Science.gov

Sample records for esfahan fuel production

  1. Farmers' Learning Strategies in the Province of Esfahan

    ERIC Educational Resources Information Center

    Karbasioun, Mostafa; Biemans, Harm; Mulder, Martin

    2008-01-01

    This study was designed to investigate changes in farming and to look at how farmers adapt to diverse changes in and around their farms in the province of Esfahan, Iran. It is part of a larger project aimed at developing a job competency profile for agricultural extension instructors (AEIs). One hundred and two farmers who had previously followed…

  2. Fuel from microalgae lipid products

    SciTech Connect

    Hill, A.M.; Feinberg, D.A.

    1984-04-01

    The large-scale production of microalgae is a promising method of producing a renewable feedstock for a wide variety of fuel products currently refined from crude petroleum. These microalgae-derived products include lipid extraction products (triglycerides, fatty acids, and hydrocarbons) and catalytic conversion products (paraffins and olefins). Microalgal biomass productivity and lipid composition of current experimental systems are estimated at 66.0 metric tons per hectare year and 30% lipid content. Similar yields in a large-scale facility indicate that production costs are approximately six times higher than the average domestic price for crude, well-head petroleum. Based on achievable targets for productivity and production costs, the potential for microalgae as a fuel feedstock is presented in context with selected process refining routes and is compared with conventional and alternative feedstocks (e.g., oilseeds) with which microalgae must compete. 24 references, 9 figures, 4 tables.

  3. Grain production for alcohol fuels

    SciTech Connect

    Lockeretz, W.

    1980-05-01

    This report provides primarily an assessment of the resource base for producing alcohol fuel from grain. The effect of different levels of alcohol production are discussed with respect to farm income, land conservation practices, food prices, and exports. The economics of ethanol production from the standpoint of feedstock availability and price are comprehensively examined.

  4. Fuel ethanol production in Brazil

    SciTech Connect

    Macedo, I.C.

    1993-12-31

    The Brazilian ethanol from sugar cane program is the largest commercial liquid fuel from biomass system in operation today, with a production of 12 million m{sup 3} ethanol/year. During its 15 years of existence many issues were considered, under varying economic and strategic conditions. An overview is presented of the program development, present situation and main trends. Main subjects are technology development and implementation, costs, environmental benefits and constraints, and social/institutional issues. Is shown that the debate over the program has led to a sound knowledge on key issues (energy and CO{sub 2} balance, technology level and cost reduction, agricultural mechanization and job creation, land utilization, urban-air pollution effects, ethanol distribution, blending and use in dedicated engines.) With this basic knowledge some trends for the near future are considered (gains in productivity/conversion efficiency and cost implications; change to unburnt cane harvesting and technology development for cane trash conversion).

  5. The Esfahan Seminar: Report of a Regional Seminar on Functional Literacy and Family Planning Education.

    ERIC Educational Resources Information Center

    Burgess, Linda, Comp.

    This report summarizes the discussion emerging from the issues raised at the Esfahan Seminar on Functional Literacy and Family Planning Education. It is divided into six chapters. Chapter I describes the seminar design, pointing out that it was structured to fulfill the major purposes of the Seminar, one of which was to help each participating…

  6. Fuel cell electric power production

    DOEpatents

    Hwang, Herng-Shinn; Heck, Ronald M.; Yarrington, Robert M.

    1985-01-01

    A process for generating electricity from a fuel cell includes generating a hydrogen-rich gas as the fuel for the fuel cell by treating a hydrocarbon feed, which may be a normally liquid feed, in an autothermal reformer utilizing a first monolithic catalyst zone having palladium and platinum catalytic components therein and a second, platinum group metal steam reforming catalyst. Air is used as the oxidant in the hydrocarbon reforming zone and a low oxygen to carbon ratio is maintained to control the amount of dilution of the hydrogen-rich gas with nitrogen of the air without sustaining an insupportable amount of carbon deposition on the catalyst. Anode vent gas may be utilized as the fuel to preheat the inlet stream to the reformer. The fuel cell and the reformer are preferably operated at elevated pressures, up to about a pressure of 150 psia for the fuel cell.

  7. [Fuel ethanol production from cassava feedstock].

    PubMed

    Huang, Ribo; Chen, Dong; Wang, Qingyan; Shen, Naikun; Wei, Yutuo; Du, Liqin

    2010-07-01

    The regions suitable for growing cassava include five provinces in Southern China, with Guangxi alone accounting for over 65% of the total cassava production in the country. In this article, the state-of-the-art development of fuel ethanol production from cassava in China is illustrated by the construction of the cassava fuel ethanol plant with its annual production capacity of 200 000 metric tons. And in the meantime, problems and challenges encountered in the development of China's cassava fuel ethanol are highlighted and the strategies to address them are proposed.

  8. Composition and methods for improved fuel production

    SciTech Connect

    Steele, Philip H.; Tanneru, Sathishkumar; Gajjela, Sanjeev K.

    2015-12-29

    Certain embodiments of the present invention are configured to produce boiler and transportation fuels. A first phase of the method may include oxidation and/or hyper-acidification of bio-oil to produce an intermediate product. A second phase of the method may include catalytic deoxygenation, esterification, or olefination/esterification of the intermediate product under pressurized syngas. The composition of the resulting product--e.g., a boiler fuel--produced by these methods may be used directly or further upgraded to a transportation fuel. Certain embodiments of the present invention also include catalytic compositions configured for use in the method embodiments.

  9. Engineering organisms for industrial fuel production.

    PubMed

    Berry, David A

    2010-01-01

    Volatile fuel costs, the need to reduce greenhouse gas emissions and fuel security concerns are driving efforts to produce sustainable renewable fuels and chemicals. Petroleum comes from sunlight, CO(2) and water converted via a biological intermediate into fuel over a several million year timescale. It stands to reason that using biology to short-circuit this time cycle offers an attractive alternative--but only with relevant products at or below market prices. The state of the art of biological engineering over the past five years has progressed to allow for market needs to drive innovation rather than trying to adapt existing approaches to the market. This report describes two innovations using synthetic biology to dis-intermediate fuel production. LS9 is developing a means to convert biological intermediates such as cellulosic hydrolysates into drop-in hydrocarbon product replacements such as diesel. Joule Unlimited is pioneering approaches to eliminate feedstock dependency by efficiently capturing sunlight, CO(2) and water to produce fuels and chemicals. The innovations behind these companies are built with the market in mind, focused on low cost biosynthesis of existing products of the petroleum industry. Through successful deployment of technologies such as those behind LS9 and Joule Unlimited, alternative sources of petroleum products will mitigate many of the issues faced with our petroleum-based economy.

  10. Engineering organisms for industrial fuel production.

    PubMed

    Berry, David A

    2010-01-01

    Volatile fuel costs, the need to reduce greenhouse gas emissions and fuel security concerns are driving efforts to produce sustainable renewable fuels and chemicals. Petroleum comes from sunlight, CO(2) and water converted via a biological intermediate into fuel over a several million year timescale. It stands to reason that using biology to short-circuit this time cycle offers an attractive alternative--but only with relevant products at or below market prices. The state of the art of biological engineering over the past five years has progressed to allow for market needs to drive innovation rather than trying to adapt existing approaches to the market. This report describes two innovations using synthetic biology to dis-intermediate fuel production. LS9 is developing a means to convert biological intermediates such as cellulosic hydrolysates into drop-in hydrocarbon product replacements such as diesel. Joule Unlimited is pioneering approaches to eliminate feedstock dependency by efficiently capturing sunlight, CO(2) and water to produce fuels and chemicals. The innovations behind these companies are built with the market in mind, focused on low cost biosynthesis of existing products of the petroleum industry. Through successful deployment of technologies such as those behind LS9 and Joule Unlimited, alternative sources of petroleum products will mitigate many of the issues faced with our petroleum-based economy. PMID:21326829

  11. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect

    H.C. Maru; M. Farooque

    2004-08-01

    The ongoing program is designed to advance the carbonate fuel cell technology from full-size proof-of-concept field test to the commercial design. DOE has been funding Direct FuelCell{reg_sign} (DFC{reg_sign}) development at FuelCell Energy, Inc. (FCE) for stationary power plant applications. The program efforts are focused on technology and system optimization for cost reduction, leading to commercial design development and prototype system field trials. FCE, Danbury, CT, is a world-recognized leader for the development and commercialization of high efficiency fuel cells that can generate clean electricity at power stations, or at distributed locations near the customers such as hospitals, schools, universities, hotels and other commercial and industrial applications. FCE has designed three different fuel cell power plant models (DFC300A, DFC1500 and DFC3000). FCE's power plants are based on its patented DFC{reg_sign} technology, where the fuel is directly fed to the fuel cell and hydrogen is generated internally. These power plants offer significant advantages compared to the existing power generation technologies--higher fuel efficiency, significantly lower emissions, quieter operation, flexible siting and permitting requirements, scalability and potentially lower operating costs. Also, the exhaust heat by-product can be used for cogeneration applications such as high-pressure steam, district heating and air conditioning. Several FCE sub-megawatt power plants are currently operating in Europe, Japan and the US. Because hydrogen is generated directly within the fuel cell module from readily available fuels such as natural gas and waste water treatment gas, DFC power plants are ready today and do not require the creation of a hydrogen infrastructure. Product improvement progress made during the reporting period in the areas of technology, manufacturing processes, cost reduction and balance of plant equipment designs is discussed in this report.

  12. Spent nuclear fuel project product specification

    SciTech Connect

    Pajunen, A.L.

    1998-01-30

    Product specifications are limits and controls established for each significant parameter that potentially affects safety and/or quality of the Spent Nuclear Fuel (SNF) packaged for transport to dry storage. The product specifications in this document cover the spent fuel packaged in MultiCanister Overpacks (MCOs) to be transported throughout the SNF Project. The SNF includes N Reactor fuel and single-pass reactor fuel. The FRS removes the SNF from the storage canisters, cleans it, and places it into baskets. The MCO loading system places the baskets into MCO/Cask assembly packages. These packages are then transferred to the Cold Vacuum Drying (CVD) Facility. After drying at the CVD Facility, the MCO cask packages are transferred to the Canister Storage Building (CSB), where the MCOs are removed from the casks, staged, inspected, sealed (by welding), and stored until a suitable permanent disposal option is implemented. The key criteria necessary to achieve these goals are documented in this specification.

  13. Fuel production potential of several agricultural crops

    SciTech Connect

    Mays, D.A.; Buchanan, W.; Bradford, B.N.

    1984-11-01

    Data collected on starch and sugar crops indicate that sweet potato and sweet sorghum have the best potential for alcohol production in the TVA area. Of the oil crops evaluated in this series of experiments only sunflower and okara appear to offer potential in the Tennessee Valley for oil production for fuel or other uses. 21 tabs.

  14. Alcohol fuel production training program. Final report

    SciTech Connect

    Burke, J.

    1982-06-30

    The purpose of the project was to offer instruction in the small scale production of ethanol, which can be added to gasoline by about 10%. The course was designed to help farmers in particular to make ethanol to extend fuel use. This project has four objectives. They are: (1) design an alcohol fuel production course with appropriate equipment for hands-on training; (2) offer at least three training sessions on alcohol fuel production in Cumberland County each year of the project; (3) work with the Governor's Task Force on Gasohol to disseminate the necessary information on alcohol production to the public; (4) identify, in consultation with the New Jersey Department of Energy and Agriculture, other training sites in the state and offer at least three training sessions outside of Cumberland County during the second year of the project. As of March 31, 1982, Cumberland County College completed all activities and objectives outlined in its Appropriate Technology project ''Alcohol Fuel Production.'' Given the six month extension requested to accommodate farmers in other parts of the state and the growing season, this project was completed within the stated time schedule. Although the response for the course was high in the beginning of 1981, the increased supply of low cost fuels at the end of the year probably accounts for the decline in the public's willingness to take a course of this nature.

  15. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect

    H. C. Maru; M. Farooque

    2003-12-19

    The ongoing program is designed to advance the carbonate fuel cell technology from full-size proof-of-concept field test to the commercial design. DOE has been funding Direct FuelCell{reg_sign} (DFC{reg_sign}) development at FuelCell Energy, Inc. (FCE) for stationary power plant applications. The program efforts are focused on technology and system optimization for cost reduction leading to commercial design development and prototype system field trials. FCE, Danbury, CT, is a world-recognized leader for the development and commercialization of high efficiency fuel cells that can generate clean electricity at power stations or in distributed locations near the customer, including hospitals, schools, universities, hotels and other commercial and industrial applications. FuelCell Energy has designed three different fuel cell power plant models (DFC300, DFC1500 and DFC3000). FCE's power plants are based on its patented Direct FuelCell technology, where the fuel is directly fed to fuel cell and hydrogen is generated internally. These power plants offer significant advantages compared to existing power generation technologies--higher fuel efficiency, significantly lower emissions, quieter operation, flexible siting and permitting requirements, scalability and potentially lower operating costs. Also, the exhaust heat by-product can be used for cogeneration applications such as high-pressure steam, district heating, and air conditioning. Several FCE sub-megawatt power plants are currently operating in Europe, Japan and the US. Because hydrogen is generated directly within the fuel cell module from readily available fuels such as natural gas and waste water treatment gas, DFC power plants are ready today and do not require the creation of a hydrogen infrastructure. Product improvement progress made during the reporting period in the areas of technology, manufacturing processes, cost reduction and balance of plant equipment designs is discussed in this report. FCE's DFC

  16. Engineering cyanobacteria for fuels and chemicals production.

    PubMed

    Zhou, Jie; Li, Yin

    2010-03-01

    The world's energy and global warming crises call for sustainable, renewable, carbon-neutral alternatives to replace fossil fuel resources. Currently, most biofuels are produced from agricultural crops and residues, which lead to concerns about food security and land shortage. Compared to the current biofuel production system, cyanobacteria, as autotrophic prokaryotes, do not require arable land and can grow to high densities by efficiently using solar energy, CO(2), water, and inorganic nutrients. Moreover, powerful genetic techniques of cyanobacteria have been developed. For these reasons, cyanobacteria, which carry out oxygenic photosynthesis, are attractive hosts for production of fuels and chemicals. Recently, several chemicals including ethanol, isobutanol and isoprene have been produced by engineered cyanobacteria directly using solar energy, CO(2), and water. Cyanobacterium is therefore a potential novel cell factory for fuels and chemicals production to address global energy security and climate change issues.

  17. Engineering cyanobacteria for fuels and chemicals production.

    PubMed

    Zhou, Jie; Li, Yin

    2010-03-01

    The world's energy and global warming crises call for sustainable, renewable, carbon-neutral alternatives to replace fossil fuel resources. Currently, most biofuels are produced from agricultural crops and residues, which lead to concerns about food security and land shortage. Compared to the current biofuel production system, cyanobacteria, as autotrophic prokaryotes, do not require arable land and can grow to high densities by efficiently using solar energy, CO(2), water, and inorganic nutrients. Moreover, powerful genetic techniques of cyanobacteria have been developed. For these reasons, cyanobacteria, which carry out oxygenic photosynthesis, are attractive hosts for production of fuels and chemicals. Recently, several chemicals including ethanol, isobutanol and isoprene have been produced by engineered cyanobacteria directly using solar energy, CO(2), and water. Cyanobacterium is therefore a potential novel cell factory for fuels and chemicals production to address global energy security and climate change issues. PMID:21203966

  18. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect

    H.C. Maru; M. Farooque

    2002-02-01

    generation, industrial cogeneration, marine applications and uninterrupted power for military bases. FuelCell Energy operated a 1.8 MW plant at a utility site in 1996-97, the largest fuel cell power plant ever operated in North America. This proof-of-concept power plant demonstrated high efficiency, low emissions, reactive power control, and unattended operation capabilities. Drawing on the manufacture, field test, and post-test experience of the full-size power plant; FuelCell Energy launched the Product Design Improvement (PDI) program sponsored by government and the private-sector cost-share. The PDI efforts are focused on technology and system optimization for cost reduction, commercial design development, and prototype system field trials. The program was initiated in December 1994. Year 2000 program accomplishments are discussed in this report.

  19. Production of chemicals and fuels from biomass

    SciTech Connect

    Woods, Elizabeth; Qiao, Ming; Myren, Paul; Cortright, Randy D.; Kania, John

    2015-12-15

    Described are methods, reactor systems, and catalysts for converting biomass to fuels and chemicals in a batch and/or continuous process. The process generally involves the conversion of water insoluble components of biomass, such as hemicellulose, cellulose and lignin, to volatile C.sub.2+O.sub.1-2 oxygenates, such as alcohols, ketones, cyclic ethers, esters, carboxylic acids, aldehydes, and mixtures thereof. In certain applications, the volatile C.sub.2+O.sub.1-2 oxygenates can be collected and used as a final chemical product, or used in downstream processes to produce liquid fuels, chemicals and other products.

  20. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect

    H.C. Maru; M. Farooque

    2003-03-01

    The program efforts are focused on technology and system optimization for cost reduction, commercial design development, and prototype system field trials. The program is designed to advance the carbonate fuel cell technology from full-size field test to the commercial design. FuelCell Energy, Inc. (FCE) is in the later stage of the multiyear program for development and verification of carbonate fuel cell based power plants supported by DOE/NETL with additional funding from DOD/DARPA and the FuelCell Energy team. FCE has scaled up the technology to full-size and developed DFC{reg_sign} stack and balance-of-plant (BOP) equipment technology to meet product requirements, and acquired high rate manufacturing capabilities to reduce cost. FCE has designed submegawatt (DFC300A) and megawatt (DFC1500 and DFC3000) class fuel cell products for commercialization of its DFC{reg_sign} technology. A significant progress was made during the reporting period. The reforming unit design was optimized using a three-dimensional stack simulation model. Thermal and flow uniformities of the oxidant-In flow in the stack module were improved using computational fluid dynamics based flow simulation model. The manufacturing capacity was increased. The submegawatt stack module overall cost was reduced by {approx}30% on a per kW basis. An integrated deoxidizer-prereformer design was tested successfully at submegawatt scale using fuels simulating digester gas, coal bed methane gas and peak shave (natural) gas.

  1. Risk factors of jet fuel combustion products.

    PubMed

    Tesseraux, Irene

    2004-04-01

    Air travel is increasing and airports are being newly built or enlarged. Concern is rising about the exposure to toxic combustion products in the population living in the vicinity of large airports. Jet fuels are well characterized regarding their physical and chemical properties. Health effects of fuel vapors and liquid fuel are described after occupational exposure and in animal studies. Rather less is known about combustion products of jet fuels and exposure to those. Aircraft emissions vary with the engine type, the engine load and the fuel. Among jet aircrafts there are differences between civil and military jet engines and their fuels. Combustion of jet fuel results in CO2, H2O, CO, C, NOx, particles and a great number of organic compounds. Among the emitted hydrocarbons (HCs), no compound (indicator) characteristic for jet engines could be detected so far. Jet engines do not seem to be a source of halogenated compounds or heavy metals. They contain, however, various toxicologically relevant compounds including carcinogenic substances. A comparison between organic compounds in the emissions of jet engines and diesel vehicle engines revealed no major differences in the composition. Risk factors of jet engine fuel exhaust can only be named in context of exposure data. Using available monitoring data, the possibilities and limitations for a risk assessment approach for the population living around large airports are presented. The analysis of such data shows that there is an impact on the air quality of the adjacent communities, but this impact does not result in levels higher than those in a typical urban environment.

  2. Risk factors of jet fuel combustion products.

    PubMed

    Tesseraux, Irene

    2004-04-01

    Air travel is increasing and airports are being newly built or enlarged. Concern is rising about the exposure to toxic combustion products in the population living in the vicinity of large airports. Jet fuels are well characterized regarding their physical and chemical properties. Health effects of fuel vapors and liquid fuel are described after occupational exposure and in animal studies. Rather less is known about combustion products of jet fuels and exposure to those. Aircraft emissions vary with the engine type, the engine load and the fuel. Among jet aircrafts there are differences between civil and military jet engines and their fuels. Combustion of jet fuel results in CO2, H2O, CO, C, NOx, particles and a great number of organic compounds. Among the emitted hydrocarbons (HCs), no compound (indicator) characteristic for jet engines could be detected so far. Jet engines do not seem to be a source of halogenated compounds or heavy metals. They contain, however, various toxicologically relevant compounds including carcinogenic substances. A comparison between organic compounds in the emissions of jet engines and diesel vehicle engines revealed no major differences in the composition. Risk factors of jet engine fuel exhaust can only be named in context of exposure data. Using available monitoring data, the possibilities and limitations for a risk assessment approach for the population living around large airports are presented. The analysis of such data shows that there is an impact on the air quality of the adjacent communities, but this impact does not result in levels higher than those in a typical urban environment. PMID:15093276

  3. Spent Nuclear Fuel (SNF) Project Product Specification

    SciTech Connect

    PAJUNEN, A.L.

    2000-01-20

    This document establishes the limits and controls for the significant parameters that could potentially affect the safety and/or quality of the Spent Nuclear Fuel (SNF) packaged for processing, transport, and storage. The product specifications in this document cover the SNF packaged in Multi-Canister Overpacks to be transported throughout the SNF Project.

  4. Fission-product retention in HTGR fuels

    SciTech Connect

    Homan, F.J.; Kania, M.J.; Tiegs, T.N.

    1982-01-01

    Retention data for gaseous and metallic fission products are presented for both Triso-coated and Biso-coated HTGR fuel particles. Performance trends are established that relate fission product retention to operating parameters, such as temperature, burnup, and neutron exposure. It is concluded that Biso-coated particles are not adequately retentive of fission gas or metallic cesium, and Triso-coated particles which retain cesium still lose silver. Design implications related to these performance trends are identified and discussed.

  5. Direct fuel cell product design improvement

    SciTech Connect

    Maru, H.C.; Farooque, M.

    1996-12-31

    Significant milestones have been attained towards the technology development field testing and commercialization of direct fuel cell power plant since the 1994 Fuel Cell Seminar. Under a 5-year cooperative agreement with the Department of Energy signed in December 1994, Energy Research Corporation (ERC) has been developing the design for a MW-scale direct fuel cell power plant with input from previous technology efforts and the Santa Clara Demonstration Project. The effort encompasses product definition in consultation with the Fuel Cell Commercialization Group, potential customers, as well as extensive system design and packaging. Manufacturing process improvements, test facility construction, cell component scale up, performance and endurance improvements, stack engineering, and critical balance-of-plant development are also addressed. Major emphasis of this product design improvement project is on increased efficiency, compactness and cost reduction to establish a competitive place in the market. A 2.85 MW power plant with an efficiency of 58% and a footprint of 420 m{sup 2} has been designed. Component and subsystem testing is being conducted at various levels. Planning and preparation for verification of a full size prototype unit are in progress. This paper presents the results obtained since the last fuel cell seminar.

  6. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect

    H.C. Maru; M. Farooque

    2005-03-01

    The program was designed to advance the carbonate fuel cell technology from full-size proof-of-concept field test to the commercial design. DOE has been funding Direct FuelCell{reg_sign} (DFC{reg_sign}) development at FuelCell Energy, Inc. (FCE, formerly Energy Research Corporation) from an early state of development for stationary power plant applications. The current program efforts were focused on technology and system development, and cost reduction, leading to commercial design development and prototype system field trials. FCE, in Danbury, CT, is a world-recognized leader for the development and commercialization of high efficiency fuel cells that can generate clean electricity at power stations, or at distributed locations near the customers such as hospitals, schools, universities, hotels and other commercial and industrial applications. FCE has designed three different fuel cell power plant models (DFC300A, DFC1500 and DFC3000). FCE's power plants are based on its patented DFC{reg_sign} technology, where a hydrocarbon fuel is directly fed to the fuel cell and hydrogen is generated internally. These power plants offer significant advantages compared to the existing power generation technologies--higher fuel efficiency, significantly lower emissions, quieter operation, flexible siting and permitting requirements, scalability and potentially lower operating costs. Also, the exhaust heat by-product can be used for cogeneration applications such as high-pressure steam, district heating and air conditioning. Several sub-MW power plants based on the DFC design are currently operating in Europe, Japan and the US. Several one-megawatt power plant design was verified by operation on natural gas at FCE. This plant is currently installed at a customer site in King County, WA under another US government program and is currently in operation. Because hydrogen is generated directly within the fuel cell module from readily available fuels such as natural gas and waste

  7. Course Experiences and Perceptions of Farmers in Esfahan as a Basis for a Competency Profile of Extension Instructors

    ERIC Educational Resources Information Center

    Karbasioun, Mostafa; Mulder, Martin; Biemans, Harm

    2007-01-01

    The purpose of this study was to analyze farmers' experiences with and perceptions of agricultural extension courses and their instructors in Esfahan, Iran. This study is part of a larger project on the development of a competency profile of extension instructors. Many attempts have been made to develop competency profiles for professionals (Shim,…

  8. Bioethanol Fuel Production Concept Study: Topline Report

    SciTech Connect

    Marketing Horizons, Inc.

    2001-11-19

    The DOE is in the process of developing technologies for converting plant matter other than feed stock, e.g., corn stover, into biofuels. The goal of this research project was to determine what the farming community thinks of ethanol as a fuel source, and specifically what they think of bioethanol produced from corn stover. This project also assessed the image of the DOE and the biofuels program and determined the perceived barriers to ethanol-from-stover production.

  9. Inspection procedures for experimental fuel production

    NASA Astrophysics Data System (ADS)

    Campsie, I. C.; Rattray, H. D.

    1988-04-01

    This paper describes the inspection procedures used in the development and manufacture of experimental fuel elements and their components. The examples quoted mainly apply to the PFR experimental fuel programme, although for well over a quarter of a century the procedures and techniques have been progressively developed and applied to the Magnox, SGHW, AGR, HTR, PFR and PWR fuel development programmes undertaken at the UKAEA's Springfields and Windscale Nuclear Power Development Laboratories. In contrast to production runs involving large numbers of standard components, experimental fuel is often assembled from components which, while they may look alike, may have design and material variations. Thus in addition to normal batching and bonding operations, great emphasis has to be placed on dimensional inspection, material testing and the individual identification of all items, thus maintaining traceability throughout all operations. The quality and performance of experimental items are often evaluated comparing pre- and post-test dimensional or NDT measurements. In the case of irradiation tests, several years can elapse between the measurements, therefore it is essential to ensure the reproducibility and compatibility of pre- and post-test measuring techniques and the traceability of all measured data and standards.

  10. Dimethyl carbonate production for fuel additives

    SciTech Connect

    Okada, Y.; Kondo, T.; Asaoka, S.

    1996-12-31

    We have taken note of the transesterification reaction as a highly safe process of dimethyl carbonate (DMC) production for fuel additives. The reaction proceeds under the low corrosiveness and in the relatively mild condition. We have aimed to use an inorganic solid catalyst for this process. The inorganic solid catalyst is thermally stable and can be used in the large-scale fixed bed reactors without a catalyst separation unit. Through the transesterification of ethylene carbonate (EG) with methanol, DMC and ethylene glycol (EG) are co-generated as the products. EG is one of the bulk chemicals produced in the large scale plant comparable to one for the fuel additives. The market balance is important in the coproduction process. On the assumption that the amount of the co-production meets the market balance, the coproduction of DMC and EG is commercially viable. If we can control the amount of the EG coproduction in this process, it makes the process more flexible in the commercial production. Accordingly we have proposed a conceptual process scheme to control the amount of the EG coproduction. In this symposium, the inorganic solid catalyst system applying to the transesterification process and the conceptual process scheme how to control the amount of co-product will be discussed.

  11. Renewable hydrogen production for fossil fuel processing

    SciTech Connect

    Greenbaum, E.

    1994-09-01

    The objective of this mission-oriented research program is the production of renewable hydrogen for fossil fuel processing. This program will build upon promising results that have been obtained in the Chemical Technology Division of Oak Ridge National Laboratory on the utilization of intact microalgae for photosynthetic water splitting. In this process, specially adapted algae are used to perform the light-activated cleavage of water into its elemental constituents, molecular hydrogen and oxygen. The great potential of hydrogen production by microalgal water splitting is predicated on quantitative measurement of their hydrogen-producing capability. These are: (1) the photosynthetic unit size of hydrogen production; (2) the turnover time of photosynthetic hydrogen production; (3) thermodynamic efficiencies of conversion of light energy into the Gibbs free energy of molecular hydrogen; (4) photosynthetic hydrogen production from sea water using marine algae; (5) the original development of an evacuated photobiological reactor for real-world engineering applications; (6) the potential for using modern methods of molecular biology and genetic engineering to maximize hydrogen production. The significance of each of these points in the context of a practical system for hydrogen production is discussed. This program will be enhanced by collaborative research between Oak Ridge National Laboratory and senior faculty members at Duke University, the University of Chicago, and Iowa State University. The special contribution that these organizations and faculty members will make is access to strains and mutants of unicellular algae that will potentially have useful properties for hydrogen production by microalgal water splitting.

  12. Traversing the mountaintop: world fossil fuel production to 2050.

    PubMed

    Nehring, Richard

    2009-10-27

    During the past century, fossil fuels--petroleum liquids, natural gas and coal--were the dominant source of world energy production. From 1950 to 2005, fossil fuels provided 85-93% of all energy production. All fossil fuels grew substantially during this period, their combined growth exceeding the increase in world population. This growth, however, was irregular, providing for rapidly growing per capita production from 1950 to 1980, stable per capita production from 1980 to 2000 and rising per capita production again after 2000. During the past half century, growth in fossil fuel production was essentially limited by energy demand. During the next half century, fossil fuel production will be limited primarily by the amount and characteristics of remaining fossil fuel resources. Three possible scenarios--low, medium and high--are developed for the production of each of the fossil fuels to 2050. These scenarios differ primarily by the amount of ultimate resources estimated for each fossil fuel. Total fossil fuel production will continue to grow, but only slowly for the next 15-30 years. The subsequent peak plateau will last for 10-15 years. These production peaks are robust; none of the fossil fuels, even with highly optimistic resource estimates, is projected to keep growing beyond 2050. World fossil fuel production per capita will thus begin an irreversible decline between 2020 and 2030.

  13. Photocatalytic semiconductor clusters for fuel production

    SciTech Connect

    Wilcoxon, J.P.; Bliss, D.E.; Martin, J.E.

    1995-10-01

    High quality crystalline, monodisperse nanometer-size semiconductor clusters were successfully grown using an inverse micellar synthesis process and their optical and structural properties were studied. Among the materials studied were PbS, FeS{sub 2}, MoS{sub 2}, CdS and related compounds. The results demonstrated strong electronic quantum confinement effects and broad tailorability of the bandgaps with decreasing cluster size, features that are important for the potential use of these materials as photocatalysts for solar fuel production and solar detoxification. The highlights of the work are included in an Executive Summary.

  14. Spent Nuclear Fuel (SNF) Project Product Specification

    SciTech Connect

    PAJUNEN, A.L.

    2000-12-07

    The process for removal of Spent Nuclear Fuel (SNF) from the K Basins has been divided into major sub-systems. The Fuel Retrieval System (FRS) removes fuel from the existing storage canisters, cleans it, and places it into baskets. The multi-canister overpack (MCO) loading system places the baskets into an MCO that has been pre-loaded in a cask. The cask, containing a loaded MCO, is then transferred to the Cold Vacuum Drying (CVD) Facility. After drying at the CVD Facility, the cask, and MCO, are transferred to the Canister Storage Building (CSB), where the MCO is removed from the cask, staged, inspected, sealed (by welding), and stored until a suitable permanent disposal option is implemented. The purpose of this document is to specify the process related characteristics of an MCO at the interface between major process systems. The characteristics are derived from the primary technical documents that form the basis for safety analysis and design calculations. This document translates the calculation assumptions into implementation requirements and describes the method of verifying that the requirement is achieved. These requirements are used to define validation test requirements and describe requirements that influence multiple sub-project safety analysis reports. This product specification establishes limits and controls for each significant process parameter at interfaces between major sub-systems that potentially affect the overall safety and/or quality of the SNF packaged for processing, transport, and interim dry storage. The product specifications in this document cover the SNF packaged in MCOs to be transported throughout the SNF Project. The description of the product specifications are organized in the document as follows: Section 2.0--Summary listing of product specifications at each major sub-system interface. Section 3.0--Summary description providing guidance as to how specifications are complied with by equipment design or processing within a major

  15. Biological production of liquid fuels from biomass

    SciTech Connect

    1982-01-01

    A scheme for the production of liquid fuels from renewable resources such as poplar wood and lignocellulosic wastes from a refuse hydropulper was investigated. The particular scheme being studied involves the conversion of a cellulosic residue, resulting from a solvent delignified lignocellulosic feed, into either high concentration sugar syrups or into ethyl and/or butyl alcohol. The construction of a pilot apparatus for solvent delignifying 150 g samples of lignocellulosic feeds was completed. Also, an analysis method for characterizing the delignified product has been selected and tested. This is a method recommended in the Forage Fiber Handbook. Delignified samples are now being prepared and tested for their extent of delignification and susceptibility to enzyme hydrolysis. Work is continuing on characterizing the cellulase and cellobiase enzyme systems derived from the YX strain of Thermomonospora.

  16. Hydrogen fuel production by transgenic microalgae.

    PubMed

    Melis, Anastasios; Seibert, Michael; Ghirardi, Maria L

    2007-01-01

    This chapter summarizes the state-of-art in the field of green algal H2-production and examines physiological and genetic engineering approaches by which to improve the hydrogen metabolism characteristics of these microalgae. Included in this chapter are emerging topics pertaining to the application of sulfur-nutrient deprivation to attenuate O2-evolution and to promote H2-production, as well as the genetic engineering of sulfate uptake through manipulation of a newly reported sulfate permease in the chloroplast of the model green alga Chlamydomonas reinhardtii. Application of the green algal hydrogenase assembly genes is examined in efforts to confer H2-production capacity to other commercially significant unicellular green algae. Engineering a solution to the O2 sensitivity of the green algal hydrogenase is discussed as an alternative approach to sulfur nutrient deprivation, along with starch accumulation in microalgae for enhanced H2-production. Lastly, current efforts aiming to optimize light utilization in transgenic microalgae for enhanced H2-production under mass culture conditions are presented. It is evident that application of genetic engineering technologies and the use of transgenic green algae will improve prospects for commercial exploitation of these photosynthetic micro-organisms in the generation of H2, a clean and renewable fuel. PMID:18161495

  17. Genetically Modified Bacteria for Fuel Production: Development of Rhodobacteria as a Versatile Platform for Fuels Production

    SciTech Connect

    2010-07-01

    Electrofuels Project: Penn State is genetically engineering bacteria called Rhodobacter to use electricity or electrically generated hydrogen to convert carbon dioxide into liquid fuels. Penn State is taking genes from oil-producing algae called Botryococcus braunii and putting them into Rhodobacter to produce hydrocarbon molecules, which closely resemble gasoline. Penn State is developing engineered tanks to support microbial fuel production and determining the most economical way to feed the electricity or hydrogen to the bacteria, including using renewable sources of power like solar energy.

  18. Food, fuel, and feed production with microalgae

    SciTech Connect

    Benemann, J.R.; Weissman, J.C.

    1993-12-31

    Large-scale (>10 hectares) microalgae cultures are being used in several countries around the world for the production of human food supplements and specialty animal (mainly aquaculture) feeds. Microalgae cultures are also extensively used in wastewater treatment and being produced on a small scale for soil inoculants and diagnostic reagents. In addition, microalgae cultures are being investigated for their potential in fuel production and CO{sub 2} utilization, as a method for greenhouse gas mitigation. A pilot plant effort in New Mexico, under a US Department of Energy/National Renewable Energy Lab. subcontract, demonstrated the feasibility of cultivating a number of algal species in large outdoor ponds on brackish waters. Building on this experience, SeaAg, Inc. has developed a process for the mass culture of microalgae as a source of bivalve feeds. In this process, algae (diatoms) are cultured in large open ponds on seawater, and then fed to clams and oysters, which filter and convert the algal cells into high value protein. The SeaAg process is another application of a technology which promises to eventually result in large-scale commercial production of microalgae for a variety of useful products and processes.

  19. Artificial leaf device for solar fuel production.

    PubMed

    Amao, Yutaka; Shuto, Naho; Furuno, Kana; Obata, Asami; Fuchino, Yoshiko; Uemura, Keiko; Kajino, Tsutomu; Sekito, Takeshi; Iwai, Satoshi; Miyamoto, Yasushi; Matsuda, Masatoshi

    2012-01-01

    Solar fuels, such as hydrogen gas produced from water and methanol produced from carbon dioxide reduction by artificial photosynthesis, have received considerable attention. In natural leaves the photosynthetic proteins are well-organized in the thylakoid membrane. To develop an artificial leaf device for solar low-carbon fuel production from CO2, a chlorophyll derivative chlorin-e6 (Chl-e6; photosensitizer), 1-carboxylundecanoyl-1'-methyl-4,4'-bipyrizinium bromide, iodide (CH3V(CH2)9COOH; the electron carrier) and formate dehydrogenase (FDH) (the catalyst) immobilised onto a silica-gel-based thin layer chromatography plate (the Chl-V-FDH device) was investigated. From luminescence spectroscopy measurements, the photoexcited triplet state of Chl-e6 was quenched by the CH3V(CH2)9COOH moiety on the device, indicating the photoinduced electron transfer from the photoexcited triplet state of Chl-e6 to the CH3V(CH2)9COOH moiety. When the CO2-saturated sample solution containing NADPH (the electron donor) was flowed onto the Chl-V-FDH device under visible light irradiation, the formic acid concentration increased with increasing irradiation time.

  20. Photosynthetic terpene hydrocarbon production for fuels and chemicals

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Photosynthetic terpene production[ED1] represents an energy and carbon-efficient route for hydrocarbon fuel production. Diverse terpene structures also provide the potential to produce next-generation 'drop-in' hydrocarbon fuel molecules. However, it is highly challenging to achieve efficient redire...

  1. (Fuel, fission product, and graphite technology)

    SciTech Connect

    Stansfield, O.M.

    1990-07-25

    Travel to the Forschungszentrum (KFA) -- Juelich described in this report was for the purpose of participating in the annual meeting of subprogram managers for the US/DOE Umbrella Agreement for Fuel, Fission Product, and Graphite Technology. At this meeting the highlights of the cooperative exchange were reviewed for the time period June 1989 through June 1990. The program continues to contribute technology in an effective way for both countries. Revision 15 of the Subprogram Plan will be issued as a result of the meeting. There was interest expressed by KFA management in the level of support received from the NPR program and in potential participation in the COMEDIE loop experiment being conducted at the CEA.

  2. Biomass gasification for liquid fuel production

    SciTech Connect

    Najser, Jan E-mail: vaclav.peer@vsb.cz; Peer, Václav E-mail: vaclav.peer@vsb.cz

    2014-08-06

    In our old fix-bed autothermal gasifier we tested wood chips and wood pellets. We make experiments for Czech company producing agro pellets - pellets made from agricultural waste and fastrenewable natural resources. We tested pellets from wheat and rice straw and hay. These materials can be very perspective, because they dońt compete with food production, they were formed in sufficient quantity and in the place of their treatment. New installation is composed of allothermal biomass fixed bed gasifier with conditioning and using produced syngas for Fischer - Tropsch synthesis. As a gasifying agent will be used steam. Gas purification will have two parts - separation of dust particles using a hot filter and dolomite reactor for decomposition of tars. In next steps, gas will be cooled, compressed and removed of sulphur and chlorine compounds and carbon dioxide. This syngas will be used for liquid fuel synthesis.

  3. Biomass gasification for liquid fuel production

    NASA Astrophysics Data System (ADS)

    Najser, Jan; Peer, Václav; Vantuch, Martin

    2014-08-01

    In our old fix-bed autothermal gasifier we tested wood chips and wood pellets. We make experiments for Czech company producing agro pellets - pellets made from agricultural waste and fastrenewable natural resources. We tested pellets from wheat and rice straw and hay. These materials can be very perspective, because they dońt compete with food production, they were formed in sufficient quantity and in the place of their treatment. New installation is composed of allothermal biomass fixed bed gasifier with conditioning and using produced syngas for Fischer - Tropsch synthesis. As a gasifying agent will be used steam. Gas purification will have two parts - separation of dust particles using a hot filter and dolomite reactor for decomposition of tars. In next steps, gas will be cooled, compressed and removed of sulphur and chlorine compounds and carbon dioxide. This syngas will be used for liquid fuel synthesis.

  4. 10 CFR 490.8 - Replacement fuel production goal.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 10 Energy 3 2012-01-01 2012-01-01 false Replacement fuel production goal. 490.8 Section 490.8 Energy DEPARTMENT OF ENERGY ENERGY CONSERVATION ALTERNATIVE FUEL TRANSPORTATION PROGRAM General... sufficient to replace, on an energy equivalent basis, at least 30 percent of motor fuel consumption in...

  5. 10 CFR 490.8 - Replacement fuel production goal.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 10 Energy 3 2014-01-01 2014-01-01 false Replacement fuel production goal. 490.8 Section 490.8 Energy DEPARTMENT OF ENERGY ENERGY CONSERVATION ALTERNATIVE FUEL TRANSPORTATION PROGRAM General... sufficient to replace, on an energy equivalent basis, at least 30 percent of motor fuel consumption in...

  6. 10 CFR 490.8 - Replacement fuel production goal.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 10 Energy 3 2013-01-01 2013-01-01 false Replacement fuel production goal. 490.8 Section 490.8 Energy DEPARTMENT OF ENERGY ENERGY CONSERVATION ALTERNATIVE FUEL TRANSPORTATION PROGRAM General... sufficient to replace, on an energy equivalent basis, at least 30 percent of motor fuel consumption in...

  7. 10 CFR 490.8 - Replacement fuel production goal.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 10 Energy 3 2011-01-01 2011-01-01 false Replacement fuel production goal. 490.8 Section 490.8 Energy DEPARTMENT OF ENERGY ENERGY CONSERVATION ALTERNATIVE FUEL TRANSPORTATION PROGRAM General... sufficient to replace, on an energy equivalent basis, at least 30 percent of motor fuel consumption in...

  8. 10 CFR 490.8 - Replacement fuel production goal.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 3 2010-01-01 2010-01-01 false Replacement fuel production goal. 490.8 Section 490.8 Energy DEPARTMENT OF ENERGY ENERGY CONSERVATION ALTERNATIVE FUEL TRANSPORTATION PROGRAM General... sufficient to replace, on an energy equivalent basis, at least 30 percent of motor fuel consumption in...

  9. Exposure to occupational air pollution and cardiac function in workers of the Esfahan Steel Industry, Iran.

    PubMed

    Golshahi, Jafar; Sadeghi, Masoumeh; Saqira, Mohammad; Zavar, Reihaneh; Sadeghifar, Mostafa; Roohafza, Hamidreza

    2016-06-01

    Air pollution is recognized as an important risk factor for cardiovascular disease. We investigated association of exposure to occupational air pollution and cardiac function in the workers of the steel industry. Fifty male workers of the agglomeration and coke-making parts of the Esfahan Steel Company were randomly selected (n = 50). Workers in the administrative parts were studied as controls (n = 50). Those with known history of hypertension, dyslipidemia, or diabetes, and active smokers were not included. Data of age, body mass index, employment duration, blood pressure, fasting blood sugar, and lipid profile were gathered. Echocardiography was performed to evaluate cardiac function. Left ventricular ejection fraction was lower in workers of the agglomeration/coke-making parts than in controls (mean difference = 5 to 5.5 %, P < 0.001). Mild right ventricular dilatation and grade I pulmonary hypertension were present in three (12 %) workers of the coke-making part, but none of the controls (P = 0.010). According to these results, occupational air pollution exposure in workers of the steel industry is associated with left heart systolic dysfunction. Possible right heart insults due to air pollution exposure warrant further investigations. PMID:26946505

  10. Exposure to occupational air pollution and cardiac function in workers of the Esfahan Steel Industry, Iran.

    PubMed

    Golshahi, Jafar; Sadeghi, Masoumeh; Saqira, Mohammad; Zavar, Reihaneh; Sadeghifar, Mostafa; Roohafza, Hamidreza

    2016-06-01

    Air pollution is recognized as an important risk factor for cardiovascular disease. We investigated association of exposure to occupational air pollution and cardiac function in the workers of the steel industry. Fifty male workers of the agglomeration and coke-making parts of the Esfahan Steel Company were randomly selected (n = 50). Workers in the administrative parts were studied as controls (n = 50). Those with known history of hypertension, dyslipidemia, or diabetes, and active smokers were not included. Data of age, body mass index, employment duration, blood pressure, fasting blood sugar, and lipid profile were gathered. Echocardiography was performed to evaluate cardiac function. Left ventricular ejection fraction was lower in workers of the agglomeration/coke-making parts than in controls (mean difference = 5 to 5.5 %, P < 0.001). Mild right ventricular dilatation and grade I pulmonary hypertension were present in three (12 %) workers of the coke-making part, but none of the controls (P = 0.010). According to these results, occupational air pollution exposure in workers of the steel industry is associated with left heart systolic dysfunction. Possible right heart insults due to air pollution exposure warrant further investigations.

  11. Occupational Stress Among Male Employees of Esfahan Steel Company, Iran: Prevalence and Associated Factors

    PubMed Central

    Lotfizadeh, Masoud; Moazen, Babak; Habibi, Ehsan; Hassim, Noor

    2013-01-01

    Background: Lack of data on occupational stress among Iranian industrial employees persuaded us to design and conduct this study to evaluate the prevalence and associated parameters of occupational stress among male employees of the Esfahan Steel Company (ESCO), one of the biggest industrial units in Iran. Methods: In this cross-sectional study, 400 male employees were sampled from the operational divisions of the company. Socio-demographic data and stress-related variables were entered into a logistic regression to determine significant associated factors of occupational stress among the participants. Results: From all samples, 53% were found as stressful. A monthly salary of less than $600 (OR = 1.88, 95% confidence interval [CI] = 1.21-2.94), family-related problems (OR = 2.75, 95% CI = 1.22-6.21), work environment (OR = 3.09, 95% CI = 1.78-5.33) and having a second job (OR = 2.68, 95% CI = 1.78-6.78) were significantly associated with the outcome. Conclusions: Attention to some variables, especially economic problems and the work environment of employees, might play a protective role against the prevalence of occupational stress, not only among the employees of ESCO but also among all industrial employees in Iran. PMID:24049599

  12. Fission product release from irradiated LWR fuel under accident conditions

    SciTech Connect

    Strain, R.V.; Sanecki, J.E.; Osborne, M.F.

    1984-01-01

    Fission product release from irradiated LWR fuel is being studied by heating fuel rod segments in flowing steam and an inert carrier gas to simulate accident conditions. Fuels with a range of irradiation histories are being subjected to several steam flow rates over a wide range of temperatures. Fission product release during each test is measured by gamma spectroscopy and by detailed examination of the collection apparatus after the test has been completed. These release results are complemented by a detailed posttest examination of samples of the fuel rod segment. Results of release measurements and fuel rod characterizations for tests at 1400 through 2000/sup 0/C are presented in this paper.

  13. Coal liquefaction to increase jet fuel production

    NASA Technical Reports Server (NTRS)

    1979-01-01

    Processing concept that increases supply of jet fuel has been developed as part of study on methods for converting coal to hydrogen, methane, and jet fuel. Concept takes advantage of high aromatic content of coal-derived liquids to make high-octane gasoline, instead of destroying aromatics to make jet fuel.

  14. Ultraclean Fuels Production and Utilization for the Twenty-First Century: Advances toward Sustainable Transportation Fuels

    SciTech Connect

    Fox, Elise B.; Liu, Zhong-Wen; Liu, Zhao-Tie

    2013-11-21

    Ultraclean fuels production has become increasingly important as a method to help decrease emissions and allow the introduction of alternative feed stocks for transportation fuels. Established methods, such as Fischer-Tropsch, have seen a resurgence of interest as natural gas prices drop and existing petroleum resources require more intensive clean-up and purification to meet stringent environmental standards. This review covers some of the advances in deep desulfurization, synthesis gas conversion into fuels and feed stocks that were presented at the 245th American Chemical Society Spring Annual Meeting in New Orleans, LA in the Division of Energy and Fuels symposium on "Ultraclean Fuels Production and Utilization".

  15. Iron based photoanodes for solar fuel production.

    PubMed

    Bassi, Prince Saurabh; Gurudayal; Wong, Lydia Helena; Barber, James

    2014-06-28

    In natural photosynthesis, the water splitting reaction of photosystem II is the source of the electrons/reducing equivalents for the reduction of carbon dioxide to carbohydrate while oxygen is formed as the by-product. Similarly, for artificial photosynthesis where the end product is a solar fuel such as hydrogen, a water splitting-oxygen evolving system is required to supply high energy electrons to drive the reductive reactions. Very attractive candidates for this purpose are iron based semiconductors which have band gaps corresponding to visible light and valence band energies sufficient to oxidise water. The most studied system is hematite (Fe2O3) which is highly abundant with many attributes for incorporation into photoelectrochemical (PEC) cells. We review the recent progress in manipulating hematite for this purpose through nanostructuring, doping and surface modifications. We also consider several hybrid iron-based semiconducting systems like ferrites and iron titanates as alternatives to hematite for light driven water splitting emphasizing their advantages with respect to their band levels and charge transport properties.

  16. Fuel ethanol production: process design trends and integration opportunities.

    PubMed

    Cardona, Carlos A; Sánchez, Oscar J

    2007-09-01

    Current fuel ethanol research and development deals with process engineering trends for improving biotechnological production of ethanol. In this work, the key role that process design plays during the development of cost-effective technologies is recognized through the analysis of major trends in process synthesis, modeling, simulation and optimization related to ethanol production. Main directions in techno-economical evaluation of fuel ethanol processes are described as well as some prospecting configurations. The most promising alternatives for compensating ethanol production costs by the generation of valuable co-products are analyzed. Opportunities for integration of fuel ethanol production processes and their implications are underlined. Main ways of process intensification through reaction-reaction, reaction-separation and separation-separation processes are analyzed in the case of bioethanol production. Some examples of energy integration during ethanol production are also highlighted. Finally, some concluding considerations on current and future research tendencies in fuel ethanol production regarding process design and integration are presented.

  17. Alcohol Fuel Production for Vocational Students: Secondary, Postsecondary.

    ERIC Educational Resources Information Center

    Green, C. Paul; Burkhalter, Wayne

    In order to help bring about the potential for alcohol production by the farming community, Navarro College (Texas) has developed this curriculum for secondary and postsecondary levels in alcohol fuel production. The alcohol fuel curriculum consists of five modules for use in practical hands-on vocational programs. The curriculum is designed to…

  18. Enteric bacterial catalysts for fuel ethanol production

    SciTech Connect

    Ingram, L.O.; Aldrich, H.C.; Borges, A.C.C.

    1999-10-01

    The technology is available to produce fuel ethanol from renewable lignocellulosic biomass. The current challenge is to assemble the various process options into a commercial venture and begin the task of incremental improvement. Current process designs for lignocellulose are far more complex than grain to ethanol processes. This complexity results in part from the complexity of the substrate and the biological limitations of the catalyst. Their work at the University of Florida has focused primarily on the genetic engineering of Enteric bacteria using genes encoding Zymomonas mobilis pyruvate decarboxylase and alcohol dehydrogenase. These two genes have been assembled into a portable ethanol production cassette, the PET operon, and integrated into the chromosome of Escherichia coli B for use with hemicellulose-derived syrups. The resulting strain, KO11, produces ethanol efficiently from all hexose and pentose sugars present in the polymers of hemicellulose. By using the same approach, the authors integrated the PET operon into the chromosome of Klebsiella oxytoca to produce strain P2 for use in the simultaneous saccharification and fermentation (SSF) process for cellulose. Strain P2 has the native ability to ferment cellobiose and cellotriose, eliminating the need for one class of cellulase enzymes.

  19. Isotope geochemistry of hydrothermal alteration in East of Esfahan, Central Iran

    NASA Astrophysics Data System (ADS)

    Taghipour, Sedigheh; Taghipour, Batoul

    2010-05-01

    In the Cenozoic magmatic belt of Central Iran, the Eocene volcanics and pyroclastics from the East of Esfahan underwent extensive hydrothermal alteration. The Eocene volcanics composed mostly of andesite lava and tuffs have been altered. The survey area is laterally zoned from an inner quartz-sericite alteration zone to an outer propylitic zone. Quartz-sericite alteration is predominant (>95%), but smaller zones of alunite-jarosite and silicified zones are present and superimposed onto a quartz-sericite alteration. In the quartz-sericite zone all altered rocks are light grayish to whitish in color and porphyritic with aphanitic groundmass. Concentrations of alunite and jarosite veinlets and stockworks are dispersed irregularly in this zone. Alunite and jarosite occur also as coatings on fractured rocks. All types of alunite occurrences are brick-red, cream, white and buff in colors, while jarosite is brown to rusty in colors. To verify, chemical composition of alunite and jarosite were identified by X-ray diffraction in mineral assemblages. Major alteration zones show inclusions of propylite, quartz sericite, advanced argillic and silicified zones. These alunites are mainly porcelaneous and their compositions show a solid solution between alunite and jarosite. In alteration zones, the mineral assemblage is characterized by alunite-jarosite + quartz + sericite + alkali feldspars + chlorite ± turquoise ± barite ± iron oxides. There are numerous alunite and jarosite occurrences, mainly as veinlets, in parts of the advanced argillic zone. Alunite δ18O and δ D values range from -1.76 to 8.81‰ and from -52.86 to -129.26‰ respectively. Field observations, mineralogical evidence and results from light element stable isotope data (δ18O, δ D and δ34S); indicate that in this area alunitization is supergene in origin.

  20. Fuel ethanol production from agricultural residues

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Ethanol is a renewable oxygenated fuel. In 2012, about 13.3 billion gallons of fuel ethanol was produced from corn in the USA which makes up 10% of gasoline supply. Various agricultural residues such as corn stover, wheat straw, rice straw and barley straw can serve as low-cost lignocellulosic fee...

  1. Production of bio-jet fuel from microalgae

    NASA Astrophysics Data System (ADS)

    Elmoraghy, Marian

    The increase in petroleum-based aviation fuel consumption, the decrease in petroleum resources, the fluctuation of the crude oil price, the increase in greenhouse gas emission and the need for energy security are motivating the development of an alternate jet fuel. Bio-jet fuel has to be a drop in fuel, technically and economically feasible, environmentally friendly, greener than jet fuel, produced locally and low gallon per Btu. Bic jet fuel has been produced by blending petro-based jet fuel with microalgae biodiesel (Fatty Acid Methyl Ester, or simply FAME). Indoor microalgae growth, lipids extraction and transetrification to biodiesel are energy and fresh water intensive and time consuming. In addition, the quality of the biodiesel product and the physical properties of the bio-jet fuel blends are unknown. This work addressed these challenges. Minimizing the energy requirements and making microalgae growth process greener were accomplished by replacing fluorescent lights with light emitting diodes (LEDs). Reducing fresh water footprint in algae growth was accomplished by waste water use. Microalgae biodiesel production time was reduced using the one-step (in-situ transestrification) process. Yields up to 56.82 mg FAME/g dry algae were obtained. Predicted physical properties of in-situ FAME satisfied European and American standards confirming its quality. Lipid triggering by nitrogen deprivation was accomplished in order to increase the FAME production. Bio-jet fuel freezing points and heating values were measured for different jet fuel to biodiesel blend ratios.

  2. Production of LEU Fully Ceramic Microencapsulated Fuel for Irradiation Testing

    SciTech Connect

    Terrani, Kurt A; Kiggans Jr, James O; McMurray, Jake W; Jolly, Brian C; Hunt, Rodney Dale; Trammell, Michael P; Snead, Lance Lewis

    2016-01-01

    Fully Ceramic Microencapsulated (FCM) fuel consists of tristructural isotropic (TRISO) fuel particles embedded inside a SiC matrix. This fuel inherently possesses multiple barriers to fission product release, namely the various coating layers in the TRISO fuel particle as well as the dense SiC matrix that hosts these particles. This coupled with the excellent oxidation resistance of the SiC matrix and the SiC coating layer in the TRISO particle designate this concept as an accident tolerant fuel (ATF). The FCM fuel takes advantage of uranium nitride kernels instead of oxide or oxide-carbide kernels used in high temperature gas reactors to enhance heavy metal loading in the highly moderated LWRs. Production of these kernels with appropriate density, coating layer development to produce UN TRISO particles, and consolidation of these particles inside a SiC matrix have been codified thanks to significant R&D supported by US DOE Fuel Cycle R&D program. Also, surrogate FCM pellets (pellets with zirconia instead of uranium-bearing kernels) have been neutron irradiated and the stability of the matrix and coating layer under LWR irradiation conditions have been established. Currently the focus is on production of LEU (7.3% U-235 enrichment) FCM pellets to be utilized for irradiation testing. The irradiation is planned at INL s Advanced Test Reactor (ATR). This is a critical step in development of this fuel concept to establish the ability of this fuel to retain fission products under prototypical irradiation conditions.

  3. Integrated coke, asphalt and jet fuel production process and apparatus

    DOEpatents

    Shang, Jer Y.

    1991-01-01

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  4. Alcohol Fuel By-Product Utilization and Production.

    ERIC Educational Resources Information Center

    Boerboom, Jim

    Ten lessons comprise this curriculum intended to assist vocational teachers in establishing and conducting an alcohol fuels workshop on engine modification and plant design. A glossary is provided first. The 10 lessons cover these topics: the alcohol fuel plant, feedstock preparation lab, distillation lab, fuel plant processes, plant design lab,…

  5. Solar hydrogen production: renewable hydrogen production by dry fuel reforming

    NASA Astrophysics Data System (ADS)

    Bakos, Jamie; Miyamoto, Henry K.

    2006-09-01

    SHEC LABS - Solar Hydrogen Energy Corporation constructed a pilot-plant to demonstrate a Dry Fuel Reforming (DFR) system that is heated primarily by sunlight focusing-mirrors. The pilot-plant consists of: 1) a solar mirror array and solar concentrator and shutter system; and 2) two thermo-catalytic reactors to convert Methane, Carbon Dioxide, and Water into Hydrogen. Results from the pilot study show that solar Hydrogen generation is feasible and cost-competitive with traditional Hydrogen production. More than 95% of Hydrogen commercially produced today is by the Steam Methane Reformation (SMR) of natural gas, a process that liberates Carbon Dioxide to the atmosphere. The SMR process provides a net energy loss of 30 to 35% when converting from Methane to Hydrogen. Solar Hydrogen production provides a 14% net energy gain when converting Methane into Hydrogen since the energy used to drive the process is from the sun. The environmental benefits of generating Hydrogen using renewable energy include significant greenhouse gas and criteria air contaminant reductions.

  6. Energy and precious fuels requirements of fuel alcohol production. Volume 1

    SciTech Connect

    Weinblatt, H.; Lawrence, M.F.; Jenkins, D.

    1982-12-01

    In this study, energy requirements for producing alcohol fuels are estimated and are compared to the energy content of the alcohol produced. The comparisons are developed for three alcohol production alternatives: ethanol from grain, methanol from cellulose, and methanol from coal. In the analysis, alcohol fuel and all nonrenewable fuels are valued on the basis of their higher heating value (in Btu), while byproducts and grain and cellulose feedstocks are valued on the basis of the effect their production would have on the consumption of nonrenewable fuels. The effects of changes in agricultural production were analyzed on the basis of their effects on overall agricultural energy consumption (not on average energy consumption associated with present production). All three alcohol production alternatives were found to be effective means of increasing supplies of liquid fuels. The cellulose-to-methanol alternative, however, produces more energy than it consumes. (The favorable energy balance for this feedstock results largely from the use of cellulose as a boiler fuel as well as a feedstock.) The grain-to-ethanol alternative yields a slightly negative energy balance, while the coal-to-methanol alternative (which uses a nonrenewable fuel as both feedstock and boiler fuel) results in a substantially negative energy balance. The report is presented in four volumes. Volume I (NASA CR-168090) contains the main body of the report, and the other three volumes contain appendices.

  7. METHANOL PRODUCTION FROM BIOMASS AND NATURAL GAS AS TRANSPORTATION FUEL

    EPA Science Inventory

    Two processes are examined for production of methanol. They are assessed against the essential requirements of a future alternative fuel for road transport: that it (i) is producible in amounts comparable to the 19 EJ of motor fuel annually consumed in the U.S., (ii) minimizes em...

  8. Fuel pins with both target and fuel pellets in an isotope-production reactor

    DOEpatents

    Cawley, W.E.; Omberg, R.P.

    1982-08-19

    A method is described for producing tritium in a fast breeder reactor cooled with liquid metal. Lithium target pellets are placed in close contact with fissile fuel pellets in order to increase the tritium production rate.

  9. Navy Mobility Fuels Forecasting System report: Navy fuel production in the year 2000

    SciTech Connect

    Hadder, G.R.; Davis, R.M.

    1991-09-01

    The Refinery Yield Model of the Navy Mobility Fuels Forecasting System has been used to study the feasibility and quality of Navy JP-5 jet fuel and F-76 marine diesel fuel for two scenarios in the year 2000. Both scenarios account for environmental regulations for fuels produced in the US and assume that Eastern Europe, the USSR, and the People`s Republic of China have free market economies. One scenario is based on business-as-usual market conditions for the year 2000. The second scenario is similar to first except that USSR crude oil production is 24 percent lower. During lower oil production in the USSR., there are no adverse effects on Navy fuel availability, but JP-5 is generally a poorer quality fuel relative to business-as-usual in the year 2000. In comparison with 1990, there are two potential problems areas for future Navy fuel quality. The first problem is increased aromaticity of domestically produced Navy fuels. Higher percentages of aromatics could have adverse effects on storage, handling, and combustion characteristics of both JP-5 and F-76. The second, and related, problem is that highly aromatic light cycle oils are blended into F-76 at percentages which promote fuel instability. It is recommended that the Navy continue to monitor the projected trend toward increased aromaticity in JP-5 and F-76 and high percentages of light cycle oils in F-76. These potential problems should be important considerations in research and development for future Navy engines.

  10. Navy Mobility Fuels Forecasting System report: Navy fuel production in the year 2000

    SciTech Connect

    Hadder, G.R.; Davis, R.M.

    1991-09-01

    The Refinery Yield Model of the Navy Mobility Fuels Forecasting System has been used to study the feasibility and quality of Navy JP-5 jet fuel and F-76 marine diesel fuel for two scenarios in the year 2000. Both scenarios account for environmental regulations for fuels produced in the US and assume that Eastern Europe, the USSR, and the People's Republic of China have free market economies. One scenario is based on business-as-usual market conditions for the year 2000. The second scenario is similar to first except that USSR crude oil production is 24 percent lower. During lower oil production in the USSR., there are no adverse effects on Navy fuel availability, but JP-5 is generally a poorer quality fuel relative to business-as-usual in the year 2000. In comparison with 1990, there are two potential problems areas for future Navy fuel quality. The first problem is increased aromaticity of domestically produced Navy fuels. Higher percentages of aromatics could have adverse effects on storage, handling, and combustion characteristics of both JP-5 and F-76. The second, and related, problem is that highly aromatic light cycle oils are blended into F-76 at percentages which promote fuel instability. It is recommended that the Navy continue to monitor the projected trend toward increased aromaticity in JP-5 and F-76 and high percentages of light cycle oils in F-76. These potential problems should be important considerations in research and development for future Navy engines.

  11. Potential production of energy cane for fuel in the Caribbean

    SciTech Connect

    Samuels, G.

    1984-08-01

    Sugarcane grown as energy cane presents a new potential to the Caribbean countries to provide their own energy needs and to reduce or eliminate fuel oil imports. The use of proper agronomic techniques can convert conventional sugarcane growing to a crop capable of giving energy feedstocks in the form of fiber for boiler fuel for electricity and fermentable solids for alcohol for motor fuel. Sugarcane can still be obtained from the energy cane for domestic consumption and export if desired. The aerable land now devoted to sugarcane can utilized for energy-cane production without causing any serious imbalance in food crop production.

  12. Midwest vision for sustainable fuel production

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Meeting the challenge of providing 30% of the transportation fuels used in the USA from those developed from biomass will require significant improvements in technology across the supply chain, significant commercial investment in infrastructure, and, because of the unique characteristics of biomass...

  13. Hybrid fusion reactor for production of nuclear fuel with minimum radioactive contamination of the fuel cycle

    NASA Astrophysics Data System (ADS)

    Velikhov, E. P.; Kovalchuk, M. V.; Azizov, E. A.; Ignatiev, V. V.; Subbotin, S. A.; Tsibulskiy, V. F.

    2015-12-01

    The paper presents the results of the system research on the coordinated development of nuclear and fusion power engineering in the current century. Considering the increasing problems of resource procurement, including limited natural uranium resources, it seems reasonable to use fusion reactors as high-power neutron sources for production of nuclear fuel in a blanket. It is shown that the share of fusion sources in this structural configuration of the energy system can be relatively small. A fundamentally important aspect of this solution to the problem of closure of the fuel cycle is that recycling of highly active spent fuel can be abandoned. Radioactivity released during the recycling of the spent fuel from the hybrid reactor blanket is at least two orders of magnitude lower than during the production of the same number of fissile isotopes after the recycling of the spent fuel from a fast reactor.

  14. Hybrid fusion reactor for production of nuclear fuel with minimum radioactive contamination of the fuel cycle

    SciTech Connect

    Velikhov, E. P.; Kovalchuk, M. V.; Azizov, E. A. Ignatiev, V. V.; Subbotin, S. A. Tsibulskiy, V. F.

    2015-12-15

    The paper presents the results of the system research on the coordinated development of nuclear and fusion power engineering in the current century. Considering the increasing problems of resource procurement, including limited natural uranium resources, it seems reasonable to use fusion reactors as high-power neutron sources for production of nuclear fuel in a blanket. It is shown that the share of fusion sources in this structural configuration of the energy system can be relatively small. A fundamentally important aspect of this solution to the problem of closure of the fuel cycle is that recycling of highly active spent fuel can be abandoned. Radioactivity released during the recycling of the spent fuel from the hybrid reactor blanket is at least two orders of magnitude lower than during the production of the same number of fissile isotopes after the recycling of the spent fuel from a fast reactor.

  15. Trends in biotechnological production of fuel ethanol from different feedstocks.

    PubMed

    Sánchez, Oscar J; Cardona, Carlos A

    2008-09-01

    Present work deals with the biotechnological production of fuel ethanol from different raw materials. The different technologies for producing fuel ethanol from sucrose-containing feedstocks (mainly sugar cane), starchy materials and lignocellulosic biomass are described along with the major research trends for improving them. The complexity of the biomass processing is recognized through the analysis of the different stages involved in the conversion of lignocellulosic complex into fermentable sugars. The features of fermentation processes for the three groups of studied feedstocks are discussed. Comparative indexes for the three major types of feedstocks for fuel ethanol production are presented. Finally, some concluding considerations on current research and future tendencies in the production of fuel ethanol regarding the pretreatment and biological conversion of the feedstocks are presented.

  16. Whole-cell biocatalysts for biodiesel fuel production.

    PubMed

    Fukuda, H; Hama, S; Tamalampudi, S; Noda, H

    2008-12-01

    Biodiesel fuel (BDF), which refers to fatty acid alkyl esters, has attracted considerable attention as an environmentally friendly alternative fuel for diesel engines. Alkali catalysis is widely applied for the commercial production of BDF. However, enzymatic transesterification offers considerable advantages, including reducing process operations in biodiesel fuel production and an easy separation of the glycerol byproduct. The high cost of the lipase enzyme is the main obstacle for a commercially feasible enzymatic production of biodiesel fuels. To reduce enzyme associated process costs, the immobilization of fungal mycelium within biomass support particles (BSPs) as well as expression of the lipase enzyme on the surface of yeast cells has been developed to generate whole-cell biocatalysts for industrial applications.

  17. Modulation of fossil fuel production by global temperature variations, 2

    SciTech Connect

    Rust, B.W.; Crosby, F.J.

    1994-01-01

    The report includes the inverse modulation of global fossil production by variations in Northern Hemispheric temperatures. The present study incorporates recent revisions and extensions of the fuel production record and uses a much improved temperature record. The authors show that the new data are consistent with the predictions of the original Rust-Kirk model which they then extend to allow for time lag between variations in the temperature and the corresponding responses in fuel production. The modulation enters the new model through the convolution of a lagged averaging function with the temperature time-series. The authors also include explicit terms to account for the perturbations caused by the Great Depression and World War II. The final model accounts for 99.84% of the total variance in the production record. This modulation represents a feedback which is consistent with the carbon dioxide problem; climate change; fossil fuel production; global warming Gaia hypothesis; temperature variations.

  18. Liquid fuels production from biomass. Final report

    SciTech Connect

    Levy, P. F.; Sanderson, J. E.; Ashare, E.; Wise, D. L.; Molyneaux, M. S.

    1980-06-30

    The current program to convert biomass into liquid hydrocarbon fuels is an extension of a previous program to ferment marine algae to acetic acid. In that study it was found that marine algae could be converted to higher aliphatic organic acids and that these acids could be readily removed from the fermentation broth by membrane or liquid-liquid extraction. It was then proposed to convert these higher organic acids via Kolbe electrolysis to aliphatic hydrocarbons, which may be used as a diesel fuel. The specific goals for the current porgram are: (1) establish conditions under which substrates other than marine algae may be converted in good yield to organic acids, here the primary task is methane suppression; (2) modify the current 300-liter fixed packed bed batch fermenter to operate in a continuous mode; (3) change from membrane extraction of organic acids to liquid-liquid extraction; (4) optimize the energy balance of the electrolytic oxidation process, the primary task is to reduce the working potential required for the electrolysis while maintaining an adequate current density; (5) scale the entire process up to match the output of the 300 liter fermenter; and (6) design pilot plant and commercial size plant (1000 tons/day) processes for converting biomass to liquid hydrocarbon fuels and perform an economic analysis for the 1000 ton/day design.

  19. EVermont Renewable Hydrogen Production and Transportation Fueling System

    SciTech Connect

    Garabedian, Harold T. Wight, Gregory Dreier, Ken Borland, Nicholas

    2008-03-30

    A great deal of research funding is being devoted to the use of hydrogen for transportation fuel, particularly in the development of fuel cell vehicles. When this research bears fruit in the form of consumer-ready vehicles, will the fueling infrastructure be ready? Will the required fueling systems work in cold climates as well as they do in warm areas? Will we be sure that production of hydrogen as the energy carrier of choice for our transit system is the most energy efficient and environmentally friendly option? Will consumers understand this fuel and how to handle it? Those are questions addressed by the EVermont Wind to Wheels Hydrogen Project: Sustainable Transportation. The hydrogen fueling infrastructure consists of three primary subcomponents: a hydrogen generator (electrolyzer), a compression and storage system, and a dispenser. The generated fuel is then used to provide transportation as a motor fuel. EVermont Inc., started in 1993 by then governor Howard Dean, is a public-private partnership of entities interested in documenting and advancing the performance of advanced technology vehicles that are sustainable and less burdensome on the environment, especially in areas of cold climates, hilly terrain and with rural settlement patterns. EVermont has developed a demonstration wind powered hydrogen fuel producing filling system that uses electrolysis, compression to 5000 psi and a hydrogen burning vehicle that functions reliably in cold climates. And that fuel is then used to meet transportation needs in a hybrid electric vehicle whose internal combustion engine has been converted to operate on hydrogen Sponsored by the DOE EERE Hydrogen, Fuel Cells & Infrastructure Technologies (HFC&IT) Program, the purpose of the project is to test the viability of sustainably produced hydrogen for use as a transportation fuel in a cold climate with hilly terrain and rural settlement patterns. Specifically, the project addresses the challenge of building a renewable

  20. PRODUCTION OF NEW BIOMASS/WASTE-CONTAINING SOLID FUELS

    SciTech Connect

    David J. Akers; Glenn A. Shirey; Zalman Zitron; Charles Q. Maney

    2001-04-20

    CQ Inc. and its team members (ALSTOM Power Inc., Bliss Industries, McFadden Machine Company, and industry advisors from coal-burning utilities, equipment manufacturers, and the pellet fuels industry) addressed the objectives of the Department of Energy and industry to produce economical, new solid fuels from coal, biomass, and waste materials that reduce emissions from coal-fired boilers. This project builds on the team's commercial experience in composite fuels for energy production. The electric utility industry is interested in the use of biomass and wastes as fuel to reduce both emissions and fuel costs. In addition to these benefits, utilities also recognize the business advantage of consuming the waste byproducts of customers both to retain customers and to improve the public image of the industry. Unfortunately, biomass and waste byproducts can be troublesome fuels because of low bulk density, high moisture content, variable composition, handling and feeding problems, and inadequate information about combustion and emissions characteristics. Current methods of co-firing biomass and wastes either use a separate fuel receiving, storage, and boiler feed system, or mass burn the biomass by simply mixing it with coal on the storage pile. For biomass or biomass-containing composite fuels to be extensively used in the U.S., especially in the steam market, a lower cost method of producing these fuels must be developed that includes both moisture reduction and pelletization or agglomeration for necessary fuel density and ease of handling. Further, this method of fuel production must be applicable to a variety of combinations of biomass, wastes, and coal; economically competitive with current fuels; and provide environmental benefits compared with coal. Notable accomplishments from the work performed in Phase I of this project include the development of three standard fuel formulations from mixtures of coal fines, biomass, and waste materials that can be used in

  1. Applying fuel cell experience to sustainable power products

    NASA Astrophysics Data System (ADS)

    King, Joseph M.; O'Day, Michael J.

    Fuel cell power plants have demonstrated high efficiency, environmental friendliness, excellent transient response, and superior reliability and durability in spacecraft and stationary applications. Broader application of fuel cell technology promises significant contribution to sustainable global economic growth, but requires improvement to size, cost, fuel flexibility and operating flexibility. International Fuel Cells (IFC) is applying lessons learned from delivery of more than 425 fuel cell power plants and 3 million h of operation to the development of product technology which captures that promise. Key findings at the fuel cell power plant level include: (1) ancillary components account for more than 40% of the weight and nearly all unscheduled outages of hydrocarbon-fuelled power plants; a higher level of integration and simplification is required to achieve reasonable characteristics, (2) hydrocarbon fuel cell power plant components are highly interactive; the fuel processing approach and power plant operating pressure are major determinants of overall efficiency, and (3) achieving the durability required for heavy duty vehicles and stationary applications requires simultaneous satisfaction of electrochemical, materials and mechanical considerations in the design of the cell stack and other power plant components. Practical designs must minimize application specific equipment. Related lessons for stationary fuel cell power plants include: (1) within fuel specification limits, natural gas varies widely in heating value, minor constituents such as oxygen and nitrogen content and trace compounds such as the odorant; (2) city water quality varies widely; recovery of product water for process use avoids costly, complicated and site-specific water treatment systems, but water treatment is required to eliminate impurities and (3) the embedded protection functions for reliable operation of fuel cell power conditioners meet or exceed those required for connection to

  2. Formate Formation and Formate Conversion in Biological Fuels Production

    PubMed Central

    Crable, Bryan R.; Plugge, Caroline M.; McInerney, Michael J.; Stams, Alfons J. M.

    2011-01-01

    Biomethanation is a mature technology for fuel production. Fourth generation biofuels research will focus on sequestering CO2 and providing carbon-neutral or carbon-negative strategies to cope with dwindling fossil fuel supplies and environmental impact. Formate is an important intermediate in the methanogenic breakdown of complex organic material and serves as an important precursor for biological fuels production in the form of methane, hydrogen, and potentially methanol. Formate is produced by either CoA-dependent cleavage of pyruvate or enzymatic reduction of CO2 in an NADH- or ferredoxin-dependent manner. Formate is consumed through oxidation to CO2 and H2 or can be further reduced via the Wood-Ljungdahl pathway for carbon fixation or industrially for the production of methanol. Here, we review the enzymes involved in the interconversion of formate and discuss potential applications for biofuels production. PMID:21687599

  3. Properties of air and combustion products of fuel with air

    NASA Technical Reports Server (NTRS)

    Poferl, D. J.; Svehla, R. A.

    1975-01-01

    Thermodynamic and transport properties have been calculated for air, the combustion products of natural gas and air, and combustion products of ASTM-A-1 jet fuel and air. Properties calculated include: ratio of specific heats, molecular weight, viscosity, specific heat, thermal conductivity, Prandtl number, and enthalpy.

  4. Hydrogen production econometric studies. [hydrogen and fossil fuels

    NASA Technical Reports Server (NTRS)

    Howell, J. R.; Bannerot, R. B.

    1975-01-01

    The current assessments of fossil fuel resources in the United States were examined, and predictions of the maximum and minimum lifetimes of recoverable resources according to these assessments are presented. In addition, current rates of production in quads/year for the fossil fuels were determined from the literature. Where possible, costs of energy, location of reserves, and remaining time before these reserves are exhausted are given. Limitations that appear to hinder complete development of each energy source are outlined.

  5. Archaebacterial Fuel Production: Methane from Biomass.

    ERIC Educational Resources Information Center

    Lennox, John E.; And Others

    1983-01-01

    Discusses microbial production of methane from biomass. Topics include methogens (bacteria producing methane), ecology of methanogenesis, methanogenesis in ruminant/nonruminant and other environments, role of methanogenesis in nature, and methane production in sewage treatment plants. Also discusses construction of methane digesters (and related…

  6. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect

    Unknown

    2000-01-01

    The FCE PDI program is designed to advance the carbonate fuel cell technology from the current full-size field test to the commercial design. The specific objectives selected to attain the overall program goal are: Define power plant requirements and specifications; Establish the design for a multifuel, low-cost, modular, market-responsive power plant; Resolve power plant manufacturing issues and define the design for the commercial-scale manufacturing facility; Define the stack and balance-of-plant (BOP) equipment packaging arrangement, and module designs; Acquire capability to support developmental testing of stacks and critical BOP equipment to prepare for commercial design; and Resolve stack and BOP equipment technology issues, and design, build and field test a modular prototype power plant to demonstrate readiness for commercial entry.

  7. Direct production of fractionated and upgraded hydrocarbon fuels from biomass

    DOEpatents

    Felix, Larry G.; Linck, Martin B.; Marker, Terry L.; Roberts, Michael J.

    2014-08-26

    Multistage processing of biomass to produce at least two separate fungible fuel streams, one dominated by gasoline boiling-point range liquids and the other by diesel boiling-point range liquids. The processing involves hydrotreating the biomass to produce a hydrotreatment product including a deoxygenated hydrocarbon product of gasoline and diesel boiling materials, followed by separating each of the gasoline and diesel boiling materials from the hydrotreatment product and each other.

  8. Assessment of technology for production of liquid fuels from biomass

    SciTech Connect

    Sheppard, A.P.; Spurlock, J.M.; Birchfield, J.L.

    1981-01-01

    Technologies for liquid fuel production from biomass vary widely in states of development and extent of need for government action. Ethanol produced from grain (principally corn), for use in gasohol blends, is the most widely used and accepted biomass-based energy source in the U.S. at present. Several practical factors strongly point to needed government emphasis on research and development to advance ethanol-production technology. Liquid fuels produced from soybeans, sunflowers, Euphorbia and similar crops, or from aquatic plants, remain as longer-term potential requiring further assessment. 6 refs.

  9. Metabolic engineering for the production of hydrocarbon fuels.

    PubMed

    Lee, Sang Yup; Kim, Hye Mi; Cheon, Seungwoo

    2015-06-01

    Biofuels have been attracting increasing attention to provide a solution to the problems of climate change and our dependence on limited fossil oil. During the last decade, metabolic engineering has been performed to develop superior microorganisms for the production of so called advanced biofuels. Among the advanced biofuels, hydrocarbons possess high-energy content and superior fuel properties to other biofuels, and thus have recently been attracting much research interest. Here we review the recent advances in the microbial production of hydrocarbon fuels together with the metabolic engineering strategies employed to develop their production strains. Strategies employed for the production of long-chain and short-chain hydrocarbons derived from fatty acid metabolism along with the isoprenoid-derived hydrocarbons are reviewed. Also, the current limitations and future prospects in hydrocarbon-based biofuel production are discussed. PMID:25445543

  10. Metabolic engineering for the production of hydrocarbon fuels.

    PubMed

    Lee, Sang Yup; Kim, Hye Mi; Cheon, Seungwoo

    2015-06-01

    Biofuels have been attracting increasing attention to provide a solution to the problems of climate change and our dependence on limited fossil oil. During the last decade, metabolic engineering has been performed to develop superior microorganisms for the production of so called advanced biofuels. Among the advanced biofuels, hydrocarbons possess high-energy content and superior fuel properties to other biofuels, and thus have recently been attracting much research interest. Here we review the recent advances in the microbial production of hydrocarbon fuels together with the metabolic engineering strategies employed to develop their production strains. Strategies employed for the production of long-chain and short-chain hydrocarbons derived from fatty acid metabolism along with the isoprenoid-derived hydrocarbons are reviewed. Also, the current limitations and future prospects in hydrocarbon-based biofuel production are discussed.

  11. Fuel alcohol production from agricultural lignocellulosic feedstocks

    SciTech Connect

    Farina, G.E.; Barrier, J.W.; Forsythe, M.L. )

    1988-01-01

    A two-stage, low-temperature, ambient pressure, acid hydrolysis process that utilizes separate unit operations to convert hemicellulose and cellulose in agricultural residues and crops to fermentable sugars is being developed and tested. Based on the results of the bench-scale tests, an acid hydrolysis experimental plant to demonstrate the concepts of low-temperature acid hydrolysis on a much larger scale was built. Plant tests using corn stover have been conducted for more that a year and conversion efficiences have equaled those achieved in the laboratory. Laboratory tests to determine the potential for low-temperature acid hydrolysis of other feedstocks - including red clover, alfalfa, kobe lespedeza, winter rape, and rye grass - are being conducted. Where applicable, process modifications to include extraction before or after hydrolysis also are being studied. This paper describes the experimental plant and process, results obtained in the plant, results of alternative feedstocks testing in the laboratory, and a plan for an integrated system that will produce other fuels, feed, and food from crops grown on marginal land.

  12. Fuel-cycle assessment of selected bioethanol production.

    SciTech Connect

    Wu, M.; Wang, M.; Hong, H.; Energy Systems

    2007-01-31

    A large amount of corn stover is available in the U.S. corn belt for the potential production of cellulosic bioethanol when the production technology becomes commercially ready. In fact, because corn stover is already available, it could serve as a starting point for producing cellulosic ethanol as a transportation fuel to help reduce the nation's demand for petroleum oil. Using the data available on the collection and transportation of corn stover and on the production of cellulosic ethanol, we have added the corn stover-to-ethanol pathway in the GREET model, a fuel-cycle model developed at Argonne National Laboratory. We then analyzed the life-cycle energy use and emission impacts of corn stover-derived fuel ethanol for use as E85 in flexible fuel vehicles (FFVs). The analysis included fertilizer manufacturing, corn farming, farming machinery manufacturing, stover collection and transportation, ethanol production, ethanol transportation, and ethanol use in light-duty vehicles (LDVs). Energy consumption of petroleum oil and fossil energy, emissions of greenhouse gases (carbon dioxide [CO{sub 2}], nitrous oxide [N{sub 2}O], and methane [CH{sub 4}]), and emissions of criteria pollutants (carbon monoxide [CO], volatile organic compounds [VOCs], nitrogen oxide [NO{sub x}], sulfur oxide [SO{sub x}], and particulate matter with diameters smaller than 10 micrometers [PM{sub 10}]) during the fuel cycle were estimated. Scenarios of ethanol from corn grain, corn stover, and other cellulosic feedstocks were then compared with petroleum reformulated gasoline (RFG). Results showed that FFVs fueled with corn stover ethanol blends offer substantial energy savings (94-95%) relative to those fueled with RFG. For each Btu of corn stover ethanol produced and used, 0.09 Btu of fossil fuel is required. The cellulosic ethanol pathway avoids 86-89% of greenhouse gas emissions. Unlike the life cycle of corn grain-based ethanol, in which the ethanol plant consumes most of the fossil fuel

  13. Fuel cell systems for a sustainable energy production

    SciTech Connect

    Kivisaari, T.

    1996-12-31

    When talking about fuel cell systems for stationary applications, two of the advantages are claimed to be a high inherent efficiency and environmentally favourable characteristics. It should, however, be obvious to everybody that in order to call an energy production route environmentally benign, it is not enough that just the energy production step itself has a low negative environmental impact, but that all steps involved (e.g. fuel pre-treatment, fuel processing etc.) should be subjected to the same constraints if the overall production process is to be considered environmentally friendly. In order to evaluate the technical possibilities of a biomass fuelled MCFC unit for stationary applications a system study of a 40 MWe biomass-fired MCFC system is currently carried out at The Royal Institute of Technology, as part of the international co-operation within the IEA Advanced Fuel Cell Programme Annex 1, Balance of Plant of MCFC Systems. In addition to the present work, other recent studies involving biomass and fuel cells can be found in literature.

  14. Technical and Economic Evaluation of Macroalgae Cultivation for Fuel Production (Draft)

    SciTech Connect

    Feinberg, D. A.; Hock, S. M.

    1985-04-01

    The potential of macroalgae as sources of renewable liquid and gaseous fuels is evaluated. A series of options for production of macroalgae feedstock is considered. Because of their high carbohydrate content, the fuel products for which macroalgae are most suitable are methane and ethanol. Fuel product costs were compared with projected fuel costs in the year 1995.

  15. CO{sub 2} mitigation and fuel production

    SciTech Connect

    Steinberg, M.

    1997-07-07

    Methanol as an alternative transportation fuel appears to be an effective intermediate agent, for reducing CO{sub 2} from the utility power and the transportation sectors. On the utilization side, methanol as a liquid fuel fits in well with the current infrastructure for storage and delivery to the automotive sector with better efficiency. On the production side, CO{sub 2} from fossil fuel plants together with natural gas and biomass can be used as feedstocks for methanol synthesis with reduced CO{sub 2}. Over the past several years, processes have emerged which have varying degrees of CO{sub 2} emission reduction depending on the feedstocks used for methanol synthesis process. This paper reviews the methanol processes from the point of view of production efficiency and CO{sub 2} emissions reduction. The processes include: (1) the Hydrocarb Process which primarily utilizes coal and natural gas and stores carbon, and (2) the Hynol Process which utilizes biomass (including carbonaceous wastes, municipal solid waste (MSW)) or coal and natural gas, and (3) the Carnol Process which utilizes natural gas and CO{sub 2} recovered from fossil fuel fired powered plant stacks, especially coal fired plants. The Carnol System consists of power generation, methanol production and methanol utilization as an automotive fuel. The efficiency and CO{sub 2} emissions for the entire system are compared to the conventional system of petroleum derived automotive fuel (gasoline) and coal fired power generation plants. CO{sub 2} reduction by as much as 56% and 77% can be achieved when methanol is used in internal combustion and fuel cell automotive vehicles, respectively.

  16. Renewable hydrogen production for fossil fuel processing

    SciTech Connect

    Greenbaum, E.; Lee, J.W.; Tevault, C.V.

    1995-06-01

    In the fundamental biological process of photosynthesis, atmospheric carbon dioxide is reduced to carbohydrate using water as the source of electrons with simultaneous evolution of molecular oxygen: H{sub 2}O + CO{sub 2} + light {yields} O{sub 2} + (CH{sub 2}O). It is well established that two light reactions, Photosystems I and II (PSI and PSII) working in series, are required to perform oxygenic photosynthesis. Experimental data supporting the two-light reaction model are based on the quantum requirement for complete photosynthesis, spectroscopy, and direct biochemical analysis. Some algae also have the capability to evolve molecular hydrogen in a reaction energized by the light reactions of photosynthesis. This process, now known as biophotolysis, can use water as the electron donor and lead to simultaneous evolution of molecular hydrogen and oxygen. In green algae, hydrogen evolution requires prior incubation under anaerobic conditions. Atmospheric oxygen inhibits hydrogen evolution and also represses the synthesis of hydrogenase enzyme. CO{sub 2} fixation competes with proton reduction for electrons relased from the photosystems. Interest in biophotolysis arises from both the questions that it raises concerning photosynthesis and its potential practical application as a process for converting solar energy to a non-carbon-based fuel. Prior data supported the requirement for both Photosystem I and Photosystem II in spanning the energy gap necessary for biophotolysis of water to oxygen and hydrogen. In this paper we report the at PSII alone is capable of driving sustained simultaneous photoevolution of molecular hydrogen and oxygen in an anaerobically adapted PSI-deficient strain of Chlamydomonas reinhardtii, mutant B4, and that CO{sub 2} competes as an electron acceptor.

  17. Fate of virginiamycin through the fuel ethanol production process

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Antibiotics are frequently used to prevent and treat bacterial contamination of commercial fuel ethanol fermentations, but there is concern that antibiotic residues may persist in the distillers grains coproducts. A study to evaluate the fate of virginiamycin during the ethanol production process wa...

  18. Antimicrobial peptides against contaminating bacteria in fuel ethanol production

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Lactic acid bacteria (LAB) are commonly found as contaminants of fuel ethanol production, resulting in reduced ethanol yields: (1). Recent reports suggest that LAB can develop resistance to antibiotics such as virginiamycin and penicillin that are commonly used to control bacterial contamination; (2...

  19. Antimicrobial peptides against contaminating bacteria in fuel ethanol production

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Lactic acid bacteria (LAB) are commonly found as contaminants of fuel ethanol production, resulting in reduced ethanol yields (1). Recent reports suggest that LAB can develop resistance to antibiotics such as virginiamycin and penicillin that are commonly used to control bacterial contamination (2)...

  20. Fuel ethanol production from alkaline peroxide pretreated corn stover

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Corn stover (CS) has the potential to serve as an abundant low-cost feedstock for production of fuel ethanol. Due to heterogeneous complexity and recalcitrance of lignocellulosic feedstocks, pretreatment is required to break the lignin seal and/or disrupt the structure of crystalline cellulose to in...

  1. H2 PRODUCTION AND FUEL CELLS.

    SciTech Connect

    WANG, X.; RODRIGUEZ, J.A.

    2006-06-30

    Oxide nanosystems play a key role as components of catalysts used for the production of H{sub 2} via the steam reforming or the partial oxidation of hydrocarbons, and for the water-gas shift reaction. The behavior seen for Cu-ceria and Au-ceria WGS catalysts indicates that the oxide is much more than a simple support. The special chemical properties of the oxide nanoparticles (defect rich, high mobility of oxygen) favor interactions with the reactants or other catalyst components. More in-situ characterization and mechanistic studies are necessary for the optimization of these nanocatalysts. The use of oxide nanomaterials for the fabrication of PEMFCs and SOFCs can lead to devices with a high practical impact. One objective is to build electrodes with low cost conducting oxide nanoarrays. The electron and oxygen-ion conducting capabilities of many oxides improve when going from the bulk to the nanoscale. Furthermore, one can get a more homogeneous surface morphology and an increase of the effective reaction area. Much more fundamental and practical research needs to be done in this area.

  2. Ethanol Production for Automotive Fuel Usage

    SciTech Connect

    Lindemuth, T.E.; Stenzel, R.A.; Yim, Y.J.; Yu, J.

    1980-01-31

    The conceptual design of the 20 million gallon per year anhydrous ethanol facility a t Raft River has been completed. The corresponding geothermal gathering, extraction and reinjection systems to supply the process heating requirement were also completed. The ethanol facility operating on sugar beets, potatoes and wheat will share common fermentation and product recovery equipment. The geothermal fluid requirement will be approximately 6,000 gpm. It is anticipated that this flow will be supplied by 9 supply wells spaced at no closer than 1/4 mile in order to prevent mutual interferences. The geothermal fluid will be flashed in three stages to supply process steam at 250 F, 225 F and 205 F for various process needs. Steam condensate plus liquid remaining after the third flash will all be reinjected through 9 reinjection wells. The capital cost estimated for this ethanol plant employing all three feedstocks is $64 million. If only a single feedstock were used (for the same 20 mm gal/yr plant) the capital costs are estimated at $51.6 million, $43.1 million and $40. 5 million for sugar beets, potatoes and wheat respectively. The estimated capital cost for the geothermal system is $18 million.

  3. Photosynthesis biomolecular electronics, and renewable fuels production

    SciTech Connect

    Greenbaum, E.

    1995-12-31

    The term {open_quotes}biomolecular electronics{close_quotes} evokes two powerful images of 20th century science and technology. First, the {open_quotes}bio{close_quotes} prefix of {open_quotes}molecular{close_quotes} explicitly acknowledges the molecular basis and understanding of living state systems. It is this understanding that forms the foundation of molecular biology, immunology, and genetic engineering. Second, {open_quotes}electronics{close_quotes} in the context of technology is understood to be that of electronic devices, starting from vacuum tubes and progressing through transistors, integrated circuits, and the semiconductor electronics industry comprising communications and consumer electronics, as examples. The conflation of these two terms into {open_quotes}biomolecular electronics{close_quotes} implies a radical concept: the construction of practical electronic devices from biomolecular components. This presentation will focus on an understanding and interpretation of the molecular architecture of the photosynthetic membrane and its potential application for the construction of optoelectronic devices and the production of renewable hydrogen via photosynthetic water splitting. Recent advances on direct electrical contact of the electron transport chain of photosynthesis with metallocatalysts as well as the discovery of new photoreactions in mutants of the green alga Chlamydomonas reinhardtii will be discussed.

  4. Harvesting feedlot manure for fuel production

    SciTech Connect

    Sweeten, J.M.; Higgins, A.; Spindler, D.; Undersander, D.J.; Egg, R.P.; Reddell, D.L.

    1981-01-01

    Field investigations were conducted to determine the variation of manure quality as a function of depth in the manure pack, the quantity of feedlot manure that can be harvested with elevating scrapers and wheel loader, and the yield of reasonable high-quality feedlot manure for biogas plant feedstock. Feedlot manure quality (ash, heat of combustion, and S content) varied with vertical location in the manure pack. Loose surface manure had the highest quality for these purposes. Heat of combustion was closely related with ash and moisture contents, it averaged 8302 Btu per pound on a dry ash-free basis for all samples. The majority of the manure pack could be collected with an elevating scraper to yield a feedstock with 30% ash and a heat of combustion of 8800 Btu per pound on a dry ash-free basis. Feedlot manure collected by the elevating scraper is much higher in quality for essentially all uses than the 1-2 inch, thick manure/soil interfacial layer. The quantity and quality of feedlot manure that can be collected from feedlots in the vicinity of a proposed biogas production plant in southeastern Colorado are reported.

  5. Production of New Biomass/Waste-Containing Solid Fuels

    SciTech Connect

    Glenn A. Shirey; David J. Akers

    2005-09-23

    CQ Inc. and its industry partners--PBS Coals, Inc. (Friedens, Pennsylvania), American Fiber Resources (Fairmont, West Virginia), Allegheny Energy Supply (Williamsport, Maryland), and the Heritage Research Group (Indianapolis, Indiana)--addressed the objectives of the Department of Energy and industry to produce economical, new solid fuels from coal, biomass, and waste materials that reduce emissions from coal-fired boilers. This project builds on the team's commercial experience in composite fuels for energy production. The electric utility industry is interested in the use of biomass and wastes as fuel to reduce both emissions and fuel costs. In addition to these benefits, utilities also recognize the business advantage of consuming the waste byproducts of customers both to retain customers and to improve the public image of the industry. Unfortunately, biomass and waste byproducts can be troublesome fuels because of low bulk density, high moisture content, variable composition, handling and feeding problems, and inadequate information about combustion and emissions characteristics. Current methods of co-firing biomass and wastes either use a separate fuel receiving, storage, and boiler feed system, or mass burn the biomass by simply mixing it with coal on the storage pile. For biomass or biomass-containing composite fuels to be extensively used in the U.S., especially in the steam market, a lower cost method of producing these fuels must be developed that is applicable to a variety of combinations of biomass, wastes, and coal; economically competitive with current fuels; and provides environmental benefits compared with coal. During Phase I of this project (January 1999 to July 2000), several biomass/waste materials were evaluated for potential use in a composite fuel. As a result of that work and the team's commercial experience in composite fuels for energy production, paper mill sludge and coal were selected for further evaluation and demonstration in Phase II

  6. Photocatalysis for renewable energy production using PhotoFuelCells.

    PubMed

    Michal, Robert; Sfaelou, Stavroula; Lianos, Panagiotis

    2014-11-27

    The present work is a short review of our recent studies on PhotoFuelCells, that is, photoelectrochemical cells which consume a fuel to produce electricity or hydrogen, and presents some unpublished data concerning both electricity and hydrogen production. PhotoFuelCells have been constructed using nanoparticulate titania photoanodes and various cathode electrodes bearing a few different types of electrocatalyst. In the case where the cell functioned with an aerated cathode, the cathode electrode was made of carbon cloth carrying a carbon paste made of carbon black and dispersed Pt nanoparticles. When the cell was operated in the absence of oxygen, the electrocatalyst was deposited on an FTO slide using a special commercial carbon paste, which was again enriched with Pt nanoparticles. Mixing of Pt with carbon paste decreased the quantity of Pt necessary to act as electrocatalyst. PhotoFuelCells can produce electricity without bias and with relatively high open-circuit voltage when they function in the presence of fuel and with an aerated cathode. In that case, titania can be sensitized in the visible region by CdS quantum dots. In the present work, CdS was deposited by the SILAR method. Other metal chalcogenides are not functional as sensitizers because the combined photoanode in their presence does not have enough oxidative power to oxidize the fuel. Concerning hydrogen production, it was found that it is difficult to produce hydrogen in an alkaline environment even under bias, however, this is still possible if losses are minimized. One way to limit losses is to short-circuit anode and cathode electrode and put them close together. This is achieved in the "photoelectrocatalytic leaf", which was presently demonstrated capable of producing hydrogen even in a strongly alkaline environment.

  7. Production of metal waste forms from spent fuel treatment

    SciTech Connect

    Westphal, B.R.; Keiser, D.D.; Rigg, R.H.; Laug, D.V.

    1995-02-01

    Treatment of spent nuclear fuel at Argonne National Laboratory consists of a pyroprocessing scheme in which the development of suitable waste forms is being advanced. Of the two waste forms being proposed, metal and mineral, the production of the metal waste form utilizes induction melting to stabilize the waste product. Alloying of metallic nuclear materials by induction melting has long been an Argonne strength and thus, the transition to metallic waste processing seems compatible. A test program is being initiated to coalesce the production of the metal waste forms with current induction melting capabilities.

  8. Characterization of Catalyst Materials for Production of Aerospace Fuels

    NASA Technical Reports Server (NTRS)

    DeLaRee, Ana B.; Hepp, Aloysius F.

    2011-01-01

    Due to environmental, economic, and security issues, there is a greater need for cleaner alternative fuels. There will undoubtedly be a shift from crude oil to non-petroleum sources as a feedstock for aviation (and other transportation) fuels. Additionally, efforts are concentrated on reducing costs coupled with fuel production from non-conventional sources. One solution to this issue is Fischer-Tropsch gas-to-liquid technology. Fischer-Tropsch processing of synthesis gas (CO/H2) produces a complex product stream of paraffins, olefins, and oxygenated compounds such as alcohols and aldehydes. The Fisher-Tropsch process can produce a cleaner diesel oil fraction with a high cetane number (typically above 70) without any sulfur or aromatic compounds. This process is most commonly catalyzed by heterogeneous (in this case, silver and platinum) catalysts composed of cobalt supported on alumina or unsupported alloyed iron powders. Physisorption, chemisorptions, scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) are described to better understand the potential performance of Fischer-Tropsch cobalt on alumina catalysts promoted with silver and platinum. The overall goal is to preferentially produce C8 to C18 paraffin compounds for use as aerospace fuels. Progress towards this goal will eventually be updated and achieved by a more thorough understanding of the characterization of catalyst materials. This work was supported by NASA s Subsonic Fixed Wing and In-situ Resource Utilization projects.

  9. Characterization of Catalyst Materials for Production of Aerospace Fuels

    NASA Technical Reports Server (NTRS)

    Best, Lauren M.; De La Ree, Ana B.; Hepp, Aloysius F.

    2012-01-01

    Due to environmental, economic, and security issues, there is a greater need for cleaner alternative fuels. There will undoubtedly be a shift from crude oil to non-petroleum sources as a feedstock for aviation (and other transportation) fuels. Additionally, efforts are concentrated on reducing costs coupled with fuel production from non-conventional sources. One solution to this issue is Fischer-Tropsch gas-to-liquid technology. Fischer-Tropsch processing of synthesis gas (CO/H2) produces a complex product stream of paraffins, olefins, and oxygenated compounds such as alcohols and aldehydes. The Fisher-Tropsch process can produce a cleaner diesel oil fraction with a high cetane number (typically above 70) without any sulfur or aromatic compounds. This process is most commonly catalyzed by heterogeneous (in this case, silver and platinum) catalysts composed of cobalt supported on alumina or unsupported alloyed iron powders. Physisorption, chemisorptions, scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS) are described to better understand the potential performance of Fischer-Tropsch cobalt on alumina catalysts promoted with silver and platinum. The overall goal is to preferentially produce C8 to C18 paraffin compounds for use as aerospace fuels. Progress towards this goal will eventually be updated and achieved by a more thorough understanding of the characterization of catalyst materials. This work was supported by NASA s Subsonic Fixed Wing and In-situ Resource Utilization projects.

  10. Potential production of energy cane for fuel in the Caribbean

    SciTech Connect

    Samuels, G.

    1984-12-01

    Sugarcane presents a tremendous potential as a renewable energy source for the non-oil producing countries of the Caribbean. The energy cane concept is sugarcane managed for maximum dry matter (total fermentable solids for alcohol fuel and combustible solids for electricity) rather than sucrose. The use of sugarcane as a renewable energy source can provide a solution, either partial or total, to the Caribbean energy problem. Sugar cane production and the use of this crop as a renewable energy source are described.

  11. Preliminary Economics for Hydrocarbon Fuel Production from Cellulosic Sugars

    SciTech Connect

    Collett, James R.; Meyer, Pimphan A.; Jones, Susanne B.

    2014-05-18

    Biorefinery process and economic models built in CHEMCAD and a preliminary, genome-scale metabolic model for the oleaginous yeast Lipomyces starkeyi were used to simulate the bioconversion of corn stover to lipids, and the upgrading of these hydrocarbon precursors to diesel and jet fuel. The metabolic model was based on the recently released genome sequence for L. starkeyi and on metabolic pathway information from the literature. The process model was based on bioconversion, lipid extraction, and lipid oil upgrading data found in literature, on new laboratory experimental data, and on yield predictions from the preliminary L. starkeyi metabolic model. The current plant gate production cost for a distillate-range hydrocarbon fuel was estimated by the process model Base Case to be $9.5/gallon ($9.0 /gallon of gasoline equivalent) with assumptions of 2011$, 10% internal return on investment, and 2205 ton/day dry feed rate. Opportunities for reducing the cost to below $5.0/gallon, such as improving bioconversion lipid yield and hydrogenation catalyst selectivity, are presented in a Target Case. The process and economic models developed for this work will be updated in 2014 with new experimental data and predictions from a refined metabolic network model for L. starkeyi. Attaining a production cost of $3.0/gallon will require finding higher value uses for lignin other than power generation, such as conversion to additional fuel or to a co-product.

  12. Engineering microbial electrocatalysis for chemical and fuel production.

    PubMed

    Rosenbaum, Miriam A; Henrich, Alexander W

    2014-10-01

    In many biotechnological areas, metabolic engineering and synthetic biology have become core technologies for biocatalyst development. Microbial electrocatalysis for biochemical and fuel production is still in its infancy and reactions rates and the product spectrum are currently very low. Therefore, molecular engineering strategies will be crucial for the advancement and realization of many new bioproduction routes using electroactive microorganisms. The complex and unresolved biochemistry and physiology of extracellular electron transfer and the lack of molecular tools for these new non-model hosts for genetic engineering constitute the major challenges for this effort. This review is providing an insight into the current status, challenges and promising approaches of pathway engineering for microbial electrocatalysis.

  13. Biomass Biorefinery for the production of Polymers and Fuels

    SciTech Connect

    Dr. Oliver P. Peoples

    2008-05-05

    The conversion of biomass crops to fuel is receiving considerable attention as a means to reduce our dependence on foreign oil imports and to meet future energy needs. Besides their use for fuel, biomass crops are an attractive vehicle for producing value added products such as biopolymers. Metabolix, Inc. of Cambridge proposes to develop methods for producing biodegradable polymers polyhydroxyalkanoates (PHAs) in green tissue plants as well as utilizating residual plant biomass after polymer extraction for fuel generation to offset the energy required for polymer extraction. The primary plant target is switchgrass, and backup targets are alfalfa and tobacco. The combined polymer and fuel production from the transgenic biomass crops establishes a biorefinery that has the potential to reduce the nation’s dependence on foreign oil imports for both the feedstocks and energy needed for plastic production. Concerns about the widespread use of transgenic crops and the grower’s ability to prevent the contamination of the surrounding environment with foreign genes will be addressed by incorporating and expanding on some of the latest plant biotechnology developed by the project partners of this proposal. This proposal also addresses extraction of PHAs from biomass, modification of PHAs so that they have suitable properties for large volume polymer applications, processing of the PHAs using conversion processes now practiced at large scale (e.g., to film, fiber, and molded parts), conversion of PHA polymers to chemical building blocks, and demonstration of the usefulness of PHAs in large volume applications. The biodegradability of PHAs can also help to reduce solid waste in our landfills. If successful, this program will reduce U.S. dependence on imported oil, as well as contribute jobs and revenue to the agricultural economy and reduce the overall emissions of carbon to the atmosphere.

  14. Metabolic engineering of yeast for production of fuels and chemicals.

    PubMed

    Nielsen, Jens; Larsson, Christer; van Maris, Antonius; Pronk, Jack

    2013-06-01

    Microbial production of fuels and chemicals from renewable carbohydrate feedstocks offers sustainable and economically attractive alternatives to their petroleum-based production. The yeast Saccharomyces cerevisiae offers many advantages as a platform cell factory for such applications. Already applied on a huge scale for bioethanol production, this yeast is easy to genetically engineer, its physiology, metabolism and genetics have been intensively studied and its robustness enables it to handle harsh industrial conditions. Introduction of novel pathways and optimization of its native cellular processes by metabolic engineering are rapidly expanding its range of cell-factory applications. Here we review recent scientific progress in metabolic engineering of S. cerevisiae for the production of bioethanol, advanced biofuels, and chemicals. PMID:23611565

  15. Production, quality and quality assurance of Refuse Derived Fuels (RDFs).

    PubMed

    Sarc, R; Lorber, K E

    2013-09-01

    This contribution describes characterization, classification, production, application and quality assurance of Refuse Derived Fuels (RDFs) that are increasingly used in a wide range of co-incineration plants. It is shown in this paper, that the fuel-parameter, i.e. net calorific value [MJ/kg(OS)], particle size d(90) or d(95) [mm], impurities [w%], chlorine content [w%], sulfur content [w%], fluorine content [w%], ash content [w%], moisture [w%] and heavy metals content [mg/kg(DM)], can be preferentially used for the classification of different types of RDF applied for co-incineration and substitution of fossil-fuel in different industial sectors. Describing the external production of RDF by processing and confectioning of wastes as well as internal processing of waste at the incineration plant, a case study is reported on the application of RDF made out of different household waste fractions in a 120,000t/yr Waste to Energy (WtE) circulating fluidized bed (CFB) incinerator. For that purpose, delivered wastes, as well as incinerator feedstock material (i.e. after internal waste processing) are extensively investigated. Starting with elaboration of sampling plan in accordance with the relevant guidelines and standards, waste from different suppliers was sampled. Moreover, manual sorting analyses and chemical analyses were carried out. Finally, results of investigations are presented and discussed in the paper. PMID:23746983

  16. Symbiotic Nuclear—Coal Systems for Production of Liquid Fuels

    NASA Astrophysics Data System (ADS)

    Taczanowski, S.

    The notion of safety is not confined to the technological or non-proliferation aspects. It covers also the elements of energy policy: irrational reactions of societies, emotions, egoistic interests of more or less powerful pressure of economical and external political factors. One should be conscious that the country's privilege of being equipped by the Nature with rich resources of oil or gas is not solely economical, but even more a political one. Simultaneously, the gradual depletion of world hydrocarbons that draws behind irrevocable price increase has to be expected within the time scale of exploitation of power plants (now amounted to ~60 years). Therefore consequences of energy policy last much longer than the perspectives the political or economical decision makers are planning and acting within and the public is expecting successes and finally evaluating them. The world oil and gas resources are geopolitically very non-uniformly distributed, in contrast to coal and uranium. Since the level of energy self-sufficiency of the EU is highest for coal, the old idea of synfuels production from coal is recalled. Yet, in view of limits to the CO2 emissions in the EU another method has to be used here than the conventional coal liquefaction just applied in China. Simultaneously, an interesting evolution of energy prices was be observed, namely an increase in that of motor fuels in contrast to that of electricity remaining well stable. This fact suggests that the use of electricity (mainly the off-peak load), generated without emissions of CO2 for production of liquid fuels can prove reasonable. Thus, the essence of the presented idea of coal-nuclear symbiosis lies in the supply of energy in the form of H2, necessary for this process, from a nuclear reactor. Particularly, in the present option H2 is obtained by electrolytic water splitting supplying also O2 as a precious by-product in well mature and commercially available already since decades, Light Water Reactors

  17. Microbial production of fatty acid-derived fuels and chemicals

    PubMed Central

    Lennen, Rebecca M; Pfleger, Brian F

    2013-01-01

    Fatty acid metabolism is an attractive route to produce liquid transportation fuels and commodity oleochemicals from renewable feedstocks. Recently, genes and enzymes, which comprise metabolic pathways for producing fatty acid-derived compounds (e.g. esters, alkanes, olefins, ketones, alcohols, polyesters) have been elucidated and used in engineered microbial hosts. The resulting strains often generate products at low percentages of maximum theoretical yields, leaving significant room for metabolic engineering. Economically viable processes will require strains to approach theoretical yields, particularly for replacement of petroleum-derived fuels. This review will describe recent progress toward this goal, highlighting the scientific discoveries of each pathway, ongoing biochemical studies to understand each enzyme, and metabolic engineering strategies that are being used to improve strain performance. PMID:23541503

  18. Chemical Characterization and Reactivity of Fuel-Oxidizer Reaction Product

    NASA Technical Reports Server (NTRS)

    David, Dennis D.; Dee, Louis A.; Beeson, Harold D.

    1997-01-01

    Fuel-oxidizer reaction product (FORP), the product of incomplete reaction of monomethylhydrazine and nitrogen tetroxide propellants prepared under laboratory conditions and from firings of Shuttle Reaction Control System thrusters, has been characterized by chemical and thermal analysis. The composition of FORP is variable but falls within a limited range of compositions that depend on three factors: the fuel-oxidizer ratio at the time of formation; whether the composition of the post-formation atmosphere is reducing or oxidizing; and the reaction or post-reaction temperature. A typical composition contains methylhydrazinium nitrate, ammonium nitrate, methylammonium nitrate, and trace amounts of hydrazinium nitrate and 1,1-dimethylhydrazinium nitrate. Thermal decomposition reactions of the FORP compositions used in this study were unremarkable. Neither the various compositions of FORP, the pure major components of FORP, nor mixtures of FORP with propellant system corrosion products showed any unusual thermal activity when decomposed under laboratory conditions. Off-limit thruster operations were simulated by rapid mixing of liquid monomethylhydrazine and liquid nitrogen tetroxide in a confined space. These tests demonstrated that monomethylhydrazine, methylhydrazinium nitrate, ammonium nitrate, or Inconel corrosion products can induce a mixture of monomethylhydrazine and nitrogen tetroxide to produce component-damaging energies. Damaging events required FORP or metal salts to be present at the initial mixing of monomethylhydrazine and nitrogen tetroxide.

  19. Reaction products of amido-amine and epoxide useful as fuel additives

    SciTech Connect

    Efner, H.F.

    1988-04-12

    A method for reducing engine deposits in an internal combustion engine is described comprising the addition of a detergent fuel additive package to a hydrocarbon fuel for the engine. The fuel detergent is added in an amount effective to reduce deposits and the hydrocarbon fuel is used with detergent additive as fuel in an internal combustion engine. The detergent fuel additive package comprises: (1) a fuel detergent additive that is the reaction product prepared by reacting (a) vegetable oil or (b) higher carboxylic acid chosen from (i) aliphatic fatty acids having 10-25 carbon atoms and (ii) aralkyl acids having 12-42 carbon atoms with (c) multiamine to obtain a fist product mixture with the first product mixture reacted with alklylene oxide to produce a second product mixture and (2) a fuel detergent additive solvent compatible with the fuels.

  20. Energy Supply- Production of Fuel from Agricultural and Animal Waste

    SciTech Connect

    Gabriel Miller

    2009-03-25

    The Society for Energy and Environmental Research (SEER) was funded in March 2004 by the Department of Energy, under grant DE-FG-36-04GO14268, to produce a study, and oversee construction and implementation, for the thermo-chemical production of fuel from agricultural and animal waste. The grant focuses on the Changing World Technologies (CWT) of West Hempstead, NY, thermal conversion process (TCP), which converts animal residues and industrial food processing biproducts into fuels, and as an additional product, fertilizers. A commercial plant was designed and built by CWT, partially using grant funds, in Carthage, Missouri, to process animal residues from a nearby turkey processing plant. The DOE sponsored program consisted of four tasks. These were: Task 1 Optimization of the CWT Plant in Carthage - This task focused on advancing and optimizing the process plant operated by CWT that converts organic waste to fuel and energy. Task 2 Characterize and Validate Fuels Produced by CWT - This task focused on testing of bio-derived hydrocarbon fuels from the Carthage plant in power generating equipment to determine the regulatory compliance of emissions and overall performance of the fuel. Task 3 Characterize Mixed Waste Streams - This task focused on studies performed at Princeton University to better characterize mixed waste incoming streams from animal and vegetable residues. Task 4 Fundamental Research in Waste Processing Technologies - This task focused on studies performed at the Massachusetts Institute of Technology (MIT) on the chemical reformation reaction of agricultural biomass compounds in a hydrothermal medium. Many of the challenges to optimize, improve and perfect the technology, equipment and processes in order to provide an economically viable means of creating sustainable energy were identified in the DOE Stage Gate Review, whose summary report was issued on July 30, 2004. This summary report appears herein as Appendix 1, and the findings of the report

  1. Solid oxide fuel cell electrode characterization and improvement for fuel flexibility and supplemental power production

    NASA Astrophysics Data System (ADS)

    Kellogg, Isaiah Daniel

    2010-03-01

    Solid oxide fuel cells (SOFC) were fabricated and the electrodes tested for their individual catalytic effectiveness in various fuels by exposing each electrode to mixed gas while the opposite electrode was exposed to its respective pure gas. Mixed hydrogen and oxygen gas was successfully utilized as fuel in a single chamber SOFC (SC-SOFC). The conditions at which the porous nickel-yttria-stabilized zirconia (Ni-YSZ) cermet anode performed well did not significantly overlap the conditions at which the La0.8Sr 0.2Fe0.8Co0.2 oxide (LSCF) cathode performed well, but there was significant catalytic activity at both electrodes which increased the open circuit voltage (OCV) beyond that predicted by the Nernst equation. The results of these tests, and future tests of similar format, could be useful in the development of SC-SOFC electrode catalysts. Pyrolytic carbon was used as fuel in a SOFC with a YSZ electrolyte and a bi-layer anode composed of nickel gadolinia-doped ceria (Ni-GDC) and Ni-YSZ. The common problems of bulk shrinkage and emergent porosity in the YSZ layer adjacent to the GDC/YSZ interface were avoided by using an interlayer of porous Ni-YSZ as a buffer anode layer between the electrolyte and the Ni-GDC primary anode. Cells were fabricated from commercially available component powders so that unconventional production methods suggested in the literature were avoided. A cell of similar construction was used with externally applied acetylene flame soot as fuel so that soot captured at the exhaust of a diesel engine could be utilized for secondary power generation in a SOFC while decreasing particulate pollution without the need for filter regeneration.

  2. Risks to global biodiversity from fossil-fuel production exceed those from biofuel production

    SciTech Connect

    Dale, Virginia H.; Parish, Esther S.; Kline, Keith L.

    2014-12-02

    Potential global biodiversity impacts from near-term gasoline production are compared to biofuel, a renewable liquid transportation fuel expected to substitute for gasoline in the near term (i.e., from now until c. 2030). Petroleum exploration activities are projected to extend across more than 5.8 billion ha of land and ocean worldwide (of which 3.1 billion is on land), much of which is in remote, fragile terrestrial ecosystems or off-shore oil fields that would remain relatively undisturbed if not for interest in fossil fuel production. Future biomass production for biofuels is projected to fall within 2.0 billion ha of land, most of which is located in areas already impacted by human activities. A comparison of likely fuel-source areas to the geospatial distribution of species reveals that both energy sources overlap with areas with high species richness and large numbers of threatened species. At the global scale, future petroleum production areas intersect more than double the area and higher total number of threatened species than future biofuel production. Energy options should be developed to optimize provisioning of ecosystem services while minimizing negative effects, which requires information about potential impacts on critical resources. Furthermore, energy conservation and identifying and effectively protecting habitats with high-conservation value are critical first steps toward protecting biodiversity under any fuel production scenario.

  3. Risks to global biodiversity from fossil-fuel production exceed those from biofuel production

    DOE PAGES

    Dale, Virginia H.; Parish, Esther S.; Kline, Keith L.

    2014-12-02

    Potential global biodiversity impacts from near-term gasoline production are compared to biofuel, a renewable liquid transportation fuel expected to substitute for gasoline in the near term (i.e., from now until c. 2030). Petroleum exploration activities are projected to extend across more than 5.8 billion ha of land and ocean worldwide (of which 3.1 billion is on land), much of which is in remote, fragile terrestrial ecosystems or off-shore oil fields that would remain relatively undisturbed if not for interest in fossil fuel production. Future biomass production for biofuels is projected to fall within 2.0 billion ha of land, most ofmore » which is located in areas already impacted by human activities. A comparison of likely fuel-source areas to the geospatial distribution of species reveals that both energy sources overlap with areas with high species richness and large numbers of threatened species. At the global scale, future petroleum production areas intersect more than double the area and higher total number of threatened species than future biofuel production. Energy options should be developed to optimize provisioning of ecosystem services while minimizing negative effects, which requires information about potential impacts on critical resources. Furthermore, energy conservation and identifying and effectively protecting habitats with high-conservation value are critical first steps toward protecting biodiversity under any fuel production scenario.« less

  4. Coal Water Fuels: Production process modifications; their impact on fuel specifications

    SciTech Connect

    Goodman, R.M.

    1986-01-01

    Coal Water Fuels (CWF) have a tremendous potential in the US Energy market. There is an ''oil glut'' and cheap oil is readily available at least in the near term future. Thus, whether future oil shortages and concomitant price escalations for oil are ''just-around-the-corner'' or off in the 21st Century, is a matter for great current debate. The recent indications of price collapse further fuel this debate. Unfortunately, it is only in the future that the correct answer will become apparent. Prudence dictates, however, that survival for a CWF supplier in early 1986, must be predicated on flexibility. It is clear that the most flexible technology and most adaptive supplier network will have the best chance to become successful in the currently difficult CWF market. The Carbogel organization enjoys tremendous flexibility in approach to CWF development and production. Further, the Carbogel technology development program, from its inception, has stressed flexibility and adaptability to different requirements.

  5. Bio-Fuel Production Assisted with High Temperature Steam Electrolysis

    SciTech Connect

    Grant Hawkes; James O'Brien; Michael McKellar

    2012-06-01

    Two hybrid energy processes that enable production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure are presented. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), these two hybrid energy processes have the potential to provide a significant alternative petroleum source that could reduce dependence on imported oil. The first process discusses a hydropyrolysis unit with hydrogen addition from HTSE. Non-food biomass is pyrolyzed and converted to pyrolysis oil. The pyrolysis oil is upgraded with hydrogen addition from HTSE. This addition of hydrogen deoxygenates the pyrolysis oil and increases the pH to a tolerable level for transportation. The final product is synthetic crude that could then be transported to a refinery and input into the already used transportation fuel infrastructure. The second process discusses a process named Bio-Syntrolysis. The Bio-Syntrolysis process combines hydrogen from HTSE with CO from an oxygen-blown biomass gasifier that yields syngas to be used as a feedstock for synthesis of liquid synthetic crude. Conversion of syngas to liquid synthetic crude, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model

  6. Production of fuels and chemicals from apple pomace

    SciTech Connect

    Hang, Y.D.

    1987-03-01

    Nearly 36 million tons of apples are produced annually in the US. Approximately 45% of the total US apple production is used for processing purposes. The primary by-product of apple processing is apple pomace. It consists of the presscake resulting from pressing apples for juice or cider, including the presscake obtained in pressing peel and core wastes generated in the manufacture of apple sauce or slices. More than 500 food processing plants in the US produce a total of about 1.3 million metric tons of apple pomace each year, and it is likely that annual disposal fees exceed $10 million. Apple pomace has the potential to be used for the production of fuels (ethanol and biogas containing 60% methane) and food-grade chemicals. These uses will be reviewed in this article.

  7. [Biodiesel fuel production from lipids of filamentous fungi].

    PubMed

    Lunin, V V; Sergeev, Ia É; Galanina, L A; Mysiakina, I S; Ivashechkin, A A; Bogdan, V I; Feofilova, E P

    2013-01-01

    The main stages in the production of biodiesel fuel from lipids of filamentous fungi belonging to the order Mucorales are described. Fungi of the family Cunninghamellaceae have been screened; the lipogenic activity of the examined strains has been assessed; and a producer generating up to 50% of lipids, represented by triacylglycerols, has been found. The substitution effect of a source of carbon and nitrogen with less expensive components (in particular, various industrial wastes) has been studied, as well as their influence on the quantity and major characteristics of the final product. An ecologically friendly method for extracting lipids from fungal mycelia, utilizing supercritical technologies, has been used. A correlation between the lipid content in the spore inoculum and the maximal lipid content in biomass has been discovered; this correlation is proposed for optimizing the biotechnology and increasing the yield of final products.

  8. Investigating the potential for subsurface primary production fueled by serpentinization

    NASA Astrophysics Data System (ADS)

    Brazelton, W. J.; Nelson, B. Y.; Schrenk, M. O.

    2011-12-01

    Ultramafic rocks in the Earth's mantle represent a tremendous reservoir of carbon and reducing power. Tectonic uplift of these materials into the crust can result in serpentinization, a highly exothermic geochemical reaction that releases hydrogen gas (H2) and promotes the abiogenic synthesis of organic molecules. The extent and activity of microbial communities in serpentinite-hosted subsurface habitats is almost entirely unknown, but they clearly have great potential to host extensive sunlight-independent primary production fueled by H2 and abiotic carbon compounds. We have been testing this hypothesis at several sites of serpentinization around the globe utilizing a suite of techniques including metagenomics, 16S rRNA pyrotag sequencing, and stable isotope tracing experiments. All four of our study sites, which include deep-sea hydrothermal vents, terrestrial alkaline springs, and continental drill holes, are characteristically low in archaeal and bacterial genetic diversity. In carbonate chimneys of the Lost City hydrothermal field (Mid-Atlantic Ridge), for example, a single archaeal phylotype dominates the biofilm community. Stable isotope tracing experiments indicated that these archaeal biofilms are capable of both production and anaerobic oxidation of methane at 80C and pH 10. Both production and oxidation were stimulated by H2, suggesting a possible syntrophic relationship among cells within the biofilm. Preliminary results from similar stable isotope tracing experiments at terrestrial alkaline seeps at the Tablelands Ophiolite (Newfoundland), Ligurian springs (Italy), and McLaughlin Reserve (California) have indicated the potential for microbial activity fueled by H2 and acetate. Furthermore, recent metagenomic sequencing of fluids from the Tablelands and Ligurian springs have revealed genomic potential for chemolithotrophy powered by iron reduction with H2. In summary, these data support the potential for extensive microbial activity fueled by

  9. Production of fuel alcohol from Jerusalem artichoke tops

    SciTech Connect

    Not Available

    1983-01-01

    The objective of this research program is to demonstrate fuel alcohol production in New Mexico using the Jerusalem artichoke and local resources. This final report summarizes progress made during the course of the project. The planting and cultivation of the tubers are described as well as the construction of the ethanol plant. During the grinding of the tubers, the Bowie gear pump failed and a larger Mayo pump was purchased. Results indicate that Jerusalem artichokes will grow well in this area of New Mexico; water requirements are about the same as for corn and cultivation is only necessary until plant height is 18 inches. (DMC)

  10. Fuel NOx production during the combustion of low caloric value fuel

    SciTech Connect

    Colaluca, M.A.; Caraway, J.P.

    1997-07-01

    The objective of this investigation is to identify and qualify physical mechanisms and parameters that affect the combustion of low caloric value gases (LCVG) and the formation of NOx pollutants produced form fuel bound nitrogen. Average physical properties of a low caloric value gas were determined from the products of several industrial coal gasifiers. A computer model was developed, utilizing the PHOENICS computational fluid dynamics software to model the combustion of LCVG. The model incorporates a 3-dimensional physical design and is based on typical industrial combustors. Feed stock to the gasifier can be wood, feed stock manure, cotton gin trash, coal, lignite and numerous forms of organic industrial wastes.

  11. Pathways to Commercial Success. Technologies and Products Supported by the Fuel Cell Technologies Program

    SciTech Connect

    none,

    2010-08-01

    This report identifies the commercial and near-commercial (emerging) hydrogen and fuel cell technologies and products that resulted from Department of Energy support through the Fuel Cell Technologies Program in the Office of Energy Efficiency and Renewable Energy.

  12. Sweet sorghum biorefinery for production of fuel ethanol and value-added co-products

    Technology Transfer Automated Retrieval System (TEKTRAN)

    An integrated process has been developed for a sweet-sorghum biorefinery in which all carbohydrate components of the feedstock were used for production of fuel ethanol and industrial chemicals. In the first step, the juice was extracted from the stalks. The resulted straw (bagasse) then was pretreat...

  13. Volatile organic compound emissions from dry mill fuel ethanol production.

    PubMed

    Brady, Daniel; Pratt, Gregory C

    2007-09-01

    Ethanol fuel production is growing rapidly in the rural Midwest, and this growth presents potential environmental impacts. In 2002, the U.S. Environmental Protection Agency (EPA) and the Minnesota Pollution Control Agency (MPCA) entered into enforcement actions with 12 fuel ethanol plants in Minnesota. The enforcement actions uncovered underreported emissions and resulted in consent decrees that required pollution control equipment be installed. A key component of the consent decrees was a requirement to conduct emissions tests for volatile organic compounds (VOCs) with the goal of improving the characterization and control of emissions. The conventional VOC stack test method was thought to underquantify total VOC emissions from ethanol plants. A hybrid test method was also developed that involved quantification of individual VOC species. The resulting database of total and speciated VOC emissions from 10 fuel ethanol plants is relatively small, but it is the most extensive to date and has been used to develop and gauge compliance with permit limits and to estimate health risks in Minnesota. Emissions were highly variable among facilities and emissions units. In addition to the variability, the small number of samples and the presence of many values below detection limits complicate the analysis of the data. To account for these issues, a nested bootstrap procedure on the Kaplan-Meier method was used to calculate means and upper confidence limits. In general, the fermentation scrubbers and fluid bed coolers emitted the largest mass of VOC emissions. Across most facilities and emissions units ethanol was the pollutant emitted at the highest rate. Acetaldehyde, acetic acid, and ethyl acetate were also important emissions from some units. Emissions of total VOCs, ethanol, and some other species appeared to be a function of the beer feed rate, although the relationship was not reliable enough to develop a production rate-based emissions factor.

  14. Fischer-Tropsch Catalyst for Aviation Fuel Production

    NASA Technical Reports Server (NTRS)

    deLaRee, Ana B.; Best, Lauren M.; Hepp, Aloysius F.

    2011-01-01

    As the oil supply declines, there is a greater need for cleaner alternative fuels. There will undoubtedly be a shift from crude oil to non-petroleum sources as a feedstock for aviation (and other transportation) fuels. The Fischer-Tropsch process uses a gas mixture of carbon monoxide and hydrogen which is converted into various liquid hydrocarbons; this versatile gas-to-liquid technology produces a complex product stream of paraffins, olefins, and oxygenated compounds such as alcohols and aldehydes. The Fischer-Tropsch process can produce a cleaner diesel oil fraction with a high cetane number (typically above 70) without any sulfur and aromatic compounds. It is most commonly catalyzed by cobalt supported on alumina, silica, or titania or unsupported alloyed iron powders. Cobalt is typically used more often than iron, in that cobalt is a longer-active catalyst, has lower water-gas shift activity, and lower yield of modified products. Promoters are valuable in improving Fischer-Tropsch catalyst as they can increase cobalt oxide dispersion, enhance the reduction of cobalt oxide to the active metal phase, stabilize a high metal surface area, and improve mechanical properties. Our goal is to build up the specificity of the Fischer-Tropsch catalyst while adding less-costly transition metals as promoters; the more common promoters used in Fischer-Tropsch synthesis are rhenium, platinum, and ruthenium. In this report we will describe our preliminary efforts to design and produce catalyst materials to achieve our goal of preferentially producing C8 to C18 paraffin compounds in the NASA Glenn Research Center Gas-To-Liquid processing plant. Efforts at NASA Glenn Research Center for producing green fuels using non-petroleum feedstocks support both the Sub-sonic Fixed Wing program of Fundamental Aeronautics and the In Situ Resource Utilization program of the Exploration Technology Development and Demonstration program.

  15. Fischer-Tropsch Catalyst for Aviation Fuel Production

    NASA Technical Reports Server (NTRS)

    DeLaRee, Ana B.; Best, Lauren M.; Bradford, Robyn L.; Gonzalez-Arroyo, Richard; Hepp, Aloysius F.

    2012-01-01

    As the oil supply declines, there is a greater need for cleaner alternative fuels. There will undoubtedly be a shift from crude oil to nonpetroleum sources as a feedstock for aviation (and other transportation) fuels. The Fischer-Tropsch process uses a gas mixture of carbon monoxide and hydrogen which is converted into various liquid hydrocarbons; this versatile gas-to-liquid technology produces a complex product stream of paraffins, olefins, and oxygenated compounds such as alcohols and aldehydes. The Fischer-Tropsch process can produce a cleaner diesel oil fraction with a high cetane number (typically above 70) without any sulfur and aromatic compounds. It is most commonly catalyzed by cobalt supported on alumina, silica, or titania or unsupported alloyed iron powders. Cobalt is typically used more often than iron, in that cobalt is a longer-active catalyst, has lower water-gas shift activity, and lower yield of modified products. Promoters are valuable in improving Fischer-Tropsch catalyst as they can increase cobalt oxide dispersion, enhance the reduction of cobalt oxide to the active metal phase, stabilize a high metal surface area, and improve mechanical properties. Our goal is to build up the specificity of the Fischer-Tropsch catalyst while adding less-costly transition metals as promoters; the more common promoters used in Fischer-Tropsch synthesis are rhenium, platinum, and ruthenium. In this report we will describe our preliminary efforts to design and produce catalyst materials to achieve our goal of preferentially producing C8 to C18 paraffin compounds in the NASA Glenn Research Center Gas-To-Liquid processing plant. Efforts at NASA Glenn Research Center for producing green fuels using non-petroleum feedstocks support both the Sub-sonic Fixed Wing program of Fundamental Aeronautics and the In Situ Resource Utilization program of the Exploration Technology Development and Demonstration program.

  16. Process for the production of fuels and metal values

    SciTech Connect

    Audeh, C.A.

    1983-06-28

    A process for producing liquid fuels and for recovering metal values from crude petroleum by vis-breaking the reduced crude petroleum and dealkylating the vis-broken, reduced crude by treatment with an aromatic compound and an acidic transalkylation catalyst. The liquid product from the dealkylation step is separated and the residue fraction thermally processed with coal to solubilize the coal in the aromatic residue and demetallate the residue with the coal. The coal is partly liquefied in this step and the liquefaction products, together with liquids derived from the petroleum, may be hydrotreated prior to further processing e.g., in an fcc unit. The solid residue from this step may be treated to recover the metal values, especially nickel and vanadium.

  17. Characterization of Cassini GPHS Fueled-Clad Production Girth Welds

    SciTech Connect

    Franco-Ferreira, E.A.

    2000-03-23

    Fueled clads for radioisotope power systems are produced by encapsulating {sup 238}PuO{sub 2} in iridium alloy cups, which are joined at their equators by gas tungsten arc welding. Cracking problems at the girth weld tie-in area during production of the Galileo/Ulysses GPHS capsules led to the development of a first-generation ultrasonic test for girth weld inspection at the Savannah River Plant. A second-generation test and equipment with significantly improved sensitivity and accuracy were jointly developed by the Oak Ridge Y-12 Plant and Westinghouse Savannah River Company for use during the production of Cassini GPHS capsules by the Los Alamos National Laboratory. The test consisted of Lamb wave ultrasonic scanning of the entire girth weld from each end of the capsule combined with a time-of-flight evaluation to aid in characterizing nonrelevant indications. Tangential radiography was also used as a supplementary test for further evaluation of reflector geometry. Each of the 317 fueled GPHS capsules, which were girth welded for the Cassini Program, was subjected to a series of nondestructive tests that included visual, dimensional, helium leak rate, and ultrasonic testing. Thirty-three capsules were rejected prior to ultrasonic testing. Of the 44 capsules rejected by the standard ultrasonic test, 22 were upgraded to flight quality through supplementary testing for an overall process acceptance rate of 82.6%. No confirmed instances of weld cracking were found.

  18. Thermocatalytic CO2-Free Production of Hydrogen from Hydrocarbon Fuels

    SciTech Connect

    University of Central Florida

    2004-01-30

    The main objective of this project is the development of an economically viable thermocatalytic process for production of hydrogen and carbon from natural gas or other hydrocarbon fuels with minimal environmental impact. The three major technical goals of this project are: (1) to accomplish efficient production of hydrogen and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive and durable carbon catalysts, (2) to obviate the concurrent production of CO/CO{sub 2} byproducts and drastically reduce CO{sub 2} emissions from the process, and (3) to produce valuable carbon products in order to reduce the cost of hydrogen production The important feature of the process is that the reaction is catalyzed by carbon particulates produced in the process, so no external catalyst is required (except for the start-up operation). This results in the following advantages: (1) no CO/CO{sub 2} byproducts are generated during hydrocarbon decomposition stage, (2) no expensive catalysts are used in the process, (3) several valuable forms of carbon can be produced in the process depending on the process conditions (e.g., turbostratic carbon, pyrolytic graphite, spherical carbon particles, carbon filaments etc.), and (4) CO{sub 2} emissions could be drastically reduced (compared to conventional processes).

  19. Molten salt extraction of transuranic and reactive fission products from used uranium oxide fuel

    DOEpatents

    Herrmann, Steven Douglas

    2014-05-27

    Used uranium oxide fuel is detoxified by extracting transuranic and reactive fission products into molten salt. By contacting declad and crushed used uranium oxide fuel with a molten halide salt containing a minor fraction of the respective uranium trihalide, transuranic and reactive fission products partition from the fuel to the molten salt phase, while uranium oxide and non-reactive, or noble metal, fission products remain in an insoluble solid phase. The salt is then separated from the fuel via draining and distillation. By this method, the bulk of the decay heat, fission poisoning capacity, and radiotoxicity are removed from the used fuel. The remaining radioactivity from the noble metal fission products in the detoxified fuel is primarily limited to soft beta emitters. The extracted transuranic and reactive fission products are amenable to existing technologies for group uranium/transuranic product recovery and fission product immobilization in engineered waste forms.

  20. Fuel alcohol: report and analysis of plant conversion potential to fuel alcohol production

    SciTech Connect

    Not Available

    1980-09-01

    An analysis is made of the national potential to convert and/or to retrofit existing plants to process their present feedstock into fuel alcohol in lieu of their originally designed final product. Categories of plants examined are distilleries, breweries, corn wet milling, beet and cane sugar mills, wineries, cheese whey, and other food processing. Outline descriptions are developed for a base-case plant in each of the industries found to be a viable contributor to a fuel alcohol program. These base-case plants are illustrative of plant size, estimated capital costs of conversion, operating costs, labor estimates for daily operation, and estimated time schedules for comparison purposes. The facilities described as convertible could begin making alcohol by 1982, with a total of 581 million gallons of ethanol identified by 1985 and an additional 300 million gallons being possible. Thus with current production, these additional volumes can largely meet the President's 1982 ethanol goal, and can contribute greatly to the 1985 goal. A glossary is included.

  1. A novel biochemical platform for fuels and chemicals production from cellulosic biomass

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The conventional biochemical platform for biofuels production featuring enzymatic hydrolysis involves five key steps: pretreatment, cellulase production, enzymatic hydrolysis, fermentation, and product recovery. Sugars are produced as reactive intermediates for subsequent fermentation to fuels and c...

  2. Use of MRF residue as alternative fuel in cement production.

    PubMed

    Fyffe, John R; Breckel, Alex C; Townsend, Aaron K; Webber, Michael E

    2016-01-01

    Single-stream recycling has helped divert millions of metric tons of waste from landfills in the U.S., where recycling rates for municipal solid waste are currently over 30%. However, material recovery facilities (MRFs) that sort the municipal recycled streams do not recover 100% of the incoming material. Consequently, they landfill between 5% and 15% of total processed material as residue. This residue is primarily composed of high-energy-content non-recycled plastics and fiber. One possible end-of-life solution for these energy-dense materials is to process the residue into Solid Recovered Fuel (SRF) that can be used as an alternative energy resource capable of replacing or supplementing fuel resources such as coal, natural gas, petroleum coke, or biomass in many industrial and power production processes. This report addresses the energetic and environmental benefits and trade-offs of converting non-recycled post-consumer plastics and fiber derived from MRF residue streams into SRF for use in a cement kiln. An experimental test burn of 118 Mg of SRF in the precalciner portion of the cement kiln was conducted. The SRF was a blend of 60% MRF residue and 40% post-industrial waste products producing an estimated 60% plastic and 40% fibrous material mixture. The SRF was fed into the kiln at 0.9 Mg/h for 24h and then 1.8 Mg/h for the following 48 h. The emissions data recorded in the experimental test burn were used to perform the life-cycle analysis portion of this study. The analysis included the following steps: transportation, landfill, processing and fuel combustion at the cement kiln. The energy use and emissions at each step is tracked for the two cases: (1) The Reference Case, where MRF residue is disposed of in a landfill and the cement kiln uses coal as its fuel source, and (2) The SRF Case, in which MRF residue is processed into SRF and used to offset some portion of coal use at the cement kiln. The experimental test burn and accompanying analysis indicate

  3. Use of MRF residue as alternative fuel in cement production.

    PubMed

    Fyffe, John R; Breckel, Alex C; Townsend, Aaron K; Webber, Michael E

    2016-01-01

    Single-stream recycling has helped divert millions of metric tons of waste from landfills in the U.S., where recycling rates for municipal solid waste are currently over 30%. However, material recovery facilities (MRFs) that sort the municipal recycled streams do not recover 100% of the incoming material. Consequently, they landfill between 5% and 15% of total processed material as residue. This residue is primarily composed of high-energy-content non-recycled plastics and fiber. One possible end-of-life solution for these energy-dense materials is to process the residue into Solid Recovered Fuel (SRF) that can be used as an alternative energy resource capable of replacing or supplementing fuel resources such as coal, natural gas, petroleum coke, or biomass in many industrial and power production processes. This report addresses the energetic and environmental benefits and trade-offs of converting non-recycled post-consumer plastics and fiber derived from MRF residue streams into SRF for use in a cement kiln. An experimental test burn of 118 Mg of SRF in the precalciner portion of the cement kiln was conducted. The SRF was a blend of 60% MRF residue and 40% post-industrial waste products producing an estimated 60% plastic and 40% fibrous material mixture. The SRF was fed into the kiln at 0.9 Mg/h for 24h and then 1.8 Mg/h for the following 48 h. The emissions data recorded in the experimental test burn were used to perform the life-cycle analysis portion of this study. The analysis included the following steps: transportation, landfill, processing and fuel combustion at the cement kiln. The energy use and emissions at each step is tracked for the two cases: (1) The Reference Case, where MRF residue is disposed of in a landfill and the cement kiln uses coal as its fuel source, and (2) The SRF Case, in which MRF residue is processed into SRF and used to offset some portion of coal use at the cement kiln. The experimental test burn and accompanying analysis indicate

  4. Storage and production of hydrogen for fuel cell applications

    NASA Astrophysics Data System (ADS)

    Aiello, Rita

    The increased utilization of proton-exchange membrane (PEM) fuel cells as an alternative to internal combustion engines is expected to increase the demand for hydrogen, which is used as the energy source in these systems. The objective of this work is to develop and test new methods for the storage and production of hydrogen for fuel cells. Six ligand-stabilized hydrides were synthesized and tested as hydrogen storage media for use in portable fuel cells. These novel compounds are more stable than classical hydrides (e.g., NaBH4, LiAlH4) and react to release hydrogen less exothermically upon hydrolysis with water. Three of the compounds produced hydrogen in high yield (88 to 100 percent of the theoretical) and at significantly lower temperatures than those required for the hydrolysis of NaBH4 and LiAlH4. However, a large excess of water and acid were required to completely wet the hydride and keep the pH of the reaction medium neutral. The hydrolysis of the classical hydrides with steam can overcome these limitations. This reaction was studied in a flow reactor and the results indicate that classical hydrides can be hydrolyzed with steam in high yields at low temperatures (110 to 123°C) and in the absence of acid. Although excess steam was required, the pH of the condensed steam was neutral. Consequently, steam could be recycled back to the reactor. Production of hydrogen for large-scale transportation fuel cells is primarily achieved via the steam reforming, partial oxidation or autothermal reforming of natural gas or the steam reforming of methanol. However, in all of these processes CO is a by-product that must be subsequently removed because the Pt-based electrocatalyst used in the fuel cells is poisoned by its presence. The direct cracking of methane over a Ni/SiO2 catalyst can produce CO-free hydrogen. In addition to hydrogen, filamentous carbon is also produced. This material accumulates on the catalyst and eventually deactivates it. The Ni/SiO2 catalyst

  5. Health effects of fossil-fuel combustion products: needed research

    SciTech Connect

    Not Available

    1980-01-01

    An examination is made of the research needed to expand and clarify the understanding of the products of fossil-fuel combustion, chiefly that taking place in stationary sources of power. One of the specific objectives that guided the study on which this report is based was to identify the pollutants potentially hazardous to man that are released into the environment in the course of the combustion of fossil fuels. The hazards of principal concern are those which could cause deleterious, long-term somatic and genetic effects. Another objective was to specify the nature of the research needed to determine the health effects of these pollutants on the general population. Special attention was paid to the interaction of pollutants; the meteorologic and climatic factors that affect the transport, diffusion, and transformation of pollutants; the effects of concentrations of aerosol, particulate, and thermal loads on biologic systems; and the susceptibility of some portions of the population to the effects of pollutants on the skin and cardiovascular, pulmonary, and urinary systems. Other objectives were to evaluate the methods of the proposed research, including analytic and interpretation techniques, to identify fields in which the available scientific information is inadequate for regulatory decision-making and to recommend a research program to meet those deficiencies, and to provide a logical framework within which the necessary information can be developed (the proposed program is presented in terms of subject, methods, and priorities).

  6. Ethyl-alcohol-fuel production from the Jerusalem artichoke. Alcohol-Fuels Grant Program

    SciTech Connect

    Middaugh, P.R.

    1983-03-01

    The project objective is to evaluate the commercial feasibility for production of fuel alcohol by fermentation of the carbohydrates in the tops of the Jerusalem artichoke. The maximum top biomass yields of the mammoth French white variety of Jerusalem artichoke was obtained at 119 days after plant emergence and maximum fresh weight of the tops was 31.6 tons per acre. During rapid growth the fresh stalks had 2% to 4% carbohydrate. After the plant reached a maximum height of 168 inches, and started to bud the stalk had a maximum of 4% carbohydrate. During blossoming the stalk carbohydrates rapidly translocated to the tuber. Single versus multiple cuttings demonstrated the maximum carbohydrate was obtained with a single harvest of the mature plants immediately following bud formation. The total carbohydrate yield from the top biomass was 1.26 tons per acre. The equivalent yield of fermentation alcohol is 180.6 gallons of anhydrous ethanol per acre. The tuber yield at both Mesa and Toppenish, WA, was 14 to 15 tons of fresh tubers with 18% total carbohydrates. The carbohydrate yield was 2.52 tons per acre. This is equivalent to a yield of 360 gallons of anhydrous ethanol per acre. Commercial scale fuel alcohol equipment was used to hammer mill and batch ferment tops and tubers. The steps for commercial processing of the biomass tops and tubers was discussed including extracting and fermentation of the carbohydrates to ethanol and their concentration by distillation and dehydration by molecular sieves to anhydrous fuel alcohol. The use of molecular sieves reduced the energy for dehydration of 95% ethanol to 5000 Btu per gallon. The economic feasibility and energy requirement for commercial processing was discussed.

  7. The chemical state of fission products in oxide fuels at different stages of the nuclear fuel cycle

    SciTech Connect

    Kleykamp, H.

    1988-03-01

    A survey of work at the Kernforschungszentrum Karlsruhe is presented on the chemical state of selected fission products that are relevant in the fuel cycle of light water reactor (LWR) and fast breeder reactor fuels. The influence of fuel type and irradiation progress on the composition of the Mo-Tc-Ru-Rh-Pd fission product alloys precipitated in the oxide matrix is examined using the respective multicomponent phase diagrams. The kinetics of dissolution of these phases in nitric acid at the reprocessing stage is discussed. Composition and structure of the residues, and the reprecipitation phenomena from highly active waste (HAW), are elucidated. A second metamorphosis of the fission products is recognized during the vitrification process. The formation of Ru(Rh) oxide and Pd(Rh, U, Te) alloys in simulated vitrified HAW concentrate and in HAW concentrate from the reprocessing of irradiated LWR fuels in interpreted on the basis of heterogeneous equilibria.

  8. Moving bed reactor for solar thermochemical fuel production

    SciTech Connect

    Ermanoski, Ivan

    2013-04-16

    Reactors and methods for solar thermochemical reactions are disclosed. Embodiments of reactors include at least two distinct reactor chambers between which there is at least a pressure differential. In embodiments, reactive particles are exchanged between chambers during a reaction cycle to thermally reduce the particles at first conditions and oxidize the particles at second conditions to produce chemical work from heat. In embodiments, chambers of a reactor are coupled to a heat exchanger to pre-heat the reactive particles prior to direct exposure to thermal energy with heat transferred from reduced reactive particles as the particles are oppositely conveyed between the thermal reduction chamber and the fuel production chamber. In an embodiment, particle conveyance is in part provided by an elevator which may further function as a heat exchanger.

  9. Artificial photosynthesis for sustainable fuel and chemical production.

    PubMed

    Kim, Dohyung; Sakimoto, Kelsey K; Hong, Dachao; Yang, Peidong

    2015-03-01

    The apparent incongruity between the increasing consumption of fuels and chemicals and the finite amount of resources has led us to seek means to maintain the sustainability of our society. Artificial photosynthesis, which utilizes sunlight to create high-value chemicals from abundant resources, is considered as the most promising and viable method. This Minireview describes the progress and challenges in the field of artificial photosynthesis in terms of its key components: developments in photoelectrochemical water splitting and recent progress in electrochemical CO2 reduction. Advances in catalysis, concerning the use of renewable hydrogen as a feedstock for major chemical production, are outlined to shed light on the ultimate role of artificial photosynthesis in achieving sustainable chemistry.

  10. Production of gaseous fuel by pyrolysis of municipal solid waste

    NASA Technical Reports Server (NTRS)

    Crane, T. H.; Ringer, H. N.; Bridges, D. W.

    1975-01-01

    Pilot plant tests were conducted on a simulated solid waste which was a mixture of shredded newspaper, wood waste, polyethylene plastics, crushed glass, steel turnings, and water. Tests were conducted at 1400 F in a lead-bath pyrolyser. Cold feed was deaerated by compression and was dropped onto a moving hearth of molten lead before being transported to a sealed storage container. About 80 percent of the feed's organic content was converted to gaseous products which contain over 90 percent of the potential waste energy; 12 percent was converted to water; and 8 percent remained as partially pyrolyzed char and tars. Nearly half of the carbon in the feed is converted to benzene, toluene and medium-quality fuel gas, a potential credit of over $25 per ton of solid waste. The system was shown to require minimal preprocessing and less sorting then other methods.

  11. Determination of alternative fuels combustion products: Phase 2 final report

    SciTech Connect

    Whitney, K.A.

    1997-06-01

    This report describes the laboratory efforts to accomplish four independent tasks: (1) speciation of hydrocarbon exhaust emissions from a light-duty vehicle operated over the chassis dynamometer portion of the light-duty FTP after modifications for operation on butane and butane blends; (2) evaluation of NREL`s Variable Conductance Vacuum Insulated Catalytic Converter Test Article 4 for the reduction of cold-start FTP exhaust emissions after extended soak periods for a Ford FFV Taurus operating on E85; (3) support of UDRI in an attempt to define correlations between engine-out combustion products identified by SwRI during chassis dynamometer testing, and those found during flow tube reactor experiments conducted by UDRI; and (4) characterization of small-diameter particulate matter from a Ford Taurus FFV operating in a simulated fuel-rich failure mode on CNG, LPG, M85, E85, and reformulated gasoline. 22 refs., 18 figs., 17 tabs.

  12. Alcohol Fuels Production, Manpower, and Education: Where Do Two-Year Colleges Fit?

    ERIC Educational Resources Information Center

    Mahoney, James R.

    The Energy Communications Center (ECC) has sponsored a number of alcohol fuels activities designed to share information about alcohol fuels with two-year college faculty and administrators and to clarify the manpower and curriculum issues related to fuel production. This paper is the result of the last of these activities, a one-day meeting of…

  13. Fundamental Studies of Irradiation-Induced Defect Formation and Fission Product Dynamics in Oxide Fuels

    SciTech Connect

    Stubbins, James

    2012-12-19

    The objective of this research program is to address major nuclear fuels performance issues for the design and use of oxide-type fuels in the current and advanced nuclear reactor applications. Fuel performance is a major issue for extending fuel burn-up which has the added advantage of reducing the used fuel waste stream. It will also be a significant issue with respect to developing advanced fuel cycle processes where it may be possible to incorporate minor actinides in various fuel forms so that they can be 'burned' rather than join the used fuel waste stream. The potential to fission or transmute minor actinides and certain long-lived fission product isotopes would transform the high level waste storage strategy by removing the need to consider fuel storage on the millennium time scale.

  14. Pectin-rich biomass as feedstock for fuel ethanol production.

    PubMed

    Edwards, Meredith C; Doran-Peterson, Joy

    2012-08-01

    The USA has proposed that 30 % of liquid transportation fuel be produced from renewable resources by 2030 (Perlack and Stokes 2011). It will be impossible to reach this goal using corn kernel-based ethanol alone. Pectin-rich biomass, an under-utilized waste product of the sugar and juice industry, can augment US ethanol supplies by capitalizing on this already established feedstock. Currently, pectin-rich biomass is sold (at low value) as animal feed. This review focuses on the three most studied types of pectin-rich biomass: sugar beet pulp, citrus waste and apple pomace. Fermentations of these materials have been conducted with a variety of ethanologens, including yeasts and bacteria. Escherichia coli can ferment a wide range of sugars including galacturonic acid, the primary component of pectin. However, the mixed acid metabolism of E. coli can produce unwanted side products. Saccharomyces cerevisiae cannot naturally ferment galacturonic acid nor pentose sugars but has a homoethanol pathway. Erwinia chrysanthemi is capable of degrading many of the cell wall components of pectin-rich materials, including pectin. Klebsiella oxytoca can metabolize a diverse array of sugars including cellobiose, one degradation product of cellulose. However, both E. chrysanthemi and K. oxytoca produce side products during fermentation, similar to E. coli. Using pectin-rich residues from industrial processes is beneficial because the material is already collected and partially pretreated to facilitate enzymatic deconstruction of the plant cell walls. Using biomass already produced for other purposes is an attractive practice because fewer greenhouse gases (GHG) will be anticipated from land-use changes.

  15. Pectin-rich biomass as feedstock for fuel ethanol production.

    PubMed

    Edwards, Meredith C; Doran-Peterson, Joy

    2012-08-01

    The USA has proposed that 30 % of liquid transportation fuel be produced from renewable resources by 2030 (Perlack and Stokes 2011). It will be impossible to reach this goal using corn kernel-based ethanol alone. Pectin-rich biomass, an under-utilized waste product of the sugar and juice industry, can augment US ethanol supplies by capitalizing on this already established feedstock. Currently, pectin-rich biomass is sold (at low value) as animal feed. This review focuses on the three most studied types of pectin-rich biomass: sugar beet pulp, citrus waste and apple pomace. Fermentations of these materials have been conducted with a variety of ethanologens, including yeasts and bacteria. Escherichia coli can ferment a wide range of sugars including galacturonic acid, the primary component of pectin. However, the mixed acid metabolism of E. coli can produce unwanted side products. Saccharomyces cerevisiae cannot naturally ferment galacturonic acid nor pentose sugars but has a homoethanol pathway. Erwinia chrysanthemi is capable of degrading many of the cell wall components of pectin-rich materials, including pectin. Klebsiella oxytoca can metabolize a diverse array of sugars including cellobiose, one degradation product of cellulose. However, both E. chrysanthemi and K. oxytoca produce side products during fermentation, similar to E. coli. Using pectin-rich residues from industrial processes is beneficial because the material is already collected and partially pretreated to facilitate enzymatic deconstruction of the plant cell walls. Using biomass already produced for other purposes is an attractive practice because fewer greenhouse gases (GHG) will be anticipated from land-use changes. PMID:22695801

  16. FRACTIONATION OF LIGNOCELLULOSIC BIOMASS FOR FUEL-GRADE ETHANOL PRODUCTION

    SciTech Connect

    F.D. Guffey; R.C. Wingerson

    2002-10-01

    PureVision Technology, Inc. (PureVision) of Fort Lupton, Colorado is developing a process for the conversion of lignocellulosic biomass into fuel-grade ethanol and specialty chemicals in order to enhance national energy security, rural economies, and environmental quality. Lignocellulosic-containing plants are those types of biomass that include wood, agricultural residues, and paper wastes. Lignocellulose is composed of the biopolymers cellulose, hemicellulose, and lignin. Cellulose, a polymer of glucose, is the component in lignocellulose that has potential for the production of fuel-grade ethanol by direct fermentation of the glucose. However, enzymatic hydrolysis of lignocellulose and raw cellulose into glucose is hindered by the presence of lignin. The cellulase enzyme, which hydrolyzes cellulose to glucose, becomes irreversibly bound to lignin. This requires using the enzyme in reagent quantities rather than in catalytic concentration. The extensive use of this enzyme is expensive and adversely affects the economics of ethanol production. PureVision has approached this problem by developing a biomass fractionator to pretreat the lignocellulose to yield a highly pure cellulose fraction. The biomass fractionator is based on sequentially treating the biomass with hot water, hot alkaline solutions, and polishing the cellulose fraction with a wet alkaline oxidation step. In September 2001 PureVision and Western Research Institute (WRI) initiated a jointly sponsored research project with the U.S. Department of Energy (DOE) to evaluate their pretreatment technology, develop an understanding of the chemistry, and provide the data required to design and fabricate a one- to two-ton/day pilot-scale unit. The efforts during the first year of this program completed the design, fabrication, and shakedown of a bench-scale reactor system and evaluated the fractionation of corn stover. The results from the evaluation of corn stover have shown that water hydrolysis prior to

  17. Methane production and isotopic fingerprinting in ethanol fuel contaminated sites.

    PubMed

    Freitas, Juliana G; Fletcher, Barbara; Aravena, Ramon; Barker, James F

    2010-01-01

    Biodegradation of organic compounds in groundwater can be a significant source of methane in contaminated sites. Methane might accumulate in indoor spaces posing a hazard. The increasing use of ethanol as a gasoline additive is a concern with respect to methane production since it is easily biodegraded and has a high oxygen demand, favoring the development of anaerobic conditions. This study evaluated the use of stable carbon isotopes to distinguish the methane origin between gasoline and ethanol biodegradation, and assessed the occurrence of methane in ethanol fuel contaminated sites. Two microcosm tests were performed under anaerobic conditions: one test using ethanol and the other using toluene as the sole carbon source. The isotopic tool was then applied to seven field sites known to be impacted by ethanol fuels. In the microcosm tests, it was verified that methane from ethanol (δ¹³C = -11.1‰) is more enriched in ¹³C, with δ¹³C values ranging from -20‰ to -30‰, while the methane from toluene (δ¹³C = -28.5‰) had a carbon isotopic signature of -55‰. The field samples had δ¹³C values varying over a wide range (-10‰ to -80‰), and the δ¹³C values allowed the methane source to be clearly identified in five of the seven ethanol/gasoline sites. In the other two sites, methane appears to have been produced from both sources. Both gasoline and ethanol were sources of methane in potentially hazardous concentrations and methane could be produced from organic acids originating from ethanol along the groundwater flow system even after all the ethanol has been completed biodegraded.

  18. Fate of virginiamycin through the fuel ethanol production process.

    PubMed

    Bischoff, Kenneth M; Zhang, Yanhong; Rich, Joseph O

    2016-05-01

    Antibiotics are frequently used to prevent and treat bacterial contamination of commercial fuel ethanol fermentations, but there is concern that antibiotic residues may persist in the distillers grains coproducts. A study to evaluate the fate of virginiamycin during the ethanol production process was conducted in the pilot plant facilities at the National Corn to Ethanol Research Center, Edwardsville, IL. Three 15,000-liter fermentor runs were performed: one with no antibiotic (F1), one dosed with 2 parts per million (ppm) of a commercial virginiamycin product (F2), and one dosed at 20 ppm of virginiamycin product (F3). Fermentor samples, distillers dried grains with solubles (DDGS), and process intermediates (whole stillage, thin stillage, syrup, and wet cake) were collected from each run and analyzed for virginiamycin M and virginiamycin S using a liquid chromatography-mass spectrometry method. Virginiamycin M was detected in all process intermediates of the F3 run. On a dry-weight basis, virginiamycin M concentrations decreased approximately 97 %, from 41 μg/g in the fermentor to 1.4 μg/g in the DDGS. Using a disc plate bioassay, antibiotic activity was detected in DDGS from both the F2 and F3 runs, with values of 0.69 μg virginiamycin equivalent/g sample and 8.9 μg/g, respectively. No antibiotic activity (<0.6 μg/g) was detected in any of the F1 samples or in the fermentor and process intermediate samples from the F2 run. These results demonstrate that low concentrations of biologically active antibiotic may persist in distillers grains coproducts produced from fermentations treated with virginiamycin.

  19. Fate of virginiamycin through the fuel ethanol production process.

    PubMed

    Bischoff, Kenneth M; Zhang, Yanhong; Rich, Joseph O

    2016-05-01

    Antibiotics are frequently used to prevent and treat bacterial contamination of commercial fuel ethanol fermentations, but there is concern that antibiotic residues may persist in the distillers grains coproducts. A study to evaluate the fate of virginiamycin during the ethanol production process was conducted in the pilot plant facilities at the National Corn to Ethanol Research Center, Edwardsville, IL. Three 15,000-liter fermentor runs were performed: one with no antibiotic (F1), one dosed with 2 parts per million (ppm) of a commercial virginiamycin product (F2), and one dosed at 20 ppm of virginiamycin product (F3). Fermentor samples, distillers dried grains with solubles (DDGS), and process intermediates (whole stillage, thin stillage, syrup, and wet cake) were collected from each run and analyzed for virginiamycin M and virginiamycin S using a liquid chromatography-mass spectrometry method. Virginiamycin M was detected in all process intermediates of the F3 run. On a dry-weight basis, virginiamycin M concentrations decreased approximately 97 %, from 41 μg/g in the fermentor to 1.4 μg/g in the DDGS. Using a disc plate bioassay, antibiotic activity was detected in DDGS from both the F2 and F3 runs, with values of 0.69 μg virginiamycin equivalent/g sample and 8.9 μg/g, respectively. No antibiotic activity (<0.6 μg/g) was detected in any of the F1 samples or in the fermentor and process intermediate samples from the F2 run. These results demonstrate that low concentrations of biologically active antibiotic may persist in distillers grains coproducts produced from fermentations treated with virginiamycin. PMID:27038946

  20. Alcohol fuels: Production. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect

    Not Available

    1994-05-01

    The bibliography contains citations concerning the synthesis of alcohol fuels, including gasohol. Alcohol production from sugar beets, industrial wastes, hardwood, biomass, and coal conversion processes are discussed. Cellulose and lignin degradation processes are described. Production systems are evaluated. The utilization of alcohol fuels is discussed in a separate bibliography. (Contains 250 citations and includes a subject term index and title list.)

  1. Alcohol fuels: Production. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect

    Not Available

    1993-09-01

    The bibliography contains citations concerning the synthesis of alcohol fuels, including gasohol. Alcohol production from sugar beets, industrial wastes, hardwood, biomass, and coal conversion processes are discussed. Cellulose and lignin degradation processes are described. Production systems are evaluated. The utilization of alcohol fuels is discussed in a separate bibliography. (Contains 250 citations and includes a subject term index and title list.)

  2. Bioelectricity production from soil using microbial fuel cells.

    PubMed

    Wolińska, Agnieszka; Stępniewska, Zofia; Bielecka, Arletta; Ciepielski, Jakub

    2014-08-01

    Microbial fuel cells (MFCs) are a device using microorganisms as biocatalysts for transforming chemical energy into bioelectricity. As soil is an environment with the highest number of microorganisms and diversity, we hypothesized that it should have the potential for energy generation. The soil used for the study was Mollic Gleysol collected from the surface layer (0-20 cm). Four combinations of soil MFC differing from each other in humidity (full water holding capacity [WHC] and flooding) and the carbon source (glucose and straw) were constructed. Voltage (mV) and current intensity (μA) produced by the MFCs were recorded every day or at 2-day intervals. The fastest and the most effective MFCs in voltage generation (372.2 ± 5 mV) were those constructed on the basis of glucose (MFC-G). The efficiency of straw MFCs (MFC-S) was noticeable after 2 weeks (319.3 ± 4 mV). Maximal power density (P max = 32 mW m(-2)) was achieved by the MFC-G at current density (CD) of 100 mA m(-2). Much lower values of P max (10.6-10.8 mW m(-2)) were noted in the MFC-S at CD of ca. 60-80 mA m(-2). Consequently, soil has potential for production of renewable energy.

  3. Bioelectricity production from soil using microbial fuel cells.

    PubMed

    Wolińska, Agnieszka; Stępniewska, Zofia; Bielecka, Arletta; Ciepielski, Jakub

    2014-08-01

    Microbial fuel cells (MFCs) are a device using microorganisms as biocatalysts for transforming chemical energy into bioelectricity. As soil is an environment with the highest number of microorganisms and diversity, we hypothesized that it should have the potential for energy generation. The soil used for the study was Mollic Gleysol collected from the surface layer (0-20 cm). Four combinations of soil MFC differing from each other in humidity (full water holding capacity [WHC] and flooding) and the carbon source (glucose and straw) were constructed. Voltage (mV) and current intensity (μA) produced by the MFCs were recorded every day or at 2-day intervals. The fastest and the most effective MFCs in voltage generation (372.2 ± 5 mV) were those constructed on the basis of glucose (MFC-G). The efficiency of straw MFCs (MFC-S) was noticeable after 2 weeks (319.3 ± 4 mV). Maximal power density (P max = 32 mW m(-2)) was achieved by the MFC-G at current density (CD) of 100 mA m(-2). Much lower values of P max (10.6-10.8 mW m(-2)) were noted in the MFC-S at CD of ca. 60-80 mA m(-2). Consequently, soil has potential for production of renewable energy. PMID:24980749

  4. Advanced liquid fuel production from biomass for power generation

    SciTech Connect

    Grassi, G.; Palmarocchi, M.; Joeler, J.

    1995-11-01

    In the European Union, important political decisions recently adopted and concerning the evolution of the Common Agriculture Policy, the GATT trade liberalisation Agreement and new measures actually under discussion (CARBON TAX, Financial support for rural development...) will have significant impact, in a no distant future, on the bioenergy activity. Also the considerable energy import ({approximately} 55% of the consumption) is of increasing concerns. The biomass potential in the E.U. is large, but the availability of commercial technologies for processing and utilising this renewable energy resource is very modest. Thus, a strong effort for the development of new and efficient technologies (like the one implemented by ENEL/CRT) is essential, as well as the build-up of an efficient industry for the commercialisation of reliable, low-cost biomass conversion/utilisation systems. The recently founded {open_quotes}European Bioenergy Industry Association{close_quotes} will make an effort for the promotion of this specific new industrial sector. In this framework, a new research effort (in Germany/Italy) for up-grading the bio-crude-oil by high energetic electrons. This process, if demonstrated feasible, could be of great interest for the production of new liquid fuels of sufficient quality to be utilised in most types of modern power generator.

  5. Mortality among workers at a nuclear fuels production facility

    SciTech Connect

    Cragle, D.L.; McLain, R.W.; Qualters, J.R.; Hickey, J.L.; Wilkinson, G.S.; Tankersley, W.G.; Lushbaugh, C.C.

    1988-01-01

    A retrospective cohort mortality study was conducted in a population of workers employed at a facility with the primary task of production of nuclear fuels and other materials. Data for hourly and salaried employees were analyzed separately by time period of first employment and length of employment. The hourly (N = 6687 with 728 deaths) and salaried (N = 2745 with 294 deaths) employees had a mortality experience comparable to that of the United States and, in fact, exhibited significant fewer deaths in many categories of diseases that are traditionally associated with the healthy worker effect. Specifically, fewer deaths were noted in the categories of all causes, all cancers, cancer of the digestive organs, lung cancer, brain cancer (hourly workers only), diabetes, all diseases of the circulatory system, all respiratory diseases, all digestive system diseases, all diseases of the genitourinary system (hourly only), and all external causes of death. A statistically significant, and as yet unexplained increase in leukemia mortality (6 observed vs. 2.18 expected) appeared among a subset of the hourly employees, first hired before 1955, and employed between 5-15 years.

  6. Maleic anhydride-polyether-polyamine reaction product and motor fuel composition containing same

    SciTech Connect

    Sung, R.L.

    1987-04-21

    A material is described having a use as a motor fuel additive for controlling engine octane requirement increase (ORI), controlling and reducing hydrocarbon and carbon monoxide engine emissions, and having carburetor detergency properties. The material is the reaction product of maleic anhydride, a polyether polyamine, preferably a polyether diamine, and a hydrocarbyl polyamine, preferably an n-alkyl-alkylene diamine. A concentrate comprising the prescribed reaction product dissolved in a hydrocarbon solvent is also described. Motor fuels containing the reaction product additive of the instant invention show improved ORI control and carburetor detergency in comparison with motor fuels without the reaction product additive.

  7. Systems analysis of electricity production from coal using fuel cells

    NASA Technical Reports Server (NTRS)

    Fleming, D. K.

    1983-01-01

    Gasifiers, heat transfer, gas stability, quench, water-gas shift reaction, reforming-methanation, other catalytic reactions, compressors and expanders, acid-gas removal, the fuel cell, and catalytic combustors are described. System pressure drops, efficiency of rotating power equipment, heat exchangers, chemical reactions, steam systems, and the fuel cell subsystems are discussed.

  8. Fusion-Fission Hybrid for Fissile Fuel Production without Processing

    SciTech Connect

    Fratoni, M; Moir, R W; Kramer, K J; Latkowski, J F; Meier, W R; Powers, J J

    2012-01-02

    Two scenarios are typically envisioned for thorium fuel cycles: 'open' cycles based on irradiation of {sup 232}Th and fission of {sup 233}U in situ without reprocessing or 'closed' cycles based on irradiation of {sup 232}Th followed by reprocessing, and recycling of {sup 233}U either in situ or in critical fission reactors. This study evaluates a third option based on the possibility of breeding fissile material in a fusion-fission hybrid reactor and burning the same fuel in a critical reactor without any reprocessing or reconditioning. This fuel cycle requires the hybrid and the critical reactor to use the same fuel form. TRISO particles embedded in carbon pebbles were selected as the preferred form of fuel and an inertial laser fusion system featuring a subcritical blanket was combined with critical pebble bed reactors, either gas-cooled or liquid-salt-cooled. The hybrid reactor was modeled based on the earlier, hybrid version of the LLNL Laser Inertial Fusion Energy (LIFE1) system, whereas the critical reactors were modeled according to the Pebble Bed Modular Reactor (PBMR) and the Pebble Bed Advanced High Temperature Reactor (PB-AHTR) design. An extensive neutronic analysis was carried out for both the hybrid and the fission reactors in order to track the fuel composition at each stage of the fuel cycle and ultimately determine the plant support ratio, which has been defined as the ratio between the thermal power generated in fission reactors and the fusion power required to breed the fissile fuel burnt in these fission reactors. It was found that the maximum attainable plant support ratio for a thorium fuel cycle that employs neither enrichment nor reprocessing is about 2. This requires tuning the neutron energy towards high energy for breeding and towards thermal energy for burning. A high fuel loading in the pebbles allows a faster spectrum in the hybrid blanket; mixing dummy carbon pebbles with fuel pebbles enables a softer spectrum in the critical reactors

  9. C1-carbon sources for chemical and fuel production by microbial gas fermentation.

    PubMed

    Dürre, Peter; Eikmanns, Bernhard J

    2015-12-01

    Fossil resources for production of fuels and chemicals are finite and fuel use contributes to greenhouse gas emissions and global warming. Thus, sustainable fuel supply, security, and prices necessitate the implementation of alternative routes to the production of chemicals and fuels. Much attention has been focussed on use of cellulosic material, particularly through microbial-based processes. However, this is still costly and proving challenging, as are catalytic routes to biofuels from whole biomass. An alternative strategy is to directly capture carbon before incorporation into lignocellulosic biomass. Autotrophic acetogenic, carboxidotrophic, and methanotrophic bacteria are able to capture carbon as CO, CO2, or CH4, respectively, and reuse that carbon in products that displace their fossil-derived counterparts. Thus, gas fermentation represents a versatile industrial platform for the sustainable production of commodity chemicals and fuels from diverse gas resources derived from industrial processes, coal, biomass, municipal solid waste (MSW), and extracted natural gas.

  10. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to commercial

  11. Solar Thermochemical Fuels Production: Solar Thermochemical Fuel Production via a Novel Lowe Pressure, Magnetically Stabilized, Non-volatile Iron Oxide Looping Process

    SciTech Connect

    2011-12-19

    HEATS Project: The University of Florida is developing a windowless high-temperature chemical reactor that converts concentrated solar thermal energy to syngas, which can be used to produce gasoline. The overarching project goal is lowering the cost of the solar thermochemical production of syngas for clean and synthetic hydrocarbon fuels like petroleum. The team will develop processes that rely on water and recycled CO2 as the sole feed-stock, and concentrated solar radiation as the sole energy source, to power the reactor to produce fuel efficiently. Successful large-scale deployment of this solar thermochemical fuel production could substantially improve our national and economic security by replacing imported oil with domestically produced solar fuels.

  12. ULTRA-CLEAN FISCHER-TROPSCH FUELS PRODUCTION AND DEMONSTRATION PROJECT

    SciTech Connect

    Steve Bergin

    2003-10-17

    The Syntroleum plant is mechanically complete and currently undergoing start-up. The fuel production and demonstration plan is near completion. The study on the impact of small footprint plant (SFP) fuel on engine performance is about half-completed. Cold start testing has been completed. Preparations have been completed for testing the fuel in diesel electric generators in Alaska. Preparations are in progress for testing the fuel in bus fleets at Denali National Park and the Washington Metropolitan Transit Authority. The experiments and analyses conducted during this project show that Fischer-Tropsch (FT) gas-to-liquid diesel fuel can easily be used in a diesel engine with little to no modifications. Additionally, based on the results and discussion presented, further improvements in performance and emissions can be realized by configuring the engine to take advantage of FT diesel fuel's properties. The FT fuel also shows excellent cold start properties and enabled the engine tested to start at more the ten degrees than traditional fuels would allow. This plant produced through this project will produce large amounts of FT fuel. This will allow the fuel to be tested extensively, in current, prototype, and advanced diesel engines. The fuel may also contribute to the nation's energy security. The military has expressed interest in testing the fuel in aircraft and ground vehicles.

  13. Production of biosolid fuels from municipal sewage sludge: Technical and economic optimisation.

    PubMed

    Wzorek, Małgorzata; Tańczuk, Mariusz

    2015-08-01

    The article presents the technical and economic analysis of the production of fuels from municipal sewage sludge. The analysis involved the production of two types of fuel compositions: sewage sludge with sawdust (PBT fuel) and sewage sludge with meat and bone meal (PBM fuel). The technology of the production line of these sewage fuels was proposed and analysed. The main objective of the study is to find the optimal production capacity. The optimisation analysis was performed for the adopted technical and economic parameters under Polish conditions. The objective function was set as a maximum of the net present value index and the optimisation procedure was carried out for the fuel production line input capacity from 0.5 to 3 t h(-1), using the search step 0.5 t h(-1). On the basis of technical and economic assumptions, economic efficiency indexes of the investment were determined for the case of optimal line productivity. The results of the optimisation analysis show that under appropriate conditions, such as prices of components and prices of produced fuels, the production of fuels from sewage sludge can be profitable. In the case of PBT fuel, calculated economic indexes show the best profitability for the capacity of a plant over 1.5 t h(-1) output, while production of PBM fuel is beneficial for a plant with the maximum of searched capacities: 3.0 t h(-1). Sensitivity analyses carried out during the investigation show that influence of both technical and economic assessments on the location of maximum of objective function (net present value) is significant. PMID:26116645

  14. Production of biosolid fuels from municipal sewage sludge: Technical and economic optimisation.

    PubMed

    Wzorek, Małgorzata; Tańczuk, Mariusz

    2015-08-01

    The article presents the technical and economic analysis of the production of fuels from municipal sewage sludge. The analysis involved the production of two types of fuel compositions: sewage sludge with sawdust (PBT fuel) and sewage sludge with meat and bone meal (PBM fuel). The technology of the production line of these sewage fuels was proposed and analysed. The main objective of the study is to find the optimal production capacity. The optimisation analysis was performed for the adopted technical and economic parameters under Polish conditions. The objective function was set as a maximum of the net present value index and the optimisation procedure was carried out for the fuel production line input capacity from 0.5 to 3 t h(-1), using the search step 0.5 t h(-1). On the basis of technical and economic assumptions, economic efficiency indexes of the investment were determined for the case of optimal line productivity. The results of the optimisation analysis show that under appropriate conditions, such as prices of components and prices of produced fuels, the production of fuels from sewage sludge can be profitable. In the case of PBT fuel, calculated economic indexes show the best profitability for the capacity of a plant over 1.5 t h(-1) output, while production of PBM fuel is beneficial for a plant with the maximum of searched capacities: 3.0 t h(-1). Sensitivity analyses carried out during the investigation show that influence of both technical and economic assessments on the location of maximum of objective function (net present value) is significant.

  15. Determination of alternative fuels combustion products: Phase 3 report

    SciTech Connect

    Whitney, K.A.

    1997-12-01

    This report describes the laboratory efforts to characterize particulate and gaseous exhaust emissions from a passenger vehicle operating on alternative fuels. Tests were conducted at room temperature (nominally 72 F) and 20 F utilizing the chassis dynamometer portion of the FTP for light-duty vehicles. Fuels evaluated include Federal RFG, LPG meeting HD-5 specifications, a national average blend of CNG, E85, and M85. Exhaust particulate generated at room temperature was further characterized to determine polynuclear aromatic content, trace element content, and trace organic constituents. For all fuels except M85, the room temperature particulate emission rate from this vehicle was about 2 to 3 mg/mile. On M85, the particulate emission rate was more than 6 mg/mile. In addition, elemental analysis of particulate revealed an order of magnitude more sulfur and calcium from M85 than any other fuel. The sulfur and calcium indicate that these higher emissions might be due to engine lubricating oil in the exhaust. For RFG, particulate emissions at 20 F were more than six times higher than at room temperature. For alcohol fuels, particulate emissions at 20 F were two to three times higher than at room temperature. For CNG and LPG, particulate emissions were virtually the same at 72 F and 20 F. However, PAH emissions from CNG and LPG were higher than expected. Both gaseous fuels had larger amounts of pyrene, 1-nitropyrene, and benzo(g,h,i)perylene in their emissions than the other fuels.

  16. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses

  17. Electricity production from municipal solid waste using microbial fuel cells.

    PubMed

    Chiu, H Y; Pai, T Y; Liu, M H; Chang, C A; Lo, F C; Chang, T C; Lo, H M; Chiang, C F; Chao, K P; Lo, W Y; Lo, S W; Chu, Y L

    2016-07-01

    The organic content of municipal solid waste has long been an attractive source of renewable energy, mainly as a solid fuel in waste-to-energy plants. This study focuses on the potential to use microbial fuel cells to convert municipal solid waste organics into energy using various operational conditions. The results showed that two-chamber microbial fuel cells with carbon felt and carbon felt allocation had a higher maximal power density (20.12 and 30.47 mW m(-2) for 1.5 and 4 L, respectively) than those of other electrode plate allocations. Most two-chamber microbial fuel cells (1.5 and 4 L) had a higher maximal power density than single-chamber ones with corresponding electrode plate allocations. Municipal solid waste with alkali hydrolysis pre-treatment and K3Fe(CN)6 as an electron acceptor improved the maximal power density to 1817.88 mW m(-2) (~0.49% coulomb efficiency, from 0.05-0.49%). The maximal power density from experiments using individual 1.5 and 4 L two-chamber microbial fuel cells, and serial and parallel connections of 1.5 and 4 L two-chamber microbial fuel cells, was found to be in the order of individual 4 L (30.47 mW m(-2)) > serial connection of 1.5 and 4 L (27.75) > individual 1.5 L (20.12) > parallel connection of 1.5 and 4 L (17.04) two-chamber microbial fuel cells . The power density using municipal solid waste microbial fuel cells was compared with information in the literature and discussed.

  18. The effectiveness of the small-tonnage solid composite fuel production from biomass

    NASA Astrophysics Data System (ADS)

    Tabakaev, R. B.; Astafev, A. V.; Kazakov, A. V.; Zavorin, A. S.; Polsongkram, M.

    2015-10-01

    The relevance of the work is caused by necessity of the involving of local low-grade raw materials in the fuel energy balance. The purpose of the work is technical and economical evaluation to implementation possibility of the solid composite fuel production from peat as an example of the Tomsk region. The results of a processing of the low-grade raw materials at certain types from Tomsk region into the solid composite fuel are shown, their competitiveness is evaluated, the process line to production of this fuel is suggested and the economical calculation of the production organization by its basis is made. As a result, the prime cost of solid composite fuel and technical and economical parameters of investments efficiency are determined.

  19. Biodiesel production from various feedstocks and their effects on the fuel properties.

    PubMed

    Canakci, M; Sanli, H

    2008-05-01

    Biodiesel, which is a new, renewable and biological origin alternative diesel fuel, has been receiving more attention all over the world due to the energy needs and environmental consciousness. Biodiesel is usually produced from food-grade vegetable oils using transesterification process. Using food-grade vegetable oils is not economically feasible since they are more expensive than diesel fuel. Therefore, it is said that the main obstacle for commercialization of biodiesel is its high cost. Waste cooking oils, restaurant greases, soapstocks and animal fats are potential feedstocks for biodiesel production to lower the cost of biodiesel. However, to produce fuel-grade biodiesel, the characteristics of feedstock are very important during the initial research and production stage since the fuel properties mainly depend on the feedstock properties. This review paper presents both biodiesel productions from various feedstocks and their effects on the fuel properties.

  20. Production of new biomass/waste-containing solid fuels

    SciTech Connect

    Akers, D.; Shirey, G.; Zitron, Z.; Nowak, M.

    2000-07-01

    The electric utility industry is interested in the use of biomass and waste byproducts as fuel to reduce both emissions and fuel costs. Unfortunately, biomass and waste byproducts can be troublesome fuels because of low bulk density, high moisture content, variable composition, handling and feeding problems, and inadequate information about combustion and emissions characteristics. One method of addressing these issues is to produce composite fuels composed of a pelletized mixture of biomass and other constituents. However, for composite fuels to be extensively used in the US, especially in the steam market, a lower cost method of producing these fuels must be developed. Also, standard formulations of biomass and coal (possibly including waste) with broad application to US boilers must be identified. In addition to acceptable cost, these standard formulations can provide environmental benefits relative to coal. The Department of Energy along with the Electric Power Research Institute and various industry partners has funded CQ Inc. to develop both a dewatering/pelletizing die and three standard formulations of biomass, coal, and waste byproducts. Six biomass/waste sources were initially selected for study: petroleum coke, mixed waste plastic, switchgrass, waxed cardboard, poultry manure, and sewage sludge. A sample representative of each source was collected and analyzed. Also, two sources of coal, recovered from waste ponds, were collected for use in the project.

  1. Subtask 2.6 - Assessment of Alternative Fuels on CO2 Production

    SciTech Connect

    Debra Pflughoeft-Hassett; Darren Naasz

    2009-06-16

    Many coal-based electric generating units use alternative fuels, and this effort assessed the impact of alternative fuels on CO{sub 2} production and other emissions and also assessed the potential impact of changes in emission regulations under the Clean Air Act (CAA) for facilities utilizing alternative fuels that may be categorized as wastes. Information was assembled from publicly available U.S. Department of Energy Energy Information Administration databases that included alternative fuel use for 2004 and 2005. Alternative fuel types were categorized along with information on usage by coal-based electric, number of facilities utilizing each fuel type, and the heating value of solid, liquid, and gaseous alternative fuels. The sulfur dioxide, nitrogen oxide, and carbon dioxide emissions associated with alternative fuels and primary fuels were also evaluated. Carbon dioxide emissions are also associated with the transport of all fuels. A calculation of carbon dioxide emissions associated with the transport of biomass-based fuels that are typically accessed on a regional basis was made. A review of CAA emission regulations for coal-based electric generating facilities from Section 112 (1) and Section 129 (2) for solid waste incinerators was performed with consideration for a potential regulatory change from Section 112 (1) regulation to Section 129 (2). Increased emission controls would be expected to be required if coal-based electric generating facilities using alternative fuels would be recategorized under CAA Section 129 (2) for solid waste incinerators, and if this change were made, it is anticipated that coal-fired electric generating facilities might reduce the use of alternative fuels. Conclusions included information on the use profile for alternative fuels and the impacts to emissions as well as the impact of potential application of emission regulations for solid waste incinerators to electric generating facilities using alternative fuels.

  2. Solar Thermochemical Fuels Production: Solar Fuels via Partial Redox Cycles with Heat Recovery

    SciTech Connect

    2011-12-19

    HEATS Project: The University of Minnesota is developing a solar thermochemical reactor that will efficiently produce fuel from sunlight, using solar energy to produce heat to break chemical bonds. The University of Minnesota is envisioning producing the fuel by using partial redox cycles and ceria-based reactive materials. The team will achieve unprecedented solar-to-fuel conversion efficiencies of more than 10% (where current state-of-the-art efficiency is 1%) by combined efforts and innovations in material development, and reactor design with effective heat recovery mechanisms and demonstration. This new technology will allow for the effective use of vast domestic solar resources to produce precursors to synthetic fuels that could replace gasoline.

  3. 1989 annual book of ASTM standards. Section 5: Petroleum products, lubricants and fossil fuels

    SciTech Connect

    Not Available

    1989-01-01

    This volume of standards pertains to petroleum products and lubricants and to catalysts. The standards presented include: Standard test method for estimation of net and gross heat of combustion of petroleum fuels; Standard guide for generation and dissipation of static electricity in petroleum fuel systems; and Standard test method for solidification point of petroleum wax.

  4. SYSTEM AND PROCESS FOR PRODUCTION OF METHANOL FROM COMBINED WIND TURBINE AND FUEL CELL POWER

    EPA Science Inventory

    The paper examines an integrated use of ultra-clean wind turbines and high temperature fuel cells to produce methanol, especially for transportation purposes. The principal utility and application of the process is the production of transportation fuel from domestic resources to ...

  5. Analyzing Losses: Transuranics into Waste and Fission Products into Recycled Fuel

    SciTech Connect

    Steven J. Piet; Nick R. Soelberg; Samuel E. Bays; Robert E. Cherry; Layne F. Pincock; Eric L. Shaber; Melissa C. Teague; Gregory M. Teske; Kurt G. Vedros; Candido Pereira; Denia Djokic

    2010-11-01

    All mass streams from separations and fuel fabrication are products that must meet criteria. Those headed for disposal must meet waste acceptance criteria (WAC) for the eventual disposal sites corresponding to their waste classification. Those headed for reuse must meet fuel or target impurity limits. A “loss” is any material that ends up where it is undesired. The various types of losses are linked in the sense that as the loss of transuranic (TRU) material into waste is reduced, often the loss or carryover of waste into TRU or uranium is increased. We have analyzed four separation options and two fuel fabrication options in a generic fuel cycle. The separation options are aqueous uranium extraction plus (UREX+1), electrochemical, Atomics International reduction oxidation separation (AIROX), and melt refining. UREX+1 and electrochemical are traditional, full separation techniques. AIROX and melt refining are taken as examples of limited separations, also known as minimum fuel treatment. The fuels are oxide and metal. To define a generic fuel cycle, a fuel recycling loop is fed from used light water reactor (LWR) uranium oxide fuel (UOX) at 51 MWth-day/kg-iHM burnup. The recycling loop uses a fast reactor with TRU conversion ratio (CR) of 0.50. Excess recovered uranium is put into storage. Only waste, not used fuel, is disposed – unless the impurities accumulate to a level so that it is impossible to make new fuel for the fast reactor. Impurities accumulate as dictated by separation removal and fission product generation. Our model approximates adjustment to fast reactor fuel stream blending of TRU and U products from incoming LWR UOX and recycling FR fuel to compensate for impurity accumulation by adjusting TRU:U ratios. Our mass flow model ignores postulated fuel impurity limits; we compare the calculated impurity values with those limits to identify elements of concern. AIROX and melt refining cannot be used to separate used LWR UOX-51 because they cannot

  6. Procedure for matching synfuel users with potential suppliers. Appendix B. Proposed and ongoing synthetic fuel production projects

    SciTech Connect

    1981-08-07

    To assist the Department of Energy, Office of Fuels Conversion (OFC), in implementing the synthetic fuel exemption under the Powerplant and Industrial Fuel Use Act (FUA) of 1978, Resource Consulting Group, Inc. (RCG), has developed a procedure for matching prospective users and producers of synthetic fuel. The matching procedure, which involves a hierarchical screening process, is designed to assist OFC in: locating a supplier for a firm that wishes to obtain a synthetic fuel exemption; determining whether the fuel supplier proposed by a petitioner is technically and economically capable of meeting the petitioner's needs; and assisting the Synthetic Fuels Corporation or a synthetic fuel supplier in evaluating potential markets for synthetic fuel production. A data base is provided in this appendix on proposed and ongoing synthetic fuel production projects to be used in applying the screening procedure. The data base encompasses a total of 212 projects in the seven production technologies.

  7. Liquid Fuel From Bacteria: Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from CO2, Hydrogen, and Oxygen

    SciTech Connect

    2010-07-15

    Electrofuels Project: MIT is using solar-derived hydrogen and common soil bacteria called Ralstonia eutropha to turn carbon dioxide (CO2) directly into biofuel. This bacteria already has the natural ability to use hydrogen and CO2 for growth. MIT is engineering the bacteria to use hydrogen to convert CO2 directly into liquid transportation fuels. Hydrogen is a flammable gas, so the MIT team is building an innovative reactor system that will safely house the bacteria and gas mixture during the fuel-creation process. The system will pump in precise mixtures of hydrogen, oxygen, and CO2, and the online fuel-recovery system will continuously capture and remove the biofuel product.

  8. State-of-the-Art Fuel Cell Voltage Durability Status: Spring 2013 Composite Data Products

    SciTech Connect

    Kurtz, J.; Sprik, S.; Saur, G.; Peters, M.; Post, M.; Ainscough, C.

    2013-05-01

    This presentation from the U.S. Department of Energy's National Renewable Energy Laboratory includes composite data products (CDPs) produced in 2013 for state-of-the-art fuel cell voltage durability status.

  9. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  10. Assemblies with both target and fuel pins in an isotope-production reactor

    DOEpatents

    Cawley, W.E.; Omberg, R.P.

    1982-08-19

    A method is described for producing tritium in a fast breeder reactor cooled with liquid metal. Lithium target material is placed in pins adjacent to fuel pins in order to increase the tritium production rate.

  11. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  12. Prospects for production of synthetic liquid fuel from low-grade coal

    NASA Astrophysics Data System (ADS)

    Shevyrev, Sergei; Bogomolov, Aleksandr; Alekssev, Maksim

    2015-01-01

    In the paper, we compare the energy costs of steam and steam-oxygen gasification technologies for production of synthetic liquid fuel. Results of mathematic simulation and experimental studies on gasification of low-grade coal are presented.

  13. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-04-23

    This report summarizes the accomplishments toward project goals during the first six months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  14. Fission Product Release from Molten U/Al Alloy Fuel: A Vapor Transpiration Model

    SciTech Connect

    Whitkop, P.G.

    2001-06-26

    This report describes the application of a vapor transportation model to fission product release data obtained for uranium/aluminum alloy fuel during early Oak Ridge fuel melt experiments. The Oak Ridge data validates the vapor transpiration model and suggests that iodine and cesium are released from the molten fuel surface in elemental form while tellurium and ruthenium are released as oxides. Cesium iodide is postulated to form in the vapor phase outside of the fuel matrix. Kinetic data indicates that cesium iodide can form from Cs atoms and diatomic iodine in the vapor phase. Temperatures lower than those capable of melting fuel are necessary in order to maintain a sufficient I2 concentration. At temperatures near the fuel melting point, cesium can react with iodine atoms to form CsI only on solid surfaces such as aerosols.

  15. Use of refinery computer model to predict fuel production

    NASA Technical Reports Server (NTRS)

    Flores, F. J.

    1979-01-01

    Several factors (crudes, refinery operation and specifications) that affect yields and properties of broad specification jet fuel were parameterized using the refinery simulation model which can simulate different types of refineries were used to make the calculations. Results obtained from the program are used to correlate yield as a function of final boiling point, hydrogen content and freezing point for jet fuels produced in two refinery configurations, each one processing a different crude mix. Refinery performances are also compared in terms of energy consumption.

  16. Determination of alternative fuels combustion products: Phase 1 report

    SciTech Connect

    Whitney, K.A.

    1997-09-01

    This report describes the laboratory effort to identify and quantify organic exhaust species generated from alternative-fueled light-duty vehicles operating over the Federal Test Procedure on compressed natural gas, liquefied petroleum gas, methanol, ethanol, and reformulated gasoline. The exhaust species from these vehicles were identified and quantified for fuel/air equivalence ratios of 0.8, 1.0, and 1.2, nominally, and were analyzed with and without a vehicle catalyst in place to determine the influence of a catalytic converter on species formation.

  17. (Production and environmental impacts of alternative motor fuels)

    SciTech Connect

    McGill, R.N.

    1990-12-04

    The traveler participated in the 13th meeting of the Executive Committee on Alternative Motor Fuels (International Energy Agency). Participating countries in addition to the US are Canada, Italy, Finland, Japan, Sweden, and New Zealand (absent). The status of five existing annexes was reviewed and a pre-proposal for an additional annex to be a review of environmental impacts of fuels was presented by the traveler. This was well received by committee members, and a detailed proposal for such work will be developed for presentation at the next Executive Committee meeting.

  18. Method for forming nuclear fuel containers of a composite construction and the product thereof

    DOEpatents

    Cheng, Bo-Ching; Rosenbaum, Herman S.; Armijo, Joseph S.

    1984-01-01

    An improved method for producing nuclear fuel containers of a composite construction having components providing therein a barrier system for resisting destructive action by volatile fission products or impurities and also interdiffusion of metal constituents, and the product thereof. The composite nuclear fuel containers of the method comprise a casing of zirconium or alloy thereof with a layer of copper overlying an oxidized surface portion of the zirconium or alloy thereof.

  19. Separation of the rare-earth fission product poisons from spent nuclear fuel

    DOEpatents

    Christian, Jerry D.; Sterbentz, James W.

    2016-08-30

    A method for the separation of the rare-earth fission product poisons comprising providing a spent nuclear fuel. The spent nuclear fuel comprises UO.sub.2 and rare-earth oxides, preferably Sm, Gd, Nd, Eu oxides, with other elements depending on the fuel composition. Preferably, the provided nuclear fuel is a powder, preferably formed by crushing the nuclear fuel or using one or more oxidation-reduction cycles. A compound comprising Th or Zr, preferably metal, is provided. The provided nuclear fuel is mixed with the Th or Zr, thereby creating a mixture. The mixture is then heated to a temperature sufficient to reduce the UO.sub.2 in the nuclear fuel, preferably to at least to 850.degree. C. for Th and up to 600.degree. C. for Zr. Rare-earth metals are then extracted to form the heated mixture thereby producing a treated nuclear fuel. The treated nuclear fuel comprises the provided nuclear fuel having a significant reduction in rare-earths.

  20. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect

    Gerald P. Huffman

    2004-09-30

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. Feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification, coalbed methane, light products produced by Fischer-Tropsch (FT) synthesis, methanol, and natural gas.

  1. Novel catalysts and photoelectrochemical system for solar fuel production

    NASA Astrophysics Data System (ADS)

    Zhang, Yan

    Solar fuel production from abundant raw chemicals such as CO2 and water is highly desired as a clean renewable energy solution for the future. Developing photoelectrochemical cells is viewed as a promising approach to realize this energy conversion and storage process. Efficient and robust oxygen evolution catalyst made from non-precious materials remains a major challenge for such a system. This thesis basically consists of three parts of work, including studies on enhancing the photocatalytic oxygen evolution activity of cobalt-based spinel nanoparticles by manganese3+ substitution, in situ formation of cobalt oxide nanocubanes as highly active catalyst for photocatalytic oxygen evolution reaction, and development of a photoanode-driven photoelectrochemical cell for CO2 reduction with water. The first part of this thesis work devotes efforts in the development and study on cobalt and other transition metal oxide based oxygen evolution catalyst. Photocatalytic oxygen evolution is a critical step for solar fuel production from abundant sources. It poses a significant challenge because it requires an efficient catalyst to bridge the one-electron photon capture process with the four-electron oxygen reaction. Among all the metal oxides, Co3O4 spinel exhibits a high activity as an oxygen evolution catalyst. The results of this work demonstrate that the photocatalytic oxygen evolution activity of Co3O4 spinel can be further enhanced by substituting Co with Mn in the spinel structure. Using a facile hydrothermal approach, Co3O4 spinel nanoparticles as well as Mn-substituted and Ni-substituted Co3O4 spinel nanoparticles with a typical particle size of 5-7 nm were successfully synthesized. The morphology and crystal structures of the as-synthesized nanoparticle catalysts have been carefully examined using various structural characterization techniques, including powder x-ray diffraction (PXRD), transmission electron microscope (TEM), gas adsorption, and x-ray absorption

  2. Metabolic Engineering for Production of Biorenewable Fuels and Chemicals: Contributions of Synthetic Biology

    PubMed Central

    Jarboe, Laura R.; Zhang, Xueli; Wang, Xuan; Moore, Jonathan C.; Shanmugam, K. T.; Ingram, Lonnie O.

    2010-01-01

    Production of fuels and chemicals through microbial fermentation of plant material is a desirable alternative to petrochemical-based production. Fermentative production of biorenewable fuels and chemicals requires the engineering of biocatalysts that can quickly and efficiently convert sugars to target products at a cost that is competitive with existing petrochemical-based processes. It is also important that biocatalysts be robust to extreme fermentation conditions, biomass-derived inhibitors, and their target products. Traditional metabolic engineering has made great advances in this area, but synthetic biology has contributed and will continue to contribute to this field, particularly with next-generation biofuels. This work reviews the use of metabolic engineering and synthetic biology in biocatalyst engineering for biorenewable fuels and chemicals production, such as ethanol, butanol, acetate, lactate, succinate, alanine, and xylitol. We also examine the existing challenges in this area and discuss strategies for improving biocatalyst tolerance to chemical inhibitors. PMID:20414363

  3. Climate Impact and Economic Feasibility of Solar Thermochemical Jet Fuel Production.

    PubMed

    Falter, Christoph; Batteiger, Valentin; Sizmann, Andreas

    2016-01-01

    Solar thermochemistry presents a promising option for the efficient conversion of H2O and CO2 into liquid hydrocarbon fuels using concentrated solar energy. To explore the potential of this fuel production pathway, the climate impact and economic performance are analyzed. Key drivers for the economic and ecological performance are thermochemical energy conversion efficiency, the level of solar irradiation, operation and maintenance, and the initial investment in the fuel production plant. For the baseline case of a solar tower concentrator with CO2 capture from air, jet fuel production costs of 2.23 €/L and life cycle greenhouse gas (LC GHG) emissions of 0.49 kgCO2-equiv/L are estimated. Capturing CO2 from a natural gas combined cycle power plant instead of the air reduces the production costs by 15% but leads to LC GHG emissions higher than that of conventional jet fuel. Favorable assumptions for all involved process steps (30% thermochemical energy conversion efficiency, 3000 kWh/(m(2) a) solar irradiation, low CO2 and heliostat costs) result in jet fuel production costs of 1.28 €/L at LC GHG emissions close to zero. Even lower production costs may be achieved if the commercial value of oxygen as a byproduct is considered. PMID:26641878

  4. The challenges and opportunities for integration of solar syngas production with liquid fuel synthesis

    NASA Astrophysics Data System (ADS)

    Hinkley, James T.; McNaughton, Robbie K.; Pye, John; Saw, Woei; Stechel, Ellen B.

    2016-05-01

    Reforming of methane is practiced on a vast scale globally for the production of syngas as a precursor for the production of many commodities, including hydrogen, ammonia and synthetic liquid fuels. Solar reforming can reduce the greenhouse gas intensity of syngas production by up to about 40% by using solar thermal energy to provide the endothermic heat of reaction, traditionally supplied by combustion of some of the feed. This has the potential to enable the production of solar derived synthetic fuels as drop in replacements for conventional fuels with significantly lower CO2 intensity than conventional gas to liquids (GTL) processes. However, the intermittent nature of the solar resource - both diurnal and seasonal - poses significant challenges for such a concept, which relies on synthesis processes that typically run continuously on very stable feed compositions. We find that the integration of solar syngas production to a GTL process is a non-trivial exercise, with the ability to turn down the capacity of the GTL synthesis section, and indeed to suspend operations for short periods without significant detriment to product quality or process operability, likely to be a key driver for the commercial implementation of solar liquid fuels. Projected costs for liquid fuel synthesis suggest that solar reforming and small scale gas to liquid synthesis can potentially compete with conventional oil derived transport fuels in the short to medium term.

  5. Climate Impact and Economic Feasibility of Solar Thermochemical Jet Fuel Production.

    PubMed

    Falter, Christoph; Batteiger, Valentin; Sizmann, Andreas

    2016-01-01

    Solar thermochemistry presents a promising option for the efficient conversion of H2O and CO2 into liquid hydrocarbon fuels using concentrated solar energy. To explore the potential of this fuel production pathway, the climate impact and economic performance are analyzed. Key drivers for the economic and ecological performance are thermochemical energy conversion efficiency, the level of solar irradiation, operation and maintenance, and the initial investment in the fuel production plant. For the baseline case of a solar tower concentrator with CO2 capture from air, jet fuel production costs of 2.23 €/L and life cycle greenhouse gas (LC GHG) emissions of 0.49 kgCO2-equiv/L are estimated. Capturing CO2 from a natural gas combined cycle power plant instead of the air reduces the production costs by 15% but leads to LC GHG emissions higher than that of conventional jet fuel. Favorable assumptions for all involved process steps (30% thermochemical energy conversion efficiency, 3000 kWh/(m(2) a) solar irradiation, low CO2 and heliostat costs) result in jet fuel production costs of 1.28 €/L at LC GHG emissions close to zero. Even lower production costs may be achieved if the commercial value of oxygen as a byproduct is considered.

  6. Ultra-clean Fischer-Tropsch (F-T) Fuels Production and Demonstration Project

    SciTech Connect

    Stephen P. Bergin

    2006-06-30

    The objective of the DOE-NETL Fischer-Tropsch (F-T) Production and Demonstration Program was to produce and evaluate F-T fuel derived from domestic natural gas. The project had two primary phases: (1) fuel production of ultra-clean diesel transportation fuels from domestic fossil resources; and (2) demonstration and performance testing of these fuels in engines. The project also included a well-to-wheels economic analysis and a feasibility study of small-footprint F-T plants (SFPs) for remote locations such as rural Alaska. During the fuel production phase, ICRC partnered and cost-shared with Syntroleum Corporation to complete the mechanical design, construction, and operation of a modular SFP that converts natural gas, via F-T and hydro-processing reactions, into hydrogensaturated diesel fuel. Construction of the Tulsa, Oklahoma plant started in August 2002 and culminated in the production of over 100,000 gallons of F-T diesel fuel (S-2) through 2004, specifically for this project. That fuel formed the basis of extensive demonstrations and evaluations that followed. The ultra-clean F-T fuels produced had virtually no sulfur (less than 1 ppm) and were of the highest quality in terms of ignition quality, saturation content, backend volatility, etc. Lubricity concerns were investigated to verify that commercially available lubricity additive treatment would be adequate to protect fuel injection system components. In the fuel demonstration and testing phase, two separate bus fleets were utilized. The Washington DC Metropolitan Area Transit Authority (WMATA) and Denali National Park bus fleets were used because they represented nearly opposite ends of several spectra, including: climate, topography, engine load factor, mean distance between stops, and composition of normally used conventional diesel fuel. Fuel evaluations in addition to bus fleet demonstrations included: bus fleet emission measurements; F-T fuel cold weather performance; controlled engine dynamometer

  7. Production of fuels and chemicals from waste by microbiomes.

    PubMed

    Marshall, Christopher W; LaBelle, Edward V; May, Harold D

    2013-06-01

    The demand for chemicals and fuels will continue to grow simultaneously with the costly requirement to treat solid waste, wastewater, and regarding climate change, carbon dioxide. A dual benefit is at hand if waste could be converted to valuable chemicals. The application of stable chemical producing microbiomes adapted to these waste streams may turn this challenge into an opportunity.

  8. Zero-Gravity Fuel-Cell Product-Water Accumulator

    NASA Technical Reports Server (NTRS)

    Barrera, Thomas P.

    1989-01-01

    Assortment of documents describes simple, passive system that removes water formed from reaction of hydrogen and oxygen in proton-exchange-membrane fuel cell. Designed for use in zero gravity, system does not require any machinery or external source of power. Works by capillary action and differential pressure.

  9. An investigation of synthetic fuel production via chemical looping.

    PubMed

    Zeman, Frank; Castaldi, Marco

    2008-04-15

    Producing liquid hydrocarbon fuels with a reduced greenhouse gas emissions profile would ease the transition to a carbon-neutral energy sector with the transportation industry being the immediate beneficiary followed by the power industry. Revolutionary solutions in transportation, such as electricity and hydrogen, depend on the deployment of carbon capture and storage technologies and/or renewable energy systems. Additionally, high oil prices may increase the development of unconventional sources, such as tar sands, that have a higher emissions profile. One process that is gaining interest is a system for producing reduced carbon fuels though chemical looping technologies. An investigation of the implications of such a process using methane and carbon dioxide that is reformed to yield methanol has been done. An important aspect of the investigation is the use of off-the-shelf technologies to achieve the results. The ability of the process to yield reduced emissions fuels depends on the source for the feed and process heat. For the range of conditions considered, the emissions profile of methanol produced in this method varies from 0.475 to 1.645 moles carbon dioxide per mole methanol. The upper bound can be lowered to 0.750 by applying CCS and/ or using nonfossil heat sources for the reforming. The process provides an initial pathway to incorporate CO2 into fuels independent of electrolytic hydrogen or developments in other sectors of the economy. PMID:18497114

  10. [Electricity production from surplus sludge using microbial fuel cells].

    PubMed

    Jia, Bin; Liu, Zhi-Hua; Li, Xiao-Ming; Yang, Yong-Lin; Yang, Qi; Zeng, Guang-Ming; Liu, Yi-Lin; Liu, Qian-Qian; Zheng, Shi-Wen

    2009-04-15

    A single-chamber and membrane-less microbial fuel cells were successfully started up using anaerobic sludge as inoculums without any chemical substance for 20 d. The electricity generation of the microbial fuel cell using surplus sludge as fuel and the change of substrate were investigated. The results showed that the obtained maximum voltage and power density were 495 mV and 44 mW x m(-2) (fixed 1,000 Omega), and the internal resistance was about 300 Omega during steady state. In a cycle, the removal efficiency of SS and VSS were 27.3% and 28.7%, pH was 6.5-8.0. In addition, the COD increased from 617 mg x L(-1) to 1,150 mg x L(-1) and decreased afterwards with time. The change of glucose was similar to that of COD, glucose increased from 47 mg x L(-1) to 60 mg x L(-1) and decreased afterwards with time. Consequently, the microbial fuel cell can transform chemical energy of surplus sludge into the cleanest electrical energy, and it provides a new way of sludge recycling.

  11. Production, characterization and fuel properties of alternative diesel fuel from pyrolysis of waste plastic grocery bags

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Pyrolysis of HDPE waste grocery bags followed by distillation resulted in a liquid hydrocarbon mixture that consisted of saturated aliphatic paraffins (96.8%), aliphatic olefins (2.6%), and aromatics (0.6%) that corresponded to the boiling range of conventional petroleum diesel fuel (#1 diesel 182–2...

  12. Comparative Study of Laboratory-Scale and Prototypic Production-Scale Fuel Fabrication Processes and Product Characteristics

    SciTech Connect

    Douglas W. Marshall

    2014-10-01

    An objective of the High Temperature Gas Reactor fuel development and qualification program for the United States Department of Energy has been to qualify fuel fabricated in prototypic production-scale equipment. The quality and characteristics of the tristructural isotropic coatings on fuel kernels are influenced by the equipment scale and processing parameters. Some characteristics affecting product quality were suppressed while others have become more significant in the larger equipment. Changes to the composition and method of producing resinated graphite matrix material has eliminated the use of hazardous, flammable liquids and enabled it to be procured as a vendor-supplied feed stock. A new method of overcoating TRISO particles with the resinated graphite matrix eliminates the use of hazardous, flammable liquids, produces highly spherical particles with a narrow size distribution, and attains product yields in excess of 99%. Compact fabrication processes have been scaled-up and automated with relatively minor changes to compact quality to manual laboratory-scale processes. The impact on statistical variability of the processes and the products as equipment was scaled are discussed. The prototypic production-scale processes produce test fuels that meet fuel quality specifications.

  13. 40 CFR 80.1455 - What are the small volume provisions for renewable fuel production facilities and importers?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 16 2011-07-01 2011-07-01 false What are the small volume provisions... ADDITIVES Renewable Fuel Standard § 80.1455 What are the small volume provisions for renewable fuel production facilities and importers? (a) Standard volume threshold. Renewable fuel production...

  14. 40 CFR 80.1455 - What are the small volume provisions for renewable fuel production facilities and importers?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 17 2013-07-01 2013-07-01 false What are the small volume provisions... ADDITIVES Renewable Fuel Standard § 80.1455 What are the small volume provisions for renewable fuel production facilities and importers? (a) Standard volume threshold. Renewable fuel production...

  15. 40 CFR 80.1455 - What are the small volume provisions for renewable fuel production facilities and importers?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 17 2014-07-01 2014-07-01 false What are the small volume provisions... ADDITIVES Renewable Fuel Standard § 80.1455 What are the small volume provisions for renewable fuel production facilities and importers? (a) Standard volume threshold. Renewable fuel production...

  16. 40 CFR 80.1455 - What are the small volume provisions for renewable fuel production facilities and importers?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 17 2012-07-01 2012-07-01 false What are the small volume provisions... ADDITIVES Renewable Fuel Standard § 80.1455 What are the small volume provisions for renewable fuel production facilities and importers? (a) Standard volume threshold. Renewable fuel production...

  17. A Reversible Planar Solid Oxide Fuel-Fed Electrolysis Cell and Solid Oxide Fuel Cell for Hydrogen and Electricity Production Operating on Natural Gas/Biomass Fuels

    SciTech Connect

    Tao, Greg, G.

    2007-03-31

    A solid oxide fuel-assisted electrolysis technique was developed to co-generate hydrogen and electricity directly from a fuel at a reduced cost of electricity. Solid oxide fuel-assisted electrolysis cells (SOFECs), which were comprised of 8YSZ electrolytes sandwiched between thick anode supports and thin cathodes, were constructed and experimentally evaluated at various operation conditions on lab-level button cells with 2 cm2 per-cell active areas as well as on bench-scale stacks with 30 cm2 and 100 cm2 per-cell active areas. To reduce the concentration overpotentials, pore former systems were developed and engineered to optimize the microstructure and morphology of the Ni+8YSZ-based anodes. Chemically stable cathode materials, which possess good electronic and ionic conductivity and exhibit good electrocatalytic properties in both oxidizing and reducing gas atmospheres, were developed and materials properties were investigated. In order to increase the specific hydrogen production rate and thereby reduce the system volume and capital cost for commercial applications, a hybrid system that integrates the technologies of the SOFEC and the solid-oxide fuel cell (SOFC), was developed and successfully demonstrated at a 1kW scale, co-generating hydrogen and electricity directly from chemical fuels.

  18. Metabolic engineering of microorganisms for biofuels production: from bugs to synthetic biology to fuels

    SciTech Connect

    Kuk Lee, Sung; Chou, Howard; Ham, Timothy S.; Soon Lee, Taek; Keasling, Jay D.

    2009-12-02

    The ability to generate microorganisms that can produce biofuels similar to petroleum-based transportation fuels would allow the use of existing engines and infrastructure and would save an enormous amount of capital required for replacing the current infrastructure to accommodate biofuels that have properties significantly different from petroleum-based fuels. Several groups have demonstrated the feasibility of manipulating microbes to produce molecules similar to petroleum-derived products, albeit at relatively low productivity (e.g. maximum butanol production is around 20 g/L). For cost-effective production of biofuels, the fuel-producing hosts and pathways must be engineered and optimized. Advances in metabolic engineering and synthetic biology will provide new tools for metabolic engineers to better understand how to rewire the cell in order to create the desired phenotypes for the production of economically viable biofuels.

  19. Metabolic engineering of microorganisms for biofuels production: from bugs to synthetic biology to fuels.

    PubMed

    Lee, Sung Kuk; Chou, Howard; Ham, Timothy S; Lee, Taek Soon; Keasling, Jay D

    2008-12-01

    The ability to generate microorganisms that can produce biofuels similar to petroleum-based transportation fuels would allow the use of existing engines and infrastructure and would save an enormous amount of capital required for replacing the current infrastructure to accommodate biofuels that have properties significantly different from petroleum-based fuels. Several groups have demonstrated the feasibility of manipulating microbes to produce molecules similar to petroleum-derived products, albeit at relatively low productivity (e.g. maximum butanol production is around 20 g/L). For cost-effective production of biofuels, the fuel-producing hosts and pathways must be engineered and optimized. Advances in metabolic engineering and synthetic biology will provide new tools for metabolic engineers to better understand how to rewire the cell in order to create the desired phenotypes for the production of economically viable biofuels.

  20. Linked strategy for the production of fuels via formose reaction

    PubMed Central

    Deng, Jin; Pan, Tao; Xu, Qing; Chen, Meng-Yuan; Zhang, Ying; Guo, Qing-Xiang; Fu, Yao

    2013-01-01

    Formose reaction converts formaldehyde to carbohydrates. We found that formose reaction can be used linking the biomass gasification with the aqueous-phase processing (APP) to produce liquid transportation fuel in three steps. First, formaldehyde from syn-gas was converted to triose. This was followed by aldol condensation and dehydration to 4-hydroxymethylfurfural (4-HMF). Finally, 4-HMF was hydrogenated to produce 2,4-dimethylfuran (2,4-DMF) or C9-C15 branched-chain alkanes as liquid transportation fuels. In the linked strategy, high energy-consuming pretreatment as well as expensive and polluting hydrolysis of biomass were omitted, but the high energy recovery of APP was inherited. In addition, the hexoketoses via formose reaction could be converted to HMFs directly without isomerization. A potential platform molecule 4-HMF was formed simultaneously in APP. PMID:23393625

  1. Linked strategy for the production of fuels via formose reaction.

    PubMed

    Deng, Jin; Pan, Tao; Xu, Qing; Chen, Meng-Yuan; Zhang, Ying; Guo, Qing-Xiang; Fu, Yao

    2013-01-01

    Formose reaction converts formaldehyde to carbohydrates. We found that formose reaction can be used linking the biomass gasification with the aqueous-phase processing (APP) to produce liquid transportation fuel in three steps. First, formaldehyde from syn-gas was converted to triose. This was followed by aldol condensation and dehydration to 4-hydroxymethylfurfural (4-HMF). Finally, 4-HMF was hydrogenated to produce 2,4-dimethylfuran (2,4-DMF) or C(9)-C(15) branched-chain alkanes as liquid transportation fuels. In the linked strategy, high energy-consuming pretreatment as well as expensive and polluting hydrolysis of biomass were omitted, but the high energy recovery of APP was inherited. In addition, the hexoketoses via formose reaction could be converted to HMFs directly without isomerization. A potential platform molecule 4-HMF was formed simultaneously in APP. PMID:23393625

  2. On-farm production of soybean oil and its properties as a fuel

    SciTech Connect

    Suh, S.R.

    1983-01-01

    This study presents the design of a system for on-farm production of soybean oil for use as a fuel in compression ignition engines. The soybean oil production system consists of a heat exchanger to heat the beans with the exhaust gas of an engine, a screw press and a system for water degumming and drying the expressed crude oil. Optimum parameters of the oil production system were found. The rheological properties of soybean oil, ester of soybean oil and blends of the above with diesel fuel and diesel fuel additives are given. Data on soybean temperature, outlet gas temperature and thermal efficiency were obtained from a developed mathematical model of the heat exchanger. Chemical analyses show that crude oil from the press is similar to that of commercially degummed oil. The degumming process is not needed for the crude oil to be used as a fuel in compression ignition engines. Rheological properties of the soybean oil and soybean oil diesel fuel mixture show that the fluids have viscosities of time independent characteristics and are Newtonian fluids. Diesel fuel additives having low viscosities can be used to lower the viscosity of soybean oil and blends with diesel fuel but the effect is insignificant.

  3. Liquid phase products and solid deposit formation from thermally stressed model jet fuels

    NASA Technical Reports Server (NTRS)

    Kim, W. S.; Bittker, D. A.

    1984-01-01

    The relationship between solid deposit formation and liquid degradation product concentration was studied for the high temperature (400 C) stressing of three hydrocarbon model fuels. A Jet Fuel Thermal Oxidation Tester was used to simulate actual engine fuel system conditions. The effects of fuel type, dissolved oxygen concentration, and hot surface contact time (reaction time) were studied. Effects of reaction time and removal of dissolved oxygen on deposit formation were found to be different for n-dodecane and for 2-ethylnaphthalene. When ten percent tetralin is added to n-dodecane to give a simpler model of an actual jet fuel, the tetralin inhibits both the deposit formation and the degradation of n-dodecane. For 2-ethylnaphthalene primary product analyses indicate a possible self-inhibition at long reaction times of the secondary reactions which form the deposit precursors. The mechanism of the primary breakdown of these fuels is suggested and the primary products which participate in these precursor-forming reactions are identified. Some implications of the results to the thermal degradation of real jet fuels are given.

  4. Economic and energetic evaluation of alcohol fuel production from agriculture: Yolo County, California

    SciTech Connect

    Meo, M.

    1983-01-01

    This dissertation reviews the technical aspects of alcohol fuel production and consumption, examines the set of policy-related issues that affect both the private and the public sectors, and investigates the economic and energetic feasibility of small-scale on-farm production on a representative Sacramento Valley field and vegetable crop farm. Candidate feedstocks, including both starch and sugar-rich crops, are: barley, corn, fodder beet, grain sorghum, Jerusalem artichoke, sugar beet, sweet sorghum, tomatoes, and wheat. The leading fuel crops were found to be sweet sorghum, Jerusalem artichoke, corn, fodder beet, and grain sorghum in order of declining preference. With better than average crop yields and the current mix of financial incentives, the breakeven cost of alcohol fuel is $1.03 per gallon when diesel fuel and gasoline prices are $1.30 and $1.46, respectively. Without subsidy, the breakeven cost is $1.62 per gallon. An energy analysis was calculated for each of the feedstocks under consideration. With the exception of sweet sorghum, wheat, and barley, all feedstocks showed a negative net energy balance. The use of agricultural residues as a boiler fuel, however, made a significant difference in the overall energy balance. The role of government in energy policy is reviewed and typical policy instruments are discussed. Although on-farm alcohol fuel production is not currently economically competitive with gasoline and diesel fuel, technological innovation and the return of increasing petroleum prices could alter the situation.

  5. Fuel gas production by microwave plasma in liquid

    SciTech Connect

    Nomura, Shinfuku; Toyota, Hiromichi; Tawara, Michinaga; Yamashita, Hiroshi; Matsumoto, Kenya

    2006-06-05

    We propose to apply plasma in liquid to replace gas-phase plasma because we expect much higher reaction rates for the chemical deposition of plasma in liquid than for chemical vapor deposition. A reactor for producing microwave plasma in a liquid could produce plasma in hydrocarbon liquids and waste oils. Generated gases consist of up to 81% hydrogen by volume. We confirmed that fuel gases such as methane and ethylene can be produced by microwave plasma in liquid.

  6. ULTRA-CLEAN FISCHER-TROPSCH FUELS PRODUCTION AND DEMONSTRATION PROJECT

    SciTech Connect

    Steve Bergin

    2004-10-18

    The Report Abstract provides summaries of the past year's activities relating to each of the main project objectives. Some of the objectives will be expanded on in greater detail further down in the report. The following objectives have their own addition sections in the report: SFP Construction and Fuel Production, Impact of SFP Fuel on Engine Performance, Fleet Testing at WMATA and Denali National Park, Demonstration of Clean Diesel Fuels in Diesel Electric Generators in Alaska, and Economic Analysis. ICRC provided overall project organization and budget management for the project. ICRC held meetings with various project participants. ICRC presented at the Department of Energy's annual project review meeting. The plant began producing fuel in October 2004. The first delivery of finished fuel was made in March of 2004 after the initial start-up period.

  7. Fuel age impacts on gaseous fission product capture during separations

    SciTech Connect

    Jubin, Robert T.; Soelberg, Nicolas R.; Strachan, Denis M.; Ilas, G.

    2012-09-21

    As a result of fuel reprocessing, volatile radionuclides will be released from the facility stack if no processes are put in place to remove them. The radionuclides that are of concern in this document are 3H, 14C, 85Kr, and 129 Rosnick 2007 I. The question we attempt to answer is how efficient must this removal process be for each of these radionuclides? To answer this question, we examine the three regulations that may impact the degree to which these radionuclides must be reduced before process gases can be released from the facility. These regulations are 40 CFR 61 (EPA 2010a), 40 CFR 190(EPA 2010b), and 10 CFR 20 (NRC 2012), and they apply to the total radonuclide release and to the dose to a particular organ – the thyroid. Because these doses can be divided amongst all the radionuclides in different ways and even within the four radionuclides in question, several cases are studied. These cases consider for the four analyzed radionuclides inventories produced for three fuel types—pressurized water reactor uranium oxide (PWR UOX), pressurized water reactor mixed oxide (PWR MOX), and advanced high-temperature gascooled reactor (AHTGR)—several burnup values and time out of reactor extending to 200 y. Doses to the maximum exposed individual (MEI) are calculated with the EPA code CAP-88 ( , 1992). Two dose cases are considered. The first case, perhaps unrealistic, assumes that all of the allowable dose is assigned to the volatile radionuclides. In lieu of this, for the second case a value of 10% of the allowable dose is arbitrarily selected to be assigned to the volatile radionuclides. The required decontamination factors (DFs) are calculated for both of these cases, including the case for the thyroid dose for which 14C and 129I are the main contributors. However, for completeness, for one fuel type and burnup, additional cases are provided, allowing 25% and 50% of the allowable dose to be assigned to the volatile radionuclides. Because 3H and 85Kr have

  8. A physical description of fission product behavior fuels for advanced power reactors.

    SciTech Connect

    Kaganas, G.; Rest, J.; Nuclear Engineering Division; Florida International Univ.

    2007-10-18

    The Global Nuclear Energy Partnership (GNEP) is considering a list of reactors and nuclear fuels as part of its chartered initiative. Because many of the candidate materials have not been explored experimentally under the conditions of interest, and in order to economize on program costs, analytical support in the form of combined first principle and mechanistic modeling is highly desirable. The present work is a compilation of mechanistic models developed in order to describe the fission product behavior of irradiated nuclear fuel. The mechanistic nature of the model development allows for the possibility of describing a range of nuclear fuels under varying operating conditions. Key sources include the FASTGRASS code with an application to UO{sub 2} power reactor fuel and the Dispersion Analysis Research Tool (DART ) with an application to uranium-silicide and uranium-molybdenum research reactor fuel. Described behavior mechanisms are divided into subdivisions treating fundamental materials processes under normal operation as well as the effect of transient heating conditions on these processes. Model topics discussed include intra- and intergranular gas-atom and bubble diffusion, bubble nucleation and growth, gas-atom re-solution, fuel swelling and ?scion gas release. In addition, the effect of an evolving microstructure on these processes (e.g., irradiation-induced recrystallization) is considered. The uranium-alloy fuel, U-xPu-Zr, is investigated and behavior mechanisms are proposed for swelling in the {alpha}-, intermediate- and {gamma}-uranium zones of this fuel. The work reviews the FASTGRASS kinetic/mechanistic description of volatile ?scion products and, separately, the basis for the DART calculation of bubble behavior in amorphous fuels. Development areas and applications for physical nuclear fuel models are identified.

  9. Energy balances in the production and end use of alcohols derived from biomass. A fuels-specific comparative analysis of alternate ethanol production cycles

    SciTech Connect

    Not Available

    1980-10-01

    Considerable public interest and debate have been focused on the so-called energy balance issue involved in the conversion of biomass materials into ethanol for fuel use. This report addresses questions of net gains in premium fuels that can be derived from the production and use of ethanol from biomass, and shows that for the US alcohol fuel program, energy balance need not be a concern. Three categories of fuel gain are discussed in the report: (1) Net petroleum gain; (2) Net premium fuel gain (petroleum and natural gas); and (3) Net energy gain (for all fuels). In this study the investment of energy (in the form of premium fuels) in alcohol production includes all investment from cultivating, harvesting, or gathering the feedstock and raw materials, through conversion of the feedstock to alcohol, to the delivery to the end-user. To determine the fuel gains in ethanol production, six cases, encompassing three feedstocks, five process fuels, and three process variations, have been examined. For each case, two end-uses (automotive fuel use and replacement of petrochemical feedstocks) were scrutinized. The end-uses were further divided into three variations in fuel economy and two different routes for production of ethanol from petrochemicals. Energy requirements calculated for the six process cycles accounted for fuels used directly and indirectly in all stages of alcohol production, from agriculture through distribution of product to the end-user. Energy credits were computed for byproducts according to the most appropriate current use.

  10. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  11. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect

    Paul A. Erickson

    2006-01-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the ninth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2005-December 31, 2005. This quarter saw progress in four areas. These areas are: (1) reformate purification, (2) heat transfer enhancement, (3) autothermal reforming coal-derived methanol degradation test; and (4) model development for fuel cell system integration. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  12. Fuel From Farms: A Guide to Small-Scale Ethanol Production.

    ERIC Educational Resources Information Center

    Solar Energy Research Inst., Golden, CO.

    Ethanol and blends of ethanol and gasoline (such as gasohol) offer a near-term fuel alternative to oil. The focus of this handbook is upon the small-scale production of ethanol using farm crops as the source of raw materials. Provided are chapters on ethanol production procedures, feedstocks, plant design, and financial planning. Also presented…

  13. Ceria-thoria pellet manufacturing in preparation for plutonia-thoria LWR fuel production

    NASA Astrophysics Data System (ADS)

    Drera, Saleem S.; Björk, Klara Insulander; Sobieska, Matylda

    2016-10-01

    Thorium dioxide (thoria) has potential to assist in niche roles as fuel for light water reactors (LWRs). One such application for thoria is its use as the fertile component to burn plutonium in a mixed oxide fuel (MOX). Thor Energy and an international consortium are currently irradiating plutonia-thoria (Th-MOX) fuel in an effort to produce data for its licensing basis. During fuel-manufacturing research and development (R&D), surrogate materials were utilized to highlight procedures and build experience. Cerium dioxide (ceria) provides a good surrogate platform to replicate the chemical nature of plutonium dioxide. The project's fuel manufacturing R&D focused on powder metallurgical techniques to ensure manufacturability with the current commercial MOX fuel production infrastructure. The following paper highlights basics of the ceria-thoria fuel production including powder milling, pellet pressing and pellet sintering. Green pellets and sintered pellets were manufactured with average densities of 67.0% and 95.5% that of theoretical density respectively.

  14. Estimate of the Sources of Plutonium-Containing Wastes Generated from MOX Fuel Production in Russia

    SciTech Connect

    Kudinov, K. G.; Tretyakov, A. A.; Sorokin, Yu. P.; Bondin, V. V.; Manakova, L. F.; Jardine, L. J.

    2002-02-26

    In Russia, mixed oxide (MOX) fuel is produced in a pilot facility ''Paket'' at ''MAYAK'' Production Association. The Mining-Chemical Combine (MCC) has developed plans to design and build a dedicated industrial-scale plant to produce MOX fuel and fuel assemblies (FA) for VVER-1000 water reactors and the BN-600 fast-breeder reactor, which is pending an official Russian Federation (RF) site-selection decision. The design output of the plant is based on a production capacity of 2.75 tons of weapons plutonium per year to produce the resulting fuel assemblies: 1.25 tons for the BN-600 reactor FAs and the remaining 1.5 tons for VVER-1000 FAs. It is likely the quantity of BN-600 FAs will be reduced in actual practice. The process of nuclear disarmament frees a significant amount of weapons plutonium for other uses, which, if unutilized, represents a constant general threat. In France, Great Britain, Belgium, Russia, and Japan, reactor-grade plutonium is used in MOX-fuel production. Making MOX-fuel for CANDU (Canada) and pressurized water reactors (PWR) (Europe) is under consideration in Russia. If this latter production is added, as many as 5 tons of Pu per year might be processed into new FAs in Russia. Many years of work and experience are represented in the estimates of MOX fuel production wastes derived in this report. Prior engineering studies and sludge treatment investigations and comparisons have determined how best to treat Pu sludges and MOX fuel wastes. Based upon analyses of the production processes established by these efforts, we can estimate that there will be approximately 1200 kg of residual wastes subject to immobilization per MT of plutonium processed, of which approximately 6 to 7 kg is Pu in the residuals per MT of Pu processed. The wastes are various and complicated in composition. Because organic wastes constitute both the major portion of total waste and of the Pu to be immobilized, the recommended treatment of MOX-fuel production waste is

  15. Hydrogen Gas Production from Nuclear Power Plant in Relation to Hydrogen Fuel Cell Technologies Nowadays

    SciTech Connect

    Yusibani, Elin; Kamil, Insan; Suud, Zaki

    2010-06-22

    Recently, world has been confused by issues of energy resourcing, including fossil fuel use, global warming, and sustainable energy generation. Hydrogen may become the choice for future fuel of combustion engine. Hydrogen is an environmentally clean source of energy to end-users, particularly in transportation applications because without release of pollutants at the point of end use. Hydrogen may be produced from water using the process of electrolysis. One of the GEN-IV reactors nuclear projects (HTGRs, HTR, VHTR) is also can produce hydrogen from the process. In the present study, hydrogen gas production from nuclear power plant is reviewed in relation to commercialization of hydrogen fuel cell technologies nowadays.

  16. Hydrogen Gas Production from Nuclear Power Plant in Relation to Hydrogen Fuel Cell Technologies Nowadays

    NASA Astrophysics Data System (ADS)

    Yusibani, Elin; Kamil, Insan; Suud, Zaki

    2010-06-01

    Recently, world has been confused by issues of energy resourcing, including fossil fuel use, global warming, and sustainable energy generation. Hydrogen may become the choice for future fuel of combustion engine. Hydrogen is an environmentally clean source of energy to end-users, particularly in transportation applications because without release of pollutants at the point of end use. Hydrogen may be produced from water using the process of electrolysis. One of the GEN-IV reactors nuclear projects (HTGRs, HTR, VHTR) is also can produce hydrogen from the process. In the present study, hydrogen gas production from nuclear power plant is reviewed in relation to commercialization of hydrogen fuel cell technologies nowadays.

  17. Estimate of the Sources of Plutonium-Containing Wastes Generated from MOX Fuel Production in Russia

    SciTech Connect

    Kudinov, K.G.; Tretyakov, A.A.; Sorokin, Y.P.; Bondin, V.V.; Manakova, L.F.; Jardine, L.J.

    2001-12-01

    In Russia, mixed oxide (MOX) fuel is produced in a pilot facility ''Paket'' at ''MAYAK'' Production Association. The Mining-Chemical Combine (MCC) has developed plans to design and build a dedicated industrial-scale plant to produce MOX fuel and fuel assemblies (FA) for VVER-1000 water reactors and the BN-600 fast-breeder reactor, which is pending an official Russian Federation (RF) site-selection decision. The design output of the plant is based on production capacity of 2.75 tons of weapons plutonium per year to produce the resulting fuel assemblies: 1.25 tons for the BN-600 reactor FAs and the remaining 1.5 tons for VVER-1000 FAs. It is likely the quantity of BN-600 FAs will be reduced in actual practice. The process of nuclear disarmament frees a significant amount of weapons plutonium for other uses, which, if unutilized, represents a constant general threat. In France, Great Britain, Belgium, Russia, and Japan, reactor-grade plutonium is used in MOX-fuel production. Making MOX-fuel for CANDU (Canada) and pressurized water reactors (PWR) (Europe) is under consideration Russia. If this latter production is added, as many as 5 tons of Pu per year might be processed into new FAs in Russia. Many years of work and experience are represented in the estimates of MOX fuel production wastes derived in this report. Prior engineering studies and sludge treatment investigations and comparisons have determined how best to treat Pu sludges and MOX fuel wastes. Based upon analyses of the production processes established by these efforts, we can estimate that there will be approximately 1200 kg of residual wastes subject to immobilization per MT of plutonium processed, of which approximately 6 to 7 kg is Pu in the residuals per MT of Pu processed. The wastes are various and complicated in composition. Because organic wastes constitute both the major portion of total waste and of the Pu to be immobilized, the recommended treatment of MOX-fuel production waste is incineration

  18. Production of solar fuels by CO2 plasmolysis

    NASA Astrophysics Data System (ADS)

    Goede, Adelbert P. H.; Bongers, Waldo A.; Graswinckel, Martijn F.; M. C. M van de Sanden, Richard; Leins, Martina; Kopecki, Jochen; Schulz, Andreas; Walker, Mathias

    2014-12-01

    A storage scheme for Renewable Energy (RE) based on the plasmolysis of CO2into CO and O2 has been experimentally investigated, demonstrating high energy efficiency (>50%) combined with high energy density, rapid start-stop and no use of scarce materials. The key parameter controlling energy efficiency has been identified as the reduced electric field. Basic plasma parameters including density and temperature are derived from a simple particle and energy balance model, allowing parameter specification of an upscale 100 kW reactor. With RE powered plasmolysis as the critical element, a CO2 neutral energy system becomes feasible when complemented by effective capture of CO2 at the input and separation of CO from the output gas stream followed by downstream chemical processing into hydrocarbon fuels.

  19. Fuel ethanol production from Jerusalem artichoke stalks using different yeasts

    SciTech Connect

    Margaritis, A.; Bajpai, P.; Bajpai, P.K.

    1983-01-01

    The inulin-type sugars present in the stalks of Jerusalem artichoke (Helianthus tuberosus) were extracted with hot water and were used as a substrate to produce fuel EtOH. Seven different yeasts were used to obtain batch kinetic data. The medium consisted of stalk extract from Jerusalem artichoke containing 7.3% total sugars, supplemented with 0.01% oleic acid, 0.01% corn steep liquor, and 0.05% Tween 80. All batch fermentations were carried out in a 1-L bioreactor at 35 degrees and pH 4.6, and the following parameters were measured as a function of time: total sugars, EtOH and biomass concentration, maximum specific growth rate, and biomass and EtOH yields. The best EtOH producer was Kluyveromyces marxianus UCD (FST) 55-82 which gave an EtOH-to-sugar yield 97% of the theoretical maximum value, with almost 100% sugar utilization.

  20. Silvicultural systems for the energy efficient production of fuel biomass

    SciTech Connect

    Ledig, F.T.

    1981-01-01

    Production of biomass by forests is highly energy efficient. Purely exploitative schemes are more efficient than highly intensive silviculture. However, net energy yield increases with intensity of cultivation, so silvicultural systems approaching those of agricultural cropping should be favored from an energy production standpoint. Efficiency can be further increased by breeding, an area neglected in forestry for centuries after it had become a proven assist in agriculture. The rate of production of biomass can be increased by breeding for rapid growth. Simultaneously, it may be possible to reduce energy inputs by breeding for trees that do not require supplemental fertilization or by engineering new symbiotic relationships with nitrogen-fixing organisms.

  1. 48 CFR 908.7109 - Fuels and packaged petroleum products.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... offices shall be in accordance with FPMR 41 CFR 101-26.602. When contractors are authorized, consistent... CFR 101-26.602. ... petroleum products. 908.7109 Section 908.7109 Federal Acquisition Regulations System DEPARTMENT OF...

  2. 48 CFR 908.7109 - Fuels and packaged petroleum products.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... offices shall be in accordance with FPMR 41 CFR 101-26.602. When contractors are authorized, consistent... CFR 101-26.602. ... petroleum products. 908.7109 Section 908.7109 Federal Acquisition Regulations System DEPARTMENT OF...

  3. 48 CFR 908.7109 - Fuels and packaged petroleum products.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... offices shall be in accordance with FPMR 41 CFR 101-26.602. When contractors are authorized, consistent... CFR 101-26.602. ... petroleum products. 908.7109 Section 908.7109 Federal Acquisition Regulations System DEPARTMENT OF...

  4. 48 CFR 908.7109 - Fuels and packaged petroleum products.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... offices shall be in accordance with FPMR 41 CFR 101-26.602. When contractors are authorized, consistent... CFR 101-26.602. ... petroleum products. 908.7109 Section 908.7109 Federal Acquisition Regulations System DEPARTMENT OF...

  5. 48 CFR 908.7109 - Fuels and packaged petroleum products.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... offices shall be in accordance with FPMR 41 CFR 101-26.602. When contractors are authorized, consistent... CFR 101-26.602. ... petroleum products. 908.7109 Section 908.7109 Federal Acquisition Regulations System DEPARTMENT OF...

  6. Liquid Fuel Production from Biomass via High Temperature Steam Electrolysis

    SciTech Connect

    Grant L. Hawkes; Michael G. McKellar

    2009-11-01

    A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-fed biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

  7. Impact of alcohol fuel production on agricultural markets

    SciTech Connect

    Gardiner, W.H.

    1986-01-01

    Production of alcohol from biomass feedstocks, such as corn, was given Federal and State support which resulted in alcohol production rising from 20 million gallons in 1979 to 430 million gallons in 1984. This study estimates the impacts of alcohol production from corn on selected agricultural markets. The tool of analysis was a three region (United States, the European Community and the rest of the world) econometric model of the markets for corn, soybeans, soybean meal, soybean oil, wheat and corn byproduct feeds. Three alternative growth paths for alcohol production (totalling 1.1, 2.0, and 3.0 billion gallons) were analyzed with the model in the context of three different trade environments. The results of this analysis indicate that alcohol production of 1.1 billion gallons by 1980 would have caused moderate adjustments to commodity markets while 3.0 billion gallons would have caused major adjustments. Corn prices rose sharply with increased alcohol production as did wheat prices but to a somewhat lesser extent. The substitution of corn for soybeans on the supply side was not sufficient to offset the demand depressing effects of corn byproduct feeds on soybean meal which translated into slightly lower soybean prices. A quota limiting imports of corn gluten feed into the EC to three million tons annually would cause reductions in export earnings for corn millers.

  8. Further studies on the modulation of fossil fuel production by global temperature variations

    SciTech Connect

    Rust, B.W.; Crosby, F.J. )

    1994-01-01

    This study extends the earlier work of Rust and Kirk (1982) on the inverse modulation of global fossil fuel production by variations in Northern Hemispheric temperatures. Recent revisions and extensions of the fuel production record are incorporated and a much improved temperature record in used. The new data are consistent with the predictions of the original Rust-Kirk model which is extended to allow for time lags between variations in the temperature and the corresponding responses in fuel production. The modulation enters the new model through the convolution of a lagged averaging function with the temperature time-series. Explicit terms account for the perturbations caused by the Great Depression and World War II. The final model accounts for 99.84% of the total variance in the production record. The temperature modulation produces variations of as much as 30% in the total production. This modulation represents a feedback which is consistent with the predictions of the Gaia hypothesis for a planetary greenhouse temperature control. The new model calculates 20-y fuel production predictions for three temperature scenarios which hopefully bracket the possibilities for temperature behavior during that time.

  9. Biofuels Fuels Technology Pathway Options for Advanced Drop-in Biofuels Production

    SciTech Connect

    Kevin L Kenney

    2011-09-01

    Advanced drop-in hydrocarbon biofuels require biofuel alternatives for refinery products other than gasoline. Candidate biofuels must have performance characteristics equivalent to conventional petroleum-based fuels. The technology pathways for biofuel alternatives also must be plausible, sustainable (e.g., positive energy balance, environmentally benign, etc.), and demonstrate a reasonable pathway to economic viability and end-user affordability. Viable biofuels technology pathways must address feedstock production and environmental issues through to the fuel or chemical end products. Potential end products include compatible replacement fuel products (e.g., gasoline, diesel, and JP8 and JP5 jet fuel) and other petroleum products or chemicals typically produced from a barrel of crude. Considering the complexity and technology diversity of a complete biofuels supply chain, no single entity or technology provider is capable of addressing in depth all aspects of any given pathway; however, all the necessary expert entities exist. As such, we propose the assembly of a team capable of conducting an in-depth technology pathway options analysis (including sustainability indicators and complete LCA) to identify and define the domestic biofuel pathways for a Green Fleet. This team is not only capable of conducting in-depth analyses on technology pathways, but collectively they are able to trouble shoot and/or engineer solutions that would give industrial technology providers the highest potential for success. Such a team would provide the greatest possible down-side protection for high-risk advanced drop-in biofuels procurement(s).

  10. Alternate routes for the production of fuels from coal and natural gas

    SciTech Connect

    Gray, D.; Tomlinson, G.; ElSawy, A.

    1994-06-01

    Almost all transportation worldwide is powered by high energy-density liquid hydrocarbon fuels produced from crude oil. Transportation fuels currently use over 50 percent of total world petroleum demand of 66 million barrels per day. Prior MITRE studies indicate that crude oil supply will become severely limited after the year 2030 as increasing world energy demand, driven by population growth and economic development, depletes oil resources. If conventional liquid hydrocarbon fuels that can use existing production and distribution infrastructures are still needed for transportation in the future, then alternate sources of these fuels will have to be utilized. Two such sources are natural gas and coal. Natural gas reserves worldwide are expected to last well into the 21st century, and coal resources are enormous. This paper examines the technologies for producing environmentally superior liquid transportation fuels from coal and natural gas using modern conversion technologies. Estimates of the costs of fuels from these sources are given, and the potential environmental impacts of these fuels are examined.

  11. Demand for waste as fuel in the swedish district heating sector: a production function approach.

    PubMed

    Furtenback, Orjan

    2009-01-01

    This paper evaluates inter-fuel substitution in the Swedish district heating industry by analyzing almost all the district heating plants in Sweden in the period 1989-2003, specifically those plants incinerating waste. A multi-output plant-specific production function is estimated using panel data methods. A procedure for weighting the elasticities of factor demand to produce a single matrix for the whole industry is introduced. The price of waste is assumed to increase in response to the energy and CO2 tax on waste-to-energy incineration that was introduced in Sweden on 1 July 2006. Analysis of the plants involved in waste incineration indicates that an increase in the net price of waste by 10% is likely to reduce the demand for waste by 4.2%, and increase the demand for bio-fuels, fossil fuels, other fuels and electricity by 5.5%, 6.0%, 6.0% and 6.0%, respectively.

  12. Production of biomass fuel for resource recovery: Trash recycling in Dade County, Florida

    SciTech Connect

    Mauriello, P.J.; Brooks, K.G.

    1997-12-01

    Dade County, Florida has been in the forefront of resources recovery from municipal solid waste since the early 1980`s. The County completed its 3,000 tons per day (six days per week) refuse derived fuel waste-to-energy facility in 1982. The Resources Recovery facility is operated under a long-term agreement with Montenay-Dade, Ltd. The trash processing capability of this facility was upgraded in 1997 to process 860 tons per day (six days per week) of trash into a biomass fuel which is used off-site to produce electrical energy. Under current Florida law, facilities like trash-to-fuel that produce alternative clean-burning fuels for the production of energy may receive credit for up to one-half of the state`s 30 percent waste reduction goal.

  13. ERC product improvement activities for direct fuel cell power plants

    SciTech Connect

    Bentley, C.; Carlson, G.; Doyon, J.

    1995-08-01

    This program is designed to advance the carbonate fuel cell technology from the current power plant demonstration status to the commercial design in an approximately five-year period. The specific objectives which will allow attainment of the overall program goal are: (1) Define market-responsive power plant requirements and specifications, (2) Establish the design for a multifuel, low-cost, modular, market-responsive power plant, (3) Resolve power plant manufacturing issues and define the design for the commercial manufacturing facility, (4) Define the stack and BOP equipment packaging arrangement and define module designs, (5) Acquire capability to support developmental testing of stacks and BOP equipment as required to prepare for commercial design, and (6) Resolve stack and BOP equipment technology issues and design, build, and field test a modular commercial prototype power plant to demonstrate readiness for commercial entry. A seven-task program, dedicated to attaining objective(s) in the areas noted above, was initiated in December 1994. Accomplishments of the first six months are discussed in this paper.

  14. Solar photochemical process engineering for production of fuels and chemicals

    NASA Technical Reports Server (NTRS)

    Biddle, J. R.; Peterson, D. B.; Fujita, T.

    1985-01-01

    The engineering costs and performance of a nominal 25,000 scmd (883,000 scfd) photochemical plant to produce dihydrogen from water were studied. Two systems were considered, one based on flat-plate collector/reactors and the other on linear parabolic troughs. Engineering subsystems were specified including the collector/reactor, support hardware, field transport piping, gas compression equipment, and balance-of-plant (BOP) items. Overall plant efficiencies of 10.3 and 11.6 percent are estimated for the flat-plate and trough systems, respectively, based on assumed solar photochemical efficiencies of 12.9 and 14.6 percent. Because of the opposing effects of concentration ratio and operating temperature on efficiency, it was concluded that reactor cooling would be necessary with the trough system. Both active and passive cooling methods were considered. Capital costs and energy costs, for both concentrating and non-concentrating systems, were determined and their sensitivity to efficiency and economic parameters were analyzed. The overall plant efficiency is the single most important factor in determining the cost of the fuel.

  15. Submersible microbial fuel cell for electricity production from sewage sludge.

    PubMed

    Zhang, Yifeng; Olias, Lola Gonzalez; Kongjan, Prawit; Angelidaki, Irini

    2011-01-01

    A submersible microbial fuel cell (SMFC) was utilized to treat sewage sludge and simultaneously generate electricity. Stable power generation (145 +/- 5 mW/m2, 470 omega) was produced continuously from raw sewage sludge for 5.5 days. The maximum power density reached 190 +/- 5 mW/m2. The corresponding total chemical oxygen demand (TCOD) removal efficiency was 78.1 +/- 0.2% with initial TCOD of 49.7 g/L. The power generation of SMFC was depended on the sludge concentration, while dilution of the raw sludge resulted in higher power density. The maximum power density was saturated at sludge concentration of 17 g-TCOD/L, where 290 mw/m2 was achieved. When effluents from an anaerobic digester that was fed with raw sludge were used as substrate in the SMFC, a maximum power density of 318 mW/m2, and a final TCOD removal of 71.9 +/- 0.2% were achieved. These results have practical implications for development of an effective system to treat sewage sludge and simultaneously recover energy.

  16. ERC product improvement activities for direct fuel cell power plants

    SciTech Connect

    Maru, H.C.; Farooque, M.; Bentley, C.

    1995-12-01

    This program is designed to advance the carbonate fuel cell technology from the current power plant demonstration status to the commercial design in an approximately five-year period. The specific objectives which will allow attainment of the overall program goal are: (1) Define market-responsive power plant requirements and specifications, (2) Establish the design for a multifuel, low-cost, modular, market-responsive power plant, (3) Resolve power plant manufacturing issues and define the design for the commercial manufacturing facility, (4) Define the stack and BOP equipment packaging arrangement and define module designs, (5) Acquire capability to support developmental testing of stacks and BOP equipment as required to prepare for commercial design, and (6) Resolve stack and BOP equipment technology issues and design, build, and field test a modular commercial prototype power plant to demonstrate readiness for commercial entry. A seven-task program, dedicated to attaining objective(s) in the areas noted above, was initiated in December 1994. Accomplishments of the first six months are discussed in this paper.

  17. Solar photochemical process engineering for production of fuels and chemicals

    NASA Technical Reports Server (NTRS)

    Biddle, J. R.; Peterson, D. B.; Fujita, T.

    1984-01-01

    The engineering costs and performance of a nominal 25,000 scmd (883,000 scfd) photochemical plant to produce dihydrogen from water were studied. Two systems were considered, one based on flat-plate collector/reactors and the other on linear parabolic troughs. Engineering subsystems were specified including the collector/reactor, support hardware, field transport piping, gas compression equipment, and balance-of-plant (BOP) items. Overall plant efficiencies of 10.3 and 11.6% are estimated for the flat-plate and trough systems, respectively, based on assumed solar photochemical efficiencies of 12.9 and 14.6%. Because of the opposing effects of concentration ratio and operating temperature on efficiency, it was concluded that reactor cooling would be necessary with the trough system. Both active and passive cooling methods were considered. Capital costs and energy costs, for both concentrating and non-concentrating systems, were determined and their sensitivity to efficiency and economic parameters were analyzed. The overall plant efficiency is the single most important factor in determining the cost of the fuel.

  18. Process for making a martensitic steel alloy fuel cladding product

    DOEpatents

    Johnson, Gerald D.; Lobsinger, Ralph J.; Hamilton, Margaret L.; Gelles, David S.

    1990-01-01

    This is a very narrowly defined martensitic steel alloy fuel cladding material for liquid metal cooled reactors, and a process for making such a martensitic steel alloy material. The alloy contains about 10.6 wt. % chromium, about 1.5 wt. % molybdenum, about 0.85 wt. % manganese, about 0.2 wt. % niobium, about 0.37 wt. % silicon, about 0.2 wt. % carbon, about 0.2 wt. % vanadium, 0.05 maximum wt. % nickel, about 0.015 wt. % nitrogen, about 0.015 wt. % sulfur, about 0.05 wt. % copper, about 0.007 wt. % boron, about 0.007 wt. % phosphorous, and with the remainder being essentially iron. The process utilizes preparing such an alloy and homogenizing said alloy at about 1000.degree. C. for 16 hours; annealing said homogenized alloy at 1150.degree. C. for 15 minutes; and tempering said annealed alloy at 700.degree. C. for 2 hours. The material exhibits good high temperature strength (especially long stress rupture life) at elevated temperature (500.degree.-760.degree. C.).

  19. Submersible microbial fuel cell for electricity production from sewage sludge.

    PubMed

    Zhang, Yifeng; Olias, Lola Gonzalez; Kongjan, Prawit; Angelidaki, Irini

    2011-01-01

    A submersible microbial fuel cell (SMFC) was utilized to treat sewage sludge and simultaneously generate electricity. Stable power generation (145 +/- 5 mW/m2, 470 omega) was produced continuously from raw sewage sludge for 5.5 days. The maximum power density reached 190 +/- 5 mW/m2. The corresponding total chemical oxygen demand (TCOD) removal efficiency was 78.1 +/- 0.2% with initial TCOD of 49.7 g/L. The power generation of SMFC was depended on the sludge concentration, while dilution of the raw sludge resulted in higher power density. The maximum power density was saturated at sludge concentration of 17 g-TCOD/L, where 290 mw/m2 was achieved. When effluents from an anaerobic digester that was fed with raw sludge were used as substrate in the SMFC, a maximum power density of 318 mW/m2, and a final TCOD removal of 71.9 +/- 0.2% were achieved. These results have practical implications for development of an effective system to treat sewage sludge and simultaneously recover energy. PMID:22053457

  20. Kinetics study on biomass pyrolysis for fuel gas production.

    PubMed

    Chen, Guan-Yi; Fang, Meng-Xiang; Andries, J; Luo, Zhong-Yang; Spliethoff, H; Cen, Ke-Fa

    2003-01-01

    Kinetic knowledge is of great importance in achieving good control of the pyrolysis and gasification process and optimising system design. An overall kinetic pyrolysis scheme is therefore addressed here. The kinetic modelling incorporates the following basic steps: the degradation of the virgin biomass materials into primary products (tar, gas and semi-char), the decomposition of primary tar into secondary products and the continuous interaction between primary gas and char. The last step is disregarded completely by models in the literature. Analysis and comparison of predicted results from different kinetic schemes and experimental data on our fixed bed pyrolyser yielded very positive evidence to support our kinetic scheme. PMID:12861621

  1. Production of coal-based fuels and value-added products: coal to liquids using petroleum refinery streams

    SciTech Connect

    Clifford, C.E.B.; Schobert, H.H.

    2008-07-01

    We are studying several processes that utilize coal, coal-derived materials, or biomass in existing refining facilities. A major emphasis is the production of a coal-based replacement for JP-8 jet fuel. This fuel is very similar to Jet A and jet A-1 in commercial variation, so this work has significant carry-over into the private sector. We have been focusing on three processes that would be retrofitted into a refinery: (1) coal tar/refinery stream blending and hydro-treatment; (2) coal extraction using refinery streams followed by hydro-treatment; and (3) co-coking of coal blended with refinery streams. 4 figs., 5 tabs.

  2. Determination of Combustion Product Radicals in a Hydrocarbon Fueled Rocket Exhaust Plume

    NASA Technical Reports Server (NTRS)

    Langford, Lester A.; Allgood, Daniel C.; Junell, Justin C.

    2007-01-01

    The identification of metallic effluent materials in a rocket engine exhaust plume indicates the health of the engine. Since 1989, emission spectroscopy of the plume of the Space Shuttle Main Engine (SSME) has been used for ground testing at NASA's Stennis Space Center (SSC). This technique allows the identification and quantification of alloys from the metallic elements observed in the plume. With the prospect of hydrocarbon-fueled rocket engines, such as Rocket Propellant 1 (RP-1) or methane (CH4) fueled engines being considered for use in future space flight systems, the contributions of intermediate or final combustion products resulting from the hydrocarbon fuels are of great interest. The effect of several diatomic molecular radicals, such as Carbon Dioxide , Carbon Monoxide, Molecular Carbon, Methylene Radical, Cyanide or Cyano Radical, and Nitric Oxide, needs to be identified and the effects of their band systems on the spectral region from 300 nm to 850 nm determined. Hydrocarbon-fueled rocket engines will play a prominent role in future space exploration programs. Although hydrogen fuel provides for higher engine performance, hydrocarbon fuels are denser, safer to handle, and less costly. For hydrocarbon-fueled engines using RP-1 or CH4 , the plume is different from a hydrogen fueled engine due to the presence of several other species, such as CO2, C2, CO, CH, CN, and NO, in the exhaust plume, in addition to the standard H2O and OH. These species occur as intermediate or final combustion products or as a result of mixing of the hot plume with the atmosphere. Exhaust plume emission spectroscopy has emerged as a comprehensive non-intrusive sensing technology which can be applied to a wide variety of engine performance conditions with a high degree of sensitivity and specificity. Stennis Space Center researchers have been in the forefront of advancing experimental techniques and developing theoretical approaches in order to bring this technology to a more

  3. The economic production of alcohol fuels from coal-derived synthesis gas

    SciTech Connect

    Kugler, E.L.; Dadyburjor, D.B.; Yang, R.Y.K.

    1995-12-31

    The objectives of this project are to discover, (1) study and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas. Specifically, alternative methods of preparing catalysts are to be investigated, and novel catalysts, including sulfur-tolerant ones, are to be pursued. (Task 1); (2) explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. (Task 1); (3) simulate by computer the most energy efficient and economically efficient process for converting coal to energy, with primary focus on converting syngas to fuel alcohols. (Task 2); (4) develop on the bench scale the best holistic combination of chemistry, catalyst, reactor and total process configuration integrated with the overall coal conversion process to achieve economic optimization for the conversion of syngas to liquid products within the framework of achieving the maximum cost effective transformation of coal to energy equivalents. (Tasks 1 and 2); and (5) evaluate the combustion, emission and performance characteristics of fuel alcohols and blends of alcohols with petroleum-based fuels. (Task 2)

  4. Artificial photosynthesis for production of hydrogen peroxide and its fuel cells.

    PubMed

    Fukuzumi, Shunichi

    2016-05-01

    The reducing power released from photosystem I (PSI) via ferredoxin enables the reduction of NADP(+) to NADPH, which is essential in the Calvin-Benson cycle to make sugars in photosynthesis. Alternatively, PSI can reduce O2 to produce hydrogen peroxide as a fuel. This article describes the artificial version of the photocatalytic production of hydrogen peroxide from water and O2 using solar energy. Hydrogen peroxide is used as a fuel in hydrogen peroxide fuel cells to make electricity. The combination of the photocatalytic H2O2 production from water and O2 using solar energy with one-compartment H2O2 fuel cells provides on-site production and usage of H2O2 as a more useful and promising solar fuel than hydrogen. This article is part of a Special Issue entitled Biodesign for Bioenergetics--The design and engineering of electronc transfer cofactors, proteins and protein networks, edited by Ronald L. Koder and J.L. Ross Anderson.

  5. Solvent degradation products in nuclear fuel processing solvents

    SciTech Connect

    Shook, H.E. Jr.

    1988-06-01

    The Savannah River Plant uses a modified Purex process to recover enriched uranium and separate fission products. This process uses 7.5% tri-n-butyl phosphate (TBP) dissolved in normal paraffin hydrocarbons for the solvent extraction of a nitric acid solution containing the materials to be separated. Periodic problems in product decontamination result from solvent degradation. A study to improve process efficiency has identified certain solvent degradation products and suggested mitigation measures. Undecanoic acid, lauric acid, and tridecanoic acid were tentatively identified as diluent degradation products in recycle solvent. These long-chain organic acids affect phase separation and lead to low decontamination factors. Solid phase extraction (SPE) was used to concentrate the organic acids in solvent prior to analysis by high performance liquid chromatography (HPLC). SPE and HPLC methods were optimized in this work for analysis of decanoic acid, undecanoic acid, and lauric acid in solvent. Accelerated solvent degradation studies with 7.5% TBP in normal paraffin hydrocarbons showed that long-chain organic acids and long-chain alkyl butyl phosphoric acids are formed by reactions with nitric acid. Degradation of both tributyl phosphate and hydrocarbon can be minimized with purified normal paraffin replacing the standard grade presently used. 12 refs., 1 fig., 3 tabs.

  6. Process for the production of fuel gas from coal

    DOEpatents

    Patel, Jitendra G.; Sandstrom, William A.; Tarman, Paul B.

    1982-01-01

    An improved apparatus and process for the conversion of hydrocarbonaceous materials, such as coal, to more valuable gaseous products in a fluidized bed gasification reaction and efficient withdrawal of agglomerated ash from the fluidized bed is disclosed. The improvements are obtained by introducing an oxygen containing gas into the bottom of the fluidized bed through a separate conduit positioned within the center of a nozzle adapted to agglomerate and withdraw the ash from the bottom of the fluidized bed. The conduit extends above the constricted center portion of the nozzle and preferably terminates within and does not extend from the nozzle. In addition to improving ash agglomeration and withdrawal, the present invention prevents sintering and clinkering of the ash in the fluidized bed and permits the efficient recycle of fine material recovered from the product gases by contacting the fines in the fluidized bed with the oxygen as it emanates from the conduit positioned within the withdrawal nozzle. Finally, the present method of oxygen introduction permits the efficient recycle of a portion of the product gases to the reaction zone to increase the reducing properties of the hot product gas.

  7. The new gold rush: fueling ethanol production while protecting water quality.

    PubMed

    Simpson, Thomas W; Sharpley, Andrew N; Howarth, Robert W; Paerl, Hans W; Mankin, Kyle R

    2008-01-01

    Renewable fuel production, particularly grain-based ethanol, is expanding rapidly in the USA. Although subsidized grain-based ethanol may provide a competitively priced transportation fuel, concerns exist about potential environmental impacts. This contribution focuses on potential water quality implications of expanded grain-based ethanol production and potential impacts of perennial-grass-based cellulosic ethanol. Expanded grain-based ethanol will increase and intensify corn production. Even with recommended fertilizer and land conservation measures, corn acreage can be a major source of N loss to water (20-40 kg ha(-1) yr(-1)). A greater acreage of corn is estimated to increase N and P loss to water by 37% (117 million kg) and 25% (9 million kg), respectively, and measures to encourage adoption of conservation practices are essential to mitigate water quality impairments. Dried distiller's grains remaining after ethanol production from corn grain are used as animal feed and can increase manure P content and may increase N content. Cellulosic fuel-stocks from perennials such as switchgrass and woody materials have the potential to produce ethanol. Although production, storage, and handling of cellulosic materials and conversion technology are limitations, accelerating development of cellulosic ethanol has the potential to reduce dependence on grain fuel-stocks and provide water quality and other environmental benefits. All alternative fuel production technologies could have environmental impacts. There is a need to understand these impacts to help guide policy and help make programmatic and scientific decisions that avoid or mitigate unintended environmental consequences of biofuel production. PMID:18268293

  8. The new gold rush: fueling ethanol production while protecting water quality.

    PubMed

    Simpson, Thomas W; Sharpley, Andrew N; Howarth, Robert W; Paerl, Hans W; Mankin, Kyle R

    2008-01-01

    Renewable fuel production, particularly grain-based ethanol, is expanding rapidly in the USA. Although subsidized grain-based ethanol may provide a competitively priced transportation fuel, concerns exist about potential environmental impacts. This contribution focuses on potential water quality implications of expanded grain-based ethanol production and potential impacts of perennial-grass-based cellulosic ethanol. Expanded grain-based ethanol will increase and intensify corn production. Even with recommended fertilizer and land conservation measures, corn acreage can be a major source of N loss to water (20-40 kg ha(-1) yr(-1)). A greater acreage of corn is estimated to increase N and P loss to water by 37% (117 million kg) and 25% (9 million kg), respectively, and measures to encourage adoption of conservation practices are essential to mitigate water quality impairments. Dried distiller's grains remaining after ethanol production from corn grain are used as animal feed and can increase manure P content and may increase N content. Cellulosic fuel-stocks from perennials such as switchgrass and woody materials have the potential to produce ethanol. Although production, storage, and handling of cellulosic materials and conversion technology are limitations, accelerating development of cellulosic ethanol has the potential to reduce dependence on grain fuel-stocks and provide water quality and other environmental benefits. All alternative fuel production technologies could have environmental impacts. There is a need to understand these impacts to help guide policy and help make programmatic and scientific decisions that avoid or mitigate unintended environmental consequences of biofuel production.

  9. Fission Product Monitoring of TRISO Coated Fuel For The Advanced Gas Reactor -1 Experiment

    SciTech Connect

    Dawn M. Scates; John K. Hartwell; John b. Walter

    2010-10-01

    The US Department of Energy has embarked on a series of tests of TRISO-coated particle reactor fuel intended for use in the Very High Temperature Reactor (VHTR) as part of the Advanced Gas Reactor (AGR) program. The AGR-1 TRISO fuel experiment, currently underway, is the first in a series of eight fuel tests planned for irradiation in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). The AGR-1 experiment reached a peak compact averaged burn up of 9% FIMA with no known TRISO fuel particle failures in March 2008. The burnup goal for the majority of the fuel compacts is to have a compact averaged burnup greater than 18% FIMA and a minimum compact averaged burnup of 14% FIMA. At the INL the TRISO fuel in the AGR-1 experiment is closely monitored while it is being irradiated in the ATR. The effluent monitoring system used for the AGR-1 fuel is the Fission Product Monitoring System (FPMS). The FPMS is a valuable tool that provides near real-time data indicative of the AGR-1 test fuel performance and incorporates both high-purity germanium (HPGe) gamma-ray spectrometers and sodium iodide [NaI(Tl)] scintillation detector-based gross radiation monitors. To quantify the fuel performance, release-to-birth ratios (R/B’s) of radioactive fission gases are computed. The gamma-ray spectra acquired by the AGR-1 FPMS are analyzed and used to determine the released activities of specific fission gases, while a dedicated detector provides near-real time count rate information. Isotopic build up and depletion calculations provide the associated isotopic birth rates. This paper highlights the features of the FPMS, encompassing the equipment, methods and measures that enable the calculation of the release-to-birth ratios. Some preliminary results from the AGR-1 experiment are also presented.

  10. Fission Product Monitoring of TRISO Coated Fuel For The Advanced Gas Reactor -1 Experiment

    SciTech Connect

    Dawn M. Scates; John K Hartwell; John B. Walter

    2008-09-01

    The US Department of Energy has embarked on a series of tests of TRISO-coated particle reactor fuel intended for use in the Very High Temperature Reactor (VHTR) as part of the Advanced Gas Reactor (AGR) program. The AGR-1 TRISO fuel experiment, currently underway, is the first in a series of eight fuel tests planned for irradiation in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). The AGR-1 experiment reached a peak compact averaged burn up of 9% FIMA with no known TRISO fuel particle failures in March 2008. The burnup goal for the majority of the fuel compacts is to have a compact averaged burnup greater than 18% FIMA and a minimum compact averaged burnup of 14% FIMA. At the INL the TRISO fuel in the AGR-1 experiment is closely monitored while it is being irradiated in the ATR. The effluent monitoring system used for the AGR-1 fuel is the Fission Product Monitoring System (FPMS). The FPMS is a valuable tool that provides near real-time data indicative of the AGR-1 test fuel performance and incorporates both high-purity germanium (HPGe) gamma-ray spectrometers and sodium iodide [NaI(Tl)] scintillation detector-based gross radiation monitors. To quantify the fuel performance, release-to-birth ratios (R/B’s) of radioactive fission gases are computed. The gamma-ray spectra acquired by the AGR-1 FPMS are analyzed and used to determine the released activities of specific fission gases, while a dedicated detector provides near-real time count rate information. Isotopic build up and depletion calculations provide the associated isotopic birth rates. This paper highlights the features of the FPMS, encompassing the equipment, methods and measures that enable the calculation of the release-to-birth ratios. Some preliminary results from the AGR-1 experiment are also presented.

  11. Engineering Bacteria for Efficient Fuel Production: Novel Biological Conversion of Hydrogen and Carbon Dioxide Directly into Free Fatty Acids

    SciTech Connect

    2010-07-12

    Electrofuels Project: OPX Biotechnologies is engineering a microorganism currently used in industrial biotechnology to directly produce a liquid fuel from hydrogen and carbon dioxide (CO2). The microorganism has the natural ability to use hydrogen and CO2 for growth. OPX Biotechnologies is modifying the microorganism to divert energy and carbon away from growth and towards the production of liquid fuels in larger, commercially viable quantities. The microbial system will produce a fuel precursor that can be chemically upgraded to various hydrocarbon fuels.

  12. Electricity production from twelve monosaccharides using microbial fuel cells

    NASA Astrophysics Data System (ADS)

    Catal, Tunc; Li, Kaichang; Bermek, Hakan; Liu, Hong

    Direct generation of electricity from monosaccharides of lignocellulosic biomass was examined using air cathode microbial fuel cells (MFCs). Electricity was generated from all carbon sources tested, including six hexoses (D-glucose, D-galactose, D(-)-levulose (fructose), L-fucose, L-rhamnose, and D-mannose), three pentoses (D-xylose, D(-)-arabinose, and D(-)-ribose), two uronic acids (D-galacturonic acid and D-glucuronic acid) and one aldonic acid (D-gluconic acid). The mixed bacterial culture, which was enriched using acetate as a carbon source, adapted well to all carbon sources tested, although the adaptation times varied from 1 to 70 h. The maximum power density obtained from these carbon sources ranged from 1240 ± 10 to 2770 ± 30 mW m -2 at current density range of 0.76-1.18 mA cm -2. D-Mannose resulted in the lowest maximum power density, whereas D-glucuronic acid generated the highest one. Coulombic efficiency ranged from 21 to 37%. For all carbon sources tested, the relationship between the maximum voltage output and the substrate concentration appeared to follow saturation kinetics at 120 Ω external resistance. The estimated maximum voltage output ranged between 0.26 and 0.44 V and half-saturation kinetic constants ranged from 111 to 725 mg L -1. Chemical oxygen demand (COD) removal was over 80% for all carbon sources tested. Results from this study indicated that lignocellulosic biomass-derived monosaccharides might be a suitable resource for electricity generation using MFC technology.

  13. Peak oil demand: the role of fuel efficiency and alternative fuels in a global oil production decline.

    PubMed

    Brandt, Adam R; Millard-Ball, Adam; Ganser, Matthew; Gorelick, Steven M

    2013-07-16

    Some argue that peak conventional oil production is imminent due to physical resource scarcity. We examine the alternative possibility of reduced oil use due to improved efficiency and oil substitution. Our model uses historical relationships to project future demand for (a) transport services, (b) all liquid fuels, and (c) substitution with alternative energy carriers, including electricity. Results show great increases in passenger and freight transport activity, but less reliance on oil. Demand for liquids inputs to refineries declines significantly after 2070. By 2100 transport energy demand rises >1000% in Asia, while flattening in North America (+23%) and Europe (-20%). Conventional oil demand declines after 2035, and cumulative oil production is 1900 Gbbl from 2010 to 2100 (close to the U.S. Geological Survey median estimate of remaining oil, which only includes projected discoveries through 2025). These results suggest that effort is better spent to determine and influence the trajectory of oil substitution and efficiency improvement rather than to focus on oil resource scarcity. The results also imply that policy makers should not rely on liquid fossil fuel scarcity to constrain damage from climate change. However, there is an unpredictable range of emissions impacts depending on which mix of substitutes for conventional oil gains dominance-oil sands, electricity, coal-to-liquids, or others.

  14. From fields to fuels: recent advances in the microbial production of biofuels.

    PubMed

    Kung, Yan; Runguphan, Weerawat; Keasling, Jay D

    2012-11-16

    Amid grave concerns over global climate change and with increasingly strained access to fossil fuels, the synthetic biology community has stepped up to the challenge of developing microbial platforms for the production of advanced biofuels. The adoption of gasoline, diesel, and jet fuel alternatives derived from microbial sources has the potential to significantly limit net greenhouse gas emissions. In this effort, great strides have been made in recent years toward the engineering of microorganisms to produce transportation fuels derived from alcohol, fatty acid, and isoprenoid biosynthesis. We provide an overview of the biosynthetic pathways devised in the strain development of biofuel-producing microorganisms. We also highlight many of the commonly used and newly devised engineering strategies that have been employed to identify and overcome pathway bottlenecks and problems of toxicity to maximize production titers.

  15. INNOVATIVE FRESH WATER PRODUCTION PROCESS FOR FOSSIL FUEL PLANTS

    SciTech Connect

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight

    2004-09-01

    An innovative Diffusion Driven Desalination (DDD) process was recently described where evaporation of mineralized water is driven by diffusion within a packed bed. The energy source to drive the process is derived from low pressure condensing steam within the main condenser of a steam power generating plant. Since waste heat is used to drive the process, the main cost of fresh water production is attributed to the energy cost of pumping air and water through the packed bed. This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. A combined thermodynamic and dynamic analysis demonstrates that the DDD process can yield a fresh water production of 1.03 million gallon/day by utilizing waste heat from a 100 MW steam power plant based on a condensing steam pressure of only 3'' Hg. Throughout the past year, the main focus of the desalination process has been on the diffusion tower and direct contact condenser. Detailed heat and mass transfer analyses required to size and analyze these heat and mass transfer devices are described. An experimental DDD facility has been fabricated, and temperature and humidity data have been collected over a range of flow and thermal conditions. The analyses agree quite well with the current data and the information available in the literature. Direct contact condensers with and without packing have been investigated. It has been experimentally observed that the fresh water production rate is significantly enhanced when packing is added to the direct contact condensers.

  16. Photosynthetic terpene hydrocarbon production for fuels and chemicals.

    PubMed

    Wang, Xin; Ort, Donald R; Yuan, Joshua S

    2015-02-01

    Photosynthetic hydrocarbon production bypasses the traditional biomass hydrolysis process and represents the most direct conversion of sunlight energy into the next-generation biofuels. As a major class of biologically derived hydrocarbons with diverse structures, terpenes are also valuable in producing a variety of fungible bioproducts in addition to the advanced 'drop-in' biofuels. However, it is highly challenging to achieve the efficient redirection of photosynthetic carbon and reductant into terpene biosynthesis. In this review, we discuss four major scientific and technical barriers for photosynthetic terpene production and recent advances to address these constraints. Collectively, photosynthetic terpene production needs to be optimized in a systematic fashion, in which the photosynthesis improvement, the optimization of terpene biosynthesis pathway, the improvement of key enzymes and the enhancement of sink effect through terpene storage or secretion are all important. New advances in synthetic biology also offer a suite of potential tools to design and engineer photosynthetic terpene platforms. The systemic integration of these solutions may lead to 'disruptive' technologies to enable biofuels and bioproducts with high efficiency, yield and infrastructure compatibility.

  17. Photosynthetic terpene hydrocarbon production for fuels and chemicals

    SciTech Connect

    Wang, X; Ort, DR; Yuan, JS

    2015-01-28

    Photosynthetic hydrocarbon production bypasses the traditional biomass hydrolysis process and represents the most direct conversion of sunlight energy into the next-generation biofuels. As a major class of biologically derived hydrocarbons with diverse structures, terpenes are also valuable in producing a variety of fungible bioproducts in addition to the advanced drop-in' biofuels. However, it is highly challenging to achieve the efficient redirection of photosynthetic carbon and reductant into terpene biosynthesis. In this review, we discuss four major scientific and technical barriers for photosynthetic terpene production and recent advances to address these constraints. Collectively, photosynthetic terpene production needs to be optimized in a systematic fashion, in which the photosynthesis improvement, the optimization of terpene biosynthesis pathway, the improvement of key enzymes and the enhancement of sink effect through terpene storage or secretion are all important. New advances in synthetic biology also offer a suite of potential tools to design and engineer photosynthetic terpene platforms. The systemic integration of these solutions may lead to disruptive' technologies to enable biofuels and bioproducts with high efficiency, yield and infrastructure compatibility.

  18. Novel Catalysts and Processing Technologies for Production of Aerospace Fuels from Non-Petroleum Raw Materials

    NASA Technical Reports Server (NTRS)

    Hepp, A. F.; Kulis, M. J.; Psarras, P. C.; Ball, D. W.; Timko, M. T.; Wong, H.-W.; Peck, J.; Chianelli, R. R.

    2014-01-01

    Transportation fuels production (including aerospace propellants) from non-traditional sources (gases, waste materials, and biomass) has been an active area of research and development for decades. Reducing terrestrial waste streams simultaneous with energy conversion, plentiful biomass, new low-cost methane sources, and/or extra-terrestrial resource harvesting and utilization present significant technological and business opportunities being realized by a new generation of visionary entrepreneurs. We examine several new approaches to catalyst fabrication and new processing technologies to enable utilization of these non-traditional raw materials. Two basic processing architectures are considered: a single-stage pyrolysis approach that seeks to basically re-cycle hydrocarbons with minimal net chemistry or a two-step paradigm that involves production of supply or synthesis gas (mainly carbon oxides and hydrogen) followed by production of fuel(s) via Sabatier or methanation reactions and/or Fischer-Tropsch synthesis. Optimizing the fraction of product stream relevant to targeted aerospace (and other transportation) fuels via modeling, catalyst fabrication and novel reactor design are described. Energy utilization is a concern for production of fuels for either terrestrial or space operations; renewable sources based on solar energy and/or energy efficient processes may be mission enabling. Another important issue is minimizing impurities in the product stream(s), especially those potentially posing risks to personnel or operations through (catalyst) poisoning or (equipment) damage. Technologies being developed to remove (and/or recycle) heteroatom impurities are briefly discussed as well as the development of chemically robust catalysts whose activity are not diminished during operation. The potential impacts on future missions by such new approaches as well as balance of system issues are addressed.

  19. Novel Catalysts and Processing Technologies for Production of Aerospace Fuels from Non-Petroleum Raw Materials

    NASA Technical Reports Server (NTRS)

    Hepp, Aloysius F.; Kulis, Michael J.; Psarras, Peter C.; Ball, David W.; Timko, Michael T.; Wong, Hsi-Wu; Peck, Jay; Chianelli, Russell R.

    2014-01-01

    Transportation fuels production (including aerospace propellants) from non-traditional sources (gases, waste materials, and biomass) has been an active area of research and development for decades. Reducing terrestrial waste streams simultaneous with energy conversion, plentiful biomass, new low-cost methane sources, and/or extra-terrestrial resource harvesting and utilization present significant technological and business opportunities being realized by a new generation of visionary entrepreneurs. We examine several new approaches to catalyst fabrication and new processing technologies to enable utilization of these nontraditional raw materials. Two basic processing architectures are considered: a single-stage pyrolysis approach that seeks to basically re-cycle hydrocarbons with minimal net chemistry or a two-step paradigm that involves production of supply or synthesis gas (mainly carbon oxides and H2) followed by production of fuel(s) via Sabatier or methanation reactions and/or Fischer-Tröpsch synthesis. Optimizing the fraction of product stream relevant to targeted aerospace (and other transportation) fuels via modeling, catalyst fabrication and novel reactor design are described. Energy utilization is a concern for production of fuels for either terrestrial or space operations; renewable sources based on solar energy and/or energy efficient processes may be mission enabling. Another important issue is minimizing impurities in the product stream(s), especially those potentially posing risks to personnel or operations through (catalyst) poisoning or (equipment) damage. Technologies being developed to remove (and/or recycle) heteroatom impurities are briefly discussed as well as the development of chemically robust catalysts whose activities are not diminished during operation. The potential impacts on future missions by such new approaches as well as balance of system issues are addressed.

  20. Integrated production of fuel gas and oxygenated organic compounds from synthesis gas

    DOEpatents

    Moore, Robert B.; Hegarty, William P.; Studer, David W.; Tirados, Edward J.

    1995-01-01

    An oxygenated organic liquid product and a fuel gas are produced from a portion of synthesis gas comprising hydrogen, carbon monoxide, carbon dioxide, and sulfur-containing compounds in a integrated feed treatment and catalytic reaction system. To prevent catalyst poisoning, the sulfur-containing compounds in the reactor feed are absorbed in a liquid comprising the reactor product, and the resulting sulfur-containing liquid is regenerated by stripping with untreated synthesis gas from the reactor. Stripping offgas is combined with the remaining synthesis gas to provide a fuel gas product. A portion of the regenerated liquid is used as makeup to the absorber and the remainder is withdrawn as a liquid product. The method is particularly useful for integration with a combined cycle coal gasification system utilizing a gas turbine for electric power generation.

  1. Efficiency maximization in solar-thermochemical fuel production: challenging the concept of isothermal water splitting.

    PubMed

    Ermanoski, I; Miller, J E; Allendorf, M D

    2014-05-14

    Widespread adoption of solar-thermochemical fuel production depends on its economic viability, largely driven by the efficiency of use of the available solar resource. Herein, we analyze the efficiency of two-step cycles for thermochemical hydrogen production, with emphasis on efficiency. Owing to water thermodynamics, isothermal H2 production is shown to be impractical and inefficient, irrespective of reactor design or reactive oxide properties, but an optimal temperature difference between cycle steps, for which efficiency is the highest, can be determined for a wide range of other operating parameters. A combination of well-targeted pressure and temperature swing, rather than either individually, emerges as the most efficient mode of operation of a two-step thermochemical cycle for solar fuel production.

  2. Effects of inoculum size on solid-phase fermentation of fodder beets for fuel ethanol production

    SciTech Connect

    Gibbons, W.R.; Westby, C.A.

    1986-10-01

    This fuel ethanol study examined the effects of Saccharomyces cerevisiae inoculum size on solid-phase fermentation of fodder beet pulp. A 5% inoculum (wt/wt) resulted in rapid yeast and ethanol (9.1% (vol/vol)) production. Higher inocula showed no advantages. Lower inocula resulted in lowered final yeast populations and increased fermentation times.

  3. Pathways to Commercial Success. Technologies and Products Supported by the Fuel Cell Technologies Program - 2012

    SciTech Connect

    none,

    2012-09-01

    This FY 2012 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell Technologies Program and its predecessor programs within DOE's Office of Energy Efficiency and Renewable Energy.

  4. Pathways to Commercial Success. Technologies and Products Supported by the Fuel Cell Technologies Program

    SciTech Connect

    none,

    2011-09-01

    This FY 2011 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell Technologies Program and its predecessor programs within DOE's Office of Energy Efficiency and Renewable Energy.

  5. Target Cultivation and Financing Parameters for Sustainable Production of Fuel and Feed from Microalgae.

    PubMed

    Gerber, Léda N; Tester, Jefferson W; Beal, Colin M; Huntley, Mark E; Sills, Deborah L

    2016-04-01

    Production of economically competitive and environmentally sustainable algal biofuel faces technical challenges that are subject to high uncertainties. Here we identify target values for algal productivity and financing conditions required to achieve a biocrude selling price of $5 per gallon and beneficial environmental impacts. A modeling framework--combining process design, techno-economic analysis, life cycle assessment, and uncertainty analysis--was applied to two conversion pathways: (1) "fuel only (HTL)", using hydrothermal liquefaction to produce biocrude, heat and power, and (2) "fuel and feed", using wet extraction to produce biocrude and lipid-extracted algae, which can substitute components of animal and aqua feeds. Our results suggest that with supporting policy incentives, the "fuel and feed" scenario will likely achieve a biocrude selling price of less than $5 per gallon at a productivity of 39 g/m(2)/day, versus 47 g/m(2)/day for the "fuel only (HTL)" scenario. Furthermore, if lipid-extracted algae are used to substitute fishmeal, the process has a 50% probability of reaching $5 per gallon with a base case productivity of 23 g/m(2)/day. Scenarios with improved economics were associated with beneficial environmental impacts for climate change, ecosystem quality, and resource depletion, but not for human health. PMID:26942694

  6. Target Cultivation and Financing Parameters for Sustainable Production of Fuel and Feed from Microalgae.

    PubMed

    Gerber, Léda N; Tester, Jefferson W; Beal, Colin M; Huntley, Mark E; Sills, Deborah L

    2016-04-01

    Production of economically competitive and environmentally sustainable algal biofuel faces technical challenges that are subject to high uncertainties. Here we identify target values for algal productivity and financing conditions required to achieve a biocrude selling price of $5 per gallon and beneficial environmental impacts. A modeling framework--combining process design, techno-economic analysis, life cycle assessment, and uncertainty analysis--was applied to two conversion pathways: (1) "fuel only (HTL)", using hydrothermal liquefaction to produce biocrude, heat and power, and (2) "fuel and feed", using wet extraction to produce biocrude and lipid-extracted algae, which can substitute components of animal and aqua feeds. Our results suggest that with supporting policy incentives, the "fuel and feed" scenario will likely achieve a biocrude selling price of less than $5 per gallon at a productivity of 39 g/m(2)/day, versus 47 g/m(2)/day for the "fuel only (HTL)" scenario. Furthermore, if lipid-extracted algae are used to substitute fishmeal, the process has a 50% probability of reaching $5 per gallon with a base case productivity of 23 g/m(2)/day. Scenarios with improved economics were associated with beneficial environmental impacts for climate change, ecosystem quality, and resource depletion, but not for human health.

  7. Fuel ethanol production from lignocellulose: a challenge for metabolic engineering and process integration.

    PubMed

    Zaldivar, J; Nielsen, J; Olsson, L

    2001-07-01

    With industrial development growing rapidly, there is a need for environmentally sustainable energy sources. Bioethanol (ethanol from biomass) is an attractive, sustainable energy source to fuel transportation. Based on the premise that fuel bioethanol can contribute to a cleaner environment and with the implementation of environmental protection laws in many countries, demand for this fuel is increasing. Efficient ethanol production processes and cheap substrates are needed. Current ethanol production processes using crops such as sugar cane and corn are well-established; however, utilization of a cheaper substrate such as lignocellulose could make bioethanol more competitive with fossil fuel. The processing and utilization of this substrate is complex, differing in many aspects from crop-based ethanol production. One important requirement is an efficient microorganism able to ferment a variety of sugars (pentoses, and hexoses) as well as to tolerate stress conditions. Through metabolic engineering, bacterial and yeast strains have been constructed which feature traits that are advantageous for ethanol production using lignocellulose sugars. After several rounds of modification/evaluation/modification, three main microbial platforms, Saccharomyces cerevisiae, Zymomonas mobilis, and Escherichia coli, have emerged and they have performed well in pilot studies. While there are ongoing efforts to further enhance their properties, improvement of the fermentation process is just one of several factors-that needs to be fully optimized and integrated to generate a competitive lignocellulose ethanol plant.

  8. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office - 2014

    SciTech Connect

    None, None

    2015-02-01

    This FY 2014 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell Technologies Office and its predecessor programs within DOE's Office of Energy Efficiency and Renewable Energy.

  9. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Office - 2013

    SciTech Connect

    none,

    2014-04-30

    This FY 2013 report updates the results of an effort to identify and characterize commercial and near-commercial (emerging) technologies and products that benefited from the support of the Fuel Cell Technologies Office and its predecessor programs within DOE's Office of Energy Efficiency and Renewable Energy.

  10. Determining the fate of virginiamycin in the fuel ethanol production process

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Antibiotics are frequently used to prevent and treat bacterial contamination at commercial fuel ethanol facilities. A study to evaluate the fate of the antibiotic virginiamycin during the ethanol production process was conducted in the pilot plant facilities at the National Corn to Ethanol Research...

  11. ENERGY PRODUCTION AND POLLUTION PREVENTION AT SEWAGE TREATMENT PLANTS USING FUEL CELL POWER PLANTS

    EPA Science Inventory

    The paper discusses energy production and pollution prevention at sewage treatment plants using fuel cell power plants. Anaerobic digester gas (ADG) is produced at waste water treatment plants during the anaerobic treatment of sewage to reduce solids. The major constituents are...

  12. Fuel ethanol production from lignocellulose: a challenge for metabolic engineering and process integration.

    PubMed

    Zaldivar, J; Nielsen, J; Olsson, L

    2001-07-01

    With industrial development growing rapidly, there is a need for environmentally sustainable energy sources. Bioethanol (ethanol from biomass) is an attractive, sustainable energy source to fuel transportation. Based on the premise that fuel bioethanol can contribute to a cleaner environment and with the implementation of environmental protection laws in many countries, demand for this fuel is increasing. Efficient ethanol production processes and cheap substrates are needed. Current ethanol production processes using crops such as sugar cane and corn are well-established; however, utilization of a cheaper substrate such as lignocellulose could make bioethanol more competitive with fossil fuel. The processing and utilization of this substrate is complex, differing in many aspects from crop-based ethanol production. One important requirement is an efficient microorganism able to ferment a variety of sugars (pentoses, and hexoses) as well as to tolerate stress conditions. Through metabolic engineering, bacterial and yeast strains have been constructed which feature traits that are advantageous for ethanol production using lignocellulose sugars. After several rounds of modification/evaluation/modification, three main microbial platforms, Saccharomyces cerevisiae, Zymomonas mobilis, and Escherichia coli, have emerged and they have performed well in pilot studies. While there are ongoing efforts to further enhance their properties, improvement of the fermentation process is just one of several factors-that needs to be fully optimized and integrated to generate a competitive lignocellulose ethanol plant. PMID:11499926

  13. Health effects of fossil fuel combustion products: report of a workshop.

    PubMed Central

    Comar, C L; Nelson, N

    1975-01-01

    Judgemental positions are presented on research priorities in regard to the health effects from stationary sources of fossil fuel combustion products. Hopefully, they can provide guidance for efforts to ensure that national energy needs are met with minimum environmental and economic burdens on the public. The major areas include epidemiological studies, controlled biological studies, mutagenesis and carcinogenesis, trace elements, monitoring and analysis. PMID:1227856

  14. Innovative Fresh Water Production Process for Fossil Fuel Plants

    SciTech Connect

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight; Venugopal Jogi

    2005-09-01

    This project concerns a diffusion driven desalination (DDD) process where warm water is evaporated into a low humidity air stream, and the vapor is condensed out to produce distilled water. Although the process has a low fresh water to feed water conversion efficiency, it has been demonstrated that this process can potentially produce low cost distilled water when driven by low grade waste heat. This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. A dynamic analysis of heat and mass transfer demonstrates that the DDD process can yield a fresh water production of 1.03 million gallon/day by utilizing waste heat from a 100 MW steam power plant based on a condensing steam pressure of only 3 Hg. The optimum operating condition for the DDD process with a high temperature of 50 C and sink temperature of 25 C has an air mass flux of 1.5 kg/m{sup 2}-s, air to feed water mass flow ratio of 1 in the diffusion tower, and a fresh water to air mass flow ratio of 2 in the condenser. Operating at these conditions yields a fresh water production efficiency (m{sub fW}/m{sub L}) of 0.031 and electric energy consumption rate of 0.0023 kW-hr/kg{sub fW}. Throughout the past year, the main focus of the desalination process has been on the direct contact condenser. Detailed heat and mass transfer analyses required to size and analyze these heat and mass transfer devices are described. The analyses agree quite well with the current data. Recently, it has been recognized that the fresh water production efficiency can be significantly enhanced with air heating. This type of configuration is well suited for power plants utilizing air-cooled condensers. The experimental DDD facility has been modified with an air heating section, and temperature and humidity data have been collected over a range of flow and thermal conditions. It has been experimentally observed that the fresh water production rate is enhanced when air

  15. Reduction of CO2 to C1 products and fuel

    USGS Publications Warehouse

    Mill, T.; Ross, D.

    2002-01-01

    Photochemical semiconductor processes readily reduced CO2 to a broad range of C1 products. However the intrinsic and solar efficiencies for the processes were low. Improved quantum efficiencies could be realized utilizing quantum-sized particles, but at the expense of using less of the visible solar spectrum. Conversely, semiconductors with small bandgaps used more of the visible solar spectrum at the expense of quantum efficiency. Thermal reduction of CO2 with Fe(II) was thermodynamically favored for forming many kinds of organic compounds and occurred readily with olivine and other Fe(II) minerals above 200??C to form higher alkanes and alkenes. No added hydrogen was required.

  16. Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates.

    PubMed

    Román-Leshkov, Yuriy; Barrett, Christopher J; Liu, Zhen Y; Dumesic, James A

    2007-06-21

    Diminishing fossil fuel reserves and growing concerns about global warming indicate that sustainable sources of energy are needed in the near future. For fuels to be useful in the transportation sector, they must have specific physical properties that allow for efficient distribution, storage and combustion; these properties are currently fulfilled by non-renewable petroleum-derived liquid fuels. Ethanol, the only renewable liquid fuel currently produced in large quantities, suffers from several limitations, including low energy density, high volatility, and contamination by the absorption of water from the atmosphere. Here we present a catalytic strategy for the production of 2,5-dimethylfuran from fructose (a carbohydrate obtained directly from biomass or by the isomerization of glucose) for use as a liquid transportation fuel. Compared to ethanol, 2,5-dimethylfuran has a higher energy density (by 40 per cent), a higher boiling point (by 20 K), and is not soluble in water. This catalytic strategy creates a route for transforming abundant renewable biomass resources into a liquid fuel suitable for the transportation sector, and may diminish our reliance on petroleum. PMID:17581580

  17. Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates.

    PubMed

    Román-Leshkov, Yuriy; Barrett, Christopher J; Liu, Zhen Y; Dumesic, James A

    2007-06-21

    Diminishing fossil fuel reserves and growing concerns about global warming indicate that sustainable sources of energy are needed in the near future. For fuels to be useful in the transportation sector, they must have specific physical properties that allow for efficient distribution, storage and combustion; these properties are currently fulfilled by non-renewable petroleum-derived liquid fuels. Ethanol, the only renewable liquid fuel currently produced in large quantities, suffers from several limitations, including low energy density, high volatility, and contamination by the absorption of water from the atmosphere. Here we present a catalytic strategy for the production of 2,5-dimethylfuran from fructose (a carbohydrate obtained directly from biomass or by the isomerization of glucose) for use as a liquid transportation fuel. Compared to ethanol, 2,5-dimethylfuran has a higher energy density (by 40 per cent), a higher boiling point (by 20 K), and is not soluble in water. This catalytic strategy creates a route for transforming abundant renewable biomass resources into a liquid fuel suitable for the transportation sector, and may diminish our reliance on petroleum.

  18. Feasibility study for a DOE research and production fuel multipurpose canister

    SciTech Connect

    Lopez, D.A.; Abbott, D.G.

    1994-02-01

    This is a report of the feasibility of multipurpose canisters for transporting, storing, and sing of Department of Energy research and production spent nuclear fuel. Six representative Department of Energy fuel assemblies were selected, and preconceptual canister designs were developed to accommodate these assemblies. The study considered physical interface, structural adequacy, criticality safety, shielding capability, thermal performance of the canisters, and fuel storage site infrastructure. The external envelope of the canisters was designed to fit within the overpack casks for commercial canisters being developed for the Department of Energy Office of Civilian Radioactive Waste Management. The budgetary cost of canisters to handle all fuel considered is estimated at $170.8M. One large conceptual boiling water reactor canister design, developed for the Office of Civilian Radioactive Waste Management, and two new canister designs can accommodate at least 85% of the volume of the Department of Energy fuel considered. Canister use minimizes public radiation exposure and is cost effective compared with bare fuel handling. Results suggest the need for additional study of issues affecting canister use and for conceptual design development of the three canisters.

  19. Nondestructive assay of fission products in spent-fuel assemblies using gamma and photoneutron activation

    NASA Astrophysics Data System (ADS)

    Lakosi, L.; Veres, Á.

    1990-12-01

    Hard γ-radiation (above 1.078 MeV) from spent reactor fuel was detected by means of excitation of 115In to its 4.5 h half-life metastable state induced by the (γ, γ') reaction and subsequent counting of the 336 keV isomeric transition. Resonance-energy quanta were produced by Compton scattering in the source, i.e. the spent fuel itself. The sensitivity of the activation method above 1.67 MeV γ-energy was enhanced by introducing a Be photoneutron converter in order to produce neutrons for exploiting their much larger activation cross sections. For short cooling times (10-40 d) the hard-γ signature of the fuel was due to the fission product 140Ba 140La, detection of which facilitated monitoring of the reactor power which existed in the core just before reactor shutdown. A linear relationship was found between the γ-signal and the fissile content in the fuel. For 100-1000 d cooled fuel the 144Ce 144Pr content could be detected, which was only sensitive to the cooling time. Spent-fuel assemblies of both a research and a power reactor were assayed by these novel methods for reactor operational and nuclear-material safeguard purposes.

  20. Porcelain enameling furnaces retrofitted with ceramic fiber to increase fuel savings and production

    SciTech Connect

    Not Available

    1984-07-01

    Appliance manufacturers and companies supplying porcelainized parts have done considerable revamping and modernizing of their furnaces. As a result, economy of production has been improved through either substantial fuel savings or increased productivity or both. Coinciding with this industry furnace upgrading, a refractory engineering and contracting firm, Ronalco Inc., Louisville, KY has emerged, within a few years, as experts in porcelain enameling furnace renovations devising their own innovative methodology for lining and heating these units.

  1. INNOVATIVE FRESH WATER PRODUCTION PROCESS FOR FOSSIL FUEL PLANTS

    SciTech Connect

    James F. Klausner; Renwei Mei; Yi Li; Mohamed Darwish; Diego Acevedo; Jessica Knight

    2003-09-01

    This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system, which is powered by the waste heat from low pressure condensing steam in power plants. The desalination is driven by water vapor saturating dry air flowing through a diffusion tower. Liquid water is condensed out of the air/vapor mixture in a direct contact condenser. A thermodynamic analysis demonstrates that the DDD process can yield a fresh water production efficiency of 4.5% based on a feed water inlet temperature of only 50 C. An example is discussed in which the DDD process utilizes waste heat from a 100 MW steam power plant to produce 1.51 million gallons of fresh water per day. The main focus of the initial development of the desalination process has been on the diffusion tower. A detailed mathematical model for the diffusion tower has been described, and its numerical implementation has been used to characterize its performance and provide guidance for design. The analysis has been used to design a laboratory scale diffusion tower, which has been thoroughly instrumented to allow detailed measurements of heat and mass transfer coefficient, as well as fresh water production efficiency. The experimental facility has been described in detail.

  2. ENHANCED HYDROGEN ECONOMICS VIA COPRODUCTION OF FUELS AND CARBON PRODUCTS

    SciTech Connect

    Kennel, Elliot B; Bhagavatula, Abhijit; Dadyburjor, Dady; Dixit, Santhoshi; Garlapalli, Ravinder; Magean, Liviu; Mukkha, Mayuri; Olajide, Olufemi A; Stiller, Alfred H; Yurchick, Christopher L

    2011-03-31

    This Department of Energy National Energy Technology Laboratory sponsored research effort to develop environmentally cleaner projects as a spin-off of the FutureGen project, which seeks to reduce or eliminate emissions from plants that utilize coal for power or hydrogen production. New clean coal conversion processes were designed and tested for coproducing clean pitches and cokes used in the metals industry as well as a heavy crude oil. These new processes were based on direct liquefaction and pyrolysis techniques that liberate volatile liquids from coal without the need for high pressure or on-site gaseous hydrogen. As a result of the research, a commercial scale plant for the production of synthetic foundry coke has broken ground near Wise, Virginia under the auspices of Carbonite Inc. This plant will produce foundry coke by pyrolyzing a blend of steam coal feedstocks. A second plant is planned by Quantex Energy Inc (in Texas) which will use solvent extraction to coproduce a coke residue as well as crude oil. A third plant is being actively considered for Kingsport, Tennessee, pending a favorable resolution of regulatory issues.

  3. Yeast selection for fuel ethanol production in Brazil.

    PubMed

    Basso, Luiz C; de Amorim, Henrique V; de Oliveira, Antonio J; Lopes, Mario L

    2008-11-01

    Brazil is one of the largest ethanol biofuel producers and exporters in the world and its production has increased steadily during the last three decades. The increasing efficiency of Brazilian ethanol plants has been evident due to the many technological contributions. As far as yeast is concerned, few publications are available regarding the industrial fermentation processes in Brazil. The present paper reports on a yeast selection program performed during the last 12 years aimed at selecting Saccharomyces cerevisiae strains suitable for fermentation of sugar cane substrates (cane juice and molasses) with cell recycle, as it is conducted in Brazilian bioethanol plants. As a result, some evidence is presented showing the positive impact of selected yeast strains in increasing ethanol yield and reducing production costs, due to their higher fermentation performance (high ethanol yield, reduced glycerol and foam formation, maintenance of high viability during recycling and very high implantation capability into industrial fermenters). Results also suggest that the great yeast biodiversity found in distillery environments could be an important source of strains. This is because during yeast cell recycling, selective pressure (an adaptive evolution) is imposed on cells, leading to strains with higher tolerance to the stressful conditions of the industrial fermentation. PMID:18752628

  4. Accelerator breeder: a viable option for the production of nuclear fuels

    SciTech Connect

    Grand, P.

    1983-01-01

    Despite the growing pains of the US nuclear power industry, our dependence on nuclear energy for the production of electricity and possibly process heat is likely to increase dramatically over the next few deacades. This statement dismisses fusion as being entirely too speculative to be practical within that time frame. Sometime, between the years 2000 and 2050, fissile material will be in short supply whether it is to fuel existing LWR's or to provide initial fuel inventory for FBR's. The accelerator breeder could produce the fuel shortfall predicted to occur during the first half of the 21st century. The accelerator breeder offers the only practical means today of producing, or breeding, large quantities of fissile fuel from fertile materials, albeit at high cost. Studies performed over the last few years at Chalk River Laboratory and at Brookhaven National Laboratory have demonstrated that the accelerator breeder is practical, technically feasible with state-of-the-art technology, and is economically competitive with any other proposed synthetic means of fissile fuel production. This paper gives the parameters of a nearly optimized accelerator-breeder system, then discusses the development needs, and the economics and institutional problems that this breeding concept faces.

  5. Recent developments in the production of liquid fuels via catalytic conversion of microalgae: experiments and simulations

    SciTech Connect

    Shi,Fan; Wang, Pin; Duan, Yuhua; Link, Dirk; Morreale, Bryan

    2012-01-01

    Due to continuing high demand, depletion of non-renewable resources and increasing concerns about climate change, the use of fossil fuel-derived transportation fuels faces relentless challenges both from a world markets and an environmental perspective. The production of renewable transportation fuel from microalgae continues to attract much attention because of its potential for fast growth rates, high oil content, ability to grow in unconventional scenarios, and inherent carbon neutrality. Moreover, the use of microalgae would minimize ‘‘food versus fuel’’ concerns associated with several biomass strategies, as microalgae do not compete with food crops in the food chain. This paper reviews the progress of recent research on the production of transportation fuels via homogeneous and heterogeneous catalytic conversions of microalgae. This review also describes the development of tools that may allow for a more fundamental understanding of catalyst selection and conversion processes using computational modelling. The catalytic conversion reaction pathways that have been investigated are fully discussed based on both experimental and theoretical approaches. Finally, this work makes several projections for the potential of various thermocatalytic pathways to produce alternative transportation fuels from algae, and identifies key areas where the authors feel that computational modelling should be directed to elucidate key information to optimize the process.

  6. Recent Developments on the Production of Transportation Fuels via Catalytic Conversion of Microalgae: Experiments and Simulations

    SciTech Connect

    Shi, Fan; Wang, Ping; Duan, Yuhua; Link, Dirk; Morreale, Bryan

    2012-08-02

    Due to continuing high demand, depletion of non-renewable resources and increasing concerns about climate change, the use of fossil fuel-derived transportation fuels faces relentless challenges both from a world markets and an environmental perspective. The production of renewable transportation fuel from microalgae continues to attract much attention because of its potential for fast growth rates, high oil content, ability to grow in unconventional scenarios, and inherent carbon neutrality. Moreover, the use of microalgae would minimize “food versus fuel” concerns associated with several biomass strategies, as microalgae do not compete with food crops in the food chain. This paper reviews the progress of recent research on the production of transportation fuels via homogeneous and heterogeneous catalytic conversions of microalgae. This review also describes the development of tools that may allow for a more fundamental understanding of catalyst selection and conversion processes using computational modelling. The catalytic conversion reaction pathways that have been investigated are fully discussed based on both experimental and theoretical approaches. Finally, this work makes several projections for the potential of various thermocatalytic pathways to produce alternative transportation fuels from algae, and identifies key areas where the authors feel that computational modelling should be directed to elucidate key information to optimize the process.

  7. Development of a Life Cycle Inventory of Water Consumption Associated with the Production of Transportation Fuels

    SciTech Connect

    Lampert, David J.; Cai, Hao; Wang, Zhichao; Keisman, Jennifer; Wu, May; Han, Jeongwoo; Dunn, Jennifer; Sullivan, John L.; Elgowainy, Amgad; Wang, Michael; Keisman, Jennifer

    2015-10-01

    The production of all forms of energy consumes water. To meet increased energy demands, it is essential to quantify the amount of water consumed in the production of different forms of energy. By analyzing the water consumed in different technologies, it is possible to identify areas for improvement in water conservation and reduce water stress in energy-producing regions. The transportation sector is a major consumer of energy in the United States. Because of the relationships between water and energy, the sustainability of transportation is tied to management of water resources. Assessment of water consumption throughout the life cycle of a fuel is necessary to understand its water resource implications. To perform a comparative life cycle assessment of transportation fuels, it is necessary first to develop an inventory of the water consumed in each process in each production supply chain. The Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model is an analytical tool that can used to estimate the full life-cycle environmental impacts of various transportation fuel pathways from wells to wheels. GREET is currently being expanded to include water consumption as a sustainability metric. The purpose of this report was to document data sources and methodologies to estimate water consumption factors (WCF) for the various transportation fuel pathways in GREET. WCFs reflect the quantity of freshwater directly consumed per unit production for various production processes in GREET. These factors do not include consumption of precipitation or low-quality water (e.g., seawater) and reflect only water that is consumed (i.e., not returned to the source from which it was withdrawn). The data in the report can be combined with GREET to compare the life cycle water consumption for different transportation fuels.

  8. Energy consumption evaluation of fuel bioethanol production from sweet potato.

    PubMed

    Ferrari, Mario Daniel; Guigou, Mairan; Lareo, Claudia

    2013-05-01

    The energy consumption for different operative conditions and configurations of the bioethanol production industrial process from an experimental variety of sweet potato (Ipomea batatas) K 9807.1 was evaluated. A process simulation model was developed using SuperPro Designer® software. The model was based on experimental data gathered from our laboratory experiments and technology and equipment suppliers. The effects of the dry matter ratio of sweet potato to water, the fermentation efficiency, and sweet potato sugar content, on the energy consumption (steam and electricity) were respectively evaluated. All factors were significant. The best ratio of dry matter to total water to work with fresh sweet potato was 0.2 kg dry sweet potato/kg water, as for greater ratios was not found a significant reduction in energy consumption. Also, the drying of the sweet potato previous its processing was studied. It presented an energy consumption greater than the energetic content of the bioethanol produced.

  9. Energy consumption evaluation of fuel bioethanol production from sweet potato.

    PubMed

    Ferrari, Mario Daniel; Guigou, Mairan; Lareo, Claudia

    2013-05-01

    The energy consumption for different operative conditions and configurations of the bioethanol production industrial process from an experimental variety of sweet potato (Ipomea batatas) K 9807.1 was evaluated. A process simulation model was developed using SuperPro Designer® software. The model was based on experimental data gathered from our laboratory experiments and technology and equipment suppliers. The effects of the dry matter ratio of sweet potato to water, the fermentation efficiency, and sweet potato sugar content, on the energy consumption (steam and electricity) were respectively evaluated. All factors were significant. The best ratio of dry matter to total water to work with fresh sweet potato was 0.2 kg dry sweet potato/kg water, as for greater ratios was not found a significant reduction in energy consumption. Also, the drying of the sweet potato previous its processing was studied. It presented an energy consumption greater than the energetic content of the bioethanol produced. PMID:23567705

  10. Energy recovery by production of fuel from citrus wastes

    SciTech Connect

    Wesley Clark, C.

    1982-05-01

    A study to determine how much energy can be recovered from a Florida citrus processing plant was conducted. The production of ethyl alcohol in particular was examined as it is thought to represent the greatest potential for immediate energy recovery. Three-fourths of the energy expended to produce, harvest, process and market a box of fruit was recoverable using existing technology, i.e. 78,500 Btu/ box of fruit recoverable from a total energy expenditure of 107,800 Btu/ box of fruit. Aside from the actual cost benefits of recovering energy in the form of ethanol, the food processor is also helping to reduce the foreign-oil imports by the blending of ethyl alcohol with unleaded gasoline to form gasohol.

  11. 41 CFR 101-26.602 - Fuels and packaged petroleum products obtained from or through the Defense Logistics Agency.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... petroleum products obtained from or through the Defense Logistics Agency. 101-26.602 Section 101-26.602... Other Than GSA § 101-26.602 Fuels and packaged petroleum products obtained from or through the Defense... requirements for coal, natural gas from sources other than a public utility, petroleum fuels, and...

  12. 41 CFR 101-26.602 - Fuels and packaged petroleum products obtained from or through the Defense Logistics Agency.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... petroleum products obtained from or through the Defense Logistics Agency. 101-26.602 Section 101-26.602... Other Than GSA § 101-26.602 Fuels and packaged petroleum products obtained from or through the Defense... requirements for coal, natural gas from sources other than a public utility, petroleum fuels, and...

  13. 41 CFR 101-26.602 - Fuels and packaged petroleum products obtained from or through the Defense Logistics Agency.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... petroleum products obtained from or through the Defense Logistics Agency. 101-26.602 Section 101-26.602... Other Than GSA § 101-26.602 Fuels and packaged petroleum products obtained from or through the Defense... requirements for coal, natural gas from sources other than a public utility, petroleum fuels, and...

  14. 41 CFR 101-26.602 - Fuels and packaged petroleum products obtained from or through the Defense Logistics Agency.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... petroleum products obtained from or through the Defense Logistics Agency. 101-26.602 Section 101-26.602... Other Than GSA § 101-26.602 Fuels and packaged petroleum products obtained from or through the Defense... requirements for coal, natural gas from sources other than a public utility, petroleum fuels, and...

  15. 41 CFR 101-26.602 - Fuels and packaged petroleum products obtained from or through the Defense Logistics Agency.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... petroleum products obtained from or through the Defense Logistics Agency. 101-26.602 Section 101-26.602... Other Than GSA § 101-26.602 Fuels and packaged petroleum products obtained from or through the Defense... requirements for coal, natural gas from sources other than a public utility, petroleum fuels, and...

  16. Alcohol fuels: production. September 1985-December 1987 (citations from the NTIS data base). Report for September 1985-December 1987

    SciTech Connect

    Not Available

    1988-01-01

    This bibliography contains citations concerning the synthesis of alcohol fuels, including gasohol. Alcohol production from sugar beets, industrial wastes, hardwood, biomass, and coal conversion processes are discussed. Cellulose and lignin degradation processes are described. Production systems are evaluated. The utilization of alcohol fuels is discussed in a separate bibliography. (Contains 75 citations fully indexed and including a title list.)

  17. Non-catalytic alcoholysis process for production of biodiesel fuel by using bubble column reactor

    NASA Astrophysics Data System (ADS)

    Hagiwara, S.; Nabetani, H.; Nakajima, M.

    2015-04-01

    Biodiesel fuel is a replacement for diesel as a fuel produced from biomass resources. It is usually defined as a fatty acid methyl ester (FAME) derived from vegetable oil or animal fat. In European countries, such as Germany and France, biodiesel fuel is commercially produced mainly from rapeseed oil, whereas in the United States and Argentina, soybean oil is more frequently used. In many other countries such as Japan and countries in Southeast Asia, lipids that cannot be used as a food source could be more suitable materials for the production of biodiesel fuel because its production from edible oils could result in an increase in the price of edible oils, thereby increasing the cost of some foodstuffs. Therefore, used edible oil, lipids contained in waste effluent from the oil milling process, byproducts from oil refining process and crude oils from industrial crops such as jatropha could be more promising materials in these countries. The materials available in Japan and Southeast Asia for the production of biodiesel fuel have common characteristics; they contain considerable amount of impurities and are high in free fatty acids (FFA). Superheated methanol vapor (SMV) reactor might be a promising method for biodiesel fuel production utilizing oil feedstock containing FFA such as waste vegetable oil and crude vegetable oil. In the conventional method using alkaline catalyst, FFA contained in waste vegetable oil is known to react with alkaline catalyst such as NaOH and KOH generating saponification products and to inactivate it. Therefore, the FFA needs to be removed from the feedstock prior to the reaction. Removal of the alkaline catalyst after the reaction is also required. In the case of the SMV reactor, the processes for removing FFA prior to the reaction and catalyst after the reaction can be omitted because it requires no catalyst. Nevertheless, detailed study on the productivity of biodiesel fuel produced from waste vegetable oils and other non

  18. Dual application of duckweed and azolla plants for wastewater treatment and renewable fuels and petrochemicals production

    PubMed Central

    2014-01-01

    Background Shortages in fresh water supplies today affects more than 1 billion people worldwide. Phytoremediation strategies, based on the abilities of aquatic plants to recycle nutrients offer an attractive solution for the bioremediation of water pollution and represents one of the most globally researched issues. The subsequent application of the biomass from the remediation for the production of fuels and petrochemicals offers an ecologically friendly and cost-effective solution for water pollution problems and production of value-added products. Results In this paper, the feasibility of the dual application of duckweed and azolla aquatic plants for wastewater treatment and production of renewable fuels and petrochemicals is explored. The differences in absorption rates of the key wastewater nutrients, ammonium and phosphorus by these aquatic macrophytes were used as the basis for optimization of the composition of wastewater effluents. Analysis of pyrolysis products showed that azolla and algae produce a similar range of bio-oils that contain a large spectrum of petrochemicals including straight-chain C10-C21 alkanes, which can be directly used as diesel fuel supplement, or a glycerin-free component of biodiesel. Pyrolysis of duckweed produces a different range of bio-oil components that can potentially be used for the production of “green” gasoline and diesel fuel using existing techniques, such as catalytic hydrodeoxygenation. Conclusions Differences in absorption rates of the key wastewater nutrients, ammonium and phosphorus by different aquatic macrophytes can be used for optimization of composition of wastewater effluents. The generated data suggest that the composition of the petrochemicals can be modified in a targeted fashion, not only by using different species, but also by changing the source plants’ metabolic profile, by exposing them to different abiotic or biotic stresses. This study presents an attractive, ecologically friendly and cost

  19. Switchgrass biomass to ethanol production economics: Field to fuel approach

    NASA Astrophysics Data System (ADS)

    Haque, Mohua

    Scope and Method of Study. Switchgrass has been proposed as a dedicated energy crop. The first essay determines switchgrass yield response to nitrogen fertilizer for a single annual harvest in July and for a single annual harvest in October based on a field experiments conducted at Stillwater, OK. Data were fitted to several functional forms to characterize both the July harvest and the October harvest response functions. Extending the harvest window to take advantage of reduction in harvest machinery investment costs has important biological consequences. The second essay determines the cost to deliver a ton of switchgrass biomass to a 2,000 tons per day plant located in Oklahoma. The model accounts for differences in yield and nitrogen fertilizer requirements across harvest months. The data were incorporated into a multi-region, multi-period, monthly time-step, mixed integer mathematical programming model that was constructed to determine the optimal strategy. Desirable feedstock properties, biomass to biofuel conversion rate, and investment required in plant differs depending on which conversion technology is used. The third essay determines the breakeven ethanol price for a cellulosic biorefinery. A comprehensive mathematical programming model that encompasses the chain from land acquisition to ethanol production was constructed and solved. Findings and Conclusions. The July and October harvest plateau yield of 4.36 and 5.49 tons per acre were achieved with an estimated annual nitrogen fertilizer application of 80 and 63 pounds per acre, respectively. Farm gate production costs were estimated to be 60 per ton for the July harvest and 50 per ton for the October harvest. Based on the model results, the strategy of extending harvest over many months is economically preferable to a strategy of harvesting only in peak yield harvest months. Restricting harvest to a two-month harvest season would increase the cost to deliver feedstock by 23 percent. For a capital

  20. Innovative Fresh Water Production Process for Fossil Fuel Plants

    SciTech Connect

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight

    2006-09-29

    This project concerns a diffusion driven desalination (DDD) process where warm water is evaporated into a low humidity air stream, and the vapor is condensed out to produce distilled water. Although the process has a low fresh water to feed water conversion efficiency, it has been demonstrated that this process can potentially produce low cost distilled water when driven by low grade waste heat. This report summarizes the progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. Detailed heat and mass transfer analyses required to size and analyze the diffusion tower using a heated water input are described. The analyses agree quite well with the current data and the information available in the literature. The direct contact condenser has also been thoroughly analyzed and the system performance at optimal operating conditions has been considered using a heated water/ambient air input to the diffusion tower. The diffusion tower has also been analyzed using a heated air input. The DDD laboratory facility has successfully been modified to include an air heating section. Experiments have been conducted over a range of parameters for two different cases: heated air/heated water and heated air/ambient water. A theoretical heat and mass transfer model has been examined for both of these cases and agreement between the experimental and theoretical data is good. A parametric study reveals that for every liquid mass flux there is an air mass flux value where the diffusion tower energy consumption is minimal and an air mass flux where the fresh water production flux is maximized. A study was also performed to compare the DDD process with different inlet operating conditions as well as different packing. It is shown that the heated air/heated water case is more capable of greater fresh water production with the same energy consumption than the ambient air/heated water process at high liquid mass flux. It is also shown that there can be

  1. CO sub 2 sources for microalgae-based liquid fuel production

    SciTech Connect

    Feinberg, D.; Karpuk, M.

    1990-08-01

    Researchers in the Aquatic Species Program at the Solar Energy Research Institute are developing species of microalgae that have high percentages of lipids, or oils. These lipids can be extracted and converted to diesel fuel substitutes. Because microalgae need carbon dioxide (CO{sub 2}) as a nutrient, optimal microalgae growth occurs in CO{sub 2}-saturated solutions. For this reason, the authors of this study sought to identify possible large-scale sources of CO{sub 2} for microalgae-based liquid fuels production. The authors concluded that several such promising sources exist. 42 refs., 14 figs., 10 tabs.

  2. Maximizing Efficiency in Two-step Solar-thermochemical Fuel Production

    SciTech Connect

    Ermanoski, I.

    2015-05-01

    Widespread solar fuel production depends on its economic viability, largely driven by the solar-to-fuel conversion efficiency. Herein, the material and energy requirements in two-step solar-thermochemical cyclesare considered.The need for advanced redox active materials is demonstrated, by considering the oxide mass flow requirements at a large scale. Two approaches are also identified for maximizing the efficiency: optimizing reaction temperatures, and minimizing the pressure in the thermal reduction step by staged thermal reduction. The results show that each approach individually, and especially the two in conjunction, result in significant efficiency gains.

  3. Fission product release phenomena during core melt accidents in metal fueled heavy water reactors

    SciTech Connect

    Ellison, P G; Hyder, M L; Monson, P R; Randolph, H W; Hagrman, D L; McClure, P R; Leonard, M T

    1990-01-01

    The phenomena that determine fission product release rates from a core melting accident in a metal-fueled, heavy water reactor are described in this paper. This information is obtained from the analysis of the current metal fuel experimental data base and from the results of analytical calculations. Experimental programs in place at the Savannah River Site are described that will provide information to resolve uncertainties in the data base. The results of the experiments will be incorporated into new severe accident computer codes recently developed for this reactor design. 47 refs., 4 figs.

  4. Chironomus tentans bioassay for testing synthetic fuel products and effluents, with data on acridine and quinoline

    SciTech Connect

    Cushman, R.M.; McKamey, M.I.

    1981-05-01

    Sensitive tests of toxicity to aquatic insects are useful for assessing the effects of potential pollutants on aquatic ecosystems. Within the last few years, research emphasis has included the toxicity of coal-related synthetic fuel products and effluents to aquatic biota. As part of an Oak Ridge National Laboratory (ORNL) program to evaluate the environmental effects of synthetic fuel products and effluents, a series of tests is being used to measure the toxicity of whole and fractionated synthetic fuel products and effluents and representative pure compounds (polycyclic aromatic hydrocarbons, phenols, and azaarenes) to aquatic organisms. Synthetic fuel materials are complex mixtures of inorganic and organic substances, including aliphatic hydrocarbons, aromatic hydrocarbons, and N-, S-, and O-substituted aromatics. By testing fractions and components of whole materials, we can begin to explain observed toxic effects and recommend further treatment to reduce toxicity. Test organisms include freshwater crustaceans (Daphnia pulex and magna), green algae (Selenastrum capricornutum), blue-green algae (Microcystis aeruginosa), snails (Physa heterostropha and Helisoma sp.), fathead minnows (Pimephales promelas), bluegill sunfish (Lepomis macrochirus), and rainbow trout (Salmo gairdneri).

  5. Opportunities to increase the productivity of spent fuel shipping casks in the United States

    SciTech Connect

    Winsor, G.H.; Faletti, D.W.; DeSteese, J.G.

    1980-03-01

    Trends indicate that future transportation requirements for spent fuel will be different from those anticipated when the current generation of casks and vehicles was designed. Increased storage capacity at most reactors will increase the average post irradiation age of the spent fuel to be transported. A scenario is presented which shows the 18 casks currently available should be sufficient until approximately 1983. Beyond this time, it appears that an adequate transportation system can be maintained by acquiring, as needed, casks of current designs and new casks currently under development. Spent fuel transportation requirements in the post-1990 period can be met by a new generation of casks specifically designed to transport long-cooled fuel. In terms of the number of casks needed, productivity may be increased by 19% if rail cask turnaround time is reduced to 4 days from the current range of 6.5 to 8.5 days. Productivity defined as payloads per cask year could be increased 62% if the turnaround time for legal weight truck casks were reduced from 12 hours to 4 hours. On a similar basis, overweight truck casks show a 28% increase in productivity.

  6. Analyses of fuel crud and coolant-borne corrosion products in normal water chemistry BWRs

    NASA Astrophysics Data System (ADS)

    Sawicki, Jerzy A.

    2011-12-01

    The samples of crud removed from the surface of fuel rods and corrosion products sampled by filtration of condensate and feed water in three boiling water reactors (BWR) operating at normal water chemistry (NWC) were analyzed using 57Fe Mössbauer spectroscopy. The corrosion products concentration and phase composition was examined in filter membranes exposed to influent and effluent of condensate polishing resin beds, as well as to final feed water. The brushed and scraped portions of fuel crud extracted from fuel rods during refueling outage comprised mostly hematite, α-Fe 2O 3, and submicron-sized goethite particles, α-FeOOH, in weight ratio similar to that observed in feed water. The observed phases are consistent with the oxidizing water chemistry of NWC BWRs. The feasibility of identifying other iron oxides and oxyhydroxides, as well as copper and zinc bearing phases in corrosion products from BWRs is briefly discussed. The results of this work can be used to better understand and minimize iron transport and crud deposition on fuel rods in BWRs.

  7. Tapered fluidized bed bioreactor for environmental control and fuel production

    SciTech Connect

    Scott, C. D.; Hancher, C. W.; Arcuri, E. J.

    1980-01-01

    Fluidized bed bioreactors are under development for use in environmental control and energy production. The most effective systems utilize a tapered portion either throughout the column or at the top of the column. This taper allows a wide range of operating conditions without loss of the fluidized particulates, and in general, results in more stable operation. The system described here utilize fixed films of microorganisms that have attached themselves to the fluidized particles. Preliminary investigations of the attachment indicate that reactor performance is related to film thickness. The biological denitrification of aqueous waste streams is typical of processes under development that utilize fluidized bed bioreactors. This development has progressed to the pilot plant scale where two 20-cm-diam x 800-cm fluidized beds in series accept aqueous wastes with nitrate concentrations as high as 10,000 mg/l and denitrification rates greater than 50 g/l/day using residence times of less than 30 minutes in each reactor. Other applications include aerobic degradation of phenolic wastes at rates greater than 25 g/l/day and the conversion of glucose to ethanol.

  8. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for

  9. Microbial liquefaction of peat for the production of synthetic fuels

    SciTech Connect

    Gunasekaran, M.

    1988-01-01

    Objectives of this study were: to evaluate the potential of using various microorganisms to hydrolyse and liquify peat; to determine the optimal conditions for peat hydrolysis and liquefaction; to study the co-metabolizable substances; to separate the compounds present in liquified peat by alumina and silica acid chromatography and capillary gas chromatography; and to identify the compounds in liquified peat by capillary GC-Mass spectrometry. Organisms used in the study include: Coprinus comatus, Coriolus hirsutus, Ganoderma lucidum, Lentinus edodes, Lenzites trabea, Phanerochaete chrysosporium, Pleurotus ostreatus, P. sapidus, Polyporus adjustus, Neurospora sitophila, Rhizophus arrhizus, Bacillus subtilis, Acinetobacter sp. and Alcaligenes sp. The fungi were maintained and cultivated in potato dextrose agar at 30 C. The bacteria were maintained in nutrient agar at 30 C. We have also initiated work on coal solubilization in addition to the studies on peat liquefaction. A relatively new substratum or semi-solid base for culture media called Pluronic F-127, or Polyol (BASF, New Jersey). Objectives of this study were: (1) to study the growth patterns of Candida ML 13 on pluronic as substratum; (2) to determine the rate of microbial coal solubilization on pluronic F-127 amended in different growth media; (3) to separate the mycelial mat of Candida ML 13 from unsolubilized coal particles and solubilized coal products from pluronic F-127; (4) to determine the effects of pH on microbial coal solubilization in pluronic F-127 media; (5) the effect of concentration of pluronic F-127 in media on coal solubilization; and, (6) to study the role of extracellular factors secreted by Candida ML 13 on coal solubilization in pluronic F-127 media. Results are discussed. 4 refs.

  10. Water consumption footprint and land requirements of large-scale alternative diesel and jet fuel production.

    PubMed

    Staples, Mark D; Olcay, Hakan; Malina, Robert; Trivedi, Parthsarathi; Pearlson, Matthew N; Strzepek, Kenneth; Paltsev, Sergey V; Wollersheim, Christoph; Barrett, Steven R H

    2013-01-01

    Middle distillate (MD) transportation fuels, including diesel and jet fuel, make up almost 30% of liquid fuel consumption in the United States. Alternative drop-in MD and biodiesel could potentially reduce dependence on crude oil and the greenhouse gas intensity of transportation. However, the water and land resource requirements of these novel fuel production technologies must be better understood. This analysis quantifies the lifecycle green and blue water consumption footprints of producing: MD from conventional crude oil; Fischer-Tropsch MD from natural gas and coal; fermentation and advanced fermentation MD from biomass; and hydroprocessed esters and fatty acids MD and biodiesel from oilseed crops, throughout the contiguous United States. We find that FT MD and alternative MD derived from rainfed biomass have lifecycle blue water consumption footprints of 1.6 to 20.1 Lwater/LMD, comparable to conventional MD, which ranges between 4.1 and 7.4 Lwater/LMD. Alternative MD derived from irrigated biomass has a lifecycle blue water consumption footprint potentially several orders of magnitude larger, between 2.7 and 22 600 Lwater/LMD. Alternative MD derived from biomass has a lifecycle green water consumption footprint between 1.1 and 19 200 Lwater/LMD. Results are disaggregated to characterize the relationship between geo-spatial location and lifecycle water consumption footprint. We also quantify the trade-offs between blue water consumption footprint and areal MD productivity, which ranges from 490 to 4200 LMD/ha, under assumptions of rainfed and irrigated biomass cultivation. Finally, we show that if biomass cultivation for alternative MD is irrigated, the ratio of the increase in areal MD productivity to the increase in blue water consumption footprint is a function of geo-spatial location and feedstock-to-fuel production pathway. PMID:24066845

  11. Water consumption footprint and land requirements of large-scale alternative diesel and jet fuel production.

    PubMed

    Staples, Mark D; Olcay, Hakan; Malina, Robert; Trivedi, Parthsarathi; Pearlson, Matthew N; Strzepek, Kenneth; Paltsev, Sergey V; Wollersheim, Christoph; Barrett, Steven R H

    2013-01-01

    Middle distillate (MD) transportation fuels, including diesel and jet fuel, make up almost 30% of liquid fuel consumption in the United States. Alternative drop-in MD and biodiesel could potentially reduce dependence on crude oil and the greenhouse gas intensity of transportation. However, the water and land resource requirements of these novel fuel production technologies must be better understood. This analysis quantifies the lifecycle green and blue water consumption footprints of producing: MD from conventional crude oil; Fischer-Tropsch MD from natural gas and coal; fermentation and advanced fermentation MD from biomass; and hydroprocessed esters and fatty acids MD and biodiesel from oilseed crops, throughout the contiguous United States. We find that FT MD and alternative MD derived from rainfed biomass have lifecycle blue water consumption footprints of 1.6 to 20.1 Lwater/LMD, comparable to conventional MD, which ranges between 4.1 and 7.4 Lwater/LMD. Alternative MD derived from irrigated biomass has a lifecycle blue water consumption footprint potentially several orders of magnitude larger, between 2.7 and 22 600 Lwater/LMD. Alternative MD derived from biomass has a lifecycle green water consumption footprint between 1.1 and 19 200 Lwater/LMD. Results are disaggregated to characterize the relationship between geo-spatial location and lifecycle water consumption footprint. We also quantify the trade-offs between blue water consumption footprint and areal MD productivity, which ranges from 490 to 4200 LMD/ha, under assumptions of rainfed and irrigated biomass cultivation. Finally, we show that if biomass cultivation for alternative MD is irrigated, the ratio of the increase in areal MD productivity to the increase in blue water consumption footprint is a function of geo-spatial location and feedstock-to-fuel production pathway.

  12. Fuel-Flexible Combustion System for Co-production Plant Applications

    SciTech Connect

    Joel Haynes; Justin Brumberg; Venkatraman Iyer; Jonathan Janssen; Ben Lacy; Matt Mosbacher; Craig Russell; Ertan Yilmaz; Williams York; Willy Ziminsky; Tim Lieuwen; Suresh Menon; Jerry Seitzman; Ashok Anand; Patrick May

    2008-12-31

    Future high-efficiency, low-emission generation plants that produce electric power, transportation fuels, and/or chemicals from fossil fuel feed stocks require a new class of fuel-flexible combustors. In this program, a validated combustor approach was developed which enables single-digit NO{sub x} operation for a future generation plants with low-Btu off gas and allows the flexibility of process-independent backup with natural gas. This combustion technology overcomes the limitations of current syngas gas turbine combustion systems, which are designed on a site-by-site basis, and enable improved future co-generation plant designs. In this capacity, the fuel-flexible combustor enhances the efficiency and productivity of future co-production plants. In task 2, a summary of market requested fuel gas compositions was created and the syngas fuel space was characterized. Additionally, a technology matrix and chemical kinetic models were used to evaluate various combustion technologies and to select two combustor concepts. In task 4 systems analysis of a co-production plant in conjunction with chemical kinetic analysis was performed to determine the desired combustor operating conditions for the burner concepts. Task 5 discusses the experimental evaluation of three syngas capable combustor designs. The hybrid combustor, Prototype-1 utilized a diffusion flame approach for syngas fuels with a lean premixed swirl concept for natural gas fuels for both syngas and natural gas fuels at FA+e gas turbine conditions. The hybrid nozzle was sized to accommodate syngas fuels ranging from {approx}100 to 280 btu/scf and with a diffusion tip geometry optimized for Early Entry Co-generation Plant (EECP) fuel compositions. The swozzle concept utilized existing GE DLN design methodologies to eliminate flow separation and enhance fuel-air mixing. With changing business priorities, a fully premixed natural gas & syngas nozzle, Protoytpe-1N, was also developed later in the program. It did

  13. Method and device for fabricating dispersion fuel comprising fission product collection spaces

    DOEpatents

    Shaber, Eric L; Fielding, Randall S

    2015-05-05

    A method of fabricating a nuclear fuel comprising a fissile material, one or more hollow microballoons, a phenolic resin, and metal matrix. The fissile material, phenolic resin and the one or more hollow microballoons are combined. The combined fissile material, phenolic resin and the hollow microballoons are heated sufficiently to form at least some fissile material carbides creating a nuclear fuel particle. The resulting nuclear fuel particle comprises one or more fission product collection spaces. In a preferred embodiment, the fissile material, phenolic resin and the one or more hollow microballoons are combined by forming the fissile material into microspheres. The fissile material microspheres are then overcoated with the phenolic resin and microballoon. In another preferred embodiment, the fissile material, phenolic resin and the one or more hollow microballoons are combined by overcoating the microballoon with the fissile material, and phenolic resin.

  14. Fission product partitioning in aerosol release from simulated spent nuclear fuel

    NASA Astrophysics Data System (ADS)

    Di Lemma, F. G.; Colle, J. Y.; Rasmussen, G.; Konings, R. J. M.

    2015-10-01

    Aerosols created by the vaporization of simulated spent nuclear fuel (simfuel) were produced by laser heating techniques and characterised by a wide range of post-analyses. In particular attention has been focused on determining the fission product behaviour in the aerosols, in order to improve the evaluation of the source term and consequently the risk associated with release from spent fuel sabotage or accidents. Different simulated spent fuels were tested with burn-up up to 8 at. %. The results from the aerosol characterisation were compared with studies of the vaporization process by Knudsen Effusion Mass Spectrometry and thermochemical equilibrium calculations. These studies permit an understanding of the aerosol gaseous precursors and the gaseous reactions taking place during the aerosol formation process.

  15. Fuel cells are a commercially viable alternative for the production of "clean" energy.

    PubMed

    Niakolas, Dimitris K; Daletou, Maria; Neophytides, Stylianos G; Vayenas, Constantinos G

    2016-01-01

    Fuel cells present a highly efficient and environmentally friendly alternative technology for decentralized energy production. The scope of the present study is to provide an overview of the technological and commercialization readiness level of fuel cells. Specifically, there is a brief description of their general advantages and weaknesses in correlation with various technological actions and political strategies, which are adopted towards their proper positioning in the global market. Some of the most important key performance indicators are also discussed, alongside with a few examples of broad commercialization. It is concluded that the increasing number of companies which utilize and invest on this technology, in combination with the supply chain improvements and the concomitant technological maturity and recognition, reinforce the fuel cell industry so as to become well-aligned for global success.

  16. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect

    Gerald P. Huffman

    2003-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research.

  17. A review of recent advances in numerical simulations of microscale fuel processor for hydrogen production

    NASA Astrophysics Data System (ADS)

    Holladay, J. D.; Wang, Y.

    2015-05-01

    Microscale (<5 W) reformers for hydrogen production have been investigated for over a decade. These devices are intended to provide hydrogen for small fuel cells. Due to the reformer's small size, numerical simulations are critical to understand heat and mass transfer phenomena occurring in the systems and help guide the further improvements. This paper reviews the development of the numerical codes and details the reaction equations used. The majority of the devices utilized methanol as the fuel due to methanol's low reforming temperature and high conversion, although, there are several methane fueled systems. The increased computational power and more complex codes have led to improved accuracy of numerical simulations. Initial models focused on the reformer, while more recently, the simulations began including other unit operations such as vaporizers, inlet manifolds, and combustors. These codes are critical for developing the next generation systems. The systems reviewed included plate reactors, microchannel reactors, and annulus reactors for both wash-coated and packed bed systems.

  18. IMPACT OF FISSION PRODUCTS IMPURITY ON THE PLUTONIUM CONTENT IN PWR MOX FUELS

    SciTech Connect

    Gilles Youinou; Andrea Alfonsi

    2012-03-01

    This report presents the results of a neutronics analysis done in response to the charter IFCA-SAT-2 entitled 'Fuel impurity physics calculations'. This charter specifies that the separation of the fission products (FP) during the reprocessing of UOX spent nuclear fuel assemblies (UOX SNF) is not perfect and that, consequently, a certain amount of FP goes into the Pu stream used to fabricate PWR MOX fuel assemblies. Only non-gaseous FP have been considered (see the list of 176 isotopes considered in the calculations in Appendix 1). This mixture of Pu and FP is called PuFP. Note that, in this preliminary analysis, the FP losses are considered element-independent, i.e., for example, 1% of FP losses mean that 1% of all non-gaseous FP leak into the Pu stream.

  19. Reversal of the β-oxidation cycle in Saccharomyces cerevisiae for production of fuels and chemicals.

    PubMed

    Lian, Jiazhang; Zhao, Huimin

    2015-03-20

    Functionally reversing the β-oxidation cycle represents an efficient and versatile strategy for synthesis of a wide variety of fuels and chemicals. However, due to the compartmentalization of cellular metabolisms, reversing the β-oxidation cycle in eukaryotic systems remains elusive. Here, we report the first successful reversal of the β-oxidation cycle in Saccharomyces cerevisiae, an important cell factory for large-scale production of fuels and chemicals. After extensive gene cloning and enzyme activity assays, a reversed β-oxidation pathway was functionally constructed in the yeast cytosol, which led to the synthesis of n-butanol, medium-chain fatty acids (MCFAs), and medium-chain fatty acid ethyl esters (MCFAEEs). The resultant recombinant strain provides a new broadly applicable platform for synthesis of fuels and chemicals in S. cerevisiae.

  20. A review of recent advances of numerical simulations of microscale fuel processors for hydrogen production

    SciTech Connect

    Holladay, Jamelyn D.; Wang, Yong

    2015-05-01

    Microscale (<5W) reformers for hydrogen production have been investigated for over a decade. These devices are intended to provide hydrogen for small fuel cells. Due to the reformer’s small size, numerical simulations are critical to understand heat and mass transfer phenomena occurring in the systems. This paper reviews the development of the numerical codes and details the reaction equations used. The majority of the devices utilized methanol as the fuel due to methanol’s low reforming temperature and high conversion, although, there are several methane fueled systems. As computational power has decreased in cost and increased in availability, the codes increased in complexity and accuracy. Initial models focused on the reformer, while more recently, the simulations began including other unit operations such as vaporizers, inlet manifolds, and combustors. These codes are critical for developing the next generation systems. The systems reviewed included, plate reactors, microchannel reactors, annulus reactors, wash-coated, packed bed systems.

  1. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect

    Paul A. Erickson

    2004-04-01

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the second report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1--March 31, 2004. This quarter saw progress in five areas. These areas are: (1) Internal and external evaluations of coal based methanol and the fuel cell grade baseline fuel; (2) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation; (3) Design and set up of the autothermal reactor; (4) Steam reformation of Coal Based Methanol; and (5) Initial catalyst degradation studies. All of the projects are proceeding on or slightly ahead of schedule.

  2. Fuel cells are a commercially viable alternative for the production of "clean" energy.

    PubMed

    Niakolas, Dimitris K; Daletou, Maria; Neophytides, Stylianos G; Vayenas, Constantinos G

    2016-01-01

    Fuel cells present a highly efficient and environmentally friendly alternative technology for decentralized energy production. The scope of the present study is to provide an overview of the technological and commercialization readiness level of fuel cells. Specifically, there is a brief description of their general advantages and weaknesses in correlation with various technological actions and political strategies, which are adopted towards their proper positioning in the global market. Some of the most important key performance indicators are also discussed, alongside with a few examples of broad commercialization. It is concluded that the increasing number of companies which utilize and invest on this technology, in combination with the supply chain improvements and the concomitant technological maturity and recognition, reinforce the fuel cell industry so as to become well-aligned for global success. PMID:26667058

  3. Increasing the power density when using inert matrix fuels to reduce production of transuranics

    SciTech Connect

    Recktenwald, G.D.; Deinert, M.R.

    2013-07-01

    Reducing the production of transuranics is a goal of most advanced nuclear fuel cycles. One way to do this is to recycle the transuranics into the same reactors that are currently producing them using an inert matrix fuel. In previous work we have modeled such a reactor where 72%, of the core is comprised of standard enriched uranium fuel pins, with the remaining 28% fuel made from Yttria stabilized zirconium, in which transuranics are loaded. A key feature of this core is that all of the transuranics produced by the uranium fuel assemblies are later burned in inert matrix fuel assemblies. It has been shown that this system can achieve reductions in transuranic waste of more than 86%. The disadvantage of such a system is that the core power rating must be significantly lower than a standard pressurized water reactor. One reason for the lower power is that high burnup of the uranium fuel precludes a critical level of reactivity at the end of the campaign. Increasing the uranium enrichment and changing the pin pitch are two ways to increase burnup while maintaining criticality. In this paper we use MCNPX and a linear reactivity model to quantify the effect of these two parameters on the end of campaign reactivity. Importantly, we show that in the region of our proposed reactor, enrichment increases core reactivity by 0.02 per percent uranium 235 and pin pitch increases reactivity by 0.02 per mm. Reactivity is lost at a rate of 0.005 per MWd/kgIHM uranium burnup. (authors)

  4. Economics of liquefied natural gas production, transport and distribution for end use as a transportation fuel

    SciTech Connect

    Adkins, R.E.; Sutton, H.E.

    1994-12-31

    Natural gas vehicles have been operating in the United States for over 30 years. With few exceptions, these vehicles are owned and operated by local gas utilities that utilize the natural gas in the compressed form (CNG), at pressures of up to 3,600 psi. However, the limited range, system weight and the high cost of fueling facilities presents a serious handicap for these compressed fuel systems. Liquefied natural gas (LNG) automotive fuel systems, on the other hand, are a relatively new player in the emerging clean fuels market. While the technical feasibility, safety, and operational suitability of LNG fuel systems have been demonstrated during the past 20 years, in a variety of test projects including automotive, marine, aviation, and rail systems, little has been done to commercialize or promote this technology. Recent independent cost comparisons and technical evaluations have been conducted by several major transit organizations and national truck fleets with interesting results. They have concluded that LNG automotive fuel systems can meet the performance and operational criteria of their gasoline and diesel fuel systems without compromising vehicle range or imposing unacceptable weight and payload penalties on their vehicles. The purpose of this paper is to further define the economics of LNG production, transportation and distribution costs. The liquefaction of natural gas is a mature technology and was first accomplished by Faraday in 1855. The first large scale plants were installed in the United States in 1941 and this paper provides a summary of the issues and costs associated with the procurement, installation, and operation of modern day natural gas liquefaction systems. There are no technical barriers to building LNG plants where needed. In addition to these {open_quotes}peak shaving{close_quotes} liquefaction plants, operated by utilities, there are many liquefaction plants owned and operated by the industrial gas business sector.

  5. Metabolic engineering of Clostridium acetobutylicum for the enhanced production of isopropanol-butanol-ethanol fuel mixture.

    PubMed

    Jang, Yu-Sin; Malaviya, Alok; Lee, Joungmin; Im, Jung Ae; Lee, Sang Yup; Lee, Julia; Eom, Moon-Ho; Cho, Jung-Hee; Seung, Do Young

    2013-01-01

    Butanol is considered as a superior biofuel, which is conventionally produced by clostridial acetone-butanol-ethanol (ABE) fermentation. Among ABE, only butanol and ethanol can be used as fuel alternatives. Coproduction of acetone thus causes lower yield of fuel alcohols. Thus, this study aimed at developing an improved Clostridium acetobutylicum strain possessing enhanced fuel alcohol production capability. For this, we previously developed a hyper ABE producing BKM19 strain was further engineered to convert acetone into isopropanol. The BKM19 strain was transformed with the plasmid pIPA100 containing the sadh (primary/secondary alcohol dehydrogenase) and hydG (putative electron transfer protein) genes from the Clostridium beijerinckii NRRL B593 cloned under the control of the thiolase promoter. The resulting BKM19 (pIPA100) strain produced 27.9 g/l isopropanol-butanol-ethanol (IBE) as a fuel alcohols with negligible amount of acetone (0.4 g/l) from 97.8 g/l glucose in lab-scale (2 l) batch fermentation. Thus, this metabolically engineered strain was able to produce 99% of total solvent produced as fuel alcohols. The scalability and stability of BKM19 (pIPA100) were evaluated at 200 l pilot-scale fermentation, which showed that the fuel alcohol yield could be improved to 0.37 g/g as compared to 0.29 g/g obtained at lab-scale fermentation, while attaining a similar titer. To the best of our knowledge, this is the highest titer of IBE achieved and the first report on the large scale fermentation of C. acetobutylicum for IBE production.

  6. Selection and properties of alternative forming fluids for TRISO fuel kernel production

    SciTech Connect

    Baker, M. P.; King, J. C.; Gorman, B. P.; Marshall, Doug W.

    2013-01-01

    Current Very High Temperature Reactor (VHTR) designs incorporate TRi-structural ISOtropic (TRISO) fuel, which consists of a spherical fissile fuel kernel surrounded by layers of pyrolytic carbon and silicon carbide. An internal sol-gel process forms the fuel kernel using wet chemistry to produce uranium oxyhydroxide gel spheres by dropping a cold precursor solution into a hot column of trichloroethylene (TCE). Over time, gelation byproducts inhibit complete gelation, and the TCE must be purified or discarded. The resulting TCE waste stream contains both radioactive and hazardous materials and is thus considered a mixed hazardous waste. Changing the forming fluid to a non-hazardous alternative could greatly improve the economics of TRISO fuel kernel production. Selection criteria for a replacement forming fluid narrowed a list of ~10,800 chemicals to yield ten potential replacement forming fluids: 1-bromododecane, 1- bromotetradecane, 1-bromoundecane, 1-chlorooctadecane, 1-chlorotetradecane, 1-iododecane, 1-iodododecane, 1-iodohexadecane, 1-iodooctadecane, and squalane. The density, viscosity, and surface tension for each potential replacement forming fluid were measured as a function of temperature between 25 °C and 80 °C. Calculated settling velocities and heat transfer rates give an overall column height approximation. 1-bromotetradecane, 1-chlorooctadecane, and 1-iodododecane show the greatest promise as replacements, and future tests will verify their ability to form satisfactory fuel kernels.

  7. Seawater usable for production and consumption of hydrogen peroxide as a solar fuel.

    PubMed

    Mase, Kentaro; Yoneda, Masaki; Yamada, Yusuke; Fukuzumi, Shunichi

    2016-05-04

    Hydrogen peroxide (H2O2) in water has been proposed as a promising solar fuel instead of gaseous hydrogen because of advantages on easy storage and high energy density, being used as a fuel of a one-compartment H2O2 fuel cell for producing electricity on demand with emitting only dioxygen (O2) and water. It is highly desired to utilize the most earth-abundant seawater instead of precious pure water for the practical use of H2O2 as a solar fuel. Here we have achieved efficient photocatalytic production of H2O2 from the most earth-abundant seawater instead of precious pure water and O2 in a two-compartment photoelectrochemical cell using WO3 as a photocatalyst for water oxidation and a cobalt complex supported on a glassy-carbon substrate for the selective two-electron reduction of O2. The concentration of H2O2 produced in seawater reached 48 mM, which was high enough to operate an H2O2 fuel cell.

  8. Seawater usable for production and consumption of hydrogen peroxide as a solar fuel

    NASA Astrophysics Data System (ADS)

    Mase, Kentaro; Yoneda, Masaki; Yamada, Yusuke; Fukuzumi, Shunichi

    2016-05-01

    Hydrogen peroxide (H2O2) in water has been proposed as a promising solar fuel instead of gaseous hydrogen because of advantages on easy storage and high energy density, being used as a fuel of a one-compartment H2O2 fuel cell for producing electricity on demand with emitting only dioxygen (O2) and water. It is highly desired to utilize the most earth-abundant seawater instead of precious pure water for the practical use of H2O2 as a solar fuel. Here we have achieved efficient photocatalytic production of H2O2 from the most earth-abundant seawater instead of precious pure water and O2 in a two-compartment photoelectrochemical cell using WO3 as a photocatalyst for water oxidation and a cobalt complex supported on a glassy-carbon substrate for the selective two-electron reduction of O2. The concentration of H2O2 produced in seawater reached 48 mM, which was high enough to operate an H2O2 fuel cell.

  9. Seawater usable for production and consumption of hydrogen peroxide as a solar fuel

    PubMed Central

    Mase, Kentaro; Yoneda, Masaki; Yamada, Yusuke; Fukuzumi, Shunichi

    2016-01-01

    Hydrogen peroxide (H2O2) in water has been proposed as a promising solar fuel instead of gaseous hydrogen because of advantages on easy storage and high energy density, being used as a fuel of a one-compartment H2O2 fuel cell for producing electricity on demand with emitting only dioxygen (O2) and water. It is highly desired to utilize the most earth-abundant seawater instead of precious pure water for the practical use of H2O2 as a solar fuel. Here we have achieved efficient photocatalytic production of H2O2 from the most earth-abundant seawater instead of precious pure water and O2 in a two-compartment photoelectrochemical cell using WO3 as a photocatalyst for water oxidation and a cobalt complex supported on a glassy-carbon substrate for the selective two-electron reduction of O2. The concentration of H2O2 produced in seawater reached 48 mM, which was high enough to operate an H2O2 fuel cell. PMID:27142725

  10. Efficient solar-to-fuels production from a hybrid microbial–water-splitting catalyst system

    PubMed Central

    Torella, Joseph P.; Gagliardi, Christopher J.; Chen, Janice S.; Bediako, D. Kwabena; Colón, Brendan; Way, Jeffery C.; Silver, Pamela A.; Nocera, Daniel G.

    2015-01-01

    Photovoltaic cells have considerable potential to satisfy future renewable-energy needs, but efficient and scalable methods of storing the intermittent electricity they produce are required for the large-scale implementation of solar energy. Current solar-to-fuels storage cycles based on water splitting produce hydrogen and oxygen, which are attractive fuels in principle but confront practical limitations from the current energy infrastructure that is based on liquid fuels. In this work, we report the development of a scalable, integrated bioelectrochemical system in which the bacterium Ralstonia eutropha is used to efficiently convert CO2, along with H2 and O2 produced from water splitting, into biomass and fusel alcohols. Water-splitting catalysis was performed using catalysts that are made of earth-abundant metals and enable low overpotential water splitting. In this integrated setup, equivalent solar-to-biomass yields of up to 3.2% of the thermodynamic maximum exceed that of most terrestrial plants. Moreover, engineering of R. eutropha enabled production of the fusel alcohol isopropanol at up to 216 mg/L, the highest bioelectrochemical fuel yield yet reported by >300%. This work demonstrates that catalysts of biotic and abiotic origin can be interfaced to achieve challenging chemical energy-to-fuels transformations. PMID:25675518

  11. Seawater usable for production and consumption of hydrogen peroxide as a solar fuel.

    PubMed

    Mase, Kentaro; Yoneda, Masaki; Yamada, Yusuke; Fukuzumi, Shunichi

    2016-01-01

    Hydrogen peroxide (H2O2) in water has been proposed as a promising solar fuel instead of gaseous hydrogen because of advantages on easy storage and high energy density, being used as a fuel of a one-compartment H2O2 fuel cell for producing electricity on demand with emitting only dioxygen (O2) and water. It is highly desired to utilize the most earth-abundant seawater instead of precious pure water for the practical use of H2O2 as a solar fuel. Here we have achieved efficient photocatalytic production of H2O2 from the most earth-abundant seawater instead of precious pure water and O2 in a two-compartment photoelectrochemical cell using WO3 as a photocatalyst for water oxidation and a cobalt complex supported on a glassy-carbon substrate for the selective two-electron reduction of O2. The concentration of H2O2 produced in seawater reached 48 mM, which was high enough to operate an H2O2 fuel cell. PMID:27142725

  12. Efficient solar-to-fuels production from a hybrid microbial-water-splitting catalyst system.

    PubMed

    Torella, Joseph P; Gagliardi, Christopher J; Chen, Janice S; Bediako, D Kwabena; Colón, Brendan; Way, Jeffery C; Silver, Pamela A; Nocera, Daniel G

    2015-02-24

    Photovoltaic cells have considerable potential to satisfy future renewable-energy needs, but efficient and scalable methods of storing the intermittent electricity they produce are required for the large-scale implementation of solar energy. Current solar-to-fuels storage cycles based on water splitting produce hydrogen and oxygen, which are attractive fuels in principle but confront practical limitations from the current energy infrastructure that is based on liquid fuels. In this work, we report the development of a scalable, integrated bioelectrochemical system in which the bacterium Ralstonia eutropha is used to efficiently convert CO2, along with H2 and O2 produced from water splitting, into biomass and fusel alcohols. Water-splitting catalysis was performed using catalysts that are made of earth-abundant metals and enable low overpotential water splitting. In this integrated setup, equivalent solar-to-biomass yields of up to 3.2% of the thermodynamic maximum exceed that of most terrestrial plants. Moreover, engineering of R. eutropha enabled production of the fusel alcohol isopropanol at up to 216 mg/L, the highest bioelectrochemical fuel yield yet reported by >300%. This work demonstrates that catalysts of biotic and abiotic origin can be interfaced to achieve challenging chemical energy-to-fuels transformations.

  13. Selection and properties of alternative forming fluids for TRISO fuel kernel production

    NASA Astrophysics Data System (ADS)

    Baker, M. P.; King, J. C.; Gorman, B. P.; Marshall, D. W.

    2013-01-01

    Current Very High Temperature Reactor (VHTR) designs incorporate TRi-structural ISOtropic (TRISO) fuel, which consists of a spherical fissile fuel kernel surrounded by layers of pyrolytic carbon and silicon carbide. An internal sol-gel process forms the fuel kernel using wet chemistry to produce uranium oxyhydroxide gel spheres by dropping a cold precursor solution into a hot column of trichloroethylene (TCE). Over time, gelation byproducts inhibit complete gelation, and the TCE must be purified or discarded. The resulting TCE waste stream contains both radioactive and hazardous materials and is thus considered a mixed hazardous waste. Changing the forming fluid to a non-hazardous alternative could greatly improve the economics of TRISO fuel kernel production. Selection criteria for a replacement forming fluid narrowed a list of ˜10,800 chemicals to yield ten potential replacement forming fluids: 1-bromododecane, 1-bromotetradecane, 1-bromoundecane, 1-chlorooctadecane, 1-chlorotetradecane, 1-iododecane, 1-iodododecane, 1-iodohexadecane, 1-iodooctadecane, and squalane. The density, viscosity, and surface tension for each potential replacement forming fluid were measured as a function of temperature between 25 °C and 80 °C. Calculated settling velocities and heat transfer rates give an overall column height approximation. 1-bromotetradecane, 1-chlorooctadecane, and 1-iodododecane show the greatest promise as replacements, and future tests will verify their ability to form satisfactory fuel kernels.

  14. Efficient solar-to-fuels production from a hybrid microbial-water-splitting catalyst system.

    PubMed

    Torella, Joseph P; Gagliardi, Christopher J; Chen, Janice S; Bediako, D Kwabena; Colón, Brendan; Way, Jeffery C; Silver, Pamela A; Nocera, Daniel G

    2015-02-24

    Photovoltaic cells have considerable potential to satisfy future renewable-energy needs, but efficient and scalable methods of storing the intermittent electricity they produce are required for the large-scale implementation of solar energy. Current solar-to-fuels storage cycles based on water splitting produce hydrogen and oxygen, which are attractive fuels in principle but confront practical limitations from the current energy infrastructure that is based on liquid fuels. In this work, we report the development of a scalable, integrated bioelectrochemical system in which the bacterium Ralstonia eutropha is used to efficiently convert CO2, along with H2 and O2 produced from water splitting, into biomass and fusel alcohols. Water-splitting catalysis was performed using catalysts that are made of earth-abundant metals and enable low overpotential water splitting. In this integrated setup, equivalent solar-to-biomass yields of up to 3.2% of the thermodynamic maximum exceed that of most terrestrial plants. Moreover, engineering of R. eutropha enabled production of the fusel alcohol isopropanol at up to 216 mg/L, the highest bioelectrochemical fuel yield yet reported by >300%. This work demonstrates that catalysts of biotic and abiotic origin can be interfaced to achieve challenging chemical energy-to-fuels transformations. PMID:25675518

  15. TVA application of integrated onfarm fuel alcohol production system. Annual report

    SciTech Connect

    Badger, P C; Pile, R S

    1980-01-01

    This contract has provided for the documentation of the feasibility of fuel alcohol production with small onfarm facilities, and for the design and construction of an efficient and easily constructed production facility. A feasibility study and a preliminary design report have been prepared. A prototype facility has been designed and constructed with a design production rate of 10 gallons per hour of 190-proof ethanol. The components of the facility are readily available through normal equipment supply channels or can be primarily owner-constructed. Energy efficiency was also of prime consideration in the design, and heat recovery equipment is included where practical. A renewable fuel boiler is used for process heat. Applicable safety standards and environmental requirements were also incorporated into the design. Other project activities included modification of a pickup truck to use the hydrous alcohol produced, evaluation of vacuum distillation for onfarm units, and development of a computer program to allow detailed economic analyses of fuel alcohol production. Efforts were also initiated to evaluate nongrain feedstocks, develop a preliminary design for a low-cost wood-fired boiler, and evaluate packed distillation columns constructed of plastic pipe.

  16. MINING PROCESS AND PRODUCT INFORMATION FROM PRESSURE FLUCTUATIONS WITHIN A FUEL PARTICLE COATER

    SciTech Connect

    Douglas W. Marshall; Charles M. Barnes

    2008-09-01

    The Next Generation Nuclear Power (NGNP) Fuel Development and Qualification Program included the design, installation, and testing of a 6-inch diameter nuclear fuel particle coater to demonstrate quality TRISO fuel production on a small industrial scale. Scale-up from the laboratory-scale coater faced challenges associated with an increase in the kernel charge mass, kernel diameter, and a redesign of the gas distributor to achieve adequate fluidization throughout the deposition of the four TRISO coating layers. TRISO coatings are applied at very high temperatures in atmospheres of dense particulate clouds, corrosive gases, and hydrogen concentrations over 45% by volume. The severe environment, stringent product and process requirements, and the fragility of partially-formed coatings limit the insertion of probes or instruments into the coater vessel during operation. Pressure instrumentation were installed on the gas inlet line and exhaust line of the 6-inch coater to monitor the bed differential pressure and internal pressure fluctuations emanating from the fuel bed as a result of bed and gas “bubble” movement. These instruments are external to the particle bed and provide a glimpse into the dynamics of fuel particle bed during the coating process and data that could be used to help ascertain the adequacy of fluidization and, potentially, the dominant fluidization regimes. Pressure fluctuation and differential pressure data are not presently useful as process control instruments, but data suggest a link between the pressure signal structure and some measurable product attributes that could be exploited to get an early estimate of the attribute values.

  17. Transportation fuel production by combination of LDPE thermal cracking and catalytic hydroreforming.

    PubMed

    Escola, J M; Aguado, J; Serrano, D P; Briones, L

    2014-11-01

    Fuel production from plastics is a promising way to reduce landfilling rates while obtaining valuable products. The usage of Ni-supported hierarchical Beta zeolite (h-Beta) for the hydroreforming of the oils coming from LDPE thermal cracking has proved to produce high selectivities to gasoline and diesel fuels (>80%). In the present work, the effect of the Ni loading on Ni/h-Beta is investigated in the hydroreforming of the oils form LDPE thermal cracking. h-Beta samples were impregnated with Ni nitrate, calcined and reduced in H2 up to 550°C to achieve different Ni contents: 1.5%, 4%, 7% and 10%. Larger and more easily reducible metal particles were obtained on Ni 7%/h-Beta and Ni 10%/h-Beta. Hydroreforming tests were carried out in autoclave reactor at 310°C, under 20 bar H2, for 45 min. Ni content progressively increased the amount of gases at the expenses of diesel fractions, while gasoline remained approximately constant about 52-54%. Maximum selectivity to automotive fuels (∼81%) was obtained with Ni 7%/h-Beta. Ni loading also enhanced olefins saturation up to Ni 7%/h-Beta. High cetane indices (71-86) and octane numbers (89-91) were obtained over all the catalysts. Regarding the different studied Ni contents, Ni 7%/h-Beta constitutes a rather promising catalyst for obtaining high quality fuels from LDPE thermal cracking oils.

  18. Partitioning of selected fission products from irradiated oxide fuel induced by thermal treatment

    NASA Astrophysics Data System (ADS)

    Shcherbina, Natalia; Kivel, Niko; Günther-Leopold, Ines

    2013-06-01

    The release of fission products (FPs) from spent nuclear fuel (SNF) has been studied as a function of the temperature and redox conditions. The present paper concerns essentially the high temperature separation of Cs and Sr from irradiated pressurized (PWR) and boiling water reactor (BWR) fuel of different burn-up levels with use of an in-house designed system for inductive vaporization (InVap). Using thermodynamic calculations with the Module of Fission Product Release (MFPR) code along with annealing experiments on SNF in the InVap it was shown that the speciation of Cs and Sr, hence their release behavior at high temperature, is sensitive to the redox conditions during thermal treatment. It was demonstrated that annealing conditions in the InVap can be adjusted in the way to promote the release of selected FPs without significant loss of the fuel matrix or actinides: complete release of Cs and I was achieved during treatment of irradiated fuel at 1800 °C under reducing atmosphere (0.7% H2/Ar mixture). The developed partitioning procedure can be used for the SNF pretreatment as an advanced head-end step in the hydrometallurgical or pyrochemical reprocessing technology.

  19. Alloy waste forms for metal fission products and actinides isolated by spent nuclear fuel treatment

    SciTech Connect

    McDeavitt, S.M.; Abraham, D.P.; Keiser, D.D. Jr.; Park, J.Y.

    1996-10-01

    Waste form alloys are being developed at Argonne National Laboratory for the disposal of remnant metallic wastes from an electrometallurgical process developed to treat spent nuclear fuel. This metal waste form consists of the fuel cladding (stainless steel or Zircaloy), noble metal fission products (e.g., Ru, Pd, Mo and Tc), and other metallic wastes. The main constituents of the metal waste stream are the cladding hulls (85 to 90 wt%); using the hulls as the dominant alloying component minimizes the overall waste volume as compared to vitrification or metal encapsulation. Two nominal compositions for the waste form are being developed: (1) stainless steel-15 wt% zirconium for stainless steel-clad fuels and (2) zirconium-8 wt% stainless steel for Zircaloy-clad fuels. The noble metal fission products are the primary source of radiation in the metal waste form. However, inclusion of actinides in the metal waste form is being investigated as an option for interim or ultimate storage. Simulated waste form alloys were prepared and analyzed to determine the baseline alloy microstructures and the microstructural distribution of noble metals and actinides. Corrosion tests of the metal waste form alloys indicate that they are highly resistant to corrosion.

  20. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program

    SciTech Connect

    Weakley, Steven A.

    2012-09-28

    The purpose of the project described in this report is to identify and document the commercial and emerging (projected to be commercialized within the next 3 years) hydrogen and fuel cell technologies and products that resulted from Department of Energy support through the Fuel Cell Technologies (FCT) Program in the Office of Energy Efficiency and Renewable Energy (EERE). Pacific Northwest National Laboratory (PNNL) undertook two efforts simultaneously to accomplish this project. The first effort was a patent search and analysis to identify patents related to hydrogen and fuel cells that are associated with FCT-funded projects (or projects conducted by DOE-EERE predecessor programs) and to ascertain the patents’ current status, as well as any commercial products that may have used the technology documented in the patent. The second effort was a series of interviews with current and past FCT personnel, a review of relevant program annual reports, and an examination of grants made under the Small Business Innovation Research and Small Business Technology Transfer Programs that are related to hydrogen and fuel cells.

  1. Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program

    SciTech Connect

    Weakley, Steven A.; Brown, Scott A.

    2011-09-29

    The purpose of the project described in this report is to identify and document the commercial and emerging (projected to be commercialized within the next 3 years) hydrogen and fuel cell technologies and products that resulted from Department of Energy support through the Fuel Cell Technologies (FCT) Program in the Office of Energy Efficiency and Renewable Energy (EERE). To do this, Pacific Northwest National Laboratory (PNNL) undertook two efforts simultaneously to accomplish this project. The first effort was a patent search and analysis to identify hydrogen- and fuel-cell-related patents that are associated with FCT-funded projects (or projects conducted by DOE-EERE predecessor programs) and to ascertain the patents current status, as well as any commercial products that may have used the technology documented in the patent. The second effort was a series of interviews with current and past FCT personnel, a review of relevant program annual reports, and an examination of hydrogen- and fuel-cell-related grants made under the Small Business Innovation Research and Small Business Technology Transfer Programs, and within the FCT portfolio.

  2. Synthesis of the U.S. specified ceramics using MOX fuel production expertise

    NASA Astrophysics Data System (ADS)

    Astafiev, V. A.; Glushenkov, A. E.; Sideinikov, M.; Borisov, G. B.; Mansourov, O. A.; Jardine, L. J.

    2000-07-01

    At present, under the auspices of the USA/Russia agreements, joint work is under way to dispose of excess plutonium being withdrawn from nuclear defense programs. A major approach is to produce mixed plutonium-uranium fuel (MOX fuel) for its further burnup in different nuclear reactors. Plutonium-containing materials, which upon their composition or from an economic standpoint cannot be used for MOX fuel production, are to be immobilized into solid ceramic and glass-type matrices with their safe storage and eventual geologic disposal. For an immobilization form in the U.S., it is proposed to use ceramics based on pyrochlore developed at LLNL that is capable of incorporating up to 10 wt.% PuO2 and 23 wt.% UO2. At VNIINM, work was done to assess the possibility of using equipment and expertise of MOX-fuel production to fabricate the ceramics. A few of the ceramic samples were synthesized, and basic physicochemical properties, including the homogeneity of the plutonium and uranium distributions in the matrix, density, and pellet porosity, were also measured.

  3. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO

  4. Gaseous fission product management for molten salt reactors and vented fuel systems

    SciTech Connect

    Messenger, S. J.; Forsberg, C.; Massie, M.

    2012-07-01

    Fission gas disposal is one of the unresolved difficulties for Molten Salt Reactors (MSRs) and advanced reactors with vented fuel systems. As these systems operate, they produce many radioactive isotopes of xenon and krypton (e.g. {sup 135}Xe t{sub 1/2} = 9.14 hours and {sup 85}Kr t{sub 1/2}= 10.73 years). Removing these gases proves vital to the success of such reactor designs for two reasons. First, the gases act as large neutron sinks which decrease reactivity and must be counterbalanced by increasing fuel loading. Second, for MSRs, inert fission product gases naturally separate quickly from high temperature salts, thus creating high vapor pressure which poses safety concerns. For advanced reactors with solid vented fuel, the gases are allowed to escape into an off-gas system and thus must be managed. Because of time delays in transport of fission product gases in vented fuel systems, some of the shorter-lived radionuclides will decay away thereby reducing the fission gas source term relative to an MSR. To calculate the fission gas source term of a typical molten salt reactor, we modeled a 1000 MWe graphite moderated thorium MSR similar to that detailed in Mathieu et al. [1]. The fuel salt used in these calculations was LiF (78 mole percent) - (HN)F 4 (22 mole percent) with a heavy nuclide composition of 3.86% {sup 233}U and 96.14% {sup 232}Th by mass. Before we can remove the fission product gases produced by this reactor configuration, we must first develop an appropriate storage mechanism. The gases could be stored in pressurized containers but then one must be concerned about bottle failure. Methods to trap noble gases in matrices are expensive and complex. Alternatively, there are direct storage/disposal options: direct injection into the Earth or injecting a grout-based product into the Earth. Advances in drilling technologies, hydro fracture technologies, and methods for the sequestration of carbon dioxide from fossil fuel plants are creating new options

  5. Mass, energy and material balances of SRF production process. Part 3: solid recovered fuel produced from municipal solid waste.

    PubMed

    Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne

    2015-02-01

    This is the third and final part of the three-part article written to describe the mass, energy and material balances of the solid recovered fuel production process produced from various types of waste streams through mechanical treatment. This article focused the production of solid recovered fuel from municipal solid waste. The stream of municipal solid waste used here as an input waste material to produce solid recovered fuel is energy waste collected from households of municipality. This article presents the mass, energy and material balances of the solid recovered fuel production process. These balances are based on the proximate as well as the ultimate analysis and the composition determination of various streams of material produced in a solid recovered fuel production plant. All the process streams are sampled and treated according to CEN standard methods for solid recovered fuel. The results of the mass balance of the solid recovered fuel production process showed that 72% of the input waste material was recovered in the form of solid recovered fuel; 2.6% as ferrous metal, 0.4% as non-ferrous metal, 11% was sorted as rejects material, 12% as fine faction and 2% as heavy fraction. The energy balance of the solid recovered fuel production process showed that 86% of the total input energy content of input waste material was recovered in the form of solid recovered fuel. The remaining percentage (14%) of the input energy was split into the streams of reject material, fine fraction and heavy fraction. The material balances of this process showed that mass fraction of paper and cardboard, plastic (soft) and wood recovered in the solid recovered fuel stream was 88%, 85% and 90%, respectively, of their input mass. A high mass fraction of rubber material, plastic (PVC-plastic) and inert (stone/rock and glass particles) was found in the reject material stream.

  6. Mass, energy and material balances of SRF production process. Part 3: solid recovered fuel produced from municipal solid waste.

    PubMed

    Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Kärki, Janne

    2015-02-01

    This is the third and final part of the three-part article written to describe the mass, energy and material balances of the solid recovered fuel production process produced from various types of waste streams through mechanical treatment. This article focused the production of solid recovered fuel from municipal solid waste. The stream of municipal solid waste used here as an input waste material to produce solid recovered fuel is energy waste collected from households of municipality. This article presents the mass, energy and material balances of the solid recovered fuel production process. These balances are based on the proximate as well as the ultimate analysis and the composition determination of various streams of material produced in a solid recovered fuel production plant. All the process streams are sampled and treated according to CEN standard methods for solid recovered fuel. The results of the mass balance of the solid recovered fuel production process showed that 72% of the input waste material was recovered in the form of solid recovered fuel; 2.6% as ferrous metal, 0.4% as non-ferrous metal, 11% was sorted as rejects material, 12% as fine faction and 2% as heavy fraction. The energy balance of the solid recovered fuel production process showed that 86% of the total input energy content of input waste material was recovered in the form of solid recovered fuel. The remaining percentage (14%) of the input energy was split into the streams of reject material, fine fraction and heavy fraction. The material balances of this process showed that mass fraction of paper and cardboard, plastic (soft) and wood recovered in the solid recovered fuel stream was 88%, 85% and 90%, respectively, of their input mass. A high mass fraction of rubber material, plastic (PVC-plastic) and inert (stone/rock and glass particles) was found in the reject material stream. PMID:25568089

  7. Brewing industry potential for the immediate and near-term production of fuel-grade ethyl alcohol. Final report

    SciTech Connect

    Mulloney, J.A. Jr.

    1980-04-15

    The brewing industry is described as it relates to productive facilities and potential for fuel grade ethyl alcohol production. The brewing process is compared to the fuel grade ethyl alcohol process in a brewery. A description is given for retrofitting a brewery as a distilled spirits plant. The following are included: estimated capital requirements and alcohol costs, targets of opportunity, barriers and actions affecting brewery production of ethyl alcohol, suggested action programs, and recommended program activities. (MHR)

  8. Polyol-acid anhydride-n-alkyl-alkylene diamine reaction product and motor fuel composition containing same

    SciTech Connect

    Sung, R.L.; Jenkins, R.H. Jr.

    1987-02-17

    A fuel composition for an internal combustion engine comprising: (a) a major portion of a liquid hydrocarbon fuel and (b) a minor amount, as a deposit inhibitor additive, of a reaction product of a process comprising: (i) reacting a dibasic acid anhydride with a polyol, thereby forming an ester of maleic acid; (ii) reacting the ester of maleic acid with an N-alkyl-alkylene diamine, thereby forming the reaction product; and (iii) recovering the reaction product.

  9. Simulation of a hydrogen production and purification system for a PEM fuel-cell using bioethanol as raw material

    NASA Astrophysics Data System (ADS)

    Giunta, Pablo; Mosquera, Carlos; Amadeo, Norma; Laborde, Miguel

    A process to produce "fuel-cell grade" hydrogen from ethanol steam reforming is analyzed from a thermodynamic point of view. The hydrogen purification process consists of WGS and COPROX reactors. Equations to evaluate the efficiency of the system, including the fuel cell, are presented. A heat exchange network is proposed in order to improve the exploitation of the available power. The effect of key variables such as the reformer temperature and the ethanol/water molar feed ratio on the fuel-cell efficiency is discussed. Results show that it is feasible to carry out the energy integration of the hydrogen catalytic production and purification-PEM fuel-cell system, using ethanol as raw material. The technology of "fuel-cell grade" hydrogen production using ethanol as raw material is a very attractive alternative to those technologies based in fossil fuels.

  10. Economics of on-farm production and use of vegetable oils for fuel

    SciTech Connect

    McIntosh, C.S.; Withers, R.V.; Smith, S.M.

    1982-01-01

    The technology of oilseed processing, on a small scale, is much simpler than that for ethanol production. This, coupled with the fact that most energy intensive farm operations use diesel powered equipment, has created substantial interest in vegetable oils as an alternative source of liquid fuel for agriculture. The purpose of this study was to estimate the impact on gross margins resulting from vegetable oil production and utilization in two case study areas, Latah and Power Counties, in Iadho. The results indicate that winter rape oil became a feasible alternative to diesel when the price of diesel reached $0.84 per liter in the Latah County model. A diesel price of $0.85 per liter was required in the Power County model before it became feasible to produce sunflower oil for fuel. 5 tables.

  11. Carbonaceous material for production of hydrogen from low heating value fuel gases

    DOEpatents

    Koutsoukos, Elias P.

    1989-01-01

    A process for the catalytic production of hydrogen, from a wide variety of low heating value fuel gases containing carbon monoxide, comprises circulating a carbonaceous material between two reactors--a carbon deposition reactor and a steaming reactor. In the carbon deposition reactor, carbon monoxide is removed from a fuel gas and is deposited on the carbonaceous material as an active carbon. In the steaming reactor, the reactive carbon reacts with steam to give hydrogen and carbon dioxide. The carbonaceous material contains a metal component comprising from about 75% to about 95% cobalt, from about 5% to about 15% iron, and up to about 10% chromium, and is effective in suppressing the production of methane in the steaming reactor.

  12. Closed circuitry operation influence on microbial electrofermentation: Proton/electron effluxes on electro-fuels productivity.

    PubMed

    Nikhil, G N; Venkata Subhash, G; Yeruva, Dileep Kumar; Venkata Mohan, S

    2015-11-01

    A novel biocatalyzed electrofermentor (BEF) was designed which uncovers the intricate role of biocatalyst involved in cogeneration of electro-fuels (hydrogen and electricity). The specific role of external resistance (Rext, electrical load) on the performance of BEF was evaluated. Four BEFs were operated separately with different resistances (25, 50, 100 and 200 Ω) at an organic load of 5 g/L. Among the tested conditions, external resistance (R3) with 100 Ω revealed maximum power and cumulative H2 production (148 mW and 450 mL, respectively). The competence of closed circuitry comparatively excelled because it facilitates congenial ambiance for the enriched EAB (electroactive bacteria) resulting high rate of metabolic activity that paves way for higher substrate degradation and electro-fuel productivity. Probing of electron kinetics was studied using voltammetric analyses wherein electron transfer by redox proteins was noticed. The designed BEF is found to be sustainable system for harnessing renewable energy through wastewater treatment. PMID:26189780

  13. New oxygen-fuel burner significantly improves electric arc furnace productivity with less energy consumption

    SciTech Connect

    Untz, J.; Knowles, D.

    1984-11-01

    This article describes a new system of electric arc steelmaking based on use of oxygen with newly designed burner for increased productivity and reduced energy consumption. The need for the oxygen-fuel burner has been recognized for years. Because of the shape of the flux lines of the arc between electrodes, some areas receive much more heat than others and consequently melt faster, leaving portions of the furnace charge unmelted for some time. Until these cold areas are melted into the bath, the arcing process must continue in a less efficient mode, delaying the completion of the process and therefore reducing productivity and using more energy. Steelmakers have been looking for a heat source to apply to these cold areas so that all material would melt at the same time. The oxygen-fuel burner was chosen because of its ability to deliver a directed flame at temperatures nearing 5000/sup 0/F.

  14. High Conversion of Coal to Transportation Fuels for the Future With Low HC Gas Production

    SciTech Connect

    Alex G. Oblad; Wendell H. Wiser

    1996-07-01

    An announced objective of the Department of Energy in funding this work, and other current research in coal liquefaction, is to produce a synthetic crude from coal at a cost lower than $30.00 per barrel (Task A). A second objective, reflecting a recent change in direction in the synthetic fuels effort of DOE, is to produce a fuel which is low in aromatics, yet of sufficiently high octane number for use in the gasoline- burning transportation vehicles of today. To meet this second objective, research was proposed, and funding awarded, for conversion of the highly-aromatic liquid product from coal conversion to a product high in isoparaffins, which compounds in the gasoline range exhibit a high octane number (Task B).

  15. Fuel ethanol production from L-arabinose: Constraints, challenges, current status and future trends

    SciTech Connect

    Saha, B.C.; Bothast, R.J.

    1995-12-01

    Interest in fermentation of L-arabinose to ethanol has increased in recent years because corn fiber contains 11% L-arabinose and is available in sufficient quantities to serve as a low cost feedstock to produce fuel ethanol. Various L-arabinose utilizing yeasts were screened for cost feedstock to produce fuel ethanol of their ability to ferment L-arabinose to ethanol. Most yeasts produced L-arabitol instead ethanol. The optimal conditions for production of L-arabitol in high yield from L-arabinose alone, in mixed sugars and in corn fiber acid hydrolyzate by certain yeasts will be described. In addition, the fermentative performance of an ethanologenic recombinant organism on L-arabinose will be discussed. Current status of microbial fermentation of L-arabinose to ethanol, problems and prospects of ethanol production from L-arabinose by yeasts and future directions of research will be reviewed.

  16. Morphology Engineering of Porous Media for Enhanced Solar Fuel and Power Production

    NASA Astrophysics Data System (ADS)

    Suter, Silvan; Haussener, Sophia

    2013-12-01

    The favorable and adjustable transport properties of porous media make them suitable components in reactors used for solar energy conversion and storage processes. The directed engineering of the porous media's morphology can significantly improve the performance of these reactors. We used a multiscale approach to characterize the changes in performance of exemplary solar fuel processing and solar power production reactors incorporating porous media as multifunctional components. The method applied uses imaging-based direct numerical simulations and digital image processing in combination with volume averaging theory to characterize the transport in porous media. Two samples with varying morphology (fibrous vs. foam) and varying size range (mm vs. μm scale), each with porosity between 0.46 and 0.84, were characterized. The obtained effective transport properties were used in continuum-scale models to quantify the performance of reactors incorporating multifunctional porous media for solar fuel processing by photoelectrochemical water splitting or power production by solar thermal processes.

  17. Reduced carbon emission estimates from fossil fuel combustion and cement production in China

    DOE PAGES

    Liu, Z.; Guan, D.; Wei, W.; Davis, S.; Ciais, P.; Bai, J; Peng, S.; Zhang, Q.; Hubacek, K.; Marland, Gregg; et al

    2015-08-19

    Nearly three-quarters of the growth in global carbon emissions from the burning of fossil fuels and cement production between 2010 and 2012 occurred in China. Yet estimates of Chinese emissions remain subject to large uncertainty; inventories of China’s total fossil fuel carbon emissions in 2008 differ by 0.3 gigatonnes of carbon, or 15 per cent. The primary sources of this uncertainty are conflicting estimates of energy consumption and emission factors, the latter being uncertain because of very few actual measurements representative of the mix of Chinese fuels. Here we re-evaluate China’s carbon emissions using updated and harmonized energy consumption andmore » clinker production data and two new and comprehensive sets of measured emission factors for Chinese coal. We find that total energy consumption in China was 10 per cent higher in 2000–2012 than the value reported by China’s national statistics, that emission factors for Chinese coal are on average 40 per cent lower than the default values recommended by the Intergovernmental Panel on Climate Change, and that emissions from China’s cement production are 45 per cent less than recent estimates. Altogether, our revised estimate of China’s CO2 emissions from fossil fuel combustion and cement production is 2.49 gigatonnes of carbon (2 standard deviations = ±7.3 per cent) in 2013, which is 14 per cent lower than the emissions reported by other prominent inventories. Over the full period 2000 to 2013, our revised estimates are 2.9 gigatonnes of carbon less than previous estimates of China’s cumulative carbon emissions. Our findings suggest that overestimation of China’s emissions in 2000–2013 may be larger than China’s estimated total forest sink in 1990–2007 (2.66 gigatonnes of carbon) or China’s land carbon sink in 2000–2009 (2.6 gigatonnes of carbon).« less

  18. Reduced carbon emission estimates from fossil fuel combustion and cement production in China

    SciTech Connect

    Liu, Z.; Guan, D.; Wei, W.; Davis, S.; Ciais, P.; Bai, J; Peng, S.; Zhang, Q.; Hubacek, K.; Marland, Gregg; Andres, Robert Joseph; Crawford-Brown, D.; Lin, J.; Zhao, H.; Hong, C.; Boden, Thomas A.; Feng, K.; Peters, Glen P.; Xi, F.; Liu, J.; Li, Y.; Zhao, Y.; Zeng, Ning; He, K.

    2015-08-19

    Nearly three-quarters of the growth in global carbon emissions from the burning of fossil fuels and cement production between 2010 and 2012 occurred in China. Yet estimates of Chinese emissions remain subject to large uncertainty; inventories of China’s total fossil fuel carbon emissions in 2008 differ by 0.3 gigatonnes of carbon, or 15 per cent. The primary sources of this uncertainty are conflicting estimates of energy consumption and emission factors, the latter being uncertain because of very few actual measurements representative of the mix of Chinese fuels. Here we re-evaluate China’s carbon emissions using updated and harmonized energy consumption and clinker production data and two new and comprehensive sets of measured emission factors for Chinese coal. We find that total energy consumption in China was 10 per cent higher in 2000–2012 than the value reported by China’s national statistics, that emission factors for Chinese coal are on average 40 per cent lower than the default values recommended by the Intergovernmental Panel on Climate Change, and that emissions from China’s cement production are 45 per cent less than recent estimates. Altogether, our revised estimate of China’s CO2 emissions from fossil fuel combustion and cement production is 2.49 gigatonnes of carbon (2 standard deviations = ±7.3 per cent) in 2013, which is 14 per cent lower than the emissions reported by other prominent inventories. Over the full period 2000 to 2013, our revised estimates are 2.9 gigatonnes of carbon less than previous estimates of China’s cumulative carbon emissions. Our findings suggest that overestimation of China’s emissions in 2000–2013 may be larger than China’s estimated total forest sink in 1990–2007 (2.66 gigatonnes of carbon) or China’s land carbon sink in 2000–2009 (2.6 gigatonnes of carbon).

  19. Molten carbonate fuel cell product development test environmental assessment/protection plan

    SciTech Connect

    Not Available

    1992-11-01

    Objective of proposed action is to conduct a 250-kW product development test of M-C Power Corporation`s molten carbonate fuel cell concept, at the Kaiser Permanente San Diego Medical Center. Review of environmental impacts of this test indicate the following: no impact on solid waste disposal, water quality, noise levels, floodplains, wetlands, ecology, historic areas, or socioeconomic resources. Impact on air quality are expected to be positive.

  20. Molten carbonate fuel cell product development test environmental assessment/protection plan

    SciTech Connect

    Brunton, Jack; Furukawa, Vance; Frost, Grant; Danna, Mike; Figueroa, Al; Scroppo, Joseph

    1992-11-01

    Objective of proposed action is to conduct a 250-kW product development test of M-C Power Corporation's molten carbonate fuel cell concept, at the Kaiser Permanente San Diego Medical Center. Review of environmental impacts of this test indicate the following: no impact on solid waste disposal, water quality, noise levels, floodplains, wetlands, ecology, historic areas, or socioeconomic resources. Impact on air quality are expected to be positive.

  1. Reduced carbon emission estimates from fossil fuel combustion and cement production in China.

    PubMed

    Liu, Zhu; Guan, Dabo; Wei, Wei; Davis, Steven J; Ciais, Philippe; Bai, Jin; Peng, Shushi; Zhang, Qiang; Hubacek, Klaus; Marland, Gregg; Andres, Robert J; Crawford-Brown, Douglas; Lin, Jintai; Zhao, Hongyan; Hong, Chaopeng; Boden, Thomas A; Feng, Kuishuang; Peters, Glen P; Xi, Fengming; Liu, Junguo; Li, Yuan; Zhao, Yu; Zeng, Ning; He, Kebin

    2015-08-20

    Nearly three-quarters of the growth in global carbon emissions from the burning of fossil fuels and cement production between 2010 and 2012 occurred in China. Yet estimates of Chinese emissions remain subject to large uncertainty; inventories of China's total fossil fuel carbon emissions in 2008 differ by 0.3 gigatonnes of carbon, or 15 per cent. The primary sources of this uncertainty are conflicting estimates of energy consumption and emission factors, the latter being uncertain because of very few actual measurements representative of the mix of Chinese fuels. Here we re-evaluate China's carbon emissions using updated and harmonized energy consumption and clinker production data and two new and comprehensive sets of measured emission factors for Chinese coal. We find that total energy consumption in China was 10 per cent higher in 2000-2012 than the value reported by China's national statistics, that emission factors for Chinese coal are on average 40 per cent lower than the default values recommended by the Intergovernmental Panel on Climate Change, and that emissions from China's cement production are 45 per cent less than recent estimates. Altogether, our revised estimate of China's CO2 emissions from fossil fuel combustion and cement production is 2.49 gigatonnes of carbon (2 standard deviations = ±7.3 per cent) in 2013, which is 14 per cent lower than the emissions reported by other prominent inventories. Over the full period 2000 to 2013, our revised estimates are 2.9 gigatonnes of carbon less than previous estimates of China's cumulative carbon emissions. Our findings suggest that overestimation of China's emissions in 2000-2013 may be larger than China's estimated total forest sink in 1990-2007 (2.66 gigatonnes of carbon) or China's land carbon sink in 2000-2009 (2.6 gigatonnes of carbon). PMID:26289204

  2. Computer model for refinery operations with emphasis on jet fuel production. Volume 1: Program description

    NASA Technical Reports Server (NTRS)

    Dunbar, D. N.; Tunnah, B. G.

    1978-01-01

    A FORTRAN computer program is described for predicting the flow streams and material, energy, and economic balances of a typical petroleum refinery, with particular emphasis on production of aviation turbine fuel of varying end point and hydrogen content specifications. The program has provision for shale oil and coal oil in addition to petroleum crudes. A case study feature permits dependent cases to be run for parametric or optimization studies by input of only the variables which are changed from the base case.

  3. Reduced carbon emission estimates from fossil fuel combustion and cement production in China.

    PubMed

    Liu, Zhu; Guan, Dabo; Wei, Wei; Davis, Steven J; Ciais, Philippe; Bai, Jin; Peng, Shushi; Zhang, Qiang; Hubacek, Klaus; Marland, Gregg; Andres, Robert J; Crawford-Brown, Douglas; Lin, Jintai; Zhao, Hongyan; Hong, Chaopeng; Boden, Thomas A; Feng, Kuishuang; Peters, Glen P; Xi, Fengming; Liu, Junguo; Li, Yuan; Zhao, Yu; Zeng, Ning; He, Kebin

    2015-08-20

    Nearly three-quarters of the growth in global carbon emissions from the burning of fossil fuels and cement production between 2010 and 2012 occurred in China. Yet estimates of Chinese emissions remain subject to large uncertainty; inventories of China's total fossil fuel carbon emissions in 2008 differ by 0.3 gigatonnes of carbon, or 15 per cent. The primary sources of this uncertainty are conflicting estimates of energy consumption and emission factors, the latter being uncertain because of very few actual measurements representative of the mix of Chinese fuels. Here we re-evaluate China's carbon emissions using updated and harmonized energy consumption and clinker production data and two new and comprehensive sets of measured emission factors for Chinese coal. We find that total energy consumption in China was 10 per cent higher in 2000-2012 than the value reported by China's national statistics, that emission factors for Chinese coal are on average 40 per cent lower than the default values recommended by the Intergovernmental Panel on Climate Change, and that emissions from China's cement production are 45 per cent less than recent estimates. Altogether, our revised estimate of China's CO2 emissions from fossil fuel combustion and cement production is 2.49 gigatonnes of carbon (2 standard deviations = ±7.3 per cent) in 2013, which is 14 per cent lower than the emissions reported by other prominent inventories. Over the full period 2000 to 2013, our revised estimates are 2.9 gigatonnes of carbon less than previous estimates of China's cumulative carbon emissions. Our findings suggest that overestimation of China's emissions in 2000-2013 may be larger than China's estimated total forest sink in 1990-2007 (2.66 gigatonnes of carbon) or China's land carbon sink in 2000-2009 (2.6 gigatonnes of carbon).

  4. [Trend of "zero energy consumption and wastewater" in fuel ethanol production].

    PubMed

    Mao, Zhonggui; Zhang, Jianhua

    2008-06-01

    The energy consumption in a Chinese ethanol manufacturer with cassava as the feedstock, has been reduced to a zero-closed level. If the R & D on technical integration of high ethanol concentration fermentation, methane fermentation technique, steam and electricity co-generation system, new distillation technology, and the wastewater reutilization, is carried out continuously, the proposed "zero energy consumption and wastewater" technique could be realized in fuel ethanol production process.

  5. Reduced carbon emission estimates from fossil fuel combustion and cement production in China

    NASA Astrophysics Data System (ADS)

    Liu, Zhu; Guan, Dabo; Wei, Wei; Davis, Steven J.; Ciais, Philippe; Bai, Jin; Peng, Shushi; Zhang, Qiang; Hubacek, Klaus; Marland, Gregg; Andres, Robert J.; Crawford-Brown, Douglas; Lin, Jintai; Zhao, Hongyan; Hong, Chaopeng; Boden, Thomas A.; Feng, Kuishuang; Peters, Glen P.; Xi, Fengming; Liu, Junguo; Li, Yuan; Zhao, Yu; Zeng, Ning; He, Kebin

    2015-08-01

    Nearly three-quarters of the growth in global carbon emissions from the burning of fossil fuels and cement production between 2010 and 2012 occurred in China. Yet estimates of Chinese emissions remain subject to large uncertainty; inventories of China's total fossil fuel carbon emissions in 2008 differ by 0.3 gigatonnes of carbon, or 15 per cent. The primary sources of this uncertainty are conflicting estimates of energy consumption and emission factors, the latter being uncertain because of very few actual measurements representative of the mix of Chinese fuels. Here we re-evaluate China's carbon emissions using updated and harmonized energy consumption and clinker production data and two new and comprehensive sets of measured emission factors for Chinese coal. We find that total energy consumption in China was 10 per cent higher in 2000-2012 than the value reported by China's national statistics, that emission factors for Chinese coal are on average 40 per cent lower than the default values recommended by the Intergovernmental Panel on Climate Change, and that emissions from China's cement production are 45 per cent less than recent estimates. Altogether, our revised estimate of China's CO2 emissions from fossil fuel combustion and cement production is 2.49 gigatonnes of carbon (2 standard deviations = +/-7.3 per cent) in 2013, which is 14 per cent lower than the emissions reported by other prominent inventories. Over the full period 2000 to 2013, our revised estimates are 2.9 gigatonnes of carbon less than previous estimates of China's cumulative carbon emissions. Our findings suggest that overestimation of China's emissions in 2000-2013 may be larger than China's estimated total forest sink in 1990-2007 (2.66 gigatonnes of carbon) or China's land carbon sink in 2000-2009 (2.6 gigatonnes of carbon).

  6. Bio-based production of chemicals, materials and fuels -Corynebacterium glutamicum as versatile cell factory.

    PubMed

    Becker, Judith; Wittmann, Christoph

    2012-08-01

    Since their discovery almost 60 years ago, Corynebacterium glutamicum and related subspecies are writing a remarkable success story in industrial biotechnology. Today, these gram-positive soil bacteria, traditionally well-known as excellent producers of L-amino acids are becoming flexible, efficient production platforms for various chemicals, materials and fuels. This development is intensively driven by systems metabolic engineering concepts integrating systems biology and synthetic biology into strain engineering.

  7. Biological Production of a Hydrocarbon Fuel Intermediate Polyhydroxybutyrate (Phb) from a Process Relevant Lignocellulosic Derived Sugar

    SciTech Connect

    Wang, Wei; Mohagheghi, Ali; Mittal, Ashutosh; Pilath, Heidi; Johnson, David K.

    2015-03-22

    PHAs are synthesized by many microorganisms to serve as intracellular carbon storage molecules. In some bacterial strains, PHB can account for up to 80% of cell mass. In addition to its application in the packaging sector, PHB also has great potential as an intermediate in the production of hydrocarbon fuels. PHB can be thermally depolymerized and decarboxylated to propene which can be upgraded to hydrocarbon fuels via commercial oligomerization technologies. In recent years a great effort has been made in bacterial production of PHB, yet the production cost of the polymer is still much higher than conventional petrochemical plastics. The high cost of PHB is because the cost of the substrates can account for as much as half of the total product cost in large scale fermentation. Thus searching for cheaper and better substrates is very necessary for PHB production. In this study, we demonstrate production of PHB by Cupriavidus necator from a process relevant lignocellulosic derived sugar stream, i.e., saccharified hydrolysate slurry from pretreated corn stover. Good cell growth was observed on slurry saccharified with advanced enzymes and 40~60% of PHB was accumulated in the cells. The mechanism of inhibition in the toxic hydrolysate generated by pretreatment and saccharification of biomass, will be discussed.

  8. Production and fuel characteristics of vegetable oil from oilseed crops in the Pacific Northwest

    SciTech Connect

    Auld, D.L.; Bettis, B.L.; Peterson, C.L.

    1982-01-01

    The purpose of this research was to evaluate the potential yield and fuel quality of various oilseed crops adapted to the Pacific Northwest as a source of liquid fuel for diesel engines. The seed yield and oil production of three cultivars of winter rape (Brassica napus L.), two cultivars of safflower (Carthamus tinctorius L.) and two cultivars of sunflower (Helianthus annuus L.) were evaluated in replicated plots at Moscow. Additional trials were conducted at several locations in Idaho, Oregon and Washington. Sunflower, oleic and linoleic safflower, and low and high erucic acid rapeseed were evaluated for fatty acid composition, energy content, viscosity and engine performance in short term tests. During 20 minute engine tests power output, fuel economy and thermal efficiency were compared to diesel fuel. Winter rape produced over twice as much farm extractable oil as either safflower or sunflower. The winter rape cultivars, Norde and Jet Neuf had oil yields which averaged 1740 and 1540 L/ha, respectively. Vegetable oils contained 94 to 95% of the KJ/L of diesel fuel, but were 11.1 to 17.6 times more viscous. Viscosity of the vegetable oils was closely related to fatty acid chain length and number of unsaturated bonds (R/sup 2/=.99). During short term engine tests all vegetable oils produced power outputs equivalent to diesel, and had thermal efficiencies 1.8 to 2.8% higher than diesel. Based on these results it appears that species and cultivars of oilseed crops to be utilized as a source of fuel should be selected on the basis of oil yield. 1 figure, 5 tables.

  9. Technological Alternatives or Use of Wood Fuel in Combined Heat and Power Production

    NASA Astrophysics Data System (ADS)

    Rusanova, Jekaterina; Markova, Darja; Bazbauers, Gatis; Valters, Kārlis

    2013-12-01

    Abstract Latvia aims for 40% share of renewable energy in the total final energy use. Latvia has large resources of biomass and developed district heating systems. Therefore, use of biomass for heat and power production is an economically attractive path for increase of the share of renewable energy. The optimum technological solution for use of biomass and required fuel resources have to be identified for energy planning and policy purposes. The aim of this study was to compare several wood fuel based energy conversion technologies from the technical and economical point of view. Three biomass conversion technologies for combined heat and electricity production (CHP) were analyzed: • CHP with steam turbine technology; • gasification CHP using gas engine; • bio-methane combined cycle CHP. Electricity prices for each alternative are presented. The results show the level of support needed for the analyzed renewable energy technologies and time period needed to reach price parity with the natural gas - fired combined cycle gas turbine (CCGT) CHPss. The results also show that bio-methane technology is most competitive when compared with CCGT among the considered technologies regarding fuel consumption and electricity production, but it is necessary to reduce investment costs to reach the electricity price parity with the natural gas CCGT.

  10. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect

    Gerald P. Huffman

    2003-09-30

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. These feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. Some highlights of the results obtained during the first year of the current research contract are summarized as: (1) Terminal alkynes are an effective chain initiator for Fischer-Tropsch (FT) reactions, producing normal paraffins with C numbers {ge} to that of the added alkyne. (2) Significant improvement in the product distribution towards heavier hydrocarbons (C{sub 5} to C{sub 19}) was achieved in supercritical fluid (SCF) FT reactions compared to that of gas-phase reactions. (3) Xerogel and aerogel silica supported cobalt catalysts were successfully employed for FT synthesis. Selectivity for diesel range products increased with increasing Co content. (4) Silicoaluminophosphate (SAPO) molecular sieve catalysts have been developed for methanol to olefin conversion, producing value-added products such as ethylene and propylene. (5) Hybrid Pt-promoted tungstated and sulfated zirconia catalysts are very effective in cracking n-C{sub 36} to jet and diesel fuel; these catalysts will be tested for cracking of FT wax. (6) Methane, ethane, and propane are readily decomposed to pure

  11. Transportation Energy Futures Series: Alternative Fuel Infrastructure Expansion: Costs, Resources, Production Capacity, and Retail Availability for Low-Carbon Scenarios

    SciTech Connect

    Melaina, M. W.; Heath, G.; Sandor, D.; Steward, D.; Vimmerstedt, L.; Warner, E.; Webster, K. W.

    2013-04-01

    Achieving the Department of Energy target of an 80% reduction in greenhouse gas emissions by 2050 depends on transportation-related strategies combining technology innovation, market adoption, and changes in consumer behavior. This study examines expanding low-carbon transportation fuel infrastructure to achieve deep GHG emissions reductions, with an emphasis on fuel production facilities and retail components serving light-duty vehicles. Three distinct low-carbon fuel supply scenarios are examined: Portfolio: Successful deployment of a range of advanced vehicle and fuel technologies; Combustion: Market dominance by hybridized internal combustion engine vehicles fueled by advanced biofuels and natural gas; Electrification: Market dominance by electric drive vehicles in the LDV sector, including battery electric, plug-in hybrid, and fuel cell vehicles, that are fueled by low-carbon electricity and hydrogen. A range of possible low-carbon fuel demand outcomes are explored in terms of the scale and scope of infrastructure expansion requirements and evaluated based on fuel costs, energy resource utilization, fuel production infrastructure expansion, and retail infrastructure expansion for LDVs. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored transportation-related strategies for abating GHGs and reducing petroleum dependence.

  12. Characterization of uranium corrosion products involved in the March 13, 1998 fuel manufacturing facility pyrophoric event.

    SciTech Connect

    Totemeier, T.C.

    1999-04-26

    Uranium metal corrosion products from ZPPR fuel plates involved in the March 13, 1998 pyrophoric event in the Fuel Manufacturing Facility at Argonne National Laboratory-West were characterized using thermo-gravimetric analysis, X-ray diffraction, and BET gas sorption techniques. Characterization was performed on corrosion products in several different conditions: immediately after separation from the source metal, after low-temperature passivation, after passivation and extended vault storage, and after burning in the pyrophoric event. The ignition temperatures and hydride fractions of the corrosion product were strongly dependent on corrosion extent. Corrosion products from plates with corrosion extents less than 0.7% did not ignite in TGA testing, while products from plates with corrosion extents greater than 1.2% consistently ignited. Corrosion extent is defined as mass of corrosion products divided by the total mass of uranium. The hydride fraction increased with corrosion extent. There was little change in corrosion product properties after low-temperature passivation or vault storage. The burned products were not reactive and contained no hydride; the principal constituents were UO{sub 2} and U{sub 3}O{sub 7}. The source of the event was a considerable quantity of reactive hydride present in the corrosion products. No specific ignition mechanism could be conclusively identified. The most likely initiator was a static discharge in the corrosion product from the 14th can as it was poured into the consolidation can. The available evidence does not support scenarios in which the powder in the consolidation can slowly self-heated to the ignition point, or in which the powder in the 14th can was improperly passivated.

  13. EXPERIMENTAL STUDY OF THE NEW BIOCATALYST METHOD FOR BIODIESEL-FUEL BASED ON THE LIPASE PRODUCTION FUNGUS

    NASA Astrophysics Data System (ADS)

    Hata, Toshiro; Shimada, Miki; Toida, Jinichi

    This paper describes how to develop and evaluate a new biocatalyst method for biodiesel fuel based on the lipase production fungus. This method can convert waste vegetable oil into biodiesel fuel without alkaline waste fluid and byproducts (gly cerine). The main outcomes of this research were: (1) The biodiesel fuel can be manufactured from lipase production fungus (Rhizupus oryzae NBRC 9364). (2) The lipase activity can be enhanced by adding glucose and oil. (3) Phased addition of the methanol enhances the conversion rate of the biodiesel fuel (Maximum conversion rate is 85%). (4) The proposed method can improve vehicle exhaust emission and reduce byproducts (glycerine). We concluded that our proposed methods are effective for the production of biodiesel fuel from waste vegetable oil.

  14. Dual-fuel production from restaurant grease trap waste: bio-fuel oil extraction and anaerobic methane production from the post-extracted residue.

    PubMed

    Kobayashi, Takuro; Kuramochi, Hidetoshi; Maeda, Kouji; Tsuji, Tomoya; Xu, Kaiqin

    2014-10-01

    An effective way for restaurant grease trap waste (GTW) treatment to generate fuel oil and methane by the combination of physiological and biological processes was investigated. The heat-driven extraction could provide a high purity oil equivalent to an A-grade fuel oil of Japanese industrial standard with 81-93 wt% of extraction efficiency. A post-extracted residue was treated as an anaerobic digestion feedstock, and however, an inhibitory effect of long chain fatty acid (LCFA) was still a barrier for high-rate digestion. From the semi-continuous experiment fed with the residual sludge as a single substrate, it can be concluded that the continuous addition of calcium into the reactor contributed to reducing LCFA inhibition, resulting in the long-term stable operation over one year. Furthermore, the anaerobic reactor performed well with 70-80% of COD reduction and methane productivity under an organic loading rate up to 5.3g-COD/L/d. PMID:25043346

  15. Dual-fuel production from restaurant grease trap waste: bio-fuel oil extraction and anaerobic methane production from the post-extracted residue.

    PubMed

    Kobayashi, Takuro; Kuramochi, Hidetoshi; Maeda, Kouji; Tsuji, Tomoya; Xu, Kaiqin

    2014-10-01

    An effective way for restaurant grease trap waste (GTW) treatment to generate fuel oil and methane by the combination of physiological and biological processes was investigated. The heat-driven extraction could provide a high purity oil equivalent to an A-grade fuel oil of Japanese industrial standard with 81-93 wt% of extraction efficiency. A post-extracted residue was treated as an anaerobic digestion feedstock, and however, an inhibitory effect of long chain fatty acid (LCFA) was still a barrier for high-rate digestion. From the semi-continuous experiment fed with the residual sludge as a single substrate, it can be concluded that the continuous addition of calcium into the reactor contributed to reducing LCFA inhibition, resulting in the long-term stable operation over one year. Furthermore, the anaerobic reactor performed well with 70-80% of COD reduction and methane productivity under an organic loading rate up to 5.3g-COD/L/d.

  16. Production of liquid fuels with a high-temperature gas-cooled reactor

    NASA Astrophysics Data System (ADS)

    Quade, R. N.; Vrable, D. L.; Green, L., Jr.

    An exploration is made of the technical, economic and environmental impact feasibility of integrating coal liquefaction methods directly and indirectly with a nuclear reactor source of process heat, with stress on the production of synthetic jet fuel. Production figures and operating costs are compared for indirect conventional and nuclear processes using Lurgi-Fischer-Tropsch technology with direct conventional and nuclear techniques employing the advanced SRC-II technology, and it is concluded that significant advantages in coal savings and environmental impact can be expected from nuclear reactor integration.

  17. Chemical forms of solid fission products in the irradiated uranium—plutonium mixed nitride fuel

    NASA Astrophysics Data System (ADS)

    Arai, Yasuo; Maeda, Atsushi; Shiozawa, Ken-ichi; Ohmichi, Toshihiko

    1994-06-01

    Chemical forms of solid fission products in the irradiated (U, Pu)N fuel were estimated by both thermodynamic equilibrium calculation and electron microprobe analysis on burnup simulated samples prepared by carbothermic reduction. Besides the MX type matrix phase dissolving zirconium, niobium, yttrium and rare earth elements, the existence of two kinds of inclusion was recognized. One is URu 3 type intermetallic compound constituted by uranium and platinum group elements. The other is an alloy containing molybdenum as a principal constituent. Furthermore, the swelling rate due to solid fission products precipitation was evaluated to be about 0.5% per %FIMA.

  18. Techno-economic comparison of biojet fuel production from lignocellulose, vegetable oil and sugar cane juice.

    PubMed

    Diederichs, Gabriel Wilhelm; Ali Mandegari, Mohsen; Farzad, Somayeh; Görgens, Johann F

    2016-09-01

    In this study, a techno-economic comparison was performed considering three processes (thermochemical, biochemical and hybrid) for production of jet fuel from lignocellulosic biomass (2G) versus two processes from first generation (1G) feedstocks, including vegetable oil and sugar cane juice. Mass and energy balances were constructed for energy self-sufficient versions of these processes, not utilising any fossil energy sources, using ASPEN Plus® simulations. All of the investigated processes obtained base minimum jet selling prices (MJSP) that is substantially higher than the market jet fuel price (2-4 fold). The 1G process which converts vegetable oil, obtained the lowest MJSPs of $2.22/kg jet fuel while the two most promising 2G processes- the thermochemical (gasification and Fischer-Tropsch synthesis) and hybrid (gasification and biochemical upgrading) processes- reached MJSPs of $2.44/kg and $2.50/kg jet fuel, respectively. According to the economic sensitivity analysis, the feedstock cost and fixed capital investment have the most influence on the MJSP. PMID:27259188

  19. Accelerator Reactor Coupling for Energy Production in Advanced Nuclear Fuel Cycles

    DOE PAGES

    Brown, Nicholas R.; Heidet, Florent; Haj Tahar, Malek

    2016-01-01

    This article is a review of several accelerator–reactor interface issues and nuclear fuel cycle applications of acceleratordriven subcritical systems. The systems considered here have the primary goal of energy production, but that goal is accomplished via a specific application in various proposed nuclear fuel cycles, such as breed-and-burn of fertile material or burning of transuranic material. Several basic principles are reviewed, starting from the proton beam window including the target, blanket, reactor core, and up to the fuel cycle. We focus on issues of interest, such as the impact of the energy required to run the accelerator and associated systemsmore » on the potential electricity delivered to the grid. Accelerator-driven systems feature many of the constraints and issues associated with critical reactors, with the added challenges of subcritical operation and coupling to an accelerator. Reliable accelerator operation and avoidance of beam trips are critically important. One interesting challenge is measurement of blanket subcriticality level during operation. We also review the potential benefits of accelerator-driven systems in various nuclear fuel cycle applications. Ultimately, accelerator-driven subcritical systems with the goal of transmutation of transuranic material have lower 100,000-year radioactivity than a critical fast reactor with recycling of uranium and plutonium.« less

  20. Accelerator Reactor Coupling for Energy Production in Advanced Nuclear Fuel Cycles

    SciTech Connect

    Brown, Nicholas R.; Heidet, Florent; Haj Tahar, Malek

    2016-01-01

    This article is a review of several accelerator–reactor interface issues and nuclear fuel cycle applications of acceleratordriven subcritical systems. The systems considered here have the primary goal of energy production, but that goal is accomplished via a specific application in various proposed nuclear fuel cycles, such as breed-and-burn of fertile material or burning of transuranic material. Several basic principles are reviewed, starting from the proton beam window including the target, blanket, reactor core, and up to the fuel cycle. We focus on issues of interest, such as the impact of the energy required to run the accelerator and associated systems on the potential electricity delivered to the grid. Accelerator-driven systems feature many of the constraints and issues associated with critical reactors, with the added challenges of subcritical operation and coupling to an accelerator. Reliable accelerator operation and avoidance of beam trips are critically important. One interesting challenge is measurement of blanket subcriticality level during operation. We also review the potential benefits of accelerator-driven systems in various nuclear fuel cycle applications. Ultimately, accelerator-driven subcritical systems with the goal of transmutation of transuranic material have lower 100,000-year radioactivity than a critical fast reactor with recycling of uranium and plutonium.

  1. Techno-economic comparison of biojet fuel production from lignocellulose, vegetable oil and sugar cane juice.

    PubMed

    Diederichs, Gabriel Wilhelm; Ali Mandegari, Mohsen; Farzad, Somayeh; Görgens, Johann F

    2016-09-01

    In this study, a techno-economic comparison was performed considering three processes (thermochemical, biochemical and hybrid) for production of jet fuel from lignocellulosic biomass (2G) versus two processes from first generation (1G) feedstocks, including vegetable oil and sugar cane juice. Mass and energy balances were constructed for energy self-sufficient versions of these processes, not utilising any fossil energy sources, using ASPEN Plus® simulations. All of the investigated processes obtained base minimum jet selling prices (MJSP) that is substantially higher than the market jet fuel price (2-4 fold). The 1G process which converts vegetable oil, obtained the lowest MJSPs of $2.22/kg jet fuel while the two most promising 2G processes- the thermochemical (gasification and Fischer-Tropsch synthesis) and hybrid (gasification and biochemical upgrading) processes- reached MJSPs of $2.44/kg and $2.50/kg jet fuel, respectively. According to the economic sensitivity analysis, the feedstock cost and fixed capital investment have the most influence on the MJSP.

  2. Electricity production from and biodegradation of quinoline in the microbial fuel cell.

    PubMed

    Zhang, Cuiping; Liu, Guangli; Zhang, Renduo; Luo, Haiping

    2010-01-01

    Quinoline has become one of the common contaminants in groundwater and soil, discharged from the process of coal tar distillation and creosote wood preservation, as well as fossil fuel facilities. The aim of this study was to investigate the feasibility of electricity production from and biodegradation of quinoline in the microbial fuel cell (MFC). Experiments were conducted in the MFC using an initial 500 mg/L quinoline with different glucose concentrations as substrates. Results showed maximum voltages of 558, 469, and 328 mV for the substrates with ratios of quinoline to glucose of 1:1, 5:3, 5:1, respectively. The MFC accomplished complete quinoline biodegradation within 6 h. Experiments were then conducted using 200 mg/L quinoline only as the MFC fuel, resulting in the maximal voltage of 145 mV and maximal power density of 16.4 mW/m(2). GC/MS analyses showed that 2(1H)quinolinone accumulated in the anode solution and later disappeared. The results clearly demonstrated the feasibility to use quinoline as the MFC fuel to generate electricity and enhance quinoline biodegradation simultaneously.

  3. Accelerator-Reactor Coupling for Energy Production in Advanced Nuclear Fuel Cycles

    NASA Astrophysics Data System (ADS)

    Heidet, Florent; Brown, Nicholas R.; Haj Tahar, Malek

    This article is a review of several accelerator-reactor interface issues and nuclear fuel cycle applications of accelerator-driven subcritical systems. The systems considered here have the primary goal of energy production, but that goal is accomplished via a specific application in various proposed nuclear fuel cycles, such as breed-and-burn of fertile material or burning of transuranic material. Several basic principles are reviewed, starting from the proton beam window including the target, blanket, reactor core, and up to the fuel cycle. We focus on issues of interest, such as the impact of the energy required to run the accelerator and associated systems on the potential electricity delivered to the grid. Accelerator-driven systems feature many of the constraints and issues associated with critical reactors, with the added challenges of subcritical operation and coupling to an accelerator. Reliable accelerator operation and avoidance of beam trips are critically important. One interesting challenge is measurement of blanket subcriticality level during operation. We also review the potential benefits of accelerator-driven systems in various nuclear fuel cycle applications. Ultimately, accelerator-driven subcritical systems with the goal of transmutation of transuranic material have lower 100,000-year radioactivity than a critical fast reactor with recycling of uranium and plutonium.

  4. LIQUID BIO-FUEL PRODUCTION FROM NON-FOOD BIOMASS VIA HIGH TEMPERATURE STEAM ELECTROLYSIS

    SciTech Connect

    G. L. Hawkes; J. E. O'Brien; M. G. McKellar

    2011-11-01

    Bio-Syntrolysis is a hybrid energy process that enables production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), bio-syntrolysis has the potential to provide a significant alternative petroleum source that could reduce US dependence on imported oil. Combining hydrogen from HTSE with CO from an oxygen-blown biomass gasifier yields syngas to be used as a feedstock for synthesis of liquid transportation fuels via a Fischer-Tropsch process. Conversion of syngas to liquid hydrocarbon fuels, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-blown biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power

  5. Combined energy production and waste management in manned spacecraft utilizing on-demand hydrogen production and fuel cells

    NASA Astrophysics Data System (ADS)

    Elitzur, Shani; Rosenband, Valery; Gany, Alon

    2016-11-01

    Energy supply and waste management are among the most significant challenges in human spacecraft. Great efforts are invested in managing solid waste, recycling grey water and urine, cleaning the atmosphere, removing CO2, generating and saving energy, and making further use of components and products. This paper describes and investigates a concept for managing waste water and urine to simultaneously produce electric and heat energies as well as fresh water. It utilizes an original technique for aluminum activation to react spontaneously with water at room temperature to produce hydrogen on-site and on-demand. This reaction has further been proven to be effective also when using waste water and urine. Applying the hydrogen produced in a fuel cell, one obtains electric energy as well as fresh (drinking) water. The method was compared to the traditional energy production technology of the Space Shuttle, which is based on storing the fuel cell reactants, hydrogen and oxygen, in cryogenic tanks. It is shown that the alternative concept presented here may provide improved safety, compactness (reduction of more than one half of the volume of the hydrogen storage system), and management of waste liquids for energy generation and drinking water production. Nevertheless, it adds mass compared to the cryogenic hydrogen technology. It is concluded that the proposed method may be used as an emergency and backup power system as well as an additional hydrogen source for extended missions in human spacecraft.

  6. Short and long-term carbon balance of bioenergy electricity production fueled by forest treatments

    PubMed Central

    2014-01-01

    Background Forests store large amounts of carbon in forest biomass, and this carbon can be released to the atmosphere following forest disturbance or management. In the western US, forest fuel reduction treatments designed to reduce the risk of high severity wildfire can change forest carbon balance by removing carbon in the form of biomass, and by altering future potential wildfire behavior in the treated stand. Forest treatment carbon balance is further affected by the fate of this biomass removed from the forest, and the occurrence and intensity of a future wildfire in this stand. In this study we investigate the carbon balance of a forest treatment with varying fates of harvested biomass, including use for bioenergy electricity production, and under varying scenarios of future disturbance and regeneration. Results Bioenergy is a carbon intensive energy source; in our study we find that carbon emissions from bioenergy electricity production are nearly twice that of coal for the same amount of electricity. However, some emissions from bioenergy electricity production are offset by avoided fossil fuel electricity emissions. The carbon benefit achieved by using harvested biomass for bioenergy electricity production may be increased through avoided pyrogenic emissions if the forest treatment can effectively reduce severity. Conclusion Forest treatments with the use of harvested biomass for electricity generation can reduce carbon emissions to the atmosphere by offsetting fossil fuel electricity generation emissions, and potentially by avoided pyrogenic emissions due to reduced intensity and severity of a future wildfire in the treated stand. However, changes in future wildfire and regeneration regimes may affect forest carbon balance and these climate-induced changes may influence forest carbon balance as much, or more, than bioenergy production. PMID:25187788

  7. System and process for the production of syngas and fuel gasses

    DOEpatents

    Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M; Benefiel, Bradley C

    2015-04-21

    The production of gasses and, more particularly, to systems and methods for the production of syngas and fuel gasses including the production of hydrogen are set forth. In one embodiment system and method includes a reactor having a molten pool of a material comprising sodium carbonate. A supply of conditioned water is in communication with the reactor. A supply of carbon containing material is also in communication with the reactor. In one particular embodiment, the carbon containing material may include vacuum residuum (VR). The water and VR may be kept at desired temperatures and pressures compatible with the process that is to take place in the reactor. When introduced into the reactor, the water, the VR and the molten pool may be homogenously mixed in an environment in which chemical reactions take place including the production of hydrogen and other gasses.

  8. An alternative feedstock of corn meal for industrial fuel ethanol production: delignified corncob residue.

    PubMed

    Lei, Cheng; Zhang, Jian; Xiao, Lin; Bao, Jie

    2014-09-01

    Delignified corncob residue is an industrial solid waste from xylose production using corncob as feedstock. In this study, delignified corncob residue was used as the feedstock of ethanol production by simultaneous saccharification and fermentation (SSF) and the optimal fermentation performance was investigated under various operation conditions. The ethanol titer and yield reached 75.07 g/L and 89.38%, respectively, using a regular industrial yeast strain at moderate cellulase dosage and high solids loading. A uniform SSF temperature of 37°C at both prehydrolysis and SSF stages was tested. The fermentation performance and cost of delignified corncob residue and corn meal was compared as feedstock of ethanol fermentation. The result shows that the delignified corncob residue is competitive to corn meal as ethanol production feedstock. The study gives a typical case to demonstrate the potential of intensively processed lignocellulose as the alternative feedstock of corn meal for industrial fuel ethanol production.

  9. Mechanisms of yeast stress tolerance and its manipulation for efficient fuel ethanol production.

    PubMed

    Zhao, X Q; Bai, F W

    2009-10-12

    Yeast strains of Saccharomyces cerevisiae have been extensively studied in recent years for fuel ethanol production, in which yeast cells are exposed to various stresses such as high temperature, ethanol inhibition, and osmotic pressure from product and substrate sugars as well as the inhibitory substances released from the pretreatment of lignocellulosic biomass. An in-depth understanding of the mechanism of yeast stress tolerance contributes to breeding more robust strains for ethanol production, especially under very high gravity conditions. Taking advantage of the "omics" technology, the stress response and defense mechanism of yeast cells during ethanol fermentation were further explored, and the newly emerged tools such as genome shuffling and global transcription machinery engineering have been applied to breed stress resistant yeast strains for ethanol production. In this review, the latest development of stress tolerance mechanisms was focused, and improvement of yeast stress tolerance by both random and rational tools was presented.

  10. System and process for the production of syngas and fuel gasses

    DOEpatents

    Bingham, Dennis N; Kllingler, Kerry M; Turner, Terry D; Wilding, Bruce M; Benefiel, Bradley C

    2014-04-01

    The production of gasses and, more particularly, to systems and methods for the production of syngas and fuel gasses including the production of hydrogen are set forth. In one embodiment system and method includes a reactor having a molten pool of a material comprising sodium carbonate. A supply of conditioned water is in communication with the reactor. A supply of carbon containing material is also in communication with the reactor. In one particular embodiment, the carbon containing material may include vacuum residuum (VR). The water and VR may be kept at desired temperatures and pressures compatible with the process that is to take place in the reactor. When introduced into the reactor, the water, the VR and the molten pool may be homogenously mixed in an environment in which chemical reactions take place including the production of hydrogen and other gasses.

  11. Electrobiocommodities: powering microbial production of fuels and commodity chemicals from carbon dioxide with electricity

    SciTech Connect

    Lovley, DR; Nevin, KP

    2013-06-01

    Electricity can be an energy source for microbially catalyzed production of fuels and other organic commodities from carbon dioxide. These electrobiocommodities (E-BCs) can be produced directly via electrode-to-microbe electron transfer or indirectly with electrochemically generated electron donors such as H-2 or formate. Producing E-BCs may be a more efficient and environmentally sustainable strategy for converting solar energy to biocommodities than approaches that rely on biological photosynthesis. A diversity of microbial physiologies could potentially be adapted for E-BC production, but to date acetogenic microorganisms are the only organisms shown to covert electrically generated low potential electrons and carbon dioxide into multi-carbon organic products with high recovery of electrons in product. Substantial research and development will be required for E-BC commercialization.

  12. An alternative feedstock of corn meal for industrial fuel ethanol production: delignified corncob residue.

    PubMed

    Lei, Cheng; Zhang, Jian; Xiao, Lin; Bao, Jie

    2014-09-01

    Delignified corncob residue is an industrial solid waste from xylose production using corncob as feedstock. In this study, delignified corncob residue was used as the feedstock of ethanol production by simultaneous saccharification and fermentation (SSF) and the optimal fermentation performance was investigated under various operation conditions. The ethanol titer and yield reached 75.07 g/L and 89.38%, respectively, using a regular industrial yeast strain at moderate cellulase dosage and high solids loading. A uniform SSF temperature of 37°C at both prehydrolysis and SSF stages was tested. The fermentation performance and cost of delignified corncob residue and corn meal was compared as feedstock of ethanol fermentation. The result shows that the delignified corncob residue is competitive to corn meal as ethanol production feedstock. The study gives a typical case to demonstrate the potential of intensively processed lignocellulose as the alternative feedstock of corn meal for industrial fuel ethanol production. PMID:25027810

  13. Possibilities of production of smokeless fuel via carbonization of Czech coals

    SciTech Connect

    Buchtele, J.; Straka, P.

    1995-12-01

    It was consumed 48 -51 % of hard coal (total output 28 - 30 Mt/year) in a long period for the production of coke. It appears to be anomaly in comparison with other coke producers in Europe and in the world, it was predeterminated by {open_quotes}steel conception{close_quotes} of state`s economics. The production of coke reached 10-11 Mt/year in former Czechoslovakia in the period 1970-1990. A considerable quantity 1.2 - 1.7 Mt/year of produced coke was utilized for heating. In comparison, 7-5.4 Mt coke/year was it in Poland for the heating. Al coke production is realized on the basis of Czech hard coals mined in the southern part of Upper Silesian Coal District. The coke production is operated in multi-chamber system with full recovery of chemical products (gas, raw tar, raw benzene, amonium etc.). The future trend of smokeless fuel production in Czech Republic makes for to the non-recovery coke oven, it means to two-product processes (coke + reduction gas, coke + electricity and so on). Jewell--Thompson coke oven (hard coal) and Salem oven (ignites) represent nonrecovery nowadays. The possibility of it`s application in Czech Republic are discussed. Jumbo coking reactor system (European project No. 500 to the Eureka programme) produces primarily metallurgical coke. The strong Clean Air Act suspends the production of smokeless fuel in multi-chamber system also in Czech Republic for the future period 2010-2020.

  14. A critical review of noise production models for turbulent, gas-fueled burners

    NASA Technical Reports Server (NTRS)

    Mahan, J. R.

    1984-01-01

    The combustion noise literature for the period between 1952 and early 1984 is critically reviewed. Primary emphasis is placed on past theoretical and semi-empirical attempts to predict or explain observed direct combustion noise characteristics of turbulent, gas-fueled burners; works involving liquid-fueled burners are reviewed only when ideas equally applicable to gas-fueled burners are pesented. The historical development of the most important contemporary direct combustion noise theories is traced, and the theories themselves are compared and criticized. While most theories explain combustion noise production by turbulent flames in terms of randomly distributed acoustic monopoles produced by turbulent mixing of products and reactants, none is able to predict the sound pressure in the acoustic farfield of a practical burner because of the lack of a proven model which relates the combustion noise source strenght at a given frequency to the design and operating parameters of the burner. Recommendations are given for establishing a benchmark-quality data base needed to support the development of such a model.

  15. Production of a pellet fuel from Illinois coal fines. Technical report, September 1--November 30, 1994

    SciTech Connect

    Rapp, D.; Lytle, J.; Berger, R.

    1994-12-31

    The primary goal of this research is to produce a pellet fuel from low-sulfur Illinois coal fines which could burn with emissions of less than 1.8 lbs SO{sub 2}/10{sup 6} Btu in stoker-fired boilers. The significance of 1.8 lbs SO{sub 2}/10{sup 6} Btu is that in the Chicago (9 counties) and St. Louis (2 counties) metropolitan areas, industrial users of coal currently must comply with this level of emissions. Stokers are an attractive market for pellets because pellets are well-suited for this application and because western coal is not a competitor in the stoker market. Compliance stoker fuels come from locations such as Kentucky and West Virginia and the price for fuels from these locations is high relative to the current price of Illinois coal. This market offers the most attractive near-term economic environment for commercialization of pelletization technology. For this effort, the authors will be investigating the use of fines from two Illinois mines which currently mine relatively low-sulfur reserves and that discard their fines fraction (minus 100 mesh). The research will involve investigation of multiple unit operations including column flotation, filtration and pellet production. The end result of the effort will allow for an evaluation of the commercial viability of the approach. This quarter pellet production work commenced and planning for collection and processing of a preparation plant fines fraction is underway.

  16. Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels

    SciTech Connect

    Steven Markovich

    2010-06-30

    This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

  17. Molten carbonate fuel cell product development test. Annual report, October 1992--September 1993

    SciTech Connect

    Not Available

    1993-12-01

    Advanced fuel cell active components have been developed and scaled up from laboratory scale to commercial scale. Full width components of both the stabilized nickel cathodes and the low chrome anodes have been successfully cast on M-C Power`s production tape caster. An improved design for a fuel cell separator plate has been developed. The improved design meets the goals of lower cost and manufacturing simplicity, and addresses performance issues of the current commercial area plate. The engineering that the Bechtel Corporation has completed for the MCFC power plant includes a site design, a preliminary site layout, a Process Flow Diagram, and specification for the procurement of some of the major equipment items. Raw materials for anode and cathode components were ordered and received during the first half of 1993. Tape casting of anodes was started in late summer and continued through August. In addition to the technical progress mentioned above, an environment assessment was prepared in compliance with the National Environmental Policy Act of 1969 (NEPA). As a result, the PDT has received a categorical exclusion from the Air Pollution Control District permit requirements. The PDT is configured to demonstrate the viability of natural gas-fueled MCFC for the production of electricity and thermal energy in an environmentally benign manner for use in commercial and industrial applications.

  18. Single particle refuse-derived fuel devolatilization: Experimental measurements of reaction products

    SciTech Connect

    Lai, Weichuan; Krieger-Brockett, B. . Dept. of Chemical Engineering)

    1993-11-01

    The authors present experimentally measured devolatilization product yields from single particles of refuse-derived fuel (RDF), a more uniform, transportable municipal solid waste. Disposal costs and environmental concerns have stimulated interest in thermochemical conversion of this material to chemicals and fuels. The composition, reaction conditions, and particle properties were systematically varied over the range found in practice to develop quantitative measures that rank the process controllables' influence on altering the product slate. Specialized regression methods and experimental designs enhanced the accuracy in view of the feed heterogeneity and offer a general method to extract real effects from experimental and sample noise''. The results have been verified successfully using actual commercial RDF and fabricated compositions that surpass those normally found in municipal waste to anticipate the influence of trends in recycling. The results show that the reaction conditions have a greater influence on altering fuel utilization and the relative yields of char, condensibles, and gases than does the composition over the range found in MSW and RDF.

  19. Molted carbonate fuel cell product design and improvement - 4th quarter, 1995. Quarterly report, October 1, 1995--December 31, 1995

    SciTech Connect

    1998-04-01

    The primary objective of this project is to establish the commercial readiness of MW-class IMHEX Molten Carbonate Fuel Cell power plants. Progress is described on marketing, systems design and analysis, product options and manufacturing.

  20. A novel biochemical route for fuels and chemicals production from cellulosic biomass.

    PubMed

    Fan, Zhiliang; Wu, Weihua; Hildebrand, Amanda; Kasuga, Takao; Zhang, Ruifu; Xiong, Xiaochao

    2012-01-01

    The conventional biochemical platform featuring enzymatic hydrolysis involves five key steps: pretreatment, cellulase production, enzymatic hydrolysis, fermentation, and product recovery. Sugars are produced as reactive intermediates for subsequent fermentation to fuels and chemicals. Herein, an alternative biochemical route is proposed. Pretreatment, enzymatic hydrolysis and cellulase production is consolidated into one single step, referred to as consolidated aerobic processing, and sugar aldonates are produced as the reactive intermediates for biofuels production by fermentation. In this study, we demonstrate the viability of consolidation of the enzymatic hydrolysis and cellulase production steps in the new route using Neurospora crassa as the model microorganism and the conversion of cellulose to ethanol as the model system. We intended to prove the two hypotheses: 1) cellulose can be directed to produce cellobionate by reducing β-glucosidase production and by enhancing cellobiose dehydrogenase production; and 2) both of the two hydrolysis products of cellobionate--glucose and gluconate--can be used as carbon sources for ethanol and other chemical production. Our results showed that knocking out multiple copies of β-glucosidase genes led to cellobionate production from cellulose, without jeopardizing the cellulose hydrolysis rate. Simulating cellobiose dehydrogenase over-expression by addition of exogenous cellobiose dehydrogenase led to more cellobionate production. Both of the two hydrolysis products of cellobionate: glucose and gluconate can be used by Escherichia coli KO 11 for efficient ethanol production. They were utilized simultaneously in glucose and gluconate co-fermentation. Gluconate was used even faster than glucose. The results support the viability of the two hypotheses that lay the foundation for the proposed new route. PMID:22384058

  1. A Novel Biochemical Route for Fuels and Chemicals Production from Cellulosic Biomass

    PubMed Central

    Fan, Zhiliang; Wu, Weihua; Hildebrand, Amanda; Kasuga, Takao; Zhang, Ruifu; Xiong, Xiaochao

    2012-01-01

    The conventional biochemical platform featuring enzymatic hydrolysis involves five key steps: pretreatment, cellulase production, enzymatic hydrolysis, fermentation, and product recovery. Sugars are produced as reactive intermediates for subsequent fermentation to fuels and chemicals. Herein, an alternative biochemical route is proposed. Pretreatment, enzymatic hydrolysis and cellulase production is consolidated into one single step, referred to as consolidated aerobic processing, and sugar aldonates are produced as the reactive intermediates for biofuels production by fermentation. In this study, we demonstrate the viability of consolidation of the enzymatic hydrolysis and cellulase production steps in the new route using Neurospora crassa as the model microorganism and the conversion of cellulose to ethanol as the model system. We intended to prove the two hypotheses: 1) cellulose can be directed to produce cellobionate by reducing β-glucosidase production and by enhancing cellobiose dehydrogenase production; and 2) both of the two hydrolysis products of cellobionate—glucose and gluconate—can be used as carbon sources for ethanol and other chemical production. Our results showed that knocking out multiple copies of β-glucosidase genes led to cellobionate production from cellulose, without jeopardizing the cellulose hydrolysis rate. Simulating cellobiose dehydrogenase over-expression by addition of exogenous cellobiose dehydrogenase led to more cellobionate production. Both of the two hydrolysis products of cellobionate: glucose and gluconate can be used by Escherichia coli KO 11 for efficient ethanol production. They were utilized simultaneously in glucose and gluconate co-fermentation. Gluconate was used even faster than glucose. The results support the viability of the two hypotheses that lay the foundation for the proposed new route. PMID:22384058

  2. Potential utilization of sorghum field waste for fuel ethanol production employing Pachysolen tannophilus and Saccharomyces cerevisiae.

    PubMed

    Sathesh-Prabu, C; Murugesan, A G

    2011-02-01

    In this study, we demonstrate that the sorghum field waste, sorghum stover could be used to produce fuel grade ethanol. The alkaline treatment of 2% NaOH for 8h removed 64% of lignin from sorghum stover. Maximum of 68 and 56 g/L of ethanol yield were obtained by Saccharomyces cerevisiae (MTCC 173) and Pachysolen tannophilus (MTCC 1077) from sorghum stover under optimized condition, respectively. pH and temperature were optimized for the better growth of S. cerevisiae and P. tannophilus. A total of 51% and 48% more ethanol yield was obtained at initial sugar concentration of 200 g/L than 150 g/L by P. tannophilus and S. cerevisiae, respectively. Respiratory deficiency and ethanol tolerance of the organisms were studied. This investigation showed that sorghum field waste could be effectively used for the production of fuel ethanol to avoid conflicts between human food use and industrial use of crops.

  3. Development of a more efficient process for production of fuel ethanol from bamboo.

    PubMed

    Sun, Zhao-Yong; Wang, Ting; Tan, Li; Tang, Yue-Qin; Kida, Kenji

    2015-06-01

    A process for production of fuel ethanol from bamboo treated with concentrated sulfuric acid has been previously proposed. To improve efficiency of the process, we tested saccharification with 70 weight% (wt%) sulfuric acid, acid-sugar separation by ion exclusion, addition of nutrients to the ethanol fermentation, and bioconversion of xylose to xylitol. A high efficiency of both sugar recovery (82.5 %) and acid recovery (97.5 %) was achieved in the saccharification process and in the continuous acid-sugar separation using a modified anion exchange resin, respectively. Reduction of the amount of mineral salts added to the saccharified liquid after acid-sugar separation did not negatively affect performance of the continuous ethanol fermentation. The ethanol yield and productivity were 93.7 % and 6 g/l h, respectively, at 35 °C and pH 4.0. And the ethanol yield and productivity were almost the same even at pH 3.5. Moreover, the xylose remaining in the fermented mash was efficiently converted to xylitol in batch fermentation by Candida tropicalis strain 2.1776. These results demonstrate a more efficient process for the production of fuel ethanol from bamboo.

  4. Optimization of enzyme parameters for fermentative production of biorenewable fuels and chemicals

    PubMed Central

    Jarboe, Laura R.; Liu, Ping; Kautharapu, Kumar Babu; Ingram, Lonnie O.

    2012-01-01

    Microbial biocatalysts such as Escherichia coli and Saccharomyces cerevisiae have been extensively subjected to Metabolic Engineering for the fermentative production of biorenewable fuels and chemicals. This often entails the introduction of new enzymes, deletion of unwanted enzymes and efforts to fine-tune enzyme abundance in order to attain the desired strain performance. Enzyme performance can be quantitatively described in terms of the Michaelis-Menten type parameters Km, turnover number kcat and Ki, which roughly describe the affinity of an enzyme for its substrate, the speed of a reaction and the enzyme sensitivity to inhibition by regulatory molecules. Here we describe examples of where knowledge of these parameters have been used to select, evolve or engineer enzymes for the desired performance and enabled increased production of biorenewable fuels and chemicals. Examples include production of ethanol, isobutanol, 1-butanol and tyrosine and furfural tolerance. The Michaelis-Menten parameters can also be used to judge the cofactor dependence of enzymes and quantify their preference for NADH or NADPH. Similarly, enzymes can be selected, evolved or engineered for the preferred cofactor preference. Examples of exporter engineering and selection are also discussed in the context of production of malate, valine and limonene. PMID:24688665

  5. Thermodynamic Analysis of Isothermal Redox Cycling of Ceria for Solar Fuel Production

    SciTech Connect

    Bader, R; Venstrom, LJ; Davidson, JH; Lipinski, W

    2013-09-01

    A thermodynamic analysis of continuous fuel production by redox cycling of ceria in a single solar reactor under isothermal conditions is presented. Ceria is partially reduced in a sweep gas flow of purified nitrogen and reoxidized with either steam or carbon dioxide to produce hydrogen or carbon monoxide, respectively. The sweep gas and oxidizer flows are preheated by the product gases. The influence of selected process parameters, including operating temperature, pressure, and the effectiveness of heat recovery, on the solar-to-fuel conversion efficiency is determined. For a solar concentration ratio of 3000, typical of state-of-the-art solar dish concentrators, and operating temperature of 1773 K, 95.5% of the available gas-phase heat must be recovered to reach conversion efficiencies of 10% and 18% for hydrogen and carbon monoxide production, respectively, assuming the flow rate of inert sweep gas is equivalent to that in a counter-current flow arrangement of gas and ceria. The efficiency depends strongly on the gas-phase heat recovery effectiveness and the sweep gas flow rate. Introducing a temperature swing of 150 K between reduction and oxidation steps strongly reduces the sweep gas flow rate and increases the efficiency from 10% to 31.6% for hydrogen production.

  6. Process Design and Economics for the Conversion of Algal Biomass to Biofuels: Algal Biomass Fractionation to Lipid-and Carbohydrate-Derived Fuel Products

    SciTech Connect

    Davis, R.; Kinchin, C.; Markham, J.; Tan, E. C. D.; Laurens, L. M. L.; Sexton, D.; Knorr, D.; Schoen, P.; Lukas, J.

    2014-09-11

    The U.S. Department of Energy (DOE) promotes the production of a range of liquid fuels and fuel blendstocks from biomass feedstocks by funding fundamental and applied research that advances the state of technology in biomass production, conversion, and sustainability. As part of its involvement in this program, the National Renewable Energy Laboratory (NREL) investigates the conceptual production economics of these fuels. This includes fuel pathways from lignocellulosic (terrestrial) biomass, as well as from algal (aquatic) biomass systems.

  7. BIOMASS AND NATURAL GAS AS CO-FEEDSTOCKS FOR PRODUCTION OF FUEL FOR FUEL-CELL VEHICLES

    EPA Science Inventory

    The article gives results of an examination of prospects for utilizing renewable energy crops as a source of liquid fuel to mitigate greenhouse gas emissions from mobile sources and reduce dependence on imported petroleum. Fuel cells would provide an optimum vehicle technology fo...

  8. Advanced turbine systems program conceptual design and product development Task 8.3 - autothermal fuel reformer (ATR). Topical report

    SciTech Connect

    1996-11-01

    Autothermal fuel reforming (ATR) consists of reacting a hydrocarbon fuel such as natural gas or diesel with steam to produce a hydrogen-rich {open_quotes}reformed{close_quotes} fuel. This work has been designed to investigate the fuel reformation and the product gas combustion under gas turbine conditions. The hydrogen-rich gas has a high flammability with a wide range of combustion stability. Being lighter and more reactive than methane, the hydrogen-rich gas mixes readily with air and can be burned at low fuel/air ratios producing inherently low emissions. The reformed fuel also has a low ignition temperature which makes low temperature catalytic combustion possible. ATR can be designed for use with a variety of alternative fuels including heavy crudes, biomass and coal-derived fuels. When the steam required for fuel reforming is raised by using energy from the gas turbine exhaust, cycle efficiency is improved because of the steam and fuel chemically recuperating. Reformation of natural gas or diesel fuels to a homogeneous hydrogen-rich fuel has been demonstrated. Performance tests on screening various reforming catalysts and operating conditions were conducted on a batch-tube reactor. Producing over 70 percent of hydrogen (on a dry basis) in the product stream was obtained using natural gas as a feedstock. Hydrogen concentration is seen to increase with temperature but less rapidly above 1300{degrees}F. The percent reforming increases as the steam to carbon ratio is increased. Two basic groups of reforming catalysts, nickel - and platinum-basis, have been tested for the reforming activity.

  9. Bio-aviation fuel production from hydroprocessing castor oil promoted by the nickel-based bifunctional catalysts.

    PubMed

    Liu, Siyang; Zhu, Qingqing; Guan, Qingxin; He, Liangnian; Li, Wei

    2015-05-01

    Bio-aviation fuel was firstly synthesized by hydroprocessing castor oil in a continuous-flow fixed-bed microreactor with the main objective to obtain the high yield of aviation fuel and determine the elemental compositions of the product phases as well as the reaction mechanism. Highest aviation range alkane yields (91.6 wt%) were achieved with high isomer/n-alkane ratio (i/n) 4.4-7.2 over Ni supported on acidic zeolites. In addition, different fuel range alkanes can be obtained by adjusting the degree of hydrodeoxygenation (HDO) and hydrocracking. And the observations are rationalized by a set of reaction pathways for the various product phases.

  10. Engineering xylose metabolism in triacylglycerol-producing Rhodococcus opacus for lignocellulosic fuel production

    PubMed Central

    2013-01-01

    Background There has been a great deal of interest in fuel productions from lignocellulosic biomass to minimize the conflict between food and fuel use. The bioconversion of xylose, which is the second most abundant sugar present after glucose in lignocellulosic biomass, is important for the development of cost effective bioprocesses to fuels. Rhodococcus opacus PD630, an oleaginous bacterium, accumulates large amounts of triacylglycerols (TAGs), which can be processed into advanced liquid fuels. However, R. opacus PD630 does not metabolize xylose. Results We generated DNA libraries from a Streptomyces bacterium capable of utilizing xylose and introduced them into R. opacus PD630. Xsp8, one of the engineered strains, was capable of growing on up to 180 g L-1 of xylose. Xsp8 grown in batch-cultures derived from unbleached kraft hardwood pulp hydrolysate containing 70 g L-1 total sugars was able to completely and simultaneously utilize xylose and glucose present in the lignocellulosic feedstock, and yielded 11.0 g L-1 of TAGs as fatty acids, corresponding to 45.8% of the cell dry weight. The yield of total fatty acids per gram of sugars consumed was 0.178 g, which consisted primarily of palmitic acid and oleic acid. The engineered strain Xsp8 was introduced with two heterologous genes from Streptomyces: xylA, encoding xylose isomerase, and xylB, encoding xylulokinase. We further demonstrated that in addition to the introduction and the concomitant expression of heterologous xylA and xylB genes, there is another molecular target in the R. opacus genome which fully enables the functionality of xylA and xylB genes to generate the robust xylose-fermenting strain capable of efficiently producing TAGs at high xylose concentrations. Conclusion We successfully engineered a R. opacus strain that is capable of completely utilizing high concentrations of xylose or mixed xylose/glucose simultaneously, and substantiated its suitability for TAG production. This study demonstrates

  11. Low-potential respirators support electricity production in microbial fuel cells.

    PubMed

    Grüning, André; Beecroft, Nelli J; Avignone-Rossa, Claudio

    2015-07-01

    In this paper, we analyse how electric power production in microbial fuel cells (MFCs) depends on the composition of the anodic biofilm in terms of metabolic capabilities of identified sets of species. MFCs are a promising technology for organic waste treatment and sustainable bioelectricity production. Inoculated with natural communities, they present a complex microbial ecosystem with syntrophic interactions between microbes with different metabolic capabilities. Our results demonstrate that low-potential anaerobic respirators--that is those that are able to use terminal electron acceptors with a low redox potential--are important for good power production. Our results also confirm that community metabolism in MFCs with natural inoculum and fermentable feedstock is a two-stage system with fermentation followed by anode respiration.

  12. Carbon neutral electricity production by Synechocystis sp. PCC6803 in a microbial fuel cell.

    PubMed

    Madiraju, Kartik S; Lyew, Darwin; Kok, Robert; Raghavan, Vijaya

    2012-04-01

    The aim of this work was to illustrate the use of photosynthetic microbes in a microbial fuel cell to produce electricity without the requirement of an external carbon source. This research here describes the use of a cyanobacterium Synechocystis PCC6803, to produce electricity without any net CO(2) production in a two-chambered MFC. Conditions for optimum electricity production were determined through standardizing operating parameters. A maximum power density of 6.7mWm(-3)(anode chamber volume) was achieved under high intensity lighting (10,000lux). Light intensity and wavelength directly affected electricity production, indicating the pivotal role played by photosynthesis. The maximum removal of CO(2) was 625mmolm(-3) over 20h under high intensity light. The results presented here will contribute to the understanding of how cyanobacteria can be exploited for the direct conversion of CO(2) to electric current.

  13. Pyrolysis of triglyceride materials for the production of renewable fuels and chemicals.

    PubMed

    Maher, K D; Bressler, D C

    2007-09-01

    Conversion of vegetable oils and animal fats composed predominantly of triglycerides using pyrolysis type reactions represents a promising option for the production of renewable fuels and chemicals. The purpose of this article was to collect and review literature on the thermo-chemical conversion of triglyceride based materials. The literature was divided and discussed as (1) direct thermal cracking and (2) combination of thermal and catalytic cracking. Typically, four main catalyst types are used including transition metal catalysts, molecular sieve type catalysts, activated alumina, and sodium carbonate. Reaction products are heavily dependant on the catalyst type and reaction conditions and can range from diesel like fractions to gasoline like fractions. Research in this area is not as advanced as bio-oil and bio-diesel research and there is opportunity for further study in the areas of reaction optimization, detailed characterization of products and properties, and scale-up.

  14. Technical/commercial feasibility study of the production of fuel-grade ethanol from corn: 100-million-gallon-per-year production facility in Myrtle Grove, Louisiana

    SciTech Connect

    Not Available

    1982-05-31

    The technical and economic feasibility of producing motor fuel alcohol from corn in a 100 million gallon per year plant to be constructed in Myrtle Grove, Louisiana is evaluated. The evaluation includes a detailed process design using proven technology, a capital cost estimate for the plant, a detailed analysis of the annual operating cost, a market study, a socioeconomic, environmental, health and safety analysis, and a complete financial analysis. Several other considerations for production of ethanol were evaluated including: cogeneration and fuel to be used in firing the boilers; single by-products vs. multiple by-products; and use of boiler flue gas for by-product drying.

  15. Technical/commercial feasibility study of the production of fuel-grade ethanol from corn: 100-million-gallon-per-year production facility in Myrtle Grove, Louisiana

    NASA Astrophysics Data System (ADS)

    1982-05-01

    The technical and economic feasibility of producing motor fuel alcohol from corn in a 100 million gallon per year plant to be constructed in Myrtle Grove, Louisiana is evaluated. The evaluation includes a detailed process design using proven technology, a capital cost estimate for the plant, a detailed analysis of the annual operating cost, a market study, a socioeconomic, environmental, health and safety analysis, and a complete financial analysis. Several other considerations for production of ethanol were evaluated including: cogeneration and fuel to be used in firing the boilers; single by-products vs. multiple by-products; and use of boiler flue gas for by-product drying.

  16. Scale up of fuel ethanol production from sugar beet juice using loofa sponge immobilized bioreactor.

    PubMed

    Ogbonna, J C; Mashima, H; Tanaka, H

    2001-01-01

    Production of fuel ethanol from sugar beet juice, using cells immobilized on loofa sponge was investigated. Based on ethanol productivity and ease of cell immobilization, a flocculating yeast strain, Saccharomyces cerevisiae IR2 was selected for ethanol production from sugar beet juice. It was found that raw sugar beet juice was an optimal substrate for ethanol production, requiring neither pH adjustment nor nitrogen source supplement. When compared with a 2 l bubble column bioreactor, mixing was not sufficient in an 8 l bioreactor containing a bed of sliced loofa sponges and consequently, the immobilized cells were not uniformly distributed within the bed. Most of the cells were immobilized in the lower part of the bed and this resulted in decreased ethanol productivity. By using an external loop bioreactor, constructing the fixed bed with cylindrical loofa sponges, dividing the bed into upper, middle and lower sections with approximately 1 cm spaces between them and circulating the broth through the loop during the immobilization, uniform cell distribution within the bed was achieved. Using this method, the system was scaled up to 50 l and when compared with the 2 l bubble column bioreactor, there were no significant differences (P > 0.05) in ethanol productivity and yield. By using external loop bioreactor to immobilize the cells uniformly on the loofa sponge beds, efficient large scale ethanol production systems can be constructed.

  17. Co-production of acetone and ethanol with molar ratio control enables production of improved gasoline or jet fuel blends.

    PubMed

    Baer, Zachary C; Bormann, Sebastian; Sreekumar, Sanil; Grippo, Adam; Toste, F Dean; Blanch, Harvey W; Clark, Douglas S

    2016-10-01

    The fermentation of simple sugars to ethanol has been the most successful biofuel process to displace fossil fuel consumption worldwide thus far. However, the physical properties of ethanol and automotive components limit its application in most cases to 10-15 vol% blends with conventional gasoline. Fermentative co-production of ethanol and acetone coupled with a catalytic alkylation reaction could enable the production of gasoline blendstocks enriched in higher-chain oxygenates. Here we demonstrate a synthetic pathway for the production of acetone through the mevalonate precursor hydroxymethylglutaryl-CoA. Expression of this pathway in various strains of Escherichia coli resulted in the co-production of acetone and ethanol. Metabolic engineering and control of the environmental conditions for microbial growth resulted in controllable acetone and ethanol production with ethanol:acetone molar ratios ranging from 0.7:1 to 10.0:1. Specifically, use of gluconic acid as a substrate increased production of acetone and balanced the redox state of the system, predictively reducing the molar ethanol:acetone ratio. Increases in ethanol production and the molar ethanol:acetone ratio were achieved by co-expression of the aldehyde/alcohol dehydrogenase (AdhE) from E. coli MG1655 and by co-expression of pyruvate decarboxylase (Pdc) and alcohol dehydrogenase (AdhB) from Z. mobilis. Controlling the fermentation aeration rate and pH in a bioreactor raised the acetone titer to 5.1 g L(-1) , similar to that obtained with wild-type Clostridium acetobutylicum. Optimizing the metabolic pathway, the selection of host strain, and the physiological conditions employed for host growth together improved acetone titers over 35-fold (0.14-5.1 g/L). Finally, chemical catalysis was used to upgrade the co-produced ethanol and acetone at both low and high molar ratios to higher-chain oxygenates for gasoline and jet fuel applications. Biotechnol. Bioeng. 2016;113: 2079-2087. © 2016 Wiley

  18. Co-production of acetone and ethanol with molar ratio control enables production of improved gasoline or jet fuel blends.

    PubMed

    Baer, Zachary C; Bormann, Sebastian; Sreekumar, Sanil; Grippo, Adam; Toste, F Dean; Blanch, Harvey W; Clark, Douglas S

    2016-10-01

    The fermentation of simple sugars to ethanol has been the most successful biofuel process to displace fossil fuel consumption worldwide thus far. However, the physical properties of ethanol and automotive components limit its application in most cases to 10-15 vol% blends with conventional gasoline. Fermentative co-production of ethanol and acetone coupled with a catalytic alkylation reaction could enable the production of gasoline blendstocks enriched in higher-chain oxygenates. Here we demonstrate a synthetic pathway for the production of acetone through the mevalonate precursor hydroxymethylglutaryl-CoA. Expression of this pathway in various strains of Escherichia coli resulted in the co-production of acetone and ethanol. Metabolic engineering and control of the environmental conditions for microbial growth resulted in controllable acetone and ethanol production with ethanol:acetone molar ratios ranging from 0.7:1 to 10.0:1. Specifically, use of gluconic acid as a substrate increased production of acetone and balanced the redox state of the system, predictively reducing the molar ethanol:acetone ratio. Increases in ethanol production and the molar ethanol:acetone ratio were achieved by co-expression of the aldehyde/alcohol dehydrogenase (AdhE) from E. coli MG1655 and by co-expression of pyruvate decarboxylase (Pdc) and alcohol dehydrogenase (AdhB) from Z. mobilis. Controlling the fermentation aeration rate and pH in a bioreactor raised the acetone titer to 5.1 g L(-1) , similar to that obtained with wild-type Clostridium acetobutylicum. Optimizing the metabolic pathway, the selection of host strain, and the physiological conditions employed for host growth together improved acetone titers over 35-fold (0.14-5.1 g/L). Finally, chemical catalysis was used to upgrade the co-produced ethanol and acetone at both low and high molar ratios to higher-chain oxygenates for gasoline and jet fuel applications. Biotechnol. Bioeng. 2016;113: 2079-2087. © 2016 Wiley

  19. Production of fuel ethanol from bamboo by concentrated sulfuric acid hydrolysis followed by continuous ethanol fermentation.

    PubMed

    Sun, Zhao-Yong; Tang, Yue-Qin; Iwanaga, Tomohiro; Sho, Tomohiro; Kida, Kenji

    2011-12-01

    An efficient process for the production of fuel ethanol from bamboo that consisted of hydrolysis with concentrated sulfuric acid, removal of color compounds, separation of acid and sugar, hydrolysis of oligosaccharides and subsequent continuous ethanol fermentation was developed. The highest sugar recovery efficiency was 81.6% when concentrated sulfuric acid hydrolysis was carried out under the optimum conditions. Continuous separation of acid from the saccharified liquid after removal of color compounds with activated carbon was conducted using an improved simulated moving bed (ISMB) system, and 98.4% of sugar and 90.5% of acid were recovered. After oligosaccharide hydrolysis and pH adjustment, the unsterilized saccharified liquid was subjected to continuous ethanol fermentation using Saccharomycescerevisiae strain KF-7. The ethanol concentration, the fermentation yield based on glucose and the ethanol productivity were approximately 27.2 g/l, 92.0% and 8.2 g/l/h, respectively. These results suggest that the process is effective for production of fuel ethanol from bamboo.

  20. Decarbonized fuel production facility -- A technical strategy for coal in the next century

    SciTech Connect

    Badin, J.; DeLallo, M.; Temchin, J.

    1999-07-01

    The US electricity market is undergoing major changes. Deregulation, increased competition, and growing environmental concerns are major challenges facing the electric power industry. These challenges also have the potential to significantly inhibit the future use of coal to produce electricity. In this paper, the authors describe a technical strategy for the coal industry that can help assure coal's competitiveness during the next century as the industry responds to these major challenges. Recently, the US Department of Energy unveiled a new concept. ``Vision 21''--a futuristic way of combining high-efficiency power technologies with advanced coal processing technologies and environmental controls to create a near-zero discharge, multi-product energy complex. This paper presents one conceptualization of a Vision 21 Plant that focuses on production of hydrogen from coal. It will show how the concept can help assure that coal can remain competitive with natural gas as a fuel for baseload electricity generation for existing and new power plants. It can also provide a feedstock for chemical and liquid fuels production, even if emissions of carbon dioxide must be controlled. Analyses are presented that provide the basis for the projected economic and technical performance objectives.

  1. Benefits analysis for the production of fuels and chemicals using solar thermal energy. Final report

    SciTech Connect

    1982-05-01

    Numerous possibilities exist for using high temperature solar thermal energy in the production of various chemicals and fuels (Sun Fuels). Research and development activities have focused on the use of feedstocks such as coal and biomass to provide synthesis gas, hydrogen, and a variety of other end-products. A Decision Analysis technique geared to the analysis of Sun Fuels options was developed. Conventional scoring methods were combined with multi-attribute utility analysis in a new approach called the Multi-Attribute Preference Scoring (MAPS) system. MAPS calls for the designation of major categories of attributes which describe critical elements of concern for the processes being examined. The six major categories include: Process Demonstration; Full-Scale Process, Feedstock; End-Product Market; National/Social Considerations; and Economics. MAPS calls for each attribute to be weighted on a simple scale for all of the candidate processes. Next, a weight is assigned to each attribute, thus creating a multiplier to be used with each individual value to derive a comparative weighting. Last, each of the categories of attributes themselves are weighted, thus creating another multiplier, for use in developing an overall score. With sufficient information and industry input, each process can be ultimately compared using a single figure of merit. After careful examination of available information, it was decided that only six of the 20 candidate processes were adequately described to allow a complete MAPS analysis which would allow direct comparisons for illustrative purposes. These six processes include three synthesis gas processes, two hydrogen and one ammonia. The remaining fourteen processes were subjected to only a partial MAPS assessment.

  2. Production and measurement of minor actinides in the commercial fuel cycle

    SciTech Connect

    Stanbro, W.D.

    1997-03-01

    The minor actinide elements, particularly neptunium and americium, are produced as a normal byproduct of the operation of thermal power reactors. Because of the existence of long-lived isotopes of these elements, they constitute the major sources of the residual radiation in spent fuel or in wastes resulting from reprocessing. This has led to examinations by some countries of the possibility of separating the minor actinides from waste products. The papers found in this report address the production of minor actinides in common thermal power reactors as well as approaches to measure these materials in various media. The first paper in this volume, {open_quotes}Production of Minor Actinides in the Commercial Fuel Cycle,{close_quotes} uses calculations with the ORIGEN2 reactor and decay code to estimate the amounts of minor actinides in spent fuel and separated plutonium as a function of reactor irradiation and the time after discharge. The second paper, {open_quotes}Destructive Assay of Minor Actinides,{close_quotes} describes a number of promising approaches for the chemical analysis of minor actinides in the various forms in which they are found at reprocessing plants. The next paper, {open_quotes}Hybrid KED/XRF Measurement of Minor Actinides in Reprocessing Plants,{close_quotes} uses the results of a simulation model to examine the possible applications of the hybrid KED/XRF instrument to the determination of minor actinides in some of the solutions found in reprocessing plants. In {open_quotes}Calorimetric Assay of Minor Actinides,{close_quotes} the authors show some possible extensions of this powerful technique beyond the normal plutonium assays to include the minor actinides. Finally, the last paper in this volume, {open_quotes}Environment Measurements of Transuranic Nuclides,{close_quotes} discusses what is known about the levels of the minor actinides in the environment and ways to analyze for these materials in environmental matrices.

  3. Comparison of Marine Microalgae Culture Systems for Fuels Production and Carbon Sequestration

    SciTech Connect

    Weissman, Joseph C; Polle, Juergen

    2006-05-30

    The dual problems of global fossil fuels supplies and global warming focus attention on the need to develop technologies that can provide large amounts of renewable fuels without contributing to global warming. The capture of power plant flue gas CO2 using microalgae cultures is one potential technology that could meet this objective. The central R&D issues are the design and operation of low-cost algal mass culture systems and the development of algal strains and cultivation techniques that can achieve very high biomass productivities. The major objective of this project was to develop mass culture techniques that could result in greatly increased biomass productivities, well above the about 50 metric tons per hectare per year (mt/ha/y) currently achievable. In this project, two marine microalgae species, the diatom Cyclotella sp.. and the green alga Tetraselmis sp., were cultivated on seawater in both open ponds and closed photo bioreactors, under a variety of different cultivation conditions. Simultaneous operation of the closed photo bioreactors and open ponds demonstrated similar productivities, under the same operating conditions. Thus the very expensive closed systems do not provide any major or inherent advantages in microalgae production over open ponds. Mutants of Cyclotella sp. were developed that exhibited reduced pigment content, which theoretically would result in greatly increased productivities when grown under full sunlight. However, in open ponds, these mutant strains exhibited similar productivities as the parental strains. The mutant strains all grew relatively slowly, suggesting that additional mutations masked whatever inherent potential for increased productivities may have resulted from the reduced pigment content. Research is still required to develop improved low pigment strains. When open pond cultures were exposed to intermittent sunlight, by partially covering the ponds with slats, solar conversion efficiencies increased dramatically

  4. Characteristics of mechanically sorted municipal wastes and their suitability for production of refuse derived fuel

    NASA Astrophysics Data System (ADS)

    Arina, Dace; Orupe, Ausma

    2012-11-01

    The article presents the results of experimental work in the first waste mechanical Pre-treatment Centre in Latvia Daibe. The goal - to detect the main parameters for sorted waste parts and to compare them with parameters stated for refuse derived fuel (RDF) in a cement plant in Latvia (Cemex). Samples were taken in four fractions - coarse, medium, fine, metal. The parameters - upper, lower heating values, moisture, ash content, S, Cl, metals were determined. Results - coarse fraction has greater potential of the production of the RDF, but reduction of its content of Cl would be necessary.

  5. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect

    Paul A. Erickson

    2005-04-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the sixth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2005. This quarter saw progress in four areas. These areas are: (1) Autothermal reforming of coal derived methanol, (2) Catalyst deactivation, (3) Steam reformer transient response, and (4) Catalyst degradation with bluff bodies. All of the projects are proceeding on or slightly ahead of schedule.

  6. Process for preparing and using sweet sorghum in a fuel product

    SciTech Connect

    Gunnerman, R.W.; Farone, W.A.

    1986-09-23

    This patent describes a method of storing sweet sorghum preparatory to pelletizing it for use as a combustible fuel product comprising: removing a majority of sugar-containing fluid from the sorghum to leave a residue of ligno-cellulosic bagasse; piling the bagasse on a hard surface; compressing the piled bagasse to form a compacted mass, whereby the compressing frees air trapped within the bagasse to inhibit microbial and fungal oxidative degradation thereof; and storing the compacted mass preparatory to pelletizing the same.

  7. Life cycle assessment of the production of hydrogen and transportation fuels from corn stover via fast pyrolysis

    NASA Astrophysics Data System (ADS)

    Zhang, Yanan; Hu, Guiping; Brown, Robert C.

    2013-06-01

    This life cycle assessment evaluates and quantifies the environmental impacts of the production of hydrogen and transportation fuels from the fast pyrolysis and upgrading of corn stover. Input data for this analysis come from Aspen Plus modeling, a GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model database and a US Life Cycle Inventory Database. SimaPro 7.3 software is employed to estimate the environmental impacts. The results indicate that the net fossil energy input is 0.25 MJ and 0.23 MJ per km traveled for a light-duty vehicle fueled by gasoline and diesel fuel, respectively. Bio-oil production requires the largest fossil energy input. The net global warming potential (GWP) is 0.037 kg CO2eq and 0.015 kg CO2eq per km traveled for a vehicle fueled by gasoline and diesel fuel, respectively. Vehicle operations contribute up to 33% of the total positive GWP, which is the largest greenhouse gas footprint of all the unit processes. The net GWPs in this study are 88% and 94% lower than for petroleum-based gasoline and diesel fuel (2005 baseline), respectively. Biomass transportation has the largest impact on ozone depletion among all of the unit processes. Sensitivity analysis shows that fuel economy, transportation fuel yield, bio-oil yield, and electricity consumption are the key factors that influence greenhouse gas emissions.

  8. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect

    Gerald P. Huffman

    2005-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  9. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect

    Gerald P. Huffman

    2004-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  10. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect

    Gerald P. Huffman

    2003-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the first six months of the subject contract (DE-FC26-02NT-4159), from October 1, 2002 through March 31, 2003.

  11. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect

    Paul A. Erickson

    2004-04-01

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the first such report that will be submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1--December 31, 2003. This quarter saw progress in three areas. These areas are: (1) Evaluations of coal based methanol and the fuel cell grade baseline fuel, (2) Design and set up of the autothermal reactor, as well as (3) Set up and data collection of baseline performance using the steam reformer. All of the projects are proceeding on schedule. During this quarter one conference paper was written that will be presented at the ASME Power 2004 conference in March 2004, which outlines the research direction and basis for looking at the coal to hydrogen pathway.

  12. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect

    Paul A. Erickson

    2004-09-30

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the fourth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of July 1-Sept 30, 2004 along with a recap of progress from the start of the project on Oct 1, 2003 to Sept 30, 2004. All of the projects are proceeding on or slightly ahead of schedule. This year saw progress in several areas. These areas are: (1) External and internal evaluation of coal based methanol and a fuel cell grade baseline fuel, (2) Design set up and initial testing of three laboratory scale steam reformers, (3) Design, set up and initial testing of a laboratory scale autothermal reactor, (4) Hydrogen generation from coal-derived methanol using steam reformation, (5) Experiments to determine the axial and radial thermal profiles of the steam reformers, (6) Initial catalyst degradation studies with steam reformation and coal based methanol, and (7) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

  13. World Biofuels Production Potential Understanding the Challenges to Meeting the U.S. Renewable Fuel Standard

    SciTech Connect

    Sastri, B.; Lee, A.

    2008-09-15

    This study by the U.S. Department of Energy (DOE) estimates the worldwide potential to produce biofuels including biofuels for export. It was undertaken to improve our understanding of the potential for imported biofuels to satisfy the requirements of Title II of the 2007 Energy Independence and Security Act (EISA) in the coming decades. Many other countries biofuels production and policies are expanding as rapidly as ours. Therefore, we modeled a detailed and up-to-date representation of the amount of biofuel feedstocks that are being and can be grown, current and future biofuels production capacity, and other factors relevant to the economic competitiveness of worldwide biofuels production, use, and trade. The Oak Ridge National Laboratory (ORNL) identified and prepared feedstock data for countries that were likely to be significant exporters of biofuels to the U.S. The National Renewable Energy Laboratory (NREL) calculated conversion costs by conducting material flow analyses and technology assessments on biofuels technologies. Brookhaven National Laboratory (BNL) integrated the country specific feedstock estimates and conversion costs into the global Energy Technology Perspectives (ETP) MARKAL (MARKet ALlocation) model. The model uses least-cost optimization to project the future state of the global energy system in five year increments. World biofuels production was assessed over the 2010 to 2030 timeframe using scenarios covering a range U.S. policies (tax credits, tariffs, and regulations), as well as oil prices, feedstock availability, and a global CO{sub 2} price. All scenarios include the full implementation of existing U.S. and selected other countries biofuels policies (Table 4). For the U.S., the most important policy is the EISA Title II Renewable Fuel Standard (RFS). It progressively increases the required volumes of renewable fuel used in motor vehicles (Appendix B). The RFS requires 36 billion (B) gallons (gal) per year of renewable fuels by 2022

  14. Effects of Fuel Aromatic Content on Nonvolatile Particulate Emissions of an In-Production Aircraft Gas Turbine.

    PubMed

    Brem, Benjamin T; Durdina, Lukas; Siegerist, Frithjof; Beyerle, Peter; Bruderer, Kevin; Rindlisbacher, Theo; Rocci-Denis, Sara; Andac, M Gurhan; Zelina, Joseph; Penanhoat, Olivier; Wang, Jing

    2015-11-17

    Aircraft engines emit particulate matter (PM) that affects the air quality in the vicinity of airports and contributes to climate change. Nonvolatile PM (nvPM) emissions from aircraft turbine engines depend on fuel aromatic content, which varies globally by several percent. It is uncertain how this variability will affect future nvPM emission regulations and emission inventories. Here, we present black carbon (BC) mass and nvPM number emission indices (EIs) as a function of fuel aromatic content and thrust for an in-production aircraft gas turbine engine. The aromatics content was varied from 17.8% (v/v) in the neat fuel (Jet A-1) to up to 23.6% (v/v) by injecting two aromatic solvents into the engine fuel supply line. Fuel normalized BC mass and nvPM number EIs increased by up to 60% with increasing fuel aromatics content and decreasing engine thrust. The EIs also increased when fuel naphthalenes were changed from 0.78% (v/v) to 1.18% (v/v) while keeping the total aromatics constant. The EIs correlated best with fuel hydrogen mass content, leading to a simple model that could be used for correcting fuel effects in emission inventories and in future aircraft engine nvPM emission standards. PMID:26495879

  15. Effects of Fuel Aromatic Content on Nonvolatile Particulate Emissions of an In-Production Aircraft Gas Turbine.

    PubMed

    Brem, Benjamin T; Durdina, Lukas; Siegerist, Frithjof; Beyerle, Peter; Bruderer, Kevin; Rindlisbacher, Theo; Rocci-Denis, Sara; Andac, M Gurhan; Zelina, Joseph; Penanhoat, Olivier; Wang, Jing

    2015-11-17

    Aircraft engines emit particulate matter (PM) that affects the air quality in the vicinity of airports and contributes to climate change. Nonvolatile PM (nvPM) emissions from aircraft turbine engines depend on fuel aromatic content, which varies globally by several percent. It is uncertain how this variability will affect future nvPM emission regulations and emission inventories. Here, we present black carbon (BC) mass and nvPM number emission indices (EIs) as a function of fuel aromatic content and thrust for an in-production aircraft gas turbine engine. The aromatics content was varied from 17.8% (v/v) in the neat fuel (Jet A-1) to up to 23.6% (v/v) by injecting two aromatic solvents into the engine fuel supply line. Fuel normalized BC mass and nvPM number EIs increased by up to 60% with increasing fuel aromatics content and decreasing engine thrust. The EIs also increased when fuel naphthalenes were changed from 0.78% (v/v) to 1.18% (v/v) while keeping the total aromatics constant. The EIs correlated best with fuel hydrogen mass content, leading to a simple model that could be used for correcting fuel effects in emission inventories and in future aircraft engine nvPM emission standards.

  16. Production and Engineering of Hydrogenase as a Biocatalyst for Hydrogen Fuel

    SciTech Connect

    Wang, Guangyi

    2010-04-09

    Hydrogenases are fascinating redox proteins, showing tremendous promise in the utilization of hydrogen fuel as a bioelectrocatalyst. They play critical roles in both biohydrogen production and hydrogen oxidation. Specifically, the recently-established comparability of the oxidative activity of the [NiFe]-hydrogenase active site to that of the fuel cell catalyst platinum marks a significant milestone for the potential application of hydrogenase in hydrogen fuel cells to replace platinum. However, the ability of producing hydrogenase in heterologous expression hosts and the sensitivity of hydrogenases to oxygen and carbon monoxide, etc. have seriously limited the viable macroscale utilization and production of hydrogen from the renewable source. A new technology for the production of up-take hydrogenase is being developed for the utilization of hydrogenase as a hydrogen catalyst. The development of this new technology integrates knowledge of structural biology, molecular biology, and principles of metabolic engineering to produce and engineer a stable hydrogenase as a hydrogen bioelectrocatalyst. It contributes to the critical issues of “expensive noble metal catalysts (i.e., platinum) and their limited reserves threatening the long-term sustainability of a hydrogen economy”. It also provides a model to “design natural materials and enzyme catalyst” for “efficient and cost-effective technologies” for a clean and sustainable energy in 21st century. This new technology includes 3 major components. The first component is the synthetic operons, which carry hydrogenase maturation pathways of Ralstonia eutropha. These synthetic operons are engineered to produce RH hydrogenase in the Escherichia coli strains based on our current molecular and genetic information of hydrogenase maturation mechanisms and pathways of R. eutropha. It presents the first example of producing hydrogenase in the conventional expression host using synthetic biology principles and tool

  17. Transportation fuel production by combination of LDPE thermal cracking and catalytic hydroreforming

    SciTech Connect

    Escola, J.M.; Briones, L.

    2014-11-15

    Highlights: • h-Beta samples were impregnated with Ni nitrate to achieve Ni contents of 1.5%, 4%, 7% and 10%. • Larger and more easily reducible metal particles were obtained on Ni 7%/h-Beta and Ni 10%/h-Beta. • Higher Ni contents increased the amount of gases at the expenses of diesel fractions. • Maximum selectivity to automotive fuels (∼81%) was obtained with Ni 7%/h-Beta. • Ni loading also enhanced olefins saturation up to Ni 7%/h-Beta. - Abstract: Fuel production from plastics is a promising way to reduce landfilling rates while obtaining valuable products. The usage of Ni-supported hierarchical Beta zeolite (h-Beta) for the hydroreforming of the oils coming from LDPE thermal cracking has proved to produce high selectivities to gasoline and diesel fuels (>80%). In the present work, the effect of the Ni loading on Ni/h-Beta is investigated in the hydroreforming of the oils form LDPE thermal cracking. h-Beta samples were impregnated with Ni nitrate, calcined and reduced in H{sub 2} up to 550 °C to achieve different Ni contents: 1.5%, 4%, 7% and 10%. Larger and more easily reducible metal particles were obtained on Ni 7%/h-Beta and Ni 10%/h-Beta. Hydroreforming tests were carried out in autoclave reactor at 310 °C, under 20 bar H{sub 2}, for 45 min. Ni content progressively increased the amount of gases at the expenses of diesel fractions, while gasoline remained approximately constant about 52–54%. Maximum selectivity to automotive fuels (∼81%) was obtained with Ni 7%/h-Beta. Ni loading also enhanced olefins saturation up to Ni 7%/h-Beta. High cetane indices (71–86) and octane numbers (89–91) were obtained over all the catalysts. Regarding the different studied Ni contents, Ni 7%/h-Beta constitutes a rather promising catalyst for obtaining high quality fuels from LDPE thermal cracking oils.

  18. Partitioning of fission products from irradiated nitride fuel using inductive vaporization

    SciTech Connect

    Shcherbina, N.; Kulik, D.A.; Kivel, N.; Potthast, H.D.; Guenther-Leopold, I.

    2013-07-01

    Irradiated nitride fuel (Pu{sub 0.3}Zr{sub 0.7})N fabricated at PSI in frame of the CONFIRM project and having a burn-up of 10.4 % FIMA (Fission per Initial Metal Atom) has been investigated by means of inductive vaporization. The study of thermal stability and release behavior of Pu, Am, Zr and fission products (FPs) was performed in a wide temperature range (up to 2300 C. degrees) and on different redox conditions. On-line monitoring by ICP-MS detected low nitride stability and significant loss of Pu and Am at T>1900 C. degrees during annealing under inert atmosphere (Ar). The oxidative pre-treatment of nitride fuel on air at 1000 C. degrees resulted in strong retention of Pu and Am in the solid, as well as of most FPs. Thermodynamic modelling of elemental speciation using GEM-Selektor v.3 code (Gibbs Energy Minimization Selektor), supported by a comprehensive literature review on thermodynamics of actinides and FPs, revealed a number of binary compounds of Cs, Mo, Te, Sr and Ba to occur in the solid. Speciation of some FPs in the fuel is discussed and compared to earlier results of electron probe microanalysis (EPMA). Predominant vapor species predicted by GEM-Selektor calculations were Pu(g), Am(g) and N{sub 2}. Nitrogen can be completely released from the fuel after complete oxidation at 1000 C. degrees. With regard to the irradiated nitride reprocessing technology, this result can have an important practical application as an alternative way for {sup 15}N recovery. (authors)

  19. Details of the Construction and Production of Fuel Pumps and Fuel Nozzles for the Airplane Diesel Engine

    NASA Technical Reports Server (NTRS)

    Lubenetsky, W S

    1936-01-01

    This report presents investigations into the design and construction of fuel pumps for diesel engines. The results of the pump tests on the engines showed that, with a good cut-off, accurate injection, assured by the proper adjustment of the pump elements, there is a decrease in the consumption of fuel and hence an increase in the rated power of the engine. Some of the aspects investigated include: cam profile, coefficient of discharge, and characteristics of the injection system.

  20. Carbon-13 and proton nuclear magnetic resonance analysis of shale-derived refinery products and jet fuels and of experimental referee broadened-specification jet fuels

    NASA Technical Reports Server (NTRS)

    Dalling, D. K.; Bailey, B. K.; Pugmire, R. J.

    1984-01-01

    A proton and carbon-13 nuclear magnetic resonance (NMR) study was conducted of Ashland shale oil refinery products, experimental referee broadened-specification jet fuels, and of related isoprenoid model compounds. Supercritical fluid chromatography techniques using carbon dioxide were developed on a preparative scale, so that samples could be quantitatively separated into saturates and aromatic fractions for study by NMR. An optimized average parameter treatment was developed, and the NMR results were analyzed in terms of the resulting average parameters; formulation of model mixtures was demonstrated. Application of novel spectroscopic techniques to fuel samples was investigated.

  1. Investigation of the Feasibility of Utilizing Gamma Emission Computed Tomography in Evaluating Fission Product Migration in Irradiated TRISO Fuel Experiments

    SciTech Connect

    Jason M. Harp; Paul A. Demkowicz

    2014-10-01

    In the High Temperature Gas-Cooled Reactor (HTGR) the TRISO particle fuel serves as the primary fission product containment. However the large number of TRISO particles present in proposed HTGRs dictates that there will be a small fraction (~10-4 to 10-5) of as manufactured and in-pile particle failures that will lead to some fission product release. The matrix material surrounding the TRISO particles in fuel compacts and the structural graphite holding the TRISO particles in place can also serve as sinks for containing any released fission products. However data on the migration of solid fission products through these materials is lacking. One of the primary goals of the AGR-3/4 experiment is to study fission product migration from failed TRISO particles in prototypic HTGR components such as structural graphite and compact matrix material. In this work, the potential for a Gamma Emission Computed Tomography (GECT) technique to non-destructively examine the fission product distribution in AGR-3/4 components and other irradiation experiments is explored. Specifically, the feasibility of using the Idaho National Laboratory (INL) Hot Fuels Examination Facility (HFEF) Precision Gamma Scanner (PGS) system for this GECT application is considered. To test the feasibility, the response of the PGS system to idealized fission product distributions has been simulated using Monte Carlo radiation transport simulations. Previous work that applied similar techniques during the AGR-1 experiment will also be discussed as well as planned uses for the GECT technique during the post irradiation examination of the AGR-2 experiment. The GECT technique has also been applied to other irradiated nuclear fuel systems that were currently available in the HFEF hot cell including oxide fuel pins, metallic fuel pins, and monolithic plate fuel.

  2. Electrocatalytic processing of renewable biomass-derived compounds for production of chemicals, fuels and electricity

    NASA Astrophysics Data System (ADS)

    Xin, Le

    The dual problems of sustaining the fast growth of human society and preserving the environment for future generations urge us to shift our focus from exploiting fossil oils to researching and developing more affordable, reliable and clean energy sources. Human beings had a long history that depended on meeting our energy demands with plant biomass, and the modern biorefinery technologies realize the effective conversion of biomass to production of transportation fuels, bulk and fine chemicals so to alleviate our reliance on fossil fuel resources of declining supply. With the aim of replacing as much non-renewable carbon from fossil oils with renewable carbon from biomass as possible, innovative R&D activities must strive to enhance the current biorefinery process and secure our energy future. Much of my Ph.D. research effort is centered on the study of electrocatalytic conversion of biomass-derived compounds to produce value-added chemicals, biofuels and electrical energy on model electrocatalysts in AEM/PEM-based continuous flow electrolysis cell and fuel cell reactors. High electricity generation performance was obtained when glycerol or crude glycerol was employed as fuels in AEMFCs. The study on selective electrocatalytic oxidation of glycerol shows an electrode potential-regulated product distribution where tartronate and mesoxalate can be selectively produced with electrode potential switch. This finding then led to the development of AEMFCs with selective production of valuable tartronate or mesoxalate with high selectivity and yield and cogeneration of electricity. Reaction mechanisms of electrocatalytic oxidation of ethylene glycol and 1,2-propanediol were further elucidated by means of an on-line sample collection technique and DFT modeling. Besides electro-oxidation of biorenewable alcohols to chemicals and electricity, electrocatalytic reduction of keto acids (e.g. levulinic acid) was also studied for upgrading biomass-based feedstock to biofuels while

  3. Hybrid photocathodes for solar fuel production: coupling molecular fuel-production catalysts with solid-state light harvesting and conversion technologies.

    PubMed

    Cedeno, Diana; Krawicz, Alexandra; Moore, Gary F

    2015-06-01

    Artificial photosynthesis is described as the great scientific and moral challenge of our time. We imagine a future where a significant portion of our energy is supplied by such technologies. However, many scientific, engineering and policy challenges must be addressed for this realization. Scientific challenges include the development of effective strategies to couple light absorption, electron transfer and catalysis for efficient conversion of light energy to chemical energy as well as the construction and study of structurally diverse assemblies to carry out these processes. In this article, we review recent efforts from our own research to develop a modular approach to interfacing molecular fuel-production catalysts to visible-light-absorbing semiconductors and discuss the role of the interfacing material as a protection layer for the catalysts as well as the underpinning semiconductor. In concluding, we briefly discuss the potential benefits of a globally coordinated project on artificial photosynthesis that interfaces teams of scientists, engineers and policymakers. Further, we offer cautions that such a large interconnected organization should consider. This article is inspired by, and draws largely from, an invited presentation given by the corresponding author at the Royal Society at Chicheley Hall, home of the Kavli Royal Society International Centre, Buckinghamshire on the themed meeting topic: 'Do we need a global project on artificial photosynthesis?'

  4. Hybrid photocathodes for solar fuel production: coupling molecular fuel-production catalysts with solid-state light harvesting and conversion technologies

    PubMed Central

    Cedeno, Diana; Krawicz, Alexandra; Moore, Gary F.

    2015-01-01

    Artificial photosynthesis is described as the great scientific and moral challenge of our time. We imagine a future where a significant portion of our energy is supplied by such technologies. However, many scientific, engineering and policy challenges must be addressed for this realization. Scientific challenges include the development of effective strategies to couple light absorption, electron transfer and catalysis for efficient conversion of light energy to chemical energy as well as the construction and study of structurally diverse assemblies to carry out these processes. In this article, we review recent efforts from our own research to develop a modular approach to interfacing molecular fuel-production catalysts to visible-light-absorbing semiconductors and discuss the role of the interfacing material as a protection layer for the catalysts as well as the underpinning semiconductor. In concluding, we briefly discuss the potential benefits of a globally coordinated project on artificial photosynthesis that interfaces teams of scientists, engineers and policymakers. Further, we offer cautions that such a large interconnected organization should consider. This article is inspired by, and draws largely from, an invited presentation given by the corresponding author at the Royal Society at Chicheley Hall, home of the Kavli Royal Society International Centre, Buckinghamshire on the themed meeting topic: ‘Do we need a global project on artificial photosynthesis?’ PMID:26052422

  5. Demonstrating hydrogen production from ammonia using lithium imide - Powering a small proton exchange membrane fuel cell

    NASA Astrophysics Data System (ADS)

    Hunter, Hazel M. A.; Makepeace, Joshua W.; Wood, Thomas J.; Mylius, O. Simon; Kibble, Mark G.; Nutter, Jamie B.; Jones, Martin O.; David, William I. F.

    2016-10-01

    Accessing the intrinsic hydrogen content within ammonia, NH3, has the potential to play a very significant role in the future of a CO2-free sustainable energy supply. Inexpensive light metal imides and amides are effective at decomposing ammonia to hydrogen and nitrogen (2NH3 → 3H2 + N2), at modest temperatures, and thus represent a low-cost approach to on-demand hydrogen production. Building upon this discovery, this paper describes the integration of an ammonia cracking unit with a post-reactor gas purification system and a small-scale PEM fuel cell to create a first bench-top demonstrator for the production of hydrogen using light metal imides.

  6. Establishment and assessment of a novel cleaner production process of corn grain fuel ethanol.

    PubMed

    Wang, Ke; Zhang, Jianhua; Tang, Lei; Zhang, Hongjian; Zhang, Guiying; Yang, Xizhao; Liu, Pei; Mao, Zhonggui

    2013-11-01

    An integrated corn ethanol-methane fermentation system was proposed to solve the problem of stillage handling, where thin stillage was treated by anaerobic digestion and then reused to make mash for the following ethanol fermentation. This system was evaluated at laboratory and pilot scale. Anaerobic digestion of thin stillage ran steadily with total chemical oxygen demand removal efficiency of 98% at laboratory scale and 97% at pilot scale. Ethanol production was not influenced by recycling anaerobic digestion effluent at laboratory and pilot scale. Compared with dried distillers' grains with solubles produced in conventional process, dried distillers' grains in the proposed system exhibited higher quality because of increased protein concentration and decreased salts concentration. Energetic assessment indicated that application of this novel process enhanced the net energy balance ratio from 1.26 (conventional process) to 1.76. In conclusion, the proposed system possessed technical advantage over the conventional process for corn fuel ethanol production.

  7. Establishment and assessment of a novel cleaner production process of corn grain fuel ethanol.

    PubMed

    Wang, Ke; Zhang, Jianhua; Tang, Lei; Zhang, Hongjian; Zhang, Guiying; Yang, Xizhao; Liu, Pei; Mao, Zhonggui

    2013-11-01

    An integrated corn ethanol-methane fermentation system was proposed to solve the problem of stillage handling, where thin stillage was treated by anaerobic digestion and then reused to make mash for the following ethanol fermentation. This system was evaluated at laboratory and pilot scale. Anaerobic digestion of thin stillage ran steadily with total chemical oxygen demand removal efficiency of 98% at laboratory scale and 97% at pilot scale. Ethanol production was not influenced by recycling anaerobic digestion effluent at laboratory and pilot scale. Compared with dried distillers' grains with solubles produced in conventional process, dried distillers' grains in the proposed system exhibited higher quality because of increased protein concentration and decreased salts concentration. Energetic assessment indicated that application of this novel process enhanced the net energy balance ratio from 1.26 (conventional process) to 1.76. In conclusion, the proposed system possessed technical advantage over the conventional process for corn fuel ethanol production. PMID:24077154

  8. Improving electricity production in tubular microbial fuel cells through optimizing the anolyte flow with spiral spacers.

    PubMed

    Zhang, Fei; Ge, Zheng; Grimaud, Julien; Hurst, Jim; He, Zhen

    2013-04-01

    The use of spiral spacers to create a helical flow for improving electricity generation in microbial fuel cells (MFCs) was investigated in both laboratory and on-site tests. The lab tests found that the MFC with the spiral spacers produced more electricity than the one without the spiral spacers at different recirculation rates or organic loading rates, likely due to the improved transport/distribution of ions and electron mediators instead of the substrates because the organic removal efficiency was not obviously affected by the presence of the spiral spacers. The energy production in the MFC with the spiral spacers reached 0.071 or 0.073 kWh/kg COD in either vertical or horizontal installment. The examination of the MFCs installed in an aeration tank of a municipal wastewater treatment plant confirmed the advantage of using the spiral spacers. Those results demonstrate that spiral spacers could be an effective approach to improve energy production in MFCs.

  9. Fission product Pd-SiC interaction in irradiated coated particle fuels

    SciTech Connect

    Tiegs, T.N.

    1980-04-01

    Silicon carbide is the main barrier to fission product release from coated particle fuels. Consequently, degradation of the SiC must be minimized. Electron microprobe analysis has identified that palladium causes corrosion of the SiC in irradiated coated particles. Further ceramographic and electron microprobe examinations on irradiated particles with kernels ranging in composition from UO/sub 2/ to UC/sub 2/, including PuO/sub 2 -x/ and mixed (Th, Pu) oxides, and in enrichment from 0.7 to 93.0% /sup 235/U revealed that temperature is the major factor affecting the penetration rate of SiC by Pd. The effects of kernel composition, Pd concentration, other fission products, and SiC properties are secondary.

  10. Metallic plate corrosion and uptake of corrosion products by nafion in polymer electrolyte membrane fuel cells.

    PubMed

    Bozzini, Benedetto; Gianoncelli, Alessandra; Kaulich, Burkhard; Kiskinova, Maya; Prasciolu, Mauro; Sgura, Ivonne

    2010-07-19

    Nafion contamination by ferrous-alloy corrosion products, resulting in dramatic drops of the Ohmic potential, is a suspected major failure mode of polymer electrolyte membrane fuel cells that make use of metallic bipolar plates. This study demonstrates the potential of scanning transmission X-ray microscopy combined with X-ray absorption and fluorescence microspectroscopy for exploring corrosion processes of Ni and Fe electrodes in contact with a hydrated Nafion film in a thin-layer cell. The imaged morphology changes of the Ni and Fe electrodes and surrounding Nafion film that result from relevant electrochemical processes are correlated to the spatial distribution, local concentration, and chemical state of Fe and Ni species. The X-ray fluorescence maps and absorption spectra, sampled at different locations, show diffusion of corrosion products within the Nafion film only in the case of the Fe electrodes, whereas the Ni electrodes appear corrosion resistant. PMID:20564283

  11. Process development of fuel ethanol production from lignocellulosic sugars using gentically engineered yeasts

    SciTech Connect

    Krishnan, M.S.; Xia, Y.; Ho, N.W.Y.

    1996-10-01

    Lignocellulosic biomass is an ideal feedstock for the large scale manufacture of fuel ethanol. Glucose and xylose represent the two major fermentable sugars in lignocellulosic hydrolysates and efficient fermentation of both these sugars is essential for the economical production of fuel ethanol. In our laboratory, a genetically engineered yeast 1400 (pLNH33) has been developed which can ferment glucose and xylose simultaneously to ethanol. This recombinant yeast has a very high ethanol tolerance (13.6% w/v) which allows high ethanol concentrations to accumulate in the fermentation medium, thus reducing downstream processing mu significantly. For large scale application of this genetically engineered cell culture, the fermentation kinetics have been investigated. We have studied the effects of substrate and product inhibition for both the host post 1400 and the engineered yeast 1400 (pLNH33) during fermentation of glucose, xylose and mixtures of glucose and xylose. Plasmid instability is an important factor influencing cell culture scale up. This aspect w investigated in selective, non-selective and partially selective fermentation media and the results will be reported in this paper. Based on these kinetic studies, a model has been developed which can simulate the fermentation of glucose and xylose to ethanol using the genetically engineered yeast 1400 (pLNH33), in both batch and continuous cultures.

  12. Feasibility of converting a sugar beet plant to fuel ethanol production

    SciTech Connect

    Hammaker, G S; Pfost, H B; David, M L; Marino, M L

    1981-04-01

    This study was performed to assess the feasibility of producing fuel ethanol from sugar beets. Sugar beets are a major agricultural crop in the area and the beet sugar industry is a major employer. There have been some indications that increasing competition from imported sugar and fructose sugar produced from corn may lead to lower average sugar prices than have prevailed in the past. Fuel ethanol might provide an attractive alternative market for beets and ethanol production would continue to provide an industrial base for labor. Ethanol production from beets would utilize much of the same field and plant equipment as is now used for sugar. It is logical to examine the modification of an existing sugar plant from producing sugar to ethanol. The decision was made to use Great Western Sugar Company's plant at Mitchell as the example plant. This plant was selected primarily on the basis of its independence from other plants and the availability of relatively nearby beet acreage. The potential feedstocks assessed included sugar beets, corn, hybrid beets, and potatoes. Markets were assessed for ethanol and fermentation by-products saleability. Investment and operating costs were determined for each prospective plant. Plants were evaluated using a discounted cash flow technique to obtain data on full production costs. Environmental, health, safety, and socio-economic aspects of potential facilities were examined. Three consulting engineering firms and 3 engineering-construction firms are considered capable of providing the desired turn-key engineering design and construction services. It was concluded that the project is technically feasible. (DMC)

  13. A Chironomus tentans bioassay for testing synthetic fuel products and effluents, with data on acridine and quinoline

    SciTech Connect

    Cushman, R.M.; McKamey, M.I.

    1981-05-01

    As part of a programme to evaluate the environmental effects of synthetic fuel products and effluents, a series of tests is being used to measure the toxicity of these products and of representative pure compounds to aquatic organisms. A method was developed using the midge, Chironomus tentans. Unlike previous C. tentans bioassays the procedure excludes effects of organic substrates, feeding, aeration and light. The midges were treated in glass beakers of filtered well water on a glass wool substrate. Calculated 48-hour LC/sub 50/ values for typical synthetic fuel products were acridine, 1.96 mg/l and quinoline, 57.2 mg/l.

  14. Evaluation of electricity production from alkaline pretreated sludge using two-chamber microbial fuel cell.

    PubMed

    Xiao, Benyi; Yang, Fang; Liu, Junxin

    2013-06-15

    Electricity production from alkaline pretreated sludge was evaluated using a two-chamber microbial fuel cell (MFC). The electricity production was found to be stable over a long period of time (approximately 17 d) with voltage outputs and power densities of 0.47-0.52 V and 46.80-55.88 mW/m(2), respectively. The anode resistance was the main internal resistance (73.2%) of MFC in the stable stage. Most soluble organic matters (proteins and carbohydrates) in the anode chamber were first degraded and converted into volatile fatty acids (0-15 d), which were then degraded and converted into electricity and methane (15-29 d). The insoluble organics were solubilized thereby decreasing the sludge concentration and reducing the sludge mass. Methane was produced in the anode chamber owing to the growth of methanogens, which did not obviously affect the electricity production. The change in humic-like substances displayed a positive correlation with the electricity production of the MFC. Microbial analysis showed that methanogens and electricity-producing bacteria co-existed mostly on the surface as well as inside the anode. Decreasing the anode resistance and increasing the anode utilization could enhance the electricity production.

  15. Biodiesel biorefinery: opportunities and challenges for microbial production of fuels and chemicals from glycerol waste.

    PubMed

    Almeida, João R M; Fávaro, Léia C L; Quirino, Betania F

    2012-01-01

    The considerable increase in biodiesel production worldwide in the last 5 years resulted in a stoichiometric increased coproduction of crude glycerol. As an excess of crude glycerol has been produced, its value on market was reduced and it is becoming a "waste-stream" instead of a valuable "coproduct". The development of biorefineries, i.e. production of chemicals and power integrated with conversion processes of biomass into biofuels, has been singled out as a way to achieve economically viable production chains, valorize residues and coproducts, and reduce industrial waste disposal. In this sense, several alternatives aimed at the use of crude glycerol to produce fuels and chemicals by microbial fermentation have been evaluated. This review summarizes different strategies employed to produce biofuels and chemicals (1,3-propanediol, 2,3-butanediol, ethanol, n-butanol, organic acids, polyols and others) by microbial fermentation of glycerol. Initially, the industrial use of each chemical is briefly presented; then we systematically summarize and discuss the different strategies to produce each chemical, including selection and genetic engineering of producers, and optimization of process conditions to improve yield and productivity. Finally, the impact of the developments obtained until now are placed in perspective and opportunities and challenges for using crude glycerol to the development of biodiesel-based biorefineries are considered. In conclusion, the microbial fermentation of glycerol represents a remarkable alternative to add value to the biodiesel production chain helping the development of biorefineries, which will allow this biofuel to be more competitive. PMID:22809320

  16. Catalytic pyrolysis-gc/ms of spirulina: evaluation of a highly proteinaceous biomass source for production of fuels and chemicals

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Pyrolysis of microalgae offers a pathway towards the production of compounds derived from the thermal decomposition of triglycerides, proteins as well as lignocelluloses and their combinations thereof. When catalytically induced, this could lead to the production of fuels and chemicals including aro...

  17. Chemical thermodynamics of Cs and Te fission product interactions in irradiated LMFBR mixed-oxide fuel pins

    NASA Astrophysics Data System (ADS)

    Adamson, M. G.; Aitken, E. A.; Lindemer, T. B.

    1985-02-01

    A combination of fuel chemistry modelling and equilibrium thermodynamic calculations has been used to predict the atom ratios of Cs and Te fission products (Cs:Te) that find their way into the fuel-cladding interface region of irradiated stainless steel-clad mixed-oxide fast breeder reactor fuel pins. It has been concluded that the ratio of condensed, chemically-associated Cs and Te in the interface region,Čs:Te, which in turn determines the Te activity, is controlled by an equilibrium reaction between Cs 2Te and the oxide fuel, and that the value of Čs:Te is, depending on fuel 0:M, either equal to or slightly less than 2:1. Since Cs and Te fission products are both implicated as causative agents in FCCI (fission product-assisted inner surface attack of stainless steel cladding) and in FPLME (fission product-assisted liquid metal embrittlement of AISI-Type 316), the observed out-of-pile Cs:Te thresholds for FCCI (4˜:1) and FPLME (2˜:1) have been rationalized in terms of Cs:Te thermochemistry and phase equilibria. Also described in the paper is an updated chemical evolution model for reactive/volatile fission product behavior in irradiated oxide pins.

  18. Fuel from Tobacco and Arundo Donax: Synthetic Crop for Direct Drop-in Biofuel Production through Re-routing the Photorespiration Intermediates and Engineering Terpenoid Pathways

    SciTech Connect

    2012-02-15

    PETRO Project: Biofuels offer renewable alternatives to petroleum-based fuels that reduce net greenhouse gas emissions to nearly zero. However, traditional biofuels production is limited not only by the small amount of solar energy that plants convert through photosynthesis into biological materials, but also by inefficient processes for converting these biological materials into fuels. Farm-ready, non-food crops are needed that produce fuels or fuel-like precursors at significantly lower costs with significantly higher productivity. To make biofuels cost-competitive with petroleum-based fuels, biofuels production costs must be cut in half.

  19. Gridded Uncertainty Maps of Fossil Fuel Carbon Dioxide Emissions: A New Data Product

    NASA Astrophysics Data System (ADS)

    Andres, R. J.; Boden, T.

    2014-12-01

    With the publication of a new assessment of the uncertainty associated with the mass of fossil fuel carbon dioxide (FFCO2) emissions (2014, Tellus B, 66, 23616, doi:10.3402/tellusb.v66.23616), it is now possible to extend that work with a gridded map of fossil fuel emission uncertainties. The new data product was created to be paired with the long-used, Carbon Dioxide Information Analysis Center (CDIAC), emission year 1751-present, one degree latitude by one degree longitude (1x1) mass of emissions data product (http://cdiac.ornl.gov/epubs/ndp/ndp058/ndp058_v2013.html). Now, for the first time, data users will have FFCO2 emission information that represents both mass and uncertainty, each of which varies in both time and space. The new data product was constructed by examining the individual uncertainties in each of the input data sets to the gridded mass maps and then combining these individual uncertainties into an overall uncertainty for the mass maps. The input data sets include a table of the mass of FFCO2 emissions by country and year, the one degree geographic map of emissions which includes changing borders on an annual time scale and ties the mass of emissions to location, and the one degree population proxy used to distribute the mass of emissions within each country. As the three input data sets are independent of each other, their combination for the overall uncertainty is accomplished by a simple square root of the sum of the squares procedure. The resulting uncertainty data product is gridded at 1x1 and exactly overlays the 1x1 mass emission maps. The default temporal resolution is annual, but a companion product is also available at monthly time scales. The monthly uncertainty product uses the same input data sets, but the mass uncertainty is scaled as described in the monthly mass product description paper (2011, Tellus B, 63:309-327, doi: 10.1111/j.1600-0889.2011.00530.x). The gridded uncertainty maps cover emission year 1950 to 2010. The start

  20. Coupling microbial fuel cells with a membrane photobioreactor for wastewater treatment and bioenergy production.

    PubMed

    Tse, Hei Tsun; Luo, Shuai; Li, Jian; He, Zhen

    2016-11-01

    Microbial fuel cells (MFCs) and membrane photobioreactors are two emerging technologies for simultaneous wastewater treatment and bioenergy production. In this study, those two technologies were coupled to form an integrated treatment system, whose performance was examined under different operating conditions. The coupled system could achieve 92-97 % removal of soluble chemical oxygen demand (SCOD) and nearly 100 % removal of ammonia. Extending the hydraulic retention time (HRT) of the membrane photobioreactor to 3.0 days improved the production of algal biomass from 44.4 ± 23.8 to 133.7 ± 12.9 mg L(-1) (based on the volume of the treated water). When the MFCs were operated in a loop mode, their effluent (which was the influent to the algal reactor) contained nitrate and had a high pH, leading to the decreased algal production in the membrane photobioreactor. Energy analysis showed that the energy consumption was mainly due to the recirculation of the anolyte and the catholyte in the MFCs and that decreasing the recirculation rates could significantly reduce energy consumption. The energy production was dominated by indirect electricity generation from algal biomass. The highest energy production of 0.205 kWh m(-3) was obtained with the highest algal biomass production, resulting in a theoretically positive energy balance of 0.033 kWh m(-3). Those results have demonstrated that the coupled system could be an alternative approach for energy-efficient wastewater treatment and using wastewater effluent for algal production. PMID:27318829

  1. Coupling microbial fuel cells with a membrane photobioreactor for wastewater treatment and bioenergy production.

    PubMed

    Tse, Hei Tsun; Luo, Shuai; Li, Jian; He, Zhen

    2016-11-01

    Microbial fuel cells (MFCs) and membrane photobioreactors are two emerging technologies for simultaneous wastewater treatment and bioenergy production. In this study, those two technologies were coupled to form an integrated treatment system, whose performance was examined under different operating conditions. The coupled system could achieve 92-97 % removal of soluble chemical oxygen demand (SCOD) and nearly 100 % removal of ammonia. Extending the hydraulic retention time (HRT) of the membrane photobioreactor to 3.0 days improved the production of algal biomass from 44.4 ± 23.8 to 133.7 ± 12.9 mg L(-1) (based on the volume of the treated water). When the MFCs were operated in a loop mode, their effluent (which was the influent to the algal reactor) contained nitrate and had a high pH, leading to the decreased algal production in the membrane photobioreactor. Energy analysis showed that the energy consumption was mainly due to the recirculation of the anolyte and the catholyte in the MFCs and that decreasing the recirculation rates could significantly reduce energy consumption. The energy production was dominated by indirect electricity generation from algal biomass. The highest energy production of 0.205 kWh m(-3) was obtained with the highest algal biomass production, resulting in a theoretically positive energy balance of 0.033 kWh m(-3). Those results have demonstrated that the coupled system could be an alternative approach for energy-efficient wastewater treatment and using wastewater effluent for algal production.

  2. Environmentally sustainable production of food, feed and fuel from natural resources in the tropics.

    PubMed

    Preston, T Reg

    2009-10-01

    Responding to the challenges posed by global warming, peak oil and biofuels will require a paradigm shift in the practice of agriculture and in the role of live stock within the farming system. Farming systems should aim at maximizing plant biomass production from locally available diversified resources, processing of the biomass on farm to provide food, feed and energy and recycling of all waste materials. The approach that is the subject of this paper is that the generation of electricity can be a by-product of food/feed production. The concept is the fractionation of biomass into inedible cell wall material that can be converted to an inflammable gas by gasification, the gas in turn being the source of fuel for internal combustion engines driving electrical generators. The cell contents and related structures such as tree leaves are used as human food or animal feed. As well as providing food and feed the model is highly appropriate for decentralized small scale production of electricity in rural areas. It also offers opportunities for sequestration of carbon in the form of biochar the solid residue remaining after gasification of the biomass.

  3. Environmentally sustainable production of food, feed and fuel from natural resources in the tropics.

    PubMed

    Preston, T Reg

    2009-08-01

    Responding to the challenges posed by global warming, peak oil and biofuels will require a paradigm shift in the practice of agriculture and in the role of live stock within the farming system. Farming systems should aim at maximizing plant biomass production from locally available diversified resources, processing of the biomass on farm to provide food, feed and energy and recycling of all waste materials. The approach that is the subject of this paper is that the generation of electricity can be a by-product of food/feed production. The concept is the fractionation of biomass into inedible cell wall material that can be converted to an inflammable gas by gasification, the gas in turn being the source of fuel for internal combustion engines driving electrical generators. The cell contents and related structures such as tree leaves are used as human food or animal feed. As well as providing food and feed the model is highly appropriate for decentralized small scale production of electricity in rural areas. It also offers opportunities for sequestration of carbon in the form of biochar the solid residue remaining after gasification of the biomass.

  4. Strategic network design of Java Island fuel supply with production-transportation solution

    NASA Astrophysics Data System (ADS)

    Dianawati, Fauzia; Farizal, -; Surjandari, Isti; Marzuli, Rully

    2011-10-01

    This study aims to find more efficient supply network, from refineries / imports to fuel terminal, which still uses the Tanker, Tank Trucks or Rail Tank Wagon with an alternative pipeline that are considered more efficient than other transport modes, as well as gaining pipeline transportation network optimization analysis tailored to the capabilities/ capacity of refinery production and capacity of the pipe mode. With the complexity of the number of 3 point sources of supply, 19 destination of terminal, 4 kinds of products and 4 types of transport modes, transport-production model modified by adding multi-modal transport and investment costs of new pipeline. Then coded in Lingo program which adopts Branch & Bound technique and input the processed data in order to obtain an optimal distribution pattern produced the lowest distribution costs. This B&B solution was also compared with SCO solution which is a metaheuristic method. The results of this study lead to the development of new modes of pipeline connections in amount of 4 alternatives, generated from the optimal solution, but still potentially earned savings of about IDR 1 Trillion per year from cost-efficiency of product procurement and transportation costs.

  5. Elemental balance of SRF production process: solid recovered fuel produced from municipal solid waste.

    PubMed

    Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Oinas, Pekka

    2016-01-01

    In the production of solid recovered fuel (SRF), certain waste components have excessive influence on the quality of product. The proportion of rubber, plastic (hard) and certain textiles was found to be critical as to the elemental quality of SRF. The mass flow of rubber, plastic (hard) and textiles (to certain extent, especially synthetic textile) components from input waste stream into the output streams of SRF production was found to play the decisive role in defining the elemental quality of SRF. This paper presents the mass flow of polluting and potentially toxic elements (PTEs) in SRF production. The SRF was produced from municipal solid waste (MSW) through mechanical treatment (MT). The results showed that of the total input chlorine content to process, 55% was found in the SRF and 30% in reject material. Of the total input arsenic content, 30% was found in the SRF and 45% in fine fraction. In case of cadmium, lead and mercury, of their total input content to the process, 62%, 38% and 30%, respectively, was found in the SRF. Among the components of MSW, rubber material was identified as potential source of chlorine, containing 8.0 wt.% of chlorine. Plastic (hard) and textile components contained 1.6 and 1.1. wt.% of chlorine, respectively. Plastic (hard) contained higher lead and cadmium content compared with other waste components, i.e. 500 mg kg(-1) and 9.0 mg kg(-1), respectively.

  6. Impacts of ruminal microorganisms on the production of fuels: how can we intercede from the outside?

    PubMed

    Weimer, Paul J; Kohn, Richard A

    2016-04-01

    The ruminal microbiome rapidly converts plant biomass to short-chain fatty acids (SCFA) that nourish the ruminant animal host. Because of its high species diversity, functional redundancy, and ease of extraruminal cultivation, this mixed microbial community is a particularly accomplished practitioner of the carboxylate platform for producing fuels and chemical precursors. Unlike reactor microbiomes derived from anaerobic digesters or sediments, the ruminal community naturally produces high concentrations of SCFA, with only modest methane production owing to the absence of both proton-reducing acetogens and aceticlastic methanogens. The extraruminal fermentation can be improved by addition of ethanol or lactate product streams, particularly in concert with reverse β-oxidizing bacteria (e.g., Clostridium kluyveri or Megasphaera elsdenii) that facilitate production of valeric and caproic acids. Application of fundamental principles of thermodynamics allows identification of optimal conditions for SCFA chain elongation, as well as discovery of novel synthetic capabilities (e.g., medium-chain alcohol and alkane production) by this mixed culture system.

  7. Environmentally sustainable production of food, feed and fuel from natural resources in the tropics.

    PubMed

    Preston, T Reg

    2009-10-01

    Responding to the challenges posed by global warming, peak oil and biofuels will require a paradigm shift in the practice of agriculture and in the role of live stock within the farming system. Farming systems should aim at maximizing plant biomass production from locally available diversified resources, processing of the biomass on farm to provide food, feed and energy and recycling of all waste materials. The approach that is the subject of this paper is that the generation of electricity can be a by-product of food/feed production. The concept is the fractionation of biomass into inedible cell wall material that can be converted to an inflammable gas by gasification, the gas in turn being the source of fuel for internal combustion engines driving electrical generators. The cell contents and related structures such as tree leaves are used as human food or animal feed. As well as providing food and feed the model is highly appropriate for decentralized small scale production of electricity in rural areas. It also offers opportunities for sequestration of carbon in the form of biochar the solid residue remaining after gasification of the biomass. PMID:19728132

  8. Environmentally sustainable production of food, feed and fuel from natural resources in the tropics.

    PubMed

    Preston, T Reg

    2009-08-01

    Responding to the challenges posed by global warming, peak oil and biofuels will require a paradigm shift in the practice of agriculture and in the role of live stock within the farming system. Farming systems should aim at maximizing plant biomass production from locally available diversified resources, processing of the biomass on farm to provide food, feed and energy and recycling of all waste materials. The approach that is the subject of this paper is that the generation of electricity can be a by-product of food/feed production. The concept is the fractionation of biomass into inedible cell wall material that can be converted to an inflammable gas by gasification, the gas in turn being the source of fuel for internal combustion engines driving electrical generators. The cell contents and related structures such as tree leaves are used as human food or animal feed. As well as providing food and feed the model is highly appropriate for decentralized small scale production of electricity in rural areas. It also offers opportunities for sequestration of carbon in the form of biochar the solid residue remaining after gasification of the biomass. PMID:19011987

  9. Impacts of ruminal microorganisms on the production of fuels: how can we intercede from the outside?

    PubMed

    Weimer, Paul J; Kohn, Richard A

    2016-04-01

    The ruminal microbiome rapidly converts plant biomass to short-chain fatty acids (SCFA) that nourish the ruminant animal host. Because of its high species diversity, functional redundancy, and ease of extraruminal cultivation, this mixed microbial community is a particularly accomplished practitioner of the carboxylate platform for producing fuels and chemical precursors. Unlike reactor microbiomes derived from anaerobic digesters or sediments, the ruminal community naturally produces high concentrations of SCFA, with only modest methane production owing to the absence of both proton-reducing acetogens and aceticlastic methanogens. The extraruminal fermentation can be improved by addition of ethanol or lactate product streams, particularly in concert with reverse β-oxidizing bacteria (e.g., Clostridium kluyveri or Megasphaera elsdenii) that facilitate production of valeric and caproic acids. Application of fundamental principles of thermodynamics allows identification of optimal conditions for SCFA chain elongation, as well as discovery of novel synthetic capabilities (e.g., medium-chain alcohol and alkane production) by this mixed culture system. PMID:26879958

  10. Elemental balance of SRF production process: solid recovered fuel produced from municipal solid waste.

    PubMed

    Nasrullah, Muhammad; Vainikka, Pasi; Hannula, Janne; Hurme, Markku; Oinas, Pekka

    2016-01-01

    In the production of solid recovered fuel (SRF), certain waste components have excessive influence on the quality of product. The proportion of rubber, plastic (hard) and certain textiles was found to be critical as to the elemental quality of SRF. The mass flow of rubber, plastic (hard) and textiles (to certain extent, especially synthetic textile) components from input waste stream into the output streams of SRF production was found to play the decisive role in defining the elemental quality of SRF. This paper presents the mass flow of polluting and potentially toxic elements (PTEs) in SRF production. The SRF was produced from municipal solid waste (MSW) through mechanical treatment (MT). The results showed that of the total input chlorine content to process, 55% was found in the SRF and 30% in reject material. Of the total input arsenic content, 30% was found in the SRF and 45% in fine fraction. In case of cadmium, lead and mercury, of their total input content to the process, 62%, 38% and 30%, respectively, was found in the SRF. Among the components of MSW, rubber material was identified as potential source of chlorine, containing 8.0 wt.% of chlorine. Plastic (hard) and textile components contained 1.6 and 1.1. wt.% of chlorine, respectively. Plastic (hard) contained higher lead and cadmium content compared with other waste components, i.e. 500 mg kg(-1) and 9.0 mg kg(-1), respectively. PMID:26608898

  11. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect

    Gerald P. Huffman

    2006-03-30

    Professors and graduate students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and hydrocarbon gases and liquids produced from coal. An Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center, and Tier Associates provides guidance on the practicality of the research. The current report summarizes the results obtained in this program during the period October 1, 2002 through March 31, 2006. The results are presented in detailed reports on 16 research projects headed by professors at each of the five CFFS Universities and an Executive Summary. Some of the highlights from these results are: (1) Small ({approx}1%) additions of acetylene or other alkynes to the Fischer-Tropsch (F-T) reaction increases its yield, causes chain initiation, and promotes oxygenate formation. (2) The addition of Mo to Fe-Cu-K/AC F-T catalysts improves catalyst lifetime and activity. (3) The use of gas phase deposition to place highly dispersed metal catalysts on silica or ceria aerogels offers promise for both the F-T and the water-gas shift WGS reactions. (4) Improved activity and selectivity are exhibited by Co F-T catalysts in supercritical hexane. (5) Binary Fe

  12. Chemical Characterization and Reactivity Testing of Fuel-Oxidizer Reaction Product (Test Report)

    NASA Technical Reports Server (NTRS)

    1996-01-01

    The product of incomplete reaction of monomethylhydrazine (MMH) and nitrogen tetroxide (NTO) propellants, or fuel-oxidizer reaction product (FORP), has been hypothesized as a contributory cause of an anomaly which occurred in the chamber pressure (PC) transducer tube on the Reaction Control Subsystem (RCS) aft thruster 467 on flight STS-51. A small hole was found in the titanium-alloy PC tube at the first bend below the pressure transducer. It was surmised that the hole may have been caused by heat and pressure resulting from ignition of FORP. The NASA Johnson Space Center (JSC) White Sands Test Facility (WSTF) was requested to define the chemical characteristics of FORP, characterize its reactivity, and simulate the events in a controlled environment which may have lead to the Pc-tube failure. Samples of FORP were obtained from the gas-phase reaction of MMH with NTO under laboratory conditions, the pulsed firings of RCS thrusters with modified PC tubes using varied oxidizer or fuel lead times, and the nominal RCS thruster firings at WSTF and Kaiser-Marquardt. Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), accelerating rate calorimetry (ARC), ion chromatography (IC), inductively coupled plasma (ICP) spectrometry, thermogravimetric analysis (TGA) coupled to FTIR (TGA/FTIR), and mechanical impact testing were used to qualitatively and quantitatively characterize the chemical, thermal, and ignition properties of FORP. These studies showed that the composition of FORP is variable but falls within a limited range of compositions that depends on the fuel loxidizer ratio at the time of formation, composition of the post-formation atmosphere (reducing or oxidizing), and reaction or postreaction temperature. A typical composition contains methylhydrazinium nitrate (MMHN), ammonium nitrate (AN), methylammonium nitrate (MAN), and trace amounts of hydrazinium nitrate and 1,1-dimethylhydrazinium nitrate. The thermal decomposition

  13. Basic mechanisms of photosynthesis and applications to improved production and conversion of biomass to fuels and chemical products

    SciTech Connect

    El-Sayed, M.; Greenbaum, E.; Wasielewski, M.

    1996-09-01

    Natural photosynthesis, the result of 3.5 billion years of evolutionary experimentation, is the best proven, functional solar energy conversion technology. It is responsible for filling the vast majority of humanity`s energy, nutritional, and materials needs. Understanding the basic physical chemical principles underlying photosynthesis as a working model system is vital to further exploitation of this natural technology. These principles can be used to improve or modify natural photosynthesis so that it is more efficient or so that it can produce unusual products such as hydrogen, methane, methanol, ethanol, diesel fuel substitutes, biodegradable materials, or other high value chemical products. Principles garnered from the natural process can also be used to design artificial photosynthetic devices that employ analogs of natural antenna and reaction center function, self-assembly and repair concepts, photoinduced charge transfer processes, photoprotection, and dark reactions that facilitate catalytic action to convert light into, useful chemical or electrical energy. The present broad understanding of many structural and functional aspects of photosynthesis has resulted from rapid recent research progress. X-ray structures of several key photosynthetic reaction centers and antenna systems are available, and the overall principles controlling photoinduced energy and electron transfer are being established.

  14. Recent advances in microbial production of fuels and chemicals using tools and strategies of systems metabolic engineering.

    PubMed

    Cho, Changhee; Choi, So Young; Luo, Zi Wei; Lee, Sang Yup

    2015-11-15

    The advent of various systems metabolic engineering tools and strategies has enabled more sophisticated engineering of microorganisms for the production of industrially useful fuels and chemicals. Advances in systems metabolic engineering have been made in overproducing natural chemicals and producing novel non-natural chemicals. In this paper, we review the tools and strategies of systems metabolic engineering employed for the development of microorganisms for the production of various industrially useful chemicals belonging to fuels, building block chemicals, and specialty chemicals, in particular focusing on those reported in the last three years. It was aimed at providing the current landscape of systems metabolic engineering and suggesting directions to address future challenges towards successfully establishing processes for the bio-based production of fuels and chemicals from renewable resources.

  15. Recovery of Navy distillate fuel from reclaimed product. Volume II. Literature review

    SciTech Connect

    Brinkman, D.W.; Whisman, M.L.

    1984-11-01

    In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). This first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in which experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 references and abstracts. This appendix, because of its volume, has been published separately as Volume 2.

  16. Recovery of Navy distillate fuel from reclaimed product. Volume I. Technical discussion

    SciTech Connect

    Brinkman, D.W.; Whisman, M.L.

    1984-11-01

    In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). The first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in which experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 referenvces and abstracts. This appendix, because of its volume, has been published separately as Volume 2. 18 figures, 4 tables.

  17. The Elephant in the Room: Dealing with Carbon Emissions from Synthetic Transportation Fuels Production

    SciTech Connect

    Parker, Graham B.; Dahowski, Robert T.

    2007-07-11

    Carbon dioxide (CO2), produced by conversion of hydrocarbons to energy, primarily via fossil fuel combustion, is one of the most ubiquitous and significant greenhouse gases (GHGs). Concerns over climate change precipitated by rising atmospheric GHG concentrations have prompted many industrialized nations to begin adopting limits on emissions to inhibit increases in atmospheric CO2 levels. The United Nations Framework Convention on Climate Change states as a key goal the stabilization of atmospheric CO2 at a level that prevents “dangerous anthropogenic interference” with the planet’s climate systems. This will require sharply reducing emissions growth rates in developing nations, and reducing CO2 emissions in the industrialized world to half current rates in the next 50 years. And ultimately, stabilization will require that annual emissions drop to almost zero.Recently, there has been interest in producing synthetic transportation fuels via coal-to-liquids (CTL) production, particularly in countries where there is an abundant supply of domestic coal, including the United States. This paper provides an overview of the current state of CTL technologies and deployment, a discussion of costs and technical requirements for mitigating the CO2 impacts associated with a CTL facility, and the challenges facing the CTL industry as it moves toward maturity.

  18. Simultaneous wastewater treatment, electricity generation and biomass production by an immobilized photosynthetic algal microbial fuel cell.

    PubMed

    He, Huanhuan; Zhou, Minghua; Yang, Jie; Hu, Youshuang; Zhao, Yingying

    2014-05-01

    A photosynthetic algal microbial fuel cell (PAMFC) was constructed by the introduction of immobilized microalgae (Chlorella vulgaris) into the cathode chamber of microbial fuel cells to fulfill electricity generation, biomass production and wastewater treatment. The immobilization conditions, including the concentration of immobilized matrix, initial inoculation concentration and cross-linking time, were investigated both for the growth of C. vulgaris and power generation. It performed the best at 5 % sodium alginate and 2 % calcium chloride as immobilization matrix, initial inoculation concentration of 10(6) cell/mL and cross-linking time of 4 h. Our findings indicated that C. vulgaris immobilization was an effective and promising approach to improve the performance of PAMFC, and after optimization the power density and Coulombic efficiency improved by 258 and 88.4 %, respectively. Important parameters such as temperature and light intensity were optimized on the performance. PAMFC could achieve a COD removal efficiency of 92.1 %, and simultaneously the maximum power density reached 2,572.8 mW/m(3) and the Coulombic efficiency was 14.1 %, under the light intensity of 5,000 lux and temperature at 25 °C.

  19. Liquid fuels production from biomass. Progress report No. 10, October 1-December 31, 1979

    SciTech Connect

    Sanderson, J.E.; Levy, P.F.; Wise, D.L.; Nabor, M.R.; Molyneaux, M.S.; Hughes, C.A.

    1980-02-01

    It was found that marine algae could be converted to higher aliphatic organic acids and that these acids could be readily removed from the fermentation broth by membrane or liquid-liquid extraction. It was then proposed to convert these higher organic acids via Kolbe Electrolysis to aliphatic hydrocarbons, which may be used as a diesel fuel. A coenzyme M analogue, 2-bromoethanesulfonic acid has been shown to be an effective suppressor of methane in nonsterile anaerobic fermentation of cellulosic substrates. Preliminary experiments have also been completed utilizing corn meal in which 2-bromoethanesulfonic acid and carbon monoxide were both found to be effective methane suppressors. An analysis of the energy outputs and requirements for the production of liquid hydrocarbon fuel from corn has been performed. As a means of expanding the number of potential substrates, pretreatment schemes are being investigated. A tapered auger device has been designed and built which has been demonstrated on the bench to be effective for adding substrate and removing residue in a continuous manner from a fixed packed bed fermenter. A solvent extractor system using kerosene as the nonaqueous phase has been constructed and is currently in operation in series with the 300 liter fixed packed bed fermenter. Although additional work is required to optimize the electrolysis process, the electrolytic oxidation of organic acids produced in the 300 liter fixed packed bed fermenter is operating with a favorable energy balance of 6/1 based on the applied potential.

  20. The production of fuels and chemicals from food processing wastes & cellulosics. Final research report

    SciTech Connect

    Dale, M.C.; Okos, M.; Burgos, N.

    1997-06-15

    High strength food wastes of about 15-20 billion pounds solids are produced annually by US food producers. Low strength food wastes of 5-10 billion pounds/yr. are produced. Estimates of the various components of these waste streams are shown in Table 1. Waste paper/lignocellulosic crops could produce 2 to 5 billion gallons of ethanol per year or other valuable chemicals. Current oil imports cost the US about $60 billion dollars/yr. in out-going balance of trade costs. Many organic chemicals that are currently derived from petroleum can be produced through fermentation processes. Petroleum based processes have been preferred over biotechnology processes because they were typically cheaper, easier, and more efficient. The technologies developed during the course of this project are designed to allow fermentation based chemicals and fuels to compete favorably with petroleum based chemicals. Our goals in this project have been to: (1) develop continuous fermentation processes as compared to batch operations; (2) combine separation of the product with the fermentation, thus accomplishing the twin goals of achieving a purified product from a fermentation broth and speeding the conversion of substrate to product in the fermentation broth; (3) utilize food or cellulosic waste streams which pose a current cost or disposal problem as compared to high cost grains or sugar substrates; (4) develop low energy recovery methods for fermentation products; and finally (5) demonstrate successful lab scale technologies on a pilot/production scale and try to commercialize the processes. The scale of the wastes force consideration of {open_quotes}bulk commodity{close_quotes} type products if a high fraction of the wastes are to be utilized.