Sample records for evening primrose oil

  1. Evening Primrose Oil

    MedlinePlus

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  2. Compare the effect of flaxseed, evening primrose oil and Vitamin E on duration of periodic breast pain

    PubMed Central

    Jaafarnejad, Farzaneh; Adibmoghaddam, Elham; Emami, Seyyed Ahmad; Saki, Azadeh

    2017-01-01

    BACKGROUND: Breast periodic pain is the most common disorder of the breast which leads to consultation with knowledgeable people like a midwife. The aim of this study was to compare the therapeutic effect of flaxseed, evening primrose oil, and Vitamin E on the duration of the period of breast pain. MATERIALS AND METHODS: This study is a quasi-randomized clinical trial conducted in 2015 on ninety patients complaining of breast periodic pain referring to Gynecologic Clinics of Ghaem Hospital or residents living in dormitories of Mashhad University of Medical Sciences. Randomization was conducted based on the study environment. The first group received 30 g of powdered flaxseed, the second group received two 1000 mg capsules of evening primrose, and the third group received 1 capsule of 400 IU Vitamin E, daily and for two menstrual cycles. Cyclical breast pain was measured at the beginning and end of both intervention periods by daily subscription form of pain duration. Data analysis was performed by SPSS 16 software and Kolmogorov–Smirnov, Chi-square, Friedman, Fisher's, and one-sided ANOVA tests. The level of significance was set at P < 0.05. RESULTS: The mean duration of breast pain in flaxseed group within 2 months of intervention decreased significantly (confidence interval [CI] =95%, P = 0.006), but despite reducing the duration of pain in evening primrose oil group (CI = 95%, P = 0.058) and Vitamin E (CI = 95%, P = 0.306), this reduction was not significant. In overall, the average duration of breast pain in all three flaxseed, evening primrose oil, and Vitamin E groups was not significantly different before the intervention (CI = 95%, P = 0.286), 1 month after the intervention (CI = 95%, P = 0.195), and 2 months after the intervention (CI = 95%, P = 0.667). CONCLUSION: The use of flaxseed, evening primrose oil, or Vitamin E may reduce breast pain, and this is a significant reduction in flaxseed. PMID:29114553

  3. Polycyclic aromatic hydrocarbons content and fatty acids profile in coconut, safflower, evening primrose and linseed oils.

    PubMed

    Silva, Simone Alves da; Torres, Elizabeth A F da Silva; Almeida, Adriana Palma de; Sampaio, Geni Rodrigues

    2018-04-15

    This study aimed at evaluating the polycyclic aromatic hydrocarbons (PAHs) contamination of commercial vegetable oils and examined the identity through the fatty acids profiles. Coconut, safflower, evening primrose, and linseed oils marketed in São Paulo (Brazil) were investigated totaling 69 samples. Four PAHs, benzo[a]anthracene (BaA), chrysene (Chr), benzo[b]fluoranthene (BbF), and benzo[a]pyrene (BaP), were detected in 96% of the samples at individual levels ranging from not detected to 14.99 μg kg -1 . Chrysene was the abundant hydrocarbon found among all types of oils, with the highest median values. The results of the fatty acid profiles revealed that 43% showed different profiles according to the ones on their labels, with a higher incidence of adulteration of evening primrose oils. The maximum tolerable limits by European Regulation No. 835/2011 were exceeded for BaP in 12%, and for total 4 PAHs in 28%, with a greater contribution of adulterated samples. Copyright © 2017. Published by Elsevier Ltd.

  4. Evening primrose (Oenothera paradoxa) cake as an unconventional protein source.

    PubMed

    Golabczak, J; Py, R

    2003-01-01

    An efficient procedure of a protein isolate production from the evening primrose cake was developed. The cake is a by-product of oil extraction from seeds by using the cold pressing method. The evening primrose cake contains 22.7% of protein. Its content in the protein isolate derived from the cake is 74%. Proteins present in evening primrose seeds are rich in Trp (7%) and Met (3%), but Lys-deficient (1.3%) as compared to the FAO protein standard. Apart from the proteins, the protein isolate contains 8.5% (w/w per s.s.) dietary fiber, that negatively affects its digestibility. To enhance the bio-availability of the protein isolate, it was partially hydrolyzed with commercial preparations of trypsin and other proteases (Alcalase and Flavourzyme, Novozymes. Denmark). The most advanced proteolysis (52%) was achieved by 6 h digestion of 2% protein suspension with a mixture of Flavourzyme and Alcalase (350 and 600 U per g of protein, respectively) at 50 degrees C and pH 9.0.

  5. Immunomodulatory and therapeutic effects of Hot-nature diet and co-supplemented hemp seed, evening primrose oils intervention in multiple sclerosis patients.

    PubMed

    Rezapour-Firouzi, Soheila; Arefhosseini, Seyed Rafie; Mehdi, Farhoudi; Mehrangiz, Ebrahimi-Mamaghani; Baradaran, Behzad; Sadeghihokmabad, Elyar; Mostafaei, Somaiyeh; Fazljou, Seyed Mohammad Bagher; Torbati, Mohammad-ali; Sanaie, Sarvin; Zamani, Fatemeh

    2013-10-01

    Multiple sclerosis (MS) is the most chronic and inflammatory disorder. Because of limited efficacy and adverse side effects, identifying novel therapeutic and protective agents is important. This study was aimed to assess the potential therapeutic effects of hemp seed and evening primrose oils as well as Hot-nature dietary intervention on RRMS patients. In this double blind, randomized trial, 100 MS patients with EDSS<6 were allocated into 3 groups: "Group A" who received co-supplemented hemp seed and evening primrose oils with advised Hot-nature diet, "Group B" who received olive oil, "Group C" who received the co-supplemented oils. Mizadj, clinically EDSS and relapse rate as well as immunological factors (IL-4, IFN-γ and IL-17) were assessed at baseline and after 6 months. Mean follow-up was 180±2.9 SD days (N=65, 23 M and 42 F aged 34.25±8.07 years with disease duration 6.80±4.33 years). There was no significant difference in studies parameters at baseline. After 6 months, significant improvements in Mizadj, EDSS and relapse rate were found in the groups A and C, while the group B showed a border significant decrease in relapse rate. Immunological parameters showed improvement in groups A and C, whereas there was worsening condition for group B after the intervention. The co-supplemented hemp seed and evening primrose oils with Hot-nature diet have beneficial effects in improving of clinical score in RRMS patients which were confirmed by immunological findings. Copyright © 2013 The Authors. Published by Elsevier Ltd.. All rights reserved.

  6. Erythrocyte membrane fatty acids in multiple sclerosis patients and hot-nature dietary intervention with co-supplemented hemp-seed and evening-primrose oils.

    PubMed

    Rezapour-Firouzi, Soheila; Arefhosseini, Seyed Rafie; Ebrahimi-Mamaghani, Mehrangiz; Farhoudi, Mehdi; Baradaran, Behzad; Ali, Torbati Mohammad; Zamani, Fatemeh

    2013-01-01

    The risk of developing multiple sclerosis (MS) is associated with increased dietary intake of saturated fatty acids. For many years it has been suspected that this disease might be associated with an imbalance between unsaturated and saturated fatty acids. We determined erythrocyte membrane fatty acids levels in Hot nature dietary intervention with co-supplemented hemp seed and evening primrose oils in multiple sclerosis patients. To determine the erythrocyte membrane fatty acids levels and correlate it with expanded disability status scale (EDSS) at baseline after 6 months intervention in MS patients by gas chromatography, in this double blind, randomized trial, 100 RRMS patients with EDSS<6 were allocated into three groups: "Group A" that received co-supplemented hemp seed and evening primrose oils with advised Hot nature diet. "Group B" received olive oil and "Group C" received the co-supplemented oils. The results showed that the mean follow-up was 180 ± 2.9SD days (N=65, 23 M and 42 F aged 34.25 ± 8.07 years with disease duration of 6.80 ± 4.33 years). There was no significant difference in the study parameters at baseline. After 6 months, EDSS, Immunological parameters and the erythrocyte cell membrane with regard to specific fatty acids showed improvement in the group A and C, whereas there was worsening condition for the group B after the intervention. We concluded that Hot-nature dietary intervention with co-supplemented hemp seed and evening primrose oils caused an increase PUFAs in MS patients and improvement in the erythrocyte membrane fatty acids composition. This could be an indication of restored plasma stores, and a reflection of disease severity reduction.

  7. A comparative study on the effect of "black cohosh" and "evening primrose oil" on menopausal hot flashes.

    PubMed

    Mehrpooya, Maryam; Rabiee, Soghra; Larki-Harchegani, Amir; Fallahian, Amir-Mohammad; Moradi, Abbas; Ataei, Sara; Javad, Masoumeh Taravati

    2018-01-01

    Hot flashes are considered to be a common experience for menopausal women and they can compromise the quality of life. The objective of this study is to assess the efficacy of Cimicifuga racemosa in comparison with evening primrose oil (EPO) in postmenopausal women with menopause-related symptoms. This study was performed on 80 postmenopausal women with hot flashes. The participants were randomly divided into two groups by blocked randomization. The participants of one group received black cohosh and the other group received EPO for 8 weeks. The severity and number of hot flashes and quality of life were measured by four-point scale, and the Menopause-Specific Quality of Life (MENQOL) questionnaire at pre-intervention, 1 st , 4 th , and 8 th weeks after treatment. Data were analyzed in SPSS Version 16 using independent t -test, Chi-square, and Fisher's exact test. Average severity of hot flashes in both groups and number of hot flashes in black cohosh group in 8 th week were significantly lower than 1 st week ( P < 0.001), but number of hot flashes in primrose oil group in 8 th week showed no significant differences ( P = 0.32). The number of hot flashes and quality of life score in black cohosh arm compared to EPO showed a significant decrease in the 8 th week ( P < 0.05). All MENQOL scores were significantly improved in two groups ( P < 0.05), but the percentage of improvement in black cohosh arm was significantly superior to EPO group. Both herbs were effective in reduction of severity of hot flashes and improvement of the quality of life, but it seems that black cohosh is more effective than primrose oil because it was able to reduce the number of hot flashes too.

  8. Effect of evening primrose oil as food supplement on reproduction in the blue fox.

    PubMed

    Tauson, A H; Forsberg, M

    1991-01-01

    Addition of evening primrose oil (EPO) to a blue fox diet in the reproduction period was evaluated in an experiment with 2 groups, each of 12 male and 25 female blue foxes, regarding the effects on reproductive performance. The experiment was carried out as a field trial and the experimental period lasted from March 10 until the end of the mating season (males) or early July (females). During this period the control group was fed the standard diet of the farm and the experimental group was fed the same diet supplemented with 4.5 g EPO and 2.5 mg zinc sulphate per animal and day. An addition of 10 mg vitamin E per 500 mg EPO was made. The results were evaluated regarding male and female treatment effects. There was an increased rate of abortions in the EPO-group, but simultaneously a non-significant decrease in the frequency of barren females, resulting in a similar level of females without litters in both groups. A tendency for increased litter size in the EPO group was found, mainly as an effect of male treatment, which might indicate an effect on semen quality.

  9. Topical nonsteroidal anti-inflammatory drugs versus oil of evening primrose in the treatment of mastalgia.

    PubMed

    Qureshi, S; Sultan, N

    2005-02-01

    To compare oil of evening primrose (OEP) and topical nonsteroidal anti-inflammatory (NSAIDs) with respect to safety, effectiveness, rapidity of response, cost effectiveness and acceptability in the treatment of breast pain. An open, non-randomised, comparative study of topical (NSAI) gel versus OEP was carried out, over a period of one year. Fifty female patients attending the outpatient department with moderate to severe breast pain were given one of the two agents alternatively, after selection. Results showed that out of 25 patients treated with OEP, 64% had a clinically significant response after three months of treatment, compared with 92% with topical NSAIDs. Only one patient (4%) had side effects with OEP, while no patient had side effects with topical NSAIDs. Twenty per cent and seventy per cent showed acceptability as far as costs were concerned and mode of administration respectively, with OEP. The acceptability rate was 68% and 96% respectively, with topical NSAIDs. This study has shown topical NSAIDs to be safe, effective, rapid and acceptable mode of treatment for cyclical and non-cyclical mastalgia.

  10. Quantitative analysis of anti-inflammatory and radical scavenging triterpenoid esters in evening primrose seeds.

    PubMed

    Zaugg, Janine; Potterat, Olivier; Plescher, Andreas; Honermeier, Bernd; Hamburger, Matthias

    2006-09-06

    Lipophilic triterpenoidal esters with radical scavenging and cyclooxygenase inhibitory properties were recently found in cold-pressed, nonraffinated evening primrose oil (EPO). A quantitative assay for the analysis of 3-O-trans-caffeoyl derivatives of betulinic, morolic, and oleanolic acid in evening primrose seeds was developed and validated. Extraction efficiency >99% was achieved by means of pressurized liquid extraction with two extraction cycles and 80% (v/v) ethanol at 120 degrees C. Analysis of esters was by normal-phase high-performance liquid chromatography on a Diol column and hexane/ethyl acetate (containing 0.1% formic acid) (65:35) as the eluent. The analytes were determined without further prepurification. Seeds from defined cultures of Oenothera biennis, Oenothera lamarckiana, and Oenothera ammophila, grown under identical conditions, were analyzed. The cultures originated from seeds from eight collections in the wild and from selections from five cultivars. The content of total triterpenoidal esters in seeds varied between 1.34 and 2.78 mg/g. Three types of qualitative patterns were observed for the triterpenoidal esters. The influence of different harvest times and plant treatments was studied with the cultivar Anothera. Variations between 1.5 and 2.3 mg/g were found.

  11. Evening primrose oil or forskolin ameliorates celecoxib-enhanced upregulation of tissue factor expression in mice subjected to lipopolysaccharide-induced endotoxemia.

    PubMed

    Mosaad, Sarah M; Zaitone, Sawsan A; Ahmed, Amal A M; Abo-Elmatty, Dina M; El-Baz, Amani A; Moustafa, Yasser M

    2017-05-01

    Celecoxib, a selective cyclooxygenase-2 inhibitor, produces thrombotic events in patients predisposed to cardiovascular risk factors. One theory reported an increase in endothelial expression of tissue factor (TF) as a predisposing factor. This work explored the effect of evening primrose oil (EPO), a source of prostaglandin E1, and forskolin (a cyclic adenosine monophosphate stimulator) against the prothrombotic effect of celecoxib in mice. Lipopolysaccharide mouse model of endotoxemia was used to induce an upregulation of TF activity. Male mice received celecoxib (25 mg/kg), celecoxib plus EPO, or celecoxib plus forskolin for 4 weeks and then subjected to a prothrombotic challenge in the form of an intraperitoneal injection of lipopolysaccharide. Results showed an increase in plasma TF activity, endothelial TF expression, and thrombin-antithrombin (TAT) but lower antithrombin III (ATIII) level in mice that received celecoxib in comparison to those that received the vehicle. Adding EPO or forskolin to celecoxib regimen significantly decreased the prothrombotic effect of celecoxib. A positive correlation (r = 0.8501) was found between TF activity and TAT. Co-administration of EPO or forskolin decreased the activity of TF and mitigated the prothrombotic effect of celecoxib. Therefore, these combinations may have the utility to abrogate the prothrombotic adverse effect of celecoxib in clinical setting.

  12. Genetic evidence of hybridization between Onothera wolfii (Wolf's evening primrose) and O. glaziovana, a garden escape

    Treesearch

    Jennifer DeWoody; Leonel Arguello; David Imper; Robert D. Westfall; Valerie D. Hipkins

    2008-01-01

    Isozyme analysis of the rare Oenothera wolfii (Wolf's evening primrose) and the garden escape, O. glazioviana, indicates that hybridization between these species may be more widespread than morphological evidence indicates. Although both species contained low amounts of genetic variation, unique alleles were identified in...

  13. No evidence that sex and transposable elements drive genome size variation in evening primroses.

    PubMed

    Ågren, J Arvid; Greiner, Stephan; Johnson, Marc T J; Wright, Stephen I

    2015-04-01

    Genome size varies dramatically across species, but despite an abundance of attention there is little agreement on the relative contributions of selective and neutral processes in governing this variation. The rate of sex can potentially play an important role in genome size evolution because of its effect on the efficacy of selection and transmission of transposable elements (TEs). Here, we used a phylogenetic comparative approach and whole genome sequencing to investigate the contribution of sex and TE content to genome size variation in the evening primrose (Oenothera) genus. We determined genome size using flow cytometry for 30 species that vary in genetic system and find that variation in sexual/asexual reproduction cannot explain the almost twofold variation in genome size. Moreover, using whole genome sequences of three species of varying genome sizes and reproductive system, we found that genome size was not associated with TE abundance; instead the larger genomes had a higher abundance of simple sequence repeats. Although it has long been clear that sexual reproduction may affect various aspects of genome evolution in general and TE evolution in particular, it does not appear to have played a major role in genome size evolution in the evening primroses. © 2015 The Author(s).

  14. Loss of sexual recombination and segregation is associated with increased diversification in evening primroses.

    PubMed

    Johnson, Marc T J; Fitzjohn, Richard G; Smith, Stacey D; Rausher, Mark D; Otto, Sarah P

    2011-11-01

    The loss of sexual recombination and segregation in asexual organisms has been portrayed as an irreversible process that commits asexually reproducing lineages to reduced diversification. We test this hypothesis by estimating rates of speciation, extinction, and transition between sexuality and functional asexuality in the evening primroses. Specifically, we estimate these rates using the recently developed BiSSE (Binary State Speciation and Extinction) phylogenetic comparative method, which employs maximum likelihood and Bayesian techniques. We infer that net diversification rates (speciation minus extinction) in functionally asexual evening primrose lineages are roughly eight times faster than diversification rates in sexual lineages, largely due to higher speciation rates in asexual lineages. We further reject the hypothesis that a loss of recombination and segregation is irreversible because the transition rate from functional asexuality to sexuality is significantly greater than zero and in fact exceeded the reverse rate. These results provide the first empirical evidence in support of the alternative theoretical prediction that asexual populations should instead diversify more rapidly than sexual populations because they are free from the homogenizing effects of sexual recombination and segregation. Although asexual reproduction may often constrain adaptive evolution, our results show that the loss of recombination and segregation need not be an evolutionary dead end in terms of diversification of lineages. © 2011 The Author(s). Evolution© 2011 The Society for the Study of Evolution.

  15. Genetic manipulation of gamma-linolenic acid (GLA) synthesis in a commercial variety of evening primrose (Oenothera sp.).

    PubMed

    de Gyves, Emilio Mendoza; Sparks, Caroline A; Sayanova, Olga; Lazzeri, Paul; Napier, Johnathan A; Jones, Huw D

    2004-07-01

    A robust Agrobacterium-mediated transformation procedure was developed for Rigel, a commercial cultivar of evening primrose, and used to deliver a cDNA encoding a Delta(6)-desaturase from borage under the control of a cauliflower mosaic virus (CaMV) 35S promoter. Analysis of the transformed plants demonstrated an altered profile of polyunsaturated fatty acids, with an increase in gamma-linolenic acid and octadecatetraenoic acid in leaf tissues when compared with control lines.

  16. PERMANENT GENETIC RESOURCES: Isolation and characterization of polymorphic microsatellite loci in common evening primrose (Oenothera biennis).

    PubMed

    Larson, E L; Bogdanowicz, S M; Agrawal, A A; Johnson, M T J; Harrison, R G

    2008-03-01

    We developed nine polymorphic microsatellite loci for evening primrose (Oenothera biennis). These loci have two to 18 alleles per locus and observed heterozygosities ranging from 0 to 0.879 in a sample of 34 individuals. In a pattern consistent with the functionally asexual reproductive system of this species, 17/36 pairs of loci revealed significant linkage disequilibrium and three loci showed significant deviations from Hardy-Weinberg equilibrium. The loci will be informative in identifying genotypes in multigenerational field studies to assess changes in genotype frequencies. © 2007 The Authors.

  17. Rapid Monitoring of Pharmacological Volatiles of Night-Flowering Evening-Primrose According to Flower Opening or Closing by Fast Gas Chromatography/Surface Acoustic Wave Sensor (Electronic zNose).

    PubMed

    Oh, Se Yeon

    2018-05-01

    Aroma is important in night-flowering species, as visually they can not be observed well. Thus, the analysis of the volatiles of evening-primrose is of great interest in biological fields and therapy. Furthermore, the analysis of volatiles demands rapid and simple procedure, because volatiles decompose. The aim of this study is to show the rapid monitoring of the volatiles of evening-primrose according to the flowering or closing by fast gas chromatography/surface acoustic wave GC/SAW. Moreover, calibration according to the sensor temperature of the GC/SAW was performed, achieving a high reproducibility and excellent sensitivity. GC/SAW is an effective analytical method that provides on-line measurements without pretreatment of sample. Headspace solid-phase micro-extraction coupled to gas chromatography mass spectrometry (HS-SPME-GC-MS) and dynamic headspace trapping and extraction with GC-MS were employed to confirm the identification of the volatiles of evening-primrose compared to GC/SAW. Linalool was found to be the dominant component, comprising 96.4-25.2% of the total amount, according to the opening or closing. Interestingly, the amount of indole also varied according to the opening or closing (3.0-0.0%) such as linalool. Also, while the sensitivity increased with the reduction in the sensor temperature of the GC/SAW, the reproducibility showed a tendency to decrease. The results showed that flower opening is related to the volatiles emission, which is pharmacological and plant defensive. GC/SAW can be a useful analytical method for the rapid monitoring of volatiles of evening-primrose according to the opening or closing as it provides second unit analysis, as well as simple, and aroma pattern recognition. Copyright © 2017 John Wiley & Sons, Ltd. Copyright © 2017 John Wiley & Sons, Ltd.

  18. Flavanols from evening primrose (Oenothera paradoxa) defatted seeds inhibit prostate cells invasiveness and cause changes in Bcl-2/Bax mRNA ratio.

    PubMed

    Lewandowska, Urszula; Szewczyk, Karolina; Owczarek, Katarzyna; Hrabec, Zbigniew; Podsędek, Anna; Koziołkiewicz, Maria; Hrabec, Elżbieta

    2013-03-27

    In this study, we assessed the influence of an evening primrose flavanol preparation (EPFP) on proliferation and invasiveness of human prostate cancer cells (DU 145) and immortalized prostate epithelial cells (PNT1A). We report for the first time that EPFP reduces DU 145 cell proliferation (IC50 = 97 μM GAE for 72 h incubation) and invasiveness (by 24% versus control at 75 μM GAE). EPFP strongly inhibited PNT1A invasiveness in a concentration-dependent manner (by 67% versus control at 75 μM GAE) and did not cause a reduction in their proliferation. Furthermore, EPFP inhibited the activities of MMP-2 and MMP-9 secreted to culture medium by PNT1A cells by 84% and 34% versus control at 100 μM GAE, respectively. In the case of DU 145, MMP-9 activity at 100 μM GAE was reduced by 37% versus control. Moreover, the evening primrose seed flavanols suppressed the expression of selected genes (MMP-1, MMP-9, MMP-14, c-Fos, c-Jun, and VEGF) and also caused favorable changes in Bcl-2/Bax mRNA ratio which render DU 145 cells more sensitive to apoptosis-triggering agents. An additional confirmation of the proapoptotic activity of EPFP toward DU 145 was visualization of characteristic apoptotic bodies by DAPI staining. In conclusion, this study suggests that EPFP may increase apoptosis and reduce angiogenesis of prostate cancer cells.

  19. Breeding system variation in 10 evening primroses (Oenothera sections Anogra and Kleinia; Onagraceae).

    PubMed

    Theiss, Kathryn E; Holsinger, Kent E; Evans, Margaret E K

    2010-06-01

    We examined two accounts of the relationship between breeding system and life history variation in a clade of evening primroses (Oenothera, Onagraceae): (1) selection for reproductive assurance should generate an association between self-compatibility and monocarpy and (2) phylogenetic conservatism leads to retention of breeding system and life history traits among closely related taxa. • We performed over 4000 hand pollinations under greenhouse conditions to determine the compatibility of 10 Oenothera taxa (sections Anogra [17 taxa] and Kleinia [2 taxa)] for which breeding systems had not previously been reported. We used generalized linear mixed models to evaluate the influence of pollination treatment, parents, and population on fruiting success. • Among the taxa tested, six were self-incompatible, two were variable in compatibility, and two were self-compatible. We combined these data with published studies in Anogra and Kleinia and mapped breeding system and life history onto a published phylogeny. • We found no evidence for phylogenetic conservatism, but detected considerable evolutionary lability in both traits. Additionally, we found no evidence for a consistent relationship between breeding system and life history. Only eight of 19 taxa followed the predicted association between self-incompatibility and polycarpy vs. self-compatibility and monocarpy. Instead, many taxa have retained self-incompatibility, regardless of monocarpy or polycarpy.

  20. A meta-analysis of randomized, placebo-controlled clinical trials of Efamol evening primrose oil in atopic eczema. Where do we go from here in light of more recent discoveries?

    PubMed

    Morse, N L; Clough, P M

    2006-12-01

    The global incidence of atopic eczema is escalating. While new treatment options are becoming available, previous treatments with certain confirmed benefits are still worth investigating as safe and effective therapies. One such treatment, Efamol evening primrose oil (EPO), was proven efficacious in a 1989 meta-analysis of randomized, double-blind, placebo-controlled clinical trials. A decade of further testing and subsequent independent reanalysis of 26 clinical studies including 1207 patients presented here, establishes that Efamol EPO has a simultaneous, beneficial effect on itch/pruritus, crusting, oedema and redness (erythema) that becomes apparent between 4 and 8 weeks after treatment is initiated. However, the magnitude of this effect is reduced in association with increasing frequency of potent steroid use. This and other confounding variables that are now being reported in the literature may account for historically reported inconsistent patient response. Recent research has uncovered unique complexities in fatty acid metabolism and immune response in the atopic condition beyond those previously reported and may well have identified a subcategory of non-responders and has helped established those that can consistently derive significant benefit. Further research is needed to provide a better understanding of the physiology behind this complex disorder and the beneficial role that fatty acids can play in its development and management. Efamol EPO has a simultaneous, beneficial effect on itch/pruritus, crusting, oedema and redness (erythema) that becomes apparent between 4 and 8 weeks after treatment is initiated. However, the magnitude of this effect is reduced in association with increasing frequency of potent steroid use.

  1. [Study on the encapsulation technique of high purity gamma-linolenic acid, part 1--saponification reaction and saponification value].

    PubMed

    Liu, Feng-xia; Xue, Gang; Gao, Qiu-hua; Gao, Wei-xia; Zhang, Li-hua

    2005-03-01

    To measure the saponification value and fatty acid formation of evening primrose oil, to study the effects of pH value on production yield and fatty acid formation during the saponification reaction, and to provide rationales for the selection of raw material, the enhancement of production yield of saponification, and the encapsulation of gamma-linolenic acid with urea. To measure fatty acid's formation with gas chromatographic method and to measure the saponification value. The content of gamma-linolenic acid is 7%-10% in evening primrose oil. The content of gamma-linolenic acid is inversely correlated with that of unsaturated fatty acid. The saponification value, the amount of KOH for saponification of evening primrose oil, and the pH value for subsequent isolations of oils are determined. From the measurement of fatty acids of evening primrose oil in two different cultivation locations, the content of gamma-linolenic acid is determined to be 7%-10%, unsaturated oils account for 90%. The saponification value of evening primrose oil is between 180-200, pH value of isolated oil is 1.5-2.0 after saponification reaction. Fatty acids mainly include palmitic acid, stearic acid, oleic acid, linolic acid and gamma-linolenic acid.

  2. Polyphenols from evening primrose ( Oenothera paradoxa ) defatted seeds induce apoptosis in human colon cancer Caco-2 cells.

    PubMed

    Gorlach, Sylwia; Wagner, Waldemar; Podsedek, Anna; Sosnowska, Dorota; Dastych, Jarosław; Koziołkiewicz, Maria

    2011-07-13

    Polyphenols extracted from evening primrose seeds (industrial waste product) were studied as apoptosis inducers in human colorectal adenocarcinoma Caco-2 and HT-29 cell lines and in rat normal intestinal IEC-6 cells. The extract dose-dependently inhibited the growth of Caco-2, HT-29, and IEC-6 cells. However, nuclear DNA fragmentation characteristic of apoptosis was observed only in Caco-2. After 72 h of incubation with the extract at 150 μM gallic acid equivalents (44.1 μg extract/mL), Caco-2 cell numbers decreased to 19% of control and 48.8% of the cells were identified by flow cytometry as apoptotic. Under the same conditions only 8% of HT-29 cells and 12.6% of IEC-6 cells exhibited hypodiploid DNA content. The effects of the extract and its fractions on phosphatidylserine exposure and cell membrane integrity were assessed by high content screening image cytometry. The fractions strongly and dose-dependently reduced Caco-2 cell numbers, whereas HT-29 and IEC-6 cells were affected to lesser extents.

  3. Anti-Helicobacter pylori activities of FEMY-R7 composed of fucoidan and evening primrose extract in mice and humans

    PubMed Central

    Kim, Tae-Su; Choi, Ehn-Kyoung; Kim, Jihyun; Shin, Kyungha; Lee, Sung-Pyo; Choi, Youngjin; Jeon, Joseph H.

    2014-01-01

    Helicobacter pylori-eliminating effects of FEMY-R7, composed of fucoidan and evening primrose extract, were investigated in mice and humans. Male C57BL/6 mice were infected with the bacteria by intragastric inoculation (1×109 CFU/mouse) 3 times at 2-day intervals, and simultaneously, orally treated twice a day with 10 or 100 mg/kg FEMY-R7 for 2 weeks. In Campylobcter-like organism-detection test, FEMY-R7 markedly reduced the urease-positive reactivity. In a clinical sudy, human subjects, confirmed to be infected with Helicobacter pylori, were orally administered twice a day with a capsule containing 150 mg FEMY-R7 for 8 weeks. FEMY-R7 significantly decreased both the Delta over baseline-value in urea breath test and the serum pepsinogens I and II levels. The results indicate that FEMY-R7 not only eliminates H. pylori from gastric mucosa of animals and humans, but also improves gastric function. PMID:25324874

  4. [The investigation of the influence of cryopreservation and inbreeding on the variability of morphological characteristics of the evening-primrose biennial (Oenothera biennis L.)].

    PubMed

    Chetviverikova, E P; Iashina, S G; Shabaeva, E V; Egorova, E F; Iashina, A V

    2005-01-01

    The effect of deep freezing of seeds at -196 degrees C (-320.8 degrees Fahrenheit) and inbreeding on the morphological characteristics of the evening-primrose biennal (Oenothera biennis L.), such as the size of plant parts and the amount of fruits, cauline nodes, and generative and vegetative shoots was investigated. The variation coefficients for these characteristics after treatment with low temperatures and inbreeding were calculated. It was shown that the characteristics of plant size show a low and a middle level of variability in the control group. The variation curves for these characteristics are similar to normal distribution curves. After stresses they slightly change or remain invariant. Large adventive shoots show a high level of variability. The distribution of the results in this case significantly differs from the normal. The branching of plants changes after both stress factors: the amount of all kinds of shoots decreases by half or even more.

  5. Bet hedging via seed banking in desert evening primroses (Oenothera, Onagraceae): demographic evidence from natural populations.

    PubMed

    Evans, Margaret E K; Ferrière, Régis; Kane, Michael J; Venable, D Lawrence

    2007-02-01

    Bet hedging is one solution to the problem of an unpredictably variable environment: fitness in the average environment is sacrificed in favor of lower variation in fitness if this leads to higher long-run stochastic mean fitness. While bet hedging is an important concept in evolutionary ecology, empirical evidence that it occurs is scant. Here we evaluate whether bet hedging occurs via seed banking in natural populations of two species of desert evening primroses (Oenothera, Onagraceae), one annual and one perennial. Four years of data on plants and 3 years of data on seeds yielded two transitions for the entire life cycle. One year was exceptionally dry, leading to reproductive failure in the sample areas, and the other was above average in precipitation, leading to reproductive success in four of five populations. Stochastic simulations of population growth revealed patterns indicative of bet hedging via seed banking, particularly in the annual populations: variance in fitness and fitness in the average environment were lower with seed banking than without, whereas long-run stochastic mean fitness was higher with seed banking than without across a wide range of probabilities of the wet year. This represents a novel, unusually rigorous demonstration of bet hedging from field data.

  6. Translocations of chromosome end-segments and facultative heterochromatin promote meiotic ring formation in evening primroses.

    PubMed

    Golczyk, Hieronim; Massouh, Amid; Greiner, Stephan

    2014-03-01

    Due to reciprocal chromosomal translocations, many species of Oenothera (evening primrose) form permanent multichromosomal meiotic rings. However, regular bivalent pairing is also observed. Chiasmata are restricted to chromosomal ends, which makes homologous recombination virtually undetectable. Genetic diversity is achieved by changing linkage relations of chromosomes in rings and bivalents via hybridization and reciprocal translocations. Although the structural prerequisite for this system is enigmatic, whole-arm translocations are widely assumed to be the mechanistic driving force. We demonstrate that this prerequisite is genome compartmentation into two epigenetically defined chromatin fractions. The first one facultatively condenses in cycling cells into chromocenters negative both for histone H3 dimethylated at lysine 4 and for C-banding, and forms huge condensed middle chromosome regions on prophase chromosomes. Remarkably, it decondenses in differentiating cells. The second fraction is euchromatin confined to distal chromosome segments, positive for histone H3 lysine 4 dimethylation and for histone H3 lysine 27 trimethylation. The end-segments are deprived of canonical telomeres but capped with constitutive heterochromatin. This genomic organization promotes translocation breakpoints between the two chromatin fractions, thus facilitating exchanges of end-segments. We challenge the whole-arm translocation hypothesis by demonstrating why reciprocal translocations of chromosomal end-segments should strongly promote meiotic rings and evolution toward permanent translocation heterozygosity. Reshuffled end-segments, each possessing a major crossover hot spot, can furthermore explain meiotic compatibility between genomes with different translocation histories.

  7. Growing evening primroses (Oenothera)

    PubMed Central

    Greiner, Stephan; Köhl, Karin

    2014-01-01

    The model plant Oenothera has contributed significantly to the biological sciences and it dominated the early development of plant genetics, cytogenetics, and evolutionary biology. The great advantage of using Oenothera as a model system is a large body of genetic, cytological, morphological, and ecological information collected over more than a century. The Oenothera system offers a well-studied taxonomy, population structure, and ecology. Cytogenetics and formal genetics at the population level are extensively developed, providing an excellent basis to study evolutionary questions. Further, Oenothera is grown as an oil seed crop for the production of essential fatty acids (gamma-linoleic acid) and is considered to be a medicinal plant due to its many pharmaceutically active secondary metabolites, such as ellagitannins. Although Oenothera has been cultivated as a laboratory organism since the end of the 19th century, there is a substantial lack of literature dealing with modern greenhouse techniques for the genus. This review compiles an overview about the growth requirements for the genus Oenothera, with a special focus on its genetically best-studied subsections Oenothera and Munzia. Requirements for greenhouse, field, and agronomic cultures are presented, together with information on substrate types, pest control, as well as vegetative and seed propagation, cross pollination, harvest, and seed storage. Particular aspects like germination, bolting, and flowering induction in taxonomically diverse material are reviewed. Methods recommended are supported by ecological and experimental data. An overview of the possibilities for wide hybridization and polyploidy induction in the genus is given. Germplasm resources are referenced. In summary, a comprehensive guideline for successful laboratory cultivation of Oenothera species is provided. PMID:24592268

  8. Growing evening primroses (Oenothera).

    PubMed

    Greiner, Stephan; Köhl, Karin

    2014-01-01

    The model plant Oenothera has contributed significantly to the biological sciences and it dominated the early development of plant genetics, cytogenetics, and evolutionary biology. The great advantage of using Oenothera as a model system is a large body of genetic, cytological, morphological, and ecological information collected over more than a century. The Oenothera system offers a well-studied taxonomy, population structure, and ecology. Cytogenetics and formal genetics at the population level are extensively developed, providing an excellent basis to study evolutionary questions. Further, Oenothera is grown as an oil seed crop for the production of essential fatty acids (gamma-linoleic acid) and is considered to be a medicinal plant due to its many pharmaceutically active secondary metabolites, such as ellagitannins. Although Oenothera has been cultivated as a laboratory organism since the end of the 19th century, there is a substantial lack of literature dealing with modern greenhouse techniques for the genus. This review compiles an overview about the growth requirements for the genus Oenothera, with a special focus on its genetically best-studied subsections Oenothera and Munzia. Requirements for greenhouse, field, and agronomic cultures are presented, together with information on substrate types, pest control, as well as vegetative and seed propagation, cross pollination, harvest, and seed storage. Particular aspects like germination, bolting, and flowering induction in taxonomically diverse material are reviewed. Methods recommended are supported by ecological and experimental data. An overview of the possibilities for wide hybridization and polyploidy induction in the genus is given. Germplasm resources are referenced. In summary, a comprehensive guideline for successful laboratory cultivation of Oenothera species is provided.

  9. Effects of functionally asexual reproduction on quantitative genetic variation in the evening primroses (Oenothera, Onagraceae).

    PubMed

    Godfrey, Ryan M; Johnson, Marc T J

    2014-11-01

    It has long been predicted that a loss of sexual reproduction leads to decreased heritable variation within populations and increased differentiation between populations. Despite an abundance of theory, there are few empirical tests of how sex affects genetic variation in phenotypic traits, especially for plants. Here we test whether repeated losses of two critical components of sex (recombination and segregation) in the evening primroses (Oenothera L., Onagraceae) affect quantitative genetic variation within and between populations. We sampled multiple genetic families from 3-5 populations from each of eight Oenothera species, which represented four independent transitions between sexual reproduction and a functionally asexual genetic system called "permanent translocation heterozygosity." We used quantitative genetics methods to partition genetic variation within and between populations for eight plant traits related to growth, leaf physiology, flowering, and resistance to herbivores. Heritability was, on average, 74% higher in sexual Oenothera populations than in functionally asexual populations, with plant growth rate, specific leaf area, and the percentage of leaf water content showing the strongest differences. By contrast, genetic differentiation among populations was 2.8× higher in functionally asexual vs. sexual Oenothera species. This difference was particularly strong for specific leaf area. Sexual populations tended to exhibit higher genetic correlations among traits, but this difference was weakly supported. These results support the prediction that sexual reproduction maintains higher genetic variation within populations, which may facilitate adaptive evolution. We also found partial support for the prediction that a loss of sex leads to greater population differentiation, which may elevate speciation rates. © 2014 Botanical Society of America, Inc.

  10. Translocations of Chromosome End-Segments and Facultative Heterochromatin Promote Meiotic Ring Formation in Evening Primroses[W][OPEN

    PubMed Central

    Golczyk, Hieronim; Massouh, Amid; Greiner, Stephan

    2014-01-01

    Due to reciprocal chromosomal translocations, many species of Oenothera (evening primrose) form permanent multichromosomal meiotic rings. However, regular bivalent pairing is also observed. Chiasmata are restricted to chromosomal ends, which makes homologous recombination virtually undetectable. Genetic diversity is achieved by changing linkage relations of chromosomes in rings and bivalents via hybridization and reciprocal translocations. Although the structural prerequisite for this system is enigmatic, whole-arm translocations are widely assumed to be the mechanistic driving force. We demonstrate that this prerequisite is genome compartmentation into two epigenetically defined chromatin fractions. The first one facultatively condenses in cycling cells into chromocenters negative both for histone H3 dimethylated at lysine 4 and for C-banding, and forms huge condensed middle chromosome regions on prophase chromosomes. Remarkably, it decondenses in differentiating cells. The second fraction is euchromatin confined to distal chromosome segments, positive for histone H3 lysine 4 dimethylation and for histone H3 lysine 27 trimethylation. The end-segments are deprived of canonical telomeres but capped with constitutive heterochromatin. This genomic organization promotes translocation breakpoints between the two chromatin fractions, thus facilitating exchanges of end-segments. We challenge the whole-arm translocation hypothesis by demonstrating why reciprocal translocations of chromosomal end-segments should strongly promote meiotic rings and evolution toward permanent translocation heterozygosity. Reshuffled end-segments, each possessing a major crossover hot spot, can furthermore explain meiotic compatibility between genomes with different translocation histories. PMID:24681616

  11. Genotype-by-environment interactions leads to variable selection on life-history strategy in Common Evening Primrose (Oenothera biennis).

    PubMed

    Johnson, M T J

    2007-01-01

    Monocarpic plant species, where reproduction is fatal, frequently exhibit variation in the length of their prereproductive period prior to flowering. If this life-history variation in flowering strategy has a genetic basis, genotype-by-environment interactions (G x E) may maintain phenotypic diversity in flowering strategy. The native monocarpic plant Common Evening Primrose (Oenothera biennis L., Onagraceae) exhibits phenotypic variation for annual vs. biennial flowering strategies. I tested whether there was a genetic basis to variation in flowering strategy in O. biennis, and whether environmental variation causes G x E that imposes variable selection on flowering strategy. In a field experiment, I randomized more than 900 plants from 14 clonal families (genotypes) into five distinct habitats that represented a natural productivity gradient. G x E strongly affected the lifetime fruit production of O. biennis, with the rank-order in relative fitness of genotypes changing substantially between habitats. I detected genetic variation in annual vs. biennial strategies in most habitats, as well as a G x E effect on flowering strategy. This variation in flowering strategy was correlated with genetic variation in relative fitness, and phenotypic and genotypic selection analyses revealed that environmental variation resulted in variable directional selection on annual vs. biennial strategies. Specifically, a biennial strategy was favoured in moderately productive environments, whereas an annual strategy was favoured in low-productivity environments. These results highlight the importance of variable selection for the maintenance of genetic variation in the life-history strategy of a monocarpic plant.

  12. Influence of polyphenol extract from evening primrose (Oenothera paradoxa) seeds on human prostate and breast cancer cell lines.

    PubMed

    Lewandowska, Urszula; Owczarek, Katarzyna; Szewczyk, Karolina; Podsędek, Anna; Koziołkiewicz, Maria; Hrabec, Elżbieta

    2014-02-03

    There is growing interest in plant polyphenols which exhibit pleiotropic biological activities, including anti-inflammatory, antioxidant, and anticancer effects. The objective of our study was to evaluate the influence of an evening primrose extract (EPE) from defatted seeds on viability and invasiveness of three human cell lines: PNT1A (normal prostate cells), DU145 (prostate cancer cells) and MDA-MB-231 (breast cancer cells). The results revealed that after 72 h of incubation the tested extract reduced the viability of DU 145 and MDA-MB-231 with IC50 equal to 14.5 μg/mL for both cell lines. In contrast, EPE did not inhibit the viability of normal prostate cells. Furthermore, EPE reduced PNT1A and MDA-MB-231 cell invasiveness; at the concentration of 21.75 μg/mL the suppression of invasion reached 92% and 47%, respectively (versus control). Additionally, zymographic analysis revealed that after 48 h of incubation EPE inhibited metalloproteinase-2 (MMP-2) and metalloproteinase-9 (MMP-9) activities in a dose-dependent manner. For PNT1A the activities of MMP-2 and MMP-9 decreased 4- and 2-fold, respectively, at EPE concentration of 29 μg/mL. In the case of MDA-MB-231 and DU 145 the decrease in MMP-9 activity at EPE concentration of 29 μg/mL was 5.5-fold and almost 1.9-fold, respectively. In conclusion, this study suggests that EPE may exhibit antimigratory, anti-invasive and antimetastatic potential towards prostate and breast cancer cell lines.

  13. Climate and life-history evolution in evening primroses (Oenothera, Onagraceae): a phylogenetic comparative analysis.

    PubMed

    Evans, Margaret E K; Hearn, David J; Hahn, William J; Spangle, Jennifer M; Venable, D Lawrence

    2005-09-01

    Evolutionary ecologists have long sought to understand the conditions under which perennial (iteroparous) versus annual (semelparous) plant life histories are favored. We evaluated the idea that aridity and variation in the length of droughts should favor the evolution of an annual life history, both by decreasing adult survival and by increasing the potential for high seedling survival via reduced plant cover. We calculated phylogenetically independent contrasts of climate with respect to life history in a clade of winter-establishing evening primroses (sections Anogra and Kleinia; Oenothera; Onagraceae), which includes seven annuals, 12 perennials, and two variable taxa. Climate variables were quantified from long-term records at weather stations near collection localities. To explicitly account for phylogenetic uncertainty, contrasts were calculated on a random sample of phylogenetic trees from the posterior distribution of a Bayesian analysis of DNA sequence data. Statements of association are based on comparing the per-tree mean contrast, which has a null expectation of zero, to a set of per-tree mean contrasts calculated on the same trees, after randomizing the climate data. As predicted, increased annual aridity, increased annual potential evapotranspiration, and decreased annual precipitation were associated with transitions to the annual habit, but these trends were not significantly different from the null pattern. Transitions to the annual habit were not significantly associated with increases in one measure of aridity in summer nor with increased summer drought, but they were associated with significantly increased maximum summer temperatures. In winter, increased aridity and decreased precipitation were significantly associated with transitions to the annual habit. Changes in life history were not significantly associated with changes in the coefficient of variation of precipitation, either on an annual or seasonal (summer vs. winter) basis. Though we

  14. Novel de novo mutations in ZBTB20 in Primrose syndrome with congenital hypothyroidism.

    PubMed

    Mattioli, Francesca; Piton, Amelie; Gérard, Bénédicte; Superti-Furga, Andrea; Mandel, Jean-Louis; Unger, Sheila

    2016-06-01

    The cardinal features of Primrose syndrome (MIM 259050) are dysmorphic facial features, macrocephaly, and intellectual disability, as well as large body size, height and weight, and calcified pinnae. A variety of neurological signs and symptoms have been reported including hearing loss, autism, behavioral abormalities, hypotonia, cerebral calcifications, and hypoplasia of the corpus callosum. Recently, heterozygous de novo missense mutations in ZBTB20, coding for a zing finger protein, have been identified in Primrose syndrome patients. We report a boy with intellectual disability carrying two de novo missense mutations in the last exon of ZBTB20 (Ser616Phe and Gly741Arg; both previously unreported). One of them, Ser616Phe, affects an amino acid located in one of the C2H2 zing-fingers involved in DNA-binding and close to other missense mutations already described. Reverse phenotyping showed that this patient presents with classic features of Primrose syndrome (dysmorphic facies, macrocephaly, hearing loss, hypotonia, hypoplasia of the corpus callosum) and, in addition, congenital hypothyroidism. Review of the literature reveals another Primrose syndrome patient with hypothyroidism and thus, this may represent an under recognized component that should be investigated in other patients. © 2016 Wiley Periodicals, Inc. © 2016 Wiley Periodicals, Inc.

  15. Inhibitory effects of Oenothera biennis (evening primrose) seed extract on Streptococcus mutans and S. mutans-induced dental caries in rats.

    PubMed

    Matsumoto-Nakano, M; Nagayama, K; Kitagori, H; Fujita, K; Inagaki, S; Takashima, Y; Tamesada, M; Kawabata, S; Ooshima, T

    2011-01-01

    Oenothera biennis (evening primrose) seed extract (OBSE) is known to contain polyphenols, which may possess antioxidant activities. Polyphenols extracted from several plants are reported to exhibit cariostatic activities by inhibiting mutans streptococcus growth and glucosyltransferase activities. The purpose of the present study was to examine the inhibitory effects of OBSE on the development of dental caries, both in vitro and in vivo. OBSE was investigated for its inhibitory effects on cellular aggregation, hydrophobicity, sucrose-dependent adherence and insoluble glucan synthesis. Furthermore, biofilm formation was examined in the presence of OBSE, using confocal microscopic imaging. An animal experiment was also performed to examine the in vivo effects. OBSE induced a strong aggregation of Streptococcus mutans MT8148 cells, while cell surface hydrophobicity was decreased by approximately 90% at a concentration of 0.25 mg/ml. The sucrose-dependent adherence of the MT8148 cells was also reduced by addition of OBSE, with a reduction rate of 73% seen at a concentration of 1.00 mg/ml. Additionally, confocal microscopic observations revealed the biofilm development phase to be remarkably changed in the presence of OBSE. Furthermore, insoluble glucan synthesis was significantly reduced when OBSE was present at concentrations greater than 0.03 mg/ml. In an animal experiment, the caries scores in rats given OBSE (0.05 mg/ml in drinking water) were significantly lower than those in rats given water without OBSE. Our results indicate that OBSE has inhibitory activity on dental caries. 2011 S. Karger AG, Basel.

  16. Time to Talk: What You Should Know about 5 Popular Herbs (Evening Primrose Oil, St. John's Wort, Fenugreek, Echinacea, ....

    MedlinePlus

    ... oil , St. John’s wort , fenugreek , echinacea , and aloe vera . Here are 5 tips about these popular herbal ... but some people may have allergic reactions. Aloe Vera. Topical use: A few small studies suggest that ...

  17. Procyanidins from evening primrose (Oenothera paradoxa) defatted seeds inhibit invasiveness of breast cancer cells and modulate the expression of selected genes involved in angiogenesis, metastasis, and apoptosis.

    PubMed

    Lewandowska, Urszula; Szewczyk, Karolina; Owczarek, Katarzyna; Hrabec, Zbigniew; Podsędek, Anna; Sosnowska, Dorota; Hrabec, Elżbieta

    2013-01-01

    There is a growing interest in plant polyphenols (including flavanols) that exhibit pleiotropic biological activities such as antiinflammatory, antioxidant, and anticancer effects. Here, we report for the first time the inhibition of MDA-MB-231 breast cancer cell viability and invasiveness by an evening primrose flavanol preparation (EPFP). We observed a decrease in MDA-MB-231 viability of 50% vs. a control after 72 h of incubation with EPFP at a concentration of 58 μM gallic acid equivalents (GAE) and an inhibition of their invasiveness of 65% vs. a control at 75 μM GAE after 48 h of incubation. EPFP caused a 10-fold reduction in matrix metalloproteinase-9 (MMP-9) activity at 100 μM GAE. Furthermore, through modulation of mRNA expression, EPFP reduced the expression levels of the following proteins: antiapoptotic Bcl-2, angiogenic vascular endothelial growth factor (VEGF), and 2 transcription factors (c-Jun, c-Fos). Moreover, analysis by flow cytometry revealed that EPFP induced apoptosis in MDA-MB-231 cells. In conclusion, our data shows that EPFP inhibits cell viability by increasing apoptosis and decreases cell invasiveness by decreasing angiogenesis.

  18. Essential fatty acid supplementation in chronic hepatitis B.

    PubMed

    Jenkins, A P; Green, A T; Thompson, R P

    1996-08-01

    Dietary supplementation with essential fatty acids and polyunsaturated lecithin may improve biochemical and histological parameters in liver disease. Ten patients with serological and histological evidence of chronic hepatitis B received capsules of the polyunsaturated fatty acid-rich evening primrose oil in a dose of 4 g daily for 12 months, while a matched group received liquid paraffin capsules as a placebo. Compared to the placebo group, the patients receiving evening primrose oil showed no improvement in either biochemical or histological indices of liver damage, or in the rate of loss of circulating e antigen. Dietary, supplementation with this dose of essential fatty acids is unlikely to be of benefit in chronic hepatitis B.

  19. Singlet oxygen autoxidation of vegetable oils: evidences for lack of synergy between β-carotene and tocopherols.

    PubMed

    Smyk, Bogdan

    2015-09-01

    The synergy between β-carotene and tocopherols--antioxidants protecting oils from oxidation, was analyzed in a model system. The model used stripped borage and evening primrose oils. A chlorophyll extract, β-carotene and one of the tocopherols were added together or separately to the oils. Oil oxidation was initiated by singlet oxygen that was produced by chlorophylls irradiated with the use of a xenon lamp equipped with the cut-off 600 nm filter. Experiments were carried out at two mole ratios of tocopherols to β-carotene, i.e. at 1:1 and 23:1. Analyses were performed using absorption and fluorescence spectra in the UV+Vis region. The results demonstrated an antagonistic action of the antioxidants. The protective effect of unsaturated fatty acids was significantly better in the case of β-carotene compared to the tocopherols. Furthermore, tocopherols were less effective in protecting the oils in the presence of β-carotene than without it. Copyright © 2015 Elsevier Ltd. All rights reserved.

  20. Establishing Research and Management Priorities for Invasive Water Primroses (Ludwigia spp.)

    DTIC Science & Technology

    2016-02-01

    among the most aggressive aquatic invasive plant invaders in the world. These aquatic Ludwigia species can impart severe ecological , economic, and...global trade and projected climate change. This technical report presents an overview of the biology and ecology of these invasive plant species, along...primrose species, like other invasive plants , must be grounded in basic knowledge of the biology and ecology of the species and their responses to

  1. Decrease of sexual organ reciprocity between heterostylous primrose species, with possible functional and evolutionary implications.

    PubMed

    Keller, Barbara; de Vos, Jurriaan M; Conti, Elena

    2012-11-01

    Heterostyly is a floral polymorphism that has fascinated evolutionary biologists since Darwin's seminal studies on primroses. The main morphological characteristic of heterostyly is the reciprocal placement of anthers and stigmas in two distinct (distyly) floral morphs. Variation in the degree of intermorph sexual reciprocity is relatively common and known to affect patterns of pollen transfer within species. However, the partitioning of sexual organ reciprocity within and between closely related species remains unknown. This study aimed at testing whether intermorph sexual reciprocity differs within vs. between primrose species that hybridize in nature and whether the positions of sexual organs are correlated with other floral traits. Six floral traits were measured in both floral morphs of 15 allopatric populations of Primula elatior, P. veris and P. vulgaris, and anther-stigma reciprocity was estimated within and between species. A combination of univariate and multivariate approaches was used to test whether positions of reproductive organs were less reciprocal between than within species, to assess correlations between sexual organ positions and other corolla traits, and to quantify differences between morphs and species. The three species were morphologically well differentiated in most floral traits, except that P. veris and P. vulgaris did not differ significantly in sexual organ positions. Overall, lower interspecific than intraspecific sexual organ reciprocity was detected. This decrease was marked between P. elatior and P. vulgaris, intermediate and variable between P. elatior and P. veris, but negligible between P. veris and P. vulgaris. Differences in anther and stigma heights between the analysed primrose species were of the same magnitude or larger than intraspecific differences that altered pollen flow within other heterostylous systems. Therefore, it is possible to suggest that considerable reductions of sexual organ reciprocity between species may

  2. Decrease of sexual organ reciprocity between heterostylous primrose species, with possible functional and evolutionary implications

    PubMed Central

    Keller, Barbara; de Vos, Jurriaan M.; Conti, Elena

    2012-01-01

    Background and Aims Heterostyly is a floral polymorphism that has fascinated evolutionary biologists since Darwin's seminal studies on primroses. The main morphological characteristic of heterostyly is the reciprocal placement of anthers and stigmas in two distinct (distyly) floral morphs. Variation in the degree of intermorph sexual reciprocity is relatively common and known to affect patterns of pollen transfer within species. However, the partitioning of sexual organ reciprocity within and between closely related species remains unknown. This study aimed at testing whether intermorph sexual reciprocity differs within vs. between primrose species that hybridize in nature and whether the positions of sexual organs are correlated with other floral traits. Methods Six floral traits were measured in both floral morphs of 15 allopatric populations of Primula elatior, P. veris and P. vulgaris, and anther–stigma reciprocity was estimated within and between species. A combination of univariate and multivariate approaches was used to test whether positions of reproductive organs were less reciprocal between than within species, to assess correlations between sexual organ positions and other corolla traits, and to quantify differences between morphs and species. Key Results The three species were morphologically well differentiated in most floral traits, except that P. veris and P. vulgaris did not differ significantly in sexual organ positions. Overall, lower interspecific than intraspecific sexual organ reciprocity was detected. This decrease was marked between P. elatior and P. vulgaris, intermediate and variable between P. elatior and P. veris, but negligible between P. veris and P. vulgaris. Conclusions Differences in anther and stigma heights between the analysed primrose species were of the same magnitude or larger than intraspecific differences that altered pollen flow within other heterostylous systems. Therefore, it is possible to suggest that considerable

  3. Purification process for MUFA- and PUFA-based monoacylglycerols from edible oils.

    PubMed

    González-Fernández, M J; Ramos-Bueno, R P; Rodríguez-García, I; Guil-Guerrero, J L

    2017-08-01

    Important health benefits have been attributed to monoacylglycerols (MAGs) due to their various physiological functions, owing to which they become candidates for use as functional foods in order to prevent the onset of certain diseases such as colon cancer. In this work, six edible oils, namely: olive, linseed, sunflower, evening primrose, DHASCO ® and ARASCO ® have been processed to obtain different MUFA- and PUFA- based MAGs. First, the oils were hydrolyzed by means of an enzymatic process using porcine pancreatic lipase and then the reaction products were fractionated by using a liquid chromatography column containing silica gel as stationary phase in order to purify the MAGs-enriched fraction. A second chromatography process was performed using silver nitrate coated silica gel as stationary phase, in order to obtain the different MUFA- and PUFA-based MAGs from the corresponding oils. Overall, MAGs based on oleic, linoleic, α-linolenic, γ-linolenic, arachidonic and docosahexaenoic acids have been isolated in high yields and purities (92.6, 97.4, 95.3, 90.9, 100 and 95.3% purity, respectively). Positional distribution was determined by means of 1 H NMR, which revealed a mix of 1(3) and 2-MAGs in variable proportions in the different MAGs. Copyright © 2017 Elsevier B.V. and Société Française de Biochimie et Biologie Moléculaire (SFBBM). All rights reserved.

  4. A Rapid Analytical Method for Determination of Aflatoxins in Plant-Derived Dietary Supplement and Cosmetic Oils

    PubMed Central

    Mahoney, Noreen; Molyneux, Russell J.

    2010-01-01

    Consumption of edible oils derived from conventional crop plants is increasing because they are generally regarded as more healthy alternatives to animal based fats and oils. More recently there has been increased interest in the use of alternative specialty plant-derived oils, including those from tree nuts (almonds, pistachios and walnuts) and botanicals (borage, evening primrose and perilla) both for direct human consumption (e.g. as salad dressings) but also for preparation of cosmetics, soaps, and fragrance oils. This has raised the issue as to whether or not exposure to aflatoxins can result from such oils. Although most crops are subject to analysis and control, it has generally been assumed that plant oils do not retain aflatoxins due to their high polarity and lipophobicity of these compounds. There is virtually no scientific evidence to support this supposition and available information is conflicting. To improve the safety and consistency of botanicals and dietary supplements, research is needed to establish whether or not oils used directly, or in the formulation of products, contain aflatoxins. A validated analytical method for the analysis of aflatoxins in plant-derived oils is essential, in order to establish the safety of dietary supplements for consumption or cosmetic use that contain such oils. The aim of this research was therefore to develop an HPLC method applicable to a wide variety of oils from different plant sources spiked with aflatoxins, thereby providing a basis for a comprehensive project to establish an intra- and inter-laboratory validated analytical method for analysis of aflatoxins in dietary supplements and cosmetics formulated with plant oils. PMID:20235534

  5. Israeli co-retorting of coal and oil shale would break even at 22/barrel

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    Work is being carried out at the Hebrew University of Jerusalem on co-retorting of coal and oil shale. The work is funded under a cooperative agreement with the US Department of Energy. The project is exploring the conversion of US eastern high-sulfur bituminous coal in a split-stage, fluidized-bed reactor. Pyrolysis occurs in the first stage and char combustion in the second stage. These data for coal will be compared with similar data from the same reactor fueled by high-sulfur eastern US oil shale and Israeli oil shales. The project includes research at three major levels: pyrolysis in lab-scale fluidized-bed reactor;more » retorting in split-stage, fluidized-bed bench-scale process (1/4 tpd); and scale-up, preparation of full-size flowchart, and economic evaluation. In the past year's research, a preliminary economic evaluation was completed for a scaled-up process using a feed of high-sulfur coal and carbonate-containing Israeli oil shale. A full-scale plant in Israel was estimated to break even at an equivalent crude oil price of $150/ton ($22/barrel).« less

  6. Germination and Seedling Growth of Water Primroses: A Cross Experiment between Two Invaded Ranges with Contrasting Climates

    PubMed Central

    Gillard, Morgane; Grewell, Brenda J.; Futrell, Caryn J.; Deleu, Carole; Thiébaut, Gabrielle

    2017-01-01

    Aquatic ecosystems are vulnerable to biological invasions, and will also be strongly impacted by climate change, including temperature increase. Understanding the colonization dynamics of aquatic invasive plant species is of high importance for preservation of native biodiversity. Many aquatic invasive plants rely on clonal reproduction to spread, but mixed reproductive modes are common. Under future climate changes, these species may favor a sexual reproductive mode. The aim of this study was to test the germination capacity and the seedling growth of two water primrose species, Ludwigia hexapetala and Ludwigia peploides, both invasive in Europe and in the United States. We performed a reciprocal transplant of seeds of L. hexapetala and L. peploides from two invasive ranges into experimental gardens characterized by Oceanic and Mediterranean-type climates. Our results showed that higher temperatures increased or maintained germination percentages and velocity, decreased survivorship of germinants, but increased their production of biomass. The origin of the seeds had low impact on L. hexapetala responses to temperature, but greatly influenced those of L. peploides. The invasiveness of water primroses in ranges with Oceanic climates might increase with temperature. The recruitment from seed banks by these species should be considered by managers to improve the conservation of native aquatic and wetland plant species. PMID:29018472

  7. Germination and Seedling Growth of Water Primroses: A Cross Experiment between Two Invaded Ranges with Contrasting Climates.

    PubMed

    Gillard, Morgane; Grewell, Brenda J; Futrell, Caryn J; Deleu, Carole; Thiébaut, Gabrielle

    2017-01-01

    Aquatic ecosystems are vulnerable to biological invasions, and will also be strongly impacted by climate change, including temperature increase. Understanding the colonization dynamics of aquatic invasive plant species is of high importance for preservation of native biodiversity. Many aquatic invasive plants rely on clonal reproduction to spread, but mixed reproductive modes are common. Under future climate changes, these species may favor a sexual reproductive mode. The aim of this study was to test the germination capacity and the seedling growth of two water primrose species, Ludwigia hexapetala and Ludwigia peploides , both invasive in Europe and in the United States. We performed a reciprocal transplant of seeds of L. hexapetala and L. peploides from two invasive ranges into experimental gardens characterized by Oceanic and Mediterranean-type climates. Our results showed that higher temperatures increased or maintained germination percentages and velocity, decreased survivorship of germinants, but increased their production of biomass. The origin of the seeds had low impact on L. hexapetala responses to temperature, but greatly influenced those of L. peploides . The invasiveness of water primroses in ranges with Oceanic climates might increase with temperature. The recruitment from seed banks by these species should be considered by managers to improve the conservation of native aquatic and wetland plant species.

  8. 75 FR 66781 - Habitat Conservation Plan for Pacific Gas & Electric Company's Operation, Maintenance, and Minor...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-10-29

    ... Dunes evening-primrose E Oenotherawolfii Wolf's evening-primrose -- Orcuttiapilosa Hairy orcutt grass E Orcuttiatenuis Slender orcutt grass T Orcuttiaviscida Sacramento orcutt grass E Packeralayneae Layne's ragwort T... Monterey pine -- Piperiayadonii Yadon's rein orchid E Pleuropogonhooverianus North Coast semaphore grass...

  9. Heterostyly accelerates diversification via reduced extinction in primroses.

    PubMed

    de Vos, Jurriaan M; Hughes, Colin E; Schneeweiss, Gerald M; Moore, Brian R; Conti, Elena

    2014-06-07

    The exceptional species diversity of flowering plants, exceeding that of their sister group more than 250-fold, is especially evident in floral innovations, interactions with pollinators and sexual systems. Multiple theories, emphasizing flower-pollinator interactions, genetic effects of mating systems or high evolvability, predict that floral evolution profoundly affects angiosperm diversification. However, consequences for speciation and extinction dynamics remain poorly understood. Here, we investigate trajectories of species diversification focusing on heterostyly, a remarkable floral syndrome where outcrossing is enforced via cross-compatible floral morphs differing in placement of their respective sexual organs. Heterostyly evolved at least 20 times independently in angiosperms. Using Darwin's model for heterostyly, the primrose family, we show that heterostyly accelerates species diversification via decreasing extinction rates rather than increasing speciation rates, probably owing to avoidance of the negative genetic effects of selfing. However, impact of heterostyly appears to differ over short and long evolutionary time-scales: the accelerating effect of heterostyly on lineage diversification is manifest only over long evolutionary time-scales, whereas recent losses of heterostyly may prompt ephemeral bursts of speciation. Our results suggest that temporal or clade-specific conditions may ultimately determine the net effects of specific traits on patterns of species diversification.

  10. Heterostyly accelerates diversification via reduced extinction in primroses

    PubMed Central

    de Vos, Jurriaan M.; Hughes, Colin E.; Schneeweiss, Gerald M.; Moore, Brian R.; Conti, Elena

    2014-01-01

    The exceptional species diversity of flowering plants, exceeding that of their sister group more than 250-fold, is especially evident in floral innovations, interactions with pollinators and sexual systems. Multiple theories, emphasizing flower–pollinator interactions, genetic effects of mating systems or high evolvability, predict that floral evolution profoundly affects angiosperm diversification. However, consequences for speciation and extinction dynamics remain poorly understood. Here, we investigate trajectories of species diversification focusing on heterostyly, a remarkable floral syndrome where outcrossing is enforced via cross-compatible floral morphs differing in placement of their respective sexual organs. Heterostyly evolved at least 20 times independently in angiosperms. Using Darwin's model for heterostyly, the primrose family, we show that heterostyly accelerates species diversification via decreasing extinction rates rather than increasing speciation rates, probably owing to avoidance of the negative genetic effects of selfing. However, impact of heterostyly appears to differ over short and long evolutionary time-scales: the accelerating effect of heterostyly on lineage diversification is manifest only over long evolutionary time-scales, whereas recent losses of heterostyly may prompt ephemeral bursts of speciation. Our results suggest that temporal or clade-specific conditions may ultimately determine the net effects of specific traits on patterns of species diversification. PMID:24759859

  11. Contrasting evolutionary processes during Quaternary climatic changes and historical orogenies: a case study of the Japanese endemic primroses Primula sect. Reinii.

    PubMed

    Yamamoto, Masaya; Ohtani, Masato; Kurata, Kaoruko; Setoguchi, Hiroaki

    2017-11-28

    Recent biogeographic studies have illustrated that Quaternary climatic changes and historical orogenies have driven the development of high levels of biodiversity. In this context, phylogenetic niche conservatism may play a role as a major precursor of allopatric speciation. However, the effects of niche evolution on the diversification patterns of plant species under rapid habitat changes are still unknown. Here, Primula section Reinii, one of the few primroses endemic to the Japanese Archipelago, was investigated. This study aimed to clarify the phylogenetic position and relationships of section Reinii, interpret the biogeographic and diversification patterns of this group and gain a better understanding of the role of climatic niche evolution in the Japanese endemic primroses. Dated phylogeny for Primula section Reinii is presented based on the sequences of six chloroplast genes and one nuclear gene. Biogeographic history was reconstructed using statistical dispersal-vicariance analysis. Macro-evolutionary modelling of the climatic niche was combined with biogeographic inferences. Section Reinii was shown to be monophyletic based on chloroplast and nuclear sequences. Fossil-calibrated dating analysis estimated that this section diverged from its sister taxon, sect. Cortusoides, around 1.82 million years ago, and intraspecific diversification occurred within the last million years. This time frame was characterized by Quaternary climatic oscillations and uplift of high mountains in Japan. Biogeographic inference suggested that this section originated at the northern end of the Japanese Archipelago and then dispersed southward to other islands. Models of climatic niche evolution indicated that the closely related species P. reinii and P. tosanensis have contrasting niche optima and rates of niche evolution. Our results highlight that spatiotemporal heterogeneity in the Japanese islands may play a significant role in the biogeographic history of Japanese endemic

  12. Gynecology: select topics.

    PubMed

    Sidani, Mohamad; Campbell, James

    2002-06-01

    Menopause, premenstrual syndrome, dysmenorrhea, female fertility, and mastalgia are common problems not easily treated by conventional medicine. Women often seek alternative therapies to help address these conditions. Some evidence points to the efficacy of black cohosh, exercise, and possibly Kava and St. John's wort, in the treatment of menopausal symptoms. Clinical trials indicate that symptoms of premenstrual syndrome may be alleviated with calcium, magnesium, vitamin E. Thiamine, omega-3 fatty acids, the Japanese herbal concoction, TSS, and calcium have proved useful in treating women with dysmenorrhea. Symptoms of mastalgia may be attenuated by evening primrose oil, chaste tree and flaxseed oil may be helpful.

  13. Helen Primrose LeVesconte: occupational therapy clinician, educator, and maker of history.

    PubMed

    Friedland, Judith; Rais, Hadassah

    2005-06-01

    The Canadian history of our profession is not well known and our identity is thought to suffer as a result. Helen Primrose LeVesconte (7896-1982) is one pioneer in our development whose story has not been told. Our purpose is to explore LeVesconte's life and work in order to expand knowledge of our roots and thereby strengthen our identity. Using interpretive biography methods we draw on LeVesconte's own writings, articles written about her, and archival documents to describe turning point moments in her life and to display meaningful patterns in her work. LeVesconte's work as a clinician and her role and reputation as an educator, show her to have been a strong and visionary leader. Her views on the client's role, the importance of the therapist-client relationship, prevention, community-based programs, and vocational rehabilitation are of particular interest. Because LeVesconte educated over 1,850 students while director of the occupational therapy program at the University of Toronto, her influence has been felt throughout the country. Her perspective is compared to current practice; and questions are raised as to aspects of her legacy and philosophy that might now be reconsidered.

  14. Primary prevention of childhood obesity through counselling sessions at Swedish child health centres: design, methods and baseline sample characteristics of the PRIMROSE cluster-randomised trial.

    PubMed

    Döring, Nora; Hansson, Lena M; Andersson, Elina Scheers; Bohman, Benjamin; Westin, Maria; Magnusson, Margaretha; Larsson, Christel; Sundblom, Elinor; Willmer, Mikaela; Blennow, Margareta; Heitmann, Berit L; Forsberg, Lars; Wallin, Sanna; Tynelius, Per; Ghaderi, Ata; Rasmussen, Finn

    2014-04-09

    Childhood obesity is a growing concern in Sweden. Children with overweight and obesity run a high risk of becoming obese as adults, and are likely to develop comorbidities. Despite the immense demand, there is still a lack of evidence-based comprehensive prevention programmes targeting pre-school children and their families in primary health care settings. The aims are to describe the design and methodology of the PRIMROSE cluster-randomised controlled trial, assess the relative validity of a food frequency questionnaire, and describe the baseline characteristics of the eligible young children and their mothers. The PRIMROSE trial targets first-time parents and their children at Swedish child health centres (CHC) in eight counties in Sweden. Randomisation is conducted at the CHC unit level. CHC nurses employed at the participating CHC received training in carrying out the intervention alongside their provision of regular services. The intervention programme, starting when the child is 8-9 months of age and ending at age 4, is based on social cognitive theory and employs motivational interviewing. Primary outcomes are children's body mass index and waist circumference at four years. Secondary outcomes are children's and mothers' eating habits (assessed by a food frequency questionnaire), and children's and mothers' physical activity (measured by accelerometer and a validated questionnaire), and mothers' body mass index and waist circumference. The on-going population-based PRIMROSE trial, which targets childhood obesity, is embedded in the regular national (routine) preventive child health services that are available free-of-charge to all young families in Sweden. Of the participants (n = 1369), 489 intervention and 550 control mothers (75.9%) responded to the validated physical activity and food frequency questionnaire at baseline (i.e., before the first intervention session, or, for children in the control group, before they reached 10 months of age). The

  15. Macroevolution of plant defenses against herbivores in the evening primroses.

    PubMed

    Johnson, Marc T J; Ives, Anthony R; Ahern, Jeffrey; Salminen, Juha-Pekka

    2014-07-01

    Plant species vary greatly in defenses against herbivores, but existing theory has struggled to explain this variation. Here, we test how phylogenetic relatedness, tradeoffs, trait syndromes, and sexual reproduction affect the macroevolution of defense. To examine the macroevolution of defenses, we studied 26 Oenothera (Onagraceae) species, combining chemistry, comparative phylogenetics and experimental assays of resistance against generalist and specialist herbivores. We detected dozens of phenolic metabolites within leaves, including ellagitannins (ETs), flavonoids, and caffeic acid derivatives (CAs). The concentration and composition of phenolics exhibited low to moderate phylogenetic signal. There were clear negative correlations between multiple traits, supporting the prediction of allocation tradeoffs. There were also positively covarying suites of traits, but these suites did not strongly predict resistance to herbivores and thus did not act as defensive syndromes. By contrast, specific metabolites did correlate with the performance of generalist and specialist herbivores. Finally, that repeated losses of sex in Oenothera was associated with the evolution of increased flavonoid diversity and altered phenolic composition. These results show that secondary chemistry has evolved rapidly during the diversification of Oenothera. This evolution has been marked by allocation tradeoffs between traits, some of which are related to herbivore performance. The repeated loss of sex appears also to have constrained the evolution of plant secondary chemistry, which may help to explain variation in defense among plants. © 2014 The Authors. New Phytologist © 2014 New Phytologist Trust.

  16. Phytostabilization potential of evening primrose (Oenothera glazioviana) for copper-contaminated sites.

    PubMed

    Guo, Pan; Wang, Ting; Liu, Yanli; Xia, Yan; Wang, Guiping; Shen, Zhenguo; Chen, Yahua

    2014-01-01

    A field investigation, field experiment, and hydroponic experiment were conducted to evaluate feasibility of using Oenothera glazioviana for phytostabilization of copper-contaminated soil. In semiarid mine tailings in Tongling, Anhui, China, O. glazioviana, a copper excluder, was a dominant species in the community, with a low bioaccumulation factor, the lowest copper translocation factor, and the lowest copper content in seed (8 mg kg(-1)). When O. glazioviana was planted in copper-polluted farmland soil in Nanjing, Jiangsu, China, its growth and development improved and the level of γ-linolenic acid in seeds reached 17.1%, compared with 8.73% in mine tailings. A hydroponic study showed that O. glazioviana had high tolerance to copper, low upward transportation capacity of copper, and a high γ-linolenic acid content. Therefore, it has great potential for the phytostabilization of copper-contaminated soils and a high commercial value without risk to human health.

  17. Extreme environments select for reproductive assurance: evidence from evening primroses (Oenothera).

    PubMed

    Evans, Margaret E K; Hearn, David J; Theiss, Kathryn E; Cranston, Karen; Holsinger, Kent E; Donoghue, Michael J

    2011-07-01

    Competing evolutionary forces shape plant breeding systems (e.g. inbreeding depression, reproductive assurance). Which of these forces prevails in a given population or species is predicted to depend upon such factors as life history, ecological conditions, and geographical context. Here, we examined two such predictions: that self-compatibility should be associated with the annual life history or extreme climatic conditions. We analyzed data from a clade of plants remarkable for variation in breeding system, life history and climatic conditions (Oenothera, sections Anogra and Kleinia, Onagraceae). We used a phylogenetic comparative approach and Bayesian or hybrid Bayesian tests to account for phylogenetic uncertainty. Geographic information system (GIS)-based climate data and ecological niche modeling allowed us to quantify climatic conditions. Breeding system and reproductive life span are not correlated in Anogra and Kleinia. Instead, self-compatibility is associated with the extremes of temperature in the coldest part of the year and precipitation in the driest part of the year. In the 60 yr since this pattern was anticipated, this is the first demonstration of a relationship between the evolution of self-compatibility and climatic extremes. We discuss possible explanations for this pattern and possible implications with respect to anthropogenic climate change. © 2011 The Authors. New Phytologist © 2011 New Phytologist Trust.

  18. Botanical medicine and cancer: a review of the safety and efficacy.

    PubMed

    Boon, Heather; Wong, Jacqueline

    2004-12-01

    It is currently estimated that > 50% of all patients diagnosed with cancer explore complementary and alternative medicine - especially herbal medicine. We conducted a comprehensive review to assess the safety and efficacy of herbal medicines commonly used by patients in an attempt to: prevent cancer; treat cancer; and treat adverse effects associated with conventional cancer treatments. Current evidence suggests that Asian ginseng, garlic, green tea, tomatoes and soy intake as part of the diet may be useful in preventing various cancers; additional research is needed in order to determine the efficacy of essiac, evening primrose oil, mistletoe, reishi, shiitake and turmeric as cancer treatments; and ginger may be effective in treating chemotherapy-induced nausea and vomiting.

  19. NCCAM's 5 Most Searched-For Herbs of 2012: What the Science Says about Evening Primrose Oil, St. John's Wort, Fenugreek,...

    MedlinePlus

    ... Resources CME/CEU and Online Lectures Online Continuing Education Series Distinguished Lecture Series Integrated Medicine Research Lecture ... has been a source of many folk or traditional remedies and more modern medicinal and cosmetic products. At various times aloe ...

  20. [Treatment of cough in respiratory tract infections - the effect of combining the natural active compounds with thymol].

    PubMed

    Schönknecht, Karina; Krauss, Hanna; Jambor, Jerzy; Fal, Andrzej M

    Cough is one of the characteristic symptoms of upper respiratory tract infections (URI). Herbal medicines are often used in the treatment of the cough associated with infection and to accelerate recovery or support the immune system. An example of such products are extracts of thyme and primrose, and also their combination with thymol. Thymus vulgaris is a spasmolytic, antimicrobial, anti-inflammatory, immunomodulatory and antioxidant agent. The most important component responsible for the activity of thyme is thymol contained in the volatile thyme oil. Primrose is, most of all, a saponine agent with expectorant and secretolytic activity, showing also spasmolytic, anti-inflammatory and antimicrobial effects. Because of the additive effects of the mentioned extracts and their wide activity profile they are often used as a combination drug. The use of this combination was assessed in the URI with the effects of alleviation of cough and dyspnea, and shortening the length of the disease. The effectiveness of the drug containing the extracts of thyme and primrose with the addition of thymol (Bronchosol®) was comparable to synthetic ambroxol and its safety has been proved. Moreover, the in-vitro antibacterial and antifungal effects of this drug have been evaluated.

  1. "Towards an even healthier Mediterranean diet".

    PubMed

    Estruch, R; Salas-Salvadó, J

    2013-12-01

    Dietary guidelines to promote good health are usually based on foods, nutrients, and dietary patterns predictive of chronic disease risk in epidemiologic studies. However, sound nutritional recommendations for cardiovascular prevention should be based on the results of large randomized clinical trials with "hard" end-points as the main outcome. Such evidence has been obtained for the Mediterranean diet from the PREDIMED (Prevención con Dieta Mediterránea) trial and the Lyon Heart Study. The traditional Mediterranean diet was that found in olive growing areas of Crete, Greece, and Southern Italy in the late 1950s. Their major characteristics include: a) a high consumption of cereals, legumes, nuts, vegetables, and fruits; b) a relatively high-fat consumption, mostly provided by olive oil; c) moderate to high fish consumption; d) poultry and dairy products consumed in moderate to small amounts; e) low consumption of red meats, and meat products; and f) moderate alcohol intake, usually in the form of red wine. However, these protective effects of the traditional Mediterranean diet may be even greater if we upgrade the health effects of this dietary pattern changing the common olive oil used for extra-virgin olive oil, increasing the consumption of nuts, fatty fish and whole grain cereals, reducing sodium intake, and maintaining a moderate consumption of wine with meals. © 2013 Elsevier B.V. All rights reserved.

  2. Oil Spill Hydrodynamics, from Droplets to Oil Slicks

    NASA Astrophysics Data System (ADS)

    Moghimi, S.; Restrepo, J. M.; Venkataramani, S.

    2016-02-01

    A fundamental challenge in proposing a model for the fate of oil in oceans relates to the extreme spatio-temporal scales required by hazard/abatement studies. We formulate a multiscale model that takes into account droplet dynamics and its effects on submerged and surface oil. The upscaling of the microphysics, within a mass conserving model, allows us to resolve oil mass exchanges between the oil found on the turbulent ocean surface and the ocean interior. In addition to presenting the model and the mutl-scale methodology we apply this upscaling to the evolution of oil on shelves and show how nearshore oil spills demonstrate dynamics that are not easily captured by oil models based on idealized tracer dynamics. In particular we demonstrate how oil can slow down and even park itself under certain oceanic conditions. An explanation for this phenomenon is proposed as well.

  3. Pollination limitation to reproductive success in the Missouri evening primrose, Oenothera macrocarpa (Onagraceae).

    PubMed

    Moody-Weis, J M; Heywood, J S

    2001-09-01

    Habitat fragmentation may result in plant populations that are less attractive to pollinators and thus susceptible to reduced reproductive output due to pollination limitation. Pollination limitation was investigated in three Missouri populations of Oenothera macrocarpa, a hawk-moth-pollinated, perennial herb. The populations represented extremes in size and habitat quality. Following supplemental pollination, mean fertilization success (proportion of ovules fertilized) across populations increased from 24.3 to 44.8% and mean seed set (proportion of ovules that matured into seed) increased from 14.7 to 27.9%. These increases were statistically significant in two of the three populations. Failure to achieve 100% fertilization and seed set following supplementation indicates that other factors, in addition to pollination, were limiting to female reproductive success. Fruit set was pollination limited in only one population. Fruits matured with as few as one seed, suggesting that fruit set was not resource limited. The degree of pollination limitation was greatest in the most disturbed population. The population located in the highest-quality habitat was not significantly pollination limited. This suggests that pollination limitation is occurring, at least in part, because of reduced pollinator activity in degraded habitats.

  4. Reevaluation of Vegetational Characteristics at the CERC (Coastal Engineering Research Center) Field Research Facility, Duck, North Carolina.

    DTIC Science & Technology

    1983-03-01

    var. cerifera L. Wax myrtle Onagraceae *Ludiigia aZata Ell. W. - r-priurose Oenothera frticoea L. drops 0. hisniflsa Nuttall Evening primrose... Orchidaceae Spiranthee cernua ver. odorata Nodding ladies’ (Nuttall) Correll. tresses Passiflorarese *PassifZora lutea L. Passion-flower Phytolacaceat POytoZaca

  5. Physiological effects of γ-linolenic acid and sesamin on hepatic fatty acid synthesis and oxidation.

    PubMed

    Ide, Takashi; Iwase, Haruka; Amano, Saaya; Sunahara, Saki; Tachihara, Ayuka; Yagi, Minako; Watanabe, Tsuyoshi

    2017-03-01

    Interrelated effects of γ-linolenic acid (GLA) and sesamin, a sesame lignan, on hepatic fatty acid synthesis and oxidation were examined. Rats were fed experimental diets supplemented with 0 or 2 g/kg sesamin (1:1 mixture of sesamin and episesamin) and containing 100 g/kg of palm oil (saturated fat), safflower oil rich in linoleic acid, or oil of evening primrose origin containing 43% GLA (GLA oil) for 18 days. In rats fed sesamin-free diets, GLA oil, compared with other oils, increased the activity and mRNA levels of various enzymes involved in fatty acid oxidation, except for some instances. Sesamin greatly increased these parameters, and the enhancing effects of sesamin on peroxisomal fatty acid oxidation rate and acyl-CoA oxidase, enoyl-CoA hydratase and acyl-CoA thioesterase activities were more exaggerated in rats fed GLA oil than in the animals fed other oils. The combination of sesamin and GLA oil also synergistically increased the mRNA levels of some peroxisomal fatty acid oxidation enzymes and of several enzymes involved in fatty acid metabolism located in other cell organelles. In the groups fed sesamin-free diets, GLA oil, compared with other oils, markedly reduced the activity and mRNA levels of various lipogenic enzymes. Sesamin reduced all these parameters, except for malic enzyme, in rats fed palm and safflower oils, but the effects were attenuated in the animals fed GLA oil. These changes by sesamin and fat type accompanied profound alterations in serum lipid levels. This may be ascribable to the changes in apolipoprotein-B-containing lipoproteins. Copyright © 2016 Elsevier Inc. All rights reserved.

  6. Bio-Friendly Alternatives for Xylene – Carrot oil, Olive oil, Pine oil, Rose oil

    PubMed Central

    Nandan, Surapaneni Rateesh Kumar; Kulkarni, Pavan G.; Rao, Thokala Madhusudan; Palakurthy, Pavan

    2015-01-01

    Background Xylene is a flammable liquid with characteristic petroleum or aromatic odours, it is miscible with most of the organic solvents and paraffin wax. Xylene clears tissues rapidly and renders transparency, facilitating clearing endpoint determination, this made it to be used as a clearing agent in routine histopathological techniques. Even though it is a good clearing agent, it causes damage to the tissues by its hardening effect particularly those fixed in non-protein coagulant fixatives. Apart from these tissue effects, it has severe, long lasting ill effects on health of technicians and pathologists when exposed to longer duration. Hence in order to overcome these effects and replace xylene with a safe alternative agent, the present study was carried out to assess the clearing ability and bio-friendly nature of four different natural oils i.e., Carrot oil, Olive oil, Pine oil and Rose oil in comparison with that of Xylene. According to Bernoulli’s principle of fluid dynamics, to decrease viscosity of these oils and increase penetration into tissues for rapid clearing hot-air oven technique was used. Aims To assess:1) Clearing ability and bio-friendly nature of four different oils i.e., Carrot oil, Olive oil, Pine oil, Rose oil in comparison with that of xylene, 2) Application of Bernoulli’s principle of fluid dynamics in rapid clearing of tissues by using hot-air oven. Materials and Methods Forty different formalin fixed tissue samples were taken. Each sample of tissue was cut into 5 bits (40x5=200 total bits) which were subjected for dehydration in differential alcohol gradients. Later, each bit is kept in 4 different oils such as Carrot oil, Olive oil, Pine oil, Rose oil and xylene and transferred into hot-air oven. Further routine steps of processing, sectioning and staining were done. Individual sections cleared in four different oils were assessed for cellular architecture, staining quality and a comparison was done between them. Results Results

  7. Encapsulated fish oil enriched in alpha-tocopherol alters plasma phospholipid and mononuclear cell fatty acid compositions but not mononuclear cell functions.

    PubMed

    Yaqoob, P; Pala, H S; Cortina-Borja, M; Newsholme, E A; Calder, P C

    2000-03-01

    Several studies have reported that dietary fish oil (FO) supplementation alters cytokine production and other functional activities of peripheral blood mononuclear cells (PBMC). However, few of these studies have been placebo controlled and few have related the functional changes to alterations in PBMC fatty acid composition Healthy subjects supplemented their diets with 9 g day-1 of encapsulated placebo oil (3 : 1 mix of coconut and soybean oils), olive oil (OO), safflower oil (SO), evening primrose oil (EPO) or FO [providing 2.1 g eicosapentaenoic acid (EPA) plus 1.1 g docosahexaenoic acid (DHA) per day] for 12 weeks; the capsules also provided 205 mg alpha-tocopherol per day. Blood was sampled at 4-weekly intervals and plasma and PBMC prepared. Plasma phospholipid and PBMC fatty acid composition, plasma alpha-tocopherol and thiobarbituric acid-reactive substance concentrations, plasma total antioxidant capacity, the proportions of different PBMC subsets, the proportions of PBMC expressing the adhesion molecules CD2, CD11b and CD54, and PBMC functions (lymphocyte proliferation, natural killer cell activity, cytokine production) were measured. All measurements were repeated after a 'washout' period of 8 weeks. The placebo, OO and SO capsules had no effect on plasma phospholipid or PBMC fatty acid composition. The proportion of dihomo-gamma-linolenic acid in plasma phospholipids was elevated in subjects taking EPO and was decreased in subjects taking FO. There was no appearance of gamma-linolenic acid in the plasma phospholipids or PBMC in subjects taking EPO. There was a marked increase in the proportion of EPA in the plasma phospholipids (10-fold) and PBMC (four-fold) of subjects taking FO supplements; this increase was maximal after 4 weeks of supplementation. There was an increase in the proportion of DHA in plasma phospholipids and PBMC, and an approximately 20% decrease in the proportion of arachidonic acid in plasma phospholipids and PBMC, during FO

  8. An experimental study on oil supply in a space bearing with an oil-impregnated retainer

    NASA Astrophysics Data System (ADS)

    Liu, Jianhai; Fan, Youwen; Wen, Shizhu

    1993-06-01

    Parched elastohydrodynamic lubrication (EHL) film thickness in a space ball bearing is measured by electrical capacitance and resistance, and parched transients of oil film and lubricant breakdown are observed. With different oil-impregnated polymer retainers, which are employed as oil supply resources, parched degradation is restricted to some degree, even lubricant breakdown disappears and a steady state of the oil film is produced. A long-term space bail bearing demands both the lowest driving torque and a steady state oil film, which depends on a strictly controlled oil supply from oil-impregnated retainers. The results of this experimental research describe the effects of oil supply by amounts of oil in retainers on parched EHL.

  9. Transporting US oil imports: The impact of oil spill legislation on the tanker market

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rowland, P.J.

    1992-05-01

    The Oil Pollution Act of 1990 ( OPA'') and an even more problematic array of State pollution laws have raised the cost, and risk, of carrying oil into and out of the US. This report, prepared under contract to the US Department of energy's Office of Domestic and International Policy, examines the impact of Federal and State oil spill legislation on the tanker market. It reviews the role of marine transportation in US oil supply, explores the OPA and State oil spill laws, studies reactions to OPA in the tanker and tank barge industries and in related industries such asmore » insurance and ship finance, and finally, discusses the likely developments in the years ahead. US waterborne oil imports amounted to 6.5 million B/D in 1991, three-quarters of which was crude oil. Imports will rise by almost 3 million B/D by 2000 according to US Department of energy forecasts, with most of the crude oil growth after 1995. Tanker demand will grow even faster: most of the US imports and the increased traffic to other world consuming regions will be on long-haul trades. Both the number of US port calls by tankers and the volume of offshore lightering will grow. Every aspect of the tanker industry's behavior is affected by OPA and a variety of State pollution laws.« less

  10. Semiclassical unified description of wobbling motion in even-even and even-odd nuclei

    NASA Astrophysics Data System (ADS)

    Raduta, A. A.; Poenaru, R.; Ixaru, L. Gr.

    2017-11-01

    A unitary description for wobbling motion in even-even and even-odd nuclei is presented. In both cases compact formulas for wobbling frequencies are derived. The accuracy of the harmonic approximation is studied for the yrast as well as for the excited bands in the even-even case. Important results for the structure of the wave function and its behavior inside the two wells of the potential energy function corresponding to the Bargmann representation are pointed out. Applications to 158Er and 163Lu reveal a very good agreement with available data. Indeed, the yrast energy levels in the even-even case and the first four triaxial superdeformed bands, TSD1, TSD2, TSD3, and TSD4, are realistically described. Also, the results agree with the data for the E 2 and M 1 intra- as well as interband transitions. Perspectives for the formalism development and an extensive application to several nuclei from various regions of the nuclides chart are presented.

  11. Unconventional Liquids, Peak Oil and Climate Change

    NASA Astrophysics Data System (ADS)

    Hughes, J. D.

    2015-12-01

    Oil is the largest source of primary energy in the world, at 32% of 2014 consumption. Forecasts by the International Energy Agency suggest oil will continue to provide the largest share of global energy through 2040, even with new policies to mitigate greenhouse gas emissions. The IPCC's Representative Concentration Pathway (RCP) scenarios indicate that between 1.5 and 3.8 trillion barrels of oil will be burnt between 2015 and 2100. Various sources suggest that the world has 5 to 6 trillion barrels of remaining recoverable oil, more than half of which are in low grade deposits. Although oil sands and extra heavy oil are claimed to hold 1.5 trillion barrels, assessments of major deposits in the Canadian oil sands and the Venezuela Orinoco Belt, which hold the bulk of these resources, total less than 500 billion barrels of recoverable oil. Kerogen oil (oil shale), which has never been produced in anything but miniscule volumes, comprises an additional trillion barrels of these estimates. These unconventional deposits are very different from the conventional oil of the past as: - they are rate constrained, as they require massive upfront capital investments and lengthy construction periods, and therefore cannot be scaled up quickly in response to declines in conventional production. - they are expensive, both in terms of cost per barrel and the large energy inputs required for production. The best in situ oil sands deposits may yield an energy return of 3:1 and kerogen oil even less if it ever becomes commercially viable. This compares to 10:1 or more for conventional oil. Shale oil (light tight oil), may yield another 300 billion barrels worldwide, but suffers from high decline rates, expensive wells and limited availability of high quality deposits. The most productive and economically viable portions of these unconventional deposits tend to be exploited first, leaving the less productive, higher cost oil for later. As a result, increasing global oil consumption

  12. Transporting US oil imports: The impact of oil spill legislation on the tanker market. Draft final report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Rowland, P.J.

    1992-05-01

    The Oil Pollution Act of 1990 (``OPA``) and an even more problematic array of State pollution laws have raised the cost, and risk, of carrying oil into and out of the US. This report, prepared under contract to the US Department of energy`s Office of Domestic and International Policy, examines the impact of Federal and State oil spill legislation on the tanker market. It reviews the role of marine transportation in US oil supply, explores the OPA and State oil spill laws, studies reactions to OPA in the tanker and tank barge industries and in related industries such as insurancemore » and ship finance, and finally, discusses the likely developments in the years ahead. US waterborne oil imports amounted to 6.5 million B/D in 1991, three-quarters of which was crude oil. Imports will rise by almost 3 million B/D by 2000 according to US Department of energy forecasts, with most of the crude oil growth after 1995. Tanker demand will grow even faster: most of the US imports and the increased traffic to other world consuming regions will be on long-haul trades. Both the number of US port calls by tankers and the volume of offshore lightering will grow. Every aspect of the tanker industry`s behavior is affected by OPA and a variety of State pollution laws.« less

  13. Robust and Superhydrophobic Surface Modification by a "Paint + Adhesive" Method: Applications in Self-Cleaning after Oil Contamination and Oil-Water Separation.

    PubMed

    Chen, Baiyi; Qiu, Jianhui; Sakai, Eiichi; Kanazawa, Nobuhiro; Liang, Ruilu; Feng, Huixia

    2016-07-13

    Conventional superhydrophobic surfaces have always depended on expensive, sophisticated, and fragile roughness structures. Therefore, poor robustness has turned into the bottleneck for large-scale industrial applications of the superhydrophobic surfaces. To handle this problem, a superhydrophobic surface with firm robustness urgently needs to be developed. In this work, we created a versatile strategy to fabricate robust, self-cleaning, and superhydrophobic surfaces for both soft and hard substrates. We created an ethanol based suspension of perfluorooctyltriethoxysilane-mdodified calcium carbonate nanoparticles which can be sprayed onto both hard and soft substrates to form superhydrophobic surfaces. For all kinds of substrates, spray adhesive was directly coated onto abluent substrate surfaces to promote the robustness. These superhydrophobic surfaces showed remarkable robustness against knife scratch and sandpaper abrasion, while retaining its superhydrophobicity even after 30 abrasion cycles with sandpaper. What is more, the superhydrophobic surfaces have shown promising potential applications in self-cleaning and oil-water separation. The surfaces retained their self-cleaning property even immersed in oil. In addition to oil-water separation, the water contents in oil after separation of various mixtures were all below 150 ppm, and for toluene even as low as 55 ppm. Furthermore, the as-prepared device for oil-water separation could be cycled 6 times and still retained excellent oil-water separation efficiency.

  14. Oil-in-oil emulsions stabilised solely by solid particles.

    PubMed

    Binks, Bernard P; Tyowua, Andrew T

    2016-01-21

    A brief review of the stabilisation of emulsions of two immiscible oils is given. We then describe the use of fumed silica particles coated with either hydrocarbon or fluorocarbon groups in acting as sole stabilisers of emulsions of various vegetable oils with linear silicone oils (PDMS) of different viscosity. Transitional phase inversion of emulsions, containing equal volumes of the two oils, from silicone-in-vegetable (S/V) to vegetable-in-silicone (V/S) occurs upon increasing the hydrophobicity of the particles. Close to inversion, emulsions are stable to coalescence and gravity-induced separation for at least one year. Increasing the viscosity of the silicone oil enables stable S/V emulsions to be prepared even with relatively hydrophilic particles. Predictions of emulsion type from calculated contact angles of a silica particle at the oil-oil interface are in agreement with experiment provided a small polar contribution to the surface energy of the oils is included. We also show that stable multiple emulsions of V/S/V can be prepared in a two-step procedure using two particle types of different hydrophobicity. At fixed particle concentration, catastrophic phase inversion of emulsions from V/S to S/V can be effected by increasing the volume fraction of vegetable oil. Finally, in the case of sunflower oil + 20 cS PDMS, the study is extended to particles other than silica which differ in chemical type, particle size and particle shape. Consistent with the above findings, we find that only sufficiently hydrophobic particles (clay, zinc oxide, silicone, calcium carbonate) can act as efficient V/S emulsion stabilisers.

  15. Microbicide activity of clove essential oil (Eugenia caryophyllata)

    PubMed Central

    Nuñez, L.; Aquino, M. D’

    2012-01-01

    Clove essential oil, used as an antiseptic in oral infections, inhibits Gram-negative and Gram-positive bacteria as well as yeast. The influence of clove essential oil concentration, temperature and organic matter, in the antimicrobial activity of clove essential oil, was studied in this paper, through the determination of bacterial death kinetics. Escherichia coli, Staphylococcus aureus and Pseudomonas aeruginosa were the microorganisms selected for a biological test. To determine the temperature effect, they were assayed at 21° and 37° C. The concentration coefficient was determined with 0.4%, and 0.2% of essential oil. The influence of the presence of organic matter was determined with 0.4% of essential oil. The results obtained demonstrated that Escherichia coli were more sensitive even though the essential oil exerted a satisfactory action in three cases. In the three microbial species, 0.4% of essential oil at 21° C have reduced the bacterial population in 5 logarithmic orders. Organic matter reduces the antibacterial activity even though the bactericide efficacy was not lost. Clove essential oil can be considered as a potential antimicrobial agent for external use PMID:24031950

  16. Detection of Oil in Water Column: Sensor Design

    DTIC Science & Technology

    2013-02-01

    rivers , and initiating dispersant application or oil recovery operations. Challenges in detecting oil within the water column include poor...facility and along transects in the Delaware River . However, all readings were at background, even when there was visible oil on the water surface...levels for extremely high CDOM rich rivers . Detection of Oil in Water Column: Sensor Design 14 UNCLAS//Public | CG-926 RDC | Fitzpatrick, et al

  17. [Separation of gamma linolenic acid from evening primrose oil with urea inclusion--orthogonal experiment of optimizing technological parameters and observation of urea inclusion compound I].

    PubMed

    Wang, Hua; Ling, Man; Xue, Gang; Liu, Fengxia; Guo, Shuxian

    2010-05-01

    The influence on the urea inclusion compound under different conditions (allocated proportion, time of inclusion, temperature of inclusion) were studied through the orthogonal test, and theoretical reference of urea inclusion process for further optimization wound be offered. The orthogonal experiment was adopted, and microscope was used to observe the shape, aperture size of the urea inclusion compound under different technological parameters, the GC was employed to inspect the purity of GLA. The results indicated that the ratio of fatty acids and urea, inclusion of temperature, time of inclusion had great effect on urea inclusion compound. The three factors and its interactions significantly affected the purity of GLA. The results also showed that the best process was that the ratio of fatty acids and urea was 1 : 3, temperature of inclusion was--15 degrees C, time of inclusion was 24 h. Under the best condition, the purity of GLA reach up to 95.575 9%; and it is feasible to observe the shape and the amount of the urea inclusion compound to reflect and guide the urea inclusion technology.

  18. Remote sensing assessment of oil lakes and oil-polluted surfaces at the Greater Burgan oil field, Kuwait

    NASA Astrophysics Data System (ADS)

    Kwarteng, Andy Yaw

    A heinous catastrophe imposed on Kuwait's desert environment during the 1990 to 1991 Arabian Gulf War was the formation of oil lakes and oil-contaminated surfaces. Presently, the affected areas consist of oil lakes, thick light and disintegrated tarmats, black soil and vegetation. In this study, Landsat TM, Spot, colour aerial photographs and IRS-1D digital image data acquired between 1989 and 1998 were used to monitor the spatial and temporal changes of the oil lakes and polluted surfaces at the Greater Burgan oil field. The use of multisensor datasets provided the opportunity to observe the polluted areas in different wavelengths, look angles and resolutions. The images were digitally enhanced to optimize the visual outlook and improve the information content. The data documented the gradual disappearance of smaller oil lakes and soot/black soil from the surface with time. Even though some of the contaminants were obscured by sand and vegetation and not readily observed on the surface or from satellite images, the harmful chemicals still remain in the soil. Some of the contaminated areas displayed a remarkable ability to support vegetation growth during the higher than average rainfall that occurred between 1992 to 1998. The total area of oil lakes calculated from an IRS-1D panchromatic image acquired on 16 February 1998, using supervised classification applied separately to different parts, was 24.13 km 2.

  19. Characteristics and oil sorption effectiveness of kapok fibre, sugarcane bagasse and rice husks: oil removal suitability matrix.

    PubMed

    Ali, Norizan; El-Harbawi, Mohanad; Jabal, Ayman Abo; Yin, Chun-Yang

    2012-01-01

    The characteristics and water/oil sorption effectiveness ofkapok fibre, sugarcane bagasse and rice husks have been compared. The three biomass types were subjected to field emission scanning electron microscopy-energy dispersive X-ray spectroscopy and surface tension analyses for liquid-air and oil-water systems were conducted. Both kapok fibre and sugarcane bagasse exhibit excellent oil sorption capabilities for diesel, crude, new engine and used engine oils as their oil sorption capacities all exceed 10 g/g. The synthetic sorbent exhibits oil sorption capacities comparable with sugarcane bagasse, while rice husks exhibit the lowest oil sorption capacities among all the sorbents. Kapok fibre shows overwhelmingly high oil-to-water sorption (O/W) ratios ranging from 19.35 to 201.53 while sugarcane bagasse, rice husks and synthetic sorbent have significantly lower O/W ratios (0.76-2.69). This suggests that kapok fibre is a highly effective oil sorbent even in well-mixed oil-water media. An oil sorbent suitability matrix is proposed to aid stakeholders in evaluating customized oil removal usage of the natural sorbents.

  20. Helping nature clean up oil spills

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Paddock, A.

    Oil spills are nothing new. In fact, for millions of years crude oil has been seeping up to the Earth`s surface, and for all that time Mother Nature has been on the job with microbes, or bacteria, to harmlessly convert the oil to water and carbon dioxide gas. Not all bacteria are bad. True, some can make us sick, however, the good ones help us bake bread, brew beer, and even clean up oil spills by a process known as biodegradation. Oil and bacteria don`t easily get together because oil and water don`t mix and bacteria prefer to stay inmore » water. After some oil tankers spills in the English Channel 25 years ago, major oil companies (Arco, BP, Exxon, and others) developed oil dispersant products-specialized chemicals that make oils and sea water mix. The simplest examples of similar wetting agents are soaps and detergents. Now, thanks to dispersants, the natural bacteria at sea can easily get to the oil and the normally slow biodegradation process goes rather quickly.« less

  1. In-situ burning of oil in coastal marshes. 2. Oil spill cleanup efficiency as a function of oil type, marsh type, and water depth.

    PubMed

    Lin, Qianxin; Mendelssohn, Irving A; Carney, Kenneth; Miles, Scott M; Bryner, Nelson P; Walton, William D

    2005-03-15

    In-situ burning of spilled oil, which receives considerable attention in marine conditions, could be an effective way to cleanup wetland oil spills. An experimental in-situ burn was conducted to study the effects of oil type, marsh type, and water depth on oil chemistry and oil removal efficiency from the water surface and sediment. In-situ burning decreased the totaltargeted alkanes and total targeted polycyclic aromatic hydrocarbons (PAHs) in the burn residues as compared to the pre-burn diesel and crude oils. Removal was even more effective for short-chain alkanes and low ring-number PAHs. Removal efficiencies for alkanes and PAHs were >98% in terms of mass balance although concentrations of some long-chain alkanes and high ring-number PAHs increased in the burn residue as compared to the pre-burn oils. Thus, in-situ burning potentially prevents floating oil from drifting into and contaminating adjacent habitats and penetrating the sediment. In addition, in-situ burning significantly removed diesel oil that had penetrated the sediment for all water depths. Furthermore, in-situ burning at a water depth 2 cm below the soil surface significantly removed crude oil that had penetrated the sediment. As a result, in-situ burning may reduce the long-term impacts of oil on benthic organisms.

  2. What's new in atopic eczema? An analysis of systematic reviews published in 2012 and 2013. Part 2. Treatment and prevention.

    PubMed

    Madhok, V; Futamura, M; Thomas, K S; Barbarot, S

    2015-06-01

    This review provides a summary of key findings from 22 systematic reviews on atopic eczema (AE) published over the 2-year period from January 2012 to 31 December 2013, focusing on prevention and treatment of AE. For an update of systematic reviews on the epidemiology, mechanisms of disease and methodological issues, see Part 1 of this update. Based on current systematic review evidence, the most promising intervention for the prevention of AE is the use of probiotics (and possibly prebiotics) during the late stages of pregnancy and early life. Exposure to household pets, especially dogs, may also be protective, but exclusive breastfeeding for up to 7 months does not confer benefit. The role of vitamin D in preventing AE is currently unclear. Very few of the systematic reviews provided additional evidence for the use of specific treatments for AE. Further research is required to establish the role of desensitization, Chinese herbal medicines, homeopathy and specialist clothing. Nevertheless, there is now clear evidence that evening primrose oil and borage oil are not effective for the treatment of AE. There have been no randomized controlled trials on the use of H1 anti-histamines as monotherapy for the treatment of AE. © 2015 British Association of Dermatologists.

  3. Broader jurisdiction for the Wyoming Oil and Gas Conservation Commission. Gulf Oil Corp. v. Wyoming Oil and Gas Conservation Commission and Story Oil Impact Committee, 693 P. 2d 227 (Wyo. 1985)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Wendtland, A.T.

    1986-01-01

    Analysis of the Gulf Oil Corp. v. Wyoming Oil and Gas Conservation Commission and Story Oil Impact Committee case finds that the Wyoming Supreme Court has set an important precedent. The case stands for the premise that Wyoming may regulate the environmental effects of oil and gas development on lands outside of federal lease boundaries. The problem with this holding is that it was the wrong case in which to set that precedent. The Wyoming Oil and gas Conservation Act does not grant the Commission broad enough authority to regulate as they did, even if such regulation is not preemptedmore » at the federal level. While the court may have perceived a need to vest the Commission with this broad authority, it should leave such decisions to the state legislature or leave this type of regulation to the appropriate federal agency.« less

  4. Oil source-fingerprinting in support of polarimetric radar mapping of Macondo-252 oil in Gulf Coast marshes

    USGS Publications Warehouse

    Ramsey, Elijah W.; Meyer, Buffy M.; Rangoonwala, Amina; Overton, Edward; Jones, Cathleen E.; Bannister, Terri

    2014-01-01

    Polarimetric synthetic aperture radar (PolSAR) data exhibited dramatic, spatially extensive changes from June 2009 to June 2010 in Barataria Bay, Louisiana. To determine whether these changes were associated with the Deepwater Horizon (DWH) oil spill, twenty-nine sediment samples were collected in 2011 from shoreline and nearshore–interior coastal marsh locations where oil was not observed visually or with optical sensors during the spill. Oil source-fingerprinting and polytopic vector analysis were used to link DWH oil to PolSAR changes. Our results prove that DWH oil extended beyond shorelines and confirm the association between presence of DWH oil and PolSAR change. These results show that the DWH oil spill probably affected much more of the southeastern Louisiana marshland than originally concluded from ground and aerial surveys and verify that PolSAR is a powerful tool for tracking oil intrusion into marshes with high probability even where contamination is not visible from above the canopy.

  5. Getting Over the Barrel- Achieving Independence from Foreign Oil in 2018

    DTIC Science & Technology

    2009-02-03

    material called kerogen. Kerogen can be converted into oil via heating in the chemical process of pyrolysis .44 Depending on the richness of oil shale, it...vegetable oil, animal fat, corn , soybeans, jatropha seed oil, palm oil, switch grass and even algae. Biofuel production techniques and technologies...vary widely based on the input source – sugar-based, starch-based or oil-based. This document only examines corn -based ethanol production. The other

  6. Clinical Benefits of n-3 PUFA and ɤ-Linolenic Acid in Patients with Rheumatoid Arthritis.

    PubMed

    Veselinovic, Mirjana; Vasiljevic, Dragan; Vucic, Vesna; Arsic, Aleksandra; Petrovic, Snjezana; Tomic-Lucic, Aleksandra; Savic, Maja; Zivanovic, Sandra; Stojic, Vladislava; Jakovljevic, Vladimir

    2017-03-25

    (1) Background: Marine n -3 polyunsaturated fatty acids (PUFA) and ɤ-linolenic acid (GLA) are well-known anti-inflammatory agents that may help in the treatment of inflammatory disorders. Their effects were examined in patients with rheumatoid arthritis; (2) Methods: Sixty patients with active rheumatoid arthritis were involved in a prospective, randomized trial of a 12 week supplementation with fish oil (group I), fish oil with primrose evening oil (group II), or with no supplementation (group III). Clinical and laboratory evaluations were done at the beginning and at the end of the study; (3) Results: The Disease Activity Score 28 (DAS 28 score), number of tender joints and visual analogue scale (VAS) score decreased notably after supplementation in groups I and II ( p < 0.001). In plasma phospholipids the n -6/ n -3 fatty acids ratio declined from 15.47 ± 5.51 to 10.62 ± 5.07 ( p = 0.005), and from 18.15 ± 5.04 to 13.50 ± 4.81 ( p = 0.005) in groups I and II respectively. The combination of n -3 PUFA and GLA (group II) increased ɤ-linolenic acid (0.00 ± 0.00 to 0.13 ± 0.11, p < 0.001), which was undetectable in all groups before the treatments; (4) Conclusion: Daily supplementation with n -3 fatty acids alone or in combination with GLA exerted significant clinical benefits and certain changes in disease activity.

  7. Oil spill dispersants: boon or bane?

    PubMed

    Prince, Roger C

    2015-06-02

    Dispersants provide a reliable large-scale response to catastrophic oil spills that can be used when the preferable option of recapturing the oil cannot be achieved. By allowing even mild wave action to disperse floating oil into tiny droplets (<70 μm) in the water column, seabirds, reptiles, and mammals are protected from lethal oiling at the surface, and microbial biodegradation is dramatically increased. Recent work has clarified how dramatic this increase is likely to be: beached oil has an environmental residence of years, whereas dispersed oil has a half-life of weeks. Oil spill response operations endorse the concept of net environmental benefit, that any environmental costs imposed by a response technique must be outweighed by the likely benefits. This critical review discusses the potential environmental debits and credits from dispersant use and concludes that, in most cases, the potential environmental costs of adding these chemicals to a polluted area are likely outweighed by the much shorter residence time, and hence integrated environmental impact, of the spilled oil in the environment.

  8. Hypolipidemic effect of oils with balanced amounts of fatty acids obtained by blending and interesterification of coconut oil with rice bran oil or sesame oil.

    PubMed

    Reena, Malongil B; Lokesh, Belur R

    2007-12-12

    Blended oils comprising coconut oil (CNO) and rice bran oil (RBO) or sesame oil (SESO) with saturated fatty acid/monounsaturated fatty acid/polyunsaturated fatty acid at a ratio of 1:1:1 and polyunsaturated/saturated ratio of 0.8-1 enriched with nutraceuticals were prepared. Blended oils (B) were subjected to interesterification reaction using sn-1,3 specific Lipase from Rhizomucor miehei. Fatty acid composition and nutraceutical contents of the blended oil were not affected by interesterification reaction. Male Wistar rats were fed with AIN-76 diet containing 10% fat from CNO, RBO, SESO, CNO+RBO blend (B), CNO+SESO(B), CNO+RBO interesterified (I), or CNO+SESO(I) for 60 days. Serum total cholesterol (TC), low-density lipoprotein cholesterol, and triacylglycerols (TAGs) were reduced by 23.8, 32.4, and 13.9%, respectively, in rats fed CNO+RBO(B) and by 20.5, 34.1, and 12.9%, respectively, in rats fed CNO+SESO(B) compared to rats given CNO. Rats fed interesterified oils showed a decrease in serum TC, low-density lipoprotein cholesterol (LDL-C), and TAGs in CNO+RBO(I) by 35, 49.1, and 23.2 and by 33.3, 47, and 19.8% in CNO+SESO(I), respectively, compared to rats given CNO. Compared to rats fed CNO+RBO blended oils, rats on CNO+RBO interesterified oil showed a further decrease of 14.6, 24.7, and 10% in TC, LDL-C, and TAG. Rats fed CNO+SESO interesterified oils showed a decrease in serum TC, LDL-C, and TAG by 16.2, 19.6, and 7.8%, respectively, compared to rats given blended oils of CNO+SESO (B). Liver lipid analysis also showed significant change in the TC and TAG concentration in rats fed blended and interesterified oils of CNO+RBO and CNO+SESO compared to the rats given CNO. The present study suggests that feeding fats containing blended oils with balanced fatty acids lowers serum and liver lipids. Interesterified oils prepared using Lipase have a further lowering effect on serum and liver lipids even though the fatty acid composition of blended and interesterified

  9. Climate, niche evolution, and diversification of the "bird-cage" evening primroses (Oenothera, sections Anogra and Kleinia).

    PubMed

    Evans, Margaret E K; Smith, Stephen A; Flynn, Rachel S; Donoghue, Michael J

    2009-02-01

    We integrate climatic niche models and dated phylogenies to characterize the evolution of climatic niches in Oenothera sections Anogra and Kleinia (Onagraceae), and from that we make inferences on diversification in relation to climate. The evolution of climatic tolerances in Anogra + Kleinia has been heterogeneous, across phylogenetic groups and across different dimensions of climate. All the extant taxa occur in semiarid to arid conditions (annual precipitation of 10.1-49.1 cm and high temperatures in the warmest month of 28.5 degrees-40.1 degrees C), but there is striking variation among taxa in their climatic tolerances, especially temperature (minimum temperatures in the coldest month of -14.0 degrees to 5.3 degrees C) and summer versus winter precipitation (precipitation in the warmest quarter of 0.6-19.4 cm). Climatic disparity is especially pronounced in two subclades (californica, deltoides) that radiated in the southwestern United States and California, apparently including both divergent and convergent evolution of climatic tolerances. This niche evolution is remarkable, given the probable timescale of the radiation (approximately 1 million years). We suggest that the spatiotemporal climatic heterogeneity of western North America has served as a driver of diversification. Our data are also consistent with Axelrod's hypothesis that the spread of arid conditions in western North America stimulated diversification of arid-adapted lineages.

  10. Tolerance to deer herbivory and resistance to insect herbivores in the common evening primrose (Oenothera biennis).

    PubMed

    Puentes, A; Johnson, M T J

    2016-01-01

    The evolution of plant defence in response to herbivory will depend on the fitness effects of damage, availability of genetic variation and potential ecological and genetic constraints on defence. Here, we examine the potential for evolution of tolerance to deer herbivory in Oenothera biennis while simultaneously considering resistance to natural insect herbivores. We examined (i) the effects of deer damage on fitness, (ii) the presence of genetic variation in tolerance and resistance, (iii) selection on tolerance, (iv) genetic correlations with resistance that could constrain evolution of tolerance and (v) plant traits that might predict defence. In a field experiment, we simulated deer damage occurring early and late in the season, recorded arthropod abundances, flowering phenology and measured growth rate and lifetime reproduction. Our study showed that deer herbivory has a negative effect on fitness, with effects being more pronounced for late-season damage. Selection acted to increase tolerance to deer damage, yet there was low and nonsignificant genetic variation in this trait. In contrast, there was substantial genetic variation in resistance to insect herbivores. Resistance was genetically uncorrelated with tolerance, whereas positive genetic correlations in resistance to insect herbivores suggest there exists diffuse selection on resistance traits. In addition, growth rate and flowering time did not predict variation in tolerance, but flowering phenology was genetically correlated with resistance. Our results suggest that deer damage has the potential to exert selection because browsing reduces plant fitness, but limited standing genetic variation in tolerance is expected to constrain adaptive evolution in O. biennis. © 2015 European Society For Evolutionary Biology. Journal of Evolutionary Biology © 2015 European Society For Evolutionary Biology.

  11. Oil, oil dispersants and related substances in the marine environment

    NASA Astrophysics Data System (ADS)

    Gunkel, W.; Gassmann, G.

    1980-03-01

    Of all substances threatening life in the seas, oil has received by far the most attention from the public, administrators, politicians and scientists. The main reasons for this are: (1) even limited amounts of oil are easily visible; (2) oil can exert obvious negative effects, e. g. extensive damage to birds and other animals, impairment of the recreational value of beaches and marinas, losses in fisheries due to tainting of catches and rejection by the public of seafood from areas known to have been recently polluted. In addition, dramatic tanker accidents are widely publicized. During the last decade tens of thousands of papers have been published about the impact of oil on the marine environment, and we are well informed about most basic facts, such as input and fate of oil, toxicity to adult organisms and recolonization. Due to considerable sophistication of analytical techniques, especially the introduction of glass-capillary gas chromatography, we are well aware that recently formed biogenic hydrocarbons by far extend the input directly due to pollution. Large gaps exist in our knowledge about sedimentation and transport of weathered oil, natural degradation rates, and the flow of hydrocarbons through the food web. Relatively little is known about the influence of oil and dispersants upon complex ecosystems. The often mentioned suspicion of increased cancer probability in humans due to seafood contaminated by hydrocarbons has not been substantiated; in fact, it seems unlikely that such an effect exists. By far the greatest uncertainty about potential oil impact concerns possible negative effects of hydrocarbons on chemical communication mechanisms between organisms. Intensive studies of behaviour scientists working with concentrations far below the toxic level are needed in fisheries biology, zoology and botany. Most cases of oil contamination known thus far have been limited in space and time; the oil has turned out to be degradable by natural processes

  12. The efficacy of Iranian herbal medicines in alleviating hot flashes: A systematic review

    PubMed Central

    Ghazanfarpour, Masumeh; Sadeghi, Ramin; Abdolahian, Somayeh; Latifnejad Roudsari, Robab

    2016-01-01

    Background: Hot flashes are the most common symptoms experienced by women around the time of menopause. Many women are interested in herbal medicines because of fear of side effects of hormone therapy. Objective: The aim of this systematic review was to assess the effectiveness of Iranian herbal medicines in alleviating hot flashes. Materials and Methods: MEDLINE (1966 to January 2015), Scopus (1996 to January 2015), and Cochrane Central Register of Controlled Trials (The Cochrane Library, issue 1, 2015) were searched along with, SID, Iran Medex, Magiran, Medlib and Irandoc. Nineteen randomized controlled trials met the inclusion criteria. Results: Overall, studies showed that Anise (Pimpinella anisum), licorice (Glycyrrhizaglabra), Soy, Black cohosh, Red clover, Evening primrose, Flaxseed, Salvia officinalis, Passiflora، itex Agnus Castus, Piascledine (Avacado plus soybean oil), St. John's wort (Hypericum perforatum), and valerian can alleviate the side effects of hot flashes. Conclusion: This research demonstrated the efficacy of herbal medicines in alleviating hot flashes, which are embraced both with people and health providers of Iran Therefore, herbal medicine can be seen as an alternative treatment for women experiencing hot flashes. PMID:27294213

  13. Performance evaluation of NEEM oil and HONGE Oil as cutting fluid in drilling operation of mild steel

    NASA Astrophysics Data System (ADS)

    Jyothi, P. N.; Susmitha, M.; Sharan, P.

    2017-04-01

    Cutting fluids are used in machining industries for improving tool life, reducing work piece and thermal deformation, improving surface finish and flushing away chips from the cutting zone. Although the application of cutting fluids increases the tool life and Machining efficiency, but it has many major problems related to environmental impacts and health hazards along with recycling & disposal. These problems gave provision for the introduction of mineral, vegetable and animal oils. These oils play an important role in improving various machining properties, including corrosion protection, lubricity, antibacterial protection, even emulsibility and chemical stability. Compared to mineral oils, vegetable oils in general possess high viscosity index, high flash point, high lubricity and low evaporative losses. Vegetable oils can be edible or non-edible oils and Various researchers have proved that edible vegetable oils viz., palm oil, coconut oil, canola oil, soya bean oil can be effectively used as eco-friendly cutting fluid in machining operations. But in present situations harnessing edible oils for lubricants formation restricts the use due to increased demands of growing population worldwide and availability. In the present work, Non-edible vegetable oil like Neem and Honge are been used as cutting fluid for drilling of Mild steel and its effect on cutting temperature, hardness and surface roughness are been investigated. Results obtained are compared with SAE 20W40 (petroleum based cutting fluid)and dry cutting condition.

  14. Does zinc moderate essential fatty acid and amphetamine treatment of attention-deficit/hyperactivity disorder?

    PubMed

    Arnold, L E; Pinkham, S M; Votolato, N

    2000-01-01

    Zinc is an important co-factor for metabolism relevant to neurotransmitters, fatty acids, prostaglandins, and melatonin, and indirectly affects dopamine metabolism, believed intimately involved in attention-deficit/hyperactivity disorder (ADHD). To explore the relationship of zinc nutrition to essential fatty acid supplement and stimulant effects in treatment of ADHD, we re-analyzed data from an 18-subject double-blind, placebo-controlled crossover treatment comparison of d-amphetamine and Efamol (evening primrose oil, rich in gamma-linolenic acid). Subjects were categorized as zinc-adequate (n = 5), borderline zinc (n = 5), and zinc-deficient (n = 8) by hair, red cell, and urine zinc levels; for each category, placebo-active difference means were calculated on teachers' ratings. Placebo-controlled d-amphetamine response appeared linear with zinc nutrition, but the relationship of Efamol response to zinc appeared U-shaped; Efamol benefit was evident only with borderline zinc. Placebo-controlled effect size (Cohen's d) for both treatments ranged up to 1.5 for borderline zinc and dropped to 0.3-0.7 with mild zinc deficiency. If upheld by prospective research, this post-hoc exploration suggests that zinc nutrition may be important for treatment of ADHD even by pharmacotherapy, and if Efamol benefits ADHD, it likely does so by improving or compensating for borderline zinc nutrition.

  15. Determination of vegetable oils and fats adulterants in diesel oil by high performance liquid chromatography and multivariate methods.

    PubMed

    Brandão, Luiz Filipe Paiva; Braga, Jez Willian Batista; Suarez, Paulo Anselmo Ziani

    2012-02-17

    The current legislation requires the mandatory addition of biodiesel to all Brazilian road diesel oil A (pure diesel) marketed in the country and bans the addition of vegetable oils for this type of diesel. However, cases of irregular addition of vegetable oils directly to the diesel oil may occur, mainly due to the lower cost of these raw materials compared to the final product, biodiesel. In Brazil, the situation is even more critical once the country is one of the largest producers of oleaginous products in the world, especially soybean, and also it has an extensive road network dependent on diesel. Therefore, alternatives to control the quality of diesel have become increasingly necessary. This study proposes an analytical methodology for quality control of diesel with intention to identify and determine adulterations of oils and even fats of vegetable origin. This methodology is based on detection, identification and quantification of triacylglycerols on diesel (main constituents of vegetable oils and fats) by high performance liquid chromatography in reversed phase with UV detection at 205nm associated with multivariate methods. Six different types of oils and fats were studied (soybean, frying oil, corn, cotton, palm oil and babassu) and two methods were developed for data analysis. The first one, based on principal component analysis (PCA), nearest neighbor classification (KNN) and univariate regression, was used for samples adulterated with a single type of oil or fat. In the second method, partial least square regression (PLS) was used for the cases where the adulterants were mixtures of up to three types of oils or fats. In the first method, the techniques of PCA and KNN were correctly classified as 17 out of 18 validation samples on the type of oil or fat present. The concentrations estimated for adulterants showed good agreement with the reference values, with mean errors of prediction (RMSEP) ranging between 0.10 and 0.22% (v/v). The PLS method was

  16. The activity of healthy olive microbiota during virgin olive oil extraction influences oil chemical composition.

    PubMed

    Vichi, Stefania; Romero, Agustí; Tous, Joan; Caixach, Josep

    2011-05-11

    The activity of olive microbiota during the oil extraction process could be a critical point for virgin olive oil quality. With the aim to evaluate the role of microbiological activity during the virgin olive oil extraction process, just before oil extraction freshly collected healthy olive fruits were immersed in contaminated water from an olive mill washing tank. The oils extracted were then compared with control samples from the same batch of hand-picked olives. The presence of lactic and enteric bacteria, fungi and Pseudomonas on the surface of olives was proved to be much higher in washed than in control olives, with increments in cfu/g between 2 and 3 orders of magnitude. The biogenesis of volatile compounds and the extraction of olive polyphenols and pigments were significantly influenced by the microbiological profile of olives even without any previous storage. In most cases the effect of olive microbiota on oil characteristics was greater than the effect exerted by malaxation time and temperature. Oils from microbiologically contaminated olives showed lower amounts of C5 volatiles and higher levels of C6 volatiles from the lipoxygenase pathway and some fermentation products. On the other hand, a decrease of chlorophylls, pheophytins, xanthophylls and the ratio chlorophyll/pheophytin was observed in these oils. Likewise, the microbiological activity during oil extraction led to significantly lower amounts of polyphenols, in particular of oleuropein derivatives. These differences in olive oil chemical composition were reflected in oil sensory characteristics by the decrease of the green and bitter attributes and by the modification of the oil color chromatic ordinates.

  17. A field experiment demonstrating plant life-history evolution and its eco-evolutionary feedback to seed predator populations.

    PubMed

    Agrawal, Anurag A; Johnson, Marc T J; Hastings, Amy P; Maron, John L

    2013-05-01

    The extent to which evolutionary change occurs in a predictable manner under field conditions and how evolutionary changes feed back to influence ecological dynamics are fundamental, yet unresolved, questions. To address these issues, we established eight replicate populations of native common evening primrose (Oenothera biennis). Each population was planted with 18 genotypes in identical frequency. By tracking genotype frequencies with microsatellite DNA markers over the subsequent three years (up to three generations, ≈5,000 genotyped plants), we show rapid and consistent evolution of two heritable plant life-history traits (shorter life span and later flowering time). This rapid evolution was only partially the result of differential seed production; genotypic variation in seed germination also contributed to the observed evolutionary response. Since evening primrose genotypes exhibited heritable variation for resistance to insect herbivores, which was related to flowering time, we predicted that evolutionary changes in genotype frequencies would feed back to influence populations of a seed predator moth that specializes on O. biennis. By the conclusion of the experiment, variation in the genotypic composition among our eight replicate field populations was highly predictive of moth abundance. These results demonstrate how rapid evolution in field populations of a native plant can influence ecological interactions.

  18. A protocol for assessing the effectiveness of oil spill dispersants in stimulating the biodegradation of oil.

    PubMed

    Prince, Roger C; Butler, Josh D

    2014-01-01

    Dispersants are important tools in oil spill response. Taking advantage of the energy in even small waves, they disperse floating oil slicks into tiny droplets (<70 μm) that entrain in the water column and drift apart so that they do not re-agglomerate to re-form a floating slick. The dramatically increased surface area allows microbial access to much more of the oil, and diffusion and dilution lead to oil concentrations where natural background levels of biologically available oxygen, nitrogen, and phosphorus are sufficient for microbial growth and oil consumption. Dispersants are only used on substantial spills in relatively deep water (usually >10 m), conditions that are impossible to replicate in the laboratory. To date, laboratory experiments aimed at following the biodegradation of dispersed oil usually show only minimal stimulation of the rate of biodegradation, but principally because the oil in these experiments disperses fairly effectively without dispersant. What is needed is a test protocol that allows comparison between an untreated slick that remains on the water surface during the entire biodegradation study and dispersant-treated oil that remains in the water column as small dispersed oil droplets. We show here that when this is accomplished, the rate of biodegradation is dramatically stimulated by an effective dispersant, Corexit 9500. Further development of this approach might result in a useful tool for comparing the full benefits of different dispersants.

  19. Quartetting in even-even and odd-odd N=Z nuclei

    NASA Astrophysics Data System (ADS)

    Sambataro, M.; Sandulescu, N.

    2018-02-01

    We report on a microscopic description of even-even N = Z nuclei in a formalism of quartets. Quartets are four-body correlated structures characterized by isospin T and angular momentum J. We show that the ground state correlations induced by a realistic shell model interaction can be well accounted for in terms of a restricted set of T = 0 low-J quartets, the J = 0 one playing by far a leading role among them. A conceptually similar description of odd-odd self-conjugate nuclei is given in terms of two distinct families of building blocks, one formed by the same T = 0 quartets employed for the even-even systems and the other by collective pairs with either T = 0 or T = 1. Some applications of this formalism are discussed for nuclei in the sd shell.

  20. Spilled oil and infaunal activity - Modification of burrowing behavior and redistribution of oil

    USGS Publications Warehouse

    Clifton, H.E.; Kvenvolden, K.A.; Rapp, J.B.

    1984-01-01

    A series of experiments in Willapa Bay, Washington, indicates the degree to which the presence of spilled oil modifies the burrowing behavior of infauna and the extent to which the animals redistribute oil into intertidal sediment. Small amounts of North Slope crude oil introduced at low tide directly into burrow openings (mostly made by the crustacean Callianassa) resulted in a limited and temporary reduction in the number of burrow openings. In contrast, a layer of oil-saturated sand 1 cm thick buried about 5 cm below the sediment surface sharply reduced the number of burrow openings. After a year, the few new burrows penetrated only the margins of the experimental plot, and bioturbation below the buried oil-saturated sand layer declined dramatically. The experiments suggest that small amounts of oil temporarily stranded by tides in themselves have no long-range effect on burrowing behavior. The fauna, however, are capable of introducing measurable amounts of oil into the subsurface, where it is retained long after the rest of the stranded oil had washed away. A buried layer of oil-saturated sand greatly reduces infaunal activity; the oil presents an effective barrier that can persist for years. The oil incorporated into the sediment from burrow openings showed evidence of degradation after 7 months. In contrast the layer of buried oil remained essentially undergraded after a period of two years, even though oil in lower concentrations above the layer was degraded after a period of one year. This variation in degree of degradation of the buried oil, as well as the heterogeneity of oil distribution wherever the oil has been incorporated from the surface, emphasises the importance of careful sampling in any attempt to locate or monitor the presence of spilled oil in the substrate.In a series of experiments in Willapa Bay, Washington, small amounts of North Slope crude oil introduced at low tide directly into burrow openings resulted in a limited and temporary

  1. Wireless Tots

    ERIC Educational Resources Information Center

    Scott, Lee-Allison

    2003-01-01

    The first wireless technology program for preschoolers was implemented in January at the Primrose School at Bentwater in Atlanta, Georgia, a new corporate school operated by Primrose School Franchising Co. The new school serves as a testing and training facility for groundbreaking educational approaches, including emerging innovations in…

  2. Offshore Oil Drilling: Buying Energy Independence or Buying Time?

    ERIC Educational Resources Information Center

    Baird, Stephen L.

    2008-01-01

    This article addresses the issues and concerns about offshore oil drilling in the United States. The demand for energy is going up, not down, and for a long time, even as alternative sources of energy are developed, more oil will be needed. The strongest argument against drilling is that it could distract the country from the pursuit of…

  3. [Diversity of oil-degrading bacteria isolated form the Indian Ocean sea surface].

    PubMed

    Wu, Changliang; Wang, Xin; Shao, Zongze

    2010-09-01

    In order to investigate the diversity of oil-degrading bacteria in the surface seawater across the India Ocean, and to obtain new oil-degrading bacteria. Potential oil-degrading bacteria were selected out via 1:1 mixture of diesel and crude oil as sole carbon source. Meanwhile, the community structure of 13 enrichments was analyzed by polymerase chain reaction with denaturing gradient gel electrophoresis (PCR-DGGE). We obtained 51 unique strains of 29 genera after screening via morphological, physiological, biochemical and 16S rRNA analyses. They mainly belonged to a and gamma-Proteobacteria. The four genera Alcanivorax (accounting for 18%), Novosphingobium (10%), Marinobacter (6%) and Thalassospira (6%) were the most predominant bacteria. Ecological analyses showed that the bacteria had high diversity with Shannon-Winner index (H) of 4.57968, and distributed even with Evenness index (E) as 0.8664771. Then Further experiments revealed oil-degrading capability of 49 strains. In addition, our investigation revealed oil-degrading ability of genera Sinomonas, Knoellia and Mesoflavibacter for the first time. DGGE fingerprint patterns indicated that the genus Alcanivorax was an important oil-degrading bacteria in the surface seawater across the India Ocean. This study demonstrated a high diversity of the oil-degradation bacteria in the surface seawater of Indian Ocean, these bacteria are of potential in bioremediation of marine oil pollution.

  4. Diet, nutraceuticals and the tear film.

    PubMed

    Jalbert, Isabelle

    2013-12-01

    Nutrition disorders and their correlates such as obesity are increasingly prevalent worldwide. A number of studies to date have suggested numerous potential associations between diet and tear film health; this paper will provide a summary of the available literature. The tear film is characterized through its protein and lipid content and through clinical measurements of characteristics such as osmolarity, volume and stability. Malnutrition, protein and vitamin-A deficiencies are extremely deleterious to tear film health and supplementation with oral vitamin A in this setting is of clear benefit. The relative impact of diet on tear film within what would be considered normal ranges of consumption is less clear. A number of population studies have suggested that hyperlipidemia and a diet low in omega-3 fatty acids are risks factor for dry eye disease. Numerous studies have investigated the effectiveness of oral supplementation with antioxidants, omega-3 (e.g. fish oil and linseed oil) and omega-6 (e.g. evening primrose oil) fatty acids in the last 10 years. Taken together, these suggest a small benefit of oral supplementation on tear film volume, stability and decreased ocular symptoms in patients previously diagnosed with diseases involving the ocular surface (e.g. Sjögren's syndrome, meibomian gland dysfunction, dry eye disease) and contact lens wearers suffering from dry eye. More research is required to determine the exact composition, dosage and indications for their use and to fully characterize how these nutraceuticals modulate the tear film. Copyright © 2013 Elsevier Ltd. All rights reserved.

  5. A 90-day subchronic toxicity study of neem oil, a Azadirachta indica oil, in mice.

    PubMed

    Wang, C; Cao, M; Shi, D-X; Yin, Z-Q; Jia, R-Y; Wang, K-Y; Geng, Y; Wang, Y; Yao, X-P; Yang, Z-R; Zhao, J

    2013-09-01

    To determine the no-observed-adverse-effect level (NOAEL) of exposure and target organs of neem oil for establishing safety criteria for human exposure, the subchronic toxicity study with neem oil in mice was evaluated. The mice (10 per sex for each dose) was orally administered with neem oil with the doses of 0 (to serve as a control), 177, 533 and 1600 mg/kg/day for 90 days. After the treatment period, observation of reversibility or persistence of any toxic effects, mice were continuously fed without treatment for the following 30 days. During the two test periods, the serum biochemistry, organ weight and histopathology were examined. The results showed that the serum biochemistry and organ coefficient in experimental groups had no statistical difference compared with those of the control group. At the 90th day, the histopathological examinations showed that the 1600 mg/kg/day dose of neem oil had varying degrees of damage on each organ except heart, uterus and ovarian. After 30-day recovery, the degree of lesions to the tissues was lessened or even restored. The NOAEL of neem oil was 177 mg/kg/day for mice and the target organs of neem oil were determined to be testicle, liver and kidneys.

  6. Newburg-South Westhope oil fields, North Dakota

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Marafi, H.

    1972-01-01

    The Newburg and South Westhope oil fields, located in Bottineau County, North Dak., in the NE. part of the Williston Basin, are excellent examples of stratigraphic traps, although structural elements are involved in trapping of the accumulations. The oil is produced from 2 adjacent zones separated by a major unconformity, and they are considered to be a common reservoir. The productive units are the ''Ratcliffe'' interval of the Mississippian Charles Formation and the Saude Member of the Triassic Spearfish Formation. Post-Paleozoic migration of the oil is indicated because, even though the Ratcliffe was exposed to considerable erosion, it is productivemore » at the unconformity.« less

  7. Local topography shapes fine-scale spatial genetic structure in the Arkansas Valley evening primrose, Oenothera harringtonii (Onagraceae).

    PubMed

    Rhodes, Matthew K; Fant, Jeremie B; Skogen, Krissa A

    2014-01-01

    Identifying factors that shape the spatial distribution of genetic variation is crucial to understanding many population- and landscape-level processes. In this study, we explore fine-scale spatial genetic structure in Oenothera harringtonii (Onagraceae), an insect-pollinated, gravity-dispersed herb endemic to the grasslands of south-central and southeastern Colorado, USA. We genotyped 315 individuals with 11 microsatellite markers and utilized a combination of spatial autocorrelation analyses and landscape genetic models to relate life history traits and landscape features to dispersal processes. Spatial genetic structure was consistent with theoretical expectations of isolation by distance, but this pattern was weak (Sp = 0.00374). Anisotropic analyses indicated that spatial genetic structure was markedly directional, in this case consistent with increased dispersal along prominent slopes. Landscape genetic models subsequently confirmed that spatial genetic variation was significantly influenced by local topographic heterogeneity, specifically that geographic distance, elevation and aspect were important predictors of spatial genetic structure. Among these variables, geographic distance was ~68% more important than elevation in describing spatial genetic variation, and elevation was ~42% more important than aspect after removing the effect of geographic distance. From these results, we infer a mechanism of hydrochorous seed dispersal along major drainages aided by seasonal monsoon rains. Our findings suggest that landscape features may shape microevolutionary processes at much finer spatial scales than typically considered, and stress the importance of considering how particular dispersal vectors are influenced by their environmental context. © The American Genetic Association 2014. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  8. Squeeze film dampers with oil hole feed

    NASA Technical Reports Server (NTRS)

    Chen, P. Y. P.; Hahn, E. J.

    1994-01-01

    To improve the damping capability of squeeze film dampers, oil hole feed rather than circumferential groove feed is a practical proposition. However, circular orbit response can no longer be assumed, significantly complicating the design analysis. This paper details a feasible transient solution procedure for such dampers, with particular emphasis on the additional difficulties due to the introduction of oil holes. It is shown how a cosine power series solution may be utilized to evaluate the oil hole pressure contributions, enabling appropriate tabular data to be compiled. The solution procedure is shown to be applicable even in the presence of flow restrictors, albeit at the expense of introducing an iteration at each time step. Though not of primary interest, the procedure is also applicable to dynamically loaded journal bearings with oil hole feed.

  9. Effects of oil on avian reproduction: A review and discussion

    USGS Publications Warehouse

    Albers, P.H.; Rosie, Don; Barnes, Stephen N.

    1983-01-01

    Oil pollution is a highly visible form of environmental contamination that affects avian reproduction in a variety of ways. Plumage oiling causes widespread and locally severe mortality of adult birds. Egg oiling can be a serious hazard for bird embryos but only a few field observationons of this have been reported. Oil ingestion seldom kills birds directly but it causes sublethal change~ in the bodily functions and behavior of adults and nestlings. Studies of the effects of oil on avian reproduction have produced varied and, in ingestion studies, sometimes conflicting results because of inconsistent experimental design and the use of different test species and types of oil. Field experimentation with the sublethal effects of ingested oil on avian reproduction has been limited. Simulation modelling of seabird populations has shown that (l) an occasional decrease in survival of breeding adults will have a greater impact on seabird populations than an occasional decrease in reproductive success, and (2) populations of long-lived seabirds with low reproductive potential have great difficulty recovering from high one-time mortality when experiencing even small sustained annual decreases in either natality or breeding adult survival. The impact of oil-related decreases in survival or reproduction will be more noticeable at the local or colony level than at the regional or species level. Immigration, surplus breeders, and possible compensatory changes in natality and mortality resulting from population reductions usually prevent local population reductions from lasting very long (unless the species is rare or at the edge of its range). A study of west European seabird populations indicates that the natural annual mortality of the region greatly exceeds the annual mortality due to plumage oiling; effects of oil ingestion and egg oiling were not measured but were thought to be less than the mortality from plu~age oiling. Oil-related mortality, even if in addition to

  10. Heavily Oiled Salt Marsh following the Deepwater Horizon Oil Spill, Ecological Comparisons of Shoreline Cleanup Treatments and Recovery

    PubMed Central

    Zengel, Scott; Bernik, Brittany M.; Rutherford, Nicolle; Nixon, Zachary; Michel, Jacqueline

    2015-01-01

    The Deepwater Horizon oil spill affected hundreds of kilometers of coastal wetland shorelines, including salt marshes with persistent heavy oiling that required intensive shoreline “cleanup” treatment. Oiled marsh treatment involves a delicate balance among: removing oil, speeding the degradation of remaining oil, protecting wildlife, fostering habitat recovery, and not causing further ecological damage with treatment. To examine the effectiveness and ecological effects of treatment during the emergency response, oiling characteristics and ecological parameters were compared over two years among heavily oiled test plots subject to: manual treatment, mechanical treatment, natural recovery (no treatment, oiled control), as well as adjacent reference conditions. An additional experiment compared areas with and without vegetation planting following treatment. Negative effects of persistent heavy oiling on marsh vegetation, intertidal invertebrates, and shoreline erosion were observed. In areas without treatment, oiling conditions and negative effects for most marsh parameters did not considerably improve over two years. Both manual and mechanical treatment were effective at improving oiling conditions and vegetation characteristics, beginning the recovery process, though recovery was not complete by two years. Mechanical treatment had additional negative effects of mixing oil into the marsh soils and further accelerating erosion. Manual treatment appeared to strike the right balance between improving oiling and habitat conditions while not causing additional detrimental effects. However, even with these improvements, marsh periwinkle snails showed minimal signs of recovery through two years, suggesting that some ecosystem components may lag vegetation recovery. Planting following treatment quickened vegetation recovery and reduced shoreline erosion. Faced with comparable marsh oiling in the future, we would recommend manual treatment followed by planting. We

  11. Mangrove Bacterial Diversity and the Impact of Oil Contamination Revealed by Pyrosequencing: Bacterial Proxies for Oil Pollution

    PubMed Central

    dos Santos, Henrique Fragoso; Cury, Juliano Carvalho; do Carmo, Flávia Lima; dos Santos, Adriana Lopes; Tiedje, James; van Elsas, Jan Dirk; Rosado, Alexandre Soares; Peixoto, Raquel Silva

    2011-01-01

    Background Mangroves are transitional coastal ecosystems in tropical and sub-tropical regions and represent biologically important and productive ecosystems. Despite their great ecological and economic importance, mangroves are often situated in areas of high anthropogenic influence, being exposed to pollutants, such as those released by oil spills. Methodology/Principal Findings A microcosm experiment was conducted, which simulated an oil spill in previously pristine mangrove sediment. The effect of the oil spill on the extant microbial community was studied using direct pyrosequencing. Extensive bacterial diversity was observed in the pristine mangrove sediment, even after oil contamination. The number of different OTUs only detected in contaminated samples was significantly higher than the number of OTUs only detected in non-contaminated samples. The phylum Proteobacteria, in particular the classes Gammaproteobacteria and Deltaproteobacteria, were prevalent before and after the simulated oil spill. On the other hand, the order Chromatiales and the genus Haliea decreased upon exposure to 2 and 5% oil, these are proposed as sensitive indicators of oil contamination. Three other genera, Marinobacterium, Marinobacter and Cycloclasticus increased their prevalence when confronted with oil. These groups are possible targets for the biomonitoring of the impact of oil in mangrove settings. Conclusions/Significance We suggest the use of sequences of the selected genera as proxies for oil pollution, using qPCR assessments. The quantification of these genera in distinct mangrove systems in relation to the local oil levels would permit the evaluation of the level of perturbance of mangroves, being useful in field monitoring. Considering the importance of mangroves to many other environments and the susceptibility of such areas to oil spills this manuscript will be of broad interest. PMID:21399677

  12. Biodegradability of commercial and weathered diesel oils

    PubMed Central

    Mariano, Adriano Pinto; Bonotto, Daniel Marcos; de Franceschi de Angelis, Dejanira; Pirôllo, Maria Paula Santos; Contiero, Jonas

    2008-01-01

    This work aimed to evaluate the capability of different microorganisms to degrade commercial diesel oil in comparison to a weathered diesel oil collected from the groundwater at a petrol station. Two microbiological methods were used for the biodegradability assessment: the technique based on the redox indicator 2,6 -dichlorophenol indophenol (DCPIP) and soil respirometric experiments using biometer flasks. In the former we tested the bacterial cultures Staphylococcus hominis, Kocuria palustris, Pseudomonas aeruginosa LBI, Ochrobactrum anthropi and Bacillus cereus, a commercial inoculum, consortia obtained from soil and groundwater contaminated with hydrocarbons and a consortium from an uncontaminated area. In the respirometric experiments it was evaluated the capability of the native microorganisms present in the soil from a petrol station to biodegrade the diesel oils. The redox indicator experiments showed that only the consortia, even that from an uncontaminated area, were able to biodegrade the weathered diesel. In 48 days, the removal of the total petroleum hydrocarbons (TPH) in the respirometric experiments was approximately 2.5 times greater when the commercial diesel oil was used. This difference was caused by the consumption of labile hydrocarbons, present in greater quantities in the commercial diesel oil, as demonstrated by gas chromatographic analyses. Thus, results indicate that biodegradability studies that do not consider the weathering effect of the pollutants may over estimate biodegradation rates and when the bioaugmentation is necessary, the best strategy would be that one based on injection of consortia, because even cultures with recognised capability of biodegrading hydrocarbons may fail when applied isolated. PMID:24031193

  13. Effects of external applications of fuel oil on hatchability of mallard eggs

    USGS Publications Warehouse

    Albers, P.H.; Wolfe, Douglas A.

    1977-01-01

    An experiment was performed to determine the toxicity of oil to incubating eggs. Number 2 fuel oil, a mixture of 9 paraffin compounds, and propylene glycol were applied to the surface of artificially incubated mallard (Anas platyrhynchos) eggs. Embryonic mortality was significantly greater (P 0.01) from the control. Thus, the transfer of even small quantities of oil to the egg surface is sufficient to reduce hatchability.

  14. Nutrigenomics of extra-virgin olive oil: A review.

    PubMed

    Piroddi, Marta; Albini, Adriana; Fabiani, Roberto; Giovannelli, Lisa; Luceri, Cristina; Natella, Fausta; Rosignoli, Patrizia; Rossi, Teresa; Taticchi, Agnese; Servili, Maurizio; Galli, Francesco

    2017-01-02

    Nutrigenomics data on the functional components of olive oil are still sparse, but rapidly increasing. Olive oil is the main source of fat and health-promoting component of the Mediterranean diet. Positive effects have been observed on genes involved in the pathobiology of most prevalent age- and lifestyle-related human conditions, such as cancer, cardiovascular disease and neurodegeneration. Other effects on health-promoting genes have been identified for bioactive components of olives and olive leafs. Omics technologies are offering unique opportunities to identify nutritional and health biomarkers associated with these gene responses, the use of which in personalized and even predictive protocols of investigation, is a main breakthrough in modern medicine and nutrition. Gene regulation properties of the functional components of olive oil, such as oleic acid, biophenols and vitamin E, point to a role for these molecules as natural homeostatic and even hormetic factors with applications as prevention agents in conditions of premature and pathologic aging. Therapeutic applications can be foreseen in conditions of chronic inflammation, and particularly in cancer, which will be discussed in detail in this review paper as major clinical target of nutritional interventions with olive oil and its functional components. © 2016 BioFactors, 43(1):17-41, 2017. © 2016 International Union of Biochemistry and Molecular Biology.

  15. Evidence of chiral bands in even-even nuclei

    NASA Astrophysics Data System (ADS)

    Petrache, C. M.; Lv, B. F.; Astier, A.; Dupont, E.; Wang, Y. K.; Zhang, S. Q.; Zhao, P. W.; Ren, Z. X.; Meng, J.; Greenlees, P. T.; Badran, H.; Cox, D. M.; Grahn, T.; Julin, R.; Juutinen, S.; Konki, J.; Pakarinen, J.; Papadakis, P.; Partanen, J.; Rahkila, P.; Sandzelius, M.; Saren, J.; Scholey, C.; Sorri, J.; Stolze, S.; Uusitalo, J.; Cederwall, B.; Aktas, Ö.; Ertoprak, A.; Liu, H.; Matta, S.; Subramaniam, P.; Guo, S.; Liu, M. L.; Zhou, X. H.; Wang, K. L.; Kuti, I.; Timár, J.; Tucholski, A.; Srebrny, J.; Andreoiu, C.

    2018-04-01

    Evidence for chiral doublet bands has been observed for the first time in the even-even nucleus 136Nd. One chiral band was firmly established. Four other candidates for chiral bands were also identified, which can contribute to the realization of the multiple pairs of chiral doublet bands (M χ D ) phenomenon. The observed bands are investigated by the constrained and tilted axis cranking covariant density functional theory (TAC-CDFT). Possible configurations have been explored. The experimental energy spectra, angular momenta, and B (M 1 )/B (E 2 ) values for the assigned configurations are globally reproduced by TAC-CDFT. Calculated results support the chiral interpretation of the observed bands, which correspond to shapes with maximum triaxiality induced by different multiquasiparticle configurations in 136Nd.

  16. A numerical/empirical technique for history matching and predicting cyclic steam performance in Canadian oil sands reservoirs

    NASA Astrophysics Data System (ADS)

    Leshchyshyn, Theodore Henry

    The oil sands of Alberta contain some one trillion barrels of bitumen-in-place, most contained in the McMurray, Wabiskaw, Clearwater, and Grand Rapids formations. Depth of burial is 0--550 m, 10% of which is surface mineable, the rest recoverable by in-situ technology-driven enhanced oil recovery schemes. To date, significant commercial recovery has been attributed to Cyclic Steam Stimulation (CSS) using vertical wellbores. Other techniques, such as Steam Assisted Gravity Drainage (SAGD) are proving superior to other recovery methods for increasing early oil production but at initial higher development and/or operating costs. Successful optimization of bitumen production rates from the entire reservoir is ultimately decided by the operator's understanding of the reservoir in its original state and/or the positive and negative changes which occur in oil sands and heavy oil deposits upon heat stimulation. Reservoir description is the single most important factor in attaining satisfactory history matches and forecasts for optimized production of the commercially-operated processes. Reservoir characterization which lacks understanding can destroy a project. For example, incorrect assumptions in the geological model for the Wolf Lake Project in northeast Alberta resulted in only about one-half of the predicted recovery by the original field process. It will be shown here why the presence of thin calcite streaks within oil sands can determine the success or failure of a commercial cyclic steam project. A vast amount of field data, mostly from the Primrose Heavy Oil Project (PHOP) near Cold Lake, Alberta, enabled the development a simple set of correlation curves for predicting bitumen production using CSS. A previously calibtrated thermal numerical simulation model was used in its simplist form, that is, a single layer, radial grid blocks, "fingering" or " dilation" adjusted permeability curves, and no simulated fracture, to generate the first cycle production

  17. Impacts, recovery rates, and treatment options for spilled oil in marshes.

    PubMed

    Michel, Jacqueline; Rutherford, Nicolle

    2014-05-15

    In a review of the literature on impacts of spilled oil on marshes, 32 oil spills and field experiments were identified with sufficient data to generate recovery curves and identify influencing factors controlling the rate of recovery. For many spills, recovery occurred within 1-2 growing seasons, even in the absence of any treatment. Recovery was longest for spills with the following conditions: Cold climate; sheltered settings; thick oil on the marsh surface; light refined products with heavy loading; oils that formed persistent thick residues; and intensive treatment. Recovery was shortest for spills with the following conditions: Warm climate; light to heavy oiling of the vegetation only; medium crude oils; and less-intensive treatment. Recommendations are made for treatment based on the following oiling conditions: Free-floating oil on the water in the marsh; thicker oil (>0.5 cm) on marsh surface; thinner oil (<0.5 cm) on marsh surface; heavy oil loading on vegetation; and light to moderate oil loading on vegetation. Copyright © 2014 Elsevier Ltd. All rights reserved.

  18. Use of Alternative Medications for Menopause-Related Symptoms in Three Major Ethnic Groups of Ipoh, Perak, Malaysia.

    PubMed

    Ohn Mar, Saw; Malhi, Fatehpal; Syed Rahim, Syed Hamid; Chua, Chin Tong; Sidhu, Sarjeet Singh; Sandheep, Sugathan

    2015-11-01

    This cross-sectional study investigated the use of alternative medications to alleviate menopause-related symptoms among Malay, Chinese, and Indian women of Ipoh city. The prevalence, types, effectiveness, and associated factors were determined. The prevalence of alternative medication use was 41.4%. Evening primrose oil (EPO) was the most popular medication used (18.1%), followed by soy-based products (12.3%), green tea (6.8%), and gingko (5.8%). The medication was reported to be highly effective by 58.3% of soya bean diet users and 41.1% of EPO users. Significant variables associated with the use were Chinese or Indian ethnicity (P < .001), age between 50 and 54 years (P < .01), lower self-health rating (P < .05), education level of diploma or professional degree (P < .05), employment as professionals or entrepreneurs (P < .05), and the use of hormone replacement therapy (P < .05). Regression analysis showed that Chinese and Indians had significantly higher odds for the use than Malays (Chinese: odds ratio [OR] = 4.33, 95% confidence interval [CI] = 2.392-7.837; Indians: OR = 3.248, 95% CI = 1.586-6.654). © 2015 APJPH.

  19. Natural health product use in Canada.

    PubMed

    Troppmann, Leticia; Johns, Timothy; Gray-Donald, Katherine

    2002-01-01

    To quantify patterns of Natural Health Product (NHP) use in Canada. The Food Habits of Canadians surveyed 1,543 Canadian adults using a 24-hour recall to record dietary supplements. Prevalence of use by user profile was examined. Forty-six percent of women and 33% of men reported taking at least one Natural Health Product with a mean of 2.3 among users. The highest prevalence of supplement use, 57%, occurred among women aged 50-65. Supplement users were older, less likely to smoke and perceived their health as better than non-users. Among supplement users, men had higher rates of use of garlic and vitamin C while women used iron, calcium, B complex, evening primrose oil and glucosamine sulfate. Supplement use by Canadians, at 38% for nutrients and 15% for herbal products, was similar to the rate of uses in the U.S., although differences in the reporting of types of supplements underline aspects of consumer behaviour as well as methodological issues specific to NHPs. Investigation of the use of NHPs in the healthcare setting is important given the widespread use and the potential health care consequences associated with supplement use.

  20. Effect of oil on an electrowetting lenticular lens and related optical characteristics.

    PubMed

    Shin, Dooseub; Kim, Junoh; Kim, Cheoljoong; Koo, Gyo Hyun; Sim, Jee Hoon; Lee, Junsik; Won, Yong Hyub

    2017-03-01

    While there are many ways to realize autostereoscopic 2D/3D switchable displays, the electrowetting lenticular lens is superior due to the high optical efficiency and short response time. In this paper, we propose a more stable electrowetting lenticular lens by controlling the quantity of oil. With a large amount of oil, the oil layer was broken and the lenticular lens was damaged at relatively low voltage. Therefore, controlling the amount of oil is crucial to obtain the required dioptric power with stability. We proposed a new structure to evenly adjust the volume of oil and the dioptric power was measured by varying the volume of oil. Furthermore, the optical characteristics were finally analyzed in the electrowetting lenticular lens array with a proper amount of oil.

  1. Electrically insulating thermal nano-oils using 2D fillers.

    PubMed

    Taha-Tijerina, Jaime; Narayanan, Tharangattu N; Gao, Guanhui; Rohde, Matthew; Tsentalovich, Dmitri A; Pasquali, Matteo; Ajayan, Pulickel M

    2012-02-28

    Different nanoscale fillers have been used to create composite fluids for applications such as thermal management. The ever increasing thermal loads in applications now require advanced operational fluids, for example, high thermal conductivity dielectric oils in transformers. These oils require excellent filler dispersion, high thermal conduction, but also electrical insulation. Such thermal oils that conform to this thermal/electrical requirement, and yet remain in highly suspended stable state, have not yet been synthesized. We report here the synthesis and characterization of stable high thermal conductivity Newtonian nanofluids using exfoliated layers of hexagonal boron nitride in oil without compromising its electrically insulating property. Two-dimensional nanosheets of hexagonal boron nitride are liquid exfoliated in isopropyl alcohol and redispersed in mineral oil, used as standard transformer oil, forming stable nanosuspensions with high shelf life. A high electrical resistivity, even higher than that of the base oil, is maintained for the nano-oil containing small weight fraction of the filler (0.01 wt %), whereas the thermal conductivity was enhanced. The low dissipation factor and high pour point for this nano-oil suggests several applications in thermal management.

  2. A randomized study of coconut oil versus sunflower oil on cardiovascular risk factors in patients with stable coronary heart disease.

    PubMed

    Vijayakumar, Maniyal; Vasudevan, D M; Sundaram, K R; Krishnan, Sajitha; Vaidyanathan, Kannan; Nandakumar, Sandya; Chandrasekhar, Rajiv; Mathew, Navin

    2016-01-01

    Coronary artery disease (CAD) and its pathological atherosclerotic process are closely related to lipids. Lipids levels are in turn influenced by dietary oils and fats. Saturated fatty acids increase the risk for atherosclerosis by increasing the cholesterol level. This study was conducted to investigate the impact of cooking oil media (coconut oil and sunflower oil) on lipid profile, antioxidant mechanism, and endothelial function in patients with established CAD. In a single center randomized study in India, patients with stable CAD on standard medical care were assigned to receive coconut oil (Group I) or sunflower oil (Group II) as cooking media for 2 years. Anthropometric measurements, serum, lipids, Lipoprotein a, apo B/A-1 ratio, antioxidants, flow-mediated vasodilation, and cardiovascular events were assessed at 3 months, 6 months, 1 year, and 2 years. Hundred patients in each arm completed 2 years with 98% follow-up. There was no statistically significant difference in the anthropometric, biochemical, vascular function, and in cardiovascular events after 2 years. Coconut oil even though rich in saturated fatty acids in comparison to sunflower oil when used as cooking oil media over a period of 2 years did not change the lipid-related cardiovascular risk factors and events in those receiving standard medical care. Copyright © 2015 Cardiological Society of India. Published by Elsevier B.V. All rights reserved.

  3. Study of weathering effects on the distribution of aromatic steroid hydrocarbons in crude oils and oil residues.

    PubMed

    Wang, Chuanyuan; Chen, Bing; Zhang, Baiyu; Guo, Ping; Zhao, Mingming

    2014-01-01

    The composition and distribution of triaromatic steroid hydrocarbons in oil residues after biodegradation and photo-oxidation processes were detected, and the diagnostic ratios for oil spill identification were developed and evaluated based on the relative standard deviation (RSD) and the repeatability limit. The preferential loss of C27 methyl triaromatic steranes (MTAS) relative to C28 MTAS and C29 MTAS was shown during the photo-oxidation process. In contrast to the photochemical degradation, the MTAS with the original 20R biological configuration was preferentially degraded during the biodegradation process. The RSD of most of the diagnostic ratios of MTAS ranged from 9 to 84% during the photo-oxidation process. However, the RSDs of such ratios derived from MTAS were all <5% even in high biodegradation, and such parameters may also provide new methods on oil spill identification. The parameters of monoaromatic sterane and monoaromatic sterane are not used well for oil spill identification after photo-oxidation. The triaromatic steroid hydrocarbons retained their molecular compositions after biodegradation and photo-oxidation and most of the diagnostic ratios derived from them could be efficiently used in oil spill identification.

  4. Tables of E2 transition probabilities from the first 2 + states in even-even nuclei [B(E2) evaluation for 0 + 1 → 2 + 1 transitions in even-even nuclei

    DOE PAGES

    Pritychenko, B.; Birch, M.; Singh, B.; ...

    2015-11-03

    A complete B(E2)↑ evaluation and compilation for even-even nuclei has been presented. The present paper is a continuation of P.H. Stelson and L. Grodzins, and S. Raman et al. nuclear data evaluations and was motivated by a large number of new measurements. It extends the list of evaluated nuclides from 328 to 452, includes an extended list of nuclear reaction kinematics parameters and comprehensive shell model analysis. Evaluation policies for analysis of experimental data have been discussed and conclusions are given. Moreover, future plans for B(E2)↑ systematics and experimental technique analyses of even-even nuclei are outlined.

  5. Hubbert's Peak: the Impending World oil Shortage

    NASA Astrophysics Data System (ADS)

    Deffeyes, K. S.

    2004-12-01

    Global oil production will probably reach a peak sometime during this decade. After the peak, the world's production of crude oil will fall, never to rise again. The world will not run out of energy, but developing alternative energy sources on a large scale will take at least 10 years. The slowdown in oil production may already be beginning; the current price fluctuations for crude oil and natural gas may be the preamble to a major crisis. In 1956, the geologist M. King Hubbert predicted that U.S. oil production would peak in the early 1970s.1 Almost everyone, inside and outside the oil industry, rejected Hubbert's analysis. The controversy raged until 1970, when the U.S. production of crude oil started to fall. Hubbert was right. Around 1995, several analysts began applying Hubbert's method to world oil production, and most of them estimate that the peak year for world oil will be between 2004 and 2008. These analyses were reported in some of the most widely circulated sources: Nature, Science, and Scientific American.2 None of our political leaders seem to be paying attention. If the predictions are correct, there will be enormous effects on the world economy. Even the poorest nations need fuel to run irrigation pumps. The industrialized nations will be bidding against one another for the dwindling oil supply. The good news is that we will put less carbon dioxide into the atmosphere. The bad news is that my pickup truck has a 25-gallon tank.

  6. Spin-dependent γ softness or triaxiality in even-even 132-138Nd nuclei

    NASA Astrophysics Data System (ADS)

    Chai, Qing-Zhen; Wang, Hua-Lei; Yang, Qiong; Liu, Min-Liang

    2015-02-01

    The properties of γ instability in rapidly rotating even-even 132-138Nd isotopes have been investigated using the pairing-deformation self-consistent total-Routhian-surface calculations in a deformation space of (β2, γ, β4). It is found that even-even 134-138Nd nuclei exhibit triaxiality in both ground and excited states, even up to high-spin states. The lightest isotope possesses a well-deformed prolate shape without a γ deformation component. The current numerical results are compared with previous calculations and available observables such as quadrupole deformation β2 and the feature of γ-band levels, showing basically a general agreement with the observed trend of γ correlations (e.g. the pattern of the odd-even energy staggering of the γ band). The existing differences between theory and experiment are analyzed and discussed briefly. Supported by National Natural Science Foundation of China (10805040,11175217), Foundation and Advanced Technology Research Program of Henan Province(132300410125) and S & T Research Key Program of Henan Province Education Department (13A140667)

  7. Oral omega-6 essential fatty acid treatment in contact lens associated dry eye.

    PubMed

    Kokke, Karolien H; Morris, Judith A; Lawrenson, John G

    2008-06-01

    Symptoms of dry eye are commonly reported in contact lens wearers and are a frequent cause of non-tolerance. The purpose of the present study is to evaluate the effects of oral treatment with particular omega-6 fatty acids in the form of evening primrose oil (EPO) on subjective symptoms, ocular surface signs and tear film characteristic in patients with contact lens associated dry eye. The study design was randomised, double-masked and placebo controlled. 76 female soft contact lens wearers were treated for 6 months with either EPO or placebo (olive oil). Subjects underwent three examinations (baseline, 3 and 6 months). At each examination subjects were given a questionnaire relating to lens comfort and dry eye symptoms and underwent a series of tests of tear film characteristics (tear meniscus height, break-up time), meibomian gland function (lipid layer thickness and quality) and ocular surface parameters (hyperaemia and staining). The EPO group showed a significant improvement in the specific symptom of 'dryness' at 3 and 6 months (p<0.01) and also a significant improvement in overall lens comfort at 6 months (p<0.01). Tear meniscus height was increased in the EPO group at 6 months relative to baseline (p<0.01), although all other objective signs were unchanged. This study provides evidence for a beneficial effect of particular orally administered omega-6 fatty acids in alleviating dry eye symptoms and improving overall lens comfort in patients suffering from contact lens associated dry eye.

  8. Study of Even-Even/Odd-Even/Odd-Odd Nuclei in Zn-Ga-Ge Region in the Proton-Neutron IBM/IBFM/IBFFM

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Yoshida, N.; Brant, S.; Zuffi, L.

    We study the even-even, odd-even and odd-odd nuclei in the region including Zn-Ga-Ge in the proton-neutron IBM and the models derived from it: IBM2, IBFM2, IBFFM2. We describe {sup 67}Ga, {sup 65}Zn, and {sup 68}Ga by coupling odd particles to a boson core {sup 66}Zn. We also calculate the beta{sup +}-decay rates among {sup 68}Ge, {sup 68}Ga and {sup 68}Zn.

  9. A superhydrophobic copper mesh as an advanced platform for oil-water separation

    NASA Astrophysics Data System (ADS)

    Ren, Guina; Song, Yuanming; Li, Xiangming; Zhou, Yanli; Zhang, Zhaozhu; Zhu, Xiaotao

    2018-01-01

    Improving the separation efficiency and simplifying the separation process would be highly desired for oil-water separation yet still challenging. Herein, to address this challenge, we fabricated a superhydrophobic copper mesh by an immersion process and exploited it as an advanced platform for oil-water separation. To realize oil-water separation efficiently, the obtained mesh was enfolded directly to form a boat-like device, and it could also be mounted on an open end of a glass barrel to form the oil skimmer device. For these devices, they can collect the floating oils through the pores of the copper mesh while repelling water completely, and the oil collection efficiency is up to 99.5%. Oils collected in the devices can be easily sucked out into a container for storing, without requiring mechanical handing for recycling. Importantly, the miniature boat and the oil skimmer devices can retain their enhanced oil collection efficiency even after 10 cycles of oil-water separation. Moreover, exploiting its superhydrophobicity under oil, the obtained copper mesh was demonstrated as a novel platform to remove tiny water droplets from oil.

  10. [Research on Oil Sands Spectral Characteristics and Oil Content by Remote Sensing Estimation].

    PubMed

    You, Jin-feng; Xing, Li-xin; Pan, Jun; Shan, Xuan-long; Liang, Li-heng; Fan, Rui-xue

    2015-04-01

    Visible and near infrared spectroscopy is a proven technology to be widely used in identification and exploration of hydrocarbon energy sources with high spectral resolution for detail diagnostic absorption characteristics of hydrocarbon groups. The most prominent regions for hydrocarbon absorption bands are 1,740-1,780, 2,300-2,340 and 2,340-2,360 nm by the reflectance of oil sands samples. These spectral ranges are dominated by various C-H overlapping overtones and combination bands. Meanwhile, there is relatively weak even or no absorption characteristics in the region from 1,700 to 1,730 nm in the spectra of oil sands samples with low bitumen content. With the increase in oil content, in the spectral range of 1,700-1,730 nm the obvious hydrocarbon absorption begins to appear. The bitumen content is the critical parameter for oil sands reserves estimation. The absorption depth was used to depict the response intensity of the absorption bands controlled by first-order overtones and combinations of the various C-H stretching and bending fundamentals. According to the Pearson and partial correlation relationships of oil content and absorption depth dominated by hydrocarbon groups in 1,740-1,780, 2,300-2,340 and 2,340-2,360 nm wavelength range, the scheme of association mode was established between the intensity of spectral response and bitumen content, and then unary linear regression(ULR) and partial least squares regression (PLSR) methods were employed to model the equation between absorption depth attributed to various C-H bond and bitumen content. There were two calibration equations in which ULR method was employed to model the relationship between absorption depth near 2,350 nm region and bitumen content and PLSR method was developed to model the relationship between absorption depth of 1,758, 2,310, 2,350 nm regions and oil content. It turned out that the calibration models had good predictive ability and high robustness and they could provide the scientific

  11. Oil spill modeling in the southeastern Mediterranean Sea in support of accelerated offshore oil and gas exploration

    NASA Astrophysics Data System (ADS)

    Brenner, Steve

    2015-12-01

    Since the discovery of major reserves in the Israeli exclusive economic zone (EEZ) 6 years ago, exploration and drilling for natural gas and oil have proceeded at an accelerated pace. As part of the licensing procedure for drilling, an environmental impact assessment and an emergency response plan must be presented to the authorities, which include several prespecified oil spill simulations. In this study, the MEDSLIK oil spill model has been applied for this purpose. The model accounts for time-dependent advection, dispersion, and physiochemical weathering of the surface slick. It is driven by currents produced by high-resolution dynamic downscaling of ocean reanalysis data and winds extracted from global atmospheric analyses. Worst case scenarios based on 30-day well blowouts under four sets of environmental conditions were simulated for wells located at 140, 70, and 20 km off the coast of central Israel. For the well furthest from the coast, the amount of oil remaining in the surface slick always exceeds the amount deposited on the coast. For the mid-distance well, the cases were evenly split. For the well closest to the coast, coastal deposition always exceeds the oil remaining in the slick. Additional simulations with the wind switched off helped highlight the importance of the wind in evaporation of the oil and in transporting the slick toward the southeastern coast.

  12. Offshore oil production not significant polluter, says government report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Danenberger, E.P.

    1977-11-01

    Only 0.0028% of the oil produced in the Gulf of Mexico from 1971 through 1975 was spilled. World-wide, natural seeps introduce nearly 7 times more oil into the sea than offshore activity, while transportation, the worst offender, puts in 25 times more than offshore oil. The report includes data for spills of 50 bbl or less; about 85.5% of the total spill volume was from 5 of the 5857 incidents. In only one case was environmental damage reported, when minor amounts of oil reached 1000 ft of beach on the Chandeleur Islands after the 9/9/74 Cobia pipeline break. The reportmore » states that 50 ppm discharges cause no adverse effect, and that hydrocarbons in this concentration may even benefit microbial sea life.« less

  13. Heritability, covariation and natural selection on 24 traits of common evening primrose (Oenothera biennis) from a field experiment.

    PubMed

    Johnson, M T J; Agrawal, A A; Maron, J L; Salminen, J-P

    2009-06-01

    This study explored genetic variation and co-variation in multiple functional plant traits. Our goal was to characterize selection, heritabilities and genetic correlations among different types of traits to gain insight into the evolutionary ecology of plant populations and their interactions with insect herbivores. In a field experiment, we detected significant heritable variation for each of 24 traits of Oenothera biennis and extensive genetic covariance among traits. Traits with diverse functions formed several distinct groups that exhibited positive genetic covariation with each other. Genetic variation in life-history traits and secondary chemistry together explained a large proportion of variation in herbivory (r(2) = 0.73). At the same time, selection acted on lifetime biomass, life-history traits and two secondary compounds of O. biennis, explaining over 95% of the variation in relative fitness among genotypes. The combination of genetic covariances and directional selection acting on multiple traits suggests that adaptive evolution of particular traits is constrained, and that correlated evolution of groups of traits will occur, which is expected to drive the evolution of increased herbivore susceptibility. As a whole, our study indicates that an examination of genetic variation and covariation among many different types of traits can provide greater insight into the evolutionary ecology of plant populations and plant-herbivore interactions.

  14. Profitability Analysis of Soybean Oil Processes.

    PubMed

    Cheng, Ming-Hsun; Rosentrater, Kurt A

    2017-10-07

    Soybean oil production is the basic process for soybean applications. Cash flow analysis is used to estimate the profitability of a manufacturing venture. Besides capital investments, operating costs, and revenues, the interest rate is the factor to estimate the net present value (NPV), break-even points, and payback time; which are benchmarks for profitability evaluation. The positive NPV and reasonable payback time represent a profitable process, and provide an acceptable projection for real operating. Additionally, the capacity of the process is another critical factor. The extruding-expelling process and hexane extraction are the two typical approaches used in industry. When the capacities of annual oil production are larger than 12 and 173 million kg respectively, these two processes are profitable. The solvent free approach, known as enzyme assisted aqueous extraction process (EAEP), is profitable when the capacity is larger than 17 million kg of annual oil production.

  15. Profitability Analysis of Soybean Oil Processes

    PubMed Central

    2017-01-01

    Soybean oil production is the basic process for soybean applications. Cash flow analysis is used to estimate the profitability of a manufacturing venture. Besides capital investments, operating costs, and revenues, the interest rate is the factor to estimate the net present value (NPV), break-even points, and payback time; which are benchmarks for profitability evaluation. The positive NPV and reasonable payback time represent a profitable process, and provide an acceptable projection for real operating. Additionally, the capacity of the process is another critical factor. The extruding-expelling process and hexane extraction are the two typical approaches used in industry. When the capacities of annual oil production are larger than 12 and 173 million kg respectively, these two processes are profitable. The solvent free approach, known as enzyme assisted aqueous extraction process (EAEP), is profitable when the capacity is larger than 17 million kg of annual oil production. PMID:28991168

  16. Special Analysis of Migrant Education Even Start Data. Even Start Information System.

    ERIC Educational Resources Information Center

    Tao, Fumiyo; Arriola, Christine

    This report analyzes data submitted by 11 of 14 state Migrant Education Even Start (MEES) projects operating in 1994-95. These projects provide migrant families with an integrated program of early childhood education, adult education, and parenting education. The data were drawn from the Even Start Information System (ESIS), which collected…

  17. PRP: The Proven Solution for Cleaning Up Oil Spills

    NASA Technical Reports Server (NTRS)

    2006-01-01

    The basic technology behind PRP is thousands of microcapsules, tiny balls of beeswax with hollow centers. Water cannot penetrate the microcapsule s cell, but oil is absorbed right into the beeswax spheres as they float on the water s surface. This way, the contaminants, chemical compounds that originally come from crude oil such as fuels, motor oils, or petroleum hydrocarbons, are caught before they settle. PRP works well as a loose powder for cleaning up contaminants in lakes and other ecologically fragile areas. The powder can be spread over a contaminated body of water or soil, and it will absorb contaminants, contain them in isolation, and dispose of them safely. In water, it is important that PRP floats and keeps the oil on the surface, because, even if oil exposure is not immediately lethal, it can cause long-term harm if allowed to settle. Bottom-dwelling fish exposed to compounds released after oil spills may develop liver disease, in addition to reproductive and growth problems. This use of PRP is especially effective for environmental cleanup in sensitive areas like coral reefs and mangroves.

  18. Characterization of the volatile composition of essential oils of some lamiaceae spices and the antimicrobial and antioxidant activities of the entire oils.

    PubMed

    Bozin, Biljana; Mimica-Dukic, Neda; Simin, Natasa; Anackov, Goran

    2006-03-08

    The essential oils of Ocimum basilicum L., Origanum vulgare L., and Thymus vulgaris L. were analyzed by means of gas chromatography-mass spectrometry and assayed for their antioxidant and antimicrobial activities. The antioxidant activity was evaluated as a free radical scavenging capacity (RSC), together with effects on lipid peroxidation (LP). RSC was assessed measuring the scavenging activity of the essential oils on 2,2-diphenyl-1-picrylhydrazil (DPPH(*)) and OH(*) radicals. Effects on LP were evaluated following the activities of essential oils in Fe(2+)/ascorbate and Fe(2+)/H(2)O(2) systems of induction. Essential oils exhibited very strong RSCs, reducing the DPPH radical formation (IC(50)) in the range from 0.17 (oregano) to 0.39 microg/mL (basil). The essential oil of T. vulgaris exhibited the highest OH radical scavenging activity, although none of the examined essential oils reached 50% of neutralization (IC(50)). All of the tested essential oils strongly inhibited LP, induced either by Fe(2+)/ascorbate or by Fe(2+)/H(2)O(2). The antimicrobial activity was tested against 13 bacterial strains and six fungi. The most effective antibacterial activity was expressed by the essential oil of oregano, even on multiresistant strains of Pseudomonas aeruginosa and Escherichia coli. A significant rate of antifungal activity of all of the examined essential oils was also exhibited.

  19. Aqueous extractive upgrading of bio-oils created by tail-gas reactive pyrolysis to produce pure hydrocarbons and phenols

    USDA-ARS?s Scientific Manuscript database

    Tail-gas reactive pyrolysis (TGRP) of biomass produces bio-oil that is lower in oxygen (~15 wt% total) and significantly more hydrocarbon-rich than traditional bio-oils or even catalytic fast pyrolysis. TGRP bio-oils lend themselves toward mild and inexpensive upgrading procedures. We isolated oxyge...

  20. Rotordynamic Design Analysis of an Oil-Free Turbocharger

    NASA Technical Reports Server (NTRS)

    Howard, Samuel A.

    1997-01-01

    Modern heavy duty diesel engines utilize turbochargers for increased power output. Also, a wide range of power levels can be achieved with one engine displacement through the use of different turbocharger configurations, eliminating the need for several different sized engines. These are the reasons that virtually all diesel truck engines currently marketed use turbochargers. However, because these turbochargers rely on ring seals and oil-lubricated floating sleeve bearings, they often suffer breakdowns. These turbochargers operate at elevated temperatures which often causes the oil to degrade and even coke to the bearing surfaces. This can lead to catastrophic failure, increased particulate emissions from oil leaks, and, in extreme cases, engine fires. Replacing the oil lubricated bearings from these turbochargers with some other device is desirable to eliminate these inherent problems. Foil bearings are compliant selecting bearings lubricated by air and are well suited to high speed, light load applications. Thus, foil bearings present one potential replacement for oil-lubricated sleeve bearings. Their use as such is investigated in this work.

  1. Optical transmission measurements for in-line monitoring of turbid oil-water emulsions

    NASA Astrophysics Data System (ADS)

    Metz, Philipp; Dopf, Katja; Aichholz, Markus; Riedel, Boris; Lemmer, Uli; Freudig, Barbara; Zimmermann, Clifton; Gerken, Martina

    2014-05-01

    For absorbing media the concentration may be calculated directly from the optical transmission following the logarithmic dependence given in the Lambert-Beer law. Due to multiple scattering events in oil-water emulsions (e.g. milk, cream, etc.), these exhibit a nonlinear relationship between the attenuation and the oil concentration. We demonstrate that for increasing oil content in oil-water emulsions the attenuation first increases, then levels out, and finally even decreases for a fat content of 60%. Single-wavelength optical transmission measurements are found to be well suited for the in-line monitoring of oil-water emulsions of fat contents below 20%, e.g., for the in-line fat content monitoring of milk. Using experiments and ray-tracing simulations we evaluate system optimization.

  2. Oil-Impregnated Polyethylene Films

    NASA Astrophysics Data System (ADS)

    Mukherjee, Ranit; Habibi, Mohammad; Rashed, Ziad; Berbert, Otacilio; Shi, Shawn; Boreyko, Jonathan

    2017-11-01

    Slippery liquid-infused porous surfaces (SLIPS) minimize the contact angle hysteresis of a wide range of liquids and aqueous food products. Although hydrophobic polymers are often used as the porous substrate for SLIPS, the choice of polymer has been limited to silicone-based or fluorine-based materials. Hydrocarbon-based polymers, such as polyethylene, are cost effective and widely used in food packaging applications where SLIPS would be highly desirable. However, to date there have been no reports on using polyethylene as a SLIPS substrate, as it is considered highly impermeable. Here, we show that thin films of low-density polyethylene can be stably impregnated with carbon-based oils without requiring any surface modification. Wicking tests reveal that oils with sufficient chemical compatibility follow Washburn's equation. The nanometric effective pore size of the polyethylene does result in a very low wicking speed, but by using micro-thin films and a drawdown coater, impregnation can still be completed in under one second. The oil-impregnated polyethylene films promoted ultra-slippery behavior for water, ketchup, and yogurt while remaining durable even after being submerged in ketchup for over one month. This work was supported by Bemis North America (AT-23981).

  3. Lifetime measurement of neutron-rich even-even molybdenum isotopes

    NASA Astrophysics Data System (ADS)

    Ralet, D.; Pietri, S.; Rodríguez, T.; Alaqeel, M.; Alexander, T.; Alkhomashi, N.; Ameil, F.; Arici, T.; Ataç, A.; Avigo, R.; Bäck, T.; Bazzacco, D.; Birkenbach, B.; Boutachkov, P.; Bruyneel, B.; Bruce, A. M.; Camera, F.; Cederwall, B.; Ceruti, S.; Clément, E.; Cortés, M. L.; Curien, D.; De Angelis, G.; Désesquelles, P.; Dewald, M.; Didierjean, F.; Domingo-Pardo, C.; Doncel, M.; Duchêne, G.; Eberth, J.; Gadea, A.; Gerl, J.; Ghazi Moradi, F.; Geissel, H.; Goigoux, T.; Goel, N.; Golubev, P.; González, V.; Górska, M.; Gottardo, A.; Gregor, E.; Guastalla, G.; Givechev, A.; Habermann, T.; Hackstein, M.; Harkness-Brennan, L.; Henning, G.; Hess, H.; Hüyük, T.; Jolie, J.; Judson, D. S.; Jungclaus, A.; Knoebel, R.; Kojouharov, I.; Korichi, A.; Korten, W.; Kurz, N.; Labiche, M.; Lalović, N.; Louchart-Henning, C.; Mengoni, D.; Merchán, E.; Million, B.; Morales, A. I.; Napoli, D.; Naqvi, F.; Nyberg, J.; Pietralla, N.; Podolyák, Zs.; Pullia, A.; Prochazka, A.; Quintana, B.; Rainovski, G.; Reese, M.; Recchia, F.; Reiter, P.; Rudolph, D.; Salsac, M. D.; Sanchis, E.; Sarmiento, L. G.; Schaffner, H.; Scheidenberger, C.; Sengele, L.; Singh, B. S. Nara; Singh, P. P.; Stahl, C.; Stezowski, O.; Thoele, P.; Valiente Dobon, J. J.; Weick, H.; Wendt, A.; Wieland, O.; Winfield, J. S.; Wollersheim, H. J.; Zielinska, M.; PreSPEC Collaboration

    2017-03-01

    Background: In the neutron-rich A ≈100 mass region, rapid shape changes as a function of nucleon number as well as coexistence of prolate, oblate, and triaxial shapes are predicted by various theoretical models. Lifetime measurements of excited levels in the molybdenum isotopes allow the determination of transitional quadrupole moments, which in turn provides structural information regarding the predicted shape change. Purpose: The present paper reports on the experimental setup, the method that allowed one to measure the lifetimes of excited states in even-even molybdenum isotopes from mass A =100 up to mass A =108 , and the results that were obtained. Method: The isotopes of interest were populated by secondary knock-out reaction of neutron-rich nuclei separated and identified by the GSI fragment separator at relativistic beam energies and detected by the sensitive PreSPEC-AGATA experimental setup. The latter included the Lund-York-Cologne calorimeter for identification, tracking, and velocity measurement of ejectiles, and AGATA, an array of position sensitive segmented HPGe detectors, used to determine the interaction positions of the γ ray enabling a precise Doppler correction. The lifetimes were determined with a relativistic version of the Doppler-shift-attenuation method using the systematic shift of the energy after Doppler correction of a γ -ray transition with a known energy. This relativistic Doppler-shift-attenuation method allowed the determination of mean lifetimes from 2 to 250 ps. Results: Even-even molybdenum isotopes from mass A =100 to A =108 were studied. The decays of the low-lying states in the ground-state band were observed. In particular, two mean lifetimes were measured for the first time: τ =29 .7-9.1+11.3 ps for the 4+ state of 108Mo and τ =3 .2-0.7+0.7 ps for the 6+ state of 102Mo. Conclusions: The reduced transition strengths B (E 2 ) , calculated from lifetimes measured in this experiment, compared to beyond

  4. Autonomous Graphene Vessel for Suctioning and Storing Liquid Body of Spilled Oil.

    PubMed

    Kim, Taewoo; Lee, Jeong Seok; Lee, Geonhui; Seo, Dong Kyun; Baek, Youngbin; Yoon, Jeyong; Oh, Seung M; Kang, Tae June; Lee, Hong H; Kim, Yong Hyup

    2016-02-29

    Despite remarkable strides in science and technology, the strategy for spilled oil collection has remained almost the same since the 1969 Santa Barbara oil spill. The graphene vessel devised here can bring about an important yet basic change in the strategy for spilled oil collection. When it is placed on the oil-covered seawater, the graphene vessel selectively separates the oil, then collects and stores the collected oil in the vessel all by itself without any external power inputs. Capillarity and gravity work together to fill this proto-type graphene vessel with the spilled oil at a rate that is higher than 20,000 liters per square meter per hour (LMH) with oil purity better than 99.9%, and allow the vessel to withstand a water head of 0.5 m. The vessel also has a superb chemical stability and recyclability. An expanded oil contact area, considerably greater than the thickness of the oil layer, forms at the reduced graphene oxide (rGO) foam interface upon contact with the spilled oil. This expanded contact area does not change much even when the oil layer thins out. As a result, the high oil collection rate is maintained throughout the recovery of spilled oil.

  5. Autonomous Graphene Vessel for Suctioning and Storing Liquid Body of Spilled Oil

    PubMed Central

    Kim, Taewoo; Lee, Jeong Seok; Lee, Geonhui; Seo, Dong Kyun; Baek, Youngbin; Yoon, Jeyong; Oh, Seung M.; Kang, Tae June; Lee, Hong H.; Kim, Yong Hyup

    2016-01-01

    Despite remarkable strides in science and technology, the strategy for spilled oil collection has remained almost the same since the 1969 Santa Barbara oil spill. The graphene vessel devised here can bring about an important yet basic change in the strategy for spilled oil collection. When it is placed on the oil-covered seawater, the graphene vessel selectively separates the oil, then collects and stores the collected oil in the vessel all by itself without any external power inputs. Capillarity and gravity work together to fill this proto-type graphene vessel with the spilled oil at a rate that is higher than 20,000 liters per square meter per hour (LMH) with oil purity better than 99.9%, and allow the vessel to withstand a water head of 0.5 m. The vessel also has a superb chemical stability and recyclability. An expanded oil contact area, considerably greater than the thickness of the oil layer, forms at the reduced graphene oxide (rGO) foam interface upon contact with the spilled oil. This expanded contact area does not change much even when the oil layer thins out. As a result, the high oil collection rate is maintained throughout the recovery of spilled oil. PMID:26923622

  6. The Oil Game: Generating Enthusiasm for Geosciences in Urban Youth in Newark, NJ

    ERIC Educational Resources Information Center

    Gates, Alexander E.; Kalczynski, Michael J.

    2016-01-01

    A hands-on game based upon principles of oil accumulation and drilling was highly effective at generating enthusiasm toward the geosciences in urban youth from underrepresented minority groups in Newark, NJ. Participating 9th-grade high school students showed little interest in the geosciences prior to participating in the oil game, even if they…

  7. Optimum oil production planning using infeasibility driven evolutionary algorithm.

    PubMed

    Singh, Hemant Kumar; Ray, Tapabrata; Sarker, Ruhul

    2013-01-01

    In this paper, we discuss a practical oil production planning optimization problem. For oil wells with insufficient reservoir pressure, gas is usually injected to artificially lift oil, a practice commonly referred to as enhanced oil recovery (EOR). The total gas that can be used for oil extraction is constrained by daily availability limits. The oil extracted from each well is known to be a nonlinear function of the gas injected into the well and varies between wells. The problem is to identify the optimal amount of gas that needs to be injected into each well to maximize the amount of oil extracted subject to the constraint on the total daily gas availability. The problem has long been of practical interest to all major oil exploration companies as it has the potential to derive large financial benefit. In this paper, an infeasibility driven evolutionary algorithm is used to solve a 56 well reservoir problem which demonstrates its efficiency in solving constrained optimization problems. Furthermore, a multi-objective formulation of the problem is posed and solved using a number of algorithms, which eliminates the need for solving the (single objective) problem on a regular basis. Lastly, a modified single objective formulation of the problem is also proposed, which aims to maximize the profit instead of the quantity of oil. It is shown that even with a lesser amount of oil extracted, more economic benefits can be achieved through the modified formulation.

  8. Immediate ecotoxicological effects of short-lived oil spills on marine biota

    PubMed Central

    Brussaard, Corina P. D.; Peperzak, Louis; Beggah, Siham; Wick, Lukas Y.; Wuerz, Birgit; Weber, Jan; Samuel Arey, J.; van der Burg, Bart; Jonas, Arjen; Huisman, Johannes; van der Meer, Jan Roelof

    2016-01-01

    Marine environments are frequently exposed to oil spills as a result of transportation, oil drilling or fuel usage. Whereas large oil spills and their effects have been widely documented, more common and recurrent small spills typically escape attention. To fill this important gap in the assessment of oil-spill effects, we performed two independent supervised full sea releases of 5 m3 of crude oil, complemented by on-board mesocosm studies and sampling of accidentally encountered slicks. Using rapid on-board biological assays, we detect high bioavailability and toxicity of dissolved and dispersed oil within 24 h after the spills, occurring fairly deep (8 m) below the slicks. Selective decline of marine plankton is observed, equally relevant for early stages of larger spills. Our results demonstrate that, contrary to common thinking, even small spills have immediate adverse biological effects and their recurrent nature is likely to affect marine ecosystem functioning. PMID:27041738

  9. Immediate ecotoxicological effects of short-lived oil spills on marine biota.

    PubMed

    Brussaard, Corina P D; Peperzak, Louis; Beggah, Siham; Wick, Lukas Y; Wuerz, Birgit; Weber, Jan; Samuel Arey, J; van der Burg, Bart; Jonas, Arjen; Huisman, Johannes; van der Meer, Jan Roelof

    2016-04-04

    Marine environments are frequently exposed to oil spills as a result of transportation, oil drilling or fuel usage. Whereas large oil spills and their effects have been widely documented, more common and recurrent small spills typically escape attention. To fill this important gap in the assessment of oil-spill effects, we performed two independent supervised full sea releases of 5 m(3) of crude oil, complemented by on-board mesocosm studies and sampling of accidentally encountered slicks. Using rapid on-board biological assays, we detect high bioavailability and toxicity of dissolved and dispersed oil within 24 h after the spills, occurring fairly deep (8 m) below the slicks. Selective decline of marine plankton is observed, equally relevant for early stages of larger spills. Our results demonstrate that, contrary to common thinking, even small spills have immediate adverse biological effects and their recurrent nature is likely to affect marine ecosystem functioning.

  10. Rapid methodology via mass spectrometry to quantify addition of soybean oil in extra virgin olive oil: A comparison with traditional methods adopted by food industry to identify fraud.

    PubMed

    da Silveira, Roberta; Vágula, Julianna Matias; de Lima Figueiredo, Ingrid; Claus, Thiago; Galuch, Marilia Bellanda; Santos Junior, Oscar Oliveira; Visentainer, Jesui Vergilio

    2017-12-01

    Fast and innovative methodology to monitors the addition of soybean oil in extra virgin olive oil was developed employing ESI-MS with ionization operating in positive mode. A certified extra virgin olive oil and refined soybean oil samples were analyzed by direct infusion, the identification of a natural lipid marker present only in soybean oil (m/z 886.68 [TAG+NH 4 ] + ) was possible. The certified extra virgin olive oil was purposely adulterated with soybean oil in different levels (1, 5, 10, 20, 50, 70, 90%) being possible to observe that the new methodology is able to detect even small fraud concentration, such as 1% (v/v). Additionally, commercial samples were analyzed and were observed the addition of soybean oil as a common fraud in this segment. This powerful analytical method proposed could be applied as routine analysis by control organization, as well as food industries, considering its pronounced advantages; simplicity, rapidity, elevated detectability and minor amounts of sample and solvent consumed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Demulsification of water/oil/solid emulsions by hollow-fiber membranes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tirmizi, N.P.; Raghuraman, B.; Wiencek, J.

    1996-05-01

    The demulsification techniques investigated use preferential surface wetting to allow separation of oil and water phases in ultrafiltration and microfiltration membranes. A hydrophobic membrane allows the permeation of an oil phase at almost zero pressure and retains the water phase, even though the molecular weight of the water molecule (18) is much smaller than that of the oil molecule (198 for tetradecane, used in this study). Hydrophobic membranes having pore sizes from 0.02 to 0.2 {micro}m were tested for demulsification of water-in-oil emulsions and water/oil/solid mixtures. The dispersed (aqueous)-phase drop sizes ranged from 1 to 5 {micro}m. High separation rates,more » as well as good permeate quality, were obtained with microfiltration membranes. Water content of permeating oil was 32--830 ppm depending on operating conditions and interfacial properties. For emulsions with high surfactant content, simultaneous operation of a hydrophobic and hydrophilic membrane, or simultaneous membrane separation with electric demulsification was more efficient in obtaining complete phase separation.« less

  12. Gravity-directed separation of both immiscible and emulsified oil/water mixtures utilizing coconut shell layer.

    PubMed

    Li, Jian; Xu, Changcheng; Zhang, Yan; Tang, Xiaohua; Qi, Wei; Wang, Qiong

    2018-02-01

    Pressure-driven and lower flux of superwetting ultrafiltration membranes in various emulsions separation are long-standing issues and major barriers for their large-scale utilization. Even though currently reported membranes have achieved great success in emulsions separeation, they still suffer from low flux and complex fabrication process resulting from their smaller nanoscale pore size. Herein, utilizition of coconut shell as a novel biomaterial for developing into a layer through the simple smashing, cleaning and stacking procedures, which not only could avoid the complexity of film making process, but also could realize efficient gravity-directed separation of both immiscible oil/water mixtures and water-in-oil emulsions with high flux. Specifically, the layer acted as "water-removing" type filtrate material with excellent underwater superoleophobicity, exhibiting high efficiency for various immiscible oil/water mixtures separation and larger oil intrusion pressure. More importantly, the layer could also serve as adsorbent material with underoil superhydrophilicity, achieving gravity-directed kinds of water-in-oil emulsions separation with high separation efficiency (above 99.99%) and higher flux (above 1620L/m 2 h), even when their pore sizes are larger than that of emulsified droplets. We deeply believe that this study would open up a new strategy for both immiscible oil/water mixtures and water-in-oil emulsions separation. Copyright © 2017 Elsevier Inc. All rights reserved.

  13. Wetland Vegetation Monitoring within Barataria Basin, Louisiana Following Exposure to Oil

    NASA Astrophysics Data System (ADS)

    Steyer, G.; Piazza, S.; Kokaly, R. F.; Patton, B.; Heckman, D.

    2011-12-01

    Following the Deepwater Horizon explosion and subsequent oil spill in April 2010 coastal wetlands in Louisiana were directly oiled, exposing vegetation and marsh soils to petroleum hydrocarbons. Oiling was observed at the marsh/water interface as well as within coastal marshes. The physical and chemical effects of oil spills can have both short and long term effects on wetland vegetation. These effects can include reductions in primary productivity and direct plant mortality. Even in the absence of this oiling event, the coastal landscape of Louisiana experiences high rates of land loss resulting from natural and anthropogenic causes. This additional stress has the potential to further reduce the extent and health of coastal marshes in this fragile ecosystem. We conducted a field study to document the impact of oiling on above and belowground vegetation biomass, plant species composition, and vegetation cover at sites within Barataria Basin, Louisiana. Six sampling sites were established, three within obviously oiled marshes and three where oiling was not readily apparent. Four sampling events occurred between October 2010 and October 2011. The preliminary results of the field study will be presented along with how these data helped validate remotely sensed data observations (AVIRIS) and calibrate ground reflectance in oiled and non-oiled marshes.

  14. Low-VOC wood floor varnishes from waterborne oil-modified urethanes

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ingle, D.M.; Petschke, G.H.

    Varnishes protect wood flooring and enhance its beauty. Varnish compositions have varied from drying oils and alkyds to more durable systems (moisture-cured urethanes, oil-modified urethanes, epoxies and UV-curable coatings). Some chemistries are better suited for professional or factory applied situations. Oils, alkyds and oil-modified urethanes (OMU) are suitable for onsite professional application or even refinish application by homeowners (DIY market). These materials traditionally have been high in VOC. Recently, waterborne (WB) systems (such as polyurethane dispersions) with greatly reduced VOC have been used; high costs and relatively poor durability are drawbacks. A new generation of high performance waterborne oil-modified urethanemore » is now available with extended shelf-stability required for contractor and consumer markets. Formulated varnishes are coming onto the market that offer performance similar to conventional OMU, but with significant reductions in VOC. For example, a typical formulation for a conventional solvent-borne oil-modified urethane can be supplied at 1.6 lb/gal (less water). This represents a VOC reduction of 70-75% at equal application coating weight. Furthermore, waterborne oil-modified urethane offers advantages over polyurethane dispersions in performance areas such as durability and mar resistance.« less

  15. Preservation of chicken breast meat treated with thyme and balm essential oils.

    PubMed

    Fratianni, Florinda; De Martino, Laura; Melone, Antonio; De Feo, Vincenzo; Coppola, Raffaele; Nazzaro, Filomena

    2010-10-01

    The present study evaluated the effects of thyme and balm essential oils on the 3-wk storage of fresh chicken breast meat at 4 °C. Thyme and, to a lesser extent, balm essential oils reduced DPPH (2,2-diphenyl-1-picrylhydrazyl) radical formation in the meat (25% to 30% and 20%, respectively). Treatment with the 2 essential oils also limited lipid peroxidation and the deterioration of sarcoplasmic proteins, helping to preserve the meat even after 2 wk of storage. Thyme and balm essential oils decreased the natural microflora present in the meat; total microbial content decreased down to 50% in comparison to the control samples. In addition, a clear effect on lactic acid bacterial growth was recorded. Balm essential oil significantly limited the growth of Salmonella sp., whereas thyme essential oil effectively inhibited the growth of Escherichia coli. Our data demonstrate that these 2 essential oils effectively reduced deteriorative processes in chicken meat and extended the shelf life of this fresh product. Practical Application: The essential oils of thyme and balm can protect the chicken meat from decomposition during the storage time.

  16. Femtosecond laser ablated durable superhydrophobic PTFE films with micro-through-holes for oil/water separation: Separating oil from water and corrosive solutions

    NASA Astrophysics Data System (ADS)

    Yong, Jiale; Fang, Yao; Chen, Feng; Huo, Jinglan; Yang, Qing; Bian, Hao; Du, Guangqing; Hou, Xun

    2016-12-01

    Separating the mixture of water and oil by the superhydrophobic porous materials has attracted increasing research interests; however, the surface microstructures and chemical composition of those materials are easily destroyed in a harsh environment, resulting in materials losing the superhydrophobicity as well as the oil/water separation function. In this paper, a kind of rough microstructures was formed on polytetrafluoroethylene (PTFE) sheet by femtosecond laser treatment. The rough surfaces showed durable superhydrophobicity and ultralow water adhesion even after storing in various harsh environment for a long time, including strong acid, strong alkali, and high temperature. A micro-through-holes array was further generated on the rough superhydrophobic PTFE film by a subsequent mechanical drilling process. The resultant sample was successfully applied in the field of oil/water separation due to the inverse superhydrophobicity and superoleophilicity. The designed separation system is also very efficient to separate the mixtures of oil and corrosive acid/alkali solutions, exhibiting the strong potential for practical application.

  17. Is Low-field NMR a Complementary Tool to GC-MS in Quality Control of Essential Oils? A Case Study: Patchouli Essential Oil.

    PubMed

    Krause, Andre; Wu, Yu; Tian, Runtao; van Beek, Teris A

    2018-04-24

    High-field NMR is an expensive and important quality control technique. In recent years, cheaper and simpler low-field NMR has become available as a new quality control technique. In this study, 60 MHz 1 H-NMR was compared with GC-MS and refractometry for the detection of adulteration of essential oils, taking patchouli essential oil as a test case. Patchouli essential oil is frequently adulterated, even today. In total, 75 genuine patchouli essential oils, 10 commercial patchouli essential oils, 10 other essential oils, 17 adulterants, and 1 patchouli essential oil, spiked at 20% with those adulterants, were measured. Visual inspection of the NMR spectra allowed for easy detection of 14 adulterants, while gurjun and copaiba balsams proved difficult and one adulterant could not be detected. NMR spectra of 10 random essential oils differed not only strongly from patchouli essential oil but also from one another, suggesting that fingerprinting by low-field NMR is not limited to patchouli essential oil. Automated chemometric evaluation of NMR spectra was possible by similarity analysis (Mahalanobis distance) based on the integration from 0.1 - 8.1 ppm in 0.01 ppm increments. Good quality patchouli essential oils were recognised as well as 15 of 17 deliberate adulterations. Visual qualitative inspection by GC-MS allowed for the detection of all volatile adulterants. Nonvolatile adulterants, and all but one volatile adulterant, could be detected by semiquantitation. Different chemometric approaches showed satisfactory results. Similarity analyses were difficult with nonvolatile adulterants. Refractive index measurements could detect only 8 of 17 adulterants. Due to advantages such as simplicity, rapidity, reproducibility, and ability to detect nonvolatile adulterants, 60 MHz 1 H-NMR is complimentary to GC-MS for quality control of essential oils. Georg Thieme Verlag KG Stuttgart · New York.

  18. Penetration enhancing effects of selected natural oils utilized in topical dosage forms.

    PubMed

    Viljoen, Joe M; Cowley, Amé; du Preez, Jan; Gerber, Minja; du Plessis, Jeanetta

    2015-01-01

    Various natural products, including oils, have been utilized as penetration enhancers due to their "safety profiles". These oils contain fatty acids promoting skin permeability through lipid fluidization within the stratum corneum; and might therefore be able to effectively enhance transdermal drug delivery. We investigated possible penetration enhancing properties of selected oils, utilizing flurbiprofen as marker compound in emulgel formulations. The formulations were compared to a liquid paraffin emulgel and a hydrogel to establish any significant penetration enhancing effects. Gas chromatographic analysis of the natural oils was performed at ambient temperature to determine the fatty acid composition in each selected natural oils. Franz cell diffusion studies and tape stripping methods were employed to study delivery of the marker into, and through the skin. The following rank order for the emulgel flux-values was obtained: Hydrogel > olive oil > liquid paraffin > coconut oil > grape seed oil > Avocado oil ≥ Crocodile oil > Emu oil. Results suggested that oils containing predominantly mono-unsaturated oleic acid, on average increased the flux of the marker to a larger extent than oils containing an almost even mixture of both mono- and poly-unsaturated fatty acids. Oils comprising saturated fatty acids (SFAs) with alkyl chains between C12 and C14, increased the marker flux to a higher extent than oils containing C16-C18 SFAs. Effects observed for branched fatty acids, however, did not vary significantly from effects for unbranched fatty acids with the same carbon chain length. Natural oils possess penetration enhancing effects.

  19. Dominant Middle East oil reserves critically important to world supply

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Riva, J.P. Jr.

    1991-09-23

    This paper reports that the location production, and transportation of the 60 million bbl of oil consumed in the world each day is of vital importance to relations between nations, as well as to their economic wellbeing. Oil has frequently been a decisive factor in the determination of foreign policy. The war in the Persian Gulf, while a dramatic example of the critical importance of oil, is just the latest of a long line of oil-influenced diplomatic/military incidents, which may be expected to continue. Assuming that the world's remaining oil was evenly distributed and demand did not grow, if explorationmore » and development proceeded as efficiently as they have in the U.S., world oil production could be sustained at around current levels to about the middle of the next century. It then would begin a long decline in response to a depleting resource base. However, the world's remaining oil is very unevenly distributed. It is located primarily in the Eastern Hemisphere, mostly in the Persian Gulf, and much is controlled by the Organization of Petroleum Exporting Countries. Scientific resource assessments indicate that about half of the world's remaining conventionally recoverable crude oil resource occurs in the Persian Gulf area. In terms of proved reserves (known recoverable oil), the Persian Gulf portion increase to almost two-thirds.« less

  20. Response to Oil Sands Products Assessment

    DTIC Science & Technology

    2015-09-01

    volume of the spill, its duration, and the viscosity and density of the crude oil involved. The denser components of a Dilbit spill would be difficult...C-4 Figure ‎C-2. Viscosity change for the three types of diluted bitumen. ......................................................... C...specific gravity) approaching or even exceeding the density of water. As a result of their high viscosity , bitumen cannot be produced by conventional

  1. Type of vegetable oils used in cooking and risk of metabolic syndrome among Asian Indians.

    PubMed

    Lakshmipriya, Nagarajan; Gayathri, Rajagopal; Praseena, Kallingal; Vijayalakshmi, Parthasarathy; Geetha, Gunasekaran; Sudha, Vasudevan; Krishnaswamy, Kamala; Anjana, Ranjit Mohan; Henry, Jeyakumar; Mohan, Viswanathan

    2013-03-01

    There is little data on the type of vegetable oil used and the prevalence of metabolic syndrome (MS) in Asian Indians. Food frequency questionnaire was used to document the type of cooking oil in 1875 adults in Chennai city. MS was assessed by new harmonizing criteria. The prevalence of MS was higher among sunflower oil users (30.7%) than palmolein (23.2%) and traditional oil (17.1%, p < 0.001) users. The higher prevalence of MS in sunflower oil group persisted even when stratified according to body mass index, except in obese groups. The risk of MS was further compounded by quantity of refined cereals consumed. Higher LA%E and linoleic acid/alpha-linolenic acid ratio in sunflower oil probably contributes to increased risk of MS.

  2. Natural Zeolite Sample and Investigation Its Use in Oil Bleaching Sector

    NASA Astrophysics Data System (ADS)

    Bilgin, Oyku

    2017-12-01

    In the sector of oil bleaching, the stored raw oil is subjected to physical and chemical methods such as degumming, neutralization, bleaching, deodorization and winterization. In the process of oil bleaching, the selection of correct bleaching earth in accordance with oil characteristics matters so much. Bleaching earth is an inorganic product used in removing impurities being available within the structures of vegetable, animal oil (sunflower, soya, corn, palm, tallow, rapeseed, fish oils…etc.) and fatty acids, mineral oils (glycerine, paraffin, mineral motor oils. etc.) with the adsorption process. The factors such as low cost of oil bleaching earth, low ratio of oil retaining, high bleaching capacity in spite of using them in small amounts, filter’s delayed blocking by the earth and non-increase of the free acidity of the oil should be taken into consideration. Bleaching earths are processed with some acids in order to widen their surface areas. During this process, a certain amount of acid is left within oil bleaching earths even if it is very little. These acids also increase oil’s acidity by oxidizing oil in the course of bleaching process. In this study, zeolite sample taken from Manisa -Demirci region was used. Following the processes of crushing and sieving, zeolite sample was subjected to chemical analyses according to their grain thickness, microscopic examination, the analyses of XRD and cation exchange capacity and their ore characteristics were determined. Afterwards, it was searched whether zeolite sample has oil bleaching ability or not or whether it can be used as oil bleaching earth or not.

  3. Generalization of the NpNn scheme to nonyrast levels of even-even nuclei

    NASA Astrophysics Data System (ADS)

    Zhao, Y. M.; Arima, A.

    2003-07-01

    In this Brief Report we present the systematics of excitation energies for even-even nuclei in two regions: the 50even if one extends it to nonyrast levels, and thus can serve as a general tool to disclose new types of structural evolution for higher excitations, besides the yrast states which have been investigated extensively. It is highlighted that deformations in nonyrast quasibands of nuclei with Z˜80 and N˜104 are often very different from those in the ground bands.

  4. Corn kernel oil and corn fiber oil

    USDA-ARS?s Scientific Manuscript database

    Unlike most edible plant oils that are obtained directly from oil-rich seeds by either pressing or solvent extraction, corn seeds (kernels) have low levels of oil (4%) and commercial corn oil is obtained from the corn germ (embryo) which is an oil-rich portion of the kernel. Commercial corn oil cou...

  5. Viet Nam, once isolated, poised for significant role in oil and gas

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1991-07-15

    This paper reports that Viet Nam is on its way up in the petroleum world. After years of international isolation, the country is poised for a flurry of exploration by international oil companies in the early 1990s. Viet Nam has joined the Soviet Union as the only members of the now dissolved, formerly Moscow dominated, 10 nation Council for Mutual Economic Assistance (CMEA) that are self-sufficient in oil production. Moreover, Viet Nam has far outstripped neighboring China, which was not a CMEA member, in offshore oil flow even though China has a much larger Outer Continental Shelf. Prospects are thatmore » Viet Nam will continue to lead China in offshore oil production until 1995 at least.« less

  6. Tourism and its hypersensitivity to oil spills.

    PubMed

    Cirer-Costa, Joan Carles

    2015-02-15

    The sinking of the Don Pedro merchant ship in 2007 near the island of Ibiza is a good example of the extreme sensitivity of the tourism sector to oil spills. Despite the limited scale of the spill (only some 20 tonnes), its minimal ecological impact, and the rapid deployment of personnel and equipment to contain it, the accident nonetheless caused significant economic damage to the island's tourism sector. This particular case demonstrates the importance of the beach as a factor of production in the holiday tourism sector, and the capacity of even small amounts of oil to render it unusable and cause heavy losses to holiday firms. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. Oil Fires and Oil Slick, Kuwait

    NASA Technical Reports Server (NTRS)

    1991-01-01

    In this color infrared view of the Kuwait oil fires and offshore oil slick, (29.0N, 48.0E), smoke from the burning oil fields both to the north and south of Kuwait City almost totally obliterates the image. Unburned pools of oil on the ground and oil offshore in the Persian Gulf are reflecting sunlight, much the same way as water does, and appear as white or light toned features. The water borne oil slicks drifted south toward the Arab Emirate States.

  8. Oil leakage detection for electric power equipment based on ultraviolet fluorescence effect

    NASA Astrophysics Data System (ADS)

    Zhang, Jing; Wang, Jian-hui; Xu, Bin; Huang, Zhi-dong; Huang, Lan-tao

    2018-03-01

    This paper presents a method to detect the oil leakage of high voltage power equipment based on ultraviolet fluorescence effect. The method exploits the principle that the insulating oil has the fluorescent effect under the irradiation of specific ultraviolet light. The emission spectrum of insulating oil under excitation light with different wavelengths is measured and analyzed first. On this basis, a portable oil leakage detective device for high voltage power equipment is designed and developed with a selected 365 nm ultraviolet as the excitation light and the low light level camera as the fluorescence image collector. Then, the feasibility of the proposed method and device in different conditions is experimentally verified in the laboratory environment. Finally, the developed oil leakage detective device is applied to 500 kV Xiamen substation and Quanzhou substation. And the results show that the device can detect the oil leakage of high voltage electrical equipment quickly and conveniently even under the condition of a slight oil leakage especially in the low light environment.

  9. Robust self-cleaning surfaces that function when exposed to either air or oil

    NASA Astrophysics Data System (ADS)

    Lu, Yao; Sathasivam, Sanjayan; Song, Jinlong; Crick, Colin R.; Carmalt, Claire J.; Parkin, Ivan P.

    2015-03-01

    Superhydrophobic self-cleaning surfaces are based on the surface micro/nanomorphologies; however, such surfaces are mechanically weak and stop functioning when exposed to oil. We have created an ethanolic suspension of perfluorosilane-coated titanium dioxide nanoparticles that forms a paint that can be sprayed, dipped, or extruded onto both hard and soft materials to create a self-cleaning surface that functions even upon emersion in oil. Commercial adhesives were used to bond the paint to various substrates and promote robustness. These surfaces maintained their water repellency after finger-wipe, knife-scratch, and even 40 abrasion cycles with sandpaper. The formulations developed can be used on clothes, paper, glass, and steel for a myriad of self-cleaning applications.

  10. Oil Dependence, Climate Change and Energy Security: Will Constraints on Oil Shape our Climate Future or Vice Versa?

    NASA Astrophysics Data System (ADS)

    Mignone, B. K.

    2008-12-01

    Threats to US and global energy security take several forms. First, the overwhelming dependence on oil in the transport sector leaves the US economy (and others) vulnerable to supply shocks and price volatility. Secondly, the global dependence on oil inflates prices and enhances the transfer of wealth to authoritarian regimes. Finally, the global reliance on fossil fuels more generally jeopardizes the stability of the climate system. These three threats - economic, strategic and environmental - can only be mitigated through a gradual substitution away from fossil fuels (both coal and oil) on a global scale. Such large-scale substitution could occur in response to potential resource constraints or in response to coordinated government policies in which these externalities are explicitly internalized. Here, I make use of a well-known integrated assessment model (MERGE) to examine both possibilities. When resource limits are considered alone, global fuel use tends to shift toward even more carbon-intensive resources, like oil shale or liquids derived from coal. On the other hand, when explicit carbon constraints are imposed, the fuel sector response is more complex. Generally, less stringent climate targets can be satisfied entirely through reductions in global coal consumption, while more stringent targets require simultaneous reductions in both coal and oil consumption. Taken together, these model results suggest that resource constraints alone will only exacerbate the climate problem, while a subset of policy-driven carbon constraints may yield tangible security benefits (in the form of reduced global oil consumption) in addition to the intended environmental outcome.

  11. Operational Satellite-based Surface Oil Analyses (Invited)

    NASA Astrophysics Data System (ADS)

    Streett, D.; Warren, C.

    2010-12-01

    During the Deepwater Horizon spill, NOAA imagery analysts in the Satellite Analysis Branch (SAB) issued more than 300 near-real-time satellite-based oil spill analyses. These analyses were used by the oil spill response community for planning, issuing surface oil trajectories and tasking assets (e.g., oil containment booms, skimmers, overflights). SAB analysts used both Synthetic Aperture Radar (SAR) and high resolution visible/near IR multispectral satellite imagery as well as a variety of ancillary datasets. Satellite imagery used included ENVISAT ASAR (ESA), TerraSAR-X (DLR), Cosmo-Skymed (ASI), ALOS (JAXA), Radarsat (MDA), ENVISAT MERIS (ESA), SPOT (SPOT Image Corp.), Aster (NASA), MODIS (NASA), and AVHRR (NOAA). Ancillary datasets included ocean current information, wind information, location of natural oil seeps and a variety of in situ oil observations. The analyses were available as jpegs, pdfs, shapefiles and through Google, KML files and also available on a variety of websites including Geoplatform and ERMA. From the very first analysis issued just 5 hours after the rig sank through the final analysis issued in August, the complete archive is still publicly available on the NOAA/NESDIS website http://www.ssd.noaa.gov/PS/MPS/deepwater.html SAB personnel also served as the Deepwater Horizon International Disaster Charter Project Manager (at the official request of the USGS). The Project Manager’s primary responsibility was to acquire and oversee the processing and dissemination of satellite data generously donated by numerous private companies and nations in support of the oil spill response including some of the imagery described above. SAB has begun to address a number of goals that will improve our routine oil spill response as well as help assure that we are ready for the next spill of national significance. We hope to (1) secure a steady, abundant and timely stream of suitable satellite imagery even in the absence of large-scale emergencies such as

  12. Market potential of solar thermal enhanced oil recovery-a techno-economic model for Issaran oil field in Egypt

    NASA Astrophysics Data System (ADS)

    Gupta, Sunay; Guédez, Rafael; Laumert, Björn

    2017-06-01

    Solar thermal enhanced oil recovery (S-EOR) is an advanced technique of using concentrated solar power (CSP) technology to generate steam and recover oil from maturing oil reservoirs. The generated steam is injected at high pressure and temperature into the reservoir wells to facilitate oil production. There are three common methods of steam injection in enhanced oil recovery - continuous steam injection, cyclic steam stimulation (CSS) and steam assisted gravity drainage (SAGD). Conventionally, this steam is generated through natural gas (NG) fired boilers with associated greenhouse gas emissions. However, pilot projects in the USA (Coalinga, California) and Oman (Miraah, Amal) demonstrated the use of S-EOR to meet their steam requirements despite the intermittent nature of solar irradiation. Hence, conventional steam based EOR projects under the Sunbelt region can benefit from S-EOR with reduced operational expenditure (OPEX) and increased profitability in the long term, even with the initial investment required for solar equipment. S-EOR can be realized as an opportunity for countries not owning any natural gas resources to make them less energy dependent and less sensible to gas price fluctuations, and for countries owning natural gas resources to reduce their gas consumption and export it for a higher margin. In this study, firstly, the market potential of S-EOR was investigated worldwide by covering some of the major ongoing steam based EOR projects as well as future projects in pipeline. A multi-criteria analysis was performed to compare local conditions and requirements of all the oil fields based on a defined set of parameters. Secondly, a modelling approach for S-EOR was designed to identify cost reduction opportunities and optimum solar integration techniques, and the Issaran oil field in Egypt was selected for a case study to substantiate the approach. This modelling approach can be consulted to develop S-EOR projects for any steam flooding based oil

  13. Mosquito repellent activity of volatile oils from selected aromatic plants.

    PubMed

    Lalthazuali; Mathew, Nisha

    2017-02-01

    Essential oils from fresh leaves of four aromatic plants viz., Ocimum sanctum, Mentha piperita, Eucalyptus globulus and Plectranthus amboinicus were extracted by hydrodistillation. The test solutions were prepared as 20% essential oil in ethanol and positive control as 20% DEET in ethanol. Essential oil blend was prepared as 5% concentration. Nulliparous, 3-5-day-old female adult Aedes aegypti mosquitoes were used for repellency screening as per ICMR protocol. The study showed that the repellency of 20% essential oil of O. sanctum, M. piperita and P. amboinicus were comparable with that of the standard DEET (20%) as no mosquito landing on the test was observed up to 6 h. The E. globulus oil exhibited mosquito repellency only upto 1½ h. Considerable mosquito landing and feeding was displayed in negative control. In the case of the oil blend, no landing of mosquitoes was seen up to 6 h as that of positive control. The results showed that the essential oil blend from O. sanctum, M. piperita, E. globulus and P. amboinicus could repel Ae. aegypti mosquitoes or prevent from feeding as in the case of DEET even at a lower concentration of 5%. This study demonstrates the potential of essential oils from O. sanctum, M. piperita, E. globulus and P. amboinicus and their blend as mosquito repellents against Ae. aegypti, the vector of dengue, chikungunya and yellow fever.

  14. Oil: a guide through the total energy jungle

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Windsor, P.

    1976-01-01

    The primary fact is, according to Mr. Windsor, that there is no shortage of oil and there won't be for many years to come--ample time for advanced technologies to provide other sources of energy if only.... This is not to downgrade the severity of the crisis--but to say that the major dangers lie elsewhere, in politics, in monetary, fiscal, social and military national policies. The author traces an easily comprehensible line for connection through these complexities. Here is a brief history of oil, of the great oil companies, their connections with their governments and their continuing, if diminishing, importance. Heremore » are answers to such vital questions as: why a complex OPEC country like Iran might want maximum oil production and the highest possible rate of price increase while a smaller and simpler one like Saudi Arabia might want to keep its oil in the ground and ask more moderate prices; what effect the price of oil may have on world economic stability and the capabilities of Western technology; how oil is now setting back if not destroying the Green Revolution in new and developing countries; why it is perhaps sensible to develop oil fields off Scotland and Alaska, and elsewhere, even though the wellhead cost per barrel is astronomically higher than in Saudi Arabia. These matters, and many others like them, are not separate although they have devastating particular effects. In the end, more concerned with international relations than with oil itself or economics in the strict sense of the word, this book points out that the solution must be political on a multinational scale and requires foresight and forbearance of a kind uncommon in history. (from book jacket)« less

  15. Peak Oil, Peak Coal and Climate Change

    NASA Astrophysics Data System (ADS)

    Murray, J. W.

    2009-05-01

    Research on future climate change is driven by the family of scenarios developed for the IPCC assessment reports. These scenarios create projections of future energy demand using different story lines consisting of government policies, population projections, and economic models. None of these scenarios consider resources to be limiting. In many of these scenarios oil production is still increasing to 2100. Resource limitation (in a geological sense) is a real possibility that needs more serious consideration. The concept of 'Peak Oil' has been discussed since M. King Hubbert proposed in 1956 that US oil production would peak in 1970. His prediction was accurate. This concept is about production rate not reserves. For many oil producing countries (and all OPEC countries) reserves are closely guarded state secrets and appear to be overstated. Claims that the reserves are 'proven' cannot be independently verified. Hubbert's Linearization Model can be used to predict when half the ultimate oil will be produced and what the ultimate total cumulative production (Qt) will be. US oil production can be used as an example. This conceptual model shows that 90% of the ultimate US oil production (Qt = 225 billion barrels) will have occurred by 2011. This approach can then be used to suggest that total global production will be about 2200 billion barrels and that the half way point will be reached by about 2010. This amount is about 5 to 7 times less than assumed by the IPCC scenarios. The decline of Non-OPEC oil production appears to have started in 2004. Of the OPEC countries, only Saudi Arabia may have spare capacity, but even that is uncertain, because of lack of data transparency. The concept of 'Peak Coal' is more controversial, but even the US National Academy Report in 2007 concluded only a small fraction of previously estimated reserves in the US are actually minable reserves and that US reserves should be reassessed using modern methods. British coal production can be

  16. Improved extraction of avocado oil by application of sono-physical processes.

    PubMed

    Martínez-Padilla, Laura Patricia; Franke, Lisa; Xu, Xin-Qing; Juliano, Pablo

    2018-01-01

    Ultrasound treatment is known to increase the oil extractability in olive and palm oil processes. This work examined the effect of ultrasound conditioning of avocado puree on oil extractability and quality, at low (18+40kHz) and high (2MHz) frequencies, at litre-scale. Other ultrasound parameters evaluated included high frequency effect (0.4, 0.6, and 2MHz; 5min; 90kJ/kg) and sonication time (2.5-10min at 2MHz), without malaxation. Finally, a megasonic post-malaxation intervention was assessed at selected malaxation times (15, 30, and 60min). Both low and high frequency ultrasound treatments of the non-malaxed avocado puree improved extractability by 15-24% additional oil recovery, with the highest extractability achieved after 2MHz treatments, depending on the fruit maturity and oil content. There was no preferential improvement on oil extractability observed across high frequencies, even though extractability increased with sonication time. Ultrasound treatment also showed a positive effect after puree malaxation. Oils obtained from sonicated purees showed peroxide and free fatty acid values below the industrial specification levels and an increase in total phenolic compounds after 2MHz treatment. High frequency ultrasound conditioning of avocado puree can enhance oil separation and potentially decrease the malaxation time in industrial processes without impacting on oil quality. Copyright © 2017 Elsevier B.V. All rights reserved.

  17. On the generation and outcome of 3-(N-phenylamino)propane-1,2-diol derivatives in deodorized model oils related to toxic oil syndrome.

    PubMed

    Morató, Anna; Escabrós, Jordi; Manich, Albert; Reig, Natàlia; Castaño, Yolanda; Abián, Joaquín; Messeguer, Angel

    2005-04-01

    Toxic Oil Syndrome (TOS) was a massive food-born intoxication that occurred in Spain in 1981 and affected more than 20,000 people. TOS was attributed to the ingestion of rapeseed oil that had been adulterated with aniline, illegally refined, and delivered for human consumption. Two chemical species derived from aniline have been identified in oil batches: fatty acid anilides, qualified as biomarkers of the adulterated oil, and fatty acid esters of 3-(N-phenylamino)propane-1,2-diol (PAP), considered toxic oil biomarkers. These esters were generated by chemical processes during oil refining, specifically in the deodorization step, which involves treatment of the oil at high temperatures under vacuum to remove volatile contaminants. Since PAP derivatives are strongly associated with TOS, their formation and putative interconversion in a toxic oil model has been studied. The main results obtained are (i) only triglycerides and aniline are required to produce PAP esters, thus eliminating the possibility that unknown activators present in the deodorization tank were required for toxification of the oil; (ii) PAP and PAP mono- and diesters are chemically interrelated, as are anilides and PAP esters to an even higher degree. In addition to the reaction of aniline with triglycerides, anilides can be also formed via attack of PAP esters by aniline. However, the most important source of anilides during deodorization seems to be the thermal decomposition of PAP esters. Overall, these results suggest that the generation and outcome of PAP derivatives during deodorization is a complex scenario whereby PAP esters are not only generated from different reactions but decompose to produce anilides, among other compounds. In addition to providing a rapeseed oil model that reproduces the composition of case oils with respect to anilides and PAP derivatives, the results presented herein further support the hypothesis imputing PAP diesters or their metabolites for the intoxication

  18. Oil

    USGS Publications Warehouse

    Rocke, T.E.

    1999-01-01

    Each year, an average of 14 million gallons of oil from more than 10,000 accidental spills flow into fresh and saltwater environments in and around the United States. Most accidental oil spills occur when oil is transported by tankers or barges, but oil is also spilled during highway, rail, and pipeline transport, and by nontransportation-related facilities, such as refinery, bulk storage, and marine and land facilities (Fig. 42.1). Accidental releases, however, account for only a small percentage of all oil entering the environment; in heavily used urban estuaries, the total petroleum hydrocarbon contributions due to transportation activities may be 10 percent or less. Most oil is introduced to the environment by intentional discharges from normal transport and refining operations, industrial and municipal discharges, used lubricant and other waste oil disposal, urban runoff, river runoff, atmospheric deposition, and natural seeps. Oil-laden wastewater is often released into settling ponds and wetlands (Fig. 42.2). Discharges of oil field brines are a major source of the petroleum crude oil that enters estuaries in Texas.

  19. Essential oil-loaded lipid nanoparticles for wound healing.

    PubMed

    Saporito, Francesca; Sandri, Giuseppina; Bonferoni, Maria Cristina; Rossi, Silvia; Boselli, Cinzia; Icaro Cornaglia, Antonia; Mannucci, Barbara; Grisoli, Pietro; Vigani, Barbara; Ferrari, Franca

    2018-01-01

    Chronic wounds and severe burns are diseases responsible for severe morbidity and even death. Wound repair is a crucial process and tissue regeneration enhancement and infection prevention are key factors to minimize pain, discomfort, and scar formation. The aim of this work was the development of lipid nanoparticles (solid lipid nanoparticles and nanostructured lipid carriers [NLC]), to be loaded with eucalyptus or rosemary essential oils and to be used, as medical devices, to enhance healing of skin wounds. Lipid nanoparticles were based on natural lipids: cocoa butter, as solid lipid, and olive oil or sesame oil, as liquid lipids. Lecithin was chosen as surfactant to stabilize nanoparticles and to prevent their aggregation. The systems were prepared by high shear homogenization followed by ultrasound application. Nanoparticles were characterized for physical-chemical properties, bioadhesion, cytocompatibility, in vitro proliferation enhancement, and wound healing properties toward normal human dermal fibroblasts. Antimicrobial activity of nanoparticles was evaluated against two reference microbial strains, one of Staphylococcus aureus , the other of Streptococcus pyogenes . Finally, the capability of nanoparticles to promote wound healing in vivo was evaluated on a rat burn model. NLC based on olive oil and loaded with eucalyptus oil showed appropriate physical-chemical properties, good bioadhesion, cytocompatibility, in vitro proliferation enhancement, and wound healing properties toward fibroblasts, associated to antimicrobial properties. Moreover, the in vivo results evidenced the capability of these NLC to enhance the healing process. Olive oil, which is characterized by a high content of oleic acid, proved to exert a synergic effect with eucalyptus oil with respect to antimicrobial activity and wound repair promotion.

  20. Traceability of plant contribution in olive oil by amplified fragment length polymorphisms.

    PubMed

    Pafundo, Simona; Agrimonti, Caterina; Marmiroli, Nelson

    2005-09-07

    Application of DNA molecular markers to traceability of foods is thought to bring new benefit to consumer's protection. Even in a complex matrix such as olive oil, DNA could be traced with PCR markers such as the amplified fragment length polymorphisms (AFLPs). In this work, fluorescent AFLPs were optimized for the characterization of olive oil DNA, to obtain highly reproducible, high-quality fingerprints, testing different parameters: the concentrations of dNTPs and labeled primer, the kind of Taq DNA polymerase and thermal cycler, and the quantity of DNA employed. It was found that correspondence of fingerprinting by comparing results in oils and in plants was close to 70% and that the DNA extraction from olive oil was the limiting step for the reliability of AFLP profiles, due to the complex matrix analyzed.

  1. Protection of groundwater from oil pollution in the vicinity of airports

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Svoma, J.; Houzim, V.

    1984-01-01

    The potential danger to the quality of groundwater close to airports is due to a combination of several ecologically unfavorable factors. Airports are usually situated in the proximity of a groundwater divide, or in wide valleys. Causes of pollution include the sheer volume of fluid being handled constantly, the physicochemical properties of hydrocarbons, and technical errors in the transport and storage of fuels. Oil hydrocarbons in concentrations of tenths to units of milligrams per liter have been found in snow in the vicinity of runways. Carcinogenic benzopyrenes are accumulated in soil. Oil hydrocarbons spread in rock formations as a separatemore » layer was well as in solution. In porous permeable formations, pollution by a free product affects areas on the order of tens of meters, while hydrocarbons in solution penetrate to distances of hundreds of meters or even kilometers. Fissured rocks are cause for even more complex conditions for the spreading of oil based substances. Preventive protection of groundwater and mineral waters using monitoring devices is being carried out at some major airports. Observation wells situated in the tectonic zone can also be used for reparative pumping. 12 references, 7 figures, 3 tables.« less

  2. Instrumental studies on silicone oil adsorption to the surface of intraocular lenses

    NASA Astrophysics Data System (ADS)

    Kim, Chun Ho; Joo, Choun-Ki; Chun, Heung Jae; Yoo, Bok Ryul; Noh, Dong Il; Shim, Young Bock

    2012-12-01

    The purpose of this study was to examine the degree of adherence of silicone oil to various intraocular lenses (IOLs) through comparison of the physico-chemical properties of the oil and IOLs. Four kinds of IOLs comprising various biomaterials were examined: PMMA (720A™), PHEMA (IOGEL 1103™), Acrysof (MA60BM™), and silicone (SI30NB™). Each lens was immersed in silicone oil or carboxylated silicone (CS-PDMS) oil for 72 h. For determination of the changes in chemical and elemental compositions on the surfaces of IOLs caused by the contact with silicone oil, IOLs were washed and rinsed with n-pentane to remove as much of the adsorbed silicone oil as possible, then subjected to Fourier transform infrared spectroscopic (FTIR) and X-ray photoelectron spectroscopic (XPS) analyses. The results of FTIR studies strongly indicate that washing with n-pentane completely removed the adhered silicone oil on the surfaces of PHEMA and Acrysof IOLs, whereas the residual silicone oil was detected on the surfaces of PMMA and silicone IOLs. XPS studies showed that silicone oil coverage of PMMA lenses was 12%, even after washing with n-pentane. In the case of silicone IOLs, the relative O1s peak area of carboxyl group in the residual CS-PDMS oil was found to be ˜2.7%. Considering that 2.8% carboxyl group-substituted silicone oil was used in the present study, CS-PDMS oil covered the entire surface of the silicone IOLs.

  3. Effects of cocoa butter triacylglycerides and minor compounds on oil migration.

    PubMed

    Wang, Hao; Maleky, Farnaz

    2018-04-01

    In a multi-component chocolate product, oil migration, from high oil content filling into chocolate, is one of the major contributors to the product quality loss. Among various parameters influencing oil diffusivity, cocoa butter is studied intensively. Studies have shown that the rate of oil transportion in cocoa butter is affected by its composition, the way that it is crystallized, and also the storage conditions. To model and study effects of cocoa butter type and processing conditions on oil migration, five different cocoa butter samples were studied in this work. Samples' chemical compositions in addition to their structural properties were analyzed to understand and compare oil migrations in the networks. Crystallized cocoa butter samples were placed in contact with a cream as a source of liquid oil. Using Magnetic Resonance Imaging, the movement of liquid oil into samples was investigated. The effects of minor differences in the cocoa butter chemical compositions on oil migrations rate are shown clearly. The highest effective diffusion coefficient was observed in the sample with the higher unsaturated fatty acids and phospholipids content. Although shearing at 250s -1 delayed oil migration in all the samples and a significantly lower diffusion coefficient was observed in the dynamic samples, the effects of chemical composition were still dominant. This study successfully highlighted that even minor differences in cocoa butter composition affect the network mass transfer phenomenon dramatically and that it is not easy to diminish these possessions by just crystallization processes. Published by Elsevier Ltd.

  4. Green bio-oil extraction for oil crops

    NASA Astrophysics Data System (ADS)

    Zainab, H.; Nurfatirah, N.; Norfaezah, A.; Othman, H.

    2016-06-01

    The move towards a green bio-oil extraction technique is highlighted in this paper. The commonly practised organic solvent oil extraction technique could be replaced with a modified microwave extraction. Jatropha seeds (Jatropha curcas) were used to extract bio-oil. Clean samples were heated in an oven at 110 ° C for 24 hours to remove moisture content and ground to obtain particle size smaller than 500μm. Extraction was carried out at different extraction times 15 min, 30 min, 45 min, 60 min and 120 min to determine oil yield. The biooil yield obtained from microwave assisted extraction system at 90 minutes was 36% while that from soxhlet extraction for 6 hours was 42%. Bio-oil extracted using the microwave assisted extraction (MAE) system could enhance yield of bio-oil compared to soxhlet extraction. The MAE extraction system is rapid using only water as solvent which is a nonhazardous, environment-friendly technique compared to soxhlet extraction (SE) method using hexane as solvent. Thus, this is a green technique of bio-oil extraction using only water as extractant. Bio-oil extraction from the pyrolysis of empty fruit bunch (EFB), a biomass waste from oil palm crop, was enhanced using a biocatalyst derived from seashell waste. Oil yield for non-catalytic extraction was 43.8% while addition of seashell based biocatalyst was 44.6%. Oil yield for non-catalytic extraction was 43.8% while with addition of seashell-based biocatalyst was 44.6%. The pH of bio-oil increased from 3.5 to 4.3. The viscosity of bio-oil obtained by catalytic means increased from 20.5 to 37.8 cP. A rapid and environment friendly extraction technique is preferable to enhance bio-oil yield. The microwave assisted approach is a green, rapid and environmental friendly extraction technique for the production of bio-oil bearing crops.

  5. Effect of mineral oil, sunflower oil, and coconut oil on prevention of hair damage.

    PubMed

    Rele, Aarti S; Mohile, R B

    2003-01-01

    Previously published results showed that both in vitro and in vivo coconut oil (CNO) treatments prevented combing damage of various hair types. Using the same methodology, an attempt was made to study the properties of mineral oil and sunflower oil on hair. Mineral oil (MO) was selected because it is extensively used in hair oil formulations in India, because it is non-greasy in nature, and because it is cheaper than vegetable oils like coconut and sunflower oils. The study was extended to sunflower oil (SFO) because it is the second most utilized base oil in the hair oil industry on account of its non-freezing property and its odorlessness at ambient temperature. As the aim was to cover different treatments, and the effect of these treatments on various hair types using the above oils, the number of experiments to be conducted was a very high number and a technique termed as the Taguchi Design of Experimentation was used. The findings clearly indicate the strong impact that coconut oil application has to hair as compared to application of both sunflower and mineral oils. Among three oils, coconut oil was the only oil found to reduce the protein loss remarkably for both undamaged and damaged hair when used as a pre-wash and post-wash grooming product. Both sunflower and mineral oils do not help at all in reducing the protein loss from hair. This difference in results could arise from the composition of each of these oils. Coconut oil, being a triglyceride of lauric acid (principal fatty acid), has a high affinity for hair proteins and, because of its low molecular weight and straight linear chain, is able to penetrate inside the hair shaft. Mineral oil, being a hydrocarbon, has no affinity for proteins and therefore is not able to penetrate and yield better results. In the case of sunflower oil, although it is a triglyceride of linoleic acid, because of its bulky structure due to the presence of double bonds, it does not penetrate the fiber, consequently resulting

  6. PROTOTYPIC CONTINUITY METHODS FOR FASTER RECOVERY OF OIL PRODUCTS SUPPLY AFTER GREAT QUAKE

    NASA Astrophysics Data System (ADS)

    Yasuno, Takato

    In the Great East Japan Earthquake, some oil product farms and tanks had a lot of damages. Then we temporally run short of oil products such as gasoline, lamp oil. The oil product is indispensable to make cargo shipment, or rescue operations, and some trouble must come for everyday shopping and movement of business. The lifeline damages come out electric power, water service, gas and communication. In addition the oil product shortage overlaps then the importance to restore was recognized. After earthquake disaster, there is a possibility to interrupt supply services such as shipping from oil tanks and sale at stations. Even if their discontinuation comes, it needs some business continuity policies in order to recover supply service at early stage. This paper grasps oil product discontinuation of supply and restoration transition and tries to get disaster lessons. This paper proposes prototypic techniques to minimize the sum of penalties to supply no service for neighbor region with capacities of critical stations. It applies to Tohoku regions and their gas stations and comments the usefulness of techniques and implication of supply service continuity policy.

  7. The new break-even analysis.

    PubMed

    Laskaris, James; Regan, Katie

    2013-12-01

    Changes in the economic and legislative environment have complicated the capital acquisition landscape. Hospitals and health systems should: Question the assumptions that underlie their break-even analysis. Revamp the break-even calculator. Engage in discussions about the clinical aspects of equipment and technology acquisition decisions.

  8. Essential Oils, Part VI: Sandalwood Oil, Ylang-Ylang Oil, and Jasmine Absolute.

    PubMed

    de Groot, Anton C; Schmidt, Erich

    In this article, some aspects of sandalwood oil, ylang-ylang oil, and jasmine absolute are discussed including their botanical origin, uses of the plants and the oils and absolute, chemical composition, contact allergy to and allergic contact dermatitis from these essential oils and absolute, and their causative allergenic ingredients.

  9. World oil

    NASA Astrophysics Data System (ADS)

    Sweeney, J. L.

    1982-06-01

    Results obtained through the application of 10 prominent world oil or world energy models to 12 scenarios are reported. These scenarios were designed to bound the range of likely future world oil market outcomes. Conclusions relate to oil market trends, impacts of policies on oil prices, security of oil supplies, impacts of policies on oil security problems, use of the oil import premium in policymaking, the transition to oil substitutes, and the state of the art of world oil modeling.

  10. Chemometric techniques in oil classification from oil spill fingerprinting.

    PubMed

    Ismail, Azimah; Toriman, Mohd Ekhwan; Juahir, Hafizan; Kassim, Azlina Md; Zain, Sharifuddin Md; Ahmad, Wan Kamaruzaman Wan; Wong, Kok Fah; Retnam, Ananthy; Zali, Munirah Abdul; Mokhtar, Mazlin; Yusri, Mohd Ayub

    2016-10-15

    Extended use of GC-FID and GC-MS in oil spill fingerprinting and matching is significantly important for oil classification from the oil spill sources collected from various areas of Peninsular Malaysia and Sabah (East Malaysia). Oil spill fingerprinting from GC-FID and GC-MS coupled with chemometric techniques (discriminant analysis and principal component analysis) is used as a diagnostic tool to classify the types of oil polluting the water. Clustering and discrimination of oil spill compounds in the water from the actual site of oil spill events are divided into four groups viz. diesel, Heavy Fuel Oil (HFO), Mixture Oil containing Light Fuel Oil (MOLFO) and Waste Oil (WO) according to the similarity of their intrinsic chemical properties. Principal component analysis (PCA) demonstrates that diesel, HFO, MOLFO and WO are types of oil or oil products from complex oil mixtures with a total variance of 85.34% and are identified with various anthropogenic activities related to either intentional releasing of oil or accidental discharge of oil into the environment. Our results show that the use of chemometric techniques is significant in providing independent validation for classifying the types of spilled oil in the investigation of oil spill pollution in Malaysia. This, in consequence would result in cost and time saving in identification of the oil spill sources. Copyright © 2016. Published by Elsevier Ltd.

  11. Use of geochemical biomarkers in bottom sediment to track oil from a spill, San Francisco Bay, California

    USGS Publications Warehouse

    Hostettler, F.D.; Rapp, J.B.; Kvenvolden, K.A.

    1992-01-01

    In April 1988, approximately 1500 m3 of a San Joaquin Valley crude oil were accidentally released from a Shell Oil Co. refinery near Martinez, Californa. The oil flowed into Carquinez Strait and Suisun Bay in northern San Francisco Bay Sediment and oil samples were collected within a week and analysed for geochemical marker compounds in order to track the molecular signature of the oil spill in the bottom sediment. Identification of the spilled oil in the sediment was complicated by the degraded nature of the oil and the similarity of the remaining, chromatographically resolvable constituents to those already present in the sediments from anthropogenic petroleum contamination, pyrogenic sources, and urban drainage. Ratios of hopane and sterane biomarkers, and of polycyclic aromatic hydrocarbons and their alkylated derivatives best identified the oil impingement. They showed the oil impact at this early stage to be surficial only, and to be patchy even within an area of heavy oil exposure.

  12. A Healthy Reduction in Oil Dependence and Carbon Emissions

    NASA Astrophysics Data System (ADS)

    Higgins, P. A.; Higgins, M.

    2003-12-01

    Societal dependence on oil as an energy source for personal transportation leads to increasingly negative social consequences including climate change, air pollution, political and economic instability and habitat degradation. Our heavy reliance on the automobile for transportation, determined in part by urban sprawl, also contributes to the population's increasingly sedentary lifestyle and to a concomitant degradation in health. We have shown that widespread substitution of exercise, commensurate with previously recommended levels, through biking or walking instead of driving can substantially reduce oil consumption and carbon emissions. For example, if all individuals between the ages of 10 and 64 substituted one hour of cycling for driving the reduction in gasoline demand would be equivalent to the gas produced from 34.9 percent of current oil consumption. Relative to 1990 net US emissions, this constitutes a 10.9 percent reduction in carbon emissions. Therefore, substitution of exercise for driving could improve health, reduce carbon emissions and save more oil than even upper estimates of that contained in the Arctic National Wildlife Refuge.

  13. Anti-dandruff Hair Tonic Containing Lemongrass (Cymbopogon flexuosus) Oil.

    PubMed

    Chaisripipat, Wannee; Lourith, Nattaya; Kanlayavattanakul, Mayuree

    2015-01-01

    Natural remedies for treating dandruff are becoming popular. A randomized, double-blind, placebo-controlled, split-head efficacy evaluation was conducted 30 Thai volunteers aged 20-60 years experiencing dandruff measured at level 3 on D-Squame® scale. An easy to use hair tonic containing essential oil of lemongrass (Cymbopogon flexuosus) active against lipophilic yeasts was developed and then evaluated for efficacy and preference. The base formulation with the significantly highest preference (p < 0.05) was stowed with the oil at 5, 10 or 15%. Subjects applied the formulation twice a day, and an efficacy assessment with D-Squame® scale was conducted on days 7 and 14 of application. The application of lemongrass oil hair tonics with 5, 10, or 15% reduced dandruff significant (p < 0.005) at day 7 (33, 75, and 51%) and increased the effect even more (p < 0.005) at day 14 (52, 81, and 74%). The hair tonic formulation with 10% of lemongrass oil seems to be the most effective preparation. © 2015 S. Karger GmbH, Freiburg.

  14. [Liver enzyme abnormalities among oil refinery workers].

    PubMed

    Carvalho, Fernando Martins; Silvany Neto, Annibal Muniz; Mendes, João Luiz Barberino; Cotrim, Helma Pinchemel; Nascimento, Ana Lísia Cunha; Lima Júnior, Alberto Soares; Cunha, Tatiana Oliveira Bernardo da

    2006-02-01

    Occupational exposure typical of an oil refinery may alter liver function among the workers. Thus, the objective of the study was to identify risk factors for liver enzyme abnormalities among oil refinery workers. The workers at an oil refinery in Northeastern Brazil underwent routine annual medical examination from 1982 to 1998. This case-control study investigated all the 150 cases of individuals with simultaneous gamma-glutamyltransferase and alanine aminotransferase abnormalities of at least 10% above reference levels. As controls, 150 workers without any liver enzyme or bilirubin abnormalities since starting to work there were selected. Odds ratios and the respective 95% confidence intervals were calculated from logistic regression models. In all the production sectors, the risk of liver enzyme abnormalities was significantly higher than in the administrative sector (OR=5.7; 95% CI: 1.7-18.4), even when the effects of alcohol, obesity and medical history of hepatitis were controlled for. During the period from 1992 to 1994, 88 out of the 89 cases occurred among workers from the various production sectors. Occupational exposure plays an important role in causing liver enzyme abnormalities among oil refinery workers. This is in addition to the specifically biological and/or behavioral risk factors such as obesity and alcohol consumption.

  15. Dispersed oil disrupts microbial pathways in pelagic food webs.

    PubMed

    Ortmann, Alice C; Anders, Jennifer; Shelton, Naomi; Gong, Limin; Moss, Anthony G; Condon, Robert H

    2012-01-01

    Most of the studies of microbial processes in response to the Deepwater Horizon oil spill focused on the deep water plume, and not on the surface communities. The effects of the crude oil and the application of dispersants on the coastal microbial food web in the northern Gulf of Mexico have not been well characterized even though these regions support much of the fisheries production in the Gulf. A mesocosm experiment was carried out to determine how the microbial community off the coast of Alabama may have responded to the influx of surface oil and dispersants. While the addition of glucose or oil alone resulted in an increase in the biomass of ciliates, suggesting transfer of carbon to higher trophic levels was likely; a different effect was seen in the presence of dispersant. The addition of dispersant or dispersed oil resulted in an increase in the biomass of heterotrophic prokaryotes, but a significant inhibition of ciliates, suggesting a reduction in grazing and decrease in transfer of carbon to higher trophic levels. Similar patterns were observed in two separate experiments with different starting nutrient regimes and microbial communities suggesting that the addition of dispersant and dispersed oil to the northern Gulf of Mexico waters in 2010 may have reduced the flow of carbon to higher trophic levels, leading to a decrease in the production of zooplankton and fish on the Alabama shelf.

  16. Bioactivity of essential oils in phytopathogenic and post-harvest fungi control.

    PubMed

    Santamarina, M P; Ibáñez, M D; Marqués, M; Roselló, J; Giménez, S; Blázquez, M A

    2017-11-01

    Commercial thyme and lavender essential oils were analysed by GC/MS. Sixty-six compounds accounting for 98.6-99.6% of total essential oil were identified. Thymol (52.14 ± 0.21%), followed by p-cymene (32.24 ± 0.16%), carvacrol (3.71 ± 0.01%) and γ-terpinene (3.34 ± 0.02%), were the main compounds in thyme essential oil, while large amounts of oxygenated monoterpenes linalool acetate (37.07 ± 0.24%) and linalool (30.16 ± 0.06%) were found in lavender one. In vitro antifungal activity of the essential oils was evaluated at 200 and 300 μg/mL against 10 phytopathogenic and post-harvest fungi, which significantly affect agriculture. Micelial growth inhibition was calculated for each tested fungus and dose. Thyme essential oil showed satisfactory results with 90-100% growth inhibition in almost all the assayed fungi at 300 μg/mL, while lavender essential oil showed no noteworthy inhibition data at either dose, and its growth was even enhanced. Thyme essential oil represents a natural alternative to control harvest and post-harvest fungi, and to extend the shelf-life of agriculture products.

  17. Why fish oil fails: a comprehensive 21st century lipids-based physiologic analysis.

    PubMed

    Peskin, B S

    2014-01-01

    The medical community suffered three significant fish oil failures/setbacks in 2013. Claims that fish oil's EPA/DHA would stop the progression of heart disease were crushed when The Risk and Prevention Study Collaborative Group (Italy) released a conclusive negative finding regarding fish oil for those patients with high risk factors but no previous myocardial infarction. Fish oil failed in all measures of CVD prevention-both primary and secondary. Another major 2013 setback occurred when fish oil's DHA was shown to significantly increase prostate cancer in men, in particular, high-grade prostate cancer, in the Selenium and Vitamin E Cancer Prevention Trial (SELECT) analysis by Brasky et al. Another monumental failure occurred in 2013 whereby fish oil's EPA/DHA failed to improve macular degeneration. In 2010, fish oil's EPA/DHA failed to help Alzheimer's victims, even those with low DHA levels. These are by no means isolated failures. The promise of fish oil and its so-called active ingredients EPA / DHA fails time and time again in clinical trials. This lipids-based physiologic review will explain precisely why there should have never been expectation for success. This review will focus on underpublicized lipid science with a focus on physiology.

  18. Quenching tank: Accidental drowning in hot quenching oil.

    PubMed

    Mugadlimath, Anand B; Sane, Mandar Ramchandra; Zine, Kailash U; Hiremath, Rekha M

    2017-06-01

    We describe an unusual case of drowning in fluid other than water in an industrial setting. A 26-year-old man was working in an industry which performs surface treatment of mechanical steel parts with quenching oil. He fell into the quenching oil (which was hot due to immersion of red hot metal parts), and as he was working alone in the particular section, there was a fatal outcome. A medico-legal autopsy was performed. The causes of death were found to be multiple, with the association of drowning, extensive superficial burns and asphyxia due to laryngeal oedema. To our knowledge, it is the first report of drowning in hot quenching oil, and only nine previous observations of drowning in industrial environments have been reported in the international literature. Even though rare, these kinds of accidental deaths can be prevented in dangerous industries with proper precautions and strict adherence to standard operating procedures.

  19. In vitro activity of ten essential oils against Sarcoptes scabiei.

    PubMed

    Fang, Fang; Candy, Kerdalidec; Melloul, Elise; Bernigaud, Charlotte; Chai, Ling; Darmon, Céline; Durand, Rémy; Botterel, Françoise; Chosidow, Olivier; Izri, Arezki; Huang, Weiyi; Guillot, Jacques

    2016-11-22

    The development of alternative approaches in ectoparasite management is currently required. Essential oils have been demonstrated to exhibit fumigant and topical toxicity to a number of arthropods. The aim of the present study was to assess the potential efficacy of ten essential oils against Sarcoptes scabiei. The major chemical components of the oils were identified by GC-MS analysis. Contact and fumigation bioassays were performed on Sarcoptes mites collected from experimentally infected pigs. For contact bioassays, essential oils were diluted with paraffin to get concentrations at 10, 5, and even 1% for the most efficient ones. The mites were inspected under a stereomicroscope 10, 20, 30, 40, 50, 60, 90, 120, 150, and 180min after contact. For fumigation bioassay, a filter paper was treated with 100 μL of the pure essential oil. The mites were inspected under a stereomicroscope for the first 5min, and then every 5min until 1h. Using contact bioassays, 1% clove and palmarosa oil killed all the mites within 20 and 50min, respectively. The oils efficacy order was: clove > palmarosa > geranium > tea tree > lavender > manuka > bitter orange > eucalyptus > Japanese cedar. In fumigation bioassays, the efficacy order was: tea tree > clove > eucalyptus > lavender > palmarosa > geranium > Japanese cedar > bitter orange > manuka. In both bioassays, cade oil showed no activity. Essential oils, especially tea tree, clove, palmarosa, and eucalyptus oils, are potential complementary or alternative products to treat S. scabiei infections in humans or animals, as well as to control the mites in the environment.

  20. Oil Biodegradation and Bioremediation: A Tale of the Two Worst Spills in U.S. History

    PubMed Central

    2011-01-01

    The devastating environmental impacts of the Exxon Valdez spill in 1989 and its media notoriety made it a frequent comparison to the BP Deepwater Horizon spill in the popular press in 2010, even though the nature of the two spills and the environments impacted were vastly different. Fortunately, unlike higher organisms that are adversely impacted by oil spills, microorganisms are able to consume petroleum hydrocarbons. These oil degrading indigenous microorganisms played a significant role in reducing the overall environmental impact of both the Exxon Valdez and BP Deepwater Horizon oil spills. PMID:21699212

  1. Oil biodegradation and bioremediation: a tale of the two worst spills in U.S. history.

    PubMed

    Atlas, Ronald M; Hazen, Terry C

    2011-08-15

    The devastating environmental impacts of the Exxon Valdez spill in 1989 and its media notoriety made it a frequent comparison to the BP Deepwater Horizon spill in the popular press in 2010, even though the nature of the two spills and the environments impacted were vastly different. Fortunately, unlike higher organisms that are adversely impacted by oil spills, microorganisms are able to consume petroleum hydrocarbons. These oil degrading indigenous microorganisms played a significant role in reducing the overall environmental impact of both the Exxon Valdez and BP Deepwater Horizon oil spills.

  2. Essential Oil Extraction, Chemical Analysis and Anti-Candida Activity of Calamintha nepeta (L.) Savi subsp. glandulosa (Req.) Ball-New Approaches.

    PubMed

    Božović, Mijat; Garzoli, Stefania; Sabatino, Manuela; Pepi, Federico; Baldisserotto, Anna; Andreotti, Elisa; Romagnoli, Carlo; Mai, Antonello; Manfredini, Stefano; Ragno, Rino

    2017-01-26

    A comprehensive study on essential oils extracted from different Calamintha nepeta (L.) Savi subsp. glandulosa (Req.) Ball samples from Tarquinia (Italy) is reported. In this study, the 24-h steam distillation procedure for essential oil preparation, in terms of different harvesting and extraction times, was applied. The Gas chromatography-mass spectrometry (GC/MS) analysis showed that C. nepeta (L.) Savi subsp. glandulosa (Req.) Ball essential oils from Tarquinia belong to the pulegone-rich chemotype. The analysis of 44 samples revealed that along with pulegone, some other chemicals may participate in exerting the related antifungal activity. The results indicated that for higher activity, the essential oils should be produced with at least a 6-h steam distillation process. Even though it is not so dependent on the period of harvesting, it could be recommended not to harvest the plant in the fruiting stage, since no significant antifungal effect was shown. The maximum essential oil yield was obtained in August, with the highest pulegone percentage. To obtain the oil with a higher content of menthone, September and October should be considered as the optimal periods. Regarding the extraction duration, vegetative stage material gives the oil in the first 3 h, while material from the reproductive phase should be extracted at least at 6 or even 12 h.

  3. Emissions of Jatropha oil-derived biodiesel blend fuels during combustion in a swirl burner

    NASA Astrophysics Data System (ADS)

    Norwazan, A. R.; Mohd. Jaafar, M. N.; Sapee, S.; Farouk, Hazir

    2018-03-01

    Experimental works on combustion of jatropha oil biodiesel blends of fuel with high swirling flow in swirl burner have been studied in various blends percentage. Jatropha oil biodiesel was produced using a two-step of esterification-transesterification process. The paper focuses on the emissions of biodiesel blends fuel using jatropha oil in lean through to rich air/fuel mixture combustion in swirl burner. The emissions performances were evaluated by using axial swirler amongst jatropha oil blends fuel including diesel fuel as baseline. The results show that the B25 has good emissions even though it has a higher emission of NOx than diesel fuel, while it emits as low as 42% of CO, 33% of SO2 and 50% of UHC emissions with high swirl number. These are due to the higher oxygen content in jatropha oil biodiesel.

  4. 21 CFR 172.861 - Cocoa butter substitute from coconut oil, palm kernel oil, or both oils.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 3 2013-04-01 2013-04-01 false Cocoa butter substitute from coconut oil, palm... substitute from coconut oil, palm kernel oil, or both oils. The food additive, cocoa butter substitute from coconut oil, palm kernel oil, or both oils, may be safely used in food in accordance with the following...

  5. 21 CFR 172.861 - Cocoa butter substitute from coconut oil, palm kernel oil, or both oils.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 3 2012-04-01 2012-04-01 false Cocoa butter substitute from coconut oil, palm... substitute from coconut oil, palm kernel oil, or both oils. The food additive, cocoa butter substitute from coconut oil, palm kernel oil, or both oils, may be safely used in food in accordance with the following...

  6. 21 CFR 172.861 - Cocoa butter substitute from coconut oil, palm kernel oil, or both oils.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 3 2011-04-01 2011-04-01 false Cocoa butter substitute from coconut oil, palm... substitute from coconut oil, palm kernel oil, or both oils. The food additive, cocoa butter substitute from coconut oil, palm kernel oil, or both oils, may be safely used in food in accordance with the following...

  7. Essential oil-loaded lipid nanoparticles for wound healing

    PubMed Central

    Saporito, Francesca; Sandri, Giuseppina; Bonferoni, Maria Cristina; Rossi, Silvia; Boselli, Cinzia; Icaro Cornaglia, Antonia; Mannucci, Barbara; Grisoli, Pietro; Vigani, Barbara; Ferrari, Franca

    2018-01-01

    Chronic wounds and severe burns are diseases responsible for severe morbidity and even death. Wound repair is a crucial process and tissue regeneration enhancement and infection prevention are key factors to minimize pain, discomfort, and scar formation. The aim of this work was the development of lipid nanoparticles (solid lipid nanoparticles and nanostructured lipid carriers [NLC]), to be loaded with eucalyptus or rosemary essential oils and to be used, as medical devices, to enhance healing of skin wounds. Lipid nanoparticles were based on natural lipids: cocoa butter, as solid lipid, and olive oil or sesame oil, as liquid lipids. Lecithin was chosen as surfactant to stabilize nanoparticles and to prevent their aggregation. The systems were prepared by high shear homogenization followed by ultrasound application. Nanoparticles were characterized for physical–chemical properties, bioadhesion, cytocompatibility, in vitro proliferation enhancement, and wound healing properties toward normal human dermal fibroblasts. Antimicrobial activity of nanoparticles was evaluated against two reference microbial strains, one of Staphylococcus aureus, the other of Streptococcus pyogenes. Finally, the capability of nanoparticles to promote wound healing in vivo was evaluated on a rat burn model. NLC based on olive oil and loaded with eucalyptus oil showed appropriate physical–chemical properties, good bioadhesion, cytocompatibility, in vitro proliferation enhancement, and wound healing properties toward fibroblasts, associated to antimicrobial properties. Moreover, the in vivo results evidenced the capability of these NLC to enhance the healing process. Olive oil, which is characterized by a high content of oleic acid, proved to exert a synergic effect with eucalyptus oil with respect to antimicrobial activity and wound repair promotion. PMID:29343956

  8. Parylene-on-oil packaging for long-term implantable pressure sensors.

    PubMed

    Shapero, Aubrey M; Liu, Yang; Tai, Yu-Chong

    2016-08-01

    This paper reports and analyzes the feasibility study of a parylene-on-oil encapsulation packaging method of pressure sensors targeted for long-term implantation. Commercial barometric digital-output pressure sensors are enclosed in silicone oil and then encapsulated in situ with parylene-C or -D (PA-C, PA-D) chemical vapor deposition. Experimentally, sensors encapsulated with 30,000 cSt silicone oil and 27 μm PA-D show good performance for 6 weeks in 77 °C saline with >99 % of original sensitivity, corresponding to an extrapolated lifetime of around 21 months in 37 °C saline. This work shows that, with proper designs, such a packaging method can preserve the original pressure sensor sensitivity without offset, validated throughout accelerated lifetime tests. In experiments, wires on the prototypes are used for external electronics but it is found that they contributed to early failures, which would be absent in real wireless versions, indicating a potential for even longer lifetimes. Finally, a verified model is presented to predict the pressure sensor sensitivity of parylene-on-oil packaging with and without the presence of a bubble in the oil.

  9. Study on the engine oil's wear based on the flash point

    NASA Astrophysics Data System (ADS)

    Niculescu, R.; Iorga-Simăn, V.; Trică, A.; Clenci, A.

    2016-08-01

    Increasing energy performance of internal combustion engines is largely influenced by frictional forces that arise between moving parts. Thus, in this respect, the nature and quality of the engine oil used is an important factor. Equally important is the effect of various engine injection strategies upon the oil quality. In other words, it's of utmost importance to maintain the quality of engine oil during engine's operation. Oil dilution is one of the most common causes that lead to its wear, creating lubrication problems. Moreover, at low temperatures operating conditions, the oil dilution with diesel fuel produces wax. When starting the engine, this may lead to lubrication deficiencies and even oil starvation with negative consequences on the engine mechanism parts wear (piston, rings and cylinders) but also crankcase bearings wear.Engine oil dilution with diesel fuel have several causes: wear of rings and/or injectors, late post-injection strategy for the sake of particulate filter regeneration, etc.This paper presents a study on the degree of deterioration of engine oils as a result of dilution with diesel fuel. The analysed oils used for this study were taken from various models of engines equipped with diesel particulate filter. The assessment is based on the determination of oil flash point and dilution degree using the apparatus Eraflash produced by Eralytics, Austria. Eraflash measurement is directly under the latest and safest standards ASTM D6450 & D7094), which are in excellent correlation with ASTM D93 Pensky - Martens ASTM D56 TAG methods; it uses the Continuous Closed Cup method for finding the Flash Point (CCCFP).

  10. Automatic Measuring System for Oil Stream Paraffin Deposits Parameters

    NASA Astrophysics Data System (ADS)

    Kopteva, A. V.; Koptev, V. Yu

    2018-03-01

    This paper describes a new method for monitoring oil pipelines, as well as a highly efficient and automated paraffin deposit monitoring method. When operating oil pipelines, there is an issue of paraffin, resin and salt deposits on the pipeline walls that come with the oil stream. It ultimately results in frequent transportation suspension to clean or even replace pipes and other equipment, thus shortening operation periods between repairs, creating emergency situations and increasing production expenses, badly affecting environment, damaging ecology and spoil underground water, killing animals, birds etc. Oil spills contaminate rivers, lakes, and ground waters. Oil transportation monitoring issues are still subject for further studying. Thus, there is the need to invent a radically new automated process control and management system, together with measurement means intellectualization. The measurement principle is based on the Lambert-Beer law that describes the dependence between the gamma-radiation frequency and the density together with the linear attenuation coefficient for a substance. Using the measuring system with high accuracy (± 0,2%), one can measure the thickness of paraffin deposits with an absolute accuracy of ± 5 mm, which is sufficient to ensure reliable operation of the pipeline system. Safety is a key advantage, when using the proposed control system.

  11. Oil/gas collector/separator for underwater oil leaks

    DOEpatents

    Henning, Carl D.

    1993-01-01

    An oil/gas collector/separator for recovery of oil leaking, for example, from an offshore or underwater oil well. The separator is floated over the point of the leak and tethered in place so as to receive oil/gas floating, or forced under pressure, toward the water surface from either a broken or leaking oil well casing, line, or sunken ship. The separator is provided with a downwardly extending skirt to contain the oil/gas which floats or is forced upward into a dome wherein the gas is separated from the oil/water, with the gas being flared (burned) at the top of the dome, and the oil is separated from water and pumped to a point of use. Since the density of oil is less than that of water it can be easily separated from any water entering the dome.

  12. National Evaluation of the Even Start Family Literacy Program: Report on Migrant Even Start Projects.

    ERIC Educational Resources Information Center

    Levin, Marjorie; Gamse, Beth; Swartz, Janet; Tao, Fumiyo; Tarr, Hope

    In fall 1994, 14 state Migrant Education Programs were receiving direct federal grants to administer Migrant Even Start projects. These projects provide migrant families with an integrated program of early childhood education, adult education, and parenting education. As part of the national evaluation of the Even Start Family Literacy Program,…

  13. Acute aquatic toxicity of western juniper (Juniperus occidentalis) foliage and Port Orford cedar (Chamaecyparis lawsoniana) heartwood oils.

    PubMed

    Duringer, Jennifer M; Swan, Laurence R; Walker, Douglas B; Craig, A Morrie

    2010-11-01

    Recently, interest has developed for using essential oils from Western juniper (Juniperus occidentalis) foliage and Port Orford cedar (Chamaecyparis lawsoniana) heartwood in commercial products such as pest repellents and cosmetics. In order to gauge the relative toxicological risk that these oils pose to freshwater and marine organisms, the acute aquatic toxicity of these oils was evaluated using OPPTS guidelines to the cladoceran Daphnia magna, the rainbow trout Oncorhynchus mykiss and the green alga Selenastrum capricornutum. For western juniper foliage oil, no toxicity was exhibited toward D. magna or O. mykiss, even at 5.0 mg/L (the highest concentration tested and limit of solubility). For toxicity to S. capricornutum using algal cell density, the 72 and 96 h EC50 value was 1.7 mg/L and the no observable effect concentration (NOEC) was 0.63 mg/L. For Port Orford cedar heartwood oil, no toxicity was exhibited toward O. mykiss or S. capricornutum, even at 5.0 mg/L (the highest concentration tested and limit of solubility). The 48-h D. magna EC50 value was 1.9 mg/L; the NOEC values for algal cell density were 1.25 mg/L (72 h) and 0.63 mg/L (96 h). In summary, this study shows that western juniper foliage and Port Orford cedar heartwood oils demonstrate little to no risk to aquatic organisms.

  14. Effects of used lubricating oil on two mangroves Aegiceras corniculatum and Avicennia marina.

    PubMed

    Ye, Yong; Tam, N F Y

    2007-01-01

    An outdoor experiment was set up to investigate the effects of used lubricating oil (5 L/m2) on Aegiceras corniculatum Blanco. and Avicennia marina (Forsk) Vierh., two salt-excreting mangroves. A. marina was more sensitive to used lubricating oil than A. corniculatum and canopy-oiling resulted in more direct physical damage and stronger lethal effects than base-oiling. When treated with canopy-oiling, half of A. corniculatum plants survived for the whole treatment time (90 d); but, for A. marina, high mortality (83%) resulted from canopy-oiling within 3 weeks and no plants survived for 80 d. Base-oiling had no lethal effects onA. corniculatum plants even at the termination of this experiment, but 83% of A. marina plants died 80 d after treatment. Forty days after canopy-oiling, 93% of A. corniculatum leaves fell and no live leaves remained on A. marina plants. By the end of the experiment, base-oiling treatment resulted in about 45% of A. corniculatum leaves falling, while all A. marina leaves and buds were burned to die. Lubricating oil resulted in physiological damage to A. corniculatum leaves, including decreases in chlorophyll and carotenoid contents, nitrate reductase, peroxidase and superoxide dismutase activities, and increases in malonaldehyde contents. For both species, oil pollution significantly reduced leaf, root, and total biomass, but did not significantly affect stem biomass. Oil pollution resulted in damage to the xylem vessels of fine roots but not to those of mediate roots.

  15. Environmental consequences of oil production from oil sands

    NASA Astrophysics Data System (ADS)

    Rosa, Lorenzo; Davis, Kyle F.; Rulli, Maria C.; D'Odorico, Paolo

    2017-02-01

    Crude oil from oil sands will constitute a substantial share of future global oil demand. Oil sands deposits account for a third of globally proven oil reserves, underlie large natural forested areas, and have extraction methods requiring large volumes of freshwater. Yet little work has been done to quantify some of the main environmental impacts of oil sands operations. Here we examine forest loss and water use for the world's major oil sands deposits. We calculate actual and potential rates of water use and forest loss both in Canadian deposits, where oil sands extraction is already taking place, and in other major deposits worldwide. We estimated that their exploitation, given projected production trends, could result in 1.31 km3 yr-1 of freshwater demand and 8700 km2 of forest loss. The expected escalation in oil sands extraction thus portends extensive environmental impacts.

  16. Light oiling of feathers increases flight energy expenditure in a migratory shorebird.

    PubMed

    Maggini, Ivan; Kennedy, Lisa V; Macmillan, Alexander; Elliott, Kyle H; Dean, Karen; Guglielmo, Christopher G

    2017-07-01

    Flying birds depend on their feathers to undertake most activities, and maintain them in peak condition through periodic molt and frequent preening. Even small exposures to crude oil reduce the integrity of feathers, and could impair flight performance. We trained wild western sandpipers ( Calidris mauri ) to perform endurance flights in a wind tunnel, and used magnetic resonance body composition analysis to measure energy expenditure after birds were exposed to weathered MC252 crude oil from the Deepwater Horizon oil spill. The cost of transport was 0.26±0.04 kJ km -1 in controls, and increased by 22% when the trailing edges of the wing and tail were oiled (<20% of body surface; considered light oiling). Additional crude oil on breast and back feathers (∼30% total surface; moderate oiling) increased the cost of transport by 45% above controls. Oiling tended to decrease flight control, and only half of moderately oiled birds completed the flight test. We then flew birds at a range of speeds to estimate basic kinematic parameters. At low speeds, light and moderately oiled birds had larger wingbeat amplitudes than controls, while moderately oiled birds showed greater wingbeat frequencies across all speeds, and a shift in optimal flight speed towards higher wind speeds. We suggest these changes reflect poorer lift production and increased drag on the wings and body. Oiling will increase the difficulty and energy costs of locomotion for daily and seasonal activities such as foraging, predator evasion, territory defense, courtship, chick provisioning, commuting and long-distance migration. These sub-lethal effects must be considered in oil spill impact assessments. © 2017. Published by The Company of Biologists Ltd.

  17. 27 CFR 21.98 - Bone oil (Dipple's oil).

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2013-04-01 2013-04-01 false Bone oil (Dipple's oil....98 Bone oil (Dipple's oil). (a) Color. The color shall be a deep brown. (b) Distillation range. When... below 90 °C. (c) Pyrrol reaction. Prepare a 1.0 percent solution of bone oil in 95 percent alcohol...

  18. 27 CFR 21.98 - Bone oil (Dipple's oil).

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2011-04-01 2011-04-01 false Bone oil (Dipple's oil....98 Bone oil (Dipple's oil). (a) Color. The color shall be a deep brown. (b) Distillation range. When... below 90 °C. (c) Pyrrol reaction. Prepare a 1.0 percent solution of bone oil in 95 percent alcohol...

  19. 27 CFR 21.98 - Bone oil (Dipple's oil).

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2014-04-01 2014-04-01 false Bone oil (Dipple's oil....98 Bone oil (Dipple's oil). (a) Color. The color shall be a deep brown. (b) Distillation range. When... below 90 °C. (c) Pyrrol reaction. Prepare a 1.0 percent solution of bone oil in 95 percent alcohol...

  20. 27 CFR 21.98 - Bone oil (Dipple's oil).

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 27 Alcohol, Tobacco Products and Firearms 1 2012-04-01 2012-04-01 false Bone oil (Dipple's oil....98 Bone oil (Dipple's oil). (a) Color. The color shall be a deep brown. (b) Distillation range. When... below 90 °C. (c) Pyrrol reaction. Prepare a 1.0 percent solution of bone oil in 95 percent alcohol...

  1. 21 CFR 172.861 - Cocoa butter substitute from coconut oil, palm kernel oil, or both oils.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 3 2014-04-01 2014-04-01 false Cocoa butter substitute from coconut oil, palm... HUMAN CONSUMPTION Multipurpose Additives § 172.861 Cocoa butter substitute from coconut oil, palm kernel oil, or both oils. The food additive, cocoa butter substitute from coconut oil, palm kernel oil, or...

  2. Anxiolytic effects of lavender oil inhalation on open-field behaviour in rats.

    PubMed

    Shaw, D; Annett, J M; Doherty, B; Leslie, J C

    2007-09-01

    To establish a valid animal model of the effects of olfactory stimuli on anxiety, a series of experiments was conducted using rats in an open-field test. Throughout, effects of lavender oil were compared with the effects of chlordiazepoxide (CDP), as a reference anxiolytic with well-known effects on open-field behaviour. Rats were exposed to lavender oil (0.1-1.0 ml) for 30 min (Experiment 1) or 1h (Experiment 2) prior to open-field test and in the open field or injected with CDP (10 mg/kg i.p.). CDP had predicted effects on behaviour, and the higher doses of lavender oil had some effects on behaviour similar to those of CDP. In Experiment 3, various combinations of pre-exposure times and amounts of lavender oil were used. With sufficient exposure time and quantity of lavender the same effects were obtained as in Experiment 2. Experiment 4 demonstrated that these behavioural effects of lavender could be obtained following pre-exposure, even if no oil was present in the open-field test. In Experiments 2-4, lavender oil increased immobility. Together, these experiments suggest that lavender oil does have anxiolytic effects in the open field, but that a sedative effect can also occur at the highest doses.

  3. Carbon Nano Tube Composites with Chemically Functionalized Plant Oils

    NASA Astrophysics Data System (ADS)

    Thielemans, Wim; Wool, Richard P.; Blau, Werner; Barron, Valerie

    2003-03-01

    Carbon Nano Tube Composites with Chemically Functionalized Plant Oil Wim Thielemans, R., P. Wool, V. Barron and W. Blau Multi-Wall Carbon Nano Tubes (MWCNT) made by the Kratchmer-Huffman CCVD process were found to interact and solubilize by slow mechanical stirring, with chemically functionalized plant oils, such as acrylated, epoxidized and maleinated triglycerides (TG) derived from plant oils. The chemical functionality on the TG imparted amphiphilic properties to the oils which allows them to self-assemble on the nanotubes, promoting both dissolution and the ability to make nanocomposites with unusual properties. Once in solution, the MWCT can be processed in a variety of methods, in particular to make composites with enhanced mechanical, fracture and thermal properties. Since the tensile modulus of MWs is about 1 TPa and a vector percolation analysis indicated tensile strengths of 50-100 GPa, we obtain significantly improved properties with even small amounts (1-3the glass transition temperature of the composite by about 20 oC, and the tensile modulus by about 11significant effects on the fracture stress can be obtained due to the both the influence of the strength and length of the MWNT at the crack tip. The ability of the oils to self-assemble on the carbon nanotube surfaces also makes them ideal candidates for self-healing materials. The properties with different functionalized oils will be reported. Supported by EPA, DoE and ISF

  4. Why Fish Oil Fails: A Comprehensive 21st Century Lipids-Based Physiologic Analysis

    PubMed Central

    Peskin, B. S.

    2014-01-01

    The medical community suffered three significant fish oil failures/setbacks in 2013. Claims that fish oil's EPA/DHA would stop the progression of heart disease were crushed when The Risk and Prevention Study Collaborative Group (Italy) released a conclusive negative finding regarding fish oil for those patients with high risk factors but no previous myocardial infarction. Fish oil failed in all measures of CVD prevention—both primary and secondary. Another major 2013 setback occurred when fish oil's DHA was shown to significantly increase prostate cancer in men, in particular, high-grade prostate cancer, in the Selenium and Vitamin E Cancer Prevention Trial (SELECT) analysis by Brasky et al. Another monumental failure occurred in 2013 whereby fish oil's EPA/DHA failed to improve macular degeneration. In 2010, fish oil's EPA/DHA failed to help Alzheimer's victims, even those with low DHA levels. These are by no means isolated failures. The promise of fish oil and its so-called active ingredients EPA / DHA fails time and time again in clinical trials. This lipids-based physiologic review will explain precisely why there should have never been expectation for success. This review will focus on underpublicized lipid science with a focus on physiology. PMID:24551453

  5. Genetic types of oils in the petroliferous basins of Cuba

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Maksimov, S.P.; Botneva, T.A.; Pankina, R.G.

    Two oil- and gas basins, the North Cuban and the Central Cuban, have been discovered in Cuba and the nearby offshore areas. The North Cuban basin developed as a result of a complete cycle of inter-plate geodynamic evolution (divergence-convergence-isostatic adjustment of the plates), and the South Cuban basin formed during the phase of convergence and isostatic adjustment of the plates. The hydrocarbon deposits discovered in the North Cuban basin are marked by their exceptional variety, and include deposits of light and heavy oils, and even asphalt. The geological conditions of their occurrence are also varied. In this paper the authorsmore » present the results of a study of the oils and a discussion of their association with the source beds. For Cuba the solution of these problems is of special importance owing to the complexity of its geological structure and, in particular, the presence of oil deposits of varied composition in the overthrust complexes of the eugeosynclinal and miogeosynclinal allochthon and para-autochthon, as well as in the sediments of the autochthonous complex. 4 references.« less

  6. [Identification of automotive lubricants and other heavy oils by isotachophoresis].

    PubMed

    Ishizawa, F; Misawa, S

    1989-06-01

    Automotive lubricants were analysed by isotachophoresis for the purpose of identification of lubricants and suspected stains adhered to victims in traffic accidents. As the results, it was found that each lubricant showed a characteristic isotachophreogram even if they were manufactured by the same maker, and that the isotachopherogram of the lubricant changed in proportion to the running distance of an automobile. Each lubricant had its own changing rate. Moreover, A, B, C heavy oils, asphalt, soy sauce and sauce, which apparently resembled lubricants when they adhered to victims, were analysed with this method. They were found to be clearly different from lubricants in isotachopherogram and they could be discriminated from lubricants. Therefore, it was found that lubricants could be easily identified or discriminated from other lubricants such as engine oils, gear oils and other oils by comparing their isotachopherograms obtained with this method in a short time. It was, however, difficult to suggest the maker of a lubricant from isotachopherogram. We conclude from these observations that isotachophoresis method is useful for the analysis of lubricants in case of traffic accidents.

  7. Environmental liability and the onshore oil and gas prospector

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Jacobs, J.A.; Davis, P.

    Environmental liability can be transferred to the oil or gas prospector along with the conveyance of an oil or gas lease. Should soil or groundwater contamination be discovered on a lease, an innocent owner or operator could be liable under state and federal environmental laws for court-ordered remediation costs if potentially responsible parties were unavailable or insolvent. Potential environmental liabilities can be minimized, however, by a preconveyance survey. Existing storage tanks, wells, pipelines, and other anthropogenic features on site should be inspected and photographically documented, as should evidence of previous spills or leaks such as discolored soil and distressed vegetation.more » Land use and ownership history can be documented from historical maps, aerial photographs, tax records, and even interviews with knowledgeable sources. Contaminated groundwater from offsite sources even miles away may migrate onto potential drill sites. Offsite reconnaissance and a review of the Environmental Protection Agency, state, and local environmental agency lists of contaminated sites in the area of the prospective lease provide information to help the potential lessee evaluate this risk. The cost to research and document potential environmental problems on or in the vicinity of a lease is a fraction of the cost required to develop an oil or gas prospect. Performing a preconveyance environmental survey may be the best way to minimize environmental liability and subsequent costs of cleanup and damages in court-ordered remediation.« less

  8. Evaluation of airfield pavement evenness

    NASA Astrophysics Data System (ADS)

    Pietruszewski, Paweł; Poświata, Adam; Wesołowski, Mariusz

    2018-05-01

    The evenness of airfield pavements is one of the basic operating parameters, which characterize them. The evenness determines not only comfort of traffic along an airfield pavement, but also influences the size of dynamic effect on the pavement, hence, the safety of air operations. In addition, the evenness condition changing as a result of dynamic loads, adverse weather conditions or inappropriate airfield pavement construction technology, lead to deviations from the desired condition in the form of longitudinal and transverse unevenness. As a result, systematic and correct performance of tests is a very significant and required factor impacting the improvement of traffic safety on airfield pavements. If the data obtained through the measurements are not sufficiently reliable, they may consequently lead to making incorrect decisions, which can ultimately impact the safety of air operations.

  9. Practical Considerations and Challenges Involved in Surfactant Enhanced Bioremediation of Oil

    PubMed Central

    Mohanty, Sagarika; Jasmine, Jublee

    2013-01-01

    Surfactant enhanced bioremediation (SEB) of oil is an approach adopted to overcome the bioavailability constraints encountered in biotransformation of nonaqueous phase liquid (NAPL) pollutants. Fuel oils contain n-alkanes and other aliphatic hydrocarbons, monoaromatics, and polynuclear aromatic hydrocarbons (PAHs). Although hydrocarbon degrading cultures are abundant in nature, complete biodegradation of oil is rarely achieved even under favorable environmental conditions due to the structural complexity of oil and culture specificities. Moreover, the interaction among cultures in a consortium, substrate interaction effects during the degradation and ability of specific cultures to alter the bioavailability of oil invariably affect the process. Although SEB has the potential to increase the degradation rate of oil and its constituents, there are numerous challenges in the successful application of this technology. Success is dependent on the choice of appropriate surfactant type and dose since the surfactant-hydrocarbon-microorganism interaction may be unique to each scenario. Surfactants not only enhance the uptake of constituents through micellar solubilization and emulsification but can also alter microbial cell surface characteristics. Moreover, hydrocarbons partitioned in micelles may not be readily bioavailable depending on the microorganism-surfactant interactions. Surfactant toxicity and inherent biodegradability of surfactants may pose additional challenges as discussed in this review. PMID:24350261

  10. Distribution and quantitative assessment of world crude oil reserves and resources

    USGS Publications Warehouse

    Masters, Charles D.; Root, David H.; Dietzman, William D.

    1983-01-01

    World Demonstrated Reserves of crude oil are approximately 723 billion barrels of oil (BBO). Cumulative production is 445 BBO and annual production is 20 BBO. Demonstrated Reserves of crude-oil have declined over the past 10 years consistent with discoveries lagging production over the same period. The assessment of Undiscovered Resources shows a 90 percent probability that the amount discoverable lies between 321 and 1,417 BBO, 550 BBO being the most likely value. The most likely value for Ultimate recoverable resources is 1,718 BBO. The distribution of Ultimate Resources of crude oil will remain highly skewed toward the Middle East; no frontier areas that have potentials large enough to significantly affect present distribution are recognized. Rates of discovery have continued to decline over the past 20 years even though exploration activity has increased in recent years. Prudence dictates, therefore, that the low side of the assessment of Undiscovered Resources be responsibly considered and that alternate energy sources be a part of future planning. Extra-heavy oil and bitumen are assessed separately, with Reserves being figured as the annual productive capacity of installed facilities times 25 years. The annual production of extra-heavy oil is about 8 million barrels and of bitumen about 60 million barrels.

  11. Liquefaction of lignocellulosic biomass: solvent, process parameter, and recycle oil screening.

    PubMed

    van Rossum, Guus; Zhao, Wei; Castellvi Barnes, Maria; Lange, Jean-Paul; Kersten, Sascha R A

    2014-01-01

    The liquefaction of lignocellulosic biomass is studied for the production of liquid (transportation) fuels. The process concept uses a product recycle as a liquefaction medium and produces a bio-oil that can be co-processed in a conventional oil refinery. This all is done at medium temperature (≈ 300 °C) and pressure (≈ 60 bar). Solvent-screening experiments showed that oxygenated solvents are preferred as they allow high oil (up to 93% on carbon basis) and low solid yields (≈ 1-2% on carbon basis) and thereby outperform the liquefaction of biomass in compressed water and biomass pyrolysis. The following solvent ranking was obtained: guaiacol>hexanoic acid ≫ n-undecane. The use of wet biomass results in higher oil yields than dry biomass. However, it also results in a higher operating pressure, which would make the process more expensive. Refill experiments were also performed to evaluate the possibility to recycle the oil as the liquefaction medium. The recycled oil appeared to be very effective to liquefy the biomass and even surpassed the start-up solvent guaiacol, but became increasingly heavy and more viscous after each refill and eventually showed a molecular weight distribution that resembles that of refinery vacuum residue. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Comparison of phytochemical profiles and health benefits in fiber and oil flaxseeds (Linum usitatissimum L.).

    PubMed

    Wang, Hong; Wang, Junhong; Qiu, Caisheng; Ye, Yutong; Guo, Xinbo; Chen, Gu; Li, Tong; Wang, Yufu; Fu, Xiong; Liu, Rui Hai

    2017-01-01

    Flaxseed (Linum usitatissimum L.) is a rich source of nutritive and bioactive compounds. The research evaluated the disparity in phytochemical profiles along with total and cellular antioxidant activities between oil and fiber flaxseeds. There were significant differences in total phenolics, total flavonoids and antioxidant activities among the six cultivars of fiber and oil flaxseed, respectively. Four phytochemical compounds including caffeic acid, p-coumaric acid and ferulic acid, and secoisolariciresinol diglucoside (SDG) were identified and quantified in the cultivars of oil and fiber flaxseed by HPLC analysis. Notably, the average of total phenolic and flavonoid contents, along with total antioxidant activities between fiber and oil flaxseeds were not different significantly; even the cellular antioxidant activity of fiber flaxseed was superior to oil flaxseed. These results suggest that fiber flaxseeds would be valuable candidates as functional products and dietary supplements production owing to the higher bioactive values as well as oil flaxseeds. Copyright © 2016 Elsevier Ltd. All rights reserved.

  13. Heat Transfer from a Horizontal Cylinder Rotating in Oil

    NASA Technical Reports Server (NTRS)

    Seban, R. A.; Johnson, H. A.

    1959-01-01

    Measurements of the heat transfer from a horizontal cylinder rotating about its axis have been made with oil as the surrounding fluid to provide an addition to the heat-transfer results for this system heretofore available only for air. The results embrace a Prandtl number range from about 130 to 660, with Reynolds numbers up to 3 x 10(exp 4), and show an increasing dependence of free-convection heat transfer on rotation as the Prandtl number is increased by reducing the oil temperature. Some correlation of this effect, which agrees with the prior results for air, has been achieved. At higher rotative speeds the flow becomes turbulent, the free- convection effect vanishes, and the results with oil can be correlated generally with those for air and with mass-transfer results for even higher Prandtl numbers. For this system, however, the analogy calculations which have successfully related the heat transfer to the friction for pipe flows at high Prandtl numbers fail.

  14. Pressure deflected: Japan and the 1973 Arab oil embargo

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Burridge, J.M.

    1988-01-01

    Japanese policy toward the Arab states for the five years before the embargo are compared with the five years that followed. Significant events from October 1973 through the February 1974 Washington Conference are described on a virtually daily basis. The study concludes that the late 1973 oil-supply reduction did not result in significantly greater Japanese political support or economic assistance in the 1974-1978 period. Japan did not even carry the only specific commitment in the November 22 statement - that it would reconsider relations with Israel if that country didn't withdraw from the occupied Arab territories. Many factors contributed tomore » this failure - American counter-pressure, Arab disunity, and a worldwide drop in oil demand. In terms of political demands, neither OAPEC nor any individual Arab state ever articulated any specific actions Japan was to take. Finally, the supply of oil was rapidly depoliticized after 1974.« less

  15. Lupus erythematosus and nutrition: a review of the literature.

    PubMed

    Brown, A C

    2000-10-01

    The purpose of this review was to search the scientific literature for dietary compounds that alleviate or exacerbate symptoms of lupus erythematosus (LE) in both animal and human models. A detailed literature review was undertaken to find articles showing a relationship between LE and nutrition by using MEDLINE/INDEX MEDICUS (1950-March 2000) for English-language articles, followed by cross-referencing. Aggravating substances appear to include excess calories, excess protein, high fat (especially saturated and omega-6 polyunsaturated fatty acids), zinc, iron, and L-canavanine found in alfalfa tablets. Possible beneficial dietary compounds include vitamin E, vitamin A (beta-carotene), selenium, fish oils (omega-3 polyunsaturated fatty acids), evening primrose oil, flaxseed, a plant herb (Tripterygium wilfordii), dehydroepiandrosterone, and calcium plus vitamin D (if taking corticosteroids). Some people with systemic LE placed on food allergy elimination diets reported improvement in their LE symptoms; however, this may be related to a decrease of other substances in the diet. Also, although no direct evidence was reported on the beneficial effects of either bromelain or a vegetarian diet (possibly allowing fish), it is suggested that they might be beneficial. Limitations to this research are that the findings are based on relatively few studies, many of which were without control groups or extrapolated from animal models. No large-scale studies have been performed with LE patients to substantiate the benefit, if any, of these individual dietary interventions, and if they were conducted, the remission and exacerbation pattern of LE may interfere with elucidating their effectiveness. Also, dietary changes should not be attempted without a physician's approval/monitoring. Copyright 2000 by the National Kidney Foundation, Inc.

  16. Microfluidic acoustophoretic force based low-concentration oil separation and detection from the environment.

    PubMed

    Wang, Han; Liu, Zhongzheng; Kim, Sungman; Koo, Chiwan; Cho, Younghak; Jang, Dong-Young; Kim, Yong-Joe; Han, Arum

    2014-03-07

    Detecting and quantifying extremely low concentrations of oil from the environment have broad applications in oil spill monitoring in ocean and coastal areas as well as in oil leakage monitoring on land. Currently available methods for low-concentration oil detection are bulky or costly with limited sensitivities. Thus they are difficult to be used as portable and field-deployable detectors in the case of oil spills or for monitoring the long-term effects of dispersed oil on marine and coastal ecosystems. Here, we present a low-concentration oil droplet trapping and detection microfluidic system based on the acoustophoresis phenomenon where oil droplets in water having a negative acoustic contrast factor move towards acoustic pressure anti-nodes. By trapping oil droplets from water samples flowing through a microfluidic channel, even very low concentrations of oil droplets can be concentrated to a detectable level for further analyses, which is a significant improvement over currently available oil detection systems. Oil droplets in water were successfully trapped and accumulated in a circular acoustophoretic trapping chamber of the microfluidic device and detected using a custom-built compact fluorescent detector based on the natural fluorescence of the trapped crude oil droplets. After the on-line detection, crude oil droplets released from the trapping chamber were successfully separated into a collection outlet by acoustophoretic force for further off-chip analyses. The developed microfluidic system provides a new way of trapping, detecting, and separating low-concentration crude oil from environmental water samples and holds promise as a low-cost field-deployable oil detector with extremely high sensitivity. The microfluidic system and operation principle are expected to be utilized in a wide range of applications where separating, concentrating, and detecting small particles having a negative acoustic contrast factor are required.

  17. Biochemically enhanced oil recovery and oil treatment

    DOEpatents

    Premuzic, Eugene T.; Lin, Mow

    1994-01-01

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil.

  18. Thiolated silicone oil: Synthesis, gelling and mucoadhesive properties

    PubMed Central

    Partenhauser, Alexandra; Laffleur, Flavia; Rohrer, Julia; Bernkop-Schnürch, Andreas

    2015-01-01

    The aim of this study was the development of novel thiolated silicone oils and their evaluation with regard to gelling and mucoadhesive properties. A thiol coupling of 220 ± 14 and 127 ± 33 μmol/g polymer for 3-mercaptopropionic acid (MPA)- and cysteine-coupled silicone oil was determined, respectively. The dynamic viscosity of MPA–silicone raised significantly (p < 0.000001) after oxidation with iodine to a maximum of 523-fold within 1 h. During tensile studies, MPA–silicone showed both the highest results for total work of adhesion (TWA) and maximum detachment force (MDF) with a 3.8- and 3.4-fold increase, respectively, compared to the control. As far as the residence time on small intestinal mucosa is concerned, both silicone conjugates were detectable in almost the same quantities for up to 8 h with 56.9 ± 3.3 and 47.8 ± 8.9% of the initially applied conjugated silicone oil. Thiolated silicone oils can be regarded superior in comparison to commonly used silicone oils due to a prolonged retention time in the small intestine as site of action. Gelling and mucoadhesive features are advantageous for antiflatulent as well as mucoprotective biomaterials. Thus, these novel thiomers seem promising for an upgrade of currently available products for the treatment of dyspepsia, reflux oesophagitis and even inflammatory bowel diseases such as ulcerative colitis or Crohn’s disease. PMID:25660565

  19. Screening of biosurfactant-producing bacteria from offshore oil and gas platforms in North Atlantic Canada.

    PubMed

    Cai, Qinhong; Zhang, Baiyu; Chen, Bing; Song, Xing; Zhu, Zhiwen; Cao, Tong

    2015-05-01

    From offshore oil and gas platforms in North Atlantic Canada, crude oil, formation water, drilling mud, treated produced water and seawater samples were collected for screening potential biosurfactant producers. In total, 59 biosurfactant producers belong to 4 genera, namely, Bacillus, Rhodococcus, Halomonas, and Pseudomonas were identified and characterized. Phytogenetic trees based on 16S ribosomal deoxyribonucleic acid (16S rDNA) were constructed with isolated strains plus their closely related strains and isolated strains with biosurfactant producers in the literature, respectively. The distributions of the isolates were site and medium specific. The richness, diversity, and evenness of biosurfactant producer communities in oil and gas platform samples have been analyzed. Diverse isolates were found with featured properties such as effective reduction of surface tension, producing biosurfactants at high rate and stabilization of water-in-oil or oil-in-water emulsion. The producers and their corresponding biosurfactants had promising potential in applications such as offshore oil spill control, enhancing oil recovery and soil washing treatment of petroleum hydrocarbon-contaminated sites.

  20. Biochemically enhanced oil recovery and oil treatment

    DOEpatents

    Premuzic, E.T.; Lin, M.

    1994-03-29

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. 62 figures.

  1. Oil Fires and Oil Slick, Kuwait

    NASA Image and Video Library

    1991-05-06

    STS039-87-012 (28 April-6 May 1991) --- A handheld 70mm camera onboard the Space Shuttle Discovery exposed this infrared frame showing oil fires near the Kuwait coast as well as south-bound oil slicks in the Gulf. Pools of oil on the land are recognized as white objects near the burning wells.

  2. Probing the intrinsically oil-wet surfaces of pores in North Sea chalk at subpore resolution.

    PubMed

    Hassenkam, T; Skovbjerg, L L; Stipp, S L S

    2009-04-14

    Pore surface properties control oil recovery. This is especially true for chalk reservoirs, where pores are particularly small. Wettability, the tendency for a surface to cover itself with fluid, is traditionally defined by the angle a droplet makes with a surface, but this macroscopic definition is meaningless when the particles are smaller than even the smallest droplet. Understanding surface wetting, at the pore scale, will provide clues for more effective oil recovery. We used a special mode of atomic force microscopy and a hydrophobic tip to collect matrices of 10,000 force curves over 5- x 5-mum(2) areas on internal pore surfaces and constructed maps of topography, adhesion, and elasticity. We investigated chalk samples from a water-bearing formation in the Danish North Sea oil fields that had never seen oil. Wettability and elasticity were inhomogeneous over scales of 10s of nanometers, smaller than individual chalk particles. Some areas were soft and hydrophobic, whereas others showed no correlation between hardness and adhesion. We conclude that the macroscopic parameter, "wetting," averages the nanoscopic behavior along fluid pathways, and "mixed-wet" samples have patches with vastly different properties. Development of reservoir hydrophobicity has been attributed to infiltrating oil, but these new results prove that wettability and elasticity are inherent properties of chalk. Their variability, even on single particles, must result from material originally present during sedimentation or material sorbed from the pore fluid some time later.

  3. Probing the intrinsically oil-wet surfaces of pores in North Sea chalk at subpore resolution

    PubMed Central

    Hassenkam, T.; Skovbjerg, L. L.; Stipp, S. L. S.

    2009-01-01

    Pore surface properties control oil recovery. This is especially true for chalk reservoirs, where pores are particularly small. Wettability, the tendency for a surface to cover itself with fluid, is traditionally defined by the angle a droplet makes with a surface, but this macroscopic definition is meaningless when the particles are smaller than even the smallest droplet. Understanding surface wetting, at the pore scale, will provide clues for more effective oil recovery. We used a special mode of atomic force microscopy and a hydrophobic tip to collect matrices of 10,000 force curves over 5- × 5-μm2 areas on internal pore surfaces and constructed maps of topography, adhesion, and elasticity. We investigated chalk samples from a water-bearing formation in the Danish North Sea oil fields that had never seen oil. Wettability and elasticity were inhomogeneous over scales of 10s of nanometers, smaller than individual chalk particles. Some areas were soft and hydrophobic, whereas others showed no correlation between hardness and adhesion. We conclude that the macroscopic parameter, “wetting,” averages the nanoscopic behavior along fluid pathways, and “mixed-wet” samples have patches with vastly different properties. Development of reservoir hydrophobicity has been attributed to infiltrating oil, but these new results prove that wettability and elasticity are inherent properties of chalk. Their variability, even on single particles, must result from material originally present during sedimentation or material sorbed from the pore fluid some time later. PMID:19321418

  4. [Pain management with herbal antirheumatic drugs].

    PubMed

    Chrubasik, Sigrun; Pollak, S

    2002-01-01

    Herbal antirheumatics are indicated in painful inflammatory and degenerative rheumatic diseases. Their mechanism of action is broader than that of synthetic antirheumatics. Particular preparations from Devils's Claw with 50 to 100 mg of harpagoside in the daily dosage as well as a particular willow bark extract with 120 to 240 mg salicin in the daily dosage proved efficacy in a number of clinical studies including confirmatory ones. Exploratory studies indicate that these herbal antirheumatics were not inferior to the selective COX-2 inhibitor rofecoxib when treating acute exacerbations of chronic low back pain. For the proprietary nettle root extract IDS23 promising in vitro/in vivo results indicate an anti-inflammatory effect, however there are only 2 open uncontrolled clinical studies available and the proof of efficacy is still missing. Safety data in order to recommend use during pregnancy and lactation are only available for the herbal combination product Phytodolor prepared from aspen, ash and goldenrod. In principle, blackcurrent leaf with not less than 1.5% flavonoids may be an appropriate antirheumatic. Likewise, the seed oils of blackcurrent, evening primrose and borage offering at least 1 to 3 g gammalinolenic acid/day are recommendable. In case superiority versus placebo has been established, proprietary herbal antirheumatics should be administered before the conventional analgesics due to the lower incidence of adverse events.

  5. Drug-Herb Interactions in the Elderly Patient with IBD: a Growing Concern.

    PubMed

    Rahman, Haider; Kim, Marina; Leung, Galen; Green, Jesse A; Katz, Seymour

    2017-12-01

    Inflammatory bowel disease (IBD), which includes conditions such as Crohn's disease and ulcerative colitis, is becoming more prevalent with the elderly being the fastest growing group. Parallel to this, there is an increasing interest in the use of complementary and alternative medicine (CAM). Nearly half of patients with IBD have used CAM at one time. The elderly patients, however, are burdened by comorbid conditions, polypharmacy, and altered functional status. With increasing use of complementary and alternative medicine in our elderly patients with IBD, it is vital for the provider to provide counsel on drug-herb potential interactions. CAM includes herbal products, diet, dietary supplements, acupuncture, and prayer. In this paper, we will review common CAM, specifically herbs, that are used in patients with IBD including the herb background, suggested use, evidence in IBD, and most importantly, potential interactions with IBD medications used in elderly patients. Most important evidence-based adverse events and drug-herb interactions are summarized. The herbs discussed include Triticum aestivum (wheat grass), Andrographis paniculata (chiretta), Boswellia serrata, tormentil, bilberry, curcumin (turmeric), Plantago ovata (blond psyllium), Oenothera biennis (evening primrose oil), germinated barley foodstuff, an herbal preparation of myrrh, chamomile and coffee extract, chios mastic gum, wormwood (absinthe, thujone), Cannabis sativa (marijuana, THC), tripterygium wilfordii (thunder god vine), Ulmus rubra (slippery elm bark), trigonella foenugraecum (fenugreek), Dioscorea mexicana (wild yam), Harpagophytum procumbens (devil's claw), ginger, cinnamon, licorice, and peppermint.

  6. Rosa damascena Mill. Essential Oil Has Protective Effect Against Testicular Damage in Diabetic Rats.

    PubMed

    Hamedi, Somayeh; Shomali, Tahoora; Haghighat, Aliakbar

    2018-05-04

    This study investigates the protective effect of Rosa damascena essential oil on diabetes-induced testicular damage in rats. Thirty-six male Wistar rats were randomly divided into 6 equal groups: Group I: negative control (no treatment); Group II: positive control (diabetic by alloxan injection); Groups III-VI that rendered diabetic and received, respectively, 50, 100, 200, and 400 µg/kg/day rose oil, orally for 28 days. Rose oil did not significantly change body weight and blood glucose level as compared to positive control. Serum testosterone level of rose oil-treated rats remained statistically the same with both negative and positive control groups (Groups I and II). Rats treated with rose oil especially at 2 higher dosages (Groups V and VI) had higher sperm count and increased diameters of seminiferous tubules as compared to Group II. Rose oil even at the lowest dosage significantly increased cell count of spermatogonia, primary spermatocytes, Sertoli cells, and Leydig cells, with better outcomes for higher dosages. It appears that short-term repeated dose administration of rose oil can dose-dependently improve structural deteriorations of testes and epididymal sperm count in diabetic rats.

  7. Chemical Methods for Ugnu Viscous Oils

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kishore Mohanty

    2012-03-31

    formulation includes 1.5% of an alkali, 0.4% of a nonionic surfactant, and 0.48% of a polymer. The secondary waterflood in a 1D sand pack had a cumulative recovery of 0.61 PV in about 3 PV injection. The residual oil saturation to waterflood was 0.26. Injection of tertiary alkaline-surfactant-polymer slug followed by tapered polymer slugs could recover almost 100% of the remaining oil. The tertiary alkali-surfactant-polymer flood of the 330 cp oil is stable in three-dimensions; it was verified by a flood in a transparent 5-spot model. A secondary polymer flood is also effective for the 330 cp viscous oil in 1D sand pack. The secondary polymer flood recovered about 0.78 PV of oil in about 1 PV injection. The remaining oil saturation was 0.09. The pressure drops were reasonable (<2 psi/ft) and depended mainly on the viscosity of the polymer slug injected. For the heavy crude oil (of viscosity 10,000 cp), low viscosity (10-100 cp) oil-in-water emulsions can be obtained at salinity up to 20,000 ppm by using a hydrophilic surfactant along with an alkali at a high water-to-oil ratio of 9:1. Very dilute surfactant concentrations (~0.1 wt%) of the synthetic surfactant are required to generate the emulsions. It is much easier to flow the low viscosity emulsion than the original oil of viscosity 10,000 cp. Decreasing the WOR reverses the type of emulsion to water-in-oil type. For a low salinity of 0 ppm NaCl, the emulsion remained O/W even when the WOR was decreased. Hence a low salinity injection water is preferred if an oil-in-water emulsion is to be formed. Secondary waterflood of the 10,000 cp heavy oil followed by tertiary injection of alkaline-surfactants is very effective. Waterflood has early water breakthrough, but recovers a substantial amount of oil beyond breakthrough. Waterflood recovers 20-37% PV of the oil in 1D sand pack in about 3 PV injection. Tertiary alkali-surfactant injection increases the heavy oil recovery to 50-70% PV in 1D sand packs. As the salinity increased

  8. Toxic oil syndrome: the perspective after 20 years.

    PubMed

    Posada de la Paz, M; Philen, R M; Borda, A I

    2001-01-01

    Toxic oil syndrome burst upon the scene in Spain in May of 1981, draining the resources of a newly evolving political and social medicine system. The vehicle of the causative toxic agent was identified as an illicit oil that had been diverted from industrial use and refined in order to remove the aniline denaturant, and that was sold in unlabeled 5-liter containers by itinerant salesmen. Over 20,000 people were ultimately affected, and over 1,200 deaths from all causes have been recorded in the affected cohort. The epidemiologic investigation of toxic oil syndrome involved all facets of investigative and analytical work; from visits to factories and interviewing workers, to sophisticated chemical and statistical analytical techniques. This investigation serves as a further illustration that data and information of all types, and from a wide range of fields, need to be systematically collected and evaluated in order to best resolve an epidemiologic mystery. Astute clinical observation of the patients, however, led to the hypothesis that toxic oil syndrome was a result of a toxic exposure. In this and other epidemics of unknown etiology, clinical observation and the intense scrutiny of patients' histories, signs, and symptoms by treating clinicians have often led to hypotheses that could be tested epidemiologically. When there are medical unknowns, the role of the astute clinician continues to be crucial. The toxic oil syndrome epidemic is an example of how even a developed country can be affected by a massive epidemic of environmental origin if failures occur in the systems that control and regulate the food supply or other consumer products. However, such failures could occur anywhere that large commercial networks operate on the regulatory edge, and if these business lack an in depth knowledge of the consequences of alterations in manufacturing conditions. Such was the case with eosinophilia-myalgia syndrome as well, when apparently minor alterations in

  9. Influences of stearidonic acid-enriched soybean oil on the blood and organ biochemical parameters in rats.

    PubMed

    Kawabata, Terue; Shimoda, Kazumi; Horiguchi, Sayaka; Domon, Marina; Hagiwara, Chie; Takiyama, Miho; Kagawa, Yasuo

    2013-02-01

    In this study, we administered various diets of stearidonic acid (SDA, 18:4n-3) soybean oil to rats and examined the subsequent blood and organ biochemical parameters. Male Wistar rats (seven rats/group, six groups total) were fed diets supplemented with a test oil for 4 weeks. Diets containing test oils were: FFC diet (fish-oil-free control diet), C diet (control group, assuming a Japanese diet), SDA25 diet (25% 18:4n-3 soybean oil in the C diet), SDA50 (50% 18:4n-3 soybean oil in the C diet), ALA diet (34% flaxseed oil in the C diet), and EPA+DHA diet (34% fish oil in the C diet). The intake of 18:4n-3 showed increased relative efficiency of 20:5n-3 accretions in serum and liver triacylglycerol and significantly decreased the serum triacylglycerol level in rats. The results suggested that the consumption of 18:4n-3 soybean oil may modify the lipid and fatty acid profiles of body fats, even when EPA and DHA derived from fish is consumed. Copyright © 2012 Elsevier Ltd. All rights reserved.

  10. Phytochemical composition and antibacterial activity of the essential oils from different parts of sea buckthorn (Hippophae rhamnoides L.).

    PubMed

    Yue, Xuan-Feng; Shang, Xiao; Zhang, Zhi-Juan; Zhang, Yan-Ni

    2017-04-01

    Essential oils from the seed, pulp, and leaf of sea buckthorn were obtained with hydrodistillation, and their phytochemical composition was analyzed through gas chromatography-mass spectrometry. Furthermore, the antibacterial activity of the oils was tested on five food-borne bacteria by spectrometry and evaluated in terms of minimum inhibitory concentration. The results indicate that the composition of all essential oils is dominated by free fatty acids, esters, and alkanes. Minimum inhibitory concentration values on each bacterium were obtained for oils from different parts. The oils from different parts exhibited nearly equal inhibitory effect on Staphylococcus aureus. The pulp oil was found to be the most effective for the rest of bacteria tested except Escherichia coli, on which seed oil shows twice the inhibitory effect to that of leaf or pulp oil. Three natural inhibitory examples were found comparable with or even better than the positive control: pulp oil on Bacillus subtilis, and pulp oil and leaf oil on Bacillus coagulans. Copyright © 2016. Published by Elsevier B.V.

  11. In vitro antimicrobial activity and antagonistic effect of essential oils from plant species.

    PubMed

    Toroglu, Sevil

    2007-07-01

    Kahramanmaras, is a developing city located in the southern part of Turkey Thymus eigii (M. Zohary and RH. Davis) Jalas, Pinus nigraAm. sub sp pallasiana and Cupressus sempervirens L. are the useful plants of the Kahramanmaras province and have been understudy since 2004 for the traditional uses of plants empiric drug, spice, herbal tea industry herbal gum and fuel. The study was designed to examine the antimicrobial activities of essential oils of these plants by the disc diffusion and minimum inhibitory concentration (MIC) methods. In addition, antimicrobial activity of Thymus eigii was researched by effects when it was used together with antibiotics and even when it was combined with other essential oils. When the results of this study were compared with vancomycin (30 mcg) and erytromycin (15 mcg) standards, it was found that Thymus eigii essential oil was particularly found to possess strongerantimicrobial activity whereas other essential oils showed susceptible or moderate activity However, antimicrobial activity changed also by in vitro interactions between antibiotics and Thymus eigii essential oil, also between essential oils of these plants and that of Thymus eigii causing synergic, additive, antagonist effect.

  12. Remediation of Petroleum-Contaminated Soil and Simultaneous Recovery of Oil by Fast Pyrolysis.

    PubMed

    Li, De-Chang; Xu, Wan-Fei; Mu, Yang; Yu, Han-Qing; Jiang, Hong; Crittenden, John C

    2018-05-01

    Petroleum-contaminated soil (PCS) caused by the accidental release of crude oil into the environment, which occurs frequently during oil exploitation worldwide, needs efficient and cost-effective remediation. In this study, a fast pyrolysis technology was implemented to remediate the PCS and concurrently recover the oil. The remediation effect related to pyrolytic parameters, the recovery rate of oil and its possible formation pathway, and the physicochemical properties of the remediated PCS and its suitability for planting were systematically investigated. The results show that 50.9% carbon was recovered in oil, whose quality even exceeds that of crude oil. Both extractable total petroleum hydrocarbon (TPH) and water-soluble organic matter (SOM) in PCS were completely removed at 500 °C within 30 min. The remaining carbon in remediated PCS was determined to be in a stable and innocuous state, which has no adverse effect on wheat growth. On the basis of the systematically characterizations of initial PCS and pyrolytic products, a possible thermochemical mechanism was proposed which involves evaporation, cracking and polymerization. In addition, the energy consumption analysis and remediation effect of various PCSs indicate that fast pyrolysis is a viable and cost-effective method for PCS remediation.

  13. Toxicities of Selected Essential Oils, Silicone Oils, and Paraffin Oil against the Common Bed Bug (Hemiptera: Cimicidae).

    PubMed

    Zha, Chen; Wang, Changlu; Li, Andrew

    2018-02-09

    The common bed bug [Cimex lectularius L. (Hemiptera: Cimicidae)] and tropical bed bug [Cimex hemipterus F. (Hemiptera: Cimicidae)] resurged in the United States and many other countries over the past decades. The need for safe and effective bed bug control products propelled the development of numerous 'green insecticides', mostly with essential oils listed as active ingredients. Various inorganic and organic oils also were used for bed bug management. However, there are no published studies on their toxicities against bed bugs. In this study, we screened 18 essential oils, three silicone oils, and paraffin oil (C5-20 paraffins) for their toxicities against bed bugs. All the oils exhibited insecticidal activity in topical assays. Their toxicities varied significantly; all of the evaluated essential oils were less effective than silicone oils and paraffin oil. The LD50 values of the most effective essential oil (blood orange), paraffin oil, and the most effective silicone oil (dodecamethylpentasiloxane) are 0.184 ± 0.018, 0.069 ± 0.012, and 0.036 ± 0.005 mg per bug, respectively. Direct spray of 1% water solution of 3-[hydroxy (polyethyleneoxy) propyl] heptamethyltrisiloxane, the only silicone oil that mixes well with water, resulted in 92% bed bug mortality after 1 d. Results of this study indicate silicone oils and paraffin oil have the potential to be used as safer alternative bed bug control materials. © The Author(s) 2017. Published by Oxford University Press on behalf of Entomological Society of America. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  14. Phytosterol structured algae oil nanoemulsions and powders: improving antioxidant and flavor properties.

    PubMed

    Chen, Xiao-Wei; Chen, Ya-Jun; Wang, Jin-Mei; Guo, Jian; Yin, Shou-Wei; Yang, Xiao-Quan

    2016-09-14

    Algae oil, enriched with omega-3 long-chain polyunsaturated fatty acids (ω-3 LC-PUFA), is known for its health benefits. However, protection against lipid oxidation as well as masking of unpleasant fishy malodors in algae oil enriched foods is a big challenge to achieve. In this study, we firstly achieved a one-pot ultrasound emulsification strategy (alternative heating-homogenization) to prepare phytosterol structured thermosensitive algae oil-in-water nanoemulsion stabilized by quillaja saponin. After spray drying, the resulting algae oil powders from the structured nanoemulsion templates exhibit an excellent reconstructed behavior, even after 30 d of storage. Furthermore, an enhanced oxidative stability was obtained by reducing both the primary and secondary oxidation products through formulation with β-sitosterol and γ-oryzanol, which are natural antioxidants. Following the results of headspace volatiles using dynamic headspace-gas chromatography-mass spectrometry (DHS-GC-MS), it was clear that the structured algae oil-loaded nanoemulsion and powder had lower levels of fishy off-flavour (e.g., (Z)-heptenal, decanal, ethanone, and hexadecenoic acid), whereas the control emulsion and oil powder without structure performed worse. This study demonstrated that the structure from phytosterols is an effective strategy to minimize the fishy off-flavour and maximize oxidative stability of both algae oil nanoemulsions and spray-dried powders, and opens up the possibility of formulation design in polyunsaturated oil encapsulates as novel delivery systems to apply in functional foods and beverages.

  15. Cosmetic Cleansing Oil Absorption by Soft Contact Lenses in Dry and Wet Conditions.

    PubMed

    Tsukiyama, Junko; Miyamoto, Yuko; Kodama, Aya; Fukuda, Masahiko; Shimomura, Yoshikazu

    2017-09-01

    Previous reports showed that cosmetic cleansing oil for removing makeup, which contains mineral oil and surfactant, can deform some silicone hydrogel contact lenses (SHCLs) when applied directly to the lenses, although plasma-coated SHCLs (lotrafilcon A and B) were not affected. In the present study, we investigated hydrogel lenses and SHCLs in both wet and dry conditions. Several brands of hydrogel and SHCLs were immersed in a cleansing oil solution containing Sudan Black B for 5 min under wet and dry conditions. The lenses under the wet condition were simply picked up from the saline, whereas those under the dry condition were blotted with paper wipes. After immersing, the excess solution remaining on the lenses was removed by finger rubbing with a multipurpose solution. The lenses were then examined using a stereomicroscope, and their mean brightness was measured and compared. The cosmetic cleansing oil was not absorbed by the hydrogel lenses under wet or dry conditions. However, four of seven brands of SHCLs absorbed the cosmetic cleansing oil under both conditions (dry and wet), whereas asmofilcon A absorbed it only under the dry condition. Lotrafilcon B and delefilcon A did not absorb cleansing oil even under the dry condition. Hydrogel lenses resist cosmetic cleansing oil. However, SHCLs have different degrees of resistance depending on the lens material. Some SHCLs absorbed cosmetic cleansing oil more under dry conditions than under wet conditions.

  16. The Bonn Agreement Aerial Surveillance programme: trends in North Sea oil pollution 1986-2004.

    PubMed

    Carpenter, Angela

    2007-02-01

    This paper examines the use of aerial surveillance activities conducted in the North Sea region of Europe since 1986 to assess trends in levels of oil inputs into the marine environment, both across the whole region and within the waters of the different coastal states. It makes use of data collected under the aegis of the 1969 Bonn Agreement through its Annual Reports on Aerial Surveillance and examines developments in surveillance methods and technology which have led to improvements in the detection of oil spills, even during the hours of darkness. The paper then examines country specific data for the eight North Sea contracting parties to the Agreement to assess trends in oil spills in the region.

  17. Neural networks for oil spill detection using TerraSAR-X data

    NASA Astrophysics Data System (ADS)

    Avezzano, Ruggero G.; Velotto, Domenico; Soccorsi, Matteo; Del Frate, Fabio; Lehner, Susanne

    2011-11-01

    The increased amount of available Synthetic Aperture Radar (SAR) images involves a growing workload on the operators at analysis centers. In addition, even if the operators go through extensive training to learn manual oil spill detection, they can provide different and subjective responses. Hence, the upgrade and improvements of algorithms for automatic detection that can help in screening the images and prioritizing the alarms are of great benefit. In this paper we present the potentialities of TerraSAR-X (TS-X) data and Neural Network algorithms for oil spills detection. The radar on board satellite TS-X provides X-band images with a resolution of up to 1m. Such resolution can be very effective in the monitoring of coastal areas to prevent sea oil pollution. The network input is a vector containing the values of a set of features characterizing an oil spill candidate. The network output gives the probability for the candidate to be a real oil spill. Candidates with a probability less than 50% are classified as look-alikes. The overall classification performances have been evaluated on a data set of 50 TS-X images containing more than 150 examples of certified oil spills and well-known look-alikes (e.g. low wind areas, wind shadows, biogenic films). The preliminary classification results are satisfactory with an overall detection accuracy above 80%.

  18. Geochemical signature of NORM waste in Brazilian oil and gas industry.

    PubMed

    De-Paula-Costa, G T; Guerrante, I C; Costa-de-Moura, J; Amorim, F C

    2018-09-01

    The Brazilian Nuclear Energy Agency (CNEN) is responsible for any radioactive waste storage and disposal in the country. The storage of radioactive waste is carried out in the facilities under CNEN regulation and its disposal is operated, managed and controlled by the CNEN. Oil NORM (Naturally Occurring Radioactive Materials) in this article refers to waste coming from oil exploitation. Oil NORM has called much attention during the last decades, mostly because it is not possible to determine its primary source due to the actual absence of a regulatory control mechanism. There is no efficient regulatory tool which allows determining the origin of such NORM wastes even among those facilities under regulatory control. This fact may encourage non-authorized radioactive material transportation, smuggling and terrorism. The aim of this project is to provide a geochemical signature for oil NORM waste using its naturally occurring isotopic composition to identify its origin. The here proposed method is the modeling of radioisotopes normally present in oil pipe contamination such as 228 Ac, 214 Bi and 214 Pb analyzed by gamma spectrometry. The specific activities of elements from different decay series are plotted in a scatter diagram. This method was successfully tested with gamma spectrometry analyses of oil sludge NORM samples from four different sources obtained from Petrobras reports for the Campos Basin/Brazil. Copyright © 2018 Elsevier Ltd. All rights reserved.

  19. Sensitivity and Antioxidant Response of Chlorella sp. MM3 to Used Engine Oil and Its Water Accommodated Fraction.

    PubMed

    Ramadass, Kavitha; Megharaj, Mallavarapu; Venkateswarlu, Kadiyala; Naidu, Ravi

    2016-07-01

    We exposed the microalgal strain, Chlorella sp. MM3, to unused or used engine oil, or their water accommodated fractions (WAFs) to determine growth inhibition and response of antioxidant enzymes. Oil type and oil concentration greatly affected the microalgal growth. Used oil at 0.04 % (0.4 g L(-1)) resulted in 50 % inhibition in algal growth, measured in terms of chlorophyll-a, while the corresponding concentration of unused oil was nontoxic. Similarly, used oil WAF showed significant toxicity to the algal growth at 10 % level, whereas WAF from unused oil was nontoxic even at 100 % concentration. Peroxidase enzyme in the microalga significantly increased with used oil at concentrations above 0.04 g L(-1) whereas the induction of superoxide dismutase and catalase was apparent only at 0.06 g L(-1). Activities of the antioxidant enzymes increased significantly when the microalga was exposed to 75 and 100 % WAF obtained from used oil. The used oil toxicity on microalga could be due to the presence of toxic soluble mono- and polyaromatic compounds, heavy metals, and other compounds attained by the oil during its use in the motor engines.

  20. The Evening/Morning Star.

    ERIC Educational Resources Information Center

    Riddle, Bob

    1997-01-01

    Explains how Venus changes visibility regularly from morning to evening because of its quick orbit time during part of the year. Includes a brief history of observations of this phenomenon and provides a detailed account from the Australian Aborigines. (DDR)

  1. Oil migration in a major growth fault: Structural analysis of the Pathfinder core, South Eugene Island Block 330, offshore Louisiana

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Losh, S.

    1998-09-01

    The Pathfinder core, collected in the South Eugene Island Block 330 field, offshore Louisiana, provides an outstanding sample of structures associated with a major growth fault that abuts a giant oil field and that is thought to have acted as a conduit for hydrocarbon migration into the producing reservoirs. The fault zone in the core consists of three structural domains, each characterized by a distinct rock type, distribution of fault dips and dip azimuths, and distribution of spacing between adjacent faults and fractures. Although all of the domains contain oil-bearing sands, only faults and fractures in the deepest domain containmore » oil, even though the oil-barren fault domains contain numerous faults and fractures that are parallel to those containing oil in the deepest domain. The deepest domain is also distinguished from the other two domains by a greater degree of structural complexity and by a well-defined power-law distribution of fault and fracture spacings. Even though oil is present in sands throughout the core, its restriction to faults and fractures in the youngest sampled portion of the fault zone implies that oil migrated only through that part of the fault that was active during the time when oil had access to it. The absence of oil in fractures or faults in the other, probably older, fault domains indicates that the oil was never sufficiently pressured to flow up the fault zone on its own, either by hydraulic fracture or by increased permeability as a result of decreased effective stress. Instead, fluid migration along faults and fractures in the Pathfinder core was enhanced by permeability created in response to relatively far-field stresses related to minibasin subsidence.« less

  2. Antioxidant Properties of Aqueous Extract of Roasted Hulled Barley in Bulk Oil or Oil-in-Water Emulsion Matrix.

    PubMed

    Oh, Sumi; Kim, Mi-Ja; Park, Kye Won; Lee, Jae Hwan

    2015-11-01

    Antioxidant properties of the aqueous extracts of hulled barley (Hordeum vulgare L.) that had been roasted at 210 °C for 20 min were determined in bulk oil and oil-in-water (O/W) emulsions. Bulk oils were heated at 60, 100, and 180 °C, and O/W emulsions were oxidized under riboflavin photosensitization. The content of phenolic compounds was analyzed by high-performance liquid chromatography, and in vitro antioxidant assays were also conducted. The major phenolics contained in the aqueous extract of roasted hulled barley (AERB) were p-coumaric, ferulic, protocatechuic, chlorogenic, 4-hydroxybenzoic, and vanillic acids. Depending on the concentration and oxidation temperature, AERB had antioxidant or prooxidant properties in bulk oil. At 60 °C, AERB at a concentration of 0.5% acted as a prooxidant, whereas at 1.0% it acted as an antioxidant. At 100 °C, AERB acted as an antioxidant irrespective of concentration. In 180 °C conditions, 0.5% AERB acted as a prooxidant, whereas other concentrations of AERB acted as antioxidants. In the case of riboflavin photosensitized O/W emulsions, AERB showed antioxidant properties irrespective of concentration. Antioxidant abilities of AERB are affected by the food matrix, including bulk oil and O/W emulsions, and concentrations of AERB, even though diverse phenolic compounds may display high antioxidant properties in in vitro assays. Roasted barley has been widely used as a tea ingredient in East Asian countries such as Korea, China, and Japan. The highly antioxidative properties of the aqueous extracts of roasted barley have been confirmed in bulk oil and O/W emulsions as well as in vitro assays because of the presence of phenolic compounds. The results of this study can contribute to the development of antioxidant-rich beverages using roasted barley by aiding in the selection of proper food matrix-containing extracts of high phenolic compounds, as well as by expanding consumers’ choices for healthy beverages. © 2015

  3. Process for preparing lubricating oil from used waste lubricating oil

    DOEpatents

    Whisman, Marvin L.; Reynolds, James W.; Goetzinger, John W.; Cotton, Faye O.

    1978-01-01

    A re-refining process is described by which high-quality finished lubricating oils are prepared from used waste lubricating and crankcase oils. The used oils are stripped of water and low-boiling contaminants by vacuum distillation and then dissolved in a solvent of 1-butanol, 2-propanol and methylethyl ketone, which precipitates a sludge containing most of the solid and liquid contaminants, unspent additives, and oxidation products present in the used oil. After separating the purified oil-solvent mixture from the sludge and recovering the solvent for recycling, the purified oil is preferably fractional vacuum-distilled, forming lubricating oil distillate fractions which are then decolorized and deodorized to prepare blending stocks. The blending stocks are blended to obtain a lubricating oil base of appropriate viscosity before being mixed with an appropriate additive package to form the finished lubricating oil product.

  4. Composition and antimicrobial activity of the essential oils of Laserpitium latifolium L. and L. ochridanum Micevski (Apiaceae).

    PubMed

    Popović, Višnja B; Petrović, Silvana D; Milenković, Marina T; Drobac, Milica M; Couladis, Maria A; Niketić, Marjan S

    2015-01-01

    The chemical composition and antimicrobial activity of essential oils of Laserpitium latifolium and L. ochridanum were investigated. The essential oils were isolated by steam distillation and characterized by GC-FID and GC/MS analyses. All essential oils were distinguished by high contents of monoterpenes, and α-pinene was the most abundant compound in the essential oils of L. latifolium underground parts and fruits (contents of 44.4 and 44.0%, resp.). The fruit essential oil was also rich in sabinene (26.8%). Regarding the L. ochridanum essential oils, the main constituents were limonene in the fruit oil (57.7%) and sabinene in the herb oil (25.9%). The antimicrobial activity of these essential oils as well as that of L. ochridanum underground parts, whose composition was reported previously, was tested by the broth-microdilution method against four Gram-positive and three Gram-negative bacteria and two Candida albicans strains. Except the L. latifolium underground-parts essential oil, the other investigated oils showed a high antimicrobial potential against Staphylococcus aureus, S. epidermidis, Micrococcus luteus, or Candida albicans (minimal inhibitory concentrations of 13.0-73.0 μg/ml), comparable to or even higher than that of thymol, which was used as reference compound. Copyright © 2015 Verlag Helvetica Chimica Acta AG, Zürich.

  5. Implications of Abundant Gas and Oil for Climate Forcing

    NASA Astrophysics Data System (ADS)

    Edmonds, J.

    2015-12-01

    Perhaps the most important development in the field of energy over the past decade has been the advent of technologies that enable the production of larger volumes of natural gas and oil at lower cost. The availability of more abundant gas and oil is reshaping the global energy system, with implications for both evolving emissions of CO2 and other climate forcers. More abundant gas and oil will also transform the character of greenhouse gas emissions mitigation. We review recent findings regarding the impact of abundant gas and oil for climate forcing and the challenge of emissions mitigation. We find strong evidence that, absent policies to limits its penetration against renewable energy, abundant gas has little observable impact on CO2 emissions, and tends to increase overall climate forcing, though the latter finding is subject to substantial uncertainty. The presence of abundant gas also affects emissions mitigation. There is relatively little literature exploring the implication of expanded gas availability on the difficulty in meeting emissions mitigation goals. However, preliminary results indicate that on global scales abundant gas does not substantially affect the cost of emissions mitigation, even though natural gas could have an expanded role in emissions mitigation scenarios as compared with scenarios in which natural gas is less abundant.

  6. Utilization of oil extracted from spent coffee grounds for sustainable production of polyhydroxyalkanoates.

    PubMed

    Obruca, Stanislav; Petrik, Sinisa; Benesova, Pavla; Svoboda, Zdenek; Eremka, Libor; Marova, Ivana

    2014-07-01

    Spent coffee grounds (SCG), an important waste product of the coffee industry, contain approximately 15 wt% of coffee oil. The aim of this work was to investigate the utilization of oil extracted from SCG as a substrate for the production of poly(3-hydroxybutyrate) (PHB) by Cupriavidus necator H16. When compared to other waste/inexpensive oils, the utilization of coffee oil resulted in the highest biomass as well as PHB yields. Since the correlation of PHB yields and the acid value of oil indicated a positive effect of the presence of free fatty acids in oil on PHB production (correlation coefficient R (2) = 0.9058), superior properties of coffee oil can be probably attributed to the high content of free fatty acids which can be simply utilized by the bacteria culture. Employing the fed-batch mode of cultivation, the PHB yields, the PHB content in biomass, the volumetric productivity, and the Y P/S yield coefficient reached 49.4 g/l, 89.1 wt%, 1.33 g/(l h), and 0.82 g per g of oil, respectively. SCG are annually produced worldwide in extensive amounts and are disposed as solid waste. Hence, the utilization of coffee oil extracted from SCG is likely to improve significantly the economic aspects of PHB production. Moreover, since oil extraction decreased the calorific value of SCG by only about 9 % (from 19.61 to 17.86 MJ/kg), residual SCG after oil extraction can be used as fuel to at least partially cover heat and energy demands of fermentation, which should even improve the economic feasibility of the process.

  7. Effects of an oil spill on benthic community production and respiration on subtropical intertidal sandflats.

    PubMed

    Lee, Li-Hua; Lin, Hsing-Juh

    2013-08-15

    This study determined effects of an oil spill on subtropical benthic community production and respiration by monitoring CO2 fluxes in benthic chambers on intertidal sandflats during emersion before and after an accidental spill. The oil spill decreased sediment chlorophyll a concentrations, altered benthic macrofaunal community, and affected ecological functioning by suppressing or even stopping microalgal production, increasing bacterial respiration, and causing a shift from an autotrophic system to a heterotrophic system. Effects of the oil spill on the macrofauna were more severe than on benthic microalgae, and affected sedentary infauna more than motile epifauna. Despite the oil spill's impact on the benthic community and carbon metabolism, the affected area appeared to return to normal in about 23 days. Our results suggest that the prompt response of benthic metabolism to exposure to petroleum hydrocarbons can serve as a useful indicator of the impact of an oil spill. Copyright © 2013 Elsevier Ltd. All rights reserved.

  8. Antimicrobial activity of essential oils from Mediterranean aromatic plants against several foodborne and spoilage bacteria.

    PubMed

    Silva, Nuno; Alves, Sofia; Gonçalves, Alexandre; Amaral, Joana S; Poeta, Patrícia

    2013-12-01

    The antimicrobial activity of essential oils extracted from a variety of aromatic plants, often used in the Portuguese gastronomy was studied in vitro by the agar diffusion method. The essential oils of thyme, oregano, rosemary, verbena, basil, peppermint, pennyroyal and mint were tested against Gram-positive (Listeria monocytogenes, Clostridium perfringens, Bacillus cereus, Staphylococcus aureus, Enterococcus faecium, Enterococcus faecalis, and Staphylococcus epidermidis) and Gram-negative strains (Salmonella enterica, Escherichia coli, and Pseudomonas aeruginosa). For most essential oils examined, S. aureus, was the most susceptible bacteria, while P. aeruginosa showed, in general, least susceptibility. Among the eight essential oils evaluated, thyme, oregano and pennyroyal oils showed the greatest antimicrobial activity, followed by rosemary, peppermint and verbena, while basil and mint showed the weakest antimicrobial activity. Most of the essential oils considered in this study exhibited a significant inhibitory effect. Thyme oil showed a promising inhibitory activity even at low concentration, thus revealing its potential as a natural preservative in food products against several causal agents of foodborne diseases and food spoilage. In general, the results demonstrate that, besides flavoring the food, the use of aromatic herbs in gastronomy can also contribute to a bacteriostatic effect against pathogens.

  9. Analysis of Processed Foods Containing Oils and Fats by Time of Flight Mass Spectrometry with an APCI Direct Probe.

    PubMed

    Ito, Shihomi; Chikasou, Masato; Inohana, Shuichi; Fujita, Kazuhiro

    2016-01-01

    Discriminating vegetable oils and animal and milk fats by infrared absorption spectroscopy is difficult due to similarities in their spectral patterns. Therefore, a rapid and simple method for analyzing vegetable oils, animal fats, and milk fats using TOF/MS with an APCI direct probe ion source was developed. This method enabled discrimination of these oils and fats based on mass spectra and detailed analyses of the ions derived from sterols, even in samples consisting of only a few milligrams. Analyses of the mass spectra of processed foods containing oils and milk fats, such as butter, cheese, and chocolate, enabled confirmation of the raw material origin based on specific ions derived from the oils and fats used to produce the final product.

  10. Effect of crude oil exposure and dispersant application on meiofauna: an intertidal mesocosm experiment.

    PubMed

    Elarbaoui, Soumaya; Richard, Marion; Boufahja, Fehmi; Mahmoudi, Ezzeddine; Thomas-Guyon, Hélène

    2015-05-01

    Dispersant application is used as a response technique to minimize the environmental risk of an oil spill. In nearshore areas, dispersant application is a controversial countermeasure: environmental benefits are counteracted by the toxicity of dispersant use. The effects of the use of chemical dispersants on meiobenthic organisms and nematodes were investigated in a mesocosm experiment. A 20 day experiment was performed in four experimental sets of mesocosms. In three of them, sediments were contaminated, respectively by oil (500 mg kg(-1)), dispersed oil (oil + 5% dispersant), and dispersant alone, whereas in the last set sediments were kept undisturbed and used as a reference (Re). Our results showed that the meiobenthic response to oil contamination was rapid, for copepods and nematodes. One-way ANOVA showed a significant decrease of the abundance of copepods. In the case of nematodes, univariate and multivariate analyses indicated a clear decrease of the abundance of the species after only 20 days of pollutant exposure and thus reducing Shannon-Wiener diversity and Pielou's evenness. In contrast, Sphaerolaimus gracilis and Sabateria sp. became more frequent within disturbed assemblages and appeared to be resistant and/or opportunistic species in the presence of these kinds of toxicants. Moreover, responses of copepods and nematodes to the treatment seemed to be the same irrespective of whether only oil or oil + dispersant was performed. The main toxicities of dispersed oil come not from the "composition of a newly formed oil and oil spill dispersant mixture" but from the "quantities of increased dispersed oil droplets".

  11. Newcastle disease oil emulsion vaccines prepared with animal, vegetable, and synthetic oils.

    PubMed

    Stone, H D

    1997-01-01

    Animal, vegetable, and synthetic oils were tested as potential replacements for mineral oil in Newcastle disease oil emulsion vaccines. Emulsifying surfactants of seed oil origin comprised 10% of the the oil phase that was used to prepare water-in-oil emulsion vaccines that contained a final concentration of 20% aqueous antigen. The hemagglutination inhibition responses of chickens inoculated with 46 of the newly formulated oil vaccines were, in most cases, not significantly different from those of control chickens inoculated with mineral oil vaccine. Tissue reactions associated with animal, vegetable, and synthetic oil vaccines were less severe than those associated with mineral oil vaccines. Viscosity of the mineral oil formulations ranged from 1/2 to 3 1/2 times that of the mineral oil control vaccines. These findings indicate that any of several oils may be more suitable than mineral oil for preparation of immune adjuvants for poultry vaccines.

  12. Oil Spill!

    ERIC Educational Resources Information Center

    Ansberry, Karen Rohrich; Morgan, Emily

    2005-01-01

    An oil spill occurs somewhere in the world almost every day of the year, and the consequences can be devastating. In this month's column, students explore the effects of oil spills on plants, animals, and the environment and investigate oil spill clean-up methods through a simulated oil spill. The activities described in this article give students…

  13. Lack of promotion of colon carcinogenesis by high-oleic safflower oil.

    PubMed

    Takeshita, M; Ueda, H; Shirabe, K; Higuchi, Y; Yoshida, S

    1997-04-15

    The nonpromoting effect of olive oil on colon carcinogenesis has been attributed to its high oleic acid content, whereas a positive association of monounsaturated fat in beef tallow with colon tumors has been reported. The effect of constituents other than fatty acids could not be neglected in these experiments. In order to minimize the effects of minor constituents in the oils, the authors compared conventional safflower oil with oil from a mutant strain of safflower that is rich in oleic acid. ICR mice were treated with 1,2-dimethylhydrazine (DMH, 20 mg/kg body weight every week for 12 weeks) and then were fed either a high-fat diet (23.5% by weight), containing safflower oil (HF-LA) or high-oleic safflower oil (HF-OA), or a low-fat diet (5% by weight), containing safflower oil (LF-LA) or high-oleic safflower oil (LF-OA). The test diets were continued until termination of the experiment at 30 weeks after the first administration of DMH. Fatty acid composition of colon phospholipids was determined by gas-liquid chromatography-mass spectrometry. Tumor multiplicity in animals fed the HF-OA diet was indistinguishable from that in animals fed LF-LA or LF-OA. In contrast, animals fed the HF-LA diet had a significantly higher incidence of colon tumors (mostly adenocarcinomas) than the other groups. Fatty acid profiles of colon phospholipids reflected those of the diet. Animals fed a HF-LA diet showed a marked decrease of nervonic acid (C24:1, n-9) in the colon sphingomyelin. These data indicate that oleic acid does not enhance DMH-induced colon carcinogenesis in mice, even when they are fed a high-fat diet.

  14. Can Producing Oil Store Carbon? Greenhouse Gas Footprint of CO2EOR, Offshore North Sea.

    PubMed

    Stewart, R Jamie; Haszeldine, R Stuart

    2015-05-05

    Carbon dioxide enhanced oil recovery (CO2EOR) is a proven and available technology used to produce incremental oil from depleted fields while permanently storing large tonnages of injected CO2. Although this technology has been used successfully onshore in North America and Europe, there are currently no CO2EOR projects in the United Kingdom. Here, we examine whether offshore CO2EOR can store more CO2 than onshore projects traditionally have and whether CO2 storage can offset additional emissions produced through offshore operations and incremental oil production. Using a high-level Life Cycle system approach, we find that the largest contribution to offshore emissions is from flaring or venting of reproduced CH4 and CO2. These can already be greatly reduced by regulation. If CO2 injection is continued after oil production has been optimized, then offshore CO2EOR has the potential to be carbon negative--even when emissions from refining, transport, and combustion of produced crude oil are included. The carbon intensity of oil produced can be just 0.056-0.062 tCO2e/bbl if flaring/venting is reduced by regulation. This compares against conventional Saudi oil 0.040 tCO2e/bbl or mined shale oil >0.300 tCO2e/bbl.

  15. Neutron scattering studies of crude oil viscosity reduction with electric field

    NASA Astrophysics Data System (ADS)

    Du, Enpeng

    data that contains information on the properties of a sample. We can analyze the data acquisition from the detectors and get the information on size, shape, etc. This is why we choose SANS as our research tool. The world's top energy problems are security concerns, climate concerns and environmental concerns. So far, oil (37%) is still the No.1 fuel in world energy consumption (Oil 37%, Coal 25%, Bio-fuels 0.2%, Gas 23%, Nuclear 6%, Biomass 4%, Hydro 3%, Solar heat 0.5%, Wind 0.3%, Geothermal 0.2% and Solar photovoltaic 0.04%). Even more and more alternative energy: bio-fuels, nuclear and solar energy will be used in the future, but nuclear energy has a major safety issue after the Japanese Fukushima I nuclear accidents, and other energies contribute only a small percent. Thus, it is very important to improve the efficiency and reduce the population of petroleum products. There is probably one thing that we can all agree on: the world's energy reserves are not unlimited. Even though it is limited, only 30% of the oil reserves is conventional oil, so in order to produce, transport, and refine of heavy crude oil without wasting huge amounts of energy, we need to reduce the viscosity without using high temperature stream heating or diluent; As more and more off-shore oil is exploited at that we need reduce the viscosity without increasing temperature. The whole petroleum consumed in U.S. in 2009 was 18.7 million barrels per day and 35% of all the energy we consumed. Diesel is one of the very important fossil fuel which is about 20% of petroleum consumed. Most of the world's oils are non-conventional, 15 % of heavy oil, 25 % of extra heavy oil, 30 % of the oil sands and bitumen, and the conventional oil reserves is only 30%. The oil sand is closely related to the heavy crude oil, the main difference being that oil sands generally do not flow at all. For efficient energy production and conservation, how to lower the liquated fuel and crude oil viscosity is a very important

  16. Science: Oil Slick.

    ERIC Educational Resources Information Center

    VanCleave, Janice

    2000-01-01

    Presents a science experiment about oil spills and oil pollution for 7th- and 8th-grade science students. This variation on a method used by pollution control experts to clean up oil spills shows students how oil is collected after an oil spill, explaining that with this method, much of the damage from an oil spill can be averted. (SM)

  17. Effects of oil and dispersant on formation of marine oil snow and transport of oil hydrocarbons.

    PubMed

    Fu, Jie; Gong, Yanyan; Zhao, Xiao; O'Reilly, S E; Zhao, Dongye

    2014-12-16

    This work explored the formation mechanism of marine oil snow (MOS) and the associated transport of oil hydrocarbons in the presence of a stereotype oil dispersant, Corexit EC9500A. Roller table experiments were carried out to simulate natural marine processes that lead to formation of marine snow. We found that both oil and the dispersant greatly promoted the formation of MOS, and MOS flocs as large as 1.6-2.1 mm (mean diameter) were developed within 3-6 days. Natural suspended solids and indigenous microorganisms play critical roles in the MOS formation. The addition of oil and the dispersant greatly enhanced the bacterial growth and extracellular polymeric substance (EPS) content, resulting in increased flocculation and formation of MOS. The dispersant not only enhanced dissolution of n-alkanes (C9-C40) from oil slicks into the aqueous phase, but facilitated sorption of more oil components onto MOS. The incorporation of oil droplets in MOS resulted in a two-way (rising and sinking) transport of the MOS particles. More lower-molecular-weight (LMW) n-alkanes (C9-C18) were partitioned in MOS than in the aqueous phase in the presence of the dispersant. The information can aid in our understanding of dispersant effects on MOS formation and oil transport following an oil spill event.

  18. The Obtaining of Oil from an Oil Reservoir.

    ERIC Educational Resources Information Center

    Dawe, R. A.

    1979-01-01

    Discusses the mechanics of how an actual oil reservoir works and provides some technical background in physics. An experiment which simulates an oil reservoir and demonstrates quantitatively all the basic concepts of oil reservoir rock properties is also presented. (HM)

  19. Functionalized Carbon Nanotubes in Modified Plant Oil Composites.

    NASA Astrophysics Data System (ADS)

    McAninch, Ian M.; Wool, Richard P.

    2007-03-01

    Carbon nanotubes (CNTs) with their impressive mechanical properties are ideal reinforcement material. Acrylated epoxidized soy oil (AESO) has been previously shown to have favorable interactions with carbon nanotubes; however a mixture of aggregates and dispersed tubes were found even at low CNT concentrations. In order to prevent re-aggregation, the CNTs were functionalized with a 10 carbon long aliphatic chain. These aliphatic chains are similar to the fatty acids that make up soy oil. Functionalization was verified using XPS and IR spectroscopy. These functionalized CNTs were dispersed by mechanical shear mixing into AESO both with and without styrene as a comonomer. No large aggregates were observed in the liquid, uncured, samples or in the final cured composites. Dispersion in the solid composites was verified using optical and electron microscopy. Better dispersion also resulted in improved mechanical properties.

  20. Coconut oil has less satiating properties than medium chain triglyceride oil.

    PubMed

    Kinsella, R; Maher, T; Clegg, M E

    2017-10-01

    It is well established that the consumption of medium-chain triglycerides (MCT) can increase satiety and reduce food intake. Many media articles promote the use of coconut oil for weight loss advocating similar health benefits to that of MCT. The aim of this study was to examine the effect of MCT oil compared to coconut oil and control oil on food intake and satiety. Following an overnight fast, participants consumed a test breakfast smoothie containing 205kcal of either (i) MCT oil (ii) coconut oil or (iii) vegetable oil (control) on three separate test days. Participants recorded appetite ratings on visual analogue scales and were presented with an ad libitum lunch meal of preselected sandwiches 180min after consumption of the breakfast. The results showed a significant difference in energy and macronutrient intakes at the ad libitum meal between the three oils with the MCT oil reducing food intake compared to the coconut and control oil. Differences in food intake throughout the day were found for energy and fat, with the control having increased food intake compared to the MCT and coconut. The MCT also increased fullness over the three hours after breakfast compared to the control and coconut oils. The coconut oil was also reported as being less palatable than the MCT oil. The results of this study confirm the differences that exist between MCT and coconut oil such that coconut oil cannot be promoted as having similar effects to MCT oil on food intake and satiety. Crown Copyright © 2017. Published by Elsevier Inc. All rights reserved.

  1. Effects of exposure to oil spills on human health: Updated review.

    PubMed

    Laffon, Blanca; Pásaro, Eduardo; Valdiglesias, Vanessa

    2016-01-01

    Oil spills may involve health risks for people participating in the cleanup operations and coastal inhabitants, given the toxicological properties of the oil components. In spite of this, only after a few major oil spills (crude oil or fuel oil no. 6) have studies on effects of exposure to diverse aspects of human health been performed. Previously, Aguilera et al. (2010) examined all documents published to that date dealing with any type of human health outcome in populations exposed to oil spills. The aim of the present review was to compile all new information available and determine whether evidence reported supports the existence of an association between exposure and adverse human health risks. Studies were classified in three groups according to type of health outcome addressed: (i) effects on mental health, (ii) physical/physiological effects, and (iii) genotoxic, immunotoxic, and endocrine toxicity. New studies published on oil-spill-exposed populations-coastal residents in the vicinity of the spills or participants in cleanup operations-provide additional support to previous evidence on adverse health effects related to exposure regarding different parameters in all three categories considered. Some of the observed effects even indicated that several symptoms may persist for some years after exposure. Hence, (1) health protection in these individuals should be a matter of concern; and (2) health risk assessment needs to be carried out not only at the time of exposure but also for prolong periods following exposure, to enable early detection of any potential exposure-related harmful effects.

  2. Oil Production, The Price Crash and Uncertainty in Climate Change

    NASA Astrophysics Data System (ADS)

    Murray, J. W.

    2015-12-01

    World oil production increased to about 74 million barrels per day by January 2005, and was fairly constant until 2011 when it started to increase to 77.8 mb/d in 2014. This spectacular increase of 4 mb/d was almost entirely due to a sharp increase in production in the US from shale formations, called light tight oil (LTO). World oil production minus this increase in US LTO Production has been flat since 2005 at about 74 mb/d. When US production starts to decline, world oil production likely will as well. That surge is forecast to end soon because LTO is expensive to produce, the first year decline rates are extremely high requiring many new wells each year to maintain or increase production and the most productive locations have already been drilled. It is unprofitable for the Exploration and Production (E&P) companies. Full-year free cash flow has been negative for most tight oil E&P companies since 2009. The total negative cash flow for the 19 largest E&P companies totaled 10.5B in 2014. The surge in US LTO production created an imbalance in global supply and demand and resulted in a 50% decrease in the price of oil. The tight-oil producers who were are financially marginal at an oil price greater than 90 per barrel are even more so at the lower price. As a result the surge in US production of LTO is declining, making it unlikely that world oil production will exceed the present value of about 28 Gb/yr (equivalent to 75 mb/d) (175 EJ/yr). Many of the SRES (IPCC Special Report on Emission Scenarios) and RCP (IPCC Representative Concentration Pathways) projections (especially RCP 8.5 and 6) require CO2 emissions due to oil consumption in the range of 32 Gb/yr to 57 Gb/yr (200 to 350 EJ/yr). The higher values would require a doubling of world oil production. It is highly uncertain whether the higher CO2 scenarios will be reached. This is an element of uncertainty missing from most considerations of future climate change.

  3. Oil Spills

    MedlinePlus

    Oil spills often happen because of accidents, when people make mistakes or equipment breaks down. Other causes include natural disasters or deliberate acts. Oil spills have major environmental and economic effects. Oil ...

  4. Specific sensors for special roles in oil spill remote sensing

    NASA Astrophysics Data System (ADS)

    Brown, Carl E.; Fingas, Mervin F.

    1997-01-01

    Remote sensing is becoming an increasingly important tool for the effective direction of oil spill countermeasures. Cleanup personnel have recognized that remote sensing can increase spill cleanup efficiency. The general public expects that the government and/or the spiller know the location and the extent of the contamination. The Emergencies Science Division (ESD) of Environment Canada, is responsible for remote sensing during oil spill emergencies along Canada's three coastlines, extensive inland waterways, as well as over the entire land mass. In addition to providing operational remote sensing, ESD conducts research into the development of airborne oil spill remote sensors, including the Scanning Laser Environmental Airborne Fluorosensor (SLEAF) and the Laser Ultrasonic Remote SEnsing of Oil Thickness (LURSOT) sensor. It has long been recognized that there is not one sensor or 'magic bullet' which is capable of detecting oil and related petroleum products in all environments and spill scenarios. There are sensors which possess a wide filed-of-view and can therefore be used to map the overall extent of the spill. These sensors, however lack the specificity required to positively identify oil and related products. This is even more of a problem along complicated beach and shoreline environments where several substrates are present. The specific laser- based sensors under development by Environment Canada are designed to respond to special roles in oil spill response. In particular, the SLEAF is being developed to unambiguously detect and map oil and related petroleum products in complicated marine and shoreline environments where other non-specific sensors experience difficulty. The role of the SLEAF would be to confirm or reject suspected oil contamination sites that have been targeted by the non- specific sensors. This confirmation will release response crews from the time consuming task of physically inspecting each site, and direct crews to sites that

  5. Structural Oil Pan With Integrated Oil Filtration And Cooling System

    DOEpatents

    Freese, V, Charles Edwin

    2000-05-09

    An oil pan for an internal combustion engine includes a body defining a reservoir for collecting engine coolant. The reservoir has a bottom and side walls extending upwardly from the bottom to present a flanged lip through which the oil pan may be mounted to the engine. An oil cooler assembly is housed within the body of the oil pan for cooling lubricant received from the engine. The body includes an oil inlet passage formed integrally therewith for receiving lubricant from the engine and delivering lubricant to the oil cooler. In addition, the body also includes an oil pick up passage formed integrally therewith for providing fluid communication between the reservoir and the engine through the flanged lip.

  6. The effects of oil pollution on Antarctic benthic diatom communities over 5 years.

    PubMed

    Polmear, R; Stark, J S; Roberts, D; McMinn, A

    2015-01-15

    Although considered pristine, Antarctica has not been impervious to hydrocarbon pollution. Antarctica's history is peppered with oil spills and numerous abandoned waste disposal sites. Both spill events and constant leakages contribute to previous and current sources of pollution into marine sediments. Here we compare the response of the benthic diatom communities over 5 years to exposure to a commonly used standard synthetic lubricant oil, an alternative lubricant marketed as more biodegradable, in comparison to a control treatment. Community composition varied significantly over time and between treatments with some high variability within contaminated treatments suggesting community stress. Both lubricants showed evidence of significant effects on community composition after 5 years even though total petroleum hydrocarbon reduction reached approximately 80% over this time period. It appears that even after 5 years toxicity remains high for both the standard and biodegradable lubricants revealing the temporal scale at which pollutants persist in Antarctica. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. Diesel oil

    MedlinePlus

    ... oil is a heavy oil used in diesel engines. Diesel oil poisoning occurs when someone swallows diesel ... people trying to suck (siphon) gas from an automobile tank using their mouth and a garden hose ( ...

  8. Profitable solutions to climate, oil, and proliferation.

    PubMed

    Lovins, Amory B

    2010-05-01

    Protecting the climate is not costly but profitable (even if avoided climate change is worth zero), mainly because saving fuel costs less than buying fuel. The two biggest opportunities, both sufficiently fast, are oil and electricity. The US, for example, can eliminate its oil use by the 2040s at an average cost of $15 per barrel ($2000), half by redoubled efficiency and half by alternative supplies, and can save three-fourths of its electricity more cheaply than operating a thermal power station. Integrative design permits this by making big energy savings cheaper than small ones, turning traditionally assumed diminishing returns into empirically observed expanding returns. Such efficiency choices accelerate climate-safe, inexhaustible, and resilient energy supply-notably the "micropower" now delivering about a sixth of the world's electricity and 90% of its new electricity. These cheap, fast, market-financeable, globally applicable options offer the most effective, yet most underestimated and overlooked, solutions for climate, proliferation, and poverty.

  9. Improving oil classification quality from oil spill fingerprint beyond six sigma approach.

    PubMed

    Juahir, Hafizan; Ismail, Azimah; Mohamed, Saiful Bahri; Toriman, Mohd Ekhwan; Kassim, Azlina Md; Zain, Sharifuddin Md; Ahmad, Wan Kamaruzaman Wan; Wah, Wong Kok; Zali, Munirah Abdul; Retnam, Ananthy; Taib, Mohd Zaki Mohd; Mokhtar, Mazlin

    2017-07-15

    This study involves the use of quality engineering in oil spill classification based on oil spill fingerprinting from GC-FID and GC-MS employing the six-sigma approach. The oil spills are recovered from various water areas of Peninsular Malaysia and Sabah (East Malaysia). The study approach used six sigma methodologies that effectively serve as the problem solving in oil classification extracted from the complex mixtures of oil spilled dataset. The analysis of six sigma link with the quality engineering improved the organizational performance to achieve its objectivity of the environmental forensics. The study reveals that oil spills are discriminated into four groups' viz. diesel, hydrocarbon fuel oil (HFO), mixture oil lubricant and fuel oil (MOLFO) and waste oil (WO) according to the similarity of the intrinsic chemical properties. Through the validation, it confirmed that four discriminant component, diesel, hydrocarbon fuel oil (HFO), mixture oil lubricant and fuel oil (MOLFO) and waste oil (WO) dominate the oil types with a total variance of 99.51% with ANOVA giving F stat >F critical at 95% confidence level and a Chi Square goodness test of 74.87. Results obtained from this study reveals that by employing six-sigma approach in a data-driven problem such as in the case of oil spill classification, good decision making can be expedited. Copyright © 2017. Published by Elsevier Ltd.

  10. CO2 Emissions in an Oil Palm Plantation on Tropical Peat in Malaysia

    NASA Astrophysics Data System (ADS)

    Leclerc, M.; Zhang, G.; Jantan, N. M.; Harun, M. H.; Kamarudin, N.; Choo, Y. M.

    2016-12-01

    Tropical peats are large contributors to greenhouse gas emissions and differ markedly from their counterparts at temperate latitudes. The rapid deforestation and subsequent land conversion of tropical virgin forests in Southeast Asia have been decried by environmental groups worldwide even though there is currently little robust scientific evidence to ascertain the net amount of greenhouse gas released to the atmosphere. The conversion to oil palm plantation at a large scale further exacerbates the situation. This paper shows preliminary data on CO2 emissions in a converted oil palm plantation grown on tropical peat in northeast Malaysia.

  11. Comparative effects of dietary corn oil, safflower oil, fish oil and palm oil on metabolism of ethanol and carnitine in the rat.

    PubMed

    Sachan, Dileep S; Yatim, Ayub M; Daily, James W

    2002-06-01

    This study was launched to determine comparative effects of corn oil (CO), safflower oil (SO), fish oil (FO) and palm oil (PO) on carnitine status and ethanol metabolism in rats. Twenty-four male Sprague-Dawley rats (300 g bw) were randomly divided into four groups (n = 6) and fed a semisynthetic diets containing fat as oils listed above. Blood and 24 hour urine samples were collected before and after dietary treatment and acute ethanol administration. Samples were analyzed for blood-ethanol concentration (BEC) and carnitine species. The diets containing FO and PO retarded ethanol metabolism compared to the diets containing CO and SO. The effect of these dietary fats on carnitine species in plasma and urine was varied before and after dietary treatment and following a single oral ethanol dose. The liver carnitine content was higher in the PO group after dietary and ethanol treatment. It is concluded that attenuation of ethanol clearance was related to unique fatty acid makeup of the oils that in part may be attributed to the composite ratio of saturated to unsaturated fatty acids in the oils.

  12. Geochemical analysis of potash mine seep oils, collapsed breccia pipe oil shows and selected crude oils, Eddy County, New Mexico

    USGS Publications Warehouse

    Palacas, J.G.; Snyder, R.P.; Baysinger, J.P.; Threlkeld, C.N.

    1982-01-01

    Oil shows, in the form of oil stains and bleeding oil, in core samples from two breccia pipes, Hills A and C, Eddy County, New Mexico, and seepage oils in a potash mine near Hill C breccia pipe are geochemically similar. The geochemical similarities strongly suggest that they belong to the same family of oils and were derived from similar sources. The oils are relatively high in sulfur (0.89 to 1.23 percent), rich in hydrocarbons (average 82 percent), relatively high in saturated hydrocarbon/aromatic hydrocarbon ratios (average 2.9), and based on analysis of seep oils alone, have a low API gravity (average 19.4?). The oils are for the most part severely biodegraded as attested by the loss of n-paraffin molecules. Geochemical comparison of seven crude oils collected in the vicinity of the breccia pipes indicates that the Yates oils are the likely source of the above family of oils. Six barrels of crude oil that were dumped into a potash exploration borehole near Hill C breccia pipe, to release stuck casing, are considered an unlikely source of the breccia pipe and mine seep oils. Volumetric and hydrodynamic constraints make it highly improbable that such a small volume of 'dumped' oil could migrate over distances ranging from about 600 feet to 2.5 miles to the sites of the oil shows.

  13. Effects of emulsifier addition on the crystallization and melting behavior of palm olein and coconut oil.

    PubMed

    Maruyama, Jessica Mayumi; Soares, Fabiana Andreia Schafer De Martini; D'Agostinho, Natalia Roque; Gonçalves, Maria Inês Almeida; Gioielli, Luiz Antonio; da Silva, Roberta Claro

    2014-03-12

    Two commercial emulsifiers (EM1 and EM2), containing predominantly monoacylglycerols (MAGs), were added in proportiond of 1.0 and 3.0% (w/w) to coconut oil and palm olein. EM1 consisted of approximately 90% MAGs, whereas EM2 consisted of approximately 50% MAGs. The crystallization behavior of these systems was evaluated by differential scanning calorimetry (DSC) and microscopy under polarized light. On the basis of DSC results, it was clear that the addition of EM2 accelerated the crystallization of coconut oil and delayed the crystallization of palm olein. In both oils EM2 addition led to the formation of smaller spherulites, and these effects improved the possibilities for using these fats as ingredients. In coconut oil the spherulites were maintained even at higher temperatures (20 °C). The addition of EM1 to coconut oil changed the crystallization pattern. In palm olein, the addition of 3.0% (w/w) of this emulsifier altered the pattern of crystallization of this fat.

  14. Continuous, high-flux and efficient oil/water separation assisted by an integrated system with opposite wettability

    NASA Astrophysics Data System (ADS)

    Li, Jian; Long, Yifei; Xu, Changcheng; Tian, Haifeng; Wu, Yanxia; Zha, Fei

    2018-03-01

    To resolve the drawbacks that single-mesh involved for oil/water separation, such as batch processing mode, only one phase was purified and the quick decrease in flux et al., herein, a two-way separation T-tube device was designed by integrating a pair of meshes with opposite wettability, i.e., underwater superoleophobic and superhydrophobic/superoleophilic properties. Such integrated system can continuously separate both oil and water phase from the oil/water mixtures simultaneously through one-step procedure with high flux (above 3.675 L m-2 s-1) and high separation efficiency larger than 99.8% regardless of the heavy oil or light oil involved in the mixture. Moreover, the as-prepared two meshes still maintained high separation efficiency larger than above 98.9% even after 50 cycle-usages. It worthy mentioned that this two-way separation mode essentially solves the oil liquid accumulation problem that is the single separation membrane needs to tolerate a large hydrostatic pressure caused by the accumulated liquid. We deeply believe this two-way separation system would provide a new strategy for realizing practical applications in oil spill clean-up via a continuous mode.

  15. An in vitro Comparative Evaluation of Efficacy of Disinfecting Ability of Garlic Oil, Neem Oil, Clove Oil, and Tulsi Oil with autoclaving on Endodontic K Files tested against Enterococcus faecalis.

    PubMed

    Hugar, Shivayogi; M Patel, Punit; Nagmoti, Jyoti; Uppin, Chaitanya; Mistry, Laresh; Dhariwal, Neha

    2017-01-01

    To comparatively evaluate the efficacy of disinfecting ability of garlic oil, neem oil, clove oil, and tulsi oil with autoclaving on endodontic K files tested against Enterococcus faecalis. Fifty endodontic K files were exposed to the test micro-organism and checked for its disinfecting ability using three different methods. Garlic oil, clove oil, tulsi oil and autoclave showed considerable effectiveness against E. faecalis except neem oil. Garlic oil, clove oil and tulsi oil are an effective disinfectant and can be used as an alternative to autoclaving against the test micro-organism. Herbs and herbal extracts are a natural and harmless way of controlling infection. These products are readily available and comparable to gold standard, thus can have its applications in rural India. Hugar S, Patel PM, Nagmoti J, Uppin C, Mistry L, Dhariwal N. An in vitro Comparative Evaluation of Efficacy of Disinfecting Ability of Garlic Oil, Neem Oil, Clove Oil, and Tulsi Oil with autoclaving on Endodontic K Files tested against Enterococcus faecalis. Int J Clin Pediatr Dent 2017;10(3):283-288.

  16. Moringa oleifera Seeds and Oil: Characteristics and Uses for Human Health.

    PubMed

    Leone, Alessandro; Spada, Alberto; Battezzati, Alberto; Schiraldi, Alberto; Aristil, Junior; Bertoli, Simona

    2016-12-20

    Moringa oleifera seeds are a promising resource for food and non-food applications, due to their content of monounsaturated fatty acids with a high monounsaturated/saturated fatty acids (MUFA/SFA) ratio, sterols and tocopherols, as well as proteins rich in sulfated amino acids. The rapid growth of Moringa trees in subtropical and tropical areas, even under conditions of prolonged drought, makes this plant a reliable resource to enhance the nutritional status of local populations and, if rationalized cultivation practices are exploited, their economy, given that a biodiesel fuel could be produced from a source not in competition with human food crops. Despite the relatively diffuse use of Moringa seeds and their oil in traditional medicine, no pharmacological activity study has been conducted on humans. Some encouraging evidence, however, justifies new efforts to obtain clear and definitive information on the benefits to human health arising from seed consumption. A critical review of literature data concerning the composition of Moringa oil has set in motion a plan for future investigations. Such investigations, using the seeds and oil, will focus on cultivation conditions to improve plant production, and will study the health effects on human consumers of Moringa seeds and their oil.

  17. Adaptation and impairment of DNA repair function in pollen of Betula verrucosa and seeds of Oenothera biennis from differently radionuclide-contaminated sites of Chernobyl.

    PubMed

    Boubriak, I I; Grodzinsky, D M; Polischuk, V P; Naumenko, V D; Gushcha, N P; Micheev, A N; McCready, S J; Osborne, D J

    2008-01-01

    The plants that have remained in the contaminated areas around Chernobyl since 1986 encapsulate the effects of radiation. Such plants are chronically exposed to radionuclides that they have accumulated internally as well as to alpha-, beta- and gamma-emitting radionuclides from external sources and from the soil. This radiation leads to genetic damage that can be countered by DNA repair systems. The objective of this study is to follow DNA repair and adaptation in haploid cells (birch pollen) and diploid cells (seed embryos of the evening primrose) from plants that have been growing in situ in different radionuclide fall-out sites in monitored regions surrounding the Chernobyl explosion of 1986. Radionuclide levels in soil were detected using gamma-spectroscopy and radiochemistry. DNA repair assays included measurement of unscheduled DNA synthesis, electrophoretic determination of single-strand DNA breaks and image analysis of rDNA repeats after repair intervals. Nucleosome levels were established using an ELISA kit. Birch pollen collected in 1987 failed to perform unscheduled DNA synthesis, but pollen at gamma/beta-emitter sites has now recovered this ability. At a site with high levels of combined alpha- and gamma/beta-emitters, pollen still exhibits hidden damage, as shown by reduced unscheduled DNA synthesis and failure to repair lesions in rDNA repeats properly. Evening primrose seed embryos generated on plants at the same gamma/beta-emitter sites now show an improved DNA repair capacity and ability to germinate under abiotic stresses (salinity and accelerated ageing). Again those from combined alpha- and gamma/beta-contaminated site do not show this improvement. Chronic irradiation at gamma/beta-emitter sites has provided opportunities for plant cells (both pollen and embryo cells) to adapt to ionizing irradiation and other environmental stresses. This may be explained by facilitation of DNA repair function.

  18. Adaptation and Impairment of DNA Repair Function in Pollen of Betula verrucosa and Seeds of Oenothera biennis from Differently Radionuclide-contaminated Sites of Chernobyl

    PubMed Central

    Boubriak, I. I.; Grodzinsky, D. M.; Polischuk, V. P.; Naumenko, V. D.; Gushcha, N. P.; Micheev, A. N.; McCready, S. J.; Osborne, D. J.

    2008-01-01

    Background and Aims The plants that have remained in the contaminated areas around Chernobyl since 1986 encapsulate the effects of radiation. Such plants are chronically exposed to radionuclides that they have accumulated internally as well as to α-, β- and γ-emitting radionuclides from external sources and from the soil. This radiation leads to genetic damage that can be countered by DNA repair systems. The objective of this study is to follow DNA repair and adaptation in haploid cells (birch pollen) and diploid cells (seed embryos of the evening primrose) from plants that have been growing in situ in different radionuclide fall-out sites in monitored regions surrounding the Chernobyl explosion of 1986. Methods Radionuclide levels in soil were detected using gamma-spectroscopy and radiochemistry. DNA repair assays included measurement of unscheduled DNA synthesis, electrophoretic determination of single-strand DNA breaks and image analysis of rDNA repeats after repair intervals. Nucleosome levels were established using an ELISA kit. Key Results Birch pollen collected in 1987 failed to perform unscheduled DNA synthesis, but pollen at γ/β-emitter sites has now recovered this ability. At a site with high levels of combined α- and γ/β-emitters, pollen still exhibits hidden damage, as shown by reduced unscheduled DNA synthesis and failure to repair lesions in rDNA repeats properly. Evening primrose seed embryos generated on plants at the same γ/β-emitter sites now show an improved DNA repair capacity and ability to germinate under abiotic stresses (salinity and accelerated ageing). Again those from combined α- and γ/β-contaminated site do not show this improvement. Conclusions Chronic irradiation at γ/β-emitter sites has provided opportunities for plant cells (both pollen and embryo cells) to adapt to ionizing irradiation and other environmental stresses. This may be explained by facilitation of DNA repair function. PMID:17981881

  19. Comparative Effect of Dietary Soybean Oil, Fish Oil, and Coconut Oil on Performance, Egg Quality and Some Blood Parameters in Laying Hens.

    PubMed

    Dong, X F; Liu, S; Tong, J M

    2018-04-14

    Two hundred and sixteen 28-wk-old Hy-line laying hens were randomly distributed to three dietary treatments and fed 1of 3 diets containing 8% soybean oil, fish oil, or coconut oil from 28 to 47 wk of age to investigate comparative effect of dietary soybean oil, fish oil, and coconut oil on the performance, egg quality and blood malondialdehyde (MDA), aspartate transaminase (AST) and uric acid (UA). Hens fed fish oil showed poor performance compared with soybean oil or coconut oil, and especially egg weight throughout the trial was significantly and consistently decreased (P < 0.05) due to dietary fish oil. Unexpectedly, shell reflectivity throughout the majority of the trial was consistently and significantly higher (P < 0.05) when hens fed fish oil than that when fed soybean oil or coconut oil. Dietary treatments affected (P < 0.05) shell shape at 4 of 8 time points tested. Average shell shape in fish oil treatment was higher (P < 0.05) than that of coconut oil group. Albumen height, Haugh unit and yolk color were influenced by dietary treatments only at 1 or 2 time points. However, average albumen height and Haugh unit in fish oil treatment were higher (P < 0.05) than that of soybean oil or coconut oil treatments and average yolk color in coconut oil treatment was higher (P < 0.05) than that of soybean oil group. Serum MDA, AST and UA concentrations were increased (P < 0.05) by fish oil during the majority of the first 2 mo of the trial. These data suggested that the inclusion of fish oil into feed may reduce the performance of laying hens, especially the egg weight, decrease the intensity of egg brown color and increase blood MDA, AST and UA levels compared with soybean oil or coconut oil. As a result, hens fed fish oil may lay smaller, longer and lighter-brown eggs whereas those fed coconut oil produce blunter and darker-brown eggs relative to soybean oil.

  20. Biomass analysis at palm oil factory as an electric power plant

    NASA Astrophysics Data System (ADS)

    Yusniati; Parinduri, Luthfi; Krianto Sulaiman, Oris

    2018-04-01

    Biomassa found in palm oil mill industryis a by-product such as palm shell, fiber, empty fruit bunches and pome. The material can be used as an alternative fuel for fossil fuel. On PTPN IVpalm oil millDolokSinumbah with a capacity of 30 tons tbs/hour of palm fruit fiber and palm shells has been utilized as boiler fuel to produce steam to supplyboilers power plant. With this utilization, the use of generators that using fossil fuel can be reduced, this would provide added value for the company. From the analysis, the fiber and shell materials were sufficient to supply 18 tons/hoursteam for the boiler. Shell material even excess as much as 441,5 tons per month. By utilizing the 2 types of biomass that is available alone, the electricity needs of the factory of 734 Kwh can be met. While other materials such as empty bunches and pome can be utilized to increase the added value and profitability for the palm oil mill.

  1. Oil spill environmental forensics: the Hebei Spirit oil spill case.

    PubMed

    Yim, Un Hyuk; Kim, Moonkoo; Ha, Sung Yong; Kim, Sunghwan; Shim, Won Joon

    2012-06-19

    After the Hebei Spirit oil spill (HSOS) in December 2007, mixtures of three types of Middle East crude oil (total 12,547 kL) were stranded along 375 km of coastline in Western Korea. Emergency responses together with 1.3 million volunteers' activity rapidly removed ca. 20% of spilled oil but the lingering oils have been found along the heavily impacted shorelines for more than 4 years. The HSOS was the worst oil spill case in Republic of Korea, and there were many issues and lessons to be shared. In this study, we summarized some of the oil spill environmental forensic issues that were raised after the HSOS. Rapid screening using on-site measurement, long-term monitoring of multimedia, fingerprinting challenges and evaluation of the extent of the submerged oil were introduced, which supported decision making process of oil spill cleanup, mitigation of debates among stakeholders and provided scientific backgrounds for reasonable compensation.

  2. [Efficiency evaluation of capsaicinoids to discriminate bio-waste oils from edible vegetable oils].

    PubMed

    Mao, Lisha; Liu, Honghe; Kang, Li; Jiang, Jie; Liao, Shicheng; Liu, Guihua; Deng, Pingjian

    2014-07-01

    To evaluate the efficiency of capsaicinoids to discriminate bio-waste oil from edible vegetable oil. 14 raw vegetable oils, 24 fried waste oils, 34 kitchen-waste oils, 32 edible non-peanut vegetable oil, 32 edible peanuts oil, 16 edible oil add flavorand and 11 refined bio-waste oils were prepared and examined for capsaicinoids including capsaicin, dihydrocapsaicin and nonylic acid vanillylamide. The detection results of the above samples were statistically tested based on sample category to assessment identify the effectiveness of the bio-waste oils with capsaicinoids. As a indicator, capsaincin was possessed of high detection sensitivity and has the highest efficiency to discern kitchen-waste oils and refined bio-waste oils samples from edible non-peanut vegetable oil correctly. The accuracy rate of identification were 100% and 90.1% respectively. There is the background in peanut oil. CONCLUSION Capsaicin added in cooking process can be retained in the refining process and hardly be removed in the refining process. In the case of fully eliminating the background interference, capsaicinoids can effectively identify bio-waste oils and edible vegetable oil in combination.

  3. Myristica oil poisoning

    MedlinePlus

    Nutmeg oil; Myristicin ... Myristica oil ( Myristica fragrans ) can be harmful. It comes from the seed of a nutmeg. ... Myristica oil is found in: Aromatherapy products Mace Nutmeg Other products may also contain myristica oil.

  4. Development of an In Situ Biosurfactant Production Technology for Enhanced Oil Recovery

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    M.J. McInerney; R.M. Knapp; Kathleen Duncan

    The long-term economic potential for enhanced oil recovery (EOR) is large with more than 300 billion barrels of oil remaining in domestic reservoirs after conventional technologies reach their economic limit. Actual EOR production in the United States has never been very large, less than 10% of the total U. S. production even though a number of economic incentives have been used to stimulate the development and application of EOR processes. The U.S. DOE Reservoir Data Base contains more than 600 reservoirs with over 12 billion barrels of unrecoverable oil that are potential targets for microbially enhanced oil recovery (MEOR). Ifmore » MEOR could be successfully applied to reduce the residual oil saturation by 10% in a quarter of these reservoirs, more than 300 million barrels of oil could be added to the U.S. oil reserve. This would stimulate oil production from domestic reservoirs and reduce our nation's dependence on foreign imports. Laboratory studies have shown that detergent-like molecules called biosurfactants, which are produced by microorganisms, are very effective in mobilizing entrapped oil from model test systems. The biosurfactants are effective at very low concentrations. Given the promising laboratory results, it is important to determine the efficacy of using biosurfactants in actual field applications. The goal of this project is to move biosurfactant-mediated oil recovery from laboratory investigations to actual field applications. In order to meet this goal, several important questions must be answered. First, it is critical to know whether biosurfactant-producing microbes are present in oil formations. If they are present, then it will be important to know whether a nutrient regime can be devised to stimulate their growth and activity in the reservoir. If biosurfactant producers are not present, then a suitable strain must be obtained that can be injected into oil reservoirs. We were successful in answering all three questions. The specific

  5. Making rice even healthier!

    USDA-ARS?s Scientific Manuscript database

    Rice is a naturally healthy food, but what if it could be made even healthier? Would Americans eat more rice if it could be advertised to be a 'New and Improved' source of calcium to promote bone growth, or iron to prevent anemia? Grocery stores are full of foods that are vitamin enhanced to attract...

  6. Synergistic degradation of crude oil by indigenous bacterial consortium and exogenous fungus Scedosporium boydii.

    PubMed

    Yuan, Xiaoyu; Zhang, Xinying; Chen, Xueping; Kong, Dewen; Liu, Xiaoyan; Shen, Siyuan

    2018-05-19

    The purpose of this study was to investigate the potential of defined co-culture of indigenous bacterial consortium and exogenous fungus Scedosporium boydii for biodegradation of crude oil. After 7 days of incubation, residual oil, n-alkanes and aromatic fraction were analyzed. The degradation rate of crude oil was increased from 61.06% to 81.45% by the defined co-culture according to the 3:1 inoculation ratio of bacteria to fungi. The microbial activity was enhanced markedly and the formation of biofilms was accelerated after suitable inoculation of Scedosporium boydii. High throughput analysis showed that bacterial evenness and diversity were increased and the relative abundance of Paraburkholderia tropica was increased observably from 7.67% to 56.13% in the defined co-culture. These results indicated that synergistic degradation of crude oil in the bacteria-fungi consortium may be advantageous for bioremediation of petroleum-contaminated site. Copyright © 2018 Elsevier Ltd. All rights reserved.

  7. Evaluation of Biomass-Derived Distillate Fuel as Renewable Heating Oil

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mante, Ofei D.; Butcher, Thomas A.; Wei, George

    The utilization of advanced biofuels in stationary applications, such as home heating, is considered as an early entry point for biomass-derived fuels into the distillate fuel market sector. Two renewable fuels produced by a biomass fluidized catalytic cracking (BFCC) process, followed by hydroprocessing and fractionation, were tested. The evaluation was performed on a pure (100%) distillate fraction, 50% blend of the distillate fraction with petroleum-based heating oil, and 20% blend of a heavier gas oil fraction. Combustion experiments were carried out in a transparent quartz chamber and a typical oil-fired residential boiler. The flame stability, size, and shape produced bymore » the fuels were examined. The flue gas was analyzed for O 2, CO, NO x, and smoke. The elastomer compatibility test was performed with nitrile slabs at 43 °C for 1 month. Fuel stability was examined at 80 °C for 1 week. The results from the combustion studies suggest that the distillate fuel blends could be used as alternative fuels to No. 2 heating oil, even up to 100% without any operational issues. The distillate fuels were found to be stable. and the nitrile slab volume swell (~10%) suggests that the fuel could be compatible to legacy elastomers.« less

  8. Evaluation of Biomass-Derived Distillate Fuel as Renewable Heating Oil

    DOE PAGES

    Mante, Ofei D.; Butcher, Thomas A.; Wei, George; ...

    2015-09-18

    The utilization of advanced biofuels in stationary applications, such as home heating, is considered as an early entry point for biomass-derived fuels into the distillate fuel market sector. Two renewable fuels produced by a biomass fluidized catalytic cracking (BFCC) process, followed by hydroprocessing and fractionation, were tested. The evaluation was performed on a pure (100%) distillate fraction, 50% blend of the distillate fraction with petroleum-based heating oil, and 20% blend of a heavier gas oil fraction. Combustion experiments were carried out in a transparent quartz chamber and a typical oil-fired residential boiler. The flame stability, size, and shape produced bymore » the fuels were examined. The flue gas was analyzed for O 2, CO, NO x, and smoke. The elastomer compatibility test was performed with nitrile slabs at 43 °C for 1 month. Fuel stability was examined at 80 °C for 1 week. The results from the combustion studies suggest that the distillate fuel blends could be used as alternative fuels to No. 2 heating oil, even up to 100% without any operational issues. The distillate fuels were found to be stable. and the nitrile slab volume swell (~10%) suggests that the fuel could be compatible to legacy elastomers.« less

  9. Detection and quantification of adulteration in sandalwood oil through near infrared spectroscopy.

    PubMed

    Kuriakose, Saji; Thankappan, Xavier; Joe, Hubert; Venkataraman, Venkateswaran

    2010-10-01

    The confirmation of authenticity of essential oils and the detection of adulteration are problems of increasing importance in the perfumes, pharmaceutical, flavor and fragrance industries. This is especially true for 'value added' products like sandalwood oil. A methodical study is conducted here to demonstrate the potential use of Near Infrared (NIR) spectroscopy along with multivariate calibration models like principal component regression (PCR) and partial least square regression (PLSR) as rapid analytical techniques for the qualitative and quantitative determination of adulterants in sandalwood oil. After suitable pre-processing of the NIR raw spectral data, the models are built-up by cross-validation. The lowest Root Mean Square Error of Cross-Validation and Calibration (RMSECV and RMSEC % v/v) are used as a decision supporting system to fix the optimal number of factors. The coefficient of determination (R(2)) and the Root Mean Square Error of Prediction (RMSEP % v/v) in the prediction sets are used as the evaluation parameters (R(2) = 0.9999 and RMSEP = 0.01355). The overall result leads to the conclusion that NIR spectroscopy with chemometric techniques could be successfully used as a rapid, simple, instant and non-destructive method for the detection of adulterants, even 1% of the low-grade oils, in the high quality form of sandalwood oil.

  10. Evaluation of sensor arrays for engine oils using artificial oil alteration

    NASA Astrophysics Data System (ADS)

    Sen, Sedat; Schneidhofer, Christoph; Dörr, Nicole; Vellekoop, Michael J.

    2011-06-01

    With respect to varying operation conditions, only sensors directly installed in the engine can detect the current oil condition hence enabling to get the right time for the oil change. Usually, only one parameter is not sufficient to obtain reliable information about the current oil condition. For this reason, appropriate sensor principles were evaluated for the design of sensor arrays for the measurement of critical lubricant parameters. In this contribution, we report on the development of a sensor array for engine oils using laboratory analyses of used engine oils for the correlation with sensor signals. The sensor array comprises the measurement of conductivity, permittivity, viscosity and temperature as well as oil corrosiveness as a consequence of acidification of the lubricant. As a key method, rapid evaluation of the sensors was done by short term simulation of entire oil change intervals based on artificial oil alteration. Thereby, the compatibility of the sensor array to the lubricant and the oil deterioration during the artificial alteration process was observed by the sensors and confirmed by additional laboratory analyses of oil samples take.

  11. What oil changers in America are doing with their used oil

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Arner, R.; O'Hare, M.

    Each year, the US generates 1.378 billion gallons of used oil, with just 57% of this oil accounted for by recycling. The most significant types of used oil disposition come from the very small generator or the so called do-it-yourselfer (DIY). The DIY is an individual who removes used oil from a motor vehicle, utility engine, or piece of farm equipment that he or she owns and operates. Numerous retailers have shown that accepting DIY used oil translates into good public relations and business. First Recovery/Valvoline conducted a recent study of its 2,000 auto parts stores that collect used oil.more » Sixty-five percent of their customers who returned used oil made a special trip for its return and 44% of them purchased something at the store (average of $13 per customer) when they returned their used oil. The cost of accepting used oil was $85 per month for the 185-gallon indoor collection system including oil pickup. This public service stimulated an additional $429 per month in new revenue for the retailer.« less

  12. An in vitro Comparative Evaluation of Efficacy of Disinfecting Ability of Garlic Oil, Neem Oil, Clove Oil, and Tulsi Oil with autoclaving on Endodontic K Files tested against Enterococcus faecalis

    PubMed Central

    Hugar, Shivayogi; Nagmoti, Jyoti; Uppin, Chaitanya; Mistry, Laresh; Dhariwal, Neha

    2017-01-01

    Aim To comparatively evaluate the efficacy of disinfecting ability of garlic oil, neem oil, clove oil, and tulsi oil with autoclaving on endodontic K files tested against Enterococcus faecalis. Materials and methods Fifty endodontic K files were exposed to the test micro-organism and checked for its disinfecting ability using three different methods. Result Garlic oil, clove oil, tulsi oil and autoclave showed considerable effectiveness against E. faecalis except neem oil. Conclusion Garlic oil, clove oil and tulsi oil are an effective disinfectant and can be used as an alternative to autoclaving against the test micro-organism. Clinical Significance Herbs and herbal extracts are a natural and harmless way of controlling infection. These products are readily available and comparable to gold standard, thus can have its applications in rural India. How to cite this article Hugar S, Patel PM, Nagmoti J, Uppin C, Mistry L, Dhariwal N. An in vitro Comparative Evaluation of Efficacy of Disinfecting Ability of Garlic Oil, Neem Oil, Clove Oil, and Tulsi Oil with autoclaving on Endodontic K Files tested against Enterococcus faecalis. Int J Clin Pediatr Dent 2017;10(3):283-288. PMID:29104390

  13. Virgin coconut oil improves hepatic lipid metabolism in rats--compared with copra oil, olive oil and sunflower oil.

    PubMed

    Arunima, S; Rajamohan, T

    2012-11-01

    Effect of virgin coconut oil (VCO) on lipid levels and regulation of lipid metabolism compared with copra oil (CO), olive oil (OO), and sunflower oil (SFO) has been reported. Male Sprague-Dawley rats were fed different oils at 8% level for 45 days along with synthetic diet. Results showed that VCO feeding significantly lowered (P < 0.05) levels of total cholesterol, LDL+ VLDL cholesterol, Apo B and triglycerides in serum and tissues compared to rats fed CO, OO and SFO, while HDL-cholesterol and Apo A1 were significantly (P < 0.05) higher in serum of rats fed VCO than other groups. Hepatic lipogenesis was also down regulated in VCO fed rats, which was evident from the decreased activities of enzymes viz., HMG CoA reductase, glucose-6-phosphate dehydrogenase, isocitrate dehydrogenase and malic enzyme. In addition, VCO significantly (P < 0.05) increased the activities of lipoprotein lipase, lecithin cholesterol acyl transferase and enhanced formation of bile acids. Results demonstrated hypolipidemic effect of VCO by regulating the synthesis and degradation of lipids.

  14. Recycling used palm oil and used engine oil to produce white bio oil, bio petroleum diesel and heavy fuel

    NASA Astrophysics Data System (ADS)

    Al-abbas, Mustafa Hamid; Ibrahim, Wan Aini Wan; Sanagi, Mohd. Marsin

    2012-09-01

    Recycling waste materials produced in our daily life is considered as an additional resource of a wide range of materials and it conserves the environment. Used engine oil and used cooking oil are two oils disposed off in large quantities as a by-product of our daily life. This study aims at providing white bio oil, bio petroleum diesel and heavy fuel from the disposed oils. Toxic organic materials suspected to be present in the used engine oil were separated using vacuum column chromatography to reduce the time needed for the separation process and to avoid solvent usage. The compounds separated were detected by gas chromatography-mass spectrometry (GC-MS) and found to contain toxic aromatic carboxylic acids. Used cooking oils (thermally cracked from usage) were collected and separated by vacuum column chromatography. White bio oil produced was examined by GC-MS. The white bio oil consists of non-toxic hydrocarbons and is found to be a good alternative to white mineral oil which is significantly used in food industry, cosmetics and drugs with the risk of containing polycyclic aromatic compounds which are carcinogenic and toxic. Different portions of the used cooking oil and used engine were mixed to produce several blends for use as heavy oil fuels. White bio oil was used to produce bio petroleum diesel by blending it with petroleum diesel and kerosene. The bio petroleum diesel produced passed the PETRONAS flash point and viscosity specification test. The heat of combustion of the two blends of heavy fuel produced was measured and one of the blends was burned to demonstrate its burning ability. Higher heat of combustion was obtained from the blend containing greater proportion of used engine oil. This study has provided a successful recycled alternative for white bio oil, bio petroleum fuel and diesel which can be an energy source.

  15. Adverse Phototoxic Effect of Essential Plant Oils on NIH 3T3 Cell Line after UV Light Exposure.

    PubMed

    Binder, Svatopluk; Hanáková, Adéla; Tománková, Kateřina; Pížová, Klára; Bajgar, Robert; Manišová, Barbora; Kejlová, Kristina; Bendová, Hana; Jírová, Dagmar; Kolářová, Hana

    2016-09-01

    Natural or artificial substances have become an inseparable part of our lives. It is questionable whether adequate testing has been performed in order to ensure these substances do not pose a serious health risk. The principal aim of our research was to clarify the potential risk of adding essential oils to food, beverages and cosmetic products. The toxicity of substances frequently employed in cosmetics, aromatherapy and food industry (bergamot oil, Litsea cubeba oil, orange oil, citral) were investigated using cell line NIH3T3 (mouse fibroblasts) with/without UV irradiation. The MTT assay was used to estimate the cell viability. Reactive oxygen species (ROS) which are products of a number of natural cellular processes such as oxygen metabolism and inflammation were measured to determine the extent of cellular stress. DNA damage caused by strand breaks was examined by comet assay. MTT test determined EC50 values for all tested substances, varying from 0.0023% v/v for bergamot oil to 0.018% v/v for citral. ROS production measurement showed that UV radiation induces oxidative stress to the cell resulting in higher ROS production compared to the control and non-irradiated samples. Comet assay revealed that both groups (UV, without UV) exert irreversible DNA damage resulting in a cell death. Our findings suggest that even low concentrations (lower than 0.0464% v/v) of orange oil can be considered as phototoxic (PIF value 8.2) and probably phototoxic for bergamot oil (PIF value 4.6). We also found significant changes in the cell viability, the ROS production and the DNA after the cells were exposed to the tested chemicals. Even though these substances are widely used as antioxidants it should be noted that they present a risk factor and their use in cosmetic and food products should be minimized. Copyright© by the National Institute of Public Health, Prague 2016

  16. Even Superheroes Need Help

    ERIC Educational Resources Information Center

    Sussman, Mel

    2018-01-01

    It is not clear exactly when school leaders first started wearing an "S" on their chests and began defiantly uttering the phrase, "I can do it all myself!" But after days, weeks, months, or even years of racing wildly from task to task, many a superhero principal has come to the stark realization that nothing could be further…

  17. Teaching Large Evening Classes

    ERIC Educational Resources Information Center

    Wambuguh, Oscar

    2008-01-01

    High enrollments, conflicting student work schedules, and the sheer convenience of once-a-week classes are pushing many colleges to schedule evening courses. Held from 6 to 9 pm or 7 to 10 pm, these classes are typically packed, sometimes with more than 150 students in a large lecture theater. How can faculty effectively teach, control, or even…

  18. Comparative study of cinnamon oil and clove oil on some oral microbiota.

    PubMed

    Gupta, Charu; Kumari, Archana; Garg, A Pankaj; Catanzaro, R; Marotta, F

    2011-12-01

    A comparative study was carried out between cinnamon oil and clove oil on the oral micro-biota causing dental caries. Cinnamon oil was found to be more effective than clove oil exhibiting broad spectrum of antibacterial activity inhibiting all the ten test bacterial species involved in dental caries. Cinnamon oil produced maximum inhibition zone of diameter (IZD) of 24.0 mm against Streptococcus mutans (major causative bacteria of dental plaque) as compared to clove oil (IZD = 13.0mm). This is contrary to the popular belief that clove oil is effective in tooth decay and dental plaque. This study shows the potential of cinnamon oil over clove oil in the treatment of dental caries. (www.actabiomedica.it).

  19. Oil Shale

    USGS Publications Warehouse

    Birdwell, Justin E.

    2017-01-01

    Oil shales are fine-grained sedimentary rocks formed in many different depositional environments (terrestrial, lacustrine, marine) containing large quantities of thermally immature organic matter in the forms of kerogen and bitumen. If defined from an economic standpoint, a rock containing a sufficient concentration of oil-prone kerogen to generate economic quantities of synthetic crude oil upon heating to high temperatures (350–600 °C) in the absence of oxygen (pyrolysis) can be considered an oil shale.

  20. Antimicrobial activity of the essential oils of Thymus vulgaris L. measured using a bioimpedometric method.

    PubMed

    Marino, M; Bersani, C; Comi, G

    1999-09-01

    The essential oils obtained from Thymus vulgaris L. harvested at four ontogenetic stages were evaluated for their biological activity and chemical composition. The thyme essential oils were tested for their inhibitory effects against nine strains of gram-negative bacteria and six strains of gram-positive bacteria. The bioimpedance method was chosen for studying the antibacterial activity of the essential oils and the parameter chosen for defining and quantifying the antibacterial activity of the essential oils was the detection time. The plate counting technique was used to study the inhibitory effect by direct contact. All the thyme essential oils examined had a significant bacteriostatic activity against the microorganisms tested. This activity was more marked against the gram-positive bacteria. The oil from thyme in full flower was the most effective at stopping the growth of the microbial species examined. The oils tested were also shown to have good antibacterial activity by direct contact, which appeared to be more marked against the gram-negative bacteria. Only a few of the species were capable of recovering at least 50% of their metabolic function after contact with the inhibitor, while most of the strains were shown to have been inactivated almost completely. Escherichia coli O157:H7 was the most sensitive species, given that after contact with even the lowest concentration of oil cells could not be recovered.

  1. Modified montmorillonite clay microparticles for stable oil-in-seawater emulsions.

    PubMed

    Dong, Jiannan; Worthen, Andrew J; Foster, Lynn M; Chen, Yunshen; Cornell, Kevin A; Bryant, Steven L; Truskett, Thomas M; Bielawski, Christopher W; Johnston, Keith P

    2014-07-23

    Environmentally benign clay particles are of great interest for the stabilization of Pickering emulsions. Dodecane-in-synthetic seawater (SSW) emulsions formed with montmorillonite (MMT) clay microparticles modified with bis(2-hydroxyethyl)oleylamine were stable against coalescence, even at clay concentrations down to 0.1% w/v. Remarkably, as little as 0.001% w/v surfactant lowered the hydrophilicity of the clay to a sufficient level for stabilization of oil-in-SSW emulsions. The favorable effect of SSW on droplet size reduction and emulsion stability enhancement is hypothesized to be due to reduced electrostatic repulsion between adsorbed clay particles and a consequent increase in the continuous phase (an aqueous clay suspension) viscosity. Water/oil (W/O) emulsions were inverted to O/W either by decreasing the mass ratio of surfactant-to-clay (transitional inversion) or by increasing the water volume fraction (catastrophic inversion). For both types of emulsions, coalescence was minimal and the sedimentation or creaming was highly correlated with the droplet size. For catastrophic inversions, the droplet size of the emulsions was smaller in the case of the preferred curvature. Suspensions of concentrated clay in oil dispersions in the presence of surfactant were stable against settling. The mass transfer pathways during emulsification of oil containing the clay particles were analyzed on the droplet size/stability phase diagrams to provide insight for the design of dispersant systems for remediating surface and subsurface oceanic oil spills.

  2. Oil Biodegradation and Oil-Degrading Microbial Populations in Marsh Sediments Impacted by Oil from the Deepwater Horizon Well Blowout.

    PubMed

    Atlas, Ronald M; Stoeckel, Donald M; Faith, Seth A; Minard-Smith, Angela; Thorn, Jonathan R; Benotti, Mark J

    2015-07-21

    To study hydrocarbon biodegradation in marsh sediments impacted by Macondo oil from the Deepwater Horizon well blowout, we collected sediment cores 18-36 months after the accident at the marshes in Bay Jimmy (Upper Barataria Bay), Louisiana, United States. The highest concentrations of oil were found in the top 2 cm of sediment nearest the waterline at the shorelines known to have been heavily oiled. Although petroleum hydrocarbons were detectable, Macondo oil could not be identified below 8 cm in 19 of the 20 surveyed sites. At the one site where oil was detected below 8 cm, concentrations were low. Residual Macondo oil was already highly weathered at the start of the study, and the concentrations of individual saturated hydrocarbons and polycyclic aromatic hydrocarbons continued to decrease over the course of the study due to biodegradation. Desulfococcus oleovorans, Marinobacter hydrocarbonoclasticus, Mycobacterium vanbaalenii, and related mycobacteria were the most abundant oil-degrading microorganisms detected in the top 2 cm at the oiled sites. Relative populations of these taxa declined as oil concentrations declined. The diversity of the microbial community was low at heavily oiled sites compared to that of the unoiled reference sites. As oil concentrations decreased over time, microbial diversity increased and approached the diversity levels of the reference sites. These trends show that the oil continues to be biodegraded, and microbial diversity continues to increase, indicating ongoing overall ecological recovery.

  3. Non-Petroleum Oils

    EPA Pesticide Factsheets

    These include synthetics such as silicone fluids and tung oils, wood-derivative oils such as resin/rosin, animal fats/oil, and seed oils. Many have similar physical properties to petroleum-based, such as water insolubility and formation of slicks.

  4. OIL SPILL AND OIL POLLUTION REPORTS

    EPA Science Inventory

    This issue contains summaries of articles, reports, patents, documents, and other materials relating to oil pollution published during the period 1974 to 1976. Subject coverage includes aquatic and terrestrial oil pollution with emphasis on the marine environment. A list of the p...

  5. Review of Anti-Inflammatory Herbal Medicines

    PubMed Central

    Ghasemian, Mona; Owlia, Sina; Owlia, Mohammad Bagher

    2016-01-01

    Medicinal plants and their secondary metabolites are progressively used in the treatment of diseases as a complementary medicine. Inflammation is a pathologic condition that includes a wide range of diseases such as rheumatic and immune-mediated conditions, diabetes, cardiovascular accident, and etcetera. We introduce some herbs which their anti-inflammatory effects have been evaluated in clinical and experimental studies. Curcuma longa, Zingiber officinale, Rosmarinus officinalis, Borago officinalis, evening primrose, and Devil's claw are some of the introduced medicinal herbs in this review. Since the treatment of inflammation is not a one-dimensional remedy, this review tries to reach a multidimensional therapeutic approach to inflammation with the help of herbal medicine and modification in lifestyle. PMID:27247570

  6. National Evaluation of the Even Start Family Literacy Program. Report on Even Start Projects for Indian Tribes and Tribal Organizations.

    ERIC Educational Resources Information Center

    Levin, Marjorie; Moss, Marc; Swartz, Janet; Khan, Sherry; Tarr, Hope

    The tribal Even Start program is one of the set-aside components of the U.S. Department of Education's Even Start Family Literacy Program. Even Start combines adult literacy, early childhood education, and parenting education services for parents eligible for adult education and their children from birth to age 7. In 1994-95, nine Indian tribes…

  7. The Oil Drop Experiment: Do Physical Chemistry Textbooks Refer to Its Controversial Nature?

    ERIC Educational Resources Information Center

    Niaz, Mansoor; Rodriguez, Maria A.

    2005-01-01

    Most general chemistry textbooks consider the oil drop experiment as a classic experiment, characterized by its simplicity and precise results. A review of the history and philosophy of science literature shows that the experiment is difficult to perform (even today!) and generated a considerable amount of controversy. Acceptance of the…

  8. Aniseed oil increases glucose absorption and reduces urine output in the rat.

    PubMed

    Kreydiyyeh, Sawsan Ibrahim; Usta, Julnar; Knio, Khuzama; Markossian, Sarine; Dagher, Shawky

    2003-12-19

    Anise (Pimpinella anisum) has been used as a traditional aromatic herb in many drinks and baked foods because of the presence of volatile oils in its fruits commonly known as seeds. Hot water extracts of the seeds have been used also in folk medicine for their diuretic and laxative effect, expectorant and anti-spasmodic action, and their ability to ease intestinal colic and flatulence. The aim of this work was to study the effect of aniseed oil on transport processes through intestinal and renal epithelia and determine its mechanism of action. The essential oils were extracted from the seeds by hydrodistillation and analyzed by gas chromatography. Aniseed oil enhanced significantly glucose absorption from the rat jejunum and increased the Na+-K+ ATPase activity in a jejunal homogenate in a dose dependent manner. The oil, however, exerted no effect on water absorption from the colon and did not alter the activity of the colonic Na+-K+ ATPase. When added to drinking water, it reduced the volume of urine produced in the rat and increased the activity of the renal Na+-K+ ATPase even at extremely low concentrations. It was concluded that aniseed oil increases glucose absorption by increasing the activity of the Na+-K+ ATPase and consequently the sodium gradient needed for the sugar transport. Its anti-diuretic effect is also mediated through a similar mechanism in the kidney whereby a stimulation of the Na+-K+ pump increases tubular sodium reabsorption and osmotic water movement. The colonic Na+-K+ ATPase was however, resistant to the oil.

  9. Chemical composition, anthelmintic, antibacterial and antioxidant effects of Thymus bovei essential oil.

    PubMed

    Jaradat, Nidal; Adwan, Lina; K'aibni, Shadi; Shraim, Naser; Zaid, Abdel Naser

    2016-10-26

    It has been recently recognized that oxidative stress, helminth and microbial infections are the cause of much illness found in the underdeveloped, developing and developed countries. The present study was undertaken to identify the chemical composition, and to assess anthelmintic, antimicrobial and antioxidant effects of Thymus bovei essential oil. The chemical composition of the essential oil was analyzed using gas chromatography mass spectrometry (GC-MS). Antimicrobial activity was tested against the selected strains from American Type Culture Collection (ATCC) and clinical isolates such as Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, Methicillin Resistant Staphylococcus aureus, Candida albicans using MIC assay. The anthelmintic assay was carried out on adult earthworm (Pheretima posthuma), while antioxidant activity was analyzed using the 2,2-diphenyl-1-picrylhydrazyl (DPPH) free radical scavenging method. Trans-geraniol (35.38 %), α-citral (20.37 %) and β-citral (14.76 %) were the major compounds comprising 70.51 % of the essential oil. Our results showed that T. bovei essential oil exhibited strong anthelmintic activity, even higher than piperazine citrate, the used reference standard, with potential antioxidant activity almost equal to the Trolox standard. Furthermore, T. bovei essential oil had powerful antibacterial and antifungal activities against the studied pathogens. Essential oil of T. bovei exerted excellent antioxidant, antimicrobial, and anthelmintic activities. Moreover, this study found that T. bovei volatile oil contains active substances that could potentially be used as natural preservatives in food and pharmaceutical industries, these substances could also be employed for developing new anthelmintic, antimicrobial and antioxidant agents.

  10. New woody and ambery notes from cedarwood and turpentine oil.

    PubMed

    Panten, Johannes; Bertram, Heinz-Jürgen; Surburg, Horst

    2004-12-01

    The development of a new product in the chemical industry is still driven by needs like technical properties, price/performance ratio, biodegradability, or product safety. However, in terms of improving more and more on ecological criteria, summarized under such catchphrases as sustainable development or green chemistry, another important aspect is to use renewable resources as starting materials. This is not significantly new in fragrance chemistry, and there are a lot of raw materials in the perfume oils that are derived from molecules of renewable resources. Two commonly used materials are: longifolene (from turpentine oil) and cedrene (from cedarwood oil). These compounds are very suitable for the synthesis of woody and ambery notes, and even though it seemed that all possibilities were exhausted, it is actually still feasible to discover new molecules with excellent olfactory properties such as Ambrocenide (50a), which is available in three steps from alpha-cedrene. Some of these molecules will be treated in this review, both with respect to synthesis as well as structural and sensory aspects.

  11. Essential oil composition and antiradical activity of the oil of Iraq plants.

    PubMed

    Kiralan, Mustafa; Bayrak, Ali; Abdulaziz, Omar Fawzi; Ozbucak, Tuğba

    2012-01-01

    This study examined the antiradical activity and chemical composition of essential oils of some plants grown in Mosul, Iraq. The essential oils of myrtle and parsley seed contained α-pinene (36.08% and 22.89%, respectively) as main constituents. Trans-Anethole was the major compound found in fennel and aniseed oils (66.98% and 93.51%, respectively). The dominant constituent of celery seed oil was limonene (76.63%). Diallyl disulphide was identified as the major component in garlic oil (36.51%). Antiradical activity was higher in garlic oil (76.63%) and lower in myrtle oil (39.23%). The results may suggest that some essential oils from Iraq possess compounds with antiradical activity, and these oils can be used as natural antioxidants in food applications.

  12. Characterisation of crude palm oil O/W emulsion produced with Tween 80 and potential in residual oil recovery of palm pressed mesocarp fibre

    NASA Astrophysics Data System (ADS)

    Ramly, N. H.; Zakaria, R.; Naim, M. N.

    2016-06-01

    Surfactant-assisted aqueous extraction has been proposed as a “green” alternative to hexane extraction for the recovery of oil from plant matters. An efficient aqueous surfactant extraction system usually use an extended type of ionic surfactant with the ability to produce Winsor type III microemulsion, reducing the interfacial tension (IFT) between plant oil and surfactant solution to an ultralow level (10-3 mN/m). However, the safe used of this surfactant in food processing is uncertain leading to non-food application of the recovered oil. In the present study, the potential of Tween 80, a commercial food-grade non-ionic surfactant, was evaluated in the recovery of residual oil from palm-pressed mesocarp. The emulsion produced between Tween 80 and crude palm oil (CPO) was characterised in terms of IFT, droplet size, viscosity and phase inversion temperature (PIT). The effect of surfactant concentration, electrolyte (NaCl) and temperature were studied to determine whether a Winsor Type III microemulsion can be produced. Results shows that although these parameters were able to reduce the IFT to very low values, Winsor type III microemulsion was not produced with this single surfactant. Emulsion of CPO and Tween 80 solution did not produce a PIT even after heating to 100°C indicating that middle phase emulsion was not able to be formed with increasing temperature. The highest percentage of oil extraction (38.84%) was obtained at the concentration above the critical micelle concentration (CMC) of Tween 80 and CPO, which was at 0.5 wt% Tween 80 with 6% NaCl, and temperature of 60°C. At this concentration, the IFT value is 0.253 mN/m with a droplet size of 4183.8 nm, and a viscosity of 7.38 cp.

  13. Development of karanja oil based offset printing ink in comparison with linseed oil.

    PubMed

    Bhattacharjee, Moumita; Roy, Ananda Sankar; Ghosh, Santinath; Dey, Munmun

    2011-01-01

    The conventional offset lithographic printing ink is mainly based on linseed oil. But in recent years, due to stiff competition from synthetic substitutes mainly from petroleum products, the crop production shrinks down to an unsustainable level, which increases the price of linseed oil. Though soyabean oil has replaced a major portion of linseed oil, it is also necessary to develop alternate cost effective vegetable oils for printing ink industry. The present study aims to evaluate the performance of karanja oil (Pongamia glabra) as an alternative of linseed oil in the formulation of offset printing ink because karanja oil is easily available in rural India. Physical properties of raw karanja oil are measured and compared with that of alkali refined linseed oil. Rosin modified phenolic resin based varnishes were made with linseed oil as well as with karanja oil and their properties are compared. Sheetfed offset inks of process colour yellow and cyan is chosen to evaluate the effect of karanja oil in ink properties. In conclusion, karanja oil can be accepted as an alternate vegetable oil source with its noticeable effect on print and post print properties with slower drying time on paper. However, the colour and odour of the oil will restrict its usage on offset inks.

  14. Size distribution, chemical composition, and hygroscopicity of fine particles emitted from an oil-fired heating plant.

    PubMed

    Happonen, Matti; Mylläri, Fanni; Karjalainen, Panu; Frey, Anna; Saarikoski, Sanna; Carbone, Samara; Hillamo, Risto; Pirjola, Liisa; Häyrinen, Anna; Kytömäki, Jorma; Niemi, Jarkko V; Keskinen, Jorma; Rönkkö, Topi

    2013-12-17

    Heavy fuel oil (HFO) is a commonly used fuel in industrial heating and power generation and for large marine vessels. In this study, the fine particle emissions of a 47 MW oil-fired boiler were studied at 30 MW power and with three different fuels. The studied fuels were HFO, water emulsion of HFO, and water emulsion of HFO mixed with light fuel oil (LFO). With all the fuels, the boiler emitted considerable amounts of particles smaller than 200 nm in diameter. Further, these small particles were quite hygroscopic even as fresh and, in the case of HFO+LFO emulsion, the hygroscopic growth of the particles was dependent on particle size. The use of emulsions and the addition of LFO to the fuel had a reducing effect on the hygroscopic growth of particles. The use of emulsions lowered the sulfate content of the smallest particles but did not affect significantly the sulfate content of particles larger than 42 nm and, further, the addition of LFO considerably increased the black carbon content of particulate matter. The results indicate that even the fine particles emitted from HFO based combustion can have a significant effect on cloud formation, visibility, and air quality.

  15. Oil turmoil

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Not Available

    1979-07-01

    A review of US oil production, refining, and retailing reveals the severity of the energy problem and illustrates the confusion over what can be accomplished by decontrolling oil prices. Conflicting statements from members of Congress, the President, and the oil industry have further confused the public. The shortages can be traced to a decline in domestic production incentives and foreign production, a slowdown in refinery expansion because of environmental constraints, competition between home heating oil and gasoline for priority, the failure of states to enforce speed limits, and a national preoccupation with oil profits. Senator Kennedy, for example, advocates continuedmore » price controls with a world-wide drilling program funded by the World Bank, while decontrol advocates feel price controls will only artifically restrain US production. The economic effects of decontrol on inflation are unclear, but conservation efforts, the development of alternative energy sources, and oil development from shale and tar sands are predicted to increase as political rhetoric declines.« less

  16. Essential oils--their antimicrobial activity against Escherichia coli and effect on intestinal cell viability.

    PubMed

    Fabian, Dusan; Dusan, Fabian; Sabol, Marián; Marián, Sabol; Domaracká, Katarína; Katarína, Domaracká; Bujnáková, Dobroslava; Dobroslava, Bujnáková

    2006-12-01

    Essential oils are known to possess antimicrobial activity against a wide spectrum of bacteria. The main objective of this study was to evaluate possible harmful effects of four commonly used essential oils and their major components on intestinal cells. Antimicrobial activity of selected plant extracts against enteroinvasive Escherichia coli was dose dependent. However, doses of essential oils with the ability to completely inhibit bacterial growth (0.05%) showed also relatively high cytotoxicity to intestinal-like cells cultured in vitro. Lower doses of essential oils (0.01%) had only partial antimicrobial activity and their damaging effect on Caco-2 cells was only modest. Cell death assessment based on morphological and viability staining followed by fluorescence microscopy showed that essential oils of cinnamon and clove and their major component eugenol had almost no cytotoxic effect at lower doses. Although essential oil of oregano and its component carvacrol slightly increased the incidence of apoptotic cell death, they showed extensive antimicrobial activity even at lower concentrations. Relatively high cytotoxicity was demonstrated by thyme oil, which increased both apoptotic and necrotic cell death incidence. In contrast, its component thymol showed no cytotoxic effect as well as greatly-reduced ability to inhibit visible growth of the chosen pathogen in the doses used. On the other hand, the addition of all essential oils and their components at lower doses, with the exception of thyme oil, to bacterial suspension significantly reduced the cytotoxic effect of E. coli on Caco-2 cells after 1h culture. In conclusion, it is possible to find appropriate doses of essential oils showing both antimicrobial activity and very low detrimental effect on intestinal cells.

  17. Predicting the optical observables for nucleon scattering on even-even actinides

    NASA Astrophysics Data System (ADS)

    Martyanov, D. S.; Soukhovitskiĩ, E. Sh.; Capote, R.; Quesada, J. M.; Chiba, S.

    2017-09-01

    The previously derived Lane consistent dispersive coupled-channel optical model for nucleon scattering on 232Th and 238U nuclei is extended to describe scattering on even-even actinides with Z = 90-98. A soft-rotator-model (SRM) description of the low-lying nuclear structure is used, where the SRM Hamiltonian parameters are adjusted to the observed collective levels of the target nucleus. SRM nuclear wave functions (mixed in K quantum number) have been used to calculate the coupling matrix elements of the generalized optical model. The “effective” deformations that define inter-band couplings are derived from the SRM Hamiltonian parameters. Conservation of nuclear volume is enforced by introducing a dynamic monopolar term to the deformed potential, leading to additional couplings between rotational bands. The fitted static deformation parameters are in very good agreement with those derived by Wang and collaborators using the Weizsäcker-Skyrme global mass model (WS4), allowing use of the latter to predict cross sections for nuclei without experimental data. A good description of the scarce “optical” experimental database is achieved. SRM couplings and volume conservation allow a precise calculation of the compound-nucleus formation cross sections, which is significantly different from that calculated with rigid-rotor potentials coupling the ground-state rotational band. The derived parameters can be used to describe both neutron- and proton-induced reactions. Supported by International Atomic Energy Agency, through the IAEA Research Contract 19263, by the Spanish Ministry of Economy and Competitivity under Contracts FPA2014-53290-C2-2-P and FPA2016-77689-C2-1-R.

  18. Implementation of physicochemical and sensory analysis in conjunction with multivariate analysis towards assessing olive oil authentication/adulteration.

    PubMed

    Arvanitoyannis, Ioannis S; Vlachos, Antonios

    2007-01-01

    The authenticity of products labeled as olive oils, and in particular as virgin olive oils, stands for a very important issue both in terms of its health and commercial aspects. In view of the continuously increasing interest in virgin olive oil therapeutic properties, the traditional methods of characterization and physical and sensory analysis were further enriched with more advanced and sophisticated methods such as HPLC-MS, HPLC-GC/C/IRMS, RPLC-GC, DEPT, and CSIA among others. The results of both traditional and "novel" methods were treated both by means of classical multivariate analysis (cluster, principal component, correspondence, canonical, and discriminant) and artificial intelligence methods showing that nowadays the adulteration of virgin olive oil with seed oil is detectable at very low percentages, sometimes even at less than 1%. Furthermore, the detection of geographical origin of olive oil is equally feasible and much more accurate in countries like Italy and Spain where databases of physical/chemical properties exist. However, this geographical origin classification can also be accomplished in the absence of such databases provided that an adequate number of oil samples are used and the parameters studied have "discriminating power."

  19. Nanofluid of graphene-based amphiphilic Janus nanosheets for tertiary or enhanced oil recovery: High performance at low concentration.

    PubMed

    Luo, Dan; Wang, Feng; Zhu, Jingyi; Cao, Feng; Liu, Yuan; Li, Xiaogang; Willson, Richard C; Yang, Zhaozhong; Chu, Ching-Wu; Ren, Zhifeng

    2016-07-12

    The current simple nanofluid flooding method for tertiary or enhanced oil recovery is inefficient, especially when used with low nanoparticle concentration. We have designed and produced a nanofluid of graphene-based amphiphilic nanosheets that is very effective at low concentration. Our nanosheets spontaneously approached the oil-water interface and reduced the interfacial tension in a saline environment (4 wt % NaCl and 1 wt % CaCl2), regardless of the solid surface wettability. A climbing film appeared and grew at moderate hydrodynamic condition to encapsulate the oil phase. With strong hydrodynamic power input, a solid-like interfacial film formed and was able to return to its original form even after being seriously disturbed. The film rapidly separated oil and water phases for slug-like oil displacement. The unique behavior of our nanosheet nanofluid tripled the best performance of conventional nanofluid flooding methods under similar conditions.

  20. Composition, diagenetic transformation and alkalinity potential of oil shale ash sediments.

    PubMed

    Mõtlep, Riho; Sild, Terje; Puura, Erik; Kirsimäe, Kalle

    2010-12-15

    Oil shale is a primary fuel in the Estonian energy sector. After combustion 45-48% of the oil shale is left over as ash, producing about 5-7 Mt of ash, which is deposited on ash plateaus annually almost without any reuse. This study focuses on oil shale ash plateau sediment mineralogy, its hydration and diagenetic transformations, a study that has not been addressed. Oil shale ash wastes are considered as the biggest pollution sources in Estonia and thus determining the composition and properties of oil shale ash sediment are important to assess its environmental implications and also its possible reusability. A study of fresh ash and drillcore samples from ash plateau sediment was conducted by X-ray diffractometry and scanning electron microscopy. The oil shale is highly calcareous, and the ash that remains after combustion is derived from the decomposition of carbonate minerals. It is rich in lime and anhydrite that are unstable phases under hydrous conditions. These processes and the diagenetic alteration of other phases determine the composition of the plateau sediment. Dominant phases in the ash are hydration and associated transformation products: calcite, ettringite, portlandite and hydrocalumite. The prevailing mineral phases (portlandite, ettringite) cause highly alkaline leachates, pH 12-13. Neutralization of these leachates under natural conditions, by rainwater leaching/neutralization and slow transformation (e.g. carbonation) of the aforementioned unstable phases into more stable forms, takes, at best, hundreds or even hundreds of thousands of years. Copyright © 2010 Elsevier B.V. All rights reserved.

  1. Effects of Citrus sinensis (L.) Osbeck epicarp essential oil on growth and morphogenesis of Aspergillus niger (L.) Van Tieghem.

    PubMed

    Sharma, Neeta; Tripathi, Abhishek

    2008-01-01

    Essential oils from different plant parts are known for their antimicrobial activity but the antifungal effects of essential oil from Citrus sinensis (L.) Osbeck epicarp on growth and morphogenesis of Aspergillus niger has not been observed so far. The mycelial growth was inhibited at 2.5 and 3.0 microg/ml of oil in Potato Dextrose Broth and Agar medium, respectively. These concentrations were fungicidal under the test conditions. The fungitoxicity of oil did not change even at exposure to 100 degrees C and autoclaving. The main changes observed under light and scanning electron microscopy after oil treatment were loss of cytoplasm in fungal hyphae, and budding of hyphal tip. The hyphal wall and its diameter became markedly thinner, distorted and resulted in cell wall disruption. The flattened and empty hyphal tips bifurcated into bud like structures. GC-MS studies of the oil revealed the presence of 10 chemical constituents. Limonene has been found to be major component (84.2%).

  2. Relative sensitivity of Arctic species to physically and chemically dispersed oil determined from three hydrocarbon measures of aquatic toxicity.

    PubMed

    Bejarano, Adriana C; Gardiner, William W; Barron, Mace G; Word, Jack Q

    2017-09-15

    The risks to Arctic species from oil releases is a global concern, but their sensitivity to chemically dispersed oil has not been assessed using a curated and standardized dataset from spiked declining tests. Species sensitivity to dispersed oil was determined by their position within species sensitivity distributions (SSDs) using three measures of hydrocarbon toxicity: total petroleum hydrocarbons (TPH), polycyclic aromatic hydrocarbon (PAHs), and naphthalenes. Comparisons of SSDs with Arctic/sub-Arctic versus non-Arctic species, and across SSDs of compositionally similar oils, showed that Arctic and non-Arctic species have comparable sensitivities even with the variability introduced by combining data across studies and oils. Regardless of hydrocarbon measure, hazard concentrations across SSDs were protective of sensitive Arctic species. While the sensitivities of Arctic species to oil exposures resemble those of commonly tested species, PAH-based toxicity data are needed for a greater species diversity including sensitive Arctic species. Copyright © 2017 Elsevier Ltd. All rights reserved.

  3. Discrimination of fish oil and mineral oil slicks on sea water

    NASA Technical Reports Server (NTRS)

    Mac Dowall, J.

    1969-01-01

    Fish oil and mineral oil slicks on sea water can be discriminated by their different spreading characteristics and by their reflectivities and color variations over a range of wavelengths. Reflectivities of oil and oil films are determined using a duel beam reflectance apparatus.

  4. Power Satellites, Carbon Dioxide, Synthetic Fuel, Sequestering Carbon as Synthetic Oil and Fresh Water from Seawater

    NASA Astrophysics Data System (ADS)

    Keith Henson, H.

    2010-05-01

    A small number of people have been working for the past year on ways to reduce the cost of power from space to the point that it could entirely displace fossil fuels and even put carbon dioxide back in empty oil fields as synthetic oil. The challenging part is reducing the cost of transport to GEO by a factor of ˜200 discussed in another paper in this volume. Given low cost power, synthetic fuels, carbon sequestration, and fresh water from seawater become economical.

  5. 19. LOWER OIL ROOM DIABLO POWERHOUSE: SHARPLES OIL CENTRIFUGE AND ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    19. LOWER OIL ROOM DIABLO POWERHOUSE: SHARPLES OIL CENTRIFUGE AND OIL TANK, 1989. - Skagit Power Development, Diablo Powerhouse, On Skagit River, 6.1 miles upstream from Newhalem, Newhalem, Whatcom County, WA

  6. Quality and stability of edible oils enriched with hydrophilic antioxidants from the olive tree: the role of enrichment extracts and lipid composition.

    PubMed

    Sánchez de Medina, Verónica; Priego-Capote, Feliciano; Jiménez-Ot, Carlos; Luque de Castro, María Dolores

    2011-11-09

    Phenolic extracts from olive tree leaves and olive pomace were used to enrich refined oils (namely, maize, soy, high-oleic sunflower, sunflower, olive, and rapeseed oils) at two concentration levels (200 and 400 μg/mL, expressed as gallic acid). The concentration of characteristic olive phenols in these extracts together with the lipidic composition of the oils to be enriched influenced the mass transfer of the target antioxidants, which conferred additional stability and quality parameters to the oils as a result. In general, all of the oils experienced either a noticeable or dramatic improvement of their quality-stability parameters (e.g., peroxide index and Rancimat) as compared with their nonenriched counterparts. The enriched oils were also compared with extra virgin olive oil with a natural content in phenols of 400 μg/mL. The healthy properties of these phenols and the scarce or nil prices of the raw materials used can convert oils in supplemented foods or even nutraceuticals.

  7. Natural Sunlight Shapes Crude Oil-Degrading Bacterial Communities in Northern Gulf of Mexico Surface Waters

    PubMed Central

    Bacosa, Hernando P.; Liu, Zhanfei; Erdner, Deana L.

    2015-01-01

    Following the Deepwater Horizon (DWH) spill in 2010, an enormous amount of oil was observed in the deep and surface waters of the northern Gulf of Mexico. Surface waters are characterized by intense sunlight and high temperature during summer. While the oil-degrading bacterial communities in the deep-sea plume have been widely investigated, the effect of natural sunlight on those in oil polluted surface waters remains unexplored to date. In this study, we incubated surface water from the DWH site with amendments of crude oil, Corexit dispersant, or both for 36 days under natural sunlight in the northern Gulf of Mexico. The bacterial community was analyzed over time for total abundance, density of alkane and polycyclic aromatic hydrocarbon degraders, and community composition via pyrosequencing. Our results showed that, for treatments with oil and/or Corexit, sunlight significantly reduced bacterial diversity and evenness and was a key driver of shifts in bacterial community structure. In samples containing oil or dispersant, sunlight greatly reduced abundance of the Cyanobacterium Synechococcus but increased the relative abundances of Alteromonas, Marinobacter, Labrenzia, Sandarakinotalea, Bartonella, and Halomonas. Dark samples with oil were represented by members of Thalassobius, Winogradskyella, Alcanivorax, Formosa, Pseudomonas, Eubacterium, Erythrobacter, Natronocella, and Coxiella. Both oil and Corexit inhibited the Candidatus Pelagibacter with or without sunlight exposure. For the first time, we demonstrated the effects of light in structuring microbial communities in water with oil and/or Corexit. Overall, our findings improve understanding of oil pollution in surface water, and provide unequivocal evidence that sunlight is a key factor in determining bacterial community composition and dynamics in oil polluted marine waters. PMID:26648916

  8. Natural Sunlight Shapes Crude Oil-Degrading Bacterial Communities in Northern Gulf of Mexico Surface Waters.

    PubMed

    Bacosa, Hernando P; Liu, Zhanfei; Erdner, Deana L

    2015-01-01

    Following the Deepwater Horizon (DWH) spill in 2010, an enormous amount of oil was observed in the deep and surface waters of the northern Gulf of Mexico. Surface waters are characterized by intense sunlight and high temperature during summer. While the oil-degrading bacterial communities in the deep-sea plume have been widely investigated, the effect of natural sunlight on those in oil polluted surface waters remains unexplored to date. In this study, we incubated surface water from the DWH site with amendments of crude oil, Corexit dispersant, or both for 36 days under natural sunlight in the northern Gulf of Mexico. The bacterial community was analyzed over time for total abundance, density of alkane and polycyclic aromatic hydrocarbon degraders, and community composition via pyrosequencing. Our results showed that, for treatments with oil and/or Corexit, sunlight significantly reduced bacterial diversity and evenness and was a key driver of shifts in bacterial community structure. In samples containing oil or dispersant, sunlight greatly reduced abundance of the Cyanobacterium Synechococcus but increased the relative abundances of Alteromonas, Marinobacter, Labrenzia, Sandarakinotalea, Bartonella, and Halomonas. Dark samples with oil were represented by members of Thalassobius, Winogradskyella, Alcanivorax, Formosa, Pseudomonas, Eubacterium, Erythrobacter, Natronocella, and Coxiella. Both oil and Corexit inhibited the Candidatus Pelagibacter with or without sunlight exposure. For the first time, we demonstrated the effects of light in structuring microbial communities in water with oil and/or Corexit. Overall, our findings improve understanding of oil pollution in surface water, and provide unequivocal evidence that sunlight is a key factor in determining bacterial community composition and dynamics in oil polluted marine waters.

  9. Oil spills abatement: factors affecting oil uptake by cellulosic fibers.

    PubMed

    Payne, Katharine C; Jackson, Colby D; Aizpurua, Carlos E; Rojas, Orlando J; Hubbe, Martin A

    2012-07-17

    Wood-derived cellulosic fibers prepared in different ways were successfully employed to absorb simulated crude oil, demonstrating their possible use as absorbents in the case of oil spills. When dry fibers were used, the highest sorption capacity (six parts of oil per unit mass of fiber) was shown by bleached softwood kraft fibers, compared to hardwood bleached kraft and softwood chemithermomechanical pulp(CTMP) fibers. Increased refining of CTMP fibers decreased their oil uptake capacity. When the fibers were soaked in water before exposure to the oil, the ability of the unmodified kraft fibers to sorb oil was markedly reduced, whereas the wet CTMP fibers were generally more effective than the wet kraft fibers. Predeposition of lignin onto the surfaces of the bleached kraft fibers improved their ability to take up oil when wet. Superior ability to sorb oil in the wet state was achieved by pretreating the kraft fibers with a hydrophobic sizing agent, alkenylsuccinic anhydride (ASA). Contact angle tests on a model cellulose surface showed that some of the sorption results onto wetted fibers could be attributed to the more hydrophobic nature of the fibers after treatment with either lignin or ASA.

  10. Exposure to oil mist and oil vapour during offshore drilling in norway, 1979-2004.

    PubMed

    Steinsvåg, Kjersti; Bråtveit, Magne; Moen, Bente E

    2006-03-01

    To describe personal exposure to airborne hydrocarbon contaminants (oil mist and oil vapour) from 1979 to 2004 in the mud-handling areas of offshore drilling facilities operating on the Norwegian continental shelf when drilling with oil-based muds. Qualitative and quantitative information was gathered during visits to companies involved in offshore oil and gas production in Norway. Monitoring reports on oil mist and oil vapour exposure covered 37 drilling facilities. Exposure data were analysed using descriptive statistics and by constructing linear mixed-effects models. Samples had been taken during the use of three generations of hydrocarbon base oils, namely diesel oils (1979-1984), low-aromatic mineral oils (1985-1997) and non-aromatic mineral oils (1998-2004). Sampling done before 1984 showed high exposure to diesel vapour (arithmetic mean, AM = 1217 mg m(-3)). When low-aromatic mineral oils were used, the exposure to oil mist and oil vapour was 4.3 and 36 mg m(-3), and the respective AMs for non-aromatic mineral oils were reduced to 0.54 and 16 mg m(-3). Downward time trends were indicated for both oil mist (6% per year) and oil vapour (8% per year) when the year of monitoring was introduced as a fixed effect in a linear mixed-effects model analysis. Rig type, technical control measures and mud temperature significantly determined exposure to oil mist. Rig type, type of base oil, viscosity of the base oil, work area, mud temperature and season significantly determined exposure to oil vapour. Major decreases in variability were found for the between-rig components. Exposure to oil mist and oil vapour declined over time in the mud-handling areas of offshore drilling facilities. Exposure levels were associated with rig type, mud temperature, technical control measures, base oil, viscosity of the base oil, work area and season.

  11. Dexamethasone implant in silicone oil: in vitro behavior.

    PubMed

    Flores-Villalobos, Erick Omar; Ramírez-Estudillo, J Abel; Robles-Contreras, Atzin; Oliva-Ramírez, Jacqueline L

    2018-01-01

    To determine the effect of the silicone on the dexamethasone intravitreal implant. Basic, experimental, prospective and transversal study performed at the hospital "Nuestra Señora de la Luz" in Mexico City. One dexamethasone implant was placed in a test tube with 4 mL of each tamponade medium: 1000cS, 5000cS and heavy silicone oil; basic saline solution was used as the control medium. Photographs were taken weekly for 12 months. 200 µL samples were taken from each medium at 24 h, 1, 2 weeks and monthly for 12 months. ELISA test was performed to quantify dexamethasone release in every sample. An inflammatory stimulus was created and later exposed it to every sample in order to test their anti-inflammatory capacity by cytokine analysis using cytometric bead array. Statistically significant results were obtained with p < 0.05. Photographic follow-up showed disintegration of the implant in control medium. Implants in silicone oil suffered no changes during follow-up. Dexamethasone levels in control medium showed stability from month 2 to 12. Silicone oil mediums showed irregular dexamethasone release during the 1 year period. Dexamethasone in control medium had inhibitory effects on TNF-α starting at 24 h (p < 0.001) and remained stable. Dexamethasone in 1000cS silicone oil showed inhibitory effects from month 2 (p < 0.001) until month 6 (p < 0.001). Implants in denser silicone oils showed no inhibitory effects in any of the samples. Denser mediums altered the implant pharmacokinetics and showed no anti-inflammatory effects even when concentrations were quantified at levels similar to control medium in vitro.

  12. Even Start Projects Serving Migrant Families: Resource Guide.

    ERIC Educational Resources Information Center

    Gonzales, Miriam; Goldstein, David; Stief, Elizabeth; Fiester, Leila; Weiner, Lisa; Waiters, Katrina

    Even Start was created by federal legislation to address poverty and illiteracy among low-income families by integrating early childhood education, adult literacy or adult basic education, and parenting education into a unified family literacy program. Migrant Education Even Start (MEES) projects resemble other Even Start projects but are affected…

  13. Oil mixing behavior after an oil spill: identification conflicts of different fingerprints.

    PubMed

    He, Shijie; Yu, Hongjun; Luo, Yongming; Wang, Chuanyuan; Li, Xueshuang; Li, Zhongping

    2018-04-01

    Clearing up whether spilled oil is mixed or not can strengthen the accuracy of oil spill identification. In the present study, the biomarkers in spilled oil samples were detected. The weathering modes of different types of diagnostic ratio and carbon isotope values of individual n-alkanes were also analyzed. The results showed that the diagnostic ratios of steroids, terpenes and aromatics, and weathering characteristics of carbon isotope composition (δ 13 C) of individual n-alkanes supported the idea that Dalian oil spill emerged from a single oil source. Furthermore, commonly used diagnostic ratios of n-alkanes indicated that the Dalian oil spill had undergone the oil mixing process. The different identifying outcomes indicate that some kinds of n-alkane-rich substance (such as oil dispersants) were mixed in the Dalian spilled oil and interfered with the routine diagnosis ratios of n-alkanes.

  14. Stabilization of Softwood-Derived Pyrolysis Oils for Continuous Bio-oil Hydroprocessing

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Olarte, Mariefel V.; Zacher, Alan H.; Padmaperuma, Asanga B.

    The use of fast pyrolysis as a potential renewable liquid transportation fuel alternative to crude oil depends on successful catalytic upgrading to produce a refinery-ready product with oxygen content and qualities (i.e. specific functional group or compound content) that is compatible with the product’s proposed insertion point. Catalytic upgrading of bio-oil requires high temperature and pressure, while similar to crude oil hydrotreating, is not as straightforward for the thermally unstable pyrolysis oil. For years, a two-temperature zone, downflow trickle bed reactor was the state-of-the art for continuous operation. However, pressure excursion due to plug formation still occurred, typically at themore » high temperature transition zone, leading to a process shutdown within 140 h. Recently, a bio-oil pre-treatment process, together with a robust commercial catalyst, was found to be enabling the continuous operation of the two-zone hydroprocessing system. Here, we report the results on pre-treating bio-oil at 413 K and 8.4 MPa of flowing H2 (500 L H2/L bio-oil, 0.5 L bio-oil/L catalyst bed) and the attempts to characterize this oil product to understand the chemistry which enabled the long-term processing of bio-oil.« less

  15. Kolkhoung (Pistacia khinjuk) Hull Oil and Kernel Oil as Antioxidative Vegetable Oils with High Oxidative Stability 
and Nutritional Value.

    PubMed

    Asnaashari, Maryam; Hashemi, Seyed Mohammad Bagher; Mehr, Hamed Mahdavian; Yousefabad, Seyed Hossein Asadi

    2015-03-01

    In this study, in order to introduce natural antioxidative vegetable oil in food industry, the kolkhoung hull oil and kernel oil were extracted. To evaluate their antioxidant efficiency, gas chromatography analysis of the composition of kolkhoung hull and kernel oil fatty acids and high-performance liquid chromatography analysis of tocopherols were done. Also, the oxidative stability of the oil was considered based on the peroxide value and anisidine value during heating at 100, 110 and 120 °C. Gas chromatography analysis showed that oleic acid was the major fatty acid of both types of oil (hull and kernel) and based on a low content of saturated fatty acids, high content of monounsaturated fatty acids, and the ratio of ω-6 and ω-3 polyunsaturated fatty acids, they were nutritionally well--balanced. Moreover, both hull and kernel oil showed high oxidative stability during heating, which can be attributed to high content of tocotrienols. Based on the results, kolkhoung hull oil acted slightly better than its kernel oil. However, both of them can be added to oxidation-sensitive oils to improve their shelf life.

  16. Efficacy of anise oil, dwarf-pine oil and chamomile oil against thymidine-kinase-positive and thymidine-kinase-negative herpesviruses.

    PubMed

    Koch, Christine; Reichling, Jürgen; Kehm, Roland; Sharaf, Mona M; Zentgraf, Hanswalter; Schneele, Jürgen; Schnitzler, Paul

    2008-11-01

    The effect of anise oil, dwarf-pine oil and chamomile oil against different thymidine-kinase-positive (aciclovir-sensitive) and thymidine-kinase-negative (aciclovir-resistant) herpes simplex virus type 1 (HSV-1) strains was examined. Clinical HSV-1 isolates containing frameshift mutations in the thymidine kinase (TK) gene, an insertion or a deletion, yield a non-functional thymidine kinase enzyme resulting in phenotypical resistance against aciclovir. The inhibitory activity of three different essential oils against herpes simplex virus isolates was tested in-vitro using a plaque reduction assay. All essential oils exhibited high levels of antiviral activity against aciclovir-sensitive HSV strain KOS and aciclovir-resistant clinical HSV isolates as well as aciclovir-resistant strain Angelotti. At maximum noncytotoxic concentrations of the plant oils, plaque formation was significantly reduced by 96.6-99.9%, when herpesviruses were preincubated with drugs before attachment to host cells. No significant effect on viral infectivity could be achieved by adding these compounds during the replication phase. These results indicate that anise oil, dwarf-pine oil and chamomile oil affected the virus by interrupting adsorption of herpesviruses and in a different manner than aciclovir, which is effective after attachment inside the infected cells. Thus the investigated essential oils are capable of exerting a direct effect on HSV and might be useful in the treatment of drug-resistant viruses. Chamomile oil did not reveal any irritating potential on hen's egg chorioallantoic membrane, demonstrated the highest selectivity index among the oils tested and was highly active against clinically relevant aciclovir-resistant HSV-1 strains.

  17. Influence of essential onion oil on tin and chromium dissolution from tinplate.

    PubMed

    Nincević Grassino, A; Grabarić, Z; Pezzani, A; Fasanaro, G; Lo Voi, A

    2009-07-01

    During food and beverage packaging in tinplate cans the dissolution of tin and chromium into food content may occur. To protect metallic surface different corrosion inhibitors are recommended, nowadays particularly a new group of natural products is of interest. In this work the influence of essential onion oil (EOO) on metals dissolution (tin and chromium) from tinplate sheets before food canning was investigated. The analyses were performed by galvanostatic method and atomic absorption spectroscopy. The values of tin obtained for the internal surface of tinplate covered with EOO (7.31-9.76 gm(-2)) are lower than the values when dioctyl sebacate oil (DOS), as a protective tinplate surface layer for food caning, was used (9.24-11.03 gm(-2)). Obviously, the presence of EOO diminished more efficiently then DOS oil the dissolution of tin in electrolyte during galvanostatic analyses. The efficiency of EOO as corrosion inhibitor was even more pronounced in the case of chromium where the dissolution from 1.8-2.5 mgm(-2) (DOS oil) was lowered to 1.0-1.3 mgm(-2) (EOO). Correlation of results obtained with two different physico-chemical methods was satisfying.

  18. 21 CFR 172.861 - Cocoa butter substitute from coconut oil, palm kernel oil, or both oils.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... fatty acids (complying with § 172.860) derived from edible coconut oil, edible palm kernel oil, or both oils. (b) The ingredient meets the following specifications: Acid number: Not to exceed 0.5..., citric acid, succinic acid, and spices; and (2) In compound coatings, cocoa creams, cocoa-based sweets...

  19. Quality of vegetable oil prior to fortification is an important criteria to achieve a health impact.

    PubMed

    Andarwulan, Nuri; Gitapratiwi, Desty; Laillou, Arnaud; Fitriani, Dwi; Hariyadi, Purwiyatno; Moench-Pfanner, Regina; Martianto, Drajat

    2014-11-11

    Unbranded palm cooking oil has been fortified for several years and can be found in the market with different oxidation levels. This study aimed to investigate the stability and shelf life of unbranded, bulk, vitamin A-fortified palm oils with the most commonly observed oxidation levels in Indonesia. Three types of cooking oils were tested: (i) cooking oil with a peroxide value (PV) below 2 mEq O2/kg (PO1); (ii) cooking oil with a PV around 4 mEq O2/kg (PO2); and (iii) cooking oil with a PV around 9 mEq O2/kg (PO3). The oil shelf life was determined by using accelerated shelf life testing (ASLT), where the product was stored at 60, 75 and 90 °C, and then PV, free fatty acid and vitamin A concentration in the oil samples were measured. The results showed that PO1 had a shelf life of between 2-3 months, while PO2's shelf life was a few weeks and PO3's only a few days. Even given those varying shelf lives, the vitamin A loss in the oils was still acceptable, at around 10%. However, the short shelf life of highly oxidized cooking oil, such as PO3, might negatively impact health, due to the potential increase of free radicals of the lipid peroxidation in the oil. Based on the results, the Indonesian government should prohibit the sale of highly-oxidized cooking oil. In addition, government authorities should promote and endorse the fortification of only cooking oil with low peroxide levels to ensure that fortification is not associated with any health issues associated with high oxidation levels of the cooking oil.

  20. Over-the-counter fish oil use in a county hospital: Medication use evaluation and efficacy analysis

    PubMed Central

    Tatachar, Amulya; Pio, Margaret; Yeung, Denise; Moss, Elizabeth; Chow, Diem; Boatright, Steven; Quinones, Marissa; Mathew, Annie; Hulstein, Jeffrey; Adams-Huet, Beverley; Ahmad, Zahid

    2016-01-01

    BACKGROUND Little is known about the use and effectiveness of over-the-counter (OTC) fish oil supplements for triglyceride (TG) lowering. OBJECTIVES To (1) perform a medication-use evaluation (MUE) and (2) assess the efficacy of OTC fish oil. METHODS Retrospective, observational cohort study using electronic medical records and the pharmacy database from Parkland Health and Hospital System in Dallas, Texas. Parkland is a tax-supported county institution that provides patients with single-brand OTC fish oil. Two separate analyses were conducted. Six hundred seventeen patients (prescribed fish oil between July 1, 2012, and August 31, 2012) were included in the MUE analysis and 235 patients (109 fish oil, 72 fenofibrate, and 54 gemfibrozil, prescribed between January 1, 2012, and July 31, 2013) were included in the efficacy analysis. The main outcome measure for the MUE was fish oil prescribing habits including dosages and patient adherence, as defined by medication possession ratio. The main outcome measure for the efficacy analysis was change in lipids measured using the last value before fish oil treatment and the first value after fish oil treatment. RESULTS MUE: 617 patients received prescriptions for OTC fish oil. Sixty-four percent were prescribed a total daily dose of 2000 mg. Only 25% of patients were adherent. Efficacy analysis: despite being prescribed suboptimal doses, fish oil reduced TGs by 29% (95% confidence interval, 34.3–22.7). Compared with fish oil therapy, fibrate therapy resulted in a greater TG reduction: 48.5% (55.1–41.0) with fenofibrate and 49.8% (57.6–40.5) with gemfibrozil (P < 0001, both medications compared with fish oil). CONCLUSIONS Health care providers prescribe suboptimal doses of fish oil, and adherence is poor. Even at low doses (2 g/d), though, fish oil lowers TGs by 29%. PMID:26073390

  1. Production and characterization of pyrolytic oils by pyrolysis of waste machinery oil.

    PubMed

    Sinağ, Ali; Gülbay, Selen; Uskan, Burçin; Uçar, Suat; Ozgürler, Sara Bilge

    2010-01-15

    The main objective of this work is to propose an alternative method for evaluation of the waste machinery oil which is an environmental problem in Turkey. For this purpose, pyrolysis of waste machinery oil was conducted in a tubular reactor. Effect of the experimental conditions (various temperatures, catalyst type) on the formation of pyrolytic oil, gas, and char was investigated. Nickel supported on silica and zeolite (HZSM-5) were used as catalysts. Properties of the pyrolytic oils were characterized by gas chromatograph equipped with a mass selective detector (GC-MS), gas chromatography with flame ionization detector (GC-FID for boiling point range distribution), nuclear magnetic resonance ((1)H NMR) spectroscopy, higher heating value measurement, and elemental analysis. The behavior of the metals in the waste machinery oil and the pyrolytic oil samples was also quantitatively detected by inductively coupled plasma (ICP) analysis. As, Cd and Cr contents of the all pyrolytic oils were found as <0.05 ppm, while Cu content of the pyrolytic oils varied between 0.3 ppm and 0.61 ppm. Only Vanadium contents of the pyrolytic oils obtained at 800 degrees C (0.342 ppm) and in the presence of HZSM5 (0.57 ppm) increased compared to that obtained by waste machinery oil (0.1 ppm). Lower metal contents of the pyrolytic oils reveal that pyrolysis of the waste machinery oils leads to the formation of environmental friendly pyrolytic oils with higher heating values.

  2. In-vitro activity of essential oils, in particular Melaleuca alternifolia (tea tree) oil and tea tree oil products, against Candida spp.

    PubMed

    Hammer, K A; Carson, C F; Riley, T V

    1998-11-01

    The in-vitro activity of a range of essential oils, including tea tree oil, against the yeast candida was examined. Of the 24 essential oils tested by the agar dilution method against Candida albicans ATCC 10231, three did not inhibit C. albicans at the highest concentration tested, which was 2.0% (v/v) oil. Sandalwood oil had the lowest MIC, inhibiting C. albicans at 0.06%. Melaleuca alternifolia (tea tree) oil was investigated for activity against 81 C. albicans isolates and 33 non-albicans Candida isolates. By the broth microdilution method, the minimum concentration of oil inhibiting 90% of isolates for both C. albicans and non-albicans Candida species was 0.25% (v/v). The minimum concentration of oil killing 90% of isolates was 0.25% for C. albicans and 0.5% for non-albicans Candida species. Fifty-seven Candida isolates were tested for sensitivity to tea tree oil by the agar dilution method; the minimum concentration of oil inhibiting 90% of isolates was 0.5%. Tests on three intra-vaginal tea tree oil products showed these products to have MICs and minimum fungicidal concentrations comparable to those of non-formulated tea tree oil, indicating that the tea tree oil contained in these products has retained its anticandidal activity. These data indicate that some essential oils are active against Candida spp., suggesting that they may be useful in the topical treatment of superficial candida infections.

  3. New insights into microbial responses to oil spills from the Deepwater Horizon incident

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Mason, O.U.; Hazen, T.C.

    2011-06-15

    On April 20, 2010, a catastrophic eruption of methane caused the Deepwater Horizon exploratory drill rig drilling the Macondo Well in Mississippi Canyon Block 252 (MC252) to explode. The Deepwater Horizon oil spill was unprecendeted for several reasons: the volume of oil released; the spill duration; the well depth; the distance from the shore-line (77 km or about 50 miles); the type of oil (light crude); and the injection of dispersant directly at the wellhead. This study clearly demonstrated that there was a profound and significant response by certain members of the in situ microbial community in the deep-sea inmore » the Gulf of Mexico. In particular putative hydrocarbon degrading Bacteria appeared to bloom in response to the Deepwater Horizon oil spill, even though the temperature at these depths is never >5 C. As the plume aged the shifts in the microbial community on a temporal scale suggested that different, yet metabolically important members of the community were able to respond to a myriad of plume constituents, e.g. shifting from propane/ethane to alkanes and finally to methane. Thus, the biodegradation of hydrocarbons in the plume by Bacteria was a highly significant process in the natural attenuation of many compounds released during the Deepwater Horizon oil spill.« less

  4. Oil and gas markets, companies, and technology in the 1990`s and beyond

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kennedy, J.L.

    1995-08-01

    During the late 1990`s and beyond, oil prices will be stagnant while costs increase, competition for markets and capital will be fierce, funds available for exploration and development will be limited, and environmental extremists will keep prospective areas off-limits. Higher taxes will limit growth in oil and gas demand and reapportion energy market shares. And a campaign to brand oil use as an ``addiction`` that must be cured will gather steam. But opportunities abound, too, even in the US High-quality properties are available throughout the US, independents can find and develop reserves cheaper than the majors, and new tools aremore » available to reduce risks both in the field and in the market. Gas prices are firming and natural gas is often labeled the ``fuel of the future.`` To succeed in the petroleum industry of the 1990`s, all companies must accept change, be creative, and take initiative. To prosper, oil and gas producers and refiners and those who supply and serve the industry must face the new realities of the market. They cannot mark time until the return of 4,000 active rigs and $40/bbl oil. those days are never coming back. Never.« less

  5. Algae to Economically Viable Low-Carbon-Footprint Oil.

    PubMed

    Bhujade, Ramesh; Chidambaram, Mandan; Kumar, Avnish; Sapre, Ajit

    2017-06-07

    Algal oil as an alternative to fossil fuel has attracted attention since the 1940s, when it was discovered that many microalgae species can produce large amounts of lipids. Economics and energy security were the motivational factors for a spurt in algae research during the 1970s, 1990s, and early 2000s. Whenever crude prices declined, research on algae stopped. The scenario today is different. Even given low and volatile crude prices ($30-$50/barrel), interest in algae continues all over the world. Algae, with their cure-all characteristics, have the potential to provide sustainable solutions to problems in the energy-food-climate nexus. However, after years of effort, there are no signs of algae-to-biofuel technology being commercialized. This article critically reviews past work; summarizes the current status of the technology; and based on the lessons learned, provides a balanced perspective on a potential path toward commercialization of algae-to-oil technology.

  6. Eri silkworm: a source of edible oil with a high content of α-linolenic acid and of significant nutritional value.

    PubMed

    Longvah, Thingnganing; Manghtya, Korra; Qadri, Syed S Y H

    2012-07-01

    The study was undertaken to provide value addition to spent eri silkworm as an alternative source of edible oil for the food and feed industry by carrying out a short-term nutritional and toxicological evaluation of eri silkworm pupae oil using Wistar NIN rats. Growth performance of rats fed either sunflower oil (Control) or eri silkworm pupae oil (Experimental) was comparable. Histopathological examination of the various tissues showed no signs of toxicity even after feeding the eri silkworm oil for 18 weeks. Serum cholesterol and triglyceride was significantly reduced (P < 0.05) while high-density lipoprotein cholesterol was significantly increased (P < 0.05) which is attributed to the high α-linolenic acid content of eri silkworm oil. The study showed that eri silkworm pupae oil is safe and nutritionally equivalent to commonly used vegetable oils. Eri silkworm pupae can be harvested to provide a cost effective alternative edible oil that can be used to nutritional advantage in the food and feed industry. Therefore eri silkworm and its host plants offer an excellent example of multiple product crops and of sustainable agricultural practice with excellent opportunity for economic and nutritional benefits. Copyright © 2012 Society of Chemical Industry.

  7. 24 CFR 904.108 - Break-even amount.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... amount. (a) Definition. The term “break-even amount” as used herein means the minimum average monthly... break-even amount, the excess shall constitute additional Project income and shall be deposited and used in the same manner as other Project income. (c) Deficit in monthly payment. When the homebuyer's...

  8. [Laser induced fluorescence spectrum characteristics of common edible oil and fried cooking oil].

    PubMed

    Mu, Tao-tao; Chen, Si-ying; Zhang, Yin-chao; Chen, He; Guo, Pan; Ge, Xian-ying; Gao, Li-lei

    2013-09-01

    In order to detect the trench oil the authors built a trench oil rapid detection system based on laser induced fluorescence detection technology. This system used 355 nm laser as excitation light source. The authors collected the fluorescence spectrum of a variety of edible oil and fried cooking oil (a kind of trench oil) and then set up a fluorescence spectrum database by taking advantage of the trench oil detection system It was found that the fluorescence characteristics of fried cooking oil and common edible oil were obviously different. Then it could easily realize the oil recognition and trench oil rapid detection by using principal component analysis and BP neural network, and the overall recognition rate could reach as high as 97.5%. Experiments showed that laser induced fluorescence spectrum technology was fast, non-contact, and highly sensitive. Combined with BP neural network, it would become a new technique to detect the trench oil.

  9. Candida albicans Impairments Induced by Peppermint and Clove Oils at Sub-Inhibitory Concentrations

    PubMed Central

    Rajkowska, Katarzyna; Otlewska, Anna; Kunicka-Styczyńska, Alina; Krajewska, Agnieszka

    2017-01-01

    Members of Candida species cause significant health problems, inducing various types of superficial and deep-seated mycoses in humans. In order to prevent from Candida sp. development, essential oils are more and more frequently applied, due to their antifungal activity, low toxicity if used appropriately, and biodegrability. The aim of the study was to characterize the early alterations in Candida albicans metabolic properties in relation to proteins and chromosomal DNA profiles, after treatment with peppermint and clove oils at sub-inhibitory concentrations. The yeasts were affected by the oils even at a concentration of 0.0075% v/v, which resulted in changes in colony morphotypes and metabolic activities. Peppermint and clove oils at concentrations ranging from 0.015× MIC (minimal inhibitory concentration) to 0.5× MIC values substantially affected the enzymatic abilities of C. albicans, and these changes were primarily associated with the loss or decrease of activity of all 9 enzymes detected in the untreated yeast. Moreover, 29% isolates showed additional activity of N-acetyl-β-glucosaminidase and 14% isolates—α-fucosidase in comparison to the yeast grown without essential oils addition. In response to essential oils at 0.25–0.5× MIC, extensive changes in C. albicans whole-cell protein profiles were noted. However, the yeast biochemical profiles were intact with the sole exception of the isolate treated with clove oil at 0.5× MIC. The alterations were not attributed to gross chromosomal rearrangements in C. albicans karyotype. The predominantly observed decrease in protein fractions and the yeast enzymatic activity after treatment with the oils should be considered as a phenotypic response of C. albicans to the essential oils at their sub-inhibitory concentrations and may lead to the reduction of this yeast pathogenicity. PMID:28629195

  10. Candida albicans Impairments Induced by Peppermint and Clove Oils at Sub-Inhibitory Concentrations.

    PubMed

    Rajkowska, Katarzyna; Otlewska, Anna; Kunicka-Styczyńska, Alina; Krajewska, Agnieszka

    2017-06-19

    Members of Candida species cause significant health problems, inducing various types of superficial and deep-seated mycoses in humans. In order to prevent from Candida sp. development, essential oils are more and more frequently applied, due to their antifungal activity, low toxicity if used appropriately, and biodegrability. The aim of the study was to characterize the early alterations in Candida albicans metabolic properties in relation to proteins and chromosomal DNA profiles, after treatment with peppermint and clove oils at sub-inhibitory concentrations. The yeasts were affected by the oils even at a concentration of 0.0075% v / v , which resulted in changes in colony morphotypes and metabolic activities. Peppermint and clove oils at concentrations ranging from 0.015× MIC (minimal inhibitory concentration) to 0.5× MIC values substantially affected the enzymatic abilities of C. albicans , and these changes were primarily associated with the loss or decrease of activity of all 9 enzymes detected in the untreated yeast. Moreover, 29% isolates showed additional activity of N -acetyl-β-glucosaminidase and 14% isolates-α-fucosidase in comparison to the yeast grown without essential oils addition. In response to essential oils at 0.25-0.5× MIC, extensive changes in C. albicans whole-cell protein profiles were noted. However, the yeast biochemical profiles were intact with the sole exception of the isolate treated with clove oil at 0.5× MIC. The alterations were not attributed to gross chromosomal rearrangements in C. albicans karyotype. The predominantly observed decrease in protein fractions and the yeast enzymatic activity after treatment with the oils should be considered as a phenotypic response of C. albicans to the essential oils at their sub-inhibitory concentrations and may lead to the reduction of this yeast pathogenicity.

  11. Bio-Oil Separation and Stabilization by Near-Critical Propane Fractionation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ginosar, Daniel M.; Petkovic, Lucia M.; Agblevor, Foster A.

    Bio-oils produced by thermal process are promising sources of sustainable, low greenhouse gas alternative fuels. These thermal processes are also well suited to decentralized energy production due to low capital and operating costs. Algae feedstocks for bio-oil production are of particular interest, due in part to their high-energy growth yields. Further, algae can be grown in non-arable areas in fresh, brackish, salt water, or even waste water. Unfortunately, bio-oils produced by thermal processes present significant stability challenges. These oils have complex chemical compositions, are viscous, reactive, and thermally unstable. Further, the components within the oils are difficult to separate bymore » fractional distillation. By far, the most effective separation and stabilization method has been solvent extraction. However, liquid phase extraction processes pose two main obstacles to commercialization; they require a significant amount of energy to remove and recover the solvent from the product, and they have a propensity for the solvent to become contaminated with minerals from the char and ash present in the original bio-oil. Separation and fractionation of thermally produced bio-oils using supercritical fluids (SCF) offers the advantages of liquid solvent extraction while drastically reducing energy demands and the predisposition to carry over solids into the extracted phase. SCFs are dense fluids with liquid-like solvent properties and gas-like transport properties. Further, SCF density and solvent strength can be tuned with minor adjustments in pressure, co-solvent addition, or gas anti-solvent addition. Catalytic pyrolysis oils were produced from Scenedesmus dimorphus algae using a fluid catalytic cracking catalyst. Bio-oil produced from catalytic fast pyrolysis (CFP) was separated using critical fluids. Propane extraction was performed at 65 °C at a fluid reduced pressure of 2.0 (85 bar) using an eight to one solvent to feed ratio by weight

  12. Contact toxicity and repellency of the essential oil from Mentha haplocalyx Briq. against Lasioderma serricorne.

    PubMed

    Zhang, Wen-Juan; Yang, Kai; You, Chun-Xue; Wang, Cheng-Fang; Geng, Zhu-Feng; Su, Yang; Wang, Ying; Du, Shu-Shan; Deng, Zhi-Wei

    2015-05-01

    The chemical composition of the essential oil obtained by hydrodistillation from the aerial parts of Mentha haplocalyx was investigated by GC-FID and GC/MS analyses. In sum, 23 components, representing 92.88% of the total oil composition, were identified, and the main compounds were found to be menthol (59.71%), menthyl acetate (7.83%), limonene (6.98%), and menthone (4.44%). By bioassay-guided fractionation (contact toxicity), three compounds were obtained from the essential oil and identified as menthol, menthyl acetate, and limonene. The essential oil and the three isolated compounds exhibited potent contact toxicity against Lasioderma serricorne adults, with LD50 values of 16.5, 7.91, 5.96, and 13.7 μg/adult, respectively. Moreover, the oil and its isolated compounds also exhibited strong repellency against L. serricorne adults. At the lower concentrations tested and at 2 h after exposure, menthol showed even significantly stronger repellency than the positive control DEET. The study revealed that the bioactivity properties of the essential oil can be attributed to the synergistic effects of its diverse major and minor components, which indicates that the M. haplocalyx oil and its isolated compounds have potential for the development as natural insecticides and/or repellents to control insects in stored grains and traditional Chinese medicinal materials. Copyright © 2015 Verlag Helvetica Chimica Acta AG, Zürich.

  13. Moringa oleifera Seeds and Oil: Characteristics and Uses for Human Health

    PubMed Central

    Leone, Alessandro; Spada, Alberto; Battezzati, Alberto; Schiraldi, Alberto; Aristil, Junior; Bertoli, Simona

    2016-01-01

    Moringa oleifera seeds are a promising resource for food and non-food applications, due to their content of monounsaturated fatty acids with a high monounsaturated/saturated fatty acids (MUFA/SFA) ratio, sterols and tocopherols, as well as proteins rich in sulfated amino acids. The rapid growth of Moringa trees in subtropical and tropical areas, even under conditions of prolonged drought, makes this plant a reliable resource to enhance the nutritional status of local populations and, if rationalized cultivation practices are exploited, their economy, given that a biodiesel fuel could be produced from a source not in competition with human food crops. Despite the relatively diffuse use of Moringa seeds and their oil in traditional medicine, no pharmacological activity study has been conducted on humans. Some encouraging evidence, however, justifies new efforts to obtain clear and definitive information on the benefits to human health arising from seed consumption. A critical review of literature data concerning the composition of Moringa oil has set in motion a plan for future investigations. Such investigations, using the seeds and oil, will focus on cultivation conditions to improve plant production, and will study the health effects on human consumers of Moringa seeds and their oil. PMID:27999405

  14. Colorado Even Start. 1998-1999 Progress Report.

    ERIC Educational Resources Information Center

    Anderson, Beckie

    Even Start programs integrate early childhood education, adult literacy or basic education, parenting education and support, and parent and child time to help break the cycle of poverty and illiteracy. This report describes the Even Start program in Colorado, and includes evaluation questions and methods. The report presents evaluation findings…

  15. Colorado Even Start. 1997-1998 Progress Report.

    ERIC Educational Resources Information Center

    Anderson, Beckie

    Even Start programs integrate early childhood education, adult literacy or basic education, parenting education and support, and parent and child time together to help break the cycle of poverty and illiteracy. This report describes the Even Start program in Colorado, including evaluation questions and methods. The report also presents evaluation…

  16. Transpiration in an oil palm landscape: effects of palm age

    NASA Astrophysics Data System (ADS)

    Röll, A.; Niu, F.; Meijide, A.; Hardanto, A.; Hendrayanto; Knohl, A.; Hölscher, D.

    2015-06-01

    epiphytes. Diurnally, oil palm transpiration rates were characterized by an early peak between 10 and 11 a.m.; there was a pronounced hysteresis in the leaf water use response to changes in vapor pressure deficit for all palms of advanced age. On the day-to-day basis this resulted in a relatively low variability of oil palm water use regardless of fluctuations in vapor pressure deficit and radiation. We conclude, that oil palm dominated landscapes show some spatial variations in (evapo)transpiration rates, e.g. due to varying age-structures, but that the temporal variability of oil palm transpiration is rather low. Stand transpiration rates of some studied oil palm stands compared to or even exceed values reported for different tropical forests, indicating a high water use of oil palms under certain site or management conditions. Our study provides first insights into the eco-hydrological characteristics of oil palms as well as a first estimate of oil palm water use across a gradient of plantation age. It sheds first light on some of the hydrological consequences of the continuing expansion of oil palm plantations.

  17. Transpiration in an oil palm landscape: effects of palm age

    NASA Astrophysics Data System (ADS)

    Röll, A.; Niu, F.; Meijide, A.; Hardanto, A.; Hendrayanto; Knohl, A.; Hölscher, D.

    2015-10-01

    epiphytes. Diurnally, oil palm transpiration rates were characterized by an early peak between 10 and 11 a.m.; there was a pronounced hysteresis in the leaf water use response to changes in vapor pressure deficit for all palms of advanced age. On the day-to-day basis this resulted in a relatively low variability of oil palm water use regardless of fluctuations in vapor pressure deficit and radiation. We conclude that oil palm dominated landscapes show some spatial variations in (evapo)transpiration rates, e.g., due to varying age-structures, but that the temporal variability of oil palm transpiration is rather low. The stand transpiration of some of the studied oil palm stands was as high or even higher than values reported for different tropical forests, indicating a high water use of oil palms under yet to be explained site or management conditions. Our study provides first insights into the eco-hydrological characteristics of oil palms as well as a first estimate of oil palm water use across a gradient of plantation age. It sheds first light on some of the hydrological consequences of the continuing expansion of oil palm plantations.

  18. Herbal treatments for alleviating premenstrual symptoms: a systematic review.

    PubMed

    Dante, Giulia; Facchinetti, Fabio

    2011-03-01

    Premenstrual syndrome (PMS) is a condition of cyclical and recurrent physical and psychological discomfort occurring 1 to 2 weeks before menstrual period. More severe psychological symptoms have been described for the premenstrual dysphoric disorder (PMDD). No single treatment is universally recognised as effective and many patients often turn to therapeutic approaches outside of conventional medicine. This systematic review is aimed at analysing the effects of herb remedies in the above conditions. Systematic literature searches were performed in electronic databases, covering the period January 1980 to September 2010. Randomised controlled clinical trials (RCTs) were included. Papers quality was evaluated with the Jadad' scale. A further evaluation of PMS/PMDD diagnostic criteria was also done. Of 102 articles identified, 17 RCTs were eligible and 10 of them were included. The heterogeneity of population included, study design and outcome presentation refrained from a meta-analysis. Vitex agnus castus was the more investigated remedy (four trials, about 500 women), and it was reported to consistently ameliorate PMS better than placebo. Single trials also support the use of either Gingko biloba or Crocus sativus. On the contrary, neither evening primrose oil nor St. John's Wort show an effect different than placebo. None of the herbs was associated with major health risks, although the reduced number of tested patients does not allow definitive conclusions on safety. Some herb remedies seem useful for the treatment of PMS. However, more RCTs are required to account for the heterogeneity of the syndrome.

  19. Therapeutic Effects of Korean Red Ginseng Extract in a Murine Model of Atopic Dermatitis: Anti-pruritic and Anti-inflammatory Mechanism

    PubMed Central

    2017-01-01

    Korean red ginseng (KRG) and ginsenosides exhibit diverse biological effects, including anti-inflammatory and anti-allergic. We aimed to investigate the therapeutic effect of KRG in a murine model of atopic dermatitis (AD) is mediated whether by diminishing the pruritus or by suppressing the inflammation. Thirty NC/Nga mice were randomly divided to 5 groups. AD-like skin lesions were induced by percutaneous challenge with 2,4,6-trinitro-1-chrolobenzene (TNCB) on the ears and backs of NC/Nga mice. KRG extract, evening primrose oil, cyclosporine, and phosphate-buffered saline were administered orally by a gastric tube. Each study group was also divided into scratching-permitted and scratching-restricted subgroups to evaluate the impact of scratching behavior on AD. The effects of KRG and the other agents were assessed by measuring the clinical severity score, ear thickness, extent of transepidermal water loss (TEWL), number of scratching movements, total systemic immunoglobulin E (IgE) and interleukin (IL)-31 levels, histologic changes of cutaneous lesions, and mRNA expression levels of tumor necrosis factor (TNF)-α, interferon (IFN)-γ, thymic stromal lymphopoietin (TSLP), and IL-31. KRG exerts therapeutic effects against AD by inhibiting the T helper 2 (Th2) mediated inflammation as well as by diminishing the itching sensation. Moreover, restricting scratching behavior suppresses the vicious cycle of itching and scratching, thus reducing clinical and systemic inflammation in our murine model of AD. PMID:28244297

  20. Oil from hydrocracking as a raw material for the production of white oils

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Potanina, V.A.; Dremova, T.I.; Ponomareva, T.P.

    1984-01-01

    This article investigates the feasibility of using distillate oil from hydrocracking for white oil production. A process technology has been developed in the USSR for the manufacture of high-quality oils by hydrocracking a heavy distillate feed in high-pressure equipment. The neutral and hydrocracked oil sample and a blend of these stocks were subjected to treatment with oleum, neutralization with 65% ethyl alcohol, and contact finishing to obtain white oils. The physicochemical properties of the white oils are given. It is determined that the hydrocracked oil can be used as the raw material in manufacturing perfume oil meeting the standard GOSTmore » 4225-76, and that the blends can be used to obtain pharmaceutical white oil meeting the standard GOST 3164-78.« less

  1. Extra virgin olive oil: from composition to "molecular gastronomy".

    PubMed

    Sacchi, Raffaele; Paduano, Antonello; Savarese, Maria; Vitaglione, Paola; Fogliano, Vincenzo

    2014-01-01

    The aim of this chapter is to provide a brief overview of the recent results of studies on extra virgin olive oil (EVOO) and its interactions with other food ingredients during cooking, to highlight basic molecular aspects of the "magic" of EVOO and its role in Mediterranean gastronomy. The use of raw EVOO added to foods after cooking (or as a salad oil) is the best way to express the original flavour and to maximize the intake of natural antioxidants and compounds related to positive effects on human health (hypotensive, anti-inflammatory, and anti-cancerogenic, among others). EVOO, however, also exhibits its protective properties during/after cooking. Different chemical interactions between biophenolic compounds and other food ingredients (water, milk proteins, carotenoids of tomato, omega-3 polyunsaturated fatty acids in canned-in-oil fish and meat or fish proteins) occur. Even during cooking, EVOO exhibits strong antioxidant properties and influences the overall flavour of cooked foods. The physical (partitioning, emulsion) and chemical (hydrolysis, covalent binding, antioxidant properties) phenomena occurring during cooking of EVOO are discussed with emphasis on the changes in the sensory (bitterness and fruity flavour) and nutritional qualities of some traditional Mediterranean foods. In particular, tomato-oil interactions during cooking, fish canning in EVOO, meat marinated in EVOO before cooking and roasting and frying in EVOO are examined. The interactions between EVOO antioxidants and flavours with milk proteins are also briefly discussed.

  2. The Fate of Crude Oil during Photooxidation under Natural Sunlight

    NASA Astrophysics Data System (ADS)

    Wang, Q.; Evans, M.; Bacosa, H. P.; Hu, X.; Liu, Z.

    2016-02-01

    Photooxidation plays an important role in removing spilled crude oil, particularly the aromatic fraction, in surface seawater. Even though much research has been done regarding the changes of different oil fractions by photooxidation, including saturate, aromatic, resin and asphaltene (SARA), we know little about how specific aromatic compounds change in the SARA fractions during photooxidation. In this study, we amended 13C-labled phenanthrene in slightly weathered Louisiana light sweet crude, and followed the fates of 13C values of the SARA fractions during a 44-d incubation experiment under the natural sunlight in south Texas. Our results showed that the aromatic fraction of the crude decreased from 25.4% at time zero to 13.5% at the 44th d, while the resin increased from 12.2% to 16.5% and asphaltene from 2.4% to 13.3%, respectively. This result indicates the aromatic was transformed mostly into asphaltene by photooxidation, and most of the changes took place within the first 10 d. In contrast, no significant difference was observed in the SARA fractions in the dark controls. Analyses of 13C values and phenanthrene concentrations in the SARA fractions are currently on going and will be presented. Results from this experiment provide insights into changes of specific aromatic compounds within oil fractions by photochemical oxidation during oil weathering in the ocean.

  3. Colorado Even Start Progress Report, 2001-2002.

    ERIC Educational Resources Information Center

    Anderson, Beckie

    Even Start programs integrate early childhood education, adult literacy or basic education, parenting education and support, and parent and child time together to help break the cycle of poverty and illiteracy. This progress report describes the Even Start program in Colorado and presents evaluation findings from the 2001-2002 implementation year,…

  4. Nylon 6,6 Nonwoven Fabric Separates Oil Contaminates from Oil-in-Water Emulsions.

    PubMed

    Ortega, Ryan A; Carter, Erin S; Ortega, Albert E

    2016-01-01

    Industrial oil spills into aquatic environments can have catastrophic environmental effects. First responders to oil spills along the coast of the Gulf of Mexico in the southern United States have used spunbond nylon fabric bags and fences to separate spilled oil and oil waste from contaminated water. Low area mass density spunbond nylon is capable of sorbing more than 16 times its mass in low viscosity crude oil and more than 26 times its mass in higher viscosity gear lube oil. Nylon bags separated more than 95% of gear lube oil contaminate from a 4.5% oil-in-water emulsion. Field testing of spunbond nylon fences by oil spill first responders has demonstrated the ability of this material to contain the oily contaminate while allowing water to flow through. We hypothesize that the effectiveness of nylon as an oil filter is due to the fact that it is both more oleophilic and more hydrophilic than other commonly used oil separation materials. The nylon traps oil droplets within the fabric or on the surface, while water droplets are free to flow through the fabric to the water on the opposite side of the fabric.

  5. Nylon 6,6 Nonwoven Fabric Separates Oil Contaminates from Oil-in-Water Emulsions

    PubMed Central

    Carter, Erin S.; Ortega, Albert E.

    2016-01-01

    Industrial oil spills into aquatic environments can have catastrophic environmental effects. First responders to oil spills along the coast of the Gulf of Mexico in the southern United States have used spunbond nylon fabric bags and fences to separate spilled oil and oil waste from contaminated water. Low area mass density spunbond nylon is capable of sorbing more than 16 times its mass in low viscosity crude oil and more than 26 times its mass in higher viscosity gear lube oil. Nylon bags separated more than 95% of gear lube oil contaminate from a 4.5% oil-in-water emulsion. Field testing of spunbond nylon fences by oil spill first responders has demonstrated the ability of this material to contain the oily contaminate while allowing water to flow through. We hypothesize that the effectiveness of nylon as an oil filter is due to the fact that it is both more oleophilic and more hydrophilic than other commonly used oil separation materials. The nylon traps oil droplets within the fabric or on the surface, while water droplets are free to flow through the fabric to the water on the opposite side of the fabric. PMID:27411088

  6. A review of oil, dispersed oil and sediment interactions in the aquatic environment: influence on the fate, transport and remediation of oil spills.

    PubMed

    Gong, Yanyan; Zhao, Xiao; Cai, Zhengqing; O'Reilly, S E; Hao, Xiaodi; Zhao, Dongye

    2014-02-15

    The 2010 Deepwater Horizon oil spill has spurred significant amounts of researches on fate, transport, and environmental impacts of oil and oil dispersants. This review critically summarizes what is understood to date about the interactions between oil, oil dispersants and sediments, their roles in developing oil spill countermeasures, and how these interactions may change in deepwater environments. Effects of controlling parameters, such as sediment particle size and concentration, organic matter content, oil properties, and salinity on oil-sediment interactions are described in detail. Special attention is placed to the application and effects of oil dispersants on the rate and extent of the interactions between oil and sediment or suspended particulate materials. Various analytical methods are discussed for characterization of oil-sediment interactions. Current knowledge gaps are identified and further research needs are proposed to facilitate sounder assessment of fate and impacts of oil spills in the marine environment. Copyright © 2013 Elsevier Ltd. All rights reserved.

  7. In situ burning of oil in coastal marshes. 1. Vegetation recovery and soil temperature as a function of water depth, oil type, and marsh type.

    PubMed

    Lin, Qianxin; Mendelssohn, Irving A; Bryner, Nelson P; Walton, William D

    2005-03-15

    In-situ burning of oiled wetlands potentially provides a cleanup technique that is generally consistent with present wetland management procedures. The effects of water depth (+10, +2, and -2 cm), oil type (crude and diesel), and oil penetration of sediment before the burn on the relationship between vegetation recovery and soil temperature for three coastal marsh types were investigated. The water depth over the soil surface during in-situ burning was a key factor controlling marsh plant recovery. Both the 10- and 2-cm water depths were sufficient to protect marsh vegetation from burning impacts, with surface soil temperatures of <35 and 48 degrees C, respectively. Plant survival rate and growth responses at these water depth burns were not significantly different from the unburned control. In contrast, a water table 2 cm below the soil surface during the burn resulted in high soil temperatures, with 90-200 degrees C at 0-0.5 cm soil depth and 55-75 degrees C at 1-2 cm soil depth. The 2-cm soil exposure to fire significantly impeded the post-burn recovery of Spartina alterniflora and Sagittaria lancifolia but did not detrimentally affect the recovery of Spartina patens and Distichlis spicata. Oil type (crude vs diesel) and oil applied to the marsh soil surface (0.5 L x m(-2)) before the burn did not significantly affect plant recovery. Thus, recovery is species-specific when no surface water exists. Even water at the soil surface will most likely protect wetland plants from burning impact.

  8. Clean and Secure Energy from Domestic Oil Shale and Oil Sands Resources

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Spinti, Jennifer; Birgenheier, Lauren; Deo, Milind

    This report summarizes the significant findings from the Clean and Secure Energy from Domestic Oil Shale and Oil Sands Resources program sponsored by the Department of Energy through the National Energy Technology Laboratory. There were four principle areas of research; Environmental, legal, and policy issues related to development of oil shale and oil sands resources; Economic and environmental assessment of domestic unconventional fuels industry; Basin-scale assessment of conventional and unconventional fuel development impacts; and Liquid fuel production by in situ thermal processing of oil shale Multiple research projects were conducted in each area and the results have been communicated viamore » sponsored conferences, conference presentations, invited talks, interviews with the media, numerous topical reports, journal publications, and a book that summarizes much of the oil shale research relating to Utah’s Uinta Basin. In addition, a repository of materials related to oil shale and oil sands has been created within the University of Utah’s Institutional Repository, including the materials generated during this research program. Below is a listing of all topical and progress reports generated by this project and submitted to the Office of Science and Technical Information (OSTI). A listing of all peer-reviewed publications generated as a result of this project is included at the end of this report; Geomechanical and Fluid Transport Properties 1 (December, 2015); Validation Results for Core-Scale Oil Shale Pyrolysis (February, 2015); and Rates and Mechanisms of Oil Shale Pyrolysis: A Chemical Structure Approach (November, 2014); Policy Issues Associated With Using Simulation to Assess Environmental Impacts (November, 2014); Policy Analysis of the Canadian Oil Sands Experience (September, 2013); V-UQ of Generation 1 Simulator with AMSO Experimental Data (August, 2013); Lands with Wilderness Characteristics, Resource Management Plan Constraints, and Land

  9. Nuclear spectroscopy of doubly-even130,132Ba

    NASA Astrophysics Data System (ADS)

    Gupta, Anuradha; Gupta, Surbhi; Singh, Suram; Bharti, Arun

    2018-05-01

    A comparative study of some high-spin characteristic nuclear structure properties of doubly-even 130,132Ba nuclei has been made using two microscopic frameworks - CHFB and PSM. The yrast spectra, intrinsic quadrupole moment and deformation systematics of these nuclei have been successfully calculated. Further, the calculated data from both the frameworks is also compared with the available experimental data and a good agreement has been obtained. The present CHFB calculations describes very well the low spin structure of even-even 130,132Ba nuclei whereas PSM calculations provide a qualitative description of the high-spin band structure of doubly-even 130,132Ba nuclei.

  10. An Estimate of Recoverable Heavy Oil Resources of the Orinoco Oil Belt, Venezuela

    USGS Publications Warehouse

    Schenk, Christopher J.; Cook, Troy A.; Charpentier, Ronald R.; Pollastro, Richard M.; Klett, Timothy R.; Tennyson, Marilyn E.; Kirschbaum, Mark A.; Brownfield, Michael E.; Pitman, Janet K.

    2009-01-01

    The Orinoco Oil Belt Assessment Unit of the La Luna-Quercual Total Petroleum System encompasses approximately 50,000 km2 of the East Venezuela Basin Province that is underlain by more than 1 trillion barrels of heavy oil-in-place. As part of a program directed at estimating the technically recoverable oil and gas resources of priority petroleum basins worldwide, the U.S. Geological Survey estimated the recoverable oil resources of the Orinoco Oil Belt Assessment Unit. This estimate relied mainly on published geologic and engineering data for reservoirs (net oil-saturated sandstone thickness and extent), petrophysical properties (porosity, water saturation, and formation volume factors), recovery factors determined by pilot projects, and estimates of volumes of oil-in-place. The U.S. Geological Survey estimated a mean volume of 513 billion barrels of technically recoverable heavy oil in the Orinoco Oil Belt Assessment Unit of the East Venezuela Basin Province; the range is 380 to 652 billion barrels. The Orinoco Oil Belt Assessment Unit thus contains one of the largest recoverable oil accumulations in the world.

  11. Valorisation of wastewater from two-phase olive oil extraction in fired clay brick production.

    PubMed

    de la Casa, José A; Lorite, Miguel; Jiménez, Juan; Castro, Eulogio

    2009-09-30

    Wastewater issued from oil-washing stage (OWW) in the two-phase olive oil extraction method was used to replace fresh water in clay brick manufacture. The extrusion trials were performed with one of the ceramic bodies currently being used in a local brick factory for red facing bricks (RB) production. Fresh water or OWW was added to a final consistency of 2.4 kg/cm(2), the same value as used at industrial scale for this kind of clay mixture. Comparative results of technological properties of facing bricks are presented. Results show that the products obtained with olive oil wastewater are comparable to traditional ones in terms of extrusion performance and technological properties of end products. Even dry-bending strength of the body formed by wastewater improves by 33% compared to fresh water body. In addition, heating requirements can be reduced in the range 2.4-7.3% depending on the final product. This application can alleviate environmental impacts from the olive oil extraction industry and, at the same time, result in economic savings for the brick manufacturing industry.

  12. Alterations of hippocampal glucose metabolism by even versus uneven medium chain triglycerides

    PubMed Central

    McDonald, Tanya S; Tan, Kah Ni; Hodson, Mark P; Borges, Karin

    2014-01-01

    Medium chain triglycerides (MCTs) are used to treat neurologic disorders with metabolic impairments, including childhood epilepsy and early Alzheimer's disease. However, the metabolic effects of MCTs in the brain are still unclear. Here, we studied the effects of feeding even and uneven MCTs on brain glucose metabolism in the mouse. Adult mice were fed 35% (calories) of trioctanoin or triheptanoin (the triglycerides of octanoate or heptanoate, respectively) or a matching control diet for 3 weeks. Enzymatic assays and targeted metabolomics by liquid chromatography tandem mass spectrometry were used to quantify metabolites in extracts from the hippocampal formations (HFs). Both oils increased the levels of β-hydroxybutyrate, but no other significant metabolic alterations were observed after triheptanoin feeding. The levels of glucose 6-phosphate and fructose 6-phosphate were increased in the HF of mice fed trioctanoin, whereas levels of metabolites further downstream in the glycolytic pathway and the pentose phosphate pathway were reduced. This indicates that trioctanoin reduces glucose utilization because of a decrease in phosphofructokinase activity. Trioctanoin and triheptanoin showed similar anticonvulsant effects in the 6 Hz seizure model, but it remains unknown to what extent the anticonvulsant mechanism(s) are shared. In conclusion, triheptanoin unlike trioctanoin appears to not alter glucose metabolism in the healthy brain. PMID:24169853

  13. Alterations of hippocampal glucose metabolism by even versus uneven medium chain triglycerides.

    PubMed

    McDonald, Tanya S; Tan, Kah Ni; Hodson, Mark P; Borges, Karin

    2014-01-01

    Medium chain triglycerides (MCTs) are used to treat neurologic disorders with metabolic impairments, including childhood epilepsy and early Alzheimer's disease. However, the metabolic effects of MCTs in the brain are still unclear. Here, we studied the effects of feeding even and uneven MCTs on brain glucose metabolism in the mouse. Adult mice were fed 35% (calories) of trioctanoin or triheptanoin (the triglycerides of octanoate or heptanoate, respectively) or a matching control diet for 3 weeks. Enzymatic assays and targeted metabolomics by liquid chromatography tandem mass spectrometry were used to quantify metabolites in extracts from the hippocampal formations (HFs). Both oils increased the levels of β-hydroxybutyrate, but no other significant metabolic alterations were observed after triheptanoin feeding. The levels of glucose 6-phosphate and fructose 6-phosphate were increased in the HF of mice fed trioctanoin, whereas levels of metabolites further downstream in the glycolytic pathway and the pentose phosphate pathway were reduced. This indicates that trioctanoin reduces glucose utilization because of a decrease in phosphofructokinase activity. Trioctanoin and triheptanoin showed similar anticonvulsant effects in the 6 Hz seizure model, but it remains unknown to what extent the anticonvulsant mechanism(s) are shared. In conclusion, triheptanoin unlike trioctanoin appears to not alter glucose metabolism in the healthy brain.

  14. Fluidized-bed pyrolysis of oil shale: oil yield, composition, and kinetics

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Richardson, J H; Huss, E B; Ott, L L

    1982-09-01

    A quartz isothermal fluidized-bed reactor has been used to measure kinetics and oil properties relevant to surface processing of oil shale. The rate of oil formation has been described with two sequential first-order rate equations characterized by two rate constants, k/sub 1/ = 2.18 x 10/sup 10/ exp(-41.6 kcal/RT) s/sup -1/ and k/sub 2/ = 4.4 x 10/sup 6/ exp(-29.7 kcal/RT) s/sup -1/. These rate constants together with an expression for the appropriate weighting coefficients describe approximately 97/sup +/% of the total oil produced. A description is given of the results of different attempts to mathematically describe the data inmore » a manner suitable for modeling applications. Preliminary results are also presented for species-selective kinetics of methane, ethene, ethane and hydrogen, where the latter is clearly distinguished as the product of a distinct intermediate. Oil yields from Western oil shale are approximately 100% Fischer assay. Oil composition is as expected based on previous work and the higher heating rates (temperatures) inherent in fluidized-bed pyrolysis. Neither the oil yield, composition nor the kinetics varied with particle size between 0.2 and 2.0 mm within experimental error. The qualitatively expected change in oil composition due to cracking was observed over the temperature range studied (460 to 540/sup 0/C). Eastern shale exhibited significantly faster kinetics and higher oil yields than did Western shale.« less

  15. A photometric method for the estimation of the oil yield of oil shale

    USGS Publications Warehouse

    Cuttitta, Frank

    1951-01-01

    A method is presented for the distillation and photometric estimation of the oil yield of oil-bearing shales. The oil shale is distilled in a closed test tube and the oil extracted with toluene. The optical density of the toluene extract is used in the estimation of oil content and is converted to percentage of oil by reference to a standard curve. This curve is obtained by relating the oil yields determined by the Fischer assay method to the optical density of the toluene extract of the oil evolved by the new procedure. The new method gives results similar to those obtained by the Fischer assay method in a much shorter time. The applicability of the new method to oil-bearing shale and phosphatic shale has been tested.

  16. [Effects of low doses of essential oil on the antioxidant state of the erythrocytes, liver, and the brains of mice].

    PubMed

    Misharina, T A; Fatkullina, L D; Alinkina, E S; Kozachenko, A I; Nagler, L G; Medvedeva, I B; Goloshchapov, A N; Burlakova, E B

    2014-01-01

    We studied the effects of essential oil from oregano and clove and a mixture of lemon essential oil and a ginger extract on the antioxidant state of organs in intact and three experimental groups of Bulb mice. We found that the essential oil was an efficient in vivo bioantioxidant when mice were treated with it for 6 months even at very low doses, such as 300 ng/day. All essential oil studied inhibited lipid peroxidation (LPO) in the membranes of erythrocytes that resulted in increased membrane resistance to spontaneous hemolysis, decreased membrane microviscosity, maintenance of their structural integrity, and functional activity. The essential oil substantially decreased the LPO intensity in the liver and the brains of mice and increased the resistance of liver and brain lipids to oxidation and the activity of antioxidant enzymes in the liver. The most expressed bioantioxidant effect on erythrocytes was observed after clove oil treatment, whereas on the liver and brain, after treatment with a mixture of lemon essential oil and a ginger extract.

  17. Effects on bread and oil quality after functionalization with microencapsulated chia oil.

    PubMed

    González, Agustín; Martínez, Marcela L; León, Alberto E; Ribotta, Pablo D

    2018-03-23

    Omega-3 and omega-6 fatty acids-rich oils suffer oxidation reactions that alter their chemical and organoleptic quality. Microencapsulation can be a powerful tool for protection against ambient conditions. In the present study, the addition of microencapsulated chia oil as an ingredient in bread preparations and its effect on the technological and chemical quality of breads was investigated. Microencapsulation of chia oil was carried out by freeze-drying with soy proteins as wall material and oil release was determined under in vitro gastric and intestinal conditions. Encapsulated oil-containing bread showed no differences in specific volume, average cell area, firmness and chewiness with respect to control bread. Unencapsulated oil-containing bread showed a marked increase in hydroperoxide values respect to control, whereas encapsulated oil-containing bread values were not affected by baking and bread storage. The fatty acid profiles showed a decrease of 13% and 16%, respectively, in α-linolenic acid in the encapsulated and unencapsulated oils with respect to bulk chia oil. Sensory analysis showed no significant differences between bread samples. The addition of encapsulated chia oil did not alter the technological quality of breads and prevented the formation of hydroperoxide radicals. A ration of encapsulated oil-containing bread contributes 60% of the recommended dietary intake of omega-3 fatty acids. © 2018 Society of Chemical Industry. © 2018 Society of Chemical Industry.

  18. Key glycolytic branch influences mesocarp oil content in oil palm.

    PubMed

    Ruzlan, Nurliyana; Low, Yoke Sum Jaime; Win, Wilonita; Azizah Musa, Noor; Ong, Ai-Ling; Chew, Fook-Tim; Appleton, David; Mohd Yusof, Hirzun; Kulaveerasingam, Harikrishna

    2017-08-29

    The fructose-1,6-bisphosphate aldolase catalyzed glycolysis branch that forms dihydroxyacetone phosphate and glyceraldehyde-3-phosphate was identified as a key driver of increased oil synthesis in oil palm and was validated in Saccharomyces cerevisiae. Reduction in triose phosphate isomerase (TPI) activity in a yeast knockdown mutant resulted in 19% increase in lipid content, while yeast strains overexpressing oil palm fructose-1,6-bisphosphate aldolase (EgFBA) and glycerol-3-phosphate dehydrogenase (EgG3PDH) showed increased lipid content by 16% and 21%, respectively. Genetic association analysis on oil palm SNPs of EgTPI SD_SNP_000035801 and EgGAPDH SD_SNP_000041011 showed that palms harboring homozygous GG in EgTPI and heterozygous AG in EgGAPDH exhibited higher mesocarp oil content based on dry weight. In addition, AG genotype of the SNP of EgG3PDH SD_SNP_000008411 was associated with higher mean mesocarp oil content, whereas GG genotype of the EgFBA SNP SD_SNP_000007765 was favourable. Additive effects were observed with a combination of favourable alleles in TPI and FBA in Nigerian x AVROS population (family F7) with highest allele frequency GG.GG being associated with a mean increase of 3.77% (p value = 2.3E -16 ) oil content over the Family 1. An analogous effect was observed in yeast, where overexpressed EgFBA in TPI - resulted in a 30% oil increment. These results provide insights into flux balances in glycolysis leading to higher yield in mesocarp oil-producing fruit.

  19. Replacing fossil oil with fresh oil – with what and for what?

    PubMed Central

    Carlsson, Anders S; Yilmaz, Jenny Lindberg; Green, Allan G; Stymne, Sten; Hofvander, Per

    2011-01-01

    Industrial chemicals and materials are currently derived mainly from fossil-based raw materials, which are declining in availability, increasing in price and are a major source of undesirable greenhouse gas emissions. Plant oils have the potential to provide functionally equivalent, renewable and environmentally friendly replacements for these finite fossil-based raw materials, provided that their composition can be matched to end-use requirements, and that they can be produced on sufficient scale to meet current and growing industrial demands. Replacement of 40% of the fossil oil used in the chemical industry with renewable plant oils, whilst ensuring that growing demand for food oils is also met, will require a trebling of global plant oil production from current levels of around 139 MT to over 400 MT annually. Realisation of this potential will rely on application of plant biotechnology to (i) tailor plant oils to have high purity (preferably >90%) of single desirable fatty acids, (ii) introduce unusual fatty acids that have specialty end-use functionalities and (iii) increase plant oil production capacity by increased oil content in current oil crops, and conversion of other high biomass crops into oil accumulating crops. This review outlines recent progress and future challenges in each of these areas. Practical applications: The research reviewed in this paper aims to develop metabolic engineering technologies to radically increase the yield and alter the fatty acid composition of plant oils and enable the development of new and more productive oil crops that can serve as renewable sources of industrial feedstocks currently provided by non-renewable and polluting fossil-based resources. As a result of recent and anticipated research developments we can expect to see significant enhancements in quality and productivity of oil crops over the coming decades. This should generate the technologies needed to support increasing plant oil production into the future

  20. Floral and vegetative cues in oil-secreting and non-oil-secreting Lysimachia species

    PubMed Central

    Schäffler, I.; Balao, F.; Dötterl, S.

    2012-01-01

    Background and Aims Unrelated plants pollinated by the same group or guild of animals typically evolve similar floral cues due to pollinator-mediated selection. Related plant species, however, may possess similar cues either as a result of pollinator-mediated selection or as a result of sharing a common ancestor that possessed the same cues or traits. In this study, visual and olfactory floral cues in Lysimachia species exhibiting different pollination strategies were analysed and compared, and the importance of pollinators and phylogeny on the evolution of these floral cues was determined. For comparison, cues of vegetative material were examined where pollinator selection would not be expected. Methods Floral and vegetative scents and colours in floral oil- and non-floral oil-secreting Lysimachia species were studied by chemical and spectrophotometric analyses, respectively, compared between oil- and non-oil-secreting species, and analysed by phylogenetically controlled methods. Key Results Vegetative and floral scent was species specific, and variability in floral but not vegetative scent was lower in oil compared with non-oil species. Overall, oil species did not differ in their floral or vegetative scent from non-oil species. However, a correlation was found between oil secretion and six floral scent constituents specific to oil species, whereas the presence of four other floral compounds can be explained by phylogeny. Four of the five analysed oil species had bee-green flowers and the pattern of occurrence of this colour correlated with oil secretion. Non-oil species had different floral colours. The colour of leaves was similar among all species studied. Conclusions Evidence was found for correlated evolution between secretion of floral oils and floral but not vegetative visual and olfactory cues. The cues correlating with oil secretion were probably selected by Macropis bees, the specialized pollinators of oil-secreting Lysimachia species, and may have

  1. Oil point and mechanical behaviour of oil palm kernels in linear compression

    NASA Astrophysics Data System (ADS)

    Kabutey, Abraham; Herak, David; Choteborsky, Rostislav; Mizera, Čestmír; Sigalingging, Riswanti; Akangbe, Olaosebikan Layi

    2017-07-01

    The study described the oil point and mechanical properties of roasted and unroasted bulk oil palm kernels under compression loading. The literature information available is very limited. A universal compression testing machine and vessel diameter of 60 mm with a plunger were used by applying maximum force of 100 kN and speed ranging from 5 to 25 mm min-1. The initial pressing height of the bulk kernels was measured at 40 mm. The oil point was determined by a litmus test for each deformation level of 5, 10, 15, 20, and 25 mm at a minimum speed of 5 mmmin-1. The measured parameters were the deformation, deformation energy, oil yield, oil point strain and oil point pressure. Clearly, the roasted bulk kernels required less deformation energy compared to the unroasted kernels for recovering the kernel oil. However, both kernels were not permanently deformed. The average oil point strain was determined at 0.57. The study is an essential contribution to pursuing innovative methods for processing palm kernel oil in rural areas of developing countries.

  2. Large Oil Spill Classification Using SAR Images Based on Spatial Histogram

    NASA Astrophysics Data System (ADS)

    Schvartzman, I.; Havivi, S.; Maman, S.; Rotman, S. R.; Blumberg, D. G.

    2016-06-01

    Among the different types of marine pollution, oil spill is a major threat to the sea ecosystems. Remote sensing is used in oil spill response. Synthetic Aperture Radar (SAR) is an active microwave sensor that operates under all weather conditions and provides information about the surface roughness and covers large areas at a high spatial resolution. SAR is widely used to identify and track pollutants in the sea, which may be due to a secondary effect of a large natural disaster or by a man-made one . The detection of oil spill in SAR imagery relies on the decrease of the backscattering from the sea surface, due to the increased viscosity, resulting in a dark formation that contrasts with the brightness of the surrounding area. Most of the use of SAR images for oil spill detection is done by visual interpretation. Trained interpreters scan the image, and mark areas of low backscatter and where shape is a-symmetrical. It is very difficult to apply this method for a wide area. In contrast to visual interpretation, automatic detection algorithms were suggested and are mainly based on scanning dark formations, extracting features, and applying big data analysis. We propose a new algorithm that applies a nonlinear spatial filter that detects dark formations and is not susceptible to noises, such as internal or speckle. The advantages of this algorithm are both in run time and the results retrieved. The algorithm was tested in genesimulations as well as on COSMO-SkyMed images, detecting the Deep Horizon oil spill in the Gulf of Mexico (occurred on 20/4/2010). The simulation results show that even in a noisy environment, oil spill is detected. Applying the algorithm to the Deep Horizon oil spill, the algorithm classified the oil spill better than focusing on dark formation algorithm. Furthermore, the results were validated by the National Oceanic and Atmospheric Administration (NOAA) data.

  3. Automotive gear oil lubricant from soybean oil

    USDA-ARS?s Scientific Manuscript database

    The use of lubricants that are based on renewable materials is rapidly increasing. Vegetable oils have good lubricity, wear protection and low volatility which are desired properties for automotive gear lubricant applications. Soybean oil is used widely in the lubricant industry due to its properti...

  4. Oil-return characteristics of refrigerant oils in split heat pump system

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sundaresan, S.G.; Radermacher, R.

    1996-08-01

    Currently, HFC substitute refrigerants for R-22 are being evaluated in air-conditioning and heat pump applications. The oil return characteristics and heat transfer effects of the lubricants are being studied again. Based on commercial refrigeration experience POEs are the lubricants of choice for HFC refrigerants. POEs have two major drawbacks: hygroscopicity and high cost. Thus the question is raised to what extent is it possible to replace POEs with a lower cost, but immiscible, oil such as mineral oil. It is the purpose of this study to experimentally investigate the oil return behavior of R-407C with mineral oil in a splitmore » three-ton heat pump in comparison to R407C/POE and R-22/Mineral Oil.« less

  5. Fuel oil poisoning

    MedlinePlus

    These substances are found in: Fuel oil Kerosene Gasoline There may be other sources of fuel oil. ... swallowing fuel oil. The main danger from swallowing kerosene is that it can also go into your ...

  6. Utah Heavy Oil Program

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    J. Bauman; S. Burian; M. Deo

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987more » technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.« less

  7. Frying stability of rapeseed Kizakinonatane (Brassica napus) oil in comparison with canola oil.

    PubMed

    Ma, Jin-Kui; Zhang, Han; Tsuchiya, Tomohiro; Akiyama, Yoshinobu; Chen, Jie-Yu

    2015-04-01

    This study was carried out to investigate the frying performance of Kizakinonatane (Brassica napus) oil during deep-fat frying of frozen French fries with/without replenishment. Commercial regular canola oil was used for comparison. The frying oils were used during intermittent frying of frozen French fries at 180, 200, and 220 ℃ for 7 h daily over four consecutive days. The Kizakinonatane oil exhibited lower levels of total polar compounds, carbonyl value, and viscosity as well as comparable color (optical density) values to that of the canola oil. The monounsaturated fatty acid/polyunsaturated fatty acid ratios were lower than that of canola oil, whereas the polyunsaturated fatty acid/saturated fatty acid ratios are higher than that of canola oil after heating. Results showed that fresh Kizakinonatane oil contains higher levels of acid value, viscosity, optical density values, tocopherols, and total phenolics contents than that of canola oil. Replenishment with fresh oil had significant effects on all chemical and physical parameters, except the acid value of the Kizakinonatane oil during frying processes. Based on the results, the Kizakinonatane oil is inherently suitable for preparing deep-fried foods at high temperatures. © The Author(s) 2014 Reprints and permissions: sagepub.co.uk/journalsPermissions.nav.

  8. Toxicity of weathered Deepwater Horizon oil to bay anchovy (Anchoa mitchilli) embryos.

    PubMed

    O'Shaughnessy, Kathryn A; Forth, Heather; Takeshita, Ryan; Chesney, Edward J

    2018-02-01

    The BP-contracted Deepwater Horizon Macondo well blowout occurred on 20 April 2010 and lasted nearly three months. The well released millions of barrels of crude oil into the northern Gulf of Mexico, causing extensive impacts on pelagic, benthic, and estuarine fish species. The bay anchovy (Anchoa mitchilli) is an important zooplanktivore in the Gulf, serving as an ecological link between lower trophic levels and pelagic predatory fish species. Bay anchovy spawn from May through November in shallow inshore and estuarine waters throughout the Gulf. Because their buoyant embryos are a dominant part of the inshore ichthyoplankton throughout the summer, it is likely bay anchovy embryos encountered oil in coastal estuaries during the summer and fall of 2010. Bay anchovy embryos were exposed to a range of concentrations of two field-collected Deepwater Horizon oils as high-energy and low-energy water accommodated fractions (HEWAFs and LEWAFs, respectively) for 48h. The median lethal concentrations (LC 50 ) were lower in exposures with the more weathered oil (HEWAF, 1.48µg/L TPAH50; LEWAF, 1.58µg/L TPAH50) compared to the less weathered oil (HEWAF, 3.87µg/L TPAH50; LEWAF, 4.28µg/L TPAH50). To measure delayed mortality and life stage sensitivity between embryos and larvae, an additional 24h acute HEWAF exposure using the more weathered oil was run followed by a 24h grow-out period. Here the LC 50 was 9.71µg/L TPAH50 after the grow-out phase, suggesting a toxic effect of oil at the embryonic or hatching stage. We also found that exposures prepared with the more weathered Slick B oil produced lower LC 50 values compared to the exposures prepared with Slick A oil. Our results demonstrate that even relatively acute environmental exposure times can have a detrimental effect on bay anchovy embryos. Copyright © 2017 Elsevier Inc. All rights reserved.

  9. Pilot-scale production of biodiesel from waste fats and oils using tetramethylammonium hydroxide.

    PubMed

    Šánek, Lubomír; Pecha, Jiří; Kolomazník, Karel; Bařinová, Michaela

    2016-02-01

    Annually, a great amount of waste fats and oils not suitable for human consumption or which cannot be further treated are produced around the world. A potential way of utilizing this low-cost feedstock is its conversion into biodiesel. The majority of biodiesel production processes today are based on the utilization of inorganic alkali catalysts. However, it has been proved that an organic base - tetramethylammonium hydroxide - can be used as a very efficient transesterification catalyst. Furthermore, it can be employed for the esterification of free fatty acids - reducing even high free fatty acid contents to the required level in just one step. The work presented herein, is focused on biodiesel production from waste frying oils and animal fats using tetramethylammonium hydroxide at the pilot-plant level. The results showed that the process performance in the pilot unit - using methanol and TMAH as a catalyst, is comparable to the laboratory procedure, even when the biodiesel is produced from waste vegetable oils or animal fats with high free fatty acid content. The reaction conditions were set at: 1.5% w/w of TMAH, reaction temperature 65°C, the feedstock to methanol molar ratio to 1:6, and the reaction time to 120min. The conversion of triglycerides to FAME was approximately 98%. The cloud point of the biodiesel obtained from waste animal fat was also determined. Copyright © 2015 Elsevier Ltd. All rights reserved.

  10. Microbially Enhanced Oil Recovery by Sequential Injection of Light Hydrocarbon and Nitrate in Low- And High-Pressure Bioreactors.

    PubMed

    Gassara, Fatma; Suri, Navreet; Stanislav, Paul; Voordouw, Gerrit

    2015-10-20

    Microbially enhanced oil recovery (MEOR) often involves injection of aqueous molasses and nitrate to stimulate resident or introduced bacteria. Use of light oil components like toluene, as electron donor for nitrate-reducing bacteria (NRB), offers advantages but at 1-2 mM toluene is limiting in many heavy oils. Because addition of toluene to the oil increased reduction of nitrate by NRB, we propose an MEOR technology, in which water amended with light hydrocarbon below the solubility limit (5.6 mM for toluene) is injected to improve the nitrate reduction capacity of the oil along the water flow path, followed by injection of nitrate, other nutrients (e.g., phosphate) and a consortium of NRB, if necessary. Hydrocarbon- and nitrate-mediated MEOR was tested in low- and high-pressure, water-wet sandpack bioreactors with 0.5 pore volumes of residual oil in place (ROIP). Compared to control bioreactors, those with 11-12 mM of toluene in the oil (gained by direct addition or by aqueous injection) and 80 mM of nitrate in the aqueous phase produced 16.5 ± 4.4% of additional ROIP (N = 10). Because toluene is a cheap commodity chemical, HN-MEOR has the potential to be a cost-effective method for additional oil production even in the current low oil price environment.

  11. Visualization of nuclear particle trajectories in nuclear oil-well logging

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Case, C.R.; Chiaramonte, J.M.

    Nuclear oil-well logging measures specific properties of subsurface geological formations as a function of depth in the well. The knowledge gained is used to evaluate the hydrocarbon potential of the surrounding oil field. The measurements are made by lowering an instrument package into an oil well and slowly extracting it at a constant speed. During the extraction phase, neutrons or gamma rays are emitted from the tool, interact with the formation, and scatter back to the detectors located within the tool. Even though only a small percentage of the emitted particles ever reach the detectors, mathematical modeling has been verymore » successful in the accurate prediction of these detector responses. The two dominant methods used to model these devices have been the two-dimensional discrete ordinates method and the three-dimensional Monte Carlo method has routinely been used to investigate the response characteristics of nuclear tools. A special Los Alamos National Laboratory version of their standard MCNP Monte carlo code retains the details of each particle history of later viewing within SABRINA, a companion three-dimensional geometry modeling and debugging code.« less

  12. Marine crude-oil biodegradation: a central role for interspecies interactions

    PubMed Central

    2012-01-01

    The marine environment is highly susceptible to pollution by petroleum, and so it is important to understand how microorganisms degrade hydrocarbons, and thereby mitigate ecosystem damage. Our understanding about the ecology, physiology, biochemistry and genetics of oil-degrading bacteria and fungi has increased greatly in recent decades; however, individual populations of microbes do not function alone in nature. The diverse array of hydrocarbons present in crude oil requires resource partitioning by microbial populations, and microbial modification of oil components and the surrounding environment will lead to temporal succession. But even when just one type of hydrocarbon is present, a network of direct and indirect interactions within and between species is observed. In this review we consider competition for resources, but focus on some of the key cooperative interactions: consumption of metabolites, biosurfactant production, provision of oxygen and fixed nitrogen. The emphasis is largely on aerobic processes, and especially interactions between bacteria, fungi and microalgae. The self-construction of a functioning community is central to microbial success, and learning how such “microbial modules” interact will be pivotal to enhancing biotechnological processes, including the bioremediation of hydrocarbons. PMID:22591596

  13. Oil biodegradation: Interactions of artificial marine snow, clay particles, oil and Corexit.

    PubMed

    Rahsepar, Shokouh; Langenhoff, Alette A M; Smit, Martijn P J; van Eenennaam, Justine S; Murk, Albertinka J; Rijnaarts, Huub H M

    2017-12-15

    During the Deepwater Horizon (DwH) oil spill, interactions between oil, clay particles and marine snow lead to the formation of aggregates. Interactions between these components play an important, but yet not well understood, role in biodegradation of oil in the ocean water. The aim of this study is to explore the effect of these interactions on biodegradation of oil in the water. Laboratory experiments were performed, analyzing respiration and n-alkane and BTEX biodegradation in multiple conditions containing Corexit, alginate particles as marine snow, and kaolin clay. Two oil degrading bacterial pure cultures were added, Pseudomonas putida F1 and Rhodococcus qingshengii TUHH-12. Results show that the presence of alginate particles enhances oil biodegradation. The presence of Corexit alone or in combination with alginate particles and/or kaolin clay, hampers oil biodegradation. Kaolin clay and Corexit have a synergistic effect in increasing BTEX concentrations in the water and cause delay in oil biodegradation. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Biotransformation of natural gas and oil compounds associated with marine oil discharges.

    PubMed

    Brakstad, Odd Gunnar; Almås, Inger K; Krause, Daniel Franklin

    2017-09-01

    Field data from the Deepwater Horizon (DWH) oil spill in the Gulf of Mexico (GoM) suggested that oxidation of gas compounds stimulated biodegradation of oil compounds in the deep sea plume. We performed experiments with local seawater from a Norwegian fjord to examine if the presence of dissolved gas compounds (methane, ethane and propane) affected biodegradation of volatile oil compounds, and if oil compounds likewise affected gas compound oxidation. The results from the experiment showed comparable oil compound biotransformation rates in seawater at 5 °C between seawater with and without soluble gases. Gas oxidation was not affected by the presence of volatile oil compounds. Contrary to DWH deep sea plume data, propane oxidation was not faster than methane oxidation. These data may reflect variations between biodegradation of oil and gas in seawater environments with different history of oil and gas exposure. Copyright © 2017 Elsevier Ltd. All rights reserved.

  15. The effects of crude oil and remediation burning on three clones of smooth cordgrass (Spartina alterniflora Loisel.)

    USGS Publications Warehouse

    Smith, D.L.; Proffitt, C.E.

    1999-01-01

    Burning has been employed as an oil spill remediation technique in coastal marshes, even though the combined and interactive effects of soil and burning on vegetation are poorly understood. Variation among clones of perennial marsh grasses in response to these perturbations is not known. We performed a greenhouse experiment designed to assess the effects of Venezuelan crude oil alone and of oil followed by burning on three clonal genets of Spartina alterniflora. The fully-crossed 6-mo experiment involved five dosages of oil (0 l m-2, 4 l m-2, 8 l m-2, 16 l m-2, and 24 l m-2) and two burn treatments (burned or unburned) applied to ramets from three clones. All oil-only dosages reduced survival, but burning after oiling (oil + burn treatments) increased survival relative to oil-only groups in all except the highest two oil dosages. Higher oil-only treatments also reduced ramet densities and inhibited density increases over 6 mo. Burning after treatment with the 16 l m-2 oil concentration allowed increased production of new ramets, but burning exacerbated the negative impacts on ramet density at the oil concentration of 24 l m-2. At some intermediate oil dosages, burning remediated the negative effects of oil on aboveground biomass production and growth in height. There was a significant effect of oil-only treatments on numbers of flowering ramets produced, in which two clones responded with decreased flower production and one exhibited increased flowering. There was no main effect of oil + burn on flowering. There were significant among-clones differences in all response variables to one or both treatments. Our experiment demonstrates that burning of oiled S. alterniflora marshes may have little measurable effect at low levels of Venezuelan crude oil, can remediate the effects of oil at intermediate oil concentrations, but can increase the negative impacts at high concentrations of oil. These results indicate that oil spills have the potential to adversely affect

  16. Nevada Even Start Family Literacy Program = Programa de alfabetizacion familiar Even Start de Nevada.

    ERIC Educational Resources Information Center

    Nevada State Dept. of Education, Carson City.

    Two pamphlets (one in English and one in Spanish) describe the Nevada Even Start (NEST) program, a home-based system designed to help parents become full partners in the education of their children and to help children and parents reach their full potential as learners. The pamphlets note that the program intends to break the cycle of…

  17. The effect of coconut oil and palm oil as substituted oils to cocoa butter on chocolate bar texture and melting point

    NASA Astrophysics Data System (ADS)

    Limbardo, Rebecca Putri; Santoso, Herry; Witono, Judy Retti

    2017-05-01

    Cocoa butter has responsibility for dispersion medium to create a stable chocolate bar. Due to the economic reason, cocoa butter is partially or wholly substituted by edible oils e.g palm oil and coconut oil. The objective of the research was to observe the effect of oil substitution in the chocolate bar towards its melting point and texture. The research were divided in three steps which were preliminary research started with fat content analysis in cocoa powder, melting point analysis of substituted oils anc cocoa butter, and iodine number analysis in vegetable fats (cocoa butter, coconut oil, and palm oil), chocolate bar production with substitution 0%, 20%, 40%, 60%, 80%, and 100%wt of cocoa butter with each of substituted oils, and analysis process to determine the chocolate bar melting point with DSC and chocolate bar hardness with texture analyser. The increasement of substituted oils during substitution in chocolate bar would reduce the melting point of chocolate bar from 33.5°C to 31.6°C in palm oil substitution with cocoa butter and 33.5°C to 30.75°C in coconut oil substitution. The hardness of chocolate with palm oil were around 88.5 to 139 g on the 1st cycle and 22.75 to 132 g on the 2nd cycle. The hardness of chocolate with coconut oil were around 74.75 to 152.5 g on the 1st cycle and 53.25 to 132 g on the 2nd cycle. Maximum amount of fats substitution to produce a stable texture chocolate bar is 60% wt.

  18. Incipient Motion of Sand and Oil Agglomerates

    NASA Astrophysics Data System (ADS)

    Nelson, T. R.; Dalyander, S.; Jenkins, R. L., III; Penko, A.; Long, J.; Frank, D. P.; Braithwaite, E. F., III; Calantoni, J.

    2016-12-01

    Weathered oil mixed with sediment in the surf zone in the northern Gulf of Mexico after the 2010 Deepwater Horizon oil spill, forming large mats of sand and oil. Wave action fragmented the mats into sand and oil agglomerates (SOAs) with diameters of about 1 to 10 cm. These SOAs were transported by waves and currents along the Gulf Coast, and have been observed on beaches for years following the spill. SOAs are composed of 70%-95% sand by mass, with an approximate density of 2107 kg/m³. To measure the incipient motion of SOAs, experiments using artificial SOAs were conducted in the Small-Oscillatory Flow Tunnel at the U.S. Naval Research Laboratory under a range of hydrodynamic forcing. Spherical and ellipsoidal SOAs ranging in size from 0.5 to 10 cm were deployed on a fixed flat bed, a fixed rippled bed, and a movable sand bed. In the case of the movable sand bed, SOAs were placed both proud and partially buried. Motion was tracked with high-definition video and with inertial measurement units embedded in some of the SOAs. Shear stress and horizontal pressure gradients, estimated from velocity measurements made with a Nortek Vectrino Profiler, were compared with observed mobility to assess formulations for incipient motion. For SOAs smaller than 1 cm in diameter, incipient motion of spherical and ellipsoidal SOAs was consistent with predicted critical stress values. The measured shear stress at incipient motion of larger, spherical SOAs was lower than predicted, indicating an increased dependence on the horizontal pressure gradient. In contrast, the measured shear stress required to move ellipsoidal SOAs was higher than predicted, even compared to values modified for larger particles in mixed-grain riverine environments. The laboratory observations will be used to improve the prediction of incipient motion, transport, and seafloor interaction of SOAs.

  19. Foam-oil interaction in porous media: implications for foam assisted enhanced oil recovery.

    PubMed

    Farajzadeh, R; Andrianov, A; Krastev, R; Hirasaki, G J; Rossen, W R

    2012-11-15

    The efficiency of a foam displacement process in enhanced oil recovery (EOR) depends largely on the stability of foam films in the presence of oil. Experimental studies have demonstrated the detrimental impact of oil on foam stability. This paper reviews the mechanisms and theories (disjoining pressure, coalescence and drainage, entering and spreading of oil, oil emulsification, pinch-off, etc.) suggested in the literature to explain the impact of oil on foam stability in the bulk and porous media. Moreover, we describe the existing approaches to foam modeling in porous media and the ways these models describe the oil effect on foam propagation in porous media. Further, we present various ideas on an improvement of foam stability and longevity in the presence of oil. The outstanding questions regarding foam-oil interactions and modeling of these interactions are pointed out. Copyright © 2012 Elsevier B.V. All rights reserved.

  20. Repellency of essential oil of Piper aduncum against Aedes albopictus in the laboratory.

    PubMed

    Misni, Norashiqin; Sulaiman, Sallehudin; Othman, Hidayatulfathi; Omar, Baharudin

    2009-12-01

    The repellent activity of Piper aduncum essential oil against Aedes albopictus was investigated under laboratory conditions with human volunteers. The lowest median effective dose (ED50) value was 1.5 microg/cm2 at 60 sec of exposure when compared to 90 sec (2.1 microg/cm2) and 120 sec (1.8 microg/cm2) of exposure. At 0.4 g, the essential oil gave a high protection (95.2%) against Ae. albopictus bites or landing at 2 h postapplication. The percentage of protection was reduced to 83.3% after 4 h, 64.5% after 6 h, and 51.6% after 8 h postapplication. As a comparison, treatment with 10% deet gave 100% protection against mosquito biting/landing for 4 h postapplication. There was no significant difference in percentage protection reduction between the plant extract and the commercial product deet, respectively (P = 0.739). The essential oil, which was not as good as deet, still gave moderate protection against Ae. albopictus biting even until 4 h postapplication. In conclusion, the P. aduncum essential oil has the potential to be used as a repellent against the dengue/dengue hemorrhagic fever vector, Ae. albopictus.

  1. Oil biodegradation. Water droplets in oil are microhabitats for microbial life.

    PubMed

    Meckenstock, Rainer U; von Netzer, Frederick; Stumpp, Christine; Lueders, Tillmann; Himmelberg, Anne M; Hertkorn, Norbert; Schmitt-Kopplin, Philipp; Harir, Mourad; Hosein, Riad; Haque, Shirin; Schulze-Makuch, Dirk

    2014-08-08

    Anaerobic microbial degradation of hydrocarbons, typically occurring at the oil-water transition zone, influences the quality of oil reservoirs. In Pitch Lake, Trinidad and Tobago--the world's largest asphalt lake--we found that microorganisms are metabolically active in minuscule water droplets (1 to 3 microliters) entrapped in oil. Pyrotag sequencing of individual droplet microbiomes revealed complex methanogenic microbial communities actively degrading the oil into a diverse range of metabolites, as shown by nuclear magnetic resonance and Fourier transform ion cyclotron resonance mass spectrometry. High salinity and water-stable isotopes of the droplets indicate a deep subsurface origin. The 13.5% water content and the large surface area of the droplets represent an underestimated potential for biodegradation of oil away from the oil-water transition zone. Copyright © 2014, American Association for the Advancement of Science.

  2. An Oil/Water disperser device for use in an oil content Monitor/Control system

    NASA Astrophysics Data System (ADS)

    Kempel, F. D.

    1985-07-01

    This patent application discloses an oil content monitor/control unit system, including an oil/water disperser device, which is configured to automatically monitor and control processed effluent from an associated oil/water separator so that if the processed effluent exceeds predetermine in-port or at-sea oil concentration lmits, it is either recirculated to an associated oil/water separator via a ship's bilge for additional processing, or diverted to a holding tank for storage. On the other hand, if the oil concentration of the processed effluent is less than predetermine in-port or at-sea limits, it is discharged overboard. The oil/water disperser device is configured to break up any oil present in the processed effluent into uniform droplets for more accurate sensing of the oil present in the processed effluent into uniform droplets for more accurate sensing of the oil-in-water concentration level thereof. The oil/water disperser device has a flow-actuated variable orifice configured into a spring-loaded polyethylene plunger which provides the uniform distribution of oil droplets.

  3. The battle against multi-resistant strains: Renaissance of antimicrobial essential oils as a promising force to fight hospital-acquired infections.

    PubMed

    Warnke, Patrick H; Becker, Stephan T; Podschun, Rainer; Sivananthan, Sureshan; Springer, Ingo N; Russo, Paul A J; Wiltfang, Joerg; Fickenscher, Helmut; Sherry, Eugene

    2009-10-01

    Hospital-acquired infections and antibiotic-resistant bacteria continue to be major health concerns worldwide. Particularly problematic is methicillin-resistant Staphylococcus aureus (MRSA) and its ability to cause severe soft tissue, bone or implant infections. First used by the Australian Aborigines, Tea tree oil and Eucalyptus oil (and several other essential oils) have each demonstrated promising efficacy against several bacteria and have been used clinically against multi-resistant strains. Several common and hospital-acquired bacterial and yeast isolates (6 Staphylococcus strains including MRSA, 4 Streptococcus strains and 3 Candida strains including Candida krusei) were tested for their susceptibility for Eucalyptus, Tea tree, Thyme white, Lavender, Lemon, Lemongrass, Cinnamon, Grapefruit, Clove Bud, Sandalwood, Peppermint, Kunzea and Sage oil with the agar diffusion test. Olive oil, Paraffin oil, Ethanol (70%), Povidone iodine, Chlorhexidine and hydrogen peroxide (H(2)O(2)) served as controls. Large prevailing effective zones of inhibition were observed for Thyme white, Lemon, Lemongrass and Cinnamon oil. The other oils also showed considerable efficacy. Remarkably, almost all tested oils demonstrated efficacy against hospital-acquired isolates and reference strains, whereas Olive and Paraffin oil from the control group produced no inhibition. As proven in vitro, essential oils represent a cheap and effective antiseptic topical treatment option even for antibiotic-resistant strains as MRSA and antimycotic-resistant Candida species.

  4. Marine Oil Biodegradation.

    PubMed

    Hazen, Terry C; Prince, Roger C; Mahmoudi, Nagissa

    2016-03-01

    Crude oil has been part of the marine environment for millions of years, and microbes that use its rich source of energy and carbon are found in seawater, sediments, and shorelines from the tropics to the polar regions. Catastrophic oil spills stimulate these organisms to "bloom" in a reproducible fashion, and although oil does not provide bioavailable nitrogen, phosphorus or iron, there are enough of these nutrients in the sea that when dispersed oil droplets dilute to low concentrations these low levels are adequate for microbial growth. Most of the hydrocarbons in dispersed oil are degraded in aerobic marine waters with a half-life of days to months. In contrast, oil that reaches shorelines is likely to be too concentrated, have lower levels of nutrients, and have a far longer residence time in the environment. Oil that becomes entrained in anaerobic sediments is also likely to have a long residence time, although it too will eventually be biodegraded. Thus, data that encompass everything from the ecosystem to the molecular level are needed for understanding the complicated process of petroleum biodegradation in marine environments.

  5. Multiwall carbon nanotubes increase the microbial community in crude oil contaminated fresh water sediments.

    PubMed

    Abbasian, Firouz; Lockington, Robin; Palanisami, Thavamani; Megharaj, Mallavarapu; Naidu, Ravi

    2016-01-01

    Since crude oil contamination is one of the biggest environmental concerns, its removal from contaminated sites is of interest for both researchers and industries. In situ bioremediation is a promising technique for decreasing or even eliminating crude oil and hydrocarbon contamination. However, since these compounds are potentially toxic for many microorganisms, high loads of contamination can inhibit the microbial community and therefore reduce the removal rate. Therefore, any strategy with the ability to increase the microbial population in such circumstances can be of promise in improving the remediation process. In this study, multiwall carbon nanotubes were employed to support microbial growth in sediments contaminated with crude oil. Following spiking of fresh water sediments with different concentrations of crude oil alone and in a mixture with carbon nanotubes for 30days, the microbial profiles in these sediments were obtained using FLX-pyrosequencing. Next, the ratios of each member of the microbial population in these sediments were compared with those values in the untreated control sediment. This study showed that combination of crude oil and carbon nanotubes can increase the diversity of the total microbial population. Furthermore, these treatments could increase the ratios of several microorganisms that are known to be effective in the degradation of hydrocarbons. Copyright © 2015 Elsevier B.V. All rights reserved.

  6. The effects of intermolecular interactions on the physical properties of organogels in edible oils.

    PubMed

    Lupi, Francesca R; Greco, Valeria; Baldino, Noemi; de Cindio, Bruno; Fischer, Peter; Gabriele, Domenico

    2016-12-01

    The microstructure of organogels based on monoglycerides of fatty acids (MAGs) and policosanol and on different edible oils was investigated by using different techniques (calorimetry, nuclear magnetic resonance, infrared spectroscopy, rheology, polarized light microscopy) towards a better understanding and control of the oil gelation phenomena. Dynamic moduli were related via a fractal model to microstructural information such as solid content and fractal dimension. Infrared spectroscopy evidenced that network structure in MAGs gel is mainly due to hydrogen bonding, whereas in policosanol system is mainly given by van der Waals interactions. Because of the different relative contribution of molecular interactions, the investigated organogelators exhibit a distinguished macroscopic behavior. MAGs are sensitive to the utilized oil and structuration occurs quickly, even though at a temperature lower than policosanol. Policosanol organogels exhibit a behavior independent of the used oil and a slower gelation rate, as a result of the weaker van der Waals interactions. Nevertheless, at lower concentration a stronger final gel is obtained, probably due to of the large number of interactions arising among the long alkyl chains of the fatty alcohols. Obtained results evidenced that policosanol is very effective in gelation of different oils and seems promising for potential commercial uses. Copyright © 2016 Elsevier Inc. All rights reserved.

  7. pH-induced motion control of self-propelled oil droplets using a hydrolyzable gemini cationic surfactant.

    PubMed

    Miura, Shingo; Banno, Taisuke; Tonooka, Taishi; Osaki, Toshihisa; Takeuchi, Shoji; Toyota, Taro

    2014-07-15

    Self-propelled motion of micrometer-sized substances has drawn much attention as an autonomous transportation system. One candidate vehicle is a chemically driven micrometer-sized oil droplet. However, to the best of our knowledge, there has been no report of a chemical reaction system controlling the three-dimensional motion of oil droplets underwater. In this study, we developed a molecular system that controlled the self-propelled motion of 4-heptyloxybenzaldehyde oil droplets by using novel gemini cationic surfactants containing carbonate linkages (2G12C). We found that, in emulsions containing sodium hydroxide, the motion time of the self-propelled oil droplets was longer in the presence of 2G12C than in the presence of gemini cationic surfactants without carbonate linkages. Moreover, in 2G12C solution, oil droplets at rest underwent unidirectional, self-propelled motion in a gradient field toward a higher concentration of sodium hydroxide. Even though they stopped within several seconds, they restarted in the same direction. 2G12C was gradually hydrolyzed under basic conditions to produce a pair of the corresponding monomeric surfactants, which exhibit different interfacial properties from 2G12C. The prolonged and restart motion of the oil droplets were explained by the increase in the heterogeneity of the interfacial tension of the oil droplets.

  8. A comparative analysis of alpha-decay half-lives for even-even 178Pb to 234U isotopes

    NASA Astrophysics Data System (ADS)

    Hosseini, S. S.; Hassanabadi, H.; Zarrinkamar, S.

    2018-02-01

    The feasibility for the alpha decay from the even-even transitions of 178Pb to 234U isotopes has been studied within the Coulomb and proximity potential model (CPPM). The alpha decay half-lives are considered from different theoretical approaches using Semi-empirical formula of Poenaru et al. (SemFIS), the Universal Decay law (UDL) of Qi et al., Akrawy-Dorin formula of Akrawy and Poenaru (ADF), the Scaling law of Brown (SLB) and the Scaling Law of Horoi et al. (SLH). The numerical results obtained by the CPPM and compared with other method as well the experimental data.

  9. 27. DIABLO POWERHOUSE UPPER OIL ROOM: OBSOLETE WESTINGHOUSE DIELECTRIC OIL ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    27. DIABLO POWERHOUSE UPPER OIL ROOM: OBSOLETE WESTINGHOUSE DIELECTRIC OIL TESTING SET. OIL IS USED AS AN INSULATOR IN TRANSFORMERS AND ITS CONDUCTIVITY USED TO BE TESTED USING EQUIPMENT SUCH AS THIS, 1989. - Skagit Power Development, Diablo Powerhouse, On Skagit River, 6.1 miles upstream from Newhalem, Newhalem, Whatcom County, WA

  10. Comparative toxicity of oil, dispersant, and oil plus dispersant to several marine species.

    PubMed

    Fuller, Chris; Bonner, James; Page, Cheryl; Ernest, Andrew; McDonald, Thomas; McDonald, Susanne

    2004-12-01

    Dispersants are a preapproved chemical response agent for oil spills off portions of the U.S. coastline, including the Texas-Louisiana coast. However, questions persist regarding potential environmental risks of dispersant applications in nearshore regions (within three nautical miles of the shoreline) that support dense populations of marine organisms and are prone to spills resulting from human activities. To address these questions, a study was conducted to evaluate the relative toxicity of test media prepared with dispersant, weathered crude oil, and weathered crude oil plus dispersant. Two fish species, Cyprinodon variegatus and Menidia beryllina, and one shrimp species, Americamysis bahia (formerly Mysidopsis bahia), were used to evaluate the relative toxicity of the different media under declining and continuous exposure regimes. Microbial toxicity was evaluated using the luminescent bacteria Vibrio fisheri. The data suggested that oil media prepared with a chemical dispersant was equal to or less toxic than the oil-only test medium. Data also indicated that continuous exposures to the test media were generally more toxic than declining exposures. The toxicity of unweathered crude oil with and without dispersant was also evaluated using Menidia beryllina under declining exposure conditions. Unweathered oil-only media were dominated by soluble hydrocarbon fractions and found to be more toxic than weathered oil-only media in which colloidal oil fractions dominated. Total concentrations of petroleum hydrocarbons in oil-plus-dispersant media prepared with weathered and unweathered crude oil were both dominated by colloidal oil and showed no significant difference in toxicity. Analysis of the toxicity data suggests that the observed toxicity was a function of the soluble crude oil components and not the colloidal oil.

  11. The macrofaunal communities in the shallow subtidal areas for the first 3 years after the Hebei Spirit oil spill.

    PubMed

    Seo, Jin-Young; Kim, Moonkoo; Lim, Hyun-Sig; Choi, Jin-Woo

    2014-05-15

    In order to detect the early impact of the Hebei Spirit oil spill on the shallow subtidal macrozoobenthic communities, macrobenthic fauna were collected seasonally for 3 years. The alkylated PAHs concentrations within sediments near Mallipo beach remained as high as 129 ng g(-)(1) DW one month after the oil spill, but the concentration decreased below the background level thereafter. The number of species and density decreased in 4 months compared to those before the oil spill. An opportunistic polychaete, Prionospio paradisea, occurred as a dominant species at subtidal area near Mallipo beach in 10 months after the oil spill. Any mass mortality of amphipods and any clear dominance of opportunistic species were not detected except for the stations near Mallipo and Hagampo beaches. The macrobenthic communities at the shallow subtidal stations seemed to have a relatively stable faunal composition, even not fully recovered, in 3 years after the Hebei Spirit oil spill. Copyright © 2014 Elsevier Ltd. All rights reserved.

  12. Development of new antioxidant systems for frying oil and omega-3 oils

    USDA-ARS?s Scientific Manuscript database

    The development of natural antioxidant systems for frying oil will be discussed in this presentation. This study aimed to utilize vegetable oils such as soybean oil for frying, of which the United States is the world’s largest producer. To overcome the vulnerability of soybean oil to oxidation due t...

  13. Transesterification process to manufacture ethyl ester of rape oil

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Korus, R.A.; Hoffman, D.S.; Bam, N.

    1993-12-31

    A process for the production of the ethyl ester of winter rape [EEWR] for use as a biodiesel fuel has been studied. The essential part of the process is the transesterification of rape oil with ethanol, in the presence of a catalyst, to yield the ethyl ester of rape oil as a product and glycerin as a by-product. Experiments have been performed to determine the optimum conditions for the preparation of EEWR. The process variables were: (1) temperature, (2) catalyst, (3) rate of agitation, (4) water content of the alcohol used, and (5) the amount of excess alcohol used. Themore » optimum conditions were: (1) room temperature, (2) 0.5% sodium methoxide or 1% potassium hydroxide catalyst by weight of rapeseed oil, (3) extremely vigorous agitation with some splashing during the initial phase of the reaction and agitation was not necessary after the reaction mixture became homogeneous, (4) absolute ethanol was necessary for high conversion, and (5) 50% excess ethanol with NaOCH{sub 3} or 100% excess with KOH gave a maximum conversion. Viscosity, cloud point and pour point of the EEWR were measured. A preliminary break-even cost for the commercial production of EEWR was found to be $0.55/liter [$2.08/US gallon].« less

  14. Vegetation recovery in an oil-impacted and burned Phragmites australis tidal freshwater marsh.

    PubMed

    Zengel, Scott; Weaver, Jennifer; Wilder, Susan L; Dauzat, Jeff; Sanfilippo, Chris; Miles, Martin S; Jellison, Kyle; Doelling, Paige; Davis, Adam; Fortier, Barret K; Harris, James; Panaccione, James; Wall, Steven; Nixon, Zachary

    2018-01-15

    In-situ burning of oiled marshes is a cleanup method that can be more effective and less damaging than intrusive manual and mechanical methods. In-situ burning of oil spills has been examined for several coastal marsh types; however, few published data are available for Phragmites australis marshes. Following an estimated 4200gallon crude oil spill and in-situ burn in a Phragmites tidal freshwater marsh at Delta National Wildlife Refuge (Mississippi River Delta, Louisiana), we examined vegetation impacts and recovery across 3years. Oil concentrations in marsh soils were initially elevated in the oiled-and-burned sites, but were below background levels within three months. Oiling and burning drastically affected the marsh vegetation; the formerly dominant Phragmites, a non-native variety in our study sites, had not fully recovered by the end of our study. However, overall vegetation recovery was rapid and local habitat quality in terms of native plants, particularly Sagittaria species, and wildlife value was enhanced by burning. In-situ burning appears to be a viable response option to consider for future spills in marshes with similar plant species composition, hydrogeomorphic settings, and oiling conditions. In addition, likely Phragmites stress from high water levels and/or non-native scale insect damage was also observed during our study and has recently been reported as causing widespread declines or loss of Phragmites stands in the Delta region. It remains an open question if these stressors could lead to a shift to more native vegetation, similar to what we observed following the oil spill and burn. Increased dominance by native plants may be desirable as local patches, but widespread loss of Phragmites, even if replaced by native species, could further acerbate coastal erosion and wetland loss, a major concern in the region. Copyright © 2017 Elsevier B.V. All rights reserved.

  15. Exploring Oil Pollution

    ERIC Educational Resources Information Center

    Rillo, Thomas J.

    1974-01-01

    Discusses damages of oil tanker spillage to the marine organisms and scientists' research in oil pollution removal techniques. Included is a list of learning activities concerning the causes and effects of oil pollution and methods of solving the problem. (CC)

  16. Deep Desulfurization of Extensively Hydrodesulfurized Middle Distillate Oil by Rhodococcus sp. Strain ECRD-1

    PubMed Central

    Grossman, M. J.; Lee, M. K.; Prince, R. C.; Minak-Bernero, V.; George, G. N.; Pickering, I. J.

    2001-01-01

    Dibenzothiophene (DBT), and in particular substituted DBTs, are resistant to hydrodesulfurization (HDS) and can persist in fuels even after aggressive HDS treatment. Treatment by Rhodococcus sp. strain ECRD-1 of a middle distillate oil whose sulfur content was virtually all substituted DBTs produced extensive desulfurization and a sulfur level of 56 ppm. PMID:11282654

  17. Contact Allergy to Neem Oil.

    PubMed

    de Groot, Anton; Jagtman, Berend A; Woutersen, Marjolijn

    A case of allergic contact dermatitis from neem oil is presented. Neem oil (synonyms: Melia azadirachta seed oil [INCI name], nim oil, margosa oil) is a vegetable (fixed) oil obtained from the seed of the neem tree Azadirachta indica by cold pressing. Contact allergy to neem oil has been described previously in only 3 patients. The allergen(s) is/are unknown.

  18. Sedimentation Of Oil-MIneral Aggregates For Remediation Of Vegetable Oil Spills

    EPA Science Inventory

    A response alternative for floating vegetable oil spills based on sedimentation of negatively buoyant oil-mineral aggregrates followed by anaerobic biodegradation in the sediments is under investigation. Sedimentation of floating canola oil by interaction with montmorillonite wa...

  19. Hepatic Regeneration and Reno-Protection by Fish oil, Nigella sativa Oil and Combined Fish Oil/Nigella sativa Volatiles in CCl4 Treated Rats.

    PubMed

    Al-Okbi, Sahar Y; Mohamed, Doha A; Hamed, Thanaa E; Edris, Amr E; Fouda, Karem

    2018-03-01

    The aim of the present research was to investigate the effect of fish oil, crude Nigella sative oil and combined fish oil/Nigella sative volatile oil as hepato-regenerative and renal protective supplements. The oils were administered as emulsions to rat model with liver injury induced by CCl 4 . Plasma activities of transaminases (AST and ALT) were evaluated as liver function indicators, while plasma creatinine and urea and creatinine clearance were determined as markers of kidney function. Plasma malondialdehyde (MDA), nitrite (NO) and tumor necrosis factor-α (TNF-α) were estimated to assess the exposure to oxidative stress and subsequent inflammation. Liver fat was extracted and their fatty acids´ methyl esters were determined using gas chromatography. Results showed that plasma activities of AST and ALT were significantly higher in CCl 4 control group compared to control healthy group. Plasma levels of creatinine and urea increased significantly in CCl 4 control, while creatinine clearance was reduced significantly in the same group. All rat treated groups given the three oil emulsions showed improvement in liver function pointing to the initiation of liver regeneration. The combination of fish oil/Nigella sative volatiles showed the most promising regenerative activity. Oxidative stress and inflammation which were increased significantly in CCl 4 control group showed improvement on administration of the three different oil emulsions. Fatty acids methyl ester of liver fat revealed that rats treated with fish oil/Nigella sative volatile oil presented the highest content of unsaturated fatty acids (45.52% ± 0.81) while fish oil showed the highest saturated fatty acids (53.28% ± 1.68). Conclusion; Oral administration of oil emulsions of native fish oil, Nigella sative crude oil and combined fish oil/Nigella sative volatile oil reduced liver and kidney injury in rat model of CCl 4 through exerting anti-inflammatory and antioxidant activity. Fish oil

  20. Essential Oils as Components of a Diet-Based Approach to Management of Helicobacter Infection

    PubMed Central

    Bergonzelli, G. E.; Donnicola, D.; Porta, N.; Corthésy-Theulaz, I. E.

    2003-01-01

    An increased density of Helicobacter pylori in the gastric mucosa can be associated with more severe gastritis and an increased incidence of peptic ulcers. Therefore, people with asymptomatic gastritis would certainly benefit from a nutritional approach to help them manage the infection and therefore decrease the risk of development of associated pathologies. We analyzed the activities of 60 essential oils against H. pylori P1 and identified 30 oils that affected growth, with in vitro inhibition zones ranging between 0.7 and 6.3 cm in diameter. We further analyzed the effects of 16 oils with different activities on H. pylori P1 viability. Fifteen showed strong bactericidal activities, with minimal bactericidal concentrations after 24 h ranging from 0.02 to 0.1 g/liter at pH 7.4. Even though slight variations in activities were observed, the essential oils that displayed the strongest bactericidal potentials against H. pylori P1 were also active against other Helicobacter strains tested. Among the pure constituents of different essential oils tested, carvacrol, isoeugenol, nerol, citral, and sabinene exhibited the strongest anti-H. pylori activities. Although oral treatment of H. pylori SS1-infected mice with carrot seed oil did not result in significant decreases in the bacterial loads in the treated animals compared to those in the control animals, in all experiments performed, the infection was cleared in 20 to 30% of carrot seed oil-treated animals. Our results indicate that essential oils are unlikely to be efficient anti-Helicobacter agents in vivo. However, their effects may not be irrelevant if one plans to use them as food additives to complement present therapies. PMID:14506036

  1. From creekology to geology: Finding and conserving oil on the Southern Plains, 1859--1930

    NASA Astrophysics Data System (ADS)

    Frehner, Brian

    This dissertation tells the story of the oil industry's westward migration from Pennsylvania to the Southern Plains states of Kansas, Oklahoma, and Texas and how different environments in these regions influenced prospectors' methods for finding oil. Petroleum engineers, geologists, and businessmen take center stage throughout the narrative, and I emphasize how their biases, values, and interests influenced the kind of knowledge produced. At the heart of this story lay a contest between professional, university-trained engineers and geologists and so-called practical oil men, or "wildcatters," who received their training less formally from surveying the landscape. Although both groups performed field work in their search for oil, I explore how each learned very different information from that activity. Wildcatters met with so much success that the oil industry failed to take geologists seriously for approximately fifty years after 1860 when the Pennsylvania oil boom started, and I argue that the environment played an important role in this contest for authority between oil prospectors who learned their trade through hands-on experience and those who learned it primarily in the classroom. I continue this theme by showing how the environment actively influenced the growing acceptance of geologists as the oil industry migrated west and companies with interests in Kansas, Oklahoma, and Texas began hiring geologists and establishing their own geological research departments. A pioneer in the use of geology, Henry L. Doherty, controlled Cities Service holding company and dispatched an army of geologists who discovered significant oil strikes in these states. Doherty's embrace of university-trained experts led him to advocate conservation of oil on the basis of geological and engineering principles. Practical men in Oklahoma, however, recognized the need for conservation even earlier and succeeded in lobbying their state legislature for laws which proved effective long

  2. Effect of citronella essential oil fractions as oil phase on emulsion stability

    NASA Astrophysics Data System (ADS)

    Septiyanti, Melati; Meliana, Yenny; Agustian, Egi

    2017-11-01

    The emulsion system consists of water, oil and surfactant. In order to create stable emulsion system, the composition and formulation between water phase, surfactant and oil phase are very important. Essential oil such as citronella oil has been known as active ingredient which has ability as insect repellent. This research studied the effect of citronella oil and its fraction as oil phase on emulsion stability. The cycle stability test was conducted to check the emulsion stability and it was monitored by pH, density, viscosity, particle size, refractive index, zeta potential, physical appearance and FTIR for 4 weeks. Citronellal fraction has better stability compared to citronella oil and rhodinol fraction with slight change of physical and chemical properties before and after the cycle stability test. However, it is need further study to enhance the stability of the emulsion stability for this formulation.

  3. The Prestige oil spill: a laboratory study about the toxicity of the water-soluble fraction of the fuel oil.

    PubMed

    Navas, José M; Babín, Mar; Casado, Susana; Fernández, Carlos; Tarazona, José V

    2006-07-01

    The Prestige oil spill caused severe effects on the coastal fauna and flora due to direct contact of organisms with the fuel oil. However, the water soluble fraction (WSF) of the fuel oil can also provoke deleterious effects in the long term and even in regions not directly affected by the spill. Our objective was to determine the toxicity of the WSF using a battery of laboratory toxicity tests. To obtain a WSF in the laboratory, a sample of the spilled fuel was mixed with adequate medium, sonicated, agitated and filtered. No cytotoxic effects were detected in RTG-2 cells exposed to the WSF. In an algae growth inhibition test (OECD test guideline 201) the WSF did not affect the growth of Chlorella vulgaris. Furthermore, acute and reproductive toxicity tests (OECD test guideline 202) carried out using Daphnia magna did not indicate any deleterious effect of the WSF. In a bioassay designed in our laboratory, D. magna were fed with algae previously exposed to the fuel, but no toxic effects were detected. However, the WSF was able to induce a dose-dependent increase of ethoxyresorufin-O-deethylase activity in RTG-2 cells, indicating the presence of chemicals that could cause sub-lethal effects to organisms. After chemical analyses it was established that the final total quantity of polyaromatic hydrocarbons dissolved in medium was approximately 70 ng/ml. These low concentrations explain the observed lack of toxicity.

  4. Application of synthetic fire-resistant oils in oil systems of turbine equipment for NPPs

    NASA Astrophysics Data System (ADS)

    Galimova, L. A.

    2017-10-01

    Results of the investigation of the synthetic fire-resistant turbine oil Fyrquel-L state in oil systems of turbosets under their operation in the equipment and oil supply facilities of nuclear power plants (NPPs) are presented. On the basis of the analysis of the operating experience, it is established that, for reliable and safe operation of the turbine equipment, at which oil systems synthetic fire-resistant oils on the phosphoric acid esters basis are used, special attention should be paid to two main factors, namely, both the guarantee of the normalized oil water content under the operation and storage and temperature regime of the operation. Methods of the acid number maintenance and reduction are shown. Results of the analysis and investigation of influence of temperature and of the variation of the qualitative state of the synthetic fair-resistant oil on its water content are reported. It is shown that the fire-resistant turbine oils are characterized by high hydrophilicity, and, in distinction to the mineral turbine oils, are capable to contain a significant amount of dissolved water, which is not extracted under the use of separation technologies. It is shown that the more degradation products are contained in oil and higher acid number, the more amount of dissolved water it is capable to retain. It is demonstrated that the organization of chemical control of the total water content of fireresistant oils with the use of the coulometric method is an important element to support the reliable operation of oil systems. It is recommended to use automatic controls of water content for organization of daily monitoring of oil state in the oil system. Recommendations and measures for improvement of oil operation on the NPP, the water content control, the use of oil cleaning plants, and the oil transfer for storage during repair works are developed.

  5. Silurian shale origin for light oil, condensate, and gas in Algeria and the Middle East

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zumberge, J.E.; Macko, S.

    1996-01-01

    Two of the largest gas fields in the world, Hasi R'Mel, Algeria and North Dome, Qatar, also contain substantial condensate and light oil reserves. Gas to source rock geochemical correlation is difficult due to the paucity of molecular parameters in the former although stable isotope composition is invaluable. However, by correlating source rocks with light oils and condensates associated with gas production using traditional geochemical parameters such as biomarkers and isotopes, a better understanding of the origin of the gas is achieved. Much of the crude oil in the Ghadames/Illizi Basins of Algeria has long been thought to have beenmore » generated from Silurian shales. New light oil discoveries in Saudi Arabia have also been shown to originate in basal euxinic Silurian shales. Key sterane and terpane biomarkers as well as the stable carbon isotopic compositions of the C15+ saturate and aromatic hydrocarbon fractions allow for the typing of Silurian-sourced, thermally mature light oils in Algeria and the Middle East. Even though biomarkers are often absent due to advanced thermal maturity, condensates can be correlated to the light oils using (1) carbon isotopes of the residual heavy hydrocarbon fractions, (2) light hydrocarbon distributions (e.g., C7 composition), and (3) compound specific carbon isotopic composition of the light hydrocarbons. The carbon isotopes of the C2-C4 gas components ran then be compared to the associated condensate and light oil isotopic composition.« less

  6. Silurian shale origin for light oil, condensate, and gas in Algeria and the Middle East

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zumberge, J.E.; Macko, S.

    Two of the largest gas fields in the world, Hasi R`Mel, Algeria and North Dome, Qatar, also contain substantial condensate and light oil reserves. Gas to source rock geochemical correlation is difficult due to the paucity of molecular parameters in the former although stable isotope composition is invaluable. However, by correlating source rocks with light oils and condensates associated with gas production using traditional geochemical parameters such as biomarkers and isotopes, a better understanding of the origin of the gas is achieved. Much of the crude oil in the Ghadames/Illizi Basins of Algeria has long been thought to have beenmore » generated from Silurian shales. New light oil discoveries in Saudi Arabia have also been shown to originate in basal euxinic Silurian shales. Key sterane and terpane biomarkers as well as the stable carbon isotopic compositions of the C15+ saturate and aromatic hydrocarbon fractions allow for the typing of Silurian-sourced, thermally mature light oils in Algeria and the Middle East. Even though biomarkers are often absent due to advanced thermal maturity, condensates can be correlated to the light oils using (1) carbon isotopes of the residual heavy hydrocarbon fractions, (2) light hydrocarbon distributions (e.g., C7 composition), and (3) compound specific carbon isotopic composition of the light hydrocarbons. The carbon isotopes of the C2-C4 gas components ran then be compared to the associated condensate and light oil isotopic composition.« less

  7. 21 CFR 102.37 - Mixtures of edible fat or oil and olive oil.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 21 Food and Drugs 2 2014-04-01 2014-04-01 false Mixtures of edible fat or oil and olive oil. 102... for Specific Nonstandardized Foods § 102.37 Mixtures of edible fat or oil and olive oil. The common or usual name of a mixture of edible fats and oils containing less than 100 percent and more than 0 percent...

  8. 21 CFR 102.37 - Mixtures of edible fat or oil and olive oil.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 21 Food and Drugs 2 2013-04-01 2013-04-01 false Mixtures of edible fat or oil and olive oil. 102... for Specific Nonstandardized Foods § 102.37 Mixtures of edible fat or oil and olive oil. The common or usual name of a mixture of edible fats and oils containing less than 100 percent and more than 0 percent...

  9. 21 CFR 102.37 - Mixtures of edible fat or oil and olive oil.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 21 Food and Drugs 2 2012-04-01 2012-04-01 false Mixtures of edible fat or oil and olive oil. 102... for Specific Nonstandardized Foods § 102.37 Mixtures of edible fat or oil and olive oil. The common or usual name of a mixture of edible fats and oils containing less than 100 percent and more than 0 percent...

  10. 21 CFR 102.37 - Mixtures of edible fat or oil and olive oil.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 21 Food and Drugs 2 2010-04-01 2010-04-01 false Mixtures of edible fat or oil and olive oil. 102... for Specific Nonstandardized Foods § 102.37 Mixtures of edible fat or oil and olive oil. The common or... olive oil shall be as follows: (a) A descriptive name for the product meeting the requirements of § 102...

  11. 21 CFR 102.37 - Mixtures of edible fat or oil and olive oil.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 21 Food and Drugs 2 2011-04-01 2011-04-01 false Mixtures of edible fat or oil and olive oil. 102... for Specific Nonstandardized Foods § 102.37 Mixtures of edible fat or oil and olive oil. The common or... olive oil shall be as follows: (a) A descriptive name for the product meeting the requirements of § 102...

  12. Crude oil desulfurization

    NASA Technical Reports Server (NTRS)

    Kalvinskas, J. J.; Hsu, G. C.; Ernest, J. B. (Inventor)

    1982-01-01

    High sulfur crude oil is desulfurized by a low temperature (25-80 C.) chlorinolysis at ambient pressure in the absence of organic solvent or diluent but in the presence of water (water/oil=0.3) followed by a water and caustic wash to remove sulfur and chlorine containing reaction products. The process described can be practiced at a well site for the recovery of desulfurized oil used to generate steam for injection into the well for enhanced oil recovery.

  13. Greek Pinus essential oils: larvicidal activity and repellency against Aedes albopictus (Diptera: Culicidae).

    PubMed

    Koutsaviti, Katerina; Giatropoulos, Athanassios; Pitarokili, Danae; Papachristos, Dimitrios; Michaelakis, Antonios; Tzakou, Olga

    2015-02-01

    The needle volatiles metabolites of seven Pinus spp.: Pinus nigra (3 samples), Pinus stankewiczii, Pinus brutia, Pinus halepensis, Pinus canariensis, Pinus pinaster and Pinus strobus from Greece were determined by gas chromatography and gas chromatography-mass spectrometry. P. nigra and P. canariensis essential oils were dominated by α-pinene (24.9-28.9 % and 15 %, respectively) and germacrene D (20.3-31.9 % and 55.8 %, respectively), whereas P. brutia and P. strobus by α-pinene (20.6 % and 31.4 %, respectively) and β-pinene (31.7 % and 33.6 %, respectively). P. halepensis and P. pinaster oils were characterized by β-caryophyllene (28.5 % and 22.5 %, respectively). Finally, β-pinene (31.4 %), germacrene D (23.3 %) and α-pinene (17.5 %) were the most abundant compounds in the needle oil of P. stankewiczii. Additionally the larvicidal and repellent properties of their essential oils were evaluated against Aedes albopictus, a mosquito of great ecological and medical importance. The results of bioassays revealed that repellent abilities of the tested essential oils were more potent than their larvicidal activities. The essential oils of P. brutia, P. halepensis and P. stankewiczii presented considerable larvicidal activity (LC50 values 67.04 mgL(-1) and 70.21 mgL(-1), respectively), while the others were weak to inactive against larvae. The essential oils of P. halepensis, P. brutia, and P. stankewiczii presented a high repellent activity, even at the dose of 0.2 μL cm(-2), while in the dose of 0.4 μL cm(-2), almost all the tested EOs displayed protection against the mosquito.

  14. Determination of Calorific Ability of Fuel Briquettes on the Basis of Oil and Oil Slimes

    NASA Astrophysics Data System (ADS)

    Fedyaeva, O. A.; Poshelyuzhnaya, E. G.; Rakhmatulina, E. M.; Zakharov, V. A.; Fisenko, T. E.

    2018-01-01

    Utilization and neutralization of oil slimes is one of important environmental problems of the oil-extracting, oil-processing and petrochemical industry. The easiest and economic way of utilization of oil slimes is their use as a part of the bricketed boiler fuel. In this work the highest calorific ability of crude oil, the oil slimes and fuel briquettes made on their basis is defined. A research problem was carrying out the technical analysis of oil fuels on the content in them analytical moisture, the cindery rest and volatiles. It is established that in comparison with oil slimes crude oil possesses bigger highest calorific ability, has smaller humidity and an ash-content. The highest calorific abilities of the boiler briquettes made of samples of crude oil, oil slimes and peat made 14 - 26 MJ/kg.

  15. Sassafras oil overdose

    MedlinePlus

    Sassafras oil comes from the root bark of the sassafras tree. Sassafras oil overdose occurs when someone swallows more than the ... Safrole is the poisonous ingredient in sassafras oil. It is a clear or ... yellow oily liquid. It can be dangerous in large amounts.

  16. Method of refining cracked oil by using metallic soaps. [desulfurization of cracked oils

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Masakichi, M.; Marunouchi, K.K.; Yoshimura, T.

    1937-04-13

    The method of refining cracked oil consists in dissolving oil-soluble heavy metallic soap of oleic acid in a volatile organic solvent which will disperse homogeneously in cracked oil; pouring the solution thus obtained slowly into cracked oil to effect dispersion naturally and homogeneously at room temperature in the cracked oil. This process serves to react the mercaptans in the cracked oil with the heavy metallic soap by a double decomposition reaction and to precipitate the mercaptans as insoluble metallic salts. The remaining liquid is distilled to separate it from the remaining solvent.

  17. Development and application of damage assessment modeling: example assessment for the North Cape oil spill.

    PubMed

    McCay, Deborah French

    2003-01-01

    Natural resource damage assessment (NRDA) models for oil spills have been under development since 1984. Generally applicable (simplified) versions with built-in data sets are included in US government regulations for NRDAs in US waters. The most recent version of these models is SIMAP (Spill Impact Model Application Package), which contains oil fates and effects models that may be applied to any spill event and location in marine or freshwater environments. It is often not cost-effective or even possible to quantify spill impacts using field data collections. Modeling allows quantification of spill impacts using as much site-specific data as available, either as input or as validation of model results. SIMAP was used for the North Cape oil spill in Rhode Island (USA) in January 1996, for injury quantification in the first and largest NRDA case to be performed under the 1996 Oil Pollution Act NRDA regulations. The case was successfully settled in 1999. This paper, which contains a description of the model and application to the North Cape spill, delineates and demonstrates the approach.

  18. Comparing terpenes from plant essential oils as pesticides for the poultry red mite (Dermanyssus gallinae).

    PubMed

    Sparagano, O; Khallaayoune, K; Duvallet, G; Nayak, S; George, D

    2013-11-01

    Resistance to conventional synthetic pesticides has been widely reported in ticks, parasitic mites and other pests of veterinary and medical significance. New and novel approaches to manage these pests are therefore needed to ensure efficient control programmes that can be implemented now and in the future. Recent research in this area has focused on the pesticidal potential of plant essential oils. These products are attractive as pesticide candidates on the grounds of low mammalian toxicity, short environmental persistence and complex chemistries (limiting the development of pest resistance against them). Although issues may exist concerning reliability in efficacy of essential oils, these may be overcome by identifying and developing bioactive oil components for use in pest management. In the current work, three such components (terpenes) found in essential oils (eugenol, geraniol and citral) were tested against the poultry red mite Dermanyssus gallinae. All provided 100% mortality in toxicity tests when undiluted. Even at 1% of this dose, eugenol was 20% effective against experimental pest populations, although the remaining terpenes were largely ineffective at this concentration. © 2013 Blackwell Verlag GmbH.

  19. Break-even analysis in a nurse-managed center.

    PubMed

    McBryde-Foster, Merry J

    2005-01-01

    The concept of break-even analysis as a financial assessment tool is defined and demonstrated in evaluation of a proposed nurse-managed center. The advantages of using break-even analysis during proposal development are explored.

  20. Oil shocks in New Keynesian models: Positive and normative implications

    NASA Astrophysics Data System (ADS)

    Chang, Jian

    Chapter 1 investigates optimal monetary policy response towards oil shocks in a New Keynesian model. We find that optimal policy, in general, becomes contractionary in response to an adverse oil shock. However, the optimal policy rule and the inflation-output trade-off depend on the specific structure of the model. The benchmark economy consists of a flexible-price energy sector and a sticky-price manufacturing sector where energy is used as an intermediate input. We show that optimal policy is to stabilize the sticky (core) price level. We then show that after incorporating a less oil-dependent sticky-price service sector, the model exhibits a trade-off in stabilizing prices and output gaps in the different sticky-price sectors. It predicts that central bank should not try to stabilize the core price level, and the economy will experience higher inflation and rising output gaps, even if central banks respond optimally. Chapter 2 addresses the observed volatility and persistence of real exchange rates and the terms of trade. It contributes to the literature with a quantitative study on the U.S. and Canada. A two-country New Keynesian model consisting of traded, non-traded, and oil production sectors is proposed to examine the time series properties of the real exchange rate, the terms of trade and the real oil price. We find that after incorporating several realistic features (namely oil price shocks, sector specific labor, non-traded goods, asymmetric pricing decisions of exporters and asymmetric consumer preferences over tradables), the benchmark model broadly matches the volatilities of the relative prices and some business cycle correlations. The model matches the data more closely after adding real demand shocks, suggesting their importance in explaining the relative price movements between the US and Canada. Chapter 3 explores several sources and transmission channels of international relative price movements. In particular, we elaborate on the role of

  1. Getty: producing oil from diatomite

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zublin, L.

    1981-10-01

    Getty Oil Company has developed unconventional oil production techniques which will yield oil from diatomaceous earth. They propose to mine oil-saturated diatomite using open-pit mining methods. Getty's diatomite deposit in the McKittrick field of California is unique because it is cocoa brown and saturated with crude oil. It is classified also as a tightly packed deposit, and oil cannot be extracted by conventional oil field methods.

  2. Migrated phthalate levels into edible oils.

    PubMed

    Sungur, Sana; Okur, Ramazan; Turgut, Faruk Hilmi; Ustun, Ihsan; Gokce, Cumali

    2015-01-01

    The determination of phthalates in edible oils (virgin olive oil, olive oil, canola oil, hazelnut oil, sunflower oil, corn oil) sold in Turkish markets was carried out using gas chromatography-mass spectrometry. Mean phthalate concentrations were between 0.102 and 3.863 mg L(-1) in virgin olive oil; 0.172 and 6.486 mg L(-1) in olive oil; 0.501 and 3.651 mg L(-1) in hazelnut oil; 0.457 and 3.415 mg L(-1) in canola oil; 2.227 and 6.673 mg L(-1) in sunflower oil; and 1.585 and 6.248 mg L(-1) in corn oil. Furthermore, the influence of the types of oil and container to the phthalate migration was investigated. The highest phthalate levels were measured in sunflower oil. The lowest phthalate levels were determined in virgin olive oil and hazelnut oil. The highest phthalate levels were determined in oil samples contained in polyethylene terephthalate.

  3. Marine Oil Biodegradation

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hazen, Terry C.; Prince, Roger; Mahmoudi, Nagissa

    Crude oil has been part of the marine environment for millions of years, and microbes that use its rich source of energy and carbon are found in seawater, sediments and shorelines from the tropics to the polar regions. Catastrophic oil spills stimulate these organisms to ‘bloom’ in a reproducible fashion, and although oil does not provide bioavailable nitrogen, phosphorus or iron, there are enough of these nutrients in the sea that when dispersed oil droplets dilute to low concentrations these low levels are adequate for microbial growth. Most of the hydrocarbons in dispersed oil are degraded in aerobic marine watersmore » with a half-life of days to months. In contrast, oil that reaches shorelines is likely to be too concentrated, have lower levels of nutrients, and have a far longer residence time in the environment. Oil that becomes entrained in anaerobic sediments is also likely to have a long residence time, although it too will eventually be biodegraded. Thus, data that encompass everything from the ecosystem to the molecular level are needed for understanding the complicated process of petroleum biodegradation in marine environments.« less

  4. Marine Oil Biodegradation

    DOE PAGES

    Hazen, Terry C.; Prince, Roger; Mahmoudi, Nagissa

    2015-12-23

    Crude oil has been part of the marine environment for millions of years, and microbes that use its rich source of energy and carbon are found in seawater, sediments and shorelines from the tropics to the polar regions. Catastrophic oil spills stimulate these organisms to ‘bloom’ in a reproducible fashion, and although oil does not provide bioavailable nitrogen, phosphorus or iron, there are enough of these nutrients in the sea that when dispersed oil droplets dilute to low concentrations these low levels are adequate for microbial growth. Most of the hydrocarbons in dispersed oil are degraded in aerobic marine watersmore » with a half-life of days to months. In contrast, oil that reaches shorelines is likely to be too concentrated, have lower levels of nutrients, and have a far longer residence time in the environment. Oil that becomes entrained in anaerobic sediments is also likely to have a long residence time, although it too will eventually be biodegraded. Thus, data that encompass everything from the ecosystem to the molecular level are needed for understanding the complicated process of petroleum biodegradation in marine environments.« less

  5. Oil and oil dispersant do not cause synergistic toxicity to fish embryos.

    PubMed

    Adams, Julie; Sweezey, Michael; Hodson, Peter V

    2014-01-01

    Atlantic herring (Clupea harengus) embryos were exposed to water accommodated fractions (WAFs; oil dissolved in water) and chemically enhanced water accommodated fractions (CEWAFs; oil dispersed in water with Corexit 9500A) of Medium South American (MESA) crude oil. The CEWAF was approximately 100-fold more toxic than WAF based on nominal loadings of test solutions (% v/v). In contrast, the ratio of WAF and CEWAF toxicity expressed as measured oil concentrations approximated 1.0, indicating that the higher toxicity of CEWAFs was caused by an increase in exposure to hydrocarbons with chemical dispersion. In a second experiment, the chronic toxicity of Corexit 9500A and chemically dispersed heavy fuel oil 7102 (HFO 7102) to rainbow trout (Oncorhynchus mykiss) embryos was compared to chemically dispersed Nujol, a nontoxic mineral oil. Dispersant alone was toxic, but caused different signs of toxicity than HFO 7102. Nujol at a dispersant-to-oil ratio of 1:20 was nontoxic, suggesting that dispersant was sequestered by oil and not present at toxic concentrations. In contrast, the same nominal loadings of dispersed HFO 7102 caused concentration-dependent increases in toxicity. Both experiments suggest that chemically dispersed oil was more toxic to fish embryos than solutions created by mechanical mixing due to the increased exposure of fish to petroleum hydrocarbons and not to changes in hydrocarbon toxicity. The Nujol control discriminated between the toxicity of oil and chemical dispersant and would be a practical addition to programs of dispersant testing.

  6. The biodegradation of cable oil components: impact of oil concentration, nutrient addition and bioaugmentation.

    PubMed

    Towell, Marcie G; Paton, Graeme I; Semple, Kirk T

    2011-12-01

    The effect of cable oil concentration, nutrient amendment and bioaugmentation on cable oil component biodegradation in a pristine agricultural soil was investigated. Biodegradation potential was evaluated over 21 d by measuring cumulative CO(2) respiration on a Micro-Oxymax respirometer and (14)C-phenyldodecane mineralisation using a (14)C-respirometric assay. Cable oil concentration had a significant effect upon oil biodegradation. Microbial respiratory activity increased with increasing cable oil concentration, whereas (14)C-phenydodecane mineralisation decreased. Bioaugmentation achieved the best cable oil biodegradation performance, resulting in increases in cumulative CO(2) respiration, and maximum rates and extents of (14)C-phenyldodecane mineralisation. Generally, nutrient amendment also enhanced cable oil biodegradation, but not to the extent that degrader amendment did. Cable oil biodegradation was a function of (i) cable oil concentration and (ii) catabolic ability of microbial populations. Bioaugmentation may enhance cable oil biodegradation, and is dependent upon composition, cell number and application of catabolic inocula to soil. Copyright © 2011 Elsevier Ltd. All rights reserved.

  7. Coreflood assay using extremophile microorganisms for recovery of heavy oil in Mexican oil fields.

    PubMed

    Castorena-Cortés, Gladys; Roldán-Carrillo, Teresa; Reyes-Avila, Jesús; Zapata-Peñasco, Icoquih; Mayol-Castillo, Martha; Olguín-Lora, Patricia

    2012-10-01

    A considerable portion of oil reserves in Mexico corresponds to heavy oils. This feature makes it more difficult to recover the remaining oil in the reservoir after extraction with conventional techniques. Microbial enhanced oil recovery (MEOR) has been considered as a promising technique to further increase oil recovery, but its application has been developed mainly with light oils; therefore, more research is required for heavy oil. In this study, the recovery of Mexican heavy oil (11.1°API and viscosity 32,906 mPa s) in a coreflood experiment was evaluated using the extremophile mixed culture A7, which was isolated from a Mexican oil field. Culture A7 includes fermentative, thermophilic, and anaerobic microorganisms. The experiments included waterflooding and MEOR stages, and were carried out under reservoir conditions (70°C and 9.65 MPa). MEOR consisted of injections of nutrients and microorganisms followed by confinement periods. In the MEOR stages, the mixed culture A7 produced surface-active agents (surface tension reduction 27 mN m⁻¹), solvents (ethanol, 1738 mg L⁻¹), acids (693 mg L⁻¹), and gases, and also degraded heavy hydrocarbon fractions in an extreme environment. The interactions of these metabolites with the oil, as well as the bioconversion of heavy oil fractions to lighter fractions (increased alkanes in the C₈-C₃₀ range), were the mechanisms responsible for the mobility and recovery of heavy oil from the porous media. Oil recovery by MEOR was 19.48% of the residual oil in the core after waterflooding. These results show that MEOR is a potential alternative to heavy oil recovery in Mexican oil fields. Copyright © 2012 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

  8. Effect of Macondo Prospect 252 Oil on Microbiota Associated with Pelagic Sargassum in the Northern Gulf of Mexico.

    PubMed

    Torralba, Manolito G; Franks, James S; Gomez, Andres; Yooseph, Shibu; Nelson, Karen E; Grimes, D Jay

    2017-01-01

    The environmental impact of major oil spills on marine microorganisms has yet to be thoroughly investigated using molecular biology techniques. The Deepwater Horizon (DWH) drilling rig explosion of 2010 affected an approximately 176,000 km 2 surface area of the Gulf of Mexico (GOM) when an estimated 210 million gallons of oil from the Macondo Prospect spilled into the environment. Pelagic Sargassum, a complex of two surface drifting species (Sargassum natans and Sargassum fluitans) of marine brown macroalgae and a critically important habitat in the GOM ecosystem, was suffused by Macondo Prospect 252 oil released during the DWH event. Using 16S rRNA PCR and Roche 454 pyrosequencing, the effect of the oil on the bacterial population associated with pelagic Sargassum and contiguous waters was examined by comparing sequence data generated from samples collected from oiled and non-oiled locations in the northern GOM. Sequence data showed similar microbial composition in Sargassum regardless of exposure to oil primarily dominated by five phyla; Proteobacteria, Bacteroidetes, Actinobacteria, Verrucomicrobia, and unclassified bacteria. The microbial composition in water samples was significantly less diverse than for Sargassum and consisted primarily of Proteobacteria, Firmicutes, and Bacteroidetes. Due to the evenly distributed abundance of microbial species on oiled and non-oiled pelagic Sargassum, study findings indicate that DWH spilled oil had minimal effect on the composition and diversity of the microbial community associated with Sargassum and contiguous waters. However, higher abundances of Sulfitobacter and one species of Psychrobacter were found in oiled water samples when compared to non-oiled water samples indicating some effect of DHW oil in the microbial composition of seawater. Though there are a number of marine studies using molecular biology approaches, this is the first molecular examination of the impact of the DWH oil spill on bacterial communities

  9. Preventive effect of cinnamon essential oil on lipid oxidation of vegetable oil

    PubMed Central

    Keshvari, Mahtab; Asgary, Sedigheh; Jafarian-dehkordi, Abbas; Najafi, Somayeh; Ghoreyshi-Yazdi, Seyed Mojtaba

    2013-01-01

    BACKGROUND Lipid oxidation is the main deterioration process that occurs in vegetable oils. This process was effectively prevented by natural antioxidants. Cinnamomum zeylanicum (Cinnamon) is rich with antioxidants. The present study was conducted to evaluate the effect of cinnamon on malondialdehyde (MDA) rate production in two high consumption oils in Iranian market. METHODS Chemical composition of cinnamon essential oil was analyzed by gas chromatography-mass spectroscopy (GC-MS). 200 µl each oil, 50 µl tween 20, and 2 ml of 40 Mm AAPH solutions were mixed and the prepared solution was divided into four glass vials. Respectively, 50 µl of 500, 1000 and 2000 ppm of cinnamon essential oil were added to three glass vials separately and one of the glass vials was used as the control. All of the glass vials were incubated at 37° C water bath. Rate of MDA production was measured by thiobarbituric acid (TBA) test at the baseline and after the 0.5, 1, 2, 3 and 5 hours. RESULTS Compounds of cinnamon essential oil by GC-MS analysis such as cinnamaldehyde (96.8%), alpha-capaene (0.2%), alpha-murolene (0.11%), para-methoxycinnamaldehyde (0.6%) and delta-cadinen (0.4%) were found to be the major compounds. For both oils, maximum rate of MDA production was achieved in 5th hours of heating. Every three concentrations of cinnamon essential oil significantly decreased MDA production (P < 0.05) in comparison with the control. CONCLUSION Essential oil of cinnamon considerably inhibited MDA production in studied oils and can be used with fresh and heated oils for reduction of lipid peroxidation and adverse free radicals effects on body. PMID:24302936

  10. Oil-free centrifugal hydrogen compression technology demonstration

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Heshmat, Hooshang

    2014-05-31

    One of the key elements in realizing a mature market for hydrogen vehicles is the deployment of a safe and efficient hydrogen production and delivery infrastructure on a scale that can compete economically with current fuels. The challenge, however, is that hydrogen, being the lightest and smallest of gases with a lower viscosity and density than natural gas, readily migrates through small spaces and is difficult to compresses efficiently. While efficient and cost effective compression technology is crucial to effective pipeline delivery of hydrogen, the compression methods used currently rely on oil lubricated positive displacement (PD) machines. PD compression technologymore » is very costly, has poor reliability and durability, especially for components subjected to wear (e.g., valves, rider bands and piston rings) and contaminates hydrogen with lubricating fluid. Even so called “oil-free” machines use oil lubricants that migrate into and contaminate the gas path. Due to the poor reliability of PD compressors, current hydrogen producers often install duplicate units in order to maintain on-line times of 98-99%. Such machine redundancy adds substantially to system capital costs. As such, DOE deemed that low capital cost, reliable, efficient and oil-free advanced compressor technologies are needed. MiTi’s solution is a completely oil-free, multi-stage, high-speed, centrifugal compressor designed for flow capacity of 500,000 kg/day with a discharge pressure of 1200 psig. The design employs oil-free compliant foil bearings and seals to allow for very high operating speeds, totally contamination free operation, long life and reliability. This design meets the DOE’s performance targets and achieves an extremely aggressive, specific power metric of 0.48 kW-hr/kg and provides significant improvements in reliability/durability, energy efficiency, sealing and freedom from contamination. The multi-stage compressor system concept has been validated through full

  11. Nanofluid of graphene-based amphiphilic Janus nanosheets for tertiary or enhanced oil recovery: High performance at low concentration

    PubMed Central

    Luo, Dan; Wang, Feng; Zhu, Jingyi; Cao, Feng; Liu, Yuan; Li, Xiaogang; Willson, Richard C.; Yang, Zhaozhong; Chu, Ching-Wu; Ren, Zhifeng

    2016-01-01

    The current simple nanofluid flooding method for tertiary or enhanced oil recovery is inefficient, especially when used with low nanoparticle concentration. We have designed and produced a nanofluid of graphene-based amphiphilic nanosheets that is very effective at low concentration. Our nanosheets spontaneously approached the oil–water interface and reduced the interfacial tension in a saline environment (4 wt % NaCl and 1 wt % CaCl2), regardless of the solid surface wettability. A climbing film appeared and grew at moderate hydrodynamic condition to encapsulate the oil phase. With strong hydrodynamic power input, a solid-like interfacial film formed and was able to return to its original form even after being seriously disturbed. The film rapidly separated oil and water phases for slug-like oil displacement. The unique behavior of our nanosheet nanofluid tripled the best performance of conventional nanofluid flooding methods under similar conditions. PMID:27354529

  12. [Advances in novel carrier systems of chemical constituents from spice volatile oils].

    PubMed

    Zhang, Jia-jia; Zhu, Yuan; Yu, Jiang-nan; Xu, Xi-ming

    2015-10-01

    Recent years, chemical constituents from spice volatile oils have gained worldwide concern owing to its multiple pharmacological effects and safety for using as the natural antibacterial agents. However, their poor dissolution, strong volatility, serious irritation, weak stability, easy oxidation and low bioavailability characteristics are the major obstacle in the preparation of effective oral formulation and practical application. Therefore, there is an urgent need to select a novel carrier system that can delivery the chemical constituents from spice volatile oils more efficiently with improving their stability as well as alleviating the irritation, and develop the functional food, health products and even medicine for exerting their pharmacological effects, which also is the focus and nodus of the research on their application. This review presents recent systematic studies on their novel carrier systems, including cyclodextrin inclusion complex, liposomes, nanoemulsions, nanoparticles, solid dispersion and so on, and summarizes the characteristics, application range and problems of each novel carrier systems, in order to provide some beneficial thoughts in further developing new products of chemical constituents from spice volatile oils.

  13. Water Displacement in Oil-Wet Tight Reservoirs by Dynamic Network Simulation

    NASA Astrophysics Data System (ADS)

    Wang, Y.; Li, M.; Chen, M.

    2017-12-01

    Pore network simulation is an effective tool for studying the multiphase flow in porous media. Based on the topological information and pore-throat size distribution obtained from the analysis of Scanning Electron Microscope (SEM) and constant-rate mercury injection (CRMI) for tight cores (composed by micro-nano scale throats and micro scale pores), a simple cubic (SC) pore-throat network was built with equilateral triangular cross-section throats and cubic bodies. Rules for oil and water movement and redistribution were devised in accordance with the physics process at pore-throat scale. Water flooding from oil-saturated under irreducible water were simulated by considering the changing displacement rate and viscosity ratio at the slightly oil-wet condition (the static contact angle ranges between π/2 to 2π/3). Different from the double pressure field algorithm, a single pressure field which solved by using successive over relaxation method was used with the flow of irreducible water in corners was ignored while its swilling was take into consideration. Dynamic of displacement fronts, relative permeability curves and residual oil saturation were obtained. It showed that there were obviously snap-off at low capillary number (Nc<10-5) and fingering at high capillary number (Nc<10-4) even at a favorable viscosity ratio (M=1). The magnitude of viscosity ratio effect on relative permeability depended largely on the capillary number, which the effect wasn't noticeable for a high capillary number. For residual oil saturation Sor, it showed that Sor decreased with the increase of capillary number at different viscosity ratio. Changing of residual oil saturation from simulation was in good agreement with the experimental results in a certain range, which indicated that this network model could be used to character the water flooding in tight reservoirs.

  14. Raman detection of extra virgin olive oil adulterated with cheaper oils

    NASA Astrophysics Data System (ADS)

    Farley, Carlton; Kassu, Aschalew; Mills, Jonathan; Kenney, Brianna; Ruffin, Paul; Sharma, Anup

    2016-09-01

    Pure extra virgin olive oil (EVOO) is mixed with cheaper edible oils and samples are kept inside clear glass containers, while a 785nm Raman system is used to take measurements as Raman probe is placed against glass container. Several types of oils at various concentrations of adulteration are used. Ratios of peak intensities are used to analyze raw data, which allows for quick, easy, and accurate analysis. While conventional Raman measurements of EVOO may take as long as 2 minutes, all measurements reported here are for integration times of 15s. It is found that adulteration of EVOO with cheaper oils is detectable at concentrations as low as 5% for all oils used in this study.

  15. Political economy of oil

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Banks, F.E.

    1980-01-01

    A nontechnical discussion of the political economy of the world oil market is intended to inform the beginning student as well as serve as a reference book. Beginning with definitions and an explanation of units, the text covers the world economy, oil supply, oil prices, oil consumption and non-oil energy materials supplies, oil companies, macroeconomics, and the market in an effort to relate both macro- and microeconomic phenomena. Professor Banks feels that population is the most crucial factor in economics today, followed by nonfuel minerals and energy; the technical problems pertaining to energy, however, can be managed if the firstmore » two are faced and dealt with. He thinks the outlook is good for replacing oil with other energy sources. 143 references, 23 figures, 26 tables. (DKC)« less

  16. Comparison of water use for hydraulic fracturing for unconventional oil and gas versus conventional oil.

    PubMed

    Scanlon, B R; Reedy, R C; Nicot, J-P

    2014-10-21

    We compared water use for hydraulic fracturing (HF) for oil versus gas production within the Eagle Ford shale. We then compared HF water use for Eagle Ford oil with Bakken oil, both plays accounting for two-thirds of U.S. unconventional oil production in 2013. In the Eagle Ford, we found similar average water use in oil and gas zones per well (4.7-4.9 × 10(6) gallons [gal]/well). However, about twice as much water is used per unit of energy (water-to-oil ratio, WOR, vol water/vol oil) in the oil zone (WOR: 1.4) as in the gas zone (water-to-oil-equivalent-ratio, WOER: 0.6). We also found large differences in water use for oil between the two plays, with mean Bakken water use/well (2.0 × 10(6) gal/well) about half that in the Eagle Ford, and a third per energy unit. We attribute these variations mostly to geological differences. Water-to-oil ratios for these plays (0.6-1.4) will further decrease (0.2-0.4) based on estimated ultimate oil recovery of wells. These unconventional water-to-oil ratios (0.2-1.4) are within the lower range of those for U.S. conventional oil production (WOR: 0.1-5). Therefore, the U.S. is using more water because HF has expanded oil production, not because HF is using more water per unit of oil production.

  17. Toluene diisocyanate based phase-selective supramolecular oil gelator for effective removal of oil spills from polluted water.

    PubMed

    Wang, Yongzhen; Wang, Youshan; Yan, Xingru; Wu, Songquan; Shao, Lu; Liu, Yuyan; Guo, Zhanhu

    2016-06-01

    Due to tremendous resource wastes and great harm to ecological environment caused by the accidental oil spills, an alkyl bicarbamate supramolecular oil gelator was synthesized and applied to selectively gelate oils from oil/water mixtures. Interestingly, the oil gelator could be self-assembled in a series of organic solvents, i.e., edible oils and fuel oils to form 3D networks and then turned into thermally reversible organogels, allowing easy separation and removal of oil spills from oil/water mixtures. The possible self-assembly mode for the formation of organogels was proposed. What's more, the optimal conditions for using the oil gelator to recover oils were experimentally determined. Inspiringly, taking gasoline as the co-congealed solvent, a complete gelation of oil phase was achieved within 15 min with high oil removal rate and oil retention rate after convenient salvage and cleanup of oil gels from oil/water mixtures. The oil gelator had some advantages in solidifying oil spills on water surface, exhibiting fast oil gelation, convenient and thorough oil removal and easy recovery. This work illustrates the significant role of oil gelators in the potential cleanup of spilled oils for water purification. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Peppermint Oil

    MedlinePlus

    ... and other problems. Peppermint leaf is available in teas, capsules, and as a liquid extract. Peppermint oil ... the oil. No harmful effects of peppermint leaf tea have been reported. However, the long-term safety ...

  19. Palm Oil

    MedlinePlus

    ... A deficiency, cancer, brain disease, aging; and treating malaria, high blood pressure, high cholesterol, and cyanide poisoning. ... oils, such as soybean, canola, or sunflower oil. Malaria. Some research suggests that dietary consumption of palm ...

  20. Peanut Oil

    MedlinePlus

    ... Rectally, peanut oil is used in ointments and medicinal oils for treating constipation. Pharmaceutical companies use peanut ... applied to the skin, or used rectally in medicinal amounts. Special precautions & warnings: Pregnancy and breast-feeding: ...

  1. Oil detection in a coastal marsh with polarimetric Synthetic Aperture Radar (SAR)

    USGS Publications Warehouse

    Ramsey, Elijah W.; Rangoonwala, Amina; Suzuoki, Yukihiro; Jones, Cathleen E.

    2011-01-01

    The National Aeronautics and Space Administration's airborne Uninhabited Aerial Vehicle Synthetic Aperture Radar (UAVSAR) was deployed in June 2010 in response to the Deepwater Horizon oil spill in the Gulf of Mexico. UAVSAR is a fully polarimetric L-band Synthetic Aperture Radar (SAR) sensor for obtaining data at high spatial resolutions. Starting a month prior to the UAVSAR collections, visual observations confirmed oil impacts along shorelines within northeastern Barataria Bay waters in eastern coastal Louisiana. UAVSAR data along several flight lines over Barataria Bay were collected on 23 June 2010, including the repeat flight line for which data were collected in June 2009. Our analysis of calibrated single-look complex data for these flight lines shows that structural damage of shoreline marsh accompanied by oil occurrence manifested as anomalous features not evident in pre-spill data. Freeman-Durden (FD) and Cloude-Pottier (CP) decompositions of the polarimetric data and Wishart classifications seeded with the FD and CP classes also highlighted these nearshore features as a change in dominant scattering mechanism. All decompositions and classifications also identify a class of interior marshes that reproduce the spatially extensive changes in backscatter indicated by the pre- and post-spill comparison of multi-polarization radar backscatter data. FD and CP decompositions reveal that those changes indicate a transform of dominant scatter from primarily surface or volumetric to double or even bounce. Given supportive evidence that oil-polluted waters penetrated into the interior marshes, it is reasonable that these backscatter changes correspond with oil exposure; however, multiple factors prevent unambiguous determination of whether UAVSAR detected oil in interior marshes.

  2. Rethink potential risks of toxic emissions from natural gas and oil mining.

    PubMed

    Meng, Qingmin

    2018-09-01

    Studies have showed the increasing environmental and public health risks of toxic emissions from natural gas and oil mining, which have become even worse as fracking is becoming a dominant approach in current natural gas extraction. However, governments and communities often overlook the serious air pollutants from oil and gas mining, which are often quantified lower than the significant levels of adverse health effects. Therefore, we are facing a challenging dilemma: how could we clearly understand the potential risks of air toxics from natural gas and oil mining. This short study aims at the design and application of simple and robust methods to enhance and improve current understanding of the becoming worse toxic air emissions from natural gas and oil mining as fracking is becoming the major approach. Two simple ratios, the min-to-national-average and the max-to-national-average, are designed and applied to each type of air pollutants in a natural gas and oil mining region. The two ratios directly indicate how significantly high a type of air pollutant could be due to natural gas and oil mining by comparing it to the national average records, although it may not reach the significant risks of adverse health effects according to current risk screening methods. The min-to-national-average and the max-to-national-average ratios can be used as a direct and powerful method to describe the significance of air pollution by comparing it to the national average. The two ratios are easy to use for governments, stakeholders, and the public to pay enough attention on the air pollutants from natural gas and oil mining. The two ratios can also be thematically mapped at sampled sites for spatial monitoring, but spatial mitigation and analysis of environmental and health risks need other measurements of environmental and demographic characteristics across a natural gas and oil mining area. Copyright © 2018 Elsevier Ltd. All rights reserved.

  3. Effect of plant essential oils as acaricides against the poultry red mite, Dermanyssus gallinae, with special focus on exposure time.

    PubMed

    George, D R; Olatunji, G; Guy, J H; Sparagano, O A E

    2010-04-19

    Essential oils from thyme and cade have been shown to be effective acaricides against the poultry red mite, Dermanyssus gallinae (De Geer) when tested over a 24h period. Data on the actual rate of knock-down achieved with these products is lacking and potentially important as essential oils are likely to display only short-term toxicity. When tested over periods of less than 24h, thyme essential oil killed D. gallinae relatively quickly and so may make for an effective acaricide even if the residual toxicity of this product is low. However, cade essential oil did not display such a high level of mite knock-down, suggesting it may hold less promise in D. gallinae management. Comparison of the results with those obtained elsewhere using alternative D. gallinae products further confirms the possibility that thyme essential may be useful in control of this pest. This might be especially true if thyme essential oil were employed as part of an integrated pest management approach.

  4. Evidence for a palaeo-oil column and alteration of residual oil in a gas-condensate field: Integrated oil inclusion and experimental results

    NASA Astrophysics Data System (ADS)

    Bourdet, Julien; Burruss, Robert C.; Chou, I.-Ming; Kempton, Richard; Liu, Keyu; Hung, Nguyen Viet

    2014-10-01

    In the Phuong Dong gas condensate field, Cuu Long Basin, Vietnam, hydrocarbon inclusions in quartz trapped a variety of petroleum fluids in the gas zone. Based on the attributes of the oil inclusion assemblages (fluorescence colour of the oil, bubble size, presence of bitumen), the presence of a palaeo-oil column is inferred prior to migration of gas into the reservoir. When a palaeo-oil column is displaced by gas, a residual volume fraction of oil remains in pores. If the gas does not completely mix with the oil, molecular partitioning between the residual oil and the new gas charge may change the composition and properties of the residual oil (gas stripping or gas washing). To simulate this phenomenon in the laboratory, we sealed small amounts of crude oil (42 and 30 °API) and excess pure gas (methane, ethane, or propane) in fused silica capillary capsules (FSCCs), with and without water. These mixtures were characterized with the same methods used to characterize the fluid inclusions, heating and cooling stage microscopy, fluorescence spectroscopy, synchrotron FT-IR, and Raman spectroscopy. At room temperature, mixtures of ethane and propane with the 30 °API oil formed a new immiscible fluorescent liquid phase with colour that is visually more blue than the initial oil. The fluorescence of the original oil phase shifted to yellow or disappeared with formation of semi-solid residues. The blue-shift of the fluorescence of the immiscible phases and strong CH stretching bands in FT-IR spectra are consistent with stripping of hydrocarbon molecules from the oil. In experiments in FSCCs with water solid residues are common. At elevated temperature, reproducing geologic reservoir conditions, the fluorescence changes and therefore the molecular fractionation are enhanced. However, the precipitation of solid residues is responsible of more complex changes. Mixing experiments with the 42 °API oil do not form a new immiscible hydrocarbon liquid although the fluorescence

  5. Tests of oil scraper piston ring and piston fitted with oil drain holes

    NASA Technical Reports Server (NTRS)

    Mcdewell, H S

    1922-01-01

    Tests were conducted to determine whether or not a properly located and properly designed oil scraper piston ring, installed on a piston provided with oil drain holes of sufficient area, would prevent the excessive oiling of the Liberty engine, particularly with the engine running at idling speed with full oil pressure. Results showed that excessive oiling was in fact prevented. It is strongly recommended that scraper rings and pistons be adopted for aircraft engines.

  6. Method to separate and recover oil and plastic from plastic contaminated with oil

    DOEpatents

    Smith, Henry M.; Bohnert, George W.; Olson, Ronald B.; Hand, Thomas E.

    1998-01-27

    The present invention provides a method to separate and recover oils and recyclable plastic from plastic contaminated with oil. The invention utilizes the different solubility of oil in as liquid or supercritical fluid as compared to a gas to effect separation of the oil from the plastic.

  7. Utilization of sulphurized palm oil as cutting fluid base oil for broaching process

    NASA Astrophysics Data System (ADS)

    Sukirno; Ningsih, Y. R.

    2017-03-01

    Broaching is one of the most severe metal cutting operation that requires the use of cutting fluids formulated with extreme pressure (EP) additives to minimize metal-to-metal contact and improve tool life. Enhancement of EP performances of the cutting fluids can be achieved by addition of sulphur containing compounds that will allow the formation of metal sulfide film that has low shear strength and good antiweld properties and acts as protection layer from wear and seizure. Most of the cutting fluids are mineral oil based. However, as regards to health and environmental issues, reseach on vegetable oil based cutting fluid have been increased recently. This paper reports a study on the sulphurization of palm oil derivatives and its usage as broaching oil. Sulphurization of the palm oil derivative was conducted via non-catalytic sulphurization using elemental sulphur at various composition and under heating of 150-160°C for 3 hr. Broaching oil was made by blending the sulphurized palm oil and additive packages. The performance parameters of the broaching oil that has been observed including load carrying capacity, wear scar diameter, corrosion protection, oxidative stability, and surface finish of workpiece. From this research, it was found that sulphurized FAME based broaching oil has excellent EP properties. The optimum formulation was obtained on composition of sulphurized FAME-mineral oil with 6% wt of sulphur. The result from the test showed that kinematic viscosity of sulphurized palm oil was about 25.3 cSt (at 40 °C), load carrying capacity was 400 kgf, and wear scar diameter was 0.407 mm. In addition, it can be concluded that the class of corrosion protection of modified palm oil was 1.b (slight tarnish category), oxidative stability at 160 °C was obtained for 0.11 hr, and the surface roughness of workpiece was about 0.0418-0.0579 μm. These performances are comparable to commercial broaching oil. By this result, it indicates that sulphurized palm oil is

  8. SOVENT BASED ENHANCED OIL RECOVERY FOR IN-SITU UPGRADING OF HEAVY OIL SANDS

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Munroe, Norman

    With the depletion of conventional crude oil reserves in the world, heavy oil and bitumen resources have great potential to meet the future demand for petroleum products. However, oil recovery from heavy oil and bitumen reservoirs is much more difficult than that from conventional oil reservoirs. This is mainly because heavy oil or bitumen is partially or completely immobile under reservoir conditions due to its extremely high viscosity, which creates special production challenges. In order to overcome these challenges significant efforts were devoted by Applied Research Center (ARC) at Florida International University and The Center for Energy Economics (CEE) atmore » the University of Texas. A simplified model was developed to assess the density of the upgraded crude depending on the ratio of solvent mass to crude oil mass, temperature, pressure and the properties of the crude oil. The simplified model incorporated the interaction dynamics into a homogeneous, porous heavy oil reservoir to simulate the dispersion and concentration of injected CO2. The model also incorporated the characteristic of a highly varying CO2 density near the critical point. Since the major challenge in heavy oil recovery is its high viscosity, most researchers have focused their investigations on this parameter in the laboratory as well as in the field resulting in disparaging results. This was attributed to oil being a complex poly-disperse blend of light and heavy paraffins, aromatics, resins and asphaltenes, which have diverse behaviors at reservoir temperature and pressures. The situation is exacerbated by a dearth of experimental data on gas diffusion coefficients in heavy oils due to the tedious nature of diffusivity measurements. Ultimately, the viscosity and thus oil recovery is regulated by pressure and its effect on the diffusion coefficient and oil swelling factors. The generation of a new phase within the crude and the differences in mobility between the new crude matrix and

  9. Chemical composition and antibiofilm activity of Petroselinum crispum and Ocimum basilicum essential oils against Vibrio spp. strains.

    PubMed

    Snoussi, Mejdi; Dehmani, Ameni; Noumi, Emira; Flamini, Guido; Papetti, Adele

    2016-01-01

    In this study, we evaluated the antibacterial activity of parsley and basilic essential oils tested against Vibrio strains and their abilities to inhibit and eradicate the mature biofilm using the XTT assay. Petroselinum crispum essential oil was characterized by 1,3,8-p-menthatriene (24.2%), β-phellandrene (22.8%), apiol (13.2%), myristicin (12.6%) and terpinolene (10.3%) as a major constituents. While, in the basilic oil, linalool (42.1%), (E)-methylcinnamate (16.9%) and 1-8 cineole (7.6%) were the main ones. These two essential oils exhibit high anti-Vibrio spp. activity with varying magnitudes. All microorganisms were strongly affected indicating an appreciable antimicrobial potential of basilic with a diameter of inhibition zones growth ranging from 8.67 to 23.33 mm and MIC and MBC values ranging from (0.023-0.047 mg/ml) and (>3->24 mg/ml), respectively. The two essential oils can inhibit and eradicate the mature biofilm formed on polystyrene surface even at low concentrations, with high magnitude for Ocimum basilicum essential oil. This study gives a better insight into the anti-Vibrio activity of parsley and basilc oils and the possibility of their use to prevent and eradicate contamination of sea products by these strains. Copyright © 2015 Elsevier Ltd. All rights reserved.

  10. The Research of New Environment-Friendly Oil-based Drilling Fluid Base Oil

    NASA Astrophysics Data System (ADS)

    Sui, Dianjie; Sun, Yuxue; Zhao, Jingyuan; Zhao, Fulei; Zhu, Xiuyu; Xu, Jianjun

    2018-01-01

    In this paper, the heavy hydrocarbon of Daqing is used, and the desulfurization and de-aromatization experiments and refining process are carried out, A base oil suitable for oil-based drilling fluid was developed, and the performance of base oil was evaluated, we can know the aromatics content of oil base is low, less toxic, less pollution and it can meet the requirement of environmental protection.

  11. The determination of water in crude oil and transformer oil reference materials.

    PubMed

    Margolis, Sam A; Hagwood, Charles

    2003-05-01

    The measurement of the amount of water in oils is of significant economic importance to the industrial community, particularly to the electric power and crude oil industries. The amount of water in transformer oils is critical to their normal function and the amount of water in crude oils affects the cost of the crude oil at the well head, the pipeline, and the refinery. Water in oil Certified Reference Materials (CRM) are essential for the accurate calibration of instruments that are used by these industries. Three NIST Standard Reference Materials (SRMs) have been prepared for this purpose. The water in these oils has been measured by both coulometric and volumetric Karl Fischer methods. The compounds (such as sulfur compounds) that interfere with the Karl Fischer reaction (interfering substances) and inflate the values for water by also reacting with iodine have been measured coulometrically. The measured water content of Reference Material (RM) 8506a Transformer Oil is 12.1+/-1.9 mg kg(-1) (plus an additional 6.2+/-0.9 mg kg(-1) of interfering substances). The measured water content of SRM 2722 Sweet Crude Oil, is 99+/-6 mg kg(-1) (plus an additional 5+/-2 mg kg(-1) of interfering substances). The measured water content of SRM 2721 Sour Crude Oil, is 134+/-18 mg kg(-1) plus an additional 807+/-43 mg kg(-1) of interfering substances. Interlaboratory studies conducted with these oil samples (using SRM 2890, water saturated 1-octanol, as a calibrant) are reported. Some of the possible sources of bias in these measurements were identified, These include: improperly calibrated instruments, inability to measure the calibrant accurately, Karl Fischer reagent selection, and volatilization of the interfering substances in SRM 2721.

  12. Applications of supercritical fluid extraction (SFE) of palm oil and oil from natural sources.

    PubMed

    Akanda, Mohammed Jahurul Haque; Sarker, Mohammed Zaidul Islam; Ferdosh, Sahena; Manap, Mohd Yazid Abdul; Ab Rahman, Nik Norulaini Nik; Ab Kadir, Mohd Omar

    2012-02-10

    Supercritical fluid extraction (SFE), which has received much interest in its use and further development for industrial applications, is a method that offers some advantages over conventional methods, especially for the palm oil industry. SC-CO₂ refers to supercritical fluid extraction (SFE) that uses carbon dioxide (CO₂) as a solvent which is a nontoxic, inexpensive, nonflammable, and nonpolluting supercritical fluid solvent for the extraction of natural products. Almost 100% oil can be extracted and it is regarded as safe, with organic solvent-free extracts having superior organoleptic profiles. The palm oil industry is one of the major industries in Malaysia that provides a major contribution to the national income. Malaysia is the second largest palm oil and palm kernel oil producer in the World. This paper reviews advances in applications of supercritical carbon dioxide (SC-CO₂) extraction of oils from natural sources, in particular palm oil, minor constituents in palm oil, producing fractionated, refined, bleached, and deodorized palm oil, palm kernel oil and purified fatty acid fractions commendable for downstream uses as in toiletries and confectionaries.

  13. 7 CFR 985.4 - Spearmint oil.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... oil. Spearmint oil, hereinafter referred to as oil, means essential oil extracted by distillation from... classes: Class 1: Oil extracted from the first cutting of Scotch Spearmint. Class 2: Oil extracted from the second cutting of Scotch Spearmint. Class 3: Oil extracted from Native Spearmint. Class 4: Oil...

  14. 7 CFR 985.4 - Spearmint oil.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... oil. Spearmint oil, hereinafter referred to as oil, means essential oil extracted by distillation from... classes: Class 1: Oil extracted from the first cutting of Scotch Spearmint. Class 2: Oil extracted from the second cutting of Scotch Spearmint. Class 3: Oil extracted from Native Spearmint. Class 4: Oil...

  15. 7 CFR 985.4 - Spearmint oil.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... oil. Spearmint oil, hereinafter referred to as oil, means essential oil extracted by distillation from... classes: Class 1: Oil extracted from the first cutting of Scotch Spearmint. Class 2: Oil extracted from the second cutting of Scotch Spearmint. Class 3: Oil extracted from Native Spearmint. Class 4: Oil...

  16. 7 CFR 985.4 - Spearmint oil.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... oil. Spearmint oil, hereinafter referred to as oil, means essential oil extracted by distillation from... classes: Class 1: Oil extracted from the first cutting of Scotch Spearmint. Class 2: Oil extracted from the second cutting of Scotch Spearmint. Class 3: Oil extracted from Native Spearmint. Class 4: Oil...

  17. The mechanism performance of improved oil pump with micro-structured vanes

    NASA Astrophysics Data System (ADS)

    Li, Ping; Xie, Jin; Qi, Dongtao; Li, Houbu

    2017-09-01

    The wear of oil pump vanes easily leads to the noise and vibration, even results the decrease of volume efficiency and total efficiency. In order to reduce the friction and improve the lubrication between the vane and the pump inner wall, the micro-machining of micro-structure on the oil pump vanes is proposed. First, the micro-V-grooves with the depth ranging from 500μm to 50μm were micro-grinding on the top of the vanes by a diamond grinding wheel. Secondly, the experiments were conducted to test the actual flow rate, the output power and the overall efficiency of the oil pump with and without the micro-groove vanes. Then, the computational fluid dynamics (CFD) method was adopted to simulate the pump internal flow field. Finally, the micro-flow field between the internal wall of the oil pump and the top of micro-grooved vanes was analyzed. The results shows that the pump overall efficiency increased as the decrease of micro-groove depth from 500 μm to 50μm and not be affected by the rotate speed and working frequency of the pump rotator. Especially the micro-groove with depth of 50μm, the actual flow rate, the output power and the overall efficiency reached to the maximum. From CFD simulation, the velocity of the micro-flow between the surfaces of the vane and inner wall was larger than the pump linear velocity when the microstructure depth is larger than 50μm, leading to an internal leakage. When the micro-groove depth is between10-50μm, the velocity of the micro-flow was less than the pump linear velocity and no internal leakage was found, but the oil film thickness is too small to be beneficial to lubrication according to the fluid dynamic characteristics. Thus, for the oil pump equipping with micro-grooved vane with the depth of 50 μm, the internal leakage not only is avoided but the lubrication efficiency is improved and the oil pump efficiency is also enhanced.

  18. Subcritical hydrothermal liquefaction of cattle manure to bio-oil: Effects of conversion parameters on bio-oil yield and characterization of bio-oil.

    PubMed

    Yin, Sudong; Dolan, Ryan; Harris, Matt; Tan, Zhongchao

    2010-05-01

    In this study, cattle manure was converted to bio-oil by subcritical hydrothermal liquefaction in the presence of NaOH. The effects of conversion temperature, process gas, initial conversion pressure, residence time and mass ratio of cattle manure to water on the bio-oil yield were studied. The bio-oil was characterized in terms of elemental composition, higher heating value, ultraviolet-visible (UV/Vis) spectroscopy, Fourier transform infrared spectroscopy (FTIR), gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS). Results showed that the bio-oil yield depended on the conversion temperature and the process gas. Higher initial conversion pressure, longer residence time and larger mass ratio of cattle manure to water, however, had negative impacts on the bio-oil yield. The higher heating value of bio-oil was 35.53MJ/kg on average. The major non-polar components of bio-oil were toluene, ethyl benzene and xylene, which are components of crude oil, gasoline and diesel. Copyright 2010 Elsevier Ltd. All rights reserved.

  19. Method to separate and recover oil and plastic from plastic contaminated with oil

    DOEpatents

    Smith, H.M.; Bohnert, G.W.; Olson, R.B.; Hand, T.E.

    1998-01-27

    The present invention provides a method to separate and recover oils and recyclable plastic from plastic contaminated with oil. The invention utilizes the different solubility of oil in a liquid or supercritical fluid as compared to a gas to effect separation of the oil from the plastic. 3 figs.

  20. Oil Spills

    MedlinePlus

    ... oil, assessing shoreline impact, and evaluating accepted cleanup technologies. Students and teachers can find a variety of oil spill-related educational resources in our Education section . For stories, news, and updates about current, notable, and historical ...