40 CFR 270.61 - Emergency permits.

Code of Federal Regulations, 2014 CFR

2014-07-01

....61 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) EPA ADMINISTERED PERMIT PROGRAMS: THE HAZARDOUS WASTE PERMIT PROGRAM Special Forms of Permits § 270.61 Emergency... an imminent and substantial endangerment to human health or the environment the Director may issue a...

ADVANCED NUCLEAR FUEL CYCLE EFFECTS ON THE TREATMENT OF UNCERTAINTY IN THE LONG-TERM ASSESSMENT OF GEOLOGIC DISPOSAL SYSTEMS - EBS INPUT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sutton, M; Blink, J A; Greenberg, H R

2012-04-25

The Used Fuel Disposition (UFD) Campaign within the Department of Energy's Office of Nuclear Energy (DOE-NE) Fuel Cycle Technology (FCT) program has been tasked with investigating the disposal of the nation's spent nuclear fuel (SNF) and high-level nuclear waste (HLW) for a range of potential waste forms and geologic environments. The planning, construction, and operation of a nuclear disposal facility is a long-term process that involves engineered barriers that are tailored to both the geologic environment and the waste forms being emplaced. The UFD Campaign is considering a range of fuel cycles that in turn produce a range of wastemore » forms. The UFD Campaign is also considering a range of geologic media. These ranges could be thought of as adding uncertainty to what the disposal facility design will ultimately be; however, it may be preferable to thinking about the ranges as adding flexibility to design of a disposal facility. For example, as the overall DOE-NE program and industrial actions result in the fuel cycles that will produce waste to be disposed, and the characteristics of those wastes become clear, the disposal program retains flexibility in both the choice of geologic environment and the specific repository design. Of course, other factors also play a major role, including local and State-level acceptance of the specific site that provides the geologic environment. In contrast, the Yucca Mountain Project (YMP) repository license application (LA) is based on waste forms from an open fuel cycle (PWR and BWR assemblies from an open fuel cycle). These waste forms were about 90% of the total waste, and they were the determining waste form in developing the engineered barrier system (EBS) design for the Yucca Mountain Repository design. About 10% of the repository capacity was reserved for waste from a full recycle fuel cycle in which some actinides were extracted for weapons use, and the remaining fission products and some minor actinides were encapsulated in borosilicate glass. Because the heat load of the glass was much less than the PWR and BWR assemblies, the glass waste form was able to be co-disposed with the open cycle waste, by interspersing glass waste packages among the spent fuel assembly waste packages. In addition, the Yucca Mountain repository was designed to include some research reactor spent fuel and naval reactor spent fuel, within the envelope that was set using the commercial reactor assemblies as the design basis waste form. This milestone report supports Sandia National Laboratory milestone M2FT-12SN0814052, and is intended to be a chapter in that milestone report. The independent technical review of this LLNL milestone was performed at LLNL and is documented in the electronic Information Management (IM) system at LLNL. The objective of this work is to investigate what aspects of quantifying, characterizing, and representing the uncertainty associated with the engineered barrier are affected by implementing different advanced nuclear fuel cycles (e.g., partitioning and transmutation scenarios) together with corresponding designs and thermal constraints.« less

40 CFR 262.54 - Special manifest requirements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Section 262.54 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Exports of Hazardous Waste § 262.54 Special... certification set forth in Item 16 of the Uniform Hazardous Waste Manifest Form: “and conforms to the terms of...

Minerals and design of new waste forms for conditioning nuclear waste

NASA Astrophysics Data System (ADS)

Montel, Jean-Marc

2011-02-01

Safe storage of radioactive waste is a major challenge for the nuclear industry. Mineralogy is a good basis for designing ceramics, which could eventually replace nuclear glasses. This requires a new storage concept: separation-conditioning. Basic rules of crystal chemistry allow one to select the most suitable structures and natural occurrences allow assessing the long-term performance of ceramics in a geological environment. Three criteria are of special interest: compatibility with geological environment, resistance to natural fluids, and effects of self-irradiation. If mineralogical information is efficient for predicting the behaviour of common, well-known minerals, such as zircon, monazite or apatite, more research is needed to rationalize the long-term behaviour of uncommon waste form analogs.

Colloid formation during waste form reaction: Implications for nuclear waste disposal

USGS Publications Warehouse

Bates, J. K.; Bradley, J.; Teetsov, A.; Bradley, C. R.; Buchholtz ten Brink, Marilyn R.

1992-01-01

Insoluble plutonium- and americium-bearing colloidal particles formed during simulated weathering of a high-level nuclear waste glass. Nearly 100 percent of the total plutonium and americium in test ground water was concentrated in these submicrometer particles. These results indicate that models of actinide mobility and repository integrity, which assume complete solubility of actinides in ground water, underestimate the potential for radionuclide release into the environment. A colloid-trapping mechanism may be necessary for a waste repository to meet long-term performance specifications.

National low-level waste management program radionuclide report series, Volume 15: Uranium-238

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adams, J.P.

1995-09-01

This report, Volume 15 of the National Low-Level Waste Management Program Radionuclide Report Series, discusses the radiological and chemical characteristics of uranium-238 ({sup 238}U). The purpose of the National Low-Level Waste Management Program Radionuclide Report Series is to provide information to state representatives and developers of low-level radioactive waste disposal facilities about the radiological, chemical, and physical characteristics of selected radionuclides and their behavior in the waste disposal facility environment. This report also includes discussions about waste types and forms in which {sup 238}U can be found, and {sup 238}U behavior in the environment and in the human body.

Method and article for primary containment of cesium wastes. [DOE patent application

DOEpatents

Angelini, P.; Lackey, W.J.; Stinton, D.P.; Blanco, R.E.; Bond, W.D.; Arnold, W.D. Jr.

1981-09-03

A method for producing a cesium-retentive waste form, characterized by a high degree of compositional stability and mechanical integrity, is provided by subjecting a cesium-loaded zeolite to heat under conditions suitable for stabilizing the zeolite and immobilizing the cesium, and coating said zeolite for sufficient duration within a suitable environment with at least one dense layer of pyrolytic carbon to seal therein said cesium to produce a final, cesium-bearing waste form. Typically, the zolite is stabilized and the cesium immobilized in less than four hours by confinement within an air environment maintained at about 600/sup 0/C. Coatings are thereafter applied by confining the calcined zeolite within a coating environment comprising inert fluidizing and carbon donor gases maintained at 1000/sup 0/C for a suitable duration.

Method for primary containment of cesium wastes

DOEpatents

Angelini, Peter; Lackey, Walter J.; Stinton, David P.; Blanco, Raymond E.; Bond, Walter D.; Arnold, Jr., Wesley D.

1983-01-01

A method for producing a cesium-retentive waste form, characterized by a high degree of compositional stability and mechanical integrity, is provided by subjecting a cesium-loaded zeolite to heat under conditions suitable for stabilizing the zeolite and immobilizing the cesium, and coating said zeolite for sufficient duration within a suitable environment with at least one dense layer of pyrolytic carbon to seal therein said cesium to produce a final, cesium-bearing waste form. Typically, the zeolite is stabilized and the cesium immobilized in less than four hours by confinement within an air environment maintained at about 600.degree. C. Coatings are thereafter applied by confining the calcined zeolite within a coating environment comprising inert fluidizing and carbon donor gases maintained at 1,000.degree. C. for a suitable duration.

40 CFR 191.12 - Definitions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... TRANSURANIC RADIOACTIVE WASTES Environmental Standards for Disposal § 191.12 Definitions. Unless otherwise... environment. For example, a barrier may be a geologic structure, a canister, a waste form with physical and... over and around waste, provided that the material or structure substantially delays movement of water...

40 CFR 270.60 - Permits by rule.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) EPA ADMINISTERED PERMIT PROGRAMS: THE HAZARDOUS WASTE PERMIT PROGRAM Special Forms of Permits § 270.60 Permits by... operator of a barge or other vessel which accepts hazardous waste for ocean disposal, if the owner or...

40 CFR 270.60 - Permits by rule.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) EPA ADMINISTERED PERMIT PROGRAMS: THE HAZARDOUS WASTE PERMIT PROGRAM Special Forms of Permits § 270.60 Permits by... operator of a barge or other vessel which accepts hazardous waste for ocean disposal, if the owner or...

40 CFR 261.11 - Criteria for listing hazardous waste.

Code of Federal Regulations, 2013 CFR

2013-07-01

... waste identified in subpart C. (2) It has been found to be fatal to humans in low doses or, in the... teratogenic effects on humans or other life forms. (Wastes listed in accordance with these criteria will be... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Criteria for listing hazardous waste...

40 CFR 261.11 - Criteria for listing hazardous waste.

Code of Federal Regulations, 2014 CFR

2014-07-01

... waste identified in subpart C. (2) It has been found to be fatal to humans in low doses or, in the... teratogenic effects on humans or other life forms. (Wastes listed in accordance with these criteria will be... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Criteria for listing hazardous waste...

40 CFR 261.11 - Criteria for listing hazardous waste.

Code of Federal Regulations, 2012 CFR

2012-07-01

... waste identified in subpart C. (2) It has been found to be fatal to humans in low doses or, in the... teratogenic effects on humans or other life forms. (Wastes listed in accordance with these criteria will be... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Criteria for listing hazardous waste...

Diffusion and Leaching Behavior of Radionuclides in Category 3 Waste Encasement Concrete and Soil Fill Material – Summary Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mattigod, Shas V.; Wellman, Dawn M.; Bovaird, Chase C.

2011-08-31

One of the methods being considered for safely disposing of Category 3 low-level radioactive wastes is to encase the waste in concrete. Such concrete encasement would contain and isolate the waste packages from the hydrologic environment and would act as an intrusion barrier. The current plan for waste isolation consists of stacking low-level waste packages on a trench floor, surrounding the stacks with reinforced steel, and encasing these packages in concrete. These concrete-encased waste stacks are expected to vary in size with maximum dimensions of 6.4 m long, 2.7 m wide, and 4 m high. The waste stacks are expectedmore » to have a surrounding minimum thickness of 15 cm of concrete encasement. These concrete-encased waste packages are expected to withstand environmental exposure (solar radiation, temperature variations, and precipitation) until an interim soil cover or permanent closure cover is installed, and to remain largely intact thereafter. Any failure of concrete encasement may result in water intrusion and consequent mobilization of radionuclides from the waste packages. The mobilized radionuclides may escape from the encased concrete by mass flow and/or diffusion and move into the surrounding subsurface environment. Therefore, it is necessary to assess the performance of the concrete encasement structure and the ability of the surrounding soil to retard radionuclide migration. The retardation factors for radionuclides contained in the waste packages can be determined from measurements of diffusion coefficients for these contaminants through concrete and fill material. Some of the mobilization scenarios include (1) potential leaching of waste form before permanent closure cover is installed; (2) after the cover installation, long-term diffusion of radionuclides from concrete waste form into surrounding fill material; (3) diffusion of radionuclides from contaminated soils into adjoining concrete encasement and clean fill material. Additionally, the rate of diffusion of radionuclides may be affected by the formation of structural cracks in concrete, the carbonation of the buried waste form, and any potential effect of metallic iron (in the form of rebars) on the mobility of radionuclides. The radionuclides iodine-129 ({sup 129}I), technetium-99 ({sup 99}Tc), and uranium-238 ({sup 238}U) are identified as long-term dose contributors in Category 3 waste (Mann et al. 2001; Wood et al. 1995). Because of their anionic nature in aqueous solutions, {sup 129}I, {sup 99}Tc, and carbonate-complexed {sup 238}U may readily leach into the subsurface environment (Serne et al. 1989, 1992a, b, 1993, and 1995). The leachability and/or diffusion of radionuclide species must be measured to assess the long-term performance of waste grouts when contacted with vadose-zone pore water or groundwater. Although significant research has been conducted on the design and performance of cementitious waste forms, the current protocol conducted to assess radionuclide stability within these waste forms has been limited to the Toxicity Characteristic Leaching Procedure, Method 1311 Federal Registry (EPA 1992) and ANSI/ANS-16.1 leach test (ANSI 1986). These tests evaluate the performance under water-saturated conditions and do not evaluate the performance of cementitious waste forms within the context of waste repositories which are located within water-deficient vadose zones. Moreover, these tests assess only the diffusion of radionuclides from concrete waste forms and neglect evaluating the mechanisms of retention, stability of the waste form, and formation of secondary phases during weathering, which may serve as long-term secondary hosts for immobilization of radionuclides. The results of recent investigations conducted under arid and semi-arid conditions (Al-Khayat et al. 2002; Garrabrants et al. 2002; Garrabrants and Kosson 2003; Garrabrants et al. 2004; Gervais et al. 2004; Sanchez et al. 2002; Sanchez et al. 2003) provide valuable information suggesting structural and chemical changes to concrete waste forms which may affect contaminant containment and waste form performance. However, continued research is necessitated by the need to understand: the mechanism of contaminant release; the significance of contaminant release pathways; how waste form performance is affected by the full range of environmental conditions within the disposal facility; the process of waste form aging under conditions that are representative of processes occurring in response to changing environmental conditions within the disposal facility; the effect of waste form aging on chemical, physical, and radiological properties, and the associated impact on contaminant release. Recent reviews conducted by the National Academies of Science recognized the efficacy of cementitious materials for waste isolation, but further noted the significant shortcomings in our current understanding and testing protocol for evaluating the performance of various formulations.« less

40 CFR 761.205 - Notification of PCB waste activity (EPA Form 7710-53).

Code of Federal Regulations, 2011 CFR

2011-07-01

... (CONTINUED) TOXIC SUBSTANCES CONTROL ACT POLYCHLORINATED BIPHENYLS (PCBs) MANUFACTURING, PROCESSING, DISTRIBUTION IN COMMERCE, AND USE PROHIBITIONS PCB Waste Disposal Records and Reports § 761.205 Notification of... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Notification of PCB waste activity...

40 CFR 761.205 - Notification of PCB waste activity (EPA Form 7710-53).

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) TOXIC SUBSTANCES CONTROL ACT POLYCHLORINATED BIPHENYLS (PCBs) MANUFACTURING, PROCESSING, DISTRIBUTION IN COMMERCE, AND USE PROHIBITIONS PCB Waste Disposal Records and Reports § 761.205 Notification of... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Notification of PCB waste activity...

40 CFR 761.205 - Notification of PCB waste activity (EPA Form 7710-53).

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) TOXIC SUBSTANCES CONTROL ACT POLYCHLORINATED BIPHENYLS (PCBs) MANUFACTURING, PROCESSING, DISTRIBUTION IN COMMERCE, AND USE PROHIBITIONS PCB Waste Disposal Records and Reports § 761.205 Notification of... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Notification of PCB waste activity...

40 CFR 761.205 - Notification of PCB waste activity (EPA Form 7710-53).

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) TOXIC SUBSTANCES CONTROL ACT POLYCHLORINATED BIPHENYLS (PCBs) MANUFACTURING, PROCESSING, DISTRIBUTION IN COMMERCE, AND USE PROHIBITIONS PCB Waste Disposal Records and Reports § 761.205 Notification of... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Notification of PCB waste activity...

High-Level Waste System Process Interface Description

DOE Office of Scientific and Technical Information (OSTI.GOV)

d'Entremont, P.D.

1999-01-14

The High-Level Waste System is a set of six different processes interconnected by pipelines. These processes function as one large treatment plant that receives, stores, and treats high-level wastes from various generators at SRS and converts them into forms suitable for final disposal. The three major forms are borosilicate glass, which will be eventually disposed of in a Federal Repository, Saltstone to be buried on site, and treated water effluent that is released to the environment.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Dunn, Darrell; Poinssot, Christophe; Begg, Bruce

Management of nuclear waste remains an important international topic that includes reprocessing of commercial nuclear fuel, waste-form design and development, storage and disposal packaging, the process of repository site selection, system design, and performance assessment. Requirements to manage and dispose of materials from the production of nuclear weapons, and the renewed interest in nuclear power, in particular through the Generation IV Forum and the Advanced Fuel Cycle Initiative, can be expected to increase the need for scientific advances in waste management. A broad range of scientific and engineering disciplines is necessary to provide safe and effective solutions and address complexmore » issues. This volume offers an interdisciplinary perspective on materials-related issues associated with nuclear waste management programs. Invited and contributed papers cover a wide range of topics including studies on: spent fuel; performance assessment and models; waste forms for low- and intermediate-level waste; ceramic and glass waste forms for plutonium and high-level waste; radionuclides; containers and engineered barriers; disposal environments and site characteristics; and partitioning and transmutation.« less

The factors that have correlation with student behavior to dispose liquid waste

NASA Astrophysics Data System (ADS)

Kusmawaningtyas, Rieneke; Darmajanti, Linda; Soesilo, Tri Edhi Budhi

2017-03-01

Students majoring in chemistry could produce toxic liquid waste in their laboratory practices. They are not allowed to dispose of hazardous laboratory liquid into the environment. The formulation of problem in this study is that not all students have good behavior to dispose liquid waste properly according to their type and chemical properties while it is expected that all students have good behavior to dispose liquid waste with the type and chemical properties in container vessel, even though all students are expected to have behavior to dispose waste in the container vessel with the support of the predisposing factors, enabling factors, and driving factors. The aim of this study is to analyze the type and chemical properties of liquid waste and the relationship between three factors forming behavior with student behavior. The relationship between three factors forming behavior with student behavior was analyzed by correlative analysis. Type and chemical properties known through observation and qualitative analysis. The results of this research is found that enabling factors and driving behavior have a weak relation with student behavior. Nevertheless, predisposing factors has no relation with student behavior. The result of analysis of waste laboratory are known that laboratory liquid waste contains Cu, Fe, and methylene blue which potentially pollute the environment. The findings show that although generally the laboratory use chemicals in small quantities, but the total quantity of laboratory liquid waste produced from all laboratories in some regions must be considered. Moreover, the impact of the big quantity of liquid waste to environment must be taken into account. Thus, it is recommended that students should raise awareness of the risks associated with laboratory liquid waste and, we should provide proper management for a laboratory and policy makers.

Supplemental Immobilization of Hanford Low-Activity Waste: Cast Stone Screening Tests

DOE Office of Scientific and Technical Information (OSTI.GOV)

Westsik, Joseph H.; Piepel, Gregory F.; Lindberg, Michael J.

2013-09-30

More than 56 million gallons of radioactive and hazardous waste are stored in 177 underground storage tanks at the U.S. Department of Energy’s (DOE’s) Hanford Site in southeastern Washington State. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is being constructed to treat the wastes and immobilize them in a glass waste form. The WTP includes a pretreatment facility to separate the wastes into a small volume of high-level waste (HLW) containing most of the radioactivity and a larger volume of low-activity waste (LAW) containing most of the nonradioactive chemicals. The HLW will be converted to glass in themore » HLW vitrification facility for ultimate disposal at an offsite federal repository. At least a portion (~35%) of the LAW will be converted to glass in the LAW vitrification facility and will be disposed of onsite at the Integrated Disposal Facility (IDF). The pretreatment and HLW vitrification facilities will have the capacity to treat and immobilize the wastes destined for each facility. However, a second LAW immobilization facility will be needed for the expected volume of LAW requiring immobilization. A cementitious waste form known as Cast Stone is being considered to provide the required additional LAW immobilization capacity. The Cast Stone waste form must be acceptable for disposal in the IDF. The Cast Stone waste form and immobilization process must be tested to demonstrate that the final Cast Stone waste form can comply with the waste acceptance criteria for the disposal facility and that the immobilization processes can be controlled to consistently provide an acceptable waste form product. Further, the waste form must be tested to provide the technical basis for understanding the long-term performance of the waste form in the disposal environment. These waste form performance data are needed to support risk assessment and performance assessment (PA) analyses of the long-term environmental impact of the waste disposal in the IDF. The PA is needed to satisfy both Washington State IDF Permit and DOE Order requirements. Cast Stone has been selected for solidification of radioactive wastes including WTP aqueous secondary wastes treated at the Effluent Treatment Facility (ETF) at Hanford. A similar waste form called Saltstone is used at the Savannah River Site (SRS) to solidify its LAW tank wastes.« less

Mobilization of radionuclides from uranium mill tailings and related waste materials in anaerobic environments

USGS Publications Warehouse

Landa, E.R.

2003-01-01

Specific extraction studies in our laboratory have shown that iron and manganese oxide- and alkaline earth sulfate minerals are important hosts of radium in uranium mill tailings. Iron- and sulfate-reducing bacteria may enhance the release of radium (and its analog barium) from uranium mill tailings, oil field pipe scale [a major technologically enhanced naturally occurring radioactive material (TENORM) waste], and jarosite (a common mineral in sulfuric acid processed-tailings). These research findings are reviewed and discussed in the context of nuclear waste forms (such as barium sulfate matrices), radioactive waste management practices, and geochemical environments in the Earth's surficial and shallow subsurface regions.

Productivity improvement with green approach to palm oil factory productivity

NASA Astrophysics Data System (ADS)

Matondang, N.

2018-02-01

The palm oil factory (POF) processes fresh fruit bunches into crude palm oil (CPO) and palm kernel oil (PKO) by products in the form of liquid and solid waste. One of the solid wastes produced in POF Tanjung Kasau is empty fruit bunches of palm oil (FBPO) which have been burned completely on incinerator tubes so that potentially produces pollutants that pollute the environment. If FBPO waste is managed properly, it will improve the productivity of the company. Therefore, it is necessary to conduct a study to find out how far the increased productivity of the company can reduce their impact on the environment, if FBPO is used as raw material of liquid smoke. The productivity improvement approach is done by Green Productivity concept, by looking at three aspects: environmental, social and economical. Green Productivity aims to protect the environment simultaneously by increasing the productivity of the company. One way is to turn FBPO waste into liquid smoke product is by pyrolysis process. The results showed that turning FBPO solid waste into liquid smoke will increase productivity by 18.18%. Implementation of Green Productivity can improve productivity through the improvement of FBPO waste treatment process which has been done by perfect combustion by pyrolysis process so that waste can be minimized to create environment industry POF clean and friendly environment.

Finite element analysis of ion transport in solid state nuclear waste form materials

NASA Astrophysics Data System (ADS)

Rabbi, F.; Brinkman, K.; Amoroso, J.; Reifsnider, K.

2017-09-01

Release of nuclear species from spent fuel ceramic waste form storage depends on the individual constituent properties as well as their internal morphology, heterogeneity and boundary conditions. Predicting the release rate is essential for designing a ceramic waste form, which is capable of effectively storing the spent fuel without contaminating the surrounding environment for a longer period of time. To predict the release rate, in the present work a conformal finite element model is developed based on the Nernst Planck Equation. The equation describes charged species transport through different media by convection, diffusion, or migration. And the transport can be driven by chemical/electrical potentials or velocity fields. The model calculates species flux in the waste form with different diffusion coefficient for each species in each constituent phase. In the work reported, a 2D approach is taken to investigate the contributions of different basic parameters in a waste form design, i.e., volume fraction, phase dispersion, phase surface area variation, phase diffusion co-efficient, boundary concentration etc. The analytical approach with preliminary results is discussed. The method is postulated to be a foundation for conformal analysis based design of heterogeneous waste form materials.

Removal of radioactive contaminants by polymeric microspheres.

PubMed

Osmanlioglu, Ahmet Erdal

2016-11-01

Radionuclide removal from radioactive liquid waste by adsorption on polymeric microspheres is the latest application of polymers in waste management. Polymeric microspheres have significant immobilization capacity for ionic substances. A laboratory study was carried out by using poly(N-isopropylacrylamide) for encapsulation of radionuclide in the liquid radioactive waste. There are numbers of advantages to use an encapsulation technology in radioactive waste management. Results show that polymerization step of radionuclide increases integrity of solidified waste form. Test results showed that adding the appropriate polymer into the liquid waste at an appropriate pH and temperature level, radionuclide was encapsulated into polymer. This technology may provide barriers between hazardous radioactive ions and the environment. By this method, solidification techniques became easier and safer in nuclear waste management. By using polymer microspheres as dust form, contamination risks were decreased in the nuclear industry and radioactive waste operations.

WastePD, an innovative center on materials degradation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Frankel, Gerald S.; Vienna, John; Lian, Jie

The US Department of Energy recently awarded funds to create the Center for Performance and Design of Nuclear Waste Forms and Containers (WastePD) as part of the Energy Frontier Research Center (EFRC) program. EFRCs are multi-investigator collaborations of universities, national labs and companies that “conduct fundamental research focusing on one or more “grand challenges” and use-inspired “basic research needs” identified in major strategic planning efforts by the scientific community.” The major performance parameter of nuclear waste forms is their ability to isolate the radionuclides by withstanding degradation in a repository environment over very long periods of time. So WastePD ismore » at heart a center focused on materials degradation.« less

National low-level waste management program radionuclide report series, Volume 14: Americium-241

DOE Office of Scientific and Technical Information (OSTI.GOV)

Winberg, M.R.; Garcia, R.S.

1995-09-01

This report, Volume 14 of the National Low-Level Waste Management Program Radionuclide Report Series, discusses the radiological and chemical characteristics of americium-241 ({sup 241}Am). This report also includes discussions about waste types and forms in which {sup 241}Am can be found and {sup 241}Am behavior in the environment and in the human body.

Characteristics and biological treatment of leachates from a domestic landfill

USDA-ARS?s Scientific Manuscript database

Waste material from urban areas is a major environmental concern and landfill application is a frequent method for waste disposal. The leachate from landfills can, however, negatively affect the surrounding environment. A bioreactor cascade containing submerged biofilms was used to treat newly forme...

Performance and modeling of cesium ion exchange by ENGI neered form crystalline silicotitanates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Anthony, R.G.; Gu, D.; Huckman, M.

1996-10-01

TAM-5, a hydrous crystalline silicotitanate (CST) powder developed by Sandia National Laboratories and Texas A&M University, and commercialized by UOP as IONSIV{reg_sign} Ion Exchanger Type IE-910, is a highly selective material for removing cesium and strontium from aqueous radioactive wastes such as those found at the Hanford site in Washington. An engineered form of the material suitable for column ion exchange type operations has been developed and tested. Data relevant to processing radioactive tank wastes including equilibrium distribution coefficients and column testing will be presented. The impact of exposure of the engineered form to chemically aggressive environments such as itmore » might experience during waste processing, and to the less aggressive environments it might experience during post processing storage has been assessed. The thermal stability of the material has also been evaluated. The experimental results have been integrated with an effort to model the material`s equilibrium and kinetic behavior.« less

The impact of incinerators on human health and environment.

PubMed

Sharma, Raman; Sharma, Meenakshi; Sharma, Ratika; Sharma, Vivek

2013-01-01

Of the total wastes generated by health-care organizations, 10%-25% are biomedical wastes, which are hazardous to humans and the environment and requires specific treatment and management. For decades, incineration was the method of choice for the treatment of such infectious wastes. Incinerator releases a wide variety of pollutants depending on the composition of the waste, which leads to health deterioration and environmental degradation. The significant pollutants emitted are particulate matter, metals, acid gases, oxides of nitrogen, and sulfur, aside from the release of innumerable substances of unknown toxicity. This process of waste incineration poses a significant threat to public health and the environment. The major impact on health is the higher incidence of cancer and respiratory symptoms; other potential effects are congenital abnormalities, hormonal defects, and increase in sex ratio. The effect on the environmental is in the form of global warming, acidification, photochemical ozone or smog formation, eutrophication, and human and animal toxicity. Thus, there is a need to skip to newer, widely accepted, economical, and environment-friendly technologies. The use of hydroclaves and plasma pyrolysis for the incineration of biomedical wastes leads to lesser environmental degradation, negligible health impacts, safe handling of treated wastes, lesser running and maintenance costs, more effective reduction of microorganisms, and safer disposal.

A novel one-step synthesis for carbon-based nanomaterials from polyethylene terephthalate (PET) bottles waste.

PubMed

El Essawy, Noha A; Konsowa, Abdelaziz H; Elnouby, Mohamed; Farag, Hassan A

2017-03-01

Nowadays our planet suffers from an accumulation of plastic products that have the potential to cause great harm to the environment in the form of air, water, and land pollution. Plastic water bottles have become a great problem in the environment because of the large numbers consumed throughout the world. Certain types of plastic bottles can be recycled but most of them are not. This paper describes an economical solvent-free process that converts polyethylene terephthalate (PET) bottles waste into carbon nanostructure materials via thermal dissociation in a closed system under autogenic pressure together with additives and/or catalyst, which can act as cluster nuclei for carbon nanostructure materials such as fullerenes and carbon nanotubes. This research succeeded in producing and controlling the microstructure of various forms of carbon nanoparticles from the PET waste by optimizing the preparation parameters in terms of time, additives, and amounts of catalyst. Plastic water bottles are becoming a growing segment of the municipal solid waste stream in the world; some are recycled but many are left in landfill sites. Recycling PET bottles waste can positively impact the environment in several ways: for instance, reduced waste, resource conservation, energy conservation, reduced greenhouse gas emissions, and decreasing the amount of pollution in air and water sources. The main novelty of the present work is based on the acquisition of high-value carbon-based nanomaterials from PET waste by a simple solvent-free chemical technique. Thus, the prepared materials are considered to be promising, cheap, eco-friendly materials that may find use in different applications.

Processing of basalt fiber production waste

NASA Astrophysics Data System (ADS)

Sevostyanov, V. S.; Shatalov, A. V.; Shatalov, V. A.; Golubeva, U. V.

2018-03-01

The production of mineral rock wool forms a large proportion of off-test waste products. In addition to the cost of their production, there are costs for processing and utilization, such as transportation, disposal and preservation. Besides, wastes have harmful effect on the environment. This necessitates research aimed to study the stress-related characteristics of materials, their recyclability and use in the production of heat-saving products.

CEM V based special cementitious materials investigated by means of SANS method. Preliminary results

NASA Astrophysics Data System (ADS)

Dragolici, A. C.; Balasoiu, M.; Orelovich, O. L.; Ionascu, L.; Nicu, M.; Soloviov, D. V.; Kuklin, A. I.; Lizunov, E. I.; Dragolici, F.

2017-05-01

The management of the radioactive waste assume the conditioning in a cement matrix as an embedding, stable, disposal material. Cement matrix is the first and most important engineering barrier against the migration in the environment of the radionuclides contained in the waste packages. Knowing how the microstructure develops is therefore desirable in order to assess the compatibility of radioactive streams with cement and predict waste form performance during storage and disposal. For conditioning wastes containing radioactive aluminum new formulas of low basicity cements, using coatings as a barrier between the metal and the conditioning environment or introducing a corrosion inhibitor in the matrix system are required. Preliminary microstructure investigation of such improved CEM V based cement matrix is reported.

40 CFR Appendix I to Part 261 - Representative Sampling Methods

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Representative Sampling Methods I...—Representative Sampling Methods The methods and equipment used for sampling waste materials will vary with the form and consistency of the waste materials to be sampled. Samples collected using the sampling...

40 CFR Appendix I to Part 261 - Representative Sampling Methods

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Representative Sampling Methods I...—Representative Sampling Methods The methods and equipment used for sampling waste materials will vary with the form and consistency of the waste materials to be sampled. Samples collected using the sampling...

Assessment of remote sensing technologies to discover and characterize waste sites

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1992-03-11

This report presents details about waste management practices that are being developed using remote sensing techniques to characterize DOE waste sites. Once the sites and problems have been located and characterized and an achievable restoration and remediation program have been established, efforts to reclaim the environment will begin. Special problems to be considered are: concentrated waste forms in tanks and pits; soil and ground water contamination; ground safety hazards for workers; and requirement for long-term monitoring.

Initial results of metal waste form development activities at ANL-West

DOE Office of Scientific and Technical Information (OSTI.GOV)

Keiser, D.D. Jr.; Westphal, B.R.; Hersbt, R.S.

1997-10-01

Argonne National Laboratory is developing a metal alloy to contain metallic waste constituents from the electrometallurgical treatment of spent nuclear fuel. This alloy will contain stainless steel (from stainless steel-clad fuel elements), {approximately}15 wt.% zirconium (from alloy fuel), fission products noble to the process (e.g., Ru, Pd, Tc, etc.), and minor amounts of actinides. The alloy will serve as a final waste form for these components and will be disposed of in a geologic repository. The alloy ingot is produced in an induction furnace situated in a hot cell using Ar cover gas. This paper discusses results from the meltingmore » campaigns that have been initiated at ANL-West to generate the metal waste form using actual process materials. In addition, metal waste form samples have been doped with Tc and selected actinides and are described in the context of how elements of interest partition between various phases in the alloy and how this distribution of elements in the alloy may affect the leaching behavior of the components in an aqueous environment. 3 refs.« less

Initial results of metal waste-form development activities at ANL-West

DOE Office of Scientific and Technical Information (OSTI.GOV)

Keiser, D.D. Jr.; Westphal, B.R.; Herbst, R.S.

1997-12-01

Argonne National Laboratory (ANL) is developing a metal alloy to contain metallic waste constituent residual from the electrometallurgical treatment of spent nuclear fuel. This alloy will contain stainless steel (from stainless steel-clad fuel elements), {approximately} 15 wt% zirconium (from alloy fuel), fission products noble to the process (e.g., ruthenium, palladium, technetium, etc.), and minor amounts of actinides. The alloy will serve as a final waste form for these components and will be disposed of in a geologic repository. The alloy ingot is produced in an induction furnace situated in a hot cell using argon cover gas. This paper discusses resultsmore » from the melting campaigns that have been initiated at ANL-West to generate the metal waste form using actual process materials. In addition, metal waste form samples have been doped with technetium and selected actinides and are described in the context of how elements of interest partition between various phases in the alloy and how this distribution of elements in the alloy may affect the leaching behavior of the components in an aqueous environment.« less

Unirradiated testing of the demonstration-scale ceramic waste form at ANL-West

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goff, K.M.; Simpson, M.F.; Bateman, K.J.

1997-12-01

The ceramic waste form is being developed by Argonne National Laboratory (ANL) as part of the demonstration of the electrometallurgical treatment of spent nuclear fuel for disposal. The alkali, alkaline earth, halide, and rare earth fission products are stabilized in zeolite, which is combined with glass and processed in a hot isostatic press (HIP) to form a ceramic composite. The transuranics, including plutonium, are also stabilized in this high-level waste. Most of the laboratory-scale development work is performed in the Chemical Technology Division of ANL in Illinois. At ANL-West in Idaho, this technology is being demonstrated on an engineering scalemore » before implementation with irradiated materials in a remote environment.« less

Extractive waste management: A risk analysis approach.

PubMed

Mehta, Neha; Dino, Giovanna Antonella; Ajmone-Marsan, Franco; Lasagna, Manuela; Romè, Chiara; De Luca, Domenico Antonio

2018-05-01

Abandoned mine sites continue to present serious environmental hazards because the heavy metals associated with extractive waste are continuously released into the environment, where they threaten human life and the environment. Remediating and securing extractive waste are complex, lengthy and costly processes. Thus, in most European countries, a site is considered for intervention when it poses a risk to human health and the surrounding environment. As a consequence, risk analysis presents a viable decisional approach towards the management of extractive waste. To evaluate the effects posed by extractive waste to human health and groundwater, a risk analysis approach was used for an abandoned nickel extraction site in Campello Monti in North Italy. This site is located in the Southern Italian Alps. The area consists of large and voluminous mafic rocks intruded by mantle peridotite. The mining activities in this area have generated extractive waste. A risk analysis of the site was performed using Risk Based Corrective Action (RBCA) guidelines, considering the properties of extractive waste and water for the properties of environmental matrices. The results showed the presence of carcinogenic risk due to arsenic and risks to groundwater due to nickel. The results of the risk analysis form a basic understanding of the current situation at the site, which is affected by extractive waste. Copyright © 2017 Elsevier B.V. All rights reserved.

Infectious waste management in Japan: A revised regulation and a management process in medical institutions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Miyazaki, M.; Une, H.

In Japan, the waste management practice is carried out in accordance with the Waste Disposal Law of 1970. The first rule of infectious waste management was regulated in 1992, and infectious wastes are defined as the waste materials generated in medical institutions as a result of medical care or research which contain pathogens that have the potential to transmit infectious diseases. Revised criteria for infectious waste management were promulgated by the Ministry of Environment in 2004. Infectious waste materials are divided into three categories: the form of waste; the place of waste generation; the kind of infectious diseases. A reductionmore » of infectious waste is expected. We introduce a summary of the revised regulation of infectious waste management in this article.« less

Corrosion mechanisms for metal alloy waste forms: experiment and theory Level 4 Milestone M4FT-14LA0804024 Fuel Cycle Research & Development

DOE Office of Scientific and Technical Information (OSTI.GOV)

Liu, Xiang-Yang; Taylor, Christopher D.; Kim, Eunja

2014-07-31

This document meets Level 4 Milestone: Corrosion mechanisms for metal alloy waste forms - experiment and theory. A multiphysics model is introduces that will provide the framework for the quantitative prediction of corrosion rates of metallic waste forms incorporating the fission product Tc. The model requires a knowledge of the properties of not only the metallic waste form, but also the passive oxide films that will be generated on the waste form, and the chemistry of the metal/oxide and oxide/environment interfaces. in collaboration with experimental work, the focus of this work is on obtaining these properties from fundamental atomistic models.more » herein we describe the overall multiphysics model, which is based on MacDonald's point-defect model for passivity. We then present the results of detailed electronic-structure calculations for the determination of the compatibility and properties of Tc when incorporated into intermetallic oxide phases. This work is relevant to the formation of multi-component oxides on metal surfaces that will incorporate Tc, and provide a kinetic barrier to corrosion (i.e. the release of Tc to the environment). Atomistic models that build upon the electronic structure calculations are then described using the modified embedded atom method to simulate metallic dissolution, and Buckingham potentials to perform classical molecular dynamics and statics simulations of the technetium (and, later, iron-technetium) oxide phases. Electrochemical methods were then applied to provide some benchmark information of the corrosion and electrochemical properties of Technetium metal. The results indicate that published information on Tc passivity is not complete and that further investigation is warranted.« less

Mercury stabilization in chemically bonded phosphate ceramics

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wagh, Arun S.; Jeong, Seung-Young; Singh, Dileep

1997-07-01

We have investigated mercury stabilization in chemically bonded phosphate ceramic (CBPC) using four surrogate waste streams that represent U.S. Department of Energy (DOE) ash, soil, and two secondary waste streams resulting from the destruction of DOE`s high-organic wastes by the DETOX{sup SM} Wet Oxidation Process. Hg content in the waste streams was 0.1 to 0.5 wt.% (added as soluble salts). Sulfidation of Hg and its concurrent stabilization in the CBPC matrix yielded highly nonleachable waste forms. The Toxicity Characteristic Leaching Procedure showed that leaching levels were well below the U.S. Environmental Protection Agency`s regulatory limits. The American Nuclear Society`s ANSmore » 16.1 immersion test also gave very high leaching indices, indicating excellent retention of the contaminants. In particular, leaching levels of Hg in the ash waste form were below the measurement detection limit in neutral and alkaline water, negligibly low but measureable in the first 72 h of leaching in acid water, and below the detection limit after that. These studies indicate that the waste forms are stable in a wide range of chemical environments during storage. 9 refs., 5 tabs.« less

Transport and transportation pathways of hazardous chemicals from solid waste disposal.

PubMed Central

Van Hook, R I

1978-01-01

To evaluate the impact of hazardous chemicals in solid wastes on man and other organisms, it is necessary to have information about amounts of chemical present, extent of exposure, and chemical toxicity. This paper addresses the question of organism exposure by considering the major physical and biological transport pathways and the physicochemical and biochemical transformations that may occur in sediments, soils, and water. Disposal of solid wastes in both terrestrial and oceanic environments is considered. Atmospheric transport is considered for emissions from incineration of solid wastes and for wind resuspension of particulates from surface waste deposits. Solid wastes deposited in terrestrial environments are subject to leaching by surface and ground waters. Leachates may then be transported to other surface waters and drinking water aquifers through hydrologic transport. Leachates also interact with natural organic matter, clays, and microorganisms in soils and sediments. These interactions may render chemical constituents in leachates more or less mobile, possibly change chemical and physical forms, and alter their biological activity. Oceanic waste disposal practices result in migration through diffusion and ocean currents. Surface area-to-volume ratios play a major role in the initial distributions of chemicals in the aquatic environment. Sediments serve as major sources and sinks of chemical contaminants. Food chain transport in both aquatic and terrestrial environments results in the movement of hazardous chemicals from lower to higher positions in the food web. Bioconcentration is observed in both terrestrial and aquatic food chains with certain elements and synthetic organics. Bioconcentration factors tend to be higher for synthetic organics, and higher in aquatic than in terrestrial systems. Biodilution is not atypical in terrestrial environments. Synergistic and antagonistic actions are common occurrences among chemical contaminants and can be particularly important toxicity considerations in aquatic environments receiving runoff from several terrestrial sources. PMID:367772

Microbial fouling and corrosion of carbon steel in deep anoxic alkaline groundwater.

PubMed

Rajala, Pauliina; Bomberg, Malin; Vepsäläinen, Mikko; Carpén, Leena

2017-02-01

Understanding the corrosion of carbon steel materials of low and intermediate level radioactive waste under repository conditions is crucial to ensure the safe storage of radioactive contaminated materials. The waste will be in contact with the concrete of repository silos and storage containers, and eventually with groundwater. In this study, the corrosion of carbon steel under repository conditions as well as the microbial community forming biofilm on the carbon steel samples, consisting of bacteria, archaea, and fungi, was studied over a period of three years in a groundwater environment with and without inserted concrete. The number of biofilm forming bacteria and archaea was 1,000-fold lower, with corrosion rates 620-times lower in the presence of concrete compared to the natural groundwater environment. However, localized corrosion was detected in the concrete-groundwater environment indicating the presence of local microenvironments where the conditions for pitting corrosion were favorable.

Westmorland-Albert Solid Waste Corporation annual report, 1997 (in English;French)

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1998-12-31

Formed under the Clean Environment Act the Corporation has been involved in landfill sites and in recycling and composting programs in New Brunswick. This report includes the Chairman`s summary of issues and accomplishment over the past year, followed by a list of WASWC members. The largest part of the document is composed of financial statements. Statistics provided in appendices covers solid waste received from each municipality by waste category (residential / commercial or industrial / commercial / institutional).

Scenario for the safety assessment of near surface radioactive waste disposal in Serpong, Indonesia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Purnomo, A.S.

2007-07-01

Near surface disposal has been practiced for some decades, with a wide variation in sites, types and amounts of wastes, and facility designs employed. Experience has shown that the effective and safe isolation of waste depends on the performance of the overall disposal system, which is formed by three major components or barriers: the site, the disposal facility and the waste form. The objective of radioactive waste disposal is to isolate waste so that it does not result in undue radiation exposure to humans and the environment. In near surface disposal, the disposal facility is located on or below themore » ground surface, where the protective covering is generally a few meters thick. These facilities are intended to contain low and intermediate level waste without appreciable quantities of long-lived radionuclides. Safety is the most important aspect in the applications of nuclear technology and the implementation of nuclear activities in Indonesia. This aspect is reflected by a statement in the Act Number 10 Year 1997, that 'The Development and use of nuclear energy in Indonesia has to be carried out in such away to assure the safety and health of workers, the public and the protection of the environment'. Serpong are one of the sites for a nuclear research center facility, it is the biggest one in Indonesia. In the future will be developed the first near surface disposal on site of the nuclear research facility in Serpong. The paper will mainly focus on scenario of the safety assessments of near-surface radioactive waste disposal is often important to evaluate the performance of the disposal system (disposal facility, geosphere and biosphere). It will give detail, how at the present and future conditions, including anticipated and less probable events in order to prevent radionuclide migration to human and environment. Refer to the geology characteristic and ground water table is enable to place something Near Surface Disposal on unsaturated zone in Serpong site. (authors)« less

INEEL Subregional Conceptual Model Report Volume 3: Summary of Existing Knowledge of Natural and Anthropogenic Influences on the Release of Contaminants to the Subsurface Environment from Waste Source Terms at the INEEL

DOE Office of Scientific and Technical Information (OSTI.GOV)

Paul L. Wichlacz

2003-09-01

This source-term summary document is intended to describe the current understanding of contaminant source terms and the conceptual model for potential source-term release to the environment at the Idaho National Engineering and Environmental Laboratory (INEEL), as presented in published INEEL reports. The document presents a generalized conceptual model of the sources of contamination and describes the general categories of source terms, primary waste forms, and factors that affect the release of contaminants from the waste form into the vadose zone and Snake River Plain Aquifer. Where the information has previously been published and is readily available, summaries of the inventorymore » of contaminants are also included. Uncertainties that affect the estimation of the source term release are also discussed where they have been identified by the Source Term Technical Advisory Group. Areas in which additional information are needed (i.e., research needs) are also identified.« less

Letter Report: LAW Simulant Development for Cast Stone Screening Test

DOE Office of Scientific and Technical Information (OSTI.GOV)

Russell, Renee L.; Westsik, Joseph H.; Swanberg, David J.

2013-03-27

More than 56 million gallons of radioactive and hazardous waste are stored in 177 underground storage tanks at the U.S. Department of Energy’s (DOE’s) Hanford Site in southeastern Washington State. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is being constructed to treat the wastes and immobilize them in a glass waste form. The WTP includes a pretreatment facility to separate the wastes into a small volume of high-level waste (HLW) containing most of the radioactivity and a larger volume of low-activity waste (LAW) containing most of the nonradioactive chemicals. The HLW will be converted to glass in themore » HLW vitrification facility for ultimate disposal at an offsite federal repository. At least a portion (~35%) of the LAW will be converted to glass in the LAW vitrification facility and will be disposed of onsite at the Integrated Disposal Facility (IDF). The pretreatment and HLW vitrification facilities will have the capacity to treat and immobilize the wastes destined for each facility. However, a second facility will be needed for the expected volume of additional LAW requiring immobilization. A cementitious waste form known as Cast Stone is being considered to provide the required additional LAW immobilization capacity. The Cast Stone waste form must be acceptable for disposal in the IDF. The Cast Stone waste form and immobilization process must be tested to demonstrate that the final Cast Stone waste form can comply with waste acceptance criteria for the IDF disposal facility and that the immobilization processes can be controlled to consistently provide an acceptable waste form product. Further, the waste form must be tested to provide the technical basis for understanding the long term performance of the waste form in the IDF disposal environment. These waste form performance data are needed to support risk assessment and performance assessment (PA) analyses of the long-term environmental impact of the waste disposal in the IDF. A testing program was developed in fiscal year (FY) 2012 describing in some detail the work needed to develop and qualify Cast Stone as a waste form for the solidification of Hanford LAW (Westsik et al. 2012). Included within Westsik et al. (2012) is a section on the near-term needs to address Tri-Party Agreement Milestone M-062-40ZZ. The objectives of the testing program to be conducted in FY 2013 and FY 2014 are to: • Determine an acceptable formulation for the LAW Cast Stone waste form. • Evaluate sources of dry materials for preparing the LAW Cast Stone. • Demonstrate the robustness of the Cast Stone waste form for a range of LAW compositions. • Demonstrate the robustness of the formulation for variability in the Cast Stone process. • Provide Cast Stone contaminant release data for PA and risk assessment evaluations. The first step in determining an acceptable formulation for the LAW Cast Stone waste form is to conduct screening tests to examine expected ranges in pretreated LAW composition, waste stream concentrations, dry-materials sources, and mix ratios of waste feed to dry blend. A statistically designed test matrix will be used to evaluate the effects of these key parameters on the properties of the Cast Stone as it is initially prepared and after curing. The second phase of testing will focus on selection of a baseline Cast Stone formulation for LAW and demonstrating that Cast Stone can meet expected waste form requirements for disposal in the IDF. It is expected that this testing will use the results of the screening tests to define a smaller suite of tests to refine the composition of the baseline Cast Stone formulation (e.g. waste concentration, water to dry mix ratio, waste loading).« less

Reactor-based management of used nuclear fuel: assessment of major options.

PubMed

Finck, Phillip J; Wigeland, Roald A; Hill, Robert N

2011-01-01

This paper discusses the current status of the ongoing Advanced Fuel Cycle Initiative (AFCI) program in the U.S. Department of Energy that is investigating the potential for using the processing and recycling of used nuclear fuel to improve radioactive waste management, including used fuel. A key element of the strategies is to use nuclear reactors for further irradiation of recovered chemical elements to transmute certain long-lived highly-radioactive isotopes into less hazardous isotopes. Both thermal and fast neutron spectrum reactors are being studied as part of integrated nuclear energy systems where separations, transmutation, and disposal are considered. Radiotoxicity is being used as one of the metrics for estimating the hazard of used fuel and the processing of wastes resulting from separations and recycle-fuel fabrication. Decay heat from the used fuel and/or wastes destined for disposal is used as a metric for use of a geologic repository. Results to date indicate that the most promising options appear to be those using fast reactors in a repeated recycle mode to limit buildup of higher actinides, since the transuranic elements are a key contributor to the radiotoxicity and decay heat. Using such an approach, there could be much lower environmental impact from the high-level waste as compared to direct disposal of the used fuel, but there would likely be greater generation of low-level wastes that will also require disposal. An additional potential waste management benefit is having the ability to tailor waste forms and contents to one or more targeted disposal environments (i.e., to be able to put waste in environments best-suited for the waste contents and forms). Copyright © 2010 Health Physics Society

Radionuclide Migration through Sediment and Concrete: 16 Years of Investigations

DOE Office of Scientific and Technical Information (OSTI.GOV)

Golovich, Elizabeth C.; Mattigod, Shas V.; Snyder, Michelle MV

The Waste Management Project provides safe, compliant, and cost-effective waste management services for the Hanford Site and the U.S. Department of Energy (DOE) complex. Part of these services includes safe disposal of low-level waste and mixed low-level waste at the Hanford Low-Level Waste Burial Grounds in accordance with the requirements of DOE Order 435.1, Radioactive Waste Management. To partially satisfy these requirements, performance assessment analyses were completed and approved. DOE Order 435.1 also requires continuing data collection to increase confidence in the critical assumptions used in these analyses to characterize the operational features of the disposal facility that are reliedmore » on to satisfy the performance objectives identified in the order. Cement-based solidification and stabilization is considered for hazardous waste disposal because it is easily done and cost-efficient. One critical assumption is that concrete will be used as a waste form or container material at the Hanford Site to control and minimize the release of radionuclide constituents in waste into the surrounding environment. Concrete encasement would contain and isolate the waste packages from the hydrologic environment and act as an intrusion barrier. Any failure of concrete encasement may result in water intrusion and consequent mobilization of radionuclides from the waste packages. The radionuclides iodine-129, selenium-75, technetium-99, and uranium-238 have been identified as long-term dose contributors (Mann et al. 2001; Wood et al. 1995). Because of their anionic nature in aqueous solutions, these constituents of potential concern may be released from the encased concrete by mass flow and/or diffusion and migrate into the surrounding subsurface environment (Serne et al. 1989; 1992; 1993a, b; 1995). Therefore, it is necessary to assess the performance of the concrete encasement structure and the ability of the surrounding soil to retard radionuclide migration. Each of the test methods performed throughout the lifetime of the project has focused on different aspects of the concrete waste form weathering process. Diffusion of different analytes [technetium-99 (Tc-99), iodine-125 (I-125), stable iodine (I), uranium (U), and rhenium (Re)] has been quantified from experiments under both saturated and unsaturated conditions. The water-saturated conditions provide a conservative estimate of the concrete’s performance in situ, and the unsaturated conditions provide a more accurate estimate of the diffusion of contaminants from the concrete.« less

Astrobiology: The Study of the Origin, Evolution, and Distribution of Life in the Universe

ERIC Educational Resources Information Center

Scalice, Daniella; Wilmoth, Krisstina

2004-01-01

Life as people know it here on Earth exchanges energy and materials with the environment. Life forms grow, develop, produce waste products, and reproduce, storing genetic information in DNA and RNA and passing it from one generation to the next. Life evolves, adapting to changes in the environment and changing the environment in return. The basic…

Astrobiology: The Study of the Origin, Evolution, and Distribution of the Life in the Universe

ERIC Educational Resources Information Center

Scalice, Daniella; Wilmoth, Krisstina

2004-01-01

Life as known here on Earth exchanges energy and materials with the environment. Life forms grow, develop, produce waste products, and reproduce, storing genetic information in DNA and RNA and passing it from one generation to the next. Life evolves, adapting to changes in the environment and changing the environment in return. The basic unit of…

Workshop on the role of natural analogs in geologic disposal of high-level nuclear waste: Proceedings

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kovach, L.A.; Murphy, W.M.

1995-09-01

A Workshop on the Role of Natural Analogs in Geologic Disposal of High-Level Nuclear Waste was held in San Antonio, Texas on July 22--25, 1991. The proceedings comprise seventeen papers submitted by participants at the workshop. A series of papers addresses the relation of natural analog studies to the regulation, performance assessment, and licensing of a geologic repository. Applications of reasoning by analogy are illustrated in papers on the role of natural analogs in studies of earthquakes, petroleum, and mineral exploration. A summary is provided of a recently completed, internationally coordinated natural analog study at Pocos de Caldas, Brazil. Papersmore » also cover problems and applications of natural analog studies in four technical areas of nuclear waste management-. waste form and waste package, near-field processes and environment, far-field processes and environment, and volcanism and tectonics. Summaries of working group deliberations in these four technical areas provide reviews and proposals for natural analog applications. Individual papers have been cataloged separately.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goldston, W.

On April 21, 2009, the Energy Facilities Contractors Group (EFCOG) Waste Management Working Group (WMWG) provided a recommendation to the Department of Energy's Environmental Management program (DOE-EM) concerning supplemental guidance on blending methodologies to use to classify waste forms to determine if the waste form meets the definition of Transuranic (TRU) Waste or can be classified as Low-Level Waste (LLW). The guidance provides specific examples and methods to allow DOE and its Contractors to properly classify waste forms while reducing the generation of TRU wastes. TRU wastes are much more expensive to characterize at the generator's facilities, ship, and thenmore » dispose at the Waste Isolation Pilot Plant (WIPP) than Low-Level Radioactive Waste's disposal. Also the reduction of handling and packaging of LLW is inherently less hazardous to the nuclear workforce. Therefore, it is important to perform the characterization properly, but in a manner that minimizes the generation of TRU wastes if at all possible. In fact, the generation of additional volumes of radioactive wastes under the ARRA programs, this recommendation should improve the cost effective implementation of DOE requirements while properly protecting human health and the environment. This paper will describe how the message of appropriate, less expensive, less hazardous blending of radioactive waste is the 'right' thing to do in many cases, but can be confused with inappropriate 'dilution' that is frowned upon by regulators and stakeholders in the public. A proposal will be made in this paper on how to communicate this very complex and confusing technical issue to regulatory bodies and interested stakeholders to gain understanding and approval of the concept. The results of application of the proposed communication method and attempt to change the regulatory requirements in this area will be discussed including efforts by DOE and the NRC on this very complex subject.« less

Evaluation of a Novel Approach for Reducing Emissions of Pharmaceuticals to the Environment

NASA Astrophysics Data System (ADS)

Bean, Thomas G.; Bergstrom, Ed; Thomas-Oates, Jane; Wolff, Amy; Bartl, Peter; Eaton, Bob; Boxall, Alistair B. A.

2016-10-01

Increased interest over the levels of pharmaceuticals detected in the environment has led to the need for new approaches to manage their emissions. Inappropriate disposal of unused and waste medicines and release from manufacturing plants are believed to be important pathways for pharmaceuticals entering the environment. In situ treatment technologies, which can be used on-site in pharmacies, hospitals, clinics, and at manufacturing plants, might provide a solution. In this study we explored the use of Pyropure, a microscale combined pyrolysis and gasification in situ treatment system for destroying pharmaceutical wastes. This involved selecting 17 pharmaceuticals, including 14 of the most thermally stable compounds currently in use and three of high environmental concern to determine the technology's success in waste destruction. Treatment simulation studies were done on three different waste types and liquid, solid, and gaseous emissions from the process were analyzed for parent pharmaceutical and known active transformation products. Gaseous emissions were also analyzed for NOx, particulates, dioxins, furans, and metals. Results suggest that Pyropure is an effective treatment process for pharmaceutical wastes: over 99 % of each study pharmaceutical was destroyed by the system without known active transformation products being formed during the treatment process. Emissions of the other gaseous air pollutants were within acceptable levels. Future uptake of the system, or similar in situ treatment approaches, by clinics, pharmacists, and manufacturers could help to reduce the levels of pharmaceuticals in the environment and reduce the economic and environmental costs of current waste management practices.

Unfair trade: e-waste in Africa.

PubMed

Schmidt, Charles W

2006-04-01

Africa is quickly becoming a destination for information technology in the form of tons of used computers, fax machines, cell phones, and other electronics. Although many of these machines can be repaired and resold, up to 75% of the electronics shipped to Africa is junk. This equipment, when dumped, may leach lead, mercury, and cadmium into the environment; when burned, it may release carcinogenic dioxins and polyaromatic hydrocarbons. In the United States, activists are working to limit the flow of e-waste to developing countries through international agreements and voluntary e-waste export reduction efforts.

Evaluating the cement stabilization of arsenic-bearing iron wastes from drinking water treatment.

PubMed

Clancy, Tara M; Snyder, Kathryn V; Reddy, Raghav; Lanzirotti, Antonio; Amrose, Susan E; Raskin, Lutgarde; Hayes, Kim F

2015-12-30

Cement stabilization of arsenic-bearing wastes is recommended to limit arsenic release from wastes following disposal. Such stabilization has been demonstrated to reduce the arsenic concentration in the Toxicity Characteristic Leaching Procedure (TCLP), which regulates landfill disposal of arsenic waste. However, few studies have evaluated leaching from actual wastes under conditions similar to ultimate disposal environments. In this study, land disposal in areas where flooding is likely was simulated to test arsenic release from cement stabilized arsenic-bearing iron oxide wastes. After 406 days submersed in chemically simulated rainwater, <0.4% of total arsenic was leached, which was comparable to the amount leached during the TCLP (<0.3%). Short-term (18 h) modified TCLP tests (pH 3-12) found that cement stabilization lowered arsenic leaching at high pH, but increased leaching at pH<4.2 compared to non-stabilized wastes. Presenting the first characterization of cement stabilized waste using μXRF, these results revealed the majority of arsenic in cement stabilized waste remained associated with iron. This distribution of arsenic differed from previous observations of calcium-arsenic solid phases when arsenic salts were stabilized with cement, illustrating that the initial waste form influences the stabilized form. Overall, cement stabilization is effective for arsenic-bearing wastes when acidic conditions can be avoided. Copyright © 2015 Elsevier B.V. All rights reserved.

Handbook: Approaches for the Remediation of Federal Facility Sites Contaminated with Explosive or Radioactive Wastes

DTIC Science & Technology

1993-09-01

ash, and incinerator fly ash in modified sulfur cement and Portland cement waste forms ................................. 70 6-10 Drawing of full-scale...6-17 Economic analysis of encapsulating sodium nitrate at Rocky Flats Plant ..................... 74 6-18 Portland cement and modified sulfur cement...environment. DP-1629. Savannah and modified sulfur cement encapsulation. Both methods River Laboratory, Aiken, South Carolina. have advantages over

Development of an Integrated Raman and Turbidity Fiber Optic Sensor for the In-Situ Analysis of High Level Nuclear Waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gasbarro, Christina; Bello, Job M.; Bryan, Samuel A.

2013-02-24

Stored nuclear waste must be retrieved from storage, treated, separated into low- and high-level waste streams, and finally put into a disposal form that effectively encapsulates the waste and isolates it from the environment for a long period of time. Before waste retrieval can be done, waste composition needs to be characterized so that proper safety precautions can be implemented during the retrieval process. In addition, there is a need for active monitoring of the dynamic chemistry of the waste during storage since the waste composition can become highly corrosive. This work describes the development of a novel, integrated fibermore » optic Raman and light scattering probe for in situ use in nuclear waste solutions. The dual Raman and turbidity sensor provides simultaneous chemical identification of nuclear waste as well as information concerning the suspended particles in the waste using a common laser excitation source.« less

Development of an Integrated Raman and Turbidity Fiber Optic Sensor for the In-Situ Analysis of High Level Nuclear Waste - 13532

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gasbarro, Christina; Bello, Job; Bryan, Samuel

2013-07-01

Stored nuclear waste must be retrieved from storage, treated, separated into low- and high-level waste streams, and finally put into a disposal form that effectively encapsulates the waste and isolates it from the environment for a long period of time. Before waste retrieval can be done, waste composition needs to be characterized so that proper safety precautions can be implemented during the retrieval process. In addition, there is a need for active monitoring of the dynamic chemistry of the waste during storage since the waste composition can become highly corrosive. This work describes the development of a novel, integrated fibermore » optic Raman and light scattering probe for in situ use in nuclear waste solutions. The dual Raman and turbidity sensor provides simultaneous chemical identification of nuclear waste as well as information concerning the suspended particles in the waste using a common laser excitation source. (authors)« less

Recycling of blast furnace sludge by briquetting with starch binder: Waste gas from thermal treatment utilizable as a fuel.

PubMed

Drobíková, Klára; Plachá, Daniela; Motyka, Oldřich; Gabor, Roman; Kutláková, Kateřina Mamulová; Vallová, Silvie; Seidlerová, Jana

2016-02-01

Steel plants generate significant amounts of wastes such as sludge, slag, and dust. Blast furnace sludge is a fine-grained waste characterized as hazardous and affecting the environment negatively. Briquetting is one of the possible ways of recycling of this waste while the formed briquettes serve as a feed material to the blast furnace. Several binders, both organic and inorganic, had been assessed, however, only the solid product had been analysed. The aim of this study was to assess the possibilities of briquetting using commonly available laundry starch as a binder while evaluating the possible utilization of the waste gas originating from the thermal treatment of the briquettes. Briquettes (100g) were formed with the admixture of starch (UNIPRET) and their mechanical properties were analysed. Consequently, they were subjected to thermal treatment of 900, 1000 and 1100°C with retention period of 40min during which was the waste gas collected and its content analysed using gas chromatography. Dependency of the concentration of the compounds forming the waste gas on the temperature used was determined using Principal component analysis (PCA) and correlation matrix. Starch was found to be a very good binder and reduction agent, it was confirmed that metallic iron was formed during the thermal treatment. Approximately 20l of waste gas was obtained from the treatment of one briquette; main compounds were methane and hydrogen rendering the waste gas utilizable as a fuel while the greatest yield was during the lowest temperatures. Preparation of blast furnace sludge briquettes using starch as a binder and their thermal treatment represents a suitable method for recycling of this type of metallurgical waste. Moreover, the composition of the resulting gas is favourable for its use as a fuel. Copyright © 2015 Elsevier Ltd. All rights reserved.

Anaerobic microbial dissolution of lead and production of organic acids

DOEpatents

Francis, A.J.; Dodge, C.; Chendrayan, K.

1986-02-28

The present invention relates to a method of solubilizing lead, in the form of lead oxide, found in industrial wastes, before these wastes are dumped into the environment. The lead is solubilized by dissolving the lead oxide in the wastes through contact with an anaerobic bacterial culture containing the bacterium ATCC No. 53464. The solubilized lead can then be removed from the wastes by chemical separation. It could also be removed by extending the contact period with the bacterial culture. As the culture grows, the solubilized lead is removed from the wastes by bioaccumulation by the microorganism or by immobilization by a polymer-like material produced by the microorganism. At this point, the lead is then removed from the wastes when the waste material is separated from the bacterial culture. If desired, the bacterial culture could be digested at this point to yield relatively pure lead for further industrial use.

Fiber reinforced concrete: An advanced technology for LL/ML radwaste conditioning and disposal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Tchemitcheff, E.; Verdier, A.

Radioactive waste immobilization is an integral part of operations in nuclear facilities. The goal of immobilization is to contain radioactive materials in a waste form which can maintain its integrity over very long periods of time, thus effectively isolating the materials from the environment and hence from the public. This is true regardless of the activity of the waste, including low-, and medium-level waste (LLW, MLW). A multiple-year research effort by Cogema culminated in the development of a new process to immobilize nuclear waste in concrete containers reinforced with metal fibers. The fiber concrete containers satisfy all French safety requirementsmore » relating to waste immobilization and disposal, and have been certified by ANDRA, the national radioactive waste management agency. The fiber concrete containers have been fabricated on a production scale since July 1990 by Sogefibre, a jointly-owned subsidiary of SGN and Compagnie Generale des Eaux.« less

Waste Isolation Safety Assessment Program. Technical progress report for FY-1978

DOE Office of Scientific and Technical Information (OSTI.GOV)

Brandstetter, A.; Harwell, M.A.; Howes, B.W.

1979-07-01

Associated with commercial nuclear power production in the United States is the generation of potentially hazardous radioactive wastes. The Department of Energy (DOE) is seeking to develop nuclear waste isolation systems in geologic formations that will preclude contact with the biosphere of waste radionuclides in concentrations which are sufficient to cause deleterious impact on humans or their environments. Comprehensive analyses of specific isolation systems are needed to assess the expectations of meeting that objective. The Waste Isolation Safety Assessment Program (WISAP) has been established at the Pacific Northwest Laboratory (operated by Battelle Memorial Institute) for developing the capability of makingmore » those analyses. Progress on the following tasks is reported: release scenario analysis, waste form release rate analysis, release consequence analysis, sorption-desorption analysis, and societal acceptance analysis. (DC)« less

Possibility of forming artificial soil based on drilling waste and sewage sludge

NASA Astrophysics Data System (ADS)

Kujawska, J.; Pawłowska, M.; Wasag, H.

2018-05-01

Land redevelopment is necessary due to the amount of a degraded area. Depositing waste on the small area of landfills is harmful for the environment. New methods of managing and utilizing waste are being sought in order to minimize the deposition of waste. In small amounts, many types of waste can be treated as a substrate or material improving physicochemical properties of soils, and hence can be used in reclamation of degraded lands. The study analysed the effect of different doses of sewage sludge (35%, 17.5%) with addition (2.5% and 5%) of drilling waste on the properties of degraded soils. The results show that created mixtures improve the sorption properties of soil. The mixtures contain the optimal the ratio of nutrient elements for growth of plants is N:P:K.

Densified waste form and method for forming

DOEpatents

Garino, Terry J.; Nenoff, Tina M.; Sava Gallis, Dorina Florentina

2015-08-25

Materials and methods of making densified waste forms for temperature sensitive waste material, such as nuclear waste, formed with low temperature processing using metallic powder that forms the matrix that encapsulates the temperature sensitive waste material. The densified waste form includes a temperature sensitive waste material in a physically densified matrix, the matrix is a compacted metallic powder. The method for forming the densified waste form includes mixing a metallic powder and a temperature sensitive waste material to form a waste form precursor. The waste form precursor is compacted with sufficient pressure to densify the waste precursor and encapsulate the temperature sensitive waste material in a physically densified matrix.

Speciation and Oxidative Stability of Alkaline Soluble, Non-Pertechnetate Technetium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Levitskaia, Tatiana G.; Rapko, Brian M.; Anderson, Amity

2014-09-30

The long half-life, complex chemical behavior in tank waste, limited incorporation in mid- to high-temperature immobilization processes, and high mobility in subsurface environments make technetium (Tc) one of the most difficult contaminants to dispose of and/or remediate. Technetium exists predominantly in the liquid tank waste phase as the relatively mobile form of pertechnetate, TcO 4 -. However, based on experimentation to date a significant fraction of the soluble Tc cannot be effectively separated from the wastes and may be present as a non- pertechnetate species. The presence of a non-pertechnetate species significantly complicates disposition of low-activity waste (LAW), and themore » development of methods to either convert them to pertechnetate or to separate directly is needed. The challenge is the uncertainty regarding the chemical form of the alkaline-soluble low-valent non-pertechnetate species in the liquid tank waste. This report summarizes work done in fiscal year (FY) 2014 exploring the chemistry of a low-valence technetium(I) species, [(CO) 3Tc(H 2O) 3] +, a compound of interest due to its implication in the speciation of alkaline-soluble technetium in several Hanford tank waste supernatants.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Osmanlioglu, Ahmet Erdal

Available in abstract form only. Full text of publication follows: Naturally occurring radioactive material (NORM) in concentrated forms arises both in industry and in nature where natural radioisotopes accumulate at particular sites. Technically enhanced naturally occurring radioactive materials (TE-NORM) often occurs in an acidic environment where precipitates containing radionuclides plate out onto pipe walls, filters, tank linings, etc. Because of the radionuclides are selectively deposited at these sites, radioactivity concentration is extremely higher than the natural concentration. This paper presents characterization and related considerations of TE-NORM wastes in Turkey. Generally, accumulation conditions tend to favour the build-up of radium. Asmore » radium is highly radio-toxic, handling, treatment, storage and disposal of such material requires careful management. Turkey has the only low level waste processing and storage facility (WPSF) in Istanbul. This facility has interim storage buildings and storage area for storage of packaged radioactive waste which are containing artificial radioisotopes, but there is an increasing demand for the storage to accept bulk concentrated TE-NORM wastes from iron-steel and related industries. Most of these wastes generated from scrap metal piles which are imported from other countries. These wastes generally contain radium. (authors)« less

Analysis of the energy potential of municipal solid waste for the thermal treatment technology development in Poland

NASA Astrophysics Data System (ADS)

Midor, Katarzyna; Jąderko, Karolina

2017-11-01

The problem of overproduction of waste has been a local issue for many years. Since the new environment law came into effect, the current approach to waste management has changed significantly. The accessible technological possibilities of thermal waste treatment with the energy recovery set a new area of research over the process of choosing effective and rational way of calorific waste management. The objective of this article is to provide assessment results of the analysed energy potential in waste management system in the form of calorific waste stream. In includes all the activities and actions required to manage municipal solid waste from its inception to its final disposal i.e. collection, transport, treatment and disposal. The graphical representation of waste flow indicates the lost opportunities of waste energy recovery. Visual research method was supported and founded on value stream mapping. On the basis of the results were presented the directions of further improvement of calorific waste stream mapping for the purposes of implementation the thermal treatment technology in the selected waste management region.

Densified waste form and method for forming

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garino, Terry J.; Nenoff, Tina M.; Sava Gallis, Dorina Florentina

Materials and methods of making densified waste forms for temperature sensitive waste material, such as nuclear waste, formed with low temperature processing using metallic powder that forms the matrix that encapsulates the temperature sensitive waste material. The densified waste form includes a temperature sensitive waste material in a physically densified matrix, the matrix is a compacted metallic powder. The method for forming the densified waste form includes mixing a metallic powder and a temperature sensitive waste material to form a waste form precursor. The waste form precursor is compacted with sufficient pressure to densify the waste precursor and encapsulate themore » temperature sensitive waste material in a physically densified matrix.« less

Antimicrobial-Resistant Bacterial Populations and Antimicrobial Resistance Genes Obtained from Environments Impacted by Livestock and Municipal Waste

PubMed Central

Durso, Lisa M.; Harhay, Dayna M.; Schmidt, John W.

2015-01-01

This study compared the populations of antimicrobial-resistant bacteria and the repertoire of antimicrobial resistance genes in four environments: effluent of three municipal wastewater treatment facilities, three cattle feedlot runoff catchment ponds, three swine waste lagoons, and two “low impact” environments (an urban lake and a relict prairie). Multiple liquid and solid samples were collected from each environment. The prevalences and concentrations of antimicrobial-resistant (AMR) Gram-negative (Escherichia coli and Salmonella enterica) and Gram-positive (enterococci) bacteria were determined from individual samples (n = 174). The prevalences of 84 antimicrobial resistance genes in metagenomic DNA isolated from samples pooled (n = 44) by collection date, location, and sample type were determined. The prevalences and concentrations of AMR E. coli and Salmonella were similar among the livestock and municipal sample sources. The levels of erythromycin-resistant enterococci were significantly higher in liquid samples from cattle catchment ponds and swine waste lagoons than in liquid samples from municipal wastewater treatment facilities, but solid samples from these environments did not differ significantly. Similarly, trimethoprim/sulfamethoxazole-resistant E. coli concentrations were significantly higher in swine liquid than in municipal liquid samples, but there was no difference in solid samples. Multivariate analysis of the distribution of antimicrobial resistance genes using principal coordinate analysis showed distinct clustering of samples with livestock (cattle and swine), low impact environment and municipal samples forming three separate clusters. The numbers of class A beta-lactamase, class C beta-lactamase, and fluoroquinolone resistance genes detected were significantly higher (P < 0.05) in municipal samples than in cattle runoff or swine lagoon samples. In conclusion, we report that AMR is a very widespread phenomenon and that similar prevalences and concentrations of antimicrobial-resistant bacteria and antimicrobial resistance genes exist in cattle, human, and swine waste streams, but a higher diversity of antimicrobial resistance genes are present in treated human waste discharged from municipal wastewater treatment plants than in livestock environments. PMID:26197056

Antimicrobial-Resistant Bacterial Populations and Antimicrobial Resistance Genes Obtained from Environments Impacted by Livestock and Municipal Waste.

PubMed

Agga, Getahun E; Arthur, Terrance M; Durso, Lisa M; Harhay, Dayna M; Schmidt, John W

2015-01-01

This study compared the populations of antimicrobial-resistant bacteria and the repertoire of antimicrobial resistance genes in four environments: effluent of three municipal wastewater treatment facilities, three cattle feedlot runoff catchment ponds, three swine waste lagoons, and two "low impact" environments (an urban lake and a relict prairie). Multiple liquid and solid samples were collected from each environment. The prevalences and concentrations of antimicrobial-resistant (AMR) Gram-negative (Escherichia coli and Salmonella enterica) and Gram-positive (enterococci) bacteria were determined from individual samples (n = 174). The prevalences of 84 antimicrobial resistance genes in metagenomic DNA isolated from samples pooled (n = 44) by collection date, location, and sample type were determined. The prevalences and concentrations of AMR E. coli and Salmonella were similar among the livestock and municipal sample sources. The levels of erythromycin-resistant enterococci were significantly higher in liquid samples from cattle catchment ponds and swine waste lagoons than in liquid samples from municipal wastewater treatment facilities, but solid samples from these environments did not differ significantly. Similarly, trimethoprim/sulfamethoxazole-resistant E. coli concentrations were significantly higher in swine liquid than in municipal liquid samples, but there was no difference in solid samples. Multivariate analysis of the distribution of antimicrobial resistance genes using principal coordinate analysis showed distinct clustering of samples with livestock (cattle and swine), low impact environment and municipal samples forming three separate clusters. The numbers of class A beta-lactamase, class C beta-lactamase, and fluoroquinolone resistance genes detected were significantly higher (P < 0.05) in municipal samples than in cattle runoff or swine lagoon samples. In conclusion, we report that AMR is a very widespread phenomenon and that similar prevalences and concentrations of antimicrobial-resistant bacteria and antimicrobial resistance genes exist in cattle, human, and swine waste streams, but a higher diversity of antimicrobial resistance genes are present in treated human waste discharged from municipal wastewater treatment plants than in livestock environments.

Method for distinctive estimation of stored acidity forms in acid mine wastes.

PubMed

Li, Jun; Kawashima, Nobuyuki; Fan, Rong; Schumann, Russell C; Gerson, Andrea R; Smart, Roger St C

2014-10-07

Jarosites and schwertmannite can be formed in the unsaturated oxidation zone of sulfide-containing mine waste rock and tailings together with ferrihydrite and goethite. They are also widely found in process wastes from electrometallurgical smelting and metal bioleaching and within drained coastal lowland soils (acid-sulfate soils). These secondary minerals can temporarily store acidity and metals or remove and immobilize contaminants through adsorption, coprecipitation, or structural incorporation, but release both acidity and toxic metals at pH above about 4. Therefore, they have significant relevance to environmental mineralogy through their role in controlling pollutant concentrations and dynamics in contaminated aqueous environments. Most importantly, they have widely different acid release rates at different pHs and strongly affect drainage water acidity dynamics. A procedure for estimation of the amounts of these different forms of nonsulfide stored acidity in mining wastes is required in order to predict acid release rates at any pH. A four-step extraction procedure to quantify jarosite and schwertmannite separately with various soluble sulfate salts has been developed and validated. Corrections to acid potentials and estimation of acid release rates can be reliably based on this method.

Decontamination of uranium-contaminated waste oil using supercritical fluid and nitric acid.

PubMed

Sung, Jinhyun; Kim, Jungsoo; Lee, Youngbae; Seol, Jeunggun; Ryu, Jaebong; Park, Kwangheon

2011-07-01

The waste oil used in nuclear fuel processing is contaminated with uranium because of its contact with materials or environments containing uranium. Under current law, waste oil that has been contaminated with uranium is very difficult to dispose of at a radioactive waste disposal site. To dispose of the uranium-contaminated waste oil, the uranium was separated from the contaminated waste oil. Supercritical R-22 is an excellent solvent for extracting clean oil from uranium-contaminated waste oil. The critical temperature of R-22 is 96.15 °C and the critical pressure is 49.9 bar. In this study, a process to remove uranium from the uranium-contaminated waste oil using supercritical R-22 was developed. The waste oil has a small amount of additives containing N, S or P, such as amines, dithiocarbamates and dialkyldithiophosphates. It seems that these organic additives form uranium-combined compounds. For this reason, dissolution of uranium from the uranium-combined compounds using nitric acid was needed. The efficiency of the removal of uranium from the uranium-contaminated waste oil using supercritical R-22 extraction and nitric acid treatment was determined.

Nuclear Energy Advanced Modeling and Simulation (NEAMS) Waste Integrated Performance and Safety Codes (IPSC) : FY10 development and integration.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Criscenti, Louise Jacqueline; Sassani, David Carl; Arguello, Jose Guadalupe, Jr.

2011-02-01

This report describes the progress in fiscal year 2010 in developing the Waste Integrated Performance and Safety Codes (IPSC) in support of the U.S. Department of Energy (DOE) Office of Nuclear Energy Advanced Modeling and Simulation (NEAMS) Campaign. The goal of the Waste IPSC is to develop an integrated suite of computational modeling and simulation capabilities to quantitatively assess the long-term performance of waste forms in the engineered and geologic environments of a radioactive waste storage or disposal system. The Waste IPSC will provide this simulation capability (1) for a range of disposal concepts, waste form types, engineered repository designs,more » and geologic settings, (2) for a range of time scales and distances, (3) with appropriate consideration of the inherent uncertainties, and (4) in accordance with robust verification, validation, and software quality requirements. Waste IPSC activities in fiscal year 2010 focused on specifying a challenge problem to demonstrate proof of concept, developing a verification and validation plan, and performing an initial gap analyses to identify candidate codes and tools to support the development and integration of the Waste IPSC. The current Waste IPSC strategy is to acquire and integrate the necessary Waste IPSC capabilities wherever feasible, and develop only those capabilities that cannot be acquired or suitably integrated, verified, or validated. This year-end progress report documents the FY10 status of acquisition, development, and integration of thermal-hydrologic-chemical-mechanical (THCM) code capabilities, frameworks, and enabling tools and infrastructure.« less

Oak Ridge National Laboratory Waste Management Plan, fiscal year 1994. Revision 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Turner, J.W.

1993-12-01

US Department of Energy (DOE) Order 5820.2A was promulgated in final form on September 26, 1988. The order requires heads of field organizations to prepare and to submit updates on the waste management plans for all operations under their purview according to the format in Chap. 6, {open_quotes}Waste Management Plan Outline.{close_quotes} These plans are to be submitted by the DOE Oak Ridge Operations Office (DOE-ORO) in December of each year and distributed to the DP-12, ES&H-1, and other appropriate DOE Headquarters (DOE-HQ) organizations for review and comment. This document was prepared in response to this requirement for fiscal year (FY)more » 1994. The Oak Ridge National Laboratory (ORNL) waste management mission is reduction, collection, storage, treatment, and disposal of DOE wastes, generated primarily in pursuit of ORNL missions, in order to protect human health and safety and the environment. In carrying out this mission, waste management staff in the Waste Management and Remedial Action Division (WMRAD) will (1) guide ORNL in optimizing waste reduction and waste management capabilities and (2) conduct waste management operations in a compliant, publicly acceptable, technically sound, and cost-efficient manner. Waste management requirements for DOE radioactive wastes are detailed in DOE Order 5820.2A, and the ORNL Waste Management Program encompasses all elements of this order. The requirements of this DOE order and other appropriate DOE orders, along with applicable Tennessee Department of Environment and Conservation and US Environmental Protection Agency (EPA) rules and regulations, provide the principal source of regulatory guidance for waste management operations at ORNL. The objective of this document is compilation and consolidation of information on how the ORNL Waste Management Program is conducted, which waste management facilities are being used to manage wastes, what activities are planned for FY 1994, and how all of the activities are documented.« less

Methods of silver recovery from radiographs - comparative study

NASA Astrophysics Data System (ADS)

Canda, L. R.; Ardelean, E.; Hepuţ, T.

2018-01-01

Management and recovery of waste are activities with multiple impacts: technologically (by using waste on current production flows, thus replacing poor raw materials), economically (can substantially reduce manufacturing costs by recycling waste), social (by creating new jobs where it is necessary to process the waste in a form more suited to technological flows) and ecologically (by removing waste that is currently produced or already stored - but poses a threat to the health of the population and / or to the environment). This is also the case for medical waste, for example radiographs, which are currently produced in large quantities, for which replacement solutions are sought, but are currently stored by archiving in hospital units. The paper presents two methods used for this kind of waste management, the result being the recovery of silver, material with applications and with increasing price, but also the proper disposal of the polymeric support. This analysis aims at developing a more efficient recycling technology for medical radiographs.

Present status of recycling waste mobile phones in China: a review.

PubMed

Li, Jingying; Ge, Zhongying; Liang, Changjin; An, Ni

2017-07-01

A large number of waste mobile phones have already been generated and are being generated. Various countries around the world have all been positively exploring the way of recycling and reuse when facing such a large amount of waste mobile phones. In some countries, processing waste mobile phones has been forming a complete industrial chain, which can not only recycle waste mobile phones to reduce their negative influence on the environment but also turn waste into treasure to acquire economic benefits dramatically. However, the situation of recycling waste mobile phones in China is not going well. Waste mobile phones are not formally covered by existing regulations and policies for the waste electric and electronic equipment in China. In order to explore an appropriate system to recover waste mobile phones, the mobile phone production and the amount of waste mobile phones are introduced in this paper, and status of waste mobile phones recycling is described; then, the disposal technology of electronic waste that would be most likely to be used for processing of electronic waste in industrial applications in the near future is reviewed. Finally, rationalization proposals are put forward based on the current recovery status of waste mobile phones for the purpose of promoting the development of recycling waste mobile phones in developing countries with a special emphasis on China.

40 CFR 270.65 - Research, development, and demonstration permits.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 28 2012-07-01 2012-07-01 false Research, development, and... Special Forms of Permits § 270.65 Research, development, and demonstration permits. (a) The Administrator may issue a research, development, and demonstration permit for any hazardous waste treatment facility...

40 CFR 270.65 - Research, development, and demonstration permits.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 28 2013-07-01 2013-07-01 false Research, development, and... Special Forms of Permits § 270.65 Research, development, and demonstration permits. (a) The Administrator may issue a research, development, and demonstration permit for any hazardous waste treatment facility...

Evaluation of Technetium Getters to Improve the Performance of Cast Stone

DOE Office of Scientific and Technical Information (OSTI.GOV)

Neeway, James J.; Qafoku, Nikolla P.; Serne, R. Jeffrey

2015-11-01

Cast Stone has been selected as the preferred waste form for solidification of aqueous secondary liquid effluents from the Hanford Tank Waste Treatment and Immobilization Plant (WTP) process condensates and low-activity waste (LAW) melter off-gas caustic scrubber effluents. Cast Stone is also being evaluated as a supplemental immobilization technology to provide the necessary LAW treatment capacity to complete the Hanford tank waste cleanup mission in a timely and cost effective manner. One of the major radionuclides that Cast Stone has the potential to immobilize is technetium (Tc). The mechanism for immobilization is through the reduction of the highly mobile Tc(VII)more » species to the less mobile Tc(IV) species by the blast furnace slag (BFS) used in the Cast Stone formulation. Technetium immobilization through this method would be beneficial because Tc is one of the most difficult contaminants to address at the U.S. Department of Energy (DOE) Hanford Site due to its complex chemical behavior in tank waste, limited incorporation in mid- to high-temperature immobilization processes (vitrification, steam reformation, etc.), and high mobility in subsurface environments. In fact, the Tank Closure and Waste Management Environmental Impact Statement for the Hanford Site, Richland, Washington (TC&WM EIS) identifies technetium-99 ( 99Tc) as one of the radioactive tank waste components contributing the most to the environmental impact associated with the cleanup of the Hanford Site. The TC&WM EIS, along with an earlier supplemental waste-form risk assessment, used a diffusion-limited release model to estimate the release of different contaminants from the WTP process waste forms. In both of these predictive modeling exercises, where effective diffusivities based on grout performance data available at the time, groundwater at the 100-m down-gradient well exceeded the allowable maximum permissible concentrations for 99Tc. (900 pCi/L). Recent relatively short-term (63 day) leach tests conducted on both LAW and secondary waste Cast Stone monoliths indicated that 99Tc diffusivities were at or near diffusivities where the groundwater at the 100-m down-gradient well would exceed the allowable maximum permissible 99Tc concentrations. There is, therefore, a need and an opportunity to improve the retention of Tc in the Cast Stone waste form. One method to improve the performance of the Cast Stone waste form is through the addition of “getters” that selectively sequester Tc inside Cast Stone.« less

Healthcare waste management status in Lagos State, Nigeria: a case study from selected healthcare facilities in Ikorodu and Lagos metropolis.

PubMed

Longe, Ezechiel O

2012-06-01

A survey of healthcare waste management practices and their implications for health and the environment was carried out. The study assessed waste management practices in 20 healthcare facilities ranging in capacity from 40 to 600 beds in Ikorodu and metropolitan Lagos, Lagos State, Nigeria. The prevailing healthcare waste management status was analysed. Management issues on quantities and proportion of different constituents of waste, segregation, collection, handling, transportation, treatment and disposal methods were assessed. The waste generation averaged 0.631 kg bed(-1) day(-1) over the survey area. The waste stream from the healthcare facilities consisted of general waste (59.0%), infectious waste (29.7%), sharps and pathological (8.9%), chemical (1.45%) and others (0.95%). Sharps/pathological waste includes disposable syringes. In general, the waste materials were collected in a mixed form, transported and disposed of along with municipal solid waste with attendant risks to health and safety. Most facilities lacked appropriate treatment systems for a variety of reasons that included inadequate funding and little or no priority for healthcare waste management as well as a lack of professionally competent waste managers among healthcare providers. Hazards associated with healthcare waste management and shortcomings in the existing system were identified.

Iron phosphate compositions for containment of hazardous metal waste

DOEpatents

Day, Delbert E.

1998-01-01

An improved iron phosphate waste form for the vitrification, containment and long-term disposition of hazardous metal waste such as radioactive nuclear waste is provided. The waste form comprises a rigid iron phosphate matrix resulting from the cooling of a melt formed by heating a batch mixture comprising the metal waste and a matrix-forming component. The waste form comprises from about 30 to about 70 weight percent P.sub.2 O.sub.5 and from about 25 to about 50 weight percent iron oxide and has metals present in the metal waste chemically dissolved therein. The concentration of iron oxide in the waste form along with a high proportion of the iron in the waste form being present as Fe.sup.3+ provide a waste form exhibiting improved chemical resistance to corrosive attack. A method for preparing the improved iron phosphate waste forms is also provided.

Iron phosphate compositions for containment of hazardous metal waste

DOEpatents

Day, D.E.

1998-05-12

An improved iron phosphate waste form for the vitrification, containment and long-term disposition of hazardous metal waste such as radioactive nuclear waste is provided. The waste form comprises a rigid iron phosphate matrix resulting from the cooling of a melt formed by heating a batch mixture comprising the metal waste and a matrix-forming component. The waste form comprises from about 30 to about 70 weight percent P{sub 2}O{sub 5} and from about 25 to about 50 weight percent iron oxide and has metals present in the metal waste chemically dissolved therein. The concentration of iron oxide in the waste form along with a high proportion of the iron in the waste form being present as Fe{sup 3+} provide a waste form exhibiting improved chemical resistance to corrosive attack. A method for preparing the improved iron phosphate waste forms is also provided. 21 figs.

Nuclear Energy Advanced Modeling and Simulation Waste Integrated Performance and Safety Codes (NEAMS Waste IPSC).

DOE Office of Scientific and Technical Information (OSTI.GOV)

Schultz, Peter Andrew

The objective of the U.S. Department of Energy Office of Nuclear Energy Advanced Modeling and Simulation Waste Integrated Performance and Safety Codes (NEAMS Waste IPSC) is to provide an integrated suite of computational modeling and simulation (M&S) capabilities to quantitatively assess the long-term performance of waste forms in the engineered and geologic environments of a radioactive-waste storage facility or disposal repository. Achieving the objective of modeling the performance of a disposal scenario requires describing processes involved in waste form degradation and radionuclide release at the subcontinuum scale, beginning with mechanistic descriptions of chemical reactions and chemical kinetics at the atomicmore » scale, and upscaling into effective, validated constitutive models for input to high-fidelity continuum scale codes for coupled multiphysics simulations of release and transport. Verification and validation (V&V) is required throughout the system to establish evidence-based metrics for the level of confidence in M&S codes and capabilities, including at the subcontiunuum scale and the constitutive models they inform or generate. This Report outlines the nature of the V&V challenge at the subcontinuum scale, an approach to incorporate V&V concepts into subcontinuum scale modeling and simulation (M&S), and a plan to incrementally incorporate effective V&V into subcontinuum scale M&S destined for use in the NEAMS Waste IPSC work flow to meet requirements of quantitative confidence in the constitutive models informed by subcontinuum scale phenomena.« less

Analysis of nuclear waste disposal in space, phase 3. Volume 2: Technical report

NASA Technical Reports Server (NTRS)

Rice, E. E.; Miller, N. E.; Yates, K. R.; Martin, W. E.; Friedlander, A. L.

1980-01-01

The options, reference definitions and/or requirements currently envisioned for the total nuclear waste disposal in space mission are summarized. The waste form evaluation and selection process is documented along with the physical characteristics of the iron nickel-base cermet matrix chosen for disposal of commercial and defense wastes. Safety aspects of radioisotope thermal generators, the general purpose heat source, and the Lewis Research Center concept for space disposal are assessed as well as the on-pad catastrophic accident environments for the uprated space shuttle and the heavy lift launch vehicle. The radionuclides that contribute most to long-term risk of terrestrial disposal were determined and the effects of resuspension of fallout particles from an accidental release of waste material were studied. Health effects are considered. Payload breakup and rescue technology are discussed as well as expected requirements for licensing, supporting research and technology, and safety testing.

Analysis of nuclear waste disposal in space, phase 3. Volume 2: Technical report

NASA Astrophysics Data System (ADS)

Rice, E. E.; Miller, N. E.; Yates, K. R.; Martin, W. E.; Friedlander, A. L.

1980-03-01

The options, reference definitions and/or requirements currently envisioned for the total nuclear waste disposal in space mission are summarized. The waste form evaluation and selection process is documented along with the physical characteristics of the iron nickel-base cermet matrix chosen for disposal of commercial and defense wastes. Safety aspects of radioisotope thermal generators, the general purpose heat source, and the Lewis Research Center concept for space disposal are assessed as well as the on-pad catastrophic accident environments for the uprated space shuttle and the heavy lift launch vehicle. The radionuclides that contribute most to long-term risk of terrestrial disposal were determined and the effects of resuspension of fallout particles from an accidental release of waste material were studied. Health effects are considered. Payload breakup and rescue technology are discussed as well as expected requirements for licensing, supporting research and technology, and safety testing.

The importance of the wood biomass in environment protection

NASA Astrophysics Data System (ADS)

Spîrchez, Cosmin; Lunguleasa, Aurel; Croitoru, Cǎtǎlin

2017-12-01

Biomass is a natural vegetal component. As a form of storing energy is chemical form sun, biomass is one of the most popular and universal resource on Earth. Today biomass fuel can be used for various purposes from room heating to produce electricity and fuel for cars. Biomass is presented in various form for energy, including biodegradable fraction of products, remains and waste from agricultural, forestry and industrial wood processing residues from factories paste stationery and paper, remnants of industrial.

Accelerated Weathering of Fluidized Bed Steam Reformation Material Under Hydraulically Unsaturated Conditions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pierce, Eric M.

2007-09-16

To predict the long-term fate of low- and high-level waste forms in the subsurface over geologic time scales, it is important to understand the behavior of the corroding waste forms under conditions the mimic to the open flow and transport properties of a subsurface repository. Fluidized bed steam reformation (FBSR), a supplemental treatment technology option, is being considered as a waste form for the immobilization of low-activity tank waste. To obtain the fundamental information needed to evaluate the behavior of the FBSR waste form under repository relevant conditions and to monitor the long-term behavior of this material, an accelerated weatheringmore » experiment is being conducted with the pressurized unsaturated flow (PUF) apparatus. Unlike other accelerated weathering test methods (product consistency test, vapor hydration test, and drip test), PUF experiments are conducted under hydraulically unsaturated conditions. These experiments are unique because they mimic the vadose zone environment and allow the corroding waste form to achieve its final reaction state. Results from this on-going experiment suggest the volumetric water content varied as a function of time and reached steady state after 160 days of testing. Unlike the volumetric water content, periodic excursions in the solution pH and electrical conductivity have been occurring consistently during the test. Release of elements from the column illustrates a general trend of decreasing concentration with increasing reaction time. Normalized concentrations of K, Na, P, Re (a chemical analogue for 99Tc), and S are as much as 1 × 104 times greater than Al, Cr, Si, and Ti. After more than 600 days of testing, the solution chemistry data collected to-date illustrate the importance of understanding the long-term behavior of the FBSR product under conditions that mimic the open flow and transport properties of a subsurface repository.« less

Safety aspects of nuclear waste disposal in space

NASA Technical Reports Server (NTRS)

Rice, E. E.; Edgecombe, D. S.; Compton, P. R.

1981-01-01

Safety issues involved in the disposal of nuclear wastes in space as a complement to mined geologic repositories are examined as part of an assessment of the feasibility of nuclear waste disposal in space. General safety guidelines for space disposal developed in the areas of radiation exposure and shielding, containment, accident environments, criticality, post-accident recovery, monitoring systems and isolation are presented for a nuclear waste disposal in space mission employing conventional space technology such as the Space Shuttle. The current reference concept under consideration by NASA and DOE is then examined in detail, with attention given to the waste source and mix, the waste form, waste processing and payload fabrication, shipping casks and ground transport vehicles, launch site operations and facilities, Shuttle-derived launch vehicle, orbit transfer vehicle, orbital operations and space destination, and the system safety aspects of the concept are discussed for each component. It is pointed out that future work remains in the development of an improved basis for the safety guidelines and the determination of the possible benefits and costs of the space disposal option for nuclear wastes.

Applications of fiber reinforced concrete containers in France and in Slovakia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Verdier, A.; Delgrande, J.; Remias, V.

Radioactive waste immobilization is an integral part of operations in nuclear facilities. The goal of immobilization is to contain radioactive materials in a waste form which can maintain its integrity over very long periods of time, thus effectively isolating the materials from the environment and hence from the public. This is true regardless of the activity of the waste, including low-, and medium-level waste (LLW, MLW). A multiple-year research effort by COGEMA culminated in the development of a new process to immobilize nuclear waste in concrete containers reinforced with metal fibers. The fiber reinforced concrete containers satisfy all French safetymore » requirements relating to waste immobilization and disposal, and have been certified by ANDRA, the national radioactive waste management agency. The fiber reinforced concrete containers have been fabricated on a production scale since July 1990 by Sogefibre, a jointly-owned subsidiary of SGN and Campaign Generale des Eaux. This technology is being transferred to Slovenske Elektrarne (Slovak Power Plant) to intern the waste produced by Bohunice and Mochovce power plants in cubical fiber reinforced concrete containers.« less

Engineering-Scale Demonstration of DuraLith and Ceramicrete Waste Forms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Josephson, Gary B.; Westsik, Joseph H.; Pires, Richard P.

2011-09-23

To support the selection of a waste form for the liquid secondary wastes from the Hanford Waste Immobilization and Treatment Plant, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing on four candidate waste forms. Two of the candidate waste forms have not been developed to scale as the more mature waste forms. This work describes engineering-scale demonstrations conducted on Ceramicrete and DuraLith candidate waste forms. Both candidate waste forms were successfully demonstrated at an engineering scale. A preliminary conceptual design could be prepared for full-scale production of the candidate waste forms. However, both waste forms are stillmore » too immature to support a detailed design. Formulations for each candidate waste form need to be developed so that the material has a longer working time after mixing the liquid and solid constituents together. Formulations optimized based on previous lab studies did not have sufficient working time to support large-scale testing. The engineering-scale testing was successfully completed using modified formulations. Further lab development and parametric studies are needed to optimize formulations with adequate working time and assess the effects of changes in raw materials and process parameters on the final product performance. Studies on effects of mixing intensity on the initial set time of the waste forms are also needed.« less

Biogeochemical transformations of mercury in solid waste landfills and pathways for release.

PubMed

Lee, Sung-Woo; Lowry, Gregory V; Hsu-Kim, Heileen

2016-02-01

Mercury (Hg) is present in a variety of solid wastes including industrial wastes, household products, consumer electronics, and medical wastes, some of which can be disposed in conventional landfills. The presence of this neurotoxic metal in landfills is a concern due to the potential for it to leach or volatilize from the landfill and impact local ecosystems. The objective of this review is to describe general practices for the disposal of mercury-bearing solid wastes, summarize previous studies on the release of mercury from landfills, and delineate the expected transformations of Hg within landfill environments that would influence transport of Hg via landfill gas and leachate. A few studies have documented the emissions of Hg as landfill gas, primarily as gaseous elemental Hg(0) and smaller amounts as methylated Hg species. Much less is known regarding the release of Hg in leachate. Landfill conditions are unique from other subsurface environments in that they can contain water with very high conductivity and organic carbon concentration. Landfills also experience large changes in redox potential (and the associated microbial community) that greatly influence Hg speciation, transformations, and mobilization potential. Generally, Hg is not likely to persist in large quantities as dissolved species, since Hg(0) tends to evolve in the gas phase and divalent Hg(ii) sorbs strongly to particulate phases including organic carbon and sulfides. However, Hg(ii) has the potential to associate with or form colloidal particles that can be mobilized in porous media under high organic carbon conditions. Moreover, the anaerobic conditions within landfills can foster the growth of microorganisms that produced monomethyl- and dimethyl-Hg species, the forms of mercury with high potential for bioaccumulation. Much advancement has recently been made in the mercury biogeochemistry research field, and this study seeks to incorporate these findings for landfill settings.

Environmental assessment of applicability of mineral-organic composite for landfill area rehabilitation

NASA Astrophysics Data System (ADS)

Mizerna, Kamila; Król, Anna; Mróz, Adrian

2017-10-01

This paper undertakes an assessment of the impact of a mineral-organic composite on the environment as well as the potential for its application for land rehabilitation purposes. The analysis involves the release of the leachable contaminations from the material subjected to testing. This material was formed by a composite manufactured on the basis of communal bottom ash and stabilized sewage sludge. The sludge resulting from wastewater treatment was subjected to stabilization and dehydration in waste pounds at the phase of pre-watering until 20% of dry mass is obtained. Subsequently, they were mixed with bottom ash, which was obtained from selective waste collection, in a 1:1 mass ratio. The analysis involved the leaching of inorganic contaminants in the form of heavy metals, sulphates (VI), chlorides, and fluorides as well as organic compounds in the form of organic carbon solution under the effect of leachant with a various level of pH. The analysed components were characterized by various leaching behaviour depending on the leachant pH. On the basis of the results, it was able to assess the potential hazard posed by the examined material on the environment as a consequence of its application for landfill area rehabilitation.

[Environmental and occupational problems in the utilization of industrial and home waste].

PubMed

Rusakov, N V; Rakhmanin, Iu A

2002-01-01

One of the acute hygienic problems of today is handling industrial and consumer wastes stored in Russia in the amount of 30 milliard tons; 30 million of solid garbage and 120 million tons of industrial wastes being formed. There are 4 garbage-handling and 10 garbage disposal plants built in the country. A third of them don't operate now. An absence of the initial selection in garbage collection causes the situation when only 3% of solid garbage is being processed. There is no state unified wastes recycling and utilizing system, no training of personnel to work out special technologies and do this work. Special attention should be given to medical wastes dangerous for the epidemiological situation, since they contain pathogenic microorganisms and helminth eggs; they may as well be contaminated by toxic and radioactive chemicals. A complex solution of the problems of industrial and consumer wastes handling is of vital importance for human health protection and protection of environment.

An Introduction to Biogas Production on the Farm.

ERIC Educational Resources Information Center

National Center for Appropriate Technology, Butte, MT.

This three-section report provides introductory information about biogas production and its application to farm environments. The first section discusses the various components of a biogas production system (a system that converts organic wastes into a usable form of energy), explains the system's benefits and liabilities, and provides a brief…

Commercial high-level-waste management: Options and economics. A comparative analysis of the ceramic and glass waste forms

NASA Astrophysics Data System (ADS)

McKisson, R. L.; Grantham, L. F.; Guon, J.; Recht, H. L.

1983-02-01

Results of an estimate of the waste management costs of the commercial high level waste from a 3000 metric ton per year reprocessing plant show that the judicious use of the ceramic waste form can save about $2 billion during a 20 year operating campaign relative to the use of the glass waste form. This assumes PWR fuel is processed and the waste is encapsulated in 0.305-m-diam canisters with ultimate emplacement in a BWIP-type horizontal-borehole repository. Waste loading and waste form density are the driving factors in that the low waste loading (25%) and relatively low density (3.1 g cu cm) characteristic of the glass form require several times as many canisters to handle a given waste throughput than is needed for the ceramic waste form whose waste loading capability exceeds 60% and whose waste density is nominally 5.2 cu cm.

Synthesis and Characterization of Tc(I) Carbonyl Nitrosyl Species Relevant to the Hanford Tank Waste: FY 2016 Status Report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hall, Gabriel B.; Chatterjee, Sayandev; Levitskaia, Tatiana G.

Among long-lived radioactive constituents in the Hanford tank waste, Tc presents a unique challenge in that it exists predominantly in the liquid phase, generally in the anionic form of pertechnetate, TcO 4 -, which is highly volatile at low-activity waste (LAW) vitrification melter temperatures and mobile in the Hanford site’s subsurface environment. The complex behavior of Tc under storage, treatment, and immobilization conditions significantly affects its management options, which to-date remain uncertain. In strongly alkaline environments, Tc exists as pertechnetate, TcO 4 - (oxidation state +7), and in the reduced forms (oxidation state < +7) collectively known as non-pertechnetate species.more » Pertechnetate is a well-characterized, anionic Tc species that can be removed from LAW by anion exchange or solvent extraction methods. There is no definitive information on the origin of the non-pertechnetate Tc species, nor is there a comprehensive description of their composition and behavior. It has been recently proposed that the non-pertechnetate species can comprise Tc(I) metal center and carbonyl or mixed carbonyl nitrosyl ligands stabilizing low-valent Tc. Recent work by our group has significantly expanded this previous work, generating a series of Tc(I) carbonyl compounds and demonstrating that they can be generated from reduction of TcO 4 - in the simulated Hanford tank waste in presence of CO at elevated temperature (Levitskaia et al. 2014). These results are consistent with the previous proposal that [Tc(CO) 3] + species can be present in the Hanford tank waste and suggest that the low Tc(I) oxidation state is stabilized by the π-accepting ability of the CO ligands. The continuation work has been initiated to develop model Tc carbonyl nitrosyl compounds and investigate their potential presence in the Hanford tank wastes. This report summarizes our to-date results.« less

[Impact of waste landfills in the Saratov region on the sanitary condition of the soil].

PubMed

Eremin, V N; Reshetnikov, M V; Sheshnev, A S

Monitoring of environment in regions of the location of waste landfills includes the implementation of the control over a sanitary condition of soils. The main origins of the spread ofpollutants into soils are the solid particles from aerosol emissions from the functioning of landfills transmitted to surrounding territories. Within zones of the impact of three largest waste landfills in the Saratov region (Aleksandrovsky, Guselsky in the city of Saratov and Balakovsky in the city of Balakovo) there were taken 152 soil samples. According to results of the estimation in soil concentration of gross and motile forms of heavy metals of the first (Zn, Cd, Ni) and the second danger classes (Cu, Cr, Pb) there was performed the analysis of coefficients of danger- K0 and total coefficients ofpollution - Zc. There was executed the assessment of both a sanitary and hygienic condition of soils and degree of danger ofpollution. The most contrast areal features of the distribution of the danger coefficient - Ko in soils are characteristic for motile forms of heavy metals. For all three studied objects persistently there is stood out the dangerous and areal pollution of soils by association of Ni and Cu . The danger ofpollution of soils by gross forms of heavy metals is minimum. The coefficient of total pollution of Zc exceeds admissible level on motile forms of heavy metals only for the soils surrounding the Balakovo landfill. In zones of the impact of waste landfills there are located the processed lands with an adverse sanitary and hygienic condition of soils. In the region of the Guselsky object soils of the processed agricultural grounds are dangerously polluted by motile forms of Ni and Cu. In vicinities of the Balakovo waste landfill considerable areas of private gardening enterprises are dangerously polluted by the motile forms of Ni, Cu and Zn.

Mechanisms of iodine release from iodoapatite in aqueous solution

NASA Astrophysics Data System (ADS)

Zhang, Z.; Wang, J.

2017-12-01

Immobilization of iodine-129 with waste forms in geological setting is challenging due to its extremely long half-life and high volatility in the environment. To evaluate the long-term performance of waste form, it is imperative to determine the release mechanism of iodine hosted in the waste form materials. This study investigated the iodine released from apatite structured waste form Pb9.85 (VO4)6 I1.7 to understand how diffusion and dissolution control the durability of apatite waste form. A standard semi-dynamic leach test was adopted in this study. Samples were exposed in fresh leachant periodically and the leachant was replaced after each interval. Each experiment was carried out in cap-sealed Teflon vessels under constant temperature (e.g. 90 °C). ICP-MS analysis on the reacted leachates shows that Pb and V were released constantly and congruently with the stoichiometric ratio of Pb/V. However, iodine release is incongruent and time dependent. The iodine release rate starts significantly higher than the corresponding stoichiometric value and gradually decreases, approaching the stoichiometric value. Therefore, a dual-mode mechanism is proposed to account for the iodine release from apatite, which is dominated by short-term diffusion and long-term dissolution processes. Additional tests show that the element release rates depend on a number of test parameters, including sample surface to solution volume ratio (m-1), interval (day), temperature (°C), and solution pH. This study provides a quantitative characterization of iodine release mechanism. The activation energy of iodine leaching 21±1.6 kJ/mol was obtained by varying the test temperature. At the test conditions of to neutral pH and 90 °C, the long-term iodine release rate 3.3 mg/(m2 • day) is projected by normalizing sample surface area to solution volume ratio (S/V) to 1.0 m-1 and interval to 1 day. These findings demonstrate i) the feasibility of our approach to quantify the release mechanism and ii) the performance of iodine apatite as a favorable waste form candidate for I-129 disposal.

Localized chemistry of 99Tc in simulated low activity waste glass

NASA Astrophysics Data System (ADS)

Weaver, Jamie L.

A priority of the United States Department of Energy (DOE) is to dispose of the nuclear waste accumulated in the underground tanks at the Hanford Nuclear Reservation in Richland, WA. Incorporation and stabilization of technetium (99Tc) from these tanks into vitrified waste forms is a concern to the waste glass community and DOE due to 99Tc's long half-life ( 2.13˙105 y), and its high mobility in the subsurface environment under oxidizing conditions. Working in collaboration with researchers at Pacific Northwest National Laboratory (PNNL) and other national laboratories, plans were formulated to obtain first-of-a-kind chemical structure determination of poorly understood and environmentally relevant technetium compounds that relate to the chemistry of the Tc in nuclear waste glasses. Knowledge of the structure and spectral signature of these compounds aid in refining the understanding of 99Tc incorporation into and release from oxide based waste glass. In this research a first-of-its kind mechanism for the behavior of 99Tc during vitrification is presented, and the structural role of Tc(VII) and (IV) in borosilicate waste glasses is readdressed.

Iron (III) Matrix Effects on Mineralization and Immobilization of Actinides

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cynthia-May S. Gong; Tyler A. Sullens; Kenneth R. Czerwinski

2006-01-01

Abstract - A number of models for the Yucca Mountain Project nuclear waste repository use studies of actinide sorption onto well-defined iron hydroxide materials. In the case of a waste containment leak, however, a complex interaction between dissolved waste forms and failed containment vessel components can lead to immediate precipitation of migratory iron and uranyl in the silicate rich near-field environment. Use of the Fe(III) and UO22+ complexing agent acetohydroxamic acid (AHA) as a colorimetric agent for visible spectrophotometry is well-known. Using the second derivative of these spectra a distinct shift in iron complexation in the presence of silicate ismore » seen that is not seen with uranyl or alone. Silica also decreases the ability of uranyl and ferric solutions to absorb hydroxide, hastening precipitation. These ferric silicate precipitates are highly amorphous and soluble. Precipitates formed in the presence of uranyl below ~1 mol% exhibit lower solubility than precipitates from up to 50 mol % and of uranyl silicates alone.« less

Structure and thermodynamics of uranium-containing iron garnets

NASA Astrophysics Data System (ADS)

Guo, Xiaofeng; Navrotsky, Alexandra; Kukkadapu, Ravi K.; Engelhard, Mark H.; Lanzirotti, Antonio; Newville, Matthew; Ilton, Eugene S.; Sutton, Stephen R.; Xu, Hongwu

2016-09-01

Use of crystalline garnet as a waste form phase appears to be advantageous for accommodating actinides from nuclear waste. Previous studies show that large amounts of uranium (U) and its analogues such as cerium (Ce) and thorium (Th) can be incorporated into the garnet structure. In this study, we synthesized U loaded garnet phases, Ca3UxZr2-xFe3O12 (x = 0.5-0.7), along with the endmember phase, Ca3(Zr2)SiFe3+2O12, for comparison. The oxidation states of U were determined by X-ray photoelectron and absorption spectroscopies, revealing the presence of mixed pentavalent and hexavalent uranium in the phases with x = 0.6 and 0.7. The oxidation states and coordination environments of Fe were measured using transmission 57Fe-Mössbauer spectroscopy, which shows that all iron is tetrahedrally coordinated Fe3+. U substitution had a significant effect on local environments, the extent of U substitution within this range had a minimal effect on the structure, and unlike in the x = 0 sample, Fe exists in two different environments in the substituted garnets. The enthalpies of formation of garnet phases from constituent oxides and elements were first time determined by high temperature oxide melt solution calorimetry. The results indicate that these substituted garnets are thermodynamically stable under reducing conditions. Our structural and thermodynamic analysis further provides explanation for the formation of natural uranium garnet, elbrusite-(Zr), and supports the potential use of Ca3UxZr2-xFe3O12 as viable waste form phases for U and other actinides.

Treatment of waste printed wire boards in electronic waste for safe disposal.

PubMed

Niu, Xiaojun; Li, Yadong

2007-07-16

The printed wire boards (PWBs) in electronic waste (E-waste) have been found to contain large amounts of toxic substances. Studies have concluded that the waste PWBs are hazardous wastes because they fails the toxicity characteristic leaching procedure (TCLP) test with high level of lead (Pb) leaching out. In this study, two treatment methods - high-pressure compaction and cement solidification - were explored for rendering the PWBs into non-hazardous forms so that they may be safely disposed or used. The high-pressure compaction method could turn the PWBs into high-density compacts with significant volume reduction, but the impact resistance of the compacts was too low to keep them intact in the environment for a long run. In contrast, the cement solidification could turn the PWBs into strong monoliths with high impact resistance and relatively high compressive strength. The leaching of the toxic heavy metal Pb from the solidified samples was evaluated by both a dynamic leaching test and the TCLP test. The dynamic leaching results revealed that Pb could be effectively confined in the solidified products under very harsh environmental conditions. The TCLP test results showed that the leaching level of Pb was far below the regulatory level of 5mg/L, suggesting that the solidified PWBs are no longer hazardous. It was concluded that the cement solidification is an effective way to render the waste PWBs into environmentally benign forms so that they can be disposed of as ordinary solid wastes or beneficially used in the place of concrete in some applications.

Straight-chain halocarbon forming fluids for TRISO fuel kernel production - Tests with yttria-stabilized zirconia microspheres

NASA Astrophysics Data System (ADS)

Baker, M. P.; King, J. C.; Gorman, B. P.; Braley, J. C.

2015-03-01

Current methods of TRISO fuel kernel production in the United States use a sol-gel process with trichloroethylene (TCE) as the forming fluid. After contact with radioactive materials, the spent TCE becomes a mixed hazardous waste, and high costs are associated with its recycling or disposal. Reducing or eliminating this mixed waste stream would not only benefit the environment, but would also enhance the economics of kernel production. Previous research yielded three candidates for testing as alternatives to TCE: 1-bromotetradecane, 1-chlorooctadecane, and 1-iodododecane. This study considers the production of yttria-stabilized zirconia (YSZ) kernels in silicone oil and the three chosen alternative formation fluids, with subsequent characterization of the produced kernels and used forming fluid. Kernels formed in silicone oil and bromotetradecane were comparable to those produced by previous kernel production efforts, while those produced in chlorooctadecane and iodododecane experienced gelation issues leading to poor kernel formation and geometry.

40 CFR 148.10 - Waste specific prohibitions-solvent wastes.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 24 2013-07-01 2013-07-01 false Waste specific prohibitions-solvent wastes. 148.10 Section 148.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) HAZARDOUS WASTE INJECTION RESTRICTIONS Prohibitions on Injection § 148.10 Waste...

40 CFR 148.10 - Waste specific prohibitions-solvent wastes.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 24 2012-07-01 2012-07-01 false Waste specific prohibitions-solvent wastes. 148.10 Section 148.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) HAZARDOUS WASTE INJECTION RESTRICTIONS Prohibitions on Injection § 148.10 Waste...

Experimental evidence of colloids and nanoparticles presence from 25 waste leachates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hennebert, Pierre, E-mail: pierre.hennebert@ineris.fr; Avellan, Astrid; Yan, Junfang

Highlights: • This work is the first assessment of colloids in waste leachates. • Analytical methods are proposed and discussed. • All the waste have at least one element in colloidal form, and some elements are always colloidal. • Man-made nanoparticles are observed. • It can change the interpretation of leachate elemental concentration. - Abstract: The potential colloids release from a large panel of 25 solid industrial and municipal waste leachates, contaminated soil, contaminated sediments and landfill leachates was studied. Standardized leaching, cascade filtrations and measurement of element concentrations in the microfiltrate (MF) and ultrafiltrate (UF) fraction were used tomore » easily detect colloids potentially released by waste. Precautions against CO{sub 2} capture by alkaline leachates, or bacterial re-growth in leachates from wastes containing organic matter should be taken. Most of the colloidal particles were visible by transmission electron microscopy with energy dispersion spectrometry (TEM–EDS) if their elemental MF concentration is greater than 200 μg l{sup −1}. If the samples are dried during the preparation for microscopy, neoformation of particles can occur from the soluble part of the element. Size distribution analysis measured by photon correlation spectroscopy (PCS) were frequently unvalid, particularly due to polydispersity and/or too low concentrations in the leachates. A low sensitivity device is required, and further improvement is desirable in that field. For some waste leachates, particles had a zeta potential strong enough to remain in suspension. Mn, As, Co, Pb, Sn, Zn had always a colloidal form (MF concentration/UF concentration > 1.5) and total organic carbon (TOC), Fe, P, Ba, Cr, Cu, Ni are partly colloidal for more than half of the samples). Nearly all the micro-pollutants (As, Ba, Co, Cr, Cu, Mo, Ni, Pb, Sb, Sn, V and Zn) were found at least once in colloidal form greater than 100 μg l{sup −1}. In particular, the colloidal forms of Zn were always by far more concentrated than its dissolved form. The TEM–EDS method showed various particles, including manufactured nanoparticles (organic polymer, TiO{sub 2}, particles with Sr, La, Ce, Nd). All the waste had at least one element detected as colloidal. The solid waste leachates contained significant amount of colloids different in elemental composition from natural ones. The majority of the elements were in colloidal form for wastes of packaging (3), a steel slag, a sludge from hydrometallurgy, composts (2), a dredged sediment (#18), an As contaminated soil and two active landfill leachates. These results showed that cascade filtration and ICP elemental analysis seems valid methods in this field, and that electronic microscopy with elemental detection allows to identify particles. Particles can be formed from dissolved elements during TEM sample preparation and cross-checking with MF and UF composition by ICP is useful. The colloidal fraction of leachate of waste seems to be a significant source term, and should be taken into account in studies of emission and transfer of contaminants in the environment. Standardized cross-filtration method could be amended for the presence of colloids in waste leachates.« less

40 CFR 268.30 - Waste specific prohibitions-wood preserving wastes.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Waste specific prohibitions-wood preserving wastes. 268.30 Section 268.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... specific prohibitions—wood preserving wastes. (a) Effective August 11, 1997, the following wastes are...

40 CFR 268.30 - Waste specific prohibitions-wood preserving wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Waste specific prohibitions-wood preserving wastes. 268.30 Section 268.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... specific prohibitions—wood preserving wastes. (a) Effective August 11, 1997, the following wastes are...

40 CFR 268.31 - Waste specific prohibitions-Dioxin-containing wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Waste specific prohibitions-Dioxin-containing wastes. 268.31 Section 268.31 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.31 Waste...

40 CFR 268.31 - Waste specific prohibitions-Dioxin-containing wastes.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 27 2014-07-01 2014-07-01 false Waste specific prohibitions-Dioxin-containing wastes. 268.31 Section 268.31 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.31 Waste...

40 CFR 268.31 - Waste specific prohibitions-Dioxin-containing wastes.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 28 2013-07-01 2013-07-01 false Waste specific prohibitions-Dioxin-containing wastes. 268.31 Section 268.31 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.31 Waste...

40 CFR 268.31 - Waste specific prohibitions-Dioxin-containing wastes.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Waste specific prohibitions-Dioxin-containing wastes. 268.31 Section 268.31 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.31 Waste...

40 CFR 268.31 - Waste specific prohibitions-Dioxin-containing wastes.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 28 2012-07-01 2012-07-01 false Waste specific prohibitions-Dioxin-containing wastes. 268.31 Section 268.31 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.31 Waste...

Immobilization of Technetium in a Metallic Waste Form

DOE Office of Scientific and Technical Information (OSTI.GOV)

S.M. Frank; D. D. Keiser, Jr.; K. C. Marsden

Fission-product technetium accumulated during treatment of spent nuclear fuel will ultimately be disposed of in a geological repository. The exact form of Tc for disposal has yet to be determined; however, a reasonable solution is to incorporate elemental Tc into a metallic waste form similar to the waste form produced during the pyrochemical treatment of spent, sodium-bonded fuel. This metal waste form, produced at the Idaho National Laboratory, has undergone extensive qualification examination and testing for acceptance to the Yucca Mountain geological repository. It is from this extensive qualification effort that the behavior of Tc and other fission products inmore » the waste form has been elucidated, and that the metal waste form is extremely robust in the retention of fission products, such as Tc, in repository like conditions. This manuscript will describe the metal waste form, the behavior of Tc in the waste form; and current research aimed at determining the maximum possible loading of Tc into the metal waste and subsequent determination of the performance of high Tc loaded metal waste forms.« less

Secondary Waste Form Down Selection Data Package – Ceramicrete

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cantrell, Kirk J.; Westsik, Joseph H.

2011-08-31

As part of high-level waste pretreatment and immobilized low activity waste processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed in the Integrated Disposal Facility. Currently, four waste forms are being considered for stabilization and solidification of the liquid secondary wastes. These waste forms are Cast Stone, Ceramicrete, DuraLith, and Fluidized Bed Steam Reformer. The preferred alternative will be down selected from these four waste forms. Pacific Northwest National Laboratorymore » is developing data packages to support the down selection process. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilization and solidification of the liquid secondary wastes. The information included will be based on information available in the open literature and from data obtained from testing currently underway. This data package is for the Ceramicrete waste form. Ceramicrete is a relatively new engineering material developed at Argonne National Laboratory to treat radioactive and hazardous waste streams (e.g., Wagh 2004; Wagh et al. 1999a, 2003; Singh et al. 2000). This cement-like waste form can be used to treat solids, liquids, and sludges by chemical immobilization, microencapsulation, and/or macroencapsulation. The Ceramicrete technology is based on chemical reaction between phosphate anions and metal cations to form a strong, dense, durable, low porosity matrix that immobilizes hazardous and radioactive contaminants as insoluble phosphates and microencapsulates insoluble radioactive components and other constituents that do not form phosphates. Ceramicrete is a type of phosphate-bonded ceramic, which are also known as chemically bonded phosphate ceramics. The Ceramicrete binder is formed through an acid-base reaction between calcined magnesium oxide (MgO; a base) and potassium hydrogen phosphate (KH{sub 2}PO{sub 4}; an acid) in aqueous solution. The reaction product sets at room temperature to form a highly crystalline material. During the reaction, the hazardous and radioactive contaminants also react with KH{sub 2}PO{sub 4} to form highly insoluble phosphates. In this data package, physical property and waste acceptance data for Ceramicrete waste forms fabricated with wastes having compositions that were similar to those expected for secondary waste effluents, as well as secondary waste effluent simulants from the Hanford Tank Waste Treatment and Immobilization Plant were reviewed. With the exception of one secondary waste form formulation (25FA+25 W+1B.A. fabricated with the mixed simulant did not meet the compressive strength requirement), all the Ceramicrete waste forms that were reviewed met or exceeded Integrated Disposal Facility waste acceptance criteria.« less

Spectroscopic Properties of Tc(I) Tricarbonyl Species Relevant to the Hanford Tank Waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Levitskaia, Tatiana G.; Andersen, Amity; Chatterjee, Sayandev

2015-12-04

Technetium-99 (Tc) exists predominately in soluble forms in the liquid supernatant and salt cake fractions of the nuclear tank waste stored at the U.S. DOE Hanford Site. In the strongly alkaline environments prevalent in the tank waste, its dominant chemical form is pertechnetate (TcO4-, oxidation state +7). However, attempts to remove Tc from the Hanford tank waste using ion-exchange processes specific to TcO 4 - only met with limited success, particularly processing tank waste samples containing elevated concentrations of organic complexants. This suggests that a significant fraction of the soluble Tc can be present as non-pertechnetate low-valent Tc (oxidation statemore » < +7) (non-pertechnetate). The chemical identities of these non-pertechnetate species are poorly understood. Previous analysis of the SY-101 and SY-103 tank waste samples provided strong evidence that non-pertechnetate can be comprised of [Tc(CO) 3] + complexes containing Tc in oxidation state +1 (Lukens et al. 2004). During the last two years, our team has expanded this work and demonstrated that high-ionic-strength solutions typifying tank waste supernatants promote oxidative stability of the [Tc(CO) 3] + species (Rapko et al. 2013; Levitskaia et al. 2014). It also was observed that high-ionic-strength alkaline matrices stabilize Tc(VI) and potentially Tc(IV) oxidation states, particularly in presence organic chelators, suggesting that the relevant Tc compounds can serve as important redox intermediates facilitating the reduction of Tc(VII) to Tc(I). Designing strategies for effective Tc processing, including separation and immobilization, necessitates understanding the molecular structure of these non-pertechnetate species and their identification in the actual tank waste samples. To-date, only limited information exists regarding the nature and characterization of the Tc(I), Tc(IV), and Tc(VI) species. One objective of this project is to identify the form of non-pertechnetate in the Hanford waste. To do this, we are developing a spectral library of reference non-pertechnetate compounds that can be compared against actual waste samples. The emphasis of the fiscal year 2015 work was Tc(I) tricarbonyl [Tc(CO) 3] + compounds. The key findings are summarized below.« less

Radionuclide Incorporation and Long Term Performance of Apatite Waste Forms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Jianwei; Lian, Jie; Gao, Fei

2016-01-04

This project aims to combines state-of-the-art experimental and characterization techniques with atomistic simulations based on density functional theory (DFT) and molecular dynamics (MD) simulations. With an initial focus on long-lived I-129 and other radionuclides such as Cs, Sr in apatite structure, specific research objectives include the atomic scale understanding of: (1) incorporation behavior of the radionuclides and their effects on the crystal chemistry and phase stability; (2) stability and microstructure evolution of designed waste forms under coupled temperature and radiation environments; (3) incorporation and migration energetics of radionuclides and release behaviors as probed by DFT and molecular dynamics (MD) simulations;more » and (4) chemical durability as measured in dissolution experiments for long term performance evaluation and model validation.« less

Novel function of polyaniline for biological environments: Cultivation of paramecium in the presence of polyaniline

NASA Astrophysics Data System (ADS)

Goto, Hiromasa

2014-03-01

The reduced form of polyaniline (PANI, emeraldine base) functions as water purification to extend the lives of paramecia. The emeraldine base can absorb discharged waste from the planktons such as nitrogenous compounds and salts. This is a new function of π-conjugated polymers for micro-organisms.

40 CFR 270.66 - Permits for boilers and industrial furnaces burning hazardous waste.

Code of Federal Regulations, 2011 CFR

2011-07-01

... blended, and blending ratios. (3) A detailed engineering description of the boiler or industrial furnace... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Permits for boilers and industrial... PROGRAM Special Forms of Permits § 270.66 Permits for boilers and industrial furnaces burning hazardous...

40 CFR 270.66 - Permits for boilers and industrial furnaces burning hazardous waste.

Code of Federal Regulations, 2013 CFR

2013-07-01

... blended, and blending ratios. (3) A detailed engineering description of the boiler or industrial furnace... 40 Protection of Environment 28 2013-07-01 2013-07-01 false Permits for boilers and industrial... PROGRAM Special Forms of Permits § 270.66 Permits for boilers and industrial furnaces burning hazardous...

40 CFR 270.66 - Permits for boilers and industrial furnaces burning hazardous waste.

Code of Federal Regulations, 2012 CFR

2012-07-01

... blended, and blending ratios. (3) A detailed engineering description of the boiler or industrial furnace... 40 Protection of Environment 28 2012-07-01 2012-07-01 false Permits for boilers and industrial... PROGRAM Special Forms of Permits § 270.66 Permits for boilers and industrial furnaces burning hazardous...

40 CFR 270.66 - Permits for boilers and industrial furnaces burning hazardous waste.

Code of Federal Regulations, 2014 CFR

2014-07-01

... blended, and blending ratios. (3) A detailed engineering description of the boiler or industrial furnace... 40 Protection of Environment 27 2014-07-01 2014-07-01 false Permits for boilers and industrial... PROGRAM Special Forms of Permits § 270.66 Permits for boilers and industrial furnaces burning hazardous...

40 CFR 270.66 - Permits for boilers and industrial furnaces burning hazardous waste.

Code of Federal Regulations, 2010 CFR

2010-07-01

... blended, and blending ratios. (3) A detailed engineering description of the boiler or industrial furnace... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Permits for boilers and industrial... PROGRAM Special Forms of Permits § 270.66 Permits for boilers and industrial furnaces burning hazardous...

Performance Test on Polymer Waste Form - 12137

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lee, Se Yup

Polymer solidification was attempted to produce stable waste form for the boric acid concentrates and the dewatered spent resins. The polymer mixture was directly injected into the mold or drum which was packed with the boric acid concentrates and the dewatered spent resins, respectively. The waste form was produced by entirely curing the polymer mixture. A series of performance tests was conducted including compressive strength test, water immersion test, leach test, thermal stability test, irradiation stability test and biodegradation stability test for the polymer waste forms. From the results of the performance tests for the polymer waste forms, it ismore » believed that the polymer waste form is very stable and can satisfy the acceptance criteria for permanent disposal. At present, performance tests with full scale polymer waste forms are being carried out in order to obtain qualification certificate by the regulatory institute in Korea. Polymer waste forms were prepared with the surrogate of boric acid concentrates and the surrogate of spent ion exchange resins respectively. Waste forms were also made in lab scale and in full scale. Lab. scale waste forms were directly subjected to a series of the performance tests. In the case of full scale waste form, the test specimens for the performance test were taken from a part of waste form by coring. A series of performance tests was conducted including compressive strength test, thermal stability test, irradiation stability test and biodegradation stability test, water immersion test, leach test, and free standing water for the polymer waste forms. In addition, a fire resistance test was performed on the waste forms by the requirement of the regulatory institute in Korea. Every polymer waste forms containing the boric acid concentrates and the spent ion exchange resins had exhibited excellent structural integrity of more than 27.58 MPa (4,000 psi) of compressive strength. On thermal stability testing, biodegradation testing and water immersion testing, no degradation was observed in the waste forms. Also, by measuring the compressive strength after these tests, it was confirmed that the structural integrity was still retained. A leach test was performed by using non radioactive cobalt, cesium and strontium. The leaching of cobalt, cesium and strontium from the polymer waste forms was very low. Also, the polymer waste forms were found to possess adequate fire resistance. From the results of the performance tests, it is believed that the polymer waste form is very stable and can satisfy the acceptance criteria for permanent disposal. At present, Performance tests with full scale polymer waste forms are on-going in order to obtain qualification certificate by the regulatory institute in Korea. (authors)« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mollah, A.S.

Low level radioactive waste (LLW) is generated from various nuclear applications in Bangladesh. The major sources of radioactive waste in the country are at present: (a) the 3 MW TRIGA Mark-II research reactor; (b) the radioisotope production facility; (c) the medical, industrial and research facilities that use radionuclides; and (d) the industrial facility for processing monazite sands. Radioactive waste needs to be safely managed because it is potentially hazardous to human health and the environment. According to Nuclear Safety and Radiation Control Act-93, the Bangladesh Atomic Energy Commission (BAEC) is the governmental body responsible for the receipt and final disposalmore » of radioactive wastes in the whole country. Waste management policy has become an important environmental, social, and economical issue for LLW in Bangladesh. Policy and strategies will serve as a basic guide for radioactive waste management in Bangladesh. The waste generator is responsible for on-site collection, conditioning and temporary storage of the waste arising from his practice. The Central Waste Processing and Storage Unit (CWPSU) of BAEC is the designated national facility with the requisite facility for the treatment, conditioning and storage of radioactive waste until a final disposal facility is established and becomes operational. The Regulatory Authority is responsible for the enforcement of compliance with provisions of the waste management regulation and other relevant requirements by the waste generator and the CWPSU. The objective of this paper is to present, in a concise form, basic information about the radioactive waste management infrastructure, regulations, policies and strategies including the total inventory of low level radioactive waste in the country. For improvement and strengthening in terms of operational capability, safety and security of RW including spent radioactive sources and overall security of the facility (CWPSF), the facility is expected to serve waste management need in the country and, in the course of time, the facility may be turned into a regional level training centre. It is essential for safe conduction and culture of research and application in nuclear science and technology maintaining the relevant safety of man and environment and future generations to come. (authors)« less

Pattern of Cleanliness with Technology Intervention for Innovation Life

NASA Astrophysics Data System (ADS)

Hutari Mulyani, Sitti; Hendrik, Billy; Andhika Putra, Rio; Masril, Mardhiah

2017-12-01

Environmental solutions around the world today are making people dependent on technological developments. However, the technology cannot be separated from the community either in the form or its influence, therefore the pattern of behavior of society must also get arrangements for technology to occur as an acceleration of life done properly. This study aims to obtain patterns of community behavior on non-organic waste by using technology intervention. Gap exploration is essential for theoretical and experimental analysis of humans who dispose of unorganic and organic waste out of place. But the field of behavior analysis is uniquely tailored to contribute to this body of work. Sustainable development depends on changing technology to achieve its goals. We report on data collected form an on-line survey, which possible solutions for trash problems. In this paper we present an integrated waste management system with IT that we called I-BSC (Indonesia Bersih (Clean), Sehat (Healty) and Cerdas (Smart)). This I-BSC is not only for deposit bottles and systems but the system aims also to create awareness of waste production and management, which serves as an educational platform in urban environments for further life innovation.

A new route to the stable capture and final immobilization of radioactive cesium.

PubMed

Yang, Jae Hwan; Han, Ahreum; Yoon, Joo Young; Park, Hwan-Seo; Cho, Yung-Zun

2017-10-05

Radioactive Cs released from damaged fuel materials in the event of nuclear accidents must be controlled to prevent the spreading of hazardous Cs into the environment. This study describes a simple and novel process to safely manage Cs gas by capturing it within ceramic filters and converting it into monolithic waste forms. The results of Cs trapping tests showed that CsAlSiO 4 was a reaction product of gas-solid reactions between Cs gas and our ceramic filters. Monolithic waste forms were readily prepared from the Cs-trapping filters by the addition of a glass frit followed by thermal treatment at 1000°C for 3h. Major findings revealed that the Cs-trapping filters could be added up to 50wt% to form durable monoliths. In 30-50wt% of waste fraction, CsAlSiO 4 was completely converted to pollucite (CsAlSi 2 O 6 ), which is a potential phase for radioactive Cs due to its excellent thermal and chemical stability. A static leaching test for 28 d confirmed the excellent chemical resistance of the pollucite structure, with a Cs leaching rate as low as 7.21×10 -5 gm -2 /d. This simple scheme of waste processing promises a new route for radioactive Cs immobilization by synthesizing pollucite-based monoliths. Copyright © 2017 Elsevier B.V. All rights reserved.

40 CFR 260.30 - Non-waste determinations and variances from classification as a solid waste.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Non-waste determinations and variances from classification as a solid waste. 260.30 Section 260.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking...

40 CFR 148.15 - Waste specific prohibitions-second third wastes.

Code of Federal Regulations, 2014 CFR

2014-07-01

... facilities. (e) Effective June 8, 1991, the waste specified in 40 CFR 261.32 as EPA Hazardous Waste number... 40 Protection of Environment 23 2014-07-01 2014-07-01 false Waste specific prohibitions-second third wastes. 148.15 Section 148.15 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 148.15 - Waste specific prohibitions-second third wastes.

Code of Federal Regulations, 2012 CFR

2012-07-01

... facilities. (e) Effective June 8, 1991, the waste specified in 40 CFR 261.32 as EPA Hazardous Waste number... 40 Protection of Environment 24 2012-07-01 2012-07-01 false Waste specific prohibitions-second third wastes. 148.15 Section 148.15 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 260.30 - Non-waste determinations and variances from classification as a solid waste.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Non-waste determinations and variances from classification as a solid waste. 260.30 Section 260.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking...

40 CFR 260.30 - Non-waste determinations and variances from classification as a solid waste.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Non-waste determinations and variances from classification as a solid waste. 260.30 Section 260.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking...

40 CFR 148.15 - Waste specific prohibitions-second third wastes.

Code of Federal Regulations, 2013 CFR

2013-07-01

... facilities. (e) Effective June 8, 1991, the waste specified in 40 CFR 261.32 as EPA Hazardous Waste number... 40 Protection of Environment 24 2013-07-01 2013-07-01 false Waste specific prohibitions-second third wastes. 148.15 Section 148.15 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

A fuzzy chance-constrained programming model with type 1 and type 2 fuzzy sets for solid waste management under uncertainty

NASA Astrophysics Data System (ADS)

Ma, Xiaolin; Ma, Chi; Wan, Zhifang; Wang, Kewei

2017-06-01

Effective management of municipal solid waste (MSW) is critical for urban planning and development. This study aims to develop an integrated type 1 and type 2 fuzzy sets chance-constrained programming (ITFCCP) model for tackling regional MSW management problem under a fuzzy environment, where waste generation amounts are supposed to be type 2 fuzzy variables and treated capacities of facilities are assumed to be type 1 fuzzy variables. The evaluation and expression of uncertainty overcome the drawbacks in describing fuzzy possibility distributions as oversimplified forms. The fuzzy constraints are converted to their crisp equivalents through chance-constrained programming under the same or different confidence levels. Regional waste management of the City of Dalian, China, was used as a case study for demonstration. The solutions under various confidence levels reflect the trade-off between system economy and reliability. It is concluded that the ITFCCP model is capable of helping decision makers to generate reasonable waste-allocation alternatives under uncertainties.

40 CFR 148.5 - Waste analysis.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Waste analysis. 148.5 Section 148.5 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) HAZARDOUS WASTE INJECTION RESTRICTIONS General § 148.5 Waste analysis. Generators of hazardous wastes that are...

40 CFR 262.27 - Waste minimization certification.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Waste minimization certification. 262.27 Section 262.27 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE The Manifest § 262.27 Waste minimization...

40 CFR 262.27 - Waste minimization certification.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Waste minimization certification. 262.27 Section 262.27 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE The Manifest § 262.27 Waste minimization...

40 CFR 262.27 - Waste minimization certification.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Waste minimization certification. 262.27 Section 262.27 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE The Manifest § 262.27 Waste minimization...

40 CFR 262.27 - Waste minimization certification.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Waste minimization certification. 262.27 Section 262.27 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE The Manifest § 262.27 Waste minimization...

40 CFR 262.27 - Waste minimization certification.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Waste minimization certification. 262.27 Section 262.27 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE The Manifest § 262.27 Waste minimization...

40 CFR 148.5 - Waste analysis.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 23 2011-07-01 2011-07-01 false Waste analysis. 148.5 Section 148.5 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) HAZARDOUS WASTE INJECTION RESTRICTIONS General § 148.5 Waste analysis. Generators of hazardous wastes that are...

Electrochemical Corrosion Studies for Modeling Metallic Waste Form Release Rates

DOE Office of Scientific and Technical Information (OSTI.GOV)

Poineau, Frederic; Tamalis, Dimitri

The isotope 99Tc is an important fission product generated from nuclear power production. Because of its long half-life (t 1/2 = 2.13 ∙ 10 5 years) and beta-radiotoxicity (β⁻ = 292 keV), it is a major concern in the long-term management of spent nuclear fuel. In the spent nuclear fuel, Tc is present as an alloy with Mo, Ru, Rh, and Pd called the epsilon-phase, the relative amount of which increases with fuel burn-up. In some separation schemes for spent nuclear fuel, Tc would be separated from the spent fuel and disposed of in a durable waste form. Technetium wastemore » forms under consideration include metallic alloys, oxide ceramics and borosilicate glass. In the development of a metallic waste form, after separation from the spent fuel, Tc would be converted to the metal, incorporated into an alloy and the resulting waste form stored in a repository. Metallic alloys under consideration include Tc–Zr alloys, Tc–stainless steel alloys and Tc–Inconel alloys (Inconel is an alloy of Ni, Cr and iron which is resistant to corrosion). To predict the long-term behavior of the metallic Tc waste form, understanding the corrosion properties of Tc metal and Tc alloys in various chemical environments is needed, but efforts to model the behavior of Tc metallic alloys are limited. One parameter that should also be considered in predicting the long-term behavior of the Tc waste form is the ingrowth of stable Ru that occurs from the radioactive decay of 99Tc ( 99Tc → 99Ru + β⁻). After a geological period of time, significant amounts of Ru will be present in the Tc and may affect its corrosion properties. Studying the effect of Ru on the corrosion behavior of Tc is also of importance. In this context, we studied the electrochemical behavior of Tc metal, Tc-Ni alloys (to model Tc-Inconel alloy) and Tc-Ru alloys in acidic media. The study of Tc-U alloys has also been performed in order to better understand the nature of Tc in metallic spent fuel. Computational modeling and simulations were performed to shed light on experimental results and explain structural and kinetics trends.« less

Improvement of nuclide leaching resistance of paraffin waste form with low density polyethylene.

PubMed

Kim, Chang Lak; Park, Joo Wan; Kim, Ju Youl; Chung, Chang Hyun

2002-01-01

Low-level liquid borate wastes have been immobilized with paraffin wax using a concentrate waste drying system (CWDS) in Korean nuclear power plants. The possibility for improving chemical durability of paraffin waste form was suggested in this study. A small amount of low density polyethylene (LDPE) was added to increase the leaching resistance of the existing paraffin waste form. The influence of LDPE on the leaching behavior of waste form was investigated by performing leaching test according to ANSI/ANS-16.1 procedure during 325 days. It was observed that the leaching of nuclides immobilized within paraffin waste form made a marked reduction although little content of LDPE was added to waste form. The acceptance criteria of paraffin waste form associated with leachability index (LI) and compressive strength after the leaching test were fully satisfied with the help of LDPE.

Formation of Hydrochemical River Regime Under Extreme Contamination by Waste Water (the Sak-Elga River in the Chelyabinsk Region)

NASA Astrophysics Data System (ADS)

Denisov, S. E.; Ulrikh, D. V.; Zhbankov, G. O.

2017-11-01

Modern technologies designed to use natural resources in different ways are applied to restructure the environment. The use of technologies results in the deformation of environment, its local, regional and global changes occur. In the course of mining the spaces disturbed by the mine opening rock heaps and processing wastes are formed and rapidly appear. These spaces are dead surfaces the negative effect of which extends to the surrounding areas. Thus, the indirect impact on the lands connected with the change of the condition and regime of the surface and groundwater, settling of dust and chemical compounds from emissions to the atmosphere as well as the products of wind and water erosion lead to deterioration in the quality of the lands, surface and groundwater resources in the area affected by mining.

40 CFR 148.11 - Waste specific prohibitions-dioxin-containing wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Waste specific prohibitions-dioxin-containing wastes. 148.11 Section 148.11 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) HAZARDOUS WASTE INJECTION RESTRICTIONS Prohibitions on Injection § 148.11...

40 CFR 148.17 - Waste specific prohibitions; newly listed wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Waste specific prohibitions; newly listed wastes. 148.17 Section 148.17 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) HAZARDOUS WASTE INJECTION RESTRICTIONS Prohibitions on Injection § 148.17...

40 CFR 148.14 - Waste specific prohibitions-first third wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Waste specific prohibitions-first third wastes. 148.14 Section 148.14 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) HAZARDOUS WASTE INJECTION RESTRICTIONS Prohibitions on Injection § 148.14...

40 CFR 148.12 - Waste specific prohibitions-California list wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Waste specific prohibitions-California list wastes. 148.12 Section 148.12 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) HAZARDOUS WASTE INJECTION RESTRICTIONS Prohibitions on Injection § 148.12...

40 CFR 148.18 - Waste specific prohibitions-newly listed and identified wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Waste specific prohibitions-newly listed and identified wastes. 148.18 Section 148.18 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) HAZARDOUS WASTE INJECTION RESTRICTIONS Prohibitions on...

40 CFR 148.15 - Waste specific prohibitions-second third wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Waste specific prohibitions-second third wastes. 148.15 Section 148.15 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) HAZARDOUS WASTE INJECTION RESTRICTIONS Prohibitions on Injection § 148.15...

40 CFR 148.16 - Waste specific prohibitions-third third wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Waste specific prohibitions-third third wastes. 148.16 Section 148.16 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) HAZARDOUS WASTE INJECTION RESTRICTIONS Prohibitions on Injection § 148.16...

40 CFR 271.11 - Requirements for transporters of hazardous wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... that such wastes do not present a hazard to human health or the environment. These requirements shall... hazardous wastes. 271.11 Section 271.11 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements...

40 CFR 271.11 - Requirements for transporters of hazardous wastes.

Code of Federal Regulations, 2014 CFR

2014-07-01

... that such wastes do not present a hazard to human health or the environment. These requirements shall... hazardous wastes. 271.11 Section 271.11 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements...

40 CFR 271.11 - Requirements for transporters of hazardous wastes.

Code of Federal Regulations, 2011 CFR

2011-07-01

... that such wastes do not present a hazard to human health or the environment. These requirements shall... hazardous wastes. 271.11 Section 271.11 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) REQUIREMENTS FOR AUTHORIZATION OF STATE HAZARDOUS WASTE PROGRAMS Requirements...

40 CFR 227.30 - High-level radioactive waste.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false High-level radioactive waste. 227.30 Section 227.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) OCEAN DUMPING...-level radioactive waste. High-level radioactive waste means the aqueous waste resulting from the...

40 CFR 261.9 - Requirements for Universal Waste.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Requirements for Universal Waste. 261.9 Section 261.9 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION AND LISTING OF HAZARDOUS WASTE General § 261.9 Requirements for Universal Waste...

Engineering Glass Passivation Layers -Model Results

DOE Office of Scientific and Technical Information (OSTI.GOV)

Skorski, Daniel C.; Ryan, Joseph V.; Strachan, Denis M.

2011-08-08

The immobilization of radioactive waste into glass waste forms is a baseline process of nuclear waste management not only in the United States, but worldwide. The rate of radionuclide release from these glasses is a critical measure of the quality of the waste form. Over long-term tests and using extrapolations of ancient analogues, it has been shown that well designed glasses exhibit a dissolution rate that quickly decreases to a slow residual rate for the lifetime of the glass. The mechanistic cause of this decreased corrosion rate is a subject of debate, with one of the major theories suggesting thatmore » the decrease is caused by the formation of corrosion products in such a manner as to present a diffusion barrier on the surface of the glass. Although there is much evidence of this type of mechanism, there has been no attempt to engineer the effect to maximize the passivating qualities of the corrosion products. This study represents the first attempt to engineer the creation of passivating phases on the surface of glasses. Our approach utilizes interactions between the dissolving glass and elements from the disposal environment to create impermeable capping layers. By drawing from other corrosion studies in areas where passivation layers have been successfully engineered to protect the bulk material, we present here a report on mineral phases that are likely have a morphological tendency to encrust the surface of the glass. Our modeling has focused on using the AFCI glass system in a carbonate, sulfate, and phosphate rich environment. We evaluate the minerals predicted to form to determine the likelihood of the formation of a protective layer on the surface of the glass. We have also modeled individual ions in solutions vs. pH and the addition of aluminum and silicon. These results allow us to understand the pH and ion concentration dependence of mineral formation. We have determined that iron minerals are likely to form a complete incrustation layer and we plan to look more closely at Vivianite [Fe3(PO4)2-8(H2O)] and Siderite [FeCO3] in the next stage of the project.« less

Methods of sampling airborne fungi in working environments of waste treatment facilities.

PubMed

Černá, Kristýna; Wittlingerová, Zdeňka; Zimová, Magdaléna; Janovský, Zdeněk

2016-01-01

The objective of the present study was to evaluate and compare the efficiency of a filter based sampling method and a high volume sampling method for sampling airborne culturable fungi present in waste sorting facilities. Membrane filters method was compared with surface air system method. The selected sampling methods were modified and tested in 2 plastic waste sorting facilities. The total number of colony-forming units (CFU)/m3 of airborne fungi was dependent on the type of sampling device, on the time of sampling, which was carried out every hour from the beginning of the work shift, and on the type of cultivation medium (p < 0.001). Detected concentrations of airborne fungi ranged 2×102-1.7×106 CFU/m3 when using the membrane filters (MF) method, and 3×102-6.4×104 CFU/m3 when using the surface air system (SAS) method. Both methods showed comparable sensitivity to the fluctuations of the concentrations of airborne fungi during the work shifts. The SAS method is adequate for a fast indicative determination of concentration of airborne fungi. The MF method is suitable for thorough assessment of working environment contamination by airborne fungi. Therefore we recommend the MF method for the implementation of a uniform standard methodology of airborne fungi sampling in working environments of waste treatment facilities. This work is available in Open Access model and licensed under a CC BY-NC 3.0 PL license.

Glass binder development for a glass-bonded sodalite ceramic waste form

NASA Astrophysics Data System (ADS)

Riley, Brian J.; Vienna, John D.; Frank, Steven M.; Kroll, Jared O.; Peterson, Jacob A.; Canfield, Nathan L.; Zhu, Zihua; Zhang, Jiandong; Kruska, Karen; Schreiber, Daniel K.; Crum, Jarrod V.

2017-06-01

This paper discusses work to develop Na2O-B2O3-SiO2 glass binders for immobilizing LiCl-KCl eutectic salt waste in a glass-bonded sodalite waste form following electrochemical reprocessing of used metallic nuclear fuel. Here, five new glasses with ∼20 mass% Na2O were designed to generate waste forms with high sodalite. The glasses were then used to produce ceramic waste forms with a surrogate salt waste. The waste forms made using these new glasses were formulated to generate more sodalite than those made with previous baseline glasses for this type of waste. The coefficients of thermal expansion for the glass phase in the glass-bonded sodalite waste forms made with the new binder glasses were closer to the sodalite phase in the critical temperature region near and below the glass transition temperature than previous binder glasses used. These improvements should result in lower probability of cracking in the full-scale monolithic ceramic waste form, leading to better long-term chemical durability.

Study on Fired Clay Bricks by Replacing Clay with Palm Oil Waste: Effects on Physical and Mechanical Properties

NASA Astrophysics Data System (ADS)

Kadir, A. A.; Sarani, N. A.; Abdullah, M. M. A. B.; Perju, M. C.; Sandu, A. V.

2017-06-01

Palm oil is one of the major agricultural industries in Malaysia. Due to the poor management system, the discarded palm oil waste has always been linked to the environment issues. During processing of palm oil, a considerable amount of solid waste by-products in the form of fibres, shells, empty fruit bunches and fly ashes are produce rapidly. Therefore, this study was conducted to incorporate 1%, 5% and 10% of palm oil waste into fired clay brick. Samples of brick were fired at 1050°C temperature with heating rates of 1°C/min. Manufactured bricks were tested with physical and mechanical properties including firing shrinkage, dry density, water absorption and compressive strength. The results demonstrated that the replacement of 1% up to 5% of palm oil waste had improved several properties, although, a decrease of performance in certain aspects has also been observed. As a result, palm oil waste can be utilized in an environmentally safe way into fired clay brick thus providing adequate properties of fired clay brick.

Updated Liquid Secondary Waste Grout Formulation and Preliminary Waste Form Qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saslow, Sarah A.; Um, Wooyong; Russell, Renee L.

This report describes the results from liquid secondary waste grout (LSWG) formulation and cementitious waste form qualification tests performed by Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions, LLC (WRPS). New formulations for preparing a cementitious waste form from a high-sulfate liquid secondary waste stream simulant, developed for Effluent Management Facility (EMF) process condensates merged with low activity waste (LAW) caustic scrubber, and the release of key constituents (e.g. 99Tc and 129I) from these monoliths were evaluated. This work supports a technology development program to address the technology needs for Hanford Site Effluent Treatment Facility (ETF) liquid secondarymore » waste (LSW) solidification and supports future Direct Feed Low-Activity Waste (DFLAW) operations. High-priority activities included simulant development, LSWG formulation, and waste form qualification. The work contained within this report relates to waste form development and testing and does not directly support the 2017 integrated disposal facility (IDF) performance assessment (PA). However, this work contains valuable information for use in PA maintenance past FY17, and for future waste form development efforts. The provided data should be used by (i) cementitious waste form scientists to further understanding of cementitious dissolution behavior, (ii) IDF PA modelers who use quantified constituent leachability, effective diffusivity, and partitioning coefficients to advance PA modeling efforts, and (iii) the U.S. Department of Energy (DOE) contractors and decision makers as they assess the IDF PA program. The results obtained help fill existing data gaps, support final selection of a LSWG waste form, and improve the technical defensibility of long-term waste form performance estimates.« less

Waste Acceptance Testing of Secondary Waste Forms: Cast Stone, Ceramicrete and DuraLith

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mattigod, Shas V.; Westsik, Joseph H.; Chung, Chul-Woo

2011-08-12

To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions has initiated secondary-waste-form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is conducting tests on four candidate waste forms to evaluate their ability to meet potential waste acceptance criteria for immobilized secondary wastes that would be placed in the IDF. All three waste forms demonstrated compressive strengths above the minimum 3.45 MPa (500 psi) set as a target formore » cement-based waste forms. Further, none of the waste forms showed any significant degradation in compressive strength after undergoing thermal cycling (30 cycles in a 10 day period) between -40 C and 60 C or water immersion for 90 days. The three leach test methods are intended to measure the diffusion rates of contaminants from the waste forms. Results are reported in terms of diffusion coefficients and a leachability index (LI) calculated based on the diffusion coefficients. A smaller diffusion coefficient and a larger LI are desired. The NRC, in its Waste Form Technical Position (NRC 1991), provides recommendations and guidance regarding methods to demonstrate waste stability for land disposal of radioactive waste. Included is a recommendation to conduct leach tests using the ANS 16.1 method. The resulting leachability index (LI) should be greater than 6.0. For Hanford secondary wastes, the LI > 6.0 criterion applies to sodium leached from the waste form. For technetium and iodine, higher targets of LI > 9 for Tc and LI > 11 for iodine have been set based on early waste-disposal risk and performance assessment analyses. The results of these three leach tests conducted for a total time between 11days (ASTM C1308) to 90 days (ANS 16.1) showed: (1) Technetium diffusivity: ANSI/ANS 16.1, ASTM C1308, and EPA 1315 tests indicated that all the waste forms had leachability indices better than the target LI > 9 for technetium; (2) Rhenium diffusivity: Cast Stone 2M specimens, when tested using EPA 1315 protocol, had leachability indices better than the target LI > 9 for technetium based on rhenium as a surrogate for technetium. All other waste forms tested by ANSI/ANS 16.1, ASTM C1308, and EPA 1315 test methods had leachability indices that were below the target LI > 9 for Tc based on rhenium release. These studies indicated that use of Re(VII) as a surrogate for 99Tc(VII) in low temperature secondary waste forms containing reductants will provide overestimated diffusivity values for 99Tc. Therefore, it is not appropriate to use Re as a surrogate 99Tc in future low temperature waste form studies. (3) Iodine diffusivity: ANSI/ANS 16.1, ASTM C1308, and EPA 1315 tests indicated that the three waste forms had leachability indices that were below the target LI > 11 for iodine. Therefore, it may be necessary to use a more effective sequestering material than silver zeolite used in two of the waste forms (Ceramicrete and DuraLith); (4) Sodium diffusivity: All the waste form specimens tested by the three leach methods (ANSI/ANS 16.1, ASTM C1308, and EPA 1315) exceeded the target LI value of 6; (5) All three leach methods (ANS 16.1, ASTM C1308 and EPA 1315) provided similar 99Tc diffusivity values for both short-time transient diffusivity effects as well as long-term ({approx}90 days) steady diffusivity from each of the three tested waste forms (Cast Stone 2M, Ceramicrete and DuraLith). Therefore, any one of the three methods can be used to determine the contaminant diffusivities from a selected waste form.« less

40 CFR 273.19 - Tracking universal waste shipments.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Tracking universal waste shipments. 273.19 Section 273.19 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID... Universal Waste § 273.19 Tracking universal waste shipments. A small quantity handler of universal waste is...

40 CFR 148.10 - Waste specific prohibitions-solvent wastes.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Waste specific prohibitions-solvent wastes. 148.10 Section 148.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER... injection unless the solvent waste is a solvent-water mixture or solvent-containing sludge containing less...

40 CFR 148.16 - Waste specific prohibitions-third third wastes.

Code of Federal Regulations, 2013 CFR

2013-07-01

... from underground injection. (e) Effective November 8, 1990, the wastes specified in paragraph (c) of... 40 Protection of Environment 24 2013-07-01 2013-07-01 false Waste specific prohibitions-third third wastes. 148.16 Section 148.16 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 148.16 - Waste specific prohibitions-third third wastes.

Code of Federal Regulations, 2011 CFR

2011-07-01

... from underground injection. (e) Effective November 8, 1990, the wastes specified in paragraph (c) of... 40 Protection of Environment 23 2011-07-01 2011-07-01 false Waste specific prohibitions-third third wastes. 148.16 Section 148.16 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 148.16 - Waste specific prohibitions-third third wastes.

Code of Federal Regulations, 2014 CFR

2014-07-01

... from underground injection. (e) Effective November 8, 1990, the wastes specified in paragraph (c) of... 40 Protection of Environment 23 2014-07-01 2014-07-01 false Waste specific prohibitions-third third wastes. 148.16 Section 148.16 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 148.16 - Waste specific prohibitions-third third wastes.

Code of Federal Regulations, 2012 CFR

2012-07-01

... from underground injection. (e) Effective November 8, 1990, the wastes specified in paragraph (c) of... 40 Protection of Environment 24 2012-07-01 2012-07-01 false Waste specific prohibitions-third third wastes. 148.16 Section 148.16 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 262.60 - Imports of hazardous waste.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Imports of hazardous waste. 262.60 Section 262.60 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Imports of Hazardous Waste § 262.60 Imports...

I-NERI-2007-004-K, DEVELOPMENT AND CHARACTERIZATION OF NEW HIGH-LEVEL WASTE FORMS FOR ACHIEVING WASTE MINIMIZATION FROM PYROPROCESSING

DOE Office of Scientific and Technical Information (OSTI.GOV)

S.M. Frank

Work describe in this report represents the final year activities for the 3-year International Nuclear Energy Research Initiative (I-NERI) project: Development and Characterization of New High-Level Waste Forms for Achieving Waste Minimization from Pyroprocessing. Used electrorefiner salt that contained actinide chlorides and was highly loaded with surrogate fission products was processed into three candidate waste forms. The first waste form, a high-loaded ceramic waste form is a variant to the CWF produced during the treatment of Experimental Breeder Reactor-II used fuel at the Idaho National Laboratory (INL). The two other waste forms were developed by researchers at the Korean Atomicmore » Energy Research Institute (KAERI). These materials are based on a silica-alumina-phosphate matrix and a zinc/titanium oxide matrix. The proposed waste forms, and the processes to fabricate them, were designed to immobilize spent electrorefiner chloride salts containing alkali, alkaline earth, lanthanide, and halide fission products that accumulate in the salt during the processing of used nuclear fuel. This aspect of the I-NERI project was to demonstrate 'hot cell' fabrication and characterization of the proposed waste forms. The outline of the report includes the processing of the spent electrorefiner salt and the fabrication of each of the three waste forms. Also described is the characterization of the waste forms, and chemical durability testing of the material. While waste form fabrication and sample preparation for characterization must be accomplished in a radiological hot cell facility due to hazardous radioactivity levels, smaller quantities of each waste form were removed from the hot cell to perform various analyses. Characterization included density measurement, elemental analysis, x-ray diffraction, scanning electron microscopy and the Product Consistency Test, which is a leaching method to measure chemical durability. Favorable results from this demonstration project will provide additional options for fission product immobilization and waste management associated the electrochemical/pyrometallurgical processing of used nuclear fuel.« less

Development of iron phosphate ceramic waste form to immobilize radioactive waste solution

NASA Astrophysics Data System (ADS)

Choi, Jongkwon; Um, Wooyong; Choung, Sungwook

2014-09-01

The objective of this research was to develop an iron phosphate ceramic (IPC) waste form using converter slag obtained as a by-product of the steel industry as a source of iron instead of conventional iron oxide. Both synthetic off-gas scrubber solution containing technetium-99 (or Re as a surrogate) and LiCl-KCl eutectic salt, a final waste solution from pyrochemical processing of spent nuclear fuel, were used as radioactive waste streams. The IPC waste form was characterized for compressive strength, reduction capacity, chemical durability, and contaminant leachability. Compressive strengths of the IPC waste form prepared with different types of waste solutions were 16 MPa and 19 MPa for LiCl-KCl eutectic salt and the off-gas scrubber simulant, respectively, which meet the minimum compressive strength of 3.45 MPa (500 psi) for waste forms to be accepted into the radioactive waste repository. The reduction capacity of converter slag, a main dry ingredient used to prepare the IPC waste form, was 4136 meq/kg by the Ce(IV) method, which is much higher than those of the conventional Fe oxides used for the IPC waste form and the blast furnace slag materials. Average leachability indexes of Tc, Li, and K for the IPC waste form were higher than 6.0, and the IPC waste form demonstrated stable durability even after 63-day leaching. In addition, the Toxicity Characteristic Leach Procedure measurements of converter slag and the IPC waste form with LiCl-KCl eutectic salt met the universal treatment standard of the leachability limit for metals regulated by the Resource Conservation and Recovery Act. This study confirms the possibility of development of the IPC waste form using converter slag, showing its immobilization capability for radionuclides in both LiCl-KCl eutectic salt and off-gas scrubber solutions with significant cost savings.

Development of iron phosphate ceramic waste form to immobilize radioactive waste solution

DOE Office of Scientific and Technical Information (OSTI.GOV)

Choi, Jongkwon; Um, Wooyong; Choung, Sungwook

The objective of this research was to develop an iron phosphate ceramic (IPC) waste form using converter slag obtained as a by-product of the steel industry as a source of iron instead of conventional iron oxide. Both synthetic off-gas scrubber solution containing technetium-99 (or Re as a surrogate) and LiCl-KCl eutectic salt, a final waste solution from pyrochemical processing of spent nuclear fuel, were used as radioactive waste streams. The IPC waste form was characterized for compressive strength, reduction capacity, chemical durability, and contaminant leachability. Compressive strengths of the IPC waste form prepared with different types of waste solutions weremore » 16 MPa and 19 MPa for LiCl-KCl eutectic salt and the off-gas scrubber simulant, respectively, which meet the minimum compressive strength of 3.45 MPa (500 psi) for waste forms to be accepted into the radioactive waste repository. The reduction capacity of converter slag, a main dry ingredient used to prepare the IPC waste form, was 4,136 meq/kg by the Ce(IV) method, which is much higher than those of the conventional Fe oxides used for the IPC waste form and the blast furnace slag materials. Average leachability indexes of Tc, Li, and K for the IPC waste form were higher than 6.0, and the IPC waste form demonstrated stable durability even after 63-day leaching. In addition, the Toxicity Characteristic Leach Procedure measurements of converter slag and the IPC waste form with LiCl-KCl eutectic salt met the universal treatment standard of the leachability limit for metals regulated by the Resource Conservation and Recovery Act. This study confirms the possibility of development of the IPC waste form using converter slag, showing its immobilization capability for radionuclides in both LiCl-KCl eutectic salt and off-gas scrubber solutions with significant cost savings.« less

40 CFR 148.18 - Waste specific prohibitions-newly listed and identified wastes.

Code of Federal Regulations, 2012 CFR

2012-07-01

.... (e) On July 8, 1996, the wastes specified in 40 CFR 261.32 as EPA Hazardous waste numbers K156-K161... 40 Protection of Environment 24 2012-07-01 2012-07-01 false Waste specific prohibitions-newly listed and identified wastes. 148.18 Section 148.18 Protection of Environment ENVIRONMENTAL PROTECTION...

40 CFR 148.18 - Waste specific prohibitions-newly listed and identified wastes.

Code of Federal Regulations, 2011 CFR

2011-07-01

.... (e) On July 8, 1996, the wastes specified in 40 CFR 261.32 as EPA Hazardous waste numbers K156-K161... 40 Protection of Environment 23 2011-07-01 2011-07-01 false Waste specific prohibitions-newly listed and identified wastes. 148.18 Section 148.18 Protection of Environment ENVIRONMENTAL PROTECTION...

40 CFR 148.18 - Waste specific prohibitions-newly listed and identified wastes.

Code of Federal Regulations, 2013 CFR

2013-07-01

.... (e) On July 8, 1996, the wastes specified in 40 CFR 261.32 as EPA Hazardous waste numbers K156-K161... 40 Protection of Environment 24 2013-07-01 2013-07-01 false Waste specific prohibitions-newly listed and identified wastes. 148.18 Section 148.18 Protection of Environment ENVIRONMENTAL PROTECTION...

40 CFR 148.18 - Waste specific prohibitions-newly listed and identified wastes.

Code of Federal Regulations, 2014 CFR

2014-07-01

.... (e) On July 8, 1996, the wastes specified in 40 CFR 261.32 as EPA Hazardous waste numbers K156-K161... 40 Protection of Environment 23 2014-07-01 2014-07-01 false Waste specific prohibitions-newly listed and identified wastes. 148.18 Section 148.18 Protection of Environment ENVIRONMENTAL PROTECTION...

AMS measurements of 14C and 129I in seawater around radioactive waste dump sites

NASA Astrophysics Data System (ADS)

Povinec, P. P.; Oregioni, B.; Jull, A. J. T.; Kieser, W. E.; Zhao, X.-L.

2000-10-01

According to a recent IAEA compilation of inventories of radioactive wastes dumped in the world ocean, a total of 85 PBq of radioactive wastes were dumped, in the Atlantic (45 PBq), the Pacific (1.4 PBq) and the Arctic (38 PBq) Oceans and their marginal seas between 1946 and 1993, mostly in the form of low-level wastes. 3H, and 14C formed an important part of the beta-activity of these dumped wastes. Because of its long half-life, 14C will be the main constituent in possible leakages from the wastes in the future. On the other hand, 14C and 129I are important radioactive tracers which have been artificially introduced into the oceans. Small amounts of 14C and 129I can be easily measured by accelerator mass spectrometry (AMS) on mg-size samples of carbon and iodine extracted from 500 ml seawater samples. The high analytical sensitivity enables one therefore to find even trace amounts of 14C and 129I which could be released from radioactive wastes, and to compare the measured levels with the global distribution of these radionuclides. The IAEAs Marine Environment Laboratory (IAEA-MEL) has been engaged in an assessment program related to radioactive waste dumping in the oceans since 1992 and has participated in several expeditions to the Atlantic, Arctic, Indian and Pacific Oceans to sample seawater, biota and sediment for radiological assessment studies. In the present paper, we report on methods of 14C and 129I measurements in seawater by AMS and present data on the NE Atlantic, the Arctic and the NW Pacific Ocean dumping sites. A small increase of 14C was observed at the NE Atlantic dumping site.

Secondary Waste Form Down-Selection Data Package—Fluidized Bed Steam Reforming Waste Form

DOE Office of Scientific and Technical Information (OSTI.GOV)

Qafoku, Nikolla; Westsik, Joseph H.; Strachan, Denis M.

2011-09-12

The Hanford Site in southeast Washington State has 56 million gallons of radioactive and chemically hazardous wastes stored in 177 underground tanks (ORP 2010). The U.S. Department of Energy (DOE), Office of River Protection (ORP), through its contractors, is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to convert the radioactive and hazardous wastes into stable glass waste forms for disposal. Within the WTP, the pretreatment facility will receive the retrieved waste from the tank farms and separate it into two treated process streams. These waste streams will be vitrified, and the resulting waste canisters will be sentmore » to offsite (high-level waste [HLW]) and onsite (immobilized low-activity waste [ILAW]) repositories. As part of the pretreatment and ILAW processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility (ETF) on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed of in the Integrated Disposal Facility (IDF). To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is developing data packages to support that down-selection. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilizing and solidifying the liquid secondary wastes. At the Hanford Site, the FBSR process is being evaluated as a supplemental technology for treating and immobilizing Hanford LAW radioactive tank waste and for treating secondary wastes from the WTP pretreatment and LAW vitrification processes.« less

Exposure to airborne fungi during sorting of recyclable plastics in waste treatment facilities.

PubMed

Černá, Kristýna; Wittlingerová, Zdeňka; Zimová, Magdaléna; Janovský, Zdeněk

2017-02-28

In working environment of waste treatment facilities, employees are exposed to high concentrations of airborne microorganisms. Fungi constitute an essential part of them. This study aims at evaluating the diurnal variation in concentrations and species composition of the fungal contamination in 2 plastic waste sorting facilities in different seasons. Air samples from the 2 sorting facilities were collected through the membrane filters method on 4 different types of cultivation media. Isolated fungi were classified to genera or species by using a light microscopy. Overall, the highest concentrations of airborne fungi were recorded in summer (9.1×10³-9.0×10⁵ colony-forming units (CFU)/m₃), while the lowest ones in winter (2.7×10³-2.9×10⁵ CFU/m³). The concentration increased from the beginning of the work shift and reached a plateau after 6-7 h of the sorting. The most frequently isolated airborne fungi were those of the genera Penicillium and Aspergillus. The turnover of fungal species between seasons was relatively high as well as changes in the number of detected species, but potentially toxigenic and allergenic fungi were detected in both facilities during all seasons. Generally, high concentrations of airborne fungi were detected in the working environment of plastic waste sorting facilities, which raises the question of health risk taken by the employees. Based on our results, the use of protective equipment by employees is recommended and preventive measures should be introduced into the working environment of waste sorting facilities to reduce health risk for employees. Med Pr 2017;68(1):1-9. This work is available in Open Access model and licensed under a CC BY-NC 3.0 PL license.

Formation of stable uranium(VI) colloidal nanoparticles in conditions relevant to radioactive waste disposal.

PubMed

Bots, Pieter; Morris, Katherine; Hibberd, Rosemary; Law, Gareth T W; Mosselmans, J Frederick W; Brown, Andy P; Doutch, James; Smith, Andrew J; Shaw, Samuel

2014-12-09

The favored pathway for disposal of higher activity radioactive wastes is via deep geological disposal. Many geological disposal facility designs include cement in their engineering design. Over the long term, interaction of groundwater with the cement and waste will form a plume of a hyperalkaline leachate (pH 10-13), and the behavior of radionuclides needs to be constrained under these extreme conditions to minimize the environmental hazard from the wastes. For uranium, a key component of many radioactive wastes, thermodynamic modeling predicts that, at high pH, U(VI) solubility will be very low (nM or lower) and controlled by equilibrium with solid phase alkali and alkaline-earth uranates. However, the formation of U(VI) colloids could potentially enhance the mobility of U(VI) under these conditions, and characterizing the potential for formation and medium-term stability of U(VI) colloids is important in underpinning our understanding of U behavior in waste disposal. Reflecting this, we applied conventional geochemical and microscopy techniques combined with synchrotron based in situ and ex situ X-ray techniques (small-angle X-ray scattering and X-ray adsorption spectroscopy (XAS)) to characterize colloidal U(VI) nanoparticles in a synthetic cement leachate (pH > 13) containing 4.2-252 μM U(VI). The results show that in cement leachates with 42 μM U(VI), colloids formed within hours and remained stable for several years. The colloids consisted of 1.5-1.8 nm nanoparticles with a proportion forming 20-60 nm aggregates. Using XAS and electron microscopy, we were able to determine that the colloidal nanoparticles had a clarkeite (sodium-uranate)-type crystallographic structure. The presented results have clear and hitherto unrecognized implications for the mobility of U(VI) in cementitious environments, in particular those associated with the geological disposal of nuclear waste.

WastePlan model implementation for New York State. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Visalli, J.R.; Blackman, D.A.

1995-07-01

WastePlan is a computer software tool that models solid waste quantities, costs, and other parameters on a regional basis. The software was developed by the Tellus Institute, a nonprofit research and consulting firm. The project`s objective was to provide local solid waste management planners in New York State responsible to develop and implement comprehensive solid waste management plans authorized by the Solid Waste Management Act of 1988, with a WastePlan model specifically tailored to fit the demographic and other characteristics of New York State and to provide training and technical support to the users. Two-day workshops were held in 1992more » to introduce planners to the existing versions; subsequently, extensive changes were made to the model and a second set of two-day workshops were held in 1993 to introduce planners to the enhanced version of WastePlan. Following user evaluations, WastePlan was further modified to allow users to model systems using a simplified version, and to incorporate report forms required by New York State. A post-project survey of trainees revealed limited regular use of software. Possible reasons include lack of synchronicity with NYSDEC planning process; lack of computer literacy and aptitude among trainees; hardware limitations; software user-friendliness; and the work environment of the trainees. A number of recommendations are made to encourage use of WastePlan by local solid waste management planners.« less

40 CFR 148.17 - Waste specific prohibitions; newly listed wastes.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Hazardous waste numbers K117, K118, K131, and K132 are prohibited from underground injection. (e) The... 40 Protection of Environment 24 2013-07-01 2013-07-01 false Waste specific prohibitions; newly listed wastes. 148.17 Section 148.17 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 148.17 - Waste specific prohibitions; newly listed wastes.

Code of Federal Regulations, 2014 CFR

2014-07-01

... Hazardous waste numbers K117, K118, K131, and K132 are prohibited from underground injection. (e) The... 40 Protection of Environment 23 2014-07-01 2014-07-01 false Waste specific prohibitions; newly listed wastes. 148.17 Section 148.17 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 148.14 - Waste specific prohibitions-first third wastes.

Code of Federal Regulations, 2013 CFR

2013-07-01

... underground injection at off-site injection facilities. (e) Effective August 8, 1990, the wastes specified in... 40 Protection of Environment 24 2013-07-01 2013-07-01 false Waste specific prohibitions-first third wastes. 148.14 Section 148.14 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 148.14 - Waste specific prohibitions-first third wastes.

Code of Federal Regulations, 2012 CFR

2012-07-01

... underground injection at off-site injection facilities. (e) Effective August 8, 1990, the wastes specified in... 40 Protection of Environment 24 2012-07-01 2012-07-01 false Waste specific prohibitions-first third wastes. 148.14 Section 148.14 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 148.17 - Waste specific prohibitions; newly listed wastes.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Hazardous waste numbers K117, K118, K131, and K132 are prohibited from underground injection. (e) The... 40 Protection of Environment 23 2011-07-01 2011-07-01 false Waste specific prohibitions; newly listed wastes. 148.17 Section 148.17 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 148.17 - Waste specific prohibitions; newly listed wastes.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Hazardous waste numbers K117, K118, K131, and K132 are prohibited from underground injection. (e) The... 40 Protection of Environment 24 2012-07-01 2012-07-01 false Waste specific prohibitions; newly listed wastes. 148.17 Section 148.17 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 148.14 - Waste specific prohibitions-first third wastes.

Code of Federal Regulations, 2014 CFR

2014-07-01

... underground injection at off-site injection facilities. (e) Effective August 8, 1990, the wastes specified in... 40 Protection of Environment 23 2014-07-01 2014-07-01 false Waste specific prohibitions-first third wastes. 148.14 Section 148.14 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 268.37 - Waste specific prohibitions-ignitable and corrosive characteristic wastes whose treatment...

Code of Federal Regulations, 2011 CFR

2011-07-01

... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.37 Waste specific prohibitions—ignitable and corrosive... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Waste specific prohibitions-ignitable...

40 CFR 268.37 - Waste specific prohibitions-ignitable and corrosive characteristic wastes whose treatment...

Code of Federal Regulations, 2012 CFR

2012-07-01

... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.37 Waste specific prohibitions—ignitable and corrosive... 40 Protection of Environment 28 2012-07-01 2012-07-01 false Waste specific prohibitions-ignitable...

40 CFR 268.37 - Waste specific prohibitions-ignitable and corrosive characteristic wastes whose treatment...

Code of Federal Regulations, 2014 CFR

2014-07-01

... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.37 Waste specific prohibitions—ignitable and corrosive... 40 Protection of Environment 27 2014-07-01 2014-07-01 false Waste specific prohibitions-ignitable...

40 CFR 268.37 - Waste specific prohibitions-ignitable and corrosive characteristic wastes whose treatment...

Code of Federal Regulations, 2013 CFR

2013-07-01

... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Prohibitions on Land Disposal § 268.37 Waste specific prohibitions—ignitable and corrosive... 40 Protection of Environment 28 2013-07-01 2013-07-01 false Waste specific prohibitions-ignitable...

40 CFR 62.15370 - What is yard waste?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 9 2014-07-01 2014-07-01 false What is yard waste? 62.15370 Section 62.15370 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED... Incinerators That Burn 100 Percent Yard Waste § 62.15370 What is yard waste? Yard waste is grass, grass...

40 CFR 62.15370 - What is yard waste?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 9 2013-07-01 2013-07-01 false What is yard waste? 62.15370 Section 62.15370 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED... Incinerators That Burn 100 Percent Yard Waste § 62.15370 What is yard waste? Yard waste is grass, grass...

40 CFR 60.1915 - What is yard waste?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 7 2014-07-01 2014-07-01 false What is yard waste? 60.1915 Section 60.1915 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED... Incinerators That Burn 100 Percent Yard Waste § 60.1915 What is yard waste? Yard waste is grass, grass...

40 CFR 60.1915 - What is yard waste?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 7 2013-07-01 2013-07-01 false What is yard waste? 60.1915 Section 60.1915 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED... Incinerators That Burn 100 Percent Yard Waste § 60.1915 What is yard waste? Yard waste is grass, grass...

Method of processing materials using an inductively coupled plasma

DOEpatents

Hull, D.E.; Bieniewski, T.M.

1987-04-13

A method of processing materials. The invention enables ultrafine, ultrapure powders to be formed from solid ingots in a gas free environment. A plasma is formed directly from an ingot which insures purity. The vaporized material is expanded through a nozzle and the resultant powder settles on a cold surface. An inductively coupled plasma may also be used to process waste chemicals. Noxious chemicals are directed through a series of plasma tubes, breaking molecular bonds and resulting in relatively harmless atomic constituents. 3 figs.

Structure and thermodynamics of uranium-containing iron garnets

DOE PAGES

Guo, Xiaofeng; Navrotsky, Alexandra; Kukkadapu, Ravi K.; ...

2016-09-15

Use of crystalline garnet as a waste form phase appears to be advantageous for accommodating actinides from nuclear waste. Previous studies show that large amounts of uranium (U) and its analogues such as cerium (Ce) and thorium (Th) can be incorporated into the garnet structure. In this study, we synthesized U loaded garnet phases, Ca 3U xZr 2–xFe 3O 12 (x = 0.5–0.7), along with the endmember phase, Ca 3(Zr 2)SiFe 3+ 2O 12, for comparison. The oxidation states of U were determined by X-ray photoelectron and absorption spectroscopies, revealing the presence of mixed pentavalent and hexavalent uranium in themore » phases with x = 0.6 and 0.7. The oxidation states and coordination environments of Fe were measured using transmission 57Fe-Mössbauer spectroscopy, which shows that all iron is tetrahedrally coordinated Fe 3+. U substitution had a significant effect on local environments, the extent of U substitution within this range had a minimal effect on the structure, and unlike in the x = 0 sample, Fe exists in two different environments in the substituted garnets. The enthalpies of formation of garnet phases from constituent oxides and elements were first time determined by high temperature oxide melt solution calorimetry. The results indicate that these substituted garnets are thermodynamically stable under reducing conditions. Furthermore, our structural and thermodynamic analysis further provides explanation for the formation of natural uranium garnet, elbrusite-(Zr), and supports the potential use of Ca 3U xZr 2–xFe 3O 12 as viable waste form phases for U and other actinides.« less

Effluent Management Facility Evaporator Bottom-Waste Streams Formulation and Waste Form Qualification Testing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Saslow, Sarah A.; Um, Wooyong; Russell, Renee L.

This report describes the results from grout formulation and cementitious waste form qualification testing performed by Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions, LLC (WRPS). These results are part of a screening test that investigates three grout formulations proposed for wide-range treatment of different waste stream compositions expected for the Hanford Effluent Management Facility (EMF) evaporator bottom waste. This work supports the technical development need for alternative disposition paths for the EMF evaporator bottom wastes and future direct feed low-activity waste (DFLAW) operations at the Hanford Site. High-priority activities included simulant production, grout formulation, and cementitious wastemore » form qualification testing. The work contained within this report relates to waste form development and testing, and does not directly support the 2017 Integrated Disposal Facility (IDF) performance assessment (PA). However, this work contains valuable information for use in PA maintenance past FY 2017 and future waste form development efforts. The provided results and data should be used by (1) cementitious waste form scientists to further the understanding of cementitious leach behavior of contaminants of concern (COCs), (2) decision makers interested in off-site waste form disposal, and (3) the U.S. Department of Energy, their Hanford Site contractors and stakeholders as they assess the IDF PA program at the Hanford Site. The results reported help fill existing data gaps, support final selection of a cementitious waste form for the EMF evaporator bottom waste, and improve the technical defensibility of long-term waste form risk estimates.« less

40 CFR 263.31 - Discharge clean up.

Code of Federal Regulations, 2010 CFR

2010-07-01

... hazardous waste discharge no longer presents a hazard to human health or the environment. ....31 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO TRANSPORTERS OF HAZARDOUS WASTE Hazardous Waste Discharges § 263.31 Discharge clean...

40 CFR 263.31 - Discharge clean up.

Code of Federal Regulations, 2014 CFR

2014-07-01

... hazardous waste discharge no longer presents a hazard to human health or the environment. ....31 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO TRANSPORTERS OF HAZARDOUS WASTE Hazardous Waste Discharges § 263.31 Discharge clean...

40 CFR 263.31 - Discharge clean up.

Code of Federal Regulations, 2013 CFR

2013-07-01

... hazardous waste discharge no longer presents a hazard to human health or the environment. ....31 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO TRANSPORTERS OF HAZARDOUS WASTE Hazardous Waste Discharges § 263.31 Discharge clean...

40 CFR 263.31 - Discharge clean up.

Code of Federal Regulations, 2011 CFR

2011-07-01

... hazardous waste discharge no longer presents a hazard to human health or the environment. ....31 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO TRANSPORTERS OF HAZARDOUS WASTE Hazardous Waste Discharges § 263.31 Discharge clean...

40 CFR 263.31 - Discharge clean up.

Code of Federal Regulations, 2012 CFR

2012-07-01

... hazardous waste discharge no longer presents a hazard to human health or the environment. ....31 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO TRANSPORTERS OF HAZARDOUS WASTE Hazardous Waste Discharges § 263.31 Discharge clean...

YUCCA Mountain Project - Argonne National Laboratory, Annual Progress Report, FY 1997 for activity WP 1221 unsaturated drip condition testing of spent fuel and unsaturated dissolution tests of glass.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bates, J. K.; Buck, E. C.; Emery, J. W.

1998-09-18

This document reports on the work done by the Nuclear Waste Management Section of the Chemical Technology Division of Argonne National Laboratory in the period of October 1996 through September 1997. Studies have been performed to evaluate the behavior of nuclear waste glass and spent fuel samples under the unsaturated conditions (low-volume water contact) that are likely to exist in the Yucca Mountain environment being considered as a potential site for a high-level waste repository. Tests with actinide-doped waste glasses, in progress for over 11 years, indicate that the transuranic element release is dominated by colloids that continuously form andmore » span from the glass surface. The nature of the colloids that form in the glass and spent fuel testing programs is being investigated by dynamic light scattering to determine the size distribution, by autoradiography to determine the chemistry, and by zeta potential to measure the electrical properties of the colloids. Tests with UO{sub 2} have been ongoing for 12 years. They show that the oxidation of UO{sub 2} occurs rapidly, and the resulting paragenetic sequence of secondary phases forming on the sample surface is similar to that observed for uranium found in natural oxidizing environments. The reaction of spent fuel samples in conditions similar to those used with UO{sub 2} have been in progress for over six years, and the results suggest that spent fuel forms many of the same alteration products as UO{sub 2}. With spent fuel, the bulk of the reaction occurs via a through-grain reaction process, although grain boundary attack is sufficient to have reacted all of the grain boundary regions in the samples. New test methods are under development to evaluate the behavior of spent fuel samples with intact cladding: the rate at which alteration and radionuclide release occurs when water penetrates fuel sections and whether the reaction causes the cladding to split. Alteration phases have been formed on fine grains of UO{sub 2} in contact with small volumes of water within a several month period when the radiolysis product H{sub 2}O{sub 2} is added to the groundwater solution. The test setup has been mocked up for operation with spent fuel in the hot-cell.« less

Vermi composting--organic waste management and disposal.

PubMed

Kumar, J Sudhir; Subbaiah, K Venkata; Rao, P V V Prasada

2012-01-01

Solid waste is an unwanted byproduct of modern civilization. Landfills are the most common means of solid waste disposal. But the increasing amount of solid waste is rapidly filling existing landfills, and new sites are difficult to establish. Alternatives to landfills include the use of source reduction, recycling, composting and incineration, as well as use of landfills. Incineration is most economical if it includes energy recovery from the waste. Energy can be recovered directly from waste by incineration or the waste can be processed to produce storable refuse derived fuel (RDF). Information on the composition of solid wastes is important in evaluating alternative equipment needs, systems, management programs and plans. Pulverization of municipal solid waste is done and the pulverized solid waste is dressed to form a bed and the bed is fed by earthworms which convert the bed into vermi compost. The obtained vermi compost is sent to Ministry of Environment & Forests (MoEF) recognized lab for estimating the major nutrients, i.e. Potassium (K), Phosphorous (P), Nitrogen (N) and Micro-nutrient values. It is estimated that 59 - 65 tons of wet waste can be collected in a town per day and if this wet waste is converted to quality compost, around 12.30 tons of vermi compost can be generated. If a Municipal Corporation manages this wet waste an income of over (see text symbol) for 0.8 9 crore per anum can be earned which is a considerable amount for providing of better services to public.

Glass binder development for a glass-bonded sodalite ceramic waste form

DOE Office of Scientific and Technical Information (OSTI.GOV)

Riley, Brian J.; Vienna, John D.; Frank, Steven M.

This paper discusses work to develop Na 2O-B 2O 3-SiO 2 glass binders for immobilizing LiCl-KCl eutectic salt waste in a glass-bonded sodalite waste form following electrochemical reprocessing of used metallic nuclear fuel. In this paper, five new glasses with ~20 mass% Na 2O were designed to generate waste forms with high sodalite. The glasses were then used to produce ceramic waste forms with a surrogate salt waste. The waste forms made using these new glasses were formulated to generate more sodalite than those made with previous baseline glasses for this type of waste. The coefficients of thermal expansion formore » the glass phase in the glass-bonded sodalite waste forms made with the new binder glasses were closer to the sodalite phase in the critical temperature region near and below the glass transition temperature than previous binder glasses used. Finally, these improvements should result in lower probability of cracking in the full-scale monolithic ceramic waste form, leading to better long-term chemical durability.« less

Glass binder development for a glass-bonded sodalite ceramic waste form

DOE PAGES

Riley, Brian J.; Vienna, John D.; Frank, Steven M.; ...

2017-06-01

This paper discusses work to develop Na 2O-B 2O 3-SiO 2 glass binders for immobilizing LiCl-KCl eutectic salt waste in a glass-bonded sodalite waste form following electrochemical reprocessing of used metallic nuclear fuel. In this paper, five new glasses with ~20 mass% Na 2O were designed to generate waste forms with high sodalite. The glasses were then used to produce ceramic waste forms with a surrogate salt waste. The waste forms made using these new glasses were formulated to generate more sodalite than those made with previous baseline glasses for this type of waste. The coefficients of thermal expansion formore » the glass phase in the glass-bonded sodalite waste forms made with the new binder glasses were closer to the sodalite phase in the critical temperature region near and below the glass transition temperature than previous binder glasses used. Finally, these improvements should result in lower probability of cracking in the full-scale monolithic ceramic waste form, leading to better long-term chemical durability.« less

Engineered Barrier System: Physical and Chemical Environment

DOE Office of Scientific and Technical Information (OSTI.GOV)

P. Dixon

2004-04-26

The conceptual and predictive models documented in this Engineered Barrier System: Physical and Chemical Environment Model report describe the evolution of the physical and chemical conditions within the waste emplacement drifts of the repository. The modeling approaches and model output data will be used in the total system performance assessment (TSPA-LA) to assess the performance of the engineered barrier system and the waste form. These models evaluate the range of potential water compositions within the emplacement drifts, resulting from the interaction of introduced materials and minerals in dust with water seeping into the drifts and with aqueous solutions forming bymore » deliquescence of dust (as influenced by atmospheric conditions), and from thermal-hydrological-chemical (THC) processes in the drift. These models also consider the uncertainty and variability in water chemistry inside the drift and the compositions of introduced materials within the drift. This report develops and documents a set of process- and abstraction-level models that constitute the engineered barrier system: physical and chemical environment model. Where possible, these models use information directly from other process model reports as input, which promotes integration among process models used for total system performance assessment. Specific tasks and activities of modeling the physical and chemical environment are included in the technical work plan ''Technical Work Plan for: In-Drift Geochemistry Modeling'' (BSC 2004 [DIRS 166519]). As described in the technical work plan, the development of this report is coordinated with the development of other engineered barrier system analysis model reports.« less

Equilibrium Temperature Profiles within Fission Product Waste Forms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kaminski, Michael D.

2016-10-01

We studied waste form strategies for advanced fuel cycle schemes. Several options were considered for three waste streams with the following fission products: cesium and strontium, transition metals, and lanthanides. These three waste streams may be combined or disposed separately. The decay of several isotopes will generate heat that must be accommodated by the waste form, and this heat will affect the waste loadings. To help make an informed decision on the best option, we present computational data on the equilibrium temperature of glass waste forms containing a combination of these three streams.

Estimating Residual Solids Volume In Underground Storage Tanks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Clark, Jason L.; Worthy, S. Jason; Martin, Bruce A.

2014-01-08

The Savannah River Site liquid waste system consists of multiple facilities to safely receive and store legacy radioactive waste, treat, and permanently dispose waste. The large underground storage tanks and associated equipment, known as the 'tank farms', include a complex interconnected transfer system which includes underground transfer pipelines and ancillary equipment to direct the flow of waste. The waste in the tanks is present in three forms: supernatant, sludge, and salt. The supernatant is a multi-component aqueous mixture, while sludge is a gel-like substance which consists of insoluble solids and entrapped supernatant. The waste from these tanks is retrieved andmore » treated as sludge or salt. The high level (radioactive) fraction of the waste is vitrified into a glass waste form, while the low-level waste is immobilized in a cementitious grout waste form called saltstone. Once the waste is retrieved and processed, the tanks are closed via removing the bulk of the waste, chemical cleaning, heel removal, stabilizing remaining residuals with tailored grout formulations and severing/sealing external penetrations. The comprehensive liquid waste disposition system, currently managed by Savannah River Remediation, consists of 1) safe storage and retrieval of the waste as it is prepared for permanent disposition; (2) definition of the waste processing techniques utilized to separate the high-level waste fraction/low-level waste fraction; (3) disposition of LLW in saltstone; (4) disposition of the HLW in glass; and (5) closure state of the facilities, including tanks. This paper focuses on determining the effectiveness of waste removal campaigns through monitoring the volume of residual solids in the waste tanks. Volume estimates of the residual solids are performed by creating a map of the residual solids on the waste tank bottom using video and still digital images. The map is then used to calculate the volume of solids remaining in the waste tank. The ability to accurately determine a volume is a function of the quantity and quality of the waste tank images. Currently, mapping is performed remotely with closed circuit video cameras and still photograph cameras due to the hazardous environment. There are two methods that can be used to create a solids volume map. These methods are: liquid transfer mapping / post transfer mapping and final residual solids mapping. The task is performed during a transfer because the liquid level (which is a known value determined by a level measurement device) is used as a landmark to indicate solids accumulation heights. The post transfer method is primarily utilized after the majority of waste has been removed. This method relies on video and still digital images of the waste tank after the liquid transfer is complete to obtain the relative height of solids across a waste tank in relation to known and usable landmarks within the waste tank (cooling coils, column base plates, etc.). In order to accurately monitor solids over time across various cleaning campaigns, and provide a technical basis to support final waste tank closure, a consistent methodology for volume determination has been developed and implemented at SRS.« less

Tanks Focus Area annual report FY2000

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2000-12-01

The U.S. Department of Energy (DOE) continues to face a major radioactive waste tank remediation effort with tanks containing hazardous and radioactive waste resulting from the production of nuclear materials. With some 90 million gallons of waste in the form of solid, sludge, liquid, and gas stored in 287 tanks across the DOE complex, containing approximately 650 million curies, radioactive waste storage tank remediation is the nation's highest cleanup priority. Differing waste types and unique technical issues require specialized science and technology to achieve tank cleanup in an environmentally acceptable manner. Some of the waste has been stored for overmore » 50 years in tanks that have exceeded their design lives. The challenge is to characterize and maintain these contents in a safe condition and continue to remediate and close each tank to minimize the risks of waste migration and exposure to workers, the public, and the environment. In 1994, the DOE's Office of Environmental Management (EM) created a group of integrated, multiorganizational teams focusing on specific areas of the EM cleanup mission. These teams have evolved into five focus areas managed within EM's Office of Science and Technology (OST): Tanks Focus Area (TFA); Deactivation and Decommissioning Focus Area; Nuclear Materials Focus Area; Subsurface Contaminants Focus Area; and Transuranic and Mixed Waste Focus Area.« less

Secondary Waste Form Screening Test Results—THOR® Fluidized Bed Steam Reforming Product in a Geopolymer Matrix

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pires, Richard P.; Westsik, Joseph H.; Serne, R. Jeffrey

2011-07-14

Screening tests are being conducted to evaluate waste forms for immobilizing secondary liquid wastes from the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Plans are underway to add a stabilization treatment unit to the Effluent Treatment Facility to provide the needed capacity for treating these wastes from WTP. The current baseline is to use a Cast Stone cementitious waste form to solidify the wastes. Through a literature survey, DuraLith alkali-aluminosilicate geopolymer, fluidized-bed steam reformation (FBSR) granular product encapsulated in a geopolymer matrix, and a Ceramicrete phosphate-bonded ceramic were identified both as candidate waste forms and alternatives to the baseline.more » These waste forms have been shown to meet waste disposal acceptance criteria, including compressive strength and universal treatment standards for Resource Conservation and Recovery Act (RCRA) metals (as measured by the toxicity characteristic leaching procedure [TCLP]). Thus, these non-cementitious waste forms should also be acceptable for land disposal. Information is needed on all four waste forms with respect to their capability to minimize the release of technetium. Technetium is a radionuclide predicted to be in the secondary liquid wastes in small quantities, but the Integrated Disposal Facility (IDF) risk assessment analyses show that technetium, even at low mass, produces the largest contribution to the estimated IDF disposal impacts to groundwater.« less

40 CFR 273.56 - Exports.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Exports. 273.56 Section 273.56 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR UNIVERSAL WASTE MANAGEMENT Standards for Universal Waste Transporters § 273.56 Exports. A universal waste...

40 CFR 264.13 - General waste analysis.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 27 2013-07-01 2013-07-01 false General waste analysis. 264.13 Section 264.13 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES General...

40 CFR 265.76 - Unmanifested waste report.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Unmanifested waste report. 265.76 Section 265.76 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND...

40 CFR 264.76 - Unmanifested waste report.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Unmanifested waste report. 264.76 Section 264.76 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES...

40 CFR 264.13 - General waste analysis.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 26 2011-07-01 2011-07-01 false General waste analysis. 264.13 Section 264.13 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES General...

40 CFR 264.13 - General waste analysis.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 27 2012-07-01 2012-07-01 false General waste analysis. 264.13 Section 264.13 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES General...

40 CFR 264.13 - General waste analysis.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false General waste analysis. 264.13 Section 264.13 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES General...

40 CFR 264.76 - Unmanifested waste report.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Unmanifested waste report. 264.76 Section 264.76 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES...

40 CFR 265.13 - General waste analysis.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 27 2013-07-01 2013-07-01 false General waste analysis. 265.13 Section 265.13 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL...

40 CFR 265.76 - Unmanifested waste report.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Unmanifested waste report. 265.76 Section 265.76 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND...

40 CFR 264.76 - Unmanifested waste report.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Unmanifested waste report. 264.76 Section 264.76 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES...

40 CFR 264.76 - Unmanifested waste report.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Unmanifested waste report. 264.76 Section 264.76 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES...

40 CFR 265.76 - Unmanifested waste report.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Unmanifested waste report. 265.76 Section 265.76 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND...

40 CFR 265.13 - General waste analysis.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 26 2011-07-01 2011-07-01 false General waste analysis. 265.13 Section 265.13 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL...

40 CFR 265.76 - Unmanifested waste report.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Unmanifested waste report. 265.76 Section 265.76 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND...

40 CFR 265.13 - General waste analysis.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false General waste analysis. 265.13 Section 265.13 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL...

40 CFR 264.76 - Unmanifested waste report.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Unmanifested waste report. 264.76 Section 264.76 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES...

40 CFR 265.76 - Unmanifested waste report.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Unmanifested waste report. 265.76 Section 265.76 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND...

40 CFR 265.13 - General waste analysis.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 27 2012-07-01 2012-07-01 false General waste analysis. 265.13 Section 265.13 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL...

Method for destroying hazardous organics and other combustible materials in a subcritical/supercritical reactor

DOEpatents

Janikowski, Stuart K.

2000-01-01

A waste destruction method using a reactor vessel to combust and destroy organic and combustible waste, including the steps of introducing a supply of waste into the reactor vessel, introducing a supply of an oxidant into the reactor vessel to mix with the waste forming a waste and oxidant mixture, introducing a supply of water into the reactor vessel to mix with the waste and oxidant mixture forming a waste, water and oxidant mixture, reciprocatingly compressing the waste, water and oxidant mixture forming a compressed mixture, igniting the compressed mixture forming a exhaust gas, and venting the exhaust gas into the surrounding atmosphere.

Dissolution Behaviour of Metal Elements from Several Types of E-waste Using Leaching Test

NASA Astrophysics Data System (ADS)

Nor, Nik Hisyamudin Muhd; Amira Nordin, Nurul; Mohamad, Fariza; Jaibee, Shafizan; Ismail, Al Emran; Omar, Badrul; Fauzi Ahmad, Mohd; Rahim, Abd Khalil Abd; Kamaruddin, Muhamad Khalif Ikhwan Mohd; Turan, Faiz Mohd; Abu Bakar, Elmi; Yokoyama, Seiji

2017-08-01

Rapid development of the electrical and electronic was increasing annually due to the demand by the human being. Increasing production of electrical and electronic product led to the increasing of electric and electronic waste or can be called as the e-waste. The UN Environment Programme estimates that the world generates 20-50 million tons of the e-waste each year and the amount is raising three times faster than other forms of municipal waste. This study is focusing on the investigation of the dissolution behaviour of metal element from several types of e-waste by hydrometallurgical process. Leaching test was conducted on the e-waste by using acid as the reagent solution. Prior to the leaching test, manual dismantling, separation, and crushing process were carried out to the e-waste. The e-waste were characterized by Scanning Electron Microcopy (SEM) and the Energy Dispersive X-ray Spectroscopy (EDX) to define the elements inside the sample of e-waste. While the liquid residue from leaching test was analyzed by using Inductively Couple Plasma-Mass Spectrometer (ICP-MS) to define the dissolution behaviour of the metal element that contain in the e-waste. It was found that the longest time for dismantling process was the dismantling of laptop. The dissolution behaviour of Fe, Al, Zn and Pb elements in the e-waste has affected to the increase of pH. The increasing pH led to the reduction of the metals element during leaching process.

Melt processed crystalline ceramic waste forms for advanced nuclear fuel cycles: CRP T21027 1813: Processing technologies for high level waste, formulation of matrices and characterization of waste forms, task 17208: Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Amoroso, J. W.; Marra, J. C.

2015-08-26

A multi-phase ceramic waste form is being developed at the Savannah River National Laboratory (SRNL) for treatment of secondary waste streams generated by reprocessing commercial spent nuclear. The envisioned waste stream contains a mixture of transition, alkali, alkaline earth, and lanthanide metals. Ceramic waste forms are tailored (engineered) to incorporate waste components as part of their crystal structure based on knowledge from naturally found minerals containing radioactive and non-radioactive species similar to the radionuclides of concern in wastes from fuel reprocessing. The ability to tailor ceramics to mimic naturally occurring crystals substantiates the long term stability of such crystals (ceramics)more » over geologic timescales of interest for nuclear waste immobilization [1]. A durable multi-phase ceramic waste form tailored to incorporate all the waste components has the potential to broaden the available disposal options and thus minimize the storage and disposal costs associated with aqueous reprocessing. This report summarizes results from three years of work on the IAEA Coordinated Research Project on “Processing technologies for high level waste, formulation of matrices and characterization of waste forms” (T21027), and specific task “Melt Processed Crystalline Ceramic Waste Forms for Advanced Nuclear Fuel Cycles” (17208).« less

Melt processed crystalline ceramic waste forms for advanced nuclear fuel cycles: CRP T21027 1813: Processing technologies for high level waste, formulation of matrices and characterization of waste forms, Task 17208: Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Amoroso, J. W.; Marra, J. C.

2015-08-26

A multi-phase ceramic waste form is being developed at the Savannah River National Laboratory (SRNL) for treatment of secondary waste streams generated by reprocessing commercial spent nuclear. The envisioned waste stream contains a mixture of transition, alkali, alkaline earth, and lanthanide metals. Ceramic waste forms are tailored (engineered) to incorporate waste components as part of their crystal structure based on knowledge from naturally found minerals containing radioactive and non-radioactive species similar to the radionuclides of concern in wastes from fuel reprocessing. The ability to tailor ceramics to mimic naturally occurring crystals substantiates the long term stability of such crystals (ceramics)more » over geologic timescales of interest for nuclear waste immobilization [1]. A durable multi-phase ceramic waste form tailored to incorporate all the waste components has the potential to broaden the available disposal options and thus minimize the storage and disposal costs associated with aqueous reprocessing. This report summarizes results from three years of work on the IAEA Coordinated Research Project on “Processing technologies for high level waste, formulation of matrices and characterization of waste forms” (T21027), and specific task “Melt Processed Crystalline Ceramic Waste Forms for Advanced Nuclear Fuel Cycles” (17208).« less

Improvement of Leaching Resistance of Low-level Waste Form in Korea

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kim, J.Y.; Lee, B.C.; Kim, C.L.

2006-07-01

Low-level liquid concentrate wastes including boric acid have been immobilized with paraffin wax using concentrate waste drying system in Korean nuclear power plants since 1995. Small amount of low density polyethylene (LDPE) was added to increase the leaching resistance of the existing paraffin waste form and the influence of LDPE on the leaching behavior of waste form was investigated. It was observed that the leaching of nuclides immobilized within paraffin waste form remarkably reduced as the content of LDPE increased. The acceptance criteria of paraffin waste form associated with leachability index and compressive strength after the leaching test were successfullymore » satisfied with the help of LDPE. (authors)« less

40 CFR 262.210 - Making the hazardous waste determination in the laboratory before the unwanted material is...

Code of Federal Regulations, 2013 CFR

2013-07-01

...)(3) for acute hazardous waste, or § 261.5(g)(3) for hazardous waste. (e) An unwanted material that is... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Making the hazardous waste....210 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...

40 CFR 262.210 - Making the hazardous waste determination in the laboratory before the unwanted material is...

Code of Federal Regulations, 2014 CFR

2014-07-01

...)(3) for acute hazardous waste, or § 261.5(g)(3) for hazardous waste. (e) An unwanted material that is... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Making the hazardous waste....210 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...

40 CFR 262.210 - Making the hazardous waste determination in the laboratory before the unwanted material is...

Code of Federal Regulations, 2012 CFR

2012-07-01

...)(3) for acute hazardous waste, or § 261.5(g)(3) for hazardous waste. (e) An unwanted material that is... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Making the hazardous waste....210 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...

40 CFR 262.210 - Making the hazardous waste determination in the laboratory before the unwanted material is...

Code of Federal Regulations, 2010 CFR

2010-07-01

...)(3) for acute hazardous waste, or § 261.5(g)(3) for hazardous waste. (e) An unwanted material that is... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Making the hazardous waste....210 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...

40 CFR 262.210 - Making the hazardous waste determination in the laboratory before the unwanted material is...

Code of Federal Regulations, 2011 CFR

2011-07-01

...)(3) for acute hazardous waste, or § 261.5(g)(3) for hazardous waste. (e) An unwanted material that is... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Making the hazardous waste....210 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...

A U-bearing composite waste form for electrochemical processing wastes

NASA Astrophysics Data System (ADS)

Chen, X.; Ebert, W. L.; Indacochea, J. E.

2018-04-01

Metallic/ceramic composite waste forms are being developed to immobilize combined metallic and oxide waste streams generated during electrochemical recycling of used nuclear fuel. Composites were made for corrosion testing by reacting HT9 steel to represent fuel cladding, Zr and Mo to simulate metallic fuel waste, and a mixture of ZrO2, Nd2O3, and UO2 to represent oxide wastes. More than half of the added UO2 was reduced to metal and formed Fe-Zr-U intermetallics and most of the remaining UO2 and all of the Nd2O3 reacted to form zirconates. Fe-Cr-Mo intermetallics were also formed. Microstructure characterization of the intermetallic and ceramic phases that were generated and tests conducted to evaluate their corrosion behaviors indicate composite waste forms can accommodate both metallic and oxidized waste streams in durable host phases.

A U-bearing composite waste form for electrochemical processing wastes

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chen, X.; Ebert, W. L.; Indacochea, J. E.

Metallic/ceramic composite waste forms are being developed to immobilize combined metallic and oxide waste streams generated during electrochemical recycling of used nuclear fuel. Composites were made for corrosion testing by reacting HT9 steel to represent fuel cladding, Zr and Mo to simulate metallic fuel waste, and a mixture of ZrO2, Nd2O3, and UO2 to represent oxide wastes. More than half of the added UO2 was reduced to metal and formed Fe-Zr-U intermetallics and most of the remaining UO2 and all of the Nd2O3 reacted to form zirconates. Fe-Cr-Mo intermetallics were also formed. Microstructure characterization of the intermetallic and ceramic phasesmore » that were generated and tests conducted to evaluate their corrosion behaviors indicate composite waste forms can accommodate both metallic and oxidized waste streams in durable host phases. (c) 2018 Elsevier B.V. All rights reserved.« less

Stabilization and disposal of Argonne-West low-level mixed wastes in ceramicrete waste forms.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Barber, D. B.; Singh, D.; Strain, R. V.

1998-02-17

The technology of room-temperature-setting phosphate ceramics or Ceramicrete{trademark} technology, developed at Argonne National Laboratory (ANL)-East is being used to treat and dispose of low-level mixed wastes through the Department of Energy complex. During the past year, Ceramicrete{trademark} technology was implemented for field application at ANL-West. Debris wastes were treated and stabilized: (a) Hg-contaminated low-level radioactive crushed light bulbs and (b) low-level radioactive Pb-lined gloves (part of the MWIR {number_sign} AW-W002 waste stream). In addition to hazardous metals, these wastes are contaminated with low-level fission products. Initially, bench-scale waste forms with simulated and actual waste streams were fabricated by acid-base reactionsmore » between mixtures of magnesium oxide powders and an acid phosphate solution, and the wastes. Size reduction of Pb-lined plastic glove waste was accomplished by cryofractionation. The Ceramicrete{trademark} process produces dense, hard ceramic waste forms. Toxicity Characteristic Leaching Procedure (TCLP) results showed excellent stabilization of both Hg and Pb in the waste forms. The principal advantage of this technology is that immobilization of contaminants is the result of both chemical stabilization and subsequent microencapsulation of the reaction products. Based on bench-scale studies, Ceramicrete{trademark} technology has been implemented in the fabrication of 5-gal waste forms at ANL-West. Approximately 35 kg of real waste has been treated. The TCLP is being conducted on the samples from the 5-gal waste forms. It is expected that because the waste forms pass the limits set by the EPAs Universal Treatment Standard, they will be sent to a radioactive-waste disposal facility.« less

40 CFR 240.201 - Solid wastes excluded.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Solid wastes excluded. 240.201 Section 240.201 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.201 Solid...

40 CFR 240.201 - Solid wastes excluded.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Solid wastes excluded. 240.201 Section 240.201 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.201 Solid...

40 CFR 240.200 - Solid wastes accepted.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Solid wastes accepted. 240.200 Section 240.200 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.200 Solid...

40 CFR 240.200 - Solid wastes accepted.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Solid wastes accepted. 240.200 Section 240.200 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR THE THERMAL PROCESSING OF SOLID WASTES Requirements and Recommended Procedures § 240.200 Solid...

Emission of nanoparticles during combustion of waste biomass in fireplace

NASA Astrophysics Data System (ADS)

Drastichová, Vendula; Krpec, Kamil; Horák, Jiří; Hopan, František; Kubesa, Petr; Martiník, Lubomír; Koloničný, Jan; Ochodek, Tadeáš; Holubčík, Michal

2014-08-01

Contamination of air by solid particles is serious problem for human health and also environment. Small particles in nano-sizes are more dangerous than same weight of larger size. Negative effect namely of the solid particles depends on (i) number, (ii) specific surface area (iii) respirability and (iv) bonding of others substances (e.g. PAHs, As, Cd, Zn, Cu etc.) which are higher for smaller (nano-sizes) particles compared to larger one. For this reason mentioned above this contribution deals with measuring of amount, and distribution of nanoparticles produced form combustion of waste city biomass in small combustion unit with impactor DLPI.

Genome-Based Models to Optimize In Situ Bioremediation of Uranium and Harvesting Electrical Energy from Waste Organic Matter

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lovley, Derek R

2012-12-28

The goal of this research was to provide computational tools to predictively model the behavior of two microbial communities of direct relevance to Department of Energy interests: 1) the microbial community responsible for in situ bioremediation of uranium in contaminated subsurface environments; and 2) the microbial community capable of harvesting electricity from waste organic matter and renewable biomass. During this project the concept of microbial electrosynthesis, a novel form of artificial photosynthesis for the direct production of fuels and other organic commodities from carbon dioxide and water was also developed and research was expanded into this area as well.

Liquid secondary waste: Waste form formulation and qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cozzi, A. D.; Dixon, K. L.; Hill, K. A.

The Hanford Site Effluent Treatment Facility (ETF) currently treats aqueous waste streams generated during site cleanup activities. When the Hanford Tank Waste Treatment and Immobilization Plant (WTP) begins operations, including Direct Feed Low Activity Waste (DFLAW) vitrification, a liquid secondary waste (LSW) stream from the WTP will need to be treated. The volume of effluent for treatment at the ETF will increase significantly. The powdered salt waste form produced by the ETF will be replaced by a stabilized solidified waste form for disposal in Hanford’s Integrated Disposal Facility (IDF). Washington River Protection Solutions is implementing a Secondary Liquid Waste Immobilizationmore » Technology Development Plan to address the technology needs for a waste form and solidification process to treat the increased volume of waste planned for disposal at the IDF. Waste form testing to support this plan is composed of work in the near term to provide data as input to a performance assessment (PA) for Hanford’s IDF. In 2015, three Hanford Liquid Secondary Waste simulants were developed based on existing and projected waste streams. Using these waste simulants, fourteen mixes of Hanford Liquid Secondary Waste were prepared and tested varying the waste simulant, the water-to-dry materials ratio, and the dry materials blend composition.1 In FY16, testing was performed using a simulant of the EMF process condensate blended with the caustic scrubber—from the Low Activity Waste (LAW) melter—, processed through the ETF. The initial EMF-16 simulant will be based on modeling efforts performed to determine the mass balance of the ETF for the DFLAW.2 The compressive strength of all of the mixes exceeded the target of 3.4 MPa (500 psi) to meet the requirements identified as potential IDF Waste Acceptance Criteria in Table 1 of the Secondary Liquid Waste Immobilization Technology Development Plan.3 The hydraulic properties of the waste forms tested (hydraulic conductivity and water characteristic curves) were comparable to the properties measured on the Savannah River Site (SRS) Saltstone waste form. Future testing should include efforts to first; 1) determine the rate and amount of ammonia released during each unit operation of the treatment process to determine if additional ammonia management is required, then; 2) reduce the ammonia content of the ETF concentrated brine prior to solidification, making the waste more amenable to grouting, or 3) manage the release of ammonia during production and ongoing release during storage of the waste form, or 4) develop a lower pH process/waste form thereby precluding ammonia release.« less

Illustrations of the importance of mass wasting in the evolution of continental margins

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pratson, L.; Ryan, W.; Twichell, D.

1990-05-01

Side-looking sonar imagery and swath bathymetry from a variety of contemporary continental slopes all display erosional scars and debris aprons, illustrating the importance of mass wasting in the evolution of continental margins. The continental slopes examined include slopes fed directly from the fronts of ice sheets, slopes adjacent to continental shelves that were the sites of glacial outwash, slopes supplied exclusively by fluvial drainage, slopes at carbonate platforms, and slopes on accretionary prisms. Examples are drawn from the Atlantic Ocean, the Gulf of Mexico, and the Mediterranean Sea in both passive and active continental margin settings. The sonar imagery andmore » bathymetry used in this study indicate that continental slopes in different tectonic and climatic environments show similar forms of mass wasting. However, in some cases the dominant mode of erosion and/or the overall degree of mass wasting appears to be distinct to particular sedimentary environments. Timing of both recent and older exhumed erosional surfaces identified in the imagery and in seismic reflection profiles is obtained by ground truth observations using submersibles, towed camera sleds, drilling, and coring. These observations suggest that eustatic fluctuations common to all the margins examined do not explain the range in magnitude and areal density of the observed mass wasting. More localized factors such as lithology, diagenesis, pore fluid conditions, sediment supply rates, and seismic ground motion appear to have a major influence in the evolution of erosional scars and their corresponding unconformities.« less

40 CFR 264.1 - Purpose, scope and applicability.

Code of Federal Regulations, 2014 CFR

2014-07-01

... waste. (D) An immediate threat to human health, public safety, property, or the environment, from the... material or waste is necessary to protect human health or the environment, that official or specialist may..., a release of hazardous waste constituents to the environment, or a threat to human health. The owner...

Endurance of high molecular weight carboxymethyl cellulose in corrosive environments

NASA Astrophysics Data System (ADS)

Murodov, M. M.; Rahmanberdiev, G. R.; Khalikov, M. M.; Egamberdiev, E. A.; Negmatova, K. C.; Saidov, M. M.; Mahmudova, N.

2012-07-01

Lignin obtained from the waste cooking liquor, formed after soda pulping process, is used as an inhibitor of NaCMC thermo oxidative degradation in presence of in extreme conditions during drilling oil wells. In this paper the schematic process of obtaining NaCMC by the principle of "monoapparat" on the basis of cellulose produced by non-wood cellulose materials is presented.

40 CFR 264.551 - Grandfathered Corrective Action Management Units (CAMUs).

Code of Federal Regulations, 2011 CFR

2011-07-01

... risks to humans or to the environment resulting from exposure to hazardous wastes or hazardous... human health and the environment, to include, for areas where wastes will remain in place, monitoring... (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE...

40 CFR 264.551 - Grandfathered Corrective Action Management Units (CAMUs).

Code of Federal Regulations, 2013 CFR

2013-07-01

... risks to humans or to the environment resulting from exposure to hazardous wastes or hazardous... human health and the environment, to include, for areas where wastes will remain in place, monitoring... (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE...

40 CFR 266.202 - Definition of solid waste.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Definition of solid waste. 266.202 Section 266.202 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... MANAGEMENT FACILITIES Military Munitions § 266.202 Definition of solid waste. (a) A military munition is not...

40 CFR 266.202 - Definition of solid waste.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Definition of solid waste. 266.202 Section 266.202 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... MANAGEMENT FACILITIES Military Munitions § 266.202 Definition of solid waste. (a) A military munition is not...

40 CFR 279.21 - Hazardous waste mixing.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 27 2014-07-01 2014-07-01 false Hazardous waste mixing. 279.21 Section 279.21 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF USED OIL Standards for Used Oil Generators § 279.21 Hazardous waste mixing...

40 CFR 279.21 - Hazardous waste mixing.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Hazardous waste mixing. 279.21 Section 279.21 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF USED OIL Standards for Used Oil Generators § 279.21 Hazardous waste mixing...

40 CFR 279.21 - Hazardous waste mixing.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 28 2013-07-01 2013-07-01 false Hazardous waste mixing. 279.21 Section 279.21 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF USED OIL Standards for Used Oil Generators § 279.21 Hazardous waste mixing...

40 CFR 279.21 - Hazardous waste mixing.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 28 2012-07-01 2012-07-01 false Hazardous waste mixing. 279.21 Section 279.21 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF USED OIL Standards for Used Oil Generators § 279.21 Hazardous waste mixing...

40 CFR 279.21 - Hazardous waste mixing.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Hazardous waste mixing. 279.21 Section 279.21 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF USED OIL Standards for Used Oil Generators § 279.21 Hazardous waste mixing...

40 CFR 262.11 - Hazardous waste determination.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Hazardous waste determination. 262.11 Section 262.11 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES... Administrator under 40 CFR 260.21; or (2) Applying knowledge of the hazard characteristic of the waste in light...

40 CFR 60.1440 - What is yard waste?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 7 2013-07-01 2013-07-01 false What is yard waste? 60.1440 Section 60.1440 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED....1440 What is yard waste? Yard waste is grass, grass clippings, bushes, shrubs, and clippings from...

40 CFR 60.1440 - What is yard waste?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 7 2014-07-01 2014-07-01 false What is yard waste? 60.1440 Section 60.1440 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED....1440 What is yard waste? Yard waste is grass, grass clippings, bushes, shrubs, and clippings from...

Progress in the Assessment of Waste-forms for the Immobilisation of UK Civil Plutonium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harrison, M.T.; Scales, C.R.; Maddrell, E.R.

The alternatives for the disposition of the UK's civil plutonium stocks are currently being investigated by Nexia Solutions Ltd. on behalf of the Nuclear Decommissioning Authority (NDA). A number of scenarios are currently being considered depending on the strategic requirements of the UK. The two main disposition options are: re-use as MOX (Mixed Oxide) fuel in reactors, or immobilisation in the event of any material being declared surplus to requirements. The amount of Pu which will require immobilisation will depend on future UK nuclear strategy, along with the extent of any stocks deemed unsuitable for re-use. However, it is likelymore » that some portion will have to be immobilised and therefore three credible waste-forms are under consideration; ceramic, glass and 'immobilisation' MOX. These are currently being developed and assessed in a systematic programme that involves periodic evaluation against a range of criteria. In this way, by down-selecting on the basis of robust and technical review, the most appropriate option for immobilising surplus civil plutonium in the UK can be recommended. The latest results from the immobilisation experimental programme are presented following the de-selection of the least favourable glass and ceramic candidates. The main criteria for this decision were waste loading, durability, processability, criticality and proliferation resistance. In addition, the durability of unirradiated MOX fuel is being examined to determine its potential as a wasteform for Pu, and recent leach test data is discussed. The current evaluation comprises not only a comparison of the relevant physical properties of the various waste-forms, but also key processing parameters, e.g. glass viscosity and melter technology, ceramic fabrication routes, and criticality issues. Other important aspects of the long-term behaviour of the waste-forms under consideration in a potential repository environment, such as radiation damage, criticality control and the properties of any neutron poisons present, are also included. (authors)« less

Converting untreated waste office paper and chitosan into aerogel adsorbent for the removal of heavy metal ions.

PubMed

Li, Zhanying; Shao, Lin; Ruan, Zehai; Hu, Wenbin; Lu, Lingbin; Chen, Yongjun

2018-08-01

The utilization of waste paper, an obsolete recyclable resource, helps to save resources and protect environment. In this paper, an aerogel was prepared to convert the waste paper into a useful material, which was used to adsorb heavy metal ions and handle water pollution. Combining waste office paper and chitosan, the aerogel obtained the enhanced mechanical strength, acid resistance and high adsorption capacity (up to 156.3 mg/g for Cu 2+ ). This adsorption process obeyed the pseudo-second order model and the Langmuir model. The research showed that a coordination compound was formed between amino group and Cu 2+ during the adsorption process. The adsorbent could be regenerated well in 0.1 M H 2 SO 4 with up to 98.3% desorption efficiency. The low cost, environmental friendliness, excellent adsorption capacity and regeneration ability made this novel aerogel a promising adsorbent for heavy metal ions. And this conversion is an effective reuse way of waste paper too. Copyright © 2018 Elsevier Ltd. All rights reserved.

Medical waste management in Jordan: A study at the King Hussein Medical Center

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oweis, Rami; Al-Widyan, Mohamad; Al-Limoon, Ohood

2005-07-01

As in many other developing countries, the generation of regulated medical waste (RMW) in Jordan has increased significantly over the last few decades. Despite the serious impacts of RMW on humans and the environment, only minor attention has been directed to its proper handling and disposal. This study was conducted in the form of a case study at one of Jordan's leading medical centers, namely, the King Hussein Medical Center (KHMC). Its purpose was to report on the current status of medical waste management at KHMC and propose possible measures to improve it. In general, it was found that themore » center's administration was reasonably aware of the importance of medical waste management and practiced some of the measures to adequately handle waste generated at the center. However, it was also found that significant voids were present that need to be addressed in the future including efficient segregation, the use of coded and colored bags, better handling and transfer means, and better monitoring and tracking techniques, as well as the need for training and awareness programs for the personnel.« less

Performance Assessments of Generic Nuclear Waste Repositories in Shale

NASA Astrophysics Data System (ADS)

Stein, E. R.; Sevougian, S. D.; Mariner, P. E.; Hammond, G. E.; Frederick, J.

2017-12-01

Simulations of deep geologic disposal of nuclear waste in a generic shale formation showcase Geologic Disposal Safety Assessment (GDSA) Framework, a toolkit for repository performance assessment (PA) whose capabilities include domain discretization (Cubit), multiphysics simulations (PFLOTRAN), uncertainty and sensitivity analysis (Dakota), and visualization (Paraview). GDSA Framework is used to conduct PAs of two generic repositories in shale. The first considers the disposal of 22,000 metric tons heavy metal of commercial spent nuclear fuel. The second considers disposal of defense-related spent nuclear fuel and high level waste. Each PA accounts for the thermal load and radionuclide inventory of applicable waste types, components of the engineered barrier system, and components of the natural barrier system including the host rock shale and underlying and overlying stratigraphic units. Model domains are half-symmetry, gridded with Cubit, and contain between 7 and 22 million grid cells. Grid refinement captures the detail of individual waste packages, emplacement drifts, access drifts, and shafts. Simulations are run in a high performance computing environment on as many as 2048 processes. Equations describing coupled heat and fluid flow and reactive transport are solved with PFLOTRAN, an open-source, massively parallel multiphase flow and reactive transport code. Additional simulated processes include waste package degradation, waste form dissolution, radioactive decay and ingrowth, sorption, solubility, advection, dispersion, and diffusion. Simulations are run to 106 y, and radionuclide concentrations are observed within aquifers at a point approximately 5 km downgradient of the repository. Dakota is used to sample likely ranges of input parameters including waste form and waste package degradation rates and properties of engineered and natural materials to quantify uncertainty in predicted concentrations and sensitivity to input parameters. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology and Engineering Solutions of Sandia, LLC., a wholly owned subsidiary of Honeywell International, Inc., for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-NA-0003525. SAND2017- 8305 A

Accessories modifying based on plastic waste of shampoo bottle as home economic product

NASA Astrophysics Data System (ADS)

Setyowati, Erna; Sukesi, Siti

2018-03-01

Plastic is a waste that can not decompose by the soil and if its left without a good handling can pollute the environment. Plastic waste needs processing by the recycle bottles principle. Shampoo bottle is one of plastic waste with high density polyethylene type (HDPE). One of the innovation to recycling shampoo bottles waste into the new products whichbeneficially and aestheticallyform by engineered the buns accesories. Accessories are one of the tools used by most women, in the form of trinkets or ornaments which ajusted to the trend to beautify the look. Accessories from shampoo bottle waste can be obtained from household waste, beauty salon and the beauty program study by inculcating human beings' behavior by transforming waste into blessing while also increasing family income. Technique of making its by compiling through improvement of panelist team. The goal of this research is to engineering theaccessories based on shampoo bottle waste as home economics. The method are using experiment, observation and documentation, analysis using descriptive. The results obtained from the overall sensory test averaged at 93%, while the favored test averaged at 85.5%. The product can be ordered according to the desired design, but it takes a long time. Therefore accessories engineering from shampoo bottles waste-based can be used as home economics. The production of shampoo bottles waste-based accessories should improved its quality and quantity, to be marketed through the community, by the cooperation with accessories and bun craftsmen.

Electrical and electronic waste: a global environmental problem.

PubMed

Ramesh Babu, Balakrishnan; Parande, Anand Kuber; Ahmed Basha, Chiya

2007-08-01

The production of electrical and electronic equipment (EEE) is one of the fastest growing global manufacturing activities. This development has resulted in an increase of waste electric and electronic equipment (WEEE). Rapid economic growth, coupled with urbanization and growing demand for consumer goods, has increased both the consumption of EEE and the production of WEEE, which can be a source of hazardous wastes that pose a risk to the environment and to sustainable economic growth. To address potential environmental problems that could stem from improper management of WEEE, many countries and organizations have drafted national legislation to improve the reuse, recycling and other forms of material recovery from WEEE to reduce the amount and types of materials disposed in landfills. Recycling of waste electric and electronic equipment is important not only to reduce the amount of waste requiring treatment, but also to promote the recovery of valuable materials. EEE is diverse and complex with respect to the materials and components used and waste streams from the manufacturing processes. Characterization of these wastes is of paramount importance for developing a cost-effective and environmentally sound recycling system. This paper offers an overview of electrical and e-waste recycling, including a description of how it is generated and classified, strategies and technologies for recovering materials, and new scientific developments related to these activities. Finally, the e-waste recycling industry in India is also discussed.

Mineral transformation controls speciation and pore-fluid transmission of contaminants in waste-weathered Hanford sediments

NASA Astrophysics Data System (ADS)

Perdrial, Nicolas; Thompson, Aaron; O'Day, Peggy A.; Steefel, Carl I.; Chorover, Jon

2014-09-01

Portions of the Hanford Site (WA, USA) vadose zone were subjected to weathering by caustic solutions during documented releases of high level radioactive waste (containing Sr, Cs and I) from leaking underground storage tanks. Previous studies have shown that waste-sediment interactions can promote variable incorporation of contaminants into neo-formed mineral products (including feldspathoids and zeolites), but processes regulating the subsequent contaminant release from these phases into infiltrating background pore waters remain poorly known. In this paper, reactive transport experiments were conducted with Hanford sediments previously weathered for one year in simulated hyper-alkaline waste solutions containing high or low 88Sr, 127I, and 133Cs concentrations, with or without CO2(aq). These waste-weathered sediments were leached in flow-through column experiments with simulated background pore water (characteristic of meteoric recharge) to measure contaminant release from solids formed during waste-sediment interaction. Contaminant sorption-desorption kinetics and mineral transformation reactions were both monitored using continuous-flow and wet-dry cycling regimes for ca. 300 pore volumes. Less than 20% of contaminant 133Cs and 88Sr mass and less than 40% 127I mass were released over the course of the experiment. To elucidate molecular processes limiting contaminant release, reacted sediments were studied with micro- (TEM and XRD) and molecular- (Sr K-edge EXAFS) scale methods. Contaminant dynamics in column experiments were principally controlled by rapid dissolution of labile solids and competitive exchange reactions. In initially feldspathoidic systems, time-dependent changes in the local zeolitic bonding environment observed with X-ray diffraction and EXAFS are responsible for limiting contaminant release. Linear combination fits and shell-by-shell analysis of Sr K-edge EXAFS data revealed modification in Sr-Si/Al distances within the zeolite cage. Wet-dry cycling did not affect significantly molecular-scale transformations relative to continuous-flow controls. Results indicate that contaminants bound to the solid phase in distinct micro- and molecular-scale coordinative environments can generate similar macro-scale release behaviors, highlighting the need for multi-scale interrogations to constrain mechanisms of reactive transport. Data also indicate that weathering-induced change in ion exchange selectivity coefficients should be incorporated in simulations of contaminant release from caustic high-level radioactive waste impacted sediments.

Liquid secondary waste. Waste form formulation and qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cozzi, A. D.; Dixon, K. L.; Hill, K. A.

The Hanford Site Effluent Treatment Facility (ETF) currently treats aqueous waste streams generated during Site cleanup activities. When the Hanford Tank Waste Treatment and Immobilization Plant (WTP) begins operations, a liquid secondary waste (LSW) stream from the WTP will need to be treated. The volume of effluent for treatment at the ETF will increase significantly. Washington River Protection Solutions is implementing a Secondary Liquid Waste Immobilization Technology Development Plan to address the technology needs for a waste form and solidification process to treat the increased volume of waste planned for disposal at the Integrated Disposal Facility IDF). Waste form testingmore » to support this plan is composed of work in the near term to demonstrate the waste form will provide data as input to a performance assessment (PA) for Hanford’s IDF.« less

Glass Ceramic Waste Forms for Combined CS+LN+TM Fission Products Waste Streams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crum, Jarrod V.; Turo, Laura A.; Riley, Brian J.

2010-09-23

In this study, glass ceramics were explored as an alternative waste form for glass, the current baseline, to be used for immobilizing alkaline/alkaline earth + lanthanide (CS+LN) or CS+LN+transition metal (TM) fission-product waste streams generated by a uranium extraction (UREX+) aqueous separations type process. Results from past work on a glass waste form for the combined CS+LN waste streams showed that as waste loading increased, large fractions of crystalline phases precipitated upon slow cooling.[1] The crystalline phases had no noticeable impact on the waste form performance by the 7-day product consistency test (PCT). These results point towards the development ofmore » a glass ceramic waste form for treating CS+LN or CS+LN+TM combined waste streams. Three main benefits for exploring glass ceramics are: (1) Glass ceramics offer increased solubility of troublesome components in crystalline phases as compared to glass, leading to increased waste loading; (2) The crystalline network formed in the glass ceramic results in higher heat tolerance than glass; and (3) These glass ceramics are designed to be processed by the same melter technology as the current baseline glass waste form. It will only require adding controlled canister cooling for crystallization into a glass ceramic waste form. Highly annealed waste form (essentially crack free) with up to 50X lower surface area than a typical High-Level Waste (HLW) glass canister. Lower surface area translates directly into increased durability. This was the first full year of exploring glass ceramics for the Option 1 and 2 combined waste stream options. This work has shown that dramatic increases in waste loading are achievable by designing a glass ceramic waste form as an alternative to glass. Table S1 shows the upper limits for heat, waste loading (based on solubility), and the decay time needed before treatment can occur for glass and glass ceramic waste forms. The improvements are significant for both combined waste stream options in terms of waste loading and/or decay time required before treatment. For Option 1, glass ceramics show an increase in waste loading of 15 mass % and reduction in decay time of 24 years. Decay times of {approx}50 years or longer are close to the expected age of the fuel that will be reprocessed when the modified open or closed fuel cycle is expected to be put into action. Option 2 shows a 2x to 2.5x increase in waste loading with decay times of only 45 years. Note that for Option 2 glass, the required decay time before treatment is only 35 years because of the waste loading limits related to the solubility of MoO{sub 3} in glass. If glass was evaluated for similar waste loadings as those achieved in Option 2 glass ceramics, the decay time would be significantly longer than 45 years. These glass ceramics are not optimized, but already they show the potential to dramatically reduce the amount of waste generated while still utilizing the proven processing technology used for glass production.« less

Study of agricultural waste treatment in China and Russia-based on the agriculture environment sustainable development

NASA Astrophysics Data System (ADS)

Chernyaeva, Victoria A.; Teng, Xiuyi; Sergio

2017-06-01

China and Russia are both agriculture countries, agricultural environment sustainable development is very important for them. The paper studies three main agricultural wastes: straw, organic waste and plastic waste, and analyzes their treatments with the view of agricultural sustainable development.

40 CFR 265.281 - Special requirements for ignitable or reactive waste.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Special requirements for ignitable or reactive waste. 265.281 Section 265.281 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... waste is immediately incorporated into the soil so that: (1) The resulting waste, mixture, or...

40 CFR 261.7 - Residues of hazardous waste in empty containers.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Residues of hazardous waste in empty containers. 261.7 Section 261.7 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION AND LISTING OF HAZARDOUS WASTE General § 261.7 Residues of hazardous...

High-level waste program progress report, April 1, 1980-June 30, 1980

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

1980-08-01

The highlights of this report are on: waste management analysis for nuclear fuel cycles; fixation of waste in concrete; study of ceramic and cermet waste forms; alternative high-level waste forms development; and high-level waste container development.

Spent fuel treatment and mineral waste form development at Argonne National Laboratory-West

DOE Office of Scientific and Technical Information (OSTI.GOV)

Goff, K.M.; Benedict, R.W.; Bateman, K.

1996-07-01

At Argonne National Laboratory-West (ANL-West) there are several thousand kilograms of metallic spent nuclear fuel containing bond sodium. This fuel will be treated in the Fuel Conditioning Facility (FCF) at ANL-West to produce stable waste forms for storage and disposal. Both mineral and metal high-level waste forms will be produced. The mineral waste form will contain the active metal fission products and the transuranics. Cold small-scale waste form testing has been on-going at Argonne in Illinois. Large-scale testing is commencing at ANL-West.

Batching alternatives for Phase I retrieval wastes to be processed in WRAP Module 1

DOE Office of Scientific and Technical Information (OSTI.GOV)

Mayancsik, B.A.

1994-10-13

During the next two decades, the transuranic (TRU) waste now stored in the 200 Area burial trenches and storage buildings is to be retrieved, processed in the Waste Receiving and Processing (WRAP) Module 1 facility, and shipped to a final disposal facility. The purpose of this document is to identify the criteria that can be used to batch suspect TRU waste, currently in retrievable storage, for processing through the WRAP Module 1 facility. These criteria are then used to generate a batch plan for Phase 1 Retrieval operations, which will retrieve the waste located in Trench 4C-04 of the 200more » West Area burial ground. The reasons for batching wastes for processing in WRAP Module 1 include reducing the exposure of workers and the environment to hazardous material and ionizing radiation; maximizing the efficiency of the retrieval, processing, and disposal processes by reducing costs, time, and space throughout the process; reducing analytical sampling and analysis; and reducing the amount of cleanup and decontamination between process runs. The criteria selected for batching the drums of retrieved waste entering WRAP Module 1 are based on the available records for the wastes sent to storage as well as knowledge of the processes that generated these wastes. The batching criteria identified in this document include the following: waste generator; type of process used to generate or package the waste; physical waste form; content of hazardous/dangerous chemicals in the waste; radiochemical type and quantity of waste; drum weight; and special waste types. These criteria were applied to the waste drums currently stored in Trench 4C-04. At least one batching scheme is shown for each of the criteria listed above.« less

Options for the Separation and Immobilization of Technetium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Serne, R Jeffrey; Crum, Jarrod V.; Riley, Brian J.

Among radioactive constituents present in the Hanford tank waste, technetium-99 (Tc) presents a unique challenge in that it is significantly radiotoxic, exists predominantly in the liquid low-activity waste (LAW), and has proven difficult to effectively stabilize in a waste form for ultimate disposal. Within the Hanford Tank Waste Treatment and Immobilization Plant, the LAW fraction will be converted to a glass waste form in the LAW vitrification facility, but a significant fraction of Tc volatilizes at the high glass-melting temperatures and is captured in the off-gas treatment system. This necessitates recycle of the off-gas condensate solution to the LAW glassmore » melter feed. The recycle process is effective in increasing the loading of Tc in the immobilized LAW (ILAW), but it also disproportionately increases the sulfur and halides in the LAW melter feed, which have limited solubility in the LAW glass and thus significantly reduce the amount of LAW (glass waste loading) that can be vitrified and still maintain good waste form properties. This increases both the amount of LAW glass and either the duration of the LAW vitrification mission or requires the need for supplemental LAW treatment capacity. Several options are being considered to address this issue. Two approaches attempt to minimize the off-gas recycle by removing Tc at one of several possible points within the tank waste processing flowsheet. The separated Tc from these two approaches must then be dispositioned in a manner such that the Tc can be safely disposed. Alternative waste forms that do not have the Tc volatility issues associated with the vitrification process are being sought for immobilization of Tc for subsequent storage and disposal. The first objective of this report is to provide insights into the compositions and volumes of the Tc-bearing waste streams including the ion exchange eluate from processing LAW and the off-gas condensate from the melter. The first step to be assessed will be the processing of ion exchange eluate. The second objective of this report is to assess the compatibility of the available waste forms with the anticipated waste streams. Two major categories of Tc-specific waste forms are considered in this report including mineral and metal waste forms. Overall, it is concluded that a metal alloy waste form is the most promising and mature Tc-specific waste form and offers several benefits. One obvious advantage of the disposition of Tc in the metal alloy waste form is the significant reduction of the generated waste form volume, which leads to a reduction of the required storage facility footprint. Among mineral waste forms, glass-bonded sodalite and possibly goethite should also be considered for the immobilization of Tc.« less

Analysis of space systems for the space disposal of nuclear waste follow-on study. Volume 2. Technical report

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

1982-01-01

Some of the conclusions reached as a result of this study are summarized. Waste form parameters for the reference cermet waste form are available only by analogy. Detail design of the waste payload would require determination of actual waste form properties. The billet configuration constraints for the cermet waste form limit the packing efficiency to slightly under 75% net volume. The effect of this packing inefficiency in reducing the net waste form per waste payload can be seen graphically. The cermet waste form mass per unit mass of waste payload is lower than that of the iodine waste form evenmore » though the cermet has a higher density (6.5 versus 5.5). This is because the lead iodide is cast achieving almost 100% efficiency in packing. This inefficiency in the packing of the cermet results in a 20% increase in number of flights which increases both cost and risk. Alternative systems for waste mixes requiring low flight rates (technetium-99, iodine-129) can make effective use of the existing 65K space transportation system in either single- or dual-launch scenarios. A comprehensive trade study would be required to select the optimum orbit transfer system for low-launch-rate systems. This study was not conducted as part of the present effort due to selection of the cermet waste form as the reference for the study. Several candidates look attractive for both single- and dual-launch systems (see sec. 4.4), but due to the relatively small number of missions, a comprehensive comparison of life cycle costs including DDT and E would be required to select the best system. The reference system described in sections 5.0, 6.0, 7.0, and 8.0 offers the best combination of cost, risk, and alignment with ongoing NASA technology development efforts for disposal of the reference cermet waste form.« less

West Valley demonstration project: Alternative processes for solidifying the high-level wastes

NASA Astrophysics Data System (ADS)

Holton, L. K.; Larson, D. E.; Partain, W. L.; Treat, R. L.

1981-10-01

Two pretreatment approaches and several waste form processes for radioactive wastes were selected for evaluation. The two waste treatment approaches were the salt/sludge separation process and the combined waste process. Both terminal and interim waste form processes were studied.

Potential metal recovery from waste streams

USGS Publications Warehouse

Smith, Kathleen S.; Hageman, Philip L.; Plumlee, Geoffrey S.; Budahn, James R.; Bleiwas, Donald I.

2015-01-01

‘Waste stream’ is a general term that describes the total flow of waste from homes, businesses, industrial facilities, and institutions that are recycled, burned or isolated from the environment in landfills or other types of storage, or dissipated into the environment. The recovery and reuse of chemical elements from waste streams have the potential to decrease U.S. reliance on primary resources and imports, and to lessen unwanted dispersion of some potentially harmful elements into the environment. Additional benefits might include reducing disposal or treatment costs and decreasing the risk of future environmental liabilities for waste generators. Elemental chemistry and mineralogical residences of the elements are poorly documented for many types of waste streams.

40 CFR 761.345 - Form of the waste to be sampled.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Characterization for PCB Disposal in Accordance With § 761.62, and Sampling PCB Remediation Waste Destined for Off-Site Disposal, in Accordance With § 761.61 § 761.345 Form of the waste to be sampled. PCB bulk product waste and PCB remediation waste destined for off-site disposal must be in the form of either flattened...

Underground waste barrier structure

DOEpatents

Saha, Anuj J.; Grant, David C.

1988-01-01

Disclosed is an underground waste barrier structure that consists of waste material, a first container formed of activated carbonaceous material enclosing the waste material, a second container formed of zeolite enclosing the first container, and clay covering the second container. The underground waste barrier structure is constructed by forming a recessed area within the earth, lining the recessed area with a layer of clay, lining the clay with a layer of zeolite, lining the zeolite with a layer of activated carbonaceous material, placing the waste material within the lined recessed area, forming a ceiling over the waste material of a layer of activated carbonaceous material, a layer of zeolite, and a layer of clay, the layers in the ceiling cojoining with the respective layers forming the walls of the structure, and finally, covering the ceiling with earth.

DuraLith geopolymer waste form for Hanford secondary waste: correlating setting behavior to hydration heat evolution.

PubMed

Xu, Hui; Gong, Weiliang; Syltebo, Larry; Lutze, Werner; Pegg, Ian L

2014-08-15

The binary furnace slag-metakaolin DuraLith geopolymer waste form, which has been considered as one of the candidate waste forms for immobilization of certain Hanford secondary wastes (HSW) from the vitrification of nuclear wastes at the Hanford Site, Washington, was extended to a ternary fly ash-furnace slag-metakaolin system to improve workability, reduce hydration heat, and evaluate high HSW waste loading. A concentrated HSW simulant, consisting of more than 20 chemicals with a sodium concentration of 5 mol/L, was employed to prepare the alkaline activating solution. Fly ash was incorporated at up to 60 wt% into the binder materials, whereas metakaolin was kept constant at 26 wt%. The fresh waste form pastes were subjected to isothermal calorimetry and setting time measurement, and the cured samples were further characterized by compressive strength and TCLP leach tests. This study has firstly established quantitative linear relationships between both initial and final setting times and hydration heat, which were never discovered in scientific literature for any cementitious waste form or geopolymeric material. The successful establishment of the correlations between setting times and hydration heat may make it possible to efficiently design and optimize cementitious waste forms and industrial wastes based geopolymers using limited testing results. Copyright © 2014 Elsevier B.V. All rights reserved.

40 CFR 62.14580 - What is a waste management plan?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 8 2010-07-01 2010-07-01 false What is a waste management plan? 62.14580 Section 62.14580 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Construction On or Before November 30, 1999 Waste Management Plan § 62.14580 What is a waste management plan? A...

40 CFR 60.2899 - What is a waste management plan?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 6 2010-07-01 2010-07-01 false What is a waste management plan? 60.2899 Section 60.2899 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... Management Plan § 60.2899 What is a waste management plan? A waste management plan is a written plan that...

40 CFR 60.2060 - When must I submit my waste management plan?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 7 2013-07-01 2013-07-01 false When must I submit my waste management plan? 60.2060 Section 60.2060 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Commercial and Industrial Solid Waste Incineration Units Waste Management Plan § 60.2060 When must I submit...

40 CFR 60.2060 - When must I submit my waste management plan?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 7 2014-07-01 2014-07-01 false When must I submit my waste management plan? 60.2060 Section 60.2060 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Commercial and Industrial Solid Waste Incineration Units Waste Management Plan § 60.2060 When must I submit...

40 CFR 262.212 - Making the hazardous waste determination at an on-site interim status or permitted treatment...

Code of Federal Regulations, 2011 CFR

2011-07-01

... permitted treatment, storage or disposal facility. (e) If the unwanted material is a hazardous waste, the... 40 Protection of Environment 26 2011-07-01 2011-07-01 false Making the hazardous waste... 262.212 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...

40 CFR 262.212 - Making the hazardous waste determination at an on-site interim status or permitted treatment...

Code of Federal Regulations, 2012 CFR

2012-07-01

... permitted treatment, storage or disposal facility. (e) If the unwanted material is a hazardous waste, the... 40 Protection of Environment 27 2012-07-01 2012-07-01 false Making the hazardous waste... 262.212 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...

40 CFR 262.212 - Making the hazardous waste determination at an on-site interim status or permitted treatment...

Code of Federal Regulations, 2014 CFR

2014-07-01

... permitted treatment, storage or disposal facility. (e) If the unwanted material is a hazardous waste, the... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Making the hazardous waste... 262.212 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...

40 CFR 262.212 - Making the hazardous waste determination at an on-site interim status or permitted treatment...

Code of Federal Regulations, 2010 CFR

2010-07-01

... permitted treatment, storage or disposal facility. (e) If the unwanted material is a hazardous waste, the... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Making the hazardous waste... 262.212 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...

40 CFR 262.212 - Making the hazardous waste determination at an on-site interim status or permitted treatment...

Code of Federal Regulations, 2013 CFR

2013-07-01

... permitted treatment, storage or disposal facility. (e) If the unwanted material is a hazardous waste, the... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Making the hazardous waste... 262.212 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vienna, John D.; Todd, Terry A.; Gray, Kimberly D.

The U.S. Department of Energy, Office of Nuclear Energy has chartered an effort to develop technologies to enable safe and cost effective recycle of commercial used nuclear fuel (UNF) in the U.S. Part of this effort includes the evaluation of exiting waste management technologies for effective treatment of wastes in the context of current U.S. regulations and development of waste forms and processes with significant cost and/or performance benefits over those existing. This study summarizes the results of these ongoing efforts with a focus on the highly radioactive primary waste streams. The primary streams considered and the recommended waste formsmore » include: •Tritium separated from either a low volume gas stream or a high volume water stream. The recommended waste form is low-water cement in high integrity containers. •Iodine-129 separated from off-gas streams in aqueous processing. There are a range of potentially suitable waste forms. As a reference case, a glass composite material (GCM) formed by the encapsulation of the silver Mordenite (AgZ) getter material in a low-temperature glass is assumed. A number of alternatives with distinct advantages are also considered including a fused silica waste form with encapsulated nano-sized AgI crystals. •Carbon-14 separated from LWR fuel treatment off-gases and immobilized as a CaCO3 in a cement waste form. •Krypton-85 separated from LWR and SFR fuel treatment off-gases and stored as a compressed gas. •An aqueous reprocessing high-level waste (HLW) raffinate waste which is immobilized by the vitrification process in one of three forms: a single phase borosilicate glass, a borosilicate based glass ceramic, or a multi-phased titanate ceramic [e.g., synthetic rock (Synroc)]. •An undissolved solids (UDS) fraction from aqueous reprocessing of LWR fuel that is either included in the borosilicate HLW glass or is immobilized in the form of a metal alloy in the case of glass ceramics or titanate ceramics. •Zirconium-based LWR fuel cladding hulls and stainless steel (SS) fuel assembly hardware that are washed and super-compacted for disposal or as an alternative Zr purification and reuse (or disposal as low-level waste, LLW) by reactive gas separations. •Electrochemical process salt HLW which is immobilized in a glass bonded Sodalite waste form known as the ceramic waste form (CWF). •Electrochemical process UDS and SS cladding hulls which are melted into an iron based alloy waste form. Mass and volume estimates for each of the recommended waste forms based on the source terms from a representative flowsheet are reported.« less

The enrichment of an alkaliphilic biofilm consortia capable of the anaerobic degradation of isosaccharinic acid from cellulosic materials incubated within an anthropogenic, hyperalkaline environment.

PubMed

Charles, C J; Rout, S P; Garratt, E J; Patel, K; Laws, A P; Humphreys, P N

2015-08-01

Anthropogenic hyperalkaline sites provide an environment that is analogous to proposed cementitious geological disposal facilities (GDF) for radioactive waste. Under anoxic, alkaline conditions cellulosic wastes will hydrolyze to a range of cellulose degradation products (CDP) dominated by isosaccharinic acids (ISA). In order to investigate the potential for microbial activity in a cementitious GDF, cellulose samples were incubated in the alkaline (∼pH 12), anaerobic zone of a lime kiln waste site. Following retrieval, these samples had undergone partial alkaline hydrolysis and were colonized by a Clostridia-dominated biofilm community, where hydrogenotrophic, alkaliphilic methanogens were also present. When these samples were used to establish an alkaline CDP fed microcosm, the community shifted away from Clostridia, methanogens became undetectable and a flocculate community dominated by Alishewanella sp. established. These flocs were composed of bacteria embedded in polysaccharides and proteins stabilized by extracellular DNA. This community was able to degrade all forms of ISA with >60% of the carbon flow being channelled into extracellular polymeric substance (EPS) production. This study demonstrated that alkaliphilic microbial communities can degrade the CDP associated with some radioactive waste disposal concepts at pH 11. These communities divert significant amounts of degradable carbon to EPS formation, suggesting that EPS has a central role in the protection of these communities from hyperalkaline conditions. © FEMS 2015.

Application of Molecular Techniques To Elucidate the Influence of Cellulosic Waste on the Bacterial Community Structure at a Simulated Low-Level-Radioactive-Waste Site▿ †

PubMed Central

Field, Erin K.; D'Imperio, Seth; Miller, Amber R.; VanEngelen, Michael R.; Gerlach, Robin; Lee, Brady D.; Apel, William A.; Peyton, Brent M.

2010-01-01

Low-level-radioactive-waste (low-level-waste) sites, including those at various U.S. Department of Energy sites, frequently contain cellulosic waste in the form of paper towels, cardboard boxes, or wood contaminated with heavy metals and radionuclides such as chromium and uranium. To understand how the soil microbial community is influenced by the presence of cellulosic waste products, multiple soil samples were obtained from a nonradioactive model low-level-waste test pit at the Idaho National Laboratory. Samples were analyzed using 16S rRNA gene clone libraries and 16S rRNA gene microarray (PhyloChip) analyses. Both methods revealed changes in the bacterial community structure with depth. In all samples, the PhyloChip detected significantly more operational taxonomic units, and therefore relative diversity, than the clone libraries. Diversity indices suggest that diversity is lowest in the fill and fill-waste interface (FW) layers and greater in the wood waste and waste-clay interface layers. Principal-coordinate analysis and lineage-specific analysis determined that the Bacteroidetes and Actinobacteria phyla account for most of the significant differences observed between the layers. The decreased diversity in the FW layer and increased members of families containing known cellulose-degrading microorganisms suggest that the FW layer is an enrichment environment for these organisms. These results suggest that the presence of the cellulosic material significantly influences the bacterial community structure in a stratified soil system. PMID:20305022

Controls on the Mobility of Antimony in Mine Waste from Three Deposit Types

NASA Astrophysics Data System (ADS)

Jamieson, H.; Radková, A. B.; Fawcett, S.

2017-12-01

Antimony can be considered both a critical metal and an environmental hazard, with a toxicity similar to arsenic. It is concentrated in stibnite deposits, but also present in polymetallic and precious metal ores, frequently accompanied by arsenic. We have studied the mineralogical controls on the mobility of antimony in three types of mine waste: stibnite tailings from an antimony mine, tetrahedrite-bearing waste rock from copper mining, and gold mine tailings and ore roaster waste. Our results demonstrate that the tendency of antimony to leach into the aqueous environment or remain sequestered in solid phases depends on the primary host minerals and conditions governing the precipitation of secondary antimony-hosting phases. In tailings at the Beaver Brook antimony mine in Newfoundland, Canada, stibnite oxidizes rapidly, and secondary minerals such as the relatively insoluble Sb-Fe tripuhyite-like phase and Sb-bearing goethite. However, under dry conditions, the most important secondary Sb host is the Mg-Sb hydroxide brandholzite, but this easily soluble mineral disappears when it rains. Antimony that was originally hosted in tetrahedrite, a complex multi-element sulfosalt, in the historic waste rock piles at Špania Dolina-Piesky, Slovakia, is not as mobile as Cu and As during weathering but reprecipiates to a mixture of tripuhyite and romeite. Finally, the original antimony-hosting minerals, both stibnite and sulphosalts, in the gold ore at Giant Mine, Yellowknife, Canada were completely destroyed during ore roasting. In tailings-contaminated sediments, antimony persists in roaster-generated iron oxide phases, except under reducing conditions where some of the antimony forms a Sb-S phase. The combined presence of antimony and arsenic in mine waste complicates risk assessment but in general, our findings suggest that antimony is less mobile than arsenic in the environment.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Not Available

This volume contains appendices for the following: Rocky Flats Plant and Idaho National Engineering Laboratory waste process information; TRUPACT-II content codes (TRUCON); TRUPACT-II chemical list; chemical compatibility analysis for Rocky Flats Plant waste forms; chemical compatibility analysis for waste forms across all sites; TRU mixed waste characterization database; hazardous constituents of Rocky Flats Transuranic waste; summary of waste components in TRU waste sampling program at INEL; TRU waste sampling program; and waste analysis data.

Physical space and its impact on waste management in the neonatal care setting

PubMed Central

Manzi, Sean

2014-01-01

This paper reports an investigation intended to obtain some understanding of how the working environment might influence the practice and knowledge of those involved in the management of healthcare waste. The National Health Service (NHS) has a continuing waste problem, and the way it manages waste harms the environment and consumes resources. It has been estimated that the carbon footprint of the NHS in England is approximately 20 million tons of CO2e. It has been suggested that better waste segregation could lead to more effective recycling, saving up to 42,000 tonnes of CO2. This qualitative study employed non-participant observation and semi-structured interviews. The interviews were carried out with the key informants within the participating neonatal intensive care unit. Findings from this study indicate that space and the physical arrangement of the environment are significant and influential factors in clinical practice. Where the clinical environment is not supportive, poor infection control and waste management practice is likely to occur. However, proximity of staff caused by a lack of physical space might facilitate situated learning and a collective development of knowledge in practice. The implementation of sustainable waste management practices would be more likely to succeed in an environment that facilitates correct waste segregation. PMID:28989373

Don't Waste Your Time Teaching in an On-Line Environment

ERIC Educational Resources Information Center

Potvin, Bernie L.

2012-01-01

In this paper I address one question asked by teachers who teach online--"How can I build community among my learners in my class?" This paper provides an answer; in fact, it provides ten possible answers, in the form of ten models for teachers to use to build community in on-line courses. Each model has been tried and tested over ten…

Land Management Panel: Army’s Net Zero Installation Initiative

DTIC Science & Technology

2012-05-24

same watershed so not to deplete the groundwater and surface water resources of that region in quantity or quality.  A Net Zero WASTE Installation...0.15 0.2 0.25 Assistant Secretary of the Army (Installations, Energy & Environment) Net Zero Waste A Net Zero WASTE Installation reduces, reuses...Net Zero Waste Strategy 17 Assistant Secretary of the Army (Installations, Energy & Environment) Waste Roadmaps Material flow analysis

Minimization and management of wastes from biomedical research.

PubMed Central

Rau, E H; Alaimo, R J; Ashbrook, P C; Austin, S M; Borenstein, N; Evans, M R; French, H M; Gilpin, R W; Hughes, J; Hummel, S J; Jacobsohn, A P; Lee, C Y; Merkle, S; Radzinski, T; Sloane, R; Wagner, K D; Weaner, L E

2000-01-01

Several committees were established by the National Association of Physicians for the Environment to investigate and report on various topics at the National Leadership Conference on Biomedical Research and the Environment held at the 1--2 November 1999 at the National Institutes of Health in Bethesda, Maryland. This is the report of the Committee on Minimization and Management of Wastes from Biomedical Research. Biomedical research facilities contribute a small fraction of the total amount of wastes generated in the United States, and the rate of generation appears to be decreasing. Significant reductions in generation of hazardous, radioactive, and mixed wastes have recently been reported, even at facilities with rapidly expanding research programs. Changes in the focus of research, improvements in laboratory techniques, and greater emphasis on waste minimization (volume and toxicity reduction) explain the declining trend in generation. The potential for uncontrolled releases of wastes from biomedical research facilities and adverse impacts on the general environment from these wastes appears to be low. Wastes are subject to numerous regulatory requirements and are contained and managed in a manner protective of the environment. Most biohazardous agents, chemicals, and radionuclides that find significant use in research are not likely to be persistent, bioaccumulative, or toxic if they are released. Today, the primary motivations for the ongoing efforts by facilities to improve minimization and management of wastes are regulatory compliance and avoidance of the high disposal costs and liabilities associated with generation of regulated wastes. The committee concluded that there was no evidence suggesting that the anticipated increases in biomedical research will significantly increase generation of hazardous wastes or have adverse impacts on the general environment. This conclusion assumes the positive, countervailing trends of enhanced pollution prevention efforts by facilities and reductions in waste generation resulting from improvements in research methods will continue. PMID:11121362

Transformation of heavy metal fractionation under changing environments: a case study of a drainage system in an e-waste dismantling community.

PubMed

Damrongsiri, Seelawut

2018-04-01

The change in environmental conditions during the transportation of contaminated soil and sediment was expected to affect the transformation of heavy metal fractionation. This study disclosed the serious contamination of copper (Cu), lead (Pb), and zinc (Zn) in the sewer sediment of an e-waste dismantling community in Thailand which may be caused by flushed contaminated soil and e-waste fragments. Two environmental conditions were simulated to observe the transformation of heavy metal fractionation. The anoxic sewer condition was induced using high substrate and sulfate in a closed container. The aeration of anoxic contaminated sediment was applied to simulate the transformation to an oxidative environment. The BCR sequential extraction was applied for heavy metal fractionation in this study. The study results exhibited that when heavy metal contaminated soil was transferred into this induced anoxic condition, fractionation was redistributed based on the chemical change of system that tends to be associated into F3 (oxidizable fraction) > F2 (reducible fraction) > F1 (acid soluble/exchangeable fraction). Cu exhibited the outstanding capability association to F3. The iron sulfide was not observed as usual due to its lower capability than Cu, Pb, and Zn. When contaminated sediment was transported to a more oxidative environment, the heavy metals fractionation would be redistributed again among those new environment media. It is noteworthy that F3 of Cu was stable even in oxic conditions. F2 of Fe was not developed by this oxic condition, possibly because its dehydration process was limited. The redistribution under an oxic environment became F1 > F2 > F3 indicating their more available form. This transformation was imperative and should be taken into account in heavy metal contaminated site management and control.

The inhabited environment, infrastructure development and advanced urbanization in China’s Yangtze River Delta Region

NASA Astrophysics Data System (ADS)

Zhu, Xiaoqing; Gao, Weijun; Zhou, Nan; Kammen, Daniel M.; Wu, Yiqun; Zhang, Yao; Chen, Wei

2016-12-01

This paper analyzes the relationship among the inhabited environment, infrastructure development and environmental impacts in China’s heavily urbanized Yangtze River Delta region. Using primary human environment data for the period 2006-2014, we examine factors affecting the inhabited environment and infrastructure development: urban population, GDP, built-up area, energy consumption, waste emission, transportation, real estate and urban greenery. Then we empirically investigate the impact of advanced urbanization with consideration of cities’ differences. Results from this study show that the growth rate of the inhabited environment and infrastructure development is strongly influenced by regional development structure, functional orientations, traffic network and urban size and form. The effect of advanced urbanization is more significant in large and mid-size cities than huge and mega cities. Energy consumption, waste emission and real estate in large and mid-size cities developed at an unprecedented rate with the rapid increase of economy. However, urban development of huge and mega cities gradually tended to be saturated. The transition development in these cities improved the inhabited environment and ecological protection instead of the urban construction simply. To maintain a sustainable advanced urbanization process, policy implications included urban sprawl control polices, ecological development mechanisms and reforming the economic structure for huge and mega cities, and construct major cross-regional infrastructure, enhance the carrying capacity and improvement of energy efficiency and structure for large and mid-size cities.

Mineral assemblage transformation of a metakaolin-based waste form after geopolymer encapsulation

NASA Astrophysics Data System (ADS)

Williams, Benjamin D.; Neeway, James J.; Snyder, Michelle M. V.; Bowden, Mark E.; Amonette, James E.; Arey, Bruce W.; Pierce, Eric M.; Brown, Christopher F.; Qafoku, Nikolla P.

2016-05-01

Mitigation of hazardous and radioactive waste can be improved through conversion of existing waste to a more chemically stable and physically robust waste form. One option for waste conversion is the fluidized bed steam reforming (FBSR) process. The resulting FBSR granular material was encapsulated in a geopolymer matrix referred to here as Geo-7. This provides mechanical strength for ease in transport and disposal. However, it is necessary to understand the phase assemblage evolution as a result of geopolymer encapsulation. In this study, we examine the mineral assemblages formed during the synthesis of the multiphase ceramic waste form. The FBSR granular samples were created from waste simulant that was chemically adjusted to resemble Hanford tank waste. Another set of samples was created using Savannah River Site Tank 50 waste simulant in order to mimic a blend of waste collected from 68 Hanford tank. Waste form performance tests were conducted using the product consistency test (PCT), the Toxicity Characteristic Leaching Procedure (TCLP), and the single-pass flow-through (SPFT) test. X-ray diffraction analyses revealed the structure of a previously unreported NAS phase and indicate that monolith creation may lead to a reduction in crystallinity as compared to the primary FBSR granular product.

Aluminum phosphate ceramics for waste storage

DOEpatents

Wagh, Arun; Maloney, Martin D

2014-06-03

The present disclosure describes solid waste forms and methods of processing waste. In one particular implementation, the invention provides a method of processing waste that may be particularly suitable for processing hazardous waste. In this method, a waste component is combined with an aluminum oxide and an acidic phosphate component in a slurry. A molar ratio of aluminum to phosphorus in the slurry is greater than one. Water in the slurry may be evaporated while mixing the slurry at a temperature of about 140-200.degree. C. The mixed slurry may be allowed to cure into a solid waste form. This solid waste form includes an anhydrous aluminum phosphate with at least a residual portion of the waste component bound therein.

40 CFR 60.2060 - When must I submit my waste management plan?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 6 2010-07-01 2010-07-01 false When must I submit my waste management plan? 60.2060 Section 60.2060 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Management Plan § 60.2060 When must I submit my waste management plan? You must submit a waste management...

40 CFR 60.2060 - When must I submit my waste management plan?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 7 2012-07-01 2012-07-01 false When must I submit my waste management plan? 60.2060 Section 60.2060 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Management Plan § 60.2060 When must I submit my waste management plan? You must submit a waste management...

40 CFR 60.2060 - When must I submit my waste management plan?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 6 2011-07-01 2011-07-01 false When must I submit my waste management plan? 60.2060 Section 60.2060 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Management Plan § 60.2060 When must I submit my waste management plan? You must submit a waste management...

Review of Potential Candidate Stabilization Technologies for Liquid and Solid Secondary Waste Streams

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pierce, Eric M.; Mattigod, Shas V.; Westsik, Joseph H.

2010-01-30

Pacific Northwest National Laboratory has initiated a waste form testing program to support the long-term durability evaluation of a waste form for secondary wastes generated from the treatment and immobilization of Hanford radioactive tank wastes. The purpose of the work discussed in this report is to identify candidate stabilization technologies and getters that have the potential to successfully treat the secondary waste stream liquid effluent, mainly from off-gas scrubbers and spent solids, produced by the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Down-selection to the most promising stabilization processes/waste forms is needed to support the design of a solidificationmore » treatment unit (STU) to be added to the Effluent Treatment Facility (ETF). To support key decision processes, an initial screening of the secondary liquid waste forms must be completed by February 2010.« less

40 CFR 264.340 - Applicability.

Code of Federal Regulations, 2014 CFR

2014-07-01

... finds that the waste will pose a threat to human health and the environment when burned in an... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Incinerators § 264...

40 CFR 264.340 - Applicability.

Code of Federal Regulations, 2013 CFR

2013-07-01

... finds that the waste will pose a threat to human health and the environment when burned in an... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Incinerators § 264...

40 CFR 264.340 - Applicability.

Code of Federal Regulations, 2011 CFR

2011-07-01

... finds that the waste will pose a threat to human health and the environment when burned in an... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Incinerators § 264...

40 CFR 266.201 - Definitions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Definitions. 266.201 Section 266.201 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR THE MANAGEMENT OF SPECIFIC HAZARDOUS WASTES AND SPECIFIC TYPES OF HAZARDOUS WASTE MANAGEMENT...

Treatment of mercury containing waste

DOEpatents

Kalb, Paul D.; Melamed, Dan; Patel, Bhavesh R; Fuhrmann, Mark

2002-01-01

A process is provided for the treatment of mercury containing waste in a single reaction vessel which includes a) stabilizing the waste with sulfur polymer cement under an inert atmosphere to form a resulting mixture and b) encapsulating the resulting mixture by heating the mixture to form a molten product and casting the molten product as a monolithic final waste form. Additional sulfur polymer cement can be added in the encapsulation step if needed, and a stabilizing additive can be added in the process to improve the leaching properties of the waste form.

Secondary Waste Cementitious Waste Form Data Package for the Integrated Disposal Facility Performance Assessment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cantrell, Kirk J.; Westsik, Joseph H.; Serne, R Jeffrey

A review of the most up-to-date and relevant data currently available was conducted to develop a set of recommended values for use in the Integrated Disposal Facility (IDF) performance assessment (PA) to model contaminant release from a cementitious waste form for aqueous wastes treated at the Hanford Effluent Treatment Facility (ETF). This data package relies primarily upon recent data collected on Cast Stone formulations fabricated with simulants of low-activity waste (LAW) and liquid secondary wastes expected to be produced at Hanford. These data were supplemented, when necessary, with data developed for saltstone (a similar grout waste form used at themore » Savannah River Site). Work is currently underway to collect data on cementitious waste forms that are similar to Cast Stone and saltstone but are tailored to the characteristics of ETF-treated liquid secondary wastes. Recommended values for key parameters to conduct PA modeling of contaminant release from ETF-treated liquid waste are provided.« less

Research on Recycling and Utilization of Solid Waste in Civil Airport

NASA Astrophysics Data System (ADS)

Li, Bo; Zhang, Wen; Wang, Jianping; Yi, Wei

2018-05-01

The aviation industry is embracing unprecedented prosperity together with the economic development. Building green airports resource-saving, environment-friendly and sustainable has become the inevitability of the times. The operation of airport will generate the large amount of waste every day, which certainly exposes airports and surrounding regions to waste disposal and ecological environment pressure. Waste disposal directly affects the surrounding environment of airports, which can be effectively mitigated by disposing waste into resources, i.e., sorting and recycling them into renewable materials. The development of green airport can also be promoted in this process. The article elaborates on the current methods of waste disposal adopted by airports. According to the principle of waste reduction, harmlessness, and resource recycling, a set of solid waste recycling and utilization methods suitable for airports are proposed, which can reduce the costs of waste transported to other places and landfilled. Various environmental pollution caused by landfill and other disposal methods can also be contained effectively. At the same time, resources can be fully recycled, converting waste into useful resources in an efficient and environmental-friendly way.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lukens, Wayne W.; Saslow, Sarah A.

Technetium-99 (Tc) is a problematic fission product that complicates the long-term disposal of nuclear waste due to its long half-life, high fission yield, and the environmental mobility of pertechnetate, its stable form in aerobic environments. One approach to preventing Tc contamination is through incorporation into durable waste forms based on weathering-resistant minerals such as rutile (titanium dioxide). Here, the incorporation of technetium into titanium dioxide by means of simple, aqueous chemistry is presented. X-ray absorption fine structure spectroscopy and diffuse reflectance spectroscopy indicate that Tc(IV) replaces Ti(IV) within the structure. Rather than being incorporated as isolated Tc(IV) ions, Tc ismore » present as pairs of edge-sharing Tc(IV) octahedra similar to molecular Tc(IV) complexes such as [(H2EDTA)TcIV](u-O)2. Technetium-doped TiO2 was suspended in deionized water under aerobic conditions, and the Tc leached under these conditions was followed for 8 months. The normalized release rate of Tc (LRTc) from the TiO2 particles is low (3×10-6 g m-2 d-1), which illustrates the potential utility of TiO2 as waste form. However, the small size of the as-prepared TiO2 nanoparticles results in estimated retention of Tc for 104 years, which is only a fraction of the half-life of Tc (2×10-5 years).« less

Isolation of clinically relevant fungal species from solid waste and environment of dental health services.

PubMed

Vieira, C D; de Carvalho, M A R; de Resende, M A; de Menezes Cussiol, N A; Alvarez-Leite, M E; dos Santos, S G; de Oliveira, M B; de Magalhães, T F F; Silva, M X; Nicoli, J R; de Macêdo Farias, L

2010-10-01

This study was undertaken to detect, identify and determine antifungal susceptibility of yeast strains isolated from dental solid waste and to evaluate airborne fungi in the Brazilian dental health care environment and in the waste storage room. A group of 17 yeast strains were identified by macroscopic and microscopic characteristics, API 20C Aux system and Multiplex PCR. All 104 airborne fungal colonies were identified by macroscopic and microscopic morphology. The CLSI broth microdilution method was utilized as the susceptibility test. Candida parapsilosis was the prevailing yeast species recovered from waste, followed by Rhodotorula glutinis. Three strains of Candida guilliermondii presented minimal inhibitory concentration values considered to be susceptible dose dependent (2 μg ml(-1)) to voriconazole. Of all airborne fungal species, 69% were recovered from the waste storage room and 31% were recovered from the clinical/surgical environment. Most of them were identified as Cladosporium spp. These findings reinforce the potential risk of waste handling and point out the need for safe management to minimize the spread of these agents to the environment. Filamentous fungi isolation in almost all sampled environments indicates that a periodic monitoring of airborne microbiota in the dental health care service environment is required. The survival of yeast strains for 48 h suggests that dental waste should be carefully controlled and monitored. © 2010 The Authors. Journal compilation © 2010 The Society for Applied Microbiology.

40 CFR Appendix Xi to Part 268 - Metal Bearing Wastes Prohibited From Dilution in a Combustion Unit According to 40 CFR 268.3(c)

Code of Federal Regulations, 2013 CFR

2013-07-01

... Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. XI Appendix XI to Part 268—Metal Bearing Wastes Prohibited From Dilution in a Combustion... 40 Protection of Environment 28 2013-07-01 2013-07-01 false Metal Bearing Wastes Prohibited From...

40 CFR Appendix IV to Part 268 - Wastes Excluded From Lab Packs Under the Alternative Treatment Standards of § 268.42(c)

Code of Federal Regulations, 2013 CFR

2013-07-01

... Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. IV Appendix IV to Part 268—Wastes Excluded From Lab Packs Under the Alternative Treatment... 40 Protection of Environment 28 2013-07-01 2013-07-01 false Wastes Excluded From Lab Packs Under...

40 CFR Appendix IV to Part 268 - Wastes Excluded From Lab Packs Under the Alternative Treatment Standards of § 268.42(c)

Code of Federal Regulations, 2012 CFR

2012-07-01

... Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. IV Appendix IV to Part 268—Wastes Excluded From Lab Packs Under the Alternative Treatment... 40 Protection of Environment 28 2012-07-01 2012-07-01 false Wastes Excluded From Lab Packs Under...

40 CFR Appendix IV to Part 268 - Wastes Excluded From Lab Packs Under the Alternative Treatment Standards of § 268.42(c)

Code of Federal Regulations, 2011 CFR

2011-07-01

... Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. IV Appendix IV to Part 268—Wastes Excluded From Lab Packs Under the Alternative Treatment... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Wastes Excluded From Lab Packs Under...

40 CFR Appendix IV to Part 268 - Wastes Excluded From Lab Packs Under the Alternative Treatment Standards of § 268.42(c)

Code of Federal Regulations, 2010 CFR

2010-07-01

... Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. IV Appendix IV to Part 268—Wastes Excluded From Lab Packs Under the Alternative Treatment... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Wastes Excluded From Lab Packs Under...

40 CFR Appendix IV to Part 268 - Wastes Excluded From Lab Packs Under the Alternative Treatment Standards of § 268.42(c)

Code of Federal Regulations, 2014 CFR

2014-07-01

... Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. IV Appendix IV to Part 268—Wastes Excluded From Lab Packs Under the Alternative Treatment... 40 Protection of Environment 27 2014-07-01 2014-07-01 false Wastes Excluded From Lab Packs Under...

40 CFR Appendix Xi to Part 268 - Metal Bearing Wastes Prohibited From Dilution in a Combustion Unit According to 40 CFR 268.3(c)

Code of Federal Regulations, 2014 CFR

2014-07-01

... Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) LAND DISPOSAL RESTRICTIONS Pt. 268, App. XI Appendix XI to Part 268—Metal Bearing Wastes Prohibited From Dilution in a Combustion... 40 Protection of Environment 27 2014-07-01 2014-07-01 false Metal Bearing Wastes Prohibited From...

Waste forms, packages, and seals working group summary

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sridhar, N.

1995-09-01

This article is a summary of the proceedings of a group discussion which took place at the Workshop on the Role of Natural Analogs in Geologic Disposal of High-Level Nuclear Waste in San Antonio, Texas on July 22-25, 1991. The working group concentrated on the subject of radioactive waste forms and packaging. Also included is a description of the use of natural analogs in waste packaging, container materials and waste forms.

40 CFR 264.255 - [Reserved

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false [Reserved] 264.255 Section 264.255 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Waste Piles § 264.255...

40 CFR 265.1 - Purpose, scope, and applicability.

Code of Federal Regulations, 2013 CFR

2013-07-01

... waste is necessary to protect human health or the environment, that official or specialist may authorize....1 Section 265.1 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND...

40 CFR 265.1 - Purpose, scope, and applicability.

Code of Federal Regulations, 2012 CFR

2012-07-01

... waste is necessary to protect human health or the environment, that official or specialist may authorize....1 Section 265.1 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND...

40 CFR 265.1 - Purpose, scope, and applicability.

Code of Federal Regulations, 2014 CFR

2014-07-01

... waste is necessary to protect human health or the environment, that official or specialist may authorize....1 Section 265.1 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) INTERIM STATUS STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND...

40 CFR 257.4 - Effective date.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Effective date. 257.4 Section 257.4 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR CLASSIFICATION OF SOLID WASTE DISPOSAL FACILITIES AND PRACTICES Classification of Solid Waste Disposal Facilities...

40 CFR 256.25 - Recommendation for inactive facilities.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Recommendation for inactive facilities. 256.25 Section 256.25 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste...

40 CFR 257.4 - Effective date.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Effective date. 257.4 Section 257.4 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR CLASSIFICATION OF SOLID WASTE DISPOSAL FACILITIES AND PRACTICES Classification of Solid Waste Disposal Facilities...

40 CFR 256.25 - Recommendation for inactive facilities.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Recommendation for inactive facilities. 256.25 Section 256.25 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste...

40 CFR 262.70 - Farmers.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Farmers. 262.70 Section 262.70 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Farmers § 262.70 Farmers. A farmer disposing of waste pesticides...

Electronic waste - an emerging threat to the environment of urban India.

PubMed

Needhidasan, Santhanam; Samuel, Melvin; Chidambaram, Ramalingam

2014-01-20

Electronic waste or e-waste is one of the emerging problems in developed and developing countries worldwide. It comprises of a multitude of components with valuable materials, some containing toxic substances, that can have an adverse impact on human health and the environment. Previous studies show that India has generated 0.4 million tons of e-waste in 2010 which may increase to 0.5 to 0.6 million tons by 2013-2014. Coupled with lack of appropriate infrastructural facilities and procedures for its disposal and recycling have posed significant importance for e-waste management in India. In general, e-waste is generated through recycling of e-waste and also from dumping of these wastes from other countries. More of these wastes are ending up in dumping yards and recycling centers, posing a new challenge to the environment and policy makers as well. In general electronic gadgets are meant to make our lives happier and simpler, but the toxicity it contains, their disposal and recycling becomes a health nightmare. Most of the users are unaware of the potential negative impact of rapidly increasing use of computers, monitors, and televisions. This review article provides a concise overview of India's current e-waste scenario, namely magnitude of the problem, environmental and health hazards, current disposal, recycling operations and mechanisms to improve the condition for better environment.

Electronic waste – an emerging threat to the environment of urban India

PubMed Central

2014-01-01

Electronic waste or e-waste is one of the emerging problems in developed and developing countries worldwide. It comprises of a multitude of components with valuable materials, some containing toxic substances, that can have an adverse impact on human health and the environment. Previous studies show that India has generated 0.4 million tons of e-waste in 2010 which may increase to 0.5 to 0.6 million tons by 2013–2014. Coupled with lack of appropriate infrastructural facilities and procedures for its disposal and recycling have posed significant importance for e-waste management in India. In general, e-waste is generated through recycling of e-waste and also from dumping of these wastes from other countries. More of these wastes are ending up in dumping yards and recycling centers, posing a new challenge to the environment and policy makers as well. In general electronic gadgets are meant to make our lives happier and simpler, but the toxicity it contains, their disposal and recycling becomes a health nightmare. Most of the users are unaware of the potential negative impact of rapidly increasing use of computers, monitors, and televisions. This review article provides a concise overview of India’s current e-waste scenario, namely magnitude of the problem, environmental and health hazards, current disposal, recycling operations and mechanisms to improve the condition for better environment. PMID:24444377

Effective pine bark composting with the Dome Aeration Technology

DOE Office of Scientific and Technical Information (OSTI.GOV)

Trois, Cristina; Polster, Andreas

2007-07-01

In South Africa garden refuse is primarily disposed of in domestic landfills. Due to the large quantities generated, any form of treatment would be beneficial for volume reduction, waste stabilization and resource recovery. Dome Aeration Technology (DAT) is an advanced process for aerobic biological degradation of garden refuse and general waste [Paar, S., Brummack, J., Gemende, B., 1999a. Advantages of dome aeration in mechanical-biological waste treatment. In: Proceedings of the 7th International Waste Management and Landfill Symposium, Cagliari, 4-8 October 1999; Paar, S., Brummack, J., Gemende, B., 1999b. Mechanical-biological waste stabilization by the dome aeration method. Environment Protection Engineering 25more » (3/99). Mollekopf, N., Brummack, J., Paar, S., Vorster, K., 2002. Use of the Dome Aeration Technology for biochemical stabilization of waste prior to landfilling. In: Proceedings of the Wastecon 2002, Waste Congress and Exhibition, Durban, South Africa.]. It is a non-reactor open windrow composting process, with the main advantage being that the input material needs no periodic turning. A rotting time of only 3-4 months indicates the high efficiency. Additionally, the low capital/operational costs, low energy inputs and limited plant requirements provide potential for use in aerobic refuse stabilization. The innovation in the DAT process is the passive aeration achieved by thermally driven advection through open windrows caused by temperature differences between the degrading material and the outside environment. This paper investigates the application of Dome Aeration Technology to pine bark composting as part of an integrated waste management strategy. A full-scale field experiment was performed at the Bisasar Road Landfill Site in Durban to assess the influence of climate, waste composition and operational conditions on the process. A test windrow was constructed and measurements of temperature and airflow through the material were taken. The process monitoring revealed that prevailing climatic conditions in a subtropical location do not affect the high efficiency of this technology. However, the composition of the input material can be detrimental for production of high quality compost because of a lack of nitrate.« less

Mineral assemblage transformation of a metakaolin-based waste form after geopolymer encapsulation

DOE PAGES

Williams, Benjamin D.; Neeway, James J.; Snyder, Michelle M. V.; ...

2015-12-23

We can improve mitigation of hazardous and radioactive waste through conversion of existing waste to a more chemically stable and physically robust waste form. One option for waste conversion is the fluidized bed steam reforming (FBSR) process. The resulting FBSR granular material was encapsulated in a geopolymer matrix referred to here as Geo-7. This provides mechanical strength for ease in transport and disposal. But, it is necessary to understand the phase assemblage evolution as a result of geopolymer encapsulation. In this study, we examine the mineral assemblages formed during the synthesis of the multiphase ceramic waste form. The FBSR granularmore » samples were created from waste simulant that was chemically adjusted to resemble Hanford tank waste. Another set of samples was created using Savannah River Site Tank 50 waste simulant in order to mimic a blend of waste collected from 68 Hanford tank. Waste form performance tests were conducted using the product consistency test (PCT), the Toxicity Characteristic Leaching Procedure (TCLP), and the single-pass flow-through (SPFT) test. Finally, X-ray diffraction analyses revealed the structure of a previously unreported NAS phase and indicate that monolith creation may lead to a reduction in crystallinity as compared to the primary FBSR granular product.« less

Pathways for Disposal of Commercially-Generated Tritiated Waste

DOE Office of Scientific and Technical Information (OSTI.GOV)

Halverson, Nancy V.

From a waste disposal standpoint, tritium is a major challenge. Because it behaves like hydrogen, tritium exchanges readily with hydrogen in the ground water and moves easily through the ground. Land disposal sites must control the tritium activity and mobility of incoming wastes to protect human health and the environment. Consequently, disposal of tritiated low-level wastes is highly regulated and disposal options are limited. The United States has had eight operating commercial facilities licensed for low-level radioactive waste disposal, only four of which are currently receiving waste. Each of these is licensed and regulated by its state. Only two ofmore » these sites accept waste from states outside of their specified regional compact. For waste streams that cannot be disposed directly at one of the four active commercial low-level waste disposal facilities, processing facilities offer various forms of tritiated low-level waste processing and treatment, and then transport and dispose of the residuals at a disposal facility. These processing facilities may remove and recycle tritium, reduce waste volume, solidify liquid waste, remove hazardous constituents, or perform a number of additional treatments. Waste brokers also offer many low-level and mixed waste management and transportation services. These services can be especially helpful for small-quantity tritiated-waste generators, such as universities, research institutions, medical facilities, and some industries. The information contained in this report covers general capabilities and requirements for the various disposal/processing facilities and brokerage companies, but is not considered exhaustive. Typically, each facility has extensive waste acceptance criteria and will require a generator to thoroughly characterize their wastes. Then a contractual agreement between the waste generator and the disposal/processing/broker entity must be in place before waste is accepted. Costs for tritiated waste transportation, processing and disposal vary based a number of factors. In many cases, wastes with very low radioactivity are priced primarily based on weight or volume. For higher activities, costs are based on both volume and activity, with the activity-based charges usually being much larger than volume-based charges. Other factors affecting cost include location, waste classification and form, other hazards in the waste, etc. Costs may be based on general guidelines used by an individual disposal or processing site, but final costs are established by specific contract with each generator. For this report, seven hypothetical waste streams intended to represent commercially-generated tritiated waste were defined in order to calculate comparative costs. Ballpark costs for disposition of these hypothetical waste streams were calculated. These costs ranged from thousands to millions of dollars. Due to the complexity of the cost-determining factors mentioned above, the costs calculated in this report should be understood to represent very rough cost estimates for the various hypothetical wastes. Actual costs could be higher or could be lower due to quantity discounts or other factors.« less

40 CFR 261.30 - General.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) Corrosive Waste (C) Reactive Waste (R) Toxicity Characteristic Waste (E) Acute Hazardous Waste (H) Toxic... Toxicity Characteristic Waste (E) or Toxic Waste (T) in §§ 261.31 and 261.32. (c) Each hazardous waste... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION...

40 CFR 261.30 - General.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) Corrosive Waste (C) Reactive Waste (R) Toxicity Characteristic Waste (E) Acute Hazardous Waste (H) Toxic... Toxicity Characteristic Waste (E) or Toxic Waste (T) in §§ 261.31 and 261.32. (c) Each hazardous waste... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION...

40 CFR 261.30 - General.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) Corrosive Waste (C) Reactive Waste (R) Toxicity Characteristic Waste (E) Acute Hazardous Waste (H) Toxic... Toxicity Characteristic Waste (E) or Toxic Waste (T) in §§ 261.31 and 261.32. (c) Each hazardous waste... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION...

40 CFR 261.30 - General.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) Corrosive Waste (C) Reactive Waste (R) Toxicity Characteristic Waste (E) Acute Hazardous Waste (H) Toxic... Toxicity Characteristic Waste (E) or Toxic Waste (T) in §§ 261.31 and 261.32. (c) Each hazardous waste... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION...

40 CFR 261.30 - General.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) Corrosive Waste (C) Reactive Waste (R) Toxicity Characteristic Waste (E) Acute Hazardous Waste (H) Toxic... Toxicity Characteristic Waste (E) or Toxic Waste (T) in §§ 261.31 and 261.32. (c) Each hazardous waste... Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION...

40 CFR 256.22 - Recommendations for State regulatory powers.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 25 2014-07-01 2014-07-01 false Recommendations for State regulatory powers. 256.22 Section 256.22 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste...

40 CFR 256.22 - Recommendations for State regulatory powers.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 26 2013-07-01 2013-07-01 false Recommendations for State regulatory powers. 256.22 Section 256.22 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste...

40 CFR 256.21 - Requirements for State regulatory powers.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 26 2013-07-01 2013-07-01 false Requirements for State regulatory powers. 256.21 Section 256.21 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste...

40 CFR 256.21 - Requirements for State regulatory powers.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 26 2012-07-01 2011-07-01 true Requirements for State regulatory powers. 256.21 Section 256.21 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste...

40 CFR 256.20 - Requirements for State legal authority.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 26 2013-07-01 2013-07-01 false Requirements for State legal authority. 256.20 Section 256.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste...

40 CFR 256.20 - Requirements for State legal authority.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 26 2012-07-01 2011-07-01 true Requirements for State legal authority. 256.20 Section 256.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste...

40 CFR 256.21 - Requirements for State regulatory powers.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 25 2014-07-01 2014-07-01 false Requirements for State regulatory powers. 256.21 Section 256.21 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste...

40 CFR 256.20 - Requirements for State legal authority.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 25 2014-07-01 2014-07-01 false Requirements for State legal authority. 256.20 Section 256.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste...

40 CFR 256.22 - Recommendations for State regulatory powers.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 26 2012-07-01 2011-07-01 true Recommendations for State regulatory powers. 256.22 Section 256.22 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste...

40 CFR 761.269 - Sampling liquid PCB remediation waste.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Sampling liquid PCB remediation waste. 761.269 Section 761.269 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC..., AND USE PROHIBITIONS Cleanup Site Characterization Sampling for PCB Remediation Waste in Accordance...

40 CFR 761.269 - Sampling liquid PCB remediation waste.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Sampling liquid PCB remediation waste. 761.269 Section 761.269 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC..., AND USE PROHIBITIONS Cleanup Site Characterization Sampling for PCB Remediation Waste in Accordance...

40 CFR 761.269 - Sampling liquid PCB remediation waste.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Sampling liquid PCB remediation waste. 761.269 Section 761.269 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC..., AND USE PROHIBITIONS Cleanup Site Characterization Sampling for PCB Remediation Waste in Accordance...

40 CFR 761.269 - Sampling liquid PCB remediation waste.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Sampling liquid PCB remediation waste. 761.269 Section 761.269 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) TOXIC..., AND USE PROHIBITIONS Cleanup Site Characterization Sampling for PCB Remediation Waste in Accordance...

40 CFR 256.20 - Requirements for State legal authority.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Requirements for State legal authority. 256.20 Section 256.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste...

40 CFR 256.20 - Requirements for State legal authority.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Requirements for State legal authority. 256.20 Section 256.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES GUIDELINES FOR DEVELOPMENT AND IMPLEMENTATION OF STATE SOLID WASTE MANAGEMENT PLANS Solid Waste...

40 CFR 273.53 - Storage time limits.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 28 2012-07-01 2012-07-01 false Storage time limits. 273.53 Section 273.53 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR UNIVERSAL WASTE MANAGEMENT Standards for Universal Waste Transporters § 273.53 Storage time...

40 CFR 273.53 - Storage time limits.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 28 2013-07-01 2013-07-01 false Storage time limits. 273.53 Section 273.53 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR UNIVERSAL WASTE MANAGEMENT Standards for Universal Waste Transporters § 273.53 Storage time...

40 CFR 273.53 - Storage time limits.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 27 2014-07-01 2014-07-01 false Storage time limits. 273.53 Section 273.53 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR UNIVERSAL WASTE MANAGEMENT Standards for Universal Waste Transporters § 273.53 Storage time...

Closed Fuel Cycle Waste Treatment Strategy

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vienna, J. D.; Collins, E. D.; Crum, J. V.

This study is aimed at evaluating the existing waste management approaches for nuclear fuel cycle facilities in comparison to the objectives of implementing an advanced fuel cycle in the U.S. under current legal, regulatory, and logistical constructs. The study begins with the Global Nuclear Energy Partnership (GNEP) Integrated Waste Management Strategy (IWMS) (Gombert et al. 2008) as a general strategy and associated Waste Treatment Baseline Study (WTBS) (Gombert et al. 2007). The tenets of the IWMS are equally valid to the current waste management study. However, the flowsheet details have changed significantly from those considered under GNEP. In addition, significantmore » additional waste management technology development has occurred since the GNEP waste management studies were performed. This study updates the information found in the WTBS, summarizes the results of more recent technology development efforts, and describes waste management approaches as they apply to a representative full recycle reprocessing flowsheet. Many of the waste management technologies discussed also apply to other potential flowsheets that involve reprocessing. These applications are occasionally discussed where the data are more readily available. The report summarizes the waste arising from aqueous reprocessing of a typical light-water reactor (LWR) fuel to separate actinides for use in fabricating metal sodium fast reactor (SFR) fuel and from electrochemical reprocessing of the metal SFR fuel to separate actinides for recycle back into the SFR in the form of metal fuel. The primary streams considered and the recommended waste forms include; Tritium in low-water cement in high integrity containers (HICs); Iodine-129: As a reference case, a glass composite material (GCM) formed by the encapsulation of the silver Mordenite (AgZ) getter material in a low-temperature glass is assumed. A number of alternatives with distinct advantages are also considered including a fused silica waste form with encapsulated nano-sized AgI crystals; Carbon-14 immobilized as a CaCO3 in a cement waste form; Krypton-85 stored as a compressed gas; An aqueous reprocessing high-level waste (HLW) raffinate waste immobilized by the vitrification process; An undissolved solids (UDS) fraction from aqueous reprocessing of LWR fuel either included in the borosilicate HLW glass or immobilized in the form of a metal alloy or titanate ceramics; Zirconium-based LWR fuel cladding hulls and stainless steel (SS) fuel assembly hardware super-compacted for disposal or purified for reuse (or disposal as low-level waste, LLW) of Zr by reactive gas separations; Electrochemical process salt HLW incorporated into a glass bonded Sodalite waste form; and Electrochemical process UDS and SS cladding hulls melted into an iron based alloy waste form. Mass and volume estimates for each of the recommended waste forms based on the source terms from a representative flowsheet are reported. In addition to the above listed primary waste streams, a range of secondary process wastes are generated by aqueous reprocessing of LWR fuel, metal SFR fuel fabrication, and electrochemical reprocessing of SFR fuel. These secondary wastes have been summarized and volumes estimated by type and classification. The important waste management data gaps and research needs have been summarized for each primary waste stream and selected waste process.« less

DOE Office of Scientific and Technical Information (OSTI.GOV)

Johnson, Bradley R.

The Hidden Cost of Nuclear Weapons The Cold War arms race drove an intense plutonium production program in the U.S. This campaign produced approximately 100 tons of plutonium over 40 years. The epicenter of plutonium production in the United States was the Hanford site, a 586 square mile reservation owned by the Department of Energy and located on the Colombia River in Southeastern Washington. Plutonium synthesis relied on nuclear reactors to convert uranium to plutonium within the reactor fuel rods. After a sufficient amount of conversion occurred, the rods were removed from the reactor and allowed to cool. They weremore » then dissolved in an acid bath and chemically processed to separate and purify plutonium from the rest of the constituents in the used reactor fuel. The acidic waste was then neutralized using sodium hydroxide and the resulting mixture of liquids and precipitates (small insoluble particles) was stored in huge underground waste tanks. The byproducts of the U.S. plutonium production campaign include over 53 million gallons of high-level radioactive waste stored in 177 large underground tanks at Hanford and another 34 million gallons stored at the Savannah River Site in South Carolina. This legacy nuclear waste represents one of the largest environmental clean-up challenges facing the world today. The nuclear waste in the Hanford tanks is a mixture of liquids and precipitates that have settled into sludge. Some of these tanks are now over 60 years old and a small number of them are leaking radioactive waste into the ground and contaminating the environment. The solution to this nuclear waste challenge is to convert the mixture of solids and liquids into a durable material that won't disperse into the environment and create hazards to the biosphere. What makes this difficult is the fact that the radioactive half-lives of some of the radionuclides in the waste are thousands to millions of years long. (The half-life of a radioactive substance is the amount of time it takes for one-half of the material to undergo radioactive decay.) In general, the ideal material would need to be durable for approximately 10 half-lives to allow the activity to decay to negligible levels. However, the potential health effects of each radionuclide vary depending on what type of radiation is emitted, the energy of that emission, and the susceptibility for the human body to accumulate and concentrate that particular element. Consequently, actual standards tend to be based on limiting the dose (energy deposited per unit mass) that is introduced into the environment. The Environmental Protection Agency (EPA) has the responsibility to establish standards for nuclear waste disposal to protect the health and safety of the public. For example, the Energy Policy Act of 1992 directed the EPA to establish radiation protection standards for the Yucca Mountain geologic repository for nuclear wastes. The standards for Yucca Mountain were promulgated in 2008, and limit the dose to 15 millirem per year for the first 10,000 years, and 100 milirem per year between 10,000 years and 1 million years (40 CFR Part 197; http://www.epa.gov/radiation/yucca/2008factsheet.html). So, the challenge is two-fold: (1) develop a material (a waste form) that is capable of immobilizing the waste over geologic time scales, and (2) develop a process to convert the radioactive sludge in the tanks into this durable waste form material. Glass: Hard, durable, inert, and with infinite chemical versatility Molten glass is a powerful solvent liquid, which can be designed to dissolve almost anything. When solidified, it can be one of the most chemically inert substances known to man. Nature's most famous analogue to glass is obsidian, a vitreous product of volcanic activity; formations over 17 million years old have been found. Archaeologists have found man-made glass specimens that are five thousand years old.« less

Diesel engine performance and emissions with fuels derived from waste tyres.

PubMed

Verma, Puneet; Zare, Ali; Jafari, Mohammad; Bodisco, Timothy A; Rainey, Thomas; Ristovski, Zoran D; Brown, Richard J

2018-02-06

The disposal of waste rubber and scrap tyres is a significant issue globally; disposal into stockpiles and landfill poses a serious threat to the environment, in addition to creating ecological problems. Fuel production from tyre waste could form part of the solution to this global issue. Therefore, this paper studies the potential of fuels derived from waste tyres as alternatives to diesel. Production methods and the influence of reactor operating parameters (such as reactor temperature and catalyst type) on oil yield are outlined. These have a major effect on the performance and emission characteristics of diesel engines when using tyre derived fuels. In general, tyre derived fuels increase the brake specific fuel consumption and decrease the brake thermal efficiency. The majority of studies indicate that NOx emissions increase with waste tyre derived fuels; however, a few studies have reported the opposite trend. A similar increasing trend has been observed for CO and CO 2 emissions. Although most studies reported an increase in HC emission owing to lower cetane number and higher density, some studies have reported reduced HC emissions. It has been found that the higher aromatic content in such fuels can lead to increased particulate matter emissions.

Corrosion assessment of refractory materials for high temperature waste vitrification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Marra, J.C.; Congdon, J.W.; Kielpinski, A.L.

1995-11-01

A variety of vitrification technologies are being evaluated to immobilize radioactive and hazardous wastes following years of nuclear materials production throughout the Department of Energy (DOE) complex. The compositions and physical forms of these wastes are diverse ranging from inorganic sludges to organic liquids to heterogeneous debris. Melt and off-gas products can be very corrosive at the high temperatures required to melt many of these waste streams. Ensuring material durability is required to develop viable treatment processes. Corrosion testing of materials in some of the anticipated severe environments is an important aspect of the materials identification and selection process. Corrosionmore » coupon tests on typical materials used in Joule heated melters were completed using glass compositions with high salt contents. The presence of chloride in the melts caused the most severe attack. In the metal alloys, oxidation was the predominant corrosion mechanism, while in the tested refractory material enhanced dissolution of the refractory into the glass was observed. Corrosion testing of numerous different refractory materials was performed in a plasma vitrification system using a surrogate heterogeneous debris waste. Extensive corrosion was observed in all tested materials.« less

Survey of degradation modes of candidate materials for high-level radioactive-waste disposal containers

DOE Office of Scientific and Technical Information (OSTI.GOV)

Farmer, J.C.; Van Konynenburg, R.A.; McCright, R.D.

1988-04-01

Three iron- to nickel-based austenitic alloys (Types 304L and 316L stainless steels and Alloy 825) are being considered as candidate materials for the fabrication of high-level radioactive-waste containers. Waste will include fuel assemblies from reactors as well as high-level waste in borosilicate glass forms, and will be sent to the prospective repository at Yucca Mountain, Nevada. The decay of radionuclides in the repository will result in the generation of substantial heat and in fluences of gamma radiation. Container materials may undergo any of several modes of degradation in this environment, including atmospheric oxidation; uniform aqueous phase corrosion; pitting; crevice corrosion;more » sensitization and intergranular stress corrosion cracking (IGSCC); and transgranular stress corrosion cracking (TGSCC). This report is an analysis of data relevant to the pitting, crevice corrosion, and stress corrosion cracking (SCC) of the three austenitic candidate alloys. The candidates are compared in terms of their susceptibilities to these forms of corrosion. Although all three candidates have demonstrated pitting and crevice corrosion in chloride-containing environments, Alloy 825 has the greatest resistance to these types of localized corrosion (LC); such resistance is important because pits can penetrate the metal and serve as crack initiation sites. Both Types 304L and 316L stainless steels are susceptible to SCC in acidic chloride media. In contrast, SCC has not been documented in Alloy 825 under comparable conditions. Gamma radiation has been found to enhance SCC in Types 304 and 304L stainless steels, but it has no detectable effect on the resistance of Alloy 825 to SCC. Furthermore, while the effects of microbiologically induced corrosion have been observed for 300-series stainless steels, nickel-based alloys such as Alloy 825 seem to be immune to such problems. 211 refs., 49 figs., 10 tabs.« less

Final report on cermet high-level waste forms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kobisk, E.H.; Quinby, T.C.; Aaron, W.S.

1981-08-01

Cermets are being developed as an alternate method for the fixation of defense and commercial high level radioactive waste in a terminal disposal form. Following initial feasibility assessments of this waste form, consisting of ceramic particles dispersed in an iron-nickel base alloy, significantly improved processing methods were developed. The characterization of cermets has continued through property determinations on samples prepared by various methods from a variety of simulated and actual high-level wastes. This report describes the status of development of the cermet waste form as it has evolved since 1977. 6 tables, 18 figures.

Radionuclide and contaminant immobilization in the fluidized bed steam reforming waste products

DOE Office of Scientific and Technical Information (OSTI.GOV)

Neeway, James J.; Qafoku, Nikolla; Westsik, Joseph H.

2012-05-01

The goal of this chapter is to introduce the reader to the Fluidized Bed Steam Reforming (FBSR) process and resulting waste form. The first section of the chapter gives an overview of the potential need for FBSR processing in nuclear waste remediation followed by an overview of the engineering involved in the process itself. This is followed by a description of waste form production at a chemical level followed by a section describing different process streams that have undergone the FBSR process. The third section describes the resulting mineral product in terms of phases that are present and the abilitymore » of the waste form to encapsulate hazardous and radioactive wastes from several sources. Following this description is a presentation of the physical properties of the granular and monolith waste form product including and contaminant release mechanisms. The last section gives a brief summary of this chapter and includes a section on the strengths associated with this waste form and the needs for additional data and remaining questions yet to be answered. The reader is directed elsewhere for more information on other waste forms such as Cast Stone (Lockrem, 2005), Ceramicrete (Singh et al., 1997, Wagh et al., 1999) and geopolymers (Kyritsis et al., 2009; Russell et al., 2006).« less

How technology transfer issues are managed

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sink, C.H.; Easley, K.R.

1991-12-31

In 1989, Secretary of Energy James Watkins made a commitment to accelerate DOE compliance with all applicable laws and standards aimed at protecting human health and the environment. At a minimum, this pledge requires the remediation of the 1989 inventory of chemical, radioactive, and mixed wastes at DOE production sites by 2019. The 1989 Complex inventory consisted of more than 3,700 sites, encompassing more than 26,000 acres contaminated with radioactive, hazardous, and mixed wastes. In addition, over 500 surplus sites are awaiting decontamination and decommissioning (D and D), and approximately 5,000 peripheral properties have contaminated soils (e.g., uranium tailings). Moreover,more » these problems exist at both inactive sites, where the primary focus is on environmental restoration, and at active sites, where the major emphasis is on improved waste management techniques. Although some of DOE`s problems are considered unique due to radioactivity, most forms of contamination resident in the Complex are not; rather, contaminants such as waste chemicals (e.g., inorganics), organics (e.g., fuels and solvents), halogenated organics (e.g., PCBs) and heavy metals commonly result in conventional industrial processes. Although certain other forms of contamination are more unique to DOE operations (e.g., radioactive materials, explosives, and pyrophorics), they are not exclusive to DOE. As DOE develops innovative solutions to these and related waste problems, it is imperative that technology systems and lessons learned be transferred from DOE sites and its R and D laboratories to private industry to maximize the nation`s return on environmental management technology investments.« less

Management of soybean oil refinery wastes through recycling them for producing biosurfactant using Pseudomonas aeruginosa MR01.

PubMed

Partovi, Maryam; Lotfabad, Tayebe Bagheri; Roostaazad, Reza; Bahmaei, Manochehr; Tayyebi, Shokoufe

2013-06-01

Biosurfactant production through a fermentation process involving the biodegradation of soybean oil refining wastes was studied. Pseudomonas aeruginosa MR01 was able to produce extracellular biosurfactant when it was cultured in three soybean oil refinement wastes; acid oil, deodorizer distillate and soapstock, at different carbon to nitrogen ratios. Subsequent fermentation kinetics in the three types of waste culture were also investigated and compared with kinetic behavior in soybean oil medium. Biodegradation of wastes, biosurfactant production, biomass growth, nitrate consumption and the number of colony forming units were detected in four proposed media, at specified time intervals. Unexpectedly, wastes could stimulate the biodegradation activity of MR01 bacterial cells and thus biosurfactant synthesis beyond that of the refined soybean oil. This is evident from higher yields of biodegradation and production, as revealed in the waste cultures (Ydeg|(Soybean oil) = 53.9 % < Ydeg|(wastes) and YP/S|(wastes) > YP/S|(Soybean oil) = 0.31 g g(-1), respectively). Although production yields were approximately the same in the three waste cultures (YP/S|(wastes) =/~ 0.5 g g(-1)), microbial activity resulted in higher yields of biodegradation (96.5 ± 1.13 %), maximum specific growth rate (μ max = 0.26 ± 0.02 h(-1)), and biosurfactant purity (89.6 %) with a productivity of 14.55 ± 1.10 g l(-1), during the bioconversion of soapstock into biosurfactant. Consequently, applying soybean oil soapstock as a substrate for the production of biosurfactant with commercial value has the potential to provide a combination of economical production with environmental protection through the biosynthesis of an environmentally friendly (green) compound and reduction of waste load entering the environment. Moreover, this work inferred spectrophotometry as an easy method to detect rhamnolipids in the biosurfactant products.

Report on the remedial investigation of Bear Creek Valley at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. Volume 3: Appendix D -- Nature and extent of contamination report

DOE Office of Scientific and Technical Information (OSTI.GOV)

NONE

1996-09-01

This Remedial Investigation (RI) Report characterizes the nature and extent of contamination, evaluates the fate and transport of contaminants, and assesses risk to human health and the environment resulting from waste disposal and other US Department of Energy (DOE) operations in Bear Creek Valley (BCV). BCV, which is located within the DOE Oak Ridge Reservation (ORR) encompasses multiple waste units containing hazardous and radioactive wastes arising from operations at the adjacent Oak Ridge Y-12 Plant. The primary waste units discussed in this RI Report are the S-3 Site, Oil Landfarm (OLF), Boneyard/Burnyard (BYBY), Sanitary Landfill 1 (SL 1), and Bearmore » Creek Burial Grounds (BCBG). These waste units, plus the contaminated media resulting from environmental transport of the wastes from these units, are the subject of this RI. This BCV RI Report represents the first major step in the decision-making process for the BCV watershed. The RI results, in concert with the follow-on FS will form the basis for the Proposed Plan and Record of Decision for all BCV sites. This comprehensive decision document process will meet the objectives of the watershed approach for BCV. Appendix D describes the nature and extent of contamination in environmental media and wastes.« less

Tempe Waste Water Degradation Using TiO2-N/Bentonite alginate Granule Photocatalyst with Ultraviolet Light Irradiation

NASA Astrophysics Data System (ADS)

Khoirun Nisaa', Aldila; Wardhani, Sri; Purwonugroho, Danar; Darjito

2018-01-01

Tempe waste water stew has high ammonia concentration which causes odor due to polluting by anaerobic decay. Free ammonia in the waste has exceeded the limit, thus endangering the aquatic environment. This research aims to determine the activity of photocatalyst granule TiO2-N/bentonite-alginate as decomposers of compounds in the photodegradation process. Photodegradation is the decomposition process of compounds by semiconductors with light. Results expected includes the photocatalyst activity of TiO2-N/bentonite-alginate granule produced by ultraviolet rays is known based on the effect of dopant N concentration on the catalyst and the effect of photocatalytic ratio toward tempe waste water. Methods proposed in this research are activation of bentonite using H2SO4 0.8 M, TiO2-N synthesize by sonication method with urea as the source of N, then TiO2-N impregnation into bentonite. Photocatalyst in granule form synthesized with alginate was then dripped with syringe pump into 3% (w/v) CaCl2. The photocatalyst characterization will be performed using XRD. The optimum tempe waste water degradation at the concentration of TiO2-N 0.4 (g/g) bentonite is 53.66%. The ratio of photocatalyst and tempe waste water, optimum at 150 mg of photocatalyst with 25 mL of waste equal to 53.66%.

40 CFR 262.80 - Applicability.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Applicability. 262.80 Section 262.80 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Transfrontier Shipments of Hazardous Waste for Recovery within the OECD § 262.80 Applicability. (a)...

40 CFR 147.3005 - Radioactive waste injection wells.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 22 2010-07-01 2010-07-01 false Radioactive waste injection wells. 147.3005 Section 147.3005 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER... the Navajo, Ute Mountain Ute, and All Other New Mexico Tribes § 147.3005 Radioactive waste injection...

40 CFR 258.57 - Selection of remedy.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 258.57 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS Ground-Water Monitoring and Corrective Action § 258.57 Selection of remedy... environment; and (4) Comply with standards for management of wastes as specified in § 258.58(d). (c) In...

40 CFR 258.57 - Selection of remedy.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 258.57 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS Ground-Water Monitoring and Corrective Action § 258.57 Selection of remedy... environment; and (4) Comply with standards for management of wastes as specified in § 258.58(d). (c) In...

SOLIDIFICATION OF THE HANFORD LAW WASTE STREAM PRODUCED AS A RESULT OF NEAR-TANK CONTINUOUS SLUDGE LEACHING AND SODIUM HYDROXIDE RECOVERY

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reigel, M.; Johnson, F.; Crawford, C.

2011-09-20

The U.S. Department of Energy (DOE), Office of River Protection (ORP), is responsible for the remediation and stabilization of the Hanford Site tank farms, including 53 million gallons of highly radioactive mixed wasted waste contained in 177 underground tanks. The plan calls for all waste retrieved from the tanks to be transferred to the Waste Treatment Plant (WTP). The WTP will consist of three primary facilities including pretreatment facilities for Low Activity Waste (LAW) to remove aluminum, chromium and other solids and radioisotopes that are undesirable in the High Level Waste (HLW) stream. Removal of aluminum from HLW sludge canmore » be accomplished through continuous sludge leaching of the aluminum from the HLW sludge as sodium aluminate; however, this process will introduce a significant amount of sodium hydroxide into the waste stream and consequently will increase the volume of waste to be dispositioned. A sodium recovery process is needed to remove the sodium hydroxide and recycle it back to the aluminum dissolution process. The resulting LAW waste stream has a high concentration of aluminum and sodium and will require alternative immobilization methods. Five waste forms were evaluated for immobilization of LAW at Hanford after the sodium recovery process. The waste forms considered for these two waste streams include low temperature processes (Saltstone/Cast stone and geopolymers), intermediate temperature processes (steam reforming and phosphate glasses) and high temperature processes (vitrification). These immobilization methods and the waste forms produced were evaluated for (1) compliance with the Performance Assessment (PA) requirements for disposal at the IDF, (2) waste form volume (waste loading), and (3) compatibility with the tank farms and systems. The iron phosphate glasses tested using the product consistency test had normalized release rates lower than the waste form requirements although the CCC glasses had higher release rates than the quenched glasses. However, the waste form failed to meet the vapor hydration test criteria listed in the WTP contract. In addition, the waste loading in the phosphate glasses were not as high as other candidate waste forms. Vitrification of HLW waste as borosilicate glass is a proven process; however the HLW and LAW streams at Hanford can vary significantly from waste currently being immobilized. The ccc glasses show lower release rates for B and Na than the quenched glasses and all glasses meet the acceptance criterion of < 4 g/L. Glass samples spiked with Re{sub 2}O{sub 7} also passed the PCT test. However, further vapor hydration testing must be performed since all the samples cracked and the test could not be performed. The waste loading of the iron phosphate and borosilicate glasses are approximately 20 and 25% respectively. The steam reforming process produced the predicted waste form for both the high and low aluminate waste streams. The predicted waste loadings for the monolithic samples is approximately 39%, which is higher than the glass waste forms; however, at the time of this report, no monolithic samples were made and therefore compliance with the PA cannot be determined. The waste loading in the geopolymer is approximately 40% but can vary with the sodium hydroxide content in the waste stream. Initial geopolymer mixes revealed compressive strengths that are greater than 500 psi for the low aluminate mixes and less than 500 psi for the high aluminate mixes. Further work testing needs to be performed to formulate a geopolymer waste form made using a high aluminate salt solution. A cementitious waste form has the advantage that the process is performed at ambient conditions and is a proven process currently in use for LAW disposal. The Saltstone/Cast Stone formulated using low and high aluminate salt solutions retained at least 97% of the Re that was added to the mix as a dopant. While this data is promising, additional leaching testing must be performed to show compliance with the PA. Compressive strength tests must also be performed on the Cast Stone monoliths to verify PA compliance. Based on testing performed for this report, the borosilicate glass and Cast Stone are the recommended waste forms for further testing. Both are proven technologies for radioactive waste disposal and the initial testing using simulated Hanford LAW waste shows compliance with the PA. Both are resistant to leaching and have greater than 25% waste loading.« less

Cultivating Composting Culture Activities among Citizens and Its Beneficial to Prolong the Landfill Lifespan

NASA Astrophysics Data System (ADS)

Azura Zakarya, Irnis; Azri Jamial, Khairul; Mat Tanda, Norazlinda

2018-03-01

Currently, the Ministry of Housing and Local Government manage solid waste in Malaysia, with the participation of the private sector. Food waste represents almost 60% of the total municipal solid waste disposed in the landfill. Material valorisation of food waste usually conducted by biological processes such as composting. Compost, an organic amendment, is the final product of the composting process. These processes are efficient, low cost and environmentally friendly alternative for managing food waste and are used extensively worldwide. Therefore, organic solid waste management practices program for the communities in Perlis was conducted. The main objective of this program was to instilling environment awareness especially among Perlis citizens. This study was investigated the impact of food waste or kitchen waste composting to the citizens in Perlis State and the beneficial of compost fertilizer to our environment especially in plant growth. Composting method was taught to the food premises owner, individuals, teachers, and students and their responses to the composting practices were then summarized. In future, we can prolong our landfill lifespan by practicing organic waste composting and can preserving our environment.

EXAFS/XANES studies of plutonium-loaded sodalite/glass waste forms

NASA Astrophysics Data System (ADS)

Richmann, Michael K.; Reed, Donald T.; Kropf, A. Jeremy; Aase, Scott B.; Lewis, Michele A.

2001-09-01

A sodalite/glass ceramic waste form is being developed to immobilize highly radioactive nuclear wastes in chloride form, as part of an electrochemical cleanup process. Two types of simulated waste forms were studied: where the plutonium was alone in an LiCl/KCl matrix and where simulated fission-product elements were added representative of the electrometallurgical treatment process used to recover uranium from spent nuclear fuel also containing plutonium and a variety of fission products. Extended X-ray absorption fine structure spectroscopy (EXAFS) and X-ray absorption near-edge spectroscopy (XANES) studies were performed to determine the location, oxidation state, and particle size of the plutonium within these waste form samples. Plutonium was found to segregate as plutonium(IV) oxide with a crystallite size of at least 4.8 nm in the non-fission-element case and 1.3 nm with fission elements present. No plutonium was observed within the sodalite in the waste form made from the plutonium-loaded LiCl/KCl eutectic salt. Up to 35% of the plutonium in the waste form made from the plutonium-loaded simulated fission-product salt may be segregated with a heavy-element nearest neighbor other than plutonium or occluded internally within the sodalite lattice.

40 CFR 761.345 - Form of the waste to be sampled.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Characterization for PCB Disposal in Accordance With § 761.62, and Sampling PCB Remediation Waste Destined for Off... waste and PCB remediation waste destined for off-site disposal must be in the form of either flattened...

Tackling the climate targets set by the Paris Agreement (COP 21): Green leadership empowers public hospitals to overcome obstacles and challenges in a resource-constrained environment.

PubMed

Weimann, E; Patel, B

2016-12-21

The healthcare sector itself contributes to climate change, the creation of hazardous waste, use of toxic metals such as mercury, and water and air pollution. To mitigate the effect of healthcare provision on the deteriorating environment and avoid creating further challenges for already burdened health systems, Global Green Hospitals was formed as a global network. Groote Schuur Hospital (GSH), as the leading academic hospital in Africa, joined the network in 2014. Since then, several projects have been initiated to reduce the amount of general waste, energy consumption and food waste, and create an environmentally friendlier and more sustainable hospital in a resource-constrained public healthcare setting. We outline the various efforts made to reduce the carbon footprint of GSH and reduce waste and hazardous substances such as mercury and polystyrene, and elaborate how obstacles and resistance to change were overcome. The hospital was able to halve the amount of coal and water used, increase recycling by 50% over 6 months, replace polystyrene cups and packaging with Forest Stewardship Council recyclable paper-based products, reduce the effect of food wastage by making use of local farmers, and implement measures to reduce the amount of expired pharmaceutical drugs. To improve commitment from all involved roleplayers, political leadership, supportive government policies and financial funding is mandatory, or public hospitals will be unable to tackle the exponentially increasing costs related to climate change and its effects on healthcare.

National Low-Level Waste Management Program Radionuclide Report Series. Volume 10, Nickel-63

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carboneau, M.L.; Adams, J.P.

1995-02-01

This report outlines the basic radiological, chemical, and physical characteristics of nickel-63 ({sup 63}Ni) and examines how these characteristics affect the behavior of {sup 63}Ni in various environmental media, such as soils, groundwater, plants, animals, the atmosphere, and the human body. Discussions also include methods of {sup 63}Ni production, waste types, and waste forms that contain {sup 63}Ni. The primary source of {sup 63}Ni in the environment has been low-level radioactive waste material generated as a result of neutron activation of stable {sup 62}Ni that is present in the structural components of nuclear reactor vessels. {sup 63}Ni enters the environmentmore » from the dismantling activities associated with nuclear reactor decommissioning. However, small amounts of {sup 63}Ni have been detected in the environment following the testing of thermonuclear weapons in the South Pacific. Concentrations as high as 2.7 Bq{sup a} per gram of sample (or equivalently 0.0022 parts per billion) were observed on Bikini Atoll (May 1954). {sup 63}Ni was not created as a fission product species (e.g., from {sup 235}U or {sup 239}Pu fissions), but instead was produced as a result of neutron capture in {sup 63}Ni, a common nickel isotope present in the stainless steel components of nuclear weapons (e.g., stainless-304 contains {approximately}9% total Ni or {approximately}0.3% {sup 63}Ni).« less

40 CFR 60.2055 - What is a waste management plan?

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 6 2010-07-01 2010-07-01 false What is a waste management plan? 60.2055 Section 60.2055 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... Which Modification or Reconstruction Is Commenced on or After June 1, 2001 Waste Management Plan § 60...

40 CFR 262.41 - Biennial report.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Biennial report. 262.41 Section 262.41 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Recordkeeping and Reporting § 262.41 Biennial report. (a) A generator who ships any hazardous waste...

Antimicrobial-resistant bacterial populations and antimicrobial resistance genes obtained from environments impacted by livestock and municipal waste

USDA-ARS?s Scientific Manuscript database

This study compared the populations of antimicrobial-resistant bacteria and the repertoire of antimicrobial resistance genes in four environments: effluent of three municipal waste water treatment facilities, three cattle feedlot runoff catchment ponds, three swine waste lagoons, and two "low impact...

40 CFR 264.281 - Special requirements for ignitable or reactive waste.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Special requirements for ignitable or reactive waste. 264.281 Section 264.281 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... immediately incorporated into the soil so that: (1) The resulting waste, mixture, or dissolution of material...

40 CFR 264.31 - Design and operation of facility.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Design and operation of facility. 264.31 Section 264.31 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES...-sudden release of hazardous waste or hazardous waste constituents to air, soil, or surface water which...

40 CFR 761.265 - Sampling bulk PCB remediation waste and porous surfaces.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Sampling bulk PCB remediation waste and porous surfaces. 761.265 Section 761.265 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY..., DISTRIBUTION IN COMMERCE, AND USE PROHIBITIONS Cleanup Site Characterization Sampling for PCB Remediation Waste...

40 CFR 761.265 - Sampling bulk PCB remediation waste and porous surfaces.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Sampling bulk PCB remediation waste and porous surfaces. 761.265 Section 761.265 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY..., DISTRIBUTION IN COMMERCE, AND USE PROHIBITIONS Cleanup Site Characterization Sampling for PCB Remediation Waste...

40 CFR 761.265 - Sampling bulk PCB remediation waste and porous surfaces.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Sampling bulk PCB remediation waste and porous surfaces. 761.265 Section 761.265 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY..., DISTRIBUTION IN COMMERCE, AND USE PROHIBITIONS Cleanup Site Characterization Sampling for PCB Remediation Waste...

40 CFR 761.265 - Sampling bulk PCB remediation waste and porous surfaces.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Sampling bulk PCB remediation waste and porous surfaces. 761.265 Section 761.265 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY..., DISTRIBUTION IN COMMERCE, AND USE PROHIBITIONS Cleanup Site Characterization Sampling for PCB Remediation Waste...

40 CFR 264.97 - General ground-water monitoring requirements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false General ground-water monitoring requirements. 264.97 Section 264.97 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS FOR OWNERS AND OPERATORS OF HAZARDOUS WASTE TREATMENT, STORAGE, AND DISPOSAL FACILITIES Releases From Solid Waste...

Understanding and modeling the economics of ECM

NASA Astrophysics Data System (ADS)

Wells, Wayne E.; Edinbarough, Immanuel A.

2004-12-01

Traditional economic analysis methods for manufacturing decisions include only the clearly identified immediate cost and revenue streams. Environmental issues have generally been seen as costs, in the form of waste material losses, conformance tests and pre-discharge treatments. The components of the waste stream often purchased as raw materials, become liabilities at the "end of the pipe" and their intrinsic material value is seldom recognized. A new mathematical treatment of manufacturing economics is proposed in which the costs of separation are compared with the intrinsic value of the waste materials to show how their recovery can provide an economic advantage to the manufacturer. The model is based on a unique combination of thermodynamic analysis, economic modeling and linear optimization. This paper describes the proposed model, and examines case studies in which the changed decision rules have yielded significant savings while protecting the environment. The premise proposed is that by including the value of the waste materials in the profit objective of the firm and applying the appropriate technological solution, manufacturing processes can become closed systems in which losses approach zero and environmental problems are converted into economic savings.

40 CFR 264.555 - Disposal of CAMU-eligible wastes in permitted hazardous waste landfills.

Code of Federal Regulations, 2010 CFR

2010-07-01

... permitted hazardous waste landfills. 264.555 Section 264.555 Protection of Environment ENVIRONMENTAL...-eligible wastes in permitted hazardous waste landfills. (a) The Regional Administrator with regulatory... hazardous waste landfills not located at the site from which the waste originated, without the wastes...

Immobilization of organic radioactive and non-radioactive liquid waste in a composite matrix

DOE Office of Scientific and Technical Information (OSTI.GOV)

Galkin, Anatoliy; Gelis, Artem V.; Castiglioni, Andrew J.

A method for immobilizing liquid radioactive waste is provided, the method having the steps of mixing waste with polymer to form a non-liquid waste; contacting the non-liquid waste with a solidifying agent to create a mixture, heating the mixture to cause the polymer, waste, and filler to irreversibly bind in a solid phase, and compressing the solid phase into a monolith. The invention also provides a method for immobilizing liquid radioactive waste containing tritium, the method having the steps of mixing liquid waste with polymer to convert the liquid waste to a non-liquid waste, contacting the non-liquid waste with amore » solidifying agent to create a mixture, heating the mixture to form homogeneous, chemically stable solid phase, and compressing the chemically stable solid phase into a final waste form, wherein the polymer comprises approximately a 9:1 weight ratio mixture of styrene block co-polymers and cross linked co-polymers of acrylamides.« less

Secondary Waste Simulant Development for Cast Stone Formulation Testing

DOE Office of Scientific and Technical Information (OSTI.GOV)

Russell, Renee L.; Westsik, Joseph H.; Rinehart, Donald E.

Washington River Protection Solutions, LLC (WRPS) funded Pacific Northwest National Laboratory (PNNL) to conduct a waste form testing program to implement aspects of the Secondary Liquid Waste Treatment Cast Stone Technology Development Plan (Ashley 2012) and the Hanford Site Secondary Waste Roadmap (PNNL 2009) related to the development and qualification of Cast Stone as a potential waste form for the solidification of aqueous wastes from the Hanford Site after the aqueous wastes are treated at the Effluent Treatment Facility (ETF). The current baseline is that the resultant Cast Stone (or grout) solid waste forms would be disposed at the Integratedmore » Disposal Facility (IDF). Data and results of this testing program will be used in the upcoming performance assessment of the IDF and in the design and operation of a solidification treatment unit planned to be added to the ETF. The purpose of the work described in this report is to 1) develop simulants for the waste streams that are currently being fed and future WTP secondary waste streams also to be fed into the ETF and 2) prepare simulants to use for preparation of grout or Cast Stone solid waste forms for testing.« less

Liquid Secondary Waste Grout Formulation and Waste Form Qualification

DOE Office of Scientific and Technical Information (OSTI.GOV)

Um, Wooyong; Williams, B. D.; Snyder, Michelle M. V.

This report describes the results from liquid secondary waste (LSW) grout formulation and waste form qualification tests performed at Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions (WRPS) to evaluate new formulations for preparing a grout waste form with high-sulfate secondary waste simulants and the release of key constituents from these grout monoliths. Specific objectives of the LSW grout formulation and waste form qualification tests described in this report focused on five activities: 1.preparing new formulations for the LSW grout waste form with high-sulfate LSW simulants and solid characterization of the cured LSW grout waste form; 2.conducting themore » U.S. Environmental Protection Agency (EPA) Method 1313 leach test (EPA 2012) on the grout prepared with the new formulations, which solidify sulfate-rich Hanford Tank Waste Treatment and Immobilization Plant (WTP) off-gas condensate secondary waste simulant, using deionized water (DIW); 3.conducting the EPA Method 1315 leach tests (EPA 2013) on the grout monoliths made with the new dry blend formulations and three LSW simulants (242-A evaporator condensate, Environmental Restoration Disposal Facility (ERDF) leachate, and WTP off-gas condensate) using two leachants, DIW and simulated Hanford Integrated Disposal Facility (IDF) Site vadose zone pore water (VZPW); 4.estimating the 99Tc desorption K d (distribution coefficient) values for 99Tc transport in oxidizing conditions to support the IDF performance assessment (PA); 5.estimating the solubility of 99Tc(IV)-bearing solid phases for 99Tc transport in reducing conditions to support the IDF PA.« less

Method for calcining radioactive wastes

DOEpatents

Bjorklund, William J.; McElroy, Jack L.; Mendel, John E.

1979-01-01

This invention relates to a method for the preparation of radioactive wastes in a low leachability form by calcining the radioactive waste on a fluidized bed of glass frit, removing the calcined waste to melter to form a homogeneous melt of the glass and the calcined waste, and then solidifying the melt to encapsulate the radioactive calcine in a glass matrix.

40 CFR 273.33 - Waste management.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Waste management. 273.33 Section 273...) STANDARDS FOR UNIVERSAL WASTE MANAGEMENT Standards for Large Quantity Handlers of Universal Waste § 273.33 Waste management. (a) Universal waste batteries. A large quantity handler of universal waste must manage...

40 CFR 273.13 - Waste management.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Waste management. 273.13 Section 273...) STANDARDS FOR UNIVERSAL WASTE MANAGEMENT Standards for Small Quantity Handlers of Universal Waste § 273.13 Waste management. (a) Universal waste batteries. A small quantity handler of universal waste must manage...

40 CFR 273.19 - Tracking universal waste shipments.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Tracking universal waste shipments... WASTES (CONTINUED) STANDARDS FOR UNIVERSAL WASTE MANAGEMENT Standards for Small Quantity Handlers of Universal Waste § 273.19 Tracking universal waste shipments. A small quantity handler of universal waste is...

Glass binder development for a glass-bonded sodalite ceramic waste form

DOE Office of Scientific and Technical Information (OSTI.GOV)

Riley, Brian J.; Vienna, John D.; Frank, Steven M.

This paper discusses work to develop Na2O-B2O3-SiO2 glass binders for immobilizing LiCl-KCl eutectic salt waste in a glass-bonded sodalite waste form following electrochemical reprocessing of used metallic nuclear fuel. Here, five new glasses with high Na2O contents were designed to generate waste forms having higher sodalite contents and fewer stress fractures. The structural, mechanical, and thermal properties of the new glasses were measured using variety of analytical techniques. The glasses were then used to produce ceramic waste forms with surrogate salt waste. The materials made using the glasses developed during this study were formulated to generate more sodalite than materialsmore » made with previous baseline glasses used. The coefficients of thermal expansion for the glass phase in the glass-bonded sodalite waste forms made with the new binder glasses were closer to the sodalite phase in the critical temperature region near and below the glass transition temperature. These improvements should result in lower probability of cracking in the full-scale monolithic ceramic waste form, leading to better long-term chemical durability. Additionally, a model generated during this study for predicting softening temperature of silicate binder glasses is presented.« less

LEACHING BOUNDARY MOVEMENT IN SOLIDIFIED/STABILIZED WASTE FORMS

EPA Science Inventory

Investigation of the leaching of cement-based waste forms in acetic acid solutions found that acids attacked the waste form from the surface toward the center. A sharp leaching boundary was identified in every leached sample, using pH color indica- tors. The movement of the leach...

The French Mess Nucleaire

DOE Office of Scientific and Technical Information (OSTI.GOV)

Davis, M.B.

1994-07-01

Nuclear weapons production has contaminated parts of France, and measures to counter this contamination may be as much cover-up as cleanup. The nuclear weapons industry is trying to remedy some of the problems it created. But until France lifts military secrecy from weapons production matters that affect the environment, the public has no way to gauge the cleanup. No institution outside the Atomic Energy Commission (CEA) and the Ministry of Defense has control over waste disposal, decontamination, and dismantlement at military nuclear sites. The major generators of weapons production waste in France are the CEA and Cogema, one of itsmore » many subsidiaries. Regular operations in military production sites produce environmental contamination. The authors also discuss some accidents causing further contamination. The clean-up measures that the industry is known to be taking, diluting the waste and minimizing the amount of waste, are suspect. The earth`s atmosphere has been considered a prime medium for diluting waste by open air burning of radioactive materials. Releases of mercury to the atmosphere, 260 kilograms per year as of 1984, contributed to water pollution as rain washed the mercury out of the air. Ocean dumping was the CEA`s answer to disposal of sold as well as liquid wastes. Injection liquids into the soil has been a temptation at sites not near substantial bodies of water. Burial of solid wastes has been common. The nuclear industry and the military must make public where and in what form wastes are stored. They must allow independent experts and institutions to examine their research, fabrication, and waste disposal sites. 48 refs.« less

Women's Environmental Literacy As Social Capital In Environmental Management For Environmental Security of Urban Area

NASA Astrophysics Data System (ADS)

Asteria, Donna; Herdiansyah, Herdis; Wayan Agus Apriana, I.

2016-02-01

This study is about experience of women's role in environmental management to raise environmental security and form of women's emancipation movement. Environmental concerns conducted by residents of urban women who become environmental activists based on environmental literacy. Because of that, women's experience in interacting with both physic and social environment have differences in managing the environment including managing household waste by applying the principles of the 3Rs (reduce, reuse, recycle) and their persuasive efforts on their communities. This is the key to achieving sustainable development by anticipating environmental problem and preserving the environment. This study is conducted qualitative research method and its type is descriptive-explanative. The result of this study is environmental literacy of women activist on pro-environment action in their community that has achieved spiritual environmental literacy. Environmental literacy may differ due to internal and external condition of each individual. Pro-environment activities conducted as a form of responsibility of environmental concern such as eco-management, educational, and economic action, by persuading residents to proactively and consistently continue to do environmental management and develop a sense of community in shaping the networks of environmental concern in local context for global effect.

An investigation of waste foundry sand in asphalt concrete mixtures.

PubMed

Bakis, Recep; Koyuncu, Hakan; Demirbas, Ayhan

2006-06-01

A laboratory study regarding the reuse of waste foundry sand in asphalt concrete production by replacing a certain portion of aggregate with WFS was undertaken. The results showed that replacement of 10% aggregates with waste foundry sand was found to be the most suitable for asphalt concrete mixtures. Furthermore, the chemical and physical properties of waste foundry sand were analysed in the laboratory to determine the potential effect on the environment. The results indicated that the investigated waste foundry sand did not significantly affect the environment around the deposition

Nuclear fuel cycle waste stream immobilization with cermets for improved thermal properties and waste consolidation

NASA Astrophysics Data System (ADS)

Ortega, Luis H.; Kaminski, Michael D.; Zeng, Zuotao; Cunnane, James

2013-07-01

In the pursuit of methods to improve nuclear waste form thermal properties and combine potential nuclear fuel cycle wastes, a bronze alloy was combined with an alkali, alkaline earth metal bearing ceramic to form a cermet. The alloy was prepared from copper and tin (10 mass%) powders. Pre-sintered ceramic consisting of cesium, strontium, barium and rubidium alumino-silicates was mixed with unalloyed bronze precursor powders and cold pressed to 300 × 103 kPa, then sintered at 600 °C and 800 °C under hydrogen. Cermets were also prepared that incorporated molybdenum, which has a limited solubility in glass, under similar conditions. The cermet thermal conductivities were seven times that of the ceramic alone. These improved thermal properties can reduce thermal gradients within the waste forms thus lowering internal temperature gradients and thermal stresses, allowing for larger waste forms and higher waste loadings. These benefits can reduce the total number of waste packages necessary to immobilize a given amount of high level waste and immobilize troublesome elements.

40 CFR 60.2630 - What should I include in my waste management plan?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 7 2012-07-01 2012-07-01 false What should I include in my waste management plan? 60.2630 Section 60.2630 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... consideration of the reduction or separation of waste-stream elements such as paper, cardboard, plastics, glass...

40 CFR 62.14590 - What should I include in my waste management plan?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 9 2014-07-01 2014-07-01 false What should I include in my waste management plan? 62.14590 Section 62.14590 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... separation of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or metals; or the...

40 CFR 62.14590 - What should I include in my waste management plan?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 9 2013-07-01 2013-07-01 false What should I include in my waste management plan? 62.14590 Section 62.14590 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... separation of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or metals; or the...

40 CFR 60.2065 - What should I include in my waste management plan?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 7 2013-07-01 2013-07-01 false What should I include in my waste management plan? 60.2065 Section 60.2065 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... reduction or separation of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or...

40 CFR 60.2901 - What should I include in my waste management plan?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 7 2014-07-01 2014-07-01 false What should I include in my waste management plan? 60.2901 Section 60.2901 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... consideration of the reduction or separation of waste-stream elements such as paper, cardboard, plastics, glass...

40 CFR 60.2065 - What should I include in my waste management plan?

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 7 2014-07-01 2014-07-01 false What should I include in my waste management plan? 60.2065 Section 60.2065 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... reduction or separation of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or...

40 CFR 62.14590 - What should I include in my waste management plan?

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 9 2012-07-01 2012-07-01 false What should I include in my waste management plan? 62.14590 Section 62.14590 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... separation of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or metals; or the...

40 CFR 60.2901 - What should I include in my waste management plan?

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 7 2013-07-01 2013-07-01 false What should I include in my waste management plan? 60.2901 Section 60.2901 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... consideration of the reduction or separation of waste-stream elements such as paper, cardboard, plastics, glass...

40 CFR 60.2630 - What should I include in my waste management plan?

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 6 2011-07-01 2011-07-01 false What should I include in my waste management plan? 60.2630 Section 60.2630 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... of waste-stream elements such as paper, cardboard, plastics, glass, batteries, or metals; or the use...

40 CFR 256.02 - Scope of the State solid waste management plan.

Code of Federal Regulations, 2011 CFR

2011-07-01

..., General Requirements, Definitions § 256.02 Scope of the State solid waste management plan. (a)(1) The... 40 Protection of Environment 25 2011-07-01 2011-07-01 false Scope of the State solid waste management plan. 256.02 Section 256.02 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 256.02 - Scope of the State solid waste management plan.

Code of Federal Regulations, 2013 CFR

2013-07-01

..., General Requirements, Definitions § 256.02 Scope of the State solid waste management plan. (a)(1) The... 40 Protection of Environment 26 2013-07-01 2013-07-01 false Scope of the State solid waste management plan. 256.02 Section 256.02 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 256.02 - Scope of the State solid waste management plan.

Code of Federal Regulations, 2014 CFR

2014-07-01

..., General Requirements, Definitions § 256.02 Scope of the State solid waste management plan. (a)(1) The... 40 Protection of Environment 25 2014-07-01 2014-07-01 false Scope of the State solid waste management plan. 256.02 Section 256.02 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 256.02 - Scope of the State solid waste management plan.

Code of Federal Regulations, 2010 CFR

2010-07-01

..., General Requirements, Definitions § 256.02 Scope of the State solid waste management plan. (a)(1) The... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Scope of the State solid waste management plan. 256.02 Section 256.02 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

40 CFR 256.02 - Scope of the State solid waste management plan.

Code of Federal Regulations, 2012 CFR

2012-07-01

..., General Requirements, Definitions § 256.02 Scope of the State solid waste management plan. (a)(1) The... 40 Protection of Environment 26 2012-07-01 2011-07-01 true Scope of the State solid waste management plan. 256.02 Section 256.02 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED...

Plastic waste in the marine environment: A review of sources, occurrence and effects.

PubMed

Li, W C; Tse, H F; Fok, L

2016-10-01

This review article summarises the sources, occurrence, fate and effects of plastic waste in the marine environment. Due to its resistance to degradation, most plastic debris will persist in the environment for centuries and may be transported far from its source, including great distances out to sea. Land- and ocean-based sources are the major sources of plastic entering the environment, with domestic, industrial and fishing activities being the most important contributors. Ocean gyres are particular hotspots of plastic waste accumulation. Both macroplastics and microplastics pose a risk to organisms in the natural environment, for example, through ingestion or entanglement in the plastic. Many studies have investigated the potential uptake of hydrophobic contaminants, which can then bioaccumulate in the food chain, from plastic waste by organisms. To address the issue of plastic pollution in the marine environment, governments should first play an active role in addressing the issue of plastic waste by introducing legislation to control the sources of plastic debris and the use of plastic additives. In addition, plastics industries should take responsibility for the end-of-life of their products by introducing plastic recycling or upgrading programmes. Copyright © 2016 Elsevier B.V. All rights reserved.

[Pollution characteristics of PCBs in electronic waste dismantling areas of Zhejiang province].

PubMed

Wang, Xiaofeng; Lou, Xiaoming; Han, Guangen; Shen, Haitao; Ding, Gangqiang

2011-09-01

To study the pollution level and distribution pattern of polychlorinated biphenyls (PCBs) in the environment media in electronic waste dismantling area of Zhejiang province. Water, soil and PM10 were sampled in electronic waste dismantling areas. The contents, distribution characteristics and toxic equivalents (TEQs) of PCBs in local environment were evaluated by ultra-trace detection methods. The PCBs contents of water, soil and PM10 in Luqiao and Zhenhai, the relatively high polluted areas, were higher than those in Longyou, the control area. The dominant PCBs detected from the environment in Luqiao were hexa-CBs (PCB138 and PCB153), while penta-CBs were dominant in Zhenhai and Longyou. TEQs in electronic waste recycling area were higher than those in control areas. The TEQs of PCBs in water and soil were the highest in Zhenhai, while the TEQs of PM10 were the highest in Luqiao. The local environment has been polluted by PCBs emitted from electronic waste recycling. PCBs pollution monitoring in electronic waste recycling area should be strengthened to prevent PCBs-induced health effects.

Cast Stone Formulation for Nuclear Waste Immobilization at Higher Sodium Concentrations

DOE PAGES

Fox, Kevin; Cozzi, Alex; Roberts, Kimberly; ...

2014-11-01

Low activity radioactive waste at U.S. Department of Energy sites can be immobilized for permanent disposal using cementitious waste forms. This study evaluated waste forms produced with simulated wastes at concentrations up to twice that of currently operating processes. The simulated materials were evaluated for their fresh properties, which determine processability, and cured properties, which determine waste form performance. The results show potential for greatly reducing the volume of material. Fresh properties were sufficient to allow for processing via current practices. Cured properties such as compressive strength meet disposal requirements. Leachability indices provide an indication of expected long-term performance.

One System Integrated Project Team: Retrieval And Delivery Of The Hanford Tank Wastes For Vitrification In The Waste Treatment Plant

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harp, Benton J.; Kacich, Richard M.; Skwarek, Raymond J.

The One System Integrated Project Team (IPT) was formed in late 2011 as a way for improving the efficiency of delivery and treatment of highly radioactive waste stored in underground tanks at the U.S. Department of Energy's (DOE's) 586-square-mile Hanford Site in southeastern Washington State. The purpose of the One System IPT is to improve coordination and integration between the Hanford's Waste Treatment Plant (WTP) contractor and the Tank Operations Contractor (TOC). The vision statement is: One System is a WTP and TOC safety conscious team that, through integrated management and implementation of risk-informed decision and mission-based solutions, will enablemore » the earliest start of safe and efficient treatment of Hanford's tank waste, to protect the Columbia River, environment and public. The IPT is a formal collaboration between Bechtel National, Inc. (BNI), which manages design and construction of the WTP for the U.S. Department of Energy's Office of River Protection (DOEORP), and Washington River Protection Solutions (WRPS), which manages the TOC for ORP. More than fifty-six (56) million gallons of highly radioactive liquid waste are stored in one hundred seventy-seven (177) aging, underground tanks. Most of Hanford's waste tanks - one hundred forty-nine (149) of them - are of an old single-shell tank (SST) design built between 1944 and 1964. More than sixty (60) of these tanks have leaked in the past, releasing an estimated one million gallons of waste into the soil and threatening the nearby Columbia River. There are another twenty-eight (28) new double-shelled tanks (DSTs), built from 1968 to 1986, that provide greater protection to the environment. In 1989, DOE, the U.S. Environmental Protection Agency (EPA), and the Washington State Department of Ecology (Ecology) signed a landmark agreement that required Hanford to comply with federal and state environmental standards. It also paved the way for agreements that set deadlines for retrieving the tank wastes and for building and operating the WTP. The tank wastes are the result of Hanford's nearly fifty (50) years of plutonium production. In the intervening years, waste characteristics have been increasingly better understood. However, waste characteristics that are uncertain and will remain as such represent a significant technical challenge in terms of retrieval, transport, and treatment, as well as for design and construction ofWTP. What also is clear is that the longer the waste remains in the tanks, the greater the risk to the environment and the people of the Pacific Northwest. The goal of both projects - tank operations and waste treatment - is to diminish the risks posed by the waste in the tanks at the earliest possible date. About two hundred (200) WTP and TOC employees comprise the IPT. Individual work groups within One System include Technical, Project Integration & Controls, Front-End Design & Project Definition, Commissioning, Nuclear Safety & Engineering Systems Integration, and Environmental Safety and Health and Quality Assurance (ESH&QA). Additional functions and team members will be added as the WTP approaches the operational phase. The team has undertaken several initiatives since its formation to collaborate on issues: (1) alternate scenarios for delivery of wastes from the tank farms to WTP; (2) improvements in managing Interface Control Documents; (3) coordination on various technical issues, including the Defense Nuclear Facilities Nuclear Safety Board's Recommendation 2010-2; (4) deployment of the SmartPlant Foundation-configuration Management System; and (5) preparation of the joint contract deliverable of the Operational Readiness Support Plan.« less

40 CFR 260.30 - Non-waste determinations and variances from classification as a solid waste.

Code of Federal Regulations, 2010 CFR

2010-07-01

... from classification as a solid waste. 260.30 Section 260.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking Petitions § 260.30 Non-waste determinations and variances from classification as a solid waste. In...

40 CFR 260.30 - Non-waste determinations and variances from classification as a solid waste.

Code of Federal Regulations, 2011 CFR

2011-07-01

... from classification as a solid waste. 260.30 Section 260.30 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) HAZARDOUS WASTE MANAGEMENT SYSTEM: GENERAL Rulemaking Petitions § 260.30 Non-waste determinations and variances from classification as a solid waste. In...

Methods and system for subsurface stabilization using jet grouting

DOEpatents

Loomis, Guy G.; Weidner, Jerry R.; Farnsworth, Richard K.; Gardner, Bradley M.; Jessmore, James J.

1999-01-01

Methods and systems are provided for stabilizing a subsurface area such as a buried waste pit for either long term storage, or interim storage and retrieval. A plurality of holes are drilled into the subsurface area with a high pressure drilling system provided with a drill stem having jet grouting nozzles. A grouting material is injected at high pressure through the jet grouting nozzles into a formed hole while the drill stem is withdrawn from the hole at a predetermined rate of rotation and translation. A grout-filled column is thereby formed with minimal grout returns, which when overlapped with other adjacent grout-filled columns encapsulates and binds the entire waste pit area to form a subsurface agglomeration or monolith of grout, soil, and waste. The formed monolith stabilizes the buried waste site against subsidence while simultaneously providing a barrier against contaminate migration. The stabilized monolith can be left permanently in place or can be retrieved if desired by using appropriate excavation equipment. The jet grouting technique can also be utilized in a pretreatment approach prior to in situ vitrification of a buried waste site. The waste encapsulation methods and systems are applicable to buried waste materials such as mixed waste, hazardous waste, or radioactive waste.

Development of Alternative Technetium Waste Forms

DOE Office of Scientific and Technical Information (OSTI.GOV)

Czerwinski, Kenneth

2013-09-13

The UREX+1 process is under consideration for the separation of transuranic elements from spent nuclear fuel. The first steps of this process extract the fission product technicium-99 ({sup 99}Tc) into an organic phase containing tributylphosphate together with uranium. Treatment of this stream requires the separation of Tc from U and placement into a suitable waste storage form. A potential candidate waste form involves immobilizing the Tc as an alloy with either excess metallic zirconium or stainless steel. Although Tc-Zr alloys seem to be promising waste forms, alternative materials must be investigated. Innovative studies related to the synthesis and behavior ofmore » a different class of Tc materials will increase the scientific knowledge related to development of Tc waste forms. These studies will also provide a better understanding of the behavior of {sup 99}Tc in repository conditions. A literature survey has selected promising alternative waste forms for further study: technetium metallic alloys, nitrides, oxides, sulfides, and pertechnetate salts. The goals of this project are to 1) synthesize and structurally characterize relevant technetium materials that may be considered as waste forms, 2) investigate material behavior in solution under different conditions of temperature, electrochemical potential, and radiation, and 3) predict the long-term behavior of these materials.« less

Methods of vitrifying waste with low melting high lithia glass compositions

DOEpatents

Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

2001-01-01

The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

Epsilon Metal Waste Form for Immobilization of Noble Metals from Used Nuclear Fuel

DOE Office of Scientific and Technical Information (OSTI.GOV)

Crum, Jarrod V.; Strachan, Denis M.; Rohatgi, Aashish

2013-10-01

Epsilon metal (ε-metal), an alloy of Mo, Pd, Rh, Ru, and Tc, is being developed as a waste form to treat and immobilize the undissolved solids and dissolved noble metals from aqueous reprocessing of commercial used nuclear fuel. Epsilon metal is an attractive waste form for several reasons: increased durability relative to borosilicate glass, it can be fabricated without additives (100% waste loading), and in addition it also benefits borosilicate glass waste loading by eliminating noble metals from the glass and thus the processing problems related there insolubility in glass. This work focused on the processing aspects of the epsilonmore » metal waste form development. Epsilon metal is comprised of refractory metals resulting in high reaction temperatures to form the alloy, expected to be 1500 - 2000°C making it a non-trivial phase to fabricate by traditional methods. Three commercially available advanced technologies were identified: spark-plasma sintering, microwave sintering, and hot isostatic pressing, and investigated as potential methods to fabricate this waste form. Results of these investigations are reported and compared in terms of bulk density, phase assemblage (X-ray diffraction and elemental analysis), and microstructure (scanning electron microscopy).« less

E-waste scenario in India, its management and implications.

PubMed

Wath, Sushant B; Dutt, P S; Chakrabarti, T

2011-01-01

Electronic waste or E-waste comprises of old, end-of-life electronic appliances such as computers, laptops, TVs, DVD players, refrigerators, freezers, mobile phones, MP3 players, etc., which have been disposed of by their original users. E-waste contains many hazardous constituents that may negatively impact the environment and affect human health if not properly managed. Various organizations, bodies, and governments of many countries have adopted and/or developed the environmentally sound options and strategies for E-waste management to tackle the ever growing threat of E-waste to the environment and human health. This paper presents E-waste composition, categorization, Global and Indian E-waste scenarios, prospects of recoverable, recyclable, and hazardous materials found in the E-waste, Best Available Practices, recycling, and recovery processes followed, and their environmental and occupational hazards. Based on the discussion, various challenges for E-waste management particularly in India are delineated, and needed policy interventions were discussed.

Guidelines for generators to meet HWHF acceptance requirements for hazardous, radioactive, and mixed wastes at Berkeley Lab. Revision 3

DOE Office of Scientific and Technical Information (OSTI.GOV)

Albert, R.

1996-06-01

This document provides performance standards that one, as a generator of hazardous chemical, radioactive, or mixed wastes at the Berkeley Lab, must meet to manage their waste to protect Berkeley Lab staff and the environment, comply with waste regulations and ensure the continued safe operation of the workplace, have the waste transferred to the correct Waste Handling Facility, and enable the Environment, Health and Safety (EH and S) Division to properly pick up, manage, and ultimately send the waste off site for recycling, treatment, or disposal. If one uses and generates any of these wastes, one must establish a Satellitemore » Accumulation Area and follow the guidelines in the appropriate section of this document. Topics include minimization of wastes, characterization of the wastes, containers, segregation, labeling, empty containers, and spill cleanup and reporting.« less

Arroyo channel head evolution in a flash-flood-dominated discontinuous ephemeral stream system

USGS Publications Warehouse

DeLong, Stephen B.; Johnson, Joel P.L.; Whipple, Kelin X.

2014-01-01

We study whether arroyo channel head retreat in dryland discontinuous ephemeral streams is driven by surface runoff, seepage erosion, mass wasting, or some combination of these hydrogeomorphic processes. We monitored precipitation, overland flow, soil moisture, and headcut migration over several seasonal cycles at two adjacent rangeland channel heads in southern Arizona. Erosion occurred by headward retreat of vertical to overhanging faces, driven dominantly by surface runoff. No evidence exists for erosion caused by shallow-groundwater–related processes, even though similar theater-headed morphologies are sometimes attributed to seepage erosion by emerging groundwater. At our field site, vertical variation in soil shear strength influenced the persistence of the characteristic theater-head form. The dominant processes of erosion included removal of grains and soil aggregates during even very shallow (1–3 cm) overland flow events by runoff on vertical to overhanging channel headwalls, plunge-pool erosion during higher-discharge runoff events, immediate postrunoff wet mass wasting, and minor intra-event dry mass wasting on soil tension fractures developing subparallel to the headwall. Multiple stepwise linear regression indicates that the migration rate is most strongly correlated with flow duration and total precipitation and is poorly correlated with peak flow depth or time-integrated flow depth. The studied channel heads migrated upslope with a self-similar morphologic form under a wide range of hydrological conditions, and the most powerful flash floods were not always responsible for the largest changes in landscape form in this environment. 

Hazardous Waste Generators

EPA Pesticide Factsheets

Many industries generate hazardous waste. EPA regulates hazardous waste under the Resource Conservation and Recovery Act to ensure these wastes are managed in ways that are protective of human health and the environment.

Impact of intervention on healthcare waste management practices in a tertiary care governmental hospital of Nepal.

PubMed

Sapkota, Binaya; Gupta, Gopal Kumar; Mainali, Dhiraj

2014-09-26

Healthcare waste is produced from various therapeutic procedures performed in hospitals, such as chemotherapy, dialysis, surgery, delivery, resection of gangrenous organs, autopsy, biopsy, injections, etc. These result in the production of non-hazardous waste (75-95%) and hazardous waste (10-25%), such as sharps, infectious, chemical, pharmaceutical, radioactive waste, and pressurized containers (e.g., inhaler cans). Improper healthcare waste management may lead to the transmission of hepatitis B, Staphylococcus aureus and Pseudomonas aeruginosa. This evaluation of waste management practices was carried out at gynaecology, obstetrics, paediatrics, medicine and orthopaedics wards at Government of Nepal Civil Service Hospital, Kathmandu from February 12 to October 15, 2013, with the permission from healthcare waste management committee at the hospital. The Individualized Rapid Assessment tool (IRAT), developed by the United Nations Development Program Global Environment Facility project, was used to collect pre-interventional and post-interventional performance scores concerning waste management. The healthcare waste management committee was formed of representing various departments. The study included responses from focal nurses and physicians from the gynaecology, obstetrics, paediatrics, medicine and orthopaedics wards, and waste handlers during the study period. Data included average scores from 40 responders. Scores were based on compliance with the IRAT. The waste management policy and standard operating procedure were developed after interventions, and they were consistent with the national and international laws and regulations. The committee developed a plan for recycling or waste minimization. Health professionals, such as doctors, nurses and waste handlers, were trained on waste management practices. The programs included segregation, collection, handling, transportation, treatment and disposal of waste, as well as occupational health and safety issues. The committee developed a plan for treatment and disposal of chemical and pharmaceutical waste. Pretest and posttest evaluation scores were 26% and 86% respectively. During the pre-intervention period, the hospital had no HCWM Committee, policy, standard operating procedure or proper color coding system for waste segregation, collection, transportation and storage and the specific well-trained waste handlers. Doctors, nurses and waste handlers were trained on HCWM practices, after interventions. Significant improvements were observed between the pre- and post-intervention periods.

10 CFR 60.17 - Contents of site characterization plan.

Code of Federal Regulations, 2012 CFR

2012-01-01

... assurance to data collection, recording, and retention. (3) Plans for the decontamination and... rule or order, requires. (b) A description of the possible waste form or waste package for the high... practicable) of the relationship between such waste form or waste package and the host rock at such area, and...

10 CFR 60.17 - Contents of site characterization plan.

Code of Federal Regulations, 2013 CFR

2013-01-01

... assurance to data collection, recording, and retention. (3) Plans for the decontamination and... rule or order, requires. (b) A description of the possible waste form or waste package for the high... practicable) of the relationship between such waste form or waste package and the host rock at such area, and...

10 CFR 60.17 - Contents of site characterization plan.

Code of Federal Regulations, 2014 CFR

2014-01-01

... assurance to data collection, recording, and retention. (3) Plans for the decontamination and... rule or order, requires. (b) A description of the possible waste form or waste package for the high... practicable) of the relationship between such waste form or waste package and the host rock at such area, and...

10 CFR 60.17 - Contents of site characterization plan.

Code of Federal Regulations, 2011 CFR

2011-01-01

... assurance to data collection, recording, and retention. (3) Plans for the decontamination and... rule or order, requires. (b) A description of the possible waste form or waste package for the high... practicable) of the relationship between such waste form or waste package and the host rock at such area, and...

40 CFR 273.52 - Waste management.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 28 2013-07-01 2013-07-01 false Waste management. 273.52 Section 273...) STANDARDS FOR UNIVERSAL WASTE MANAGEMENT Standards for Universal Waste Transporters § 273.52 Waste management. (a) A universal waste transporter must comply with all applicable U.S. Department of...

40 CFR 273.52 - Waste management.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 28 2012-07-01 2012-07-01 false Waste management. 273.52 Section 273...) STANDARDS FOR UNIVERSAL WASTE MANAGEMENT Standards for Universal Waste Transporters § 273.52 Waste management. (a) A universal waste transporter must comply with all applicable U.S. Department of...

40 CFR 273.52 - Waste management.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 27 2011-07-01 2011-07-01 false Waste management. 273.52 Section 273...) STANDARDS FOR UNIVERSAL WASTE MANAGEMENT Standards for Universal Waste Transporters § 273.52 Waste management. (a) A universal waste transporter must comply with all applicable U.S. Department of...

40 CFR 273.52 - Waste management.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 27 2014-07-01 2014-07-01 false Waste management. 273.52 Section 273...) STANDARDS FOR UNIVERSAL WASTE MANAGEMENT Standards for Universal Waste Transporters § 273.52 Waste management. (a) A universal waste transporter must comply with all applicable U.S. Department of...

40 CFR 273.52 - Waste management.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 26 2010-07-01 2010-07-01 false Waste management. 273.52 Section 273...) STANDARDS FOR UNIVERSAL WASTE MANAGEMENT Standards for Universal Waste Transporters § 273.52 Waste management. (a) A universal waste transporter must comply with all applicable U.S. Department of...

The use of positrons to survey alteration layers on synthetic nuclear waste glasses

NASA Astrophysics Data System (ADS)

Reiser, Joelle T.; Parruzot, Benjamin; Weber, Marc H.; Ryan, Joseph V.; McCloy, John S.; Wall, Nathalie A.

2017-07-01

In order to safeguard society and the environment, understanding radioactive waste glass alteration mechanisms in interactions with solutions and near-field materials, such as Fe, is essential to nuclear waste repository performance assessments. Alteration products are formed at the surface of glasses after reaction with solution. In this study, glass altered in the presence of Fe0 in aqueous solution formed two alteration layers: one embedded with Fe closer to the surface and one without Fe found deeper in the sample. Both layers were found to be thinner than the alteration layer found in glass altered in aqueous solution only. For the first time, Doppler Broadening Positron Annihilation Spectroscopy (DB-PAS) is used to non-destructively characterize the pore structures of glass altered in the presence of Fe0. Advantages and disadvantages of DB-PAS compared to other techniques used to analyze pore structures for altered glass samples are discussed. Ultimately, DB-PAS has shown to be an excellent choice for pore structure characterization for glasses with multiple alteration layers. Monte Carlo modeling predicted positron trajectories through the layers, and helped explain DB-PAS data, which showed that the deeper alteration layer without Fe had a similar composition and pore structure to layers on glass altered in water only.

The use of positrons to survey alteration layers on synthetic nuclear waste glasses

DOE PAGES

Reiser, Joelle T.; Parruzot, Benjamin; Weber, Marc H.; ...

2017-07-01

Here, in order to safeguard society and the environment, understanding radioactive waste glass alteration mechanisms in interactions with solutions and near-field materials, such as Fe, is essential to nuclear waste repository performance assessments. Alteration products are formed at the surface of glasses after reaction with solution. In this study, glass altered in the presence of Fe 0 in aqueous solution formed two alteration layers: one embedded with Fe closer to the surface and one without Fe found deeper in the sample. Both layers were found to be thinner than the alteration layer found in glass altered in aqueous solution only.more » For the first time, Doppler Broadening Positron Annihilation Spectroscopy (DB-PAS) is used to non-destructively characterize the pore structures of glass altered in the presence of Fe 0. Advantages and disadvantages of DB-PAS compared to other techniques used to analyze pore structures for altered glass samples are discussed. Ultimately, DB-PAS has shown to be an excellent choice for pore structure characterization for glasses with multiple alteration layers. Monte Carlo modeling predicted positron trajectories through the layers, and helped explain DB-PAS data, which showed that the deeper alteration layer without Fe had a similar composition and pore structure to layers on glass altered in water only.« less

The use of positrons to survey alteration layers on synthetic nuclear waste glasses

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reiser, Joelle T.; Parruzot, Benjamin; Weber, Marc H.

Here, in order to safeguard society and the environment, understanding radioactive waste glass alteration mechanisms in interactions with solutions and near-field materials, such as Fe, is essential to nuclear waste repository performance assessments. Alteration products are formed at the surface of glasses after reaction with solution. In this study, glass altered in the presence of Fe 0 in aqueous solution formed two alteration layers: one embedded with Fe closer to the surface and one without Fe found deeper in the sample. Both layers were found to be thinner than the alteration layer found in glass altered in aqueous solution only.more » For the first time, Doppler Broadening Positron Annihilation Spectroscopy (DB-PAS) is used to non-destructively characterize the pore structures of glass altered in the presence of Fe 0. Advantages and disadvantages of DB-PAS compared to other techniques used to analyze pore structures for altered glass samples are discussed. Ultimately, DB-PAS has shown to be an excellent choice for pore structure characterization for glasses with multiple alteration layers. Monte Carlo modeling predicted positron trajectories through the layers, and helped explain DB-PAS data, which showed that the deeper alteration layer without Fe had a similar composition and pore structure to layers on glass altered in water only.« less

Phase-Pure and Multiphase Ceramic Waste Forms: Microstructure Evolution and Cesium Immobilization

NASA Astrophysics Data System (ADS)

Tumurugoti, Priyatham

Efforts of this thesis are directed towards developing ceramic waste forms as a potential replacement for the conventional glass waste forms for the safe immobilization and disposal of nuclear wastes from the legacy weapons programs as well as commercial power production. The body of this work consists of two equal parts with first focused on multiphase waste form containing hollandite as major phase and the later, on single-phase hollandites for Cs incorporation. Part I: Multiphase waste forms:. Hollandite-rich multiphase waste form compositions processed by melt-solidification and spark plasma sintering (SPS) were characterized, compared, and validated for nuclear waste incorporation. Phase identification by X-ray diffraction (XRD) and electron back-scattered diffraction (EBSD) confirm hollandite as the major phase present in these samples along with perovskite, pyrochlore and zirconolite. Distribution of select elements observed by wavelength dispersive spectroscopy (WDS) maps indicate that Cs forms a secondary phase during SPS processing, which is considered undesirable. On the other hand Cs partitioned into hollandite phase in melt-processed samples. Further analysis of hollandite structure in melt-processed composition, by selected area electron diffraction (SAED), reveals ordered arrangement of tunnel ions (Ba/Cs) and vacancies, suggesting efficient Cs incorporation into the lattice. Following the microstructural analysis, the crystallization behavior of the multiphase composition during melt-processing was studied. The phase assemblage and evolution of hollandite, zirconolite, pyrochlore, and perovskite type structures during melt processing were studied using thermal analysis, in-situ XRD, and scanning electron microscopy (SEM). Samples prepared by melting followed by annealing and quenching were analyzed to determine and measure the progression of the phase assemblage. Samples were melted at 1500°C and heat-treated at crystallization temperatures of 1285°C and 1325°C corresponding to exothermic events identified from differential scanning calorimetry (DSC) measurements. Results indicate that the selected multiphase composition partially melts at 1500°C with hollandite coexisting as crystalline phase. Perovskite and zirconolite phases crystallized from the residual melt at temperatures below 1350°C. Depending on their respective thermal histories, different quenched samples were found to have different phase assemblages including phases such as perovskite, zirconolite and TiO2. Part II: Single phase waste forms. Hollandites with compositions Ba1.15-xCs2xCr 2.3Ti5.7O16 have been identified as promising lattices to host Cs. Series of compositions with 0 ≤ x ≤ 1.15 were prepared by sol-gel synthesis, characterized, and analyzed for Cs retention properties. Phase-pure hollandites adopting monoclinic symmetry (I2/m) were observed to form in the compositional range 0 ≤ x ≤ 0.4. Structural models for the compositions: x = 0, 0.15, and 0.25, were developed from Rietveld analysis of powder XRD and neutron diffraction data. Refined anisotropic displacement parameters (beta ij) for Ba and Cs ions in the hollandite tunnels indicate local disorder of Ba/Cs along the tunnel direction. In addition, weak super lattice reflections have also been observed in XRD patterns. Our data suggests the presence of supercell structures with ordered tunnel cations for the phase-pure hollandites studied. Finally, the performance of phase-pure hollandites have been evaluated qualitatively by chemical durability testing and ion-irradiation experiments. Elemental analysis of the leachants after 7-day leach tests show that Cs and Cr were extracted from the lattice together. No direct correlation between structural parameters or Cs content was observed. The simulated light-ion (He2+) and heavy-ion (Kr3+) irradiation experiments reveal that all the hollandite compositions studied undergo amorphization during alpha-decay events, and the extent of it increases with the Cs content. In summary, the present work validates melt-processing as an effective method to prepare multiphase waste forms with the desired phase assemblage. Ba1.15-xCs2xCr2.3Ti5.7O16 hollandite has been identified as an effective ceramic host for Cs immobilization and appropriate structural models for hollandites with different Cs levels have been developed. The structural information may be used to study or simulate the lattice-environment interaction.

An overview on characterization, utilization and leachate analysis of biomedical waste incinerator ash.

PubMed

Rajor, Anita; Xaxa, Monika; Mehta, Ratika; Kunal

2012-10-15

Solid waste management is one of the major global environmental issues, as there is continuous increase in industrial globalization and generation of waste. Solid wastes encompass the heterogeneous mass of throwaways from the urban community as well as the homogeneous accumulations of agricultural, industrial and mineral wastes. Biomedical waste pose a significant impact on health and environment. A proper waste management system should be required to dispose hazardous biomedical waste and incineration should be the best available technology to reduce the volume of this hazardous waste. The incineration process destroys pathogens and reduces the waste volume and weight but leaves a solid material called biomedical waste ash as residue which increases the levels of heavy metals, inorganic salts and organic compounds in the environment. Disposal of biomedical waste ash in landfill may cause contamination of groundwater as metals are not destroyed during incineration. The limited space and the high cost for land disposal led to the development of recycling technologies and the reuse of ash in different systems. In order to minimize leaching of its hazardous components into the environment several studies confirmed the successful utilization of biomedical waste ash in agriculture and construction sector. This paper presents the overview on the beneficial use of ash in agriculture and construction materials and its leachate characteristics. This review also stressed on the need to further evaluate the leachate studies of the ashes and slag for their proper disposal and utilization. Copyright © 2012 Elsevier Ltd. All rights reserved.

Social life and sanitary risks: evolutionary and current ecological conditions determine waste management in leaf-cutting ants.

PubMed

Farji-Brener, Alejandro G; Elizalde, Luciana; Fernández-Marín, Hermógenes; Amador-Vargas, Sabrina

2016-05-25

Adequate waste management is vital for the success of social life, because waste accumulation increases sanitary risks in dense societies. We explored why different leaf-cutting ants (LCA) species locate their waste in internal nest chambers or external piles, including ecological context and accounting for phylogenetic relations. We propose that waste location depends on whether the environmental conditions enhance or reduce the risk of infection. We obtained the geographical range, habitat and refuse location of LCA from published literature, and experimentally determined whether pathogens on ant waste survived to the high soil temperatures typical of xeric habitats. The habitat of the LCA determined waste location after phylogenetic correction: species with external waste piles mainly occur in xeric environments, whereas those with internal waste chambers mainly inhabit more humid habitats. The ancestral reconstruction suggests that dumping waste externally is less derived than digging waste nest chambers. Empirical results showed that high soil surface temperatures reduce pathogen prevalence from LCA waste. We proposed that LCA living in environments unfavourable for pathogens (i.e. xeric habitats) avoid digging costs by dumping the refuse above ground. Conversely, in environments suitable for pathogens, LCA species prevent the spread of diseases by storing waste underground, presumably, a behaviour that contributed to the colonization of humid habitats. These results highlight the adaptation of organisms to the hygienic challenges of social living, and illustrate how sanitary behaviours can result from a combination of evolutionary history and current environmental conditions. © 2016 The Author(s).

Social life and sanitary risks: evolutionary and current ecological conditions determine waste management in leaf-cutting ants

PubMed Central

Farji-Brener, Alejandro G.; Elizalde, Luciana; Amador-Vargas, Sabrina

2016-01-01

Adequate waste management is vital for the success of social life, because waste accumulation increases sanitary risks in dense societies. We explored why different leaf-cutting ants (LCA) species locate their waste in internal nest chambers or external piles, including ecological context and accounting for phylogenetic relations. We propose that waste location depends on whether the environmental conditions enhance or reduce the risk of infection. We obtained the geographical range, habitat and refuse location of LCA from published literature, and experimentally determined whether pathogens on ant waste survived to the high soil temperatures typical of xeric habitats. The habitat of the LCA determined waste location after phylogenetic correction: species with external waste piles mainly occur in xeric environments, whereas those with internal waste chambers mainly inhabit more humid habitats. The ancestral reconstruction suggests that dumping waste externally is less derived than digging waste nest chambers. Empirical results showed that high soil surface temperatures reduce pathogen prevalence from LCA waste. We proposed that LCA living in environments unfavourable for pathogens (i.e. xeric habitats) avoid digging costs by dumping the refuse above ground. Conversely, in environments suitable for pathogens, LCA species prevent the spread of diseases by storing waste underground, presumably, a behaviour that contributed to the colonization of humid habitats. These results highlight the adaptation of organisms to the hygienic challenges of social living, and illustrate how sanitary behaviours can result from a combination of evolutionary history and current environmental conditions. PMID:27226469

40 CFR 262.83 - Notification and consent.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Section 262.83 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE Transboundary Movements of Hazardous Waste... exporting hazardous waste destined for recovery operations subject to this subpart. Hazardous wastes subject...

40 CFR 60.52a - Standard for municipal waste combustor metals.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 6 2011-07-01 2011-07-01 false Standard for municipal waste combustor metals. 60.52a Section 60.52a Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... September 20, 1994 § 60.52a Standard for municipal waste combustor metals. (a) On and after the date on...

40 CFR 60.52a - Standard for municipal waste combustor metals.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standard for municipal waste combustor metals. 60.52a Section 60.52a Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... September 20, 1994 § 60.52a Standard for municipal waste combustor metals. (a) On and after the date on...

A review on organic waste to energy systems in India.

PubMed

Dhar, Hiya; Kumar, Sunil; Kumar, Rakesh

2017-12-01

Waste generation is increasing day-by-day with the growth of population which directly affects the environment and economy. Organic municipal solid waste (MSW) and agriculture sectors contribute towards maximum waste generation in India. Thus, management of organic waste is very much essential with the increasing demand for energy. The present paper mainly focusses on reviewing waste to energy (WtE) potentials, its technologies, and the associated challenges. Different substrates are utilized through various technological options in India. Organic waste has good potential to attain sustainable energy yields with and without affecting the environment. A realistic scenario of WtE technologies and their challenges in line with the existing Indian condition is presented in this paper. Copyright © 2017 Elsevier Ltd. All rights reserved.

On The Cusp of the New Spatial Challenges - The Thermal Waste Processing Plant as an Element of Urban Space

NASA Astrophysics Data System (ADS)

Wójtowicz-Wróbel, Agnieszka

2017-10-01

The goal of this paper is to answer the question about the current importance of structures associated with the thermal processing of waste within the space of Polish cities and what status can they have in the functional and spatial structure of Polish cities in the future. The construction of thermal waste processing plants in Poland is currently a new and important problem, with numerous structures of this type being built due to increasing care for the natural environment, with the introduction of legal regulations, as well as due to the possibility of obtaining large external funding for the purposes of undertaking pro-environmental spatial initiatives, etc. For this reason, the paper contains research on the increase in the number of thermal waste processing plants in Poland in recent years. The abovementioned data was compared with similar information from other European Union member states. In the group containing Polish thermal waste processing plants, research was performed regarding the stage of the construction of a plant (operating plant, plant under construction, design in a construction phase, etc.). The paper also contains a listing of the functions other than the basic form of use, which is the incineration of waste - similarly to numerous foreign examples - that the environmentally friendly waste incineration plants fulfil in Poland, dividing the additional forms of use into "hard" elements (at the design level, requiring the expansion of a building featuring new elements that are not directly associated with the basic purpose of waste processing) and soft (social, educational, promotional actions, as well as other endeavours that require human involvement, but that do not entail significant design work on the buildings itself, expanding its form of use, etc.) as well as mixed activity, which required design work, but on a relatively small scale. Research was also conducted regarding the placement of thermal waste processing plants within the spatial structures of cities (a city’s outer zone, central zone, etc.) and their placement in relation to the more important urban units, in addition to specifying what type of urban structure they are located in. On the basis of the research, we can observe that the construction of environmentally friendly thermal waste processing plants is a valid and new problem in Poland, and the potential that lies in the construction of a new environmentally friendly structure and the possibility of using it to improve the quality of an urban space is often left untapped, bringing the construction of such a structure down to nothing but its technological function. The research can serve as a comparative study for similar experiences in other countries, or for studies related to urban structures and their elements.

40 CFR 258.20 - Procedures for excluding the receipt of hazardous waste.

Code of Federal Regulations, 2011 CFR

2011-07-01

... of hazardous waste. 258.20 Section 258.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS Operating Criteria § 258.20 Procedures..., regulated hazardous waste means a solid waste that is a hazardous waste, as defined in 40 CFR 261.3, that is...

40 CFR 258.20 - Procedures for excluding the receipt of hazardous waste.

Code of Federal Regulations, 2010 CFR

2010-07-01

... of hazardous waste. 258.20 Section 258.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS Operating Criteria § 258.20 Procedures..., regulated hazardous waste means a solid waste that is a hazardous waste, as defined in 40 CFR 261.3, that is...

40 CFR 261.10 - Criteria for identifying the characteristics of hazardous waste.

Code of Federal Regulations, 2014 CFR

2014-07-01

... characteristics of hazardous waste. 261.10 Section 261.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION AND LISTING OF HAZARDOUS WASTE Criteria for Identifying the Characteristics of Hazardous Waste and for Listing Hazardous Waste § 261.10 Criteria for...

40 CFR 261.10 - Criteria for identifying the characteristics of hazardous waste.

Code of Federal Regulations, 2013 CFR

2013-07-01

... characteristics of hazardous waste. 261.10 Section 261.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION AND LISTING OF HAZARDOUS WASTE Criteria for Identifying the Characteristics of Hazardous Waste and for Listing Hazardous Waste § 261.10 Criteria for...

40 CFR 261.10 - Criteria for identifying the characteristics of hazardous waste.

Code of Federal Regulations, 2012 CFR

2012-07-01

... characteristics of hazardous waste. 261.10 Section 261.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION AND LISTING OF HAZARDOUS WASTE Criteria for Identifying the Characteristics of Hazardous Waste and for Listing Hazardous Waste § 261.10 Criteria for...

40 CFR 261.10 - Criteria for identifying the characteristics of hazardous waste.

Code of Federal Regulations, 2010 CFR

2010-07-01

... characteristics of hazardous waste. 261.10 Section 261.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION AND LISTING OF HAZARDOUS WASTE Criteria for Identifying the Characteristics of Hazardous Waste and for Listing Hazardous Waste § 261.10 Criteria for...

40 CFR 261.10 - Criteria for identifying the characteristics of hazardous waste.

Code of Federal Regulations, 2011 CFR

2011-07-01

... characteristics of hazardous waste. 261.10 Section 261.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION AND LISTING OF HAZARDOUS WASTE Criteria for Identifying the Characteristics of Hazardous Waste and for Listing Hazardous Waste § 261.10 Criteria for...

40 CFR 265.382 - Open burning; waste explosives.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 27 2013-07-01 2013-07-01 false Open burning; waste explosives. 265... DISPOSAL FACILITIES Thermal Treatment § 265.382 Open burning; waste explosives. Open burning of hazardous waste is prohibited except for the open burning and detonation of waste explosives. Waste explosives...

40 CFR 265.382 - Open burning; waste explosives.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 40 Protection of Environment 26 2014-07-01 2014-07-01 false Open burning; waste explosives. 265... DISPOSAL FACILITIES Thermal Treatment § 265.382 Open burning; waste explosives. Open burning of hazardous waste is prohibited except for the open burning and detonation of waste explosives. Waste explosives...

40 CFR 265.382 - Open burning; waste explosives.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 25 2010-07-01 2010-07-01 false Open burning; waste explosives. 265... DISPOSAL FACILITIES Thermal Treatment § 265.382 Open burning; waste explosives. Open burning of hazardous waste is prohibited except for the open burning and detonation of waste explosives. Waste explosives...