Thermophilic campylobacters in surface waters around Lancaster, UK: negative correlation with Campylobacter infections in the community.

PubMed

Jones, K; Betaieb, M; Telford, D R

1990-11-01

The incidence of campylobacter enteritis in Lancaster City Health Authority is three times the UK average for similar sizes of population and has marked seasonal peaks in May and June. Environmental monitoring of surface waters around Lancaster showed that thermophilic campylobacters were absent from drinking water from the fells and from the clean upper reaches of the River Conder but were present in the main rivers entering Morecambe Bay, the lower reaches of the River Conder, the Lancaster canal, and seawater from the Lune estuary and Morecambe Bay. All the surface waters tested showed the same seasonality, namely, higher numbers in the winter months and low numbers or none in May, June and July. The absence of thermophilic campylobacters in the summer months may be due to high sunshine levels because experiments on the effects of light showed that campylobacters in sewage effluent and seawater were eliminated within 60 and 30 min of daylight respectively but survived for 24 h in darkness. As the concentrations of campylobacters in surface waters were at their lowest precisely at the time of peak infections in the community it is unlikely that surface waters form Lancaster's reservoir of campylobacter infection for the community.

Effect of seasonal and long-term changes in stress on sources of water to wells

USGS Publications Warehouse

Reilly, Thomas E.; Pollock, David W.

1995-01-01

The source of water to wells is ultimately the location where the water flowing to a well enters the boundary surface of the ground-water system . In ground-water systems that receive most of their water from areal recharge, the location of the water entering the system is at the water table . The area contributing recharge to a discharging well is the surface area that defines the location of the water entering the groundwater system. Water entering the system at the water table flows to the well and is eventually discharged from the well. Many State agencies are currently (1994) developing wellhead-protection programs. The thrust of some of these programs is to protect water supplies by determining the areas contributing recharge to water-supply wells and by specifying regulations to minimize the opportunity for contamination of the recharge water by activities at the land surface. In the analyses of ground-water flow systems, steady-state average conditions are frequently used to simplify the problem and make a solution tractable. Recharge is usually cyclic in nature, however, having seasonal cycles and longer term climatic cycles. A hypothetical system is quantitatively analyzed to show that, in many cases, these cyclic changes in the recharge rates apparently do not significantly affect the location and size of the areas contributing recharge to wells. The ratio of the mean travel time to the length of the cyclic stress period appears to indicate whether the transient effects of the cyclic stress must be explicitly represented in the analysis of contributing areas to wells. For the cases examined, if the ratio of the mean travel time to the period of the cyclic stress was much greater than one, then the transient area contributing recharge to wells was similar to the area calculated using an average steady-state condition. Noncyclic long-term transient changes in water use, however, and cyclic stresses on systems with ratios less than 1 can and do affect the location and size of the areas contributing recharge to wells.

Effects of rainfall events on the occurrence and detection efficiency of viruses in river water impacted by combined sewer overflows.

PubMed

Hata, Akihiko; Katayama, Hiroyuki; Kojima, Keisuke; Sano, Shoichi; Kasuga, Ikuro; Kitajima, Masaaki; Furumai, Hiroaki

2014-01-15

Rainfall events can introduce large amount of microbial contaminants including human enteric viruses into surface water by intermittent discharges from combined sewer overflows (CSOs). The present study aimed to investigate the effect of rainfall events on viral loads in surface waters impacted by CSO and the reliability of molecular methods for detection of enteric viruses. The reliability of virus detection in the samples was assessed by using process controls for virus concentration, nucleic acid extraction and reverse transcription (RT)-quantitative PCR (qPCR) steps, which allowed accurate estimation of virus detection efficiencies. Recovery efficiencies of poliovirus in river water samples collected during rainfall events (<10%) were lower than those during dry weather conditions (>10%). The log10-transformed virus concentration efficiency was negatively correlated with suspended solid concentration (r(2)=0.86) that increased significantly during rainfall events. Efficiencies of DNA extraction and qPCR steps determined with adenovirus type 5 and a primer sharing control, respectively, were lower in dry weather. However, no clear relationship was observed between organic water quality parameters and efficiencies of these two steps. Observed concentrations of indigenous enteric adenoviruses, GII-noroviruses, enteroviruses, and Aichi viruses increased during rainfall events even though the virus concentration efficiency was presumed to be lower than in dry weather. The present study highlights the importance of using appropriate process controls to evaluate accurately the concentration of water borne enteric viruses in natural waters impacted by wastewater discharge, stormwater, and CSOs. © 2013.

Substance flow analysis as a tool for urban water management.

PubMed

Chèvre, N; Guignard, C; Rossi, L; Pfeifer, H-R; Bader, H-P; Scheidegger, R

2011-01-01

Human activity results in the production of a wide range of pollutants that can enter the water cycle through stormwater or wastewater. Among others, heavy metals are still detected in high concentrations around urban areas and their impact on aquatic organisms is of major concern. In this study, we propose to use a substance flow analysis as a tool for heavy metals management in urban areas. We illustrate the approach with the case of copper in Lausanne, Switzerland. The results show that around 1,500 kg of copper enter the aquatic compartment yearly. This amount contributes to sediment enrichment, which may pose a long-term risk for benthic organisms. The major sources of copper in receiving surface water are roofs and catenaries of trolleybuses. They represent 75% of the total input of copper into the urban water system. Actions to reduce copper pollution should therefore focus on these sources. Substance flow analysis also highlights that copper enters surface water mainly during rain events, i.e., without passing through any treatment procedure. A reduction in pollution could also be achieved by improving stormwater management. In conclusion, the study showed that substance flow analysis is a very effective tool for sustainable urban water management.

Ecohydrology across Scales in an Arid, Human-dominated Landscape: Implications for Ecosystems, Water Availability and Human Interactions

NASA Astrophysics Data System (ADS)

Belnap, J.; Deems, J. S.; Kind, A.; Munson, S.; Neff, J.; Okin, G.; Painter, T. H.; Reheis, M. C.; Reynolds, R. L.; Wilcox, B. P.

2011-12-01

Arid and semi-arid regions constitute over 35% of global lands. The utilization of these areas is increasing rapidly in response to rising human populations and attendant food needs. In addition, they are also foci for activities associated with energy production, mineral extraction, military training and conflict, and recreation. The resultant disturbance reduces the protective cover of plants and physical and biological soil crusts. This leads to accelerated soil loss by both wind and water, across a wide range of parent materials, textures, or soil surface ages. Further vulnerability to soil erosion is expected with predicted future drier and hotter climates, as plant cover declines and fires increase. Synergistic effects, such as surface disturbance occurring during drought periods in plant communities dominated by annual weeds, can exacerbate the situation further. At a local scale, the redistribution of soil by wind and water results in nutrients being more heterogeneously distributed, subsequently altering abundance and distribution of plants, animals, and rates of biogeochemical cycling. Particles transported by wind from disturbed settings can be deposited in washes, subsequently entering streams and rivers.Particles saltating across the soil surface are also frequently deposited in washes, subsequently entering streams and rivers. This process represents a local loss of soil fertility and a local and regional decrease in water quality, as sediment and salts enter water bodies. At the larger watershed scale, dust is deposited on nearby snow cover, darkening the snow and increasing melt rates. Increased melt rates decrease the length of the snow-cover season, increasing water losses to evapotranspiration and thus the amount of water entering streams and rivers. As water quantity decreases, salts and sediments are concentrated, thereby further decreasing water quality. As water becomes scarcer in drylands around the world, the diminishing integrity of the soil surface is likely to become a major issue for land managers. In addition, the spatial decoupling between the people engaged in the upstream activities that lower water availability/quality and the downstream users facing water shortages will likely result in new combinations of interest groups and the need for novel ways to address their differences. The science of ecohydrology has an important role to play in these conversations.

Sorption of Heterotrophic and Enteric Bacteria to Glass Surfaces in the Continuous Culture of River Water

PubMed Central

Hendricks, Charles W.

1974-01-01

A natural population of heterotrophic bacteria, including enterics, was observed to sorb to glass surfaces and multiply during the continuous culture of river water. An initial rate of attachment equivalent to a doubling time of about 2 h was observed with a corresponding increase in the suspended population. After 24 h both the sorbed and suspended populations stabilized with a mass doubling time approximating 100 h at a dilution rate of 0.012/h. On the basis of respiration and degradative enzymatic data, the sorbed microorganisms appeared to be somewhat more metabolically active than the organisms in suspension. PMID:4424694

Comparative study of enteric viruses, coliphages and indicator bacteria for evaluating water quality in a tropical high-altitude system.

PubMed

Espinosa, Ana C; Arias, Carlos F; Sánchez-Colón, Salvador; Mazari-Hiriart, Marisa

2009-10-27

Bacteria used as indicators for pathogenic microorganisms in water are not considered adequate as enteric virus indicators. Surface water from a tropical high-altitude system located in Mexico City that receives rainwater, treated and non-treated wastewater used for irrigation, and groundwater used for drinking, was studied. The presence of enterovirus, rotavirus, astrovirus, coliphage, coliform bacteria, and enterococci was determined during annual cycles in 2001 and 2002. Enteric viruses in concentrated water samples were detected by reverse transcriptase-polymerase chain reaction (RT-PCR). Coliphages were detected using the double agar layer method. Bacteria analyses of the water samples were carried out by membrane filtration. The presence of viruses and bacteria in the water used for irrigation showed no relationship between current bacterial indicator detection and viral presence. Coliphages showed strong association with indicator bacteria and enterovirus, but weak association with other enteric viruses. Enterovirus and rotavirus showed significant seasonal differences in water used for irrigation, although this was not clear for astrovirus. Coliphages proved to be adequate faecal pollution indicators for the irrigation water studied. Viral presence in this tropical high-altitude system showed a similar trend to data previously reported for temperate zones.

Safety of community drinking-water and outbreaks of waterborne enteric disease: Israel, 1976-97.

PubMed Central

Tulchinsky, T. H.; Burla, E.; Clayman, M.; Sadik, C.; Brown, A.; Goldberger, S.

2000-01-01

Waterborne disease remains a major public health problem in many countries. We report findings on nearly three decades of waterborne disease in Israel and the part these diseases play in the total national burden of enteric disease. During the 1970s and 1980s, Israel's community water supplies were frequently of poor quality according to the microbiological standards at that time, and the country experienced many outbreaks of waterborne enteric disease. New regulations raised water quality standards and made chlorination of community water supplies mandatory, as well as imposing more stringent guidelines on maintaining water sources and distribution systems for both surface water and groundwater. This was followed by improved compliance and water quality, and a marked decline in the number of outbreaks of waterborne disease; no outbreaks were detected between 1992 and 1997. The incidence of waterborne salmonellosis, shigellosis, and typhoid declined markedly as proportions of the total burden of these diseases, but peaked during the time in which there were frequent outbreaks of waterborne disease (1980-85). Long-term trends in the total incidence of reported infectious enteric diseases from all sources, including typhoid, shigellosis, and viral hepatitis (all types) declined, while the total incidence of salmonellosis increased. Mandatory chlorination has had an important impact on improving water quality, in reducing outbreaks of waterborne disease in Israel, and reducing the total burden of enteric disease in the country. PMID:11196499

Ecohydrologic separation of water between trees and streams in a Mediterranean climate

EPA Science Inventory

Water movement in upland humid watersheds from the soil surface to the stream is often described using the concept of translatory flow, which assumes that water entering the soil as precipitation displaces the water that was present previously, pushing it deeper into the soil and...

Influences of Coal Ash Leachates and Emergent Macrophytes on Water Quality in Wetland Microcosms

EPA Science Inventory

The storage of coal combustion residue (CCR) in surface water impoundments may have an impact on nearby water quality and aquatic ecosystems. CCR contains leachable trace elements that can enter nearby waters through spills and monitored discharge. It is important, therefore, to ...

A hydrodynamics-based approach to evaluating the risk of waterborne pathogens entering drinking water intakes in a large, stratified lake.

PubMed

Hoyer, Andrea B; Schladow, S Geoffrey; Rueda, Francisco J

2015-10-15

Pathogen contamination of drinking water lakes and reservoirs is a severe threat to human health worldwide. A major source of pathogens in surface sources of drinking waters is from body-contact recreation in the water body. However, dispersion pathways of human waterborne pathogens from recreational beaches, where body-contact recreation is known to occur to drinking water intakes, and the associated risk of pathogens entering the drinking water supply remain largely undocumented. A high spatial resolution, three-dimensional hydrodynamic and particle tracking modeling approach has been developed to analyze the risk and mechanisms presented by pathogen dispersion. The pathogen model represents the processes of particle release, transport and survival. Here survival is a function of both water temperature and cumulative exposure to ultraviolet (UV) radiation. Pathogen transport is simulated using a novel and computationally efficient technique of tracking particle trajectories backwards, from a drinking water intake toward their source areas. The model has been applied to a large, alpine lake - Lake Tahoe, CA-NV (USA). The dispersion model results reveal that for this particular lake (1) the risk of human waterborne pathogens to enter drinking water intakes is low, but significant; (2) this risk is strongly related to the depth of the thermocline in relation to the depth of the intake; (3) the risk increases with the seasonal deepening of the surface mixed layer; and (4) the risk increases at night when the surface mixed layer deepens through convective mixing and inactivation by UV radiation is eliminated. While these risk factors will quantitatively vary in different lakes, these same mechanisms will govern the process of transport of pathogens. Copyright © 2015 Elsevier Ltd. All rights reserved.

The survival and inactivation of enteric viruses on soft surfaces: A systematic review of the literature.

PubMed

Yeargin, Thomas; Buckley, David; Fraser, Angela; Jiang, Xiuping

2016-11-01

Worldwide, enteric viruses are the main cause of acute gastroenteritis. In humans, these viruses spread via person-to-person contact, food, water, and/or the environment. Their survival and inactivation on hard surfaces have been extensively studied; however, nonlaunderable soft surfaces, such as upholstery and carpet, have received little attention. The aim of this systematic review was to determine factors that influence the survival and inactivation of enteric viruses on nonlaunderable soft surfaces. EBSCO and Web of Science were searched for experimental studies published between 1965 and 2015 using Preferred Reporting Items for Systematic Reviews and Meta-Analyses methods. Titles and abstracts were screened using 3 eligibility criteria. The quality of all study methods was also assessed. Our search yielded 12 articles. Viruses survived between 0 hours and 140 days depending on surface and environment conditions. Virus survival was influenced by temperature, relative humidity, organic content, and deposition method. A variety of chemistries were tested across studies and were shown to have a varied effect on enteric viruses. Chlorine, glutaraldehyde, vaporous ozone, and hydrogen peroxide were the most efficacious against enteric viruses (> 3-log reduction). Environmental factors, such as temperature and relative humidity, can influence survival of enteric viruses on nonlaunderable soft surfaces. The efficacy of liquid and vaporous chemistries are associated with surface and virus type. Copyright © 2016 Association for Professionals in Infection Control and Epidemiology, Inc. Published by Elsevier Inc. All rights reserved.

Internalization of fresh produce by foodborne pathogens.

PubMed

Erickson, Marilyn C

2012-01-01

Recent studies addressing the internalization of fresh produce by foodborne pathogens arose in response to the growing number of recent and high profile outbreaks involving fresh produce. Because chemical sanitizing agents used during harvest and minimal processing are unlikely to reach enteric pathogens residing within plant tissue, it is imperative that paths for pathogen entry be recognized and minimized. Using both microscopy and microbial enumeration tools, enteric pathogens have been shown to enter plant tissues through both natural apertures (stomata, lateral junctions of roots, flowers) and damaged (wounds, cut surfaces) tissue. In studies revealing preharvest internalization via plant roots or leaf stomata, experimental conditions have primarily involved exposure of plants to high pathogen concentrations (≥ 6 log g⁻¹ soil or 6 log ml⁻¹ water), but those pathogens internalized appear to have short-term persistence. Postharvest internalization of pathogens via cut surfaces may be minimized by maintaining effective levels of sanitizing agents in waters during harvesting and minimal processing.

Atrazine sorption by biochar, tire chips, and steel slag as media for blind inlets: A kinetic and isotherm sorption approach

USDA-ARS?s Scientific Manuscript database

Surface inlets are installed in subsurface drainage systems to reduce ponding duration and surface runoff, but can contribute to water quality concerns by allowing water to directly enter buried drains. Blind inlets, consist of perforated pipes covered with gravel and are separated from an overlying...

Evaluation of Listeria monocytogenes survival and infectivity in non-traditional agricultural waters

USDA-ARS?s Scientific Manuscript database

Introduction: Listeria monocytogenes (Lm) is an enteric bacterium that can be found in environmental reservoirs. Restricted water availability for agriculture has increased interest in surface and reuse water sources which could potentially transmit Lm. Purpose: Persistence and infectivity of Lm re...

Hydrological and chlorofluoromethane measurements of the Indonesian throughflow entering the Indian Ocean

NASA Astrophysics Data System (ADS)

Fieux, M.; Andrié, C.; Charriaud, E.; Ilahude, A. G.; Metzl, N.; Molcard, R.; Swallow, J. C.

1996-05-01

The Java Australia Dynamic Experiment high-resolution February-March 1992 conductivity-temperature-depth and chlorofluoromethane section obtained between Australia and Bali and on the sills between Flores, Sumba, Sawu, Roti, and the Australian continental shelf allows detailed examination of the water masses distribution and their inferred circulation. A sharp hydrological front between the Indonesian waters and the southern Indian Ocean waters is found between 13°S and 14°S in both seasons (February-March 1992 and August 1989). It separates the high-salinity surface waters to the south from the lower-salinity surface waters derived from the Indonesian Seas to the north. It reaches the surface in February 1992, whereas it was capped by a particularly low salinity surface layer in August 1989. Near Bali, the NW monsoon of February-March produces large intrusions of low-salinity water from the Java Sea, through Lombok Strait in the upper 100 m. At depth, the North Indian Intermediate Water, flowing along the Indonesian coast, brings salty, low-oxygen and low-chlorofluorocarbon water. It enters the Sawu Sea through Sumba Strait toward the east, while it undergoes strong mixing with the Indonesian Seas water. The primary pathway of the Indonesian waters is found north of the front and south of the North Indian Intermediate Water, between 13°S and 9°30'S, and the associated salinity minimum can be followed all across the Indian Ocean.

Exploring Paleoclimatic and -Oceanographic Consequences for Arctic Beringia by the Eocene Formation and Progressive E-W Lengthening of the Aleutian Ridge (arc) Across the North Pacific Basin

NASA Astrophysics Data System (ADS)

Scholl, D. W.

2013-12-01

INTRODUCTION: During the past ~50 Myr, magmatic growth of the offshore Aleutian Ridge (AR) or arc and its progressive tectonic lengthening to the west cordoned off the NW corner of the Pacific Basin to formed the deep water (3000-4000 m), marginal sea of the Bering Sea Basin (BSB). Cordoning continuously altered the paths, depths, and locations of water-exchange passes controlling the circulation of waters between the north Pacific and the Bering Sea (BS), and, via the fixed Bering Strait, that entering the Pacific sector of the Arctic Basin. PRESENT PATTERN OF PACIFIC-BERING-ARCTIC WATER EXCHANGE: Cool, low salinity water of the Alaska Stream flowing west along the Pacific side of the AR crosses northward into the BS via tectonically controlled, inter-island passes. The largest volume (~9 SV) enters near the western end of the AR via Near Pass. Flow turns back to the east and CCW northward over the BSB. Surface water exits southward around the western end of the AR through the far western, deep-water (~4000 m) pass of Kamchatka Strait. Because water salinity is low, vertical thermohaline circulation (THC) does not occur over the BSB. However, the deposition of the larger Meiji Drift body, which is charged with Bering-sourced, detritus, on the Pacific side of Kamchatka Strait implies THC may have occurred in the past. Deep-water circulation is presently linked to the inflow of Pacific abyssal water via Kamchatka Strait. A small volume (~0.8 SV) of cool, low salinity water entering the BS mainly through eastern, shallow-silled passes continues northward across the broad Beringian shelf to enter the Arctic Ocean via the Bering Strait. EVOLUTION OF ALEUTIAN RIDGE: At it's inception, the arc massif of the AR likely extended only about 1200 km west of Alaska. Because convergence is increasingly oblique to the west, plate-boundary-driven, right-lateral strike-slip faulting extensionally fragmented the AR and progressively rotated and transported blocks and slivers westward toward Kamchatka. Water-exchange passes were created between them as the AR tectonically lengthened to ~2200 km at an estimated average speed of ~40-50 km/Myr. PALEOCEANOGRPAIC WONDERMENTS FOR PACIFIC SECTOR OF ARCTIC: The Arctic Ocean presently receives low salinity water entering the BS from the east. Prior to Northern Hemisphere glaciation, fossil plant and animal taxa document the BS was far more temperature than the cold, foggy, rawness of today, and surface waters were saltier and warmer than now. Although the BSB is today effectively closed to north-bound western Pacific circulation, during much of Tertiary it was open to the west. It can be posited that subtopical, western Pacific boundary currents (e.g., the Kuroshio Current) formerly entered the BS from the west and exited eastward--the reverse of now. Salty surface water in the BSB could have supported THC to begin construction of the Meiji drift body by southward outflow of abyssal BS water through Kamchatka Strait. To the north, when the Tertiary Bering Strait was open, BS water entering the Arctic Ocean may well have been sourced from the western subtropical Pacific rather than, as now, from the subboreal NE Pacific.

Waterborne transmission ofCampylobacter enteritis.

PubMed

Taylor, D N; Brown, M; McDermott, K T

1982-12-01

Campylobacter jejuni is an important cause of human diarrheal disease throughout the world and likeSalmonella enteritidis, has a large animal reservoir which includes most of man's domestic animals. Until recently, it has been difficult to trace the chain of transmission from animals to man because of inadequate environmental sampling techniques and means to distinguish strains. Recent improvements in these techniques have made environmental studies more feasible in 2 water-related out-breaks.In 1 study,C. jejuni was found to be an important cause of sporadic, summertime diarrheal disease among hikers in national wilderness areas of Wyoming. In this setting, illness was significantly associated with drinking untreated surface water. SubsequentlyC. jejuni was isolated from surface water, including mountian streams, and from animals in the area. Some of the environmental isolates were serotypically identical to strains isolated from humans.A second study occurred as a result of an outbreak of Campylobacter enteritis in a community in northern Illinois which was epidemiologically associated with the community water system.Campylobacter jejuni was isolated from several surface water sources and from the implicated water system. These studies demonstrate that environmental isolation ofC. jejuni is now possible and may add to our understanding of disease transmission.

Spatial Distribution of Triclosan in Sediments and Water of an Urbanized Estuarine Embayment

EPA Science Inventory

Triclosan (TCS) is a broad spectrum anti-microbial compound found in many consumer and personal care products. TCS enters water bodies primarily through wastewater treatment plant (WWTP) effluent and may also be introduced by combined sewer overflows or surface water runoff. TC...

Human enteric viruses in groundwater indicate offshore transport of human sewage to coral reefs of the Upper Florida Keys.

PubMed

Futch, J Carrie; Griffin, Dale W; Lipp, Erin K

2010-04-01

To address the issue of human sewage reaching corals along the main reef of the Florida Keys, samples were collected from surface water, groundwater and coral [surface mucopolysaccharide layers (SML)] along a 10 km transect near Key Largo, FL. Samples were collected semi-annually between July 2003 and September 2005 and processed for faecal indicator bacteria (faecal coliform bacteria, enterococci and Clostridium perfringens) and human-specific enteric viruses (enterovirus RNA and adenovirus DNA) by (RT)-nested polymerase chain reaction. Faecal indicator bacteria concentrations were generally higher nearshore and in the coral SML. Enteric viruses were evenly distributed across the transect stations. Adenoviruses were detected in 37 of 75 samples collected (49.3%) whereas enteroviruses were only found in 8 of 75 samples (10.7%). Both viruses were detected twice as frequently in coral compared with surface water or groundwater. Offshore, viruses were most likely to be found in groundwater, especially during the wet summer season. These data suggest that polluted groundwater may be moving to the outer reef environment in the Florida Keys.

Human enteric viruses in groundwater indicate offshore transport of human sewage to coral reefs of the Upper Florida Keys

USGS Publications Warehouse

Futch, J. Carrie; Griffin, Dale W.; Lipp, Erin K.

2010-01-01

To address the issue of human sewage reaching corals along the main reef of the Florida Keys, samples were collected from surface water, groundwater and coral [surface mucopolysaccharide layers (SML)] along a 10 km transect near Key Largo, FL. Samples were collected semi-annually between July 2003 and September 2005 and processed for faecal indicator bacteria (faecal coliform bacteria, enterococci and Clostridium perfringens) and human-specific enteric viruses (enterovirus RNA and adenovirus DNA) by (RT)-nested polymerase chain reaction. Faecal indicator bacteria concentrations were generally higher nearshore and in the coral SML. Enteric viruses were evenly distributed across the transect stations. Adenoviruses were detected in 37 of 75 samples collected (49.3%) whereas enteroviruses were only found in 8 of 75 samples (10.7%). Both viruses were detected twice as frequently in coral compared with surface water or groundwater. Offshore, viruses were most likely to be found in groundwater, especially during the wet summer season. These data suggest that polluted groundwater may be moving to the outer reef environment in the Florida Keys.

Water Masses and Nutrient Sources to the Gulf of Maine

PubMed Central

Townsend, David W.; Pettigrew, Neal R.; Thomas, Maura A.; Neary, Mark G.; McGillicuddy, Dennis J.; O’Donnell, James

2016-01-01

The Gulf of Maine, a semi-enclosed basin on the continental shelf of the northwest Atlantic Ocean, is fed by surface and deep water flows from outside the Gulf: Scotian Shelf Water from the Nova Scotian shelf that enters the Gulf at the surface, and Slope Water that enters at depth and along the bottom through the Northeast Channel. There are two types of Slope Water, Labrador Slope Water (LSW) and Warm Slope Water (WSW); it is these deep water masses that are the major source of dissolved inorganic nutrients to the Gulf. It has been known for some time that the volume inflow of Slope Waters of either type that enters the Gulf of Maine is variable, that it co-varies with the magnitude of inflowing Scotian Shelf Water, and that periods of greater inflows of Scotian Shelf Water have become more frequent in recent years, accompanied by reduced Slope Water inflows. We present here analyses of a ten-year record of data collected by moored sensors in Jordan Basin, in the interior Gulf of Maine, and in the Northeast Channel, along with recent and historical hydrographic and nutrient data, that help reveal the nature of Scotian Shelf Water and Slope Water inflows. Proportional inflows of nutrient-rich Slope Waters and nutrient-poor Scotian Shelf Waters alternate episodically with one another on time scales of months to several years, creating a variable nutrient field upon which the biological productivities of the Gulf of Maine and Georges Bank depend. Unlike decades past, the inflows of Slope Waters of either type do not appear to be correlated with the North Atlantic Oscillation, which had been shown earlier to influence the relative proportions of the two Slope Waters, WSW and LSW, that enter the Gulf. We suggest that of greater importance in recent years are more frequent, episodic influxes of colder, fresher, less dense, and low-nutrient Scotian Shelf Water into the Gulf of Maine, and concomitant reductions in the inflow of deep, nutrient-rich Slope Waters. We also discuss evidence of modified Gulf Stream ring water that penetrated to Jordan Basin in summer of 2013. PMID:27721519

Water Masses and Nutrient Sources to the Gulf of Maine.

PubMed

Townsend, David W; Pettigrew, Neal R; Thomas, Maura A; Neary, Mark G; McGillicuddy, Dennis J; O'Donnell, James

2015-01-01

The Gulf of Maine, a semi-enclosed basin on the continental shelf of the northwest Atlantic Ocean, is fed by surface and deep water flows from outside the Gulf: Scotian Shelf Water from the Nova Scotian shelf that enters the Gulf at the surface, and Slope Water that enters at depth and along the bottom through the Northeast Channel. There are two types of Slope Water, Labrador Slope Water (LSW) and Warm Slope Water (WSW); it is these deep water masses that are the major source of dissolved inorganic nutrients to the Gulf. It has been known for some time that the volume inflow of Slope Waters of either type that enters the Gulf of Maine is variable, that it co-varies with the magnitude of inflowing Scotian Shelf Water, and that periods of greater inflows of Scotian Shelf Water have become more frequent in recent years, accompanied by reduced Slope Water inflows. We present here analyses of a ten-year record of data collected by moored sensors in Jordan Basin, in the interior Gulf of Maine, and in the Northeast Channel, along with recent and historical hydrographic and nutrient data, that help reveal the nature of Scotian Shelf Water and Slope Water inflows. Proportional inflows of nutrient-rich Slope Waters and nutrient-poor Scotian Shelf Waters alternate episodically with one another on time scales of months to several years, creating a variable nutrient field upon which the biological productivities of the Gulf of Maine and Georges Bank depend. Unlike decades past, the inflows of Slope Waters of either type do not appear to be correlated with the North Atlantic Oscillation, which had been shown earlier to influence the relative proportions of the two Slope Waters, WSW and LSW, that enter the Gulf. We suggest that of greater importance in recent years are more frequent, episodic influxes of colder, fresher, less dense, and low-nutrient Scotian Shelf Water into the Gulf of Maine, and concomitant reductions in the inflow of deep, nutrient-rich Slope Waters. We also discuss evidence of modified Gulf Stream ring water that penetrated to Jordan Basin in summer of 2013.

Comparative study of enteric viruses, coliphages and indicator bacteria for evaluating water quality in a tropical high-altitude system

PubMed Central

2009-01-01

Background Bacteria used as indicators for pathogenic microorganisms in water are not considered adequate as enteric virus indicators. Surface water from a tropical high-altitude system located in Mexico City that receives rainwater, treated and non-treated wastewater used for irrigation, and groundwater used for drinking, was studied. Methods The presence of enterovirus, rotavirus, astrovirus, coliphage, coliform bacteria, and enterococci was determined during annual cycles in 2001 and 2002. Enteric viruses in concentrated water samples were detected by reverse transcriptase-polymerase chain reaction (RT-PCR). Coliphages were detected using the double agar layer method. Bacteria analyses of the water samples were carried out by membrane filtration. Results The presence of viruses and bacteria in the water used for irrigation showed no relationship between current bacterial indicator detection and viral presence. Coliphages showed strong association with indicator bacteria and enterovirus, but weak association with other enteric viruses. Enterovirus and rotavirus showed significant seasonal differences in water used for irrigation, although this was not clear for astrovirus. Conclusion Coliphages proved to be adequate faecal pollution indicators for the irrigation water studied. Viral presence in this tropical high-altitude system showed a similar trend to data previously reported for temperate zones. PMID:19860917

One-year Surveillance of Human Enteric Viruses in Raw and Treated Wastewaters, Downstream River Waters, and Drinking Waters.

PubMed

Iaconelli, M; Muscillo, M; Della Libera, S; Fratini, M; Meucci, L; De Ceglia, M; Giacosa, D; La Rosa, G

2017-03-01

Human enteric viruses are a major cause of waterborne diseases, and can be transmitted by contaminated water of all kinds, including drinking and recreational water. The objectives of the present study were to assess the occurrence of enteric viruses (enterovirus, norovirus, adenovirus, hepatitis A and E virus) in raw and treated wastewaters, in rivers receiving wastewater discharges, and in drinking waters. Wastewater treatment plants' (WWTP) pathogen removal efficiencies by adenovirus quantitative real-time PCR and the presence of infectious enterovirus, by cell culture assays, in treated wastewaters and in surface waters were also evaluated. A total of 90 water samples were collected: raw and treated wastewaters (treated effluents and ultrafiltered water reused for industrial purposes), water from two rivers receiving treated discharges, and drinking water. Nested PCR assays were used for the identification of viral DNA/RNA, followed by direct amplicon sequencing. All raw sewage samples (21/21), 61.9 % of treated wastewater samples (13/21), and 25 % of ultrafiltered water samples (3/12) were contaminated with at least one viral family. Multiple virus families and genera were frequently detected. Mean positive PCRs per sample decreased significantly from raw to treated sewage and to ultrafiltered waters. Moreover, quantitative adenovirus data showed a reduction in excess of 99 % in viral genome copies following wastewater treatment. In surface waters, 78.6 % (22/28) of samples tested positive for one or more viruses by molecular methods, but enterovirus-specific infectivity assays did not reveal infectious particles in these samples. All drinking water samples tested negative for all viruses, demonstrating the effectiveness of treatment in removing viral pathogens from drinking water. Integrated strategies to manage water from all sources are crucial to ensure water quality.

MTBE OXIDATION BYPRODUCTS FROM THE TREATMENT OF SURFACE WATERS BY OZONATION AND UV-OZONATION

EPA Science Inventory

In recent years, there has been considerable concern over the release of methyl tert-butyl ether (MTBE), as gasoline additive, into the aquifers used as potable water sources. MTBE readily dissolves in water and has entered the environment via gasoline spills and leaking...

Simultaneous concentration of bovine viruses and agricultural zoonotic bacteria from water using sodocalcic glass wool filters

USDA-ARS?s Scientific Manuscript database

Infiltration and runoff from manured agricultural fields can result in livestock pathogens reaching groundwater and surface waters. Here, we measured the effectiveness of glass wool filters to simultaneously concentrate enteric viruses and bacteria of bovine origin from water. The recovery efficienc...

From source to filter: changes in bacterial community composition during potable water treatment.

PubMed

Zanacic, Enisa; McMartin, Dena W; Stavrinides, John

2017-06-01

Rural communities rely on surface water reservoirs for potable water. Effective removal of chemical contaminants and bacterial pathogens from these reservoirs requires an understanding of the bacterial community diversity that is present. In this study, we carried out a 16S rRNA-based profiling approach to describe the bacterial consortia in the raw surface water entering the water treatment plants of 2 rural communities. Our results show that source water is dominated by the Proteobacteria, Bacteroidetes, and Cyanobacteria, with some evidence of seasonal effects altering the predominant groups at each location. A subsequent community analysis of transects of a biological carbon filter in the water treatment plant revealed a significant increase in the proportion of Proteobacteria, Acidobacteria, Planctomycetes, and Nitrospirae relative to raw water. Also, very few enteric coliforms were identified in either the source water or within the filter, although Mycobacterium was of high abundance and was found throughout the filter along with Aeromonas, Legionella, and Pseudomonas. This study provides valuable insight into bacterial community composition within drinking water treatment facilities, and the importance of implementing appropriate disinfection practices to ensure safe potable water for rural communities.

Removal of bacterial fecal indicators, coliphages and enteric adenoviruses from waters with high fecal pollution by slow sand filtration.

PubMed

Bauer, Rosalie; Dizer, Halim; Graeber, Ingeborg; Rosenwinkel, Karl-Heinz; López-Pila, Juan M

2011-01-01

The aim of the present study was to estimate the performance of slow sand filtration (SSF) facilities, including the time needed for reaching stabilization (maturation), operated with surface water bearing high fecal contamination, representing realistic conditions of rivers in many emerging countries. Surface water spiked with wastewater was infiltrated at different pore water velocities (PWV) and samples were collected at different migration distances. The samples were analyzed for phages and to a lesser extent for fecal bacteria and enteric adenoviruses. At the PWV of 50 cm/d, at which somatic phages showed highest removal, their mean log(10) removal after 90 cm migration was 3.2. No substantial differences of removal rates were observed at PWVs between 100 and 900 cm/d (2.3 log(10) mean removal). The log(10) mean removal of somatic phages was less than the observed for fecal bacteria and tended more towards that of enteric adenoviruses This makes somatic phages a potentially better process indicator than Escherichia coli for the removal of viruses in SSF. We conclude that SSF, and by inference in larger scale river bank filtration (RBF), is an excellent option as a component in multi-barrier systems for drinking water treatment also in areas where the sources of raw water are considerably fecally polluted, as often found in many emerging countries. Copyright © 2010 Elsevier Ltd. All rights reserved.

Hydrology of the coastal sabkhas of Abu Dhabi, United Arab Emirates

USGS Publications Warehouse

Sanford, Ward E.; Wood, Warren W.

2001-01-01

Water fluxes were estimated and a water budget developed for the land surface and a surficial 10-m-deep section of the coastal sabkhas that extend from the city of Abu Dhabi, United Arab Emirates, west to the border with Saudi Arabia. The fluxes were estimated on the basis of water levels and hydraulic conductivities measured in wells and evaporation rates measured with a humidity chamber. In contrast with conceptual models proposed in earlier studies, groundwater inflow is estimated to be small, whereas the largest components of the water budget are recharge from rainfall and evaporation from the water table. Estimates within a rectilinear volume of sabkha, defined as 1 m wide by 10 km long by 10 m deep, indicate that about 1 m3/year of water enters and exits by lateral groundwater flow; 40–50 m3/year enters by upward leakage; and 640 m3/year enters by recharge from rainfall. Based on the water and solute fluxes estimated for the upward leakage into the sabkha, 7–8 pore volumes of brine have entered the sabkha from below since the time the sabkha became saturated (7,000 years ago) as a result of the last global sea-level rise.

Prevalence of E. coli, Salmonella spp. and L. monocytogenes in non-traditional irrigation waters in the Mid-Atlantic U.S.: a conserve project

USDA-ARS?s Scientific Manuscript database

Introduction: Surface and non-traditional irrigation water (SNIW) sources can increase the irrigation water supplies without consuming potable water. However, these sources must be evaluated for enteric pathogens that could adulterate crops intended for human consumption and comply with Food Safety ...

Use of chemical and isotopic tracers to characterize the interactions between ground water and surface water in mantled karst

DOE Office of Scientific and Technical Information (OSTI.GOV)

Katz, B.G.; Davis, J.H.; Coplen, T.B.

1997-11-01

In the mantled karst terrane of northern Florida, the water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface. Chemical and isotopic analyses [{sup 18}O/{sup 16}O ({delta}{sup 18}O), {sup 2}H/{sup 1}H ({delta}D), {sup 13}C/{sup 12}C ({delta}{sup 13}C), tritium ({sup 3}H), and strontium-87/strontium-86 ({sup 87}Sr/{sup 86}Sr)] along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of ground water as it evolves downgradient in two systems. In one system, surface water enters the Upper Florida aquifer through a sinkhole located in the Northern Highlandsmore » physiographic unit. In the other system, surface water enters the aquifer through a sinkhole lake (Lake Bradford) in the Woodville Karst Plain. Differences in the composition of water isotopes ({delta}{sup 18}O and {delta}D) in rainfall, ground water, and surface water were used to develop mixing models of surface water (leakage of water to the Upper Floridan aquifer from a sinkhole lake and a sinkhole) and ground water. Using mass-balance calculations, based on differences in {delta}{sup 18}O and {delta}D, the proportion of lake water that mixed with meteoric water ranged from 7 to 86% in water from wells located in close proximity to lake Bradford. In deeper parts of the Upper Floridan aquifer, water enriched in {sup 18}O and D from five of 12 samples municipal wells indicated that recharge from a sinkhole (1 to 24%) and surface water with an evaporated isotopic signature (2 to 32%) was mixing with ground water. The solute isotopes, {delta}{sup 13}C and {sup 87}Sr/{sup 86}Sr, were used to test the sensitivity of binary and ternary mixing models, and to estimate the amount of mass transfer of carbon and other dissolved species in geochemical reactions.« less

Spatial Variability of Factors Influencing the Distribution of Triclosan in Sediments and Water of an Urbanized Estuarine Embayment

EPA Science Inventory

Triclosan (TCS) is a broad spectrum anti-microbial compound added to many consumer and personal care products. TCS enters water bodies primarily through wastewater treatment plant (WWTP) effluent and may be introduced by combined sewer overflows or surface water runoff. In estu...

40 CFR 170.130 - Pesticide safety training for workers.

Code of Federal Regulations, 2010 CFR

2010-07-01

... restricted-entry interval applies, including but not limited to, soil, water, or surfaces of plants, the..., soil, irrigation water, or drifting from nearby applications. (2) Prevent pesticides from entering your... poisonings. (vi) How to obtain emergency medical care. (vii) Routine and emergency decontamination procedures...

SEROLOGICAL RESPONSES TO CRYPTOSPORIDIUM ANTIGENS AMONG USERS OF SURFACE VERSUS UNDERGROUND DRINKING WATER SOURCES

EPA Science Inventory

Cryptosporidium oocysts have been detected in source and treated drinking waters in the United States and elsewhere. Enhanced enteric disease surveillance, initiated following detection of oocysts, has not often detected elevated rates of infection or of symptoms compatible with...

Thermally stratified pools and their use by steelhead in northern California streams

Treesearch

Jennifer L. Nielsen; Thomas E. Lisle; Vicki Ozaki

1994-01-01

Abstract - Thermal stratification occurred in pools of three rivers in northern California when inflow of cold water was sufficiently great or currents were sufficiently weak to prevent thorough mixing of water of contrasting temperatures. Surface water temperatures in such pools were commonly 3-9°C higher than those at the bottom. Cold water entered pools from...

Survival, Biofilm Formation, and Growth Potential of Environmental and Enteric Escherichia coli Strains in Drinking Water Microcosms

PubMed Central

Abberton, Cathy L.; Bereschenko, Ludmila; van der Wielen, Paul W. J. J.

2016-01-01

ABSTRACT Escherichia coli is the most commonly used indicator for fecal contamination in drinking water distribution systems (WDS). The assumption is that E. coli bacteria are of enteric origin and cannot persist for long outside their host and therefore act as indicators of recent contamination events. This study investigates the fate of E. coli in drinking water, specifically addressing survival, biofilm formation under shear stress, and regrowth in a series of laboratory-controlled experiments. We show the extended persistence of three E. coli strains (two enteric isolates and one soil isolate) in sterile and nonsterile drinking water microcosms at 8 and 17°C, with T90 (time taken for a reduction in cell number of 1 log10 unit) values ranging from 17.4 ± 1.8 to 149 ± 67.7 days, using standard plate counts and a series of (reverse transcription-)quantitative PCR [(RT-)Q-PCR] assays targeting 16S rRNA, tuf, uidA, and rodA genes and transcripts. Furthermore, each strain was capable of attaching to a surface and replicating to form biofilm in the presence of nutrients under a range of shear stress values (0.6, 2.0, and 4.4 dynes [dyn] cm−2; BioFlux system; Fluxion); however, cell numbers did not increase when drinking water flowed over the biofilm (P > 0.05 by t test). Finally, E. coli regrowth within drinking water microcosms containing polyethylene PE-100 pipe wall material was not observed in the biofilm or water phase using a combination of culturing and Q-PCR methods for E. coli. The results of this work highlight that when E. coli enters drinking water it has the potential to survive and attach to surfaces but that regrowth within drinking water or biofilm is unlikely. IMPORTANCE The provision of clean, safe drinking water is fundamental to society. WDS deliver water to consumers via a vast network of pipes. E. coli is used as an indicator organism for recent contamination events based on the premise that it cannot survive for long outside its host. A key public health concern therefore arises around the fate of E. coli on entering a WDS; its survival, ability to form a biofilm, and potential for regrowth. In particular, if E. coli bacteria have the ability to incorporate and regrow within the pipe wall biofilm of a WDS, they could reinoculate the water at a later stage. This study sheds light on the fate of environmental and enteric strains of E. coli in drinking water showing extended survival, the potential for biofilm formation under shear stress, and importantly, that regrowth in the presence of an indigenous microbial community is unlikely. PMID:27342552

Survival, Biofilm Formation, and Growth Potential of Environmental and Enteric Escherichia coli Strains in Drinking Water Microcosms.

PubMed

Abberton, Cathy L; Bereschenko, Ludmila; van der Wielen, Paul W J J; Smith, Cindy J

2016-09-01

Escherichia coli is the most commonly used indicator for fecal contamination in drinking water distribution systems (WDS). The assumption is that E. coli bacteria are of enteric origin and cannot persist for long outside their host and therefore act as indicators of recent contamination events. This study investigates the fate of E. coli in drinking water, specifically addressing survival, biofilm formation under shear stress, and regrowth in a series of laboratory-controlled experiments. We show the extended persistence of three E. coli strains (two enteric isolates and one soil isolate) in sterile and nonsterile drinking water microcosms at 8 and 17°C, with T90 (time taken for a reduction in cell number of 1 log10 unit) values ranging from 17.4 ± 1.8 to 149 ± 67.7 days, using standard plate counts and a series of (reverse transcription-)quantitative PCR [(RT-)Q-PCR] assays targeting 16S rRNA, tuf, uidA, and rodA genes and transcripts. Furthermore, each strain was capable of attaching to a surface and replicating to form biofilm in the presence of nutrients under a range of shear stress values (0.6, 2.0, and 4.4 dynes [dyn] cm(-2); BioFlux system; Fluxion); however, cell numbers did not increase when drinking water flowed over the biofilm (P > 0.05 by t test). Finally, E. coli regrowth within drinking water microcosms containing polyethylene PE-100 pipe wall material was not observed in the biofilm or water phase using a combination of culturing and Q-PCR methods for E. coli The results of this work highlight that when E. coli enters drinking water it has the potential to survive and attach to surfaces but that regrowth within drinking water or biofilm is unlikely. The provision of clean, safe drinking water is fundamental to society. WDS deliver water to consumers via a vast network of pipes. E. coli is used as an indicator organism for recent contamination events based on the premise that it cannot survive for long outside its host. A key public health concern therefore arises around the fate of E. coli on entering a WDS; its survival, ability to form a biofilm, and potential for regrowth. In particular, if E. coli bacteria have the ability to incorporate and regrow within the pipe wall biofilm of a WDS, they could reinoculate the water at a later stage. This study sheds light on the fate of environmental and enteric strains of E. coli in drinking water showing extended survival, the potential for biofilm formation under shear stress, and importantly, that regrowth in the presence of an indigenous microbial community is unlikely. Copyright © 2016, American Society for Microbiology. All Rights Reserved.

From vegetated ditches to rice fields: Thinking outside the box for pesticide mitigation

USDA-ARS?s Scientific Manuscript database

Pesticide contamination of surface waters has been a global concern for decades. In agricultural areas, pesticides enter aquatic receiving waters through irrigation and storm runoff, spray drift, or even atmospheric deposition. With increased pressure to continue producing food and fiber to sustai...

Groundwater and enteric disease: A review of the epidemiological evidence

USDA-ARS?s Scientific Manuscript database

Globally, approximately 2.2 billion people rely on groundwater for daily consumption. It is widely accepted that groundwater typically represents a more pristine source of water for human consumption than surface water resources. While this assumption is frequently the case, groundwater is not ubiqu...

Transfer rates of enteric microorganisms in recycled water during machine clothes washing.

PubMed

O'Toole, Joanne; Sinclair, Martha; Leder, Karin

2009-03-01

Approximately 15% of overall Australian household water usage is in the laundry; hence, a significant reduction in household drinking water demand could be achieved if potable-quality water used for clothes washing is replaced with recycled water. To investigate the microbiological safety of using recycled water in washing machines, bacteriophages MS-2 and PRD-1, Escherichia coli, and Cryptosporidium parvum oocysts were used in a series of experiments to investigate the transfer efficiency of enteric microorganisms from washing machine water to objects including hands, environmental surfaces, air, and fabric swatches. By determining the transference efficiency, it is possible to estimate the numbers of microorganisms that the user will be exposed to if recycled water with various levels of residual microorganisms is used in washing machines. Results, expressed as transfer rates to a given surface area per object, showed that the mean transfer efficiency of E. coli, bacteriophages MS-2 and PRD-1, and C. parvum oocysts from seeded water to fabric swatches ranged from 0.001% to 0.090%. Greatest exposure to microorganisms occurred through direct contact of hands with seeded water and via hand contact with contaminated fabric swatches. No microorganisms were detected in the air samples during the washing machine spin cycle, and transfer rates of bacteriophages from water to environmental surfaces were 100-fold less than from water directly to hands. Findings from this study provide relevant information that can be used to refine regulations governing recycled water and to allay public concerns about the use of recycled water.

Surveillance of enteric viruses and coliphages in a tropical urban catchment.

PubMed

Rezaeinejad, S; Vergara, G G R V; Woo, C H; Lim, T T; Sobsey, M D; Gin, K Y H

2014-07-01

An assessment of the occurrence and concentration of enteric viruses and coliphages was carried out in highly urbanized catchment waters in the tropical city-state of Singapore. Target enteric viruses in this study were noroviruses, adenoviruses, astroviruses and rotaviruses. In total, 65 water samples were collected from canals and the reservoir of the Marina catchment on a monthly basis over a period of a year. Quantitative PCR (qPCR) and single agar layer plaque assay (SAL) were used to enumerate target enteric viruses and coliphages in water samples, respectively. The most prevalent pathogen were noroviruses, detected in 37 samples (57%), particularly norovirus genogroup II (48%), with a mean concentration of 3.7 × 10(2) gene copies per liter. Rotavirus was the second most prevalent virus (40%) with a mean concentration of 2.5 × 10(2) GC/L. The mean concentrations of somatic and male-specific coliphages were 2.2 × 10(2) and 1.1 × 10(2) PFU/100 ml, respectively. The occurrence and concentration of each target virus and the ratio of somatic to male-specific coliphages varied at different sampling sites in the catchment. For sampling sites with higher frequency of occurrence and concentration of viruses, the ratio of somatic to male-specific coliphages was generally much lower than other sampling sites with lower incidences of enteric viruses. Overall, higher statistical correlation was observed between target enteric viruses than between enteric viruses and coliphages. However, male-specific coliphages were positively correlated with norovirus concentrations. A multi-level integrated surveillance system, which comprises the monitoring of bacterial indicators, coliphages and selected enteric viruses, could help to meet recreational and surface water quality criteria in a complex urbanized catchment. Copyright © 2014 Elsevier Ltd. All rights reserved.

Tangential-flow ultrafiltration with integrated inhibition detection for recovery of surrogates and human pathogens from large-volume source water and finished drinking water.

PubMed

Gibson, Kristen E; Schwab, Kellogg J

2011-01-01

Tangential-flow ultrafiltration was optimized for the recovery of Escherichia coli, Enterococcus faecalis, Clostridium perfringens spores, bacteriophages MS2 and PRD1, murine norovirus, and poliovirus seeded into 100-liter surface water (SW) and drinking water (DW) samples. SW and DW collected from two drinking water treatment plants were then evaluated for human enteric viruses.

Rapid removal of Chernobyl fallout from Mediterranean surface waters by biological activity

NASA Astrophysics Data System (ADS)

Fowler, Scott W.; Buat-Menard, Patrick; Yokoyama, Yuji; Ballestra, Serge; Holm, Elis; Nguyen, Huu Van

1987-09-01

The sinking of participate organic matter from the euphotic zone is an important pathway for the vertical transport of many elements and organic compounds in the sea1-3. Many natural4-5 and artificial5-7 radionuclides in surface waters are readily adsorbed onto suspended particles and are presumably scavenged and removed to depth on time scales commensurate with both particle sinking rate and retention time of the radionuclide on the particle. Previously, abyssal benthic organisms from the northeast Pacific were found to contain short-lived fission products which entered the sea surface as fallout from nuclear testing8. The presence of these radionuclides at great depth could not be explained by Stokesian settling of small fallout particles and it was hypothesized8 that zooplankton grazing in the surface layers packaged these particle-reactive radionuclides into large, relatively dense faecal pellets which rapidly sank to depth. We report here data from a time-series sediment trap experiment and concomitant zooplankton collections which show conclusively that Chernobyl radioactivity, in particular the rare earth nuclides 141Ce and 144Ce, entering the Mediterranean as a single pulse, was rapidly removed from surface waters and transported to 200m in a few days primarily by zooplankton grazing.

Surface water flooding, groundwater contamination, and enteric disease in developed countries: A scoping review of connections and consequences.

PubMed

Andrade, L; O'Dwyer, J; O'Neill, E; Hynds, P

2018-05-01

Significant volumes of research over the past four decades has sought to elucidate the social, infrastructural, economic, and human health effects of climate change induced surface flooding. To date, epidemiological and public health studies of flooding events have focused on mental health effects, vector-borne diseases, and infectious enteric disease due to floodwater contact (i.e. typically low consumption rates). The inherent nature of groundwater (i.e. out of sight, out of mind) and the widely held belief that aquifers represent a pristine source of drinking water due to natural attenuation may represent the "perfect storm" causing direct consumption of relatively large volumes of surface flood-contaminated groundwater. Accordingly, the current study sought to systematically identify and synthesize all available peer-reviewed literature pertaining to the nexus between surface flooding, groundwater contamination and human gastroenteric outcomes. Just 14 relevant studies were found to have been published during the period 1980-2017, thus highlighting the fact that this potentially significant source of climate-related exposure to environmental infection has remained understudied to date. Studies differed significantly in terms of type and data reporting procedures, making it difficult to discern clear trends and patterns. Approximately 945 confirmed cases of flood-related enteric disease were examined across studies; these concurred with almost 10,000 suspected cases, equating to approximately 20 suspected cases per confirmed case. As such, no regional, national or global estimates are available for the human gastrointestinal health burden of flood-related groundwater contamination. In light of the demonstrable public health significance of the concurrent impacts of groundwater susceptibility and climate change exacerbation, strategies to increase awareness about potential sources of contamination and motivate precautionary behaviour (e.g. drinking water testing and treatment, supply interruptions) are necessary. Mainstreaming climate adaptation concerns into planning policies will also be necessary to reduce human exposure to waterborne sources of enteric infection. Copyright © 2018 Elsevier Ltd. All rights reserved.

Presence of enteric viruses in freshwater and their removal by the conventional drinking water treatment process.

PubMed Central

Hurst, C. J.

1991-01-01

A review of results published in English or French between 1980 and 1990 was carried out to determine the levels of indigenous human enteric viruses in untreated surface and subsurface freshwaters, as well as in drinking water that had undergone the complete conventional treatment process. For this purpose, the conventional treatment process was defined as an operation that included coagulation followed by sedimentation, filtration, and disinfection. Also assessed was the stepwise efficiency of the conventional treatment process, as practised at full-scale facilities, for removing indigenous viruses from naturally occurring freshwaters. A list was compiled of statistical correlations relating to the occurrence of indigenous viruses in water. PMID:1647273

The association between campylobacteriosis, agriculture and drinking water: a case-case study in a region of British Columbia, Canada, 2005-2009.

PubMed

Galanis, E; Mak, S; Otterstatter, M; Taylor, M; Zubel, M; Takaro, T K; Kuo, M; Michel, P

2014-10-01

We studied the association between drinking water, agriculture and sporadic human campylobacteriosis in one region of British Columbia (BC), Canada. We compared 2992 cases of campylobacteriosis to 4816 cases of other reportable enteric diseases in 2005-2009 using multivariate regression. Cases were geocoded and assigned drinking water source, rural/urban environment and socioeconomic status (SES) according to the location of their residence using geographical information systems analysis methods. The odds of campylobacteriosis compared to enteric disease controls were higher for individuals serviced by private wells than municipal surface water systems (odds ratio 1·4, 95% confidence interval 1·1-1·8). In rural settings, the odds of campylobacteriosis were higher in November (P = 0·014). The odds of campylobacteriosis were higher in individuals aged ⩾15 years, especially in those with higher SES. In this region of BC, campylobacteriosis risk, compared to other enteric diseases, seems to be mediated by vulnerable drinking water sources and rural factors. Consideration should be given to further support well-water users and to further study the microbiological impact of agriculture on water.

Molecular assays for targeting human and bovine enteric viruses in coastal waters and their application for library-independent source tracking

USGS Publications Warehouse

Fong, T.-T.; Griffin, Dale W.; Lipp, E.K.

2005-01-01

Rapid population growth and urban development along waterways and coastal areas have led to decreasing water quality. To examine the effects of upstream anthropogenic activities on microbiological water quality, methods for source-specific testing are required. In this study, molecular assays targeting human enteroviruses (HEV), bovine enteroviruses (BEV), and human adenoviruses (HAdV) were developed and used to identify major sources of fecal contamination in the lower Altamaha River, Georgia. Two-liter grab samples were collected monthly from five tidally influenced stations between July and December 2002. Samples were analyzed by reverse transcription- and nested-PCR. PCR results were confirmed by dot blot hybridization. Eleven and 17 of the 30 surface water samples tested positive for HAdV and HEV, respectively. Two-thirds of the samples tested positive for either HEV or HAdV, and the viruses occurred simultaneously in 26% of samples. BEV were detected in 11 of 30 surface water samples. Binary logistic regression analysis showed that the presence of both human and bovine enteric viruses was not significantly related to either fecal coliform or total coliform levels. The presence of these viruses was directly related to dissolved oxygen and streamflow but inversely related to water temperature, rainfall in the 30 days preceding sampling, and chlorophyll-?? concentrations. The stringent host specificity of enteric viruses makes them good library-independent indicators for identification of water pollution sources. Viral pathogen detection by PCR is a highly sensitive and easy-to-use tool for rapid assessment of water quality and fecal contamination when public health risk characterization is not necessary. Copyright ?? 2005, American Society for Microbiology. All Rights Reserved.

Use of chemical and isotopic tracers to characterize the interactions between ground water and surface water in mantled karst

USGS Publications Warehouse

Katz, B.G.; Coplen, T.B.; Bullen, T.D.; Hal, Davis J.

1997-01-01

In the mantled karst terrane of northern Florida, the water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface. Chemical and isotopic analyses [18O/16O (??18O), 2H/1H (??D), 13C/12C (??13C), tritium(3H), and strontium-87/strontium-86(87Sr/86Sr)]along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of ground water as it evolves downgradient in two systems. In one system, surface water enters the Upper Floridan aquifer through a sinkhole located in the Northern Highlands physiographic unit. In the other system, surface water enters the aquifer through a sinkhole lake (Lake Bradford) in the Woodville Karst Plain. Differences in the composition of water isotopes (??18O and ??D) in rainfall, ground water, and surface water were used to develop mixing models of surface water (leakage of water to the Upper Floridan aquifer from a sinkhole lake and a sinkhole) and ground water. Using mass-balance calculations, based on differences in ??18O and ??D, the proportion of lake water that mixed with meteoric water ranged from 7 to 86% in water from wells located in close proximity to Lake Bradford. In deeper parts of the Upper Floridan aquifer, water enriched in 18O and D from five of 12 sampled municipal wells indicated that recharge from a sinkhole (1 to 24%) and surface water with an evaporated isotopic signature (2 to 32%) was mixing with ground water. The solute isotopes, ??13C and 87Sr/86Sr, were used to test the sensitivity of binary and ternary mixing models, and to estimate the amount of mass transfer of carbon and other dissolved species in geochemical reactions. In ground water downgradient from Lake Bradford, the dominant processes controlling carbon cycling in ground water were dissolution of carbonate minerals, aerobic degradation of organic matter, and hydrolysis of silicate minerals. In the deeper parts of the Upper Floridan aquifer, the major processes controlling the concentrations of major dissolved species included dissolution of calcite and dolomite, and degradation of organic matter under oxic conditions. The Upper Floridan aquifer is highly susceptible to contamination from activities at the land surface in the Tallahassee area. The presence of post-1950s concentrations of 3H in ground water from depths greater than 100 m below land surface indicates that water throughout much of the Upper Floridan aquifer has been recharged during the last 40 years. Even though mixing is likely between ground water and surface water in many parts of the study area, the Upper Floridan aquifer produces good quality water, which due to dilution effects shows little if any impact from trace elements or nutrients that are present in surface waters.The water quality of the Upper Floridan aquifer is influenced by the degree of connectivity between the aquifer and the surface water. Chemical and isotopic analyses, tritium, and strontium-87/strontium-86 along with geochemical mass-balance modeling were used to identify the dominant hydrochemical processes that control the composition of groundwater. Differences in the composition of water isotopes in rainfall, groundwater and surface water were used to develop mixing models of surface water and groundwater. Even though mixing is likely between groundwater and surface water in many parts of the study area, the Upper Floridan aquifer produces good quality water, showing little impact from trace elements present in surface waters.

How clean must our drinking water be: the importance of protective immunity.

PubMed

Frost, Floyd J; Roberts, Melissa; Kunde, Twila R; Craun, Gunther; Tollestrup, Kristine; Harter, Lucy; Muller, Tim

2005-03-01

Cryptosporidium parvum is an important cause of epidemic diarrhea. Few studies have assessed whether serological evidence of prior infection in adults is related to a reduced occurrence of enteric illness. Serum samples and enteric illness event data were obtained in 2000 and 2001 from 326 people served by 1 of 2 unfiltered surface sources or 1 groundwater source. In 2001, filtration was initiated at 1 of the surface sources. Poisson regression related illness episodes with serological responses to the 15/17- and 27-kDa Cryptosporidium antigen groups. Subjects with moderately strong responses to the 15/17-kDa antigen had <65% of the risk of all 1-3-day episodes of diarrheal or gastrointestinal illness and <40% of the risk of all >/=4-day episodes, compared with subjects without a moderately strong response. Water source, change in water treatment, and very weak responses were unrelated to illness events. Endemic Cryptosporidium infections are a common cause of diarrheal and gastrointestinal illness in persons without a moderately strong response to the 15/17-kDa antigen group. Users of surface-derived drinking water are more likely to have strong serological responses to this antigen group and may be at a lower risk of endemic gastrointestinal illness caused by Cryptosporidium infection.

Water at protein surfaces studied with femtosecond nonlinear spectroscopy

NASA Astrophysics Data System (ADS)

Bakker, Huib J.

We report on an investigation of the structure and dynamics of water molecules near protein surfaces with femtosecond nonlinear spectroscopic techniques. We measured the reorientation dynamics of water molecules near the surface of several globular protein surfaces, using polarization-resolved femtosecond infrared spectroscopy. We found that water molecules near the protein surface have a much slower reorientation than water molecules in bulk liquid water. The number of slow water molecules scales scales with the size of the hydrophobic surface of the protein. When we denature the proteins by adding an increasing amount of urea to the protein solution, we observe that the water-exposed surface increases by 50% before the secondary structure of the proteins changes. This finding indicates that protein unfolding starts with the protein structure becoming less tight, thereby allowing water to enter. With surface vibrational sum frequency generation (VSFG) spectroscopy, we studied the structure of water at the surface of antifreeze protein III. The measured VSFG spectra showed the presence of ice-like water layers at the ice-binding site of the protein in aqueous solution, at temperatures well above the freezing point. This ordered ice-like hydration layers at the protein surface likely plays an important role in the specific recognition and binding of anti-freeze protein III to nascent ice crystallites, and thus in its anti-freeze mechanism. This research is supported by the ''Nederlandse organisatie voor Wetenschappelijk Onderzoek (NWO).

Observing mass exchange with the Lofoten Basin using surface drifters

NASA Astrophysics Data System (ADS)

Dugstad, Johannes S.; LaCasce, Joe; Koszalka, Inga M.; Fer, Ilker

2017-04-01

The Lofoten Basin in the Nordic Seas plays a central role in the global overturning circulation, acting as a reservoir for northward-flowing Atlantic water. Substantial heat loss occurs here, permitting the waters to become denser and eventually sink nearer the Arctic. Idealized modeling studies and theoretical arguments suggest the warm water enters the Lofoten Basin via eddy transport from the boundary current over the adjacent continental slope. But there is no observational evidence that this is the major contribution to mass exchange between the warm Atlantic Current and the Basin. How the basin waters exit also remains a mystery. Surface drifters offer an unique possibility to study the pathways of the boundary-basin exchange of mass and heat. We thereby examine trajectories of surface drifters released in the Nordic Seas in the POLEWARD and PROVOLO experiments, and supplemented by historical data from the Global Drifter Array. Contrary to the idea that the boundary current eddies are the main source, the results suggest that fluid is entering the Lofoten Basin from all sides. However, the drifters exit preferentially in the northeast corner of the basin. This asymmetry likely contributes to the extended residence times of the warm Atlantic waters in the Lofoten Basin. We consider various measures to quantify the effect, and test whether this is captured in a high resolution numerical model.

Effectiveness of highway-drainage systems in preventing contamination of ground water by road salt, Route 25, southeastern Massachusetts; description of study area, data collection programs, and methodology

USGS Publications Warehouse

Church, P.E.; Armstrong, D.S.; Granato, G.E.; Stone, V.J.; Smith, K.P.; Provencher, P.L.

1996-01-01

Four test sites along a 7-mile section of Route 25 in southeastern Massachusetts, each representing a specific highway-drainage system, were instrumented to determine the effectiveness of the drainage systems in preventing contamination of ground water by road salt. One of the systems discharges highway runoff onsite through local drainpipes. The other systems use trunkline drainpipes through which runoff from highway surfaces, shoulders, and median strips is diverted and discharged into either a local stream or a coastal waterway. Route 25 was completed and opened to traffic in the summer of 1987. Road salt was first applied to the highway in the winter of 1987-88. The study area is on a thick outwash plain composed primarily of sand and gravel. Water-table depths range from 15 to 60 feet below land surface at the four test sites. Ground-water flow is in a general southerly direction, approximately perpendicular to the highway. Streamflow in the study area is controlled primarily by ground-water discharge. Background concentrations of dissolved chloride, sodium, and calcium-the primary constituents of road salt-are similar in ground water and surface water and range from 5 to 20, 5 to 10, and 1 to 5 milligrams per liter, respectively. Data-collection programs were developed for monitoring the application of road salt to the highway, the quantity of road-salt water entering the ground water, diverted through the highway-drainage systems, and entering a local stream. The Massachusetts Highway Department monitored road salt applied to the highway and reported these data to the U.S. Geological Survey. The U.S. Geological Survey designed and operated the ground-water, highway- drainage, and surface-water data-collection programs. A road-salt budget will be calculated for each test site so that the effectiveness of the different highway-drainage systems in preventing contamination of ground water by road salt can be determined.

Drugs in the environment: emission of drugs, diagnostic aids and disinfectants into wastewater by hospitals in relation to other sources--a review.

PubMed

Kümmerer, K

2001-11-01

After administration, pharmaceuticals are excreted by the patients into wastewater. Unused medications are sometimes disposed of in drains. The drugs enter the aquatic environment and eventually reach drinking water if they are not biodegraded or eliminated during sewage treatment. Additionally, antibiotics and disinfectants are supposed to disturb the wastewater treatment process and the microbial ecology in surface waters. Furthermore, resistant bacteria may be selected in the aeration tanks of STPs by the antibiotic substances present. Recently, pharmaceuticals have been detected in surface water, ground water and drinking water. However, only little is known about the significance of emissions from households and hospitals. A brief summary of input by different sources, occurrence, and elimination of different pharmaceutical groups such as antibiotics, anti-tumour drugs, anaesthetics and contrast media as well as AOX resulting from hospital effluent input into sewage water and surface water will be presented.

Source, movement, and effects of nitrogen and phosphorus in three ponds in the headwaters of Hop Brook, Marlborough, Massachusetts

USGS Publications Warehouse

Briggs, John C.; Silvey, William D.

1984-01-01

The headwaters of Hop Brook near Marlborough, Massachusetts, contain a series of three in-line ponds--Hager Pond, Brist Millpond, and Carding Millpond--which receive over half of their surface-water inflow as effluent from the Marlborough Easterly Wastewater Treatment Plant. These ponds have a history of summer algal blooms and fish kills. Water entering these ponds contains quantities of nitrogen and phosphorus far higher than the levels known to promote excessive growth of aquatic vegetation. As the water moves through the three ponds, nitrogen levels decrease. Although some nitrogen is lost to the atmosphere by denitrification, the bulk of the nitrogen probably is retained in the pond sediments. There is a net decrease in phosphorus in the water leaving Carding Millpond compared to the water entering Hager Pond. However, during most sampling periods, the phosphorus concentration of water leaving Carding Millpond is still above the level known to cause excessive growth of aquatic vegetation in lakes. During certain summer periods, there appears to be release of some phosphorus from the sediments in Carding and Grist Millponds. No improvement in water quality of the three ponds can be expected until the concentrations of nutrients entering Hager Pond are reduced to levels that will not support excessive growth of aquatic vegetation. (USGS)

Freshwater molluscs as indicators of bioavailability and toxicity of metals in surface-water systems

USGS Publications Warehouse

Elder, John F.; Collins, Jerilyn J.; Ware, George W.

1991-01-01

During the past several decades, studies from a variety of locations have demonstrated widespread occurrence of metals in surface waters at concentrations significantly higher than background levels. Elevated concentrations are not limited to certain water types or polluted areas; they appear in all types of systems and in all geographic areas. It is clear that metals enter the aquatic systems from diverse sources, both point and nonpoint, and they can be readily transported from one system to another. Transport routes include atmospheric, terrestrial, subterranean, aquatic, and biological pathways (Elder 1988; Salomons and Forstner 1984).

QUALITY ASSURANCE FOR METHODS TO DETECT HUMAN ENTERIC VIRUSES IN DRINKING WATER

EPA Science Inventory

Surface or groundwaters impacted by untreated or inadequately treated domestic wastes may contain human pathogenic viruses that cause hepatitis, gastroenteritis, meningitis, encephalitis, myocarditis, diabetes, conjunctivitis and temporary or permanent paralysis. These viruses c...

Spatio-temporal variability of hyporheic exchange through a pool-riffle-pool sequence

Treesearch

Frank P. Gariglio; Daniele Tonina; Charles H. Luce

2013-01-01

Stream water enters and exits the streambed sediment due to hyporheic fluxes, which stem primarily from the interaction between surface water hydraulics and streambed morphology. These fluxes sustain a rich ecotone, whose habitat quality depends on their direction and magnitude. The spatio-temporal variability of hyporheic fluxes is not well understood over several...

Prevalence of Rotavirus Genogroup A and Norovirus Genogroup II in Bassaseachic Falls National Park Surface Waters in Chihuahua, Mexico.

PubMed

Delgado-Gardea, Ma Carmen E; Tamez-Guerra, Patricia; Gomez-Flores, Ricardo; Mendieta-Mendoza, Aurora; Zavala-Díaz de la Serna, Francisco Javier; Contreras-Cordero, Juan Francisco; Erosa-de la Vega, Gilberto; Pérez-Recoder, María Concepción; Sánchez-Ramírez, Blanca; González-Horta, Carmen; Infante-Ramírez, Rocío

2017-05-05

In areas lacking potable water treatment, drinking contaminated water may represent a public health threat. In addition to enteropathogenic bacteria and parasites, fecal contamination in water environments is associated with the transmission of enteric viruses and other causal agents of infectious disease. Rotavirus and norovirus are the main enteric viral agents responsible for diarrheic outbreaks. The aim of the present study was to detect seasonal variation of rotavirus and norovirus in the surface water at Bassaseachic Falls National Park during 2013. Rivers and streams within and nearby this park were sampled once in each season during 2013. Viral concentration was carried out by a handmade filtration equipment, using a commercial electropositive membrane coupled with the virus absortion elution technique (VIRADEL©). Detection of rotavirus and norovirus was performed by SYBR Green reverse transcription-real time polymerase chain reaction (SYBR GREEN© RT-qPCR) analyses. Norovirus genogroup II was detected in samples collected in June and October 2013. In the case of rotavirus, genogroup A was detected in March and June. The presence of rotavirus and norovirus was related to viral acute diarrhea in children less than five years of age, who were inhabiting the sampled areas. This may indicates that the contaminated water was potentially a risk factor for regional diarrheic outbreaks.

Development of an Operational Land Water Mask for MODIS Collection 6, and Influence on Downstream Data Products

NASA Technical Reports Server (NTRS)

Carroll, M. L.; DiMiceli, C. M.; Townshend, J. R. G.; Sohlberg, R. A.; Elders, A. I.; Devadiga, S.; Sayer, A. M.; Levy, R. C.

2016-01-01

Data from the Moderate Resolution Imaging Spectro-radiometer (MODIS)on-board the Earth Observing System Terra and Aqua satellites are processed using a land water mask to determine when an algorithm no longer needs to be run or when an algorithm needs to follow a different pathway. Entering the fourth reprocessing (Collection 6 (C6)) the MODIS team replaced the 1 km water mask with a 500 m water mask for improved representation of the continental surfaces. The new water mask represents more small water bodies for an overall increase in water surface from 1 to 2 of the continental surface. While this is still a small fraction of the overall global surface area the increase is more dramatic in certain areas such as the Arctic and Boreal regions where there are dramatic increases in water surface area in the new mask. MODIS products generated by the on-going C6 reprocessing using the new land water mask show significant impact in areas with high concentrations of change in the land water mask. Here differences between the Collection 5 (C5) and C6 water masks and the impact of these differences on the MOD04 aerosol product and the MOD11 land surface temperature product are shown.

30 CFR 817.15 - Casing and sealing of underground openings: Permanent.

Code of Federal Regulations, 2013 CFR

2013-07-01

... be designed to prevent access to the mine workings by people, livestock, fish and wildlife, machinery and to keep acid or other toxic drainage from entering ground or surface waters. [44 FR 15422, Mar. 13...

30 CFR 817.15 - Casing and sealing of underground openings: Permanent.

Code of Federal Regulations, 2014 CFR

2014-07-01

... be designed to prevent access to the mine workings by people, livestock, fish and wildlife, machinery and to keep acid or other toxic drainage from entering ground or surface waters. [44 FR 15422, Mar. 13...

30 CFR 817.15 - Casing and sealing of underground openings: Permanent.

Code of Federal Regulations, 2012 CFR

2012-07-01

... be designed to prevent access to the mine workings by people, livestock, fish and wildlife, machinery and to keep acid or other toxic drainage from entering ground or surface waters. [44 FR 15422, Mar. 13...

30 CFR 817.15 - Casing and sealing of underground openings: Permanent.

Code of Federal Regulations, 2011 CFR

2011-07-01

... be designed to prevent access to the mine workings by people, livestock, fish and wildlife, machinery and to keep acid or other toxic drainage from entering ground or surface waters. [44 FR 15422, Mar. 13...

Occurrence and distribution of pesticide compounds in surface water of the Santa Ana basin, California, 1998-2001

USGS Publications Warehouse

Kent, Robert; Belitz, Kenneth; Altmann, Andrea J.; Wright, Michael T.; Mendez, Gregory O.

2005-01-01

A study of the occurrence and distribution of pesticide compounds in surface water of the highly urbanized Santa Ana Basin, California, was done as part of the U.S. Geological Survey's National Water-Quality Assessment Program (NAWQA). One-hundred and forty-eight samples were collected from 23 sites, and analyzed for pesticide compounds during the study period from November 1998 to September 2001. Sixty-six different pesticide compounds were detected at varying frequencies and concentrations, and one or more pesticides were detected in 92 percent of the samples. All pesticide concentrations were below maximum levels permitted in drinking water. However, two compounds-diazinon and diuron-exceeded nonenforceable drinking water health-advisory levels in at least one stream sample, and five compounds exceeded guidelines to protect aquatic life-carbaryl, chlorpyrifos, diazinon, lindane, and malathion. Twenty-two pesticide compounds were detected in at least 25 percent of the samples collected from any one fixed site. These are identified as 'major' pesticide compounds and are emphasized in this report. The degree to which pesticides were used in the basin, as well as their physical-chemical properties, are important explanatory factors in stream pesticide occurrence, and most pesticides probably enter streams with urban runoff. Stormflow substantially increases urban runoff, and storm effects on stream pesticide concentrations sometimes persist for several days or weeks after the storm. Water sources other than urban runoff also deliver pesticide compounds to surface water in the basin. For example, atrazine may enter streams in gaining reaches where ground water carries high loads as a result of historical use in the basin. Also, the data suggest that lindane, and perhaps bromacil, are present in treated wastewater, the predominant source of water to streams in the Santa Ana Basin.

Sulfur, a Key Water Quality Issue in the Everglades

NASA Astrophysics Data System (ADS)

Orem, W. H.; Lerch, H. E.; Bates, A. L.; Corum, M.; Beck, M.; Kleckner, S.

2002-05-01

Sulfur is an important water quality issue in the Everglades because of its role in microbial sulfate reduction and the methylation of mercury. Methylmercury (MeHg), a neurotoxin that is bioaccumulated, has been found in high concentrations in freshwater fish from the Everglades, and poses a potential threat to fish-eating wildlife and to human health through fish consumption. Sulfur appears to play a key role in regulating both the magnitude and distribution of MeHg in the Everglades. Freshwater wetlands typically have low sulfur concentrations, but marshes in portions of the northern Everglades have average surface water sulfate concentrations of 60 mg/l, compared to 1 mg/l or less at background sites. Marsh areas with excess sulfate are concentrated near sites of canal discharge and along canal levees. The canal water that is discharged into the marshes appears to be the major source of excess sulfate entering the Everglades. This canal water drains the Everglades Agricultural Area (EAA) and has sulfate concentrations averaging over 70 mg/l and periodically approaching 200 mg/l. We used sulfate concentration data and the sulfur (d34S) isotopic composition of sulfate in marsh surface water, canal water, rainwater, and groundwater to trace the source of the excess sulfate entering the Everglades. Results show that canal water from the EAA is the major source of excess sulfate entering the Everglades. Furthermore, canal water with the highest sulfate concentrations had d34S values of +16 per mil, similar to the d34S signature of agricultural sulfur used as a soil amendment in the EAA. Rainwater has too little sulfate to account for the high sulfate concentrations observed in the canals and in large portions of the Everglades. Groundwater beneath the present day Everglades generally has either too low a sulfate concentration or a d34S signature that is inconsistent with that of surface water in the Everglades. The excess sulfate entering the Everglades from canal discharge stimulates sulfate reduction and sulfide buildup in the sediments. This lowers redox potentials in sulfur-contaminated areas to values more reducing than natural, which may affect macrophyte growth in the Everglades by limiting oxygen penetration to roots. Excess sulfur has two differential effects with respect to MeHg production: stimulation through increased sulfate reduction, and inhibition through buildup of excess sulfide in sediment porewater. The balance between these two effects influences the magnitude and distribution of MeHg production in the Everglades. Results from this study and research of others suggest that the MeHg problem in the Everglades results largely from two factors: (1) increased fallout of mercury on the ecoxyxtem, and (2) sulfur contamination of the ecosystem from agricultural runoff.

Drugs, diagnostic agents and disinfectants in wastewater and water--a review.

PubMed

Kümmerer, K

2000-01-01

After administration pharmaceuticals are excreted by the patients into the aquatic environment via wastewater. Unused medications are sometimes disposed of in drains. The drugs may enter the aquatic environment and eventually reach drinking water, if they are not biodegraded or eliminated during sewage treatment. Additionally, antibiotics and disinfectants are assumed to disturb the wastewater treatment process and the microbial ecology in surface waters. Furthermore, resistant bacteria may be selected in the aeration tanks of sewage treatment plants by the antibiotic substances present. Since the 1980s, data on the occurrence of pharmaceuticals in natural surface waters and the effluents of sewage treatment plants have been reported. More recently, pharmaceuticals have been detected in ground and drinking water. However, only little is known about the risk imposed on humans by pharmaceuticals and their metabolites in surface and drinking water. An overview of input, occurrence, elimination (e.g. biodegradability) and possible effects of different pharmaceutical groups such as anti-tumour drugs, antibiotics and contrast media as well as AOX resulting from hospitals effluent input into sewage water and surface water is presented.

Nano-Pervaporation Membrane with Heat Exchanger Generates Medical-Grade Water

NASA Technical Reports Server (NTRS)

Tsai, Chung-Yi; Alexander, Jerry

2009-01-01

A nanoporous membrane is used for the pervaporation process in which potable water is maintained, at atmospheric pressure, on the feed side of the membrane. The water enters the non-pervaporation (NPV) membrane device where it is separated into two streams -- retentate water and permeated water. The permeated pure water is removed by applying low vapor pressure on the permeate side to create water vapor before condensation. This permeated water vapor is subsequently condensed by coming in contact with the cool surface of a heat exchanger with heat being recovered through transfer to the feed water stream.

Importance of Surface-Ground Water Interaction to Corps Total Water Management: Regional and National Examples

DTIC Science & Technology

1991-02-01

Trenton to Wilmington. Here the Potomac-Raritan- Magothy aquifer system outcrops along approximately 65 miles of the Delaware River as it enters the...industrial supply, ground water from the Potomac-Raritan- Magothy aquifer system flowed to the Delaware River. As the area became populated and industrialized...Delaware River, precipitation, or other freshwater sources to prevent saltwater intrusion of the Potomac-Raritan- Magothy aquifer. Without replenishment

Compatible Goals: Defense and Environmental Protection

DTIC Science & Technology

1984-03-22

Remedial Action Site. AD-P004 146 Treatment of Wastewater (Red Water ) Resulti g from TNT Trinitrotoluene) Purification. AD-P004 147 Location of Volatile... Availabilit C040e3 _Vafl" -,ior OEC 5 1984 Ths document has been appeoved Dist Spool.A distribution.Is unlimiedL..... .. . COMFATABLE GOALS : DEFENSE AND...surface water to the same good biological quality as the water entering the installation. 4. Conserve fossil fuel energy to the highest degree possi

Green Pharmacy & PharmEcovigilance: Prescribing and the Planet

EPA Science Inventory

Active pharmaceutical ingredients (APIs) are well documented as ubiquitous contaminants in the environment, especially in surface waters. Although their primary source is excretion and bathing, a secondary route by which many APIs enter the environment is disposal of unwanted, le...

Water budget and flow attenuation in a small montane meadow in the Sierra Nevada, California

NASA Astrophysics Data System (ADS)

Mancuso, L. A.; Cornwell, K.

2011-12-01

The purpose of this study was to assess how montane meadows aid in flow attenuation and store groundwater. The Van Vleck meadow, a 73 acre relatively healthy montane meadow in the Sierra Nevada of northern California was chosen for this analysis due to its protected status (in the Eldorado National Forest) and drainage infrastructure (culverts managing flow into and out of the meadow). A water budget for the meadow was developed to understand the quantity and timing of water entering and leaving the meadow throughout the 2009-2010 water year. The water storage capacity was estimated from data collected from piezometers, seismic refraction surveys and weirs. Flow attenuation parameters were assessed by comparing water reservoir increases and decreases during specific precipitation events. Results suggest that the meadow does slow down surface water pass through. An imbalance of surface flow in versus surface flow out suggests that surplus inflow waters may be recharging deeper aquifer systems via bedrock fractures although additional work is necessary to confirm this connection.

Spatial heterogeneity of mobilization processes and input pathways of herbicides into a brook in a small agricultural catchment

NASA Astrophysics Data System (ADS)

Doppler, Tobias; Lück, Alfred; Popow, Gabriel; Strahm, Ivo; Winiger, Luca; Gaj, Marcel; Singer, Heinz; Stamm, Christian

2010-05-01

Soil applied herbicides can be transported from their point of application (agricultural field) to surface waters during rain events. There they can have harmful effects on aquatic species. Since the spatial distribution of mobilization and transport processes is very heterogeneous, the contributions of different fields to the total load in a surface water body may differ considerably. The localization of especially critical areas (contributing areas) can help to efficiently minimize herbicide inputs to surface waters. An agricultural field becomes a contributing area when three conditions are met: 1) herbicides are applied, 2) herbicides are mobilized on the field and 3) the mobilized herbicides are transported rapidly to the surface water. In spring 2009, a controlled herbicide application was performed on corn fields in a small (ca 1 km2) catchment with intensive crop production in the Swiss plateau. Subsequently water samples were taken at different locations in the catchment with a high temporal resolution during rain events. We observed both saturation excess and hortonian overland flow during the field campaign. Both can be important mobilization processes depending on the intensity and quantity of the rain. This can lead to different contributing areas during different types of rain events. We will show data on the spatial distribution of herbicide loads during different types of rain events. Also the connectivity of the fields with the brook is spatially heterogeneous. Most of the fields are disconnected from the brook by internal sinks in the catchment, which prevents surface runoff from entering the brook directly. Surface runoff from these disconnected areas can only enter the brook rapidly via macropore-flow into tile drains beneath the internal sinks or via direct shortcuts to the drainage system (maintenance manholes, farmyard or road drains). We will show spatially distributed data on herbicide concentration in purely subsurface systems which shows how important such input pathways can be.

Organic contaminants in Great Lakes tributaries: Identification of watersheds and chemicals of greatest concern

EPA Science Inventory

Trace organic contaminant concentrations in some Great Lakes tributaries indicate potential for adverse effects on aquatic organisms. Chemicals used in agriculture, industry, and households enter surface waters via variety of sources, including urban and agricultural runoff, sewa...

Sea surface salinity of the Eocene Arctic Azolla event using innovative isotope modeling

NASA Astrophysics Data System (ADS)

Speelman, E. N.; Sewall, J. O.; Noone, D.; Huber, M.; Sinninghe Damste, J. S.; Reichart, G. J.

2009-04-01

With the realization that the Eocene Arctic Ocean was covered with enormous quantities of the free floating freshwater fern Azolla, new questions regarding Eocene conditions facilitating these blooms arose. Our present research focuses on constraining the actual salinity of, and water sources for, the Eocene Arctic basin through the application of stable water isotope tracers. Precipitation pathways potentially strongly affect the final isotopic composition of water entering the Arctic Basin. Therefore we use the Community Atmosphere Model (CAM3), developed by NCAR, combined with a recently developed integrated isotope tracer code to reconstruct the isotopic composition of global Eocene precipitation and run-off patterns. We further addressed the sensitivity of the modeled hydrological cycle to changes in boundary conditions, such as pCO2, sea surface temperatures (SSTs) and sea ice formation. In this way it is possible to assess the effect of uncertainties in proxy estimates of these parameters. Overall, results of all runs with Eocene boundary conditions, including Eocene topography, bathymetry, vegetation patterns, TEX86 derived SSTs and pCO2 estimates, show the presence of an intensified hydrological cycle with precipitation exceeding evaporation in the Arctic region. Enriched, precipitation weighted, isotopic values of around -120‰ are reported for the Arctic region. Combining new results obtained from compound specific isotope analyses (δD) on terrestrially derived n-alkanes extracted from Eocene sediments, and model outcomes make it possible to verify climate reconstructions for the middle Eocene Arctic. Furthermore, recently, characteristic long-chain mid-chain ω20 hydroxy wax constituents of Azolla were found in ACEX sediments. δD values of these C32 - C36 diols provide insight into the isotopic composition of the Eocene Arctic surface water. As the isotopic signature of the runoff entering the Arctic is modelled, and the final isotopic composition of the surface waters can be deduced from the isotopic composition of the diols, we can calculate the degree of mixing between freshwater (isotopically light) and seawater (isotopically heavy) in the surface waters. This way we quantify Eocene Arctic surface water salinity, which in turn will shed light on the degree of (seasonal) mixing and stratification.

Prevalence of Rotavirus Genogroup A and Norovirus Genogroup II in Bassaseachic Falls National Park Surface Waters in Chihuahua, Mexico

PubMed Central

Delgado-Gardea, Ma. Carmen E.; Tamez-Guerra, Patricia; Gomez-Flores, Ricardo; Mendieta-Mendoza, Aurora; Zavala-Díaz de la Serna, Francisco Javier; Contreras-Cordero, Juan Francisco; Erosa-de la Vega, Gilberto; Pérez-Recoder, María Concepción; Sánchez-Ramírez, Blanca; González-Horta, Carmen; Infante-Ramírez, Rocío

2017-01-01

In areas lacking potable water treatment, drinking contaminated water may represent a public health threat. In addition to enteropathogenic bacteria and parasites, fecal contamination in water environments is associated with the transmission of enteric viruses and other causal agents of infectious disease. Rotavirus and norovirus are the main enteric viral agents responsible for diarrheic outbreaks. The aim of the present study was to detect seasonal variation of rotavirus and norovirus in the surface water at Bassaseachic Falls National Park during 2013. Rivers and streams within and nearby this park were sampled once in each season during 2013. Viral concentration was carried out by a handmade filtration equipment, using a commercial electropositive membrane coupled with the virus absortion elution technique (VIRADEL©). Detection of rotavirus and norovirus was performed by SYBR Green reverse transcription-real time polymerase chain reaction (SYBR GREEN© RT-qPCR) analyses. Norovirus genogroup II was detected in samples collected in June and October 2013. In the case of rotavirus, genogroup A was detected in March and June. The presence of rotavirus and norovirus was related to viral acute diarrhea in children less than five years of age, who were inhabiting the sampled areas. This may indicates that the contaminated water was potentially a risk factor for regional diarrheic outbreaks. PMID:28475152

Locating Shallow Groundwater Discharge to Streams Near Concentrated Animal Feeding Operations Using Aerial Infrared Thermography: A Novel Potential Pollution Detection Method

NASA Astrophysics Data System (ADS)

Mapes, K. L.; Pricope, N. G.

2017-12-01

The Cape Fear River Basin (CFRB) has some of the highest densities of concentrated animal feeding operations (CAFO) in the United States (factoryfarmmap.org) and was recently named one of the country's most endangered rivers (americanrivers.org). There is high potential for CAFO land use to degrade stream water quality by introducing pollutants, primarily nitrates and fecal coliform, into sub-surface and surface waters. The regionally high water table in the Lower CFRB increases the risk of water quality degradation due to increased connectivity of ground- and surface water. The Lower CFRB is periodically subjected to frequent or intense hurricanes, which have been shown to exacerbate water quality issues associated with CAFOs. Additionally, the growing population in this region is placing more pressure on an already taxed water source and will continue to rely on the Cape Fear River for drinking water and wastewater discharge. While there are documented occurrences of groundwater contamination from CAFOs, we still have little understanding on how and where pollution may be entering streams by shallow sub-surface discharge. Shallow groundwater discharge to streams is becoming easier to detect using thermal infrared imaging cameras onboard unmanned aerial systems. The temperature differences between groundwater and stream water are easily distinguished in the resulting images. While this technology cannot directly measure water quality, it can locate areas of shallow groundwater discharge that can later be tested for pollutants using conventional methods. We will utilize a thermal infrared camera onboard a SenseFly eBee Plus to determine the feasibility of using this technology on a larger scale within the Lower CFRB as an inexpensive means of identifying sites of potential pollution input. Aerial surveys will be conducted in two sub-watersheds: one containing swine CAFO and a control that lacks swine CAFO. Information from this study can be integrated into subsequent water quality models within geographic information systems. Understanding how and where CAFO-related pollution is entering streams will also greatly assist scientists, conservationists, and farmers with designing experiments and implementing best management practices that produce measurable improvements to water quality.

EVALUATING THE SENSITIVITY OF SCREENING-LEVEL VAPOR INTRUSTION MODELS

EPA Science Inventory

Vapor intrusion is defined as the migration of volatile chemicals from the subsurface into overlying buildings. Volatile organic contaminants (VOCs) in soil or ground water can volatilize into soil gas and be transported towards the land surface where it can enter homes or busin...

Occurrence and quality of surface water and ground water within the Yavapai-Prescott Indian Reservation, central Arizona, 1994-98

USGS Publications Warehouse

Littin, Gregory R.; Truini, Margot; Pierce, Herbert A.; Baum, Brad M.

2000-01-01

The Yavapai-Prescott Indian Reservation encompasses about 1,395 acres in central Arizona adjacent to the city of Prescott. From October 1994 to September 1997, the annual average rainfall was 14.9 inches and the total annual streamflow leaving the reservation along Granite Creek was about 430 acre-feet more than the amount of streamflow entering the reservation. The channel-fill and valley-fill sediments within the flood plain of Granite Creek make up the principal aquifer. The only ground-water development is from spring discharge that is being contained for livestock and wildlife use. About 29 acre-feet of ground water leaves the reservation each year after discharging into Granite Creek. Water levels in wells throughout the reservation reflect seasonal variations in rainfall and snowmelt. Surface water and ground water on the reservation are calcium bicarbonate types. Specific-conductance field measurements ranged from 187 to 724 microsiemens per centimeter for surface water and 381 to 990 microsiemens per centimeter for ground water. Fecal streptococcal bacteria and fecal coliform bacteria in the surface water make the water unsuitable for domestic use. Some volatile and semivolatile organic compounds were detected in samples of surface water, ground water, and streambed sediment. The potential for contamination exists from point and nonpoint sources on and off the reservation.

In-Package Chemistry Abstraction

DOE Office of Scientific and Technical Information (OSTI.GOV)

E. Thomas

2004-11-09

This report was developed in accordance with the requirements in ''Technical Work Plan for: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package'' (BSC 2004 [DIRS 171583]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA). The scope of this report is to describe the development and validation of the in-package chemistry model. The in-package model is a combination of two models, amore » batch reactor model that uses the EQ3/6 geochemistry-modeling tool, and a surface complexation model that is applied to the results of the batch reactor model. The batch reactor model considers chemical interactions of water with the waste package materials and the waste form for commercial spent nuclear fuel (CSNF) waste packages and codisposed waste packages that contain both high-level waste glass (HLWG) and DOE spent fuel. The surface complexation model includes the impact of fluid-surface interactions (i.e., surface complexation) on the resulting fluid composition. The model examines two types of water influx: (1) the condensation of water vapor that diffuses into the waste package, and (2) seepage water that enters the waste package from the drift as a liquid. (1) Vapor Influx Case: The condensation of vapor onto the waste package internals is simulated as pure H2O and enters at a rate determined by the water vapor pressure for representative temperature and relative humidity conditions. (2) Water Influx Case: The water entering a waste package from the drift is simulated as typical groundwater and enters at a rate determined by the amount of seepage available to flow through openings in a breached waste package. TSPA-LA uses the vapor influx case for the nominal scenario for simulations where the waste package has been breached but the drip shield remains intact, so all of the seepage flow is diverted from the waste package. The chemistry from the vapor influx case is used to determine the stability of colloids and the solubility of radionuclides available for transport by diffusion, and to determine the degradation rates for the waste forms. TSPA-LA uses the water influx case for the seismic scenario, where the waste package has been breached and the drip shield has been damaged such that seepage flow is actually directed into the waste package. The chemistry from the water influx case that is a function of the flow rate is used to determine the stability of colloids and the solubility of radionuclides available for transport by diffusion and advection, and to determine the degradation rates for the CSNF and HLW glass. TSPA-LA does not use this model for the igneous scenario. Outputs from the in-package chemistry model implemented inside TSPA-LA include pH, ionic strength, and total carbonate concentration. These inputs to TSPA-LA will be linked to the following principle factors: dissolution rates of the CSNF and HLWG, dissolved concentrations of radionuclides, and colloid generation.« less

Evaluating impacts of pulp and paper mill process changes on bioactive contaminant loading to St. Louis Bay.

EPA Science Inventory

As a convergence point for human waste streams, wastewater treatment plants are recognized as point sources through which contaminants originating from domestic, industrial, and commercial activities enter surface waters. Effluent from the Western Lake Superior Sanitary District ...

Effects of a real-time exposure to an estrogenic effluent on reproduction in the fathead minnow (Pimephales promelas)

EPA Science Inventory

Wastewater treatment plant (WWTP) effluents are a well-established point of convergence through which anthropogenic chemicals enter surface waters. Whole effluent testing guidelines were developed to screen these complex mixtures for acute toxicity. However, effects-based approac...

Background, short-term and potential long-term denitrification capacity of soils in urbanized coastal watersheds on Kiawah Island, South Carolina, USA

Treesearch

S.R. Drescher; A.J. Lewitus; S.D. Brown

2006-01-01

Urbanization is escalating in many coastal areas of the US and is associated with deteriorating water quality. Often the associated changes in land use result in an overabundance of nutrients and other types of pollution entering ground and surface waters. It is important that we understand biogeochemical transformation processes on urbanizing watersheds if we are to...

Industrial waste pollution

NASA Technical Reports Server (NTRS)

Jensen, L. D.

1972-01-01

The characteristics and effects of industrial waste pollution in the Chesapeake Bay are discussed. The sources of inorganic and organic pollution entering the bay are described. The four types of pollutants are defined as: (1) inorganic chemical wastes, (2) naturally occurring organic wastes, (3) synthetic organic wastes (exotics) and (4) thermal effluents. The ecological behavior of industrial wastes in the surface waters is analyzed with respect to surface film phenomena, interfacial phenomena, and benthis phenomena

Cu mesh's super-hydrophobic and oleophobic properties with variations in gravitational pressure and surface components for oil/water separation applications

NASA Astrophysics Data System (ADS)

Guo, Wei; Zhang, Qin; Xiao, Haibo; Xu, Jie; Li, Qintao; Pan, Xiaohui; Huang, Zhiyong

2014-09-01

The super-hydrophobic and super-oleophilic properties of various materials have been utilized to separate oil from water. These properties induce both oil penetration and water slide off. This research demonstrates that the mesh with both super-hydrophobic and oleophobic properties, with a water contact angle (WCA) higher than 150° and oil contact angle (OCA) near 140°, can also be used to separate oil from. Oil has a higher probability than water of entering into the interstice of the Cu mesh surface and passing through it due to the capillarity effect, van der Waals attractions and the effects of gravitational pressure. The modified mesh surface can easily adsorb the oil, which then forms a film, due to the very strong adhesion properties of the oil molecules. The oil film then contributes to the water sliding off. These properties can be used to separate oil from water with separation efficiencies reaching 99.3%. Additionally, the separation of an oil/water mixture using sand permeated with oil yielded separation efficiencies exceeding 90%.

Design of porous microparticles with single-micron size by novel spray freeze-drying technique using four-fluid nozzle.

PubMed

Niwa, Toshiyuki; Shimabara, Hiroko; Kondo, Masahiro; Danjo, Kazumi

2009-12-01

Spray freeze-drying (SFD) process, which is a novel particle design technique previously developed by authors, has been improved by using four-fluid nozzle (4N) instead of conventional two-fluid nozzle (2N) to expand its application in pharmaceutical industry. Aqueous spray solutions of the drug and the polymeric carrier were separately supplied into 4N, and atomized while colliding with each other at the tip of nozzle. The droplets of mixed solutions were directly immersed into liquid nitrogen and immediately frozen to form a suspension. Then, the iced droplets were lyophilized by freeze-dryer to prepare the composite particles of the drug and carrier. This process has been used in the present study to modify and enhance the dissolution profiles of poorly water-soluble drug, phenytoin. Water-soluble and enteric polymeric carriers in pharmaceutical use were used as a dissolution modifier. The SFD composite particles prepared by using 4N were fully characterized compared to those using 2N from morphological and physicochemical perspectives. It was found that the particles have fine porous structure producing vast specific surface area. Further, phenytoin was completely dispersed as amorphous state in the polymeric matrix with higher carrier ratio than phenytoin:carrier = 1:3. The dissolution of phenytoin from the water-soluble carrier-based particles was greatly enhanced because of large effective surface area and disappearance of crystalline. On the other hand, the release profiles from enteric carrier-based particles showed the typical enteric patterns, that is, delayed in acidic medium and accelerated in neutral pH. The results demonstrated that SFD technique using 4N has potential to develop the novel solubilized formulation for poorly water-soluble APIs.

Most microbeads in a preliminary survey of personal care products are smaller than the typical 330µm trawl mesh size used in surface water surveys

NASA Astrophysics Data System (ADS)

Conkle, J. L.; Baez-Del Valle, C.; Turner, J.

2016-02-01

Research on plastic debris in aquatic environments, particularly the ocean, has recently exploded due to our emerging understanding of their ubiquitous presence and organismal effects. One study estimated that hundreds of thousands of tons of plastic float at our ocean surface, while another estimated that up to 12.7 million metric tons enter the ocean in a year. These studies produced reasonable estimates of oceanic loads, but research is needed to understand the sources and properties of plastics, particularly microplastics, entering the environment. In this preliminary study, polyethylene (PE) microbeads from 6 facial scrubs, 4 body washes and 3 toothpaste products were extracted and quantified by mass and particle count for the following size classes: 50, 100, 200, 300, 400, 500 and 1000µm. Within the product classes, roughly half (face scrub, 55% and body wash, 48%) to nearly all (toothpaste, 97%) of PE microbeads on a mass basis were smaller than 300µm in diameter. When examining the size distribution by particle count, the results were even more astounding. Nearly all PE microbeads were smaller than 300µm for face scrub (95%), body wash (97%) and toothpaste (100%). The 300µm particle diameter is significant, as major surveys in the published literature (Eriksen et al., 2014; Law et al, 2014) used 330µm or greater mesh size to sample plastic debris and estimate oceanic plastic loads. Therefore, these published surveys, which are some of our best estimates of plastic debris at the ocean surface, likely underestimate total environmental loads because they may exclude half of the mass and nearly all of the individual PE microbead particles that enter our waste stream and potentially surface waters after the use of personal care products.

Prevalence, characteristics and correlates of enteric pathogenic protozoa in drinking water sources in Molyko and Bomaka, Cameroon: a cross-sectional study.

PubMed

Nsoh, Fuh Anold; Wung, Buh Amos; Atashili, Julius; Benjamin, Pokam Thumamo; Marvlyn, Eba; Ivo, Keumami Katte; Nguedia, Assob Jules Clément

2016-11-08

Access to potable water remains a major challenge particularly in resource-limited settings. Although the potential contaminants of water are varied, enteric pathogenic protozoa are known to cause waterborne diseases greatly. This study aimed at investigating the prevalence, characteristics and correlates of enteric pathogenic protozoa in drinking water sources in Buea, Cameroon. A cross-sectional study was conducted using 155 water samples collected from various drinking sources (boreholes, springs, taps and wells). Each sample was subjected to physicochemical examinations (pH, turbidity, odour and sliminess) and parasitological analysis (wet mount, modified Ziehl-Neelsen stain) to determine the presence of enteric pathogenic protozoa. A data collection tool was used to note characteristics of collected samples and the data was analysed using EPI-INFO Version 3.5.3. The overall prevalence of enteric pathogenic protozoa in water sources was 62.6 %. Eight species of enteric protozoa were observed with Cryptosporidium parvum being the most predominant (45.8 %). Spring water was the most contaminated source with enteric protozoa (85.7 %) while pipe borne water had all eight species of protozoa identified. A pH of 6 was the only significant factor associated with the prevalence of these pathogens in water sources. The prevalence of enteric protozoa in water sources in Molyko and Bomaka is high, spring water is the most contaminated water source and Cryptosporidium parvum is the most common protozoa contaminating water. A water pH of 6 is associated to the prevalence of protozoa. Community members need to be educated to treat water before drinking to avoid infection by enteric protozoa in water and further studies with larger samples of water need to be conducted to find other correlates of the presence of protozoa in water.

ANTIMICROBIAL RESISTANCE AMONG ENTERIC BACTERIA ISOLATED FROM HUMAN AND ANIMAL WASTES AND IMPACTED SURFACE WATERS: COMPARISON WITH NARMS FINDINGS

EPA Science Inventory

Human infection with bacteria exhibiting mono or multiple antimicrobial resistance (MAR) has been a growing problem in the US, and studies have implicated livestock as a source of MAR bacteria primarily through foodborne transmission routes. However, waterborne transmission of...

Plant Growth and Phosphorus Uptake of Three Riparian Grass Species

USDA-ARS?s Scientific Manuscript database

Riparian buffers can significantly reduce sediment-bound phosphorus (P) entering surface water, but control of dissolved P inputs is more challenging. Because plant roots remove P from soil solution, it follows that plant uptake will reduce dissolved P losses. We evaluated P uptake of smooth bromegr...

Green-ampt infiltration parameters in riparian buffers

Treesearch

L.M. Stahr; D.E. Eisenhauer; M.J. Helmers; Mike G. Dosskey; T.G. Franti

2004-01-01

Riparian buffers can improve surface water quality by filtering contaminants from runoff before they enter streams. Infiltration is an important process in riparian buffers. Computer models are often used to assess the performance of riparian buffers. Accurate prediction of infiltration by these models is dependent upon accurate estimates of infiltration parameters....

PREVALENCE AND CONCENTRATION OF CRYPTOSPORIDIUM PARVUM OOCYSTS IN BEEF CATTLE PADDOCK SOILS AND FORAGE

USDA-ARS?s Scientific Manuscript database

Cryptosporidium parvum is an enteric coccidian protozoan that receives a great amount of interest because of its widespread occurrence in surface waters, its high degree of infectivity, and the difficulty of risk management associated with its presence and control. Information about environmental l...

Geology and ground water in Door County, Wisconsin, with emphasis on contamination potential in the Silurian dolomite

USGS Publications Warehouse

Sherrill, Marvin G.

1977-01-01

Door County, a recreational and fruit-growing area bordering Lake Michigan in northeastern Wisconsin, has had a long history of ground-water contamination from surface and near-surface sources. Contamination is most severe in late summer when fruit-canning operations and the influx of tourists create additional wastes. Silurian dolomite is the upper bedrock unit in the county and yields generally adequate supplies of very hard water with locally objectionable concentrations of iron and nitrate. Thin soil cover and well-fractured dolomitic bedrock give easy entry to ground-water contaminants throughout large parts of Door County. Many contaminants enter the dolomite by surface or near-surface seepage. There is little attenuation of contamination concentrations in the well-jointed dolomite, and contaminants may travel long distances underground in a relatively short time. The major source of ground-water contamination is bacteria, from individual waste-disposal systems, agricultural, industrial, and municipal wastes. Areas of the county underlain by contaminated zones include only a small percentage of the total ground-water system and are separated by large volumes of ground water free of contamination. (Woodard-USGS)

Some properties of the walls of metaxylem vessels of maize roots, including tests of the wettability of their lumenal wall surfaces

PubMed Central

McCully, Margaret; Canny, Martin; Baker, Adam; Miller, Celia

2014-01-01

Background and Aims Since the proposal of the cohesion theory there has been a paradox that the lumenal surface of vessels is rich in hydrophobic lignin, while tension in the rising sap requires adhesion to a hydrophilic surface. This study sought to characterize the strength of that adhesion in maize (Zea mays), the wettability of the vessel surface, and to reconcile this with its histochemical and physical nature. Methods Wettability was assessed by emptying the maize root vessels of sap, perfusing them with either water or oil, and examining the adhesion (as revealed by contact angles) of the two liquids to vessel walls by cryo-scanning electron microscopy. The phobicity of the lumenal surface was also assessed histochemically with hydrophilic and hydrophobic probes. Key Results Pit borders in the lumen-facing vessel wall surface were wetted by both sap/water and oil. The attraction for oil was weaker: water could replace oil but not vice versa. Pit apertures repelled oil and were strongly stained by hydrophilic probes. Pit chambers were probably hydrophilic. Oil never entered the pits. When vessels were emptied and cryo-fixed immediately, pit chambers facing away from the vessels were always sap-filled. Pit chambers facing vessel lumens were either sap- or gas-filled. Sap from adjoining tracheary elements entering empty vessels accumulated on the lumenal surface in hemispherical drops, which spread out with decreasing contact angles to fill the lumen. Conclusions The vessel lumenal surface has a dual nature, namely a mosaic of hydrophilic and hydrophobic patches at the micrometre scale, with hydrophilic predominating. A key role is shown, for the first time, of overarching borders of pits in determining the dual nature of the surface. In gas-filled (embolized) vessels they are hydrophobic. When wetted by sap (vessels refilling or full) they are hydrophilic. A hypothesis is proposed to explain the switch between the two states. PMID:24709790

Contrasting Effects of Central Pacific and Eastern Pacific El Nino on Stratospheric Water Vapor

NASA Technical Reports Server (NTRS)

Garfinkel, Chaim I.; Hurwitz, Margaret M.; Oman, Luke D.; Waugh, Darryn W.

2013-01-01

Targeted experiments with a comprehensive chemistry-climate model are used to demonstrate that seasonality and the location of the peak warming of sea surface temperatures dictate the response of stratospheric water vapor to El Nino. In spring, El Nino events in which sea surface temperature anomalies peak in the eastern Pacific lead to a warming at the tropopause above the warm pool region, and subsequently to more stratospheric water vapor (consistent with previous work). However, in fall and in early winter, and also during El Nino events in which the sea surface temperature anomaly is found mainly in the central Pacific, the response is qualitatively different: temperature changes in the warm pool region are nonuniform and less water vapor enters the stratosphere. The difference in water vapor in the lower stratosphere between the two variants of El Nino approaches 0.3 ppmv, while the difference between the winter and spring responses exceeds 0.5 ppmv.

Methane excess production in oxygen-rich polar water and a model of cellular conditions for this paradox

NASA Astrophysics Data System (ADS)

Damm, E.; Thoms, S.; Beszczynska-Möller, A.; Nöthig, E. M.; Kattner, G.

2015-09-01

Summer sea ice cover in the Arctic Ocean has undergone a reduction in the last decade exposing the sea surface to unforeseen environmental changes. Melting sea ice increases water stratification and induces nutrient limitation, which is also known to play a crucial role in methane formation in oxygenated surface water. We report on an excess of methane in the marginal ice zone in the western Fram Strait. Our study is based on measurements of oxygen, methane, DMSP, nitrate and phosphate concentrations as well as on phytoplankton composition and light transmission, conducted along the 79°N oceanographic transect, in the western part of the Fram Strait and in Northeast Water Polynya region off Greenland. Between the eastern Fram Strait, where Atlantic water enters from the south and the western Fram Strait, where Polar water enters from the north, different nutrient limitations occurred and consequently different bloom conditions were established. Ongoing sea ice melting enhances the environmental differences between both water masses and initiates regenerated production in the western Fram Strait. We show that in this region methane is in situ produced while DMSP (dimethylsulfoniopropionate) released from sea ice may serve as a precursor for the methane formation. The methane production occured despite high oxygen concentrations in this water masses. As the metabolic activity (respiration) of unicellular organisms explains the presence of anaerobic conditions in the cellular environment we present a theoretical model which explains the maintenance of anaerobic conditions for methane formation inside bacterial cells, despite enhanced oxygen concentrations in the environment.

Overpumping leads to California groundwater arsenic threat.

PubMed

Smith, Ryan; Knight, Rosemary; Fendorf, Scott

2018-06-05

Water resources are being challenged to meet domestic, agricultural, and industrial needs. To complement finite surface water supplies that are being stressed by changes in precipitation and increased demand, groundwater is increasingly being used. Sustaining groundwater use requires considering both water quantity and quality. A unique challenge for groundwater use, as compared with surface water, is the presence of naturally occurring contaminants within aquifer sediments, which can enter the water supply. Here we find that recent groundwater pumping, observed through land subsidence, results in an increase in aquifer arsenic concentrations in the San Joaquin Valley of California. By comparison, historic groundwater pumping shows no link to current groundwater arsenic concentrations. Our results support the premise that arsenic can reside within pore water of clay strata within aquifers and is released due to overpumping. We provide a quantitative model for using subsidence as an indicator of arsenic concentrations correlated with groundwater pumping.

Water contamination in urban south India: household storage practices and their implications for water safety and enteric infections.

PubMed

Brick, Thomas; Primrose, Beryl; Chandrasekhar, R; Roy, Sheela; Muliyil, Jayaprakash; Kang, Gagandeep

2004-10-01

Water contamination, at source and during household storage, is a major cause of enterically transmitted infections in developing countries. This study assessed contamination of the municipal water in a south Indian town, which obtains its water intermittently from a surface lake and by pumping subsurface water from a dry river bed, and monitored microbial contamination during household storage. All samples of the 'treated' municipal water were contaminated when freshly pumped, and on household storage, 25/37 (67%) showed increased contamination during storage periods from 1 to 9 days. Household storage in brass, but not in containers of other materials significantly decreased contamination of water (p = 0.04). This was confirmed in the laboratory by testing water seeded with 10(3) to 10(5) Escherichia coli per 100 ml stored in containers of different materials (p < 0.01). Despite the requirements for provision of safe drinking water in municipal areas, in practice the water supplied in Vellore is contaminated and current household storage practices increase the level of contamination in at least two-thirds of households. The implementation of locally appropriate point-of-use disinfection and safe household storage practices in developing countries is an urgent need to ensure a safe, reliable year-round supply in areas where clean water is not available.

Spatial distribution of perchlorate, iodide and thiocyanate in the aquatic environment of Tianjin, China: environmental source analysis.

PubMed

Qin, Xiaolei; Zhang, Tao; Gan, Zhiwei; Sun, Hongwen

2014-09-01

Although China is the largest producer of fireworks (perchlorate-containing products) in the world, the pathways through which perchlorate enters the environment have not been characterized completely in this country. In this study, perchlorate, iodide and thiocyanate were measured in 101 water samples, including waste water, surface water, sea water and paired samples of rain water and surface runoff collected in Tianjin, China. The concentrations of the target anions were generally on the order of rain>surface water≈waste water treatment plant (WWTP) influent>WWTP effluent. High concentrations of perchlorate, iodide and thiocyanate were detected in rain samples, ranging from 0.35 to 27.3 (median: 4.05), 0.51 to 8.33 (2.92), and 1.31 to 107 (5.62) ngmL(-)(1), respectively. Furthermore, the concentrations of the target anions in rain samples were significantly (r=0.596-0.750, p<0.01) positively correlated with the concentrations obtained in the paired surface runoff samples. The anions tested showed a clear spatial distribution, and higher concentrations were observed in the upper reaches of rivers, sea waters near the coast, and rain-surface runoff pairs sampled in urban areas. Our results revealed that precipitation may act as an important source of perchlorate, iodide and thiocyanate in surface water. Moreover, iodide concentrations in the Haihe River and Dagu Drainage Canal showed a good correlation with an ideal marker (acesulfame) of domestic waste water, indicating that input from domestic waste water was an important source of iodide in the surface waters of Tianjin. Copyright © 2014 Elsevier Ltd. All rights reserved.

DMSO Induces Dehydration near Lipid Membrane Surfaces

PubMed Central

Cheng, Chi-Yuan; Song, Jinsuk; Pas, Jolien; Meijer, Lenny H.H.; Han, Songi

2015-01-01

Dimethyl sulfoxide (DMSO) has been broadly used in biology as a cosolvent, a cryoprotectant, and an enhancer of membrane permeability, leading to the general assumption that DMSO-induced structural changes in cell membranes and their hydration water play important functional roles. Although the effects of DMSO on the membrane structure and the headgroup dehydration have been extensively studied, the mechanism by which DMSO invokes its effect on lipid membranes and the direct role of water in this process are unresolved. By directly probing the translational water diffusivity near unconfined lipid vesicle surfaces, the lipid headgroup mobility, and the repeat distances in multilamellar vesicles, we found that DMSO exclusively weakens the surface water network near the lipid membrane at a bulk DMSO mole fraction (XDMSO) of <0.1, regardless of the lipid composition and the lipid phase. Specifically, DMSO was found to effectively destabilize the hydration water structure at the lipid membrane surface at XDMSO <0.1, lower the energetic barrier to dehydrate this surface water, whose displacement otherwise requires a higher activation energy, consequently yielding compressed interbilayer distances in multilamellar vesicles at equilibrium with unaltered bilayer thicknesses. At XDMSO >0.1, DMSO enters the lipid interface and restricts the lipid headgroup motion. We postulate that DMSO acts as an efficient cryoprotectant even at low concentrations by exclusively disrupting the water network near the lipid membrane surface, weakening the cohesion between water and adhesion of water to the lipid headgroups, and so mitigating the stress induced by the volume change of water during freeze-thaw. PMID:26200868

Emerging contaminants in surface waters in China—a short review

NASA Astrophysics Data System (ADS)

Yang, Guang; Fan, Maohong; Zhang, Guangming

2014-07-01

Emerging contaminants (ECs) have drawn attention to many countries due to their persistent input and potential threat to human health and the environment. This article reviews the current contamination sources and their status for surface waters in China. The contamination levels of ECs in surface waters are in the range ng L-1 to μg L-1 in China, apparently about the same as the situation in other countries. ECs enter surface water via runoff, drainage, rainfall, and wastewater treatment effluent. The frequency of occurrence of ECs increased rapidly from 2006 to 2011; a significant reason is the production and consumption of pharmaceuticals and personal care products. As for the distribution of EC pollution in China, the frequency of occurrence of ECs in eastern regions is higher than in western regions. A majority of EC studies have focused on surface waters of the Haihe River and Pearl River watersheds due to their highly developed industries and intense human activity. Legislative and administrative regulation of ECs is lacking in China. To remove ECs, a number of technologies, such as absorption by activated carbon, membrane filtration technology, and advanced oxidation processes, have been researched.

Super-hydrophobic fluorine containing aerogels

DOEpatents

Coronado, Paul R [Livermore, CA; Poco, John F [Livermore, CA; Hrubesh, Lawrence W [Pleasanton, CA

2007-05-01

An aerogel material with surfaces containing fluorine atoms which exhibits exceptional hydrophobicity, or the ability to repel liquid water. Hydrophobic aerogels are efficient absorbers of solvents from water. Solvents miscible with water are separated from it because the solvents are more volatile than water and they enter the porous aerogel as a vapor across the liquid water/solid interface. Solvents that are immisicble with water are separated from it by selectively wetting the aerogel. The hydrophobic property is achieved by formulating the aerogel using fluorine containing molecules either directly by addition in the sol-gel process, or by treating a standard dried aerogel using the vapor of fluorine containing molecules.

Copepod communities from surface and ground waters in the everglades, south Florida

USGS Publications Warehouse

Bruno, M.C.; Cunningham, K.J.; Perry, S.A.

2003-01-01

We studied species composition and individual abundance of copepods in the surficial aquifer northeast of Everglades National Park. We identified the spatial distribution of subsurface habitats by assessing the depth of the high porosity layers in the limestone along a canal system, and we used copepods to assess the exchange between surface water and ground water along canal banks, at levels in the wells where high porosity connections to the canals exist. Surface- and ground-water taxa were defined, and species composition was related to areal position, sampling depth, and time. Subsurface copepod communities were dominated by surface copepods that disperse into the aquifer following the groundwater seepage along canal L-31N. The similarities in species composition between wells along canal reaches, suggest that copepods mainly enter ground water horizontally along canals via active and passive dispersal. Thus, the copepod populations indicate continuous connections between surface- and ground waters. The most abundant species were Orthocyclops modestus, Arctodiaptomus floridanus, Mesocyclops edax, and Thermocyclops parvus, all known in literature from surface habitats; however, these species have been collected in ground water in ENP. Only two stygophiles were collected: Diacylcops nearcticus and Diacyclops crassicaudis brachycercus. Restoration of the Everglades ecosystem requires a mosaic of data to reveal a complete picture of this complex system. The use of copepods as indicators of seepage could be a tool in helping to assess the direction and the duration of surface and ground water exchange.

Liquid filtration properties in gravel foundation of railroad tracks

NASA Astrophysics Data System (ADS)

Strelkov, A.; Teplykh, S.; Bukhman, N.

2016-08-01

Railway bed gravel foundation has a constant permanent impact on urban ecology and ground surface. It is only natural that larger objects, such as railway stations, make broader impact. Surface run-off waters polluted by harmful substances existing in railroad track body (ballast section) flow along railroad tracks and within macadam, go down into subterranean ground flow and then enter neighbouring rivers and water basins. This paper presents analytic calculations and characteristics of surface run-off liquid filtration which flows through gravel multiple layers (railroad track ballast section). The authors analyse liquids with various density and viscosity flowing in multi-layer porous medium. The paper also describes liquid stationary and non-stationary weepage into gravel foundation of railroad tracks.

Heat pump water heater and method of making the same

DOEpatents

Mei, Viung C.; Tomlinson, John J.; Chen, Fang C.

2001-01-01

An improved heat pump water heater wherein the condenser assembly of the heat pump is inserted into the water tank through an existing opening in the top of the tank, the assembly comprising a tube-in-a-tube construction with an elongated cylindrical outer body heat exchanger having a closed bottom with the superheated refrigerant that exits the compressor of the heat pump entering the top of the outer body. As the refrigerant condenses along the interior surface of the outer body, the heat from the refrigerant is transferred to the water through the outer body. The refrigerant then enters the bottom of an inner body coaxially disposed within the outer body and exits the top of the inner body into the refrigerant conduit leading into the expansion device of the heat pump. The outer body, in a second embodiment of the invention, acts not only as a heat exchanger but also as the sacrificial anode in the water tank by being constructed of a metal which is more likely to corrode than the metal of the tank.

Water quality indicators: bacteria, coliphages, enteric viruses.

PubMed

Lin, Johnson; Ganesh, Atheesha

2013-12-01

Water quality through the presence of pathogenic enteric microorganisms may affect human health. Coliform bacteria, Escherichia coli and coliphages are normally used as indicators of water quality. However, the presence of above-mentioned indicators do not always suggest the presence of human enteric viruses. It is important to study human enteric viruses in water. Human enteric viruses can tolerate fluctuating environmental conditions and survive in the environment for long periods of time becoming causal agents of diarrhoeal diseases. Therefore, the potential of human pathogenic viruses as significant indicators of water quality is emerging. Human Adenoviruses and other viruses have been proposed as suitable indices for the effective identification of such organisms of human origin contaminating water systems. This article reports on the recent developments in the management of water quality specifically focusing on human enteric viruses as indicators.

Presence, infectivity, and stability of enteric viruses in seawater: Relationship to marine water quality in the Florida Keys

USGS Publications Warehouse

Wetz, J.J.; Lipp, E.K.; Griffin, Dale W.; Lukasik, J.; Wait, D.; Sobsey, M.D.; Scott, T.M.; Rose, J.B.

2004-01-01

Concerns about the presence of enteric viruses in the surface waters of the Florida Keys prompted analyses of virus stability and persistence in these waters. In an in vitro study we evaluated the survival of poliovirus and stability of viral RNA in filtered natural seawater (FSW), unfiltered natural seawater (USW), artificial seawater (ASW) and DI water. This study compared cell culture infectivity with direct reverse transcription-polymerase chain reaction analysis. Attenuated poliovirus was seeded in the above water types and incubated in the dark at 22 and 30??C for 60 days. At 22??C, enhanced poliovirus survival and enhanced detection of viral RNA was observed in the seeded DI water control, artificial seawater and FSW samples. Detection of viruses in unfiltered seawater decreased rapidly at both temperatures by both methods of detection, suggesting that in the natural environment detection of enteroviral RNA may indicate a recent contamination event. In addition, in situ sampling in the Florida Keys during the late winter of 2000 revealed the presence of infectious enteroviruses at two sites and no sites exceeded recommended levels of microbial water quality indicators (enterococci or fecal coliform bacteria). ?? 2003 Elsevier Ltd. All rights reserved.

Microbiological quality and safe handling of enteral diets in a hospital in Minas Gerais, Brazil.

PubMed

Pinto, Raquel Oliveira Medrado; Correia, Eliznara Fernades; Pereira, Keyla Carvalho; Costa Sobrinho, Paulo de Souza; da Silva, Daniele Ferreira

2015-06-01

Contamination of enteral diets represents a high risk of compromising the patient's medical condition. To assess the microbiological quality and aseptic conditions in the preparation and administration of handmade and industrialized enteral diets offered in a hospital in the Valley of Jequitinhonha, MG, Brazil, we performed a microbiological analysis of 50 samples of diets and 27 samples of surfaces, utensils, and water used in the preparation of the diets. In addition, we assessed the good handling practices of enteral diets according to the requirements specified by the Brazilian legislation. Both kinds of enteral diets showed contamination by coliforms and Pseudomonas spp. No sample was positive for Staphylococcus aureus and Salmonella spp. On the other hand, Listeria spp. was detected in only one sample of handmade diets. Contamination was significantly higher in the handmade preparations (p < 0.05). Nonconformities were detected with respect to good handling practices, which may compromise the diet safety. The results indicate that the sanitary quality of the enteral diets is unsatisfactory, especially handmade diets. Contamination by Pseudomonas spp. is significant because it is often involved in infection episodes. With regard to aseptic practices, it was observed the need of implementing new procedures for handling enteral diets.

Sea-ice cover in the Nordic Seas and the sensitivity to Atlantic water temperatures

NASA Astrophysics Data System (ADS)

Jensen, Mari F.; Nisancioglu, Kerim H.; Spall, Michael A.

2017-04-01

Changes in the sea-ice cover of the Nordic Seas have been proposed to play a key role for the dramatic temperature excursions associated with the Dansgaard-Oeschger events during the last glacial. However, with its proximity to the warm Atlantic water, how a sea-ice cover can persist in the Nordic Seas is not well understood. In this study, we apply an eddy-resolving configuration of the Massachusetts Institute of Technology general circulation model with an idealized topography to study the presence of sea ice in a Nordic Seas-like domain. We assume an infinite amount of warm Atlantic water present in the south by restoring the southern area to constant temperatures. The sea-surface temperatures are restored toward cold, atmospheric temperatures, and as a result, sea ice is present in the interior of the domain. However, the sea-ice cover in the margins of the Nordic Seas, an area with a warm, cyclonic boundary current, is sensitive to the amount of heat entering the domain, i.e., the restoring temperature in the south. When the temperature of the warm, cyclonic boundary current is high, the margins are free of sea ice and heat is released to the atmosphere. We show that with a small reduction in the temperature of the incoming Atlantic water, the Nordic Seas-like domain is fully covered in sea ice. Warm water is still entering the Nordic Seas, however, this happens at depths below a cold, fresh surface layer produced by melted sea ice. Consequently, the heat release to the atmosphere is reduced along with the eddy heat fluxes. Results suggest a threshold value in the amount of heat entering the Nordic Seas before the sea-ice cover disappears in the margins. We study the sensitivity of this threshold to changes in atmospheric temperatures and vertical diffusivity.

Setback distances between small biological wastewater treatment systems and drinking water wells against virus contamination in alluvial aquifers.

PubMed

Blaschke, A P; Derx, J; Zessner, M; Kirnbauer, R; Kavka, G; Strelec, H; Farnleitner, A H; Pang, L

2016-12-15

Contamination of groundwater by pathogenic viruses from small biological wastewater treatment system discharges in remote areas is a major concern. To protect drinking water wells against virus contamination, safe setback distances are required between wastewater disposal fields and water supply wells. In this study, setback distances are calculated for alluvial sand and gravel aquifers for different vadose zone and aquifer thicknesses and horizontal groundwater gradients. This study applies to individual households and small settlements (1-20 persons) in decentralized locations without access to receiving surface waters but with the legal obligation of biological wastewater treatment. The calculations are based on Monte Carlo simulations using an analytical model that couples vertical unsaturated and horizontal saturated flow with virus transport. Hydraulic conductivities and water retention curves were selected from reported distribution functions depending on the type of subsurface media. The enteric virus concentration in effluent discharge was calculated based on reported ranges of enteric virus concentration in faeces, virus infectivity, suspension factor, and virus reduction by mechanical-biological wastewater treatment. To meet the risk target of <10 -4 infections/person/year, a 12 log 10 reduction was required, using a linear dose-response relationship for the total amount of enteric viruses, at very low exposure concentrations. The results of this study suggest that the horizontal setback distances vary widely ranging 39 to 144m in sand aquifers, 66-289m in gravel aquifers and 1-2.5km in coarse gravel aquifers. It also varies for the same aquifers, depending on the thickness of the vadose zones and the groundwater gradient. For vulnerable fast-flow alluvial aquifers like coarse gravels, the calculated setback distances were too large to achieve practically. Therefore, for this category of aquifer, a high level of treatment is recommended before the effluent is discharged to the ground surface. Copyright © 2016 The Authors. Published by Elsevier B.V. All rights reserved.

Solar light (hv) and H2O2/hv photo-disinfection of natural alkaline water (pH 8.6) in a compound parabolic collector at different day periods in Sahelian region.

PubMed

Ndounla, J; Pulgarin, C

2015-11-01

The photo-disinfection of natural alkaline surface water (pH 8.6 ± 0.3) for drinking purposes was carried out under solar radiation treatments. The enteric bacteria studied were the wild total coliforms/Escherichia coli (10(4) CFU/ml) and Salmonella spp. (10(4) CFU/ml) naturally present in the water. The photo-disinfection of a 25-l water sample was carried out in a solar compound parabolic collector (CPC) in the absence and in the presence of hydrogen peroxide (H2O2). The addition of H2O2 (10 mg/L) to the sample water was sufficient to enhance the photo-disinfection and ensure an irreversible lethal action on the wild enteric bacteria contents of the sample. The inactivation kinetic of the system was significantly enhanced compared to the one carried out without H2O2 addition. The effect of the solar radiation parameters on the efficiency of the photo-disinfection were assessed. The pH has increased during the treatment in all the photo-disinfection processes (hv and H2O2/hv). The Salmonella spp strain has shown the best effective inactivate time in alkaline water than the one recorded under acidic or near-neutral conditions. The evolution of some physico-chemical parameters of the water (turbidity, NO2(-), NO3(-), NH4(+), HPO4(2-), and bicarbonate (HCO3(-))) was monitored during the treatment. Finally, the possible mechanistic process involved during the enteric bacteria inactivation was suggested.

Investigation of enteric adenovirus and poliovirus removal by coagulation processes and suitability of bacteriophages MS2 and φX174 as surrogates for those viruses.

PubMed

Shirasaki, N; Matsushita, T; Matsui, Y; Marubayashi, T; Murai, K

2016-09-01

We evaluated the removal of enteric adenovirus (AdV) type 40 and poliovirus (PV) type 1 by coagulation, using water samples from 13 water sources for drinking water treatment plants in Japan. The behaviors of two widely accepted enteric virus surrogates, bacteriophages MS2 and φX174, were compared with the behaviors of AdV and PV. Coagulation with polyaluminum chloride (PACl, basicity 1.5) removed AdV and PV from virus-spiked source waters: the infectious AdV and PV removal ratios evaluated by means of a plaque-forming-unit method were 0.1-1.4-log10 and 0.5-2.4-log10, respectively. A nonsulfated high-basicity PACl (basicity 2.1) removed infectious AdV and PV more efficiently than did other commercially available PACls (basicity 1.5-2.1), alum, and ferric chloride. The MS2 removal ratios tended to be larger than those of AdV and PV, partly because of differences in the hydrophobicities of the virus particles and the sensitivity of the virus to the virucidal activity of PACl; the differences in removal ratios were not due to differences in the surface charges of the virus particles. MS2, which was more hydrophobic than the other viruses, was inactivated during coagulation with PACl. Therefore, MS2 does not appear to be an appropriate surrogate for AdV and PV during coagulation. In contrast, because φX174, like AdV and PV, was not inactivated during coagulation, and because the hydrophobicity of φX174 was similar to or somewhat lower than the hydrophobicities of AdV and PV, the φX174 removal ratios tended to be similar to or somewhat smaller than those of the enteric viruses. Therefore, φX174 is a potential conservative surrogate for AdV and PV during coagulation. In summary, the surface hydrophobicity of virus particles and the sensitivity of the virus to the virucidal activity of the coagulant are probably important determinants of the efficiency of virus removal during coagulation. Copyright © 2016 Elsevier B.V. All rights reserved.

Spontaneous encapsulation behavior of ionic liquid into carbon nanotube

NASA Astrophysics Data System (ADS)

Jiang, Yanyan; Zhang, Kun; Li, Hui; He, Yezeng; Song, Xigui

2012-10-01

Molecular dynamics simulations and density functional theory have been performed to investigate the spontaneous encapsulation of 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) into single-walled carbon nanotubes (SWCNTs). This phenomenon can be attributed to the van der Waals attractive force, hydrogen bonds and especially the π-π stacking effect. The [Bmim][Cl] molecules enter SWCNTs with larger diameters more rapidly, showing an interesting dependence on tube size. A high temperature is not beneficial to, and may even disrupt, the encapsulation of the [Bmim][Cl] molecules. It is also worth noting that the graphene nanoribbon entering the SWCNT would have an extremely different effect on this encapsulation process from when they wrap around the outer surface. Furthermore, the [Bmim][Cl] molecules can assist water transport in the SWCNT by expelling water molecules from the SWCNT. The proposed discoveries eventually provide a powerful way to fabricate nanoscale materials and devices and tune their properties.Molecular dynamics simulations and density functional theory have been performed to investigate the spontaneous encapsulation of 1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) into single-walled carbon nanotubes (SWCNTs). This phenomenon can be attributed to the van der Waals attractive force, hydrogen bonds and especially the π-π stacking effect. The [Bmim][Cl] molecules enter SWCNTs with larger diameters more rapidly, showing an interesting dependence on tube size. A high temperature is not beneficial to, and may even disrupt, the encapsulation of the [Bmim][Cl] molecules. It is also worth noting that the graphene nanoribbon entering the SWCNT would have an extremely different effect on this encapsulation process from when they wrap around the outer surface. Furthermore, the [Bmim][Cl] molecules can assist water transport in the SWCNT by expelling water molecules from the SWCNT. The proposed discoveries eventually provide a powerful way to fabricate nanoscale materials and devices and tune their properties. Electronic supplementary information (ESI) available: (1) Movie: the encapsulation process of the ILs into the SWCNT (16,16). (2) More calculation details, including the data of the morphology vs. the encapsulation process from both ends and different tube diameters. See DOI: 10.1039/c2nr31432k

Surface properties of semi-synthetic enteric coating films: Opportunities to develop bio-based enteric coating films for colon- targeted delivery

USDA-ARS?s Scientific Manuscript database

This study investigated the surface properties of the semi-synthetic enteric coating materials for potential colon- targeted bioactive delivery. The enteric coating materials were produced by combining nanoscale resistant starch, pectin, and carboxymethylcellulose. The surface properties of the co...

Microscopic structure and properties of discrete water layer in Na-exchanged montmorillonite.

PubMed

Emmerich, Katja; Koeniger, Franz; Kaden, Heike; Thissen, Peter

2015-06-15

In this work, we focus on the atomic structure of the water interlayer of Na-exchanged montmorillonite. For two different surface charge densities, namely -0.086 and -0.172 C/m(2), the adsorption process in the presence of water is described by first principles calculations. We describe the interactions and forces for every water molecule entering the interlayer during the swelling process. In particular, the dielectric permittivity of the water interlayer is calculated. Finally, we confirm our results performing ab initio thermodynamics calculations leading to a wide range of realistic experimental scenarios. Copyright © 2015 Elsevier Inc. All rights reserved.

Effects of crude oil and swimming behavior and survival in the rice rat

USGS Publications Warehouse

Wolfe, J.L.; Esher, R.J.

1981-01-01

Oil slicks in laboratory test chambers inhibited swimming behavior of rice rats, and reduced survival at low temperature. Predisposition to enter the water and swim was greatly reduced at both high (200 ml/m2 water surface) and low (20 ml/m2) concentrations of oil. Survival was significantly affected only at high concentrations. The results may be of value in predicting the impact of oil spills on the mammal community of coastal marshes.

Bovine Enteroviruses as Indicators of Fecal Contamination

PubMed Central

Ley, Victoria; Higgins, James; Fayer, Ronald

2002-01-01

Surface waters frequently have been contaminated with human enteric viruses, and it is likely that animal enteric viruses have contaminated surface waters also. Bovine enteroviruses (BEV), found in cattle worldwide, usually cause asymptomatic infections and are excreted in the feces of infected animals in large numbers. In this study, the prevalence and genotype of BEV in a closed herd of cattle were evaluated and compared with BEV found in animals in the immediate environment and in environmental specimens. BEV was found in feces from 76% of cattle, 38% of white-tailed deer, and one of three Canada geese sharing the same pastures, as well as the water obtained from animal watering tanks, from the pasture, from streams running from the pasture to an adjacent river, and from the river, which emptied into the Chesapeake Bay. Furthermore, BEV was found in oysters collected from that river downstream from the farm. These findings suggest that BEV could be used as an indicator of fecal pollution originating from animals (cattle and/or deer). Partial sequence analysis of the viral genomes indicates that different viral variants coexist in the same area. The possibility of identifying the viral strains found in the animals and in the contaminated areas by sequencing the RNA genome, could provide a tool to find the origin of the contamination and should be useful for epidemiological and viral molecular evolution studies. PMID:12089028

Analysis of coral mucus as an improved medium for detection of enteric microbes and for determining patterns of sewage contamination in reef environments

USGS Publications Warehouse

Lipp, Erin K.; Griffin, Dale W.

2004-01-01

Traditional fecal indicator bacteria are often subject to a high degree of die-off and dilution in tropical marine waters, particularly in offshore areas such as coral reefs. Furthermore, these microbes are often not associated with human waste, and their presence may not be indicative of health risk. To address the offshore extent of wastewater contamination in the Florida Keys reef tract, we assayed coral surfaces for the presence of human-specific enteric viruses. The overlying water column and surface mucopolysaccharide (mucus) layers from scleractinian corals were sampled from three stations along a nearshore-to-offshore transect beginning at Long Key in the middle Florida Keys, USA. Samples were assayed for standard bacterial water quality indicators (fecal coliform bacteria and enterococci) and for human enteroviruses by direct reverse transcriptase-polymerase chain reaction (RT-PCR). The concentration of the bacterial indicators was greatest at the nearshore station in both the water column and corals, and decreased with distance from shore; no indicator bacteria were detected at the offshore station. Whereas human enteroviruses were not detected in any of the water column samples, they were detected in 50–80% of coral mucus samples at each station. These data provide evidence that human sewage is impacting the reef tract up to ~6.5 km from shore in the middle Florida Keys and that coral mucus is an efficient trap for viral markers associated with anthropogenic pollution.

Water in the trail of the Chelyabinsk bolide

NASA Astrophysics Data System (ADS)

Gladysheva, O. G.

2017-09-01

At 03:20 UTC on February 15, 2013 a very bright bolide entered Earth's atmosphere. Fragments of the meteorite fell to the earth's surface. Examination of these fragments revealed that several of them were located directly on the surface of the celestial body [1], while the majority lay at a depth of less than 2.5 m from the surface [2, 3]. The stone meteorite's durability, >15 MPa, corresponded to <1% of the initial mass, while the rest of the object possessed a low durability of 1 MPa [4]. Moreover, Fe3+ hydroxyls were discovered in meteorite samples, the formation of which required water [5]. The glow at the head of the bolide trail, lasting 8 seconds after the flight of the object, and the development of the cloud trail indicate that the celestial body carried water. The Chinese weather satellite Feng-Yun 2D discovered ice debris (water) in the bolide trail [6]. Here, we will demonstrate that the Chelyabinsk chondrite was delivered to the Earth by an ice-bearing celestial body.

Base of moderately saline ground water in the Uinta Basin, Utah, with an introductory section describing the methods used in determining its position

USGS Publications Warehouse

Howells, Lewis; Longson, M.S.; Hunt, Gilbert L.

1987-01-01

The base of the moderately saline water (water that contains from 3,000 to 10,000 milligrams per liter of dissolved solids) was mapped by using available water-quality data and by determining formation-water resistivities from geophysical well logs based on the resistivity-porosity, spontaneous potential, and resistivity-ratio methods. The contour map developed from these data showed a mound of very saline and briny water, mostly of sodium chloride and sodium bicarbonate type, in most of that part of the Uinta Basin that is underlain by either the Green River or Wasatch Formations. Along its northern edge, the mound rises steeply from below sea level to within 2,000 feet of the land surface and, locally, to land surface. Along its southern edge, the mound rises less steeply and is more complex in outline. This body of very saline to briny water may be a lens; many wells or test holes drilled within the area underlain by the mound re-entered fresh to moderately saline water at depths of 8,000 to 15,000 feet below lam surface.

Riparian vegetation dynamics and evapotranspiration in the riparian corridor in the delta of the Colorado River, Mexico.

PubMed

Nagler, Pamela L; Glenn, Edward P; Hinojosa-Huerta, Osvel; Zamora, Francisco; Howard, Keith

2008-09-01

Like other great desert rivers, the Colorado River in the United States and Mexico is highly regulated to provide water for human use. No water is officially allotted to support the natural ecosystems in the delta of the river in Mexico. However, precipitation is inherently variable in this watershed, and from 1981-2004, 15% of the mean annual flow of the Lower Colorado River has entered the riparian corridor below the last diversion point for water in Mexico. These flows include flood releases from US dams and much smaller administrative spills released back to the river from irrigators in the US and Mexico. These flows have germinated new cohorts of native cottonwood and willow trees and have established an active aquatic ecosystem in the riparian corridor in Mexico. We used ground and remote-sensing methods to determine the composition and fractional cover of the vegetation in the riparian corridor, its annual water consumption, and the sources of water that support the ecosystem. The study covered the period 2000-2004, a flood year followed by 4 dry years. The riparian corridor occupies 30,000 ha between flood control levees in Mexico. Annual evapotranspiration (ET), estimated by Moderate Resolution Imaging Spectrometer (MODIS) satellite imagery calibrated against moisture flux tower data, was about 1.1 m yr(-1) and was fairly constant throughout the study period despite a paucity of surface flows 2001-2004. Total ET averaged 3.4 x 10(8)m(3)yr(-1), about 15% of Colorado River water entering Mexico from the US Surface flows could have played only a small part in supporting these high ET losses. We conclude that the riparian ET is supported mainly by the shallow regional aquifer, derived from agricultural return flows, that approaches the surface in the riparian zone. Nevertheless, surface flows are important in germinating cohorts of native trees, in washing salts from the soil and aquifer, and in providing aquatic habitat, thereby enriching the habitat value of the riparian corridor for birds and other wildlife. Conservation and water management strategies to enhance the delta habitats are discussed in light of the findings.

Riparian vegetation dynamics and evapotranspiration in the riparian corridor in the delta of the Colorado River, Mexico

USGS Publications Warehouse

Nagler, P.L.; Glenn, E.P.; Hinojosa-Huerta, O.; Zamora, F.; Howard, K. J.

2008-01-01

Like other great desert rivers, the Colorado River in the United States and Mexico is highly regulated to provide water for human use. No water is officially allotted to support the natural ecosystems in the delta of the river in Mexico. However, precipitation is inherently variable in this watershed, and from 1981-2004, 15% of the mean annual flow of the Lower Colorado River has entered the riparian corridor below the last diversion point for water in Mexico. These flows include flood releases from US dams and much smaller administrative spills released back to the river from irrigators in the US and Mexico. These flows have germinated new cohorts of native cottonwood and willow trees and have established an active aquatic ecosystem in the riparian corridor in Mexico. We used ground and remote-sensing methods to determine the composition and fractional cover of the vegetation in the riparian corridor, its annual water consumption, and the sources of water that support the ecosystem. The study covered the period 2000-2004, a flood year followed by 4 dry years. The riparian corridor occupies 30,000 ha between flood control levees in Mexico. Annual evapotranspiration (ET), estimated by Moderate Resolution Imaging Spectrometer (MODIS) satellite imagery calibrated against moisture flux tower data, was about 1.1 m yr-1 and was fairly constant throughout the study period despite a paucity of surface flows 2001-2004. Total ET averaged 3.4??108 m3 yr-1, about 15% of Colorado River water entering Mexico from the US Surface flows could have played only a small part in supporting these high ET losses. We conclude that the riparian ET is supported mainly by the shallow regional aquifer, derived from agricultural return flows, that approaches the surface in the riparian zone. Nevertheless, surface flows are important in germinating cohorts of native trees, in washing salts from the soil and aquifer, and in providing aquatic habitat, thereby enriching the habitat value of the riparian corridor for birds and other wildlife. Conservation and water management strategies to enhance the delta habitats are discussed in light of the findings. ?? 2007 Elsevier Ltd. All rights reserved.

Quantitative and qualitative analysis of naphthenic acids in natural waters surrounding the Canadian oil sands industry.

PubMed

Ross, Matthew S; Pereira, Alberto dos Santos; Fennell, Jon; Davies, Martin; Johnson, James; Sliva, Lucie; Martin, Jonathan W

2012-12-04

The Canadian oil sands industry stores toxic oil sands process-affected water (OSPW) in large tailings ponds adjacent to the Athabasca River or its tributaries, raising concerns over potential seepage. Naphthenic acids (NAs; C(n)H(2n-Z)O(2)) are toxic components of OSPW, but are also natural components of bitumen and regional groundwaters, and may enter surface waters through anthropogenic or natural sources. This study used a selective high-resolution mass spectrometry method to examine total NA concentrations and NA profiles in OSPW (n = 2), Athabasca River pore water (n = 6, representing groundwater contributions) and surface waters (n = 58) from the Lower Athabasca Region. NA concentrations in surface water (< 2-80.8 μg/L) were 100-fold lower than previously estimated. Principal components analysis (PCA) distinguished sample types based on NA profile, and correlations to water quality variables identified two sources of NAs: natural fatty acids, and bitumen-derived NAs. Analysis of NA data with water quality variables highlighted two tributaries to the Athabasca River-Beaver River and McLean Creek-as possibly receiving OSPW seepage. This study is the first comprehensive analysis of NA profiles in surface waters of the region, and demonstrates the need for highly selective analytical methods for source identification and in monitoring for potential effects of development on ambient water quality.

Abundance and Distribution of Enteric Bacteria and Viruses in Coastal and Estuarine Sediments—a Review

PubMed Central

Hassard, Francis; Gwyther, Ceri L.; Farkas, Kata; Andrews, Anthony; Jones, Vera; Cox, Brian; Brett, Howard; Jones, Davey L.; McDonald, James E.; Malham, Shelagh K.

2016-01-01

The long term survival of fecal indicator organisms (FIOs) and human pathogenic microorganisms in sediments is important from a water quality, human health and ecological perspective. Typically, both bacteria and viruses strongly associate with particulate matter present in freshwater, estuarine and marine environments. This association tends to be stronger in finer textured sediments and is strongly influenced by the type and quantity of clay minerals and organic matter present. Binding to particle surfaces promotes the persistence of bacteria in the environment by offering physical and chemical protection from biotic and abiotic stresses. How bacterial and viral viability and pathogenicity is influenced by surface attachment requires further study. Typically, long-term association with surfaces including sediments induces bacteria to enter a viable-but-non-culturable (VBNC) state. Inherent methodological challenges of quantifying VBNC bacteria may lead to the frequent under-reporting of their abundance in sediments. The implications of this in a quantitative risk assessment context remain unclear. Similarly, sediments can harbor significant amounts of enteric viruses, however, the factors regulating their persistence remains poorly understood. Quantification of viruses in sediment remains problematic due to our poor ability to recover intact viral particles from sediment surfaces (typically <10%), our inability to distinguish between infective and damaged (non-infective) viral particles, aggregation of viral particles, and inhibition during qPCR. This suggests that the true viral titre in sediments may be being vastly underestimated. In turn, this is limiting our ability to understand the fate and transport of viruses in sediments. Model systems (e.g., human cell culture) are also lacking for some key viruses, preventing our ability to evaluate the infectivity of viruses recovered from sediments (e.g., norovirus). The release of particle-bound bacteria and viruses into the water column during sediment resuspension also represents a risk to water quality. In conclusion, our poor process level understanding of viral/bacterial-sediment interactions combined with methodological challenges is limiting the accurate source apportionment and quantitative microbial risk assessment for pathogenic organisms associated with sediments in aquatic environments. PMID:27847499

Influence of the Yukon River on the Bering Sea

NASA Technical Reports Server (NTRS)

Dean, K.; Mcroy, C. P.

1987-01-01

The distribution of near-surface, turbid water, discharged by the Yukon River, was studied based on analysis of satellite imagery. The interannual analyses indicates that the net flow of near-surface, turbid water is northward of the delta across the entrance to Norton Sound. Only turbid water to the east enters Norton Sound and consists of 25% of the total area. Approximately 10% of the water circulates into the sound along the southern coast and is lost to view in the vicinity of Unalakleet. Suspended sediments transported by this southern circulation are primarily deposited along the southern coast. Three distinct zones within the turbid water were identified based on relative brightness levels. These zones appear to be primarily related to differences in suspended-sediment concentrations and position of the sediments in the water column. The extent of turbid water varies seasonally. It is most extensive June through October even though discharge of the Yukon River decreases substantially after July.

Fecal pollution source tracking toolbox for identification, evaluation and characterization of fecal contamination in receiving urban surface waters and groundwater.

PubMed

Tran, Ngoc Han; Gin, Karina Yew-Hoong; Ngo, Huu Hao

2015-12-15

The quality of surface waters/groundwater of a geographical region can be affected by anthropogenic activities, land use patterns and fecal pollution sources from humans and animals. Therefore, the development of an efficient fecal pollution source tracking toolbox for identifying the origin of the fecal pollution sources in surface waters/groundwater is especially helpful for improving management efforts and remediation actions of water resources in a more cost-effective and efficient manner. This review summarizes the updated knowledge on the use of fecal pollution source tracking markers for detecting, evaluating and characterizing fecal pollution sources in receiving surface waters and groundwater. The suitability of using chemical markers (i.e. fecal sterols, fluorescent whitening agents, pharmaceuticals and personal care products, and artificial sweeteners) and/or microbial markers (e.g. F+RNA coliphages, enteric viruses, and host-specific anaerobic bacterial 16S rDNA genetic markers) for tracking fecal pollution sources in receiving water bodies is discussed. In addition, this review also provides a comprehensive approach, which is based on the detection ratios (DR), detection frequencies (DF), and fate of potential microbial and chemical markers. DR and DF are considered as the key criteria for selecting appropriate markers for identifying and evaluating the impacts of fecal contamination in surface waters/groundwater. Copyright © 2015 Elsevier B.V. All rights reserved.

Hydrogeology, water quality, and potential for contamination of the Upper Floridan aquifer in the Silver Springs ground-water basin, central Marion County, Florida

USGS Publications Warehouse

Phelps, G.G.

1994-01-01

The Upper Floridan aquifer, composed of a thick sequence of very porous limestone and dolomite, is the principal source of water supply in the Silver Springs ground-water basin of central Marion County, Florida. The karstic nature of the local geology makes the aquifer susceptible to contaminants from the land surface. Contaminants can enter the aquifer by seepage through surficial deposits and through sinkholes and drainage wells. Potential contaminants include agricultural chemicals, landfill leachates and petroleum products from leaking storage tanks and accidental spills. More than 560 sites of potential contamination sources were identified in the basin in 1990. Detailed investigation of four sites were used to define hydrologic conditions at representative sites. Ground-water flow velocities determined from dye trace studies ranged from about 1 foot per hour under natural flow conditions to about 10 feet per hour under pumping conditions, which is considerably higher than velocities estimated using Darcy's equation for steady-state flow in a porous medium. Water entering the aquifer through drainage wells contained bacteria, elevated concentrations of nutrients, manganese and zinc, and in places, low concentrations of organic compounds. On the basis of results from the sampling of 34 wells in 1989 and 1990, and from the sampling of water entering the Upper Floridan aquifer through drainage wells, there has been no widespread degradation of water quality in the study area. In an area of karst, particularly one in which fracture flow is significant, evaluating the effects from contaminants is difficult and special care is required when interpolating hydrogeologic data from regional studies to a specific. (USGS)

Water flow through temperate glaciers

USGS Publications Warehouse

Fountain, A.G.; Walder, J.S.

1998-01-01

Understanding water movement through a glacier is fundamental to several critical issues in glaciology, including glacier dynamics, glacier-induced floods, and the prediction of runoff from glacierized drainage basins. to this end we have synthesized a conceptual model os water movement through a temperate glacier from the surface to the outlet stream. Processes that regulate the rate and distribution of water input at the glacier surface and that regulate water movement from the surface to the bed play important but commonly neglected roles in glacier hydrology. Where a glacier is covered by a layer of porous, permeable firn (the accumulation zone), the flux of water to the glacier interior varies slowly because the firn temporarily stores water and thereby smooths out variations in the supply rate. In the firn-free ablation zone, in contrast, the flux of water into the glacier depends directly on the rate of surface melt or rainfall and therefore varies greatly in time. Water moves from the surface to the bed through an upward branching arborescent network consisting of both steeply inclined conduits, formed by the enlargement of intergranular veins, and gently inclined conduits, sprqwned by water flow along the bottoms of near-surface fractures (crevasses). Englacial drainage conduits deliver water to the glacier bed at a linited number of points, probably a long distance downglacier of where water enters the glacier. Englacial conduits supplied from the accumulation zone are quasi steady state features that convey the slowly varying water flux delivered via the firn. their size adjusts so that they are usually full of water and flow is pressurized. In contrast, water flow in englacial conduits supplied from the ablation area is pressurized only near times of peak daily flow or during rainstorms; flow is otherwise in an open-channel configuration. The subglacial drainage system typically consists of several elements that are distinct both morpphologically and hydrologically. An up-glacier branching, arborescent network of channels incised into the basal ice conveys water rapidly. Much of the water flux to the bed probably enters directly into the arborescent channel network, which covers only a small fraction of the glacier bed. More extensive spatially is a nonarborescent network, which commonly includes cabities (gaps between the glacier sole and bed), channels incised into the bed, and a layer of permeable sediment. The nonarborescent network conveys water slowly and is usually poorly connected to the arborescent system. The arborescent channel network largely collapses during winter but reforms in the spring as the first flush of meltwater to the bed destabilizes the cavities within the nonarborescent net6work. The volume of water stored by a glacier varies diurnally and seasonally. Small, temperate alpine glaciers seem to attain a maximum seasonal water storage of ~200 mm of water averaged over the area of the glacier bed, with daily fluctuations of as much as 20-30 mm. The likely storage capacity of subglacial cavities is insufficient to account for estimated stored water volumes, so most water storage may actually occur englacially. Sotred water may also be released abruptly and catastrophically in the form of outburst floods.

Swimming and grommets1

PubMed Central

Marks, N J; Mills, R P

1983-01-01

The dictum that patients who have plastic ventilation tubes (grommets) inserted in their tympanic membranes should not go swimming is questioned. A theoretical assessment is made of the pressure necessary to push water through a grommet. This value is compared with practical observations. These values are discussed with reference to chemical and bacteriological hazards and it is concluded that water is unlikely to enter the middle ear in surface swimming, and even when diving underwater the chances of setting up an otitis media must be small. PMID:6827495

Experimental Observations of Vortex Ring Interaction with the Fluid Adjacent to a Surface.

DTIC Science & Technology

1983-10-01

minute. The water enters the inlet tank from a distribution manifold pipe and rises vertically through a 15 cm. thick plastic sponge. The flow then passes...parts exposed to water are made from PVC plastic to resist corrosion. The generator was designed to have interchangeable parts which allow the generation...of vortex rings over a range of caracteristics . The motor speed is continuously variable up to a speed of 7400 rpm. Cams with stroke lengths of 0.64

Removal of indigenous coliphages and enteric viruses during riverbank filtration from highly polluted river water in Delhi (India).

PubMed

Sprenger, C; Lorenzen, G; Grunert, A; Ronghang, M; Dizer, H; Selinka, H-C; Girones, R; Lopez-Pila, J M; Mittal, A K; Szewzyk, R

2014-06-01

Emerging countries frequently afflicted by waterborne diseases require safe and cost-efficient production of drinking water, a task that is becoming more challenging as many rivers carry a high degree of pollution. A study was conducted on the banks of the Yamuna River, Delhi, India, to ascertain if riverbank filtration (RBF) can significantly improve the quality of the highly polluted surface water in terms of virus removal (coliphages, enteric viruses). Human adenoviruses and noroviruses, both present in the Yamuna River in the range of 10(5) genomes/100 mL, were undetectable after 50 m infiltration and approximately 119 days of underground passage. Indigenous somatic coliphages, used as surrogates of human pathogenic viruses, underwent approximately 5 log10 removal after only 3.8 m of RBF. The initial removal after 1 m was 3.3 log10, and the removal between 1 and 2.4 m and between 2.4 and 3.8 m was 0.7 log10 each. RBF is therefore an excellent candidate to improve the water situation in emerging countries with respect to virus removal.

Stream denitrification across biomes and its response to anthropogenic nitrate loading

Treesearch

Patrick J Mulholland; Ashely M. Helton; Geoffrey C. Poole; Robert O. Hall; Stephen K. Hamilton; Bruce J. Peterson; Jennifer L. Tank; Linda R. Ashkenas; Lee W. Cooper; Clifford N. Dahm; Walter K. Dodds; Stuart E.G. Findlay; Stanley V. Gregory; Nancy B. Grimm; Sherri L. Johnson; William H. McDowell; Judy L. Meyer; H. Maurice Valett; Jackson R. Webster; Clay P. Arango; Jake J. Beaulieu; Melody J. Bernot; Amy J. Burgin; Chelsea L. Crenshaw; Laura T. Johnson; B.R. Niederlehner; Jonathan M. O' Brien; Jody D. Potter; Richard W. Sheibley; Daniel J. Sobota; Suzanne M. Thomas

2008-01-01

Anthropogenic addition of bioavailable nitrogen to the biosphere is increasing, and terrestrial ecosystems are becoming increasingly nitrogen-saturated, causing more bioavailable nitrogen to enter groundwater and surface waters. Large-scale nitrogen budgets show that an average of about 20 to 25 percent of the nitrogen added to the biosphere is exported from rivers to...

Persistence of F-specific RNA phages in surface waters from a produce production region along the central coast of California

USDA-ARS?s Scientific Manuscript database

F+ RNA coliphages (FRNA) are used to source-track fecal contamination and as surrogates for enteric pathogen persistence in the environment. However, the environmental persistence of FRNA is not clearly understood and thus we evaluated the survival of prototype and environmental isolates of FRNA rep...

Grooved impactor and inertial trap for sampling inhalable particulate matter

DOEpatents

Loo, Billy W.

1984-01-01

An inertial trap and grooved impactor for providing a sharp cutoff for particles over 15 microns from entering an inhalable particulate sampler. The impactor head has a tapered surface and is provided with V-shaped grooves. The tapered surface functions for reducing particle blow-off or reentrainment while the grooves prevent particle bounce. Water droplets and any resuspended material over the 15 micron size are collected by the inertial trap and deposited in a reservoir associated with the impactor.

Suitability of artificial sweeteners as indicators of raw wastewater contamination in surface water and groundwater.

PubMed

Tran, Ngoc Han; Hu, Jiangyong; Li, Jinhua; Ong, Say Leong

2014-01-01

There is no quantitative data on the occurrence of artificial sweeteners in the aquatic environment in Southeast Asian countries, particularly no information on their suitability as indicators of raw wastewater contamination on surface water and groundwater. This study provided the first quantitative information on the occurrence of artificial sweeteners in raw wastewater, surface water and groundwater in the urban catchment area in Singapore. Acesulfame, cyclamate, saccharin, and sucralose were ubiquitous in raw wastewater samples at concentrations in the range of ng/L-μg/L, while other sweeteners were not found or found only in a few of the raw wastewater samples. Residential and commercial effluents were demonstrated to be the two main sources of artificial sweeteners entering the municipal sewer systems. Relatively higher concentrations of the detected sweeteners were frequently found in surface waters at the sampling sites located in the residential/commercial areas. No significant difference in the concentrations of the detected sweeteners in surface water or groundwater was noted between wet and dry weather conditions (unpaired T-test, p> 0.05). Relatively higher concentrations and detection frequencies of acesulfame, cyclamate and saccharin in surface water samples were observed at the potentially impacted sampling sites, while these sweeteners were absent in most of the background surface water samples. Similarly, acesulfame, cyclamate, and saccharin were found in most groundwater samples at the monitoring well (GW6), which is located close to known leaking sewer segment; whereas these were absent in the background monitoring well, which is located in the catchment with no known wastewater sources. Taken together, the results suggest that acesulfame, cyclamate, and saccharin can be used as potential indicators of raw wastewater contamination in surface water and groundwater. Copyright © 2013 Elsevier Ltd. All rights reserved.

Guidelines for Coding and Entering Ground-Water Data into the Ground-Water Site Inventory Data Base, Version 4.6, U.S. Geological Survey, Washington Water Science Center

DTIC Science & Technology

2006-01-01

collected, code both. Code Type of Analysis Code Type of Analysis A Physical properties I Common ions/trace elements B Common ions J Sanitary analysis and...1) A ground-water site is coded as if it is a single point, not a geographic area or property . (2) Latitude and longitude should be determined at a...terrace from an adjacent upland on one side, and a lowland coast or valley on the other. Due to the effects of erosion, the terrace surface may not be as

Application of microbial risk assessment to the development of standards for enteric pathogens in water used to irrigate fresh produce.

PubMed

Stine, Scott W; Song, Inhong; Choi, Christopher Y; Gerba, Charles P

2005-05-01

Microbial contamination of the surfaces of cantaloupe, iceberg lettuce, and bell peppers via contact with irrigation water was investigated to aid in the development of irrigation water quality standards for enteric bacteria and viruses. Furrow and subsurface drip irrigation methods were evaluated with the use of nonpathogenic surrogates, coliphage PRD1, and Escherichia coli ATCC 25922. The concentrations of hepatitis A virus (HAV) and Salmonella in irrigation water necessary to achieve a 1:10,000 annual risk of infection, the acceptable level of risk used for drinking water by the U.S. Environmental Protection Agency, were calculated with a quantitative microbial risk assessment approach. These calculations were based on the transfer of the selected nonpathogenic surrogates to fresh produce via irrigation water, as well as previously determined preharvest inactivation rates of pathogenic microorganisms on the surfaces of fresh produce. The risk of infection was found to be variable depending on type of crop, irrigation method, and days between last irrigation event and harvest. The worst-case scenario, in which produce is harvested and consumed the day after the last irrigation event and maximum exposure is assumed, indicated that concentrations of 2.5 CFU/100 ml of Salmonella and 2.5 x 10(-5) most probable number per 100 ml of HAV in irrigation water would result in an annual risk of 1:10,000 when the crop was consumed. If 14 days elapsed before harvest, allowing for die-off of the pathogens, the concentrations were increased to 5.7 x 10(3) Salmonella per 100 ml and 9.9 x 10(-3) HAV per 100 ml.

Partitioning of tritium between surface and bulk of 316 stainless steel at room temperature

DOE PAGES

Sharpe, M. D.; Fagan, C.; Shmayda, W. T.; ...

2018-03-28

The distribution of tritium between the near surface and the bulk of 316 stainless steel has been measured using two independent techniques: pulsed-plasma exposures and a zinc-chloride wash. Between 17% and 20% of the total inventory absorbed into a stainless-steel sample during a 24-h exposure to DT gas at room temperature resides in the water layers present on the metal surface. Redistribution of tritium between the surface and the bulk of stainless steel, if it occurs, is very slow. Finally, tritium does not appear to enter into the bulk at a rate defined solely by lattice diffusivity.

Partitioning of tritium between surface and bulk of 316 stainless steel at room temperature

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sharpe, M. D.; Fagan, C.; Shmayda, W. T.

The distribution of tritium between the near surface and the bulk of 316 stainless steel has been measured using two independent techniques: pulsed-plasma exposures and a zinc-chloride wash. Between 17% and 20% of the total inventory absorbed into a stainless-steel sample during a 24-h exposure to DT gas at room temperature resides in the water layers present on the metal surface. Redistribution of tritium between the surface and the bulk of stainless steel, if it occurs, is very slow. Finally, tritium does not appear to enter into the bulk at a rate defined solely by lattice diffusivity.

Bacteriophages as indicators of faecal pollution and enteric virus removal.

PubMed

McMinn, B R; Ashbolt, N J; Korajkic, A

2017-07-01

Bacteriophages are an attractive alternative to faecal indicator bacteria (FIB), particularly as surrogates of enteric virus fate and transport, due to their closer morphological and biological properties. Based on a review of published data, we summarize densities of coliphages (F+ and somatic), Bacteroides spp. and enterococci bacteriophages (phages) in individual human waste, raw wastewater, ambient fresh and marine waters and removal through wastewater treatment processes utilizing traditional treatments. We also provide comparisons with FIB and enteric viruses whenever possible. Lastly, we examine fate and transport characteristics in the aquatic environment and provide an overview of the environmental factors affecting their survival. In summary, concentrations of bacteriophages in various sources were consistently lower than FIB, but more reflective of infectious enteric virus levels. Overall, our investigation indicates that bacteriophages may be adequate viral surrogates, especially in built systems, such as wastewater treatment plants. Bacteriophage are alternative fecal indicators that may be better surrogates for viral pathogens than fecal indicator bacteria (FIB). This report offers a summary of the existing literature concerning the utility of bacteriophage as indicators of viral presence (fecal sources and surface waters) and persistence (in built infrastructure and aquatic environments). Our findings indicate that bacteriophage levels in all matrices examined are consistently lower than FIB, but similar to viral pathogens. Furthermore, in built infrastructure (e.g. wastewater treatment systems) bacteriophage closely mimic viral pathogen persistence suggesting they may be adequate sentinels of enteric virus removal. © 2017 The Society for Applied Microbiology.

Microbiological quality and safe handling of enteral diets in a hospital in Minas Gerais, Brazil

PubMed Central

Pinto, Raquel Oliveira Medrado; Correia, Eliznara Fernades; Pereira, Keyla Carvalho; Costa, Paulo de Souza; da Silva, Daniele Ferreira

2015-01-01

Contamination of enteral diets represents a high risk of compromising the patient's medical condition. To assess the microbiological quality and aseptic conditions in the preparation and administration of handmade and industrialized enteral diets offered in a hospital in the Valley of Jequitinhonha, MG, Brazil, we performed a microbiological analysis of 50 samples of diets and 27 samples of surfaces, utensils, and water used in the preparation of the diets. In addition, we assessed the good handling practices of enteral diets according to the requirements specified by the Brazilian legislation. Both kinds of enteral diets showed contamination by coliforms and Pseudomonas spp. No sample was positive for Staphylococcus aureus and Salmonella spp. On the other hand, Listeria spp. was detected in only one sample of handmade diets. Contamination was significantly higher in the handmade preparations (p < 0.05). Nonconformities were detected with respect to good handling practices, which may compromise the diet safety. The results indicate that the sanitary quality of the enteral diets is unsatisfactory, especially handmade diets. Contamination by Pseudomonas spp. is significant because it is often involved in infection episodes. With regard to aseptic practices, it was observed the need of implementing new procedures for handling enteral diets. PMID:26273278

Modeling the dispersal of Levantine Intermediate Water and its role in Mediterranean deep water formation

NASA Astrophysics Data System (ADS)

Wu, Peili; Haines, Keith

1996-03-01

This paper demonstrates the importance of Levantine Intermediate Water (LIW) in the deep water formation process in the Mediterranean using the modular ocean general circulation model at 0.25° resolution, 19 vertical levels, over the entire Mediterranean with an open Gibraltar strait. LIW formation is strongly prescribed in the Rhodes Gyre region by Haney [1971] relaxation, while in other regions, surface salinity relaxation is much reduced by applying the `mixed' thermohaline surface boundary conditions. Isopycnal diagnostics are used to trace water mass movements, and volume fluxes are monitored at straits. Low viscosity and diffusion are used to permit baroclinic eddies to play a role in water mass dispersal. The overall water budget is measured by an average flux at Gibraltar of 0.8 Sv, of which 0.7 Sv is exchanged with the eastern basin at Sicily. LIW (density around 28.95) spreads rapidly after formation throughout the entire Levantine due to baroclinic eddies. Toward the west, LIW accumulates in the northern and central Ionian, with some entering the Adriatic through Otranto and some mixing southward in eddies and exiting to the western Mediterranean through Sicily. LIW is converted to deep water in the south Adriatic at an average rate of 0.4 Sv. Water exchange through the Otranto strait appears to be buoyancy driven, with a strong bias to the end of winter (March-April), while at Sicily the exchange has a strong symmetric seasonal cycle, with maximum transport of 1.1 Sv in December indicating the effects of wind driving. LIW pathways in the west are complex and variable. In the Tyrrhenian, intermediate water becomes uniform on isopycnal surfaces due to eddy stirring. West of Sardinia, two LIW boundary currents are formed in the Balearic basin; one flows northward up the west coast of Sardinia and Corsica, and one westward along the northern African coast. The northward current is consistent with observations, while the westward current is intermittent for the first 10 years, often breaking up into eddies which enter the basin interior. Some observations of high-salinity waters near the African coast may support this interpretation. LIW retains a subsurface salinity maximum of 38.4-38.5 practical salinity units (psu) when reaching the northwestern Mediterranean, contrasting with surface waters fresher than 38.0 psu. West Mediterranean deep water is formed below 1500 m depth with climatological characteristics, when it is mixed and cooled during winter convection in Lions Gyre.

Optimization of a reusable hollow-fiber ultrafilter for simultaneous concentration of enteric bacteria, protozoa, and viruses from water.

PubMed

Morales-Morales, Hugo A; Vidal, Guadalupe; Olszewski, John; Rock, Channah M; Dasgupta, Debanjana; Oshima, Kevin H; Smith, Geoffrey B

2003-07-01

The detection and identification of pathogens from water samples remain challenging due to variations in recovery rates and the cost of procedures. Ultrafiltration offers the possibility to concentrate viral, bacterial, and protozoan organisms in a single process by using size-exclusion-based filtration. In this study, two hollow-fiber ultrafilters with 50,000-molecular-weight cutoffs were evaluated to concentrate microorganisms from 2- and 10-liter water samples. When known quantities (10(5) to 10(6) CFU/liter) of two species of enteric bacteria were introduced and concentrated from 2 liters of sterile water, the addition of 0.1% Tween 80 increased Escherichia coli strain K-12 recoveries from 70 to 84% and Salmonella enterica serovar Enteritidis recoveries from 36 to 72%. An E. coli antibiotic-resistant strain, XL1-Blue, was recovered at a level (87%) similar to that for strain K-12 (96%) from 10 liters of sterile water. When E. coli XL1-Blue was introduced into 10 liters of nonsterile Rio Grande water with higher turbidity levels (23 to 29 nephelometric turbidity units) at two inoculum levels (9 x 10(5) and 2.4 x 10(3) per liter), the recovery efficiencies were 89 and 92%, respectively. The simultaneous addition of E. coli XL1-Blue (9 x 10(5) CFU/liter), Cryptosporidium parvum oocysts (10 oocysts/liter), phage T1 (10(5) PFU/liter), and phage PP7 (10(5) PFU/liter) to 10 liters of Rio Grande surface water resulted in mean recoveries of 96, 54, 59, and 46%, respectively. Using a variety of surface waters from around the United States, we obtained recovery efficiencies for bacteria and viruses that were similar to those observed with the Rio Grande samples, but recovery of Cryptosporidium oocysts was decreased, averaging 32% (the site of collection of these samples had previously been identified as problematic for oocyst recovery). Results indicate that the use of ultrafiltration for simultaneous recovery of bacterial, viral, and protozoan pathogens from variable surface waters is ready for field deployment.

Transitional changes in microfossil assemblages in the Japan Sea from the Late Pliocene to Early Pleistocene related to global climatic and local tectonic events

NASA Astrophysics Data System (ADS)

Itaki, Takuya

2016-12-01

Many micropaleontological studies based on data from on-land sections, oil wells, and deep-sea drilling cores have provided important information about environmental changes in the Japan Sea that are related to the global climate and the local tectonics of the Japanese Islands. Here, major changes in the microfossil assemblages during the Late Pliocene to Early Pleistocene are reviewed. Late Pliocene (3.5-2.7 Ma) surface-water assemblages were characterized mainly by cold-temperate planktonic flora and fauna (nannofossils, diatoms, radiolarians, and planktonic foraminifera), suggesting that nutrient-rich North Pacific surface waters entered the Japan Sea via northern straits. The common occurrence of Pacific-type deep-water radiolarians during this period also suggests that deep water from the North Pacific entered the Japan Sea via the northern straits, indicating a sill depth >500 m. A weak warm-water influence is recognized along the Japanese coast, suggesting a small inflow of warm water via a southern strait. Nannofossil and sublittoral ostracod assemblages record an abrupt cooling event at 2.75 Ma that correlates with the onset of the Northern Hemisphere glaciation. Subsequently, cold intermediate- and deep-water assemblages of ostracods and radiolarians increased in abundance, suggesting active ventilation and the formation of the Japan Sea Proper Water, associated with a strengthened winter monsoon. Pacific-type deep-water radiolarians also disappeared around 2.75 Ma, which is attributed to the intermittent occurrence of deep anoxic environments and limited migration from the North Pacific, resulting from the near-closure or shallowing of the northern strait by a eustatic fall in sea level and tectonic uplift of northeastern Japan. A notable reduction in primary productivity from 2.3 to 1.3 Ma also suggests that the nutrient supply from the North Pacific was restricted by the near-closure of the northern strait. An increase in the abundance of subtropical surface fauna suggests that the inflow of the Tsushima Warm Current into the Japan Sea via a southern strait began at 1.7 Ma. The opening of the southern strait may have occurred after the subsidence of southwestern Japan.

Rotating Reverse-Osmosis for Water Purification

NASA Technical Reports Server (NTRS)

Lueptow, RIchard M.

2004-01-01

A new design for a water-filtering device combines rotating filtration with reverse osmosis to create a rotating reverse- osmosis system. Rotating filtration has been used for separating plasma from whole blood, while reverse osmosis has been used in purification of water and in some chemical processes. Reverse- osmosis membranes are vulnerable to concentration polarization a type of fouling in which the chemicals meant not to pass through the reverse-osmosis membranes accumulate very near the surfaces of the membranes. The combination of rotating filtration and reverse osmosis is intended to prevent concentration polarization and thereby increase the desired flux of filtered water while decreasing the likelihood of passage of undesired chemical species through the filter. Devices based on this concept could be useful in a variety of commercial applications, including purification and desalination of drinking water, purification of pharmaceutical process water, treatment of household and industrial wastewater, and treatment of industrial process water. A rotating filter consists of a cylindrical porous microfilter rotating within a stationary concentric cylindrical outer shell (see figure). The aqueous suspension enters one end of the annulus between the inner and outer cylinders. Filtrate passes through the rotating cylindrical microfilter and is removed via a hollow shaft. The concentrated suspension is removed at the end of the annulus opposite the end where the suspension entered.

Response of the Rio Grande and shallow ground water in the Mesilla Bolson to irrigation, climate stress, and pumping

USGS Publications Warehouse

Walton, J.; Ohlmacher, G.; Utz, D.; Kutianawala, M.

1999-01-01

The El Paso-Ciudad Juarez metropolitan area obtains its water from the Rio Grande and intermontane-basin aquifers. Shallow ground water in this region is in close communications with the surface water system. A major problem with both systems is salinity. Upstream usage of the water in the Rio Grande for irrigation and municipalities has led to concentration of soluble salts to the point where the surface water commonly exceeds drinking water standards. Shallow ground water is recharged by surface water (primarily irrigation canals and agricultural fields) and discharges to surface water (agricultural drains) and deeper ground water. The source of water entering the Rio Grande varies seasonally. During the irrigation season, water is released from reservoirs and mixes with the return flow from irrigation drains. During the non-irrigation season (winter), flow is from irrigation drains and river water quality is indicative of shallow ground water. The annual cycle can be ascertained from the inverse correlation between ion concentrations and discharge in the river. Water-quality data indicate that the salinity of shallow ground water increases each year during a drought. Water-management strategies in the region can affect water quality. Increasing the pumping rate of water-supply wells will cause shallow ground water to flow into the deeper aquifers and degrade the water quality. Lining the canals in the irrigation system to stop water leakage will lead to water quality degradation in shallow ground water and, eventually, deep ground water by removing a major source of high quality recharge that currently lowers the salinity of the shallow ground water.

Nitrogen in the environment: sources, problems, and management.

PubMed

Follett, R F; Hatfield, J L

2001-10-30

Nitrogen (N) is applied worldwide to produce food. It is in the atmosphere, soil, and water and is essential to all life. N for agriculture includes fertilizer, biologically fixed, manure, recycled crop residue, and soil-mineralized N. Presently, fertilizer N is a major source of N, and animal manure N is inefficiently used. Potential environmental impacts of N excreted by humans are increasing rapidly with increasing world populations. Where needed, N must be efficiently used because N can be transported immense distances and transformed into soluble and/or gaseous forms that pollute water resources and cause greenhouse effects. Unfortunately, increased amounts of gaseous N enter the environment as N2O to cause greenhouse warming and as NH3 to shift ecological balances of natural ecosystems. Large amounts of N are displaced with eroding sediments in surface waters. Soluble N in runoff or leachate water enters streams, rivers, and groundwater. High-nitrate drinking water can cause methemoglobinemia, while nitrosamines are associated with various human cancers. We describe the benefits, but also how N in the wrong form or place results in harmful effects on humans and animals, as well as to ecological and environmental systems.

Enteric Pathogen Survival Varies Substantially in Irrigation Water from Belgian Lettuce Producers

PubMed Central

Van Der Linden, Inge; Cottyn, Bart; Uyttendaele, Mieke; Berkvens, Nick; Vlaemynck, Geertrui; Heyndrickx, Marc; Maes, Martine

2014-01-01

It is accepted that irrigation water is a potential carrier of enteric pathogens, such as Salmonella and E. coli O157:H7 and, therefore, a source for contamination of fresh produce. We tested this by comparing irrigation water samples taken from five different greenhouses in Belgium. The water samples were inoculated with four zoonotic strains, two Salmonella and two E. coli O157:H7 strains, and pathogen survival and growth in the water were monitored up till 14 days. The influence of water temperature and chemical water quality was evaluated, and the survival tests were also performed in water samples from which the resident aquatic microbiota had previously been eliminated by filter sterilization. The pathogen’s survival differed greatly in the different irrigation waters. Three water samples contained nutrients to support important growth of the pathogens, and another enabled weaker growth. However, for all, growth was only observed in the samples that did not contain the resident aquatic microbiota. In the original waters with their specific water biota, pathogen levels declined. The same survival tendencies existed in water of 4 °C and 20 °C, although always more expressed at 20 °C. Low water temperatures resulted in longer pathogen survival. Remarkably, the survival capacity of two E. coli 0157:H7 strains differed, while Salmonella Thompson and Salmonella Typhimurium behaved similarly. The pathogens were also transferred to detached lettuce leaves, while suspended in two of the water samples or in a buffer. The effect of the water sample on the pathogen’s fitness was also reproduced on the leaves when stored at 100% relative humidity. Inoculation of the suspension in buffer or in one of the water samples enabled epiphytic growth and survival, while the pathogen level in the other water sample decreased once loaded on the leaves. Our results show that irrigation waters from different origin may have a different capacity to transmit enteric pathogens and an important impact on the fitness of the pathogens to sustain and even grow on the leaf surface. PMID:25268508

Approaches for integrated assessment of ecological and eutrophication status of surface waters in Nordic Countries.

PubMed

Andersen, Jesper H; Aroviita, Jukka; Carstensen, Jacob; Friberg, Nikolai; Johnson, Richard K; Kauppila, Pirkko; Lindegarth, Mats; Murray, Ciarán; Norling, Karl

2016-10-01

We review approaches and tools currently used in Nordic countries (Denmark, Finland, Norway and Sweden) for integrated assessment of 'ecological status' sensu the EU Water Framework Directive as well as assessment of 'eutrophication status' in coastal and marine waters. Integration principles for combining indicators within biological quality elements (BQEs) and combining BQEs into a final-integrated assessment are discussed. Specific focus has been put on combining different types of information into indices, since several methods are currently employed. As a consequence of the variety of methods used, comparisons across both BQEs and water categories (river, lakes and coastal waters) can be difficult. Based on our analyses, we conclude that some principles and methods for integration can be critical and that a harmonised approach should be developed. Further, we conclude that the integration principles applied within BQEs are critical and in need of harmonisation if we want a better understanding of potential transition in ecological status between surface water types, e.g. when riverine water enters a downstream lake or coastal water body.

Effects of landscape-based green infrastructure on stormwater ...

EPA Pesticide Factsheets

The development of impervious surfaces in urban and suburban catchments affects their hydrological behavior by decreasing infiltration, increasing peak hydrograph response following rainfall events, and ultimately increasing the total volume of water and mass of pollutants reaching streams. These changes have deleterious effects on downstream surface waters. Consequently, strategies to mitigate these impacts are now components of contemporary urban development and stormwater management. This study evaluates the effectiveness of landscape green infrastructure (GI) in reducing stormwater runoff volumes and controlling peak flows in four subdivision-scale suburban catchments (1.88 – 12.97 acres) in Montgomery County, MD, USA. Stormwater flow rates during runoff events were measured in five minute intervals at each catchment outlet. One catchment was built with GI vegetated swales on all parcels with the goal of intercepting, conveying, and infiltrating stormwater before it enters the sewer network. The remaining catchments were constructed with traditional gray infrastructure and “end-of-pipe” best management practices (BMPs) that treat stormwater before entering streams. This study compared characteristics of rainfall-runoff events at the green and gray infrastructure sites to understand their effects on suburban hydrology. The landscape GI strategy generally reduced rainfall-runoff ratios compared to gray infrastructure because of increased infiltration, ul

Geochemistry of the Mattole River in Northern California

USGS Publications Warehouse

Kennedy, Vance C.; Malcolm, Ronald L.

1977-01-01

The chemical composition of streams can vary greatly with changing discharge during storm runoff. These chemical changes are related to the pathways of various water parcels from the time they fall as rain until they enter the stream, and to the interactions between water and sediment during transport downstream. In order to understand better the chemical variations during storms, an extensive investigation was made of the Mattole River, a chemically clean coastal stream in Mendocino County, California. The Mattole drains a topographically mature basin of 620 sw km which has relief of about 1200 m, a long summer dry season, and mean annual rainfall of about 2300 mm. The stream flow is composed of seasonally varying proportions of four flow components, namely, surface runoff, quick-return flow (rainfall having brief and intimate contact with the soil before entering the surface drainage), delayed-return flow, and base runoff. Each component is identified by its characteristic chemistry and by the time delay between rainfall and entrance into the stream. Information is also presented on rain chemistry, adsorption reactions of suspended sediments in the fresh and brackish environments, and compositional variation of river sediments with particle size. (Woodard-USGS)

Process and apparatus for coal hydrogenation

DOEpatents

Ruether, John A.

1988-01-01

In a coal liquefaction process an aqueous slurry of coal is prepared containing a dissolved liquefaction catalyst. A small quantity of oil is added to the slurry and then coal-oil agglomerates are prepared by agitation of the slurry at atmospheric pressure. The resulting mixture of agglomerates, excess water, dissolved catalyst, and unagglomerated solids is pumped to reaction pressure and then passed through a drainage device where all but a small amount of surface water is removed from the agglomerates. Sufficient catalyst for the reaction is contained in surface water remaining on the agglomerates. The agglomerates fall into the liquefaction reactor countercurrently to a stream of hot gas which is utilized to dry and preheat the agglomerates as well as deposit catalyst on the agglomerates before they enter the reactor where they are converted to primarily liquid products under hydrogen pressure.

43 CFR 404.56 - If a financial assistance agreement is entered into for a rural water supply project that...

Code of Federal Regulations, 2010 CFR

2010-10-01

... entered into for a rural water supply project that benefits more than one Indian tribe, is the approval of... Lands BUREAU OF RECLAMATION, DEPARTMENT OF THE INTERIOR RECLAMATION RURAL WATER SUPPLY PROGRAM Miscellaneous § 404.56 If a financial assistance agreement is entered into for a rural water supply project that...

Secondary Channel Bifurcation Geometry: A Multi-dimensional Problem

NASA Astrophysics Data System (ADS)

Gaeuman, D.; Stewart, R. L.

2017-12-01

The construction of secondary channels (or side channels) is a popular strategy for increasing aquatic habitat complexity in managed rivers. Such channels, however, frequently experience aggradation that prevents surface water from entering the side channels near their bifurcation points during periods of relatively low discharge. This failure to maintain an uninterrupted surface water connection with the main channel can reduce the habitat value of side channels for fish species that prefer lotic conditions. Various factors have been proposed as potential controls on the fate of side channels, including water surface slope differences between the main and secondary channels, the presence of main channel secondary circulation, transverse bed slopes, and bifurcation angle. A quantitative assessment of more than 50 natural and constructed secondary channels in the Trinity River of northern California indicates that bifurcations can assume a variety of configurations that are formed by different processes and whose longevity is governed by different sets of factors. Moreover, factors such as bifurcation angle and water surface slope vary with discharge level and are continuously distributed in space, such that they must be viewed as a multi-dimensional field rather than a single-valued attribute that can be assigned to a particular bifurcation.

ANNUAL WATER BUDGETS FOR A FORESTED SINKHOLE WETLAND

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hill, Dr. Andrew Jason; Neary, Vincent S

2012-01-01

Annual water budgets spanning two years, 2004 and 2005, are constructed for a sinkhole wetland in the Tennessee Highland Rim following conversion of 13 % of its watershed to impervious surfaces. The effect of watershed development on the hydrology of the study wetland was significant. Surface runoff was the dominant input, with a contribution of 61.4 % of the total. An average of 18.9 % of gross precipitation was intercepted by the canopy and evaporated. Seepage from the surface water body to the local groundwater system accounted for 83.1 % of the total outflow. Deep recharge varied from 43.2 %more » (2004) to 12.1 % (2005) of total outflow. Overall, evapotranspiration accounted for 72.4 % of the total losses, with an average of 65.7 % lost from soil profile storage. The annual water budgets indicate that deep recharge is a significant hydrologic function performed by isolated sinkhole wetlands, or karst pans, on the Tennessee Highland Rim. Continued hydrologic monitoring of sinkhole wetlands are needed to evaluate hydrologic function and response to anthropogenic impacts. The regression technique developed to estimate surface runoff entering the wetland is shown to provide reasonable annual runoff estimates, but further testing is needed.« less

Positive Enteric Contrast Material for Abdominal and Pelvic CT with Automatic Exposure Control: What Is the Effect On Patient Radiation Exposure?

PubMed Central

Wang, Zhen J.; Chen, Katherine S.; Gould, Robert; Coakley, Fergus V.; Fu, Yanjun; Yeh, Benjamin M.

2014-01-01

Objective To assess the effect of positive enteric contrast administration on automatic exposure control (AEC) CT radiation exposure in 1) a CT phantom, and 2) a retrospective review of patients. Materials and Methods We scanned a CT phantom containing simulated bowel that was sequentially filled with water and positive enteric contrast, and recorded the mean volume CT dose index (CTDIvol). We also identified 17 patients who had undergone 2 technically comparable CT scans of the abdomen and pelvis, one with positive enteric contrast and the other with oral water. Paired student t-tests were used to compare the mean CTDIvol between scans performed with and without positive enteric contrast. Both the phantom and patient CT scans were performed using AEC with a fixed noise index. Results The mean CTDIvol for the phantom with simulated bowel containing water and positive enteric contrast were 8.2 ± 0.2 mGy, and 8.7 ± 0.1 mGy (6.1% higher than water, p=0.02), respectively. The mean CTDIvol for patients scanned with oral water and with positive enteric contrast were 11.8mGy and 13.1mGy, respectively (p=0.003). This corresponded to a mean CTDIvol which was 11.0% higher (range: 0.0–20.7% higher) in scans with positive enteric contrast than those with oral water in patients. Conclusions When automatic exposure control is utilized for abdominopelvic CT, the radiation exposure, as measured by CTDIvol, is higher for scans performed with positive enteric contrast than those with oral water. PMID:21493028

Pepper mild mottle virus as an indicator and a tracer of fecal pollution in water environments: comparative evaluation with wastewater-tracer pharmaceuticals in Hanoi, Vietnam.

PubMed

Kuroda, Keisuke; Nakada, Norihide; Hanamoto, Seiya; Inaba, Manami; Katayama, Hiroyuki; Do, An Thuan; Nga, Tran Thi Viet; Oguma, Kumiko; Hayashi, Takeshi; Takizawa, Satoshi

2015-02-15

We analyzed pepper mild mottle virus (PMMoV) in 36 samples taken from surface water, wastewater, groundwater, tap water and bottled water in Hanoi, Vietnam. We then compared the occurrence and fates of PMMoV with pharmaceuticals and personal care products (PPCPs), which are known wastewater tracers. PMMoV was detected in 94% of the surface water samples (ponds, water from irrigated farmlands and rivers) and in all the wastewater samples. The PMMoV concentration ranged from 5.5×10(6)-7.2×10(6)copies/L in wastewater treatment plant (WWTP) influents, 6.5×10(5)-8.5×10(5)copies/L in WWTP effluents and 1.0×10(4)-1.8×10(6)copies/L in surface water. Among the sixty PPCPs analyzed, caffeine and carbamazepine had high detection rates in surface water (100% and 88%, respectively). In surface water, the concentration ratio of PMMoV to caffeine remained unchanged than that in WWTP influents, suggesting that the persistence of PMMoV in surface water was comparable to that of caffeine. The persistence and the large concentration ratio of PMMoV in WWTP influents to the method detection limit would account for its ubiquitous detection in surface water. In comparison, human enteric viruses (HEV) were less frequently detected (18-59%) than PMMoV in surface water, probably because of their faster decay. Together with the reported high human feces-specificity, our results suggested that PMMoV is useful as a sensitive fecal indicator for evaluating the potential occurrence of pathogenic viruses in surface water. Moreover, PMMoV can be useful as a moderately conservative fecal tracer for specifically tracking fecal pollution of surface water. PMMoV was detected in 38% of the groundwater samples at low concentrations (up to 19copies/L). PMMoV was not detected in the tap water and bottled water samples. In groundwater, tap water and bottled water samples, the occurrence of PPCPs and HEV disagreed with that of PMMoV, suggesting that PMMoV is not suitable as an indicator or a tracer in those waters. Copyright © 2014 Elsevier B.V. All rights reserved.

Effect of Coadsorbed Water on the Photodecomposition of Acetone on TiO2(110)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Henderson, Michael A.

2008-06-10

The influence of coadsorbed water on the photodecomposition of acetone on TiO2 was examined using temperature programmed desorption (TPD) and the rutile TiO2(110) surface as a model photocatalyst. Of the two major influences ascribed to water in the heterogeneous photocatalysis literature (promotion via OH radical supply and inhibition due to site blocking), only the negative influence of water was observed. As long as the total water and acetone coverage was maintained well below the first layer saturation coverage (‘1 ML’), little inhibition of acetone photodecomposition was observed. However, as the total water+acetone coverage exceeded 1 ML, acetone was preferentially displacedmore » from the first layer to physisorbed states by water and the extent of acetone photodecomposition attenuated. The displacement originated from water compressing acetone into high coverage regions where increased acetone-acetone repulsions caused displacement from the first layer. The immediate product of acetone photodecomposition was adsorbed acetate, which occupies twice as many surface sites per molecule as compared to acetone. Since the acetate intermediate was more stable on the TiO2(110) surface than either water or acetone (as gauged by TPD) and since its photodecomposition rate was less than that of acetone, additional surface sites were not opened up during acetone photodecomposition for previously displaced acetone molecules to re-enter the first layer. Results in this study suggest that increased molecular-level repulsions between organic molecules brought about by increased water coverage are as influential in the inhibiting effect of water on photooxidation rates as are water-organic repulsions.« less

Irrigated acreage and other land uses on the Snake River Plain, Idaho and eastern Oregon

USGS Publications Warehouse

Lindholm, Gerald F.; Goodell, S.A.

1986-01-01

Prompted by the need for a current, accurate, and repeatable delineation of irrigated acreage on the Snake River Plain, the U.S. Geological Survey entered into a cooperative agreement with the Idaho Department of Water Resources Image Analysis Facility and the U.S. Bureau of Reclamation to delineate 1980 land use form Landsat data. Irrigated acreage data were needed as input to groundwater flow models developed by the U.S. Geological Survey in a study of the regional aquifer system underlying the Snake River Plain. Single-date digital multispectral scanner data analyzed to delineate land-use classes. Source of irrigation water (surface water, ground water, and combined) was determined from county maps of 1975 water-related land use, data from previous investigations, and field checking. Surface-water diversions for irrigation on the Snake River Plain began in the 1840's. With the stimulus of Federal aid authorized by the Desert Land Act, Carey Act, and Reclamation Act, irrigated area increased rapidly in the early 1900's. By 1929, 2.2 million acres were irrigated. Ground water became and important source of irrigation water after World War II. In 1980, about 3.1 million acres of the Snake River Plain were irrigate: 2.0 million acres with surface water, 1.0 million with ground water, and 0.1 million with combined surface and ground water. About 5.2 million acres (half of the plain) are undeveloped rangeland, 1.0 million acres (one-tenth) are classified as barren. The remaining land is a mixture of dryland agriculture, water bodies, wetland, forests, and urban areas.

Animated molecular dynamics simulations of hydrated caesium-smectite interlayers

PubMed Central

Sutton, Rebecca; Sposito, Garrison

2002-01-01

Computer animation of center of mass coordinates obtained from 800 ps molecular dynamics simulations of Cs-smectite hydrates (1/3 and 2/3 water monolayers) provided information concerning the structure and dynamics of the interlayer region that could not be obtained through traditional simulation analysis methods. Cs+ formed inner sphere complexes with the mineral surface, and could be seen to jump from one attracting location near a layer charge site to the next, while water molecules were observed to migrate from the hydration shell of one ion to that of another. Neighboring ions maintained a partial hydration shell by sharing water molecules, such that a single water molecule hydrated two ions simultaneously for hundreds of picoseconds. Cs-montmorillonite hydrates featured the largest extent of this sharing interaction, because interlayer ions were able to inhabit positions near surface cavities as well as at their edges, close to oxygen triads. The greater positional freedom of Cs+ within the montmorillonite interlayer, a result of structural hydroxyl orientation and low tetrahedral charge, promoted the optimization of distances between cations and water molecules required for water sharing. Preference of Cs+ for locations near oxygen triads was observed within interlayer beidellite and hectorite. Water molecules also could be seen to interact directly with the mineral surface, entering its surface cavities to approach attracting charge sites and structural hydroxyls. With increasing water content, water molecules exhibited increased frequency and duration of both cavity habitation and water sharing interactions. Competition between Cs+ and water molecules for surface sites was evident. These important cooperative and competitive features of interlayer molecular behavior were uniquely revealed by animation of an otherwise highly complex simulation output.

Movement of coliform bacteria and nutrients in ground water flowing through basalt and sand aquifers.

PubMed

Entry, J A; Farmer, N

2001-01-01

Large-scale deposition of animal manure can result in contamination of surface and ground water and in potential transfer of disease-causing enteric bacteria to animals or humans. We measured total coliform bacteria (TC), fecal coliform bacteria (FC), NO3, NH4, total P, and PO4 in ground water flowing from basalt and sand aquifers, in wells into basalt and sand aquifers, in irrigation water, and in river water. Samples were collected monthly for 1 yr. Total coliform and FC numbers were always higher in irrigation water than in ground water, indicating that soil and sediment filtered most of these bacteria before they entered the aquifers. Total coliform and FC numbers in ground water were generally higher in the faster flowing basalt aquifer than in the sand aquifer, indicating that the slower flow and finer grain size may filter more TC and FC bacteria from water. At least one coliform bacterium/100 mL of water was found in ground water from both basalt and sand aquifers, indicating that ground water pumped from these aquifers is not necessarily safe for human consumption according to the American Public Health Association and the USEPA. The NO3 concentrations were usually higher in water flowing from the sand aquifer than in water flowing from the basalt aquifer or in perched water tables in the basalt aquifer. The PO4 concentrations were usually higher in water flowing from the basalt aquifer than in water flowing from the sand aquifer. The main concern is fecal contamination of these aquifers and health consequences that may arise from human consumption.

Linking atmospheric synoptic transport, cloud phase, surface energy fluxes, and sea-ice growth: observations of midwinter SHEBA conditions

NASA Astrophysics Data System (ADS)

Persson, P. Ola G.; Shupe, Matthew D.; Perovich, Don; Solomon, Amy

2017-08-01

Observations from the Surface Heat Budget of the Arctic Ocean (SHEBA) project are used to describe a sequence of events linking midwinter long-range advection of atmospheric heat and moisture into the Arctic Basin, formation of supercooled liquid water clouds, enhancement of net surface energy fluxes through increased downwelling longwave radiation, and reduction in near-surface conductive heat flux loss due to a warming of the surface, thereby leading to a reduction in sea-ice bottom growth. The analyses provide details of two events during Jan. 1-12, 1998, one entering the Arctic through Fram Strait and the other from northeast Siberia; winter statistics extend the results. Both deep, precipitating frontal clouds and post-frontal stratocumulus clouds impact the surface radiation and energy budget. Cloud liquid water, occurring preferentially in stratocumulus clouds extending into the base of the inversion, provides the strongest impact on surface radiation and hence modulates the surface forcing, as found previously. The observations suggest a minimum water vapor threshold, likely case dependent, for producing liquid water clouds. Through responses to the radiative forcing and surface warming, this cloud liquid water also modulates the turbulent and conductive heat fluxes, and produces a thermal wave penetrating into the sea ice. About 20-33 % of the observed variations of bottom ice growth can be directly linked to variations in surface conductive heat flux, with retarded ice growth occurring several days after these moisture plumes reduce the surface conductive heat flux. This sequence of events modulate pack-ice wintertime environmental conditions and total ice growth, and has implications for the annual sea-ice evolution, especially for the current conditions of extensive thinner ice.

Mechanisms for surface contamination of soils and bottom sediments in the Shagan River zone within former Semipalatinsk Nuclear Test Site.

PubMed

Aidarkhanov, A O; Lukashenko, S N; Lyakhova, O N; Subbotin, S B; Yakovenko, Yu Yu; Genova, S V; Aidarkhanova, A K

2013-10-01

The Shagan River is the only surface watercourse within the former Semipalatinsk Test Site (STS). Research in the valley of the Shagan River was carried out to study the possible migration of artificial radionuclides with surface waters over considerable distances, with the possibility these radionuclides may have entered the Irtysh River. The investigations revealed that radioactive contamination of soil was primarily caused by the first underground nuclear test with soil outburst conducted at the "Balapan" site in Borehole 1004. The surface nuclear tests carried out at the "Experimental Field" site and global fallout made insignificant contributions to contamination. The most polluted is the area in the immediate vicinity of the "Atomic" Lake crater. Contamination at the site is spatial. The total area of contamination is limited to 10-12 km from the crater piles. The ratio of plutonium isotopes was useful to determine the source of soil contamination. There was virtual absence of artificial radionuclide migration with surface waters, and possible cross-border transfer of radionuclides with the waters of Shagan and Irtysh rivers was not confirmed. Copyright © 2013 Elsevier Ltd. All rights reserved.

Effective charges and zeta potentials of oil in water microemulsions in the presence of Hofmeister salts.

PubMed

Dos Santos, Alexandre P; Levin, Yan

2018-06-14

We present a theory which allows us to calculate the effective charge and zeta potential of oil droplets in microemulsions containing Hofmeister salts. A modified Poisson-Boltzmann equation is used to account for the surface and ion polarizations and hydrophobic and dispersion interactions. The ions are classified as kosmotropes and chaotropes according to their Jones-Dole viscosity B coefficient. Kosmotropes stay hydrated and do not enter into the oil phase, while chaotropes can adsorb to the oil-water interface. The effective interaction potentials between ions and oil-water interface are parametrized so as to accurately account for the excess interfacial tension.

Effective charges and zeta potentials of oil in water microemulsions in the presence of Hofmeister salts

NASA Astrophysics Data System (ADS)

dos Santos, Alexandre P.; Levin, Yan

2018-06-01

We present a theory which allows us to calculate the effective charge and zeta potential of oil droplets in microemulsions containing Hofmeister salts. A modified Poisson-Boltzmann equation is used to account for the surface and ion polarizations and hydrophobic and dispersion interactions. The ions are classified as kosmotropes and chaotropes according to their Jones-Dole viscosity B coefficient. Kosmotropes stay hydrated and do not enter into the oil phase, while chaotropes can adsorb to the oil-water interface. The effective interaction potentials between ions and oil-water interface are parametrized so as to accurately account for the excess interfacial tension.

Environmental factors and chemical and microbiological water-quality constituents related to the presence of enteric viruses in ground water from small public water supplies in southeastern Michigan

USGS Publications Warehouse

Francy, Donna S.; Bushon, Rebecca N.; Stopar, Julie; Luzano, Emma J.; Fout, G. Shay

2004-01-01

A study of small public ground-water-supply wells that produce water from discontinuous sand and gravel aquifers was done from July 1999 through July 2001 in southeastern Michigan. Samples were collected to determine the occurrence of viral pathogens and microbiological indicators of fecal contamination (indicators), determine whether indicators are adequate predictors of the presence of enteric viruses, and determine the factors that affect the presence of enteric viruses. Small systems are those that serve less than 3,300 people. Samples were analyzed for specific enteric viruses by reverse transcriptase-polymerase chain reaction (RT-PCR), for culturable viruses by cell culture, and for the indicators total coliforms, Escherichia coli (E. coli), enterococci, and F-specific and somatic coliphage. Ancillary environmental and water-quality data were collected or compiled. A total of 169 regular samples and 32 replicate pairs were collected from 38 wells. Replicate pairs were samples collected at the same well on the same date. One well was sampled 6 times, 30 wells were sampled five times, 6 wells were sampled twice, and 1 well was sampled once. By use of RT-PCR, enterovirus was found in four wells (10.5 percent) and hepatitis A virus (HAV) in five wells (13.2 percent). In two of these wells, investigators found both enterovirus and HAV, but on different sampling dates. Culturable viruses were found one time in two wells (5.9 percent), and neither of these wells was positive for viruses by use of RT-PCR on any sampling date. If results for all viruses are combined, 9 of the 38 small public-supply wells were positive for enteric viruses (23.7 percent) by either cell culture or RT-PCR. One or more indicators were found in 18 of 38 wells. Total coliforms, E. coli, enterococci, and F-specific and somatic coliphage were found in 34.2, 10.5, 15.8, 5.9, and 5.9 percent, respectively, of the wells tested. In only 3 out of 18 wells were samples positive for an indicator on more than one date at the same well. The co-occurrence of enteric viruses and any indicator was 55.6 percent; five out of the nine virus-positive wells were also found to be positive for an indicator. Two wells with detections of viruses had a detection of total coliforms, one well had a detection of E. coli, one of enterococci, and one of F-specific coliphage. On a per sample basis, of 11 samples that were positive for enteric viruses, indicator bacteria co-occurred in only 2 samples, and coliphage were not present in any. More virus-positive samples were found at sites served by septic systems than those served by sewerlines. Sampling condition (ground water or a mixture of tank and ground water), distance to septic system, type of and distance to nearest surface-water body, well characteristics, or land use were not related to the presence of viruses or indicators. Among continuous water-quality variables, statistically significant relations were found between total coliforms and dissolved organic carbon and between total coliforms and iron. There was a statistically significant relation between chloride concentrations >20 mg/L and detections of total coliforms. Presence of nitrate and nitrite was related to the presence of other indicators (E. coli, enterococci, and F-specific and somatic coliphage) or enteric viruses, but not to total coliforms. The data indicated that chloride-to-bromide (C1:Br) ratios may be useful as a screening tool for total coliforms and enteric viruses but not for E. coli, enterococci, and F-specific and somatic coliphage. This study provides evidence for fecal contamination of ground water from small public-supply wells, at least on an intermittent basis. Collecting data on multiple lines of evidence would be needed to reliably predict the presence of enteric viruses and protect public health. Future data collection toward this end could include repeat sampling several times a year for different indicators, measuring dissolv

Prevalence of Shiga toxin producing Escherichia coli, Salmonella enterica and Listeria monocytogenes at public access watershed sites in a California central coast agricultural region

USDA-ARS?s Scientific Manuscript database

Produce contaminated with enteric pathogens is a major source of foodborne illness in the United States. Surface water regions serves as both a source and a vehicle for transport of pathogens to produce in the field. Lakes, streams, rivers, and ponds at 30 locations in the vicinity of a leafy green ...

Stream denitrification across biomes and its response to anthropogenic nitrate loading

Treesearch

Patrick J. Mulholland; Ashley M. Helton; Geoffrey C. Poole; Robert O. Hall; Stephen K. Hamilton; et al

2008-01-01

Anthropogenic addition of bioavailable nitrogen to the biosphere is increasing1, 2 and terrestrial ecosystems are becoming increasingly nitrogen-saturated3, causing more bioavailable nitrogen to enter groundwater and surface waters4, 5, 6. Large-scale nitrogen budgets show that an average of about 20–25 per cent of the nitrogen added to the biosphere is exported from...

Micropollutants in urban watersheds : substance flow analysis as management tool

NASA Astrophysics Data System (ADS)

Rossi, L.; Copin, P. J.; Barry, A. D.; Bader, H.-P.; Scheidegger, R.; Chèvre, N.

2009-04-01

Micropollutants released by cities into water are of increasing concern as they are suspected of inducing long-term effects on both aquatic organisms and humans (eg., hormonally active substances). Substances found in the urban water cycle have different sources in the urban area and different fates in this cycle. For example, the pollutants emitted from traffic, like copper or PAHs get to surface water during rain events often without any treatment. Pharmaceuticals resulting from human medical treatments get to surface water mainly through wastewater treatment plants, where they are only partly treated and eliminated. One other source of contamination in urban areas for these compounds are combined sewer overflows (CSOs). Once in the receiving waters (lakes, rivers, groundwater), these substances may re-enter the cycle through drinking water. It is therefore crucial to study the behaviour of micropollutants in the urban water cycle and to get flexible tools for urban water management. Substance flow analysis (SFA) has recently been proposed as instrument for water pollution management in urban water systems. This kind of analysis is an extension of material flow analysis (MFA) originally developed in the economic sector and later adapted to regional investigations. In this study, we propose to test the application of SFA for a large number of classes of micropollutants to evaluate its use for urban water management. We chose the city of Lausanne as case study since the receiving water of this city (Lake Geneva) is an important source of drinking water for the surrounding population. Moreover a profound system-knowledge and many data were available, both on the sewer system and the water quality. We focus our study on one heavy metal (copper) and four pharmaceuticals (diclofenac, ibuprofen, carbamazepine and naproxen). Results conducted on copper reveals that around 1500 kg of copper enter the aquatic compartment yearly. This amount contributes to sediment enrichment, which may pose a long-term risk for the benthic organisms. The major sources (total of 73%) of copper in receiving surface water are roofs and contact lines of trolleybuses. Thus technical solutions have to be found to manage this specific source of contamination. Application of SFA approach to four pharmaceuticals reveals that CSOs represent an important source of contamination: Between 14% (carbamazepine) and 61% (ibuprofen) of the total annual loads of Lausanne city to the Lake are due to CSOs. These results will help in defining the best management strategy to limit Lake Geneva contamination. SFA is thus a promising tool for integrated urban water management.

Late Quaternary Palaeoceanographic Changes in Sea Surface Conditions in the Tropical Atlantic

NASA Astrophysics Data System (ADS)

Fischel, Andrea; Seidenkrantz, Marit-Solveig; Kuijpers, Antoon; Nürnberg, Dirk

2013-04-01

Palaeoceanographic changes and the variability in surface water mass hydrography are reconstructed in order to track tropical ocean and climate variability and inter-hemispheric heat exchange through the last 42,000 year BP. Our studies are based on the relative abundance of planktonic foraminifera combined with sea surface temperature approximation based Mg/Ca measurements, XRF scanning and stable oxygen isotope analyses in a 5 m long gravity core Ga307-Win-12GC (17°50.80N, 64°48.7290W), retrieved in the Virgin Island Basin in approx. 3,960 m water depth. The Virgin Island Basin is the deepest part of the Anegada-Jungfern Passage in the northeast Caribbean, one of the most important pathways for water mass exchange between the Central Atlantic and the Caribbean Sea. Due to its bathymetry surface waters as well as deep water mass strata from the northern and southern hemisphere enter the basin, comprising Caribbean Surface Water (CSW), Antarctic Intermediate Water (AAIW), Atlantic Intermediate Water (AIW) and North Atlantic Deep Water (NADW). The planktonic foraminiferal assemblage suggests rather stable sea-surface conditions during the Holocene in the NE Caribbean. However, major changes in the hydrographic setting could be identified within the glacial period. During the glacial period, clear millennial-scale variability in sea-surface temperature and productivity are present. Fluctuations in the relative abundance of Globigerinoides ruber in the sediment core may be correlated to Dansgaard-Oeschger events in the northern North Atlantic. Furthermore an increase in relative abundance of Globorotalia rubescens occurs synchronous with ice rafted debris layers described from the North Atlantic. The faunal changes in the tropical Atlantic may thus be correlated to major climate changes in the North Atlantic, mainly D-O cyclicity as well as Heinrich events. Thus, the synchronous change in water mass distribution and hydrographic cyclicity suggests a possible linkage between tropical and North Atlantic Ocean variability during the Late Quaternary.

Hydrogeologic characteristics of four public drinking-water supply springs in northern Arkansas

USGS Publications Warehouse

Galloway, Joel M.

2004-01-01

In October 2000, a study was undertaken by the U.S. Geological Survey (USGS) in cooperation with the Arkansas Department of Health to determine the hydrogeologic characteristics, including the extent of the recharge areas, for Hughes Spring, Stark Spring, Evening Shade Spring, and Roaring Spring, which are used for public-water supply in northern Arkansas. Information pertaining to each spring can be used to enable development of effective management plans to protect these water resources and public health. An integrated approach to determine the ground-water characteristics and the extent of the local recharge areas of the four springs incorporated tools and methods of hydrology, structural geology, geomorphology, geophysics, and geochemistry. Analyses of discharge, temperature, and water quality were completed to describe ground-water flow characteristics, source-water characteristics, and connectivity of the ground-water system with surface runoff. Water-level contour maps were constructed to determine ground-water flow directions and ground-water tracer tests were conducted to determine the extent of the recharge areas and ground-water flow velocities. Hughes Spring supplies water for the city of Marshall, Arkansas, and the surrounding area. The mean annual discharge for Hughes Spring was 2.9 and 5.2 cubic feet per second for water years 2001 and 2002, respectively. Recharge to the spring occurs mainly from the Boone Formation (Springfield Plateau aquifer). Ground-water tracer tests indicate the recharge area for Hughes Spring generally coincides with the surface drainage area (15.8 square miles) and that Hughes Spring is connected directly to the surface flow in Brush Creek. The geochemistry of Hughes Spring demonstrated variations with flow conditions and the influence of surface-runoff in the recharge area. Calcite saturation indices, total dissolved solids concentrations, and hardness demonstrate noticeable differences with flow conditions reflecting the reduced residence time and interaction of water with the source rock within the ground-water system at higher discharges for Hughes Spring. Concentrations of fecal indicator bacteria also demonstrated a substantial increase during high-flow conditions, suggesting that a non-point source of bacteria possibly from livestock may enter the system. Conversely, nutrient concentrations did not vary with flow and were similar to concentrations reported for undeveloped sites in the Springfield Plateau and Ozark aquifers in northern Arkansas and southern Missouri. Deuterium and oxygen-18 data show that the Hughes Spring discharge is representative of direct precipitation and not influenced by water enriched in oxygen-18 through evaporation. Discharge data show that Hughes Spring is dominated by conduit type ground-water flow, but a considerable component of diffuse flow also exists in the ground-water system. Carbon-13 data indicate a substantial component of the recharge water interacts with the surface material (soil and regolith) in the recharge area before entering the ground-water system for Hughes Spring. Tritium data for Hughes Spring indicate that the discharge water is a mixture of recent recharge and sub-modern water (recharged prior to 1952). Stark Spring supplies water for the city of Cushman, Arkansas, and the surrounding area. 2 Hydrogeologic Characteristics of Four Public Drinking-Water Supply Springs in Northern Arkansas The mean annual discharge for Stark Spring was 0.5 and 1.5 cubic feet per second for water years 2001 and 2002, respectively. The discharge and water-quality data show the ground-water system for Stark Spring is dominated by rapid recharge from surface runoff and mainly consists of a conduit- type flow system with little diffuse-type flow. Analyses of discharge data show that the estimated recharge area (0.79 square mile) is larger than the surface drainage area (0.34 square mile). Ground-water tracer tests and the outcrop of the

A review of contamination of surface-, ground-, and drinking water in Sweden by perfluoroalkyl and polyfluoroalkyl substances (PFASs).

PubMed

Banzhaf, Stefan; Filipovic, Marko; Lewis, Jeffrey; Sparrenbom, Charlotte J; Barthel, Roland

2017-04-01

Perfluoroalkyl and polyfluoroalkyl substances (PFASs) are found in aquatic systems, flora, and fauna worldwide. These potentially harmful compounds are also frequently detected in Sweden and have already resulted in severe problems for public drinking water supply, i.e., some wells had to be closed due to high PFAS concentrations both in raw water and produced drinking water. Knowledge on PFAS occurrence in Sweden is still quite low, although monitoring is currently ongoing. This work describes potential sources for PFASs to enter the drinking water supply in Sweden and compares different occurrences of PFASs in raw and drinking water in the country. Moreover, the monitoring history, the legal situation, and remediation actions taken are presented. Finally, future challenges and the way forward in Sweden are discussed.

Health assessment for Harvey and Knott Drum National Priorities List (NPL) Site, New Castle County, Delaware, Region 3. CERCLIS No. DED980713093. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

The Harvey Knott Drum National Priorities List site, located near Kirkwood in New Castle County, Delaware, is an inactive landfill that had received sanitary, municipal and industrial wastes. Contaminants released from the site include heavy metals and organic compounds and have entered groundwater, soils, sediments, and surface waters. The principal concern is that contaminated groundwater may migrate to off-site domestic, public, and agricultural water supply wells. Also, contaminants in off-site surface water and sediments pose some concern for recreational use and consumption of fish. Off-site contaminated soils near the west property line may be a threat to persons that trespassmore » into that area. The site is of potential health concern because of the risk to human health resulting from possible exposure to hazardous substances at concentrations that may result in adverse health effects.« less

Low temperature MS2 (ATCC15597-B1) virus inactivation using a hot bubble column evaporator (HBCE).

PubMed

Garrido, A; Pashley, R M; Ninham, B W

2017-03-01

In the treatment of household wastewater viruses are hard to eliminate. A new technique is described which tackles this major problem. The MS2 (ATCC15597-B1) virus was used as a surrogate to estimate the inactivation rates for enteric viruses by a hot (150°C) air bubble column evaporator (HBCE) system Its surface charging properties obtained by dynamic light scattering, have been studied in a range of aqueous salt solutions and secondary treated synthetic sewage water. A combination of MS2 virus surface charge properties with thermal inactivation rates, and an improved double layer plaque assay technique, allows an assessment of the efficiency of the HBCE process for virus removal in water. The system is a new energy efficient treatment for water reuse applications. Copyright © 2016 Elsevier B.V. All rights reserved.

Simulation of annual biogeochemical cycles of nutrient balance, phytoplankton bloom(s), and DO in Puget Sound using an unstructured grid model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Khangaonkar, Tarang; Sackmann, Brandon; Long, Wen

2012-08-14

Nutrient pollution from rivers, nonpoint source runoff, and nearly 100 wastewater discharges is a potential threat to the ecological health of Puget Sound with evidence of hypoxia in some basins. However, the relative contributions of loads entering Puget Sound from natural and anthropogenic sources, and the effects of exchange flow from the Pacific Ocean are not well understood. Development of a quantitative model of Puget Sound is thus presented to help improve our understanding of the annual biogeochemical cycles in this system using the unstructured grid Finite-Volume Coastal Ocean Model framework and the Integrated Compartment Model (CE-QUAL-ICM) water quality kinetics.more » Results based on 2006 data show that phytoplankton growth and die-off, succession between two species of algae, nutrient dynamics, and dissolved oxygen in Puget Sound are strongly tied to seasonal variation of temperature, solar radiation, and the annual exchange and flushing induced by upwelled Pacific Ocean waters. Concentrations in the mixed outflow surface layer occupying approximately 5–20 m of the upper water column show strong effects of eutrophication from natural and anthropogenic sources, spring and summer algae blooms, accompanied by depleted nutrients but high dissolved oxygen levels. The bottom layer reflects dissolved oxygen and nutrient concentrations of upwelled Pacific Ocean water modulated by mixing with biologically active surface outflow in the Strait of Juan de Fuca prior to entering Puget Sound over the Admiralty Inlet. The effect of reflux mixing at the Admiralty Inlet sill resulting in lower nutrient and higher dissolved oxygen levels in bottom waters of Puget Sound than the incoming upwelled Pacific Ocean water is reproduced. Finally, by late winter, with the reduction in algal activity, water column constituents of interest, were renewed and the system appeared to reset with cooler temperature, higher nutrient, and higher dissolved oxygen waters from the Pacific Ocean.« less

Assessment of sewer source contamination of drinking water wells using tracers and human enteric viruses

USGS Publications Warehouse

Hunt, R.J.; Borchardt, M. A.; Richards, K.D.; Spencer, S. K.

2010-01-01

This study investigated the source, transport, and occurrence of human enteric viruses in municipal well water, focusing on sanitary sewer sources. A total of 33 wells from 14 communities were sampled once for wastewater tracers and viruses. Wastewater tracers were detected in four of these wells, and five wells were virus- positive by qRT-PCR. These results, along with exclusion of wells with surface water sources, were used to select three wells for additional investigation. Viruses and wastewater tracers were found in the groundwater at all sites. Some wastewater tracers, such as ionic detergents, flame retardants, and cholesterol, were considered unambiguous evidence of wastewater. Sampling at any given time may not show concurrent virus and tracer presence; however, given sufficient sampling over time, a relation between wastewater tracers and virus occurrence was identified. Presence of infectious viruses at the wellhead demonstrates that high-capacity pumping induced sufficiently short travel times for the transport of infectious viruses. Therefore, drinking-water wells are vulnerable to contaminants that travel along fast groundwater flowpaths even if they contribute a small amount of virus-laden water to the well. These results suggest that vulnerability assessments require characterization of "low yield-fast transport" in addition to traditional "high yield-slow transport", pathways. ?? 2010 American Chemical Society.

Final Report: Computer Simulation of Osmosis and Reverse Osmosis in Structured Membranes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sohail Murad

2012-01-03

Molecular simulation methods were developed as part of this project to increase our fundamental understanding of membrane based separation systems. Our simulations clarified for example that steric (size) effects had a significant impact on the desalination membranes. Previously it was thought the separation was entirely driven by coulombic force (attractive/repulsive forces at the membrane surfaces). Steric effects played an important role, because salt ions in brackish water are never present alone, but are strongly hydrated which effectively increases their size, and makes it impossible to enter a membrane, while the smaller water molecules can enter more readily. Membrane surface effectsmore » did play a role in increasing the flux of water, but not in the separation itself. In addition we also developed simulation methods to study ion exchange, gas separations, and pervaporation. The methods developed were used to once again increase our fundamental understanding of these separation processes. For example our studies showed that when the separation factor of gases in membranes can be significantly affected by the presence of another gas, it is generally because the separation mechanism has changed. For example in the case of nitrogen and carbon dioxide, in their pure state the separation factor is determined by diffusion, while in mixtures it is influenced more by adsorption in the membrane (zeolite in our case) Finally we developed a new technique using the NMR chemical shift to determine intermolecular interactions for mixtures. For polar-nonpolar systems such as Xe dissolved in water we were able to significantly improve the accuracy of gas solubilities, which are very sensitive to the cross interaction between water and Xe.« less

Effect of inlet modelling on surface drainage in coupled urban flood simulation

NASA Astrophysics Data System (ADS)

Jang, Jiun-Huei; Chang, Tien-Hao; Chen, Wei-Bo

2018-07-01

For a highly developed urban area with complete drainage systems, flood simulation is necessary for describing the flow dynamics from rainfall, to surface runoff, and to sewer flow. In this study, a coupled flood model based on diffusion wave equations was proposed to simulate one-dimensional sewer flow and two-dimensional overland flow simultaneously. The overland flow model provides details on the rainfall-runoff process to estimate the excess runoff that enters the sewer system through street inlets for sewer flow routing. Three types of inlet modelling are considered in this study, including the manhole-based approach that ignores the street inlets by draining surface water directly into manholes, the inlet-manhole approach that drains surface water into manholes that are each connected to multiple inlets, and the inlet-node approach that drains surface water into sewer nodes that are connected to individual inlets. The simulation results were compared with a high-intensity rainstorm event that occurred in 2015 in Taipei City. In the verification of the maximum flood extent, the two approaches that considered street inlets performed considerably better than that without street inlets. When considering the aforementioned models in terms of temporal flood variation, using manholes as receivers leads to an overall inefficient draining of the surface water either by the manhole-based approach or by the inlet-manhole approach. Using the inlet-node approach is more reasonable than using the inlet-manhole approach because the inlet-node approach greatly reduces the fluctuation of the sewer water level. The inlet-node approach is more efficient in draining surface water by reducing flood volume by 13% compared with the inlet-manhole approach and by 41% compared with the manhole-based approach. The results show that inlet modeling has a strong influence on drainage efficiency in coupled flood simulation.

Ground-water resources of Kansas

USGS Publications Warehouse

Moore, R.C.; Lohman, S.W.; Frye, J.C.; Waite, H.A.; McLaughlin, Thad G.; Latta, Bruce

1940-01-01

Importance of ground-water resources.—The importance of Kansas' ground-water resources may be emphasized from various viewpoints and in different ways. More than three-fourths of the public water supplies of Kansas are obtained from wells. In 1939, only 60 out of 375 municipal water supplies in Kansas, which is 16 percent, utilized surface waters. If the water wells of the cities and those located on all privately owned land in the state were suddenly destroyed, making it necessary to go to streams, springs, lakes (which are almost all artificial), and ponds for water supply domestic, stock, and industrial use, there would be almost incalculable difficulty and expense. If one could not go to springs, or dig new wells, or use any surface water derived from underground flow, much of Kansas would become uninhabitable.  These suggested conditions seem absurd, but they emphasize our dependence on ground-water resources. Fromm a quantitative standpoint, ground-water supplies existent in Kansas far outweigh surface waters that are present in the state at any one time. No exact figures for such comparison can be given, but, taking 384 square miles as the total surface water area of the state and estimating an average water depth of five feet, the computed volume of surface waters is found to be 1/100th of that of the conservatively estimated ground-water storage in Kansas. The latter takes account only of potable fresh water and is based on an assumed mean thickness of ten feet of reservoir having an effective porosity of twenty percent. It is to be remembered, however, that most of the surface water is run-off, which soon leaves the state, stream valleys being replenished from rainfall and flow from ground-water reservoirs. Most of the ground-water supplies, on the other hand, have existed for many years with almost no appreciable movement--in fact, it is reasonably certain that some well water drawn from beneath the surface of Kansas in 1940 represents rainfall in this region at time before the first white man entered Kansas, even before the visit of Coronado in the 16th century. Most ground water is to be regarded as water in storage rather than water in transit.   

Patterns of fish use and piscivore abundance within a reconnected saltmarsh impoundment in the northern Indian River Lagoon, Florida

USGS Publications Warehouse

Stevens, Philip W.; Montague, C.L.; Sulak, K.J.

2006-01-01

Nearly all saltmarshes in east-central, Florida were impounded for mosquito control during the 1960s. The majority of these marshes have since been reconnected to the estuary by culverts, providing an opportunity to effectively measure exchange of aquatic organisms. A multi-gear approach was used monthly to simultaneously estimate fish standing stock (cast net), fish exchange with the estuary (culvert traps), and piscivore abundance (gill nets and bird counts) to document patterns of fish use in a reconnected saltmarsh impoundment. Changes in saltmarsh fish abundance, and exchange of fish with the estuary reflected the seasonal pattern of marsh flooding in the northern Indian River Lagoon system. During a 6-month period of marsh flooding, resident fish had continuous access to the marsh surface. Large piscivorous fish regularly entered the impoundment via creeks and ditches to prey upon small resident fish, and piscivorous birds aggregated following major fish movements to the marsh surface or to deep habitats. As water levels receded in winter, saltmarsh fish concentrated into deep habitats and emigration to the estuary ensued (200% greater biomass left the impoundment than entered). Fish abundance and community structure along the estuary shoreline (although fringed with marsh vegetation) were not analogous to marsh creeks and ditches. Perimeter ditches provided deep-water habitat for large estuarine predators, and shallow creeks served as an alternative habitat for resident fish when the marsh surface was dry. Use of the impoundment as nursery by transients was limited to Mugil cephalus Linnaeus, but large juvenile and adult piscivorous fish used the impoundment for feeding. In conclusion, the saltmarsh impoundment was a feeding site for piscivorous fish and birds, and functioned as a net exporter of forage fish to adjacent estuarine waters. ?? Springer 2006.

Hydrogeology and simulation of ground-water flow and land-surface subsidence in the Chicot and Evangeline aquifers, Houston area, Texas

USGS Publications Warehouse

Kasmarek, Mark C.; Strom, Eric W.

2002-01-01

In November 1997, the U.S. Geological Survey, in cooperation with the City of Houston Utilities Planning Section and the City of Houston Department of Public Works & Engineering, began an investigation of the Chicot and Evangeline aquifers in the greater Houston area in Texas to better understand the hydrology, flow, and associated land-surface subsidence. The principal part of the investigation was a numerical finite-difference model (MODFLOW) developed to simulate ground-water flow and land-surface subsidence in an 18,100-square-mile area encompassing greater Houston.The focus of the study was Harris and Galveston Counties, but other counties were included to achieve the appropriate boundary conditions. The model was vertically discretized into three 103-row by 109-column layers resulting in a total of 33,681 grid cells. Layer 1 represents the water table using a specified head, layer 2 represents the Chicot aquifer, and layer 3 represents the Evangeline aquifer.Simulations were made under transient conditions for 31 ground-water-withdrawal (stress) periods spanning 1891–1996. The years 1977 and 1996 were chosen as potentiometric-surface calibration periods for the model. Simulated and measured potentiometric surfaces of the Chicot and Evangeline aquifers for 1977 match closely. Waterlevel measurements indicate that by 1977, large ground-water withdrawals in east-central and southeastern areas of Harris County had caused the potentiometric surfaces to decline as much as 250 feet below sea level in the Chicot aquifer and as much as 350 feet below sea level in the Evangeline aquifer. Simulated and measured potentiometric surfaces of the Chicot and Evangeline aquifers for 1996 also match closely. The large potentiometric-surface decline in 1977 in the southeastern Houston area showed significant recovery by 1996. The 1996 centers of potentiometric-surface decline are located much farther northwest. Potentiometric-surface declines of more than 200 feet below sea level in the Chicot aquifer and more than 350 feet below sea level in the Evangeline aquifer were measured in observation wells and simulated in the flow model.Simulation of land-surface subsidence and water released from storage in the clay layers was accomplished using the Interbed-Storage Package of the MODFLOW model. Land-surface subsidence was calibrated by comparing simulated long-term (1891–1995) and short-term (1978–95) land-surface subsidence with published maps of land-surface subsidence for about the same period until acceptable matches were achieved.Simulated 1996 Chicot aquifer flow rates indicate that a net flow of 562.5 cubic feet per second enters the Chicot aquifer in the outcrop area, and a net flow of 459.5 cubic feet per second passes through the Chicot aquifer into the Evangeline aquifer. The remaining 103.0 cubic feet per second of flow is withdrawn as pumpage, with a shortfall of about 84.9 cubic feet per second supplied to the wells from storage in sands and clays. Water simulated from storage in clays in the Chicot aquifer is about 19 percent of the total water withdrawn from the aquifer.Simulated 1996 Evangeline aquifer flow rates indicate that a net flow of 14.8 cubic feet per second enters the Evangeline aquifer in the outcrop area, and a net flow of 459.5 cubic feet per second passes through the Chicot aquifer into the Evangeline aquifer for a total inflow of 474.3 cubic feet per second. A greater amount, 528.6 cubic feet per second, is withdrawn by wells; the shortfall of about 54.8 cubic feet per second is supplied from storage in sands and clays. Water simulated from storage in clays in the Evangeline aquifer is about 10 percent of the total water withdrawn from the aquifer.

DEVELOPMENT OF HOMOLOGOUS VIRAL INTERNAL CONTROLS FOR USE IN RT-PCR ASSAYS OF WATERBORNE ENTERIC VIRUSES

EPA Science Inventory

Enteric viruses often contaminate water sources causing frequent outbreaks of gastroenteritis. Reverse transcription-polymerase chain reaction (RT-PCR) assays are commonly used for detection of human enteric viruses in environmental and drinking water samples. RT-PCR provides ...

Surface-water quality assessment of the Clover Creek basin, Pierce County, Washington, 1991-1992

USGS Publications Warehouse

McCarthy, K.A.

1996-01-01

Increasing urbanization in the 67-square-mile Clover Creek Basin has generated interest in the effects of land-use changes on local water quality. To investigate these effects, water-quality and streamflow data were collected from 19 surface-water sites in the basin over a 16-month period from January 1991 through April 1992. These data were used to understand the effects of surficial geology, land-use practices, and wastewater disposal practices on surface-water quality within the basin. The basin was divided into four drainage subbasins with dissimilar hydrogeologic, land-use, and water-quality characteristics. In the Upper Clover Creek subbasin, the high permeability of surficial geologic materials promotes infiltration of precipitation to ground water and thus attenuates the response of streams to rainfall. Significant interaction occurs between surface and ground water in this subbasin, and nitrate concentrations and specific conductance values, similar to those found historically in local ground water, indicate that sources such as subsurface waste-disposal systems and fertilizers are affecting surface- water quality in this area. In the Spanaway subbasin, the presence of Spanaway and Tule Lakes affects water quality, primarily because of the reduced velocity and long residence time of water in the lakes. Reduced water velocity and long residence times (1) cause settling of suspended materials, thereby reducing concentrations of suspended sediment and constituents that are bound to the sediment; (2) promote biological activity, which tends to trap nutrients in the lakes; and (3) allow dispersion to attenuate peaks in discharge and water-quality constituent concentrations. In the North Fork subbasin, the low permeability of surficial geologic materials and areas of intensive land development inhibit infiltration of precipitation and thus promote surface runoff to streams. Surface pathways provide little attenuation of storm runoff and result in rapid increases in stream discharge in response to rainfall. Substantial increases in concentrations of constituents associated with surface wash off, for example, suspended sediment, ammonia, phosphorus, and fecal coliform, also were observed in this subbasin during rainfall. In the Lower Clover Creek subbasin, which is the most downstream subbasin, stream-discharge and water-quality characteristics show the integrated effects of the entire basin. The data show that further characterization of local ground water and discharge from stormwater outfalls entering Clover Creek and its tributaries would be necessary to successfully apply a numerical water-quality model to the basin.

Flow and storage in groundwater systems.

PubMed

Alley, William M; Healy, Richard W; LaBaugh, James W; Reilly, Thomas E

2002-06-14

The dynamic nature of groundwater is not readily apparent, except where discharge is focused at springs or where recharge enters sinkholes. Yet groundwater flow and storage are continually changing in response to human and climatic stresses. Wise development of groundwater resources requires a more complete understanding of these changes in flow and storage and of their effects on the terrestrial environment and on numerous surface-water features and their biota.

Ground-water levels in Huron County, Michigan, January 1995 through December 1995

USGS Publications Warehouse

Sweat, M.J.

1996-01-01

In 1990, the U.S. Geological Survey (USGS) completed a study of the hydrogeology of Huron County, Michigan (Sweat, 1991). In 1993, Huron County and the USGS entered into an agreement to continue collecting water levels at selected wells throughout Huron County. As part of the agreement, the USGS has provided training and instrumentation for County personnel to measure, on a quarterly basis, the depth to water below the land surface in selected wells. The agreement includes the operation of continuous water-level recorders installed on four wells in Bingham, Fairhaven, Grant and Lake Townships (fig. 1). County personnel make quarterly water-level measurements of 22 other wells. Once each year, County personnel are accompanied by USGS personnel who provide a quality assurance/quality control check of all measurements being made.

Vulnerability of drinking water supplies to engineered nanoparticles.

PubMed

Troester, Martin; Brauch, Heinz-Juergen; Hofmann, Thilo

2016-06-01

The production and use of engineered nanoparticles (ENPs) inevitably leads to their release into aquatic environments, with the quantities involved expected to increase significantly in the future. Concerns therefore arise over the possibility that ENPs might pose a threat to drinking water supplies. Investigations into the vulnerability of drinking water supplies to ENPs are hampered by the absence of suitable analytical methods that are capable of detecting and quantifiying ENPs in complex aqueous matrices. Analytical data concerning the presence of ENPs in drinking water supplies is therefore scarce. The eventual fate of ENPs in the natural environment and in processes that are important for drinking water production are currently being investigated through laboratory based-experiments and modelling. Although the information obtained from these studies may not, as yet, be sufficient to allow comprehensive assessment of the complete life-cycle of ENPs, it does provide a valuable starting point for predicting the significance of ENPs to drinking water supplies. This review therefore addresses the vulnerability of drinking water supplies to ENPs. The risk of ENPs entering drinking water is discussed and predicted for drinking water produced from groundwater and from surface water. Our evaluation is based on reviewing published data concerning ENP production amounts and release patterns, the occurrence and behavior of ENPs in aquatic systems relevant for drinking water supply and ENP removability in drinking water purification processes. Quantitative predictions are made based on realistic high-input case scenarios. The results of our synthesis of current knowledge suggest that the risk probability of ENPs being present in surface water resources is generally limited, but that particular local conditions may increase the probability of raw water contamination by ENPs. Drinking water extracted from porous media aquifers are not generally considered to be prone to ENP contamination. In karstic aquifers, however, there is an increased probability that if any ENPs enter the groundwater system they will reach the extraction point of a drinking water treatment plant (DWTP). The ability to remove ENPs during water treatment depends on the specific design of the treatment process. In conventional DWTPs with no flocculation step a proportion of ENPs, if present in the raw water, may reach the final drinking water. The use of ultrafiltration techniques improves drinking water safety with respect to ENP contamination. Copyright © 2016 Elsevier Ltd. All rights reserved.

Habitable planets around white and brown dwarfs: the perils of a cooling primary.

PubMed

Barnes, Rory; Heller, René

2013-03-01

White and brown dwarfs are astrophysical objects that are bright enough to support an insolation habitable zone (IHZ). Unlike hydrogen-burning stars, they cool and become less luminous with time; hence their IHZ moves in with time. The inner edge of the IHZ is defined as the orbital radius at which a planet may enter a moist or runaway greenhouse, phenomena that can remove a planet's surface water forever. Thus, as the IHZ moves in, planets that enter it may no longer have any water and are still uninhabitable. Additionally, the close proximity of the IHZ to the primary leads to concern that tidal heating may also be strong enough to trigger a runaway greenhouse, even for orbital eccentricities as small as 10(-6). Water loss occurs due to photolyzation by UV photons in the planetary stratosphere, followed by hydrogen escape. Young white dwarfs emit a large amount of these photons, as their surface temperatures are over 10(4) K. The situation is less clear for brown dwarfs, as observational data do not constrain their early activity and UV emission very well. Nonetheless, both types of planets are at risk of never achieving habitable conditions, but planets orbiting white dwarfs may be less likely to sustain life than those orbiting brown dwarfs. We consider the future habitability of the planet candidates KOI 55.01 and 55.02 in these terms and find they are unlikely to become habitable.

Occurrence and fate of the angiotensin II receptor antagonist transformation product valsartan acid in the water cycle--a comparative study with selected β-blockers and the persistent anthropogenic wastewater indicators carbamazepine and acesulfame.

PubMed

Nödler, Karsten; Hillebrand, Olav; Idzik, Krzysztof; Strathmann, Martin; Schiperski, Ferry; Zirlewagen, Johannes; Licha, Tobias

2013-11-01

The substantial transformation of the angiotensin II receptor antagonist valsartan to the transformation product 2'-(2H-tetrazol-5-yl)-[1,1'-biphenyl]-4-carboxylic acid (referred to as valsartan acid) during the activated sludge process was demonstrated in the literature and confirmed in the here presented study. However, there was a severe lack of knowledge regarding the occurrence and fate of this compound in surface water and its behavior during drinking water treatment. In this work a comparative study on the occurrence and persistency of valsartan acid, three frequently used β-blockers (metoprolol, atenolol, and sotalol), atenolol acid (one significant transformation product of atenolol and metoprolol), and the two widely distributed persistent anthropogenic wastewater indicators carbamazepine and acesulfame in raw sewage, treated wastewater, surface water, groundwater, and tap water is presented. Median concentrations of valsartan acid in the analyzed matrices were 101, 1,310, 69, <1.0, and 65 ng L(-1), respectively. Treated effluents from wastewater treatment plants were confirmed as significant source. Regarding concentration levels of pharmaceutical residues in surface waters valsartan acid was found just as relevant as the analyzed β-blockers and the anticonvulsant carbamazepine. Regarding its persistency in surface waters it was comparable to carbamazepine and acesulfame. Furthermore, removal of valsartan acid during bank filtration was poor, which demonstrated the relevance of this compound for drinking water suppliers. Regarding drinking water treatment (Muelheim Process) the compound was resistant to ozonation but effectively eliminated (≥90%) by subsequent activated carbon filtration. However, without applying activated carbon filtration the compound may enter the drinking water distribution system as it was demonstrated for Berlin tap water. Copyright © 2013 Elsevier Ltd. All rights reserved.

Modeling disinfection of plastic poultry transport cages inoculated with Salmonella enteritids by slightly acidic electrolyzed water using response surface methodology.

PubMed

Zang, Y T; Li, B M; Bing, Sh; Cao, W

2015-09-01

In order to reduce the risk of enteric pathogens transmission in animal farms, the disinfection effectiveness of slightly acidic electrolyzed water (SAEW, pH 5.85 to 6.53) for inactivating Salmonella Enteritidis on the surface of plastic poultry transport cages was evaluated. The coupled effects of the tap water cleaning time (5 to 15 s), SAEW treatment time (20 to 40 s), and available chlorine concentrations (ACCs) of 30 to 70 mg/l on the reductions of S. Enteritidis on chick cages were investigated using a central composite design of the response surface methodology (RSM). The established RS model had a goodness of fit quantified by the parameter R2 (0.971), as well as a lack of fit test (P>0.05). The maximum reduction of 3.12 log10 CFU/cm2 for S. Enteritidis was obtained for the cage treated with tap water cleaning for 15 s followed by SAEW treatment for 40 s at an ACC of 50 mg/l. Results indicate that the established RS model has shown the potential of SAEW in disinfection of bacteria on cages. © 2015 Poultry Science Association Inc.

Public health significance of zoonotic Cryptosporidium species in wildlife: Critical insights into better drinking water management.

PubMed

Zahedi, Alireza; Paparini, Andrea; Jian, Fuchun; Robertson, Ian; Ryan, Una

2016-04-01

Cryptosporidium is an enteric parasite that is transmitted via the faecal-oral route, water and food. Humans, wildlife and domestic livestock all potentially contribute Cryptosporidium to surface waters. Human encroachment into natural ecosystems has led to an increase in interactions between humans, domestic animals and wildlife populations. Increasing numbers of zoonotic diseases and spill over/back of zoonotic pathogens is a consequence of this anthropogenic disturbance. Drinking water catchments and water reservoir areas have been at the front line of this conflict as they can be easily contaminated by zoonotic waterborne pathogens. Therefore, the epidemiology of zoonotic species of Cryptosporidium in free-ranging and captive wildlife is of increasing importance. This review focuses on zoonotic Cryptosporidium species reported in global wildlife populations to date, and highlights their significance for public health and the water industry.

Pathways of upwelling deep waters to the surface of the Southern Ocean

NASA Astrophysics Data System (ADS)

Tamsitt, Veronica; Drake, Henri; Morrison, Adele; Talley, Lynne; Dufour, Carolina; Gray, Alison; Griffies, Stephen; Mazloff, Matthew; Sarmiento, Jorge; Wang, Jinbo; Weijer, Wilbert

2017-04-01

Upwelling of Atlantic, Indian and Pacific deep waters to the sea surface in the Southern Ocean closes the global overturning circulation and is fundamentally important for oceanic uptake of anthropogenic carbon and heat, nutrient resupply for sustaining oceanic biological production, and the melt rate of ice shelves. Here we go beyond the two-dimensional view of Southern Ocean upwelling, to show detailed Southern Ocean upwelling pathways in three dimensions, using hydrographic observations and particle tracking in high-resolution ocean and climate models. The northern deep waters enter the Antarctic Circumpolar Current (ACC) via narrow southward currents along the boundaries of the three ocean basins, before spiraling southeastward and upward through the ACC. Upwelling is greatly enhanced at five major topographic features, associated with vigorous mesoscale eddy activity. Deep water reaches the upper ocean predominantly south of the southern ACC boundary, with a spatially nonuniform distribution, regionalizing warm water supply to Antarctic ice shelves and the delivery of nutrient and carbon-rich water to the sea surface. The timescale for half of the deep water to upwell from 30°S to the mixed layer is on the order of 60-90 years, which has important implications for the timescale for signals to propagate through the deep ocean. In addition, we quantify the diabatic transformation along particle trajectories, to identify where diabatic processes are important along the upwelling pathways.

APEX (Aqueous Photochemistry of Environmentally occurring Xenobiotics): a free software tool to predict the kinetics of photochemical processes in surface waters.

PubMed

Bodrato, Marco; Vione, Davide

2014-04-01

The APEX software predicts the photochemical transformation kinetics of xenobiotics in surface waters as a function of: photoreactivity parameters (direct photolysis quantum yield and second-order reaction rate constants with transient species, namely ˙OH, CO₃(-)˙, (1)O₂ and the triplet states of chromophoric dissolved organic matter, (3)CDOM*), water chemistry (nitrate, nitrite, bicarbonate, carbonate, bromide and dissolved organic carbon, DOC), and water depth (more specifically, the optical path length of sunlight in water). It applies to well-mixed surface water layers, including the epilimnion of stratified lakes, and the output data are average values over the considered water column. Based on intermediate formation yields from the parent compound via the different photochemical pathways, the software can also predict intermediate formation kinetics and overall yield. APEX is based on a photochemical model that has been validated against available field data of pollutant phototransformation, with good agreement between model predictions and field results. The APEX software makes allowance for different levels of knowledge of a photochemical system. For instance, the absorption spectrum of surface water can be used if known, or otherwise it can be modelled from the values of DOC. Also the direct photolysis quantum yield can be entered as a detailed wavelength trend, as a single value (constant or average), or it can be defined as a variable if unknown. APEX is based on the free software Octave. Additional applications are provided within APEX to assess the σ-level uncertainty of the results and the seasonal trend of photochemical processes.

Surface enhanced Raman scattering on Tardigrada--towards monitoring and imaging molecular structures in live cryptobiotic organisms.

PubMed

Kneipp, Harald; Møbjerg, Nadja; Jørgensen, Aslak; Bohr, Henrik G; Hélix-Nielsen, Claus; Kneipp, Janina; Kneipp, Katrin

2013-10-01

Tardigrades are microscopic metazoans which are able to survive extreme physical and chemical conditions by entering a stress tolerant state called cryptobiosis. At present, the molecular mechanisms behind cryptobiosis are still poorly understood. We show that surface enhanced Raman scattering supported by plasmonic gold nanoparticles can measure molecular constituents and their local distribution in live tardigrades. Surface enhanced Raman signatures allow to differentiate between two species and indicate molecular structural differences between tardigrades in water and in a dry state. This opens new avenues for exploring cryptobiosis by studying molecular changes in live cryptobiotic organisms. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Presence of Legionella in London's water supplies.

PubMed

Colbourne, J S; Trew, R M

1986-09-01

Legionella occurs frequently (52 to 54%) in domestic water and cooling water inside commercial, industrial and health care buildings, and these types of water systems are now regarded as a normal habitat for Legionella. The factors that predispose a particular water system to colonization by these organisms are ill-defined, although it is fairly certain that biological and physicochemical environmental factors play an important role in allowing Legionella to multiply in the circulating water. It has been postulated that the organism may gain access to water systems inside buildings by one of three routes: contact with air through open points such as uncovered storage tanks or vents, ingress of soil or surface water during construction or repair, or intermittent seeding with organisms present in low numbers in the public water supply. Three studies in the USA have found Legionella in 0.4 to 8.8% of drinking-water samples, but these were not representative of the public supply network as a whole. The aim of this study was to determine, over a period of 1 year, the frequency of Legionella in London's drinking water--from the treatment plant through to the consumer's tap. To date, Legionella has not been isolated from raw river water entering London's treatment works or from treated water entering the distribution network. Sixty-two monitoring taps in buildings located in 21 supply areas have been sampled twice for Legionella; only 2 (2.4%) have proved positive during the autumn and winter of 1985/86. The strain found was L. pneumophila serotype 1, subgroup Olda, and the numbers ranged from 10(2) to 10(4)/l. Although the survey is incomplete, it is already clear that the public water supplies in London are not a source of strains of Legionella associated with disease.

The use and re-use of unsustainable groundwater for irrigation: A global budget

DOE Office of Scientific and Technical Information (OSTI.GOV)

Grogan, Danielle S.; Wisser, Dominik; Prusevich, Alex

Depletion of groundwater aquifers across the globe has become a significant concern, as groundwater is an important and often unsustainable source of irrigation water. Simultaneously, the field of water resource management has seen a lively debate over the concepts and metrics used to assess the downstream re-use of agricultural runoff, with most studies focusing on surface water balances. Here, we bring these two lines of research together, recognizing that depletion of aquifers leads to large amounts of groundwater entering surface water storages and flows by way of agricultural runoff. While it is clear that groundwater users will be impacted bymore » reductions in groundwater availability, there is a major gap in our understanding of potential impacts downstream of groundwater pumping locations. We find that the volume of unsustainable groundwater that is re-used for irrigation following runoff from agricultural systems is nearly as large as the volume initially extracted from reservoirs for irrigation. Basins in which the volume of irrigation water re-used is equal to or greater than the volume of water initially used (which is possible due to multiple re-use of the same water) contain 33 million hectares of irrigated land and are home to 1.3 billion people. Some studies have called for increasing irrigation efficiency as a solution to water shortages. We find that with 100% irrigation efficiency, global demand for unsustainable groundwater is reduced by 52%, but not eliminated. In many basins, increased irrigation efficiency leads to significantly decreased river low flows; increasing irrigation efficiency to 70% globally decreases total surface water supplies by ~600 km 3 yr –1. Lastly, these findings illustrate that estimates of aquifer depletion alone underestimate the importance of unsustainable groundwater to sustaining surface water systems and irrigated agriculture.« less

The use and re-use of unsustainable groundwater for irrigation: A global budget

DOE PAGES

Grogan, Danielle S.; Wisser, Dominik; Prusevich, Alex; ...

2017-03-08

Depletion of groundwater aquifers across the globe has become a significant concern, as groundwater is an important and often unsustainable source of irrigation water. Simultaneously, the field of water resource management has seen a lively debate over the concepts and metrics used to assess the downstream re-use of agricultural runoff, with most studies focusing on surface water balances. Here, we bring these two lines of research together, recognizing that depletion of aquifers leads to large amounts of groundwater entering surface water storages and flows by way of agricultural runoff. While it is clear that groundwater users will be impacted bymore » reductions in groundwater availability, there is a major gap in our understanding of potential impacts downstream of groundwater pumping locations. We find that the volume of unsustainable groundwater that is re-used for irrigation following runoff from agricultural systems is nearly as large as the volume initially extracted from reservoirs for irrigation. Basins in which the volume of irrigation water re-used is equal to or greater than the volume of water initially used (which is possible due to multiple re-use of the same water) contain 33 million hectares of irrigated land and are home to 1.3 billion people. Some studies have called for increasing irrigation efficiency as a solution to water shortages. We find that with 100% irrigation efficiency, global demand for unsustainable groundwater is reduced by 52%, but not eliminated. In many basins, increased irrigation efficiency leads to significantly decreased river low flows; increasing irrigation efficiency to 70% globally decreases total surface water supplies by ~600 km 3 yr –1. Lastly, these findings illustrate that estimates of aquifer depletion alone underestimate the importance of unsustainable groundwater to sustaining surface water systems and irrigated agriculture.« less

The use and re-use of unsustainable groundwater for irrigation: a global budget

NASA Astrophysics Data System (ADS)

Grogan, Danielle S.; Wisser, Dominik; Prusevich, Alex; Lammers, Richard B.; Frolking, Steve

2017-03-01

Depletion of groundwater aquifers across the globe has become a significant concern, as groundwater is an important and often unsustainable source of irrigation water. Simultaneously, the field of water resource management has seen a lively debate over the concepts and metrics used to assess the downstream re-use of agricultural runoff, with most studies focusing on surface water balances. Here, we bring these two lines of research together, recognizing that depletion of aquifers leads to large amounts of groundwater entering surface water storages and flows by way of agricultural runoff. While it is clear that groundwater users will be impacted by reductions in groundwater availability, there is a major gap in our understanding of potential impacts downstream of groundwater pumping locations. We find that the volume of unsustainable groundwater that is re-used for irrigation following runoff from agricultural systems is nearly as large as the volume initially extracted from reservoirs for irrigation. Basins in which the volume of irrigation water re-used is equal to or greater than the volume of water initially used (which is possible due to multiple re-use of the same water) contain 33 million hectares of irrigated land and are home to 1.3 billion people. Some studies have called for increasing irrigation efficiency as a solution to water shortages. We find that with 100% irrigation efficiency, global demand for unsustainable groundwater is reduced by 52%, but not eliminated. In many basins, increased irrigation efficiency leads to significantly decreased river low flows; increasing irrigation efficiency to 70% globally decreases total surface water supplies by ∽600 km3 yr-1. These findings illustrate that estimates of aquifer depletion alone underestimate the importance of unsustainable groundwater to sustaining surface water systems and irrigated agriculture.

Bisphenol-A sensors on polyimide fabricated by laser direct writing for on-site river water monitoring at attomolar concentration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Cheng; Wang, Shutong; Wu, Jayne

This work presents an aptamer-based, highly sensitive and specific sensor for atto- to femtomolar level detection of bisphenol A (BPA). Because of its widespread use in numerous products, BPA enters surface water from effluent discharges during its manufacture, use, and from waste landfill sites throughout the world. On-site measurement of BPA concentrations in water is important for evaluating compliance with water quality standards or environmental risk levels of the harmful compound in the environment. The sensor in this work is porous, conducting, interdigitated electrodes that are formed by laser-induced carbonization of flexible polyimide sheets. BPA-specific aptamer is immobilized on themore » electrodes as the probe, and its binding with BPA at the electrode surface is detected by capacitive sensing. The binding process is aided by ac electroosmotic effect that accelerates the transport of BPA molecules to the nanoporous graphene-like structured electrodes. The sensor achieved a limit of detection of 58.28 aM with a response time of 20 s. The sensor is further applied for recovery analysis of BPA spiked in surface water. In conclusion, this work provides an affordable platform for highly sensitive, real time, and field-deployable BPA surveillance critical to the evaluation of the ecological impact of BPA exposure.« less

Bisphenol-A sensors on polyimide fabricated by laser direct writing for on-site river water monitoring at attomolar concentration

DOE PAGES

Cheng, Cheng; Wang, Shutong; Wu, Jayne; ...

2016-06-28

This work presents an aptamer-based, highly sensitive and specific sensor for atto- to femtomolar level detection of bisphenol A (BPA). Because of its widespread use in numerous products, BPA enters surface water from effluent discharges during its manufacture, use, and from waste landfill sites throughout the world. On-site measurement of BPA concentrations in water is important for evaluating compliance with water quality standards or environmental risk levels of the harmful compound in the environment. The sensor in this work is porous, conducting, interdigitated electrodes that are formed by laser-induced carbonization of flexible polyimide sheets. BPA-specific aptamer is immobilized on themore » electrodes as the probe, and its binding with BPA at the electrode surface is detected by capacitive sensing. The binding process is aided by ac electroosmotic effect that accelerates the transport of BPA molecules to the nanoporous graphene-like structured electrodes. The sensor achieved a limit of detection of 58.28 aM with a response time of 20 s. The sensor is further applied for recovery analysis of BPA spiked in surface water. In conclusion, this work provides an affordable platform for highly sensitive, real time, and field-deployable BPA surveillance critical to the evaluation of the ecological impact of BPA exposure.« less

Bisphenol A Sensors on Polyimide Fabricated by Laser Direct Writing for Onsite River Water Monitoring at Attomolar Concentration.

PubMed

Cheng, Cheng; Wang, Shutong; Wu, Jayne; Yu, Yongchao; Li, Ruozhou; Eda, Shigetoshi; Chen, Jiangang; Feng, Guoying; Lawrie, Benjamin; Hu, Anming

2016-07-20

This work presents an aptamer-based, highly sensitive and specific sensor for atto- to femtomolar level detection of bisphenol A (BPA). Because of its widespread use in numerous products, BPA enters surface water from effluent discharges during its manufacture, use, and from waste landfill sites throughout the world. On-site measurement of BPA concentrations in water is important for evaluating compliance with water quality standards or environmental risk levels of the harmful compound in the environment. The sensor in this work is porous, conducting, interdigitated electrodes that are formed by laser-induced carbonization of flexible polyimide sheets. BPA-specific aptamer is immobilized on the electrodes as the probe, and its binding with BPA at the electrode surface is detected by capacitive sensing. The binding process is aided by ac electroosmotic effect that accelerates the transport of BPA molecules to the nanoporous graphene-like structured electrodes. The sensor achieved a limit of detection of 58.28 aM with a response time of 20 s. The sensor is further applied for recovery analysis of BPA spiked in surface water. This work provides an affordable platform for highly sensitive, real time, and field-deployable BPA surveillance critical to the evaluation of the ecological impact of BPA exposure.

Microplastics in Arctic polar waters: the first reported values of particles in surface and sub-surface samples

PubMed Central

Lusher, Amy L.; Tirelli, Valentina; O’Connor, Ian; Officer, Rick

2015-01-01

Plastic, as a form of marine litter, is found in varying quantities and sizes around the globe from surface waters to deep-sea sediments. Identifying patterns of microplastic distribution will benefit an understanding of the scale of their potential effect on the environment and organisms. As sea ice extent is reducing in the Arctic, heightened shipping and fishing activity may increase marine pollution in the area. Microplastics may enter the region following ocean transport and local input, although baseline contamination measurements are still required. Here we present the first study of microplastics in Arctic waters, south and southwest of Svalbard, Norway. Microplastics were found in surface (top 16 cm) and sub-surface (6 m depth) samples using two independent techniques. Origins and pathways bringing microplastic to the Arctic remain unclear. Particle composition (95% fibres) suggests they may either result from the breakdown of larger items (transported over large distances by prevailing currents, or derived from local vessel activity), or input in sewage and wastewater from coastal areas. Concurrent observations of high zooplankton abundance suggest a high probability for marine biota to encounter microplastics and a potential for trophic interactions. Further research is required to understand the effects of microplastic-biota interaction within this productive environment. PMID:26446348

Microplastics in Arctic polar waters: the first reported values of particles in surface and sub-surface samples

NASA Astrophysics Data System (ADS)

Lusher, Amy L.; Tirelli, Valentina; O'Connor, Ian; Officer, Rick

2015-10-01

Plastic, as a form of marine litter, is found in varying quantities and sizes around the globe from surface waters to deep-sea sediments. Identifying patterns of microplastic distribution will benefit an understanding of the scale of their potential effect on the environment and organisms. As sea ice extent is reducing in the Arctic, heightened shipping and fishing activity may increase marine pollution in the area. Microplastics may enter the region following ocean transport and local input, although baseline contamination measurements are still required. Here we present the first study of microplastics in Arctic waters, south and southwest of Svalbard, Norway. Microplastics were found in surface (top 16 cm) and sub-surface (6 m depth) samples using two independent techniques. Origins and pathways bringing microplastic to the Arctic remain unclear. Particle composition (95% fibres) suggests they may either result from the breakdown of larger items (transported over large distances by prevailing currents, or derived from local vessel activity), or input in sewage and wastewater from coastal areas. Concurrent observations of high zooplankton abundance suggest a high probability for marine biota to encounter microplastics and a potential for trophic interactions. Further research is required to understand the effects of microplastic-biota interaction within this productive environment.

Microplastics in Arctic polar waters: the first reported values of particles in surface and sub-surface samples.

PubMed

Lusher, Amy L; Tirelli, Valentina; O'Connor, Ian; Officer, Rick

2015-10-08

Plastic, as a form of marine litter, is found in varying quantities and sizes around the globe from surface waters to deep-sea sediments. Identifying patterns of microplastic distribution will benefit an understanding of the scale of their potential effect on the environment and organisms. As sea ice extent is reducing in the Arctic, heightened shipping and fishing activity may increase marine pollution in the area. Microplastics may enter the region following ocean transport and local input, although baseline contamination measurements are still required. Here we present the first study of microplastics in Arctic waters, south and southwest of Svalbard, Norway. Microplastics were found in surface (top 16 cm) and sub-surface (6 m depth) samples using two independent techniques. Origins and pathways bringing microplastic to the Arctic remain unclear. Particle composition (95% fibres) suggests they may either result from the breakdown of larger items (transported over large distances by prevailing currents, or derived from local vessel activity), or input in sewage and wastewater from coastal areas. Concurrent observations of high zooplankton abundance suggest a high probability for marine biota to encounter microplastics and a potential for trophic interactions. Further research is required to understand the effects of microplastic-biota interaction within this productive environment.

Geohydrologic, geochemical, and geologic controls on the occurrence of radon in ground water near Conifer, Colorado, USA

USGS Publications Warehouse

Lawrence, E.; Poeter, E.; Wanty, R.

1991-01-01

Integrated studies of geohydrology, geochemistry, and geology of crystalline rocks in the vicinity of Conifer, Colorado, reveal that radon concentrations do not correlate with variations in concentrations of other dissolved species. Concentrations of major ions show systematic variations along selected groundwater flowpaths, whereas radon concentrations are dependent on local geochemical and geologic phenomena (such as localized uranium concentration in the rock or the presence of faults or folds). When radon enters the flow system, concentrations do not increase along flowpaths because its decay rate is fast relative to groundwater flow rates. Radon-222 is not in secular equilibrium with 238U and 226Ra in the water. Therefore, most of the 238U and 226Ra necessary to support the waterborne 222Rn must be present locally in the rock. High concentrations of dissolved radon are not found in zones of high transmissivity, and transmissivity is not correlated with rock type in the study area. A higher transmissivity can be indicative of higher water-volume to rock-surface-area ratios, which could effectively dilute 222Rn entering the water and/or may indicate that emanated radon is carried away more rapidly. Water samples collected from individual wells over periods of several months showed significant fluctuations in the dissolved 222Rn content. This fluctuation may be controlled by changes in the contributions of water-producing zones within the well resulting from seasonal fluctuations of the water table and/or pumping stresses. ?? 1991.

Groundwater Discharges to Rivers in the Western Canadian Oil Sands Region

NASA Astrophysics Data System (ADS)

Ellis, J.; Jasechko, S.

2016-12-01

Groundwater discharges into rivers impacts the movement and fate of nutrients and contaminants in the environment. Understanding groundwater-surface water interactions is especially important in the western Canadian oil sands, where groundwater contamination risks are elevated and baseline water chemistry data is lacking, leading to substantial uncertainties about anthropogenic influences on local river quality. High salinity groundwater springs sourced from deep aquifers, comprised of Pleistocene-aged glacial meltwater, are known to discharge into many rivers in the oil sands. Understanding connections between deep aquifers and surficial waterways is important in order to determine natural inputs into these rivers and to assess the potential for injected wastewater or oil extraction fluids to enter surface waters. While these springs have been identified, their spatial distribution along rivers has not been fully characterized. Here we present river chemistry data collected along a number of major river corridors in the Canadian oil sands region. We show that saline groundwater springs vary spatially along the course of these rivers and tend to be concentrated where the rivers incise Devonian- or Cretaceous-aged aquifers along an evaporite dissolution front. Our results suggest that water sourced from Devonian aquifers may travel through bitumen-bearing Cretaceous units and discharge into local rivers, implying a strong groundwater-surface water connection in specialized locations. These findings indicate that oil sands process-affected waters that are injected at depth have the potential to move through these aquifers and reach the rivers at the surface at some time in the future. Groundwater-surface water interactions remain key to understanding the risks oil sands activities pose to aquatic ecosystems and downstream communities.

A New Electropositive Filter for Concentrating Enterovirus and Norovirus from Large Volumes of Water - MCEARD

EPA Science Inventory

The detection of enteric viruses in environmental water usually requires the concentration of viruses from large volumes of water. The 1MDS electropositive filter is commonly used for concentrating enteric viruses from water but unfortunately these filters are not cost-effective...

Chemical and bacteriological quality of water at selected sites in the San Antonio area, Texas, August 1968-January 1975

USGS Publications Warehouse

Reeves, R.D.; Blakey, J.F.

1976-01-01

Urban development on or adjacent to the recharge zone of the Edwards aquifer is causing concern about the possible pollution of ground water in the aquifer, which is the principal source of water supply for the San Antonio area. Water-quality data for many wells and springs and for selected sites on streams that cross the recharge zone of the aquifer are being collected to provide background information and to detect any current pollution of ground water in the area. Water from the Edwards aquifer is very hard and of the calcium bicarbonate type. The concentrations of dissolved solids in samples from wells and springs ranged from about 200 to 470 mg/1 (milligrams per liter); the chloride and sulfate concentrations ranged from 6.5 to 62 mg/1 and from 0.0 to 65 mg/1, respectively. The nitrate and phosphate contents of the ground water ranged from 0.0 to 15 mg/1 and from 0.00 to 0. 37 mg/1. The concentrations of these and other constituents show that the chemical quality of water in the Edwards aquifer has not been degraded significantly by domestic, industrial, or agricultural effluents. However, variations in the number of coliforms, the concentrations of nitrate and phosphate, and the presence of fecal coliforms and fecal streptococci in samples from some wells show that fecal pollution is reaching the aquifer. Most of these wells, which are located in or just downdip from the recharge zone, are poorly sealed or inadequately cased. The areal variation in the locations of these wells indicates that pollution of ground water in the aquifer is very localized. Prllution results principally from runoff from the land surface and from effluent from septic tanks which enters the aquifer through fractures in the recharge zone or which infiltrates through the thin soil into poorly sealed or inadequately cased wells in or adjacent to the recharge zone. Trace amounts of several pesticides have been detected in samples from two wells in the San Antonio area. Field investigations showed the source of pesticides in these wells to be. surface drainage that entered the wellbores. Water-quality data collected at sites on streams that cross the recharge zone of the Edwards aquifer show the chemical composition of surface water to be very similar to that of ground water in the area. Water in most streams is very hard and of the calcium bicarbonate type. Limited data on the bacteriological quality show that coliforms were present at each of the site sampled and that fecal coliforms and fecal streptococci were present at most sites. Although the number of these bacteria varied greatly in both time and place, their density in samples from most sites were low for untreated surface water.

Iron oxidation kinetics and phosphorus immobilization at the groundwater-surface water interface

NASA Astrophysics Data System (ADS)

van der Grift, Bas; Rozemeijer, Joachim; Griffioen, Jasper; van der Velde, Ype

2014-05-01

Eutrophication of freshwater environments following diffuse nutrient loads is a widely recognized water quality problem in catchments. Fluxes of non-point P sources to surface waters originate from surface runoff and flow from soil water and groundwater into surface water. The availability of P in surface waters is controlled strongly by biogeochemical nutrient cycling processes at the soil-water interface. The mechanisms and rates of the iron oxidation process with associated binding of phosphate during exfiltration of anaerobic Fe(II) bearing groundwater are among the key unknowns in P retention processes in surface waters in delta areas where the shallow groundwater is typically pH-neutral to slightly acid, anoxic, iron-rich. We developed an experimental field set-up to study the dynamics in Fe(II) oxidation and mechanisms of P immobilization at the groundwater-surface water interface in an agricultural experimental catchment of a small lowland river. We physically separated tube drain effluent from groundwater discharge before it entered a ditch in an agricultural field. The exfiltrating groundwater was captured in in-stream reservoirs constructed in the ditch. Through continuous discharge measurements and weekly water quality sampling of groundwater, tube drain water, exfiltrated groundwater, and ditch water, we quantified Fe(II) oxidation kinetics and P immobilization processes across the seasons. This study showed that seasonal changes in climatic conditions affect the Fe(II) oxidation process. In winter time the dissolved iron concentrations in the in-stream reservoirs reached the levels of the anaerobic groundwater. In summer time, the dissolved iron concentrations of the water in the reservoirs are low, indicating that dissolved Fe(II) is completely oxidized prior to inflow into the reservoirs. Higher discharges, lower temperatures and lower pH of the exfiltrated groundwater in winter compared to summer shifts the location of the redox transition zone, with Fe(II) oxidation taking place in the soil surrounding the ditch during summer and in the surface water during winter. The dynamics in Fe(II) oxidation did not affect the dissolved P concentrations. The dissolved P concentrations of the in-stream reservoirs water were an order of magnitude lower than observed in the groundwater and have no seasonal trend. Our data showed preferential binding of P during initial stage of the Fe(II) oxidation process, indicating the formation of Fe(III)-phosphate precipitates. The formation of Fe(III)-phosphates at the groundwater-surface water interface is an important geochemical mechanism in the transformation of dissolved phosphate to particulate phosphate and therefore a major control on the P retention in natural waters that drain anaerobic aquifers.

A sample-freezing drive shoe for a wire line piston core sampler

USGS Publications Warehouse

Murphy, F.; Herkelrath, W.N.

1996-01-01

Loss of fluids and samples during retrieval of cores of saturated, noncohesive sediments results in incorrect measures of fluid distributions and an inaccurate measure of the stratigraphic position of the sample. To reduce these errors, we developed a hollow drive shoe that freezes in place the lowest 3 inches (75 mm) of a 1.88-inch-diameter (48 mm), 5-foot-long (1.5 m) sediment sample taken using a commercial wire line piston core sampler. The end of the core is frozen by piping liquid carbon dioxide at ambient temperature through a steel tube from a bottle at the land surface to the drive shoe where it evaporates and expands, cooling the interior surface of the shoe to about -109??F (-78??C). Freezing a core end takes about 10 minutes. The device was used to collect samples for a study of oil-water-air distributions, and for studies of water chemistry and microbial activity in unconsolidated sediments at the site of an oil spill near Bemidji, Minnesota. Before freezing was employed, samples of sandy sediments from near the water table sometimes flowed out of the core barrel as the sampler was withdrawn. Freezing the bottom of the core allowed for the retention of all material that entered the core barrel and lessened the redistribution of fluids within the core. The device is useful in the unsaturated and shallow saturated zones, but does not freeze cores well at depths greater than about 20 feet (6 m) below water, possibly because the feed tube plugs with dry ice with increased exhaust back-pressure, or because sediment enters the annulus between the core barrel and the core barrel liner and blocks the exhaust.

Observations of Surfzone Albedo

NASA Astrophysics Data System (ADS)

Sinnett, G.; Feddersen, F.

2014-12-01

The surfzone environment (where waves break) contains several unique and previously unconsidered processes that affect the heat budget. Entering short-wave radiation is a dominant term in both shelf and surfzone heat budgets. In contrast to the shelf, however, depth limited wave breaking in the surfzone generates spray, whitewater and suspended sediments, elevating the surface albedo (ratio of reflected to incident short-wave radiation). Elevated albedo reduces the level of solar short-wave radiation entering the water, potentially resulting in less heating. Additionally, surfzone water quality is often impacted by fecal bacteria contamination. As bacteria mortality is related to short-wave solar radiation, elevated surfzone albedo could reduce pathogen mortality, impacting human health. Albedo in the open ocean has been frequently studied and parameterizations often consider solar zenith angle, wind speed and ocean chlorophyll concentration, producing albedo values typically near 0.06. However, surfzone albedo observations have been extremely sparse, yet show depth limited wave breaking may increase the albedo by nearly a factor of 10 up to 0.5. Here, we present findings from a field study at the Scripps Institution of Oceanography pier to observe the affect of waves on surfzone albedo. Concurrent measurements were taken with a four-way radiometer (to measure both downwelling and upwelling short-wave and long wave radiation) mounted above the surfzone. A co-located GoPro camera was used to relate visual aspects of the surfzone to measured reflectance, and wave height and period were observed with a bottom mounted pressure sensor in 5 m water depth just outside the surfzone. Wind speed and direction were observed on the pier 10 m above the water surface. Here, we will examine the surfzone albedo dependence on surfzone parameters, such as wave height.

Assessment and impact of microbial fecal pollution and human enteric pathogens in a coastal community.

PubMed

Lipp, E K; Farrah, S A; Rose, J B

2001-04-01

The goals of this study were to assess watersheds impacted by high densities of OSDS (onsite sewage disposal systems) for evidence of fecal contamination and evaluate the occurrence of human pathogens in coastal waters off west Florida. Eleven stations (representing six watersheds) were intensively sampled for microbial indicators of fecal pollution (fecal coliform bacteria, enterococci, Clostridium perfringens and coliphage) and the human enteric pathogens, Cryptosporidium, Giardia, and enteroviruses during the summer rainy season (May-September 1996). Levels of all indicators ranged between < 5 and > 4000 CFU/100 ml. Cryptosporidium and Giardia were detected infrequently (6.8% and 2.3% of samples tested positive, respectively). Conversely, infectious enteroviruses were detected at low levels in 5 of the 6 watersheds sampled. Using cluster analysis, sites were grouped into two categories, high and low risks, based on combined levels of indicators. These results suggest that stations of highest pollution risk were located within areas of high OSDS densities. Furthermore, data indicate a subsurface transport of contaminated water to surface waters. The high prevalence of enteroviruses throughout the study area suggests a chronic pollution problem and potential risk to recreational swimmers in and around Sarasota Bay.

Fault tree analysis of the causes of waterborne outbreaks.

PubMed

Risebro, Helen L; Doria, Miguel F; Andersson, Yvonne; Medema, Gertjan; Osborn, Keith; Schlosser, Olivier; Hunter, Paul R

2007-01-01

Prevention and containment of outbreaks requires examination of the contribution and interrelation of outbreak causative events. An outbreak fault tree was developed and applied to 61 enteric outbreaks related to public drinking water supplies in the EU. A mean of 3.25 causative events per outbreak were identified; each event was assigned a score based on percentage contribution per outbreak. Source and treatment system causative events often occurred concurrently (in 34 outbreaks). Distribution system causative events occurred less frequently (19 outbreaks) but were often solitary events contributing heavily towards the outbreak (a mean % score of 87.42). Livestock and rainfall in the catchment with no/inadequate filtration of water sources contributed concurrently to 11 of 31 Cryptosporidium outbreaks. Of the 23 protozoan outbreaks experiencing at least one treatment causative event, 90% of these events were filtration deficiencies; by contrast, for bacterial, viral, gastroenteritis and mixed pathogen outbreaks, 75% of treatment events were disinfection deficiencies. Roughly equal numbers of groundwater and surface water outbreaks experienced at least one treatment causative event (18 and 17 outbreaks, respectively). Retrospective analysis of multiple outbreaks of enteric disease can be used to inform outbreak investigations, facilitate corrective measures, and further develop multi-barrier approaches.

Validation of the REA bioassay to detect estrogenic activity in the water cycle.

PubMed

Nguyen, Mai Thao; van der Oost, Ron; Bovee, Toine F H

2011-12-01

Endocrine disrupting compounds (EDCs) with estrogenic potency contaminate water and might eventually cause adverse effects to the aquatic environment. Many estrogenic compounds are not completely removed by wastewater treatment systems and, together with the run-off from agricultural areas, they enter surface waters. Chemical analytical methods to determine these compounds are usually expensive and laborious. Therefore, screening bioassays which are able to detect compounds based on their effects offer a solution for prior selection of samples that need to be chemically analyzed. In this study, the REA (RIKILT yeast Estrogen bioAssay), which has been developed to detect estrogenic compounds in calf urine and animal feed at RIKILT, is validated at the Water Board Laboratory of Waterproef for water samples. According to EC Decision 2002/657, detection capability CCβ, specificity and stability have to be determined for the internal validation of a qualitative screening test. In addition, surface water and effluent samples were analyzed to further demonstrate the applicability of the validated test procedure. Results demonstrate that the REA assay is reproducible and specific for estrogenic compounds in water and meets the criteria as prescribed in EC Decision 2002/657. The assay was sensitive enough to detect estrogenic activity of pollutants in water with a limit of quantification (LOQ) below 1 ng EEQ/L. This means that samples can be compared with preliminary threshold levels for drinking water and surface waters (7 and 1 ng EEQ/L, respectively). The stability of estrogenic activity in water samples is at least 4 weeks, when stored at 4 °C. Copyright © 2011 Elsevier Ltd. All rights reserved.

Enteric pathogens in stored drinking water and on caregiver's hands in Tanzanian households with and without reported cases of child diarrhea.

PubMed

Mattioli, Mia Catharine; Boehm, Alexandria B; Davis, Jennifer; Harris, Angela R; Mrisho, Mwifadhi; Pickering, Amy J

2014-01-01

Diarrhea is one of the leading causes of mortality in young children. Diarrheal pathogens are transmitted via the fecal-oral route, and for children the majority of this transmission is thought to occur within the home. However, very few studies have documented enteric pathogens within households of low-income countries. The presence of molecular markers for three enteric viruses (enterovirus, adenovirus, and rotavirus), seven Escherichia coli virulence genes (ECVG), and human-specific Bacteroidales was assessed in hand rinses and household stored drinking water in Bagamoyo, Tanzania. Using a matched case-control study design, we examined the relationship between contamination of hands and water with these markers and child diarrhea. We found that the presence of ECVG in household stored water was associated with a significant decrease in the odds of a child within the home having diarrhea (OR = 0.51; 95% confidence interval 0.27-0.93). We also evaluated water management and hygiene behaviors. Recent hand contact with water or food was positively associated with detection of enteric pathogen markers on hands, as was relatively lower volumes of water reportedly used for daily hand washing. Enteropathogen markers in stored drinking water were more likely found among households in which the markers were also detected on hands, as well as in households with unimproved water supply and sanitation infrastructure. The prevalence of enteric pathogen genes and the human-specific Bacteroidales fecal marker in stored water and on hands suggests extensive environmental contamination within homes both with and without reported child diarrhea. Better stored water quality among households with diarrhea indicates caregivers with sick children may be more likely to ensure safe drinking water in the home. Interventions to increase the quantity of water available for hand washing, and to improve food hygiene, may reduce exposure to enteric pathogens in the domestic environment.

Enteric Pathogens in Stored Drinking Water and on Caregiver’s Hands in Tanzanian Households with and without Reported Cases of Child Diarrhea

PubMed Central

Mattioli, Mia Catharine; Boehm, Alexandria B.; Davis, Jennifer; Harris, Angela R.; Mrisho, Mwifadhi; Pickering, Amy J.

2014-01-01

Background Diarrhea is one of the leading causes of mortality in young children. Diarrheal pathogens are transmitted via the fecal-oral route, and for children the majority of this transmission is thought to occur within the home. However, very few studies have documented enteric pathogens within households of low-income countries. Methods and Findings The presence of molecular markers for three enteric viruses (enterovirus, adenovirus, and rotavirus), seven Escherichia coli virulence genes (ECVG), and human-specific Bacteroidales was assessed in hand rinses and household stored drinking water in Bagamoyo, Tanzania. Using a matched case-control study design, we examined the relationship between contamination of hands and water with these markers and child diarrhea. We found that the presence of ECVG in household stored water was associated with a significant decrease in the odds of a child within the home having diarrhea (OR = 0.51; 95% confidence interval 0.27–0.93). We also evaluated water management and hygiene behaviors. Recent hand contact with water or food was positively associated with detection of enteric pathogen markers on hands, as was relatively lower volumes of water reportedly used for daily hand washing. Enteropathogen markers in stored drinking water were more likely found among households in which the markers were also detected on hands, as well as in households with unimproved water supply and sanitation infrastructure. Conclusions The prevalence of enteric pathogen genes and the human-specific Bacteroidales fecal marker in stored water and on hands suggests extensive environmental contamination within homes both with and without reported child diarrhea. Better stored water quality among households with diarrhea indicates caregivers with sick children may be more likely to ensure safe drinking water in the home. Interventions to increase the quantity of water available for hand washing, and to improve food hygiene, may reduce exposure to enteric pathogens in the domestic environment. PMID:24392161

Oil/gas collector/separator for underwater oil leaks

DOEpatents

Henning, Carl D.

1993-01-01

An oil/gas collector/separator for recovery of oil leaking, for example, from an offshore or underwater oil well. The separator is floated over the point of the leak and tethered in place so as to receive oil/gas floating, or forced under pressure, toward the water surface from either a broken or leaking oil well casing, line, or sunken ship. The separator is provided with a downwardly extending skirt to contain the oil/gas which floats or is forced upward into a dome wherein the gas is separated from the oil/water, with the gas being flared (burned) at the top of the dome, and the oil is separated from water and pumped to a point of use. Since the density of oil is less than that of water it can be easily separated from any water entering the dome.

Atrazine degradation in a small stream in Iowa

USGS Publications Warehouse

Kolpin, D.W.; Kalkhoff, S.J.

1993-01-01

A study was conducted during 1990 through an 11.2-km reach of Roberts Creek in northeastern Iowa to determine the fate of atrazine in a surface water environment Water samples were collected at ~1-month intervals from April through November during stable low to medium flow conditions and analyzed for atrazine and two of its initial biotic degradation products, desethylatrazine and deisopropylatrazine. Samples were collected on the basis of a Lagrangian model of streamflow in order to sample the same parcel of water as it moved downstream. Atrazine concentrations substantially decreased (roughly 25-60%) between water entering and exiting the study reach during four of the seven sampling periods. During these same four sampling periods, the concentrations of the two biotic atrazine degradation products were constant or decreasing downstream, suggesting an abiotic degradation process.

Inactivation of a model coliphage virus in water by iodine

NASA Technical Reports Server (NTRS)

Brion, Gail M.; Silverstein, Joann

1992-01-01

Until now, NASA's space water reuse research program has not considered the transport of water-borne infectious enteric viruses; however, viral diseases probably are a signifficant concern in long-duration space missions. To simplify monitoring and prediction of pathogen distribution, model indicator strains historically have been used. In this research, the male specific RNA coliphage MS-2 is used as a model of enteric viruses due to their similar size and biochemical composition. Inactivation of some water-borne enteric viruses by iodine has previously been characterized. In this paper, iodine inactivation of the model coliphage MS-2 in buffered water is compared with earlier bench-scale disinfection survival data and with survival in iodinated simulated shower water used in a test water recycling system.

Iron oxidation kinetics and phosphate immobilization along the flow-path from groundwater into surface water

NASA Astrophysics Data System (ADS)

van der Grift, B.; Rozemeijer, J. C.; Griffioen, J.; van der Velde, Y.

2014-11-01

The retention of phosphorus in surface waters through co-precipitation of phosphate with Fe-oxyhydroxides during exfiltration of anaerobic Fe(II) rich groundwater is not well understood. We developed an experimental field set-up to study Fe(II) oxidation and P immobilization along the flow-path from groundwater into surface water in an agricultural experimental catchment of a small lowland river. We physically separated tube drain effluent from groundwater discharge before it entered a ditch in an agricultural field. Through continuous discharge measurements and weekly water quality sampling of groundwater, tube drain water, exfiltrated groundwater, and surface water, we investigated Fe(II) oxidation kinetics and P immobilization processes. The oxidation rate inferred from our field measurements closely agreed with the general rate law for abiotic oxidation of Fe(II) by O2. Seasonal changes in climatic conditions affected the Fe(II) oxidation process. Lower pH and lower temperatures in winter (compared to summer) resulted in low Fe oxidation rates. After exfiltration to the surface water, it took a couple of days to more than a week before complete oxidation of Fe(II) is reached. In summer time, Fe oxidation rates were much higher. The Fe concentrations in the exfiltrated groundwater were low, indicating that dissolved Fe(II) is completely oxidized prior to inflow into a ditch. While the Fe oxidation rates reduce drastically from summer to winter, P concentrations remained high in the groundwater and an order of magnitude lower in the surface water throughout the year. This study shows very fast immobilization of dissolved P during the initial stage of the Fe(II) oxidation process which results in P-depleted water before Fe(II) is completely depleted. This cannot be explained by surface complexation of phosphate to freshly formed Fe-oxyhydroxides but indicates the formation of Fe(III)-phosphate precipitates. The formation of Fe(III)-phosphates at redox gradients seems an important geochemical mechanism in the transformation of dissolved phosphate to structural phosphate and, therefore, a major control on the P retention in natural waters that drain anaerobic aquifers.

Mechanics of water pore formation in lipid membrane under electric field

NASA Astrophysics Data System (ADS)

Bu, Bing; Li, Dechang; Diao, Jiajie; Ji, Baohua

2017-04-01

Transmembrane water pores are crucial for substance transport through cell membranes via membrane fusion, such as in neural communication. However, the molecular mechanism of water pore formation is not clear. In this study, we apply all-atom molecular dynamics and bias-exchange metadynamics simulations to study the process of water pore formation under an electric field. We show that water molecules can enter a membrane under an electric field and form a water pore of a few nanometers in diameter. These water molecules disturb the interactions between lipid head groups and the ordered arrangement of lipids. Following the movement of water molecules, the lipid head groups are rotated and driven into the hydrophobic region of the membrane. The reorientated lipid head groups inside the membrane form a hydrophilic surface of the water pore. This study reveals the atomic details of how an electric field influences the movement of water molecules and lipid head groups, resulting in water pore formation.

Physical and hydrochemical evidence of lake leakage near Jim Woodruff lock and dam and ground-water inflow to Lake Seminole, and an assessment of karst features in and near the lake, southwestern Georgia and northwestern Florida

USGS Publications Warehouse

Torak, Lynn J.; Crilley, Dianna M.; Painter, Jaime A.

2006-01-01

Hydrogeologic data and water-chemistry analyses indicate that Lake Seminole leaks into the Upper Floridan aquifer near Jim Woodruff Lock and Dam, southwestern Georgia and northwestern Florida, and that ground water enters Lake Seminole along upstream reaches of the lake's four impoundment arms (Chattahoochee and Flint Rivers, Spring Creek, and Fishpond Drain). Written accounts by U.S. Army Corps of Engineers geologists during dam construction in the late 1940s and early 1950s, and construction-era photographs, document karst-solution features in the limestone that comprise the lake bottom and foundation rock to the dam, and confirm the hydraulic connection of the lake and aquifer. More than 250 karst features having the potential to connect the lake and aquifer were identified from preimpoundment aerial photographs taken during construction. An interactive map containing a photomosaic of 53 photographic negatives was orthorectfied to digital images of 1:24,000-scale topographic maps to aid in identifying karst features that function or have the potential to function as locations of water exchange between Lake Seminole and the Upper Floridan aquifer. Some identified karst features coincide with locations of mapped springs, spring runs, and depressions that are consistent with sinkholes and sinkhole ponds. Hydrographic surveys using a multibeam echosounder (sonar) with sidescan sonar identified sinkholes in the lake bottom along the western lakeshore and in front of the dam. Dye-tracing experiments indicate that lake water enters these sinkholes and is transported through the Upper Floridan aquifer around the west side of the dam at velocities of about 500 feet per hour to locations where water 'boils up' on land (at Polk Lake Spring) and in the channel bottom of the Apalachicola River (at the 'River Boil'). Water discharging from Polk Lake Spring joins flow from a spring-fed ground-water discharge zone located downstream of the dam; the combined flow disappears into a sinkhole located on the western floodplain of the river and is transmitted through the Upper Floridan aquifer, eventually discharging to the Apalachicola River at the River Boil. Acoustic Doppler current profiling yielded flow estimates from the River Boil in the range from about 140 to 220 cubic feet per second, which represents from about 1 to 3 percent of the average daily flow in the river. Binary mixing-model analysis using naturally occurring isotopes of oxygen and hydrogen (oxygen-18 and deuterium) indicates that discharge from the River Boil consists of a 13-to-1 ratio of lake water to ground water and that other sources of lake leakage and discharge to the boil probably exist. Analyses of major ions, nutrients, radon-222, and stable isotopes of hydrogen and oxygen contained in water samples collected from 29 wells, 7 lake locations, and 5 springs in the Lake Seminole area during 2000 indicate distinct chemical signatures for ground water and surface water. Ground-water samples contained higher concentrations of calcium and magnesium, and higher alkalinity and specific conductance than surface-water samples, which contained relatively high concentrations of total organic carbon and sulfate. Solute and isotopic tracers indicate that, from May to October 2000, springflow exhibited more ground-water qualities (high specific conductance, low dissolved oxygen, and low temperature) than surface water; however, the ratio of ground water to surface water of the springs was difficult to quantify from November to April because of reduced springflow and rapid mixing of springflow and lake water during sampling. The saturation index of calcite in surface-water samples indicates that while surface water is predominately undersaturated with regard to calcite year-round, a higher potential for dissolution of the limestone matrix exists from late fall through early spring than during summer. The relatively short residence time (5-7 hours) and rapid flow velocity

Curtailing Agricultural Pumping in an Era of Extended Drought: Infusing Science and Leagality into a Common Hydrologic Framework

NASA Astrophysics Data System (ADS)

Carroll, R. W. H.; Pohll, G.; Benedict, J.; Felling, R.

2016-12-01

Many arid and semi-arid agricultural systems of the Great Basin in the western United States depend on supplemental groundwater pumping to augment diminished surface water flows during periods of drought. As droughts become longer and more severe in the region, unprecedented drawdown in these aquifer systems has occurred with legal and environmental implications on both surface and groundwater. The Walker River in the Great Basin supports extensive agriculture in the region and is the sole perennial stream to one of the few desert terminal lakes in North America. Continuous declines in the lake have spurred extensive research into management options to balance demands of agriculture and increase water deliveries to the lake. Smith and Mason Valleys are important agricultural centers within the Walker Basin. In 2015 the region entered its fifth year of drought and both valleys were the focus of curtailment orders to restrict the use of supplemental groundwater rights. To aid management decisions, hydrologic models were developed that simulate complex feedbacks between surface diversions, crop consumptive needs, groundwater recharge, return flow, and groundwater-surface water interactions. Demand-driven pumping that incorporates priority dates and maximum duty allocations are directly input to the hydrologic model to allow an assessment of groundwater curtailment options under a variety of drought scenarios to meet targeted water levels and downstream conveyance of surface water in a legally defensible framework. Hydrologic results using a sliding scale approach to priority based curtailment are presented in the arena of stakeholder participation and response.

Application of new point measurement device to quantify groundwater-surface water interactions

NASA Astrophysics Data System (ADS)

Cremeans, M. M.; Devlin, J. F.; McKnight, U. S.; Bjerg, P. L.

2018-04-01

The streambed point velocity probe (SBPVP) measures in situ groundwater velocities at the groundwater-surface water interface without reliance on hydraulic conductivity, porosity, or hydraulic gradient information. The tool operates on the basis of a mini-tracer test that occurs on the probe surface. The SBPVP was used in a meander of the Grindsted Å (stream), Denmark, to determine the distribution of flow through the streambed. These data were used to calculate the contaminant mass discharge of chlorinated ethenes into the stream. SBPVP data were compared with velocities estimated from hydraulic head and temperature gradient data collected at similar scales. Spatial relationships of water flow through the streambed were found to be similar by all three methods, and indicated a heterogeneous pattern of groundwater-surface water exchange. The magnitudes of estimated flow varied to a greater degree. It was found that pollutants enter the stream in localized regions of high flow which do not always correspond to the locations of highest pollutant concentration. The results show the combined influence of flow and concentration on contaminant discharge and illustrate the advantages of adopting a flux-based approach to risk assessment at the groundwater-surface water interface. Chlorinated ethene mass discharges, expressed in PCE equivalents, were determined to be up to 444 kg/yr (with SBPVP data) which compared well with independent estimates of mass discharge up to 438 kg/yr (with mini-piezometer data from the streambed) and up to 372 kg/yr crossing a control plane on the streambank (as determined in a previous, independent study).

Shifting Surface Currents in the Northern North Atlantic Ocean

NASA Technical Reports Server (NTRS)

Hakkinen, Sirpa; Rhines, Peter B.

2007-01-01

Analysis of surface drifter tracks in the North Atlantic Ocean from the time period 1990 to 2006 provides the first evidence that the Gulf Stream waters can have direct pathways to the Nordic Seas. Prior to 2000, the drifters entering the channels leading to the Nordic Seas originated in the western and central subpolar region. Since 2001 several paths from the western subtropics have been present in the drifter tracks leading to the Rockall Trough through which the most saline North Atlantic Waters pass to the Nordic Seas. Eddy kinetic energy from altimetry shows also the increased energy along the same paths as the drifters, These near surface changes have taken effect while the altimetry shows a continual weakening of the subpolar gyre. These findings highlight the changes in the vertical structure of the northern North Atlantic Ocean, its dynamics and exchanges with the higher latitudes, and show how pathways of the thermohaline circulation can open up and maintain or increase its intensity even as the basin-wide circulation spins down.

Short circuit of water vapor and polluted air to the global stratosphere by convective transport over the Tibetan Plateau

PubMed Central

Fu, Rong; Hu, Yuanlong; Wright, Jonathon S.; Jiang, Jonathan H.; Dickinson, Robert E.; Chen, Mingxuan; Filipiak, Mark; Read, William G.; Waters, Joe W.; Wu, Dong L.

2006-01-01

During boreal summer, much of the water vapor and CO entering the global tropical stratosphere is transported over the Asian monsoon/Tibetan Plateau (TP) region. Studies have suggested that most of this transport is carried out either by tropical convection over the South Asian monsoon region or by extratropical convection over southern China. By using measurements from the newly available National Aeronautics and Space Administration Aura Microwave Limb Sounder, along with observations from the Aqua and Tropical Rainfall-Measuring Mission satellites, we establish that the TP provides the main pathway for cross-tropopause transport in this region. Tropospheric moist convection driven by elevated surface heating over the TP is deeper and detrains more water vapor, CO, and ice at the tropopause than over the monsoon area. Warmer tropopause temperatures and slower-falling, smaller cirrus cloud particles in less saturated ambient air at the tropopause also allow more water vapor to travel into the lower stratosphere over the TP, effectively short-circuiting the slower ascent of water vapor across the cold tropical tropopause over the monsoon area. Air that is high in water vapor and CO over the Asian monsoon/TP region enters the lower stratosphere primarily over the TP, and it is then transported toward the Asian monsoon area and disperses into the large-scale upward motion of the global stratospheric circulation. Thus, hydration of the global stratosphere could be especially sensitive to changes of convection over the TP. PMID:16585523

Review: Epidemiological evidence of groundwater contribution to global enteric disease, 1948-2015

NASA Astrophysics Data System (ADS)

Murphy, Heather M.; Prioleau, Morgan D.; Borchardt, Mark A.; Hynds, Paul D.

2017-06-01

Globally, approximately 2.2 billion people rely on groundwater for daily consumption. It is widely accepted that groundwater is more pristine than surface water but while this assumption is frequently the case, groundwater is not ubiquitously free of contaminants; accordingly, this presumption can result in an unfounded and potentially hazardous sense of security among owners, operators and users. The current paper presents a review of published literature providing epidemiological evidence of the contribution of groundwater to global human enteric infection. An emphasis is placed on enteric pathogens transmitted via the faecal-oral route, and specifically those associated with acute gastrointestinal illness (AGI). The review identified 649 published groundwater outbreaks globally between 1948 and 2013 and several epidemiological studies that show there is an increased risk of AGI associated with the consumption of untreated groundwater. The review identified that the following five pathogens were responsible for most outbreaks: norovirus, Campylobacter, Shigella, Hepatitis A and Giardia. Crudely, the authors estimate that between 35.2 and 59.4 million cases of AGI per year globally could be attributable to the consumption of groundwater. Although groundwater is frequently presumed to be a microbiologically safe source of water for consumption, this review demonstrates that consumers served by an untreated groundwater supply remain at risk to enteric disease. The authors conclude that collaboration between microbiologists, hydrogeologists and epidemiologists is needed to better understand pathogen occurrence, persistence, detection and transport in groundwater as well as build stronger epidemiological evidence documenting the true magnitude of disease associated with groundwater globally.

Hybrid constructed wetlands for highly polluted river water treatment and comparison of surface- and subsurface-flow cells.

PubMed

Zheng, Yucong; Wang, Xiaochang; Xiong, Jiaqing; Liu, Yongjun; Zhao, Yaqian

2014-04-01

A series of large pilot constructed wetland (CW) systems were constructed near the confluence of an urban stream to a larger river in Xi'an, a northwestern megacity in China, for treating polluted stream water before it entered the receiving water body. Each CW system is a combination of surface-and subsurface-flow cells with local gravel, sand or slag as substrates and Phragmites australis and Typha orientalis as plants. During a one-year operation with an average surface loading of 0.053 m(3)/(m(2)·day), the overall COD, BOD, NH3-N, total nitrogen (TN) and total phosphorus (TP) removals were 72.7% ± 4.5%, 93.4% ± 2.1%, 54.0% ± 6.3%, 53.9% ± 6.0% and 69.4% ± 4.6%, respectively, which brought about an effective improvement of the river water quality. Surface-flow cells showed better NH3-N removal than their TN removal while subsurface-flow cells showed better TN removal than their NH3-N removal. Using local slag as the substrate, the organic and phosphorus removal could be much improved. Seasonal variation was also found in the removal of all the pollutants and autumn seemed to be the best season for pollutant removal due to the moderate water temperature and well grown plants in the CWs. Copyright © 2014 The Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

Responses of Surface Runoff to Climate Change and Human Activities in the Arid Region of Central Asia: A Case Study in the Tarim River Basin, China

NASA Astrophysics Data System (ADS)

Xu, Changchun; Chen, Yaning; Chen, Yapeng; Zhao, Ruifeng; Ding, Hui

2013-04-01

Based on hydrological and climatic data and land use/cover change data covering the period from 1957 to 2009, this paper investigates the hydrological responses to climate change and to human activities in the arid Tarim River basin (TRB). The results show that the surface runoff of three headstreams (Aksu River, Yarkant River and Hotan River) of the Tarim River exhibited a significant increasing trend since 1960s and entered an even higher-runoff stage in 1994. In the contrary, the surface runoff of Tarim mainstream displayed a persistent decreasing trend since 1960s. The increasing trend of surface runoff in the headstreams can be attributed to the combined effects of both temperature and precipitation changes during the past five decades. But, the decreasing trend of surface runoff in the mainstream and the observed alterations of the temporal and spatial distribution patterns were mainly due to the adverse impacts of human activities. Specifically, increasingly intensified water consumption for irrigation and the associated massive constructions of water conservancy projects were responsible for the decreasing trend of runoff in the mainstream. And, the decreasing trend has been severely jeopardizing the ecological security in the lower reaches. It is now unequivocally clear that water-use conflicts among different sectors and water-use competitions between upper and lower reaches are approaching to dangerous levels in TRB that is thus crying for implementing an integrated river basin management scheme.

Responses of surface runoff to climate change and human activities in the arid region of central Asia: a case study in the Tarim River basin, China.

PubMed

Xu, Changchun; Chen, Yaning; Chen, Yapeng; Zhao, Ruifeng; Ding, Hui

2013-04-01

Based on hydrological and climatic data and land use/cover change data covering the period from 1957 to 2009, this paper investigates the hydrological responses to climate change and to human activities in the arid Tarim River basin (TRB). The results show that the surface runoff of three headstreams (Aksu River, Yarkant River and Hotan River) of the Tarim River exhibited a significant increasing trend since 1960s and entered an even higher-runoff stage in 1994. In the contrary, the surface runoff of Tarim mainstream displayed a persistent decreasing trend since 1960s. The increasing trend of surface runoff in the headstreams can be attributed to the combined effects of both temperature and precipitation changes during the past five decades. But, the decreasing trend of surface runoff in the mainstream and the observed alterations of the temporal and spatial distribution patterns were mainly due to the adverse impacts of human activities. Specifically, increasingly intensified water consumption for irrigation and the associated massive constructions of water conservancy projects were responsible for the decreasing trend of runoff in the mainstream. And, the decreasing trend has been severely jeopardizing the ecological security in the lower reaches. It is now unequivocally clear that water-use conflicts among different sectors and water-use competitions between upper and lower reaches are approaching to dangerous levels in TRB that is thus crying for implementing an integrated river basin management scheme.

Variability of trace-metal fluxes through the Strait of Gibraltar

NASA Astrophysics Data System (ADS)

van Geen, Alexander; Boyle, Edward

1990-10-01

Three water masses originating in the Atlantic and entering the Alboran Sea through the Strait of Gibraltar have recently been identified on the basis of salinity and Cu, Ni, Cd and Zn concentrations. The endmembers are (1) Atlantic surface water, (2) North Atlantic Central Water and (3) Spanish shelf water. Spanish shelf water is of particular relevance to the trace-metal composition of the inflow to the Mediterranean Sea because this water mass is highly enriched in Cu, Cd and Zn relative to Atlantic surface water. Here, a conservative mixing model is solved for the above Atlantic endmembers, (with the addition of (4) a Mediterranean deep-water endmember) by weighted least-squares and shown to be consistent with tracer data for 42 surface samples collected in April '86 within the Strait of Gibraltar. Sensitivity of the solution to errors in the data and the assumptions of the model are discussed in detail. Uncertainties in the proportions of metal-enriched Spanish shelf water and NACW are (at most) on the order of 6 and 16%, respectively, and often smaller depending on the composition of a given sample. The inversion shows that Spanish shelf water is present predominantly in the northern half of the Strait and contributes up to 55% to Alboran Sea surface samples. Determining a representative composition of the inflow is complicated, however, by rapid change in the proportion of the three Atlantic endmembers present in the Strait of Gibraltar: entrainment of Spanish shelf water through the Strait roughly doubles between April 11 and 17. We show that the timing of collection of these samples minimizes a potential bias in endmember distributions simply due to variable tidal currents. The increase in entrainment of Spanish shelf water from neap tide to spring tide could, therefore, reflect a significant shift to the north of source waters to the Atlantic inflow over the course of a week. The data show that entrainment of Spanish shelf water is a significant source of the increased Cu, Cd and Zn concentrations observed in the Mediterranean relative to open Atlantic surface water, and this source may even account for the greater part of the Mediterranean enrichments.

Habitable Planets Around White and Brown Dwarfs: The Perils of a Cooling Primary

PubMed Central

Heller, René

2013-01-01

Abstract White and brown dwarfs are astrophysical objects that are bright enough to support an insolation habitable zone (IHZ). Unlike hydrogen-burning stars, they cool and become less luminous with time; hence their IHZ moves in with time. The inner edge of the IHZ is defined as the orbital radius at which a planet may enter a moist or runaway greenhouse, phenomena that can remove a planet's surface water forever. Thus, as the IHZ moves in, planets that enter it may no longer have any water and are still uninhabitable. Additionally, the close proximity of the IHZ to the primary leads to concern that tidal heating may also be strong enough to trigger a runaway greenhouse, even for orbital eccentricities as small as 10−6. Water loss occurs due to photolyzation by UV photons in the planetary stratosphere, followed by hydrogen escape. Young white dwarfs emit a large amount of these photons, as their surface temperatures are over 104 K. The situation is less clear for brown dwarfs, as observational data do not constrain their early activity and UV emission very well. Nonetheless, both types of planets are at risk of never achieving habitable conditions, but planets orbiting white dwarfs may be less likely to sustain life than those orbiting brown dwarfs. We consider the future habitability of the planet candidates KOI 55.01 and 55.02 in these terms and find they are unlikely to become habitable. Key Words: Extrasolar terrestrial planets—Habitability—Habitable zone—Tides—Exoplanets. Astrobiology 13, 279–291. PMID:23537137

Department of Defense Strategy to Support Multi-Agency Bat Conservation Initiative within the State of Utah

DTIC Science & Technology

2008-02-28

Range, and Section are entered. Datum: Geometric reference surface. Original Site Location datum is defined by user’s map datum; e.g. NAD27...Section are entered. Datum: Geometric reference surface. Original Site Location datum is defined by user’s map datum; e.g. NAD27 Conus or NAD83...Calculated and recorded automatically if the fields UTM_N and UTM_E or Township, Range, and Section are entered. 41 Datum: Geometric reference surface

Spatial Distribution of Nitrate in Mizoro-Ga a Pond with Floating at Bog

NASA Astrophysics Data System (ADS)

Shimamura, Tetsuya; Takemon, Yasuhiro; Osaka, Ken'ichi; Itoh, Masayuki; Ohte, Nobuhito

Artificial nutrient loading has been linked to the decrease in plant diversity in peatlands, riparian areas, and swamps. Mizoro-ga-ike pond is one of the natural monuments of Japan and contains temperate floating mat and diverse plant community. The pond had experienced eutrophication by sewage and tap water. As the inflows of nutrient-rich water had been lessened, the amount of source area of the pond has decreased to 30%. We investigated factors that control water chemistry in and around the pond to assess the present situation of the pond. The pond has two mouths of inflows. One of the inflows includes leaked water from a tap water reserver. The other is the surface flow collected by a ditch. The result of water quality census indicates the pond has two sources of nutrient-rich water. One is the drainage from the surface water polluted by the road for automobile that flows into the northern coast of the pond, and the other is the tap water-contaminated water entering from the southern coast. Also the result of the census indicates that emergent plants such as reeds and wild rice modify the effect of nutrient-rich water by exploiting nutrients. Especially, it was suggested that the nursery effects of emergent grasslands that spread southern part of the pond protect the less robust plants, Nuphar subintegerrimum.

Spatial Distribution of Nitrate in Mizoro-Ga a Pond with Floating Mat Bog

NASA Astrophysics Data System (ADS)

Shimamura, Tetsuya; Takemon, Yasuhiro; Osaka, Ken'ichi; Itoh, Masayuki; Ohte, Nobuhito

Artificial nutrient loading has been linked to the decrease in plant diversity in peatlands, riparian areas, and swamps. Mizoro-ga-ike pond is one of the natural monuments of Japan and contains temperate floating mat and diverse plant community. The pond had experienced eutrophication by sewage and tap water. As the inflows of nutrient-rich water had been lessened, the amount of source area of the pond has decreased to 30%. We investigated factors that control water chemistry in and around the pond to assess the present situation of the pond. The pond has two mouths of inflows. One of the inflows includes leaked water from a tap water reserver. The other is the surface flow collected by a ditch. The result of water quality census indicates the pond has two sources of nutrient-rich water. One is the drainage from the surface water polluted by the road for automobile that flows into the northern coast of the pond, and the other is the tap water-contaminated water entering from the southern coast. Also the result of the census indicates that emergent plants such as reeds and wild rice modify the effect of nutrient-rich water by exploiting nutrients. Especially, it was suggested that the nursery effects of emergent grasslands that spread southern part of the pond protect the less robust plants, Nuphar subintegerrimum.

Distribution and decline of human pathogenic bacteria in soil after application in irrigation water and the potential for soil-splash-mediated dispersal onto fresh produce.

PubMed

Monaghan, J M; Hutchison, M L

2012-05-01

To improve our understanding of the survival and splash-mediated transfer of zoonotic agents and faecal indicator bacteria introduced into soils used for crop cultivation via contaminated irrigation waters. Zoonotic agents and an Escherichia coli marker bacterium were inoculated into borehole water, which was applied to two different soil types in early-, mid- and late summer. Decline of the zoonotic agents was influenced by soil type. Marker bacteria applied to columns of two soil types in irrigation water did not concentrate at the surface of the soils. Decline of zoonotic agents at the surface was influenced by soil type and environmental conditions. Typically, declines were rapid and bacteria were not detectable after 5 weeks. Selective agar strips were used to determine that the impact of water drops 24-87 μl could splash marker bacteria from soil surfaces horizontal distances of at least 25 cm and heights of 20 cm. Soil splash created by rain-sized water droplets can transfer enteric bacteria from soil to ready-to-eat crops. Persistence of zoonotic agents was reduced at the hottest part of the growing season when irrigation is most likely. Soil splash can cause crop contamination. We report the penetration depths and seasonally influenced declines of bacteria applied in irrigation water into two soil types. © 2012 The Authors. Journal of Applied Microbiology © 2012 The Society for Applied Microbiology.

Capture and storage of hydrogen gas by zero-valent iron.

PubMed

Reardon, Eric J

2014-02-01

Granular Fe(o), used to reductively degrade a variety of contaminants in groundwater, corrodes in water to produce H2(g). A portion enters the Fe(o) lattice where it is stored in trapping sites such as lattice defects and microcracks. The balance is dissolved by the groundwater where it may exsolve as a gas if its solubility is exceeded. Gas exsolution can reduce the effectiveness of the Fe(o) treatment zone by reducing contact of the contaminant with iron surfaces or by diverting groundwater flow. It also represents a lost electron resource that otherwise could be involved in reductive degradation of contaminants. It is advantageous to select an iron for remediation purposes that captures a large proportion of the H2(g) it generates. This study examines various aspects of the H2(g) uptake process and has found 1) H2(g) does not have to be generated at the water/iron interface to enter the lattice. It can enter directly from the gas/water phases, 2) exposure of granular sponge iron to H2(g) reduces the dormant period for the onset of iron corrosion, 3) the large quantities of H2(g) generated by nano-Fe(o) injected into a reactive barrier of an appropriate granular iron can be captured in the lattice of that iron, and 4) lattice-bound hydrogen represents an additional electron resource to Fe(o) for remediation purposes and may be accessible using physical or chemical means. Copyright © 2013 Elsevier B.V. All rights reserved.

Analysis of cyanobacterial metabolites in surface and raw drinking waters reveals more than microcystin.

PubMed

Beversdorf, Lucas J; Rude, Kayla; Weirich, Chelsea A; Bartlett, Sarah L; Seaman, Mary; Kozik, Christine; Biese, Peter; Gosz, Timothy; Suha, Michael; Stempa, Christopher; Shaw, Christopher; Hedman, Curtis; Piatt, Joseph J; Miller, Todd R

2018-04-16

Freshwater cyanobacterial blooms are becoming increasingly problematic in regions that rely on surface waters for drinking water production. Microcystins (MCs) are toxic peptides produced by multiple cyanobacterial genera with a global occurrence. Cyanobacteria also produce a variety of other toxic and/or otherwise bioactive peptides (TBPs) that have gained less attention including cyanopeptolins (Cpts), anabaenopeptins (Apts), and microginins (Mgn). In this study, we compared temporal and spatial trends of four MCs (MCLR, MCRR, MCYR, MCLA), three Cpts (Cpt1020, Cpt1041, Cpt1007), two Apts (AptF, AptB), and Mgn690 in raw drinking water and at six surface water locations above these drinking water intakes in a eutrophic lake. All four MC congeners and five of six TBPs were detected in lake and raw drinking water. Across all samples, MCLR was the most frequently detected metabolite (100% of samples) followed by MCRR (97%) > Cpt1007 (74%) > MCYR (69%) > AptF (67%) > MCLA (61%) > AptB (54%) > Mgn690 (29%) and Cpt1041 (15%). Mean concentrations of MCs, Apts, and Cpts into two drinking water intakes were 3.9 ± 4.7, 0.14 ± 0.21, and 0.38 ± 0.92, respectively. Mean concentrations in surface water were significantly higher (p < 0.05) than in drinking water intakes for MCs but not for Cpts and Apts. Temporal trends in MCs, Cpts, and Apts in the two raw drinking water intakes were significantly correlated (p < 0.05) with measures of cell abundance (chlorophyll-a, Microcystis cell density), UV absorbance, and turbidity in surface water. This study expands current information about cyanobacterial TBPs that occur in lakes and that enter drinking water treatment plants and underscores the need to determine the fate of less studied cyanobacterial metabolites during drinking water treatment that may exacerbate toxicity of more well-known cyanobacterial toxins. Copyright © 2018 Elsevier Ltd. All rights reserved.

Comparative Climates of the Trappist-1 Planetary System: Results from a Simple Climate-vegetation Model

DOE Office of Scientific and Technical Information (OSTI.GOV)

Alberti, Tommaso; Carbone, Vincenzo; Lepreti, Fabio

The recent discovery of the planetary system hosted by the ultracool dwarf star TRAPPIST-1 could open new paths for investigations of the planetary climates of Earth-sized exoplanets, their atmospheres, and their possible habitability. In this paper, we use a simple climate-vegetation energy-balance model to study the climate of the seven TRAPPIST-1 planets and the climate dependence on various factors: the global albedo, the fraction of vegetation that could cover their surfaces, and the different greenhouse conditions. The model allows us to investigate whether liquid water could be maintained on the planetary surfaces (i.e., by defining a “surface water zone (SWZ)”)more » in different planetary conditions, with or without the presence of a greenhouse effect. It is shown that planet TRAPPIST-1d seems to be the most stable from an Earth-like perspective, since it resides in the SWZ for a wide range of reasonable values of the model parameters. Moreover, according to the model, outer planets (f, g, and h) cannot host liquid water on their surfaces, even with Earth-like conditions, entering a snowball state. Although very simple, the model allows us to extract the main features of the TRAPPIST-1 planetary climates.« less

Lateral and subsurface flows impact arctic coastal plain lake water budgets

USGS Publications Warehouse

Koch, Joshua C.

2016-01-01

Arctic thaw lakes are an important source of water for aquatic ecosystems, wildlife, and humans. Many recent studies have observed changes in Arctic surface waters related to climate warming and permafrost thaw; however, explaining the trends and predicting future responses to warming is difficult without a stronger fundamental understanding of Arctic lake water budgets. By measuring and simulating surface and subsurface hydrologic fluxes, this work quantified the water budgets of three lakes with varying levels of seasonal drainage, and tested the hypothesis that lateral and subsurface flows are a major component of the post-snowmelt water budgets. A water budget focused only on post-snowmelt surface water fluxes (stream discharge, precipitation, and evaporation) could not close the budget for two of three lakes, even when uncertainty in input parameters was rigorously considered using a Monte Carlo approach. The water budgets indicated large, positive residuals, consistent with up to 70% of mid-summer inflows entering lakes from lateral fluxes. Lateral inflows and outflows were simulated based on three processes; supra-permafrost subsurface inflows from basin-edge polygonal ground, and exchange between seasonally drained lakes and their drained margins through runoff and evapotranspiration. Measurements and simulations indicate that rapid subsurface flow through highly conductive flowpaths in the polygonal ground can explain the majority of the inflow. Drained lakes were hydrologically connected to marshy areas on the lake margins, receiving water from runoff following precipitation and losing up to 38% of lake efflux to drained margin evapotranspiration. Lateral fluxes can be a major part of Arctic thaw lake water budgets and a major control on summertime lake water levels. Incorporating these dynamics into models will improve our ability to predict lake volume changes, solute fluxes, and habitat availability in the changing Arctic.

River stage influences on uranium transport in a hydrologically dynamic groundwater-surface water transition zone: U TRANSPORT IN A GROUNDWATER-SURFACE WATER TRANSITION ZONE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zachara, John M.; Chen, Xingyuan; Murray, Chris

A tightly spaced well-field within a groundwater uranium (U) plume in the groundwater-surface water transition zone was monitored for a three year period for groundwater elevation and dissolved solutes. The plume discharges to the Columbia River, which displays a dramatic spring stage surge resulting from mountain snowmelt. Groundwater exhibits a low hydrologic gradient and chemical differences with river water. River water intrudes the site in spring. Specific aims were to assess the impacts of river intrusion on dissolved uranium (Uaq), specific conductance (SpC), and other solutes, and to discriminate between transport, geochemical, and source term heterogeneity effects. Time series trendsmore » for Uaq and SpC were complex and displayed large temporal well-to well variability as a result of water table elevation fluctuations, river water intrusion, and changes in groundwater flow directions. The wells were clustered into subsets exhibiting common temporal behaviors resulting from the intrusion dynamics of river water and the location of source terms. Concentration hot spots were observed in groundwater that varied in location with increasing water table elevation. Heuristic reactive transport modeling with PFLOTRAN demonstrated that mobilized U was transported between wells and source terms in complex trajectories, and was diluted as river water entered and exited the groundwater system. While uranium time-series concentration trends varied significantly from year to year as a result of climate-caused differences in the spring hydrograph, common and partly predictable response patterns were observed that were driven by water table elevation, and the extent and duration of the river water intrusion event.« less

Water cycle research associated with the CaPE hydrometeorology project (CHymP

NASA Technical Reports Server (NTRS)

Duchon, Claude E.

1993-01-01

One outgrowth of the Convection and Precipitation/Electrification (CaPE) experiment that took place in central Florida during July and August 1991 was the creation of the CaPE Hydrometeorology Project (CHymP). The principal goal of this project is to investigate the daily water cycle of the CaPE experimental area by analyzing the numerous land and atmosphere in situ and remotely sensed data sets that were generated during the 40-days of observations. The water cycle comprises the atmospheric branch. In turn, the atmospheric branch comprises precipitation leaving the base of the atmospheric volume under study, evaporation and transpiration entering the base, the net horizontal fluxes of water vapor and cloud water through the volume and the conversion of water vapor to cloud water and vice-versa. The sum of these components results in a time rate of change in the water and liquid water (or ice) content of the atmospheric volume. The components of the land branch are precipitation input to and evaporation and transpiration output from the surface, net horizontal fluxes of surface and subsurface water, the sum of which results in a time rate of change in surface and subsurface water mass. The objective of CHymP is to estimate these components in order to determine the daily water budget for a selected area within the CaPE domain. This work began in earnest in the summer of 1992 and continues. Even estimating all the budget components for one day is a complex and time consuming task. The discussions below provides a short summary of the rainfall quality assessment procedures followed by a plan for estimating the horizontal moisture flux.

Water quality of a coastal Louisiana swamp and how dredging is undermining restoration efforts

NASA Astrophysics Data System (ADS)

Lane, Robert R.; Huang, Haosheng; Day, John W.; Justic, Dubravko; DeLaune, Ronald D.

2015-01-01

The Bayou Boeuf Basin (BBB), a sub-basin of the Barataria Basin estuary in coastal Louisiana, consists of forested and floating wetlands receiving drainage from surrounding agricultural fields and urban watersheds. We characterized surface water quality in the BBB, and determined through hydrologic modeling if a series of levee breaks along major drainage channels would significantly improve water quality by allowing flow into surrounding wetlands. Surface water monitoring found surrounding sugarcane farm fields to be major sources of nutrient and sediment loading. Hydrological modeling indicated that levee breaks would increase N reduction from the current 21.4% to only 29.2%, which is much lower than the anticipated 90-100% removal rate. This was due to several factors, one them being dredging of main drainage channels to such a degree that water levels do not rise much above the surrounding wetland elevation even during severe storms, so only a very small fraction of the stormwater carried in the channel is exposed to wetlands. These unexpected results provide insight into an undoubtedly pervasive problem in human dominated wetland systems; that of decreased flooding during storm events due to channel deepening by dredging activities. Additional water quality management practices should be implemented at the farm field level, prior to water entering major drainage canals.

Mercury, monomethyl mercury, and dissolved organic carbon concentrations in surface water entering and exiting constructed wetlands treated with metal-based coagulants, Twitchell Island, California

USGS Publications Warehouse

Stumpner, Elizabeth B.; Kraus, Tamara E.C.; Fleck, Jacob A.; Hansen, Angela M.; Bachand, Sandra M.; Horwath, William R.; DeWild, John F.; Krabbenhoft, David P.; Bachand, Philip A.M.

2015-09-02

Following coagulation, but prior to passage through the wetland cells, coagulation treatments transferred dissolved mercury and carbon to the particulate fraction relative to untreated source water: at the wetland cell inlets, the coagulation treatments decreased concentrations of filtered total mercury by 59–76 percent, filtered monomethyl mercury by 40–70 percent, and dissolved organic carbon by 65–86 percent. Passage through the wetland cells decreased the particulate fraction of mercury in wetland cells that received coagulant-treated water. Changes in total mercury, monomethyl mercury, and dissolved organic carbon concentrations resulting from wetland passage varied both by treatment and season. Despite increased monomethyl mercury in the filtered fraction during wetland passage between March and August, the coagulation-wetland systems generally decreased total mercury (filtered plus particulate) and monomethyl mercury (filtered plus particulate) concentrations relative to source water. Coagulation—either alone or in association with constructed wetlands—could be an effective way to decrease concentrations of mercury and dissolved organic carbon in surface water as well as the bioavailability of mercury in the Sacramento–San Joaquin Delta.

Indian Ocean sources of Agulhas leakage

NASA Astrophysics Data System (ADS)

Durgadoo, Jonathan; Rühs, Siren; Biastoch, Arne; Böning, Claus

2017-04-01

We examine the mean pathways, transit timescales, and transformation of waters flowing from the Pacific and the marginal seas through the Indian Ocean (IO) on their way toward the South Atlantic within a high-resolution ocean/sea-ice model. The model fields are analysed from a Lagrangian perspective where water volumes are tracked as they enter the IO. The IO contributes 12.6 Sv to Agulhas leakage, which within the model is 14.1 ± 2.2 Sv, the rest originates from the South Atlantic. The Indonesian Through-flow constitutes about half of the IO contribution, is surface bound, cools and salinificates as it leaves the basin within 1-3 decades. Waters entering the IO south of Australia are at intermediate depths and maintain their temperature-salinity properties as they exit the basin within 1.5-3.5 decades. Of these waters, the contribution from Tasman leakage is 1.4 Sv. The rest stem from recirculation of Subantarctic Mode Water formed within the IO. The marginal seas export 1.0 Sv into the Atlantic within 1.5-4 decades, and the waters cool and freshen on-route. However, the model's simulation of waters from the Gulfs of Aden and Oman are too light and hence overly susceptible to upper ocean circulations. In the Cape Basin, Agulhas leakage is well mixed. On-route, temperature-salinity transformations occur predominantly in the Arabian Sea and within the greater Agulhas Current region. Overall, the IO communicates at least 7.9 Sv from the Pacific to the Atlantic, thereby quantifying the strength of the upper cell of the global conveyor belt.

The degradation behaviour of nine diverse contaminants in urban surface water and wastewater prior to water treatment.

PubMed

Cormier, Guillaume; Barbeau, Benoit; Arp, Hans Peter H; Sauvé, Sébastien

2015-12-01

An increasing diversity of emerging contaminants are entering urban surface water and wastewater, posing unknown risks for the environment. One of the main contemporary challenges in ensuring water quality is to design efficient strategies for minimizing such risks. As a first step in such strategies, it is important to establish the fate and degradation behavior of contaminants prior to any engineered secondary water treatment. Such information is relevant for assessing treatment solutions by simple storage, or to assess the impacts of contaminant spreading in the absence of water treatment, such as during times of flooding or in areas of poor infrastructure. Therefore in this study we examined the degradation behavior of a broad array of water contaminants in actual urban surface water and wastewater, in the presence and absence of naturally occurring bacteria and at two temperatures. The chemicals included caffeine, sulfamethoxazole, carbamazepine, atrazine, 17β-estradiol, ethinylestradiol, diclofenac, desethylatrazine and norethindrone. Little information on the degradation behavior of these pollutants in actual influent wastewater exist, nor in general in water for desethylatrazine (a transformation product of atrazine) and the synthetic hormone norethindrone. Investigations were done in aerobic conditions, in the absence of sunlight. The results suggest that all chemicals except estradiol are stable in urban surface water, and in waste water neither abiotic nor biological degradation in the absence of sunlight contribute significantly to the disappearance of desethylatrazine, atrazine, carbamazepine and diclofenac. Biological degradation in wastewater was effective at transforming norethindrone, 17β-estradiol, ethinylestradiol, caffeine and sulfamethoxazole, with measured degradation rate constants k and half-lives ranging respectively from 0.0082-0.52 d(-1) and 1.3-85 days. The obtained degradation data generally followed a pseudo-first-order-kinetic model. This information can be used to model degradation prior to water treatment.

Iron oxidation kinetics and phosphate immobilization along the flow-path from groundwater into surface water

NASA Astrophysics Data System (ADS)

van der Grift, B.; Rozemeijer, J. C.; Griffioen, J.; van der Velde, Y.

2014-06-01

The retention of phosphorus in surface waters though co-precipitation of phosphate with Fe-oxyhydroxides during exfiltration of anaerobic Fe(II) rich groundwater is not well understood. We developed an experimental field set-up to study Fe(II) oxidation and P immobilization along the flow-path from groundwater to surface water in an agricultural experimental catchment of a small lowland river. We physically separated tube drain effluent from groundwater discharge before it entered a ditch in an agricultural field. Through continuous discharge measurements and weekly water quality sampling of groundwater, tube drain water, exfiltrated groundwater, and ditch water, we investigated Fe(II) oxidation kinetics and P immobilization processes. The oxidation rate inferred from our field measurements closely agreed with the general rate law for abiotic oxidation of Fe(II) by O2. Seasonal changes in climatic conditions affected the Fe(II) oxidation process. Lower pH and lower temperatures in winter (compared to summer) resulted in low Fe oxidation rates. After exfiltration to the surface water, it took a couple of days to more than one week before complete oxidation of Fe(II) is reached. In summer time, Fe oxidation rates were much higher. The Fe concentrations in the exfiltrated groundwater were low, indicating that dissolved Fe(II) is completely oxidized prior to inflow into a ditch. While the Fe oxidation rates reduce drastically from summer to winter, P concentrations remained high in the groundwater and an order of magnitude lower in the surface water throughout the year. This study shows very fast immobilisation of dissolved P during the initial stage of the Fe(II) oxidation proces which results in P-depleted water before Fe(II) is competly depleted. This cannot be explained by surface complexation of phosphate to freshly formed Fe-oxyhydroxides but indicates the formation of Fe(III)-phosphate precipitates. The formation of Fe(III)-phosphates at redox gradients seems an important geochemical mechanism in the transformation of dissolved phosphate to particulate phosphate and, therefore, a major control on the P retention in natural waters that drain anaerobic aquifers.

Drainage of Southeast Greenland firn aquifer water through crevasses to the bed

NASA Astrophysics Data System (ADS)

Poinar, Kristin; Joughin, Ian; Lilien, David; Brucker, Ludovic; Kehrl, Laura; Nowicki, Sophie

2017-02-01

A firn aquifer in the Helheim Glacier catchment of Southeast Greenland lies directly upstream of a crevasse field. Previous measurements show that a 3.5-km long segment of the aquifer lost a large volume of water (26,000 - 65,000 m2 in cross section) between spring 2012 and spring 2013, compared to annual meltwater accumulation of 6000 - 15,000 m2. The water is thought to have entered the crevasses, but whether the water reached the bed or refroze within the ice sheet is unknown. We used a thermo-visco-elastic model for crevasse propagation to calculate the depths and volumes of these water-filled crevasses. We compared our model output to data from the Airborne Topographic Mapper (ATM), which reveals the near-surface geometry of specific crevasses, and WorldView images, which capture the surface expressions of crevasses across our 1.5-km study area. We found a best fit with a shear modulus between 0.2 and 1.5 GPa within our study area. We show that surface meltwater can drive crevasses to the top surface of the firn aquifer ( 20 m depth), whereupon it receives water at rates corresponding to the water flux through the aquifer. Our model shows that crevasses receiving firn-aquifer water hydrofracture through to the bed, 1000 m below, in 10-40 days. Englacial refreezing of firn-aquifer water raises the average local ice temperature by 4°C over a ten-year period, which enhances deformational ice motion by 50 m/yr, compared to the observed surface velocity of 200 m/yr. The effect of the basal water on the sliding velocity remains unknown. Were the firn aquifer not present to concentrate surface meltwater into crevasses, we find that no surface melt would reach the bed; instead, it would refreeze annually in crevasses at depths <500 m. The crevasse field downstream of the firn aquifer likely allows a large fraction of the aquifer water in our study area to reach the bed. Thus, future studies should consider the aquifer and crevasses as part of a common system. This system may uniquely affect ice-sheet dynamics by routing a large volume of water to the bed outside of the typical runoff period.

Analyzing the Deposition of Titanium Dioxide Nanoparticles at Model Rough Mineral Surfaces Using a Quartz Crystal Microbalance with Dissipation Monitoring

NASA Astrophysics Data System (ADS)

Li, Y.; Kananizadeh, N.; Rodenhausen, K. B.; Schubert, M.; Bartelt-Hunt, S.

2015-12-01

Titanium dioxide nanoparticles (nTiO2) is the most extensively manufactured engineered materials. nTiO2 from sunscreens was found to enter sediments after released into a lake. nTiO2 may also enter the subsurface via irrigation using effluents from wastewater treatment plants. Interaction of nTiO2 with soils and sediments will largely influence their fate, transport, and ecotoxicity. Measuring the interaction between nTiO2 and natural substrates (e.g. such as sands) is particularly challenging due to highly heterogeneous and rough natural sand surfaces. In this study, an engineered controllable rough surface known as three dimensional nanostructured sculptured columnar thin films (SCTFs) has been used to mimic surface roughness. SCTFs were fabricated by glancing angle deposition (GLAD), a physical vapor deposition technique facilitated by electron beam evaporation. Interaction between nTiO2 and SCTF coated surfaces was investigated using a quartz crystal microbalance with dissipation monitoring (QCM-D). In parallel, a Generalized Ellipsometry (GE) was coupled with the QCM-D to measure the deposition of nTiO2. We found that the typical QCM-D modeling approach, e.g. viscoelastic model, would largely overestimate the mass of deposited nTiO2, because the frequency drops due to particle deposition or water entrapment in rough areas were not differentiated. Here, we demonstrate a new approach to model QCM-D data for nTiO2 deposition on rough surfaces, which couples the viscoelastic model with a model of flow on the non-uniform surface.

Reducing nitrate loss in tile drainage water with cover crops and water-table management systems.

PubMed

Drury, C F; Tan, C S; Welacky, T W; Reynolds, W D; Zhang, T Q; Oloya, T O; McLaughlin, N B; Gaynor, J D

2014-03-01

Nitrate lost from agricultural soils is an economic cost to producers, an environmental concern when it enters rivers and lakes, and a health risk when it enters wells and aquifers used for drinking water. Planting a winter wheat cover crop (CC) and/or use of controlled tile drainage-subirrigation (CDS) may reduce losses of nitrate (NO) relative to no cover crop (NCC) and/or traditional unrestricted tile drainage (UTD). A 6-yr (1999-2005) corn-soybean study was conducted to determine the effectiveness of CC+CDS, CC+UTD, NCC+CDS, and NCC+UTD treatments for reducing NO loss. Flow volume and NO concentration in surface runoff and tile drainage were measured continuously, and CC reduced the 5-yr flow-weighted mean (FWM) NO concentration in tile drainage water by 21 to 38% and cumulative NO loss by 14 to 16% relative to NCC. Controlled tile drainage-subirrigation reduced FWM NO concentration by 15 to 33% and cumulative NO loss by 38 to 39% relative to UTD. When CC and CDS were combined, 5-yr cumulative FWM NO concentrations and loss in tile drainage were decreased by 47% (from 9.45 to 4.99 mg N L and from 102 to 53.6 kg N ha) relative to NCC+UTD. The reductions in runoff and concomitant increases in tile drainage under CC occurred primarily because of increases in near-surface soil hydraulic conductivity. Cover crops increased corn grain yields by 4 to 7% in 2004 increased 3-yr average soybean yields by 8 to 15%, whereas CDS did not affect corn or soybean yields over the 6 yr. The combined use of a cover crop and water-table management system was highly effective for reducing NO loss from cool, humid agricultural soils. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Estimation of selenium loads entering the south arm of Great Salt Lake, Utah, from May 2006 through March 2008

USGS Publications Warehouse

Naftz, David L.; Johnson, William P.; Freeman, Michael L.; Beisner, Kimberly; Diaz, Ximena; Cross, VeeAnn A.

2009-01-01

Discharge and water-quality data collected from six streamflow-gaging stations were used in combination with the LOADEST software to provide an estimate of total (dissolved + particulate) selenium (Se) load to the south arm of Great Salt Lake (GSL) from May 2006 through March 2008. Total estimated Se load to GSL during this time period was 2,370 kilograms (kg). The 12-month estimated Se load to GSL for May 1, 2006, to April 30, 2007, was 1,560 kg. During the 23-month monitoring period, inflows from the Kennecott Utah Copper Corporation (KUCC) Drain and Bear River outflow contributed equally to the largest proportion of total Se load to GSL, accounting for 49 percent of the total Se load. Five instantaneous discharge measurements at three sites along the railroad causeway indicate a consistent net loss of Se mass from the south arm to the north arm of GSL (mean = 2.4 kg/day, n = 5). Application of the average daily loss rate equates to annual Se loss rate to the north arm of 880 kg (56 percent of the annual Se input to the south arm). The majority of Se in water entering GSL is in the dissolved (less than 0.45 micron) state and ranges in concentration from 0.06 to 35.7 micrograms per liter (ug/L). Particulate Se concentration ranged from less than 0.05 to 2.5 ug/L. Except for the KUCC Drain streamflow-gaging station, dissolved (less than 0.45 um) inflow samples contain an average of 21 percent selenite (SeO32-) during two sampling events (May 2006 and 2007). Selenium concentration in water samples collected from four monitoring sites within GSL during May 2006 through August 2007 were used to understand how the cumulative Se load was being processed by various biogeochemical processes within the lake. On the basis of the Mann-Kendall test results, changes in dissolved Se concentration at the four monitoring sites indicate a statistically significant (90-percent confidence interval) upward trend in Se concentration over the 16-month monitoring period. Furthermore, the upward trend at three of the four GSL sites also was significant at the 95-percent confidence interval. Given the large amount of Se removal from GSL of greater than 1,900 kg/year by gaseous flux and permanent sedimentation, the observed increase in both dissolved (less than 0.45 micron) and total (dissolved + particulate) Se in the open-water monitoring sites indicates additional, unquantified source(s) of Se are contributing substantial masses of Se load to the south arm of GSL. Potential source(s) of this unmeasured Se load could include (1) Se loads entering GSL from unmeasured surface inflows; (2) ground-water discharge to GSL; (3) wind-blown dust that is deposited directly on the lake surface; (4) wet and dry atmospheric deposition falling directly on the lake surface; and (5) lake sediment pore-water diffusion into the overlying water column. Electrical resistivity surveys in the south part of GSL indicate areas of potential ground-water discharge to the open water of GSL and elevated (exceeding 10,000 ug/L) Se concentrations have been previously measured in ground water within 1.6 kilometers of the south shore of GSL.

2. CONFLUENCE POOL, DETAIL OF TUNNEL PORTAL WITH WATER ENTERING ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

2. CONFLUENCE POOL, DETAIL OF TUNNEL PORTAL WITH WATER ENTERING FROM SANTA ANA RIVER. VIEW TO NORTHEAST. - Santa Ana River Hydroelectric System, Bear Creek Diversion Dam & Confluence Pool, Redlands, San Bernardino County, CA

Radioactive pollution of the waters of the baltic sea during 1986

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lazarev, L.N.; Kuznetsov, Yu.V.; Gedeonov, L.I.

Results are presented from an investigation of radioactive pollution of the waters of the Baltic Sea during 1986. Inhomogeneities in the pollution of this area of water, due to varying density of atmospheric radioactive fallout, are detected. It is found that among the radionuclides entering the surface of the Baltic Sea in 1986 as a result of atmospheric transport, the main one in terms of radiation dose is cesium-137. Comparisons are made of the level of cesium-137 content in the waters of the Baltic Sea in 1986 and in preceding years. It is noted that even in the most pollutedmore » regions of the sea the cesium-137 content was 500 times less than the maximum allowable concentration (MAC) in the USSR for drinking water. The first results of the determination of plutonium-239 and 240 in the Baltic Sea are presented.« less

Application of physical adsorption thermodynamics to heterogeneous chemistry on polar stratospheric clouds

NASA Technical Reports Server (NTRS)

Elliott, Scott; Turco, Richard P.; Toon, Owen B.; Hamill, Patrick

1991-01-01

Laboratory isotherms for the binding of several nonheterogeneously active atmospheric gases and for HCl to water ice are translated into adsorptive equilibrium constants and surface enthalpies. Extrapolation to polar conditions through the Clausius Clapeyron relation yields coverage estimates below the percent level for N2, Ar, CO2, and CO, suggesting that the crystal faces of type II stratospheric cloud particles may be regarded as clean with respect to these species. For HCl, and perhaps HF and HNO3, estimates rise to several percent, and the adsorbed layer may offer acid or proton sources alternate to the bulk solid for heterogeneous reactions with stratospheric nitrates. Measurements are lacking for many key atmospheric molecules on water ice, and almost entirely for nitric acid trihydrate as substrate. Adsorptive equilibria enter into gas to particle mass flux descriptions, and the binding energy determines rates for desorption of, and encounter between, potential surface reactants.

Discrepancy between Snowmelt and Soil Infiltration

NASA Astrophysics Data System (ADS)

Fassnacht, S. R.

2017-12-01

A majority of snowmelt enters the soil and is either transmitted through or stored in the soil. Snowmelt has been estimated from the decrease in snow mass of a snow pillow and soil infiltration has been estimated from near surface TDR probes. Here, these data are from a set of Snow Telemetry (SNOTEL) stations across Colorado. While seasonal totals are similar, it is shown that there is a disconnect between the amount of water melted in a day and the increased daily volume of water measured in the near sub-surface. It is surmised that these differences are a function of the data collection methods, the infiltration rate, and possible lateral flow. An examination of daily infiltration volumes at depth shows a further disconnect, as it is likely that lateral flow complicates the measurements to a true three dimensional problem. The data are informative to illustrate the transmission of meltwater into the soil; methods for improvement are explored.

SURFACE WATER AND GROUND WATER QUALITY MONITORING FOR RESTORATION OF URBAN LAKES IN GREATER HYDERABAD, INDIA

NASA Astrophysics Data System (ADS)

Mohanty, A. K.

2009-12-01

SURFACE WATER AND GROUND WATER QUALITY MONITORING FOR RESTORATION OF URBAN LAKES IN GREATER HYDERABAD, INDIA A.K. Mohanty, K. Mahesh Kumar, B. A. Prakash and V.V.S. Gurunadha Rao Ecology and Environment Group National Geophysical Research Institute, (CSIR) Hyderabad - 500 606, India E-mail:atulyakumarmohanty@yahoo.com Abstract: Hyderabad Metropolitan Development Authority has taken up restoration of urban lakes around Hyderabad city under Green Hyderabad Environment Program. Restoration of Mir Alam Tank, Durgamcheruvu, Patel cheruvu, Pedda Cheruvu and Nallacheruvu lakes have been taken up under the second phase. There are of six lakes viz., RKPuramcheruvu, Nadimicheruvu (Safilguda), Bandacheruvu Patelcheruvu, Peddacheruvu, Nallacheruvu, in North East Musi Basin covering 38 sq km. Bimonthly monitoring of lake water quality for BOD, COD, Total Nitrogen, Total phosphorous has been carried out for two hydrological cycles during October 2002- October 2004 in all the five lakes at inlet channels and outlets. The sediments in the lake have been also assessed for nutrient status. The nutrient parameters have been used to assess eutrophic condition through computation of Trophic Status Index, which has indicated that all the above lakes under study are under hyper-eutrophic condition. The hydrogeological, geophysical, water quality and groundwater data base collected in two watersheds covering 4 lakes has been used to construct groundwater flow and mass transport models. The interaction of lake-water with groundwater has been computed for assessing the lake water budget combining with inflow and outflow measurements on streams entering and leaving the lakes. Individual lake water budget has been used for design of appropriate capacity of Sewage Treatment Plants (STPs) on the inlet channels of the lakes for maintaining Full Tank Level (FTL) in each lake. STPs are designed for tertiary treatment i.e. removal of nutrient load viz., Phosphates and Nitrates. Phosphates are removed through addition of Alum to the influent stream to the STPs whereas Nitrates reduction is achieved by sending the treated wastewater from the STP through a wetland before entering the lake. STP Capacity ranging from 2-10 MLD have been recommended depending on lake water budget of individual lake and considering surrounding urbanization. Sediment nutrient data has helped for deciding the need for dredging of lake bed for removal of phosphates. Key Words: Lake water budget, Eutrophication, Trophic Status Index, Urban Lakes Restoration

Data on metals (Zn, Al, Sr, and Co) and metalloid (As) concentration levels of ballast water in commercial ships entering Bushehr port, along the Persian Gulf.

PubMed

Soleimani, Farshid; Dobaradaran, Sina; Hayati, Abdolreza; Khorsand, Maryam; Keshtkar, Mozhgan

2016-12-01

In this article, we determined the concentration levels of metals including Zn, Al, Sr, and Co and metalloid of As of ballast water in commercial ships entering Bushehr port, along the Persian Gulf. Ballast water samples were taken from commercial ships entering Bushehr port from 34 ports around the world during 15 February and 25 August 2016. The concentration levels of metals and metalloid were determined by using a graphite furnace absorption spectrometer (AAS).

Risk assessment for drugs of abuse in the Dutch watercycle.

PubMed

van der Aa, Monique; Bijlsma, Lubertus; Emke, Erik; Dijkman, Ellen; van Nuijs, Alexander L N; van de Ven, Bianca; Hernández, Felix; Versteegh, Ans; de Voogt, Pim

2013-04-01

A screening campaign of drugs of abuse (DOA) and their relevant metabolites in the aqueous environment was performed in the Netherlands. The presence of DOA, together with the potential risks for the environment and the possible human exposure to these compounds through consumption of drinking water was investigated. Sewage water (influent and effluent), surface water of the rivers Rhine and Meuse, and drinking water (raw and finished) were analysed by four different laboratories using fully in-house validated methods for a total number of 34 DOA and metabolites. In this way, data reported for several compounds could also be confirmed by other laboratories, giving extra confidence to the results obtained in this study. In total 17 and 22 DOA were detected and quantified in influent and effluent sewage samples, respectively. The tranquilizers oxazepam and temazepam, and cocaine and its metabolite benzoylecgonine were found in high concentrations in sewage water. Nine compounds were possibly not efficiently removed during treatment and were detected in surface waters. The results indicated that substantial fractions of the total load of DOA and metabolites in the rivers Rhine and Meuse enter the Netherlands from abroad. For some compounds, loads appear to increase going downstream, which is caused by a contribution from Dutch sewage water effluents. As far as data are available, no environmental effects are expected of the measured DOA in surface waters. In raw water, three DOA were detected, whereas in only one finished drinking water out of the 17 tested, benzoylecgonine was identified, albeit at a concentration below the limit of quantification (<1 ng/L). Concentrations were well below the general signal value of 1 μg/L, which is specified for organic compounds of anthropogenic origin in the Dutch Drinking Water Act. Copyright © 2013 Elsevier Ltd. All rights reserved.

The Impact of the Extreme Amazonian Flood Season on the Incidence of Viral Gastroenteritis Cases.

PubMed

Vieira, Carmen Baur; de Abreu Corrêa, Adriana; de Jesus, Michele Silva; Luz, Sérgio Luiz Bessa; Wyn-Jones, Peter; Kay, David; Rocha, Mônica Simões; Miagostovich, Marize Pereira

2017-06-01

During the Amazonian flood season in 2012, the Negro River reached its highest level in 110 years, submerging residential and commercial areas which appeared associated with an elevation in the observed gastroenteritis cases in the city of Manaus. The aim of this study was to evaluate the microbiological water quality of the Negro River basin during this extreme flood to investigate this apparent association between the illness cases and the population exposed to the contaminated waters. Forty water samples were collected and analysed for classic and emerging enteric viruses. Human adenoviruses, group A rotaviruses and genogroup II noroviruses were detected in 100, 77.5 and 27.5% of the samples, respectively, in concentrations of 10 3 -10 6 GC/L. All samples were compliant with local bacteriological standards. HAdV2 and 41 and RVA G2, P[6], and P[8] were characterised. Astroviruses, sapoviruses, genogroup IV noroviruses, klasseviruses, bocaviruses and aichiviruses were not detected. Statistical analyses showed correlations between river stage level and reported gastroenteritis cases and, also, significant differences between virus concentrations during this extreme event when compared with normal dry seasons and previous flood seasons of the Negro River. These findings suggest an association between the extreme flood experienced and gastrointestinal cases in the affected areas providing circumstantial evidence of causality between the elevations in enteric viruses in surface waters and reported illness.

Specific conductance measurements in central and western New York streams - A retrospective characterization

USGS Publications Warehouse

Kappel, William M.; Sinclair, Gaylen J.; Reddy, James E.; Eckhardt, David A.; deVries, M. Peter; Phillips, Margaret E.

2012-01-01

U.S. Geological Survey (USGS) Data Rescue Program funds were used to recover data from paper records for 139 streamgages across central and western New York State; 6,133 different streamflow measurement forms, collected between 1970-80, contained field water-quality measurements. The water-quality data were entered, reviewed, and uploaded into the USGS National Water Information System. In total, 4,285 unique site visits were added to the database. The new values represent baseline water quality from which to measure change and will lead to a comparison of water-quality change over the last 40 years and into the future. Specific conductance was one of the measured properties and represents a simple way to determine if ambient inorganic water quality has been altered by anthropogenic (road salt runoff, wastewater discharges, or natural gas development) or natural sources. The objective of this report is to describe ambient specific conductance characteristics of surface water across the central and western part of New York. This report presents median specific conductance of stream discharge for the period 1970-80 and a description of the relation between specific conductance and concentrations of total dissolved solids (TDS) retrieved from the USGS National Water Information System (NWIS) database from 1955 to present. The data descriptions provide a baseline of surface-water specific conductance data that can used for comparison to current and future measurements in New York streams.

Absorption of water and lubricating oils into porous nylon

NASA Technical Reports Server (NTRS)

Bertrand, P. A.

1995-01-01

Oil and water absorption from air into sintered porous nylon can be described by infiltration into the pores of the material. This process can be modeled by a diffusion-like mechanism. For water absorption, we find a formal diffusion coefficient of 1.5 x 10(exp -4)sq cm/min when the nylon is initially dry. The diffusion coefficient is 4 x 10(exp -6)sq cm/min when the nylon is oil-impregnated prior to air exposure. In a 52% RH atmosphere, dry nylon absorbs 3% w/w water, and oil-impregnated nylon absorbs 0.6% w/w water. For oil absorption there are three steps: (1) surface absorption and infiltration into (2) larger and (3) smaller pores. Surface absorption is too fast to be measured in these experiments. The diffusion coefficient for the second step is 6 x 10(exp -4)sq cm/min for SRG-60 oil into dry nylon and 4 x 10(exp -4)sq cm/min for air-equilibrated nylon. The diffusion coefficient for the third step is about 1 x 10(exp -6)sq cm/min for both cases. The total amount of oil absorbed is 31% w/w. The interaction between water and nylon is not as strong as that between water and cotton-phenolic: oil can replace water, and only a small amount of water can enter previously oil-impregnated nylon.

Phosphorus cycling and partitioning in an oligotrophic Everglades wetland ecosystem: A radioisotope tracing study

USGS Publications Warehouse

Noe, G.B.; Scinto, L.J.; Taylor, J.; Childers, D.L.; Jones, R.D.

2003-01-01

1. Our goal was to quantify short-term phosphorus (P) partitioning and identify the ecosystem components important to P cycling in wetland ecosystems. To do this, we added P radiotracer to oligotrophic, P-limited Everglades marshes. 32PO4 was added to the water column in six 1-m2 enclosed mesocosms located in long-hydroperiod marshes of Shark River Slough, Everglades National Park. Ecosystem components were then repeatedly sampled over 18 days. 2. Water column particulates (>0.45 ??m) incorporated radiotracer within the first minute after dosing and stored 95-99% of total water column 32P activity throughout the study. Soluble (<0.45 ??m) 32P in the water column, in contrast, was always <5% of the 32P in surface water. Periphyton, both floating and attached to emergent macrophytes, had the highest specific activity of 32P (Bq g-131P) among the different ecosystem components. Fish and aquatic macroinvertebrates also had high affinity for P, whereas emergent macrophytes, soil and flocculent detrital organic matter (floc) had the lowest specific activities of radiotracer. 3. Within the calcareous, floating periphyton mats, 81% of the initial 32P uptake was associated with Ca, but most of this 32P entered and remained within the organic pool (Ca-associated = 14% of total) after 1 day. In the floc layer, 32P rapidly entered the microbial pool and the labile fraction was negligible for most of the study. 4. Budgeting of the radiotracer indicated that 32P moved from particulates in the water column to periphyton and floc and then to the floc and soil over the course of the 18 days incubations. Floc (35% of total) and soil (27%) dominated 32P storage after 18 days, with floating periphyton (12%) and surface water (10%) holding smaller proportions of total ecosystem 32P. 5. To summarise, oligotrophic Everglades marshes exhibited rapid uptake and retention of labile 32P. Components dominated by microbes appear to control short-term P cycling in this oligotrophic ecosystem.

OCCURRENCE OF ENTERIC VIRUSES IN WATERS

EPA Science Inventory

A number of different types of human enteric viruses cause waterborne outbreaks when individuals are exposed to contaminated drinking and recreational waters. Vaccination against poliovirus has virtually eliminated poliomyelitis from the planet, but other members of the enterovi...

DEVELOPMENT OF VIRAL INTERNAL CONTROLS FOR THE ASSESSMENT OF INHIBITOR REMOVAL FROM ENVIRONMENTAL WATER SAMPLES.

EPA Science Inventory

The presence of human enteric viruses in drinking water is of public health concern. It is therefore important to be able to reliably detect these viruses in contaminating water sources. Cell culture methods are time consuming and also not all enteric viruses can currently be p...

Ground-water contamination and legal controls in Michigan

USGS Publications Warehouse

Deutsch, Morris

1963-01-01

The great importance of the fresh ground-water resources of Michigan is evident because 90 percent of the rural and about 70 percent of the total population of the State exclusive of the Detroit metropolitan area are supplied from underground sources. The water-supply and public-health problems that have been caused by some cases of ground-water contamination in the State illustrate the necessity of protecting this vital resource.Manmade and natural contaminants, including many types of chemical and organic matter, have entered many of the numerous aquifers of the State. Aquifers have been contaminated by waste-laden liquids percolating from the surface or from the zone of aeration and by direct injection to the aquifer itself. Industrial and domestic wastes, septic tanks, leaking sewers, flood waters or other poor quality surface waters, mine waters, solids stored or spread at the surface, and even airborne wastes all have been sources of ground-water contamination in Michigan. In addition, naturally occurring saline waters have been induced into other aquifers by overpumping or unrestricted flow from artesian wells, possibly by dewatering operations, and by the deepening of surface stream channels. Vertical migration of saline waters through open holes from formations underlying various important aquifers also has spoiled some of the fresh ground waters in the State. In spite of the contamination that has occurred, however, the total amount of ground water that has been spoiled is only a small part of the total resource. Neither is the contamination so widespread as that of the surface streams of Michigan.Overall legal authority to control most types of ground-water contamination in the State has been assigned by the Michigan Legislature to the Water Resources Commission, although the Department of Conservation and the Health Department also exercise important water-pollution control functions. The Michigan Supreme Court, in an important case upholding the power of the Water Resources Commission to control pollution of ground water, in effect has introduced the doctrine of reasonable use into the law of the State. Excluding controls administered by the Department of Conservation on activities of the oil and gas industry, however, legal controls have not been used abate intrusion of natural saline waters into fresh-water aquifers in response to pumping and other manmade changes in the hydrologic regimen.

Radon (222Rn) in ground water of fractured rocks: A diffusion/ion exchange model

USGS Publications Warehouse

Wood, W.W.; Kraemer, T.F.; Shapiro, A.

2004-01-01

Ground waters from fractured igneous and high-grade sialic metamorphic rocks frequently have elevated activity of dissolved radon (222Rn). A chemically based model is proposed whereby radium (226Ra) from the decay of uranium (238U) diffuses through the primary porosity of the rock to the water-transmitting fracture where it is sorbed on weathering products. Sorption of 226Ra on the fracture surface maintains an activity gradient in the rock matrix, ensuring a continuous supply of 226Ra to fracture surfaces. As a result of the relatively long half-life of 226Ra (1601 years), significant activity can accumulate on fracture surfaces. The proximity of this sorbed 226Ra to the active ground water flow system allows its decay progeny 222Rn to enter directly into the water. Laboratory analyses of primary porosity and diffusion coefficients of the rock matrix, radon emanation, and ion exchange at fracture surfaces are consistent with the requirements of a diffusion/ion- exchange model. A dipole-brine injection/withdrawal experiment conducted between bedrock boreholes in the high-grade metamorphic and granite rocks at the Hubbard Brook Experimental Forest, Grafton County, New Hampshire, United States (42??56???N, 71??43???W) shows a large activity of 226Ra exchanged from fracture surfaces by a magnesium brine. The 226Ra activity removed by the exchange process is 34 times greater than that of 238U activity. These observations are consistent with the diffusion/ion-exchange model. Elutriate isotopic ratios of 223Ra/226Ra and 238U/226Ra are also consistent with the proposed chemically based diffusion/ion-exchange model.

Application of new point measurement device to quantify groundwater-surface water interactions.

PubMed

Cremeans, M M; Devlin, J F; McKnight, U S; Bjerg, P L

2018-04-01

The streambed point velocity probe (SBPVP) measures in situ groundwater velocities at the groundwater-surface water interface without reliance on hydraulic conductivity, porosity, or hydraulic gradient information. The tool operates on the basis of a mini-tracer test that occurs on the probe surface. The SBPVP was used in a meander of the Grindsted Å (stream), Denmark, to determine the distribution of flow through the streambed. These data were used to calculate the contaminant mass discharge of chlorinated ethenes into the stream. SBPVP data were compared with velocities estimated from hydraulic head and temperature gradient data collected at similar scales. Spatial relationships of water flow through the streambed were found to be similar by all three methods, and indicated a heterogeneous pattern of groundwater-surface water exchange. The magnitudes of estimated flow varied to a greater degree. It was found that pollutants enter the stream in localized regions of high flow which do not always correspond to the locations of highest pollutant concentration. The results show the combined influence of flow and concentration on contaminant discharge and illustrate the advantages of adopting a flux-based approach to risk assessment at the groundwater-surface water interface. Chlorinated ethene mass discharges, expressed in PCE equivalents, were determined to be up to 444 kg/yr (with SBPVP data) which compared well with independent estimates of mass discharge up to 438 kg/yr (with mini-piezometer data from the streambed) and up to 372 kg/yr crossing a control plane on the streambank (as determined in a previous, independent study). Copyright © 2018 Elsevier B.V. All rights reserved.

Comparative Persistence of Subgroups of F-Specific RNA Phages in River Water

PubMed Central

Yang, Yongheng

2013-01-01

F-specific (F+) RNA phages are widely used as indicators for the presence of fecal contamination and/or enteric viruses in water, and identifying subgroups of F+ RNA phages provides an approach for microbial source tracking. Different survival characteristics of the F+ RNA phage subgroups result in a misinterpretation of their original proportion in water, thus giving misleading information when they are used for microbial source tracking. This study investigated the comparative persistence of subgroups of F+ RNA phages in river water under different conditions. Results suggested that temperature and pH are the major factors affecting the persistence of F+ RNA phages in river water, and organic substances promote phage survival. The comparative persistence patterns of subgroups of F+ RNA phages varied and may bias extrapolation of their initial proportions in surface water. Thus, the characteristics of water should be taken into consideration and the results should be carefully interpreted when F+ RNA phages are used for microbial source tracking. PMID:23686274

Identification of bacteria in drinking and purified water during the monitoring of a typical water purification system

PubMed Central

Penna, Vessoni Thereza Christina; Martins, Silva Alzira Maria; Mazzola, Priscila Gava

2002-01-01

Background A typical purification system that provides purified water which meets ionic and organic chemical standards, must be protected from microbial proliferation to minimize cross-contamination for use in cleaning and preparations in pharmaceutical industries and in health environments. Methodology Samples of water were taken directly from the public distribution water tank at twelve different stages of a typical purification system were analyzed for the identification of isolated bacteria. Two miniature kits were used: (i) identification system (api 20 NE, Bio-Mérieux) for non-enteric and non-fermenting gram-negative rods; and (ii) identification system (BBL crystal, Becton and Dickson) for enteric and non-fermenting gram-negative rods. The efficiency of the chemical sanitizers used in the stages of the system, over the isolated and identified bacteria in the sampling water, was evaluated by the minimum inhibitory concentration (MIC) method. Results The 78 isolated colonies were identified as the following bacteria genera: Pseudomonas, Flavobacterium and Acinetobacter. According to the miniature kits used in the identification, there was a prevalence of isolation of P. aeruginosa 32.05%, P. picketti (Ralstonia picketti) 23.08%, P. vesiculares 12.82%,P. diminuta 11.54%, F. aureum 6.42%, P. fluorescens 5.13%, A. lwoffi 2.56%, P. putida 2.56%, P. alcaligenes 1.28%, P. paucimobilis 1.28%, and F. multivorum 1.28%. Conclusions We found that research was required for the identification of gram-negative non-fermenting bacteria, which were isolated from drinking water and water purification systems, since Pseudomonas genera represents opportunistic pathogens which disperse and adhere easily to surfaces, forming a biofilm which interferes with the cleaning and disinfection procedures in hospital and industrial environments. PMID:12182763

Nitrogen Loads in Groundwater Entering Back Bays and Ocean from Fire Island National Seashore, Long Island, New York

USGS Publications Warehouse

Schubert, Christopher E.; deVries, M. Peter; Finch, Anne J.

2010-01-01

Fire Island is a barrier island that lies south of central Long Island, N.Y. It is about 60 km (37 mi) long and 0.5 km (1/4 mi) wide and is bounded by the Great South Bay, Narrow Bay, and Moriches Bay estuaries to the north; by the Atlantic Ocean to the south; by Fire Island Inlet to the west; and by Moriches Inlet to the east (fig. 1). Fire Island National Seashore (FIIS) encompasses a 42-km (26-mi) length of Fire Island that is bordered by Robert Moses State Park to the west and Smith Point County Park to the east (fig. 2). Interspersed throughout FIIS are 17 residential beach communities that together contain about 4,100 homes. The barrier island's summer population increases 50-fold through the arrival of summer residents and vacationers. The National Park Service (NPS) has established several facilities on the island to accommodate visitors to FIIS. About 2.2 million people visit at least one of the 17 communities and (or) Smith Point County Park, the waterways surrounding Fire Island, or a FIIS facility annually (National Park Service, 2007). Combined visitation on a peak-season weekend day can be as high as 100,000 (National Park Service, 2002). Most homes and businesses in the 17 barrier-island communities discharge untreated wastewater directly to the shallow (water-table) aquifer through private septic systems and cesspools; the NPS facilities discharge wastewater to this aquifer through leach fields and cesspools. (The community of Ocean Beach (fig. 2) has a treatment plant that discharges to tidewater.) Contaminants in sewage entering the shallow groundwater move through the flow system and are ultimately discharged to adjacent marine surface waters, where they can pose a threat to coastal habitats. A contaminant of major concern is nitrogen, which is derived from fertilizers and human waste. The continuous inflow of nitrogen to surface-water bodies can lead to increased production of phytoplankton and macroalgae, which in turn can cause oxygen depletion, decreases in size of estuarine fish and shellfish communities, and loss of submerged seagrass habitat through light limitation (Valiela and others, 1992). The FIIS boundary extends roughly 1.2 km (0.8 mi) into the back-barrier estuaries of Great South Bay, Narrow Bay, and Moriches Bay (fig. 1). Within this estuarine zone are extensive areas of seagrass, shellfish, and finfish habitat, as well as intense recreational activity (Bokuniewicz and others, 1993). Management strategies for protection of these habitats require data on (1) concentrations and movement of nutrients and other human-derived contaminants that enter the groundwater system from on-site septic systems, and (2) aquifer characteristics and groundwater flow patterns. These data can then be used in three-dimensional flow models of the shallow aquifer system to predict the rates of groundwater discharge to the marine surface waters that bound Fire Island and the concentrations of nitrogen entering these water bodies from the aquifer's discharge zones. In 2004, the U.S. Geological Survey (USGS), in cooperation with the NPS, began a 3-year investigation to (1) measure groundwater levels within four local study areas at FIIS, (2) collect groundwater samples from these areas for nutrient (nitrogen) analysis, (3) develop a three-dimensional model of the hydrologic system and adjacent saltwater bodies for groundwater-flow delineation and particle tracking, and (4) apply the results of groundwater-discharge simulations to calculate the annual nitrogen loads in these discharges, particularly those entering Great South Bay, which together with the other back bays receives an estimated 80 percent of the total groundwater discharge from Fire Island. The four areas on which the investigation focused were the communities of Kismet and Robbins Rest, the NPS Visitor Center at Watch Hill, and the undeveloped Otis Pike Fire Island High Dune Wilderness (shown in panels A, B, C, and D in fig. 2); these were

Do wastewater treatment plants act as a potential point source of microplastics? Preliminary study in the coastal Gulf of Finland, Baltic Sea.

PubMed

Talvitie, Julia; Heinonen, Mari; Pääkkönen, Jari-Pekka; Vahtera, Emil; Mikola, Anna; Setälä, Outi; Vahala, Riku

2015-01-01

This study on the removal of microplastics during different wastewater treatment unit processes was carried out at Viikinmäki wastewater treatment plant (WWTP). The amount of microplastics in the influent was high, but it decreased significantly during the treatment process. The major part of the fibres were removed already in primary sedimentation whereas synthetic particles settled mostly in secondary sedimentation. Biological filtration further improved the removal. A proportion of the microplastic load also passed the treatment and was found in the effluent, entering the receiving water body. After the treatment process, an average of 4.9 (±1.4) fibres and 8.6 (±2.5) particles were found per litre of wastewater. The total textile fibre concentration in the samples collected from the surface waters in the Helsinki archipelago varied between 0.01 and 0.65 fibres per litre, while the synthetic particle concentration varied between 0.5 and 9.4 particles per litre. The average fibre concentration was 25 times higher and the particle concentration was three times higher in the effluent compared to the receiving body of water. This indicates that WWTPs may operate as a route for microplastics entering the sea.

Spiraling pathways of global deep waters to the surface of the Southern Ocean.

PubMed

Tamsitt, Veronica; Drake, Henri F; Morrison, Adele K; Talley, Lynne D; Dufour, Carolina O; Gray, Alison R; Griffies, Stephen M; Mazloff, Matthew R; Sarmiento, Jorge L; Wang, Jinbo; Weijer, Wilbert

2017-08-02

Upwelling of global deep waters to the sea surface in the Southern Ocean closes the global overturning circulation and is fundamentally important for oceanic uptake of carbon and heat, nutrient resupply for sustaining oceanic biological production, and the melt rate of ice shelves. However, the exact pathways and role of topography in Southern Ocean upwelling remain largely unknown. Here we show detailed upwelling pathways in three dimensions, using hydrographic observations and particle tracking in high-resolution models. The analysis reveals that the northern-sourced deep waters enter the Antarctic Circumpolar Current via southward flow along the boundaries of the three ocean basins, before spiraling southeastward and upward through the Antarctic Circumpolar Current. Upwelling is greatly enhanced at five major topographic features, associated with vigorous mesoscale eddy activity. Deep water reaches the upper ocean predominantly south of the Antarctic Circumpolar Current, with a spatially nonuniform distribution. The timescale for half of the deep water to upwell from 30° S to the mixed layer is ~60-90 years.Deep waters of the Atlantic, Pacific and Indian Oceans upwell in the Southern Oceanbut the exact pathways are not fully characterized. Here the authors present a three dimensional view showing a spiralling southward path, with enhanced upwelling by eddy-transport at topographic hotspots.

Freshwater sediments and sludges: two important terrestrial sinks for emissions from damaged NPPs

NASA Astrophysics Data System (ADS)

Fischer, Helmut W.; Evangelia Souti, Maria; Ulbrich, Susanne; Hormann, Volker

2013-04-01

Surface deposition of radionuclides released from the damaged Fukushima NPPs is well documented and emissions to the Pacific Ocean and their distribution with time and space are also subject to monitoring and research. In both cases, solid matter (soil and sea sediment, respectively) acts as a sink for radioisotopes after their transport through air and water. The possible hazards from direct irradiation of workers and public and from entry of radionuclides into food chains are well recognized. Apart from direct deposition onto soil, plants, building roofs etc., aerosols and contaminated rainwater will reach surface waters, leading to long-term deposition in freshwater sediments (and possibly to interim contamination of drinking water). In populated and industrial areas, drained rainwater will enter the wastewater collection and treatment chain if a combined rain and wastewater sewer is used. Depending on the processes in the wastewater treatment plant and chemical element and speciation, the isotopes will either concentrate in treatment sludge or be released with the effluent to rivers and lakes and their sediments. The mentioned media may act as long-term storage for radioisotopes when disposed of properly, but can also contribute to direct irradiation of workers or public, lead to continuous releases to the environment and possibly enter the food chain in the same way as soil and sea sediments. It appears therefore essential to monitor these environmental compartments as well. However, very few data on Fukushima-related radioisotope concentration in sludges and freshwater sediments have been published to date. We will therefore compare data for regional surface deposition and related concentrations in surface water, river sediments and sewage sludge obtained in Europe during 1986 to published data from Japan in 2011 for the most important common short-lived (I-131, half-life = 8.02 d) and long-lived (Cs-137, half-life = 30.17 yr) isotopes. As in central Europe the Chernobyl fallout was not accompanied by other catastrophic events, well documented time series of data exist. It might become possible to estimate sludge and sediment isotope concentrations in Japan by proportionality considerations and by application of transport models when no or insufficient current data exist. Additional insight into transport processes can be obtained from ongoing investigations of medically used I-131 in wastewater and rivers. The results might help in identification and remediation of possibly emerging hazards.

Evaluation of an Infiltration Model with Microchannels

NASA Astrophysics Data System (ADS)

Garcia-Serrana, M.; Gulliver, J. S.; Nieber, J. L.

2015-12-01

This research goal is to develop and demonstrate the means by which roadside drainage ditches and filter strips can be assigned the appropriate volume reduction credits by infiltration. These vegetated surfaces convey stormwater, infiltrate runoff, and filter and/or settle solids, and are often placed along roads and other impermeable surfaces. Infiltration rates are typically calculated by assuming that water flows as sheet flow over the slope. However, for most intensities water flow occurs in narrow and shallow micro-channels and concentrates in depressions. This channelization reduces the fraction of the soil surface covered with the water coming from the road. The non-uniform distribution of water along a hillslope directly affects infiltration. First, laboratory and field experiments have been conducted to characterize the spatial pattern of flow for stormwater runoff entering onto the surface of a sloped surface in a drainage ditch. In the laboratory experiments different micro-topographies were tested over bare sandy loam soil: a smooth surface, and three and five parallel rills. All the surfaces experienced erosion; the initially smooth surface developed a system of channels over time that increased runoff generation. On average, the initially smooth surfaces infiltrated 10% more volume than the initially rilled surfaces. The field experiments were performed in the side slope of established roadside drainage ditches. Three rates of runoff from a road surface into the swale slope were tested, representing runoff from 1, 2, and 10-year storm events. The average percentage of input runoff water infiltrated in the 32 experiments was 67%, with a 21% standard deviation. Multiple measurements of saturated hydraulic conductivity were conducted to account for its spatial variability. Second, a rate-based coupled infiltration and overland model has been designed that calculates stormwater infiltration efficiency of swales. The Green-Ampt-Mein-Larson assumptions were implemented to calculate infiltration along with a kinematic wave model for overland flow that accounts for short-circuiting of flow. Additionally, a sensitivity analysis on the parameters implemented in the model has been performed. Finally, the field experiments results have been used to quantify the validity of the coupled model.

The Longevity of Water Ice on Ganymedes and Europas around Migrated Giant Planets

NASA Astrophysics Data System (ADS)

Lehmer, Owen R.; Catling, David C.; Zahnle, Kevin J.

2017-04-01

The gas giant planets in the Solar System have a retinue of icy moons, and we expect giant exoplanets to have similar satellite systems. If a Jupiter-like planet were to migrate toward its parent star the icy moons orbiting it would evaporate, creating atmospheres and possible habitable surface oceans. Here, we examine how long the surface ice and possible oceans would last before being hydrodynamically lost to space. The hydrodynamic loss rate from the moons is determined, in large part, by the stellar flux available for absorption, which increases as the giant planet and icy moons migrate closer to the star. At some planet-star distance the stellar flux incident on the icy moons becomes so great that they enter a runaway greenhouse state. This runaway greenhouse state rapidly transfers all available surface water to the atmosphere as vapor, where it is easily lost from the small moons. However, for icy moons of Ganymede’s size around a Sun-like star we found that surface water (either ice or liquid) can persist indefinitely outside the runaway greenhouse orbital distance. In contrast, the surface water on smaller moons of Europa’s size will only persist on timescales greater than 1 Gyr at distances ranging 1.49-0.74 au around a Sun-like star for Bond albedos of 0.2 and 0.8, where the lower albedo becomes relevant if ice melts. Consequently, small moons can lose their icy shells, which would create a torus of H atoms around their host planet that might be detectable in future observations.

The Longevity of Water Ice on Ganymedes and Europas around Migrated Giant Planets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lehmer, Owen R.; Catling, David C.; Zahnle, Kevin J., E-mail: olehmer@gmail.com

The gas giant planets in the Solar System have a retinue of icy moons, and we expect giant exoplanets to have similar satellite systems. If a Jupiter-like planet were to migrate toward its parent star the icy moons orbiting it would evaporate, creating atmospheres and possible habitable surface oceans. Here, we examine how long the surface ice and possible oceans would last before being hydrodynamically lost to space. The hydrodynamic loss rate from the moons is determined, in large part, by the stellar flux available for absorption, which increases as the giant planet and icy moons migrate closer to themore » star. At some planet–star distance the stellar flux incident on the icy moons becomes so great that they enter a runaway greenhouse state. This runaway greenhouse state rapidly transfers all available surface water to the atmosphere as vapor, where it is easily lost from the small moons. However, for icy moons of Ganymede’s size around a Sun-like star we found that surface water (either ice or liquid) can persist indefinitely outside the runaway greenhouse orbital distance. In contrast, the surface water on smaller moons of Europa’s size will only persist on timescales greater than 1 Gyr at distances ranging 1.49–0.74 au around a Sun-like star for Bond albedos of 0.2 and 0.8, where the lower albedo becomes relevant if ice melts. Consequently, small moons can lose their icy shells, which would create a torus of H atoms around their host planet that might be detectable in future observations.« less

Viruses in non-disinfected drinking water from municipal wells are related to community rates of acute gastrointestinal illness

USDA-ARS?s Scientific Manuscript database

Groundwater supplies for drinking water are frequently contaminated with low-levels of human enteric virus genomes, yet evidence for waterborne disease transmission is lacking. We related qPCR-measured enteric viruses in the tap water of 14 non-chlorinating communities in the U.S. to acute gastroint...

Water Mass Classification on a Highly Variable Arctic Shelf Region: Origin of Laptev Sea Water Masses and Implications for the Nutrient Budget

NASA Astrophysics Data System (ADS)

Bauch, D.; Cherniavskaia, E.

2018-03-01

Large gradients and inter annual variations on the Laptev Sea shelf prevent the use of uniform property ranges for a classification of major water masses. The central Laptev Sea is dominated by predominantly marine waters, locally formed polynya waters and riverine summer surface waters. Marine waters enter the central Laptev Sea from the northwestern Laptev Sea shelf and originate from the Kara Sea or the Arctic Ocean halocline. Local polynya waters are formed in the Laptev Sea coastal polynyas. Riverine summer surface waters are formed from Lena river discharge and local melt. We use a principal component analysis (PCA) in order to assess the distribution and importance of water masses within the Laptev Sea. This mathematical method is applied to hydro-chemical summer data sets from the Laptev Sea from five years and allows to define water types based on objective and statistically significant criteria. We argue that the PCA-derived water types are consistent with the Laptev Sea hydrography and indeed represent the major water masses on the central Laptev Sea shelf. Budgets estimated for the thus defined major Laptev Sea water masses indicate that freshwater inflow from the western Laptev Sea is about half or in the same order of magnitude as freshwater stored in locally formed polynya waters. Imported water dominates the nutrient budget in the central Laptev Sea; and only in years with enhanced local polynya activity is the nutrient budget of the locally formed water in the same order as imported nutrients.

1. WATER ENTERING CONFLUENCE POOL FROM BEAR CREEK AT LEFT, ...

Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

1. WATER ENTERING CONFLUENCE POOL FROM BEAR CREEK AT LEFT, AND FROM SANTA ANA RIVER THROUGH TUNNEL #0 AT RIGHT. VIEW TO NORTHEAST. - Santa Ana River Hydroelectric System, Bear Creek Diversion Dam & Confluence Pool, Redlands, San Bernardino County, CA

Groundwater monitoring system

DOEpatents

Ames, Kenneth R.; Doesburg, James M.; Eschbach, Eugene A.; Kelley, Roy C.; Myers, David A.

1987-01-01

A groundwater monitoring system includes a bore, a well casing within and spaced from the bore, and a pump within the casing. A water impermeable seal between the bore and the well casing prevents surface contamination from entering the pump. Above the ground surface is a removable operating means which is connected to the pump piston by a flexible cord. A protective casing extends above ground and has a removable cover. After a groundwater sample has been taken, the cord is disconnected from the operating means. The operating means is removed for taking away, the cord is placed within the protective casing, and the cover closed and locked. The system is thus protected from contamination, as well as from damage by accident or vandalism.

Settling and survival profile of enteric pathogens in the swine effluent for water reuse purpose.

PubMed

Fongaro, G; Kunz, A; Magri, M E; Schissi, C D; Viancelli, A; Philippi, L S; Barardi, C R M

2016-11-01

The present study evaluated the pathogens persistence and settling profile in swine effluent. We determined the enteric pathogens settling characteristics, their survival and inactivation profile in swine effluent (for water reuse purpose) and in sludge (generated after aerobic treatment - during secondary settling process). The study was performed in laboratorial-scale and in full-scale (manure treatment plant). Enteric viruses and enteric bacteria were used as biomarkers. Results showed that these enteric pathogens were significantly reduced from swine effluent during secondary settling process, and enteric viruses removal was correlated with the suspended solids decantation. The design of secondary settlers can be adapted to improve pathogens removal, by diminishing the solids loading rate per area and time, ending in higher hydraulic retention times. Copyright © 2016 Elsevier GmbH. All rights reserved.

Optical Characterization and Bioavailability of Dissolved Organic Matter of Leaf Leachates from Restored and Forested Delmarva Bay Catchments

NASA Astrophysics Data System (ADS)

Reed, E.; Armstrong, A.

2016-12-01

The optical properties and lability of fresh leaf and litter leachates obtained from Delmarva wetlands were analyzed to gain a further understanding of the carbon inputs and outputs of that wetland system. Carbon entering the wetland system may be digested by microbes and then given off as either carbon dioxide or methane, both of which enter the atmosphere as greenhouse gases. Delmarva Bays are often considered geographically isolated and only have surface water present in certain times of year. The vegetation around the wetlands are assumed to be a major input of the dissolved organic matter (DOM) in the wetland surface water. An understanding of the sources and lability of wetland water DOM can lead to further insight into the connections between vegetation, wetland management, and carbon cycling. Two paired wetland sites were sampled in this study, each included a forested catchment and a prior-converted agricultural wetland that had undergone hydrological ecosystem restoration. Leaf samples of Liquidambar styraciflua, Acer rubrum, Nyssa sylvatica, Polygonum, and Typha were taken directly from the living plant or from surrounding ground as litter. Spectral properties of the leachates were determined from fluorescence and absorbance, including PARAFAC components, fluorescence index (FI), humification index (HI), and the specific ultraviolet absorbance (SUVA). Leachates were also incubated with microbes taken from Tuckahoe Creek, a stream to which all sampled sites eventually drain, to determine the bioavailability of the carbon. There were measurable differences found between samples obtained from leaves and litter, as well as a difference between the herbaceous and tree samples. The results obtained from this study can help create more accurate models of how carbon cycles through these wetlands, both in forested and restored environments.

Concentration data for anthropogenic organic compounds in groundwater, surface water, and finished water of selected community water systems in the United States, 2002-10

USGS Publications Warehouse

Carter, Janet M.; Kingsbury, James A.; Hopple, Jessica A.; Delzer, Gregory C.

2010-01-01

The National Water-Quality Assessment Program of the U.S. Geological Survey began implementing Source Water-Quality Assessments (SWQAs) in 2001 that focus on characterizing the quality of source water and finished water of aquifers and major rivers used by some of the larger community water systems in the United States. As used in SWQA studies, source water is the raw (ambient) water collected at the supply well before water treatment (for groundwater) or the raw (ambient) water collected from the river near the intake (for surface water), and finished water is the water that has been treated and is ready to be delivered to consumers. Finished-water samples are collected before the water enters the distribution system. The primary objective of SWQAs is to determine the occurrence of more than 250 anthropogenic organic compounds in source water used by community water systems, many of which currently are unregulated in drinking water by the U.S. Environmental Protection Agency. A secondary objective is to understand recurrence patterns in source water and determine if these patterns also occur in finished water before distribution. SWQA studies were conducted in two phases for most studies completed by 2005, and in one phase for most studies completed since 2005. Analytical results are reported for a total of 295 different anthropogenic organic compounds monitored in source-water and finished-water samples collected during 2002-10. The 295 compounds were classified according to the following 13 primary use or source groups: (1) disinfection by-products; (2) fumigant-related compounds; (3) fungicides; (4) gasoline hydrocarbons, oxygenates, and oxygenate degradates; (5) herbicides and herbicide degradates; (6) insecticides and insecticide degradates; (7) manufacturing additives; (8) organic synthesis compounds; (9) pavement- and combustion-derived compounds; (10) personal-care and domestic-use products; (11) plant- or animal-derived biochemicals; (12) refrigerants and propellants; and (13) solvents. This report presents the analytical results of source- water samples from 448 community water system wells and 21 surface-water sites. This report also presents the analytical results of finished-water samples from 285 wells and 20 surface-water sites from community water systems. Results of quality-assurance/quality-control samples also are presented including data for equipment blanks, field blanks, source solution blanks, and replicate samples.

Occurrence of Mycobacteria in Water Treatment Lines and in Water Distribution Systems

PubMed Central

Le Dantec, Corinne; Duguet, Jean-Pierre; Montiel, Antoine; Dumoutier, Nadine; Dubrou, Sylvie; Vincent, Véronique

2002-01-01

The frequency of recovery of atypical mycobacteria was estimated in two treatment plants providing drinking water to Paris, France, at some intermediate stages of treatment. The two plants use two different filtration processes, rapid and slow sand filtration. Our results suggest that slow sand filtration is more efficient for removing mycobacteria than rapid sand filtration. In addition, our results show that mycobacteria can colonize and grow on granular activated carbon and are able to enter distribution systems. We also investigated the frequency of recovery of mycobacteria in the water distribution system of Paris (outside buildings). The mycobacterial species isolated from the Paris drinking water distribution system are different from those isolated from the water leaving the treatment plants. Saprophytic mycobacteria (present in 41.3% of positive samples), potentially pathogenic mycobacteria (16.3%), and unidentifiable mycobacteria (54.8%) were isolated from 12 sites within the Paris water distribution system. Mycobacterium gordonae was preferentially recovered from treated surface water, whereas Mycobacterium nonchromogenicum was preferentially recovered from groundwater. No significant correlations were found among the presence of mycobacteria, the origin of water, and water temperature. PMID:12406720

An introduction to food and waterborne viruses: diseases, transmission, outbreaks, detection and control

USDA-ARS?s Scientific Manuscript database

Enteric viruses are the number one cause of foodborne illness throughout the world. In addition to foods, contaminated drinking water is another major cause of enteric viral illness. Among the enteric viruses are the noroviruses, hepatitis A and E viruses, enteric adenoviruses, rotavirus, and astro...

Does Personalized Water and Hand Quality Information Affect Attitudes, Behavior, and Health in Dar es Salaam, Tanzania?

NASA Astrophysics Data System (ADS)

Davis, J.; Pickering, A.; Horak, H.; Boehm, A.

2008-12-01

Tanzania (TZ) has one of the highest rates of child mortality due to enteric disease in the world. NGOs and local agencies have introduced numerous technologies (e.g., chlorine tablets, borewells) to increase the quantity and quality of water in Dar es Salaam, the capital of Tanzania, in hopes of reducing morbidity and mortality of waterborne disease. The objective of the present study is to determine if providing personalized information about water quality and hand surface quality, as determined by concentrations of enterococci and E. coli, results in improved health and water quality in households. A cohort study was completed in June-September 2008 in 3 communities ranging from urban to per-urban in Dar es Salaam, Tanzania to achieve our objective. The study consisted of 4 cohorts that were visited 4 times over the 3 month study. One cohort received no information about water and hand quality until the end of the summer, while the other groups received either just information on hand surface quality, just information on water quality, and information on both hand surface and water quality after the first (baseline) household visit. We report concentrations of enterococci and E. coli in water sources (surface waters and bore wells), water stored in households, and environmental waters were children and adults swim and bathe. In addition, we report concentrations of enterococci and E. coli on hands of caregivers and children in households. Preliminary results of surveys on health and perceptions of water quality and illness from the households are provided. Ongoing work will integrate the microbiological and sociological data sets to determine if personalized information interventions resulted in changes in health, water quality in the household, or perceptions of water quality, quantity and relation to human health. Future work will analyze DNA samples from hands and water for human-specific Bacteroides bacteria which are only present in human feces. Our study has the potential to provide empirical evidence to promote large scale monitoring and education campaigns in Africa to improve health and reduce the burden of waterborne disease.

Ground-water flow in the shallow aquifer system at the Naval Weapons Station Yorktown, Virginia

USGS Publications Warehouse

Smith, Barry S.

2001-01-01

The Environmental Directorate of the Naval Weapons Station Yorktown, Virginia, is concerned about possible contamination of ground water at the Station. Ground water at the Station flows through a shallow system of layered aquifers and leaky confining units. The units of the shallow aquifer system are the Columbia aquifer, the Cornwallis Cave confining unit, the Cornwallis Cave aquifer, the Yorktown confining unit, and the Yorktown-Eastover aquifer. The Eastover-Calvert confining unit separates the shallow aquifer system from deeper confined aquifers beneath the Station. A three-dimensional, finite-difference, ground-water flow model was used to simulate steady-state ground-water flow of the shallow aquifer system in and around the Station. The model simulated ground-water flow from the peninsular drainage divide that runs across the Lackey Plain near the southern end of the Station north to King Creek and the York River and south to Skiffes Creek and the James River. The model was calibrated by minimizing the root mean square error between 4 7 measured and corresponding simulated water levels. The calibrated model was used to determine the ground-water budget and general directions of ground-water flow. A particle-tracking routine was used with the calibrated model to estimate groundwater flow paths, flow rates, and traveltimes from selected sites at the Station. Simulated ground-water flow velocities of the Station-area model were small beneath the interstream areas of the Lackey Plain and Croaker Flat, but increased outward toward the streams and rivers where the hydraulic gradients are larger. If contaminants from the land surface entered the water table at or near the interstream areas of the Station, where hydraulic gradients are smaller, they would migrate more slowly than if they entered closer to the streams or the shores of the rivers where gradients commonly are larger. The ground-water flow simulations indicate that some ground water leaks downward from the water table to the Yorktown confining unit and, where the confining unit is absent, to the Yorktown-Eastover aquifer. The velocities of advective-driven contaminants would decrease considerably when entering the Yorktown confining unit because the hydraulic conductivity of the confining unit is small compared to that of the aquifers. Any contaminants that moved with advective ground-water flow near the groundwater divide of the Lackey Plain would move relatively slowly because the hydraulic gradients are small there. The direction in which the contaminants would move, however, would be determined by precisely where the contaminants entered the water table. The model was not designed to accurately simulate ground-water flow paths through local karst features. Beneath Croaker Flat, ground water flows downward through the Columbia aquifer and the Yorktown confining unit into the Yorktown-Eastover aquifer. Analyses of the movement of simulated particles from two adjacent sites at Croaker Flat indicated that ground-water flow paths were similar at first but diverged and discharged to different tributaries of Indian Field Creek or to the York River. These simulations indicate that complex and possibly divergent flow paths and traveltimes are possible at the Station. Although the Station-area model is not detailed enough to simulate ground-water flow at the scales commonly used to track and remediate contaminants at specific sites, general concepts about possible contaminant migration at the Station can be inferred from the simulations.

Using Sealed Wells to Measure Water Levels Beneath Streams and Floodplains.

PubMed

Noorduijn, Saskia L; Cook, Peter G; Wood, Cameron; White, Nick

2015-01-01

The design of wells beneath streams and floodplains has often employed with tall standpipes to prevent incursion of surface water into the well during flood events. Here, an approach has been presented to minimise the infrastructure demands in these environments by sealing the well top (e.g., prevent water entering the well) and monitor the total pressure in the water column using an absolute (non-vented) pressure transducer. The sealed well design was tested using a laboratory experiment where the total pressure responses were monitored in both an unsealed and sealed well, while the water level was varied. It is observed that, whether the well is sealed or not, the total pressure at a given depth in the aquifer will be equal to that within the well. This indicates that the sealed well design is a viable alternative to tall standpipes and also facilitates installation of wells beneath streams and floodplains. © 2015, National Ground Water Association.

Cryptosporidium species in Australian wildlife and domestic animals.

PubMed

Ryan, Una; Power, Michelle

2012-11-01

Cryptosporidium is an important enteric parasite that is transmitted via the fecal-oral route, water and food. Humans, wildlife and domestic livestock all potentially contribute Cryptosporidium to surface waters. Most species of Cryptosporidium are morphologically indistinguishable and can only be identified using molecular tools. Over 24 species have been identified and of these, 7 Cryptosporidium species/genotypes are responsible for most human cryptosporidiosis cases. In Australia, relatively few genotyping studies have been conducted. Six Cryptosporidium species (C. hominis, C. parvum, C. meleagridis, C. fayeri, C. andersoni and C. bovis) have been identified in humans in Australia. However, little is known about the contribution of animal hosts to human pathogenic strains of Cryptosporidium in drinking water catchments. In this review, we focus on the available genotyping data for native, feral and domestic animals inhabiting drinking water catchments in Australia to provide an improved understanding of the public health implications and to identify key research gaps.

Ocean thermal plant

NASA Technical Reports Server (NTRS)

Owens, L. J. (Inventor)

1978-01-01

A floating energy converter is described which uses large volumes of sea water to produce electrical power. In this plant, a fluid working medium is pumped to an evaporator where is is heated by a flow of warm surface sea water. The fluid in liquid form boils to a pressurized gas vapor which is routed to drive a turbine that, in turn, drives a generator for producing electricity. The gas vapor then enters a condenser immersed in cold sea water pumped from lower depths, condenses to its original liquid form, and then pumped to the evaporator to repeat the cycle. Modular components can be readily interchanged on the ocean thermal unit and inlet pipes for the sea water are provided with means for maintaining the pipes in alignment with the oncoming current. The modular construction allows for the testing of various components to provide a more rapid optimization of a standardized plant.

Nanocolloids in Natural Water: Isolation, Characterization, and Toxicity.

PubMed

Ouyang, Shaohu; Hu, Xiangang; Zhou, Qixing; Li, Xiaokang; Miao, Xinyu; Zhou, Ruiren

2018-04-17

Nanocolloids are widespread in natural water systems, but their characterization and ecological risks are largely unknown. Herein, tangential flow ultrafiltration (TFU) was used to separate and concentrate nanocolloids from surface waters. Unexpectedly, nanocolloids were present in high concentrations ranging from 3.7 to 7.2 mg/L in the surface waters of the Harihe River in Tianjin City, China. Most of the nanocolloids were 10-40 nm in size, contained various trace metals and polycyclic aromatic hydrocarbons, and exhibited fluorescence properties. Envelopment effects and aggregation of Chlorella vulgaris in the presence of nanocolloids were observed. Nanocolloids entered cells and nanocolloid-exposed cells exhibited stronger plasmolysis, chloroplast damage and more starch grains than the control cells. Moreover, nanocolloids inhibited the cell growth, promoted reactive oxygen species (ROS), reduce the chlorophyll a content and increased the cell permeability. The genotoxicity of nanocolloids was also observed. The metabolomics analysis revealed a significant ( p < 0.05) downregulation of amino acids and upregulation of fatty acids contributing to ROS increase, chlorophyll a decrease and plasmolysis. The present work reveals that nanocolloids, which are different from specific, engineered nanoparticles (e.g., Ag nanoparticles), are present at high concentrations, exhibit an obvious toxicity in environments, and deserve more attention in the future.

The Effect of Atrazine on Louisiana Gulf Coast Estuarine Phytoplankton.

PubMed

Starr, Alexis V; Bargu, Sibel; Maiti, Kanchan; DeLaune, Ronald D

2017-02-01

Pesticides may enter water bodies in areas with a high proportion of agricultural land use through surface runoff, groundwater discharge, and erosion and thus negatively impact nontarget aquatic organisms. The herbicide atrazine is used extensively throughout the Midwest and enters the Mississippi River through surface runoff and groundwater discharge. The purpose of this study was to determine the extent of atrazine contamination in Louisiana's estuaries from Mississippi River water under different flow and nutrient regimes (spring and summer) and its effect on the biomass and oxygen production of the local phytoplankton community. The results showed that atrazine was consistently present in these systems at low levels. Microcosm experiments exposed to an atrazine-dilution series under low and high nutrient conditions to determine the phytoplankton stress response showed that high atrazine levels greatly decreased phytoplankton biomass and oxygen production. Phytoplankton exposed to low and moderate atrazine levels under high nutrient conditions were able to recover after an extended acclimation period. Communities grown under high nutrient conditions grew more rapidly and produced greater levels of oxygen than the low nutrient treatment groups, thus indicating that atrazine exposure may induce a greater stress response in phytoplankton communities under low-nutrient conditions. The native community also experienced a shift from more sensitive species, such as chlorophytes, to potentially more resilient species such as diatoms. The phytoplankton response to atrazine exposure at various concentrations can be especially important to greater trophic levels because their growth and abundance can determine the potential productivity of the entire ecosystem.

Pathways of Atlantic Waters in the Nordic seas: locally eddy-permitting ocean simulation in a global setup

NASA Astrophysics Data System (ADS)

Wekerle, C.; Wang, Q.; Danilov, S.; Jung, T.; Schourup-Kristensen, V.

2016-02-01

Atlantic Water (AW) passes through the Nordic Seas and enters the Arctic Ocean through the shallow Barents Sea and the deep Fram Strait. Since the 1990's, observations indicate a series of anomalously warm pulses of Atlantic Water that entered the Arctic Ocean. In fact, poleward oceanic heat transport may even increase in the future, which might have implications for the heat uptake in the Arctic Ocean as well as for the sea ice cover. The ability of models to faithfully simulate the pathway of the AW and accompanying dynamics is thus of high climate relevance. In this study, we explore the potential of a global multi-resolution sea ice-ocean model with a locally eddy-permitting resolution (around 4.5 km) in the Nordic seas region and Arctic Ocean in improving the representation of Atlantic Water inflow, and more broadly, the dynamics of the circulation in the Northern North Atlantic and Arctic. The simulation covers the time period 1969-2009. We find that locally increased resolution improves the localization and thickness of the Atlantic Water layer in the Nordic seas, compared with a 20 km resolution reference simulation. In particular, the inflow of Atlantic Waters through the Greenland Scotland Ridge and the narrow branches of the Norwegian Atlantic Current can be realistically represented. Lateral spreading due to simulated eddies essentially reduces the bias in the surface temperature. In addition, a qualitatively good agreement of the simulated eddy kinetic energy field with observations can be achieved. This study indicates that a substantial improvement in representing local ocean dynamics can be reached through the local refinement, which requires a rather moderate computational effort. The successful model assessment allows us to further investigate the variability and mechanisms behind Atlantic Water transport into the Arctic Ocean.

Transport of human adenoviruses in porous media

NASA Astrophysics Data System (ADS)

Kokkinos, Petros; Syngouna, Vasiliki I.; Tselepi, Maria A.; Bellou, Maria; Chrysikopoulos, Constantinos V.; Vantarakis, Apostolos

2015-04-01

Groundwater may be contaminated with infective human enteric viruses from various wastewater discharges, sanitary landfills, septic tanks, agricultural practices, and artificial groundwater recharge. Coliphages have been widely used as surrogates of enteric viruses, because they share many fundamental properties and features. Although a large number of studies focusing on various factors (i.e. pore water solution chemistry, fluid velocity, moisture content, temperature, and grain size) that affect biocolloid (bacteria, viruses) transport have been published over the past two decades, little attention has been given toward human adenoviruses (hAdVs). The main objective of this study was to evaluate the effect of pore water velocity on hAdV transport in water saturated laboratory-scale columns packed with glass beads. The effects of pore water velocity on virus transport and retention in porous media was examined at three pore water velocities (0.39, 0.75, and 1.22 cm/min). The results indicated that all estimated average mass recovery values for hAdV were lower than those of coliphages, which were previously reported in the literature by others for experiments conducted under similar experimental conditions. However, no obvious relationship between hAdV mass recovery and water velocity could be established from the experimental results. The collision efficiencies were quantified using the classical colloid filtration theory. Average collision efficiency, α, values decreased with decreasing flow rate, Q, and pore water velocity, U, but no significant effect of U on α was observed. Furthermore, the surface properties of viruses and glass beads were used to construct classical DLVO potential energy profiles. The results revealed that the experimental conditions of this study were unfavorable to deposition and that no aggregation between virus particles is expected to occur. A thorough understanding of the key processes governing virus transport is pivotal for public health protection.

Temporal Evolution of the High-energy Irradiation and Water Content of TRAPPIST-1 Exoplanets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bourrier, V.; Ehrenreich, D.; Wit, J. de

The ultracool dwarf star TRAPPIST-1 hosts seven Earth-size transiting planets, some of which could harbor liquid water on their surfaces. Ultraviolet observations are essential to measuring their high-energy irradiation and searching for photodissociated water escaping from their putative atmospheres. Our new observations of the TRAPPIST-1 Ly α line during the transit of TRAPPIST-1c show an evolution of the star emission over three months, preventing us from assessing the presence of an extended hydrogen exosphere. Based on the current knowledge of the stellar irradiation, we investigated the likely history of water loss in the system. Planets b to d might stillmore » be in a runaway phase, and planets within the orbit of TRAPPIST-1g could have lost more than 20 Earth oceans after 8 Gyr of hydrodynamic escape. However, TRAPPIST-1e to h might have lost less than three Earth oceans if hydrodynamic escape stopped once they entered the habitable zone (HZ). We caution that these estimates remain limited by the large uncertainty on the planet masses. They likely represent upper limits on the actual water loss because our assumptions maximize the X-rays to ultraviolet-driven escape, while photodissociation in the upper atmospheres should be the limiting process. Late-stage outgassing could also have contributed significant amounts of water for the outer, more massive planets after they entered the HZ. While our results suggest that the outer planets are the best candidates to search for water with the JWST , they also highlight the need for theoretical studies and complementary observations in all wavelength domains to determine the nature of the TRAPPIST-1 planets and their potential habitability.« less

Study of contaminant transport at an open-tipping waste disposal site.

PubMed

Ashraf, Muhammad Aqeel; Yusoff, Ismail; Yusof, Mohamad; Alias, Yatimah

2013-07-01

Field and laboratory studies were conducted to estimate concentration of potential contaminants from landfill in the underlying groundwater, leachate, and surface water. Samples collected in the vicinity of the landfill were analyzed for physiochemical parameters, organic contaminants, and toxic heavy metals. Water quality results obtained were compared from published data and reports. The results indicate serious groundwater and surface water contamination in and around the waste disposal site. Analysis of the organic samples revealed that the site contains polychlorinated biphenyls and other organo-chlorine chemicals, principally chloro-benzenes. Although the amount of PCB concentration discovered was not extreme, their presence indicates a potentially serious environmental threat. Elevated concentrations of lead, copper, nickel, manganese, cadmium, and cobalt at the downgradient indicate that the contamination plume migrated further from the site, and the distribution of metals and metals containing wastes in the site is nonhomogeneous. These results clearly indicate that materials are poorly contained and are at risk of entering the environment. Therefore, full characterization of the dump contents and the integrity of the site are necessary to evaluate the scope of the problem and to identify suitable remediation options.

Do insect repellents induce drift behaviour in aquatic non-target organisms?

PubMed

Fink, Patrick; Moelzner, Jana; Berghahn, Ruediger; von Elert, Eric

2017-01-01

Synthetic insect repellents are compounds applied to surfaces to discourage insects, mainly mosquitoes, from landing on those surfaces. As some of these repellents have repeatedly been detected in surface waters at significant concentrations, they may also exert repellent effects on aquatic non-target organisms. In running water systems, aquatic invertebrates actively enter downstream drift in order to avoid unfavourable environmental conditions. We thus tested the hypothesis that the widely used insect repellents DEET (N,N-Diethyl-m-toluamide), EBAAP (3-[N-butyl-N-acetyl]-aminopropionic acid ethyl ester) and Icaridin (1-piperidinecarboxylic acid 2-(2-hydroxyethyl)-1-methylpropyl ester) induce downstream drift behaviour in the aquatic invertebrates Gammarus pulex (Crustacea, Amphipoda) and Cloeon dipterum (Insecta, Ephemeroptera), using a laboratory-scale drift assay. We found no clear increase in the drift behaviour of both invertebrate species across a concentration gradient of eight orders of magnitude and even beyond maximum environmental concentrations for any of the three repellents. We found no evidence for a direct drift-inducing activity of insect repellents on aquatic non-target organisms. Copyright © 2016 Elsevier Ltd. All rights reserved.

Is There Ecological Information in Optical Polarization Data?

NASA Technical Reports Server (NTRS)

Vanderbilt, Vern; Daughtry, Craig; Dahlgren, Robert

2015-01-01

Optical linear polarization? In remote sensing it's due to specular reflection. The first surface that incident light encounters - a smooth water surface or the waxy first surface of a leaf's cuticle, if it's even somewhat smooth (i.e. shiny) - will specularly reflect and linearly polarize the incident light. We provide three examples of the types of ecological information contained in remotely sensed optical linear polarization measurements. Remove the surface reflection to better see the interior. The linearly polarized light reflected by leaf surfaces contains no information about cellular pigments, metabolites, or water contained in the leaf interiors of a plant canopy, because it never enters the leaf interior to interact with them. Thus, for purposes of remotely sensing the leaf interiors of a plant canopy, the linearly polarized light should be subtracted from the total reflected light, because including it would add noise to the measurement. In particular 'minus specular' vegetation indices should allow improved monitoring of a plant canopy's physiological processes. Estimate plant development stage and yield. Wheat and sorghum grain heads, following emergence, rapidly extend upward and very quickly tower over nearby leaves, partially blocking our view of the sunlight reflected by those leaf surfaces. The resulting decrease in the amount of surface reflected and polarized sunlight, if monitored over time, potentially allows per-field estimates of the dates of the heading and flowering development stages to be interleaved with weather data in models, which is key to better estimating per-field grain yield. Similar polarization changes may occur in other grasses, such as oats, barley, corn and rice, each a crop so widely grown that it potentially affects climate at the regional scale. Wetlands Mapping. The sunlight specularly reflected by surface waters is blindingly bright, spectrally flat and polarized - all of which telegraphs that the ground area is inundated. Inundated soils exchange methane with the atmosphere; non-inundated soils, carbon dioxide. Aquatic plants growing through the water surface pipe the soil-produced methane via the stomata to the atmosphere, enhancing exchanges rates by factors of 10-20 compared to ebullition (bubbling) or diffusion through the water column to the atmosphere. Thus, mapping wetland areas into three community types - inundated areas with emergent vegetation, open water and uplands - provides potentially key information to water, carbon and energy budgets at landscape to global scales.

The Response of a Branch of Puget Sound, Washington to the 2014 North Pacific Warm Anomaly

NASA Astrophysics Data System (ADS)

Mickett, J.; Newton, J.; Devol, A.; Krembs, C.; Ruef, W.

2016-02-01

The flow of the unprecedentedly-warm upper-ocean North Pacific "Blob" water into Puget Sound, Washington, caused local extreme water property anomalies that extended from the arrival of the water inshore in the fall of 2014 through 2015. Here we report on moored and seaplane observations from Hood Canal, a branch of Puget Sound, where temperature was more than 2σ above climatology for much of the year with maximum temperature anomalies at depth and at the surface +2.5 °C and +7 °C respectively. The low density of the oceanic warm "Blob" water resulted in weak deep water flushing in Hood Canal in the fall of 2014, which combined with a lack of wintertime flushing to result in anomalously-low dissolved oxygen (DO) concentrations at depth. Late-summer 2015 DO values were the lowest in a decade of mooring observations and more than 2σ below climatology. The anomalously low density of the deep basin water allowed a very early onset of the annually-occurring, late-summer intrusion, which first entered Hood Canal at the end of July compared to the usual arrival in early to mid-September. In late August this intrusion conspired with an early fall storm to lift the very low DO deep water to surface at the south end of Hood Canal, causing a significant fish kill event.

Continuous Manufacturing of Nitrocellulose by Magnesium Nitrate Method. Volume 1

DTIC Science & Technology

1979-06-01

enters a scrubber . The scrubber removes entrained acid, water, and NC fines from the air before it enters a Roots water sealed (lobe type) vacuum pump...and is exhausted to the atmosphere. The air enters the bottom of the scrubber and is forced (by vacuum) sequentially through two weir arrangements...the panel from left to right, the Eimco dewatering filter drive, vacuum pressure, receiver, vacuum scrubber , and pump controls may be seen along with

Entry of Yersinia Pestis into the Viable but Nonculturable State in a Low-Temperature Tap Water Microcosm

DTIC Science & Technology

2011-03-16

to enter the VBNC state [17,18,19,20]. In addition, many other bacterial pathogens, including Francisella tularensis, Vibrio cholerae, and Escherichia...sterilized distilled water microcosms at 4uC after 21 days [31]. Likewise, Linder and Oliver reported that Vibrio vulnificus entered the VBNC state... Vibrio cholerae, and Escherichia coli enter the VBNC state [12,21]. In addition, the two closest pathogenic relatives of Y. pestis, namely Y

Sources of baseflow for the Minnehaha Creek Watershed, Minnesota, US

NASA Astrophysics Data System (ADS)

Nieber, J. L.; Moore, T. L.; Gulliver, J. S.; Magner, J. A.; Lahti, L. B.

2013-12-01

Minnehaha Creek is among the most valued surface water features in the Minneapolis, MN metro area, with a waterfall as it enters the Minnehaha Creek park. Flow in Minnehaha Creek is heavily dependent on discharge from the stream's origin, Lake Minnetonka, the outlet of which is closed during drought periods to maintain water elevations in the lake resulting in low- (or no-) flow conditions in the creek. Stormwater runoff entering directly to the creek from the creek's largely urbanized watershed exacerbates extremes in flow conditions. Given the cultural and ecological value of this stream system, there is great interest in enhancing the cultural and ecosystem services provided by Minnehaha Creek through improvements in streamflow regime by reducing flashiness and sustaining increased low-flows. Determining the potential for achieving improvements in flow requires first that the current sources of water contributing to low-flows in the creek be identified and quantified. Work on this source identification has involved a number of different approaches, including analyses of the streamflow record using a hydrologic system model framework, examination of the Quaternary and bedrock geology of the region, estimation of groundwater-surface water exchange rates within the channel using hyporheic zone temperature surveys and flux meter measurements, and analyses of the stable isotopes of oxygen and hydrogen in samples of stream water, groundwater, and rainfall. Analysis of baseflow recessions using the method of Brutsaert and Nieber (1977) indicates that only a small portion of the catchment, probably the riparian zone, contributes to baseflows. This result appears to be supported by the observation that the limestone/shale bedrock layer underlying the surficial aquifer has a non-zero permeability, and in a significant portion of the watershed the layer has been eroded away leaving the surficial aquifer ';bottomless' and highly susceptible to vertical (down) water loss. The analysis of the stable isotopes indicate that much of the low flow volume originates from surface storages including wetlands and small lakes within the watershed, with a small amount of the flow originating from groundwater seepage into the creek in the upper reaches of the creek. The temperature surveys and the seepage meter measurements along the main channel of the watershed show a trend that groundwater enters into the creek in the upper reaches, while the flux exchange is from the creek to groundwater in the lower reaches. The differences in flux direction between the upper and lower portions of the creek can be explained by three possible nonexclusive causes. First, the creek empties to the Mississippi River, and as the mouth of the creek is approached, the regional piezometric head drops significantly. Second, the lower end of the creek has a much larger portion of ';bottomless' surficial aquifer and therefore greater potential vertical loss of water. Third, the lower portion of the watershed is more developed and has major stormwater pipe infrastructure, a possible pathway for accelerating drainage of the surficial aquifer. To address the issue of low groundwater contribution to low-flows in the creek it is proposed to divert stormwater to key locations within the riparian zone along the creek, and to infiltrate that water and store it for slow release to the creek during non-rain periods.

Water and sediment dynamics in the Red River mouth and adjacent coastal zone

NASA Astrophysics Data System (ADS)

van Maren, D. S.

2007-02-01

The coastline of the Red River Delta is characterized by alternating patterns of rapid accretion and severe erosion. The main branch of the Red River, the Ba Lat, is presently expanding seaward with a main depositional area several km downstream and offshore the Ba Lat River mouth. Sediment deposition rates are approximately 6 m in the past 50 years. Field measurements were done to determine the processes that regulate marine dispersal and deposition of sediment supplied by the Ba Lat. These measurements reveal that the waters surrounding the Ba Lat delta are strongly stratified with a pronounced southward-flowing surface layer. This southward-flowing surface layer is a coastal current which is generated by river plumes that flow into the coastal zone north of the Ba Lat. However, outflow of turbid river water is not continuous and most sediment enters the coastal zone when the alongshore surface velocities are low. As a consequence, most sediment settles from suspension close to the river mouth. In addition to the southward surface flow, the southward near-bottom currents are also stronger than northward currents. Contrasting with the residual flow near-surface, this southward flow component near-bottom is caused by tidal asymmetry. Because most sediment is supplied by the Ba Lat when wave heights are low, sediment is able to consolidate and therefore the long-term deposition is southward of, but still close to, the Ba Lat mouth.

Ground-Water Hydrology of the Upper Deschutes Basin, Oregon

USGS Publications Warehouse

Gannett, Marshall W.; Lite, Kenneth E.; Morgan, David S.; Collins, Charles A.

2001-01-01

The upper Deschutes Basin is among the fastest growing regions in Oregon. The rapid population growth has been accompanied by increased demand for water. Surface streams, however, have been administratively closed to additional appropriation for many years, and surface water is not generally available to support new development. Consequently, ground water is being relied upon to satisfy the growth in water demand. Oregon water law requires that the potential effects of ground-water development on streamflow be evaluated when considering applications for new ground-water rights. Prior to this study, hydrologic understanding has been insufficient to quantitatively evaluate the connection between ground water and streamflow, and the behavior of the regional ground-water flow system in general. This report describes the results of a hydrologic investigation undertaken to provide that understanding. The investigation encompasses about 4,500 square miles of the upper Deschutes River drainage basin.A large proportion of the precipitation in the upper Deschutes Basin falls in the Cascade Range, making it the principal ground-water recharge area for the basin. Water-balance calculations indicate that the average annual rate of ground- water recharge from precipitation is about 3,500 ft3/s (cubic feet per second). Water-budget calculations indicate that in addition to recharge from precipitation, water enters the ground-water system through interbasin flow. Approximately 800 ft3/s flows into the Metolius River drainage from the west and about 50 ft3/s flows into the southeastern part of the study area from the Fort Rock Basin. East of the Cascade Range, there is little or no ground-water recharge from precipitation, but leaking irrigation canals are a significant source of artificial recharge north of Bend. The average annual rate of canal leakage during 1994 was estimated to be about 490 ft3/s. Ground water flows from the Cascade Range through permeable volcanic rocks eastward out into the basin and then generally northward. About one-half the ground water flowing from the Cascade Range discharges to spring-fed streams along the margins of the range, including the upper Metolius River and its tributaries. The remaining ground water flows through the subsurface, primarily through rocks of the Deschutes Formation, and eventually discharges to streams near the confluence of the Deschutes, Crooked, and Metolius Rivers. Substantial ground-water discharge occurs along the lower 2 miles of Squaw Creek, the Deschutes River between Lower Bridge and Pelton Dam, the lower Crooked River between Osborne Canyon and the mouth, and in Lake Billy Chinook (a reservoir that inundates the confluence of the Deschutes, Crooked, and Metolius Rivers).The large amount of ground-water discharge in the confluence area is primarily caused by geologic factors. North (downstream) of the confluence area, the upper Deschutes Basin is transected by a broad region of low-permeability rock of the John Day Formation. The Deschutes River flows north across the low-permeability region, but the permeable Deschutes Formation, through which most of the regional ground water flows, ends against this rampart of low-permeability rock. The northward-flowing ground water discharges to the streams in this area because the permeable strata through which it flows terminate, forcing the water to discharge to the surface. Virtually all of the regional ground water in the upper Deschutes Basin discharges to surface streams south of the area where the Deschutes River enters this low-permeability terrane, at roughly the location of Pelton Dam.The effects of ground-water withdrawal on streamflow cannot presently be measured because of measurement error and the large amount of natural variability in ground-water discharge. The summer streamflow near Madras, which is made up largely of ground-water discharge, is approximately 4,000 ft3/s. Estimated consumptive ground-water use in the basin i

Interaction and Relationship Between Groundwater and Surface Water at Keystone Heritage Park EL Paso Texas

NASA Astrophysics Data System (ADS)

Gonzalez, B.

2012-12-01

Belinda Gonzalez1, Joshua Villalobos1, Marissa Cameron 2 1Department of Geological Sciences, El Paso Community College, El Paso, TX 79925, USA 2Department of Geological Sciences, University of Texas at El Paso, El Paso, TX 79968, USA beli_72764@yahoo.com Historically the floodplain of the Rio Grande River was dotted with shifting wetlands and ponds.The increasing population throughout the United States and Mexico has made it necessary to put the Rio Grande floodplain under till for cultivation. Along with cultivation, the river was channelized and dammed to prevent flooding and to stabilize the Mexico/U.S. border.The loss of wetland ecosystems in the area changed migration patterns of water fowl and destroyed priceless aquatic habitats.The area of our study, Keystone Heritage Park, is the last remaining open wetlands in El Paso County. Before efforts of restoration to reestablish wetlands associated with the Rio Grande can begin, there must be an in-depth, and complete, understanding of the surface and subsurface hydrological system which created and sustains this last remaining wetland. Studies of the wetland's soil properties and their effect on groundwater flow have indicated regions on the periphery of the wetlands where soils are saturated with moisture.These subsurface regions of saturated soils are semi-linear in shape and lead toward the wetland indicating that they are possible loci for groundwater flow for the wetland.These subsurface soil layers are possibly composed of mountain front alluvium that is being feed with meteoric water entering faults that bound the nearby Franklin Mountains.The primary goals of this study are 1) initiate a systematic data acquisition from 9 piezometers and 2 water level loggers of temporal variations in the depth of the groundwater due to regional pumping or rain fall and 2) generate a depth and TDS (Total Dissolved Solids) profile of the wetland pond to locate regions where groundwater maybe entering the lake.

Evaluating tsunami hazards from debris flows

USGS Publications Warehouse

Watts, P.; Walder, J.S.; ,

2003-01-01

Debris flows that enter water bodies may have significant kinetic energy, some of which is transferred to water motion or waves that can impact shorelines and structures. The associated hazards depend on the location of the affected area relative to the point at which the debris flow enters the water. Three distinct regions (splash zone, near field, and far field) may be identified. Experiments demonstrate that characteristics of the near field water wave, which is the only coherent wave to emerge from the splash zone, depend primarily on debris flow volume, debris flow submerged time of motion, and water depth at the point where debris flow motion stops. Near field wave characteristics commonly may be used as & proxy source for computational tsunami propagation. This result is used to assess hazards associated with potential debris flows entering a reservoir in the northwestern USA. ?? 2003 Millpress,.

Geology, geochemistry, and geophysics of the Fry Canyon uranium/copper project site, southeastern Utah - Indications of contaminant migration

USGS Publications Warehouse

Otton, James K.; Zielinski, Robert A.; Horton, Robert J.

2010-01-01

The Fry Canyon uranium/copper project site in San Juan County, southeastern Utah, was affected by the historical (1957-68) processing of uranium and copper-uranium ores. Relict uranium tailings and related ponds, and a large copper heap-leach pile at the site represent point sources of uranium and copper to local soils, surface water, and groundwater. This study was designed to establish the nature, extent, and pathways of contaminant dispersion. The methods used in this study are applicable at other sites of uranium mining, milling, or processing. The uranium tailings and associated ponds sit on a bench that is as much as 4.25 meters above the level of the adjacent modern channel of Fry Creek. The copper heap leach pile sits on bedrock just south of this bench. Contaminated groundwater from the ponds and other nearby sites moves downvalley and enters the modern alluvium of adjacent Fry Creek, its surface water, and also a broader, deeper paleochannel that underlies the modern creek channel and adjacent benches and stream terraces. The northern extent of contaminated groundwater is uncertain from geochemical data beyond an area of monitoring wells about 300 meters north of the site. Contaminated surface water extends to the State highway bridge. Some uranium-contaminated groundwater may also enter underlying bedrock of the Permian Cedar Mesa Sandstone along fracture zones. Four dc-resistivity surveys perpendicular to the valley trend were run across the channel and its adjacent stream terraces north of the heap-leach pile and ponds. Two surveys were done in a small field of monitoring wells and two in areas untested by borings to the north of the well field. Bedrock intercepts, salt distribution, and lithologic information from the wells and surface observations in the well field aided interpretation of the geophysical profiles there and allowed interpretation of the two profiles not tested by wells. The geophysical data for the two profiles to the north of the well field suggest that the paleochannel persists at least 900 m to the north of the heap leach and pond sites. Contamination of groundwater beneath the stream terraces may extend at least that far. Fry Creek surface water (six samples), seeps and springs (six samples), and wells (eight samples) were collected during a dry period of April 16-19, 2007. The most uranium-rich (18.7 milligrams per liter) well water on the site displays distinctive Ca-Mg-SO4-dominant chemistry indicating the legacy of heap leaching copper-uranium ores with sulfuric acid. This same water has strongly negative d34S of sulfate (-13.3 per mil) compared to most local waters of -2.4 to -5.4 per mil. Dissolved uranium species in all sampled waters are dominantly U(VI)-carbonate complexes. All waters are undersaturated with respect to U(VI) minerals. The average 234U/238U activity ratio (AR) in four well waters from the site (0.939 + or ? 0.011) is different from that of seven upstream waters (1.235 + or ? 0.069). This isotopic contrast permits quantitative estimates of mixing of site-derived uranium with natural uranium in waters collected downstream. At the time of sampling, uranium in downstream surface water was mostly (about 67 percent) site-derived and subject to further concentration by evaporation. Three monitoring wells located approximately 0.4 kilometer downstream contained dominantly (78-87 percent) site-derived uranium. Distinctive particles of chalcopyrite (CuFeS) and variably weathered pyrite (FeS2) are present in tailings at the stream edge on the site and are identified in stream sediments 1.3 kilometers downstream, based on inspection of polished grain mounts of magnetic mineral separates.

49 CFR 192.323 - Casing.

Code of Federal Regulations, 2011 CFR

2011-10-01

... loads. (b) If there is a possibility of water entering the casing, the ends must be sealed. (c) If the... operating pressure of the pipe, the casing must be designed to hold this pressure at a stress level of not... the weather to prevent water from entering the casing. ...

49 CFR 192.323 - Casing.

Code of Federal Regulations, 2010 CFR

2010-10-01

... loads. (b) If there is a possibility of water entering the casing, the ends must be sealed. (c) If the... operating pressure of the pipe, the casing must be designed to hold this pressure at a stress level of not... the weather to prevent water from entering the casing. ...

Environmental Assessment: North Ditch Crossing Culvert Replacement at West of Grand Forks AFB, North Dakota

DTIC Science & Technology

2003-08-09

this area. Wood nettle (Laportea canadensis), stinging nettle (Urtica dioica), beggars’ ticks (Bidens frondosa), and waterleaf (Hydrophyllum viginianum...materials, herbicides, and insecticides from entering public waters (this includes eliminating sediment from entering the storm drain inlets). Water used

Conceptual Model and Numerical Simulation of the Ground-Water-Flow System in the Unconsolidated Sediments of Thurston County, Washington

USGS Publications Warehouse

Drost, B.W.; Ely, D.M.; Lum, W. E.

1999-01-01

The demand for water in Thurston County has increased steadily in recent years because of a rapid growth in population. Surface-water resources in the county have been fully appropriated for many years and Thurston County now relies entirely on ground water for new supplies of water. Thurston County is underlain by up to 2,000 feet of unconsolidated glacial and non-glacial Quaternary sediments which overlie consolidated rocks of Tertiary age. Six geohydrologic units have been identified within the unconsolidated sediments. Between 1988 and 1990, median water levels rose 0.6 to 1.9 feet in all geohydrologic units except bedrock, in which they declined 1.4 feet. Greater wet-season precipitation in 1990 (43 inches) than in 1988 (26 inches) was the probable cause of the higher 1990 water levels. Ground-water flow in the unconsolidated sediments underlying Thurston County was simulated with a computerized numerical model (MODFLOW). The model was constructed to simulate 1988 ground-water conditions as steady state. Simulated inflow to the model area from precipitation and secondary recharge was 620,000 acre-feet per year (93 percent), leakage from streams and lakes was 38,000 acre-ft/yr (6 percent), and ground water entering the model along the Chehalis River valley was 5,800 acre-ft/yr (1 percent). Simulated outflow from the model was primarily leakage to streams, springs, lakes, and seepage faces (500,000 acre-ft/yr or 75 percent of the total outflow). Submarine seepage to Puget Sound was simulated to be 88,000 acre-ft/yr (13 percent). Simulated ground-water discharge along the Chehalis River valley was simulated to be 12,000 acreft/yr (2 percent). Simulated withdrawals by wells for all purposes was 62,000 acre-ft/yr (9 percent). The numerical model was used to simulate the possible effects of increasing ground-water withdrawals by 23,000 acre-ft/yr above the 1988 rate of withdrawal. The model indicated that the increased withdrawals would come from reduced discharge to springs, seepage faces, and offshore (total of 51 percent of increased pumping) and decreased flow to rivers (46 percent). About 3 percent would come from increased leakage from rivers. Water levels would decline more than 1 foot over most of the model area, more than 10 feet over some areas, and would be at a maximum of about 35 feet. Contributing areas for water discharging at McAllister and Abbott Springs and to pumping centers near Tumwater and Lacey were estimated using a particle-tracking post-processing computer code (MODPATH) and a MODFLOW model calibrated to steady-state (1988) conditions. Water discharging at McAllister and Abbot Springs was determined to come from water entering the ground-water system at the water table in an area of about 20 square miles (mi2) to the west and south of the springs. This water is estimated to come from recharge (both precipitation and secondary) and from leakage from Lake St. Clair and several other surface-water bodies. Southeast of Lacey, about 3,800 acre-ft of ground water were pumped from five municipal wells during 1988. The source of the pumped water was determined to be an area that covers about 1.1 mi2. The water was estimated to come from recharge (both precipitation and secondary) and leakage from surface-water bodies. Along the lower Deschutes River nearly 3,900 acre-ft/yr of ground water were pumped during 1988 from 15 wells for municipal and industrial use. The calculated source of this water was an area that covers about 1.3 mi2. Within the calculated contributing area the pumped ground water comes from recharge (both precipitation and secondary) and leakage from the Deschutes River and several other surface-water bodies.

Decadal variability of tropical tropopause temperature and its relationship to the Pacific Decadal Oscillation.

PubMed

Wang, Wuke; Matthes, Katja; Omrani, Nour-Eddine; Latif, Mojib

2016-07-12

Tropopause temperatures (TPTs) control the amount of stratospheric water vapour, which influences chemistry, radiation and circulation in the stratosphere, and is also an important driver of surface climate. Decadal variability and long-term trends in tropical TPTs as well as stratospheric water vapour are largely unknown. Here, we present for the first time evidence, from reanalysis and state-of-the-art climate model simulations, of a link between decadal variability in tropical TPTs and the Pacific Decadal Oscillation (PDO). The negative phase of the PDO is associated with anomalously cold sea surface temperatures (SSTs) in the tropical east and central Pacific, which enhance the zonal SST gradient across the equatorial Pacific. The latter drives a stronger Walker Circulation and a weaker Hadley Circulation, which leads to less convection and subsequently a warmer tropopause over the central equatorial Pacific. Over the North Pacific, positive sea level pressure anomalies occur, which damp vertical wave propagation into the stratosphere. This in turn slows the Brewer-Dobson circulation, and hence warms the tropical tropopause, enabling more water vapour to enter the stratosphere. The reverse chain of events holds for the positive phase of the PDO. Such ocean-troposphere-stratosphere interactions may provide an important feedback on the Earth's global surface temperature.

Decadal variability of tropical tropopause temperature and its relationship to the Pacific Decadal Oscillation

PubMed Central

Wang, Wuke; Matthes, Katja; Omrani, Nour-Eddine; Latif, Mojib

2016-01-01

Tropopause temperatures (TPTs) control the amount of stratospheric water vapour, which influences chemistry, radiation and circulation in the stratosphere, and is also an important driver of surface climate. Decadal variability and long-term trends in tropical TPTs as well as stratospheric water vapour are largely unknown. Here, we present for the first time evidence, from reanalysis and state-of-the-art climate model simulations, of a link between decadal variability in tropical TPTs and the Pacific Decadal Oscillation (PDO). The negative phase of the PDO is associated with anomalously cold sea surface temperatures (SSTs) in the tropical east and central Pacific, which enhance the zonal SST gradient across the equatorial Pacific. The latter drives a stronger Walker Circulation and a weaker Hadley Circulation, which leads to less convection and subsequently a warmer tropopause over the central equatorial Pacific. Over the North Pacific, positive sea level pressure anomalies occur, which damp vertical wave propagation into the stratosphere. This in turn slows the Brewer-Dobson circulation, and hence warms the tropical tropopause, enabling more water vapour to enter the stratosphere. The reverse chain of events holds for the positive phase of the PDO. Such ocean-troposphere-stratosphere interactions may provide an important feedback on the Earth’s global surface temperature. PMID:27404090

Genetic Investigation of Beta-Lactam Associated Antibiotic Resistance Among Escherichia Coli Strains Isolated from Water Sources.

PubMed

Ranjbar, Reza; Sami, Mehrdad

2017-01-01

Antimicrobial resistance is an important factor threatening human health. It is widely accepted that antibiotic resistant bacteria such as Escherichia coli ( E. coli) released from humans and animals into the water sources, can introduce their resistance genes into the natural bacterial community. The aim of this study was to investigate the prevalence of bla TEM , bla CTX , bla SHV , bla OXA and bla VEB associated-antibiotic resistance among E. coli bacteria isolated from different water resources in Iran. The study contained all E. coli strains segregated from different surface water sources. The Kirby-Bauer method and combined discs method was determined in this study for testing antimicrobial susceptibility and strains that produced Extended-Spectrum Beta Lactamases (ESBL), respectively. DNA extraction kit was applied for genomic and plasmid DNA derivation. Finally the frequency of resistant genes including bla TEM , bla CTX , bla SHV , bla OXA and bla VEB in ESBL producing isolates were studied by PCR. One hundred E. coli strains were isolated and entered in the study. The highest antibiotic resistance was observed on clindamycin (96%). Moreover, 38.5% isolates were ESBL producers. The frequency of different ESBLs genes were 37%, 27%, 27%, and 25% for bla TEM , bla CTX , bla SHV , and bla OXA , respectively. The bla VEB wasn't found in any isolates. The study revealed a high prevalence of CTX-M, TEM, SHV and OXA genes among E. coli strains in surface water resources. In conclusion, these results raised a concern regarding the presence and distribution of these threatening factors in surface water sources and its subsequent outcomes.

Seasonal change in precipitation, snowpack, snowmelt, soil water and streamwater chemistry, northern Michigan

USGS Publications Warehouse

Stottlemyer, R.; Toczydlowski, D.

1999-01-01

We have studied weekly precipitation, snowpack, snowmelt, soil water and streamwater chemistry throughout winter for over a decade in a small (176 ha) northern Michigan watershed with high snowfall and vegetated by 60 to 80 year-old northern hardwoods. In this paper, we examine physical, chemical, and biological processes responsible for observed seasonal change in streamwater chemistry based upon intensive study during winter 1996-1997. The objective was to define the contributions made to winter and spring streamwater chemical concentration and flux by processes as snowmelt, over-winter forest floor and surface soil mineralization, immobilization, and exchange, and subsurface flowpath. The forest floor and soil were unfrozen beneath the snowpack which permitted most snowmelt to enter. Over-winter soil mineralization and other biological processes maintain shallow subsurface ion and dissolved organic carbon (DOC) reservoirs. Small, but steady, snowmelt throughout winter removed readily mobilized soil NO3- which resulted in high over-winter streamwater concentrations but little flux. Winter soil water levels and flowpaths were generally deep which increased soil water and streamwater base cation (C(B)), HCO3-, and Si concentrations. Spring snowmelt increased soil water levels and removal of ions and DOC from the biologically active forest floor and shallow soils. The snowpack solute content was a minor component in determining streamwater ion concentration or flux during and following peak snowmelt. Exchangeable ions, weakly adsorbed anions, and DOC in the forest floor and surface soils dominated the chemical concentration and flux in soil water and streamwater. Following peak snowmelt, soil microbial immobilization and rapidly increased plant uptake of limiting nutrients removed nearly all available nitrogen from soil water and streamwater. During the growing season high evapotranspiration increased subsurface flowpath depth which in turn removed weathering products, especially C(B), HCO3-, and Si, from deeper soils. Soil water was a major component in the hydrologic and chemical budgets.We have studied weekly precipitation, snowpack, snowmelt, soil water and streamwater chemistry throughout winter for over a decade in a small (176 ha) northern Michigan watershed with high snowfall and vegetated by 60 to 80 year-old northern hardwoods. In this paper, we examine physical, chemical, and biological processes responsible for observed seasonal change in streamwater chemistry based upon intensive study during winter 1996-1997. The objective was to define the contributions made to winter and spring streamwater chemical concentration and flux by processes as snowmelt, over-winter forest floor and surface soil mineralization, immobilization, and exchange, and subsurface flowpath. The forest floor and soils were unfrozen beneath the snowpack which permitted most snowmelt to enter. Over-winter soil mineralization and other biological processes maintain shallow subsurface ion and dissolved organic carbon (DOC) reservoirs. Small, but steady, snowmelt throughout winter removed readily mobilized soil NO3- which resulted in high over-winter streamwater concentrations but little flux. Winter soil water levels and flowpaths were generally deep which increased soil water and streamwater base cation (CB), HCO3-, and Si concentrations. Spring snowmelt increased soil water levels and removal of ions and DOC from the biologically active forest floor and shallow soils. The snowpack solute content was a minor component in determining streamwater ion concentration or flux during and following peak snowmelt. Exchangeable ions, weakly adsorbed anions, and DOC in the forest floor and surface soils dominated the chemical concentration and flux in soil water and streamwater. Following peak snowmelt, soil microbial immobilization and rapidly increased plant uptake of limiting nutrients removed nearly all available nitrogen from soil water and streamwater. D

Modeling spray drift and runoff-related inputs of pesticides to receiving water.

PubMed

Zhang, Xuyang; Luo, Yuzhou; Goh, Kean S

2018-03-01

Pesticides move to surface water via various pathways including surface runoff, spray drift and subsurface flow. Little is known about the relative contributions of surface runoff and spray drift in agricultural watersheds. This study develops a modeling framework to address the contribution of spray drift to the total loadings of pesticides in receiving water bodies. The modeling framework consists of a GIS module for identifying drift potential, the AgDRIFT model for simulating spray drift, and the Soil and Water Assessment Tool (SWAT) for simulating various hydrological and landscape processes including surface runoff and transport of pesticides. The modeling framework was applied on the Orestimba Creek Watershed, California. Monitoring data collected from daily samples were used for model evaluation. Pesticide mass deposition on the Orestimba Creek ranged from 0.08 to 6.09% of applied mass. Monitoring data suggests that surface runoff was the major pathway for pesticide entering water bodies, accounting for 76% of the annual loading; the rest 24% from spray drift. The results from the modeling framework showed 81 and 19%, respectively, for runoff and spray drift. Spray drift contributed over half of the mass loading during summer months. The slightly lower spray drift contribution as predicted by the modeling framework was mainly due to SWAT's under-prediction of pesticide mass loading during summer and over-prediction of the loading during winter. Although model simulations were associated with various sources of uncertainties, the overall performance of the modeling framework was satisfactory as evaluated by multiple statistics: for simulation of daily flow, the Nash-Sutcliffe Efficiency Coefficient (NSE) ranged from 0.61 to 0.74 and the percent bias (PBIAS) < 28%; for daily pesticide loading, NSE = 0.18 and PBIAS = -1.6%. This modeling framework will be useful for assessing the relative exposure from pesticides related to spray drift and runoff in receiving waters and the design of management practices for mitigating pesticide exposure within a watershed. Published by Elsevier Ltd.

When interflow also percolates: downslope travel distances and hillslope process zones.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jackson, C. Rhett; Bitew, Menberu; Du, Enhao

2014-02-17

In hillslopes with soils characterized by deep regoliths, such as Ultisols,Oxisols, and Alfisols, interflow occurs episodically over impeding layers near and parallel to the soil surface such as low-conductivity B horizons (e.g.Newman et al., 1998; Buttle andMcDonald, 2002; Du et al., In Review), till layers (McGlynn et al., 1999; Bishop et al., 2004), hardpans (McDaniel et al., 2008), C horizons (Detty and McGuire, 2010), and permeable bedrock (Tromp van Meerveld et al., 2007). As perched saturation develops within and above these impeding but permeable horizons, flow moves laterally downslope, but the perched water also continues to percolate through the impedingmore » horizon to the unsaturated soils and saprolite below. Perched water and solutes will eventually traverse the zone of perched saturation above the impeding horizon and then enter and percolate through the impeding horizon. In such flow situations, only lower hillslope segments with sufficient downslope travel distance will deliver water to the riparian zone within the time scale of a storm.farther up the slope, lateral flow within the zone of perched saturation. will act mainly to shift the point of percolation (location where a water packet leaves the downslope flow zone in the upper soil layer and enters the impeding layer) down the hillslope from the point of infiltration. In flatter parts of the hillslope or in areas with little contrast between the conductivities of the upper and impeding soil layers, lateral flow distances will be negligible.« less

History of hepatic bile formation: old problems, new approaches.

PubMed

Javitt, Norman B

2014-12-01

Studies of hepatic bile formation reported in 1958 established that it was an osmotically generated water flow. Intravenous infusion of sodium taurocholate established a high correlation between hepatic bile flow and bile acid excretion. Secretin, a hormone that stimulates bicarbonate secretion, was also found to increase hepatic bile flow. The sources of the water entering the biliary system with these two stimuli were differentiated by the use of mannitol. An increase in its excretion parallels the increase in bile flow in response to bile acids but not secretin, which led to a quantitative distinction between canalicular and ductular water flow. The finding of aquaglyceroporin-9 in the basolateral surface of the hepatocyte accounted for the rapid entry of mannitol into hepatocytes and its exclusion from water movement in the ductules where aquaporin-1 is present. Electron microscopy demonstrated that bile acids generate the formation of vesicles that contain lecithin and cholesterol after their receptor-mediated canalicular transport. Biophysical studies established that the osmotic effect of bile acids varies with their concentration and also with the proportion of mono-, di-, and trihydroxy bile acids and provides a basis for understanding their physiological effects. Because of the varying osmotic effect of bile acids, it is difficult to quantify bile acid independent flow generated by other solutes, such as glutathione, which enters the biliary system. Monohydroxy bile acids, by markedly increasing aggregation number, severely reduce water flow. Developing biomarkers for the noninvasive assessment of normal hepatic bile flow remains an elusive goal that merits further study. Copyright © 2014 The American Physiological Society.

HYSEP: A Computer Program for Streamflow Hydrograph Separation and Analysis

USGS Publications Warehouse

Sloto, Ronald A.; Crouse, Michele Y.

1996-01-01

HYSEP is a computer program that can be used to separate a streamflow hydrograph into base-flow and surface-runoff components. The base-flow component has traditionally been associated with ground-water discharge and the surface-runoff component with precipitation that enters the stream as overland runoff. HYSEP includes three methods of hydrograph separation that are referred to in the literature as the fixed interval, sliding-interval, and local-minimum methods. The program also describes the frequency and duration of measured streamflow and computed base flow and surface runoff. Daily mean stream discharge is used as input to the program in either an American Standard Code for Information Interchange (ASCII) or binary format. Output from the program includes table,s graphs, and data files. Graphical output may be plotted on the computer screen or output to a printer, plotter, or metafile.

The role of water exchange between a stream channel and its hyporheic zone in nitrogen cycling at the terrestrial-aquatic interface

USGS Publications Warehouse

Triska, F.J.; Duff, J.H.; Avanzino, R.J.

1993-01-01

The subsurface riparian zone was examined as an ecotone with two interfaces. Inland is a terrestrial boundary, where transport of water and dissolved solutes is toward the channel and controlled by watershed hydrology. Streamside is an aquatic boundary, where exchange of surface water and dissolved solutes is bi-directional and flux is strongly influenced by channel hydraulics. Streamside, bi-directional exchange of water was qualitatively defined using biologically conservative tracers in a third order stream. In several experiments, penetration of surface water extended 18 m inland. Travel time of water from the channel to bankside sediments was highly variable. Subsurface chemical gradients were indirectly related to the travel time. Sites with long travel times tended to be low in nitrate and DO (dissolved oxygen) but high in ammonium and DOC (dissolved organic carbon). Sites with short travel times tended to be high in nitrate and DO but low in ammonium and DOC. Ammonium concentration of interstitial water also was influenced by sorption-desorption processes that involved clay minerals in hyporheic sediments. Denitrification potential in subsurface sediments increased with distance from the channel, and was limited by nitrate at inland sites and by DO in the channel sediments. Conversely, nitrification potential decreased with distance from the channel, and was limited by DO at inland sites and by ammonium at channel locations. Advection of water and dissolved oxygen away from the channel resulted in an oxidized subsurface habitat equivalent to that previously defined as the hyporheic zone. The hyporheic zone is viewed as stream habitat because of its high proportion of surface water and the occurrence of channel organisms. Beyond the channel's hydrologic exchange zone, interstitial water is often chemically reduced. Interstitial water that has not previously entered the channel, groundwater, is viewed as a terrestrial component of the riparian ecotone. Thus, surface water habitats may extend under riparian vegetation, and terrestrial groundwater habitats may be found beneath the stream channel. ?? 1993 Kluwer Academic Publishers.

Hydrology of a nuclear-processing plant site, Rocky Flats, Jefferson County, Colorado

USGS Publications Warehouse

Hurr, R. Theodore

1976-01-01

Accidental releases of contaminants resulting from the operation of the U.S. Energy Research and Development Administration's nuclear-processing and recovery plant located on Rocky Flats will move at different rates through -different parts of the hydrologic system. Rates of movement are dependent upon the magnitude of the accidental release and the hydrologic conditions at the time of the release. For example, during wet periods, a contaminant resulting from a 5,000-gallon (19,000-1itre) release on the land surface would enter the ground-water system in about 2 to 12 hours. Ground-water flow in the Rocky Flats Alluvium might move the contaminant eastward at a rate of about 3 to 11 feet (0.9 to 3.4 metres) per day, if it remains dissolved. Maximum time to a point of discharge would be about 3 years; minimum time could be a few days. A contaminant entering a stream would then move at a rate of about 60 feet (18 metres) per minute under pool-and-riffle conditions. The rate of movement might be about 420 feet (128 metres) per minute under open-channel-flow conditions following intense thunderstorms.

Europa's Great Lakes

NASA Astrophysics Data System (ADS)

Schmidt, B. E.; Blankenship, D. D.; Patterson, G. W.; Schenk, P. M.

2012-04-01

Unique to the surface of Europa, chaos terrain is diagnostic of the properties and dynamics of its icy shell. While models have suggested that partial melt within a thick shell or melt-through of a thin shell may form chaos, neither model has been able to definitively explain all observations of chaos terrain. However, we present a new model that suggests large melt lenses form within the shell and that water-ice interactions above and within these lenses drive the production of chaos. Our analysis of the geomorphology of Conamara Chaos and Thera Macula, was used to infer and test a four-stage lens-collapse chaos formation model: 1) Thermal plumes of warm, pure ice ascend through the shell melting the impure brittle ice above, producing a lake of briny water and surface down draw due to volume reduction. 2) Surface deflection and driving force from the plume below hydraulically seals the water in place. 3) Extension of the brittle ice lid generates fractures from below, allowing brines to enter and fluidize the ice matrix. 4) As the lens and now brash matrix refreeze, thermal expansion creates domes and raises the chaos feature above the background terrain. This new "lense-collapse" model indicates that chaos features form in the presence of a great deal of liquid water, and that large liquid water bodies exist within 3km of Europa's surface comparable in volume to the North American Great Lakes. The detection of shallow subsurface "lakes" implies that the ice shell is recycling rapidly and that Europa may be currently active. In this presentation, we will explore environments on Europa and their analogs on Earth, from collapsing Antarctic ice shelves to to subglacial volcanos in Iceland. I will present these new analyses, and describe how this new perspective informs the debate about Europa's habitability and future exploration.

Characterization of Natural Organic Matter by FeCl3 Coagulation

NASA Astrophysics Data System (ADS)

Cahyonugroho, O. H.; Hidayah, E. N.

2018-01-01

Natural organic matter (NOM) is heterogenous mixture of organic compounds that enter the water from various decomposition and metabolic reactions, including animal, plant, domestic and industrial wastes. NOM refers to group of carbon-based compounds that are found in surface water and ground water. The aim of the study is to assess organic matter characteristics in Jagir River as drinking water source and to characterize the organic components that could be removed during coagulation. Coagulation is the common water treatment process can be used to remove NOM with FeCl3 coagulant in various dosage. NOM surrogates, including total organic carbon (TOC), ultraviolet absorbance at 254 nm (UV254) and specific UV absorbance (SUVA) were chosen to assess the organic removal. Results of jar test experiments showed that NOM can be removed about 40% of NOM surrogates with 200 mg/L FeCl3. About 60% removal of total organic fraction, which is mainly humic substances, as detected by size exclusion chromatography (SEC).

Storage in California’s reservoirs and snowpack in this time of drought

USGS Publications Warehouse

Dettinger, Michael; Anderson, Michael L.

2015-01-01

The San Francisco Bay and Sacramento–San Joaquin Delta (Delta) are the recipients of inflows from a watershed that spans much of California and that has ties to nearly the entire state. Historically, California has buffered its water supplies and flood risks both within—and beyond—the Delta’s catchment by developing many reservoirs, large and small, high and low. Most of these reservoirs carry water from wet winter seasons—when water demands are low and flood risks are high—to dry, warm seasons (and years) when demands are high and little precipitation falls. Many reservoirs are also used to catch and delay (or spread in time) flood flows that otherwise might cause damage to communities and floodplains. This essay describes the status of surface-water and snowpack storage conditions in California in spring 2015, providing context for better understanding where the state’s water stores stand as we enter summer 2015.

Stratospheric water vapor feedback.

PubMed

Dessler, A E; Schoeberl, M R; Wang, T; Davis, S M; Rosenlof, K H

2013-11-05

We show here that stratospheric water vapor variations play an important role in the evolution of our climate. This comes from analysis of observations showing that stratospheric water vapor increases with tropospheric temperature, implying the existence of a stratospheric water vapor feedback. We estimate the strength of this feedback in a chemistry-climate model to be +0.3 W/(m(2)⋅K), which would be a significant contributor to the overall climate sensitivity. One-third of this feedback comes from increases in water vapor entering the stratosphere through the tropical tropopause layer, with the rest coming from increases in water vapor entering through the extratropical tropopause.

Coal-water mixture fuel burner

DOEpatents

Brown, T.D.; Reehl, D.P.; Walbert, G.F.

1985-04-29

The present invention represents an improvement over the prior art by providing a rotating cup burner arrangement for use with a coal-water mixture fuel which applies a thin, uniform sheet of fuel onto the inner surface of the rotating cup, inhibits the collection of unburned fuel on the inner surface of the cup, reduces the slurry to a collection of fine particles upon discharge from the rotating cup, and further atomizes the fuel as it enters the combustion chamber by subjecting it to the high shear force of a high velocity air flow. Accordingly, it is an object of the present invention to provide for improved combustion of a coal-water mixture fuel. It is another object of the present invention to provide an arrangement for introducing a coal-water mixture fuel into a combustion chamber in a manner which provides improved flame control and stability, more efficient combustion of the hydrocarbon fuel, and continuous, reliable burner operation. Yet another object of the present invention is to provide for the continuous, sustained combustion of a coal-water mixture fuel without the need for a secondary combustion source such as natural gas or a liquid hydrocarbon fuel. Still another object of the present invention is to provide a burner arrangement capable of accommodating a coal-water mixture fuel having a wide range of rheological and combustion characteristics in providing for its efficient combustion. 7 figs.

Sinuous Ridge on the Orson Welles Bajada

NASA Image and Video Library

2015-04-22

Alluvial fans are piles of debris dumped by rivers when they emerge from the mountains and enter a mostly dry valley as seen by NASA Mars Reconnaissance Orbiter. A bajada (such as this example named after the famous American filmmaker) consists of a series of coalescing alluvial fans along a mountain front. On the surface of this bajada, one can see many sinuous ridges. These ridges mark the path that streams of water took as they flowed into this crater. The sinuosity of the ridges tells us something about the speed of the water flow. Fast moving flows tend to be straighter than slow-moving. Observations like this help us build a picture of how rivers behaved on ancient Mars. http://photojournal.jpl.nasa.gov/catalog/PIA19366

Slamming pressures on the bottom of a free-falling vertical wedge

NASA Astrophysics Data System (ADS)

Ikeda, C. M.; Judge, C. Q.

2013-11-01

High-speed planing boats are subjected to repeat impacts due to slamming, which can cause structural damage and injury to passengers. A first step in understanding and predicting the physics of a craft re-entering the water after becoming partially airborne is an experimental vertical drop test of a prismastic wedge (deadrise angle, β =20° beam, B = 300 mm; and length, L = 600 mm). The acrylic wedge was mounted to a rig allowing it to free-fall into a deep-water tank (5.2m × 5.2m × 4.2m deep) from heights 0 <= H <= 635 mm, measured from the keel to the free surface. The wedge was instrumented to record vertical position, acceleration, and pressure on the bottom surface. A pressure mapping system, capable of measuring several points over the area of the thin (0.1 mm) film sensor at sampling rates up to 20 kHz, is used and compared to surface-mounted pressure transducers (sampled at 10 kHz). A high speed camera (1000 fps, resolution of 1920 × 1200 pixels) is mounted above the wedge model to record the wetted surface as the wedge descended below the free surface. The pressure measurements taken with both conventional surface pressure transducers and the pressure mapping system agree within 10% of the peak pressure values (0.7 bar, typical). Supported by the Office of Naval Research.

A feasibility study to estimate minimum surface-casing depths of oil and gas wells to prevent ground-water contamination in four areas of western Pennsylvania

USGS Publications Warehouse

Buckwalter, T.F.; Squillace, P.J.

1995-01-01

Hydrologic data were evaluated from four areas of western Pennsylvania to estimate the minimum depth of well surface casing needed to prevent contamination of most of the fresh ground-water resources by oil and gas wells. The areas are representative of the different types of oil and gas activities and of the ground-water hydrology of most sections of the Appalachian Plateaus Physiographic Province in western Pennsylvania. Approximate delineation of the base of the fresh ground-water system was attempted by interpreting the following hydrologic data: (1) reports of freshwater and saltwater in oil and gas well-completion reports, (2) water well-completion reports, (3) geophysical logs, and (4) chemical analyses of well water. Because of the poor quality and scarcity of ground-water data, the altitude of the base of the fresh ground-water system in the four study areas cannot be accurately delineated. Consequently, minimum surface-casing depths for oil and gas wells cannot be estimated with confidence. Conscientious and reliable reporting of freshwater and saltwater during drilling of oil and gas wells would expand the existing data base. Reporting of field specific conductance of ground water would greatly enhance the value of the reports of ground water in oil and gas well-completion records. Water-bearing zones in bedrock are controlled mostly by the presence of secondary openings. The vertical and horizontal discontinuity of secondary openings may be responsible, in part, for large differences in altitudes of freshwater zones noted on completion records of adjacent oil and gas wells. In upland and hilltop topographies, maximum depths of fresh ground water are reported from several hundred feet below land surface to slightly more than 1,000 feet, but the few deep reports are not substantiated by results of laboratory analyses of dissolved-solids concentrations. Past and present drillers for shallow oil and gas wells commonly install surface casing to below the base of readily observed fresh ground water. Casing depths are selected generally to maximize drilling efficiency and to stop freshwater from entering the well and subsequently interfering with hydrocarbon recovery. The depths of surface casing generally are not selected with ground-water protection in mind. However, on the basis of existing hydrologic data, most freshwater aquifers generally are protected with current casing depths. Minimum surface-casing depths for deep gas wells are prescribed by Pennsylvania Department of Environmental Resources regulations and appear to be adequate to prevent ground-water contamination, in most respects, for the only study area with deep gas fields examined in Crawford County.

Presence of noroviruses and other enteric viruses in sewage and surface waters in The Netherlands.

PubMed

Lodder, W J; de Roda Husman, A M

2005-03-01

Since virus concentrations in drinking waters are generally below the detection limit, the infectious risk from drinking water consumption requires assessment from the virus concentrations in source waters and removal efficiency of treatment processes. In this study, we estimated from reverse transcription-PCR on 10-fold serially diluted RNA that noroviruses, the most prevalent waterborne gastroenteritis agents, were present at 4 (0.2 to 38) to 4,900 (303 to 4.6 x 10(4)) PCR-detectable units (PDU) per liter of river water (ranges are given in parentheses). These virus concentrations are still high compared with 896 to 7,499 PDU/liter of treated sewage and 5,111 to 850,000 PDU/liter in raw sewage. Sequencing analyses designated human norovirus GGII.4 Lordsdale as the most prevalent strain in the sampling period 1998 to 1999 in both sewage and surface waters. Other GGII strains were also very abundant, indicating that the majority of the virus contamination was derived from urban sewage, although very divergent strains and one animal strain were also detected in the surface and sewage waters. Rotaviruses were also detected in two large rivers (the Maas and the Waal) at 57 to 5,386 PDU/liter. The high virus concentrations determined by PCR may in part be explained by the detection of virus RNA instead of infectious particles. Indeed, reoviruses and enteroviruses that can be cultured were present at much lower levels, of 0.3 to 1 and 2 to 10 PFU/liter, respectively. Assuming 1% of the noroviruses and rotaviruses to be infectious, a much higher disease burden than for other viruses can be expected, not only because of the higher levels but also because of these viruses' higher infectivity and attack rates.

Polydopamine-coated magnetic nanoparticles for isolation and enrichment of estrogenic compounds from surface water samples followed by liquid chromatography-tandem mass spectrometry determination.

PubMed

Capriotti, Anna Laura; Cavaliere, Chiara; La Barbera, Giorgia; Piovesana, Susy; Samperi, Roberto; Zenezini Chiozzi, Riccardo; Laganà, Aldo

2016-06-01

Estrogens, phytoestrogens, and mycoestrogens may enter into the surface waters from different sources, such as effluents of municipal wastewater treatment plants, industrial plants, and animal farms and runoff from agricultural areas. In this work, a multiresidue analytical method for the determination of 17 natural estrogenic compounds, including four steroid estrogens, six mycoestrogens, and seven phytoestrogens, in river water samples has been developed. (Fe3O4)-based magnetic nanoparticles coated by polydopamine (Fe3O4@pDA) were used for dispersive solid-phase extraction, and the final extract was analyzed by ultra-high performance liquid chromatography coupled with tandem mass spectrometry. The Fe3O4 magnetic nanoparticles were prepared by a co-precipitation procedure, coated by pDA, and characterized by scanning electron microscopy, infrared spectroscopy, and elemental analysis. The sample preparation method was optimized in terms of extraction recovery, matrix effect, selectivity, trueness, precision, method limits of detection, and method limits of quantification (MLOQs). For all the 17 analytes, recoveries were >70 % and matrix effects were below 30 % when 25 mL of river water sample was treated with 90 mg of Fe3O4@pDA nanoparticles. Selectivity was tested by spiking river water samples with 50 other compounds (mycotoxins, antibacterials, conjugated hormones, UV filters, alkylphenols, etc.), and only aflatoxins and some benzophenones showed recoveries >60 %. This method proved to be simple and robust and allowed the determination of natural estrogenic compounds belonging to different classes in surface waters with MLOQs ranging between 0.003 and 0.1 μg L(-1). Graphical Abstract Determination of natural estrogenic compounds in water by magnetic solid phase extraction followed by liquid chromatography-tandem mass spectrometry analysis.

Presence of Noroviruses and Other Enteric Viruses in Sewage and Surface Waters in The Netherlands

PubMed Central

Lodder, W. J.; de Roda Husman, A. M.

2005-01-01

Since virus concentrations in drinking waters are generally below the detection limit, the infectious risk from drinking water consumption requires assessment from the virus concentrations in source waters and removal efficiency of treatment processes. In this study, we estimated from reverse transcription-PCR on 10-fold serially diluted RNA that noroviruses, the most prevalent waterborne gastroenteritis agents, were present at 4 (0.2 to 38) to 4,900 (303 to 4.6 × 104) PCR-detectable units (PDU) per liter of river water (ranges are given in parentheses). These virus concentrations are still high compared with 896 to 7,499 PDU/liter of treated sewage and 5,111 to 850,000 PDU/liter in raw sewage. Sequencing analyses designated human norovirus GGII.4 Lordsdale as the most prevalent strain in the sampling period 1998 to 1999 in both sewage and surface waters. Other GGII strains were also very abundant, indicating that the majority of the virus contamination was derived from urban sewage, although very divergent strains and one animal strain were also detected in the surface and sewage waters. Rotaviruses were also detected in two large rivers (the Maas and the Waal) at 57 to 5,386 PDU/liter. The high virus concentrations determined by PCR may in part be explained by the detection of virus RNA instead of infectious particles. Indeed, reoviruses and enteroviruses that can be cultured were present at much lower levels, of 0.3 to 1 and 2 to 10 PFU/liter, respectively. Assuming 1% of the noroviruses and rotaviruses to be infectious, a much higher disease burden than for other viruses can be expected, not only because of the higher levels but also because of these viruses' higher infectivity and attack rates. PMID:15746348

The effect of surface characteristics on the transport of multiple Escherichia coli isolates in large scale columns of quartz sand.

PubMed

Lutterodt, G; Basnet, M; Foppen, J W A; Uhlenbrook, S

2009-02-01

Bacteria properties play an important role in the transport of bacteria in groundwater, but their role, especially for longer transport distances (>0.5 m) has not been studied. Thereto, we studied the effects of cell surface hydrophobicity, outer surface potential (OSP), cell sphericity, motility, and Ag43 protein expression on the outer cell surface for a number of E. coli strains, obtained from the environment on their transport behavior in columns of saturated quartz sand of 5 m height in two solutions: demineralized (DI) water and artificial groundwater (AGW). In DI water, sticking efficiencies ranged between 0.1 and 0.4 at the column inlet, and then decreased with transport distance to 0.02-0.2. In AGW, sticking efficiencies were on average 1log-unit higher than those in DI (water). Bacteria motility and Ag43 expression affected attachment with a (high) statistical significance. In contrast, hydrophobicity, OSP and cell sphericity did not significantly correlate with sticking efficiency. However, for transport distances more than 0.33 m, the correlation between sticking efficiency, Ag43 expression, and motility became insignificant. We concluded that Ag43 and motility played an important role in E. coli attachment to quartz grain surfaces, and that the transport distance dependent sticking efficiency reductions were caused by motility and Ag43 expression variations within a population. The implication of our findings is that less motile bacteria with little or no Ag43 expression may travel longer distances once they enter groundwater environments. In future studies, the possible effect of bacteria surface structures, like fimbriae, pili and surface proteins on bacteria attachment need to be considered more systematically in order to arrive at more meaningful inter-population comparisons of the transport behavior of E. coli strains in aquifers.

Nitrate Accumulation and Leaching in Surface and Ground Water Based on Simulated Rainfall Experiments

PubMed Central

Wang, Hong; Gao, Jian-en; Li, Xing-hua; Zhang, Shao-long; Wang, Hong-jie

2015-01-01

To evaluate the process of nitrate accumulation and leaching in surface and ground water, we conducted simulated rainfall experiments. The experiments were performed in areas of 5.3 m2 with bare slopes of 3° that were treated with two nitrogen fertilizer inputs, high (22.5 g/m2 NH4NO3) and control (no fertilizer), and subjected to 2 hours of rainfall, with. From the 1st to the 7th experiments, the same content of fertilizer mixed with soil was uniformly applied to the soil surface at 10 minutes before rainfall, and no fertilizer was applied for the 8th through 12th experiments. Initially, the time-series nitrate concentration in the surface flow quickly increased, and then it rapidly decreased and gradually stabilized at a low level during the fertilizer experiments. The nitrogen loss in the surface flow primarily occurred during the first 18.6 minutes of rainfall. For the continuous fertilizer experiments, the mean nitrate concentrations in the groundwater flow remained at less than 10 mg/L before the 5th experiment, and after the 7th experiment, these nitrate concentrations were greater than 10 mg/L throughout the process. The time-series process of the changing concentration in the groundwater flow exhibited the same parabolic trend for each fertilizer experiment. However, the time at which the nitrate concentration began to change lagged behind the start time of groundwater flow by approximately 0.94 hours on average. The experiments were also performed with no fertilizer. In these experiments, the mean nitrate concentration of groundwater initially increased continuously, and then, the process exhibited the same parabolic trend as the results of the fertilization experiments. The nitrate concentration decreased in the subsequent experiments. Eight days after the 12 rainfall experiments, 50.53% of the total nitrate applied remained in the experimental soil. Nitrate residues mainly existed at the surface and in the bottom soil layers, which represents a potentially more dangerous pollution scenario for surface and ground water. The surface and subsurface flow would enter into and contaminate water bodies, thus threatening the water environment. PMID:26291616

Nitrate Accumulation and Leaching in Surface and Ground Water Based on Simulated Rainfall Experiments.

PubMed

Wang, Hong; Gao, Jian-en; Li, Xing-hua; Zhang, Shao-long; Wang, Hong-jie

2015-01-01

To evaluate the process of nitrate accumulation and leaching in surface and ground water, we conducted simulated rainfall experiments. The experiments were performed in areas of 5.3 m2 with bare slopes of 3° that were treated with two nitrogen fertilizer inputs, high (22.5 g/m2 NH4NO3) and control (no fertilizer), and subjected to 2 hours of rainfall, with. From the 1st to the 7th experiments, the same content of fertilizer mixed with soil was uniformly applied to the soil surface at 10 minutes before rainfall, and no fertilizer was applied for the 8th through 12th experiments. Initially, the time-series nitrate concentration in the surface flow quickly increased, and then it rapidly decreased and gradually stabilized at a low level during the fertilizer experiments. The nitrogen loss in the surface flow primarily occurred during the first 18.6 minutes of rainfall. For the continuous fertilizer experiments, the mean nitrate concentrations in the groundwater flow remained at less than 10 mg/L before the 5th experiment, and after the 7th experiment, these nitrate concentrations were greater than 10 mg/L throughout the process. The time-series process of the changing concentration in the groundwater flow exhibited the same parabolic trend for each fertilizer experiment. However, the time at which the nitrate concentration began to change lagged behind the start time of groundwater flow by approximately 0.94 hours on average. The experiments were also performed with no fertilizer. In these experiments, the mean nitrate concentration of groundwater initially increased continuously, and then, the process exhibited the same parabolic trend as the results of the fertilization experiments. The nitrate concentration decreased in the subsequent experiments. Eight days after the 12 rainfall experiments, 50.53% of the total nitrate applied remained in the experimental soil. Nitrate residues mainly existed at the surface and in the bottom soil layers, which represents a potentially more dangerous pollution scenario for surface and ground water. The surface and subsurface flow would enter into and contaminate water bodies, thus threatening the water environment.

Nutrients and water masses in the Gulf of Maine - Georges Bank region: Variability and importance to blooms of the toxic dinoflagellate Alexandrium fundyense.

PubMed

Townsend, D W; McGillicuddy, D J; Thomas, M A; Rebuck, N R

2014-05-01

We report here the results of ten oceanographic survey cruises carried out in the Gulf of Maine - Georges Bank region of the Northwest Atlantic during the late spring to summer period in 2007, 2008 and 2010, for which we examine and characterize relationships among dissolved inorganic nutrient fields, water mass dynamics and cell densities of the toxic dinoflagellate Alexandrium fundyense . Nutrients are supplied to continental shelf waters of the Gulf of Maine - Georges Bank region by inflows of deep offshore water masses; once in the Gulf they are transported with the residual circulation and mix with surface waters, both in the Gulf and on the Bank. Those fluxes of offshore water masses and their nutrient loads are the major source of nutrients for phytoplankton production in the region, including annual blooms of A. fundyense in the Gulf and on Georges Bank. This much is already known. We suggest here that the locations and magnitude of A. fundyense blooms are controlled in part by variable nutrient fluxes to the interior Gulf of Maine from offshore, and, those interior Gulf of Maine waters are, in turn, the main nutrient source to Georges Bank, which are brought onto the Bank by tidal pumping on the Northern Flank. We present evidence that nitrate is the initial form of nitrogenous nutrient for A. fundyense blooms, but it is quickly depleted to limiting concentrations of less than 0.5 μM, at which time continued growth and maintenance of the population is likely fueled by recycled ammonium. We also show that phosphate may be the limiting nutrient over much of Georges Bank in summer, allowing recycled ammonium concentrations to increase. Our temperature-salinity analyses reveal spatial and temporal (seasonal and interannual) variability in the relative proportions of two deep source waters that enter the Gulf of Maine at depth through the Northeast Channel: Warm Slope Water (WSW) and Labrador Slope Water (LSW). Those two source waters are known to vary in their nutrient loads, with nitrate concentrations about 50% higher in WSW than LSW, for example, and as such the proportions of these two water masses to one another are important determinants of the overall nutrient loads in the interior Gulf. In addition to these deep slope water fluxes, we show evidence here of episodic fluxes of relatively fresh and low-nutrient shelf waters from the Nova Scotian Shelf, which enter the Gulf in pulses at depths between the surface and approximately 150 m, displacing deep slope waters, and consequently they significantly dilute the Gulf's interior waters, reducing nutrient concentrations and, in turn, affect the magnitude of A. fundyense blooms.

Nutrients and water masses in the Gulf of Maine - Georges Bank region: Variability and importance to blooms of the toxic dinoflagellate Alexandrium fundyense

PubMed Central

Townsend, D.W.; McGillicuddy, D.J.; Thomas, M.A.; Rebuck, N.R.

2015-01-01

We report here the results of ten oceanographic survey cruises carried out in the Gulf of Maine - Georges Bank region of the Northwest Atlantic during the late spring to summer period in 2007, 2008 and 2010, for which we examine and characterize relationships among dissolved inorganic nutrient fields, water mass dynamics and cell densities of the toxic dinoflagellate Alexandrium fundyense. Nutrients are supplied to continental shelf waters of the Gulf of Maine - Georges Bank region by inflows of deep offshore water masses; once in the Gulf they are transported with the residual circulation and mix with surface waters, both in the Gulf and on the Bank. Those fluxes of offshore water masses and their nutrient loads are the major source of nutrients for phytoplankton production in the region, including annual blooms of A. fundyense in the Gulf and on Georges Bank. This much is already known. We suggest here that the locations and magnitude of A. fundyense blooms are controlled in part by variable nutrient fluxes to the interior Gulf of Maine from offshore, and, those interior Gulf of Maine waters are, in turn, the main nutrient source to Georges Bank, which are brought onto the Bank by tidal pumping on the Northern Flank. We present evidence that nitrate is the initial form of nitrogenous nutrient for A. fundyense blooms, but it is quickly depleted to limiting concentrations of less than 0.5 μM, at which time continued growth and maintenance of the population is likely fueled by recycled ammonium. We also show that phosphate may be the limiting nutrient over much of Georges Bank in summer, allowing recycled ammonium concentrations to increase. Our temperature-salinity analyses reveal spatial and temporal (seasonal and interannual) variability in the relative proportions of two deep source waters that enter the Gulf of Maine at depth through the Northeast Channel: Warm Slope Water (WSW) and Labrador Slope Water (LSW). Those two source waters are known to vary in their nutrient loads, with nitrate concentrations about 50% higher in WSW than LSW, for example, and as such the proportions of these two water masses to one another are important determinants of the overall nutrient loads in the interior Gulf. In addition to these deep slope water fluxes, we show evidence here of episodic fluxes of relatively fresh and low-nutrient shelf waters from the Nova Scotian Shelf, which enter the Gulf in pulses at depths between the surface and approximately 150 m, displacing deep slope waters, and consequently they significantly dilute the Gulf's interior waters, reducing nutrient concentrations and, in turn, affect the magnitude of A. fundyense blooms. PMID:26028824

Concentration data for anthropogenic organic compounds in ground water, surface water, and finished water of selected community water systems in the United States, 2002-05

USGS Publications Warehouse

Carter, Janet M.; Delzer, Gregory C.; Kingsbury, James A.; Hopple, Jessica A.

2007-01-01

The National Water-Quality Assessment Program of the U.S. Geological Survey began implementing Source Water-Quality Assessments (SWQAs) in 2001 that focus on characterizing the quality of source water and finished water of aquifers and major rivers used by some of the larger community water systems (CWSs) in the United States. As used for SWQA studies, source water is the raw (ambient) water collected at the supply well prior to water treatment (for ground water) or the raw (ambient) water collected from the river near the intake (for surface water), and finished water is the water that is treated and ready to be delivered to consumers. Finished water is collected before entering the distribution system. SWQA studies are conducted in two phases, and the objectives of SWQA studies are twofold: (1) to determine the occurrence and, for rivers, seasonal changes in concentrations of a broad list of anthropogenic organic compounds (AOCs) in aquifers and rivers that have some of the largest withdrawals for drinking-water supply (phase 1), and (2) for those AOCs found to occur most frequently in source water, characterize the extent to which these compounds are present in finished water (phase 2). These objectives were met for SWQA studies by collecting ground-water and surface-water (source) samples and analyzing these samples for 258 AOCs during phase 1. Samples from a subset of wells and surface-water sites located in areas with substantial agricultural production in the watershed were analyzed for 19 additional AOCs, for a total of 277 compounds analyzed for SWQA studies. The 277 compounds were classified according to the following 13 primary use or source groups: (1) disinfection by-products; (2) fumigant-related compounds; (3) fungicides; (4) gasoline hydrocarbons, oxygenates, and oxygenate degradates; (5) herbicides and herbicide degradates; (6) insecticides and insecticide degradates; (7) manufacturing additives; (8) organic synthesis compounds; (9) pavement- and combustion-derived compounds; (10) personal care and domestic use products; (11) plant- or animal-derived biochemicals; (12) refrigerants and propellants; and (13) solvents. Source and finished water samples were collected during phase 2 and analyzed for constituents that were detected frequently during phase 1. This report presents concentration data for AOCs in ground water, surface water, and finished water of CWSs sampled for SWQA studies during 2002-05. Specifically, this report presents the analytical results of samples collected during phase 1 including (1) samples from 221 wells that were analyzed for 258 AOCs; (2) monthly samples from 9 surface-water sites that were analyzed for 258 AOCs during phase 1; and (3) samples from a subset of the wells and surface-water sites located in areas with substantial agricultural production that were analyzed for 3 additional pesticides and 16 pesticide degradates. Samples collected during phase 2 were analyzed for selected AOCs that were detected most frequently in source water during phase 1 sampling; analytical results for phase 2 are presented for (1) samples of source water and finished water from 94 wells; and (2) samples of source water and finished water samples that were collected monthly and during selected flow conditions at 8 surface-water sites. Results of quality-assurance/quality-control samples collected for SWQA studies during 2002-05 also are presented.

Water quality in the Withers Swash Basin, with emphasis on enteric bacteria, Myrtle Beach, South Carolina, 1991-93

USGS Publications Warehouse

Guimaraes, W.B.

1995-01-01

Water samples were collected in 1991-93 from Withers Swash and its two tributaries (the Mainstem and KOA Branches) in Myrtle Beach, S.C., and analyzed for physical properties, organic and inorganic constituents, and fecal coliform and streptococcus bacteria. Samples were collected during wet- and dry-weather conditions to assess the water quality of the streams before and after storm runoff. Water samples were analyzed for over 200 separate physical, chemical, and biological constituents. Concentrations of 11 constituents violated State criteria for shellfish harvesting waters, and State Human Health Criteria. The 11 constituents included concentrations of dissolved oxygen, arsenic, lead, cadmium, mercury, chlordane, dieldrin, 1,1,1-trichloroethane, 1,1-dichloroethylene, trichloroethylene, and fecal coliform bacteria. Water samples were examined for the presence of enteric bacteria (fecal coliform and fecal streptococcus) at 46 sites throughout the Withers Swash Basin and 5 sites on the beach and in the Atlantic Ocean. Water samples were collected just upstream from all confluences in order to determine sources of bacterial contamination. Temporally and spatially high concentrations of enteric bacteria were detected throughout the Withers Swash Basin; however, these sporadic bacteria concentrations made it difficult to determine a single source of the contamination. These enteric bacteria concentrations are probably derived from a number of sources in the basin including septic tanks, garbage containers, and the feces of waterfowl and domestic animals.

Nutrient transport through a Vegetative Filter Strip with subsurface drainage.

PubMed

Bhattarai, Rabin; Kalita, Prasanta Kumar; Patel, Mita Kanu

2009-04-01

The transport of nutrients and soil sediments in runoff has been recognized as a noteworthy environmental issue. Vegetative Filter Strips (VFS) have been used as one of the best management practices (BMPs) for retaining nutrients and sediments from surface runoff, thus preventing the pollutants from reaching receiving waters. However, the effectiveness of a VFS when combined with a subsurface drainage system has not been investigated previously. This study was undertaken to monitor the retention and transport of nutrients within a VFS that had a subsurface drainage system installed at a depth of 1.2 m below the soil surface. Nutrient concentrations of NO(3)-N (Nitrate Nitrogen), PO(-)(4) (Orthophosphorus), and TP (Total Phosphorus) were measured in surface water samples (entering and leaving the VFS), and subsurface outflow. Soil samples were collected and analyzed for plant available Phosphorus (Bray P1) and NO(3)-N concentrations. Results showed that PO(-)(4), NO(3)-N, and TP concentrations decreased in surface flow through the VFS. Many surface outflow water samples from the VFS showed concentration reductions of as much as 75% for PO(-)(4) and 70% for TP. For subsurface outflow water samples through the drainage system, concentrations of PO(-)(4) and TP decreased but NO(3)-N concentrations increased in comparison to concentrations in surface inflow samples. Soil samples that were collected from various depths in the VFS showed a minimal buildup of nutrients in the top soil profile but indicated a gradual buildup of nutrients at the depth of the subsurface drain. Results demonstrate that although a VFS can be very effective in reducing runoff and nutrients from surface flow, the presence of a subsurface drain underneath the VFS may not be environmentally beneficial. Such a combination may increase NO(3)-N transport from the VFS, thus invalidating the purpose of the BMP.

40 CFR 63.1409 - Heat exchange system provisions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... locations where the cooling water enters and exits each heat exchanger or any combination of heat exchangers.... (iii) For samples taken at the entrance and exit of each heat exchanger or any combination of heat exchangers, the entrance is the point at which the cooling water enters the individual heat exchanger or...

9 CFR 381.305 - Equipment and procedures for heat processing systems.

Code of Federal Regulations, 2010 CFR

2010-01-01

... control unit. A nonreturn valve shall be provided in the air supply line to prevent water from entering... control unit. A nonreturn valve shall be provided in the air supply line to prevent water from entering... supply of clean, dry air. The recorder timing mechanism shall be accurate. (i) Chart-type devices...

Use of propidium monoazide in reverse transcriptase PCR to distinguish between infectious and noninfectious enteric viruses in water samples

EPA Science Inventory

Human enteric viruses can be present in untreated and inadequately treated drinking water. Molecular methods, such as the reverse transcriptase PCR (RT-PCR), can detect viral genomes in a few hours, but they cannot distinguish between infectious and noninfectious viruses. Since o...

40 CFR 63.1409 - Heat exchange system provisions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... locations where the cooling water enters and exits each heat exchanger or any combination of heat exchangers.... (iii) For samples taken at the entrance and exit of each heat exchanger or any combination of heat exchangers, the entrance is the point at which the cooling water enters the individual heat exchanger or...

Hydrogeological and statistical evidence for wide-spread enteric virus contamination of deep municipal wells

USDA-ARS?s Scientific Manuscript database

Over the past eight years our research group has repeatedly detected human enteric viruses in water produced from deep (over 800 ft) bedrock water-supply wells in Madison, WI. The likely source of the viruses is leakage from urban sewers. These virus detections have been surprising because human ent...

Water use and quality of fresh surface-water resources in the Barataria-Terrebonne Basins, Louisiana

USGS Publications Warehouse

Johnson-Thibaut, Penny M.; Demcheck, Dennis K.; Swarzenski, Christopher M.; Ensminger, Paul A.

1998-01-01

Approximately 170 Mgal/d (million gallons per day) of ground- and surface-water was withdrawn from the Barataria-Terrebonne Basins in 1995. Of this amount, surface water accounted for 64 percent ( 110 MgaVd) of the total withdrawal rates in the basins. The largest surface-water withdrawal rates were from Bayou Lafourche ( 40 Mgal/d), Bayou Boeuf ( 14 MgaVd), and the Gulf Intracoastal Waterway (4.2 Mgal/d). The largest ground-water withdrawal rates were from the Mississippi River alluvial aquifer (29 Mgal/d), the Gonzales-New Orleans aquifer (9.5 Mgal/d), and the Norco aquifer (3.6 MgaVd). The amounts of water withdrawn in the basins in 1995 differed by category of use. Public water suppliers within the basins withdrew 41 Mgal/d of water. The five largest public water suppliers in the basins withdrew 30 Mgal/d of surface water: Terrebonne Waterworks District 1 withdrew the largest amount, almost 15 MgaVd. Industrial facilities withdrew 88 Mgal/d, fossil-fuel plants withdrew 4.7 MgaVd, and commercial facilities withdrew 0.67 MgaVd. Aggregate water-withdrawal rates, compiled by parish for aquaculture (37 Mgal/d), livestock (0.56 Mgal/d), rural domestic (0.44 MgaVd), and irrigation uses (0.54 MgaVd), totaled about 38 MgaVd in the basins. Ninety-five percent of aquaculture withdrawal rates, primarily for crawfish and alligator farming, were from surface-water sources. >br> Total water-withdrawal rates increased 221 percent from 1960–95. Surface-water withdrawal rates have increased by 310 percent, and ground-water withdrawal rates have increased by 133 percent. The projection for the total water-withdrawal rates in 2020 is 220 MgaVd, an increase of 30 percent from 1995. Surface-water withdrawal rates would account for 59 percent of the total, or 130 Mgal/d. Surface-water withdrawal rates are projected to increase by 20 percent from 1995 to 2020. Analysis of water-quality data from the Mississippi River indicates that the main threats to surface water resources are from the herbicide atrazine and excessive nutrients. Atrazine concentrations in the Mississippi River at Baton Rouge briefly exceed the U.S. Environmental Protection Agency maximum contaminant level of 3.0 micrograms per liter during periods in the late spring and early summer. Trace metals in bottom material collected from Bayou Lafourche indicate that the reach of Bayou Lafourche from Donaldsonville to Golden Meadow is adversely affected by low-level contamination. Dissolved nitrate had a mean concentration of 1.4 milligrams per liter in the Mississippi River near Bayou Lafourche and can contribute to excessive plant growth. Long-term salinity records near Bayou Lafourche indicate no pronounced trends, with the exception of the Gulf Intracoastal Waterway at Houma. At this site, salinities remained low until 1961, when the Gulf Intracoastal Waterway was connected to the Gulf of Mexico by the Houma Navigation Canal. The sources of saltwater are variable. Some saltwater has entered Bayou Lafourche south of the Gulf Intracoastal Waterway; at other times saltwater has moved up the Houma Navigation Canal and has flowed east in the Gulf Intracoastal Waterway, north into Company Canal, and southeast in Bayou Lafourche towards Larose, Louisiana.

Ancestral irrigation method by kanis in Bolivia

NASA Astrophysics Data System (ADS)

Roldán-Cañas, José; Chipana, René; Fátima Moreno-Pérez, María

2015-04-01

Irrigation in the Andean region is an ancient practice. For centuries, farmers were able to use the waters of rivers, lakes and springs to complement or supplement the scarce rainfall regime. The inter-Andean valleys of the Department of La Paz are the best areas for the study of traditional irrigation systems. This work has been carried out in the community of Jatichulaya located in te town of Charazani, 300 km from the city of La Paz, which lies 3250 meters above sea level. The annual rainfall ranges around 450 mm distributed mainly between the months of December to March. Therefore, water is needed to achieve adequate crop yields. The traditional irrigation system is done by the method of Kanis, consisting of a surface irrigation already developed by traditional Andean cultures of the country, in harmony with the ecological and productive characteristics of the area. Water enters the irrigation plot through a main channel (mama kani) from which the secondary channels (juchuy kanis) are derived. The fundamental characteristic of this irrigation is that these channels are open at the same time the water enters into the plot. The system works properly, adapting to the topography of the area. The irrigation method practiced in this community does not cause water erosion of soils because water management within the plot is based on the ancient knowledge of farmers following the contour lines. This practice allows good irrigation development and soil protection without causing any problems. However, it was evident a high use of labor in irrigation practice. Irrigation scheduling is done according to requests made by the irrigators in a given period. Delivering of water to the farmers is made by the so-called Water Agent (Agente de Aguas) or person in charge of the distribution of water. The Water Agent is elected annually and its functions include the maintenance and care of all system waterworks. The period between August and January is the highest water demand and, therefore, the water is distributed by turns among irrigators. Turns usually depend on water availability. Water Agent distributes water equitably without giving preference to anyone.

Reverse Osmosis Water Purification Unit: Efficacy of Cartridge Filters for Removal of Bacteria and Protozoan Cysts when Ro Elements are Bypassed

DTIC Science & Technology

1993-04-01

were Klebsiella terrigena, Cryptosporidium parvum oocysts, Rhodotorula rubra, and 3.7 pm latex beads. Challenge waters were dechlorinated tap water and...The morphological and size characteristics of Rhodotorula rubra (ATCC 36053) made the yeast suitable as a protozoan cyst simulant. The yeast cells...representative enteric bacterium), Cryptosporidium parvum (an enteric protozoan pathogen) oocysts, Rhodotorula rubra (a yeast, used to test prefilters only

The Runaway Greenhouse Effect on Earth and other Planets

NASA Technical Reports Server (NTRS)

Rabbette, Maura; Pilewskie, Peter; McKay, Christopher; Young, Robert

2001-01-01

Water vapor is an efficient absorber of outgoing longwave infrared radiation on Earth and is the primary greenhouse gas. Since evaporation increases with increasing sea surface temperature, and the increase in water vapor further increases greenhouse warming, there is a positive feedback. The runaway greenhouse effect occurs if this feedback continues unchecked until all the water has left the surface and enters the atmosphere. For Mars and the Earth the runaway greenhouse was halted when water vapor became saturated with respect to ice or liquid water respectively. However, Venus is considered to be an example of a planet where the runaway greenhouse effect did occur, and it has been speculated that if the solar luminosity were to increase above a certain limit, it would also occur on the Earth. Satellite data acquired during the Earth Radiation Budget Experiment (ERBE) under clear sky conditions shows that as the sea surface temperature (SST) increases, the rate of outgoing infrared radiation at the top of the atmosphere also increases, as expected. Over the pacific warm pool where the SST exceeds 300 K the outgoing radiation emitted to space actually decreases with increasing SST, leading to a potentially unstable system. This behavior is a signature of the runaway greenhouse effect on Earth. However, the SST never exceeds 303K, thus the system has a natural cap which stops the runaway. According to Stefan-Boltzmann's law the amount of heat energy radiated by the Earth's surface is proportional to (T(sup 4)). However, if the planet has a substantial atmosphere, it can absorb all infrared radiation from the lower surface before the radiation penetrates into outer space. Thus, an instrument in space looking at the planet does not detect radiation from the surface. The radiation it sees comes from some level higher up. For the earth#s atmosphere the effective temperature (T(sub e)) has a value of 255 K corresponding to the middle troposphere, above most of the water vapor and clouds. "Additional information is contained in the original extended abstract."

Water for Agriculture: the Convergence of Sustainability and Safety.

PubMed

Markland, Sarah M; Ingram, David; Kniel, Kalmia E; Sharma, Manan

2017-05-01

Agricultural water is a precious and limited resource. Increasingly more water types and sources are being explored for use in irrigation within the United States and across the globe. As outlined in this chapter, the Produce Safety Rule (PSR) in the Food Safety and Modernization Act (FSMA) provide irrigation water standards for application of water to fruits and vegetables consumed raw. These rules for production and use of water will continue to develop and be required as the world experiences aspects of a changing climate including flooding as well as drought conditions. Research continues to assess the use of agricultural water types. The increased use of reclaimed water in the United States as well as for selected irrigation water needs for specific crops may provide increased water availability. The use of surface water can be used in irrigation as well, but several studies have shown the presence of some enteric bacterial pathogens (enterohemorrhagic E. coli , Salmonella spp. and Listeria monocytogenes ) in these waters that may contaminate fruits and vegetables. There have been outbreaks of foodborne illness in the U.S., South America, Europe, and Australia related to the use of contaminated water in fruit and vegetable irrigation or washing. Unreliable water supplies, more stringent microbial water standards, mitigation technologies and expanded uses of reclaimed waters have all increased interest in agricultural water.

Risk characterization of methyl tertiary butyl ether (MTBE) in tap water.

PubMed

Stern, B R; Tardiff, R G

1997-12-01

Methyl tertiary butyl ether (MTBE) can enter surface water and groundwater through wet atmospheric deposition or as a result of fuel leaks and spills. About 30% of the U.S. population lives in areas where MTBE is in regular use. Ninety-five percent of this population is unlikely to be exposed to MTBE in tap water at concentrations exceeding 2 ppb, and most will be exposed to concentrations that are much lower and may be zero. About 5% of this population may be exposed to higher levels of MTBE in tap water, resulting from fuel tank leaks and spills into surface or groundwater used for potable water supplies. This paper describes the concentration ranges found and anticipated in surface and groundwater, and estimates the distribution of doses experienced by humans using water containing MTBE to drink, prepare food, and shower/bathe. The toxic properties (including potency) of MTBE when ingested, inhaled, and in contact with the skin are summarized. Using a range of human toxic potency values derived from animal studies, margins of exposure (MOE) associated with alternative chronic exposure scenarios are estimated to range from 1700 to 140,000. Maximum concentrations of MTBE in tap water anticipated not to cause adverse health effects are determined to range from 700 to 14,000 ppb. The results of this analysis demonstrate that no health risks are likely to be associated with chronic and subchronic human exposures to MTBE in tap water. Although some individuals may be exposed to very high concentrations of MTBE in tap water immediately following a localized spill, these exposures are likely to be brief in duration due to large-scale dilution and rapid volatilization of MTBE, the institution of emergency response and remediation measures to minimize human exposures, and the low taste and odor thresholds of MTBE which ensure that its presence in tap water is readily detected at concentrations well below the threshold for human injury.

Stratospheric water vapor feedback

PubMed Central

Dessler, A. E.; Schoeberl, M. R.; Wang, T.; Davis, S. M.; Rosenlof, K. H.

2013-01-01

We show here that stratospheric water vapor variations play an important role in the evolution of our climate. This comes from analysis of observations showing that stratospheric water vapor increases with tropospheric temperature, implying the existence of a stratospheric water vapor feedback. We estimate the strength of this feedback in a chemistry–climate model to be +0.3 W/(m2⋅K), which would be a significant contributor to the overall climate sensitivity. One-third of this feedback comes from increases in water vapor entering the stratosphere through the tropical tropopause layer, with the rest coming from increases in water vapor entering through the extratropical tropopause. PMID:24082126

Water pollution control technology and strategy for river-lake systems: a case study in Gehu Lake and Taige Canal.

PubMed

Zhang, Yimin; Zhang, Yongchun; Gao, Yuexiang; Zhang, Houhu; Cao, Jianying; Cai, Jinbang; Kong, Xiangji

2011-07-01

The Taoge water system is located in the upstream of Taihu Lake basin and is characterized by its multi-connected rivers and lakes. In this paper, current analyses of hydrology, hydrodynamics and water pollution of Gehu Lake and Taige Canal are presented. Several technologies are proposed for pollution prevention and control, and water environmental protection in the Taihu Lake basin. These included water pollution control integration technology for the water systems of Gehu Lake, Taige Canal and Caoqiao River. Additionally, river-lake water quality and quantity regulation technology, ecological restoration technology for polluted and degraded water bodies, and water environmental integration management and optimization strategies were also examined. The main objectives of these strategies are to: (a) improve environmental quality of relative water bodies, prevent pollutants from entering Gehu Lake and Taige Canal, and ensure that the clean water after the pre-treatment through Gehu Lake is not polluted before entering the Taihu Lake through Taige Canal; (b) stably and efficiently intercept and decrease the pollution load entering the lake through enhancing the river outlet ecological system structure function and water self-purifying capacity, and (c) designate Gehu Lake as a regulation system for water quality and water quantity in the Taoge water system and thus guarantee the improvement of the water quality of the inflow into Taihu Lake.

The mechanisms of filter feeding on oil droplets: Theoretical considerations.

PubMed

Mehrabian, Sasan; Letendre, Francis; Cameron, Christopher B

2018-04-01

Filter feeding animals capture food particles and oil droplets from the fluid environment using cilia or appendages composed of arrays of fibers. Here we review the theoretical models that have provided a foundation for observations on the efficiency of particle capture. We then provide the mathematical theoretical framework to characterize the efficient filtration of oil droplets. In the aquatic and marine environments oil droplets are released from the decay of organisms or as hydrocarbons. Droplet size and flow velocity, oil-to-water viscosity ratio, oil-water interfacial tension, oil and water density difference, and the surface wettability, or surface texture, of the filter fiber are the key parameters for oil droplet capture. Following capture, capillary force maintains the droplet at its location due to the oil-water interfacial tension. If the oil-coated fiber is subject to any external force such as viscous or gravitational forces, it may deform and separate from the fiber and re-enter the fluid stream. We show oil droplet capture in Daphnia and the barnacle Balanus glandula, and outline some of the ecological unknowns regarding oil capture in the oceans. Awareness of these mechanisms and their interrelationships will provide a foundation for investigations into the efficiency of various modes of filter feeding on oil droplets. Copyright © 2018 Elsevier Ltd. All rights reserved.

Tire wear particles in the aquatic environment - A review on generation, analysis, occurrence, fate and effects.

PubMed

Wagner, Stephan; Hüffer, Thorsten; Klöckner, Philipp; Wehrhahn, Maren; Hofmann, Thilo; Reemtsma, Thorsten

2018-08-01

Tire wear particles (TWP), generated from tire material during use on roads have gained increasing attention as part of organic particulate contaminants, such as microplastic, in aquatic environments. The available information on properties and generation of TWP, analytical techniques to determine TWP, emissions, occurrence and behavior and ecotoxicological effects of TWP are reviewed with a focus on surface water as a potential receptor. TWP emissions are traffic related and contribute 5-30% to non-exhaust emissions from traffic. The mass of TWP generated is estimated at 1,327,000 t/a for the European Union, 1,120,000 t/a for the United States and 133,000 t/a for Germany. For Germany, this is equivalent to four times the amount of pesticides used. The mass of TWP ultimately entering the aquatic environment strongly depends on the extent of collection and treatment of road runoff, which is highly variable. For the German highways it is estimated that up to 11,000 t/a of TWP reach surface waters. Data on TWP concentrations in the environment, including surface waters are fragmentary, which is also due to the lack of suitable analytical methods for their determination. Information on TWP properties such as density and size distribution are missing; this hampers assessing the fate of TWP in the aquatic environment. Effects in the aquatic environment may stem from TWP itself or from compounds released from TWP. It is concluded that reliable knowledge on transport mechanism to surface waters, concentrations in surface waters and sediments, effects of aging, environmental half-lives of TWP as well as effects on aquatic organisms are missing. These aspects need to be addressed to allow for the assessment of risk of TWP in an aquatic environment. Copyright © 2018 Elsevier Ltd. All rights reserved.

FURTHER STUDIES ON THE KINETICS OF OSMOSIS IN LIVING CELLS

PubMed Central

Lucké, Balduin; Hartline, H. Keffer; McCutcheon, Morton

1931-01-01

Using unfertilized eggs of Arbacia punctulata as natural osmometers an attempt has been made to account for the course of swelling and shrinking of these cells in anisotonic solutions by means of the laws governing osmosis and diffusion. The method employed has been to compute permeability of the cell to water, as measured by the rate of volume change per unit of cell surface per unit of osmotic pressure outstanding between the cell and its medium. Permeability to water as here defined and as somewhat differently defined by Northrop is approximately constant during swelling and shrinking, at least for the first several minutes of these processes. Permeability is found to be independent of the osmotic pressure of the solution in which cells are swelling. Water is found to leave cells more readily than it enters, that is, permeability is greater during exosmosis than during endosmosis. PMID:19872594

In vivo assessing of nanometric changes on the surface of whole tomatoes that have been inoculated with Candida guilliermondii yeast.

PubMed

Infante, Esperanza Del Pilar

2014-08-01

The cuticle of plants that covers the epidermis of cells, an interface between the fruit and the environment, has an important role to play in fruit quality because it prevents water loss and mechanical damage while simultaneously forming a barrier as it prevents phytopathogens from entering the fruit. All these factors give rise to flaws in the appearance of the fruit, thus contributing to marketing problems in the form of financial loss. In the search for solutions to some of these problems, certain biocontrolling yeasts have been introduced in the last few years. In the study described here, the changes observed on the surface of the whole tomato were evaluated in vivo during the first 72 h after inoculation by spraying Candida guilliermondii yeast onto the fruit's surface. The measurements were taken on a nanometric scale using atomic force microscopy; images were created in both contact and tapping modes. The results showed diminished roughness of the surface, which could contribute to reduced phytopathogen adherence due to the thinner contact area. These results furthermore showed that a yeast biofilm was formed on the fruit which probably helps to improve water retention inside the fruit. © 2014 Federation of European Microbiological Societies. Published by John Wiley & Sons Ltd. All rights reserved.

9 CFR 318.305 - Equipment and procedures for heat processing systems.

Code of Federal Regulations, 2010 CFR

2010-01-01

... control unit. A nonreturn valve shall be provided in the air supply line to prevent water from entering... control unit. A nonreturn valve shall be provided in the air supply line to prevent water from entering... ensure a supply of clean, dry air. The recorder timing mechanism shall be accurate. (i) Chart-type...

Relationship between viral detection and turbidity in a watershed contaminated with group A rotavirus.

PubMed

Assis, Andrêssa Silvino Ferreira; Cruz, Lucas Taffarel; Ferreira, Aline Siqueira; Bessa, Martha Eunice; de Oliveira Pinto, Miriam Aparecida; Vieira, Carmen Baur; Otenio, Marcelo Henrique; Miagostovich, Marize Pereira; da Rosa E Silva, Maria Luzia

2015-05-01

Enteric viruses are present in aquatic environments due to contamination by raw sewage, even in the absence of fecal coliforms, which are considered to be significant indicators when it comes to microbial water quality assessment. This study investigated the presence of group A rotavirus (RVA) in surface water from a river basin in Minas Gerais, Brazil, assessing the influence of the urbanization, the rainfall, and the microbiological and physico-chemical parameters regarding water quality. Forty-eight surface water samples collected in urbanized and non-urbanized areas, both in dry and rainy periods, were obtained throughout the study. The viral particles were concentrated by adsorption-elution in a negatively charged membrane. Fecal coliforms, as well as physico-chemical water parameters were determined at each point in all collections. The RVA was detected in 62.5 % (30/48) of the water samples through a real-time PCR assay. All the sequenced RVA strains belonged to genotype I1. The RVA was detected in 50.0 % (11/22) of the water samples regarded as being acceptable by current microbiological standards. The presence of the RVA and the viral load were influenced by the collection area (p < 0.05). It was also observed a significant association between the RVA and detecting the turbidity of water (p < 0.05). The collected data showed a high level of contamination in this watershed by the discharge of raw sewage, highlighting the need for urgent measures to improve water quality, ensuring the safe use of this matrix.

Implications of biofilm-associated waterborne Cryptosporidium oocysts for the water industry.

PubMed

Angles, Mark L; Chandy, Joseph P; Cox, Peter T; Fisher, Ian H; Warnecke, Malcolm R

2007-08-01

Waterborne Cryptosporidium has been responsible for drinking water-associated disease outbreaks in a number of developed countries. As a result of the resistance of Cryptosporidium to chlorine, which is typically applied as a final barrier to protect the quality of distributed drinking water, current management practices are focused on source-water management and water treatment as ways of preventing Cryptosporidium from entering drinking-water supplies. In the event that treatment barriers fail, surprisingly little is known of the fate of oocysts once they enter a distribution system. To assess properly the risks of waterborne Cryptosporidium, a more thorough understanding of the fate of oocysts in water distribution systems, with emphasis on Cryptosporidium-biofilm interactions, is required.

Simulation of groundwater flow in the shallow aquifer system of the Delmarva Peninsula, Maryland and Delaware

USGS Publications Warehouse

Sanford, Ward E.; Pope, Jason P.; Selnick, David L.; Stumvoll, Ryan F.

2012-01-01

Estimating future loadings of nitrogen to the Chesapeake Bay requires knowledge about the groundwater flow system and the traveltime of water and chemicals between recharge at the water table and the discharge to streams and directly to the bay. The Delmarva Peninsula has a relatively large proportion of its land devoted to agriculture and a large associated nitrogen load in groundwater that has the potential to enter the bay in discharging groundwater. To better understand the shallow aquifer system with respect to this loading and the traveltime to the bay, the U.S. Geological Survey constructed a steady-state groundwater flow model for the region. The model is based on estimates of recharge calculated using recently developed regression equations for evapotranspiration and surface runoff. The hydrogeologic framework incorporated into the model includes unconfined surficial aquifer sediments, as well as subcropping confined aquifers and confining beds down to 300 feet below land surface. The model was calibrated using 48 water-level measurements and 24 tracer-based ages from wells located across the peninsula. The resulting steady-state flow solution was used to estimate ages of water in the shallow aquifer system through the peninsula and the distribution and magnitude of groundwater traveltime from recharge at the water table to discharge in surface-water bodies (referred to as return time). Return times vary but are typically less than 10 years near local streams and greater than 100 years near the stream divides. The model can be used to calculate nitrate transport parameters in various local watersheds and predict future trends in nitrate loadings to Chesapeake Bay for different future nitrogen application scenarios.

Bacteria associated with granular activated carbon particles in drinking water.

PubMed Central

Camper, A K; LeChevallier, M W; Broadaway, S C; McFeters, G A

1986-01-01

A sampling protocol was developed to examine particles released from granular activated carbon filter beds. A gauze filter/Swinnex procedure was used to collect carbon fines from 201 granular activated carbon-treated drinking water samples over 12 months. Application of a homogenization procedure (developed previously) indicated that 41.4% of the water samples had heterotrophic plate count bacteria attached to carbon particles. With the enumeration procedures described, heterotrophic plate count bacteria were recovered at an average rate of 8.6 times higher than by conventional analyses. Over 17% of the samples contained carbon particles colonized with coliform bacteria as enumerated with modified most-probable-number and membrane filter techniques. In some instances coliform recoveries were 122 to 1,194 times higher than by standard procedures. Nearly 28% of the coliforms attached to these particles in drinking water exhibited the fecal biotype. Scanning electron micrographs of carbon fines from treated drinking water showed microcolonies of bacteria on particle surfaces. These data indicate that bacteria attached to carbon fines may be an important mechanism by which microorganisms penetrate treatment barriers and enter potable water supplies. PMID:3767356

Description of water-resource-related data compiled for Reno County, south-central Kansas

USGS Publications Warehouse

Hansen, C.V.

1993-01-01

Water-resource-related data for sites in Reno County, Kansas were compiled in cooperation with the Reno County Health Department as part of the Kansas Department of Health and Environment's Local Environmental Protection Program (LEPP). These data were entered into a relational data-base management system (RDBMS) to facilitate the spatial analysis required to meet the LEPP goals of developing plans for nonpoint-source management and for public- water-supply protection. The data in the RDBMS are organized into digital data sets. The data sets contain the water-resource-related data compiled by the U.S. Geological Survey for 958 wells; by the Kansas Department of Health and Environment for 3,936 wells; by the Kansas Department of Health and Environment for 51 wells, 18 public-water-supply distribution systems, and 7 streams; by the Kansas State Board of Agriculture for 643 wells and 23 streams or surface-water impoundments; and by well-drilling contractors and the Kansas Geological Survey for 96 wells. The data in these five data sets are available from the Reno County Health Department in Hutchinson, Kansas. (USGS)

Tracking enteric viruses in green vegetables from central Argentina: potential association with viral contamination of irrigation waters.

PubMed

Prez, V E; Martínez, L C; Victoria, M; Giordano, M O; Masachessi, G; Ré, V E; Pavan, J V; Colina, R; Barril, P A; Nates, S V

2018-05-11

Consumption of green vegetable products is commonly viewed as a potential risk factor for infection with enteric viruses. The link between vegetable crops and fecally contaminated irrigation water establishes an environmental scenario that can result in a risk to human health. The aim of this work was to analyze the enteric viral quality in leafy green vegetables from Córdoba (Argentina) and its potential association with viral contamination of irrigation waters. During July-December 2012, vegetables were collected from peri-urban green farms (n = 19) and its corresponding urban river irrigation waters (n = 12). Also, urban sewage samples (n = 6) were collected to analyze the viral variants circulating in the community. Viruses were eluted and concentrated by polyethylene glycol precipitation and then were subject to Reverse Transcription Polymerase Chain Reaction to assess the genome presence of norovirus, rotavirus and human astrovirus. The concentrates were also inoculated in HEp-2 (Human Epidermoid carcinoma strain #2) cells to monitor the occurrence of infective enterovirus. The frequency of detection of the viral groups in sewage, irrigation water and crops was: norovirus 100%, 67% and 58%, rotavirus 100%, 75% and 5%, astrovirus 83%, 75% and 32% and infective enterovirus 50%, 33% and 79%, respectively. A similar profile in sewage, irrigation water and green vegetables was observed for norovirus genogroups (I and II) distribution as well as for rotavirus and astrovirus G-types. These results provide the first data for Argentina pointing out that green leafy vegetables are contaminated with a broad range of enteric viruses and that the irrigation water would be a source of contamination. The presence of viral genomes and infective particles in food that in general suffer minimal treatment before consumption underlines that green crops can act as potential sources of enteric virus transmission. Public intervention in the use of the river waters as irrigation source is needed. Copyright © 2018. Published by Elsevier B.V.

A study of parabens and bisphenol A in surface water and fish brain tissue from the Greater Pittsburgh Area.

PubMed

Renz, Lara; Volz, Conrad; Michanowicz, Drew; Ferrar, Kyle; Christian, Charles; Lenzner, Diana; El-Hefnawy, Talal

2013-05-01

Pollution from xenoestrogens has been discovered in the aquatic environment of the Greater Pittsburgh Area and is suspected to be caused by the failing sewer system. Personal care products and plasticizers have the potential to enter the water supply though treated and untreated sewage. Many of these compounds are suspected xenoestrogens. Paraben detection in surface waters was as follows: methyl paraben ranged between 2.2 to 17.3 ppt; ethyl paraben was not detectable; propyl paraben was detected at 9.2 and 12.0 ppt; butyl paraben was detected at 0.2 ppt. BPA was detected between 0.6 and 15.4 ppt. Estrogenic potential of extracts from fish brain tissue was tested via Bromodeoxyuridine MCF-7 analysis and paired with HPLC-MS to investigate the presence of xenoestrogens. All samples were non-detectable for parabens. BPA was detected in 44 of the 58 samples, with a range from non-detectable to 120 pg/g. BCFs were calculated. Results were statistically significant for location of capture (p < 0.05) and correlation existed between estrogenicity and BPA.

Stormwater dissolved organic matter: influence of land cover and environmental factors.

PubMed

McElmurry, Shawn P; Long, David T; Voice, Thomas C

2014-01-01

Dissolved organic matter (DOM) plays a major role in defining biological systems and it influences the fate and transport of many pollutants. Despite the importance of DOM, understanding of how environmental and anthropogenic factors influence its composition and characteristics is limited. This study focuses on DOM exported as stormwater from suburban and urban sources. Runoff was collected before entering surface waters and DOM was characterized using specific ultraviolet absorbance at 280 nm (a proxy for aromaticity), molecular weight, polydispersity and the fraction of DOM removed from solution via hydrophobic and H-bonding mechanisms. General linear models (GLMs) incorporating land cover, precipitation, solar radiation and selected aqueous chemical measurements explained variations in DOM properties. Results show (1) molecular characteristics of DOM differ as a function of land cover, (2) DOM produced by forested land is significantly different from other landscapes, particularly urban and suburban areas, and (3) DOM from land cover that contains paved surfaces and sewers is more hydrophobic than from other types of land cover. GLMs incorporating environmental factors and land cover accounted for up to 86% of the variability observed in DOM characteristics. Significant variables (p < 0.05) included solar radiation, water temperature and water conductivity.

River stage influences on uranium transport in a hydrologically dynamic groundwater-surface water transition zone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Zachara, John M.; Chen, Xingyuan; Murray, Chris

In this study, a well-field within a uranium (U) plume in the groundwater-surface water transition zone was monitored for a 3 year period for water table elevation and dissolved solutes. The plume discharges to the Columbia River, which displays a dramatic spring stage surge resulting from snowmelt. Groundwater exhibits a low hydrologic gradient and chemical differences with river water. River water intrudes the site in spring. Specific aims were to assess the impacts of river intrusion on dissolved uranium (U aq), specific conductance (SpC), and other solutes, and to discriminate between transport, geochemical, and source term heterogeneity effects. Time seriesmore » trends for U aq and SpC were complex and displayed large temporal and well-to-well variability as a result of water table elevation fluctuations, river water intrusion, and changes in groundwater flow directions. The wells were clustered into subsets exhibiting common behaviors resulting from the intrusion dynamics of river water and the location of source terms. Hot-spots in U aq varied in location with increasing water table elevation through the combined effects of advection and source term location. Heuristic reactive transport modeling with PFLOTRAN demonstrated that mobilized U aq was transported between wells and source terms in complex trajectories, and was diluted as river water entered and exited the groundwater system. While U aq time-series concentration trends varied significantly from year-to-year as a result of climate-caused differences in the spring hydrograph, common and partly predictable response patterns were observed that were driven by water table elevation, and the extent and duration of river water intrusion.« less

River stage influences on uranium transport in a hydrologically dynamic groundwater-surface water transition zone

DOE PAGES

Zachara, John M.; Chen, Xingyuan; Murray, Chris; ...

2016-03-04

In this study, a well-field within a uranium (U) plume in the groundwater-surface water transition zone was monitored for a 3 year period for water table elevation and dissolved solutes. The plume discharges to the Columbia River, which displays a dramatic spring stage surge resulting from snowmelt. Groundwater exhibits a low hydrologic gradient and chemical differences with river water. River water intrudes the site in spring. Specific aims were to assess the impacts of river intrusion on dissolved uranium (U aq), specific conductance (SpC), and other solutes, and to discriminate between transport, geochemical, and source term heterogeneity effects. Time seriesmore » trends for U aq and SpC were complex and displayed large temporal and well-to-well variability as a result of water table elevation fluctuations, river water intrusion, and changes in groundwater flow directions. The wells were clustered into subsets exhibiting common behaviors resulting from the intrusion dynamics of river water and the location of source terms. Hot-spots in U aq varied in location with increasing water table elevation through the combined effects of advection and source term location. Heuristic reactive transport modeling with PFLOTRAN demonstrated that mobilized U aq was transported between wells and source terms in complex trajectories, and was diluted as river water entered and exited the groundwater system. While U aq time-series concentration trends varied significantly from year-to-year as a result of climate-caused differences in the spring hydrograph, common and partly predictable response patterns were observed that were driven by water table elevation, and the extent and duration of river water intrusion.« less

Reduction of enteric infectious disease in rural China by providing deep-well tap water.

PubMed Central

Wang, Z. S.; Shepard, D. S.; Zhu, Y. C.; Cash, R. A.; Zhao, R. J.; Zhu, Z. X.; Shen, F. M.

1989-01-01

Enteric infectious disease (EID), defined here as bacillary dysentery, viral hepatitis A, El Tor cholera, or acute watery diarrhoea, is an important public health problem in most developing countries. This study assessed the impact on EID of providing deep-well tap water (DWTW) through household taps in rural China. For this purpose, we compared the incidence of EID in six study villages (population, 10,290) in Qidong County that had DWTW with that in six control villages (population 9397) that had only surface water. Both the bacterial counts and chemical properties of the DWTW met established hygiene standards for drinking water. The incidence of EID in the study region was 38.6% lower than in the control region; however, the introduction of DWTW supplies did not significantly affect the incidence of bacillary dysentery. These results indicate that the construction and use of DWTW systems with household taps is associated with decreased incidences of El Tor cholera, viral hepatitis A, and acute watery diarrhoea. Since high construction costs have led many authorities to question the value of DWTW, we carried out a cost-benefit analysis of the programme. The cost of constructing a DWTW system averaged US $36,000 at 1983 prices, or US $10.50 per capita. The combined capital and operating costs of a DWTW system were US $1.46 per capita per annum over its 20-year estimated life. The benefits derived from reductions in cost of illness and savings in time to fetch water were 2.2 times the costs at present values Capital outlays were recouped in a 3.6-year payback period and the provision of DWTW proved highly beneficial in both economic and social terms. PMID:2501042

Hydrology of some deep mines in Precambrian rocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yardley, D.H.

1975-10-01

A number of underground mines were investigated during the summer of 1975. All of them are in Precambrian rocks of the Lake Superior region. They represent a variety of geologic settings. The purpose of the investigations was to make a preliminary study of the dryness, or lack of dryness of these rocks at depth. In other words, to see if water was entering the deeper workings through the unmined rock by some means such as fracture or fault zones, joints or permeable zones. Water entering through old mine workings extending to, or very near to the surface, or from themore » drilling equipment, was of interest only insofar as it might mask any water whose source was through the hanging or footwall rocks. No evidence of running, seeping or moving water was seen or reported at depths exceeding 3,000 feet. At depths of 3,000 feet or less, water seepages do occur in some of the mines, usually in minor quantities but increased amounts occur as depth becomes less. Others are dry at 2,000 feet of depth. Rock movements associated with extensive mining should increase the local secondary permeability of the rocks adjoining the mined out zones. Also most ore bodies are located where there has been a more than average amount of faulting, fracturing, and folding during the geologic past. They tend to cluster along crustal flows. In general, Precambrian rocks of similar geology, to those seen, well away from zones that have been disturbed by extensive deep mining, and well away from the zones of more intense geologic activity ought to be even less permeable than their equivalents in a mining district.« less

Multivariate logistic regression for predicting total culturable virus presence at the intake of a potable-water treatment plant: novel application of the atypical coliform/total coliform ratio.

PubMed

Black, L E; Brion, G M; Freitas, S J

2007-06-01

Predicting the presence of enteric viruses in surface waters is a complex modeling problem. Multiple water quality parameters that indicate the presence of human fecal material, the load of fecal material, and the amount of time fecal material has been in the environment are needed. This paper presents the results of a multiyear study of raw-water quality at the inlet of a potable-water plant that related 17 physical, chemical, and biological indices to the presence of enteric viruses as indicated by cytopathic changes in cell cultures. It was found that several simple, multivariate logistic regression models that could reliably identify observations of the presence or absence of total culturable virus could be fitted. The best models developed combined a fecal age indicator (the atypical coliform [AC]/total coliform [TC] ratio), the detectable presence of a human-associated sterol (epicoprostanol) to indicate the fecal source, and one of several fecal load indicators (the levels of Giardia species cysts, coliform bacteria, and coprostanol). The best fit to the data was found when the AC/TC ratio, the presence of epicoprostanol, and the density of fecal coliform bacteria were input into a simple, multivariate logistic regression equation, resulting in 84.5% and 78.6% accuracies for the identification of the presence and absence of total culturable virus, respectively. The AC/TC ratio was the most influential input variable in all of the models generated, but producing the best prediction required additional input related to the fecal source and the fecal load. The potential for replacing microbial indicators of fecal load with levels of coprostanol was proposed and evaluated by multivariate logistic regression modeling for the presence and absence of virus.

Clostridium perfringens and somatic coliphages as indicators of the efficiency of drinking water treatment for viruses and protozoan cysts.

PubMed Central

Payment, P; Franco, E

1993-01-01

To find the most suitable indicator of viral and parasitic contamination of drinking water, large-volume samples were collected and analyzed for the presence of pathogens (cultivable human enteric viruses, Giardia lamblia cysts, and Cryptosporidium oocysts) and potential indicators (somatic and male-specific coliphages, Clostridium perfringens). The samples were obtained from three water treatment plants by using conventional or better treatments (ozonation, biological filtration). All samples of river water contained the microorganisms sought, and only C. perfringens counts were correlated with human enteric viruses, cysts, or oocysts. For settled and filtered water samples, all indicators were statistically correlated with human enteric viruses but not with cysts or oocysts. By using multiple regression, the somatic coliphage counts were the only explanatory variable for the human enteric virus counts in settled water, while in filtered water samples it was C. perfringens counts. Finished water samples of 1,000 liters each were free of all microorganisms, except for a single sample that contained low levels of cysts and oocysts of undetermined viability. Three of nine finished water samples of 20,000 liters each revealed residual levels of somatic coliphages at 0.03, 0.10, and 0.26 per 100 liters. Measured virus removal was more than 4 to 5 log10, and cyst removal was more than 4 log10. Coliphage and C. perfringens counts suggested that the total removal and inactivation was more than 7 log10 viable microorganisms. C. perfringens counts appear to be the most suitable indicator for the inactivation and removal of viruses in drinking water treatment.(ABSTRACT TRUNCATED AT 250 WORDS) PMID:8368831

Surface Sampling Collection and Culture Methods for Escherichia coli in Household Environments with High Fecal Contamination

PubMed Central

Kosek, Margaret N.; Schwab, Kellogg J.

2017-01-01

Empiric quantification of environmental fecal contamination is an important step toward understanding the impact that water, sanitation, and hygiene interventions have on reducing enteric infections. There is a need to standardize the methods used for surface sampling in field studies that examine fecal contamination in low-income settings. The dry cloth method presented in this manuscript improves upon the more commonly used swabbing technique that has been shown in the literature to have a low sampling efficiency. The recovery efficiency of a dry electrostatic cloth sampling method was evaluated using Escherichia coli and then applied to household surfaces in Iquitos, Peru, where there is high fecal contamination and enteric infection. Side-by-side measurements were taken from various floor locations within a household at the same time over a three-month period to compare for consistency of quantification of E. coli bacteria. The dry cloth sampling method in the laboratory setting showed 105% (95% Confidence Interval: 98%, 113%) E. coli recovery efficiency off of the cloths. The field application demonstrated strong agreement of side-by-side results (Pearson correlation coefficient for dirt surfaces was 0.83 (p < 0.0001) and 0.91 (p < 0.0001) for cement surfaces) and moderate agreement for results between entrance and kitchen samples (Pearson (0.53, p < 0.0001) and weighted Kappa statistic (0.54, p < 0.0001)). Our findings suggest that this method can be utilized in households with high bacterial loads using either continuous (quantitative) or categorical (semi-quantitative) data. The standardization of this low-cost, dry electrostatic cloth sampling method can be used to measure differences between households in intervention and non-intervention arms of randomized trials. PMID:28829392

Surface Sampling Collection and Culture Methods for Escherichia coli in Household Environments with High Fecal Contamination.

PubMed

Exum, Natalie G; Kosek, Margaret N; Davis, Meghan F; Schwab, Kellogg J

2017-08-22

Empiric quantification of environmental fecal contamination is an important step toward understanding the impact that water, sanitation, and hygiene interventions have on reducing enteric infections. There is a need to standardize the methods used for surface sampling in field studies that examine fecal contamination in low-income settings. The dry cloth method presented in this manuscript improves upon the more commonly used swabbing technique that has been shown in the literature to have a low sampling efficiency. The recovery efficiency of a dry electrostatic cloth sampling method was evaluated using Escherichia coli and then applied to household surfaces in Iquitos, Peru, where there is high fecal contamination and enteric infection. Side-by-side measurements were taken from various floor locations within a household at the same time over a three-month period to compare for consistency of quantification of E. coli bacteria. The dry cloth sampling method in the laboratory setting showed 105% (95% Confidence Interval: 98%, 113%) E. coli recovery efficiency off of the cloths. The field application demonstrated strong agreement of side-by-side results (Pearson correlation coefficient for dirt surfaces was 0.83 ( p < 0.0001) and 0.91 ( p < 0.0001) for cement surfaces) and moderate agreement for results between entrance and kitchen samples (Pearson (0.53, p < 0.0001) and weighted Kappa statistic (0.54, p < 0.0001)). Our findings suggest that this method can be utilized in households with high bacterial loads using either continuous (quantitative) or categorical (semi-quantitative) data. The standardization of this low-cost, dry electrostatic cloth sampling method can be used to measure differences between households in intervention and non-intervention arms of randomized trials.

Hot water tank for use with a combination of solar energy and heat-pump desuperheating

DOEpatents

Andrews, John W.

1983-06-28

A water heater or system which includes a hot water tank having disposed therein a movable baffle to function as a barrier between the incoming volume of cold water entering the tank and the volume of heated water entering the tank which is heated by the circulation of the cold water through a solar collector and/or a desuperheater of a heat pump so as to optimize the manner in which heat is imparted to the water in accordance to the demand on the water heater or system. A supplemental heater is also provided and it is connected so as to supplement the heating of the water in the event that the solar collector and/or desuperheater cannot impart all of the desired heat input into the water.

Simulated effects of proposed Arkansas Valley Conduit on hydrodynamics and water quality for projected demands through 2070, Pueblo Reservoir, southeastern Colorado

USGS Publications Warehouse

Ortiz, Roderick F.

2013-01-01

The purpose of the Arkansas Valley Conduit (AVC) is to deliver water for municipal and industrial use within the boundaries of the Southeastern Colorado Water Conservancy District. Water supplied through the AVC would serve two needs: (1) to supplement or replace existing poor-quality water to communities downstream from Pueblo Reservoir; and (2) to meet a portion of the AVC participants’ projected water demands through 2070. The Bureau of Reclamation (Reclamation) initiated an Environmental Impact Statement (EIS) to address the potential environmental consequences associated with constructing and operating the proposed AVC, entering into a conveyance contract for the Pueblo Dam north-south outlet works interconnect (Interconnect), and entering into a long-term excess capacity master contract (Master Contract). Operational changes, as a result of implementation of proposed EIS alternatives, could change the hydrodynamics and water-quality conditions in Pueblo Reservoir. An interagency agreement was initiated between Reclamation and the U.S. Geological Survey to accurately simulate hydrodynamics and water quality in Pueblo Reservoir for projected demands associated with four of the seven proposed EIS alternatives. The four alternatives submitted to the USGS for scenario simulation included various combinations (action or no action) of the proposed Arkansas Valley Conduit, Master Contract, and Interconnect options. The four alternatives were the No Action, Comanche South, Joint Use Pipeline North, and Master Contract Only. Additionally, scenario simulations were done that represented existing conditions (Existing Conditions scenario) in Pueblo Reservoir. Water-surface elevations, water temperature, dissolved oxygen, dissolved solids, dissolved ammonia, dissolved nitrate, total phosphorus, total iron, and algal biomass (measured as chlorophyll-a) were simulated. Each of the scenarios was simulated for three contiguous water years representing a wet, average, and dry annual hydrologic cycle. Each selected simulation scenario also was evaluated for differences in direct/indirect effects and cumulative effects on a particular scenario. Analysis of the results for the direct/indirect- and cumulative-effects analyses indicated that, in general, the results were similar for most of the scenarios and comparisons in this report focused on results from the direct/indirect-effects analyses. Scenario simulations that represented existing conditions in Pueblo Reservoir were compared to the No Action scenario to assess changes in water quality from current demands (2006) to projected demands in 2070. Overall, comparisons of the results between the Existing Conditions and the No Action scenarios for water-surface elevations, water temperature, and dissolved oxygen, dissolved solids, dissolved ammonia, dissolved nitrate, total phosphorus, and total iron concentrations indicated that the annual median values generally were similar for all three simulated years. Additionally, algal groups and chlorophyll-a concentrations (algal biomass) were similar for the Existing Conditions and the No Action scenarios at site 7B in the epilimnion for the simulated period (Water Year 2000 through 2002). The No Action scenario also was compared individually to the Comanche South, Joint Use Pipeline North, and Master Contract Only scenarios. These comparisons were made to describe changes in the annual median, 85th percentile, or 15th percentile concentration between the No Action scenario and each of the other three simulation scenarios. Simulated water-surface elevations, water temperature, dissolved oxygen, dissolved solids, dissolved ammonia, dissolved nitrate, total phosphorus, total iron, algal groups, and chlorophyll-a concentrations in Pueblo Reservoir generally were similar between the No Action scenario and each of the other three simulation scenarios.

Sedimentation of Free and Attached Cryptosporidium Oocysts and Giardia Cysts in Water

PubMed Central

Medema, G. J.; Schets, F. M.; Teunis, P. F. M.; Havelaar, A. H.

1998-01-01

Experimental analysis of the sedimentation velocity of Cryptosporidium parvum oocysts and Giardia lamblia cysts was compared with mathematical description of their sedimentation velocities by using measurements of (oo)cyst size and density and the density and viscosity of the sedimentation medium to determine if the sedimentation kinetics of freely suspended oocysts of C. parvum and cysts of G. lamblia can be described by Stokes’ law. The theoretically calculated sedimentation kinetics showed a good agreement with the experimentally observed kinetics. Both showed a decline in sedimentation velocity over time, caused primarily by variation in (oo)cyst density. The initial apparent sedimentation velocities in Hanks balanced salt solution at 23°C was 0.35 μm · s−1 for oocysts and 1.4 μm · s−1 for cysts. (Oo)cysts that enter the surface water environment by discharges of biologically treated sewage may be attached to sewage particles, and this will affect their sedimentation kinetics. Therefore, (oo)cysts were mixed with settled secondary effluent. (Oo)cysts readily attached to the (biological) particles in effluent; 30% of both cysts and oocysts attached during the first minutes of mixing, and this fraction increased to approximately 75% after 24 h. The sedimentation velocity of (oo)cysts attached to secondary effluent particles increased with particle size and was (already in the smallest size fraction [1 to 40 μm]) determined by the sedimentation kinetics of the effluent particles. The observed sedimentation velocities of freely suspended (oo)cysts are probably too low to cause significant sedimentation in surface water or reservoirs. However, since a significant proportion of both cysts and oocysts attached readily to organic biological particles in secondary effluent, sedimentation of attached (oo)cysts after discharge into surface water will probably be a significant factor in the environmental ecology of C. parvum and G. lamblia. Attachment to particles influences not only sedimentation of (oo)cysts in surface water but also their behavior in drinking water treatment processes. PMID:9797307

THE ROLE OF WATER IN PROTOPLASMIC PERMEABILITY AND IN ANTAGONISM

PubMed Central

Osterhout, W. J. V.

1956-01-01

The behavior of the cell depends to a large extent on the permeability of the outer non-aqueous surface layer of the protoplasm. This layer is immiscible with water but may be quite permeable to it. It seems possible that a reversible increase or decrease in permeability may be due to a corresponding increase or decrease in the water content of the non-aqueous surface layer. Irreversible increase in permeability need not be due primarily to increase in the water content of the surface layer but may be caused chiefly by changes in the protoplasm on which the surface layer rests. It may include desiccation, precipitation, and other alterations. An artificial cell is described in which the outer protoplasmic surface layer is represented by a layer of guaiacol on one side of which is a solution of KOH + KCl representing the external medium and on the other side is a solution of CO2 representing the protoplasm. The K+ unites with guaiacol and diffuses across to the artificial protoplasm where its concentration becomes higher than in the external solution. The guaiacol molecule thus acts as a carrier molecule which transports K+ from the external medium across the protoplasmic surface. The outer part of the protoplasm may contain relatively few potassium ions so that the outwardly directed potential at the outer protoplasmic surface may be small but the inner part of the protoplasm may contain more potassium ions. This may happen when potassium enters in combination with carrier molecules which do not completely dissociate until they reach the vacuole. Injury and recovery from injury may be studied by measuring the movements of water into and out of the cell. Metabolism by producing CO2 and other acids may lower the pH and cause local shrinkage of the protoplasm which may lead to protoplasmic motion. Antagonism between Na+ and Ca++ appears to be due to the fact that in solutions of NaCl the surface layer takes up an excessive amount of water and this may be prevented by the addition of suitable amounts of CaCl2. In Nitella the outer non-aqueous surface layer may be rendered irreversibly permeable by sharply bending the cell without permanent damage to the inner non-aqueous surface layer surrounding the vacuole. The formation of contractile vacuoles may be imitated in non-living systems. An extract of the sperm of the marine worm Nereis which contains a highly surface-active substance can cause the egg to divide. It seems possible that this substance may affect the surface layer of the egg and cause it to take up water. A surface-active substance has been found in all the seminal fluids examined including those of trout, rooster, bull, and man. Duponol which is highly surface-active causes the protoplasm of Spirogyra to take up water and finally dissolve but it can be restored to the gel state by treatment with Lugol solution (KI + I). The transition from gel to sol and back again can be repeated many times in succession. The behavior of water in the surface layer of the protoplasm presents important problems which deserve careful examination. PMID:13346047

Microbial Contamination of Drinking Water and Human Health from Community Water Systems.

PubMed

Ashbolt, Nicholas J

2015-03-01

A relatively short list of reference viral, bacterial and protozoan pathogens appears adequate to assess microbial risks and inform a system-based management of drinking waters. Nonetheless, there are data gaps, e.g. human enteric viruses resulting in endemic infection levels if poorly performing disinfection and/or distribution systems are used, and the risks from fungi. Where disinfection is the only treatment and/or filtration is poor, cryptosporidiosis is the most likely enteric disease to be identified during waterborne outbreaks, but generally non-human-infectious genotypes are present in the absence of human or calf fecal contamination. Enteric bacteria may dominate risks during major fecal contamination events that are ineffectively managed. Reliance on culture-based methods exaggerates treatment efficacy and reduces our ability to identify pathogens/indicators; however, next-generation sequencing and polymerase chain reaction approaches are on the cusp of changing that. Overall, water-based Legionella and non-tuberculous mycobacteria probably dominate health burden at exposure points following the various societal uses of drinking water.

Stormwater runoff plumes in the Southern California Bight: A comparison study with SAR and MODIS imagery.

PubMed

Holt, Benjamin; Trinh, Rebecca; Gierach, Michelle M

2017-05-15

Stormwater runoff is the largest source of pollution in the Southern California Bight (SCB), resulting from untreated runoff and pollutants from urban watersheds entering the coastal waters after rainstorms. We make use of both satellite SAR and MODIS-Aqua ocean color imagery to examine two different components of runoff plumes, the surface slick and the sediment discharge. We expand on earlier satellite SAR studies by examining an extensive collection of multi-platform SAR imagery, spanning from 1992 to 2014, that provides a more comprehensive view of the plume surface slick characteristics, illustrated with distribution maps of the extent and flow direction of the plumes. The SAR-detected surface plumes are compared with coincident rain and runoff measurements, and with available measured shoreline fecal bacteria loads. We illustrate differences in the detection of SAR surface plumes with the sediment-related discharge plumes derived from MODIS imagery. A conceptual satellite stormwater runoff monitoring approach is presented. Copyright © 2017 Elsevier Ltd. All rights reserved.

Seasonal changes in Fe along a glaciated Greenlandic fjord.

NASA Astrophysics Data System (ADS)

Hopwood, Mark; Connelly, Douglas; Arendt, Kristine; Juul-Pedersen, Thomas; Stinchcombe, Mark; Meire, Lorenz; Esposito, Mario; Krishna, Ram

2016-03-01

Greenland's ice sheet is the second largest on Earth, and is under threat from a warming Arctic climate. An increase in freshwater discharge from Greenland has the potential to strongly influence the composition of adjacent water masses with the largest impact on marine ecosystems likely to be found within the glaciated fjords. Here we demonstrate that physical and chemical estuarine processes within a large Greenlandic fjord are critical factors in determining the fate of meltwater derived nutrients and particles, especially for non-conservative elements such as Fe. Concentrations of Fe and macronutrients in surface waters along Godthåbsfjord, a southwest Greenlandic fjord with freshwater input from 6 glaciers, changed markedly between the onset and peak of the meltwater season due to the development of a thin (<10 m), outflowing, low-salinity surface layer. Dissolved (<0.2 µm) Fe concentrations in meltwater entering Godthåbsfjord (200 nM), in freshly melted glacial ice (mean 38 nM) and in surface waters close to a land terminating glacial system (80 nM) all indicated high Fe inputs into the fjord in summer. Total dissolvable (unfiltered at pH <2.0) Fe was similarly high with concentrations always in excess of 100 nM throughout the fjord and reaching up to 5.0 µM close to glacial outflows in summer. Yet, despite the large seasonal freshwater influx into the fjord, Fe concentrations near the fjord mouth in the out-flowing surface layer were similar in summer to those measured before the meltwater season. Furthermore, turbidity profiles indicated that sub-glacial particulate Fe inputs may not actually mix into the outflowing surface layer of this fjord. Emphasis has previously been placed on the possibility of increased Fe export from Greenland as meltwater fluxes increase. Here we suggest that in-fjord processes may be effective at removing Fe from surface waters before it can be exported to coastal seas.

Warming of the Global Ocean: Spatial Structure and Water-Mass Trends

NASA Technical Reports Server (NTRS)

Hakkinen, Sirpa; Rhines, Peter B.; Worthen, Denise L.

2016-01-01

This study investigates the multidecadal warming and interannual-to-decadal heat content changes in the upper ocean (0-700 m), focusing on vertical and horizontal patterns of variability. These results support a nearly monotonic warming over much of the World Ocean, with a shift toward Southern Hemisphere warming during the well-observed past decade. This is based on objectively analyzed gridded observational datasets and on a modeled state estimate. Besides the surface warming, a warming climate also has a subsurface effect manifesting as a strong deepening of the midthermocline isopycnals, which can be diagnosed directly from hydrographic data. This deepening appears to be a result of heat entering via subduction and spreading laterally from the high-latitude ventilation regions of subtropical mode waters. The basin-average multidecadal warming mainly expands the subtropical mode water volume, with weak changes in the temperature-salinity (u-S) relationship (known as ''spice'' variability). However, the spice contribution to the heat content can be locally large, for example in Southern Hemisphere. Multidecadal isopycnal sinking has been strongest over the southern basins and weaker elsewhere with the exception of the Gulf Stream/North Atlantic Current/subtropical recirculation gyre. At interannual to decadal time scales, wind-driven sinking and shoaling of density surfaces still dominate ocean heat content changes, while the contribution from temperature changes along density surfaces tends to decrease as time scales shorten.

Eutrophication of freshwater and marine ecosystems

USGS Publications Warehouse

Smith, Val H.; Joye, Samantha B.; Howarth, Robert W.

2006-01-01

Initial understanding of the links between nutrients and aquatic productivity originated in Europe in the early 1900s, and our knowledge base has expanded greatly during the past 40 yr. This explosion of eutrophication-related research has made it unequivocally clear that a comprehensive strategy to prevent excessive amounts of nitrogen and phosphorus from entering our waterways is needed to protect our lakes, rivers, and coasts from water quality deterioration. However, despite these very significant advances, cultural eutrophication remains one of the foremost problems for protecting our valuable surface water resources. The papers in this special issue provide a valuable cross section and synthesis of our current understanding of both freshwater and marine eutrophication science. They also serve to identify gaps in our knowledge and will help to guide future research.

US Fish and Wildlife Service biomonitoring operations manual, Appendices A--K

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gianotto, D.F.; Rope, R.C.; Mondecar, M.

1993-04-01

Volume 2 contains Appendices and Summary Sheets for the following areas: A-Legislative Background and Key to Relevant Legislation, B- Biomonitoring Operations Workbook, C-Air Monitoring, D-Introduction to the Flora and Fauna for Biomonitoring, E-Decontamination Guidance Reference Field Methods, F-Documentation Guidance, Sample Handling, and Quality Assurance/Quality Control Standard Operating Procedures, G-Field Instrument Measurements Reference Field Methods, H-Ground Water Sampling Reference Field Methods, I-Sediment Sampling Reference Field Methods, J-Soil Sampling Reference Field Methods, K-Surface Water Reference Field Methods. Appendix B explains how to set up strategy to enter information on the ``disk workbook``. Appendix B is enhanced by DE97006389, an on-line workbook formore » users to be able to make revisions to their own biomonitoring data.« less

Uranium in Surface Waters and Sediments Affected by Historical Mining in the Denver West 1:100,000 Quadrangle, Colorado

USGS Publications Warehouse

Zielinski, Robert A.; Otton, James K.; Schumann, R. Randall; Wirt, Laurie

2008-01-01

Geochemical sampling of 82 stream waters and 87 stream sediments within mountainous areas immediately west of Denver, Colorado, was conducted by the U.S. Geological Survey in October 1994. The primary purpose was to evaluate regionally the effects of geology and past mining on the concentration and distribution of uranium. The study area contains uranium- and thorium-rich bedrock, numerous noneconomic occurrences of uranium minerals, and several uranium deposits of variable size and production history. During the sampling period, local streams had low discharge and were more susceptible to uranium-bearing acid drainage originating from historical mines of base- and precious-metal sulfides. Results indicated that the spatial distribution of Precambrian granites and metamorphic rocks strongly influences the concentration of uranium in stream sediments. Within-stream transport increases the dispersion of uranium- and thorium rich mineral grains derived primarily from granitic source rocks. Dissolved uranium occurs predominantly as uranyl carbonate complexes, and concentrations ranged from less than 1 to 65 micrograms per liter. Most values were less than 5 micrograms per liter, which is less than the current drinking water standard of 30 micrograms per liter and much less than locally applied aquatic-life toxicity standards of several hundred micrograms per liter. In local streams that are affected by uranium-bearing acid mine drainage, dissolved uranium is moderated by dilution and sorptive uptake by stream sediments. Sorbents include mineral alteration products and chemical precipitates of iron- and aluminum-oxyhydroxides, which form where acid drainage enters streams and is neutralized. Suspended uranium is relatively abundant in some stream segments affected by nearby acid drainage, which likely represents mobilization of these chemical precipitates. The 234U/238U activity ratio of acid drainage (0.95-1.0) is distinct from that of local surface waters (more than 1.05), and this distinctive isotopic composition may be preserved in iron-oxyhydroxide precipitates of acid drainage origin. The study area includes a particularly large vein-type uranium deposit (Schwartzwalder mine) with past uranium production. Stream water and sediment collected downstream from the mine's surface operations have locally anomalous concentrations of uranium. Fine-grained sediments downstream from the mine contain rare minute particles (10-20 micrometers) of uraninite, which is unstable in a stream environment and thus probably of recent origin related to mining. Additional rare particles of very fine grained (less than 5 micrometer) barite likely entered the stream as discharge from settling ponds in which barite precipitation was formerly used to scavenge dissolved radium from mine effluent.

Impact of the Sun on Remote Sensing of Sea Surface Salinity from Space

NASA Technical Reports Server (NTRS)

LeVine, David M; Abraham, Saji; Wentz, F; Lagerloef, G S

2005-01-01

The sun is a sufficiently strong source of radiation at L-band to be an important source of interference for radiometers on future satellite missions such as SMOS, Aquarius, and Hydros designed to monitor soil moisture and sea surface salinity. Radiation from the sun can impact passive remote sensing systems in several ways, including line-of-sight radiation that comes directly from the sun and enters through antenna side lobes and radiation that is reflected from the surface to the radiometer. Examples are presented in the case of Aquarius, a pushbroom radiometer with three beams designed to monitor sea surface salinity. Near solar minimum, solar contamination is not a problem unless the sun enters near the main beam. But near solar maximum, contamination from the sun equivalent to a change of salinity on the order of 0.1 psu can occur even when the signal enters in sidelobes far from the main beam.

Hydrologic Resources of Guam

USGS Publications Warehouse

Gingerich, Stephen B.

2003-01-01

Introduction The U.S. Territory of Guam, which lies in the western Pacific Ocean near latitude 13?28'N and longitude 144?45'E, is the largest (211 mi2) and southernmost of the islands in the Mariana chain. Ground water supplies about 80 percent of the drinking water for the island's 150,000 residents and nearly one million visitors per year. In northern Guam, water is obtained from wells that tap the upper part of a fresh ground-water lens in an aquifer composed mainly of limestone. About 180 wells, nearly all in the north, withdraw about 35 Mgal/d of water with chloride concentrations ranging from 6 to 585 mg/L. In southern Guam, the main source of freshwater is from surface water that runs off the weathered volcanic rocks that are exposed over much of the area. About 9.9 Mgal/d of freshwater is obtained using surface reservoirs. The island's freshwater resources are adequate to meet current (2003) needs, but future demands will eventually be higher. To better understand the hydrology of the island, the U.S. Geological Survey (USGS) entered into a cooperative study with the Water and Environmental Research Institute of the Western Pacific (WERI) at the University of Guam. The objective of the study was to provide a better understanding of the water resources of the island through analysis of data collected by the USGS on Guam. This report provides a description of the general hydrologic principles of the island's ground-water systems, as well as of the rainfall and geology of Guam. Hydrologic data described in the report include water levels, chloride concentrations, and pumpage from ground-water wells and streamflow data from southern Guam.

Monitoring for Pesticides in Groundwater and Surface Water in Nevada, 2008

USGS Publications Warehouse

Thodal, Carl E.; Carpenter, Jon; Moses, Charles W.

2009-01-01

Commercial pesticide applicators, farmers, and homeowners apply about 1 billion pounds of pesticides annually to agricultural land, non-crop land, and urban areas throughout the United States (Gilliom and others, 2006, p. 1). The U.S. Environmental Protection Agency (USEPA) defines a pesticide as any substance used to kill or control insects, weeds, plant diseases, and other pest organisms. Although there are important benefits from the proper use of pesticides, like crop protection and prevention of human disease outbreaks, there are also risks. One risk is the contamination of groundwater and surface-water resources. Data collected during 1992-2001 from 51 major hydrologic systems across the United States indicate that one or more pesticide or pesticide breakdown product was detected in more than 50 percent of 5,057 shallow (less than 20 feet below land surface) wells and in all of the 186 stream sites that were sampled in agricultural and urban areas (Gilliom and others, 2006, p. 2-4). Pesticides can contaminate surface water and groundwater from both point sources and non-point sources. Point sources are from specific locations such as spill sites, disposal sites, pesticide drift during application, and application of pesticides to control aquatic pests. Non-point sources represent the dominant source of surface water and groundwater contamination and may include agricultural and urban runoff, erosion, leaching from application sites, and precipitation that has become contaminated by upwind applications. Pesticides typically enter surface water when rainfall or irrigation exceeds the infiltration capacity of soil and resulting runoff then transports pesticides to streams, rivers, and other surface-water bodies. Contamination of groundwater may result directly from spills near poorly sealed well heads and from pesticide applications through improperly designed or malfunctioning irrigation systems that also are used to apply pesticides (chemigation; Carpenter and Johnson, 1997). Groundwater contamination also may come indirectly by the percolation of agricultural and urban irrigation water through soil layers and into groundwater and from pesticide residue in surface water, such as drainage ditches, streams, and municipal wastewater. To protect surface water and groundwater from pesticide contamination, the USEPA requires that all states establish a pesticide management plan. The Nevada Department of Agriculture (NDOA), with assistance from the USEPA, developed a management program of education (Hefner and Donaldson, 2006), regulation (Johnson and others, 2006), and monitoring (Pennington and others, 2001) to protect Nevada's water resources from pesticide contaminants. Sampling sites are located in areas where urban or agricultural pesticide use may affect groundwater, water bodies, endangered species, and other aquatic life. Information gathered from these sites is used by NDOA to help make regulatory decisions that will protect human and environmental health by reducing and eliminating the occurrence of pesticide contamination. This fact sheet describes current (2008) pesticide monitoring of groundwater and streams by the NDOA in Nevada and supersedes Pennington and others (2001).

Urban Runoff and Nutrients Loading Control from Sustainable BMPs (Invited)

NASA Astrophysics Data System (ADS)

Xiao, Q.

2009-12-01

Climate change alters hydrodynamic and nutrient dynamic in both large and small geographic scales. These changes in our freshwater system directly affect drinking water, food production, business, and all aspects of our life. Along with climate change is increasing urbanization which alters natural landscape. Urban runoff has been identified as one of many potential drivers of the decline of pelagic fishes in san Francisco Bay-Delta region. Recent found of Pyrethroids in American River has increased scientists, public, and policy makers’ concern about our fresh water system. Increasing our understanding about the fundamental hydrodynamic, nutrient dynamics, and the transport mechanics of runoff and nutrients are important for future water resource and ecosystem management. Urbanization has resulted in significantly increasing the amount of impervious land cover. Most impervious land covers are hydrophobic that alters surface runoff because of the effects on surface retention storage, rainfall interception, and infiltration. Large volumes of excess storm runoff from urbanized areas cause flooding, water pollution, groundwater recharge deficits, destroyed habitat, beach closures, and toxicity to aquatic organisms. Parking lot alone accounts for more than 11% of these impervious surfaces. Contrast to impervious parking lot, turfgrass can accouter for 12% of urban land in California. Irrigated urban landscapes create considerable benefits to our daily living. However, the use of fertilizers and pesticides has caused environmental problems. Preventing fertilizers and pesticides from entering storm drains is an important goal for both landscape and storm runoff managers. Studies of urban runoff have found that the most fertilizers and pesticides are from dry weather runoff which conveys pollutants to sidewalks, streets, and storm drains. Controlling surface runoff is critical to preventing these pollutants from entering storm drains and water bodies. Large scale construction of runoff retention basins and treatment facilities to meet TMDL (Total Maximum Daily Load) regulations are not cost-effective or practical. An alternative approach is to control runoff and nutrients on-site through installation of decentralized BMPs that detain and infiltrate runoff before it reaches storm drains. Recent developed green-infrastructure which integrating engineered soil and trees to reduce runoff and nutrients loading is a self-sustained best management practice (BMP). This BMP has been testing and used in urban runoff control. In Davis, CA this type of BMPs were installed in a parking lot and a residential property to evaluate the system’s effectiveness on reducing storm runoff and pollutant loading from the parking lot and irrigated landscape. Storm runoff and pollutant loading were measured and monitored during February 2007 thru May 2009 from the parking lot. The BMP reduced surface runoff and nutrients by 88.8% and 95.3%, respectively. In the residential irrigated landscape, the dry-weather runoff was monitored during 2007 irrigation season, the BMP captured almost all dry weather runoff. The performance of these BMPs demonstrated their potential use for reducing runoff and nutrients loading. Control urban runoff from these 23% landscape (i.e., parking lot and irrigated turf grass) could largely alter the runoff and nutrients transport and their dynamic in our water system.

Development of homologous viral internal controls for use in RT-PCR assays of waterborne enteric viruses.

PubMed

Parshionikar, Sandhya U; Cashdollar, Jennifer; Fout, G Shay

2004-10-01

Enteric viruses often contaminate water sources causing frequent outbreaks of gastroenteritis. Reverse transcription-polymerase chain reaction (RT-PCR) assays are commonly used for detection of human enteric viruses in environmental and drinking water samples. RT-PCR provides a means to rapidly detect low levels of these viruses, but it is sensitive to inhibitors that are present in water samples. Inhibitors of RT-PCR are concentrated along with viruses during sample processing. While procedures have been developed to remove inhibitors, none of them completely remove all inhibitors from all types of water matrices. This problem requires that adequate controls be used to distinguish true from potentially false-negative results. To address this problem, we have developed homologous viral internal controls for hepatitis A virus (HAV), poliovirus, Norwalk virus and rotavirus. These internal controls can be used in RT-PCR assays for the detection of the above viruses by competitive amplification, thereby allowing the detection of false negatives in processed water samples. The internal controls developed in this study were successfully tested with virus-seeded environmental water sample concentrates.

Changes in atmospheric CO2 - Influence of the marine biota at high latitude

NASA Technical Reports Server (NTRS)

Knox, F.; Mcelroy, M. B.

1984-01-01

Approximately half of the nitrogen and phosphorus entering deep waters of the contemporary ocean are transported from the surface in inorganic form as preformed nutrients. A simple model for ocean chemistry is presented and shown to account for the present level of atmospheric CO2. Fluctuations in preformed nutrients, modulated by changes in insolation and circulation at high latitudes, can result in significant variations in CO2. It is suggested that these changes may account for the apparent control on climate exercised by secular variations in the orbital parameters of the earth.

Hydrogeochemical Investigation of the Standard Mine Vicinity, Upper Elk Creek Basin, Colorado

USGS Publications Warehouse

Manning, Andrew H.; Verplanck, Philip L.; Mast, M. Alisa; Wanty, Richard B.

2008-01-01

Ground- and surface-water samples were collected in the vicinity of the Standard Mine in west-central Colorado in order to characterize the local ground-water flow system, determine metal concentrations in local ground water, and better understand factors controlling the discharge of metal-rich waters from the mine. The sampling program included a one-time sampling of springs, mine adits, and exploration pits in Elk Basin and Redwell Basin; repeated sampling throughout one year of Standard Mine Level 1 discharge and Elk Creek near its confluence with Coal Creek; and a one-time sampling of underground sites in Levels 3 and 5 of the Standard Mine. Samples were analyzed for major ions and trace elements, stable isotopes of hydrogen (2H/1H) and oxygen (18O/16O), strontium isotopes, and tritium and dissolved noble gases (including helium isotopes) for tritium/helium-3 age dating. No clear correlations were observed between natural ground-water discharge locations and map-scale faults and lithology. Surface observations and the location of ground-water discharge suggest that simple topography, rather than large-scale geologic features, primarily controls the occurrence and flow of shallow ground water in Elk Basin. Discrete inflows from cross faults or other features were not observed in Levels 3 and 5 of the Standard Mine. Instead, water entered the mine as relatively persistent dripping from gouge and breccia within the Standard fault, which both tunnels follow. Therefore, the Standard fault itself is probably the main pathway of ground-water flow from the shallow subsurface to the mine workings. Low pH (as low as 3.2) and elevated concentrations of zinc, lead, cadmium, copper, and manganese (commonly exceeding water-quality standards for Elk Creek) were measured in samples located within or immediately downgradient of areas where sulfides are abundant, including the Standard fault, the Elk Lode portal, and the breccia pipe in Redwell Basin. Concentrations of these metals were typically low and pH values were circumneutral at surrounding locations. Metal concentrations in samples collected from underground workings in the Standard Mine were also generally higher than in samples collected at aboveground sites located outside of sulfide-rich areas. Metal concentrations in discharge from the Level 1 tunnel were among the highest measured in Elk Basin. All of these observations suggest that sulfide-rich mineralized rock is the primary control on dissolved metal concentrations and pH in ground water in the Standard Mine vicinity. Waste-rock piles apparently exert another major control on metal concentrations and pH; the lowest pH and highest metal concentrations typically are found in discharge from waste-rock piles. Concentrations of several chemical constituents along with strontium isotope data indicate that none of the sampled waters could have been the primary source of metals in discharge from Level 1. Therefore, this study did not identify the primary source location for metals in Level 1 discharge. Possible sources must be located below Levels 3 and 5 or farther back into the mountainside than the ends of Levels 3 and 5. Apparent tritium/helium-3 ground-water ages ranged from 0 to 9 yr, and a considerable majority were <1 yr. Tritium data and computed initial tritium values (measured tritium plus measured tritiogenic helium-3) suggest that much of the ground water in the Standard Mine vicinity was weeks to months old rather than years old. Tritium, d2H, and d18O data from water entering into and discharging from the Standard Mine displayed spatial and temporal patterns indicating that these tracers were influenced by seasonal variations in their concentration in precipitation. The tracer data therefore suggest that ground water entering into and discharging from the Standard Mine was largely composed of water <1 yr old. Pronounced seasonal variations in geochemistry in Level 1 discharge also are consistent with short r

A Pilot Study on Effects of Hydraulic Dredging and Disposal on Water Quality of the Upper Mississippi River (July 1976). GREAT I Water Quality Work Group

DTIC Science & Technology

1976-07-01

coliform, fecal coliform, and fecal streptococcus densities. Salmonellae and shigellae were not recovered from either upstream water samples or from...fecal streptococci, Clostridlum perfringens) and enteric pathogens (salmonellae, shigellae , enteroviruses, infectious hepatitus agent) have beeii shown...the Mississippi River that was polluted with Shigella sonnet (5,32). 49W 1.----Wq W P4 p TABLE 1. Incidence of selected enteric diseases during 1975 in

Illicit drugs and the environment--a review.

PubMed

Pal, Raktim; Megharaj, Mallavarapu; Kirkbride, K Paul; Naidu, Ravi

2013-10-01

Illicit drugs and their metabolites are the latest group of emerging pollutants. Determination of their concentration in environment (such as water bodies, soil, sediment, air) is an indirect tool to estimate the community level consumption of illicit drug and to evaluate potential ecotoxicological impacts from chronic low level exposure. They enter the wastewater network as unaltered drugs and/or their active metabolites by human excretion after illegal consumption or by accidental or deliberate disposal from clandestine drug laboratories. This article critically reviews the occurrence and concentration levels of illicit drugs and their metabolites in different environmental compartments (e.g., wastewater, surface waters, groundwater, drinking water, and ambient air) and their potential impact on the ecosystem. There is limited published information available on the presence of illicit drugs in the environment, reports are available mainly from European countries, UK, USA, and Canada but there is a lack of information from the remainder of the world. Although the environmental concentrations are not very high, they can potentially impact the human health and ecosystem functioning. Cocaine, morphine, amphetamine, and MDMA have potent pharmacological activities and their presence as complex mixtures in water may cause adverse effect on aquatic organisms and human health. However, there is no current regulation demanding the determination of occurrence of these emerging pollutants in treated wastewater, surface water, drinking water, or atmosphere. Thus, critical investigation on distribution pattern of this new group of emerging contaminant and their potential harmful impact on our environment needs immediate attention. Copyright © 2012. Published by Elsevier B.V.

Auxin Uptake and the Rapid Auxin-Induced Growth in Isolated Sections of Helianthus annuus

PubMed Central

Firn, Richard D.

1982-01-01

When a sunflower (Helianthus annuus L.) hypocotyl section is placed in a solution of 10 micromolar 1-naphthylacetic acid, the majority of the auxin enters via the cut surfaces. However, it is the minority entering radially which causes the typical growth response. Auxin supplied only to the apical cut surface gives a weak, slower response. PMID:16662719

Communitywide cryptosporidiosis outbreak associated with a surface water-supplied municipal water system--Baker City, Oregon, 2013.

PubMed

DeSilva, M B; Schafer, S; Kendall Scott, M; Robinson, B; Hills, A; Buser, G L; Salis, K; Gargano, J; Yoder, J; Hill, V; Xiao, L; Roellig, D; Hedberg, K

2016-01-01

Cryptosporidium, a parasite known to cause large drinking and recreational water outbreaks, is tolerant of chlorine concentrations used for drinking water treatment. Human laboratory-based surveillance for enteric pathogens detected a cryptosporidiosis outbreak in Baker City, Oregon during July 2013 associated with municipal drinking water. Objectives of the investigation were to confirm the outbreak source and assess outbreak extent. The watershed was inspected and city water was tested for contamination. To determine the community attack rate, a standardized questionnaire was administered to randomly sampled households. Weighted attack rates and confidence intervals (CIs) were calculated. Water samples tested positive for Cryptosporidium species; a Cryptosporidium parvum subtype common in cattle was detected in human stool specimens. Cattle were observed grazing along watershed borders; cattle faeces were observed within watershed barriers. The city water treatment facility chlorinated, but did not filter, water. The community attack rate was 28·3% (95% CI 22·1-33·6), sickening an estimated 2780 persons. Watershed contamination by cattle probably caused this outbreak; water treatments effective against Cryptosporidium were not in place. This outbreak highlights vulnerability of drinking water systems to pathogen contamination and underscores the need for communities to invest in system improvements to maintain multiple barriers to drinking water contamination.

Sampling methods for recovery of human enteric viruses from environmental surfaces.

PubMed

Turnage, Nicole L; Gibson, Kristen E

2017-10-01

Acute gastroenteritis causes the second highest infectious disease burden worldwide. Human enteric viruses have been identified as leading causative agents of acute gastroenteritis as well as foodborne illnesses in the U.S. and are generally transmitted by fecal-oral contamination. There is growing evidence of transmission occurring via contaminated fomite including food contact surfaces. Additionally, human enteric viruses have been shown to remain infectious on fomites over prolonged periods of time. To better understand viral persistence, there is a need for more studies to investigate this phenomenon. Therefore, optimization of surface sampling methods is essential to aid in understanding environmental contamination to ensure proper preventative measures are being applied. In general, surface sampling studies are limited and highly variable among recovery efficiencies and research parameters used (e.g., virus type/density, surface type, elution buffers, tools). This review aims to discuss the various factors impacting surface sampling of viruses from fomites and to explore how researchers could move towards a more sensitive and standard sampling method. Copyright © 2017 Elsevier B.V. All rights reserved.

Comparative assessment of the bacterial communities associated with Aedes aegypti larvae and water from domestic water storage containers.

PubMed

Dada, Nsa; Jumas-Bilak, Estelle; Manguin, Sylvie; Seidu, Razak; Stenström, Thor-Axel; Overgaard, Hans J

2014-08-24

Domestic water storage containers constitute major Aedes aegypti breeding sites. We present for the first time a comparative analysis of the bacterial communities associated with Ae. aegypti larvae and water from domestic water containers. The 16S rRNA-temporal temperature gradient gel electrophoresis (TTGE) was used to identify and compare bacterial communities in fourth-instar Ae. aegypti larvae and water from larvae positive and negative domestic containers in a rural village in northeastern Thailand. Water samples were cultured for enteric bacteria in addition to TTGE. Sequences obtained from TTGE and bacterial cultures were clustered into operational taxonomic units (OTUs) for analyses. Significantly lower OTU abundance was found in fourth-instar Ae. aegypti larvae compared to mosquito positive water samples. There was no significant difference in OTU abundance between larvae and mosquito negative water samples or between mosquito positive and negative water samples. Larval samples had significantly different OTU diversity compared to mosquito positive and negative water samples, with no significant difference between mosquito positive and negative water samples. The TTGE identified 24 bacterial taxa, belonging to the phyla Proteobacteria, Firmicutes, Actinobacteria, Bacteroidetes and TM7 (candidate phylum). Seven of these taxa were identified in larval samples, 16 in mosquito positive and 13 in mosquito negative water samples. Only two taxa, belonging to the phyla Firmicutes and Actinobacteria, were common to both larvae and water samples. Bacilli was the most abundant bacterial class identified from Ae. aegypti larvae, Gammaproteobacteria from mosquito positive water samples, and Flavobacteria from mosquito negative water samples. Enteric bacteria belonging to the class Gammaproteobacteria were sparsely represented in TTGE, but were isolated from both mosquito positive and negative water samples by selective culture. Few bacteria from water samples were identified in fourth-instar Ae. aegypti larvae, suggesting that established larval bacteria, most likely acquired at earlier stages of development, control the larval microbiota. Further studies at all larval stages are needed to fully understand the dynamics involved. Isolation of enteric bacteria from water samples supports earlier outcomes of E. coli contamination in Ae. aegypti infested domestic containers, suggesting the need to further explore the role of enteric bacteria in Ae. aegypti infestation.

Sources and dispersive modes of micro-fibers in the environment.

PubMed

Carr, Steve A

2017-05-01

Understanding the sources and distribution of microfibers (MFs) in the environment is critical if control and remediation measures are to be effective. Microfibers comprise an overwhelming fraction (>85%) of microplastic debris found on shorelines around the world. Although primary sources have not been fully vetted, until recently it was widely believed that domestic laundry discharges were the major source. It was also thought that synthetic fibers and particles having dimensions <5 mm easily bypassed filtration and other solid separation processes at wastewater treatment plants (WWTPs) and entered oceans and surface waters. A more thorough assessment of WWTP effluent discharges indicates, however, that fiber and particulate counts do not support the belief that plants are the primary vectors for fibers entering the environment. This finding may bolster concerns that active and pervasive shedding of fibers from common fabrics and textiles could be contributing significantly, via direct pathways, to burgeoning environmental loads. Integr Environ Assess Manag 2017;13:466-469. © 2017 SETAC. © 2017 SETAC.

Attenuation of Scattered Thermal Energy Atomic Oxygen

NASA Technical Reports Server (NTRS)

Banks, Bruce a.; Seroka, Katelyn T.; McPhate, Jason B.; Miller, Sharon K.

2011-01-01

The attenuation of scattered thermal energy atomic oxygen is relevant to the potential damage that can occur within a spacecraft which sweeps through atomic oxygen in low Earth orbit (LEO). Although there can be significant oxidation and resulting degradation of polymers and some metals on the external surfaces of spacecraft, there are often openings on a spacecraft such as telescope apertures, vents, and microwave cavities that can allow atomic oxygen to enter and scatter internally to the spacecraft. Atomic oxygen that enters a spacecraft can thermally accommodate and scatter to ultimately react or recombine on surfaces. The atomic oxygen that does enter a spacecraft can be scavenged by use of high erosion yield polymers to reduce its reaction on critical surfaces and materials. Polyoxymethylene and polyethylene can be used as effective atomic oxygen scavenging polymers.

Differential Epidemiology of Salmonella Typhi and Paratyphi A in Kathmandu, Nepal: A Matched Case Control Investigation in a Highly Endemic Enteric Fever Setting

PubMed Central

Tran Vu Thieu, Nga; Dongol, Sabina; Le Thi Phuong, Tu; Voong Vinh, Phat; Arjyal, Amit; Martin, Laura B.; Rondini, Simona; Farrar, Jeremy J.; Dolecek, Christiane; Basnyat, Buddha; Baker, Stephen

2013-01-01

Background Enteric fever, a systemic infection caused by the bacteria Salmonella Typhi and Salmonella Paratyphi A, is endemic in Kathmandu, Nepal. Previous work identified proximity to poor quality water sources as a community-level risk for infection. Here, we sought to examine individual-level risk factors related to hygiene and sanitation to improve our understanding of the epidemiology of enteric fever in this setting. Methodology and principal findings A matched case-control analysis was performed through enrollment of 103 blood culture positive enteric fever patients and 294 afebrile community-based age and gender-matched controls. A detailed questionnaire was administered to both cases and controls and the association between enteric fever infection and potential exposures were examined through conditional logistic regression. Several behavioral practices were identified as protective against infection with enteric fever, including water storage and hygienic habits. Additionally, we found that exposures related to poor water and socioeconomic status are more influential in the risk of infection with S. Typhi, whereas food consumption habits and migration play more of a role in risk of S. Paratyphi A infection. Conclusions and significance Our work suggests that S. Typhi and S. Paratyphi A follow different routes of infection in this highly endemic setting and that sustained exposure to both serovars probably leads to the development of passive immunity. In the absence of a polyvalent vaccine against S. Typhi and S. Paratyphi A, we advocate better systems for water treatment and storage, improvements in the quality of street food, and vaccination with currently available S. Typhi vaccines. PMID:23991240

Glacial reduction and millennial-scale variations in Drake Passage throughflow.

PubMed

Lamy, Frank; Arz, Helge W; Kilian, Rolf; Lange, Carina B; Lembke-Jene, Lester; Wengler, Marc; Kaiser, Jérôme; Baeza-Urrea, Oscar; Hall, Ian R; Harada, Naomi; Tiedemann, Ralf

2015-11-03

The Drake Passage (DP) is the major geographic constriction for the Antarctic Circumpolar Current (ACC) and exerts a strong control on the exchange of physical, chemical, and biological properties between the Atlantic, Pacific, and Indian Ocean basins. Resolving changes in the flow of circumpolar water masses through this gateway is, therefore, crucial for advancing our understanding of the Southern Ocean's role in global ocean and climate variability. Here, we reconstruct changes in DP throughflow dynamics over the past 65,000 y based on grain size and geochemical properties of sediment records from the southernmost continental margin of South America. Combined with published sediment records from the Scotia Sea, we argue for a considerable total reduction of DP transport and reveal an up to ∼ 40% decrease in flow speed along the northernmost ACC pathway entering the DP during glacial times. Superimposed on this long-term decrease are high-amplitude, millennial-scale variations, which parallel Southern Ocean and Antarctic temperature patterns. The glacial intervals of strong weakening of the ACC entering the DP imply an enhanced export of northern ACC surface and intermediate waters into the South Pacific Gyre and reduced Pacific-Atlantic exchange through the DP ("cold water route"). We conclude that changes in DP throughflow play a critical role for the global meridional overturning circulation and interbasin exchange in the Southern Ocean, most likely regulated by variations in the westerly wind field and changes in Antarctic sea ice extent.

Glacial reduction and millennial-scale variations in Drake Passage throughflow

PubMed Central

Lamy, Frank; Arz, Helge W.; Kilian, Rolf; Lange, Carina B.; Lembke-Jene, Lester; Wengler, Marc; Kaiser, Jérôme; Baeza-Urrea, Oscar; Hall, Ian R.; Harada, Naomi; Tiedemann, Ralf

2015-01-01

The Drake Passage (DP) is the major geographic constriction for the Antarctic Circumpolar Current (ACC) and exerts a strong control on the exchange of physical, chemical, and biological properties between the Atlantic, Pacific, and Indian Ocean basins. Resolving changes in the flow of circumpolar water masses through this gateway is, therefore, crucial for advancing our understanding of the Southern Ocean’s role in global ocean and climate variability. Here, we reconstruct changes in DP throughflow dynamics over the past 65,000 y based on grain size and geochemical properties of sediment records from the southernmost continental margin of South America. Combined with published sediment records from the Scotia Sea, we argue for a considerable total reduction of DP transport and reveal an up to ∼40% decrease in flow speed along the northernmost ACC pathway entering the DP during glacial times. Superimposed on this long-term decrease are high-amplitude, millennial-scale variations, which parallel Southern Ocean and Antarctic temperature patterns. The glacial intervals of strong weakening of the ACC entering the DP imply an enhanced export of northern ACC surface and intermediate waters into the South Pacific Gyre and reduced Pacific–Atlantic exchange through the DP (“cold water route”). We conclude that changes in DP throughflow play a critical role for the global meridional overturning circulation and interbasin exchange in the Southern Ocean, most likely regulated by variations in the westerly wind field and changes in Antarctic sea ice extent. PMID:26417070

Use of molecular approaches in hydrogeological studies: the case of carbonate aquifers in southern Italy

NASA Astrophysics Data System (ADS)

Bucci, Antonio; Petrella, Emma; Celico, Fulvio; Naclerio, Gino

2017-06-01

Waterborne pathogens represent a significant health risk in both developed and developing countries with sensitive sub-populations including children, the elderly, neonates, and immune-compromised people, who are particularly susceptible to enteric infections. Annually, approximately 1.8 billion people utilize a faecally contaminated water source, and waterborne diseases are resulting in up to 2.1 million human mortalities globally. Although groundwater has traditionally been considered less susceptible to contamination by enteric pathogens than surface water due to natural attenuation by overlying strata, the degree of microbial removal attributable to soils and aquifers can vary significantly depending on several factors. Thus, accurate assessment of the variable presence and concentration of microbial contaminants, and the relative importance of potentially causative factors affecting contaminant ingress, is critical in order to develop effective source (well) and resource (aquifer) protection strategies. "Traditional" and molecular microbiological study designs, when coupled with hydrogeological, hydrochemical, isotopic, and geophysical methods, have proven useful for analysis of numerous aspects of subsurface microbial dynamics. Accordingly, this overview paper presents the principal microbial techniques currently being employed (1) to predict and identify sources of faecal contamination in groundwater, (2) to elucidate the dynamics of contaminant migration, and (3) to refine knowledge about the hydrogeological characteristics and behaviours of aquifer systems affected by microbial contamination with an emphasis on carbonate aquifers, which represent an important global water supply. Previous investigations carried out in carbonate aquifers in southern Italy are discussed.

A systematic review of zoonotic enteric parasitic diseases among nomadic and pastoral people

PubMed Central

Davaasuren, Anu; Baasandagva, Uyanga; Gray, Gregory C.

2017-01-01

Introduction Zoonotic enteric parasites are ubiquitous and remain a public health threat to humans due to our close relationship with domestic animals and wildlife, inadequate water, sanitation, and hygiene practices and diet. While most communities are now sedentary, nomadic and pastoral populations still exist and experience unique exposure risks for acquiring zoonotic enteric parasites. Through this systematic review we sought to summarize published research regarding pathogens present in nomadic populations and to identify the risk factors for their infection. Methods Using systematic review guidelines set forth by PRISMA, research articles were identified, screened and summarized based on exclusion criteria for the documented presence of zoonotic enteric parasites within nomadic or pastoral human populations. A total of 54 articles published between 1956 and 2016 were reviewed to determine the pathogens and exposure risks associated with the global transhumance lifestyle. Results The included articles reported more than twenty different zoonotic enteric parasite species and illustrated several risk factors for nomadic and pastoralist populations to acquire infection including; a) animal contact, b) food preparation and diet, and c) household characteristics. The most common parasite studied was Echinococcosis spp. and contact with dogs was recognized as a leading risk factor for zoonotic enteric parasites followed by contact with livestock and/or wildlife, water, sanitation, and hygiene barriers, home slaughter of animals, environmental water exposures, household member age and sex, and consumption of unwashed produce or raw, unprocessed, or undercooked milk or meat. Conclusion Nomadic and pastoral communities are at risk of infection with a variety of zoonotic enteric parasites due to their living environment, cultural and dietary traditions, and close relationship to animals. Global health efforts aimed at reducing the transmission of these animal-to-human pathogens must incorporate a One Health approach to support water, sanitation, and hygiene development, provide education on safe food handling and preparation, and improve the health of domestic animals associated with these groups, particularly dogs. PMID:29190664

A systematic review of zoonotic enteric parasitic diseases among nomadic and pastoral people.

PubMed

Barnes, Amber N; Davaasuren, Anu; Baasandagva, Uyanga; Gray, Gregory C

2017-01-01

Zoonotic enteric parasites are ubiquitous and remain a public health threat to humans due to our close relationship with domestic animals and wildlife, inadequate water, sanitation, and hygiene practices and diet. While most communities are now sedentary, nomadic and pastoral populations still exist and experience unique exposure risks for acquiring zoonotic enteric parasites. Through this systematic review we sought to summarize published research regarding pathogens present in nomadic populations and to identify the risk factors for their infection. Using systematic review guidelines set forth by PRISMA, research articles were identified, screened and summarized based on exclusion criteria for the documented presence of zoonotic enteric parasites within nomadic or pastoral human populations. A total of 54 articles published between 1956 and 2016 were reviewed to determine the pathogens and exposure risks associated with the global transhumance lifestyle. The included articles reported more than twenty different zoonotic enteric parasite species and illustrated several risk factors for nomadic and pastoralist populations to acquire infection including; a) animal contact, b) food preparation and diet, and c) household characteristics. The most common parasite studied was Echinococcosis spp. and contact with dogs was recognized as a leading risk factor for zoonotic enteric parasites followed by contact with livestock and/or wildlife, water, sanitation, and hygiene barriers, home slaughter of animals, environmental water exposures, household member age and sex, and consumption of unwashed produce or raw, unprocessed, or undercooked milk or meat. Nomadic and pastoral communities are at risk of infection with a variety of zoonotic enteric parasites due to their living environment, cultural and dietary traditions, and close relationship to animals. Global health efforts aimed at reducing the transmission of these animal-to-human pathogens must incorporate a One Health approach to support water, sanitation, and hygiene development, provide education on safe food handling and preparation, and improve the health of domestic animals associated with these groups, particularly dogs.

Sources of Water to Wells for Transient Cyclic Systems

USGS Publications Warehouse

Reilly, T.E.; Pollock, D.W.

1996-01-01

Many state agencies are currently (1995) developing wellhead protection programs. The thrust of some of these programs is to protect water supplies by determining the areas contributing recharge to water-supply wells and by specifying regulations to minimize the opportunity for contamination of the recharge water by activities at the land surface. The area contributing recharge to a discharging well is the surface area at the water table through which the water flowing to the well entered the ground-water system. In the analyses of ground-water flow systems, steady-state average conditions are commonly used to simplify the problem and make a solution tractable. However, recharge is usually cyclic in nature, with seasonal cycles and longer term climatic cycles. The effect of these cyclic stresses on the area contributing recharge to wells is quantitatively analyzed for a hypothetical alluvial valley aquifer system that is representative of a large class of ground-water systems that are extensively developed for water supply. The analysis shows that, in many cases, these cyclic changes in the recharge rates do not significantly affect the location and size of the areas contributing recharge to wells. The ratio of the mean travel time to the length of the cyclic stress period appears to be an indicator of whether the transient effects of the cyclic stress must be explicitly represented in the analysis of contributing areas to wells. For the cases examined, if the ratio of the mean travel time to the period of the cyclic stress was much greater than one, then the transient area contributing recharge to wells was similar to the area calculated using an average steady-state condition. However, cyclic stresses on systems with ratios less than one do have an effect on the location and size of the areas contributing recharge to wells.

[Hydrochemistry and Dissolved Inorganic Carbon Stable Isotope of Shibing Dolomite Karst Area in Guizhou Province].

PubMed

Xiao, Shi-zhen; Lan, Jia-cheng; Yuan, Dao-xian; Wang, Yun; Yang, Long; Ao, Xiang-hong

2015-06-01

Totally 49 water samples were collected in Shibing Dolomite Karst World Natural Heritage Site in Guizhou Province to analyze the characteristics and controlling factors of both the surface and underground waters, as well as the features and their origins of the dissolved inorganic carbon isotope. It was found that the pH of the study area was neutral to alkaline with low concentrations of total dissolved solids. The cations were dominated by Ca2+, Mg2 and anions by HCO3-, featured by HCO3-Ca x Mg type water. The ratios of Cl-, NO3- and SO4(2-) in the allogenic water from the shale area in the northern catchment were higher than those in autogenic water from the dolomite karst area, so did the concentration of Si. The SIc and SId of the allogenic waters in the shale area were negative. After the waters entered into and flew by the dolomite karst area, both the SIc and SId increased to over 0. It could be told by the water chemistry that the hydrochemistry was little impacted by the rainfall and human activities. The Gibbs plot revealed that the chemical composition of the waters was mainly controlled by rock weathering. The δ(13)C(DIC) of the surface waters ranged from -8.27% to -11.55% per hundred, averaging -9.45% per hundredo, while that of the underground waters ranged from -10.57% per hundred to -15.59% per hundred, averaging -12.04% per hundred, which was lighter than that of surface water. For the distribution features, it was found the δ(13)C(DIC), of the upper reaches of branches of Shangmuhe River was lighter than that of the lower reach, while that of the main river Shangmuhe River was relatively complex. Based on the mass balance of stable isotopes and the δ(13)C(DIC), the ratio of the origin of DIC of the ground water was calculated. It was found that 51.2% was from soil CO2, and 48.8% was from the rock itself.

Hydrogeology and simulation of ground-water flow and land-surface subsidence in the northern part of the Gulf Coast aquifer system, Texas

USGS Publications Warehouse

Kasmarek, Mark C.; Robinson, James L.

2004-01-01

As a part of the Texas Water Development Board Ground- Water Availability Modeling program, the U.S. Geological Survey developed and tested a numerical finite-difference (MODFLOW) model to simulate ground-water flow and land-surface subsidence in the northern part of the Gulf Coast aquifer system in Texas from predevelopment (before 1891) through 2000. The model is intended to be a tool that water-resource managers can use to address future ground-water-availability issues.From land surface downward, the Chicot aquifer, the Evangeline aquifer, the Burkeville confining unit, the Jasper aquifer, and the Catahoula confining unit are the hydrogeologic units of the Gulf Coast aquifer system. Withdrawals of large quantities of ground water have resulted in potentiometric surface (head) declines in the Chicot, Evangeline, and Jasper aquifers and land-surface subsidence (primarily in the Houston area) from depressurization and compaction of clay layers interbedded in the aquifer sediments. In a generalized conceptual model of the aquifer system, water enters the ground-waterflow system in topographically high outcrops of the hydrogeologic units in the northwestern part of the approximately 25,000-square-mile model area. Water that does not discharge to streams flows to intermediate and deep zones of the system southeastward of the outcrop areas where it is discharged by wells and by upward leakage in topographically low areas near the coast. The uppermost parts of the aquifer system, which include outcrop areas, are under water-table conditions. As depth increases in the aquifer system and as interbedded sand and clay accumulate, water-table conditions evolve into confined conditions.The model comprises four layers, one for each of the hydrogeologic units of the aquifer system except the Catahoula confining unit, the assumed no-flow base of the system. Each layer consists of 137 rows and 245 columns of uniformly spaced grid blocks, each block representing 1 square mile. Lateral no-flow boundaries were located on the basis of outcrop extent (northwestern), major streams (southwestern, northeastern), and downdip limit of freshwater (southeastern). The MODFLOW general-head boundary package was used to simulate recharge and discharge in the outcrops of the hydrogeologic units. Simulation of land-surface subsidence (actually, compaction of clays) and release of water from storage in the clays of the Chicot and Evangeline aquifers was accomplished using the Interbed-Storage Package designed for use with the MODFLOW model. The model was calibrated by trial-anderror adjustment of selected model input data in a series of transient simulations until the model output (potentiometric surfaces, land-surface subsidence, and selected water-budget components) reasonably reproduced field measured (or estimated) aquifer responses.Model calibration comprised four elements: The first was qualitative comparison of simulated and measured heads in the aquifers for 1977 and 2000; and quantitative comparison by computation and areal distribution of the root-mean-square error between simulated and measured heads. The second calibration element was comparison of simulated and measured hydrographs from wells in the aquifers in a number of counties throughout the modeled area. The third calibration element was comparison of simulated water-budget componentsprimarily recharge and dischargeto estimates of physically reasonable ranges of actual water-budget components. The fourth calibration element was comparison of simulated land-surface subsidence from predevelopment to 2000 to measured land surface subsidence from 1906 through 1995.

Hot water tank for use with a combination of solar energy and heat-pump desuperheating

DOEpatents

Andrews, J.W.

1980-06-25

A water heater or system is described which includes a hot water tank having disposed therein a movable baffle to function as a barrier between the incoming volume of cold water entering the tank and the volume of heated water entering the tank which is heated by the circulation of the cold water through a solar collector and/or a desuperheater of a heat pump so as to optimize the manner in which heat is imparted to the water in accordance to the demand on the water heater or system. A supplemental heater is also provided and it is connected so as to supplement the heating of the water in the event that the solar collector and/or desuperheater cannot impart all of the desired heat input into the water.

Elution Is a Critical Step for Recovering Human Adenovirus 40 from Tap Water and Surface Water by Cross-Flow Ultrafiltration

PubMed Central

Shi, Hang; Xagoraraki, Irene; Bruening, Merlin L.

2016-01-01

ABSTRACT This paper examines the recovery of the enteric adenovirus human adenovirus 40 (HAdV 40) by cross-flow ultrafiltration and interprets recovery values in terms of physicochemical interactions of virions during sample concentration. Prior to ultrafiltration, membranes were either blocked by exposure to calf serum (CS) or coated with a polyelectrolyte multilayer (PEM). HAdV 40 is a hydrophobic virus with a point of zero charge between pH 4.0 and pH 4.3. In accordance with predictions from the extended Derjaguin-Landau-Verwey-Overbeek theory, the preelution recovery of HAdV (rpre) from deionized water was higher with PEM-coated membranes (rprePEM = 74.8% ± 9.7%) than with CS-blocked membranes (rpreCS = 54.1% ± 6.2%). With either membrane type, the total virion recovery after elution (rpost) was high for both deionized water (rpostPEM = 99.5% ± 6.6% and rpostCS = 98.8% ± 7.7%) and tap water (rpostPEM = 89% ± 15% and rpostCS = 93.7% ± 6.9%). The nearly 100% recoveries suggest that the polyanion (sodium polyphosphate) and surfactant (Tween 80) in the eluent disrupt electrostatic and hydrophobic interactions between the virion and the membrane. Addition of EDTA to the eluent greatly improved the elution efficacy (rpostCS = 88.6% ± 4.3% and rpostPEM = 87.0% ± 6.9%) with surface water, even when the organic carbon concentration in the water was high (9.4 ± 0.1 mg/liter). EDTA likely disrupts cation bridging between virions and particles in the feed water matrix or the fouling layer on the membrane surface. For complex water matrices, the eluent composition is the most important factor for achieving high virion recovery. IMPORTANCE Herein we present the results of a comprehensive physicochemical characterization of HAdV 40, an important human pathogen. The data on HAdV 40 surface properties enabled rigorous modeling to gain an understanding of the energetics of virion-virion and virion-filter interactions. Cross-flow filtration for concentration and recovery of HAdV 40 was evaluated, with postelution recoveries from ultrapure water (99%), tap water (∼91%), and high-carbon-content surface water (∼84%) being demonstrated. These results are significant because of the very low adenovirus recoveries that have been reported, to date, for other methods. The recovery data were interpreted in terms of specific interactions, and the eluent composition was designed accordingly to maximize HAdV 40 recovery. PMID:27287319

Development of the initial diatom microfouling layer on antifouling and fouling-release surfaces in temperate and tropical Australia.

PubMed

Molino, Paul J; Campbell, Ewan; Wetherbee, Richard

2009-11-01

Diatoms are a major component of the slime layers that form on artificial surfaces in marine environments. In this article, the role played by diatoms during the pioneering stages of colonization of three marine antifouling (AF) coatings, viz Intersmooth 360, Super Yacht 800 and a fouling-release (FR) coating Intersleek 700, was investigated. The study was conducted over three distinct seasons in two very different marine environments in Australia, ie temperate Williamstown, Victoria and tropical Cairns, Queensland. Diatom fouling occurred more rapidly on the FR coating Intersleek 700, compared to both biocidal AF paints. However, colonization by diatoms on all three coatings was generally slow during the 16-day study. Benthic diatoms do not subsist by floating around in the water column, rather they only gain the opportunity to colonize new surfaces when they either voluntarily release or are displaced from their benthic habitat, thereafter entering the water column where the opportunity to adhere to a new surface presents itself. However, once settled, fouling diatoms grow exponentially from the site of attachment, spreading out until they populate large areas of the surface. This mode of surface colonization correlates more with an 'infection' type, epidemiology model, a mechanism that accounts for the colonization of significant regions of the coating surface from a single fouling diatom cell, forming 'clonal patches'. This is in comparison to the bacterial colonization of the surface, which exhibits far more rapid recruitment and growth of cells on the substratum surface. Therefore, it is hypothesized that fouling diatoms may be characterized more by their ability to adhere and grow on surfaces already modified by bacterial biofilms, rather than on their strength of adhesion. Cell morphology and the ability to avoid shear may also be an important factor.

Radioactive Water Treatment at a United States Environmental Protection Agency Superfund Site - 12322

DOE Office of Scientific and Technical Information (OSTI.GOV)

Beckman, John C.

2012-07-01

A water treatment system at a United States Environmental Protection Agency (USEPA) Superfund site impacted by radiological contaminants is used to treat water entering the site. The United States Army Corps of Engineers (USACE) is actively managing the remedial action for the USEPA using contracts to support the multiple activities on site. The site is where former gas mantle production facilities operated around the turn of the century. The manufacturing facilities used thorium ores to develop the mantles and disposed of off-specification mantles and ore residuals in the surrounding areas. During Site remedial actions, both groundwater and surface water comesmore » into contact with contaminated soils and must be collected and treated at an on-site treatment facility. The radionuclides thorium and radium with associated progeny are the main concern for treatment. Suspended solids, volatile organic compounds, and select metals are also monitored during water treatment. The water treatment process begins were water is pumped to a collection tank where debris and grit settle out. Stored water is pumped to a coagulant tank containing poly-aluminum chloride to collect dissolved solids. The water passes into a reaction tube where aspirated air is added or reagent added to remove Volatile Organic Compounds (VOC'S) by mass transfer and convert dissolved iron to a solid. The water enters the flocculent polymer tank to drop solids out. The flocculated water overflows to a fluidized bed contact chamber to increase precipitation. Flocculation is where colloids of material drop out of suspension and settle. The settled solids are periodically removed and disposed of as radioactive waste. The water is passed through filters and an ion exchange process to extract the radionuclides. Several million liters of water are processed each year from two water treatment plants servicing different areas of the remediation site. Ion exchange resin and filter material are periodically replaced and disposed of as radioactive waste. A total of 0.85 m{sup 3} of waste sludge per year requires disposal on average, in addition to another 6.6 m{sup 3} of waste cartridge filters. All water discharges are regulated by a state of New Jersey Pollutant Discharge Elimination System Permit implemented by the Federal Water Pollution Control Act (Clean Water Act). Laboratory analyses are required to satisfy requirements of the state NPDES permit. Specific monitoring parameters and discharge rates will be provided. Use of the water treatment systems drastically reduces the amount of contaminated water requiring solidification and water disposal to near zero. Millions of liters of potentially contaminated water from excavation activities is treated and released within permit limits. A small volume of solid radioactive waste (21 cubic meters) is generated annually from water treatment process operations. Management of ground and surface water is effectively controlled in remediation areas by the use of sumps, erosion control measures and pumping of water to storage vessels. Continued excavations can be made as water impacting the site is effectively controlled. (authors)« less

Surface interactions and degradation of a fluoroquinolone antibiotic in the dark in aqueous TiO 2 suspensions

DOE PAGES

Peterson, Jonathan W.; Gu, Baohua; Seymour, Michael D.

2015-06-15

Fluoroquinolone antibiotics (FQs) are important drugs used in human and veterinary medicine. Their detection in natural waters and waste water treatment plants, along with increased resistance to FQs among some bacteria, have generated an increased interest in the fate of these drugs in the environment. Partitioning of FQs between an aqueous solution and attendant substrates depends, in part, on the surface reactivity of the adsorbent, commonly a function of particle size, surface charge, and functional groups. In this paper, this study investigated the surface interactions between the FQ drug ofloxacin (OFL) and titanium oxide (TiO 2), a common catalyst andmore » widely-observed constituent in many consumer products. Raman and fluorescence spectroscopic techniques, as well as LC/MS, were used to determine the OFL moieties present on TiO 2 surfaces and in attendant solutions. Raman spectra indicate that the C==O (ketone) group of the quinolone core, the NH + of the piperazinyl ring, and CH 3 of benzoxazine core are the most active in sorption onto the TiO 2 surface. Raman spectra also show that the sorbed benzoxazine–quinolone core and piperazinyl moieties are readily desorbed from the surface by re-suspending samples in water. Importantly, we found that OFL could be degraded by reacting with TiO 2 even in the dark. Complementary LC/MS analysis of the attendant supernatants indicates the presence of de-piperazinylated and de-carboxylated OFL breakdown products in supernatant solutions. Together, both Raman and LC/MS analyses indicate that TiO 2 breaks the compound into piperazinyl and carboxylate groups which attach to the surface, whereas de-carboxylated and hydroxylated quinolone moieties remain in solution. Finally, the present study thus identifies the sorption mechanisms and breakdown products of OFL during dark reactions with TiO 2, which is critically important for understanding the fate and transport of OFL as it enters the soil and aquatic environment.« less

Surface interactions and degradation of a fluoroquinolone antibiotic in the dark in aqueous TiO2 suspensions.

PubMed

Peterson, Jonathan W; Gu, Baohua; Seymour, Michael D

2015-11-01

Fluoroquinolone antibiotics (FQs) are important drugs used in human and veterinary medicine. Their detection in natural waters and waste water treatment plants, along with increased resistance to FQs among some bacteria, have generated an increased interest in the fate of these drugs in the environment. Partitioning of FQs between an aqueous solution and attendant substrates depends, in part, on the surface reactivity of the adsorbent, commonly a function of particle size, surface charge, and functional groups. This study investigated the surface interactions between the FQ drug ofloxacin (OFL) and titanium oxide (TiO2), a common catalyst and widely-observed constituent in many consumer products. Raman and fluorescence spectroscopic techniques, as well as LC/MS, were used to determine the OFL moieties present on TiO2 surfaces and in attendant solutions. Raman spectra indicate that the CO (ketone) group of the quinolone core, the NH(+) of the piperazinyl ring, and CH3 of benzoxazine core are the most active in sorption onto the TiO2 surface. Raman spectra also show that the sorbed benzoxazine-quinolone core and piperazinyl moieties are readily desorbed from the surface by re-suspending samples in water. Importantly, we found that OFL could be degraded by reacting with TiO2 even in the dark. Complementary LC/MS analysis of the attendant supernatants indicates the presence of de-piperazinylated and de-carboxylated OFL breakdown products in supernatant solutions. Together, both Raman and LC/MS analyses indicate that TiO2 breaks the compound into piperazinyl and carboxylate groups which attach to the surface, whereas de-carboxylated and hydroxylated quinolone moieties remain in solution. The present study thus identifies the sorption mechanisms and breakdown products of OFL during dark reactions with TiO2, which is critically important for understanding the fate and transport of OFL as it enters the soil and aquatic environment. Copyright © 2015 Elsevier B.V. All rights reserved.

FRNA Bacteriophages as Viral Indicators of Faecal Contamination in Mexican Tropical Aquatic Systems.

PubMed

Arredondo-Hernandez, Luis Jose Rene; Diaz-Avalos, Carlos; Lopez-Vidal, Yolanda; Castillo-Rojas, Gonzalo; Mazari-Hiriart, Marisa

2017-01-01

A particular challenge to water safety in populous intertropical regions is the lack of reliable faecal indicators to detect microbiological contamination of water, while the numerical relationships of specific viral indicators remain largely unexplored. The aim of this study was to investigate the numerical relationships of FRNA-bacteriophage genotypes, adenovirus 41, and human adenoviruses (HADV) in Mexican surface water systems to assess sewage contamination. We studied the presence of HADV, HADV41 and FRNA bacteriophage genotypes in water samples and quantified by qPCR and RT-qPCR. Virus and water quality indicator variances, as analyzed by principal component analysis and partial least squared regression, followed along the major percentiles of water faecal enterococci. FRNA bacteriophages adequately deciphered viral and point source water contamination. The strongest correlation for HADV was with FRNA bacteriophage type II, in water samples higher than the 50th percentiles of faecal enterococci, thus indicating urban pollution. FRNA bacteriophage genotypes I and III virus indicator performances were assisted by their associations with electrical conductivity and faecal enterococci. In combination, our methods are useful for inferring water quality degradation caused by sewage contamination. The methods used have potential for determining source contamination in water and, specifically, the presence of enteric viruses where clean and contaminated water have mixed.

User's manual for the National Water Information System of the U.S. Geological Survey: Automated Data Processing System (ADAPS)

USGS Publications Warehouse

,

2003-01-01

The Automated Data Processing System (ADAPS) was developed for the processing, storage, and retrieval of water data, and is part of the National Water Information System (NWIS) developed by the U.S. Geological Survey. NWIS is a distributed water database in which data can be processed over a network of computers at U.S. Geological Survey offices throughout the United States. NWIS comprises four subsystems: ADAPS, the Ground-Water Site Inventory System (GWSI), the Water-Quality System (QWDATA), and the Site-Specific Water-Use Data System (SWUDS). This section of the NWIS User's Manual describes the automated data processing of continuously recorded water data, which primarily are surface-water data; however, the system also allows for the processing of water-quality and ground-water data. This manual describes various components and features of the ADAPS, and provides an overview of the data processing system and a description of the system framework. The components and features included are: (1) data collection and processing, (2) ADAPS menus and programs, (3) command line functions, (4) steps for processing station records, (5) postprocessor programs control files, (6) the standard format for transferring and entering unit and daily values, and (7) relational database (RDB) formats.

Fish elevator and method of elevating fish

DOEpatents

Truebe, Jonathan; Drooker, Michael S.

1984-01-01

A means and method for transporting fish from a lower body of water to a higher body of water. The means comprises a tubular lock with a gated entrance below the level of the lower body of water through which fish may enter the lock and a discharge passage above the level of the upper body of water. The fish raising means in the lock is a crowder pulled upward by a surface float as water from the upper body of water gravitationally flows into the closed lock filling it to the level of the upper body. Water is then pumped into the lock to raise the level to the discharge passage. The crowder is then caused to float upward the remaining distance through the water to the level of the discharge passage by the introduction of air into a pocket on the underside of the crowder. The fish are then automatically discharged from the lock into the discharge passage by the out of water position of the crowder. The movement of the fish into the discharge passage is aided by the continuous overflow of water still being pumped into the lock. A pipe may be connected to the discharge passage to deliver the fish to a selected location in the upper body of water.

FRNA Bacteriophages as Viral Indicators of Faecal Contamination in Mexican Tropical Aquatic Systems

PubMed Central

Diaz-Avalos, Carlos; Lopez-Vidal, Yolanda; Castillo-Rojas, Gonzalo; Mazari-Hiriart, Marisa

2017-01-01

A particular challenge to water safety in populous intertropical regions is the lack of reliable faecal indicators to detect microbiological contamination of water, while the numerical relationships of specific viral indicators remain largely unexplored. The aim of this study was to investigate the numerical relationships of FRNA-bacteriophage genotypes, adenovirus 41, and human adenoviruses (HADV) in Mexican surface water systems to assess sewage contamination. We studied the presence of HADV, HADV41 and FRNA bacteriophage genotypes in water samples and quantified by qPCR and RT-qPCR. Virus and water quality indicator variances, as analyzed by principal component analysis and partial least squared regression, followed along the major percentiles of water faecal enterococci. FRNA bacteriophages adequately deciphered viral and point source water contamination. The strongest correlation for HADV was with FRNA bacteriophage type II, in water samples higher than the 50th percentiles of faecal enterococci, thus indicating urban pollution. FRNA bacteriophage genotypes I and III virus indicator performances were assisted by their associations with electrical conductivity and faecal enterococci. In combination, our methods are useful for inferring water quality degradation caused by sewage contamination. The methods used have potential for determining source contamination in water and, specifically, the presence of enteric viruses where clean and contaminated water have mixed. PMID:28114378

Fecal coliforms on environmental surfaces in two day care centers.

PubMed Central

Weniger, B G; Ruttenber, A J; Goodman, R A; Juranek, D D; Wahlquist, S P; Smith, J D

1983-01-01

A survey of environmental surfaces in two Atlanta area day care centers was conducted to determine the prevalence of fecal coliform bacteria, considered a marker for the presence of fecal contamination which might contain pathogenic parasites, bacteria, or viruses. Fecal coliforms were found in 17 (4.3%) of 398 representative samples of building surfaces, furniture, and other objects. These surfaces may be involved in the chain of transmission of enteric diseases among children. Therefore, disinfection of inanimate objects, in addition to good handwashing, may be important in controlling the spread of enteric diseases in day care centers. PMID:6830225

Geostatistical methods in the assessment of the spatial variability of the quality of river water

NASA Astrophysics Data System (ADS)

Krasowska, Małgorzata; Banaszuk, Piotr

2017-11-01

The research was conducted in the agricultural catchment in north-eastern Poland. The aim of this study was to check how geostatistical analysis can be useful for the detection zones and forms of supply stream by water from different sources. The work was included the implementation of hydrochemical profiles. These profiles were made by measuring the electrical conductivity (EC) values and temperature along the river. On the basis of these results, the authors calculated the coefficient of Moran I and performed semivariogram and found that the EC values are correlated on a stretch of about 140 m. This means that the spatial correlation between samples of water in the stream is readable over a distance of about 140 meters. Therefore it is believed that the degree of water mineralization on this section is shaped by water entering the river channel migration in different ways: through tributaries, leachate drainage and surface runoff. In the case of the analyzed catchment, the potential sources of pollution were drainage systems. Therefore, the spatial analysis allowed the identification pollution sources in a catchment, especially in drained agricultural catchments.

Sources of phosphorus to the Carson River upstream from Lahontan Reservoir, Nevada and California, Water Years 2001-02

USGS Publications Warehouse

Alvarez, Nancy L.; Seiler, Ralph L.

2004-01-01

Discharge of treated municipal-sewage effluent to the Carson River in western Nevada and eastern California ceased by 1987 and resulted in a substantial decrease in phosphorus concentrations in the Carson River. Nonetheless, concentrations of total phosphorus and suspended sediment still commonly exceed beneficial-use criteria established for the Carson River by the Nevada Division of Environmental Protection. Potential sources of phosphorus in the study area include natural inputs from undisturbed soils, erosion of soils and streambanks, construction of low-head dams and their destruction during floods, manure production and grazing by cattle along streambanks, drainage from fields irrigated with streamwater and treated municipal-sewage effluent, ground-water seepage, and urban runoff including inputs from golf courses. In 2000, the U.S. Geological Survey (USGS), in cooperation with Carson Water Subconservancy District, began an investigation with the overall purpose of providing managers and regulators with information necessary to develop and implement total maximum daily loads for the Carson River. Two specific goals of the investigation were (1) to identify those reaches of the Carson River upstream from Lahontan Reservoir where the greatest increases in phosphorus and suspended-sediment concentrations and loading occur, and (2) to identify the most important sources of phosphorus within the reaches of the Carson River where the greatest increases in concentration and loading occur. Total-phosphorus concentrations in surface-water samples collected by USGS in the study area during water years 2001-02 ranged from <0.01 to 1.78 mg/L and dissolved-orthophosphate concentrations ranged from <0.01 to 1.81 mg/L as phosphorus. In streamflow entering Carson Valley from headwater areas in the East Fork Carson River, the majority of samples exceeding the total phosphorus water-quality standard of 0.1 mg/L occur during spring runoff (March, April, and May) when suspended-sediment concentrations are high. Downstream from Carson Valley, almost all samples exceed the water-quality standard, with the greatest concentrations observed during spring and summer months. Estimated annual total-phosphorus loads ranged from 1.33 tons at the West Fork Carson River at Woodfords to 43.41 tons at the Carson River near Carson City during water years 2001-02. Loads are greatest during spring runoff, followed by fall and winter, and least during the summer, which corresponds to the amount of streamflow in the Carson River. The estimated average annual phosphorus load entering Carson Valley was 21.9 tons; whereas, the estimated average annual phosphorus load leaving Carson Valley was 37.8 tons, for an annual gain in load across Carson Valley of 15.9 tons. Thus, about 58 percent of the total-phosphorus load leaving Carson Valley on an annual basis could be attributed to headwater reaches upstream from Carson Valley. During spring and summer (April 1-September 30) an average of 85 percent of the total-phosphorus load leaving Carson Valley could be attributed to headwater reaches. During fall and winter (October 1-March 31) only 17 percent of the phosphorus load leaving Carson Valley could be attributed to headwater reaches. The composition of the phosphorus changes during summer from particulate phosphorus entering Carson Valley to dissolved orthophosphate leaving Carson Valley. Particulate phosphorus entering Carson Valley could be settling out when water is applied to fields and be replaced by dissolved orthophosphate from other sources. Alternatively, the particulate phosphorus could be converted to dissolved orthophosphate as it travels across Carson Valley. Data collected during the study are not sufficient to distinguish between the two possibilities. Eagle Valley and Dayton-Churchill Valleys may act as sinks for phosphorus. On an annual basis, during water years 2001-02, about 90 percent of the phosphorus entering Eagle Valley left the

Using spatial, seasonal, and diel drift patterns of larval Lost River suckers Deltistes luxatus (Cypriniformes: Catostomidae) and shortnose suckers Chasmistes brevirostris (Cypriniformes: Catostomidae) to help identify a site for a water withdrawal structure on the Williamson River, Oregon

USGS Publications Warehouse

Ellsworth, Craig M.; Tyler, Torrey J.; VanderKooi, Scott P.

2010-01-01

A small irrigation diversion dam near Chiloquin, Oregon, was removed and replaced with a pump station to improve fish passage for Lost River suckers (Deltistes luxatus) and shortnose suckers (Chasmistes brevirostris) entering the Sprague River on their spawning migrations. During the developmental phase of the pump station, a need was identified to better understand the larval drift characteristics of these endangered catostomids in order to reduce entrainment into the irrigation system. The spatial, seasonal, and diel distribution of drifting larvae was measured during the 2004 spawning season at two proposed sites on the Williamson River where the pump station could be located. Larval drift for both species coincided with the irrigation season making them subject to entrainment into the irrigation system. Drift occurred almost exclusively at night with larvae entering the drift at sunset and exiting the drift at sunrise. Nighttime larval densities were concentrated near the surface and at midchannel at both sites. Densities were generally greater on the side of mid-channel with greater flow. During early morning sampling we detected a general shift in larval drift from surface to subsurface drift. We also observed an increase in larval densities towards the shore opposite from the proposed pump station at the upper site whereas larval densities remained high at midchannel at the lower site. During daytime sampling, the few larvae that were collected were distributed throughout the water column at both pump sites. This study found that larvae drifting during all time periods were generally distributed further across the cross section, deeper in the water column, and closer to where the proposed water withdrawal structure would be built at the downstream site when compared to the upstream site. Recommendations were provided to locate the withdrawal facility at the upstream site and operate it in a manner such that larval entrainment would likely be minimized.

Simulation of the ground-water-flow system in the Kalamazoo County area, Michigan

USGS Publications Warehouse

Luukkonen, Carol L.; Blumer, Stephen P.; Weaver, T.L.; Jean, Julie

2004-01-01

A ground-water-flow model was developed to investigate the ground-water resources of Kalamazoo County. Ground water is widely used as a source of water for drinking and industry in Kalamazoo County and the surrounding area. Additionally, lakes and streams are valued for their recreational and aesthetic uses. Stresses on the ground-water system, both natural and human-induced, have raised concerns about the long-term availability of ground water for people to use and for replenishment of lakes and streams. Potential changes in these stresses, including withdrawals and recharge, were simulated using a ground-water-flow model. Simulations included steady-state conditions (in which stresses remained constant and changes in storage were not included) and transient conditions (in which stresses changed in seasonal and monthly time scales and storage within the system was included). Steady-state simulations were used to investigate the long-term effects on water levels and streamflow of a reduction in recharge or an increase in pumping to projected 2010 withdrawal rates, withdrawal and application of water for irrigation, and a reduction in recharge in urban areas caused by impervious surfaces. Transient simulations were used to investigate changes in withdrawals to match seasonal and monthly patterns under various recharge conditions, and the potential effects of the use of water for irrigation over the summer months. With a reduction in recharge, simulated water levels declined over most of the model area in Kalamazoo County; with an increase in pumping, water levels declined primarily near pumping centers. Because withdrawals by wells intercept water that would have discharged possibly to a stream or lake, model simulations indicated that streamflow was reduced with increased withdrawals. With withdrawal and consumption of water for irrigation, simulated water levels declined. Assuming a reduction in recharge due to urbanization, water levels declined and flow to streams was reduced based on steady-state simulation results. Transient results indicated a reduction of water levels with the simulated use of water for irrigation over the summer months. Generally the transient simulation with recharge only in the winter provided the best fit to observed water levels collected during synoptic water-level measurements in some wells and to the trends observed in water levels for other wells. Analysis of the regional hydrologic budgets provides an increased understanding of water movement within the ground-water-flow system in Kalamazoo County. Budgets for the steady-state simulations indicated that with reduced recharge, less water was available for streamflow and less water left the model area through the model boundaries. Similarly, with an increase in pumping rates, less water was available to enter streams and become streamflow. When recharge was assumed to remain constant and when it was allowed to vary throughout the year, the amount of water that entered storage was greater than that which left storage. However, when recharge was distributed through October?May only or when recharge rates were reduced from October to May, the amount of water that entered storage was less than that which left storage. Thus, on the basis of model simulations, with reduced recharge or increased withdrawals, water must come from storage, rivers, or from ground-flow-system boundaries to meet withdrawal demands.

1988 Hanford riverbank springs characterization report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dirkes, R.L.

1990-12-01

This reports presents the results of a special study undertaken to characterize the riverbank springs (i.e., ground-water seepage) entering the Columbia River along the Hanford Site. Radiological and nonradiological analyses were performed. River water samples were also analyzed from upstream and downstream of the Site as well as from the immediate vicinity of the springs. In addition, irrigation return water and spring water entering the river along the shoreline opposite Hanford were analyzed. Hanford-origin contaminants were detected in spring water entering the Columbia River along the Hanford Site. The type and concentrations of contaminants in the spring water were similarmore » to those known to exist in the ground water near the river. The location and extent of the contaminated discharges compared favorably with recent ground-water reports and predictions. Spring discharge volumes remain very small relative to the flow of the Columbia. Downstream river sampling demonstrates the impact of ground-water discharges to be minimal, and negligible in most cases. Radionuclide concentrations were below US Department of Energy Derived Concentration Guides (DCGs) with the exception {sup 90}Sr near the 100-N Area. Tritium, while below the DCG, was detected at concentrations above the US Environmental Protection Agency drinking water standards in several springs. All other radionuclide concentrations were below drinking water standards. Nonradiological contaminants were generally undetectable in the spring water. River water contaminant concentrations, outside of the immediate discharge zones, were below drinking water standards in all cases. 19 refs., 5 figs., 12 tabs.« less

Evaluation of an anion exchange resin-based method for concentration of F-RNA coliphages (enteric virus indicators) from water samples.

PubMed

Pérez-Méndez, A; Chandler, J C; Bisha, B; Goodridge, L D

2014-08-01

Enteric viral contaminants in water represent a public health concern, thus methods for detecting these viruses or their indicator microorganisms are needed. Because enteric viruses and their viral indicators are often found at low concentrations in water, their detection requires upfront concentration methods. In this study, a strong basic anion exchange resin was evaluated as an adsorbent material for the concentration of F-RNA coliphages (MS2, Qβ, GA, and HB-P22). These coliphages are recognized as enteric virus surrogates and fecal indicator organisms. Following adsorption of the coliphages from 50ml water samples, direct RNA isolation and real time RT-PCR detection were performed. In water samples containing 10(5)pfu/ml of the F-RNA coliphages, the anion exchange resin (IRA-900) adsorbed over 96.7% of the coliphages present, improving real time RT-PCR detection by 5-7 cycles compared to direct testing. F-RNA coliphage RNA recovery using the integrated method ranged from 12.6% to 77.1%. Resin-based concentration of samples with low levels of the F-RNA coliphages allowed for 10(0)pfu/ml (MS2 and Qβ) and 10(-1)pfu/ml (GA and HB-P22) to be detected. The resin-based method offers considerable advantages in cost, speed, simplicity and field adaptability. Copyright © 2014 Elsevier B.V. All rights reserved.

Accumulation of MS2, GA, and Qβ phages on high density polyethylene (HDPE) and drinking water biofilms under flow/non-flow conditions.

PubMed

Pelleïeux, Sandra; Bertrand, Isabelle; Skali-Lami, Salaheddine; Mathieu, Laurence; Francius, Grégory; Gantzer, Christophe

2012-12-01

Accumulation of enteric viruses on surfaces within a drinking water distribution system was investigated in a reactor using three F-specific RNA bacteriophages (MS2, GA, and Qβ) as models of human pathogenic viruses. The influence of hydrodynamic versus hydrostatic conditions and the effect of the colonization of HDPE surfaces with two-month-old biofilms were assessed for virus accumulation on surfaces. In order to work under controlled laminar conditions and to study various wall shear stresses at the same time, a new rotating disc reactor was designed. Among the wall shear rates applied in the reactor (450 to 1640 s(-1)) no significant differences were observed concerning both the total number of bacteria, which was found to be around 1.7 × 10(7) cells/cm(2) and the virus concentrations on surfaces were about 3 × 10(4), 5 × 10(5) and 3 × 10(5) eq PFU/cm(2) for MS2, GA and Qβ phages, respectively. Comparison between static versus dynamic conditions revealed that both Brownian diffusion and convective diffusion were involved in the transport of these soft colloidal particles and an increase reaching about 1 log in virus concentrations measured on surfaces appeared when hydrodynamic conditions where applied. Our results also showed the influence of the colonization by two-month-old drinking water biofilms which led to a change in the level of virus adhesion. The implication of the physico-chemical properties was also underlined since different adhesion profiles were obtained for the three bacteriophages and MS2 phage was found to be the less adherent one whatever the conditions applied. Copyright © 2012 Elsevier Ltd. All rights reserved.

Morphological and physicochemical characteristics of iron corrosion scales formed under different water source histories in a drinking water distribution system.

PubMed

Yang, Fan; Shi, Baoyou; Gu, Junnong; Wang, Dongsheng; Yang, Min

2012-10-15

The corrosion scales on iron pipes could have great impact on the water quality in drinking water distribution systems (DWDS). Unstable and less protective corrosion scale is one of the main factors causing "discolored water" issues when quality of water entering into distribution system changed significantly. The morphological and physicochemical characteristics of corrosion scales formed under different source water histories in duration of about two decades were systematically investigated in this work. Thick corrosion scales or densely distributed corrosion tubercles were mostly found in pipes transporting surface water, but thin corrosion scales and hollow tubercles were mostly discovered in pipes transporting groundwater. Magnetite and goethite were main constituents of iron corrosion products, but the mass ratio of magnetite/goethite (M/G) was significantly different depending on the corrosion scale structure and water source conditions. Thick corrosion scales and hard shell of tubercles had much higher M/G ratio (>1.0), while the thin corrosion scales had no magnetite detected or with much lower M/G ratio. The M/G ratio could be used to identify the characteristics and evaluate the performances of corrosion scales formed under different water conditions. Compared with the pipes transporting ground water, the pipes transporting surface water were more seriously corroded and could be in a relatively more active corrosion status all the time, which was implicated by relatively higher siderite, green rust and total iron contents in their corrosion scales. Higher content of unstable ferric components such as γ-FeOOH, β-FeOOH and amorphous iron oxide existed in corrosion scales of pipes receiving groundwater which was less corroded. Corrosion scales on groundwater pipes with low magnetite content had higher surface area and thus possibly higher sorption capacity. The primary trace inorganic elements in corrosion products were Br and heavy metals. Corrosion products obtained from pipes transporting groundwater had higher levels of Br, Ti, Ba, Cu, Sr, V, Cr, La, Pb and As. Copyright © 2012 Elsevier Ltd. All rights reserved.

Viruses in the environment - presence and diversity of bacteriophage and enteric virus populations in the Umhlangane River, Durban, South Africa.

PubMed

Marie, Veronna; Lin, Johnson

2017-10-01

Due to the continued persistence of waterborne viral-associated infections, the presence of enteric viruses is a concern. Notwithstanding the health implications, viral diversity and abundance is an indicator of water quality declination in the environment. The aim of this study was to evaluate the presence of viruses (bacteriophage and enteric viruses) in a highly polluted, anthropogenic-influenced river system over a 6-month period at five sampling points. Cytopathic-based tissue culture assays revealed that the isolated viruses were infectious when tested on Hep-G2, HEK293 and Vero cells. While transmission electron microscopy (TEM) revealed that the majority of the viruses were bacteriophages, a number of presumptive enteric virus families were visualized, some of which include Picornaviridae, Adenoviridae, Polyomaviridae and Reoviridae. Finally, primer specific nested polymerase chain reaction (nested-PCR)/reverse transcription-polymerase chain reaction (RT-PCR) coupled with BLAST analysis identified human adenovirus, polyomavirus and hepatitis A and C virus genomes in river water samples. Taken together, the complexity of both bacteriophage and enteric virus populations in the river has potential health implications. Finally, a systematic integrated risk assessment and management plan to identify and minimize sources of faecal contamination is the most effective way of ensuring water safety and should be established in all future guidelines.

Understanding and exploiting the phase behavior of mixtures of oppositely charged polymers and surfactants in water.

PubMed

Piculell, Lennart

2013-08-20

Complexes of oppositely charged polymers and surfactants (OCPS) in water come in many varieties, including liquid-crystalline materials, soluble complexes, structured nanoparticles, and water-insoluble surface layers. The range of available structures and properties increases even further with the addition of other amphiphilic substances that may enter, or even dissolve, the complexes, depending on the nature of the additive. Simple operations may change the properties of OCPS systems dramatically. For instance, dilution with water can induce a phase separation in an initially stable OCPS solution. More complicated processes, involving chemical reactions, can be used to either create or disintegrate OCPS particles or surface layers. The richness of their properties has made OCPS mixtures ubiquitous in everyday household products, such as shampoos and laundry detergents, and also attractive ingredients in the design of new types of responsive particles, surfaces, and delivery agents of potential use in future applications. A challenge for the rational design of an OCPS system is, however, to obtain a good fundamental understanding of how to select molecular shapes and sizes and how to tune the hydrophobic and electrostatic interactions such that the desired properties are obtained. Recent studies of OCPS phase equilibria, using a strategy where the minimum number of components is always used to address a particular question, have brought out general rules and trends that can be used for such a rational design. Those fundamental studies are reviewed here, together with more application-oriented studies where fundamental learning has been put to use.

Large scale reactive transport of nitrate across the surface water divide

NASA Astrophysics Data System (ADS)

Kortunov, E.; Lu, C.; Amos, R.; Grathwohl, P.

2016-12-01

Groundwater pollution caused by agricultural and atmospheric inputs is a pressing issue in environmental management worldwide. Various researchers have studied different aspects of nitrate contamination since the substantial increase of the agriculture pollution in the second half of the 20th century. This study addresses large scale reactive solute transport in a typical Germany hilly landscapes in a transect crossing 2 valleys: River Neckar and Ammer. The numerical model was constructed compromising a 2-D cross-section accounting for typical fractured mudstones and unconsolidated sediments. Flow modelling showed that the groundwater divide significantly deviates from the surface water divide providing conditions for inter-valley flow and transport. Reactive transport modelling of redox-sensitive solutes (e.g. agriculture nitrate and natural sulfate, DOC, ammonium) with MIN3P was used to elucidate source of nitrate in aquifers and rivers. Since both floodplains, in the Ammer and Neckar valley contain Holocene sediments relatively high in organic carbon, agricultural nitrate is reduced therein and does not reach the groundwater. However, nitrate applied in the hillslopes underlain by fractured oxidized mudrock is transported to the high yield sand and gravel aquifer in the Neckar valley. Therefore, the model predicts that nitrate in the Neckar valley comes, to a large extent, from the neighboring Ammer valley. Moreover, nitrate observed in the rivers and drains in the Ammer valley is very likely geogenic since frequent peat layers there release ammonium which is oxidized as it enters the surface water. Such findings are relevant for land and water quality management.

Modeling the fate and transport of 17β-estradiol in the South River watershed in Virginia.

PubMed

Zhao, Xiaomin; Lung, Wu-Seng

2017-11-01

Hormones excreted by livestock metabolisms often enter surface water through feces and urine and can potentially cause adverse impacts to aquatic biota. This study involved a modeling analysis of 17β-estradiol (E2), a prevalent estrogen, in the South River watershed located in Augusta County, Virginia from 2013 to 2015. Cattle manure, poultry litter, biosolids, septic systems, and wastewater treatment plants (WWTPs) were considered as sources of E2 in this study. The EPA's BASINS modeling framework was configured to track the fate and transport of E2. The first-order kinetics and the wash-off model were adopted to characterize the attenuation and the transport of E2. The modeling results indicated that the flow rate was a major input affecting the simulated E2 levels in the water. During storm events, E2 on the land surface was transported into the rivers by the surface runoff and the E2 released into streams was diluted by the high water flow. Variations of the simulated E2 concentrations in the South River depended on the relative magnitudes of the loads from point and nonpoint sources. Modeling results showed that E2 levels in the South River were below the lowest observable effect level (LOEL) for fish. However, the practices of storing manure before land application and fencing off rivers to keep cattle out of the water are encouraged to prevent the potential for high E2 levels in streams receiving feedlot runoff. Copyright © 2017 Elsevier Ltd. All rights reserved.

Atmospheric Inputs of Nitrogen, Carbon, and Phosphorus across an Urban Area: Unaccounted Fluxes and Canopy Influences

NASA Astrophysics Data System (ADS)

Decina, Stephen M.; Templer, Pamela H.; Hutyra, Lucy R.

2018-02-01

Rates of atmospheric deposition are declining across the United States, yet urban areas remain hotspots of atmospheric deposition. While past studies show elevated rates of inorganic nitrogen (N) deposition in cities, less is known about atmospheric inputs of organic N, organic carbon (C), and organic and inorganic phosphorus (P), all of which can affect ecosystem processes, water quality, and air quality. Further, the effect of the tree canopy on amounts and forms of nutrients reaching urban ground surfaces is not well-characterized. We measured growing season rates of total N, organic C, and total P in bulk atmospheric inputs, throughfall, and soil solution around the greater Boston area. We found that organic N constitutes a third of total N inputs, organic C inputs are comparable to rural inputs, and inorganic P inputs are 1.2 times higher than those in sewage effluent. Atmospheric inputs are enhanced two-to-eight times in late spring and are elevated beneath tree canopies, suggesting that trees augment atmospheric inputs to ground surfaces. Additionally, throughfall inputs may directly enter runoff when trees extend above impervious surfaces, as is the case with 26.1% of Boston's tree canopy. Our results indicate that the urban atmosphere is a significant source of elemental inputs that may impact urban ecosystems and efforts to improve water quality, particularly in terms of P. Further, as cities create policies encouraging tree planting to provide ecosystem services, locating trees above permeable surfaces to reduce runoff nutrient loads may be essential to managing urban biogeochemical cycling and water quality.

Physical associations to spring phytoplankton biomass interannual variability in the U.S. Northeast Continental Shelf

NASA Astrophysics Data System (ADS)

Saba, Vincent S.; Hyde, Kimberly J. W.; Rebuck, Nathan D.; Friedland, Kevin D.; Hare, Jonathan A.; Kahru, Mati; Fogarty, Michael J.

2015-02-01

The continental shelf of the Northeast United States and Nova Scotia is a productive marine ecosystem that supports a robust biomass of living marine resources. Understanding marine ecosystem sensitivity to changes in the physical environment can start with the first-order response of phytoplankton (i.e., chlorophyll a), the base of the marine food web. However, the primary physical associations to the interannual variability of chlorophyll a in these waters are unclear. Here we used ocean color satellite measurements and identified the local and remote physical associations to interannual variability of spring surface chlorophyll a from 1998 to 2013. The highest interannual variability of chlorophyll a occurred in March and April on the northern flank of Georges Bank, the western Gulf of Maine, and Nantucket Shoals. Complex interactions between winter wind speed over the Shelf, local winter water levels, and the relative proportions of Atlantic versus Labrador Sea source waters entering the Gulf of Maine from the previous summer/fall were associated with the variability of March/April chlorophyll a in Georges Bank and the Gulf of Maine. Sea surface temperature and sea surface salinity were not robust correlates to spring chlorophyll a. Surface nitrate in the winter was not a robust correlate to chlorophyll a or the physical variables in every case suggesting that nitrate limitation may not be the primary constraint on the interannual variability of the spring bloom throughout all regions. Generalized linear models suggest that we can resolve 88% of March chlorophyll a interannual variability in Georges Bank using lagged physical data.

Presence and fate of coliphages and enteric viruses in three wastewater treatment plants effluents and activated sludge from Tunisia.

PubMed

Jebri, Sihem; Jofre, Juan; Barkallah, Insaf; Saidi, Mouldi; Hmaied, Fatma

2012-07-01

The role of water in the transmission of infectious diseases is well defined; it may act as a reservoir of different types of pathogens. Enteric viruses can survive and persist for a long time in water, maintaining infectivity in many instances. This suggests the need to include virus detection in the evaluation of the microbiological quality of waters. In this study, enteric viruses (enteroviruses and hepatitis A virus (HAV)) were investigated by RT-PCR and coliphages (known as indicators of viral contamination) were enumerated with the double-layer technique agar in effluents and sewage sludge from three Tunisian wastewater treatment plants. The molecular detection of enteric viruses revealed 7.7% of positive activated sludge samples for enteroviruses. None of the samples was positive for HAV. Molecular virus detection threshold was estimated to be 10(3) PFU/100 ml. All samples contained high concentrations of coliphages except those of dry sludge. Reductions in the concentrations of bacteriophages attained by the wastewater treatment plants are of the order of magnitude as reductions described elsewhere. Peak concentrations in raw wastewater were associated with winter rains and suspended materials rate in analysed samples. Our data which is the first in North Africa showed that similar trends of coliphages distribution to other studies in other countries. No clear correlation between studied enteric viruses and coliphages concentration was proved. Coliphages abundance in collected samples should raise concerns about human enteric viruses transmission as these residues are reused in agricultural fields.

Fate of individual sewage disposal system wastewater within regolith in mountainous terrain

NASA Astrophysics Data System (ADS)

Dano, Kathleen; Poeter, Eileen; Thyne, Geoff

2008-06-01

In order to improve understanding of the fate of septic tank or individual sewage disposal system (ISDS) effluent in regolith overlying fractured-rock aquifers, effluent from an ISDS in such a setting was tracked via geophysical, hydrological, and geochemical methods. Under typical precipitation conditions, the effluent entered the fractured bedrock within 5 m of the boundary of the constructed infiltration area. During a period of unusually high spring recharge, the plume migrated between 50 and 100 m within the regolith before infiltrating the fractured bedrock. The chemical signature of the effluent is similar to that required to account for the decline in water quality, suggesting a causative relationship (as estimated from mass-balance models of the surface-water chemistry near the mouth of the basin). The elevated salt content of the effluent during periods of high natural recharge to the infiltration area correlates with elevated salt concentrations in surface and groundwater at the basin scale, suggesting that some of the effluent salt load may be stored in the unsaturated zone during dry periods and flushed during periods of elevated natural recharge.

Spin relaxation measurements of electrostatic bias in intermolecular exploration

NASA Astrophysics Data System (ADS)

Teng, Ching-Ling; Bryant, Robert G.

2006-04-01

We utilize the paramagnetic contribution to proton spin-lattice relaxation rate constants induced by freely diffusing charged paramagnetic centers to investigate the effect of charge on the intermolecular exploration of a protein by the small molecule. The proton NMR spectrum provided 255 resolved resonances that report how the explorer molecule local concentration varies with position on the surface. The measurements integrate over local dielectric constant variations, and, in principle, provide an experimental characterization of the surface free energy sampling biases introduced by the charge distribution on the protein. The experimental results for ribonuclease A obtained using positive, neutral, and negatively charged small nitroxide radicals are qualitatively similar to those expected from electrostatic calculations. However, while systematic electrostatic trends are apparent, the three different combinations of the data sets do not yield internally consistent values for the electrostatic contribution to the intermolecular free energy. We attribute this failure to the weakness of the electrostatic sampling bias for charged nitroxides in water and local variations in effective translational diffusion constant at the water-protein interface, which enters the nuclear spin relaxation equations for the nitroxide-proton dipolar coupling.

Science for the stewardship of the groundwater resources of Cape Cod, Massachusetts

USGS Publications Warehouse

Barbaro, Jeffrey R.; Masterson, John P.; LeBlanc, Denis R.

2014-01-01

Groundwater is the sole source of drinking water and a major source of freshwater for domestic, industrial, and agricultural uses on Cape Cod, Massachusetts. Groundwater discharged from aquifers also supports freshwater pond and stream ecosystems and coastal wetlands. Six hydraulically distinct groundwater-flow systems (lenses) have been delineated on Cape Cod. Of the approximately 450 million gallons per day of water that enters these lenses as recharge from precipitation, about 69 percent discharges directly to the coast, about 24 percent discharges to streams, and almost 7 percent is withdrawn by public-supply wells. In most areas, groundwater in the sand and gravel aquifers is shallow and susceptible to contamination from anthropogenic sources and saltwater intrusion. Continued land development and population growth on Cape Cod have created concerns that potable water will become less available and that the quantity and quality of water flowing to natural discharge areas such as ponds, streams, and coastal waters will continue to decline. The U.S. Geological Survey (USGS) has been investigating groundwater and surface-water resources on Cape Cod for more than 50 years. Recent studies highlighted in this fact sheet have focused on the sources of water to public-supply wells, ponds, streams, and coastal areas; the transport and discharge of nitrogen derived from domestic and municipal disposal of wastewater; and the effects of climate change on groundwater and surface-water resources. Other USGS activities include long-term monitoring of groundwater and pond levels and field research on groundwater contamination at the USGS Cape Cod Toxic Substances Hydrology Research Site (http://ma.water.usgs.gov/MMRCape/) near the Joint Base Cape Cod (JBCC), formerly the Massachusetts Military Reservation.

Analysis of the cylinder’s movement characteristics after entering water based on CFD

NASA Astrophysics Data System (ADS)

Liu, Xianlong

2017-10-01

It’s a variable speed motion after the cylinder vertical entry the water. Using dynamic mesh is mostly unstructured grid, and the calculation results are not ideal and consume huge computing resources. CFD method is used to calculate the resistance of the cylinder at different velocities. Cubic spline interpolation method is used to obtain the resistance at fixed speeds. The finite difference method is used to solve the motion equation, and the acceleration, velocity, displacement and other physical quantities are obtained after the cylinder enters the water.

Source, Transport, and Fate of Groundwater Contamination at Site 45, Marine Corps Recruit Depot, Parris Island, South Carolina

USGS Publications Warehouse

Vroblesky, Don A.; Petkewich, Matthew D.; Landmeyer, James E.; Lowery, Mark A.

2009-01-01

Groundwater contamination by tetrachloroethene and its dechlorination products is present in two partially intermingled plumes in the surficial aquifer near a former dry-cleaning facility at Site 45, Marine Corps Recruit Depot, Parris Island, South Carolina. The northern plume originates from the vicinity of former above-ground storage tanks. Free-phase tetrachloroethene from activities in this area entered the groundwater and the storm sewer. The southern plume originates at a nearby new dry-cleaning facility, but probably was the result of contamination released to the aquifer from a leaking sanitary sewer line from the former dry-cleaning facility. Discharge of dissolved groundwater contamination is primarily to leaking storm sewers below the water table. Extensive biodegradation of the contamination takes place in the surficial aquifer; however, the biodegradation is insufficient to reduce trichloroethene to less than milligram-per-liter concentrations prior to discharging into the storm sewers. The groundwater volatile organic compounds entering the storm sewers are substantially diluted by tidal flushing upon entry and are subject to volatilization as they are transported through the storm sewer to a discharge point in a tributary to Ballast Creek. TCE concentrations of about 2-6 micrograms per liter were present in storm-sewer water near the discharge point (sampled at manhole STS26). On three out of four sampling events at manhole STS14, the storm-sewer water contained no vinyl chloride. During a time of relatively high groundwater levels, however, 20 micrograms per liter of vinyl chloride was present in STS14 storm-sewer water. Because groundwater leaks into that storm sewer and because the storm sewer upgradient from manhole STS14 is adjacent to part of the aquifer where 2,290 micrograms per liter of vinyl chloride have been detected, there is a potential for substantially increased concentrations of vinyl chloride to discharge at the storm-sewer outfall under conditions of high groundwater levels and low tidal flushing. In addition, the observation that free-phase tetrachloroethene may have entered the storm-sewer system during the 1994 discharge means that dense nonaqueous phase liquid tetrachloroethene could have leaked from various parts of the storm sewer or discharged to surface water at the storm-sewer outfall.

A numerical modeling study of the East Australian Current encircling and overwashing a warm-core eddy

NASA Astrophysics Data System (ADS)

MacDonald, H. S.; Roughan, M.; Baird, M. E.; Wilkin, J.

2013-01-01