NASA Astrophysics Data System (ADS)
Mehdizadeh, Saeid; Behmanesh, Javad; Khalili, Keivan
2016-08-01
In the present research, three artificial intelligence methods including Gene Expression Programming (GEP), Artificial Neural Networks (ANN) and Adaptive Neuro-Fuzzy Inference System (ANFIS) as well as, 48 empirical equations (10, 12 and 26 equations were temperature-based, sunshine-based and meteorological parameters-based, respectively) were used to estimate daily solar radiation in Kerman, Iran in the period of 1992-2009. To develop the GEP, ANN and ANFIS models, depending on the used empirical equations, various combinations of minimum air temperature, maximum air temperature, mean air temperature, extraterrestrial radiation, actual sunshine duration, maximum possible sunshine duration, sunshine duration ratio, relative humidity and precipitation were considered as inputs in the mentioned intelligent methods. To compare the accuracy of empirical equations and intelligent models, root mean square error (RMSE), mean absolute error (MAE), mean absolute relative error (MARE) and determination coefficient (R2) indices were used. The results showed that in general, sunshine-based and meteorological parameters-based scenarios in ANN and ANFIS models presented high accuracy than mentioned empirical equations. Moreover, the most accurate method in the studied region was ANN11 scenario with five inputs. The values of RMSE, MAE, MARE and R2 indices for the mentioned model were 1.850 MJ m-2 day-1, 1.184 MJ m-2 day-1, 9.58% and 0.935, respectively.
ERIC Educational Resources Information Center
Sims, Paul A.
2012-01-01
A brief history of the development of the empirical equation that is used by prominent, Internet-based programs to estimate (or calculate) the extinction coefficients of proteins is presented. In addition, an overview of a series of related assignments designed to help students understand the origin of the empirical equation is provided. The…
NASA Astrophysics Data System (ADS)
Kim, Taeyoun; Hwang, Seho; Jang, Seonghyung
2017-01-01
When finding the "sweet spot" of a shale gas reservoir, it is essential to estimate the brittleness index (BI) and total organic carbon (TOC) of the formation. Particularly, the BI is one of the key factors in determining the crack propagation and crushing efficiency for hydraulic fracturing. There are several methods for estimating the BI of a formation, but most of them are empirical equations that are specific to particular rock types. We estimated the mineralogical BI based on elemental capture spectroscopy (ECS) log and elastic BI based on well log data, and we propose a new method for predicting S-wave velocity (VS) using mineralogical BI and elastic BI. The TOC is related to the gas content of shale gas reservoirs. Since it is difficult to perform core analysis for all intervals of shale gas reservoirs, we make empirical equations for the Horn River Basin, Canada, as well as TOC log using a linear relation between core-tested TOC and well log data. In addition, two empirical equations have been suggested for VS prediction based on density and gamma ray log used for TOC analysis. By applying the empirical equations proposed from the perspective of BI and TOC to another well log data and then comparing predicted VS log with real VS log, the validity of empirical equations suggested in this paper has been tested.
NASA Astrophysics Data System (ADS)
Kiafar, Hamed; Babazadeh, Hosssien; Marti, Pau; Kisi, Ozgur; Landeras, Gorka; Karimi, Sepideh; Shiri, Jalal
2017-10-01
Evapotranspiration estimation is of crucial importance in arid and hyper-arid regions, which suffer from water shortage, increasing dryness and heat. A modeling study is reported here to cross-station assessment between hyper-arid and humid conditions. The derived equations estimate ET0 values based on temperature-, radiation-, and mass transfer-based configurations. Using data from two meteorological stations in a hyper-arid region of Iran and two meteorological stations in a humid region of Spain, different local and cross-station approaches are applied for developing and validating the derived equations. The comparison of the gene expression programming (GEP)-based-derived equations with corresponding empirical-semi empirical ET0 estimation equations reveals the superiority of new formulas in comparison with the corresponding empirical equations. Therefore, the derived models can be successfully applied in these hyper-arid and humid regions as well as similar climatic contexts especially in data-lack situations. The results also show that when relying on proper input configurations, cross-station might be a promising alternative for locally trained models for the stations with data scarcity.
Galindo-Romero, Marta; Lippert, Tristan; Gavrilov, Alexander
2015-12-01
This paper presents an empirical linear equation to predict peak pressure level of anthropogenic impulsive signals based on its correlation with the sound exposure level. The regression coefficients are shown to be weakly dependent on the environmental characteristics but governed by the source type and parameters. The equation can be applied to values of the sound exposure level predicted with a numerical model, which provides a significant improvement in the prediction of the peak pressure level. Part I presents the analysis for airgun arrays signals, and Part II considers the application of the empirical equation to offshore impact piling noise.
Local Linear Observed-Score Equating
ERIC Educational Resources Information Center
Wiberg, Marie; van der Linden, Wim J.
2011-01-01
Two methods of local linear observed-score equating for use with anchor-test and single-group designs are introduced. In an empirical study, the two methods were compared with the current traditional linear methods for observed-score equating. As a criterion, the bias in the equated scores relative to true equating based on Lord's (1980)…
Kepner, Gordon R
2010-04-13
The numerous natural phenomena that exhibit saturation behavior, e.g., ligand binding and enzyme kinetics, have been approached, to date, via empirical and particular analyses. This paper presents a mechanism-free, and assumption-free, second-order differential equation, designed only to describe a typical relationship between the variables governing these phenomena. It develops a mathematical model for this relation, based solely on the analysis of the typical experimental data plot and its saturation characteristics. Its utility complements the traditional empirical approaches. For the general saturation curve, described in terms of its independent (x) and dependent (y) variables, a second-order differential equation is obtained that applies to any saturation phenomena. It shows that the driving factor for the basic saturation behavior is the probability of the interactive site being free, which is described quantitatively. Solving the equation relates the variables in terms of the two empirical constants common to all these phenomena, the initial slope of the data plot and the limiting value at saturation. A first-order differential equation for the slope emerged that led to the concept of the effective binding rate at the active site and its dependence on the calculable probability the interactive site is free. These results are illustrated using specific cases, including ligand binding and enzyme kinetics. This leads to a revised understanding of how to interpret the empirical constants, in terms of the variables pertinent to the phenomenon under study. The second-order differential equation revealed the basic underlying relations that describe these saturation phenomena, and the basic mathematical properties of the standard experimental data plot. It was shown how to integrate this differential equation, and define the common basic properties of these phenomena. The results regarding the importance of the slope and the new perspectives on the empirical constants governing the behavior of these phenomena led to an alternative perspective on saturation behavior kinetics. Their essential commonality was revealed by this analysis, based on the second-order differential equation.
Arefin, Md Shamsul
2012-01-01
This work presents a technique for the chirality (n, m) assignment of semiconducting single wall carbon nanotubes by solving a set of empirical equations of the tight binding model parameters. The empirical equations of the nearest neighbor hopping parameters, relating the term (2n− m) with the first and second optical transition energies of the semiconducting single wall carbon nanotubes, are also proposed. They provide almost the same level of accuracy for lower and higher diameter nanotubes. An algorithm is presented to determine the chiral index (n, m) of any unknown semiconducting tube by solving these empirical equations using values of radial breathing mode frequency and the first or second optical transition energy from resonant Raman spectroscopy. In this paper, the chirality of 55 semiconducting nanotubes is assigned using the first and second optical transition energies. Unlike the existing methods of chirality assignment, this technique does not require graphical comparison or pattern recognition between existing experimental and theoretical Kataura plot. PMID:28348319
Constitutive Equation with Varying Parameters for Superplastic Flow Behavior
NASA Astrophysics Data System (ADS)
Guan, Zhiping; Ren, Mingwen; Jia, Hongjie; Zhao, Po; Ma, Pinkui
2014-03-01
In this study, constitutive equations for superplastic materials with an extra large elongation were investigated through mechanical analysis. From the view of phenomenology, firstly, some traditional empirical constitutive relations were standardized by restricting some strain paths and parameter conditions, and the coefficients in these relations were strictly given new mechanical definitions. Subsequently, a new, general constitutive equation with varying parameters was theoretically deduced based on the general mechanical equation of state. The superplastic tension test data of Zn-5%Al alloy at 340 °C under strain rates, velocities, and loads were employed for building a new constitutive equation and examining its validity. Analysis results indicated that the constitutive equation with varying parameters could characterize superplastic flow behavior in practical superplastic forming with high prediction accuracy and without any restriction of strain path or deformation condition, showing good industrial or scientific interest. On the contrary, those empirical equations have low prediction capabilities due to constant parameters and poor applicability because of the limit of special strain path or parameter conditions based on strict phenomenology.
Equating Scores from Adaptive to Linear Tests
ERIC Educational Resources Information Center
van der Linden, Wim J.
2006-01-01
Two local methods for observed-score equating are applied to the problem of equating an adaptive test to a linear test. In an empirical study, the methods were evaluated against a method based on the test characteristic function (TCF) of the linear test and traditional equipercentile equating applied to the ability estimates on the adaptive test…
UDOT calibration of AASHTO's new prestress loss design equations.
DOT National Transportation Integrated Search
2009-07-01
In the next edition of the AASHTO LRFD Bridge Design Specifications the procedure to calculate prestress losses will change dramatically. The new equations are empirically based on high performance concrete from four states (Nebraska, New Hampshire, ...
UDOT's calibration of AASHTO's new prestress loss design equations.
DOT National Transportation Integrated Search
2009-07-01
In the next edition of the AASHTO LRFD Bridge Design Specifications the procedure to calculate prestress losses will change dramatically. The new equations are empirically based on high performance concrete from four states (Nebraska, New Hampshire, ...
ERIC Educational Resources Information Center
Liu, Jinghua; Zu, Jiyun; Curley, Edward; Carey, Jill
2014-01-01
The purpose of this study is to investigate the impact of discrete anchor items versus passage-based anchor items on observed score equating using empirical data.This study compares an "SAT"® critical reading anchor that contains more discrete items proportionally, compared to the total tests to be equated, to another anchor that…
Bridging the Knowledge Gaps between Richards' Equation and Budyko Equation
NASA Astrophysics Data System (ADS)
Wang, D.
2017-12-01
The empirical Budyko equation represents the partitioning of mean annual precipitation into evaporation and runoff. Richards' equation, based on Darcy's law, represents the movement of water in unsaturated soils. The linkage between Richards' equation and Budyko equation is presented by invoking the empirical Soil Conservation Service curve number (SCS-CN) model for computing surface runoff at the event-scale. The basis of the SCS-CN method is the proportionality relationship, i.e., the ratio of continuing abstraction to its potential is equal to the ratio of surface runoff to its potential value. The proportionality relationship can be derived from the Richards' equation for computing infiltration excess and saturation excess models at the catchment scale. Meanwhile, the generalized proportionality relationship is demonstrated as the common basis of SCS-CN method, monthly "abcd" model, and Budyko equation. Therefore, the linkage between Darcy's law and the emergent pattern of mean annual water balance at the catchment scale is presented through the proportionality relationship.
DOT National Transportation Integrated Search
2017-01-01
The New York State Department of Transportation (NYSDOT) has used the AASHTO 1993 Design Guide for the design of new flexible pavement structures for more than two decades. The AASHTO 1993 Guide is based on the empirical design equations developed fr...
Further Evaluation of an Emperical Equation for Annual Total Evaporation
NASA Technical Reports Server (NTRS)
Choudhury, Bhaskar J.
1999-01-01
An empirical equation for annual total evaporation based on annual precipitation and net radiation was found to provide evaporation within 10% of the observed values at seven locations within temperate and tropical regions, but it overestimated evaporation by 90% at one location within the tundra region. A synthesis of observations at two other locations within the tundra region gives overestimates of about 65%. A general analysis of observed precipitation, net radiation, and runoff within the tundra region shows that the empirical equation is generally biased to overestimate annual evaporation within the tundra region. A theoretical analysis is being done to understand the reason behind this bias.
NASA Astrophysics Data System (ADS)
Dadashev, R. Kh.; Dzhambulatov, R. S.; Mezhidov, V. Kh.; Elimkhanov, D. Z.
2018-05-01
Concentration dependences of the surface tension and density of solutions of three-component acetone-ethanol-water systems and the bounding binary systems at 273 K are studied. The molar volume, adsorption, and composition of surface layers are calculated. Experimental data and calculations show that three-component solutions are close to ideal ones. The surface tensions of these solutions are calculated using semi-empirical and theoretical equations. Theoretical equations qualitatively convey the concentration dependence of surface tension. A semi-empirical method based on the Köhler equation allows us to predict the concentration dependence of surface tension within the experimental error.
NASA Astrophysics Data System (ADS)
Gontis, V.; Kononovicius, A.
2017-10-01
We address the problem of long-range memory in the financial markets. There are two conceptually different ways to reproduce power-law decay of auto-correlation function: using fractional Brownian motion as well as non-linear stochastic differential equations. In this contribution we address this problem by analyzing empirical return and trading activity time series from the Forex. From the empirical time series we obtain probability density functions of burst and inter-burst duration. Our analysis reveals that the power-law exponents of the obtained probability density functions are close to 3 / 2, which is a characteristic feature of the one-dimensional stochastic processes. This is in a good agreement with earlier proposed model of absolute return based on the non-linear stochastic differential equations derived from the agent-based herding model.
Empirical Allometric Models to Estimate Total Needle Biomass For Loblolly Pine
Hector M. de los Santos-Posadas; Bruce E. Borders
2002-01-01
Empirical geometric models based on the cone surface formula were adapted and used to estimate total dry needle biomass (TNB) and live branch basal area (LBBA). The results suggest that the empirical geometric equations produced good fit and stable parameters while estimating TNB and LBBA. The data used include trees form a spacing study of 12 years old and a set of...
Educational Inequality and Income Inequality: An Empirical Study on China
ERIC Educational Resources Information Center
Yang, Jun; Huang, Xiao; Li, Xiaoyu
2009-01-01
Based on the endogenous growth theory, this paper uses the Gini coefficient to measure educational inequality and studies the empirical relationship between educational inequality and income inequality through a simultaneous equation model. The results show that: (1) Income inequality leads to educational inequality while the reduction of…
A Rapid Empirical Method for Estimating the Gross Takeoff Weight of a High Speed Civil Transport
NASA Technical Reports Server (NTRS)
Mack, Robert J.
1999-01-01
During the cruise segment of the flight mission, aircraft flying at supersonic speeds generate sonic booms that are usually maximum at the beginning of cruise. The pressure signature with the shocks causing these perceived booms can be predicted if the aircraft's geometry, Mach number, altitude, angle of attack, and cruise weight are known. Most methods for estimating aircraft weight, especially beginning-cruise weight, are empirical and based on least- square-fit equations that best represent a body of component weight data. The empirical method discussed in this report used simplified weight equations based on a study of performance and weight data from conceptual and real transport aircraft. Like other weight-estimation methods, weights were determined at several points in the mission. While these additional weights were found to be useful, it is the determination of beginning-cruise weight that is most important for the prediction of the aircraft's sonic-boom characteristics.
van Noort, Paul C M
2009-06-01
Fugacity ratios of organic compounds are used to calculate (subcooled) liquid properties, such as solubility or vapour pressure, from solid properties and vice versa. They can be calculated from the entropy of fusion, the melting temperature, and heat capacity data for the solid and the liquid. For many organic compounds, values for the fusion entropy are lacking. Heat capacity data are even scarcer. In the present study, semi-empirical compound class specific equations were derived to estimate fugacity ratios from molecular weight and melting temperature for polycyclic aromatic hydrocarbons and polychlorinated benzenes, biphenyls, dibenzo[p]dioxins and dibenzofurans. These equations estimate fugacity ratios with an average standard error of about 0.05 log units. In addition, for compounds with known fusion entropy values, a general semi-empirical correction equation based on molecular weight and melting temperature was derived for estimation of the contribution of heat capacity differences to the fugacity ratio. This equation estimates the heat capacity contribution correction factor with an average standard error of 0.02 log units for polycyclic aromatic hydrocarbons, polychlorinated benzenes, biphenyls, dibenzo[p]dioxins and dibenzofurans.
Heavy use of equations impedes communication among biologists.
Fawcett, Tim W; Higginson, Andrew D
2012-07-17
Most research in biology is empirical, yet empirical studies rely fundamentally on theoretical work for generating testable predictions and interpreting observations. Despite this interdependence, many empirical studies build largely on other empirical studies with little direct reference to relevant theory, suggesting a failure of communication that may hinder scientific progress. To investigate the extent of this problem, we analyzed how the use of mathematical equations affects the scientific impact of studies in ecology and evolution. The density of equations in an article has a significant negative impact on citation rates, with papers receiving 28% fewer citations overall for each additional equation per page in the main text. Long, equation-dense papers tend to be more frequently cited by other theoretical papers, but this increase is outweighed by a sharp drop in citations from nontheoretical papers (35% fewer citations for each additional equation per page in the main text). In contrast, equations presented in an accompanying appendix do not lessen a paper's impact. Our analysis suggests possible strategies for enhancing the presentation of mathematical models to facilitate progress in disciplines that rely on the tight integration of theoretical and empirical work.
Solar radiation is one of the main factors controlling the rate of primary production on the Louisiana Shelf in the northern Gulf of Mexico. This work seeks to improve on previously published empirical equations through the use of statistical data transformation and the incorpora...
Model development and applications at the USDA-ARS National Soil Erosion Research Laboratory
USDA-ARS?s Scientific Manuscript database
The United States Department of Agriculture (USDA) has a long history of development of soil erosion prediction technology, initially with empirical equations like the Universal Soil Loss Equation (USLE), and more recently with process-based models such as the Water Erosion Prediction Project (WEPP)...
Optimum wall impedance for spinning modes: A correlation with mode cut-off ratio
NASA Technical Reports Server (NTRS)
Rice, E. J.
1978-01-01
A correlating equation relating the optimum acoustic impedance for the wall lining of a circular duct to the acoustic mode cut-off ratio, is presented. The optimum impedance was correlated with cut-off ratio because the cut-off ratio appears to be the fundamental parameter governing the propagation of sound in the duct. Modes with similar cut-off ratios respond in a similar way to the acoustic liner. The correlation is a semi-empirical expression developed from an empirical modification of an equation originally derived from sound propagation theory in a thin boundary layer. This correlating equation represents a part of a simplified liner design method, based upon modal cut-off ratio, for multimodal noise propagation.
NASA Astrophysics Data System (ADS)
Martins, Luciano; Díez-Herrero, Andrés; Bodoque, Jose M.; Bateira, Carlos
2016-04-01
The perception of flood risk by the responsible authorities on the flood management disasters and mitigation strategies should be based on an overall evaluation of the uncertainties associated with the procedures for risk assessment and mapping production. This contribution presents the results of the development of mapping evaluation of the time of concentration (tc). This parameter reflects the time-space at which a watershed responds to rainfall events and is the most frequently utilized time parameter, and is of great importance in many hydrologic analysis. Accurate estimates of the tc are very important, for instance, if tc is under-estimated, the result is an over-estimated peak discharge and vice versa, resulting significant variations on the flooded areas, and could have important consequences in terms of the land use and occupation of territory, as management's own flood risk. The methology used evaluate 20 different empirical, semi-empirical and kinematics equations of tc calculation, due to different cartographic scales (1:200000; 1:100000; 1:25000; LIDAR 5x5m &1x1m) in in two hydrographic basins with distinct dimensions and geomorphological characteristics, located in the Gredos Mountain range (Spain). The results suggest that the changes in the cartographic scale, has not influence as significant as one might expect. The most important variations occur in the characteristics of the fequations, use different morphometricparameters in the calculations. Some just are based on geomorphological criteria and other magnify the hydraulic characteristics of the channels, resulting in very different tc values. However, we highlighting the role of cartographic scale particularly in the application of semi-empirical equations that take into account changes in land use and occupation. In this case, the determination of parameters, such as flow coefficient, curve number and roughness coefficient are very sensitive to cartographic scale. Sensitivity analysis demonstrates that the empirical equations are simpler (e.g Giandotti, Chow, Temez), since it is based only on the geometrical characteristics of the basin and therefore the results tend not to reflect the dynamic range leadings to worse results of tc.The application of these equations based on local parameters should not be applied to other regions that have distinct geomorphological and climatic characteristics, since greatly influences the results.The semi-empirical and kinematics equations (e.g SCS, Kinematic Wave) tc is reflected mainly in the form of the hydrograph, particularly in the Lag-time. Thats seems be an appropriate to the integrated analysis of hydrographic basins. Moreover, these methods are fundamental to understand spatio-temporal dynamics within the basin, even if some parameters are difficult to calculate. The best way to calibrate and evaluate the obtained concentration time values, should be based on known events, calibrated by rating curves records.
NASA Astrophysics Data System (ADS)
Prabhu Verleker, Akshay; Fang, Qianqian; Choi, Mi-Ran; Clare, Susan; Stantz, Keith M.
2015-03-01
The purpose of this study is to develop an alternate empirical approach to estimate near-infra-red (NIR) photon propagation and quantify optically induced drug release in brain metastasis, without relying on computationally expensive Monte Carlo techniques (gold standard). Targeted drug delivery with optically induced drug release is a noninvasive means to treat cancers and metastasis. This study is part of a larger project to treat brain metastasis by delivering lapatinib-drug-nanocomplexes and activating NIR-induced drug release. The empirical model was developed using a weighted approach to estimate photon scattering in tissues and calibrated using a GPU based 3D Monte Carlo. The empirical model was developed and tested against Monte Carlo in optical brain phantoms for pencil beams (width 1mm) and broad beams (width 10mm). The empirical algorithm was tested against the Monte Carlo for different albedos along with diffusion equation and in simulated brain phantoms resembling white-matter (μs'=8.25mm-1, μa=0.005mm-1) and gray-matter (μs'=2.45mm-1, μa=0.035mm-1) at wavelength 800nm. The goodness of fit between the two models was determined using coefficient of determination (R-squared analysis). Preliminary results show the Empirical algorithm matches Monte Carlo simulated fluence over a wide range of albedo (0.7 to 0.99), while the diffusion equation fails for lower albedo. The photon fluence generated by empirical code matched the Monte Carlo in homogeneous phantoms (R2=0.99). While GPU based Monte Carlo achieved 300X acceleration compared to earlier CPU based models, the empirical code is 700X faster than the Monte Carlo for a typical super-Gaussian laser beam.
Hasani, Mojtaba H; Gharibzadeh, Shahriar; Farjami, Yaghoub; Tavakkoli, Jahan
2013-09-01
Various numerical algorithms have been developed to solve the Khokhlov-Kuznetsov-Zabolotskaya (KZK) parabolic nonlinear wave equation. In this work, a generalized time-domain numerical algorithm is proposed to solve the diffraction term of the KZK equation. This algorithm solves the transverse Laplacian operator of the KZK equation in three-dimensional (3D) Cartesian coordinates using a finite-difference method based on the five-point implicit backward finite difference and the five-point Crank-Nicolson finite difference discretization techniques. This leads to a more uniform discretization of the Laplacian operator which in turn results in fewer calculation gridding nodes without compromising accuracy in the diffraction term. In addition, a new empirical algorithm based on the LU decomposition technique is proposed to solve the system of linear equations obtained from this discretization. The proposed empirical algorithm improves the calculation speed and memory usage, while the order of computational complexity remains linear in calculation of the diffraction term in the KZK equation. For evaluating the accuracy of the proposed algorithm, two previously published algorithms are used as comparison references: the conventional 2D Texas code and its generalization for 3D geometries. The results show that the accuracy/efficiency performance of the proposed algorithm is comparable with the established time-domain methods.
Development of an empirically based dynamic biomechanical strength model
NASA Technical Reports Server (NTRS)
Pandya, A.; Maida, J.; Aldridge, A.; Hasson, S.; Woolford, B.
1992-01-01
The focus here is on the development of a dynamic strength model for humans. Our model is based on empirical data. The shoulder, elbow, and wrist joints are characterized in terms of maximum isolated torque, position, and velocity in all rotational planes. This information is reduced by a least squares regression technique into a table of single variable second degree polynomial equations determining the torque as a function of position and velocity. The isolated joint torque equations are then used to compute forces resulting from a composite motion, which in this case is a ratchet wrench push and pull operation. What is presented here is a comparison of the computed or predicted results of the model with the actual measured values for the composite motion.
Empirically Derived Optimal Growth Equations For Hardwoods and Softwoods in Arkansas
Don C. Bragg
2002-01-01
Accurate growth projections are critical to reliable forest models, and ecologically based simulators can improve siivicultural predictions because of their sensitivity to change and their capacity to produce long-term forecasts. Potential relative increment (PRI) optimal diameter growth equations for loblolly pine, shortleaf pine, sweetgum, and white oak were fit to...
Boore, D.M.
2001-01-01
This article has the modest goal of comparing the ground motions recorded during the 1999 Chi-Chi, Taiwan, mainshock with predictions from four empirical-based equations commonly used for western North America; these empirical predictions are largely based on data from California. Comparisons are made for peak acceleration and 5%-damped response spectra at periods between 0.1 and 4 sec. The general finding is that the Chi-Chi ground motions are smaller than those predicted from the empirically based equations for periods less than about 1 sec by factors averaging about 0.4 but as small as 0.26 (depending on period, on which equation is used, and on whether the sites are assumed to be rock or soil). There is a trend for the observed motions to approach or even exceed the predicted motions for longer periods. Motions at similar distances (30-60 km) to the east and to the west of the fault differ dramatically at periods between about 2 and 20 sec: Long-duration wave trains are present on the motions to the west, and when normalized to similar amplitudes at short periods, the response spectra of the motions at the western stations are as much as five times larger than those of motions from eastern stations. The explanation for the difference is probably related to site and propagation effects; the western stations are on the Coastal Plain, whereas the eastern stations are at the foot of young and steep mountains, either in the relatively narrow Longitudinal Valley or along the eastern coast-the sediments underlying the eastern stations are probably shallower and have higher velocity than those under the western stations.
Fateen, Seif-Eddeen K; Khalil, Menna M; Elnabawy, Ahmed O
2013-03-01
Peng-Robinson equation of state is widely used with the classical van der Waals mixing rules to predict vapor liquid equilibria for systems containing hydrocarbons and related compounds. This model requires good values of the binary interaction parameter kij . In this work, we developed a semi-empirical correlation for kij partly based on the Huron-Vidal mixing rules. We obtained values for the adjustable parameters of the developed formula for over 60 binary systems and over 10 categories of components. The predictions of the new equation system were slightly better than the constant-kij model in most cases, except for 10 systems whose predictions were considerably improved with the new correlation.
Modeling Explosive Cladding of Metallic Liners to Gun Tubes
2010-01-01
a Jones Wilkins Lee ( JWL ) equation of state was parameterized using nonlinear optimization (ref. 8) and scaling the empirical v2£ for other volume...expansions based on TNT. The JWL equation of state is ( ,. A i -RiV* , GJE RiV* V IS./K v f +7~* (2) where P is pressure, V is
NASA Astrophysics Data System (ADS)
Barreneche, C.; Ferrer, G.; Palacios, A.; Solé, A.; Inés Fernández, A.; Cabeza, L. F.
2017-10-01
Phase change materials (PCM) used in thermal energy storage (TES) systems have been presented, over recent years, as one of the most effective options in energy storage. Paraffin and fatty acids are some of the most used PCM in TES systems, as they have high phase change enthalpy and in addition they do not present subcooling nor hysteresis and have proper cycling stability. The simulations and design of TES systems require the knowledge of the thermophysical properties of PCM. Thermal conductivity, viscosity, specific heat capacity (Cp) can be experimentally determined, but these are material and time consuming tasks. To avoid or to reduce them, and to have reliable data without the need of experimentation, thermal properties can be calculated by empirical equations. In this study, five different equations are given to calculate the viscosity and specific heat capacity of fatty acid PCM and paraffin PCM. Two of these equations concern, respectively, the empirical calculation of the viscosity and liquid Cp of the whole paraffin PCM family, while the other three equations presented are for the corresponding calculation of viscosity, solid Cp, liquid Cp of the whole fatty acid family of PCM. Therefore, this study summarize the work performed to obtain the main empirical equations to measure the above mentioned properties for whole fatty acid PCM family and whole paraffin PCM family. Moreover, empirical equations have been obtained to calculate these properties for other materials of these PCM groups and these empirical equations can be extrapolated for PCM with higher or lower phase change temperatures within a lower relative error 4%.
On the methods for determining the transverse dispersion coefficient in river mixing
NASA Astrophysics Data System (ADS)
Baek, Kyong Oh; Seo, Il Won
2016-04-01
In this study, the strengths and weaknesses of existing methods for determining the dispersion coefficient in the two-dimensional river mixing model were assessed based on hydraulic and tracer data sets acquired from experiments conducted on either laboratory channels or natural rivers. From the results of this study, it can be concluded that, when the longitudinal dispersion coefficient as well as the transverse dispersion coefficients must be determined in the transient concentration situation, the two-dimensional routing procedures, 2D RP and 2D STRP, can be employed to calculate dispersion coefficients among the observation methods. For the steady concentration situation, the STRP can be applied to calculate the transverse dispersion coefficient. When the tracer data are not available, either theoretical or empirical equations by the estimation method can be used to calculate the dispersion coefficient using the geometric and hydraulic data sets. Application of the theoretical and empirical equations to the laboratory channel showed that equations by Baek and Seo [[3], 2011] predicted reasonable values while equations by Fischer [23] and Boxwall and Guymer (2003) overestimated by factors of ten to one hundred. Among existing empirical equations, those by Jeon et al. [28] and Baek and Seo [6] gave the agreeable values of the transverse dispersion coefficient for most cases of natural rivers. Further, the theoretical equation by Baek and Seo [5] has the potential to be broadly applied to both laboratory and natural channels.
A Hybrid Ground-Motion Prediction Equation for Earthquakes in Western Alberta
NASA Astrophysics Data System (ADS)
Spriggs, N.; Yenier, E.; Law, A.; Moores, A. O.
2015-12-01
Estimation of ground-motion amplitudes that may be produced by future earthquakes constitutes the foundation of seismic hazard assessment and earthquake-resistant structural design. This is typically done by using a prediction equation that quantifies amplitudes as a function of key seismological variables such as magnitude, distance and site condition. In this study, we develop a hybrid empirical prediction equation for earthquakes in western Alberta, where evaluation of seismic hazard associated with induced seismicity is of particular interest. We use peak ground motions and response spectra from recorded seismic events to model the regional source and attenuation attributes. The available empirical data is limited in the magnitude range of engineering interest (M>4). Therefore, we combine empirical data with a simulation-based model in order to obtain seismologically informed predictions for moderate-to-large magnitude events. The methodology is two-fold. First, we investigate the shape of geometrical spreading in Alberta. We supplement the seismic data with ground motions obtained from mining/quarry blasts, in order to gain insights into the regional attenuation over a wide distance range. A comparison of ground-motion amplitudes for earthquakes and mining/quarry blasts show that both event types decay at similar rates with distance and demonstrate a significant Moho-bounce effect. In the second stage, we calibrate the source and attenuation parameters of a simulation-based prediction equation to match the available amplitude data from seismic events. We model the geometrical spreading using a trilinear function with attenuation rates obtained from the first stage, and calculate coefficients of anelastic attenuation and site amplification via regression analysis. This provides a hybrid ground-motion prediction equation that is calibrated for observed motions in western Alberta and is applicable to moderate-to-large magnitude events.
An Empirical Comparison of Five Linear Equating Methods for the NEAT Design
ERIC Educational Resources Information Center
Suh, Youngsuk; Mroch, Andrew A.; Kane, Michael T.; Ripkey, Douglas R.
2009-01-01
In this study, a data base containing the responses of 40,000 candidates to 90 multiple-choice questions was used to mimic data sets for 50-item tests under the "nonequivalent groups with anchor test" (NEAT) design. Using these smaller data sets, we evaluated the performance of five linear equating methods for the NEAT design with five levels of…
Empirical tests of a theory of language, mathematics, and matter.
Abler, William L
2008-01-01
In an earlier paper (Abler, 2006), I proposed a theory of language, especially sentences, based on the symmetrical structure of the equation. Here, I use the structure of equations to deduce neural structures (e.g., mirror neurons or intra-cellular macromolecules, or crystals, or resonations) that might generate them. Ultimately, the properties described are a consequence of dimensional properties of matter
Numerical simulation of life cycles of advection warm fog
NASA Technical Reports Server (NTRS)
Hung, R. J.; Vaughan, O. H.
1977-01-01
The formation, development and dissipation of advection warm fog is investigated. The equations employed in the model include the equation of continuity, momentum and energy for the descriptions of density, wind component and potential temperature, respectively, together with two diffusion equations for the modification of water-vapor mixing ratio and liquid-water mixing ratios. A description of the vertical turbulent transfer of heat, moisture and momentum has been taken into consideration. The turbulent exchange coefficients adopted in the model are based on empirical flux-gradient relations.
Charge Transport in Nonaqueous Liquid Electrolytes: A Paradigm Shift
2015-05-18
that provide inadequate descriptions of experimental data, often using empirical equations whose fitting parameters have no physical significance...provide inadequate descriptions of experimental data, often using empirical equations whose fitting parameters have no physical significance...Ea The hydrodynamic model, utilizing the Stokes equation describes isothermal conductivity, self-diffusion coefficient, and the dielectric
Quantitative model of the growth of floodplains by vertical accretion
Moody, J.A.; Troutman, B.M.
2000-01-01
A simple one-dimensional model is developed to quantitatively predict the change in elevation, over a period of decades, for vertically accreting floodplains. This unsteady model approximates the monotonic growth of a floodplain as an incremental but constant increase of net sediment deposition per flood for those floods of a partial duration series that exceed a threshold discharge corresponding to the elevation of the floodplain. Sediment deposition from each flood increases the elevation of the floodplain and consequently the magnitude of the threshold discharge resulting in a decrease in the number of floods and growth rate of the floodplain. Floodplain growth curves predicted by this model are compared to empirical growth curves based on dendrochronology and to direct field measurements at five floodplain sites. The model was used to predict the value of net sediment deposition per flood which best fits (in a least squares sense) the empirical and field measurements; these values fall within the range of independent estimates of the net sediment deposition per flood based on empirical equations. These empirical equations permit the application of the model to estimate of floodplain growth for other floodplains throughout the world which do not have detailed data of sediment deposition during individual floods. Copyright (C) 2000 John Wiley and Sons, Ltd.
A review of physically based models for soil erosion by water
NASA Astrophysics Data System (ADS)
Le, Minh-Hoang; Cerdan, Olivier; Sochala, Pierre; Cheviron, Bruno; Brivois, Olivier; Cordier, Stéphane
2010-05-01
Physically-based models rely on fundamental physical equations describing stream flow and sediment and associated nutrient generation in a catchment. This paper reviews several existing erosion and sediment transport approaches. The process of erosion include soil detachment, transport and deposition, we present various forms of equations and empirical formulas used when modelling and quantifying each of these processes. In particular, we detail models describing rainfall and infiltration effects and the system of equations to describe the overland flow and the evolution of the topography. We also present the formulas for the flow transport capacity and the erodibility functions. Finally, we present some recent numerical schemes to approach the shallow water equations and it's coupling with infiltration and erosion source terms.
Estimating Finite Rate of Population Increase for Sharks Based on Vital Parameters
Liu, Kwang-Ming; Chin, Chien-Pang; Chen, Chun-Hui; Chang, Jui-Han
2015-01-01
The vital parameter data for 62 stocks, covering 38 species, collected from the literature, including parameters of age, growth, and reproduction, were log-transformed and analyzed using multivariate analyses. Three groups were identified and empirical equations were developed for each to describe the relationships between the predicted finite rates of population increase (λ’) and the vital parameters, maximum age (Tmax), age at maturity (Tm), annual fecundity (f/Rc)), size at birth (Lb), size at maturity (Lm), and asymptotic length (L∞). Group (1) included species with slow growth rates (0.034 yr-1 < k < 0.103 yr-1) and extended longevity (26 yr < Tmax < 81 yr), e.g., shortfin mako Isurus oxyrinchus, dusky shark Carcharhinus obscurus, etc.; Group (2) included species with fast growth rates (0.103 yr-1 < k < 0.358 yr-1) and short longevity (9 yr < Tmax < 26 yr), e.g., starspotted smoothhound Mustelus manazo, gray smoothhound M. californicus, etc.; Group (3) included late maturing species (Lm/L∞ ≧ 0.75) with moderate longevity (Tmax < 29 yr), e.g., pelagic thresher Alopias pelagicus, sevengill shark Notorynchus cepedianus. The empirical equation for all data pooled was also developed. The λ’ values estimated by these empirical equations showed good agreement with those calculated using conventional demographic analysis. The predictability was further validated by an independent data set of three species. The empirical equations developed in this study not only reduce the uncertainties in estimation but also account for the difference in life history among groups. This method therefore provides an efficient and effective approach to the implementation of precautionary shark management measures. PMID:26576058
NASA Astrophysics Data System (ADS)
Meshgi, Ali; Schmitter, Petra; Babovic, Vladan; Chui, Ting Fong May
2014-11-01
Developing reliable methods to estimate stream baseflow has been a subject of interest due to its importance in catchment response and sustainable watershed management. However, to date, in the absence of complex numerical models, baseflow is most commonly estimated using statistically derived empirical approaches that do not directly incorporate physically-meaningful information. On the other hand, Artificial Intelligence (AI) tools such as Genetic Programming (GP) offer unique capabilities to reduce the complexities of hydrological systems without losing relevant physical information. This study presents a simple-to-use empirical equation to estimate baseflow time series using GP so that minimal data is required and physical information is preserved. A groundwater numerical model was first adopted to simulate baseflow for a small semi-urban catchment (0.043 km2) located in Singapore. GP was then used to derive an empirical equation relating baseflow time series to time series of groundwater table fluctuations, which are relatively easily measured and are physically related to baseflow generation. The equation was then generalized for approximating baseflow in other catchments and validated for a larger vegetation-dominated basin located in the US (24 km2). Overall, this study used GP to propose a simple-to-use equation to predict baseflow time series based on only three parameters: minimum daily baseflow of the entire period, area of the catchment and groundwater table fluctuations. It serves as an alternative approach for baseflow estimation in un-gauged systems when only groundwater table and soil information is available, and is thus complementary to other methods that require discharge measurements.
Estimation of air-water gas exchange coefficient in a shallow lagoon based on 222Rn mass balance.
Cockenpot, S; Claude, C; Radakovitch, O
2015-05-01
The radon-222 mass balance is now commonly used to quantify water fluxes due to Submarine Groundwater Discharge (SGD) in coastal areas. One of the main loss terms of this mass balance, the radon evasion to the atmosphere, is based on empirical equations. This term is generally estimated using one among the many empirical equations describing the gas transfer velocity as a function of wind speed that have been proposed in the literature. These equations were, however, mainly obtained from areas of deep water and may be less appropriate for shallow areas. Here, we calculate the radon mass balance for a windy shallow coastal lagoon (mean depth of 6m and surface area of 1.55*10(8) m(2)) and use these data to estimate the radon loss to the atmosphere and the corresponding gas transfer velocity. We present new equations, adapted to our shallow water body, to express the gas transfer velocity as a function of wind speed at 10 m height (wind range from 2 to 12.5 m/s). When compared with those from the literature, these equations fit particularly well with the one of Kremer et al. (2003). Finally, we emphasize that some gas transfer exchange may always occur, even for conditions without wind. Copyright © 2015 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Shiri, Jalal
2018-06-01
Among different reference evapotranspiration (ETo) modeling approaches, mass transfer-based methods have been less studied. These approaches utilize temperature and wind speed records. On the other hand, the empirical equations proposed in this context generally produce weak simulations, except when a local calibration is used for improving their performance. This might be a crucial drawback for those equations in case of local data scarcity for calibration procedure. So, application of heuristic methods can be considered as a substitute for improving the performance accuracy of the mass transfer-based approaches. However, given that the wind speed records have usually higher variation magnitudes than the other meteorological parameters, application of a wavelet transform for coupling with heuristic models would be necessary. In the present paper, a coupled wavelet-random forest (WRF) methodology was proposed for the first time to improve the performance accuracy of the mass transfer-based ETo estimation approaches using cross-validation data management scenarios in both local and cross-station scales. The obtained results revealed that the new coupled WRF model (with the minimum scatter index values of 0.150 and 0.192 for local and external applications, respectively) improved the performance accuracy of the single RF models as well as the empirical equations to great extent.
Theoretical Foundation of Zisman's Empirical Equation for Wetting of Liquids on Solid Surfaces
ERIC Educational Resources Information Center
Zhu, Ruzeng; Cui, Shuwen; Wang, Xiaosong
2010-01-01
Theories of wetting of liquids on solid surfaces under the condition that van der Waals force is dominant are briefly reviewed. We show theoretically that Zisman's empirical equation for wetting of liquids on solid surfaces is a linear approximation of the Young-van der Waals equation in the wetting region, and we express the two parameters in…
Fuel consumption modeling in support of ATM environmental decision-making
DOT National Transportation Integrated Search
2009-07-01
The FAA has recently updated the airport terminal : area fuel consumption methods used in its environmental models. : These methods are based on fitting manufacturers fuel : consumption data to empirical equations. The new fuel : consumption metho...
Predicting the particle size distribution of eroded sediment using artificial neural networks.
Lagos-Avid, María Paz; Bonilla, Carlos A
2017-03-01
Water erosion causes soil degradation and nonpoint pollution. Pollutants are primarily transported on the surfaces of fine soil and sediment particles. Several soil loss models and empirical equations have been developed for the size distribution estimation of the sediment leaving the field, including the physically-based models and empirical equations. Usually, physically-based models require a large amount of data, sometimes exceeding the amount of available data in the modeled area. Conversely, empirical equations do not always predict the sediment composition associated with individual events and may require data that are not always available. Therefore, the objective of this study was to develop a model to predict the particle size distribution (PSD) of eroded soil. A total of 41 erosion events from 21 soils were used. These data were compiled from previous studies. Correlation and multiple regression analyses were used to identify the main variables controlling sediment PSD. These variables were the particle size distribution in the soil matrix, the antecedent soil moisture condition, soil erodibility, and hillslope geometry. With these variables, an artificial neural network was calibrated using data from 29 events (r 2 =0.98, 0.97, and 0.86; for sand, silt, and clay in the sediment, respectively) and then validated and tested on 12 events (r 2 =0.74, 0.85, and 0.75; for sand, silt, and clay in the sediment, respectively). The artificial neural network was compared with three empirical models. The network presented better performance in predicting sediment PSD and differentiating rain-runoff events in the same soil. In addition to the quality of the particle distribution estimates, this model requires a small number of easily obtained variables, providing a convenient routine for predicting PSD in eroded sediment in other pollutant transport models. Copyright © 2017 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
Yamaguchi, Makoto; Midorikawa, Saburoh
The empirical equation for estimating the site amplification factor of ground motion by the average shear-wave velocity of ground (AVS) is examined. In the existing equations, the coefficient on dependence of the amplification factor on the AVS was treated as constant. The analysis showed that the coefficient varies with change of the AVS for short periods. A new estimation equation was proposed considering the dependence on the AVS. The new equation can represent soil characteristics that the softer soil has the longer predominant period, and can make better estimations for short periods than the existing method.
Fractal Theory for Permeability Prediction, Venezuelan and USA Wells
NASA Astrophysics Data System (ADS)
Aldana, Milagrosa; Altamiranda, Dignorah; Cabrera, Ana
2014-05-01
Inferring petrophysical parameters such as permeability, porosity, water saturation, capillary pressure, etc, from the analysis of well logs or other available core data has always been of critical importance in the oil industry. Permeability in particular, which is considered to be a complex parameter, has been inferred using both empirical and theoretical techniques. The main goal of this work is to predict permeability values on different wells using Fractal Theory, based on a method proposed by Pape et al. (1999). This approach uses the relationship between permeability and the geometric form of the pore space of the rock. This method is based on the modified equation of Kozeny-Carman and a fractal pattern, which allows determining permeability as a function of the cementation exponent, porosity and the fractal dimension. Data from wells located in Venezuela and the United States of America are analyzed. Employing data of porosity and permeability obtained from core samples, and applying the Fractal Theory method, we calculated the prediction equations for each well. At the beginning, this was achieved by training with 50% of the data available for each well. Afterwards, these equations were tested inferring over 100% of the data to analyze possible trends in their distribution. This procedure gave excellent results in all the wells in spite of their geographic distance, generating permeability models with the potential to accurately predict permeability logs in the remaining parts of the well for which there are no core samples, using even porority logs. Additionally, empirical models were used to determine permeability and the results were compared with those obtained by applying the fractal method. The results indicated that, although there are empirical equations that give a proper adjustment, the prediction results obtained using fractal theory give a better fit to the core reference data.
List, Jeffrey; Benedet, Lindino; Hanes, Daniel M.; Ruggiero, Peter
2009-01-01
Predictions of alongshore transport gradients are critical for forecasting shoreline change. At the previous ICCE conference, it was demonstrated that alongshore transport gradients predicted by the empirical CERC equation can differ substantially from predictions made by the hydrodynamics-based model Delft3D in the case of a simulated borrow pit on the shoreface. Here we use the Delft3D momentum balance to examine the reason for this difference. Alongshore advective flow accelerations in our Delft3D simulation are mainly driven by pressure gradients resulting from alongshore variations in wave height and setup, and Delft3D transport gradients are controlled by these flow accelerations. The CERC equation does not take this process into account, and for this reason a second empirical transport term is sometimes added when alongshore gradients in wave height are thought to be significant. However, our test case indicates that this second term does not properly predict alongshore transport gradients.
Heuristic approach to capillary pressures averaging
DOE Office of Scientific and Technical Information (OSTI.GOV)
Coca, B.P.
1980-10-01
Several methods are available to average capillary pressure curves. Among these are the J-curve and regression equations of the wetting-fluid saturation in porosity and permeability (capillary pressure held constant). While the regression equation seem completely empiric, the J-curve method seems to be theoretically sound due to its expression based on a relation between the average capillary radius and the permeability-porosity ratio. An analysis is given of each of these methods.
Prediction of the Dynamic Yield Strength of Metals Using Two Structural-Temporal Parameters
NASA Astrophysics Data System (ADS)
Selyutina, N. S.; Petrov, Yu. V.
2018-02-01
The behavior of the yield strength of steel and a number of aluminum alloys is investigated in a wide range of strain rates, based on the incubation time criterion of yield and the empirical models of Johnson-Cook and Cowper-Symonds. In this paper, expressions for the parameters of the empirical models are derived through the characteristics of the incubation time criterion; a satisfactory agreement of these data and experimental results is obtained. The parameters of the empirical models can depend on some strain rate. The independence of the characteristics of the incubation time criterion of yield from the loading history and their connection with the structural and temporal features of the plastic deformation process give advantage of the approach based on the concept of incubation time with respect to empirical models and an effective and convenient equation for determining the yield strength in a wider range of strain rates.
NASA Astrophysics Data System (ADS)
Vanini, Seyed Ali Sadough; Abolghasemzadeh, Mohammad; Assadi, Abbas
2013-07-01
Functionally graded steels with graded ferritic and austenitic regions including bainite and martensite intermediate layers produced by electroslag remelting have attracted much attention in recent years. In this article, an empirical model based on the Zener-Hollomon (Z-H) constitutive equation with generalized material constants is presented to investigate the effects of temperature and strain rate on the hot working behavior of functionally graded steels. Next, a theoretical model, generalized by strain compensation, is developed for the flow stress estimation of functionally graded steels under hot compression based on the phase mixture rule and boundary layer characteristics. The model is used for different strains and grading configurations. Specifically, the results for αβγMγ steels from empirical and theoretical models showed excellent agreement with those of experiments of other references within acceptable error.
Shiraishi, Emi; Maeda, Kazuhiro; Kurata, Hiroyuki
2009-02-01
Numerical simulation of differential equation systems plays a major role in the understanding of how metabolic network models generate particular cellular functions. On the other hand, the classical and technical problems for stiff differential equations still remain to be solved, while many elegant algorithms have been presented. To relax the stiffness problem, we propose new practical methods: the gradual update of differential-algebraic equations based on gradual application of the steady-state approximation to stiff differential equations, and the gradual update of the initial values in differential-algebraic equations. These empirical methods show a high efficiency for simulating the steady-state solutions for the stiff differential equations that existing solvers alone cannot solve. They are effective in extending the applicability of dynamic simulation to biochemical network models.
Empirical State Error Covariance Matrix for Batch Estimation
NASA Technical Reports Server (NTRS)
Frisbee, Joe
2015-01-01
State estimation techniques effectively provide mean state estimates. However, the theoretical state error covariance matrices provided as part of these techniques often suffer from a lack of confidence in their ability to describe the uncertainty in the estimated states. By a reinterpretation of the equations involved in the weighted batch least squares algorithm, it is possible to directly arrive at an empirical state error covariance matrix. The proposed empirical state error covariance matrix will contain the effect of all error sources, known or not. This empirical error covariance matrix may be calculated as a side computation for each unique batch solution. Results based on the proposed technique will be presented for a simple, two observer and measurement error only problem.
U.S. ENVIRONMENTAL PROTECTION AGENCY'S LANDFILL GAS EMISSION MODEL (LANDGEM)
The paper discusses EPA's available software for estimating landfill gas emissions. This software is based on a first-order decomposition rate equation using empirical data from U.S. landfills. The software provides a relatively simple approach to estimating landfill gas emissi...
An Empirical State Error Covariance Matrix for the Weighted Least Squares Estimation Method
NASA Technical Reports Server (NTRS)
Frisbee, Joseph H., Jr.
2011-01-01
State estimation techniques effectively provide mean state estimates. However, the theoretical state error covariance matrices provided as part of these techniques often suffer from a lack of confidence in their ability to describe the un-certainty in the estimated states. By a reinterpretation of the equations involved in the weighted least squares algorithm, it is possible to directly arrive at an empirical state error covariance matrix. This proposed empirical state error covariance matrix will contain the effect of all error sources, known or not. Results based on the proposed technique will be presented for a simple, two observer, measurement error only problem.
Design optimization of a brush turbine with a cleaner/water based solution
NASA Technical Reports Server (NTRS)
Kim, Rhyn H.
1995-01-01
Recently, a turbine-brush was analyzed based on the energy conservation and the force momentum equation with an empirical relationship of the drag coefficient. An equation was derived to predict the rotational speed of the turbine-brush in terms of the blade angle, number of blades, rest of geometries of the turbine-brush and the incoming velocity. Using the observed flow conditions, drag coefficients were determined. Based on the experimental values as boundary conditions, the turbine-brush flows were numerically simulated to understand first the nature of the flows, and to extend the observed drag coefficient to a flow without holding the turbine-brush.
NASA Astrophysics Data System (ADS)
Zhang, B.; Tang, H.; Liu, X. Y.; Zhai, X.; Yao, X. C.
2018-01-01
The equilibrium method was used to measure the solubility of gossypol acetic acid and gossypol acetic acid of optical activity in isopropyl alcohol, ethanol, acetic acid and ethyl acetate at temperature from 288.15 to 315.15. The Empirical equation and the Apelblat equation model were adopted to correlate the experimental data. For gossypol acetic acid, the root-mean-square deviations (RMSD) were observed in the range of 0.023-4.979 and 0.0112-0.614 for the Empirical equation and the Apelblat equation, respectively. For gossypol acetic acid of optical activity, the RMSD were observed in the range of 0.021-2.211 and 0.021-2.243 for the Empirical equation and the Apelblat equation, individually. And the maximum relative average deviation was 7.5%. Both equations offered an accurate mathematical expression of the experimental results. The calculated solubility showed a good relationship with the experimental solubility for most of solvents. This study provided valuable datas not only for optimizing the process of purification of gossypol acetic acid of optical activity in industry but also for further theoretical studies.
Sensitivity of viscosity Arrhenius parameters to polarity of liquids
NASA Astrophysics Data System (ADS)
Kacem, R. B. H.; Alzamel, N. O.; Ouerfelli, N.
2017-09-01
Several empirical and semi-empirical equations have been proposed in the literature to estimate the liquid viscosity upon temperature. In this context, this paper aims to study the effect of polarity of liquids on the modeling of the viscosity-temperature dependence, considering particularly the Arrhenius type equations. To achieve this purpose, the solvents are classified into three groups: nonpolar, borderline polar and polar solvents. Based on adequate statistical tests, we found that there is strong evidence that the polarity of solvents affects significantly the distribution of the Arrhenius-type equation parameters and consequently the modeling of the viscosity-temperature dependence. Thus, specific estimated values of parameters for each group of liquids are proposed in this paper. In addition, the comparison of the accuracy of approximation with and without classification of liquids, using the Wilcoxon signed-rank test, shows a significant discrepancy of the borderline polar solvents. For that, we suggested in this paper new specific coefficient values of the simplified Arrhenius-type equation for better estimation accuracy. This result is important given that the accuracy in the estimation of the viscosity-temperature dependence may affect considerably the design and the optimization of several industrial processes.
Sensor fault detection and isolation system for a condensation process.
Castro, M A López; Escobar, R F; Torres, L; Aguilar, J F Gómez; Hernández, J A; Olivares-Peregrino, V H
2016-11-01
This article presents the design of a sensor Fault Detection and Isolation (FDI) system for a condensation process based on a nonlinear model. The condenser is modeled by dynamic and thermodynamic equations. For this work, the dynamic equations are described by three pairs of differential equations which represent the energy balance between the fluids. The thermodynamic equations consist in algebraic heat transfer equations and empirical equations, that allow for the estimation of heat transfer coefficients. The FDI system consists of a bank of two nonlinear high-gain observers, in order to detect, estimate and to isolate the fault in any of both outlet temperature sensors. The main contributions of this work were the experimental validation of the condenser nonlinear model and the FDI system. Copyright © 2016 ISA. Published by Elsevier Ltd. All rights reserved.
Gibbs Sampler-Based λ-Dynamics and Rao-Blackwell Estimator for Alchemical Free Energy Calculation.
Ding, Xinqiang; Vilseck, Jonah Z; Hayes, Ryan L; Brooks, Charles L
2017-06-13
λ-dynamics is a generalized ensemble method for alchemical free energy calculations. In traditional λ-dynamics, the alchemical switch variable λ is treated as a continuous variable ranging from 0 to 1 and an empirical estimator is utilized to approximate the free energy. In the present article, we describe an alternative formulation of λ-dynamics that utilizes the Gibbs sampler framework, which we call Gibbs sampler-based λ-dynamics (GSLD). GSLD, like traditional λ-dynamics, can be readily extended to calculate free energy differences between multiple ligands in one simulation. We also introduce a new free energy estimator, the Rao-Blackwell estimator (RBE), for use in conjunction with GSLD. Compared with the current empirical estimator, the advantage of RBE is that RBE is an unbiased estimator and its variance is usually smaller than the current empirical estimator. We also show that the multistate Bennett acceptance ratio equation or the unbinned weighted histogram analysis method equation can be derived using the RBE. We illustrate the use and performance of this new free energy computational framework by application to a simple harmonic system as well as relevant calculations of small molecule relative free energies of solvation and binding to a protein receptor. Our findings demonstrate consistent and improved performance compared with conventional alchemical free energy methods.
Unleashing Empirical Equations with "Nonlinear Fitting" and "GUM Tree Calculator"
NASA Astrophysics Data System (ADS)
Lovell-Smith, J. W.; Saunders, P.; Feistel, R.
2017-10-01
Empirical equations having large numbers of fitted parameters, such as the international standard reference equations published by the International Association for the Properties of Water and Steam (IAPWS), which form the basis of the "Thermodynamic Equation of Seawater—2010" (TEOS-10), provide the means to calculate many quantities very accurately. The parameters of these equations are found by least-squares fitting to large bodies of measurement data. However, the usefulness of these equations is limited since uncertainties are not readily available for most of the quantities able to be calculated, the covariance of the measurement data is not considered, and further propagation of the uncertainty in the calculated result is restricted since the covariance of calculated quantities is unknown. In this paper, we present two tools developed at MSL that are particularly useful in unleashing the full power of such empirical equations. "Nonlinear Fitting" enables propagation of the covariance of the measurement data into the parameters using generalized least-squares methods. The parameter covariance then may be published along with the equations. Then, when using these large, complex equations, "GUM Tree Calculator" enables the simultaneous calculation of any derived quantity and its uncertainty, by automatic propagation of the parameter covariance into the calculated quantity. We demonstrate these tools in exploratory work to determine and propagate uncertainties associated with the IAPWS-95 parameters.
NASA Astrophysics Data System (ADS)
Lim, Hyungkwang; Kim, Inho; Kim, Jin-Sang; Hwang, Cheol Seong; Jeong, Doo Seok
2013-09-01
Chemical synapses are important components of the large-scaled neural network in the hippocampus of the mammalian brain, and a change in their weight is thought to be in charge of learning and memory. Thus, the realization of artificial chemical synapses is of crucial importance in achieving artificial neural networks emulating the brain’s functionalities to some extent. This kind of research is often referred to as neuromorphic engineering. In this study, we report short-term memory behaviours of electrochemical capacitors (ECs) utilizing TiO2 mixed ionic-electronic conductor and various reactive electrode materials e.g. Ti, Ni, and Cr. By experiments, it turned out that the potentiation behaviours did not represent unlimited growth of synaptic weight. Instead, the behaviours exhibited limited synaptic weight growth that can be understood by means of an empirical equation similar to the Bienenstock-Cooper-Munro rule, employing a sliding threshold. The observed potentiation behaviours were analysed using the empirical equation and the differences between the different ECs were parameterized.
De Vries, Rowen J; Marsh, Steven
2015-11-08
Internal lead shielding is utilized during superficial electron beam treatments of the head and neck, such as lip carcinoma. Methods for predicting backscattered dose include the use of empirical equations or performing physical measurements. The accuracy of these empirical equations required verification for the local electron beams. In this study, a Monte Carlo model of a Siemens Artiste linac was developed for 6, 9, 12, and 15 MeV electron beams using the EGSnrc MC package. The model was verified against physical measurements to an accuracy of better than 2% and 2mm. Multiple MC simulations of lead interfaces at different depths, corresponding to mean electron energies in the range of 0.2-14 MeV at the interfaces, were performed to calculate electron backscatter values. The simulated electron backscatter was compared with current empirical equations to ascertain their accuracy. The major finding was that the current set of backscatter equations does not accurately predict electron backscatter, particularly in the lower energies region. A new equation was derived which enables estimation of electron backscatter factor at any depth upstream from the interface for the local treatment machines. The derived equation agreed to within 1.5% of the MC simulated electron backscatter at the lead interface and upstream positions. Verification of the equation was performed by comparing to measurements of the electron backscatter factor using Gafchromic EBT2 film. These results show a mean value of 0.997 ± 0.022 to 1σ of the predicted values of electron backscatter. The new empirical equation presented can accurately estimate electron backscatter factor from lead shielding in the range of 0.2 to 14 MeV for the local linacs.
Marsh, Steven
2015-01-01
Internal lead shielding is utilized during superficial electron beam treatments of the head and neck, such as lip carcinoma. Methods for predicting backscattered dose include the use of empirical equations or performing physical measurements. The accuracy of these empirical equations required verification for the local electron beams. In this study, a Monte Carlo model of a Siemens Artiste linac was developed for 6, 9, 12, and 15 MeV electron beams using the EGSnrc MC package. The model was verified against physical measurements to an accuracy of better than 2% and 2 mm. Multiple MC simulations of lead interfaces at different depths, corresponding to mean electron energies in the range of 0.2–14 MeV at the interfaces, were performed to calculate electron backscatter values. The simulated electron backscatter was compared with current empirical equations to ascertain their accuracy. The major finding was that the current set of backscatter equations does not accurately predict electron backscatter, particularly in the lower energies region. A new equation was derived which enables estimation of electron backscatter factor at any depth upstream from the interface for the local treatment machines. The derived equation agreed to within 1.5% of the MC simulated electron backscatter at the lead interface and upstream positions. Verification of the equation was performed by comparing to measurements of the electron backscatter factor using Gafchromic EBT2 film. These results show a mean value of 0.997±0.022 to 1σ of the predicted values of electron backscatter. The new empirical equation presented can accurately estimate electron backscatter factor from lead shielding in the range of 0.2 to 14 MeV for the local linacs. PACS numbers: 87.53.Bn, 87.55.K‐, 87.56.bd PMID:26699566
USING MICROSOFT OFFICE EXCEL® 2007 TO CONDUCT GENERALIZED MATCHING ANALYSES
Reed, Derek D
2009-01-01
The generalized matching equation is a robust and empirically supported means of analyzing relations between reinforcement and behavior. Unfortunately, no simple task analysis is available to behavior analysts interested in using the matching equation to evaluate data in clinical or applied settings. This technical article presents a task analysis for the use of Microsoft Excel to analyze and plot the generalized matching equation. Using a data-based case example and a step-by-step guide for completing the analysis, these instructions are intended to promote the use of quantitative analyses by researchers with little to no experience in quantitative analyses or the matching law. PMID:20514196
Using Microsoft Office Excel 2007 to conduct generalized matching analyses.
Reed, Derek D
2009-01-01
The generalized matching equation is a robust and empirically supported means of analyzing relations between reinforcement and behavior. Unfortunately, no simple task analysis is available to behavior analysts interested in using the matching equation to evaluate data in clinical or applied settings. This technical article presents a task analysis for the use of Microsoft Excel to analyze and plot the generalized matching equation. Using a data-based case example and a step-by-step guide for completing the analysis, these instructions are intended to promote the use of quantitative analyses by researchers with little to no experience in quantitative analyses or the matching law.
An Attempt to Derive the epsilon Equation from a Two-Point Closure
NASA Technical Reports Server (NTRS)
Canuto, V. M.; Cheng, Y.; Howard, A. M.
2010-01-01
The goal of this paper is to derive the equation for the turbulence dissipation rate epsilon for a shear-driven flow. In 1961, Davydov used a one-point closure model to derive the epsilon equation from first principles but the final result contained undetermined terms and thus lacked predictive power. Both in 1987 and in 2001, attempts were made to derive the epsilon equation from first principles using a two-point closure, but their methods relied on a phenomenological assumption. The standard practice has thus been to employ a heuristic form of the equation that contains three empirical ingredients: two constants, c(sub 1 epsilon), and c(sub 2 epsilon), and a diffusion term D(sub epsilon) In this work, a two-point closure is employed, yielding the following results: 1) the empirical constants get replaced by c(sub 1), c(sub 2), which are now functions of Kappa and epsilon; 2) c(sub 1) and c(sub 2) are not independent because a general relation between the two that are valid for any Kappa and epsilon are derived; 3) c(sub 1), c(sub 2) become constant with values close to the empirical values c(sub 1 epsilon), c(sub epsilon 2), (i.e., homogenous flows); and 4) the empirical form of the diffusion term D(sub epsilon) is no longer needed because it gets substituted by the Kappa-epsilon dependence of c(sub 1), c(sub 2), which plays the role of the diffusion, together with the diffusion of the turbulent kinetic energy D(sub Kappa), which now enters the new equation (i.e., inhomogeneous flows). Thus, the three empirical ingredients c(sub 1 epsilon), c(sub epsilon 2), D (sub epsilon)are replaced by a single function c(sub 1)(Kappa, epsilon ) or c(sub 2)(Kappa, epsilon ), plus a D(sub Kappa)term. Three tests of the new equation for epsilon are presented: one concerning channel flow and two concerning the shear-driven planetary boundary layer (PBL).
Modifying Bagnold's Sediment Transport Equation for Use in Watershed-Scale Channel Incision Models
NASA Astrophysics Data System (ADS)
Lammers, R. W.; Bledsoe, B. P.
2016-12-01
Destabilized stream channels may evolve through a sequence of stages, initiated by bed incision and followed by bank erosion and widening. Channel incision can be modeled using Exner-type mass balance equations, but model accuracy is limited by the accuracy and applicability of the selected sediment transport equation. Additionally, many sediment transport relationships require significant data inputs, limiting their usefulness in data-poor environments. Bagnold's empirical relationship for bedload transport is attractive because it is based on stream power, a relatively straightforward parameter to estimate using remote sensing data. However, the equation is also dependent on flow depth, which is more difficult to measure or estimate for entire drainage networks. We recast Bagnold's original sediment transport equation using specific discharge in place of flow depth. Using a large dataset of sediment transport rates from the literature, we show that this approach yields similar predictive accuracy as other stream power based relationships. We also explore the applicability of various critical stream power equations, including Bagnold's original, and support previous conclusions that these critical values can be predicted well based solely on sediment grain size. In addition, we propagate error in these sediment transport equations through channel incision modeling to compare the errors associated with our equation to alternative formulations. This new version of Bagnold's bedload transport equation has utility for channel incision modeling at larger spatial scales using widely available and remote sensing data.
Establishing an Explanatory Model for Mathematics Identity
ERIC Educational Resources Information Center
Cribbs, Jennifer D.; Hazari, Zahra; Sonnert, Gerhard; Sadler, Philip M.
2015-01-01
This article empirically tests a previously developed theoretical framework for mathematics identity based on students' beliefs. The study employs data from more than 9,000 college calculus students across the United States to build a robust structural equation model. While it is generally thought that students' beliefs about their own competence…
Kepner, Gordon R
2014-08-27
This study uses dimensional analysis to derive the general second-order differential equation that underlies numerous physical and natural phenomena described by common mathematical functions. It eschews assumptions about empirical constants and mechanisms. It relies only on the data plot's mathematical properties to provide the conditions and constraints needed to specify a second-order differential equation that is free of empirical constants for each phenomenon. A practical example of each function is analyzed using the general form of the underlying differential equation and the observable unique mathematical properties of each data plot, including boundary conditions. This yields a differential equation that describes the relationship among the physical variables governing the phenomenon's behavior. Complex phenomena such as the Standard Normal Distribution, the Logistic Growth Function, and Hill Ligand binding, which are characterized by data plots of distinctly different sigmoidal character, are readily analyzed by this approach. It provides an alternative, simple, unifying basis for analyzing each of these varied phenomena from a common perspective that ties them together and offers new insights into the appropriate empirical constants for describing each phenomenon.
How Darcy's equation is linked to the linear reservoir at catchment scale
NASA Astrophysics Data System (ADS)
Savenije, Hubert H. G.
2017-04-01
In groundwater hydrology two simple linear equations exist that describe the relation between groundwater flow and the gradient that drives it: Darcy's equation and the linear reservoir. Both equations are empirical at heart: Darcy's equation at the laboratory scale and the linear reservoir at the watershed scale. Although at first sight they show similarity, without having detailed knowledge of the structure of the underlying aquifers it is not trivial to upscale Darcy's equation to the watershed scale. In this paper, a relatively simple connection is provided between the two, based on the assumption that the groundwater system is organized by an efficient drainage network, a mostly invisible pattern that has evolved over geological time scales. This drainage network provides equally distributed resistance to flow along the streamlines that connect the active groundwater body to the stream, much like a leaf is organized to provide all stomata access to moisture at equal resistance.
Hao, Tian
2015-02-28
The tap density of a granular powder is often linked to the flowability via the Carr index that measures how tight a powder can be packed, under an assumption that more easily packed powders usually flow poorly. Understanding how particles are packed is important for revealing why a powder flows better than others. There are two types of empirical equations that were proposed to fit the experimental data of packing fractions vs. numbers of taps in the literature: the inverse logarithmic and the stretched exponential. Using the rate process theory and the free volume concept under the assumption that particles will obey similar thermodynamic laws during the tapping process if the "granular temperature" is defined in a different way, we obtain the tap density equations, and they are reducible to the two empirical equations currently widely used in literature. Our equations could potentially fit experimental data better with an additional adjustable parameter. The tapping amplitude and frequency, the weight of the granular materials, and the environmental temperature are grouped into this parameter that weighs the pace of the packing process. The current results, in conjunction with our previous findings, may imply that both "dry" (granular) and "wet" (colloidal and polymeric) particle systems are governed by the same physical mechanisms in term of the role of the free volume and how particles behave (a rate controlled process).
NASA Astrophysics Data System (ADS)
Kamajaya, Ketut; Umar, Efrizon; Sudjatmi, K. S.
2012-06-01
This study focused on natural convection heat transfer using a vertical rectangular sub-channel and water as the coolant fluid. To conduct this study has been made pipe heaters are equipped with thermocouples. Each heater is equipped with five thermocouples along the heating pipes. The diameter of each heater is 2.54 cm and 45 cm in length. The distance between the central heating and the pitch is 29.5 cm. Test equipment is equipped with a primary cooling system, a secondary cooling system and a heat exchanger. The purpose of this study is to obtain new empirical correlations equations of the vertical rectangular sub-channel, especially for the natural convection heat transfer within a bundle of vertical cylinders rectangular arrangement sub-channels. The empirical correlation equation can support the thermo-hydraulic analysis of research nuclear reactors that utilize cylindrical fuel rods, and also can be used in designing of baffle-free vertical shell and tube heat exchangers. The results of this study that the empirical correlation equations of natural convection heat transfer coefficients with rectangular arrangement is Nu = 6.3357 (Ra.Dh/x)0.0740.
An analysis of bedload and suspended load interactions
NASA Astrophysics Data System (ADS)
Recking, alain; Navratil, Oldrich
2013-04-01
Several approaches were used to develop suspension equations. It includes semi-theoretical equations based on the convection diffusion equation (Einstein 1950; Van Rijn 1984; Camenen and Larson 2008; Julien 2010), semi-empirical tools based on energy concept (Velikanov 1954; Bagnold 1966), empirical adjustments (Prosser and Rusttomji 2000). One essential characteristic of all these equations is that most of them were developed by considering continuity between bedload and suspended load, and that the partitioning between these two modes of transport evolves progressively with increasing shear stress, which is the case for fine bed materials. The use of these equations is thus likely to be welcome in estuaries or lowland sandy rivers, but may be questionable in gravel-bed rivers and headwater streams where the bed is usually structured vertically and fine sediments potentially contributing to suspension are stored under a poorly mobile surface armour comprising coarse sediments. Thus one question this work aimed to answer is does the presence of an armour at the bed surface influence suspended load? This was investigated through a large field data set comprising instantaneous measurements of both bedload and suspension. We also considered the river characteristics, distinguishing between lowland rivers, gravel bed rivers and headwater streams. The results showed that a correlation exist between bedload and suspension for lowland and gravel bed rivers. This suggests that in gravel bed rivers a large part of the suspended load is fed by subsurface material, and depends on the remobilization of the surface material. No correlation was observed for head water streams where the sediment production is more likely related to hillslope processes. These results were used with a bedload transport equation for proposing a method for suspended load estimate. The method is rough, but especially for gravel bed rivers, it predicts suspended load reasonably well when compared to standard convection diffusion equations.
A root-mean-square pressure fluctuations model for internal flow applications
NASA Technical Reports Server (NTRS)
Chen, Y. S.
1985-01-01
A transport equation for the root-mean-square pressure fluctuations of turbulent flow is derived from the time-dependent momentum equation for incompressible flow. Approximate modeling of this transport equation is included to relate terms with higher order correlations to the mean quantities of turbulent flow. Three empirical constants are introduced in the model. Two of the empirical constants are estimated from homogeneous turbulence data and wall pressure fluctuations measurements. The third constant is determined by comparing the results of large eddy simulations for a plane channel flow and an annulus flow.
The consentaneous model of the financial markets exhibiting spurious nature of long-range memory
NASA Astrophysics Data System (ADS)
Gontis, V.; Kononovicius, A.
2018-09-01
It is widely accepted that there is strong persistence in the volatility of financial time series. The origin of the observed persistence, or long-range memory, is still an open problem as the observed phenomenon could be a spurious effect. Earlier we have proposed the consentaneous model of the financial markets based on the non-linear stochastic differential equations. The consentaneous model successfully reproduces empirical probability and power spectral densities of volatility. This approach is qualitatively different from models built using fractional Brownian motion. In this contribution we investigate burst and inter-burst duration statistics of volatility in the financial markets employing the consentaneous model. Our analysis provides an evidence that empirical statistical properties of burst and inter-burst duration can be explained by non-linear stochastic differential equations driving the volatility in the financial markets. This serves as an strong argument that long-range memory in finance can have spurious nature.
Modeling of a stacked-screen regenerator in an oscillatory flow
NASA Astrophysics Data System (ADS)
Hsu, Shu Han; Biwa, Tetsushi
2017-01-01
In this paper, we model tortuous flow channels of a stacked-screen regenerator as a bundle of cylindrical tubes to analyze and design thermoacoustic Stirling engines. The oscillatory flow resistance of stacked-screen regenerators is measured and compared with those obtained using empirical equations to verify the applicability of those empirical equations to oscillating flows of pressurized Ar and He gases. It is then converted to an effective radius parameterized by Re h and r 0/δν, where Re h represents the Reynolds number based on velocity oscillation amplitude, r 0 is Ueda’s effective radius ( = \\sqrt{d\\text{h}D} /2, where d h is the hydraulic diameter and D is the mesh wire diameter), and δν denotes the viscous penetration depth. The applicability of the proposed effective radius is demonstrated experimentally when the axial temperature gradient is imposed on the regenerator.
ERIC Educational Resources Information Center
Chen, Greg; Weikart, Lynne A.
2008-01-01
This study develops and tests a school disorder and student achievement model based upon the school climate framework. The model was fitted to 212 New York City middle schools using the Structural Equations Modeling Analysis method. The analysis shows that the model fits the data well based upon test statistics and goodness of fit indices. The…
Maclean, Brendan; Tomazela, Daniela M; Abbatiello, Susan E; Zhang, Shucha; Whiteaker, Jeffrey R; Paulovich, Amanda G; Carr, Steven A; Maccoss, Michael J
2010-12-15
Proteomics experiments based on Selected Reaction Monitoring (SRM, also referred to as Multiple Reaction Monitoring or MRM) are being used to target large numbers of protein candidates in complex mixtures. At present, instrument parameters are often optimized for each peptide, a time and resource intensive process. Large SRM experiments are greatly facilitated by having the ability to predict MS instrument parameters that work well with the broad diversity of peptides they target. For this reason, we investigated the impact of using simple linear equations to predict the collision energy (CE) on peptide signal intensity and compared it with the empirical optimization of the CE for each peptide and transition individually. Using optimized linear equations, the difference between predicted and empirically derived CE values was found to be an average gain of only 7.8% of total peak area. We also found that existing commonly used linear equations fall short of their potential, and should be recalculated for each charge state and when introducing new instrument platforms. We provide a fully automated pipeline for calculating these equations and individually optimizing CE of each transition on SRM instruments from Agilent, Applied Biosystems, Thermo-Scientific and Waters in the open source Skyline software tool ( http://proteome.gs.washington.edu/software/skyline ).
Arvanitis, Spyros; Loukis, Euripidis N
2016-05-01
Hospitals are making big investments in various types of ICT, so it is important to investigate their effects on innovation and performance. This paper presents an empirical study in this direction, based on data for 743 hospitals from 18 European countries. We specified and estimated econometrically five equations: one for product innovation, one for process innovation and three equations for the three different dimensions of (ICT-enabled) hospital performance. All five equations included various ICT-related variables reflecting ICT infrastructure and a series of important ICT applications, some of them hospital-specific, and some others of general business use, and also ICT personnel (viewed as a kind of 'soft' ICT investment), while the performance equations also included the two innovation measures.
Braking the bandwagon: scrutinizing the science and politics of empirically supported therapies.
Hagemoser, Steven D
2009-12-01
Proponents of empirically supported therapies (ESTs) argue that because manualized ESTs have demonstrated efficacy in treating a range of psychological disorders, they should be the treatments of choice. In this article, the author uses a hypothetical treatment for obesity to highlight numerous flaws in EST logic and argues for common factors as a more clinically relevant but empirically challenging approach. The author then explores how political variables may be contributing to the expansion of EST and the resulting restriction of practitioner autonomy. Last, the author argues that EST is best viewed as 1 component of a more comprehensive evidence-based practice framework. The author concludes with some cautionary statements about the perils of equating the EST paradigm with the scientist-practitioner ideal.
Simulation studies of chemical erosion on carbon based materials at elevated temperatures
NASA Astrophysics Data System (ADS)
Kenmotsu, T.; Kawamura, T.; Li, Zhijie; Ono, T.; Yamamura, Y.
1999-06-01
We simulated the fluence dependence of methane reaction yield in carbon with hydrogen bombardment using the ACAT-DIFFUSE code. The ACAT-DIFFUSE code is a simulation code based on a Monte Carlo method with a binary collision approximation and on solving diffusion equations. The chemical reaction model in carbon was studied by Roth or other researchers. Roth's model is suitable for the steady state methane reaction. But this model cannot estimate the fluence dependence of the methane reaction. Then, we derived an empirical formula based on Roth's model for methane reaction. In this empirical formula, we assumed the reaction region where chemical sputtering due to methane formation takes place. The reaction region corresponds to the peak range of incident hydrogen distribution in the target material. We adopted this empirical formula to the ACAT-DIFFUSE code. The simulation results indicate the similar fluence dependence compared with the experiment result. But, the fluence to achieve the steady state are different between experiment and simulation results.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jung, Jinwoo; Lee, Jewon; Song, Hanjung
2011-03-15
This paper presents a fully integrated circuit implementation of an operational amplifier (op-amp) based chaotic neuron model with a bipolar output function, experimental measurements, and analyses of its chaotic behavior. The proposed chaotic neuron model integrated circuit consists of several op-amps, sample and hold circuits, a nonlinear function block for chaotic signal generation, a clock generator, a nonlinear output function, etc. Based on the HSPICE (circuit program) simulation results, approximated empirical equations for analyses were formulated. Then, the chaotic dynamical responses such as bifurcation diagrams, time series, and Lyapunov exponent were calculated using these empirical equations. In addition, we performedmore » simulations about two chaotic neuron systems with four synapses to confirm neural network connections and got normal behavior of the chaotic neuron such as internal state bifurcation diagram according to the synaptic weight variation. The proposed circuit was fabricated using a 0.8-{mu}m single poly complementary metal-oxide semiconductor technology. Measurements of the fabricated single chaotic neuron with {+-}2.5 V power supplies and a 10 kHz sampling clock frequency were carried out and compared with the simulated results.« less
Soil loss is commonly estimated using the Revised Universal Soil Loss Equation (RUSLE). Since RUSLE is an empirically based soil loss model derived from surveys on plots, the high spatial and temporal variability of erosion in Mediterranean environments and scale effects provoke...
ERIC Educational Resources Information Center
Ali, Muhammad; Raza, Syed Ali; Qazi, Wasim; Puah, Chin-Hong
2018-01-01
Purpose: This study aims to examine university students' acceptance of e-learning systems in Pakistan. A Web-based learning system is a new form of utilizing technological features. Although, developed countries have initiated and established the concept for e-learning, developing countries require empirical support to implement e-learning.…
Applications of Nonlinear Principal Components Analysis to Behavioral Data.
ERIC Educational Resources Information Center
Hicks, Marilyn Maginley
1981-01-01
An empirical investigation of the statistical procedure entitled nonlinear principal components analysis was conducted on a known equation and on measurement data in order to demonstrate the procedure and examine its potential usefulness. This method was suggested by R. Gnanadesikan and based on an early paper of Karl Pearson. (Author/AL)
Soil loss is commonly estimated using the Revised Universal Soil Loss Equation (RUSLE). Since RUSLE is an empirically based soil loss model derived from surveys on plots, the high spatial and temporal variability of erosion in Mediterranean environments and scale effects provo...
How to Teach Recycling at an Advanced Phase of Diffusion
ERIC Educational Resources Information Center
Meneses, Gonzalo Diaz
2006-01-01
The author conducted an empirical study based on structural equation modeling with a convenience sample of 246 individuals with the goal of demonstrating that recycling behavior is a routine conduct and should be addressed as such in educational materials. Although the classic hierarchy of effects dominates the interpretation of recycling behavior…
NASA Astrophysics Data System (ADS)
Sudibyo, Aziz, N.
2016-02-01
One of the available methods to solve a roughening in cobalt electrodeposition is magneto electrodeposition (MED) in the presence of additive electrolyte. Semi-empirical equation of limiting current under a magnetic field for cobalt MED in the presence of boric acid as an additive electrolyte was successfully developed. This semi empirical equation shows the effects of the electrode area (A), the concentration of the electro active species (C), the diffusion coefficient of the electro active species (D), the kinematic viscosity of the electrolyte (v), magnetic strength (B) and the number of electrons involved in the redox process (n). The presence of boric acid led to decrease in the limiting current, but the acid was found useful as a buffer to avoid the local pH rise caused by parallel hydrogen evolution reaction (HER).
NASA Astrophysics Data System (ADS)
Wharmby, Andrew William
Existing fractional calculus models having a non-empirical basis used to describe constitutive relationships between stress and strain in viscoelastic materials are modified to employ all orders of fractional derivatives between zero and one. Parallels between viscoelastic and dielectric theory are drawn so that these modified fractional calculus based models for viscoelastic materials may be used to describe relationships between electric flux density and electric field intensity in dielectric materials. The resulting fractional calculus based dielectric relaxation model is tested using existing complex permittivity data in the radio-frequency bandwidth of a wide variety of homogeneous materials. The consequences that the application of this newly developed fractional calculus based dielectric relaxation model has on Maxwell's equations are also examined through the effects of dielectric dissipation and dispersion.
An alternative method for centrifugal compressor loading factor modelling
NASA Astrophysics Data System (ADS)
Galerkin, Y.; Drozdov, A.; Rekstin, A.; Soldatova, K.
2017-08-01
The loading factor at design point is calculated by one or other empirical formula in classical design methods. Performance modelling as a whole is out of consideration. Test data of compressor stages demonstrates that loading factor versus flow coefficient at the impeller exit has a linear character independent of compressibility. Known Universal Modelling Method exploits this fact. Two points define the function - loading factor at design point and at zero flow rate. The proper formulae include empirical coefficients. A good modelling result is possible if the choice of coefficients is based on experience and close analogs. Earlier Y. Galerkin and K. Soldatova had proposed to define loading factor performance by the angle of its inclination to the ordinate axis and by the loading factor at zero flow rate. Simple and definite equations with four geometry parameters were proposed for loading factor performance calculated for inviscid flow. The authors of this publication have studied the test performance of thirteen stages of different types. The equations are proposed with universal empirical coefficients. The calculation error lies in the range of plus to minus 1,5%. The alternative model of a loading factor performance modelling is included in new versions of the Universal Modelling Method.
A five-step procedure for the clinical use of the MPD in neuropsychological assessment of children.
Wallbrown, F H; Fuller, G B
1984-01-01
Described a five-step procedure that can be used to detect organicity on the basis of children's performance on the Minnesota Percepto Diagnostic Test (MPD). The first step consists of examining the T score for rotations to determine whether it is below the cut-off score, which has been established empirically as an indicator of organicity. The second step consists of matching the examinee's configuration of error scores, separation of circle-diamond (SpCD), distortion of circle-diamond (DCD), and distortion of dots (DD), with empirically derived tables. The third step consists of considering the T score for rotations and error configuration jointly. The fourth step consists of using empirically established discriminant equations, and the fifth step involves using data from limits testing and other data sources. The clinical and empirical bases for the five-step procedure also are discussed.
Saygın, Selen Deviren; Basaran, Mustafa; Ozcan, Ali Ugur; Dolarslan, Melda; Timur, Ozgur Burhan; Yilman, F Ebru; Erpul, Gunay
2011-09-01
Land degradation by soil erosion is one of the most serious problems and environmental issues in many ecosystems of arid and semi-arid regions. Especially, the disturbed areas have greater soil detachability and transportability capacity. Evaluation of land degradation in terms of soil erodibility, by using geostatistical modeling, is vital to protect and reclaim susceptible areas. Soil erodibility, described as the ability of soils to resist erosion, can be measured either directly under natural or simulated rainfall conditions, or indirectly estimated by empirical regression models. This study compares three empirical equations used to determine the soil erodibility factor of revised universal soil loss equation prediction technology based on their geospatial performances in the semi-arid catchment of the Saraykoy II Irrigation Dam located in Cankiri, Turkey. A total of 311 geo-referenced soil samples were collected with irregular intervals from the top soil layer (0-10 cm). Geostatistical analysis was performed with the point values of each equation to determine its spatial pattern. Results showed that equations that used soil organic matter in combination with the soil particle size better agreed with the variations in land use and topography of the catchment than the one using only the particle size distribution. It is recommended that the equations which dynamically integrate soil intrinsic properties with land use, topography, and its influences on the local microclimates, could be successfully used to geospatially determine sites highly susceptible to water erosion, and therefore, to select the agricultural and bio-engineering control measures needed.
Small-Sample Equating with Prior Information. Research Report. ETS RR-09-25
ERIC Educational Resources Information Center
Livingston, Samuel A.; Lewis, Charles
2009-01-01
This report proposes an empirical Bayes approach to the problem of equating scores on test forms taken by very small numbers of test takers. The equated score is estimated separately at each score point, making it unnecessary to model either the score distribution or the equating transformation. Prior information comes from equatings of other…
Towards an Airframe Noise Prediction Methodology: Survey of Current Approaches
NASA Technical Reports Server (NTRS)
Farassat, Fereidoun; Casper, Jay H.
2006-01-01
In this paper, we present a critical survey of the current airframe noise (AFN) prediction methodologies. Four methodologies are recognized. These are the fully analytic method, CFD combined with the acoustic analogy, the semi-empirical method and fully numerical method. It is argued that for the immediate need of the aircraft industry, the semi-empirical method based on recent high quality acoustic database is the best available method. The method based on CFD and the Ffowcs William- Hawkings (FW-H) equation with penetrable data surface (FW-Hpds ) has advanced considerably and much experience has been gained in its use. However, more research is needed in the near future particularly in the area of turbulence simulation. The fully numerical method will take longer to reach maturity. Based on the current trends, it is predicted that this method will eventually develop into the method of choice. Both the turbulence simulation and propagation methods need to develop more for this method to become useful. Nonetheless, the authors propose that the method based on a combination of numerical and analytical techniques, e.g., CFD combined with FW-H equation, should also be worked on. In this effort, the current symbolic algebra software will allow more analytical approaches to be incorporated into AFN prediction methods.
Relations for estimating unit-hydrograph parameters in New Mexico
Waltemeyer, Scott D.
2001-01-01
Data collected from 20 U.S. Geological Survey streamflow-gaging stations, most of which were operated in New Mexico between about 1969 and 1977, were used to define hydrograph characteristics for small New Mexico streams. Drainage areas for the gaging stations ranged from 0.23 to 18.2 square miles. Observed values for the hydrograph characteristics were determined for 87 of the most significant rainfall-runoff events at these gaging stations and were used to define regional regression relations with basin characteristics. Regional relations defined lag time (tl), time of concentration (tc), and time to peak (tp) as functions of stream length and basin shape. The regional equation developed for time of concentration for New Mexico agrees well with the Kirpich equation developed for Tennessee. The Kirpich equation is based on stream length and channel slope, whereas the New Mexico equation is based on stream length and basin shape. Both equations, however, underestimate tc when applied to larger basins where tc is greater than about 2 hours. The median ratio between tp and tc for the observed data was 0.66, which equals the value (0.67) recommended by the Natural Resources Conservation Service (formerly the Soil Conservation Service). However, the median ratio between tl and tc was only 0.42, whereas the commonly used ratio is 0.60. A relation also was developed between unit-peak discharge (qu) and time of concentration. The unit-peak discharge relation is similar in slope to the Natural Resources Conservation Service equation, but the equation developed for New Mexico in this study produces estimates of qu that range from two to three times as large as those estimated from the Natural Resources Conservation Service equation. An average value of 833 was determined for the empirical constant Kp. A default value of 484 has been used by the Natural Resources Conservation Service when site-specific data are not available. The use of a lower value of Kp in calculations generally results in a lower peak discharge. A relation between the empirical constant Kp and average channel slope was defined in this study. The predicted Kp values from the equation ranged from 530 to 964 for the 20 flood-hydrograph gaging stations. The standard error of estimate for the equation is 36 percent.
ERIC Educational Resources Information Center
Huang, Wenhao David; Johnson, Tristan E.; Han, Seung-Hyun Caleb
2013-01-01
Colleges and universities have begun to understand the instructional potential of digital game-based learning (DGBL) due to digital games' immersive features. These features, however, might overload learners as excessive motivational and cognitive stimuli thus impeding intended learning. Current research, however, lacks empirical evidences to…
Aaron Weiskittel; Jereme Frank; David Walker; Phil Radtke; David Macfarlane; James Westfall
2015-01-01
Prediction of forest biomass and carbon is becoming important issues in the United States. However, estimating forest biomass and carbon is difficult and relies on empirically-derived regression equations. Based on recent findings from a national gap analysis and comprehensive assessment of the USDA Forest Service Forest Inventory and Analysis (USFS-FIA) component...
St. Lawrence River Freeze-Up Forecast Procedure.
ERIC Educational Resources Information Center
Assel, R. A.
A standard operating procedure (SOP) is presented for calculating the date of freeze-up on the St. Lawrence River at Massena, N.Y. The SOP is based on two empirical temperature decline equations developed for Kingston, Ontario, and Massena, N.Y., respectively. Input data needed to forecast freeze-up consist of the forecast December flow rate and…
TEACHING PHYSICS: Biking around a hollow sphere
NASA Astrophysics Data System (ADS)
Mak, Se-yuen; Yip, Din-yan
1999-11-01
The conditions required for a cyclist riding a motorbike in a horizontal circle on or above the equator of a hollow sphere are derived using concepts of equilibrium and the condition for uniform circular motion. The result is compared with an empirical analysis based on a video show. Some special cases of interest derived from the general solution are elaborated.
Uncertainty Analysis in Humidity Measurements by the Psychrometer Method
Chen, Jiunyuan; Chen, Chiachung
2017-01-01
The most common and cheap indirect technique to measure relative humidity is by using psychrometer based on a dry and a wet temperature sensor. In this study, the measurement uncertainty of relative humidity was evaluated by this indirect method with some empirical equations for calculating relative humidity. Among the six equations tested, the Penman equation had the best predictive ability for the dry bulb temperature range of 15–50 °C. At a fixed dry bulb temperature, an increase in the wet bulb depression increased the error. A new equation for the psychrometer constant was established by regression analysis. This equation can be computed by using a calculator. The average predictive error of relative humidity was <0.1% by this new equation. The measurement uncertainty of the relative humidity affected by the accuracy of dry and wet bulb temperature and the numeric values of measurement uncertainty were evaluated for various conditions. The uncertainty of wet bulb temperature was the main factor on the RH measurement uncertainty. PMID:28216599
Uncertainty Analysis in Humidity Measurements by the Psychrometer Method.
Chen, Jiunyuan; Chen, Chiachung
2017-02-14
The most common and cheap indirect technique to measure relative humidity is by using psychrometer based on a dry and a wet temperature sensor. In this study, the measurement uncertainty of relative humidity was evaluated by this indirect method with some empirical equations for calculating relative humidity. Among the six equations tested, the Penman equation had the best predictive ability for the dry bulb temperature range of 15-50 °C. At a fixed dry bulb temperature, an increase in the wet bulb depression increased the error. A new equation for the psychrometer constant was established by regression analysis. This equation can be computed by using a calculator. The average predictive error of relative humidity was <0.1% by this new equation. The measurement uncertainty of the relative humidity affected by the accuracy of dry and wet bulb temperature and the numeric values of measurement uncertainty were evaluated for various conditions. The uncertainty of wet bulb temperature was the main factor on the RH measurement uncertainty.
Quantifying the driving factors for language shift in a bilingual region.
Prochazka, Katharina; Vogl, Gero
2017-04-25
Many of the world's around 6,000 languages are in danger of disappearing as people give up use of a minority language in favor of the majority language in a process called language shift. Language shift can be monitored on a large scale through the use of mathematical models by way of differential equations, for example, reaction-diffusion equations. Here, we use a different approach: we propose a model for language dynamics based on the principles of cellular automata/agent-based modeling and combine it with very detailed empirical data. Our model makes it possible to follow language dynamics over space and time, whereas existing models based on differential equations average over space and consequently provide no information on local changes in language use. Additionally, cellular automata models can be used even in cases where models based on differential equations are not applicable, for example, in situations where one language has become dispersed and retreated to language islands. Using data from a bilingual region in Austria, we show that the most important factor in determining the spread and retreat of a language is the interaction with speakers of the same language. External factors like bilingual schools or parish language have only a minor influence.
NASA Astrophysics Data System (ADS)
Zhang, Zhilin; Savenije, Hubert H. G.
2017-07-01
The practical value of the surprisingly simple Van der Burgh equation in predicting saline water intrusion in alluvial estuaries is well documented, but the physical foundation of the equation is still weak. In this paper we provide a connection between the empirical equation and the theoretical literature, leading to a theoretical range of Van der Burgh's coefficient of 1/2 < K < 2/3 for density-driven mixing which falls within the feasible range of 0 < K < 1. In addition, we developed a one-dimensional predictive equation for the dispersion of salinity as a function of local hydraulic parameters that can vary along the estuary axis, including mixing due to tide-driven residual circulation. This type of mixing is relevant in the wider part of alluvial estuaries where preferential ebb and flood channels appear. Subsequently, this dispersion equation is combined with the salt balance equation to obtain a new predictive analytical equation for the longitudinal salinity distribution. Finally, the new equation was tested and applied to a large database of observations in alluvial estuaries, whereby the calibrated K values appeared to correspond well to the theoretical range.
NASA Astrophysics Data System (ADS)
Mia, Mozammel; Al Bashir, Mahmood; Dhar, Nikhil Ranjan
2016-10-01
Hard turning is increasingly employed in machining, lately, to replace time-consuming conventional turning followed by grinding process. An excessive amount of tool wear in hard turning is one of the main hurdles to be overcome. Many researchers have developed tool wear model, but most of them developed it for a particular work-tool-environment combination. No aggregate model is developed that can be used to predict the amount of principal flank wear for specific machining time. An empirical model of principal flank wear (VB) has been developed for the different hardness of workpiece (HRC40, HRC48 and HRC56) while turning by coated carbide insert with different configurations (SNMM and SNMG) under both dry and high pressure coolant conditions. Unlike other developed model, this model includes the use of dummy variables along with the base empirical equation to entail the effect of any changes in the input conditions on the response. The base empirical equation for principal flank wear is formulated adopting the Exponential Associate Function using the experimental results. The coefficient of dummy variable reflects the shifting of the response from one set of machining condition to another set of machining condition which is determined by simple linear regression. The independent cutting parameters (speed, rate, depth of cut) are kept constant while formulating and analyzing this model. The developed model is validated with different sets of machining responses in turning hardened medium carbon steel by coated carbide inserts. For any particular set, the model can be used to predict the amount of principal flank wear for specific machining time. Since the predicted results exhibit good resemblance with experimental data and the average percentage error is <10 %, this model can be used to predict the principal flank wear for stated conditions.
Cho, Han Sang; Moon, Hee Sun; Kim, Jae Young
2012-04-01
A study was conducted to investigate the effect of waste composition change on the methane production in landfills. An empirical equation for the methane potential of the mixed waste is derived based on the methane potential values of individual waste components and the compositional ratio of waste components. A correction factor was introduced in the equation and was determined from the BMP and lysimeter tests. The equation and LandGEM were applied for a full size landfill and the annual methane potential was estimated. Results showed that the changes in quantity of waste affected the annual methane potential from the landfill more than the changes of waste composition. Copyright © 2012 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Claure, Yuri Navarro; Matsubara, Edson Takashi; Padovani, Carlos; Prati, Ronaldo Cristiano
2018-03-01
Traditional methods for estimating timing parameters in hydrological science require a rigorous study of the relations of flow resistance, slope, flow regime, watershed size, water velocity, and other local variables. These studies are mostly based on empirical observations, where the timing parameter is estimated using empirically derived formulas. The application of these studies to other locations is not always direct. The locations in which equations are used should have comparable characteristics to the locations from which such equations have been derived. To overcome this barrier, in this work, we developed a data-driven approach to estimate timing parameters such as travel time. Our proposal estimates timing parameters using historical data of the location without the need of adapting or using empirical formulas from other locations. The proposal only uses one variable measured at two different locations on the same river (for instance, two river-level measurements, one upstream and the other downstream on the same river). The recorded data from each location generates two time series. Our method aligns these two time series using derivative dynamic time warping (DDTW) and perceptually important points (PIP). Using data from timing parameters, a polynomial function generalizes the data by inducing a polynomial water travel time estimator, called PolyWaTT. To evaluate the potential of our proposal, we applied PolyWaTT to three different watersheds: a floodplain ecosystem located in the part of Brazil known as Pantanal, the world's largest tropical wetland area; and the Missouri River and the Pearl River, in United States of America. We compared our proposal with empirical formulas and a data-driven state-of-the-art method. The experimental results demonstrate that PolyWaTT showed a lower mean absolute error than all other methods tested in this study, and for longer distances the mean absolute error achieved by PolyWaTT is three times smaller than empirical formulas.
Analysis of physics-based preconditioning for single-phase subchannel equations
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hansel, J. E.; Ragusa, J. C.; Allu, S.
2013-07-01
The (single-phase) subchannel approximations are used throughout nuclear engineering to provide an efficient flow simulation because the computational burden is much smaller than for computational fluid dynamics (CFD) simulations, and empirical relations have been developed and validated to provide accurate solutions in appropriate flow regimes. Here, the subchannel equations have been recast in a residual form suitable for a multi-physics framework. The Eigen spectrum of the Jacobian matrix, along with several potential physics-based preconditioning approaches, are evaluated, and the the potential for improved convergence from preconditioning is assessed. The physics-based preconditioner options include several forms of reduced equations that decouplemore » the subchannels by neglecting crossflow, conduction, and/or both turbulent momentum and energy exchange between subchannels. Eigen-scopy analysis shows that preconditioning moves clusters of eigenvalues away from zero and toward one. A test problem is run with and without preconditioning. Without preconditioning, the solution failed to converge using GMRES, but application of any of the preconditioners allowed the solution to converge. (authors)« less
Empirical equation for predicting the surface tension of some liquid metals at their melting point
NASA Astrophysics Data System (ADS)
Ceotto, D.
2014-07-01
A new empirical equation is proposed for predicting the surface tension of some pure metals at their melting point. The investigation has been conducted adopting a statistical approach using some of the most accredited data available in literature. It is found that for Ag, Al, Au, Co, Cu, Fe, Ni, and Pb the surface tension can be conveniently expressed in function of the latent heat of fusion and of the geometrical parameters of an ideal liquid spherical drop. The equation proposed has been compared also with the model proposed by Lu and Jiang giving satisfactory agreement for the metals considered.
Drift from the Use of Hand-Held Knapsack Pesticide Sprayers in Boyacá (Colombian Andes).
García-Santos, Glenda; Feola, Giuseppe; Nuyttens, David; Diaz, Jaime
2016-05-25
Offsite pesticide losses in tropical mountainous regions have been little studied. One example is measuring pesticide drift soil deposition, which can support pesticide risk assessment for surface water, soil, bystanders, and off-target plants and fauna. This is considered a serious gap, given the evidence of pesticide-related poisoning in those regions. Empirical data of drift deposition of a pesticide surrogate, Uranine tracer, within one of the highest potato-producing regions in Colombia, characterized by small plots and mountain orography, is presented. High drift values encountered in this study reflect the actual spray conditions using hand-held knapsack sprayers. Comparison between measured and predicted drift values using three existing empirical equations showed important underestimation. However, after their optimization based on measured drift information, the equations showed a strong predictive power for this study area and the study conditions. The most suitable curve to assess mean relative drift was the IMAG calculator after optimization.
NASA Astrophysics Data System (ADS)
Shibata, Kenichiro; Adhiperdana, Billy G.; Ito, Makoto
2018-01-01
Reconstructions of the dimensions and hydrological features of ancient fluvial channels, such as bankfull depth, bankfull width, and water discharges, have used empirical equations developed from compiled data-sets, mainly from modern meandering rivers, in various tectonic and climatic settings. However, the application of the proposed empirical equations to an ancient fluvial succession should be carefully examined with respect to the tectonic and climatic settings of the objective deposits. In this study, we developed empirical relationships among the mean bankfull channel depth, bankfull channel depth, drainage area, bankfull channel width, mean discharge, and bankfull discharge using data from 24 observation sites of modern gravelly rivers in the Kanto region, central Japan. Some of the equations among these parameters are different from those proposed by previous studies. The discrepancies are considered to reflect tectonic and climatic settings of the present river systems, which are characterized by relatively steeper valley slope, active supply of volcaniclastic sediments, and seasonal precipitation in the Kanto region. The empirical relationships derived from the present study can be applied to modern and ancient gravelly fluvial channels with multiple and alternate bars, developed in convergent margin settings under a temperate climatic condition. The developed empirical equations were applied to a transgressive gravelly fluvial succession of the Paleogene Iwaki Formation, Northeast Japan as a case study. Stratigraphic thicknesses of bar deposits were used for estimation of the bankfull channel depth. In addition, some other geomorphological and hydrological parameters were calculated using the empirical equations developed by the present study. The results indicate that the Iwaki Formation fluvial deposits were formed by a fluvial system that was represented by the dimensions and discharges of channels similar to those of the middle to lower reaches of the modern Kuji River, northern Kanto region. In addition, no distinct temporal changes in paleochannel dimensions and discharges were observed in an overall transgressive Iwaki Formation fluvial system. This implies that a rise in relative sea level did not affect the paleochannel dimensions within a sequence stratigraphic framework.
ERIC Educational Resources Information Center
Moses, Tim; Holland, Paul
2007-01-01
The purpose of this study was to empirically evaluate the impact of loglinear presmoothing accuracy on equating bias and variability across chained and post-stratification equating methods, kernel and percentile-rank continuization methods, and sample sizes. The results of evaluating presmoothing on equating accuracy generally agreed with those of…
Development of a new model for short period ocean tidal variations of Earth rotation
NASA Astrophysics Data System (ADS)
Schuh, Harald
2015-08-01
Within project SPOT (Short Period Ocean Tidal variations in Earth rotation) we develop a new high frequency Earth rotation model based on empirical ocean tide models. The main purpose of the SPOT model is its application to space geodetic observations such as GNSS and VLBI.We consider an empirical ocean tide model, which does not require hydrodynamic ocean modeling to determine ocean tidal angular momentum. We use here the EOT11a model of Savcenko & Bosch (2012), which is extended for some additional minor tides (e.g. M1, J1, T2). As empirical tidal models do not provide ocean tidal currents, which are re- quired for the computation of oceanic relative angular momentum, we implement an approach first published by Ray (2001) to estimate ocean tidal current veloci- ties for all tides considered in the extended EOT11a model. The approach itself is tested by application to tidal heights from hydrodynamic ocean tide models, which also provide tidal current velocities. Based on the tidal heights and the associated current velocities the oceanic tidal angular momentum (OTAM) is calculated.For the computation of the related short period variation of Earth rotation, we have re-examined the Euler-Liouville equation for an elastic Earth model with a liquid core. The focus here is on the consistent calculation of the elastic Love num- bers and associated Earth model parameters, which are considered in the Euler- Liouville equation for diurnal and sub-diurnal periods in the frequency domain.
NASA Technical Reports Server (NTRS)
Yang, H. Q.; West, Jeff
2018-01-01
Determination of slosh damping is a very challenging task as there is no analytical solution. The damping physics involves the vorticity dissipation which requires the full solution of the nonlinear Navier-Stokes equations. As a result, previous investigations were mainly carried out by extensive experiments. A systematical study is needed to understand the damping physics of baffled tanks, to identify the difference between the empirical Miles equation and experimental measurements, and to develop new semi-empirical relations to better represent the real damping physics. The approach of this study is to use Computational Fluid Dynamics (CFD) technology to shed light on the damping mechanisms of a baffled tank. First, a 1-D Navier-Stokes equation representing different length scales and time scales in the baffle damping physics is developed and analyzed. Loci-STREAM-VOF, a well validated CFD solver developed at NASA MSFC, is applied to study the vorticity field around a baffle and around the fluid-gas interface to highlight the dissipation mechanisms at different slosh amplitudes. Previous measurement data is then used to validate the CFD damping results. The study found several critical parameters controlling fluid damping from a baffle: local slosh amplitude to baffle thickness (A/t), surface liquid depth to tank radius (d/R), local slosh amplitude to baffle width (A/W); and non-dimensional slosh frequency. The simulation highlights three significant damping regimes where different mechanisms dominate. The study proves that the previously found discrepancies between Miles equation and experimental measurement are not due to the measurement scatter, but rather due to different damping mechanisms at various slosh amplitudes. The limitations on the use of Miles equation are discussed based on the flow regime.
Consumer trust in food safety--a multidisciplinary approach and empirical evidence from Taiwan.
Chen, Mei-Fang
2008-12-01
Food scandals that happened in recent years have increased consumers' risk perceptions of foods and decreased their trust in food safety. A better understanding of the consumer trust in food safety can improve the effectiveness of public policy and allow the development of the best practice in risk communication. This study proposes a research framework from a psychometric approach to investigate the relationships between the consumer's trust in food safety and the antecedents of risk perceptions of foods based on a reflexive modernization perspective and a cultural theory perspective in the hope of benefiting the future empirical study. The empirical results from a structural equation modeling analysis of Taiwan as a case in point reveal that this research framework based on a multidisciplinary perspective can be a valuable tool for a growing understanding of consumer trust in food safety. The antecedents in the psychometric research framework comprised reflexive modernization factors and cultural theory factors have all been supported in this study except the consumer's perception of pessimism toward food. Moreover, the empirical results of repeated measures analysis of variance give more detailed information to grasp empirical implications and to provide some suggestions to the actors and institutions involved in the food supply chain in Taiwan.
NASA Astrophysics Data System (ADS)
Szega, Marcin; Nowak, Grzegorz Tadeusz
2013-12-01
In generalized method of data reconciliation as equations of conditions beside substance and energy balances can be used equations which don't have precisely the status of conservation lows. Empirical coefficients in these equations are traded as unknowns' values. To this kind of equations, in application of the generalized method of data reconciliation in supercritical power unit, can be classified: steam flow capacity of a turbine for a group of stages, adiabatic internal efficiency of group of stages, equations for pressure drop in pipelines and equations for heat transfer in regeneration heat exchangers. Mathematical model of a power unit was developed in the code Thermoflex. Using this model the off-design calculation has been made in several points of loads for the power unit. Using these calculations identification of unknown values and empirical coefficients for generalized method of data reconciliation used in power unit has been made. Additional equations of conditions will be used in the generalized method of data reconciliation which will be used in optimization of measurement placement in redundant measurement system in power unit for new control systems
DOUBLE SHELL TANK (DST) HYDROXIDE DEPLETION MODEL FOR CARBON DIOXIDE ABSORPTION
DOE Office of Scientific and Technical Information (OSTI.GOV)
OGDEN DM; KIRCH NW
2007-10-31
This document generates a supernatant hydroxide ion depletion model based on mechanistic principles. The carbon dioxide absorption mechanistic model is developed in this report. The report also benchmarks the model against historical tank supernatant hydroxide data and vapor space carbon dioxide data. A comparison of the newly generated mechanistic model with previously applied empirical hydroxide depletion equations is also performed.
Willingness to Communicate in English: A Microsystem Model in the Iranian EFL Classroom Context
ERIC Educational Resources Information Center
Khajavy, Gholam Hassan; Ghonsooly, Behzad; Fatemi, Azar Hosseini; Choi, Charles W.
2016-01-01
This study examined willingness to communicate (WTC) in English among Iranian EFL learners in the classroom context. For this purpose, a second language willingness to communicate (L2WTC) model based on WTC theory (MacIntyre, Clément, Dörnyei, and Noels, 1998) and empirical studies was proposed and tested using structural equation modeling (SEM).…
ERIC Educational Resources Information Center
Chaisamrej, Rungrat; Zimmerman, Rick S.
2014-01-01
This research compared the ability of the theory of planned behavior (TPB) and the altruism framework (AM) to predict paper-recycling behavior. It was comprised of formative research and a major survey. Data collected from 628 undergraduate students in Thailand were analyzed using structural equation modeling. Results showed that TPB was superior…
NASA Technical Reports Server (NTRS)
Davis, J. W.; Cramer, B. A.
1974-01-01
Cyclic creep response was investigated and design methods applicable to thermal protection system structures were developed. The steady-state (constant temperature and load) and cyclic creep response characteristics of four alloys were studied. Steady-state creep data were gathered through a literature survey to establish reference data bases. These data bases were used to develop empirical equations describing creep as a function of time, temperature, and stress and as a basis of comparison for test data. Steady-state creep tests and tensile cyclic tests were conducted. The following factors were investigated: material thickness and rolling direction; material cyclic creep response under varying loads and temperatures; constant stress and temperature cycles representing flight conditions; changing stresses present in a creeping beam as a result of stress redistribution; and complex stress and temperature profiles representative of space shuttle orbiter trajectories. A computer program was written, applying creep hardening theories and empirical equations for creep, to aid in analysis of test data. Results are considered applicable to a variety of structures which are cyclicly exposed to creep producing thermal environments.
Testing a theory of aircraft noise annoyance: a structural equation analysis.
Kroesen, Maarten; Molin, Eric J E; van Wee, Bert
2008-06-01
Previous research has stressed the relevance of nonacoustical factors in the perception of aircraft noise. However, it is largely empirically driven and lacks a sound theoretical basis. In this paper, a theoretical model which explains noise annoyance based on the psychological stress theory is empirically tested. The model is estimated by applying structural equation modeling based on data from residents living in the vicinity of Amsterdam Airport Schiphol in The Netherlands. The model provides a good model fit and indicates that concern about the negative health effects of noise and pollution, perceived disturbance, and perceived control and coping capacity are the most important variables that explain noise annoyance. Furthermore, the model provides evidence for the existence of two reciprocal relationships between (1) perceived disturbance and noise annoyance and (2) perceived control and coping capacity and noise annoyance. Lastly, the model yielded two unexpected results. Firstly, the variables noise sensitivity and fear related to the noise source were unable to explain additional variance in the endogenous variables of the model and were therefore excluded from the model. And secondly, the size of the total effect of noise exposure on noise annoyance was relatively small. The paper concludes with some recommended directions for further research.
Robustness of fit indices to outliers and leverage observations in structural equation modeling.
Yuan, Ke-Hai; Zhong, Xiaoling
2013-06-01
Normal-distribution-based maximum likelihood (NML) is the most widely used method in structural equation modeling (SEM), although practical data tend to be nonnormally distributed. The effect of nonnormally distributed data or data contamination on the normal-distribution-based likelihood ratio (LR) statistic is well understood due to many analytical and empirical studies. In SEM, fit indices are used as widely as the LR statistic. In addition to NML, robust procedures have been developed for more efficient and less biased parameter estimates with practical data. This article studies the effect of outliers and leverage observations on fit indices following NML and two robust methods. Analysis and empirical results indicate that good leverage observations following NML and one of the robust methods lead most fit indices to give more support to the substantive model. While outliers tend to make a good model superficially bad according to many fit indices following NML, they have little effect on those following the two robust procedures. Implications of the results to data analysis are discussed, and recommendations are provided regarding the use of estimation methods and interpretation of fit indices. (PsycINFO Database Record (c) 2013 APA, all rights reserved).
A General Model for Estimating Macroevolutionary Landscapes.
Boucher, Florian C; Démery, Vincent; Conti, Elena; Harmon, Luke J; Uyeda, Josef
2018-03-01
The evolution of quantitative characters over long timescales is often studied using stochastic diffusion models. The current toolbox available to students of macroevolution is however limited to two main models: Brownian motion and the Ornstein-Uhlenbeck process, plus some of their extensions. Here, we present a very general model for inferring the dynamics of quantitative characters evolving under both random diffusion and deterministic forces of any possible shape and strength, which can accommodate interesting evolutionary scenarios like directional trends, disruptive selection, or macroevolutionary landscapes with multiple peaks. This model is based on a general partial differential equation widely used in statistical mechanics: the Fokker-Planck equation, also known in population genetics as the Kolmogorov forward equation. We thus call the model FPK, for Fokker-Planck-Kolmogorov. We first explain how this model can be used to describe macroevolutionary landscapes over which quantitative traits evolve and, more importantly, we detail how it can be fitted to empirical data. Using simulations, we show that the model has good behavior both in terms of discrimination from alternative models and in terms of parameter inference. We provide R code to fit the model to empirical data using either maximum-likelihood or Bayesian estimation, and illustrate the use of this code with two empirical examples of body mass evolution in mammals. FPK should greatly expand the set of macroevolutionary scenarios that can be studied since it opens the way to estimating macroevolutionary landscapes of any conceivable shape. [Adaptation; bounds; diffusion; FPK model; macroevolution; maximum-likelihood estimation; MCMC methods; phylogenetic comparative data; selection.].
Empirical relations between large wood transport and catchment characteristics
NASA Astrophysics Data System (ADS)
Steeb, Nicolas; Rickenmann, Dieter; Rickli, Christian; Badoux, Alexandre
2017-04-01
The transport of vast amounts of large wood (LW) in water courses can considerably aggravate hazardous situations during flood events, and often strongly affects resulting flood damage. Large wood recruitment and transport are controlled by various factors which are difficult to assess and the prediction of transported LW volumes is difficult. Such information are, however, important for engineers and river managers to adequately dimension retention structures or to identify critical stream cross-sections. In this context, empirical formulas have been developed to estimate the volume of transported LW during a flood event (Rickenmann, 1997; Steeb et al., 2017). The data base of existing empirical wood load equations is, however, limited. The objective of the present study is to test and refine existing empirical equations, and to derive new relationships to reveal trends in wood loading. Data have been collected for flood events with LW occurrence in Swiss catchments of various sizes. This extended data set allows us to derive statistically more significant results. LW volumes were found to be related to catchment and transport characteristics, such as catchment size, forested area, forested stream length, water discharge, sediment load, or Melton ratio. Both the potential wood load and the fraction that is effectively mobilized during a flood event (effective wood load) are estimated. The difference of potential and effective wood load allows us to derive typical reduction coefficients that can be used to refine spatially explicit GIS models for potential LW recruitment.
An Empirical Temperature Variance Source Model in Heated Jets
NASA Technical Reports Server (NTRS)
Khavaran, Abbas; Bridges, James
2012-01-01
An acoustic analogy approach is implemented that models the sources of jet noise in heated jets. The equivalent sources of turbulent mixing noise are recognized as the differences between the fluctuating and Favre-averaged Reynolds stresses and enthalpy fluxes. While in a conventional acoustic analogy only Reynolds stress components are scrutinized for their noise generation properties, it is now accepted that a comprehensive source model should include the additional entropy source term. Following Goldstein s generalized acoustic analogy, the set of Euler equations are divided into two sets of equations that govern a non-radiating base flow plus its residual components. When the base flow is considered as a locally parallel mean flow, the residual equations may be rearranged to form an inhomogeneous third-order wave equation. A general solution is written subsequently using a Green s function method while all non-linear terms are treated as the equivalent sources of aerodynamic sound and are modeled accordingly. In a previous study, a specialized Reynolds-averaged Navier-Stokes (RANS) solver was implemented to compute the variance of thermal fluctuations that determine the enthalpy flux source strength. The main objective here is to present an empirical model capable of providing a reasonable estimate of the stagnation temperature variance in a jet. Such a model is parameterized as a function of the mean stagnation temperature gradient in the jet, and is evaluated using commonly available RANS solvers. The ensuing thermal source distribution is compared with measurements as well as computational result from a dedicated RANS solver that employs an enthalpy variance and dissipation rate model. Turbulent mixing noise predictions are presented for a wide range of jet temperature ratios from 1.0 to 3.20.
Streamflow characteristics related to channel geometry of streams in western United States
Hedman, E.R.; Osterkamp, W.R.
1982-01-01
Assessment of surface-mining and reclamation activities generally requires extensive hydrologic data. Adequate streamflow data from instrumented gaging stations rarely are available, and estimates of surface- water discharge based on rainfall-runoff models, drainage area, and basin characteristics sometimes have proven unreliable. Channel-geometry measurements offer an alternative method of quickly and inexpensively estimating stream-flow characteristics for ungaged streams. The method uses the empirical development of equations to yield a discharge value from channel-geometry and channel-material data. The equations are developed by collecting data at numerous streamflow-gaging sites and statistically relating those data to selected discharge characteristics. Mean annual runoff and flood discharges with selected recurrence intervals can be estimated for perennial, intermittent, and ephemeral streams. The equations were developed from data collected in the western one-half of the conterminous United States. The effect of the channel-material and runoff characteristics are accounted for with the equations.
NASA Astrophysics Data System (ADS)
Yue, Zhiyuan; Cao, Zhixian; Li, Xin; Che, Tao
2008-09-01
Alluvial rivers may experience intense sediment transport and rapid bed evolution under a high flow regime, for which traditional decoupled mathematical river models based on simplified conservation equations are not applicable. A two-dimensional coupled mathematical model is presented, which is generally applicable to the fluvial processes with either intense or weak sediment transport. The governing equations of the model comprise the complete shallow water hydrodynamic equations closed with Manning roughness for boundary resistance and empirical relationships for sediment exchange with the erodible bed. The second-order Total-Variation-Diminishing version of the Weighted-Average-Flux method, along with the HLLC approximate Riemann Solver, is adapted to solve the governing equations, which can properly resolve shock waves and contact discontinuities. The model is applied to the pilot study of the flooding due to a sudden outburst of a real glacial-lake.
Goličnik, Marko
2011-06-01
Many pharmacodynamic processes can be described by the nonlinear saturation kinetics that are most frequently based on the hyperbolic Michaelis-Menten equation. Thus, various time-dependent solutions for drugs obeying such kinetics can be expressed in terms of the Lambert W(x)-omega function. However, unfortunately, computer programs that can perform the calculations for W(x) are not widely available. To avoid this problem, the replacement of the integrated Michaelis-Menten equation with an empiric integrated 1--exp alternative model equation was proposed recently by Keller et al. (Ther Drug Monit. 2009;31:783-785), although, as shown here, it was not necessary. Simulated concentrations of model drugs obeying Michaelis-Menten elimination kinetics were generated by two approaches: 1) calculation of time-course data based on an approximation equation W2*(x) performed using Microsoft Excel; and 2) calculation of reference time-course data based on an exact W(x) function built in to the Wolfram Mathematica. I show here that the W2*(x) function approximates the actual W(x) accurately. W2*(x) is expressed in terms of elementary mathematical functions and, consequently, it can be easily implemented using any of the widely available software. Hence, with the example of a hypothetical drug, I demonstrate here that an equation based on this approximation is far better, because it is nearly equivalent to the original solution, whereas the same characteristics cannot be fully confirmed for the 1--exp model equation. The W2*(x) equation proposed here might have an important role as a useful shortcut in optional software to estimate kinetic parameters from experimental data for drugs, and it might represent an easy and universal analytical tool for simulating and designing dosing regimens.
An Alternative to the Stay/Switch Equation Assessed When Using a Changeover-Delay
MacDonall, James S.
2015-01-01
An alternative to the generalized matching equation for understanding concurrent performances is the stay/switch model. For the stay/switch model, the important events are the contingencies and behaviors at each alternative. The current experiment compares the descriptions by two stay/switch equations, the original, empirically derived stay/switch equation and a more theoretically derived equation based on ratios of stay to switch responses matching ratios of stay to switch reinforcers. The present experiment compared descriptions by the original stay/switch equation when using and not using a changeover delay. It also compared descriptions by the more theoretical equation with and without a changeover delay. Finally, it compared descriptions of the concurrent performances by these two equations. Rats were trained in 15 conditions on identical concurrent random-interval schedules in each component of a multiple schedule. A COD operated in only one component. There were no consistent differences in the variance accounted for by each equation of concurrent performances whether or not a COD was used. The simpler equation found greater sensitivity to stay than to switch reinforcers. It also found a COD eliminated the influence of switch reinforcers. Because estimates of parameters were more meaningful when using the more theoretical stay/switch equation it is preferred. PMID:26299548
An alternative to the stay/switch equation assessed when using a changeover-delay.
MacDonall, James S
2015-11-01
An alternative to the generalized matching equation for understanding concurrent performances is the stay/switch model. For the stay/switch model, the important events are the contingencies and behaviors at each alternative. The current experiment compares the descriptions by two stay/switch equations, the original, empirically derived stay/switch equation and a more theoretically derived equation based on ratios of stay to switch responses matching ratios of stay to switch reinforcers. The present experiment compared descriptions by the original stay/switch equation when using and not using a changeover delay. It also compared descriptions by the more theoretical equation with and without a changeover delay. Finally, it compared descriptions of the concurrent performances by these two equations. Rats were trained in 15 conditions on identical concurrent random-interval schedules in each component of a multiple schedule. A COD operated in only one component. There were no consistent differences in the variance accounted for by each equation of concurrent performances whether or not a COD was used. The simpler equation found greater sensitivity to stay than to switch reinforcers. It also found a COD eliminated the influence of switch reinforcers. Because estimates of parameters were more meaningful when using the more theoretical stay/switch equation it is preferred. Copyright © 2015 Elsevier B.V. All rights reserved.
Mesoscale Particle-Based Model of Electrophoresis
Giera, Brian; Zepeda-Ruiz, Luis A.; Pascall, Andrew J.; ...
2015-07-31
Here, we develop and evaluate a semi-empirical particle-based model of electrophoresis using extensive mesoscale simulations. We parameterize the model using only measurable quantities from a broad set of colloidal suspensions with properties that span the experimentally relevant regime. With sufficient sampling, simulated diffusivities and electrophoretic velocities match predictions of the ubiquitous Stokes-Einstein and Henry equations, respectively. This agreement holds for non-polar and aqueous solvents or ionic liquid colloidal suspensions under a wide range of applied electric fields.
Mesoscale Particle-Based Model of Electrophoresis
DOE Office of Scientific and Technical Information (OSTI.GOV)
Giera, Brian; Zepeda-Ruiz, Luis A.; Pascall, Andrew J.
Here, we develop and evaluate a semi-empirical particle-based model of electrophoresis using extensive mesoscale simulations. We parameterize the model using only measurable quantities from a broad set of colloidal suspensions with properties that span the experimentally relevant regime. With sufficient sampling, simulated diffusivities and electrophoretic velocities match predictions of the ubiquitous Stokes-Einstein and Henry equations, respectively. This agreement holds for non-polar and aqueous solvents or ionic liquid colloidal suspensions under a wide range of applied electric fields.
Molecular Volumes and the Stokes-Einstein Equation
ERIC Educational Resources Information Center
Edward, John T.
1970-01-01
Examines the limitations of the Stokes-Einstein equation as it applies to small solute molecules. Discusses molecular volume determinations by atomic increments, molecular models, molar volumes of solids and liquids, and molal volumes. Presents an empirical correction factor for the equation which applies to molecular radii as small as 2 angstrom…
Niang, Oumar; Thioune, Abdoulaye; El Gueirea, Mouhamed Cheikh; Deléchelle, Eric; Lemoine, Jacques
2012-09-01
The major problem with the empirical mode decomposition (EMD) algorithm is its lack of a theoretical framework. So, it is difficult to characterize and evaluate this approach. In this paper, we propose, in the 2-D case, the use of an alternative implementation to the algorithmic definition of the so-called "sifting process" used in the original Huang's EMD method. This approach, especially based on partial differential equations (PDEs), was presented by Niang in previous works, in 2005 and 2007, and relies on a nonlinear diffusion-based filtering process to solve the mean envelope estimation problem. In the 1-D case, the efficiency of the PDE-based method, compared to the original EMD algorithmic version, was also illustrated in a recent paper. Recently, several 2-D extensions of the EMD method have been proposed. Despite some effort, 2-D versions for EMD appear poorly performing and are very time consuming. So in this paper, an extension to the 2-D space of the PDE-based approach is extensively described. This approach has been applied in cases of both signal and image decomposition. The obtained results confirm the usefulness of the new PDE-based sifting process for the decomposition of various kinds of data. Some results have been provided in the case of image decomposition. The effectiveness of the approach encourages its use in a number of signal and image applications such as denoising, detrending, or texture analysis.
Equation of state for dense nucleonic matter from metamodeling. I. Foundational aspects
NASA Astrophysics Data System (ADS)
Margueron, Jérôme; Hoffmann Casali, Rudiney; Gulminelli, Francesca
2018-02-01
Metamodeling for the nucleonic equation of state (EOS), inspired from a Taylor expansion around the saturation density of symmetric nuclear matter, is proposed and parameterized in terms of the empirical parameters. The present knowledge of nuclear empirical parameters is first reviewed in order to estimate their average values and associated uncertainties, and thus defining the parameter space of the metamodeling. They are divided into isoscalar and isovector types, and ordered according to their power in the density expansion. The goodness of the metamodeling is analyzed against the predictions of the original models. In addition, since no correlation among the empirical parameters is assumed a priori, all arbitrary density dependences can be explored, which might not be accessible in existing functionals. Spurious correlations due to the assumed functional form are also removed. This meta-EOS allows direct relations between the uncertainties on the empirical parameters and the density dependence of the nuclear equation of state and its derivatives, and the mapping between the two can be done with standard Bayesian techniques. A sensitivity analysis shows that the more influential empirical parameters are the isovector parameters Lsym and Ksym, and that laboratory constraints at supersaturation densities are essential to reduce the present uncertainties. The present metamodeling for the EOS for nuclear matter is proposed for further applications in neutron stars and supernova matter.
Empirical Likelihood in Nonignorable Covariate-Missing Data Problems.
Xie, Yanmei; Zhang, Biao
2017-04-20
Missing covariate data occurs often in regression analysis, which frequently arises in the health and social sciences as well as in survey sampling. We study methods for the analysis of a nonignorable covariate-missing data problem in an assumed conditional mean function when some covariates are completely observed but other covariates are missing for some subjects. We adopt the semiparametric perspective of Bartlett et al. (Improving upon the efficiency of complete case analysis when covariates are MNAR. Biostatistics 2014;15:719-30) on regression analyses with nonignorable missing covariates, in which they have introduced the use of two working models, the working probability model of missingness and the working conditional score model. In this paper, we study an empirical likelihood approach to nonignorable covariate-missing data problems with the objective of effectively utilizing the two working models in the analysis of covariate-missing data. We propose a unified approach to constructing a system of unbiased estimating equations, where there are more equations than unknown parameters of interest. One useful feature of these unbiased estimating equations is that they naturally incorporate the incomplete data into the data analysis, making it possible to seek efficient estimation of the parameter of interest even when the working regression function is not specified to be the optimal regression function. We apply the general methodology of empirical likelihood to optimally combine these unbiased estimating equations. We propose three maximum empirical likelihood estimators of the underlying regression parameters and compare their efficiencies with other existing competitors. We present a simulation study to compare the finite-sample performance of various methods with respect to bias, efficiency, and robustness to model misspecification. The proposed empirical likelihood method is also illustrated by an analysis of a data set from the US National Health and Nutrition Examination Survey (NHANES).
NASA Astrophysics Data System (ADS)
Fernando, Viraj
2011-09-01
This paper formulates a coherent theory of occurrence of relativistic phenomena in their interconnection in a feedback loop, unlike other theories, by tracing back concepts that Newton held but suppressed, when he developed his mechanics in his Principia. Despite Newtonian mechanics being based on a closed system, Newton in the General Scholium has indicated that in reality thee is in an open system, where 'a certain most subtle spirit' participates and directs all interactions from motion of bodies, to motion of light, to how the human brain operates. We have identified this 'most subtle spirit' as the non-empirical 'universal governing field' and that no empirical interaction in this universe can occur without exchange of energy between the empirical interactants and the governing field. By analyzing the energy momentum equation, we have demonstrated that everything empirical has a non-empirical substratum, identified with Spinoza's primitive substance, which binds everything in the universe to the field and through it to one another. Algorithm of Motion is founded on the Pythagorean character of the energy-momentum equation, which is applicable to all velocities 0
Crash Padding Research : Volume II. Constitutive Equation Models.
DOT National Transportation Integrated Search
1986-08-01
Several simplified one-dimensional constitutive equations for viscoelastic materials are reviewed and found to be inadequate for representing the impact-response performance of strongly nonlinear materials. Two multi-parameter empirical models are de...
Factors influencing the thermally-induced strength degradation of B/Al composites
NASA Technical Reports Server (NTRS)
Dicarlo, J. A.
1982-01-01
Literature data related to the thermally-induced strength degradation of B/Al composites were examined in the light of fracture theories based on reaction-controlled fiber weakening. Under the assumption of a parabolic time-dependent growth for the interfacial reaction product, a Griffith-type fracture model was found to yield simple equations whose predictions were in good agreement with data for boron fiber average strength and for B/Al axial fracture strain. The only variables in these equations were the time and temperature of the thermal exposure and an empirical factor related to fiber surface smoothness prior to composite consolidation. Such variables as fiber diameter and aluminum alloy composition were found to have little influence. The basic and practical implications of the fracture model equations are discussed.
Quantifying the driving factors for language shift in a bilingual region
Prochazka, Katharina; Vogl, Gero
2017-01-01
Many of the world’s around 6,000 languages are in danger of disappearing as people give up use of a minority language in favor of the majority language in a process called language shift. Language shift can be monitored on a large scale through the use of mathematical models by way of differential equations, for example, reaction–diffusion equations. Here, we use a different approach: we propose a model for language dynamics based on the principles of cellular automata/agent-based modeling and combine it with very detailed empirical data. Our model makes it possible to follow language dynamics over space and time, whereas existing models based on differential equations average over space and consequently provide no information on local changes in language use. Additionally, cellular automata models can be used even in cases where models based on differential equations are not applicable, for example, in situations where one language has become dispersed and retreated to language islands. Using data from a bilingual region in Austria, we show that the most important factor in determining the spread and retreat of a language is the interaction with speakers of the same language. External factors like bilingual schools or parish language have only a minor influence. PMID:28298530
Canadian Field Soils IV: Modeling Thermal Conductivity at Dryness and Saturation
NASA Astrophysics Data System (ADS)
Tarnawski, V. R.; McCombie, M. L.; Leong, W. H.; Coppa, P.; Corasaniti, S.; Bovesecchi, G.
2018-03-01
The thermal conductivity data of 40 Canadian soils at dryness (λ _{dry}) and at full saturation (λ _{sat}) were used to verify 13 predictive models, i.e., four mechanistic, four semi-empirical and five empirical equations. The performance of each model, for λ _{dry} and λ _{sat}, was evaluated using a standard deviation ( SD) formula. Among the mechanistic models applied to dry soils, the closest λ _{dry} estimates were obtained by MaxRTCM (it{SD} = ± 0.018 Wm^{-1}\\cdot K^{-1}), followed by de Vries and a series-parallel model (S-{\\vert }{\\vert }). Among the semi-empirical equations (deVries-ave, Advanced Geometric Mean Model (A-GMM), Chaudhary and Bhandari (C-B) and Chen's equation), the closest λ _{dry} estimates were obtained by the C-B model (± 0.022 Wm^{-1}\\cdot K^{-1}). Among the empirical equations, the top λ _{dry} estimates were given by CDry-40 (± 0.021 Wm^{-1}\\cdot K^{-1} and ± 0.018 Wm^{-1}\\cdot K^{-1} for18-coarse and 22-fine soils, respectively). In addition, λ _{dry} and λ _{sat} models were applied to the λ _{sat} database of 21 other soils. From all the models tested, only the maxRTCM and the CDry-40 models provided the closest λ _{dry} estimates for the 40 Canadian soils as well as the 21 soils. The best λ _{sat} estimates for the 40-Canadian soils and the 21 soils were given by the A-GMM and the S-{\\vert }{\\vert } model.
New Equations for the Sublimation Pressure and Melting Pressure of H2O Ice Ih
NASA Astrophysics Data System (ADS)
Wagner, Wolfgang; Riethmann, Thomas; Feistel, Rainer; Harvey, Allan H.
2011-12-01
New reference equations, adopted by the International Association for the Properties of Water and Steam (IAPWS), are presented for the sublimation pressure and melting pressure of ice Ih as a function of temperature. These equations are based on input values derived from the phase-equilibrium condition between the IAPWS-95 scientific standard for thermodynamic properties of fluid H2O and the equation of state of H2O ice Ih adopted by IAPWS in 2006, making them thermodynamically consistent with the bulk-phase properties. Compared to the previous IAPWS formulations, which were empirical fits to experimental data, the new equations have significantly less uncertainty. The sublimation-pressure equation covers the temperature range from 50 K to the vapor-liquid-solid triple point at 273.16 K. The ice Ih melting-pressure equation describes the entire melting curve from 273.16 K to the ice Ih-ice III-liquid triple point at 251.165 K. For completeness, we also give the IAPWS melting-pressure equation for ice III, which is slightly adjusted to agree with the ice Ih melting-pressure equation at the corresponding triple point, and the unchanged IAPWS melting-pressure equations for ice V, ice VI, and ice VII.
Is Directivity Still Effective in a PSHA Framework?
NASA Astrophysics Data System (ADS)
Spagnuolo, E.; Herrero, A.; Cultrera, G.
2008-12-01
Source rupture parameters, like directivity, modulate the energy release causing variations in the radiated signal amplitude. Thus they affect the empirical predictive equations and as a consequence the seismic hazard assessment. Classical probabilistic hazard evaluations, e.g. Cornell (1968), use very simple predictive equations only based on magnitude and distance which do not account for variables concerning the rupture process. However nowadays, a few predictive equations (e.g. Somerville 1997, Spudich and Chiou 2008) take into account for rupture directivity. Also few implementations have been made in a PSHA framework (e.g. Convertito et al. 2006, Rowshandel 2006). In practice, these new empirical predictive models incorporate quantitatively the rupture propagation effects through the introduction of variables like rake, azimuth, rupture velocity and laterality. The contribution of all these variables is summarized in corrective factors derived from measuring differences between the real data and the predicted ones Therefore, it's possible to keep the older computation, making use of a simple predictive model, and besides, to incorporate the directivity effect through the corrective factors. Any single supplementary variable meaning a new integral in the parametric space. However the difficulty consists of the constraints on parameter distribution functions. We present the preliminary result for ad hoc distributions (Gaussian, uniform distributions) in order to test the impact of incorporating directivity into PSHA models. We demonstrate that incorporating directivity in PSHA by means of the new predictive equations may lead to strong percentage variations in the hazard assessment.
Equation-free mechanistic ecosystem forecasting using empirical dynamic modeling
Ye, Hao; Beamish, Richard J.; Glaser, Sarah M.; Grant, Sue C. H.; Hsieh, Chih-hao; Richards, Laura J.; Schnute, Jon T.; Sugihara, George
2015-01-01
It is well known that current equilibrium-based models fall short as predictive descriptions of natural ecosystems, and particularly of fisheries systems that exhibit nonlinear dynamics. For example, model parameters assumed to be fixed constants may actually vary in time, models may fit well to existing data but lack out-of-sample predictive skill, and key driving variables may be misidentified due to transient (mirage) correlations that are common in nonlinear systems. With these frailties, it is somewhat surprising that static equilibrium models continue to be widely used. Here, we examine empirical dynamic modeling (EDM) as an alternative to imposed model equations and that accommodates both nonequilibrium dynamics and nonlinearity. Using time series from nine stocks of sockeye salmon (Oncorhynchus nerka) from the Fraser River system in British Columbia, Canada, we perform, for the the first time to our knowledge, real-data comparison of contemporary fisheries models with equivalent EDM formulations that explicitly use spawning stock and environmental variables to forecast recruitment. We find that EDM models produce more accurate and precise forecasts, and unlike extensions of the classic Ricker spawner–recruit equation, they show significant improvements when environmental factors are included. Our analysis demonstrates the strategic utility of EDM for incorporating environmental influences into fisheries forecasts and, more generally, for providing insight into how environmental factors can operate in forecast models, thus paving the way for equation-free mechanistic forecasting to be applied in management contexts. PMID:25733874
Prediction of pressure drop in fluid tuned mounts using analytical and computational techniques
NASA Technical Reports Server (NTRS)
Lasher, William C.; Khalilollahi, Amir; Mischler, John; Uhric, Tom
1993-01-01
A simplified model for predicting pressure drop in fluid tuned isolator mounts was developed. The model is based on an exact solution to the Navier-Stokes equations and was made more general through the use of empirical coefficients. The values of these coefficients were determined by numerical simulation of the flow using the commercial computational fluid dynamics (CFD) package FIDAP.
F. N. Scatena
1990-01-01
This paper describe the hydraulics of unsubmerged flow for 5 culverts in the Luiquillo Esperimental Forest of Puerto Rico. A General equation based on empirical data is presented to estimate culvert discharge during unsubmerged conditions. Large culverts are needed in humid tropical montane areas than in humid temperatute watersheds and are usually appropriate only...
DOT National Transportation Integrated Search
1979-01-01
Presented is a relatively simple empirical equation that reasonably approximates the relationship between mesoscale carbon monoxide (CO) concentrations, areal vehicular CO emission rates, and the meteorological factors of wind speed and mixing height...
Thermodynamics Fundamental Equation of a "Non-Ideal" Rubber Band from Experiments
ERIC Educational Resources Information Center
Ritacco, Herna´n A.; Fortunatti, Juan C.; Devoto, Walter; Ferna´ndez-Miconi, Eugenio; Dominguez, Claudia; Sanchez, Miguel D.
2014-01-01
In this paper, we describe laboratory and classroom exercises designed to obtain the "fundamental" equation of a rubber band by combining experiments and theory. The procedure shows students how classical thermodynamics formalism can help to obtain empirical equations of state by constraining and guiding in the construction of the…
The Empirical Derivation of Equations for Predicting Subjective Textual Information. Final Report.
ERIC Educational Resources Information Center
Kauffman, Dan; And Others
A study was made to derive an equation for predicting the "subjective" textual information contained in a text of material written in the English language. Specifically, this investigation describes, by a mathematical equation, the relationship between the "subjective" information content of written textual material and the relative number of…
ERIC Educational Resources Information Center
Baker, Frank B.
1997-01-01
Examined the sampling distributions of equating coefficients produced by the characteristic curve method for tests using graded and nominal response scoring using simulated data. For both models and across all three equating situations, the sampling distributions were generally bell-shaped and peaked, and occasionally had a small degree of…
NASA Astrophysics Data System (ADS)
Lestari, E. R.; Ardianti, F. L.; Rachmawati, L.
2018-03-01
This study investigated the relationship between learning orientation, innovation, and firm performance. A conceptual model and hypothesis were empirically examined using structural equation modelling. The study involved a questionnaire-based survey of owners of small and medium enterprises (SMEs) operating in Batu City, Indonesia. The results showed that both variables of learning orientation and innovation effect positively on firm performance. Additionally, learning orientation has positive effect innovation. This study has implication for SMEs aiming at increasing their firm performance based on learning orientation and innovation capability.
Empirical Equations for Estimating Drying Times of Thick Rotary-Cut Veneer in Press and Jet Dryers.
1985-05-01
producing veneer species. greater areas of effective contact in gluing. This paper describes the use of empirical equations for ’The use of trade, firm...grade logs have different volumes of knots from one area to another in the log, and because knots Of the three dryers, the roller unit has the lowest... areas of knotty veneer would be the same for chosen so that a smooth curve of MC over time could both. be obtained with about six passes per curve. All
NASA Astrophysics Data System (ADS)
Yang, Gongping; Zhou, Guang-Tong; Yin, Yilong; Yang, Xiukun
2010-12-01
A critical step in an automatic fingerprint recognition system is the segmentation of fingerprint images. Existing methods are usually designed to segment fingerprint images originated from a certain sensor. Thus their performances are significantly affected when dealing with fingerprints collected by different sensors. This work studies the sensor interoperability of fingerprint segmentation algorithms, which refers to the algorithm's ability to adapt to the raw fingerprints obtained from different sensors. We empirically analyze the sensor interoperability problem, and effectively address the issue by proposing a [InlineEquation not available: see fulltext.]-means based segmentation method called SKI. SKI clusters foreground and background blocks of a fingerprint image based on the [InlineEquation not available: see fulltext.]-means algorithm, where a fingerprint block is represented by a 3-dimensional feature vector consisting of block-wise coherence, mean, and variance (abbreviated as CMV). SKI also employs morphological postprocessing to achieve favorable segmentation results. We perform SKI on each fingerprint to ensure sensor interoperability. The interoperability and robustness of our method are validated by experiments performed on a number of fingerprint databases which are obtained from various sensors.
NASA Astrophysics Data System (ADS)
Limbach, P.; Müller, T.; Skoda, R.
2015-12-01
Commonly, for the simulation of cavitation in centrifugal pumps incompressible flow solvers with VOF kind cavitation models are applied. Since the source/sink terms of the void fraction transport equation are based on simplified bubble dynamics, empirical parameters may need to be adjusted to the particular pump operating point. In the present study a barotropic cavitation model, which is based solely on thermodynamic fluid properties and does not include any empirical parameters, is applied on a single flow channel of a pump impeller in combination with a time-explicit viscous compressible flow solver. The suction head curves (head drop) are compared to the results of an incompressible implicit standard industrial CFD tool and are predicted qualitatively correct by the barotropic model.
NASA Astrophysics Data System (ADS)
Bora, Sanjay; Scherbaum, Frank; Kuehn, Nicolas; Stafford, Peter; Edwards, Benjamin
2016-04-01
The current practice of deriving empirical ground motion prediction equations (GMPEs) involves using ground motions recorded at multiple sites. However, in applications like site-specific (e.g., critical facility) hazard ground motions obtained from the GMPEs are need to be adjusted/corrected to a particular site/site-condition under investigation. This study presents a complete framework for developing a response spectral GMPE, within which the issue of adjustment of ground motions is addressed in a manner consistent with the linear system framework. The present approach is a two-step process in which the first step consists of deriving two separate empirical models, one for Fourier amplitude spectra (FAS) and the other for a random vibration theory (RVT) optimized duration (Drvto) of ground motion. In the second step the two models are combined within the RVT framework to obtain full response spectral amplitudes. Additionally, the framework also involves a stochastic model based extrapolation of individual Fourier spectra to extend the useable frequency limit of the empirically derived FAS model. The stochastic model parameters were determined by inverting the Fourier spectral data using an approach similar to the one as described in Edwards and Faeh (2013). Comparison of median predicted response spectra from present approach with those from other regional GMPEs indicates that the present approach can also be used as a stand-alone model. The dataset used for the presented analysis is a subset of the recently compiled database RESORCE-2012 across Europe, the Middle East and the Mediterranean region.
NASA Technical Reports Server (NTRS)
Yang, H. Q.; West, Jeff
2016-01-01
Determination of slosh damping is a very challenging task as there is no analytical solution. The damping physics involves the vorticity dissipation which requires the full solution of the nonlinear Navier-Stokes equations. As a result, previous investigations were mainly carried out by extensive experiments. A systematical study is needed to understand the damping physics of baffled tanks, to identify the difference between the empirical Miles equation and experimental measurements, and to develop new semi-empirical relations to better represent the real damping physics. The approach of this study is to use Computational Fluid Dynamics (CFD) technology to shed light on the damping mechanisms of a baffled tank. First, a 1-D Navier-Stokes equation representing different length scales and time scales in the baffle damping physics is developed and analyzed. Loci-STREAM-VOF, a well validated CFD solver developed at NASA MSFC, is applied to study the vorticity field around a baffle and around the fluid-gas interface to highlight the dissipation mechanisms at different slosh amplitudes. Previous measurement data is then used to validate the CFD damping results. The study found several critical parameters controlling fluid damping from a baffle: local slosh amplitude to baffle thickness (A/t), surface liquid depth to tank radius (d/R), local slosh amplitude to baffle width (A/W); and non-dimensional slosh frequency. The simulation highlights three significant damping regimes where different mechanisms dominate. The study proves that the previously found discrepancies between Miles equation and experimental measurement are not due to the measurement scatter, but rather due to different damping mechanisms at various slosh amplitudes. The limitations on the use of Miles equation are discussed based on the flow regime.
Clausius-Clapeyron Equation and Saturation Vapour Pressure: Simple Theory Reconciled with Practice
ERIC Educational Resources Information Center
Koutsoyiannis, Demetris
2012-01-01
While the Clausius-Clapeyron equation is very important as it determines the saturation vapour pressure, in practice it is replaced by empirical, typically Magnus-type, equations which are more accurate. It is shown that the reduced accuracy reflects an inconsistent assumption that the latent heat of vaporization is constant. Not only is this…
NASA Technical Reports Server (NTRS)
Sengers, J. V.; Basu, R. S.; Sengers, J. M. H. L.
1981-01-01
A survey is presented of representative equations for various thermophysical properties of fluids in the critical region. Representative equations for the transport properties are included. Semi-empirical modifications of the theoretically predicted asymtotic critical behavior that yield simple and practical representations of the fluid properties in the critical region are emphasized.
Collateral Information for Equating in Small Samples: A Preliminary Investigation
ERIC Educational Resources Information Center
Kim, Sooyeon; Livingston, Samuel A.; Lewis, Charles
2011-01-01
This article describes a preliminary investigation of an empirical Bayes (EB) procedure for using collateral information to improve equating of scores on test forms taken by small numbers of examinees. Resampling studies were done on two different forms of the same test. In each study, EB and non-EB versions of two equating methods--chained linear…
Physics, stability, and dynamics of supply networks
NASA Astrophysics Data System (ADS)
Helbing, Dirk; Lämmer, Stefan; Seidel, Thomas; Šeba, Pétr; Płatkowski, Tadeusz
2004-12-01
We show how to treat supply networks as physical transport problems governed by balance equations and equations for the adaptation of production speeds. Although the nonlinear behavior is different, the linearized set of coupled differential equations is formally related to those of mechanical or electrical oscillator networks. Supply networks possess interesting features due to their complex topology and directed links. We derive analytical conditions for absolute and convective instabilities. The empirically observed “bullwhip effect” in supply chains is explained as a form of convective instability based on resonance effects. Moreover, it is generalized to arbitrary supply networks. Their related eigenvalues are usually complex, depending on the network structure (even without loops). Therefore, their generic behavior is characterized by damped or growing oscillations. We also show that regular distribution networks possess two negative eigenvalues only, but perturbations generate a spectrum of complex eigenvalues.
Factors influencing the thermally-induced strength degradation of B/Al composites
NASA Technical Reports Server (NTRS)
Dicarlo, J. A.
1983-01-01
Literature data related to the thermally-induced strength degradation of B/Al composites were examined in the light of fracture theories based on reaction-controlled fiber weakening. Under the assumption of a parabolic time-dependent growth for the interfacial reaction product, a Griffith-type fracture model was found to yield simple equations whose predictions were in good agreement with data for boron fiber average strength and for B/Al axial fracture strain. The only variables in these equations were the time and temperature of the thermal exposure and an empirical factor related to fiber surface smoothness prior to composite consolidation. Such variables as fiber diameter and aluminum alloy composition were found to have little influence. The basic and practical implications of the fracture model equations are discussed. Previously announced in STAR as N82-24297
[Aluminum mobilization models of forest yellow earth in South China].
Xin, Yan; Zhao, Yu; Duan, Lei
2009-07-15
For the application of acidification models in predicting effects of acid deposition and formulating control strategy in China, it is important selecting regionally applicable models of soil aluminum mobilization and determining their parameters. Based on the long-term monitoring results of soil water chemistry from four forested watersheds in South China, the applicability of a range of equilibriums describing aluminum mobilization was evaluated. The tested equilibriums included those for gibbsite, jurbanite, kaolinite, imogolite, and SOM-Al: Results show that the gibbsite equilibrium commonly used in several acidification models is not suitable for the typical forest soil in South China, while the modified empirical gibbsite equation is applicable with pK = - 2.40, a = 1.65 (for upper layer) and pK = - 2.82, a = 1.66 (for lower layers) at only pH > or = 4. Comparing with the empirical gibbsite equation, the other equilibriums do not perform better. It can also be seen that pAl varies slightly with pH decreases at pH < 4, which is unexplainable by any of these suggested equilibriums.
NASA Astrophysics Data System (ADS)
Margueron, Jérôme; Hoffmann Casali, Rudiney; Gulminelli, Francesca
2018-02-01
Employing recently proposed metamodeling for the nucleonic matter equation of state, we analyze neutron star global properties such as masses, radii, momentum of inertia, and others. The impact of the uncertainty on empirical parameters on these global properties is analyzed in a Bayesian statistical approach. Physical constraints, such as causality and stability, are imposed on the equation of state and different hypotheses for the direct Urca (dUrca) process are investigated. In addition, only metamodels with maximum masses above 2 M⊙ are selected. Our main results are the following: the equation of state exhibits a universal behavior against the dUrca hypothesis under the condition of charge neutrality and β equilibrium; neutron stars, if composed exclusively of nucleons and leptons, have a radius of 12.7 ±0.4 km for masses ranging from 1 up to 2 M⊙ ; a small radius lower than 11 km is very marginally compatible with our present knowledge of the nuclear empirical parameters; and finally, the most important empirical parameters which are still affected by large uncertainties and play an important role in determining the radius of neutrons stars are the slope and curvature of the symmetry energy (Lsym and Ksym) and, to a lower extent, the skewness parameters (Qsat /sym).
Test Operations Procedure (TOP) 1-1-062 Environmental Effects Data Collection
2008-09-12
this procedure. 11. ESTIMATION DESCRIPTION The prime example of an empirically based model is the Universal Soil Loss Equation ( USLE ) developed...impacts to human health and welfare and to the natural environment. The type of data collected might include noise levels, soil erosion, and...uptake relevant to flora/fauna and the soil erosion effects of proposed testing. c. Plan to identify any modifications/alternatives implemented
Monthly hydroclimatology of the continental United States
NASA Astrophysics Data System (ADS)
Petersen, Thomas; Devineni, Naresh; Sankarasubramanian, A.
2018-04-01
Physical/semi-empirical models that do not require any calibration are of paramount need for estimating hydrological fluxes for ungauged sites. We develop semi-empirical models for estimating the mean and variance of the monthly streamflow based on Taylor Series approximation of a lumped physically based water balance model. The proposed models require mean and variance of monthly precipitation and potential evapotranspiration, co-variability of precipitation and potential evapotranspiration and regionally calibrated catchment retention sensitivity, atmospheric moisture uptake sensitivity, groundwater-partitioning factor, and the maximum soil moisture holding capacity parameters. Estimates of mean and variance of monthly streamflow using the semi-empirical equations are compared with the observed estimates for 1373 catchments in the continental United States. Analyses show that the proposed models explain the spatial variability in monthly moments for basins in lower elevations. A regionalization of parameters for each water resources region show good agreement between observed moments and model estimated moments during January, February, March and April for mean and all months except May and June for variance. Thus, the proposed relationships could be employed for understanding and estimating the monthly hydroclimatology of ungauged basins using regional parameters.
Peacock, Stuart J; Richardson, Jeffrey R J
2007-09-01
This paper re-examines criticisms of cross-sectional methods used to test for supplier-induced demand (SID) and re-evaluates the empirical evidence using data from Australian medical services. Cross-sectional studies of SID have been criticised on two grounds. First, and most important, the inclusion of the doctor supply in the demand equation leads to an identification problem. This criticism is shown to be invalid, as the doctor supply variable is stochastic and depends upon a variety of other variables including the desirability of the location. Second, cross-sectional studies of SID fail diagnostic tests and produce artefactual findings due to model misspecification. Contrary to this, the re-evaluation of cross-sectional Australian data indicate that demand equations that do not include the doctor supply are misspecified. Empirical evidence from the re-evaluation of Australian medical services data supports the notion of SID. Demand and supply equations are well specified and have very good explanatory power. The demand equation is identified and the desirability of a location is an important predictor of the doctor supply. Results show an average price elasticity of demand of 0.22 and an average elasticity of demand with respect to the doctor supply of 0.46, with the impact of SID becoming stronger as the doctor supply rises. The conclusion we draw from this paper is that two of the main criticisms of the empirical evidence supporting the SID hypothesis have been inappropriately levelled at the methods used. More importantly, SID provides a satisfactory, and robust, explanation of the empirical data on the demand for medical services in Australia.
Cheng, Xuemin; Yang, Yikang; Hao, Qun
2016-01-01
The thermal environment is an important factor in the design of optical systems. This study investigated the thermal analysis technology of optical systems for navigation guidance and control in supersonic aircraft by developing empirical equations for the front temperature gradient and rear thermal diffusion distance, and for basic factors such as flying parameters and the structure of the optical system. Finite element analysis (FEA) was used to study the relationship between flying and front dome parameters and the system temperature field. Systematic deduction was then conducted based on the effects of the temperature field on the physical geometry and ray tracing performance of the front dome and rear optical lenses, by deriving the relational expressions between the system temperature field and the spot size and positioning precision of the rear optical lens. The optical systems used for navigation guidance and control in supersonic aircraft when the flight speed is in the range of 1–5 Ma were analysed using the derived equations. Using this new method it was possible to control the precision within 10% when considering the light spot received by the four-quadrant detector, and computation time was reduced compared with the traditional method of separately analysing the temperature field of the front dome and rear optical lens using FEA. Thus, the method can effectively increase the efficiency of parameter analysis and computation in an airborne optical system, facilitating the systematic, effective and integrated thermal analysis of airborne optical systems for navigation guidance and control. PMID:27763515
Cheng, Xuemin; Yang, Yikang; Hao, Qun
2016-10-17
The thermal environment is an important factor in the design of optical systems. This study investigated the thermal analysis technology of optical systems for navigation guidance and control in supersonic aircraft by developing empirical equations for the front temperature gradient and rear thermal diffusion distance, and for basic factors such as flying parameters and the structure of the optical system. Finite element analysis (FEA) was used to study the relationship between flying and front dome parameters and the system temperature field. Systematic deduction was then conducted based on the effects of the temperature field on the physical geometry and ray tracing performance of the front dome and rear optical lenses, by deriving the relational expressions between the system temperature field and the spot size and positioning precision of the rear optical lens. The optical systems used for navigation guidance and control in supersonic aircraft when the flight speed is in the range of 1-5 Ma were analysed using the derived equations. Using this new method it was possible to control the precision within 10% when considering the light spot received by the four-quadrant detector, and computation time was reduced compared with the traditional method of separately analysing the temperature field of the front dome and rear optical lens using FEA. Thus, the method can effectively increase the efficiency of parameter analysis and computation in an airborne optical system, facilitating the systematic, effective and integrated thermal analysis of airborne optical systems for navigation guidance and control.
Biot-Gassmann theory for velocities of gas hydrate-bearing sediments
Lee, M.W.
2002-01-01
Elevated elastic velocities are a distinct physical property of gas hydrate-bearing sediments. A number of velocity models and equations (e.g., pore-filling model, cementation model, effective medium theories, weighted equations, and time-average equations) have been used to describe this effect. In particular, the weighted equation and effective medium theory predict reasonably well the elastic properties of unconsolidated gas hydrate-bearing sediments. A weakness of the weighted equation is its use of the empirical relationship of the time-average equation as one element of the equation. One drawback of the effective medium theory is its prediction of unreasonably higher shear-wave velocity at high porosities, so that the predicted velocity ratio does not agree well with the observed velocity ratio. To overcome these weaknesses, a method is proposed, based on Biot-Gassmann theories and assuming the formation velocity ratio (shear to compressional velocity) of an unconsolidated sediment is related to the velocity ratio of the matrix material of the formation and its porosity. Using the Biot coefficient calculated from either the weighted equation or from the effective medium theory, the proposed method accurately predicts the elastic properties of unconsolidated sediments with or without gas hydrate concentration. This method was applied to the observed velocities at the Mallik 2L-39 well, Mackenzie Delta, Canada.
Universal equation for estimating ideal body weight and body weight at any BMI1
Peterson, Courtney M; Thomas, Diana M; Blackburn, George L; Heymsfield, Steven B
2016-01-01
Background: Ideal body weight (IBW) equations and body mass index (BMI) ranges have both been used to delineate healthy or normal weight ranges, although these 2 different approaches are at odds with each other. In particular, past IBW equations are misaligned with BMI values, and unlike BMI, the equations have failed to recognize that there is a range of ideal or target body weights. Objective: For the first time, to our knowledge, we merged the concepts of a linear IBW equation and of defining target body weights in terms of BMI. Design: With the use of calculus and approximations, we derived an easy-to-use linear equation that clinicians can use to calculate both IBW and body weight at any target BMI value. We measured the empirical accuracy of the equation with the use of NHANES data and performed a comparative analysis with past IBW equations. Results: Our linear equation allowed us to calculate body weights for any BMI and height with a mean empirical accuracy of 0.5–0.7% on the basis of NHANES data. Moreover, we showed that our body weight equation directly aligns with BMI values for both men and women, which avoids the overestimation and underestimation problems at the upper and lower ends of the height spectrum that have plagued past IBW equations. Conclusions: Our linear equation increases the sophistication of IBW equations by replacing them with a single universal equation that calculates both IBW and body weight at any target BMI and height. Therefore, our equation is compatible with BMI and can be applied with the use of mental math or a calculator without the need for an app, which makes it a useful tool for both health practitioners and the general public. PMID:27030535
Universal equation for estimating ideal body weight and body weight at any BMI.
Peterson, Courtney M; Thomas, Diana M; Blackburn, George L; Heymsfield, Steven B
2016-05-01
Ideal body weight (IBW) equations and body mass index (BMI) ranges have both been used to delineate healthy or normal weight ranges, although these 2 different approaches are at odds with each other. In particular, past IBW equations are misaligned with BMI values, and unlike BMI, the equations have failed to recognize that there is a range of ideal or target body weights. For the first time, to our knowledge, we merged the concepts of a linear IBW equation and of defining target body weights in terms of BMI. With the use of calculus and approximations, we derived an easy-to-use linear equation that clinicians can use to calculate both IBW and body weight at any target BMI value. We measured the empirical accuracy of the equation with the use of NHANES data and performed a comparative analysis with past IBW equations. Our linear equation allowed us to calculate body weights for any BMI and height with a mean empirical accuracy of 0.5-0.7% on the basis of NHANES data. Moreover, we showed that our body weight equation directly aligns with BMI values for both men and women, which avoids the overestimation and underestimation problems at the upper and lower ends of the height spectrum that have plagued past IBW equations. Our linear equation increases the sophistication of IBW equations by replacing them with a single universal equation that calculates both IBW and body weight at any target BMI and height. Therefore, our equation is compatible with BMI and can be applied with the use of mental math or a calculator without the need for an app, which makes it a useful tool for both health practitioners and the general public. © 2016 American Society for Nutrition.
Calculation of free turbulent mixing by interaction approach.
NASA Technical Reports Server (NTRS)
Morel, T.; Torda, T. P.
1973-01-01
The applicability of Bradshaw's interaction hypothesis to two-dimensional free shear flows was investigated. According to it, flows with velocity extrema may be considered to consist of several interacting layers. The hypothesis leads to a new expression for the shear stress which removes the usual restriction that shear stress vanishes at the velocity extremum. The approach is based on kinetic energy and the length scale equations. The compressible flow equations are simplified by restriction to low Mach numbers, and the range of their applicability is discussed. The empirical functions of the turbulence model are found here to be correlated with the spreading rate of the shear layer. The analysis demonstrates that the interaction hypothesis is a workable concept.
NASA Astrophysics Data System (ADS)
Klibanov, Michael V.; Kuzhuget, Andrey V.; Golubnichiy, Kirill V.
2016-01-01
A new empirical mathematical model for the Black-Scholes equation is proposed to forecast option prices. This model includes new interval for the price of the underlying stock, new initial and new boundary conditions. Conventional notions of maturity time and strike prices are not used. The Black-Scholes equation is solved as a parabolic equation with the reversed time, which is an ill-posed problem. Thus, a regularization method is used to solve it. To verify the validity of our model, real market data for 368 randomly selected liquid options are used. A new trading strategy is proposed. Our results indicates that our method is profitable on those options. Furthermore, it is shown that the performance of two simple extrapolation-based techniques is much worse. We conjecture that our method might lead to significant profits of those financial insitutions which trade large amounts of options. We caution, however, that further studies are necessary to verify this conjecture.
Modeling of transport phenomena in concrete porous media.
Plecas, Ilija
2014-02-01
Two fundamental concerns must be addressed when attempting to isolate low-level waste in a disposal facility on land. The first concern is isolating the waste from water, or hydrologic isolation. The second is preventing movement of the radionuclides out of the disposal facility, or radionuclide migration. Particularly, we have investigated here the latter modified scenario. To assess the safety for disposal of radioactive waste-concrete composition, the leakage of 60Co from a waste composite into a surrounding fluid has been studied. Leakage tests were carried out by the original method, developed at the Vinča Institute. Transport phenomena involved in the leaching of a radioactive material from a cement composite matrix are investigated using three methods based on theoretical equations. These are: the diffusion equation for a plane source: an equation for diffusion coupled to a first-order equation, and an empirical method employing a polynomial equation. The results presented in this paper are from a 25-y mortar and concrete testing project that will influence the design choices for radioactive waste packaging for a future Serbian radioactive waste disposal center.
Combined Effects Aluminized Explosives
2010-07-01
1 4 5 AREA EXPANSIONS Figure 4 Cylinder velocities for PAX-3 (left) and an empirical PAX-30 JWL (right) THERMODYNAMIC EQUATIONS OF...STATE The JWLB and Jones-Wilkins-Lee ( JWL ) equations of state were parameterized for combined effects explosives using fairly conventional methodology...state. Such warning messages should be ignored when using these JWLB and JWL equations of state representing eigenvalue detonation behavior. Table 1
Empirical improvements for estimating earthquake response spectra with random‐vibration theory
Boore, David; Thompson, Eric M.
2012-01-01
The stochastic method of ground‐motion simulation is often used in combination with the random‐vibration theory to directly compute ground‐motion intensity measures, thereby bypassing the more computationally intensive time‐domain simulations. Key to the application of random‐vibration theory to simulate response spectra is determining the duration (Drms) used in computing the root‐mean‐square oscillator response. Boore and Joyner (1984) originally proposed an equation for Drms , which was improved upon by Liu and Pezeshk (1999). Though these equations are both substantial improvements over using the duration of the ground‐motion excitation for Drms , we document systematic differences between the ground‐motion intensity measures derived from the random‐vibration and time‐domain methods for both of these Drms equations. These differences are generally less than 10% for most magnitudes, distances, and periods of engineering interest. Given the systematic nature of the differences, however, we feel that improved equations are warranted. We empirically derive new equations from time‐domain simulations for eastern and western North America seismological models. The new equations improve the random‐vibration simulations over a wide range of magnitudes, distances, and oscillator periods.
NASA Astrophysics Data System (ADS)
Lazzari, Maurizio; Danese, Maria; Gioia, Dario; Piccarreta, Marco
2013-04-01
Sedimentary budget estimation is an important topic for both scientific and social community, because it is crucial to understand both dynamics of orogenic belts and many practical problems, such as soil conservation and sediment accumulation in reservoir. Estimations of sediment yield or denudation rates in southern-central Italy are generally obtained by simple empirical relationships based on statistical regression between geomorphic parameters of the drainage network and the measured suspended sediment yield at the outlet of several drainage basins or through the use of models based on sediment delivery ratio or on soil loss equations. In this work, we perform a study of catchment dynamics and an estimation of sedimentary yield for several mountain catchments of the central-western sector of the Basilicata region, southern Italy. Sediment yield estimation has been obtained through both an indirect estimation of suspended sediment yield based on the Tu index (mean annual suspension sediment yield, Ciccacci et al., 1980) and the application of the Rusle (Renard et al., 1997) and the USPED (Mitasova et al., 1996) empirical methods. The preliminary results indicate a reliable difference between the RUSLE and USPED methods and the estimation based on the Tu index; a critical data analysis of results has been carried out considering also the present-day spatial distribution of erosion, transport and depositional processes in relation to the maps obtained from the application of those different empirical methods. The studied catchments drain an artificial reservoir (i.e. the Camastra dam), where a detailed evaluation of the amount of historical sediment storage has been collected. Sediment yield estimation obtained by means of the empirical methods have been compared and checked with historical data of sediment accumulation measured in the artificial reservoir of the Camastra dam. The validation of such estimations of sediment yield at the scale of large catchments using sediment storage in reservoirs provides a good opportunity: i) to test the reliability of the empirical methods used to estimate the sediment yield; ii) to investigate the catchment dynamics and its spatial and temporal evolution in terms of erosion, transport and deposition. References Ciccacci S., Fredi F., Lupia Palmieri E., Pugliese F., 1980. Contributo dell'analisi geomorfica quantitativa alla valutazione dell'entita dell'erosione nei bacini fluviali. Bollettino della Società Geologica Italiana 99: 455-516. Mitasova H, Hofierka J, Zlocha M, Iverson LR. 1996. Modeling topographic potential for erosion and deposition using GIS. International Journal of Geographical Information Systems 10: 629-641. Renard K.G., Foster G.R., Weesies G.A., McCool D.K., Yoder D.C., 1997. Predicting soil erosion by water: a guide to conservation planning with the Revised Universal Soil Loss Equation (RUSLE), USDA-ARS, Agricultural Handbook No. 703.
Katharaki, Maria; Daskalakis, Stelios; Mantas, John
2010-01-01
The objective of this paper is to assess the future adaptability of e-Learning platforms within postgraduate modules. An ongoing empirical assessment was conducted amongst postgraduate students, based on the Technology Acceptance Model (TAM). The current paper presents the outcomes from the second phase of a survey, involving fifty six participants. Data analysis was performed using a structural equation model, based on partial least squares. Results highlighted the very strong effect of perceived usefulness and perceived ease of use to attitude towards using e-Learning platforms. Consequently, attitude towards use proved to be a very strong predictor of behavioral intention. Perceived usefulness, on the contrary, did not prove to have an effect to behavioral intention. Implications on the potential of using e-Learning platforms are discussed along with limitations and future directions of the study.
Modeling techniques for quantum cascade lasers
NASA Astrophysics Data System (ADS)
Jirauschek, Christian; Kubis, Tillmann
2014-03-01
Quantum cascade lasers are unipolar semiconductor lasers covering a wide range of the infrared and terahertz spectrum. Lasing action is achieved by using optical intersubband transitions between quantized states in specifically designed multiple-quantum-well heterostructures. A systematic improvement of quantum cascade lasers with respect to operating temperature, efficiency, and spectral range requires detailed modeling of the underlying physical processes in these structures. Moreover, the quantum cascade laser constitutes a versatile model device for the development and improvement of simulation techniques in nano- and optoelectronics. This review provides a comprehensive survey and discussion of the modeling techniques used for the simulation of quantum cascade lasers. The main focus is on the modeling of carrier transport in the nanostructured gain medium, while the simulation of the optical cavity is covered at a more basic level. Specifically, the transfer matrix and finite difference methods for solving the one-dimensional Schrödinger equation and Schrödinger-Poisson system are discussed, providing the quantized states in the multiple-quantum-well active region. The modeling of the optical cavity is covered with a focus on basic waveguide resonator structures. Furthermore, various carrier transport simulation methods are discussed, ranging from basic empirical approaches to advanced self-consistent techniques. The methods include empirical rate equation and related Maxwell-Bloch equation approaches, self-consistent rate equation and ensemble Monte Carlo methods, as well as quantum transport approaches, in particular the density matrix and non-equilibrium Green's function formalism. The derived scattering rates and self-energies are generally valid for n-type devices based on one-dimensional quantum confinement, such as quantum well structures.
Bernoulli-Langevin Wind Speed Model for Simulation of Storm Events
NASA Astrophysics Data System (ADS)
Fürstenau, Norbert; Mittendorf, Monika
2016-12-01
We present a simple nonlinear dynamics Langevin model for predicting the instationary wind speed profile during storm events typically accompanying extreme low-pressure situations. It is based on a second-degree Bernoulli equation with δ-correlated Gaussian noise and may complement stationary stochastic wind models. Transition between increasing and decreasing wind speed and (quasi) stationary normal wind and storm states are induced by the sign change of the controlling time-dependent rate parameter k(t). This approach corresponds to the simplified nonlinear laser dynamics for the incoherent to coherent transition of light emission that can be understood by a phase transition analogy within equilibrium thermodynamics [H. Haken, Synergetics, 3rd ed., Springer, Berlin, Heidelberg, New York 1983/2004.]. Evidence for the nonlinear dynamics two-state approach is generated by fitting of two historical wind speed profiles (low-pressure situations "Xaver" and "Christian", 2013) taken from Meteorological Terminal Air Report weather data, with a logistic approximation (i.e. constant rate coefficients k) to the solution of our dynamical model using a sum of sigmoid functions. The analytical solution of our dynamical two-state Bernoulli equation as obtained with a sinusoidal rate ansatz k(t) of period T (=storm duration) exhibits reasonable agreement with the logistic fit to the empirical data. Noise parameter estimates of speed fluctuations are derived from empirical fit residuals and by means of a stationary solution of the corresponding Fokker-Planck equation. Numerical simulations with the Bernoulli-Langevin equation demonstrate the potential for stochastic wind speed profile modeling and predictive filtering under extreme storm events that is suggested for applications in anticipative air traffic management.
Modeling techniques for quantum cascade lasers
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jirauschek, Christian; Kubis, Tillmann
2014-03-15
Quantum cascade lasers are unipolar semiconductor lasers covering a wide range of the infrared and terahertz spectrum. Lasing action is achieved by using optical intersubband transitions between quantized states in specifically designed multiple-quantum-well heterostructures. A systematic improvement of quantum cascade lasers with respect to operating temperature, efficiency, and spectral range requires detailed modeling of the underlying physical processes in these structures. Moreover, the quantum cascade laser constitutes a versatile model device for the development and improvement of simulation techniques in nano- and optoelectronics. This review provides a comprehensive survey and discussion of the modeling techniques used for the simulation ofmore » quantum cascade lasers. The main focus is on the modeling of carrier transport in the nanostructured gain medium, while the simulation of the optical cavity is covered at a more basic level. Specifically, the transfer matrix and finite difference methods for solving the one-dimensional Schrödinger equation and Schrödinger-Poisson system are discussed, providing the quantized states in the multiple-quantum-well active region. The modeling of the optical cavity is covered with a focus on basic waveguide resonator structures. Furthermore, various carrier transport simulation methods are discussed, ranging from basic empirical approaches to advanced self-consistent techniques. The methods include empirical rate equation and related Maxwell-Bloch equation approaches, self-consistent rate equation and ensemble Monte Carlo methods, as well as quantum transport approaches, in particular the density matrix and non-equilibrium Green's function formalism. The derived scattering rates and self-energies are generally valid for n-type devices based on one-dimensional quantum confinement, such as quantum well structures.« less
Predicting plot soil loss by empirical and process-oriented approaches: A review
USDA-ARS?s Scientific Manuscript database
Soil erosion directly affects the quality of the soil, its agricultural productivity and its biological diversity. Many mathematical models have been developed to estimate plot soil erosion at different temporal scales. At present, empirical soil loss equations and process-oriented models are consid...
NASA Astrophysics Data System (ADS)
Xie, Xuemei
Based on a survey to 1206 Chinese firms, this paper empirically explores the factors impacting cooperative innovation effect of firms, and seeks to explore the relationship between cooperative innovation effect (CIE) and innovation performance using the technique of Structural Equation Modeling (SEM). The study finds there are significant positive relationships between basic sustaining factors, factors of government and policy, factors of cooperation mechanism and social network, and cooperative innovation effect. However, the result reveals that factors of government and policy demonstrate little impact on the CIE of firms compared with other factors. It is hoped that the findings can pave the way for future studies in improving cooperative innovation capacity for firms in emerging countries.
An empirical test of competing theories of hazard-related trust: the case of GM food.
Allum, Nick
2007-08-01
Few scholars doubt the importance of trust in explaining variation in public perception of technological risk. Relatively little, however, is known about the particular types of judgments that people use in granting or withholding trust. This article presents findings from an empirical study that explores several dimensions of trust relevant for citizens' judgments of scientists involved in the development of GM food. The relationship between particular dimensions of trust and perceptions of GM food risk is also explored, using structural equation modeling. Results suggest that trust judgments based on the perception of shared values are most important in relation to GM food risk, but that judgments about scientists' technical competence are also important.
Design flood hydrograph estimation procedure for small and fully-ungauged basins
NASA Astrophysics Data System (ADS)
Grimaldi, S.; Petroselli, A.
2013-12-01
The Rational Formula is the most applied equation in practical hydrology due to its simplicity and the effective compromise between theory and data availability. Although the Rational Formula is affected by several drawbacks, it is reliable and surprisingly accurate considering the paucity of input information. However, after more than a century, the recent computational, theoretical, and large-scale monitoring progresses compel us to try to suggest a more advanced yet still empirical procedure for estimating peak discharge in small and ungauged basins. In this contribution an alternative empirical procedure (named EBA4SUB - Event Based Approach for Small and Ungauged Basins) based on the common modelling steps: design hyetograph, rainfall excess, and rainfall-runoff transformation, is described. The proposed approach, accurately adapted for the fully-ungauged basin condition, provides a potentially better estimation of the peak discharge, a design hydrograph shape, and, most importantly, reduces the subjectivity of the hydrologist in its application.
Modeling Demic and Cultural Diffusion: An Introduction.
Fort, Joaquim; Crema, Enrico R; Madella, Marco
2015-07-01
Identifying the processes by which human cultures spread across different populations is one of the most topical objectives shared among different fields of study. Seminal works have analyzed a variety of data and attempted to determine whether empirically observed patterns are the result of demic and/or cultural diffusion. This special issue collects articles exploring several themes (from modes of cultural transmission to drivers of dispersal mechanisms) and contexts (from the Neolithic in Europe to the spread of computer programming languages), which offer new insights that will augment the theoretical and empirical basis for the study of demic and cultural diffusion. In this introduction we outline the state of art in the modeling of these processes, briefly discuss the pros and cons of two of the most commonly used frameworks (equation-based models and agent-based models), and summarize the significance of each article in this special issue.
Uncertainty quantification in Eulerian-Lagrangian models for particle-laden flows
NASA Astrophysics Data System (ADS)
Fountoulakis, Vasileios; Jacobs, Gustaaf; Udaykumar, Hs
2017-11-01
A common approach to ameliorate the computational burden in simulations of particle-laden flows is to use a point-particle based Eulerian-Lagrangian model, which traces individual particles in their Lagrangian frame and models particles as mathematical points. The particle motion is determined by Stokes drag law, which is empirically corrected for Reynolds number, Mach number and other parameters. The empirical corrections are subject to uncertainty. Treating them as random variables renders the coupled system of PDEs and ODEs stochastic. An approach to quantify the propagation of this parametric uncertainty to the particle solution variables is proposed. The approach is based on averaging of the governing equations and allows for estimation of the first moments of the quantities of interest. We demonstrate the feasibility of our proposed methodology of uncertainty quantification of particle-laden flows on one-dimensional linear and nonlinear Eulerian-Lagrangian systems. This research is supported by AFOSR under Grant FA9550-16-1-0008.
An objective analysis of the dynamic nature of field capacity
NASA Astrophysics Data System (ADS)
Twarakavi, Navin K. C.; Sakai, Masaru; Å Imå¯Nek, Jirka
2009-10-01
Field capacity is one of the most commonly used, and yet poorly defined, soil hydraulic properties. Traditionally, field capacity has been defined as the amount of soil moisture after excess water has drained away and the rate of downward movement has materially decreased. Unfortunately, this qualitative definition does not lend itself to an unambiguous quantitative approach for estimation. Because of the vagueness in defining what constitutes "drainage of excess water" from a soil, the estimation of field capacity has often been based upon empirical guidelines. These empirical guidelines are either time, pressure, or flux based. In this paper, we developed a numerical approach to estimate field capacity using a flux-based definition. The resulting approach was implemented on the soil parameter data set used by Schaap et al. (2001), and the estimated field capacity was compared to traditional definitions of field capacity. The developed modeling approach was implemented using the HYDRUS-1D software with the capability of simultaneously estimating field capacity for multiple soils with soil hydraulic parameter data. The Richards equation was used in conjunction with the van Genuchten-Mualem model to simulate variably saturated flow in a soil. Using the modeling approach to estimate field capacity also resulted in additional information such as (1) the pressure head, at which field capacity is attained, and (2) the drainage time needed to reach field capacity from saturated conditions under nonevaporative conditions. We analyzed the applicability of the modeling-based approach to estimate field capacity on real-world soils data. We also used the developed method to create contour diagrams showing the variation of field capacity with texture. It was found that using benchmark pressure heads to estimate field capacity from the retention curve leads to inaccurate results. Finally, a simple analytical equation was developed to predict field capacity from soil hydraulic parameter information. The analytical equation was found to be effective in its ability to predict field capacities.
Correlation of published data on the solubility of methane in H/sub 2/O-NaCl solutions
DOE Office of Scientific and Technical Information (OSTI.GOV)
Coco, L.T.; Johnson, A.E. Jr.; Bebout, D.G.
1981-01-01
A new correlation of the available published data for the solubility of methane in water was developed, based on fundamental thermodynamic relationships. An empirical relationship for the salting-out coefficient of NaCl for methane solubility in water was determined as a function of temperature. Root mean square and average deviations for the new correlation, the Haas correlation, and the revised Blount equation are compared.
Group Theoretical Characterization of Wave Equations
NASA Astrophysics Data System (ADS)
Nisticò, Giuseppe
2017-12-01
Group theoretical methods, worked out in particular by Mackey and Wigner, allow to attain the explicit Quantum Theory of a free particle through a purely deductive development based on symmetry principles. The extension of these methods to the case of an interacting particle finds a serious obstacle in the loss of the symmetry condition for the transformations of Galilei's group. The known attempts towards such an extension introduce restrictions which lead to theories empirically too limited. In the present article we show how the difficulties raised by the loss of symmetry can be overcome without the restrictions that affect tha past attempts. According to our results, the different specific forms of the wave equation of an interacting particle are implied by particular first order invariance properties that characterize the interaction with respect to specific sub-groups of galileian transformations. Moreover, the possibility of yet unknown forms of the wave equation is left open.
Abnormal formation velocities and applications to pore pressure prediction
NASA Astrophysics Data System (ADS)
Liu, Libin; Shen, Guoqiang; Wang, Zhentao; Yang, Hongwei; Han, Hongwei; Cheng, Yuanfeng
2018-06-01
The pore pressure is a vital concept to the petroleum industry and cannot be ignored by either reservoir engineers or geoscientists. Based on theoretical analyses of effective stresses and the grain packing model, a new equation is proposed for predicting pore pressures from formation velocity data. The predictions agree well with both measured pressures and estimations using Eaton's empirical equation, but the application of the new equation to seismic data is simple and convenient. One application example shows that the identification of sweet spots is much easier using pore pressure data than with inverted seismic velocity data. In another application example using field seismic data, a distribution of overpressured strata is revealed, which is a crucial clue for petroleum generation and accumulation. Still, the accuracy of pore pressure prediction is hardly always guaranteed, mainly owing to the complexity of the real geology and the suitability of specific assumptions about the underlying rock physics.
Simulating sunflower canopy temperatures to infer root-zone soil water potential
NASA Technical Reports Server (NTRS)
Choudhury, B. J.; Idso, S. B.
1983-01-01
A soil-plant-atmosphere model for sunflower (Helianthus annuus L.), together with clear sky weather data for several days, is used to study the relationship between canopy temperature and root-zone soil water potential. Considering the empirical dependence of stomatal resistance on insolation, air temperature and leaf water potential, a continuity equation for water flux in the soil-plant-atmosphere system is solved for the leaf water potential. The transpirational flux is calculated using Monteith's combination equation, while the canopy temperature is calculated from the energy balance equation. The simulation shows that, at high soil water potentials, canopy temperature is determined primarily by air and dew point temperatures. These results agree with an empirically derived linear regression equation relating canopy-air temperature differential to air vapor pressure deficit. The model predictions of leaf water potential are also in agreement with observations, indicating that measurements of canopy temperature together with a knowledge of air and dew point temperatures can provide a reliable estimate of the root-zone soil water potential.
NASA Astrophysics Data System (ADS)
Bora, S. S.; Scherbaum, F.; Kuehn, N. M.; Stafford, P.; Edwards, B.
2014-12-01
In a probabilistic seismic hazard assessment (PSHA) framework, it still remains a challenge to adjust ground motion prediction equations (GMPEs) for application in different seismological environments. In this context, this study presents a complete framework for the development of a response spectral GMPE easily adjustable to different seismological conditions; and which does not suffer from the technical problems associated with the adjustment in response spectral domain. Essentially, the approach consists of an empirical FAS (Fourier Amplitude Spectrum) model and a duration model for ground motion which are combined within the random vibration theory (RVT) framework to obtain the full response spectral ordinates. Additionally, FAS corresponding to individual acceleration records are extrapolated beyond the frequency range defined by the data using the stochastic FAS model, obtained by inversion as described in Edwards & Faeh, (2013). To that end, an empirical model for a duration, which is tuned to optimize the fit between RVT based and observed response spectral ordinate, at each oscillator frequency is derived. Although, the main motive of the presented approach was to address the adjustability issues of response spectral GMPEs; comparison, of median predicted response spectra with the other regional models indicate that presented approach can also be used as a stand-alone model. Besides that, a significantly lower aleatory variability (σ<0.5 in log units) in comparison to other regional models, at shorter periods brands it to a potentially viable alternative to the classical regression (on response spectral ordinates) based GMPEs for seismic hazard studies in the near future. The dataset used for the presented analysis is a subset of the recently compiled database RESORCE-2012 across Europe, Middle East and the Mediterranean region.
NASA Technical Reports Server (NTRS)
Schonberg, William P.; Mohamed, Essam
1997-01-01
This report presents the results of a study whose objective was to develop first-principles-based models of hole size and maximum tip-to-tip crack length for a spacecraft module pressure wall that has been perforated in an orbital debris particle impact. The hole size and crack length models are developed by sequentially characterizing the phenomena comprising the orbital debris impact event, including the initial impact, the creation and motion of a debris cloud within the dual-wall system, the impact of the debris cloud on the pressure wall, the deformation of the pressure wall due to debris cloud impact loading prior to crack formation, pressure wall crack initiation, propagation, and arrest, and finally pressure wall deformation following crack initiation and growth. The model development has been accomplished through the application of elementary shock physics and thermodynamic theory, as well as the principles of mass, momentum, and energy conservation. The predictions of the model developed herein are compared against the predictions of empirically-based equations for hole diameters and maximum tip-to-tip crack length for three International Space Station wall configurations. The ISS wall systems considered are the baseline U.S. Lab Cylinder, the enhanced U.S. Lab Cylinder, and the U.S. Lab Endcone. The empirical predictor equations were derived from experimentally obtained hole diameters and crack length data. The original model predictions did not compare favorably with the experimental data, especially for cases in which pressure wall petalling did not occur. Several modifications were made to the original model to bring its predictions closer in line with the experimental results. Following the adjustment of several empirical constants, the predictions of the modified analytical model were in much closer agreement with the experimental results.
Piezoviscosity In Lubrication Of Nonconformal Contacts
NASA Technical Reports Server (NTRS)
Jeng, Yeau-Ren; Hamrock, Bernard J.; Brewe, David E.
1988-01-01
Developments in theory of lubrication. Analysis of piezoviscous-rigid regime of lubrication of two ellipsoidal contacts. Begins with Reynolds equation for point contact. Equation nondimensionalized using Roelands empirical formula and Dowson and Higginson formula. Equation solved numerically. Solutions obtained for full spectrum of conditions to find effects of dimensionless load, speed, parameters of lubricated and lubricating materials, and angle between direction of rolling and direction of entrainment of lubricant.
NASA Technical Reports Server (NTRS)
Mintz, Y.; Walker, G. K.
1993-01-01
The global fields of normal monthly soil moisture and land surface evapotranspiration are derived with a simple water budget model that has precipitation and potential evapotranspiration as inputs. The precipitation is observed and the potential evapotranspiration is derived from the observed surface air temperature with the empirical regression equation of Thornthwaite (1954). It is shown that at locations where the net surface radiation flux has been measured, the potential evapotranspiration given by the Thornthwaite equation is in good agreement with those obtained with the radiation-based formulations of Priestley and Taylor (1972), Penman (1948), and Budyko (1956-1974), and this provides the justification for the use of the Thornthwaite equation. After deriving the global fields of soil moisture and evapotranspiration, the assumption is made that the potential evapotranspiration given by the Thornthwaite equation and by the Priestley-Taylor equation will everywhere be about the same; the inverse of the Priestley-Taylor equation is used to obtain the normal monthly global fields of net surface radiation flux minus ground heat storage. This and the derived evapotranspiration are then used in the equation for energy conservation at the surface of the earth to obtain the global fields of normal monthly sensible heat flux from the land surface to the atmosphere.
The rate of bubble growth in a superheated liquid in pool boiling
NASA Astrophysics Data System (ADS)
Abdollahi, Mohammad Reza; Jafarian, Mehdi; Jamialahmadi, Mohammad
2017-12-01
A semi-empirical model for the estimation of the rate of bubble growth in nucleate pool boiling is presented, considering a new equation to estimate the temperature history of the bubble in the bulk of liquid. The conservation equations of energy, mass and momentum have been firstly derived and solved analytically. The present analytical model of the bubble growth predicts that the radius of the bubble grows as a function of √{t}.{\\operatorname{erf}}( N√{t}) , while so far the bubble growth rate has been mainly correlated to √{t} in the previous studies. In the next step, the analytical solutions were used to develop a new semi-empirical equation. To achieve this, firstly the analytical solution were non-dimensionalised and then the experimental data, available in the literature, were applied to tune the dimensionless coefficients appeared in the dimensionless equation. Finally, the reliability of the proposed semi-empirical model was assessed through comparison of the model predictions with the available experimental data in the literature, which were not applied in the tuning of the dimensionless parameters of the model. The comparison of the model predictions with other proposed models in the literature was also performed. These comparisons show that this model enables more accurate predictions than previously proposed models with a deviation of less than 10% in a wide range of operating conditions.
Structural Equations and Causal Explanations: Some Challenges for Causal SEM
ERIC Educational Resources Information Center
Markus, Keith A.
2010-01-01
One common application of structural equation modeling (SEM) involves expressing and empirically investigating causal explanations. Nonetheless, several aspects of causal explanation that have an impact on behavioral science methodology remain poorly understood. It remains unclear whether applications of SEM should attempt to provide complete…
DOE Office of Scientific and Technical Information (OSTI.GOV)
Balajewicz, Maciej; Tezaur, Irina; Dowell, Earl
For a projection-based reduced order model (ROM) of a fluid flow to be stable and accurate, the dynamics of the truncated subspace must be taken into account. This paper proposes an approach for stabilizing and enhancing projection-based fluid ROMs in which truncated modes are accounted for a priori via a minimal rotation of the projection subspace. Attention is focused on the full non-linear compressible Navier–Stokes equations in specific volume form as a step toward a more general formulation for problems with generic non-linearities. Unlike traditional approaches, no empirical turbulence modeling terms are required, and consistency between the ROM and themore » Navier–Stokes equation from which the ROM is derived is maintained. Mathematically, the approach is formulated as a trace minimization problem on the Stiefel manifold. As a result, the reproductive as well as predictive capabilities of the method are evaluated on several compressible flow problems, including a problem involving laminar flow over an airfoil with a high angle of attack, and a channel-driven cavity flow problem.« less
Balajewicz, Maciej; Tezaur, Irina; Dowell, Earl
2016-05-25
For a projection-based reduced order model (ROM) of a fluid flow to be stable and accurate, the dynamics of the truncated subspace must be taken into account. This paper proposes an approach for stabilizing and enhancing projection-based fluid ROMs in which truncated modes are accounted for a priori via a minimal rotation of the projection subspace. Attention is focused on the full non-linear compressible Navier–Stokes equations in specific volume form as a step toward a more general formulation for problems with generic non-linearities. Unlike traditional approaches, no empirical turbulence modeling terms are required, and consistency between the ROM and themore » Navier–Stokes equation from which the ROM is derived is maintained. Mathematically, the approach is formulated as a trace minimization problem on the Stiefel manifold. As a result, the reproductive as well as predictive capabilities of the method are evaluated on several compressible flow problems, including a problem involving laminar flow over an airfoil with a high angle of attack, and a channel-driven cavity flow problem.« less
Carkovic, Athena B; Pastén, Pablo A; Bonilla, Carlos A
2015-04-15
Water erosion is a leading cause of soil degradation and a major nonpoint source pollution problem. Many efforts have been undertaken to estimate the amount and size distribution of the sediment leaving the field. Multi-size class water erosion models subdivide eroded soil into different sizes and estimate the aggregate's composition based on empirical equations derived from agricultural soils. The objective of this study was to evaluate these equations on soil samples collected from natural landscapes (uncultivated) and fire-affected soils. Chemical, physical, and soil fractions and aggregate composition analyses were performed on samples collected in the Chilean Patagonia and later compared with the equations' estimates. The results showed that the empirical equations were not suitable for predicting the sediment fractions. Fine particles, including primary clay, primary silt, and small aggregates (<53 μm) were over-estimated, and large aggregates (>53 μm) and primary sand were under-estimated. The uncultivated and fire-affected soils showed a reduced fraction of fine particles in the sediment, as clay and silt were mostly in the form of large aggregates. Thus, a new set of equations was developed for these soils, where small aggregates were defined as particles with sizes between 53 μm and 250 μm and large aggregates as particles>250 μm. With r(2) values between 0.47 and 0.98, the new equations provided better estimates for primary sand and large aggregates. The aggregate's composition was also well predicted, especially the silt and clay fractions in the large aggregates from uncultivated soils (r(2)=0.63 and 0.83, respectively) and the fractions of silt in the small aggregates (r(2)=0.84) and clay in the large aggregates (r(2)=0.78) from fire-affected soils. Overall, these new equations proved to be better predictors for the sediment and aggregate's composition in uncultivated and fire-affected soils, and they reduce the error when estimating soil loss in natural landscapes. Copyright © 2015 Elsevier B.V. All rights reserved.
NASA Astrophysics Data System (ADS)
Andrei, Armas; Robert, Beilicci; Erika, Beilicci
2017-10-01
MIKE 11 is an advanced hydroinformatic tool, a professional engineering software package for simulation of one-dimensional flows in estuaries, rivers, irrigation systems, channels and other water bodies. MIKE 11 is a 1-dimensional river model. It was developed by DHI Water · Environment · Health, Denmark. The basic computational procedure of HEC-RAS for steady flow is based on the solution of the one-dimensional energy equation. Energy losses are evaluated by friction and contraction / expansion. The momentum equation may be used in situations where the water surface profile is rapidly varied. These situations include hydraulic jumps, hydraulics of bridges, and evaluating profiles at river confluences. For unsteady flow, HEC-RAS solves the full, dynamic, 1-D Saint Venant Equation using an implicit, finite difference method. The unsteady flow equation solver was adapted from Dr. Robert L. Barkau’s UNET package. Fluid motion is controlled by the basic principles of conservation of mass, energy and momentum, which form the basis of fluid mechanics and hydraulic engineering. Complex flow situations must be solved using empirical approximations and numerical models, which are based on derivations of the basic principles (backwater equation, Navier-Stokes equation etc.). All numerical models are required to make some form of approximation to solve these principles, and consequently all have their limitations. The study of hydraulics and fluid mechanics is founded on the three basic principles of conservation of mass, energy and momentum. Real-life situations are frequently too complex to solve without the aid of numerical models. There is a tendency among some engineers to discard the basic principles taught at university and blindly assume that the results produced by the model are correct. Regardless of the complexity of models and despite the claims of their developers, all numerical models are required to make approximations. These may be related to geometric limitations, numerical simplification, or the use of empirical correlations. Some are obvious: one-dimensional models must average properties over the two remaining directions. It is the less obvious and poorly advertised approximations that pose the greatest threat to the novice user. Some of these, such as the inability of one-dimensional unsteady models to simulate supercritical flow can cause significant inaccuracy in the model predictions.
Conservational PDF Equations of Turbulence
NASA Technical Reports Server (NTRS)
Shih, Tsan-Hsing; Liu, Nan-Suey
2010-01-01
Recently we have revisited the traditional probability density function (PDF) equations for the velocity and species in turbulent incompressible flows. They are all unclosed due to the appearance of various conditional means which are modeled empirically. However, we have observed that it is possible to establish a closed velocity PDF equation and a closed joint velocity and species PDF equation through conditions derived from the integral form of the Navier-Stokes equations. Although, in theory, the resulted PDF equations are neither general nor unique, they nevertheless lead to the exact transport equations for the first moment as well as all higher order moments. We refer these PDF equations as the conservational PDF equations. This observation is worth further exploration for its validity and CFD application
Semi-empirical model for prediction of unsteady forces on an airfoil with application to flutter
NASA Technical Reports Server (NTRS)
Mahajan, Aparajit J.; Kaza, Krishna Rao V.
1992-01-01
A semi-empirical model is described for predicting unsteady aerodynamic forces on arbitrary airfoils under mildly stalled and unstalled conditions. Aerodynamic forces are modeled using second order ordinary differential equations for lift and moment with airfoil motion as the input. This model is simultaneously integrated with structural dynamics equations to determine flutter characteristics for a two degrees-of-freedom system. Results for a number of cases are presented to demonstrate the suitability of this model to predict flutter. Comparison is made to the flutter characteristics determined by a Navier-Stokes solver and also the classical incompressible potential flow theory.
Semi-empirical model for prediction of unsteady forces on an airfoil with application to flutter
NASA Technical Reports Server (NTRS)
Mahajan, A. J.; Kaza, K. R. V.; Dowell, E. H.
1993-01-01
A semi-empirical model is described for predicting unsteady aerodynamic forces on arbitrary airfoils under mildly stalled and unstalled conditions. Aerodynamic forces are modeled using second order ordinary differential equations for lift and moment with airfoil motion as the input. This model is simultaneously integrated with structural dynamics equations to determine flutter characteristics for a two degrees-of-freedom system. Results for a number of cases are presented to demonstrate the suitability of this model to predict flutter. Comparison is made to the flutter characteristics determined by a Navier-Stokes solver and also the classical incompressible potential flow theory.
Preequating with Empirical Item Characteristic Curves: An Observed-Score Preequating Method
ERIC Educational Resources Information Center
Zu, Jiyun; Puhan, Gautam
2014-01-01
Preequating is in demand because it reduces score reporting time. In this article, we evaluated an observed-score preequating method: the empirical item characteristic curve (EICC) method, which makes preequating without item response theory (IRT) possible. EICC preequating results were compared with a criterion equating and with IRT true-score…
N-Loop Learning: Part II--An Empirical Investigation
ERIC Educational Resources Information Center
Simonin, Bernard L.
2017-01-01
Purpose: Through a survey of firm's experiences with strategic alliances and a structural equation modeling approach, the aim of this study is to stimulate further interest in modeling and empirical research in the area of N-loop learning. Although the concepts of single-loop and double-loop learning, in particular, are well established in the…
Empirical data and the variance-covariance matrix for the 1969 Smithsonian Standard Earth (2)
NASA Technical Reports Server (NTRS)
Gaposchkin, E. M.
1972-01-01
The empirical data used in the 1969 Smithsonian Standard Earth (2) are presented. The variance-covariance matrix, or the normal equations, used for correlation analysis, are considered. The format and contents of the matrix, available on magnetic tape, are described and a sample printout is given.
Deterministic multidimensional nonuniform gap sampling.
Worley, Bradley; Powers, Robert
2015-12-01
Born from empirical observations in nonuniformly sampled multidimensional NMR data relating to gaps between sampled points, the Poisson-gap sampling method has enjoyed widespread use in biomolecular NMR. While the majority of nonuniform sampling schemes are fully randomly drawn from probability densities that vary over a Nyquist grid, the Poisson-gap scheme employs constrained random deviates to minimize the gaps between sampled grid points. We describe a deterministic gap sampling method, based on the average behavior of Poisson-gap sampling, which performs comparably to its random counterpart with the additional benefit of completely deterministic behavior. We also introduce a general algorithm for multidimensional nonuniform sampling based on a gap equation, and apply it to yield a deterministic sampling scheme that combines burst-mode sampling features with those of Poisson-gap schemes. Finally, we derive a relationship between stochastic gap equations and the expectation value of their sampling probability densities. Copyright © 2015 Elsevier Inc. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wood, D.A.
1988-02-01
Thermal maturity can be calculated with time-temperature indices (TTI) based on the Arrhenius equation using kinetics applicable to a range of Types II and III kerogens. These TTIs are compared with TTI calculations based on the Lopatin method and are related theoretically (and empirically via vitrinite reflectance) to the petroleum-generation window. The TTIs for both methods are expressed mathematically as integrals of temperature combined with variable linear heating rates for selected temperature intervals. Heating rates control the thermal-maturation trends of buried sediments. Relative to Arrhenius TTIs, Lopatin TTIs tend to underestimate thermal maturity at high heating rates and overestimate itmore » as low heating rates. Complex burial histories applicable to a range of tectonic environments illustrate the different exploration decisions that might be made on the basis of independent results of these two thermal-maturation models. 15 figures, 8 tables.« less
First-principles calculations on thermodynamic properties of BaTiO3 rhombohedral phase.
Bandura, Andrei V; Evarestov, Robert A
2012-07-05
The calculations based on the linear combination of atomic orbitals have been performed for the low-temperature phase of BaTiO(3) crystal. Structural and electronic properties, as well as phonon frequencies were obtained using hybrid PBE0 exchange-correlation functional. The calculated frequencies and total energies at different volumes have been used to determine the equation of state and thermal contribution to the Helmholtz free energy within the quasiharmonic approximation. For the first time, the bulk modulus, volume thermal expansion coefficient, heat capacity, and Grüneisen parameters in BaTiO(3) rhombohedral phase have been estimated at zero pressure and temperatures form 0 to 200 K, based on the results of first-principles calculations. Empirical equation has been proposed to reproduce the temperature dependence of the calculated quantities. The agreement between the theoretical and experimental thermodynamic properties was found to be satisfactory. Copyright © 2012 Wiley Periodicals, Inc.
1980-01-01
SUPPLEMENTARY NOTES Is. KEY WORDS (Continue on reverse ede If neceseay id Identify by block number) Carbon Monoxide (CO) Computer Program Carboxyhemoglobin ...several researchers, which predicts the instantaneous amount of carboxyhemoglobin (COHb) in the blood of a person based upon the amount of carbon monoxide...developed from an empirical equation (derived from reference I and detailed in reference 3) which predicts the amount of carboxyhemoglobin (COHb) in
Understanding and Modeling Teams As Dynamical Systems
Gorman, Jamie C.; Dunbar, Terri A.; Grimm, David; Gipson, Christina L.
2017-01-01
By its very nature, much of teamwork is distributed across, and not stored within, interdependent people working toward a common goal. In this light, we advocate a systems perspective on teamwork that is based on general coordination principles that are not limited to cognitive, motor, and physiological levels of explanation within the individual. In this article, we present a framework for understanding and modeling teams as dynamical systems and review our empirical findings on teams as dynamical systems. We proceed by (a) considering the question of why study teams as dynamical systems, (b) considering the meaning of dynamical systems concepts (attractors; perturbation; synchronization; fractals) in the context of teams, (c) describe empirical studies of team coordination dynamics at the perceptual-motor, cognitive-behavioral, and cognitive-neurophysiological levels of analysis, and (d) consider the theoretical and practical implications of this approach, including new kinds of explanations of human performance and real-time analysis and performance modeling. Throughout our discussion of the topics we consider how to describe teamwork using equations and/or modeling techniques that describe the dynamics. Finally, we consider what dynamical equations and models do and do not tell us about human performance in teams and suggest future research directions in this area. PMID:28744231
Holgado-Tello, Fco P; Chacón-Moscoso, Salvador; Sanduvete-Chaves, Susana; Pérez-Gil, José A
2016-01-01
The Campbellian tradition provides a conceptual framework to assess threats to validity. On the other hand, different models of causal analysis have been developed to control estimation biases in different research designs. However, the link between design features, measurement issues, and concrete impact estimation analyses is weak. In order to provide an empirical solution to this problem, we use Structural Equation Modeling (SEM) as a first approximation to operationalize the analytical implications of threats to validity in quasi-experimental designs. Based on the analogies established between the Classical Test Theory (CTT) and causal analysis, we describe an empirical study based on SEM in which range restriction and statistical power have been simulated in two different models: (1) A multistate model in the control condition (pre-test); and (2) A single-trait-multistate model in the control condition (post-test), adding a new mediator latent exogenous (independent) variable that represents a threat to validity. Results show, empirically, how the differences between both the models could be partially or totally attributed to these threats. Therefore, SEM provides a useful tool to analyze the influence of potential threats to validity.
Holgado-Tello, Fco. P.; Chacón-Moscoso, Salvador; Sanduvete-Chaves, Susana; Pérez-Gil, José A.
2016-01-01
The Campbellian tradition provides a conceptual framework to assess threats to validity. On the other hand, different models of causal analysis have been developed to control estimation biases in different research designs. However, the link between design features, measurement issues, and concrete impact estimation analyses is weak. In order to provide an empirical solution to this problem, we use Structural Equation Modeling (SEM) as a first approximation to operationalize the analytical implications of threats to validity in quasi-experimental designs. Based on the analogies established between the Classical Test Theory (CTT) and causal analysis, we describe an empirical study based on SEM in which range restriction and statistical power have been simulated in two different models: (1) A multistate model in the control condition (pre-test); and (2) A single-trait-multistate model in the control condition (post-test), adding a new mediator latent exogenous (independent) variable that represents a threat to validity. Results show, empirically, how the differences between both the models could be partially or totally attributed to these threats. Therefore, SEM provides a useful tool to analyze the influence of potential threats to validity. PMID:27378991
NASA Astrophysics Data System (ADS)
Nasruddin, Syaka, Darwin R. B.; Alhamid, M. Idrus
2012-06-01
Various binary mixtures of carbon dioxide and hydrocarbons, especially propane or ethane, as alternative natural refrigerants to Chlorofluorocarbons (CFCs) or Hydro fluorocarbons (HFCs) are presented in this paper. Their environmental performance is friendly, with an ozone depletion potential (ODP) of zero and Global-warming potential (GWP) smaller than 20. The capillary tube performance for the alternative refrigerant HFC HCand mixed refrigerants have been widely studied. However, studies that discuss the performance of the capillary tube to a mixture of natural refrigerants, in particular a mixture of azeotrope carbon dioxide and ethane is still undeveloped. A method of empirical correlation to determine the mass flow rate and pipe length has an important role in the design of the capillary tube for industrial refrigeration. Based on the variables that effect the rate of mass flow of refrigerant in the capillary tube, the Buckingham Pi theorem formulated eight non-dimensional parameters to be developed into an empirical equations correlation. Furthermore, non-linear regression analysis used to determine the co-efficiency and exponent of this empirical correlation based on experimental verification of the results database.
Equation-free modeling unravels the behavior of complex ecological systems
DeAngelis, Donald L.; Yurek, Simeon
2015-01-01
Ye et al. (1) address a critical problem confronting the management of natural ecosystems: How can we make forecasts of possible future changes in populations to help guide management actions? This problem is especially acute for marine and anadromous fisheries, where the large interannual fluctuations of populations, arising from complex nonlinear interactions among species and with varying environmental factors, have defied prediction over even short time scales. The empirical dynamic modeling (EDM) described in Ye et al.’s report, the latest in a series of papers by Sugihara and his colleagues, offers a promising quantitative approach to building models using time series to successfully project dynamics into the future. With the term “equation-free” in the article title, Ye et al. (1) are suggesting broader implications of their approach, considering the centrality of equations in modern science. From the 1700s on, nature has been increasingly described by mathematical equations, with differential or difference equations forming the basic framework for describing dynamics. The use of mathematical equations for ecological systems came much later, pioneered by Lotka and Volterra, who showed that population cycles might be described in terms of simple coupled nonlinear differential equations. It took decades for Lotka–Volterra-type models to become established, but the development of appropriate differential equations is now routine in modeling ecological dynamics. There is no question that the injection of mathematical equations, by forcing “clarity and precision into conjecture” (2), has led to increased understanding of population and community dynamics. As in science in general, in ecology equations are a key method of communication and of framing hypotheses. These equations serve as compact representations of an enormous amount of empirical data and can be analyzed by the powerful methods of mathematics.
NASA Astrophysics Data System (ADS)
Asgari, Jamal; Mohammadloo, Tannaz H.; Amiri-Simkooei, Ali Reza
2015-09-01
GNSS kinematic techniques are capable of providing precise coordinates in extremely short observation time-span. These methods usually determine the coordinates of an unknown station with respect to a reference one. To enhance the precision, accuracy, reliability and integrity of the estimated unknown parameters, GNSS kinematic equations are to be augmented by possible constraints. Such constraints could be derived from the geometric relation of the receiver positions in motion. This contribution presents the formulation of the constrained kinematic global navigation satellite systems positioning. Constraints effectively restrict the definition domain of the unknown parameters from the three-dimensional space to a subspace defined by the equation of motion. To test the concept of the constrained kinematic positioning method, the equation of a circle is employed as a constraint. A device capable of moving on a circle was made and the observations from 11 positions on the circle were analyzed. Relative positioning was conducted by considering the center of the circle as the reference station. The equation of the receiver's motion was rewritten in the ECEF coordinates system. A special attention is drawn onto how a constraint is applied to kinematic positioning. Implementing the constraint in the positioning process provides much more precise results compared to the unconstrained case. This has been verified based on the results obtained from the covariance matrix of the estimated parameters and the empirical results using kinematic positioning samples as well. The theoretical standard deviations of the horizontal components are reduced by a factor ranging from 1.24 to 2.64. The improvement on the empirical standard deviation of the horizontal components ranges from 1.08 to 2.2.
Olsen, S O
2001-04-01
A theoretical model of involvement in consumption of food products was tested in a representative survey of Norwegian households for the particular case of consuming seafood as a common family meal. The empirical study is based on using structural equation approach to test construct validity of measures and the empirical fit of the theoretical model. Attitudes, negative feelings, social norms and moral obligation were proved to be important, reliable and different constructs and explained 63% of the variation in seafood involvement. Negative feelings and moral obligation was the most important antecedents of involvement. Both our proposed model and modified model with seafood involvement as a mediator fit well with the data and proved our expectations in a promising way. Copyright 2001 Academic Press.
Dynamics of osmosis in a porous medium.
Cardoso, Silvana S S; Cartwright, Julyan H E
2014-11-01
We derive from kinetic theory, fluid mechanics and thermodynamics the minimal continuum-level equations governing the flow of a binary, non-electrolytic mixture in an isotropic porous medium with osmotic effects. For dilute mixtures, these equations are linear and in this limit provide a theoretical basis for the widely used semi-empirical relations of Kedem & Katchalsky (Kedem & Katchalsky 1958 Biochim. Biophys. Acta 27, 229-246 (doi:10.1016/0006-3002(58)90330-5), which have hitherto been validated experimentally but not theoretically. The above linearity between the fluxes and the driving forces breaks down for concentrated or non-ideal mixtures, for which our equations go beyond the Kedem-Katchalsky formulation. We show that the heretofore empirical solute permeability coefficient reflects the momentum transfer between the solute molecules that are rejected at a pore entrance and the solvent molecules entering the pore space; it can be related to the inefficiency of a Maxwellian demi-demon.
A model of rotationally-sampled wind turbulence for predicting fatigue loads in wind turbines
NASA Technical Reports Server (NTRS)
Spera, David A.
1995-01-01
Empirical equations are presented with which to model rotationally-sampled (R-S) turbulence for input to structural-dynamic computer codes and the calculation of wind turbine fatigue loads. These equations are derived from R-S turbulence data which were measured at the vertical-plane array in Clayton, New Mexico. For validation, the equations are applied to the calculation of cyclic flapwise blade loads for the NASA/DOE Mod-2 2.5-MW experimental HAWT's (horizontal-axis wind turbines), and the results compared to measured cyclic loads. Good correlation is achieved, indicating that the R-S turbulence model developed in this study contains the characteristics of the wind which produce many of the fatigue loads sustained by wind turbines. Empirical factors are included which permit the prediction of load levels at specified percentiles of occurrence, which is required for the generation of fatigue load spectra and the prediction of the fatigue lifetime of structures.
Heat-transfer processes in air-cooled engine cylinders
NASA Technical Reports Server (NTRS)
Pinkel, Benjamin
1938-01-01
From a consideration of heat-transfer theory, semi-empirical expressions are set up for the transfer of heat from the combustion gases to the cylinder of an air-cooled engine and from the cylinder to the cooling air. Simple equations for the average head and barrel temperatures as functions of the important engine and cooling variables are obtained from these expressions. The expressions involve a few empirical constants, which may be readily determined from engine tests. Numerical values for these constants were obtained from single-cylinder engine tests for cylinders of the Pratt & Whitney 1535 and 1340-h engines. The equations provide a means of calculating the effect of the various engine and cooling variables on the cylinder temperatures and also of correlating the results of engine cooling tests. An example is given of the application of the equations to the correlation of cooling-test data obtained in flight.
Equation of State for Detonation Product Gases
NASA Astrophysics Data System (ADS)
Nagayama, Kunihito; Kubota, Shiro
2013-06-01
Based on the empirical linear relationship between detonation velocity and loading density, an approximate description for the Chapman-Jouguet state for detonation product gases of solid phase high explosives has been developed. Provided that the Grüneisen parameter is a function only of volume, systematic and closed system of equations for the Grüneisen parameter and CJ volume have been formulated. These equations were obtained by combining this approximation with the Jones-Stanyukovich-Manson relation together with JWL isentrope for detonation of crystal density PETN. A thermodynamic identity between the Grüneisen parameter and another non-dimensional material parameter introduced by Wu and Jing can be used to derive the enthalpy-pressure-volume equation of state for detonation gases. This Wu-Jing parameter is found to be the ratio of the Grüneisen parameter and the adiabatic index. Behavior of this parameter as a function of pressure was calculated and revealed that their change with pressure is very gradual. By using this equation of state, several isentropes down from the Chapman-Jouguet states reached by four different lower initial density PETN have been calculated and compared with available cylinder expansion tests.
Stadler, Tanja; Degnan, James H.; Rosenberg, Noah A.
2016-01-01
Classic null models for speciation and extinction give rise to phylogenies that differ in distribution from empirical phylogenies. In particular, empirical phylogenies are less balanced and have branching times closer to the root compared to phylogenies predicted by common null models. This difference might be due to null models of the speciation and extinction process being too simplistic, or due to the empirical datasets not being representative of random phylogenies. A third possibility arises because phylogenetic reconstruction methods often infer gene trees rather than species trees, producing an incongruity between models that predict species tree patterns and empirical analyses that consider gene trees. We investigate the extent to which the difference between gene trees and species trees under a combined birth–death and multispecies coalescent model can explain the difference in empirical trees and birth–death species trees. We simulate gene trees embedded in simulated species trees and investigate their difference with respect to tree balance and branching times. We observe that the gene trees are less balanced and typically have branching times closer to the root than the species trees. Empirical trees from TreeBase are also less balanced than our simulated species trees, and model gene trees can explain an imbalance increase of up to 8% compared to species trees. However, we see a much larger imbalance increase in empirical trees, about 100%, meaning that additional features must also be causing imbalance in empirical trees. This simulation study highlights the necessity of revisiting the assumptions made in phylogenetic analyses, as these assumptions, such as equating the gene tree with the species tree, might lead to a biased conclusion. PMID:26968785
THE COSMIC RAY EQUATOR FROM DATA OF THE SECOND SOVIET EARTH SATELLITE
DOE Office of Scientific and Technical Information (OSTI.GOV)
Savenko, I.A.; Shavrin, P.I.; Nesterov, V.Ye.
1962-11-01
Determination of the geographical position of the line of minimum intensity of primary cosmic radiation (cosmic ray equator) makes is possible to study the structure of the geomagnetic field and to check theoretical and empirical approximations to this field. The minima of cosmic radiation intensity were determined by the second Soviet spaceship for 22 latitude curves obtained from various crossings in the region of the geographical equator. (W.D.M.)
ERIC Educational Resources Information Center
Livingston, Samuel A.; Kim, Sooyeon
2010-01-01
A series of resampling studies investigated the accuracy of equating by four different methods in a random groups equating design with samples of 400, 200, 100, and 50 test takers taking each form. Six pairs of forms were constructed. Each pair was constructed by assigning items from an existing test taken by 9,000 or more test takers. The…
NASA Technical Reports Server (NTRS)
Bergrun, N. R.
1951-01-01
An empirical method for the determination of the area, rate, and distribution of water-drop impingement on airfoils of arbitrary section is presented. The procedure represents an initial step toward the development of a method which is generally applicable in the design of thermal ice-prevention equipment for airplane wing and tail surfaces. Results given by the proposed empirical method are expected to be sufficiently accurate for the purpose of heated-wing design, and can be obtained from a few numerical computations once the velocity distribution over the airfoil has been determined. The empirical method presented for incompressible flow is based on results of extensive water-drop. trajectory computations for five airfoil cases which consisted of 15-percent-thick airfoils encompassing a moderate lift-coefficient range. The differential equations pertaining to the paths of the drops were solved by a differential analyzer. The method developed for incompressible flow is extended to the calculation of area and rate of impingement on straight wings in subsonic compressible flow to indicate the probable effects of compressibility for airfoils at low subsonic Mach numbers.
An Application of Structural Equation Modeling for Developing Good Teaching Characteristics Ontology
ERIC Educational Resources Information Center
Phiakoksong, Somjin; Niwattanakul, Suphakit; Angskun, Thara
2013-01-01
Ontology is a knowledge representation technique which aims to make knowledge explicit by defining the core concepts and their relationships. The Structural Equation Modeling (SEM) is a statistical technique which aims to explore the core factors from empirical data and estimates the relationship between these factors. This article presents an…
ERIC Educational Resources Information Center
Li, Spencer D.
2011-01-01
Mediation analysis in child and adolescent development research is possible using large secondary data sets. This article provides an overview of two statistical methods commonly used to test mediated effects in secondary analysis: multiple regression and structural equation modeling (SEM). Two empirical studies are presented to illustrate the…
Bootstrap Estimation of Sample Statistic Bias in Structural Equation Modeling.
ERIC Educational Resources Information Center
Thompson, Bruce; Fan, Xitao
This study empirically investigated bootstrap bias estimation in the area of structural equation modeling (SEM). Three correctly specified SEM models were used under four different sample size conditions. Monte Carlo experiments were carried out to generate the criteria against which bootstrap bias estimation should be judged. For SEM fit indices,…
Stress-intensity factor equations for cracks in three-dimensional finite bodies
NASA Technical Reports Server (NTRS)
Newman, J. C., Jr.; Raju, I. S.
1981-01-01
Empirical stress intensity factor equations are presented for embedded elliptical cracks, semi-elliptical surface cracks, quarter-elliptical corner cracks, semi-elliptical surface cracks at a hole, and quarter-elliptical corner cracks at a hole in finite plates. The plates were subjected to remote tensile loading. Equations give stress intensity factors as a function of parametric angle, crack depth, crack length, plate thickness, and where applicable, hole radius. The stress intensity factors used to develop the equations were obtained from three dimensional finite element analyses of these crack configurations.
Prediction of Scour below Flip Bucket using Soft Computing Techniques
NASA Astrophysics Data System (ADS)
Azamathulla, H. Md.; Ab Ghani, Aminuddin; Azazi Zakaria, Nor
2010-05-01
The accurate prediction of the depth of scour around hydraulic structure (trajectory spillways) has been based on the experimental studies and the equations developed are mainly empirical in nature. This paper evaluates the performance of the soft computing (intelligence) techiques, Adaptive Neuro-Fuzzy System (ANFIS) and Genetic expression Programming (GEP) approach, in prediction of scour below a flip bucket spillway. The results are very promising, which support the use of these intelligent techniques in prediction of highly non-linear scour parameters.
Cooling tower plume - model and experiment
NASA Astrophysics Data System (ADS)
Cizek, Jan; Gemperle, Jiri; Strob, Miroslav; Nozicka, Jiri
The paper discusses the description of the simple model of the, so-called, steam plume, which in many cases forms during the operation of the evaporative cooling systems of the power plants, or large technological units. The model is based on semi-empirical equations that describe the behaviour of a mixture of two gases in case of the free jet stream. In the conclusion of the paper, a simple experiment is presented through which the results of the designed model shall be validated in the subsequent period.
Risk Modelling of Agricultural Products
NASA Astrophysics Data System (ADS)
Nugrahani, E. H.
2017-03-01
In the real world market, agricultural commodity are imposed with fluctuating prices. This means that the price of agricultural products are relatively volatile, which means that agricultural business is a quite risky business for farmers. This paper presents some mathematical models to model such risks in the form of its volatility, based on certain assumptions. The proposed models are time varying volatility model, as well as time varying volatility with mean reversion and with seasonal mean equation models. Implementation on empirical data show that agricultural products are indeed risky.
Simón-Manso, Yamil
2005-03-10
Density functional theory has been applied to describe electronic substituent effects, especially in the pursuit of linear relationships similar to those observed from physical organic chemistry experiments. In particular, analogues for the Hammett equation parameters (sigma, rho) have been developed. Theoretical calculations were performed on several series of organic molecules in order to validate our model and for comparison with experimental results. The trends obtained by Hammett-like relations predicted by the model were found to be in qualitative agreement with the experimental data. The results obtained in this study suggest the applicability of similar correlation analysis based on theoretical methodologies that do not make use of empirical fits to experimental data can be useful in the study of substituent effects in organic chemistry.
Development of Semi-Empirical Damping Equation for Baffled Tank with Oblate Spheroidal Dome
NASA Technical Reports Server (NTRS)
Yang, H. Q.; West, Jeff; Brodnick, Jacob; Eberhart, Chad
2016-01-01
Propellant slosh is a potential source of disturbance that can significantly impact the stability of space vehicles. The slosh dynamics are typically represented by a mechanical model of a spring-mass-damper. This mechanical model is then included in the equation of motion of the entire vehicle for Guidance, Navigation and Control analysis. The typical parameters required by the mechanical model include natural frequency of the slosh, slosh mass, slosh mass center location, and the critical damping ratio. A fundamental study has been undertaken at NASA MSFC to understand the fluid damping physics from a ring baffle in the barrel section of a propellant tank. An asymptotic damping equation and CFD blended equation have been derived by NASA MSFC team to complement the popularly used Miles equation at different flow regimes. The new development has found success in providing a nonlinear damping model for the Space Launch System. The purpose of this study is to further extend the semi-empirical damping equations into the oblate spheroidal dome section of the propellant tanks. First, previous experimental data from the spherical baffled tank are collected and analyzed. Several methods of taking the dome curvature effect, including a generalized Miles equation, area projection method, and equalized fill height method, are assessed. CFD simulation is used to shed light on the interaction of vorticity around the baffle with the locally curved wall and liquid-gas interface. The final damping equation will be validated by a recent subscale test with an oblate spheroidal dome conducted at NASA MSFC.
Item Selection and Pre-equating with Empirical Item Characteristic Curves.
ERIC Educational Resources Information Center
Livingston, Samuel A.
An empirical item characteristic curve shows the probability of a correct response as a function of the student's total test score. These curves can be estimated from large-scale pretest data. They enable test developers to select items that discriminate well in the score region where decisions are made. A similar set of curves can be used to…
Regionalisation of low flow frequency curves for the Peninsular Malaysia
NASA Astrophysics Data System (ADS)
Mamun, Abdullah A.; Hashim, Alias; Daoud, Jamal I.
2010-02-01
SUMMARYRegional maps and equations for the magnitude and frequency of 1, 7 and 30-day low flows were derived and are presented in this paper. The river gauging stations of neighbouring catchments that produced similar low flow frequency curves were grouped together. As such, the Peninsular Malaysia was divided into seven low flow regions. Regional equations were developed using the multivariate regression technique. An empirical relationship was developed for mean annual minimum flow as a function of catchment area, mean annual rainfall and mean annual evaporation. The regional equations exhibited good coefficient of determination ( R2 > 0.90). Three low flow frequency curves showing the low, mean and high limits for each region were proposed based on a graphical best-fit technique. Knowing the catchment area, mean annual rainfall and evaporation in the region, design low flows of different durations can be easily estimated for the ungauged catchments. This procedure is expected to overcome the problem of data unavailability in estimating low flows in the Peninsular Malaysia.
Two-time scale subordination in physical processes with long-term memory
NASA Astrophysics Data System (ADS)
Stanislavsky, Aleksander; Weron, Karina
2008-03-01
We describe dynamical processes in continuous media with a long-term memory. Our consideration is based on a stochastic subordination idea and concerns two physical examples in detail. First we study a temporal evolution of the species concentration in a trapping reaction in which a diffusing reactant is surrounded by a sea of randomly moving traps. The analysis uses the random-variable formalism of anomalous diffusive processes. We find that the empirical trapping-reaction law, according to which the reactant concentration decreases in time as a product of an exponential and a stretched exponential function, can be explained by a two-time scale subordination of random processes. Another example is connected with a state equation for continuous media with memory. If the pressure and the density of a medium are subordinated in two different random processes, then the ordinary state equation becomes fractional with two-time scales. This allows one to arrive at the Bagley-Torvik type of state equation.
Effects of Drift-Shell Splitting by Chorus Waves on Radiation Belt Electrons
NASA Astrophysics Data System (ADS)
Chan, A. A.; Zheng, L.; O'Brien, T. P., III; Tu, W.; Cunningham, G.; Elkington, S. R.; Albert, J.
2015-12-01
Drift shell splitting in the radiation belts breaks all three adiabatic invariants of charged particle motion via pitch angle scattering, and produces new diffusion terms that fully populate the diffusion tensor in the Fokker-Planck equation. Based on the stochastic differential equation method, the Radbelt Electron Model (REM) simulation code allows us to solve such a fully three-dimensional Fokker-Planck equation, and to elucidate the sources and transport mechanisms behind the phase space density variations. REM has been used to perform simulations with an empirical initial phase space density followed by a seed electron injection, with a Tsyganenko 1989 magnetic field model, and with chorus wave and ULF wave diffusion models. Our simulation results show that adding drift shell splitting changes the phase space location of the source to smaller L shells, which typically reduces local electron energization (compared to neglecting drift-shell splitting effects). Simulation results with and without drift-shell splitting effects are compared with Van Allen Probe measurements.
Statistical methods for incomplete data: Some results on model misspecification.
McIsaac, Michael; Cook, R J
2017-02-01
Inverse probability weighted estimating equations and multiple imputation are two of the most studied frameworks for dealing with incomplete data in clinical and epidemiological research. We examine the limiting behaviour of estimators arising from inverse probability weighted estimating equations, augmented inverse probability weighted estimating equations and multiple imputation when the requisite auxiliary models are misspecified. We compute limiting values for settings involving binary responses and covariates and illustrate the effects of model misspecification using simulations based on data from a breast cancer clinical trial. We demonstrate that, even when both auxiliary models are misspecified, the asymptotic biases of double-robust augmented inverse probability weighted estimators are often smaller than the asymptotic biases of estimators arising from complete-case analyses, inverse probability weighting or multiple imputation. We further demonstrate that use of inverse probability weighting or multiple imputation with slightly misspecified auxiliary models can actually result in greater asymptotic bias than the use of naïve, complete case analyses. These asymptotic results are shown to be consistent with empirical results from simulation studies.
Kang, Xiaofeng; Dennison Himmelfarb, Cheryl R; Li, Zheng; Zhang, Jian; Lv, Rong; Guo, Jinyu
2015-01-01
The Self-care of Heart Failure Index (SCHFI) is an empirically tested instrument for measuring the self-care of patients with heart failure. The aim of this study was to develop a simplified Chinese version of the SCHFI and provide evidence for its construct validity. A total of 182 Chinese with heart failure were surveyed. A 2-step structural equation modeling procedure was applied to test construct validity. Factor analysis showed 3 factors explaining 43% of the variance. Structural equation model confirmed that self-care maintenance, self-care management, and self-care confidence are indeed indicators of self-care, and self-care confidence was a positive and equally strong predictor of self-care maintenance and self-care management. Moreover, self-care scores were correlated with the Partners in Health Scale, indicating satisfactory concurrent validity. The Chinese version of the SCHFI is a theory-based instrument for assessing self-care of Chinese patients with heart failure.
Asymptotic Standard Errors for Item Response Theory True Score Equating of Polytomous Items
ERIC Educational Resources Information Center
Cher Wong, Cheow
2015-01-01
Building on previous works by Lord and Ogasawara for dichotomous items, this article proposes an approach to derive the asymptotic standard errors of item response theory true score equating involving polytomous items, for equivalent and nonequivalent groups of examinees. This analytical approach could be used in place of empirical methods like…
Prediction of Battery Life and Behavior from Analysis of Voltage Data
NASA Technical Reports Server (NTRS)
Mcdermott, P. P.
1984-01-01
A method for simulating charge and discharge characteristics of secondary batteries is discussed. The analysis utilizes a nonlinear regression technique where empirical data is computer fitted with a five coefficient nonlinear equation. The equations for charge and discharge voltage are identical except for a change of sign before the second and third terms.
NASA Astrophysics Data System (ADS)
Ghnimi, Thouraya; Hassini, Lamine; Bagane, Mohamed
2016-12-01
The aim of this work is to determine the desorption isotherms and the drying kinetics of bay laurel leaves ( Laurus Nobilis L.). The desorption isotherms were performed at three temperature levels: 50, 60 and 70 °C and at water activity ranging from 0.057 to 0.88 using the statistic gravimetric method. Five sorption models were used to fit desorption experimental isotherm data. It was found that Kuhn model offers the best fitting of experimental moisture isotherms in the mentioned investigated ranges of temperature and water activity. The Net isosteric heat of water desorption was evaluated using The Clausius-Clapeyron equation and was then best correlated to equilibrium moisture content by the empirical Tsami's equation. Thin layer convective drying curves of bay laurel leaves were obtained for temperatures of 45, 50, 60 and 70 °C, relative humidity of 5, 15, 30 and 45 % and air velocities of 1, 1.5 and 2 m/s. A non linear regression procedure of Levenberg-Marquardt was used to fit drying curves with five semi empirical mathematical models available in the literature, The R2 and χ2 were used to evaluate the goodness of fit of models to data. Based on the experimental drying curves the drying characteristic curve (DCC) has been established and fitted with a third degree polynomial function. It was found that the Midilli Kucuk model was the best semi-empirical model describing thin layer drying kinetics of bay laurel leaves. The bay laurel leaves effective moisture diffusivity and activation energy were also identified.
Foundations for computer simulation of a low pressure oil flooded single screw air compressor
NASA Astrophysics Data System (ADS)
Bein, T. W.
1981-12-01
The necessary logic to construct a computer model to predict the performance of an oil flooded, single screw air compressor is developed. The geometric variables and relationships used to describe the general single screw mechanism are developed. The governing equations to describe the processes are developed from their primary relationships. The assumptions used in the development are also defined and justified. The computer model predicts the internal pressure, temperature, and flowrates through the leakage paths throughout the compression cycle of the single screw compressor. The model uses empirical external values as the basis for the internal predictions. The computer values are compared to the empirical values, and conclusions are drawn based on the results. Recommendations are made for future efforts to improve the computer model and to verify some of the conclusions that are drawn.
NASA Technical Reports Server (NTRS)
Bergrun, Norman R
1952-01-01
An empirically derived basis for predicting the area, rate, and distribution of water-drop impingement on airfoils of arbitrary section is presented. The concepts involved represent an initial step toward the development of a calculation technique which is generally applicable to the design of thermal ice-prevention equipment for airplane wing and tail surfaces. It is shown that sufficiently accurate estimates, for the purpose of heated-wing design, can be obtained by a few numerical computations once the velocity distribution over the airfoil has been determined. The calculation technique presented is based on results of extensive water-drop trajectory computations for five airfoil cases which consisted of 15-percent-thick airfoils encompassing a moderate lift-coefficient range. The differential equations pertaining to the paths of the drops were solved by a differential analyzer.
Comparison of in vitro and in situ methods in evaluation of forage digestibility in ruminants.
Krizsan, S J; Nyholm, L; Nousiainen, J; Südekum, K-H; Huhtanen, P
2012-09-01
The objective of this study was to compare the application of different in vitro and in situ methods in empirical and mechanistic predictions of in vivo OM digestibility (OMD) and their associations to near-infrared reflectance spectroscopy spectra for a variety of forages. Apparent in vivo OMD of silages made from alfalfa (n = 2), corn (n = 9), corn stover (n = 2), grass (n = 11), whole crops of wheat and barley (n = 8) and red clover (n = 7), and fresh alfalfa (n = 1), grass hays (n = 5), and wheat straws (n = 5) had previously been determined in sheep. Concentrations of indigestible NDF (iNDF) in all forage samples were determined by a 288-h ruminal in situ incubation. Gas production of isolated forage NDF was measured by in vitro incubations for 72 h. In vitro pepsin-cellulase OM solubility (OMS) of the forages was determined by a 2-step gravimetric digestion method. Samples were also subjected to a 2-step determination of in vitro OMD based on buffered rumen fluid and pepsin. Further, rumen fluid digestible OM was determined from a single 96-h incubation at 38°C. Digestibility of OM from the in situ and the in vitro incubations was calculated according to published empirical equations, which were either forage specific or general (1 equation for all forages) within method. Indigestible NDF was also used in a mechanistic model to predict OMD. Predictions of OMD were evaluated by residual analysis using the GLM procedure in SAS. In vitro OMS in a general prediction equation of OMD did not display a significant forage-type effect on the residuals (observed - predicted OMD; P = 0.10). Predictions of OMD within forage types were consistent between iNDF and the 2-step in vitro method based on rumen fluid. Root mean square error of OMD was least (0.032) when the prediction was based on a general forage equation of OMS. However, regenerating a simple regression for iNDF by omitting alfalfa and wheat straw reduced the root mean square error of OMD to 0.025. Indigestible NDF in a general forage equation predicted OMD without any bias (P ≥ 0.16), and root mean square error of prediction was smallest among all methods when alfalfa and wheat straw samples were excluded. Our study suggests that compared with the in vitro laboratory methods, iNDF used in forage-specific equations will improve overall predictions of forage in vivo OMD. The in vitro and in situ methods performed equally well in calibrations of iNDF or OMD by near-infrared reflectance spectroscopy.
Yuan, Ke-Hai; Tian, Yubin; Yanagihara, Hirokazu
2015-06-01
Survey data typically contain many variables. Structural equation modeling (SEM) is commonly used in analyzing such data. The most widely used statistic for evaluating the adequacy of a SEM model is T ML, a slight modification to the likelihood ratio statistic. Under normality assumption, T ML approximately follows a chi-square distribution when the number of observations (N) is large and the number of items or variables (p) is small. However, in practice, p can be rather large while N is always limited due to not having enough participants. Even with a relatively large N, empirical results show that T ML rejects the correct model too often when p is not too small. Various corrections to T ML have been proposed, but they are mostly heuristic. Following the principle of the Bartlett correction, this paper proposes an empirical approach to correct T ML so that the mean of the resulting statistic approximately equals the degrees of freedom of the nominal chi-square distribution. Results show that empirically corrected statistics follow the nominal chi-square distribution much more closely than previously proposed corrections to T ML, and they control type I errors reasonably well whenever N ≥ max(50,2p). The formulations of the empirically corrected statistics are further used to predict type I errors of T ML as reported in the literature, and they perform well.
Generalized Bootstrap Method for Assessment of Uncertainty in Semivariogram Inference
Olea, R.A.; Pardo-Iguzquiza, E.
2011-01-01
The semivariogram and its related function, the covariance, play a central role in classical geostatistics for modeling the average continuity of spatially correlated attributes. Whereas all methods are formulated in terms of the true semivariogram, in practice what can be used are estimated semivariograms and models based on samples. A generalized form of the bootstrap method to properly model spatially correlated data is used to advance knowledge about the reliability of empirical semivariograms and semivariogram models based on a single sample. Among several methods available to generate spatially correlated resamples, we selected a method based on the LU decomposition and used several examples to illustrate the approach. The first one is a synthetic, isotropic, exhaustive sample following a normal distribution, the second example is also a synthetic but following a non-Gaussian random field, and a third empirical sample consists of actual raingauge measurements. Results show wider confidence intervals than those found previously by others with inadequate application of the bootstrap. Also, even for the Gaussian example, distributions for estimated semivariogram values and model parameters are positively skewed. In this sense, bootstrap percentile confidence intervals, which are not centered around the empirical semivariogram and do not require distributional assumptions for its construction, provide an achieved coverage similar to the nominal coverage. The latter cannot be achieved by symmetrical confidence intervals based on the standard error, regardless if the standard error is estimated from a parametric equation or from bootstrap. ?? 2010 International Association for Mathematical Geosciences.
NASA Technical Reports Server (NTRS)
Stochl, R. J.
1974-01-01
An experimental investigation was conducted to determine the thermal effectiveness of an aluminized Mylar-silk net insulation system containing up to 160 layers. The experimentally measured heat flux was compared with results predicted by using (1) a previously developed semi-empirical equation and (2) an effective-thermal-conductivity value. All tests were conducted at a nominal hot-boundary temperature of 294 K (530 R) with liquid hydrogen as the heat sink. The experimental results show that the insulation performed as expected and that both the semi-empirical equation and effective thermal conductivity of a small number of layers were adequate in predicting the thermal performance of a large number of layers of insulation.
Numerical methods for assessing water quality in lakes and reservoirs
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mahamah, D.S.
1984-01-01
Water quality models are used as tools for predicting both short-term and long-term trends in water quality. They are generally classified into two groups based on the degree of empiricism. The two groups consists of the purely empirical types known as black-box models and the theoretical types called ecosystem models. This dissertation deals with both types of water quality models. The first part deals with empirical phosphorus models. The theory behind this class of models is discussed, leading to the development of an empirical phosphorus model using data from 79 western US lakes. A new approach to trophic state classificationmore » is introduced. The data used for the model was obtained from the Environmental Protection Agency National Eutrophication Study (EPA-NES) of western US lakes. The second portion of the dissertation discusses the development of an ecosystem model for culturally eutrophic Liberty Lake situated in eastern Washington State. The model is capable of simulating chlorophyll-a, phosphorus, and nitrogen levels in the lake on a weekly basis. For computing sediment release rates of phosphorus and nitrogen, equations based on laboratory bench-top studies using sediment samples from Liberty Lake are used. The model is used to simulate certain hypothetical nutrient control techniques such as phosphorus flushing, precipitation, and diversion.« less
Evaluation of theoretical and empirical water vapor sorption isotherm models for soils
NASA Astrophysics Data System (ADS)
Arthur, Emmanuel; Tuller, Markus; Moldrup, Per; de Jonge, Lis W.
2016-01-01
The mathematical characterization of water vapor sorption isotherms of soils is crucial for modeling processes such as volatilization of pesticides and diffusive and convective water vapor transport. Although numerous physically based and empirical models were previously proposed to describe sorption isotherms of building materials, food, and other industrial products, knowledge about the applicability of these functions for soils is noticeably lacking. We present an evaluation of nine models for characterizing adsorption/desorption isotherms for a water activity range from 0.03 to 0.93 based on measured data of 207 soils with widely varying textures, organic carbon contents, and clay mineralogy. In addition, the potential applicability of the models for prediction of sorption isotherms from known clay content was investigated. While in general, all investigated models described measured adsorption and desorption isotherms reasonably well, distinct differences were observed between physical and empirical models and due to the different degrees of freedom of the model equations. There were also considerable differences in model performance for adsorption and desorption data. While regression analysis relating model parameters and clay content and subsequent model application for prediction of measured isotherms showed promise for the majority of investigated soils, for soils with distinct kaolinitic and smectitic clay mineralogy predicted isotherms did not closely match the measurements.
Effect of casing yield stress on bomb blast impulse
NASA Astrophysics Data System (ADS)
Hutchinson, M. D.
2012-08-01
An equation to predict blast effects from cased charges was first proposed by U. Fano in 1944 and revised by E.M. Fisher in 1953 [1]. Fisher's revision provides much better matches to available blast impulse data, but still requires empirical parameter adjustments. A new derivation [2], based on the work of R.W. Gurney [3] and G.I. Taylor [4], has resulted in an equation which nearly matches experimental data. This new analytical model is also capable of being extended, through the incorporation of additional physics, such as the effects of early case fracture, finite casing thickness, casing metal strain energy dissipation, explosive gas escape through casing fractures and the comparative dynamics of blast wave and metal fragment impacts. This paper will focus on the choice of relevant case fracture strain criterion, as it will be shown that this allows the explicit inclusion of the dynamic properties of the explosive and casing metal. It will include a review and critique of the most significant earlier work on this topic, contained in a paper by Hoggatt and Recht [5]. Using this extended analytical model, good matches can readily be made to available free-field blast impulse data, without any empirical adjustments being needed. Further work will be required to apply this model to aluminised and other highly oxygen-deficient explosives.
Guo, Juanjuan; Zhang, Longtao; Lu, Xu; Zeng, Shaoxiao; Zhang, Yi; Xu, Hui; Zheng, Baodong
2016-11-05
Effective degradation of κ-carrageenan by isolated Thalassospira sp. fjfst-332 is reported for the first time in this paper. It was identified by 16S rDNA sequencing and morphological observation using Transmission Electron Microscopy (TEM). Based on a Plackett-Burman design for significant variables, Box-Behnken experimental design and response surface methodology were used to optimize the culture conditions. Through statistical optimization, the optimum medium components were determined as follows: 2.0 g/L κ-carrageenan, 1.0 g/L yeast extract, 1.0 g/L FOS, 20.0 g/L NaCl, 2.0 g/L NaNO₃, 0.5 g/L MgSO₄·7H₂O, 0.1 g/L K₂HPO₄, and 0.1 g/L CaCl₂. The highest activity exhibited by Thalassospira sp. fjfst-332 was 267 U/mL, which makes it the most vigorous wild bacterium for κ-carrageenan production. In order to guide scaled-up production, two empirical models-the logistic equation and Luedeking-Piretequation-were proposed to predict the strain growth and enzyme production, respectively. Furthermore, we report the fermentation kinetics and every empirical equation of the coefficients (α, β, X ₀, X m and μ m ) for the two models, which could be used to design and optimize industrial processes.
NASA Astrophysics Data System (ADS)
Amri, N.; Hashim, M. I.; Ismail, N.; Rohman, F. S.; Bashah, N. A. A.
2017-09-01
Electrocoagulation (EC) is a promising technology that extensively used to remove fluoride ions efficiently from industrial wastewater. However, it has received very little consideration and understanding on mechanism and factors that affecting the fluoride removal process. In order to determine the efficiency of fluoride removal in EC process, the effect of operating parameters such as voltage and electrolysis time were investigated in this study. A batch experiment with monopolar aluminium electrodes was conducted to identify the model of fluoride removal using empirical model equation. The EC process was investigated using several parameters which include voltage (3 - 12 V) and electrolysis time (0 - 60 minutes) at a constant initial fluoride concentration of 25 mg/L. The result shows that the fluoride removal efficiency increased steadily with increasing voltage and electrolysis time. The best fluoride removal efficiency was obtained with 94.8 % removal at 25 mg/L initial fluoride concentration, voltage of 12 V and 60 minutes electrolysis time. The results indicated that the rate constant, k and number of order, n decreased as the voltage increased. The rate of fluoride removal model was developed based on the empirical model equation using the correlation of k and n. Overall, the result showed that EC process can be considered as a potential alternative technology for fluoride removal in wastewater.
Recalibrated Equations for Determining Effect of Oil Filtration on Rolling Bearing Life
NASA Technical Reports Server (NTRS)
Needelman, William M.; Zaretsky, Erwin V.
2014-01-01
In 1991, Needelman and Zaretsky presented a set of empirically derived equations for bearing fatigue life (adjustment) factors (LFs) as a function of oil filter ratings. These equations for life factors were incorporated into the reference book, "STLE Life Factors for Rolling Bearings." These equations were normalized (LF = 1) to a 10-micrometer filter rating at Beta(sub x) = 200 (normal cleanliness) as it was then defined. Over the past 20 years, these life factors based on oil filtration have been used in conjunction with ANSI/ABMA standards and bearing computer codes to predict rolling bearing life. Also, additional experimental studies have been made by other investigators into the relationship between rolling bearing life and the size, number, and type of particle contamination. During this time period filter ratings have also been revised and improved, and they now use particle counting calibrated to a new National Institute of Standards and Technology (NIST) reference material, NIST SRM 2806, 1997. This paper reviews the relevant bearing life studies and describes the new filter ratings. New filter ratings, Beta(sub x(c)) = 200 and Beta(sub x(c)) = 1000, are benchmarked to old filter ratings, Beta(sub x) = 200, and vice versa. Two separate sets of filter LF values were derived based on the new filter ratings for roller bearings and ball bearings, respectively. Filter LFs can be calculated for the new filter ratings.
NASA Astrophysics Data System (ADS)
Kamai, Tamir; Nassar, Mohamed K.; Nelson, Kirk E.; Ginn, Timothy R.
2017-04-01
Colloid filtration in porous media spans across many disciplines and includes scenarios such as in-situ bioremediation, colloid-facilitated transport, water treatment of suspended particles and pathogenic bacteria, and transport of natural and engineered nanoparticles in the environment. Transport and deposition of colloid particles in porous media are determined by a combination of complex processes and forces. Given the convoluted physical, chemical, and biological processes involved, and the complexity of porous media in natural settings, it should not come as surprise that colloid filtration theory does not always sufficiently predict colloidal transport, and that there is still a pressing need for improved predictive capabilities. Here, instead of developing the macroscopic equation from pore-scale models, we parametrize the different terms in the macroscopic collection equation through fitting it to experimental data, by optimizing the parameters in the different terms of the equation. This way we combine a mechanistically-based filtration-equation with empirical evidence. The impact of different properties of colloids and porous media are studied by comparing experimental properties with different terms of the correlation equation. This comparison enables insight about different processes that occur during colloid transport and retention under in porous media under favorable conditions, and provides directions for future theoretical developments.
Predicting Thermal Conductivity
NASA Technical Reports Server (NTRS)
Penn, B.; Ledbetter, F. E., III; Clemons, J.
1984-01-01
Empirical equation predicts thermal conductivity of composite insulators consisting of cellular, granular or fibrous material embedded in matrix of solid viscoelastic material. Application in designing custom insulators for particular environments.
Mindfulness as a personal resource to reduce work stress in the job demands-resources model.
Grover, Steven L; Teo, Stephen T T; Pick, David; Roche, Maree
2017-10-01
Based on the job demands-resources (JD-R) model, this study examines the different ways that the personal resource of mindfulness reduces stress. Structural equation modeling based on data from 415 Australian nurses shows that mindfulness relates directly and negatively to work stress and perceptions of emotional demands as well as buffering the relation of emotional demands on psychological stress. This study contributes to the literature by employing empirical analysis to the task of unravelling how personal resources function within the JD-R model. It also introduces mindfulness as a personal resource in the JD-R model. Copyright © 2016 John Wiley & Sons, Ltd.
Potential relative increment (PRI): a new method to empirically derive optimal tree diameter growth
Don C Bragg
2001-01-01
Potential relative increment (PRI) is a new method to derive optimal diameter growth equations using inventory information from a large public database. Optimal growth equations for 24 species were developed using plot and tree records from several states (Michigan, Minnesota, and Wisconsin) of the North Central US. Most species were represented by thousands of...
Prediction of blast fragmentation of underground stopes for in situ leaching
DOE Office of Scientific and Technical Information (OSTI.GOV)
Stagg, M.S.; Otterness, R.E.; Djahanguiri, F.
1994-12-31
The US Bureau of Mines (USBM) evaluated empirical equations that predict fragmentation from underground stope rounds. Controlled blasting is necessary for creating leaching stopes that maximize the recovery and minimize backbreak of the perimeter wall. This paper presents the fragmentation results from one of the three drop-raise blasts used to develop a reduced-scale cylindrical stope, 1.8 m in diameter and 6 m in height. The stope is located in the Colorado School of Mines Experimental Mine (Edgar Mine) in Idaho Springs, Colorado. This stope is part of a USBM research effort to determine the feasibility of incorporating in situ leachingmore » of rubblized stopes into active underground metal and nonmetal mines. All the material from the first blast, 14 mtons was sieved. The resulting distribution was compared to the distribution predicted from empirical equations. The best fit was found with a USBM equation developed from over 50 sieved, reduced-scale (1- to 2-m) high wall blasts. Modifications to the equations were made to account for the observed differences due to breakout angle, shot geometry, initiation timing, decoupling, rock fracture toughness and explosive energy.« less
The Dynamic Characteristic and Hysteresis Effect of an Air Spring
NASA Astrophysics Data System (ADS)
Löcken, F.; Welsch, M.
2015-02-01
In many applications of vibration technology, especially in chassis, air springs present a common alternative to steel spring concepts. A design-independent and therefore universal approach is presented to describe the dynamic characteristic of such springs. Differential and constitutive equations based on energy balances of the enclosed volume and the mountings are given to describe the nonlinear and dynamic characteristics. Therefore all parameters can be estimated directly from physical and geometrical properties, without parameter fitting. The numerically solved equations fit very well to measurements of a passenger car air spring. In a second step a simplification of this model leads to a pure mechanical equation. While in principle the same parameters are used, just an empirical correction of the effective heat transfer coefficient is needed to handle some simplification on this topic. Finally, a linearization of this equation leads to an analogous mechanical model that can be assembled from two common spring- and one dashpot elements in a specific arrangement. This transfer into "mechanical language" enables a system description with a simple force-displacement law and a consideration of the nonobvious hysteresis and stiffness increase of an air spring from a mechanical point of view.
Mathematical modeling of PDC bit drilling process based on a single-cutter mechanics
DOE Office of Scientific and Technical Information (OSTI.GOV)
Wojtanowicz, A.K.; Kuru, E.
1993-12-01
An analytical development of a new mechanistic drilling model for polycrystalline diamond compact (PDC) bits is presented. The derivation accounts for static balance of forces acting on a single PDC cutter and is based on assumed similarity between bit and cutter. The model is fully explicit with physical meanings given to all constants and functions. Three equations constitute the mathematical model: torque, drilling rate, and bit life. The equations comprise cutter`s geometry, rock properties drilling parameters, and four empirical constants. The constants are used to match the model to a PDC drilling process. Also presented are qualitative and predictive verificationsmore » of the model. Qualitative verification shows that the model`s response to drilling process variables is similar to the behavior of full-size PDC bits. However, accuracy of the model`s predictions of PDC bit performance is limited primarily by imprecision of bit-dull evaluation. The verification study is based upon the reported laboratory drilling and field drilling tests as well as field data collected by the authors.« less
Hypervelocity impact on shielded plates
NASA Technical Reports Server (NTRS)
Smith, James P.
1993-01-01
A ballistic limit equation for hypervelocity impact on thin plates is derived analytically. This equation applies to cases of impulsive impact on a plate that is protected by a multi-shock shield, and it is valid in the range of velocity above 6 km/s. Experimental tests were conducted at the NASA Johnson Space Center on square aluminum plates. Comparing the center deflections of these plates with the theoretical deflections of a rigid-plastic plate subjected to a blast load, one determines the dynamic yield strength of the plate material. The analysis is based on a theory for the expansion of the fragmented projectile and on a simple failure criterion. Curves are presented for the critical projectile radius versus the projectile velocity, and for the critical plate thickness versus the velocity. These curves are in good agreement with curves that have been generated empirically.
NASA Astrophysics Data System (ADS)
Tchoufag, Joël; Fabre, David; Magnaudet, Jacques
2015-09-01
Gravity- or buoyancy-driven bodies moving in a slightly viscous fluid frequently follow fluttering or helical paths. Current models of such systems are largely empirical and fail to predict several of the key features of their evolution, especially close to the onset of path instability. Here, using a weakly nonlinear expansion of the full set of governing equations, we present a new generic reduced-order model based on a pair of amplitude equations with exact coefficients that drive the evolution of the first pair of unstable modes. We show that the predictions of this model for the style (e.g., fluttering or spiraling) and characteristics (e.g., frequency and maximum inclination angle) of path oscillations compare well with various recent data for both solid disks and air bubbles.
NASA Astrophysics Data System (ADS)
Magnaudet, Jacques; Tchoufag, Joel; Fabre, David
2015-11-01
Gravity/buoyancy-driven bodies moving in a slightly viscous fluid frequently follow fluttering or helical paths. Current models of such systems are largely empirical and fail to predict several of the key features of their evolution, especially close to the onset of path instability. Using a weakly nonlinear expansion of the full set of governing equations, we derive a new generic reduced-order model of this class of phenomena based on a pair of amplitude equations with exact coefficients that drive the evolution of the first pair of unstable modes. We show that the predictions of this model for the style (eg. fluttering or spiraling) and characteristics (eg. frequency and maximum inclination angle) of path oscillations compare well with various recent data for both solid disks and air bubbles.
A structural equation modeling analysis of students' understanding in basic mathematics
NASA Astrophysics Data System (ADS)
Oktavia, Rini; Arif, Salmawaty; Ferdhiana, Ridha; Yuni, Syarifah Meurah; Ihsan, Mahyus
2017-11-01
This research, in general, aims to identify incoming students' understanding and misconceptions of several basic concepts in mathematics. The participants of this study are the 2015 incoming students of Faculty of Mathematics and Natural Science of Syiah Kuala University, Indonesia. Using an instrument that were developed based on some anecdotal and empirical evidences on students' misconceptions, a survey involving 325 participants was administered and several quantitative and qualitative analysis of the survey data were conducted. In this article, we discuss the confirmatory factor analysis using Structural Equation Modeling (SEM) on factors that determine the new students' overall understanding of basic mathematics. The results showed that students' understanding on algebra, arithmetic, and geometry were significant predictors for their overall understanding of basic mathematics. This result supported that arithmetic and algebra are not the only predictors of students' understanding of basic mathematics.
NASA Astrophysics Data System (ADS)
McMillan, Mitchell; Hu, Zhiyong
2017-10-01
Streambank erosion is a major source of fluvial sediment, but few large-scale, spatially distributed models exist to quantify streambank erosion rates. We introduce a spatially distributed model for streambank erosion applicable to sinuous, single-thread channels. We argue that such a model can adequately characterize streambank erosion rates, measured at the outsides of bends over a 2-year time period, throughout a large region. The model is based on the widely-used excess-velocity equation and comprised three components: a physics-based hydrodynamic model, a large-scale 1-dimensional model of average monthly discharge, and an empirical bank erodibility parameterization. The hydrodynamic submodel requires inputs of channel centerline, slope, width, depth, friction factor, and a scour factor A; the large-scale watershed submodel utilizes watershed-averaged monthly outputs of the Noah-2.8 land surface model; bank erodibility is based on tree cover and bank height as proxies for root density. The model was calibrated with erosion rates measured in sand-bed streams throughout the northern Gulf of Mexico coastal plain. The calibrated model outperforms a purely empirical model, as well as a model based only on excess velocity, illustrating the utility of combining a physics-based hydrodynamic model with an empirical bank erodibility relationship. The model could be improved by incorporating spatial variability in channel roughness and the hydrodynamic scour factor, which are here assumed constant. A reach-scale application of the model is illustrated on ∼1 km of a medium-sized, mixed forest-pasture stream, where the model identifies streambank erosion hotspots on forested and non-forested bends.
Osmotically inactive sodium and potassium storage: lessons learned from the Edelman and Boling data.
Nguyen, Minhtri K; Nguyen, Dai-Scott; Nguyen, Minh-Kevin
2016-09-01
Because changes in the plasma water sodium concentration ([Na(+)]pw) are clinically due to changes in the mass balance of Na(+), K(+), and H2O, the analysis and treatment of the dysnatremias are dependent on the validity of the Edelman equation in defining the quantitative interrelationship between the [Na(+)]pw and the total exchangeable sodium (Nae), total exchangeable potassium (Ke), and total body water (TBW) (Edelman IS, Leibman J, O'Meara MP, Birkenfeld LW. J Clin Invest 37: 1236-1256, 1958): [Na(+)]pw = 1.11(Nae + Ke)/TBW - 25.6. The interrelationship between [Na(+)]pw and Nae, Ke, and TBW in the Edelman equation is empirically determined by accounting for measurement errors in all of these variables. In contrast, linear regression analysis of the same data set using [Na(+)]pw as the dependent variable yields the following equation: [Na(+)]pw = 0.93(Nae + Ke)/TBW + 1.37. Moreover, based on the study by Boling et al. (Boling EA, Lipkind JB. 18: 943-949, 1963), the [Na(+)]pw is related to the Nae, Ke, and TBW by the following linear regression equation: [Na(+)]pw = 0.487(Nae + Ke)/TBW + 71.54. The disparities between the slope and y-intercept of these three equations are unknown. In this mathematical analysis, we demonstrate that the disparities between the slope and y-intercept in these three equations can be explained by how the osmotically inactive Na(+) and K(+) storage pool is quantitatively accounted for. Our analysis also indicates that the osmotically inactive Na(+) and K(+) storage pool is dynamically regulated and that changes in the [Na(+)]pw can be predicted based on changes in the Nae, Ke, and TBW despite dynamic changes in the osmotically inactive Na(+) and K(+) storage pool. Copyright © 2016 the American Physiological Society.
Viscosity studies of water based magnetite nanofluids
DOE Office of Scientific and Technical Information (OSTI.GOV)
Anu, K.; Hemalatha, J.
2016-05-23
Magnetite nanofluids of various concentrations have been synthesized through co-precipitation method. The structural and topographical studies made with the X-Ray Diffractometer and Atomic Force Microscope are presented in this paper. The density and viscosity studies for the ferrofluids of various concentrations have been made at room temperature. The experimental viscosities are compared with theoretical values obtained from Einstein, Batchelor and Wang models. An attempt to modify the Rosensweig model is made and the modified Rosensweig equation is reported. In addition, new empirical correlation is also proposed for predicting viscosity of ferrofluid at various concentrations.
NASA Astrophysics Data System (ADS)
Dmitrenko, Artur V.
2017-11-01
The stochastic equations of continuum are used for determining the heat transfer coefficients. As a result, the formulas for Nusselt (Nu) number dependent on the turbulence intensity and scale instead of only on the Reynolds (Peclet) number are proposed for the classic flows of a nonisothermal fluid in a round smooth tube. It is shown that the new expressions for the classical heat transfer coefficient Nu, which depend only on the Reynolds number, should be obtained from these new general formulas if to use the well-known experimental data for the initial turbulence. It is found that the limitations of classical empirical and semiempirical formulas for heat transfer coefficients and their deviation from the experimental data depend on different parameters of initial fluctuations in the flow for different experiments in a wide range of Reynolds or Peclet numbers. Based on these new dependences, it is possible to explain that the differences between the experimental results for the fixed Reynolds or Peclet numbers are caused by the difference in values of flow fluctuations for each experiment instead of only due to the systematic error in the experiment processing. Accordingly, the obtained general dependences of Nu for a smooth round tube can serve as the basis for clarifying the experimental results and empirical formulas used for continuum flows in various power devices. Obtained results show that both for isothermal and for nonisothermal flows, the reason for the process of transition from a deterministic state into a turbulent one is determined by the physical law of equivalence of measures between them. Also the theory of stochastic equations and the law of equivalence of measures could determine mechanics which is basis in different phenomena of self-organization and chaos theory.
Predicting the reference evapotranspiration based on tensor decomposition
NASA Astrophysics Data System (ADS)
Misaghian, Negin; Shamshirband, Shahaboddin; Petković, Dalibor; Gocic, Milan; Mohammadi, Kasra
2017-11-01
Most of the available models for reference evapotranspiration (ET0) estimation are based upon only an empirical equation for ET0. Thus, one of the main issues in ET0 estimation is the appropriate integration of time information and different empirical ET0 equations to determine ET0 and boost the precision. The FAO-56 Penman-Monteith, adjusted Hargreaves, Blaney-Criddle, Priestley-Taylor, and Jensen-Haise equations were utilized in this study for estimating ET0 for two stations of Belgrade and Nis in Serbia using collected data for the period of 1980 to 2010. Three-order tensor is used to capture three-way correlations among months, years, and ET0 information. Afterward, the latent correlations among ET0 parameters were found by the multiway analysis to enhance the quality of the prediction. The suggested method is valuable as it takes into account simultaneous relations between elements, boosts the prediction precision, and determines latent associations. Models are compared with respect to coefficient of determination ( R 2), mean absolute error (MAE), and root-mean-square error (RMSE). The proposed tensor approach has a R 2 value of greater than 0.9 for all selected ET0 methods at both selected stations, which is acceptable for the ET0 prediction. RMSE is ranged between 0.247 and 0.485 mm day-1 at Nis station and between 0.277 and 0.451 mm day-1 at Belgrade station, while MAE is between 0.140 and 0.337 mm day-1 at Nis and between 0.208 and 0.360 mm day-1 at Belgrade station. The best performances are achieved by Priestley-Taylor model at Nis station ( R 2 = 0.985, MAE = 0.140 mm day-1, RMSE = 0.247 mm day-1) and FAO-56 Penman-Monteith model at Belgrade station (MAE = 0.208 mm day-1, RMSE = 0.277 mm day-1, R 2 = 0.975).
Combining Empirical and Stochastic Models for Extreme Floods Estimation
NASA Astrophysics Data System (ADS)
Zemzami, M.; Benaabidate, L.
2013-12-01
Hydrological models can be defined as physical, mathematical or empirical. The latter class uses mathematical equations independent of the physical processes involved in the hydrological system. The linear regression and Gradex (Gradient of Extreme values) are classic examples of empirical models. However, conventional empirical models are still used as a tool for hydrological analysis by probabilistic approaches. In many regions in the world, watersheds are not gauged. This is true even in developed countries where the gauging network has continued to decline as a result of the lack of human and financial resources. Indeed, the obvious lack of data in these watersheds makes it impossible to apply some basic empirical models for daily forecast. So we had to find a combination of rainfall-runoff models in which it would be possible to create our own data and use them to estimate the flow. The estimated design floods would be a good choice to illustrate the difficulties facing the hydrologist for the construction of a standard empirical model in basins where hydrological information is rare. The construction of the climate-hydrological model, which is based on frequency analysis, was established to estimate the design flood in the Anseghmir catchments, Morocco. The choice of using this complex model returns to its ability to be applied in watersheds where hydrological information is not sufficient. It was found that this method is a powerful tool for estimating the design flood of the watershed and also other hydrological elements (runoff, volumes of water...).The hydrographic characteristics and climatic parameters were used to estimate the runoff, water volumes and design flood for different return periods.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Boero, Riccardo; Edwards, Brian Keith
Economists use computable general equilibrium (CGE) models to assess how economies react and self-organize after changes in policies, technology, and other exogenous shocks. CGE models are equation-based, empirically calibrated, and inspired by Neoclassical economic theory. The focus of this work was to validate the National Infrastructure Simulation and Analysis Center (NISAC) CGE model and apply it to the problem of assessing the economic impacts of severe events. We used the 2012 Hurricane Sandy event as our validation case. In particular, this work first introduces the model and then describes the validation approach and the empirical data available for studying themore » event of focus. Shocks to the model are then formalized and applied. Finally, model results and limitations are presented and discussed, pointing out both the model degree of accuracy and the assessed total damage caused by Hurricane Sandy.« less
Which Are the Determinants of Online Students' Efficiency in Higher Education?
NASA Astrophysics Data System (ADS)
Castillo-Merino, David; Serradell-Lopez, Enric; González-González, Inés
International literature shows that the positive effect on students performance from the adoption of innovations in the technology of teaching and learning do not affect all teaching methods and learning styles equally, as it depends on university strategy and policy towards Information and Communication Technologies (ICT) adoption, students abilities, technology uses in the educational process by teachers and students, or the selection of a methodology that matches with digital uses. This paper provides empirical answers to these questions with data from online students at the Open University of Catalonia (UOC). An empirical model based on structural equations has been defined to explain complex relationships between variables. Our results show that motivation is the main variable affecting online students' performance. It appears as a latent variable influenced by students' perception of efficiency, a driver for indirect positive and significant effect on students' performance from students' ability in ICT uses.
NASA Technical Reports Server (NTRS)
Richey, Edward, III
1995-01-01
This research aims to develop the methods and understanding needed to incorporate time and loading variable dependent environmental effects on fatigue crack propagation (FCP) into computerized fatigue life prediction codes such as NASA FLAGRO (NASGRO). In particular, the effect of loading frequency on FCP rates in alpha + beta titanium alloys exposed to an aqueous chloride solution is investigated. The approach couples empirical modeling of environmental FCP with corrosion fatigue experiments. Three different computer models have been developed and incorporated in the DOS executable program. UVAFAS. A multiple power law model is available, and can fit a set of fatigue data to a multiple power law equation. A model has also been developed which implements the Wei and Landes linear superposition model, as well as an interpolative model which can be utilized to interpolate trends in fatigue behavior based on changes in loading characteristics (stress ratio, frequency, and hold times).
Multielement suppressor nozzles for thrust augmentation systems.
NASA Technical Reports Server (NTRS)
Lawrence, R. L.; O'Keefe, J. V.; Tate, R. B.
1972-01-01
The noise reduction and nozzle performance characteristics of large-scale, high-aspect-ratio multielement nozzle arrays operated at low velocities were determined by test. The nozzles are selected for application to high-aspect-ratio augmentor suppressors to be used for augmentor wing airplanes. Significant improvements in noise characteristics for multielement nozzles over those of round or high-aspect-ratio slot nozzles are obtained. Elliptical noise patterns typical of slot nozzles are presented for high-aspect-ratio multielement nozzle arrays. Additional advantages are available in OASPL noise reduction from the element size and spacing. Augmentor-suppressor systems can be designed for maximum beam pattern directivity and frequency spectrum shaping advantages. Measurements of the nozzle wakes show a correlation with noise level data and frequency spectrum peaks. The noise and jet wake results are compared with existing prediction procedures based on empirical jet flow equations, Lighthill relationships, Strouhal number, and empirical shock-induced screech noise effects.
Calibration of semi-stochastic procedure for simulating high-frequency ground motions
Seyhan, Emel; Stewart, Jonathan P.; Graves, Robert
2013-01-01
Broadband ground motion simulation procedures typically utilize physics-based modeling at low frequencies, coupled with semi-stochastic procedures at high frequencies. The high-frequency procedure considered here combines deterministic Fourier amplitude spectra (dependent on source, path, and site models) with random phase. Previous work showed that high-frequency intensity measures from this simulation methodology attenuate faster with distance and have lower intra-event dispersion than in empirical equations. We address these issues by increasing crustal damping (Q) to reduce distance attenuation bias and by introducing random site-to-site variations to Fourier amplitudes using a lognormal standard deviation ranging from 0.45 for Mw < 7 to zero for Mw 8. Ground motions simulated with the updated parameterization exhibit significantly reduced distance attenuation bias and revised dispersion terms are more compatible with those from empirical models but remain lower at large distances (e.g., > 100 km).
NASA Technical Reports Server (NTRS)
Smith, Joseph G., Jr.; Connell, John W.; Watson, Kent A.; Danehy, Paul M.
2005-01-01
The incorporation of single-walled carbon nanotubes (SWNTs) into the bulk of space environmentally durable polymers at loading levels greater than or equal to 0.05 wt % has afforded thin films with surface and volume resistivities sufficient for electrostatic charge mitigation. However, the optical transparency at 500 nm decreased and the thermo-optical properties (solar absorptivity and thermal emissivity) increased with increaed SWNT loading. These properties were also dependent on film thickness. The absorbance characteristics of the films as a function of SWNT loading and film thickness were measured and determined to follow the classical Beer-Lambert law. Based on these results, an empirical relationship was derived and molar absorptivities determined for both the SWNTs and polymer matrix to provide a predictive approximation of these properties. The molar absorptivity determined for SWNTs dispersed in the polymer was comparable to reported solution determined values for HiPco SWNTs.
[Mobbing: a meta-analysis and integrative model of its antecedents and consequences].
Topa Cantisano, Gabriela; Depolo, Marco; Morales Domínguez, J Francisco
2007-02-01
Although mobbing has been extensively studied, empirical research has not led to firm conclusions regarding its antecedents and consequences, both at personal and organizational levels. An extensive literature search yielded 86 empirical studies with 93 samples. The matrix correlation obtained through meta-analytic techniques was used to test a structural equation model. Results supported hypotheses regarding organizational environmental factors as main predictors of mobbing.
How to Quantify Deterministic and Random Influences on the Statistics of the Foreign Exchange Market
NASA Astrophysics Data System (ADS)
Friedrich, R.; Peinke, J.; Renner, Ch.
2000-05-01
It is shown that price changes of the U.S. dollar-German mark exchange rates upon different delay times can be regarded as a stochastic Marcovian process. Furthermore, we show how Kramers-Moyal coefficients can be estimated from the empirical data. Finally, we present an explicit Fokker-Planck equation which models very precisely the empirical probability distributions, in particular, their non-Gaussian heavy tails.
Hong, Sehee; Kim, Soyoung
2018-01-01
There are basically two modeling approaches applicable to analyzing an actor-partner interdependence model: the multilevel modeling (hierarchical linear model) and the structural equation modeling. This article explains how to use these two models in analyzing an actor-partner interdependence model and how these two approaches work differently. As an empirical example, marital conflict data were used to analyze an actor-partner interdependence model. The multilevel modeling and the structural equation modeling produced virtually identical estimates for a basic model. However, the structural equation modeling approach allowed more realistic assumptions on measurement errors and factor loadings, rendering better model fit indices.
Diffusion equations and the time evolution of foreign exchange rates
NASA Astrophysics Data System (ADS)
Figueiredo, Annibal; de Castro, Marcio T.; da Fonseca, Regina C. B.; Gleria, Iram
2013-10-01
We investigate which type of diffusion equation is most appropriate to describe the time evolution of foreign exchange rates. We modify the geometric diffusion model assuming a non-exponential time evolution and the stochastic term is the sum of a Wiener noise and a jump process. We find the resulting diffusion equation to obey the Kramers-Moyal equation. Analytical solutions are obtained using the characteristic function formalism and compared with empirical data. The analysis focus on the first four central moments considering the returns of foreign exchange rate. It is shown that the proposed model offers a good improvement over the classical geometric diffusion model.
NASA Technical Reports Server (NTRS)
Kay, P. K.
1984-01-01
The influence of friction is included in the present equations describing the performance of an inductively driven rail gun. These equations, which have their basis in an empirical formulation, are applied to results from two different experiments. Only an approximate physical description of the problem is attempted, in view of the complexity of details in the interaction among forces of this magnitude over time periods of the order of milisecs.
NASA Technical Reports Server (NTRS)
Lebedeff, S. A.; Hameed, S.
1975-01-01
The problem investigated can be solved exactly in a simple manner if the equations are written in terms of a similarity variable. The exact solution is used to explore two questions of interest in the modelling of urban air pollution, taking into account the distribution of surface concentration downwind of an area source and the distribution of concentration with height.
Empirical solution of Green-Ampt equation using soil conservation service - curve number values
NASA Astrophysics Data System (ADS)
Grimaldi, S.; Petroselli, A.; Romano, N.
2012-09-01
The Soil Conservation Service - Curve Number (SCS-CN) method is a popular widely used rainfall-runoff model for quantifying the total stream-flow volume generated by storm rainfall, but its application is not appropriate for sub-daily resolutions. In order to overcome this drawback, the Green-Ampt (GA) infiltration equation is considered and an empirical solution is proposed and evaluated. The procedure, named CN4GA (Curve Number for Green-Ampt), aims to calibrate the Green-Ampt model parameters distributing in time the global information provided by the SCS-CN method. The proposed procedure is evaluated by analysing observed rainfall-runoff events; results show that CN4GA seems to provide better agreement with the observed hydrographs respect to the classic SCS-CN method.
NASA Astrophysics Data System (ADS)
Lagomarsino, Daniela; Martelloni, Gianluca; Segoni, Samuele; Catani, Filippo; Fanti, Riccardo
2013-04-01
In this work we propose a snow accumulation-melting model (SAMM) to forecast the snowpack height and we compare the results with a simple temperature index model and an improved version of the latter.For this purpose we used rainfall, temperature and snowpack thickness 5-years data series from 7 weather stations in the Northern Apennines (Emilia Romagna Region, Italy). SAMM is based on two modules modelling the snow accumulation and the snowmelt processes. Each module is composed by two equations: a mass conservation equation is solved to model snowpack thickness and an empirical equation is used for the snow density. The processes linked to the accumulation/depletion of the snowpack (e.g. compression of the snowpack due to newly fallen snow and effects of rainfall) are modelled identifying limiting and inhibitory factors according to a kinetic approach. The model depends on 13 empirical parameters, whose optimal values were defined with an optimization algorithm (simplex flexible) using calibration measures of snowpack thickness. From an operational point of view, SAMM uses as input data only temperature and rainfall measurements, bringing the additional advantage of a relatively easy implementation. In order to verify the improvement of SAMM with respect to a temperature-index model, the latter was applied considering, for the amount of snow melt, the following equation: M = fm(T-T0), where M is hourly melt, fm is the melting factor and T0 is a threshold temperature. In this case the calculation of the depth of the snowpack requires the use of 3 parameters: fm, T0 and ?0 (the mean density of the snowpack). We also performed a simulation by replacing the SAMM melting module with the above equation and leaving unchanged the accumulation module: in this way we obtained a model with 9 parameters. The simulations results suggest that any further extension of the simple temperature index model brings some improvements with a consequent decrease of the mean error between model and experimental data of the snowpack thickness.
Data-Driven H∞ Control for Nonlinear Distributed Parameter Systems.
Luo, Biao; Huang, Tingwen; Wu, Huai-Ning; Yang, Xiong
2015-11-01
The data-driven H∞ control problem of nonlinear distributed parameter systems is considered in this paper. An off-policy learning method is developed to learn the H∞ control policy from real system data rather than the mathematical model. First, Karhunen-Loève decomposition is used to compute the empirical eigenfunctions, which are then employed to derive a reduced-order model (ROM) of slow subsystem based on the singular perturbation theory. The H∞ control problem is reformulated based on the ROM, which can be transformed to solve the Hamilton-Jacobi-Isaacs (HJI) equation, theoretically. To learn the solution of the HJI equation from real system data, a data-driven off-policy learning approach is proposed based on the simultaneous policy update algorithm and its convergence is proved. For implementation purpose, a neural network (NN)- based action-critic structure is developed, where a critic NN and two action NNs are employed to approximate the value function, control, and disturbance policies, respectively. Subsequently, a least-square NN weight-tuning rule is derived with the method of weighted residuals. Finally, the developed data-driven off-policy learning approach is applied to a nonlinear diffusion-reaction process, and the obtained results demonstrate its effectiveness.
Hauschild, L; Lovatto, P A; Pomar, J; Pomar, C
2012-07-01
The objective of this study was to develop and evaluate a mathematical model used to estimate the daily amino acid requirements of individual growing-finishing pigs. The model includes empirical and mechanistic model components. The empirical component estimates daily feed intake (DFI), BW, and daily gain (DG) based on individual pig information collected in real time. Based on DFI, BW, and DG estimates, the mechanistic component uses classic factorial equations to estimate the optimal concentration of amino acids that must be offered to each pig to meet its requirements. The model was evaluated with data from a study that investigated the effect of feeding pigs with a 3-phase or daily multiphase system. The DFI and BW values measured in this study were compared with those estimated by the empirical component of the model. The coherence of the values estimated by the mechanistic component was evaluated by analyzing if it followed a normal pattern of requirements. Lastly, the proposed model was evaluated by comparing its estimates with those generated by the existing growth model (InraPorc). The precision of the proposed model and InraPorc in estimating DFI and BW was evaluated through the mean absolute error. The empirical component results indicated that the DFI and BW trajectories of individual pigs fed ad libitum could be predicted 1 d (DFI) or 7 d (BW) ahead with the average mean absolute error of 12.45 and 1.85%, respectively. The average mean absolute error obtained with the InraPorc for the average individual of the population was 14.72% for DFI and 5.38% for BW. Major differences were observed when estimates from InraPorc were compared with individual observations. The proposed model, however, was effective in tracking the change in DFI and BW for each individual pig. The mechanistic model component estimated the optimal standardized ileal digestible Lys to NE ratio with reasonable between animal (average CV = 7%) and overtime (average CV = 14%) variation. Thus, the amino acid requirements estimated by model are animal- and time-dependent and follow, in real time, the individual DFI and BW growth patterns. The proposed model can follow the average feed intake and feed weight trajectory of each individual pig in real time with good accuracy. Based on these trajectories and using classical factorial equations, the model makes it possible to estimate dynamically the AA requirements of each animal, taking into account the intake and growth changes of the animal.
Stochastic model of financial markets reproducing scaling and memory in volatility return intervals
NASA Astrophysics Data System (ADS)
Gontis, V.; Havlin, S.; Kononovicius, A.; Podobnik, B.; Stanley, H. E.
2016-11-01
We investigate the volatility return intervals in the NYSE and FOREX markets. We explain previous empirical findings using a model based on the interacting agent hypothesis instead of the widely-used efficient market hypothesis. We derive macroscopic equations based on the microscopic herding interactions of agents and find that they are able to reproduce various stylized facts of different markets and different assets with the same set of model parameters. We show that the power-law properties and the scaling of return intervals and other financial variables have a similar origin and could be a result of a general class of non-linear stochastic differential equations derived from a master equation of an agent system that is coupled by herding interactions. Specifically, we find that this approach enables us to recover the volatility return interval statistics as well as volatility probability and spectral densities for the NYSE and FOREX markets, for different assets, and for different time-scales. We find also that the historical S&P500 monthly series exhibits the same volatility return interval properties recovered by our proposed model. Our statistical results suggest that human herding is so strong that it persists even when other evolving fluctuations perturbate the financial system.
Validity test and its consistency in the construction of patient loyalty model
NASA Astrophysics Data System (ADS)
Yanuar, Ferra
2016-04-01
The main objective of this present study is to demonstrate the estimation of validity values and its consistency based on structural equation model. The method of estimation was then implemented to an empirical data in case of the construction the patient loyalty model. In the hypothesis model, service quality, patient satisfaction and patient loyalty were determined simultaneously, each factor were measured by any indicator variables. The respondents involved in this study were the patients who ever got healthcare at Puskesmas in Padang, West Sumatera. All 394 respondents who had complete information were included in the analysis. This study found that each construct; service quality, patient satisfaction and patient loyalty were valid. It means that all hypothesized indicator variables were significant to measure their corresponding latent variable. Service quality is the most measured by tangible, patient satisfaction is the most mesured by satisfied on service and patient loyalty is the most measured by good service quality. Meanwhile in structural equation, this study found that patient loyalty was affected by patient satisfaction positively and directly. Service quality affected patient loyalty indirectly with patient satisfaction as mediator variable between both latent variables. Both structural equations were also valid. This study also proved that validity values which obtained here were also consistence based on simulation study using bootstrap approach.
Dynamic and Thermal Turbulent Time Scale Modelling for Homogeneous Shear Flows
NASA Technical Reports Server (NTRS)
Schwab, John R.; Lakshminarayana, Budugur
1994-01-01
A new turbulence model, based upon dynamic and thermal turbulent time scale transport equations, is developed and applied to homogeneous shear flows with constant velocity and temperature gradients. The new model comprises transport equations for k, the turbulent kinetic energy; tau, the dynamic time scale; k(sub theta), the fluctuating temperature variance; and tau(sub theta), the thermal time scale. It offers conceptually parallel modeling of the dynamic and thermal turbulence at the two equation level, and eliminates the customary prescription of an empirical turbulent Prandtl number, Pr(sub t), thus permitting a more generalized prediction capability for turbulent heat transfer in complex flows and geometries. The new model also incorporates constitutive relations, based upon invariant theory, that allow the effects of nonequilibrium to modify the primary coefficients for the turbulent shear stress and heat flux. Predictions of the new model, along with those from two other similar models, are compared with experimental data for decaying homogeneous dynamic and thermal turbulence, homogeneous turbulence with constant temperature gradient, and homogeneous turbulence with constant temperature gradient and constant velocity gradient. The new model offers improvement in agreement with the data for most cases considered in this work, although it was no better than the other models for several cases where all the models performed poorly.
Topa Cantisano, Gabriela; Morales Domínguez, J F; Depolo, Marco
2008-05-01
Although sexual harassment has been extensively studied, empirical research has not led to firm conclusions about its antecedents and consequences, both at the personal and organizational level. An extensive literature search yielded 42 empirical studies with 60 samples. The matrix correlation obtained through meta-analytic techniques was used to test a structural equation model. Results supported the hypotheses regarding organizational environmental factors as main predictors of harassment.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lipnikov, Konstantin; Moulton, David; Svyatskiy, Daniil
2016-04-29
We develop a new approach for solving the nonlinear Richards’ equation arising in variably saturated flow modeling. The growing complexity of geometric models for simulation of subsurface flows leads to the necessity of using unstructured meshes and advanced discretization methods. Typically, a numerical solution is obtained by first discretizing PDEs and then solving the resulting system of nonlinear discrete equations with a Newton-Raphson-type method. Efficiency and robustness of the existing solvers rely on many factors, including an empiric quality control of intermediate iterates, complexity of the employed discretization method and a customized preconditioner. We propose and analyze a new preconditioningmore » strategy that is based on a stable discretization of the continuum Jacobian. We will show with numerical experiments for challenging problems in subsurface hydrology that this new preconditioner improves convergence of the existing Jacobian-free solvers 3-20 times. Furthermore, we show that the Picard method with this preconditioner becomes a more efficient nonlinear solver than a few widely used Jacobian-free solvers.« less
The influence of pressure relaxation on the structure of an axial vortex
NASA Astrophysics Data System (ADS)
Ash, Robert L.; Zardadkhan, Irfan; Zuckerwar, Allan J.
2011-07-01
Governing equations including the effects of pressure relaxation have been utilized to study an incompressible, steady-state viscous axial vortex with specified far-field circulation. When sound generation is attributed to a velocity gradient tensor-pressure gradient product, the modified conservation of momentum equations that result yield an exact solution for a steady, incompressible axial vortex. The vortex velocity profile has been shown to closely approximate experimental vortex measurements in air and water over a wide range of circulation-based Reynolds numbers. The influence of temperature and humidity on the pressure relaxation coefficient in air has been examined using theoretical and empirical approaches, and published axial vortex experiments have been employed to estimate the pressure relaxation coefficient in water. Non-equilibrium pressure gradient forces have been shown to balance the viscous stresses in the vortex core region, and the predicted pressure deficits that result from this non-equilibrium balance can be substantially larger than the pressure deficits predicted using a Bernoulli equation approach. Previously reported pressure deficit distributions for dust devils and tornados have been employed to validate the non-equilibrium pressure deficit predictions.
Measuring the effects of heat wave episodes on the human body's thermal balance
NASA Astrophysics Data System (ADS)
Katavoutas, George; Theoharatos, George; Flocas, Helena A.; Asimakopoulos, Dimosthenis N.
2009-03-01
During the peak of an extensive heat wave episode on 23-25 July 2007, simultaneous thermophysiological measurements were made in two non-acclimated healthy adults of different sex in a suburban area of Greater Athens, Greece. Based on experimental measurements of mean skin temperature and metabolic heat production, heat fluxes to and from the human body were calculated, and the biometeorological index heat load (HL) produced was determined according to the heat balance equation. Comparing experimental values with those derived from theoretical estimates revealed a great heat stress for both individuals, especially the male, while theoretical values underestimated heat stress. The study also revealed that thermophysiological factors, such as mean skin temperature and metabolic heat production, play an important role in determining heat fluxes patterns in the heat balance equation. The theoretical values of mean skin temperature as derived from an empirical equation may not be appropriate to describe the changes that take place in a non-acclimated individual. Furthermore, the changes in metabolic heat production were significant even for standard activity.
Creasy, Arch; Reck, Jason; Pabst, Timothy; Hunter, Alan; Barker, Gregory; Carta, Giorgio
2018-05-29
A previously developed empirical interpolation (EI) method is extended to predict highly overloaded multicomponent elution behavior on a cation exchange (CEX) column based on batch isotherm data. Instead of a fully mechanistic model, the EI method employs an empirically modified multicomponent Langmuir equation to correlate two-component adsorption isotherm data at different salt concentrations. Piecewise cubic interpolating polynomials are then used to predict competitive binding at intermediate salt concentrations. The approach is tested for the separation of monoclonal antibody monomer and dimer mixtures by gradient elution on the cation exchange resin Nuvia HR-S. Adsorption isotherms are obtained over a range of salt concentrations with varying monomer and dimer concentrations. Coupled with a lumped kinetic model, the interpolated isotherms predict the column behavior for highly overloaded conditions. Predictions based on the EI method showed good agreement with experimental elution curves for protein loads up to 40 mg/mL column or about 50% of the column binding capacity. The approach can be extended to other chromatographic modalities and to more than two components. This article is protected by copyright. All rights reserved.
Development of Quantum Chemical Method to Calculate Half Maximal Inhibitory Concentration (IC50 ).
Bag, Arijit; Ghorai, Pradip Kr
2016-05-01
Till date theoretical calculation of the half maximal inhibitory concentration (IC50 ) of a compound is based on different Quantitative Structure Activity Relationship (QSAR) models which are empirical methods. By using the Cheng-Prusoff equation it may be possible to compute IC50 , but this will be computationally very expensive as it requires explicit calculation of binding free energy of an inhibitor with respective protein or enzyme. In this article, for the first time we report an ab initio method to compute IC50 of a compound based only on the inhibitor itself where the effect of the protein is reflected through a proportionality constant. By using basic enzyme inhibition kinetics and thermodynamic relations, we derive an expression of IC50 in terms of hydrophobicity, electric dipole moment (μ) and reactivity descriptor (ω) of an inhibitor. We implement this theory to compute IC50 of 15 HIV-1 capsid inhibitors and compared them with experimental results and available other QASR based empirical results. Calculated values using our method are in very good agreement with the experimental values compared to the values calculated using other methods. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
He, Jingjing; Zhou, Yibin; Guan, Xuefei; Zhang, Wei; Zhang, Weifang; Liu, Yongming
2016-08-16
Structural health monitoring has been studied by a number of researchers as well as various industries to keep up with the increasing demand for preventive maintenance routines. This work presents a novel method for reconstruct prompt, informed strain/stress responses at the hot spots of the structures based on strain measurements at remote locations. The structural responses measured from usage monitoring system at available locations are decomposed into modal responses using empirical mode decomposition. Transformation equations based on finite element modeling are derived to extrapolate the modal responses from the measured locations to critical locations where direct sensor measurements are not available. Then, two numerical examples (a two-span beam and a 19956-degree of freedom simplified airfoil) are used to demonstrate the overall reconstruction method. Finally, the present work investigates the effectiveness and accuracy of the method through a set of experiments conducted on an aluminium alloy cantilever beam commonly used in air vehicle and spacecraft. The experiments collect the vibration strain signals of the beam via optical fiber sensors. Reconstruction results are compared with theoretical solutions and a detailed error analysis is also provided.
Inferring genetic connectivity in real populations, exemplified by coastal and oceanic Atlantic cod.
Spies, Ingrid; Hauser, Lorenz; Jorde, Per Erik; Knutsen, Halvor; Punt, André E; Rogers, Lauren A; Stenseth, Nils Chr
2018-05-08
Genetic data are commonly used to estimate connectivity between putative populations, but translating them to demographic dispersal rates is complicated. Theoretical equations that infer a migration rate based on the genetic estimator F ST , such as Wright's equation, F ST ≈ 1/(4 N e m + 1), make assumptions that do not apply to most real populations. How complexities inherent to real populations affect migration was exemplified by Atlantic cod in the North Sea and Skagerrak and was examined within an age-structured model that incorporated genetic markers. Migration was determined under various scenarios by varying the number of simulated migrants until the mean simulated level of genetic differentiation matched a fixed level of genetic differentiation equal to empirical estimates. Parameters that decreased the N e / N t ratio (where N e is the effective and N t is the total population size), such as high fishing mortality and high fishing gear selectivity, increased the number of migrants required to achieve empirical levels of genetic differentiation. Higher maturity-at-age and lower selectivity increased N e / N t and decreased migration when genetic differentiation was fixed. Changes in natural mortality, fishing gear selectivity, and maturity-at-age within expected limits had a moderate effect on migration when genetic differentiation was held constant. Changes in population size had the greatest effect on the number of migrants to achieve fixed levels of F ST , particularly when genetic differentiation was low, F ST ≈ 10 -3 Highly variable migration patterns, compared with constant migration, resulted in higher variance in genetic differentiation and higher extreme values. Results are compared with and provide insight into the use of theoretical equations to estimate migration among real populations. Copyright © 2018 the Author(s). Published by PNAS.
Wesolowski, E.A.; Nelson, R.A.
1987-01-01
As part of the Sour is River water-quality assessment, traveltime, longitudinal-dispersion, and reaeration measurements were made during September 1983 on segments of the 186-mile reach of the Sour is River from Lake Darling Dam to the J. Clark Salyer National Wildlife Refuge. The primary objective was to determine traveltime, longitudinal-dispersion, and reaeration coefficients during low flow. Streamflow in the reach ranged from 10.5 to 47.0 cubic feet per second during the measurement period.On the basis of channel and hydraulic characteristics, the 186-mile reach was subdivided into five subreaches that ranged from 18 to 55 river miles in length. Within each subreach, representative test reaches that ranged from 5.0 to 9.1 river miles in length were selected for tracer injection and sample collection. Standard fluorometric techniques were used to measure traveltime and longitudinal dispersion, and a modified tracer technique that used ethylene and propane gas was used to measure reaeration. Mean test-reach velocities ranged from 0.05 to 0.30 foot per second, longitudinal-dispersion coefficients ranged from 4.2 to 61 square feet per second, and reaeration coefficients based on propane ranged from 0.39 to 1.66 per day. Predictive reaeration coefficients obtained from 18 equations (8 semiempirical and 10 empirical) were compared with each measured reaeration coefficient by use of an error-of-estimate analysis. The predictive reaeration coefficients ranged from 0.0008 to 3.4 per day. A semiempirical equation that produced coefficients most similar to the measured coefficients had the smallest absolute error of estimate (0.35). The smallest absolute error of estimate for the empirical equations was 0.41.
ERIC Educational Resources Information Center
Puhan, Gautam
2010-01-01
This study used real data to construct testing conditions for comparing results of chained linear, Tucker, and Levine-observed score equatings. The comparisons were made under conditions where the new- and old-form samples were similar in ability and when they differed in ability. The length of the anchor test was also varied to enable examination…
ERIC Educational Resources Information Center
de Guzman, Allan B.; Ines, Joanna Louise C.; Inofinada, Nina Josefa A.; Ituralde, Nielson Louie J.; Janolo, John Robert E.; Jerezo, Jnyv L.; Jhun, Hyae Suk J.
2013-01-01
While a number of empirical studies have been conducted regarding risk for falls among the elderly, there is still a paucity of similar studies in a developing country like the Philippines. This study purports to test through Structural Equation Modeling (SEM) a model that shows the interaction between and among nutrition, balance, fear of…
Improvement in lifetime of color DC PDP K, Maezawa, T. Akeyoshi, and T. Mizutani
NASA Astrophysics Data System (ADS)
Motoyama, Y.; Ushirozawa, M.; Sakai, T.
1995-05-01
An important subject for the color DC PDP is how to extend its lifetime (defined by the decrease of luminance). The empirical equations for lifetime in He-Xe, Ne-Xe gas mixture have been obtained. These equations indicate that high pressure and a current limiting resistor built into each cell can secure a lifetime over 10,000 hours, which is long enough for practical use.
Proposed Framework for Determining Added Mass of Orion Drogue Parachutes
NASA Technical Reports Server (NTRS)
Fraire, Usbaldo, Jr.; Dearman, James; Morris, Aaron
2011-01-01
The Crew Exploration Vehicle (CEV) Parachute Assembly System (CPAS) project is executing a program to qualify a parachute system for a next generation human spacecraft. Part of the qualification process involves predicting parachute riser tension during system descent with flight simulations. Human rating the CPAS hardware requires a high degree of confidence in the simulation models used to predict parachute loads. However, uncertainty exists in the heritage added mass models used for loads predictions due to a lack of supporting documentation and data. Even though CPAS anchors flight simulation loads predictions to flight tests, extrapolation of these models outside the test regime carries the risk of producing non-bounding loads. A set of equations based on empirically derived functions of skirt radius is recommended as the simplest and most viable method to test and derive an enhanced added mass model for an inflating parachute. This will increase confidence in the capability to predict parachute loads. The selected equations are based on those published in A Simplified Dynamic Model of Parachute Inflation by Dean Wolf. An Ames 80x120 wind tunnel test campaign is recommended to acquire the reefing line tension and canopy photogrammetric data needed to quantify the terms in the Wolf equations and reduce uncertainties in parachute loads predictions. Once the campaign is completed, the Wolf equations can be used to predict loads in a typical CPAS Drogue Flight test. Comprehensive descriptions of added mass test techniques from the Apollo Era to the current CPAS project are included for reference.
Statistical Mechanical Model for Adsorption Coupled with SAFT-VR Mie Equation of State.
Franco, Luís F M; Economou, Ioannis G; Castier, Marcelo
2017-10-24
We extend the SAFT-VR Mie equation of state to calculate adsorption isotherms by considering explicitly the residual energy due to the confinement effect. Assuming a square-well potential for the fluid-solid interactions, the structure imposed by the fluid-solid interface is calculated using two different approaches: an empirical expression proposed by Travalloni et al. ( Chem. Eng. Sci. 65 , 3088 - 3099 , 2010 ), and a new theoretical expression derived by applying the mean value theorem. Adopting the SAFT-VR Mie ( Lafitte et al. J. Chem. Phys. , 139 , 154504 , 2013 ) equation of state to describe the fluid-fluid interactions, and solving the phase equilibrium criteria, we calculate adsorption isotherms for light hydrocarbons adsorbed in a carbon molecular sieve and for carbon dioxide, nitrogen, and water adsorbed in a zeolite. Good results are obtained from the model using either approach. Nonetheless, the theoretical expression seems to correlate better the experimental data than the empirical one, possibly implying that a more reliable way to describe the structure ensures a better description of the thermodynamic behavior.
Ballistic Limit Equation for Single Wall Titanium
NASA Technical Reports Server (NTRS)
Ratliff, J. M.; Christiansen, Eric L.; Bryant, C.
2009-01-01
Hypervelocity impact tests and hydrocode simulations were used to determine the ballistic limit equation (BLE) for perforation of a titanium wall, as a function of wall thickness. Two titanium alloys were considered, and separate BLEs were derived for each. Tested wall thicknesses ranged from 0.5mm to 2.0mm. The single-wall damage equation of Cour-Palais [ref. 1] was used to analyze the Ti wall's shielding effectiveness. It was concluded that the Cour-Palais single-wall equation produced a non-conservative prediction of the ballistic limit for the Ti shield. The inaccurate prediction was not a particularly surprising result; the Cour-Palais single-wall BLE contains shield material properties as parameters, but it was formulated only from tests of different aluminum alloys. Single-wall Ti shield tests were run (thicknesses of 2.0 mm, 1.5 mm, 1.0 mm, and 0.5 mm) on Ti 15-3-3-3 material custom cut from rod stock. Hypervelocity impact (HVI) tests were used to establish the failure threshold empirically, using the additional constraint that the damage scales with impact energy, as was indicated by hydrocode simulations. The criterion for shield failure was defined as no detached spall from the shield back surface during HVI. Based on the test results, which confirmed an approximately energy-dependent shield effectiveness, the Cour-Palais equation was modified.
Farber, B S; Moreinis, I Sh
1995-11-01
A solution for finding a rational distribution of mass in lower limb prostheses has been considered based on the formal premise favoring the identification of the movements of a prosthetic and an intact leg. For the purpose of simplicity, and analysis has been carried out for only the swing phase, the data about the properties of moving segments being determined without integrating differential equations of motion. At the formation of equations of motion, an assumption that body segments are absolutely rigid and have constant moments of inertia and locations of the center of mass was taken into consideration. Based on independent proportions formed of combinations of the coefficients of equations of motion, a system of three equations has been formulated and solved in relation to the mass values sought: a static radius and a radius of inertia of the prosthesis complex link "shin + foot + footwear." From the six unknowns included in the equations, three values are chosen as mean values determined empirically. The solution of obtained equations results in the following conclusions: the parameters of the mass distribution in a "shin + foot + footwear" complex link depend on the amputation level and the patient's mass. These data, reported in appropriate tables, may be used in prosthetics practice. Recommendations have also been presented with regard to a prosthesic mass relative to the age of the person with amputation and a method of a balancing of prostheses aimed at the achievement of a rational distribution of masses. The analysis of obtained equations has also allowed us to make recommendations about the artificial foot mass. It has been concluded that a reasonable desire to reduce the mass of the prosthetic segments is not an end in itself, but is only the means of a rational distribution by means of balancing. It has been proved that rational prosthetic fitting results in decreased energy costs and overloads are decreased and a normalized gait.
NASA Astrophysics Data System (ADS)
Hozman, J.; Tichý, T.
2017-12-01
Stochastic volatility models enable to capture the real world features of the options better than the classical Black-Scholes treatment. Here we focus on pricing of European-style options under the Stein-Stein stochastic volatility model when the option value depends on the time, on the price of the underlying asset and on the volatility as a function of a mean reverting Orstein-Uhlenbeck process. A standard mathematical approach to this model leads to the non-stationary second-order degenerate partial differential equation of two spatial variables completed by the system of boundary and terminal conditions. In order to improve the numerical valuation process for a such pricing equation, we propose a numerical technique based on the discontinuous Galerkin method and the Crank-Nicolson scheme. Finally, reference numerical experiments on real market data illustrate comprehensive empirical findings on options with stochastic volatility.
NASA Astrophysics Data System (ADS)
Dymond, J. H.; Robertson, J.; Isdale, J. D.
1981-09-01
Viscosity coefficient measurements made with an estimated accuracy of ±2% using a self-centering falling body viscometer are reported for benzene, perdeuterobenzene, hexafluorobenzene and an equimolar mixture of benzene + hexafluorobenzene at 25, 50, 75 and 100°C at pressures up to the freezing pressure. The data for each liquid at different temperatures and pressures are correlated very satisfactorily by a graphical method based on plots of 9.118×107 ηV 2/3/(MRT)1/2 versus logV, and are reproduced to within the experimental uncertainty by a free-volume form of equation. Application of the empirical Grunberg and Nissan equation to the mixture viscosity coefficient data shows that the characteristic constant G is practically temperature- and pressure-independent for this system.
Construct validity of the Moral Development Scale for Professionals (MDSP).
Söderhamn, Olle; Bjørnestad, John Olav; Skisland, Anne; Cliffordson, Christina
2011-01-01
The aim of this study was to investigate the construct validity of the Moral Development Scale for Professionals (MDSP) using structural equation modeling. The instrument is a 12-item self-report instrument, developed in the Scandinavian cultural context and based on Kohlberg's theory. A hypothesized simplex structure model underlying the MDSP was tested through structural equation modeling. Validity was also tested as the proportion of respondents older than 20 years that reached the highest moral level, which according to the theory should be small. A convenience sample of 339 nursing students with a mean age of 25.3 years participated. Results confirmed the simplex model structure, indicating that MDSP reflects a moral construct empirically organized from low to high. A minority of respondents >20 years of age (13.5%) scored more than 80% on the highest moral level. The findings support the construct validity of the MDSP and the stages and levels in Kohlberg's theory.
Carbon deposition thresholds on nickel-based solid oxide fuel cell anodes I. Fuel utilization
NASA Astrophysics Data System (ADS)
Kuhn, J.; Kesler, O.
2015-03-01
In the first of a two part publication, the effect of fuel utilization (Uf) on carbon deposition rates in solid oxide fuel cell nickel-based anodes was studied. Representative 5-component CH4 reformate compositions (CH4, H2, CO, H2O, & CO2) were selected graphically by plotting the solutions to a system of mass-balance constraint equations. The centroid of the solution space was chosen to represent a typical anode gas mixture for each nominal Uf value. Selected 5-component and 3-component gas mixtures were then delivered to anode-supported cells for 10 h, followed by determination of the resulting deposited carbon mass. The empirical carbon deposition thresholds were affected by atomic carbon (C), hydrogen (H), and oxygen (O) fractions of the delivered gas mixtures and temperature. It was also found that CH4-rich gas mixtures caused irreversible damage, whereas atomically equivalent CO-rich compositions did not. The coking threshold predicted by thermodynamic equilibrium calculations employing graphite for the solid carbon phase agreed well with empirical thresholds at 700 °C (Uf ≈ 32%); however, at 600 °C, poor agreement was observed with the empirical threshold of ∼36%. Finally, cell operating temperatures correlated well with the difference in enthalpy between the supplied anode gas mixtures and their resulting thermodynamic equilibrium gas mixtures.
Probability of survival during accidental immersion in cold water.
Wissler, Eugene H
2003-01-01
Estimating the probability of survival during accidental immersion in cold water presents formidable challenges for both theoreticians and empirics. A number of theoretical models have been developed assuming that death occurs when the central body temperature, computed using a mathematical model, falls to a certain level. This paper describes a different theoretical approach to estimating the probability of survival. The human thermal model developed by Wissler is used to compute the central temperature during immersion in cold water. Simultaneously, a survival probability function is computed by solving a differential equation that defines how the probability of survival decreases with increasing time. The survival equation assumes that the probability of occurrence of a fatal event increases as the victim's central temperature decreases. Generally accepted views of the medical consequences of hypothermia and published reports of various accidents provide information useful for defining a "fatality function" that increases exponentially with decreasing central temperature. The particular function suggested in this paper yields a relationship between immersion time for 10% probability of survival and water temperature that agrees very well with Molnar's empirical observations based on World War II data. The method presented in this paper circumvents a serious difficulty with most previous models--that one's ability to survive immersion in cold water is determined almost exclusively by the ability to maintain a high level of shivering metabolism.
Thermal Analysis of the PediaFlow pediatric ventricular assist device.
Gardiner, Jeffrey M; Wu, Jingchun; Noh, Myounggyu D; Antaki, James F; Snyder, Trevor A; Paden, David B; Paden, Brad E
2007-01-01
Accurate modeling of heat dissipation in pediatric intracorporeal devices is crucial in avoiding tissue and blood thermotrauma. Thermal models of new Maglev ventricular assist device (VAD) concepts for the PediaFlow VAD are developed by incorporating empirical heat transfer equations with thermal finite element analysis (FEA). The models assume three main sources of waste heat generation: copper motor windings, active magnetic thrust bearing windings, and eddy currents generated within the titanium housing due to the two-pole motor. Waste heat leaves the pump by convection into blood passing through the pump and conduction through surrounding tissue. Coefficients of convection are calculated and assigned locally along fluid path surfaces of the three-dimensional pump housing model. FEA thermal analysis yields a three-dimensional temperature distribution for each of the three candidate pump models. Thermal impedances from the motor and thrust bearing windings to tissue and blood contacting surfaces are estimated based on maximum temperature rise at respective surfaces. A new updated model for the chosen pump topology is created incorporating computational fluid dynamics with empirical fluid and heat transfer equations. This model represents the final geometry of the first generation prototype, incorporates eddy current heating, and has 60 discrete convection regions. Thermal analysis is performed at nominal and maximum flow rates, and temperature distributions are plotted. Results suggest that the pump will not exceed a temperature rise of 2 degrees C during normal operation.
Relationship between the Kubelka-Munk scattering and radiative transfer coefficients.
Thennadil, Suresh N
2008-07-01
The relationship between the Kubelka-Munk (K-M) and the transport scattering coefficient is obtained through a semi-empirical approach. This approach gives the same result as that given by Gate [Appl. Opt.13, 236 (1974)] when the incident beam is diffuse. This result and those given by Star et al. [Phys. Med. Biol.33, 437 (1988)] and Brinkworth [Appl. Opt.11, 1434 (1972)] are compared with the exact solution of the radiative transfer equation over a large range of optical properties. It is found that the latter expressions, which include an absorption component, do not give accurate results over the range considered. Using the semi-empirical approach, the relationship between the K-M and the transport scattering coefficient is derived for the case where the incident light is collimated. It is shown that although the K-M equation is derived based on diffuse incident light, it can also represent very well the reflectance from a slab of infinite thickness when the incident light is collimated. However, in this case the relationship between the coefficients has to include a function that is dependent on the anisotropy factor. Analysis indicates that the K-M transform achieves the objective of obtaining a measure that gives the ratio of absorption to scattering effects for both diffuse and collimated incident beams over a large range of optical properties.
Sea Ice Freeboard and Thickness from the 2013 IceBridge ATM and DMS Data in Ross Sea, Antarctica
NASA Astrophysics Data System (ADS)
Xie, H.; Tian, L.; Tang, J.; Ackley, S. F.
2016-12-01
In November (20, 21, 27, and 28) 2013, NASA's IceBridge mission flew over the Ross Sea, Antarctica and collected important sea ice data with the ATM and DMS for the first time. We will present our methods to derive the local sea level and total freeboard for ice thickness retrieval from these two datasets. The methods include (1) leads classification from DMS data using an automated lead detection method, (2) potential leads from the reflectance of less than 0.25 from the ATM laser shots of L1B data, (3) local sea level retrieval based on these qualified ATM laser shots (L1B) within the DMS-derived leads (after outliers removal from the mean ± 2 standard deviation of these ATM elevations), (4) establishment of an empirical equation of local sea level as a function of distance from the starting point of each IceBridge flight, (5) total freeboard retrieval from the ATM L2 elevations by subtracting the local sea level derived from the empirical equation, and (6) ice thickness retrieval. The ice thickness derived from this method will be analyzed and compared with ICESat data (2003-2009) and other available data for the same region at the similar time period. Possible change and potential reasons will be identified and discussed.
Modeling of dielectric properties of aqueous salt solutions with an equation of state.
Maribo-Mogensen, Bjørn; Kontogeorgis, Georgios M; Thomsen, Kaj
2013-09-12
The static permittivity is the most important physical property for thermodynamic models that account for the electrostatic interactions between ions. The measured static permittivity in mixtures containing electrolytes is reduced due to kinetic depolarization and reorientation of the dipoles in the electrical field surrounding ions. Kinetic depolarization may explain 25-75% of the observed decrease in the permittivity of solutions containing salts, but since this is a dynamic property, this effect should not be included in the thermodynamic modeling of electrolytes. Kinetic depolarization has, however, been ignored in relation to thermodynamic modeling, and authors have either neglected the effect of salts on permittivity or used empirical correlations fitted to the measured static permittivity, leading to an overestimation of the reduction in the thermodynamic static permittivity. We present a new methodology for obtaining the static permittivity over wide ranges of temperatures, pressures, and compositions for use within an equation of state for mixed solvents containing salts. The static permittivity is calculated from a new extension of the framework developed by Onsager, Kirkwood, and Fröhlich to associating mixtures. Wertheim's association model as formulated in the statistical associating fluid theory is used to account for hydrogen-bonding molecules and ion-solvent association. Finally, we compare the Debye-Hückel Helmholtz energy obtained using an empirical model with the new physical model and show that the empirical models may introduce unphysical behavior in the equation of state.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Glass, R. W.; Gilliam, T. M.; Fowler, V. L.
An empirical model is presented for vapor-liquid equilibria and enthalpy for the CO$sub 2$-O$sub 2$ system. In the model, krypton and xenon in very low concentrations are combined with the CO$sub 2$-O$sub 2$ system, thereby representing the total system of primary interest in the High-Temperature Gas- Cooled Reactor program for removing krypton from off-gas generated during the reprocessing of spent fuel. Selected properties of the individual and combined components being considered are presented in the form of tables and empirical equations. (auth)
Review of Thawing Time Prediction Models Depending on Process Conditions and Product Characteristics
Kluza, Franciszek; Spiess, Walter E. L.; Kozłowicz, Katarzyna
2016-01-01
Summary Determining thawing times of frozen foods is a challenging problem as the thermophysical properties of the product change during thawing. A number of calculation models and solutions have been developed. The proposed solutions range from relatively simple analytical equations based on a number of assumptions to a group of empirical approaches that sometimes require complex calculations. In this paper analytical, empirical and graphical models are presented and critically reviewed. The conditions of solution, limitations and possible applications of the models are discussed. The graphical and semi--graphical models are derived from numerical methods. Using the numerical methods is not always possible as running calculations takes time, whereas the specialized software and equipment are not always cheap. For these reasons, the application of analytical-empirical models is more useful for engineering. It is demonstrated that there is no simple, accurate and feasible analytical method for thawing time prediction. Consequently, simplified methods are needed for thawing time estimation of agricultural and food products. The review reveals the need for further improvement of the existing solutions or development of new ones that will enable accurate determination of thawing time within a wide range of practical conditions of heat transfer during processing. PMID:27904387
Hybrid BEM/empirical approach for scattering of correlated sources in rocket noise prediction
NASA Astrophysics Data System (ADS)
Barbarino, Mattia; Adamo, Francesco P.; Bianco, Davide; Bartoccini, Daniele
2017-09-01
Empirical models such as the Eldred standard model are commonly used for rocket noise prediction. Such models directly provide a definition of the Sound Pressure Level through the quadratic pressure term by uncorrelated sources. In this paper, an improvement of the Eldred Standard model has been formulated. This new formulation contains an explicit expression for the acoustic pressure of each noise source, in terms of amplitude and phase, in order to investigate the sources correlation effects and to propagate them through a wave equation. In particular, the correlation effects between adjacent and not-adjacent sources have been modeled and analyzed. The noise prediction obtained with the revised Eldred-based model has then been used for formulating an empirical/BEM (Boundary Element Method) hybrid approach that allows an evaluation of the scattering effects. In the framework of the European Space Agency funded program VECEP (VEga Consolidation and Evolution Programme), these models have been applied for the prediction of the aeroacoustics loads of the VEGA (Vettore Europeo di Generazione Avanzata - Advanced Generation European Carrier Rocket) launch vehicle at lift-off and the results have been compared with experimental data.
Formulation, Implementation and Validation of a Two-Fluid model in a Fuel Cell CFD Code
DOE Office of Scientific and Technical Information (OSTI.GOV)
Jain, Kunal; Cole, J. Vernon; Kumar, Sanjiv
2008-12-01
Water management is one of the main challenges in PEM Fuel Cells. While water is essential for membrane electrical conductivity, excess liquid water leads to flooding of catalyst layers. Despite the fact that accurate prediction of two-phase transport is key for optimal water management, understanding of the two-phase transport in fuel cells is relatively poor. Wang et. al. have studied the two-phase transport in the channel and diffusion layer separately using a multiphase mixture model. The model fails to accurately predict saturation values for high humidity inlet streams. Nguyen et. al. developed a two-dimensional, two-phase, isothermal, isobaric, steady state modelmore » of the catalyst and gas diffusion layers. The model neglects any liquid in the channel. Djilali et. al. developed a three-dimensional two-phase multicomponent model. The model is an improvement over previous models, but neglects drag between the liquid and the gas phases in the channel. In this work, we present a comprehensive two-fluid model relevant to fuel cells. Models for two-phase transport through Channel, Gas Diffusion Layer (GDL) and Channel-GDL interface, are discussed. In the channel, the gas and liquid pressures are assumed to be same. The surface tension effects in the channel are incorporated using the continuum surface force (CSF) model. The force at the surface is expressed as a volumetric body force and added as a source to the momentum equation. In the GDL, the gas and liquid are assumed to be at different pressures. The difference in the pressures (capillary pressure) is calculated using an empirical correlations. At the Channel-GDL interface, the wall adhesion affects need to be taken into account. SIMPLE-type methods recast the continuity equation into a pressure-correction equation, the solution of which then provides corrections for velocities and pressures. However, in the two-fluid model, the presence of two phasic continuity equations gives more freedom and more complications. A general approach would be to form a mixture continuity equation by linearly combining the phasic continuity equations using appropriate weighting factors. Analogous to mixture equation for pressure correction, a difference equation is used for the volume/phase fraction by taking the difference between the phasic continuity equations. The relative advantages of the above mentioned algorithmic variants for computing pressure correction and volume fractions are discussed and quantitatively assessed. Preliminary model validation is done for each component of the fuel cell. The two-phase transport in the channel is validated using empirical correlations. Transport in the GDL is validated against results obtained from LBM and VOF simulation techniques. The Channel-GDL interface transport will be validated against experiment and empirical correlation of droplet detachment at the interface.« less
Mendyk, Aleksander; Güres, Sinan; Szlęk, Jakub; Wiśniowska, Barbara; Kleinebudde, Peter
2015-01-01
The purpose of this work was to develop a mathematical model of the drug dissolution (Q) from the solid lipid extrudates based on the empirical approach. Artificial neural networks (ANNs) and genetic programming (GP) tools were used. Sensitivity analysis of ANNs provided reduction of the original input vector. GP allowed creation of the mathematical equation in two major approaches: (1) direct modeling of Q versus extrudate diameter (d) and the time variable (t) and (2) indirect modeling through Weibull equation. ANNs provided also information about minimum achievable generalization error and the way to enhance the original dataset used for adjustment of the equations' parameters. Two inputs were found important for the drug dissolution: d and t. The extrudates length (L) was found not important. Both GP modeling approaches allowed creation of relatively simple equations with their predictive performance comparable to the ANNs (root mean squared error (RMSE) from 2.19 to 2.33). The direct mode of GP modeling of Q versus d and t resulted in the most robust model. The idea of how to combine ANNs and GP in order to escape ANNs' black-box drawback without losing their superior predictive performance was demonstrated. Open Source software was used to deliver the state-of-the-art models and modeling strategies. PMID:26101544
Liquid hydrogen mass flow through a multiple orifice Joule-Thomson device
NASA Astrophysics Data System (ADS)
Papell, S. Stephen; Nyland, Ted W.; Saiyed, Naseem H.
Liquid hydrogen mass flow rate, pressure drop, and temperature drop data were obtained for a number of multiple orifice Joule-Thomas devices known as visco jets. The present investigation continues a study to develop an equation for predicting two phase flow of cryogens through these devices. The test apparatus design allowed isenthalpic expansion of the cryogen through the visco jets. The data covered a range of inlet and outlet operating conditions. The mass flow rate range single phase or two phase was 0.015 to 0.98 lbm/hr. The manufacturer's equation was found to overpredict the single phase hydrogen data by 10 percent and the two phase data by as much as 27 percent. Two modifications of the equation resulted in a data correlation that predicts both the single and two phase flow across the visco jet. The first modification was of a theoretical nature, and the second strictly empirical. The former reduced the spread in the two phase data. It was a multiplication factor of 1 - X applied to the manufacturer's equation. The parameter X is the flow quality downstream of the visco jet based on isenthalpic expansion across the device. The latter modification was a 10 percent correction term that correlated 90 percent of the single and two phase data to within +/- 10 percent scatter band.
Liquid hydrogen mass flow through a multiple orifice Joule-Thomson device
NASA Technical Reports Server (NTRS)
Papell, S. S.; Nyland, Ted W.; Saiyed, Naseem H.
1992-01-01
Liquid hydrogen mass flow rate, pressure drop, and temperature drop data were obtained for a number of multiple orifice Joule-Thomson devices known as visco jets. The present investigation continues a study to develop an equation for predicting two phase flow of cryogens through these devices. The test apparatus design allowed isenthalpic expansion of the cryogen through the visco jets. The data covered a range of inlet and outlet operating conditions. The mass flow rate range single phase or two phase was 0.015 to 0.98 lbm/hr. The manufacturer's equation was found to overpredict the single phase hydrogen data by 10 percent and the two phase data by as much as 27 percent. Two modifications of the equation resulted in a data correlation that predicts both the single and two phase flow across the visco jet. The first modification was of a theoretical nature, and the second strictly empirical. The former reduced the spread in the two phase data. It was a multiplication factor of 1-X applied to the manufacturer's equation. The parameter X is the flow quality downstream of the visco jet based on isenthalpic expansion across the device. The latter modification was a 10 percent correction term that correlated 90 percent of the single and two phase data to within +/- 10 percent scatter band.
Liquid hydrogen mass flow through a multiple orifice Joule-Thomson device
NASA Technical Reports Server (NTRS)
Papell, S. Stephen; Nyland, Ted W.; Saiyed, Naseem H.
1992-01-01
Liquid hydrogen mass flow rate, pressure drop, and temperature drop data were obtained for a number of multiple orifice Joule-Thomas devices known as visco jets. The present investigation continues a study to develop an equation for predicting two phase flow of cryogens through these devices. The test apparatus design allowed isenthalpic expansion of the cryogen through the visco jets. The data covered a range of inlet and outlet operating conditions. The mass flow rate range single phase or two phase was 0.015 to 0.98 lbm/hr. The manufacturer's equation was found to overpredict the single phase hydrogen data by 10 percent and the two phase data by as much as 27 percent. Two modifications of the equation resulted in a data correlation that predicts both the single and two phase flow across the visco jet. The first modification was of a theoretical nature, and the second strictly empirical. The former reduced the spread in the two phase data. It was a multiplication factor of 1 - X applied to the manufacturer's equation. The parameter X is the flow quality downstream of the visco jet based on isenthalpic expansion across the device. The latter modification was a 10 percent correction term that correlated 90 percent of the single and two phase data to within +/- 10 percent scatter band.
Liquid hydrogen mass flow through a multiple orifice Joule-Thomson device
NASA Astrophysics Data System (ADS)
Papell, S. S.; Nyland, Ted W.; Saiyed, Naseem H.
1992-07-01
Liquid hydrogen mass flow rate, pressure drop, and temperature drop data were obtained for a number of multiple orifice Joule-Thomson devices known as visco jets. The present investigation continues a study to develop an equation for predicting two phase flow of cryogens through these devices. The test apparatus design allowed isenthalpic expansion of the cryogen through the visco jets. The data covered a range of inlet and outlet operating conditions. The mass flow rate range single phase or two phase was 0.015 to 0.98 lbm/hr. The manufacturer's equation was found to overpredict the single phase hydrogen data by 10 percent and the two phase data by as much as 27 percent. Two modifications of the equation resulted in a data correlation that predicts both the single and two phase flow across the visco jet. The first modification was of a theoretical nature, and the second strictly empirical. The former reduced the spread in the two phase data. It was a multiplication factor of 1-X applied to the manufacturer's equation. The parameter X is the flow quality downstream of the visco jet based on isenthalpic expansion across the device. The latter modification was a 10 percent correction term that correlated 90 percent of the single and two phase data to within +/- 10 percent scatter band.
Mendyk, Aleksander; Güres, Sinan; Jachowicz, Renata; Szlęk, Jakub; Polak, Sebastian; Wiśniowska, Barbara; Kleinebudde, Peter
2015-01-01
The purpose of this work was to develop a mathematical model of the drug dissolution (Q) from the solid lipid extrudates based on the empirical approach. Artificial neural networks (ANNs) and genetic programming (GP) tools were used. Sensitivity analysis of ANNs provided reduction of the original input vector. GP allowed creation of the mathematical equation in two major approaches: (1) direct modeling of Q versus extrudate diameter (d) and the time variable (t) and (2) indirect modeling through Weibull equation. ANNs provided also information about minimum achievable generalization error and the way to enhance the original dataset used for adjustment of the equations' parameters. Two inputs were found important for the drug dissolution: d and t. The extrudates length (L) was found not important. Both GP modeling approaches allowed creation of relatively simple equations with their predictive performance comparable to the ANNs (root mean squared error (RMSE) from 2.19 to 2.33). The direct mode of GP modeling of Q versus d and t resulted in the most robust model. The idea of how to combine ANNs and GP in order to escape ANNs' black-box drawback without losing their superior predictive performance was demonstrated. Open Source software was used to deliver the state-of-the-art models and modeling strategies.
Modeling electrokinetic flows by consistent implicit incompressible smoothed particle hydrodynamics
DOE Office of Scientific and Technical Information (OSTI.GOV)
Pan, Wenxiao; Kim, Kyungjoo; Perego, Mauro
2017-04-01
We present an efficient implicit incompressible smoothed particle hydrodynamics (I2SPH) discretization of Navier-Stokes, Poisson-Boltzmann, and advection-diffusion equations subject to Dirichlet or Robin boundary conditions. It is applied to model various two and three dimensional electrokinetic flows in simple or complex geometries. The I2SPH's accuracy and convergence are examined via comparison with analytical solutions, grid-based numerical solutions, or empirical models. The new method provides a framework to explore broader applications of SPH in microfluidics and complex fluids with charged objects, such as colloids and biomolecules, in arbitrary complex geometries.
Solid motor aft closure insulation erosion. [heat flux correlation for rate analysis
NASA Technical Reports Server (NTRS)
Stampfl, E.; Landsbaum, E. M.
1973-01-01
The erosion rate of aft closure insulation in a number of large solid propellant motors was empirically analyzed by correlating the average ablation rate with a number of variables that had previously been demonstrated to affect heat flux. The main correlating parameter was a heat flux based on the simplified Bartz heat transfer coefficient corrected for two-dimensional effects. A multiplying group contained terms related to port-to-throat ratio, local wall angle, grain geometry and nozzle cant angle. The resulting equation gave a good correlation and is a useful design tool.
An Empirical Estimation of Underground Thermal Performance for Malaysian Climate
NASA Astrophysics Data System (ADS)
Mukhtar, Azfarizal; Zamri Yusoff, Mohd; Khai Ching, Ng
2017-12-01
In this study, the soil temperature profile was computed based on the harmonic heat transfer equations at various depths. The meteorological data ranging from January, 1st 2016 to December, 31st 2016 measured by local weather stations were employed. The findings indicted that as the soil depth increases, the temperature changes are negligible and the soil temperature is nearly equal to the mean annual air temperature. Likewise, the results have been compared with those reported by other researchers. Overall, the predicted soil temperature can be readily adopted in various engineering applications in Malaysia.
The solubility of the noble gases He, Ne, Ar, Kr, and Xe in water up to the critical point
Potter, R.W.; Clynne, M.A.
1978-01-01
The solubility of the noble gases Ar, He, Ne, Kr, and Xe in pure water was measured from 298 to 561??K. These data in turn were extrapolated to the critical point of water, thus providing a complete set of Henry's law constants from 274 to 647??K when combined with the existing literature data. Equations describing the behavior of the Henry's law constants over this temperature range are also given. The data do not confirm extrapolations of empirical correlations based on low-temperature solubility data. ?? 1978 Plenum Publishing Corporation.
A survey and new measurements of ice vapor pressure at temperatures between 170 and 250K
NASA Technical Reports Server (NTRS)
Marti, James; Mauersberger, Konrad
1993-01-01
New measurements of ice vapor pressures at temperatures between 170 and 250 K are presented and published vapor pressure data are summarized. An empirical vapor pressure equation was derived and allows prediction of vapor pressures between 170 k and the triple point of water with an accuracy of approximately 2 percent. Predictions obtained agree, within experimental uncertainty, with the most reliable equation derived from thermodynamic principles.
Experimental study on thrust and power of flapping-wing system based on rack-pinion mechanism.
Nguyen, Tuan Anh; Vu Phan, Hoang; Au, Thi Kim Loan; Park, Hoon Cheol
2016-06-20
This experimental study investigates the effect of three parameters: wing aspect ratio (AR), wing offset, and flapping frequency, on thrust generation and power consumption of a flapping-wing system based on a rack-pinion mechanism. The new flapping-wing system is simple but robust, and is able to create a large flapping amplitude. The thrust measured by a load cell reveals that for a given power, the flapping-wing system using a higher wing AR produces larger thrust and higher flapping frequency at the wing offset of 0.15[Formula: see text] or 0.20[Formula: see text] ([Formula: see text] is the mean chord) than other wing offsets. Of the three parameters, the flapping frequency plays a more significant role on thrust generation than either the wing AR or the wing offset. Based on the measured thrusts, an empirical equation for thrust prediction is suggested, as a function of wing area, flapping frequency, flapping angle, and wing AR. The difference between the predicted and measured thrusts was less than 7%, which proved that the empirical equation for thrust prediction is reasonable. On average, the measured power consumption to flap the wings shows that 46.5% of the input power is spent to produce aerodynamic forces, 14.0% to overcome inertia force, 9.5% to drive the rack-pinion-based flapping mechanism, and 30.0% is wasted as the power loss of the installed motor. From the power analysis, it is found that the wing with an AR of 2.25 using a wing offset of 0.20[Formula: see text] showed the optimal power loading in the flapping-wing system. In addition, the flapping frequency of 25 Hz is recommended as the optimal frequency of the current flapping-wing system for high efficiency, which was 48.3%, using a wing with an AR of 2.25 and a wing offset of 0.20[Formula: see text] in the proposed design.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Siefken, L.J.
1999-01-01
Models were designed to resolve deficiencies in the SCDAP/RELAP5/MOD3.2 calculations of the configuration and integrity of hot, partially oxidized cladding. These models are expected to improve the calculations of several important aspects of fuel rod behavior. First, an improved mapping was established from a compilation of PIE results from severe fuel damage tests of the configuration of melted metallic cladding that is retained by an oxide layer. The improved mapping accounts for the relocation of melted cladding in the circumferential direction. Then, rules based on PIE results were established for calculating the effect of cladding that has relocated from abovemore » on the oxidation and integrity of the lower intact cladding upon which it solidifies. Next, three different methods were identified for calculating the extent of dissolution of the oxidic part of the cladding due to its contact with the metallic part. The extent of dissolution effects the stress and thus the integrity of the oxidic part of the cladding. Then, an empirical equation was presented for calculating the stress in the oxidic part of the cladding and evaluating its integrity based on this calculated stress. This empirical equation replaces the current criterion for loss of integrity which is based on temperature and extent of oxidation. Finally, a new rule based on theoretical and experimental results was established for identifying the regions of a fuel rod with oxidation of both the inside and outside surfaces of the cladding. The implementation of these models is expected to eliminate the tendency of the SCDAP/RELAP5 code to overpredict the extent of oxidation of the upper part of fuel rods and to underpredict the extent of oxidation of the lower part of fuel rods and the part with a high concentration of relocated material. This report is a revision and reissue of the report entitled, Improvements in Modeling of Cladding Oxidation and Meltdown.« less
NASA Technical Reports Server (NTRS)
Davis, R. L.
1986-01-01
A program called ALESEP is presented for the analysis of the inviscid-viscous interaction which occurs due to the presence of a closed laminar-transitional separation bubble on an airfoil or infinite swept wing. The ALESEP code provides an iterative solution of the boundary layer equations expressed in an inverse formulation coupled to a Cauchy integral representation of the inviscid flow. This interaction analysis is treated as a local perturbation to a known solution obtained from a global airfoil analysis; hence, part of the required input to the ALESEP code are the reference displacement thickness and tangential velocity distributions. Special windward differencing may be used in the reversed flow regions of the separation bubble to accurately account for the flow direction in the discretization of the streamwise convection of momentum. The ALESEP code contains a forced transition model based on a streamwise intermittency function, a natural transition model based on a solution of the integral form of the turbulent kinetic energy equation, and an empirical natural transition model.
NASA Astrophysics Data System (ADS)
Hooshyar, M.; Wang, D.
2016-12-01
The empirical proportionality relationship, which indicates that the ratio of cumulative surface runoff and infiltration to their corresponding potentials are equal, is the basis of the extensively used Soil Conservation Service Curve Number (SCS-CN) method. The objective of this paper is to provide the physical basis of the SCS-CN method and its proportionality hypothesis from the infiltration excess runoff generation perspective. To achieve this purpose, an analytical solution of Richards' equation is derived for ponded infiltration in shallow water table environment under the following boundary conditions: 1) the soil is saturated at the land surface; and 2) there is a no-flux boundary which moves downward. The solution is established based on the assumptions of negligible gravitational effect, constant soil water diffusivity, and hydrostatic soil moisture profile between the no-flux boundary and water table. Based on the derived analytical solution, the proportionality hypothesis is a reasonable approximation for rainfall partitioning at the early stage of ponded infiltration in areas with a shallow water table for coarse textured soils.
NASA Astrophysics Data System (ADS)
Hooshyar, Milad; Wang, Dingbao
2016-08-01
The empirical proportionality relationship, which indicates that the ratio of cumulative surface runoff and infiltration to their corresponding potentials are equal, is the basis of the extensively used Soil Conservation Service Curve Number (SCS-CN) method. The objective of this paper is to provide the physical basis of the SCS-CN method and its proportionality hypothesis from the infiltration excess runoff generation perspective. To achieve this purpose, an analytical solution of Richards' equation is derived for ponded infiltration in shallow water table environment under the following boundary conditions: (1) the soil is saturated at the land surface; and (2) there is a no-flux boundary which moves downward. The solution is established based on the assumptions of negligible gravitational effect, constant soil water diffusivity, and hydrostatic soil moisture profile between the no-flux boundary and water table. Based on the derived analytical solution, the proportionality hypothesis is a reasonable approximation for rainfall partitioning at the early stage of ponded infiltration in areas with a shallow water table for coarse textured soils.
How does slope form affect erosion in CATFLOW-SED?
NASA Astrophysics Data System (ADS)
Gabelmann, Petra; Wienhöfer, Jan; Zehe, Erwin
2016-04-01
Erosion is a severe environmental problem in agro-ecosystems with highly erodible loess soils. It is controlled by various factors, e.g. rainfall intensity, initial wetness conditions, soil type, land use and tillage practice. Furthermore slope form and gradient have been shown to influence erosion amounts to a large extent. Within the last fifty years, various erosion models have been developed to describe the erosion process, estimate erosion amounts and identify erosion-prone areas. These models differ in terms of complexity, the processes which are considered, and the data required for model calibration and they can be categorised into empirical or statistical, conceptual, and physically-based models. CATFLOW-SED is a process-based hydrology and erosion model that can operate on catchment and hillslope scales. Soil water dynamics are described by the Richards equation including effective approaches for preferential flow. Evapotranspiration is simulated using an approach based on the Penman-Monteith equation. The model simulates overland flow using the diffusion wave equation. Soil detachment is related to the attacking forces of rainfall and overland flow, and the erosion resistance of soil. Sediment transport capacity and sediment deposition are related to overland flow velocity using the equation of Engelund and Hansen and the sinking velocity of grain sizes respectively. We performed a study to analyse the erosion process on different virtual hillslopes, with varying slope gradient and slope form, using the CATFLOW-SED model. We explored the role of landform on erosion and sedimentation, particularly we look for forms that either maximise or minimise erosion. Results indicate the importance to performing the process implementation within physically meaningful limits and choose appropriate model parameters respectively.
Healy, Richard W.; Scanlon, Bridget R.
2010-01-01
Simulation models are widely used in all types of hydrologic studies, and many of these models can be used to estimate recharge. Models can provide important insight into the functioning of hydrologic systems by identifying factors that influence recharge. The predictive capability of models can be used to evaluate how changes in climate, water use, land use, and other factors may affect recharge rates. Most hydrological simulation models, including watershed models and groundwater-flow models, are based on some form of water-budget equation, so the material in this chapter is closely linked to that in Chapter 2. Empirical models that are not based on a water-budget equation have also been used for estimating recharge; these models generally take the form of simple estimation equations that define annual recharge as a function of precipitation and possibly other climatic data or watershed characteristics.Model complexity varies greatly. Some models are simple accounting models; others attempt to accurately represent the physics of water movement through each compartment of the hydrologic system. Some models provide estimates of recharge explicitly; for example, a model based on the Richards equation can simulate water movement from the soil surface through the unsaturated zone to the water table. Recharge estimates can be obtained indirectly from other models. For example, recharge is a parameter in groundwater-flow models that solve for hydraulic head (i.e. groundwater level). Recharge estimates can be obtained through a model calibration process in which recharge and other model parameter values are adjusted so that simulated water levels agree with measured water levels. The simulation that provides the closest agreement is called the best fit, and the recharge value used in that simulation is the model-generated estimate of recharge.
Efficient model reduction of parametrized systems by matrix discrete empirical interpolation
NASA Astrophysics Data System (ADS)
Negri, Federico; Manzoni, Andrea; Amsallem, David
2015-12-01
In this work, we apply a Matrix version of the so-called Discrete Empirical Interpolation (MDEIM) for the efficient reduction of nonaffine parametrized systems arising from the discretization of linear partial differential equations. Dealing with affinely parametrized operators is crucial in order to enhance the online solution of reduced-order models (ROMs). However, in many cases such an affine decomposition is not readily available, and must be recovered through (often) intrusive procedures, such as the empirical interpolation method (EIM) and its discrete variant DEIM. In this paper we show that MDEIM represents a very efficient approach to deal with complex physical and geometrical parametrizations in a non-intrusive, efficient and purely algebraic way. We propose different strategies to combine MDEIM with a state approximation resulting either from a reduced basis greedy approach or Proper Orthogonal Decomposition. A posteriori error estimates accounting for the MDEIM error are also developed in the case of parametrized elliptic and parabolic equations. Finally, the capability of MDEIM to generate accurate and efficient ROMs is demonstrated on the solution of two computationally-intensive classes of problems occurring in engineering contexts, namely PDE-constrained shape optimization and parametrized coupled problems.
Refractive Index of Alkali Halides and Its Wavelength and Temperature Derivatives.
1975-05-01
of CoBr . . . .......... 236 82. Comparison of Dispersion Equations Proposed for CsBr ... . 237 83. Recommmded Values on the Refractive Index and Its... discovery of empirical relationships which enable us to calculate dn/dT data at 293 K for some ma- terials on which no data are available. In the data...or in handbooks. In the present work, however, this problem 160 was solved by our empirical discoveries by which the unknown parameters of Eq. (19) for
Theoretical Motions of Hydrofoil Systems
1947-06-01
mentioned in the main test. 22 NACA TIT No. 1285 By the use of D ’ Alemberts principle , the" following equations of equilibrium at the center of gravity...spacing-is d ^Bii;a^i§_iiv order; tominimize the.-effepts-of unavo idable.. change s iiic enter-: of, r gravi ty. location. eine ouster ej._ $n...disturbance to hydrofoil system k, empirical constant used to determine value 1 *(WJ* of d (CT) /ÖZ1 fco> k5 empirical constants used to determine
Single evolution equation in a light-matter pairing system
NASA Astrophysics Data System (ADS)
Bugaychuk, S.; Tobisch, E.
2018-03-01
The coupled system including wave mixing and nonlinear dynamics of a nonlocal optical medium is usually studied (1) numerically, with the medium being regarded as a black box, or (2) experimentally, making use of some empirical assumptions. In this paper we deduce for the first time a single evolution equation describing the dynamics of the pairing system as a holistic complex. For a non-degenerate set of parameters, we obtain the nonlinear Schrödinger equation with coefficients being written out explicitly. Analytical solutions of this equation can be experimentally realized in any photorefractive medium, e.g. in photorefractive, liquid or photonic crystals. For instance, a soliton-like solution can be used in dynamical holography for designing an artificial grating with maximal amplification of an image.
Oblate-Earth Effects on the Calculation of Ec During Spacecraft Reentry
NASA Technical Reports Server (NTRS)
Bacon, John B.; Matney, Mark
2017-01-01
The bulge in the Earth at its equator has been shown to lead to a clustering of natural decays biased to occur towards the equator and away from the orbit's extreme latitudes. Such clustering must be considered when predicting the Expectation of Casualty (Ec) during a natural decay, because of the corresponding clustering of the human population in the lower latitudes. This study expands upon prior work, and formalizes in a single empirical equation the correction that must be made to the calculation of the average exposed population density as a result of this effect. The equation is represented as a function of ballistic number and inclination of the entering spacecraft over the credible range of ballistic numbers.
Engineering analyses for railroad tank car head puncture resistance
DOT National Transportation Integrated Search
2006-11-06
This paper describes engineering analyses to estimate the : forces, deformations, and puncture resistance of railroad tank : cars. Different approaches to examine puncture of the tank car : head are described. One approach is semi-empirical equations...
Derrida, Bernard; Meerson, Baruch; Sasorov, Pavel V
2016-04-01
Consider a one-dimensional branching Brownian motion and rescale the coordinate and time so that the rates of branching and diffusion are both equal to 1. If X_{1}(t) is the position of the rightmost particle of the branching Brownian motion at time t, the empirical velocity c of this rightmost particle is defined as c=X_{1}(t)/t. Using the Fisher-Kolmogorov-Petrovsky-Piscounov equation, we evaluate the probability distribution P(c,t) of this empirical velocity c in the long-time t limit for c>2. It is already known that, for a single seed particle, P(c,t)∼exp[-(c^{2}/4-1)t] up to a prefactor that can depend on c and t. Here we show how to determine this prefactor. The result can be easily generalized to the case of multiple seed particles and to branching random walks associated with other traveling-wave equations.
The educated midwife in the Roman Empire. An example of differential equations.
Laes, Christian
2010-01-01
This paper deals with both the reality and the idealization of training of midwives in the Roman Empire. It aims at a full survey of the existing source material (mainly literary and epigraphical sources, though iconographical and papyrological evidence has been included in the discussion). For the first time, a complete collection of the epigraphically attested Latin cases will be given. Moreover, I will deal with the apparent contradiction between the image of the educated midwife as it is exhibited mainly by Soranus, and the picture of midwives as low class women as it is revealed in other sources. In doing so, I will make use of the concept of differential equations, as applied by Joshel and Murnaghan concerning women and slaves in ancient society. As such, I will take issue with the Cilliers and Retief thesis about the social role of women in ancient medicine.
Plausibility check of a redesigned rain-on-snow simulator (RASA)
NASA Astrophysics Data System (ADS)
Rössler, Ole; Probst, Sabine; Weingartner, Rolf
2016-04-01
Rain-on-snow events are fascinating but still not completely understood processes. Although, several studies and equations have been published since decades that describe past events and theoretical descriptions, empirical data of what is happening in the snow cover is far less available. A way to fill this gap of empirical data, rain-on-snow-simulators might be of help. In 2013, Juras et al. published their inspiring idea of a portable rain-on-snow simulator. The huge advantage of this devise - in contrast to other purely field-based experiments - are their fixed, and mostly standardized conditions and the possibility to measure all required data to monitor the water fluxes and melting processes at a time. Mounted in a convenient location, a large number of experiments are relatively easy conductible. We applied and further developed the original device and plausified the results of this redesigned version, called RASA. The principal design was borrowed from the original version being a frame with a sprinkler on top and a snow sample in a box at the bottom, from which the outflow is measured with a tipping gauge. We added a moving sprinkling plate to ensure a uniform distribution of raindrops on the snow, and - most importantly - we suspended the watered snow sampled on weighting cells. The latter enables to continuous measurement of the snow sample throughout the experiment and thus the indirect quantification of liquid water saturation, water holding capacity, and snowmelt amount via balance equations. As it is remains unclear if this device is capable to reproduce known processes, a hypothesis based plausibility check was accomplished. Thus, eight hypothesizes were derived from literature and tested in 28 experiments with the RASA mounted at 2000 m elevation. In general, we were able to reproduce most of the hypotheses. The RASA proved to be a very valuable device that can generate suitable results and has the potential to extend the empirical-experimental data set on rain-on-snow events. Juras R., et al. (2013): A portable simulator for investigating rain-on-snow events, Zeitschrift für Geomorphologie, 57, Suppl.1, 73-89.
Density of Jatropha curcas Seed Oil and its Methyl Esters: Measurement and Estimations
NASA Astrophysics Data System (ADS)
Veny, Harumi; Baroutian, Saeid; Aroua, Mohamed Kheireddine; Hasan, Masitah; Raman, Abdul Aziz; Sulaiman, Nik Meriam Nik
2009-04-01
Density data as a function of temperature have been measured for Jatropha curcas seed oil, as well as biodiesel jatropha methyl esters at temperatures from above their melting points to 90 ° C. The data obtained were used to validate the method proposed by Spencer and Danner using a modified Rackett equation. The experimental and estimated density values using the modified Rackett equation gave almost identical values with average absolute percent deviations less than 0.03% for the jatropha oil and 0.04% for the jatropha methyl esters. The Janarthanan empirical equation was also employed to predict jatropha biodiesel densities. This equation performed equally well with average absolute percent deviations within 0.05%. Two simple linear equations for densities of jatropha oil and its methyl esters are also proposed in this study.
Mohammad Al Alfy, Ibrahim
2018-01-01
A set of three pads was constructed from primary materials (sand, gravel and cement) to calibrate the gamma-gamma density tool. A simple equation was devised to convert the qualitative cps values to quantitative g/cc values. The neutron-neutron porosity tool measures the qualitative cps porosity values. A direct equation was derived to calculate the porosity percentage from the cps porosity values. Cement-bond log illustrates the cement quantities, which surround well pipes. This log needs a difficult process due to the existence of various parameters, such as: drilling well diameter as well as internal diameter, thickness and type of well pipes. An equation was invented to calculate the cement percentage at standard conditions. This equation can be modified according to varying conditions. Copyright © 2017 Elsevier Ltd. All rights reserved.
Reconstruction of normal forms by learning informed observation geometries from data.
Yair, Or; Talmon, Ronen; Coifman, Ronald R; Kevrekidis, Ioannis G
2017-09-19
The discovery of physical laws consistent with empirical observations is at the heart of (applied) science and engineering. These laws typically take the form of nonlinear differential equations depending on parameters; dynamical systems theory provides, through the appropriate normal forms, an "intrinsic" prototypical characterization of the types of dynamical regimes accessible to a given model. Using an implementation of data-informed geometry learning, we directly reconstruct the relevant "normal forms": a quantitative mapping from empirical observations to prototypical realizations of the underlying dynamics. Interestingly, the state variables and the parameters of these realizations are inferred from the empirical observations; without prior knowledge or understanding, they parametrize the dynamics intrinsically without explicit reference to fundamental physical quantities.
Shizgal, Bernie D
2018-05-01
This paper considers two nonequilibrium model systems described by linear Fokker-Planck equations for the time-dependent velocity distribution functions that yield steady state Kappa distributions for specific system parameters. The first system describes the time evolution of a charged test particle in a constant temperature heat bath of a second charged particle. The time dependence of the distribution function of the test particle is given by a Fokker-Planck equation with drift and diffusion coefficients for Coulomb collisions as well as a diffusion coefficient for wave-particle interactions. A second system involves the Fokker-Planck equation for electrons dilutely dispersed in a constant temperature heat bath of atoms or ions and subject to an external time-independent uniform electric field. The momentum transfer cross section for collisions between the two components is assumed to be a power law in reduced speed. The time-dependent Fokker-Planck equations for both model systems are solved with a numerical finite difference method and the approach to equilibrium is rationalized with the Kullback-Leibler relative entropy. For particular choices of the system parameters for both models, the steady distribution is found to be a Kappa distribution. Kappa distributions were introduced as an empirical fitting function that well describe the nonequilibrium features of the distribution functions of electrons and ions in space science as measured by satellite instruments. The calculation of the Kappa distribution from the Fokker-Planck equations provides a direct physically based dynamical approach in contrast to the nonextensive entropy formalism by Tsallis [J. Stat. Phys. 53, 479 (1988)JSTPBS0022-471510.1007/BF01016429].
NASA Astrophysics Data System (ADS)
Shizgal, Bernie D.
2018-05-01
This paper considers two nonequilibrium model systems described by linear Fokker-Planck equations for the time-dependent velocity distribution functions that yield steady state Kappa distributions for specific system parameters. The first system describes the time evolution of a charged test particle in a constant temperature heat bath of a second charged particle. The time dependence of the distribution function of the test particle is given by a Fokker-Planck equation with drift and diffusion coefficients for Coulomb collisions as well as a diffusion coefficient for wave-particle interactions. A second system involves the Fokker-Planck equation for electrons dilutely dispersed in a constant temperature heat bath of atoms or ions and subject to an external time-independent uniform electric field. The momentum transfer cross section for collisions between the two components is assumed to be a power law in reduced speed. The time-dependent Fokker-Planck equations for both model systems are solved with a numerical finite difference method and the approach to equilibrium is rationalized with the Kullback-Leibler relative entropy. For particular choices of the system parameters for both models, the steady distribution is found to be a Kappa distribution. Kappa distributions were introduced as an empirical fitting function that well describe the nonequilibrium features of the distribution functions of electrons and ions in space science as measured by satellite instruments. The calculation of the Kappa distribution from the Fokker-Planck equations provides a direct physically based dynamical approach in contrast to the nonextensive entropy formalism by Tsallis [J. Stat. Phys. 53, 479 (1988), 10.1007/BF01016429].
Modelling soil erosion at European scale: towards harmonization and reproducibility
NASA Astrophysics Data System (ADS)
Bosco, C.; de Rigo, D.; Dewitte, O.; Poesen, J.; Panagos, P.
2015-02-01
Soil erosion by water is one of the most widespread forms of soil degradation. The loss of soil as a result of erosion can lead to decline in organic matter and nutrient contents, breakdown of soil structure and reduction of the water-holding capacity. Measuring soil loss across the whole landscape is impractical and thus research is needed to improve methods of estimating soil erosion with computational modelling, upon which integrated assessment and mitigation strategies may be based. Despite the efforts, the prediction value of existing models is still limited, especially at regional and continental scale, because a systematic knowledge of local climatological and soil parameters is often unavailable. A new approach for modelling soil erosion at regional scale is here proposed. It is based on the joint use of low-data-demanding models and innovative techniques for better estimating model inputs. The proposed modelling architecture has at its basis the semantic array programming paradigm and a strong effort towards computational reproducibility. An extended version of the Revised Universal Soil Loss Equation (RUSLE) has been implemented merging different empirical rainfall-erosivity equations within a climatic ensemble model and adding a new factor for a better consideration of soil stoniness within the model. Pan-European soil erosion rates by water have been estimated through the use of publicly available data sets and locally reliable empirical relationships. The accuracy of the results is corroborated by a visual plausibility check (63% of a random sample of grid cells are accurate, 83% at least moderately accurate, bootstrap p ≤ 0.05). A comparison with country-level statistics of pre-existing European soil erosion maps is also provided.
Valenzuela-Calahorro, C; Cuerda-Correa, E; Navarrete-Guijosa, A; Gonzalez-Pradas, E
2002-06-01
The knowledge of sorption processes of nonelectrolytes in solution by solid adsorbents implies the study of kinetics, equilibrium, and thermodynamic functions. However, quite frequently the equilibrium isotherms are studied by comparing them with those corresponding to the Giles et al. classification (1); these isotherms are also analyzed by fitting them to equations based on thermodynamic or kinetic criteria, and even to empirical equations. Nevertheless, information obtained is more coherent and satisfactory if the adsorption isotherms are fitted by using an equation describing the equilibrium isotherms according to the kinetic laws. These mentioned laws would determine each one of the unitary processes (one or more) which condition the global process. In this paper, an adsorption process of prednisolone in solution by six carbonaceous materials is explained according to a previously proposed single model, which allows to establish a kinetic law which fits satisfactorily most of C vs t isotherms (2). According to the above-mentioned kinetic law, equations describing sorption equilibrium processes have been deducted, and experimental data points have been fitted to these equations; such a fitting yields to different values of adsorption capacity and kinetic equilibrium constants for the different processes at several temperatures. However, in spite of their practical interest, these constants have no thermodynamic signification. Thus, the thermodynamic equilibrium constant (K) has been calculated by using a modified expression of the Gaines et al. equation (3). Global average values of the thermodynamic functions have also been calculated from the K values. Information related to variations of DeltaH and DeltaS with the surface coverage fraction was obtained by using the corresponding Clausius-Clapeyron equations.
Production, depreciation and the size distribution of firms
NASA Astrophysics Data System (ADS)
Ma, Qi; Chen, Yongwang; Tong, Hui; Di, Zengru
2008-05-01
Many empirical researches indicate that firm size distributions in different industries or countries exhibit some similar characters. Among them the fact that many firm size distributions obey power-law especially for the upper end has been mostly discussed. Here we present an agent-based model to describe the evolution of manufacturing firms. Some basic economic behaviors are taken into account, which are production with decreasing marginal returns, preferential allocation of investments, and stochastic depreciation. The model gives a steady size distribution of firms which obey power-law. The effect of parameters on the power exponent is analyzed. The theoretical results are given based on both the Fokker-Planck equation and the Kesten process. They are well consistent with the numerical results.
Dynamic equilibrium of reconstituting hematopoietic stem cell populations.
O'Quigley, John
2010-12-01
Clonal dominance in hematopoietic stem cell populations is an important question of interest but not one we can directly answer. Any estimates are based on indirect measurement. For marked populations, we can equate empirical and theoretical moments for binomial sampling, in particular we can use the well-known formula for the sampling variation of a binomial proportion. The empirical variance itself cannot always be reliably estimated and some caution is needed. We describe the difficulties here and identify ready solutions which only require appropriate use of variance-stabilizing transformations. From these we obtain estimators for the steady state, or dynamic equilibrium, of the number of hematopoietic stem cells involved in repopulating the marrow. The calculations themselves are not too involved. We give the distribution theory for the estimator as well as simple approximations for practical application. As an illustration, we rework on data recently gathered to address the question as to whether or not reconstitution of marrow grafts in the clinical setting might be considered to be oligoclonal.
NASA Astrophysics Data System (ADS)
Adams, Matthew P.; Collier, Catherine J.; Uthicke, Sven; Ow, Yan X.; Langlois, Lucas; O'Brien, Katherine R.
2017-01-01
When several models can describe a biological process, the equation that best fits the data is typically considered the best. However, models are most useful when they also possess biologically-meaningful parameters. In particular, model parameters should be stable, physically interpretable, and transferable to other contexts, e.g. for direct indication of system state, or usage in other model types. As an example of implementing these recommended requirements for model parameters, we evaluated twelve published empirical models for temperature-dependent tropical seagrass photosynthesis, based on two criteria: (1) goodness of fit, and (2) how easily biologically-meaningful parameters can be obtained. All models were formulated in terms of parameters characterising the thermal optimum (Topt) for maximum photosynthetic rate (Pmax). These parameters indicate the upper thermal limits of seagrass photosynthetic capacity, and hence can be used to assess the vulnerability of seagrass to temperature change. Our study exemplifies an approach to model selection which optimises the usefulness of empirical models for both modellers and ecologists alike.
Adams, Matthew P; Collier, Catherine J; Uthicke, Sven; Ow, Yan X; Langlois, Lucas; O'Brien, Katherine R
2017-01-04
When several models can describe a biological process, the equation that best fits the data is typically considered the best. However, models are most useful when they also possess biologically-meaningful parameters. In particular, model parameters should be stable, physically interpretable, and transferable to other contexts, e.g. for direct indication of system state, or usage in other model types. As an example of implementing these recommended requirements for model parameters, we evaluated twelve published empirical models for temperature-dependent tropical seagrass photosynthesis, based on two criteria: (1) goodness of fit, and (2) how easily biologically-meaningful parameters can be obtained. All models were formulated in terms of parameters characterising the thermal optimum (T opt ) for maximum photosynthetic rate (P max ). These parameters indicate the upper thermal limits of seagrass photosynthetic capacity, and hence can be used to assess the vulnerability of seagrass to temperature change. Our study exemplifies an approach to model selection which optimises the usefulness of empirical models for both modellers and ecologists alike.
Adams, Matthew P.; Collier, Catherine J.; Uthicke, Sven; Ow, Yan X.; Langlois, Lucas; O’Brien, Katherine R.
2017-01-01
When several models can describe a biological process, the equation that best fits the data is typically considered the best. However, models are most useful when they also possess biologically-meaningful parameters. In particular, model parameters should be stable, physically interpretable, and transferable to other contexts, e.g. for direct indication of system state, or usage in other model types. As an example of implementing these recommended requirements for model parameters, we evaluated twelve published empirical models for temperature-dependent tropical seagrass photosynthesis, based on two criteria: (1) goodness of fit, and (2) how easily biologically-meaningful parameters can be obtained. All models were formulated in terms of parameters characterising the thermal optimum (Topt) for maximum photosynthetic rate (Pmax). These parameters indicate the upper thermal limits of seagrass photosynthetic capacity, and hence can be used to assess the vulnerability of seagrass to temperature change. Our study exemplifies an approach to model selection which optimises the usefulness of empirical models for both modellers and ecologists alike. PMID:28051123
Kish-Gephart, Jennifer J; Harrison, David A; Treviño, Linda Klebe
2010-01-01
As corporate scandals proliferate, practitioners and researchers alike need a cumulative, quantitative understanding of the antecedents associated with unethical decisions in organizations. In this meta-analysis, the authors draw from over 30 years of research and multiple literatures to examine individual ("bad apple"), moral issue ("bad case"), and organizational environment ("bad barrel") antecedents of unethical choice. Findings provide empirical support for several foundational theories and paint a clearer picture of relationships characterized by mixed results. Structural equation modeling revealed the complexity (multidetermined nature) of unethical choice, as well as a need for research that simultaneously examines different sets of antecedents. Moderator analyses unexpectedly uncovered better prediction of unethical behavior than of intention for several variables. This suggests a need to more strongly consider a new "ethical impulse" perspective in addition to the traditional "ethical calculus" perspective. Results serve as a data-based foundation and guide for future theoretical and empirical development in the domain of behavioral ethics. Copyright 2009 APA, all rights reserved.
Sabry, A H; W Hasan, W Z; Ab Kadir, M Z A; Radzi, M A M; Shafie, S
2018-01-01
The power system always has several variations in its profile due to random load changes or environmental effects such as device switching effects when generating further transients. Thus, an accurate mathematical model is important because most system parameters vary with time. Curve modeling of power generation is a significant tool for evaluating system performance, monitoring and forecasting. Several numerical techniques compete to fit the curves of empirical data such as wind, solar, and demand power rates. This paper proposes a new modified methodology presented as a parametric technique to determine the system's modeling equations based on the Bode plot equations and the vector fitting (VF) algorithm by fitting the experimental data points. The modification is derived from the familiar VF algorithm as a robust numerical method. This development increases the application range of the VF algorithm for modeling not only in the frequency domain but also for all power curves. Four case studies are addressed and compared with several common methods. From the minimal RMSE, the results show clear improvements in data fitting over other methods. The most powerful features of this method is the ability to model irregular or randomly shaped data and to be applied to any algorithms that estimating models using frequency-domain data to provide state-space or transfer function for the model.
W. Hasan, W. Z.
2018-01-01
The power system always has several variations in its profile due to random load changes or environmental effects such as device switching effects when generating further transients. Thus, an accurate mathematical model is important because most system parameters vary with time. Curve modeling of power generation is a significant tool for evaluating system performance, monitoring and forecasting. Several numerical techniques compete to fit the curves of empirical data such as wind, solar, and demand power rates. This paper proposes a new modified methodology presented as a parametric technique to determine the system’s modeling equations based on the Bode plot equations and the vector fitting (VF) algorithm by fitting the experimental data points. The modification is derived from the familiar VF algorithm as a robust numerical method. This development increases the application range of the VF algorithm for modeling not only in the frequency domain but also for all power curves. Four case studies are addressed and compared with several common methods. From the minimal RMSE, the results show clear improvements in data fitting over other methods. The most powerful features of this method is the ability to model irregular or randomly shaped data and to be applied to any algorithms that estimating models using frequency-domain data to provide state-space or transfer function for the model. PMID:29351554
Skrdla, Peter J; Floyd, Philip D; Dell'Orco, Philip C
2017-08-09
Predicting the glass transition temperature (T g ) of mixtures has applications that span across industries and scientific disciplines. By plotting experimentally determined T g values as a function of the glass composition, one can usually apply the Gordon-Taylor (G-T) equation to determine the slope, k, which subsequently can be used in T g predictions. Traditionally viewed as a phenomenological/empirical model, this work proposes a physical basis for the G-T equation. The proposed equations allow for the calculation of k directly and, hence, they determine/predict the T g values of mixtures algebraically. Two derivations for k are provided, one for strong glass-formers and the other for fragile mixtures, with the modeled trehalose-water and naproxen-indomethacin systems serving as examples of each. Separately, a new equation is described for the first time that allows for the direct determination of the crossover temperature, T x , for fragile glass-formers. Lastly, the so-called "Rule of 2/3", which is commonly used to estimate the T g of a pure amorphous phase based solely on the fusion/melting temperature, T f , of the corresponding crystalline phase, is shown to be underpinned by the heat capacity ratio of the two phases referenced to a common temperature, as evidenced by the calculations put forth for indomethacin and felodipine.
Numerical Simulations of Flow Separation Control in Low-Pressure Turbines using Plasma Actuators
NASA Technical Reports Server (NTRS)
Suzen, Y. B.; Huang, P. G.; Ashpis, D. E.
2007-01-01
A recently introduced phenomenological model to simulate flow control applications using plasma actuators has been further developed and improved in order to expand its use to complicated actuator geometries. The new modeling approach eliminates the requirement of an empirical charge density distribution shape by using the embedded electrode as a source for the charge density. The resulting model is validated against a flat plate experiment with quiescent environment. The modeling approach incorporates the effect of the plasma actuators on the external flow into Navier Stokes computations as a body force vector which is obtained as a product of the net charge density and the electric field. The model solves the Maxwell equation to obtain the electric field due to the applied AC voltage at the electrodes and an additional equation for the charge density distribution representing the plasma density. The new modeling approach solves the charge density equation in the computational domain assuming the embedded electrode as a source therefore automatically generating a charge density distribution on the surface exposed to the flow similar to that observed in the experiments without explicitly specifying an empirical distribution. The model is validated against a flat plate experiment with quiescent environment.
Renormalization of the fragmentation equation: exact self-similar solutions and turbulent cascades.
Saveliev, V L; Gorokhovski, M A
2012-12-01
Using an approach developed earlier for renormalization of the Boltzmann collision integral [Saveliev and Nanbu, Phys. Rev. E 65, 051205 (2002)], we derive an exact divergence form for the fragmentation operator. Then we reduce the fragmentation equation to the continuity equation in size space, with the flux given explicitly. This allows us to obtain self-similar solutions and to find the integral of motion for these solutions (we call it the bare flux). We show how these solutions can be applied as a description of cascade processes in three- and two-dimensional turbulence. We also suggested an empirical cascade model of impact fragmentation of brittle materials.
Bubble statistics in aged wet foams and the Fokker-Planck equation
NASA Astrophysics Data System (ADS)
Zimnyakov, D. A.; Yuvchenko, S. A.; Tzyipin, D. V.; Samorodina, T. V.
2018-04-01
Results of the experimental study of changes in the bubble size statistics during aging of wet foams are discussed. It is proposed that the evolution of the bubble radii distributions can be described in terms of the one dimensional Fokker- Planck equation. The empirical distributions of the bubble radii exhibit a self-similarity of their shapes and can be transformed to a time-independent form using the radius renormalization. Analysis of obtained data allows us to suggest that the drift term of the Fokker-Planck equation dominates in comparison with the diffusion term in the case of aging of isolated quasi-stable wet foams.
Developing a generalized allometric equation for aboveground biomass estimation
NASA Astrophysics Data System (ADS)
Xu, Q.; Balamuta, J. J.; Greenberg, J. A.; Li, B.; Man, A.; Xu, Z.
2015-12-01
A key potential uncertainty in estimating carbon stocks across multiple scales stems from the use of empirically calibrated allometric equations, which estimate aboveground biomass (AGB) from plant characteristics such as diameter at breast height (DBH) and/or height (H). The equations themselves contain significant and, at times, poorly characterized errors. Species-specific equations may be missing. Plant responses to their local biophysical environment may lead to spatially varying allometric relationships. The structural predictor may be difficult or impossible to measure accurately, particularly when derived from remote sensing data. All of these issues may lead to significant and spatially varying uncertainties in the estimation of AGB that are unexplored in the literature. We sought to quantify the errors in predicting AGB at the tree and plot level for vegetation plots in California. To accomplish this, we derived a generalized allometric equation (GAE) which we used to model the AGB on a full set of tree information such as DBH, H, taxonomy, and biophysical environment. The GAE was derived using published allometric equations in the GlobAllomeTree database. The equations were sparse in details about the error since authors provide the coefficient of determination (R2) and the sample size. A more realistic simulation of tree AGB should also contain the noise that was not captured by the allometric equation. We derived an empirically corrected variance estimate for the amount of noise to represent the errors in the real biomass. Also, we accounted for the hierarchical relationship between different species by treating each taxonomic level as a covariate nested within a higher taxonomic level (e.g. species < genus). This approach provides estimation under incomplete tree information (e.g. missing species) or blurred information (e.g. conjecture of species), plus the biophysical environment. The GAE allowed us to quantify contribution of each different covariate in estimating the AGB of trees. Lastly, we applied the GAE to an existing vegetation plot database - Forest Inventory and Analysis database - to derive per-tree and per-plot AGB estimations, their errors, and how much the error could be contributed to the original equations, the plant's taxonomy, and their biophysical environment.
NASA Astrophysics Data System (ADS)
Pisek, J.
2017-12-01
Clumping index (CI) is the measure of foliage aggregation relative to a random distribution of leaves in space. CI is an important factor for the correct quantification of true leaf area index (LAI). Global and regional scale CI maps have been generated from various multi-angle sensors based on an empirical relationship with the normalized difference between hotspot and darkspot (NDHD) index (Chen et al., 2005). Ryu et al. (2011) suggested that accurate calculation of radiative transfer in a canopy, important for controlling gross primary productivity (GPP) and evapotranspiration (ET) (Baldocchi and Harley, 1995), should be possible by integrating CI with incoming solar irradiance and LAI from MODIS land and atmosphere products. It should be noted that MODIS LAI/FPAR product uses internal non-empirical, stochastic equations for parameterization of foliage clumping. This raises a question if integration of the MODIS LAI product with empirically-based CI maps does not introduce any inconsistencies. Here, the consistency is examined independently through the `recollision probability theory' or `p-theory' (Knyazikhin et al., 1998) along with raw LAI-2000/2200 Plant Canopy Analyzer (PCA) data from > 30 sites, surveyed across a range of vegetation types. The theory predicts that the amount of radiation scattered by a canopy should depend only on the wavelength and the spectrally invariant canopy structural parameter p. The parameter p is linked to the foliage clumping (Stenberg et al., 2016). Results indicate that integration of the MODIS LAI product with empirically-based CI maps is feasible. Importantly, for the first time it is shown that it is possible to obtain p values for any location solely from Earth Observation data. This is very relevant for future applications of photon recollision probability concept for global and local monitoring of vegetation using Earth Observation data.
Smart Utilization of Tertiary Instructional Modes
ERIC Educational Resources Information Center
Hamilton, John; Tee, Singwhat
2010-01-01
This empirical research surveys first year tertiary business students across different campuses regarding their perceived views concerning traditional, blended and flexible instructional approaches. A structural equation modeling approach shows traditional instructional modes deliver lower levels of student-perceived learning quality, learning…
NASA Technical Reports Server (NTRS)
Komar, Paul D.
1987-01-01
The concept of flow competence is generally employed to evaluate the velocities, discharges, and bottom stresses of river floods inferred from the size of the largest sediment particles transported. Flow competence has become an important tool for evaluating the hydraulics of exceptional floods on Earth, including those which eroded the Channeled Scabland of eastern Washington, and has potential for similar evaluations of the floods which carved the outflow channels on Mars. For the most part, flow-competence evaluations were empirical, based on data compiled from a variety of sources including major terrestrial floods caused by natural processes or dam failures. Such flow-competence relationships would appear to provide a straight-forward assessment of flood-flow stresses and velocities based on the maximum size of gravel and boulders transported. However, a re-examination of the data base and comparisons with measurements of selective entrainment and transport of gravel in rivers open to question such evaluations. Analyses of the forces acting on the grain during entrainment by pivoting, rolling, or sliding, an approach which focuses more on the physical processes than the purely empirical relationships can be demonstrated. These derived equations require further testing by flume and field measurements before being applied to flow-competence evaluations. Such tests are now underway.
The development of a peak-time criterion for designing controlled-release devices.
Simon, Laurent; Ospina, Juan
2016-08-25
This work consists of estimating dynamic characteristics for topically-applied drugs when the magnitude of the flux increases to a maximum value, called peak flux, before declining to zero. This situation is typical of controlled-released systems with a finite donor or vehicle volume. Laplace transforms were applied to the governing equations and resulted in an expression for the flux in terms of the physical characteristics of the system. After approximating this function by a second-order model, three parameters of this reduced structure captured the essential features of the original process. Closed-form relationships were then developed for the peak flux and time-to-peak based on the empirical representation. Three case studies that involve mechanisms, such as diffusion, partitioning, dissolution and elimination, were selected to illustrate the procedure. The technique performed successfully as shown by the ability of the second-order flux to match the prediction of the original transport equations. A main advantage of the proposed method is that it does not require a solution of the original partial differential equations. Less accurate results were noted for longer lag times. Copyright © 2016 Elsevier B.V. All rights reserved.
Fokker-Planck description for the queue dynamics of large tick stocks.
Garèche, A; Disdier, G; Kockelkoren, J; Bouchaud, J-P
2013-09-01
Motivated by empirical data, we develop a statistical description of the queue dynamics for large tick assets based on a two-dimensional Fokker-Planck (diffusion) equation. Our description explicitly includes state dependence, i.e., the fact that the drift and diffusion depend on the volume present on both sides of the spread. "Jump" events, corresponding to sudden changes of the best limit price, must also be included as birth-death terms in the Fokker-Planck equation. All quantities involved in the equation can be calibrated using high-frequency data on the best quotes. One of our central findings is that the dynamical process is approximately scale invariant, i.e., the only relevant variable is the ratio of the current volume in the queue to its average value. While the latter shows intraday seasonalities and strong variability across stocks and time periods, the dynamics of the rescaled volumes is universal. In terms of rescaled volumes, we found that the drift has a complex two-dimensional structure, which is a sum of a gradient contribution and a rotational contribution, both stable across stocks and time. This drift term is entirely responsible for the dynamical correlations between the ask queue and the bid queue.
Fokker-Planck description for the queue dynamics of large tick stocks
NASA Astrophysics Data System (ADS)
Garèche, A.; Disdier, G.; Kockelkoren, J.; Bouchaud, J.-P.
2013-09-01
Motivated by empirical data, we develop a statistical description of the queue dynamics for large tick assets based on a two-dimensional Fokker-Planck (diffusion) equation. Our description explicitly includes state dependence, i.e., the fact that the drift and diffusion depend on the volume present on both sides of the spread. “Jump” events, corresponding to sudden changes of the best limit price, must also be included as birth-death terms in the Fokker-Planck equation. All quantities involved in the equation can be calibrated using high-frequency data on the best quotes. One of our central findings is that the dynamical process is approximately scale invariant, i.e., the only relevant variable is the ratio of the current volume in the queue to its average value. While the latter shows intraday seasonalities and strong variability across stocks and time periods, the dynamics of the rescaled volumes is universal. In terms of rescaled volumes, we found that the drift has a complex two-dimensional structure, which is a sum of a gradient contribution and a rotational contribution, both stable across stocks and time. This drift term is entirely responsible for the dynamical correlations between the ask queue and the bid queue.
Penke, Lars; Deary, Ian J
2010-09-01
Charlton et al. (2008) (Charlton, R.A., Landua, S., Schiavone, F., Barrick, T.R., Clark, C.A., Markus, H.S., Morris, R.G.A., 2008. Structural equation modelling investigation of age-related variance in executive function and DTI-measured white matter change. Neurobiol. Aging 29, 1547-1555) presented a model that suggests a specific age-related effect of white matter integrity on working memory. We illustrate potential pitfalls of structural equation modelling by criticizing their model for (a) its neglect of latent variables, (b) its complexity, (c) its questionable causal assumptions, (d) the use of empirical model reduction, (e) the mix-up of theoretical perspectives, and (f) the failure to compare alternative models. We show that a more parsimonious model, based solely on the well-established general factor of cognitive ability, fits their data at least as well. Importantly, when modelled this way there is no support for a role of white matter integrity in cognitive aging in this sample, indicating that their conclusion is strongly dependent on how the data are analysed. We suggest that evidence from more conclusive study designs is needed. Copyright 2009 Elsevier Inc. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Seal, Sudip K; Perumalla, Kalyan S; Hirshman, Steven Paul
2013-01-01
Simulations that require solutions of block tridiagonal systems of equations rely on fast parallel solvers for runtime efficiency. Leading parallel solvers that are highly effective for general systems of equations, dense or sparse, are limited in scalability when applied to block tridiagonal systems. This paper presents scalability results as well as detailed analyses of two parallel solvers that exploit the special structure of block tridiagonal matrices to deliver superior performance, often by orders of magnitude. A rigorous analysis of their relative parallel runtimes is shown to reveal the existence of a critical block size that separates the parameter space spannedmore » by the number of block rows, the block size and the processor count, into distinct regions that favor one or the other of the two solvers. Dependence of this critical block size on the above parameters as well as on machine-specific constants is established. These formal insights are supported by empirical results on up to 2,048 cores of a Cray XT4 system. To the best of our knowledge, this is the highest reported scalability for parallel block tridiagonal solvers to date.« less
NASA Technical Reports Server (NTRS)
Ehlers, F. E.; Sebastian, J. D.; Weatherill, W. H.
1979-01-01
Analytical and empirical studies of a finite difference method for the solution of the transonic flow about harmonically oscillating wings and airfoils are presented. The procedure is based on separating the velocity potential into steady and unsteady parts and linearizing the resulting unsteady equations for small disturbances. Since sinusoidal motion is assumed, the unsteady equation is independent of time. Three finite difference investigations are discussed including a new operator for mesh points with supersonic flow, the effects on relaxation solution convergence of adding a viscosity term to the original differential equation, and an alternate and relatively simple downstream boundary condition. A method is developed which uses a finite difference procedure over a limited inner region and an approximate analytical procedure for the remaining outer region. Two investigations concerned with three-dimensional flow are presented. The first is the development of an oblique coordinate system for swept and tapered wings. The second derives the additional terms required to make row relaxation solutions converge when mixed flow is present. A finite span flutter analysis procedure is described using the two-dimensional unsteady transonic program with a full three-dimensional steady velocity potential.
Bayesian Factor Analysis as a Variable Selection Problem: Alternative Priors and Consequences
Lu, Zhao-Hua; Chow, Sy-Miin; Loken, Eric
2016-01-01
Factor analysis is a popular statistical technique for multivariate data analysis. Developments in the structural equation modeling framework have enabled the use of hybrid confirmatory/exploratory approaches in which factor loading structures can be explored relatively flexibly within a confirmatory factor analysis (CFA) framework. Recently, a Bayesian structural equation modeling (BSEM) approach (Muthén & Asparouhov, 2012) has been proposed as a way to explore the presence of cross-loadings in CFA models. We show that the issue of determining factor loading patterns may be formulated as a Bayesian variable selection problem in which Muthén and Asparouhov’s approach can be regarded as a BSEM approach with ridge regression prior (BSEM-RP). We propose another Bayesian approach, denoted herein as the Bayesian structural equation modeling with spike and slab prior (BSEM-SSP), which serves as a one-stage alternative to the BSEM-RP. We review the theoretical advantages and disadvantages of both approaches and compare their empirical performance relative to two modification indices-based approaches and exploratory factor analysis with target rotation. A teacher stress scale data set (Byrne, 2012; Pettegrew & Wolf, 1982) is used to demonstrate our approach. PMID:27314566
A two-layer multiple-time-scale turbulence model and grid independence study
NASA Technical Reports Server (NTRS)
Kim, S.-W.; Chen, C.-P.
1989-01-01
A two-layer multiple-time-scale turbulence model is presented. The near-wall model is based on the classical Kolmogorov-Prandtl turbulence hypothesis and the semi-empirical logarithmic law of the wall. In the two-layer model presented, the computational domain of the conservation of mass equation and the mean momentum equation penetrated up to the wall, where no slip boundary condition has been prescribed; and the near wall boundary of the turbulence equations has been located at the fully turbulent region, yet very close to the wall, where the standard wall function method has been applied. Thus, the conservation of mass constraint can be satisfied more rigorously in the two-layer model than in the standard wall function method. In most of the two-layer turbulence models, the number of grid points to be used inside the near-wall layer posed the issue of computational efficiency. The present finite element computational results showed that the grid independent solutions were obtained with as small as two grid points, i.e., one quadratic element, inside the near wall layer. Comparison of the computational results obtained by using the two-layer model and those obtained by using the wall function method is also presented.
Numerical Modeling of Cavitating Venturi: A Flow Control Element of Propulsion System
NASA Technical Reports Server (NTRS)
Majumdar, Alok; Saxon, Jeff (Technical Monitor)
2002-01-01
In a propulsion system, the propellant flow and mixture ratio could be controlled either by variable area flow control valves or by passive flow control elements such as cavitating venturies. Cavitating venturies maintain constant propellant flowrate for fixed inlet conditions (pressure and temperature) and wide range of outlet pressures, thereby maintain constant, engine thrust and mixture ratio. The flowrate through the venturi reaches a constant value and becomes independent of outlet pressure when the pressure at throat becomes equal to vapor pressure. In order to develop a numerical model of propulsion system, it is necessary to model cavitating venturies in propellant feed systems. This paper presents a finite volume model of flow network of a cavitating venturi. The venturi was discretized into a number of control volumes and mass, momentum and energy conservation equations in each control volume are simultaneously solved to calculate one-dimensional pressure, density, and flowrate and temperature distribution. The numerical model predicts cavitations at the throat when outlet pressure was gradually reduced. Once cavitation starts, with further reduction of downstream pressure, no change in flowrate is found. The numerical predictions have been compared with test data and empirical equation based on Bernoulli's equation.
Empirical Ground Motion Characterization of Induced Seismicity in Alberta and Oklahoma
NASA Astrophysics Data System (ADS)
Novakovic, M.; Atkinson, G. M.; Assatourians, K.
2017-12-01
We develop empirical ground-motion prediction equations (GMPEs) for ground motions from induced earthquakes in Alberta and Oklahoma following the stochastic-model-based method of Atkinson et al. (2015 BSSA). The Oklahoma ground-motion database is compiled from over 13,000 small to moderate seismic events (M 1 to 5.8) recorded at 1600 seismic stations, at distances from 1 to 750 km. The Alberta database is compiled from over 200 small to moderate seismic events (M 1 to 4.2) recorded at 50 regional stations, at distances from 30 to 500 km. A generalized inversion is used to solve for regional source, attenuation and site parameters. The obtained parameters describe the regional attenuation, stress parameter and site amplification. Resolving these parameters allows for the derivation of regionally-calibrated GMPEs that can be used to compare ground motion observations between waste water injection (Oklahoma) and hydraulic fracture induced events (Alberta), and further compare induced observations with ground motions resulting from natural sources (California, NGAWest2). The derived GMPEs have applications for the evaluation of hazards from induced seismicity and can be used to track amplitudes across the regions in real time, which is useful for ground-motion-based alerting systems and traffic light protocols.
Osman, S M; Grosdidier, B; Ali, I; Abdellah, A Ben
2013-06-01
Quite recently, we reported a semianalytical equation of state (EOS) for the Ga-Pb alloy [Phys. Rev. B 78, 024205 (2008)], which was based on the first-order perturbation theory of fluid mixtures, within the simplified random phase approximation, in conjunction with the Grosdidier et al. model pair potentials for Ga-Ga and Pb-Pb with a suitable nonadditive pair potential between Ga-Pb unlike pairs. In the present work, we employ the present EOS to calculate the Ga-Pb phase diagram along the immiscibility gap region. The accuracy of the EOS is tested by consulting the empirical binodal curve. A statistical-mechanical-based theory for the surface tension is employed to obtain an analytical expression for the alloy surface tension. We calculated the surface tension along the bimodal curve and at extreme conditions of temperatures and pressures. The surface tension exhibits reasonably well the prewetting transition of Pb atoms at the surface of the Ga-rich liquid alloy and could qualitatively explain the prewetting phenomena occurring in the Ga-rich side of the phase diagram. The predicted prewetting line and wetting temperature qualitatively agree with the empirical measurements.
Shear wave velocities of unconsolidated shallow sediments in the Gulf of Mexico
Lee, Myung W.
2013-01-01
Accurate shear-wave velocities for shallow sediments are important for a variety of seismic applications such as inver-sion and amplitude versus offset analysis. During the U.S. Department of Energy-sponsored Gas Hydrate Joint Industry Project Leg II, shear-wave velocities were measured at six wells in the Gulf of Mexico using the logging-while-drilling SonicScope acoustic tool. Because the tool measurement point was only 35 feet from the drill bit, the adverse effect of the borehole condition, which is severe for the shallow unconsolidated sediments in the Gulf of Mexico, was mini-mized and accurate shear-wave velocities of unconsolidated sediments were measured. Measured shear-wave velocities were compared with the shear-wave velocities predicted from the compressional-wave velocities using empirical formulas and the rock physics models based on the Biot-Gassmann theory, and the effectiveness of the two prediction methods was evaluated. Although the empirical equation derived from measured shear-wave data is accurate for predicting shear-wave velocities for depths greater than 500 feet in these wells, the three-phase Biot-Gassmann-theory -based theory appears to be optimum for predicting shear-wave velocities for shallow unconsolidated sediments in the Gulf of Mexico.
Isotope Separation in Concurrent Gas Centrifuges
NASA Astrophysics Data System (ADS)
Bogovalov, S. V.; Borman, V. D.
An analytical equation defining separative power of an optimized concurrent gas centrifuge is obtained for an arbitrary binary mixture of isotopes. In the case of the uranium isotopes the equation gives δU= 12.7(V/700 m/s)2(300 K/T)L, kg SWU/yr, where L and V are the length and linear velocity of the rotor of the gas centrifuge, T is the temperature. This formula well agrees with an empirical separative power of counter current gas centrifuges.
The impact of fraction magnitude knowledge on algebra performance and learning.
Booth, Julie L; Newton, Kristie J; Twiss-Garrity, Laura K
2014-02-01
Knowledge of fractions is thought to be crucial for success with algebra, but empirical evidence supporting this conjecture is just beginning to emerge. In the current study, Algebra 1 students completed magnitude estimation tasks on three scales (0-1 [fractions], 0-1,000,000, and 0-62,571) just before beginning their unit on equation solving. Results indicated that fraction magnitude knowledge, and not whole number knowledge, was especially related to students' pretest knowledge of equation solving and encoding of equation features. Pretest fraction knowledge was also predictive of students' improvement in equation solving and equation encoding skills. Students' placement of unit fractions (e.g., those with a numerator of 1) was not especially useful for predicting algebra performance and learning in this population. Placement of non-unit fractions was more predictive, suggesting that proportional reasoning skills might be an important link between fraction knowledge and learning algebra. Copyright © 2013 Elsevier Inc. All rights reserved.
Dust cyclone research in the 21st century
USDA-ARS?s Scientific Manuscript database
Research to meet the demand for ever more efficient dust cyclones continues after some eighty years. Recent trends emphasize design optimization through computational fluid dynamics (CFD) and testing design subtleties not modeled by semi-empirical equations. Improvements to current best available ...
Shear in high strength concrete bridge girders : technical report.
DOT National Transportation Integrated Search
2013-04-01
Prestressed Concrete (PC) I-girders are used extensively as the primary superstructure components in Texas highway bridges. : A simple semi-empirical equation was developed at the University of Houston (UH) to predict the shear strength of PC I-girde...
Modeling electrokinetic flows by consistent implicit incompressible smoothed particle hydrodynamics
Pan, Wenxiao; Kim, Kyungjoo; Perego, Mauro; ...
2017-01-03
In this paper, we present a consistent implicit incompressible smoothed particle hydrodynamics (I 2SPH) discretization of Navier–Stokes, Poisson–Boltzmann, and advection–diffusion equations subject to Dirichlet or Robin boundary conditions. It is applied to model various two and three dimensional electrokinetic flows in simple or complex geometries. The accuracy and convergence of the consistent I 2SPH are examined via comparison with analytical solutions, grid-based numerical solutions, or empirical models. Lastly, the new method provides a framework to explore broader applications of SPH in microfluidics and complex fluids with charged objects, such as colloids and biomolecules, in arbitrary complex geometries.
NASA Astrophysics Data System (ADS)
Conroy, M. W.; Budzevich, M. M.; Lin, Y.; Oleynik, I. I.; White, C. T.
2009-12-01
An empirical correction to account for van der Waals interactions based on the work of Neumann and Perrin [J. Phys. Chem. B 109, 15531 (2005)] was applied to density functional theory calculations of energetic molecular crystals. The calculated equilibrium unit-cell volumes of FOX-7, β-HMX, solid nitromethane, PETN-I, α-RDX, and TATB show a significant improvement in the agreement with experimental results. Hydrostatic-compression simulations of β-HMX, PETN-I, and α-RDX were also performed. The isothermal equations of state calculated from the results show increased agreement with experiment in the pressure intervals studied.
Time-dependent seismic hazard analysis for the Greater Tehran and surrounding areas
NASA Astrophysics Data System (ADS)
Jalalalhosseini, Seyed Mostafa; Zafarani, Hamid; Zare, Mehdi
2018-01-01
This study presents a time-dependent approach for seismic hazard in Tehran and surrounding areas. Hazard is evaluated by combining background seismic activity, and larger earthquakes may emanate from fault segments. Using available historical and paleoseismological data or empirical relation, the recurrence time and maximum magnitude of characteristic earthquakes for the major faults have been explored. The Brownian passage time (BPT) distribution has been used to calculate equivalent fictitious seismicity rate for major faults in the region. To include ground motion uncertainty, a logic tree and five ground motion prediction equations have been selected based on their applicability in the region. Finally, hazard maps have been presented.
Topography and geology site effects from the intensity prediction model (ShakeMap) for Austria
NASA Astrophysics Data System (ADS)
del Puy Papí Isaba, María; Jia, Yan; Weginger, Stefan
2017-04-01
The seismicity in Austria can be categorized as moderated. Despite the fact that the hazard seems to be rather low, earthquakes can cause great damage and losses, specially in densely populated and industrialized areas. It is well known, that equations which predict intensity as a function of magnitude and distance, among other parameters, are useful tool for hazard and risk assessment. Therefore, this study aims to determine an empirical model of the ground shaking intensities (ShakeMap) of a series of earthquakes occurred in Austria between 1000 and 2014. Furthermore, the obtained empirical model will lead to further interpretation of both, contemporary and historical earthquakes. A total of 285 events, which epicenters were located in Austria, and a sum of 22.739 reported macreoseismic data points from Austria and adjoining countries, were used. These events are enclosed in the period 1000-2014 and characterized by having a local magnitude greater than 3. In the first state of the model development, the data was careful selected, e.g. solely intensities equal or greater than III were used. In a second state the data was adjusted to the selected empirical model. Finally, geology and topography corrections were obtained by means of the model residuals in order to derive intensity-based site amplification effects.
Optimization of a middle atmosphere diagnostic scheme
NASA Astrophysics Data System (ADS)
Akmaev, Rashid A.
1997-06-01
A new assimilative diagnostic scheme based on the use of a spectral model was recently tested on the CIRA-86 empirical model. It reproduced the observed climatology with an annual global rms temperature deviation of 3.2 K in the 15-110 km layer. The most important new component of the scheme is that the zonal forcing necessary to maintain the observed climatology is diagnosed from empirical data and subsequently substituted into the simulation model at the prognostic stage of the calculation in an annual cycle mode. The simulation results are then quantitatively compared with the empirical model, and the above mentioned rms temperature deviation provides an objective measure of the `distance' between the two climatologies. This quantitative criterion makes it possible to apply standard optimization procedures to the whole diagnostic scheme and/or the model itself. The estimates of the zonal drag have been improved in this study by introducing a nudging (Newtonian-cooling) term into the thermodynamic equation at the diagnostic stage. A proper optimal adjustment of the strength of this term makes it possible to further reduce the rms temperature deviation of simulations down to approximately 2.7 K. These results suggest that direct optimization can successfully be applied to atmospheric model parameter identification problems of moderate dimensionality.
Ponec, R; Amat, L; Carbó-Dorca, R
1999-05-01
Since the dawn of quantitative structure-properties relationships (QSPR), empirical parameters related to structural, electronic and hydrophobic molecular properties have been used as molecular descriptors to determine such relationships. Among all these parameters, Hammett sigma constants and the logarithm of the octanol-water partition coefficient, log P, have been massively employed in QSPR studies. In the present paper, a new molecular descriptor, based on quantum similarity measures (QSM), is proposed as a general substitute of these empirical parameters. This work continues previous analyses related to the use of QSM to QSPR, introducing molecular quantum self-similarity measures (MQS-SM) as a single working parameter in some cases. The use of MQS-SM as a molecular descriptor is first confirmed from the correlation with the aforementioned empirical parameters. The Hammett equation has been examined using MQS-SM for a series of substituted carboxylic acids. Then, for a series of aliphatic alcohols and acetic acid esters, log P values have been correlated with the self-similarity measure between density functions in water and octanol of a given molecule. And finally, some examples and applications of MQS-SM to determine QSAR are presented. In all studied cases MQS-SM appeared to be excellent molecular descriptors usable in general QSPR applications of chemical interest.
NASA Astrophysics Data System (ADS)
Ponec, Robert; Amat, Lluís; Carbó-dorca, Ramon
1999-05-01
Since the dawn of quantitative structure-properties relationships (QSPR), empirical parameters related to structural, electronic and hydrophobic molecular properties have been used as molecular descriptors to determine such relationships. Among all these parameters, Hammett σ constants and the logarithm of the octanol- water partition coefficient, log P, have been massively employed in QSPR studies. In the present paper, a new molecular descriptor, based on quantum similarity measures (QSM), is proposed as a general substitute of these empirical parameters. This work continues previous analyses related to the use of QSM to QSPR, introducing molecular quantum self-similarity measures (MQS-SM) as a single working parameter in some cases. The use of MQS-SM as a molecular descriptor is first confirmed from the correlation with the aforementioned empirical parameters. The Hammett equation has been examined using MQS-SM for a series of substituted carboxylic acids. Then, for a series of aliphatic alcohols and acetic acid esters, log P values have been correlated with the self-similarity measure between density functions in water and octanol of a given molecule. And finally, some examples and applications of MQS-SM to determine QSAR are presented. In all studied cases MQS-SM appeared to be excellent molecular descriptors usable in general QSPR applications of chemical interest.
NASA Technical Reports Server (NTRS)
Weatherill, W. H.; Ehlers, F. E.; Yip, E.; Sebastian, J. D.
1980-01-01
Analytical and empirical studies of a finite difference method for the solution of the transonic flow about harmonically oscillating wings and airfoils are presented. The procedure is based on separating the velocity potential into steady and unsteady parts and linearizing the resulting unsteady equations for small disturbances. The steady velocity potential is obtained first from the well-known nonlinear equation for steady transonic flow. The unsteady velocity potential is then obtained from a linear differential equation in complex form with spatially varying coefficients. Since sinusoidal motion is assumed, the unsteady equation is independent of time. An out-of-core direct solution procedure was developed and applied to two-dimensional sections. Results are presented for a section of vanishing thickness in subsonic flow and an NACA 64A006 airfoil in supersonic flow. Good correlation is obtained in the first case at values of Mach number and reduced frequency of direct interest in flutter analyses. Reasonable results are obtained in the second case. Comparisons of two-dimensional finite difference solutions with exact analytic solutions indicate that the accuracy of the difference solution is dependent on the boundary conditions used on the outer boundaries. Homogeneous boundary conditions on the mesh edges that yield complex eigenvalues give the most accurate finite difference solutions. The plane outgoing wave boundary conditions meet these requirements.
IR spectroscopy as a source of data on bond strengths
NASA Astrophysics Data System (ADS)
Finkelshtein, E. I.; Shamsiev, R. S.
2018-02-01
The aim of this work is the estimation of double bond strength, namely Cdbnd O bonds in ketones and aldehydes and Cdbnd C bonds in various compounds. By the breaking of these bonds one or both fragments formed are carbenes, for which experimental data on the enthalpies of formation (ΔHf298) are scarce. Thus for the estimation of ΔHf298 of the corresponding carbenes, the empirical equations were proposed based on different approximations. In addition, a quantum chemical calculations of the ΔHf298 values of carbenes were performed, and the data obtained were compared with experimental values and the results of earlier calculations. Equations for the calculation of Cdbnd O bond strengths of different ketones and aldehydes from the corresponding stretching frequencies ν(Cdbnd O) were derived. Using the proposed equations, the strengths of Cdbnd O bonds of 25 ketones and 12 conjugated aldehydes, as well as Cdbnd C bonds of 13 hydrocarbons and 7 conjugated aldehydes were estimated for the first time. Linear correlations of Cdbnd C and Cdbnd O bond strengths with the bond lengths were established, and the equations permitting the estimation of the double bond strengths and lengths with acceptable accuracy were obtained. Also, the strength of central Cdbnd C bond of stilbene was calculated for the first time. The uncertainty of the strengths of double bonds obtained may be regarded as accurate ±10-15 kJ/mol.
NASA Astrophysics Data System (ADS)
Phillips, C. B.; Jerolmack, D. J.
2017-12-01
Understanding when coarse sediment begins to move in a river is essential for linking rivers to the evolution of mountainous landscapes. Unfortunately, the threshold of surface particle motion is notoriously difficult to measure in the field. However, recent studies have shown that the threshold of surface motion is empirically correlated with channel slope, a property that is easy to measure and readily available from the literature. These studies have thoroughly examined the mechanistic underpinnings behind the observed correlation and produced suitably complex models. These models are difficult to implement for natural rivers using widely available data, and thus others have treated the empirical regression between slope and the threshold of motion as a predictive model. We note that none of the authors of the original studies exploring this correlation suggested their empirical regressions be used in a predictive fashion, nevertheless these regressions between slope and the threshold of motion have found their way into numerous recent studies engendering potentially spurious conclusions. We demonstrate that there are two significant problems with using these empirical equations for prediction: (1) the empirical regressions are based on a limited sampling of the phase space of bed-load rivers and (2) the empirical measurements of bankfull and critical shear stresses are paired. The upshot of these problems limits the empirical relations predictive capacity to field sites drawn from the same region of the bed-load river phase space and that the paired nature of the data introduces a spurious correlation when considering the ratio of bankfull to critical shear stress. Using a large compilation of bed-load river hydraulic geometry data, we demonstrate that the variation within independently measured values of the threshold of motion changes systematically with bankfull shields stress and not channel slope. Additionally, we highlight using several recent datasets the potential pitfalls that one can encounter when using simplistic empirical regressions to predict the threshold of motion showing that while these concerns could be construed as subtle the resulting implications can be substantial.
Errors in calculated oncotic pressure of dog plasma.
Gabel, J C; Scott, R L; Adair, T H; Drake, R E; Traber, D L
1980-12-01
Several equations to calculate plasma oncotic pressure (pi) from the total protein concentration (C) have been previously described. These equations were derived empirically from samples with a wide range of C obtained by diluting or concentrating normal plasma samples. To test these equations over a range of naturally occurring C, we measured C and pi of plasma samples from 40 dogs. C ranged from 5.3 to 8.7 g/dl and averaged 6.5 +/- 0.1 (mean +/- SE) and pi averaged 17.9 +/- 0.3 mmHg. The regression equation was pi = 78.14 + 1.67 C (r = 0.74). pi increased with C much less than predicted with the commonly used equations. The albumin-to-globulin concentration ratios (A/G), determined in 27 of the dogs, decreased with increasing C (A/G = 1.56-0.128 C, r = 0.62). The lower A/G at the higher C's could cause the lower than predicted increase in pi with C, because the equations were developed from data in which A/G was constant.
Effect of sub-pore scale morphology of biological deposits on porous media flow properties
NASA Astrophysics Data System (ADS)
Ghezzehei, T. A.
2012-12-01
Biological deposits often influence fluid flow by altering the pore space morphology and related hydrologic properties such as porosity, water retention characteristics, and permeability. In most coupled-processes models changes in porosity are inferred from biological process models using mass-balance. The corresponding evolution of permeability is estimated using (semi-) empirical porosity-permeability functions such as the Kozeny-Carman equation or power-law functions. These equations typically do not account for the heterogeneous spatial distribution and morphological irregularities of the deposits. As a result, predictions of permeability evolution are generally unsatisfactory. In this presentation, we demonstrate the significance of pore-scale deposit distribution on porosity-permeability relations using high resolution simulations of fluid flow through a single pore interspersed with deposits of varying morphologies. Based on these simulations, we present a modification to the Kozeny-Carman model that accounts for the shape of the deposits. Limited comparison with published experimental data suggests the plausibility of the proposed conceptual model.
Empirical Approach for Determining Axial Strength of Circular Concrete Filled Steel Tubular Columns
NASA Astrophysics Data System (ADS)
Jayalekshmi, S.; Jegadesh, J. S. Sankar; Goel, Abhishek
2018-06-01
The concrete filled steel tubular (CFST) columns are highly regarded in recent years as an interesting option in the construction field by designers and structural engineers, due to their exquisite structural performance, with enhanced load bearing capacity and energy absorption capacity. This study presents a new approach to simulate the capacity of circular CFST columns under axial loading condition, using a large database of experimental results by applying artificial neural network (ANN). A well trained network is established and is used to simulate the axial capacity of CFST columns. The validation and testing of the ANN is carried out. The current study is focused on proposing a simplified equation that can predict the ultimate strength of the axially loaded columns with high level of accuracy. The predicted results are compared with five existing analytical models which estimate the strength of the CFST column. The ANN-based equation has good prediction with experimental data, when compared with the analytical models.
The thermodynamics of dense granular flow and jamming
NASA Astrophysics Data System (ADS)
Lu, Shih Yu
The scope of the thesis is to propose, based on experimental evidence and theoretical validation, a quantifiable connection between systems that exhibit the jamming phenomenon. When jammed, some materials that flow are able to resist deformation so that they appear solid-like on the laboratory scale. But unlike ordinary fusion, which has a critically defined criterion in pressure and temperature, jamming occurs under a wide range of conditions. These condition have been rigorously investigated but at the moment, no self-consistent framework can apply to grains, foam and colloids that may have suddenly ceased to flow. To quantify the jamming behavior, a constitutive model of dense granular flows is deduced from shear-flow experiments. The empirical equations are then generalized, via a thermodynamic approach, into an equation-of-state for jamming. Notably, the unifying theory also predicts the experimental data on the behavior of molecular glassy liquids. This analogy paves a crucial road map for a unifying theoretical framework in condensed matter, for example, ranging from sand to fire retardants to toothpaste.
NASA Technical Reports Server (NTRS)
Yang, H. Q.; West, Jeff
2016-01-01
Propellant slosh is a potential source of disturbance critical to the stability of space vehicles. The slosh dynamics are typically represented by a mechanical model of a spring-mass-damper. This mechanical model is then included in the equation of motion of the entire vehicle for Guidance, Navigation and Control analysis. A Volume-Of-Fluid (VOF) based Computational Fluid Dynamics (CFD) program developed at MSFC was applied to extract slosh damping in the baffled tank from the first principle. First the experimental data using water with sub-scale smooth wall tank were used as the baseline validation. It is demonstrated that CFD can indeed accurately predict low damping values from the smooth wall at different fill levels. The damping due to a ring baffles at different depths from the free surface was then simulated, and fairly good agreement with experimental measurement was observed. Comparison with an empirical correlation of Miles equation is also made.
Pore-scale modeling of saturated permeabilities in random sphere packings.
Pan, C; Hilpert, M; Miller, C T
2001-12-01
We use two pore-scale approaches, lattice-Boltzmann (LB) and pore-network modeling, to simulate single-phase flow in simulated sphere packings that vary in porosity and sphere-size distribution. For both modeling approaches, we determine the size of the representative elementary volume with respect to the permeability. Permeabilities obtained by LB modeling agree well with Rumpf and Gupte's experiments in sphere packings for small Reynolds numbers. The LB simulations agree well with the empirical Ergun equation for intermediate but not for small Reynolds numbers. We suggest a modified form of Ergun's equation to describe both low and intermediate Reynolds number flows. The pore-network simulations agree well with predictions from the effective-medium approximation but underestimate the permeability due to the simplified representation of the porous media. Based on LB simulations in packings with log-normal sphere-size distributions, we suggest a permeability relation with respect to the porosity, as well as the mean and standard deviation of the sphere diameter.
Calculation of effective penetration depth in X-ray diffraction for pharmaceutical solids.
Liu, Jodi; Saw, Robert E; Kiang, Y-H
2010-09-01
The use of the glancing incidence X-ray diffraction configuration to depth profile surface phase transformations is of interest to pharmaceutical scientists. The Parratt equation has been used to depth profile phase changes in pharmaceutical compacts. However, it was derived to calculate 1/e penetration at glancing incident angles slightly below the critical angle of condensed matter and is, therefore, applicable to surface studies of materials such as single crystalline nanorods and metal thin films. When the depth of interest is 50-200 microm into the surface, which is typical for pharmaceutical solids, the 1/e penetration depth, or skin depth, can be directly calculated from an exponential absorption law without utilizing the Parratt equation. In this work, we developed a more relevant method to define X-ray penetration depth based on the signal detection limits of the X-ray diffractometer. Our definition of effective penetration depth was empirically verified using bilayer compacts of varying known thicknesses of mannitol and lactose.
Monroe, Scott; Cai, Li
2015-01-01
This research is concerned with two topics in assessing model fit for categorical data analysis. The first topic involves the application of a limited-information overall test, introduced in the item response theory literature, to structural equation modeling (SEM) of categorical outcome variables. Most popular SEM test statistics assess how well the model reproduces estimated polychoric correlations. In contrast, limited-information test statistics assess how well the underlying categorical data are reproduced. Here, the recently introduced C2 statistic of Cai and Monroe (2014) is applied. The second topic concerns how the root mean square error of approximation (RMSEA) fit index can be affected by the number of categories in the outcome variable. This relationship creates challenges for interpreting RMSEA. While the two topics initially appear unrelated, they may conveniently be studied in tandem since RMSEA is based on an overall test statistic, such as C2. The results are illustrated with an empirical application to data from a large-scale educational survey.
FT-IR spectroscopy combined with DFT calculation to explore solvent effects of vinyl acetate
NASA Astrophysics Data System (ADS)
Chen, Yi; Zhang, Hui; Liu, Qing
The infrared vibration frequencies of vinyl acetate (VAc) in 18 different solvents were theoretically computed at Density Function Theory (DFT) B3LYP/6-311G* level based on Polarizable Continuum Model (PCM) and experimentally recorded by FT-IR spectroscopy. The solvent-induced long-range bulk electrostatic solvation free energies of VAc (ΔGelec) were calculated by the SMD model. The Cdbnd O stretching vibration frequencies of VAc were utilized as a measure of the chemical reactivities of the Cdbnd C group in VAc. The calculated and experimental Cdbnd O stretching vibration frequencies of VAc (νcal(Cdbnd O) and νexp(Cdbnd O)) were correlated with empirical solvent parameters including the KBM equation, the Swain equation and the linear solvation energy relationships (LSER). Through ab initio calculation, assignments of the two Cdbnd O absorption bands of VAc in alcohol solvents were achieved. The PCM, SMD and ab initio calculation offered supporting evidence to explain the FT-IR experimental observations from differing aspects.
NASA Technical Reports Server (NTRS)
Kustas, William P.; Choudhury, Bhaskar J.; Kunkel, Kenneth E.
1989-01-01
Surface-air temperature differences are commonly used in a bulk resistance equation for estimating sensible heat flux (H), which is inserted in the one-dimensional energy balance equation to solve for the latent heat flux (LE) as a residual. Serious discrepancies between estimated and measured LE have been observed for partial-canopy-cover conditions, which are mainly attributed to inappropriate estimates of H. To improve the estimates of H over sparse canopies, one- and two-layer resistance models that account for some of the factors causing poor agreement are developed. The utility of the two models is tested with remotely sensed and micrometeorological data for a furrowed cotton field with 20 percent cover and a dry soil surface. It is found that the one-layer model performs better than the two-layer model when a theoretical bluff-body correction for heat transfer is used instead of an empirical adjustment; otherwise, the two-layer model is better.
Empirical Approach for Determining Axial Strength of Circular Concrete Filled Steel Tubular Columns
NASA Astrophysics Data System (ADS)
Jayalekshmi, S.; Jegadesh, J. S. Sankar; Goel, Abhishek
2018-03-01
The concrete filled steel tubular (CFST) columns are highly regarded in recent years as an interesting option in the construction field by designers and structural engineers, due to their exquisite structural performance, with enhanced load bearing capacity and energy absorption capacity. This study presents a new approach to simulate the capacity of circular CFST columns under axial loading condition, using a large database of experimental results by applying artificial neural network (ANN). A well trained network is established and is used to simulate the axial capacity of CFST columns. The validation and testing of the ANN is carried out. The current study is focused on proposing a simplified equation that can predict the ultimate strength of the axially loaded columns with high level of accuracy. The predicted results are compared with five existing analytical models which estimate the strength of the CFST column. The ANN-based equation has good prediction with experimental data, when compared with the analytical models.
Construct validity of the Moral Development Scale for Professionals (MDSP)
Söderhamn, Olle; Bjørnestad, John Olav; Skisland, Anne; Cliffordson, Christina
2011-01-01
The aim of this study was to investigate the construct validity of the Moral Development Scale for Professionals (MDSP) using structural equation modeling. The instrument is a 12-item self-report instrument, developed in the Scandinavian cultural context and based on Kohlberg’s theory. A hypothesized simplex structure model underlying the MDSP was tested through structural equation modeling. Validity was also tested as the proportion of respondents older than 20 years that reached the highest moral level, which according to the theory should be small. A convenience sample of 339 nursing students with a mean age of 25.3 years participated. Results confirmed the simplex model structure, indicating that MDSP reflects a moral construct empirically organized from low to high. A minority of respondents >20 years of age (13.5%) scored more than 80% on the highest moral level. The findings support the construct validity of the MDSP and the stages and levels in Kohlberg’s theory. PMID:21655343
Guerrin, F; Dumas, J
2001-02-01
This work aims at representing empirical knowledge of freshwater ecologists on the functioning of salmon redds (spawning areas of salmon) and its impact on mortality of early stages. For this, we use Qsim, a qualitative simulator. In this first part, we provide unfamiliar readers with the underlying qualitative differential equation (QDE) ontology of Qsim: representing quantities, qualitative variables, qualitative constraints, QDE structure. Based on a very simple example taken of the salmon redd application, we show how informal biological knowledge may be represented and simulated using an approach that was first intended to analyze qualitatively ordinary differential equations systems. A companion paper (Part II) gives the full description and simulation of the salmon redd qualitative model. This work was part of a project aimed at assessing the impact of the environment on salmon populations dynamics by the use of models of processes acting at different levels: catchment, river, and redds. Only the latter level is dealt with in this paper.
Single wall penetration equations
NASA Technical Reports Server (NTRS)
Hayashida, K. B.; Robinson, J. H.
1991-01-01
Five single plate penetration equations are compared for accuracy and effectiveness. These five equations are two well-known equations (Fish-Summers and Schmidt-Holsapple), two equations developed by the Apollo project (Rockwell and Johnson Space Center (JSC), and one recently revised from JSC (Cour-Palais). They were derived from test results, with velocities ranging up to 8 km/s. Microsoft Excel software was used to construct a spreadsheet to calculate the diameters and masses of projectiles for various velocities, varying the material properties of both projectile and target for the five single plate penetration equations. The results were plotted on diameter versus velocity graphs for ballistic and spallation limits using Cricket Graph software, for velocities ranging from 2 to 15 km/s defined for the orbital debris. First, these equations were compared to each other, then each equation was compared with various aluminum projectile densities. Finally, these equations were compared with test results performed at JSC for the Marshall Space Flight Center. These equations predict a wide variety of projectile diameters at a given velocity. Thus, it is very difficult to choose the 'right' prediction equation. The thickness of a single plate could have a large variation by choosing a different penetration equation. Even though all five equations are empirically developed with various materials, especially for aluminum alloys, one cannot be confident in the shield design with the predictions obtained by the penetration equations without verifying by tests.
2007-12-14
society.” Sigmund Freud (1927, p.7) -The basic idea that will be developed in this essay is that a symbolic equation is unconsciously made between acts...and criminology literature, this model has weak logical, theoretical, and empirical foundations. -The enemy that we see, according to Freud , is
ERIC Educational Resources Information Center
Barry, P. J.
Air flow in the neighborhood of buildings is briefly described and compared with that assumed for the usual atmospheric diffusion equations. The literature is reviewed and empirical formulae which have been proposed are listed and compared. (RH)
Thermodynamics of Oligonucleotide Duplex Melting
ERIC Educational Resources Information Center
Schreiber-Gosche, Sherrie; Edwards, Robert A.
2009-01-01
Melting temperatures of oligonucleotides are useful for a number of molecular biology applications, such as the polymerase chain reaction (PCR). Although melting temperatures are often calculated with simplistic empirical equations, application of thermodynamics provides more accurate melting temperatures and an opportunity for students to apply…
NASA Astrophysics Data System (ADS)
Reaver, N.; Kaplan, D. A.; Jawitz, J. W.
2017-12-01
The Budyko hypothesis states that a catchment's long-term water and energy balances are dependent on two relatively easy to measure quantities: rainfall depth and potential evaporation. This hypothesis is expressed as a simple function, the Budyko equation, which allows for the prediction of a catchment's actual evapotranspiration and discharge from measured rainfall depth and potential evaporation, data which are widely available. However, the two main analytically derived forms of the Budyko equation contain a single unknown watershed parameter, whose value varies across catchments; variation in this parameter has been used to explain the hydrological behavior of different catchments. The watershed parameter is generally thought of as a lumped quantity that represents the influence of all catchment biophysical features (e.g. soil type and depth, vegetation type, timing of rainfall, etc). Previous work has shown that the parameter is statistically correlated with catchment properties, but an explicit expression has been elusive. While the watershed parameter can be determined empirically by fitting the Budyko equation to measured data in gauged catchments where actual evapotranspiration can be estimated, this limits the utility of the framework for predicting impacts to catchment hydrology due to changing climate and land use. In this study, we developed an analytical solution for the lumped catchment parameter for both forms of the Budyko equation. We combined these solutions with a statistical soil moisture model to obtain analytical solutions for the Budyko equation parameter as a function of measurable catchment physical features, including rooting depth, soil porosity, and soil wilting point. We tested the predictive power of these solutions using the U.S. catchments in the MOPEX database. We also compared the Budyko equation parameter estimates generated from our analytical solutions (i.e. predicted parameters) with those obtained through the calibration of the Budyko equation to discharge data (i.e. empirical parameters), and found good agreement. These results suggest that it is possible to predict the Budyko equation watershed parameter directly from physical features, even for ungauged catchments.
Soil roughness, slope and surface storage relationship for impervious areas
NASA Astrophysics Data System (ADS)
Borselli, Lorenzo; Torri, Dino
2010-11-01
SummaryThe study of the relationships between surface roughness, local slope gradient and maximum volume of water storage in surface depressions is a fundamental element in the development of hydrological models to be used in soil and water conservation strategies. Good estimates of the maximum volume of water storage are important for runoff assessment during rainfall events. Some attempts to link surface storage to parameters such as indices of surface roughness and, more rarely, local gradient have been proposed by several authors with empirical equations often conflicting between them and usually based on a narrow range of slope gradients. This suggests care in selecting any of the proposed equations or models and invites one to verify the existence of more realistic experimental relationships, based on physical models of the surfaces and valid for a larger range of gradients. The aim of this study is to develop such a relation for predicting/estimating the maximum volume of water that a soil surface, with given roughness characteristics and local slope gradient, can store. Experimental work has been carried out in order to reproduce reliable rough surfaces able to maintain the following properties during the experimental activity: (a) impervious surface to avoid biased storage determination; (b) stable, un-erodible surfaces to avoid changes of retention volume during tests; (c) absence of hydrophobic behaviour. To meet the conditions a-c we generate physical surfaces with various roughness magnitude using plasticine (emulsion of non-expansible clay and oil). The plasticine surface, reproducing surfaces of arable soils, was then wetted and dirtied with a very fine timber sawdust. This reduced the natural hydrophobic behaviour of the plasticine to an undetectable value. Storage experiments were conducted with plasticine rough surfaces on top of large rigid polystyrene plates inclined at different slope gradient: 2%, 5%, 10%, 20%, 30%. Roughness data collected on the generated plasticine surfaces were successfully compared with roughness data collected on real soil surfaces for similar conditions. A set of roughness indices was computed for each surface using roughness profiles measured with a laser profile meter. Roughness indices included quantiles of the Abbot-Firestone curve, which is used in surface metrology for industrial application to characterize surface roughness in a non-parametric approach ( Whitehouse, 1994). Storage data were fitted with an empirical equation (double negative exponential of roughness and slope). Several roughness indices resulted well related to storage. The better results were obtained using the Abbot-Firestone curve parameter P100. Beside this storage empirical model (SEM) a geometrical model was also developed, trying to give a more physical basis to the result obtained so far. Depression geometry was approximated with spherical cups. A general physical model was derived (storage cup model - SCM). The cup approximation identifies where roughness elevation comes in and how it relates to slope gradient in defining depression volume. Moreover, the exponential decay used for assessing slope effect on storage volume in the empirical model of Eqs. (8) and (9) emerges as consistent with distribution of cup sizes.
Synoptic, Global Mhd Model For The Solar Corona
NASA Astrophysics Data System (ADS)
Cohen, Ofer; Sokolov, I. V.; Roussev, I. I.; Gombosi, T. I.
2007-05-01
The common techniques for mimic the solar corona heating and the solar wind acceleration in global MHD models are as follow. 1) Additional terms in the momentum and energy equations derived from the WKB approximation for the Alfv’en wave turbulence; 2) some empirical heat source in the energy equation; 3) a non-uniform distribution of the polytropic index, γ, used in the energy equation. In our model, we choose the latter approach. However, in order to get a more realistic distribution of γ, we use the empirical Wang-Sheeley-Arge (WSA) model to constrain the MHD solution. The WSA model provides the distribution of the asymptotic solar wind speed from the potential field approximation; therefore it also provides the distribution of the kinetic energy. Assuming that far from the Sun the total energy is dominated by the energy of the bulk motion and assuming the conservation of the Bernoulli integral, we can trace the total energy along a magnetic field line to the solar surface. On the surface the gravity is known and the kinetic energy is negligible. Therefore, we can get the surface distribution of γ as a function of the final speed originating from this point. By interpolation γ to spherically uniform value on the source surface, we use this spatial distribution of γ in the energy equation to obtain a self-consistent, steady state MHD solution for the solar corona. We present the model result for different Carrington Rotations.
Dynamical stochastic processes of returns in financial markets
NASA Astrophysics Data System (ADS)
Lim, Gyuchang; Kim, SooYong; Yoon, Seong-Min; Jung, Jae-Won; Kim, Kyungsik
2007-03-01
We study the evolution of probability distribution functions of returns, from the tick data of the Korean treasury bond (KTB) futures and the S&P 500 stock index, which can be described by means of the Fokker-Planck equation. We show that the Fokker-Planck equation and the Langevin equation from the estimated Kramers-Moyal coefficients can be estimated directly from the empirical data. By analyzing the statistics of the returns, we present quantitatively the deterministic and random influences on financial time series for both markets, for which we can give a simple physical interpretation. We particularly focus on the diffusion coefficient, which may be important for the creation of a portfolio.
On the effects of nonlinear boundary conditions in diffusive logistic equations on bounded domains
NASA Astrophysics Data System (ADS)
Cantrell, Robert Stephen; Cosner, Chris
We study a diffusive logistic equation with nonlinear boundary conditions. The equation arises as a model for a population that grows logistically inside a patch and crosses the patch boundary at a rate that depends on the population density. Specifically, the rate at which the population crosses the boundary is assumed to decrease as the density of the population increases. The model is motivated by empirical work on the Glanville fritillary butterfly. We derive local and global bifurcation results which show that the model can have multiple equilibria and in some parameter ranges can support Allee effects. The analysis leads to eigenvalue problems with nonstandard boundary conditions.
NASA Technical Reports Server (NTRS)
Wang, Qun-Zhen; Massey, Steven J.; Abdol-Hamid, Khaled S.; Frink, Neal T.
1999-01-01
USM3D is a widely-used unstructured flow solver for simulating inviscid and viscous flows over complex geometries. The current version (version 5.0) of USM3D, however, does not have advanced turbulence models to accurately simulate complicated flows. We have implemented two modified versions of the original Jones and Launder k-epsilon two-equation turbulence model and the Girimaji algebraic Reynolds stress model in USM3D. Tests have been conducted for two flat plate boundary layer cases, a RAE2822 airfoil and an ONERA M6 wing. The results are compared with those of empirical formulae, theoretical results and the existing Spalart-Allmaras one-equation model.
Renormalization of the fragmentation equation: Exact self-similar solutions and turbulent cascades
NASA Astrophysics Data System (ADS)
Saveliev, V. L.; Gorokhovski, M. A.
2012-12-01
Using an approach developed earlier for renormalization of the Boltzmann collision integral [Saveliev and Nanbu, Phys. Rev. E1539-375510.1103/PhysRevE.65.051205 65, 051205 (2002)], we derive an exact divergence form for the fragmentation operator. Then we reduce the fragmentation equation to the continuity equation in size space, with the flux given explicitly. This allows us to obtain self-similar solutions and to find the integral of motion for these solutions (we call it the bare flux). We show how these solutions can be applied as a description of cascade processes in three- and two-dimensional turbulence. We also suggested an empirical cascade model of impact fragmentation of brittle materials.
Prediction of distribution coefficient from structure. 1. Estimation method.
Csizmadia, F; Tsantili-Kakoulidou, A; Panderi, I; Darvas, F
1997-07-01
A method has been developed for the estimation of the distribution coefficient (D), which considers the microspecies of a compound. D is calculated from the microscopic dissociation constants (microconstants), the partition coefficients of the microspecies, and the counterion concentration. A general equation for the calculation of D at a given pH is presented. The microconstants are calculated from the structure using Hammett and Taft equations. The partition coefficients of the ionic microspecies are predicted by empirical equations using the dissociation constants and the partition coefficient of the uncharged species, which are estimated from the structure by a Linear Free Energy Relationship method. The algorithm is implemented in a program module called PrologD.
Network Reconstruction From High-Dimensional Ordinary Differential Equations.
Chen, Shizhe; Shojaie, Ali; Witten, Daniela M
2017-01-01
We consider the task of learning a dynamical system from high-dimensional time-course data. For instance, we might wish to estimate a gene regulatory network from gene expression data measured at discrete time points. We model the dynamical system nonparametrically as a system of additive ordinary differential equations. Most existing methods for parameter estimation in ordinary differential equations estimate the derivatives from noisy observations. This is known to be challenging and inefficient. We propose a novel approach that does not involve derivative estimation. We show that the proposed method can consistently recover the true network structure even in high dimensions, and we demonstrate empirical improvement over competing approaches. Supplementary materials for this article are available online.
NASA Astrophysics Data System (ADS)
Felix, D.; Abgottspon, A.; Albayrak, I.; Boes, R. M.
2016-11-01
At medium- and high-head hydropower plants (HPPs) on sediment-laden rivers, hydro-abrasive erosion on hydraulic turbines is a major economic issue. For optimization of such HPPs, there is an interest in equations to predict erosion depths. Such a semi-empirical equation suitable for engineering practice is proposed in the relevant guideline of the International Electrotechnical Commission (IEC 62364). However, for Pelton turbines no numerical values of the model's calibration parameters have been available yet. In the scope of a research project at the high-head HPP Fieschertal, Switzerland, the particle load and the erosion on the buckets of two hard-coated 32 MW-Pelton runners have been measured since 2012. Based on three years of field data, the numerical values of a group of calibration parameters of the IEC erosion model were determined for five application cases: (i) reduction of splitter height, (ii) increase of splitter width and (iii) increase of cut-out depth due to erosion of mainly base material, as well as erosion of coating on (iv) the splitter crests and (v) inside the buckets. Further laboratory and field investigations are recommended to quantify the effects of individual parameters as well as to improve, generalize and validate erosion models for uncoated and coated Pelton turbines.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Buzakuk, M.R.
1988-01-01
This study explores the determinants of foreign reserves flow in light of the oil-based small open economies of Libya, Kuwait, and Saudi Arabia. The period of study encompasses the major oil price increases of the 1970s and early 1980s, which had led to the huge transfers of foreign exchanges towards these, among other, developing economies. The framework of analysis is basically a monetary approach to the balance of payments. This study is of both a theoretical and empirical nature. It utilizes the monetary forces in the domestic money market to derive a basic balance of payments (BOP) equation that explainsmore » the monetary nature of the balance of payments. The study found that the data from those countries support the monetary relationships as hypothesized by the monetary approach, especially the negative one-to-one relation between domestic credit (DC) and the BOP. Results from the simultaneous estimations of the BOP and DC reported better estimates than the single-equation model. Findings from the reaction function indicated that the monetary authorities of these oil-based economies were actively sterilizing the effect of foreign reserve flows. Findings supported the integrated market hypothesis in Kuwait and Libya, but not in the Saudi case.« less
Dlubac, Katherine; Knight, Rosemary; Song, Yi-Qiao; Bachman, Nate; Grau, Ben; Cannia, Jim; Williams, John
2013-01-01
Hydraulic conductivity (K) is one of the most important parameters of interest in groundwater applications because it quantifies the ease with which water can flow through an aquifer material. Hydraulic conductivity is typically measured by conducting aquifer tests or wellbore flow (WBF) logging. Of interest in our research is the use of proton nuclear magnetic resonance (NMR) logging to obtain information about water-filled porosity and pore space geometry, the combination of which can be used to estimate K. In this study, we acquired a suite of advanced geophysical logs, aquifer tests, WBF logs, and sidewall cores at the field site in Lexington, Nebraska, which is underlain by the High Plains aquifer. We first used two empirical equations developed for petroleum applications to predict K from NMR logging data: the Schlumberger Doll Research equation (KSDR) and the Timur-Coates equation (KT-C), with the standard empirical constants determined for consolidated materials. We upscaled our NMR-derived K estimates to the scale of the WBF-logging K(KWBF-logging) estimates for comparison. All the upscaled KT-C estimates were within an order of magnitude of KWBF-logging and all of the upscaled KSDR estimates were within 2 orders of magnitude of KWBF-logging. We optimized the fit between the upscaled NMR-derived K and KWBF-logging estimates to determine a set of site-specific empirical constants for the unconsolidated materials at our field site. We conclude that reliable estimates of K can be obtained from NMR logging data, thus providing an alternate method for obtaining estimates of K at high levels of vertical resolution.
NASA Astrophysics Data System (ADS)
Kim, Jongho; Ivanov, Valeriy Y.; Katopodes, Nikolaos D.
2013-09-01
A novel two-dimensional, physically based model of soil erosion and sediment transport coupled to models of hydrological and overland flow processes has been developed. The Hairsine-Rose formulation of erosion and deposition processes is used to account for size-selective sediment transport and differentiate bed material into original and deposited soil layers. The formulation is integrated within the framework of the hydrologic and hydrodynamic model tRIBS-OFM, Triangulated irregular network-based, Real-time Integrated Basin Simulator-Overland Flow Model. The integrated model explicitly couples the hydrodynamic formulation with the advection-dominated transport equations for sediment of multiple particle sizes. To solve the system of equations including both the Saint-Venant and the Hairsine-Rose equations, the finite volume method is employed based on Roe's approximate Riemann solver on an unstructured grid. The formulation yields space-time dynamics of flow, erosion, and sediment transport at fine scale. The integrated model has been successfully verified with analytical solutions and empirical data for two benchmark cases. Sensitivity tests to grid resolution and the number of used particle sizes have been carried out. The model has been validated at the catchment scale for the Lucky Hills watershed located in southeastern Arizona, USA, using 10 events for which catchment-scale streamflow and sediment yield data were available. Since the model is based on physical laws and explicitly uses multiple types of watershed information, satisfactory results were obtained. The spatial output has been analyzed and the driving role of topography in erosion processes has been discussed. It is expected that the integrated formulation of the model has the promise to reduce uncertainties associated with typical parameterizations of flow and erosion processes. A potential for more credible modeling of earth-surface processes is thus anticipated.
Strengthening safety compliance in nuclear power operations: a role-based approach.
Martínez-Córcoles, Mario; Gracia, Francisco J; Tomás, Inés; Peiró, José M
2014-07-01
Safety compliance is of paramount importance in guaranteeing the safe running of nuclear power plants. However, it depends mostly on procedures that do not always involve the safest outcomes. This article introduces an empirical model based on the organizational role theory to analyze the influence of legitimate sources of expectations (procedures formalization and leadership) on workers' compliance behaviors. The sample was composed of 495 employees from two Spanish nuclear power plants. Structural equation analysis showed that, in spite of some problematic effects of proceduralization (such as role conflict and role ambiguity), procedure formalization along with an empowering leadership style lead to safety compliance by clarifying a worker's role in safety. Implications of these findings for safety research are outlined, as well as their practical implications. © 2014 Society for Risk Analysis.
Geometric Model of Induction Heating Process of Iron-Based Sintered Materials
NASA Astrophysics Data System (ADS)
Semagina, Yu V.; Egorova, M. A.
2018-03-01
The article studies the issue of building multivariable dependences based on the experimental data. A constructive method for solving the issue is presented in the form of equations of (n-1) – surface compartments of the extended Euclidean space E+n. The dimension of space is taken to be equal to the sum of the number of parameters and factors of the model of the system being studied. The basis for building multivariable dependencies is the generalized approach to n-space used for the surface compartments of 3D space. The surface is designed on the basis of the kinematic method, moving one geometric object along a certain trajectory. The proposed approach simplifies the process aimed at building the multifactorial empirical dependencies which describe the process being investigated.
Comparison of the secondary electrons produced by proton and electron beams in water
NASA Astrophysics Data System (ADS)
Kia, Mohammad Reza; Noshad, Houshyar
2016-05-01
The secondary electrons produced in water by electron and proton beams are compared with each other. The total ionization cross section (TICS) for an electron impact in water is obtained by using the binary-encounter-Bethe model. Hence, an empirical equation based on two adjustable fitting parameters is presented to determine the TICS for proton impact in media. In order to calculate the projectile trajectory, a set of stochastic differential equations based on the inelastic collision, elastic scattering, and bremsstrahlung emission are used. In accordance with the projectile trajectory, the depth dose deposition, electron energy loss distribution in a certain depth, and secondary electrons produced in water are calculated. The obtained results for the depth dose deposition and energy loss distribution in certain depth for electron and proton beams with various incident energies in media are in excellent agreement with the reported experimental data. The difference between the profiles for the depth dose deposition and production of secondary electrons for a proton beam can be ignored approximately. But, these profiles for an electron beam are completely different due to the effect of elastic scattering on electron trajectory.
Comparison of the secondary electrons produced by proton and electron beams in water
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kia, Mohammad Reza, E-mail: m-r-kia@aut.ac.ir; Noshad, Houshyar
The secondary electrons produced in water by electron and proton beams are compared with each other. The total ionization cross section (TICS) for an electron impact in water is obtained by using the binary-encounter-Bethe model. Hence, an empirical equation based on two adjustable fitting parameters is presented to determine the TICS for proton impact in media. In order to calculate the projectile trajectory, a set of stochastic differential equations based on the inelastic collision, elastic scattering, and bremsstrahlung emission are used. In accordance with the projectile trajectory, the depth dose deposition, electron energy loss distribution in a certain depth, andmore » secondary electrons produced in water are calculated. The obtained results for the depth dose deposition and energy loss distribution in certain depth for electron and proton beams with various incident energies in media are in excellent agreement with the reported experimental data. The difference between the profiles for the depth dose deposition and production of secondary electrons for a proton beam can be ignored approximately. But, these profiles for an electron beam are completely different due to the effect of elastic scattering on electron trajectory.« less
A method for obtaining a statistically stationary turbulent free shear flow
NASA Technical Reports Server (NTRS)
Timson, Stephen F.; Lele, S. K.; Moser, R. D.
1994-01-01
The long-term goal of the current research is the study of Large-Eddy Simulation (LES) as a tool for aeroacoustics. New algorithms and developments in computer hardware are making possible a new generation of tools for aeroacoustic predictions, which rely on the physics of the flow rather than empirical knowledge. LES, in conjunction with an acoustic analogy, holds the promise of predicting the statistics of noise radiated to the far-field of a turbulent flow. LES's predictive ability will be tested through extensive comparison of acoustic predictions based on a Direct Numerical Simulation (DNS) and LES of the same flow, as well as a priori testing of DNS results. The method presented here is aimed at allowing simulation of a turbulent flow field that is both simple and amenable to acoustic predictions. A free shear flow is homogeneous in both the streamwise and spanwise directions and which is statistically stationary will be simulated using equations based on the Navier-Stokes equations with a small number of added terms. Studying a free shear flow eliminates the need to consider flow-surface interactions as an acoustic source. The homogeneous directions and the flow's statistically stationary nature greatly simplify the application of an acoustic analogy.
Population entropies estimates of proteins
NASA Astrophysics Data System (ADS)
Low, Wai Yee
2017-05-01
The Shannon entropy equation provides a way to estimate variability of amino acids sequences in a multiple sequence alignment of proteins. Knowledge of protein variability is useful in many areas such as vaccine design, identification of antibody binding sites, and exploration of protein 3D structural properties. In cases where the population entropies of a protein are of interest but only a small sample size can be obtained, a method based on linear regression and random subsampling can be used to estimate the population entropy. This method is useful for comparisons of entropies where the actual sequence counts differ and thus, correction for alignment size bias is needed. In the current work, an R based package named EntropyCorrect that enables estimation of population entropy is presented and an empirical study on how well this new algorithm performs on simulated dataset of various combinations of population and sample sizes is discussed. The package is available at https://github.com/lloydlow/EntropyCorrect. This article, which was originally published online on 12 May 2017, contained an error in Eq. (1), where the summation sign was missing. The corrected equation appears in the Corrigendum attached to the pdf.
Prediction of blast-induced air overpressure: a hybrid AI-based predictive model.
Jahed Armaghani, Danial; Hajihassani, Mohsen; Marto, Aminaton; Shirani Faradonbeh, Roohollah; Mohamad, Edy Tonnizam
2015-11-01
Blast operations in the vicinity of residential areas usually produce significant environmental problems which may cause severe damage to the nearby areas. Blast-induced air overpressure (AOp) is one of the most important environmental impacts of blast operations which needs to be predicted to minimize the potential risk of damage. This paper presents an artificial neural network (ANN) optimized by the imperialist competitive algorithm (ICA) for the prediction of AOp induced by quarry blasting. For this purpose, 95 blasting operations were precisely monitored in a granite quarry site in Malaysia and AOp values were recorded in each operation. Furthermore, the most influential parameters on AOp, including the maximum charge per delay and the distance between the blast-face and monitoring point, were measured and used to train the ICA-ANN model. Based on the generalized predictor equation and considering the measured data from the granite quarry site, a new empirical equation was developed to predict AOp. For comparison purposes, conventional ANN models were developed and compared with the ICA-ANN results. The results demonstrated that the proposed ICA-ANN model is able to predict blast-induced AOp more accurately than other presented techniques.
Equation of State for Gaseous Products of Detonation
NASA Astrophysics Data System (ADS)
Rightley, Maria
1998-11-01
There have been many equations of state (EOS) proposed for gaseous products of detonation, from simple theoretically-based EOS to empirically-based EOS with many adjustable parameters. How well these EOS approximate the real behavior depends on the material which is detonated. Gases, for example, are much easier to represent simply than are condensed or solid materials. If we concentrate solely on the particular class of condensed materials known as high explosives (HE) and their products of detonation, the most common formulation is the Jones-Wilkins-Lee (JWL) EOS. It has six adjustable parameters, and is as popular as it is in some part due to the fact that it can represent well the experiments which are primary source for HE EOS data, the explosive cylinder test. This test uses a cylinder of copper filled with an HE, which is then initiated, and the expansion is recorded. The obtained expansion profile is then used to calibrate the EOS, generally the JWL form. The work presented here will describe the rereading of some old film data, as well as recalibration of that data for the JWL EOS, and progress with modified EOS forms.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Dennis, J.S.; Hayhurst, A.N.; Scott, S.A.
Particles of char derived from a variety of fuels (e.g., biomass, sewage sludge, coal, or graphite), with diameters in excess of {approx}1.5mm, burn in fluidized bed combustors containing smaller particles of, e.g., sand, such that the rate is controlled by the diffusion both of O{sub 2} to the burning solid and of the products CO and CO{sub 2} away from it into the particulate phase. It is therefore important to characterize these mass transfer processes accurately. Measurements of the burning rate of char particles made from sewage sludge suggest that the Sherwood number, Sh, increases linearly with the diameter ofmore » the fuel particle, d{sub char} (for d{sub char}>{approx}1.5mm). This linear dependence of Sh on d{sub char} is expected from the basic equation Sh=2{epsilon}{sub mf}(1+d{sub char}/2{delta}{sub diff})/{tau}, provided the thickness of the boundary layer for mass transfer, {delta}{sub diff}, is constant in the region of interest (d{sub char}>{approx}1.5mm). Such a dependence is not seen in the empirical equations currently used and based on the Frossling expression. It is found here that for chars made from sewage sludge (for d{sub char}>{approx}1.5mm), the thickness of the boundary layer for mass transfer in a fluidized bed, {delta}{sub diff}, is less than that predicted by empirical correlations based on the Frossling expression. In fact, {delta}{sub diff} is not more than the diameter of the fluidized sand particles. Finally, the experiments in this study indicate that models based on surface renewal theory should be rejected for a fluidized bed, because they give unrealistically short contact times for packets of fluidized particles at the surface of a burning sphere. The result is the new correlation Sh = 2{epsilon}{sub mf}/{tau} + (A{sub cush}/A{sub char})(d{sub char}/ {delta}{sub diff}) for the dependence of Sh on d{sub char}, the diameter of a burning char particle. This equation is based on there being a gas-cushion of fluidizing gas underneath a burning char particle; the implication of this correlation is that a completely new picture emerges for the combustion of a char particle in a hot fluidized bed. (author)« less
Erbe, Malena; Gredler, Birgit; Seefried, Franz Reinhold; Bapst, Beat; Simianer, Henner
2013-01-01
Prediction of genomic breeding values is of major practical relevance in dairy cattle breeding. Deterministic equations have been suggested to predict the accuracy of genomic breeding values in a given design which are based on training set size, reliability of phenotypes, and the number of independent chromosome segments ([Formula: see text]). The aim of our study was to find a general deterministic equation for the average accuracy of genomic breeding values that also accounts for marker density and can be fitted empirically. Two data sets of 5'698 Holstein Friesian bulls genotyped with 50 K SNPs and 1'332 Brown Swiss bulls genotyped with 50 K SNPs and imputed to ∼600 K SNPs were available. Different k-fold (k = 2-10, 15, 20) cross-validation scenarios (50 replicates, random assignment) were performed using a genomic BLUP approach. A maximum likelihood approach was used to estimate the parameters of different prediction equations. The highest likelihood was obtained when using a modified form of the deterministic equation of Daetwyler et al. (2010), augmented by a weighting factor (w) based on the assumption that the maximum achievable accuracy is [Formula: see text]. The proportion of genetic variance captured by the complete SNP sets ([Formula: see text]) was 0.76 to 0.82 for Holstein Friesian and 0.72 to 0.75 for Brown Swiss. When modifying the number of SNPs, w was found to be proportional to the log of the marker density up to a limit which is population and trait specific and was found to be reached with ∼20'000 SNPs in the Brown Swiss population studied.
Study of Parameters And Methods of LL-Ⅳ Distributed Hydrological Model in DMIP2
NASA Astrophysics Data System (ADS)
Li, L.; Wu, J.; Wang, X.; Yang, C.; Zhao, Y.; Zhou, H.
2008-05-01
: The Physics-based distributed hydrological model is considered as an important developing period from the traditional experience-hydrology to the physical hydrology. The Hydrology Laboratory of the NOAA National Weather Service proposes the first and second phase of the Distributed Model Intercomparison Project (DMIP),that it is a great epoch-making work. LL distributed hydrological model has been developed to the fourth generation since it was established in 1997 on the Fengman-I district reservoir area (11000 km2).The LL-I distributed hydrological model was born with the applications of flood control system in the Fengman-I in China. LL-II was developed under the DMIP-I support, it is combined with GIS, RS, GPS, radar rainfall measurement.LL-III was established along with Applications of LL Distributed Model on Water Resources which was supported by the 973-projects of The Ministry of Science and Technology of the People's Republic of China. LL-Ⅳ was developed to face China's water problem. Combined with Blue River and the Baron Fork River basin of DMIP-II, the convection-diffusion equation of non-saturated and saturated seepage was derived from the soil water dynamics and continuous equation. In view of the technical characteristics of the model, the advantage of using convection-diffusion equation to compute confluence overall is longer period of predictable, saving memory space, fast budgeting, clear physical concepts, etc. The determination of parameters of hydrological model is the key, including experience coefficients and parameters of physical parameters. There are methods of experience, inversion, and the optimization to determine the model parameters, and each has advantages and disadvantages. This paper briefly introduces the LL-Ⅳ distribution hydrological model equations, and particularly introduces methods of parameters determination and simulation results on Blue River and Baron Fork River basin for DMIP-II. The soil moisture diffusion coefficient and coefficient of hydraulic conductivity are involved all through the LL-Ⅳ distribution of runoff and slope convergence model, used mainly empirical formula to determine. It's used optimization methods to calculate the two parameters of evaporation capacity (coefficient of bare land and vegetation land), two parameters of interception and wave velocity of Overland Flow, interflow and groundwater. The approach of determining wave velocity of River Network confluence and diffusion coefficient is: 1. Estimate roughness based mainly on digital information such as land use, soil texture, etc. 2.Establish the empirical formula. Another method is called convection-diffusion numerical inversion.
NASA Astrophysics Data System (ADS)
Pitts, James Daniel
Rotary ultrasonic machining (RUM), a hybrid process combining ultrasonic machining and diamond grinding, was created to increase material removal rates for the fabrication of hard and brittle workpieces. The objective of this research was to experimentally derive empirical equations for the prediction of multiple machined surface roughness parameters for helically pocketed rotary ultrasonic machined Zerodur glass-ceramic workpieces by means of a systematic statistical experimental approach. A Taguchi parametric screening design of experiments was employed to systematically determine the RUM process parameters with the largest effect on mean surface roughness. Next empirically determined equations for the seven common surface quality metrics were developed via Box-Behnken surface response experimental trials. Validation trials were conducted resulting in predicted and experimental surface roughness in varying levels of agreement. The reductions in cutting force and tool wear associated with RUM, reported by previous researchers, was experimentally verified to also extended to helical pocketing of Zerodur glass-ceramic.
Positive direct current corona discharges in single wire-duct electrostatic precipitators
DOE Office of Scientific and Technical Information (OSTI.GOV)
Yehia, Ashraf, E-mail: yehia30161@yahoo.com; Department of Physics, Faculty of Science, Assiut University, Assiut 71516, Arab Republic of Egypt; Abdel-Fattah, E.
This paper is aimed to study the characteristics of the positive dc corona discharges in single wire-duct electrostatic precipitators. Therefore, the corona discharges were formed inside dry air fed single wire-duct reactor under positive dc voltage at the normal atmospheric conditions. The corona current-voltage characteristics curves have been measured in parallel with the ozone concentration generated inside the reactor under different discharge conditions. The corona current-voltage characteristics curves have agreed with a semi empirical equation derived from the previous studies. The experimental results of the ozone concentration generated inside the reactor were formulated in the form of an empirical equationmore » included the different parameters that were studied experimentally. The obtained equations are valid to expect both the current-voltage characteristics curves and the corresponding ozone concentration that generates with the positive dc corona discharges inside single wire-duct electrostatic precipitators under any operating conditions in the same range of the present study.« less
Kanazawa, Kiyoshi; Sueshige, Takumi; Takayasu, Hideki; Takayasu, Misako
2018-03-30
A microscopic model is established for financial Brownian motion from the direct observation of the dynamics of high-frequency traders (HFTs) in a foreign exchange market. Furthermore, a theoretical framework parallel to molecular kinetic theory is developed for the systematic description of the financial market from microscopic dynamics of HFTs. We report first on a microscopic empirical law of traders' trend-following behavior by tracking the trajectories of all individuals, which quantifies the collective motion of HFTs but has not been captured in conventional order-book models. We next introduce the corresponding microscopic model of HFTs and present its theoretical solution paralleling molecular kinetic theory: Boltzmann-like and Langevin-like equations are derived from the microscopic dynamics via the Bogoliubov-Born-Green-Kirkwood-Yvon hierarchy. Our model is the first microscopic model that has been directly validated through data analysis of the microscopic dynamics, exhibiting quantitative agreements with mesoscopic and macroscopic empirical results.
Bruni, Aline Thaís; Velho, Jesus Antonio; Ferreira, Arthur Serra Lopes; Tasso, Maria Júlia; Ferrari, Raíssa Santos; Yoshida, Ricardo Luís; Dias, Marcos Salvador; Leite, Vitor Barbanti Pereira
2014-08-01
This study uses statistical techniques to evaluate reports on suicide scenes; it utilizes 80 reports from different locations in Brazil, randomly collected from both federal and state jurisdictions. We aimed to assess a heterogeneous group of cases in order to obtain an overall perspective of the problem. We evaluated variables regarding the characteristics of the crime scene, such as the detected traces (blood, instruments and clothes) that were found and we addressed the methodology employed by the experts. A qualitative approach using basic statistics revealed a wide distribution as to how the issue was addressed in the documents. We examined a quantitative approach involving an empirical equation and we used multivariate procedures to validate the quantitative methodology proposed for this empirical equation. The methodology successfully identified the main differences in the information presented in the reports, showing that there is no standardized method of analyzing evidences. Copyright © 2014 Elsevier Ltd and Faculty of Forensic and Legal Medicine. All rights reserved.
NASA Astrophysics Data System (ADS)
Kanazawa, Kiyoshi; Sueshige, Takumi; Takayasu, Hideki; Takayasu, Misako
2018-03-01
A microscopic model is established for financial Brownian motion from the direct observation of the dynamics of high-frequency traders (HFTs) in a foreign exchange market. Furthermore, a theoretical framework parallel to molecular kinetic theory is developed for the systematic description of the financial market from microscopic dynamics of HFTs. We report first on a microscopic empirical law of traders' trend-following behavior by tracking the trajectories of all individuals, which quantifies the collective motion of HFTs but has not been captured in conventional order-book models. We next introduce the corresponding microscopic model of HFTs and present its theoretical solution paralleling molecular kinetic theory: Boltzmann-like and Langevin-like equations are derived from the microscopic dynamics via the Bogoliubov-Born-Green-Kirkwood-Yvon hierarchy. Our model is the first microscopic model that has been directly validated through data analysis of the microscopic dynamics, exhibiting quantitative agreements with mesoscopic and macroscopic empirical results.
Gas Generator Feedline Orifice Sizing Methodology: Effects of Unsteadiness and Non-Axisymmetric Flow
NASA Technical Reports Server (NTRS)
Rothermel, Jeffry; West, Jeffrey S.
2011-01-01
Engine LH2 and LO2 gas generator feed assemblies were modeled with computational fluid dynamics (CFD) methods at 100% rated power level, using on-center square- and round-edge orifices. The purpose of the orifices is to regulate the flow of fuel and oxidizer to the gas generator, enabling optimal power supply to the turbine and pump assemblies. The unsteady Reynolds-Averaged Navier-Stokes equations were solved on unstructured grids at second-order spatial and temporal accuracy. The LO2 model was validated against published experimental data and semi-empirical relationships for thin-plate orifices over a range of Reynolds numbers. Predictions for the LO2 square- and round-edge orifices precisely match experiment and semi-empirical formulas, despite complex feedline geometry whereby a portion of the flow from the engine main feedlines travels at a right-angle through a smaller-diameter pipe containing the orifice. Predictions for LH2 square- and round-edge orifice designs match experiment and semi-empirical formulas to varying degrees depending on the semi-empirical formula being evaluated. LO2 mass flow rate through the square-edge orifice is predicted to be 25 percent less than the flow rate budgeted in the original engine balance, which was subsequently modified. LH2 mass flow rate through the square-edge orifice is predicted to be 5 percent greater than the flow rate budgeted in the engine balance. Since CFD predictions for LO2 and LH2 square-edge orifice pressure loss coefficients, K, both agree with published data, the equation for K has been used to define a procedure for orifice sizing.
Evaluating rainfall kinetic energy - intensity relationships with observed disdrometric data
NASA Astrophysics Data System (ADS)
Angulo-Martinez, Marta; Begueria, Santiago; Latorre, Borja
2016-04-01
Rainfall kinetic energy is required for determining erosivity, the ability of rainfall to detach soil particles and initiate erosion. Its determination relay on the use of disdrometers, i.e. devices capable of measuring the drop size distribution and velocity of falling raindrops. In the absence of such devices, rainfall kinetic energy is usually estimated with empirical expressions relating rainfall energy and intensity. We evaluated the performance of 14 rainfall energy equations in estimating one-minute rainfall energy and event total energy, in comparison with observed data from 821 rainfall episodes (more than 100 thousand one-minute observations) by means of an optical disdrometer. In addition, two sources of bias when using such relationships were evaluated: i) the influence of using theoretical terminal raindrop fall velocities instead of measured values; and ii) the influence of time aggregation (rainfall intensity data every 5-, 10-, 15-, 30-, and 60-minutes). Empirical relationships did a relatively good job when complete events were considered (R2 > 0.82), but offered poorer results for within-event (one-minute resolution) variation. Also, systematic biases where large for many equations. When raindrop size distribution was known, estimating the terminal fall velocities by empirical laws produced good results even at fine time resolution. The influence of time aggregation was very high in the estimated kinetic energy, although linear scaling may allow empirical correction. This results stress the importance of considering all these effects when rainfall energy needs to be estimated from more standard precipitation records. , and recommends the use of disdrometer data to locally determine rainfall kinetic energy.
Coupled latent differential equation with moderators: simulation and application.
Hu, Yueqin; Boker, Steve; Neale, Michael; Klump, Kelly L
2014-03-01
Latent differential equations (LDE) use differential equations to analyze time series data. Because of the recent development of this technique, some issues critical to running an LDE model remain. In this article, the authors provide solutions to some of these issues and recommend a step-by-step procedure demonstrated on a set of empirical data, which models the interaction between ovarian hormone cycles and emotional eating. Results indicated that emotional eating is self-regulated. For instance, when people do more emotional eating than normal, they will subsequently tend to decrease their emotional eating behavior. In addition, a sudden increase will produce a stronger tendency to decrease than will a slow increase. We also found that emotional eating is coupled with the cycle of the ovarian hormone estradiol, and the peak of emotional eating occurs after the peak of estradiol. The self-reported average level of negative affect moderates the frequency of eating regulation and the coupling strength between eating and estradiol. Thus, people with a higher average level of negative affect tend to fluctuate faster in emotional eating, and their eating behavior is more strongly coupled with the hormone estradiol. Permutation tests on these empirical data supported the reliability of using LDE models to detect self-regulation and a coupling effect between two regulatory behaviors. (c) 2014 APA, all rights reserved.
Refinement of Strut-and-Tie Model for Reinforced Concrete Deep Beams
Panjehpour, Mohammad; Chai, Hwa Kian; Voo, Yen Lei
2015-01-01
Deep beams are commonly used in tall buildings, offshore structures, and foundations. According to many codes and standards, strut-and-tie model (STM) is recommended as a rational approach for deep beam analyses. This research focuses on the STM recommended by ACI 318-11 and AASHTO LRFD and uses experimental results to modify the strut effectiveness factor in STM for reinforced concrete (RC) deep beams. This study aims to refine STM through the strut effectiveness factor and increase result accuracy. Six RC deep beams with different shear span to effective-depth ratios (a/d) of 0.75, 1.00, 1.25, 1.50, 1.75, and 2.00 were experimentally tested under a four-point bending set-up. The ultimate shear strength of deep beams obtained from non-linear finite element modeling and STM recommended by ACI 318-11 as well as AASHTO LRFD (2012) were compared with the experimental results. An empirical equation was proposed to modify the principal tensile strain value in the bottle-shaped strut of deep beams. The equation of the strut effectiveness factor from AASHTTO LRFD was then modified through the aforementioned empirical equation. An investigation on the failure mode and crack propagation in RC deep beams subjected to load was also conducted. PMID:26110268
A physically-based Mie–Gruneisen equation of state to determine hot spot temperature distributions
Kittell, David Erik; Yarrington, Cole Davis
2016-07-14
Here, a physically-based form of the Mie–Grüneisen equation of state (EOS) is derived for calculating 1d planar shock temperatures, as well as hot spot temperature distributions from heterogeneous impact simulations. This form utilises a multi-term Einstein oscillator model for specific heat, and is completely algebraic in terms of temperature, volume, an integrating factor, and the cold curve energy. Moreover, any empirical relation for the reference pressure and energy may be substituted into the equations via the use of a generalised reference function. The complete EOS is then applied to calculations of the Hugoniot temperature and simulation of hydrodynamic pore collapsemore » using data for the secondary explosive, hexanitrostilbene (HNS). From these results, it is shown that the choice of EOS is even more significant for determining hot spot temperature distributions than planar shock states. The complete EOS is also compared to an alternative derivation assuming that specific heat is a function of temperature alone, i.e. cv(T). Temperature discrepancies on the order of 100–600 K were observed corresponding to the shock pressures required to initiate HNS (near 10 GPa). Overall, the results of this work will improve confidence in temperature predictions. By adopting this EOS, future work may be able to assign physical meaning to other thermally sensitive constitutive model parameters necessary to predict the shock initiation and detonation of heterogeneous explosives.« less
A STATE-VARIABLE APPROACH FOR PREDICTING THE TIME REQUIRED FOR 50% RECRYSTALLIZATION
DOE Office of Scientific and Technical Information (OSTI.GOV)
M. STOUT; ET AL
2000-08-01
It is important to be able to model the recrystallization kinetics in aluminum alloys during hot deformation. The industrial relevant process of hot rolling is an example of where the knowledge of whether or not a material recrystallizes is critical to making a product with the correct properties. Classically, the equations that describe the kinetics of recrystallization predict the time to 50% recrystallization. These equations are largely empirical; they are based on the free energy for recrystallization, a Zener-Holloman parameter, and have several adjustable exponents to fit the equation to engineering data. We have modified this form of classical theorymore » replacing the Zener-Hollomon parameter with a deformation energy increment, a free energy available to drive recrystallization. The advantage of this formulation is that the deformation energy increment is calculated based on the previously determined temperature and strain-rate sensitivity of the constitutive response. We modeled the constitutive response of the AA5182 aluminum using a state variable approach, the value of the state variable is a function of the temperature and strain-rate history of deformation. Thus, the recrystallization kinetics is a function of only the state variable and free energy for recrystallization. There are no adjustable exponents as in classical theory. Using this approach combined with engineering recrystallization data we have been able to predict the kinetics of recrystallization in AA5182 as a function of deformation strain rate and temperature.« less
Changes in the lower boundary condition of water fluxes in the NOAH land surface scheme
NASA Astrophysics Data System (ADS)
Lohmann, D.; Peters-Lidard, C. D.
2002-05-01
One problem with current land surface schemes (LSS) used in weather prediction and climate models is their inabilty to reproduce streamflow in large river basins. This can be attributed to the weak representation of their upper (infiltration) and lower (baseflow) boundary conditions in their water balance / transport equations. Operational (traditional) hydrological models, which operate on the same spatial scale as a LSS, on the other hand, are able to reproduce streamflow time series. Their infiltration and baseflow equations are often empirically based and therefore have been neglected by the LSS community. It must be argued that we need to include a better representation of long time scales (as represented by groundwater and baseflow) into the current LSS to make valuable predictions of streamflow and water resources. This talk concentrates on the lower boundary condition of water fluxes within LSS. It reviews briefly previous attempts to incorporate groundwater and more realistic lower boundary conditions into LSS and summarizes the effect on the runoff (baseflow) production time scales as compared to currently used lower boundary conditions in LSS. The NOAH - LSM in the LDAS and DMIP setting is used to introduce a simplified groundwater model, based on the linearized Boussinesq equation, and the TOPMODEL. The NOAH - LSM will be coupled to a linear routing model to investigate the effects of the new lower boundary condition on the water balance (in particular, streamflow) in small to medium sized catchments in the LDAS / DMIP domain.
Adaptive Osher-type scheme for the Euler equations with highly nonlinear equations of state
NASA Astrophysics Data System (ADS)
Lee, Bok Jik; Toro, Eleuterio F.; Castro, Cristóbal E.; Nikiforakis, Nikolaos
2013-08-01
For the numerical simulation of detonation of condensed phase explosives, a complex equation of state (EOS), such as the Jones-Wilkins-Lee (JWL) EOS or the Cochran-Chan (C-C) EOS, are widely used. However, when a conservative scheme is used for solving the Euler equations with such equations of state, a spurious solution across the contact discontinuity, a well known phenomenon in multi-fluid systems, arises even for single materials. In this work, we develop a generalised Osher-type scheme in an adaptive primitive-conservative framework to overcome the aforementioned difficulties. Resulting numerical solutions are compared with the exact solutions and with the numerical solutions from the Godunov method in conjunction with the exact Riemann solver for the Euler equations with Mie-Grüneisen form of equations of state, such as the JWL and the C-C equations of state. The adaptive scheme is extended to second order and its empirical convergence rates are presented, verifying second order accuracy for smooth solutions. Through a suite of several tests problems in one and two space dimensions we illustrate the failure of conservative schemes and the capability of the methods of this paper to overcome the difficulties.
Thermal boundary layer due to sudden heating of fluid
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kurkal, K.R.; Munukutla, S.
This paper proposes to solve computationally the heat-transfer problems (introduced by Munukutla and Venkataraman, 1988) related to a closed-cycle pulsed high-power laser flow loop. The continuity and the momentum equations as well as the unsteady energy equation are solved using the Keller-Box method. The solutions were compared with the steady-state solutions at large times, and the comparison was found to be excellent. Empirical formulas are proposed for calculating the time-dependent boundary-layer thickness and mass-heat transfer, that can be used by laser flow loop designers. 6 refs.
Thermal boundary layer due to sudden heating of fluid
NASA Astrophysics Data System (ADS)
Kurkal, K. R.; Munukutla, S.
1989-10-01
This paper proposes to solve computationally the heat-transfer problems (introduced by Munukutla and Venkataraman, 1988) related to a closed-cycle pulsed high-power laser flow loop. The continuity and the momentum equations as well as the unsteady energy equation are solved using the Keller-Box method. The solutions were compared with the steady-state solutions at large times, and the comparison was found to be excellent. Empirical formulas are proposed for calculating the time-dependent boundary-layer thickness and mass-heat transfer, that can be used by laser flow loop designers.
NASA Astrophysics Data System (ADS)
Fritzsch, Robert; Kennedy, Mark W.; Aune, Ragnhild E.
2018-02-01
Special induction coils used for electro magnetic priming of ceramic foam filters in liquid metal filtration have been designed using a combination of analytical and finite element modeling. Relatively simple empirical equations published by Wheeler in 1928 and 1982 have been used during the design process. The equations were found to accurately predict the z-component of the magnetic flux densities of both single- and multi-layer coils as verified both experimentally and by using COMSOL® 5.1 multiphysics simulations.
Modeling of Kerena Emergency Condenser
NASA Astrophysics Data System (ADS)
Bryk, Rafał; Schmidt, Holger; Mull, Thomas; Wagner, Thomas; Ganzmann, Ingo; Herbst, Oliver
2017-12-01
KERENA is an innovative boiling water reactor concept equipped with several passive safety systems. For the experimental verification of performance of the systems and for codes validation, the Integral Test Stand Karlstein (INKA) was built in Karlstein, Germany. The emergency condenser (EC) system transfers heat from the reactor pressure vessel (RPV) to the core flooding pool in case of water level decrease in the RPV. EC is composed of a large number of slightly inclined tubes. During accident conditions, steam enters into the tubes and condenses due to the contact of the tubes with cold water at the secondary side. The condensed water flows then back to the RPV due to gravity. In this paper two approaches for modeling of condensation in slightly inclined tubes are compared and verified against experiments. The first approach is based on the flow regime map. Depending on the regime, heat transfer coefficient is calculated according to specific semi-empirical correlation. The second approach uses a general, fully-empirical correlation. The models are developed with utilization of the object-oriented Modelica language and the open-source OpenModelica environment. The results are compared with data obtained during a large scale integral test, simulating loss of coolant accident performed at Integral Test Stand Karlstein (INKA). The comparison shows a good agreement.Due to the modularity of models, both of them may be used in the future in systems incorporating condensation in horizontal or slightly inclined tubes. Depending on his preferences, the modeller may choose one-equation based approach or more sophisticated model composed of several exchangeable semi-empirical correlations.
ERIC Educational Resources Information Center
Stylianides, Andreas J.
2009-01-01
A proof's potential to promote understanding and conviction is one of the main reasons for which proof is so important for students' learning of mathematics. Unless students realise the limitations of empirical arguments as methods for validating mathematical generalisations, they are unlikely to appreciate the importance of proof in mathematics.…
Separating Cognitive and Content Domains in Mathematical Competence
ERIC Educational Resources Information Center
Harks, Birgit; Klieme, Eckhard; Hartig, Johannes; Leiss, Dominik
2014-01-01
The present study investigates the empirical separability of mathematical (a) content domains, (b) cognitive domains, and (c) content-specific cognitive domains. There were 122 items representing two content domains (linear equations vs. theorem of Pythagoras) combined with two cognitive domains (modeling competence vs. technical competence)…
The Structural Algebra Option: A Discussion Paper.
ERIC Educational Resources Information Center
Kirshner, David
The goal of this paper is to renew interest in the structural option to algebra instruction. Concern for the usual secondary school algebra curriculum related to simplifying expressions, solving equations, and rationalizing numerators and denominators is viewed from three pedagogical approaches: (1) structural approach, (2) empirical approach, and…
Design guidelines for an umbilical cord blood stem cell therapy quality assessment model
NASA Astrophysics Data System (ADS)
Januszewski, Witold S.; Michałek, Krzysztof; Yagensky, Oleksandr; Wardzińska, Marta
The paper enlists the pivotal guidelines for producing an empirical umbilical cord blood stem cell therapy quality assessment model. The methodology adapted was single equation linear model with domain knowledge derived from MEDAFAR classification. The resulting model is ready for therapeutical application.
Gucciardi, Daniel F; Jackson, Ben
2015-01-01
Fostering individuals' long-term participation in activities that promote positive development such as organised sport is an important agenda for research and practice. We integrated the theories of planned behaviour (TPB) and basic psychological needs (BPN) to identify factors associated with young adults' continuation in organised sport over a 12-month period. Prospective study, including an online psycho-social assessment at Time 1 and an assessment of continuation in sport approximately 12 months later. Participants (N=292) aged between 17 and 21 years (M=18.03; SD=1.29) completed an online survey assessing the theories of planned behaviour and basic psychological needs constructs. Bayesian structural equation modelling (BSEM) was employed to test the hypothesised theoretical sequence, using informative priors for structural relations based on empirical and theoretical expectations. The analyses revealed support for the robustness of the hypothesised theoretical model in terms of the pattern of relations as well as the direction and strength of associations among the constructs derived from quantitative summaries of existing research and theoretical expectations. The satisfaction of basic psychological needs was associated with more positive attitudes, higher levels of perceived behavioural control, and more favourable subjective norms; positive attitudes and perceived behavioural control were associated with higher behavioural intentions; and both intentions and perceived behavioural control predicted sport continuation. This study demonstrated the utility of Bayesian structural equation modelling for testing the robustness of an integrated theoretical model, which is informed by empirical evidence from meta-analyses and theoretical expectations, for understanding sport continuation. Crown Copyright © 2013. Published by Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Luo, Xin; Jiao, Jiu Jimmy; Wang, Xu-sheng; Liu, Kun
2016-03-01
How lake systems are maintained and water is balanced in the lake areas in the Badain Jaran Desert (BJD), northeast of China have been debated for about a decade. In this study, continuous 222Rn measurement is used to quantify groundwater discharge into two representative fresh and brine water lakes in the desert using a steady-state mass-balance model. Two empirical equations are used to calculate atmospheric evasion loss crossing the water-air interface of the lakes. Groundwater discharge rates yielded from the radon mass balance model based on the two empirical equations are well correlated and of almost the same values, confirming the validity of the model. The fresh water and brine lakes have a daily averaged groundwater discharge rate of 7.6 ± 1.7 mm d-1 and 6.4 ± 1.8 mm d-1, respectively. The temporal fluctuations of groundwater discharge show similar patterns to those of the lake water level, suggesting that the lakes are recharged from nearby groundwater. Assuming that all the lakes have the same discharge rate as the two studied lakes, total groundwater discharge into all the lakes in the desert is estimated to be 1.59 × 105 m3 d-1. A conceptual model of water balance within a desert lake catchment is proposed to characterize water behaviors within the catchment. This study sheds lights on the water balance in the BJD and is of significance in sustainable regional water resource utilization in such an ecologically fragile area.
Chow, Sy-Miin; Bendezú, Jason J.; Cole, Pamela M.; Ram, Nilam
2016-01-01
Several approaches currently exist for estimating the derivatives of observed data for model exploration purposes, including functional data analysis (FDA), generalized local linear approximation (GLLA), and generalized orthogonal local derivative approximation (GOLD). These derivative estimation procedures can be used in a two-stage process to fit mixed effects ordinary differential equation (ODE) models. While the performance and utility of these routines for estimating linear ODEs have been established, they have not yet been evaluated in the context of nonlinear ODEs with mixed effects. We compared properties of the GLLA and GOLD to an FDA-based two-stage approach denoted herein as functional ordinary differential equation with mixed effects (FODEmixed) in a Monte Carlo study using a nonlinear coupled oscillators model with mixed effects. Simulation results showed that overall, the FODEmixed outperformed both the GLLA and GOLD across all the embedding dimensions considered, but a novel use of a fourth-order GLLA approach combined with very high embedding dimensions yielded estimation results that almost paralleled those from the FODEmixed. We discuss the strengths and limitations of each approach and demonstrate how output from each stage of FODEmixed may be used to inform empirical modeling of young children’s self-regulation. PMID:27391255
Chow, Sy-Miin; Bendezú, Jason J; Cole, Pamela M; Ram, Nilam
2016-01-01
Several approaches exist for estimating the derivatives of observed data for model exploration purposes, including functional data analysis (FDA; Ramsay & Silverman, 2005 ), generalized local linear approximation (GLLA; Boker, Deboeck, Edler, & Peel, 2010 ), and generalized orthogonal local derivative approximation (GOLD; Deboeck, 2010 ). These derivative estimation procedures can be used in a two-stage process to fit mixed effects ordinary differential equation (ODE) models. While the performance and utility of these routines for estimating linear ODEs have been established, they have not yet been evaluated in the context of nonlinear ODEs with mixed effects. We compared properties of the GLLA and GOLD to an FDA-based two-stage approach denoted herein as functional ordinary differential equation with mixed effects (FODEmixed) in a Monte Carlo (MC) study using a nonlinear coupled oscillators model with mixed effects. Simulation results showed that overall, the FODEmixed outperformed both the GLLA and GOLD across all the embedding dimensions considered, but a novel use of a fourth-order GLLA approach combined with very high embedding dimensions yielded estimation results that almost paralleled those from the FODEmixed. We discuss the strengths and limitations of each approach and demonstrate how output from each stage of FODEmixed may be used to inform empirical modeling of young children's self-regulation.
Fluid flow and heat transfer of carbon nanotubes along a flat plate with Navier slip boundary
NASA Astrophysics Data System (ADS)
Khan, W. A.; Khan, Z. H.; Rahi, M.
2014-06-01
Homogeneous flow model is used to study the flow and heat transfer of carbon nanotubes (CNTs) along a flat plate subjected to Navier slip and uniform heat flux boundary conditions. This is the first paper on the flow and heat transfer of CNTs along a flat plate. Two types of CNTs, namely, single- and multi-wall CNTs are used with water, kerosene or engine oil as base fluids. The empirical correlations are used for the thermophysical properties of CNTs in terms of the solid volume fraction of CNTs. For the effective thermal conductivity of CNTs, Xue (Phys B Condens Matter 368:302-307,
Use of transport models for wildfire behavior simulations
DOE Office of Scientific and Technical Information (OSTI.GOV)
Linn, R.R.; Harlow, F.H.
1998-01-01
Investigators have attempted to describe the behavior of wildfires for over fifty years. Current models for numerical description are mainly algebraic and based on statistical or empirical ideas. The authors have developed a transport model called FIRETEC. The use of transport formulations connects the propagation rates to the full conservation equations for energy, momentum, species concentrations, mass, and turbulence. In this paper, highlights of the model formulation and results are described. The goal of the FIRETEC model is to describe most probable average behavior of wildfires in a wide variety of conditions. FIRETEC represents the essence of the combination ofmore » many small-scale processes without resolving each process in complete detail.« less
Direct determination of surface albedos from satellite imagery
NASA Technical Reports Server (NTRS)
Mekler, Y.; Joseph, J. H.
1983-01-01
An empirical method to measure the spectral surface albedo of surfaces from Landsat imagery is presented and analyzed. The empiricism in the method is due only to the fact that three parameters of the solution must be determined for each spectral photograph of an image on the basis of independently known albedos at three points. The approach is otherwise based on exact solutions of the radiative transfer equation for upwelling intensity. Application of the method allows the routine construction of spectral albedo maps from satelite imagery, without requiring detailed knowledge of the atmospheric aerosol content, as long as the optical depth is less than 0.75, and of the calibration of the satellite sensor.
NASA Technical Reports Server (NTRS)
Martinovic, Zoran N.; Cerro, Jeffrey A.
2002-01-01
This is an interim user's manual for current procedures used in the Vehicle Analysis Branch at NASA Langley Research Center, Hampton, Virginia, for launch vehicle structural subsystem weight estimation based on finite element modeling and structural analysis. The process is intended to complement traditional methods of conceptual and early preliminary structural design such as the application of empirical weight estimation or application of classical engineering design equations and criteria on one dimensional "line" models. Functions of two commercially available software codes are coupled together. Vehicle modeling and analysis are done using SDRC/I-DEAS, and structural sizing is performed with the Collier Research Corp. HyperSizer program.
Conjugate Heat Transfer Analyses on the Manifold for Ramjet Fuel Injectors
NASA Technical Reports Server (NTRS)
Wang, Xiao-Yen J.
2006-01-01
Three-dimensional conjugate heat transfer analyses on the manifold located upstream of the ramjet fuel injector are performed using CFdesign, a finite-element computational fluid dynamics (CFD) software. The flow field of the hot fuel (JP-7) flowing through the manifold is simulated and the wall temperature of the manifold is computed. The three-dimensional numerical results of the fuel temperature are compared with those obtained using a one-dimensional analysis based on empirical equations, and they showed a good agreement. The numerical results revealed that it takes around 30 to 40 sec to reach the equilibrium where the fuel temperature has dropped about 3 F from the inlet to the exit of the manifold.
Yang, Yi-Feng
2014-02-01
This paper discusses the effects of transformational leadership on cooperative conflict resolution (management) by evaluating several alternative models related to the mediating role of job satisfaction and change commitment. Samples of data from customer service personnel in Taiwan were analyzed. Based on the bootstrap sample technique, an empirical study was carried out to yield the best fitting model. The procedure of hierarchical nested model analysis was used, incorporating the methods of bootstrapping mediation, PRODCLIN2, and structural equation modeling (SEM) comparison. The analysis suggests that leadership that promotes integration (change commitment) and provides inspiration and motivation (job satisfaction), in the proper order, creates the means for cooperative conflict resolution.
From microscopic taxation and redistribution models to macroscopic income distributions
NASA Astrophysics Data System (ADS)
Bertotti, Maria Letizia; Modanese, Giovanni
2011-10-01
We present here a general framework, expressed by a system of nonlinear differential equations, suitable for the modeling of taxation and redistribution in a closed society. This framework allows one to describe the evolution of income distribution over the population and to explain the emergence of collective features based on knowledge of the individual interactions. By making different choices of the framework parameters, we construct different models, whose long-time behavior is then investigated. Asymptotic stationary distributions are found, which enjoy similar properties as those observed in empirical distributions. In particular, they exhibit power law tails of Pareto type and their Lorenz curves and Gini indices are consistent with some real world ones.
Discharge in Long Air Gaps; Modelling and applications
NASA Astrophysics Data System (ADS)
Beroual, A.; Fofana, I.
2016-06-01
Discharge in Long Air Gaps: Modelling and applications presents self-consistent predictive dynamic models of positive and negative discharges in long air gaps. Equivalent models are also derived to predict lightning parameters based on the similarities between long air gap discharges and lightning flashes. Macroscopic air gap discharge parameters are calculated to solve electrical, empirical and physical equations, and comparisons between computed and experimental results for various test configurations are presented and discussed. This book is intended to provide a fresh perspective by contributing an innovative approach to this research domain, and universities with programs in high-voltage engineering will find this volume to be a working example of how to introduce the basics of electric discharge phenomena.
Smiga, Szymon; Fabiano, Eduardo
2017-11-15
We have developed a simplified coupled cluster (SCC) methodology, using the basic idea of scaled MP2 methods. The scheme has been applied to the coupled cluster double equations and implemented in three different non-iterative variants. This new method (especially the SCCD[3] variant, which utilizes a spin-resolved formalism) has been found to be very efficient and to yield an accurate approximation of the reference CCD results for both total and interaction energies of different atoms and molecules. Furthermore, we demonstrate that the equations determining the scaling coefficients for the SCCD[3] approach can generate non-empirical SCS-MP2 scaling coefficients which are in good agreement with previous theoretical investigations.
Stress-Strain Behavior of Cementitious Materials with Different Sizes
Zhou, Jikai; Qian, Pingping; Chen, Xudong
2014-01-01
The size dependence of flexural properties of cement mortar and concrete beams is investigated. Bazant's size effect law and modified size effect law by Kim and Eo give a very good fit to the flexural strength of both cement mortar and concrete. As observed in the test results, a strong size effect in flexural strength is found in cement mortar than in concrete. A modification has been suggested to Li's equation for describing the stress-strain curve of cement mortar and concrete by incorporating two different correction factors, the factors contained in the modified equation being established empirically as a function of specimen size. A comparison of the predictions of this equation with test data generated in this study shows good agreement. PMID:24744688
Implementation of Advanced Two Equation Turbulence Models in the USM3D Unstructured Flow Solver
NASA Technical Reports Server (NTRS)
Wang, Qun-Zhen; Massey, Steven J.; Abdol-Hamid, Khaled S.
2000-01-01
USM3D is a widely-used unstructured flow solver for simulating inviscid and viscous flows over complex geometries. The current version (version 5.0) of USM3D, however, does not have advanced turbulence models to accurately simulate complicated flow. We have implemented two modified versions of the original Jones and Launder k-epsilon "two-equation" turbulence model and the Girimaji algebraic Reynolds stress model in USM3D. Tests have been conducted for three flat plate boundary layer cases, a RAE2822 airfoil and an ONERA M6 wing. The results are compared with those from direct numerical simulation, empirical formulae, theoretical results, and the existing Spalart-Allmaras one-equation model.
An improved model of fission gas atom transport in irradiated uranium dioxide
NASA Astrophysics Data System (ADS)
Shea, J. H.
2018-04-01
The hitherto standard approach to predicting fission gas release has been a pure diffusion gas atom transport model based upon Fick's law. An additional mechanism has subsequently been identified from experimental data at high burnup and has been summarised in an empirical model that is considered to embody a so-called fuel matrix 'saturation' phenomenon whereby the fuel matrix has become saturated with fission gas so that the continued addition of extra fission gas atoms results in their expulsion from the fuel matrix into the fuel rod plenum. The present paper proposes a different approach by constructing an enhanced fission gas transport law consisting of two components: 1) Fick's law and 2) a so-called drift term. The new transport law can be shown to be effectively identical in its predictions to the 'saturation' approach and is more readily physically justifiable. The method introduces a generalisation of the standard diffusion equation which is dubbed the Drift Diffusion Equation. According to the magnitude of a dimensionless Péclet number, P, the new equation can vary from pure diffusion to pure drift, which latter represents a collective motion of the fission gas atoms through the fuel matrix at a translational velocity. Comparison is made between the saturation and enhanced transport approaches. Because of its dependence on P, the Drift Diffusion Equation is shown to be more effective at managing the transition from one type of limiting transport phenomenon to the other. Thus it can adapt appropriately according to the reactor operation.
Nghiem, Son; Hoang, Viet-Ngu; Vu, Xuan-Binh; Wilson, Clevo
2017-12-04
This paper proposes a new empirical model for examining the relationship between obesity and school performance using the simultaneous equation modelling approach. The lagged effects of both learning and health outcomes were included to capture both the dynamic and inter-relational aspects of the relationship between obesity and school performance. The empirical application of this study used comprehensive data from the first five waves of the Longitudinal Study of Australian Children (LSAC), which commenced in 2004 (wave 1) and was repeated every two years until 2018. The study sample included 10,000 children, equally divided between two cohorts (infants and children) across Australia. The empirical results show that past learning and obesity status are strongly associated with most indicators of school outcomes, including reading, writing, spelling, grammar and numeracy national tests, and scores from the internationally standardized Peabody Picture Vocabulary Test and the Matrix Reasoning Test. The main findings of this study are robust due to the choice of obesity indicator and estimation methods.
Komilis, Dimitrios; Evangelou, Alexandros; Giannakis, Georgios; Lymperis, Constantinos
2012-03-01
In this work, the elemental content (C, N, H, S, O), the organic matter content and the calorific value of various organic components that are commonly found in the municipal solid waste stream were measured. The objective of this work was to develop an empirical equation to describe the calorific value of the organic fraction of municipal solid waste as a function of its elemental composition. The MSW components were grouped into paper wastes, food wastes, yard wastes and plastics. Sample sizes ranged from 0.2 to 0.5 kg. In addition to the above individual components, commingled municipal solid wastes were sampled from a bio-drying facility located in Crete (sample sizes ranged from 8 to 15 kg) and were analyzed for the same parameters. Based on the results of this work, an improved empirical model was developed that revealed that carbon, hydrogen and oxygen were the only statistically significant predictors of calorific value. Total organic carbon was statistically similar to total carbon for most materials in this work. The carbon to organic matter ratio of 26 municipal solid waste substrates and of 18 organic composts varied from 0.40 to 0.99. An approximate chemical empirical formula calculated for the organic fraction of commingled municipal solid wastes was C(32)NH(55)O(16). Copyright © 2011 Elsevier Ltd. All rights reserved.
NASA Astrophysics Data System (ADS)
Yang, Bo
This thesis aims to contribute to a further understanding of the real dynamics of OPEC production behavior and its impacts on the world oil market. A literature review in this area shows that the existing studies on OPEC still have some major deficiencies in theoretical interpretation and empirical estimation technique. After a brief background review in chapter 1, chapter 2 tests Griffin's market-sharing cartel model on the post-Griffin time horizon with a simultaneous system of equations, and an innovative hypothesis of OPEC's behavior (Saudi Arabia in particular) is then proposed based on the estimation results. Chapter 3 first provides a conceptual analysis of OPEC behavior under the framework of non-cooperative collusion with imperfect information. An empirical model is then constructed and estimated. The results of the empirical studies in this thesis strongly support the hypothesis that OPEC has operated as a market-sharing cartel since the early 1980s. In addition, the results also provide some support of the theory of non-cooperative collusion under imperfect information. OPEC members collude under normal circumstances and behave competitively at times in response to imperfect market signals of cartel compliance and some internal attributes. Periodic joint competition conduct plays an important role in sustaining the collusion in the long run. Saudi Arabia acts as the leader of the cartel, accommodating intermediate unfavorable market development and punishing others with a tit-for-tat strategy in extreme circumstances.
Derivation of the Freundlich Adsorption Isotherm from Kinetics
ERIC Educational Resources Information Center
Skopp, Joseph
2009-01-01
The Freundlich adsorption isotherm is a useful description of adsorption phenomena. It is frequently presented as an empirical equation with little theoretical basis. In fact, a variety of derivations exist. Here a new derivation is presented using the concepts of fractal reaction kinetics. This derivation provides an alternative basis for…
Infiltration is important to modeling the overland transport of microorganisms in environmental waters. In watershed- and hillslope scale-models, infiltration is commonly described by simple equations relating infiltration rate to soil saturated conductivity and by empirical para...
Coefficient Alpha: A Reliability Coefficient for the 21st Century?
ERIC Educational Resources Information Center
Yang, Yanyun; Green, Samuel B.
2011-01-01
Coefficient alpha is almost universally applied to assess reliability of scales in psychology. We argue that researchers should consider alternatives to coefficient alpha. Our preference is for structural equation modeling (SEM) estimates of reliability because they are informative and allow for an empirical evaluation of the assumptions…
The Influence of Sexual Identity on Higher Education Outcomes
ERIC Educational Resources Information Center
Sorgen, Carl H., IV.
2011-01-01
This research empirically explores how sexual identity influences higher education outcomes for lesbian, gay, bisexual, and queer (LGBQ) college students. A path model was constructed with structural equation modeling using responses from 1,125 non-heterosexual college students. The model includes four psychological variables (level of sexual…
Formic Acid Investigation for the Prediction of High Explosive Detonation Properties and Performance
2010-07-01
determine constants of the Jones-Wilkins-Lee ( JWL ) and Jones-Wilkins-Lee- Baker (JWLB) thermodynamic equations of state for hydrocode calculations by the...empirical JWL relationships for a number of explosives. Similarly, calculated cylinder velocities at 7 area expansions were within 1% of
Diagnostic Procedures for Detecting Nonlinear Relationships between Latent Variables
ERIC Educational Resources Information Center
Bauer, Daniel J.; Baldasaro, Ruth E.; Gottfredson, Nisha C.
2012-01-01
Structural equation models are commonly used to estimate relationships between latent variables. Almost universally, the fitted models specify that these relationships are linear in form. This assumption is rarely checked empirically, largely for lack of appropriate diagnostic techniques. This article presents and evaluates two procedures that can…
Impact of the Equation of State in Models for Surfactant Spreading Experiments
NASA Astrophysics Data System (ADS)
Levy, Rachel
2014-11-01
Pulmonary surfactant spreading models often rely on an equation of state relating surfactant concentration to surface tension. Mathematically, these models have been analyzed with simple functional relationships. However, to model an experiment with a given fluid and surfactant, a physically meaningful equation of state can be derived from experimentally obtained isotherms. We discuss the comparison between model and experiment for NBD-PC lipid (surfactant) spreading on glycerol for an empirically-determined equation of state, and compare those results to simulations with traditionally employed functional forms. In particular we compare the timescales by tracking the leading edge of surfactant, the central fluid height and dynamics of the Marangoni ridge. We consider both outward spreading of a disk-shaped region of surfactant and the hole-closure problem in which a disk-shaped surfactant-free region self-heals. Support from NSF-DMS-FRG 0968154, RCSA-CCS-19788, and HHMI.
Modeling NAPL dissolution from pendular rings in idealized porous media
NASA Astrophysics Data System (ADS)
Huang, Junqi; Christ, John A.; Goltz, Mark N.; Demond, Avery H.
2015-10-01
The dissolution rate of nonaqueous phase liquid (NAPL) often governs the remediation time frame at subsurface hazardous waste sites. Most formulations for estimating this rate are empirical and assume that the NAPL is the nonwetting fluid. However, field evidence suggests that some waste sites might be organic wet. Thus, formulations that assume the NAPL is nonwetting may be inappropriate for estimating the rates of NAPL dissolution. An exact solution to the Young-Laplace equation, assuming NAPL resides as pendular rings around the contact points of porous media idealized as spherical particles in a hexagonal close packing arrangement, is presented in this work to provide a theoretical prediction for NAPL-water interfacial area. This analytic expression for interfacial area is then coupled with an exact solution to the advection-diffusion equation in a capillary tube assuming Hagen-Poiseuille flow to provide a theoretical means of calculating the mass transfer rate coefficient for dissolution at the NAPL-water interface in an organic-wet system. A comparison of the predictions from this theoretical model with predictions from empirically derived formulations from the literature for water-wet systems showed a consistent range of values for the mass transfer rate coefficient, despite the significant differences in model foundations (water wetting versus NAPL wetting, theoretical versus empirical). This finding implies that, under these system conditions, the important parameter is interfacial area, with a lesser role played by NAPL configuration.
Systems of frequency distributions for water and environmental engineering
NASA Astrophysics Data System (ADS)
Singh, Vijay P.
2018-09-01
A wide spectrum of frequency distributions are used in hydrologic, hydraulic, environmental and water resources engineering. These distributions may have different origins, are based on different hypotheses, and belong to different generating systems. Review of literature suggests that different systems of frequency distributions employed in science and engineering in general and environmental and water engineering in particular have been derived using different approaches which include (1) differential equations, (2) distribution elasticity, (3) genetic theory, (4) generating functions, (5) transformations, (6) Bessel function, (7) expansions, and (8) entropy maximization. This paper revisits these systems of distributions and discusses the hypotheses that are used for deriving these systems. It also proposes, based on empirical evidence, another general system of distributions and derives a number of distributions from this general system that are used in environmental and water engineering.
Rover Slip Validation and Prediction Algorithm
NASA Technical Reports Server (NTRS)
Yen, Jeng
2009-01-01
A physical-based simulation has been developed for the Mars Exploration Rover (MER) mission that applies a slope-induced wheel-slippage to the rover location estimator. Using the digital elevation map from the stereo images, the computational method resolves the quasi-dynamic equations of motion that incorporate the actual wheel-terrain speed to estimate the gross velocity of the vehicle. Based on the empirical slippage measured by the Visual Odometry software of the rover, this algorithm computes two factors for the slip model by minimizing the distance of the predicted and actual vehicle location, and then uses the model to predict the next drives. This technique, which has been deployed to operate the MER rovers in the extended mission periods, can accurately predict the rover position and attitude, mitigating the risk and uncertainties in the path planning on high-slope areas.
Multiobjective Optimization of Rocket Engine Pumps Using Evolutionary Algorithm
NASA Technical Reports Server (NTRS)
Oyama, Akira; Liou, Meng-Sing
2001-01-01
A design optimization method for turbopumps of cryogenic rocket engines has been developed. Multiobjective Evolutionary Algorithm (MOEA) is used for multiobjective pump design optimizations. Performances of design candidates are evaluated by using the meanline pump flow modeling method based on the Euler turbine equation coupled with empirical correlations for rotor efficiency. To demonstrate the feasibility of the present approach, a single stage centrifugal pump design and multistage pump design optimizations are presented. In both cases, the present method obtains very reasonable Pareto-optimal solutions that include some designs outperforming the original design in total head while reducing input power by one percent. Detailed observation of the design results also reveals some important design criteria for turbopumps in cryogenic rocket engines. These results demonstrate the feasibility of the EA-based design optimization method in this field.
Modeling of Wave Spectrum and Wave Breaking Statistics Based on Balance Equation
NASA Astrophysics Data System (ADS)
Irisov, V.
2012-12-01
Surface roughness and foam coverage are the parameters determining microwave emissivity of sea surface in a wide range of wind. Existing empirical wave spectra are not associated with wave breaking statistics although physically they are closely related. We propose a model of sea surface based on the balance of three terms: wind input, dissipation, and nonlinear wave-wave interaction. It provides an insight on wave generation, interaction, and dissipation - very important parameters for understanding of wave development under changing oceanic and atmospheric conditions. The wind input term is the best known among all three. For our analysis we assume a wind input term as it was proposed by Plant [1982] and consider modification necessary to do to account for proper interaction of long fast waves with wind. For long gravity waves (longer than 15-30 cm) the dissipation term can be related to the wave breaking with whitecaps, as it was shown by Kudryavtsev et al. [2003], so we assume the cubic dependence of dissipation term on wind. It implies certain limitations on the spectrum shape. The most difficult is to estimate the term describing nonlinear wave-wave interaction. Hasselmann [1962] and Zakharov [1999] developed theory of 4-wave interaction, but the resulting equation requires at least 3-fold integration over wavenumbers at each time step of integration of balance equation, which makes it difficult for direct numerical modeling. It is desirable to use an approximation of wave-wave interaction term, which preserves wave action, energy, and momentum, and can be easily estimated during time integration of balance equation. Zakharov and Pushkarev [1999] proposed the diffusion approximation of the wave interaction term and showed that it can be used for estimate of wave spectrum. We believe their assumption that wave-wave interaction is the dominant factor in forming the wave spectrum does not agree with the observations made by Hwang and Sletten [2008]. Finally we consider modifications of the model equation, which can be done to describe gravity-capillary and capillary waves. An obvious correction is to add viscous dissipation. A little less obvious is a transition from 4-wave to 3-wave interaction. The model allows one to include easily generation of parasitic capillary waves as it was proposed by Kudryavtsev et al. [2003]. A modification of dissipation term can explain an "overshoot" phenomenon observed in JONSWAP spectrum. These examples demonstrate that the proposed model is quite flexible and can be used to account for various physical phenomena. The resulting balance equation is easy to integrate using a personal computer and necessity of its numerical solution is paid by the model flexibility and better physical background compared with empirical spectra. References Hasselmann, K., J. Fluid Mech., 12, pp.481-500, 1962. Hwang, P., and M. Sletten, J. Geophys. Res., 113, doi:10.1029/2007JC004277, 2008. Kudryavtsev, V., et al., J. Geophys. Res., 108 (C3), doi:10.1029/2001JC001003, 2003. Plant, W. J., J. Geophys. Res., vol. 87, pp. 1961-1967, 1982. Zakharov, V., and A. Pushkarev, Nonlinear Processes in Geophysics, 6, pp.1-10, 1999. Zakharov, V., Eur. J. Mech. B/Fluids, 18, pp.327-344, 1999.
NASA Astrophysics Data System (ADS)
Reitz, M. D.; Sanford, W. E.; Senay, G. B.; Cazenas, J.
2015-12-01
Evapotranspiration (ET) is a key quantity in the hydrologic cycle, accounting for ~70% of precipitation across the contiguous United States (CONUS). However, it is a challenge to estimate, due to difficulty in making direct measurements and gaps in our theoretical understanding. Here we present a new data-driven, ~1km2 resolution map of long-term average actual evapotranspiration rates across the CONUS. The new ET map is a function of the USGS Landsat-derived National Land Cover Database (NLCD), precipitation, temperature, and daily average temperature range (from the PRISM climate dataset), and is calibrated to long-term water balance data from 679 watersheds. It is unique from previously presented ET maps in that (1) it was co-developed with estimates of runoff and recharge; (2) the regression equation was chosen from among many tested, previously published and newly proposed functional forms for its optimal description of long-term water balance ET data; (3) it has values over open-water areas that are derived from separate mass-transfer and humidity equations; and (4) the data include additional precipitation representing amounts converted from 2005 USGS water-use census irrigation data. The regression equation is calibrated using data from 2000-2013, but can also be applied to individual years with their corresponding input datasets. Comparisons among this new map, the more detailed remote-sensing-based estimates of MOD16 and SSEBop, and AmeriFlux ET tower measurements shows encouraging consistency, and indicates that the empirical ET estimate approach presented here produces closer agreement with independent flux tower data for annual average actual ET than other more complex remote sensing approaches.
Population, internal migration, and economic growth: an empirical analysis.
Moreland, R S
1982-01-01
The role of population growth in the development process has received increasing attention during the last 15 years, as manifested in the literature in 3 broad categories. In the 1st category, the effects of rapid population growth on the growth of income have been studied with the use of simulation models, which sometimes include endogenous population growth. The 2nd category of the literature is concerned with theoretical and empirical studies of the economic determinants of various demographic rates--most usually fertility. Internal migration and dualism is the 3rd population development category to recieve attention. An attempt is made to synthesize developments in these 3 categories by estimating from a consistent set of data a 2 sector economic demographic model in which the major demographic rates are endogenous. Due to the fact that the interactions between economic and demographic variables are nonlinear and complex, the indirect effects of changes in a particular variable may depend upon the balance of numerical coefficients. For this reason it was felt that the model should be empirically grounded. A brief overview of the model is provided, and the model is compared to some similar existing models. Estimation of the model's 9 behavior equations is discussed, followed by a "base run" simulation of a developing country "stereotype" and a report of a number of policy experiments. The relatively new field of economic determinants of demographic variables was drawn upon in estimating equations to endogenize demographic phenomena that are frequently left exogenous in simulation models. The fertility and labor force participation rate functions are fairly standard, but a step beyong existing literature was taken in the life expectancy and intersectorial migration equations. On the economic side, sectoral savings functions were estimated, and it was found that the marginal propensity to save is lower in agriculture than in nonagriculture. Testing to see the effect of a population's age structure on savings rather than assuming a particular direction as Coale-Hoover and Simon do in their models, it was found that a higher proportion of children compete with savings in agriculture but complement savings in industrial areas. This was consistent with the economic value of children in agricultural and nonagricultural regions of less developed countries. The estimated production functions showed that marginal products of labor were considerably higher in agriculture than in nonagriculture. As with other simulation models, the effect of reducing fertility was to accelerate income growth. Reductions in rural fertility were more equitable and raised the overall level of per capita income more than similar efforts directed to urban areas only.
NASA Astrophysics Data System (ADS)
Pan, J.; Durand, M. T.; Sandells, M. J.; Lemmetyinen, J.; Kim, E. J.
2013-12-01
Application of passive microwave (PM) brightness temperature for snow water equivalent retrieval requires deep understanding of snow emission models, not only for their performance to reproduce in-situ PM observations, but also for their theoretical differences to approximate radiative transfer theory. In this paper, differences between the multiple-layer HUT (or TKK) model and the Microwave Emission Model of Layered Snowpacks (MEMLS) were listed, and the two models were compared with snow ground-based PM observations at Streamboat Springs, Colorado, USA; Churchill, Canada; and Sodankyla, Finland. The two models were chosen for their multiple-layer schemes are close to actual layer-by-layer snow measurements. Both the two models are semi-empirical models; whereas the HUT model uses the mean snow grain size, MEMLS uses the correlation length to relate the snow microstructure with the scattering coefficients. The two parameters are related according to previous studies. The Specific Surface Area (SSA) was measured at three test sites to derive the correlation length, while the mean snow grain sizes was available at Stream Springs and Sodankyla. It was shown that with different apparent forms of radiative transfer equations, the different parts of the two models have one-to-one correspondence however, and intermediate parameters are comparable. Regarding the multiple-layer structure of the models, it was found that the HUT model considers the internal reflectivity of each snow layer to be zero. The two-flux radiative transfer equations of the two models were compared, and the correspondence of the semi-empirical parameter q in the HUT model was found in the MEMLS. The effect of consideration of transverse radiation scattered into the direction under consideration via the six-flux approximation in MEMLS is compared. Based on model comparisons, we analyzed the differences of TB predictions at the three test sites.
Hot Spot Detection System Using Landsat 8/OLI Data
NASA Astrophysics Data System (ADS)
Kato, S.; Nakamura, R.; Oda, A.; Iijima, A.; Kouyama, T.; Iwata, T.
2015-12-01
We developed a simple algorithm and a Web-based visualizing system to detect hot spots using Landsat 8 OLI multispectral data as one of the applications of the real-time processing of Landsat 8 data. An empirical equation and radiometric and reflective thresholds were derived to detect hot spots using the OLI data at band 5 (0.865 μm) and band 7 (2.200 μm) based on the increase in spectral radiance at shortwave infrared (SWIR) region due to the emission from objects with high surface temperature. We surveyed typical patterns of surface spectra using the ASTER spectral library to delineate a threshold to distinguish hot spots from background surfaces. To adjust the empirical coefficients of our detection algorithm, we visually inspected the detected hot spots using 6593 Landsat 8 scenes, which cover eastern part of East Asia, taken from January 1, 2014 to December 31, 2014, displayed on a dedicated Web GIS system. Eventually we determined threshold equations which can theoretically detect hot spots at temperatures above 230 °C over isothermal pixels and hot spots as small as 1 m2 at temperatures of 1000 °C as the lowest temperature and the smallest subpixel coverage, respectively, for daytime scenes. The algorithm detected hot spots including wildfires, volcanos, open burnings and factories. 30-m spatial resolution of Landsat 8 enabled to detect wild fires and open burnings accompanied by clearer shapes of fire front lines than MODIS and VIIRS fire products. Although the 16-day revisit cycle of Landsat 8 is too long to effectively find unexpected wildfire or outbreak of eruption, the revisit cycle is enough to monitor temporally stable heat sources, such as continually erupting volcanos and factories. False detection was found over building rooftops, which have relatively smooth surfaces at longer wavelengths, when specular reflection occurred at the satellite overpass.