulyatt, Marcus J.; Martin, Ross J.; Walker, Carolyn F.; David Shelton, I.

    We report measurements of methane emissions from individual ruminant livestock-both sheep and dairy cows-grazing pasture typical of New Zealand lowlands in the temperate southwest Pacific. These are the first measurements reported from grazing sheep, and among the first from grazing cattle. The measurement technique, developed at Washington State University, enables emission rates to be determined from analyses of "breath" samples collected while grazing. More than 250 measurements of daily methane emission from 50 sheep (8 months old) were made, with flock-mean emission 18.9 ± 0.8 g hd -1 d -1. Although emissions were weakly correlated with feed intake, they represented a 4.6 ± 0.1 % average loss of gross dietary energy. The corresponding mean emission based on 40 measurements of daily emissions from 10 lactating dairy cows was 263 ± 10 g hd -1 d -1, approximately 6.2% of estimated gross energy intake. A notable feature was the large inter-sheep variability in daily methane emission (factor of 1.4 range) that could not be attributed to variable intake. This would appear to suggest an appreciable diversity of methanogenetic response to digestion, and may be significant in the search for strategies to control emissions of this greenhouse gas.

  6. Portable emission measurements of Yellowstone Park snowcoaches and snowmobiles.

    PubMed

    Bishop, Gary A; Stadtmuller, Ryan; Stedman, Donald H; Ray, John D

    2009-08-01

    As part of the National Park Service's Temporary Winter Use Plans Environmental Assessment, the University of Denver has been collecting in-use tailpipe emissions data from snowcoaches and snowmobiles in Yellowstone National Park. During the winter of 2006, using a portable emissions monitoring system, tailpipe data were collected from 10 snowcoaches and 2 four-stroke snowmobiles. These vehicles were operated over a standard route within the park, and the snowcoaches all carried identical passenger loads. These snowcoaches were newer in age with more advanced fuel management technology than those studied earlier, and average emissions were lower as a result (120, 1.7, and 11 g/mi for carbon monoxide [CO], hydrocarbons [HC], and oxides of nitrogen [NOx]). Large emissions variability was still observed despite using a standardized route and equal passenger loading. A comparison between five nearly identically equipped snowcoaches that had CO emissions ranging between 12 and 310 g/mi suggests that snow and road conditions are the most important factors behind the large emissions variability observed between modern snowcoaches: The first comprehensive emission measurements, using a portable emissions measurement system, on two snowmobiles showed that computer-controlled fuel management systems have increased fuel economy (>25 mpg) and are a major reason that emissions from these winter vehicles have dropped so dramatically. Using all of the tailpipe emissions data collected to date shows that the two primary winter vehicles in Yellowstone National Park are now very similar in their per-passenger emissions.

  7. Pygmy Gamow-Teller resonance in the N =50 region: New evidence from staggering of β -delayed neutron-emission probabilities

    NASA Astrophysics Data System (ADS)

    Verney, D.; Testov, D.; Ibrahim, F.; Penionzhkevich, Yu.; Roussière, B.; Smirnov, V.; Didierjean, F.; Flanagan, K.; Franchoo, S.; Kuznetsova, E.; Li, R.; Marsh, B.; Matea, I.; Pai, H.; Sokol, E.; Stefan, I.; Suzuki, D.

    2017-05-01

    We report on the β -delayed neutron emission probability (P1 n) measurements of the 82,83,84Ga (N =51 ,52 ,53 ) precursors performed in one single experiment using the 3He neutron-counter TETRA at the ALTO facility in Orsay. Altogether our results for the three A =82 ,83 , and 84 Ga precursors point towards a sizable P1 n staggering in the N =50 region, similar to the one already observed just after the N =28 shell closure in the K isotopes chain, hinting at a similar mechanism. We will discuss the possible microscopic origin of this behavior, i.e., the existence in the light N =51 isotones of low-lying components of the so called pygmy Gamow-Teller resonance, already well established at Z =36 , and persisting toward 79Ni.

  8. Characteristics of typical non-road machinery emissions in China by using portable emission measurement system.

    PubMed

    Fu, Mingliang; Ge, Yunshan; Tan, Jianwei; Zeng, Tao; Liang, Bin

    2012-10-15

    Non-road machinery, especially construction equipment could be an important pollutant source of the deterioration in air quality in Chinese urban areas due to its large quantity and to the absence of stringent emission requirements. In this study, emission tests were performed on 12 excavators and 8 wheel loaders by using portable emission measurement system (PEMS) to determine their emission characteristics. The typical operating modes were categorized as idling mode, moving mode and working mode. Compared with those during idling and moving modes, the average time-based emission factors during working mode of HC were 2.61 and 1.27 times higher, NO(x) were 3.66 and 1.36 times higher, and PM were 4.05 and 1.95 times higher, respectively. Under all conditions, categories of the measured emissions increased with the rise in engine power. Compared with those of Stage I emission standard equipment, gaseous emissions and PM emitted from Stage II emission standard equipment were lower. The results indicated that, from Stage I to Stage II, the average reductions of HC, NO(x) and PM were 56%, 37% and 29% for the working mode, respectively. Those results also demonstrated the effectiveness of emission control regulation and the improvement of emission control technology. The data and tests show that the longer the accumulated working hours, the higher HC and NO(x) average fuel-based emission factors are. The emissions measured from the construction vehicles employed in this study were higher than the data collected in previous studies, which shows that it is critical for the government to put into effect more stringent emission regulations to further improve the air quality in Chinese urban areas.

  9. A new perspective: Measuring and modeling of landfill methane emissions

    SciTech Connect

    Bogner, J. |; Meadows, M.; Repa, E.

    1998-06-01

    Estimating landfill methane emissions at national and global levels is fraught with uncertainties. The goal for the near-term is to improve national and global estimates based on improved models, which more realistically simulate a growing database of field measurements. This would assist regulators and policy makers to more accurately evaluate landfill methane emissions and guide development of national mitigation strategies. This article provides an updated perspective on landfill methane emissions by: (1) discussing recent field measurements and research results; (2) proposing research still needed; and (3) suggesting improved modeling strategies (including regulatory approaches) to assess landfill methane emissions more accurately.

  10. Recent volcanic activity on Venus - Evidence from radiothermal emissivity measurements

    NASA Technical Reports Server (NTRS)

    Robinson, Cordula A.; Wood, John A.

    1993-01-01

    Radiothermal emissivity measurements are analyzed in order to study large volcanic constructs on Venus and to correlate details of the reflectivity/emissivity patterns with geological landforms and stratigraphy visible in corresponding SAR images. There appears to be a correlation between locations on Venus where high emissivity at high altitudes and low emissivity at low altitudes are observed. These phenomena are attributed here to relatively recent volcanic activity: the former to summit eruptions that have not had time to weather to the low-emissivity state, the latter to continuing emission of volcanic gases from neighboring small plains volcanoes. The pattern of reflectivity and emissivity on Maat Mons is examined in the light of these findings. It is concluded that Maat Mons has undergone the most recent episode of volcanic activity of all the volcanoes studied here.

  11. How plasma parameters fluctuations influence emissive probe measurements

    SciTech Connect

    Bousselin, G. Plihon, N.; Lemoine, N.; Heuraux, S.; Cavalier, J.

    2015-05-15

    Relationship between the floating potential of an emissive probe and plasma potential oscillations is studied in the case of controlled oscillations of plasma parameters. This relationship is compared to a quasi-static model for floating potential oscillations that assumes a constant emission current and includes the fluctuations of plasma parameters (density and electron temperature). Two different plasma regimes are considered. In the first one, the model is coherent with experimental results. In the second, the model does not fulfill one of the assumption due to the evidence of emission current oscillations when the mean emission current exceeds a given threshold. This second regime highlights the importance of taking into account emission current oscillations in the interpretation of emissive probe measurements. Nevertheless, discrepancies are still observed between emissive probe floating potential and plasma potential oscillations.

  12. Recent volcanic activity on Venus - Evidence from radiothermal emissivity measurements

    NASA Technical Reports Server (NTRS)

    Robinson, Cordula A.; Wood, John A.

    1993-01-01

    Radiothermal emissivity measurements are analyzed in order to study large volcanic constructs on Venus and to correlate details of the reflectivity/emissivity patterns with geological landforms and stratigraphy visible in corresponding SAR images. There appears to be a correlation between locations on Venus where high emissivity at high altitudes and low emissivity at low altitudes are observed. These phenomena are attributed here to relatively recent volcanic activity: the former to summit eruptions that have not had time to weather to the low-emissivity state, the latter to continuing emission of volcanic gases from neighboring small plains volcanoes. The pattern of reflectivity and emissivity on Maat Mons is examined in the light of these findings. It is concluded that Maat Mons has undergone the most recent episode of volcanic activity of all the volcanoes studied here.

  13. Recent volcanic activity on Venus - Evidence from radiothermal emissivity measurements

    NASA Astrophysics Data System (ADS)

    Robinson, C. A.; Wood, J. A.

    1993-03-01

    Radiothermal emissivity measurements are analyzed in order to study large volcanic constructs on Venus and to correlate details of the reflectivity/emissivity patterns with geological landforms and stratigraphy visible in corresponding SAR images. There appears to be a correlation between locations on Venus where high emissivity at high altitudes and low emissivity at low altitudes are observed. These phenomena are attributed here to relatively recent volcanic activity: the former to summit eruptions that have not had time to weather to the low-emissivity state, the latter to continuing emission of volcanic gases from neighboring small plains volcanoes. The pattern of reflectivity and emissivity on Maat Mons is examined in the light of these findings. It is concluded that Maat Mons has undergone the most recent episode of volcanic activity of all the volcanoes studied here.

  14. Measurement of spin-flip probabilities for ultracold neutrons interacting with nickel phosphorus coated surfaces

    SciTech Connect

    Tang, Zhaowen; Adamek, Evan Robert; Brandt, Aaron; Callahan, Nathan Brannan; Clayton, Steven M.; Currie, Scott Allister; Ito, Takeyasu M.; Makela, Mark F.; Masuda, Yasuhiro; Morris, Christopher L.; Pattie, Robert Wayne; Ramsey, John Clinton; Salvat, Daniel J.; Saunders, Alexander; Young, Albert R.

    2016-04-26

    In this paper, we report a measurement of the spin-flip probabilities for ultracold neutrons interacting with surfaces coated with nickel phosphorus. For 50 μm thick nickel phosphorus coated on stainless steel, the spin-flip probability per bounce was found to be βNiP on SS = (3.3 +1.8, -5.6) X 10-6. For 50 μm thick nickel phosphorus coated on aluminum, the spin-flip probability per bounce was found to be βNiP on Al = (3.6 +2.1, -5.9) X 10-6. For the copper guide used as reference, the spin flip probability per bounce was found to be βCu = (6.7 + 5.0, -2.5) X 10-6. The results on the nickel phosphorus-coated surfaces may be interpreted as upper limits, yielding βNiP on SS < 6.2 X 10-6 (90% C.L.) and βNiP on Al < 7.0 X 10-6 (90% C.L.) for 50 μm thick nickel phosphorus coated on stainless steel and 50 μm thick nickel phosphorus coated on aluminum, respectively. Finally, nickel phosphorus coated stainless steel or aluminum provides a solution when low-cost, mechanically robust, and non-depolarizing UCN guides with a high Fermi potential are needed.

  15. Measurement of spin-flip probabilities for ultracold neutrons interacting with nickel phosphorus coated surfaces

    SciTech Connect

    Tang, Zhaowen; Adamek, Evan Robert; Brandt, Aaron; Callahan, Nathan Brannan; Clayton, Steven M.; Currie, Scott Allister; Ito, Takeyasu M.; Makela, Mark F.; Masuda, Yasuhiro; Morris, Christopher L.; Pattie, Robert Wayne; Ramsey, John Clinton; Salvat, Daniel J.; Saunders, Alexander; Young, Albert R.

    2016-04-26

    In this paper, we report a measurement of the spin-flip probabilities for ultracold neutrons interacting with surfaces coated with nickel phosphorus. For 50 μm thick nickel phosphorus coated on stainless steel, the spin-flip probability per bounce was found to be βNiP on SS = (3.3 +1.8, -5.6) X 10-6. For 50 μm thick nickel phosphorus coated on aluminum, the spin-flip probability per bounce was found to be βNiP on Al = (3.6 +2.1, -5.9) X 10-6. For the copper guide used as reference, the spin flip probability per bounce was found to be βCu = (6.7 + 5.0, -2.5) X 10-6. The results on the nickel phosphorus-coated surfaces may be interpreted as upper limits, yielding βNiP on SS < 6.2 X 10-6 (90% C.L.) and βNiP on Al < 7.0 X 10-6 (90% C.L.) for 50 μm thick nickel phosphorus coated on stainless steel and 50 μm thick nickel phosphorus coated on aluminum, respectively. Finally, nickel phosphorus coated stainless steel or aluminum provides a solution when low-cost, mechanically robust, and non-depolarizing UCN guides with a high Fermi potential are needed.

  16. Measurement of the transition probability of the C III 190.9 nanometer intersystem line

    NASA Technical Reports Server (NTRS)

    Kwong, Victor H. S.; Fang, Z.; Gibbons, T. T.; Parkinson, W. H.; Smith, Peter L.

    1993-01-01

    A radio-frequency ion trap has been used to store C(2+) ions created by electron bombardment of CO. The transition probability for the 2s2p 3Po1-2s2 1S0 intersystem line of C m has been measured by recording the radiative decay at 190.9 nm. The measured A-value is 121 +/- 7/s and agrees, within mutual uncertainty limits, with that of Laughlin et al. (1978), but is 20 percent larger than that of Nussbaumer and Storey (1978). The effective collision mixing rate coefficient among the fine structure levels of 3Po and the combined quenching and charge transfer rate coefficients out of the 3Po1 level with the CO source gas have also been measured.

  17. Measurement of the transition probability of the C III 190.9 nanometer intersystem line

    NASA Technical Reports Server (NTRS)

    Kwong, Victor H. S.; Fang, Z.; Gibbons, T. T.; Parkinson, W. H.; Smith, Peter L.

    1993-01-01

    A radio-frequency ion trap has been used to store C(2+) ions created by electron bombardment of CO. The transition probability for the 2s2p 3Po1-2s2 1S0 intersystem line of C m has been measured by recording the radiative decay at 190.9 nm. The measured A-value is 121 +/- 7/s and agrees, within mutual uncertainty limits, with that of Laughlin et al. (1978), but is 20 percent larger than that of Nussbaumer and Storey (1978). The effective collision mixing rate coefficient among the fine structure levels of 3Po and the combined quenching and charge transfer rate coefficients out of the 3Po1 level with the CO source gas have also been measured.

  18. A short note on measuring subjective life expectancy: survival probabilities versus point estimates.

    PubMed

    Rappange, David R; van Exel, Job; Brouwer, Werner B F

    2017-01-01

    Understanding subjective longevity expectations is important, but measurement is not straightforward. Two common elicitation formats are the direct measurement of a subjective point estimate of life expectancy and the assessment of survival probabilities to a range of target ages. This study presents one of the few direct comparisons of these two methods. Results from a representative sample of the Dutch population indicate that respondents on average gave higher estimates of longevity using survival probabilities (83.6 years) compared to point estimates (80.2 years). Individual differences between elicitation methods were smaller for younger respondents and for respondents with a higher socioeconomic status. The correlation between the subjective longevity estimations was moderate, but their associations with respondents' characteristics were similar. Our results are in line with existing literature and suggest that findings from both elicitation methods may not be directly comparable, especially in certain subgroups of the population. Implications of inconsistent and focal point answers, rounding and anchoring require further attention. More research on the measurement of subjective expectations is required.

  19. Review of measurement and testing problems. [of aircraft emissions

    NASA Technical Reports Server (NTRS)

    1976-01-01

    Good instrumentation was required to obtain reliable and repeatable baseline data. Problems that were encountered in developing such a total system were: (1) accurate airflow measurement, (2) precise fuel flow measurement, and (3) the instrumentation used for pollutant measurement was susceptible to frequent malfunctions. Span gas quality had a significant effect on emissions test results. The Spindt method was used in the piston aircraft emissions program. The Spindt method provided a comparative computational procedure for fuel/air ratio based on measured emissions concentrations.

  20. Measurement of nano particle adhesion by atomic force microscopy using probability theory based analysis

    NASA Astrophysics Data System (ADS)

    Geiger, D.; Schrezenmeier, I.; Roos, M.; Neckernuss, T.; Lehn, M.; Marti, O.

    2017-05-01

    We present a method to detect adhesive forces of nano particles by analysis of the distribution of measured lateral forces. The measurement protocol is suitable for all types of atomic force microscopes with a lateral force channel. Lateral forces are measured, in constant normal force contact mode, by scanning of substrates decorated with nano beads. By using probability theory, geometry based measurement errors are compensated and the real adhesion force is determined within a given confidence interval. The theoretical model can be adapted for particles with arbitrary shape and distribution of adhesion forces. It is applied to the adhesion problem of spherical particles with a Gaussian distribution of adhesion forces. We analyze the measured force distribution qualitatively and quantitatively. The theory predicts a systematic underestimation of the mean value of any particle adhesion measurement done by lateral pushing. Real measurement data of 50 nm diameter silica nano beads on silicon substrate is used to test the theoretical model for plausibility by means of information theory.

  1. Field Measurements of Isoprene and Monoterpene Emission Rates from Trees.

    NASA Astrophysics Data System (ADS)

    Dilts, Stephen Blair

    Monoterpene emission rates were measured by a branch enclosure technique from Pinus ponderosa in central Oregon in the early summer and fall along with photosynthesis and monoterpene needle concentrations. beta -pinene, Delta^3-carene, and alpha-pinene were the major constituents of the emissions with smaller amounts of myrcene, limonene, and beta-phellandrene. The emission rates of alpha-pinene and beta-pinene were highly correlated with their needle concentrations, while those of Delta ^3-carene were not. There was no discernible effect on emissions when photosynthesis was water stress limited in the fall, and monoterpene emissions appear to be distinct from short term photosynthetic carbon assimilation. Isoprene emission rates were measured from a Quercus robur on the Washington State University campus in the fall of 1989 and throughout the 1990 growing season, and from a Quercus rubra during most of the 1991 season and occasionally in 1992. The measured emission rates showed distinct seasonal patterns which could not be explained by temperature or light. Emission rates were initially low early in the season when the leaves were immature. Rates increased rapidly after leaf maturity to a maximum value and then declined over the rest of the season. Evidence suggests that the rate and magnitude of this decline depends on stresses on the tree. Isoprene emission rates were measured from several species near Oak Ridge, Tennessee. The mean normalized isoprene emission rate from the branch enclosure was compared to the rate measured from a Q. alba leaf in a light and temperature controlled cuvette. The branch enclosure result for Q. alba was about 65% lower than the mean leaf cuvette measurement. This difference appears be due to shading of leaves within the branch enclosure. A comparison was also made between the normalized branch enclosure results and normalized canopy isoprene flux measured by a micrometeorological gradient method with generally good agreement.

  2. Object Tracking Using Local Multiple Features and a Posterior Probability Measure

    PubMed Central

    Guo, Wenhua; Feng, Zuren; Ren, Xiaodong

    2017-01-01

    Object tracking has remained a challenging problem in recent years. Most of the trackers can not work well, especially when dealing with problems such as similarly colored backgrounds, object occlusions, low illumination, or sudden illumination changes in real scenes. A centroid iteration algorithm using multiple features and a posterior probability criterion is presented to solve these problems. The model representation of the object and the similarity measure are two key factors that greatly influence the performance of the tracker. Firstly, this paper propose using a local texture feature which is a generalization of the local binary pattern (LBP) descriptor, which we call the double center-symmetric local binary pattern (DCS-LBP). This feature shows great discrimination between similar regions and high robustness to noise. By analyzing DCS-LBP patterns, a simplified DCS-LBP is used to improve the object texture model called the SDCS-LBP. The SDCS-LBP is able to describe the primitive structural information of the local image such as edges and corners. Then, the SDCS-LBP and the color are combined to generate the multiple features as the target model. Secondly, a posterior probability measure is introduced to reduce the rate of matching mistakes. Three strategies of target model update are employed. Experimental results show that our proposed algorithm is effective in improving tracking performance in complicated real scenarios compared with some state-of-the-art methods. PMID:28362345

  3. Isotropic probability measures in infinite dimensional spaces: Inverse problems/prior information/stochastic inversion

    NASA Technical Reports Server (NTRS)

    Backus, George

    1987-01-01

    Let R be the real numbers, R(n) the linear space of all real n-tuples, and R(infinity) the linear space of all infinite real sequences x = (x sub 1, x sub 2,...). Let P sub n :R(infinity) approaches R(n) be the projection operator with P sub n (x) = (x sub 1,...,x sub n). Let p(infinity) be a probability measure on the smallest sigma-ring of subsets of R(infinity) which includes all of the cylinder sets P sub n(-1) (B sub n), where B sub n is an arbitrary Borel subset of R(n). Let p sub n be the marginal distribution of p(infinity) on R(n), so p sub n(B sub n) = p(infinity)(P sub n to the -1(B sub n)) for each B sub n. A measure on R(n) is isotropic if it is invariant under all orthogonal transformations of R(n). All members of the set of all isotropic probability distributions on R(n) are described. The result calls into question both stochastic inversion and Bayesian inference, as currently used in many geophysical inverse problems.

  4. An exacting transition probability measurement - a direct test of atomic many-body theories

    NASA Astrophysics Data System (ADS)

    Dutta, Tarun; de Munshi, Debashis; Yum, Dahyun; Rebhi, Riadh; Mukherjee, Manas

    2016-07-01

    A new protocol for measuring the branching fraction of hydrogenic atoms with only statistically limited uncertainty is proposed and demonstrated for the decay of the P3/2 level of the barium ion, with precision below 0.5%. Heavy hydrogenic atoms like the barium ion are test beds for fundamental physics such as atomic parity violation and they also hold the key to understanding nucleo-synthesis in stars. To draw definitive conclusion about possible physics beyond the standard model by measuring atomic parity violation in the barium ion it is necessary to measure the dipole transition probabilities of low-lying excited states with a precision better than 1%. Furthermore, enhancing our understanding of the barium puzzle in barium stars requires branching fraction data for proper modelling of nucleo-synthesis. Our measurements are the first to provide a direct test of quantum many-body calculations on the barium ion with a precision below one percent and more importantly with no known systematic uncertainties. The unique measurement protocol proposed here can be easily extended to any decay with more than two channels and hence paves the way for measuring the branching fractions of other hydrogenic atoms with no significant systematic uncertainties.

  5. An exacting transition probability measurement - a direct test of atomic many-body theories

    PubMed Central

    Dutta, Tarun; De Munshi, Debashis; Yum, Dahyun; Rebhi, Riadh; Mukherjee, Manas

    2016-01-01

    A new protocol for measuring the branching fraction of hydrogenic atoms with only statistically limited uncertainty is proposed and demonstrated for the decay of the P3/2 level of the barium ion, with precision below 0.5%. Heavy hydrogenic atoms like the barium ion are test beds for fundamental physics such as atomic parity violation and they also hold the key to understanding nucleo-synthesis in stars. To draw definitive conclusion about possible physics beyond the standard model by measuring atomic parity violation in the barium ion it is necessary to measure the dipole transition probabilities of low-lying excited states with a precision better than 1%. Furthermore, enhancing our understanding of the barium puzzle in barium stars requires branching fraction data for proper modelling of nucleo-synthesis. Our measurements are the first to provide a direct test of quantum many-body calculations on the barium ion with a precision below one percent and more importantly with no known systematic uncertainties. The unique measurement protocol proposed here can be easily extended to any decay with more than two channels and hence paves the way for measuring the branching fractions of other hydrogenic atoms with no significant systematic uncertainties. PMID:27432734

  6. Method for emissivity measurement of semitransparent coatings at ambient temperature.

    PubMed

    Honnerová, Petra; Martan, Jiří; Veselý, Zdeněk; Honner, Milan

    2017-05-03

    Coatings deposited on a material surface are effective way of changing its surface properties. For increasing or decreasing radiation heat transfer, coatings with high or low emissivity are used. Measurement of spectral emissivity is a fundamental step to effective use of coatings for this application. Up to now the measurement methods are focused on bulk samples and mainly opaque ones. Here we present a method enabling measurement of emissivity of semitransparent coating itself, although it is deposited on a substrate. The method is based on measurement of transmittance and reflectance using an integration sphere system and Fourier transform infrared (FTIR) spectrometer for samples with two different coating thicknesses deposited on transparent substrates. Measured transmittance of the coating indicates spectral regions of potential emissivity differences using different substrates. From all the measured values, spectral emissivity can be characterized for different coating thicknesses. The spectral range of the method is from 2 μm to 20 μm. The measurement is done at ambient temperature enabling measurement of samples sensitive to heating like biomedical or nanocoatings. The method was validated on known bulk samples and an example of semitransparent coating measurement is shown on high-temperature high-emissivity coating.

  7. Direct comparison of defect ensembles extracted from damage probability and raster scan measurements

    SciTech Connect

    Batavičiūtė, G. Ščiuka, M.; Melninkaitis, A.

    2015-09-14

    The presented study addresses the characterization of nanometer sized defects acting as damage precursors in nanosecond laser pulse duration regime. Two approaches are used to extract distributions of localized damage precursors, namely, damage probability and damage density measurements. Testing is performed on uncoated and SiO{sub 2} monolayer film deposited fused silica substrate exposed with pulsed UV irradiation (355 nm, 4.8 ns). Then, a direct comparison of damage precursor ensembles obtained from both methods is carried out. Our analysis indicates apparent differences between both methods that are discussed in detail. Contamination by ablation products is identified as one of the key factors that influence damage density measurements.

  8. A new measuring method to determine material spectral emissivity

    NASA Astrophysics Data System (ADS)

    Smetana, W.; Reicher, R.

    1998-05-01

    Emissivity is a measure of how well a real surface can radiate energy as compared with a blackbody. This characteristic radiative number is usually determined by means of optical pyrometry. By contrast an indirect measurement method has been developed which enables the determination of the normal spectral emissivity of various materials at a specific wavelength. A heat flow induced in a test body by the absorbed irradiation of a laser beam may be correlated with the spectral emissivity of its surface. The theory of the measuring principle is discussed and the feasibility of the method evaluated by means of practical experiments utilizing a thermopile built up using a thick film technique.

  9. Area Source Emission Measurements Using EPA OTM 10

    EPA Science Inventory

    Measurement of air pollutant emissions from area and non-point sources is an emerging environmental concern. Due to the spatial extent and non-homogenous nature of these sources, assessment of fugitive emissions using point sampling techniques can be difficult. To help address th...

  10. Area Source Emission Measurements Using EPA OTM 10

    EPA Science Inventory

    Measurement of air pollutant emissions from area and non-point sources is an emerging environmental concern. Due to the spatial extent and non-homogenous nature of these sources, assessment of fugitive emissions using point sampling techniques can be difficult. To help address th...

  11. 40 CFR 86.1837-01 - Rounding of emission measurements.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 19 2011-07-01 2011-07-01 false Rounding of emission measurements. 86.1837-01 Section 86.1837-01 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR...-Duty Trucks, and Complete Otto-Cycle Heavy-Duty Vehicles § 86.1837-01 Rounding of emission...

  12. Characterization and measurement of VOC emissions from silage

    USDA-ARS?s Scientific Manuscript database

    There is growing concern in the U.S. regarding the emission of volatile organic compounds (VOCs) from farms and their contribution to smog formation near ozone non-attainment areas. The few studies that have measured VOC emissions have identified mixed feed and the exposed silage face as major farm ...

  13. Measurement and analysis related to infrared emissions

    NASA Astrophysics Data System (ADS)

    Murphy, R. E.; Bruce, M. H.; Green, B. D.; Vanasse, G. A.

    1994-09-01

    PL/GPO field programs, CIRRIS-lA, EXCEDE III, FISTA and others have collected interferometer data i.e., interferograms, which were Fourier transformed to recover spectral information. Specific analysis has been performed to ascertain fundamental properties regarding the nature of the earth/atmosphere emissions. For the CIRRIS-1A nadir viewing interferometer data, fundamental relations regarding resolution limitations imposed by the finite character of the data are presented. Chromatic and achromatic sources are considered with conclusions on increasing spatial resolution. An extensive documentation on the earth/atmosphere ultraviolet radiation backgrounds is provided. Transformed EXCEDE III interferograms yielding high resolution spectra of electron (18 amp, 2.5 keV) irradiated air over 85 to 115 km are presented. The emission characteristics of many species are reveled including NO(+) (Delta v =1) with over 40 vibration-rotation lines isolated. Energy efficiency of NO(+) (Delta v= 1) photon production is derived. A computer model of electron impacting air was generated to follow radiation history of NO+. Detailed reaction rates have been derived for the nacient distribution of N(+) + O2 yields NO(+)(v).

  14. Predicting vehicular emissions in high spatial resolution using pervasively measured transportation data and microscopic emissions model

    SciTech Connect

    Nyhan, Marguerite; Sobolevsky, Stanislav; Kang, Chaogui; Robinson, Prudence; Corti, Andrea; Szell, Michael; Streets, David; Lu, Zifeng; Britter, Rex; Barrett, Steven R. H.; Ratti, Carlo

    2016-06-07

    Air pollution related to traffic emissions pose an especially significant problem in cities; this is due to its adverse impact on human health and well-being. Previous studies which have aimed to quantify emissions from the transportation sector have been limited by either simulated or coarsely resolved traffic volume data. Emissions inventories form the basis of urban pollution models, therefore in this study, Global Positioning System (GPS) trajectory data from a taxi fleet of over 15,000 vehicles were analyzed with the aim of predicting air pollution emissions for Singapore. This novel approach enabled the quantification of instantaneous drive cycle parameters in high spatio-temporal resolution, which provided the basis for a microscopic emissions model. Carbon dioxide (CO2), nitrogen oxides (NOx), volatile organic compounds (VOCs) and particulate matter (PM) emissions were thus estimated. Highly localized areas of elevated emissions levels were identified, with a spatio-temporal precision not possible with previously used methods for estimating emissions. Relatively higher emissions areas were mainly concentrated in a few districts that were the Singapore Downtown Core area, to the north of the central urban region and to the east of it. Daily emissions quantified for the total motor vehicle population of Singapore were found to be comparable to another emissions dataset Results demonstrated that high resolution spatio-temporal vehicle traces detected using GPS in large taxi fleets could be used to infer highly localized areas of elevated acceleration and air pollution emissions in cities, and may become a complement to traditional emission estimates, especially in emerging cities and countries where reliable fine-grained urban air quality data is not easily available. This is the first study of its kind to investigate measured microscopic vehicle movement in tandem with microscopic emissions modeling for a substantial study domain.

  15. Predicting vehicular emissions in high spatial resolution using pervasively measured transportation data and microscopic emissions model

    NASA Astrophysics Data System (ADS)

    Nyhan, Marguerite; Sobolevsky, Stanislav; Kang, Chaogui; Robinson, Prudence; Corti, Andrea; Szell, Michael; Streets, David; Lu, Zifeng; Britter, Rex; Barrett, Steven R. H.; Ratti, Carlo

    2016-09-01

    Air pollution related to traffic emissions pose an especially significant problem in cities; this is due to its adverse impact on human health and well-being. Previous studies which have aimed to quantify emissions from the transportation sector have been limited by either simulated or coarsely resolved traffic volume data. Emissions inventories form the basis of urban pollution models, therefore in this study, Global Positioning System (GPS) trajectory data from a taxi fleet of over 15,000 vehicles were analyzed with the aim of predicting air pollution emissions for Singapore. This novel approach enabled the quantification of instantaneous drive cycle parameters in high spatio-temporal resolution, which provided the basis for a microscopic emissions model. Carbon dioxide (CO2), nitrogen oxides (NOx), volatile organic compounds (VOCs) and particulate matter (PM) emissions were thus estimated. Highly localized areas of elevated emissions levels were identified, with a spatio-temporal precision not possible with previously used methods for estimating emissions. Relatively higher emissions areas were mainly concentrated in a few districts that were the Singapore Downtown Core area, to the north of the central urban region and to the east of it. Daily emissions quantified for the total motor vehicle population of Singapore were found to be comparable to another emissions dataset. Results demonstrated that high-resolution spatio-temporal vehicle traces detected using GPS in large taxi fleets could be used to infer highly localized areas of elevated acceleration and air pollution emissions in cities, and may become a complement to traditional emission estimates, especially in emerging cities and countries where reliable fine-grained urban air quality data is not easily available. This is the first study of its kind to investigate measured microscopic vehicle movement in tandem with microscopic emissions modeling for a substantial study domain.

  16. Aircraft measurements of microwave emission from Arctic Sea ice

    USGS Publications Warehouse

    Wilheit, T.; Nordberg, W.; Blinn, J.; Campbell, W.; Edgerton, A.

    1971-01-01

    Measurements of the microwave emission from Arctic Sea ice were made with aircraft at 8 wavelengths ranging from 0.510 to 2.81 cm. The expected contrast in emissivities between ice and water was observed at all wavelengths. Distributions of sea ice and open water were mapped from altitudes up to 11 km in the presence of dense cloud cover. Different forms of ice also exhibited strong contrasts in emissivity. Emissivity differences of up to 0.2 were observed between two types of ice at the 0.811-cm wavelength. The higher emissivity ice type is tentatively identified as having been formed more recently than the lower emissivity ice. ?? 1971.

  17. NOx emission trends in megacities derived from satellite measurements

    NASA Astrophysics Data System (ADS)

    Konovalov, Igor; Beekmann, Matthias; Richter, Andreas

    2010-05-01

    The effects of air pollutant emissions on both local air quality in megacities and composition of the atmosphere on regional and global scales are currently an important issue of atmospheric researches. In order to properly evaluate these effects, atmospheric models should be provided with accurate information on emissions of major air pollutants. However, such information is frequently very uncertain, as it is documented in literature. The quantification of emissions and related effects is an especially difficult task in the case of developing countries. Recently, it has been demonstrated that satellite measurements of nitrogen dioxide (NO2) can be used as a source of independent information on NOx emissions. In particular, the satellite measurements were used in our earlier studies to improve spatial allocation of NOx emissions, to estimate multi-annual changes of NOx emissions on regional scales and to validate data of traditional emission inventories (see Ref. 1, 2). The goals of the present study are (1) developing an efficient method for estimation of NOx emissions trend in megacity regions by using satellite measurements and an inverse modeling technique and (2) obtaining independent estimates of NOx emission trends in several megacities in Europe and the Middle East in the period from 1996 to 2008. The study is based on the synergetic use of the data for tropospheric NO2 column amounts derived from the long-term GOME and SCIAMACHY measurements and simulations performed by the CHIMERE chemistry transport model. We performed the analysis involving methods of different complexity ranging from estimation of linear trends in the tropospheric NO2 columns retrieved from satellite measurements to evaluation of nonlinear trends in NOx emission estimates obtained with the inverse modeling approach, which, in the given case, involves only very simple and transparent formulations. The most challenging part of the study is the nonlinear trend estimation, which is

  18. Aircraft emission measurements by remote sensing methodologies at airports

    NASA Astrophysics Data System (ADS)

    Schäfer, Klaus; Jahn, Carsten; Sturm, Peter; Lechner, Bernhard; Bacher, Michael

    The emission indices of aircraft engine exhausts from measurements taken under operating conditions, to calculate precisely the emission inventories of airports, are not available up to now. To determine these data, measurement campaigns were performed on idling aircraft at major European airports using non-intrusive spectroscopic methods like Fourier transform infrared spectrometry and differential optical absorption spectroscopy. Emission indices for CO and NO x were calculated and compared to the values given in the International Civil Aviation Organisation (ICAO) database. The emission index for CO for 36 different aircraft engine types and for NO x (24 different engine types) were determined. It was shown that for idling aircraft, CO emissions are underestimated using the ICAO database. The emission indices for NO x determined in this work are lower than given in the ICAO database. In addition, a high variance of emission indices in each aircraft family and from engine to engine of the same engine type was found. During the same measurement campaigns, the emission indices for CO and NO of eight different types of auxilliary power units were investigated.

  19. Spectral ratio method for measuring emissivity

    USGS Publications Warehouse

    Watson, K.

    1992-01-01

    The spectral ratio method is based on the concept that although the spectral radiances are very sensitive to small changes in temperature the ratios are not. Only an approximate estimate of temperature is required thus, for example, we can determine the emissivity ratio to an accuracy of 1% with a temperature estimate that is only accurate to 12.5 K. Selecting the maximum value of the channel brightness temperatures is an unbiased estimate. Laboratory and field spectral data are easily converted into spectral ratio plots. The ratio method is limited by system signal:noise and spectral band-width. The images can appear quite noisy because ratios enhance high frequencies and may require spatial filtering. Atmospheric effects tend to rescale the ratios and require using an atmospheric model or a calibration site. ?? 1992.

  20. Measurements of aircraft emissions indices at airports passive remote sensing

    NASA Astrophysics Data System (ADS)

    Schaefer, Klaus; Jahn, Carsten; Sturm, Peter J.; Lechner, Bernhard; Bacher, Michael

    2003-04-01

    The emission indices of aircraft engine exhausts to calculate precisely the emissions inventories of airports are not available up to now from measurements taken under operating conditions. To determine these data no installations nearby or behind the aircraft are possible at airports. That's why measurements by FTIR emission spectrometry were performed by the IMK-IFU with a spectrometer installed in a van and with total measurement time at one thrust level of about 1 minute to determine CO, NO and CO2. The FTIR instrument telescope was aligned to the engine nozzle exit of standing aircraft. A DOAS and a FTIR spectrometer with globar were used for simultaneous open-path measurements of NO, NO2, CO, CO2 and speciated hydrocarbons behind the aircraft by the TUG-VKMB. Measurement results at the airports Frankfurt/Main, London-Heathrow and Vienna are presented. The methods are evaluated by comparing CO emission indices from passive measurements with open-path data. The measured emission indices of CO show slightly higher values than the International Civil Aviation Organisation data sheets but less values for NOx emissions. A fruitful co-operation with the airlines AUA, BA and DLH as well as the airport authorities in Vienna and London-Heathrow supported this work which is financed from EC.

  1. Administrative data measured surgical site infection probability within 30 days of surgery in elderly patients.

    PubMed

    van Walraven, Carl; Jackson, Timothy D; Daneman, Nick

    2016-09-01

    Elderly patients are inordinately affected by surgical site infections (SSIs). This study derived and internally validated a model that used routinely collected health administrative data to measure the probability of SSI in elderly patients within 30 days of surgery. All people exceeding 65 years undergoing surgery from two hospitals with known SSI status were linked to population-based administrative data sets in Ontario, Canada. We used bootstrap methods to create a multivariate model that used health administrative data to predict the probability of SSI. Of 3,436 patients, 177 (5.1%) had an SSI. The Elderly SSI Risk Model included six covariates: number of distinct physician fee codes within 30 days of surgery; presence or absence of a postdischarge prescription for an antibiotic; presence or absence of three diagnostic codes; and a previously derived score that gauged SSI risk based on procedure codes. The model was highly explanatory (Nagelkerke's R(2), 0.458), strongly discriminative (C statistic, 0.918), and well calibrated (calibration slope, 1). Health administrative data can effectively determine 30-day risk of SSI risk in elderly patients undergoing a broad assortment of surgeries. External validation is necessary before this can be routinely used to monitor SSIs in the elderly. Copyright © 2016 Elsevier Inc. All rights reserved.

  2. Accurate measurement of the sticking time and sticking probability of Rb atoms on a polydimethylsiloxane coating

    SciTech Connect

    Atutov, S. N. Plekhanov, A. I.

    2015-01-15

    We present the results of a systematic study of Knudsen’s flow of Rb atoms in cylindrical capillary cells coated with a polydimethylsiloxane (PDMS) compound. The purpose of the investigation is to determine the characterization of the coating in terms of the sticking probability and sticking time of Rb on the two types of coating of high and medium viscosities. We report the measurement of the sticking probability of a Rb atom to the coating equal to 4.3 × 10{sup −5}, which corresponds to the number of bounces 2.3 × 10{sup 4} at room temperature. These parameters are the same for the two kinds of PDMS used. We find that at room temperature, the respective sticking times for high-viscosity and medium-viscosity PDMS are 22 ± 3 μs and 49 ± 6 μs. These sticking times are about million times larger than the sticking time derived from the surface Rb atom adsorption energy and temperature of the coating. A tentative explanation of this surprising result is proposed based on the bulk diffusion of the atoms that collide with the surface and penetrate inside the coating. The results can be important in many resonance cell experiments, such as the efficient magnetooptical trapping of rare elements or radioactive isotopes and in experiments on the light-induced drift effect.

  3. Pasture-scale measurement of methane emissions of grazing cattle

    USDA-ARS?s Scientific Manuscript database

    Quantifying methane emission of cattle grazing on southern Great Plains pastures using micrometeorology presents several challenges. Cattle are elevated, mobile point sources of methane, so that knowing their location in relation to atmospheric methane concentration measurements becomes critical. St...

  4. 40 CFR 86.1338-2007 - Emission measurement accuracy.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...) Emission Regulations for New Otto-Cycle and Diesel Heavy-Duty Engines; Gaseous and Particulate Exhaust Test... measured by the oxides of nitrogen analyzer following the analyzer's monthly periodic calibration....

  5. Air Monitoring, Measuring, and Emissions Research

    EPA Pesticide Factsheets

    Measurement research is advancing the ability to determine the composition of sources of air pollution, conduct exposure assessments, improve monitoring capabilities and support public health research.

  6. An information complexity index for probability measures on ℝ with all moments

    NASA Astrophysics Data System (ADS)

    Accardi, Luigi; Barhoumi, Abdessatar; Rhaima, Mohamed

    2016-08-01

    We prove that, each probability meassure on ℝ, with all moments, is canonically associated with (i) a ∗-Lie algebra; (ii) a complexity index labeled by pairs of natural integers. The measures with complexity index (0,K) consist of two disjoint classes: that of all measures with finite support and the semi-circle-arcsine class (the discussion in Sec. 4.1 motivates this name). The class C(μ) = (0, 0) coincides with the δ-measures in the finite support case and includes the semi-circle laws in the infinite support case. In the infinite support case, the class C(μ) = (0, 1) includes the arcsine laws, and the class C(μ) = (0, 2) appeared in central limit theorems of quantum random walks in the sense of Konno. The classes C(μ) = (0,K), with K ≥ 3, do not seem to be present in the literature. The class (1, 0) includes the Gaussian and Poisson measures and the associated ∗-Lie algebra is the Heisenberg algebra. The class (2, 0) includes the non-standard (i.e. neither Gaussian nor Poisson) Meixner distributions and the associated ∗-Lie algebra is a central extension of sl(2, ℝ). Starting from n = 3, the ∗-Lie algebra associated to the class (n, 0) is infinite dimensional and the corresponding classes include the higher powers of the standard Gaussian.

  7. A multitower measurement network estimate of California's methane emissions

    NASA Astrophysics Data System (ADS)

    Jeong, Seongeun; Hsu, Ying-Kuang; Andrews, Arlyn E.; Bianco, Laura; Vaca, Patrick; Wilczak, James M.; Fischer, Marc L.

    2013-10-01

    present an analysis of methane (CH4) emissions using atmospheric observations from five sites in California's Central Valley across different seasons (September 2010 to June 2011). CH4 emissions for spatial regions and source sectors are estimated by comparing measured CH4 mixing ratios with transport model (Weather Research and Forecasting and Stochastic Time-Inverted Lagrangian Transport) predictions based on two 0.1° CH4 (seasonally varying "California-specific" (California Greenhouse Gas Emission Measurements, CALGEM) and a static global (Emission Database for Global Atmospheric Research, release version 42, EDGAR42)) prior emission models. Region-specific Bayesian analyses indicate that for California's Central Valley, the CALGEM- and EDGAR42-based inversions provide consistent annual total CH4 emissions (32.87 ± 2.09 versus 31.60 ± 2.17 Tg CO2eq yr-1; 68% confidence interval (CI), assuming uncorrelated errors between regions). Summing across all regions of California, optimized CH4 emissions are only marginally consistent between CALGEM- and EDGAR42-based inversions (48.35 ± 6.47 versus 64.97 ± 11.85 Tg CO2eq), because emissions from coastal urban regions (where landfill and natural gas emissions are much higher in EDGAR than CALGEM) are not strongly constrained by the measurements. Combining our results with those from a recent study of the South Coast Air Basin narrows the range of estimates to 43-57 Tg CO2eq yr-1 (1.3-1.8 times higher than the current state inventory). These results suggest that the combination of rural and urban measurements will be necessary to verify future changes in California's total CH4 emissions.

  8. A multitower measurement network estimate of California's methane emissions

    SciTech Connect

    Jeong, Seongeun; Hsu, Ying-Kuang; Andrews, Arlyn E.; Bianco, Laura; Vaca, Patrick; Wilczak, James M.; Fischer, Marc L.

    2013-09-20

    In this paper, we present an analysis of methane (CH4) emissions using atmospheric observations from five sites in California's Central Valley across different seasons (September 2010 to June 2011). CH4 emissions for spatial regions and source sectors are estimated by comparing measured CH4 mixing ratios with transport model (Weather Research and Forecasting and Stochastic Time-Inverted Lagrangian Transport) predictions based on two 0.1° CH4 (seasonally varying “California-specific” (California Greenhouse Gas Emission Measurements, CALGEM) and a static global (Emission Database for Global Atmospheric Research, release version 42, EDGAR42)) prior emission models. Region-specific Bayesian analyses indicate that for California's Central Valley, the CALGEM- and EDGAR42-based inversions provide consistent annual total CH4 emissions (32.87 ± 2.09 versus 31.60 ± 2.17 Tg CO2eq yr-1; 68% confidence interval (CI), assuming uncorrelated errors between regions). Summing across all regions of California, optimized CH4 emissions are only marginally consistent between CALGEM- and EDGAR42-based inversions (48.35 ± 6.47 versus 64.97 ± 11.85 Tg CO2eq), because emissions from coastal urban regions (where landfill and natural gas emissions are much higher in EDGAR than CALGEM) are not strongly constrained by the measurements. Combining our results with those from a recent study of the South Coast Air Basin narrows the range of estimates to 43–57 Tg CO2eq yr-1 (1.3–1.8 times higher than the current state inventory). Finally, these results suggest that the combination of rural and urban measurements will be necessary to verify future changes in California's total CH4 emissions.

  9. The differential emission measure of dynamic coronal loops

    NASA Technical Reports Server (NTRS)

    Antiochos, S. K.

    1981-01-01

    The effects of time dependent phenomena, such as flare energization and decay, on the temperature and density structure of the transition region and, in particular, on the form of the differential emission measure are studied. It is found that unlike the case of the static models, the form of the differential emission measure can be used to determine the important physical mechanisms in the dynamic models.

  10. Superthermal electron distribution measurements from polarized electron cyclotron emission

    SciTech Connect

    Luce, T.C.; Efthimion, P.C.; Fisch, N.J.

    1988-06-01

    Measurements of the superthermal electron distribution can be made by observing the polarized electron cyclotron emission. The emission is viewed along a constant magnetic field surface. This simplifies the resonance condition and gives a direct correlation between emission frequency and kinetic energy of the emitting electron. A transformation technique is formulated which determines the anisotropy of the distribution and number density of superthermals at each energy measured. The steady-state distribution during lower hybrid current drive and examples of the superthermal dynamics as the runaway conditions is varied are presented for discharges in the PLT tokamak. 15 refs., 8 figs.

  11. Particulate Measurements and Emissions Characterization of Alternative Fuel Vehicle Exhaust

    SciTech Connect

    Durbin, T. D.; Truex, T. J.; Norbeck, J. M.

    1998-11-19

    The objective of this project was to measure and characterize particulate emissions from light-duty alternative fuel vehicles (AFVs) and equivalent gasoline-fueled vehicles. The project included emission testing of a fleet of 129 gasoline-fueled vehicles and 19 diesel vehicles. Particulate measurements were obtained over Federal Test Procedure and US06 cycles. Chemical characterization of the exhaust particulate was also performed. Overall, the particulate emissions from modern technology compressed natural gas and methanol vehicles were low, but were still comparable to those of similar technology gasoline vehicles.

  12. Investigating rare events with nonequilibrium work measurements. I. Nonequilibrium transition path probabilities.

    PubMed

    Moradi, Mahmoud; Sagui, Celeste; Roland, Christopher

    2014-01-21

    We have developed a formalism for investigating transition pathways and transition probabilities for rare events in biomolecular systems. In this paper, we set the theoretical framework for employing nonequilibrium work relations to estimate the relative reaction rates associated with different classes of transition pathways. Particularly, we derive an extension of Crook's transient fluctuation theorem, which relates the relative transition rates of driven systems in the forward and reverse directions, and allows for the calculation of these relative rates using work measurements (e.g., in Steered Molecular Dynamics). The formalism presented here can be combined with Transition Path Theory to relate the equilibrium and driven transition rates. The usefulness of this framework is illustrated by means of a Gaussian model and a driven proline dimer.

  13. Photoelectron Emission and Lyman Alpha Measurements by the CHAMPS Rockets

    NASA Astrophysics Data System (ADS)

    Sternovsky, Z.; Robertson, S. H.; Dickson, S.; Gausa, M. A.; Friedrich, M.; Horanyi, M.

    2012-12-01

    The daytime CHAMPS (CHarge And mass of Meteoritic smoke ParticleS) sounding rocket carried a suit of instruments for the monitoring of photoemission current and Lyman alpha flux as a function of altitude. The results show that photoemission is significant down to 60-75 km altitude, depending on the photo-emitting surface. Lyman alpha was detected to about 65 km altitude. The daytime CHAMPS rocket launched on 13 October 13:50 UT from the Andøya Rocket Range, Norway. The CHAMPS instruments detected layers of particles, probably of meteoric origin, charged both positive and negative in the 63-93 km altitude range. The CHAMPS payloads were also designed to characterize the plasma environment and thus also carried Faraday rotation antennas and electron and ion probes. Solar UV plays an important role in charge balance for both the rocket body and meteoric smoke particles. Photoelectron emission was monitored by a set of three detectors consisting of an emitting surface (Platinum, Aluminum and Zirconium) biased at -10 V and placed behind a fine grid. The Al and Zr surfaces produced similar signals with photoemission measureable above 75 km altitude. The Pt surface emitted photoelectrons even below 60 km altitude. The different behavior of Pt can possibly be due to exposure to atomic oxygen, though further analysis is necessary. The solar Lyman alpha radiation was measured by a UV photodiode placed behind a pair or filters to reduce the contribution to the signal from visible light. Lyman alpha was detected down to 65 km altitude, which confirms that photo-detachment and photoelectric charging needs to be considered for the charge balance of particle layers in the mesosphere region. All instruments were calibrated at the facilities of the Laboratory for Atmospheric and Space Physics at the University of Colorado.

  14. Quantitative measurement of direct nitrous oxide emissions from microalgae cultivation.

    PubMed

    Fagerstone, Kelly D; Quinn, Jason C; Bradley, Thomas H; De Long, Susan K; Marchese, Anthony J

    2011-11-01

    Although numerous lifecycle assessments (LCA) of microalgae-based biofuels have suggested net reductions of greenhouse gas emissions, limited experimental data exist on direct emissions from microalgae cultivation systems. For example, nitrous oxide (N(2)O) is a potent greenhouse gas that has been detected from microalgae cultivation. However, little quantitative experimental data exist on direct N(2)O emissions from microalgae cultivation, which has inhibited LCA performed to date. In this study, microalgae species Nannochloropsis salina was cultivated with diurnal light-dark cycling using a nitrate nitrogen source. Gaseous N(2)O emissions were quantitatively measured using Fourier transform infrared spectrometry. Under a nitrogen headspace (photobioreactor simulation), the reactors exhibited elevated N(2)O emissions during dark periods, and reduced N(2)O emissions during light periods. Under air headspace conditions (open pond simulation), N(2)O emissions were negligible during both light and dark periods. Results show that N(2)O production was induced by anoxic conditions when nitrate was present, suggesting that N(2)O was produced by denitrifying bacteria within the culture. The presence of denitrifying bacteria was verified through PCR-based detection of norB genes and antibiotic treatments, the latter of which substantially reduced N(2)O emissions. Application of these results to LCA and strategies for growth management to reduce N(2)O emissions are discussed.

  15. Measurements of Gas and Particle Emissions From Commercial Marine Vessels

    NASA Astrophysics Data System (ADS)

    Williams, E.; Lerner, B.; Quinn, P.; Bates, T.

    2005-12-01

    Commercial marine vessels are powered by large diesel engines with power outputs up to 80 MW and typically consume high-sulfur fuel. They can be viewed as small floating power plants that produce large quantities of nitrogen oxides, sulfur dioxide, and particles. Thus these vessels can be significant pollution sources globally, regionally (e.g., coastal shipping lanes) and locally (e.g., ports). Assessment of this significance is done via emission inventory modelling in which activity factors are combined with emission factors to produce estimates of source strengths over different scales. This work addresses potential uncertainties in marine vessel emission factors. Measurements of trace gases and particles in the exhaust plumes from commercial marine vessels were made from the NOAA research vessel Ronald H. Brown during the 2002 and 2004 NEAQS missions in the Gulf of Maine. Numerous encounters with these exhaust plumes provided the opportunity to examine emission of NOx, SO2, CO, CO2, particle number, and particle composition from these ships. Data from these studies suggest that emission factors used in current inventories may not adequately represent emission from ships under actual operating conditions. For example, our NOy data indicate that current inventories may overestimate these emissions by 20-30%. Though emission of CO by marine diesel engines is typically very low, several encounters with diesel-powered fishing vessel exhaust plumes showed high levels of CO which may indicate that engine maintenance plays a large role in the actual emissions from these vessels. Particle composition data from a container ship plume indicate that sub-micron mass was principally organic and not sulfate while literature data suggest a strong dependence of particle mass emission on the fuel sulfur level. In this presentation we will discuss the emission factors determined from our data and the importance of marine vessel emissions at different scales.

  16. Measurements of fusion product emission profiles in tokamaks

    SciTech Connect

    Strachan, J.D.; Heidbrink, W.W.; Hendel, H.W.; Lovberg, J.; Murphy, T.J.; Nieschmidt, E.B.; Tait, G.D.; Zweben, S.J.

    1986-11-01

    The techniques and results of fusion product emission profile measurements are reviewed. While neutron source strength profile measurements have been attempted by several methods, neutron scattering is a limitation to the results. Profile measurements using charged fusion products have recently provided an alternative since collimation is much easier for the charged particles.

  17. Determining neutron capture cross sections with the Surrogate Reaction Technique: Measuring decay probabilities with STARS

    SciTech Connect

    Church, J A; Ahle, L; Bernstein, L A; Cooper, J; Dietrich, F S; Escher, J; Forssen, C; Ai, H; Amro, H; Babilon, M; Beausang, C; Caggiano, J; Heinz, A; Hughes, R; McCutchan, E; Meyer, D; Plettner, C; Ressler, J; Zamfir, V

    2004-07-14

    Neutron-induced reaction cross sections are sometimes difficult to measure due to target or beam limitations. For two-step reactions proceeding through an equilibrated intermediate state, an alternate ''surrogate reaction'' technique can be applicable, and is currently undergoing investigation at LLNL. Measured decay probabilities for the intermediate nucleus formed in a light-ion reaction can be combined with optical-model calculations for the formation of the same intermediate nucleus via the neutron-induced reaction. The result is an estimation for overall (n,{gamma}/n/2n) cross sections. As a benchmark, the reaction {sup 92}Zr({alpha},{alpha}'), surrogate, for n+{sup 91}Zr, was studied at the A.W. Wright Nuclear Structure Laboratory at Yale. Particles were detected in the silicon telescope STARS (Silicon Telescope Array for Reaction Studies) and {gamma}-ray energies measured with germanium clover detectors from the YRAST (Yale Rochester Array for SpecTroscopy) ball. The experiment and preliminary observations will be discussed.

  18. Determining neutron capture cross sections with the Surrogate Reaction Technique: Measuring decay probabilities with STARS

    NASA Astrophysics Data System (ADS)

    Church, J. A.; Ahle, L.; Bernstein, L. A.; Cooper, J.; Dietrich, F. S.; Escher, J.; Forssen, C.; Ai, H.; Amro, H.; Babilon, M.; et al.

    2005-07-01

    Neutron-induced reaction cross sections are sometimes difficult to measure due to target or beam limitations. For two-step reactions proceeding through an equilibrated intermediate state, an alternate "surrogate reaction" technique [J.D. Cramer and H.C. Britt, Nucl. Sci. Eng. 41, 177 (1970), H.C. Britt and J.B. Wilhelmy, Nucl. Sci. Eng. 72, 222 (1979), W.Younes and H.C. Britt, Phys. Rev. C 67, 024610 (2003)] can be applicable, and is currently undergoing investigation at LLNL. Measured decay probabilities for the intermediate nucleus formed in a light-ion reaction can be combined with optical-model calculations for the formation of the same intermediate nucleus via the neutron-induced reaction. The result is an estimation for overall (n,γ/n/2n) cross sections. As a bench-mark, the reaction 92Zr(α, α'), surrogate for n+91Zr, was studied at the A.W. Wright Nuclear Structure Laboratory at Yale. Particles were detected in the silicon telescope STARS (Silicon Telescope Array for Reaction Studies) and γ-ray energies measured with germanium clover detectors from the YRAST (Yale Rochester Array for SpecTroscopy) ball. The experiment and preliminary observations will be discussed.

  19. Surface temperature measurements of heterogeneous explosives by IR emission

    SciTech Connect

    Henson, B.F.; Funk, D.J.; Dickson, P.M.; Fugard, C.S.; Asay, B.W.

    1998-03-01

    The authors present measurements of the integrated IR emission (1--5 {micro}m) from both the heterogeneous explosive PBX 9501 and pure HMX at calibrated temperatures from 300 C to 2,500 C. The IR power emitted as a function of temperature is that expected of a black body, attenuated by a unique temperature independent constant which the authors report as the thermal emissivity. The authors have utilized this calibration of IR emission in measurements of the surface temperature from PBX 9501 subject to 1 GPa, two dimensional impact, and spontaneous ignition in unconfined cookoff. They demonstrate that the measurement of IR emission in this spectral region provides a temperature probe of sufficient sensitivity to resolve the thermal response from the solid explosive throughout the range of weak mechanical perturbation, prolonged heating to ignition, and combustion.

  20. Surface temperature measurements of heterogeneous explosives by IR emission

    NASA Astrophysics Data System (ADS)

    Henson, B. F.; Funk, D. J.; Dickson, P. M.; Fugard, C. S.; Asay, B. W.

    1998-07-01

    We present measurements of the integrated IR emission (1-5 μm) from both the heterogeneous explosive PBX 9501 and pure HMX at calibrated temperatures from 30 °C to 250 °C. The IR power emitted as a function of temperature is that expected of a black body, attenuated by a unique temperature independent constant which we report as the thermal emissivity. We have utilized this calibration of IR emission in measurements of the surface temperature from PBX 9501 subject to 1 GPa, two dimensional impact, and spontaneous ignition in unconfined cookoff. We demonstrate that the measurement of IR emission in this spectral region provides a temperature probe of sufficient sensitivity to resolve the thermal response from the solid explosive throughout the range of weak mechanical perturbation, prolonged heating to ignition, and combustion.

  1. Power Plant Emission Monitoring in Munich Using Differential Column Measurements

    NASA Astrophysics Data System (ADS)

    Chen, Jia; Nguyen, Hai; Toja-Silva, Francisco; Heinle, Ludwig; Hase, Frank; Butz, André

    2017-04-01

    Differential column measurements using compact Fourier transform spectrometers (EM27/SUN) have shown to be an effective method to determine the greenhouse gas emissions. Citywide measurement campaigns were carried out in Boston, Indianapolis, San Francisco, etc., focusing on city (e.g. emissions from natural gas infrastructure) and local sources. We are particularly working on validating this novel method for attributing and quantifying local emission sources. Optimal strategies are developed for measuring in different seasons with various sun elevations. We have deployed two spectrometers to monitor the CO2 and CH4 emission rates (kg s-1) of a natural gas fired combined heat-and-power plant in Munich, Germany (Heizkraftwerk Süd). We placed our spectrometers in the vicinity (<800 m) of the power plant and measured the differences between the column-averaged dry-air mole fractions at a downwind and a non-downwind site of the power plant (ΔXCO2 and ΔXCH4). Measurements in summer and winter have been carried out. We compared the measured data of ΔXCO2 with the results of a Gaussian plume model and a computational fluid dynamics simulation using OpenFOAM. The determined emission rates agree well with our a priori knowledge of the inflow. In this work, we discuss the accuracy of the differential column measurements for determining power plant emissions and explore their sensitivities to meteorological and model parameters. In addition, we present measurement strategies and experimental design criteria for different meteorological conditions and time of the year, including winter when the sun elevation is low and the column inclination becomes very important. Differential column measurements using compact spectrometers are shown to be a reliable method to monitor power plant emissions.

  2. Micrometeorological methods for measurements of mercury emissions over contaminated soils

    SciTech Connect

    Kim, K.H.; Lindberg, S.E.; Hanson, P.J.; Owens, J.; Myers, T.P.

    1993-12-31

    As part of a larger study involving development and application of field and laboratory methods (micrometeorological, dynamic enclosure chamber, and controlled laboratory chamber methods) to measure the air/surface exchange of Hg vapor, we performed a series of preliminary measurements over contaminated soils. From March--April 1993, we used the modified Bowen ratio (MBR) method to measure emission rates of mercury over a floodplain contaminated with mercury near Oak Ridge, TN. The mercury emission rates measured from contaminated EFPC soils using the MBR method during early spring show that (1) in all cases, the contaminated soils acted as a source of mercury to the atmosphere with source strengths ranging from 17 to 160 ng m{sup {minus}2} h{sup {minus}1}; and (2) the strengths of mercury emissions can be greatly influenced by the combined effects of surface soil temperature, residence time of air masses over the source area, and turbulence conditions. The mercury fluxes measured in a controlled flow chamber indicate that contaminated soils can exhibit up to an order of magnitude higher emission rates of Hg under conditions of elevated soil temperature, soil structure disturbance, and high turbulence. Mercury emissions from contaminated soils exceeded emissions from background soils by one to two orders of magnitude.

  3. Subsurface Emission Effects in AMSR-E Measurements: Implications for Land Surface Microwave Emissivity Retrieval

    NASA Technical Reports Server (NTRS)

    Galantowicz, John F.; Moncet, Jean-Luc; Liang, Pan; Lipton, Alan E.; Uymin, Gennady; Prigent, Catherine; Grassotti, Christopher

    2011-01-01

    An analysis of land surface microwave emission time series shows that the characteristic diurnal signature associated with subsurface emission in sandy deserts carry over to arid and semi-arid region worldwide. Prior work found that diurnal variation of Special Sensor Microwave/Imager (SSM/I) brightness temperatures in deserts was small relative to International Satellite Cloud Climatology Project land surface temperature (LST) variation and that the difference varied with surface type and was largest in sand sea regions. Here we find more widespread subsurface emission effects in Advanced Microwave Scanning Radiometer-EOS (AMSR-E) measurements. The AMSR-E orbit has equator crossing times near 01:30 and 13 :30 local time, resulting in sampling when near-surface temperature gradients are likely to be large and amplifying the influence of emission depth on effective emitting temperature relative to other factors. AMSR-E measurements are also temporally coincident with Moderate Resolution Imaging Spectroradiometer (MODIS) LST measurements, eliminating time lag as a source of LST uncertainty and reducing LST errors due to undetected clouds. This paper presents monthly global emissivity and emission depth index retrievals for 2003 at 11, 19, 37, and 89 GHz from AMSR-E, MODIS, and SSM/I time series data. Retrieval model fit error, stability, self-consistency, and land surface modeling results provide evidence for the validity of the subsurface emission hypothesis and the retrieval approach. An analysis of emission depth index, emissivity, precipitation, and vegetation index seasonal trends in northern and southern Africa suggests that changes in the emission depth index may be tied to changes in land surface moisture and vegetation conditions

  4. Subsurface Emission Effects in AMSR-E Measurements: Implications for Land Surface Microwave Emissivity Retrieval

    NASA Technical Reports Server (NTRS)

    Galantowicz, John F.; Moncet, Jean-Luc; Liang, Pan; Lipton, Alan E.; Uymin, Gennady; Prigent, Catherine; Grassotti, Christopher

    2011-01-01

    An analysis of land surface microwave emission time series shows that the characteristic diurnal signature associated with subsurface emission in sandy deserts carry over to arid and semi-arid region worldwide. Prior work found that diurnal variation of Special Sensor Microwave/Imager (SSM/I) brightness temperatures in deserts was small relative to International Satellite Cloud Climatology Project land surface temperature (LST) variation and that the difference varied with surface type and was largest in sand sea regions. Here we find more widespread subsurface emission effects in Advanced Microwave Scanning Radiometer-EOS (AMSR-E) measurements. The AMSR-E orbit has equator crossing times near 01:30 and 13 :30 local time, resulting in sampling when near-surface temperature gradients are likely to be large and amplifying the influence of emission depth on effective emitting temperature relative to other factors. AMSR-E measurements are also temporally coincident with Moderate Resolution Imaging Spectroradiometer (MODIS) LST measurements, eliminating time lag as a source of LST uncertainty and reducing LST errors due to undetected clouds. This paper presents monthly global emissivity and emission depth index retrievals for 2003 at 11, 19, 37, and 89 GHz from AMSR-E, MODIS, and SSM/I time series data. Retrieval model fit error, stability, self-consistency, and land surface modeling results provide evidence for the validity of the subsurface emission hypothesis and the retrieval approach. An analysis of emission depth index, emissivity, precipitation, and vegetation index seasonal trends in northern and southern Africa suggests that changes in the emission depth index may be tied to changes in land surface moisture and vegetation conditions

  5. Probing the radio emission from air showers with polarization measurements

    NASA Astrophysics Data System (ADS)

    Aab, A.; Abreu, P.; Aglietta, M.; Ahlers, M.; Ahn, E. J.; Albuquerque, I. F. M.; Allekotte, I.; Allen, J.; Allison, P.; Almela, A.; Alvarez Castillo, J.; Alvarez-Muñiz, J.; Alves Batista, R.; Ambrosio, M.; Aminaei, A.; Anchordoqui, L.; Andringa, S.; Antičić, T.; Aramo, C.; Arqueros, F.; Asorey, H.; Assis, P.; Aublin, J.; Ave, M.; Avenier, M.; Avila, G.; Badescu, A. M.; Barber, K. B.; Bardenet, R.; Bäuml, J.; Baus, C.; Beatty, J. J.; Becker, K. H.; Bellido, J. A.; BenZvi, S.; Berat, C.; Bertou, X.; Biermann, P. L.; Billoir, P.; Blanco, F.; Blanco, M.; Bleve, C.; Blümer, H.; Boháčová, M.; Boncioli, D.; Bonifazi, C.; Bonino, R.; Borodai, N.; Brack, J.; Brancus, I.; Brogueira, P.; Brown, W. C.; Buchholz, P.; Bueno, A.; Buscemi, M.; Caballero-Mora, K. S.; Caccianiga, B.; Caccianiga, L.; Candusso, M.; Caramete, L.; Caruso, R.; Castellina, A.; Cataldi, G.; Cazon, L.; Cester, R.; Cheng, S. H.; Chiavassa, A.; Chinellato, J. A.; Chudoba, J.; Cilmo, M.; Clay, R. W.; Cocciolo, G.; Colalillo, R.; Collica, L.; Coluccia, M. R.; Conceição, R.; Contreras, F.; Cooper, M. J.; Coutu, S.; Covault, C. E.; Criss, A.; Cronin, J.; Curutiu, A.; Dallier, R.; Daniel, B.; Dasso, S.; Daumiller, K.; Dawson, B. R.; de Almeida, R. M.; De Domenico, M.; de Jong, S. J.; De La Vega, G.; de Mello Junior, W. J. M.; de Mello Neto, J. R. T.; De Mitri, I.; de Souza, V.; de Vries, K. D.; del Peral, L.; Deligny, O.; Dembinski, H.; Dhital, N.; Di Giulio, C.; Di Matteo, A.; Diaz, J. C.; Díaz Castro, M. L.; Diep, P. N.; Diogo, F.; Dobrigkeit, C.; Docters, W.; D'Olivo, J. C.; Dong, P. N.; Dorofeev, A.; dos Anjos, J. C.; Dova, M. T.; Ebr, J.; Engel, R.; Erdmann, M.; Escobar, C. O.; Espadanal, J.; Etchegoyen, A.; Facal San Luis, P.; Falcke, H.; Fang, K.; Farrar, G.; Fauth, A. C.; Fazzini, N.; Ferguson, A. P.; Fick, B.; Figueira, J. M.; Filevich, A.; Filipčič, A.; Foerster, N.; Fox, B. D.; Fracchiolla, C. E.; Fraenkel, E. D.; Fratu, O.; Fröhlich, U.; Fuchs, B.; Gaior, R.; Gamarra, R. F.; Gambetta, S.; García, B.; Garcia Roca, S. T.; Garcia-Gamez, D.; Garcia-Pinto, D.; Garilli, G.; Gascon Bravo, A.; Gemmeke, H.; Ghia, P. L.; Giammarchi, M.; Giller, M.; Gitto, J.; Glaser, C.; Glass, H.; Gomez Albarracin, F.; Gómez Berisso, M.; Gómez Vitale, P. F.; Gonçalves, P.; Gonzalez, J. G.; Gookin, B.; Gorgi, A.; Gorham, P.; Gouffon, P.; Grebe, S.; Griffith, N.; Grillo, A. F.; Grubb, T. D.; Guardincerri, Y.; Guarino, F.; Guedes, G. P.; Hansen, P.; Harari, D.; Harrison, T. A.; Harton, J. L.; Haungs, A.; Hebbeker, T.; Heck, D.; Herve, A. E.; Hill, G. C.; Hojvat, C.; Hollon, N.; Holt, E.; Homola, P.; Hörandel, J. R.; Horvath, P.; Hrabovský, M.; Huber, D.; Huege, T.; Insolia, A.; Isar, P. G.; Jansen, S.; Jarne, C.; Josebachuili, M.; Kadija, K.; Kambeitz, O.; Kampert, K. H.; Karhan, P.; Kasper, P.; Katkov, I.; Kégl, B.; Keilhauer, B.; Keivani, A.; Kemp, E.; Kieckhafer, R. M.; Klages, H. O.; Kleifges, M.; Kleinfeller, J.; Knapp, J.; Krause, R.; Krohm, N.; Krömer, O.; Kruppke-Hansen, D.; Kuempel, D.; Kunka, N.; La Rosa, G.; LaHurd, D.; Latronico, L.; Lauer, R.; Lauscher, M.; Lautridou, P.; Le Coz, S.; Leão, M. S. A. B.; Lebrun, D.; Lebrun, P.; Leigui de Oliveira, M. A.; Letessier-Selvon, A.; Lhenry-Yvon, I.; Link, K.; López, R.; Lopez Agüera, A.; Louedec, K.; Lozano Bahilo, J.; Lu, L.; Lucero, A.; Ludwig, M.; Lyberis, H.; Maccarone, M. C.; Malacari, M.; Maldera, S.; Maller, J.; Mandat, D.; Mantsch, P.; Mariazzi, A. G.; Marin, V.; Mariş, I. C.; Marquez Falcon, H. R.; Marsella, G.; Martello, D.; Martin, L.; Martinez, H.; Martínez Bravo, O.; Martraire, D.; Masías Meza, J. J.; Mathes, H. J.; Matthews, J.; Matthews, J. A. J.; Matthiae, G.; Maurel, D.; Maurizio, D.; Mayotte, E.; Mazur, P. O.; Medina, C.; Medina-Tanco, G.; Melissas, M.; Melo, D.; Menichetti, E.; Menshikov, A.; Messina, S.; Meyhandan, R.; Mićanović, S.; Micheletti, M. I.; Middendorf, L.; Minaya, I. A.; Miramonti, L.; Mitrica, B.; Molina-Bueno, L.; Mollerach, S.; Monasor, M.; Monnier Ragaigne, D.; Montanet, F.; Morales, B.; Morello, C.; Moreno, J. C.; Mostafá, M.; Moura, C. A.; Muller, M. A.; Müller, G.; Münchmeyer, M.; Mussa, R.; Navarra, G.; Navarro, J. L.; Navas, S.; Necesal, P.; Nellen, L.; Nelles, A.; Neuser, J.; Nhung, P. T.; Niechciol, M.; Niemietz, L.; Niggemann, T.; Nitz, D.; Nosek, D.; Nožka, L.; Oehlschläger, J.; Olinto, A.; Oliveira, M.; Ortiz, M.; Pacheco, N.; Pakk Selmi-Dei, D.; Palatka, M.; Pallotta, J.; Palmieri, N.; Parente, G.; Parra, A.; Pastor, S.; Paul, T.; Pech, M.; PeÂķala, J.; Pelayo, R.; Pepe, I. M.; Perrone, L.; Pesce, R.; Petermann, E.; Petrera, S.; Petrolini, A.; Petrov, Y.; Piegaia, R.; Pierog, T.; Pieroni, P.; Pimenta, M.; Pirronello, V.; Platino, M.; Plum, M.; Pontz, M.; Porcelli, A.; Preda, T.; Privitera, P.; Prouza, M.; Quel, E. J.; Querchfeld, S.; Quinn, S.; Rautenberg, J.; Ravel, O.; Ravignani, D.; Revenu, B.; Ridky, J.; Riggi, S.; Risse, M.; Ristori, P.; Rivera, H.; Rizi, V.; Roberts, J.; Rodrigues de Carvalho, W.; Rodriguez Cabo, I.; Rodriguez Fernandez, G.; Rodriguez Martino, J.; Rodriguez Rojo, J.; Rodríguez-Frías, M. D.; Ros, G.; Rosado, J.; Rossler, T.; Roth, M.; Rouillé-d'Orfeuil, B.; Roulet, E.; Rovero, A. C.; Rühle, C.; Saffi, S. J.; Saftoiu, A.; Salamida, F.; Salazar, H.; Salesa Greus, F.; Salina, G.; Sánchez, F.; Sanchez-Lucas, P.; Santo, C. E.; Santos, E.; Santos, E. M.; Sarazin, F.; Sarkar, B.; Sarmento, R.; Sato, R.; Scharf, N.; Scherini, V.; Schieler, H.; Schiffer, P.; Schmidt, A.; Scholten, O.; Schoorlemmer, H.; Schovánek, P.; Schröder, F. G.; Schulz, A.; Schulz, J.; Sciutto, S. J.; Scuderi, M.; Segreto, A.; Settimo, M.; Shadkam, A.; Shellard, R. C.; Sidelnik, I.; Sigl, G.; Sima, O.; Śmiałkowski, A.; Šmída, R.; Snow, G. R.; Sommers, P.; Sorokin, J.; Spinka, H.; Squartini, R.; Srivastava, Y. N.; Stanič, S.; Stapleton, J.; Stasielak, J.; Stephan, M.; Straub, M.; Stutz, A.; Suarez, F.; Suomijärvi, T.; Supanitsky, A. D.; Šuša, T.; Sutherland, M. S.; Swain, J.; Szadkowski, Z.; Szuba, M.; Tapia, A.; Tartare, M.; Taşcǎu, O.; Thao, N. T.; Tiffenberg, J.; Timmermans, C.; Tkaczyk, W.; Todero Peixoto, C. J.; Toma, G.; Tomankova, L.; Tomé, B.; Tonachini, A.; Torralba Elipe, G.; Torres Machado, D.; Travnicek, P.; Tridapalli, D. B.; Trovato, E.; Tueros, M.; Ulrich, R.; Unger, M.; Valdés Galicia, J. F.; Valiño, I.; Valore, L.; van Aar, G.; van den Berg, A. M.; van Velzen, S.; van Vliet, A.; Varela, E.; Vargas Cárdenas, B.; Varner, G.; Vázquez, J. R.; Vázquez, R. A.; Veberič, D.; Verzi, V.; Vicha, J.; Videla, M.; Villaseñor, L.; Wahlberg, H.; Wahrlich, P.; Wainberg, O.; Walz, D.; Watson, A. A.; Weber, M.; Weidenhaupt, K.; Weindl, A.; Werner, F.; Westerhoff, S.; Whelan, B. J.; Widom, A.; Wieczorek, G.; Wiencke, L.; Wilczyńska, B.; Wilczyński, H.; Will, M.; Williams, C.; Winchen, T.; Wundheiler, B.; Wykes, S.; Yamamoto, T.; Yapici, T.; Younk, P.; Yuan, G.; Yushkov, A.; Zamorano, B.; Zas, E.; Zavrtanik, D.; Zavrtanik, M.; Zaw, I.; Zepeda, A.; Zhou, J.; Zhu, Y.; Zimbres Silva, M.; Ziolkowski, M.; Pierre Auger Collaboration

    2014-03-01

    The emission of radio waves from air showers has been attributed to the so-called geomagnetic emission process. At frequencies around 50 MHz this process leads to coherent radiation which can be observed with rather simple setups. The direction of the electric field induced by this emission process depends only on the local magnetic field vector and on the incoming direction of the air shower. We report on measurements of the electric field vector where, in addition to this geomagnetic component, another component has been observed that cannot be described by the geomagnetic emission process. The data provide strong evidence that the other electric field component is polarized radially with respect to the shower axis, in agreement with predictions made by Askaryan who described radio emission from particle showers due to a negative charge excess in the front of the shower. Our results are compared to calculations which include the radiation mechanism induced by this charge-excess process.

  6. Measurement of temperature and emissivity of specularly reflecting glowing bodies

    NASA Technical Reports Server (NTRS)

    Hansen, G. P.; Hauge, R. H.; Margrave, J. L.; Krishnan, S.

    1988-01-01

    A new method of measuring the thermodynamic temperature of an object as well as the surface emissivity based on laser reflectivity has been developed. By using rotator analyzer ellipsometry, the light reflected from the sample at a specific angle of incidence can be analyzed for its ellipticity. The normal incidence reflectivity and emissivity are then extracted using standard relations. The thermodynamic temperature of the body is obtained simultaneously by measuring the intensity of emitted light at the same angle of incidence. Room temperature measurements are carried out on selected metals to test the system. Elevated temperature measurements on platinum foils show that this technique is reliable and accurate for monitoring and measuring the temperature and emissivity of specularly reflecting, glowing bodies.

  7. Measurement of temperature and emissivity of specularly reflecting glowing bodies

    NASA Technical Reports Server (NTRS)

    Hansen, G. P.; Hauge, R. H.; Margrave, J. L.; Krishnan, S.

    1988-01-01

    A new method of measuring the thermodynamic temperature of an object as well as the surface emissivity based on laser reflectivity has been developed. By using rotator analyzer ellipsometry, the light reflected from the sample at a specific angle of incidence can be analyzed for its ellipticity. The normal incidence reflectivity and emissivity are then extracted using standard relations. The thermodynamic temperature of the body is obtained simultaneously by measuring the intensity of emitted light at the same angle of incidence. Room temperature measurements are carried out on selected metals to test the system. Elevated temperature measurements on platinum foils show that this technique is reliable and accurate for monitoring and measuring the temperature and emissivity of specularly reflecting, glowing bodies.

  8. European emissions of halogenated greenhouse gases inferred from atmospheric measurements.

    PubMed

    Keller, Christoph A; Hill, Matthias; Vollmer, Martin K; Henne, Stephan; Brunner, Dominik; Reimann, Stefan; O'Doherty, Simon; Arduini, Jgor; Maione, Michela; Ferenczi, Zita; Haszpra, Laszlo; Manning, Alistair J; Peter, Thomas

    2012-01-03

    European emissions of nine representative halocarbons (CFC-11, CFC-12, Halon 1211, HCFC-141b, HCFC-142b, HCFC-22, HFC-125, HFC-134a, HFC-152a) are derived for the year 2009 by combining long-term observations in Switzerland, Italy, and Ireland with campaign measurements from Hungary. For the first time, halocarbon emissions over Eastern Europe are assessed by top-down methods, and these results are compared to Western European emissions. The employed inversion method builds on least-squares optimization linking atmospheric observations with calculations from the Lagrangian particle dispersion model FLEXPART. The aggregated halocarbon emissions over the study area are estimated at 125 (106-150) Tg of CO(2) equiv/y, of which the hydrofluorocarbons (HFCs) make up the most important fraction with 41% (31-52%). We find that chlorofluorocarbon (CFC) emissions from banks are still significant and account for 35% (27-43%) of total halocarbon emissions in Europe. The regional differences in per capita emissions are only small for the HFCs, while emissions of CFCs and hydrochlorofluorocarbons (HCFCs) tend to be higher in Western Europe compared to Eastern Europe. In total, the inferred per capita emissions are similar to estimates for China, but 3.5 (2.3-4.5) times lower than for the United States. Our study demonstrates the large benefits of adding a strategically well placed measurement site to the existing European observation network of halocarbons, as it extends the coverage of the inversion domain toward Eastern Europe and helps to better constrain the emissions over Central Europe.

  9. Probability Theory

    NASA Astrophysics Data System (ADS)

    Jaynes, E. T.; Bretthorst, G. Larry

    2003-04-01

    Foreword; Preface; Part I. Principles and Elementary Applications: 1. Plausible reasoning; 2. The quantitative rules; 3. Elementary sampling theory; 4. Elementary hypothesis testing; 5. Queer uses for probability theory; 6. Elementary parameter estimation; 7. The central, Gaussian or normal distribution; 8. Sufficiency, ancillarity, and all that; 9. Repetitive experiments, probability and frequency; 10. Physics of 'random experiments'; Part II. Advanced Applications: 11. Discrete prior probabilities, the entropy principle; 12. Ignorance priors and transformation groups; 13. Decision theory: historical background; 14. Simple applications of decision theory; 15. Paradoxes of probability theory; 16. Orthodox methods: historical background; 17. Principles and pathology of orthodox statistics; 18. The Ap distribution and rule of succession; 19. Physical measurements; 20. Model comparison; 21. Outliers and robustness; 22. Introduction to communication theory; References; Appendix A. Other approaches to probability theory; Appendix B. Mathematical formalities and style; Appendix C. Convolutions and cumulants.

  10. A Novel Method for Measurement of Total Hemispherical Emissivity

    DTIC Science & Technology

    2006-06-01

    emissivity of a passive coating (black paint). Second, a larger heat flux sensor was custom made to accommodate the size of an ESR device . The size of the...sensors. Assembly and Testing the ESR To demonstrate the capability of the HFB method in measurement of the rapid changes in emissivity of an ESR device ...a test module incorporating a heat flux sensor and an ESR device was assembled by Sensortex Inc. Operation principle of the ESR is discussed in

  11. Can UK fossil fuel emissions be determined by radiocarbon measurements?

    NASA Astrophysics Data System (ADS)

    Wenger, Angelina; O'Doherty, Simon; Rigby, Matthew; Manning, Alistair; Palmer, Paul

    2016-04-01

    The GAUGE project evaluates different methods to estimate UK emissions. However, estimating carbon dioxide emissions as a result of fossil fuel burning is challenging as natural fluxes in and out of the atmosphere are very large. Radiocarbon (14C) measurements offer a way to specifically measure the amount of recently added carbon dioxide from fossil fuel burning. This is possible as, due to their age, all the radiocarbon in fossil fuels has decayed. Hence the amount of recently added CO2 from fossil fuel burning can be measured as a depletion of the 14C content in air. While this method has been successfully applied by several groups on a city or a regional scale, this is the first attempt at using the technique for a national emission estimate. Geographically the UK, being an island, is a good location for such an experiment. But are 14CO2 measurements the ideal solution for estimating fossil fuel emissions as they are heralded to be? Previous studies have shown that 14CO2emissions from the nuclear industry mask the 14C depletion caused by fossil fuel burning and result in an underestimation of the fossil fuel CO2. While this might not be a problem in certain regions around the world, many countries like the UK have a substantial nuclear industry. A correction for this enhancement from the nuclear industry can be applied but are invariably difficult as 14CO2emissions from nuclear power plants have a high temporal variability. We will explain how our sampling strategy was chosen to minimize the influence form the nuclear industry and why this proved to be challenging. In addition we present the results from our ground based measurements to show why trying to estimate national emissions using radiocarbon measurements was overambitious, and how practical the technique is for the UK in general.

  12. Differential Absorption Lidar (DIAL) Measurements of Landfill Methane Emissions

    NASA Astrophysics Data System (ADS)

    Innocenti, Fabrizio; Robinson, Rod; Gardiner, Tom; Finlayson, Andrew; Connor, Andy

    2017-04-01

    DIFFERENTIAL ABSORPTION LIDAR (DIAL) MEASURMENTS OF LANDFILL METHANE EMISSIONS F. INNOCENTI *, R.A. ROBINSON *, T.D. GARDINER, A. FINLAYSON *, A. CONNOR* * National Physical Laboratory (NPL), Hampton Road, Teddington, Middlesex, TW11 0LW, United Kingdom Methane is one of the most important gaseous hydrocarbon species for both industrial and environmental reasons. Understanding and quantifying methane emissions to atmosphere is an important element of climate change research. Range-resolved infrared Differential Absorption Lidar (DIAL) measurements provide the means to map and quantify a wide range of different methane sources. DIAL is a powerful technique that can be used to track and quantify plumes emitted from area emission sources such as landfill sites, waste water treatment plants and petrochemical plants. By using lidar (light detection and ranging), the DIAL technique is able to make remote range-resolved single-ended measurements of the actual distribution of target gases in the atmosphere, with no disruption to normal site operational activities. DIAL provides 3D mapping of emission concentrations and quantification of emission rates for a wide range of target gases such as methane. The NPL DIAL laser source is operated alternately at two similar wavelengths. One of these, termed the "on-resonant wavelength", is chosen to be at a wavelength which is absorbed by the target species. The other, the "off-resonant wavelength", is chosen to be at a nearby wavelength which is not absorbed significantly by the target species. The two wavelengths are chosen to be close, so that the atmospheric scattering properties are the same for both wavelengths. They are also chosen so that any differential absorption due to other atmospheric species are minimised. Any measured difference in the returned signals is therefore due to absorption by the target gas. In the typical DIAL measurement configuration the mobile DIAL facility is positioned downwind of the area being

  13. Differential Absorption Lidar Measurements of Fugitive Benzene Emissions

    NASA Astrophysics Data System (ADS)

    Robinson, R. A.; Innocenti, F.; Helmore, J.; Gardiner, T.; Finlayson, A.; Connor, A.

    2016-12-01

    The Differential Absorption Lidar (DIAL) technique is based on the optical analogue of radar; lidar (light detection and ranging). It provides the capability to remotely measure the concentration and spatial distribution of compounds in the atmosphere. The ability to scan the optical measurement beam throughout the atmosphere enables pollutant concentrations to be mapped, and emission fluxes to be determined when combined with wind data. The NPL DIAL systems can operate in the UV and infrared spectral, enabling the measurement of a range of air pollutants and GHGs including hazardous air pollutants such as benzene. The mobile ground based DIAL systems developed at NPL for pollution monitoring have been used for over 25 years. They have been deployed for routine monitoring, emission factor studies, research investigations and targeted monitoring campaigns. More recently the NPL DIAL has been used in studies to validate other monitoring techniques. In support of this capability, NPL have developed a portable, configurable controlled release system (CRF) able to simulate emissions from typical sources. This has been developed to enable the validation and assessment of fugitive emission monitoring techniques. Following a brief summary of the technique, we outline recent developments in the use of DIAL for monitoring fugitive and diffuse emissions, including the development of a European Standard Method for fugitive emission monitoring. We will present the results of a number of validation exercises using the CRF presenting an update on the performance of DIAL for emission quantification and discuss the wider validation of novel technologies. We will report on recent measurements of the emissions of benzene from industrial sites including a large scale emissions monitoring study carried out by the South Coast Air Quality Management District (SCAQMD) and will report on the measurement of emissions from petrochemical facilities and examine an example of the identification

  14. Measurement of automobile exhaust emissions under realistic road conditions

    SciTech Connect

    Staab, J.; Schurmann, D.

    1987-01-01

    An exhaust gas measurement system for on-board use has been developed, which enables the direct and continuous determination of the exhaust mass emissions in vehicles on the road. Such measurements under realistic traffic conditions are a valuable supplement to measurements taken on test benches, the latter, however, still being necessary. In the last two years numerous test runs were undertaken. The reliability of the on-board system could be demonstrated and a very informative view of the exhaust emissions behavior of a vehicle on the road was obtained from the test results.

  15. Measuring real-time streamflow using emerging technologies: Radar, hydroacoustics, and the probability concept

    USGS Publications Warehouse

    Fulton, J.; Ostrowski, J.

    2008-01-01

    Forecasting streamflow during extreme hydrologic events such as floods can be problematic. This is particularly true when flow is unsteady, and river forecasts rely on models that require uniform-flow rating curves to route water from one forecast point to another. As a result, alternative methods for measuring streamflow are needed to properly route flood waves and account for inertial and pressure forces in natural channels dominated by nonuniform-flow conditions such as mild water surface slopes, backwater, tributary inflows, and reservoir operations. The objective of the demonstration was to use emerging technologies to measure instantaneous streamflow in open channels at two existing US Geological Survey streamflow-gaging stations in Pennsylvania. Surface-water and instream-point velocities were measured using hand-held radar and hydroacoustics. Streamflow was computed using the probability concept, which requires velocity data from a single vertical containing the maximum instream velocity. The percent difference in streamflow at the Susquehanna River at Bloomsburg, PA ranged from 0% to 8% with an average difference of 4% and standard deviation of 8.81 m3/s. The percent difference in streamflow at Chartiers Creek at Carnegie, PA ranged from 0% to 11% with an average difference of 5% and standard deviation of 0.28 m3/s. New generation equipment is being tested and developed to advance the use of radar-derived surface-water velocity and instantaneous streamflow to facilitate the collection and transmission of real-time streamflow that can be used to parameterize hydraulic routing models.

  16. Measurement of directional thermal infrared emissivity of vegetation and soils

    SciTech Connect

    Norman, J.M.; Balick, L.K.

    1995-10-01

    A new method has been developed for measuring directional thermal emissivity as a function of view angle for plant canopies and soils using two infrared thermometers each sensitive to a different wavelength band. By calibrating the two infrared thermometers to 0.1C consistency, canopy directional emissivity can be estimated with typical errors less than 0.005 in the 8--14 um wavelength band, depending on clarity of the sky and corrections for CO{sub 2} absorption by the atmosphere. A theoretical justification for the method is developed along with an error analysis. Laboratory measurements were used to develop corrections for CO{sub 2}, absorption and a field calibration method is used to obtain the necessary 0.1C consistency for relatively low cost infrared thermometers. The emissivity of alfalfa (LAI=2.5) and corn (LAI=3.2) was near 0.995 and independent of view angle. Individual corn leaves had an emissivity of 0.97. A wheat (LAI=3.0) canopy had an emissivity of 0.985 at nadir and 0.975 at 75 degree view angle. The canopy emissivity values tend to be higher than values in the literature, and are useful for converting infrared thermometer measurements to kinetic temperature and interpreting satellite thermal observations.

  17. A simple method for the measurement of reflective foil emissivity

    NASA Astrophysics Data System (ADS)

    Ballico, M. J.; van der Ham, E. W. M.

    2013-09-01

    Reflective metal foil is widely used to reduce radiative heat transfer within the roof space of buildings. Such foils are typically mass-produced by vapor-deposition of a thin metallic coating onto a variety of substrates, ranging from plastic-coated reinforced paper to "bubble-wrap". Although the emissivity of such surfaces is almost negligible in the thermal infrared, typically less than 0.03, an insufficiently thick metal coating, or organic contamination of the surface, can significantly increase this value. To ensure that the quality of the installed insulation is satisfactory, Australian building code AS/NZS 4201.5:1994 requires a practical agreed method for measurement of the emissivity, and the standard ASTM-E408 is implied. Unfortunately this standard is not a "primary method" and requires the use of specified expensive apparatus and calibrated reference materials. At NMIA we have developed a simple primary technique, based on an apparatus to thermally modulate the sample and record the apparent modulation in infra-red radiance with commercially available radiation thermometers. The method achieves an absolute accuracy in the emissivity of approximately 0.004 (k=2). This paper theoretically analyses the equivalence between the thermal emissivity measured in this manner, the effective thermal emissivity in application, and the apparent emissivity measured in accordance with ASTM-E408.

  18. Measurement of soil NO x emissions in central Pennsylvania

    NASA Astrophysics Data System (ADS)

    Williams, E. J.; Parrish, D. D.; Buhr, M. P.; Fehsenfeld, F. C.; Fall, R.

    1988-08-01

    Soil emissions of NO and NO2 were measured at forest and agricultural sites in Pennsylvania. The strong dependence of NO emissions on soil temperature observed in earlier studies was also found in these measurements. The large variation in the measured NO flux at these sites indicated that variables other than soil temperature play an important role. In the present study the strong correlation between the NO flux and the soil nitrate level suggests that the level of available nitrate in the soils may affect NO emission. In this connection it should be noted that the application of chemical pesticides, as well as nitrate-containing fertilizer, may influence these results. In these studies, NO2 accounted for a minor fraction (6%) of the nitrogen oxide emissions. Laboratory studies designed to investigate the influence of certain environmental and experimental factors on NO emissions under controlled conditions were also conducted. These results also indicate that temperature has a large effect on soil NO emissions, while flush gas humidity and carbon dioxide level exert little, if any, effect.

  19. REVIEW ARTICLE: Emission measurement techniques for advanced powertrains

    NASA Astrophysics Data System (ADS)

    Adachi, Masayuki

    2000-10-01

    Recent developments in high-efficiency low-emission powertrains require the emission measurement technologies to be able to detect regulated and unregulated compounds with very high sensitivity and a fast response. For example, levels of a variety of nitrogen compounds and sulphur compounds should be analysed in real time in order to develop aftertreatment systems to decrease emission of NOx for the lean burning powertrains. Also, real-time information on the emission of particulate matter for the transient operation of diesel engines and direct injection gasoline engines is invaluable. The present paper reviews newly introduced instrumentation for such emission measurement that is demanded for the developments in advanced powertrain systems. They include Fourier transform infrared spectroscopy, mass spectrometry and fast response flame ionization detection. In addition, demands and applications of the fuel reformer developments for fuel cell electric vehicles are discussed. Besides the detection methodologies, sample handling techniques for the measurement of concentrations emitted from low emission vehicles for which the concentrations of the pollutants are significantly lower than the concentrations present in ambient air, are also described.

  20. A simple method for the measurement of reflective foil emissivity

    SciTech Connect

    Ballico, M. J.; Ham, E. W. M. van der

    2013-09-11

    Reflective metal foil is widely used to reduce radiative heat transfer within the roof space of buildings. Such foils are typically mass-produced by vapor-deposition of a thin metallic coating onto a variety of substrates, ranging from plastic-coated reinforced paper to 'bubble-wrap'. Although the emissivity of such surfaces is almost negligible in the thermal infrared, typically less than 0.03, an insufficiently thick metal coating, or organic contamination of the surface, can significantly increase this value. To ensure that the quality of the installed insulation is satisfactory, Australian building code AS/NZS 4201.5:1994 requires a practical agreed method for measurement of the emissivity, and the standard ASTM-E408 is implied. Unfortunately this standard is not a 'primary method' and requires the use of specified expensive apparatus and calibrated reference materials. At NMIA we have developed a simple primary technique, based on an apparatus to thermally modulate the sample and record the apparent modulation in infra-red radiance with commercially available radiation thermometers. The method achieves an absolute accuracy in the emissivity of approximately 0.004 (k=2). This paper theoretically analyses the equivalence between the thermal emissivity measured in this manner, the effective thermal emissivity in application, and the apparent emissivity measured in accordance with ASTM-E408.

  1. Reporting central tendencies of chamber measured surface emission and oxidation.

    PubMed

    Abichou, Tarek; Clark, Jeremy; Chanton, Jeffery

    2011-05-01

    Methane emissions, concentrations, and oxidation were measured on eleven MSW landfills in eleven states spanning from California to Pennsylvania during the three year study. The flux measurements were performed using a static chamber technique. Initial concentration samples were collected immediately after placement of the flux chamber. Oxidation of the emitted methane was evaluated using stable isotope techniques. When reporting overall surface emissions and percent oxidation for a landfill cover, central tendencies are typically used to report "averages" of the collected data. The objective of this study was to determine the best way to determine and report central tendencies. Results showed that 89% of the data sets of collected surface flux have lognormal distributions, 83% of the surface concentration data sets are also lognormal. Sixty seven percent (67%) of the isotope measured percent oxidation data sets are normally distributed. The distribution of data for all eleven landfills provides insight of the central tendencies of emissions, concentrations, and percent oxidation. When reporting the "average" measurement for both flux and concentration data collected at the surface of a landfill, statistical analyses provided insight supporting the use of the geometric mean. But the arithmetic mean can accurately represent the percent oxidation, as measured with the stable isotope technique. We examined correlations between surface CH(4) emissions and surface air CH(4) concentrations. Correlation of the concentration and flux values using the geometric mean proved to be a good fit (R(2)=0.86), indicating that surface scans are a good way of identifying locations of high emissions.

  2. MEASUREMENT OF FUGITIVE EMISSIONS AT REGION I LANDFILL

    EPA Science Inventory

    This report discusses a new measurement technology for characterizing emissions from large area sources. This work was funded by EPA's Monitoring and Measurement for the 21st Century Initiative, or 21M2. The site selected for demonstrating this technology is a superfund landfil...

  3. MEASUREMENT OF FUGITIVE EMISSIONS AT REGION I LANDFILL

    EPA Science Inventory

    This report discusses a new measurement technology for characterizing emissions from large area sources. This work was funded by EPA's Monitoring and Measurement for the 21st Century Initiative, or 21M2. The site selected for demonstrating this technology is a superfund landfil...

  4. Measurement of air pollutant emissions from Lome, Cotonou and Accra

    NASA Astrophysics Data System (ADS)

    Lee, James; Vaughan, Adam; Nelson, Bethany; Young, Stuart; Evans, Mathew; Morris, Eleanor; Ladkin, Russel

    2017-04-01

    High concentrations of airborne pollutants (e.g. the oxides of nitrogen, sulphur dioxide and carbon monoxide) in existing and evolving cities along the Guinea Coast cause respiratory diseases with potentially large costs to human health and the economic capacity of the local workforce. It is important to understand the rate of emission of such pollutants in order to model current and future air quality and provide guidance to the potential outcomes of air pollution abatement strategies. Often dated technologies and poor emission control strategies lead to substantial uncertainties in emission estimates calculated from vehicle and population number density statistics. The unreliable electrical supply in cities in the area has led to an increased reliance on small-scale diesel powered generators and these potentially present a significant source of emissions. The uncontrolled open incineration of waste adds a further very poorly constrained emission source within the cities. The DACCIWA (Dynamics-Aerosol-Chemistry-Cloud Interactions in West Africa) project involved a field campaign which used highly instrumented aircraft capable of in situ measurements of a range of air pollutants. Seven flights using the UK British Antarctic Survey's Twin Otter aircraft specifically targeted air pollution emissions from cities in West Africa (4 x Accra, Ghana; 2 x Lome, Togo and 1 x Cotonou, Benin). Measurements of NO, NO2, SO2, CO, CH4 and CO2 were made at multiple altitudes upwind and downwind of the cities, with the mass balance technique used to calculate emission rates. These are then compared to the Emissions Database for Global Atmospheric Research (EDGAR) estimates. Ultimately the data will be used to inform on and potentially improve the emission estimates, which in turn should lead to better forecasting of air pollution in West African cities and help guide future air pollution abatement strategy.

  5. Nitrogen trifluoride global emissions estimated from updated atmospheric measurements

    PubMed Central

    Arnold, Tim; Harth, Christina M.; Mühle, Jens; Manning, Alistair J.; Salameh, Peter K.; Kim, Jooil; Ivy, Diane J.; Steele, L. Paul; Petrenko, Vasilii V.; Severinghaus, Jeffrey P.; Baggenstos, Daniel; Weiss, Ray F.

    2013-01-01

    Nitrogen trifluoride (NF3) has potential to make a growing contribution to the Earth’s radiative budget; however, our understanding of its atmospheric burden and emission rates has been limited. Based on a revision of our previous calibration and using an expanded set of atmospheric measurements together with an atmospheric model and inverse method, we estimate that the global emissions of NF3 in 2011 were 1.18 ± 0.21 Gg⋅y−1, or ∼20 Tg CO2-eq⋅y−1 (carbon dioxide equivalent emissions based on a 100-y global warming potential of 16,600 for NF3). The 2011 global mean tropospheric dry air mole fraction was 0.86 ± 0.04 parts per trillion, resulting from an average emissions growth rate of 0.09 Gg⋅y−2 over the prior decade. In terms of CO2 equivalents, current NF3 emissions represent between 17% and 36% of the emissions of other long-lived fluorinated compounds from electronics manufacture. We also estimate that the emissions benefit of using NF3 over hexafluoroethane (C2F6) in electronics manufacture is significant—emissions of between 53 and 220 Tg CO2-eq⋅y−1 were avoided during 2011. Despite these savings, total NF3 emissions, currently ∼10% of production, are still significantly larger than expected assuming global implementation of ideal industrial practices. As such, there is a continuing need for improvements in NF3 emissions reduction strategies to keep pace with its increasing use and to slow its rising contribution to anthropogenic climate forcing. PMID:23341630

  6. Improving the estimation of detection probability and magnitude of completeness in strongly heterogeneous media, an application to acoustic emission (AE)

    NASA Astrophysics Data System (ADS)

    Maghsoudi, Samira; Cesca, Simone; Hainzl, Sebastian; Kaiser, Diethelm; Becker, Dirk; Dahm, Torsten

    2013-06-01

    Reliable estimations of magnitude of completeness (Mc) are essential for a correct interpretation of seismic catalogues. The spatial distribution of Mc may be strongly variable and difficult to assess in mining environments, owing to the presence of galleries, cavities, fractured regions, porous media and different mineralogical bodies, as well as in consequence of inhomogeneous spatial distribution of the seismicity. We apply a 3-D modification of the probabilistic magnitude of completeness (PMC) method, which relies on the analysis of network detection capabilities. In our approach, the probability to detect an event depends on its magnitude, source-receiver Euclidian distance and source-receiver direction. The suggested method is proposed for study of the spatial distribution of the magnitude of completeness in a mining environment and here is applied to a 2-months acoustic emission (AE) data set recorded at the Morsleben salt mine, Germany. The dense seismic network and the large data set, which includes more than one million events, enable a detailed testing of the method. This method is proposed specifically for strongly heterogeneous media. Besides, it can also be used for specific network installations, with sensors with a sensitivity, dependent on the direction of the incoming wave (e.g. some piezoelectric sensors). In absence of strong heterogeneities, the standards PMC approach should be used. We show that the PMC estimations in mines strongly depend on the source-receiver direction, and cannot be correctly accounted using a standard PMC approach. However, results can be improved, when adopting the proposed 3-D modification of the PMC method. Our analysis of one central horizontal and vertical section yields a magnitude of completeness of about Mc ≈ 1 (AE magnitude) at the centre of the network, which increases up to Mc ≈ 4 at further distances outside the network; the best detection performance is estimated for a NNE-SSE elongated region, which

  7. Emissivity measurements of Mercury analogue materials from the Berlin Emissivity Database (BED)

    NASA Astrophysics Data System (ADS)

    Maturilli, A.; Helbert, J.; Moroz, L.

    To determine the planetary surfaces composition, remote sensing infrared spectroscopy is a suitable and powerful method of investigation. Past, present and future missions to bodies in the solar system include in their payload instruments measuring the emerging radiation in the infrared range. The MERTIS instrument, a TIR spectrometer combined with a radiometer, is part of the scientific payload of the ESA BepiColombo mission to Mercury, scheduled for 2013. The Berlin Emissivity Database (BED) is an emissivity spectral library of planetary analogue materials, essential for the interpretation of the measured data. Our unique database is focused on relatively fine-grained size separates, providing a realistic basis for interpretation of thermal emission spectra of Mercury and other planetary bodies. The BED spectral library currently contains emissivity spectra of plagioclase and potassium feldspars, low Ca and high Ca pyroxenes, olivine, elemental sulfur and a lunar highland soil sample measured in the wavelength range from 7 to 22 µm as a function of particle size. For each sample we measured the spectra of four particle size separates ranging from 0 to 250 µm. The device we used is built at DLR (Berlin) and is coupled to a Fourier transform infrared spectrometer (Bruker IFS 88), purged with dry air and equipped with a cooled detector (MCT). All spectra were acquired with a spectral resolution of 4 cm-1 . We present here the emissivity spectra of a basic set of analogue materials reflecting the current knowledge of the surface composition of Mercury. We are currently working to upgrade our emissivity facility: a new spectrometer (Bruker VERTEX 80v) and new detectors will allow us to measure the emissivity of samples in the wavelength range from 1 to 50 µm, even in a vacuum environment.

  8. Probability Distributions of Measured Bedload Transport Rates with Application for Computing Sediment Rating Curves

    NASA Astrophysics Data System (ADS)

    Gaeuman, D. A.; Holt, C. R.

    2011-12-01

    Variability in fractional bedload transport rates derived from 948 bedload samples collected over a 7-year period at 4 locations along the same river were analyzed to assess the variability in measured transport rates under similar transport conditions. Sediment transport rating curves fit to the sample data show that transport characteristics can vary markedly between sampling locations. In addition, transport rates at the same locations usually exhibit clockwise bedload hysteresis between the rising and falling limbs of the annual flood hydrograph, even though long-term transport characteristics have remained comparatively stable over the period of record. Thus, the full set of sample data was separated into 8 groups, consisting of a rising and falling limb population at each of the 4 locations, for subsequent analysis. This separation was intended to reduce systematic variability caused by seasonal factors and position along the river while ensuring that each group contains a large population of measurements. Within each group, dimensionless fractional transport rates were computed and sorted into bins defined by the ratio of shear stress to reference shear stresses estimated from the sample data for each grain size fraction and sampling location. The mean and standard deviation transport rates computed for each shear stress bin were found to fit Chi-squared cumulative probability functions with means and degrees of freedom that increased with the shear stress ratio. Mean dimensionless transport rates ranged about 0.002 for bins with average shear stresses near the reference value to more than 0.12 for bins with average shear stresses exceeding twice the reference value. The standard deviations in dimensionless transport within bins ranged less than 0.6 times the mean value for large transport rates up to about twice the mean value for small transport rates. The relationship between the means and standard deviation transport rates and the shear stress ratio was

  9. Interferometric measurements of sea surface temperature and emissivity

    NASA Astrophysics Data System (ADS)

    Fiedler, Lars; Bakan, Stephan

    1997-09-01

    A new multispectral method to derive sea surface emissivity and temperature by using interferometer measurements of the near surface upwelling radiation in the infrared window region is presented. As reflected sky radiation adds substantial spectral variability to the otherwise spectrally smooth surface radiation, an appropriate estimate of surface emissivity allows the measured upwelling radiation to be corrected for the reflected sky component. The remaining radiation, together with the estimated surface emissivity, yields an estimate of the sea surface temperature. Measurements from an ocean pier in the Baltic Sea in October 1995 indicate an accuracy of about 0.1 K for the sea surface temperature thus derived. A strong sea surface skin effect of about 0.6 K is found in that particular case.

  10. Effect of filament supports on emissive probe measurements

    SciTech Connect

    Wang, X.; Howes, C. T.; Horanyi, M.; Robertson, S.

    2013-01-15

    We have constructed an emissive probe with a thin tungsten filament spot-welded across two nickel wires insulated with ceramic paint. We show that the ceramic supports covering the nickel wires have a large effect on the potential measurements in low-density plasmas. It is found that the potential measured by the emissive probe is more negative than the potential derived from a Langmuir probe current-voltage (I-V) characteristic curve when the plasma density is so low that the emitting filament remains immersed in the sheaths of the ceramic supports. The length of the filament L needs to be larger than about 2 Debye lengths (L > 2{lambda}{sub De}) in order to avoid the influence of the ceramic supports and to achieve reliable plasma potential measurements using emissive probes.

  11. Spectral measurements and analysis of beam-gas emissions

    NASA Astrophysics Data System (ADS)

    Chong, Y. P.; Yu, S. S.; Fessenden, T. J.; Masamitsu, J. A.; Frank, A. M.; Prono, D. S.

    1984-02-01

    Spectral emissions of the Experimental Test Accelerator beam in 500-Torr synthetic air have been measured in the wavelength range 250-700 nm for beam currents of 4.5 and 8 kA. Intense emissions are identified as radiation from nitrogen. Relative intensities agree well with Franck-Condon factors. Wet air results in a dramatic decrease (by a factor of 2-3) in intensity over the scanned range. This effect is presently attributed to incresed hose motion. Near 700 nm, emissions that are not observed in dry air are identified as emanating from water vapor, nitric oxide, and oxygen. The pressure dependence of emitted intensities at 337.1 and 391.4 nm were measured. Results obtained for an 8-kA beam are not explained by a time-dependent Boltzmann air chemistry code which predicted very well previous measurements for a 1-kA beam.

  12. Laboratory technique for quantitative thermal emissivity measurements of geological samples

    NASA Astrophysics Data System (ADS)

    Mathew, George; Nair, Archana; Gundu Rao, T. K.; Pande, Kanchan

    2009-08-01

    Thermal infrared spectroscopy is a powerful technique for the compositional analysis of geological materials. The spectral feature in the mid-IR region is diagnostic of the mineralogy and spectral signatures of mixtures of minerals that add linearly, and therefore, can be used as an important tool to determine the mineralogy of rocks in the laboratory and remotely for planetary exploration. The greatest challenge in the emission measurement lies in the measurement of the weak thermal photons emitted from geological materials in a laboratory setup, and accurately records the temperature of the rock sample. The present work pertains to the details of a new Thermal Emission Spectrometer (TES) laboratory that has been developed under the ISRO Planetary Science and Exploration (PLANEX) programme, for emission related mineralogical investigations of planetary surfaces. The focus of the paper is on the acquisition and calibration technique for obtaining emissivity, and the deconvolution procedure to obtain the modal abundances of the thermal emission spectra in the range of 6-25 µm using Fourier Transform Infrared (FTIR) spectroscopy. The basic technique is adopted from the work of Ruff et al (1997). This laboratory at the Department of Earth Sciences, IIT-Bombay is currently developing pure end mineral library of mineral particulates (<65 µm), and adding new end members to the existing ASU spectral library. The paper argues the need for considering Lunar Orbiter Thermal Emission Spectrometer (LOTES) for future Indian Moon mission programme (Chandrayan-II) to determine evidences of varied lithologies on the lunar surface.

  13. Voyager IRIS Measurements of Triton's Thermal Emission: Impllications for Pluto?

    NASA Astrophysics Data System (ADS)

    Stansberry, John A.; Spencer, John; Linscott, Ivan

    2015-11-01

    The New Horizons Pluto encounter data set includes unique observations obtained using the Radio Science experiment to measure the night-side thermal emission at centimeter wavelengths, well beyond the emission peak (in the 70 to 100 micron range). 26 years ago the Voyager 2 Infrared Interferometer Spectrometer (IRIS) obtained spectra in the 30 - 50 micron wavelength range to try and detect thermal emission from Pluto's sibling, Triton. Conrath etal. (1989) analyzed 16 of the IRIS spectra of Triton's dayside and derived a weak limit of 36 K - 41 K. We have analysed those, and an additional 75 spectra, to refine the limits on the temperature of Triton's surface, and to explore diurnal differences in the thermal emission. Triton results from other Voyager instruments provide important constraints on our interpretation of the IRIS data, as do Spitzer measurements of Pluto's thermal emission.For unit-emissivity, average temperature is 34 K, inconsistent with the pressure of Triton's atmosphere (13 - 19 microbar), the presence of beta-phase nitrogen ice on the surface, and the likely presence ofwarm regions on the surface. The atmospheric pressure requires nitrogen ice temperatures of 37.4 K - 38.1 K, which in turn requires emissivity of 0.31--0.53. Such a low emissivity in this spectral region might be expected if the surface is dominated by nitrogen or methane ice. Averages of data subsets show evidence for brightness temperature variations across Triton's surface. Surprisingly, the data seem to indicate that Triton's nightside equatorial region was warmer than on the dayside.These Voyager results for Triton provide a useful context for interpreting New Horizons and ALMA observations of emission from Pluto in the sub-millimeter and centimeter region. JWST will be capable of detecting Triton's and Pluto's 10 - 28 micron thermal emission, although scattered light from Neptune may be an issue for the Triton. Combined with new capabilities of ALMA to measure the sub

  14. Apparatus for Measuring Total Emissivity of Small, Low-Emissivity Samples

    NASA Technical Reports Server (NTRS)

    Tuttle, James; DiPirro, Michael J.

    2011-01-01

    An apparatus was developed for measuring total emissivity of small, lightweight, low-emissivity samples at low temperatures. The entire apparatus fits inside a small laboratory cryostat. Sample installation and removal are relatively quick, allowing for faster testing. The small chamber surrounding the sample is lined with black-painted aluminum honeycomb, which simplifies data analysis. This results in the sample viewing a very high-emissivity surface on all sides, an effect which would normally require a much larger chamber volume. The sample and chamber temperatures are individually controlled using off-the-shelf PID (proportional integral derivative) controllers, allowing flexibility in the test conditions. The chamber can be controlled at a higher temperature than the sample, allowing a direct absorptivity measurement. The lightweight sample is suspended by its heater and thermometer leads from an isothermal bar external to the chamber. The wires run out of the chamber through small holes in its corners, and the wires do not contact the chamber itself. During a steady-state measurement, the thermometer and bar are individually controlled at the same temperature, so there is zero heat flow through the wires. Thus, all of sample-temperature-control heater power is radiated to the chamber. Double-aluminized Kapton (DAK) emissivity was studied down to 10 K, which was about 25 K colder than any previously reported measurements. This verified a minimum in the emissivity at about 35 K and a rise as the temperature dropped to lower values.

  15. Emission measure distribution for diffuse regions in solar active regions

    SciTech Connect

    Subramanian, Srividya; Tripathi, Durgesh; Klimchuk, James A.; Mason, Helen E.

    2014-11-01

    Our knowledge of the diffuse emission that encompasses active regions is very limited. In this paper we investigate two off-limb active regions, namely, AR 10939 and AR 10961, to probe the underlying heating mechanisms. For this purpose, we have used spectral observations from Hinode/EIS and employed the emission measure (EM) technique to obtain the thermal structure of these diffuse regions. Our results show that the characteristic EM distributions of the diffuse emission regions peak at log T = 6.25 and the coolward slopes are in the range 1.4-3.3. This suggests that both low- as well as high-frequency nanoflare heating events are at work. Our results provide additional constraints on the properties of these diffuse emission regions and their contribution to the background/foreground when active region cores are observed on-disk.

  16. Fleet-wide Emissions from Mobile CO2 Measurements

    NASA Astrophysics Data System (ADS)

    Maness, H.; Thurlow, M. E.; Mcdonald, B. C.; Fung, I. Y.; Harley, R.

    2014-12-01

    In response to regional and municipal policies, transportation agencies are increasingly integrating greenhouse gas considerations into decision making. At the local level, fuel-based methods suffer leakage, mandating a bottom-up approach based on emissions models driven by local activity data. However, high spatial and temporal resolution traffic datasets are in general scarce and subject to error. Emissions models too are based on limited data and often require inputs that are not directly measured. Here, we show that routine, on-road CO2 surface measurements can be used to improve uncertainties on both of these fronts. Using forty hours of surface concentration data collected on CA Highway 24 together with a simple atmospheric dispersion model, we simultaneously derive traffic density as a function of vehicle speed, composite vehicle parameters needed to map vehicle operation to fuel consumption, and baseline meteorological parameters such as wind speed and mixing height. We compare our results directly with traffic loop detector measurements made by California's Performance Measurement System (PeMS), with emissions predictions from EPA's MOtor Vehicle Emission Simulator (MOVES), and with weather station data included in NOAA's Meteorological Assimilation Data Ingest System (MADIS). Using both top-down and bottom-up techniques, we measure the immediate rush-hour emissions reduction associated with congestion alleviation following the opening of the Caldecott Tunnel fourth bore. We use this example to argue that routine and distributed on-road measurements of this kind could serve as a much needed policy tool for testing the impact of traffic-related emissions reduction strategies.

  17. First Compilation and Evaluation of Beta-Delayed Neutron Emission Probabilities and Associated Half-Lives for A ≤ 72 Nuclei

    NASA Astrophysics Data System (ADS)

    Birch, M.; Singh, B.; Abriola, D.; Dillmann, I.; Johnson, T. D.; McCutchan, E. A.; Sonzogni, A. A.

    2014-06-01

    A comprehensive compilation and evaluation of beta-delayed neutron (β- n) emission probabilities, Pn, and associated half-lives for A ≤ 72 nuclei has been performed for the first time. The recommended values have been used to analyze the systematics of β- n emission in this region. The ratio Pn /T1/2 is better correlated with the Q-value of the β- n decay mode than the previously proposed Kratz-Herrmann Formula (KHF). The recommended values are also compared with theoretical quasi-particle random phase approximation (QRPA) calculations.

  18. NOAA's Van-Based Mobile Atmospheric Emissions Measurement Laboratory

    NASA Astrophysics Data System (ADS)

    Dube, W. P.; Peischl, J.; Neuman, J. A.; Eilerman, S. J.; Holloway, M.; Roberts, O.; Aikin, K. C.; Ryerson, T. B.

    2015-12-01

    The Chemical Science Division (CSD) mobile atmospheric emissions measurement laboratory is the second and latest of two mobile measurement vans outfitted for atmospheric sampling by the NOAA Earth System Research Laboratory. In this presentation we will describe the modifications made to this vehicle to provide a versatile and relatively inexpensive instrument platform including: the 2 kW 120 volt instrument power system; battery back-up system; data acquisition system; real-time display; meteorological, directional, and position sensor package; and the typical atmospheric emissions instrument package. The van conversion uses commercially available, off-the-shelf components from the marine and RV industries, thus keeping the costs quite modest.

  19. Snow property measurements correlative to microwave emission at 35 GHz

    NASA Technical Reports Server (NTRS)

    Davis, Robert E.; Dozier, Jeff; Chang, Alfred T. C.

    1987-01-01

    Snow microstructure, measured by plane section analysis, and snow wetness, measured by the dilution method, are used to calculate input parameters for a microwave emission model that uses the radiative transfer method. The scattering and absorbing properties are calculated by Mie theory. The effects of different equivalent sphere conversions, adjustments for near-field interference, and different snow wetness characterizations are compared for various snow conditions. The concentric shell geometry of liquid water in snow yields higher emissivities and better model results than the separate-sphere configuration for liquid water contents greater than 0.05, while at lower liquid water contents the separate-sphere treatment gives better results.

  20. Functional requirements document for measuring emissions of airborne radioactive materials

    SciTech Connect

    Criddle, J.D. Jr.

    1994-09-01

    This document states the functional requirements and procedures for systems making measurements of radioactive airborne emissions from facilities at the Hanford Site. The following issues are addressed in this document: Definition of the program objectives; Selection of the overall approach to collecting the samples; Sampling equipment design; Sampling equipment maintenance, and quality assurance issues. The intent of this document is to assist WHC in demonstrating a high quality of air emission measurements with verified system performance based on documented system design, testing, inspection, and maintenance.

  1. Extracting gridded probability density functions for precipitation intensity from point measurements

    NASA Astrophysics Data System (ADS)

    Haerter, Jan; Eggert, Bastian; Moseley, Christopher; Piani, Claudio; Berg, Peter

    2016-04-01

    A common complication arising in comparisons of modeled data, e.g. from regional climate models or re-analysis, to measurements, e.g. rain gauge data collected at a single position, is that the resolutions do not match. Thereby, a direct comparison of the probability density functions of precipitation rates is not possible, since the gridded data represent an average over an area and a time interval while the point data represent only a temporal average. The spatial resolution of the point data can be considered "infinitely high". This especially constitutes an obstacle in statistical downscaling approaches such as statistical bias correction, or the proper assessment of extremes as computed by climate models. It is well known from the Taylor hypothesis that considerable spatio-temporal information about a dynamical process, such as the eddies of the atmospheric flow, is already contained in a point measurement. Applying the Taylor hypothesis to the statistical distribution functions of precipitation intensity, we show that a gridded spatio-temporal process can be approximated very well by the zero-dimensional analog, i.e. the statistics at a single point. All that needs to be done is to use a coarser temporal resolution for the point timeseries, when comparing to the gridded data, i.e. much better results can be achieved when coarsening the resolution of the point data. The remaining question is, how to extract the proper "scale-adapted" temporal resolution in practice, when only an observed point timeseries and some gridded model data sets are available. We show that this is indeed possible by use of the model alone. Indeed, we find that models which misrepresent precipitation intensity, still serve well in producing proper scale-adaptation, i.e. the model is sufficient in representing larger-scale atmospheric dynamics even though precipitation formation is misrepresented. Our results may have relevance to improved statistical downscaling as well as the

  2. The Next Generation Heated Halo for Blackbody Emissivity Measurement

    NASA Astrophysics Data System (ADS)

    Gero, P.; Taylor, J. K.; Best, F. A.; Revercomb, H. E.; Knuteson, R. O.; Tobin, D. C.; Adler, D. P.; Ciganovich, N. N.; Dutcher, S. T.; Garcia, R. K.

    2011-12-01

    The accuracy of radiance measurements from space-based infrared spectrometers is contingent on the quality of the calibration subsystem, as well as knowledge of its uncertainty. Future climate benchmarking missions call for measurement uncertainties better than 0.1 K (k=3) in radiance temperature for the detection of spectral climate signatures. Blackbody cavities impart the most accurate calibration for spaceborne infrared sensors, provided that their temperature and emissivity is traceably determined on-orbit. The On-Orbit Absolute Radiance Standard (OARS) has been developed at the University of Wisconsin to meet the stringent requirements of the next generation of infrared remote sensing instruments. It provides on-orbit determination of both traceable temperature and emissivity for calibration blackbodies. The Heated Halo is the component of the OARS that provides a robust and compact method to measure the spectral emissivity of a blackbody in situ. A carefully baffled thermal source is placed in front of a blackbody in an infrared spectrometer system, and the combined radiance of the blackbody and Heated Halo reflection is observed. Knowledge of key temperatures and the viewing geometry allow the blackbody cavity spectral emissivity to be calculated. We present the results from the Heated Halo methodology implemented with a new Absolute Radiance Interferometer (ARI), which is a prototype space-based infrared spectrometer designed for climate benchmarking that was developed under the NASA Instrument Incubator Program (IIP). We compare our findings to models and other experimental methods of emissivity determination.

  3. Measurements of methane emissions from natural gas gathering facilities and processing plants: measurement results.

    PubMed

    Mitchell, Austin L; Tkacik, Daniel S; Roscioli, Joseph R; Herndon, Scott C; Yacovitch, Tara I; Martinez, David M; Vaughn, Timothy L; Williams, Laurie L; Sullivan, Melissa R; Floerchinger, Cody; Omara, Mark; Subramanian, R; Zimmerle, Daniel; Marchese, Anthony J; Robinson, Allen L

    2015-03-03

    Facility-level methane emissions were measured at 114 gathering facilities and 16 processing plants in the United States natural gas system. At gathering facilities, the measured methane emission rates ranged from 0.7 to 700 kg per hour (kg/h) (0.6 to 600 standard cubic feet per minute (scfm)). Normalized emissions (as a % of total methane throughput) were less than 1% for 85 gathering facilities and 19 had normalized emissions less than 0.1%. The range of methane emissions rates for processing plants was 3 to 600 kg/h (3 to 524 scfm), corresponding to normalized methane emissions rates <1% in all cases. The distributions of methane emissions, particularly for gathering facilities, are skewed. For example, 30% of gathering facilities contribute 80% of the total emissions. Normalized emissions rates are negatively correlated with facility throughput. The variation in methane emissions also appears driven by differences between inlet and outlet pressure, as well as venting and leaking equipment. Substantial venting from liquids storage tanks was observed at 20% of gathering facilities. Emissions rates at these facilities were, on average, around four times the rates observed at similar facilities without substantial venting.

  4. Constraining isoprene emission factors using airborne flux measurements during CABERNET

    NASA Astrophysics Data System (ADS)

    Misztal, P. K.; Karl, T.; Jiang, X.; Avise, J. C.; Scott, K.; Jonsson, H.; Guenther, A. B.; Goldstein, A. H.

    2012-12-01

    An aircraft flux study was conducted to assess biogenic volatile organic compound (BVOC) emissions from California ecosystems targeting oak woodlands and isoprene for most transects. The direct eddy covariance approach featured high speed proton transfer reaction mass spectrometry onboard a CIRPAS (Center for Interdisciplinary Remotely-Piloted Aircraft Studies) Twin Otter aircraft during June 2011 as part of the CABERNET (California Airborne BVOC Emission Research in Natural Ecosystem Transects) project. Isoprene fluxes were calculated using wavelet analysis and scaled to surface fluxes using a divergence term obtained by measuring fluxes at multiple altitudes over homogenous oak terrain. By normalization of fluxes to standard temperature and photosynthetically active radiation levels using standard BVOC modeling equations, the resulting emission factors could be directly compared with those used by MEGAN (Model of Emissions of Gases and Aerosols from Nature) and BEIGIS (Biogenic Emission Inventory Geographic Information System) models which are the most commonly used BVOC emission models for California. As expected, oak woodlands were found to be the dominant source of isoprene in all areas surrounding and in the Central Valley of California. The airborne fluxes averaged to 2 km spatial resolution matched remarkably well with current oak woodland distributions driving the models and hence the correspondence of modeled and aircraft derived emission factors was also good, although quantitative differences were encountered depending on the region and driving variables used. Fluxes measured from aircraft proved to be useful for the improvement of the accuracy of modeled predictions for isoprene and other important ozone and aerosol precursor compounds. These are the first regional isoprene flux measurements using direct eddy covariance on aircraft.

  5. Incorporating photometric redshift probability density information into real-space clustering measurements

    NASA Astrophysics Data System (ADS)

    Myers, Adam D.; White, Martin; Ball, Nicholas M.

    2009-11-01

    The use of photometric redshifts in cosmology is increasing. Often, however these photo-z are treated like spectroscopic observations, in that the peak of the photometric redshift, rather than the full probability density function (PDF), is used. This overlooks useful information inherent in the full PDF. We introduce a new real-space estimator for one of the most used cosmological statistics, the two-point correlation function, that weights by the PDF of individual photometric objects in a manner that is optimal when Poisson statistics dominate. As our estimator does not bin based on the PDF peak, it substantially enhances the clustering signal by usefully incorporating information from all photometric objects that overlap the redshift bin of interest. As a real-world application, we measure quasi-stellar object (QSO) clustering in the Sloan Digital Sky Survey (SDSS). We find that our simplest binned estimator improves the clustering signal by a factor equivalent to increasing the survey size by a factor of 2-3. We also introduce a new implementation that fully weights between pairs of objects in constructing the cross-correlation and find that this pair-weighted estimator improves clustering signal in a manner equivalent to increasing the survey size by a factor of 4-5. Our technique uses spectroscopic data to anchor the distance scale and it will be particularly useful where spectroscopic data (e.g. from BOSS) overlap deeper photometry (e.g. from Pan-STARRS, DES or the LSST). We additionally provide simple, informative expressions to determine when our estimator will be competitive with the autocorrelation of spectroscopic objects. Although we use QSOs as an example population, our estimator can and should be applied to any clustering estimate that uses photometric objects.

  6. High temperature spectral emissivity measurement using integral blackbody method

    NASA Astrophysics Data System (ADS)

    Pan, Yijie; Dong, Wei; Lin, Hong; Yuan, Zundong; Bloembergen, Pieter

    2016-10-01

    Spectral emissivity is a critical material's thermos-physical property for heat design and radiation thermometry. A prototype instrument based upon an integral blackbody method was developed to measure material's spectral emissivity above 1000 °. The system was implemented with an optimized commercial variable-high-temperature blackbody, a high speed linear actuator, a linear pyrometer, and an in-house designed synchronization circuit. A sample was placed in a crucible at the bottom of the blackbody furnace, by which the sample and the tube formed a simulated blackbody which had an effective total emissivity greater than 0.985. During the measurement, the sample was pushed to the end opening of the tube by a graphite rod which was actuated through a pneumatic cylinder. A linear pyrometer was used to monitor the brightness temperature of the sample surface through the measurement. The corresponding opto-converted voltage signal was fed and recorded by a digital multi-meter. A physical model was proposed to numerically evaluate the temperature drop along the process. Tube was discretized as several isothermal cylindrical rings, and the temperature profile of the tube was measurement. View factors between sample and rings were calculated and updated along the whole pushing process. The actual surface temperature of the sample at the end opening was obtained. Taking advantages of the above measured voltage profile and the calculated true temperature, spectral emissivity under this temperature point was calculated.

  7. Comprehensive laboratory measurements of biomass-burning emissions: 1. Emissions from Indonesian, African, and other fuels

    NASA Astrophysics Data System (ADS)

    Christian, T. J.; Kleiss, B.; Yokelson, R. J.; Holzinger, R.; Crutzen, P. J.; Hao, W. M.; Saharjo, B. H.; Ward, D. E.

    2003-12-01

    Trace gas and particle emissions were measured from 47 laboratory fires burning 16 regionally to globally significant fuel types. Instrumentation included the following: open-path Fourier transform infrared spectroscopy; proton transfer reaction mass spectrometry; filter sampling with subsequent analysis of particles with diameter <2.5 μm for organic and elemental carbon and other elements; and canister sampling with subsequent analysis by gas chromatography (GC)/flame ionization detector, GC/electron capture detector, and GC/mass spectrometry. The emissions of 26 compounds are reported by fuel type. The results include the first detailed measurements of the emissions from Indonesian fuels. Carbon dioxide, CO, CH4, NH3, HCN, methanol, and acetic acid were the seven most abundant emissions (in order) from burning Indonesian peat. Acetol (hydroxyacetone) was a major, previously unobserved emission from burning rice straw (21-34 g/kg). The emission factors for our simulated African fires are consistent with field data for African fires for compounds measured in both the laboratory and the field. However, the higher concentrations and more extensive instrumentation in this work allowed quantification of at least 10 species not previously quantified for African field fires (in order of abundance): acetaldehyde, phenol, acetol, glycolaldehyde, methylvinylether, furan, acetone, acetonitrile, propenenitrile, and propanenitrile. Most of these new compounds are oxygenated organic compounds, which further reinforces the importance of these reactive compounds as initial emissions from global biomass burning. A few high-combustion-efficiency fires emitted very high levels of elemental (black) carbon, suggesting that biomass burning may produce more elemental carbon than previously estimated.

  8. On the Uncertainty in Single Molecule Fluorescent Lifetime and Energy Emission Measurements

    NASA Technical Reports Server (NTRS)

    Brown, Emery N.; Zhang, Zhenhua; McCollom, Alex D.

    1996-01-01

    Time-correlated single photon counting has recently been combined with mode-locked picosecond pulsed excitation to measure the fluorescent lifetimes and energy emissions of single molecules in a flow stream. Maximum likelihood (ML) and least squares methods agree and are optimal when the number of detected photons is large, however, in single molecule fluorescence experiments the number of detected photons can be less than 20, 67 percent of those can be noise, and the detection time is restricted to 10 nanoseconds. Under the assumption that the photon signal and background noise are two independent inhomogeneous Poisson processes, we derive the exact joint arrival time probability density of the photons collected in a single counting experiment performed in the presence of background noise. The model obviates the need to bin experimental data for analysis, and makes it possible to analyze formally the effect of background noise on the photon detection experiment using both ML or Bayesian methods. For both methods we derive the joint and marginal probability densities of the fluorescent lifetime and fluorescent emission. The ML and Bayesian methods are compared in an analysis of simulated single molecule fluorescence experiments of Rhodamine 110 using different combinations of expected background noise and expected fluorescence emission. While both the ML or Bayesian procedures perform well for analyzing fluorescence emissions, the Bayesian methods provide more realistic measures of uncertainty in the fluorescent lifetimes. The Bayesian methods would be especially useful for measuring uncertainty in fluorescent lifetime estimates in current single molecule flow stream experiments where the expected fluorescence emission is low. Both the ML and Bayesian algorithms can be automated for applications in molecular biology.

  9. On the uncertainty in single molecule fluorescent lifetime and energy emission measurements

    NASA Technical Reports Server (NTRS)

    Brown, Emery N.; Zhang, Zhenhua; Mccollom, Alex D.

    1995-01-01

    Time-correlated single photon counting has recently been combined with mode-locked picosecond pulsed excitation to measure the fluorescent lifetimes and energy emissions of single molecules in a flow stream. Maximum likelihood (ML) and least square methods agree and are optimal when the number of detected photons is large however, in single molecule fluorescence experiments the number of detected photons can be less than 20, 67% of those can be noise and the detection time is restricted to 10 nanoseconds. Under the assumption that the photon signal and background noise are two independent inhomogeneous poisson processes, we derive the exact joint arrival time probably density of the photons collected in a single counting experiment performed in the presence of background noise. The model obviates the need to bin experimental data for analysis, and makes it possible to analyze formally the effect of background noise on the photon detection experiment using both ML or Bayesian methods. For both methods we derive the joint and marginal probability densities of the fluorescent lifetime and fluorescent emission. the ML and Bayesian methods are compared in an analysis of simulated single molecule fluorescence experiments of Rhodamine 110 using different combinations of expected background nose and expected fluorescence emission. While both the ML or Bayesian procedures perform well for analyzing fluorescence emissions, the Bayesian methods provide more realistic measures of uncertainty in the fluorescent lifetimes. The Bayesian methods would be especially useful for measuring uncertainty in fluorescent lifetime estimates in current single molecule flow stream experiments where the expected fluorescence emission is low. Both the ML and Bayesian algorithms can be automated for applications in molecular biology.

  10. Accuracy of exhaust emission factor measurements on chassis dynamometer.

    PubMed

    Joumard, Robert; Laurikko, Juhani; Le Han, Tuan; Geivanidis, Savas; Samaras, Zissis; Merétei, Tamás; Devaux, Philippe; André, Jean-Marc; Cornelis, Erwin; Lacour, Stéphanie; Prati, Maria Vittoria; Vermeulen, Robin; Zallinger, Michael

    2009-06-01

    To improve the accuracy, reliability, and representativeness of emission factors, 10 European laboratories worked together to study the influence of 20 parameters on the measurement of light-vehicle emission factors on chassis dynamometer of 4 main categories: driving patterns, vehicle-related parameters, vehicle sampling, and laboratory-related parameters. The results are based on (1) literature synthesis, (2) approximately 2700 specific tests with 183 vehicles, and (3) the reprocessing of more than 900 tests. These tests concern the regulated atmospheric pollutants and pre-Euro to Euro 4 vehicles. Of the 20 parameters analyzed, 7 seemed to have no effect, 7 were qualitatively influential, and 6 were highly influential (gearshift strategy, vehicle mileage, ambient temperature, humidity, dilution ratio, and driving cycle). The first four of the six were able to have correction factors developed for them. The results allow for the design of recommendations or guidelines for the emission factor measurement method.

  11. Continuous measurements of N2O emissions from arable fields

    NASA Astrophysics Data System (ADS)

    Wallman, Magdalena; Lammirato, Carlo; Rütting, Tobias; Delin, Sofia; Weslien, Per; Klemedtsson, Leif

    2017-04-01

    Agriculture represents 59 % of the anthropogenic nitrous oxide (N2O) emissions, according to the IPCC (Ciais et al. 2013). N2O emissions are typically irregular and vary widely in time and space, which makes it difficult to get a good representation of the emissions (Henault et al. 2012), particularly if measurements have low frequency and/or cover only a short time period. Manual measurements are, for practical reasons, often short-term and low-frequent, or restricted to periods where emissions are expected to be high, e.g. after fertilizing. However, the nature of N2O emissions, being largely unpredictable, calls for continuous or near-continuous measurements over long time periods. So far, rather few long-term, high resolution measurements of N2O emissions from arable fields are reported; among them are Flessa et al. (2002) and Senapati et al. (2016). In this study, we have a two-year data set (2015-2017) with hourly measurements from ten automatic chambers, covering unfertilized controls as well as different nitrogen fertilizer treatments. Grain was produced on the field, and effects of tillage, harvest and other cropping measures were covered. What we can see from the experiment is that (a) the unfertilized control plots seem to follow the same emission pattern as the fertilized plots, at a level similar to the standard mineral fertilized plots (120 kg N ha-1 yr-1) and (b) freeze/thaw emissions are comparable in size to emissions after fertilizing. These two findings imply that the importance of fertilizing to the overall N2O emissions from arable soils may be smaller than previously expected. References: Ciais, P., C. Sabine, G. Bala, L. Bopp, V. Brovkin, J. Canadell et al. 2013: Carbon and Other Biogeochemical Cycles. In: Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change [Stocker, T.F., D. Qin, G.-K. Plattner, M. Tignor, S.K. Allen, J. Boschung et

  12. FAST DIFFERENTIAL EMISSION MEASURE INVERSION OF SOLAR CORONAL DATA

    SciTech Connect

    Plowman, Joseph; Kankelborg, Charles; Martens, Petrus

    2013-07-01

    We present a fast method for reconstructing differential emission measures (DEMs) using solar coronal data. The method consists of a fast, simple regularized inversion in conjunction with an iteration scheme for removal of residual negative emission measure. On average, it computes over 1000 DEMs s{sup -1} for a sample active region observed by the Atmospheric Imaging Assembly (AIA) on the Solar Dynamics Observatory, and achieves reduced chi-squared of order unity with no negative emission in all but a few test cases. The high performance of this method is especially relevant in the context of AIA, which images of order one million solar pixels per second. This paper describes the method, analyzes its fidelity, compares its performance and results with other DEM methods, and applies it to an active region and loop observed by AIA and by the Extreme-ultraviolet Imaging Spectrometer on Hinode.

  13. Atmospheric Sulfur Hexafluoride: Measurements and Emission Estimates from 1970 - 2008

    NASA Astrophysics Data System (ADS)

    Rigby, M. L.; Prinn, R. G.; Muhle, J.; Miller, B. R.; Dlugokencky, E. J.; Krummel, P. B.; Steele, L. P.; Fraser, P. J.; Leist, M.; Weiss, R. F.; Harth, C. M.; O'Doherty, S. J.; Greally, B. R.; Simmonds, P. G.; Derek, N.; Vollmer, M. K.; Kim, J.; Kim, K.; Porter, L. W.

    2009-12-01

    We present an air history of atmospheric sulfur hexafluoride (SF6) from the early 1970s through 2008. During this period, concentrations of this extremely potent and long-lived greenhouse gas have increased by more than an order of magnitude, and its growth has accelerated in recent years. In this study, historical concentrations are determined from archived air samples measured on the Advanced Global Atmospheric Gases Experiment (AGAGE) ‘Medusa’ gas chromatography/mass spectrometry system. These data are combined with modern high-frequency measurements from the AGAGE and National Oceanic and Atmospheric Administration (NOAA) in situ networks and ˜weekly samples from the NOAA flask network, to produce a unique time series with increasing global coverage spanning almost four decades. Using the three-dimensional chemical transport Model for Ozone and Related Tracers (MOZART v4.5) and a discrete Kalman filter, we derive estimates of the annual emission strength of SF6 on hemispheric scales from 1970 - 2004 and on continental scales from 2004 - 2008. Our emission estimates are compared to the recently compiled Emissions Database for Global Atmospheric Research (EDGAR v4), and emissions reported under the United Nations Framework Convention on Climate Change (UNFCCC). The cause of the recent growth rate increase is also investigated, indicating that the origin of the required emissions rise is likely to be South-East Asia.

  14. Measurements of air pollution emission factors for marine transportation

    NASA Astrophysics Data System (ADS)

    Alföldy, B.; Balzani Lööv, J.; Lagler, F.; Mellqvist, J.; Berg, N.; Beecken, J.; Weststrate, H.; Duyzer, J.; Bencs, L.; Horemans, B.; Cavalli, F.; Putaud, J.-P.; Janssens-Maenhout, G.; Pintér Csordás, A.; Van Grieken, R.; Borowiak, A.; Hjorth, J.

    2012-12-01

    The chemical composition of the plumes of seagoing ships was investigated during a two weeks long measurement campaign in the port of Rotterdam, Hoek van Holland, The Netherlands, in September 2009. Altogether, 497 ships were monitored and a statistical evaluation of emission factors (g kg-1 fuel) was provided. The concerned main atmospheric components were SO2, NO2, NOx and the aerosol particle number. In addition, the elemental and water-soluble ionic composition of the emitted particulate matter was determined. Emission factors were expressed as a function of ship type, power and crankshaft rotational speed. The average SO2 emission factor was found to be roughly half of what is allowed in sulphur emission control areas (16 vs. 30 g kg-1 fuel), and exceedances of this limit were rarely registered. A significant linear relationship was observed between the SO2 and particle number emission factor. The intercept of the regression line, 0.5 × 1016 (kg fuel)-1, gives the average number of particles formed during the burning of 1 kg zero sulphur content fuel, while the slope, 2 × 1018, provides the average number of particles formed with 1 kg sulphur burnt with the fuel. Water-soluble ionic composition analysis of the aerosol samples from the plumes showed that ~144 g of particulate sulphate was emitted from 1 kg sulphur burnt with the fuel. The mass median diameter of sulphate particles estimated from the measurements was ~42 nm.

  15. Measurement of coronal X-ray emission lines from Capella

    NASA Technical Reports Server (NTRS)

    Vedder, P. W.; Canizares, C. R.

    1983-01-01

    The Einstein Observatory's Focal Plane Crystal Spectrometer has detected X-ray emission lines due to O VIII, Fe XVII, and Fe XX, from the binary star system Capella. Line luminosities are well fitted by an emitting plasma at a single temperature of 6.29 + or - 0.01 - 0.03 million K, and a volume emission measure of about 8.6 x 10 to the 52nd/cu cm, corresponding to the low temperature component previously observed. A high temperature component is undetectable, since the observed lines are not produced in plasma at temperatures above about 20 million K. Nearly isothermal plasma would be expected if many of the magnetically confined coronal loops have similar sizes and pressures, and a second population of longer loops would be required to account for the hotter component. An alternative interpretation of the observed X-ray line emission and upper limit is that the plasma contains a continuous distribution of emission measure versus temperature that rises sharply to 3 million K and then falls by nearly a decade to 16 million. An extrapolation of the loop sizes suggested by this alternative to hotter, longer loops may also account for the higher temperature emission.

  16. Polarized radio emission from extensive air showers measured with LOFAR

    SciTech Connect

    Schellart, P.; Buitink, S.; Corstanje, A.; Enriquez, J.E.; Falcke, H.; Hörandel, J.R.; Krause, M.; Nelles, A.; Rachen, J.P.; Veen, S. ter; Thoudam, S.

    2014-10-01

    We present LOFAR measurements of radio emission from extensive air showers. We find that this emission is strongly polarized, with a median degree of polarization of nearly 99%, and that the angle between the polarization direction of the electric field and the Lorentz force acting on the particles, depends on the observer location in the shower plane. This can be understood as a superposition of the radially polarized charge-excess emission mechanism, first proposed by Askaryan and the geomagnetic emission mechanism proposed by Kahn and Lerche. We calculate the relative strengths of both contributions, as quantified by the charge-excess fraction, for 163 individual air showers. We find that the measured charge-excess fraction is higher for air showers arriving from closer to the zenith. Furthermore, the measured charge-excess fraction also increases with increasing observer distance from the air shower symmetry axis. The measured values range from (3.3± 1.0)% for very inclined air showers at 25 m to (20.3± 1.3)% for almost vertical showers at 225 m. Both dependencies are in qualitative agreement with theoretical predictions.

  17. Developments in Emission Measurements Using Lightweight Sensors and Samplers

    EPA Science Inventory

    Lightweight emission measurement systems making use of miniaturized sensors and samplers have been developed for portable and aerial sampling for an array of pollutants. Shoebox-sized systems called “Kolibri”, weighing 3-5 kg, have been deployed on NASA-flown unmanned aerial syst...

  18. Virtual Instrument for Emissions Measurement of Internal Combustion Engines.

    PubMed

    Pérez, Armando; Ramos, Rogelio; Montero, Gisela; Coronado, Marcos; García, Conrado; Pérez, Rubén

    2016-01-01

    The gases emissions measurement systems in internal combustion engines are strict and expensive nowadays. For this reason, a virtual instrument was developed to measure the combustion emissions from an internal combustion diesel engine, running with diesel-biodiesel mixtures. This software is called virtual instrument for emissions measurement (VIEM), and it was developed in the platform of LabVIEW 2010® virtual programming. VIEM works with sensors connected to a signal conditioning system, and a data acquisition system is used as interface for a computer in order to measure and monitor in real time the emissions of O2, NO, CO, SO2, and CO2 gases. This paper shows the results of the VIEM programming, the integrated circuits diagrams used for the signal conditioning of sensors, and the sensors characterization of O2, NO, CO, SO2, and CO2. VIEM is a low-cost instrument and is simple and easy to use. Besides, it is scalable, making it flexible and defined by the user.

  19. Virtual Instrument for Emissions Measurement of Internal Combustion Engines

    PubMed Central

    Pérez, Armando; Montero, Gisela; Coronado, Marcos; García, Conrado; Pérez, Rubén

    2016-01-01

    The gases emissions measurement systems in internal combustion engines are strict and expensive nowadays. For this reason, a virtual instrument was developed to measure the combustion emissions from an internal combustion diesel engine, running with diesel-biodiesel mixtures. This software is called virtual instrument for emissions measurement (VIEM), and it was developed in the platform of LabVIEW 2010® virtual programming. VIEM works with sensors connected to a signal conditioning system, and a data acquisition system is used as interface for a computer in order to measure and monitor in real time the emissions of O2, NO, CO, SO2, and CO2 gases. This paper shows the results of the VIEM programming, the integrated circuits diagrams used for the signal conditioning of sensors, and the sensors characterization of O2, NO, CO, SO2, and CO2. VIEM is a low-cost instrument and is simple and easy to use. Besides, it is scalable, making it flexible and defined by the user. PMID:27034893

  20. GHG emission mitigation measures and technologies in the Czech Republic

    SciTech Connect

    Tichy, M.

    1996-12-31

    The paper presents a short overview of main results in two fields: projection of GHG emission from energy sector in the Czech Republic and assessment of technologies and options for GHG mitigation. The last part presents an overview of measures that were prepared for potential inclusion to the Czech Climate Change Action Plan.

  1. Work function measurements by the field emission retarding potential method

    NASA Technical Reports Server (NTRS)

    Swanson, L. W.; Strayer, R. W.; Mackie, W. A.

    1971-01-01

    Using the field emission retarding potential method true work functions have been measured for the following monocrystalline substrates: W(110), W(111), W(100), Nb(100), Ni(100), Cu(100), Ir(110) and Ir(111). The electron elastic and inelastic reflection coefficients from several of these surfaces have also been examined near zero primary beam energy.

  2. 47 CFR 2.1511 - Measurements of radiated emissions.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... quarter-wave monopole antenna located on a one wavelength minimum diameter metal ground plane. The Rules...) General set-up instructions. Measurements of radiated electromagnetic emissions (EME) are to be performed... (1) Place a 121.5 MHz quarter-wave vertical antenna element at the center of the ground plane and...

  3. 47 CFR 2.1511 - Measurements of radiated emissions.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... quarter-wave monopole antenna located on a one wavelength minimum diameter metal ground plane. The Rules...) General set-up instructions. Measurements of radiated electromagnetic emissions (EME) are to be performed... (1) Place a 121.5 MHz quarter-wave vertical antenna element at the center of the ground plane and...

  4. Developments in Emission Measurements Using Lightweight Sensors and Samplers

    EPA Science Inventory

    Lightweight emission measurement systems making use of miniaturized sensors and samplers have been developed for portable and aerial sampling for an array of pollutants. Shoebox-sized systems called “Kolibri”, weighing 3-5 kg, have been deployed on NASA-flown ...

  5. Surface Temperature Measurements of Heterogeneous Explosives by IR Emission

    NASA Astrophysics Data System (ADS)

    Henson, B. F.; Funk, D. J.; Laabs, G. W.; Asay, B. W.

    1997-07-01

    Solid phase temperature is a key observable for understanding chemical and physical properties of energetic materials. Material decomposition during prolonged heating and the rate and mechanism of energy release during explosive ignition are both strongly coupled to the temperature field in the solid. Toward the end of addressing these issues we are pursuing the remote measurement of temperature by the quantitative collection of IR emission from the material surface. We present measurements of the integrated IR emission (1-5 mm) from both the heterogeneous explosive PBX 9501 and pure components at calibrated temperatures from 100C to 250C. The IR power emitted as a function of temperature is that expected of a black body, attenuated by a unique temperature-independent constant for each component which we report as the thermal emissivity of that component in this spectral region. In addition, we report preliminary measurements of the thermal transients from the unconfined surface of both PBX9501 and pressed HMX during ignition after periods of prolonged heating. We demonstrate that the measurement of IR emission in this spectral region provides both a reliable probe of static surface temperature and a unique observable of dynamic temperature change during ignition.

  6. MEASUREMENT OF FUGITIVE EMISSIONS AT A BIOREACTOR LANDFILL

    EPA Science Inventory

    This report focuses on three field campaigns performed in 2002 and 2003 to measure fugitive emissions at a bioreactor landfill in Louisville, KY, using an open-path Fourier transform infrared spectrometer. The study uses optical remote sensing-radial plume mapping. The horizontal...

  7. Sub-micronewton thrust measurements of indium field emission thrusters

    NASA Technical Reports Server (NTRS)

    Ziemer, J. K.

    2003-01-01

    The performance of three indium field emission thrusters (In-FETs) developed by the Austrian Research Center Seibersdorf (ARCS) have been measured up to 200 muN, 2 mA, and 20 W using a submicronewton resolution thrust stand.

  8. Sub-micronewton thrust measurements of indium field emission thrusters

    NASA Technical Reports Server (NTRS)

    Ziemer, J. K.

    2003-01-01

    The performance of three indium field emission thrusters (In-FETs) developed by the Austrian Research Center Seibersdorf (ARCS) have been measured up to 200 muN, 2 mA, and 20 W using a submicronewton resolution thrust stand.

  9. MEASUREMENT OF FUGITIVE EMISSIONS AT A BIOREACTOR LANDFILL

    EPA Science Inventory

    This report focuses on three field campaigns performed in 2002 and 2003 to measure fugitive emissions at a bioreactor landfill in Louisville, KY, using an open-path Fourier transform infrared spectrometer. The study uses optical remote sensing-radial plume mapping. The horizontal...

  10. Mapping methane emission sources over California based on airborne measurements

    NASA Astrophysics Data System (ADS)

    Karl, T.; Guha, A.; Peischl, J.; Misztal, P. K.; Jonsson, H.; Goldstein, A. H.; Ryerson, T. B.

    2011-12-01

    The California Global Warming Solutions Act of 2006 (AB 32) has created a need to accurately characterize the emission sources of various greenhouse gases (GHGs) and verify the existing state GHG inventory. Methane (CH4) is a major GHG with a global warming potential of 20 times that of CO2 and currently constitutes about 6% of the total statewide GHG emissions on a CO2 equivalent basis. Some of the major methane sources in the state are area sources where methane is biologically produced (e.g. dairies, landfills and waste treatment plants) making bottom-up estimation of emissions a complex process. Other potential sources include fugitive emissions from oil extraction processes and natural gas distribution network, emissions from which are not well-quantified. The lack of adequate field measurement data to verify the inventory and provide independently generated estimates further contributes to the overall uncertainty in the CH4 inventory. In order to gain a better perspective of spatial distribution of major CH4 sources in California, a real-time measurement instrument based on Cavity Ring Down Spectroscopy (CRDS) was installed in a Twin Otter aircraft for the CABERNET (California Airborne BVOC Emissions Research in Natural Ecosystems Transects) campaign, where the driving research goal was to understand the spatial distribution of biogenic VOC emissions. The campaign took place in June 2011 and encompassed over forty hours of airborne CH4 and CO2 measurements during eight unique flights which covered much of the Central Valley and its eastern edge, the Sacramento-San Joaquin delta and the coastal range. The coincident VOC measurements, obtained through a high frequency proton transfer reaction mass spectrometer (PTRMS), aid in CH4 source identification. High mixing ratios of CH4 (> 2000 ppb) are observed consistently in all the flight transects above the Central Valley. These high levels of CH4 are accompanied by high levels of methanol which is an important

  11. Trending in Probability of Collision Measurements via a Bayesian Zero-Inflated Beta Mixed Model

    NASA Technical Reports Server (NTRS)

    Vallejo, Jonathon; Hejduk, Matt; Stamey, James

    2015-01-01

    We investigate the performance of a generalized linear mixed model in predicting the Probabilities of Collision (Pc) for conjunction events. Specifically, we apply this model to the log(sub 10) transformation of these probabilities and argue that this transformation yields values that can be considered bounded in practice. Additionally, this bounded random variable, after scaling, is zero-inflated. Consequently, we model these values using the zero-inflated Beta distribution, and utilize the Bayesian paradigm and the mixed model framework to borrow information from past and current events. This provides a natural way to model the data and provides a basis for answering questions of interest, such as what is the likelihood of observing a probability of collision equal to the effective value of zero on a subsequent observation.

  12. Measuring reaction probability ratios to simulate neutron-induced cross-sections of short-lived nuclei

    NASA Astrophysics Data System (ADS)

    Plettner, C.; Ai, H.; Beausang, C. W.; Bernstein, L. A.; Ahle, L.; Amro, H.; Babilon, M.; Burke, J. T.; Caggiano, J. A.; Casten, R. F.; Church, J. A.; Cooper, J. R.; Crider, B.; Gürdal, G.; Heinz, A.; McCutchan, E. A.; Moody, K.; Punyon, J. A.; Qian, J.; Ressler, J. J.; Schiller, A.; Williams, E.; Younes, W.

    2005-10-01

    Measuring the neutron-induced fission cross-sections of short-lived nuclei represents an experimental challenge due to target activity and the low intensity of neutron beams. One way to alleviate the problems inherent in the direct measurement is to use the surrogate method, where one measures the decay probability of the same compound nucleus formed using a charged beam and a stable target. The decay probability of the compound nucleus is then used to estimate the neutron-induced cross-section. As an extension to the surrogate method, we introduce a new method of reporting the fission probabilities of two compound nuclei as a ratio, which has the advantage of removing most of the systematic uncertainties. The ratio method was checked in a known case, the 236U(n, f)/238U(n, f) cross-section ratio, which turned out to be the same as the probability ratio of P(236U(d, pf))/P(238U(d, pf)). As an application, the 237U(n, f)/235U(n, f) cross-section ratio was inferred, on the basis of the measured P(238U(d, d'f))/P(236U(d, d'f)) probability ratio.

  13. Reporting central tendencies of chamber measured surface emission and oxidation

    SciTech Connect

    Abichou, Tarek; Clark, Jeremy; Chanton, Jeffery

    2011-05-15

    Methane emissions, concentrations, and oxidation were measured on eleven MSW landfills in eleven states spanning from California to Pennsylvania during the three year study. The flux measurements were performed using a static chamber technique. Initial concentration samples were collected immediately after placement of the flux chamber. Oxidation of the emitted methane was evaluated using stable isotope techniques. When reporting overall surface emissions and percent oxidation for a landfill cover, central tendencies are typically used to report 'averages' of the collected data. The objective of this study was to determine the best way to determine and report central tendencies. Results showed that 89% of the data sets of collected surface flux have lognormal distributions, 83% of the surface concentration data sets are also lognormal. Sixty seven percent (67%) of the isotope measured percent oxidation data sets are normally distributed. The distribution of data for all eleven landfills provides insight of the central tendencies of emissions, concentrations, and percent oxidation. When reporting the 'average' measurement for both flux and concentration data collected at the surface of a landfill, statistical analyses provided insight supporting the use of the geometric mean. But the arithmetic mean can accurately represent the percent oxidation, as measured with the stable isotope technique. We examined correlations between surface CH{sub 4} emissions and surface air CH{sub 4} concentrations. Correlation of the concentration and flux values using the geometric mean proved to be a good fit (R{sup 2} = 0.86), indicating that surface scans are a good way of identifying locations of high emissions.

  14. Visible light emission measurements from a dense electrothermal launcher plasma

    NASA Astrophysics Data System (ADS)

    Hankins, O. E.; Bourham, M. A.; Earnhart, J.; Gilligan, J. G.

    1993-01-01

    Measurements of the visible light emission from dense, weakly non-ideal plasmas have been performed on the experimental electrothermal launcher device 'SIRENS'. The plasma is created by the ablation or a Lexan insulator in the source, which then flows through a cylindrical barrel which serves as the material sample. Visible light emission spectra have been observed both in-bore and from the muzzle flash or the barrel, and from the flash or the source. Due to high plasma opacity (the plasma emits as a near blackbody) and absorption by the molecular components of the vapor shield, the hotter core or the arc has been difficult to observe. Recent measurements along the axis or the device indicate time-averaged plasma temperatures in the barrel or about 1 eV for lower energy shots, which agree with experimental measurements of the average heat flux and plasma conductivity along the barrel. Measurements or visible emission from the source indicate time averaged temperatures of 1 to 2 eV which agree with the theoretical estimates derived from ablated mass measurements and calculated estimates derived from plasma conductivity measurements.

  15. Radio Emission in Atmospheric Air Showers Measured by LOPES-30

    SciTech Connect

    Isar, P. G.

    2008-01-24

    When Ultra High Energy Cosmic Rays (UHECR) interact with particles in the Earth's atmosphere, they produce a shower of secondary particles propagating towards the ground. These relativistic particles emit synchrotron radiation in the radio frequency range when passing the Earth's magnetic field. The LOPES (LOFAR Prototype Station) experiment investigates the radio emission from these showers in detail and will pave the way to use this detection technique for large scale applications like in LOFAR (Low Frequency Array) and the Pierre Auger Observatory. The LOPES experiment is co-located and measures in coincidence with the air shower experiment KASCADE-Grande at Forschungszentrum Karlsruhe, Germany. LOPES has an absolute amplitude calibration array of 30 dipole antennas (LOPES-30). After one year of measurements of the single East-West polarization by all 30 antennas, recently, the LOPES-30 set-up was configured to perform dual-polarization measurements. Half of the antennas have been configured for measurements of the North-South polarization. Only by measuring at the same time both, the E-W and N-S polarization components of the radio emission, the geo-synchrotron effect as the dominant emission mechanism in air showers can be verified. The status of the measurements, including the absolute calibration procedure of the dual-polarized antennas as well as analysis of dual-polarized event examples are reported.

  16. Evaluation of the eruptive potential and probability in open conduit volcano (Mt Etna) based on soil CO2 flux measurements

    NASA Astrophysics Data System (ADS)

    De Gregorio, Sofia; Camarda, Marco

    2016-04-01

    The evaluation of the amount of magma that might be potentially erupted, i.e. the eruptive potential (EP), and the probability of eruptive event occurrence, i.e. eruptive probability (EPR) of active volcano is one of the most compelling and challenging topic addressed by the volcanology community in the last years. The evaluation of the EP in open conduit volcano is generally based on constant magma supply rate deduced by long-term series of eruptive rate. This EP computation gives good results on long-term (centuries) evaluations, but resulted less effective when short-term (years or months) estimations are needed. Actually the rate of magma supply can undergo changes both on long-term and short-term. At steady condition it can be supposed that the regular supply of magma determines an almost constant level of magma in the feeding system (FS) whereas episodic surplus of magma inputs, with respect the regular supply, can cause large variations in the magma level. Follow that the surplus of magma occasionally entered in the FS represents a supply of material that sooner or later will be disposed, i.e. it will be emitted. Afterwards the amount of surplus of magma inward the FS nearly corresponds to the amount of magma that must be erupted in order to restore the equilibrium. Further, larger is the amount of surplus of magma stored in the system higher is the energetic level of the system and its propensity to erupt or in other words its EPR. On the light of the above consideration herein, we present an innovative methodology to evaluate the EP based on the quantification of surplus of magma with respect the regular supply, progressively intruded in the FS. To estimate the surplus of magma supply we used soil CO2 emission data measured monthly at 130 sites in two peripheral areas of Mt Etna Volcano. Indeed as reported by many authors soil CO2 emissions in the areas are linked to magma supply dynamics and more, anomalous discharges of CO2 are ascribable to surplus of

  17. Measurements of fugitive hydrocarbon emissions with a tunable infrared DIAL

    NASA Technical Reports Server (NTRS)

    Milton, M. J. T.; Woods, P. T.; Jolliffe, B. W.; Swann, N. R. W.; Robinson, R. A.

    1992-01-01

    A tunable infrared differential absorption lidar (DIAL) system has been designed and developed at the National Physics Lab (NPL) which is capable of making measurements throughout the spectral region 3.0 to 4.2 micro-m. It is ideally suited to measuring a range of organic and inorganic species including methane, propane, and butane. The system also has an ultraviolet channel that is capable of making simultaneous measurements of aromatic hydrocarbons such as Toluene and benzene. This paper describes the source and detection system, together with some measurements of fugitive hydrocarbon emissions performed at various petrochemical plants.

  18. Measurements of fugitive hydrocarbon emissions with a tunable infrared DIAL

    NASA Technical Reports Server (NTRS)

    Milton, M. J. T.; Woods, P. T.; Jolliffe, B. W.; Swann, N. R. W.; Robinson, R. A.

    1992-01-01

    A tunable infrared differential absorption lidar (DIAL) system has been designed and developed at the National Physics Lab (NPL) which is capable of making measurements throughout the spectral region 3.0 to 4.2 micro-m. It is ideally suited to measuring a range of organic and inorganic species including methane, propane, and butane. The system also has an ultraviolet channel that is capable of making simultaneous measurements of aromatic hydrocarbons such as Toluene and benzene. This paper describes the source and detection system, together with some measurements of fugitive hydrocarbon emissions performed at various petrochemical plants.

  19. Measuring Greenhouse-Gas Emissions from a Synthetic Tracer Source

    NASA Astrophysics Data System (ADS)

    Wang, W.; Liu, W.; Zhang, T.; Lu, Y.

    2014-05-01

    This paper describes a controlled tracer-release experiment in which methane was released from a synthetic source at known rates. An open-path Fourier transform infrared (OP-FTIR) spectroscopy system was used to measure line-averaged methane concentrations downwind of the source. A Lagrangian stochastic (LS) dispersion model was employed to infer emission rates from downwind gas concentrations. The main purpose of our study was to investigate the ability of our open-path FTIR system combined with the LS dispersion model to accurately measure greenhouse gas emissions. In our study, the average ratio of the estimated emissions to actual release rates QLS/Q for CH4 was about 0.86 (σQLS/Q = 0.2, n = 6) and 0.84 (σQLS/Q = 0.22, n = 3) after data fi ltering for a 15- and a 30- min period, respectively. Although there is a limited amount of data in this experiment, the results demonstrate the potential of the measurement system for accurate quantifi cation of greenhouse gas emissions.

  20. Measurements of nitrous oxide emissions from vegetable production in China

    NASA Astrophysics Data System (ADS)

    Xiong, Zhengqin; Xie, Yingxin; Xing, Guangxi; Zhu, Zhaoliang; Butenhoff, Chris

    Nitrous oxide (N 2O) emissions resulting from Chinese vegetable production were measured. A site in suburban Nanjing (East coast; Jiangsu Province) was monitored from November 2001 to January 2003, in which five consecutive vegetable crops were sown. The crops consisted of radish, baby bok choy, lettuce, second planting of baby bok choy, and finally celery. Results suggested that N 2O emission events occur in pulses. The average N 2O-N flux for all five crops was 148±9 μg N m -2 h -1 and the average emission rate was 12±0.7 kg N ha -1. The average seasonal emission fluxes ranged from 37 μg N m -2 h -1 in the radish plot to 300 μg N m -2 h -1 in the celery plot. The celery field produced the greatest cumulative emission of 5.8 kg N ha -1 while the baby bok choy field had the lowest rate of 0.96-1.0 kg N ha -1. In total, 0.73% of applied fertilizer N was emitted as N 2O-N as a whole. The lettuce field had the largest emission factor of 2.2%. Results indicate that emissions from vegetable field are a potential source of national N 2O inventory. Temporal variation is much greater than spatial variation and the corresponding CV averaged 115% and 22%, respectively. Under the same total sampling quantity, increasing sampling frequency is more important than increasing spatial replicates.

  1. Measurement of stimulated Hawking emission in an analogue system.

    PubMed

    Weinfurtner, Silke; Tedford, Edmund W; Penrice, Matthew C J; Unruh, William G; Lawrence, Gregory A

    2011-01-14

    Hawking argued that black holes emit thermal radiation via a quantum spontaneous emission. To address this issue experimentally, we utilize the analogy between the propagation of fields around black holes and surface waves on moving water. By placing a streamlined obstacle into an open channel flow we create a region of high velocity over the obstacle that can include surface wave horizons. Long waves propagating upstream towards this region are blocked and converted into short (deep-water) waves. This is the analogue of the stimulated emission by a white hole (the time inverse of a black hole), and our measurements of the amplitudes of the converted waves demonstrate the thermal nature of the conversion process for this system. Given the close relationship between stimulated and spontaneous emission, our findings attest to the generality of the Hawking process.

  2. Measurements of transition probabilities for two N I infrared transitions and their application for diagnostics of low temperature plasmas

    NASA Astrophysics Data System (ADS)

    Baclawski, A.; Musielok, J.

    2010-02-01

    Spectra emitted from a wall-stabilized arc, running in a gas mixture of helium, argon, nitrogen, oxygen and traces of hydrogen have been studied. Intensities of selected spectral transitions of neutral nitrogen and oxygen have been measured. Applying the Boltzmann plot method and using a reliable set of O I transition probabilities of spectral lines, originating from levels considerably spread in excitation energies, the temperatures of arc plasmas have been determined. Line intensities of two N I infrared transitions, originating from doubly excited terms 3p' 2F o and 3p' 2G have been measured. In order to obtain the corresponding transition probabilities ( Aki) for these lines, intensities of other N I infrared lines, with well known transition probabilities (taken from recently published data by Wiese and Fuhr [W.L. Wiese and J.R. Fuhr, Improved critical compilations of selected atomic transition probabilities for neutral and singly ionized carbon and nitrogen, J. Phys. Chem. Ref. Data 36 (2007) 1287-1345] from National Institute of Standards and Technology — NIST) have been measured. For evaluation of the transition probabilities the temperatures obtained from the above mentioned O I Boltzmann plots have been used. The results agree satisfactorily with older data found in literature. The new Aki values for transitions involving the doubly excited levels, together with Aki values taken from the above mentioned NIST source (used for determination of the new Aki values), are proposed as a convenient set for determining temperatures of plasmas containing nitrogen atoms.

  3. Spectroscopic Temperature and Emissivity Measurements of Iron and Quartz

    NASA Astrophysics Data System (ADS)

    Akin, M. C.; Chau, R.; Crum, R. S.; Nguyen, J.; Ambrose, W. P.; Holmes, N. C.

    2016-12-01

    We report on progress toward measuring the temperature of Fe at 200 GPa, near the melting point on the Hugoniot, as part of an effort to obtain a complete equation of state for Fe. Fe was directly coated on a LiF tamping window and shock compressed using a two stage light gas gun. Radiance and reflectance were simultaneously measured from 350-750 nm using four streak spectrometers. Comparison of reflected and emitted light allows us to calculate emissivity as a function of wavelength to correct graybody emission to determine T, predicted to be around 5000K, and compare measured reflectance with band structure calculations. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

  4. Quality assured measurements of animal building emissions: odor concentrations.

    PubMed

    Jacobson, Larry D; Hetchler, Brian P; Schmidt, David R; Nicolai, Richard E; Heber, Albert J; Ni, Ji-Qin; Hoff, Steven J; Koziel, Jacek A; Zhang, Yuanhui; Beasley, David B; Parker, David B

    2008-06-01

    Standard protocols for sampling and measuring odor emissions from livestock buildings are needed to guide scientists, consultants, regulators, and policy-makers. A federally funded, multistate project has conducted field studies in six states to measure emissions of odor, coarse particulate matter (PM(10)), total suspended particulates, hydrogen sulfide, ammonia, and carbon dioxide from swine and poultry production buildings. The focus of this paper is on the intermittent measurement of odor concentrations at nearly identical pairs of buildings in each state and on protocols to minimize variations in these measurements. Air was collected from pig and poultry barns in small (10 L) Tedlar bags through a gas sampling system located in an instrument trailer housing gas and dust analyzers. The samples were analyzed within 30 hr by a dynamic dilution forced-choice olfactometer (a dilution apparatus). The olfactometers (AC'SCENT International Olfactometer, St. Croix Sensory, Inc.) used by all participating laboratories meet the olfactometry standards (American Society for Testing and Materials and European Committee for Standardization [CEN]) in the United States and Europe. Trained panelists (four to eight) at each laboratory measured odor concentrations (dilution to thresholds [DT]) from the bag samples. Odor emissions were calculated by multiplying odor concentration differences between inlet and outlet air by standardized (20 degrees C and 1 atm) building airflow rates.

  5. Measurement of the deuterium Balmer series line emission on EAST

    SciTech Connect

    Wu, C. R.; Xu, Z.; Jin, Z.; Zhang, P. F.; Huang, J. Gao, W.; Gao, W.; Chang, J. F.; Xu, J. C.; Duan, Y. M.; Chen, Y. J.; Zhang, L.; Wu, Z. W.; Li, J. G.; Hou, Y. M.

    2016-11-15

    Volume recombination plays an important role towards plasma detachment for magnetically confined fusion devices. High quantum number states of the Balmer series of deuterium are used to study recombination. On EAST (Experimental Advanced Superconducting Tokamak), two visible spectroscopic measurements are applied for the upper/lower divertor with 13 channels, respectively. Both systems are coupled with Princeton Instruments ProEM EMCCD 1024B camera: one is equipped on an Acton SP2750 spectrometer, which has a high spectral resolution ∼0.0049 nm with 2400 gr/mm grating to measure the D{sub α}(H{sub α}) spectral line and with 1200 gr/mm grating to measure deuterium molecular Fulcher band emissions and another is equipped on IsoPlane SCT320 using 600 gr/mm to measure high-n Balmer series emission lines, allowing us to study volume recombination on EAST and to obtain the related line averaged plasma parameters (T{sub e}, n{sub e}) during EAST detached phases. This paper will present the details of the measurements and the characteristics of deuterium Balmer series line emissions during density ramp-up L-mode USN plasma on EAST.

  6. Measurement of the deuterium Balmer series line emission on EAST

    NASA Astrophysics Data System (ADS)

    Wu, C. R.; Huang, J.; Gao, W.; Gao, W.; Xu, Z.; Chang, J. F.; Hou, Y. M.; Jin, Z.; Xu, J. C.; Duan, Y. M.; Zhang, P. F.; Chen, Y. J.; Zhang, L.; Wu, Z. W.; Li, J. G.

    2016-11-01

    Volume recombination plays an important role towards plasma detachment for magnetically confined fusion devices. High quantum number states of the Balmer series of deuterium are used to study recombination. On EAST (Experimental Advanced Superconducting Tokamak), two visible spectroscopic measurements are applied for the upper/lower divertor with 13 channels, respectively. Both systems are coupled with Princeton Instruments ProEM EMCCD 1024B camera: one is equipped on an Acton SP2750 spectrometer, which has a high spectral resolution ˜0.0049 nm with 2400 gr/mm grating to measure the Dα(Hα) spectral line and with 1200 gr/mm grating to measure deuterium molecular Fulcher band emissions and another is equipped on IsoPlane SCT320 using 600 gr/mm to measure high-n Balmer series emission lines, allowing us to study volume recombination on EAST and to obtain the related line averaged plasma parameters (Te, ne) during EAST detached phases. This paper will present the details of the measurements and the characteristics of deuterium Balmer series line emissions during density ramp-up L-mode USN plasma on EAST.

  7. Profiting from Probability; Combining Low and High Probability Isotopes as a Tool Extending the Dynamic Range of an Assay Measuring Amphetamine and Methamphetamine in Urine.

    PubMed

    Miller, Anna M; Goggin, Melissa M; Nguyen, An; Gozum, Stephanie D; Janis, Gregory C

    2017-06-01

    A wide range of concentrations are frequently observed when measuring drugs of abuse in urine toxicology samples; this is especially true for amphetamine and methamphetamine. Routine liquid chromatography-tandem mass spectrometry confirmatory methods commonly anchored at a 50 ng/mL lower limit of quantitation can span approximately a 100-fold concentration range before regions of non-linearity are reached deteriorating accurate quantitation and qualitative assessments. In our experience, approximately a quarter of amphetamine and methamphetamine positive samples are above a 5,000 ng/mL upper limit of quantitation and thus require reanalysis with dilution for accurate quantitative and acceptable qualitative results. We present here the development of an analytical method capable of accurately quantifying samples with concentrations spanning several orders of magnitude without the need for sample dilution and reanalysis. For each analyte the major isotopes were monitored for analysis through the lower concentration ranges (50-5,000 ng/mL), and the naturally occurring, low probability 13C2 isotopes were monitored for the analysis of the high concentration samples (5,000-100,000 ng/mL amphetamine and 5,000-200,000 ng/mL methamphetamine). The method simultaneously monitors transitions for the molecules containing only 12C and 13C2 isotopologues eliminating the need for re-extraction and reanalysis of high concentration samples. © The Author 2017. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  8. Evaluating measurements of carbon dioxide emissions using a precision source--A natural gas burner.

    PubMed

    Bryant, Rodney; Bundy, Matthew; Zong, Ruowen

    2015-07-01

    A natural gas burner has been used as a precise and accurate source for generating large quantities of carbon dioxide (CO2) to evaluate emissions measurements at near-industrial scale. Two methods for determining carbon dioxide emissions from stationary sources are considered here: predicting emissions based on fuel consumption measurements-predicted emissions measurements, and direct measurement of emissions quantities in the flue gas-direct emissions measurements. Uncertainty for the predicted emissions measurement was estimated at less than 1%. Uncertainty estimates for the direct emissions measurement of carbon dioxide were on the order of ±4%. The relative difference between the direct emissions measurements and the predicted emissions measurements was within the range of the measurement uncertainty, therefore demonstrating good agreement. The study demonstrates how independent methods are used to validate source emissions measurements, while also demonstrating how a fire research facility can be used as a precision test-bed to evaluate and improve carbon dioxide emissions measurements from stationary sources. Fossil-fuel-consuming stationary sources such as electric power plants and industrial facilities account for more than half of the CO2 emissions in the United States. Therefore, accurate emissions measurements from these sources are critical for evaluating efforts to reduce greenhouse gas emissions. This study demonstrates how a surrogate for a stationary source, a fire research facility, can be used to evaluate the accuracy of measurements of CO2 emissions.

  9. Searching for the Culprit of Anomalous Microwave Emission: An AKARI PAHrange Analysis of Probable Electric Dipole Emitting Regions

    NASA Astrophysics Data System (ADS)

    Bell, A. C.; Onaka, T.; Sakon, I.; Ishihara, D.; Kaneda, H.; Lee, H. G.; Itoh, M.; Ohsawa, R.; Hammonds, M.

    In the march forward of interstellar medium inquiry, many new species of interstellar dust have been modelled and discovered. The modes by which these species interact and evolve are beginning to be understood, but in recent years a peculiar new feature has appeared in microwave surveys. Anomalous microwave emission (AME), appearing between 10 and 90Ghz, has been correlated with thermal dust emission, leading to the popular suggestion that this anomaly is electric dipole emission from spinning dust [2]. The observed frequencies suggest that spinning grains should be on the order of 10nm in size, hinting at poly-cyclic aromatic hydrocarbon molecules. We present data from AKARI/Infrared Camera [1], due to the effective PAH/Unidentified Infrared Band (UIR) coverage of its 9um survey to investigate their role within a few regions showing strong AME in the Planck low frequency data. We include the well studied Perseus and ρOphiuchi clouds . We use the IRAS/IRIS 100µm data to account for the overall dust temperature. We present our results as abundance maps for dust emitting around 9µm, and 100µm. Part of the AME in these regions may actually be attributed to thermal dust emission, or the star forming nature of these targets is masking the vibrational modes of PAHs which should be present there, suggesting further investigation for various galactic environments.

  10. Backward-in-time Modeling to Identify Sources of Reactive Solutes in Groundwater Using Probabilities Conditioned on Concentration Measurements

    NASA Astrophysics Data System (ADS)

    Neupauer, R. M.; Lin, R.

    2003-12-01

    When contamination is observed in an aquifer, the source of contamination is often unknown. We present an approach that can be used to identify sources of contamination based on the observed distribution (spatial, temporal, or both) of the contaminant plume. Using backward-in-time advection dispersion theory, we first obtain a backward location probability distribution that describes the possible prior positions of the contamination. This distribution is independent of the measured concentrations of the contaminant. Next, we condition the probability distribution on the measured concentrations, resulting in an improvement in the accuracy and a reduction in the variance of the backward location probability distribution. We illustrate the approach for a reactive solute (first-order decay), and demonstrate its applicability for identifying possible source locations of a trichloroethylene plume at the Massachusetts Military Reservation.

  11. Confidence Probability versus Detection Probability

    SciTech Connect

    Axelrod, M

    2005-08-18

    In a discovery sampling activity the auditor seeks to vet an inventory by measuring (or inspecting) a random sample of items from the inventory. When the auditor finds every sample item in compliance, he must then make a confidence statement about the whole inventory. For example, the auditor might say: ''We believe that this inventory of 100 items contains no more than 5 defectives with 95% confidence.'' Note this is a retrospective statement in that it asserts something about the inventory after the sample was selected and measured. Contrast this to the prospective statement: ''We will detect the existence of more than 5 defective items in this inventory with 95% probability.'' The former uses confidence probability while the latter uses detection probability. For a given sample size, the two probabilities need not be equal, indeed they could differ significantly. Both these probabilities critically depend on the auditor's prior belief about the number of defectives in the inventory and how he defines non-compliance. In other words, the answer strongly depends on how the question is framed.

  12. Estimates of CO2 traffic emissions from mobile concentration measurements

    NASA Astrophysics Data System (ADS)

    Maness, H. L.; Thurlow, M. E.; McDonald, B. C.; Harley, R. A.

    2015-03-01

    We present data from a new mobile system intended to aid in the design of upcoming urban CO2-monitoring networks. Our collected data include GPS probe data, video-derived traffic density, and accurate CO2 concentration measurements. The method described here is economical, scalable, and self-contained, allowing for potential future deployment in locations without existing traffic infrastructure or vehicle fleet information. Using a test data set collected on California Highway 24 over a 2 week period, we observe that on-road CO2 concentrations are elevated by a factor of 2 in congestion compared to free-flow conditions. This result is found to be consistent with a model including vehicle-induced turbulence and standard engine physics. In contrast to surface concentrations, surface emissions are found to be relatively insensitive to congestion. We next use our model for CO2 concentration together with our data to independently derive vehicle emission rate parameters. Parameters scaling the leading four emission rate terms are found to be within 25% of those expected for a typical passenger car fleet, enabling us to derive instantaneous emission rates directly from our data that compare generally favorably to predictive models presented in the literature. The present results highlight the importance of high spatial and temporal resolution traffic data for interpreting on- and near-road concentration measurements. Future work will focus on transport and the integration of mobile platforms into existing stationary network designs.

  13. Atmospheric measurement of point source fossil CO2 emissions

    NASA Astrophysics Data System (ADS)

    Turnbull, J. C.; Keller, E. D.; Baisden, T.; Brailsford, G.; Bromley, T.; Norris, M.; Zondervan, A.

    2014-05-01

    We use the Kapuni Gas Treatment Plant to examine methodologies for atmospheric monitoring of point source fossil fuel CO2 (CO2ff) emissions. The Kapuni plant, located in rural New Zealand, removes CO2 from locally extracted natural gas and vents that CO2 to the atmosphere, at a rate of ~0.1 Tg carbon per year. The plant is located in a rural dairy farming area, with no other significant CO2ff sources nearby, but large, diurnally varying, biospheric CO2 fluxes from the surrounding highly productive agricultural grassland. We made flask measurements of CO2 and 14CO2 (from which we derive the CO2ff component) and in situ measurements of CO2 downwind of the Kapuni plant, using a Helikite to sample transects across the emission plume from the surface up to 100 m above ground level. We also determined the surface CO2ff content averaged over several weeks from the 14C content of grass samples collected from the surrounding area. We use the WindTrax plume dispersion model to compare the atmospheric observations with the emissions reported by the Kapuni plant, and to determine how well atmospheric measurements can constrain the emissions. The model has difficulty accurately capturing the fluctuations and short-term variability in the Helikite samples, but does quite well in representing the observed CO2ff in 15 min averaged surface flask samples and in ~ one week integrated CO2ff averages from grass samples. In this pilot study, we found that using grass samples, the modeled and observed CO2ff emissions averaged over one week agreed to within 30%. The results imply that greater verification accuracy may be achieved by including more detailed meteorological observations and refining 14C sampling strategies.

  14. Atmospheric measurement of point source fossil fuel CO2 emissions

    NASA Astrophysics Data System (ADS)

    Turnbull, J. C.; Keller, E. D.; Baisden, W. T.; Brailsford, G.; Bromley, T.; Norris, M.; Zondervan, A.

    2013-11-01

    We use the Kapuni Gas Treatment Plant to examine methodologies for atmospheric monitoring of point source fossil fuel CO2 (CO2ff) emissions. The Kapuni plant, located in rural New Zealand, removes CO2 from locally extracted natural gas and vents that CO2 to the atmosphere, at a rate of ~0.1 Tg carbon per year. The plant is located in a rural dairy farming area, with no other significant CO2ff sources nearby, but large, diurnally varying, biospheric CO2 fluxes from the surrounding highly productive agricultural grassland. We made flask measurements of CO2 and 14CO2 (from which we derive the CO2ff component) and in situ measurements of CO2 downwind of the Kapuni plant, using a Helikite to sample transects across the emission plume from the surface up to 100 m a.g.l. We also determined the surface CO2ff content averaged over several weeks from the 14CO2 content of grass samples collected from the surrounding area. We use the WindTrax plume dispersion model to compare the atmospheric observations with the emissions reported by the Kapuni plant, and to determine how well atmospheric measurements can constrain the emissions. The model has difficulty accurately capturing the fluctuations and short-term variability in the Helikite samples, but does quite well in representing the observed CO2ff in 15 min averaged surface flask samples and in ~1 week integrated CO2ff averages from grass samples. In this pilot study, we found that using grass samples, the modeled and observed CO2ff emissions averaged over one week agreed to within 30%. The results imply that greater verification accuracy may be achieved by including more detailed meteorological observations and refining 14CO2 sampling strategies.

  15. Measurement and modeling ammonia emissions from broiler litter

    NASA Astrophysics Data System (ADS)

    Liu, Zifei

    Ammonia is a very important atmospheric pollutant. Agricultural activities, livestock production in particular, have been reported to be the largest contributor of ammonia emissions into the atmosphere. Accurate estimation of ammonia emission rate from individual operations or sources is important and yet a challenging task for both regulatory agencies and animal producers. The overall research objective of this study was to develop an emission model which can be used to estimate ammonia emission from broiler litter. In the reported model, the ammonia flux is essentially a function of the litter's total ammoniacal nitrogen (TAN) content, moisture content, pH, and temperature, as well as the Freundlich partition coefficient (Kf), mass transfer coefficient (KG), ventilation rate (Q), and emission surface area (A). A dynamic flow-through chamber system and a wind tunnel were designed to measure ammonia fluxes from broiler litter. The dynamic flow-through chamber experiments evaluated the reported model with various litter samples under a constant temperature and wind profile. The wind tunnel experiments evaluated the reported model under various temperatures and wind profiles. Regression sub-models were developed to estimate Kf as a function of litter pH and temperature and to estimate KG as a function of air velocity and temperature. Sensitivity analysis of the model showed that ammonia flux is very sensitive to litter pH and to a lesser extent temperature. A validation metric based on the mean and covariance in the measurement and in the model parameters were used to validate the model in the presence of measurement and model parameter uncertainties.

  16. The Heated Halo for Space-Based Blackbody Emissivity Measurement

    NASA Astrophysics Data System (ADS)

    Gero, P.; Taylor, J. K.; Best, F. A.; Revercomb, H. E.; Garcia, R. K.; Adler, D. P.; Ciganovich, N. N.; Knuteson, R. O.; Tobin, D. C.

    2012-12-01

    The accuracy of radiance measurements with space-based infrared spectrometers is contingent on the quality of the calibration subsystem, as well as knowledge of its uncertainty. Upcoming climate benchmark missions call for measurement uncertainties better than 0.1 K (k=3) in radiance temperature for the detection of spectral climate signatures. Blackbody cavities impart the most accurate calibration for spaceborne infrared sensors, provided that their temperature and emissivity is traceably determined on-orbit. The On-Orbit Absolute Radiance Standard (OARS) has been developed at the University of Wisconsin and has undergone further refinement under the NASA Instrument Incubator Program (IIP) to meet the stringent requirements of the next generation of infrared remote sensing instruments. It provides on-orbit determination of both traceable temperature and emissivity for calibration blackbodies. The Heated Halo is the component of the OARS that provides a robust and compact method to measure the spectral emissivity of a blackbody in situ. A carefully baffled thermal source is placed in front of a blackbody in an infrared spectrometer system, and the combined radiance of the blackbody and Heated Halo reflection is observed. Knowledge of key temperatures and the viewing geometry allow the blackbody cavity spectral emissivity to be calculated. We present the results from the Heated Halo methodology implemented with a new Absolute Radiance Interferometer (ARI), which is a prototype space-based infrared spectrometer designed for climate benchmarking. We show the evolution of the technical readiness level of this technology and we compare our findings to models and other experimental methods of emissivity determination.

  17. Emission factors of PM species based on freeway measurements and comparison with tunnel and dynamometer studies

    NASA Astrophysics Data System (ADS)

    Ning, Zhi; Polidori, Andrea; Schauer, James J.; Sioutas, Constantinos

    Emission factors of various particle species from light- and heavy-duty vehicles (LDVs and HDVs, respectively), including organic and elemental carbon (OC and EC), sulfate, polycyclic aromatic hydrocarbons (PAHs), hopanes, steranes, trace metals, elements, and particle number (PN), were estimated based on roadway measurements. Sampling campaigns were conducted at two different roadways: the CA-110 highway (where only gasoline-powered vehicles are allowed), and the I-710 freeway (where about 20% of the total number of vehicles are diesel-powered trucks). The particulate matter (PM) emission factors determined in these roadways were compared to those reconstructed from recent source emission data from the Caldecott tunnel [Phuleria, H.C., Geller, M.D., Fine, P.M., Sioutas, C., 2006. Size-resolved emissions of organic tracers from light- and heavy-duty vehicles measured in a California roadway tunnel. Environmental Science and Technology 40 (13), 4109-4118], and those from previous tunnel and chassis dynamometer studies. Very good agreement between estimated and reconstructed emission factors was found for PN, EC, sulfate, high-molecular-weight (MW) PAHs, hopanes and steranes. This suggests that PM-speciated chemical data collected at roadsides can be used to calculate reliable emission factors for several important particle species at other locations characterized by a similar mix of on-road motor vehicles. The agreement between our results and other studies in the emission factors of trace elements and metals varied from very good (for species such as Cu, Mo, Ba, Pb) to poor (for species such as Mg, Fe, Ca), probably because the atmospheric concentrations of the latter elements are associated with both traffic and non-traffic sources, and the relative abundances of Mg, Ca, and Fe in road dust varies considerably across locations. The emission factors of OC and EC were clearly the highest for HDVs, and those of PAHs, hopanes, and steranes from our roadway

  18. 14 CFR 34.64 - Sampling and analytical procedures for measuring gaseous exhaust emissions.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE... Turbine Engines) § 34.64 Sampling and analytical procedures for measuring gaseous exhaust emissions....

  19. 14 CFR 34.64 - Sampling and analytical procedures for measuring gaseous exhaust emissions.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE... Turbine Engines) § 34.64 Sampling and analytical procedures for measuring gaseous exhaust emissions....

  20. Measurements of in-use emissions from modern vehicles using an on-board measurement system.

    PubMed

    Collins, John F; Shepherd, Paul; Durbin, Thomas D; Lents, James; Norbeck, Joseph; Barth, Matthew

    2007-09-15

    Emissions from "low emitting" modern vehicles were measured on-road using a Fourier transform infrared (FTIR) on-board emissions measurement system. Twenty vehicles were tested on road and on a chassis dynamometer. A subset of four vehicles was tested on a test track as well as on the dynamometer. Comparison of on-board measurements with laboratory measurements while operating on the dynamometer showed agreement within measurement and test to test variability. Comparison of dynamometer measurements with test track measurements showed some larger differences attributable to track test conditions. On-road and dynamometer tests were conducted on the remaining 16 vehicles, with the on-road testing including freeway, arterial, and residential streets. The on-road testing showed that most of the low emitting vehicles under most operating conditions are operating below certification levels. Most vehicles reached a hot stabilized condition within 60 to 100 s. Hot running emissions were on average very low once the catalyst lights off. For NMHC, the majority of the "certification" emissions occur during the start-up, especially for PZEVs. NOx and CO also showed a high fraction of "certification" emissions during start-up, but also showed emission spikes under hot running conditions, especially during transients.

  1. Projectile Two-dimensional Coordinate Measurement Method Based on Optical Fiber Coding Fire and its Coordinate Distribution Probability

    NASA Astrophysics Data System (ADS)

    Li, Hanshan; Lei, Zhiyong

    2013-01-01

    To improve projectile coordinate measurement precision in fire measurement system, this paper introduces the optical fiber coding fire measurement method and principle, sets up their measurement model, and analyzes coordinate errors by using the differential method. To study the projectile coordinate position distribution, using the mathematical statistics hypothesis method to analyze their distributing law, firing dispersion and probability of projectile shooting the object center were put under study. The results show that exponential distribution testing is relatively reasonable to ensure projectile position distribution on the given significance level. Through experimentation and calculation, the optical fiber coding fire measurement method is scientific and feasible, which can gain accurate projectile coordinate position.

  2. Transient Earth system responses to cumulative carbon dioxide emissions: linearities, uncertainties, and probabilities in an observation-constrained model ensemble

    NASA Astrophysics Data System (ADS)

    Steinacher, M.; Joos, F.

    2016-02-01

    Information on the relationship between cumulative fossil CO2 emissions and multiple climate targets is essential to design emission mitigation and climate adaptation strategies. In this study, the transient response of a climate or environmental variable per trillion tonnes of CO2 emissions, termed TRE, is quantified for a set of impact-relevant climate variables and from a large set of multi-forcing scenarios extended to year 2300 towards stabilization. An ˜ 1000-member ensemble of the Bern3D-LPJ carbon-climate model is applied and model outcomes are constrained by 26 physical and biogeochemical observational data sets in a Bayesian, Monte Carlo-type framework. Uncertainties in TRE estimates include both scenario uncertainty and model response uncertainty. Cumulative fossil emissions of 1000 Gt C result in a global mean surface air temperature change of 1.9 °C (68 % confidence interval (c.i.): 1.3 to 2.7 °C), a decrease in surface ocean pH of 0.19 (0.18 to 0.22), and a steric sea level rise of 20 cm (13 to 27 cm until 2300). Linearity between cumulative emissions and transient response is high for pH and reasonably high for surface air and sea surface temperatures, but less pronounced for changes in Atlantic meridional overturning, Southern Ocean and tropical surface water saturation with respect to biogenic structures of calcium carbonate, and carbon stocks in soils. The constrained model ensemble is also applied to determine the response to a pulse-like emission and in idealized CO2-only simulations. The transient climate response is constrained, primarily by long-term ocean heat observations, to 1.7 °C (68 % c.i.: 1.3 to 2.2 °C) and the equilibrium climate sensitivity to 2.9 °C (2.0 to 4.2 °C). This is consistent with results by CMIP5 models but inconsistent with recent studies that relied on short-term air temperature data affected by natural climate variability.

  3. Thermospheric metal emissions: update on GLO Mg+ measurements

    NASA Astrophysics Data System (ADS)

    Gardner, James A.; Murad, Edmond; Knecht, David J.; Viereck, Rodney A.; Pike, Charles P.; Broadfoot, A. Lyle

    1996-10-01

    The GLO experiment includes a ground-controlled shuttle- based UV-vis-IR spectrograph and imager set, and has flown on four space shuttle flights, including three in 1995. Each flight returned limb-view on metal atom and ion emissions in the 80-350 km tangent height region. Improved optics provided 0.3 nm FWHM resolution in the ultraviolet, and simultaneous altitude profiles were routinely measured that spanned 150 km in tangent height with 10-15 km resolution. CLouds of metal ions, particularly Mg+, were observed in daytime above 120 km tangent height near the geomagnetic equator. The GLO project returned approximately 30 gigabytes of spectral data in 1995. The current high altitude metal ion emission measurements are reported here.

  4. Evidence for a low surface temperature on pluto from millimeter-wave thermal emission measurements.

    PubMed

    Stern, S A; Weintraub, D A; Festou, M C

    1993-09-24

    Thermal continuum emission from the Pluto-Charon system has been detected at wavelents of 800 and 1300 micrometers, and significant upper limits have been obtained at 450 and 1100 micrometers. After the subtraction of emission from Charon, the deduced surface temperature of much of Pluto is between 30 and 44 kein, probably near 35 to 37 kelvin. This range is significantly cooler than what radiative equilibrium models have suged and cooler than the surface temperature derived by the Infrared Astronomy Satellite. The low temperature indicates that methane cannot be present at the microbar pressure levels indicated by the 1988 stellar occultation measurements and that the methane features in Pluto's spectrum are from solid, not gas-phase, absorptions. This result is evidence that Pluto's atmosphere is dominated by nitrogen or carbon monoxide rather than methane.

  5. Determining the Differential Emission Measure from EIS, XRT, and AIA

    NASA Technical Reports Server (NTRS)

    Winebarger, Amy R.; Warren, H.P.; Schmelz, J.

    2010-01-01

    This viewgraph presentation determines the Differential Emission Measure (DEM) from the EUV Imaging Spectrometer (EIS), X Ray Telescope (XRT), and Atmospheric Imaging Array (AIA). Common observations with Fe, Si, and Ca EIS lines are shown along with observations with Al-mesh, Ti-poly Al-thick and Be-thick XRT filters. Results from these observations are shown to determine what lines and filters are important to better constrain the hot component.

  6. Quasi-probabilities in conditioned quantum measurement and a geometric/statistical interpretation of Aharonov's weak value

    NASA Astrophysics Data System (ADS)

    Lee, Jaeha; Tsutsui, Izumi

    2017-05-01

    We show that the joint behavior of an arbitrary pair of (generally noncommuting) quantum observables can be described by quasi-probabilities, which are an extended version of the standard probabilities used for describing the outcome of measurement for a single observable. The physical situations that require these quasi-probabilities arise when one considers quantum measurement of an observable conditioned by some other variable, with the notable example being the weak measurement employed to obtain Aharonov's weak value. Specifically, we present a general prescription for the construction of quasi-joint probability (QJP) distributions associated with a given combination of observables. These QJP distributions are introduced in two complementary approaches: one from a bottom-up, strictly operational construction realized by examining the mathematical framework of the conditioned measurement scheme, and the other from a top-down viewpoint realized by applying the results of the spectral theorem for normal operators and their Fourier transforms. It is then revealed that, for a pair of simultaneously measurable observables, the QJP distribution reduces to the unique standard joint probability distribution of the pair, whereas for a noncommuting pair there exists an inherent indefiniteness in the choice of such QJP distributions, admitting a multitude of candidates that may equally be used for describing the joint behavior of the pair. In the course of our argument, we find that the QJP distributions furnish the space of operators in the underlying Hilbert space with their characteristic geometric structures such that the orthogonal projections and inner products of observables can be given statistical interpretations as, respectively, "conditionings" and "correlations". The weak value Aw for an observable A is then given a geometric/statistical interpretation as either the orthogonal projection of A onto the subspace generated by another observable B, or equivalently

  7. Thermal conductivity and emissivity measurements of uranium carbides

    NASA Astrophysics Data System (ADS)

    Corradetti, S.; Manzolaro, M.; Andrighetto, A.; Zanonato, P.; Tusseau-Nenez, S.

    2015-10-01

    Thermal conductivity and emissivity measurements on different types of uranium carbide are presented, in the context of the ActiLab Work Package in ENSAR, a project within the 7th Framework Program of the European Commission. Two specific techniques were used to carry out the measurements, both taking place in a laboratory dedicated to the research and development of materials for the SPES (Selective Production of Exotic Species) target. In the case of thermal conductivity, estimation of the dependence of this property on temperature was obtained using the inverse parameter estimation method, taking as a reference temperature and emissivity measurements. Emissivity at different temperatures was obtained for several types of uranium carbide using a dual frequency infrared pyrometer. Differences between the analyzed materials are discussed according to their compositional and microstructural properties. The obtainment of this type of information can help to carefully design materials to be capable of working under extreme conditions in next-generation ISOL (Isotope Separation On-Line) facilities for the generation of radioactive ion beams.

  8. Neutron emission profiles and energy spectra measurements at JET

    NASA Astrophysics Data System (ADS)

    Giacomelli, L.; Conroy, S.; Belli, F.; Gorini, G.; Horton, L.; Joffrin, E.; Lerche, E.; Murari, A.; Popovichev, S.; Riva, M.; Syme, B.; JET EFDA Contributors

    2014-08-01

    The Joint European Toras (JET, Culham, UK) is the largest tokamak in the world. It is devoted to nuclear fusion experiments of magnetic confined Deuterium (D) or Deuterium-Tritium (DT) plasmas. JET has been upgraded over the years and recently it has also become a test facility of the components designed for ITER, the next step fusion machine under construction in Cadarache (France). JET makes use of many different diagnostics to measure the physical quantities of interest in plasma experiments. Concerning D or DT plasmas neutron production, various types of detectors are implemented to provide information upon the neutron total yield, emission profile and energy spectrum. The neutron emission profile emitted from the JET plasma poloidal section is reconstructed using the neutron camera (KN3). In 2010 KN3 was equipped with a new digital data acquisition system capable of high rate neutron measurements (<0.5 MCps). A similar instrument will be implemented on ITER and it is currently in its design phase. Various types of neutron spectrometers with different view lines are also operational on JET. One of them is a new compact spectrometer (KM12) based on organic liquid scintillating material which was installed in 2010 and implements a similar digital data acquisition system as for KN3. This article illustrates the measurement results of KN3 neutron emission profiles and KM 12 neutron energy spectra from the latest JET D experimental campaign C31.

  9. Measurement of photoemission and secondary emission from laboratory dust grains

    NASA Technical Reports Server (NTRS)

    Hazelton, Robert C.; Yadlowsky, Edward J.; Settersten, Thomas B.; Spanjers, Gregory G.; Moschella, John J.

    1995-01-01

    The overall goal of this project is experimentally determine the emission properties of dust grains in order to provide theorists and modelers with an accurate data base to use in codes that predict the charging of grains in various plasma environments encountered in the magnetospheres of the planets. In general these modelers use values which have been measured on planar, bulk samples of the materials in question. The large enhancements expected due to the small size of grains can have a dramatic impact upon the predictions and the ultimate utility of these predictions. The first experimental measurement of energy resolved profiles of the secondary electron emission coefficient, 6, of sub-micron diameter particles has been accomplished. Bismuth particles in the size range of .022 to .165 micrometers were generated in a moderate pressure vacuum oven (average size is a function of oven temperature and pressure) and introduced into a high vacuum chamber where they interacted with a high energy electron beam (0.4 to 20 keV). Large enhancements in emission were observed with a peak value, delta(sub max) = 4. 5 measured for the ensemble of particles with a mean size of .022 micrometers. This is in contrast to the published value, delta(sub max) = 1.2, for bulk bismuth. The observed profiles are in general agreement with recent theoretical predictions made by Chow et al. at UCSD.

  10. Asymmetries in coronal spectral lines and emission measure distribution

    SciTech Connect

    Tripathi, Durgesh; Klimchuk, James A.

    2013-12-10

    It has previously been argued that (1) spicules do not provide enough pre-heated plasma to fill the corona, and (2) even if they did, additional heating would be required to keep the plasma hot as it expands upward. Here we address whether spicules play an important role by injecting plasma at cooler temperatures (<2 MK), which then gets heated to coronal values at higher altitudes. We measure red-blue asymmetries in line profiles formed over a wide range of temperatures in the bright moss areas of two active regions. We derive emission measure distributions from the excess wing emission. We find that the asymmetries and emission measures are small and conclude that spicules do not inject an important (dominant) mass flux into the cores of active regions at temperatures >0.6 MK (log T > 5.8). These conclusions apply not only to spicules but also to any process that suddenly heats and accelerates chromospheric plasma (e.g., a chromospheric nanoflare). The traditional picture of coronal heating and chromospheric evaporation appears to remain the most likely explanation of the active region corona.

  11. Evaluation of VOC emission measurement methods for paint spray booths.

    PubMed

    Eklund, B M; Nelson, T P

    1995-03-01

    Interest in regulations to control solvent emissions from automotive painting systems is increasing, especially in ozone nonattainment areas. Therefore, an accurate measurement method for VOC emissions from paint spray booths used in the automotive industry is needed to ascertain the efficiency of the spray booth capture and the total emissions. This paper presents the results of a laboratory study evaluating potential VOC sampling and analytical methods used in estimating paint spray booth emissions, and discusses these results relative to other published data. Eight test methods were selected for evaluation. The accuracy of each sampling and analytical method was determined using test atmospheres of known concentration and composition that closely matched the actual exhaust air from paint spray booths. The solvent mixture to generate the test atmospheres contained a large proportion of polar, oxygenated hydrocarbons such as ketones and alcohols. A series of identical tests was performed for each sampling/analytical method with each test atmosphere to assess the precision of the methods. The study identified significant differences among the test methods in terms of accuracy, precision, cost, and complexity.

  12. The measurement of alpha particle emissions from semiconductor memory materials

    NASA Astrophysics Data System (ADS)

    Bouldin, D. P.

    1981-07-01

    With the increasing concern for the affects of alpha particles on the reliability of semiconductor memories, an interest has arisen in characterizing semiconductor manufacturing materials for extremely low-level alpha-emitting contaminants. It is shown that four elements are of primary concern: uranium, thorium, radium, and polonium. Measurement of contamination levels are given relevance by first correlating them with alpha flux emission levels and then corre1ating these flux values with device soft error rates. Measurement techniques involve either measurements of elemental concentrations-applicable to only uranium and thorium - or direct measurements of alpha emission fluxes. Alpha fluxes are most usefully measured by means of ZnS scintillation counting, practical details of which are discussed. Materials measurements are reported for ceramics, solder, silicon, quartz, and various metals and organic materials. Ceramics and most metals have contamination levels of concern, but the high temperature processing normally used in semiconductor manufacturing and low total amounts reduce problems, at least for metals. Silicon, silicon compounds, and organic materials have been found to have no detectable alpha emitters. Finally, a brief discussion of the calibration of alpha sources for accelerated device testing is given, including practical details on the affects of source/chip separation and alignment variations.

  13. Multi-decadal satellite measurements of passive and eruptive volcanic SO2 emissions

    NASA Astrophysics Data System (ADS)

    Carn, Simon; Yang, Kai; Krotkov, Nickolay; Prata, Fred; Telling, Jennifer

    2015-04-01

    strongest volcanic SO2 sources between 2004 and 2015. OMI measurements are most sensitive to SO2 emission rates on the order of ~1000 tons/day or more, and thus the satellite data provide new constraints on the location and persistence of major volcanic SO2 sources. We find that OMI has detected non-eruptive SO2 emissions from at least ~60 volcanoes since 2004. Results of our analysis reveal the emergence of several major tropospheric SO2 sources that are not prominent in existing inventories (Ambrym, Nyiragongo, Turrialba, Ubinas), the persistence of some well-known sources (Etna, Kilauea) and a possible decline in emissions at others (e.g., Lascar). The OMI measurements provide particularly valuable information in regions lacking regular ground-based monitoring such as Indonesia, Melanesia and Kamchatka. We describe how the OMI measurements of SO2 total column, and their probability density function, can be used to infer SO2 emission rates for compatibility with existing emissions data and assimilation into chemical transport models. The satellite-derived SO2 emission rates are in good agreement with ground-based measurements from frequently monitored volcanoes (e.g., from the NOVAC network), but differ for other volcanoes. We conclude that some ground-based SO2 measurements may be biased high if collected during periods of elevated unrest, and hence may not be representative of long-term average emissions.

  14. Direct measurements of methane emissions from grazing and feedlot cattle.

    PubMed

    Harper, L A; Denmead, O T; Freney, J R; Byers, F M

    1999-06-01

    Methane (CH4) emissions from animals represent a significant contribution to anthropogenically produced radiatively active trace gases. Global and national CH4 budgets currently use predictive models based on emission data from laboratory experiments to estimate the magnitude of the animal source. This paper presents a method for measuring CH4 from animals under undisturbed field conditions and examines the performance of common models used to simulate field conditions. A micrometeorological mass difference technique was developed to measure CH4 production by cattle in pasture and feedlot conditions. Measurements were made continuously under field conditions, semiautomatically for several days, and the technique was virtually nonintrusive. The method permits a relatively large number of cattle to be sampled. Limitations include light winds (less than approximately 2 m/s), rapid wind direction changes, and high-precision CH4 gas concentration measurement. Methane production showed a marked periodicity, with greater emissions during periods of rumination as opposed to grazing. When the cattle were grazed on pasture, they produced .23 kg CH4 x animal(-1) x d(-1), which corresponded to the conversion of 7.7 to 8.4% of gross energy into CH4. When the same cattle were fed a highly digestible, high-grain diet, they produced .07 kg CH4 x animal(-1) x d(-1), corresponding to a conversion of only 1.9 to 2.2% of the feed energy to CH4. These measurements clearly document higher CH4 production (about four times) for cattle receiving low-quality, high-fiber diets than for cattle fed high-grain diets. The mass difference method provides a useful tool for "undisturbed" measurements on the influence of feedstuffs and nutritional management practices on CH4 production from animals and for developing improved management practice for enhanced environmental quality.

  15. First Compilation and Evaluation of Beta-Delayed Neutron Emission Probabilities and Associated Half-Lives for A ≤ 72 Nuclei

    SciTech Connect

    Birch, M.; Singh, B.; Abriola, D.; Dillmann, I.; Johnson, T.D.; McCutchan, E.A.; Sonzogni, A.A.

    2014-06-15

    A comprehensive compilation and evaluation of beta-delayed neutron (β{sup −}n) emission probabilities, P{sub n}, and associated half-lives for A ≤ 72 nuclei has been performed for the first time. The recommended values have been used to analyze the systematics of β{sup −}n emission in this region. The ratio P{sub n}/T{sub 1/2} is better correlated with the Q-value of the β{sup −}n decay mode than the previously proposed Kratz-Herrmann Formula (KHF). The recommended values are also compared with theoretical quasi-particle random phase approximation (QRPA) calculations.

  16. Measurements of wavelength-dependent double photoelectron emission from single photons in VUV-sensitive photomultiplier tubes

    NASA Astrophysics Data System (ADS)

    Faham, C. H.; Gehman, V. M.; Currie, A.; Dobi, A.; Sorensen, P.; Gaitskell, R. J.

    2015-09-01

    Measurements of double photoelectron emission (DPE) probabilities as a function of wavelength are reported for Hamamatsu R8778, R8520, and R11410 VUV-sensitive photomultiplier tubes (PMTs). In DPE, a single photon strikes the PMT photocathode and produces two photoelectrons instead of a single one. It was found that the fraction of detected photons that result in DPE emission is a function of the incident photon wavelength, and manifests itself below ~250 nm. For the xenon scintillation wavelength of 175 nm, a DPE probability of 18-24% was measured depending on the tube and measurement method. This wavelength-dependent single photon response has implications for the energy calibration and photon counting of current and future liquid xenon detectors such as LUX, LZ, XENON100/1T, Panda-X and XMASS.

  17. Verifying Inventory Predictions of Animal Methane Emissions with Meteorological Measurements

    NASA Astrophysics Data System (ADS)

    Denmead, O.T.; Leuning, R.; Griffith, D.W.T.; Jamie, I.M.; Esler, M.B.; Harper, L.A.; Freney, J.R.

    The paper examines the strengths and weaknesses of a rangeof meteorological flux measurement techniques that mightbe used to verify predictions of greenhouse gas inventories.Recent research into emissions of methane (CH4)produced by enteric fermentation in grazing cattle and sheepis used to illustrate various methodologies. Quantifying thisimportant source presents special difficulties because the animalsconstitute moving, heterogeneously distributed, intermittent, pointsources. There are two general approaches: one, from the bottom up,involves direct measurements of emissions from a known number ofanimals, and the other, from the top down, infers areal emissions ofCH4 from its atmospheric signature. A mass-balance methodproved successful for bottom-up verification. It permits undisturbedgrazing, has a simple theoretical basis and is appropriate for fluxmeasurements on small plots and where there are scattered pointsources. The top-down methodologies include conventional flux-gradientapproaches and convective and nocturnal boundary-layer (CBL and NBL)budgeting schemes. Particular attention is given to CBL budget methods inboth differential and integral form. All top-down methodologies require ideal weather conditions for their application, and they suffer from the scattered nature of the source, varying wind directions and low instrument resolution. As for mass-balance, flux-gradient micrometeorological measurements were in good agreement with inventory predictions of CH4 production by livestock, but the standard errors associated with both methods were too large to permit detection of changes of a few per cent in emission rate, which might be important for inventory, regulatory or research purposes. Fluxes calculated by CBL and NBL methods were of the same order of magnitude as inventory predictions, but more improvement is needed before their use can be endorsed. Opportunities for improving the precision of both bottom-up and top-down methodologies are discussed.

  18. Work function measurements using a field emission retarding potential technique

    NASA Astrophysics Data System (ADS)

    Hamanaka, M. H. M. O.; Dall'Agnol, F. F.; Pimentel, V. L.; Mammana, V. P.; Tatsch, P. J.; den Engelsen, D.

    2016-03-01

    Herein we describe the measurement of the work function of a metal with advanced equipment based on the field emission retarding potential (FERP) method using a carbon nanotube (CNT) as cathode. The accuracy of the FERP method using a CNT emitter is described and a comparison between measurements of the work functions of aluminum, barium, calcium, gold, and platinum with published data will be presented. Our FERP equipment could be optimized with the aid of particle tracing simulations. These simulations led us to insert a magnetic collimator to improve the collection efficiency at the anode.

  19. Measurement of radio emission from extensive air showers with LOPES

    NASA Astrophysics Data System (ADS)

    Hörandel, J. R.; Apel, W. D.; Arteaga, J. C.; Asch, T.; Badea, F.; Bähren, L.; Bekk, K.; Bertaina, M.; Biermann, P. L.; Blümer, J.; Bozdog, H.; Brancus, I. M.; Brüggemann, M.; Buchholz, P.; Buitink, S.; Cantoni, E.; Chiavassa, A.; Cossavella, F.; Daumiller, K.; de Souza, V.; di Pierro, F.; Doll, P.; Ender, M.; Engel, R.; Falcke, H.; Finger, M.; Fuhrmann, D.; Gemmeke, H.; Ghia, P. L.; Glasstetter, R.; Grupen, C.; Haungs, A.; Heck, D.; Horneffer, A.; Huege, T.; Isar, P. G.; Kampert, K.-H.; Kang, D.; Kickelbick, D.; Krömer, O.; Kuijpers, J.; Lafebre, S.; Link, K.; Łuczak, P.; Ludwig, M.; Mathes, H. J.; Mayer, H. J.; Melissas, M.; Mitrica, B.; Morello, C.; Navarra, G.; Nehls, S.; Nigl, A.; Oehlschläger, J.; Over, S.; Palmieri, N.; Petcu, M.; Pierog, T.; Rautenberg, J.; Rebel, H.; Roth, M.; Saftoiu, A.; Schieler, H.; Schmidt, A.; Schröder, F.; Sima, O.; Singh, K.; Toma, G.; Trinchero, G. C.; Ulrich, H.; Weindl, A.; Wochele, J.; Wommer, M.; Zabierowski, J.; Zensus, J. A.

    2011-02-01

    A new method is explored to detect extensive air showers: the measurement of radio waves emitted during the propagation of the electromagnetic shower component in the magnetic field of the Earth. Recent results of the pioneering experiment LOPES are discussed. It registers radio signals in the frequency range between 40 and 80 MHz. The intensity of the measured radio emission is investigated as a function of different shower parameters, such as shower energy, angle of incidence, and distance to shower axis. In addition, new antenna types are developed in the framework of LOPESstar and new methods are explored to realize a radio self-trigger algorithm in real time.

  20. Time Resolved Measurements of Speciated Tailpipe Emissions from Motor Vehicles: Trends with Emission Control Technology, Cold Start Effects, and Speciation.

    PubMed

    Drozd, Greg T; Zhao, Yunliang; Saliba, Georges; Frodin, Bruce; Maddox, Christine; Weber, Robert J; Chang, M-C Oliver; Maldonado, Hector; Sardar, Satya; Robinson, Allen L; Goldstein, Allen H

    2016-12-20

    Experiments were conducted at the California Air Resources Board Haagen-Smit Laboratory to understand changes in vehicle emissions in response to stricter emissions standards over the past 25 years. Measurements included a wide range of volatile organic compounds (VOCs) for a wide range of spark ignition gasoline vehicles meeting varying levels of emissions standards, including all certifications from Tier 0 up to Partial Zero Emission Vehicle. Standard gas chromatography (GC) and high performance liquid chromatography (HLPC) analyses were employed for drive-cycle phase emissions. A proton-transfer-reaction mass spectrometer measured time-resolved emissions for a wide range of VOCs. Cold-start emissions occur almost entirely in the first 30-60 s for newer vehicles. Cold-start emissions have compositions that are not significantly different across all vehicles tested and are markedly different from neat fuel. Hot-stabilized emissions have varying importance depending on species and may require a driving distance of 200 miles to equal the emissions from a single cold start. Average commute distances in the U.S. suggest the majority of in-use vehicles have emissions dominated by cold starts. The distribution of vehicle ages in the U.S. suggests that within several years only a few percent of vehicles will have significant driving emissions compared to cold-start emissions.

  1. Monitoring Surface Climate With its Emissivity Derived From Satellite Measurements

    NASA Technical Reports Server (NTRS)

    Zhou, Daniel K.; Larar, Allen M.; Liu, Xu

    2012-01-01

    Satellite thermal infrared (IR) spectral emissivity data have been shown to be significant for atmospheric research and monitoring the Earth fs environment. Long-term and large-scale observations needed for global monitoring and research can be supplied by satellite-based remote sensing. Presented here is the global surface IR emissivity data retrieved from the last 5 years of Infrared Atmospheric Sounding Interferometer (IASI) measurements observed from the MetOp-A satellite. Monthly mean surface properties (i.e., skin temperature T(sub s) and emissivity spectra epsilon(sub v) with a spatial resolution of 0.5x0.5-degrees latitude-longitude are produced to monitor seasonal and inter-annual variations. We demonstrate that surface epsilon(sub v) and T(sub s) retrieved with IASI measurements can be used to assist in monitoring surface weather and surface climate change. Surface epsilon(sub v) together with T(sub s) from current and future operational satellites can be utilized as a means of long-term and large-scale monitoring of Earth 's surface weather environment and associated changes.

  2. Contribution of correlated noise and selective decoding to choice probability measurements in extrastriate visual cortex.

    PubMed

    Gu, Yong; Angelaki, Dora E; DeAngelis, Gregory C

    2014-07-01

    Trial by trial covariations between neural activity and perceptual decisions (quantified by choice Probability, CP) have been used to probe the contribution of sensory neurons to perceptual decisions. CPs are thought to be determined by both selective decoding of neural activity and by the structure of correlated noise among neurons, but the respective roles of these factors in creating CPs have been controversial. We used biologically-constrained simulations to explore this issue, taking advantage of a peculiar pattern of CPs exhibited by multisensory neurons in area MSTd that represent self-motion. Although models that relied on correlated noise or selective decoding could both account for the peculiar pattern of CPs, predictions of the selective decoding model were substantially more consistent with various features of the neural and behavioral data. While correlated noise is essential to observe CPs, our findings suggest that selective decoding of neuronal signals also plays important roles.

  3. Amplitude spectrum area: measuring the probability of successful defibrillation as applied to human data.

    PubMed

    Young, Clayton; Bisera, Joe; Gehman, Stacy; Snyder, David; Tang, Wanchun; Weil, Max Harry

    2004-09-01

    The objective of our study was to examine the effectiveness of an electrocardiographic predictor, amplitude spectral area (AMSA), for the optimal timing of defibrillation shocks in human victims of cardiac arrest. Based on the spectral characteristics of ventricular fibrillation potentials, we examined the probability of successful conversion to an organized viable rhythm, including the return of spontaneous circulation. The incentive was to predict the likelihood of successful defibrillation and thereby improve outcomes by minimizing interruptions in chest compression and minimizing electrically induced myocardial injury due to repetitive high-current shocks. Observational study on human electrocardiographic recordings during cardiopulmonary resuscitation. Medical research laboratory of a university-affiliated research and educational institute. Victims of out-of-hospital cardiac arrest. Iteration of electrocardiographic records, representing lead 2 equivalent recordings on 108 defibrillation attempts with an automated external defibrillator, of 46 victims of cardiac arrest due to ventricular fibrillation. Three seconds of ventricular fibrillation, recorded immediately preceding delivery of a shock, were analyzed utilizing the AMSA algorithm. AMSA represents a numerical value based on the sum of the magnitude of the weighted frequency spectrum between 3 and 48 Hz. The greater the AMSA value, the greater was the probability of reversal of ventricular fibrillation. At an AMSA value of >13.0 mV-Hz, successful defibrillation yielded a sensitivity of .91 and a specificity of .94. AMSA predicts the success of electrical defibrillation with high specificity. AMSA therefore serves to minimize interruptions of precordial compression and the myocardial damage caused by delivery of repetitive and ineffective electrical shocks.

  4. Information Fusion via the Wasserstein Barycenter in the Space of Probability Measures: Direct Fusion of Empirical Measures and Gaussian Fusion with Unknown Correlation

    DTIC Science & Technology

    2014-07-14

    metric captures the error in the expected value of a class of functions due to the approximation of one measure by another [22]. Thus, the fusion...result can be viewed as a measure with an expected value (for a class of function) that is minimally different (simultaneously) from the same expectation...Information Fusion via the Wasserstein Barycenter in the Space of Probability Measures : Direct Fusion of Empirical Measures and Gaussian Fusion with

  5. Measuring Redshifts of Emission-line Galaxies Using Ramp Filters

    NASA Astrophysics Data System (ADS)

    Lesser, Ryan William; Bohman, John; McNeff, Mathew; Holden, Marcus; Moody, Joseph; Joner, Michael D.; Barnes, Jonathan

    2016-01-01

    Photometric redshifts are routinely obtained for galaxies without emission using broadband photometry. It is possible in theory to derive reasonably accurate (< 200 km/sec) photometric redshift values for emission-line objects using "ramp" filters with a linearly increasing/decreasing transmission through the bandpass. To test this idea we have obtained a set of filters tuned for isolating H-alpha at a redshift range of 0-10,000 km/sec. These filters consist of two that vary close to linearly in transmission, have opposite slope, and cover the wavelength range from 655nm - 685nm, plus a Stromgren y and 697nm filter to measure the continuum. Redshifts are derived from the ratio of the ramp filters indices after the continuum has been subtracted out. We are finishing the process of obtaining photometric data on a set of about 100 galaxies with known redshift to calibrate the technique and will report on our results.

  6. The 'Geographic Emission Benchmark' model: a baseline approach to measuring emissions associated with deforestation and degradation.

    PubMed

    Kim, Oh Seok; Newell, Joshua P

    2015-10-01

    This paper proposes a new land-change model, the Geographic Emission Benchmark (GEB), as an approach to quantify land-cover changes associated with deforestation and forest degradation. The GEB is designed to determine 'baseline' activity data for reference levels. Unlike other models that forecast business-as-usual future deforestation, the GEB internally (1) characterizes 'forest' and 'deforestation' with minimal processing and ground-truthing and (2) identifies 'deforestation hotspots' using open-source spatial methods to estimate regional rates of deforestation. The GEB also characterizes forest degradation and identifies leakage belts. This paper compares the accuracy of GEB with GEOMOD, a popular land-change model used in the UN-REDD (Reducing Emissions from Deforestation and Forest Degradation) Program. Using a case study of the Chinese tropics for comparison, GEB's projection is more accurate than GEOMOD's, as measured by Figure of Merit. Thus, the GEB produces baseline activity data that are moderately accurate for the setting of reference levels.

  7. X-ray emission from MSH 14-63 - Probable remnant of the A.D. 185 supernova

    NASA Technical Reports Server (NTRS)

    Winkler, P. F., Jr.

    1978-01-01

    Observations during 1972 from an experiment on OSO 7 detected a 2-10-keV X-ray flux of 1.7 by 10 to the -10th power erg/sq cm per sec from a source coincident with MSH 14-63, the most probable candidate for association with the A.D. 185 supernova. Both the present data and those of Naranan et al. (1977) at lower energy can be fitted by a dual-temperature thermal spectrum similar to that observed in other young supernova remnants. Model calculations indicate that a mass in excess of 5 solar masses must have been ejected in the A.D. 185 supernova event.

  8. Polychromatic emission from polar-plane-free faceted InGaN quantum wells with high radiative recombination probabilities

    NASA Astrophysics Data System (ADS)

    Matsuda, Yoshinobu; Funato, Mitsuru; Kawakami, Yoichi

    2017-07-01

    We fabricated three-dimensional (3D) InGaN quantum wells (QWs) on \\{ 11\\bar{2}2\\} semipolar GaN substrates by selective area epitaxy. It was found that polar-plane-free 3D structures can be fabricated with a particular mask pattern on the (\\bar{1}\\bar{1}2\\bar{2}) plane and that InGaN/GaN QWs on these structures exhibit facet-dependent polychromatic emission properties. In addition, time-resolved photoluminescence spectroscopy indicated that the radiative recombination lifetimes of the obtained 3D QWs without the polar (0001) plane are much shorter than those of conventional 3D QWs with the (0001) plane, particularly at long wavelengths.

  9. Instrument for benzene and toluene emission measurements of glycol regenerators

    NASA Astrophysics Data System (ADS)

    Hanyecz, Veronika; Mohácsi, Árpád; Puskás, Sándor; Vágó, Árpád; Szabó, Gábor

    2013-11-01

    We introduce an in-field and in-explosive atmosphere useable instrument, which can measure the benzene and toluene concentration in two gas and two glycol samples produced by natural gas dehydration units. It is a two-phase, on-line gas chromatograph with a photoacoustic spectroscopy based detector. The time resolution is 10 min per cycle and the minimum detectable concentrations are 2 mg m-3 for benzene, 3 mg m-3 for toluene in natural gas, and 5 g m-3 for benzene and 6 g m-3 for toluene in glycol. Test measurements were carried out at a dehydration plant belonging to MOL Hungarian Oil and Gas Company. Benzene and toluene emissions of gas dehydration unit are calculated from the measured values based on mass balance of a glycol regenerator. The relationship between the outdoor temperature and the measured concentration was observed which is caused by temperature-dependent operation of the whole dehydration unit. Emission decreases with increase of outdoor temperature.

  10. A Michelson Interferometer for Electron Cyclotron Emission Measurements on EAST

    NASA Astrophysics Data System (ADS)

    Liu, Yong; Stefan, Schmuck; Zhao, Hailin; John, Fessey; Paul, Trimble; Liu, Xiang; Zhu, Zeying; Zang, Qing; Hu, Liqun

    2016-12-01

    A Michelson interferometer, on loan from EFDA-JET (Culham, United Kingdom) has recently been commissioned on the experimental advanced superconducting tokamak (EAST, ASIPP, Hefei, China). Following a successful in-situ absolute calibration the instrument is able to measure the electron cyclotron emission (ECE) spectrum, from 80 GHz to 350 GHz in extraordinary mode (X-mode) polarization, with high accuracy. This allows the independent determination of the electron temperature profile from observation of the second harmonic ECE and the possible identification of non-Maxwellian features by comparing higher harmonic emission with numerical simulations. The in-situ calibration results are presented together with the initial measured temperature profiles. These measurements are then discussed and compared with other independent temperature profile measurements. This paper also describes the main hardware features of the diagnostic and the associated commissioning test results. supported by National Natural Science Foundation of China (Nos. 11405211, 11275233), and the National Magnetic Confinement Fusion Science Program of China (Nos. 2013GB106002, 2015GB101000), and the RCUK Energy Programme (No. EP/I501045), partly supported by the JSPS-NRF-NSFC A3 Foresight Program in the Field of Plasma Physics (NSFC: No. 11261140328)

  11. Compensating for ear-canal acoustics when measuring otoacoustic emissions.

    PubMed

    Charaziak, Karolina K; Shera, Christopher A

    2017-01-01

    Otoacoustic emissions (OAEs) provide an acoustic fingerprint of the inner ear, and changes in this fingerprint may indicate changes in cochlear function arising from efferent modulation, aging, noise trauma, and/or exposure to harmful agents. However, the reproducibility and diagnostic power of OAE measurements is compromised by the variable acoustics of the ear canal, in particular, by multiple reflections and the emergence of standing waves at relevant frequencies. Even when stimulus levels are controlled using methods that circumvent standing-wave problems (e.g., forward-pressure-level calibration), distortion-product otoacoustic emission (DPOAE) levels vary with probe location by 10-15 dB near half-wave resonant frequencies. The method presented here estimates the initial outgoing OAE pressure wave at the eardrum from measurements of the conventional OAE, allowing one to separate the emitted OAE from the many reflections trapped in the ear canal. The emitted pressure level (EPL) represents the OAE level that would be recorded were the ear canal replaced by an infinite tube with no reflections. When DPOAEs are expressed using EPL, their variation with probe location decreases to the test-retest repeatability of measurements obtained at similar probe positions. EPL provides a powerful way to reduce the variability of OAE measurements and improve their ability to detect cochlear changes.

  12. Measurement of methane emission from a landfill with flux chamber

    SciTech Connect

    Liao, W.P.; Chou, F.S.

    1998-12-31

    Two types of flux chamber have been employed to measure the emission rate of the greenhouse gases from a landfill. For realizing the dynamic fluid characteristics of the flux chamber, this study performed the airtight and tracer-retention-time tests in the lab, besides field experiment. The results of air-tightness test show that the chamber pressure varied with both fan speed and temperature. The fan speed at 200 rpm caused no significant pressure difference at constant room temperature. A burial depth between 3 and 6 cm will provide adequate air-tightness in the field. It is recommended that the effects of temperature, fan speed, and burial depth need to be studied before measuring. The retention time distribution (RTD) curves shows that the flux chamber designed for this research can be regarded as a completely mixing chamber. The tracer recovery rate was around 81--84% with carrier gas at 6 to 18 l/min and fan speed at 200 rpm. Preliminary results of the field measurement indicate that the emission rates of methane vary in location with four peaks on the side slopes. Most of the methane (87 percent) is emitting from the side slopes. The measured amount is much less than the theoretical estimate for this landfill.

  13. Neutron-emission measurements at a white neutron source

    SciTech Connect

    Haight, Robert C

    2010-01-01

    Data on the spectrum of neutrons emittcd from neutron-induced reactions are important in basic nuclear physics and in applications. Our program studies neutron emission from inelastic scattering as well as fission neutron spectra. A ''white'' neutron source (continuous in energy) allows measurements over a wide range of neutron energies all in one experiment. We use the tast neutron source at the Los Alamos Neutron Science Center for incident neutron energies from 0.5 MeV to 200 MeV These experiments are based on double time-of-flight techniques to determine the energies of the incident and emitted neutrons. For the fission neutron measurements, parallel-plate ionization or avalanche detectors identify fission in actinide samples and give the required fast timing pulse. For inelastic scattering, gamma-ray detectors provide the timing and energy spectroscopy. A large neutron-detector array detects the emitted neutrons. Time-of-flight techniques are used to measure the energies of both the incident and emitted neutrons. Design considerations for the array include neutron-gamma discrimination, neutron energy resolution, angular coverage, segmentation, detector efficiency calibration and data acquisition. We have made preliminary measurements of the fission neutron spectra from {sup 235}U, {sup 238}U, {sup 237}Np and {sup 239}Pu. Neutron emission spectra from inelastic scattering on iron and nickel have also been investigated. The results obtained will be compared with evaluated data.

  14. Lexicographic Probability, Conditional Probability, and Nonstandard Probability

    DTIC Science & Technology

    2009-11-11

    the following conditions: CP1. µ(U |U) = 1 if U ∈ F ′. CP2 . µ(V1 ∪ V2 |U) = µ(V1 |U) + µ(V2 |U) if V1 ∩ V2 = ∅, U ∈ F ′, and V1, V2 ∈ F . CP3. µ(V |U...µ(V |X)× µ(X |U) if V ⊆ X ⊆ U , U,X ∈ F ′, V ∈ F . Note that it follows from CP1 and CP2 that µ(· |U) is a probability measure on (W,F) (and, in... CP2 hold. This is easily seen to determine µ. Moreover, µ vaciously satisfies CP3, since there do not exist distinct sets U and X in F ′ such that U

  15. Implementation of Portable Emissions Measurement Systems (PEMS) for the Real-driving Emissions (RDE) Regulation in Europe.

    PubMed

    Giechaskiel, Barouch; Vlachos, Theodoros; Riccobono, Francesco; Forni, Fausto; Colombo, Rinaldo; Montigny, Francois; Le-Lijour, Philippe; Carriero, Massimo; Bonnel, Pierre; Weiss, Martin

    2016-12-04

    Vehicles are tested in controlled and relatively narrow laboratory conditions to determine their official emission values and reference fuel consumption. However, on the road, ambient and driving conditions can vary over a wide range, sometimes causing emissions to be higher than those measured in the laboratory. For this reason, the European Commission has developed a complementary Real-Driving Emissions (RDE) test procedure using the Portable Emissions Measurement Systems (PEMS) to verify gaseous pollutant and particle number emissions during a wide range of normal operating conditions on the road. This paper presents the newly-adopted RDE test procedure, differentiating six steps: 1) vehicle selection, 2) vehicle preparation, 3) trip design, 4) trip execution, 5) trip verification, and 6) calculation of emissions. Of these steps, vehicle preparation and trip execution are described in greater detail. Examples of trip verification and the calculations of emissions are given.

  16. Implementation of Portable Emissions Measurement Systems (PEMS) for the Real-driving Emissions (RDE) Regulation in Europe

    PubMed Central

    Giechaskiel, Barouch; Vlachos, Theodoros; Riccobono, Francesco; Forni, Fausto; Colombo, Rinaldo; Montigny, Francois; Le-Lijour, Philippe; Carriero, Massimo; Bonnel, Pierre; Weiss, Martin

    2016-01-01

    Vehicles are tested in controlled and relatively narrow laboratory conditions to determine their official emission values and reference fuel consumption. However, on the road, ambient and driving conditions can vary over a wide range, sometimes causing emissions to be higher than those measured in the laboratory. For this reason, the European Commission has developed a complementary Real-Driving Emissions (RDE) test procedure using the Portable Emissions Measurement Systems (PEMS) to verify gaseous pollutant and particle number emissions during a wide range of normal operating conditions on the road. This paper presents the newly-adopted RDE test procedure, differentiating six steps: 1) vehicle selection, 2) vehicle preparation, 3) trip design, 4) trip execution, 5) trip verification, and 6) calculation of emissions. Of these steps, vehicle preparation and trip execution are described in greater detail. Examples of trip verification and the calculations of emissions are given. PMID:28060306

  17. On-road particle number measurements using a portable emission measurement system (PEMS)

    NASA Astrophysics Data System (ADS)

    Gallus, Jens; Kirchner, Ulf; Vogt, Rainer; Börensen, Christoph; Benter, Thorsten

    2016-01-01

    In this study the on-road particle number (PN) performance of a Euro-5 direct-injection (DI) gasoline passenger car was investigated. PN emissions were measured using the prototype of a portable emission measurement system (PEMS). PN PEMS correlations with chassis dynamometer tests show a good agreement with a chassis dynamometer set-up down to emissions in the range of 1·1010 #/km. Parallel on-line soot measurements by a photo acoustic soot sensor (PASS) were applied as independent measurement technique and indicate a good on-road performance for the PN-PEMS. PN-to-soot ratios were 1.3·1012 #/mg, which was comparable for both test cell and on-road measurements. During on-road trips different driving styles as well as different road types were investigated. Comparisons to the world harmonized light-duty test cycle (WLTC) 5.3 and to European field operational test (euroFOT) data indicate the PEMS trips to be representative for normal driving. Driving situations in varying traffic seem to be a major contributor to a high test-to-test variability of PN emissions. However, there is a trend to increasing PN emissions with more severe driving styles. A cold start effect is clearly visible for PN, especially at low ambient temperatures down to 8 °C.

  18. Contribution of correlated noise and selective decoding to choice probability measurements in extrastriate visual cortex

    PubMed Central

    Gu, Yong; Angelaki, Dora E; DeAngelis, Gregory C

    2014-01-01

    Trial by trial covariations between neural activity and perceptual decisions (quantified by choice Probability, CP) have been used to probe the contribution of sensory neurons to perceptual decisions. CPs are thought to be determined by both selective decoding of neural activity and by the structure of correlated noise among neurons, but the respective roles of these factors in creating CPs have been controversial. We used biologically-constrained simulations to explore this issue, taking advantage of a peculiar pattern of CPs exhibited by multisensory neurons in area MSTd that represent self-motion. Although models that relied on correlated noise or selective decoding could both account for the peculiar pattern of CPs, predictions of the selective decoding model were substantially more consistent with various features of the neural and behavioral data. While correlated noise is essential to observe CPs, our findings suggest that selective decoding of neuronal signals also plays important roles. DOI: http://dx.doi.org/10.7554/eLife.02670.001 PMID:24986734

  19. Atomic transition probabilities of Nd I

    NASA Astrophysics Data System (ADS)

    Stockett, M. H.; Wood, M. P.; Den Hartog, E. A.; Lawler, J. E.

    2011-12-01

    Fourier transform spectra are used to determine emission branching fractions for 236 lines of the first spectrum of neodymium (Nd i). These branching fractions are converted to absolute atomic transition probabilities using radiative lifetimes from time-resolved laser-induced fluorescence measurements (Den Hartog et al 2011 J. Phys. B: At. Mol. Opt. Phys. 44 225001). The wavelength range of the data set is from 390 to 950 nm. These transition probabilities from emission and laser measurements are compared to relative absorption measurements in order to assess the importance of unobserved infrared branches from selected upper levels.

  20. CONSTRAINING SOLAR FLARE DIFFERENTIAL EMISSION MEASURES WITH EVE AND RHESSI

    SciTech Connect

    Caspi, Amir; McTiernan, James M.; Warren, Harry P.

    2014-06-20

    Deriving a well-constrained differential emission measure (DEM) distribution for solar flares has historically been difficult, primarily because no single instrument is sensitive to the full range of coronal temperatures observed in flares, from ≲2 to ≳50 MK. We present a new technique, combining extreme ultraviolet (EUV) spectra from the EUV Variability Experiment (EVE) onboard the Solar Dynamics Observatory with X-ray spectra from the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI), to derive, for the first time, a self-consistent, well-constrained DEM for jointly observed solar flares. EVE is sensitive to ∼2-25 MK thermal plasma emission, and RHESSI to ≳10 MK; together, the two instruments cover the full range of flare coronal plasma temperatures. We have validated the new technique on artificial test data, and apply it to two X-class flares from solar cycle 24 to determine the flare DEM and its temporal evolution; the constraints on the thermal emission derived from the EVE data also constrain the low energy cutoff of the non-thermal electrons, a crucial parameter for flare energetics. The DEM analysis can also be used to predict the soft X-ray flux in the poorly observed ∼0.4-5 nm range, with important applications for geospace science.

  1. Constraining Solar Flare Differential Emission Measures with EVE and RHESSI

    NASA Astrophysics Data System (ADS)

    Caspi, Amir; McTiernan, James M.; Warren, Harry P.

    2014-06-01

    Deriving a well-constrained differential emission measure (DEM) distribution for solar flares has historically been difficult, primarily because no single instrument is sensitive to the full range of coronal temperatures observed in flares, from lsim2 to gsim50 MK. We present a new technique, combining extreme ultraviolet (EUV) spectra from the EUV Variability Experiment (EVE) onboard the Solar Dynamics Observatory with X-ray spectra from the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI), to derive, for the first time, a self-consistent, well-constrained DEM for jointly observed solar flares. EVE is sensitive to ~2-25 MK thermal plasma emission, and RHESSI to gsim10 MK together, the two instruments cover the full range of flare coronal plasma temperatures. We have validated the new technique on artificial test data, and apply it to two X-class flares from solar cycle 24 to determine the flare DEM and its temporal evolution; the constraints on the thermal emission derived from the EVE data also constrain the low energy cutoff of the non-thermal electrons, a crucial parameter for flare energetics. The DEM analysis can also be used to predict the soft X-ray flux in the poorly observed ~0.4-5 nm range, with important applications for geospace science.

  2. THE COLD SHOULDER: EMISSION MEASURE DISTRIBUTIONS OF ACTIVE REGION CORES

    SciTech Connect

    Schmelz, J. T.; Pathak, S.

    2012-09-10

    The coronal heating mechanism for active region core loops is difficult to determine because these loops are often not resolved and cannot be studied individually. Rather, we concentrate on the 'inter-moss' areas between loop footpoints. We use observations from the Hinode EUV Imaging Spectrometer and the X-Ray Telescope to calculate the emission measure distributions of eight inter-moss areas in five different active regions. The combined data sets provide both high- and low-temperature constraints and ensure complete coverage in the temperature range appropriate for active regions. For AR 11113, the emission can be modeled with heating events that occur on timescales less than the cooling time. The loops in the core regions appear to be close to equilibrium and are consistent with steady heating. The other regions studied, however, appear to be dominated by nanoflare heating. Our results are consistent with the idea that active region age is an important parameter in determining whether steady or nanoflare heating is primarily responsible for the core emission, that is, older regions are more likely to be dominated by steady heating, while younger regions show more evidence of nanoflares.

  3. Objective Measure of Nasal Air Emission Using Nasal Accelerometry.

    PubMed

    Cler, Meredith J; Lien, Yu-An S; Braden, Maia N; Mittelman, Talia; Downing, Kerri; Stepp, Cara E

    2016-10-01

    This article describes the development and initial validation of an objective measure of nasal air emission (NAE) using nasal accelerometry. Nasal acceleration and nasal airflow signals were simultaneously recorded while an expert speech language pathologist modeled NAEs at a variety of severity levels. In addition, microphone and nasal accelerometer signals were collected during the production of /pɑpɑpɑpɑ/ speech utterances by 25 children with and without cleft palate. Fourteen inexperienced raters listened to the microphone signals from the pediatric speakers and rated the samples for the severity of NAE using direct magnitude estimation. Mean listener ratings were compared to a novel quantitative measurement of NAE derived from the nasal acceleration signals. Correlation between the nasal acceleration energy measure and the measured nasal airflow was high (r = .87). Correlation between the measure and auditory-perceptual ratings was moderate (r = .49). The measure presented here is quantitative and noninvasive, and the required hardware is inexpensive ($150). Future studies will include speakers with a wider range of NAE severity and etiology, including cleft palate, hearing impairment, or dysarthria. Further development will also involve validation of the measure against airflow measures across subjects.

  4. Objective Measure of Nasal Air Emission Using Nasal Accelerometry

    PubMed Central

    Cler, Meredith J.; Lien, Yu-An S.; Braden, Maia N.; Mittelman, Talia; Downing, Kerri

    2016-01-01

    Purpose This article describes the development and initial validation of an objective measure of nasal air emission (NAE) using nasal accelerometry. Method Nasal acceleration and nasal airflow signals were simultaneously recorded while an expert speech language pathologist modeled NAEs at a variety of severity levels. In addition, microphone and nasal accelerometer signals were collected during the production of /pɑpɑpɑpɑ/ speech utterances by 25 children with and without cleft palate. Fourteen inexperienced raters listened to the microphone signals from the pediatric speakers and rated the samples for the severity of NAE using direct magnitude estimation. Mean listener ratings were compared to a novel quantitative measurement of NAE derived from the nasal acceleration signals. Results Correlation between the nasal acceleration energy measure and the measured nasal airflow was high (r = .87). Correlation between the measure and auditory-perceptual ratings was moderate (r = .49). Conclusion The measure presented here is quantitative and noninvasive, and the required hardware is inexpensive ($150). Future studies will include speakers with a wider range of NAE severity and etiology, including cleft palate, hearing impairment, or dysarthria. Further development will also involve validation of the measure against airflow measures across subjects. PMID:27618145

  5. Nighttime reactive nitrogen measurements from stratospheric infrared thermal emission observations

    NASA Technical Reports Server (NTRS)

    Abbas, Mian M.; Kunde, Virgil G.; Brasunas, J. C.; Herman, J. R.; Massie, Steven T.

    1991-01-01

    IR thermal emission spectra of the earth's atmosphere in the 700-2000/cm region were obtained with a cryogenically cooled high-resolution interferometer spectrometer on a balloon flight from Palestine, Texas, on September 15-16, 1986. The observations exhibit spectral features of a number of stratospheric constituents, including important species of the reactive nitrogen family. An analysis of the observed data for simultaneously measured vertical distributions of O3, H2O, N2O, NO2, N2O5, HNO3, and ClONO2 is presented. These measurements permit the first direct determination of the nighttime total reactive nitrogen concentrations, and the partitioning of the important elements of the NO(x) family. Comparisons of the total reactive nitrogen budget are made with the measurements by the ATMOS experiment and with the predictions of one-dimensional and two-dimensional photochemical models.

  6. Measuring Coronal Magnetic Fields with Coronal Emission Line Polarimetry

    NASA Astrophysics Data System (ADS)

    Lin, H.

    2003-12-01

    Magnetic field is the dominating field in the solar corona, responsible for the majestic coronal structures and dynamic events. However, no direct measurements of the coronal magnetic fields are routinely available and we can only infer the coronal magnetic field structures from observed intensity images. Although several methods for the diagnostics of coronal magnetic fields have been demonstrated, measurement of the coronal magnetic fields remains a very challenging observational task. This paper reports on a concerted effort at the Institute for Astronomy (IfA) to establish routine vector coronal magnetic field measurement capabilities using spectropolarimetric observation of the near infrared Fe XIII 1074.7 nm coronal emission line. The IfA effort includes observations of two-dimensional circular polarization maps of the emission line which carry information about the coronal magnetic field strength. High resolution observation of the linear polarization maps which yield the projected direction of the coronal magnetic field in the plane of the sky will also be obtained. The latest results from these experiments will be presented.

  7. Application of ultra-weak photon emission measurements in agriculture.

    PubMed

    Kato, Kimihiko; Iyozumi, Hiroyuki; Kageyama, Chizuko; Inagaki, Hidehiro; Yamaguchi, Akira; Nukui, Hideki

    2014-10-05

    Here we report our two applications of ultra-weak photon emission (UPE) measurements in agriculture. One is to find new types of agrochemicals that potentiate plants' defense, so-called "plant activator". We first analyzed the relation between plant defense and Elicitor-Responsive Photon Emission (ERPE) using a combination of rice cells and a chitin elicitor. Pharmacological analyses clarified that ERPE was generated as a part of the chitin elicitor-responsive defense in close relation with the generation of reactive oxygen species (ROS). Then we successfully detected the activity of plant activators as the potentiation of ERPE, and developed a new screening system for plant activators based on this principle. Another UPE application is to distinguish herbicide-resistant weeds from susceptible ones by measuring UPE in weeds. In our study, it was revealed that the weed biotypes resistant to sulfonylurea (SU) herbicides, one of the major herbicide groups, showed stronger UPE than susceptible ones after an SU herbicide treatment. By further analysis with a pharmacological and RNAi study, we found that the detoxifying enzyme P450s contributed to the UPE increase in SU herbicide resistant weeds. It is considered that weeds resistant to herbicides other than SU might also be able to be distinguished from susceptible ones by UPE measurement, as long as the herbicides are subject to detoxification by P450s.

  8. Measurement of total hemispherical emissivity of contaminated mirror surfaces

    NASA Technical Reports Server (NTRS)

    Facey, T. A.; Nonnenmacher, A. L.

    1989-01-01

    The effects of dust contamination on the total hemispherical emissivity (THE) of a 1.5-inch-diameter Al/MgF2-coated telescope mirror are investigated experimentally. The THE is determined by means of cooling-rate measurements in the temperature range 10-14.5 C in a vacuum of 100 ntorr or better. Photographs and drawings of the experimental setup are provided, and results for 11 dust levels are presented in tables and graphs. It is shown that dust has a significant effect on THE, but the experimental losses are only about half those predicted for perfectly black dust in perfect thermal contact with the mirror surface.

  9. Emission Measure Distribution and Heating of Two Active Region Cores

    NASA Technical Reports Server (NTRS)

    Tripathi, Durgesh; Klimchuk, James A.; Mason, Helen E.

    2011-01-01

    Using data from the Extreme-ultraviolet Imaging Spectrometer aboard Hinode, we have studied the coronal plasma in the core of two active regions. Concentrating on the area between opposite polarity moss, we found emission measure distributions having an approximate power-law form EM/T(exp 2.4) from log T = 5.55 up to a peak at log T = 6.57. The observations are explained extremely well by a simple nanoflare model. However, in the absence of additional constraints, the observations could possibly also be explained by steady heating.

  10. The longwave emission signature of urban pollution: Radiometric FTIR measurement

    NASA Astrophysics Data System (ADS)

    Lubin, Dan; Simpson, A. Sabrina

    1994-01-01

    Air pollutants trapped beneath frequent temperature inversions in the Los Angeles basin bring about surface radiance enhancements of up to fifty percent in the middle-infrared window (8-12 microns). This constitutes an anthropogenic modification to the downwelling longwave flux which can be as large as 9 W/m². A Fourier Transform Infrared (FTIR) spectroradiometer has been used to measure middle-infrared atmospheric emission spectra under Los Angeles smog, and these 1 cm-1 resolution spectra demonstrate that both anthropogenic aerosols and increased tropospheric ozone abundance contribute to enhancements in surface longwave radiation.

  11. The longwave emission signature of urban pollution: Radiometric FTIR measurement

    SciTech Connect

    Lubin, D. Simpson, A.S.

    1994-01-01

    Air pollutants trapped beneath frequent temperature inversions in the Los Angeles basin bring about surface radiance enhancements of up to fifty percent in the middle-infrared window (8 - 12 microns). This constitutes an anthrogenic modification to the downwelling longwave flux which can be as large as 9 W/sq m. A Fourier Transform Infrared (FTIR) spectroradiometer has been used to measure middle-infrared atmospheric emission spectra under Los Angeles smog, and these 1/cm resolution spectra demonstrate that both anthropogenic aerosols and increased tropospheric ozone abundance contribute to enhancements in surface longwave radiation.

  12. A Comprehensive Program for Measurement of Military Aircraft Emissions

    SciTech Connect

    Cheng, Mengdawn

    2009-11-01

    Emissions of gases and particulate matter by military aircraft were characterized inplume by 'extractive' and 'optical remote-sensing (ORS)' technologies. Non-volatile particle size distribution, number and mass concentrations were measured with good precision and reproducibly. Time-integrated particulate filter samples were collected and analyzed for smoke number, elemental composition, carbon contents, and sulfate. Observed at EEP the geometric mean diameter (as measured by the mobility diameter) generally increased as the engine power setting increased, which is consistent with downstream observations. The modal diameters at the downstream locations are larger than that at EEP at the same engine power level. The results indicate that engine particles were processed by condensation, for example, leading to particle growth in-plume. Elemental analysis indicated little metals were present in the exhaust, while most of the exhaust materials in the particulate phase were carbon and sulfate (in the JP-8 fuel). CO, CO{sub 2}, NO, NO{sub 2}, SO{sub 2}, HCHO, ethylene, acetylene, propylene, and alkanes were measured. The last five species were most noticeable under engine idle condition. The levels of hydrocarbons emitted at high engine power level were generally below the detection limits. ORS techniques yielded real-time gaseous measurement, but the same techniques could not be extended directly to ultrafine particles found in all engine exhausts. The results validated sampling methodology and measurement techniques used for non-volatile particulate aircraft emissions, which also highlighted the needs for further research on sampling and measurement for volatile particulate matter and semi-volatile species in the engine exhaust especially at the low engine power setting.

  13. Measuring chemical emissions from wet products--development of a new measurement technique.

    PubMed

    Wang, Rong; Zhu, Jiping; Rastan, Soheil; Haghighat, Fariborz

    2011-09-15

    A new approach for estimating chemical emissions from wet products has been developed. The concept of such approach is that emission rates can be estimated from the amount of target chemicals in the product as a function of evaporation time. Samples were placed under a laboratory fume hood under controlled conditions (surface air velocity and temperature). Weight losses of the product were monitored and residuals at different time intervals were chemically analyzed. Emission factors of the target chemicals were then calculated based on the weight losses and residual levels of the chemicals. To demonstrate the applicability of this approach, two wet products with very different physical characteristics, one liquid and one paste-like viscous fluid, were chosen. Emissions of two principle chemicals in the products, decamethylcyclopentasiloxane (D5), and dodecamethylcyclohexasiloxane (D6) were measured. The influences of initial sample weight, surface air velocity, and temperature were investigated. The calculated emission profiles were compared with those obtained from the chamber method. The described approach could be used as an alternative screening method for emission tests of wet products, especially for compounds with low vapour pressure when sink effect poses serious challenge in traditional chamber-based emission tests.

  14. Measurements of methane emissions from natural gas gathering facilities and processing plants: measurement methods

    NASA Astrophysics Data System (ADS)

    Roscioli, J. R.; Yacovitch, T. I.; Floerchinger, C.; Mitchell, A. L.; Tkacik, D. S.; Subramanian, R.; Martinez, D. M.; Vaughn, T. L.; Williams, L.; Zimmerle, D.; Robinson, A. L.; Herndon, S. C.; Marchese, A. J.

    2015-05-01

    Increased natural gas production in recent years has spurred intense interest in methane (CH4) emissions associated with its production, gathering, processing, transmission, and distribution. Gathering and processing facilities (G&P facilities) are unique in that the wide range of gas sources (shale, coal-bed, tight gas, conventional, etc.) results in a wide range of gas compositions, which in turn requires an array of technologies to prepare the gas for pipeline transmission and distribution. We present an overview and detailed description of the measurement method and analysis approach used during a 20-week field campaign studying CH4 emissions from the natural gas G&P facilities between October 2013 and April 2014. Dual-tracer flux measurements and on-site observations were used to address the magnitude and origins of CH4 emissions from these facilities. The use of a second tracer as an internal standard revealed plume-specific uncertainties in the measured emission rates of 20-47%, depending upon plume classification. Combining downwind methane, ethane (C2H6), carbon monoxide (CO), carbon dioxide (CO2), and tracer gas measurements with on-site tracer gas release allows for quantification of facility emissions and in some cases a more detailed picture of source locations.

  15. Measurements of methane emissions from natural gas gathering facilities and processing plants: measurement methods

    NASA Astrophysics Data System (ADS)

    Roscioli, J. R.; Yacovitch, T. I.; Floerchinger, C.; Mitchell, A. L.; Tkacik, D. S.; Subramanian, R.; Martinez, D. M.; Vaughn, T. L.; Williams, L.; Zimmerle, D.; Robinson, A. L.; Herndon, S. C.; Marchese, A. J.

    2014-12-01

    Increased natural gas production in recent years has spurred intense interest in methane (CH4) emissions associated with its production, gathering, processing, transmission and distribution. Gathering and processing facilities (G&P facilities) are unique in that the wide range of gas sources (shale, coal-bed, tight gas, conventional, etc.) results in a wide range of gas compositions, which in turn requires an array of technologies to prepare the gas for pipeline transmission and distribution. We present an overview and detailed description of the measurement method and analysis approach used during a 20-week field campaign studying CH4 emissions from the natural gas G&P facilities between October 2013 and April 2014. Dual tracer flux measurements and onsite observations were used to address the magnitude and origins of CH4 emissions from these facilities. The use of a second tracer as an internal standard revealed plume-specific uncertainties in the measured emission rates of 20-47%, depending upon plume classification. Combining downwind methane, ethane (C2H6), carbon monoxide (CO), carbon dioxide (CO2), and tracer gas measurements with onsite tracer gas release allows for quantification of facility emissions, and in some cases a more detailed picture of source locations.

  16. The lifetime probability tag measurement of R{sub b} using the SLD

    SciTech Connect

    SLD Collaboration

    1995-08-01

    The authors present a new measurement of R{sub b} = {Lambda}{sub Z{degree}{yields}b{anti b}}/{Lambda}{sub Z{degree}{yields}hadrons} using a lifetime double tag on 150k hadronic Z{degree} events collected from the SLD 1993 and 1994 runs. The method utilizes the high precision 3-D position measurements provided by the CCD vertex detector and the small stable SLC beams to obtain a b hemisphere tagging efficiency of 31% for a purity of 94%. The b-Hemisphere tagging efficiency is measured from the data reducing dependence on the B-decay model and detector simulation. They obtain a result of R{sub b} = 0.2171 {+-} 0.0040{sub statistical} {+-} 0.0037{sub systematic} {+-} 0.0023{sub R{sub c}}.

  17. Measurement of amplified spontaneous emission at 200 A (invited; abstract)

    NASA Astrophysics Data System (ADS)

    Ceglio, N. M.

    1985-05-01

    Recent interest in the production of laser radiation at soft x-ray wavelengths makes appropriate the discussion of diagnostic considerations and techniques for the measurement of same. A source of soft x-ray ASE has a number of characteristics which drive the design of diagnostic instruments: (1) The anisotropy of the ASE makes target alignment a critical part of the diagnosis, and couples collection solid angle to S/N considerations in the measurement. (2) The narrow linewidth of the amplified emission and its long wavelength put a high S/N premium on spectroscopic instrumentation of high spectral resolution and good higher-order discrimination. (3) The specialized plasma conditions required to produce gain are typically short lived, requiring time-resolved or at least time-discriminating spectroscopy. (4) The nonlinear nature of the threshold processes involved in ASE requires instrumentation of large dynamic range, broad angular acceptance, and large field of view and depth of focus. Of the many possible methods for gain verification of the x-ray source, five are discussed: (1) Probe amplification; (2) spatial coherence measurement (as a function of gain length); (3) output intensity measurement (absolute measurement and nonlinear variation with gain length); (4) divergence measurement; and (5) cavity formation. In addition, recent soft x-ray laser experiments at LLNL are discussed along with descriptions of the instruments used to measure the ASE. Diagnostic design suggestions for future soft x-ray laser experiments are also presented.

  18. Next Generation Emission Measurements for Fugitive, Area Source, and Fence Line Applications?

    EPA Science Inventory

    Next generation emissions measurements (NGEM) is an EPA term for the rapidly advancing field of air pollutant sensor technologies, data integration concepts, and associated geospatial modeling strategies for source emissions measurements. Ranging from low coat sensors to satelli...

  19. Next Generation Emission Measurements for Fugitive, Area Source, and Fence Line Applications?

    EPA Science Inventory

    Next generation emissions measurements (NGEM) is an EPA term for the rapidly advancing field of air pollutant sensor technologies, data integration concepts, and associated geospatial modeling strategies for source emissions measurements. Ranging from low coat sensors to satelli...

  20. Characteristics of On-road Diesel Vehicles: Black Carbon Emissions in Chinese Cities Based on Portable Emissions Measurement.

    PubMed

    Zheng, Xuan; Wu, Ye; Jiang, Jingkun; Zhang, Shaojun; Liu, Huan; Song, Shaojie; Li, Zhenhua; Fan, Xiaoxiao; Fu, Lixin; Hao, Jiming

    2015-11-17

    Black carbon (BC) emissions from heavy-duty diesel vehicles (HDDVs) are rarely continuously measured using portable emission measurement systems (PEMSs). In this study, we utilize a PEMS to obtain real-world BC emission profiles for 25 HDDVs in China. The average fuel-based BC emissions of HDDVs certified according to Euro II, III, IV, and V standards are 2224 ± 251, 612 ± 740, 453 ± 584, and 152 ± 3 mg kg(-1), respectively. Notably, HDDVs adopting mechanical pump engines had significantly higher BC emissions than those equipped with electronic injection engines. Applying the useful features of PEMSs, we can relate instantaneous BC emissions to driving conditions using an operating mode binning methodology, and the average emission rates for Euro II to Euro IV diesel trucks can be constructed. From a macroscopic perspective, we observe that average speed is a significant factor affecting BC emissions and is well correlated with distance-based emissions (R(2) = 0.71). Therefore, the average fuel-based and distance-based BC emissions on congested roads are 40 and 125% higher than those on freeways. These results should be taken into consideration in future emission inventory studies.

  1. A mechanical model for predicting the probability of osteoporotic hip fractures based in DXA measurements and finite element simulation

    PubMed Central

    2012-01-01

    Background Osteoporotic hip fractures represent major cause of disability, loss of quality of life and even mortality among the elderly population. Decisions on drug therapy are based on the assessment of risk factors for fracture, from BMD measurements. The combination of biomechanical models with clinical studies could better estimate bone strength and supporting the specialists in their decision. Methods A model to assess the probability of fracture, based on the Damage and Fracture Mechanics has been developed, evaluating the mechanical magnitudes involved in the fracture process from clinical BMD measurements. The model is intended for simulating the degenerative process in the skeleton, with the consequent lost of bone mass and hence the decrease of its mechanical resistance which enables the fracture due to different traumatisms. Clinical studies were chosen, both in non-treatment conditions and receiving drug therapy, and fitted to specific patients according their actual BMD measures. The predictive model is applied in a FE simulation of the proximal femur. The fracture zone would be determined according loading scenario (sideway fall, impact, accidental loads, etc.), using the mechanical properties of bone obtained from the evolutionary model corresponding to the considered time. Results BMD evolution in untreated patients and in those under different treatments was analyzed. Evolutionary curves of fracture probability were obtained from the evolution of mechanical damage. The evolutionary curve of the untreated group of patients presented a marked increase of the fracture probability, while the curves of patients under drug treatment showed variable decreased risks, depending on the therapy type. Conclusion The FE model allowed to obtain detailed maps of damage and fracture probability, identifying high-risk local zones at femoral neck and intertrochanteric and subtrochanteric areas, which are the typical locations of osteoporotic hip fractures. The

  2. WEAK CONVERGENCE OF PROBABILITY MEASURES ON PRODUCT SPACES WITH APPLICATIONS TO SUMS OF RANDOM VECTORS,

    DTIC Science & Technology

    product of k copies of D(0,1), the space of right continuous functions on (0,1) having left limits with the Skorohod metric. Necessary and...measure P. These results are then applied to obtain functional central limit theorems for sums of random vectors. The random vectors considered are

  3. Probable errors in width distributions of sea ice leads measured along a transect

    NASA Technical Reports Server (NTRS)

    Key, J.; Peckham, S.

    1991-01-01

    The degree of error expected in the measurement of widths of sea ice leads along a single transect are examined in a probabilistic sense under assumed orientation and width distributions, where both isotropic and anisotropic lead orientations are examined. Methods are developed for estimating the distribution of 'actual' widths (measured perpendicular to the local lead orientation) knowing the 'apparent' width distribution (measured along the transect), and vice versa. The distribution of errors, defined as the difference between the actual and apparent lead width, can be estimated from the two width distributions, and all moments of this distribution can be determined. The problem is illustrated with Landsat imagery and the procedure is applied to a submarine sonar transect. Results are determined for a range of geometries, and indicate the importance of orientation information if data sampled along a transect are to be used for the description of lead geometries. While the application here is to sea ice leads, the methodology can be applied to measurements of any linear feature.

  4. A Probability-Based Measure of Effect Size: Robustness to Base Rates and Other Factors

    ERIC Educational Resources Information Center

    Ruscio, John

    2008-01-01

    Calculating and reporting appropriate measures of effect size are becoming standard practice in psychological research. One of the most common scenarios encountered involves the comparison of 2 groups, which includes research designs that are experimental (e.g., random assignment to treatment vs. placebo conditions) and nonexperimental (e.g.,…

  5. Copula Models for Sociology: Measures of Dependence and Probabilities for Joint Distributions

    ERIC Educational Resources Information Center

    Vuolo, Mike

    2017-01-01

    Often in sociology, researchers are confronted with nonnormal variables whose joint distribution they wish to explore. Yet, assumptions of common measures of dependence can fail or estimating such dependence is computationally intensive. This article presents the copula method for modeling the joint distribution of two random variables, including…

  6. Methods of Temperature and Emission Measure Determination of Coronal Loops

    NASA Astrophysics Data System (ADS)

    Cirtain, J. W.; Schmelz, J. T.; Martens, P. C. H.

    2002-05-01

    Recent observational results from both SOHO-EIT and TRACE indicate that coronal loops are isothermal along their length (axially). These results are obtained from a narrowband filter ratio method that assumes that the plasma is isothermal along the line of sight (radially). However, these temperatures vary greatly from those derived from differential emission measure (DEM) curves produced from spectral lines recorded by SOHO-CDS. The DEM results indicate that the loops are neither axially nor radially isothermal. This discrepancy was investigated by Schmelz et al. (2001). They chose pairs of iron lines from the same CDS data set to mimic the EIT and TRACE loop results. Ratios of different lines gave different temperatures, indicating that the plasma was not radially isothermal. In addition the results indicated that the loop was axially isothermal, even though the DEM analysis of the same data showed this result to be false. Here we have analyzed the EIT data for the CDS loop published by Schmelz et al. (2001). We took the ratios of the 171-to-195 and 195-to-284 filter data, and made temperature maps of the loop. The results indicate that the loop is axially isothermal, but different temperatures were found for each pair of filters. Both ratio techniques force the resultant temperature to lie within the range where the response functions (for filters) or the emissivity functions (for lines) overlap; isothermal loops are therefore a byproduct of the analysis. This conclusion strengthens support for the idea that temperature and emission measure results from filter ratio methods may be misleading or even drastically wrong. This research was funded in part by the NASA/TRACE MODA grant for Montana State University. Solar physics research at the University of Memphis is supported by NASA grant NAG5-9783.

  7. Methane emissions from a beef cattle feedyard: measurements and models

    USDA-ARS?s Scientific Manuscript database

    Methane (CH4) emissions from enteric fermentation by livestock account for about 2% of U.S. greenhouse gas (GHG) emissions, with beef and dairy cattle the most significant sources. Most current approaches to estimate the contribution of cattle to GHG emissions use emission factors based on productio...

  8. Road salt emissions: A comparison of measurements and modelling using the NORTRIP road dust emission model

    NASA Astrophysics Data System (ADS)

    Denby, B. R.; Ketzel, M.; Ellermann, T.; Stojiljkovic, A.; Kupiainen, K.; Niemi, J. V.; Norman, M.; Johansson, C.; Gustafsson, M.; Blomqvist, G.; Janhäll, S.; Sundvor, I.

    2016-09-01

    De-icing of road surfaces is necessary in many countries during winter to improve vehicle traction. Large amounts of salt, most often sodium chloride, are applied every year. Most of this salt is removed through drainage or traffic spray processes but a certain amount may be suspended, after drying of the road surface, into the air and will contribute to the concentration of particulate matter. Though some measurements of salt concentrations are available near roads, the link between road maintenance salting activities and observed concentrations of salt in ambient air is yet to be quantified. In this study the NORTRIP road dust emission model, which estimates the emissions of both dust and salt from the road surface, is applied at five sites in four Nordic countries for ten separate winter periods where daily mean ambient air measurements of salt concentrations are available. The model is capable of reproducing many of the salt emission episodes, both in time and intensity, but also fails on other occasions. The observed mean concentration of salt in PM10, over all ten datasets, is 4.2 μg/m3 and the modelled mean is 2.8 μg/m3, giving a fractional bias of -0.38. The RMSE of the mean concentrations, over all 10 datasets, is 2.9 μg/m3 with an average R2 of 0.28. The mean concentration of salt is similar to the mean exhaust contribution during the winter periods of 2.6 μg/m3. The contribution of salt to the kerbside winter mean PM10 concentration is estimated to increase by 4.1 ± 3.4 μg/m3 for every kg/m2 of salt applied on the road surface during the winter season. Additional sensitivity studies showed that the accurate logging of salt applications is a prerequisite for predicting salt emissions, as well as good quality data on precipitation. It also highlights the need for more simultaneous measurements of salt loading together with ambient air concentrations to help improve model parameterisations of salt and moisture removal processes.

  9. Hidden lignin in soils: What's left behind is probably more important than what's measured

    NASA Astrophysics Data System (ADS)

    Hernes, P.; Kaiser, K.; Dyda, R. Y.; Cerli, C.

    2013-12-01

    The relative importance of lignin toward stabilized soil organic matter has been a subject of much debate, with early paradigms based on supposed recalcitrance replaced by more recent studies in surface soils that suggest turnover times similar to bulk organic matter. A primary tool in these studies has been alkaline CuO oxidation in which soils are subjected to high temperatures and 2N basic conditions, which is presumed to extract all lignin from mineral soils. However, we conducted an experiment using plant litter leachates sorbed to various minerals to demonstrate that even the hot alkaline conditions of CuO oxidation are insufficient to extract all lignin. This irreversible lignin (determined by difference) is almost certainly more stable than the measured lignin in previous turnover studies, and compositionally quite distinct from either the parent litter leachates or what can be measured on the sorbed systems. Further, our optical characterizations of the leachate (carbon-specific absorbance in the UV range as a proxy for aromaticity) indicate that lignin may be more broadly representative of aromatic compounds in general, if not all surface active compounds. This has clear implications for deep-soil organic carbon as sorption of dissolved organic matter leached from upper layers is a primary mechanism for building up and stabilizing deep-soil carbon stores, namely that lignin and other aromatics may become increasingly important toward soil organic matter stabilization with depth, even if we cannot directly measure them.

  10. Influence of sampling intake position on suspended solid measurements in sewers: two probability/time-series-based approaches.

    PubMed

    Sandoval, Santiago; Bertrand-Krajewski, Jean-Luc

    2016-06-01

    Total suspended solid (TSS) measurements in urban drainage systems are required for several reasons. Aiming to assess uncertainties in the mean TSS concentration due to the influence of sampling intake vertical position and vertical concentration gradients in a sewer pipe, two methods are proposed: a simplified method based on a theoretical vertical concentration profile (SM) and a time series grouping method (TSM). SM is based on flow rate and water depth time series. TSM requires additional TSS time series as input data. All time series are from the Chassieu urban catchment in Lyon, France (time series from 2007 with 2-min time step, 89 rainfall events). The probability of measuring a TSS value lower than the mean TSS along the vertical cross section (TSS underestimation) is about 0.88 with SM and about 0.64 with TSM. TSM shows more realistic TSS underestimation values (about 39 %) than SM (about 269 %). Interquartile ranges (IQR) over the probability values indicate that SM is more uncertain (IQR = 0.08) than TSM (IQR = 0.02). Differences between the two methods are mainly due to simplifications in SM (absence of TSS measurements). SM assumes a significant asymmetry of the TSS concentration profile along the vertical axis in the cross section. This is compatible with the distribution of TSS measurements found in the TSM approach. The methods provide insights towards an indicator of the measurement performance and representativeness for a TSS sampling protocol.

  11. Detection of Chamber Conditioning Through Optical Emission and Impedance Measurements

    NASA Technical Reports Server (NTRS)

    Cruden, Brett A.; Rao, M. V. V. S.; Sharma, Surendra P.; Meyyappan, Meyya

    2001-01-01

    During oxide etch processes, buildup of fluorocarbon residues on reactor sidewalls can cause run-to-run drift and will necessitate some time for conditioning and seasoning of the reactor. Though diagnostics can be applied to study and understand these phenomena, many of them are not practical for use in an industrial reactor. For instance, measurements of ion fluxes and energy by mass spectrometry show that the buildup of insulating fluorocarbon films on the reactor surface will cause a shift in both ion energy and current in an argon plasma. However, such a device cannot be easily integrated into a processing system. The shift in ion energy and flux will be accompanied by an increase in the capacitance of the plasma sheath. The shift in sheath capacitance can be easily measured by a common commercially available impedance probe placed on the inductive coil. A buildup of film on the chamber wall is expected to affect the production of fluorocarbon radicals, and thus the presence of such species in the optical emission spectrum of the plasma can be monitored as well. These two techniques are employed on a GEC (Gaseous Electronics Conference) Reference Cell to assess the validity of optical emission and impedance monitoring as a metric of chamber conditioning. These techniques are applied to experimental runs with CHF3 and CHF3/O2/Ar plasmas, with intermediate monitoring of pure argon plasmas as a reference case for chamber conditions.

  12. Detection of Chamber Conditioning Through Optical Emission and Impedance Measurements

    NASA Technical Reports Server (NTRS)

    Cruden, Brett A.; Rao, M. V. V. S.; Sharma, Surendra P.; Meyyappan, Meyya

    2001-01-01

    During oxide etch processes, buildup of fluorocarbon residues on reactor sidewalls can cause run-to-run drift and will necessitate some time for conditioning and seasoning of the reactor. Though diagnostics can be applied to study and understand these phenomena, many of them are not practical for use in an industrial reactor. For instance, measurements of ion fluxes and energy by mass spectrometry show that the buildup of insulating fluorocarbon films on the reactor surface will cause a shift in both ion energy and current in an argon plasma. However, such a device cannot be easily integrated into a processing system. The shift in ion energy and flux will be accompanied by an increase in the capacitance of the plasma sheath. The shift in sheath capacitance can be easily measured by a common commercially available impedance probe placed on the inductive coil. A buildup of film on the chamber wall is expected to affect the production of fluorocarbon radicals, and thus the presence of such species in the optical emission spectrum of the plasma can be monitored as well. These two techniques are employed on a GEC (Gaseous Electronics Conference) Reference Cell to assess the validity of optical emission and impedance monitoring as a metric of chamber conditioning. These techniques are applied to experimental runs with CHF3 and CHF3/O2/Ar plasmas, with intermediate monitoring of pure argon plasmas as a reference case for chamber conditions.

  13. Electron cyclotron emission measurements on the Texas Experimental Tokamak

    SciTech Connect

    Austin, M.E. Jr.

    1992-01-01

    A ten-channel grating polychromator was designed, constructed, and installed on the Texas Experimental Tokamak to monitor the second harmonic electron cyclotron emission. Electron temperature profiles were derived from measurements of the optically thick radiation for a variety of plasma confinement experiments. The radial and temporal evolution of T[sub e] has been characterized for electron cyclotron heated discharges with 150 kW of 60 GHz power. Comparisons were made of the heating efficiency of two type of ECH launchers. A focussed launcher was shown to have slightly better heating efficiency than an unfocussed launcher; however, the focussed antenna did not yield significantly higher electron temperatures as expected. A study of the time evolution of the electron temperature indicated that increased sawtooth activity limited the effectiveness of the focussed launcher. A focussing hog-horn antenna was fabricated and installed on the inboard side of the tokamak to measure emission directed towards the high-field side during ECH. Comparison of the radiation temperature profiles from low-field side and high-field side antennas indicates the creation of a nonthermal electron distribution by the heating. The results of the experiment compare favorably with theoretical predictions from a quasi-linear Fokker-Planck code of a 6 keV nonthermal population with a density about 1 percent of the thermal density.

  14. THE EMISSION MEASURE DISTRIBUTION OF IMPULSIVE PHASE FLARE FOOTPOINTS

    SciTech Connect

    Graham, D. R.; Hannah, I. G.; Fletcher, L.; Milligan, R. O.

    2013-04-10

    The temperature distribution of the emitting plasma is a crucial constraint when studying the heating of solar flare footpoints. However, determining this for impulsive phase footpoints has been difficult in the past due to insufficient spatial resolution to resolve the footpoints from the loop structures, and a lack of spectral and temporal coverage. We use the capabilities of Hinode/Extreme Ultraviolet Imaging Spectrometer to obtain the first emission measure distributions (EMDs) from impulsive phase footpoints in six flares. Observations with good spectral coverage were analyzed using a regularized inversion method to recover the EMDs. We find that the EMDs all share a peak temperature of around 8 MK, with lines formed around this temperature having emission measures (EMs) peaking between 10{sup 28} and 10{sup 29} cm{sup -5}, indicating a substantial presence of plasma at very high temperatures within the footpoints. An EMD gradient of EM(T) {approx} T is found in all events. Previous theoretical work on EM gradients shows this to be consistent with a scenario in which the deposited flare energy directly heats only the top layer of the flare chromosphere, while deeper layers are heated by conduction.

  15. Photoluminescence of charged CdSe/ZnS quantum dots in the gas phase: effects of charge and heating on absorption and emission probabilities.

    PubMed

    Howder, Collin R; Long, Bryan A; Bell, David M; Furakawa, Kevin H; Johnson, Ryan C; Fang, Zhiyuan; Anderson, Scott L

    2014-12-23

    Gas phase spectral measurements for CdSe/ZnS core/shell nanocrystal quantum dots (QDs) before and after heating with both infrared (CO2) and visible lasers are reported. As-trapped QDs are spectrally similar to the same QDs in solution; however their photoluminescence (PL) intensities are very low, at least partly due to low absorption cross sections. After heating, the PL intensities brighten by factors ranging from ∼4 to 1800 depending on the QD size and pump laser wavelength. The emission spectra no longer resemble solution spectra and are similar, regardless of the QD diameter. Emission extends from the pump laser wavelength into the near-IR, with strong emission features above the band gap energy, between 645 and 775 nm, and in the near-infrared. Emission spectra from brightened QD ensembles, single QD aggregates, and single QD monomers are similar, showing that even single QDs support PL from a wide variety of states. The heating and cooling processes for QDs in this environment are analyzed, providing limits on the magnitudes of the absorption cross sections before and after thermal brightening. A model, based on absorption bleaching by extra electrons in the conduction band, appears to account for the changes in absorption and emission behavior induced by charging and heating.

  16. Measurement of undisturbed di-nitrogen emissions from aquatic ecosystems

    NASA Astrophysics Data System (ADS)

    Qin, Shuping, Clough, Timothy, Lou, Jiafa; Hu, Chunsheng; Oenema, Oene; Wrage-Mönnig, Nicole; Zhang, Yuming

    2016-04-01

    Increased production of reactive nitrogen (Nr) from atmospheric di-nitrogen (N2) during the last century has greatly contributed to increased food production1-4. However, enriching the biosphere with Nr through N fertilizer production, combustion, and biological N2 fixation has also caused a series of negative effects on global ecosystems 5,6, especially aquatic ecosystems7. The main pathway converting Nr back into the atmospheric N2 pool is the last step of the denitrification process, i.e., the reduction of nitrous oxide (N2O) into N2 by micro-organisms7,8. Despite several attempts9,10, there is not yet an accurate, fast and direct method for measuring undisturbed N2 fluxes from denitrification in aquatic sediments at the field scale11-14. Such a method is essential to study the feedback of aquatic ecosystems to Nr inputs1,2,7. Here we show that the measurement of both N2O emission and its isotope signature can be used to infer the undisturbed N2 fluxes from aquatic ecosystems. The microbial reduction of N2O increases the natural abundance of 15N-N2O relative to 14N-N2O (δ15N-N2O). We observed linear relationships between δ15N-N2O and the logarithmic transformed N2O/(N2+N2O) emission ratios. Through independent measurements, we verified that the undisturbed N2 flux from aquatic ecosystems can be inferred from measurements of N2O emissions and the δ15N-N2O signature. Our method allows the determination of field-scale N2 fluxes from undisturbed aquatic ecosystems, and thereby allows model predictions of denitrification rates to be tested. The undisturbed N2 fluxes observed are almost one order of magnitude higher than those estimated by the traditional method, where perturbation of the system occurs, indicating that the ability of aquatic ecosystems to remove Nr may have been severely underestimated.

  17. Can the Quantum Measurement Problem be Resolved within the Framework of Schroedinger Dynamics and Quantum Probability?

    SciTech Connect

    Sewell, Geoffrey

    2007-12-03

    We provide an affirmative answer to the question posed in the title. Our argument is based on a treatment of the Schroedinger dynamics of the composite, S{sub c}, of a quantum microsystem, S, and a macroscopic measuring apparatus, J, consisting of N interacting particles. The pointer positions of this apparatus are represented by subspaces of its representative Hilbert space that are simultaneous eigenspaces of coarse-grained intercommuting macroscopic observables. By taking explicit account of their macroscopicality, we prove that, for suitably designed apparatus J, the evolution of the composite S{sub c} leads both to the reduction of the wave-packet of S and to a one-to-one correspondence between the resultant state of this microsystem and the pointer position of J, up to utterly neglible corrections that decrease exponentially with N.

  18. Spectral measurements of the atmospheric thermal infrared emission in Antarctica

    NASA Astrophysics Data System (ADS)

    Palchetti, L.; Bianchini, G.; Del Guasta, M.; Baglioni, A.

    2012-12-01

    A better understanding of radiative effects of water vapor and clouds could be achieved through better spectrally-resolved measurements of the atmospheric thermal emission, particularly in the far infrared (FIR) region below 650 cm-1. To explore this relatively unknown region, an experiment, named Radiative Properties of Water Vapor and Clouds in Antarctica (PRANA, "Proprieta' Radiative del vapore Acqueo e delle Nubi in Antartide"), is under way at Concordia station in Antarctica since December 2011. This experiment exploits the high altitude and extremely dry air conditions found on the Antarctic Plateau to extend the ground-based infrared sounding capabilities to the water vapor pure rotational band. The experiment includes a spectroradiometer for the spectral characterization of the downwelling longwave radiance in the 100-1400 cm-1 spectral region and a LIDAR to characterize a possible cloud coverage. Measurements will be carried on for two years, thus covering systematically different sky conditions. Moreover, routine integrated measurements of downwelling and upwelling shortwave and longwave radiation components (performed within the Baseline Surface Radiation Network - BSRN) and daily radiosoundings of water vapor and temperature vertical profiles are performed from the base, providing an independent knowledge of the state of the observed atmosphere. Detailed specifications of the complete set of instruments are shown along with a preliminary analysis of spectroscopic data. The analysis shows that a spectrally-resolved measurement has the capability to identify and to quantify the effect of the different atmospheric components on the radiation budget, and at the same time it shows that it is necessary to improve the spectroscopic characterization of the water vapor rotational band to be used in radiative transfer models in order to perform this task at best. The spectral signature of thin ice clouds is also identified in the measurements and characterized in

  19. First Compilation and Evaluation of Beta-Delayed Neutron Emission Probabilities and Associated Half-Lives for A ≤72 Nuclei

    SciTech Connect

    Birch, M.; Singh, B.; Abriola, D.; Dillmann, I.; Johnson, T.; McCutchan, E. A.; Sonzogni, A. A.

    2014-06-01

    After a comprehensive compilation and evaluation of beta-delayed neutron (β-n) emission probabilities, Pn, and associated half-lives for A ≤ 72 nuclei has been performed for the first time. The recommended values have been used to analyze the systematics of β-nemission in this region. The ratio Pn/T1/2 is better correlated with the Q-value of the β-n decay mode than the previously proposed Kratz-Herrmann Formula (KHF). Moreover, the recommended values are also compared with theoretical quasi-particle random phase approximation (QRPA) calculations.

  20. Global Land Surface Emissivity Retrieved From Satellite Ultraspectral IR Measurements

    NASA Technical Reports Server (NTRS)

    Zhou, D. K.; Larar, A. M.; Liu, Xu; Smith, W. L.; Strow, L. L.; Yang, Ping; Schlussel, P.; Calbet, X.

    2011-01-01

    Ultraspectral resolution infrared (IR) radiances obtained from nadir observations provide information about the atmosphere, surface, aerosols, and clouds. Surface spectral emissivity (SSE) and surface skin temperature from current and future operational satellites can and will reveal critical information about the Earth s ecosystem and land-surface-type properties, which might be utilized as a means of long-term monitoring of the Earth s environment and global climate change. In this study, fast radiative transfer models applied to the atmosphere under all weather conditions are used for atmospheric profile and surface or cloud parameter retrieval from ultraspectral and/or hyperspectral spaceborne IR soundings. An inversion scheme, dealing with cloudy as well as cloud-free radiances observed with ultraspectral IR sounders, has been developed to simultaneously retrieve atmospheric thermodynamic and surface or cloud microphysical parameters. This inversion scheme has been applied to the Infrared Atmospheric Sounding Interferometer (IASI). Rapidly produced SSE is initially evaluated through quality control checks on the retrievals of other impacted surface and atmospheric parameters. Initial validation of retrieved emissivity spectra is conducted with Namib and Kalahari desert laboratory measurements. Seasonal products of global land SSE and surface skin temperature retrieved with IASI are presented to demonstrate seasonal variation of SSE.

  1. Global Land Surface Emissivity Retrieved From Satellite Ultraspectral IR Measurements

    NASA Technical Reports Server (NTRS)

    Zhou, D. K.; Larar, A. M.; Liu, Xu; Smith, W. L.; Strow, L. L.; Yang, Ping; Schlussel, P.; Calbet, X.

    2011-01-01

    Ultraspectral resolution infrared (IR) radiances obtained from nadir observations provide information about the atmosphere, surface, aerosols, and clouds. Surface spectral emissivity (SSE) and surface skin temperature from current and future operational satellites can and will reveal critical information about the Earth s ecosystem and land-surface-type properties, which might be utilized as a means of long-term monitoring of the Earth s environment and global climate change. In this study, fast radiative transfer models applied to the atmosphere under all weather conditions are used for atmospheric profile and surface or cloud parameter retrieval from ultraspectral and/or hyperspectral spaceborne IR soundings. An inversion scheme, dealing with cloudy as well as cloud-free radiances observed with ultraspectral IR sounders, has been developed to simultaneously retrieve atmospheric thermodynamic and surface or cloud microphysical parameters. This inversion scheme has been applied to the Infrared Atmospheric Sounding Interferometer (IASI). Rapidly produced SSE is initially evaluated through quality control checks on the retrievals of other impacted surface and atmospheric parameters. Initial validation of retrieved emissivity spectra is conducted with Namib and Kalahari desert laboratory measurements. Seasonal products of global land SSE and surface skin temperature retrieved with IASI are presented to demonstrate seasonal variation of SSE.

  2. Linearized spectrum correlation analysis for line emission measurements

    NASA Astrophysics Data System (ADS)

    Nishizawa, T.; Nornberg, M. D.; Den Hartog, D. J.; Sarff, J. S.

    2017-08-01

    A new spectral analysis method, Linearized Spectrum Correlation Analysis (LSCA), for charge exchange and passive ion Doppler spectroscopy is introduced to provide a means of measuring fast spectral line shape changes associated with ion-scale micro-instabilities. This analysis method is designed to resolve the fluctuations in the emission line shape from a stationary ion-scale wave. The method linearizes the fluctuations around a time-averaged line shape (e.g., Gaussian) and subdivides the spectral output channels into two sets to reduce contributions from uncorrelated fluctuations without averaging over the fast time dynamics. In principle, small fluctuations in the parameters used for a line shape model can be measured by evaluating the cross spectrum between different channel groupings to isolate a particular fluctuating quantity. High-frequency ion velocity measurements (100-200 kHz) were made by using this method. We also conducted simulations to compare LSCA with a moment analysis technique under a low photon count condition. Both experimental and synthetic measurements demonstrate the effectiveness of LSCA.

  3. Measurement of Barkhausen emission and magnetoacoustic emission from a fractured steel bar

    SciTech Connect

    Ng, D.H.L.; Yu, C.C.; Li, A.S.K.; Lo, C.C.H.

    1995-11-01

    Barkhausen emission (BE) and magnetoacoustic emission (MAE) measurements have been made on a fractured steel bar. The MAE profile shows a large initial peak and a small final peak, whereas the BE profile contains an initial peak and a large central peak. These observations suggest that the process of domain nucleation involves the enlargement of residual domains that surround the defects, and is a result of the unpinning of the trapped domain walls. In the maximum field, the residual domains confined by the walls are not completely annihilated due to the strong demagnetizing field surrounding the defects, causing the final BE and MAE peaks to be small. Also, in the low field region of the BE profile, the large central peak indicates that the elongated grains have enhanced the motion of the 180{degree} walls. After the bar has been annealed, the authors found that (1) the differences in magnitude between the initial and final peaks of both BE and MAE profiles are narrowed because of the fewer defects, and (2) the overall BE and MAE signals are reduced as a result of the coarsening of ferrite and cementite grains.

  4. Wide angle Michelson Doppler imaging interferometer. [measuring atmospheric emissions

    NASA Technical Reports Server (NTRS)

    Shepherd, G. G.

    1980-01-01

    The optical system, stepping control, phase and modulation depth, array detector, and directions sensor are described for a specialized type of Michelson interferometer which works at sufficiently high resolution to measure the line widths and Doppler shifts of naturally occurring atmospheric emissions. With its imaging capability, the instrument can potentially supply this data independently for each element of the 100 x 100 detector array. The experiment seeks: (1) to obtain vertical profiles of atmospheric winds and temperatures as functions of latitude by observing near the limb; (2) to acquire exploratory wind and temperature data on smaller scale structures in airglow irregularities and in auroral forms; and (3) to collaborate with other Spacelab experiments, such as barium cloud releases, in providing wind and temperature data.

  5. Ionospheric plasma density irregularities measured by stimulated electromagnetic emission

    NASA Astrophysics Data System (ADS)

    Norin, L.; Grach, S. M.; Leyser, T. B.; Thidé, B.; Sergeev, E. N.; Berlin, M.

    2008-09-01

    It is well known that ionospheric plasma turbulence can be conveniently generated by controlled injection of powerful high-frequency radio beams from the ground. Irradiation of the ionosphere with such radio waves leads to the formation of plasma density structures, striations, and the generation of secondary electromagnetic radiation, a phenomenon known as stimulated electromagnetic emission (SEE). In this paper we present experimental results of the dependence of SEE on decreasing excitation levels of the striations. In the experiments the frequency of the injected radio beam was varied near the fifth harmonic of the local ionospheric electron gyro frequency. We use the SEE measurements to obtain transverse length scales of the striations involved in the generation of the SEE. Our results show that different spectral features of the SEE display different temporal dynamics, suggesting that they are related to striations with different transverse length scales (1 ≲ l⊥ ≲ 25 m).

  6. Measurement of elemental concentration of aerosols using spark emission spectroscopy.

    PubMed

    Diwakar, Prasoon K; Kulkarni, Pramod

    A coaxial microelectrode system has been used to collect and analyse the elemental composition of aerosol particles in near real-time using spark emission spectroscopy. The technique involves focused electrostatic deposition of charged aerosol particles onto the flat tip of a microelectrode, followed by introduction of spark discharge. A pulsed spark discharge was generated across the electrodes with input energy ranging from 50 to 300 mJ per pulse, resulting in the formation of controlled pulsed plasma. The particulate matter on the cathode tip is ablated and atomized by the spark plasma, resulting in atomic emissions which are subsequently recorded using a broadband optical spectrometer for element identification and quantification. The plasma characteristics were found to be very consistent and reproducible even after several thousands of spark discharges using the same electrode system. The spark plasma was characterized by measuring the excitation temperature (~7000 to 10 000 K), electron density (~10(16) cm(-3)), and evolution of spectral responses as a function of time. The system was calibrated using particles containing Pb, Si, Na and Cr. Absolute mass detection limits in the range 11 pg to 1.75 ng were obtained. Repeatability of spectral measurements varied from 2 to 15%. The technique offers key advantages over similar microplasma-based techniques such as laser-induced breakdown spectroscopy, as: (i) it does not require any laser beam optics and eliminates any need for beam alignment, (ii) pulse energy from dc power supply in SIBS system can be much higher compared to that from laser source of the same physical size, and (iii) it is quite conducive to compact, field-portable instrumentation.

  7. Measurement of elemental concentration of aerosols using spark emission spectroscopy†

    PubMed Central

    Diwakar, Prasoon K.

    2015-01-01

    A coaxial microelectrode system has been used to collect and analyse the elemental composition of aerosol particles in near real-time using spark emission spectroscopy. The technique involves focused electrostatic deposition of charged aerosol particles onto the flat tip of a microelectrode, followed by introduction of spark discharge. A pulsed spark discharge was generated across the electrodes with input energy ranging from 50 to 300 mJ per pulse, resulting in the formation of controlled pulsed plasma. The particulate matter on the cathode tip is ablated and atomized by the spark plasma, resulting in atomic emissions which are subsequently recorded using a broadband optical spectrometer for element identification and quantification. The plasma characteristics were found to be very consistent and reproducible even after several thousands of spark discharges using the same electrode system. The spark plasma was characterized by measuring the excitation temperature (~7000 to 10 000 K), electron density (~1016 cm−3), and evolution of spectral responses as a function of time. The system was calibrated using particles containing Pb, Si, Na and Cr. Absolute mass detection limits in the range 11 pg to 1.75 ng were obtained. Repeatability of spectral measurements varied from 2 to 15%. The technique offers key advantages over similar microplasma-based techniques such as laser-induced breakdown spectroscopy, as: (i) it does not require any laser beam optics and eliminates any need for beam alignment, (ii) pulse energy from dc power supply in SIBS system can be much higher compared to that from laser source of the same physical size, and (iii) it is quite conducive to compact, field-portable instrumentation. PMID:26491209

  8. Mitigation of methane emissions in cities: How new measurements and partnerships can contribute to emissions reduction strategies

    NASA Astrophysics Data System (ADS)

    Hopkins, Francesca M.; Ehleringer, James R.; Bush, Susan E.; Duren, Riley M.; Miller, Charles E.; Lai, Chun-Ta; Hsu, Ying-Kuang; Carranza, Valerie; Randerson, James T.

    2016-09-01

    Cities generate 70% of anthropogenic greenhouse gas emissions, a fraction that is growing with global urbanization. While cities play an important role in climate change mitigation, there has been little focus on reducing urban methane (CH4) emissions. Here, we develop a conceptual framework for CH4 mitigation in cities by describing emission processes, the role of measurements, and a need for new institutional partnerships. Urban CH4 emissions are likely to grow with expanding use of natural gas and organic waste disposal systems in growing population centers; however, we currently lack the ability to quantify this increase. We also lack systematic knowledge of the relative contribution of these distinct source sectors on emissions. We present new observations from four North American cities to demonstrate that CH4 emissions vary in magnitude and sector from city to city and hence require different mitigation strategies. Detections of fugitive emissions from these systems suggest that current mitigation approaches are absent or ineffective. These findings illustrate that tackling urban CH4 emissions will require research efforts to identify mitigation targets, develop and implement new mitigation strategies, and monitor atmospheric CH4 levels to ensure the success of mitigation efforts. This research will require a variety of techniques to achieve these objectives and should be deployed in cities globally. We suggest that metropolitan scale partnerships may effectively coordinate systematic measurements and actions focused on emission reduction goals.

  9. HMM-ModE – Improved classification using profile hidden Markov models by optimising the discrimination threshold and modifying emission probabilities with negative training sequences

    PubMed Central

    Srivastava, Prashant K; Desai, Dhwani K; Nandi, Soumyadeep; Lynn, Andrew M

    2007-01-01

    Background Profile Hidden Markov Models (HMM) are statistical representations of protein families derived from patterns of sequence conservation in multiple alignments and have been used in identifying remote homologues with considerable success. These conservation patterns arise from fold specific signals, shared across multiple families, and function specific signals unique to the families. The availability of sequences pre-classified according to their function permits the use of negative training sequences to improve the specificity of the HMM, both by optimizing the threshold cutoff and by modifying emission probabilities to minimize the influence of fold-specific signals. A protocol to generate family specific HMMs is described that first constructs a profile HMM from an alignment of the family's sequences and then uses this model to identify sequences belonging to other classes that score above the default threshold (false positives). Ten-fold cross validation is used to optimise the discrimination threshold score for the model. The advent of fast multiple alignment methods enables the use of the profile alignments to align the true and false positive sequences, and the resulting alignments are used to modify the emission probabilities in the original model. Results The protocol, called HMM-ModE, was validated on a set of sequences belonging to six sub-families of the AGC family of kinases. These sequences have an average sequence similarity of 63% among the group though each sub-group has a different substrate specificity. The optimisation of discrimination threshold, by using negative sequences scored against the model improves specificity in test cases from an average of 21% to 98%. Further discrimination by the HMM after modifying model probabilities using negative training sequences is provided in a few cases, the average specificity rising to 99%. Similar improvements were obtained with a sample of G-Protein coupled receptors sub-classified with

  10. Relationship among methane emission, ammonia emission and selected animal performance measurements

    USDA-ARS?s Scientific Manuscript database

    Enteric methane (CH4) emission and subsequent CH4 emission from manure of ruminant livestock are major contributors to anthropogenic greenhouse gases (GHG) emission in many countries. Similarly, livestock manure is an important source of undesirable atmospheric ammonia (NH3). Identifying and quantif...

  11. 40 CFR 87.82 - Sampling and analytical procedures for measuring smoke exhaust emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... measuring smoke exhaust emissions. 87.82 Section 87.82 Protection of Environment ENVIRONMENTAL PROTECTION... Test Procedures for Engine Smoke Emissions (Aircraft Gas Turbine Engines) § 87.82 Sampling and analytical procedures for measuring smoke exhaust emissions. The system and procedures for sampling and...

  12. 40 CFR 87.82 - Sampling and analytical procedures for measuring smoke exhaust emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... measuring smoke exhaust emissions. 87.82 Section 87.82 Protection of Environment ENVIRONMENTAL PROTECTION... Test Procedures for Engine Smoke Emissions (Aircraft Gas Turbine Engines) § 87.82 Sampling and analytical procedures for measuring smoke exhaust emissions. The system and procedures for sampling and...

  13. Effect of measurement protocol on organic aerosol measurements of exhaust emissions from gasoline and diesel vehicles

    NASA Astrophysics Data System (ADS)

    Kim, Youngseob; Sartelet, Karine; Seigneur, Christian; Charron, Aurélie; Besombes, Jean-Luc; Jaffrezo, Jean-Luc; Marchand, Nicolas; Polo, Lucie

    2016-09-01

    Exhaust emissions of semi-volatile organic compounds (SVOC) from passenger vehicles are usually estimated only for the particle phase via the total particulate matter measurements. However, they also need to be estimated for the gas phase, as they are semi-volatile. To better estimate SVOC emission factors of passenger vehicles, a measurement campaign using a chassis dynamometer was conducted with different instruments: (1) a constant volume sampling (CVS) system in which emissions were diluted with filtered air and sampling was performed on filters and polyurethane foams (PUF) and (2) a Dekati Fine Particle Sampler (FPS) in which emissions were diluted with purified air and sampled with on-line instruments (PTR-ToF-MS, HR-ToF-AMS, MAAP, CPC). Significant differences in the concentrations of organic carbon (OC) measured by the instruments are observed. The differences can be explained by sampling artefacts, differences between (1) the time elapsed during sampling (in the case of filter and PUF sampling) and (2) the time elapsed from emission to measurement (in the case of on-line instruments), which vary from a few seconds to 15 min, and by the different dilution factors. To relate elapsed times and measured concentrations of OC, the condensation of SVOC between the gas and particle phases is simulated with a dynamic aerosol model. The simulation results allow us to understand the relation between elapsed times and concentrations in the gas and particle phases. They indicate that the characteristic times to reach thermodynamic equilibrium between gas and particle phases may be as long as 8 min. Therefore, if the elapsed time is less than this characteristic time to reach equilibrium, gas-phase SVOC are not at equilibrium with the particle phase and a larger fraction of emitted SVOC will be in the gas phase than estimated by equilibrium theory, leading to an underestimation of emitted OC if only the particle phase is considered or if the gas-phase SVOC are estimated

  14. Otoacoustic emissions measured in spotted hyenas (Crocuta crocuta)

    NASA Astrophysics Data System (ADS)

    McFadden, Dennis; Pasanen, Edward G.; Weldele, Mary L.; Glickman, Stephen E.; Place, Ned J.

    2003-10-01

    From birth, female spotted hyenas exhibit highly masculinized bodies and behaviors. Their external genitalia greatly resemble those of males, and they are behaviorally dominant over males. This marked masculinization raised the question of whether the otoacoustic emissions (OAEs) of female spotted hyenas also would be masculinized. Click-evoked OAEs were measured in six female and six male hyenas at two click levels. Also, distortion-product OAEs were measured at four or more primary levels in three frequency regions: 2, 3.5, and 5.0 kHz. Both CEOAEs and DPOAEs were strong in both sexes in spotted hyenas. In humans, both CEOAEs and DPOAEs are stronger in females than males and stronger in right ears than left. Unlike humans, both the CEOAEs and DPOAEs in female spotted hyenas were weaker than those in males, and unlike humans, OAEs were not stronger in right ears. The implication is that the same androgenizing processes that masculinize the body and behavior of female hyenas also masculinize those elements of the cochlea responsible for OAEs. That implication is being tested by measuring the OAEs of other hyenas in the Berkeley colony that were treated with antiandrogenic agents during fetal development. [Work supported by NIDCD.

  15. Use of portable emissions measurement system (PEMS) for the development and validation of passenger car emission factors

    NASA Astrophysics Data System (ADS)

    Kousoulidou, Marina; Fontaras, Georgios; Ntziachristos, Leonidas; Bonnel, Pierre; Samaras, Zissis; Dilara, Panagiota

    2013-01-01

    This paper discusses the development and validation of passenger car emission factors, using real world operation data. In total, six passenger cars of different technologies were studied. The tested vehicles were operated under various driving conditions and over two different routes in the region of Lombardia, Italy. These routes were specifically defined in order to provide a range of driving conditions, including urban, rural and highway driving. Tailpipe emissions and exhaust gas flows were measured on-board the vehicle, using a portable emissions measurement system (PEMS). In addition, all vehicles were tested over the European type-approval driving cycle (NEDC) with the same PEMS equipment. The testing of gasoline vehicles showed that emissions are well below the emission standards and do not raise any concern. However, the testing of diesel vehicles both under real-world driving conditions and over the NEDC brought to the surface important concerns regarding the actual NOx emissions of modern diesel vehicles, since they seem to comply with the corresponding emission standard over the type-approval cycle, but they constantly exceed the specified limit when tested under real-world driving conditions. Results from real-world operation revealed that there is a significant deviation from the NOx emission standard limit (especially for the newly introduced Euro 5 technology). These observations raise concerns regarding the actual NOx emissions of modern vehicles and their impact on urban air-quality. The emission factors originally measured on the road are also compared to the corresponding COPERT average speed emission factors. In general, emissions of CO2, THC and CO correlate fairly well with COPERT, for all vehicles. In the case of NOx emissions, emission levels of the two tested Euro 5 diesel passenger cars are consistently higher in urban, rural, and highway driving compared to the corresponding COPERT emission factor. Thus, leading to the conclusion that

  16. X-ray Emission Line Anisotropy Effects on the Isoelectronic Temperature Measurement Method

    NASA Astrophysics Data System (ADS)

    Liedahl, Duane; Barrios, Maria; Brown, Greg; Foord, Mark; Gray, William; Hansen, Stephanie; Heeter, Robert; Jarrott, Leonard; Mauche, Christopher; Moody, John; Schneider, Marilyn; Widmann, Klaus

    2016-10-01

    Measurements of the ratio of analogous emission lines from isoelectronic ions of two elements form the basis of the isoelectronic method of inferring electron temperatures in laser-produced plasmas, with the expectation that atomic modeling errors cancel to first order. Helium-like ions are a common choice in many experiments. Obtaining sufficiently bright signals often requires sample sizes with non-trivial line optical depths. For lines with small destruction probabilities per scatter, such as the 1s2p-1s2 He-like resonance line, repeated scattering can cause a marked angular dependence in the escaping radiation. Isoelectronic lines from near-Z equimolar dopants have similar optical depths and similar angular variations, which leads to a near angular-invariance for their line ratios. Using Monte Carlo simulations, we show that possible ambiguities associated with anisotropy in deriving electron temperatures from X-ray line ratios are minimized by exploiting this isoelectronic invariance.

  17. Trend of vehicle emission levels until 2020 - Prognosis based on current vehicle measurements and future emission legislation

    NASA Astrophysics Data System (ADS)

    Rexeis, Martin; Hausberger, Stefan

    The paper describes the incorporation of actual emission measurements and future emission standards into the emission model 'NEMO' (Network Emission Model). This model is then applied to make predictions on vehicle emission levels on basis of the Austrian fleet composition until 2020. The output is compared to the results based on the most common emission tool for the calculation of vehicle emissions in Central Europe - the recent version (2.1) of the 'Handbook Emission Factors for Road Transport'. The discussion is focused on NO x and particulate matter (PM), since these pollutants are considered to be the most critical for the local air quality level. The NO x emission levels of recent modern diesel vehicle generations observed in several real world driving conditions were observed to be clearly higher than demanded in the type approval procedure. Due to the growing number of modern diesel engine concepts equipped with coated catalytic exhaust after treatment, the fraction of NO 2 of the total tailpipe NO x emissions is predicted to continue to increase in the next few years. Bearing in mind the upcoming tightening of the NO 2 air quality limits and the steady increase of traffic volumes, excesses of the NO 2 air quality limits at roadside locations have to be expected to an increasing extent for the beginning of the next decade. The issue of particle emissions originated from the diesel engine combustion process can be regarded as being technically solved due to the extensive introduction of diesel particle filters in the vehicle fleet if these systems will prove a high efficiency over the entire vehicle life in real world operation conditions. However, PM emissions from road transport will continue to be in the focus of public attention due to particle emissions caused by dust re-suspension and abrasion processes.

  18. Driving cycles for measuring passenger car emissions on roads with traffic calming measures

    PubMed

    Boutler; Latham; Ainge

    1999-09-01

    Although local authorities in the UK need to be aware of any air quality impacts resulting from their traffic calming operations, there is little information relating to the effects of different traffic calming measures. The effects on air quality on this scale are complex, and so TRL is providing guidance by developing performance indices for different measures based on their effects on vehicle emissions. The emissions indices for passenger cars are based on tests conducted on a chassis dynamometer, and this paper describes the development of the methodology for constructing the driving cycles to be used. The technique involves the measurement of the speed profiles of a large number of vehicles using a roadside LIDAR system, and the determination of typical gear selections using three-instrumented cars.

  19. Measurements of oscillator strengths for EUV emissions of ionized oxygen, nitrogen and sulfur

    NASA Technical Reports Server (NTRS)

    Ryan, L. J.; Cunningham, A. J.; Rayburn, L. A.

    1989-01-01

    Oscillator-strength determinations for EUV branching emissions of atomic oxygen, nitrogen and sulfur are reported. The transitions studied were excited using a beam-foil source and both branching ratios and radiative lifetimes were determined. Calculated transition-probability data for multiply-ionized neon and oxygen emissions were used to obtain an in situ relative sensitivity curve for the EUV detection system used. New oscillator strengths for NII, OII, SII, and SIII EUV branching emissions that terminate on metastable states of the respective ions are reported, together with new lifetime data for ionized sulfur emissions.

  20. Measurement of sodium density and the Na 514-nm transition probability in a high-pressure sodium arc

    NASA Astrophysics Data System (ADS)

    Benson, T. P.; Bhattacharya, A. K.

    1990-09-01

    Spatially resolved arc temperatures and sodium density measurements are presented for two high-pressure sodium arcs. Absolute intensities of the optically thick 818/819-nm lines were used to determine the arc temperature while the radial profile of the optically thin 514-nm line was Abel inverted to determine the Na atomic density. Agreement with an independent measurement of the Na density obtained by controlling pressure of sodium in the lamp with a tin bath consistently required a value for the Na 514-nm transition probability 2-3 times smaller than the literature value (A=0.011×108 s-1 ) of Wiese, Smith, and Miles [Atomic Transition Probabilities, NSRDS-NBS 4 (NBS, Washington, DC, 1971), Vol. II], obtained from quantum mechanical calculations. The results of three separate experiments indicate that the value should be modified to A=0.0040×108 s-1 with a standard deviation of ±21%. A more detailed error analysis including systematic error would indicate an accuracy to within ±33%.

  1. COMPARISON OF ANALYTICAL TECHNIQUES FOR MEASURING HYDROCARBON EMISSIONS FROM THE MANUFACTURE OF FIBERGLASS-REINFORCED PLASTICS

    EPA Science Inventory

    The paper discusses several projects to measure hydrocarbon emissions associated with the manufacture of fiberglass-reinforced plastics. The main purpose of the projects was to evaluate pollution prevention techniques to reduce emissions by altering raw materials, application equ...

  2. COMPARISON OF ANALYTICAL TECHNIQUES FOR MEASURING HYDROCARBON EMISSIONS FROM THE MANUFACTURE OF FIBERGLASS-REINFORCED PLASTICS

    EPA Science Inventory

    The paper discusses several projects to measure hydrocarbon emissions associated with the manufacture of fiberglass-reinforced plastics. The main purpose of the projects was to evaluate pollution prevention techniques to reduce emissions by altering raw materials, application equ...

  3. Area-Based Measurements of Methane Emissions from Oil and Natural Gas Operations- September 2012 Workshop

    EPA Pesticide Factsheets

    View a presentation on area-based measurements of methane (CH4) emissions, presented at the Stakeholder Workshop on Natural Gas in the Inventory of U.S. Greenhouse Gas (GHG) Emissions and Sinks on Thursday, September 13, 2012.

  4. Spectroscopic inferences from HIS measurements of atmospheric thermal emission

    NASA Technical Reports Server (NTRS)

    Revercomb, H. E.; Knuteson, R. O.; Smith, W. L.; Woolf, H. M.; Howell, H. B.

    1991-01-01

    Radiometrically accurate observations of the earth's emission spectrum from 3.8 to 16.6 microns have been made using the High-resolution Interferometer Sounder (HIS) to look downward from the NASA U2/ER2 aircraft or upward from the ground. These observations have been used to demonstrate the substantially improved vertical resolution of temperature and water vapor soundings derived from high resolution spectra (resolving power from 1800 to 3800), as compared to soundings from the low resolution filter radiometer observations used in current satellite sounders. The HIS observations have also demonstrated that Fourier Transform Infrared (FTIR) instruments are especially well suited to absolute emission measurements of broad spectral bands at high resolution. A fundamental advantage of FTIR instruments for accurate calibration is wavelength integrity, the same property which has made FTIR the standard for very high resolution absorption measurements. The long wavelength part of a HIS downwelling radiance spectrum is compared to a calculated spectrum. The calculation uses the AFGL HITRAN/86 line file and FASCOD2 line-by-line program with atmospheric state data from in situ measurements. In general, agreement between HIS and FASCOD2 spectra is remarkably good, a tribute to the current state of spectral line files and line-by-line codes. Reproducible differences between HIS observations and FASCOD2 line-by-line calculations lead to the following conclusions: (1) The FASCOD2 water vapor continuum in the longwave window region from 10 to 13 microns (750 to 1000 cm(exp -1)) gives reasonable agreement with radiance observations; (2) The model H2O continuum from 7 to 8 microns (1250 to 1425 cm(exp -2)) needs adjustment to reduce its contribution by about 60 percent; (3) CO2 absorption in the region from 13.1 to 14.3 microns (700 to 760 cm(exp -1)) is too small in the model; and (4) Water vapor line strengths in the region from 8.1 to 9.1 microns (1100 to 1230 cm(exp -1)) need

  5. Spectroscopic inferences from HIS measurements of atmospheric thermal emission

    NASA Astrophysics Data System (ADS)

    Revercomb, H. E.; Knuteson, R. O.; Smith, W. L.; Woolf, H. M.; Howell, H. B.

    1991-12-01

    Radiometrically accurate observations of the earth's emission spectrum from 3.8 to 16.6 microns have been made using the High-resolution Interferometer Sounder (HIS) to look downward from the NASA U2/ER2 aircraft or upward from the ground. These observations have been used to demonstrate the substantially improved vertical resolution of temperature and water vapor soundings derived from high resolution spectra (resolving power from 1800 to 3800), as compared to soundings from the low resolution filter radiometer observations used in current satellite sounders. The HIS observations have also demonstrated that Fourier Transform Infrared (FTIR) instruments are especially well suited to absolute emission measurements of broad spectral bands at high resolution. A fundamental advantage of FTIR instruments for accurate calibration is wavelength integrity, the same property which has made FTIR the standard for very high resolution absorption measurements. The long wavelength part of a HIS downwelling radiance spectrum is compared to a calculated spectrum. The calculation uses the AFGL HITRAN/86 line file and FASCOD2 line-by-line program with atmospheric state data from in situ measurements. In general, agreement between HIS and FASCOD2 spectra is remarkably good, a tribute to the current state of spectral line files and line-by-line codes. Reproducible differences between HIS observations and FASCOD2 line-by-line calculations lead to the following conclusions: (1) The FASCOD2 water vapor continuum in the longwave window region from 10 to 13 microns (750 to 1000 cm(exp -1)) gives reasonable agreement with radiance observations; (2) The model H2O continuum from 7 to 8 microns (1250 to 1425 cm(exp -2)) needs adjustment to reduce its contribution by about 60 percent; (3) CO2 absorption in the region from 13.1 to 14.3 microns (700 to 760 cm(exp -1)) is too small in the model; and (4) Water vapor line strengths in the region from 8.1 to 9.1 microns (1100 to 1230 cm(exp -1)) need

  6. Otoacoustic emissions measured in rhesus monkeys (Macaca mulatta)

    NASA Astrophysics Data System (ADS)

    McFadden, Dennis; Pasanen, Edward G.; Raper, Jessica; Wallen, Kim

    2003-10-01

    In humans, otoacoustic emissions (OAEs) are stronger in females than in males and stronger in right ears than in left. The physiological bases for these differences are unknown, but several lines of circumstantial evidence suggest that the sex difference is attributable to androgenizing mechanisms operating during prenatal development. Specifically, it appears that exposure to high levels of androgens during prenatal development diminishes the strength of the cochlear amplifiers and thus the strength of the OAEs. Sex and ear differences in OAEs have not been well studied in species other than humans. Accordingly, click-evoked OAEs and distortion-product OAEs were measured in nine female and nine male rhesus monkeys. For CEOAEs, but less clearly for DPOAEs, females exhibited significantly stronger OAEs than males. There was no consistent ear difference for either sex for either type of OAE. In order to better study the early components of the CEOAE waveform, a nonlinear procedure [Molenaar et al., Hearing Res. 143, 197-207 (2002)] was used to collect CEOAEs along with our standard (linear) procedure. This colony also contains animals of each sex that were treated with androgenic or antiandrogenic agents during prenatal development, and OAEs are also currently being measured on those animals. [Work supported by NIDCD.

  7. Active Region Emission Measure Distributions and Implications for Nanoflare Heating

    NASA Astrophysics Data System (ADS)

    Cargill, P. J.

    2014-03-01

    The temperature dependence of the emission measure (EM) in the core of active regions coronal loops is an important diagnostic of heating processes. Observations indicate that EM(T) ~ Ta below approximately 4 MK, with 2 < a < 5. Zero-dimensional hydrodynamic simulations of nanoflare trains are used to demonstrate the dependence of a on the time between individual nanoflares (TN ) and the distribution of nanoflare energies. If TN is greater than a few thousand seconds, a < 3. For smaller values, trains of equally spaced nanoflares cannot account for the observed range of a if the distribution of nanoflare energies is either constant, randomly distributed, or a power law. Power law distributions where there is a delay between consecutive nanoflares proportional to the energy of the second nanoflare do lead to the observed range of a. However, TN must then be of the order of hundreds to no more than a few thousand seconds. If a nanoflare leads to the relaxation of a stressed coronal field to a near-potential state, the time taken to build up the required magnetic energy is thus too long to account for the EM measurements. Instead, it is suggested that a nanoflare involves the relaxation from one stressed coronal state to another, dissipating only a small fraction of the available magnetic energy. A consequence is that nanoflare energies may be smaller than previously envisioned.

  8. Active region emission measure distributions and implications for nanoflare heating

    SciTech Connect

    Cargill, P. J.

    2014-03-20

    The temperature dependence of the emission measure (EM) in the core of active regions coronal loops is an important diagnostic of heating processes. Observations indicate that EM(T) ∼ T{sup a} below approximately 4 MK, with 2 < a < 5. Zero-dimensional hydrodynamic simulations of nanoflare trains are used to demonstrate the dependence of a on the time between individual nanoflares (T{sub N} ) and the distribution of nanoflare energies. If T{sub N} is greater than a few thousand seconds, a < 3. For smaller values, trains of equally spaced nanoflares cannot account for the observed range of a if the distribution of nanoflare energies is either constant, randomly distributed, or a power law. Power law distributions where there is a delay between consecutive nanoflares proportional to the energy of the second nanoflare do lead to the observed range of a. However, T{sub N} must then be of the order of hundreds to no more than a few thousand seconds. If a nanoflare leads to the relaxation of a stressed coronal field to a near-potential state, the time taken to build up the required magnetic energy is thus too long to account for the EM measurements. Instead, it is suggested that a nanoflare involves the relaxation from one stressed coronal state to another, dissipating only a small fraction of the available magnetic energy. A consequence is that nanoflare energies may be smaller than previously envisioned.

  9. Multi-spectrum retrieval of Venus IR surface emissivity maps from VIRTIS/VEX nightside measurements at Themis Regio

    NASA Astrophysics Data System (ADS)

    Kappel, David; Arnold, Gabriele; Haus, Rainer

    2016-02-01

    Surface emissivity maps in the infrared can contribute to explore Venus' geology. Nightside radiance spectra at Themis Regio acquired by the IR mapping channel of the Visible and InfraRed Thermal Imaging Spectrometer (VIRTIS-M-IR) aboard Venus EXpress (VEX) are used to derive emissivity data from the three accessible spectral surface windows at 1.02, 1.10, and 1.18 μm. The measured spectra are simulated by applying a full radiative transfer model. Neglecting geologic activity, a multi-spectrum retrieval algorithm is utilized to determine the emissivity maps of the surface target as parameter vectors that are common to many spectrally resolved images that cover this target. Absolute emissivity values are difficult to obtain due to strong interferences from other parameters. The true emissivity mean of the target cannot be retrieved, nor can the emissivity mean of a retrieved map be strictly preset. The retrieved map can exhibit trends with latitude and topography that are probably artificial. Once the trends have been removed in a post-processing step, it can be observed that the magnitude of the resulting spatial emissivity fluctuations around their mean value increases with increasing mean value. A linear transformation is applied that converts the de-trended map to exhibit a defined emissivity mean value called reference emissivity, here 0.5, yielding the 'renormalized emissivity map' with accordingly transformed fluctuations. It is verified that renormalized emissivity maps are largely independent of the emissivity mean before renormalization, of modifications to interfering atmospheric, surface, and instrumental parameters, and of selected details of the retrieval pipeline and data calibration and preprocessing. Extremely large emissivity retrieval errors due to imperfect or unconsidered forward model parameters are effectively avoided. If the absolute emissivity at a given bin of the target were known, the absolute emissivity map of the entire target could be

  10. Emissions of N2O and NO from fertilized fields: Summary of available measurement data

    NASA Astrophysics Data System (ADS)

    Bouwman, A. F.; Boumans, L. J. M.; Batjes, N. H.

    2002-12-01

    Information from 846 N2O emission measurements in agricultural fields and 99 measurements for NO emissions was summarized to assess the influence of various factors regulating emissions from mineral soils. The data indicate that there is a strong increase of both N2O and NO emissions accompanying N application rates, and soils with high organic-C content show higher emissions than less fertile soils. A fine soil texture, restricted drainage, and neutral to slightly acidic conditions favor N2O emission, while (though not significant) a good soil drainage, coarse texture, and neutral soil reaction favor NO emission. Fertilizer type and crop type are important factors for N2O but not for NO, while the fertilizer application mode has a significant influence on NO only. Regarding the measurements, longer measurement periods yield more of the fertilization effect on N2O and NO emissions, and intensive measurements (≥1 per day) yield lower emissions than less intensive measurements (2-3 per week). The available data can be used to develop simple models based on the major regulating factors which describe the spatial variability of emissions of N2O and NO with less uncertainty than emission factor approaches based on country N inputs, as currently used in national emission inventories.

  11. Real-world operation conditions and on-road emissions of Beijing diesel buses measured by using portable emission measurement system and electric low-pressure impactor.

    PubMed

    Liu, Zhihua; Ge, Yunshan; Johnson, Kent C; Shah, Asad Naeem; Tan, Jianwei; Wang, Chu; Yu, Linxiao

    2011-03-15

    On-road measurement is an effective method to investigate real-world emissions generated from vehicles and estimate the difference between engine certification cycles and real-world operating conditions. This study presents the results of on-road measurements collected from urban buses which propelled by diesel engine in Beijing city. Two widely used Euro III emission level buses and two Euro IV emission level buses were chosen to perform on-road emission measurements using portable emission measurement system (PEMS) for gaseous pollutant and Electric Low Pressure Impactor (ELPI) for particulate matter (PM) number emissions. The results indicate that considerable discrepancies of engine operating conditions between real-world driving cycles and engine certification cycles have been observed. Under real-world operating conditions, carbon monoxide (CO) and hydrocarbon (HC) emissions can easily meet their respective regulations limits, while brake specification nitrogen oxide (bsNO(x)) emissions present a significant deviation from its corresponding limit. Compared with standard limits, the real-world bsNO(x) emission of the two Euro III emission level buses approximately increased by 60% and 120% respectively, and bsNO(x) of two Euro IV buses nearly twice standard limits because Selective Catalytic Reduction (SCR) system not active under low exhaust temperature. Particle mass were estimated via particle size distribution with the assumption that particle density and diameter is liner. The results demonstrate that nanometer size particulate matter make significant contribution to total particle number but play a minor role to total particle mass. It is suggested that specific certified cycle should be developed to regulate bus engines emissions on the test bench or use PEMS to control the bus emissions under real-world operating conditions. Copyright © 2010 Elsevier B.V. All rights reserved.

  12. On-road remote sensing of liquefied petroleum gas (LPG) vehicle emissions measurement and emission factors estimation

    NASA Astrophysics Data System (ADS)

    Ning, Z.; Chan, T. L.

    In the present study, the real-world on-road liquefied petroleum gas (LPG) vehicle/taxi emissions of carbon monoxide (CO), hydrocarbon (HC) and nitric oxide (NO) were investigated. A regression analysis approach based on the measured LPG vehicle emission data was also used to estimate the on-road LPG vehicle emission factors of CO, HC and NO with respect to the effects of instantaneous vehicle speed and acceleration/deceleration profiles for local urban driving patterns. The results show that the LPG vehicle model years and driving patterns have a strong correlation to their emission factors. A unique correlation of LPG vehicle emission factors (i.e., g km -1 and g l -1) on different model years for urban driving patterns has been established. Finally, a comparison was made between the average LPG, and petrol [Chan, T.L., Ning, Z., Leung, C.W., Cheung, C.S., Hung, W.T., Dong, G., 2004. On-road remote sensing of petrol vehicle emissions measurement and emission factors estimation in Hong Kong. Atmospheric Environment 38, 2055-2066 and 3541] and diesel [Chan, T.L., Ning, Z., 2005. On-road remote sensing of diesel vehicle emissions measurement and emission factors estimation in Hong Kong. Atmospheric Environment 39, 6843-6856] vehicle emission factors. It has shown that the introduction of the replacement of diesel taxis to LPG taxis has alleviated effectively the urban street air pollution. However, it has demonstrated that proper maintenance on the aged LPG taxis should also be taken into consideration.

  13. A Portable Emissions Measurement System (PEMS) study of NOx and primary NO2 emissions from Euro 6 diesel passenger cars and comparison with COPERT emission factors

    NASA Astrophysics Data System (ADS)

    O'Driscoll, Rosalind; ApSimon, Helen M.; Oxley, Tim; Molden, Nick; Stettler, Marc E. J.; Thiyagarajah, Aravinth

    2016-11-01

    Real world emissions of oxides of nitrogen (NOx) often greatly exceed those achieved in the laboratory based type approval process. In this paper the real world emissions from a substantial sample of the latest Euro 6 diesel passenger cars are presented with a focus on NOx and primary NO2. Portable Emissions Measurement System (PEMS) data is analysed from 39 Euro 6 diesel passenger cars over a test route comprised of urban and motorway sections. The sample includes vehicles installed with exhaust gas recirculation (EGR), lean NOx traps (LNT), or selective catalytic reduction (SCR). The results show wide variability in NOx emissions from 1 to 22 times the type approval limit. The average NOx emission, 0.36 (sd. 0.36) g km-1, is 4.5 times the Euro 6 limit. The average fraction primary NO2 (fNO2) is 44 (sd. 20) %. Higher emissions during the urban section of the route are attributed to an increased number of acceleration events. Comparisons between PEMS measurements and COPERT speed dependent emissions factors show PEMS measurements to be on average 1.6 times higher than COPERT estimates for NOx and 2.5 times for NO2. However, by removing the 5 most polluting vehicles average emissions were reduced considerably.

  14. Expressions to determine temperatures and emission measures for solar X-ray events from GOES measurements

    NASA Technical Reports Server (NTRS)

    Thomas, R. J.; Starr, R.; Crannell, C. J.

    1984-01-01

    Expressions which give the effective color temperatures and corresponding emission measures for solar X-ray events observed with instruments onboard any of the GOES satellites are developed. Theoretical spectra were used to simulate the solar X-ray input at a variety of plasma temperatures. These spectra were folded through the wavelength dependent transfer functions for the two GOES detectors. The resulting detector responses and their ratio as a function of plasma temperature were then fit with simple analytic curves. Over the entire range between 5 and 30 million degrees, these fits reproduce the calculated color temperatures within 2% and the calculated emission measures within 5%. With the theoretical spectra, similar expressions for any pair of broadband X-ray detectors whose sensitivities are limited to wavelengths between 0.2 and 100 A are calculable.

  15. [Correction method for infrared spectral emissivity measurement system based on integrating sphere reflectometer].

    PubMed

    Zhang, Yu-Feng; Dai, Jing-Min; Zhang, Yu; Pan, Wei-Dong; Zhang, Lei

    2013-08-01

    In view of the influence of non-ideal reference standard on spectral emissivity measurement, by analyzing the principle of infrared emissivity measurement system based on integrating sphere reflectometer, a calibration method suitable for measuring spectral emissivity system using the reflection measurement was proposed. By fitting a spectral reflectance curve of the reference standard sample to the given reflectance data, the correction coefficient of measurement system was computed. Then the output voltage curve of reference standard sample was corrected by this coefficient. The system error caused by the imperfection of reference standard was eliminated. The correction method was applied to the spectral emissivity measurement system based on integrating sphere reflectometer. The results measured by the corrected system and the results measured by energy comparison measurement were compared to verify the feasibility and effectivity of this correction method in improving the accuracy of spectral emissivity measurement.

  16. Measurements of L to M shell vacancy transfer probabilities for the elements in the atomic region 70 <= Z <= 92

    NASA Astrophysics Data System (ADS)

    Puri, S.; Mehta, D.; Chand, B.; Singh, Nirmal; Trehan, P. N.

    1993-05-01

    The probabilities for vacancy transfer from L to M shell, ¯gh LM, are deduced for 15 elements in the atomic region 70 ≤ Z ≤ 92 by measuring the M X-ray yields from the targets excited by 5.96 and 22.6 keV incident photons, i.e. below and above the L-edge of the elements and using the theoretical L and M shell photoionisation cross-sections. These results are compared with the theoretical values based on the relativistic Dirac-Hartree-Slater (RDHS) and the nonrelativistic approximate Herman-Skillman (AHS) calculations. From the comparison, it is concluded that the onset of L 1-L 3M 5 Coster-Kronig transition occurs at Z = 75 as predicted by the RDHS model based Coster-Kronig transition energy calculations.

  17. Demonstration of a mobile Flux Laboratory for the Atmospheric Measurement of Emissions (FLAME) to assess emissions inventories.

    PubMed

    Moore, Tim O; Doughty, David C; Marr, Linsey C

    2009-02-01

    The advancement of air quality science and the development of effective air quality management plans require accurate estimates of emissions. In response to the need for new approaches to quantifying emissions, we have designed a mobile Flux Lab for the Atmospheric Measurement of Emissions (FLAME) that uses eddy covariance for the direct measurement of anthropogenic emissions at the neighborhood scale. To demonstrate the FLAME's capabilities, we have deployed it in the Huntington-Ashland region at the borders of Ohio, Kentucky and West Virginia. This area routinely experiences high ozone and fine particulate matter (PM(2.5)) concentrations and is home to a significant amount of industrial activity, including coal storage and transport. Experiments focused on carbon dioxide (CO(2)), nitrogen oxides (NO(x)) and fine particulate matter (PM(2.5)). Spikes in CO(2) and NO(x) concentrations were correlated with the passage of trains and barges through the FLAME's footprint. Calculated barge emission factors ranged from 49 to 76 kg NO(x) tonne(-1) fuel and agreed well with previously published values. Fluxes measured at three sites in the town of Worthington were mainly positive. They ranged between -6.5 to 29 mg m(-2) s(-1) for CO(2) and -9.7 x 10(-5) to 9.1 x 10(-5) mg m(-2) s(-1) for PM(2.5). We illustrate how the measurements can be compared to emissions inventories on a per capita basis for greenhouse gases and countywide for other pollutants. The results show that a mobile eddy covariance system can be used successfully to measure fluxes of multiple pollutants in a variety of settings. This alternative method for estimating emissions can be a useful tool for assessing uncertainties in emissions inventories and for improving their accuracy.

  18. Can dust emission mechanisms be determined from field measurements?

    USDA-ARS?s Scientific Manuscript database

    Field observations are needed to develop and test theories on dust emission for use in dust modeling systems. The dust emission mechanism (aerodynamic entrainment, saltation bombardment, aggregate disintegration) as well as the amount and particle-size distribution of emitted dust may vary under sed...

  19. Estimating CH4 Emissions in California Using Measurements from a Tower Network

    NASA Astrophysics Data System (ADS)

    Jeong, S.; Hsu, Y.; Andrews, A. E.; Bianco, L.; Vaca, P.; Wilczak, J. M.; Fischer, M. L.

    2012-12-01

    We estimate regionally resolved methane (CH4) emissions for California using a Bayesian inverse model driven by CH4 mixing ratios measured at a network of five towers across the Central Valley during 2010 - 2011. The method estimates emissions by comparing measurements with transport model predictions of CH4 signals obtained from two 0.1 degree prior emission maps: 1) seasonally varying "California-specific" emission maps, calibrated to State emission totals, and 2) the EDGAR4.2 static global emission map. Atmospheric transport is calculated from particle trajectories and surface footprints using the Weather Research and Forecasting (WRF) and Stochastic Time-Inverted Lagrangian Transport (STILT) models. Results for the 5-tower CARB-CEC-LBNL-NOAA network show that significant reductions in posterior emissions uncertainty are obtained for regions comprising ~ 90% of California's known CH4 emissions, with annually averaged emissions totaling 1.6+/-0.1 and 2.5+/-0.3 times California's inventory for the California-specific and EDGAR4.2 emissions maps, respectively. Assuming these results apply across California, total CH4 emissions account for approximately 8% - 14% of current state total greenhouse gas emissions. The magnitude and uncertainty of emissions from specific regions and source sectors (e.g., crop agriculture, waste management, livestock, and energy activities) are estimated by comparing region and source sector results obtained with the CA-specific and EDGAR4.2 emission maps.

  20. Self-mixing vibration measurement using emission frequency sinusoidal modulation

    NASA Astrophysics Data System (ADS)

    Tao, Yufeng; Wang, Ming; Guo, Dongmei; Hao, Hui; Liu, Qiang

    2015-04-01

    In this paper, a simplified phase demodulation scheme is applied to recover vibration trail on a laser self-mixing interferometer for noncontact vibration measurement. The emission of semiconductor laser diode is modulated by injecting sinusoidal wave, and corresponding interference signal is a quasi-sinusoid wave. The vibration mathematical model for semiconductor laser diode is theoretically educed from basic self-mixing theory, the variation of target is converted into phase information. The simulation of demodulation algorithm and standard deviation are presented and the reconstructed waveform displays a desirable consistence with various moving trails. Following the principle, a minimum experimental system is established and position variation of the target mirror driven by voltage signal is translated into phase shifts, feedback is controlled at weak level during experiment, Fourier transform is implemented to analyze phase information. The comparisons of both amplitude and velocity with a Germany Doppler vibrometer are performed to testify vibration model, the error of proposed demodulation method is less than 30 nm and achieve a high accuracy in vibration frequency. The experimental results indicate the traditional phase technology can be applied on complex optical power signal after adaption providing a feasible application prospects in industrial and scientific situation with an inexpensive semiconductor laser.

  1. On-road remote sensing of petrol vehicle emissions measurement and emission factors estimation in Hong Kong

    NASA Astrophysics Data System (ADS)

    Chan, T. L.; Ning, Z.; Leung, C. W.; Cheung, C. S.; Hung, W. T.; Dong, G.

    In the present study, the real world on-road petrol vehicle emissions of carbon monoxide (CO), hydrocarbons (HC) and nitric oxide (NO) were investigated at nine sites in Hong Kong. A regression analysis approach based on the measured petrol vehicle emission data was also used to estimate the on-road petrol vehicle emission factors of CO, HC and NO with respect to the effects of instantaneous vehicle speed and acceleration/deceleration profiles for local urban driving patterns. The results show that the petrol vehicle model years, engine sizes and driving patterns have a strong correlation on their emission factors. A comparison of average petrol vehicle emission factors in different engine sizes and European vehicle emission standards was also presented. The deviation of the average emission factors of aggregate petrol vehicle reflects on the variability of local road condition, vehicle traffic fleet and volume, driving pattern, fuel composition and ambient condition etc. Finally, a unique database of the correlation of petrol vehicle emission factors on different model years and engine sizes for urban driving patterns in Hong Kong was established.

  2. Measurements of biogenic non-methane organic compound emissions from grasslands

    SciTech Connect

    Fukui, Yoshiko

    1994-12-31

    Non-methane organic compounds (NMOCs) play an important role in the formation of photochemical oxidants in the troposphere. NMOCs originate from both anthropogenic and biogenic sources. Many organic compounds of biogenic origins are more reactive than those of anthropogenic origin because of the presence of internal double bonds within their molecular structure. The objective of this investigation was to examine the seasonal variation of NMOC emissions from grasslands and determine the environmental factors that control the emissions. An enclosure system was chosen as the most appropriate sampling technique for measuring emissions from herbaceous vegetation, and an analysis method using cryogenic preconcentration/high resolution gas chromatography was established. Emission rates were measured at a fixed location in a natural grassland during 1992 and 1993. Measurements were also made at various locations within the same site where the vegetation was harvested after the emission rates were determined. Emission rates of NMOCs for grasslands are not as large as those reported for forests. However the emissions of oxygenated hydrocarbons exceeded the emissions of monoterpenes and have not previously been identified as important forest-type emissions. A framework for parameterizing the NMOC emissions from grasslands based on seasonal and instantaneous variations of the emission rate measurements was developed. Temperature, hypoxia induced by water saturated soil, and frost were key environmental factors affecting both the composition and magnitude of NMOC emissions.

  3. Impact of the β-Delayed Neutron Emission Probabilities Around A = 100-125 on the r-Process and the BRIKEN Project

    NASA Astrophysics Data System (ADS)

    Phong, H. Vi; Nishimura, Shunji; Lorusso, Giuseppe; Algora, Alejandro

    Recent observations of metal-poor Eu-enriched stars show large deviations in the abundance pattern of light elements with Z ≤ 47 suggesting the existence of a second type of r-process, called weak r-process, which has occurred besides the more robust main r-process. It is believed that Ag and Pd, the heaviest among light r-process elements, may help reveal the nature of the weak r-process. We present a sensitivity studies to clarify the role of the β-delayed neutron emission probabilities (Pn values) in shaping the final elemental abundance of Ag and Pd. We show that the uncertainty on the calculated abundance of those elements causedby the unknown Pn values is comparable with the their abundance deviations from star to star. The BRIKEN project, an experimental program at RIBF, has been proposed to study the beta decay properties of the nuclei relevant to the r-process. A brief introduction about the experimental setup will be presented.

  4. 40 CFR 86.1372-2007 - Measuring smoke emissions within the NTE zone.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 19 2011-07-01 2011-07-01 false Measuring smoke emissions within the... Exhaust Test Procedures § 86.1372-2007 Measuring smoke emissions within the NTE zone. This section contains the measurement techniques to be used for determining compliance with the filter smoke limit or...

  5. 40 CFR 86.1372-2007 - Measuring smoke emissions within the NTE zone.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Measuring smoke emissions within the... Exhaust Test Procedures § 86.1372-2007 Measuring smoke emissions within the NTE zone. This section contains the measurement techniques to be used for determining compliance with the filter smoke limit or...

  6. Odor and odorous chemical emissions from animal buildings: part 4-correlations between sensory and chemical measurements

    USDA-ARS?s Scientific Manuscript database

    This study supplemented the National Air Emissions Monitoring Study (NAEMS) with one year of comprehensive measurements of odor emission at five swine and four dairy buildings. The measurements included both standard human sensory measurements using dynamic forced-choice olfactometry and chemical an...

  7. Direct Continuous Measurements of Methane Emissions from a Landfill: Method, Station and Latest Results

    NASA Astrophysics Data System (ADS)

    Burba, G. G.; Xu, L.; Lin, X.; Amen, J.; Welding, K.; McDermitt, D. K.

    2014-12-01

    Solar-powered automated flux station was deployed continuously inside the Bluff Road Landfill (Lincoln, NE) for the period of over4 years starting June 2010. Landfill methane emissions were measured using the eddy covariance method, reporting hourly emission rates. The data shown in this presentation are from the period of June to December 2010 when no gas recovery was in operation. The continuous measurements of hourly emission rates allowed a number of important analyses of the key factors affecting landfill methane emissions at different time scales. In particular, the results show that landfill methane emissions strongly depended on changes in barometric pressure. Rising barometric pressure suppressed the emission, while falling barometric pressure enhanced the emission, resulting in up to a 35-fold variation in day-to-day methane emissions. Wavelet coherence analysis revealed a strong spectral coherency between variations of barometric pressure and methane emission at periodicities ranging from 1 day to 8 days. Power spectrum and ogive analysis showed that at least 10 days of continuous measurements was needed in order to capture 90% of the total variance in the methane emission time series at the site.From these results, it is apparent that point-in-time measurements taken at monthly or longer time intervals using techniques such as the trace plume method, the mass balance method, or the closed-chamber method will be subject to large variations in measured emission rates because of the barometric pumping phenomenon. Estimates of long-term integrated methane emissions based on such measurements could yield uncertainties, ranging from 28% underestimation to 32% overestimation.The results demonstrate a need for continuous measurements to quantify annual total landfill emissions. This conclusion may also apply to the wetlands, peatlands, lakes, and other environments where emissions are from porous media or ebullition.

  8. Molecular Emission and Temperature Measurements from Single-Bubble Sonoluminescence

    NASA Astrophysics Data System (ADS)

    Xu, Hangxun; Suslick, Kenneth S.

    2010-06-01

    Single-bubble sonoluminescence (SBSL) spectra in H2O show featureless continuum emission. From an acoustically driven, moving bubble in phosphoric acid (H3PO4), we observe very strong molecular emission from excited OH radicals (˜310nm), which can be used as a spectroscopic thermometer by fitting the experimental SBSL spectra to the OH AΣ+2-XΠ2 rovibronic transitions. The observed emission temperature (Tem) ranges from 6200 to 9500 K as the acoustic pressure (Pa) varies from 1.9 to 3.1 bar and from 6000 to >10000K as the dissolved monatomic gas varies over the series from He to Xe.

  9. Measurement of the double K-shell vacancy creation probability in the electron-capture decay of 55Fe with active-pixel detectors

    NASA Astrophysics Data System (ADS)

    Michel, Thilo; Bergmann, Benedikt; Durst, Jürgen; Filipenko, Mykaylo; Gleixner, Thomas; Zuber, Kai

    2014-01-01

    of emission of satellite and hypersatellite photons. Our result supports the suspicion that the reported discrepancy between PKK measured for the electron-capture decays of 54Mn and 55Fe was probably due to statistical fluctuations in the measurements. Furthermore, the Z-2 dependence of PKK predicted by Primakoff and Porter is supported. The improved statistical error of our measurements underlines the previously reported discrepancy between PKK expected for 65Zn if an extrapolation is carried out from our result on 55Fe. Thus, our result strengthens the need for triple coincidence measurements of PKK on 65Zn.

  10. PROBABILITY AND STATISTICS.

    DTIC Science & Technology

    STATISTICAL ANALYSIS, REPORTS), (*PROBABILITY, REPORTS), INFORMATION THEORY, DIFFERENTIAL EQUATIONS, STATISTICAL PROCESSES, STOCHASTIC PROCESSES, MULTIVARIATE ANALYSIS, DISTRIBUTION THEORY , DECISION THEORY, MEASURE THEORY, OPTIMIZATION

  11. Satellite measurements of daily variations in soil NOx emissions

    NASA Astrophysics Data System (ADS)

    Bertram, Timothy H.; Heckel, Andreas; Richter, Andreas; Burrows, John P.; Cohen, Ronald C.

    2005-12-01

    Soil NOx emission from agricultural regions in the western United States has been investigated using satellite observations of NO2 from the SCIAMACHY instrument. We show that the SCIAMACHY observations over a 2 million hectare agricultural region in Montana capture the short intense NOx pulses following fertilizer application and subsequent precipitation and we demonstrate that these variations can be reproduced by tuning the mechanistic parameters in an existing model of soil NOx emissions.

  12. Field measurements of dust emission from sand dunes

    NASA Astrophysics Data System (ADS)

    Huang, Y.; Kok, J. F.; Martin, R. L.; Turney, F. A.; Souza Freire, L.; Chamecki, M.

    2016-12-01

    Mineral dust affects Earth's radiation budget, the climate system, biogeochemistry, as well as human health. Model simulations of the global dust emission rate vary by a factor of 8, ranging from 500 to 4000 Tg/yr. A primary reason for these divergent model results is a lack of understanding of the exact sources and emission mechanism of dust. Regions containing soils with a large proportion of fine clay and silt particles, like topographic depressions, have long been treated as the primary source of mineral dust. However, recent remote sensing results suggest that sand dunes, which contain only a small fraction of fine dust, might be a major contributor to mineral dust emissions, and account for over 40% of North Africa dust storms. This makes it problematic that dust emissions from sand dunes are generally not accounted for in climate models. In order to evaluate the potential of sand dunes as an important global source of dust emissions, we conducted a field campaign at the Oceano sand dunes in California. Comparing with soils that contain a larger proportion of fine dust particles, the size distribution of sand dunes is finer, however vertical dust flux of sand dunes per unit horizontal sand saltation flux is smaller. This emission efficiency of sand dunes remains constant when shear velocity increases.

  13. Quantifying greenhouse-gas emissions from atmospheric measurements: a critical reality check for climate legislation.

    PubMed

    Weiss, Ray F; Prinn, Ronald G

    2011-05-28

    Emissions reduction legislation relies upon 'bottom-up' accounting of industrial and biogenic greenhouse-gas (GHG) emissions at their sources. Yet, even for relatively well-constrained industrial GHGs, global emissions based on 'top-down' methods that use atmospheric measurements often agree poorly with the reported bottom-up emissions. For emissions reduction legislation to be effective, it is essential that these discrepancies be resolved. Because emissions are regulated nationally or regionally, not globally, top-down estimates must also be determined at these scales. High-frequency atmospheric GHG measurements at well-chosen station locations record 'pollution events' above the background values that result from regional emissions. By combining such measurements with inverse methods and atmospheric transport and chemistry models, it is possible to map and quantify regional emissions. Even with the sparse current network of measurement stations and current inverse-modelling techniques, it is possible to rival the accuracies of regional 'bottom-up' emission estimates for some GHGs. But meeting the verification goals of emissions reduction legislation will require major increases in the density and types of atmospheric observations, as well as expanded inverse-modelling capabilities. The cost of this effort would be minor when compared with current investments in carbon-equivalent trading, and would reduce the volatility of that market and increase investment in emissions reduction.

  14. Estimation of fossil-fuel CO2 emissions using satellite measurements of "proxy" species

    NASA Astrophysics Data System (ADS)

    Konovalov, Igor B.; Berezin, Evgeny V.; Ciais, Philippe; Broquet, Grégoire; Zhuravlev, Ruslan V.; Janssens-Maenhout, Greet

    2016-11-01

    Fossil-fuel (FF) burning releases carbon dioxide (CO2) together with many other chemical species, some of which, such as nitrogen dioxide (NO2) and carbon monoxide (CO), are routinely monitored from space. This study examines the feasibility of estimation of FF CO2 emissions from large industrial regions by using NO2 and CO column retrievals from satellite measurements in combination with simulations by a mesoscale chemistry transport model (CTM). To this end, an inverse modeling method is developed that allows estimating FF CO2 emissions from different sectors of the economy, as well as the total CO2 emissions, in a given region. The key steps of the method are (1) inferring "top-down" estimates of the regional budget of anthropogenic NOx and CO emissions from satellite measurements of proxy species (NO2 and CO in the case considered) without using formal a priori constraints on these budgets, (2) the application of emission factors (the NOx-to-CO2 and CO-to-CO2 emission ratios in each sector) that relate FF CO2 emissions to the proxy species emissions and are evaluated by using data of "bottom-up" emission inventories, and (3) cross-validation and optimal combination of the estimates of CO2 emission budgets derived from measurements of the different proxy species. Uncertainties in the top-down estimates of the NOx and CO emissions are evaluated and systematic differences between the measured and simulated data are taken into account by using original robust techniques validated with synthetic data. To examine the potential of the method, it was applied to the budget of emissions for a western European region including 12 countries by using NO2 and CO column amounts retrieved from, respectively, the OMI and IASI satellite measurements and simulated by the CHIMERE mesoscale CTM, along with the emission conversion factors based on the EDGAR v4.2 emission inventory. The analysis was focused on evaluation of the uncertainty levels for the top-down NOx and CO emission

  15. On-road remote sensing of diesel vehicle emissions measurement and emission factors estimation in Hong Kong

    NASA Astrophysics Data System (ADS)

    Chan, T. L.; Ning, Z.

    In the present study, the real world on-road diesel vehicle emissions of carbon monoxide (CO), hydrocarbons (HC) and nitric oxide (NO) were investigated at nine sites in Hong Kong. A regression analysis approach based on the measured vehicle emission data was used to estimate the on-road diesel vehicle emission factors of CO, HC and NO with respect to the effects of instantaneous vehicle speed and acceleration/deceleration profiles for local urban driving patterns. The results show that the diesel vehicle model years, engine sizes, vehicle types and driving patterns have a strong correlation with their emission factors. A comparison was made between the average diesel and petrol vehicle emissions factors in Hong Kong. The deviation of the average emission factors of aggregate diesel vehicles reflects the variability of local road condition, vehicle traffic fleet and volume, driving pattern, fuel composition and ambient condition etc. Finally, a unique database of the correlation of diesel vehicle emission factors (i.e., g km -1 and g l -1) on different model years and vehicle types for urban driving patterns in Hong Kong was established.

  16. Control of odour emission in wastewater treatment plants by direct and undirected measurement of odour emission capacity.

    PubMed

    Zarra, T; Giuliani, S; Naddeo, V; Belgiorno, V

    2012-01-01

    Odour emissions from wastewater treatment plants (WWTPs) are considered to be the main causes of disturbance noticed by the exposed population and have relevant impacts on both tourism economy and land costs. Odour impact from WWTPs is generated by primary and secondary odour emissions. Primary odour emissions are related especially to the wastewater type and variability discharged into the sewer and directed to the WWTP, and to the wastewater collection and sewage system. Secondary odours are related to the treatment units of the plant. Several studies describe the key role of primary odour emissions and how they are strongly related to odour impacts of WWTPs. In this way, a opportune characterization of the emission capacity of primary odour could be an effective way to control odour emission in the WWTPs. In this study the odour emission capacity (OEC) of different domestic sewers was described and investigated; a correlation between the OEC and the main physical-chemical parameters of wastewater quality was also carried out. Results of this study identify the optimum conditions for sampling and measuring OEC in wastewaters and define its dependence by wastewater quality. These results can contribute to setting the standards for the maximum odourant content of wastewater that are discharged into the publicly owned sewage system.

  17. Volatile organic compound concentrations and emission rates measured over one year in a new manufactured house

    SciTech Connect

    Hodgson, Alfred T.; Nabinger, Steven J.; Persily, Andrew K.

    2004-09-01

    A study to measure indoor concentrations and emission rates of volatile organic compounds (VOCs), including formaldehyde, was conducted in a new, unoccupied manufactured house installed at the National Institute of Standards and Technology (NIST) campus. The house was instrumented to continuously monitor indoor temperature and relative humidity, heating and air conditioning system operation, and outdoor weather. It also was equipped with an automated tracer gas injection and detection system to estimate air change rates every 2 h. Another automated system measured indoor concentrations of total VOCs with a flame ionization detector every 30 min. Active samples for the analysis of VOCs and aldehydes were collected indoors and outdoors on 12 occasions from August 2002 through September 2003. Individual VOCs were quantified by thermal desorption to a gas chromatograph with a mass spectrometer detector (GC/MS). Formaldehyde and acetaldehyde were quantified by high performance liquid chromatography (HPLC). Weather conditions changed substantially across the twelve active sampling periods. Outdoor temperatures ranged from 7 C to 36 C. House air change rates ranged from 0.26 h{sup -1} to 0.60 h{sup -1}. Indoor temperature was relatively constant at 20 C to 24 C for all but one sampling event. Indoor relative humidity (RH) ranged from 21% to 70%. The predominant and persistent indoor VOCs included aldehydes (e.g., formaldehyde, acetaldehyde, pentanal, hexanal and nonanal) and terpene hydrocarbons (e.g., a-pinene, 3-carene and d-limonene), which are characteristic of wood product emissions. Other compounds of interest included phenol, naphthalene, and other aromatic hydrocarbons. VOC concentrations were generally typical of results reported for other new houses. Measurements of total VOCs were used to evaluate short-term changes in indoor VOC concentrations. Most of the VOCs probably derived from indoor sources. However, the wall cavity was an apparent source of

  18. Validating modelled carbon-dioxide emissions against long-term eddy-covariance measurements at the urban neighborhood-scale

    NASA Astrophysics Data System (ADS)

    Christen, A.; Coops, N. C.; Crawford, B.; Heyman, E.; Kellett, R.; Liss, K.; Oke, T. R.; Olchovski, I.; Tooke, R.; van der Laan, M.; Voogt, J. A.

    2010-12-01

    -flux data are available for a two-year period. Modelled and measured emissions agree within 11% with 6.71 kg C m-2 year-1 measured vs. 7.11 kg C m-2 year-1 modeled, and show more substantial differences in wind sectors dominated by traffic emissions probably due an oversimplified transportation model. Observed, and projected transportation sector emissions were shown to be 42% less on weekends than weekdays in the study area. The presentation concludes that direct CO2 flux measurements from urban flux towers are a promising method to independently validate fine-scale emission inventories. However it will be also noted that - if considering all processes that are part of an ‘urban metabolism’ - effects that take place beyond the study area’s limits there is a conceptual discrepancy between localized tower measurements and the carbon ‘footprint’ of urban activities.

  19. On-board measurements of emissions from diesel trucks in five cities in China

    NASA Astrophysics Data System (ADS)

    Huo, Hong; Yao, Zhiliang; Zhang, Yingzhi; Shen, Xianbao; Zhang, Qiang; He, Kebin

    2012-07-01

    This paper, which focuses on diesel trucks, is the third in a series of three papers published in Atmospheric Environment to understand vehicle emissions in China by conducting on-board emission measurements. Diesel trucks are a significant source of emissions in ambient air, especially for NOx. Recently, China announces an aggressive target to reduce national NOx emissions by 10% from 2010 to 2015 in the "Twelfth Five-Year Plan (2011-2015)" and diesel vehicles are identified as a key target for NOx control. However, the understanding of the real-world emissions of diesel trucks is limited. In this study, we measured HC, CO, NOx, and PM2.5 emissions from 175 diesel trucks of different sizes and technologies in five Chinese cities during 2007 and 2011, and generated emission factors on the basis of the measurements. The results show that the HC, CO, and PM2.5 emission factors have been reduced significantly as the emission standards become more stringent from Euro 0 to Euro IV, but the NOx emission factors change differently. Euro II trucks have 3-6% higher NOx emission levels than Euro I technologies and Euro III trucks fail to show a reduction as regulated by the standards. More stringent NOx requirements (e.g. Euro IV) for diesel vehicles need to be enforced. The comparison with the emission factors used in recent emission inventory studies shows that these inventories may have overestimated or underestimated diesel emissions for the years after 2006. This study emphasizes the importance of conducting local measurement research to improve the accuracy of the estimates of mobile emissions in China.

  20. Passive emission colorimetric sensor (PECS) for measuring emission rates of formaldehyde based on an enzymatic reaction and reflectance photometry.

    PubMed

    Shinohara, Naohide; Kajiwara, Tomohisa; Ohnishi, Masato; Kodama, Kenichi; Yanagisawa, Yukio

    2008-06-15

    A coin-sized passive emission colorimetric sensor (PECS) based on an enzymatic reaction and a portable reflectance photometry device were developed to determine the emission rates of formaldehyde from building materials and other materials found indoors in only 30 minutes on-site. The color change of the PECS linearly correlated to the concentration of formaldehyde aqueous solutions up to 28 microg/mL. The correlation between the emission rates measured by using the PECS and those measured by using a desiccator method or by using a chamber method was fitted with a linear function and a power function, and the determination coefficients were more than 0.98. The reproducible results indicate that the emission rates could be obtained with the correlation equations from the data measured by using the PECS and the portable reflectance photometry device. Limits of detection (LODs) were 0.051 mg/L for the desiccator method and 3.1 microg/m2/h for the chamber method. Thus, it was confirmed that the emission rates of formaldehyde from the building materials classified as F four-star (< 0.3 mg/L (desiccator method) or < 5.0 microg/m2/h (chamber method)), based on Japanese Industrial Standards (JIS), could be measured with the PECS. The measurement with PECS was confirmed to be precise (RSD < 10%). Other chemicals emitted from indoor materials, such as methanol, ethanol, acetone, toluene, and xylene, interfered little with the measurement of formaldehyde emission rates by using the PECS.

  1. Methods for Measuring and Estimating Methane Emission from Ruminants

    PubMed Central

    Storm, Ida M. L. D.; Hellwing, Anne Louise F.; Nielsen, Nicolaj I.; Madsen, Jørgen

    2012-01-01

    Simple Summary Knowledge about methods used in quantification of greenhouse gasses is currently needed due to international commitments to reduce the emissions. In the agricultural sector one important task is to reduce enteric methane emissions from ruminants. Different methods for quantifying these emissions are presently being used and others are under development, all with different conditions for application. For scientist and other persons working with the topic it is very important to understand the advantages and disadvantage of the different methods in use. This paper gives a brief introduction to existing methods but also a description of newer methods and model-based techniques. Abstract This paper is a brief introduction to the different methods used to quantify the enteric methane emission from ruminants. A thorough knowledge of the advantages and disadvantages of these methods is very important in order to plan experiments, understand and interpret experimental results, and compare them with other studies. The aim of the paper is to describe the principles, advantages and disadvantages of different methods used to quantify the enteric methane emission from ruminants. The best-known methods: Chambers/respiration chambers, SF6 technique and in vitro gas production technique and the newer CO2 methods are described. Model estimations, which are used to calculate national budget and single cow enteric emission from intake and diet composition, are also discussed. Other methods under development such as the micrometeorological technique, combined feeder and CH4 analyzer and proxy methods are briefly mentioned. Methods of choice for estimating enteric methane emission depend on aim, equipment, knowledge, time and money available, but interpretation of results obtained with a given method can be improved if knowledge about the disadvantages and advantages are used in the planning of experiments. PMID:26486915

  2. Monoterpene emission rate measurements from a Monterey pine

    SciTech Connect

    Juuti, S. ); Arey, J.; Atkinson, R. )

    1990-05-20

    The monoterpenes emitted from a Monterey pine (pinus radiata) were investigated using a dynamic flow-through enclosure technique. The monoterpenes identified and quantified were {alpha}- and {beta}-pinene, d-limonene + {beta} phellandrene, myrcene, camphene and {Delta}{sup 3}-carene, with {alpha}- and {beta}-pinene accounting for over 80% of the total monoterpene emissions. The monoterpene emission rate increased with temperature, in good agreement with previous data for other coniferous species. The absence of added CO{sub 2} to the synthetic air flow stream, exposure to elevated levels (300-500 ppb mixing ratio) of O{sub 3} for 3-4 hours, and increased air movement within the enclosure, had no observable effect on the monoterpene emission rate at a given temperature. In contrast, rough handling of the pine during the sampling protocol resulted in increases in the monoterpene emission rate by factors of 10-50. These results will be useful to those designing enclosure sampling protocols for the determination of the emission rates of biogenic organic compounds from vegetation.

  3. Molecular emission and temperature measurements from single-bubble sonoluminescence.

    PubMed

    Xu, Hangxun; Suslick, Kenneth S

    2010-06-18

    Single-bubble sonoluminescence (SBSL) spectra in H2O show featureless continuum emission. From an acoustically driven, moving bubble in phosphoric acid (H3PO4), we observe very strong molecular emission from excited OH radicals (∼310  nm), which can be used as a spectroscopic thermometer by fitting the experimental SBSL spectra to the OH A 2Σ+ - X 2Π rovibronic transitions. The observed emission temperature (T(em)) ranges from 6200 to 9500 K as the acoustic pressure (P(a)) varies from 1.9 to 3.1 bar and from 6000 to >10,000  K as the dissolved monatomic gas varies over the series from He to Xe.

  4. Apparatus for Measuring Spectral Emissivity of Solid Materials at Elevated Temperatures

    NASA Astrophysics Data System (ADS)

    Ren, Dengfeng; Tan, Hong; Xuan, Yimin; Han, Yuge; Li, Qiang

    2016-05-01

    Spectral emissivity measurements at high temperature are of great importance for both scientific research and industrial applications. A method to perform spectral emissivity measurements is presented based on two sample heating methods, the flat plate and tubular furnace. An apparatus is developed to measure the normal spectral emissivity of solid material at elevated temperatures from 1073 K to 1873 K and wavelengths from 2 \\upmu hbox {m} to 25 \\upmu hbox {m}. Sample heating is accomplished by a torch flame or a high temperature furnace. Two different variable temperature blackbody sources are used as standard references and the radiance is measured by a FTIR spectrometer. Following calibration of the spectral response and background radiance of the spectrometer, the effect of the blackbody temperature interval on calibration results is discussed. Measurements are performed of the normal spectral emissivity of SiC and graphite over the prescribed temperature and wavelength range. The emissivity of SiC at high temperatures is compared with the emissivity at room temperature, and the influence of an oxide layer formed at the surface of SiC on the emissivity is studied. The effect of temperature on the emissivity of graphite is also investigated. Furthermore, a thorough analysis of the uncertainty components of the emissivity measurement is performed.

  5. Airborne Methane Emission Measurements for Selected Oil and Gas Facilities Across California.

    PubMed

    Mehrotra, Shobhit; Faloona, Ian C; Suard, Maxime; Conley, Stephen A; Fischer, Marc L

    2017-10-11

    We report 65 individual measurements of methane emissions from 24 oil & gas facilities across California. Methane emission rates were estimated using in-situ methane and wind velocity measurements from a small aircraft by a novel Gauss' Theorem flux integral approach. The estimates are compared with annual mean emissions reported to the US-EPA and the California Air Resources Board (CARB) through their respective greenhouse gas reporting programs. The average emissions from 36 measurements of 10 gas storage facilities were within a factor of 2 of emissions reported to US-EPA or CARB, though large variance was observed and the reporting database did not contain all of the facilities. In contrast, average emissions from 15 measurements of the three refineries were roughly an order of magnitude more than reported to the US-EPA or CARB. The remaining measurements suggest compressor emissions are variable and perhaps slightly larger than reported, and emissions from one oil production facility were roughly concordant with a separate (not GHG reporting) bottom-up estimate from other work. Together, these results provide an initial facility-specific survey of methane emissions from California oil and natural gas infrastructure with observed variability suggesting the need for expanded measurements in the future.

  6. Comparison of in-situ measurements and satellite-derived surface emissivity over Italian volcanic areas

    NASA Astrophysics Data System (ADS)

    Silvestri, Malvina; Musacchio, Massimo; Cammarano, Diego; Fabrizia Buongiorno, Maria; Amici, Stefania; Piscini, Alessandro

    2016-04-01

    In this work we compare ground measurements of emissivity collected during dedicated fields campaign on Mt. Etna and Solfatara of Pozzuoli volcanoes and acquired by means of Micro-FTIR (Fourier Thermal Infrared spectrometer) instrument with the emissivity obtained by using single ASTER data (Advanced Spaceborne Thermal Emission and Reflection Radiometer, ASTER 05) and the ASTER emissivity map extract from ASTER Global Emissivity Database (GED), released by LP DAAC on April 2, 2014. The database was developed by the National Aeronautics and Space Administration's (NASA) Jet Propulsion Laboratory (JPL), California Institute of Technology. The database includes land surface emissivity derived from ASTER data acquired over the contiguous United States, Africa, Arabian Peninsula, Australia, Europe, and China. Through this analysis we want to investigate the differences existing between the ASTER-GED dataset (average from 2000 to 2008 seasoning independent) and fall in-situ emissivity measurement. Moreover the role of different spatial resolution characterizing ASTER and MODIS, 90mt and 1km respectively, by comparing them with in situ measurements, is analyzed. Possible differences can be due also to the different algorithms used for the emissivity estimation, Temperature and Emissivity Separation algorithm for ASTER TIR band( Gillespie et al, 1998) and the classification-based emissivity method (Snyder and al, 1998) for MODIS. Finally land surface temperature products generated using ASTER-GED and ASTER 05 emissivity are also analyzed. Gillespie, A. R., Matsunaga, T., Rokugawa, S., & Hook, S. J. (1998). Temperature and emissivity separation from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) images. IEEE Transactions on Geoscience and Remote Sensing, 36, 1113-1125. Snyder, W.C., Wan, Z., Zhang, Y., & Feng, Y.-Z. (1998). Classification-based emissivity for land surface temperature measurement from space. International Journal of Remote Sensing, 19

  7. Spatially resolved measurement of Ar excited species in magnetized inductively coupled plasma using multi-port optical emission spectroscopy

    NASA Astrophysics Data System (ADS)

    Kim, Yun-Gi; Ha, Chang-Seung; Han, Moon-Ki; Seo, Kwon-Sang; Kim, Dong-Hyun; Lee, Hae June; Lee, Ho-Jun; Koo, Il Gyo; Lee, Soojin; Seong, Hyo-Seong

    2013-09-01

    Optical emission spectrometry (OES), which is the spectral analysis of the light emanating from plasma, is probably the most widely used method for monitoring and diagnosis of plasma processes. This technique has the advantage of being external to the reactor and vacuum system. However, the OES method is limited to measure spatial distribution of species accurately. In this work, multi-port optical emission spectroscopy system was developed to improve the space-resolved ability. This multi-port OES system consists of Si wafers, optical fibers, prisms and windows. The Si wafers are used for making the same condition while this device is put in the etching or deposition reactor. The emission light from plasma is collected and transferred through the optical fibers. The spatial distribution of Ar excited species is measured using this device in inductively coupled plasma with and without external axial magnetic field. The off-axis density profile of electron, Ar ion and excited species are appeared in weakly magnetized inductively coupled plasma. Also the emission intensity was changed in this experimental condition. Two-dimensional simulation was studied to verify this experimental result. This was supported by SEMES cooperative research project.

  8. 40 CFR Appendix IV to Part 92 - Guidelines for Determining Equivalency Between Emission Measurement Systems

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Between Emission Measurement Systems IV Appendix IV to Part 92 Protection of Environment ENVIRONMENTAL... Emission Measurement Systems This appendix describes a series of correlation criteria that EPA considers to... guidelines. When requested to make a finding of equivalency, EPA could base its decision on criteria...

  9. Automated, low-power chamber system for measuring nitrous oxide emissions

    USDA-ARS?s Scientific Manuscript database

    Continuous measurement of soil emissions is needed to constrain estimates of N2O loss to the atmosphere. Here, we describe the performance of a low-power, automated chamber system that can continuously measure N2O soil emissions, powered by wind and solar power. Laboratory testing of the Teledyne N2...

  10. Measurement of Opacity and Particulate Emissions With an On-Stack Transmissometer

    ERIC Educational Resources Information Center

    Beutner, Heinz P.

    1974-01-01

    An on-stack transmissometer system, that is designed to provide a precision measurement of the opacity of visible emissions, is described. The sources of error in opacity measurements with regard to recent Environmental Protection Agency emission monitoring requirements and planned specifications are discussed. (Author/BT)

  11. 40 CFR 87.64 - Sampling and analytical procedures for measuring gaseous exhaust emissions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Sampling and analytical procedures for measuring gaseous exhaust emissions. 87.64 Section 87.64 Protection of Environment ENVIRONMENTAL PROTECTION....64 Sampling and analytical procedures for measuring gaseous exhaust emissions. (a) The system...

  12. Odor and odorous chemical emissions from animal buildings: Part 4 - correlations between sensory and chemical measurements

    USDA-ARS?s Scientific Manuscript database

    This study supplemented the National Air Emissions Monitoring Study (NAEMS) by making comprehensive measurements, over a full calendar year, of odor emissions from five swine and four dairy rooms/buildings (subset of the total number of buildings monitored for the NAEMS project). The measurements ma...

  13. 14 CFR 34.64 - Sampling and analytical procedures for measuring gaseous exhaust emissions.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 14 Aeronautics and Space 1 2012-01-01 2012-01-01 false Sampling and analytical procedures for measuring gaseous exhaust emissions. 34.64 Section 34.64 Aeronautics and Space FEDERAL AVIATION... Turbine Engines) § 34.64 Sampling and analytical procedures for measuring gaseous exhaust emissions. The...

  14. 14 CFR 34.82 - Sampling and analytical procedures for measuring smoke exhaust emissions.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 14 Aeronautics and Space 1 2012-01-01 2012-01-01 false Sampling and analytical procedures for measuring smoke exhaust emissions. 34.82 Section 34.82 Aeronautics and Space FEDERAL AVIATION ADMINISTRATION... Sampling and analytical procedures for measuring smoke exhaust emissions. The system and procedures for...

  15. On-Road Measurement of Exhaust Emission Factors for Individual Diesel Trucks

    NASA Astrophysics Data System (ADS)

    Dallmann, T. R.; DeMartini, S.; Harley, R. A.; Kirchstetter, T. W.; Wood, E. C.; Onasch, T. B.; Herndon, S. C.

    2011-12-01

    Diesel trucks are an important source of primary fine particulate matter (PM2.5) that includes black carbon (BC) as a major component. More stringent exhaust emission standards for new engines, effective starting in 2007, considerably reduce allowable emissions and have led to use of after-treatment control devices such as diesel particle filters. The state of California is also implementing programs to accelerate replacement or retrofit of older trucks. In light of these changes, measurements of emissions from in-use heavy-duty diesel trucks are timely and needed to understand the impact of new control technologies on emissions. PM2.5, BC mass, particle light absorption, and particle light extinction emission factors for hundreds of individual diesel trucks were measured in this study. Emissions were measured in July 2010 from trucks driving through the Caldecott tunnel in the San Francisco Bay area. Gas-phase emissions including nitric oxide, nitrogen dioxide, carbon monoxide, and carbon dioxide (CO2) were also measured. Pollutants were measured using air sampling inlets located directly above the vertical exhaust stacks of heavy-duty trucks driving by on the roadway below. All of these measurements were made using fast time response (1 Hz) sensors. Particle optical properties were simultaneously characterized with direct measurements of absorption (babs) and extinction (bext) coefficients. Emission factors for individual trucks were calculated using a carbon balance method in which emissions of PM2.5, BC, babs, and bext in each exhaust plume were normalized to emissions of CO2. Emission factor distributions and fleet-average values are quantified. Absorption and extinction emission factors are used to calculate the aerosol single scattering albedo and BC mass absorption efficiency for individual truck exhaust plumes.

  16. Biomass burning emissions over northern Australia constrained by aerosol measurements: I—Modelling the distribution of hourly emissions

    NASA Astrophysics Data System (ADS)

    Meyer, C. P. (Mick); Luhar, Ashok K.; Mitchell, Ross M.

    Emissions of aerosol from biomass burning in northern Australia are globally significant, yet existing estimates of their magnitude are essentially unconstrained by observation. This two-part series (see Part II by Luhar et al. [2008. Biomass burning emissions over northern Australia constrained by aerosol measurements: II—Model validation, and impacts on air quality and radiative forcing. Atmospheric Environment, submitted for publication] seeks to address this by first formulating a scheme to determine the emissions from the Top End region of the Northern Territory during the 2004 burning season at a high temporal and spatial resolution (1 h, 1 km). The emissions are then validated using a meteorological and transport model called TAPM coupled with a variety of field measurements. The high resolution not only enables validation against various meteorological and aerosol data sets, but also allows prediction of local air quality events. Essential inputs to the emission calculations are satellite-based measurements of fire scars, yielding burnt areas, and hotspots, providing timing information on daily basis. It is shown that hotspots without associated fire scars must be taken into account in order to produce credible aerosol fields. Prediction of emissions at hourly time resolution is enabled by assigning a diurnal variation based on a McArthur fire danger meter. The total carbon emission for the 2004 season is computed to be 67.6 Tg, in remarkable agreement with the bulk estimate of 64.3 Tg derived for the Australian National Greenhouse Gas Inventory, and comparable to the figure of 57.0 Tg determined from the Global Fire Emissions Database (GFEDv2). The total PM 2.5 (particulate matter with an aerodynamic diameter of 2.5 μm or less) emission is computed to be 0.67 Tg. The transport modelling shows that emissions leaving the study region are largely advected to the west over the Timor Sea towards the Indonesian archipelago from April to September, shifting to

  17. Validation of emission inventories by measurements of ambient volatile organic compounds in Beijing, China

    NASA Astrophysics Data System (ADS)

    Wang, M.; Shao, M.; Chen, W.; Yuan, B.; Lu, S.; Zhang, Q.; Zeng, L.; Wang, Q.

    2013-10-01

    Understanding the sources of volatile organic compounds (VOCs) is essential for ground-level ozone and secondary organic aerosols (SOA) abatement measures. We made measurements at 28 sites and online observations at an urban site in Beijing from July 2009 to January 2012. From these we determined the spatial and temporal distributions of VOCs, estimated their annual emission strengths based on their emission ratios relative to CO, and quantified the relative contributions of various sources using the chemical mass balance (CMB) model. The results from ambient measurements were compared with existing emission inventories to evaluate the spatial distribution, species-specific emissions, and source structure of VOCs. The measured VOC distributions revealed a hotspot in the southern suburban area of Beijing, whereas current emission inventories suggested that VOC emissions were concentrated in downtown areas. Compared with results derived from ambient measurements, the annual inventoried emissions of oxygenated VOC (OVOC) species and C2-C4 alkanes might be underestimated, while the emissions of styrene and 1,3-butadiene might be overestimated by current inventories. Source apportionment using the CMB model identified vehicular exhaust as the most important VOC source, contributing 46%, in good agreement with the 40-51% assumed by emission inventories. However, the relative contribution of solvent and paint usage obtained from the CMB model was only 5%, significantly lower than the values reported by emission inventories (14-32%). Meanwhile, the relative contribution of industrial processes calculated using the CMB model was 17%, slightly higher than that in emission inventories. These results suggested that VOCs emission strengths in southern suburban area of Beijing, annual emissions of alkenes and OVOCs, and the contributions of solvent and paint usage and industrial processes in current inventories, all require significant revision.

  18. Substituting EMC emission measurement by field and cable scan method using measured transfer function

    NASA Astrophysics Data System (ADS)

    Rinas, D.; Jia, J.; Zeichner, A.; Frei, S.

    2013-07-01

    Today EMC emissions of automotive components are often measured in anechoic chambers by an antenna at fixed position according to CISPR 25 (ALSE-method). The antenna voltage often cannot sufficiently describe the behaviour of the measured electronic components and systems. Furthermore space requirements and costs are very high for the ALSE-method. Field- and cable-scan methods combined with near-field to far-field transformation techniques might be a good alternative. Residual reflections from the walls, the metallic floor, the measuring table, interaction of the antenna with the environment, and other factors affect the measurements. Thus, models which only regard the current distribution for near- and far field calculation cannot produce results equal to a chamber measurement. In this paper methods for computing transfer functions for the substitution of EMC antenna measurements with field- and cable scans in a specified calibration area are introduced. To consider influences of the environment, the environment is characterized in a first step and included with transfer functions in the calculation process for the equivalent ALSE-field.

  19. A fast multichannel Martin-Puplett interferometer for electron cyclotron emission measurements on JET

    SciTech Connect

    Simonetto, A.; Sozzi, C.; Garavaglia, S.; Nowak, S.; Fessey, J. A.; Collaboration: JET-EFDA Contributors

    2011-11-15

    A Martin Puplett interferometer for electron cyclotron emission (ECE) measurements from JET tokamak plasmas was extended to multichannel operation for simultaneous radial and oblique ECE measurements. This paper describes the new optics and the instrument's performance.

  20. Design Parameter Studies of Emission-Based Iron Opacity Measurements

    NASA Astrophysics Data System (ADS)

    Martin, Madison E.; London, Richard A.; Goluoglu, Sedat; Whitley, Heather D.

    2016-10-01

    Opacity is a critical parameter in the transport of radiation in systems such as inertial confinement fusion capsules and stars. The resolution of current disagreements between solar models and helioseismological observations would benefit from experimental validation of theoretical opacity models. Short pulse lasers can be used to heat targets to higher temperatures and densities than long pulse lasers and pulsed power machines, thus potentially enabling access to x-ray emission spectra at conditions relevant to solar models. The radiation-hydrodynamic code HYDRA is used to investigate the effects of modifying laser energy, laser pulse length, and target dimensions on the plasma conditions, x-ray emission, and inferred opacity of a buried layer iron target. The accuracy of the opacity inference is sensitive to tamper emission and optical depth effects. An example design that reaches temperatures and densities relevant to the radiative zone of the sun while reducing optical depth and tamper emission effects will be discussed. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. Lawrence Livermore National Security, LLC.

  1. Measuring Emissions of Volatile Organic Compounds from Silage

    USDA-ARS?s Scientific Manuscript database

    Volatile organic compound (VOC) emissions are considered to be important precursors to smog and ozone production. An experimental protocol was developed to obtain undisturbed silage samples from silage storages. Samples were placed in a wind tunnel where temperature, humidity, and air flow were cont...

  2. Measurement and Modeling of Volatile Particle Emissions from Military Aircraft

    DTIC Science & Technology

    2011-10-01

    distribution of the emissions. The smog chamber experiments demonstrated that photo-oxidation creates substantial secondary particulate matter, greatly...19 Dilution sampler.................................................................................................. 19 Smog chamber...The T63 engine test cell was located inside the building. The smog chamber and other sampling equipment were located outside

  3. Investigating seasonal methane emissions in Northern California using airborne measurements and inverse modeling

    NASA Astrophysics Data System (ADS)

    Johnson, Matthew S.; Xi, Xin; Jeong, Seongeun; Yates, Emma L.; Iraci, Laura T.; Tanaka, Tomoaki; Loewenstein, Max; Tadić, Jovan M.; Fischer, Marc L.

    2016-11-01

    Seasonal methane (CH4) emissions in Northern California are evaluated during this study by using airborne measurement data and inverse model simulations. This research applies Alpha Jet Atmospheric eXperiment (AJAX) measurements obtained during January-February 2013, July 2014, and October-November 2014 over the San Francisco Bay Area (SFBA) and northern San Joaquin Valley (SJV) in order to constrain seasonal CH4 emissions in Northern California. The California Greenhouse Gas Emissions Measurement (CALGEM) a priori emission inventory was applied in conjunction with the Weather Research and Forecasting and Stochastic Time-Inverted Lagrangian Transport model and inverse modeling techniques to optimize CH4 emissions. Comparing model-predicted CH4 mixing ratios with airborne measurements, we find substantial underestimates suggesting that CH4 emissions were likely larger than the year 2008 a priori CALGEM emission inventory in Northern California. Using AJAX measurements to optimize a priori emissions resulted in CH4 flux estimates from the SFBA/SJV of 1.77 ± 0.41, 0.83 ± 0.31, and 1.06 ± 0.39 Tg yr-1 when using winter, summer, and fall flight data, respectively. Averaging seasonal a posteriori emission estimates (weighted by posterior uncertainties) results in SFBA/SJV annual CH4 emissions of 1.28 ± 0.38 Tg yr-1. A posteriori uncertainties are reduced more effectively in the SFBA/SJV region compared to state-wide values indicating that the airborne measurements are most sensitive to emissions in this region. A posteriori estimates during this study suggest that dairy livestock was the source with the largest increase relative to the a priori CALGEM emission inventory during all seasons.

  4. On the potential of redox potential measurements for the characterization of greenhouse gas emissions - preliminary results

    NASA Astrophysics Data System (ADS)

    Wang, Jihuan; Bogena, Heye; Brüggemann, Nicolas

    2017-04-01

    Soil greenhouse gas (GHG) emissions contribute to global warming. In order to support mitigation measures against global warming it is important to understand the controlling processes of GHG emissions. Previous studies focused mainly on the paddy rice fields or wetlands showed a strong relationship between soil redox potential and GHG emission (e.g. N2O). Recent sensor developments open the possibility for the long-term monitoring of field scale soil redox potential changes. Here, we performed laboratory lysimeter experiments to investigate how changes in the redox potential, induced by changes in the water level, affect GHG emissions from agricultural soil. Under our experimental conditions, we found that N2O emissions followed closely the changes in redox potential. The dynamics of redox potential were induced by changing the water-table depth in a laboratory lysimeter. During saturated conditions we found a clear negative correlation between redox potentials and N2O emission rates N2O. After switching from saturated to unsaturated conditions, N2O emission quickly decreased. In contrast, the emissions of CO2 increased with increasing soil redox potentials. The level of N2O emission also depended on the fertilization level of the soil. We propose that redox potential measurements are a viable method for better understanding of the controlling factors of GHG emission and the development agricultural management practices to reduce such emissions.

  5. The CU 2-D-MAX-DOAS instrument - Part 2: Raman scattering probability measurements and retrieval of aerosol optical properties

    NASA Astrophysics Data System (ADS)

    Ortega, Ivan; Coburn, Sean; Berg, Larry K.; Lantz, Kathy; Michalsky, Joseph; Ferrare, Richard A.; Hair, Johnathan W.; Hostetler, Chris A.; Volkamer, Rainer

    2016-08-01

    The multiannual global mean of aerosol optical depth at 550 nm (AOD550) over land is ˜ 0.19, and that over oceans is ˜ 0.13. About 45 % of the Earth surface shows AOD550 smaller than 0.1. There is a need for measurement techniques that are optimized to measure aerosol optical properties under low AOD conditions. We present an inherently calibrated retrieval (i.e., no need for radiance calibration) to simultaneously measure AOD and the aerosol phase function parameter, g, based on measurements of azimuth distributions of the Raman scattering probability (RSP), the near-absolute rotational Raman scattering (RRS) intensity. We employ radiative transfer model simulations to show that for solar azimuth RSP measurements at solar elevation and solar zenith angle (SZA) smaller than 80°, RSP is insensitive to the vertical distribution of aerosols and maximally sensitive to changes in AOD and g under near-molecular scattering conditions. The University of Colorado two-dimensional Multi-AXis Differential Optical Absorption Spectroscopy (CU 2-D-MAX-DOAS) instrument was deployed as part of the Two Column Aerosol Project (TCAP) at Cape Cod, MA, during the summer of 2012 to measure direct sun spectra and RSP from scattered light spectra at solar relative azimuth angles (SRAAs) between 5 and 170°. During two case study days with (1) high aerosol load (17 July, 0.3 < AOD430 < 0.6) and (2) near-molecular scattering conditions (22 July, AOD430 < 0.13) we compare RSP-based retrievals of AOD430 and g with data from a co-located CIMEL sun photometer, Multi-Filter Rotating Shadowband Radiometer (MFRSR), and an airborne High Spectral Resolution Lidar (HSRL-2). The average difference (relative to DOAS) for AOD430 is +0.012 ± 0.023 (CIMEL), -0.012 ± 0.024 (MFRSR), -0.011 ± 0.014 (HSRL-2), and +0.023 ± 0.013 (CIMELAOD - MFRSRAOD) and yields the following expressions for correlations between different instruments

  6. FIELD MEASUREMENT OF GREENHOUSE GAS EMISSION RATES AND DEVELOPMENT OF EMISSION FACTORS FOR WASTEWATER TREATMENT

    EPA Science Inventory

    The report gives results of field testing to develop more reliable green house gas (GHG) emission estimates for Wastewater treatment (WWT) lagoons. (NOTE: Estimates are available for the amount of methane (CH4) emitted from certain types of waste facilities, but there is not adeq...

  7. EMISSION MEASUREMENTS OF PARTICLE MASS AND SIZE EMISSION PROFILES FROM CONSTRUCTION ACTIVITIES

    EPA Science Inventory

    The report gives results from field tests that characterize the amount and size distribution of particulate matter (PM) emissions from operations at construction sites. Of particular interest is the movement of earth by scraper loading and unloading, grading, transit vehicular m...

  8. FIELD MEASUREMENT OF GREENHOUSE GAS EMISSION RATES AND DEVELOPMENT OF EMISSION FACTORS FOR WASTEWATER TREATMENT

    EPA Science Inventory

    The report gives results of field testing to develop more reliable green house gas (GHG) emission estimates for Wastewater treatment (WWT) lagoons. (NOTE: Estimates are available for the amount of methane (CH4) emitted from certain types of waste facilities, but there is not adeq...

  9. EMISSION MEASUREMENTS OF PARTICLE MASS AND SIZE EMISSION PROFILES FROM CONSTRUCTION ACTIVITIES

    EPA Science Inventory

    The report gives results from field tests that characterize the amount and size distribution of particulate matter (PM) emissions from operations at construction sites. Of particular interest is the movement of earth by scraper loading and unloading, grading, transit vehicular m...

  10. Systematic Errors in the Measurement of Emissivity Caused by Directional Effects

    NASA Astrophysics Data System (ADS)

    Kribus, Abraham; Vishnevetsky, Irna; Rotenberg, Eyal; Yakir, Dan

    2003-04-01

    Accurate knowledge of surface emissivity is essential for applications in remote sensing (remote temperature measurement), radiative transport, and modeling of environmental energy balances. Direct measurements of surface emissivity are difficult when there is considerable background radiation at the same wavelength as the emitted radiation. This occurs, for example, when objects at temperatures near room temperature are measured in a terrestrial environment by use of the infrared 8 -14- μm band. This problem is usually treated by assumption of a perfectly diffuse surface or of diffuse background radiation. However, real surfaces and actual background radiation are not diffuse; therefore there will be a systematic measurement error. It is demonstrated that, in some cases, the deviations from a diffuse behavior lead to large errors in the measured emissivity. Past measurements made with simplifying assumptions should therefore be reevaluated and corrected. Recommendations are presented for improving experimental procedures in emissivity measurement.

  11. Spatially resolved flux measurements of NOx from London suggest significantly higher emissions than predicted by inventories.

    PubMed

    Vaughan, Adam R; Lee, James D; Misztal, Pawel K; Metzger, Stefan; Shaw, Marvin D; Lewis, Alastair C; Purvis, Ruth M; Carslaw, David C; Goldstein, Allen H; Hewitt, C Nicholas; Davison, Brian; Beevers, Sean D; Karl, Thomas G

    2016-07-18

    To date, direct validation of city-wide emissions inventories for air pollutants has been difficult or impossible. However, recent technological innovations now allow direct measurement of pollutant fluxes from cities, for comparison with emissions inventories, which are themselves commonly used for prediction of current and future air quality and to help guide abatement strategies. Fluxes of NOx were measured using the eddy-covariance technique from an aircraft flying at low altitude over London. The highest fluxes were observed over central London, with lower fluxes measured in suburban areas. A footprint model was used to estimate the spatial area from which the measured emissions occurred. This allowed comparison of the flux measurements to the UK's National Atmospheric Emissions Inventory (NAEI) for NOx, with scaling factors used to account for the actual time of day, day of week and month of year of the measurement. The comparison suggests significant underestimation of NOx emissions in London by the NAEI, mainly due to its under-representation of real world road traffic emissions. A comparison was also carried out with an enhanced version of the inventory using real world driving emission factors and road measurement data taken from the London Atmospheric Emissions Inventory (LAEI). The measurement to inventory agreement was substantially improved using the enhanced version, showing the importance of fully accounting for road traffic, which is the dominant NOx emission source in London. In central London there was still an underestimation by the inventory of 30-40% compared with flux measurements, suggesting significant improvements are still required in the NOx emissions inventory.

  12. Aircraft-Based Measurements of Point Source Methane Emissions in the Barnett Shale Basin.

    PubMed

    Lavoie, Tegan N; Shepson, Paul B; Cambaliza, Maria O L; Stirm, Brian H; Karion, Anna; Sweeney, Colm; Yacovitch, Tara I; Herndon, Scott C; Lan, Xin; Lyon, David

    2015-07-07

    We report measurements of methane (CH4) emission rates observed at eight different high-emitting point sources in the Barnett Shale, Texas, using aircraft-based methods performed as part of the Barnett Coordinated Campaign. We quantified CH4 emission rates from four gas processing plants, one compressor station, and three landfills during five flights conducted in October 2013. Results are compared to other aircraft- and surface-based measurements of the same facilities, and to estimates based on a national study of gathering and processing facilities emissions and 2013 annual average emissions reported to the U.S. EPA Greenhouse Gas Reporting Program (GHGRP). For the eight sources, CH4 emission measurements from the aircraft-based mass balance approach were a factor of 3.2-5.8 greater than the GHGRP-based estimates. Summed emissions totaled 7022 ± 2000 kg hr(-1), roughly 9% of the entire basin-wide CH4 emissions estimated from regional mass balance flights during the campaign. Emission measurements from five natural gas management facilities were 1.2-4.6 times larger than emissions based on the national study. Results from this study were used to represent "super-emitters" in a newly formulated Barnett Shale Inventory, demonstra