Pharmaceutical products as emerging contaminant in water: relevance for developing nations and identification of critical compounds for Indian environment.

PubMed

Chinnaiyan, Prakash; Thampi, Santosh G; Kumar, Mathava; Mini, K M

2018-04-17

Pharmaceuticals and personal care products (PPCPs) are contaminants of emerging concern and have been detected worldwide in water bodies in trace concentrations. Most of these emerging contaminants are not regulated in water quality standards except a few in the developed countries. In the case of developing countries, research in this direction is at a nascent stage. For the effective management of Pharmaceutical contaminants (PC) in developing countries, the relevance of PCs as an emerging contaminant has to be analyzed followed by regular monitoring of the environment. Considering the resource constraints, this could be accomplished by identifying the priority compounds which is again region specific and dependent on consumption behavior and pattern. In this work, relevance of pharmaceutical compound as emerging contaminant in water for a developing country like India is examined by considering the data pertaining to pharmaceutical consumption data. To identify the critical Pharmaceutical Contaminants to be monitored in the Indian environment, priority compounds from selected prioritization methods were screened with the compounds listed in National List of Essential Medicine (NLEM), India. Further, information on the number of publications on the compound as an emerging contaminant, data on monitoring studies in India and the number of brands marketing the compound in India were also analyzed. It is found that out of 195 compounds from different prioritization techniques, only 77 compounds were found relevant to India based on NLEM sorting.

Effect-directed analysis supporting monitoring of aquatic environments - An in-depth overview

EPA Science Inventory

Aquatic environments are often contaminated with complex mixtures of chemicals that may pose a risk to ecosystems and human health. This contamination cannot be addressed with target analysis alone but tools are required to reduce this complexity and identify those chemicals that...

Strengthen the collaboration between the River Basin Management Organization of China and International Environmental Specimen Bank Group.

PubMed

Tan, Lingzhi; Liu, Hui; Shu, Jinxiang; Xia, Fan

2015-02-01

Several types of emerging organic contaminants were investigated in many recent researches, such as persistent toxic substance (PTS), persistent organic pollutants (POPs), endocrine disrupters (EDs), and volatile organic compounds (VOCs). But the Chinese country standard detection methods of emerging organic pollutants were not developed with the dramatic increasing of the organic substances production. Hence, it is necessary to obtain the latest informations about the long-term storage of representative environmental specimens, which could provide scientific basis for environmental management and environmental decision-making of the water resources protection and management organization. As the significant water resource conservation organization, the Water Environment Monitoring Center of Yangtze River Basin is experienced in water environmental monitoring and records many useful water resources and environment informations. It is also our responsibility to monitor all the pollutants in water environment of the Yangtze River valley, especially the emerging organic contaminants. Meanwhile, the International Environmental Specimen Bank (IESB) accumulates lots environmental organic pollution specimens and plays a significant role in environmental monitoring. Thus, the collaboration between the two parties will be greatly helpful for each further researches and monitoring work of organic contaminants in Yangtze River Basin.

Fungal contamination in hospital environments.

PubMed

Perdelli, F; Cristina, M L; Sartini, M; Spagnolo, A M; Dallera, M; Ottria, G; Lombardi, R; Grimaldi, M; Orlando, P

2006-01-01

To assess the degree of fungal contamination in hospital environments and to evaluate the ability of air conditioning systems to reduce such contamination. We monitored airborne microbial concentrations in various environments in 10 hospitals equipped with air conditioning. Sampling was performed with a portable Surface Air System impactor with replicate organism detection and counting plates containing a fungus-selective medium. The total fungal concentration was determined 72-120 hours after sampling. The genera most involved in infection were identified by macroscopic and microscopic observation. The mean concentration of airborne fungi in the set of environments examined was 19 +/- 19 colony-forming units (cfu) per cubic meter. Analysis of the fungal concentration in the different types of environments revealed different levels of contamination: the lowest mean values (12 +/- 14 cfu/m(3)) were recorded in operating theaters, and the highest (45 +/- 37 cfu/m(3)) were recorded in kitchens. Analyses revealed statistically significant differences between median values for the various environments. The fungal genus most commonly encountered was Penicillium, which, in kitchens, displayed the highest mean airborne concentration (8 +/- 2.4 cfu/m(3)). The percentage (35%) of Aspergillus documented in the wards was higher than that in any of the other environments monitored. The fungal concentrations recorded in the present study are comparable to those recorded in other studies conducted in hospital environments and are considerably lower than those seen in other indoor environments that are not air conditioned. These findings demonstrate the effectiveness of air-handling systems in reducing fungal contamination.

40 CFR 257.25 - Assessment monitoring program.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 25 2014-07-01 2014-07-01 false Assessment monitoring program. 257.25 Section 257.25 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA... unit caused the contamination, or that the statistically significant increase resulted from error in...

Contamination avoidance devices for poppet type shutoff valves

NASA Technical Reports Server (NTRS)

Endicott, D. L.

1972-01-01

The technology required to provide acceptable contamination damage avoidance characteristics for poppet type shutoff valves is discussed. Evaluation of the contamination avoidance characteristics of the basic 1T32095 propellant shutoff valve, the cycle life performance of these valves in an uncontaminated environment, and the effectiveness of various auxiliary contamination avoidance devices when used in conjunction with these poppet type valves are included. In addition, a secondary objective is to evaluate two methods of monitoring the performance of the test valves during actual operations using acoustical monitoring instrumentation.

An overview of existing raptor contaminant monitoring activities in Europe.

PubMed

Gómez-Ramírez, P; Shore, R F; van den Brink, N W; van Hattum, B; Bustnes, J O; Duke, G; Fritsch, C; García-Fernández, A J; Helander, B O; Jaspers, V; Krone, O; Martínez-López, E; Mateo, R; Movalli, P; Sonne, C

2014-06-01

Biomonitoring using raptors as sentinels can provide early warning of the potential impacts of contaminants on humans and the environment and also a means of tracking the success of associated mitigation measures. Examples include detection of heavy metal-induced immune system impairment, PCB-induced altered reproductive impacts, and toxicity associated with lead in shot game. Authorisation of such releases and implementation of mitigation is now increasingly delivered through EU-wide directives but there is little established pan-European monitoring to quantify outcomes. We investigated the potential for EU-wide coordinated contaminant monitoring using raptors as sentinels. We did this using a questionnaire to ascertain the current scale of national activity across 44 European countries. According to this survey, there have been 52 different contaminant monitoring schemes with raptors over the last 50years. There were active schemes in 15 (predominantly western European) countries and 23 schemes have been running for >20years; most monitoring was conducted for >5years. Legacy persistent organic compounds (specifically organochlorine insecticides and PCBs), and metals/metalloids were monitored in most of the 15 countries. Fungicides, flame retardants and anticoagulant rodenticides were also relatively frequently monitored (each in at least 6 countries). Common buzzard (Buteo buteo), common kestrel (Falco tinnunculus), golden eagle (Aquila chrysaetos), white-tailed sea eagle (Haliaeetus albicilla), peregrine falcon (Falco peregrinus), tawny owl (Strix aluco) and barn owl (Tyto alba) were most commonly monitored (each in 6-10 countries). Feathers and eggs were most widely analysed although many schemes also analysed body tissues. Our study reveals an existing capability across multiple European countries for contaminant monitoring using raptors. However, coordination between existing schemes and expansion of monitoring into Eastern Europe is needed. This would enable assessment of the appropriateness of the EU-regulation of substances that are hazardous to humans and the environment, the effectiveness of EU level mitigation policies, and identify pan-European spatial and temporal trends in current and emerging contaminants of concern. Copyright © 2014. Published by Elsevier Ltd.

A comparison of techniques for assessing central tendency in left-censored data using PCB and p,p'DDE contaminant concentrations from Michigan's bald eagle biosentinel program

Treesearch

Katherine F. Leith; William W. Bowerman; Michael R. Wierda; Dave A. Best; Teryl G. Grubb; James G. Sikarske

2010-01-01

Monitoring of contaminants in the environment is an important part of understanding the fate of ecosystems after a chemical insult. Frequently, such monitoring efforts result in datasets with observations below the detection limit (DL) that are reported as 'non-detect' or '

An Induced Environment Contamination Monitor for the Space Shuttle

NASA Technical Reports Server (NTRS)

Miller, E. R. (Editor); Decher, R. (Editor)

1978-01-01

The Induced Environment Contamination Monitor (IECM), a set of ten instruments integrated into a self-contained unit and scheduled to fly on shuttle Orbital Flight Tests 1 through 6 and on Spacelabs 1 and 2, is described. The IECM is designed to measure the actual environment to determine whether the strict controls placed on the shuttle system have solved the contamination problem. Measurements are taken during prelaunch, ascent, on-orbit, descent, and postlanding. The on-orbit measurements are molecular return flux, background spectral intensity, molecular deposition, and optical surface effects. During the other mission phases dew point, humidity, aerosol content, and trace gas are measured as well as optical surface effects and molecular deposition. The IECM systems and thermal design are discussed. Preflight and ground operations are presented together with associated ground support equipment. Flight operations and data reduction plans are given.

An inexpensive, temporally-integrated system for monitoring occurrence and biological effects of aquatic contaminants in the field

EPA Science Inventory

Assessment of potential ecological risks of complex contaminant mixtures in the environment requires integrated chemical and biological approaches. Instrumental analysis of environmental samples alone can identify contaminants, but provides only limited insights as to possible a...

An inexpensive, temporally-integrated system for monitoring occurrence and biological effects of contaminants in the field

EPA Science Inventory

Assessing potential biological impacts of complex mixtures of contaminants in aquatic environments is an ongoing challenge for ecotoxicologists. Instrumental analysis of site waters alone can identify contaminants but provides only limited insights as to possible adverse effects...

40 CFR 258.55 - Assessment monitoring program.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 25 2014-07-01 2014-07-01 false Assessment monitoring program. 258.55 Section 258.55 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA... days; or (2) May demonstrate that a source other than a MSWLF unit caused the contamination, or that...

Performance of Passive Samplers for Monitoring Estuarine Water Column Concentrations: 1. Contaminants of Concern

EPA Science Inventory

Contaminants enter marine and estuarine environments and can potentially pose risk to human and ecological health. Measuring contaminants of concern (COC) in these aqueous media can be difficult due to their relatively low solubilities and tendency to associate with environmenta...

An inexpensive, temporally-integrated system for monitoring occurrence and biological effects of contaminants in the field (Poster)

EPA Science Inventory

Assessing potential biological impacts of complex mixtures of contaminants in aquatic environments is an ongoing challenge for ecotoxicologists. Instrumental analysis of site waters alone can identify contaminants but provides only limited insights as to possible adverse effects...

Evaluation of radioisotope tracer and activation analysis techniques for contamination monitoring in space environment simulation chambers

NASA Technical Reports Server (NTRS)

Smathers, J. B.; Kuykendall, W. E., Jr.; Wright, R. E., Jr.; Marshall, J. R.

1973-01-01

Radioisotope measurement techniques and neutron activation analysis are evaluated for use in identifying and locating contamination sources in space environment simulation chambers. The alpha range method allows the determination of total contaminant concentration in vapor state and condensate state. A Cf-252 neutron activation analysis system for detecting oils and greases tagged with stable elements is described. While neutron activation analysis of tagged contaminants offers specificity, an on-site system is extremely costly to implement and provides only marginal detection sensitivity under even the most favorable conditions.

Federal Radiological Monitoring and Assessment Center Monitoring Manual Volume 1, Operations

DOE Office of Scientific and Technical Information (OSTI.GOV)

NSTec Aerial Measurement Systems

2012-07-31

The Monitoring division is primarily responsible for the coordination and direction of: Aerial measurements to delineate the footprint of radioactive contaminants that have been released into the environment. Monitoring of radiation levels in the environment; Sampling to determine the extent of contaminant deposition in soil, water, air and on vegetation; Preliminary field analyses to quantify soil concentrations or depositions; and Environmental and personal dosimetry for FRMAC field personnel, during a Consequence Management Response Team (CMRT) and Federal Radiological Monitoring and Assessment Center (FRMAC) response. Monitoring and sampling techniques used during CM/FRMAC operations are specifically selected for use during radiological emergenciesmore » where large numbers of measurements and samples must be acquired, analyzed, and interpreted in the shortest amount of time possible. In addition, techniques and procedures are flexible so that they can be used during a variety of different scenarios; e.g., accidents involving releases from nuclear reactors, contamination by nuclear waste, nuclear weapon accidents, space vehicle reentries, or contamination from a radiological dispersal device. The Monitoring division also provides technicians to support specific Health and Safety Division activities including: The operation of the Hotline; FRMAC facility surveys; Assistance with Health and Safety at Check Points; and Assistance at population assembly areas which require support from the FRMAC. This volume covers deployment activities, initial FRMAC activities, development and implementation of the monitoring and assessment plan, the briefing of field teams, and the transfer of FRMAC to the EPA.« less

Bias in groundwater samples caused by wellbore flow

USGS Publications Warehouse

Reilly, Thomas E.; Franke, O. Lehn; Bennett, Gordon D.

1989-01-01

Proper design of physical installations and sampling procedures for groundwater monitoring networks is critical for the detection and analysis of possible contaminants. Monitoring networks associated with known contaminant sources sometimes include an array of monitoring wells with long well screens. The purpose of this paper is: (a) to report the results of a numerical experiment indicating that significant borehole flow can occur within long well screens installed in homogeneous aquifers with very small head differences in the aquifer (less than 0.01 feet between the top and bottom of the screen); (b) to demonstrate that contaminant monitoring wells with long screens may completely fail to fulfill their purpose in many groundwater environments.

Apparatus for monitoring tritium in tritium contaminating environments using a modified Kanne chamber

DOEpatents

Anderson, David F.

1984-01-01

A conventional Kanne tritium monitor has been redesigned to reduce its sensitivity to such contaminants as tritiated water vapor and tritiated oil. The high voltage electrode has been replaced by a wire cylinder and the collector electrode has been reduced in diameter. The area sensitive to contamination has thereby been reduced by about a factor of forty while the overall apparatus sensitivity and operation has not been affected. The design allows for in situ decontamination of the chambers, if necessary.

Apparatus for monitoring tritium in tritium-contaminating environments using a modified Kanne chamber

DOEpatents

Anderson, D.F.

1981-01-27

A conventional Kanne tritium monitor has been redesigned to reduce its sensitivity to such contaminants as tritiated water vapor and tritiated oil. The high voltage electrode has been replaced by a wire cylinder and the collector electrode has been reduced in diameter. The area sensitive to contamination has thereby been reduced by about a factor of forty while the overall apparatus sensitivity and operation has not been affected. The design allows for in situ decontamination of the chambers, if necessary.

Zebrafish as a model system to study toxicology.

PubMed

Dai, Yu-Jie; Jia, Yong-Fang; Chen, Na; Bian, Wan-Ping; Li, Qin-Kai; Ma, Yan-Bo; Chen, Yan-Ling; Pei, De-Sheng

2014-01-01

Monitoring and assessing the effects of contaminants in the aquatic eco-environment is critical in protecting human health and the environment. The zebrafish has been widely used as a prominent model organism in different fields because of its small size, low cost, diverse adaptability, short breeding cycle, high fecundity, and transparent embryos. Recent studies have demonstrated that zebrafish sensitivity can aid in monitoring environmental contaminants, especially with the application of transgenic technology in this area. The present review provides a brief overview of recent studies on wild-type and transgenic zebrafish as a model system to monitor toxic heavy metals, endocrine disruptors, and organic pollutants for toxicology. The authors address the new direction of developing high-throughput detection of genetically modified transparent zebrafish to open a new window for monitoring environmental pollutants. © 2013 SETAC.

CY2017 Annual Closure Monitoring Report for Corrective Action Unit 98, Frenchman Flat, Underground Test Area, Nevada National Security Site, Nevada: (January 2017–December 2017), Revision 0

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rehfeldt, Ken; Haight, Brian

Corrective Action Unit (CAU) 98: Frenchman Flat on the Nevada National Security Site was the location of 10 underground nuclear tests. CAU 98 underwent a series of investigations and actions in accordance with the Federal Facility Agreement and Consent Order to assess contamination of groundwater by radionuclides from the tests. A Closure Report completed that process in 2016 and called for long-term monitoring, use restrictions (URs), and institutional controls to protect the public and environment from potential exposure to contaminated groundwater. Three types of monitoring are performed for CAU 98: water quality, water level, and institutional control. These are monitoredmore » to determine whether the URs remain protective of human health and the environment, and to ensure that the regulatory boundary objectives are being met. Monitoring data will be used in the future, once multiple years of data are available, to evaluate consistency with the groundwater flow and contaminant transport models because the contaminant boundaries calculated with the models are the primary basis of the UR boundaries. Six wells were sampled for water-quality monitoring in 2017. Contaminants of concern were detected only in the two source/plume wells already known to contain contamination as a result of a radionuclide migration experiment. The 86,000-picocuries-per-liter (pCi/L) tritium concentration in one of the wells is about 12 percent higher than measured in 2016 but is over an order of magnitude less than the peak value measured in the well in 1980. The concentration in the other source/plume well is lower than measured in 2016. The water-level monitoring network includes 16 wells. Depth to water measured in 2017 is generally consistent with recent measurements for most wells. Water-level declines differing from long-term trends were observed in four wells. Three of these (WW-4, WW-4A, and WW-5B) are water-supply wells that experienced increases in pumping during the year. No definitive cause for the sharp decline in the fourth well (ER-5-3-2) in 2016 is known as yet. Institutional control monitoring confirmed the URs are recorded in U.S. Department of Energy and U.S. Air Force land management systems, and that no activities within Frenchman Flat basin are occurring that could potentially affect the contaminant boundaries. Survey of groundwater resources in basins surrounding Frenchman Flat similarly identify no current or pending development that would indicate the need to increase monitoring activities or would otherwise cause concern for the closure decision. The URs continue to prevent exposure of the public, workers, and the environment to contaminants of concern by preventing use of potentially contaminated groundwater.« less

Use of semipermeable membrane devices for in situ monitoring of polycyclic aromatic hydrocarbons in aquatic environments

USGS Publications Warehouse

Lebo, Jon A.; Zajicek, James L.; Huckins, James N.; Petty, Jimmie D.; Peterman, Paul H.

1992-01-01

A method is given for the recovery, cleanup, and analysis of polycyclic aromatic hydrocarbons (PAHs) that have been sequestered in SPMDs (semipermeable membrane devices). SPMDs are polymeric membranes enclosing lipids, and mimic the bioconcentration process of aquatic animals. SPMDs are used as passive, in situ monitors of contamination by organic pollutants of aquatic environments. The method reported here includes dialytic recovery of the PAHs, cleanup of the dialysates using size exclusion, adsorption, and argentation chromatographic modules in tandem, then analysis by gas chromatography with photoionization or mass spectrometric detection. The method is demonstrated to overcome the presence of a variety of environmental co-contaminants and other potential interferents in the dialysates. A field application is also demonstrated in which SPMDs are used to monitor PAH contamination in an urban creek. Approaches to the use of SPMD data to calculate aqueous concentrations of PAHs are discussed. The use of SPMDs in combination with the complementary, PAH-specific cleanup procedure provides a unique approach to the analysis of PAH residues in the aquatic environment.

Legacy of Environmental Research During the Space Shuttle Program

NASA Technical Reports Server (NTRS)

Lane, Helen W.

2011-01-01

The Space Shuttle Program provided many opportunities to study the role of spaceflight on human life for over the last 30 years and represents the longest and largest U.S. human spaceflight program. Risks to crewmembers were included in the research areas of nutrition, microbiology, toxicology, radiation, and sleep quality. To better understand the Shuttle environment, Crew Health Care System was developed. As part of this system, the Environmental Health Subsystem was developed to monitor the atmosphere for gaseous contaminants and microbial contamination levels and to monitor water quality and radiation. This program expended a great deal of effort in studying and mitigating risks related to contaminations due to food, water, air, surfaces, crewmembers, and payloads including those with animals. As the Shuttle had limited stowage space and food selection, the development of nutritional requirements for crewmembers was imperative. As the Shuttle was a reusable vehicle, microbial contamination was of great concern. The development of monitoring instruments that could withstand the space environment took several years and many variations to come up with a suitable instrument. Research with space radiation provided an improved understanding of the various sources of ionizing radiation and the development of monitoring instrumentation for space weather and the human exposure within the orbiter's cabin. Space toxicology matured to include the management of offgassing products that could pollute the crewmembers air quality. The Shuttle Program implemented a 5-level toxicity rating system and developed new monitoring instrumentation to detect toxic compounds. The environment of space caused circadian desynchrony, sleep deficiency, and fatigue leading to much research and major emphasis on countermeasures. Outcomes of the research in these areas were countermeasures, operational protocols, and hardware. Learning Objectives: This symposium will provide an overview of the major environmental lessons learned and the development of countermeasures, monitoring hardware, and procedures.

Shuttle on-orbit contamination and environmental effects

NASA Technical Reports Server (NTRS)

Leger, L. J.; Jacobs, S.; Ehlers, H. K. F.; Miller, E.

1985-01-01

Ensuring the compatibility of the space shuttle system with payloads and payload measurements is discussed. An extensive set of quantitative requirements and goals was developed and implemented by the space shuttle program management. The performance of the Shuttle system as measured by these requirements and goals was assessed partly through the use of the induced environment contamination monitor on Shuttle flights 2, 3, and 4. Contamination levels are low and generally within the requirements and goals established. Additional data from near-term payloads and already planned contamination measurements will complete the environment definition and allow for the development of contamination avoidance procedures as necessary for any payload.

Using blue mussels (Mytilus spp.) as biosentinels of Cryptosporidium spp. and Toxoplasma gondii contamination in marine aquatic environments

USDA-ARS?s Scientific Manuscript database

Methods to monitor microbial contamination typically involve collecting discrete samples at specific time-points and analyzing for a single contaminant. While informative, many of these methods suffer from poor recovery rates and only provide a snapshot of the microbial load at the time of collectio...

Post-Closure Monitoring Report for Corrective Action Unit 98, Frenchman Flat, Underground Test Area, Nevada National Security Site, Nevada for Calendar Year 2016 (January 2016–December 2016), Revision 0

DOE Office of Scientific and Technical Information (OSTI.GOV)

Farnham, Irene

Corrective Action Unit (CAU) 98: Frenchman Flat on the Nevada National Security Site was the location of 10 underground nuclear tests. CAU 98 underwent a series of investigations and actions in accordance with the Federal Facility Agreement and Consent Order to assess contamination of groundwater by radionuclides from the tests. A Closure Report completed that process in 2016 and called for long-term monitoring, use restrictions (URs), and institutional controls to protect the public and environment from potential exposure to contaminated groundwater. Three types of monitoring are performed for CAU 98: water quality, water level, and institutional control. These are evaluatedmore » to determine whether the UR boundaries remain protective of human health and the environment, and to ensure that the regulatory boundary objectives are being met. Additionally, monitoring data are used to evaluate consistency with the groundwater flow and contaminant transport models because the contaminant boundaries (CBs) calculated with the models are the primary basis of the UR boundaries. In summary, the monitoring results from 2016 indicate the regulatory controls on the closure of CAU 98 remain effective in protection of human health and the environment. Recommendations resulting from this first year of monitoring activities include formally incorporating wells UE-5 PW-1, UE-5 PW-2, and UE-5 PW-3 into the groundwater-level monitoring network given their strategic location in the basin; and early development of a basis for trigger levels for the groundwater-level monitoring given the observed trends. Additionally, it is recommended to improve the Real Estate/Operations Permit process for capturing information important for evaluating the impact of activities on groundwater resources, and to shift the reporting requirement for this annual report from the second quarter of the federal fiscal year (end of March) to the second quarter of the calendar year (end of June).« less

USING SPMDS TO ACCESS MANAGEMENT STRATEGIES FOR PCB CONTAMINATED SEDIMENTS

EPA Science Inventory

Dredging, in-place treatment, capping and monitored natural recovery, used together or separately are the primary approaches for managing contaminated sediment risks. Understanding how well different approaches work in different environments is critical for choosing an appropria...

USING SPMDS TO ACCESS MANAGMENT STRATEGIES FOR PCB CONTAMINATED SEDIMENTS

EPA Science Inventory

Dredging, in-place treatment, capping and monitored natural recovery, used together or separately are the primary approaches for managing contaminated sediment risks. Understanding how well different approaches work in different environments is critical for choosing an appropria...

USING SPMDS TO ASSESS MANAGEMENT STRATEGIES FOR PCB CONTAMINATED SEDIMENTS.

EPA Science Inventory

Abstract: Dredging in-place treatment, capping and monitored natural recovery, used together or separately are the primary approaches for managing contaminated sediment risks. Understanding how well different approaches work in different environments is critical for choosing an...

Tracking contaminants in seabirds of Arctic Canada: temporal and spatial insights.

PubMed

Mallory, Mark L; Braune, Birgit M

2012-07-01

Levels and trends of persistent organic pollutants and trace elements in seabirds breeding in the vast Canadian Arctic have been monitored since 1975. Data from this monitoring have indicated both spatial and temporal variation across the region, attributable in part to differences in species' diets, differences in regional deposition patterns, and unidirectional trends in contaminants reaching this area from emissions in temperate and tropical areas to the south. Seabird tissues have served as effective biomonitors to examine this variation, and national and international collaboration in this monitoring effort has promoted valuable synthetic assessments of spatial and temporal patterns in Arctic contaminants. Here we review the history of the monitoring program, the critical role played by Environment Canada's National Wildlife Specimen Bank, and we summarize important spatial and temporal trends in various contaminants in Canadian Arctic seabirds. Copyright © 2012 Elsevier Ltd. All rights reserved.

Effective radiological contamination control and monitoring techniques in high alpha environments.

PubMed

Funke, Kevin C

2003-02-01

In the decommissioning of a highly contaminated alpha environment, such as the one at Hanford's 233-S Plutonium Concentration Facility, one of the key elements of a successful radiological control program is an integrated safety approach. This approach begins with the job-planning phase where the scope of the work is described. This is followed by a brainstorming session involving engineering and craft to identify how to perform the work in a logical sequence of events. Once the brainstorming session is over, a Job Hazard Analysis is performed to identify any potential problems. Mockups are utilized to enable the craft to get hands on experience and provide feedback and ideas to make the job run smoother. Ideas and experience gained during mockups are incorporated into the task instruction. To assure appropriate data are used in planning and executing the job, our principal evaluation tools included lapel and workplace air sampling, plus continuous air monitors and frequent surveys to effectively monitor job progress. In this highly contaminated alpha environment, with contamination levels ranging from 0.3 Bq cm-2 to approximately 100,000 Bq cm-2 (2,000 dpm per 100 cm2 to approximately 600 million dpm per 100 cm2), with average working levels of 1,600-3,200 Bq cm-2 (10-20 million dpm per 100 cm2) without concomitant ambient radiation levels, control of the spread of contamination is key to keeping airborne levels As Low As Reasonably Achievable.

Effective Radiological Contamination Control and Monitoring Techniques In High Alpha Environments.

PubMed

Funke, Kevin C.

2003-02-01

In the decommissioning of a highly contaminated alpha environment, such as the one at Hanford's 233-S Plutonium Concentration Facility, one of the key elements of a successful radiological control program is an integrated safety approach. This approach begins with the job-planning phase where the scope of the work is described. This is followed by a brainstorming session involving engineering and craft to identify how to perform the work in a logical sequence of events. Once the brainstorming session is over, a Job Hazard Analysis is performed to identify any potential problems. Mockups are utilized to enable the craft to get hands on experience and provide feedback and ideas to make the job run smoother. Ideas and experience gained during mockups are incorporated into the task instruction. To assure appropriate data are used in planning and executing the job, our principal evaluation tools included lapel and workplace air sampling, plus continuous air monitors and frequent surveys to effectively monitor job progress. In this highly contaminated alpha environment, with contamination levels ranging from 0.3 Bq cm to approximately 100,000 Bq cm (2,000 dpm per 100 cm to approximately 600 million dpm per 100 cm ), with average working levels of 1,600-3,200 Bq cm (10-20 million dpm per 100 cm ) without concomitant ambient radiation levels, control of the spread of contamination is key to keeping airborne levels As Low As Reasonably Achievable.

Determination of water saturation using gas phase partitioning tracers and time-lapse electrical conductivity measurements

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, Timothy C.; Oostrom, Martinus; Truex, Michael J.

2013-05-21

Water saturation is an important indicator of contaminant distribution and plays a governing role in contaminant transport within the vadose zone. Understanding the water saturation distribution is critical for both remediation and contaminant flux monitoring in unsaturated environments. In this work we propose and demonstrate a method of remotely determining water saturation levels using gas phase partitioning tracers and time-lapse bulk electrical conductivity measurements. The theoretical development includes the partitioning chemistry for the tracers we demonstrate (ammonia and carbon dioxide), as well as a review of the petrophysical relationship governing how these tracers influence bulk conductivity. We also investigate methodsmore » of utilizing secondary information provided by electrical conductivity breakthrough magnitudes induced by the tracers. We test the method on clean, well characterized, intermediate-scale sand columns under controlled conditions. Results demonstrate the capability to predict partitioning coefficients and accurately monitor gas breakthrough curves along the length of the column according to the corresponding electrical conductivity response, leading to accurate water saturation estimates. This work is motivated by the need to develop effective characterization and monitoring techniques for contaminated deep vadose zone environments, and provides a proof-of-concept toward uniquely characterizing and monitoring water saturation levels at the field scale and in three-dimensions using electrical resistivity tomography.« less

Evaluation of Using Caged Clams to Monitor Contaminated Groundwater Exposure in the Near-Shore Environment of the Hanford Site 300 Area

DOE Office of Scientific and Technical Information (OSTI.GOV)

Larson, Kyle B.; Poston, Ted M.; Tiller, Brett L.

2008-01-31

The Asiatic clam (Corbicula fluminea) has been identified as an indicator species for locating and monitoring contaminated groundwater in the Columbia River. Pacific Northwest National Laboratory conducted a field study to explore the use of caged Asiatic clams to monitor contaminated groundwater upwelling in the 300 Area near-shore environment and assess seasonal differences in uranium uptake in relation to seasonal flow regimes of the Columbia River. Additional objectives included examining the potential effects of uranium accumulation on growth, survival, and tissue condition of the clams. This report documents the field conditions and procedures, laboratory procedures, and statistical analyses used inmore » collecting samples and processing the data. Detailed results are presented and illustrated, followed by a discussion comparing uranium concentrations in Asiatic clams collected at the 300 Area and describing the relationship between river discharge, groundwater indicators, and uranium in clams. Growth and survival, histology, and other sources of environmental variation also are discussed.« less

Space Environment Effects on Materials at Different Positions and Operational Periods of ISS

NASA Astrophysics Data System (ADS)

Kimoto, Yugo; Ichikawa, Shoichi; Miyazaki, Eiji; Matsumoto, Koji; Ishizawa, Junichiro; Shimamura, Hiroyuki; Yamanaka, Riyo; Suzuki, Mineo

2009-01-01

A space materials exposure experiment was condcuted on the exterior of the Russian Service Module (SM) of the International Space Station (ISS) using the Micro-Particles Capturer and Space Environment Exposure Device (MPAC&SEED) of the Japan Aerospace Exploration Agency (JAXA). Results reveal artificial environment effects such as sample contamination, attitude change effects on AO fluence, and shading effects of UV on ISS. The sample contamination was coming from ISS components. The particles attributed to micrometeoroids and/or debris captured by MPAC might originate from the ISS solar array. Another MPAC&SEED will be aboard the Exposure Facility of the Japanese Experiment Module, KIBO Exposure Facility (EF) on ISS. The JEM/MPAC&SEED is attached to the Space Environment Data Acquisition Equipment-Attached Payload (SEDA-AP) and is exposed to space. Actually, SEDA-AP is a payload on EF to be launched by Space Shuttle flight 2J/A. In fact, SEDA-AP has space environment monitors such as a high-energy particle monitor, atomic oxygen monitor, and plasma monitor to measure in-situ natural space environment data during JEM/MPAC&SEED exposure. Some exposure samples for JEM/MPAC&SEED are identical to SM/MPAC&SEED samples. Consequently, effects on identical materials at different positions and operation periods of ISS will be evaluated. This report summarizes results from space environment monitoring samples for atomic oxygen analysis on SM/MPAC&SEED, along with experimental plans for JEM/MPAC&SEED.

Wireless remote monitoring of critical facilities

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tsai, Hanchung; Anderson, John T.; Liu, Yung Y.

A method, apparatus, and system are provided for monitoring environment parameters of critical facilities. A Remote Area Modular Monitoring (RAMM) apparatus is provided for monitoring environment parameters of critical facilities. The RAMM apparatus includes a battery power supply and a central processor. The RAMM apparatus includes a plurality of sensors monitoring the associated environment parameters and at least one communication module for transmitting one or more monitored environment parameters. The RAMM apparatus is powered by the battery power supply, controlled by the central processor operating a wireless sensor network (WSN) platform when the facility condition is disrupted. The RAMM apparatusmore » includes a housing prepositioned at a strategic location, for example, where a dangerous build-up of contamination and radiation may preclude subsequent manned entrance and surveillance.« less

STS-2, -3, -4 Induced Environment Contamination Monitor (ICEM)

NASA Technical Reports Server (NTRS)

Miller, E. R. (Editor)

1983-01-01

The second, third, and fourth space transportation system missions are described including the location of the IECM in the payload bay and the shuttle coordinate systems used. Measurement results from the three flights are given for each instrument with comparisons to original goals for preflight environment and induced environment contamination. These results include very low levels of molecular mass accumulation rates, absence of molecular films on optical samples, outgassing species above 50 amu undetectable generally low levels of on-orbit particulates, and decay rates for early mission water dump particulates. Results of exposure of several optical materials and coatings to atomic oxygen are also presented. From these results, it is concluded that the space shuttle met the established induced environment contamination goals.

Application of pulsed-field gel electrophoresis to characterise and trace the prevalence of Enterobacter sakazakii in an infant formula processing facility.

PubMed

Mullane, N R; Whyte, P; Wall, P G; Quinn, T; Fanning, S

2007-05-01

Enterobacter sakazakii (E. sakazakii) contamination of powdered infant formula (PIF) and its processing environment was monitored between April 2005 and March 2006. The purpose of the monitoring programme was to locate points of contamination, investigate clonal persistence, and identify possible dissemination routes along the processing chain. A total of 80 E. sakazakii isolates were recovered from the manufacturing facility. The overall frequency of isolation of E. sakazakii in intermediate and final product was 2.5%, while specific locations in the processing environment were contaminated at frequencies up to 31%. All E. sakazakii isolates were characterised by pulsed-field gel electrophoresis (PFGE). XbaI macrorestriction digests yielded 19 unique pulse-types that could be grouped into 6 clusters of between 5 and 32 isolates. The formation of large clusters was consistent with the presence of a number of clones in the manufacturing environment. While the majority of isolates were of environmental origin (72.5%), no cluster was confined to one specific location and indistinguishable PFGE profiles were generated from isolates cultured from the manufacturing environment, sampling points along the processing chain and from intermediate and final product. These findings suggest that the manufacturing environment serves as a key route for sporadic contamination of PIF. These data will support the development of efficient intervention measures contributing to the reduction of E. sakazakii in the PIF processing chain.

Field-lysimeter and Column Studies As Complementary Survey Tools For Monitored Natural Attenuation (mna)

NASA Astrophysics Data System (ADS)

Totsche, K. U.; Hensel, D.; Jann, S.; Jaesche, P.; Kögel-Knabner, I.; Scheibke, R.

The contamination of the unsaturated soil zone with organic pollutants (PAH, BTEX, PCB, Phenols, etc.) and pollutant mixtures, e.g. light/dense non-aqueous phase liq- uids (L/D-NAPLs), represents a specific challenge for sanitation and remediation of contaminated sites. Monitored natural attenuation as an alternative option for remedi- ation of such sites requires (1) the proof of an effective pollutant reduction potential and (2) the proof that a further spreading of the contaminants and their potentially toxic metabolites is minimized to an acceptable minimum concentration level. These demands apply equally likely to contaminated soil and groundwater environments. However, a major problem arises when the task is to monitor the release and transport of contaminants within the unsaturated soil zone over a longer period (> 10 years) of time at an expenditure as small as possible. The aim of our presentation is to employ and test a survey technique to monitor pollutant release and redistribution within the unsaturated soil zone in the context of MNA. The proposed technique is based on the combination of laboratory-column and field-lysimeter studies. The first is used to ac- quire knowledge on the governing processes, the latter is used to monitor release and transport of the contaminants.

Towards a better control of optics cleanliness

NASA Astrophysics Data System (ADS)

Berlioz, P.

2017-11-01

The contamination of optics can considerably degrade the transmission and scattering of spacecraft optics. To prevent efficiently optics from contamination involves introducing since design phase requirements on materials and protections (covers…). Then, integration and test phase demands to implement heavy and stringent means (clean room, specific garment, covers…) and a permanent monitoring by fine contamination measurement of instrument environment and surfaces. Contamination budgets are drawn the project along, first prediction budgets based on analysis and potentially modeling, during design phase, then actual budgets based on contamination measurement during integration and test phase. Finally, the risk still exists to have to clean optics because of hazardous contamination, furthermore to dismount them. The cleanliness engineering set at ASTRIUM Toulouse is presented here, including the contamination monitoring via witness samples measured by IR spectrometry and via counters. ASTRIUM is presently focusing attention on no contact cleaning like the promising UV-ozone process.

Monitoring spacecraft atmosphere contaminants by laser absorption spectroscopy

NASA Technical Reports Server (NTRS)

Steinfeld, J. I.

1976-01-01

Laser-based spectrophotometric methods which have been proposed for the detection of trace concentrations of gaseous contaminants include Raman backscattering (LIDAR) and passive radiometry (LOPAIR). Remote sensing techniques using laser spectrometry are presented and in particular a simple long-path laser absorption method (LOLA), which is capable of resolving complex mixtures of closely related trace contaminants at ppm levels is discussed. A number of species were selected for study which are representative of those most likely to accumulate in closed environments, such as submarines or long-duration manned space flights. Computer programs were developed which will permit a real-time analysis of the monitored atmosphere. Estimates of the dynamic range of this monitoring technique for various system configurations, and comparison with other methods of analysis, are given.

COMPARISON OF IMMUNOASSAY AND GAS CHROMATOGRAPHY/MASS SPECTROMETRY FOR MEASUREMENT OF POLYCYCLIC AROMATIC HYDROCARBONS IN CONTAMINATED SOIL

EPA Science Inventory

Polycyclic aromatic hydrocarbons (PAHs) are frequently encountered in the environment and may pose health concerns due to their carcinogenicity. A commercial enzyme-linked immunosorbent assay (ELISA), was evaluated as a screening method for monitoring PAHs at contaminated site...

Current perspectives in contaminant hydrology and water resources sustainability

USGS Publications Warehouse

Bradley, Paul M.

2013-01-01

Human society depends on liquid freshwater resources to meet drinking, sanitation and hygiene, agriculture, and industry needs. Improved resource monitoring and better understanding of the anthropogenic threats to freshwater environments are critical to efficient management of freshwater resources and ultimately to the survival and quality of life of the global human population. This book helps address the need for improved freshwater resource monitoring and threat assessment by presenting current reviews and case studies focused on the fate and transport of contaminants in the environment and on the sustainability of groundwater and surface-water resources around the world. It is intended for students and professionals working in hydrology and water resources management.

BIOSENSORS RESEARCH FOR DEVELOPMENT OF INNOVATIVE MONITORING TECHNIQUES THAT SUPPORT EXPOSURE ASSESSMENT RELATED TO THE SUPERFUND PROGRAM

EPA Science Inventory

One of the approaches for reducing uncertainties in the assessment of human exposure is to better characterize the hazardous wastes that contaminate our environment. A significant limitation to this approach, however, is that sampling and laboratory analysis of contaminated envi...

Associating Changes in Endogenous Metabolite Profiles of Field-Deployed Fish with Chemical Contaminants and Other Stressors

EPA Science Inventory

Assessing risk from contaminant exposure in the aquatic environment typically begins (and often ends) with identification of “listed” chemicals in water samples. While providing useful information about potential exposures, this approach to monitoring – in the absence of site-spe...

Biochemical markers for the assessment of aquatic environment contamination

PubMed Central

Havelková, Marcela; Randák, Tomáš; Blahová, Jana; Slatinská, Iveta; Svobodová, Zdeňka

2008-01-01

The need for assessment of aquatic ecosystem contamination and of its impact on water dwelling organisms was developed in response to rising aquatic environmental pollution. In this field study, liver enzymes of phase I and phase II of xenobiotic transformation, namely cytochrome P450, ethoxyresorufin-O-deethylase, glutathione-S-transferase and tripeptide glutathione were used to assess the contamination of the aquatic environment at different rivers in the Czech Republic. The indicator species selected was the male chub (Leuciscus cephalus L.) and male brown trout (Salmo trutta fario). Chemical analyses included also the assessment of the most important inductors of previously mentioned biochemical markers. The major inductors of monitored biomarkers are industrial contaminants which belong to a large group of organic pollutants (PCB, PAH, PCDD/F, DDT, HCH, HCB and OCS), persistent in the environment. Four different groups of river basins were assessed: the River Tichá Orlice and its tributary the Kralický brook; important tributaries of the River Elbe (the rivers Orlice, Chrudimka, Cidlina, Jizera, Vltava, Ohře and Bílina); major rivers in the Czech Republic (the rivers Lužnice, Otava, Sázava, Berounka, Vltava, Labe, Ohře, Svratka, Dyje, Morava and Odra) and the River Vltava. The use of the biochemical markers together with chemical analyses seems to be an effective way to monitor the quality of aquatic environment. PMID:21218108

Monitoring minimization of grade B environments based on risk assessment using three-dimensional airflow measurements and computer simulation.

PubMed

Katayama, Hirohito; Higo, Takashi; Tokunaga, Yuji; Katoh, Shigeo; Hiyama, Yukio; Morikawa, Kaoru

2008-01-01

A practical, risk-based monitoring approach using the combined data collected from actual experiments and computer simulations was developed for the qualification of an EU GMP Annex 1 Grade B, ISO Class 7 area. This approach can locate and minimize the representative number of sampling points used for microbial contamination risk assessment. We conducted a case study on an aseptic clean room, newly constructed and specifically designed for the use of a restricted access barrier system (RABS). Hotspots were located using three-dimensional airflow analysis based on a previously published empirical measurement method, the three-dimensional airflow analysis. Local mean age of air (LMAA) values were calculated based on computer simulations. Comparable results were found using actual measurements and simulations, demonstrating the potential usefulness of such tools in estimating contamination risks based on the airflow characteristics of a clean room. Intensive microbial monitoring and particle monitoring at the Grade B environmental qualification stage, as well as three-dimensional airflow analysis, were also conducted to reveal contamination hotspots. We found representative hotspots were located at perforated panels covering the air exhausts where the major piston airflows collect in the Grade B room, as well as at any locations within the room that were identified as having stagnant air. However, we also found that the floor surface air around the exit airway of the RABS EU GMP Annex 1 Grade A, ISO Class 5 area was always remarkably clean, possibly due to the immediate sweep of the piston airflow, which prevents dispersed human microbes from falling in a Stokes-type manner on settling plates placed on the floor around the Grade A exit airway. In addition, this airflow is expected to be clean with a significantly low LMAA. Based on these observed results, we propose a simplified daily monitoring program to monitor microbial contamination in Grade B environments. To locate hotspots we propose using a combination of computer simulation, actual airflow measurements, and intensive environmental monitoring at the qualification stage. Thereafter, instead of particle or microbial air monitoring, we recommend the use of microbial surface monitoring at the main air exhaust. These measures would be sufficient to assure the efficiency of the monitoring program, as well as to minimize the number of surface sampling points used in environments surrounding a RABS.

Microbial Source Tracking in Adjacent Karst Springs.

PubMed

Ohad, Shoshanit; Vaizel-Ohayon, Dalit; Rom, Meir; Guttman, Joseph; Berger, Diego; Kravitz, Valeria; Pilo, Shlomo; Huberman, Zohar; Kashi, Yechezkel; Rorman, Efrat

2015-08-01

Modern man-made environments, including urban, agricultural, and industrial environments, have complex ecological interactions among themselves and with the natural surroundings. Microbial source tracking (MST) offers advanced tools to resolve the host source of fecal contamination beyond indicator monitoring. This study was intended to assess karst spring susceptibilities to different fecal sources using MST quantitative PCR (qPCR) assays targeting human, bovine, and swine markers. It involved a dual-time monitoring frame: (i) monthly throughout the calendar year and (ii) daily during a rainfall event. Data integration was taken from both monthly and daily MST profile monitoring and improved identification of spring susceptibility to host fecal contamination; three springs located in close geographic proximity revealed different MST profiles. The Giach spring showed moderate fluctuations of MST marker quantities amid wet and dry samplings, while the Zuf spring had the highest rise of the GenBac3 marker during the wet event, which was mirrored in other markers as well. The revelation of human fecal contamination during the dry season not connected to incidents of raining leachates suggests a continuous and direct exposure to septic systems. Pigpens were identified in the watersheds of Zuf, Shefa, and Giach springs and on the border of the Gaaton spring watershed. Their impact was correlated with partial detection of the Pig-2-Bac marker in Gaaton spring, which was lower than detection levels in all three of the other springs. Ruminant and swine markers were detected intermittently, and their contamination potential during the wet samplings was exposed. These results emphasized the importance of sampling design to utilize the MST approach to delineate subtleties of fecal contamination in the environment. Copyright © 2015, American Society for Microbiology. All Rights Reserved.

Bringing together raptor collections in Europe for contaminant research and monitoring in relation to chemicals regulations.

PubMed

Movalli, Paola; Dekker, René; Koschorreck, Jan; Treu, Gabriele

2017-11-01

Raptors are good sentinels of environmental contamination and there is good capability for raptor biomonitoring in Europe. Raptor biomonitoring can benefit from natural history museums (NHMs), environmental specimen banks (ESBs) and other collections (e.g. specialist raptor specimen collections). Europe's NHMs, ESBs and other collections hold large numbers of raptor specimens and samples, covering long periods of time. These collections are potentially a valuable resource for contaminant studies over time and space. There are strong needs to monitor contaminants in the environment to support EU and national chemical management. However, data on raptor specimens in NHMs, ESBs and other collections are dispersed, few are digitised, and they are thus not easy to access. Specimen coverage is patchy in terms of species, space and time. Contaminant research with raptors would be facilitated by creating a framework to link relevant collections, digitising all collections, developing a searchable meta-database covering all existing collections, making them more visible and accessible for contaminant research. This would also help identify gaps in coverage and stimulate specimen collection to fill gaps in support of prioritised contaminant monitoring. Collections can further support raptor biomonitoring by making samples available for analysis on request.

Medical Significance of Microorganisms in Spacecraft Environment

NASA Technical Reports Server (NTRS)

Pierson, Duane L.; Ott, C. Mark

2007-01-01

Microorganisms can spoil food supplies, contaminate drinking water, release noxious volatile compounds, initiate allergic responses, contaminate the environment, and cause infectious diseases. International acceptability limits have been established for bacterial and fungal contaminants in air and on surfaces, and environmental monitoring is conducted to ensure compliance. Allowable levels of microorganism in water and food have also been established. Environmental monitoring of the space shuttle, the Mir, and the ISS have allowed for some general conclusions. Generally, the bacteria found in air and on interior surfaces are largely of human origin such as Staphylococcus spp., Micrococcus spp. Common environmental genera such as Bacillus spp. are the most commonly isolated bacteria from all spacecraft. Yeast species associated with humans such as Candida spp. are commonly found. Aspergillus spp., Penicillium spp., and Cladosporium spp. are the most commonly isolated filamentous fungi. Microbial levels in the environment differ significantly depending upon humidity levels, condensate accumulation, and availability of carbon sources. However, human "normal flora" of bacteria and fungi can result in serious, life-threatening diseases if human immunity is compromised. Disease incidence is expected to increase as mission duration increases.

Calibration and controlled flume evaluation of polar organic chemical integrative samplers (POCIS) for tylosin

USDA-ARS?s Scientific Manuscript database

In recent years, the occurrence and fate of emerging contaminants such as antibiotics in the environment have become a concern. One of these is tylosin, a macrolide antibiotic that is used extensively in the swine industry as a growth promoter. The monitoring of these emerging contaminants for asses...

Innovative biological approaches for monitoring and improving water quality

PubMed Central

Aracic, Sanja; Manna, Sam; Petrovski, Steve; Wiltshire, Jennifer L.; Mann, Gülay; Franks, Ashley E.

2015-01-01

Water quality is largely influenced by the abundance and diversity of indigenous microbes present within an aquatic environment. Physical, chemical and biological contaminants from anthropogenic activities can accumulate in aquatic systems causing detrimental ecological consequences. Approaches exploiting microbial processes are now being utilized for the detection, and removal or reduction of contaminants. Contaminants can be identified and quantified in situ using microbial whole-cell biosensors, negating the need for water samples to be tested off-site. Similarly, the innate biodegradative processes can be enhanced through manipulation of the composition and/or function of the indigenous microbial communities present within the contaminated environments. Biological contaminants, such as detrimental/pathogenic bacteria, can be specifically targeted and reduced in number using bacteriophages. This mini-review discusses the potential application of whole-cell microbial biosensors for the detection of contaminants, the exploitation of microbial biodegradative processes for environmental restoration and the manipulation of microbial communities using phages. PMID:26322034

From municipal sewage to drinking water: fate and removal of pharmaceutical residues in the aquatic environment in urban areas.

PubMed

Heberer, Th; Reddersen, K; Mechlinski, A

2002-01-01

Recently, the occurrence and fate of pharmaceutically active compounds (PhACs) in the aquatic environment was recognized as one of the emerging issues in environmental chemistry and as a matter of public concern. Residues of PhACs have been found as contaminants in sewage, surface, and ground- and drinking water samples. Since June 2000, a new long-term monitoring program of sewage, surface, ground- and drinking water has been carried out in Berlin, Germany. Samples, collected periodically from selected sites in the Berlin area, are investigated for residues of PhACs and related contaminants. The purpose of this monitoring is to investigate these compounds over a long time period to get more reliable data on their occurrence and fate in the different aquatic compartments. Moreover, the surface water investigations allow the calculation of season-dependent contaminant loads in the Berlin waters. In the course of the monitoring program, PhACs and some other polar compounds were detected at concentrations up to the microg/L-level in all compartments of the Berlin water cycle. The monitoring is accompanied and supported by several other investigations such as laboratory column experiments and studies on bank filtration and drinking water treatment using conventional or membrane filtration techniques.

Residual indicator bacteria in autosampler tubing: a field and laboratory assessment.

PubMed

Hathaway, J M; Hunt, W F; Guest, R M; McCarthy, D T

2014-01-01

Microbial contamination in surface waters has become a worldwide cause for concern. As efforts are made to reduce this contamination, monitoring is integral to documenting and evaluating water quality improvements. Autosamplers are beneficial in such monitoring efforts, as large data sets can be generated with minimized effort. The extent to which autosamplers can be utilized for microbial monitoring is largely unknown due to concerns over contamination. Strict sterilization regimes for components contacting the water being sampled are difficult, and sometimes logistically implausible, when utilizing autosamplers. Field experimentation showed contamination of fecal coliform in autosamplers to be more of a concern than that of Escherichia coli. Further study in a controlled laboratory environment suggested that tubing configuration has a significant effect on residual E. coli concentrations in sampler tubing. The amount of time that passed since the last sample was collected from a given sampler (antecedent dry weather period - DWP) tubing was also a significant factor. At a DWP of 7 days, little to no contamination was found. Thus, simple protocols such as providing positive drainage of tubing between sample events and programming samplers to include rinses will reduce concerns of contamination in autosamplers.

EPA/ORD WORKSHOP ON SOURCE EMISSION AND AMBIENT AIR MONITORING OF MERCURY. OPENING & CLOSING REMARKS AND OVERVIEW

EPA Science Inventory

The Mercury Monitoring Workshop was developed because mercury contamination, both nationally and internationally, has long been recognized as a growing problem for both humans and ecosystems. Mercury is released to the environment from a variety of human (anthropogenic) sources i...

Innovative Methods for Integrating Knowledge for Long-Term Monitoring of Contaminated Groundwater Sites: Understanding Microorganism Communities and their Associated Hydrochemical Environment

NASA Astrophysics Data System (ADS)

Mouser, P. J.; Rizzo, D. M.; Druschel, G.; O'Grady, P.; Stevens, L.

2005-12-01

This interdisciplinary study integrates hydrochemical and genome-based data to estimate the redox processes occurring at long-term monitoring sites. Groundwater samples have been collected from a well-characterized landfill-leachate contaminated aquifer in northeastern New York. Primers from the 16S rDNA gene were used to amplify Bacteria and Archaea in groundwater taken from monitoring wells located in clean, fringe, and contaminated locations within the aquifer. PCR-amplified rDNA were digested with restriction enzymes to evaluate terminal restriction fragment length polymorphism (T-RFLP) community profiles. The rDNA was cloned, sequenced, and partial sequences were matched against known organisms using the NCBI Blast database. Phylogenetic trees and bootstrapping were used to identify classifications of organisms and compare the communities from clean, fringe, and contaminated locations. We used Artificial Neural Network (ANN) models to incorporate microbial data with hydrochemical information for improving our understanding of subsurface processes.

Synthetic Electric Microbial Biosensors

DTIC Science & Technology

2017-06-10

In particular, monitoring of heavy metals in the environment, drinking water, food , and biological fluids is of interest. Conventional techniques...instances of contamination , and the potential for deliberate spills, interest has grown in portable devices for onsite long-term detection using sensor...biosensor systems for the online detection of a range of contaminants . Synthetic Biology and biosensors Synthetic biology has gained much interest

The development and implementation of a method using blue mussels (Mytilus spp.) as biosentinels of Cryptosporidium spp. and Toxoplasma gondii contamination in marine aquatic environments

EPA Science Inventory

It is estimated that protozoan parasites still account for greater than one third of waterborne disease outbreaks reported. Methods used to monitor microbial contamination typically involve collecting discrete samples at specific time-points and analyzing for a single contaminan...

Microbial Groundwater Sampling Protocol for Fecal-Rich Environments

PubMed Central

Harter, Thomas; Watanabe, Naoko; Li, Xunde; Atwill, Edward R; Samuels, William

2014-01-01

Inherently, confined animal farming operations (CAFOs) and other intense fecal-rich environments are potential sources of groundwater contamination by enteric pathogens. The ubiquity of microbial matter poses unique technical challenges in addition to economic constraints when sampling wells in such environments. In this paper, we evaluate a groundwater sampling protocol that relies on extended purging with a portable submersible stainless steel pump and Teflon® tubing as an alternative to equipment sterilization. The protocol allows for collecting a large number of samples quickly, relatively inexpensively, and under field conditions with limited access to capacity for sterilizing equipment. The protocol is tested on CAFO monitoring wells and considers three cross-contamination sources: equipment, wellbore, and ambient air. For the assessment, we use Enterococcus, a ubiquitous fecal indicator bacterium (FIB), in laboratory and field tests with spiked and blank samples, and in an extensive, multi-year field sampling campaign on 17 wells within 2 CAFOs. The assessment shows that extended purging can successfully control for equipment cross-contamination, but also controls for significant contamination of the well-head, within the well casing and within the immediate aquifer vicinity of the well-screen. Importantly, our tests further indicate that Enterococcus is frequently entrained in water samples when exposed to ambient air at a CAFO during sample collection. Wellbore and air contamination pose separate challenges in the design of groundwater monitoring strategies on CAFOs that are not addressed by equipment sterilization, but require adequate QA/QC procedures and can be addressed by the proposed sampling strategy. PMID:24903186

New family of biosensors for monitoring BTX in aquatic and edaphic environments.

PubMed

Hernández-Sánchez, Verónica; Molina, Lázaro; Ramos, Juan Luis; Segura, Ana

2016-11-01

Benzene, toluene, ethylbenzene and xylenes (BTEX) contamination is a serious threat to public health and the environment, and therefore, there is an urgent need to detect its presence in nature. The use of whole-cell reporters is an efficient, easy-to-use and low-cost approach to detect and follow contaminants outside specialized laboratories; this is especially important in oil spills that are frequent in marine environments. The aim of this study is the construction of a bioreporter system and its comparison and validation for the specific detection of monocyclic aromatic hydrocarbons in different host bacteria and environmental samples. Our bioreporter system is based on the two component regulatory system TodS-TodT of P. putida DOT-T1E, and the P todX promoter fused to the GFP protein as the reporter protein. For the construction of different biosensors, this bioreporter was transferred into three different bacterial strains isolated from three different environments, and their performance was measured. Validation of the biosensors on water samples spiked with petrol, diesel and crude oil on contaminated waters from oil spills and on contaminated soils demonstrated that they can be used in mapping and monitoring some BTEX compounds (specifically benzene, toluene and two xylene isomers). Validation of biosensors is an important issue for the integration of these devices into pollution-control programmes. © 2016 The Authors. Microbial Biotechnology published by John Wiley & Sons Ltd and Society for Applied Microbiology.

Natural Remediation at Savannah River Site

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lewis, C. M.; Van Pelt, R.

2002-02-25

Natural remediation is a general term that includes any technology or strategy that takes advantage of natural processes to remediate a contaminated media to a condition that is protective of human health and the environment. Natural remediation techniques are often passive and minimally disruptive to the environment. They are generally implemented in conjunction with traditional remedial solutions for source control (i.e., capping, stabilization, removal, soil vapor extraction, etc.). Natural remediation techniques being employed at Savannah River Site (SRS) include enhanced bio-remediation, monitored natural attenuation, and phytoremediation. Enhanced bio-remediation involves making nutrients available and conditions favorable for microbial growth. With propermore » precautions and feeding, the naturally existing microbes flourish and consume the contaminants. Case studies of enhanced bio-remediation include surface soils contaminated with PCBs and pesticides, and Volatile Organic Compound (VOC) contamination in both the vadose zone and groundwater. Monitored natural attenuation (MNA) has been selected as the preferred alternative for groundwater clean up at several SRS waste units. Successful implementation of MNA has been based on demonstration that sources have been controlled, groundwater modeling that indicates that plumes will not expand or reach surface water discharge points at levels that exceed regulatory limits, and continued monitoring. Phytoremediation is being successfully utilized at several SRS waste units. Phytoremediation involves using plants and vegetation to uptake, break down, or manage contaminants in groundwater or soils. Case studies at SRS include managing groundwater plumes of tritium and VOCs with pine trees that are native to the area. Significant decreases in tritium discharge to a site stream have been realized in one phytoremediation project. Studies of other vegetation types, methods of application, and other target contaminants are underway.« less

Retrospective biomonitoring of chemical contamination in the marine coastal environment of Terra Nova Bay (Ross Sea, Antarctica) by environmental specimen banking.

PubMed

Grotti, Marco; Pizzini, Sarah; Abelmoschi, Maria Luisa; Cozzi, Giulio; Piazza, Rossano; Soggia, Francesco

2016-12-01

Antarctica offers a good opportunity to investigate planetary-scale pollution and climate change, and provides baseline values for contaminants such as Trace Elements (TEs) and Persistent Organic Pollutants (POPs). Literature data on contaminant levels in the Antarctic environment indicate that long-range atmospheric transport is the primary pathway by which pollutants from surrounding continents are carried to this pristine environment. However, local contamination sources represented by the scientific stations are also not negligible. Climate change and global warming are altering the global budget of anthropogenic contaminants and their monitoring in Antarctica ecosystems is very important to protect the global environment. In this work, eighty specimens of Adamussium colbecki (Smith, 1902), a benthic Antarctic scallop, collected from 1996 to 2009 and stored in the Antarctic Environmental Specimen Bank, were analyzed to quantify TEs and POPs, including polychlorinated biphenyls (PCBs), polychlorinated naphthalenes (PCNs) and polycyclic aromatic hydrocarbons (PAHs). Metals concentrations were not affected by anthropogenic contributions, highlighting a natural accumulation with the age of the organism. Similarly, no temporal trend was found for PCNs, PCBs and PAHs. However, specimens collected during the summer 1997-98 showed enhanced concentration levels of PCBs and PAHs that could refer to a local anthropogenic source of contamination. Copyright © 2016 Elsevier Ltd. All rights reserved.

Geophysical monitoring of organic contaminants in sediments

NASA Astrophysics Data System (ADS)

Zhang, C.; Jennings, J.

2016-12-01

Soil and groundwater contamination pose threats to the health of human and the environment. Successful contaminant remediation requires effective in situ monitoring of physical, chemical, and biological processes in the subsurface. Minimally invasive geophysical methods have shown promise in characterizing organic contaminants in soil and groundwater and have been applied to monitor remediation processes. This study examines the sensitivity of low field proton nuclear magnetic resonance (NMR) and complex conductivity to the presence of organic contaminants in sediments. We aim to improve understanding of relationships between NMR and complex conductivity observables and hydrological properties of the sediments, as well as the amount and state of contaminants in porous media. We used toluene as a representative organic contaminant, and pure silica sands and montmorillonite clay as synthetic sediments. Sand-clay mixtures with various sand/clay ratios were prepared and saturated with different concentration of toluene. Relationships between the compositions of porous media, hydrocarbon concentration, and hydrological properties of sediments and geophysical response were investigated. The results from NMR relaxation time (T2) measurements reveal the dominant control of clay content on T2 relaxation, establish minimum toluene detectability, and demonstrate the effect of contaminant concentration on NMR signals. The diffusion-relaxation (D-T2) correlation measurement show toluene can be resolved from toluene-water mixture in sand-clay mixture. The results from ongoing complex conductivity measurements will also be presented and discussed.

Annual Reporting of Monitoring at Morrill, Kansas in 2015

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, Lorraine M.

In September 2005, the CCC/USDA initiated periodic sampling of groundwater, in accord with a program (Argonne 2005b) approved by the KDHE (2005), to monitor carbon tetrachloride concentrations in the groundwater. Under the KDHE-approved monitoring plan (Argonne 2005b), groundwater was sampled twice yearly for VOCs analyses through 2011. During the initial two years of monitoring, analysis for selected geochemical parameters was also conducted to aid in the evaluation of possible natural contaminant degradation (reductive dechlorination) processes in the subsurface environment. Consistently low levels of dissolved oxygen (DO) and oxidation-reduction potential (ORP) at monitoring well MW1D (in the deepest portion of themore » contaminated aquifer) and the presence of chloroform (the primary degradation product of carbon tetrachloride) suggested that some degree of reductive dechlorination was occurring.« less

Predicting biological effects of environmental mixtures using exposure:activity ratios (EAR) derived from US EPA’s ToxCast data: Retrospective application to chemical monitoring data

EPA Science Inventory

Chemical monitoring has been widely used in environmental surveillance to assess exposure to environmental contaminants which could represent potential hazards to exposed organisms. However, the ability to detect chemicals in the environment has rapidly outpaced assessment of pot...

View of the Columbia's RMS arm and end effector grasping IECM

NASA Image and Video Library

1982-06-27

STS004-37-670 (27 June-4 July 1982) --- The North Atlantic Ocean southeast of the Bahamas serves as backdrop for this 70mm scene of the Columbia?s remote manipulator system (RMS) arm and hand-like device (called and end effector) grasping a multi-instrument monitor for detecting contaminants. The experiments is called the induced environment contaminant monitor (IECM). The small box contains 11 instruments for checking the contaminants in and around the orbiter?s cargo bay which might adversely affect delicate experiments carried onboard. Astronauts Thomas K. Mattingly II and Henry W. Hartsfield Jr. manned the Columbia for seven days and one hour. The Columbia?s vertical tail and orbital maneuvering system (OMS) pods are at left foreground. Photo credit: NASA

Chemical contaminants entering the marine environment from sea-based sources: A review with a focus on European seas.

PubMed

Tornero, Victoria; Hanke, Georg

2016-11-15

Anthropogenic contaminants reach the marine environment mostly directly from land-based sources, but there are cases in which they are emitted or re-mobilized in the marine environment itself. This paper reviews the literature, with a predominant focus on the European environment, to compile a list of contaminants potentially released into the sea from sea-based sources and provide an overview of their consideration under existing EU regulatory frameworks. The resulting list contains 276 substances and for some of them (22 antifouling biocides, 32 aquaculture medicinal products and 34 warfare agents) concentrations and toxicity data are additionally provided. The EU Marine Strategy Framework Directive Descriptor 8, together with the Water Framework Directive and the Regional Sea Conventions, provides the provisions against pollution of marine waters by chemical substances. This literature review should inform about the current state of knowledge regarding marine contaminant sources and provide support for setting-up of monitoring approaches, including hotspots screening. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

16S rRNA beacons for bacterial monitoring during human space missions.

PubMed

Larios-Sanz, Maia; Kourentzi, Katerina D; Warmflash, David; Jones, Jeffrey; Pierson, Duane L; Willson, Richard C; Fox, George E

2007-04-01

Microorganisms are unavoidable in space environments and their presence has, at times, been a source of problems. Concerns about disease during human space missions are particularly important considering the significant changes the immune system incurs during spaceflight and the history of microbial contamination aboard the Mir space station. Additionally, these contaminants may have adverse effects on instrumentation and life-support systems. A sensitive, highly specific system to detect, characterize, and monitor these microbial populations is essential. Herein we describe a monitoring approach that uses 16S rRNA targeted molecular beacons to successfully detect several specific bacterial groupings. This methodology will greatly simplify in-flight monitoring by minimizing sample handling and processing. We also address and provide solutions to target accessibility problems encountered in hybridizations that target 16S rRNA.

Evaluation of targeted and untargeted effects-based monitoring tools to assess impacts of contaminants of emerging concern on fish in the South Platte River, CO.

PubMed

Ekman, Drew R; Keteles, Kristen; Beihoffer, Jon; Cavallin, Jenna E; Dahlin, Kenneth; Davis, John M; Jastrow, Aaron; Lazorchak, James M; Mills, Marc A; Murphy, Mark; Nguyen, David; Vajda, Alan M; Villeneuve, Daniel L; Winkelman, Dana L; Collette, Timothy W

2018-08-01

Rivers in the arid Western United States face increasing influences from anthropogenic contaminants due to population growth, urbanization, and drought. To better understand and more effectively track the impacts of these contaminants, biologically-based monitoring tools are increasingly being used to complement routine chemical monitoring. This study was initiated to assess the ability of both targeted and untargeted biologically-based monitoring tools to discriminate impacts of two adjacent wastewater treatment plants (WWTPs) on Colorado's South Platte River. A cell-based estrogen assay (in vitro, targeted) determined that water samples collected downstream of the larger of the two WWTPs displayed considerable estrogenic activity in its two separate effluent streams. Hepatic vitellogenin mRNA expression (in vivo, targeted) and NMR-based metabolomic analyses (in vivo, untargeted) from caged male fathead minnows also suggested estrogenic activity downstream of the larger WWTP, but detected significant differences in responses from its two effluent streams. The metabolomic results suggested that these differences were associated with oxidative stress levels. Finally, partial least squares regression was used to explore linkages between the metabolomics responses and the chemical contaminants that were detected at the sites. This analysis, along with univariate statistical approaches, identified significant covariance between the biological endpoints and estrone concentrations, suggesting the importance of this contaminant and recommending increased focus on its presence in the environment. These results underscore the benefits of a combined targeted and untargeted biologically-based monitoring strategy when used alongside contaminant monitoring to more effectively assess ecological impacts of exposures to complex mixtures in surface waters. Published by Elsevier Ltd.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.; Environmental Science Division

The 2007 investigation of carbon tetrachloride and chloroform contamination at Powhattan, Kansas, was conducted at the request of the Kansas Department of Health and Environment (KDHE 2006a). The Environmental Science Division of Argonne National Laboratory implemented the investigation on behalf of the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA). The primary purposes of the investigation were to evaluate potential contaminant source areas on the former CCC/USDA property, determine the horizontal and vertical extent of potential contamination, conduct groundwater monitoring, and provide recommendations for future action.

photonic sensors review progress of optical fiber sensors and its application in harsh environment

NASA Astrophysics Data System (ADS)

Zhang, Min; Ma, Xiaohong; Wang, Liwei; Lai, Shurong; Zhou, Hongpu; Zhao, Huafeng; Liao, Yanbiao

2011-03-01

Fiber sensors have been developed for industry application with significant advantages. In this paper, Fiber sensors for oil field service and harsh environment monitoring which have been investigated in Tsinghua University are demonstrated. By discussing the requirements of practical applications, the key technologies of long-period fiber grating (LPFG) based fiber sensor, optical spectrum analyzer for oil detection, laser induced breakdown spectroscopy (LIBS) system for soil contamination monitoring, and seismic sensor arrays are described.

Monitoring temporal and spatial trends of legacy and emerging contaminants in marine environment: results from the environmental specimen bank (es-BANK) of Ehime University, Japan.

PubMed

Tanabe, Shinsuke; Ramu, Karri

2012-07-01

The Environmental Specimen Bank (es-BANK) for Global Monitoring at the Center for Marine Environmental Studies, Ehime University, Japan has more than four decades of practical experience in specimen banking. Over the years, es-BANK has archived specimens representing a wide range of environmental matrices, i.e. fishes, reptiles, birds, aquatic mammals, terrestrial mammals, human, soils, and sediments. The samples have been collected as part of the various monitoring programs conducted worldwide. The current review is a summary of selected studies conducted at the Center for Marine Environmental Studies, on temporal and spatial trends of legacy and emerging contaminants in the marine environment. One of the major conclusions drawn from the studies is that environmental problems are no more regional issues and, thus, environmental specimen banking should not be limited to national boundaries, but should have a global outlook. Copyright © 2012 Elsevier Ltd. All rights reserved.

Enhanced Raman Monitor Project

NASA Technical Reports Server (NTRS)

Westenskow, Dwayne

1996-01-01

Monitoring of gaseous contaminants stems from the need to ensure a healthy and safe environment. NASA/Ames needs sensors that are able to monitor common atmospheric gas concentrations as well as trace amounts of contaminant gases. To provide an accurate assessment of air quality, a monitoring system would need to be continuous and on-line with full spectrum capabilities, allowing simultaneous detection of all gas components in a sample, including both combustible and non-combustible gases. The system demands a high degree of sensitivity to detect low gas concentrations in the low-ppm and sub-ppm regions. For clean and healthy air ('good' category), criteria established by the EPA requires that contaminant concentrations not exceed 4 ppm of carbon monoxide (CO) in an 8 hour period, 60 ppb of ozone(O3) in a one hour period and 30 ppb of sulfur dioxide (SO2) in a 24 hour period. One step below this is the National Ambient Air Quality Standard ('moderate' category) which requires that contaminant concentrations not exceed 9 ppm of carbon monoxide (CO), 120 ppb of ozone (O3) and 140 ppb of sulfur dioxide (SO2) for their respective time periods. Ideally a monitor should be able to detect the concentrations specified in the 'good' category. To benchmark current abilities of Raman technology in gas phase analysis, laboratory experiments were performed to evaluate the RASCAL II anesthetic gas monitor.

Lead distribution and its potential risk to the environment: lesson learned from environmental monitoring of abandon mine.

PubMed

Nobuntou, Wanida; Parkpian, Preeda; Oanh, Nguyen Thi Kim; Noomhorm, Athapol; Delaune, R D; Jugsujinda, Aroon

2010-11-01

There are many abandon and existing mines (tin, lead and zinc) in the mountainous areas of Thailand. Toxic elements including heavy metals such as lead (Pb), cadmium (Cd) and arsenic (As) have been released and transported from the mining sites to the adjacent landscape. In Thong Pha Phum District, Kanchanaburi Province, Thailand Pb contamination in the vicinity of the mine has occurred which could lead to potential health problems in downstream communities. To better understand current status of Pb contamination and accumulation in the surrounding environment and potential health impact, surface sediment, soil and plant samples were collected seasonally from representative monitoring sites along the aquatic track or flow regime. Potential health risk was determined using hazard quotient (HQ) as an index for local inhabitants who consume rice. Environmental monitoring illustrated that Pb concentrations in the surface sediment was as high as 869.4 mg kg(-1) dry weight and varied differently among stations sampled. Lead content in agricultural soil ranged between 137.8 to 613.5 mg kg(-1) dry weight and was inversely proportion to the distance from the point source. Moreover Pb was transported from the point source to down hill areas. At the highly polluted monitoring stations (S1, S2, and S3), concentrations of Pb exceeded the maximum allowable concentration for Pb in agricultural soil (300 mg kg(-1)) by 1.7-2 times. The Pb in soil was primarily associated with Fe/Mn oxides bound fraction (46-56%) followed by the organic bound fraction (25-30%). Lead uptake by plant varied and was species dependent. However root and tuber crops like cassava (19.92 mg Pb kg(-1) dry weight) and curcumin (3.25 mg Pb kg(-1) dry weight) could have removed Pb from the soil which suggest growing root crops in Pb contaminated soils should be avoided. However Cd, a co-contaminant at one of monitored stations (S4) yielded rice grain with Cd exceeding the maximum allowable concentration suggesting some potential health risk (HQ = 5.34) if people consume rice grown at this station. Overall result shows a low risk associated with Pb release into the environment.

WASTE HANDLING BUILDING VENTILATION SYSTEM DESCRIPTION DOCUMENT

DOE Office of Scientific and Technical Information (OSTI.GOV)

P.A. Kumar

2000-06-21

The Waste Handling Building Ventilation System provides heating, ventilation, and air conditioning (HVAC) for the contaminated, potentially contaminated, and uncontaminated areas of the Monitored Geologic Repository's (MGR) Waste Handling Building (WHB). In the uncontaminated areas, the non-confinement area ventilation system maintains the proper environmental conditions for equipment operation and personnel comfort. In the contaminated and potentially contaminated areas, in addition to maintaining the proper environmental conditions for equipment operation and personnel comfort, the contamination confinement area ventilation system directs potentially contaminated air away from personnel in the WHB and confines the contamination within high-efficiency particulate air (HEPA) filtration units. Themore » contamination confinement areas ventilation system creates airflow paths and pressure zones to minimize the potential for spreading contamination within the building. The contamination confinement ventilation system also protects the environment and the public by limiting airborne releases of radioactive or other hazardous contaminants from the WHB. The Waste Handling Building Ventilation System is designed to perform its safety functions under accident conditions and other Design Basis Events (DBEs) (such as earthquakes, tornadoes, fires, and loss of the primary electric power). Additional system design features (such as compartmentalization with independent subsystems) limit the potential for cross-contamination within the WHB. The system provides status of important system parameters and equipment operation, and provides audible and/or visual indication of off-normal conditions and equipment failures. The Waste Handling Building Ventilation System confines the radioactive and hazardous material within the building such that the release rates comply with regulatory limits. The system design, operations, and maintenance activities incorporate ALARA (as low as is reasonably achievable) principles to maintain personnel radiation doses to all occupational workers below regulatory limits and as low as is reasonably achievable. The Waste Handling Building Ventilation System interfaces with the Waste Handling Building System by being located within the WHB and by maintaining specific pressures, temperatures, and humidity within the building. The system also depends on the WHB for water supply. The system interfaces with the Site Radiological Monitoring System for continuous monitoring of the exhaust air; the Waste Handling Building Fire Protection System for detection of fire and smoke; the Waste Handling Building Electrical System for normal, emergency, and standby power; and the Monitored Geologic Repository Operations Monitoring and Control System for monitoring and control of the system.« less

Comparison of two freshwater turtle species as monitors of environmental contamination

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meyers-Schoene, L.; Walton, B.T.

1990-04-01

Two species of turtles that occupy different ecological niches were compared for their usefulness as monitors of contamination in freshwater ecosystems. Trachemys scripta (Agassiz) and Chelydra serpentina (Linnaeus) were selected for comparison based on species abundance and differences in food habits and sediment contact. A review of the literature on contaminants in turtles and results of preliminary surveys conducted at the field sites, which are included in this study, were used to direct and focus this research project. White Oak Lake, a settling basin for low-level radioactive and nonradioactive contaminants, and Bearden Creek Embayment, an uncontaminated reference site upriver, weremore » used as study sites in the investigation of turtles as indicators of chemical contamination. Turtles were analyzed for concentrations of strontium-90, cesium-137, cobalt 60, and mercury in specific target tissues, and for single-stranded DNA breaks, a non-specific indicator of possible exposure to genotoxic agents in the environment. 133 refs., 2 figs., 15 tabs.« less

The implications of the precautionary principle for biological monitoring

NASA Astrophysics Data System (ADS)

Macgarvin, M.

1995-03-01

Marine biological monitoring programmes frequently attempt to determine “safe” levels of contamination, based on assumptions about the assimilative capacity of the environment. This paper argues that such assumptions lack scientific rigour, and do not form the basis upon which a precautionary policy can be built. It notes the problems associated with assessing toxicological effects, but centres its attention on the crucial (yet far less discussed) weaknesses in theoretical ecology that make it extremely unlikely that biological monitoring can determine safe levels of contamination that leave ecosystems unaffected. It is argued that many marine biologists, if pressed, would concede these shortcomings but believe that, in the face of the technical difficulties and high costs of pollution prevention, we have no choice but to use such methods. This paper argues, with examples, that pollution prevention, often with considerable economic savings, is becoming a reality for even the most problematic substances. The difficulty is that the development of “clean production” methods lie outside the sphere of interest of those carrying out monitoring, so that measures that attempt to determine safe levels of contamination continue to be advocated. This gulf needs to be bridged so that the continuation of monitoring programmes that are part of dilute and disperse policies become regarded as inappropriate, indeed unethical. The paper concludes that this does not mean the end of marine monitoring. Instead, reliable methods for assessing physical levels of contamination will be required to determine whether the reduction targets set—as part of the introduction of clean production—are being met. Formidable difficulties will remain, requiring a precautious approach. Nevertheless, monitoring will no longer carry the burden of attempting to demonstrate that a particular level of environmental contamination is safe, which is currently destroying its scientific credibility.

Environmental Baseline Survey for Installation of Five New Hydrogeologic Groundwater Monitoring Wells

DOE Office of Scientific and Technical Information (OSTI.GOV)

Catechis, Christopher S.

This Phase I Environmental Baseline Survey (EBS) provides the findings of a survey and assessment for termination of an existing easement granted to the Department of Energy (DOE) for the installation of 5 new hydrogeologic groundwater monitoring wells located on KAFB, New Mexico. The purpose of this EBS is to: Document the nature, magnitude, and extent of any environmental contamination of the property. Identify potential environmental contamination liabilities associated with the property. Develop sufficient information to assess the health and safety risks. Ensure adequate protection for human health and the environment related to a specific property. Determine possible effects ofmore » contamination on property valuation, and serve as the basis for notice of environmental condition for applicable federal or local real property disclosure requirements.« less

Multi-residue analysis of legacy POPs and emerging organic contaminants in Singapore's coastal waters using gas chromatography-triple quadrupole tandem mass spectrometry.

PubMed

Zhang, Hui; Bayen, Stéphane; Kelly, Barry C

2015-08-01

A gas chromatography-triple quadrupole mass spectrometry (GC-MS/MS) based method was developed for determination of 86 hydrophobic organic compounds in seawater. Solid-phase extraction (SPE) was employed for sequestration of target analytes in the dissolved phase. Ultrasound assisted extraction (UAE) and florisil chromatography were utilized for determination of concentrations in suspended sediments (particulate phase). The target compounds included multi-class hydrophobic contaminants with a wide range of physical-chemical properties. This list includes several polycyclic and nitro-aromatic musks, brominated and chlorinated flame retardants, methyl triclosan, chlorobenzenes, organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs). Spiked MilliQ water and seawater samples were used to evaluate the method performance. Analyte recoveries were generally good, with the exception of some of the more volatile target analytes (chlorobenzenes and bromobenzenes). The method is very sensitive, with method detection limits typically in the low parts per quadrillion (ppq) range. Analysis of 51 field-collected seawater samples (dissolved and particulate-bound phases) from four distinct coastal sites around Singapore showed trace detection of several polychlorinated biphenyl congeners and other legacy POPs, as well as several current-use emerging organic contaminants (EOCs). Polycyclic and nitro-aromatic musks, bromobenzenes, dechlorane plus isomers (syn-DP, anti-DP) and methyl triclosan were frequently detected at appreciable levels (2-20,000pgL(-1)). The observed concentrations of the monitored contaminants in Singapore's marine environment were generally comparable to previously reported levels in other coastal marine systems. To our knowledge, these are the first measurements of these emerging contaminants of concern in Singapore or Southeast Asia. The developed method may prove beneficial for future environmental monitoring of hydrophobic organic contaminants in marine environments. Further, the study provides novel information regarding several potentially hazardous contaminants of concern in Singapore's marine environment, which will aid future risk assessment initiatives. Copyright © 2015 Elsevier B.V. All rights reserved.

[Levels of mercury in samples of bees and honey from areas with and without industrial contamination].

PubMed

Toporcák, J; Legáth, J; Kul'ková, J

1992-07-01

Increasing numbers of specialists have been concerned with the problem of friendly environment in relation to man as well as to farm and wild animals. Greater interest in the biological monitoring of environment and ecosystem contamination can be observed. Determination of residues of organic and inorganic substances in bees (Apis mellifera) and in their products is one of effective possibilities of environmental pollution monitoring. Our work was aimed at the study of mercury levels in bees and their products. Mercury levels were determined in the head, abdomen and thorax of bees (Apis mellifera) from 20 bee populations coming from industrially contaminated areas with a dominant load of mercury (10 populations) and from uncontaminated areas. Mercury levels were determined simultaneously in honey coming from both contaminated and uncontaminated areas. The following mercury levels were found in bees from the contaminated area: heads 0.029-0.385 mg/kg, thorax 0.028-0.595 mg/kg and abdomen 0.083-2.255 mg/kg. Mercury levels in samples from uncontaminated areas ranged from 0.004 to 0.024 mg/kg in the heads, from 0.004 to 0.008 mg/kg in the thorax and from 0.008 to 0.020 mg/kg in the abdomen. In honey samples from the contaminated and uncontaminated areas mercury levels ranged from 0.050 to 0.212 mg/kg and from 0.001 to 0.003 mg/kg, respectively. The results of sample analyses for mercury loads in bees and honey from both contaminated and uncontaminated areas are given in Tab. I. Mean mercury levels in the single parts of the body in Apis mellifera and in honey from contaminated and uncontaminated areas are given in Figs. 1, 2, 3.(ABSTRACT TRUNCATED AT 250 WORDS)

A new risk and stochastic analysis of monitoring and remediation in subsurface contamination

NASA Astrophysics Data System (ADS)

Papapetridis, K.; Paleologos, E.

2012-04-01

Sanitary landfills constitute the most widely used management approach for the disposal of solid wastes because of their simplicity and cost effectiveness. However, historical records indicate that landfills exhibit a high failure rate of groundwater contamination. Successful detection of aquifer contamination via monitoring wells is a complicated problem with many factors, such as the heterogeneity of the geologic environment, the dispersion of contamination into the geologic medium, the quantity and nature of the contaminants, the number and location of the monitoring wells, and the frequency of sampling, all contributing to the uncertainty of early detection. Detection of contaminants, of course, is of value if remedial actions follow as soon as possible, so that the volume of contaminated groundwater to be treated is minimized. Practically, there is always a time lag between contaminant detection and remedial action response. Administrative decisions and arrangements with local contractors initiate remedial procedures introduces a time lag between detection and remediation time. During this time lag a plume continues to move into an aquifer contaminating larger groundwater volumes. In the present study these issues are addressed by investigating the case of instantaneous leakage from a landfill facility into a heterogeneous aquifer. The stochastic Monte Carlo framework was used to address, in two dimensions, the problem of evaluating the effectiveness of contaminant detection in heterogeneous aquifers by linear networks of monitoring wells. Numerical experiments based on the random-walk tracking-particle method were conducted to determine the detection probabilities and to calculate contaminated areas at different time steps. Several cases were studied assuming different levels of geologic heterogeneity, contamination dispersion, detectable contamination limits and monitoring wells' sampling frequencies. A new perspective is introduced for the correction of risk analyses; contemporary risk analyses consider the cost of alternative remediation procedures by assuming that the contamination area to be remediated coincides with the area calculated at the time of detection. However, there is always a considerable lag between the time that a plume is detected and the time when remediation commences. This time lag constitutes a random variable that depends on available resources and technologies, as well as efficiency of administration decision-making. An expression is proposed that accounts for the delay between detection and remedial action in order to provide a correction to decision analyses that evaluate the economic worth of well monitoring. This expression illustrates that delays over 3 years are equivalent to reducing the monitoring performance of 12 wells to that of a much lower number of wells, or equally, having to consider higher failure costs than those assumed in current risk analyses.

Non-target screening analyses of organic contaminants in river systems as a base for monitoring measures

NASA Astrophysics Data System (ADS)

Schwarzbauer, J.

2009-04-01

Organic contaminants discharged to the aquatic environment exhibit a high diversity with respect to their molecular structures and the resulting physico-chemical properties. The chemical analysis of anthropogenic contamination in river systems is still an important feature, especially with respect to (i) the identification and structure elucidation of novel contaminants, (ii) to the characterisation of their environmental behaviour and (iii) to their risk for natural systems. A huge proportion of riverine contamination is caused by low-molecular weight organic compounds, like pesticides plasticizers, pharmaceuticals, personal care products, technical additives etc. Some of them, like PCB or PAH have already been investigated thoroughly and, consequently, their behaviour in aqueous systems is very well described. Although analyses on organic substances in river water traditionally focused on selected pollutants, in particular on common priority pollutants which are monitored routinely, the occurrence of further contaminants, e.g. pharmaceuticals, personal care products or chelating agents has received increasing attention within the last decade. Accompanied, screening analyses revealing an enormous diversity of low-molecular weight organic contaminants in waste water effluents and river water become more and more noticed. Since many of these substances have been rarely noticed so far, it will be an important task for the future to study their occurrence and fate in natural environments. Further on, it should be a main issue of environmental studies to provide a comprehensive view on the state of pollution of river water, in particular with respect to lipophilic low molecular weight organic contaminants. However, such non-target-screening analyses has been performed only rarely in the past. Hence, we applied extended non-target screening analyses on longitudinal sections of the rivers Rhine, Rur and Lippe (Germany) on the base of GC/MS analyses. The investigations revealed complex pattern of anthropogenic contaminants comprising a lot of still unnoticed pollutants (e.g. specific sulfones, trifluoromethyl substituted substances, nitrogen heterocycles etc.) or still unidentified compounds (such as selected brominated aromatics) of obviously high environmental relevance. In this presentation, a selection of several different contaminants will be discussed in detail comprising their emission sources, their emission behaviour, their fate within the river water bodies and in particular their structural properties. Generally. this investigation demonstrated the need to expand our analytical focus on a broader spectrum of organic contaminants, in particular to build up an adapted base for advanced monitoring studies.

Oak Ridge Reservation Annual Site Environmental Report, 2003

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hughes, JF

2004-08-24

This document is prepared annually to summarize environmental activities, primarily environmental-monitoring activities, on the ORR and within the ORR surroundings. The document fulfills the requirement of U.S. Department of Energy (DOE) Order 231.1, ''Environment, Safety and Health Reporting,'' for an annual summary of environmental data to characterize environmental performance. The environmental monitoring criteria are described in DOE Order 450.1, ''Environmental Protection Program''. The results summarized in this report are based on data collected prior to and through 2003. This report is not intended to provide the results of all sampling on the ORR. Additional data collected for other site andmore » regulatory purposes, such as environmental restoration remedial investigation reports, waste management characterization sampling data, and environmental permit compliance data, are presented in other documents that have been prepared in accordance with applicable DOE guidance and/or laws. Corrections to the report for the previous year are found in Appendix A. Environmental monitoring on the ORR consists primarily of two major activities: effluent monitoring and environmental surveillance. Effluent monitoring involves the collection and analysis of samples or measurements of liquid and gaseous effluents at the point of release to the environment; these measurements allow the quantification and official reporting of contaminants, assessment of radiation and chemical exposures to the public, and demonstration of compliance with applicable standards and permit requirements. Environmental surveillance consists of the collection and analysis of environmental samples from the site and its environs; these activities provide direct measurement of contaminants in air, water, groundwater, soil, foods, biota, and other media subsequent to effluent release into the environment. Environmental surveillance data provide information regarding conformity with applicable DOE orders and, combined with data from effluent monitoring, allow the determination of chemical and radiation dose/exposure assessments of ORR operations and effects, if any, on the local environment.« less

Oak Ridge Reservation Annual Site Environmental Report for 2003

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2004-09-30

This document is prepared annually to summarize environmental activities, primarily environmental-monitoring activities, on the ORR and within the ORR surroundings. The document fulfills the requirement of U.S. Department of Energy (DOE) Order 231.1, “Environment, Safety and Health Reporting,” for an annual summary of environmental data to characterize environmental performance. The environmental monitoring criteria are described in DOE Order 450.1, “Environmental Protection Program.” The results summarized in this report are based on data collected prior to and through 2003. This report is not intended to provide the results of all sampling on the ORR. Additional data collected for other site andmore » regulatory purposes, such as environmental restoration remedial investigation reports, waste management characterization sampling data, and environmental permit compliance data, are presented in other documents that have been prepared in accordance with applicable DOE guidance and/or laws. Corrections to the report for the previous year are found in Appendix A. Environmental monitoring on the ORR consists primarily of two major activities: effluent monitoring and environmental surveillance. Effluent monitoring involves the collection and analysis of samples or measurements of liquid and gaseous effluents at the point of release to the environment; these measurements allow the quantification and official reporting of contaminants, assessment of radiation and chemical exposures to the public, and demonstration of compliance with applicable standards and permit requirements. Environmental surveillance consists of the collection and analysis of environmental samples from the site and its environs; these activities provide direct measurement of contaminants in air, water, groundwater, soil, foods, biota, and other media subsequent to effluent release into the environment. Environmental surveillance data provide information regarding conformity with applicable DOE orders and, combined with data from effluent monitoring, allow the determination of chemical and radiation dose/exposure assessments of ORR operations and effects, if any, on the local environment.« less

Research Animal Holding Facility Prevents Space Lab Contamination

NASA Technical Reports Server (NTRS)

Savage, P. D., Jr.; Jahns, G. C.; Dalton, B. P.; Hogan, R. P.; Wray, A. E.

1991-01-01

Healthy environment for both rodents and human researchers maintained. Research animal holding facility (RAHF) and rodent cage prevent solid particles (feces, food bits, hair), micro-organisms, ammonia, and odors from escaping into outside environment during spaceflight. Rodent cage contains compartments for two animals. Provides each drinking-water dispenser, feeding alcove, and activity-monitoring port. Feeding and waste trays removable.

Contamination Mitigation Strategies for Long Duration Human Spaceflight Missions

NASA Technical Reports Server (NTRS)

Lewis, Ruthan; Lupisella, Mark; Bleacher, Jake; Farrell, William

2017-01-01

Contamination control issues are particularly challenging for long-term human spaceflight and are associated with the search for life, dynamic environmental conditions, human-robotic-environment interaction, sample collection and return, biological processes, waste management, long-term environmental disturbance, etc. These issues impact mission success, human health, planetary protection, and research and discovery. Mitigation and control techniques and strategies may include and integrate long-term environmental monitoring and reporting, contamination control and planetary protection protocols, habitation site design, habitat design, and surface exploration and traverse pathways and area access planning.

ETV - HOMELAND SECURITY EVALUATION OF CYANIDE DETECTORS

EPA Science Inventory

EPA's Environmental Technology Verification (ETV) Program was established in 1995 to objectively verify the performance of technologies that measure / monitor the quality of our environment, both for background or at suspected contamination site. The ETV program has established...

EPA Water Strategy: Advancing Technologies

EPA Science Inventory

National Risk Management Research Laboratory conducts innovative research to manage contaminants in water supplies that pose a threat to human health and the environment, and to develop approaches and tools to monitor, treat, characterize, protect, and restore impaired waterways,...

The role of environmental biotechnology in exploring, exploiting, monitoring, preserving, protecting and decontaminating the marine environment.

PubMed

Kalogerakis, Nicolas; Arff, Johanne; Banat, Ibrahim M; Broch, Ole Jacob; Daffonchio, Daniele; Edvardsen, Torgeir; Eguiraun, Harkaitz; Giuliano, Laura; Handå, Aleksander; López-de-Ipiña, Karmele; Marigomez, Ionan; Martinez, Iciar; Øie, Gunvor; Rojo, Fernando; Skjermo, Jorunn; Zanaroli, Giulio; Fava, Fabio

2015-01-25

In light of the Marine Strategy Framework Directive (MSFD) and the EU Thematic Strategy on the Sustainable Use of Natural Resources, environmental biotechnology could make significant contributions in the exploitation of marine resources and addressing key marine environmental problems. In this paper 14 propositions are presented focusing on (i) the contamination of the marine environment, and more particularly how to optimize the use of biotechnology-related tools and strategies for predicting and monitoring contamination and developing mitigation measures; (ii) the exploitation of the marine biological and genetic resources to progress with the sustainable, eco-compatible use of the maritime space (issues are very diversified and include, for example, waste treatment and recycling, anti-biofouling agents; bio-plastics); (iii) environmental/marine biotechnology as a driver for a sustainable economic growth. Copyright © 2014 Elsevier B.V. All rights reserved.

Portable Mass Spectrometer Applications for In Situ Environmental Gas Monitoring

NASA Technical Reports Server (NTRS)

Griffin, Timothy P.; Diaz, J. Andres; Arkin, C. Richard; Conejo, Elian

2005-01-01

Primary Goal of this project is to (1) Design/build a flexible system to monitor air contamination (2) Learn requirements for operating system in low pressure and low temperature environments (3) Design/build system for integration into aircraft and automobiles Secondary Goals/Offshoots are (1) Fly aboard different aircraft (2)Hand-carry unit (3) Drive unit in automobiles.

Mobility and bio-availability of heavy metals in anthropogenically contaminated alluvial (deluvial) meadow soils (EUTRIC FLUVISOLS)

NASA Astrophysics Data System (ADS)

Dinev, Nikolai; Hristova, Mariana; Tzolova, Venera

2015-04-01

The total content of heavy metals is not sufficient to assess the pollution and the risk for environment as it does not provide information for the type and solubility of heavy metals' compounds in soils. The purpose was to study and determine the mobility of heavy metals in anthropogenically contaminated alluvial (delluvial) meadow soils spread around the non-ferrous plant near the town of Asenovgrad in view of risk assessment for environment pollution. Soil samples from monitoring network (1x1 km) was used. The sequential extraction procedure described by Zein and Brummer (1989) was applied. Results showed that the easily mobilizable cadmium compounds predominate in both contaminated and not contaminated soils. The stable form of copper (associated with silicate minerals, carbonates or amorphous and crystalline oxide compounds) predominates only in non polluted soils and reviles the risk of the environment contamination. Lead spreads and accumulates as highly soluble (mobile) compounds and between 72.3 and 99.6 percent of the total lead is bioavailable in soils. The procedure is very suitable for studying the mobility of technogenic lead and copper in alluvial soils with neutral medium reaction and in particular at the high levels of cadmium contamination. In soils with alkaline reaction - polluted and unpolluted the error of analysis increases for all studied elements.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.; Environmental Science Division

The Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) operated a grain storage facility at Barnes, Kansas, during most of the interval 1949-1974. Carbon tetrachloride contamination was initially detected in 1986 in the town's public water supply wells. In 2006-2007, the CCC/USDA conducted a comprehensive targeted investigation at and near its former property in Barnes to characterize this contamination. Those results were reported previously (Argonne 2008a). In November 2007, the CCC/USDA began quarterly groundwater monitoring at Barnes. The monitoring is being conducted on behalf of the CCC/USDA by Argonne National Laboratory, in accord with the recommendations made inmore » the report for the 2006-2007 targeted investigation (Argonne 2008a). The objective is to monitor the carbon tetrachloride contamination identified in the groundwater at Barnes. The sampling is presently conducted in a network of 28 individual monitoring wells (at 19 distinct locations), 2 public water supply wells, and 1 private well (Figure 1.1). The results of the 2006-2007 targeted investigation and the subsequent monitoring events (Argonne 2008a-d, 2009) demonstrated the presence of carbon tetrachloride contamination in groundwater at levels exceeding the Kansas Department of Health and Environment (KDHE) Tier 2 risk-based screening level (RBSL) of 5.0 {micro}g/L for this compound. The contaminant plume appears to extend from the former CCC/USDA property northwestward, toward the Barnes public water supply wells. Information obtained during the 2006-2007 investigation indicates that at least one other potential source might have contributed to the groundwater contaminant plume (Argonne 2008a). The former agriculture building owned by the local school district, located immediately east of well PWS3, is also a potential source of the contamination. This current report presents the results of the fifth and sixth quarterly monitoring events, conducted in March and June 2009. During these two monitoring events, low-flow sampling methods were used to purge and sample all wells. These were the fourth and fifth events at Barnes during which the low-flow sampling method was used.« less

Capabilities of the Materials Contamination Team at Marshall Space Flight Center

NASA Technical Reports Server (NTRS)

Burns, H. D.; Finckenor, M. M.; Boothe, R. E.; Albyn, K. C.; Finchum, C. A.

2003-01-01

The Materials Contamination Team of the Environmental Effects Group, Materials, Processes, and Manufacturing Department, has been recognized for its contribution to space flight, including space transportation, space science and flight projects, such as the reusable solid rocket motor, Chandra X-Ray Observatory, and the International Space Station. The Materials Contamination Team s realm of responsibility encompasses all phases of hardware development including design, manufacturing, assembly, test, transportation, launch-site processing, on-orbit exposure, return, and refurbishment if required. Contamination is a concern in the Space Shuttle with sensitivity bondlines and reactive fluid (liquid oxygen) compatibility as well as for sensitive optics, particularly spacecraft such as Hubble Space Telescope and Chandra X-Ray Observatory. The Materials Contamination Team has a variety of facilities and instrumentation capable of contaminant detection identification, and monitoring. The team addresses material applications dealing with environments, including production facilities, clean rooms, and on-orbit exposure. The team of engineers and technicians also develop and evaluates new surface cleanliness inspection technologies. Databases are maintained by the team for proces! materials as well as outgassing and optical compatibility test results for specific environments.

Sampling the food processing environment: taking up the cudgel for preventive quality management in food processing environments.

PubMed

Wagner, Martin; Stessl, Beatrix

2014-01-01

The Listeria monitoring program for Austrian cheese factories was established in 1988. The basic idea is to control the introduction of L. monocytogenes into the food processing environment, preventing the pathogen from contaminating the food under processing. The Austrian Listeria monitoring program comprises four levels of investigation, dealing with routine monitoring of samples and consequences of finding a positive sample. Preventive quality control concepts attempt to detect a foodborne hazard along the food processing chain, prior to food delivery, retailing, and consumption. The implementation of a preventive food safety concept provokes a deepened insight by the manufacturers into problems concerning food safety. The development of preventive quality assurance strategies contributes to the national food safety status and protects public health.

Oak Ridge Reservation annual site environmental report for 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1997-10-01

The US Department of Energy currently oversees activities on the Oak Ridge Reservation (ORR), a government-owned, contractor-operated facility. Three sites compose the reservation: the Oak Ridge Y-12 Plant, Oak Ridge National Laboratory, and East Tennessee Technology Park (formerly the K-25 Site). The ORR was established in the early 1940s as part of the Manhattan Project, a secret undertaking that produced the materials for the first atomic bombs. The reservation`s role has evolved over the years, and it continues to adapt to meet the changing defense, energy, and research needs of the US. Both the work carried out for the warmore » effort and subsequent research, development, and production activities have produced (and continue to produce) radiological and hazardous wastes. This document contains a summary of environmental monitoring activities on the ORR and its surroundings. Environmental monitoring on the ORR consists of two major activities: effluent monitoring and environmental surveillance. Effluent monitoring involves the collection and analysis of samples or measurements of liquid and gaseous effluents prior to release into the environment; these measurements allow the quantification and official reporting of contaminants, assessment of radiation exposures to the public, and demonstration of compliance with applicable standards and permit requirements. Environmental surveillance consists of the collection and analysis of environmental samples from the site and its environs; this provides direct measurement of contaminants in air, water, groundwater, soil, foods, biota, and other media subsequent to effluent release into the environment. Environmental surveillance data verify ORR`s compliance status and, combined with data from effluent monitoring, allow the determination of chemical and radiation dose/exposure assessment of ORR operations and effects, if any, on the local environment.« less

How Do I Sample the Environment and Equipment?

NASA Astrophysics Data System (ADS)

Kornacki, Jeffrey L.

Food product contamination from the post-processing environment is likely the most frequent cause of contaminated processed food product recalls and a significant source of poisoning outbreaks, and shelf life problems in North America with processed Ready-To-Eat foods. Conditions exist for the growth of microorganisms in most food processing factories. Failure to clean and effectively sanitize a microbial growth niche can lead to biofilm formation. Biofilms may be orders of magnitude more resistant to destruction by sanitizers. Cells in some biofilms have been shown to be 1,000 times more resistant to destruction than those which are freely suspended. This has implications for cleaning, sanitizing, sampling, and training. Sampling the factory environment is one means of monitoring the efficacy of microbiological control as well as a powerful tool for in-factory contamination investigation. Many sampling techniques exist and are discussed. It is important to recognize the difference between cleaning (removal of soil) and sanitization (reduction of microbial populations). Knowing where, when, and how to sample, how many samples to take, and what to test for and how to interpret test information is critical in finding and preventing contamination.

Source and long-term behavior of transuranic aerosols in the WIPP environment.

PubMed

Thakur, P; Lemons, B G

2016-10-01

Source and long-term behavior transuranic aerosols ((239+240)Pu, (238)Pu, and (241)Am) in the ambient air samples collected at and near the Waste Isolation Pilot Plant (WIPP) deep geologic repository site were investigated using historical data from an independent monitoring program conducted by the Carlsbad Environmental Monitoring and Research Center and an oversight monitoring program conducted by the management and operating contractor for WIPP at and near the facility. An analysis of historical data indicates frequent detections of (239+240)Pu and (241)Am, whereas (238)Pu is detected infrequently. Peaks in (239+240)Pu and (241)Am concentrations in ambient air generally occur from March to June timeframe, which is when strong and gusty winds in the area frequently give rise to blowing dust. Long-term measurements of plutonium isotopes (1985-2015) in the WIPP environment suggest that the resuspension of previously contaminated soils is likely the primary source of plutonium in the ambient air samples from WIPP and its vicinity. There is no evidence that WIPP is a source of environmental contamination that can be considered significant by any health-based standard.

European isolation and confinement study. Additional experiments.

PubMed

Novara, M

1993-01-01

Microbiological Experiments. The ISEMSI microbiological contamination experiments confirmed known hypotheses, such as: the trend toward uniformity of skin microbial flora across a group of individuals enclosed together; the rather fast "colonization" of the environment by microorganisms shed by human inhabitants; and the heavy growth of microorganisms in poorly accessible and wet areas (toilets, air conditioning). In addition, possible disturbances of skin defense mechanisms against colonization by potentially pathogenic microbes were noted, as well as a difficulty in monitoring the microbial contents of the atmosphere (significant random variations occur between samples taken at different times and locations). Sensors for Atmospheric Contaminants. Several different prototypes of "array sensors" for the monitoring of trace gas contaminants in the atmosphere were evaluated during ISEMSI. Their performance was promising when compared with results achieved with a more conventional (and more complex) gas chromatograph/mass spectrometer device, also used during ISEMSI. An overall picture of the most important chemical contaminants to be found in enclosed, manned habitats (including contaminants produced by man himself) was obtained via the use of Tenax gas-adsorption traps. This permitted monitoring the fluctuation of contaminants on a daily basis, as well as during the complete 4-week period. Results will provide a valuable input for designing systems to monitor and control atmospheric contamination in future spacecraft. Particular attention was devoted to the monitoring of carbon monoxide in the chamber. Results showing the correlation between its concentration in the atmosphere and the percentage of carboxyhemoglobin in the EMSInauts' blood will allow the evaluation of the correctness of the presently specified maximum allowable concentration for spacecraft. Telemedicine Experiment. The telemedicine experiment confirmed the feasibility and importance of applying to a space station scenario many aspects of remote health care already widely used in the maritime environment. ISEMSI successfully evaluated telemedical consultation procedures and training protocols for the crew. EMSInauts, trained as paramedical assistants, had to interview a "patient" (another EMSInaut, trained to feign illness symptoms), prepare an anamnesis, carry out a medical examination, assess the severity of the case, and administer effective medical care under remote medical advice. An expert system was used to provide step-by-step guidance to the paramedical assistant. ISEMSI demonstrated the great importance of practicing and rehearsing emergency procedures; it confirmed that simulation of medical emergencies during an actual long-duration space mission will be required to provide "refresher training" to astronauts trained as paramedical assistants.(ABSTRACT TRUNCATED AT 400 WORDS)

Public health response to an incident of secondary chemical contamination at a beach in the United Kingdom

PubMed Central

Goodfellow, F; Murray, V; Ouki, S; Iversen, A; Sparks, A; Bartlett, T

2001-01-01

OBJECTIVES—To gather enough data from a large scale investigation involving two health authorities, to assess the possible concentrations and routes of exposure and the consequent health implications.To use the data to decide whether a polluted beach should remain open to the public. In Spring 1997, a chemical incident came to light at a beach on the south coast of England when a local resident reported a sulphurous smell, visible signs of oil, and reduced numbers of fishing bait. The beach was situated adjacent to a former gasworks site and was accessible to the public. The incident was reported to the local authority and was initially investigated by the Environment Agency and the local authority. An Environment Agency report confirmed contamination of the beach with cyanide, ammonia, and polycyclic aromatic hydrocarbons (PAHs) with associated potential health risks. The incident was then referred to the local health authorities for investigation.
METHODS—The investigation was carried out in four stages: comprehensive sampling and analysis to identify the extent of contamination, followed by an assessment of risk to health; establishment of a long term monitoring programme to identify any changes in contaminant concentrations; investigation of the effects of the contamination on shellfish; and review of the routine monitoring data and current sampling strategy.
RESULTS—The initial investigation confirmed that the beach was contaminated, with the most likely source being the adjacent former gasworks site. The level of contamination was not found to be likely to pose a hazard to users of the beach. However, subsequent investigation of shellfish in the area led to warning signs being erected on the beach to prevent human consumption of mussels contaminated with PAHs.
CONCLUSIONS—Several lessons can be learnt from this investigation, which can be applied to incident management more generally: the importance of collaboration and coordination; the need for early involvement of the health authority; and the importance of carrying out appropriate sampling and analysis as soon as possible, to assess the risk to health and the environment.


Keywords: public health; water pollutants; chemical; hydrocarbons; cyanides PMID:11245739

Contamination in Ontario farmstead domestic wells and its association with agriculture:. 2. Results from multilevel monitoring well installations

NASA Astrophysics Data System (ADS)

Rudolph, D. L.; Barry, D. A. J.; Goss, M. J.

1998-08-01

Multilevel monitoring wells (MLWs) were installed at 144 farms which were part of a province-wide survey of farm drinking water wells conducted in 1991-1992 in Ontario, Canada. The multilevel sites were selected in areas characterized by coarse-textured soils, on farms typifying local agricultural enterprises. The MLWs were installed in cultivated fields adjacent to the location of the drinking water wells on each farm (within 200 m). On 16 of these farms, MLWs were also installed in a woodlot adjacent to the field site. Water samples were collected on two occasions (winter and summer) and analyses were conducted for nitrate (NO 3-), typical bacteria and a selected suite of common pesticides. At 23% of the sites, concentrations in 50% or more of the monitored intervals exceeded the provincial drinking water standard (MAC) for NO 3--N during both sampling periods. Significantly higher frequencies of total coliform contamination were encountered in the winter (66%) than in the summer (36%). Very few pesticide detections were recorded. The average concentration of NO 3- with depth in multilevel wells decreased from approximately 10 mg N l -1 near the water table to 3 mg N l -1 at a depth of about 6.5 m. Bacteria concentrations remained more uniform with depth but decreased significantly in the summer. For most analytes, contaminant frequency was similar for both the drinking water wells and multilevel wells. The occurrence of elevated levels of contamination in the water wells appeared to be associated more with activities on the cultivated fields than with on-farm point sources of contamination. Groundwater quality determined using drinking water wells was consistent with conclusions drawn from multilevel monitoring wells, indicating the utility of water well survey data for assessing groundwater quality within the rural environment. No correlations were observed between the type of cropping practice and the frequency of groundwater contamination. Farms where manure spreading occurred, however, had significantly higher occurrences of contamination from NO 3- and bacteria than farms where manure was not applied along with commercial N-fertilizer. The uncultivated conditions beneath the woodlot areas appeared to provide an environment conducive to attenuation of nitrate but not bacteria.

Development of wireless sensor network for monitoring indoor air pollutant

NASA Astrophysics Data System (ADS)

Saad, Shaharil Mad; Shakaff, Ali Yeon Md; Saad, Abdul Rahman Mohd; Yusof @ Kamarudin, Azman Muhamad

2015-05-01

The air that we breathe with everyday contains variety of contaminants and particles. Some of these contaminants and particles are hazardous to human health. Most of the people don't realize that the content of air they being exposed to whether it was a good or bad air quality. The air quality whether in indoor or outdoor environment can be influenced by physical factors like dust particles, gaseous pollutants (including carbon dioxide, carbon monoxide and volatile organic compounds) and biological like molds and bacteria growth which largely depend on temperature and humidity condition of a room. These kinds of pollutants can affect human health, physical reaction, comfort or work performance. In this study, a wireless sensor network (WSN) monitoring system for monitor air pollutant in indoor environment was developed. The system was divided into three parts: web-based interface program, sensing module and a base station. The measured data was displayed on the web which is can be accessed by the user. The result shows that the overall measured parameters were meet the acceptable limit, requirement and criteria of indoor air pollution inside the building. The research can be used to improve the indoor air quality level in order to create a comfortable working and healthy environment for the occupants inside the building.

Microbial monitoring of spacecraft and associated environments

NASA Technical Reports Server (NTRS)

La Duc, M. T.; Kern, R.; Venkateswaran, K.

2004-01-01

Rapid microbial monitoring technologies are invaluable in assessing contamination of spacecraft and associated environments. Universal and widespread elements of microbial structure and chemistry are logical targets for assessing microbial burden. Several biomarkers such as ATP, LPS, and DNA (ribosomal or spore-specific), were targeted to quantify either total bioburden or specific types of microbial contamination. The findings of these assays were compared with conventional, culture-dependent methods. This review evaluates the applicability and efficacy of some of these methods in monitoring the microbial burden of spacecraft and associated environments. Samples were collected from the surfaces of spacecraft, from surfaces of assembly facilities, and from drinking water reservoirs aboard the International Space Station (ISS). Culture-dependent techniques found species of Bacillus to be dominant on these surfaces. In contrast, rapid, culture-independent techniques revealed the presence of many Gram-positive and Gram-negative microorganisms, as well as actinomycetes and fungi. These included both cultivable and noncultivable microbes, findings further confirmed by DNA-based microbial detection techniques. Although the ISS drinking water was devoid of cultivable microbes, molecular-based techniques retrieved DNA sequences of numerous opportunistic pathogens. Each of the methods tested in this study has its advantages, and by coupling two or more of these techniques even more reliable information as to microbial burden is rapidly obtained. Copyright 2004 Springer-Verlag.

Microbial Contamination Detection in Water Resources: Interest of Current Optical Methods, Trends and Needs in the Context of Climate Change

PubMed Central

Jung, Aude-Valérie; Le Cann, Pierre; Roig, Benoit; Thomas, Olivier; Baurès, Estelle; Thomas, Marie-Florence

2014-01-01

Microbial pollution in aquatic environments is one of the crucial issues with regard to the sanitary state of water bodies used for drinking water supply, recreational activities and harvesting seafood due to a potential contamination by pathogenic bacteria, protozoa or viruses. To address this risk, microbial contamination monitoring is usually assessed by turbidity measurements performed at drinking water plants. Some recent studies have shown significant correlations of microbial contamination with the risk of endemic gastroenteresis. However the relevance of turbidimetry may be limited since the presence of colloids in water creates interferences with the nephelometric response. Thus there is a need for a more relevant, simple and fast indicator for microbial contamination detection in water, especially in the perspective of climate change with the increase of heavy rainfall events. This review focuses on the one hand on sources, fate and behavior of microorganisms in water and factors influencing pathogens’ presence, transportation and mobilization, and on the second hand, on the existing optical methods used for monitoring microbiological risks. Finally, this paper proposes new ways of research. PMID:24747537

Characteristics and trends on global environmental monitoring research: a bibliometric analysis based on Science Citation Index Expanded.

PubMed

Zhang, Di; Fu, Hui-Zhen; Ho, Yuh-Shan

2017-11-01

A bibliometric analysis based on the Science Citation Index Expanded from Web of Science was carried out to provide insights into research activities and trends of the environmental monitoring from 1993 to 2012. Study emphases covered publication outputs, language, categories, journals, countries/territories, institutions, words, and hot issues. The results indicated that the annual output of environmental monitoring publications increased steadily. The environmental sciences and analytical chemistry were the two most common categories. Environmental Monitoring and Assessment published the most articles. The USA and the UK ranked in the top two in terms of all five indicators. The U.S. Environmental Protection Agency took the leading position of the institutions in terms of publication output. The synthesized analysis by words in title, author keywords, and KeyWords Plus provided important clues for hot issues. Researchers paid more attention on water environment monitoring than other environmental factors. The contaminants including organic contaminants, heavy metal, and radiation were most common research focuses, and the organic contaminants and heavy metal of the degree of concern were gradually rising. Sensor and biosensor played an important role in the field of environmental monitoring devices. In addition to conventional device detection method, the remote sensing, GIS, and wireless sensor networks were the mainstream environmental monitoring methods. The international organization, social awareness, and the countries' positive and effective political and policies promoted the published articles.

Sources and sinks of microplastics in Canadian Lake Ontario nearshore, tributary and beach sediments.

PubMed

Ballent, Anika; Corcoran, Patricia L; Madden, Odile; Helm, Paul A; Longstaffe, Fred J

2016-09-15

Microplastics contamination of Lake Ontario sediments is investigated with the aim of identifying distribution patterns and hotspots in nearshore, tributary and beach depositional environments. Microplastics are concentrated in nearshore sediments in the vicinity of urban and industrial regions. In Humber Bay and Toronto Harbour microplastic concentrations were consistently >500 particles per kg dry sediment. Maximum concentrations of ~28,000 particles per kg dry sediment were determined in Etobicoke Creek. The microplastic particles were primarily fibres and fragments <2mm in size. Both low- and high-density plastics were identified using Raman spectroscopy. We provide a baseline for future monitoring and discuss potential sources of microplastics in terms of how and where to implement preventative measures to reduce the contaminant influx. Although the impacts of microplastics contamination on ecosystem health and functioning is uncertain, understanding, monitoring and preventing further microplastics contamination in Lake Ontario and the other Great Lakes is crucial. Copyright © 2016 Elsevier Ltd. All rights reserved.

A 3-year hygiene and safety monitoring of a meat processing plant which uses raw materials of global origin.

PubMed

Manios, Stavros G; Grivokostopoulos, Nikolaos C; Bikouli, Vasiliki C; Doultsos, Dimitrios A; Zilelidou, Evangelia A; Gialitaki, Maria A; Skandamis, Panagiotis N

2015-09-16

A systematic approach in monitoring the hygiene of a meat processing plant using classical microbiological analyses combined with molecular characterization tools may assist in the safety of the final products. This study aimed: (i) to evaluate the total hygiene level and, (ii) to monitor and characterize the occurrence and spread of Salmonella spp. and Listeria monocytogenes in the environment and the final products of a meat industry that processes meat of global origin. In total, 2541 samples from the processing environment, the raw materials, and the final products were collected from a Greek meat industry in the period 2011-2013. All samples were subjected to enumeration of total viable counts (TVC), Escherichia coli (EC) and total coliforms (TCC) and the detection of Salmonella spp., while 709 of these samples were also analyzed for the presence L. monocytogenes. Pathogen isolates were serotyped and further characterized for their antibiotic resistance and subtyped by PFGE. Raw materials were identified as the primary source of contamination, while improper handling might have also favored the proliferation of the initial microbial load. The occurrence of Salmonella spp. and L. monocytogenes reached 5.5% and 26.9%, respectively. Various (apparent) cross-contamination or persistence trends were deduced based on PFGE analysis results. Salmonella isolates showed wide variation in their innate antibiotic resistance, contrary to L. monocytogenes ones, which were found susceptible to all antibiotics except for cefotaxime. The results emphasize the biodiversity of foodborne pathogens in a meat industry and may be used by meat processors to understand the spread of pathogens in the processing environment, as well as to assist the Food Business Operator (FBO) in establishing effective criteria for selection of raw materials and in improving meat safety and quality. This approach can limit the increase of microbial contamination during the processing steps observed in our study as well as the cross contamination of meat products. Copyright © 2014 Elsevier B.V. All rights reserved.

FISH SKELETAL ANOMALIES IN THE GULF OF MEXICO

EPA Science Inventory

Measurement of skeletal deformities in fish has been proposed as a means of monitoring pollution effects in marine environments. Effects of organic and inorganic contaminants on bone integrity are similar in that vertebral anomalies are produced, although they may develop through...

Behavioral response to contamination risk information in a spatially explicit groundwater environment: Experimental evidence

NASA Astrophysics Data System (ADS)

Li, Jingyuan; Michael, Holly A.; Duke, Joshua M.; Messer, Kent D.; Suter, Jordan F.

2014-08-01

This paper assesses the effectiveness of aquifer monitoring information in achieving more sustainable use of a groundwater resource in the absence of management policy. Groundwater user behavior in the face of an irreversible contamination threat is studied by applying methods of experimental economics to scenarios that combine a physics-based, spatially explicit, numerical groundwater model with different representations of information about an aquifer and its risk of contamination. The results suggest that the threat of catastrophic contamination affects pumping decisions: pumping is significantly reduced in experiments where contamination is possible compared to those where pumping cost is the only factor discouraging groundwater use. The level of information about the state of the aquifer also affects extraction behavior. Pumping rates differ when information that synthesizes data on aquifer conditions (a "risk gauge") is provided, despite invariant underlying economic incentives, and this result does not depend on whether the risk information is location-specific or from a whole aquifer perspective. Interestingly, users increase pumping when the risk gauge signals good aquifer status compared to a no-gauge treatment. When the gauge suggests impending contamination, however, pumping declines significantly, resulting in a lower probability of contamination. The study suggests that providing relatively simple aquifer condition guidance derived from monitoring data can lead to more sustainable use of groundwater resources.

Oak Ridge Reservation Annual Site Environmental Report for 2006

DOE Office of Scientific and Technical Information (OSTI.GOV)

McMahon, Wayne; Hughes, Joan; Coffey, Mike

2007-09-01

This document is prepared annually to summarize environmental activities, primarily environmental-monitoring activities, on the Oak Ridge Reservation (ORR) and within the ORR surroundings. The document fulfills the requirement of Department of Energy (DOE) Order 23l.IA, 'Environment, Safety and Health Reporting,' for an annual summary of environmental data to characterize environmental performance. The environmental-monitoring criteria are described in DOE Order 450.1, 'Environmental Protection Program.' The results summarized in this report are based on data collected prior to and through 2006. This report is not intended to provide the results of all sampling on the ORR. Additional data collected for other sitemore » and regulatory purposes, such as environmental restoration remedial investigation reports, waste management characterization sampling data, and environmental permit compliance data, are presented in other documents that have been prepared in accordance with applicable DOE guidance and/or laws and are referenced herein as appropriate. Corrections to the report for the previous year are found in Appendix A. Environmental monitoring on the ORR consists primarily of two major activities: effluent monitoring and environmental surveillance. Effluent monitoring involves the collection and analysis of samples or measurements of liquid and gaseous effluents at the point of release to the environment; these measurements allow the quantification and official reporting of contaminants, assessment of radiation and chemical exposures to the public, and demonstration of compliance with applicable standards and permit requirements. Environmental surveillance consists of the collection and analysis of environmental samples from the site and its environs; these activities provide direct measurement of contaminant concentrations in air, water, groundwater, soil, foods, biota, and other media. Environmental surveillance data provide information regarding conformity with applicable DOE orders and, combined with data from effluent monitoring, allow the determination of chemical and radiation dose/exposure assess ments of ORR operations and effects, if any, on the local environment.« less

Comparative evaluation of several small mammal species as monitors of heavy metals, radionuclides, and selected organic compounds in the environment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Talmage, S.S.; Walton, B.T.

1990-08-01

The primary purpose of this study was to evaluate which small mammal species are the best monitors of specific environmental contaminants. The evaluation is based on the published literature and on an analysis of small mammals trapped at several sites on the Oak Ridge National Laboratory (ORNL) Reservation in Oak Ridge, Tennessee. Studies on the uptake of heavy metals, radionuclides, and organic chemicals are reviewed in Chapter II to evaluate several small mammal species for their capacity to serve as sentinels for the presence, accumulation, and effects of various contaminants. Where several species were present at a site, a comparativemore » evaluation was made and species are ranked for their capacity to serve as monitors of specific contaminants. Food chain accumulation and food habits of the species are used to establish a relationship with suitability as a biomonitor. Tissue-specific concentration factors were noted in order to establish target tissues. Life histories, habitat, and food habits are reviewed in order to make generalizations concerning the ability of similar taxa to serve as biomonitor. Finally, the usefulness of several small mammal species as monitors of three contaminants -- benzo(a)pyrene, mercury, and strontium-90 -- present on or near the ORNL facilities was investigated. 133 refs., 5 figs., 20 tabs.« less

MERCURY IN MARINE LIFE DATABASE

EPA Science Inventory

The purpose of the Mercury in Marine Life Project is to organize information on estuarine and marine species so that EPA can better understand both the extent of monitoring for mercury and level of mercury contamination in the biota of coastal environments. This report follows a ...

A REVIEW OF APPLICATIONS OF LUMINESCENCE TO MONITORING OF CHEMICAL CONTAMINANTS IN THE ENVIRONMENT

EPA Science Inventory

The recent analytical literature on the application of luminescence techniques to the measurement of various classes of environmentally significant chemicals has been reviewed. Luminescent spectroscopy based methods are compared to other current techniques. Also, examples of rece...

Global risk of pharmaceutical contamination from highly populated developing countries.

PubMed

Rehman, Muhammad Saif Ur; Rashid, Naim; Ashfaq, Muhammad; Saif, Ameena; Ahmad, Nasir; Han, Jong-In

2015-11-01

Global pharmaceutical industry has relocated from the west to Asian countries to ensure competitive advantage. This industrial relocation has posed serious threats to the environment. The present study was carried out to assess the possible pharmaceutical contamination in the environment of emerging pharmaceutical manufacturing countries (Bangladesh, China, India and Pakistan). Although these countries have made tremendous progress in the pharmaceutical sector but most of their industrial units discharge wastewater into domestic sewage network without any treatment. The application of untreated wastewater (industrial and domestic) and biosolids (sewage sludge and manure) in agriculture causes the contamination of surface water, soil, groundwater, and the entire food web with pharmaceutical compounds (PCs), their metabolites and transformed products (TPs), and multidrug resistant microbes. This pharmaceutical contamination in Asian countries poses global risks via product export and international traveling. Several prospective research hypotheses including the development of new analytical methods to monitor these PCs/TPs and their metabolites, highly resistant microbial strains, and mixture toxicity as a consequence of pharmaceutical contamination in these emerging pharmaceutical exporters have also been proposed based on the available literature. Copyright © 2013 Elsevier Ltd. All rights reserved.

Mass balance in the monitoring of pollutants in tidal rivers of the Guanabara Bay, Rio de Janeiro, Brazil.

PubMed

da Silveira, Raquel Pinhão; Rodrigues, Ana Paula de Castro; Santelli, Ricardo Erthal; Cordeiro, Renato Campello; Bidone, Edison Dausacker

2011-10-01

This study addressed the identification and monitoring of pollution sources of terrestrial origin in rivers (domestic sewage and industrial effluents) and critical fluvial segments in highly polluted environments under tidal influence (mixing marine and continental sources) from Guanabara Bay Basin, Rio de Janeiro, Brazil. The mass balance of contaminants was determined in conditions of continuous flow (low tide) during dry season (lower dilution capability). The results allowed the evaluation of the potential of contaminant mass generation by the different river segments and the estimation of their natural and anthropogenic components. The water quality of Iguaçú and Sarapuí Rivers were evaluated for metals and biochemical oxygen demand. The method gave an excellent response, including the possibility of sources identification and contaminated river segments ranking. The approach also offers fast execution and data interpretation, being highly efficient.

Water Quality Analysis of Yosemite Creek Watershed, San Francisco, California

NASA Astrophysics Data System (ADS)

Davis, J. R.; Snow, M. K.; Aquino, A.; Huang, C.; Thai, A.; Yuen, C.

2003-12-01

Surface water quality in urban settings can become contaminated by anthropogenic inputs. Yosemite Creek watershed is situated on the east side of San Francisco near Bayview Hunters Point and provides an ideal location for water quality investigations in urban environments. Accordingly, students from Philip and Sala Burton High School monitored water quality at three locations for their physicochemical and biological characteristics. Water was tested for pH, dissolved oxygen, conductivity, total dissolved solids, salinity, and oxidation reduction potential. In addition, a Hach DR 850 digital colorimeter was utilized to measure chlorine, fluorine, nitrogen, phosphorous, and sulfate. The biological component was assessed via monitoring benthic macro invertebrates. Specifically, the presence of caddisfly (Trichoptera) were used to indicate low levels of contaminants and good water quality. Our results indicate that water quality and macro invertebrate populations varied spatially within the watershed. Further investigation is needed to pinpoint the precise location of contaminant inputs.

FY90 R&D Project Descriptions ESL (Engineering & Services Laboratory) Environics Division

DTIC Science & Technology

1989-07-01

and Development Support for Subsurface Monitoring Technology 15 19007048 Pumping and Purging Contaminants 16 19007049 Methods for Selecting In Situ...Decontamination 40 3788VW17 Treatment of Chlorinated Organics with Aboveground Bioreactors 41 3788VW18 Improved Methods for Monitoring Fuel Biodegradation 42 2...Fluoride (HF) Dispersion Model 63 21036093 Solvent Capacity Field Test Method 64 21037097 Volatile Organic Compound (VOC) Control Technology 65 21037102

Evaluating legacy contaminants and emerging chemicals in marine environments using adverse outcome pathways and biological effects-directed analysis.

PubMed

Hutchinson, Thomas H; Lyons, Brett P; Thain, John E; Law, Robin J

2013-09-30

Natural and synthetic chemicals are essential to our daily lives, food supplies, health care, industries and safe sanitation. At the same time protecting marine ecosystems and seafood resources from the adverse effects of chemical contaminants remains an important issue. Since the 1970s, monitoring of persistent, bioaccumulative and toxic (PBT) chemicals using analytical chemistry has provided important spatial and temporal trend data in three important contexts; relating to human health protection from seafood contamination, addressing threats to marine top predators and finally providing essential evidence to better protect the biodiversity of commercial and non-commercial marine species. A number of regional conventions have led to controls on certain PBT chemicals over several years (termed 'legacy contaminants'; e.g. cadmium, lindane, polycyclic aromatic hydrocarbons [PAHs] and polychlorinated biphenyls [PCBs]). Analytical chemistry plays a key role in evaluating to what extent such regulatory steps have been effective in leading to reduced emissions of these legacy contaminants into marine environments. In parallel, the application of biomarkers (e.g. DNA adducts, CYP1A-EROD, vitellogenin) and bioassays integrated with analytical chemistry has strengthened the evidence base to support an ecosystem approach to manage marine pollution problems. In recent years, however,the increased sensitivity of analytical chemistry, toxicity alerts and wider environmental awareness has led to a focus on emerging chemical contaminants (defined as chemicals that have been detected in the environment, but which are currently not included in regulatory monitoring programmes and whose fate and biological impacts are poorly understood). It is also known that natural chemicals (e.g. algal biotoxins) may also pose a threat to marine species and seafood quality. Hence complex mixtures of legacy contaminants, emerging chemicals and natural biotoxins in marine ecosystems represent important scientific, economic and health challenges. In order to meet these challenges and pursue cost-effective scientific approaches that can provide evidence necessary to support policy needs (e.g. the European Marine Strategy Framework Directive), it is widely recognised that there is a need to (i) provide marine exposure assessments for priority contaminants using a range of validated models, passive samplers and biomarkers; (ii) integrate chemical monitoring data with biological effects data across spatial and temporal scales (including quality controls); and (iii) strengthen the evidence base to understand the relationship between exposure to complex chemical mixtures, biological and ecological impacts through integrated approaches and molecular data (e.g. genomics, proteomics and metabolomics). Additionally, we support the widely held view that (iv) that rather than increasing the analytical chemistry monitoring of large number of emerging contaminants, it will be important to target analytical chemistry towards key groups of chemicals of concern using effects-directed analysis. It is also important to evaluate to what extent existing biomarkers and bioassays can address various classes of emerging chemicals using the adverse outcome pathway (AOP) approach now being developed by the Organization for Economic Cooperation and Development (OECD) with respect to human toxicology and ecotoxicology. Crown Copyright © 2013. Published by Elsevier Ltd. All rights reserved.

Sources of Listeria monocytogenes Contamination in a Cold-Smoked Rainbow Trout Processing Plant Detected by Pulsed-Field Gel Electrophoresis Typing

PubMed Central

Autio, Tiina; Hielm, Sebastian; Miettinen, Maria; Sjöberg, Anna-Maija; Aarnisalo, Kaarina; Björkroth, Johanna; Mattila-Sandholm, Tiina; Korkeala, Hannu

1999-01-01

Sites of Listeria monocytogenes contamination in a cold-smoked rainbow trout (Oncorhynchus mykiss) processing plant were detected by sampling the production line, environment, and fish at different production stages. Two lots were monitored. The frequency of raw fish samples containing L. monocytogenes was low. During processing, the frequency of fish contaminated with L. monocytogenes clearly rose after brining, and the most contaminated sites of the processing plant were the brining and postbrining areas. A total of 303 isolates from the raw fish, product, and the environment were characterized by pulsed-field gel electrophoresis (PFGE). PFGE yielded nine pulsotypes, which formed four clusters. The predominating L. monocytogenes pulsotypes of the final product were associated with brining and slicing, whereas contaminants of raw fish were not detected in the final product. Air-mediated contamination in the plant could not be proved. In accordance with these results, an L. monocytogenes eradication program was planned. The use of hot steam, hot air, and hot water seemed to be useful in eliminating L. monocytogenes. None of the control samples taken in the 5 months after the eradication program was implemented contained L. monocytogenes. PMID:9872773

Determination of selected pesticides in water samples adjacent to agricultural fields and removal of organophosphorus insecticide chlorpyrifos using soil bacterial isolates

NASA Astrophysics Data System (ADS)

Hossain, M. S.; Chowdhury, M. Alamgir Zaman; Pramanik, Md. Kamruzzaman; Rahman, M. A.; Fakhruddin, A. N. M.; Alam, M. Khorshed

2015-06-01

The use of pesticide for crops leads to serious environmental pollution, therefore, it is essential to monitor and develop approaches to remove pesticide from contaminated environment. In this study, water samples were collected to monitor pesticide residues, and degradation of chlorpyrifos was also performed using soil bacteria. Identification of pesticide residues and determination of their levels were performed by high-performance liquid chromatography with photodiode array detector. Among 12 samples, 10 samples were found contaminated with pesticides. Chlorpyrifos was detected in four tested samples and concentrations ranged from 3.27 to 9.31 μg/l whereas fenitrothion ranging from (Below Detection Limit, <0.1 μg/l) to 33.41 μg/l in the tested samples. Parathion was found in two tested samples at the concentration of 0.73 and 6.23 μg/l. None of the tested samples was found contaminated with Methoxychlor, DDT and Ethion. Three soil bacterial isolates, Pseudomonas peli BG1, Burkholderia caryophylli BG4 and Brevundimonas diminuta PD6 degraded chlorpyrifos completely in 8, 10 and 10 days, respectively, when 20 mg/l chlorpyrifos was supplied as sole source of carbon. Whereas, BG1, BG4 and PD6 took 14, 16 and 16 days, respectively, for complete removal of 50 mg/l chlorpyrifos. Chlorpyrifos degradation rates were found maximum by all three isolates at 2nd day of incubation for both tested concentrations. The results of the present study suggest the need for regular monitoring of pesticide residues in water, to protect the aquatic environment. Chlorpyrifos degrading bacterial isolates can be used to clean up environmental samples contaminated with the organophosphate pesticides.

Residues of organochlorine and synthetic pyrethroid pesticides in honey, an indicator of ambient environment, a pilot study.

PubMed

Malhat, Farag M; Haggag, Mohamed N; Loutfy, Naglaa M; Osman, Mohamed A M; Ahmed, Mohamed Tawfic

2015-02-01

Samples of honey were screened to monitor residues of organochlorine and pyrethroid pesticides. The study meant to examine the quality of honey, and to use honey as a bioindicator of environmental contamination. Residue levels were determined by gas chromatography (GC-μECD). Samples had a wide spectrum of organochlorine and synthetic pyrethroids pesticides, with hexachlorobenzene (HCB) as the most frequently detected organochlorine, followed by permethrin, heptachlor epoxide. Only one sample had a concentration of γ-HCH higher than maximum residue limit of honey (0.01 mg kg(-1)). Residues of organochlorines detected, indicate the presence of some fresh supplies, despite the ban imposed on their use. The study confirmed that honey bee and beehive matrices could be used as gauge for monitoring environment contamination. From public health point of view, the observed levels of pesticide residues in honey do not pose a serious health risk to the consumers, but raises questions of the source of organochlorines. Copyright © 2014 Elsevier Ltd. All rights reserved.

Induced Environment Contamination Monitor (IECM), air sampler - Results from the Space Transport System (STS-2) flight

NASA Technical Reports Server (NTRS)

Peters, P. N.; Hester, H. B.; Bertsch, W.; Mayfield, H.; Zatko, D.

1983-01-01

An investigation involving sampling the rapidly changing environment of the Shuttle cargo bay is considered. Four time-integrated samples and one rapid acquisition sample were collected to determine the types and quantities of contaminants present during ascent and descent of the Shuttle. The sampling times for the various bottles were controlled by valves operated by the Data Acquisition and Control System (DACS) of the IECM. Many of the observed species were found to be common solvents used in cleaning surfaces. When the actual volume sampled is taken into account, the relative mass of organics sampled during descent is about 20 percent less than during ascent.

Advanced Environmental Monitoring and Control Program: Technology Development Requirements

NASA Technical Reports Server (NTRS)

Jan, Darrell (Editor); Seshan, Panchalam (Editor); Ganapathi, Gani (Editor); Schmidt, Gregory (Editor); Doarn, Charles (Editor)

1996-01-01

Human missions in space, from the International Space Station on towards potential human exploration of the moon, Mars and beyond into the solar system, will require advanced systems to maintain an environment that supports human life. These systems will have to recycle air and water for many months or years at a time, and avoid harmful chemical or microbial contamination. NASA's Advanced Environmental Monitoring and Control program has the mission of providing future spacecraft with advanced, integrated networks of microminiaturized sensors to accurately determine and control the physical, chemical and biological environment of the crew living areas. This document sets out the current state of knowledge for requirements for monitoring the crew environment, based on (1) crew health, and (2) life support monitoring systems. Both areas are updated continuously through research and space mission experience. The technologies developed must meet the needs of future life support systems and of crew health monitoring. These technologies must be inexpensive and lightweight, and use few resources. Using these requirements to continue to push the state of the art in miniaturized sensor and control systems will produce revolutionary technologies to enable detailed knowledge of the crew environment.

Stormwater chemical contamination caused by cured-in-place pipe (CIPP) infrastructure rehabilitation activities.

PubMed

Tabor, Matthew L; Newman, Derrick; Whelton, Andrew J

2014-09-16

Cured-in-place pipe (CIPP) is becoming a popular U.S. stormwater culvert rehabilitation method. Several State transportation agencies have reported that CIPP activities can release styrene into stormwater, but no other contaminants have been monitored. CIPP's stormwater contamination potential and that of its condensate waste was characterized. Condensate completely dissolved Daphnia magna within 24 h. Condensate pH was 6.2 and its chemical oxygen demand (COD) level was 36,000 ppm. D. magna mortality (100%) occurred in 48 h, even when condensate was diluted by a factor of 10,000 and styrene was present at a magnitude less than its LC50. Condensate and stormwater contained numerous carcinogenic solvents used in resin synthesis, endocrine disrupting contaminants such as plasticizers, and initiator degradation products. For 35 days, COD levels at the culvert outlets and downstream ranged from 100 to 375 ppm and styrene was 0.01 to 7.4 ppm. Although contaminant levels generally reduced with time, styrene levels were greatest 50 ft downstream, not at the culvert outlet. Cured CIPP extraction tests confirmed that numerous contaminants other than styrene were released into the environment and their persistence and toxicity should be investigated. More effective contaminant containment and cleaner installation processes must be developed to protect the environment.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.

The Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) operated a grain storage facility at Barnes, Kansas, in 1949-1974. Carbon tetrachloride contamination was initially detected in 1986 in the town's public water supply wells. In 2006-2007, the CCC/USDA conducted a comprehensive targeted investigation at and near its former property in Barnes to characterize this contamination. Those results were reported previously (Argonne 2008a). The results of that investigation indicated that carbon tetrachloride contamination is present in groundwater at low to moderate levels in the vicinity of the former CCC/USDA grain storage facility. Information obtained during the 2006-2007 investigation alsomore » indicated that at least one other potential source might have contributed to the groundwater contaminant plume (Argonne 2008a). The former agriculture building owned by the local school district, located immediately east of well PWS3, is also a potential source of the contamination. In November 2007, the CCC/USDA began periodic groundwater monitoring at Barnes. The monitoring is being conducted on behalf of the CCC/USDA by Argonne National Laboratory, under the direction of the Kansas Department of Health and Environment (KDHE). The objective is to monitor the carbon tetrachloride contamination identified in the groundwater at Barnes. Through 2010, sampling was conducted in a network of 28 individual monitoring wells (at 19 distinct locations), 2 public water supply wells, and 1 private well (Figure 1.1). The results of the 2006-2007 targeted investigation and the subsequent monitoring events (Argonne 2008a-d, 2009a,b, 2010) demonstrated the presence of carbon tetrachloride contamination in groundwater at levels exceeding the KDHE Tier 2 risk-based screening level (RBSL) of 5.0 {micro}g/L for this compound. The contaminant plume appears to extend from the former CCC/USDA property northwestward, toward the Barnes public water supply wells. Long-term monitoring of the groundwater levels and the contaminant distribution has confirmed that pumping of the public water supply wells affects the direction of groundwater flow. When these wells are not pumping, the direction of groundwater flow is to the northeast. However, when they are pumping, groundwater flow is directed to the northwest, toward the public wells. A contingency interim measure (Argonne 2009c) has been approved by the KDHE (2009) and will be implemented if the two operating public water supply wells become contaminated at levels above the RBSL of 5.0 {micro}g/L for carbon tetrachloride. This current report presents the results of monitoring conducted in 2010. Sampling of the monitoring well network was conducted in March-April 2010 and September 2010. In addition, the two operating public water supply wells were sampled in June 2010 and December 2010. On the basis of an evaluation of the data collected in 2006-2009 (Argonne 2010), including a trend analysis of the site contamination and its migration, the KDHE (2010) concurred that future monitoring will occur on an annual basis, with twice-yearly sampling of the two public water supply wells in service (conducted in cooperation with the city). The KDHE (2010) also agreed to decrease the number wells to be sampled in the future, as discussed in Section 5.« less

Subsurface Environment Sampler for Improved In Situ Characterization of Subsurface Microbial Communities

NASA Astrophysics Data System (ADS)

Barnhart, E. P.; Ruppert, L. F.; Orem, W. H.; McIntosh, J. C.; Cunningham, A. B.; Fields, M. W.; Hiebert, R.; Hyatt, R.

2016-12-01

There is an increasing threat that deep aquifers, an important drinking water resource, may be contaminated by the extraction and transport of fossil fuels. This threat increases the need for improved groundwater monitoring and the ability to predict the extent to which microbial activity may remediate such contamination. The characterization of subsurface microbial communities could provide an ideal biomonitoring tool for the assessment of subsurface contamination due to prokaryotes environmental ubiquity, rapidity of response to environmental perturbation and the important role they play in hydrocarbon degradation and bioremediation. New DNA sequencing technologies provide the opportunity to cost-effectively identify the vast subsurface microbial ecosystem, but use of this new technology is restricted due to issues with sampling. Prior subsurface microbiology studies have relied on core samples that are expensive to obtain hard to collect aseptically and/or ground water samples that do not reflect in situ microbial densities or activities. The development of down-well incubation of sterile sediment with a Diffusive Microbial Sampler (DMS) has emerged as an alternative method to sample subsurface microbial communities that minimizes cost and contamination issues associated with traditional methods. We have designed a Subsurface Environment Sampler with a DMS module that could enable the anaerobic transport of the in situ microbial community from the field for laboratory bioremediation studies. This sampler could provide an inexpensive and standard method for subsurface microbial sampling which would make this tool useful for Federal, State, private and local agencies interested in monitoring contamination or the effectiveness of bioremediation activities in subsurface aquifers.

Does groundwater protection in Europe require new EU-wide environmental quality standards?

PubMed

Balderacchi, Matteo; Filippini, Maria; Gemitzi, Alexandra; Klöve, Björn; Petitta, Marco; Trevisan, Marco; Wachniew, Przemysław; Witczak, Stanisław; Gargini, Alessandro

2014-01-01

The European Groundwater Directive could be improved by limiting the scopes of the Annexes I and II to the manmade and natural substances, respectively, and by defining a common monitoring protocol. The changes in the European landuse patterns, in particular the urban sprawl phenomena, obscure the distinction between the point and diffuse sources of contamination. In the future more importance will be given to the household contamination. Moreover, the agricultural environment could be used for developing new conceptual models related to the pharmaceuticals.

Trace Elements in Marine Sediment and Organisms in the Gulf of Thailand

PubMed Central

Worakhunpiset, Suwalee

2018-01-01

This review summarizes the findings from studies of trace element levels in marine sediment and organisms in the Gulf of Thailand. Spatial and temporal variations in trace element concentrations were observed. Although trace element contamination levels were low, the increased urbanization and agricultural and industrial activities may adversely affect ecosystems and human health. The periodic monitoring of marine environments is recommended in order to minimize human health risks from the consumption of contaminated marine organisms. PMID:29677146

Toward Lower Organic Environments in Astromaterial Sample Curation for Diverse Collections

NASA Technical Reports Server (NTRS)

Allton, J. H.; Allen, C. C.; Burkett, P. J.; Calaway, M. J.; Oehler, D. Z.

2012-01-01

Great interest was taken during the frenzied pace of the Apollo lunar sample return to achieve and monitor organic cleanliness. Yet, the first mission resulted in higher organic contamination to samples than desired. But improvements were accomplished by Apollo 12 [1]. Quarantine complicated the goal of achieving organic cleanliness by requiring negative pressure glovebox containment environments, proximity of animal, plant and microbial organic sources, and use of organic sterilants in protocols. A special low organic laboratory was set up at University of California Berkeley (UCB) to cleanly subdivide a subset of samples [2, 3, 4]. Nevertheless, the basic approach of handling rocks and regolith inside of a positive pressure stainless steel glovebox and restrict-ing the tool and container materials allowed in the gloveboxes was established by the last Apollo sample re-turn. In the last 40 years, the collections have grown to encompass Antarctic meteorites, Cosmic Dust, Genesis solar wind, Stardust comet grains and Hayabusa asteroid grains. Each of these collections have unique curation requirements for organic contamination monitor-ing and control. Here is described some changes allowed by improved technology or driven by changes in environmental regulations and economy, concluding with comments on organic witness wafers. Future sample return missions (OSIRIS-Rex; Mars; comets) will require extremely low levels of organic contamination in spacecraft collection and thus similarly low levels in curation. JSC Curation is undertaking a program to document organic baseline levels in current operations and devise ways to reduce those levels.

Optical properties monitor: Experiment definition phase

NASA Technical Reports Server (NTRS)

Wilkes, Donald R.; Bennett, Jean M.; Hummer, Leigh L.; Chipman, Russell A.; Hadaway, James B.; Pezzaniti, Larry

1990-01-01

The stability of materials used in the space environment will continue to be a limiting technology for space missions. The Optical Properties Monitor (OPM) Experiment provides a comprehensive space research program to study the effects of the space environment (both natural and induced) on optical, thermal and space power materials. The OPM Experiment was selected for definition under the NASA/OAST In-Space Technology Experiment Program. The results of the OPM Definition Phase are presented. The OPM experiment will expose selected materials to the space environment and measure the effects with in-space optical measurements. In-space measurements include total hemispherical reflectance total integrated scatter and VUV reflectance/transmittance. The in-space measurements will be augmented with extensive pre- and post-flight sample measurements to determine other optical, mechanical, electrical, chemical or surface effects of space exposure. Environmental monitors will provide the amount and time history of the sample exposure to solar irradiation, atomic oxygen and molecular contamination.

Optical properties monitor: Experiment definition phase

NASA Technical Reports Server (NTRS)

Wilkes, Donald R.; Bennett, Jean M.; Hummer, Leigh L.; Chipman, Russell A.; Hadaway, James B.; Pezzaniti, Larry

1989-01-01

The stability of materials used in the space environment will continue to be a limiting technology for space missions. The Optical Properties Monitor (OPM) Experiment provides a comprehensive space research program to study the effects of the space environment-both natural and induced-on optical, thermal and space power materials. The OPM Experiment was selected for definition under the NASA/OAST In-Space Technology Experiment Program. The results of the OPM Definition Phase are presented. The OPM Experiment will expose selected materials to the space environment and measure the effects with in-space optical measurements. In-space measurements include total hemispherical reflectance total integrated scatter and VUV reflectance/transmittance. The in-space measurements will be augmented with extensive pre- and post-flight sample measurements to determine other optical, mechanical, electrical, chemical or surface effects of space exposure. Environmental monitors will provide the amount and time history of the sample exposure to solar irradiation, atomic oxygen and molecular contamination.

A tiered, integrated biological and chemical monitoring framework for contaminants of emerging concern in aquatic ecosystems.

PubMed

Maruya, Keith A; Dodder, Nathan G; Mehinto, Alvine C; Denslow, Nancy D; Schlenk, Daniel; Snyder, Shane A; Weisberg, Stephen B

2016-07-01

The chemical-specific risk-based paradigm that informs monitoring and assessment of environmental contaminants does not apply well to the many thousands of new chemicals that are being introduced into ambient receiving waters. We propose a tiered framework that incorporates bioanalytical screening tools and diagnostic nontargeted chemical analysis to more effectively monitor for contaminants of emerging concern (CECs). The framework is based on a comprehensive battery of in vitro bioassays to first screen for a broad spectrum of CECs and nontargeted analytical methods to identify bioactive contaminants missed by the currently favored targeted analyses. Water quality managers in California have embraced this strategy with plans to further develop and test this framework in regional and statewide pilot studies on waterbodies that receive discharge from municipal wastewater treatment plants and stormwater runoff. In addition to directly informing decisions, the data obtained using this framework can be used to construct and validate models that better predict CEC occurrence and toxicity. The adaptive interplay among screening results, diagnostic assessment and predictive modeling will allow managers to make decisions based on the most current and relevant information, instead of extrapolating from parameters with questionable linkage to CEC impacts. Integr Environ Assess Manag 2016;12:540-547. © 2015 SETAC. © 2015 SETAC.

Bee pollen as a bioindicator of environmental pesticide contamination.

PubMed

de Oliveira, Renata Cabrera; Queiroz, Sonia Claudia do Nascimento; da Luz, Cynthia Fernandes Pinto; Porto, Rafael Silveira; Rath, Susanne

2016-11-01

Honeybees and bee products are potential bioindicators of the presence of contaminants in the environment, enabling monitoring of large areas due to the long distances travelled by bees. This work evaluates the use of bee pollen as a bioindicator of environmental contamination by pesticides. A GC-MS/MS analytical method for multiresidue determination of 26 different pesticides in pollen was developed and validated in accordance with the recommendations of the European Union SANCO guide. Environmental monitoring was conducted using the analysis of 145 pollen samples collected from ten beehives in the experimental apiary of Embrapa in Jaguariúna (São Paulo State, Brazil). Bioallethrin and pendimethalin were identified in four and eighteen samples, respectively, at concentrations below the LOQ of the method (25 ng g(-1)). Passive sampling with polyurethane foam discs was used as a control, and no pesticides were found. The detection of pesticide residues in seven samples (33%) from commercial apiaries in Ribeirão Preto (São Paulo State) confirmed the efficiency of the analytical method and the need for environmental monitoring for the presence of pesticide residues. The results demonstrated the potential of bee pollen as a bioindicator of environmental contamination by pesticides. Copyright © 2016 Elsevier Ltd. All rights reserved.

Low cost environmental sensors for Spaceflight : NMP Space Environmental Monitor (SEM) requirements

NASA Technical Reports Server (NTRS)

Garrett, Henry B.; Buelher, Martin G.; Brinza, D.; Patel, J. U.

2005-01-01

An outstanding problem in spaceflight is the lack of adequate sensors for monitoring the space environment and its effects on engineering systems. By adequate, we mean low cost in terms of mission impact (e.g., low price, low mass/size, low power, low data rate, and low design impact). The New Millennium Program (NMP) is investigating the development of such a low-cost Space Environmental Monitor (SEM) package for inclusion on its technology validation flights. This effort follows from the need by NMP to characterize the space environment during testing so that potential users can extrapolate the test results to end-use conditions. The immediate objective of this effort is to develop a small diagnostic sensor package that could be obtained from commercial sources. Environments being considered are: contamination, atomic oxygen, ionizing radiation, cosmic radiation, EMI, and temperature. This talk describes the requirements and rational for selecting these environments and reviews a preliminary design that includes a micro-controller data logger with data storage and interfaces to the sensors and spacecraft. If successful, such a sensor package could be the basis of a unique, long term program for monitoring the effects of the space environment on spacecraft systems.

Low Cost Environmental Sensors for Spaceflight: NMP Space Environmental Monitor (SEM) Requirements

NASA Technical Reports Server (NTRS)

Garrett, Henry B.; Buehler, Martin G.; Brinza, D.; Patel, J. U.

2005-01-01

An outstanding problem in spaceflight is the lack of adequate sensors for monitoring the space environment and its effects on engineering systems. By adequate, we mean low cost in terms of mission impact (e.g., low price, low mass/size, low power, low data rate, and low design impact). The New Millennium Program (NMP) is investigating the development of such a low-cost Space Environmental Monitor (SEM) package for inclusion on its technology validation flights. This effort follows from the need by NMP to characterize the space environment during testing so that potential users can extrapolate the test results to end-use conditions. The immediate objective of this effort is to develop a small diagnostic sensor package that could be obtained from commercial sources. Environments being considered are: contamination, atomic oxygen, ionizing radiation, cosmic radiation, EMI, and temperature. This talk describes the requirements and rational for selecting these environments and reviews a preliminary design that includes a micro-controller data logger with data storage and interfaces to the sensors and spacecraft. If successful, such a sensor package could be the basis of a unique, long term program for monitoring the effects of the space environment on spacecraft systems.

Contamination assessment in microbiological sampling of the Eyreville core, Chesapeake Bay impact structure

USGS Publications Warehouse

Gronstal, A.L.; Voytek, M.A.; Kirshtein, J.D.; Von der, Heyde; Lowit, M.D.; Cockell, C.S.

2009-01-01

Knowledge of the deep subsurface biosphere is limited due to difficulties in recovering materials. Deep drilling projects provide access to the subsurface; however, contamination introduced during drilling poses a major obstacle in obtaining clean samples. To monitor contamination during the 2005 International Continental Scientific Drilling Program (ICDP)-U.S. Geological Survey (USGS) deep drilling of the Chesapeake Bay impact structure, four methods were utilized. Fluorescent microspheres were used to mimic the ability of contaminant cells to enter samples through fractures in the core material during retrieval. Drilling mud was infused with a chemical tracer (Halon 1211) in order to monitor penetration of mud into cores. Pore water from samples was examined using excitation-emission matrix (EEM) fl uorescence spectroscopy to characterize dissolved organic carbon (DOC) present at various depths. DOC signatures at depth were compared to signatures from drilling mud in order to identify potential contamination. Finally, microbial contaminants present in drilling mud were identified through 16S ribosomal deoxyribonucleic acid (rDNA) clone libraries and compared to species cultured from core samples. Together, these methods allowed us to categorize the recovered core samples according to the likelihood of contamination. Twenty-two of the 47 subcores that were retrieved were free of contamination by all the methods used and were subsequently used for microbiological culture and culture-independent analysis. Our approach provides a comprehensive assessment of both particulate and dissolved contaminants that could be applied to any environment with low biomass. ?? 2009 The Geological Society of America.

Colonie Interim Storage Site annual environmental report for calendar year 1991, Colonie, New York

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-09-01

This document describes the environmental monitoring program at the Colonie Interim Storage Site (CISS) and surrounding area, implementation of the program, and monitoring results for 1991. Environmental monitoring at CISS began in 1984 when Congress added the site to the US Department of Energy's Formerly Utilized Sites Remedial Action Program. CISS property and surrounding areas were radioactively contaminated by operations conducted by National Lead Industries, which manufactured various components from uranium and thorium from 1958 to 1984. The environmental monitoring program at CISS includes sampling networks for external gamma radiation exposure and for radium-226, thorium-232, and total uranium concentrations inmore » surface water, sediment, and groundwater. Additionally, several nonradiological parameters are measured in groundwater. In 1992 the program will also include sampling networks for radioactive and chemical contaminants in stormwater to meet permit application requirements under the Clean Water Act. Monitoring results are compared with applicable Environmental Protection Agency (EPA) standards, DOE derived concentration guides (DCGs), dose limits, and other requirements in DOE.orders. Environmental standards are established to protect public health and the environment. Results of environmental monitoring during 1991 indicate that average concentrations of radioactive contaminants of concern were well below applicable standards and DCGS. Concentrations of some chemical contaminants in groundwater were above-the New York State Department of Environmental Conservation (Class GA) and EPA guidelines for drinking water. The potential annual radiation exposure (excluding background) calculated for a hypothetical maximally exposed individual is 0.23 mrem (milliroentgen equivalent man), which is less than an individual would receive while traveling in an airplane at 12,000 meters (39,000 feet) for one hour.« less

Colonie Interim Storage Site annual environmental report for calendar year 1991, Colonie, New York. Formerly Utilized Sites Remedial Action Program (FUSRAP)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1992-09-01

This document describes the environmental monitoring program at the Colonie Interim Storage Site (CISS) and surrounding area, implementation of the program, and monitoring results for 1991. Environmental monitoring at CISS began in 1984 when Congress added the site to the US Department of Energy`s Formerly Utilized Sites Remedial Action Program. CISS property and surrounding areas were radioactively contaminated by operations conducted by National Lead Industries, which manufactured various components from uranium and thorium from 1958 to 1984. The environmental monitoring program at CISS includes sampling networks for external gamma radiation exposure and for radium-226, thorium-232, and total uranium concentrations inmore » surface water, sediment, and groundwater. Additionally, several nonradiological parameters are measured in groundwater. In 1992 the program will also include sampling networks for radioactive and chemical contaminants in stormwater to meet permit application requirements under the Clean Water Act. Monitoring results are compared with applicable Environmental Protection Agency (EPA) standards, DOE derived concentration guides (DCGs), dose limits, and other requirements in DOE.orders. Environmental standards are established to protect public health and the environment. Results of environmental monitoring during 1991 indicate that average concentrations of radioactive contaminants of concern were well below applicable standards and DCGS. Concentrations of some chemical contaminants in groundwater were above-the New York State Department of Environmental Conservation (Class GA) and EPA guidelines for drinking water. The potential annual radiation exposure (excluding background) calculated for a hypothetical maximally exposed individual is 0.23 mrem (milliroentgen equivalent man), which is less than an individual would receive while traveling in an airplane at 12,000 meters (39,000 feet) for one hour.« less

Calibration of the radiation monitor onboard Akebono using Geant4

NASA Astrophysics Data System (ADS)

Asai, Keiko; Takashima, Takeshi; Koi, Tatsumi; Nagai, Tsugunobu

Natural high-energy electrons and protons (keV-MeV) in the space contaminate the data re-ciprocally. In order to calibrate the energy ranges and to remove data contamination on the radiation monitor (RDM) onboard the Japanese satellite, Akebono (EXOS-D), the detector is investigated using the Geant4 simulation toolkit of computational particle tracing. The semi-polar orbiting Akebono, launched in February 1989, is active now. This satellite has been observed the space environment at altitudes of several thousands km. The RDM instrument onboard Akebono monitors energetic particles in the Earth's radiation belt and gives important data accumulated for about two solar cycles. The data from RDM are for electrons in three energy channels of 0.3 MeV, protons in three energy channels of ¿ 30 MeV, and alpha particles in one energy channels of 15-45 MeV. The energy ranges are however based on information of about 20 years ago so that the data seem to include some errors actuary. In addition, these data include contamination of electrons and protons reciprocally. Actuary it is noticed that the electron data are contaminated by the solar protons but unknown quantitative amount of the contamination. Therefore we need data calibration in order to correct the energy ranges and to remove data contamination. The Geant4 simulation gives information of trajectories of incident and secondary particles whose are interacted with materials. We examine the RDM monitor using the Geant4 simulation. We find from the results that relativistic electrons of MeV behave quite complicatedly because of particle-material interaction in the instrument. The results indicate that efficiencies of detection and contamination are dependent on energy. This study compares the electron data from Akebono RDM with the simultaneous observation of CRRES and tries to lead the values of correction for each of the energy channels.

Case study to illustrate an approach for detecting contamination and impurities in pesticide formulations.

PubMed

Karasali, Helen; Kasiotis, Konstantinos M; Machera, Kyriaki; Ambrus, Arpad

2014-11-26

Counterfeit pesticides threaten public health, food trade, and the environment. The present work draws attention to the importance of regular monitoring of impurities in formulated pesticide products. General screening revealed the presence of carbaryl as a contaminant in a copper oxychloride formulated product. In this paper, as a case study, a liquid chromatographic diode array-mass spectrometric method developed for general screening of pesticide products and quantitative determination of carbaryl together with its validation is presented. The proposed testing strategy is considered suitable for use as a general approach for testing organic contaminants and impurities in solid pesticide formulations.

The New Bedford Harbor Superfund Site Long Term Monitoring Program (1993-2009)

EPA Science Inventory

New Bedford Harbor (NBH), located in southeastern Massachusetts, was designated as a marine Superfund site in 1983 due to sediment contamination by polychlorinated biphenyls (PCBs). Based on risks to human health and the environment, the first two phases of the site cleanup invo...

DEVELOPMENT OF MARKERS OF EXPOSURE TO COPPER, NONYLPHENOL AND ATRAZINE USING SUTRACTIVE HYBRIDIZATION

EPA Science Inventory

Daphnia have been among the most commonly used test organisms for aquatic toxicity studies due to their sensitivity to contaminants. This sensitivity makes them excellent candidates for development as sentinels to monitor the occurrence of chemicals in the environment. The sequen...

Environmental exposure modeling and monitoring of human pharmaceutical concentrations in the environment

USGS Publications Warehouse

Versteeg, D.J.; Alder, A. C.; Cunningham, V. L.; Kolpin, D.W.; Murray-Smith, R.; Ternes, T.

2005-01-01

Human pharmaceuticals are receiving increased attention as environmental contaminants. This is due to their biological activity and the number of monitoring programs focusing on analysis of these compounds in various environmental media and compartments. Risk assessments are needed to understand the implications of reported concentrations; a fundamental part of the risk assessment is an assessment of environmental exposures. The purpose of this chapter is to provide guidance on the use of predictive tools (e.g., models) and monitoring data in exposure assessments for pharmaceuticals in the environment. Methods to predict environmental concentrations from equations based on first principles are presented. These equations form the basis of existing GIS (geographic information systems)-based systems for understanding the spatial distribution of pharmaceuticals in the environment. The pharmaceutical assessment and transport (PhATE), georeferenced regional exposure assessment tool for European rivers (GREAT-ER), and geographical information system (GIS)-ROUT models are reviewed and recommendations are provided concerning the design and execution of monitoring studies. Model predictions and monitoring data are compared to evaluate the relative utility of each approach in environmental exposure assessments. In summary, both models and monitoring data can be used to define representative exposure concentrations of pharmaceuticals in the environment in support of environmental risk assessments.

Advances in on-line drinking water quality monitoring and early warning systems.

PubMed

Storey, Michael V; van der Gaag, Bram; Burns, Brendan P

2011-01-01

Significant advances have been made in recent years in technologies to monitor drinking water quality for source water protection, treatment operations, and distribution system management, in the event of accidental (or deliberate) contamination. Reports prepared through the Global Water Research Coalition (GWRC) and United States Environment Protection Agency (USEPA) agree that while many emerging technologies show promise, they are still some years from being deployed on a large scale. Further underpinning their viability is a need to interpret data in real time and implement a management strategy in response. This review presents the findings of an international study into the state of the art in this field. These results are based on visits to leading water utilities, research organisations and technology providers throughout Europe, the United States and Singapore involved in the development and deployment of on-line monitoring technology for the detection of contaminants in water. Copyright © 2010 Elsevier Ltd. All rights reserved.

Near surface geophysical techniques on subsoil contamination: laboratory experiments

NASA Astrophysics Data System (ADS)

Capozzoli, Luigi; Giampaolo, Valeria; Rizzo, Enzo

2016-04-01

Hydrocarbons contamination of soil and groundwater has become a serious environmental problem, because of the increasing number of accidental spills caused by human activities. The starting point of any studies is the reconstruction of the conceptual site model. To make valid predictions about the flow pathways following by hydrocarbons compound is necessary to make a correct reconstruction of their characteristics and the environment in which they move. Near-surface geophysical methods, based on the study of electrical and electromagnetic properties, are proved to be very useful in mapping spatial distribution of the organic contaminants in the subsurface. It is well known, in fact, that electrical properties of the porous media are significantly influenced by hydrocarbons because, when contaminants enter the rock matrix, surface reaction occur between the contaminant and the soil grain surface. The main aim of this work is to investigate the capability of near-surface geophysical methods in mapping and monitoring spatial distribution of contaminants in a controlled setting. A laboratory experiment has been performed at the Hydrogeosite Laboratory of CNR-IMAA (Marsico Nuovo, PZ) where a box-sand has been contaminated by diesel. The used contaminant is a LNAPL, added to the sand through a drilled pipe. Contaminant behaviour and its migration paths have been monitored for one year by Electrical Resistivity measurements. In details, a Cross Borehole Electrical Resistivity Tomography techniques were used to characterize the contamination dynamics after a controlled hydrocarbon spillage occurring in the vadose zone. The approach with cross-borehole resistivity imaging provide a great advantage compared to more conventional surface electrical resistivity tomography, due to the high resolution at high depth (obviously depending on the depth of the well instrumented for the acquisition). This method has been shown to provide good information on the distribution of electrical properties of the subsoil at high depths and, in some cases, a detailed assessment of dynamic processes in the subsurface environment (Binley et al., 2002). Our study confirms the link between hydrocarbons contamination and geoelectrical signal and the capability of cross-hole electrical resistivity tomographies to realize a non-invasive characterization of LNAPL contamination of the media. Although, the electrical behaviour is much more complex and the relation with the contaminants depends also by time of investigation.

UV-sensitive scientific CCD image sensors

NASA Astrophysics Data System (ADS)

Vishnevsky, Grigory I.; Kossov, Vladimir G.; Iblyaminova, A. F.; Lazovsky, Leonid Y.; Vydrevitch, Michail G.

1997-06-01

An investigation of probe laser irradiation interaction with substances containing in an environment has long since become a recognized technique for contamination detection and identification. For this purpose, a near and midrange-IR laser irradiation is traditionally used. However, as many works presented on last ecology monitoring conferences show, in addition to traditional systems, rapidly growing are systems with laser irradiation from near-UV range (250 - 500 nm). Use of CCD imagers is one of the prerequisites for this allowing the development of a multi-channel computer-based spectral research system. To identify and analyze contaminating impurities on an environment, such methods as laser fluorescence analysis, UV absorption and differential spectroscopy, Raman scattering are commonly used. These methods are used to identify a large number of impurities (petrol, toluene, Xylene isomers, SO2, acetone, methanol), to detect and identify food pathogens in real time, to measure a concentration of NH3, SO2 and NO in combustion outbursts, to detect oil products in a water, to analyze contaminations in ground waters, to define ozone distribution in the atmosphere profile, to monitor various chemical processes including radioactive materials manufacturing, heterogeneous catalytic reactions, polymers production etc. Multi-element image sensor with enhanced UV sensitivity, low optical non-uniformity, low intrinsic noise and high dynamic range is a key element of all above systems. Thus, so called Virtual Phase (VP) CCDs possessing all these features, seems promising for ecology monitoring spectral measuring systems. Presently, a family of VP CCDs with different architecture and number of pixels is developed and being manufactured. All CCDs from this family are supported with a precise slow-scan digital image acquisition system that can be used in various image processing systems in astronomy, biology, medicine, ecology etc. An image is displayed directly on a PC monitor through a software support.

Field Analysis of Microbial Contamination Using Three Molecular Methods in Parallel

NASA Technical Reports Server (NTRS)

Morris, H.; Stimpson, E.; Schenk, A.; Kish, A.; Damon, M.; Monaco, L.; Wainwright, N.; Steele, A.

2010-01-01

Advanced technologies with the capability of detecting microbial contamination remain an integral tool for the next stage of space agency proposed exploration missions. To maintain a clean, operational spacecraft environment with minimal potential for forward contamination, such technology is a necessity, particularly, the ability to analyze samples near the point of collection and in real-time both for conducting biological scientific experiments and for performing routine monitoring operations. Multiple molecular methods for detecting microbial contamination are available, but many are either too large or not validated for use on spacecraft. Two methods, the adenosine- triphosphate (ATP) and Limulus Amebocyte Lysate (LAL) assays have been approved by the NASA Planetary Protection Office for the assessment of microbial contamination on spacecraft surfaces. We present the first parallel field analysis of microbial contamination pre- and post-cleaning using these two methods as well as universal primer-based polymerase chain reaction (PCR).

Monitoring occurrence and persistence of Listeria monocytogenes in foods and food processing environments in the Republic of Ireland.

PubMed

Leong, Dara; Alvarez-Ordóñez, Avelino; Jordan, Kieran

2014-01-01

Although rates of listeriosis are low in comparison to other foodborne pathogenic illness, listeriosis poses a significant risk to human health as the invasive form can have a mortality rate as high as 30%. Food processors, especially those who produce ready-to-eat (RTE) products, need to be vigilant against Listeria monocytogenes, the causative pathogen of listeriosis, and as such, the occurrence of L. monocytogenes in food and in the food processing environment needs to be carefully monitored. To examine the prevalence and patterns of contamination in food processing facilities in Ireland, 48 food processors submitted 8 samples every 2 months from March 2013 to March 2014 to be analyzed for L. monocytogenes. No positive samples were detected at 38% of the processing facilities tested. Isolates found at the remaining 62% of facilities were characterized by serotyping and Pulsed Field Gel Electrophoresis (PFGE). A general L. monocytogenes prevalence of 4.6% was seen in all samples analyzed with similar rates seen in food and environmental samples. Differences in prevalence were seen across different food processors, food sectors, sampling months etc. and PFGE analysis allowed for the examination of contamination patterns and for the identification of several persistent strains. Seven of the food processing facilities tested showed contamination with persistent strains and evidence of bacterial transfer from the processing environment to food (the same pulsotype found in both) was seen in four of the food processing facilities tested.

Monitoring occurrence and persistence of Listeria monocytogenes in foods and food processing environments in the Republic of Ireland

PubMed Central

Leong, Dara; Alvarez-Ordóñez, Avelino; Jordan, Kieran

2014-01-01

Although rates of listeriosis are low in comparison to other foodborne pathogenic illness, listeriosis poses a significant risk to human health as the invasive form can have a mortality rate as high as 30%. Food processors, especially those who produce ready-to-eat (RTE) products, need to be vigilant against Listeria monocytogenes, the causative pathogen of listeriosis, and as such, the occurrence of L. monocytogenes in food and in the food processing environment needs to be carefully monitored. To examine the prevalence and patterns of contamination in food processing facilities in Ireland, 48 food processors submitted 8 samples every 2 months from March 2013 to March 2014 to be analyzed for L. monocytogenes. No positive samples were detected at 38% of the processing facilities tested. Isolates found at the remaining 62% of facilities were characterized by serotyping and Pulsed Field Gel Electrophoresis (PFGE). A general L. monocytogenes prevalence of 4.6% was seen in all samples analyzed with similar rates seen in food and environmental samples. Differences in prevalence were seen across different food processors, food sectors, sampling months etc. and PFGE analysis allowed for the examination of contamination patterns and for the identification of several persistent strains. Seven of the food processing facilities tested showed contamination with persistent strains and evidence of bacterial transfer from the processing environment to food (the same pulsotype found in both) was seen in four of the food processing facilities tested. PMID:25191314

Oak Ridge Reservation: Annual Site Environmental Report for 2015

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rochelle, James; Rogers, Ben; Roche, Paula R.

The Oak Ridge Reservation Annual Site Environmental Report is prepared annually and presents summary environmental data to (1) characterize environmental performance, (2) summarize environmental occurrences reported during the year, (3) confirm compliance with environmental standards and requirements, and (4) highlight significant program activities. The report fulfills the requirement contained in DOE Order 231.1A, Environment, Safety and Health Reporting (DOE 2004) that an integrated annual site environmental report be prepared. The results summarized in this report are based on data collected prior to and through 2015. This report is not intended to nor does it present the results of all environmentalmore » monitoring associated with the ORR. Data collected for other site and regulatory purposes, such as environmental restoration/remedial investigation reports, waste management characterization sampling data, and environmental permit compliance data, are presented in other documents that have been prepared in accordance with applicable DOE guidance and/or laws and are referenced herein as appropriate. Environmental monitoring on the ORR consists primarily of two major activities: effluent monitoring and environmental surveillance. Effluent monitoring involves the collection and analysis of samples or measurements of liquid and gaseous effluents at the points of release to the environment; these measurements allow the quantification and official reporting of contaminant levels, assessment of radiation and chemical exposures to the public, and demonstration of compliance with applicable standards and permit requirements. Environmental surveillance consists of direct measurements and collection and analysis of samples taken from the site and its environs exclusive of effluents; these activities provide information on contaminant concentrations in air, water, groundwater, soil, foods, biota, and other media. Environmental surveillance data support determinations regarding environmental compliance and, when combined with data from effluent monitoring, support chemical and radiation dose and exposure assessments of the potential effects of ORR operations, if any, on the local environment.« less

Detection and monitoring of volatile and semivolatile pollutants in soil through different sensing strategies

NASA Astrophysics Data System (ADS)

De Cesare, Fabrizio; Macagnano, Antonella

2013-04-01

Pollutants in environments are more and more threatening the maintenance of health of habitats and their inhabitants. A proper evaluation of the impact of contaminants from several different potential sources on soil quality and health and then on organisms living therein, and the possible and sometime probable related risk of transfer of pollutants, with their toxic effects, to organisms living in different environmental compartments, through the trophic chain up to humans is strongly required by decision makers, in order to promptly take adequate actions to prevent environmental and health damages and monitor the exposure rate of individuals to toxicants. Then, a reliable detection of pollutants in environments and the monitoring of dynamics and fate of contaminants therein are of utmost importance to achieve this goal. In soil, chemical and physical techniques to detect pollutants have been well known for decades, but can often drive to both over- and underestimations of the actual bioavailable (and then toxic) fraction of contaminants, and then of the real risk for organisms, deriving from their presence therein. The use of bioindicators (both living organisms and enzyme activities somehow derived from them) can supply more reliable information about the quantification of the bioavailable fraction of soil pollutants. In the last decades, a physicochemical technique, such as SPME (solid phase microextraction) followed by GC-MS analysis, has been demonstrated to provide similar results to those obtained from some pedofaunal populations, used as bioindicators, as concerns the bioavailable pollutant quantification in soil. More recently, we have applied a sensing technology, namely electronic nose (EN), which comprises several unspecific sensors arranged in an array and that is capable of providing more qualitative than quantitative information about complex air samples, to the study of soils contaminated with semivolatile (SVOCs) pollutants, such as polycyclic aromatic hydrocarbons (PAHs). The EN device set up on purpose involved suitable sensors and it was demonstrated to be capable of supplying information related to the whole soil environment as well as to the presence of contaminants and their dynamics, such as their biodegradation by soil microorganisms and the contemporary increase of CO2 release. These results were also somehow related to those obtained through SPME-GC/MS analyses, since a list of substances could be identified to be responsible for the different classification of contaminated and uncontaminated soil samples obtained through EN. Presently, we also have got evidences that more complex sensing devices can be used for in situ monitoring of contaminated soils. We have designed and fabricated a multi-parametric hybrid sensing system, based on the assembly of several different sensors and sensing systems (i.e. single sensors and a sensor array), some of which are commercially available, while some others were created by design in laboratory and tested for their specificity. The main target of such a hybrid sensing device was to be capable of measuring various soil parameters and volatile pollutants (VOCs) in soil, such as BTEX (benzene, toluene, ethylbenzene and xylene), in order to relate the quantification and behaviour of contaminants in soil (e.g. solubility, volatility, phase partitioning, adsorption and desorption, etc.) to the relative environmental conditions, by measuring physical (temperature and moisture) and chemical (pH) parameters, which can affect such processes. Furthermore, a suitable procedure was set up on purpose to provide VOCs quantifications actually related to the bioavailable fraction of pollutants (passive vs. active sampling). That sensing system was also set up for a wireless communication of the recorded values to a data-collecting centre. Such a tool was designed to be used as a proper probe to insert into soil for in situ monitoring of contaminated sites in order to provide semi-continuous information about soil pollution conditions and evolutions, suitable for unskilled employees, on the basis of three different levels of contaminations and alarms. That probe might be then a suitable tool for decision makers about environmental risk assessment. Finally, an EN device has also been recently applied to detect microbial activity and biomass in soil. Then, the described sensing strategies might be successfully used to both monitor the presence of pollutants and their dynamics during and after remediation processes, in order to validate the effectiveness of the specific techniques applied in contaminated sites, and evaluate the recovery of soil metabolic activities and active microbial biomass.

Heavy metal contamination in the Western Indian Ocean (a review)

NASA Astrophysics Data System (ADS)

Mamboya, F. A.; Pratap, H. B.; Björk, M.

2003-05-01

Western Indian Ocean Coast has many potential marine ecosystems such as mangrove, seagrass meadows, macroalgae, and coral reefs. It is largely unspoiled environment however, tourism and population growth in coastal urban centres, industrialization, are presenting a risk of pollutants input to the marine environment of the Western Indian Ocean. Mining, shipping and agricultural activities also input contaminants into the marine environment via runoff, vessel operations and accidental spillage. Heavy metals are among the pollutants that are expected to increase in the marine environment of the Western Indian Ocean. The increase in heavy metal pollution can pose a serious health problem to marine organism and human through food chain. This paper reviews studies on heavy metal contamination in the Western Indian Ocean. It covers heavy metal studies in the sediments, biota, particulates and seawater collected in different sites. In comparison to other regions, only few studies have been conducted in the Western Indian Ocean and are localized in some certain areas. Most of these studies were conducted in Kenyan and Tanzanian coasts while few of them were conducted in Mauritius, Somalia and Reunion. No standard or common method has been reported for the analysis or monitoring of heavy metals in the Western Indian Ocean.

Occurrence of pharmaceutically active and non-steroidal estrogenic compounds in three different wastewater recycling schemes in Australia.

PubMed

Al-Rifai, Jawad H; Gabelish, Candace L; Schäfer, Andrea I

2007-10-01

The discovery that natural and synthetic chemicals, in the form of excreted hormones and pharmaceuticals, as well as a vast array of compounds with domestic and industrial applications, can enter the environment via wastewater treatment plants and cause a wide variety of environmental and health problems even at very low concentrations, suggests the need for improvement of water recycling. Three Australian wastewater recycling schemes, two of which employ reverse osmosis (RO) technology, the other applying ozonation and biological activated carbon filtration, have been studied for their ability to remove trace organic contaminants including 11 pharmaceutically active compounds and two non-steroidal estrogenic compounds. Contaminant concentrations were determined using a sensitive analytical method comprising solid phase extraction, derivatization and GC with MS using selected ion monitoring. In raw wastewater, concentrations of analgesics and non-steroidal anti-inflammatory medications were comparable to those found in wastewaters around the world. Remarkably, removal efficiencies for the three schemes were superior to literature values and RO was responsible for the greatest proportion of contaminant removal. The ability of RO membranes to concentrate many of the compounds was demonstrated and highlights the need for continued research into monitoring wastewater treatment, concentrate disposal, improved water recycling schemes and ultimately, safer water and a cleaner environment.

Science Data Report for the Optical Properties Monitor (OPM) Experiment

NASA Technical Reports Server (NTRS)

Wilkes, Donald R.; Zwiener, James M.

1999-01-01

Long term stability of spacecraft materials when exposed to the space environment continues to be a major area of investigation. The natural and induced environment surrounding a spacecraft can decrease material performance and limit useful lifetimes. The Optical Properties Monitor (OPM) experiment provided the capability to perform the important flight testing of materials and was flown on the Russian Mir Station to study the long term effects of the natural and induced space environment on materials. The core of the OPM in-flight analysis was three independent optical instruments. These instruments included an integrating sphere spectral reflectometer, a vacuum ultraviolet spectrometer, and a Total Integrated Scatter instrument. The OPM also monitored selected components of the environment including molecular contamination. The OPM was exposed on the exterior of the Mir Docking Module for approximately 8-1/2 months. This report describes the OPM experiment, a brief background of its development, program organization, experiment description, mission overview including space environment definition, performance overview, materials data including flight and ground data, in-depth post flight analysis including ground analysis measurements and a summary discussion of the findings and results.

Continuous monitoring of water flow and solute transport using vadose zone monitoring technology

NASA Astrophysics Data System (ADS)

Dahan, O.

2009-04-01

Groundwater contamination is usually attributed to pollution events that initiate on land surface. These may be related to various sources such as industrial, urban or agricultural, and may appear as point or non point sources, through a single accidental event or a continuous pollution process. In all cases, groundwater pollution is a consequence of pollutant transport processes that take place in the vadose zone above the water table. Attempts to control pollution events and prevent groundwater contamination usually involve groundwater monitoring programs. This, however, can not provide any protection against contamination since pollution identification in groundwater is clear evidence that the groundwater is already polluted and contaminants have already traversed the entire vadose zone. Accordingly, an efficient monitoring program that aims at providing information that may prevent groundwater pollution has to include vadose-zone monitoring systems. Such system should provide real-time information on the hydrological and chemical properties of the percolating water and serve as an early warning system capable of detecting pollution events in their early stages before arrival of contaminants to groundwater. Recently, a vadose-zone monitoring system (VMS) was developed to allow continuous monitoring of the hydrological and chemical properties of percolating water in the deep vadose zone. The VMS includes flexible time-domain reflectometry (FTDR) probes for continuous tracking of water content profiles, and vadose-zone sampling ports (VSPs) for frequent sampling of the deep vadose pore water at multiple depths. The monitoring probes and sampling ports are installed through uncased slanted boreholes using a flexible sleeve that allows attachment of the monitoring devices to the borehole walls while achieving good contact between the sensors and the undisturbed sediment column. The system has been successfully implemented in several studies on water flow and contaminant transport in various hydrological and geological setups. These include floodwater infiltration in arid environments, land use impact on groundwater quality, and control of remediation process in a contaminated vadose zone. The data which is collected by the VMS allows direct measurements of flow velocities and fluxes in the vadose zone while continuously monitoring the chemical evolution of the percolating water. While real time information on the hydrological and chemical properties of the percolating water in the vadose is essential to prevent groundwater contamination it is also vital for any remediation actions. Remediation of polluted soils and aquifers essentially involves manipulation of surface and subsurface hydrological, physical and biochemical conditions to improve pollutant attenuation. Controlling the biochemical conditions to enhance biodegradation often includes introducing degrading microorganisms, applying electron donors or acceptors, or adding nutrients that can promote growth of the desired degrading organisms. Accordingly real time data on the hydrological and chemical properties of the vadose zone may be used to select remediation strategies and determine its efficiency on the basis of real time information.

40 CFR 141.207 - Special notice of the availability of unregulated contaminant monitoring results.

Code of Federal Regulations, 2010 CFR

2010-07-01

... PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS Public Notification of Drinking Water Violations § 141.207 Special notice of the availability of unregulated... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Special notice of the availability of...

Process for guidance, containment, treatment, and imaging in a subsurface environment utilizing ferro-fluids

DOEpatents

Moridis, George J.; Oldenburg, Curtis M.

2001-01-01

Disclosed are processes for monitoring and control of underground contamination, which involve the application of ferrofluids. Two broad uses of ferrofluids are described: (1) to control liquid movement by the application of strong external magnetic fields; and (2) to image liquids by standard geophysical methods.

The New Bedford Harbor Superfund Site Long Term Monitoring Program: Results from 1993 to 2014

EPA Science Inventory

Background. New Bedford Harbor (NBH), located in southeastern Massachusetts, was designated as a marine Superfund site in 1983 due to sediment contamination by polychlorinated biphenyls (PCBs). Based on risks to human health and the environment, the first two phases of the site ...

Electrochemical Biosensors: A Solution to Pollution Detection with Reference to Environmental Contaminants.

PubMed

Hernandez-Vargas, Gustavo; Sosa-Hernández, Juan Eduardo; Saldarriaga-Hernandez, Sara; Villalba-Rodríguez, Angel M; Parra-Saldivar, Roberto; Iqbal, Hafiz M N

2018-03-24

The increasing environmental pollution with particular reference to emerging contaminants, toxic heavy elements, and other hazardous agents is a serious concern worldwide. Considering this global issue, there is an urgent need to design and develop strategic measuring techniques with higher efficacy and precision to detect a broader spectrum of numerous contaminants. The development of precise instruments can further help in real-time and in-process monitoring of the generation and release of environmental pollutants from different industrial sectors. Moreover, real-time monitoring can also reduce the excessive consumption of several harsh chemicals and reagents with an added advantage of on-site determination of contaminant composition prior to discharge into the environment. With key scientific advances, electrochemical biosensors have gained considerable attention to solve this problem. Electrochemical biosensors can be an excellent fit as an analytical tool for monitoring programs to implement legislation. Herein, we reviewed the current trends in the use of electrochemical biosensors as novel tools to detect various contaminant types including toxic heavy elements. A particular emphasis was given to screen-printed electrodes, nanowire sensors, and paper-based biosensors and their role in the pollution detection processes. Towards the end, the work is wrapped up with concluding remarks and future perspectives. In summary, electrochemical biosensors and related areas such as bioelectronics, and (bio)-nanotechnology seem to be growing areas that will have a marked influence on the development of new bio-sensing strategies in future studies.

Electrosurgical Smoke: Ultrafine Particle Measurements and Work Environment Quality in Different Operating Theatres.

PubMed

Romano, Francesco; Gustén, Jan; De Antonellis, Stefano; Joppolo, Cesare M

2017-01-30

Air cleanliness in operating theatres (OTs) is an important factor for preserving the health of both the patient and the medical staff. Particle contamination in OTs depends mainly on the surgery process, ventilation principle, personnel clothing systems and working routines. In many open surgical operations, electrosurgical tools (ESTs) are used for tissue cauterization. ESTs generate a significant airborne contamination, as surgical smoke. Surgical smoke is a work environment quality problem. Ordinary surgical masks and OT ventilation systems are inadequate to control this problem. This research work is based on numerous monitoring campaigns of ultrafine particle concentrations in OTs, equipped with upward displacement ventilation or with a downward unidirectional airflow system. Measurements performed during ten real surgeries highlight that the use of ESTs generates a quite sharp and relevant increase of particle concentration in the surgical area as well within the entire OT area. The measured contamination level in the OTs are linked to surgical operation, ventilation principle, and ESTs used. A better knowledge of airborne contamination is crucial for limiting the personnel's exposure to surgical smoke. Research results highlight that downward unidirectional OTs can give better conditions for adequate ventilation and contaminant removal performances than OTs equipped with upward displacement ventilation systems.

Development of the Space Station Freedom Environmental Health System

NASA Technical Reports Server (NTRS)

Richard, Elizabeth E.; Russo, Dane

1990-01-01

The Environmental Health System (EHS), a subsystem of the Space Station Freedom (SSF) Crew Health Care System, was established to ensure that crewmembers will have a safe and healthy environment in which to live and work. EHS is comprised of six subsystems: Microbiology, Toxicology, Water Quality, Radiological Health, Vibroacoustics, and Barothermal Physiology. Each subsystem contributes to the overall functions of the EHS including environmental planning, environmental monitoring, environmental monitoring, environmental health assessments, and operations support. The EHS will provide hardware for monitoring the air, water, and internal surfaces of Freedom, including capabilities for inflight sample collection, processing, and analysis. The closed environment of SSF, and its dependence on recycled air and water, will necessitate a reliable monitoring system to alert crewmembers if contamination levels exceed the maximum allowable limits established to ensure crew health and safety. This paper describes the functions and hardware design status of the EHS.

Monitoring of organic contaminants in sediments using low field proton nuclear magnetic resonance

NASA Astrophysics Data System (ADS)

Zhang, Chi; Rupert, Yuri

2016-04-01

The effective monitoring of soils and groundwater contaminated with organic compounds is an important goal of many environmental restoration efforts. Recent geophysical methods such as electrical resistivity, complex conductivity, and ground penetrating radar have been successfully applied to characterize organic contaminants in the subsurface and to monitor remediation process both in laboratory and in field. Low field proton nuclear magnetic resonance (NMR) is a geophysical tool sensitive to the molecular-scale physical and chemical environment of hydrogen-bearing fluids in geological materials and shows promise as a novel method for monitoring contaminant remediation. This laboratory research focuses on measurements on synthetic samples to determine the sensitivity of NMR to the presence of organic contaminants and improve understanding of relationships between NMR observables, hydrological properties of the sediments, and amount and state of contaminants in porous media. Toluene, a light non-aqueous phase liquid (LNAPL) has been selected as a representative organic contaminant. Three types of porous media (pure silica sands, montmorillonite clay, and various sand-clay mixtures with different sand/clay ratios) were prepared as synthetic sediments. NMR relaxation time (T2) and diffusion-relaxation (D - T2) correlation measurements were performed in each sediment saturated with water and toluene mixed fluid at assorted concentrations (0% toluene and 100% water, 1% toluene and 99% water, 5% toluene and 95% water, 25% toluene and 75% water, and 100% toluene and 0% water) to 1) understand the effect of different porous media on the NMR responses in each fluid mixture, 2) investigate the role of clay content on T2 relaxation of each fluid, 3) quantify the amount hydrocarbons in the presence of water in each sediment, and 4) resolve hydrocarbons from water in D - T2 map. Relationships between the compositions of porous media, hydrocarbon concentration, and hydraulic properties of sediments will be presented and discussed. A minimum toluene detection limit has been established, and influences on NMR signals from increasing contaminant concentration have been investigated as well. It is evident in our data that the dominant control of porous media on NMR responses relies on clay content in the sand-clay mixture.

Biosensor for remote monitoring of airborne toxins

NASA Astrophysics Data System (ADS)

Knopf, George K.; Bassi, Amarjeet S.; Singh, Shikha; Macleod, Roslyn

1999-12-01

The rapid detection of toxic contaminants released into the air by chemical processing facilities is a high priority for many manufacturers. This paper describes a novel biosensor for the remote monitoring of toxic sites. The proposed biosensor is a measurement system that employs immobilized luminescent Vibrio fisheri bacteria to detect airborne contaminants. The presence of toxic chemicals will lead to a detectable decrease in the intensity of light produced by the bacteria. Both cellular and environmental factors control the bioluminescence of these bacteria. Important design factors are the appropriate cell growth media, environmental toxicity, oxygen and cell concentrations. The luminescent bacteria are immobilized on polyvinyl alcohol (PVA) gels and placed inside a specially constructed, miniature flow cell which houses a transducer, power source, and transmitter to convert the light signal information into radio frequencies that are picked up by a receiver at a remote location. The biosensor prototype is designed to function either as a single unit mounted on an exploratory robot or numerous units spatially distributed throughout a contaminated environment for remote sensing applications.

Performance Analysis of Retrofitted Tribo-Corrosion Test Rig for Monitoring In Situ Oil Conditions.

PubMed

Siddaiah, Arpith; Khan, Zulfiqar Ahmad; Ramachandran, Rahul; Menezes, Pradeep L

2017-09-28

Oils and lubricants, once extracted after use from a mechanical system, can hardly be reused, and should be refurbished or replaced in most applications. New methods of in situ oil and lubricant efficiency monitoring systems have been introduced for a wide variety of mechanical systems, such as automobiles, aerospace aircrafts, ships, offshore wind turbines, and deep sea oil drilling rigs. These methods utilize electronic sensors to monitor the "byproduct effects" in a mechanical system that are not indicative of the actual remaining lifecycle and reliability of the oils. A reliable oil monitoring system should be able to monitor the wear rate and the corrosion rate of the tribo-pairs due to the inclusion of contaminants. The current study addresses this technological gap, and presents a novel design of a tribo-corrosion test rig for oils used in a dynamic system. A pin-on-disk tribometer test rig retrofitted with a three electrode-potentiostat corrosion monitoring system was used to analyze the corrosion and wear rate of a steel tribo-pair in industrial grade transmission oil. The effectiveness of the retrofitted test rig was analyzed by introducing various concentrations of contaminants in an oil medium that usually leads to a corrosive working environment. The results indicate that the retrofitted test rig can effectively monitor the in situ tribological performance of the oil in a controlled dynamic corrosive environment. It is a useful method to understand the wear-corrosion synergies for further experimental work, and to develop accurate predictive lifecycle assessment and prognostic models. The application of this system is expected to have economic benefits and help reduce the ecological oil waste footprint.

Performance Analysis of Retrofitted Tribo-Corrosion Test Rig for Monitoring In Situ Oil Conditions

PubMed Central

Ramachandran, Rahul; Menezes, Pradeep L.

2017-01-01

Oils and lubricants, once extracted after use from a mechanical system, can hardly be reused, and should be refurbished or replaced in most applications. New methods of in situ oil and lubricant efficiency monitoring systems have been introduced for a wide variety of mechanical systems, such as automobiles, aerospace aircrafts, ships, offshore wind turbines, and deep sea oil drilling rigs. These methods utilize electronic sensors to monitor the “byproduct effects” in a mechanical system that are not indicative of the actual remaining lifecycle and reliability of the oils. A reliable oil monitoring system should be able to monitor the wear rate and the corrosion rate of the tribo-pairs due to the inclusion of contaminants. The current study addresses this technological gap, and presents a novel design of a tribo-corrosion test rig for oils used in a dynamic system. A pin-on-disk tribometer test rig retrofitted with a three electrode-potentiostat corrosion monitoring system was used to analyze the corrosion and wear rate of a steel tribo-pair in industrial grade transmission oil. The effectiveness of the retrofitted test rig was analyzed by introducing various concentrations of contaminants in an oil medium that usually leads to a corrosive working environment. The results indicate that the retrofitted test rig can effectively monitor the in situ tribological performance of the oil in a controlled dynamic corrosive environment. It is a useful method to understand the wear–corrosion synergies for further experimental work, and to develop accurate predictive lifecycle assessment and prognostic models. The application of this system is expected to have economic benefits and help reduce the ecological oil waste footprint. PMID:28956819

Dynamic Sampling of Trace Contaminants During the Mission Operations Test of the Deep Space Habitat

NASA Technical Reports Server (NTRS)

Monje, Oscar; Valling, Simo; Cornish, Jim

2013-01-01

The atmospheric composition inside spacecraft during long duration space missions is dynamic due to changes in the living and working environment of crew members, crew metabolism and payload operations. A portable FTIR gas analyzer was used to monitor the atmospheric composition within the Deep Space Habitat (DSH) during the Mission Operations Test (MOT) conducted at the Johnson Space Center (JSC). The FTIR monitored up to 20 gases in near- real time. The procedures developed for operating the FTIR were successful and data was collected with the FTIR at 5 minute intervals. Not all the 20 gases sampled were detected in all the modules and it was possible to measure dynamic changes in trace contaminant concentrations that were related to crew activities involving exercise and meal preparation.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.; Environmental Science Division

The Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) operated a grain storage facility at Barnes, Kansas, during most of the interval 1949-1974. Carbon tetrachloride contamination was initially detected in 1986 in the town's public water supply wells. In 2006-2007, the CCC/USDA conducted a comprehensive targeted investigation at and near its former property in Barnes to characterize this contamination. Those results were reported previously (Argonne 2008a). In November 2007, the CCC/USDA began quarterly groundwater monitoring at Barnes. The monitoring is being conducted on behalf of the CCC/USDA by Argonne National Laboratory, in accord with the recommendations made inmore » the report for the 2006-2007 targeted investigation (Argonne 2008a). The objective is to monitor the carbon tetrachloride contamination identified in the groundwater at Barnes. The sampling is presently conducted in a network of 28 individual monitoring wells (at 19 distinct locations), 2 public water supply wells, and 1 private well (Figure 1.1). The results of the 2006-2007 targeted investigation and the subsequent monitoring events (Argonne 2008a-d, 2009a,b) demonstrated the presence of carbon tetrachloride contamination in groundwater at levels exceeding the Kansas Department of Health and Environment (KDHE) Tier 2 risk-based screening level (RBSL) of 5.0 {micro}g/L for this compound. The contaminant plume appears to extend from the former CCC/USDA property northwestward, toward the Barnes public water supply wells. Information obtained during the 2006-2007 investigation indicates that at least one other potential source might have contributed to the groundwater contaminant plume (Argonne 2008a). The former agriculture building owned by the local school district, located immediately east of well PWS3, is also a potential source of the contamination. This current report presents the results of the seventh quarterly monitoring event, conducted in September-October, and also sampling of only the public wells in December 2009. During the September-October quarterly event, low-flow sampling methods were used to purge and sample all wells. This was the seventh event at Barnes during which the low-flow sampling method was used. After the September-October 2009 quarterly sampling event, the KDHE (2009) approved a change in the sampling frequency for the monitoring wells from quarterly to twice yearly. Quarterly sampling is to continue for the public water supply wells. Accordingly, in December 2009, only the public wells were sampled. All results for the six-month period July-December 2009 are reported here.« less

Temporal Change of Environmental Contamination Conditions in Five Years after the Fukushima Accident

NASA Astrophysics Data System (ADS)

Saito, Kimiaki

2017-09-01

The temporal change of environmental contamination conditions after the Fukushima accident have been clarified based on large-scale environmental monitoring data repeatedly obtained in the 80 km zone. The decreasing tendency of air dose rates was confirmed to obviously depend on land uses. In human-related diverse environments the air dose rates have decreased much faster than the physical decay of radiocesium. The horizontal movement of radiocesium in undisturbed fields were found to be generally quite small, though it has gradually penetrated into the deeper parts of the ground.

Using natural archives to track sources and long-term trends of pollution: some final thoughts and suggestions for future directions

USGS Publications Warehouse

Blais, Jules M.; Rosen, Michael R.; Smol, John P.

2015-01-01

Newly produced, as well as some so-called legacy contaminants, continue to be released into the environment at an accelerated rate. Given the general lack of integrated, direct monitoring programs, the use of natural archival records of contaminants will almost certainly continue to increase. We conclude this volume with a short chapter highlighting some of our final thoughts, with a focus on a call to action to develop and apply methodologies to assess the fidelity of the archival record.

Exploring the occurrence and distribution of contaminants of emerging concern through unmanned sampling from ships of opportunity in the North Sea

NASA Astrophysics Data System (ADS)

Brumovský, Miroslav; Bečanová, Jitka; Kohoutek, Jiří; Thomas, Henrike; Petersen, Wilhelm; Sørensen, Kai; Sáňka, Ondřej; Nizzetto, Luca

2016-10-01

Chemical pollution is of concern for the marine environment. New European regulation demands exposure and impact assessment to be conducted in coastal environments in order to define and ensure fulfillment of environmental quality standards. A cost-effective approach for monitoring the over 100,000 km of European coasts is necessary. This proof-of-concept study focuses on the use of unmanned water sampling from a commercial ship of opportunity to implement monitoring of marine contaminants of emerging concern. Marine areas that are not directly affected by river plumes or other direct sources were covered in order to provide information on background pollution. 14 currently used pesticides, 11 pharmaceuticals and personal care products and 3 food additives were detected in water samples through targeted analysis at sub-ng to tenths of ng/L levels in both coastal and offshore areas of the North Sea. Among contaminants, 6 pesticides (dimethoate, fenpropimorph, pendimethalin, propiconazole, tebuconazole and temephos), 3 pharmaceuticals (acetaminophen, naproxen and ketoprofen) and 2 food additives (acesulfame and saccharine) have never been detected before in offshore areas. 4 pesticides (diuron, isoproturon, metazachlor and terbuthylazine), 4 pharmaceuticals (carbamazepine, atenolol, ibuprofen and ketoprofen) and 2 food additives (sucralose and acesulfame) were detected in over 90% of the samples. The antibiotic sulfamethoxazole was detected in 50% of the samples at tenths of pg/L levels, including some offshore areas. Our study highlights that the use of ships of opportunity can provide a key support for the development and cost-effective implementation of marine monitoring of chemical pollutants in Europe and elsewhere.

Illicit drugs and pharmaceuticals in the environment--forensic applications of environmental data, Part 2: Pharmaceuticals as chemical markers of faecal water contamination.

PubMed

Kasprzyk-Hordern, Barbara; Dinsdale, Richard M; Guwy, Alan J

2009-06-01

This manuscript is part two of a two-part study aiming to provide a better understanding and application of environmental data not only for environmental aims but also to meet forensic objectives. In this paper pharmaceuticals were investigated as potential chemical indicators of water contamination with sewage. The monitoring program carried out in Wales revealed that some pharmaceuticals are particularly persistent and/or ubiquitous in contaminated river water and therefore might be considered as potential conservative or labile wastewater indicators. In particular, these include some anti-inflammatory/analgesics, antiepileptics, beta-blockers, some H2-receptor antagonists and antibacterial drugs.

Exposure to 4,4'-methylene bis (2-chloroaniline) (MbOCA) in New South Wales, Australia

PubMed Central

Shankar, Kiran; Fung, Vivian; Seneviratne, Mahinda; O'Donnell, Gregory E

2017-01-01

Objectives: This study was conducted to determine the level of exposure of 4,4'-methylene bis (2-chloroaniline) (MbOCA) in New South Wales (NSW), Australia. Methods: An integrated occupational hygiene and biological monitoring program were used to assess the workers' exposure to MbOCA via inhalation, ingestion and dermal contact. This was conducted by personal air monitoring, static air monitoring and surface contamination monitoring of the work environment and biological monitoring of the workers' exposure to MbOCA at nine workplaces in NSW. Results: The air monitoring results for MbOCA gave a geometric mean (GM) of 0.06 μg/m3 and a geometric standard deviation (GSD) of 2.70 and a 95% confidence interval of 0.29 μg/m3. The surface contamination in the main work area showed the highest contamination with a GM of 74 ng/cm2 and a GSD of 17 and a 95% confidence interval of 7,751 ng/cm2. Biological monitoring showed a GM of 0.89 μmol/mol cr and a GSD of 11.9 and a 95% confidence interval of 52 μmol/mol cr. This indicated that 13% of the workers were over the SafeWork NSW Biological Occupational Exposure Limit of 15 μmol/mol cr. Conclusions: Workers' exposure through inhalation was minimal; however, evidence from biological monitoring of MbOCA suggested that the main contributing factor to exposure was skin absorption. This was attributed to poor housekeeping and inadequate personal protection. Improvements in these areas were recommended, and it was also recommended to improve the awareness of the workers to the adverse effects to their health of exposure to this carcinogen. PMID:28320979

Occurrence and methods of control of chemical contaminants in foods.

PubMed

Jelinek, C

1981-06-01

Contamination of food by chemicals can result from their use on agricultural commodities; accidents or misuse during food handling and processing; nucler weapon testing and operation of nuclear power plants; and disposal of industrial chemicals or by-products with subsequent dispersal into the environment. The Food and Drug Administration (FDA), as the Federal agency mainly responsible for evaluating the hazards of chemical contaminants and enforcing any established tolerance levels for them in foods, has been monitoring pesticides, industrial chemicals, metals, and radionuclides in foods in its nationwide programs for many years. In addition, FDA searches for potential contaminants among the approximately 50,000 industrial chemicals manufactured in the United States and coordinates its efforts with those of other Federal and state agencies in these investigations. The overall results of the FDA surveillance and compliance programs for chemical contaminants in foods, as well as specific examples illustrating the wide range of incidents and types of occurrences, are presented.

Study of surfaces using near infrared optical fiber spectrometry

NASA Technical Reports Server (NTRS)

Workman, G. L.; Arendale, W. A.; Hughes, C.

1995-01-01

The measurement and control of cleanliness for critical surfaces during manufacturing and in service provides a unique challenge for fulfillment of environmentally benign operations. Of particular interest has been work performed in maintaining quality in the production of bondline surfaces in propulsion systems and the identification of possible contaminants. This work requires an in-depth study of the possible sources of contamination, methodologies to identify contaminants, discrimination between contaminants and chemical species caused by environment, and the effect of particular contaminants on the bondline integrity of the critical surfaces. This presentation will provide an introduction to the use of optical fiber spectrometry in a nondestructive measurement system for process monitoring and how it can be used to help clarify issues concerning surface chemistry. Correlation of the Near Infrared (NIR) spectroscopic results with Optical Stimulated Electron Emission (OSEE) and ellipsometry will also be presented.

Cleanrooms and tissue banking how happy I could be with either GMP or GTP?

PubMed

Klykens, J; Pirnay, J-P; Verbeken, G; Giet, O; Baudoux, E; Jashari, R; Vanderkelen, A; Ectors, N

2013-12-01

The regulatory framework of tissue banking introduces a number of requirements for monitoring cleanrooms for processing tissue or cell grafts. Although a number of requirements were clearly defined, some requirements are open for interpretation. This study aims to contribute to the interpretation of GMP or GTP guidelines for tissue banking. Based on the experience of the participating centers, the results of the monitoring program were evaluated to determine the feasibility of a cleanroom in tissue banking and the monitoring program. Also the microbial efficacy of a laminar airflow cabinet and an incubator in a cleanroom environment was evaluated. This study indicated that a monitoring program of a cleanroom at rest in combination with (final) product testing is a feasible approach. Although no statistical significance (0.90 < p < 0.95) was found there is a strong indication that a Grade D environment is not the ideal background environment for a Grade A obtained through a laminar airflow cabinet. The microbial contamination of an incubator in a cleanroom is limited but requires closed containers for tissue and cell products.

IDENTIFICATION OF SPECIES-ENVIRONMENT RELATIONSHIPS IN THE HUDSON-RARITAN ESTUARY AND RELATED SUB-BASINS

EPA Science Inventory

The US EP A's Regional Environmental Monitoring and Assessment Program (REMAP) conducted a study in 1993/94 to assess the effects of sediment contamination in the Hudson- Raritan area (Upper New York, Raritan Bay, Jamaica Bay, western Long Island Sound and the Bight Apex). This s...

Chemical-gene interaction networks and causal reasoning for biological effects prediction and prioritization of contaminants for environmental monitoring and surveillance

EPA Science Inventory

Evaluating the potential human health and ecological risks associated with exposures to complex chemical mixtures in the environment is one of the main challenges of chemical safety assessment and environmental protection. There is a need for approaches that can help to integrat...

Chemical-gene interaction networks and causal reasoning for biological effects prediction and prioritization of contaminants for environmental monitoring and surveillance (poster)

EPA Science Inventory

Product Description:Evaluation of the potential effects of complex mixtures of chemicals in the environment is challenged by the lack of extensive toxicity data for many chemicals. However, there are growing sources of online information that curate and compile literature reports...

Need and reasons for population control.

PubMed

Srivastava, P K

1995-02-01

The author posits that overpopulation is a problem that can be solved only with an understanding of the natural environment and its interactions with people. The formation of a national Indian planning commission for population control is viewed as necessary for motivating all people to reduce population size. More statistics are needed in India on environmental measures and population. Man is part of nature, but not a master of nature. Water-borne diseases occur after flooding and earthquakes and when the drinking water supply is contaminated. Weather forecasting would be useful in preventing these diseases. Construction sites are reservoirs of infectious diseases and affect the natural environment. Environmental conditions must be monitored. Monitoring of environmental sanitation will help in forecasting epidemics and in curbing the negative affects on human physical, mental, and social well-being. Man alters the environment through such activities as urbanization, industrialization, deforestation, construction of dams and irrigation channels, and use of pesticides and chemical fertilizers. New negative effects are occurring. Environmental degradation lowers economic status, which in turn contributes to poverty. Low income populations are more prone to crime, drug abuse, alcoholism, depression, and violence. The health status of an individual, community, or nation is a product of man's internal environment and the external natural environment, which can be physical, biological, and social. The biological environment includes viruses and disease producing agents, which struggle for their survival. The social environment includes customs, values, socioeconomic status, religion, standard of living, and political factors. Natural ecological regulation was suspended when man made technological advances. Scientific knowledge does not yet hold all the answers. Pollution is the result of progress in technology. Agricultural development has negative effects on the environment. Large population size contributes to the contamination of air, water, and agricultural areas. Demographic transition has been uneven in India.

Tracking pan-continental trends in environmental contamination using sentinel raptors-what types of samples should we use?

PubMed

Espín, S; García-Fernández, A J; Herzke, D; Shore, R F; van Hattum, B; Martínez-López, E; Coeurdassier, M; Eulaers, I; Fritsch, C; Gómez-Ramírez, P; Jaspers, V L B; Krone, O; Duke, G; Helander, B; Mateo, R; Movalli, P; Sonne, C; van den Brink, N W

2016-05-01

Biomonitoring using birds of prey as sentinel species has been mooted as a way to evaluate the success of European Union directives that are designed to protect people and the environment across Europe from industrial contaminants and pesticides. No such pan-European evaluation currently exists. Coordination of such large scale monitoring would require harmonisation across multiple countries of the types of samples collected and analysed-matrices vary in the ease with which they can be collected and the information they provide. We report the first ever pan-European assessment of which raptor samples are collected across Europe and review their suitability for biomonitoring. Currently, some 182 monitoring programmes across 33 European countries collect a variety of raptor samples, and we discuss the relative merits of each for monitoring current priority and emerging compounds. Of the matrices collected, blood and liver are used most extensively for quantifying trends in recent and longer-term contaminant exposure, respectively. These matrices are potentially the most effective for pan-European biomonitoring but are not so widely and frequently collected as others. We found that failed eggs and feathers are the most widely collected samples. Because of this ubiquity, they may provide the best opportunities for widescale biomonitoring, although neither is suitable for all compounds. We advocate piloting pan-European monitoring of selected priority compounds using these matrices and developing read-across approaches to accommodate any effects that trophic pathway and species differences in accumulation may have on our ability to track environmental trends in contaminants.

Strategies for monitoring the emerging polar organic contaminants in water with emphasis on integrative passive sampling.

PubMed

Söderström, Hanna; Lindberg, Richard H; Fick, Jerker

2009-01-16

Although polar organic contaminants (POCs) such as pharmaceuticals are considered as some of today's most emerging contaminants few of them are regulated or included in on-going monitoring programs. However, the growing concern among the public and researchers together with the new legislature within the European Union, the registration, evaluation and authorisation of chemicals (REACH) system will increase the future need of simple, low cost strategies for monitoring and risk assessment of POCs in aquatic environments. In this article, we overview the advantages and shortcomings of traditional and novel sampling techniques available for monitoring the emerging POCs in water. The benefits and drawbacks of using active and biological sampling were discussed and the principles of organic passive samplers (PS) presented. A detailed overview of type of polar organic PS available, and their classes of target compounds and field of applications were given, and the considerations involved in using them such as environmental effects and quality control were discussed. The usefulness of biological sampling of POCs in water was found to be limited. Polar organic PS was considered to be the only available, but nevertheless, an efficient alternative to active water sampling due to its simplicity, low cost, no need of power supply or maintenance, and the ability of collecting time-integrative samples with one sample collection. However, the polar organic PS need to be further developed before they can be used as standard in water quality monitoring programs.

Changing tides: Adaptive monitoring, assessment, and management of pharmaceutical hazards in the environment through time.

PubMed

Gaw, Sally; Brooks, Bryan W

2016-04-01

Pharmaceuticals are ubiquitous contaminants in aquatic ecosystems. Adaptive monitoring, assessment, and management programs will be required to reduce the environmental hazards of pharmaceuticals of concern. Potentially underappreciated factors that drive the environmental dose of pharmaceuticals include regulatory approvals, marketing campaigns, pharmaceutical subsidies and reimbursement schemes, and societal acceptance. Sales data for 5 common antidepressants (duloxetine [Cymbalta], escitalopram [Lexapro], venlafaxine [Effexor], bupropion [Wellbutrin], and sertraline [Zoloft]) in the United States from 2004 to 2008 were modeled to explore how environmental hazards in aquatic ecosystems changed after patents were obtained or expired. Therapeutic hazard ratios for Effexor and Lexapro did not exceed 1; however, the therapeutic hazard ratio for Zoloft declined whereas the therapeutic hazard ratio for Cymbalta increased as a function of patent protection and sale patterns. These changes in therapeutic hazard ratios highlight the importance of considering current and future drivers of pharmaceutical use when prioritizing pharmaceuticals for water quality monitoring programs. When urban systems receiving discharges of environmental contaminants are examined, water quality efforts should identify, prioritize, and select target analytes presently in commerce for effluent monitoring and surveillance. © 2015 SETAC.

A multidisciplinary approach to the study of cultural heritage environments: Experience at the Palatina Library in Parma.

PubMed

Pasquarella, C; Balocco, C; Pasquariello, G; Petrone, G; Saccani, E; Manotti, P; Ugolotti, M; Palla, F; Maggi, O; Albertini, R

2015-12-01

The aim of this paper is to describe a multidisciplinary approach including biological and particle monitoring, and microclimate analysis associated with the application of the Computational Fluid Dynamic (CFD). This approach was applied at the Palatina historical library in Parma. Monitoring was performed both in July and in December, in the absence of visitors and operators. Air microbial monitoring was performed with active and passive methods. Airborne particles with a diameter of ≥0.3, ≥0.5, ≥1 and ≥5 μm/m3, were counted by a laser particle counter. The surface contamination of shelves and manuscripts was assessed with nitrocellulose membranes. A spore trap sampler was used to identify both viable and non-viable fungal spores by optical microscope. Microbiological contaminants were analyzed through cultural and molecular biology techniques. Microclimatic parameters were also recorded. An infrared thermal camera provided information on the surface temperature of the different building materials, objects and components. Transient simulation models, for coupled heat and mass-moisture transfer, taking into account archivist and general public movements, combined with the related sensible and latent heat released into the environment, were carried out applying the CFD-FE (Finite Elements) method. Simulations of particle tracing were carried out. A wide variability in environmental microbial contamination, both for air and surfaces, was observed. Cladosporium spp., Alternaria spp., Aspergillus spp., and Penicillium spp. were the most frequently found microfungi. Bacteria such as Streptomyces spp., Bacillus spp., Sphingomonas spp., and Pseudoclavibacter as well as unculturable colonies were characterized by molecular investigation. CFD simulation results obtained were consistent with the experimental data on microclimatic conditions. The tracing and distribution of particles showed the different slice planes of diffusion mostly influenced by the convective airflow. This interdisciplinary research represents a contribution towards the definition of standardized methods for assessing the biological and microclimatic quality of indoor cultural heritage environments. Copyright © 2015 Elsevier B.V. All rights reserved.

Research Trends in Emerging Contaminants on the Aquatic Environments of Tanzania

PubMed Central

Miraji, H.; Othman, O. C.; Ngassapa, F. N.; Mureithi, E. W.

2016-01-01

The continuity for discovery and production of new chemicals, allied products, and uses has currently resulted into generation of recent form of contaminants known as Emerging Contaminants (ECs). Once in the aquatic environment ECs are carcinogenic and cause other threats to both human's and animals' health. Due to their effects this study was aimed at investigating research trends of ECs in Tanzania. Findings revealed that USA and EU countries were leading in ECs researches, little followed by Asia, South Africa, and then Zambia. Only few guidelines from USA-EPA, WHO, Canada, and Australia existed. Neither published guidelines nor regulations for ECs existed in Tanzania; rather only the occurrence of some disinfection by-products and antibiotics was, respectively, reported in Arusha and Dar es Salaam, Tanzania. As these reports had a limited coverage of ECs, henceforth, these findings constitute the first-line reference materials for ECs research in Tanzania which shall be useful for future monitoring and regulation planning. PMID:26998381

3D Inversion of Induced Polarization Data From Borehole Measurements to Map Subsurface Contaminations of Tetrachloroethylene and Trichloroethylene.

NASA Astrophysics Data System (ADS)

Briggs, V. A.; Sogade, J.; Minsley, B.; Lambert, M.; Coles, D.; Repert, P.; Morgan, F.; Rossabi, J.; Riha, B.

2003-12-01

The purpose of this study is to image contaminant plumes of tetrachloroethylene (PCE) and Trichloroethylene (TCE) in a subsurface environment. PCE and TCE have been used in the metals fabrication industry since the start of the second word war and subsequently millions of tons of these chemicals have been released in to the environment. Once in the water supply these contaminants are difficult to remove and can be toxic at the part per billion level. Remediation at the source of many of these contaminated sites, in the form of vapour extraction, can effectively remove alot of the chemicals but without techniques to delineate the size and shape of the contaminated zone, or to monitor the effectiveness of the remediation effort, it is difficult to quantify the remediation success. Using complex resistivity methods it is possible to determine the spatial extent and concentration of these chemicals due to their effect on the pore space chemistry. Even at parts per billion the contaminantas can significantly alter the IP signature enabling detection. Data were collected from a site in South Carolina where these chemcals are known to have been released in large quantities from the 1950's through to the 1980's. Induced Polarization data were measured in a multi-borehole environment to ensure good data coverage. Data is inverted using a 3D finite difference bi-conjugate gradient method and correlated to ground truth boreholes within the region of interest.

2004 Environmental Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Althouse, P E; Bertoldo, N A; Brown, R A

2005-09-28

The Lawrence Livermore National Laboratory (LLNL) annual Environmental Report, prepared for the Department of Energy (DOE) and made available to the public, presents summary environmental data that characterizes site environmental management performance, summarizes environmental occurrences and responses reported during the calendar year, confirms compliance with environmental standards and requirements, and highlights significant programs and efforts. By explaining the results of effluent and environmental monitoring, mentioning environmental performance indicators and performance measure programs, and assessing the impact of Laboratory operations on the environment and the public, the report also demonstrates LLNL's continuing commitment to minimize any potentially adverse impact of itsmore » operations. The combination of environmental and effluent monitoring, source characterization, and dose assessment showed that radiological doses to the public caused by LLNL operations in 2004 were less than 0.26% of regulatory standards and more than 11,000 times smaller than dose from natural background. Analytical results and evaluations generally showed continuing low levels of most contaminants; remediation efforts further reduced the concentrations of contaminants of concern in groundwater and soil vapor. In addition, LLNL's extensive environmental compliance activities related to water, air, endangered species, waste, wastewater, and waste reduction controlled or reduced LLNL's effects on the environment. LLNL's environmental program clearly demonstrates a commitment to protecting the environment from operational impacts.« less

Master environmental plan for Fort Devens, Massachusetts

DOE Office of Scientific and Technical Information (OSTI.GOV)

Biang, C.A.; Peters, R.W.; Pearl, R.H.

Argonne National Laboratory has prepared a master environmental plan (MEP) for Fort Devens, Massachusetts, for the US Army Toxic and Hazardous Materials Agency. The MEP is an assessment based on environmental laws and regulations of both the federal government and the Commonwealth of Massachusetts. The MEP assess the physical and environmental status of 58 potential hazardous waste sites, including 54 study areas (SAs) that pose a potential for releasing contamination into the environment and 4 areas of concern (AOCs) that are known to have substantial contamination. For each SA or AOC, this MEP describes the known history and environment, identifiesmore » additional data needs, and proposes possible response actions. Most recommended response actions consist of environmental sampling and monitoring and other characterization studies. 74 refs., 63 figs., 50 tabs.« less

Microplastic Exposure Assessment in Aquatic Environments: Learning from Similarities and Differences to Engineered Nanoparticles.

PubMed

Hüffer, Thorsten; Praetorius, Antonia; Wagner, Stephan; von der Kammer, Frank; Hofmann, Thilo

2017-03-07

Microplastics (MPs) have been identified as contaminants of emerging concern in aquatic environments and research into their behavior and fate has been sharply increasing in recent years. Nevertheless, significant gaps remain in our understanding of several crucial aspects of MP exposure and risk assessment, including the quantification of emissions, dominant fate processes, types of analytical tools required for characterization and monitoring, and adequate laboratory protocols for analysis and hazard testing. This Feature aims at identifying transferrable knowledge and experience from engineered nanoparticle (ENP) exposure assessment. This is achieved by comparing ENP and MPs based on their similarities as particulate contaminants, whereas critically discussing specific differences. We also highlight the most pressing research priorities to support an efficient development of tools and methods for MPs environmental risk assessment.

Mercury in tropical and subtropical coastal environments

PubMed Central

Costa, Monica F.; Landing, William M.; Kehrig, Helena A.; Barletta, Mário; Holmes, Christopher D.; Barrocas, Paulo R. G.; Evers, David C.; Buck, David G.; Vasconcellos, Ana Claudia; Hacon, Sandra S.; Moreira, Josino C.; Malm, Olaf

2012-01-01

Anthropogenic activities influence the biogeochemical cycles of mercury, both qualitatively and quantitatively, on a global scale from sources to sinks. Anthropogenic processes that alter the temporal and spatial patterns of sources and cycling processes are changing the impacts of mercury contamination on aquatic biota and humans. Human exposure to mercury is dominated by the consumption of fish and products from aquaculture operations. The risk to society and to ecosystems from mercury contamination is growing, and it is important to monitor these expanding risks. However, the extent and manner to which anthropogenic activities will alter mercury sources and biogeochemical cycling in tropical and sub-tropical coastal environments is poorly understood. Factors as (1) lack of reliable local/regional data; (2) rapidly changing environmental conditions; (3) governmental priorities and; (4) technical actions from supra-national institutions, are some of the obstacles to overcome in mercury cycling research and policy formulation. In the tropics and sub-tropics, research on mercury in the environment is moving from an exploratory “inventory” phase towards more process-oriented studies. Addressing biodiversity conservation and human health issues related to mercury contamination of river basins and tropical coastal environments are an integral part of paragraph 221 paragraph of the United Nations document “The Future We Want” issued in Rio de Janeiro in June 2012. PMID:22901765

Monitoring coastal marine waters for spore-forming bacteria of faecal and soil origin to determine point from non-point source pollution.

PubMed

Fujioka, R S

2001-01-01

The US Environmental Protection Agency (USEPA) and the World Health Organization (WHO) have established recreational water quality standards limiting the concentrations of faecal indicator bacteria (faecal coliform, E. coli, enterococci) to ensure that these waters are safe for swimming. In the application of these hygienic water quality standards, it is assumed that there are no significant environmental sources of these faecal indicator bacteria which are unrelated to direct faecal contamination. However, we previously reported that these faecal indicator bacteria are able to grow in the soil environment of humid tropical island environments such as Hawaii and Guam and are transported at high concentrations into streams and storm drains by rain. Thus, streams and storm drains in Hawaii contain consistently high concentrations of faecal indicator bacteria which routinely exceed the EPA and WHO recreational water quality standards. Since, streams and storm drains eventually flow out to coastal marine waters, we hypothesize that all the coastal beaches which receive run-off from streams and storm drains will contain elevated concentrations of faecal indicator bacteria. To test this hypothesis, we monitored the coastal waters at four beaches known to receive water from stream or storm drains for salinity, turbidity, and used the two faecal indicator bacteria (E. coli, enterococci) to establish recreational water quality standards. To determine if these coastal waters are contaminated with non-point source pollution (streams) or with point source pollution (sewage effluent), these same water samples were also assayed for spore-forming bacteria of faecal origin (Cl. perfringens) and of soil origin (Bacillus species). Using this monitoring strategy it was possible to determine when coastal marine waters were contaminated with non-point source pollution and when coastal waters were contaminated with point source pollution. The results of this study are most likely applicable to all countries in the warm and humid region of the world.

Monitoring of the impact of Prestige oil spill on Mytilus galloprovincialis from Galician coast.

PubMed

Laffon, Blanca; Rábade, Tamara; Pásaro, Eduardo; Méndez, Josefina

2006-04-01

In November 2002, the Prestige oil tanker was wrecked in front of Galician coast (NW of Spain), spilling near 63,000 tons of heavy oil until February 2003. Contamination produced was very extensive (70% of Galician beaches were reached by the oil) but heterogeneous, alternating intensely affected zones with neighbour locations where the repercussion was minimal. The objective of this study was to monitor sea environment contamination caused by Prestige oil spill during an 11-month period (August 2003-June 2004, nine samplings) in two locations of Galician coast with different geographical properties (Lira and Ancoradoiro beaches), by means of chemical determination of total polycyclic aromatic hydrocarbons (TPAH) in seawater, and using as exposure biomarker TPAH content in mussel (Mytilus galloprovincialis) tissues, and as effect biomarker DNA damage in mussel gills, evaluated by the comet assay. In addition, recovery ability of the mussels was determined after a 7-day stay in the laboratory. TPAH contents in seawater were very high in the earliest samplings, but then they maintained below 200 ng L(-)(1), similar to reference seawater. However, TPAH levels in mussel tissues were more variable: they increased again from January 2004, probably due to the adverse meteorological conditions that turned over the sea bottom and dispersed the oil accumulated in sediments. In most samplings, these levels decreased during the recovery stage. DNA damage in oil-exposed mussels was significantly higher than in reference mussels, both before and after the recovery phase, but they did not differ to one another. Comet tail length was slightly reduced during the recovery stage, indicative of a certain DNA repair in exposed mussels. This study showed up the importance of monitoring sea contamination events during an extended time, not only in evaluating the presence of the contaminants in the environment but also in determining their bioaccumulation and their effect on the exposed organisms.

Five-year microbiological monitoring of wards and operating theatres in southern Italy.

PubMed

La Fauci, V; Genovese, C; Facciolà, A; Palamara, M A R; Squeri, R

2017-06-01

Nosocomial infections are one of the greatest problems in public health. Several studies have highlighted the role played by the hospital environment as a possible source of transmission of nosocomial pathogens. A five-year monitoring of bacterial contamination on healthcare workers hands, surfaces most closely in contact with inpatient wards, operating theatres and "at rest" and "in use" operating theatre air samples. For the samples, we used sterile swabs, contact slides, manual API, and automated VITEK systems for identification. In the five-year period, a total of 9396 samples were collected and analysed. In ward patients, 4398 samplings were carried out with 4.7%, 9.4%, 7%, 10.8% and 7.9% positive results respectively from 2010 to 2014. For hands, 648 samplings were carried out, with a positivity of 40.74%. In operating theatres, 4188 samples were taken, with a positivity of 11.9%. Regarding air in empty and full theatres, 1962 samplings were carried out with a positivity rate equal to 31.9%. The monitoring showed a low rate of contamination with a progressive decrease in the fiveyear period on operating theatres surfaces and hands, while there was an increase in the surgical site wards and in the air of operating rooms. Our investigation has revealed the presence of pathogens on the assessed surfaces and the need for environmental monitoring, which can be a valuable tool for reducing contamination.

Monitoring psychrotrophic lactic acid bacteria contamination in a ready-to-eat vegetable salad production environment.

PubMed

Pothakos, Vasileios; Snauwaert, Cindy; De Vos, Paul; Huys, Geert; Devlieghere, Frank

2014-08-18

A study monitoring lactic acid bacteria contamination was conducted in a company producing fresh, minimally processed, packaged and ready-to-eat (RTE) vegetable salads (stored at 4°C) in order to investigate the reason for high psychrotrophic LAB levels in the products at the end of shelf-life. Initially, high microbial counts exceeding the established psychrotrophic thresholds (>10(7)-10(8)CFU/g) and spoilage manifestations before the end of the shelf-life (7days) occurred in products containing an assortment of sliced and diced vegetables, but within a one year period these spoilage defects became prevalent in the entire processing plant. Environmental sampling and microbiological analyses of the raw materials and final products throughout the manufacturing process highlighted the presence of high numbers of Leuconostoc spp. in halved and unseeded, fresh sweet bell peppers provided by the supplier. A combination of two DNA fingerprinting techniques facilitated the assessment of the species diversity of LAB present in the processing environment along with the critical point of their introduction in the production facility. Probably through air mediation and surface adhesion, mainly members of the strictly psychrotrophic species Leuconostoc gelidum subsp. gasicomitatum and L. gelidum subsp. gelidum were responsible for the cross-contamination of every vegetable handled within the plant. Copyright © 2014 Elsevier B.V. All rights reserved.

Environmental Impacts and Recovery After the Hebei Spirit Oil Spill in Korea.

PubMed

Yim, U H; Khim, J S; Kim, M; Jung, J-H; Shim, W J

2017-07-01

The Hebei Spirit oil spill (HSOS) on December 7, 2007 was the worst oil spill recorded in Korea, with the release of approximately 10,900 tons of crude oil and 375 km of coastline polluted along the west coast of Korea. Cleanup operation was conducted by official and contract responders as well as volunteers for massive oil containment and removal of heavy accumulations of stranded oil. Together with the oil cleanup, a long-term environmental impact assessment (EIA) of the HSOS was initiated based on the Marine Environmental Management Act, which covers oil contamination in a multimedia environment, toxic effects on organisms, and ecosystem injury. This review summarizes the long-term monitoring results of HSOS EIA focused on (1) pollution status of seawater, sediment, and bivalves, (2) ecotoxicological effects, and (3) ecosystem recovery. Overall, concentrations of petroleum hydrocarbons in the environment indicated that their concentrations were well down to at or near background or pre-spill contamination levels at most sites after 1 year. The potential toxic effects of residual oils in sediments have decreased to background levels in most coastal areas of Taean. The entire ecosystem in the most affected area of the Taean coasts appear to be considerably, but not fully, recovered at present, namely after 8 years of the HSOS. The presence of lingering oil and elevated contamination levels at several sites still require continuous long-term monitoring.

Salmon Site Remedial Investigation Report, Exhibit 5

DOE Office of Scientific and Technical Information (OSTI.GOV)

USDOE /NV

1999-09-01

This Salmon Site Remedial Investigation Report provides the results of activities initiated by the U.S. Department of Energy (DOE) to determine if contamination at the Salmon Site poses a current or future risk to human health and the environment. These results were used to develop and evaluate a range of risk-based remedial alternatives. Located in Lamar County, Mississippi, the Salmon Site was used by the U.S. Atomic Energy Commission (predecessor to the DOE) between 1964 and 1970 for two nuclear and two gas explosions conducted deep underground in a salt dome. The testing resulted in the release of radionuclides intomore » the salt dome. During reentry drilling and other site activities, liquid and solid wastes containing radioactivity were generated resulting in surface soil and groundwater contamination. Most of the waste and contaminated soil and water were disposed of in 1993 during site restoration either in the cavities left by the tests or in an injection well. Other radioactive wastes were transported to the Nevada Test Site for disposal. Nonradioactive wastes were disposed of in pits at the site and capped with clean soil and graded. The preliminary investigation showed residual contamination in the Surface Ground Zero mud pits below the water table. Remedial investigations results concluded the contaminant concentrations detected present no significant risk to existing and/or future land users, if surface institutional controls and subsurface restrictions are maintained. Recent sampling results determined no significant contamination in the surface or shallow subsurface. The test cavity resulting from the experiments is contaminated and cannot be economically remediated with existing technologies. The ecological sampling did not detect biological uptake of contaminants in the plants or animals sampled. Based on the current use of the Salmon Site, the following remedial actions were identified to protect both human health and the environment: (1) the installation of a water supply system that will provide potable water to the site and residence in the proximity to the site; (2) continued maintenance of surface institutional controls and subsurface restrictions; and (3) continue to implement the long-term hydrologic monitoring program. The Salmon Site will be relinquished the State of Mississippi as mandated by Public Law 104-201-September 23, 1996, to be used as a demonstration forest/wildlife refuge. Should the land use change in the future and/or monitoring information indicates a change in the site conditions, the DOE will reassess the risk impacts to human health and the environment.« less

Salmon Site Remedial Investigation Report, Main Body

DOE Office of Scientific and Technical Information (OSTI.GOV)

US DOE /NV

1999-09-01

This Salmon Site Remedial Investigation Report provides the results of activities initiated by the U.S. Department of Energy (DOE) to determine if contamination at the Salmon Site poses a current or future risk to human health and the environment. These results were used to develop and evaluate a range of risk-based remedial alternatives. Located in Lamar County, Mississippi, the Salmon Site was used by the U.S. Atomic Energy Commission (predecessor to the DOE) between 1964 and 1970 for two nuclear and two gas explosions conducted deep underground in a salt dome. The testing resulted in the release of radionuclides intomore » the salt dome. During reentry drilling and other site activities, liquid and solid wastes containing radioactivity were generated resulting in surface soil and groundwater contamination. Most of the waste and contaminated soil and water were disposed of in 1993 during site restoration either in the cavities left by the tests or in an injection well. Other radioactive wastes were transported to the Nevada Test Site for disposal. Nonradioactive wastes were disposed of in pits at the site and capped with clean soil and graded. The preliminary investigation showed residual contamination in the Surface Ground Zero mud pits below the water table. Remedial investigations results concluded the contaminant concentrations detected present no significant risk to existing and/or future land users, if surface institutional controls and subsurface restrictions are maintained. Recent sampling results determined no significant contamination in the surface or shallow subsurface. The test cavity resulting from the experiments is contaminated and cannot be economically remediated with existing technologies. The ecological sampling did not detect biological uptake of contaminants in the plants or animals sampled. Based on the current use of the Salmon Site, the following remedial actions were identified to protect both human health and the environment: (1) the installation of a water supply system that will provide potable water to the site and residence in the proximity to the site; (2) continued maintenance of surface institutional controls and subsurface restrictions; and (3) continue to implement the long-term hydrologic monitoring program. The Salmon Site will be relinquished the State of Mississippi as mandated by Public Law 104-201-September 23, 1996, to be used as a demonstration forest/wildlife refuge. Should the land use change in the future and/or monitoring information indicates a change in the site conditions, the DOE will reassess the risk impacts to human health and the environment.« less

Salmon Site Remedial Investigation Report, Exhibit 2

DOE Office of Scientific and Technical Information (OSTI.GOV)

USDOE NV

1999-09-01

This Salmon Site Remedial Investigation Report provides the results of activities initiated by the U.S. Department of Energy (DOE) to determine if contamination at the Salmon Site poses a current or future risk to human health and the environment. These results were used to develop and evaluate a range of risk-based remedial alternatives. Located in Lamar County, Mississippi, the Salmon Site was used by the U.S. Atomic Energy Commission (predecessor to the DOE) between 1964 and 1970 for two nuclear and two gas explosions conducted deep underground in a salt dome. The testing resulted in the release of radionuclides intomore » the salt dome. During reentry drilling and other site activities, liquid and solid wastes containing radioactivity were generated resulting in surface soil and groundwater contamination. Most of the waste and contaminated soil and water were disposed of in 1993 during site restoration either in the cavities left by the tests or in an injection well. Other radioactive wastes were transported to the Nevada Test Site for disposal. Nonradioactive wastes were disposed of in pits at the site and capped with clean soil and graded. The preliminary investigation showed residual contamination in the Surface Ground Zero mud pits below the water table. Remedial investigations results concluded the contaminant concentrations detected present no significant risk to existing and/or future land users, if surface institutional controls and subsurface restrictions are maintained. Recent sampling results determined no significant contamination in the surface or shallow subsurface. The test cavity resulting from the experiments is contaminated and cannot be economically remediated with existing technologies. The ecological sampling did not detect biological uptake of contaminants in the plants or animals sampled. Based on the current use of the Salmon Site, the following remedial actions were identified to protect both human health and the environment: (1) the installation of a water supply system that will provide potable water to the site and residence in the proximity to the site; (2) continued maintenance of surface institutional controls and subsurface restrictions; and (3) continue to implement the long-term hydrologic monitoring program. The Salmon Site will be relinquished the State of Mississippi as mandated by Public Law 104-201-September 23, 1996, to be used as a demonstration forest/wildlife refuge. Should the land use change in the future and/or monitoring information indicates a change in the site conditions, the DOE will reassess the risk impacts to human health and the environment.« less

High sensitivity real-time NVR monitor

NASA Technical Reports Server (NTRS)

Bowers, William D. (Inventor); Chuan, Raymond L. (Inventor)

1997-01-01

A real time non-volatile residue (NVR) monitor, which utilizes surface acoustic wave (SAW) resonators to detect molecular contamination in a given environment. The SAW resonators operate at a resonant frequency of approximately 200 MHz-2,000 MHz which enables the NVR monitor to detect molecular contamination on the order of 10.sup.-11 g-cm.sup.-2 to 10.sup.-13 g-cm.sup.2. The NVR monitor utilizes active temperature control of (SAW) resonators to achieve a stable resonant frequency. The temperature control system of the NVR monitor is able to directly heat and cool the SAW resonators utilizing a thermoelectric element to maintain the resonators at a present temperature independent of the environmental conditions. In order to enable the direct heating and cooling of the SAW resonators, the SAW resonators are operatively mounted to a heat sink. In one embodiment, the heat sink is located in between the SAW resonators and an electronic circuit board which contains at least a portion of the SAW control electronics. The electrical leads of the SAW resonators are connected through the heat sink to the circuit board via an electronic path which prevents inaccurate frequency measurement.

Seabird tissue archival and monitoring project: Protocol for collecting and banking seabird eggs

USGS Publications Warehouse

Weston-York, Geoff; Porter, Barbara J.; Pugh, Rebecca S.; Roseneau, David G.; Simac, Kristin S.; Becker, Paul R.; Thorsteinson, Lyman K.; Wise, Stephen A.

2001-01-01

Archiving biological and environmental samples for retrospective analysis is a major component of systematic environmental monitoring. The long-term storage of carefully selected, representative samples in an environmental specimen bank is an important complement to the real-time monitoring of the environment. These archived samples permit:The use of subsequently developed innovative analytical technology that was not available at the time the samples were archived, for clear state-of-art identification an~ quantification of analytes of interest,The identification and quantification of analytes that are of subsequent interest but that were not of interest at the time the samples were archived, andThe comparison of present and past analytical techniques and values, providing continued credibility of past analytical values, and allowing flexibility in environmental monitoring programs.Seabirds, including albatrosses, pelicans, cormorants, terns, kittiwakes, murres, guillemots, and puffins spend most of their lives at sea and have special adaptations for feeding in the marine environment, including the ability to excrete the excess salt obtained from ingesting seawater. Many species nest in dense groups (colonies) on steep, precipitous sea-cliffs and headlands.Seabirds are long-lived and slow to mature. They occupy high positions in the marine food web and are considered sensitive indicators for the marine environment (prey includes krill, small fish, and squid). Breeding success, timing of nesting, diets, and survival rates may provide early indications of changing environmental conditions (e.g., see Hatch et aI., 1993). Chemical analysis of seabird tissues, including egg contents, can be particularly useful in determining whether contaminants (and potential biological effects) associated with human industrial activities, such as offshore petroleum and mineral exploration and development, are accumulating in marine environments. The collection and archival of seabird tissues over a period of several years will be a resource for future analyses, providing samples that can be used to determine historical baseline contaminant levels.

Demolition and removal of radioactively contaminated concrete soil: Aerosol control and monitoring

DOE Office of Scientific and Technical Information (OSTI.GOV)

Newton, G.J.; Hoover, M.D.; Grace, A.C. III

1995-12-01

From 1963 to 1985, two concrete-lined ponds were used to reduce the volume of radioactive liquids from the Institute`s research programs. Following withdrawal of the {open_quotes}hot ponds{close_quotes} from active use, the residual sludges and plastic liners of the ponds were removed and shipped to a radioactive waste disposal site. From 1987 to 1994, the concrete structures remained undisturbed pending environmental restoration on the site. Restoration began in 1994 and was completed in 1995. Restoration involved mechanical breakup and removal of the concrete structures and removal of areas of contaminated soils from the site. This report describes the design and resultsmore » of the aerosol control and monitoring program that was conducted to ensure protection of workers and the environment during the restoration process. The aerosol control and monitoring strategy developed for remediation of the ITRI hot ponds was successful both in preventing dispersion of radioactive dusts and in demonstrating that exposures of workers and offsite releases were within statutory limits.« less

May 2011 Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site (Data Validation Package)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hutton, Rick

2011-12-01

Annual sampling was conducted at the Rio Blanco, Colorado, site for the Long-Term Hydrologic Monitoring Program May 16-17, 2011, to monitor groundwater and surface water for potential radionuclide contamination. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location Johnson Artesian WL. Samples were analyzed by the U.S. Environmental Protection Agency (EPA) Radiation&Indoor Environments National Laboratory in Las Vegas, Nevada. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry, and for tritium using the conventional method.more » Tritium was not measured using the enrichment method because the EPA laboratory no longer offers that service. Results of this monitoring at the Rio Blanco site demonstrate that groundwater and surface water outside the boundaries have not been affected by project-related contaminants.« less

Presentations from the Fourth Unregulated Contaminant Monitoring Rule (UCMR 4) Methods Stakeholder Meeting on May 15, 2013

EPA Pesticide Factsheets

This document contains the presentations from the Unregulated Contaminant Monitoring Rule 4 Methods Stakeholder Meeting held on May 15, 2013 about the Contaminant Candidate List (CCL) and the Unregulated Contaminant Monitoring Rule.

Application of stable isotope ratio analysis for biodegradation monitoring in groundwater

USGS Publications Warehouse

Hatzinger, Paul B.; Böhlke, John Karl; Sturchio, Neil C.

2013-01-01

Stable isotope ratio analysis is increasingly being applied as a tool to detect, understand, and quantify biodegradation of organic and inorganic contaminants in groundwater. An important feature of this approach is that it allows degradative losses of contaminants to be distinguished from those caused by non-destructive processes such as dilution, dispersion, and sorption. Recent advances in analytical techniques, and new approaches for interpreting stable isotope data, have expanded the utility of this method while also exposing complications and ambiguities that must be considered in data interpretations. Isotopic analyses of multiple elements in a compound, and multiple compounds in the environment, are being used to distinguish biodegradative pathways by their characteristic isotope effects. Numerical models of contaminant transport, degradation pathways, and isotopic composition are improving quantitative estimates of in situ contaminant degradation rates under realistic environmental conditions.

[Correlation of bacteria in the contaminated drug and the environmental microbes in the clean room for pharmaceutical microbial test investigated by FTIR].

PubMed

Pei, Lin; Hu, Chang-qin; Ma, Shi-hong; Dai, Hui; Hang, Tai-jun

2007-11-01

The FTIR method was used to investigate the correlation of bacteria in the contaminated drug and the environmental microbes in the clean room for pharmaceutical microbial test. The similarity of bacteria in the contaminated drug and environmental microbes was compared by critical hit value method and cluster analysis method. This constructed the FTIR spectra library of clean room environmental microbe, and determined the criterion to promptly judge if the bacteria isolated from pharmaceuticals were contaminated by environment or not, hence the exactness of "one-off report" of sterile test result can be guaranteed, and can be used for the dynamic monitoring of environmental bacteria of clean room. The method is proven to be simple, accurate and rapid, and can be easily spread to the pharmaceutical microbial control.

Fourth Annual Workshop on Space Operations Applications and Research (SOAR 90)

NASA Technical Reports Server (NTRS)

Savely, Robert T. (Editor)

1991-01-01

The papers from the symposium are presented. Emphasis is placed on human factors engineering and space environment interactions. The technical areas covered in the human factors section include: satellite monitoring and control, man-computer interfaces, expert systems, AI/robotics interfaces, crew system dynamics, and display devices. The space environment interactions section presents the following topics: space plasma interaction, spacecraft contamination, space debris, and atomic oxygen interaction with materials. Some of the above topics are discussed in relation to the space station and space shuttle.

Electrosurgical Smoke: Ultrafine Particle Measurements and Work Environment Quality in Different Operating Theatres

PubMed Central

Romano, Francesco; Gustén, Jan; De Antonellis, Stefano; Joppolo, Cesare M.

2017-01-01

Air cleanliness in operating theatres (OTs) is an important factor for preserving the health of both the patient and the medical staff. Particle contamination in OTs depends mainly on the surgery process, ventilation principle, personnel clothing systems and working routines. In many open surgical operations, electrosurgical tools (ESTs) are used for tissue cauterization. ESTs generate a significant airborne contamination, as surgical smoke. Surgical smoke is a work environment quality problem. Ordinary surgical masks and OT ventilation systems are inadequate to control this problem. This research work is based on numerous monitoring campaigns of ultrafine particle concentrations in OTs, equipped with upward displacement ventilation or with a downward unidirectional airflow system. Measurements performed during ten real surgeries highlight that the use of ESTs generates a quite sharp and relevant increase of particle concentration in the surgical area as well within the entire OT area. The measured contamination level in the OTs are linked to surgical operation, ventilation principle, and ESTs used. A better knowledge of airborne contamination is crucial for limiting the personnel’s exposure to surgical smoke. Research results highlight that downward unidirectional OTs can give better conditions for adequate ventilation and contaminant removal performances than OTs equipped with upward displacement ventilation systems. PMID:28146089

PLANTS AS BIO-MONITORS FOR 137CS, 238PU, 239, 240PU AND 40K AT THE SAVANNAH RIVER SITE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Caldwell, E.; Duff, M.; Ferguson, C.

2010-12-16

The nuclear fuel cycle generates a considerable amount of radioactive waste, which often includes nuclear fission products, such as strontium-90 ({sup 90}Sr) and cesium-137 ({sup 137}Cs), and actinides such as uranium (U) and plutonium (Pu). When released into the environment, large quantities of these radionuclides can present considerable problems to man and biota due to their radioactive nature and, in some cases as with the actinides, their chemical toxicity. Radionuclides are expected to decay at a known rate. Yet, research has shown the rate of elimination from an ecosystem to differ from the decay rate due to physical, chemical andmore » biological processes that remove the contaminant or reduce its biological availability. Knowledge regarding the rate by which a contaminant is eliminated from an ecosystem (ecological half-life) is important for evaluating the duration and potential severity of risk. To better understand a contaminants impact on an environment, consideration should be given to plants. As primary producers, they represent an important mode of contamination transfer from sediments and soils into the food chain. Contaminants that are chemically and/or physically sequestered in a media are less likely to be bio-available to plants and therefore an ecosystem.« less

Scientific advances provide opportunities to improve pediatric environmental health

USGS Publications Warehouse

Reddy, Michael M.; Reddy, Micaela B.; Reddy, Carol F.

2004-01-01

The health consequences of contaminants in the environment, with respect to the health of children and infants, recently have been dramatically brought to public attention by the motion pictures Erin Brockovich and A Civil Action. These productions focused public attention on the potential link between water contaminants and pediatric health, a continuing subject of public concern. As a consequence of the increasing production of new commercial chemicals, many chemicals have appeared in the scientific and public awareness as potential threats to health. These new or novel compounds eventually distribute in the environment and often are termed emerging contaminants. Gitterman and Bearer stated, "Children may serve as unwitting sentinels for society; they are often the youngest exposed to many environmental toxicants and may become the youngest in age to manifest adverse responses." The discipline of pediatric environmental health is still in its adolescence, but it will be increasingly important as new chemicals are generated and as more is learned about the health effects of chemicals already in commerce. Here, we provide an overview of recent advances in biomonitoring and environmental monitoring of environmental contaminants including emerging contaminants. Our purpose in writing this commentary is to make pediatricians aware of the current resources available for learning about pediatric environmental health and of ongoing research initiatives that provide opportunities to improve pediatric environmental health.

Microplate freeze-dried cyanobacterial bioassay for fresh-waters environmental monitoring.

PubMed

Martín-Betancor, Keila; Durand, Marie-José; Thouand, Gérald; Leganés, Francisco; Fernández-Piñas, Francisca; Rodea-Palomares, Ismael

2017-12-01

Microorganisms have been very useful in environmental monitoring due to their constant sensing of the surrounding environment, their easy maintenance and low cost. Some freeze-dried toxicity kits based on naturally bioluminescent bacteria are commercially available and commonly used to assess the toxicity of environmental samples such as Microtox (Aliivibrio fischeri) or ToxScreen (Photobacterium leiognathi), however, due to the marine origin of these bacteria, they could not be the most appropriate for fresh-waters monitoring. Cyanobacteria are one of the most representative microorganisms of aquatic environments, and are well suited for detecting contaminants in aqueous samples. This study presents the development and application of the first freeze-dried cyanobacterial bioassay for fresh-water contaminants detection. The effects of different cell growth phases, cryoprotectant solutions, freezing protocols, rehydration solutions and incubation conditions methods were evaluated and the best combination of these parameters for freeze-drying was selected. The study includes detailed characterization of sensitivity towards reference pollutants, as well as, comparison with the standard assays. Moreover, long-term viability and sensitivity were evaluated after 3 years of storage. Freeze-dried cyanobacteria showed, in general, higher sensitivity than the standard assays and viability of the cells remained after 3 years of storage. Finally, the validation of the bioassay using a wastewater sample was also evaluated. Freeze-drying of cyanobacteria in 96-well plates presents a simple, fast and multi-assay method for environmental monitoring. Copyright © 2017 Elsevier Ltd. All rights reserved.

Strontium-90 at the Hanford Site and its ecological implications

DOE Office of Scientific and Technical Information (OSTI.GOV)

RE Peterson; TM Poston

2000-05-22

Strontium-90, a radioactive contaminant from historical operations at the U.S. Department of Energy (DOE) Hanford Site, enters the Columbia River at several locations associated with former plutonium production reactors at the Site. Strontium-90 is of concern to humans and the environment because of its moderately long half-life (29.1 years), its potential for concentrating in bone tissue, and its relatively high energy of beta decay. Although strontium-90 in the environment is not a new issue for the Hanford Site, recent studies of near-river vegetation along the shoreline near the 100 Areas raised public concern about the possibility of strontium-90-contaminated groundwater reachingmore » the riverbed and fall chinook salmon redds. To address these concerns, DOE asked Pacific Northwest National Laboratory (PNNL) to prepare this report on strontium-90, its distribution in groundwater, how and where it enters the river, and its potential ecological impacts, particularly with respect to fall chinook salmon. The purpose of the report is to characterize groundwater contaminants in the near-shore environment and to assess the potential for ecological impact using salmon embryos, one of the most sensitive ecological indicators for aquatic organisms. Section 2.0 of the report provides background information on strontium-90 at the Hanford Site related to historical operations. Public access to information on strontium-90 also is described. Section 3.0 focuses on key issues associated with strontium-90 contamination in groundwater that discharges in the Hanford Reach. The occurrence and distribution of fall chinook salmon redds in the Hanford Reach and characteristics of salmon spawning are described in Section 4.0. Section 5.0 describes the regulatory standards and criteria used to set action levels for strontium-90. Recommendations for initiating additional monitoring and remedial action associated with strontium-90 contamination at the Hanford Site are presented in Section 6.0. Appendix A describes monitoring methods. Appendix B discusses uncertainties associated with plume characterizations, and Appendix C provides an overview of studies on fish immuno-suppression and exposure to tritium.« less

MERCURY IN MARINE LIFE DATABASE | Science Inventory ...

EPA Pesticide Factsheets

The purpose of the Mercury in Marine Life Project is to organize information on estuarine and marine species so that EPA can better understand both the extent of monitoring for mercury and level of mercury contamination in the biota of coastal environments. This report follows a similar report commissioned by the Gulf of Mexico Program (GMP), entitled

Comprehensive analysis of airborne contaminants from recent Spacelab missions

NASA Technical Reports Server (NTRS)

Matney, M. L.; Boyd, J. F.; Covington, P. A.; Leano, H. J.; Pierson, D. L.; Limero, T. F.; James, J. T.

1993-01-01

The Shuttle experiences unique air contamination problems because of microgravity and the closed environment. Contaminant build-up in the closed atmosphere and the lack of a gravitational settling mechanism have produced some concern in previous missions about the amount of solid and volatile airborne contaminants in the Orbiter and Spacelab. Degradation of air quality in the Orbiter/Spacelab environment, through processes such as chemical contamination, high solid-particulate levels, and high microbial levels, may affect crew performance and health. A comprehensive assessment of the Shuttle air quality was undertaken during STS-40 and STS-42 missions, in which a variety of air sampling and monitoring techniques were employed to determine the contaminant load by characterizing and quantitating airborne contaminants. Data were collected on the airborne concentrations of volatile organic compounds, microorganisms, and particulate matter collected on Orbiter/Spacelab air filters. The results showed that STS-40/42 Orbiter/Spacelab air was toxicologically safe to breathe, except during STS-40 when the Orbiter Refrigerator/Freezer unit was releasing noxious gases in the middeck. On STS-40, the levels of airborne bacteria appeared to increase as the mission progressed; however, this trend was not observed for the STS-42 mission. Particulate matter in the Orbiter/Spacelab air filters was chemically analyzed in order to determine the source of particles. Only small amounts of rat hair and food bar (STS-40) and traces of soiless medium (STS-42) were detected in the Spacelab air filters, indicating that containment for Spacelab experiments was effective.

Natural attenuation is enhanced in previously contaminated and coniferous forest soils.

PubMed

Kauppi, Sari; Romantschuk, Martin; Strömmer, Rauni; Sinkkonen, Aki

2012-01-01

Prevalence of organic pollutants or their natural analogs in soil is often assumed to lead to adaptation in the bacterial community, which results in enhanced bioremediation if the soil is later contaminated. In this study, the effects of soil type and contamination history on diesel oil degradation and bacterial adaptation were studied. Mesocosms of mineral and organic forest soil (humus) were artificially treated with diesel oil, and oil hydrocarbon concentrations (GC-FID), bacterial community composition (denaturing gradient gel electrophoresis, DGGE), and oil hydrocarbon degraders (DGGE + sequencing of 16S rRNA genes) were monitored for 20 weeks at 16°C. Degradation was advanced in previously contaminated soils as compared with pristine soils and in coniferous organic forest soil as compared with mineral soil. Contamination affected bacterial community composition especially in the pristine mineral soil, where diesel addition increased the number of strong bands in the DGGE gel. Sequencing of cloned 16S rRNA gene fragments and DGGE bands showed that potential oil-degrading bacteria were found in mineral and organic soils and in both pristine and previously contaminated mesocosms. Fast oil degradation was not associated with the presence of any particular bacterial strain in soil. We demonstrate at the mesocosm scale that previously contaminated and coniferous organic soils are superior environments for fast oil degradation as compared with pristine and mineral soil environments. These results may be utilized in preventing soil pollution and planning soil remediation.

Spatio-temporal evaluation of organic contaminants and their transformation products along a river basin affected by urban, agricultural and industrial pollution.

PubMed

Gómez, María José; Herrera, Sonia; Solé, David; García-Calvo, Eloy; Fernández-Alba, Amadeo R

2012-03-15

This study aims to assess the occurrence, fate and temporal and spatial distribution of anthropogenic contaminants in a river subjected to different pressures (industrial, agricultural, wastewater discharges). For this purpose, the Henares River basin (central Spain) can be considered a representative basin within a continental Mediterranean climate. As the studied river runs through several residential, industrial and agricultural areas, it would be expected that the chemical water quality is modified along its course. Thereby the selection of sampling points and timing of sample collection are critical factors in the monitoring of a river basin. In this study, six different monitoring campaigns were performed in 2010 and contaminants were measured at the effluent point of the main wastewater treatment plant (WWTP) in the river basin and at five different points upstream and downstream from the WWTP emission point. The target compounds evaluated were personal care products (PCPs), polycyclic aromatic hydrocarbons (PAHs) and pesticides. Results show that the river is clearly influenced by wastewater discharges and also by its proximity to agricultural areas. The contaminants detected at higher concentrations were the PCPs. The spatial distribution of the contaminants indicates that the studied contaminants persist along the river. In the time period studied no great seasonal variations of PCPs at the river collection points were observed. In contrast, a temporal trend of pesticides and PAHs was observed. Besides the target compounds, other new contaminants were identified and evaluated in the water samples, some of them being investigated for the first time in the aquatic environment. The behaviour of three important transformation products was also evaluated: 9,10-anthracenodione, galaxolide-lactone and 4-amino-musk xylene. These were found at higher concentrations than their parent compounds, indicating the significance of including the study of transformation products in the monitoring programmes. Copyright © 2012 Elsevier B.V. All rights reserved.

Oak Ridge Reservation Annual Site Environmental Report for 2009

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bechtel Jacobs

2010-09-01

The Oak Ridge Reservation Annual Site Environmental Report is prepared animally and presents summary environmental data to (1) characterize environmental performance, (2) summarize environmental occurrences reported during the year, (3) confirm compliance with environmental standards and requirements, and (4) highlight significant program activities. The report fulfills the requirement contained in DOE Order 231.1 A, Environment, Safety and Health Reporting (DOE 2004) that an integrated annual site environmental report be prepared. The results summarized in this report are based on data collected prior to and through 2009. This report is not intended to nor does it present the results of allmore » environmental monitoring associated with the ORR. Data collected for other site and regulatory purposes, such as environmental restoration/remedial investigation reports, waste management characterization sampling data, and environmental permit compliance data, are presented in other documents that have been prepared in accordance with applicable DOE guidance and/or laws and are referenced herein as appropriate. Appendix A to this report identifies corrections to the 2008 report. Appendix B contains a glossary of technical terms that may be useful for understanding the terminology used in this document. Environmental monitoring on the ORR consists primarily of two major activities: effluent monitoring and environmental surveillance. Effluent monitoring involves the collection and analysis of samples or measurements of liquid and gaseous effluents at the points of release to the environment; these measurements allow the quantification and official reporting of contaminant levels, assessment of radiation and chemical exposures to the public, and demonstration of compliance with applicable standards and permit requirements. Environmental surveillance consists of direct measurements and collection and analysis of samples taken from the site and its environs exclusive of effluents; these activities provide information on contaminant concentrations in air, water, groundwater, soil, foods, biota, and other media. Environmental surveillance data support determinations regarding environmental compliance and, when combined with data from effluent monitoring, support chemical and radiation dose and exposure assessments regarding the potential effects of ORR operations, if any, on the local environment.« less

Oak Ridge Reservation Annual Site Environmental Report for 2010

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thompson, Sharon D

2011-10-01

The Oak Ridge Reservation Annual Site Environmental Report is prepared annually and presents summary environmental data to (1) characterize environmental performance, (2) summarize environmental occurrences reported during the year, (3) confirm compliance with environmental standards and requirements, and (4) highlight significant program activities. The report fulfills the requirement contained in DOE Order 231.1A, Environment, Safety and Health Reporting (DOE 2004) that an integrated annual site environmental report be prepared. The results summarized in this report are based on data collected prior to and through 2010. This report is not intended to nor does it present the results of all environmentalmore » monitoring associated with the ORR. Data collected for other site and regulatory purposes, such as environmental restoration/remedial investigation reports, waste management characterization sampling data, and environmental permit compliance data, are presented in other documents that have been prepared in accordance with applicable DOE guidance and/or laws and are referenced herein as appropriate. Appendix A to this report identifies corrections to the 2009 report. Appendix B contains a glossary of technical terms that may be useful for understanding the terminology used in this document. Environmental monitoring on the ORR consists primarily of two major activities: effluent monitoring and environmental surveillance. Effluent monitoring involves the collection and analysis of samples or measurements of liquid and gaseous effluents at the points of release to the environment; these measurements allow the quantification and official reporting of contaminant levels, assessment of radiation and chemical exposures to the public, and demonstration of compliance with applicable standards and permit requirements. Environmental surveillance consists of direct measurements and collection and analysis of samples taken from the site and its environs exclusive of effluents; these activities provide information on contaminant concentrations in air, water, groundwater, soil, foods, biota, and other media. Environmental surveillance data support determinations regarding environmental compliance and, when combined with data from effluent monitoring, support chemical and radiation dose and exposure assessments of the potential effects of ORR operations, if any, on the local environment.« less

Oak Ridge Reservation Annual Site Environmental Report for 2009

DOE Office of Scientific and Technical Information (OSTI.GOV)

Thompson, Sharon D; Loffman, Regis S

2010-10-01

The Oak Ridge Reservation Annual Site Environmental Report is prepared annually and presents summary environmental data to (1) characterize environmental performance, (2) summarize environmental occurrences reported during the year, (3) confirm compliance with environmental standards and requirements, and (4) highlight significant program activities. The report fulfills the requirement contained in DOE Order 231.1A, Environment, Safety and Health Reporting (DOE 2004) that an integrated annual site environmental report be prepared. The results summarized in this report are based on data collected prior to and through 2009. This report is not intended to nor does it present the results of all environmentalmore » monitoring associated with the ORR. Data collected for other site and regulatory purposes, such as environmental restoration/remedial investigation reports, waste management characterization sampling data, and environmental permit compliance data, are presented in other documents that have been prepared in accordance with applicable DOE guidance and/or laws and are referenced herein as appropriate. Appendix A to this report identifies corrections for the 2008 report. Appendix B contains a glossary of technical terms that may be useful for understanding the terminology used in this document. Environmental monitoring on the ORR consists primarily of two major activities: effluent monitoring and environmental surveillance. Effluent monitoring involves the collection and analysis of samples or measurements of liquid and gaseous effluents at the points of release to the environment; these measurements allow the quantification and official reporting of contaminant levels, assessment of radiation and chemical exposures to the public, and demonstration of compliance with applicable standards and permit requirements. Environmental surveillance consists of direct measurements and collection and analysis of samples taken from the site and its environs exclusive of effluents; these activities provide information on contaminant concentrations in air, water, groundwater, soil, foods, biota, and other media. Environmental surveillance data support determinations regarding environmental compliance and, when combined with data from effluent monitoring, support chemical and radiation dose and exposure assessments regarding the potential effects of ORR operations, if any, on the local environment.« less

Installation of five new hydrogeologic groundwater monitoring wells.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Catechis, Christopher Spyros

There are two sites comprised of several parcels of land within the Kirtland Military Reservation, Bernalillo County, New Mexico. Site A is located within T 9N, R 4E, Section 13 and Site B is located within T 9N, R 4E, Section 36. The purpose of this EBS is to document the nature, magnitude, and extent of any environmental contamination of the property; identify potential environmental contamination liabilities associated with the property; develop sufficient information to assess the health and safety risks; and ensure adequate protection for human health and the environment related to a specific property.

Volatile hydrocarbons and fuel oxygenates: Chapter 12

USGS Publications Warehouse

Cozzarelli, Isabelle M.

2014-01-01

Petroleum hydrocarbons and fuel oxygenates are among the most commonly occurring and widely distributed contaminants in the environment. This chapter presents a summary of the sources, transport, fate, and remediation of volatile fuel hydrocarbons and fuel additives in the environment. Much research has focused on the transport and transformation processes of petroleum hydrocarbons and fuel oxygenates, such as benzene, toluene, ethylbenzene, and xylenes and methyl tert‐butyl ether, in groundwater following release from underground storage tanks. Natural attenuation from biodegradation limits the movement of these contaminants and has received considerable attention as an environmental restoration option. This chapter summarizes approaches to environmental restoration, including those that rely on natural attenuation, and also engineered or enhanced remediation. Researchers are increasingly combining several microbial and molecular-based methods to give a complete picture of biodegradation potential and occurrence at contaminated field sites. New insights into the fate of petroleum hydrocarbons and fuel additives have been gained by recent advances in analytical tools and approaches, including stable isotope fractionation, analysis of metabolic intermediates, and direct microbial evidence. However, development of long-term detailed monitoring programs is required to further develop conceptual models of natural attenuation and increase our understanding of the behavior of contaminant mixtures in the subsurface.

Capabilities of the Materials Contamination Team at Marshall Space Flight Center

NASA Technical Reports Server (NTRS)

Burns, Howard; Albyn, Keith; Edwards, David; Boothe, Richard; Finchum, Charles; Finckenor, Miria

2003-01-01

The Materials Contamination Team at the Marshall Space Flight Center (MSFC) has been recognized for its contributions supporting the National Aeronautics and Space Administration (NASA) spacecraft development programs. These programs include the Reusable Solid Rocket Motor (RSRM), Chandra X-Ray Observatory, and the International Space Station (ISS). The Environmental Effects Group, with the Materials Contamination Team and the Space Environmental Effects Team has been an integral part of NASA's success by the testing, evaluation, and qualification of materials, hardware, and processes. This paper focuses on the capabilities of the Materials Contamination Team. The Materials Contamination Team's realm of responsibility includes establishing contamination control during all phases of hardware development, including design, manufacturing, assembly, test, transportation, launch site processing, on-orbit exposure, return, and refurbishment. The team continues its mission of reducing the risk of equipment failure due to molecular or particulate contamination. Contamination is a concern in the Space Shuttle with sensitive bond-lines and reactive fluid (liquid oxygen) compatibility as well as for spacecraft with sensitive optics, such as Hubble Space Telescope and Chandra X-ray Observatory. The Materials Contamination Team has a variety of facilities and instrumentation capable of contaminant detection, identification, and monitoring. The team addresses material applications dealing with environments, including production facilities, clean rooms, and on-orbit exposure. The optically stimulated electron emission (OSEE) system, the Ultraviolet (UV) fluorescence (UVF) surface contamination detection, and the Surface Optics Corporation 400 (SOC 400) portable hand-held Fourier Transform Infrared (FTIR) spectrometer are state-of-the-art tools for in-process molecular contamination detection. The team of engineers and technicians also develop contamination calibration standards and evaluate new surface cleanliness inspection technologies. The team utilizes facilities for on-orbit simulation testing of materials for outgassing and molecular film deposition characteristics in the presence of space environmental effects, such as Atomic Oxygen (AO) and UV radiation exposure. The Materials Contamination Team maintains databases for process materials as well as outgassing and optical compatibility test results for specific environments.

Development of RadRob15, A Robot for Detecting Radioactive Contamination in Nuclear Medicine Departments.

PubMed

Shafe, A; Mortazavi, S M J; Joharnia, A; Safaeyan, Gh H

2016-09-01

Accidental or intentional release of radioactive materials into the living or working environment may cause radioactive contamination. In nuclear medicine departments, radioactive contamination is usually due to radionuclides which emit high energy gamma photons and particles. These radionuclides have a broad range of energies and penetration capabilities. Rapid detection of radioactive contamination is very important for efficient removing of the contamination without spreading the radionuclides. A quick scan of the contaminated area helps health physicists locate the contaminated area and assess the level of activity. Studies performed in IR Iran shows that in some nuclear medicine departments, areas with relatively high levels of activity can be found. The highest contamination level was detected in corridors which are usually used by patients. To monitor radioactive contamination in nuclear medicine departments, RadRob15, a contamination detecting robot was developed in the Ionizing and Non-ionizing Radiation Protection Research Center (INIRPRC). The motor vehicle scanner and the gas radiation detector are the main components of this robot. The detection limit of this robot has enabled it to detect low levels of radioactive contamination. Our preliminary tests show that RadRob15 can be easily used in nuclear medicine departments as a device for quick surveys which identifies the presence or absence of radioactive contamination.

Current Measures on Radioactive Contamination in Japan: A Policy Situation Analysis.

PubMed

Gilmour, Stuart; Miyagawa, Shoji; Kasuga, Fumiko; Shibuya, Kenji

2016-01-01

The Great East Japan Earthquake on 11th March 2011 and the subsequent Fukushima Dai-ichi nuclear power plant disaster caused radioactive contamination in the surrounding environment. In the immediate aftermath of the accident the Government of Japan placed strict measures on radio-contamination of food, and enhanced radio-contamination monitoring activities. Japan is a pilot country in the WHO Foodborne Disease Burden Epidemiology Reference Group (FERG), and through this initiative has an opportunity to report on policy affecting chemicals and toxins in the food distribution network. Nuclear accidents are extremely rare, and a policy situation analysis of the Japanese government's response to the Fukushima Dai-ichi nuclear accident is a responsibility of Japanese scientists. This study aims to assess Japan government policies to reduce radio-contamination risk and to identify strategies to strengthen food policies to ensure the best possible response to possible future radiation accidents. We conducted a hand search of all publicly available policy documents issued by the Cabinet Office, the Food Safety Commission, the Ministry of Health, Labor and Welfare (MHLW), the Ministry of Agriculture, Forestry and Fishery (MAFF) and prefectural governments concerning food safety standards and changes to radiation and contamination standards since March 11th, 2011. We extracted information on food shipment and sales restrictions, allowable radio-contamination limits, monitoring activities and monitoring results. The standard for allowable radioactive cesium (Cs-134 and Cs-137) of 100 Bq/Kg in general food, 50 Bq/Kg in infant formula and all milk products, and 10 Bq/Kg in drinking water was enforced from April 2012 under the Food Sanitation Law, although a provisional standard on radio-contamination had been applied since the nuclear accident. Restrictions on the commercial sale and distribution of specific meat, vegetable and fish products were released for areas at risk of radioactive contamination. Monitoring of radioactive materials in food products in the prefectures has been mainly conducted before shipment to restrict the distribution of radio-contaminated foods. Between March 2011 and March 2012, 133,832 tests of non-commercial and commercial products were conducted, and 1,204 tests (0.9%) were found to violate the provisional standards. Since April 2012, 278,275 tests were conducted, and 2,372 tests (0.9%) were found to violate the revised standards. MHLW assessment of representative market baskets of foodstuffs at 15 locations throughout Japan between February and March 2014 found very low estimated dietary intake of radioactive cesium (0.0007-0.019 mSv/year), as did assessments of the contents of an average day's food. Monitoring of fisheries products in coastal areas affected by the nuclear accident found very limited and declining radio-contamination of live fish outside of Fukushima prefecture. Fisheries monitoring is of limited geographical scope and covers only certain fishes. Area-specific bans on production and distribution have been effective in preventing radioactive contamination in the Japanese food market. Currently there is no major concern about radioactive cesium concentrations in retail foodstuffs in Japan, and very low levels of contamination at the production and wholesale stage. However, because the residue limits and food safety policies were revised on an ad hoc, emergency basis after the nuclear accident, the monitoring procedure needs to be reviewed based on objective and scientifically rational criteria. A transparent and objective scientific framework is needed for prioritizing foodstuffs for inspection and revising Prefecture-specific restrictions. Monitoring of fishes and other seafood products in the wild should be regularized and the information made more publicly accessible, and monitoring activities expanded to identify foodstuffs that are no longer a food safety risk. Consultation with producers and consumers should be more formalized to ensure their concerns are incorporated into regular policy reviews in an appropriate and transparent manner. However, despite the limited available knowledge on best practice in food control and enforcement of provisional radio-contamination limits after the accident, current Japanese policy is sufficient to protect the Japanese public from major risk of radio-contamination from the commercial food market.

Current Measures on Radioactive Contamination in Japan: A Policy Situation Analysis

PubMed Central

Gilmour, Stuart; Miyagawa, Shoji; Kasuga, Fumiko; Shibuya, Kenji

2016-01-01

Background The Great East Japan Earthquake on 11th March 2011 and the subsequent Fukushima Dai-ichi nuclear power plant disaster caused radioactive contamination in the surrounding environment. In the immediate aftermath of the accident the Government of Japan placed strict measures on radio-contamination of food, and enhanced radio-contamination monitoring activities. Japan is a pilot country in the WHO Foodborne Disease Burden Epidemiology Reference Group (FERG), and through this initiative has an opportunity to report on policy affecting chemicals and toxins in the food distribution network. Nuclear accidents are extremely rare, and a policy situation analysis of the Japanese government’s response to the Fukushima Dai-ichi nuclear accident is a responsibility of Japanese scientists. This study aims to assess Japan government policies to reduce radio-contamination risk and to identify strategies to strengthen food policies to ensure the best possible response to possible future radiation accidents. Methods and Findings We conducted a hand search of all publicly available policy documents issued by the Cabinet Office, the Food Safety Commission, the Ministry of Health, Labor and Welfare (MHLW), the Ministry of Agriculture, Forestry and Fishery (MAFF) and prefectural governments concerning food safety standards and changes to radiation and contamination standards since March 11th, 2011. We extracted information on food shipment and sales restrictions, allowable radio-contamination limits, monitoring activities and monitoring results. The standard for allowable radioactive cesium (Cs-134 and Cs-137) of 100 Bq/Kg in general food, 50 Bq/Kg in infant formula and all milk products, and 10 Bq/Kg in drinking water was enforced from April 2012 under the Food Sanitation Law, although a provisional standard on radio-contamination had been applied since the nuclear accident. Restrictions on the commercial sale and distribution of specific meat, vegetable and fish products were released for areas at risk of radioactive contamination. Monitoring of radioactive materials in food products in the prefectures has been mainly conducted before shipment to restrict the distribution of radio-contaminated foods. Between March 2011 and March 2012, 133,832 tests of non-commercial and commercial products were conducted, and 1,204 tests (0.9%) were found to violate the provisional standards. Since April 2012, 278,275 tests were conducted, and 2,372 tests (0.9%) were found to violate the revised standards. MHLW assessment of representative market baskets of foodstuffs at 15 locations throughout Japan between February and March 2014 found very low estimated dietary intake of radioactive cesium (0.0007–0.019 mSv/year), as did assessments of the contents of an average day’s food. Monitoring of fisheries products in coastal areas affected by the nuclear accident found very limited and declining radio-contamination of live fish outside of Fukushima prefecture. Fisheries monitoring is of limited geographical scope and covers only certain fishes. Conclusions Area-specific bans on production and distribution have been effective in preventing radioactive contamination in the Japanese food market. Currently there is no major concern about radioactive cesium concentrations in retail foodstuffs in Japan, and very low levels of contamination at the production and wholesale stage. However, because the residue limits and food safety policies were revised on an ad hoc, emergency basis after the nuclear accident, the monitoring procedure needs to be reviewed based on objective and scientifically rational criteria. A transparent and objective scientific framework is needed for prioritizing foodstuffs for inspection and revising Prefecture-specific restrictions. Monitoring of fishes and other seafood products in the wild should be regularized and the information made more publicly accessible, and monitoring activities expanded to identify foodstuffs that are no longer a food safety risk. Consultation with producers and consumers should be more formalized to ensure their concerns are incorporated into regular policy reviews in an appropriate and transparent manner. However, despite the limited available knowledge on best practice in food control and enforcement of provisional radio-contamination limits after the accident, current Japanese policy is sufficient to protect the Japanese public from major risk of radio-contamination from the commercial food market. PMID:27007509

Curating NASA's Astromaterials Collections: Past, Present, and Future

NASA Technical Reports Server (NTRS)

Zeigler, Ryan

2015-01-01

Planning for the curation of samples from future sample return missions must begin during the initial planning stages of a mission. Waiting until the samples have been returned to Earth, or even when you begin to physically build the spacecraft is too late. A lack of proper planning could lead to irreversible contamination of the samples, which in turn would compromise the scientific integrity of the mission. For example, even though the Apollo missions first returned samples in 1969, planning for the curation facility began in the early 1960s, and construction of the Lunar Receiving Laboratory was completed in 1967. In addition to designing the receiving facility and laboratory that the samples will be characterized and stored in, there are many aspects of contamination that must be addressed during the planning and building of the spacecraft: planetary protection (both outbound and inbound); cataloging, documenting, and preserving the materials used to build spacecraft (also known as coupons); near real-time monitoring of the environment in which the spacecraft is being built using witness plates for critical aspects of contamination (known as contamination control); and long term monitoring and preservation of the environment in which the spacecraft is being built for most aspects of potential contamination through the use of witness plates (known as contamination knowledge). The OSIRIS REx asteroid sample return mission, currently being built, is dealing with all of these aspects of contamination in order to ensure they return the best preserved sample possible. Coupons and witness plates from OSIRIS REx are currently being studied and stored (for future studies) at the Johnson Space Center. Similarly, planning for the clean room facility at Johnson Space Center to house the OSIRIS-REx samples is well advanced, and construction of the facility should begin in early 2017 (despite a nominal 2023 return date for OSIRIS-REx samples). Similar development is being done, in concert with JAXA, for the return of Hayabusa 2 samples (nominally in 2020). We are also actively developing advanced techniques like cold curation and organically clean curation in anticipation of future sample return missions such as comet nucleus sample return and Mars sample return.

Identification and Tracing Groundwater Contamination by Livestock Burial Sites

NASA Astrophysics Data System (ADS)

Ko, K.; Ha, K.; Park, S.; Kim, Y.; Lee, K.

2011-12-01

Foot-and-mouth disease (FMD) or hoof-and-mouth disease is a severe plague for animal farming that affects cloven-hoofed animals such as cattle, pigs, sheep, and goats. Since it is highly infectious and can be easily proliferated by infected animals, contaminated equipments, vehicles, clothing, people, and predators. It is widely known that the virus responsible for FMD is a picornavirus, the prototypic member of the genus Aphthovirus. A serious outbreak of foot-and-mouth disease, leading to the stamping out of 3.53 millions of pigs and cattle and the construction of 4,538 burial sites until 15th March, 2011. The build-up of carcass burial should inevitably produce leachate by the decomposition of buried livestock affecting the surround environment such as air, soil, groundwater, and surface water. The most important issues which are currently raised by scientists are groundwater contamination by leachate from the livestock burial sites. This study examined the current status of FMD outbreak occurred in 2010-2011 and the issues of groundwater contamination by leachate from livestock burial sites. The hydrogeochemical, geophysical, and hydrogeological studies were executed to identify and trace groundwater contamination by leachate from livestock burial sites. Generally livestock mortality leachate contains high concentrations of NH3-N, HCO3-, Cl-, SO42-, K+, Na+, P along with relative lesser amounts of iron, calcium, and magnesium. The groundwater chemical data around four burial sites showed high NH3-N, HCO3-, and K+ suggesting the leachate leakage from burial sites. This is also proved by resistivity monitoring survey and tracer tests. The simulation results of leachate dispersion showed the persistent detrimental impacts for groundwater environment for a long time (~50 years). It is need to remove the leachate of burial sites to prevent the dispersion of leachate from livestock burial to groundwater and to monitor the groundwater quality. The most important forthcoming issues for livestock burial are the treatment of leachate, protection of groundwater contamination by leachate, prevention of land slide, and prevention of rainfall percolation into burial site. It is also needed to develop the remediation, prospecting, and management technologies of groundwater contamination by carcass burial.

Pollution pathways and release estimation of perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) in central and eastern China.

PubMed

Liu, Zhaoyang; Lu, Yonglong; Wang, Pei; Wang, Tieyu; Liu, Shijie; Johnson, Andrew C; Sweetman, Andrew J; Baninla, Yvette

2017-02-15

China has gradually become the most important manufacturing and consumption centre for perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) in the world, and inadvertently become the world's major contamination hotspots. However, a systematic analysis of pollution pathways for PFOS/PFOA into the different environmental compartments and their quantification in China has yet to be carried out. This study focused on PFOS and PFOA release into the environment in the central and eastern region of China, which accounts for the vast majority of national emission. About 80-90% of PFOS/PFOA contamination in the Chinese environment was estimated to come directly from manufacturing and industrial sites mostly via wastewater discharge from these facilities. The other major contamination sources for PFOS were identified as being linked to aqueous fire-fighting foams (AFFFs), and pesticides including sulfluramid. For PFOA, following some way behind industrial wastewater, were industrial exhaust gas, domestic wastewater and landfill leachate as contamination sources. For surface water contamination, the major pollution contributors after industrial wastewater were AFFF spill runoff for PFOS, and domestic wastewater and precipitation-runoff for PFOA. The majority of PFOS that contaminated soil was considered to be linked with infiltration of AFFF and pesticides, while most PFOA in soil was attributed to atmospheric deposition and landfill leachate. Where groundwater had become contaminated, surface water seepage was estimated to contribute about 50% of PFOS and 40% of PFOA while the remainder was mostly derived from soil leaching. A review of the available monitoring data for PFOS/PFOA in the literature supported the view that industrial wastewater, landfill leachate and AFFF application were the dominant sources. Higher concentrations of PFOA than PFOS found in precipitation also corroborated the prediction of more PFOA release into air. To reduce PFOS/PFOA contamination of the Chinese environment the focus for control should be on industrial wastewater emissions. Copyright © 2016 Elsevier B.V. All rights reserved.

Airborne particle monitoring in clean room environments for stem cell cultures.

PubMed

Cobo, Fernando; Grela, David; Concha, Angel

2008-01-01

Modern high-technology industrial practices like pharmaceutical and stem cell line production demand high-quality environmental conditions to avoid particle contamination in the final product. Particles are important because their presence can affect both the output and the productivity and because they can have repercussion on human health. In this kind of production practice it is necessary to implement optimal methods for particle management and to introduce an environmental monitoring program. This should also address the regional regulatory requirements and will depend on local conditions in each processing center. Each center must evaluate its specific needs and establish appropriate monitoring procedures.

Electrical resistivity tomography to monitor enhanced biodegradation of hydrocarbons with Rhodococcus erythropolis T902.1 at a pilot scale.

PubMed

Masy, Thibaut; Caterina, David; Tromme, Olivier; Lavigne, Benoît; Thonart, Philippe; Hiligsmann, Serge; Nguyen, Frédéric

2016-01-01

Petroleum hydrocarbons (HC) represent the most widespread contaminants and in-situ bioremediation remains a competitive treatment in terms of cost and environmental concerns. However, the efficiency of such a technique (by biostimulation or bioaugmentation) strongly depends on the environment affected and is still difficult to predict a priori. In order to overcome these uncertainties, Electrical Resistivity Tomography (ERT) appears as a valuable non-invasive tool to detect soil heterogeneities and to monitor biodegradation. The main objective of this study was to isolate an electrical signal linked to an enhanced bacterial activity with ERT, in an aged HC-contaminated clay loam soil. To achieve this, a pilot tank was built to mimic field conditions. Compared to a first insufficient biostimulation phase, bioaugmentation with Rhodococcus erythropolis T902.1 led to a HC depletion of almost 80% (6900 to 1600ppm) in 3months in the center of the contaminated zone, where pollutants were less bioavailable. In the meantime, lithological heterogeneities and microbial activities (growth and biosurfactant production) were successively discriminated by ERT images. In the future, this cost-effective technique should be more and more transferred to the field in order to monitor biodegradation processes and assist in selecting the most appropriate remediation technique. Copyright © 2015 Elsevier B.V. All rights reserved.

Electrical resistivity tomography to monitor enhanced biodegradation of hydrocarbons with Rhodococcus erythropolis T902.1 at a pilot scale

NASA Astrophysics Data System (ADS)

Masy, Thibaut; Caterina, David; Tromme, Olivier; Lavigne, Benoît; Thonart, Philippe; Hiligsmann, Serge; Nguyen, Frédéric

2016-01-01

Petroleum hydrocarbons (HC) represent the most widespread contaminants and in-situ bioremediation remains a competitive treatment in terms of cost and environmental concerns. However, the efficiency of such a technique (by biostimulation or bioaugmentation) strongly depends on the environment affected and is still difficult to predict a priori. In order to overcome these uncertainties, Electrical Resistivity Tomography (ERT) appears as a valuable non-invasive tool to detect soil heterogeneities and to monitor biodegradation. The main objective of this study was to isolate an electrical signal linked to an enhanced bacterial activity with ERT, in an aged HC-contaminated clay loam soil. To achieve this, a pilot tank was built to mimic field conditions. Compared to a first insufficient biostimulation phase, bioaugmentation with Rhodococcus erythropolis T902.1 led to a HC depletion of almost 80% (6900 to 1600 ppm) in 3 months in the center of the contaminated zone, where pollutants were less bioavailable. In the meantime, lithological heterogeneities and microbial activities (growth and biosurfactant production) were successively discriminated by ERT images. In the future, this cost-effective technique should be more and more transferred to the field in order to monitor biodegradation processes and assist in selecting the most appropriate remediation technique.

Photo-Fenton and modified photo-Fenton at neutral pH for the treatment of emerging contaminants in wastewater treatment plant effluents: a comparison.

PubMed

Klamerth, N; Malato, S; Agüera, A; Fernández-Alba, A

2013-02-01

This study compares two different solar photo-Fenton processes, conventional photo-Fenton at pH3 and modified photo-Fenton at neutral pH with minimal Fe (5 mg L⁻¹) and minimal initial H₂O₂ (50 mg L⁻¹) concentrations for the degradation of emerging contaminants in Municipal Wastewater Treatment Plants effluents in solar pilot plant. As Fe precipitates at neutral pH, complexing agents which are able to form photoactive species, do not pollute the environment or increase toxicity have to be used to keep the iron in solution. This study was done using real effluents containing over 60 different contaminants, which were monitored during treatment by liquid chromatography coupled to a hybrid quadrupole/linear ion trap mass analyzer (LC-QTRAP-MS/MS) operating in selected reaction monitoring (SRM) mode. Concentrations of the selected contaminants ranged from a few ng L⁻¹ to tens of μg L⁻¹. It was demonstrated in all cases the removal of over 95% of the contaminants. Photo-Fenton at pH3 provided the best treatment time, but has the disadvantage that the water must be previously acidified. The most promising process was photo-Fenton modified with Ethylenediamine-N,N'-disuccinic acid (EDDS), as the pH remained in the neutral range. Copyright © 2012 Elsevier Ltd. All rights reserved.

Monitoring airborne biotic contaminants in the indoor environment of pig and poultry confinement buildings.

PubMed

Hong, Pei-Ying; Li, Xiangzhen; Yang, Xufei; Shinkai, Takumi; Zhang, Yuanhui; Wang, Xinlei; Mackie, Roderick I

2012-06-01

Given the growing concerns over human and animal health issues related to confined animal feeding operations, an in-depth examination is required to monitor for airborne bacteria and associated antibiotic resistance genes. Our 16S rRNA-based pyrosequencing revealed that the airborne microbial community skewed towards a higher abundance of Firmicutes (> 59.2%) and Bacteroidetes (4.2-31.4%) within the confinement buildings, while the office environment was predominated by Proteobacteria (55.2%). Furthermore, bioaerosols in the confinement buildings were sporadically associated with genera of potential pathogens, and these genera were more frequently observed in the bioaerosols of pig and layer hen confinement than the turkey confinement buildings and office environment. High abundances of tetracycline resistance genes (9.55 × 10(2) to 1.69 × 10(6) copies ng(-1) DNA) were also detected in the bioaerosols sampled from confinement buildings. Bacterial lineages present in the poultry bioaerosols clustered apart from those present in the pig bioaerosols and among the different phases of pig production, suggesting that different livestock as well as production phase were associated with a distinct airborne microbial community. By understanding the diversity of biotic contaminants associated with the different confinement buildings, this study facilitates the implementation of better management strategies to minimize potential health impacts on both livestock and humans working in this environment. © 2012 Society for Applied Microbiology and Blackwell Publishing Ltd.

Causes and ecological effects of resuspended contaminated sediments (RCS) in marine environments.

PubMed

Roberts, David A

2012-04-01

Sediments act as a net sink for anthropogenic contaminants in marine ecosystems and contaminated sediments may have a range of toxicological effects on benthic fauna and associated species. When resuspended, however, particulate-bound contaminants may be remobilised into the water column and become bioavailable to an additional assemblage of species. Such resuspension occurs through a range of natural and anthropogenic processes each of which may be thought of as pulsed disturbances resulting in pulsed exposures to contaminants. Thus, it is important to understand not only the toxicological responses of organisms to resuspended contaminated sediments (RCS), but also the frequency, magnitude and duration of sediment disturbance events. Such information is rarely collected together with toxicological data. Rather, the majority of published studies (>50% of the articles captured in this review) have taken the form of fixed-duration laboratory-based exposures with individual species. While this research has clearly demonstrated that resuspension of contaminated sediments can liberate sediment-bound contaminants leading to toxicity and bioaccumulation under controlled conditions, the potential for ecological effects in the field is often unclear. Monitoring studies suggest that recurrent natural disturbances such as tides and waves may cause the majority of contaminant release in many environments. However, various processes also act to limit the spatial and temporal scales across which contaminants are remobilised to the most toxic dissolved state. Various natural and anthropogenic disturbances of contaminated sediments have been linked to both community-level and sub-lethal responses in exposed populations of invertebrates and fish in the field. Together these findings suggest that resuspension of contaminated sediments is a frequently recurring ecological threat in contaminated marine habitats. Further consideration of how marine communities respond to temporally variable exposures to RCS is required, as well as research into the relative importance of various disturbances under field conditions. Crown Copyright © 2011. Published by Elsevier Ltd. All rights reserved.

Use of liquid nitrogen during storage in a cell and tissue bank: contamination risk and effect on the detectability of potential viral contaminants.

PubMed

Mirabet, Vicente; Alvarez, Manuel; Solves, Pilar; Ocete, Dolores; Gimeno, Concepción

2012-04-01

Cryopreservation is widely used for banking cells and tissues intended for transplantation. Liquid nitrogen provides a very stable ultra-low temperature environment. Thus, it is used for longterm storage. Unlike the exhaustive microbiological monitoring of the environmental conditions during tissue processing, storage is not usually considered as a critical point of potential contamination risk in professional standards for cell and tissue banking. We have analysed the presence of microbial agents inside our nitrogen tanks. We have mainly detected environmental and water-borne bacteria and fungi. In addition, we have studied the effect of liquid nitrogen exposure on virus detectability. Only differences for hepatitis C virus RNA were observed. Measures for contamination risk reduction during storage must be mandatory in cell and tissue banking. Copyright © 2011 Elsevier Inc. All rights reserved.

Outpatient radioiodine therapy for thyroid cancer: a safe nuclear medicine procedure.

PubMed

Willegaignon, José; Sapienza, Marcelo; Ono, Carla; Watanabe, Tomoco; Guimarães, Maria Inês; Gutterres, Ricardo; Marechal, Maria Helena; Buchpiguel, Carlos

2011-06-01

To evaluate the dosimetric effect of outpatient radioiodine therapy for thyroid cancer in members of a patient's family and their living environment, when using iodine-131 doses reaching 7.4 GBq. The following parameters were thus defined: (a) whole-body radiation doses to caregivers, (b) the production of contaminated solid waste, and (c) radiation potential and surface contamination within patients' living quarters. In total, 100 patients were treated on an outpatient basis, taking into consideration their acceptable living conditions, interests, and willingness to comply with medical and radiation safety guidelines. Both the caregivers and the radiation dose potentiality inside patients' residences were monitored by using thermoluminescent dosimeters. Surface contamination and contaminated solid wastes were identified and measured with a Geiger-Müller detector. A total of 90 monitored individuals received a mean dose of 0.27 (±0.28) mSv, and the maximum dose registered was 1.6 mSv. The mean value for the potential dose within all living quarters was 0.31 (±0.34) mSv, and the mean value per monitored surface was 5.58 Bq/cm(2) for all the 1659 points measured. The overall production of contaminated solid wastes was at a low level, being about 3 times less than the exemption level indicated by the International Atomic Energy Agency. This study indicates that the treatment of thyroid cancer by applying radioiodine activities up to 7.4 GBq, on an outpatient basis, is a safe procedure, especially when supervised by qualified professionals. This alternative therapy should be a topic for careful discussion considering the high potential for reducing costs in healthcare and improving patient acceptance.

A novel bioassay using the barnacle Amphibalanus amphitrite to evaluate chronic effects of aluminium, gallium and molybdenum in tropical marine receiving environments.

PubMed

van Dam, Joost W; Trenfield, Melanie A; Harries, Simon J; Streten, Claire; Harford, Andrew J; Parry, David; van Dam, Rick A

2016-11-15

A need exists for appropriate tools to evaluate risk and monitor potential effects of contaminants in tropical marine environments, as currently impact assessments are conducted by non-representative approaches. Here, a novel bioassay is presented that allows for the estimation of the chronic toxicity of contaminants in receiving tropical marine environments. The bioassay is conducted using planktonic larvae of the barnacle Amphibalanus amphitrite and is targeted at generating environmentally relevant, chronic toxicity data for water quality guideline derivation or compliance testing. The developmental endpoint demonstrated a consistently high control performance, validated through the use of copper as a reference toxicant. In addition, the biological effects of aluminium, gallium and molybdenum were assessed. The endpoint expressed high sensitivity to copper and moderate sensitivity to aluminium, whereas gallium and molybdenum exhibited no discernible effects, even at high concentrations, providing valuable information on the toxicity of these elements in tropical marine waters. Crown Copyright © 2016. Published by Elsevier Ltd. All rights reserved.

Triclosan: Current Status, Occurrence, Environmental Risks and Bioaccumulation Potential

PubMed Central

Dhillon, Gurpreet Singh; Kaur, Surinder; Pulicharla, Rama; Brar, Satinder Kaur; Cledón, Maximiliano; Verma, Mausam; Surampalli, Rao Y.

2015-01-01

Triclosan (TCS) is a multi-purpose antimicrobial agent used as a common ingredient in everyday household personal care and consumer products. The expanded use of TCS provides a number of pathways for the compound to enter the environment and it has been detected in sewage treatment plant effluents; surface; ground and drinking water. The physico-chemical properties indicate the bioaccumulation and persistence potential of TCS in the environment. Hence, there is an increasing concern about the presence of TCS in the environment and its potential negative effects on human and animal health. Nevertheless, scarce monitoring data could be one reason for not prioritizing TCS as emerging contaminant. Conventional water and wastewater treatment processes are unable to completely remove the TCS and even form toxic intermediates. Considering the worldwide application of personal care products containing TCS and inefficient removal and its toxic effects on aquatic organisms, the compound should be considered on the priority list of emerging contaminants and its utilization in all products should be regulated. PMID:26006133

Tulane/Xavier Center for Bioenvironmental Research; project: hazardous materials in aquatic environments; subproject: biomarkers and risk assessment in Bayou Trepagnier, LA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ide, C.

1996-12-31

Tulane and Xavier Universities have singled out the environment as a major strategic focus for research and training for now and beyond the year 2000. the Tulane/Xavier Center for Bioenvironmental Research (CBR) was established in 1989 as the umbrella organization to coordinate environmental research at both universities. CBR projects funded by the DOE under the Hazardous Materials in Aquatic Environments grant are defining the following: (1) the complex interactions that occur during the transport of contaminants through wetlands environments, (2) the actual and potential impact of contaminants on ecological systems and health, (3) the mechanisms and new technologies through whichmore » these impacts might be remediated, and (4) new programs aimed at educating and training environmental workers of the future. The subproject described in this report, `Biomarkers and Risk Assessment in Bayou Trepagnier, LN`, is particularly relevant to the US Department of Energy`s Environmental Restoration and Waste Management program aimed at solving problems related to hazard monitoring and clean-up prioritization at sites with aquatic pollution problems in the DOE complex.« less

Occurrence and methods of control of chemical contaminants in foods.

PubMed Central

Jelinek, C

1981-01-01

Contamination of food by chemicals can result from their use on agricultural commodities; accidents or misuse during food handling and processing; nucler weapon testing and operation of nuclear power plants; and disposal of industrial chemicals or by-products with subsequent dispersal into the environment. The Food and Drug Administration (FDA), as the Federal agency mainly responsible for evaluating the hazards of chemical contaminants and enforcing any established tolerance levels for them in foods, has been monitoring pesticides, industrial chemicals, metals, and radionuclides in foods in its nationwide programs for many years. In addition, FDA searches for potential contaminants among the approximately 50,000 industrial chemicals manufactured in the United States and coordinates its efforts with those of other Federal and state agencies in these investigations. The overall results of the FDA surveillance and compliance programs for chemical contaminants in foods, as well as specific examples illustrating the wide range of incidents and types of occurrences, are presented. PMID:6786871

MMS Observatory Thermal Vacuum Results Contamination Summary

NASA Technical Reports Server (NTRS)

Rosecrans, Glenn P.; Errigo, Therese; Brieda, Lubos

2014-01-01

The MMS mission is a constellation of 4 observatories designed to investigate the fundamental plasma physics of reconnection in the Earths magnetosphere. Each spacecraft has undergone extensive environmental testing to prepare it for its minimum 2 year mission. The various instrument suites measure electric and magnetic fields, energetic particles, and plasma composition. Thermal vacuum testing was conducted at the Naval Research Laboratory (NRL) in their Big Blue vacuum chamber. The individual spacecraft were tested and enclosed in a cryopanel enclosure called a Hamster cage. Specific contamination control validations were actively monitored by several QCMs, a facility RGA, and at times, with 16 Ion Gauges. Each spacecraft underwent a bakeout phase, followed by 4 thermal cycles. Unique aspects of the TV environment included slow pump downs with represses, thruster firings, Helium identification, and monitoring pressure spikes with Ion gauges. Various data from these TV tests will be shown along with lessons learned.

Subsurface clade of Geobacteraceae that predominates in a diversity of Fe(III)-reducing subsurface environments

USGS Publications Warehouse

Holmes, Dawn E.; O'Neil, Regina A.; Vrionis, Helen A.; N'Guessan, Lucie A.; Ortiz-Bernad, Irene; Larrahondo, Maria J.; Adams, Lorrie A.; Ward, Joy A.; Nicoll , Julie S.; Nevin, Kelly P.; Chavan, Milind A.; Johnson, Jessica P.; Long, Philip E.; Lovely, Derek R.

2007-01-01

There are distinct differences in the physiology of Geobacter species available in pure culture. Therefore, to understand the ecology of Geobacter species in subsurface environments, it is important to know which species predominate. Clone libraries were assembled with 16S rRNA genes and transcripts amplified from three subsurface environments in which Geobacter species are known to be important members of the microbial community: (1) a uranium-contaminated aquifer located in Rifle, CO, USA undergoing in situ bioremediation; (2) an acetate-impacted aquifer that serves as an analog for the long-term acetate amendments proposed for in situ uranium bioremediation and (3) a petroleum-contaminated aquifer in which Geobacter species play a role in the oxidation of aromatic hydrocarbons coupled with the reduction of Fe(III). The majority of Geobacteraceae 16S rRNA sequences found in these environments clustered in a phylogenetically coherent subsurface clade, which also contains a number of Geobacter species isolated from subsurface environments. Concatamers constructed with 43 Geobacter genes amplified from these sites also clustered within this subsurface clade. 16S rRNA transcript and gene sequences in the sediments and groundwater at the Rifle site were highly similar, suggesting that sampling groundwater via monitoring wells can recover the most active Geobacter species. These results suggest that further study of Geobacter species in the subsurface clade is necessary to accurately model the behavior of Geobacter species during subsurface bioremediation of metal and organic contaminants.

[Updating the problems of human ecology and environmental health and the ways of solving them].

PubMed

Rakhmanin, Iu A

2012-01-01

Displaying a variety of scientific areas studying the influence of the environment on human health, the state and modern issues of assessment of environmental quality, hygienic standardization of chemical and biological contamination, methodical support of sanitarian and health monitoring and risk assessment of pollution, environmental health, the need for improvement and harmonization with the international instruments of the legal and methodological framework for the protection of the human environment, of the development of a modern management system of her quality based on epidemiological methods for simulation, risk analysis, assessment of economic damage to the environment and health of the population, forming a new branch of medicine--medicine of environment.

Monitoring airborne fungal spores in an experimental indoor environment to evaluate sampling methods and the effects of human activity on air sampling.

PubMed Central

Buttner, M P; Stetzenbach, L D

1993-01-01

Aerobiological monitoring was conducted in an experimental room to aid in the development of standardized sampling protocols for airborne microorganisms in the indoor environment. The objectives of this research were to evaluate the relative efficiencies of selected sampling methods for the retrieval of airborne fungal spores and to determine the effect of human activity on air sampling. Dry aerosols containing known concentrations of Penicillium chrysogenum spores were generated, and air samples were taken by using Andersen six-stage, Surface Air System, Burkard, and depositional samplers. The Andersen and Burkard samplers retrieved the highest numbers of spores compared with the measurement standard, an aerodynamic particle sizer located inside the room. Data from paired samplers demonstrated that the Andersen sampler had the highest levels of sensitivity and repeatability. With a carpet as the source of P. chrysogenum spores, the effects of human activity (walking or vacuuming near the sampling site) on air sampling were also examined. Air samples were taken under undisturbed conditions and after human activity in the room. Human activity resulted in retrieval of significantly higher concentrations of airborne spores. Surface sampling of the carpet revealed moderate to heavy contamination despite relatively low airborne counts. Therefore, in certain situations, air sampling without concomitant surface sampling may not adequately reflect the level of microbial contamination in indoor environments. PMID:8439150

Amchitka Island, Alaska, special sampling project 1997

DOE Office of Scientific and Technical Information (OSTI.GOV)

U.S. Department of Energy, Nevada Operations Office

2000-06-28

This 1997 special sampling project represents a special radiobiological sampling effort to augment the 1996 Long-Term Hydrological Monitoring Program (LTHMP) for Amchitka Island in Alaska. Lying in the western portion of the Aleutian Islands arc, near the International Date Line, Amchitka Island is one of the southernmost islands of the Rat Island Chain. Between 1965 and 1971, the U.S. Atomic Energy Commission conducted three underground nuclear tests on Amchitka Island. In 1996, Greenpeace collected biota samples and speculated that several long-lived, man-made radionuclides detected (i.e., americium-241, plutonium-239 and -240, beryllium-7, and cesium-137) leaked into the surface environment from underground cavitiesmore » created during the testing. The nuclides of interest are detected at extremely low concentrations throughout the environment. The objectives of this special sampling project were to scientifically refute the Greenpeace conclusions that the underground cavities were leaking contaminants to the surface. This was achieved by first confirming the presence of these radionuclides in the Amchitka Island surface environment and, second, if the radionuclides were present, determining if the source is the underground cavity or worldwide fallout. This special sampling and analysis determined that the only nonfallout-related radionuclide detected was a low level of tritium from the Long Shot test, which had been previously documented. The tritium contamination is monitored and continues a decreasing trend due to radioactive decay and dilution.« less

Functional gene array-based analysis of microbial community structure in groundwaters with a gradient of contaminant levels

DOE Office of Scientific and Technical Information (OSTI.GOV)

Waldron, P.J.; Wu, L.; Van Nostrand, J.D.

2009-06-15

To understand how contaminants affect microbial community diversity, heterogeneity, and functional structure, six groundwater monitoring wells from the Field Research Center of the U.S. Department of Energy Environmental Remediation Science Program (ERSP; Oak Ridge, TN), with a wide range of pH, nitrate, and heavy metal contamination were investigated. DNA from the groundwater community was analyzed with a functional gene array containing 2006 probes to detect genes involved in metal resistance, sulfate reduction, organic contaminant degradation, and carbon and nitrogen cycling. Microbial diversity decreased in relation to the contamination levels of the wells. Highly contaminated wells had lower gene diversity butmore » greater signal intensity than the pristine well. The microbial composition was heterogeneous, with 17-70% overlap between different wells. Metal-resistant and metal-reducing microorganisms were detected in both contaminated and pristine wells, suggesting the potential for successful bioremediation of metal-contaminated groundwaters. In addition, results of Mantel tests and canonical correspondence analysis indicate that nitrate, sulfate, pH, uranium, and technetium have a significant (p < 0.05) effect on microbial community structure. This study provides an overall picture of microbial community structure in contaminated environments with functional gene arrays by showing that diversity and heterogeneity can vary greatly in relation to contamination.« less

Ten-Year Monitored Natural Recovery of Lead-Contaminated Mine Tailing in Klity Creek, Kanchanaburi Province, Thailand

PubMed Central

Phenrat, Tanapon; Otwong, Ashijya; Chantharit, Aphichart; Lowry, Gregory V.

2016-01-01

Background: Klity Creek has become Thailand’s first official remediation ordered by the court in 2013, 15 years after the spill of lead (Pb)-contaminated mine tailing into the creek. The Pollution Control Department (PCD) decided to restore the creek through monitored natural recovery (MNR) since 2006 but has not been successful. Interestingly, the most recent remediation plan in 2015 will still apply MNR to five out of the seven portions of the creek, despite no scientific feasibility evaluation of using MNR to restore the creek. Objective: This study qualitatively and quantitatively evaluated the feasibility of using MNR to clean up the creek in order to protect the Klity children from excess Pb exposure. Methods: We analyzed the physical and chemical transformation of Pb contaminated sediment in the creek and developed a remedial action goal and cleanup level using the Integrated Exposure Uptake Biokinetic model (IEUBK). We empirically determined the natural recovery (NR) potentials and rates using 10 years of data monitoring the water and sediment samples from eight monitoring stations (KC1 to KC8). Results: Klity Creek has NR potential for water except at KC2, which is closest to the spill and the other improperly managed Pb sources. However, the creek has no NR potential for sediment except at the KC8 location (NR rate = 11.1 ± 3.0 × 10–3 month–1) farthest from the spill. Conclusion: The MNR method is not suitable to use as the sole remedial approach for Klity Creek (KC2 to KC7). Although MNR is applicable at KC8, it may require up to 377 ± 76 years to restore the sediment to the background Pb concentration. Citation: Phenrat T, Otwong A, Chantharit A, Lowry GV. 2016. Ten-year monitored natural recovery of lead-contaminated mine tailing in Klity Creek, Kanchanaburi Province, Thailand. Environ Health Perspect 124:1511–1520; http://dx.doi.org/10.1289/EHP215 PMID:27157823

Long-term monitoring of persistent organic pollutants (POPs) at the Norwegian Troll station in Dronning Maud Land, Antarctica

NASA Astrophysics Data System (ADS)

Kallenborn, R.; Breivik, K.; Eckhardt, S.; Lunder, C. R.; Manø, S.; Schlabach, M.; Stohl, A.

2013-07-01

A first long-term monitoring of selected persistent organic pollutants (POPs) in Antarctic air has been conducted at the Norwegian research station Troll (Dronning Maud Land). As target contaminants 32 PCB congeners, α- and γ-hexachlorocyclohexane (HCH), trans- and cis-chlordane, trans- and cis-nonachlor, p,p'- and o,p-DDT, DDD, DDE as well as hexachlorobenzene (HCB) were selected. The monitoring program with weekly samples taken during the period 2007-2010 was coordinated with the parallel program at the Norwegian Arctic monitoring site (Zeppelin mountain, Ny-Ålesund, Svalbard) in terms of priority compounds, sampling schedule as well as analytical methods. The POP concentration levels found in Antarctica were considerably lower than Arctic atmospheric background concentrations. Similar to observations for Arctic samples, HCB is the predominant POP compound, with levels of around 22 pg m-3 throughout the entire monitoring period. In general, the following concentration distribution was found for the Troll samples analyzed: HCB > Sum HCH > Sum PCB > Sum DDT > Sum chlordanes. Atmospheric long-range transport was identified as a major contamination source for POPs in Antarctic environments. Several long-range transport events with elevated levels of pesticides and/or compounds with industrial sources were identified based on retroplume calculations with a Lagrangian particle dispersion model (FLEXPART).

Long-term assessment of natural attenuation: statistical approach on soils with aged PAH contamination.

PubMed

Ouvrard, Stéphanie; Chenot, Elodie-Denise; Masfaraud, Jean-François; Schwartz, Christophe

2013-07-01

Natural attenuation processes valorization for PAH-contaminated soil remediation has gained increasing interest from site owners. A misunderstanding of this method and a small amount of data available does not encourage its development. However, monitored natural attenuation (MNA) offers a valuable, cheaper and environmentally friendly alternative to more classical options such as physico-chemical treatments (e.g., chemical oxidation, thermal desorption). The present work proposes the results obtained during a long-term natural attenuation assessment of historically contaminated industrial soils under real climatic conditions. This study was performed after a 10 year natural attenuation period on 60 off-ground lysimeters filled with contaminated soils from different former industrial sites (coking industry, manufactured gas plants) whose initial concentration of PAH varied between 380 and 2,077 mg kg(-1). The analysed parameters included leached water characterization, soil PAH concentrations, evaluation of vegetation cover quality and quantity. Results showed a good efficiency of the PAH dissipation and limited transfer of contaminants to the environment. It also highlighted the importance of the fine soil fractions in controlling PAH reactivity. PAH dissipation through water leaching was limited and did not present a significant risk for the environment. This PAH water concentration appeared however as a good indicator of overall dissipation rate, thereby illustrating the importance of pollutant availability in predicting its degradation potential.

Fact Sheets about the Fourth Unregulated Contaminant Monitoring Rule (UCMR 4)

EPA Pesticide Factsheets

Fact Sheets explaining the program, contaminants for monitoring, water systems applicable, timeframe & monitoring frequency, monitoring locations, critical requirements, data elements and where to find additional information on monitoring data.

Absorption-Edge-Modulated Transmission Spectra for Water Contaminant Monitoring

DTIC Science & Technology

2016-03-31

Naval Research Laboratory Washington, DC 20375-5320 NRL/MR/6390--16-9675 Absorption-Edge-Modulated Transmission Spectra for Water Contaminant ...ABSTRACT c. THIS PAGE 18. NUMBER OF PAGES 17. LIMITATION OF ABSTRACT Absorption-Edge-Modulated Transmission Spectra for Water Contaminant Monitoring...Unlimited Unclassified Unlimited 35 Samuel G. Lambrakos (202) 767-2601 Monitoring of contaminants associated with specific water resources using

Contamination of water and soil by the Erdenet copper-molybdenum mine in Mongolia

NASA Astrophysics Data System (ADS)

Battogtokh, B.; Lee, J.; Woo, N. C.; Nyamjav, A.

2013-12-01

As one of the largest copper-molybdenum (Cu-Mo) mines in the world, the Erdenet Mine in Mongolia has been active since 1978, and is expected to continue operations for at least another 30 years. In this study, the potential impacts of mining activities on the soil and water environments have been evaluated. Water samples showed high concentrations of sulfate, calcium, magnesium, Mo, and arsenic, and high pH values in the order of high to low as follows: tailing water > Khangal River > groundwater. Statistical analysis and the δ2H and δ18O values of water samples indicate that the tailing water directly affects the stream water and indirectly affects groundwater through recharge processes. Soil and stream sediments are highly contaminated with Cu and Mo, which are major elements of ore minerals. Based on the contamination factor (CF), the pollution load index (PLI), and the degree of contamination (Cd), soil appears to be less contaminated than stream sediments. The soil particle size is similar to that of tailing materials, but stream sediments have much coarser particles, implying that the materials have different origins. Contamination levels in stream sediments display a tendency to decrease with distance from the mine, but no such changes are found in soil. Consequently, soil contamination by metals is attributable to wind-blown dusts from the tailing materials, and stream sediment contamination is caused by discharges from uncontained subgrade ore stock materials. Considering the evident impact on the soil and water environment, and the human health risk from the Erdenet Mine, measures to mitigate its environmental impact should be taken immediately including source control, the establishment of a systematic and continuous monitoring system, and a comprehensive risk assessment. Sampling locations around the Erdenet Mine

Oxygen Mass Flow Rate Generated for Monitoring Hydrogen Peroxide Stability

NASA Technical Reports Server (NTRS)

Ross, H. Richard

2002-01-01

Recent interest in propellants with non-toxic reaction products has led to a resurgence of interest in hydrogen peroxide for various propellant applications. Because peroxide is sensitive to contaminants, material interactions, stability and storage issues, monitoring decomposition rates is important. Stennis Space Center (SSC) uses thermocouples to monitor bulk fluid temperature (heat evolution) to determine reaction rates. Unfortunately, large temperature rises are required to offset the heat lost into the surrounding fluid. Also, tank penetration to accomodate a thermocouple can entail modification of a tank or line and act as a source of contamination. The paper evaluates a method for monitoring oxygen evolution as a means to determine peroxide stability. Oxygen generation is not only directly related to peroxide decomposition, but occurs immediately. Measuring peroxide temperature to monitor peroxide stability has significant limitations. The bulk decomposition of 1% / week in a large volume tank can produce in excess of 30 cc / min. This oxygen flow rate corresponds to an equivalent temperature rise of approximately 14 millidegrees C, which is difficult to measure reliably. Thus, if heat transfer were included, there would be no temperature rise. Temperature changes from the surrounding environment and heat lost to the peroxide will also mask potential problems. The use of oxygen flow measurements provides an ultra sensitive technique for monitoring reaction events and will provide an earlier indication of an abnormal decomposition when compared to measuring temperature rise.

Mercury pollution in Malaysia.

PubMed

Hajeb, Parvaneh; Jinap, S; Ismail, Ahmad; Mahyudin, Nor Ainy

2012-01-01

Although several studies have been published on levels of mercury contamination of the environment, and of food and human tissues in Peninsular Malaysia, there is a serious dearth of research that has been performed in East Malaysia (Sabah and Sarawak). Industry is rapidly developing in East Malaysia, and, hence, there is a need for establishing baseline levels of mercury contamination in environmental media in that part of the country by performing monitoring studies. Residues of total mercury and inorganic in food samples have been determined in nearly all previous studies that have been conducted; however, few researchers have analyzed samples for the presence of methlymercury residues. Because methylmercury is the most toxic form of mercury, and because there is a growing public awareness of the risk posed by methylmercury exposure that is associated with fish and seafood consumption, further monitoring studies on methylmercury in food are also essential. From the results of previous studies, it is obvious that the economic development in Malaysia, in recent years, has affected the aquatic environment of the country. Primary areas of environmental concern are centered on the rivers of the west Peninsular Malaysian coast, and the coastal waters of the Straits of Malacca, wherein industrial activities are rapidly expanding. The sources of existing mercury input to both of these areas of Malaysia should be studied and identified. Considering the high levels of mercury that now exists in human tissues, efforts should be continued, and accelerated in the future, if possible, to monitor mercury contamination levels in the coastal states, and particularly along the west Peninsular Malaysian coast. Most studies that have been carried out on mercury residues in environmental samples are dated, having been conducted 20-30 years ago; therefore, the need to collect much more and more current data is urgent. Furthermore, establishing baseline levels of mercury exposure to humans in Malaysia will be useful in establishing the levels at which detrimental effects in both humans and marine life may occur, and therefore the levels at which warning should be raised or limits established. In particular, we believe that two or three monitoring centers should be established in Peninsular Malaysia, and one in East Malaysia for the specific purpose of monitoring for the presence of hazardous environmental chemicals, and particularly monitoring for heavy metals such as mercury that reach food that is subject to consistent human consumption.

Current and future trends in fecal source tracking and deployment in the Lake Taihu Region of China

NASA Astrophysics Data System (ADS)

Hagedorn, Charles; Liang, Xinqiang

The emerging discipline of microbial and/or chemical source tracking (collectively termed fecal source tracking (FST)) is being used to identify origins of fecal contamination in polluted waters in many countries around the world. FST has developed rapidly because standard methods of measuring contamination in water by enumerating fecal indicator bacteria (FIB) such as fecal coliforms and enterococci do not identify the sources of the contamination. FST is an active area of research and development in both the academic and private sectors and includes: Developing and testing new microbial and chemical FST methods. Determining the geographic application and animal host ranges of existing and emerging FST techniques. Conducting experimental comparisons of FST techniques. Combining direct monitoring of human pathogens associated with waterborne outbreaks and zoonotic pathogens responsible for infections among people, wildlife, or domesticated animals with the use of FST techniques. Applying FST to watershed analysis and coastal environments. Designing appropriate statistical and probability analysis of FST data and developing models for mass loadings of host-specific fecal contamination. This paper includes a critical review of FST with emphasis on the extent to which methods have been tested (especially in comparison with other methods and/or with blind samples), which methods are applicable to different situations, their shortcomings, and their usefulness in predicting public health risk or pathogen occurrence. In addition, the paper addresses the broader question of whether FST and fecal indicator monitoring is the best approach to regulate water quality and protect human health. Many FST methods have only been tested against sewage or fecal samples or isolates in laboratory studies (proof of concept testing) and/or applied in field studies where the “real” answer is not known, so their comparative performance and accuracy cannot be assessed. For FST to be quantitative, stability of ratios between host-specific markers in the environment must be established. In addition, research is needed on the correlation between host-specific markers and pathogens, and survival of markers after waste treatments. As a result of the exclusive emphasis on FIB by regulatory agencies, monitoring and FST development has concentrated on FIB rather than the actual pathogens. A more rational approach to regulating water quality might be to use available epidemiological data to identify pathogens of concern in a particular water body, and then use targeted pathogen monitoring coupled with very specific FST approaches to control the pathogens. Baseline monitoring of FIB would be just one tool among many in this example.

Monitoring materials

DOEpatents

Orr, Christopher Henry; Luff, Craig Janson; Dockray, Thomas; Macarthur, Duncan Whittemore

2002-01-01

The apparatus and method provide techniques for effectively implementing alpha and/or beta and/or gamma monitoring of items or locations as desired. Indirect alpha monitoring by detecting ions generated by alpha emissions, in conjunction with beta and/or gamma monitoring is provided. The invention additionally provides for screening of items prior to alpha monitoring using beta and/or gamma monitoring, so as to ensure that the alpha monitoring apparatus is not contaminated by proceeding direct to alpha monitoring of a heavily contaminated item or location. The invention provides additional versatility in the emission forms which can be monitored, whilst maintaining accuracy and avoiding inadvertent contamination.

Novel HPGe Probe solution for Harsh Environments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Clauss, J.; Pirard, B.; Menaa, N.

2015-07-01

In situ measurement is a privileged way of monitoring radioactive contamination compared to analyzing samples in a distant, specialized laboratory. Scintillators based spectrometers offer small footprints and are easy to easy to use, however they do not provide an accurate nuclide identification capability and activities measurement because notably of their limited energy resolution, for instance when low minimum detectable activity (MDA) are required, or in complex mixture of sources. On the other hand, High Purity Germanium (HPGe) detectors provide unmatched nuclide identification capability with the lowest MDA but they are not always of practical use on the field because themore » crystal needs to be cooled down to liquid nitrogen temperature, increasing the overall weight, bulkiness and complexity of the measurement. This paper presents the configuration and performance of a novel turnkey and compact HPGe solution developed by Canberra for radionuclide identification under harsh environments. Radio-contaminations surveys now can be undertaken outdoor under various weather conditions, in contaminated areas, underground or underwater locations (including under sea water), with fast on site deployment. The spectrometer is also designed in a small diameter tubular shape to offer minimal footprint for an operation in narrow and confined spaces. Besides, this innovative design does not mitigate the performances nor the reliability experienced with standard laboratory-grade HPGe spectrometers. This achievement relies on advanced technologies such as the encapsulation of the crystal in ultra-high vacuum (UHV) which provides higher robustness and does not requires thermal cycles faced with regular HPGe equipment. It also relies on a low vibration, low consumption electrical cooler so that no liquid nitrogen is being used. The detector is connected to a state-of-the-art digital spectroscopy suite embedded in an autonomous acquisition station monitoring the cryo-cooler and including the spectroscopy software. This system presented is therefore a new solution to perform high resolution spectroscopy where no current products are compact or robust enough to be installed, for instance for soil and water decontamination measurement when anthropogenic radioactive sources must be identified from natural ones or when low contamination levels are expected, the MDA being 3 to 5 times higher than scintillator-based detectors of similar sizes. Environmental inspection such as well logging for geophysics and mining, water contamination monitoring, or decommissioning works can thus benefits from both ruggedness, mobility without compromise on the nuclide identification or activity measurement capability. (authors)« less

Impact of Scale-Dependent Coupled Processes on Solute Fate and Transport in the Critical Zone: Case Studies Involving Inorganic and Radioactive Contaminants

NASA Astrophysics Data System (ADS)

Jardine, P. M.; Gentry, R. W.

2011-12-01

Soil, the thin veneer of matter covering the Earths surface that supports a web of living diversity, is often abused through anthropogenic inputs of toxic waste. This subsurface regime, coupled with life sustaining surface water and groundwater is known as the "Critical Zone". The disposal of radioactive and toxic organic and inorganic waste generated by industry and various government agencies has historically involved shallow land burial or the use of surface impoundments in unsaturated soils and sediments. Presently, contaminated sites have been closing rapidly and many remediation strategies have chosen to leave contaminants in-place. As such, contaminants will continue to interact with the geosphere and investigations on long term changes and interactive processes is imperative to verify risks. In this presentation we provide a snap-shot of subsurface science research from the past 25 y that seeks to provide an improved understanding and predictive capability of multi-scale contaminant fate and transport processes in heterogeneous unsaturated and saturated environments. Investigations focus on coupled hydrological, geochemical, and microbial processes that control reactive contaminant transport and that involve multi-scale fundamental research ranging from the molecular scale (e.g. synchrotrons, electron sources, arrays) to in situ plume interrogation strategies at the macroscopic scale (e.g. geophysics, field biostimulation, coupled processes monitoring). We show how this fundamental research is used to provide multi-process, multi-scale predictive monitoring and modeling tools that can be used at contaminated sites to (1) inform and improve the technical basis for decision making, and (2) assess which sites are amenable to natural attenuation and which would benefit from source zone remedial intervention.

Effect-directed analysis supporting monitoring of aquatic environments--An in-depth overview.

PubMed

Brack, Werner; Ait-Aissa, Selim; Burgess, Robert M; Busch, Wibke; Creusot, Nicolas; Di Paolo, Carolina; Escher, Beate I; Mark Hewitt, L; Hilscherova, Klara; Hollender, Juliane; Hollert, Henner; Jonker, Willem; Kool, Jeroen; Lamoree, Marja; Muschket, Matthias; Neumann, Steffen; Rostkowski, Pawel; Ruttkies, Christoph; Schollee, Jennifer; Schymanski, Emma L; Schulze, Tobias; Seiler, Thomas-Benjamin; Tindall, Andrew J; De Aragão Umbuzeiro, Gisela; Vrana, Branislav; Krauss, Martin

2016-02-15

Aquatic environments are often contaminated with complex mixtures of chemicals that may pose a risk to ecosystems and human health. This contamination cannot be addressed with target analysis alone but tools are required to reduce this complexity and identify those chemicals that might cause adverse effects. Effect-directed analysis (EDA) is designed to meet this challenge and faces increasing interest in water and sediment quality monitoring. Thus, the present paper summarizes current experience with the EDA approach and the tools required, and provides practical advice on their application. The paper highlights the need for proper problem formulation and gives general advice for study design. As the EDA approach is directed by toxicity, basic principles for the selection of bioassays are given as well as a comprehensive compilation of appropriate assays, including their strengths and weaknesses. A specific focus is given to strategies for sampling, extraction and bioassay dosing since they strongly impact prioritization of toxicants in EDA. Reduction of sample complexity mainly relies on fractionation procedures, which are discussed in this paper, including quality assurance and quality control. Automated combinations of fractionation, biotesting and chemical analysis using so-called hyphenated tools can enhance the throughput and might reduce the risk of artifacts in laboratory work. The key to determining the chemical structures causing effects is analytical toxicant identification. The latest approaches, tools, software and databases for target-, suspect and non-target screening as well as unknown identification are discussed together with analytical and toxicological confirmation approaches. A better understanding of optimal use and combination of EDA tools will help to design efficient and successful toxicant identification studies in the context of quality monitoring in multiply stressed environments. Copyright © 2015 Elsevier B.V. All rights reserved.

Ozone injury to forests across the northeast and north central United States, 1994 - 2010

Treesearch

Gretchen C. Smith; Randall S. Morin; George L. McCaskill

2012-01-01

Ozone is a highly toxic air contaminant that has been shown to decrease tree growth and cause significant disturbance to forested ecosystems. Ozone also causes distinct foliar injury symptoms to certain species (bioindicator plants) that can be used to detect and monitor ozone stress (biomonitoring) in the forest environment. In the early 1990s, the U.S. Forest Service...

Groundwater contamination from waste management sites: The interaction between risk-based engineering design and regulatory policy: 1. Methodology

NASA Astrophysics Data System (ADS)

Massmann, Joel; Freeze, R. Allan

1987-02-01

This paper puts in place a risk-cost-benefit analysis for waste management facilities that explicitly recognizes the adversarial relationship that exists in a regulated market economy between the owner/operator of a waste management facility and the government regulatory agency under whose terms the facility must be licensed. The risk-cost-benefit analysis is set up from the perspective of the owner/operator. It can be used directly by the owner/operator to assess alternative design strategies. It can also be used by the regulatory agency to assess alternative regulatory policy, but only in an indirect manner, by examining the response of an owner/operator to the stimuli of various policies. The objective function is couched in terms of a discounted stream of benefits, costs, and risks over an engineering time horizon. Benefits are in the form of revenues for services provided; costs are those of construction and operation of the facility. Risk is defined as the cost associated with the probability of failure, with failure defined as the occurrence of a groundwater contamination event that violates the licensing requirements established for the facility. Failure requires a breach of the containment structure and contaminant migration through the hydrogeological environment to a compliance surface. The probability of failure can be estimated on the basis of reliability theory for the breach of containment and with a Monte-Carlo finite-element simulation for the advective contaminant transport. In the hydrogeological environment the hydraulic conductivity values are defined stochastically. The probability of failure is reduced by the presence of a monitoring network operated by the owner/operator and located between the source and the regulatory compliance surface. The level of reduction in the probability of failure depends on the probability of detection of the monitoring network, which can be calculated from the stochastic contaminant transport simulations. While the framework is quite general, the development in this paper is specifically suited for a landfill in which the primary design feature is one or more synthetic liners in parallel. Contamination is brought about by the release of a single, inorganic nonradioactive species into a saturated, high-permeability, advective, steady state horizontal flow system which can be analyzed with a two-dimensional analysis. It is possible to carry out sensitivity analyses for a wide variety of influences on this system, including landfill size, liner design, hydrogeological parameters, amount of exploration, extent of monitoring network, nature of remedial schemes, economic factors, and regulatory policy.

PubMed Central

Genovese, C.; Facciolà, A.; Palamara, M.A.R.; Squeri, R.

2017-01-01

Summary Introduction. Nosocomial infections are one of the greatest problems in public health. Several studies have highlighted the role played by the hospital environment as a possible source of transmission of nosocomial pathogens. Methods. A five-year monitoring of bacterial contamination on healthcare workers hands, surfaces most closely in contact with inpatient wards, operating theatres and "at rest" and "in use" operating theatre air samples. For the samples, we used sterile swabs, contact slides, manual API, and automated VITEK systems for identification. Results. In the five-year period, a total of 9396 samples were collected and analysed. In ward patients, 4398 samplings were carried out with 4.7%, 9.4%, 7%, 10.8% and 7.9% positive results respectively from 2010 to 2014. For hands, 648 samplings were carried out, with a positivity of 40.74%. In operating theatres, 4188 samples were taken, with a positivity of 11.9%. Regarding air in empty and full theatres, 1962 samplings were carried out with a positivity rate equal to 31.9%. The monitoring showed a low rate of contamination with a progressive decrease in the fiveyear period on operating theatres surfaces and hands, while there was an increase in the surgical site wards and in the air of operating rooms. Conclusions. Our investigation has revealed the presence of pathogens on the assessed surfaces and the need for environmental monitoring, which can be a valuable tool for reducing contamination. PMID:28900357

Contaminant treatment method

DOEpatents

Shapiro, Andrew Philip; Thornton, Roy Fred; Salvo, Joseph James

2003-01-01

The present invention provides a method for treating contaminated media. The method comprises introducing remediating ions consisting essentially of ferrous ions, and being peroxide-free, in the contaminated media; applying a potential difference across the contaminated media to cause the remediating ions to migrate into contact with contaminants in the contaminated media; chemically degrading contaminants in the contaminated media by contact with the remediating ions; monitoring the contaminated media for degradation products of the contaminants; and controlling the step of applying the potential difference across the contaminated media in response to the step of monitoring.

Measurement of long-term outgassing from the materials used on the MSX spacecraft

NASA Astrophysics Data System (ADS)

Boies, Mark T.; Green, B. David; Galica, Gary E.; Uy, O. Manuel; Benson, Richard C.; Silver, David M.; Wood, Bob E.; Lesho, Jeffrey C.; Hall, David F.; Dyer, James S.

2000-09-01

The Midcourse Space Experiment (MSX) spacecraft was specifically designed and processed to minimize contamination. This spacecraft represents a best case scenario of spacecraft induced environment. The contamination instrument suite consisted of 10 sensors for monitoring the gaseous and particulate environment. The Total Pressure Sensor (TPS) has continuously measured the ambient local pressure surrounding MSX since its launch on April 24, 1996. The sensor's primary goal was to monitor the early mission (less than one week) ambient pressure surrounding the spacecraft's optical telescopes and to indicate when environmental conditions were acceptable for opening the protective covers. However, the instrument has illustrated that it is quite robust and has successfully measured the long-term decay of the pressure environment. The primary constituent of the atmosphere is water outgassed from the thermal blankets of the spacecraft. The water-induced environment was expected to rapidly decay over the first few months to levels more closely approaching the natural environment. The data generally shows decay toward this level, however, the pressure is quite variable with time and can be influenced by discrete illumination and spacecraft orbital events. Several experiments conducted yearly indicate that the thermal blankets retain significant quantities of water. The local pressure due to water vapor is shown to increase by a factor of 100 from direct solar illumination. Moreover, the multi-layer construction of the blankets causes them to form a deep reservoir that continues to be a source of water vapor 3+ years into the mission. We will present pressure data from several experiments, each separated by one orbital year, that exhibit these water vapor induced pressure busts. The decay and longevity of these bursts will also be discussed.

DNA damage, repair monitoring and epigenetic DNA methylation changes in seedlings of Chernobyl soybeans.

PubMed

Georgieva, Mariyana; Rashydov, Namik M; Hajduch, Martin

2017-02-01

This pilot study was carried out to assess the effect of radio-contaminated Chernobyl environment on plant genome integrity 27 years after the accident. For this purpose, nuclei were isolated from root tips of the soybean seedlings harvested from plants grown in the Chernobyl area for seven generations. Neutral, neutral-alkaline, and methylation-sensitive comet assays were performed to evaluate the induction and repair of primary DNA damage and the epigenetic contribution to stress adaptation mechanisms. An increased level of single and double strand breaks in the radio-contaminated Chernobyl seedlings at the stage of primary root development was detected in comparison to the controls. However, the kinetics of the recovery of DNA breaks of radio-contaminated Chernobyl samples revealed that lesions were efficiently repaired at the stage of cotyledon. Methylation-sensitive comet assay revealed comparable levels in the CCGG methylation pattern between control and radio-contaminated samples with a slight increase of approximately 10% in the latter ones. The obtained preliminary data allow us to speculate about the onset of mechanisms providing an adaptation potential to the accumulated internal irradiation after the Chernobyl accident. Despite the limitations of this study, we showed that comet assay is a sensitive and flexible technique which can be efficiently used for genotoxic screening of plant specimens in natural and human-made radio-contaminated areas, as well as for safety monitoring of agricultural products. Copyright © 2016 Elsevier B.V. All rights reserved.

Remedial investigation/feasibility study report for Lower Watts Bar Reservoir Operable Unit

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1995-03-01

This document is the combined Remedial Investigation and Feasibility Study Report for the lower Watts Bar Reservoir (LWBR) Operable Unit (OU). The LWBR is located in Roane, Rhea, and Meigs counties, Tennessee, and consists of Watts Bar Reservoir downstream of the Clinch river. This area has received hazardous substances released over a period of 50 years from the US Department of Energy`s Oak Ridge Reservation (ORR), a National Priority List site established under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). As required by this law, the ORR and all off-site areas that have received contaminants, including LWBR, mustmore » be investigated to determine the risk to human health and the environment resulting from these releases, the need for any remedial action to reduce these risks, and the remedial actions that are most feasible for implementation in this OU. Contaminants from the ORR are primarily transported to the LWBR via the Clinch River. There is little data regarding the quantities of most contaminants potentially released from the ORR to the Clinch River, particularly for the early years of ORR operations. Estimates of the quantities released during this period are available for most radionuclides and some inorganic contaminants, indicating that releases 30 to 50 years ago were much higher than today. Since the early 1970s, the release of potential contaminants has been monitored for compliance with environmental law and reported in the annual environmental monitoring reports for the ORR.« less

TOOLS FOR ASSESSING MONITORED NATURAL RECOVERY OF PCB-CONTAMINATED SEDIMENTS

EPA Science Inventory

Management of contaminated sediments poses many challenges due to varied contaminants and volumes of sediments to manage. dredging, capping, and monitored natural recovery (MNR) are the primary approaches at this time for managing contaminated sediment risks. Understanding how we...

Groundwater monitoring program plan and conceptual site model for the Al-Tuwaitha Nuclear Research Center in Iraq.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Copland, John Robin; Cochran, John Russell

2013-07-01

The Radiation Protection Center of the Iraqi Ministry of Environment is developing a groundwater monitoring program (GMP) for the Al-Tuwaitha Nuclear Research Center located near Baghdad, Iraq. The Al-Tuwaitha Nuclear Research Center was established in about 1960 and is currently being cleaned-up and decommissioned by Iraqs Ministry of Science and Technology. This Groundwater Monitoring Program Plan (GMPP) and Conceptual Site Model (CSM) support the Radiation Protection Center by providing: A CSM describing the hydrogeologic regime and contaminant issues, recommendations for future groundwater characterization activities, and descriptions of the organizational elements of a groundwater monitoring program. The Conceptual Site Model identifiesmore » a number of potential sources of groundwater contamination at Al-Tuwaitha. The model also identifies two water-bearing zones (a shallow groundwater zone and a regional aquifer). The depth to the shallow groundwater zone varies from approximately 7 to 10 meters (m) across the facility. The shallow groundwater zone is composed of a layer of silty sand and fine sand that does not extend laterally across the entire facility. An approximately 4-m thick layer of clay underlies the shallow groundwater zone. The depth to the regional aquifer varies from approximately 14 to 17 m across the facility. The regional aquifer is composed of interfingering layers of silty sand, fine-grained sand, and medium-grained sand. Based on the limited analyses described in this report, there is no severe contamination of the groundwater at Al-Tuwaitha with radioactive constituents. However, significant data gaps exist and this plan recommends the installation of additional groundwater monitoring wells and conducting additional types of radiological and chemical analyses.« less

Development, application, and sensitivity analysis of a water quality index for drinking water management in small systems.

PubMed

Scheili, A; Rodriguez, Manuel J; Sadiq, R

2015-11-01

The aim of this study was to produce a drinking water assessment tool for operators of small distribution systems. A drinking water quality index (DWQI) was developed and applied to small systems based on the water quality index of the Canadian Council of Ministers of Environment. The drinking water quality index was adapted to specific needs by creating four drinking water quality scenarios. First, the temporal and spatial dimensions of drinking water quality variability were taken into account. The DWQI was designed to express global drinking water quality according to different monitoring frequencies. Daily, monthly, and seasonal assessment was also considered. With the data made available, it was possible to use the index as a spatial monitoring tool and express water quality in different points in the distribution system. Moreover, adjustments were made to prioritize the type of contaminant to monitor. For instance, monitoring contaminants with acute health effects led to a scenario based on daily measures, including easily accessible and affordable water quality parameters. On the other hand, contaminants with chronic effects, especially disinfection by-products, were considered in a seasonal monitoring scenario where disinfection by-product reference values were redefined according to their seasonal variability. A sensitivity analysis was also carried out to validate the index. Globally, the DWQI developed is adapted to the needs of small systems. In fact, expressing drinking water quality using the DWQI contributes to the identification of problematic periods and segments in the distribution system. Further work may include this index in the development of a customized decision-making tool for small-system operators and managers.

Environment contamination by mycotoxins and their occurrence in food and feed: Physiological aspects and economical approach.

PubMed

Capcarova, Marcela; Zbynovska, Katarina; Kalafova, Anna; Bulla, Jozef; Bielik, Peter

2016-01-01

The contamination of food and feed by mycotoxins as toxic metabolites of fungi is a risk not only for consumers resulting in various embarrassment regarding health status and well-being, but also for producers, companies and export market on the ground of economic losses and ruined stability of economic trade. As it is given in historical evidence, the contamination of food by mycotoxins is a topic as old as a history of mankind, finding some evidence even in the ancient books and records. Nowadays, the mycotoxins are used in modern biotechnological laboratories and are considered an agent for targeting the specific cells (e.g., defected cells to eliminate them). However, this promising procedure is only the beginning. More concern is focused on mycotoxins as abiotic hazard agents. The dealing with them, systematic monitoring, and development of techniques for their elimination from agricultural commodities are worldwide issues concerning all countries. They can be found alone or in co-occurrence with other mycotoxins. Thus, this review aims to provide widened information regarding mycotoxins contamination in environment with the consequences on health of animals and humans. The inevitability for more data that correctly determine the risk points linked to mycotoxins occurrence and their specific reactions in the environment is demonstrated. This review includes various symptoms in animals and humans that result from mycotoxin exposure. For better understanding of mycotoxin's impact on animals, the sensitivities of various animal species to various mycotoxins are listed. Strategies for elimination and preventing the risks of mycotoxins contamination as well as economical approach are discussed. To complete the topic, some data from past as historical evidences are presented.

Revealing Pesticide Residues Under High Pesticide Stress in Taiwan's Agricultural Environment Probed by Fresh Honey Bee (Hymenoptera: Apidae) Pollen.

PubMed

Nai, Yu-Shin; Chen, Tsui-Yao; Chen, Yi-Cheng; Chen, Chun-Ting; Chen, Bor-Yann; Chen, Yue-Wen

2017-10-01

Significant pesticide residues are among the most serious problems for sustainable agriculture. In the beekeeping environment, pesticides not only impact a honey bee's survival, but they also contaminate bee products. Taiwan's agricultural environment has suffered from pesticide stress that was higher than that found in Europe and America. This study deciphered problems of pesticide residues in fresh honey bee pollen samples collected from 14 monitoring apiaries in Taiwan, which reflected significant contaminations within the honey bee population. In total, 155 pollen samples were screened for 232 pesticides, and 56 pesticides were detected. Among the residues, fluvalinate and chlorpyrifos showed the highest concentrations, followed by carbendazim, carbaryl, chlorfenapyr, imidacloprid, ethion, and flufenoxuron. The average frequency of pesticide residues detected in pollen samples was ca. 74.8%. The amounts and types of pesticides were higher in winter and in southwestern Taiwan. Moreover, five of these pollen samples were contaminated with 11-15 pesticides, with average levels between 1,560 and 6,390 μg/kg. Compared with the literature, this study emphasized that pollen gathered by honey bee was highly contaminated with more pesticides in Taiwan than in the America, France, and Spain. The ubiquity of pesticides in the pollen samples was likely due to the field applications of common pesticides. Recently, the Taiwanese government began to improve the pesticide policy. According to the resurvey data in 2016, there were reductions in several pesticide contamination parameters in pollen samples from west to southwest Taiwan. A long-term investigation of pollen pesticide residues should be conducted to inspect pesticides usage in Taiwan's agriculture. © The Author 2017. Published by Oxford University Press on behalf of Entomological Society of America. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

Extensive severe fever with thrombocytopenia syndrome virus contamination in surrounding environment in patient rooms.

PubMed

Ryu, B-H; Kim, J Y; Kim, T; Kim, M-C; Kim, M J; Chong, Y-P; Lee, S-O; Choi, S-H; Kim, Y S; Woo, J H; Kim, S-H

2018-01-31

Severe fever with thrombocytopenia syndrome (SFTS) is an emerging tick-borne disease in Korea and China. Although there is previous evidence of person-to-person transmission via direct contact with body fluids, the role of environmental contamination by SFTS virus (SFTSV) in healthcare settings has not been established. We therefore investigated the contamination of the healthcare environment by SFTSV. We investigated the possible contamination of hospital air and surfaces with SFTSV transmission by collecting air and swabbing environmental surface samples in two hospitals treating six SFTS patients between March and September 2017. The samples were tested using real-time RT-PCR for SFTS M and S segments. Of the six SFTS patients, four received mechanical ventilation and three died. Five rooms were occupied by those using mechanical ventilation or total plasma exchange therapy in isolation rooms without negative pressure and one room was occupied by a patient bedridden due to SFTS. SFTSV was detected in 14 (21%) of 67 swab samples. Five of 24 swab samples were obtained from fomites including stethoscopes, and 9 of 43 were obtained from fixed structures including doorknobs and bed guardrails. Some samples from fixed structures such as television monitors and sink tables were obtained in areas remote from the patients. SFTSV RNA was not detected in five air samples from three patients' rooms. Our data suggest that SFTSV contamination was extensive in surrounding environments in SFTS patients' rooms. Therefore, more strict isolation methods and disinfecting procedures should be considered when managing SFTS patients. Copyright © 2018 European Society of Clinical Microbiology and Infectious Diseases. Published by Elsevier Ltd. All rights reserved.

A national-scale assessment of micro-organic contaminants in groundwater of England and Wales.

PubMed

Manamsa, Katya; Crane, Emily; Stuart, Marianne; Talbot, John; Lapworth, Dan; Hart, Alwyn

2016-10-15

A large variety of micro-organic (MO) compounds is used in huge quantities for a range of purposes (e.g. manufacturing, food production, healthcare) and is now being frequently detected in the aquatic environment. Interest in the occurrence of MO contaminants in the terrestrial and aquatic environments continues to grow, as well as in their environmental fate and potential toxicity. However, the contamination of groundwater resources by MOs has a limited evidence base compared to other freshwater resources. Of particular concern are newly 'emerging contaminants' such as pharmaceuticals and lifestyle compounds, particularly those with potential endocrine disrupting properties. While groundwater often has a high degree of protection from pollution due to physical, chemical and biological attenuation processes in the subsurface compared to surface aquatic environments, trace concentrations of a large range of compounds are still detected in groundwater and in some cases may persist for decades due to the long residence times of groundwater systems. This study provides the first national-scale assessment of micro-organic compounds in groundwater in England and Wales. A large set of monitoring data was analysed to determine the relative occurrence and detected concentrations of different groups of compounds and to determine relationships with land-use, aquifer type and groundwater vulnerability. MOs detected including emerging compounds such as caffeine, DEET, bisphenol A, anti-microbial agents and pharmaceuticals as well as a range of legacy contaminants including chlorinated solvents and THMs, petroleum hydrocarbons, pesticides and other industrial compounds. There are clear differences in MOs between land-use types, particularly for urban-industrial and natural land-use. Temporal trends of MO occurrence are assessed but establishing long-term trends is not yet possible. Copyright © 2016 British Geological Survey, NERC. Published by Elsevier B.V. All rights reserved.

Radiation monitoring systems as a tool for assessment of accidental releases at the Chernobyl and Fukushima NPPs

NASA Astrophysics Data System (ADS)

Shershakov, Vjacheslav; Bulgakov, Vladimir

2013-04-01

The experience gained during mitigation of the consequences of the accidents at the Chernobyl and Fukushima NPPs has shown that what makes different the decision-making in case of nuclear accidents is that the greatest benefit from decision-making can be achieved in the early phase of an accident. Support to such process can be provided only by a real-time decision-making support system. In case of a nuclear accident the analysis of the situation and decision-making is not feasible without an operational radiation monitoring system, international data exchange and automated data processing, and the use of computerized decision-making support systems. With this in mind, in the framework of different international programs on the Chernobyl-related issues numerous projects were undertaken to study and develop a set of methods, algorithms and programs providing effective support to emergency response decision-making, starting from accident occurrence to decision-making regarding countermeasures to mitigate effects of radioactive contamination of the environment. The presentation focuses results of the analysis of radiation monitoring data and, on this basis, refining or, for many short-lived radionuclides, reconstructing the source term, modeling dispersion of radioactivity in the environment and assessing its impacts. The obtained results allowed adding and refining the existing estimates and in some cases reconstructing doses for the public on the territories contaminated as a result of the Chernobyl accident. The activities were implemented in two stages. In the first stage, several scenarios for dispersion of Chernobyl-related radioactivity were developed. For each scenario cesium-137 dispersion was estimated and these estimates were compared with measurement data. In the second stage, the scenario which showed the best agreement of calculations and measurements was used for modeling the dispersion of iodine-131and other short-lived radionuclides. The described approach was used for assessing the consequences at the Fukushima NPP. These results are also provided in the presentation. References 1. Kelly G.N., Ehrhardt J., Shershakov V.M.. Decision Support for Off-Site Emergency Preparedness in Europe. Radiation Protection Dosimetry, Vol. 64 Nos. 1-2, 1996, pp. 129-142. 2. Ehrhardt J., Shershakov V.M. Real-time on-line decision support systems (RODOS) for off-site emergency management following a nuclear accident. EUR 16533, 1996 3. Kelly G.N., Shershakov V.M. (Editors). Environmental contamination, radiation doses and health consequences after the ?hernobyl accident. Radiation Protection Dosimetry. Special Commemorative Issue.Vol. 64, 1996 4. Shershakov V.M. Computer information technology for support of radiation monitoring problems. OECD Proceedings of an International Workshop «Nuclear Emergency Data Management», Zurich, Switzerland, 1998, pp. 377-388 5. Pitkevich V.A., Duba V.V., Ivanov V.K., Tsyb A.F., Shershakov V.M., Golubenkov A.V., Borodin R.V., V.A., Kosykh V.S. Reconstruction of External Dose to the Inhabitants Living in the Contaminated Territory of Russia by the Results of the Accident at the Chernobyl NPP. Health Phys., Vol. 30, No. 1, pp. 54-68, 1995. 6. Shershakov V., Fesenko S., Kryshev I., Semioshkina T. Decision-Aiding Tools for Remediation Strategies. In: Radioactivity in the Environment, Volume 14, Remediation of Contaminated Environments, 2009, pp 41- 120, Elsevier Ltd.

A simple assay system to monitor the potential for contamination during different stages of cryopreservation.

PubMed

Morris, G J

2009-01-01

A simple assay to monitor the potential for contamination during different steps of cryopreservation is described. The assay is based on the contamination of liquid nitrogen using crystals of sucrose hemi-heptahydrate, these are stable in liquid nitrogen, nitrogen vapour and ambient air and can be monitored by a simple assay which allows contamination risks to be evaluated in a direct, rapid manner.

ISSUES IN UNDERSTANDING DERMAL EXPOSURES RESULTING FROM CONTACT WITH CONTAMINATED SURFACES, MEASURING SURFACE CONTAMINATION, AND CHARACTERIZING TRANSFERS

EPA Science Inventory

Although monitoring for surface contamination in work with radioactive materials and dermal monitoring of pesticide exposure to agricultural workers have been standard practice for 50 years, regular surface sampling and dermal monitoring methods have only been applied to indust...

Contamination movement around a permeable reactive barrier at Solid Waste Management Unit 12, Naval Weapons Station Charleston, North Charleston, South Carolina, 2009

USGS Publications Warehouse

Vroblesky, Don A.; Petkewich, Matthew D.; Conlon, Kevin J.

2010-01-01

The ability to monitor the fate and behavior of the plume in the forest is severely limited because the present axis of maximum contamination in that area bypasses all but one of the existing monitoring wells (12MW-12S). Moreover, the 2009 data indicate that there are no optimally placed sentinel wells in the probable path of contaminant transport. Thus the monitoring network is no longer adequate to monitor the groundwater contamination downgradient from the PRB.

[Epidemiology of toxic and infectious risk related to shellfish consumption].

PubMed

Desenclos, J C

1996-10-01

For feeding purposes shellfish filter large amounts of water but also concentrate infectious agents and toxins that are present in the marine environment either naturally or because of pollution. Thus, the consumption of raw or undercooked shellfish is a substantial source of foodborne poisoning, mostly epidemic and sometimes sporadic. Most of shellfish-borne infectious diseases are linked to fecal contamination of the marine environment; they include: thyphoid fever, salmonellosis, shigellosis, campylobacteriosis, cholera, Norwalk or Norwalk-like gastroenteritis and hepatitis A. In warm climates, shellfish contains naturally occurring halopilic Vibrios and may cause severe sporadic infections (septicemias) among very susceptible consumers (immunocompromised). Shellfish also causes outbreaks of paralytic shellfish poisoning (PSP) and diarrheic shellfish poisoning (DSP) when they are contaminated by toxins produced when Dinophisis, a marine plancton, proliferates. Chemical compounds (heavy metals and organic toxins) that are dumped in the environment (soil, air, and water) also reach shellfish harvesting waters where they are cocentrated. Although acute or chronic effects of the chemical contamination of shellfish have not been clearly documented, the cadmium pollution of some shellfish harvesting waters raises a serious problem. Since it is impossible to prevent completely the contamination of coastal waters by any of the agents cited above, the prevention of shellfish-borne diseases requires monitoring of the marine environment and shellfish flesh (coliform count, Dinophysis toxins, heavy metals...). This surveillance allows the classification of growing areas as suitable or not for harvesting and distribution of shellfish. However, this surveillance is not always sensitive enough. Indicators of fecal pollution are particularly not reliable for shellfish viral contamination. A better knowledge of marine biology, the limitation of coastal waters pollution, improved surveillance, the development of more sensitive indicators, the responsabilisation of the industry and the information of the public on the health hazards associated with shellfish consumption are the key issues for the improvement of shellfish-borne disease prevention.

MONITORING OF WATERWAYS FOR EMERGING ...

EPA Pesticide Factsheets

Assessing the potential impact to the aquatic environment from emerging contaminants, entails monitoring a complex mixture (pharmaceuticals, polar pesticides, industrial by- products and degradation products) in natural waters. The presence of these chemicals, often at ultra-trace levels, may be responsible for development of sub-lethal toxic effects in aquatic organisms (i.e., reproductive dysfunction, immune dysfunction, neurological disorders). Conventional sampling techniques (i.e., grab sampling) often are insufficient for detecting these trace levels. An integrative sampler, the Polar Organic Chemical Integrative Sampler (POCIS), developed by the USGS Columbia Environmental Research Center, provided a way to measure the time-weighted average concentrations of these complex mixtures of contaminants. When POCIS was combined with liquid chromatography/mass spectrometry (LC/MS), it proved to be a powerful tool in identification and quantification of polar anthropogenic contaminants. Data from a pilot study showed the antibiotic azithromycin, illicit drugs [methamphetamine and MDMA (Ecstasy)], polyfluorinated organic acids (PFOA and PFOS) (essential ingredients in the manufacture of fluoropolymers), and surfactants [i.e., diethanolamine polyethylene glycols (DAPGs), polyethylene glycols (PEGs), and nonylphenol ethoxylates (NPEOs)] were all present in the extracts from the effluents of three wastewater treatment plants and other bodies of natural waters. Althoug

Global styrene oligomers monitoring as new chemical contamination from polystyrene plastic marine pollution.

PubMed

Kwon, Bum Gun; Koizumi, Koshiro; Chung, Seon-Yong; Kodera, Yoichi; Kim, Jong-Oh; Saido, Katsuhiko

2015-12-30

Polystyrene (PS) plastic marine pollution is an environmental concern. However, a reliable and objective assessment of the scope of this problem, which can lead to persistent organic contaminants, has yet to be performed. Here, we show that anthropogenic styrene oligomers (SOs), a possible indicator of PS pollution in the ocean, are found globally at concentrations that are higher than those expected based on the stability of PS. SOs appear to persist to varying degrees in the seawater and sand samples collected from beaches around the world. The most persistent forms are styrene monomer, styrene dimer, and styrene trimer. Sand samples from beaches, which are commonly recreation sites, are particularly polluted with these high SOs concentrations. This finding is of interest from both scientific and public perspectives because SOs may pose potential long-term risks to the environment in combination with other endocrine disrupting chemicals. From SOs monitoring results, this study proposes a flow diagram for SOs leaching from PS cycle. Using this flow diagram, we conclude that SOs are global contaminants in sandy beaches around the world due to their broad spatial distribution. Copyright © 2015 Elsevier B.V. All rights reserved.

[Status of lead exposure and its impact on health of workers in an accumulator factory].

PubMed

Liang, Jiabin; Zhang, Jian; Guo, Xiaojing; Mai, Jianping; Wang, Zhi; Liu, Yimin

2014-02-01

To identify the occupational hazard factors in an accumulator factory, to analyze the status of internal and external lead exposure and evaluate the impact of lead exposure on the health of workers in the accumulator industry, and to provide a theoretical basis for improved lead exposure criteria and technical support for the control of lead contamination in the accumulator industry. An on-site investigation was carried out to monitor and evaluate the lead fume and dust in the workplaces of an accumulator factory, and occupational health examination was performed in all workers. The occupational hazard safeguards in the accumulator factory were unadvanced. The contamination of lead fume and dust was serious. The abnormal rate of blood lead was up to 79.80%, and many workers developed anemia and mild peripheral nerve disease. Lead contamination is serious in the accumulator factory, leading to poor health of workers. It is essential to take effective control measures, improve the working environment, provide occupational health education, increase workers' self-protection awareness, and periodically conduct occupational hazard monitoring and health surveillance. The government must reinforce occupational health supervision of such enterprises.

Fumigants and related chemicals in foods: review of residue findings, contamination sources, and analytical methods.

PubMed

Daft, J L

1991-03-01

Public concern over chemical residues in foods increased in the United States during the early 1980s. Potentially hazardous levels of ethylene dibromide (EDB), a relatively non-volatile fumigant, were detected in several finished grain-based products by governmental food-monitoring laboratories. As a result, the U.S. Environmental Protection Agency banned the use of EDB as a fumigant in 1983. Commercial fumigators then began using more of the highly volatile chemicals such as methyl bromide and phosphine. These chemicals are less likely to leave residues on stored crops than the previously used fumigants such as EDB, chloroform, and carbon tetrachloride. However, trace residues of many pest-control fumigants and related industrial chemicals are currently found in assorted foods. This contamination may come from the original fumigation of stored crops, or from the industrial chemicals occurring in the environment and in food processing chains. No potential health problem is indicated at this time. Yet scientists continue to uncover the sources of this chemical contamination, and to develop better methods to monitor foods for it. They also seek better ways to protect foodstuffs from pests prior to human consumption.

Pollution monitoring using networks of honey bees

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bromenshenk, J.J.; Dewart, M.L.; Thomas, J.M.

1983-08-01

Each year thousands of chemicals in large quantities are introduced into the global environment and the need for effective methods of monitoring these substances has steadily increased. Most monitoring programs rely upon instrumentation to measure specific contaminants in air, water, or soil. However, it has become apparent that humans and their environment are exposed to complex mixtures of chemicals rather than single entities. As our ability to detect ever smaller quantities of pollutants has increased, the biological significance of these findings has become more uncertain. Also, it is clear that monitoring efforts should shift from short-term studies of easily identifiablemore » sources in localized areas to long-term studies of multiple sources over widespread regions. Our investigations aim at providing better tools to meet these exigencies. Honey bees are discussed as an effective, long-term, self-sustaining system for monitoring environmental impacts. Our results indicate that the use of regional, and possibly national or international, capability can be realized with the aid of beekeepers in obtaining samples and conducting measurements. This approach has the added advantage of public involvement in environmental problem solving and protection of human health and environmental quality.« less

Using bald eagles to track spatial (1999-2008) and temporal (1987-1992, 1999-2003, and 2004-2008) trends of contaminants in Michigan's aquatic ecosystems.

PubMed

Wierda, Michael R; Leith, Katherine F; Roe, Amy S; Grubb, Teryl G; Sikarskie, James G; Best, David A; Pittman, H Tyler; Fuentes, Latice; Simon, Kendall L; Bowerman, William

2016-08-01

The bald eagle (Haliaeetus leucocephalus) is an extensively researched tertiary predator. Studies have delineated information about its life history and the influences of various stressors on its reproduction. Due to the bald eagle's position at the top of the food web, it is susceptible to biomagnification of xenobiotics. The Michigan Department of Environmental Quality implemented a program in 1999 to monitor persistent chemicals including polychlorinated biphenols (PCBs) and dichlorodiphenyltrichloroethane (DDE). The objectives of the present study were to evaluate spatial and temporal trends of PCBs and organochlorine pesticides in nestling bald eagles of Michigan. The authors' study found that concentrations of PCBs and DDE were higher in Great Lakes areas with Lakes Michigan and Lake Huron having the highest concentrations of DDE and Lake Erie having the highest concentrations of PCBs. Temporally (1987-1992, 1999-2003, and 2004-2008) the present study found declines in PCB and DDE concentrations with a few exceptions. Continued monitoring of Michigan bald eagle populations is suggested for a couple of reasons. First, nestling blood contaminant levels are an appropriate method to monitor ecosystem contaminant levels. Second, from 1999 to 2008 PCB and DDE concentrations for 30% and 40%, respectively, of the nestling eagles sampled were above the no observable adverse effect level (NOAEL) for bald eagles. Lastly, with the continued development and deployment of new chemistries a continuous long term monitoring program is an invaluable resource. Environ Toxicol Chem 2016;35:1995-2002. © 2016 SETAC. © 2016 SETAC.

A Risk-Based Characterization of Sediment Contamination by Legacy and Emergent Contaminants of Concern in Coastal British Columbia, Canada.

PubMed

Morales-Caselles, Carmen; Desforges, Jean-Pierre W; Dangerfield, Neil; Ross, Peter S

2017-08-01

Sediments have long been used to help describe pollution sources, contaminated sites, trends over time, and habitat quality for marine life. We collected surficial sediments from 12 sites at an average seawater depth of 25 m in three near-urban areas of the Salish Sea (British Columbia, Canada) to investigate habitat quality for marine life, including heavily contaminated killer whales. Samples were analyzed using high-resolution instrumentation for a wide variety of congeners of polychlorinated biphenyls (PCBs), polybrominated diphenylethers (PBDEs), hexabromocyclododecane (HBCDD), polybrominated biphenyls, polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans, organochlorine pesticides, and polychlorinated naphthalenes (PCNs). The top six contaminant classes detected in sediments were ∑PCB > ∑PBDE > ∑PCDD/F > DDT > ∑HBCDD > ∑PCN. Near-urban harbor sediments had up to three orders of magnitude higher concentrations of contaminants than more remote sites. With limited tools available to characterize biological risks associated with complex mixtures in the real world, we applied several available approaches to prioritize the pollutant found in our study: (1) sediment quality guidelines from the Canadian Council of Ministers of the Environment where available; (2) US NOAA effects range low and other international guidelines; (3) total TEQ for dioxin-like PCBs for the protection of mammals; and (4) the calculation of risk quotients. Our findings provide an indication of the state of contamination of coastal environments in British Columbia and guidance for chemical regulations and priority setting, as well as management actions including best-practices, dredging, disposal at sea, and source control. In this regard, the legacy PCB and the emergent PBDEs should command continued priority monitoring.

Parametric fate and transport profiling for selective groundwater monitoring at closed landfills: a case study.

PubMed

Sizirici, Banu; Tansel, Berrin

2015-04-01

Monitoring contaminant concentrations in groundwater near closed municipal solid waste landfills requires long term monitoring program which can require significant investment for monitoring efforts. The groundwater monitoring data from a closed landfill in Florida was analyzed to reduce the monitoring efforts. The available groundwater monitoring data (collected over 20 years) were analyzed (i.e., type, concentration and detection level) to identify the trends in concentrations of contaminants and spatial mobility characteristics of groundwater (i.e., groundwater direction, retardation characteristics of contaminants, groundwater well depth, subsoil characteristics), to identify critical monitoring locations. Among the 7 groundwater monitoring well clusters (totaling 22 wells) in landfill, the data from two monitoring well clusters (totaling 7 wells) located along direction of groundwater flow showed similarities (the highest concentrations and same contaminants). These wells were used to assess the transport characteristics of the contaminants. Some parameters (e.g., iron, sodium, ammonia as N, chlorobenzene, 1,4-dichlorobenzene) showed decreasing trends in the groundwater due to soil absorption and retardation. Metals were retarded by ion exchange and their concentration increased by depth indicating soil reached breakthrough over time. Soil depth did not have a significant effect on the concentrations of volatile organic contaminants. Based on the analyses, selective groundwater monitoring modifications were developed for effective monitoring to acquire data from the most critical locations which may be impacted by leachate mobility. The adjustments in the sampling strategy reduced the amount of data collected by as much as 97.7% (i.e., total number of parameters monitored). Effective groundwater sampling strategies can save time, effort and monitoring costs while improving the quality of sample handling and data analyses for better utilization of post closure monitoring funds. Copyright © 2015 Elsevier Ltd. All rights reserved.

Application of Trophic Magnification Factors (TMFs) Under the ...

EPA Pesticide Factsheets

Directive 2013/39/EU amending and updating the Water Framework Directive (2000/60/EC) and its Daughter Directive (the so-called EQS Directive: 2008/105/EC) sets Environmental Quality Standards for biota (EQSbiota) for a number of bioaccumulative chemicals which can pose a threat to both aquatic wildlife (piscivorous birds and mammals) and human health via the consumption of contaminated prey or the intake of contaminated food originating from the aquatic environment. Member States (MS) of the European Union will need to establish programs to monitor the concentration of 11 priority substances in biota and assess compliance against these new standards for surface water classification. The biota standards essentially refer to fish and should be applied to the trophic level (TL) at which contaminant concentrations peak, so that the predator of the species at that TL is exposed to the highest contaminant levels in its food. For chemicals that are subject to biomagnification, the peak concentrations are theoretically attained at TL 3 to 4 in freshwater food webs and TL 5 in marine food webs, where the risk of secondary poisoning of top predators should also be considered. An EU-wide guidance effectively addresses the implementation of EQSbiota (EC 2014). Flexibility is allowed in the choice of target species used for monitoring because of the diversity of both habitats and aquatic community composition across Europe. According to that guidance, the consistency and co

Monitoring of the aerobe biodegradation of chlorinated organic solvents by stable isotope analysis

NASA Astrophysics Data System (ADS)

Horváth, Anikó; Futó, István; Palcsu, László

2014-05-01

Our chemical-biological basic research aims to eliminate chlorinated environmental contaminants from aquifers around industrial areas in the frame of research program supported by the European Social Fund (TÁMOP-4.2.2.A-11/1/KONV-2012-0043). The most careful and simplest way includes the in situ biodegradation with the help of cultured and compound specific strains. Numerous members of Pseudomonas bacteria are famous about function of bioremediation. They can metabolism the environmental hazardous chemicals like gas oils, dyes, and organic solvents. Our research based on the Pseudomonas putida F1 strain, because its ability to degrade halogenated hydrocarbons such as trichloroethylene. Several methods were investigated to estimate the rate of biodegradation, such as the measurement of the concentration of the pollutant along the contamination pathway, the microcosm's studies or the compound specific stable isotope analysis. In this area in the Transcarpathian basin we are pioneers in the stable isotope monitoring of biodegradation. The main goal is to find stable isotope fractionation factors by stable isotope analysis, which can help us to estimate the rate and effectiveness of the biodegradation. The subsequent research period includes the investigation of the method, testing its feasibility and adaptation in the environment. Last but not least, the research gives an opportunity to identify the producer of the contaminant based on the stable isotope composition of the contaminant.

Clean assembly and integration techniques for the Hubble Space Telescope High Fidelity Mechanical Simulator

NASA Technical Reports Server (NTRS)

Hughes, David W.; Hedgeland, Randy J.

1994-01-01

A mechanical simulator of the Hubble Space Telescope (HST) Aft Shroud was built to perform verification testing of the Servicing Mission Scientific Instruments (SI's) and to provide a facility for astronaut training. All assembly, integration, and test activities occurred under the guidance of a contamination control plan, and all work was reviewed by a contamination engineer prior to implementation. An integrated approach was followed in which materials selection, manufacturing, assembly, subsystem integration, and end product use were considered and controlled to ensure that the use of the High Fidelity Mechanical Simulator (HFMS) as a verification tool would not contaminate mission critical hardware. Surfaces were cleaned throughout manufacturing, assembly, and integration, and reverification was performed following major activities. Direct surface sampling was the preferred method of verification, but access and material constraints led to the use of indirect methods as well. Although surface geometries and coatings often made contamination verification difficult, final contamination sampling and monitoring demonstrated the ability to maintain a class M5.5 environment with surface levels less than 400B inside the HFMS.

A trench study to assess transfer of pesticides in subsurface lateral flow for a soil with contrasting texture on a sloping vineyard in Beaujolais.

PubMed

Peyrard, X; Liger, L; Guillemain, C; Gouy, V

2016-01-01

Subsurface lateral flow in both texture-contrast soils and catchments with shallow bedrock is suspected to be a non-point source of contamination of watercourses by pesticides used in agriculture. As a case study, the north of the Beaujolais region (eastern France) provides a favorable environment for such contamination due to its agro-pedo-climatic conditions. Environments seen in the Beaujolais region include intense viticulture, permeable and shallow soils, steep hillslopes, and storms that occur during the periods of pesticide application. Watercourse contamination by pesticides has been widely observed in this region, and offsite pesticide transport by subsurface lateral flow is suspected to be involved in diffuse and chronic presence of pesticides in surface water. In order to confirm and quantify the potential role of such processes in pesticide transfer, an automated trench system has been designed. The trench was set up on a steep farmed hillslope in a texture-contrast soil. It was equipped with a tipping bucket flow meter and an automatic sampler to monitor pesticide concentrations in lateral flow at fine resolution, by means of a flow-dependent sampling strategy. Four pesticides currently used in vine growing were studied to provide a range of mobility properties: one insecticide (chlorpyrifos-methyl) and three fungicides (spiroxamine, tebuconazole, and dimethomorph). With this system, it was possible to study pesticide concentration dynamics in the subsurface lateral flow, generated by substantial rainfall events following pesticide applications. The experimental design ascertained to be a suitable method in which to monitor subsurface lateral flow and related transfer of pesticides.

New approach to the determination of contaminants of emerging concern in natural water: study of alprazolam employing adsorptive cathodic stripping voltammetry.

PubMed

Nunes, Chalder Nogueira; Pauluk, Lucas Ely; Dos Anjos, Vanessa Egéa; Lopes, Mauro Chierici; Quináia, Sueli Pércio

2015-08-01

Contaminants of emerging concern (CECs) are chemicals, including pharmaceutical and personal care products, not commonly monitored in the aquatic environment. Pharmaceuticals are nowadays considered as an important environmental contaminant. Chromatography methods which require expensive equipment and complicated sample pretreatment are used for detection of CECs in natural water. Thus, in this study we proposed a simple, fast, and low-cost voltammetric method as a screening tool for the determination of CECs in natural water prior to chromatography. A case study was conducted with alprazolam (benzodiazepine). The method was optimized and validated in-house. The limit of quantification was 0.4 μg L(-1) for a 120 s preconcentration time. The recoveries ranged from 93 to 120 % for accuracy tests. A further proposal aim was to determine for the first time the occurrence of alprazolam in Brazilian river water and to evaluate its potential use as a marker of contamination by wastewater.

Use of the JPL Electronic Nose to detect leaks and spills in an enclosed environment

NASA Technical Reports Server (NTRS)

Ryan, Margaret A.; Homer, M. L.; Zhou, H.; Pelletier, C. C.; Manatt, K.; Jewell, A. D.; Kisor, A.; Shevade, A. V.; Lewis, C. R.; Taylor, C. J.;

Pharmaceuticals and personal care products in the aquatic environment in China: a review.

PubMed

Bu, Qingwei; Wang, Bin; Huang, Jun; Deng, Shubo; Yu, Gang

2013-11-15

Pharmaceuticals and personal care products (PPCPs) have been detected as contaminants of emerging concern ubiquitously in the aquatic environment in China and worldwide. A clear picture of PPCP contamination in the Chinese aquatic environment is needed to gain insight for both research and regulatory needs (e.g. monitoring, control and management). The occurrence data of 112 PPCPs in waters and sediments in China has been reviewed. In most cases, the detected concentration of these PPCPs in waters and sediments were at ng/L and ng/g levels, which were lower than or comparable to those reported worldwide. A screening level risk assessment (SLERA) identified six priority PPCPs in surface waters, namely erythromycin, roxithromycin, diclofenac, ibuprofen, salicylic acid and sulfamethoxazole. The results of SLERA also revealed that the hot spots for PPCP pollution were those river waters affected by the megacities with high density of population, such as Beijing, Tianjin, Guangzhou and Shanghai. Limitations of current researches and implications for future research in China were discussed. Some regulatory issues were also addressed. Copyright © 2013 Elsevier B.V. All rights reserved.

An "EAR" on environmental surveillance and monitoring: A ...

EPA Pesticide Factsheets

Current environmental monitoring approaches focus primarily on chemical occurrence. However, based on chemical concentration alone, it can be difficult to identify which compounds may be of toxicological concern for prioritization for further monitoring or management. This can be problematic because toxicological characterization is lacking for many emerging contaminants. New sources of high throughput screening data like the ToxCast™ database, which contains data for over 9,000 compounds screened through up to 1,100 assays, are now available. Integrated analysis of chemical occurrence data with HTS data offers new opportunities to prioritize chemicals, sites, or biological effects for further investigation based on concentrations detected in the environment linked to relative potencies in pathway-based bioassays. As a case study, chemical occurrence data from a 2012 study in the Great Lakes Basin along with the ToxCast™ effects database were used to calculate exposure-activity ratios (EARs) as a prioritization tool. Technical considerations of data processing and use of the ToxCast™ database are presented and discussed. EAR prioritization identified multiple sites, biological pathways, and chemicals that warrant further investigation. Biological pathways were then linked to adverse outcome pathways to identify potential adverse outcomes and biomarkers for use in subsequent monitoring efforts. Anthropogenic contaminants are frequently reported in environm

Optical effects module and passive sample array

NASA Technical Reports Server (NTRS)

Linton, R. C.

1983-01-01

The Optical Effects Module (OEM) has the objective to monitor the effects of the deposition and adhesion of both molecular species and particles on optical surfaces in the Shuttle cargo bay environment. The OEM performs inflight measurements of the ultraviolet (253.7 nm) transmittance and diffuse reflectance of five optical samples at regular intervals throughout the orbital mission. Most of the obtained results indicates or implies the absence of a significant accumulation of contamination other than particulates on the samples. The contaminant species (or particulates) adhering to the samples of the Passive Sample Array (PSA) were identified by means of Auger and X-ray energy dispersive analyses. The elements silicon, chlorine, and phosphorus were discovered.

PHYSICAL, CHEMICAL AND BIOLOGICAL TOOLS FOR EVALUATING, MONITORED NATURAL RECOVERY OF PCB CONTAMINATED SEDIMENTS IN LAKE HARTWELL, CLEMSON, SC

EPA Science Inventory

Management of contaminated sediments poses significant challenges due to varied contaminants and volumes of sediments to
manage. Dredging, capping, and monitored natural recovery (MNR) are the primary approaches for managing the contaminated sediment risks.
Understanding ho...

A MULTI-ORD LAB AND REGIONAL ASSESSMENT OF MONITORED NATURAL RECOVERY OF PCB-CONTAMINATED SEDIMENTS IN LAKE HARTWELL, CLEMSON, SC

EPA Science Inventory

Management of contaminated sediments poses many challenges due to varied contaminants and volumes of sediments to manage. Dredging, capping, and monitored natural recovery (MNR) are the primary approaches for managing the contaminated sediment risks. Understanding how well the ...

A PHYSICAL, CHEMICAL, AND BIOLOGICAL ASSESSMENT OF MONITORED NATURAL RECOVERY OF PCB-CONTAMINATED SEDIMENTS IN LAKE HARTWELL, CLEMSON, NC

EPA Science Inventory

Management of contaminated sediments poses significant challenges due to varied contaminants and volumes of sediments to manage. Dredging, capping, and monitored natural recovery (MNR) are the primary approaches for managing the contaminated sediment risks. Understanding how eff...

Monitoring Arthrobacter protophormiae RKJ100 in a 'tag and chase' method during p-nitrophenol bio-remediation in soil microcosms.

PubMed

Pandey, Gunjan; Pandey, Janmejay; Jain, Rakesh K

2006-05-01

Monitoring of micro-organisms released deliberately into the environment is essential to assess their movement during the bio-remediation process. During the last few years, DNA-based genetic methods have emerged as the preferred method for such monitoring; however, their use is restricted in cases where organisms used for bio-remediation are not well characterized or where the public domain databases do not provide sufficient information regarding their sequence. For monitoring of such micro-organisms, alternate approaches have to be undertaken. In this study, we have specifically monitored a p-nitrophenol (PNP)-degrading organism, Arthrobacter protophormiae RKJ100, using molecular methods during PNP degradation in soil microcosm. Cells were tagged with a transposon-based foreign DNA sequence prior to their introduction into PNP-contaminated microcosms. Later, this artificially introduced DNA sequence was PCR-amplified to distinguish the bio-augmented organism from the indigenous microflora during PNP bio-remediation.

Microbial Monitoring of Crewed Habitats in Space—Current Status and Future Perspectives

PubMed Central

Yamaguchi, Nobuyasu; Roberts, Michael; Castro, Sarah; Oubre, Cherie; Makimura, Koichi; Leys, Natalie; Grohmann, Elisabeth; Sugita, Takashi; Ichijo, Tomoaki; Nasu, Masao

2014-01-01

Previous space research conducted during short-term flight experiments and long-term environmental monitoring on board orbiting space stations suggests that the relationship between humans and microbes is altered in the crewed habitat in space. Both human physiology and microbial communities adapt to spaceflight. Microbial monitoring is critical to crew safety in long-duration space habitation and the sustained operation of life support systems on space transit vehicles, space stations, and surface habitats. To address this critical need, space agencies including NASA (National Aeronautics and Space Administration), ESA (European Space Agency), and JAXA (Japan Aerospace Exploration Agency) are working together to develop and implement specific measures to monitor, control, and counteract biological contamination in closed-environment systems. In this review, the current status of microbial monitoring conducted in the International Space Station (ISS) as well as the results of recent microbial spaceflight experiments have been summarized and future perspectives are discussed. PMID:25130885

Comparison, association, and risk assessment of phthalates in floor dust at different indoor environments in Delaware, USA.

PubMed

Bi, Xiaolong; Yuan, Shoujun; Pan, Xiaojun; Winstead, Cherese; Wang, Qiquan

2015-01-01

This study aimed to compare and assess phthalate contamination in various indoor environments. In this study, 44 floor dust samples from different indoor environments in Delaware, USA were collected and analyzed for 14 phthalates using gas chromatography-mass spectrometry. Phthalates were detected in all dust samples with the total concentration ranging from 84 to 7117 mg kg(-1). DEHP (di-2-ethylhexyl phthalate), BzBP (benzylbutyl phthalate), DBP (dibutyl phthalate), and DiBP (di-isobutyl phthalate) were both the most frequently and abundantly detected phthalates. The average concentration of total phthalates in dust from offices, student dorms, gyms, stores, and daycare centers was found to be significantly or insignificantly (P = 0.05) higher than that in dust from houses and apartments. Plastic flooring materials and the application of floor care chemical products were positively associated with total phthalate concentration in floor dust. Toxicological risk assessment indicated that an investigated daycare center in this study was the only indoor environment that may cause the intake amount of DEHP of infants, toddlers, and children via dust ingestion to exceed the reference dose established by the U.S. Environmental Protection Agency (USEPA). Regular monitoring on phthalate contamination in sensitive indoor environments is recommended.

Comparison of Air Impaction and Electrostatic Dust Collector Sampling Methods to Assess Airborne Fungal Contamination in Public Buildings.

PubMed

Normand, Anne-Cécile; Ranque, Stéphane; Cassagne, Carole; Gaudart, Jean; Sallah, Kankoé; Charpin, Denis-André; Piarroux, Renaud

2016-03-01

Many ailments can be linked to exposure to indoor airborne fungus. However, obtaining a precise measurement of airborne fungal levels is complicated partly due to indoor air fluctuations and non-standardized techniques. Electrostatic dust collector (EDC) sampling devices have been used to measure a wide range of airborne analytes, including endotoxins, allergens, β-glucans, and microbial DNA in various indoor environments. In contrast, viable mold contamination has only been assessed in highly contaminated environments such as farms and archive buildings. This study aimed to assess the use of EDCs, compared with repeated air-impactor measurements, to assess airborne viable fungal flora in moderately contaminated indoor environments. Indoor airborne fungal flora was cultured from EDCs and daily air-impaction samples collected in an office building and a daycare center. The quantitative fungal measurements obtained using a single EDC significantly correlated with the cumulative measurement of nine daily air impactions. Both methods enabled the assessment of fungal exposure, although a few differences were observed between the detected fungal species and the relative quantity of each species. EDCs were also used over a 32-month period to monitor indoor airborne fungal flora in a hospital office building, which enabled us to assess the impact of outdoor events (e.g. ground excavations) on the fungal flora levels on the indoor environment. In conclusion, EDC-based measurements provided a relatively accurate profile of the viable airborne flora present during a sampling period. In particular, EDCs provided a more representative assessment of fungal levels compared with single air-impactor sampling. The EDC technique is also simpler than performing repetitive air-impaction measures over the course of several consecutive days. EDC is a versatile tool for collecting airborne samples and was efficient for measuring mold levels in indoor environments. © The Author 2015. Published by Oxford University Press on behalf of the British Occupational Hygiene Society.

Associations of urban environmental pollution with health-related physiological traits in a free-living bird species.

PubMed

Bauerová, Petra; Vinklerová, Jitka; Hraníček, Jakub; Čorba, Vojtěch; Vojtek, Libor; Svobodová, Jana; Vinkler, Michal

2017-12-01

Urban environmental pollution results in contamination of the tissues of synanthropic organisms by toxic trace elements with potential impacts on human health. Passerine birds may serve as convenient indicators of such contamination. In this study we investigated the effect of blood and plumage contamination with heavy metals (lead Pb, cadmium Cd, copper Cu, chromium Cr) and arsenic metalloid (As) on condition, health and ornamental colour in free-living great tit (Parus major) males from 13 cities across the Czech Republic (EU), mist netted during the early breading season (April-May). Our results showed a significant association of heavy metal tissue contamination with immune function, namely leukocyte composition in the avian blood circulation. High heavy metal contamination in bird feathers was linked to a high heterophil/lymphocyte (H/L) ratio, indicating long-term stress in individuals inhabiting heavily polluted environments. In contrast, males with higher concentrations of heavy metals in blood had a lower H/L ratio, assumingly due to the direct toxicity of heavy metals in certain cell types. This is also supported by traits indicative of anaemia-like haemolytic conditions (decreased absolute erythrocyte count) and increased haematopoiesis (a tendency for increased frequencies of immature erythrocytes). We did not find any association of heavy metal contamination with the bacteriolytic activity of plasma complement, feather growth or ornamentation (black breast stripe area and yellow colouration). There was no significant relationship between heavy metal contamination in blood or feathers and PM 10 pollution at the study sites. Our correlational study is the first to show on a large geographic scale that despite strict European air pollution regulations and regular monitoring that have allowed general improvements in atmospheric contamination, non-degradable heavy metals persistently contaminate animal blood and feathers in anthropogenic environments at levels that may have subclinical yet physiological effects with varied influence on health. Copyright © 2017 Elsevier B.V. All rights reserved.

Developing a strategy and closure criteria for radioactive and mixed waste sites in the ORNL remedial action program: Regulatory interface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Trabalka, J.R.

1987-09-01

Some options for stabilization and treatment of contaminated sites can theoretically provide a once-and-for-all solution (e.g., removal or destruction of contaminants). Most realizable options, however, leave contaminants in place (in situ), potentially isolated by physical or chemical, but more typically, by hydrologic measures. As a result of the dynamic nature of the interactions between contaminants, remedial measures, and the environment, in situ stablization measures are likely to have limited life spans, and maintenance and monitoring of performance become an essential part of the scheme. The length of formal institutional control over the site and related questions about future uses ofmore » the land and waters are of paramount importance. Unique features of the ORNL site and environs appear to be key ingredients in achieving the very long term institutional control necessary for successful financing and implementation of in situ stabilization. Some formal regulatory interface is necessary to ensure that regulatory limitations and new guidance which can affect planning and implementation of the ORNL Remedial Action Program are communicated to ORNL staff and potential technical and financial limitations which can affect schedules or alternatives for achievement of long-term site stabilization and the capability to meet environmental regulations are provided to regulatory bodies as early as possible. Such an interface should allow decisions on closure criteria to be based primarily on technical merit and protection of human health and the environment. A plan for interfacing with federal and state regulatory authorities is described. 93 refs., 1 fig., 4 tabs.« less

A review on emerging contaminants in wastewaters and the environment: current knowledge, understudied areas and recommendations for future monitoring.

PubMed

Petrie, Bruce; Barden, Ruth; Kasprzyk-Hordern, Barbara

2015-04-01

This review identifies understudied areas of emerging contaminant (EC) research in wastewaters and the environment, and recommends direction for future monitoring. Non-regulated trace organic ECs including pharmaceuticals, illicit drugs and personal care products are focused on due to ongoing policy initiatives and the expectant broadening of environmental legislation. These ECs are ubiquitous in the aquatic environment, mainly derived from the discharge of municipal wastewater effluents. Their presence is of concern due to the possible ecological impact (e.g., endocrine disruption) to biota within the environment. To better understand their fate in wastewaters and in the environment, a standardised approach to sampling is needed. This ensures representative data is attained and facilitates a better understanding of spatial and temporal trends of EC occurrence. During wastewater treatment, there is a lack of suspended particulate matter analysis due to further preparation requirements and a lack of good analytical approaches. This results in the under-reporting of several ECs entering wastewater treatment works (WwTWs) and the aquatic environment. Also, sludge can act as a concentrating medium for some chemicals during wastewater treatment. The majority of treated sludge is applied directly to agricultural land without analysis for ECs. As a result there is a paucity of information on the fate of ECs in soils and consequently, there has been no driver to investigate the toxicity to exposed terrestrial organisms. Therefore a more holistic approach to environmental monitoring is required, such that the fate and impact of ECs in all exposed environmental compartments are studied. The traditional analytical approach of applying targeted screening with low resolution mass spectrometry (e.g., triple quadrupoles) results in numerous chemicals such as transformation products going undetected. These can exhibit similar toxicity to the parent EC, demonstrating the necessity of using an integrated analytical approach which compliments targeted and non-targeted screening with biological assays to measure ecological impact. With respect to current toxicity testing protocols, failure to consider the enantiomeric distribution of chiral compounds found in the environment, and the possible toxicological differences between enantiomers is concerning. Such information is essential for the development of more accurate environmental risk assessment. Copyright © 2014 The Authors. Published by Elsevier Ltd.. All rights reserved.

Comparison of Two Freshwater Turtle Species as Monitors of Environmental Contamination

DOE Office of Scientific and Technical Information (OSTI.GOV)

Meyers-Schone, L.

1990-01-01

Two species of turtles that occupy different ecological niches were compared for their usefulness as monitors of contamination in freshwater ecosystems. Trachemvs scrinta (Agassiz) (yellow-bellied slider) and Chelvdra sernentina (Linnaeus) (common snapping turtle) were selected for comparison based on species abundance and differences in food habits and sediment contact. A review of the literature on contaminants in turtles and results of preliminary surveys conducted at the field sites, which are included in this study, were used to direct and focus this research project. White Oak Lake, a settling basin for low-level radioactive and nonradioactive contaminants, and Bearden Creek Embayment, anmore » uncontaminated reference site upriver, were used as study sites in the investigation of turtles as indicators of chemical contamination. Turtles were analyzed for concentrations of strontium-go, cesium-137, cobalt 60, and mercury in specific target tissues, and for single-stranded DNA breaks, a non-specific indicator of possible exposure to genotoxic agents in the environment. Significantly higher concentrations of {sup 90}Sr, {sup 137}Cs, {sup 60}Co, and mercury were detected in turtles from White Oak Lake than in turtles from the reference site. In addition, turtles from White Oak Lake contained a significantly greater amount of DNA damage than those from the reference site. Although this suggests greater exposure of White Oak Lake turtles to genotoxic agents, further studies are needed to establish the cause of the enhanced amount of single-stranded breaks. Interspecific comparisons of the turtles from White Oak Lake indicated that diet may play a significant role in the exposure of turtles to certain contaminants. No difference was detected between the concentrations of {sup 90}Sr, {sup 137}Cs, {sup 60}Co between the two species.« less

Learn About the Unregulated Contaminant Monitoring Rule

EPA Pesticide Factsheets

EPA uses the Unregulated Contaminant Monitoring program to collect data for contaminants suspected to be present in drinking water, but that do not have health-based standards set under the Safe Drinking Water Act (SDWA)

Opportunities and challenges of integrating ecological restoration into assessment and management of contaminated ecosystems.

PubMed

Hull, Ruth N; Luoma, Samuel N; Bayne, Bruce A; Iliff, John; Larkin, Daniel J; Paschke, Mark W; Victor, Sasha L; Ward, Sara E

2016-04-01

Ecosystem restoration planning near the beginning of the site assessment and management process ("early integration") involves consideration of restoration goals from the outset in developing solutions for contaminated ecosystems. There are limitations to integration that stem from institutional barriers, few successful precedents, and limited availability of guidance. Challenges occur in integrating expertise from various disciplines and multiple, sometimes divergent interests and goals. The more complex process can result in timing, capacity, communication, and collaboration challenges. On the other hand, integrating the 2 approaches presents new and creative opportunities. For example, integration allows early planning for expanding ecosystem services on or near contaminated lands or waters that might otherwise have been unaddressed by remediation alone. Integrated plans can explicitly pursue ecosystem services that have market value, which can add to funds for long-term monitoring and management. Early integration presents opportunities for improved and productive collaboration and coordination between ecosystem restoration and contaminant assessment and management. Examples exist where early integration facilitates liability resolution and generates positive public relations. Restoration planning and implementation before the completion of the contaminated site assessment, remediation, or management process ("early restoration") can facilitate coordination with offsite restoration options and a regional approach to restoration of contaminated environments. Integration of performance monitoring, for both remedial and restoration actions, can save resources and expand the interpretive power of results. Early integration may aid experimentation, which may be more feasible on contaminated lands than in many other situations. The potential application of concepts and tools from adaptive management is discussed as a way of avoiding pitfalls and achieving benefits in early integration. In any case, there will be challenges with early integration of restoration concepts for contaminated ecosystems, but the benefits are likely to outweigh them. © 2015 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals, Inc. on behalf of Society of Environmental Toxicology & Chemistry (SETAC).

Pharmaceuticals, hormones, personal-care products, and other organic wastewater contaminants in water resources: Recent research activities of the U.S. Geological Survey's toxic substances hydrology program

USGS Publications Warehouse

Focazio, Michael J.; Kolpin, Dana W.; Buxton, Herbert T.

2003-01-01

Recent decades have brought increasing concerns for potential contamination of water resources that could inadvertently result during production, use, and disposal of the numerous chemicals offering improvements in industry, agriculture, medical treatment, and even common household products. Increasing knowledge of the environmental occurrence or toxicological behavior of these contaminants from various studies in Europe, United States, and elsewhere has resulted in increased concern for potential adverse environmental and human health effects (Daughton and Ternes, 1999). Ecologists and public health experts often have incomplete understandings of the toxicological significance of many of these contaminants, particularly long-term, low-level exposure and when they occur in mixtures with other contaminants (Daughton and Ternes, 1999; Kümmerer, 2001). In addition, these ‘emerging contaminants’ are not typically monitored or assessed in ambient water resources. The need to understand the processes controlling the transport and fate of these contaminants in the environment, and the lack of knowledge of the significance of long-term exposures have increased the need to study environmental occurrence down to trace (nanogram per liter) levels. Furthermore, the possibility that mixtures of environmental contaminants may interact synergistically or antagonistically has increased the need to characterize the types of mixtures that are found in our waters. The U.S. Geological Survey’s Toxic Substances Hydrology Program (Toxics Program) is developing information and tools on emerging water-quality issues that will be used to design and improve water-quality monitoring and assessment programs of the USGS and others, and for proactive decision-making by industry, regulators, the research community, and the public (http://toxics.usgs.gov/regional/emc.html). This research on emerging water-quality issues includes a combination of laboratory work to develop new analytical capabilities as well as field work on the occurrence, fate, and effects of these contaminants.

Unmanned aerial vehicles for the assessment and monitoring of environmental contamination: An example from coal ash spills.

PubMed

Messinger, Max; Silman, Miles

2016-11-01

Unmanned aerial vehicles (UAVs) offer new opportunities to monitor pollution and provide valuable information to support remediation. Their low-cost, ease of use, and rapid deployment capability make them ideal for environmental emergency response. Here we present a UAV-based study of the third largest coal ash spill in the United States. Coal ash from coal combustion is a toxic industrial waste material present worldwide. Typically stored in settling ponds in close proximity to waterways, coal ash poses significant risk to the environment and drinking water supplies from both chronic contamination of surface and ground water and catastrophic pond failure. We sought to provide an independent estimate of the volume of coal ash and contaminated water lost during the rupture of the primary coal ash pond at the Dan River Steam Station in Eden, NC, USA and to demonstrate the feasibility of using UAVs to rapidly respond to and measure the volume of spills from ponds or containers that are open to the air. Using structure-from-motion (SfM) imagery analysis techniques, we reconstructed the 3D structure of the pond bottom after the spill, used historical imagery to estimate the pre-spill waterline, and calculated the volume of material lost. We estimated a loss of 66,245 ± 5678 m 3 of ash and contaminated water. The technique used here allows rapid response to environmental emergencies and quantification of their impacts at low cost, and these capabilities will make UAVs a central tool in environmental planning, monitoring, and disaster response. Copyright © 2016 Elsevier Ltd. All rights reserved.

Biochar as enhancement material in natural attenuation systems

NASA Astrophysics Data System (ADS)

Kirmizakis, P.; Doherty, R.; Mendonça, C. A.; Costeira, R.; Allen, C.; Kulakov, L.

2017-12-01

Bioelectrochemical systems (BESs) have gained increasingly popularity over the last years especially in monitoring and clean-up of contaminants. BES are systems that combine wastewater treatment with energy production and resource recovery by harness the electro-activity of microorganisms. BESs consist of two electrodes, an anode and a cathode, separated with a proton-exchange membrane and an external electrical circuit which permits the passage of electrons generated at the anode to the cathode. Here we present a speed up of this natural breakdown process by providing a place to capture the anaerobic contaminants onto Biochar which captures the contaminants and also acts like a high surface area electrode passing electrons to the aerobic environments. For the purpose of this project, identical graphite and Teflon cells were constructed to compare and determine whether a Biochar BES was more efficient than a standard BES and more efficient than Biochar as sorption agent. Current production monitoring used as a real-time view of the process. The Biochar BES out performed both the BES and the Biochar BES in reduction of contaminants across the board. Our results suggest that the maximum growth and electro-activity of the microbial community occurred in the Biochar BES. This is in agreement with microbial findings which suggests that Biochar BES has a less diverse population which is more focused towards degradation and electroactive activity. For further understanding of the results, further geochemical analysis performed to provide additional insight on the process. This works shows clearly the applicability and efficiency of biochar among other electrode and sorption materials and electrical monitoring is versatile experimental tool to the remediation process and can be used as a non-destructive way to indirectly reveal process leading in understanding basic fundamental physical behaviours under specific experimental conditions.

Environmental Management

ScienceCinema

None

2018-01-16

Another key aspect of the NNSS mission is Environmental Management program, which addresses the environmental legacy from historic nuclear weapons related activities while also ensuring the health and safety of present day workers, the public, and the environment as current and future missions are completed. The Area 5 Radioactive Waste Management site receives low-level and mixed low-level waste from some 28 different generators from across the DOE complex in support of the legacy clean-up DOE Environmental Management project. Without this capability, the DOE would not be able to complete the clean up and proper disposition of these wastes. The program includes environmental protection, compliance, and monitoring of the air, water, plants, animals, and cultural resources at the NNSS. Investigation and implementation of appropriate corrective actions to address the contaminated ground water facilities and soils resulting from historic nuclear testing activities, the demolition of abandoned nuclear facilities, as well as installation of ground water wells to identify and monitor the extent of ground water contamination.

Assessment of heavy metal pollution in surface soils and plant material in the post-industrial city of Katowice, Poland.

PubMed

Steindor, Karolina A; Franiel, Izabella J; Bierza, Wojciech M; Pawlak, Beata; Palowski, Bernard F

2016-01-01

This investigation was undertaken to assess the level of environment pollution by biological monitoring. The leaves and bark of popular ornamental trees Acer pseudoplatanus L. and Acer platanoides L. and soil from the sampling sites were used to perform heavy metals pollution monitoring in urban areas with different pollution sources, as well to investigate the suitability of the leaves and bark as bioindicators of Pb, Zn, Cd and Cu pollution. Plant samples were collected at nine locations classified into three pollution groups based on metal content in the soils. The chosen pollution indices were used to assess the level of contamination according to background values. Soils in the Katowice area are found to be relatively heavily contaminated with Pb, Zn and Cd. Both of the maple tree species did not statistically differ in terms of the investigated elements' concentration in leaves or bark. Only bark samples reflected the pollution level, showing differences between the sampling points, and therefore are recommended for biomonitoring purposes.

Implementing AORN recommended practices for sterile technique.

PubMed

Kennedy, Lynne

2013-07-01

Using sterile technique helps prevent the surgical environment from becoming contaminated and thus can help reduce the incidence of surgical site infection. The AORN "Recommended practices for sterile technique" provides guidance for setting up, maintaining, and monitoring a sterile field. Topics include the use of surgical attire and personal protective equipment; appropriate selection and evaluation of surgical gowns, gloves, and drape products for each procedure; use of sterile technique to don sterile gowns and gloves; appropriate methods for establishing and monitoring a sterile field; and techniques to ensure that items such as surgical instruments that may be contaminated are not used. Breaks in sterile technique should be corrected immediately unless the actions necessary would endanger the patient. If remedial actions must be delayed, they should be undertaken as soon as possible. Adhering to best practices for sterile technique requires remaining up to date with new approaches and incorporating these into quality initiatives. Copyright © 2013 AORN, Inc. Published by Elsevier Inc. All rights reserved.

Assessment of molecular contamination in mask pod

NASA Astrophysics Data System (ADS)

Foray, Jean Marie; Dejaune, Patrice; Sergent, Pierre; Gough, Stuart; Cheung, D.; Davenet, Magali; Favre, Arnaud; Rude, C.; Trautmann, T.; Tissier, Michel; Fontaine, H.; Veillerot, M.; Avary, K.; Hollein, I.; Lerit, R.

2008-04-01

Context/ study Motivation: Contamination and especially Airbone Molecular Contamination (AMC) is a critical issue for mask material flow with a severe and fairly unpredictable risk of induced contamination and damages especially for 193 nm lithography. It is therefore essential to measure, to understand and then try to reduce AMC in mask environment. Mask material flow was studied in a global approach by a pool of European partners, especially within the frame of European MEDEA+ project, so called "MUSCLE". This paper deals with results and assessment of mask pod environment in term of molecular contamination in a first step, then in a second step preliminary studies to reduce mask pod influence and contamination due to material out gassing. Approach and techniques: A specific assessment of environmental / molecular contamination along the supply chain was performed by all partners. After previous work presented at EMLC 07, further studies were performed on real time contamination measurement pod at different sites locations (including Mask manufacturing site, blank manufacturing sites, IC fab). Studies were linked to the main critical issues: cleaning, storage, handling, materials and processes. Contamination measurement campaigns were carried out along the mask supply chain using specific Adixen analyzer in order to monitor in real time organic contaminants (ppb level) in mask pods. Key results would be presented: VOC, AMC and humidity level on different kinds of mask carriers, impact of basic cleaning on pod outgassing measurement (VOC, NH3), and process influence on pod contamination... In a second step, preliminary specific pod conditioning studies for better pod environment were performed based on Adixen vacuum process. Process influence had been experimentally measured in term of molecular outgassing from mask pods. Different AMC experimental characterization methods had been carried out leading to results on a wide range of organic and inorganic contaminants: by inline techniques based on Adixen humidity, also VOC and organic sensors, together by off-line techniques already used in the extensive previous mask pods benchmark (TD-GCMS & Ionic Chromatography). Humidity and VOC levels from mask carriers had shown significant reduction after Adixen pod conditioning process. Focus had been made on optimized vacuum step (for AMC) after particles carrier cleaning cycle. Based upon these key results new procedures, as well as guidelines for mask carrier cleaning optimization are proposed to improve pod contamination control. Summary results/next steps: This paper reports molecular contamination measurement campaigns performed by a pool of European partners along the mask supply chain. It allows us to investigate, identify and quantify critical molecular contamination in mask pod, as well as VOC and humidity, issues depending on locations, uses, and carrier's type. Preliminary studies highlight initial process solutions for pods conditioning that are being used for short term industrialization and further industrialized.

Proposal for MSW contaminant classification applied to a tropical aquifer.

PubMed

de Faria, Gabriel Messias Moura; Mondelli, Giulliana

2018-04-01

Groundwater is a natural resource exploited worldwide causing danger due to the lixiviation of waste deposited, which presents high potential degradation. Internationally, regulation aims for the maintenance of the quality of this resource. But the local lithology, mainly in countries with tropical weather, was not considered. This paper has an objective to propose two methodologies of contaminant identification of municipal solid waste (MSW) considering the Brazilian regulation, the local lithology and the temporal aspect. The study site is located in the midwest of São Paulo, at the Marília Formation, Bauru Aquifer, which presents sandstone rich in calcite. At first, the historic monitoring data accumulated between 2002 and 2015 were statistically organized. Then, methodologies of classification of major constituents and contamination method were developed. After these analyses, the compounds that possibly cause anomaly in the local environment are Al, As, Ba, Ca, Cd, Co, Cr, Cu, phosphatic, nitrogenous, and sulfated compounds, Fe, K, Mn, Ni, and Pb. Some of these have lithogenic genesis typical of tropical environment, and others come from the disposed waste. Despite different approaches, both methods demonstrate efficiency in identifying the pollutants presenting distinctions among themselves in conjunction with actual local regulation and the lithogenic source of certain compounds.

Workshop 3.5: Closing the gap between exposure and effects in monitoring studies

USGS Publications Warehouse

Tillitt, Donald E.; Papoulias, Diana M.

2003-01-01

A major challenge to contaminant monitoring programs is the selection of an appropriate suite of measurements for assessing exposure and effects. Early monitoring programs relied solely on residue analysis to detect the organochlorine compounds that were in use at that time. A shift to the use of more transient, less persistent chemicals required that a new set of tools be developed to determine if an organism had been exposed. This led to the development of cellular and biochemical assays that could indicate the presence of these types of chemicals in biota and the environment. However, it was recognized that measures of contaminant presence alone were insufficient to assess the health of biota. As a result, considerable research began to be directed toward development of diagnostic tools for measuring chemical effects in fish and wildlife. Today, contaminant monitoring programs follow a paradigm for study design that emphasizes not only the use of measures of exposure, but also measures of effect. Using data from our monitoring and research studies for hormonally active substances, we discuss a variety of metrics of exposure and effects and their application to specific chemicals, and the current information gaps. We conclude that although several bioindicators of exposure and effect have been promoted and used, to date there continues to be a poor association between cause and effect for endocrine active substances. In part, this is due to the limited number of diagnostic tools that are available and to a lack of basic toxicological information concerning toxicokinetics and mechanisms of action of hormonally active chemicals in fish and wildlife species. In the foreseeable future, both tissue and environmental residue data, despite the many limitations, will continue to be an important component of monitoring programs for hormonally active chemicals as we continue to develop and validate more specific bioindicators of exposure and effects.

Space Science Payloads Optical Properties Monitor (OPM) Mission Flight Anomalies Thermal Analyses

NASA Technical Reports Server (NTRS)

Schmitz, Craig P.

2001-01-01

The OPM was the first space payload that measured in-situ the optical properties of materials and had data telemetered to ground. The OPM was EVA mounted to the Mir Docking Module for an eight-month stay where flight samples were exposed to the Mir induced and natural environments. The OPM was comprised of three optical instruments; a total hemispherical spectral reflectometer, a vacuum ultraviolet spectrometer, and a total integrated scatterometer. There were also three environmental monitors; an atomic oxygen monitor, solar and infrared radiometers, and two temperature-controlled quartz crystal microbalances (to monitor contamination). Measurements were performed weekly and data telemetered to ground through the Mir data system. This paper will describe the OPM thermal control design and how the thermal math models were used to analyze anomalies which occurred during the space flight mission.

Some Case Studies on Metal-Microbe Interactions to Remediate Heavy Metals- Contaminated Soils in Korea

NASA Astrophysics Data System (ADS)

Chon, Hyo-Taek

2015-04-01

Conventional physicochemical technologies to remediate heavy metals-contaminated soil have many problems such as low efficiency, high cost and occurrence of byproducts. Recently bioremediation technology is getting more and more attention. Bioremediation is defined as the use of biological methods to remediate and/or restore the contaminated land. The objectives of bioremediation are to degrade hazardous organic contaminants and to convert hazardous inorganic contaminants to less toxic compounds of safe levels. The use of bioremediation in the treatment of heavy metals in soils is a relatively new concept. Bioremediation using microbes has been developed to remove toxic heavy metals from contaminated soils in laboratory scale to the contaminated field sites. Recently the application of cost-effective and environment-friendly bioremediation technology to the heavy metals-contaminated sites has been gradually realized in Korea. The merits of bioremediation include low cost, natural process, minimal exposure to the contaminants, and minimum amount of equipment. The limitations of bioremediation are length of remediation, long monitoring time, and, sometimes, toxicity of byproducts for especially organic contaminants. From now on, it is necessary to prove applicability of the technologies to contaminated sites and to establish highly effective, low-cost and easy bioremediation technology. Four categories of metal-microbe interactions are generally biosorption, bioreduction, biomineralization and bioleaching. In this paper, some case studies of the above metal-microbe interactions in author's lab which were published recently in domestic and international journals will be introduced and summarized.

Contrasting congener profiles for persistent organic pollutants and PAH monitoring in European storm petrels (Hydrobates pelagicus) breeding in Ireland: a preen oil versus feathers approach.

PubMed

Acampora, Heidi; White, Philip; Lyashevska, Olga; O'Connor, Ian

2018-04-05

Persistent organic pollutants (POPs) and polycyclic aromatic hydrocarbons (PAHs) are anthropogenic contaminants of environmental concern due to their persistence in the environment and capacity to accumulate in biota. Many of these contaminants have been found to have ill effects over wildlife and humans. Birds are known to be particularly affected through endocrine disruption and eggshell thinning. POPs have been banned or restricted through the Stockholm Convention (2001), making monitoring essential for tracking effects of regulation. Seabirds have been used as monitoring tools for being top predators and consuming a diverse array of prey in different trophic levels. Non-destructive sampling has become widely popular using feathers and preen oil, as opposed to carcasses and internal organs. This study aimed to set baseline levels of POP and PAH concentration in a highly pelagic and abundant seabird in Ireland and the Atlantic, the European storm petrel, Hydrobates pelagicus, and to investigate the profiles of contaminant congeners in preen oil and feathers, comparatively. Mean concentrations in preen oil followed: PCB (10.1 ng/g ww) > PAH (7.1 ng/g ww) > OCP (5.4 ng/g ww) > PBDE (3.9 ng/g ww), whilst mean concentrations in feathers followed the order: PAH (38.9 ng/g ww) > PCB (27.2 ng/g ww) > OCP (17.9 ng/g ww) > PBDE (4.5 ng/g ww). Congener profiles highly differed between preen oil and feathers, and little correlation was found between the matrices. These results demonstrate that the sampling of a single matrix alone (preen oil or feathers) might produce confounding results on contamination in seabirds and that more than one matrix is recommended to obtain a full picture of contamination by persistent organic pollutants.

Monitoring Salmonella, Campylobacter, Escherichia coli and Staphylococcus aureus in traditional free-range 'Label Rouge' broiler production: a 23-year survey programme.

PubMed

Salvat, G; Guyot, M; Protino, J

2017-01-01

'Label Rouge' broiler free-range carcasses have been monitored since 1991, and broiler flocks since 2010, for contamination by the main foodborne zoonotic bacteria. Initially, the monitoring plan mainly focused on the surveillance of Salmonella, and on indicators of the overall microbiological quality of free-range broiler carcasses such as Staphylococcus aureus and coliforms, but was extended in 2007 to include Campylobacter enumeration on carcasses and in 2010, to Salmonella in the environment of live birds. Salmonella contamination of free-range broiler carcasses rose to a peak of 16% in 1994 but less than 1% of carcasses are now regularly found to be positive. Indicators of the overall microbiological quality of carcasses are also improving. These results correlate with the low prevalence of Salmonella in free-range broiler breeding and production flocks, and with the continuous improvement of hazard analysis and critical control points in slaughterhouses, the implementation of a good manufacturing practice guide since 1997 and the application of EU regulations on Salmonella since 1998 in France. Regarding Campylobacter counts on carcasses, the situation has been improving continuously over the last few years, even if 2·5% of the carcasses are still contaminated by more than 1000 Campylobacter per g of skin. Although the current control system focusing on Salmonella is based on firm epidemiologic data and offers effective means of control (e.g. slaughtering of positive breeder flocks), existing information on Campylobacter makes it more difficult to formulate an effective control plan for free-range broilers, due to their particular exposure to environmental contamination. This long-term surveillance programme provided an extended view of the evolution of the contamination of free-range broilers and a direct measurement of the impact of mandatory and profession-driven interventions on the microbiological quality of carcasses. © 2016 The Society for Applied Microbiology.

Quantitative evaluation of intensive remedial action using long-term monitoring and tracer data at a DNAPL contaminated site, Wonju, Korea

NASA Astrophysics Data System (ADS)

Lee, S. S.; Kim, H. J.; Kim, M. O.; Lee, K.; Lee, K. K.

2016-12-01

A study finding evidence of remediation represented on monitoring data before and after in site intensive remedial action was performed with various quantitative evaluation methods such as mass discharge analysis, tracer data, statistical trend analysis, and analytical solutions at DNAPL contaminated site, Wonju, Korea. Remediation technologies such as soil vapor extraction, soil flushing, biostimulation, and pump-and-treat have been applied to eliminate the contaminant sources of trichloroethylene (TCE) and to prevent the migration of TCE plume from remediation target zones. Prior to the remediation action, the concentration and mass discharges of TCE at all transects were affected by seasonal recharge variation and residual DNAPLs sources. After the remediation, the effect of remediation took place clearly at the main source zone and industrial complex. By tracing a time-series of plume evolution, a greater variation in the TCE concentrations was detected at the plumes near the source zones compared to the relatively stable plumes in the downstream. The removal amount of the residual source mass during the intensive remedial action was estimated to evaluate the efficiency of the intensive remedial action using analytical solution. From results of quantitative evaluation using analytical solution, it is assessed that the intensive remedial action had effectively performed with removal efficiency of 70% for the residual source mass during the remediation period. Analytical solution which can consider and quantify the impacts of partial mass reduction have been proven to be useful tools for quantifying unknown contaminant source mass and verifying dissolved concentration at the DNAPL contaminated site and evaluating the efficiency of remediation using long-term monitoring data. Acknowledgement : This subject was supported by the Korea Ministry of Environment under "GAIA project (173-092-009) and (201400540010)", R&D Project on Enviornmental Management of Geologic CO2 storage" from the KEITI (Project number:2014001810003).

A novel exploratory chemometric approach to environmental monitorring by combining block clustering with Partial Least Square (PLS) analysis

PubMed Central

2013-01-01

Background Given the serious threats posed to terrestrial ecosystems by industrial contamination, environmental monitoring is a standard procedure used for assessing the current status of an environment or trends in environmental parameters. Measurement of metal concentrations at different trophic levels followed by their statistical analysis using exploratory multivariate methods can provide meaningful information on the status of environmental quality. In this context, the present paper proposes a novel chemometric approach to standard statistical methods by combining the Block clustering with Partial least square (PLS) analysis to investigate the accumulation patterns of metals in anthropized terrestrial ecosystems. The present study focused on copper, zinc, manganese, iron, cobalt, cadmium, nickel, and lead transfer along a soil-plant-snai food chain, and the hepatopancreas of the Roman snail (Helix pomatia) was used as a biological end-point of metal accumulation. Results Block clustering deliniates between the areas exposed to industrial and vehicular contamination. The toxic metals have similar distributions in the nettle leaves and snail hepatopancreas. PLS analysis showed that (1) zinc and copper concentrations at the lower trophic levels are the most important latent factors that contribute to metal accumulation in land snails; (2) cadmium and lead are the main determinants of pollution pattern in areas exposed to industrial contamination; (3) at the sites located near roads lead is the most threatfull metal for terrestrial ecosystems. Conclusion There were three major benefits by applying block clustering with PLS for processing the obtained data: firstly, it helped in grouping sites depending on the type of contamination. Secondly, it was valuable for identifying the latent factors that contribute the most to metal accumulation in land snails. Finally, it optimized the number and type of data that are best for monitoring the status of metallic contamination in terrestrial ecosystems exposed to different kinds of anthropic polution. PMID:23987502

Occurrence Data for the Unregulated Contaminant Monitoring Rule

EPA Pesticide Factsheets

EPA uses the Unregulated Contaminant Monitoring Rule (UCMR) to collect data for contaminants suspected to be present in drinking water, but that do not have health-based standards set under the Safe Drinking Water Act (SDWA)

Wandering albatrosses document latitudinal variations in the transfer of persistent organic pollutants and mercury to Southern Ocean predators.

PubMed

Carravieri, Alice; Bustamante, Paco; Tartu, Sabrina; Meillère, Alizée; Labadie, Pierre; Budzinski, Hélène; Peluhet, Laurent; Barbraud, Christophe; Weimerskirch, Henri; Chastel, Olivier; Cherel, Yves

2014-12-16

Top marine predators are effective tools to monitor bioaccumulative contaminants in remote oceanic environments. Here, we used the wide-ranging wandering albatross Diomedea exulans to investigate potential geographical variations of contaminant transfer to predators in the Southern Ocean. Blood concentrations of 19 persistent organic pollutants and 14 trace elements were measured in a large number of individuals (N = 180) of known age, sex and breeding status from the subantarctic Crozet Islands. Wandering albatrosses were exposed to a wide range of contaminants, with notably high blood mercury concentrations. Contaminant burden was markedly influenced by latitudinal foraging habitats (inferred from blood δ(13)C values), with individuals feeding in warmer subtropical waters having lower concentrations of pesticides, but higher concentrations of mercury, than those feeding in colder subantarctic waters. Sexual differences in contaminant burden seemed to be driven by gender specialization in feeding habitats, rather than physiological characteristics, with females foraging further north than males. Other individual traits, such as adult age and reproductive status, had little effect on blood contaminant concentrations. Our study provides further evidence of the critical role of global distillation on organic contaminant exposure to Southern Ocean avian predators. In addition, we document an unexpected high transfer of mercury to predators in subtropical waters, which merits further investigation.

Occurrence of bacteriophages infecting Aeromonas, Enterobacter, and Klebsiella in water and association with contamination sources in Thailand.

PubMed

Wangkahad, Bencharong; Bosup, Suchada; Mongkolsuk, Skorn; Sirikanchana, Kwanrawee

2015-06-01

The co-residence of bacteriophages and their bacterial hosts in humans, animals, and environmental sources directed the use of bacteriophages to track the origins of the pathogenic bacteria that can be found in contaminated water. The objective of this study was to enumerate bacteriophages of Aeromonas caviae (AecaKS148), Enterobacter sp. (EnspKS513), and Klebsiella pneumoniae (KlpnKS648) in water and evaluate their association with contamination sources (human vs. animals). Bacterial host strains were isolated from untreated wastewater in Bangkok, Thailand. A double-layer agar technique was used to detect bacteriophages. All three bacteriophages were detected in polluted canal samples, with likely contamination from human wastewater, whereas none was found in non-polluted river samples. AecaKS148 was found to be associated with human fecal sources, while EnspKS513 and KlpnKS648 seemed to be equally prevalent in both human and animal fecal sources. Both bacteriophages were also present in polluted canals that could receive contamination from other fecal sources or the environment. In conclusion, all three bacteriophages were successfully monitored in Bangkok, Thailand. This study provided an example of bacteriophages for potential use as source identifiers of pathogen contamination. The results from this study will assist in controlling sources of pathogen contamination, especially in developing countries.

Fate and Transport Modeling of Selected Chlorinated Organic Compounds at Operable Unit 1, U.S. Naval Air Station, Jacksonville, Florida

USGS Publications Warehouse

Davis, J. Hal

2007-01-01

The U.S. Naval Air Station occupies 3,800 acres adjacent to the St. Johns River in Jacksonville, Florida. The Station was placed on the U.S. Environmental Protection Agency's National Priorities List in December 1989 and is participating in the U.S. Department of Defense Installation Restoration Program, which serves to identify and remediate environmental contamination. One contaminated site, the old landfill, was designated as Operable Unit 1 (OU1) in 1989. The major source of ground-water contamination was from the disposal of waste oil and solvents into open pits, which began in the 1940s. Several remedial measures were implemented at this site to prevent the spread of contamination. Recovery trenches were installed in 1995 to collect free product. In 1998, some of the contamination was consolidated to the center of the old landfill and covered by an impermeable cap. Currently, Operable Unit 1 is being reevaluated as part of a 5-year review process to determine if the remedial actions were effective. Solute transport modeling indicated that the concentration of contaminants would have reached its maximum extent by the 1970s, after which the concentration levels would have generally declined because the pits would have ceased releasing high levels of contaminants. In the southern part of the site, monitoring well MW-19, which had some of the highest levels of contamination, showed decreases for measured and simulated concentrations of trichloroethene (TCE) and dichloroethene (DCE) from 1992 to present. Two upgradient disposal pits were simulated to have ceased releasing high levels of contamination in 1979, which consequently caused a drop in simulated concentrations. Monitoring well MW-100 had the highest levels of contamination of any well directly adjacent to a creek. Solute transport modeling substantially overestimated the concentrations of TCE, DCE, and vinyl chloride (VC) in this well. The reason for this overestimation is not clear, however, it indicates that the model will be conservative when used to predict concentration levels and the time required for the contamination to move through the system. Monitoring well MW-97 had the highest levels of contamination in the central part of the site. The levels decreased for both the measured and simulated values of TCE, DCE, and VC from 1999 to present. Simulating the source area as ceasing to release high levels of contamination in 1979 caused the drop in concentration, which began in the 1990s at this well. Monitoring well MW-89 had the highest levels of contamination in the northern part of the site. In order to match the low levels of contamination in wells MW-12 and MW-93, the pit was simulated as ceasing to release contamination in 1970; however, the installation of a trench in 1995 could have caused the source area to release additional contamination from 1995 to 1998. The effect of the additional dissolution was a spike in contamination at MW-89, beginning in about 1996 and continuing until the present time. Results from the last several sampling events indicate that the TCE and DCE levels could be decreasing, but VC shows no apparent trend. Several more years of sampling are needed to determine if these trends are continuing. Based on the solute transport modeling predictions, TCE, DCE, and VC will have migrated to the vicinity of creeks that drain ground water from the aquifer by 2010, and only relatively low levels will remain in the aquifer by 2015. Because the creeks represent the point where the contaminated ground water comes into contact with the environment, future contamination levels are a concern. The concentration of chlorinated solvents in the creek water has always been relatively low. Because the model shows that concentrations of TCE, DCE, and VC are declining in the aquifer, contamination levels in the creeks also are anticipated to decline.

Evaluation of the sources of contamination in the suburban area of Koropi-Markopoulo, Athens, Greece.

PubMed

Kaitantzian, Agavni; Kelepertzis, Efstratios; Kelepertsis, Akindynos

2013-07-01

Heavy metal concentrations were monitored in agricultural soils and irrigation groundwaters of Koropi-Markopoulo area, a representative agricultural suburb in Athens, Greece, aiming at the identification of the sources of contaminants. Multivariate analyses of geochemical data demonstrated that agricultural practices and industrial activities considerably affected the quality of both environmental compartments. The levels of Ni, Cr, Co, Mn and Fe in agricultural soils were associated with geological parent materials whereas Pb, Zn and Cu mainly originated from anthropic activities. Referring to groundwaters, individual major anions and cations (K⁺, Na⁺, Ca²⁺, Mg²⁺, NO₃⁻, SO₄²⁻, Cl⁻) were influenced by various natural and anthropogenic factors whereas Ni, Cr, Cu and Zn were controlled by industrial and agronomic activities. The identification of the sources of contaminants in soil and groundwater environments is a valuable basis for encouraging mitigation strategies preventing further quality degradation.

Tools for monitoring aquatic environments to identify anthropic effects.

PubMed

da Rocha, Monyque Palagano; Dourado, Priscila Leocadia Rosa; Cardoso, Claudia Andrea Lima; Cândido, Liliam Silva; Pereira, Joelson Gonçalves; de Oliveira, Kelly Mari Pires; Grisolia, Alexeia Barufatti

2018-01-05

Anthropic activities are directly related to the contamination of aquatic ecosystems owing to the release of numerous chemicals from agricultural and urban waste. These contaminants cause environmental degradation and a decrease in the availability of water quality. The objective of this search was to evaluate the efficiency of physicochemical, chemical, and microbiological tests; extraction of chlorophyll a; and genetic parameters to identify anthropic activities and weather condition effects on the stream water quality and the consequences of its use by the population. The physicochemical parameters were within the limits allowed by the Brazilian law. However, contamination by metals (Cd 0.510 mg L -1 , Co 0.405 mg L -1 , and Ni 0.316 mg L -1 ) has been found at various collection points to be more than the allowable values. The antibiotic oxytetracycline was detected in stream water in quantities of up to 89 μg L -1 . In relation to microbiological contamination, Escherichia coli and Pseudomonas spp. have been isolated. The averages of chlorophyll a were up to 0.15558 mg cm -2 . Genetic tools identified greater number of micronuclei and DNA damage in periods that showed lower rainfall rates and lower amounts of metals. The analysis used for monitoring was efficient to verify the interference that animal breeding and planting of different cultures have caused on that stream. Thus, the continued use of this water for drinking, irrigation of vegetables, and recreational activities makes the population susceptible to contamination by bacteria and creates conditions for the development of genetic alterations in the long run.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.; Environmental Science Division

The 2006-2007 investigation of carbon tetrachloride and chloroform contamination at Barnes, Kansas, was conducted at the request of the Kansas Department of Health and Environment (KDHE). The Environmental Science Division of Argonne National Laboratory implemented the investigation on behalf of the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA). The overall goal of the investigation was to establish criteria for monitoring leading to potential site reclassification. The investigation objectives were to (1) determine the hydraulic gradient near the former CCC/USDA facility, (2) delineate the downgradient carbon tetrachloride plume, and (3) design and implement an expanded monitoring network atmore » Barnes (Argonne 2006a).« less

Environmental microbial contamination in a stem cell bank.

PubMed

Cobo, F; Concha, A

2007-04-01

The aim of this study was to evaluate the main environmental microbial contaminants of the clean rooms in our stem cell bank. We have measured the microbial air contamination by both passive and active air sampling and the microbial monitoring of surfaces by means of Rodac plates. The environmental monitoring tests were carried out in accordance with the guidelines of European Pharmacopeia and US Pharmacopeia. The micro-organisms were identified by means of an automated system (VITEK 2). During the monitoring, the clean rooms are continually under good manufacturing practices specifications. The most frequent contaminants were Gram-positive cocci. The main contaminants in our stem cell bank were coagulase-negative staphylococci and other opportunistic human pathogens. In order to assure the levels of potential contamination in both embryonic and adult stem cell lines, a continuous sampling of air particles and testing for viable microbiological contamination is necessary. This study is the first evaluation of the environmental contaminants in stem cell banks and can serve as initial evaluation for these establishments. The introduction of environmental monitoring programmes in the processing of stem cell lines could diminish the risk of contamination in stem cell cultures.

Environmental survey to assess viral contamination of air and surfaces in hospital settings.

PubMed

Carducci, A; Verani, M; Lombardi, R; Casini, B; Privitera, G

2011-03-01

The presence of pathogenic viruses in healthcare settings represents a serious risk for both staff and patients. Direct viral detection in the environment poses significant technical problems and the indirect indicators currently in use suffer from serious limitations. The aim of this study was to monitor surfaces and air in hospital settings to reveal the presence of hepatitis C virus, human adenovirus, norovirus, human rotavirus and torque teno virus by nucleic acid assays, in parallel with measurements of total bacterial count and haemoglobin presence. In total, 114 surface and 62 air samples were collected. Bacterial contamination was very low (<1 cfu/cm(2)) on surfaces, whereas the 'medium' detected value in air was 282 cfu/m(3). Overall, 19 (16.7%) surface samples tested positive for viral nucleic acids: one for norovirus, one for human adenovirus and 17 (14.9%) for torque teno virus (TTV). Only this latter virus was directly detected in 10 air samples (16.1%). Haemoglobin was found on two surfaces. No relationship was found between viral, biochemical or bacterial indicators. The data obtained confirm the difficulty of assessing viral contamination using bacterial indicators. The frequent detection of TTV suggests its possible use as an indicator for general viral contamination of the environment. Copyright © 2010 The Hospital Infection Society. Published by Elsevier Ltd. All rights reserved.

A reliable sewage quality abnormal event monitoring system.

PubMed

Li, Tianling; Winnel, Melissa; Lin, Hao; Panther, Jared; Liu, Chang; O'Halloran, Roger; Wang, Kewen; An, Taicheng; Wong, Po Keung; Zhang, Shanqing; Zhao, Huijun

2017-09-15

With closing water loop through purified recycled water, wastewater becomes a part of source water, requiring reliable wastewater quality monitoring system (WQMS) to manage wastewater source and mitigate potential health risks. However, the development of reliable WQMS is fatally constrained by severe contamination and biofouling of sensors due to the hostile analytical environment of wastewaters, especially raw sewages, that challenges the limit of existing sensing technologies. In this work, we report a technological solution to enable the development of WQMS for real-time abnormal event detection with high reliability and practicality. A vectored high flow hydrodynamic self-cleaning approach and a dual-sensor self-diagnostic concept are adopted for WQMS to effectively encounter vital sensor failing issues caused by contamination and biofouling and ensure the integrity of sensing data. The performance of the WQMS has been evaluated over a 3-year trial period at different sewage catchment sites across three Australian states. It has demonstrated that the developed WQMS is capable of continuously operating in raw sewage for a prolonged period up to 24 months without maintenance and failure, signifying the high reliability and practicality. The demonstrated WQMS capability to reliably acquire real-time wastewater quality information leaps forward the development of effective wastewater source management system. The reported self-cleaning and self-diagnostic concepts should be applicable to other online water quality monitoring systems, opening a new way to encounter the common reliability and stability issues caused by sensor contamination and biofouling. Copyright © 2017 Elsevier Ltd. All rights reserved.

Integrated methodology for assessing the HCH groundwater pollution at the multi-source contaminated mega-site Bitterfeld/Wolfen.

PubMed

Wycisk, Peter; Stollberg, Reiner; Neumann, Christian; Gossel, Wolfgang; Weiss, Holger; Weber, Roland

2013-04-01

A large-scale groundwater contamination characterises the Pleistocene groundwater system of the former industrial and abandoned mining region Bitterfeld/Wolfen, Eastern Germany. For more than a century, local chemical production and extensive lignite mining caused a complex contaminant release from local production areas and related dump sites. Today, organic pollutants (mainly organochlorines) are present in all compartments of the environment at high concentration levels. An integrated methodology for characterising the current situation of pollution as well as the future fate development of hazardous substances is highly required to decide on further management and remediation strategies. Data analyses have been performed on regional groundwater monitoring data from about 10 years, containing approximately 3,500 samples, and up to 180 individual organic parameters from almost 250 observation wells. Run-off measurements as well as water samples were taken biweekly from local creeks during a period of 18 months. A kriging interpolation procedure was applied on groundwater analytics to generate continuous distribution patterns of the nodal contaminant samples. High-resolution geological 3-D modelling serves as a database for a regional 3-D groundwater flow model. Simulation results support the future fate assessment of contaminants. A first conceptual model of the contamination has been developed to characterise the contamination in regional surface waters and groundwater. A reliable explanation of the variant hexachlorocyclohexane (HCH) occurrence within the two local aquifer systems has been derived from the regionalised distribution patterns. Simulation results from groundwater flow modelling provide a better understanding of the future pollutant migration paths and support the overall site characterisation. The presented case study indicates that an integrated assessment of large-scale groundwater contaminations often needs more data than only from local groundwater monitoring. The developed methodology is appropriate to assess POP-contaminated mega-sites including, e.g. HCH deposits. Although HCH isomers are relevant groundwater pollutants at this site, further organochlorine pollutants are present at considerably higher levels. The study demonstrates that an effective evaluation of the current situation of contamination as well as of the related future fate development requires detailed information of the entire observed system.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.; Environmental Science Division

In September 2005, the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) initiated periodic sampling of groundwater in the vicinity of a grain storage facility formerly operated by the CCC/USDA at Morrill, Kansas. The sampling at Morrill is being performed on behalf of the CCC/USDA by Argonne National Laboratory, in accord with a monitoring program approved by the Kansas Department of Health and Environment (KDHE 2005), to monitor levels of carbon tetrachloride contamination identified in the groundwater at this site (Argonne 2004, 2005a). This report provides results for monitoring events in April and September 2009. Under the KDHE-approvedmore » monitoring plan (Argonne 2005b), groundwater was initially sampled twice yearly for a period of two years (in fall 2005, in spring and fall 2006, and in spring and fall 2007). The samples were analyzed for volatile organic compounds (VOCs), as well as for selected geochemical parameters to aid in the evaluation of possible natural contaminant degradation (reductive dechlorination) processes in the subsurface environment. The analytical results for groundwater sampling events at Morrill from September 2005 to October 2008 were documented previously (Argonne 2006a,b, 2007, 2008a,b, 2009). Those results consistently demonstrated the presence of carbon tetrachloride contamination, at levels exceeding the KDHE Tier 2 risk-based screening level of 5.0 {micro}g/L for this compound, in a groundwater plume extending generally south-southeastward from the former CCC/USDA facility, toward Terrapin Creek at the south edge of the town. Low levels ({le} 1.3 {micro}g/L) of carbon tetrachloride were persistently detected at monitoring well MW8S, on the bank of an intermittent tributary to Terrapin Creek. This observation suggested a possible risk of contamination of the surface waters of the creek. That concern is the regulatory driver for ongoing monitoring. In light of the early findings, in 2006 the CCC/USDA recommended expansion of the approved monitoring program to include the collection and analysis of surface water samples along Terrapin Creek (Argonne 2006a). At the request of the KDHE (2007a), locations for both surface water and shallow sediment sampling were discussed with the KDHE in January 2007. An addendum to the existing monitoring plan (Appendix A) and a standard operating procedure (SOP AGEM-15; Appendix B) for sediment sampling were submitted to the KDHE on the basis of these discussions and were subsequently approved (KDHE 2008b). Results of sediment sampling prior to 2009 were reported previously (Argonne 2008a,b; 2009). To supplement the original scope of the monitoring, Argonne also sampled natural vegetation along Terrapin Creek in October 2006, April 2007, and July 2007 for analyses for VOCs. The results of these plant tissue analyses were reported previously (Argonne 2008a, 2009). The April and September 2009 sampling events reported here represent a continuation of the two-year monitoring program, as requested by the KDHE (2007b). The groundwater sampling is presently conducted, in accord with the monitoring plan (Argonne 2005b) and the addendum to that plan (Appendix A in this report), in a network of 12 monitoring wells and 3 private wells (Figure 1.1), at locations approved by the KDHE (2008b). The findings of the April and September 2009 monitoring events at Morrill support the following conclusions: (1) Groundwater flow during the early spring and the later part of this review period was predominantly to the south-southeast, from the vicinity of the former CCC/USDA facility toward Terrapin Creek. In late spring, a slight shift occurred toward more southerly groundwater flow (possibly southwesterly in the immediate vicinity of the intermittent tributary that flows into Terrapin Creek). This shift in the late spring reflected transient seasonal precipitation and recharge that resulted in higher groundwater levels at this time. (2) No significant changes were observed in the levels or distribution of carbon tetrachloride in the groundwater at Morrill during the current review period, or in comparison to the results of the spring and fall 2008 monitoring events. A maximum carbon tetrachloride concentration of 28-30 {micro}g/L was identified in groundwater - at well MW3S - during both the April and September 2009 sampling events. (3) No carbon tetrachloride contamination was detected in surface waters or shallow streambed sediments sampled at five locations along Terrapin Creek, downgradient from the former CCC/USDA facility. (4) Sampling of tree branch tissues from existing trees for VOCs analyses can be an indicator of shallow subsurface groundwater contamination. Detections of carbon tetrachloride in vegetation at the Morrill site to date have been generally consistent with the documented location of the groundwater plume.« less

Monitoring of selected priority and emerging contaminants in the Guadalquivir River and other related surface waters in the province of Jaén, South East Spain.

PubMed

Robles-Molina, José; Gilbert-López, Bienvenida; García-Reyes, Juan F; Molina-Díaz, Antonio

2014-05-01

The province of Jaén counts with four natural parks, numerous rivers, reservoirs and wetlands; moreover, it is probably the region with higher olive oil production in the world, which makes this zone a proper target to be studied based on the European Water Framework Directive 2000/60/CE. The aim of this survey is to monitor a total number of 373 compounds belonging to different families (pesticides, PAHs, nitrosamines, drugs of abuse, pharmaceuticals and life-style compounds) in surface waters located at different points of the province of Jaén. Among these compounds some priority organic substances (regulated by the EU Directive 2008/105/EC) and pollutants of emerging concern (not regulated yet) can be found. A liquid chromatography electrospray time-of-flight mass spectrometry (LC-TOFMS) method covering 340 compounds was developed and applied, together with a gas chromatography triple-quadrupole mass spectrometry (GC-MS/MS) method which enabled the analysis of 63 organic contaminants (30 of these compounds are analyzed by LC-TOFMS as well). From April 2009 to November 2010 a total of 83 surface water samples were collected (rivers, reservoirs and wetlands). In this period numerous organic contaminants were detected, most of them at the ng L(-1) level. The most frequently priority substances found were chlorpyrifos ethyl, diuron and hexachlorobenzene. Within the other groups, the most frequently detected compounds were: terbuthylazine, oxyfluorfen, desethyl terbuthylazine, diphenylamine (pesticide family); fluorene, phenanthrene, pyrene (PAHs group), codeine, paracetamol (pharmaceuticals compounds) and caffeine, nicotine (life-style compounds). As is could be expected, the total concentration of emerging contaminants is distinctly larger than that of priority pollutants, highlighting the importance of continuing with the study of their presence, fate and effects in aquatic environments. However, concentration levels (at the ng per liter level) are low in general for both kinds of contaminants which minimizes the possible harmful effect on the environment. Copyright © 2014 Elsevier B.V. All rights reserved.

Estimating the susceptibility of surface water in Texas to nonpoint-source contamination by use of logistic regression modeling

USGS Publications Warehouse

Battaglin, William A.; Ulery, Randy L.; Winterstein, Thomas; Welborn, Toby

2003-01-01

In the State of Texas, surface water (streams, canals, and reservoirs) and ground water are used as sources of public water supply. Surface-water sources of public water supply are susceptible to contamination from point and nonpoint sources. To help protect sources of drinking water and to aid water managers in designing protective yet cost-effective and risk-mitigated monitoring strategies, the Texas Commission on Environmental Quality and the U.S. Geological Survey developed procedures to assess the susceptibility of public water-supply source waters in Texas to the occurrence of 227 contaminants. One component of the assessments is the determination of susceptibility of surface-water sources to nonpoint-source contamination. To accomplish this, water-quality data at 323 monitoring sites were matched with geographic information system-derived watershed- characteristic data for the watersheds upstream from the sites. Logistic regression models then were developed to estimate the probability that a particular contaminant will exceed a threshold concentration specified by the Texas Commission on Environmental Quality. Logistic regression models were developed for 63 of the 227 contaminants. Of the remaining contaminants, 106 were not modeled because monitoring data were available at less than 10 percent of the monitoring sites; 29 were not modeled because there were less than 15 percent detections of the contaminant in the monitoring data; 27 were not modeled because of the lack of any monitoring data; and 2 were not modeled because threshold values were not specified.

Role of Groundwater Monitoring for Closure of Underground Nuclear Tests on the Nevada Test Site

NASA Astrophysics Data System (ADS)

Chapman, J. B.; Pohlmann, K.; Pohll, G.; Russell, C.

2009-12-01

Over 800 underground nuclear tests were conducted at the Nevada Test Site in a variety of hydrogeologic environments. As of the 1996 Environmental Impact Statement for the site, more than 100 million curies of radioactivity remained in the subsurface from these tests, much of it near or below the water table. The U.S. Department of Energy Environmental Management program is implementing a closure strategy for these sites that anticipates closure-in-place, natural attenuation, and institutional controls. Groundwater monitoring is a key component of this strategy, but its role is significantly evolved from that of a detection- or compliance-based monitoring concept. Indeed, monitoring is part of the integrated closure process itself, not an activity confined to a static post-closure period. The reasons for this evolution derive from the complex hydrogeologic conditions, the long time-frames of concern, and recognition that a significant degree of uncertainty is irreducible. The hundreds of test locations are grouped into Corrective Action Units that measure over 100 km2 in area and extend to depths in excess of 1000 m. Despite concerted data collection efforts, the technical basis for closure of these large regions relies heavily on complex numerical models of flow and transport. The inherent uncertainties in these models present challenges for reaching regulatory acceptance of closure, and challenges for confidently locating monitoring wells. The solution now being pursued for the NTS is to integrate model evaluation and monitoring. In addition to standard goals of contaminant detection and protection of human health, an explicit monitoring objective is to increase confidence in model results by assessing the reliability of model forecasts. The initial monitoring network is expected to eventually transition to a long-term closure design, with less emphasis on confidence-building as uncertainty in forecasts is reduced. The methodology for this iterative process of monitoring and model refinement will incorporate expert-judgment and Bayesian updating of model input parameters to provide a cost-beneficial monitoring network that is expected to reduce model prediction uncertainty. This approach to monitoring for these large and complex contaminant areas is consistent with the underlying reliance on model predictions and will ensure that water quality samples are collected in a manner and location that is consistent with the current understanding of contaminant flowpaths.

Validation of Passive Sampling Devices for Monitoring of Munitions Constituents in Underwater Environments

DTIC Science & Technology

2017-09-01

this project, we launched at Esperanza pier (Figure 5-4), which required a minimum of 2 hours of travel time , including transit from Camp Garcia to the...concentrations of emerging contaminants by providing a time -integrated sample with low detection limits and in situ extraction. PSDs are fairly well...A continuous sampling approach allows detection and quantification of chemicals in an integrated manner, providing time - weighted average (TWA

NBC Contamination Survivability, Large Item Exteriors

DTIC Science & Technology

1998-04-17

environment. Ability to control temperature , relative humidity (RH), and wind speed is required. The facility must be designed to ensure safe and...2.2 Instrumentation. Measuring Devices Permissible Error of Measurement Air temperature ±0.5°C Relative humidity (RH) ±5 % Wind speed ±0.1 rm/sec Still...process, excluding monitoring, should last no longer than 75 minutes. (3) The item surface temperature is 30’C and exterior wind speed is no greater

Development of integrated protocols to track the deposition and impacts of metal contaminants in tidal riverine environments

NASA Astrophysics Data System (ADS)

Roe, Helen M.; Patterson, R. Timothy; Nasser, Nawaf; Edwards, Robin J.; Graham, Conor

2016-04-01

Tidally-influenced rivers are particularly vulnerable to the effects of metal contamination, yet are amongst the most complex fluvial environments in terms of their sediment deposition and transport patterns. We present the results of an interdisciplinary study that aims to elucidate the fluxes and deposition of metal contaminants in a tidally-influenced river system in Northern Ireland, with a view to developing protocols that will have wide applicability for the monitoring and assessment of metal contaminants in similar environments in other regions. We employ a novel methodology that combines ICPMS analysis of sediments, ITRAX-based core analysis and the examination a important group of shelled protozoans (foraminifera), which occur widely in tidal riverine environments, and which are highly sensitive to metal contamination. The responses shown by the group vary between species and with different levels of contaminant exposure. Some species, for example, show increased relative abundances in proximity to discharge sources, whilst others develop chamber deformities. Application of our integrated multiproxy approach to the analysis of surface sediment samples and cores provides a framework for assessing both the spatial and temporal patterns of metal deposition and the impact of contaminants on the biota. Modern sediment samples (n=90) were collected at varying distances from a point contamination source (a former industrial site) in different morpho-sedimentary settings. The impact of 25 measured variables on the modern foraminiferal faunas was considered, including 20 metals, pH, conductivity, elevation and particle size. Channel sediments in close proximity to the contamination source and with the highest levels of Fe, Cu, Zn, Mg and As, yielded the sparsest foraminiferal faunas (Shannon Diversity Index values 0-1.5), whilst the highest prevalence of foraminiferids showing chamber deformities were observed in channel edge and levée bank sites. Kernal density plots showing metal loading and foraminiferal concentrations across the site aided in determining spatial trends. The sediment core data revealed that deformed foraminiferal specimens can extend >15 cm below the contemporary floodplain surface to horizons that pre-date the historical onset of the contamination, suggesting vertical mobilisation of sediment and/or infaunal migration. Etching of the foraminiferal tests in association with reduced pH conditions was also observed for some species. Biometric analysis of tests using SEM imagery further aided in the identification of deformities and the delimitation of graded responses to contaminants. The results of this study of core and surficial samples indicate that the adoption of integrated methodologies that combine established geochemical analysis techniques (e.g. ICPMS analysis) with the observed ecophenotypic response of key indicator microfossil groups (e.g. foraminifera) can provide invaluable data on habitat responses to environmental contamination. Such long-term habitat evaluation data is invaluable to policy makers and planners when prioritising management and remediation efforts.

Contamination Effects Due to Space Environmental Interactions

NASA Technical Reports Server (NTRS)

Chen, Philip T.; Paquin, Krista C. (Technical Monitor)

2001-01-01

Molecular and particulate contaminants are commonly generated from the orbital spacecraft operations that are under the influence of the space environment. Once generated, these contaminants may attach to the surfaces of the spacecraft or may remain in the vicinity of the spacecraft. In the event these contaminants come to rest on the surfaces of the spacecraft or situated in the line-of-sight of the observation path, they will create various degrees of contamination effect which may cause undesirable effects for normal spacecraft operations, There will be circumstances in which the spacecraft may be subjected to special space environment due to operational conditions. Interactions between contaminants and special space environment may alter or greatly increase the contamination effect due to the synergistic effect. This paper will address the various types of contamination generation on orbit, the general effects of the contamination on spacecraft systems, and the typical impacts on the spacecraft operations due to the contamination effect. In addition, this paper will explain the contamination effect induced by the space environment and will discuss the intensified contamination effect resulting from the synergistic effect with the special space environment.

Halogen occultation experiment (HALOE) optical witness-plate program

NASA Technical Reports Server (NTRS)

Harvey, Gale A.; Raper, James L.

1989-01-01

An optical witness plate program was implemented to monitor buildup of molecular contamination in the clean room during the assembly and testing of the Halogen Occulation Experiment (HALOE) instrument. Travel plates to monitor molecular contamination when the instrument is not in the clean room are also measured. The instrument technique is high-resolution transmission spectroscopy in the 3 micron spectral region using a Fourier transform spectrometer. Witness specimens of low index of refraction, infrared transmitting material are used for contaminant monitoring and for spectral signature analysis. Spectral signatures of possible molecular contamination are presented. No condensible volatile material contamination of HALOE optical witness specimens have yet been found.

MONITORED NATURAL ATTENUATION FOR INORGANIC CONTAMINANT REMEDIATION IN GROUNDWATER

EPA Science Inventory

Monitored natural attenuation (MNA) has been applied as a knowledge-based remediation technology for organic contaminants in ground water. Development of a site-specific assessment of biotic and abiotic processes that lead to organic contaminant degradation provides the technica...

EVALUATING MONITORED NATURAL ATTENUATION FOR RADIONUCLIDE AND INORGANIC CONTAMINANTS IN GROUNDWATER

EPA Science Inventory

Monitored Natural Attenuation (MNA) for inorganic contaminants is dependent on naturally occurring processes in the subsurface that act without human intervention to reduce the mass, toxicity, mobility, volume or concentration of contaminants. EPA is developing a technical refer...

Deep Vadose Zone Treatability Test for the Hanford Central Plateau: Interim Post-Desiccation Monitoring Results, Fiscal Year 2014

DOE Office of Scientific and Technical Information (OSTI.GOV)

Truex, Michael J.; Strickland, Christopher E.; Johnson, Christian D.

Over decades of operation, the U.S. Department of Energy (DOE) and its predecessors have released nearly 2 trillion L (450 billion gal.) of liquid into the vadose zone at the Hanford Site. Much of this discharge of liquid waste into the vadose zone occurred in the Central Plateau, a 200 km 2 (75 mi 2) area that includes approximately 800 waste sites. Some of the inorganic and radionuclide contaminants in the deep vadose zone at the Hanford Site are at depths below the limit of direct exposure pathways, but may need to be remediated to protect groundwater. The Tri-Party Agenciesmore » (DOE, U.S. Environmental Protection Agency, and Washington State Department of Ecology) established Milestone M 015 50, which directed DOE to submit a treatability test plan for remediation of technetium-99 (Tc-99) and uranium in the deep vadose zone. These contaminants are mobile in the subsurface environment and have been detected at high concentrations deep in the vadose zone, and at some locations have reached groundwater. Testing technologies for remediating Tc-99 and uranium will also provide information relevant for remediating other contaminants in the vadose zone. A field test of desiccation is being conducted as an element of the DOE test plan published in March 2008 to meet Milestone M 015 50. The active desiccation portion of the test has been completed. Monitoring data have been collected at the field test site during the post-desiccation period and are reported herein. This is an interim data summary report that includes about 3 years of post-desiccation monitoring data. The DOE field test plan proscribes a total of 5 years of post-desiccation monitoring.« less

Use of plants to monitor contamination of air by SO2 in and around refinery.

PubMed

Abdul-Wahab, Sabah A; Yaghi, Basma

2004-01-01

The generation of SO2 from a refinery may affect the surrounding environment. Moreover, SO2 and its by-products are phytotoxic as berg. This study aims to investigate plant responses to SO2. The work has been designed with emphasis on using the plants directly in monitoring the contamination of the atmospheric air by SO2. An assessment was made of the impacts of long-term SO2 emissions from an oil refinery on plants located in nearby areas that are likely to be exposed to emission fallout. Three different plant species (Prosopis cineraria. Azadirachta indica, and Phoenix dactilifera) common to the environment of the Arabian Gulf were selected at different distances and directions from the refinery. The analysis of the sulphate contents of these plants were used as bioindicators for monitoring SO2 concentration levels in and around the refinery. The results of this study showed that the three different plant species responsed differently to SO2 in terms of their sulphate contents. Generally, all three species were found to be sensitive to SO2 exposure. Furthermore, the concentration of sulphate was found to be much higher closer to the refinery. On the basis of this study, it can be stated that even though SO2 levels were lower than the permissible limit values, the sulphate contents accumulated in the plants were likely to cause plant injury especially in the vicinity of the source. This suggests that the present environmental guidelines for SO2 may not protect sensitive plant species.

Numerical Simulation for Impact of Groundwater Environment in a Chemical Industry Park in the Southwest of Shandong Province Based on GMS

NASA Astrophysics Data System (ADS)

Huang, Lin-xian; Chang, Le-ran; Xing, Li-ting; Liu, Ben-hua

2018-02-01

The establishment of chemical industry park can bring great pressure on local groundwater environment, and even cause serious groundwater pollution problems. This study armed at a chemical industry park in southeast of Shandong province and developed a three-dimensional groundwater solute transport model through GMS software, selected dichloromethane as the typical contaminant, simulated and predicated the transport characteristic of groundwater contaminant in different conditions. The results showed that after 20 years, the dichloromethane can separately transport 820m and 1,000m under different hypothetical conditions, the greatest affected area can separately reach 32×104 m2 and 21×104 m2; it indicated that the studied area would be polluted under these simulated conditions, so measures must be done to improve the ability of seepage-proofing of this chemical industry park and to enhance the management and the monitoring of groundwater in this studied area.

Challenges to effective cancer control in China, India, and Russia.

PubMed

Goss, Paul E; Strasser-Weippl, Kathrin; Lee-Bychkovsky, Brittany L; Fan, Lei; Li, Junjie; Chavarri-Guerra, Yanin; Liedke, Pedro E R; Pramesh, C S; Badovinac-Crnjevic, Tanja; Sheikine, Yuri; Chen, Zhu; Qiao, You-lin; Shao, Zhiming; Wu, Yi-Long; Fan, Daiming; Chow, Louis W C; Wang, Jun; Zhang, Qiong; Yu, Shiying; Shen, Gordon; He, Jie; Purushotham, Arnie; Sullivan, Richard; Badwe, Rajendra; Banavali, Shripad D; Nair, Reena; Kumar, Lalit; Parikh, Purvish; Subramanian, Somasundarum; Chaturvedi, Pankaj; Iyer, Subramania; Shastri, Surendra Srinivas; Digumarti, Raghunadhrao; Soto-Perez-de-Celis, Enrique; Adilbay, Dauren; Semiglazov, Vladimir; Orlov, Sergey; Kaidarova, Dilyara; Tsimafeyeu, Ilya; Tatishchev, Sergei; Danishevskiy, Kirill D; Hurlbert, Marc; Vail, Caroline; St Louis, Jessica; Chan, Arlene

2014-04-01

Cancer is one of the major non-communicable diseases posing a threat to world health. Unfortunately, improvements in socioeconomic conditions are usually associated with increased cancer incidence. In this Commission, we focus on China, India, and Russia, which share rapidly rising cancer incidence and have cancer mortality rates that are nearly twice as high as in the UK or the USA, vast geographies, growing economies, ageing populations, increasingly westernised lifestyles, relatively disenfranchised subpopulations, serious contamination of the environment, and uncontrolled cancer-causing communicable infections. We describe the overall state of health and cancer control in each country and additional specific issues for consideration: for China, access to care, contamination of the environment, and cancer fatalism and traditional medicine; for India, affordability of care, provision of adequate health personnel, and sociocultural barriers to cancer control; and for Russia, monitoring of the burden of cancer, societal attitudes towards cancer prevention, effects of inequitable treatment and access to medicine, and a need for improved international engagement. Copyright © 2014 Elsevier Ltd. All rights reserved.

[Determination of total mercury in water samples, sediments and solids in suspension in aquatic systems by cold-vapor atomic absorption spectrophotometry].

PubMed

Vieira, J L; Passarelli, M M

1996-06-01

The use of metallic mercury in the extraction and concentration of gold causes the discarding of tons of this metal in the environment, leading to a considerable increase in the natural levels of the same and the contamination of the surrounding areas. Thus it is extremely important to monitor the presence of this metal in various sectors of the environment with a view aiming to preventing human exposure to excessive concentrations which can result in serious episodes of mercury poisoning. It is also important to estimate the possibility of river sediments becoming potential sources of contamination of human beings. The determination of total mercury was undertaken by using cold vapor atomic absorption spectrometry. River waters, as well as sediments and suspended solids were used as samples for the standardization of the analytical procedure. Later on, this method was tested on samples originating in gold mining areas for the purpose of assessing its validity.

Utilising monitoring and modelling of estuarine environments to investigate catchment conditions responsible for stratification events in a typically well-mixed urbanised estuary

NASA Astrophysics Data System (ADS)

Lee, Serena B.; Birch, Gavin F.

2012-10-01

Estuarine health is affected by contamination from stormwater, particularly in highly-urbanised environments. For systems where catchment monitoring is insufficient, novel techniques must be employed to determine the impact of urban runoff on receiving water bodies. In the present work, estuarine monitoring and modelling were successfully employed to determine stormwater runoff volumes and establish an appropriate rainfall/runoff relationship capable of replicating fresh-water discharge due to the full range of precipitation conditions in the Sydney Estuary, Australia. Using estuary response to determine relationships between catchment rainfall and runoff is a widely applicable method and may be of assistance in the study of waterways where monitoring fluvial discharges is not practical or is beyond the capacity of management authorities. For the Sydney Estuary, the SCS-CN method replicated rainfall/runoff and was applied in numerical modelling experiments investigating the hydrodynamic characteristics affecting stratification and estuary recovery following high precipitation. Numerical modelling showed stratification in the Sydney Estuary was dominated by fresh-water discharge. Spring tides and up-estuary winds contributed to mixing and neap tides and down-estuary winds enhanced stratification.

Long-term autonomous resistivity monitoring of oil-contaminated sediments from the Deepwater Horizon spill

NASA Astrophysics Data System (ADS)

Heenan, J. W.; Slater, L. D.; Ntarlagiannis, D.; Atekwana, E. A.; Ross, C.; Nolan, J. T.; Atekwana, E. A.; Werkema, D. D.; Fathepure, B.

2012-12-01

We conducted a long-term electrical resistivity survey at Grand Terre 1 (GT1) Island off the coast of Louisiana, a site contaminated with crude oil associated with the April 2010 BP Deepwater Horizon oil spill. Electrical resistivity has proven sensitivity to biogeochemical processes associated with the biodegradation of hydrocarbons in the subsurface. However, most of these studies have been in freshwater environments and for aged spills. The BP Deepwater Horizon oil spill therefore provided an unprecedented opportunity to capture the early time biogeophysical signals resulting from the physical, chemical and microbial transformation of crude oil in highly saline environments. We used a multi-channel resistivity system powered by solar panels to obtain continuous measurements twice a day on both a surface array and two shallow borehole arrays. This system operated for approximately 1.5 years and provided a unique long-term dataset of resistivity changes. Temperature and specific conductance values for the shallow groundwater were continuously logged. . Resistivity changes likely associated with biodegradation processes were then isolated from these environmental factors by modeling. In addition, groundwater was sampled for geochemical analyses from wells installed at the study site and soil samples were collected for microbial analyses at several locations, including both contaminated and uncontaminated locations. Microcosms were set up to determine the biodegradation potential of indigenous populations, and microbial diversity analysis was used to determine microbial community composition. Surface and borehole resistivity arrays revealed an initial resistive anomaly co-located with the known contamination. Pixel time series analysis of an inverted time sequence of resistivity sections highlighted differing responses between contaminated and uncontaminated locations. The contaminated locations exhibit persistent resistivity decreases over time, whereas areas outside of the contaminated location exhibit relatively uniform resistivity or show clear evidence of seasonal effect. Temperature-corrected resistivity changes show no direct correlation with pore fluid specific conductance changes, suggesting that specific conductance changes (e.g. due to tides) have little influence on imaged resistivity structure. Microbial data suggest that resistivity changes within the contaminated location resulted from biodegradation, showing the presence of native populations capable of degrading aromatic hydrocarbons at salinities ranging from 6 to 15 % NaCl within the contaminated location. Aqueous geochemical measurements performed on samples from the site further indicate that at depth intervals coincident with the resistivity anomaly, marked increases in the concentration of dissolved inorganic carbon (DIC) were observed suggesting biodegradation of petroleum hydrocarbon although other DIC generating processes such as organic matter degradation coupled to sulfate and iron reduction were also prominent. This experiment demonstrates the potential viability of long-term autonomous electrical monitoring as a means of decreasing the frequency of more costly and invasive chemical analysis of natural attenuation.

EVALUATING MONITORED NATURAL ATTENUATION FOR RADIONUCLIDE & ORGANIC CONTAMINATION IN GROUNDWATER (SALT LAKE CITY, UT)

EPA Science Inventory

Monitored Natural Attenuation (MNA) for radionuclides and inorganic contaminants is dependent on naturally occurring processes in the subsurface that act without human intervention to reduce the mass, toxicity, mobility, volume or concentration of contaminants. EPA is developing ...

Stable Isotopes Reveal Nitrogen Loading to Lake Tanganyika from Remote Shoreline Villages

NASA Astrophysics Data System (ADS)

Kelly, Brianne; Mtiti, Emmanuel; McIntyre, Peter B.; Vadeboncoeur, Yvonne

2017-02-01

Access to safe water is an ongoing challenge in rural areas in Tanzania where communities often lack access to improved sanitation. Methods to detect contamination of surface water bodies, such as monitoring nutrient concentrations and bacterial counts, are time consuming and results can be highly variable in space and time. On the northeast shore of Lake Tanganyika, Tanzania, the low population density coupled with the high potential for dilution in the lake necessitates the development of a sensitive method for detecting contamination in order to avoid human health concerns. We investigated the potential use of nitrogen and carbon stable isotopes of snail tissues to detect anthropogenic nutrient loading along the northeast shore of Lake Tanganyika. δ15N of snails was positively related to human population size in the nearest village, but only for villages with >4000 inhabitants. The areal footprint of villages within their watershed was also significantly correlated with snail δ15N, while agricultural land use and natural vegetation were not. Dissolved nutrient concentrations were not significantly different between village and reference sites. Our results indicate that nitrogen isotopes provide a sensitive index of local nutrient loading that can be used to monitor contamination of oligotrophic aquatic environments with low surrounding population densities.

Interaction between shallow groundwater, saline surface water and contaminant discharge at a seasonally and tidally forced estuarine boundary

NASA Astrophysics Data System (ADS)

Westbrook, S. J.; Rayner, J. L.; Davis, G. B.; Clement, T. P.; Bjerg, P. L.; Fisher, S. J.

2005-02-01

This paper presents findings from a 2-year field investigation of a dissolved hydrocarbon groundwater plume flowing towards a tidally and seasonally forced estuarine river system in Perth, Western Australia. Samples collected from transects of multiport wells along the riverbank and into the river, enabled mapping of the fine scale (0.5 m) vertical definition of the hydrocarbon plume and its longitudinal extent. Spear probing beneath the river sediments and water table, and transient monitoring of multiport wells (electrical conductivity) was also carried out to define the zone of mixing between river water and groundwater (the hyporheic zone) and its variability. The results showed that groundwater seepage into the estuarine surface sediments occurred in a zone less than 10 m from the high tide mark, and that this distance and the hyporheic transition zone were influenced by tidal fluctuations and infiltration of river water into the sediments. The dissolved BTEXN (benzene, toluene, ethylbenzene, the xylene isomers and naphthalene) distributions indicated the behaviour of the hydrocarbon plume at the groundwater/surface water transition zone to be strongly influenced by edge-focussed discharge. Monitoring programs and risk assessment studies at similar contaminated sites should therefore focus efforts within the intertidal zone where contaminants are likely to impact the surface water and shallow sediment environments.

Managing dredged material in the coastal zone of the Baltic Sea.

PubMed

Staniszewska, Marta; Boniecka, Helena

2017-01-01

This article deals with the legal and practical recommendations for the management of dredged material in the riparian countries of the Baltic Sea. The recommendations are contained in three conventions: LC, 2000. London Convention (1972), Convention on the Protection of the Marine Environment of the Baltic Sea area (Helsinki Convention) (1992), the OSPAR Convention (1972). Different approaches to evaluating the contamination level of dredge spoils, used by the Baltic Sea riparian countries, have been characterized. The differences in those approaches manifest themselves by various concentration limits for contaminants, which form a basis for the classification of dredged material as either contaminated or non-contaminated, and thus determine how the spoils will be processed further. Based on the collected information about the concentration limits for contaminants of surface sediments in the coastal ports, it was pointed out that it is necessary to conduct routine monitoring of heavy metals, polycyclic aromatic hydrocarbons, polychlorinated biphenyls, tributyltin, and petroleum hydrocarbons in dredged sediments in all the Baltic Sea states. On the other hand, the monitoring of polychlorinated dibenzo-p-dioxins/furans, organochlorine, and organophosphoric pesticides is only needed in locations that are suspected of historical or being the local contamination sources. Due to significant economic limitations of chemical determinations, it is important to consider a simple screening test of sediment that would say whether sediment may be "contaminated" and qualifies for more detailed and costly chemical research. It may be typical basic physical-chemical analysis of sediments or ecotoxicological classification of sediments.Despite environmentally friendly tendencies, the practical application of dredged material within the Baltic Sea area is very limited. Dredged material is most frequently stored at the specifically designated sites. From among the practical uses of dredge spoils, beach nourishment is of the highest significance.In the conclusion, the new proposed management procedure of dredged material was presented.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Elvado Environmental LLC

This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2009 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2009 will be in accordance with DOE Order 540.1 requirements and the following goals: (1) to protect the worker, the public, and the environment; (2) to maintain surveillance of existing and potential groundwater contamination sources; (3) to provide for the early detection of groundwater contamination andmore » determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; (4) to identify and characterize long-term trends in groundwater quality at Y-12; and (5) to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring during CY 2009 will be performed primarily in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley, and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge, along the boundary of the Oak Ridge Reservation. Modifications to the CY 2009 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. All modifications to the monitoring program will be approved by the Y-12 GWPP manager and documented as addenda to this sampling and analysis plan. The following sections of this report provide details regarding the CY 2009 groundwater and surface water monitoring activities. Section 2 describes the monitoring locations in each regime and the processes used to select the sampling locations. A description of the field measurements and laboratory analytes is provided in Section 3; sample collection methods and procedures are described in Section 4; and Section 5 lists the documents cited for more detailed operational and technical information.« less

Scale-dependency of macroinvertebrate communities: responses to contaminated sediments within run-of-river dams.

PubMed

Colas, Fanny; Archaimbault, Virginie; Devin, Simon

2011-03-01

Due to their nutrient recycling function and their importance in food-webs, macroinvertebrates are essential for the functioning of aquatic ecosystems. These organisms also constitute an important component of biodiversity. Sediment evaluation and monitoring is an essential aspect of ecosystem monitoring since sediments represent an important component of aquatic habitats and are also a potential source of contamination. In this study, we focused on macroinvertebrate communities within run-of-river dams, that are prime areas for sediment and pollutant accumulation. Little is known about littoral macroinvertebrate communities within run-of-river dam or their response to sediment levels and pollution. We therefore aimed to evaluate the following aspects: the functional and structural composition of macroinvertebrate communities in run-of-river dams; the impact of pollutant accumulation on such communities, and the most efficient scales and tools needed for the biomonitoring of contaminated sediments in such environments. Two run-of-river dams located in the French alpine area were selected and three spatial scales were examined: transversal (banks and channel), transversal x longitudinal (banks/channel x tail/middle/dam) and patch scale (erosion, sedimentation and vegetation habitats). At the patch scale, we noted that the heterogeneity of littoral habitats provided many available niches that allow for the development of diversified macroinvertebrate communities. This implies highly variable responses to contamination. Once combined on a global 'banks' spatial scale, littoral habitats can highlight the effects of toxic disturbances. Copyright © 2011 Elsevier B.V. All rights reserved.

Copper in indigenous and transplanted zebra mussels in relation to changing water concentrations and body weight

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mersch, J.; Wagner, P.; Pihan, J.C.

Zebra mussels, Dreissena polymorpha, were collected monthly from a copper-contaminated reservoir over a period of nearly 3 years. Copper concentrations in the organisms showed marked fluctuations reflecting changes in the water contamination. Bioconcentration patterns were influenced by the specific capacity of this sentinel organism to biologically integrate the continuously evolving water pollution; the sampling pattern, which inevitably introduced a certain subjectivity into monitoring results; and weight changes in the animals within the yearly cycle. Consequently, the successive monthly indications obtained with the zebra mussels provided a current biological assessment of a complex dynamic contamination situation. In a second experiment, cagedmore » mussels from three different populations were transferred for 3 months into the reservoir and sampled on six occasions. Mortality rates, attachment capacity, and a condition index revealed no substantial fitness disturbances in the transplanted organisms. Differences in dry weight throughout the experiment were attributable to the initial characteristics of each population. The influence of body mass on monitoring results was eliminated by replacing copper concentrations ({micro}g/g dry weight) with copper burdens ({micro}g/specimen). In terms of copper burdens, the three transplanted populations exhibited very similar metal patterns. Moderate quantitative differences between introduced and indigenous populations were interpreted as the result of physiological adaptation of the indigenous mussels to their contaminated environment. This study showed that the transfer technique with D. polymorpha is a useful tool for active biomonitoring programs.« less

Proposal for a Universal Particle Detector Experiment

NASA Technical Reports Server (NTRS)

Lesho, J. C.; Cain, R. P; Uy, O. M.

1993-01-01

The Universal Particle Detector Experiment (UPDE), which consists of parallel planes of two diode laser beams of different wavelengths and a large surface metal oxide semiconductor (MOS) impact detector, is proposed. It will be used to perform real-time monitoring of contamination particles and meteoroids impacting the spacecraft surface with high resolution of time, position, direction, and velocity. The UPDE will discriminate between contaminants and meteoroids, and will determine their velocity and size distribution around the spacecraft environment. With two different color diode lasers, the contaminant and meteroid composition will also be determined based on laboratory calibration with different materials. Secondary particles dislodged from the top aluminum surface of the MOS detector will also be measured to determine the kinetic energy losses during energetic meteoroid impacts. The velocity range of this instrument is 0.1 m/s to more than 14 km/s, while its size sensitivity is from 0.2 microns to millimeter-sized particles. The particulate measurements in space of the kind proposed will be the first simultaneous multipurpose particulate experiment that includes velocities from very slow to hypervelocities, sizes from submicrometer- to pellet-sized diameters, chemical analysis of the particulate composition, and measurements of the kinetic energy losses after energetic impacts of meteroids. The experiment will provide contamination particles and orbital debris data that are critically needed for our present understanding of the space environment. The data will also be used to validate contamination and orbital debris models for predicting optimal configuration of future space sensors and for understanding their effects on sensitive surfaces such as mirrors, lenses, paints, and thermal blankets.

Proposal for a universal particle detector experiment

NASA Astrophysics Data System (ADS)

Lesho, J. C.; Cain, R. P.; Uy, O. M.

The Universal Particle Detector Experiment (UPDE), which consists of parallel planes of two diode laser beams of different wavelengths and a large surface metal oxide semiconductor (MOS) impact detector, is proposed. It will be used to perform real-time monitoring of contamination particles and meteoroids impacting the spacecraft surface with high resolution of time, position, direction, and velocity. The UPDE will discriminate between contaminants and meteoroids, and will determine their velocity and size distribution around the spacecraft environment. With two different color diode lasers, the contaminant and meteroid composition will also be determined based on laboratory calibration with different materials. Secondary particles dislodged from the top aluminum surface of the MOS detector will also be measured to determine the kinetic energy losses during energetic meteoroid impacts. The velocity range of this instrument is 0.1 m/s to more than 14 km/s, while its size sensitivity is from 0.2 microns to millimeter-sized particles. The particulate measurements in space of the kind proposed will be the first simultaneous multipurpose particulate experiment that includes velocities from very slow to hypervelocities, sizes from submicrometer- to pellet-sized diameters, chemical analysis of the particulate composition, and measurements of the kinetic energy losses after energetic impacts of meteroids. The experiment will provide contamination particles and orbital debris data that are critically needed for our present understanding of the space environment. The data will also be used to validate contamination and orbital debris models for predicting optimal configuration of future space sensors and for understanding their effects on sensitive surfaces such as mirrors, lenses, paints, and thermal blankets.

A Study of Space Station Contamination Effects. [conference

NASA Technical Reports Server (NTRS)

Torr, M. R. (Editor); Spann, J. F. (Editor); Moorehead, T. W. (Editor)

1988-01-01

A workshop was held with the specific objective of reviewing the state-of-knowledge regarding Space Station contamination, the extent to which the various categories of contamination can be predicted, and the extent to which the predicted levels would interfere with onboard scientific investigations or space station functions. The papers presented at the workshop are compiled and address the following topics: natural environment, plasma electromagnetic environment, optical environment, particulate environment, spacecraft contamination, surface physics processes, laboratory experiments and vented chemicals/contaminants.

TEMPORAL VARIABILITY OF MICROBIAL INDICATORS OF FECAL CONTAMINATION OF MARINE AND FRESHWATER BEACHES

EPA Science Inventory

Monitoring methods for microbial indicators of fecal contamination are an integral component for protecting the health of swimmers exposed to potentially contaminated bathing beach waters. The design of monitoring systems which will accurately characterize the quality of water is...

Inorganic and organic contaminants in Alaskan shorebird eggs.

PubMed

Saalfeld, David T; Matz, Angela C; McCaffery, Brian J; Johnson, Oscar W; Bruner, Phil; Lanctot, Richard B

2016-05-01

Many shorebird populations throughout North America are thought to be declining, with potential causes attributed to habitat loss and fragmentation, reduced prey availability, increased predation, human disturbance, and increased exposure to environmental pollutants. Shorebirds may be particularly vulnerable to contaminant exposure throughout their life cycle, as they forage primarily on invertebrates in wetlands, where many contaminants accumulate disproportionately in the sediments. Therefore, it is important to document and monitor shorebird populations thought to be at risk and assess the role that environmental contaminants may have on population declines. To investigate potential threats and provide baseline data on shorebird contaminant levels in Alaskan shorebirds, contaminant concentrations were evaluated in shorebird eggs from 16 species residing in seven geographic distinct regions of Alaska. Similar to previous studies, low levels of most inorganic and organic contaminants were found, although concentrations of several inorganic and organic contaminants were higher than those of previous studies. For example, elevated strontium levels were observed in several species, especially black oystercatcher (Haematopus bachmani) sampled in Prince William Sound, Alaska. Additionally, contaminant concentrations varied among species, with significantly higher concentrations of inorganic contaminants found in eggs of pectoral sandpiper (Calidris melanotos), semipalmated sandpiper (Calidris pusilla), black oystercatcher, and bar-tailed godwit (Limosa lapponica). Similarly, significantly higher concentrations of some organic contaminants were found in the eggs of American golden plover (Pluvialis dominica), black-bellied plover (Pluvialis squatarola), pacific golden plover (Pluvialis fulva), bar-tailed godwit, and semipalmated sandpiper. Despite these elevated levels, current concentrations of contaminants in shorebird eggs suggest that breeding environments are relatively free of most contaminants and that contaminant concentrations are below levels (except potentially strontium) that would likely affect the survival of individuals and consequently regulate the species at the population level.

Remote Sensing Combined with Field Spectroscopy for the Detection and Monitoring of Heavy Metal Contamination from Informal E-waste Recycling

NASA Astrophysics Data System (ADS)

Friedlander, L. R.; Garb, Y.

2017-12-01

Electronic waste (e-waste) is one of today's fastest growing waste streams. Made up of discarded electronics, e-waste disposal is complex. However, e-waste also provides economic opportunity through the processing and extraction of precious metals. Sometimes referred to as "urban mining," this recycling operates informally or illegally and is characterized by dangerous practices such as, open-pit burning, acid leaching, and burning of low value wastes. Poorly controlled e-waste recycling releases dangerous contaminants, especially heavy metals, directly to the surface environment where they can infiltrate water resources and spread through precipitation events. Despite growing recognition of the prevalence of unregulated e-waste processing, systematic data on the extent and persistence of the released contamination is still limited. In general, contamination is established through techniques that provide only a snapshot in time and in a limited geographic area. Here we present preliminary results from attempts to combine field, laboratory, and remote sensing studies toward a systematic remote sensing methodology for e-waste contamination detection and monitoring. The ongoing work utilizes a tragic "natural experiment," in which over 500 e-waste burn sites were active over more than a decade in a variety of agricultural, residential, and natural contexts. We have collected over 100 soil samples for which we have both XRF and ICP-AES measurements showing soil Pb concentrations as high as 14000 ppm. We have also collected 480 in-situ reflectance spectra with corresponding soil samples over 4 field transects of areas with long-term burn activity. The most heavily contaminated samples come from within the burn sites and are made up of ash. Field spectra of these samples reflect their dark color with low overall reflectance and shallow spectral features. These spectra are challenging to use for image classification due to their similarity with other low-reflectance parts of the image (e.g., shadows). We have begun to distinguish shadows from the dark burn site centers by automatically detecting and masking shadows. This will allow us to utilize images taken at different times and our in-situ field spectral results to develop a method for monitoring contaminant spread from these complex point sources.

Microbial Fingerprints of Community Structure Correlate with Changes in Ecosystem Function Induced by Perturbing the Redox Environment

NASA Astrophysics Data System (ADS)

Mills, A. L.; Ford, R. M.; Vallino, J. J.; Herman, J. S.; Hornberger, G. M.

2001-12-01

Restoration of high-quality groundwater has been an elusive engineering goal. Consequently, natural microbially-mediated reactions are increasingly relied upon to degrade organic contaminants, including hydrocarbons and many synthetic compounds. Of concern is how the introduction of an organic chemical contaminant affects the indigenous microbial communities, the geochemistry of the aquifer, and the function of the ecosystem. The presence of functional redundancy in microbial communities suggests that recovery of the community after a disturbance such as a contamination event could easily result in a community that is similar in function to that which existed prior to the contamination, but which is compositionally quite different. To investigate the relationship between community structure and function we observed the response of a diverse microbial community obtained from raw sewage to a dynamic redox environment using an aerobic/anaerobic/aerobic cycle. To evaluate changes in community function CO2, pH, ammonium and nitrate levels were monitored. A phylogenetically-based DNA technique (tRFLP) was used to assess changes in microbial community structure. Principal component analysis of the tRFLP data revealed significant changes in the composition of the microbial community that correlated well with changes in community function. Results from our experiments will be discussed in the context of a metabolic model based the biogeochemistry of the system. The governing philosophy of this thermodynamically constrained metabolic model is that living systems synthesize and allocate cellular machinery in such a way as to "optimally" utilize available resources in the environment. The robustness of this optimization-based approach provides a powerful tool for studying relationships between microbial diversity and ecosystem function.

Vacuum mechatronics

NASA Technical Reports Server (NTRS)

Hackwood, Susan; Belinski, Steven E.; Beni, Gerardo

1989-01-01

The discipline of vacuum mechatronics is defined as the design and development of vacuum-compatible computer-controlled mechanisms for manipulating, sensing and testing in a vacuum environment. The importance of vacuum mechatronics is growing with an increased application of vacuum in space studies and in manufacturing for material processing, medicine, microelectronics, emission studies, lyophylisation, freeze drying and packaging. The quickly developing field of vacuum mechatronics will also be the driving force for the realization of an advanced era of totally enclosed clean manufacturing cells. High technology manufacturing has increasingly demanding requirements for precision manipulation, in situ process monitoring and contamination-free environments. To remove the contamination problems associated with human workers, the tendency in many manufacturing processes is to move towards total automation. This will become a requirement in the near future for e.g., microelectronics manufacturing. Automation in ultra-clean manufacturing environments is evolving into the concept of self-contained and fully enclosed manufacturing. A Self Contained Automated Robotic Factory (SCARF) is being developed as a flexible research facility for totally enclosed manufacturing. The construction and successful operation of a SCARF will provide a novel, flexible, self-contained, clean, vacuum manufacturing environment. SCARF also requires very high reliability and intelligent control. The trends in vacuum mechatronics and some of the key research issues are reviewed.

Early Results and Spaceflight Implications of the SWAB Flight Experiment

NASA Technical Reports Server (NTRS)

Ott, C. Mark; Pierson, Duane L.

2007-01-01

Microbial monitoring of spacecraft environments provides key information in the assessment of infectious disease risk to the crew. Monitoring aboard the Mir space station and International Space Station (ISS) has provided a tremendous informational baseline to aid in determining the types and concentrations of microorganisms during a mission. Still, current microbial monitoring hardware utilizes culture-based methodology which may not detect many medically significant organisms, such as Legionella pneumophila. We hypothesize that evaluation of the ISS environment using non-culture-based technologies would reveal microorganisms not previously reported in spacecraft, allowing for a more complete health assessment. To achieve this goal, a spaceflight experiment, operationally designated as SWAB, was designed to evaluate the DNA from environmental samples collected from ISS and vehicles destined for ISS. Results from initial samples indicate that the sample collection and return procedures were successful. Analysis of these samples using denaturing gradient gel electrophoresis and targeted PCR primers for fungal contaminants is underway. The current results of SWAB and their implication for in-flight molecular analysis of environmental samples will be discussed.

Monitored Natural Recovery at Contaminated Sediment Sites

DTIC Science & Technology

2009-05-01

Cr(VI)  hexavalent  chromium   Cr(III)  trivalent   chromium   CSM  conceptual site model  DBT  dibutyltin  DELT  deformities, eroded fins, lesions, and...nickel sulfide complexes in Foundry Cove, NY (USEPA 2005c).  Hexavalent chromium (Cr(VI)) reduction, subsequent precipitation as trivalent chromium (Cr...established scientific findings—such as the reduction of hexavalent chromium (Cr(VI)) to trivalent chromium (Cr(III)) in reduced environments (Martello et

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wellman, Dawn M.; Freshley, Mark D.; Truex, Michael J.

Current requirements for site remediation and closure are standards-based and are often overly conservative, costly, and in some cases, technically impractical to achieve. Use of risk-informed alternate endpoints provide a means to achieve remediation goals that are permitted by regulations and are protective of human health and the environment. Alternate endpoints enable establishing a path for cleanup that may include intermediate remedial milestones and transition points and/or regulatory alternatives to standards-based remediation. A framework is presented that is centered around developing and refining conceptual models in conjunction with assessing risks and potential endpoints as part of a system-based assessment thatmore » integrates site data with scientific understanding of processes that control the distribution and transport of contaminants in the subsurface and pathways to receptors. This system based assessment and subsequent implementation of the remediation strategy with appropriate monitoring are targeted at providing a holistic approach to addressing risks to human health and the environment. This holistic approach also enables effective predictive analysis of contaminant behavior to provide defensible criteria and data for making long-term decisions. Developing and implementing an alternate endpoint-based approach for remediation and waste site closure presents a number of challenges and opportunities. Categories of these challenges include scientific and technical, regulatory, institutional, and budget and resource allocation issues. Opportunities exist for developing and implementing systems-based approaches with respect to supportive characterization, monitoring, predictive modeling, and remediation approaches.« less

Three-dimensional data interpolation for environmental purpose: lead in contaminated soils in southern Brazil.

PubMed

Piedade, Tales Campos; Melo, Vander Freitas; Souza, Luiz Cláudio Paula; Dieckow, Jeferson

2014-09-01

Monitoring of heavy metal contamination plume in soils can be helpful in establishing strategies to minimize its hazardous impacts to the environment. The objective of this study was to apply a new approach of visualization, based on tridimensional (3D) images, of pseudo-total (extracted with concentrated acids) and exchangeable (extracted with 0.5 mol L(-1) Ca(NO3)2) lead (Pb) concentrations in soils of a mining and metallurgy area to determine the spatial distribution of this pollutant and to estimate the most contaminated soil volumes. Tridimensional images were obtained after interpolation of Pb concentrations of 171 soil samples (57 points × 3 depths) with regularized spline with tension in a 3D function version. The tridimensional visualization showed great potential of use in environmental studies and allowed to determine the spatial 3D distribution of Pb contamination plume in the area and to establish relationships with soil characteristics, landscape, and pollution sources. The most contaminated soil volumes (10,001 to 52,000 mg Pb kg(-1)) occurred near the metallurgy factory. The main contamination sources were attributed to atmospheric emissions of particulate Pb through chimneys. The large soil volume estimated to be removed to industrial landfills or co-processing evidenced the difficulties related to this practice as a remediation strategy.

Environmental contaminants in food. Volume II-part a: working papers. I. Priority setting of toxic substances for guiding monitoring programs. II. Five case studies of environmental food contamination

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This volume contains working papers written for Office of Technology Assessment (OTA) to assist in preparation of the report Environmental Contaminants in Food. The contents include: (1) Priority setting of toxic substances for guiding monitoring programs; and (2) Five case studies of environmental food contamination.

Pollution monitoring of puget sound with honey bees.

PubMed

Bromenshenk, J J; Carlson, S R; Simpson, J C; Thomas, J M

1985-02-08

To show that honey bees are effective biological monitors of environmental contaminants over large geographic areas, beekeepers of Puget Sound, Washington, collected pollen and bees for chemical analysis. From these data, kriging maps of arsenic, cadmium, and fluoride were generated. Results, based on actual concentrations of contaminants in bee tissues, show that the greatest concentrations of contaminants occur close to Commencement Bay and that honey bees are effective as large-scale monitors.

Evaluation of a new mobile system for protecting immune-suppressed patients against airborne contamination.

PubMed

Poirot, Jean-Louis; Gangneux, Jean-Pierre; Fischer, Alain; Malbernard, Mireille; Challier, Svetlana; Laudinet, Nicolas; Bergeron, Vance

2007-09-01

Invasive aspergillosis is one of the most lethal airborne dangers for immune-suppressed subjects. Providing patient protection from such airborne threats requires costly and high-maintenance facilities. We herein evaluate a new self-contained mobile unit as an alternative for creating a patient protective environment. Airborne contamination levels were monitored for different simulated scenarios and under actual clinical conditions. Functional tests were used to challenge the unit under adverse conditions, and a preliminary clinical study with patients and staff present was performed at 2 different French hospitals. Functional tests demonstrated that the unit can rapidly decontaminate air in the protected zone created by the unit and in the surrounding room. In addition, the protected zone is not sensitive to large disturbances that occur in the room. The clinical study included 4 patients with 150 accumulated days of testing. The protected zone created by the unit systematically provided an environment with undetectable airborne fungal levels (ie, <1 CFU/m(3)) regardless of the levels in the room or corridor (P < .01). These tests show that the unit can be used to create a mobile protective environment for immune-suppressed patients in a standard hospital setting.

77 FR 22282 - Draft Guidelines on Biologics Quality Monitoring: Testing for the Detection of Mycoplasma...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-04-13

...] Draft Guidelines on Biologics Quality Monitoring: Testing for the Detection of Mycoplasma Contamination... Detection of Mycoplasma Contamination.'' This draft guideline identifies stages of manufacture where... contamination. Because the guidelines apply to final product and master seed/cell testing in veterinary vaccines...

Development of LC/MS/MS Methods for Implementation in US EPA’s Drinking Water Unregulated Contaminant Monitoring Regulations

EPA Science Inventory

Well-characterized and standardized methods are the foundation upon which monitoring of regulated and unregulated contaminants in drinking water are based. To obtain reliable, high quality data for trace analysis of contaminants, these methods must be rugged, selective and sensit...

ELEMENTAL FISH TISSUE CONTAMINATION IN NORTHEASTERN U.S. LAKES: EVALUATION OF AN APPROACH TO REGIONAL ASSESSMENT

EPA Science Inventory

The approach of the Environmental Monitoring and Assessment Program (EMAP) to monitoring of fish tissue contaminants is shown to have utility for regional assessment,and for discrimination of regional from local contamination.The survey sampling design employed by EMAP can be use...

ELEMENTAL FISH TISSUE CONTAMINATION IN NORTHEASTERN U.S. LAKES: EVALUATION OF AN APPROACH TO REGIONAL ASSESSMENT

EPA Science Inventory

The approach of the Environmental Monitoring and Assessment Program (EMAP) to monitoring of fish tissue contaminants is shown to have utility for regional assessment, and for discrimination of regional from local contamination. The survey sampling design employed EMAP can be used...

MONITORING THE SUCCESS OF SEDIMENT REMEDIATION AT A SITE CONTAMINATED WITH CHLORINATED PESTICIDES, POLYNUCLEAR AROMATIC HYDROCARBONS AND ARSENIC

EPA Science Inventory

Monitoring the Success of Sediment Remediation at a Site Contaminated with Chlorinated Pesticides, Polynuclear Aromatic Hydrocarbons and Arsenic (Baird & McGuire Superfund Site, Holbrook, MA) Contaminated sediment in the Cochato River adjacent to the Baird & McGuire Superfund Sit...

Incorporating bioavailability into management limits for copper in sediments contaminated by antifouling paint used in aquaculture.

PubMed

Simpson, Stuart L; Spadaro, David A; O'Brien, Dom

2013-11-01

Although now well embedded within many risk-based sediment quality guideline (SQG) frameworks, contaminant bioavailability is still often overlooked in assessment and management of contaminated sediments. To optimise management limits for metal contaminated sediments, we assess the appropriateness of a range methods for modifying SQGs based on bioavailability considerations. The impairment of reproduction of the amphipod, Melita plumulosa, and harpacticoid copepod, Nitocra spinipes, was assessed for sediments contaminated with copper from antifouling paint, located below aquaculture cages. The measurement of dilute acid-extractable copper (AE-Cu) was found to provide the most useful means for monitoring the risks posed by sediment copper and setting management limits. Acid-volatile sulfide was found to be ineffective as a SQG-modifying factor as these organisms live mostly at the more oxidised sediment water interface. SQGs normalised to %-silt/organic carbon were effective, but the benefits gained were too small to justify this approach. The effectiveness of SQGs based on AE-Cu was attributed to a small portion of the total copper being present in potentially bioavailable forms (typically<10% of the total). Much of the non-bioavailable form of copper was likely present as paint flakes in the form of copper (I) oxide, the active ingredient of the antifoulant formulation. While the concentrations of paint-associated copper are very high in some sediments, as the transformation of this form of copper to AE-Cu appears slow, monitoring and management limits should assess the more bioavailable AE-Cu forms, and further efforts be made to limit the release of paint particles into the environment. Crown Copyright © 2013. Published by Elsevier Ltd. All rights reserved.

Contamination monitoring approaches for EUV space optics

NASA Technical Reports Server (NTRS)

Ray, David C.; Malina, Roger F.; Welsh, Barry J.; Battel, Steven J.

1989-01-01

Data from contaminant-induced UV optics degradation studies and particulate models are used here to develop end-of-service-life instrument contamination requirements which are very stringent but achievable. The budget is divided into allocations for each phase of hardware processing. Optical and nonoptical hardware are monitored for particulate and molecular contamination during initial cleaning and baking, assembly, test, and calibration phases. The measured contamination levels are compared to the requirements developed for each phase to provide confidence that the required end-of-life levels will be met.

Monitoring hygiene on- and at-line is critical for controlling Listeria monocytogenes during produce processing.

PubMed

Pappelbaum, Krystyna; Grif, Katharina; Heller, Ingrid; Wüirzner, Reinhard; Hein, Ingeborg; Ellerbroek, Lueppo; Wagner, Martin

2008-04-01

The prevalence of Listeria monocytogenes in different types of produce and on processing plant environments was investigated over a 4-year period in a large produce processing plant in Poland. Prevalence of L. monocytogenes was 46% in frozen vegetables and 41.3% in swab samples taken from the plant environment. Survival studies using artificial inocula demonstrated that the number of Listeria in frozen produce stored for 100 days did not significantly decrease in relation to the initial contamination level. A subset of 129 L. monocytogenes isolates originating from produce and the plant environment were typed by pulsed-field gel electrophoresis. Seventy-six of these isolates were retyped by ribo- and serotyping. Thirteen pulsotypes and 18 ribotypes were distinguished. Persistent Listeria isolates were found even when cleansing and sanitization was applied on a daily basis. Nine (69.2%) of 13 pulsotypes were recovered during a period of more than 2 years. L. monocytogenes of the same pulsotype was isolated from broccoli sampled directly before and after blanching, thus suggesting that blanching at 92 to 95 degrees C for 4 to 8 min did not result in a Listeria-free product, most likely due to massive recontamination. This finding is of importance since blanching is the only critical control point in produce processing. Cross-contamination between the two lines was demonstrated through isolating L. monocytogenes strains indistinguishable by pulsed-field gel electrophoresis from contaminated gloves and floor surfaces.

Application of remote sensing data to monitoring of oil pollution as part of the environmental expert system

NASA Astrophysics Data System (ADS)

Shagarova, Lyudmila; Muratova, Mira; Abuova, Sholpan

2016-07-01

The impact of oil-producing facilities on the environment is caused by toxicity of hydrocarbons and by-products, a variety of chemicals used in industrial processes, as well as specificity of production, treatment, transportation and storage of oil and oil products. To predict the state of the geological environment, scientists carry out investigations, which help to choose the optimal strategy for creation of the expert system taking into account simulations and to provide efficient use of available environmentally relevant information related to the current state of the geological environment. The expert system is a complex of interconnected blocks, one of which is the information on the presence of oil pollution, which can be identified using satellite imagery. The satellite imagery has practical application in monitoring of oil pollution, as it allows specialists to identify oil spills remotely and to determine their characteristics based on the differentiation of the surface reflectance spectra. Snapshots are used to estimate the area of oil-contamination and location of spills. To detect contaminants it is necessary to perform the following steps in processing of the remote sensing data: - Identify and isolate all the dark deformations in the satellite images, as a result of processing of segmentation and threshold processing; - Calculate statistical parameters of dark deformations, i.e., signs similar to areas prone to contamination. These signs are related to the geometry of formation, their physical changes (backscattering value) and the image context; - Classify the selected spectral anomalies as oil pollution and oil sludge. On the basis of classification of satellite imagery, the objects of oil pollution are detected and deciphering signs are analyzed in order to refer classified objects to implicit or explicit contaminations. To detect oil pollution, pixels are classified into categories with learning on the given areas with creation of the corresponding signature for each of them, i.e. the area with a given class, which is used to determine centers of classes in further supervised classification. The classification process compares the luminance of pixels with the training sample, as a result, each pixel is referred to the most appropriate class of objects. The development of an expert system using digital space information will extend the circle of problems solved in the environmental protection, creation of complex schemes of intensive development of hydrocarbon production regions in view of environmental risks.

Contamination of soil and the medicinal plant Phyllanthus niruri Linn. with cadmium in ceramic industrial areas.

PubMed

Santos, Vanessa Santana Vieira; Arantes, Karen Magalhães; Gonçalves, Ester Luiza; Campos, Carlos Fernando; de Campos Júnior, Edimar Olegário; de Oliveira, Antônio Marcos Machado; Pereira, Boscolli Barbosa

2018-04-22

Phyllanthus niruri is a plant that is used to prevent calcium oxalate crystallisation and to block the stone formation in urolithiasis. Contaminants in the environment can be readily taken up by medicinal plants due to their ability to absorb chemicals into their tissues. If contaminated plants are ingested, they have the potential to negatively affect human and environmental health. The aim of this study was to assess contamination in the soil and the medicinal plant P. niruri by cadmium (Cd) in ceramic industrial areas of Monte Carmelo, Brazil. Soil samples and plant samples (divided in root, shoot and leaves) were collected from a contaminated monitoring site and from a rural area (which was used as a reference site for comparative purposes). The Cd concentrations of the samples were analysed with an atomic absorption spectrometer. P. niruri was found to be sensitive to soil contamination by Cd that was attributed to ceramic industrial emissions. The results revealed that Cd bioaccumulation in the roots and shoots of P. niruri was associated with a significant increase (p < 0.05) in the concentration of active lignan compounds (phyllanthin and hypophyllanthin) in the leaves. The identification of high concentrations of Cd and active lignan compounds suggests a risk of contamination of the site and the risk of a high dose of Cd to people exposed at the site.

Sitewide monitoring at Agra, Kansas, June 2009.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.; Environmental Science Division

In 1985, carbon tetrachloride was discovered in the groundwater at Agra, Kansas, during routine sampling of public water supply wells. Two of Agra's four public water supply wells contained low but detectable levels of carbon tetrachloride; the concentrations in wells PWS-3 and PWS-4 exceeded the maximum contaminant level. These wells were removed from service in 1986, although they remain available for uses other than drinking water. Other public wells, outside the area of contamination, supply drinking water for the city of Agra. In 1987-2005, the Kansas Department of Health and Environment (KDHE) and the Commodity Credit Corporation of the U.S.more » Department of Agriculture (CCC/USDA) conducted investigations to delineate the contaminant plume and to identify source areas for the contamination - which results from the past use of grain fumigants containing carbon tetrachloride. Source areas were identified on the former CCC/USDA grain storage facility property and on the Producers Agricultural Marketing Association, Inc., property located to the south (Argonne 2006). The contaminant plume extends to the southeast, toward well PWS-3, from the identified source areas. Both the CCC/USDA and Pro-Ag Marketing are currently implementing KDHE-approved interim measures (IMs). To address the contamination identified on its former property, the CCC/USDA is implementing a source control IM consisting of large-diameter boreholes (LDBs) coupled with soil vapor extraction (SVE) and air sparging (AS). Pro-Ag Marketing plans to use groundwater extraction to address the downgradient plume. The CCC/USDA and Pro-Ag completed installation of the two interim measures in May 2009 and August 2009, respectively. The performance and assessments of the effectiveness of the IMs are being reported separately by the responsible entities. As part of the IM process, the KDHE (2008) requested the development of a joint sitewide groundwater monitoring plan to allow periodic assessment of the effectiveness of the separate IMs being implemented by the CCC/USDA and Pro-Ag, through monitoring of the level of contamination and the resulting change in both the extent and internal configuration of the downgradient plume. A Joint Work Plan for Sitewide Monitoring was developed by the CCC/USDA through its technical consultant, Argonne National Laboratory, and was reviewed, approved, and signed by Pro-Ag Marketing and subsequently submitted to the KDHE on May 12, 2009. The KDHE (2009a) provided comments on the Joint Work Plan on May 27, 2009, requesting submission of a revised version. To minimize delays, the KDHE allowed the CCC/USDA to proceed with the scheduled annual sampling proposed in the Joint Work Plan. The sampling was to be conducted according to the previously approved low-flow sampling methodology (Argonne 2009). Argonne conducted the first annual sampling event for the CCC/USDA on June 15-16, 2009. The finalized, signed version of the Joint Work Plan provided to the KDHE on November 9, 2009, is in Appendix A. Table 1.1 lists the monitoring and public water supply wells to be sampled under the Joint Work Plan, plus the wells being sampled to monitor the respective IMs. The entity responsible for each monitoring element is indicated, along with well completion dates and well registration numbers. The subject of this report is the initial sitewide groundwater sampling event that occurred on June 15-16, 2009, under the Joint Work Plan.« less

Time vs. Money: A Quantitative Evaluation of Monitoring Frequency vs. Monitoring Duration.

PubMed

McHugh, Thomas E; Kulkarni, Poonam R; Newell, Charles J

2016-09-01

The National Research Council has estimated that over 126,000 contaminated groundwater sites are unlikely to achieve low ug/L clean-up goals in the foreseeable future. At these sites, cost-effective, long-term monitoring schemes are needed in order to understand the long-term changes in contaminant concentrations. Current monitoring optimization schemes rely on site-specific evaluations to optimize groundwater monitoring frequency. However, when using linear regression to estimate the long-term zero-order or first-order contaminant attenuation rate, the effect of monitoring frequency and monitoring duration on the accuracy and confidence for the estimated attenuation rate is not site-specific. For a fixed number of monitoring events, doubling the time between monitoring events (e.g., changing from quarterly monitoring to semi-annual monitoring) will double the accuracy of estimated attenuation rate. For a fixed monitoring frequency (e.g., semi-annual monitoring), increasing the number of monitoring events by 60% will double the accuracy of the estimated attenuation rate. Combining these two factors, doubling the time between monitoring events (e.g., quarterly monitoring to semi-annual monitoring) while decreasing the total number of monitoring events by 38% will result in no change in the accuracy of the estimated attenuation rate. However, the time required to collect this dataset will increase by 25%. Understanding that the trade-off between monitoring frequency and monitoring duration is not site-specific should simplify the process of optimizing groundwater monitoring frequency at contaminated groundwater sites. © 2016 The Authors. Groundwater published by Wiley Periodicals, Inc. on behalf of National Ground Water Association.

Temporal dynamics of urbanization-driven environmental changes explored by metal contamination in surface sediments in a restoring urban wetland park.

PubMed

Ma, Jun; Liu, Yi; Yu, Guangbin; Li, Hongbo; Yu, Shen; Jiang, Yueping; Li, Guilin; Lin, Jinchang

2016-05-15

Spatial patterns of metal distribution along urban-rural or multi-city gradients indicate that the urbanization process directly lead to metal enrichment and contamination in the environments. However, it has not yet looked at homogenization dynamics of an urban-rural gradient pattern over time with urbanization process in an area. This study monitored anthropogenic metals (Cr, Cu, Pb, and Zn) in surface sediments from channels of a newly-opened National Wetland Park to elucidate the urbanization-driven dissolution of urban-rural gradient pattern between 2008 and 2011. Sixty-eight surface sediment samples were taken from these channels in July of both 2008 and 2011. Results showed that a spatial distribution pattern of total metal contents along the gradient of urbanization influence, evident in 2008, was homogenized in 2011 with the area development. The lead stable isotope ratio analysis identified anthropogenic Pb origins from vehicular exhausts, cements, and coal flying ashes, which elevated metal contents in the inner channels via atmospheric deposition. Specific hazard quotients of the metal contamination in surface sediment were also assessed and enhanced over time in the study wetland park. These findings suggest that emissions from traffic, construction, and energy generation contribute metal loadings in the urbanizing environment. Copyright © 2016 Elsevier B.V. All rights reserved.

The influence of industrial and agricultural waste on water quality in the Água Boa stream (Dourados, Mato Grosso do Sul, Brazil).

PubMed

da Rocha, Monyque Palagano; Dourado, Priscila Leocadia Rosa; de Souza Rodrigues, Mayara; Raposo, Jorge Luiz; Grisolia, Alexeia Barufatti; de Oliveira, Kelly Mari Pires

2015-07-01

Water quality monitoring is used to determine the impact of human activities on the environment. We evaluated water quality in the Água Boa stream, located within the municipality of Dourados, State of Mato Grosso do Sul, Brazil, by analyzing physico-chemical, chemical, and microbiological parameters, as well as chlorophyll concentrations. Five sets of water samples were collected between December 2012 and November 2013 from three locations within the stream. The results showed the presence of Escherichia coli and antibiotic-resistant Pseudomonas spp. strains and high concentrations of organic matter (total dissolved solids), inorganic species (Mg, Ca, and Fe), and agrochemical residues (thiamethoxam). The main stream water contaminants are derived from urban, industrial, and agricultural activities within the watershed. Given the presence of contaminants, it is important that such findings are disseminated in order to highlight the risks that contact with this water may pose to human health. To preserve the environment and improve site conditions, people would need to participate by demanding that normative national and international standards be respected and that the situation be supervised by the competent governmental agencies; this would make it possible to reverse or minimize contamination problems within the Água Boa stream.

Soil-plant relationships and contamination by trace elements: A review of twenty years of experimentation and monitoring after the Aznalcóllar (SW Spain) mine accident.

PubMed

Madejón, Paula; Domínguez, María T; Madejón, Engracia; Cabrera, Francisco; Marañón, Teodoro; Murillo, José M

2018-06-01

Soil contamination by trace elements (TE) is a major environmental problem and much research is done into its effects on ecosystems and human health, as well as into remediation techniques. The Aznalcóllar mine accident (April 1998) was a large-scale ecological and socio-economic catastrophe in the South of Spain. We present here a literature review that synthesizes the main results found during the research conducted at the affected area over the past 20years since the mine accident, focused on the soil-plant system. We review, in depth, information about the characterization of the mine slurry and contaminated soils, and of the TE monitoring, performed until the present time. The reclamation techniques included the removal of sludge and soil surface layer and use of soil amendments; we review the effects of different types of amendments at different spatial scales and their effectiveness with time. Monitoring of TE in soil and their transfer to plants (crops, herbs, shrubs, and trees) were evaluated to assess potential toxicity effects in the food web. The utility of some plants (accumulators) with regard to the biomonitoring of TE in the environment was also evaluated. On the other hand, retention of TE by plant roots and their associated microorganisms was used as a low-cost technique for TE stabilization and soil remediation. We also evaluate the experience acquired in making the Guadiamar Green Corridor a large-scale soil reclamation and phytoremediation case study. Copyright © 2017 Elsevier B.V. All rights reserved.

Monitoring the effect of poplar trees on petroleum-hydrocarbon and chlorinated-solvent contaminated ground water

USGS Publications Warehouse

Landmeyer, James E.

2001-01-01

At contaminated groundwater sites, poplar trees can be used to affect ground-water levels, flow directions, and ultimately total groundwater and contaminant flux to areas downgradient of the trees. The magnitude of the hydrologic changes can be monitored using fundamental concepts of groundwater hydrology, in addition to plant physiology-based approaches, and can be viewed as being almost independent of the contaminant released. The affect of poplar trees on the fate of groundwater contaminants, however, is contaminant dependent. Some petroleum hydrocarbons or chlorinated solvents may be mineralized or transformed to innocuous compounds by rhizospheric bacteria associated with the tree roots, mineralized or transformed by plant tissues in the transpiration stream or leaves after uptake, or passively volatilized and rapidly dispersed or oxidized in the atmosphere. These processes also can be monitored using a combination of physiological- or geochemical-based field or laboratory approaches. When combined, such hydrologic and contaminant monitoring approaches can result in a more accurate assessment of the use of poplar trees to meet regulatory goals at contaminated groundwater sites, verify that these goals continue to be met in the future, and ultimately lead to a consensus on how the performance of plant-based remedial strategies (phytoremediation) is to be assessed.

Pollution monitoring of Puget Sound with honey bees

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bromenshenk, J.J.; Carlson, S.R.; Simpson, J.C.

To show that honey bees are effective biological monitors of environmental contaminants over large geographic areas, beekeepers of Puget Sound, Washington, collected pollen and bees for chemical analysis. From these data, kriging maps of arsenic, cadmium, and fluoride were generated. Results, based on actual concentrations of contaminants in bee tissues, show that the greatest concentrations of contaminants occur close to Commencement Bay and that honey bees are effective as large-scale monitors. 27 references, 2 figures.

40 CFR 141.50 - Maximum contaminant level goals for organic contaminants.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Maximum contaminant level goals for organic contaminants. 141.50 Section 141.50 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS Maximum Contaminant Level...

Microbiologic Testing for 503A Sterile-Compounding Pharmacies.

PubMed

Mixon, William; Roth, Abby

2017-01-01

Compounding pharmacists must ensure that the sterile preparations they dispense are free of microbiologic contamination. Working in a cleanroom under controlled conditions (proper differential air pressure, temperature, and humidity; acceptable levels of viable and nonviable airborne particles and surface counts, etc.) and testing the efficacy of cleaning and disinfecting practices via environmental monitoring (viable-air and surface testing, glove-fingertip-thumb testing, etc.) are essential to preparing contamination-free medications. Sterile-compounding pharmacists must understand how to monitor their cleanroom environment and, if they perform testing in house, to interpret the results of simple microbiologic tests (a skill helpful even when tests are outsourced to a contract laboratory). In this article, which pertains to 503A sterile compounding, and is based on the current version of United States Pharmacopeia (USP) Chapter <797>, basic concepts in microbiology and the microbial tests that can be performed and interpreted in house and those that must be outsourced are discussed. Streamlining communication with contract laboratory personnel is reviewed. Requirements for an inhouse microbiology laboratory are presented, and the advantages and disadvantages of inhouse and outsourced testing are examined. A list of suggested reading is provided for easy reference. In a subsequent article, environmental monitoring and analysis will be addressed in detail. Copyright© by International Journal of Pharmaceutical Compounding, Inc.

Closeups of IECM grappled by RMS and positioned above payload bay (PLB)

NASA Image and Video Library

1982-07-04

STS004-23-119 (27 June-4 July 1982) --- This is a close-up view of the Marshall Space Flight Center-developed Induced Environment Contamination Monitor (IECM), a multi-instrument box designed to check for contaminants in and around the space shuttle orbiter cargo bay which might adversely affect delicate experiments carried aboard. The astronaut crew of Thomas K. Mattingly II and Henry W. Hartsfield Jr. maneuvered the Canadian-built robot arm (called the remote manipulator system) very near their overhead flight deck windows and captured this scene with a 35mm camera. HOLD PICTURE HORIZONTALLY WITH FRAME NUMBER AT TOP CENTER. Cameras for the 11 instruments are pictured as black circles at the bottom of the frame. The access door to the arm and safe plug is located about halfway up the left edge of the box. A cascade injector device is immediately to the right of the plug. The rectangular opening at right center of the monitor is the optical effects module. Mass spectrometer is at upper left. Air sampler bottles are at upper left. The colorful rectangle near upper left of the monitor is the passive array. Not easily seen, but also a part of the instrument, are the cryogenic quartz crystal micro balance and the temperature controlled quartz micro balance. Photo credit: NASA

Evaluation of targeted and untargeted effects-based monitoring tools to assess impacts of contaminants of emerging concern on fish in the South Platte River, CO

EPA Science Inventory

Rivers in the arid Western United States face increasing influences from anthropogenic contaminants due to population growth, urbanization, and drought. To better understand and more effectively track the impacts of these contaminants, biologically-based monitoring tools are incr...

EPA Workshop on Monitored Natural Attenuation for Inorganic Contaminants: 3 – Discussion of Specific Contaminants & Case Study

EPA Science Inventory

The purpose of this training is to present an overview of site characterization approaches to support evaluation of the potential for Monitored Natural Attenuation (MNA) as a remedy for inorganic contaminants in ground water. The training will include discussion of the types of ...

A COMPENDIUM OF CHEMICAL, PHYSICAL AND BIOLOGICAL METHODS FOR ASSESSING AND MONITORING THE REMEDIATION OF CONTAMINATED SEDIMENT SITES

EPA Science Inventory

Considering the many organizations which have published methods for monitoring contaminated sediments and the large number of documents on this subject, it can be a formidable task for a superfund project manager to find methods appropriate for his or her contaminated sediment si...

Hydraulic Fracturing and the Environment

NASA Astrophysics Data System (ADS)

Ayatollahy Tafti, T.; Aminzadeh, F.; Jafarpour, B.; de Barros, F.

2013-12-01

In this presentation, we highlight two key environmental concerns of hydraulic fracturing (HF), namely induced seismicity and groundwater contamination (GC). We examine the induced seismicity (IS) associated with different subsurface fluid injection and production (SFIP) operations and the key operational parameters of SFIP impacting it. In addition we review the key potential sources for possible water contamination. Both in the case of IS and GC we propose modeling and data analysis methods to quantify the risk factors to be used for monitoring and risk reduction. SFIP include presents a risk in hydraulic fracturing, waste water injection, enhanced oil recovery as well as geothermal energy operations. Although a recent report (NRC 2012) documents that HF is not responsible for most of the induced seismicities, we primarily focus on HF here. We look into vaious operational parameters such as volume and rate of water injection, the direction of the well versus the natural fracture network, the depth of the target and the local stress field and fault system, as well as other geological features. The latter would determine the potential for triggering tectonic related events by small induced seismicity events. We provide the building blocks for IS risk assessment and monitoring. The system we propose will involve adequate layers of complexity based on mapped seismic attributes as well as results from ANN and probabilistic predictive modeling workflows. This leads to a set of guidelines which further defines 'safe operating conditions' and 'safe operating zones' which will be a valuable reference for future SFIP operations. We also illustrate how HF can lead to groundwater aquifer contamination. The source of aquifer contamination can be the hydrocarbon gas or the chemicals used in the injected liquid in the formation. We explore possible pathways of contamination within and discuss the likelihood of contamination from each source. Many of the chemical compounds used in HF fluids are carcinogenic and may pose risk to humans. In addition, recovered HF fluids can be contaminated. We illustrate how different pathways can lead to the risk of aquifer contamination and consequently, risk to human health.

Pilot-scale UV/H2O2 study for emerging organic contaminants decomposition.

PubMed

Chu, Xiaona; Xiao, Yan; Hu, Jiangyong; Quek, Elaine; Xie, Rongjin; Pang, Thomas; Xing, Yongjie

2016-03-01

Human behaviors including consumption of drugs and use of personal care products, climate change, increased international travel, and the advent of water reclamation for direct potable use have led to the introduction of significant amounts of emerging organic contaminants into the aqueous environment. In addition, the lower detection limits associated with improved scientific methods of chemical analysis have resulted in a recent increase in documented incidences of these contaminants which previously were not routinely monitored in water. Such contaminants may cause known or suspected adverse ecological and/or human health effects at very low concentrations. Conventional drinking water treatment processes may not effectively remove these organic contaminants. Advanced oxidation process (AOP) is a promising treatment process for the removal of most of these emerging organic contaminants, and has been accepted worldwide as a suitable treatment process. In this study, different groups of emerging contaminants were studied for decomposition efficiency using pilot-scale UV/H2O2 oxidation setup, including EDCs, PPCPs, taste and odor (T&O), and perfluorinated compounds. Results found that MP UV/H2O2 AOP was efficient in removing all the selected contaminants except perfluorinated compounds. Study of the kinetics of the process showed that both light absorption and quantum yield of each compound affected the decomposition performance. Analysis of water quality parameters of the treated water indicated that the outcome of both UV photolysis and UV/H2O2 processes can be affected by changes in the feed water quality.

Annual report of groundwater monitoring at Centralia, Kansas, in 2010.

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.

In September 2005, periodic sampling of groundwater was initiated by the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) in the vicinity of a grain storage facility formerly operated by the CCC/USDA at Centralia, Kansas. The sampling at Centralia is performed on behalf of the CCC/USDA by Argonne National Laboratory, in accord with a monitoring program approved by the Kansas Department of Health and Environment (KDHE). The objective is to monitor levels of carbon tetrachloride contamination identified in the groundwater at Centralia (Argonne 2003, 2004, 2005a). Under the KDHE-approved monitoring plan (Argonne 2005b), the groundwater was sampled twicemore » yearly from September 2005 until September 2007 for analyses for volatile organic compounds (VOCs), as well as measurement of selected geochemical parameters to aid in the evaluation of possible natural contaminant degradation processes (reductive dechlorination) in the subsurface environment (Argonne 2006, 2007a, 2008a). The results from the two-year sampling program demonstrated the presence of carbon tetrachloride contamination at levels exceeding the KDHE Tier 2 risk-based screening level (RBSL) of 5 {micro}g/L for this compound, in a localized groundwater plume that has shown little movement. The relative concentrations of chloroform, the primary degradation product of carbon tetrachloride, suggested that some degree of reductive dechlorination or natural biodegradation was talking place in situ at the former CCC/USDA facility on a localized scale. The CCC/USDA subsequently developed an Interim Measure Conceptual Design (Argonne 2007b), proposing a pilot test of the Adventus EHC technology for in situ chemical reduction (ISCR). The proposed interim measure (IM) was approved by the KDHE in November 2007 (KDHE 2007). Implementation of the pilot test occurred in November-December 2007. The objective was to create highly reducing conditions that would enhance both chemical and biological reductive dechlorination in the injection test area (Argonne 2009a). The KDHE (2008a) requested that sitewide monitoring continue until a final remedy is selected (as part of a Corrective Action Study [CAS] evaluation) and implemented. In response to this request, the established sampling across the site and additional sampling in the IM pilot test area continued in 2008 (Argonne 2008b, 2009a,b). On the basis of results of the 2005-2008 sitewide monitoring and the 2008 IM pilot test monitoring, the CCC/USDA recommended a revised sampling program for both the wider site and the IM pilot test area (Section 4.2 in Argonne 2009b). The elements of this interim monitoring plan are as follows: (1) Annual sampling of twelve monitoring points across the site (Figure 1.1) and five outlying IM pilot test monitoring points (PMP4, PMP5, PMP6, PMP7, PMP9; Figure 1.2); and (2) Twice yearly sampling of five IM pilot test monitoring points inside the injection area (PMP1-PMP3, PMP8, MW02; Figure 1.2). With the approval of the KDHE (2009), the initial groundwater sampling for VOCs and geochemical analyses under the interim monitoring plan outlined above was conducted in 2009 (Argonne 2010). The present report documents the findings of the 2010 monitoring events, conducted on April 5 and September 19-21, 2010.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

LaFreniere, L. M.; Environmental Science Division

In September 2005, the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) initiated periodic sampling of groundwater in the vicinity of a grain storage facility formerly operated by the CCC/USDA at Morrill, Kansas. On the basis of available information, the CCC/USDA believes that one or more third parties operated this facility after termination of the CCC/USDA's lease in 1971. The sampling at Morrill is being performed on behalf of the CCC/USDA by Argonne National Laboratory, in accord with a monitoring program approved by the Kansas Department of Health and Environment (KDHE), to monitor levels of carbon tetrachloride contaminationmore » identified in the groundwater at this site (Argonne 2004, 2005a). Under the KDHE-approved monitoring plan (Argonne 2005b), the groundwater has been sampled twice yearly for a recommended period of two years. The samples are analyzed for volatile organic compounds (VOCs), as well as for selected geochemical parameters to aid in the evaluation of possible natural contaminant degradation (reductive dechlorination) processes in the subsurface environment. The sampling is presently conducted in a network of 12 monitoring wells and 3 private wells (Figure 1.1), at locations approved by the KDHE. The scope of the originally approved monitoring has been expanded to include vegetation sampling (initiated in October 2006) and surface water and stream bed sediment sampling (initiated in March 2007). The analytical results for groundwater sampling events at Morrill in September 2005, March 2006, September 2006, and March 2007 were documented previously (Argonne 2006a, 2007c,e). The results have demonstrated the presence of carbon tetrachloride contamination, at levels exceeding the KDHE Tier 2 Risk-Based Screening Level (5.0 {micro}g/L) for this compound, in a groundwater plume extending generally south-southeastward from the former CCC/USDA facility, toward Terrapin Creek at the south edge of the town. Little clear pattern of change in the concentrations observed at the individual monitoring points and little plume migration have been observed in previous monitoring events. Low levels ({le} 1.3 {micro}g/L) of carbon tetrachloride have persistently been detected at monitoring well MW8S, however, along an intermittent tributary to Terrapin Creek. This observation suggests a possible risk of contamination of the surface waters of the creek. In light of these findings, in 2006 the CCC/USDA recommended expansion of the approved monitoring program to include the collection and analysis of surface water samples along Terrapin Creek (Argonne 2007e). At the request of the KDHE (KDHE 2007a), locations for both surface water and shallow sediment sampling were discussed with the KDHE in January 2007. An addendum to the existing monitoring plan and a standard operating procedure (SOP AGEM-15) for sediment sampling were submitted to the KDHE on the basis of these discussions (Argonne 2007a,b). This report presents the results of groundwater, surface water, and sediment sampling performed at Morrill in October 2007, in accord with the monitoring plan (Argonne 2005b) and the addendum to that plan (Argonne 2007a). To supplement these studies, Argonne also sampled natural vegetation along Terrapin Creek in October 2006, April 2007, and July 2007 for analyses for VOCs. The results of the plant tissue analyses are included in this report. The October 2007 groundwater sampling at Morrill represents the fifth and final monitoring event performed under the recommended two-year monitoring program approved by the KDHE.« less

Shuttle/spacelab contamination environment and effects handbook

NASA Technical Reports Server (NTRS)

Bareiss, L. E.; Payton, R. M.; Papazian, H. A.

1986-01-01

This handbook is intended to assist users of the Spacelab/Space Transportation System by providing contamination environments and effects information that may be of value in planning, designing, manufacturing, and operating a space flight experiment. A summary of available molecular and particulate contamination data on the Space Transportation System and its facilities is presented. Contamination models, contamination effects, and protection methods information are also presented. In addition to contamination, the effects of the space environments at STS altitudes on spacecraft materials are included. Extensive references, bibliographies, and contacts are provided.

Ecology and distribution of a new biomarker linked to 1,2-dichloropropane dechlorination in subsurface environments

NASA Astrophysics Data System (ADS)

Padilla-Crespo, E.; Loeffler, F. E.

2011-12-01

Reductive dechlorination plays a major role in the transformation and detoxification of chlorinated solvents, including chlorinated ethenes. Molecular biological tools are being applied at contaminated sites in order to assess the process-specific biomarkers that impact site performance, and to monitor the progress of bioremediation approaches. The few current biomarker genes in use provide an incomplete picture of the reductively dechlorinating bacterial community; this is a limitation for implementing enhanced bioremediation and monitored natural attenuation as cleanup strategies at chlorinated solvent contaminated sites. Reductively dehalogenating organisms, particularly Dehalococcoides (Dhc) strains, possess multiple reductive dehalogenase (RDase) genes, which are promising targets to specifically monitor dehalogenation processes of interest. Dehalococcoides populations in two highly enriched cultures (RC and KS) have been implicated in the reductive dechlorination of dechlorination of 1,2-dichloropropane (1,2-D), a widespread halogenated organic pollutant, to the non-toxic propene. Using a combined approach of transcription, expression and molecular analysis a new biomarker linked to 1,2-dichloropropane has been identified in Dhc strains RC and KS providing for the first time, convincing evidence of a specific RDase implicated in 1,2-D dechlorination to propene. Further analyses imply that new biomarker is in a "mobile DNA segment", a genomic island (GI) of horizontal gene transfer origin. A valid quantitative PCR approach was designed to detect and enumerate this gene in cultures and environmental samples; this will be a useful to bioremediation practitioners to more efficiently implement reductive dechlorination as a remediation tool. The new biomarker has been identified in fresh water sediment samples from different geographical locations in Europe, North and South America. Further research aims to shed light on RDase gene dissemination and the adaptation of dehalospiring populations in subsurface environments.

Quantifying the contribution of airborne lead (Pb) to surface waters in northeastern Oklahoma

NASA Astrophysics Data System (ADS)

Li, J. J.; McDonald, J.; Curtis, H.

2017-12-01

The northeastern Oklahoma, home to a number of Native American Tribes, is part of the well-known Tri-State Mining District (TSMD). One hundred years of mining production in this area has left numerous, large chat piles on the surrounding environment, directly affecting the town of Picher and many other tribe communities. Byproducts of the mining, including lead (Pb)-contain dust have been transported to the atmosphere and seeped into groundwater, lakes, ponds and rivers. Due to this contamination, many children in the area have elevated levels of Pb in their bodies. Despite a substantial number of studies and efforts on the restoration of heavy metal contamination in this area (e.g. The Tar Creek Superfund Site, EPA), no studies have attempted to distinguish the contributions of different sources, particularly from the atmospheric deposition, of heavy metals to the aquatic environment. In this study, we analyzed the atmospheric deposition of Pb from 4 sites located close to the chat piles for the period of 2010 to 2016. Our preliminary analysis showed that atmospheric Pb has a strong seasonal pattern with two peak times in early spring and late fall, which largely correspond with the dry periods in the this area. Atmospheric concentrations of Pb monitored at these sites frequently exceeded 0.15 μg/m3, the National Ambient Air Quality Standards (NAAQS) standard for ambient air Pb, and was generally 10 times higher than atmospheric Pb monitored in Tulsa, OK, a major metropolitan area 150 km southwest of the monitoring sites. With the known Pb flux to the sediments of the water bodies, we estimated that the contribution of Pb from the atmospheric deposition to the surface waters is up to 25%, depending on the distance of the water bodies to concentrated distribution of the chat piles.

Integrated site investigation and groundwater monitoring in an urban environment

NASA Astrophysics Data System (ADS)

Weatherl, R. K.

2017-12-01

Understanding groundwater dynamics around cities and other areas of human influence is of crucial importance for water resource management and protection, especially in a time of environmental and societal change. The human environment presents a unique challenge in terms of hydrological characterization, as the water cycle is generally artificialized and emissions of treated waste and chemical products into the surface- and groundwater system tend to disrupt the natural aqueous signature in significant ways. This project presents an integrated approach for robust characterization and monitoring of an urban aquifer which is actively exploited for municipal water supply. The study is carried out in the town of Fehraltorf, in the canton of Zürich, Switzerland. This particular town encompasses industrial and agricultural zones in addition to its standard urban setting. A minimal amount of data exist at this site, and the data that do exist are spatially and temporally sparse. Making use of traditional hydrogeological methods alongside evolving and emerging technologies, we aim to identify sources of contamination and to define groundwater flow and solute transport through space and time. Chemical and physical indicator parameters are identified for tracing contaminations including micropollutants and plant nutrients. Wireless sensors are installed for continuous on-line monitoring of essential parameters (electrical conductivity, temperature, water level). A wireless sensor network has previously been installed in the sewer system of the study site, facilitating investigation into interactions between sewer water and groundwater. Our approach illustrates the relations between land use, climate, rainfall dynamics, and the groundwater signature through time. At its conclusion, insights gained from this study will be used by municipal authorities to refine protective zones around pumping wells and to direct resources towards updating practices and replacing infrastructure where necessary.

Assessment of remote sensing technologies to discover and characterize waste sites

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1992-03-11

This report presents details about waste management practices that are being developed using remote sensing techniques to characterize DOE waste sites. Once the sites and problems have been located and characterized and an achievable restoration and remediation program have been established, efforts to reclaim the environment will begin. Special problems to be considered are: concentrated waste forms in tanks and pits; soil and ground water contamination; ground safety hazards for workers; and requirement for long-term monitoring.

[Environmental Hazards Assessment Program annual report, June 1992--June 1993]. Use of diatom distributions to monitor environmental health

DOE Office of Scientific and Technical Information (OSTI.GOV)

Levine, R.H.

1993-12-01

A variety of approaches has been used in the past to assess the environmental impact of anthropogenic contaminants. One reliable index for aquatic environments is the analysis of diatom species distribution; the focus in this case being on the Savannah River. The completed objectives of this study were: (A) the development and use of procedures for measuring diatom distribution in the water column and (B) the development and evaluation of sediment sampling methods for retrospective analysis.

Remediation and its effect represented on long term monitoring data at a chlorinated ethenes contaminated site, Wonju, Korea

NASA Astrophysics Data System (ADS)

Lee, Seong-Sun; Lee, Seung Hyun; Lee, Kang-Kun

2016-04-01

A research for the contamination of chlorinated ethenes such as trichloroethylene (TCE) at an industrial complex, Wonju, Korea, was carried out based on 17 rounds of groundwater quality data collection from 2009 to 2015. Remediation technologies such as soil vapor extraction, soil flushing, biostimulation, and pump-and-treat have been applied to eliminate the contaminant sources of trichloroethylene (TCE) and to prevent the migration of TCE plume from remediation target zones to groundwater discharge area like a stream. The remediation efficiency according to the remedial actions was evaluated by tracing a time-series of plume evaluation and temporal mass discharge at three transects (Source, Transect-1, Transect-2) which was assigned along the groundwater flow path. Also, based on long term monitoring data, dissolved TCE concentration and mass of residual TCE in the initial stage of disposal were estimated to evaluate the efficiency of in situ remediation. The results of temporal and spatial monitoring before remedial actions showed that a TCE plume originating from main and local source zones continues to be discharged to a stream. However, from the end of intensive remedial actions from 2012 to 2013, the aqueous concentrations of TCE plume present at and around the main source areas decreased significantly. Especially, during the intensive remediation period, the early average mass discharge (26.58 g/day) at source transect was decreased to average 4.99 g/day. Estimated initial dissolved concentration and residual mass of TCE in the initial stage of disposal decreased rapidly after an intensive remedial action in 2013 and it is expected to be continuously decreased from the end of remedial actions to 2020. This study demonstrates that long term monitoring data are useful in assessing the effectiveness of remedial actions at chlorinated ethenes contaminated site. Acknowledgements This project is supported by the Korea Ministry of Environment under "The GAIA Project (173-092-009)"and "R&D Project on Environmental Management of Geologic CO2 storage" from the KEITI (Project number:2014001810003).

Investigating the Influence of Remedial Capping on the Hydrological, Geochemical, and Microbial Processes that Control Subsurface Contaminant Migration at WAG 5 on the Oak Ridge Reservation: Implications toward Long-Term Stewardship

NASA Astrophysics Data System (ADS)

Jardine, P. M.; Mehlhorn, T. L.

2006-05-01

The following research investigated the effectiveness of an aggressive, large scale remedial action that is occurring to subsurface waste trenches containing radioactive and organic waste at the Oak Ridge National Laboratory. The site is being remediated as one of the top cleanup prioritization for the Oak Ridge Accelerated Remediation endeavor. Site landlords, Bechtel Jacobs Co., LLC (BJC) are installing a minimal RCRA cap with the primary objective of controlling the infiltration of storm water into the hundreds of unconfined waste trenches containing radioactive and organic waste. The site now offers a unique scientific opportunity to track the kinetic evolution of post-cap processes influencing contaminant migration and immobilization, because we have many years of pre-cap coupled processes information and knowledge. Since the cap is certain to disrupt the near steady-state contaminant discharge profiles that have existed for many years from the site, we have been quantifying the influence of post-cap hydrological, geochemical, and microbial processes on contaminant discharge as a function of scale and time in an effort to assess local-scale cap influences versus regional scale groundwater flow influences on contaminant discharge. We have been allowed to maintain numerous groundwater monitoring wells at a field site and these have a rich historical data set with regard to hydrology, geochemistry, microbiology, and contaminant flux. Our objectives are to investigate cap induced changes in (1) groundwater and surface hydrology and contaminant flux, (2) geochemistry and contaminant speciation, and (3) microbial community structure and organic contaminant degradation and inorganic contaminant immobilization. Our approach monitors coupled processes during base-flow and during storm events in both the groundwater and surface water discharge from the site and the surrounding watershed. Pre- and post-cap data will than be modeled with a multiprocess, multicomponent, transport model which is linked to pre- and post-cap surface water hydrograph analysis from the site and the surrounding watershed. Our goal is to provide an improved fundamental understanding of the long-term fate and transport of contaminants and an improved ability to predict system response to remedial actions. The experimental and numerical results from this investigation will provide knowledge and information in previously unexplored areas of cap performance with regard to coupled hydrology, geochemistry, microbiology, and contaminant flux in humid regimes. The products will support DOE's mission of long-term stewardship of contaminated environments and be transferable to other site where similar remediation exists or is planned.

Vegetated Treatment Systems for Removing Contaminants Associated with Surface Water Toxicity in Agriculture and Urban Runoff.

PubMed

Anderson, Brian S; Phillips, Bryn M; Voorhees, Jennifer P; Cahn, Michael

2017-05-15

Urban stormwater and agriculture irrigation runoff contain a complex mixture of contaminants that are often toxic to adjacent receiving waters. Runoff may be treated with simple systems designed to promote sorption of contaminants to vegetation and soils and promote infiltration. Two example systems are described: a bioswale treatment system for urban stormwater treatment, and a vegetated drainage ditch for treating agriculture irrigation runoff. Both have similar attributes that reduce contaminant loading in runoff: vegetation that results in sorption of the contaminants to the soil and plant surfaces, and water infiltration. These systems may also include the integration of granulated activated carbon as a polishing step to remove residual contaminants. Implementation of these systems in agriculture and urban watersheds requires system monitoring to verify treatment efficacy. This includes chemical monitoring for specific contaminants responsible for toxicity. The current paper emphasizes monitoring of current use pesticides since these are responsible for surface water toxicity to aquatic invertebrates.

Payload/orbiter contamination control requirement study: Spacelab configuration contamination study

NASA Technical Reports Server (NTRS)

Bareiss, L. E.; Hetrick, M. A.; Ress, E. B.; Strange, D. A.

1976-01-01

The assessment of the Spacelab carrier induced contaminant environment was continued, and the ability of Spacelab to meet established contamination control criteria for the space transportation system program was determined. The primary areas considered included: (1) updating, refining, and improving the Spacelab contamination computer model and contamination analysis methodology, (2) establishing the resulting adjusted induced environment predictions for comparison with the applicable criteria, (3) determining the Spacelab design and operational requirements necessary to meet the criteria, (4) conducting mission feasibility analyses of the combined Spacelab/Orbiter contaminant environment for specific proposed mission and payload mixes, and (5) establishing a preliminary Spacelab mission support plan as well as model interface requirements; A summary of those activities conducted to date with respect to the modelling, analysis, and predictions of the induced environment, including any modifications in approach or methodology utilized in the contamination assessment of the Spacelab carrier, was presented.

Prevalent Glucocorticoid and Androgen Activity in US Water Sources

PubMed Central

Stavreva, Diana A.; George, Anuja A.; Klausmeyer, Paul; Varticovski, Lyuba; Sack, Daniel; Voss, Ty C.; Schiltz, R. Louis; Blazer, Vicki S.; Iwanowicz, Luke R.; Hager, Gordon L.

2012-01-01

Contamination of the environment with endocrine disrupting chemicals (EDCs) is a major health concern. The presence of estrogenic compounds in water and their deleterious effect are well documented. However, detection and monitoring of other classes of EDCs is limited. Here we utilize a high-throughput live cell assay based on sub-cellular relocalization of GFP-tagged glucocorticoid and androgen receptors (GFP-GR and GFP-AR), in combination with gene transcription analysis, to screen for glucocorticoid and androgen activity in water samples. We report previously unrecognized glucocorticoid activity in 27%, and androgen activity in 35% of tested water sources from 14 states in the US. Steroids of both classes impact body development, metabolism, and interfere with reproductive, endocrine, and immune systems. This prevalent contamination could negatively affect wildlife and human populations. PMID:23226835

Prevalent glucocorticoid and androgen activity in US water sources.

PubMed

Stavreva, Diana A; George, Anuja A; Klausmeyer, Paul; Varticovski, Lyuba; Sack, Daniel; Voss, Ty C; Schiltz, R Louis; Blazer, Vicki S; Iwanowicz, Luke R; Hager, Gordon L

2012-01-01

Contamination of the environment with endocrine disrupting chemicals (EDCs) is a major health concern. The presence of estrogenic compounds in water and their deleterious effect are well documented. However, detection and monitoring of other classes of EDCs is limited. Here we utilize a high-throughput live cell assay based on sub-cellular relocalization of GFP-tagged glucocorticoid and androgen receptors (GFP-GR and GFP-AR), in combination with gene transcription analysis, to screen for glucocorticoid and androgen activity in water samples. We report previously unrecognized glucocorticoid activity in 27%, and androgen activity in 35% of tested water sources from 14 states in the US. Steroids of both classes impact body development, metabolism, and interfere with reproductive, endocrine, and immune systems. This prevalent contamination could negatively affect wildlife and human populations.

Seabed gamma-ray spectrometry: applications at IAEA-MEL.

PubMed

Osvath, I; Povinec, P P

2001-01-01

The technique of underwater gamma-ray spectrometry has been developed to complement or replace the traditional sampling-sample analysis approach for applications with space-time constraints, e.g. large areas of investigation, emergency response or long-term monitoring. IAEA-MEL has used both high-efficiency NaI(Tl) and high-resolution HPGe spectrometry to investigate contamination with anthropogenic radionuclides in a variety of marine environments. Surveys at the South Pacific nuclear test sites of Mururoa and Fangataufa have been used to guide sampling in areas of high contamination around ground zero points. In the Irish Sea offshore from the Sellafield nuclear reprocessing plant, a gamma-ray survey of seabed sediment was carried out to obtain estimates of the distribution and subsequently, for the inventory of 137Cs in the investigated area.

Prevalent flucocorticoid and androgen activity in US water sources

USGS Publications Warehouse

Stavreva, Diana A.; George, Anuja A.; Klausmeyer, Paul; Varticovski, Lyuba; Sack, Daniel; Voss, Ty C.; Schiltz, R. Louis; Blazer, Vicki; Iwanowiczl, Luke R.; Hager, Gordon L.

2012-01-01

Contamination of the environment with endocrine disrupting chemicals (EDCs) is a major health concern. The presence of estrogenic compounds in water and their deleterious effect are well documented. However, detection and monitoring of other classes of EDCs is limited. Here we utilize a high-throughput live cell assay based on sub-cellular relocalization of GFP-tagged glucocorticoid and androgen receptors (GFP-GR and GFP-AR), in combination with gene transcription analysis, to screen for glucocorticoid and androgen activity in water samples. We report previously unrecognized glucocorticoid activity in 27%, and androgen activity in 35% of tested water sources from 14 states in the US. Steroids of both classes impact body development, metabolism, and interfere with reproductive, endocrine, and immune systems. This prevalent contamination could negatively affect wildlife and human populations.

Petroleum hydrocarbon pollution of urban topsoil in Ibadan city, Nigeria

DOE Office of Scientific and Technical Information (OSTI.GOV)

Onianwa, P.C.

The distribution of total petroleum hydrocarbon in topsoils from various parts of Ibadan city, Nigeria, was studied. Samples were selected from around the following zones: (a) railway tracks, (b) petrol stations, (c) refuse dumps, (d) residential areas, (e) high traffic density areas, (f) mechanical workshops, and (g) control zones. Contamination of the topsoil with hydrocarbons was significant only around petrol stations and mechanical workshops where the factors of accumulation were 10.1 and 4.72, respectively. The general trend in hydrocarbon levels was petrol station > mechanical workshop > refuse dumps > high traffic areas {ge} rail tracks > control residential areas.more » The results highlight the need to monitor urban environments that are remote from petroleum exploration activities for petroleum hydrocarbon contamination. 19 refs., 3 tabs.« less

Evaluation of a hygiene monitor for detection of contamination in dental surgeries.

PubMed

Douglas, C W; Rothwell, P S

1991-05-11

Routines for disinfecting working surfaces in dental surgeries are difficult to monitor without time-consuming and labour-intensive microbiological techniques, yet effective monitoring is a vital part of cross-infection control. Easy to use, on-site methods would be valuable in this context. This study evaluates a portable monitor, the Biotrace Hygiene Monitor, which uses bioluminescence to measure adenosine triphosphate (ATP) on surfaces. Under laboratory conditions, the ability of the monitor to detect whole saliva and Streptococcus sanguis was determined and, in the general practice environment, the level of ATP on surfaces in five dental surgeries was assessed. The minimum amount of saliva detectable was 0.5 microliters and in surgeries, the monitor readily identified numerous surfaces with fairly high levels of ATP. Routine cleaning methods sometimes left ATP on surfaces at levels which represented a cross-infection risk, if it is assumed that the ATP derived from patients' saliva. Modification of cleaning methods resulted in a reduction of ATP levels to within that which could be considered reasonably practicably safe. It is concluded that the Biotrace Hygiene Monitor offers a simple and valuable means of monitoring dental practice cleaning routines.

Evaluating leaf and canopy reflectance of stressed rice plants to monitor arsenic contamination

USDA-ARS?s Scientific Manuscript database

Arsenic contamination is a serious problem in rice cultivated soils of many developing countries. Hence, it is critical to monitor and control arsenic uptake in rice plants to avoid adverse effects on human health. This study evaluated the feasibility of using reflectance spectroscopy to monitor ars...

Caged Fish Studies to Detect and Monitor Contaminants of Emerging Concern in the Great Lakes

EPA Science Inventory

Effects-based monitoring studies were conducted in the St. Louis Harbor, Lake Superior, in support of the Great Lakes Restoration Initiative (GLRI). The overall goal of the research was to develop and validate methods using caged fish exposures to detect and monitor contaminants...

40 CFR 141.35 - Reporting for unregulated contaminant monitoring results.

Code of Federal Regulations, 2010 CFR

2010-07-01

... addition, you must notify the public of the availability of unregulated contaminant monitoring data as... single monitoring event at the same sampling location), EPA will use the highest of the reported values... value up to 30 characters assigned by the laboratory to uniquely identify containers, or groups of...

Princeton Plasma Physics Laboratory Annual Site Environmental Report for Calendar Year 1996

DOE Office of Scientific and Technical Information (OSTI.GOV)

J.D. Levine; V.L. Finley

1998-03-01

The results of the 1996 environmental surveillance and monitoring program for the Princeton Plasma Physics Laboratory (PPPL) are presented and discussed. The purpose of this report is to provide the US Department of Energy and the public with information on the level of radioactive and nonradioactive pollutants, if any, that are added to the environment as a result of PPPL's operations. During Calendar Year 1996, PPPL's Tokamak Fusion Test Reactor (TFTR) continued to conduct fusion experiments. Having set a world record on November 2, 1994, by achieving approximately 10.7 million watts of controlled fusion power during the deuterium-tritium (D-T) plasmamore » experiments, researchers turned their attention to studying plasma science experiments, which included ''enhanced reverse shear techniques.'' Since November 1993, more than 700 tritium-fueled experiments were conducted, which generated more than 4 x 10(superscript 20) neutrons and 1.4 gigajoules of fusion energy. In 1996, the overall performance of Princeton Plasma Physics Laboratory was rated ''excellent'' by the US Department of Energy in the Laboratory Appraisal report issued in early 1997. The report cited the Laboratory's consistently excellent scientific and technological achievements and its successful management practices, which included high marks for environmental management, employee health and safety, human resources administration, science education, and communications. Groundwater investigations continued under a voluntary agreement with the New Jersey Department of Environmental Protection. PPPL monitored for the presence of nonradiological contaminants, mainly volatile organic compounds (components of degreasing solvents) and petroleum hydrocarbons (past leaks of releases of diesel fuel from underground storage tanks). Also, PPPL's radiological monitoring program characterized the ambient, background levels of tritium in the environment and from the TFTR stack; the data are presented in this report. During 1996, PPPL completed the removal of contaminated soil from two locations that were identified through the monitoring program: petroleum hydrocarbons along a drainage swale and chromium adjacent to the cooling tower.« less

Evaluation of an Environmental Monitoring Program for the Microbial Safety of Air and Surfaces in a Dairy Plant Environment.

PubMed

Zacharski, Krzysztof A; Southern, Mark; Ryan, Alan; Adley, Catherine C

2018-07-01

Microbiological hazards can occur when foodstuffs come into contact with contaminated surfaces or infectious agents dispersed by air currents in the manufacturing environment. An environmental monitoring program (EMP) is a critical aspect of sustainable and safe food manufacturing used to evaluate the effectiveness of the microbial controls in place. An effective EMP should be based on risk analysis, taking into account previous sampling history to determine the selection of the sampling points, the scope of the test, and the frequency of analysis. This study involved evaluation of the environmental monitoring regime and microbiological status of a medium-sized dairy plant manufacturing food ingredients, e.g., proteins, milk powders, and dairy fats. The data specific to microbial tests ( n = 3,468), recorded across 124 fixed sampling locations over a 2-year period (2014 to 2015) from air ( n = 1,787) and surfaces ( n = 1,681) were analyzed. The aim of this study was to highlight the strengths and weaknesses of the EMP in a select dairy processing plant. The results of this study outline the selection of sampling locations, the scope of the test, and the frequency of analysis. An analysis of variance revealed subsections of the manufacturing areas with high risk factors, especially the packaging subsection specified for bulk packaging, the atomizer, and the fluidized bed. The temporal and spatial analysis showed the potential to reduce or relocate the monitoring effort, most notably related to total coliforms and Staphylococcus aureus, across the dairy plant due to homogeneity across the sampling subsections with little or no deviations. The results suggest a need to reevaluate the current EMP and the corrective action plan, especially with regard to detection of pathogens. Recommendations for optimization of the EMP are presented to assist the dairy industry with reviewing and revising the control measures and hazard assessment with regard to existing contamination issues.

Prioritizing Contaminants for Monitoring and Management

EPA Pesticide Factsheets

EPA researcher presents work to develop methods and tools that integrate chemical monitoring with pathway-based bioactivity measurements, which will help provide screening-level assessments useful to identify and prioritize emerging contaminants.

Mineral transformation controls speciation and pore-fluid transmission of contaminants in waste-weathered Hanford sediments

NASA Astrophysics Data System (ADS)

Perdrial, Nicolas; Thompson, Aaron; O'Day, Peggy A.; Steefel, Carl I.; Chorover, Jon

2014-09-01

Portions of the Hanford Site (WA, USA) vadose zone were subjected to weathering by caustic solutions during documented releases of high level radioactive waste (containing Sr, Cs and I) from leaking underground storage tanks. Previous studies have shown that waste-sediment interactions can promote variable incorporation of contaminants into neo-formed mineral products (including feldspathoids and zeolites), but processes regulating the subsequent contaminant release from these phases into infiltrating background pore waters remain poorly known. In this paper, reactive transport experiments were conducted with Hanford sediments previously weathered for one year in simulated hyper-alkaline waste solutions containing high or low 88Sr, 127I, and 133Cs concentrations, with or without CO2(aq). These waste-weathered sediments were leached in flow-through column experiments with simulated background pore water (characteristic of meteoric recharge) to measure contaminant release from solids formed during waste-sediment interaction. Contaminant sorption-desorption kinetics and mineral transformation reactions were both monitored using continuous-flow and wet-dry cycling regimes for ca. 300 pore volumes. Less than 20% of contaminant 133Cs and 88Sr mass and less than 40% 127I mass were released over the course of the experiment. To elucidate molecular processes limiting contaminant release, reacted sediments were studied with micro- (TEM and XRD) and molecular- (Sr K-edge EXAFS) scale methods. Contaminant dynamics in column experiments were principally controlled by rapid dissolution of labile solids and competitive exchange reactions. In initially feldspathoidic systems, time-dependent changes in the local zeolitic bonding environment observed with X-ray diffraction and EXAFS are responsible for limiting contaminant release. Linear combination fits and shell-by-shell analysis of Sr K-edge EXAFS data revealed modification in Sr-Si/Al distances within the zeolite cage. Wet-dry cycling did not affect significantly molecular-scale transformations relative to continuous-flow controls. Results indicate that contaminants bound to the solid phase in distinct micro- and molecular-scale coordinative environments can generate similar macro-scale release behaviors, highlighting the need for multi-scale interrogations to constrain mechanisms of reactive transport. Data also indicate that weathering-induced change in ion exchange selectivity coefficients should be incorporated in simulations of contaminant release from caustic high-level radioactive waste impacted sediments.

The occurrence of pesticides and persistent organic pollutants in Italian organic honeys from different productive areas in relation to potential environmental pollution.

PubMed

Chiesa, L M; Labella, G F; Giorgi, A; Panseri, S; Pavlovic, R; Bonacci, S; Arioli, F

2016-07-01

Bee products, such as honey, are widely consumed as food and consumer interest is currently oriented towards organic foods. Regarding this, the European Commission establishes that the qualification of organic honey and other beekeeping products as being from organic production is closely bound with the characteristics of hive treatments as well as the quality of the environment. Agricultural contamination with pesticides is a challenging problem that needs to be fully addressed, in particular in the field of organic production systems. In this study, the occurrence of different classes of contaminants selected as representative of potential contamination sources were investigated in 59 organic honeys: organochlorines, OCs; organophosphates, OPs; polychlorobiphenyls, PCBs and polybromodiphenylethers, PBDEs. A method based on Accelerated Solvent Extraction with "in line" clean-up and GC-MS/MS detection was developed to detect contaminants. Residues of many pesticides were found in most of the samples investigated. The majority of honey samples contained at least one of the pesticides, even if their concentrations were found to be lower than its MRL. Diazinon, Mevinphos, Coumaphos, Chlorpyrifos and Quinoxyfen were the residues frequently detected in samples coming from the apple and citrus orchard areas. Furthermore, the results of the present study show that the presence of the residue in organic honey may also be affected by the geographical area (e.g. the presence of an agricultural system) confirming honey bee and beehive matrices as appropriate sentinels for monitoring contamination in the environment. The optimised method proved to be simple and rapid, requiring small sample sizes and minimising solvent consumption, due to the ASE having an "in line" clean-up step. Copyright © 2016 Elsevier Ltd. All rights reserved.

Mind the Gap: Persistent and Mobile Organic Compounds-Water Contaminants That Slip Through.

PubMed

Reemtsma, Thorsten; Berger, Urs; Arp, Hans Peter H; Gallard, Hervé; Knepper, Thomas P; Neumann, Michael; Quintana, José Benito; Voogt, Pim de

2016-10-04

The discharge of persistent and mobile organic chemicals (PMOCs) into the aquatic environment is a threat to the quality of our water resources. PMOCs are highly polar (mobile in water) and can pass through wastewater treatment plants, subsurface environments and potentially also drinking water treatment processes. While a few such compounds are known, we infer that their number is actually much larger. This Feature highlights the issue of PMOCs from an environmental perspective and assesses the gaps that appear to exist in terms of analysis, monitoring, water treatment and regulation. On this basis we elaborate strategies on how to narrow these gaps with the intention to better protect our water resources.

UTSI/CFFF MHD PROGRAM COMPLETION AND RELATED ACTIVITY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Joel W. Muehlhauser

2003-08-01

The Discharge Monitoring Reports (DMRs) for April, May and June, 2003, were prepared and submitted to the Tennessee Department of Environment and Conservation (TDEC). TVG Environmental, Inc. of Nashville, TN conducted the second semi-annual sampling event for the groundwater wells on the UTSI campus in mid-May, 2003. A report detailing the sampling and subsequent water analysis was forwarded to The Tennessee Department of Environment and Conservation in early June. Copies of that report were provided to DOE by Dr. Joel Muehlhauser. Contamination levels above state limits were found in all five wells sampled for at least one compound. TDEC willmore » be contacted next quarter to determine what subsequent actions are necessary.« less

Detection of microbial contamination during human islet isolation.

PubMed

Kin, Tatsuya; Rosichuk, Shawn; Shapiro, A M James; Lakey, Jonathan R T

2007-01-01

Current good manufacturing practice (cGMP) islet processing facilities provide an ultraclean environment for the safe production of clinical grade islets for transplantation into immunosuppressed diabetic recipients. The objective of this study was to monitor the rate of microbial contamination in islet products after implementation of good manufacturing practice conditions. Fluid samples for microbial contamination were collected at the following steps: from the pancreas transport solution upon arrival of the organ (n=157), after surface decontamination of the pancreas with antiseptic agents (n=89), from islet supernatant at the end of the isolation (n=104), and from islet supernatant as a final transplantable product after culture (n=53). Bacterial, fungal, and mycoplasma cultures were conducted for 2, 2, and 3 weeks, respectively. Microbial contamination was detected in 31% of transport solution. The contamination was not associated with the presence of the duodenum during the preservation, cold ischemia time, or procurement team (local vs. distant). Surface decontamination of the pancreas resulted in clearance of 92% of the microbial contamination. Six preparations at the end of the isolation revealed microbial growth. All were de novo contamination during the processing. Fifty-three preparations that met our release criteria in terms of product sterility were transplanted into type 1 diabetic patients. In two instances, positive culture of the islet preparation was reported after transplantation had occurred. No patient showed any clinical findings suggestive of infection or any radiological abnormalities suggestive of abscess; a single dose of antibiotic coverage was given routinely to recipients prior to islet infusion. Although transport solution carries a high risk of microbial contamination, most contaminants become undetectable during islet processing. Microbial contamination in final products is rare, but de novo contamination still occurs during processing even under cGMP conditions.

Detection of Microbial Contamination during Human Islet Isolation.

PubMed

Kin, Tatsuya; Rosichuk, Shawn; Shapiro, A M James; Lakey, Jonathan R T

2007-01-01

Current good manufacturing practice (cGMP) islet processing facilities provide an ultraclean environment for the safe production of clinical grade islets for transplantation into immunosuppressed diabetic recipients. The objective of this study was to monitor the rate of microbial contamination in islet products after implementation of good manufacturing practice conditions. Fluid samples for microbial contamination were collected at the following steps: from the pancreas transport solution upon arrival of the organ (n = 157), after surface decontamination of the pancreas with antiseptic agents (n = 89), from islet supernatant at the end of the isolation (n = 104), and from islet supernatant as a final transplantable product after culture (n = 53). Bacterial, fungal, and mycoplasma cultures were conducted for 2, 2, and 3 weeks, respectively. Microbial contamination was detected in 31% of transport solution. The contamination was not associated with the presence of the duodenum during the preservation, cold ischemia time, or procurement team (local vs. distant). Surface decontamination of the pancreas resulted in clearance of 92% of the microbial contamination. Six preparations at the end of the isolation revealed microbial growth. All were de novo contamination during the processing. Fifty-three preparations that met our release criteria in terms of product sterility were transplanted into type 1 diabetic patients. In two instances, positive culture of the islet preparation was reported after transplantation had occurred. No patient showed any clinical findings suggestive of infection or any radiological abnormalities suggestive of abscess; a single dose of antibiotic coverage was given routinely to recipients prior to islet infusion. Although transport solution carries a high risk of microbial contamination, most contaminants become undetectable during islet processing. Microbial contamination in final products is rare, but de novo contamination still occurs during processing even under cGMP conditions.

The New Bedford Harbor Superfund site long-term monitoring program (1993-2009).

PubMed

Nelson, William G; Bergen, Barbara J

2012-12-01

New Bedford Harbor (NBH), located in southeastern Massachusetts, was designated as a marine Superfund site in 1983 due to sediment contamination by polychlorinated biphenyls (PCBs). Based on risks to human health and the environment, the first two phases of the site cleanup involved dredging PCB-contaminated sediments from the harbor. Therefore, a long-term monitoring program (LTM) was developed to measure spatial and temporal chemical and biological changes in sediment, water, and biota to assess the effects and effectiveness of the remedial activities. A systematic, probabilistic sampling design was used to select sediment sampling stations. This unbiased design allowed the three segments of the harbor to be compared spatially and temporally to quantify changes resulting from dredging the contaminated sediments. Sediment was collected at each station, and chemical (e.g., PCBs and metals), physical (e.g., grain size), and biological (e.g., benthic community) measurements were conducted on all samples. This paper describes the overall NBH-LTM approach and the results from the five rounds of sample collections. There is a decreasing spatial gradient in sediment PCB concentrations from the northern boundary (upper harbor) to the southern boundary (outer harbor) of the site. Along this same transect, there is an increase in biological condition (e.g., benthic community diversity). Temporally, the contaminant and biological gradients have been maintained since the 1993 baseline collection; however, since the onset of full-scale remediation, PCB concentrations have decreased throughout the site, and one of the benthic community indices has shown significant improvement in the lower and outer harbor areas.

Aerospace toxicology overview: aerial application and cabin air quality.

PubMed

Chaturvedi, Arvind K

2011-01-01

Aerospace toxicology is a rather recent development and is closely related to aerospace medicine. Aerospace toxicology can be defined as a field of study designed to address the adverse effects of medications, chemicals, and contaminants on humans who fly within or outside the atmosphere in aviation or on space flights. The environment extending above and beyond the surface of the Earth is referred to as aerospace. The term aviation is frequently used interchangeably with aerospace. The focus of the literature review performed to prepare this paper was on aerospace toxicology-related subject matters, aerial application and aircraft cabin air quality. Among the important topics addressed are the following: · Aerial applications of agricultural chemicals, pesticidal toxicity, and exposures to aerially applied mixtures of chemicals and their associated formulating solvents/surfactants The safety of aerially encountered chemicals and the bioanalytical methods used to monitor exposures to some of them · The presence of fumes and smoke, as well as other contaminants that may generally be present in aircraft/space vehicle cabin air · And importantly, the toxic effects of aerially encountered contaminants, with emphasis on the degradation products of oils, fluids, and lubricants used in aircraft, and finally · Analytical methods used for monitoring human exposure to CO and HCN are addressed in the review, as are the signs and symptoms associated with exposures to these combustion gases. Although many agricultural chemical monitoring studies have been published, few have dealt with the occurrence of such chemicals in aircraft cabin air. However, agricultural chemicals do appear in cabin air; indeed, attempts have been made to establish maximum allowable concentrations for several of the more potentially toxic ones that are found in aircraft cabin air. In this article, I emphasize the need for precautionary measures to be taken to minimize exposures to aerially encountered chemicals, or aircraft cabin air contaminants and point out the need for future research to better address toxicological evaluation of aircraft-engine oil additives.

Microbial Monitoring of the International Space Station

NASA Technical Reports Server (NTRS)

Pierson, Duane L.; Botkin, Douglas J.; Bruce, Rebekah J.; Castro, Victoria A.; Smith, Melanie J.; Oubre, Cherie M.; Ott, C. Mark

2013-01-01

Humans living and working in the harsh environment of space present many challenges for habitability engineers and microbiologists. Spacecraft must provide an internal environment in which physical (gas composition, pressure, temperature, and humidity), chemical, and biological environmental parameters are maintained at safe levels. Microorganisms are ubiquitous and will accompany all human-occupied spacecraft, but if biological contamination were to reach unacceptable levels, long-term human space flight would be impossible. Prevention of microbiological problems, therefore, must have a high priority. Historically, prevention of infectious disease in the crew has been the highest priority, but experience gained from the NASA-Mir program showed that microbial contamination of vehicle and life-support systems, such as biofouling of water and food, are of equal importance. The major sources of microbiological risk factors for astronauts include food, drinking water, air, surfaces, payloads, research animals, crew members, and personnel in close contact with the astronauts. In our efforts to eliminate or mitigate the negative effects of microorganisms in spacecraft, the National Aeronautics and Space Administration (NASA) implemented comprehensive microbial analyses of the major risk factors. This included the establishment of acceptability requirements for food, water, air, surfaces, and crew members. A robust monitoring program was then implemented to verify that the risks were within acceptable limits. Prevention of microbiological problems is preferred over mitigation of problems during flight, and preventive steps must begin very early in the design phase. Spacecraft development must include requirements to control free water from humidity, condensate, hygiene activities, and other releases. If water is available, microbes are likely to grow because sufficient nutrients are potentially available. Materials selected for the spacecraft must not promote or support microbial growth. Air filtration can dramatically reduce the number of airborne bacteria, fungi, and particulates in spacecraft breathing air. Waterborne bacteria can be reduced to acceptable levels by thermal inactivation of bacteria during water processing, along with a residual biocide, and filtration at the point of use can ensure safety. System design must include onboard capability to achieve recovery of the system from contamination. Robust housekeeping procedures that include periodic cleaning and disinfection will prevent high levels of microbial growth on surfaces. Food for consumption in space must be thoroughly tested for excessive microbial content and pathogens before launch. Thorough preflight examination of flight crews, consumables, payloads, and the environment can greatly reduce pathogens in spacecraft. Many of the lessons learned from the Space Shuttle and previous programs were applied in the early design phase of the International Space Station, resulting in the safest space habitat to date. This presentation describes the monitoring program for the International Space Station and will summarize results from preflight and on-orbit monitoring.

Application of 4D resistivity image profiling to detect DNAPLs plume.

NASA Astrophysics Data System (ADS)

Liu, H.; Yang, C.; Tsai, Y.

2008-12-01

In July 1993, the soil and groundwater of the factory of Taiwan , Miaoli was found to be contaminated by dichloroethane, chlorobenzene and other hazardous solvents. The contaminants were termed to be dense non-aqueous phase liquids (DNAPLs). The contaminated site was neglected for the following years until May 1998, the Environment Protection Agency of Miaoli ordered the company immediately take an action for treatment of the contaminated site. Excavating and exposing the contaminated soil was done at the previous waste DNAPL dumped area. In addition, more than 53 wells were drilled around the pool with a maximum depth of 12 m where a clayey layer was found. Continuous pumping the groundwater and monitoring the concentration of residual DNAPL contained in the well water samples have done in different stages of remediation. However, it is suspected that the DNAPL has existed for a long time, therefore the contaminants might dilute but remnants of a DNAPL plume that are toxic to humans still remain in the soil and migrate to deeper aquifers. A former contaminated site was investigated using the 2D, 3D and 4D resisitivity image technique, with aims of determining buried contaminant geometry. This paper emphasizes the use of resistivity image profiling (RIP) method to map the limit of this DNAPL waste disposal site where the records of operations are not variations. A significant change in resistivity values was detected between known polluted and non-polluted subsurface; a high resistivity value implies that the subsurface was contaminated by DNAPL plume. The results of the survey serve to provide insight into the sensitivity of RIP method for detecting DNAPL plumes within the shallow subsurface, and help to provide valuable information related to monitoring the possible migration path of DNAPL plume in the past. According to the formerly studies in this site, affiliation by excavates with pumps water remediation had very long time, Therefore this research was used iron nanoparticles with pumps water remediation ways. The survey lines use the same length and the same position of the different time observation. The survey lines monitors the iron nanoparticles and pollution flow direction with remediation effect. By used the iron nanoparticles and pumping water remediation ways, the DNAPL plumes had eminent changed. Iron nanoparticles granule is smaller than the micron iron, Therefore the reaction rate was quite quick at the iron nanoparticles and pumps, but the ferric oxide can cause the electronic resistivity to elevate produces after the response. Pumps water rectifies may remove the ferric oxide to cause the electronic resistivity to reduce. The iron nanoparticles and pollution response is extremely obviously of the Resistivity Image Profile.

Is the soil quality monitoring an effective tool in consumers' protection of agricultural crops from cadmium soil contamination?-a case of the Silesia region (Poland).

PubMed

Piekut, Agata; Baranowska, Renata; Marchwińska-Wyrwał, Ewa; Ćwieląg-Drabek, Małgorzata; Hajok, Ilona; Dziubanek, Grzegorz; Grochowska-Niedworok, Elżbieta

2017-12-16

The monitoring of soil quality should be a control tool used to reduce the adverse health effects arising from exposure to toxic chemicals in soil through cultivated crop absorption. The aim of the study was to evaluate the effectiveness of the monitoring and control system of soil quality in Poland, in terms of consumer safety, for agricultural plants cultivated in areas with known serious cadmium contamination, such as Silesia Province. To achieve the objective, the contents of cadmium in soils and vegetables in the Silesia administrative area were examined. The obtained results were compared with the results of soil contamination from the quality monitoring of arable soil in Poland. The studies show a significant exceedance of the permissible values of cadmium in soil samples and the vegetables cultivated on that soil. The threat to consumer health is a valid concern, although this threat was not indicated by the results of the national monitoring of soil quality. The results indicated an unequal distribution of risk to consumers resulting from contaminated soil. Moreover, the monitoring systems should be designed at the local or regional scale to guarantee the safety of consumers of edible plants cultivated in the areas contaminated with cadmium.

System Report for the Optical Properties Monitor (OPM) Experiment

NASA Technical Reports Server (NTRS)

Hummer, L.

2001-01-01

This systems report describes how the Optical Properties Monitor (OPM) experiment was developed. Pertinent design parameters are discussed, along with mission information and system requirements to successfully complete the mission. Environmental testing was performed on the OPM to certify it for spaceflight. This testing included vibration, thermal vacuum, electromagnetic interference and conductance, and toxicity tests. Instrument and monitor subsystem performances, including the reflectometer, vacuum ultraviolet, total integrated scatter, atomic oxygen monitor, irradiance monitor, and molecular contamination monitor during the mission are discussed. The OPM experiment was launched aboard the Space Shuttle on mission STS-81 in January 1997 and transferred to the Mir space station. An extravehicular activity (EVA) was performed in April 1997 to attach the OPM experiment to the outside of the Mir/Shuttle Docking Module for space environment exposure. The OPM conducted in situ measurements of a number of material samples. These data may be found in the OPM Science Report. OPM was retrieved during an EVA in January 1998 and was returned to Earth on board the Space Shuttle on mission STS-89.

Modeling, Monitoring and Fault Diagnosis of Spacecraft Air Contaminants

NASA Technical Reports Server (NTRS)

Ramirez, W. Fred; Skliar, Mikhail; Narayan, Anand; Morgenthaler, George W.; Smith, Gerald J.

1996-01-01

Progress and results in the development of an integrated air quality modeling, monitoring, fault detection, and isolation system are presented. The focus was on development of distributed models of the air contaminants transport, the study of air quality monitoring techniques based on the model of transport process and on-line contaminant concentration measurements, and sensor placement. Different approaches to the modeling of spacecraft air contamination are discussed, and a three-dimensional distributed parameter air contaminant dispersion model applicable to both laminar and turbulent transport is proposed. A two-dimensional approximation of a full scale transport model is also proposed based on the spatial averaging of the three dimensional model over the least important space coordinate. A computer implementation of the transport model is considered and a detailed development of two- and three-dimensional models illustrated by contaminant transport simulation results is presented. The use of a well established Kalman filtering approach is suggested as a method for generating on-line contaminant concentration estimates based on both real time measurements and the model of contaminant transport process. It is shown that high computational requirements of the traditional Kalman filter can render difficult its real-time implementation for high-dimensional transport model and a novel implicit Kalman filtering algorithm is proposed which is shown to lead to an order of magnitude faster computer implementation in the case of air quality monitoring.

Modeling, Monitoring and Fault Diagnosis of Spacecraft Air Contaminants

NASA Technical Reports Server (NTRS)

Ramirez, W. Fred; Skliar, Mikhail; Narayan, Anand; Morgenthaler, George W.; Smith, Gerald J.

1998-01-01

Control of air contaminants is a crucial factor in the safety considerations of crewed space flight. Indoor air quality needs to be closely monitored during long range missions such as a Mars mission, and also on large complex space structures such as the International Space Station. This work mainly pertains to the detection and simulation of air contaminants in the space station, though much of the work is easily extended to buildings, and issues of ventilation systems. Here we propose a method with which to track the presence of contaminants using an accurate physical model, and also develop a robust procedure that would raise alarms when certain tolerance levels are exceeded. A part of this research concerns the modeling of air flow inside a spacecraft, and the consequent dispersal pattern of contaminants. Our objective is to also monitor the contaminants on-line, so we develop a state estimation procedure that makes use of the measurements from a sensor system and determines an optimal estimate of the contamination in the system as a function of time and space. The real-time optimal estimates in turn are used to detect faults in the system and also offer diagnoses as to their sources. This work is concerned with the monitoring of air contaminants aboard future generation spacecraft and seeks to satisfy NASA's requirements as outlined in their Strategic Plan document (Technology Development Requirements, 1996).

Executive summary: Weldon Spring Site Environmental Report for calendar year 1992. Weldon Spring Site Remedial Action Project, Weldon Spring, Missouri

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

1993-06-01

This report has been prepared to provide information about the public safety and environmental protection programs conducted by the Weldon Spring Site Remedial Action Project. The Weldon Spring site is located in southern St. Charles County, Missouri, approximately 48 km (30 mi) west of St. Louis. The site consists of two main areas, the Weldon Spring Chemical Plant and raffinate pits and the Weldon Spring Quarry. The objectives of the Site Environmental Report are to present a summary of data from the environmental monitoring program, to characterize trends and environmental conditions at the site, and to confirm compliance with environmentalmore » and health protection standards and requirements. The report also presents the status of remedial activities and the results of monitoring these activities to assess their impacts on the public and environment. The scope of the environmental monitoring program at the Weldon Spring site has changed since it was initiated. Previously, the program focused on investigations of the extent and level of contaminants in the groundwater, surface waters, buildings, and air at the site. In 1992, the level of remedial activities required monitoring for potential impacts of those activities, particularly on surface water runoff and airborne effluents. This report includes monitoring data from routine radiological and nonradiological sampling activities. These data include estimates of dose to the public from the Weldon Spring site; estimates of effluent releases; and trends in groundwater contaminant levels. Also, applicable compliance requirements, quality assurance programs, and special studies conducted in 1992 to support environmental protection programs are reviewed.« less

Proposed Fourth Unregulated Contaminant Monitoring Rule (UCMR 4) Meeting Presentations

EPA Pesticide Factsheets

This document contains the proposed Unregulated Contaminant Monitoring Rule (UCMR 4) Meeting Presentations from a public webinar held by EPA's Office of Ground Water and Drinking Water on January 13, 2016.

Final report on Weeks Island Monitoring Phase : 1999 through 2004.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ehgartner, Brian L.; Munson, Darrell Eugene

2005-05-01

This Final Report on the Monitoring Phase of the former Weeks Island Strategic Petroleum Reserve crude oil storage facility details the results of five years of monitoring of various surface accessible quantities at the decommissioned facility. The Weeks Island mine was authorized by the State of Louisiana as a Strategic Petroleum Reserve oil storage facility from 1979 until decommissioning of the facility in 1999. Discovery of a sinkhole over the facility in 1992 with freshwater inflow to the facility threatened the integrity of the oil storage and led to the decision to remove the oil, fill the chambers with brine,more » and decommission the facility. Thereafter, a monitoring phase, by agreement between the Department of Energy and the State, addressed facility stability and environmental concerns. Monitoring of the surface ground water and the brine of the underground chambers from the East Fill Hole produced no evidence of hydrocarbon contamination, which suggests that any unrecovered oil remaining in the underground chambers has been contained. Ever diminishing progression of the initial major sinkhole, and a subsequent minor sinkhole, with time was verification of the response of sinkholes to filling of the facility with brine. Brine filling of the facility ostensively eliminates any further growth or new formation from freshwater inflow. Continued monitoring of sinkhole response, together with continued surface surveillance for environmental problems, confirmed the intended results of brine pressurization. Surface subsidence measurements over the mine continued throughout the monitoring phase. And finally, the outward flow of brine was monitored as a measure of the creep closure of the mine chambers. Results of each of these monitoring activities are presented, with their correlation toward assuring the stability and environmental security of the decommissioned facility. The results suggest that the decommissioning was successful and no contamination of the surface environment by crude oil has been found.« less

Overview of Sensors and Needs for Environmental Monitoring

PubMed Central

Ho, Clifford K.; Robinson, Alex; Miller, David R.; Davis, Mary J.

2005-01-01

This paper surveys the needs associated with environmental monitoring and long-term environmental stewardship. Emerging sensor technologies are reviewed to identify compatible technologies for various environmental monitoring applications. The contaminants that are considered in this report are grouped into the following categories: (1) metals, (2) radioisotopes, (3) volatile organic compounds, and (4) biological contaminants. United States regulatory drivers are evaluated for different applications (e.g., drinking water, storm water, pretreatment, and air emissions), and sensor requirements are derived from these regulatory metrics. Sensor capabilities are then summarized according to contaminant type, and the applicability of the different sensors to various environmental monitoring applications is discussed.

Concentrations of Elements in Hellbender Blood and Fish Fillets from the Missouri Department of Conservation Monitoring Programs

USGS Publications Warehouse

May, Thomas W.; Walther, Mike J.; Brumbaugh, William G.

2007-01-01

This report presents the results of contaminant monitoring surveys conducted annually by the Missouri Department of Conservation to examine the levels of selected elemental contaminants in hellbender (Cryptobranchus alleganiensis) blood and fish. Catfish (Ictalurus furcatus, Ictalurus punctatus, Pylodictis olivaris), redhorse (Moxostoma anisorum, Moxostoma erythrurum), bass (Micropterus salmoides, Micropterus punctulatus, Micropterus Lacepede, Ambloplites rupestris), walleye (Sander vitreus), and sunfish (Lepomis megalotis) were collected from 17 sites as part of the Department's General Contaminant Monitoring Program. Bluegill (Lepomis macrochirus) and other sunfish (Lepomis megalotis, Lepomis cyanellus) were collected from 18 sites as part of the Department's Resource Assessment and Monitoring Program. Blood from hellbenders was collected from seven sites as part of the Department's Hellbender Monitoring Program.

Detection of long duration cloud contamination in hyper-temporal NDVI imagery

NASA Astrophysics Data System (ADS)

Ali, A.; de Bie, C. A. J. M.; Skidmore, A. K.; Scarrott, R. G.

2012-04-01

NDVI time series imagery are commonly used as a reliable source for land use and land cover mapping and monitoring. However long duration cloud can significantly influence its precision in areas where persistent clouds prevails. Therefore quantifying errors related to cloud contamination are essential for accurate land cover mapping and monitoring. This study aims to detect long duration cloud contamination in hyper-temporal NDVI imagery based land cover mapping and monitoring. MODIS-Terra NDVI imagery (250 m; 16-day; Feb'03-Dec'09) were used after necessary pre-processing using quality flags and upper envelope filter (ASAVOGOL). Subsequently stacked MODIS-Terra NDVI image (161 layers) was classified for 10 to 100 clusters using ISODATA. After classifications, 97 clusters image was selected as best classified with the help of divergence statistics. To detect long duration cloud contamination, mean NDVI class profiles of 97 clusters image was analyzed for temporal artifacts. Results showed that long duration clouds affect the normal temporal progression of NDVI and caused anomalies. Out of total 97 clusters, 32 clusters were found with cloud contamination. Cloud contamination was found more prominent in areas where high rainfall occurs. This study can help to stop error propagation in regional land cover mapping and monitoring, caused by long duration cloud contamination.

Application of Emulsified Zero-Valent Iron to Marine Environments

NASA Technical Reports Server (NTRS)

Quinn, Jacqueline W.; Brooks, Kathleen B.; Geiger, Cherie L.; Clausen, Christian A.; Milum, Kristen M.

2006-01-01

Contamination of marine waters and sediments with heavy metals and dense non-aqueous phase liquids (DNAPLs) including chlorinated solvents, pesticides and PCBs pose ecological and human health risks through the potential of the contaminant to bioaccumulate in fish, shellfish and avian populations. The contaminants enter marine environments through improper disposal techniques and storm water runoff. Current remediation technologies for application to marine environments include costly dredging and off-site treatment of the contaminated media. Emulsified zero-valent iron (EZVI) has been proven to effectively degrade dissolved-phase and DNAPL-phase contaminants in freshwater environments on both the laboratory and field-scale level. Emulsified Zero-Valent Metal (EZVM) using metals such as iron and/or magnesium have been shown in the laboratory and on the bench scale to be effective at removing metals contamination in freshwater environments. The application to marine environments, however, is only just being explored. This paper discusses. the potential use of EZVI or EZVM in brackish and saltwater environments, with supporting laboratory data detailing its effectiveness on trichloroethylene, lead, copper, nickel and cadmium.

Metabolomics for in situ environmental monitoring of surface waters impacted by contaminants from both point and non-point sources

EPA Science Inventory

We investigated the efficacy of metabolomics for field-monitoring of fish exposed to waste water treatment plant (WWTP) effluents and non-point sources of chemical contamination. Lab-reared male fathead minnows (Pimephales promelas, FHM) were held in mobile monitoring units and e...

Degradation of common polymer ropes in a sublittoral marine environment.

PubMed

Welden, Natalie A; Cowie, Phillip R

2017-05-15

Contamination by microplastic particles and fibres has been observed in sediment and animals sampled from the Firth of Clyde, West Scotland. In addition to microplastics released during clothes washing, a probable source is polymer ropes in abandoned, lost and discarded fishing and recreational sailing gear. The fragmentation of polypropylene, polyethylene, and nylon exposed to benthic conditions at 10m depth over 12months was monitored using changes in weight and tensile properties. Water temperature and light levels were continuously monitored. The degree of biofouling was measured using chlorophyll a, the weight of attached macroalgae, and colonising fauna. Results indicate microplastic fibres and particles may be formed in benthic environments despite reduced photodegradation. Polypropylene, Nylon, and polyethylene lost an average of 0.39%, 1.02%, and 0.45% of their mass per month respectively. Microscope images of the rope surface revealed notable surface roughening believed to be caused by abrasion by substrate and the action of fouling organisms. Copyright © 2017 Elsevier Ltd. All rights reserved.

Combined virtual and real robotic test-bed for single operator control of multiple robots

NASA Astrophysics Data System (ADS)

Lee, Sam Y.-S.; Hunt, Shawn; Cao, Alex; Pandya, Abhilash

2010-04-01

Teams of heterogeneous robots with different dynamics or capabilities could perform a variety of tasks such as multipoint surveillance, cooperative transport and explorations in hazardous environments. In this study, we work with heterogeneous robots of semi-autonomous ground and aerial robots for contaminant localization. We developed a human interface system which linked every real robot to its virtual counterpart. A novel virtual interface has been integrated with Augmented Reality that can monitor the position and sensory information from video feed of ground and aerial robots in the 3D virtual environment, and improve user situational awareness. An operator can efficiently control the real multi-robots using the Drag-to-Move method on the virtual multi-robots. This enables an operator to control groups of heterogeneous robots in a collaborative way for allowing more contaminant sources to be pursued simultaneously. The advanced feature of the virtual interface system is guarded teleoperation. This can be used to prevent operators from accidently driving multiple robots into walls and other objects. Moreover, the feature of the image guidance and tracking is able to reduce operator workload.

Contamination by Microcystis and microcystins of blue-green algae food supplements (BGAS) on the Italian market and possible risk for the exposed population.

PubMed

Vichi, Susanna; Lavorini, Paolo; Funari, Enzo; Scardala, Simona; Testai, Emanuela

2012-12-01

Blue green algae supplements (BGAS) are generally proposed as health-promoting natural products for their purported beneficial effects. Spirulina spp. and Aphanizomenon flos aquae are mainly used in BGAS production. They are usually collected from the natural environment, where other potentially toxic cyanobacteria can be present, making possible BGAS contamination by cyanotoxins, with potential risk for human health. In this work we apply a combined approach, by using chemical and molecular techniques, on BGAS of 17 brands available in Italy. Samples containing Spirulina-only were free of contamination. The Aphanizomenon flos aquae-based samples were contaminated by highly variable levels of microcystins (MC-LR and MC-LA congeners), up to 5.2 μg MC-LR equivalents per gram product. The highest variability (up to 50 fold) was among batches of the same brand, although intra-batch differences were also evidenced. PCR analyses were positive only for the presence of Microcystis sp., identified as the toxin-producing species responsible for contamination. At the maximum contamination levels found, a risk for consumers can be expected following chronic or sub-chronic exposure to a reasonable daily BGAS consumption of 4 g. The need for a strict monitoring by producers and Health Authority to assure an adequate protection for consumers is underscored. Copyright © 2012 Elsevier Ltd. All rights reserved.

Investigation of contamination of thin-film aluminum filters by MMH-NTO plumes exposed to UV radiation

NASA Astrophysics Data System (ADS)

Gupta, Vaibhav; Wieman, Seth; Didkovsky, Leonid; Haiges, Ralf; Yao, Yuhan; Wu, Wei; Gruntman, Mike; Erwin, Dan

2015-09-01

Thin-film aluminum filters degrade in space with significant reduction of their Extreme Ultraviolet (EUV) transmission. This degradation was observed on the EUV Spectrophotometer (ESP) onboard the Solar Dynamics Observatory's EUV Variability Experiment and the Solar EUV Monitor (SEM) onboard the Solar and Heliospheric Observatory. One of the possible causes for deterioration of such filters over time is contamination of their surfaces from plumes coming from periodic firing of their satellite's Monomethylhydrazine (MMH) - Nitrogen Tetroxide (NTO) thrusters. When adsorbed by the filters, the contaminant molecules are exposed to solar irradiance and could lead to two possible compositions. First, they could get polymerized leading to a permanent hydrocarbon layer buildup on the filter's surface. Second, they could accelerate and increase the depth of oxidation into filter's bulk aluminum material. To study the phenomena we experimentally replicate contamination of such filters in a simulated environment by MMH-NTO plumes. We apply, Scanning Electron Microscopy and X-Ray photoelectron spectroscopy to characterize the physical and the chemical changes on these contaminated sample filter surfaces. In addition, we present our first analysis of the effects of additional protective layer coatings based on self-assembled carbon monolayers for aluminum filters. This coverage is expected to significantly decrease their susceptibility to contamination and reduce the overall degradation of filter-based EUV instruments over their mission life.

A prospective survey of air and surface fungal contamination in a medical mycology laboratory at a tertiary care university hospital.

PubMed

Sautour, Marc; Dalle, Frédéric; Olivieri, Claire; L'ollivier, Coralie; Enderlin, Emilie; Salome, Elsa; Chovelon, Isabelle; Vagner, Odile; Sixt, Nathalie; Fricker-Pap, Véronique; Aho, Serge; Fontaneau, Olivier; Cachia, Claire; Bonnin, Alain

2009-04-01

Invasive filamentous fungi infections resulting from inhalation of mold conidia pose a major threat in immunocompromised patients. The diagnosis is based on direct smears, cultural symptoms, and culturing fungi. Airborne conidia present in the laboratory environment may cause contamination of cultures, resulting in false-positive diagnosis. Baseline values of fungal contamination in a clinical mycology laboratory have not been determined to date. A 1-year prospective survey of air and surface contamination was conducted in a clinical mycology laboratory during a period when large construction projects were being conducted in the hospital. Air was sampled with a portable air system impactor, and surfaces were sampled with contact Sabouraud agar plates. The collected data allowed the elaboration of Shewhart graphic charts. Mean fungal loads ranged from 2.27 to 4.36 colony forming units (cfu)/m(3) in air and from 0.61 to 1.69 cfu/plate on surfaces. Strict control procedures may limit the level of fungal contamination in a clinical mycology laboratory even in the context of large construction projects at the hospital site. Our data and the resulting Shewhart graphic charts provide baseline values to use when monitoring for inappropriate variations of the fungal contamination in a mycology laboratory as part of a quality assurance program. This is critical to the appropriate management of the fungal risk in hematology, cancer and transplantation patients.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dam, William; Gil, Dr. April; Johnson, Raymond H.

The US Department of Energy Office of Legacy Management (LM) is responsible for maintaining protective public health and environmental conditions at former uranium mill tailings sites nationwide via long-term stewardship. One of these sites, a former uranium mill near Riverton, Wyoming, is within the boundary of the Wind River Indian Reservation and operated from 1958 to 1963. Tailings and contaminated material associated with mill operations were removed and transported to an offsite disposal cell in 1989. The remedial action was completed under Title I of the Uranium Mill Tailings Radiation Control Act of 1978. Milling operations, which included an unlinedmore » tailings impoundment and an unlined evaporation pond, contaminated the shallow groundwater, resulting in a downgradient groundwater plume that discharges to the Little Wind River. A natural flushing compliance strategy was implemented in 1998. This strategy allows contaminants of concern to naturally flush from the groundwater, provided that contaminants flush below US Environmental Protection Agency maximum concentration limits within 100 years. As part of the compliance strategy, LM has implemented a groundwater monitoring program along with institutional controls that include the installation of an alternate water supply, continued sampling of private wells, and restrictions on well drilling and gravel pit construction. LM works closely with local stakeholders and community members to ensure that these institutional controls are in place and maintained. The Riverton site provides an interesting case study where contaminant remobilization due to river flooding prompted a reevaluation of the conceptual site model to verify if the current compliance strategy would remain protective of human health and the environment. Concentrations of groundwater contaminants, which include sulfate, molybdenum, and uranium, were transiently elevated following flooding of the Little Wind River in 2010 and 2016. These flood events provided the impetus to investigate other aspects of the hydrologic system, including the unsaturated zone, naturally reduced (sulfidic) zones, and evaporite deposits. New site conceptual models, field and laboratory studies, and numerical models are being developed to explain how biogeochemical sediment–water interactions contribute to plume persistence and flood-related increases in groundwater concentrations. Updated human health and ecological risk assessments are progressing to evaluate the risk to human health and the environment based on current site conditions. Groundwater concentrations may remain above US Environmental Protection Agency maximum concentration limits beyond the 100-year natural flushing regulatory time frame. LM in its capacity as a long-term steward continues to monitor the site to ensure protectiveness is maintained and to determine the feasibility of alternative compliance and remediation strategies.« less

Influences of climate on aflatoxin producing fungi and aflatoxin contamination.

PubMed

Cotty, Peter J; Jaime-Garcia, Ramon

2007-10-20

Aflatoxins are potent mycotoxins that cause developmental and immune system suppression, cancer, and death. As a result of regulations intended to reduce human exposure, crop contamination with aflatoxins causes significant economic loss for producers, marketers, and processors of diverse susceptible crops. Aflatoxin contamination occurs when specific fungi in the genus Aspergillus infect crops. Many industries frequently affected by aflatoxin contamination know from experience and anecdote that fluctuations in climate impact the extent of contamination. Climate influences contamination, in part, by direct effects on the causative fungi. As climate shifts, so do the complex communities of aflatoxin-producing fungi. This includes changes in the quantity of aflatoxin-producers in the environment and alterations to fungal community structure. Fluctuations in climate also influence predisposition of hosts to contamination by altering crop development and by affecting insects that create wounds on which aflatoxin-producers proliferate. Aflatoxin contamination is prevalent both in warm humid climates and in irrigated hot deserts. In temperate regions, contamination may be severe during drought. The contamination process is frequently broken down into two phases with the first phase occurring on the developing crop and the second phase affecting the crop after maturation. Rain and temperature influence the phases differently with dry, hot conditions favoring the first and warm, wet conditions favoring the second. Contamination varies with climate both temporally and spatially. Geostatistics and multiple regression analyses have shed light on influences of weather on contamination. Geostatistical analyses have been used to identify recurrent contamination patterns and to match these with environmental variables. In the process environmental conditions with the greatest impact on contamination are identified. Likewise, multiple regression analyses allow ranking of environmental variables based on relative influence on contamination. Understanding the impact of climate may allow development of improved management procedures, better allocation of monitoring efforts, and adjustment of agronomic practices in anticipation of global climate change.

Contamination during production of heater-cooler units by Mycobacterium chimaera potential cause for invasive cardiovascular infections: results of an outbreak investigation in Germany, April 2015 to February 2016.

PubMed

Haller, Sebastian; Höller, Christiane; Jacobshagen, Anja; Hamouda, Osamah; Abu Sin, Muna; Monnet, Dominique L; Plachouras, Diamantis; Eckmanns, Tim

2016-04-28

Invasive infections with Mycobacterium chimaera were reported in patients with previous open chest surgery and exposure to contaminated heater-cooler units (HCUs). We present results of the surveillance of clinical cases and of contaminated HCUs as well as environmental investigations in Germany up until February 2016. Clinical infections occurred in five male German cases over 50 years of age (range 53-80). Cases had been exposed to HCUs from one single manufacturer during open chest surgery up to five years prior to onset of symptoms. During environmental investigations, M. chimaera was detected in samples from used HCUs from three different countries and samples from new HCUs as well as in the environment at the manufacturing site of one manufacturer in Germany. Our investigation suggests that at least some of the M. chimaera infections may have been caused by contamination of HCUs at manufacturing site. We recommend that until sustainable measures for safe use of HCUs in operation theatres are implemented, users continue to adhere to instructions for use of HCUs and Field Safety Notices issued by the manufacturer, implement local monitoring for bacterial contamination and continuously check the websites of national and European authorities for current recommendations for the safe operation of HCUs.

Disposal and improvement of contaminated by waste extraction of copper mining in chile

NASA Astrophysics Data System (ADS)

Naranjo Lamilla, Pedro; Blanco Fernández, David; Díaz González, Marcos; Robles Castillo, Marcelo; Decinti Weiss, Alejandra; Tapia Alvarez, Carolina; Pardo Fabregat, Francisco; Vidal, Manuel Miguel Jordan; Bech, Jaume; Roca, Nuria

2016-04-01

This project originated from the need of a mining company, which mines and processes copper ore. High purity copper is produced with an annual production of 1,113,928 tons of concentrate to a law of 32%. This mining company has generated several illegal landfills and has been forced by the government to make a management center Industrial Solid Waste (ISW). The forecast volume of waste generated is 20,000 tons / year. Chemical analysis established that the studied soil has a high copper content, caused by nature or from the spread of contaminants from mining activities. Moreover, in some sectors, soil contamination by mercury, hydrocarbons and oils and fats were detected, likely associated with the accumulation of waste. The waters are also impacted by mining industrial tasks, specifically copper ores, molybdenum, manganese, sulfates and have an acidic pH. The ISW management center dispels the pollution of soil and water and concentrating all activities in a technically suitable place. In this center the necessary guidelines for the treatment and disposal of soil contamination caused by uncontrolled landfills are given, also generating a leachate collection system and a network of fluid monitoring physicochemical water quality and soil environment. Keywords: Industrial solid waste, soil contamination, Mining waste

Study of SRM Critical Surfaces Using Near Infrared Optical Fiber Spectrometry

NASA Technical Reports Server (NTRS)

Workman, G. L.; Hughes, C.; Arendale, W. A.

1997-01-01

The measurement and control of cleanliness for critical surfaces during manufacturing and in service operations provides a unique challenge in the current thrust for environmentally benign processes. Of particular interest has been work performed in maintaining quality in the production of bondline surfaces in propulsion systems and the identification of possible contaminants which are detrimental to the integrity of the bondline. This work requires an in-depth study of the possible sources of contamination, methodologies to identify contaminants, discrimination between contaminants and chemical species caused by environment, and the effect of particular contaminants on the bondline integrity of the critical surfaces. This paper will provide an introduction to the use of Near Infrared (NIR) optical fiber spectrometry in a nondestructive measurement system for process monitoring and how it can be used to help clarify issues concerning surface chemistry. In a previous conference, experimental results for quantitative measurement of silicone and Conoco HD2 greases, and tape residues on solid rocket motor surfaces were presented. This paper will present data for metal hydroxides and discuss the use of the integrating sphere to minimize the effects of physical properties of the surfaces (such as surface roughness) on the results obtained from the chemometric methods used for quantitative analysis.

Evaluation of membrane filter field monitors for microbiological air sampling

NASA Technical Reports Server (NTRS)

Fields, N. D.; Oxborrow, G. S.; Puleo, J. R.; Herring, C. M.

1974-01-01

Due to area constraints encountered in assembly and testing areas of spacecraft, the membrane filter field monitor (MF) and the National Aeronautics and Space Administration-accepted Reyniers slit air sampler were compared for recovery of airborne microbial contamination. The intramural air in a microbiological laboratory area and a clean room environment used for the assembly and testing of the Apollo spacecraft was studied. A significantly higher number of microorganisms was recovered by the Reyniers sampler. A high degree of consistency between the two sampling methods was shown by a regression analysis, with a correlation coefficient of 0.93. The MF samplers detected 79% of the concentration measured by the Reyniers slit samplers. The types of microorganisms identified from both sampling methods were similar.

Microcontroller - Based System for Electrogastrography Monitoring Through Wireless Transmission

NASA Astrophysics Data System (ADS)

Haddab, S.; Laghrouche, M.

2009-01-01

Electrogastrography (EGG) is a non-invasive method for recording the electrical activity of the stomach. This paper presents a system designed for monitoring the EGG physiological variables of a patient outside the hospital environment. The signal acquisition is achieved by means of an ambulatory system carried by the patient and connected to him through skin electrodes. The acquired signal is transmitted via the Bluetooth to a mobile phone where the data are stored into the memory and then transferred via the GSM network to the processing and diagnostic unit in the hospital. EGG is usually contaminated by artefacts and other signals, which are sometimes difficult to remove. We have used a neural network method for motion artefacts removal and biological signal separation.

[Surface disinfection in nursing homes--what is really happening? Study of control success in three Duisburg nursing homes].

PubMed

Martin, U; Sonntag, A-K; Neuhaus, B; Karch, H

2004-10-01

The effectiveness of cleaning and disinfection of environmental surfaces was evaluated in three nursing homes using bacteriological monitoring. Samples from inmates (nose, throat and wounds) and surface cleaning equipment were also taken. Cleaning solutions, disinfectants and cleaning clothes were found to be highly contaminated in two of three institutions. Referring to the surfaces in some cases disinfection didn't reduce bacterial colony counts and seeded MRSA as a potential pathogen in one nursing home. Six MRSA-positive inmates and identical strains were registered in the environment. MRSA can be used as a marker organism to demonstrate effectiveness of cleaning. To achieve further improvement bacteriological monitoring can help in focussing special cleaning and disinfection related problems.

An integrated approach for fusion of environmental and human health data for disease surveillance.

PubMed

Burkom, Howard S; Ramac-Thomas, Liane; Babin, Steven; Holtry, Rekha; Mnatsakanyan, Zaruhi; Yund, Cynthia

2011-02-28

This paper describes the problem of public health monitoring for waterborne disease outbreaks using disparate evidence from health surveillance data streams and environmental sensors. We present a combined monitoring approach along with examples from a recent project at the Johns Hopkins University Applied Physics Laboratory in collaboration with the U.S. Environmental Protection Agency. The project objective was to build a module for the Electronic Surveillance System for the Early Notification of Community-based Epidemics (ESSENCE) to include water quality data with health indicator data for the early detection of waterborne disease outbreaks. The basic question in the fused surveillance application is 'What is the likelihood of the public health threat of interest given recent information from available sources of evidence?' For a scientific perspective, we formulate this question in terms of the estimation of positive predictive value customary in classical epidemiology, and we present a solution framework using Bayesian Networks (BN). An overview of the BN approach presents advantages, disadvantages, and required adaptations needed for a fused surveillance capability that is scalable and robust relative to the practical data environment. In the BN project, we built a top-level health/water-quality fusion BN informed by separate waterborne-disease-related networks for the detection of water contamination and human health effects. Elements of the art of developing networks appropriate to this environment are discussed with examples. Results of applying these networks to a simulated contamination scenario are presented. Copyright © 2011 John Wiley & Sons, Ltd.

International Space Station External Contamination Environment for Space Science Utilization

NASA Technical Reports Server (NTRS)

Soares, Carlos E.; Mikatarian, Ronald R.; Steagall, Courtney A.; Huang, Alvin Y.; Koontz, Steven; Worthy, Erica

2014-01-01

The International Space Station (ISS) is the largest and most complex on-orbit platform for space science utilization in low Earth orbit. Multiple sites for external payloads, with exposure to the associated natural and induced environments, are available to support a variety of space science utilization objectives. Contamination is one of the induced environments that can impact performance, mission success and science utilization on the vehicle. The ISS has been designed, built and integrated with strict contamination requirements to provide low levels of induced contamination on external payload assets. This paper addresses the ISS induced contamination environment at attached payload sites, both at the requirements level as well as measurements made on returned hardware, and contamination forecasting maps being generated to support external payload topology studies and science utilization.

Geochemical cartography as a tool for assessing the degree of soil contamination with heavy metals in Poland

NASA Astrophysics Data System (ADS)

Szymon Borkowski, Andrzej; Kwiatkowska-Malina, Jolanta

2016-04-01

Spatial disposition of chemical elements including heavy metals in the soil environment is a very important information during preparation of the thematic maps for the environmental protection and/or spatial planning. This knowledge is also essential for the earth's surface and soil's monitoring, designation of areas requiring improvement including remediation. The main source of anthropogenic pollution of soil with heavy metals are industry related to the mining coal and liquid fuels, mining and metallurgy, chemical industry, energy production, waste management, agriculture and transport. The geochemical maps as a kind of specific thematic maps made on the basis of datasets obtained from the Polish Geological Institute's resources allow to get to know the spatial distribution of different chemical elements including heavy metals in soil. The results of the research carried out by the Polish Geological Institute showed strong contamination in some regions in Poland mainly with arsenic, cadmium, lead and nickel. For this reason it was the point to prepare geochemical maps showing contamination of soil with heavy metals, and determine main sources of contamination and zones where heavy metals concentration was higher than acceptable contents. It was also presented a summary map of soil contamination with heavy metals. Additionally, location of highly contaminated zones was compiled with predominant in those areas types of arable soils and then results were thoroughly analyzed. This information can provide a base for further detailed studies on the soil contamination with heavy metals.

Saltwater contamination in the managed low-lying farmland of the Venice coast, Italy: An assessment of vulnerability.

PubMed

Da Lio, Cristina; Carol, Eleonora; Kruse, Eduardo; Teatini, Pietro; Tosi, Luigi

2015-11-15

The original morphology and hydrogeology of many low-lying coastlands worldwide have been significantly modified over the last century through river diversion, embankment built-up, and large-scale land reclamation projects. This led to a progressive shifting of the groundwater-surficial water exchanges from naturally to anthropogenically driven. In this human-influenced hydrologic landscape, the saltwater contamination usually jeopardizes the soil productivity. In the coastland south of Venice (Italy), several well log measurements, chemical and isotope analyses have been performed over the last decade to characterize the occurrence of the salt contamination. The processing of this huge dataset highlights a permanent variously-shaped saline contamination up to 20km inland, with different conditions in relation with the various geomorphological features of the area. The results point out the important role of the land reclamation in shaping the present-day salt contamination and reveal the contribution of precipitation, river discharge, lagoon and sea water to the shallow groundwater in the various coastal sectors. Moreover, an original vulnerability map to salt contamination in relation to the farmland productivity has been developed taking into account the electrical conductivity of the upper aquifer in the worst condition, the ground elevation, and the distance from salt and fresh surface water sources. Finally, the study allows highlighting the limit of traditional investigations in monitoring saltwater contamination at the regional scale in managed Holocene coastal environments. Possible improvements are outlined. Copyright © 2015 Elsevier B.V. All rights reserved.

Landfill-stimulated iron reduction and arsenic release at the Coakley Superfund Site (NH).

PubMed

deLemos, Jamie L; Bostick, Benjamin C; Renshaw, Carl E; Stürup, Stefan; Feng, Xiahong

2006-01-01

Arsenic is a contaminant at more than one-third of all Superfund Sites in the United States. Frequently this contamination appearsto resultfrom geochemical processes rather than the presence of a well-defined arsenic source. Here we examine the geochemical processes that regulate arsenic levels at the Coakley Landfill Superfund Site (NH), a site contaminated with As, Cr, Pb, Ni, Zn, and aromatic hydrocarbons. Long-term field observations indicate that the concentrations of most of these contaminants have diminished as a result of treatment by monitored natural attenuation begun in 1998; however, dissolved arsenic levels increased modestly over the same interval. We attribute this increase to the reductive release of arsenic associated with poorly crystalline iron hydroxides within a glaciomarine clay layer within the overburden underlying the former landfill. Anaerobic batch incubations that stimulated iron reduction in the glaciomarine clay released appreciable dissolved arsenic and iron. Field observations also suggest that iron reduction associated with biodegradation of organic waste are partly responsible for arsenic release; over the five-year study period since a cap was emplaced to prevent water flow through the site, decreases in groundwater dissolved benzene concentrations at the landfill are correlated with increases in dissolved arsenic concentrations, consistent with the microbial decomposition of both benzene and other organics, and reduction of arsenic-bearing iron oxides. Treatment of contaminated groundwater increasingly is based on stimulating natural biogeochemical processes to degrade the contaminants. These results indicate that reducing environments created within organic contaminant plumes may release arsenic. In fact, the strong correlation (>80%) between elevated arsenic levels and organic contamination in groundwater systems at Superfund Sites across the United States suggests that arsenic contamination caused by natural degradation of organic contaminants may be widespread.

Emerging pollutants in the environment: present and future challenges in biomonitoring, ecological risks and bioremediation.

PubMed

Gavrilescu, Maria; Demnerová, Kateřina; Aamand, Jens; Agathos, Spiros; Fava, Fabio

2015-01-25

Emerging pollutants reach the environment from various anthropogenic sources and are distributed throughout environmental matrices. Although great advances have been made in the detection and analysis of trace pollutants during recent decades, due to the continued development and refinement of specific techniques, a wide array of undetected contaminants of emerging environmental concern need to be identified and quantified in various environmental components and biological tissues. These pollutants may be mobile and persistent in air, water, soil, sediments and ecological receptors even at low concentrations. Robust data on their fate and behaviour in the environment, as well as on threats to ecological and human health, are still lacking. Moreover, the ecotoxicological significance of some emerging micropollutants remains largely unknown, because satisfactory data to determine their risk often do not exist. This paper discusses the fate, behaviour, (bio)monitoring, environmental and health risks associated with emerging chemical (pharmaceuticals, endocrine disruptors, hormones, toxins, among others) and biological (bacteria, viruses) micropollutants in soils, sediments, groundwater, industrial and municipal wastewaters, aquaculture effluents, and freshwater and marine ecosystems, and highlights new horizons for their (bio)removal. Our study aims to demonstrate the imperative need to boost research and innovation for new and cost-effective treatment technologies, in line with the uptake, mode of action and consequences of each emerging contaminant. We also address the topic of innovative tools for the evaluation of the effects of toxicity on human health and for the prediction of microbial availability and degradation in the environment. Additionally, we consider the development of (bio)sensors to perform environmental monitoring in real-time mode. This needs to address multiple species, along with a more effective exploitation of specialised microbes or enzymes capable of degrading endocrine disruptors and other micropollutants. In practical terms, the outcomes of these activities will build up the knowledge base and develop solutions to fill the significant innovation gap faced worldwide. Copyright © 2014 Elsevier B.V. All rights reserved.

Solventless and solvent-minimized sample preparation techniques for determining currently used pesticides in water samples: a review.

PubMed

Tankiewicz, Maciej; Fenik, Jolanta; Biziuk, Marek

2011-10-30

The intensification of agriculture means that increasing amounts of toxic organic and inorganic compounds are entering the environment. The pesticides generally applied nowadays are regarded as some of the most dangerous contaminants of the environment. Their presence in the environment, especially in water, is hazardous because they cause human beings to become more susceptible to disease. For these reasons, it is essential to monitor pesticide residues in the environment with the aid of all accessible analytical methods. The analysis of samples for the presence of pesticides is problematic, because of the laborious and time-consuming operations involved in preparing samples for analysis, which themselves may be a source of additional contaminations and errors. To date, it has been standard practice to use large quantities of organic solvents in the sample preparation process; but as these solvents are themselves hazardous, solventless and solvent-minimized techniques are coming into use. This paper discusses the most commonly used over the last 15 years sample preparation techniques for monitoring organophosphorus and organonitrogen pesticides residue in water samples. Furthermore, a significant trend in sample preparation, in accordance with the principles of 'Green Chemistry' is the simplification, miniaturization and automation of analytical techniques. In view of this aspect, several novel techniques are being developed in order to reduce the analysis step, increase the sample throughput and to improve the quality and the sensitivity of analytical methods. The paper describes extraction techniques requiring the use of solvents - liquid-liquid extraction (LLE) and its modifications, membrane extraction techniques, hollow fibre-protected two-phase solvent microextraction, liquid phase microextraction based on the solidification of a floating organic drop (LPME-SFO), solid-phase extraction (SPE) and single-drop microextraction (SDME) - as well as solvent-free techniques - solid phase microextraction (SPME) and stir bar sorptive extraction (SBSE). The advantages and drawbacks of these techniques are also discussed, and some solutions to their limitations are proposed. Copyright © 2011 Elsevier B.V. All rights reserved.

Lawrence Livermore National Laboratory Environmental Report 2016

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rosene, Crystal

The purposes of the Environmental Report 2016 are to record LLNL’s compliance with environmental standards and requirements, describe LLNL’s environmental protection and remediation programs, and present the results of environmental monitoring. Specifically, the report discusses LLNL’s EMS; describes significant accomplishments in pollution prevention; presents the results of air, water, vegetation, and foodstuff monitoring; reports radiological doses from LLNL operations; summarizes LLNL’s activities involving special status wildlife, plants, and habitats; and describes the progress LLNL has made in remediating groundwater contamination. Environmental monitoring at LLNL, including analysis of samples and data, is conducted according to documented standard operating procedures. Duplicate samplesmore » are collected and analytical results are reviewed and compared to internal acceptance standards. This report is prepared for DOE by LLNL’s Environmental Functional Area (EFA). Submittal of the report satisfies requirements under DOE Order 231.1B, “Environment, Safety and Health Reporting,” and DOE Order 458.1, “Radiation Protection of the Public and Environment.” The report is distributed in electronic form and is available to the public at https://saer.llnl.gov/, the website for the LLNL annual environmental report. Previous LLNL annual environmental reports beginning with 1994 are also on the website.« less

External Contamination Environment at ISS Included: Selected Results from Payloads Contamination Mapping Delivery 3 Package

NASA Technical Reports Server (NTRS)

Olsen, Randy; Huang, Alvin; Steagall, Courtney; Kohl, Nathaniel; Koontz, Steve; Worthy, Erica

2017-01-01

The International Space Station is the largest and most complex on-orbit platform for space science utilization in low Earth orbit. Multiple sites for external payloads, with exposure to the associated natural and induced environments, are available to support a variety of space science utilization objectives. Contamination is one of the induced environments that can impact performance, mission success and science utilization on the vehicle. The ISS has been designed, built and integrated with strict contamination requirements to provide low levels of induced contamination on external payload assets.

An approach for mapping the vulnerability of European Union soils to antibiotic contamination.

PubMed

de la Torre, Ana; Iglesias, Irene; Carballo, Matilde; Ramírez, Pablo; Muñoz, María Jesús

2012-01-01

Release of antibiotics into the environment through the agricultural reuse of animal manure is considered a cause of chronic environmental exposure that often leads to adverse ecotoxicological effects, as well as to the introduction of antibiotic-resistant bacteria into the environment. The vulnerability of soil to antibiotic contamination plays a major role in determining the extent of the contamination and the likelihood of the emergence of antibiotic resistance and the appearance of ecotoxicological effects. It depends on soil characteristics, which vary across Europe, and antibiotic characteristics, which vary across drug classes. Understanding how soil vulnerability varies geographically for different veterinary medicinal products would be very useful for resource allocation among surveillance programmes. This paper performs risk analysis of the EU region for 12 antimicrobials using a spatial assessment performed in four steps. First, antibiotic release was estimated based on livestock density. Then exposure was estimated based on antimicrobial soil contamination. Third, consequences were modelled based on soil uses. Finally, risk was estimated by combining release, exposure and consequences using spatial multicriteria decision analysis. A final risk value for soil vulnerability was calculated for each antibiotic studied and displayed in chloropletic maps (ArcGIS 9.3). Furthermore, the Getis-Ord Gi statistic was used to identify clusters of areas at high risk for antibiotic soil contamination. Enrofloxacin was the highest-risk antibiotic in the European Union, followed by tetracyclines, tylosin and sulfodiazine. The highest risk values were found in Belgium, Ireland, Netherlands, Switzerland, Denmark, Germany and the UK. The results suggest that this methodology can be used successfully for evaluating the contamination potential of antibiotics over large areas with limited input data. This work is a preliminary step towards prioritising the use of veterinary medicinal products (VMPs), orientating monitoring studies and antimicrobial surveillance programmes, and informing sustainable decision-making for interventions designed to mitigate the risk of VMPs. Copyright © 2011 Elsevier B.V. All rights reserved.

List of Laboratories Approved by EPA for the Fourth Unregulated Contaminant Monitoring Rule (UCMR 4)

EPA Pesticide Factsheets

This document provides a list of laboratories that met the Unregulated Contaminant Monitoring Rule 4 (UCMR 4) Laboratory Approval Program application and Proficiency Testing (PT) criteria for the methods indicated.

List of Laboratories Approved by EPA for the Third Unregulated Contaminant Monitoring Rule (UCMR 3)

EPA Pesticide Factsheets

This document provides a list of laboratories that met the Unregulated Contaminant Monitoring Rule 3 (UCMR 3) Laboratory Approval Program application and Proficiency Testing (PT) criteria for the methods indicated.

Groundwater contaminants in the deep benthic zone of urban streams in Canada (Invited)

NASA Astrophysics Data System (ADS)

Roy, J. W.; Bickerton, G.

2010-12-01

There is little information available on the potential threat that groundwater containing land-based contaminants poses to aquatic ecosystems in urban environments. In this study, a rapid screening approach was applied at the stream reach-scale for eight urban streams (reaches from 100 to < 1000 m). The objective was to determine what types of groundwater contaminants could be detected in the deeper benthic zone of these streams, if any, to start to address questions of whether such contaminants are a concern and which types are the most problematic. The benthic community may be especially at risk since it may experience higher contaminant concentrations than the stream itself due to fewer losses from sorption, degradation and volatilization processes. For each stream, groundwater samples from below the stream bed (typically 25-75 cm) were collected using a drive-point mini-profiler at intervals of 10-15 m along the stream and were subsequently analysed for general chemistry and a wide range of common and emerging urban contaminants. For a few test streams with known contamination, the area of contamination was identified with this technique. In addition, previously unknown contaminants or areas of contamination were identified at all nine streams. Identified contaminants included benzene and other petroleum hydrocarbons, fuel oxygenates (e.g. MTBE), perchlorate, pesticides, artificial sweeteners, and various chlorinated solvent compounds. In addition, elevated levels of nitrate, phosphate, some heavy metals, including cadmium and arsenic, and elevated chloride (likely indicating road salt) were detected. Most streams had many different types of contaminants, often overlapping over small stretches, and together often covering substantial portions of the monitored reach. The findings provide support for this screening approach for delineating areas of potential ecological concern and identifying possible sources of groundwater contamination, for urban settings. They also suggest that the presence of multiple groundwater contaminants may be a more common threat to the benthic community of urban streams than currently perceived.

Application and assessment of a regular environmental monitoring of the antineoplastic drug contamination level in pharmacies - the MEWIP project.

PubMed

Kiffmeyer, Thekla K; Tuerk, Jochen; Hahn, Moritz; Stuetzer, Hartmut; Hadtstein, Claudia; Heinemann, André; Eickmann, Udo

2013-05-01

A large-scale study was carried out in order to determine the contamination level of antineoplastic drugs in pharmacies and to investigate the suitability and effects of wipe sample monitoring at regular intervals. A specific study design was developed. The 130 participating pharmacies were divided into a study and a control group, carrying out five and two wipe sampling cycles, respectively. The work practice was analyzed using questionnaires to identify factors that influence the contamination level. From 1269 wipe samples, 774 (61%) were contaminated with at least one of the analyzed cytotoxic drugs: cyclophosphamide, docetaxel, etoposide, 5-fluorouracil, gemcitabine, ifosfamide, methotrexate, and paclitaxel. A significant decrease of the contamination with cyclophosphamide and 5-fluorouracil was observed in the study group. The Monitoring-Effect Study of Wipe Sampling in Pharmacies method has proven to be a reliable and affordable tool for contamination control. Based on the 90th percentile of the contamination values, a substance-independent performance-based guidance value of 0.1ng cm(-2) has been derived.

Space Station Environmental Health System water quality monitoring

NASA Technical Reports Server (NTRS)

Vincze, Johanna E.; Sauer, Richard L.

1990-01-01

One of the unique aspects of the Space Station is that it will be a totally encapsulated environment and the air and water supplies will be reclaimed for reuse. The Environmental Health System, a subsystem of CHeCS (Crew Health Care System), must monitor the air and water on board the Space Station Freedom to verify that the quality is adequate for crew safety. Specifically, the Water Quality Subsystem will analyze the potable and hygiene water supplies regularly for organic, inorganic, particulate, and microbial contamination. The equipment selected to perform these analyses will be commercially available instruments which will be converted for use on board the Space Station Freedom. Therefore, the commercial hardware will be analyzed to identify the gravity dependent functions and modified to eliminate them. The selection, analysis, and conversion of the off-the-shelf equipment for monitoring the Space Station reclaimed water creates a challenging project for the Water Quality engineers and scientists.

Environmental Assessment for Sustainability and Resiliency for Ecological and Human Health

PubMed Central

Burger, Joanna; Gochfeld, Michael; Clarke, James; Jeitner, Christian; Pittfield, Taryn

2015-01-01

Considerable attention has been devoted to environmental assessment and monitoring, primarily by physical and biological scientists, and more recently by social scientists. However, population growth and global change have resulted in an imperative to assess the resiliency of the environment to adapt to large scale changes and to continue to produce goods and services for future generations (sustainability). Changing land use needs or expectations may require the remediation and restoration of degraded or contaminated land. This paper provides an overview of monitoring types, and discusses how indicators for the different monitoring types can be developed to address questions of ecological health, human health, and whether restoration and remediation are effective. We suggest that along with more traditional types of monitoring, agencies should consider recovery indicators or metrics, as well as resiliency metrics. We suggest that one goal of assessment should be to determine if management, remediation, restoration, and mitigation reduce recovery time, thus reducing community vulnerability and enhancing resiliency to environmental stressors and disasters. PMID:27468428

Mercury Assessment and Monitoring Protocol for the Bear Creek Watershed, Colusa County, California

USGS Publications Warehouse

Suchanek, Thomas H.; Hothem, Roger L.; Rytuba, James J.; Yee, Julie L.

2010-01-01

This report summarizes the known information on the occurrence and distribution of mercury (Hg) in physical/chemical and biological matrices within the Bear Creek watershed. Based on these data, a matrix-specific monitoring protocol for the evaluation of the effectiveness of activities designed to remediate Hg contamination in the Bear Creek watershed is presented. The monitoring protocol documents procedures for collecting and processing water, sediment, and biota for estimation of total Hg (TotHg) and monomethyl mercury (MMeHg) in the Bear Creek watershed. The concurrent sampling of TotHg and MMeHg in biota as well as water and sediment from 10 monitoring sites is designed to assess the relative bioavailability of Hg released from Hg sources in the watershed and identify environments conducive to Hg methylation. These protocols are designed to assist landowners, land managers, water quality regulators, and scientists in determining whether specific restoration/mitigation actions lead to significant progress toward achieving water quality goals to reduce Hg in Bear and Sulphur Creeks.

Buffer zone monitoring plan for the Dos Rios subdivision, Gunnison, Colorado

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-02-01

This report presents a plan for water quality monitoring at the Dos Rios subdivision (Units 2, 3, and the Island Unit) that is intended to satisfy the informational needs of residents who live southwest (downgradient) of the former Gunnison processing site. Water quality monitoring activities described in this report are designed to protect the public from residual contamination that entered the ground water as a result of previous uranium milling operations. Requirements presented in this monitoring plan are also included in the water sampling and analysis plan (WSAP) for the Gunnison Uranium Mill Tailings Remedial Action (UMTRA) Project site. Themore » Gunnison WSAP is a site-specific document prepared by the U.S. Department of Energy (DOE) that provides background, guidance, and justification for future ground water sampling and analysis activities for the UMTRA Project Gunnison processing and disposal sites. The WSAP will be updated annually, as additional water quality data are collected and interpreted, to provide ongoing protection for public health and the environment.« less

The monitoring of pesticides and alkylphenols in selected rivers in the State of Selangor, Malaysia.

PubMed

Tan, B L L; Mustafa, A M

2004-01-01

Alkylphenols and most pesticides, especially organochlorine pesticides are endocrine-disrupting chemicals and they usually mimic the female hormone, estrogen. Using these chemicals in our environment would eventually lead us to consume them somehow in the food web. Several rivers in the State of Selangor, Malaysia were selected to monitor the level of alkylphenols and pesticides contamination for several months. The compounds were extracted from the water samples using liquid-liquid extraction method with dichloromethane and ethyl acetate as the extracting solvents. The alkylphenols and pesticides were analyzed by selected ion monitoring (SIM) mode using the quadrapole detector in Shimadzu QP-5000 gas chromatograph-mass spectrometer (GCMS). Recovery of most alkylphenols and pesticides were in the range of 50% to 120%. Trace amounts of the compounds were detected in the river water samples, mainly in the range of parts per trillion. This technique of monitoring the levels of endocrine-disruptors in river water is consistent and cost effective.

Monitoring Potential Transport of Radioactive Contaminants in Shallow Ephemeral Channels: FY2015 and FY2016

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mizell, Steve A; Miller, Julianne J; McCurdy, Greg

The Desert Research Institute (DRI) is conducting a field assessment of the potential for contaminated soil to be transported from the Smoky Contamination Area (CA) as a result of storm runoff. This activity supports Nevada Nuclear Security Administration (NNSA) efforts to complete regulatory closure of the Soils Corrective Action Unit (CAU) contamination areas. The work is intended to confirm the likely mechanism of transport and determine the meteorological conditions that might cause movement of contaminated soils, as well as determine the particle size fraction that is most closely associated with transported radionuclide-contaminated soils. These data will facilitate the appropriate closuremore » design and post-closure monitoring program.« less

Monitoring Potential Transport of Radioactive Contaminants in Shallow Ephemeral Channels: FY2013 and FY2014 (revised)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mizell, Steve A.; Miller, Julianne J.; McCurdy, Greg D.

The Desert Research Institute (DRI) is conducting a field assessment of the potential for contaminated soil to be transported from the Smoky Contamination Area (CA) as a result of storm runoff, which supports National Nuclear Security Administration (NNSA) efforts to complete regulatory closure of the Soils Corrective Action Unit (CAU) contamination areas. The work is intended to confirm the likely mechanism of transport and determine the meteorological conditions that might cause movement of contaminated soils, as well as determine the particle size fraction that is most closely associated with transported radionuclide-contaminated soils. These data will facilitate the appropriate closure designmore » and post-closure monitoring program.« less

In situ assessment of phytotechnologies for multicontaminated soil management.

PubMed

Ouvrard, S; Barnier, C; Bauda, P; Beguiristain, T; Biache, C; Bonnard, M; Caupert, C; Cébron, A; Cortet, J; Cotelle, S; Dazy, M; Faure, P; Masfaraud, J F; Nahmani, J; Palais, F; Poupin, P; Raoult, N; Vasseur, P; Morel, J L; Leyval, C

2011-01-01

Due to human activities, large volumes of soils are contaminated with organic pollutants such as polycyclic aromatic hydrocarbons, and very often by metallic pollutants as well. Multipolluted soils are therefore a key concern for remediation. This work presents a long-term evaluation of the fate and environmental impact of the organic and metallic contaminants of an industrially polluted soil under natural and plant-assisted conditions. A field trial was followed for four years according to six treatments in four replicates: unplanted, planted with alfalfa with or without mycorrhizal inoculation, planted with Noccaea caerulescens, naturally colonized by indigenous plants, and thermally treated soil planted with alfalfa. Leaching water volumes and composition, PAH concentrations in soil and solutions, soil fauna and microbial diversity, soil and solution toxicity using standardized bioassays, plant biomass, mycorrhizal colonization, were monitored. Results showed that plant cover alone did not affect total contaminant concentrations in soil. However, it was most efficient in improving the contamination impact on the environment and in increasing the biological diversity. Leaching water quality remained an issue because of its high toxicity shown by micro-algae testing. In this matter, prior treatment of the soil by thermal desorption proved to be the only effective treatment.

Instruction manual, Optical Effects Module, Model OEM

NASA Technical Reports Server (NTRS)

1975-01-01

The Optical Effects Module Model OEM-1, a laboratory prototype instrument designed for the automated measurement of radiation transmission and scattering through optical samples, is described. The system comprises two main components: the Optical Effects Module Enclosure (OEME) and the Optical Effects Module Electronic Controller and Processor (OEMCP). The OEM is designed for operation in the near UV at approximately 2540A, corresponding to the most intense spectral line activated by the mercury discharge lamp used for illumination. The radiation from this source is detected in transmission and reflection through a number of selectable samples. The basic objective of this operation is to monitor in real time the accretion of possible contamination on the surface of these samples. The optical samples are exposed outside of the OEME proper to define exposure conditions and to separate exposure and measurement environments. Changes in the transmissivity of the sample are attributable to surface contamination or to bulk effects due to radiation. Surface contamination will increase radiation scattering due to Rayleigh-Gans effect or to other phenomena, depending on the characteristics size of the particulate contaminants. Thus, also scattering from the samples becomes a part of the measurement program.

An OSEE Based Portable Surface Contamination Monitor

NASA Technical Reports Server (NTRS)

Perey, Daniel F.

1997-01-01

Many industrial and aerospace processes involving the joining of materials, require sufficient surface cleanliness to insure proper bonding. Processes as diverse as painting, welding, or the soldering of electronic circuits will be compromised if prior inspection and removal of surface contaminants is inadequate. As process requirements become more stringent and the number of different materials and identified contaminants increases, various instruments and techniques have been developed for improved inspection. One such technique based on the principle of Optically Stimulated Electron Emission (OSEE) has been explored for a number of years as a tool for surface contamination monitoring. Some of the benefits of OSEE are: it's non-contacting; requires little operator training; and has very high contamination sensitivity. This paper describes the development of a portable OSEE based surface contamination monitor. The instrument is suitable for both hand-held and robotic inspections with either manual or automated control of instrument operation. In addition, instrument output data is visually displayed to the operator and may be output to an external computer for archiving or analysis.

Pesticide use in the wheat-maize double cropping systems of the North China Plain: Assessment, field study, and implications.

PubMed

Brauns, Bentje; Jakobsen, Rasmus; Song, Xianfang; Bjerg, Poul L

2018-03-01

In the North China Plain (NCP), rising inputs of pesticides have intensified the environmental impact of farming activities in recent decades by contributing to surface water and groundwater contamination. In response to this, the Chinese government imposed stricter regulations on pesticide approval and application, and better monitoring strategies are being developed. However, sufficient and well-directed research on the accumulation and impact of different pesticides is needed for informed decision-making. In this study, current pesticide use, and recent and current research on water contamination by pesticides in the NCP are reviewed and assessed. Additionally, a small-scale field study was performed to determine if residuals from currently-used pesticides in the NCP can be detected in surface water, and in connected shallow groundwater. The contaminants of interest were commonly used pesticides on winter wheat-summer maize fields (the dominant cropping system in the NCP), such as 2,4-D and atrazine. Sampling took place in May, July, and October 2013; and March 2014. Results from our literature research showed that sampling is biased towards surface water monitoring. Furthermore, most studies focus on organic chlorinated pesticides (OCPs) like the isomers of dichlorodiphenyltrichloroethane (DDT) and hexachlorocyclohexane (HCH), which were banned in China in 1983. However, currently-used herbicides like 2,4-D and atrazine were detected in river water and groundwater in all samplings of our field study. The highest concentrations of 2,4-D and atrazine were found in the river water, ranging up to 3.00 and 0.96μg/L, respectively. The monitoring of banned compounds was found to be important because several studies indicate that they are still accumulating in the environment and/or are still illegally in use. However, supported by our own data, we find that the monitoring in groundwater and surface water of currently permitted pesticides in China needs equal attention, and should therefore be increased. Copyright © 2017 Elsevier B.V. All rights reserved.