Identification of water-quality trends using sediment cores from Dillon Reservoir, Summit County, Colorado

USGS Publications Warehouse

Greve, Adrienne I.; Spahr, Norman E.; Van Metre, Peter C.; Wilson, Jennifer T.

2001-01-01

Since the construction of Dillon Reservoir, in Summit County, Colorado, in 1963, its drainage area has been the site of rapid urban development and the continued influence of historical mining. In an effort to assess changes in water quality within the drainage area, sediment cores were collected from Dillon Reservoir in 1997. The sediment cores were analyzed for pesticides, polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), and trace elements. Pesticides, PCBs, and PAHs were used to determine the effects of urban development, and trace elements were used to identify mining contributions. Water-quality and streambed-sediment samples, collected at the mouth of three streams that drain into Dillon Reservoir, were analyzed for trace elements. Of the 14 pesticides and 3 PCBs for which the sediment samples were analyzed, only 2 pesticides were detected. Low amounts of dichloro-diphenyldichloroethylene (DDE) and dichloro-diphenyldichloroethane (DDD), metabolites of dichlorodiphenyltrichloroethane (DDT), were found at core depths of 5 centimeters and below 15 centimeters in a core collected near the dam. The longest core, which was collected near the dam, spanned the entire sedimentation history of the reservoir. Concentrations of total combustion PAH and the ratio of fluoranthene to pyrene in the core sample decreased with core depth and increased over time. This relation is likely due to growth in residential and tourist populations in the region. Comparisons between core samples gathered in each arm of the reservoir showed the highest PAH concentrations were found in the Tenmile Creek arm, the only arm that has an urban area on its shores, the town of Frisco. All PAH concentrations, except the pyrene concentration in one segment in the core near the dam and acenaphthylene concentrations in the tops of three cores taken in the reservoir arms, were below Canadian interim freshwater sediment-quality guidelines. Concentrations of arsenic, cadmium, chromium, copper, lead, and zinc in sediment samples from Dillon Reservoir exceeded the Canadian interim freshwater sediment-quality guidelines. Copper, iron, lithium, nickel, scandium, titanium, and vanadium concentrations in sediment samples decreased over time. Other elements, while no trend was evident, displayed concentration spikes in the down-core profiles, indicating loads entering the reservoir may have been larger than they were in 1997. The highest concentrations of copper, lead, manganese, mercury, and zinc were detected during the late 1970's and early 1980's. Elevated concentrations of trace elements in sediment in Dillon Reservoir likely resulted from historical mining in the drainage area. The downward trend identified for copper, iron, lithium, nickel, scandium, titanium, and vanadium may be due in part to restoration efforts in mining-affected areas and a decrease in active mining in the Dillon Reservoir watershed. Although many trace-element core-sediment concentrations exceeded the Canadian probable effect level for freshwater lakes, under current limnological conditions, the high core-sediment concentrations do not adversely affect water quality in Dillon Reservoir. The trace-element concentrations in the reservoir water column meet the standards established by the Colorado Water Quality Control Commission. Although many trace-element core-sediment concentrations exceeded the Canadian probable effect level for freshwater lakes, under current limnological conditions, the high core-sediment concentrations do not adversely affect water quality in Dillon Reservoir. The trace-element concentrations in the reservoir water column meet the standards established by the Colorado Water Quality Control Commission.

Field screening of water quality, bottom sediment, and biota associated with irrigation drainage in and near Walker River Indian Reservation, Nevada 1994-95

USGS Publications Warehouse

Thodal, Carl E.; Tuttle, Peter L.

1996-01-01

A study was begun in 1994 to determine whether the quality of irrigation drainage from the Walker River Indian Reservation, Nevada, has caused or has potential to cause harmful effects on human health or on fish and wildlife, or may adversely affect the suitability of the Walker River for other beneficial uses. Samples of water, bottom sediment, and biota were collected during June-August 1994 (during a drought year) from sites upstream from and on the Walker River Indian Reservation for analyses of trace elements. Other analyses included physical characteristics, major dissolved constituents, selected species of water-soluble nitrogen and phosphorus, and selected pesticides in bottom sediment. Water samples were collected again from four sites on the Reservation in August 1995 (during a wetterthan- average year) to provide data for comparing extreme climatic conditions. Water samples collected from the Walker River Indian Reservation in 1994 equaled or exceeded the Nevada water-quality standard or level of concern for at least one of the following: water temperature, pH, dissolved solids, unionized ammonia, phosphate, arsenic, boron, chromium, lead, and molybdenum; in 1995, only a single sample from one site exceeded a Nevada water-quality standard for molybdenum. Levels of concern for trace elements in bottom sediment collected in 1994 were equaled or exceeded for arsenic, iron, manganese, and zinc. Concentrations of organochiorine pesticide residues in bottom sediment were below analytical reporting limits. Levels of concern for trace-elements in samples of biota were equaled or exceeded for arsenic, boron, copper, and mercury. Results of toxicity testing indicate that only water samples from Walker Lake caused a toxic response in test bacteria. Arsenic and boron concentrations in water, bottom sediment, and biological tissue exceeded levels of concern throughout the Walker River Basin, but most commonly in the lower Walker River Basin. Mercury also was elevated in several biological samples collected throughout the Basin, although concentrations in water and bottom sediment were below analytical reporting limits. Sources of arsenic, boron, and mercury in the Basin are uncertain, but ambient levels reported for a variety of sample matrices collected from western Nevada generally exceed ranges cited as natural background levels. Because these potentially toxic constituents exceeded concern levels in areas that do not directly receive irrigation drainage, concentrations measured in samples collected for this study may not necessarily be attributable to agricultural activities. Diversion of river water for irrigation may have greater effects on beneficial uses of water and on fish and wildlife than does drainage from agricultural areas on the Reservation. In 1994, agricultural water consumption precluded dilution of ground-water seepage to the river channel. This resulted in concentrations of potentially toxic solutes that exceeded levels of concern. Diversion of irrigation water also may have facilitated leaching of potentially toxic solutes from irrigated soil on the Reservation, but during this study all water applied for irrigation on the Reservation was either consumed by evapotranspiration or infiltrated to recharge shallow ground water. No irrigation drainage was found on the Reservation during this study. However, because 1994 samples of ground-water seepage to the Walker River channel exceeded at least six Nevada waterquality standards, water-quality problems may result should ground-water levels rise enough to cause ground-water discharge to the agricultural drain on the Reservation. Nevertheless, the potential for adverse effects from irrigation drainage on the Reservation is believed to be small because surface-water rights for the Walker River Indian Reservation amount to only 2 percent of total surface- water rights in the entire Walker River Basin.

Sediment Chemistry and Toxicity in Barnegat Bay, New Jersey: Pre- and Post- Hurricane Sandy, 2012-2013.

USGS Publications Warehouse

Romanok, Kristin M.; Szabo, Zoltan; Reilly, Timothy J.; Defne, Zafer; Ganju, Neil K.

2016-01-01

Hurricane Sandy made landfall in Barnegat Bay, October, 29, 2012, damaging shorelines and infrastructure. Estuarine sediment chemistry and toxicity were investigated before and after to evaluate potential environmental health impacts and to establish post-event baseline sediment-quality conditions. Trace element concentrations increased throughout Barnegat Bay up to two orders of magnitude, especially north of Barnegat Inlet, consistent with northward redistribution of silt. Loss of organic compounds, clay, and organic carbon is consistent with sediment winnowing and transport through the inlets and sediment transport modeling results. The number of sites exceeding sediment quality guidance levels for trace elements tripled post-Sandy. Sediment toxicity post-Sandy was mostly unaffected relative to pre-Sandy conditions, but at the site with the greatest relative increase for trace elements, survival rate of the test amphipod decreased (indicating degradation). This study would not have been possible without comprehensive baseline data enabling the evaluation of storm-derived changes in sediment quality.

Sediment chemistry and toxicity in Barnegat Bay, New Jersey: Pre- and post-Hurricane Sandy, 2012-13.

PubMed

Romanok, Kristin M; Szabo, Zoltan; Reilly, Timothy J; Defne, Zafer; Ganju, Neil K

2016-06-30

Hurricane Sandy made landfall in Barnegat Bay, October, 29, 2012, damaging shorelines and infrastructure. Estuarine sediment chemistry and toxicity were investigated before and after to evaluate potential environmental health impacts and to establish post-event baseline sediment-quality conditions. Trace element concentrations increased throughout Barnegat Bay up to two orders of magnitude, especially north of Barnegat Inlet, consistent with northward redistribution of silt. Loss of organic compounds, clay, and organic carbon is consistent with sediment winnowing and transport through the inlets and sediment transport modeling results. The number of sites exceeding sediment quality guidance levels for trace elements tripled post-Sandy. Sediment toxicity post-Sandy was mostly unaffected relative to pre-Sandy conditions, but at the site with the greatest relative increase for trace elements, survival rate of the test amphipod decreased (indicating degradation). This study would not have been possible without comprehensive baseline data enabling the evaluation of storm-derived changes in sediment quality. Published by Elsevier Ltd.

Quality of water and chemistry of bottom sediment in the Rillito Creek basin, Tucson, Arizona, 1992-93

USGS Publications Warehouse

Tadayon, Saeid

1995-01-01

Physical and chemical data were collected from four surface-water sites, six ground-water sites, and two bottom-sediment sites during 1992-93. Specific conductance, hardness, alkalinity, and dissolved- solids concentrations generally were higher in ground water than in surface water. The median concentrations of dissolved major ions, with the exception of potassium, were higher in ground water than in surface water. In surface water and ground water, calcium was the dominant cation, and bicarbonate was the dominant anion. Concentrations of dissolved nitrite and nitrite plus nitrate in surface water and ground water did not exceed the U.S. Environmental Protection Agency maximum contaminant levels of 1 and 10 milligrams per liter for drinking water, respectively. Ammonium plus organic nitrogen in bottom sediment was detected at the highest concentration of any nitrogen species. Median values for most of the dissolved trace elements in surface water and ground water were below the detection levels. Dissolved trace elements in surface water and ground water did not exceed the U.S. Environmental Protection Agency maximum contaminant levels for drinking water. Trace-element concentrations in bottom sediment were similar to trace-element concentrations reported for soils of the western conterminous United States. Several organochlorine pesticides and priority pollutants were detected in surface-water and bottom-sediment samples; however, they did not exceed water-quality standards. Pesticides or priority pollutants were not detected in ground-water samples.

Benthic invertebrates and quality of streambed sediments in the White River and selected tributaries in and near Indianapolis, Indiana, 1994-96

USGS Publications Warehouse

Voelker, David C.; Renn, Danny E.

2000-01-01

During this study, 369 benthic-invertebrate samples were collected at 21 sites and 33 streambed-sediment samples were collected at 14 sites to help develop and evaluate control strategies to mediate the impact of point and nonpoint sources of pollution on the White River and selected tributaries in and near Indianapolis, Indiana. Data analyses show that 124 taxa were identified and that most of the benthic invertebrates found belong to one of three taxa: the pollution-tolerant Diptera and the pollution-intolerant Ephemeroptera and Trichoptera. The Hilsenhoff Biotic Index, which was calculated from the number of arthropods and their tolerance to pollution, ranged from 4.4 (very good) to 9.4 (very poor) on the White River, and from 4.9 (good) to 9.1 (very poor) on the tributaries. The Ephemeroptera, Plecoptera, and Trichoptera (EPT) Richness Index, which was calculated from the number of taxa in pollution-intolerant species, ranged from 0 to 9 for the White River and from 0 to 9 for the tributaries. A high EPT Richness Index value reflects a great diversity of pollution-intolerant invertebrates at a site and generally indicates good water quality. A comparison of data collected during the 1994 through 1996 study to data collected during a 1981 through 1987 study indicates that the proportion of pollution-tolerant taxa increased in the immediate vicinity of Indianapolis. This increase may be an indicator that the water quality in the immediate vicinity of Indianapolis has declined since the earlier study. Comparison of the Hilsenhoff Biotic Index values, however, indicates there has been no change since the previous study. In the analysis of streambed sediments, small amounts of 12 metals were detected. Of those, only lead exceeded sediment-quality guidelines for the protection of aquatic life in three samples from two sites. Thirteen insecticides were detected in the streambed sediments, and of those only chlordane exceeded sediment-quality guidelines for the protection of aquatic life. Seventeen semivolatile organic compounds also were detected in streambed sediments at nine sites: four on the White River and five on the tributaries. Six of these compounds exceeded sedimentquality guidelines for the protection of aquatic life.

Do antiparasitic medicines used in aquaculture pose a risk to the Norwegian aquatic environment?

PubMed

Langford, Katherine H; Øxnevad, Sigurd; Schøyen, Merete; Thomas, Kevin V

2014-07-15

Aquaculture production is an important industry in many countries and there has been a growth in the use of medicines to ensure the health and cost effectiveness of the industry. This study focused on the inputs of sea lice medication to the marine environment. Diflubenzuron, teflubenzuron, emamectin benzoate, cypermethrin, and deltamethrin were measured in water, sediment, and biota samples in the vicinity of five aquaculture locations along the Norwegian coast. Deltamethrin and cypermethrin were not detected above the limits of detection in any samples. Diflubenzuron, teflubenzuron, and emamectin benzoate were detected, and the data was compared the UK Environmental Quality Standards. The concentrations of emamectin benzoate detected in sediments exceed the environmental quality standard (EQS) on 5 occasions in this study. The EQS for teflubenzuron in sediment was exceeded in 67% of the samples and exceeded for diflubenzuron in 40% of the water samples collected. A crude assessment of the concentrations detected in the shrimp collected from one location and the levels at which chronic effects are seen in shrimp would suggest that there is a potential risk to shrimp. It would also be reasonable to extrapolate this to any species that undergoes moulting during its life cycle.

Development and evaluation of sediment quality guidelines for Florida coastal waters

USGS Publications Warehouse

MacDonald, Donald D.; Carr, R. Scott; Calder, Fred D.; Long, Edward R.; Ingersoll, Christopher G.

1996-01-01

The weight-of-evidence approach to the development of sediment quality guidelines (SQGs) was modified to support the derivation of biological effects-based SQGs for Florida coastal waters. Numerical SQGs were derived for 34 substances, including nine trace metals, 13 individual polycyclic aromatic hydrocarbons (PAHs), three groups of PAHs, total polychlorinated biphenyls (PCBs), seven pesticides and one phthalate ester. For each substance, a threshold effects level (TEL) and a probable effects level (PEL) was calculated. These two values defined three ranges of chemical concentrations, including those that were (1) rarely, (2) occasionally or (3) frequently associated with adverse effects. The SQGs were then evaluated to determine their degree of agreement with other guidelines (an indicator of comparability) and the percent incidence of adverse effects within each concentration range (an indicator of reliability). The guidelines also were used to classify (using a dichotomous system: toxic, with one or more exceedances of the PELs or non-toxic, with no exceedances of the TELs) sediment samples collected from various locations in Florida and the Gulf of Mexico. The accuracy of these predictions was then evaluated using the results of the biological tests that were performed on the same sediment samples. The resultant SQGs were demonstrated to provide practical, reliable and predictive tools for assessing sediment quality in Florida and elsewhere in the southeastern portion of the United States.

Distribution and pollution, toxicity and risk assessment of heavy metals in sediments from urban and rural rivers of the Pearl River delta in southern China.

PubMed

Xiao, Rong; Bai, Junhong; Huang, Laibin; Zhang, Honggang; Cui, Baoshan; Liu, Xinhui

2013-12-01

Sediments were collected from the upper, middle and lower reaches of both urban and rural rivers in a typical urbanization zone of the Pearl River delta. Six heavy metals (Cd, Cr, Cu, Ni, Pb and Zn) were analyzed in all sediment samples, and their spatial distribution, pollution levels, toxicity and ecological risk levels were evaluated to compare the characteristics of heavy metal pollution between the two rivers. Our results indicated that the total contents of the six metals in all samples exceeded the soil background value in Guangdong province. Based on the soil quality thresholds of the China SEPA, Cd levels at all sites exceeded class III criteria, and other metals exhibited pollution levels exceeding class II or III criteria at both river sites. According to the sediment quality guidelines of the US EPA, all samples were moderately to heavily polluted by Cr, Cu, Ni, Pb and Zn. Compared to rural river sites, urban river sites exhibited heavier pollution. Almost all sediment samples from both rivers exhibited moderate to serious toxicity to the environment, with higher contributions from Cr and Ni. A "hot area" of heavy metal pollution being observed in the upper and middle reaches of the urban river area, whereas a "hot spot" was identified at a specific site in the middle reach of the rural river. Contrary metal distribution patterns were also observed along typical sediment profiles from urban and rural rivers. However, the potential ecological risk indices of rural river sediments in this study were equal to those of urban river sediments, implying that the ecological health issues of the rivers in the undeveloped rural area should also be addressed. Sediment organic matter and grain size might be important factors influencing the distribution profiles of these heavy metals.

Sediment-quality assessment of Franklin D. Roosevelt Lake and the upstream reach of the Columbia River, Washington, 1992

USGS Publications Warehouse

Bortleson, Gilbert Carl; Cox, S.E.; Munn, M.D.; Schumaker, R.J.; Block, E.K.

2001-01-01

Elevated concentrations of trace elements were found in bed sediment of Lake Roosevelt and the Columbia River, its principal source of inflow. Trace-element concentrations in whole water samples did not exceed criteria for freshwater organisms. Bed sediments of Lake Roosevelt were analyzed for organic compounds associated with wood-pulp waste. Dioxins and furans were found in suspended sediment and water of the Columbia River. Abundance and diversity of benthic invertebrate communities were analyzed.

Water Quality of Camp Creek, Costello Creek, and Other Selected Streams on the South Side of Denali National Park and Preserve, Alaska

USGS Publications Warehouse

Brabets, Timothy P.; Whitman, Matthew S.

2002-01-01

The Camp and Costello Creek watersheds are located on the south side of Denali National Park and Preserve. The Dunkle Mine, an abandoned coal mine, is located near the mouth of Camp Creek. Due to concern about runoff from the mine and its possible effects on the water quality and aquatic habitat of Camp Creek and its receiving stream, Costello Creek, these two streams were studied during the summer runoff months (June to September) in 1999 and 2000 as part of a cooperative study with the National Park Service. Since the south side of Denali National Park and Preserve is part of the U.S. Geological Survey?s National Water-Quality Assessment Cook Inlet Basin study unit, an additional part of this study included analysis of existing water-quality data at 23 sites located throughout the south side of Denali National Park and Preserve to compare with the water quality of Camp and Costello Creeks and to obtain a broader understanding of the water quality in this area of the Cook Inlet Basin. Analysis of water column, bed sediment, fish, invertebrate, and algae data indicate no effects on the water quality of Camp Creek from the Dunkle Mine. Although several organic compounds were found in the streambed of Camp Creek, all concentrations were below recommended levels for aquatic life and most of the concentrations were below the minimum reporting level of 50 ?g/kg. Trace element concentrations of arsenic, chromium, and nickel in the bed sediments of Camp Creek exceeded threshold effect concentrations (TEC), but concentrations of these trace elements were also exceeded in streambed sediments of Costello Creek above Camp Creek. Since the percent organic carbon in Camp Creek is relatively high, the toxicity quotient of 0.55 is only slightly above the threshold value of 0.5. Costello Creek has a relatively low organic carbon content and has a higher toxicity quotient of 1.19. Analysis of the water-quality data for other streams located in the south side of Denali National Park and Preserve indicate similarities to Camp Creek and Costello Creek. Most of the streams are calcium bicarbonate/calcium bicarbonate-sulfate type water with the exception of two streams that are calcium sulfate and magnesium sulfate type water. Trace element concentrations of arsenic, chromium, and nickel in the bed sediments of 9 streams exceeded the TEC or the probable effect concentration (PEC). Seven streams exceeded the threshold value of the toxicity quotient. Analysis of trace element concentrations in bed sediment and basin characteristics for 16 watersheds by cluster and discriminant analysis techniques indicated that the watersheds could be separated into two groups based on their basin characteristics.

Multivariate analysis for source identification of pollution in sediment of Linggi River, Malaysia.

PubMed

Elias, Md Suhaimi; Ibrahim, Shariff; Samuding, Kamarudin; Rahman, Shamsiah Ab; Wo, Yii Mei; Daung, Jeremy Andy Dominic

2018-03-29

Rapid socioeconomic development in the Linggi River Basin has contributed to the significant increase of pollution discharge into the Linggi River and its adjacent coastal areas. The toxic element contents and distributions in the sediment samples collected along the Linggi River were determined using neutron activation analysis (NAA) and inductively coupled plasma-mass spectrometry (ICP-MS) techniques. The measured mean concentration of As, Cd, Pb, Sb, U, Th and Zn is relatively higher compared to the continental crust value of the respective element. Most of the elements (As, Cr, Fe, Pb, Sb and Zn) exceeded the freshwater sediment quality guideline-threshold effect concentration (FSQG-TEC) value. Downstream stations of the Linggi River showed that As concentrations in sediment exceeded the freshwater sediment quality guideline-probable effect concentration (FSQG-PEC) value. This indicates that the concentration of As will give an adverse effect to the growth of sediment-dwelling organisms. Generally, the Linggi River sediment can be categorised as unpolluted to strongly polluted and unpolluted to strongly to extremely polluted. The correlation matrix of metal-metal relationship, principle component analysis (PCA) and cluster analysis (CA) indicates that the pollution sources of Cu, Ni, Zn, Cd and Pb in sediments of the Linggi River originated from the industry of electronics and electroplating. Elements of As, Cr, Sb and Fe mainly originated from motor-vehicle workshops and metal work, whilst U and Th originated from natural processes such as terrestrial runoff and land erosion.

Trace-metal concentrations in sediment and water and health of aquatic macroinvertebrate communities of streams near Park City, Summit County, Utah

USGS Publications Warehouse

Giddings, Elis M.P.; Hornberger, Michelle I.; Hadley, Heidi K.

2001-01-01

The spatial distribution of metals in streambed sediment and surface water of Silver Creek, McLeod Creek, Kimball Creek, Spring Creek, and part of the Weber River, near Park City, Utah, was examined. From the mid-1800s through the 1970s, this region was extensively mined for silver and lead ores. Although some remediation has occurred, residual deposits of tailing wastes remain in place along large sections of Silver Creek. These tailings are the most likely source of metals to this system. Bed sediment samples were collected in 1998, 1999, and 2000 and analyzed using two extraction techniques: a total extraction that completely dissolves all forms of metals in minerals and trace elements associated with the sediment; and a weak-acid extraction that extracts the metals and trace elements that are only weakly adsorbed onto the sediment surface. This latter method is used to determine the more biologically relevant fraction of metal complexed onto the sediment. Water samples were collected in March and August 2000 and were analyzed for total and dissolved trace metals.Concentrations of silver, cadmium, copper, lead, mercury, and zinc in the streambed sediment of Silver Creek greatly exceeded background concentrations. These metals also exceeded established aquatic life criteria at most sites. In the Weber River, downstream of the confluence with Silver Creek, concentrations of cadmium, lead, zinc, and total mercury in streambed sediment also exceeded aquatic life guidelines, however, concentrations of metals in streambed sediment of McLeod and Kimball Creeks were lower than Silver Creek. Water-column concentrations of zinc, total mercury, and methylmercury in Silver Creek were high relative to unimpacted sites, and exceeded water quality criteria for the protection of aquatic organisms. Qualitative measurements of the macroinvertebrate community in Silver Creek were compared to the spatial distribution of metals in streambed sediment. The data indicate that impairment related to metal concentration exists in Silver Creek.

Quality of water and sediment in streams affected by historical mining, and quality of Mine Tailings, in the Rio Grande/Rio Bravo Basin, Big Bend Area of the United States and Mexico, August 2002

USGS Publications Warehouse

Lambert, Rebecca B.; Kolbe, Christine M.; Belzer, Wayne

2008-01-01

The U.S. Geological Survey, in cooperation with the International Boundary and Water Commission - U.S. and Mexican Sections, the National Park Service, the Texas Commission on Environmental Quality, the Secretaria de Medio Ambiente y Recursos Naturales in Mexico, the Area de Proteccion de Flora y Fauna Canon de Santa Elena in Mexico, and the Area de Proteccion de Flora y Fauna Maderas del Carmen in Mexico, collected samples of stream water, streambed sediment, and mine tailings during August 2002 for a study to determine whether trace elements from abandoned mines in the area in and around Big Bend National Park have affected the water and sediment quality in the Rio Grande/Rio Bravo Basin of the United States and Mexico. Samples were collected from eight sites on the main stem of the Rio Grande/Rio Bravo, four Rio Grande/Rio Bravo tributary sites downstream from abandoned mines or mine-tailing sites, and 11 mine-tailing sites. Mines in the area were operated to produce fluorite, germanium, iron, lead, mercury, silver, and zinc during the late 1800s through at least the late 1970s. Moderate (relatively neutral) pHs in stream-water samples collected at the 12 Rio Grande/Rio Bravo main-stem and tributary sites indicate that water is well mixed, diluted, and buffered with respect to the solubility of trace elements. The highest sulfate concentrations were in water samples from tributaries draining the Terlingua mining district. Only the sample from the Rough Run Draw site exceeded the Texas Surface Water Quality Standards general-use protection criterion for sulfate. All chloride and dissolved solids concentrations in water samples were less than the general-use protection criteria. Aluminum, copper, mercury, nickel, selenium, and zinc were detected in all water samples for which each element was analyzed. Cadmium, chromium, and lead were detected in samples less frequently, and silver was not detected in any of the samples. None of the sample concentrations of aluminum, cadmium, chromium, nickel, selenium, and zinc exceeded the Texas Surface Water Quality Standards criteria for aquatic life-use protection or human health. The only trace elements detected in the water samples at concentrations exceeding the Texas Surface Water Quality Standards criterion for human health (fish consumption use) was lead at one site and mercury at 10 of 12 sites. Relatively high mercury concentrations distributed throughout the area might indicate sources of mercury in addition to abandoned mining areas. Streambed-sediment samples were collected from 12 sites and analyzed for 44 major and trace elements. In general, the trace elements detected in streambed-sediment samples were low in concentration, interpreted as consistent with background concentrations. Concentrations at two sites, however, were elevated compared to Texas Commission on Environmental Quality criteria. Concentrations of antimony, arsenic, cadmium, lead, silver, and zinc in the sample from San Carlos Creek downstream from La Esperanza (San Carlos) Mine exceeded the Texas Commission on Environmental Quality screening levels for sediment. The sample from Rough Run Draw, downstream from the Study Butte Mine, also showed elevated concentrations of arsenic, cadmium, and lead, but these concentrations were much lower than those in the San Carlos Creek sample and did not exceed screening levels. Elevated concentrations of multiple trace elements in streambed-sediment samples from San Carlos Creek and Rough Run Draw indicate that San Carlos Creek, and probably Rough Run Draw, have been adversely affected by mining activities. Fourteen mine-tailing samples from 11 mines were analyzed for 25 major and trace elements. All trace elements except selenium and thallium were detected in one or more samples. The highest lead concentrations were detected in tailings samples from the Boquillas, Puerto Rico, La Esperanza (San Carlos), and Tres Marias Mines, as might be expected because the tailings ar

Heavy metal in sediments of Ziya River in northern China: distribution, potential risks, and source apportionment.

PubMed

Zhu, Xiaolei; Shan, Baoqing; Tang, Wenzhong

2016-12-01

The concentration partitioning between the sediment particle and the interstitial water phase plays an important role in controlling the toxicity of heavy metals in aquatic systems. The aim of this study was to assess the sediment quality in a polluted area of the Ziya River, Northern China. The contamination potential and bioavailability of six metals were determined from the concentrations of total metals and the bioavailable fractions. The results showed that the concentrations of Cr, Cu, Ni, Zn, and Pb exceeded the probable effect concentration at several sites. The high geoaccumulation indices showed that the sediments were seriously contaminated by Cd. The ratio of acid-volatile sulfide (AVS) to simultaneously extracted metal (SEM) was higher than 1, which indicated that the availability of metals in sediments was low. The risk assessment of interstitial waters confirmed that there was little chance of release of metals associated with acid-volatile sulfide into the water column. Values of the interstitial water criteria toxicity unit indicated that none of the concentrations of the studied metals exceeded the corresponding water quality thresholds of the US Environmental Protection Agency. Positive matrix factorization showed that the major sources of metals were related to anthropogenic activities. Further, if assessments are based on total heavy metal concentrations, the toxicity of heavy metals in sediment may be overestimated.

Trends in hydrophobic organic contaminants in urban and reference lake sediments across the United States, 1970-2001

USGS Publications Warehouse

Van Metre, P.C.; Mahler, B.J.

2005-01-01

A shift in national policy toward stronger environmental protection began in the United States in about 1970. Conversely, urban land use, population, energy consumption, and vehicle use have increased greatly since then. To assess the effects of these changes on water quality, the U.S. Geological Survey used sediment cores to reconstruct water-quality histories for38 urban and reference lakes across the United States. Cores were age-dated, and concentration profiles of polycyclic aromatic hydrocarbons (PAHs) and chlorinated hydrocarbons were tested statistically. Significant trends in total DDT, p,p???-DDE, and total PCBs were all downward. Trends in chlordane were split evenly between upward and downward, and trends in PAHs were mostly upward. Significant trends did not occur in about one-half of cases tested. Concentrations of p,p???-DDE, p,p???-DDD, and PCBs were about one-half as likely to exceed the probable effect concentration (PEC), a sediment quality guideline, in sediments deposited in the 1990s as in 1965-1975, whereas PAHs were twice as likely to exceed the PEC in the more recently deposited sediments. Concentrations of all contaminants evaluated correlated strongly with urban land use. Upward trends in PAH concentrations, the strong association of PAH with urban settings, and rapid urbanization occurring in the United States suggest that PAHs could surpass chlorinated hydrocarbons in the threat they pose to aquatic biota in urban streams and lakes.

Water-quality assessment of the upper Illinois River Basin in Illinois, Indiana, and Wisconsin; major and trace elements in water, sediment, and biota, 1978-90

USGS Publications Warehouse

Fitzpatrick, F.A.; Scudder, B.C.; Crawford, J.K.; Schmidt, A.R.; Sieverling, J.B.

1995-01-01

The distribution of 22 major and trace elements was examined in water, sediment, and biota in the upper Illinois River Basin in Illinois, Indiana, and Wisconsin as part of a pilot National Water-Quality Assessment project done by the U.S. Geological Survey from 1987 through 1990. The 22 elements are aluminum, antimony, arsenic, barium, beryllium, boron, cadmium, chromium, cobalt, copper, iron, lead, manganese, mercury, molybdenum, nickel, phosphorus, selenium, silver, strontium, vanadium, and zinc. Concentrations of U.S. Environmental Protection Agency (USEPA) priority pollutants among the 22 elements were elevated in the Chicago area in all three aquatic components (water, sediment, and biota). Further, some of the priority pollutants also were found at elevated concentrations in biota in agricultural areas in the basin. Cadmium, chromium, copper, iron, lead, mercury, silver, and zinc concentrations in water exceeded USEPA acute or chronic water-quality criteria at several sites in the Chicago area. Correlations among concentra- tions of elements in water, sediment, and biota were found, but the correlation analysis was hindered by the large proportion of observations less than the minimum reporting level in water. Those sites where water-quality criteria were sometimes exceeded were not always the same sites where concentrations in biota were the largest. This relation indicates that accumulation of these pollutants in biota is confounded by complex geochemical and biological processes that differ throughout the upper Illinois River Basin.

Areal distribution and concentrations of contaminants of concern in surficial streambed and lakebed sediments, Lake Erie-Lake Saint Clair Drainages, 1990-97

USGS Publications Warehouse

Rheaume, S.J.; Button, D.T.; Myers, Donna N.; Hubbell, D.L.

2001-01-01

Concerns about elevated concentrations of contaminants such as polychlorinated biphenyls and mercury in aquatic bed sediments throughout the Great Lakes Basin have resulted in a need for better understanding of the scope and severity of the problem. Various organochlorine pesticides, polychlorinated biphenyls, trace metals, and polycyclic aromatic hydrocarbons are a concern because of their ability to persist and accumulate in aquatic sediments and their association with adverse aquatic biological effects. The areal distribution and concentrations in surficial bed sediments of 20 contaminants of concern with established bed-sediment-toxicity guidelines were examined in relation to their potential effects on freshwater aquatic biota. Contaminants at more than 800 sampling locations are characterized in this report. Surficial bed-sediment-quality data collected from 1990 to 1997 in the Lake Erie?Lake Saint Clair Drainages were evaluated to reflect recent conditions. In descending order, concentrations of total polycyclic aromatic hydrocarbons, phenanthrene, total polychlorinated biphenyls, chrysene, benz[a]anthracene, benzo[a]pyrene, cadmium, lead, zinc, arsenic, and mercury were the contaminants that most commonly exceeded levels associated with probable adverse effects on aquatic benthic organisms. The highest concentrations of most of these contaminants in aquatic bed sediments are confined to the 12 specific geographic Areas of Concern identified in the 1987 Revisions to the Great Lakes Water Quality Agreement of 1972. An exception is arsenic, which was detected at concentrations exceeding threshold effect levels at many locations outside Areas of Concern.

An evaluation of contaminated estuarine sites using sediment quality guidelines and ecological assessment methodologies.

PubMed

Fulton, M; Key, P; Wirth, E; Leight, A K; Daugomah, J; Bearden, D; Sivertsen, S; Scott, G

2006-10-01

Toxic contaminants may enter estuarine ecosystems through a variety of pathways. When sediment contaminant levels become sufficiently high, they may impact resident biota. One approach to predict sediment-associated toxicity in estuarine ecosystems involves the use of sediment quality guidelines (ERMs, ERLs) and site-specific contaminant chemistry while a second approach utilizes site-specific ecological sampling to assess impacts at the population or community level. The goal of this study was to utilize an integrated approach including chemical contaminant analysis, sediment quality guidelines and grass shrimp population monitoring to evaluate the impact of contaminants from industrial sources. Three impacted sites and one reference site were selected for study. Grass shrimp populations were sampled using a push-netting approach. Sediment samples were collected at each site and analyzed for metals, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and pesticides. Contaminant levels were then compared to sediment quality guidelines. In general, grass shrimp population densities at the sites decreased as the ERM quotients increased. Grass shrimp densities were significantly reduced at the impacted site that had an ERM exceedance for chromium and the highest Mean ERM quotient. Regression analysis indicated that sediment chromium concentrations were negatively correlated with grass shrimp density. Grass shrimp size was reduced at two sites with intermediate levels of contamination. These findings support the use of both sediment quality guidelines and site-specific population monitoring to evaluate the impacts of sediment-associated contaminants in estuarine systems.

Organotins and new antifouling biocides in water and sediments from three Korean Special Management Sea Areas following ten years of tributyltin regulation: Contamination profiles and risk assessment.

PubMed

Lam, Nguyen Hoang; Jeong, Hui-Ho; Kang, Su-Dong; Kim, Dae-Jin; Ju, Mi-Jo; Horiguchi, Toshihiro; Cho, Hyeon-Seo

2017-08-15

A simultaneous monitoring study on organotins (butyltins and phenyltins) and most frequently used alternative antifouling biocides (Irgarol 1051, Diuron, Sea-Nine 211 and M1) in water and sediments (n=44) collected from three Special Management Sea Areas operated by Korean government. The lower concentration of butyltins (BTs) than that of new antifouling biocides (NEW) was found in water but the significant greater concentration of BTs than that of NEW was still found in sediments. The tributyltin (TBT) levels in water exceeded the chronic criterion to protect seawater aquatic life at several sites. Even ten years after the ban of the use of TBT-based antifouling paint, the concentrations of TBT, Diuron and Irgarol 1051 in sediments from shipyards exceeded global sediment quality guidelines and potentially poses adverse risks on marine organisms and extremely high concentration of TBT up to 2304ng/g was found for a sediment collected at a shipyard. Copyright © 2017 Elsevier Ltd. All rights reserved.

A sediment resuspension and water quality model of Lake Okeechobee

USGS Publications Warehouse

James, R.T.; Martin, J.; Wool, T.; Wang, P.-F.

1997-01-01

The influence of sediment resuspension on the water quality of shallow lakes is well documented. However, a search of the literature reveals no deterministic mass-balance eutrophication models that explicitly include resuspension. We modified the Lake Okeeehobee water quality model - which uses the Water Analysis Simulation Package (WASP) to simulate algal dynamics and phosphorus, nitrogen, and oxygen cycles - to include inorganic suspended solids and algorithms that: (1) define changes in depth with changes in volume; (2) compute sediment resuspension based on bottom shear stress; (3) compute partition coefficients for ammonia and ortho-phosphorus to solids; and (4) relate light attenuation to solids concentrations. The model calibration and validation were successful with the exception of dissolved inorganic nitrogen species which did not correspond well to observed data in the validation phase. This could be attributed to an inaccurate formulation of algal nitrogen preference and/or the absence of nitrogen fixation in the model. The model correctly predicted that the lake is lightlimited from resuspended solids, and algae are primarily nitrogen limited. The model simulation suggested that biological fluxes greatly exceed external loads of dissolved nutrients; and sedimentwater interactions of organic nitrogen and phosphorus far exceed external loads. A sensitivity analysis demonstrated that parameters affecting resuspension, settling, sediment nutrient and solids concentrations, mineralization, algal productivity, and algal stoichiometry are factors requiring further study to improve our understanding of the Lake Okeechobee ecosystem.

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Dolores Project area, southwestern Colorado and southeastern Utah, 1990-91

USGS Publications Warehouse

Butler, D.L.; Krueger, R.P.; Osmundson, B.C.; Jensen, E.G.

1995-01-01

Water, bottom-sediment, and biota samples were collected in 1990-91 to identify water-quality problems associated with irrigation drainage in the Dolores Project area. Concentrations of cadmium, mercury, and selenium in some water samples exceeded aquatic-life criteria. Selenium was associated with irrigaton drainage from the Dolores Project, but other trace elements may be transported into the area in the irrigation water supply. Selenium concentrations exceeded the chronic aquatic-life criterion in water samples from lower McElmo Creek and Navajo Wash, which drain the Montezuma Valley, from newly irrigated areas, and from the Mancos River. The maximum selenium con- centration in water was 88 micrograms per liter from Navajo Wash. Concentrations of herbicides in water were less than concentrations harmful to aquatic life. Selenium concentrations in four bottom-sediment samples exceeded the baseline concentrations for soils in the Western United States. The largest selenium concentrations in biota were in samples from Navajo Wash, from newly irrigated areas north of the Montezuma Valley, and from the Mancos River basin. Selenium concentrations in aquatic-invertebrate samples from the newly irrigated areas exceeded a guideline for food items consumed by fish and wildlife. Selenium concen- trations in whole-body suckers were larger in the San Juan River downstream from the Dolores Project than upstream from the project at Four Corners. Selenium concentrations in fathead minnow samples from two sites were at adverse-effect levels. Mercury concentrations in warm-water game fish in reservoirs in the study area may be of concern to human health. Some concentrations of other trace elements exceeded background concentrations, but the concentrations were not toxicologically significant or the toxicologic significance is not known.

Water and sediment quality assessment in the Colastiné-Corralito stream system (Santa Fe, Argentina): impact of industry and agriculture on aquatic ecosystems.

PubMed

Regaldo, Luciana; Gutierrez, María F; Reno, Ulises; Fernández, Viviana; Gervasio, Susana; Repetti, María R; Gagneten, Ana M

2018-03-01

The present study focuses on the evaluation of metal (chromium, copper, and lead), arsenic, and pesticide (atrazine and endosulfan) contamination in freshwater streams of one of the most important agricultural and industrial areas of central-eastern Argentina, which has not been reported earlier. The environmental fate of inorganic microcontaminants and pesticides was assessed. Samples were collected monthly for a year. Pesticide concentrations were measured in water; metal and arsenic concentrations were measured in water and sediments, and physicochemical variables were analyzed. In most cases, metals and arsenic in water exceeded the established guideline levels for the protection of aquatic biota: 98 and 56.25% of the samples showed higher levels of Cr and Pb, while 81.25 and 85% of the samples presented higher values for Cu and As, respectively. Cr, Pb, Cu, and As exceeded 181.5 times, 41.6 times, 57.5 times, and 12.9 times, respectively, the guideline level values. In sediment samples, permitted levels were also surpassed by 40% for Pb, 15% for As, 4% for Cu, and 2% for Cr. Geoaccumulation Index (Igeo) demonstrated that most of the sediment samples were highly polluted by Cr and Cu and very seriously polluted by Pb, which indicates progressive deterioration of the sediment quality. Atrazine never exceeded them, but 27% of the 48 water samples contained total endosulfan that surpassed the guidelines. The findings of this study suggest risk to the freshwater biota over prolong periods and possible risk to humans if such type of contaminated water is employed for recreation or human use. Improper disposal of industrial effluents and agricultural runoffs need to be controlled, and proper treatment should be done before disposal to avoid further deterioration of the aquifers of this area.

Water-quality assessment of part of the Upper Mississippi River Basin, Minnesota and Wisconsin: Organochlorine compounds in streambed sediments and fish tissues, 1995-97

USGS Publications Warehouse

McNellis, R.P.; Fallon, J.D.; Lee, K.E.

2001-01-01

Streambed sediments and fish tissues were collected in part of the Upper Mississippi River Basin to assess the presence and distribution of organochlorine compounds (OCs) including PCBs. A total of 13 OCs were detected among 14 of 27 streambed sediment sampling locations. In fish tissues analyzed, 9 OCs were detected among 17 of 24 sites sampled. Eight OCs were detected in both fish and streambed sediment samples, they were: cis-chlordane, o,p'-DDD; p,p'-DDD; p,p'-DDE; p,p'-DDT; hexachlorobenzene; transnonachlor; and PCBs. The most frequently detected OCs were: p,p'-DDE; and p,p'-DDD in streambed sediment and p,p'-DDE and PCBs in fish tissues. No OCs were detected in streambed sediment at agricultural sites; however, the agricultural sites had 17 detections of OCs in fish tissue. Urban streams had concentrations of total DDT and metabolites in streambed sediment that exceed guidelines for classification of sites with high probabilities of adverse effects to aquatic organisms. Total DDT was the only OC within an urban land use that exceeded guidelines for piscivorous wildlife.

Recovery of ostracod with known ages in differently textured sediments and comparison of toxicity of heavily contaminated sediments with ostracod Heterocypris incongruens and amphipod Hyalella azteca

NASA Astrophysics Data System (ADS)

Stepanova, N. Yu; Nikitin, O. V.; Latypova, V. Z.; Vybornova, I. B.; Galieva, G. S.; Okunev, R. V.

2018-01-01

The recovery of 1-, 4-, 6,-, and 8-d-old ostracods (Heterocypris incongruens) from sediments with different texture has been evaluated. The recovery of ostracods at all ages has been in agreement with the acceptability criterion of 80% of survival for sediment tests. The recovery of ostracods has turned out to be equal to or more than 80% for sand and silt sediments, respectively. The comparison of survival rates between ostracods and amphipods has shown good convergence in the tests of heavily contaminated sediments (R2=0.75, p<0.05). The sediment quality criteria (TEC) have been exceeded mostly for total petroleum hydrocarbons (100% samples), Cr (100%), Ni (87%), Cu (87%), Pb (47%), and Cd (53%). The content of acid volatile sulfides (AVS) has been significantly higher than that of simultaneously extracted metals (SEM). The obtained results have indicated that, metals (Cu, Zn, Cd, Ni, and Pb) are non-bioavailable. Only one sample has exceeded TEC for PAHs (dibenz[a,h]anthracene). It was observed that, no significant correlation between the effect of toxicity and the chemical content.

Trace elements and organic compounds in bed sediment from selected streams in southern Louisiana, 1998

USGS Publications Warehouse

Skrobialowski, Stanley C.

2002-01-01

Bed-sediment samples from 21 selected streams in southern Louisiana were collected and analyzed for the presence of trace elements and organic compounds during 1998 as part of the U.S. Geological Survey National Water-Quality Assessment Program. Concentrations of selected trace elements and organic compounds were compared on the basis of sediment-quality criteria, land use, and grain size; concentrations of selected trace elements also were compared with concentrations from previous studies. Concentrations of seven selected trace elements and 21 organic compounds were evaluated with sediment-quality criteria established by the Canadian Council of Ministers of the Environment. Concentrations of selected trace elements and organic compounds were highest at sites draining urban and agricultural areas and may result from cumulative effects of relatively high percentages of fine-grained material, iron, and organic material. Concentrations exceeding sediment-quality criteria for the protection of aquatic life occurred most frequently at Bayou Grosse Tete at Rosedale and Bayou Lafourche below weir at Thibodaux. Exceedance of Interim Sediment Quality Guidelines occurred most frequently for arsenic and chromium. Trace-element concentrations in fine-grained samples were compared with concentrations in bulk samples and were determined to be significantly different, and concentrations were generally higher in finegrained sediment. Shapiro-Wilk, paired t-test, and Wilcoxon rank sum statistical procedures, with an alpha of 0.05, were used to compare concentrations of 21 trace elements, total organic carbon, and total carbon in finegrained and bulk sediment samples for 19 sites. Significant differences were determined between fine-grained and bulk sediment samples for aluminum, barium, beryllium, chromium, copper, iron, lithium, nickel, phosphorus, selenium, titanium, and zinc concentrations. Of 133 paired concentrations, 69 percent were greater in fine-grained samples, and 23 percent were greater in bulk samples. Comparisons with data from previous studies indicate increases by more than 20 percent in concentrations of antimony at Bayou Lafourche below weir at Thibodaux, arsenic and chromium at Tickfaw River at Liverpool, lead at Bayou Lafourche below weir at Thibodaux, and zinc at Bayou Lafourche below weir at Thibodaux and Vermilion River at Perry. Historic comparisons also indicate decreases by more than 20 percent in concentrations of chromium at Bayou des Cannes near Eunice and mercury at Mermentau River at Mermentau.

Water quality and bed sediment quality in the Albemarle Sound, North Carolina, 2012–14

USGS Publications Warehouse

Moorman, Michelle C.; Fitzgerald, Sharon A.; Gurley, Laura N.; Rhoni-Aref, Ahmed; Loftin, Keith A.

2017-01-23

The Albemarle Sound region was selected in 2012 as one of two demonstration sites in the Nation to test and improve the design of the National Water Quality Monitoring Council’s National Monitoring Network (NMN) for U.S. Coastal Waters and Tributaries. The goal of the NMN for U.S. Coastal Waters and Tributaries is to provide information about the health of our oceans, coastal ecosystems, and inland influences on coastal waters for improved resource management. The NMN is an integrated, multidisciplinary, and multi-organizational program using multiple sources of data and information to augment current monitoring programs.This report presents and summarizes selected water-quality and bed sediment-quality data collected as part of the demonstration project conducted in two phases. The first phase was an occurrence and distribution study to assess nutrients, metals, pesticides, cyanotoxins, and phytoplankton communities in the Albemarle Sound during the summer of 2012 at 34 sites in Albemarle Sound, nearby sounds, and various tributaries. The second phase consisted of monthly sampling over a year (March 2013 through February 2014) to assess seasonality in a more limited set of constituents including nutrients, cyanotoxins, and phytoplankton communities at a subset (eight) of the sites sampled in the first phase. During the summer of 2012, few constituent concentrations exceeded published water-quality thresholds; however, elevated levels of chlorophyll a and pH were observed in the northern embayments and in Currituck Sound. Chlorophyll a, and metals (copper, iron, and zinc) were detected above a water-quality threshold. The World Health Organization provisional guideline based on cyanobacterial density for high recreational risk was exceeded in approximately 50 percent of water samples collected during the summer of 2012. Cyanobacteria capable of producing toxins were present, but only low levels of cyanotoxins below human health benchmarks were detected. Finally, 12 metals in surficial bed sediments were detected at levels above a published sediment-quality threshold. These metals included chromium, mercury, copper, lead, arsenic, nickel, and cadmium. Sites with several metal concentrations above the respective thresholds had relatively high concentrations of organic carbon or fine sediment (silt plus clay), or both and were predominantly located in the western and northwestern parts of the Albemarle Sound.Results from the second phase were generally similar to those of the first in that relatively few constituents exceeded a water-quality threshold, both pH and chlorophyll a were detected above the respective water-quality thresholds, and many of these elevated concentrations occurred in the northern embayments and in Currituck Sound. In contrast to the results from phase one, the cyanotoxin, microcystin was detected at more than 10 times the water-quality threshold during a phytoplankton bloom on the Chowan River at Mount Gould, North Carolina in August of 2013. This was the only cyanotoxin concentration measured during the entire study that exceeded a respective water-quality threshold.The information presented in this report can be used to improve understanding of water-quality conditions in the Albemarle Sound, particularly when evaluating causal and response variables that are indicators of eutrophication. In particular, this information can be used by State agencies to help develop water-quality criteria for nutrients, and to understand factors like cyanotoxins that may affect fisheries and recreation in the Albemarle Sound region.

Assessment of heavy metal pollution risks in Yonki Reservoir environmental matrices affected by gold mining activity.

PubMed

Kapia, Samuel; Rao, B K Rajashekhar; Sakulas, Harry

2016-10-01

This study reports the heavy metal (Hg, Cd, Cr, Cu, and Pb) contamination risks to and safety of two species of fresh water fish (tilapia, Oreochromis mossambicus and carp, Cyprinus carpio) that are farmed in the Yonki Reservoir in the Eastern Highlands of Papua New Guinea (PNG). The upper reaches of the reservoir are affected by alluvial and large-scale gold mining activities. We also assessed heavy metal levels in the surface waters and sediments and in selected aquatic plant species from the reservoir and streams that intersect the gold mining areas. The water quality was acceptable, except for the Cr concentration, which exceeded the World Health Organization (WHO) standard for water contamination. The sediments were contaminated with Cd and Cu in most of the sampling stations along the upstream waters and the reservoir. The Cd concentration in the sediments exceeded the US Environmental Protection Agency's Sediment Quality Guideline (SQG) values, and the geoaccumulation index (Igeo) values indicated heavy to extreme pollution. In addition, the Cd, Cu, and Pb concentrations in aquatic plants exceeded the WHO guidelines for these contaminants. Between the fish species, tilapia accumulated significantly higher (P < 0.05) Cu in their organ tissues than carp, confirming the bioaccumulation of some metals in the aquatic fauna. The edible muscles of the fish specimens had metal concentrations below the maximum permissible levels established by statutory guidelines. In addition, a human health risk assessment, performed using the estimated weekly intake (EWI) values, indicated that farmed fish from the Yonki Reservoir are safe for human consumption.

Estuarine water-quality and sediment data, and surface-water and ground-water-quality data, Naval Submarine Base Kings Bay, Camden County, Georgia, January 1999

USGS Publications Warehouse

Leeth, David C.; Holloway, Owen G.

2000-01-01

In January 1999, the U.S. Geological Survey collected estuarine-water, estuarine-sediment, surface-water, and ground-water quality samples in the vicinity of Naval Submarine Base Kings Bay, Camden County, Georgia. Data from these samples are used by the U.S. Navy to monitor the impact of submarine base activities on local water resources. Estuarine water and sediment data were collected from five sites on the Crooked River, Kings Bay, and Cumberland Sound. Surface-water data were collected from seven streams that discharge from Naval Submarine Base, Kings Bay. Ground-water data were collected from six ground-water monitoring wells completed in the water-table zone of the surficial aquifer at Naval Submarine Base Kings Bay. Samples were analyzed for nutrients, total and dissolved trace metals, total and dissolved organic carbon, oil and grease, total organic halogens, biological and chemical oxygen demand, and total and fecal coliform. Trace metals in ground and surface waters did not exceed U.S. Environmental Protection Agency Drinking Water Standards; and trace metals in surface water also did not exceed U.S. Environmental Protection Agency Surface Water Standards. These trace metals included arsenic, barium, cadmium, chromium, copper, lead, mercury, selenium, silver, tin, and zinc. Barium was detected in relatively high concentrations in ground water (concentrations ranged from 18 to 264 micrograms per liter). Two estuarine water samples exceeded the Georgia Department of Natural Resources, Environmental Protection Division standards for copper (concentrations of 6.2 and 3.0 micrograms per liter).

Spatial distribution, enrichment, and source of environmentally important elements in Batticaloa lagoon, Sri Lanka.

PubMed

Adikaram, Madurya; Pitawala, Amarasooriya; Ishiga, Hiroaki; Jayawardana, Daham

2017-01-01

The present paper is the first documentation of distribution and contamination status of environmentally important elements of superficial sediments in the Batticaloa lagoon that is connected to the largest bay of the world. Surface sediment samples were collected from 34 sites covering all over the lagoon. Concentrations of elements such as As, Cr, Cu, Fe, Nb, Ni, Pb, Sc, Sr, Th, V, Y, Zn, and Zr were measured by X-ray florescence analysis. Geochemically, the lagoon has three different zones that were influenced mainly by fresh water sources, marine fronts, and intermediate mixing zones. The marine sediment quality standards indicate that Zr and Th values are exceeded throughout the lagoon. According to the freshwater sediment quality standards, Cr levels of all sampling sites exceed the threshold effect level (TEL) and 17 % of them are even above the probable effect level (PEL). Most sampling sites of the channel discharging areas show minor enrichment of Cu, Ni, and Zn with respect to the TEL. Contamination indices show that the lagoon mouth area is enriched with As. Statistical analysis implies that discharges from agricultural channel and marine fluxes of the lagoon effects on the spatial distribution of measured elements. Further research is required to understand the rate of contamination in the studied marine system.

Quality of water and chemistry of bottom sediment in the Rillito Creek basin, Tucson, Arizona, 1986-92

USGS Publications Warehouse

Tadayon, Saeid; Smith, C.F.

1994-01-01

Data were collected on physical properties and chemistry of 4 surface water, l4 ground water, and 4 bottom sediment sites in the Rillito Creek basin where artificial recharge of surface runoff is being considered. Concentrations of suspended sediment in streams generally increased with increases in streamflow and were higher during the summer. The surface water is a calcium and bicarbonate type, and the ground water is calcium sodium and bicarbonate type. Total trace ek=nents in surface water that exceeded the U.S. Environmental Protection Agency primary maximum contaminant levels for drinking-water standards were barium, beryllium, cadmium, chromium, lead, mercury and nickel. Most unfiltered samples for suspended gross alpha as uranium, and unadjusted gross alpha plus gross beta in surface water exceeded the U.S. Environmental Protection Agency and the State of Arizona drinking-water standards. Comparisons of trace- element concentrations in bottom sediment with those in soils of the western conterminous United States generally indicate similar concentrations for most of the trace elements, with the exceptions of scandium and tin. The maximum concentration of total nitrite plus nitrate as nitrogen in three ground- samples and total lead in one ground-water sample exceeded U.S. Environmental Protection Agency primary maximum contaminant levels for drinking- water standards, respectively. Seven organochlorine pesticides were detected in surface-water samples and nine in bottom-sediment samples. Three priority pollutants were detected in surface water, two were detected in ground water, and eleven were detected in bottom sediment. Low concentrations of oil and grease were detected in surface-water and bottom- sediment samples.

Selenium in irrigated agricultural areas of the western United States

USGS Publications Warehouse

Nolan, B.T.; Clark, M.L.

1997-01-01

A logistic regression model was developed to predict the likelihood that Se exceeds the USEPA chronic criterion for aquatic life (5 ??g/L) in irrigated agricultural areas of the western USA. Preliminary analysis of explanatory variables used in the model indicated that surface-water Se concentration increased with increasing dissolved solids (DS) concentration and with the presence of Upper Cretaceous, mainly marine sediment. The presence or absence of Cretaceous sediment was the major variable affecting Se concentration in surface-water samples from the National Irrigation Water Quality Program. Median Se concentration was 14 ??g/L in samples from areas underlain by Cretaceous sediments and < 1 ??g/L in samples from areas underlain by non-Cretaceous sediments. Wilcoxon rank sum tests indicated that elevated Se concentrations in samples from areas with Cretaceous sediments, irrigated areas, and from closed lakes and ponds were statistically significant. Spearman correlations indicated that Se was positively correlated with a binary geology variable (0.64) and DS (0.45). Logistic regression models indicated that the concentration of Se in surface water was almost certain to exceed the Environmental Protection Agency aquatic-life chronic criterion of 5 ??g/L when DS was greater than 3000 mg/L in areas with Cretaceous sediments. The 'best' logistic regression model correctly predicted Se exceedances and nonexceedances 84.4% of the time, and model sensitivity was 80.7%. A regional map of Cretaceous sediment showed the location of potential problem areas. The map and logistic regression model are tools that can be used to determine the potential for Se contamination of irrigated agricultural areas in the western USA.

An assessment of butyltins and metals in sediment cores from the St. Thomas East End Reserves, USVI.

PubMed

Hartwell, S Ian; Apeti, Dennis A; Mason, Andrew L; Pait, Anthony S

2016-11-01

Tributyltin (TBT) concentrations near a marina complex in Benner Bay on St. Thomas, US Virgin Islands, were elevated relative to other areas in a larger study of the southeastern shore of the island. At the request of the USVI Coastal Zone Management Program, sediment cores and surface sediment samples were collected to better define the extent and history of TBT deposition in the vicinity of Benner Bay. The sediment cores were sectioned into 2-cm intervals and dated with 210 Pb and 137 Cs. The core sections and the surface samples were analyzed for butyltins and 16 elements. Deposition rates varied from 0.07-5.0 mm/year, and were highest in the marina complex. Core ages ranged from 54 to 200 years. The bottoms of the cores contained shell hash, but the top layers all consisted of much finer material. Surface concentrations of TBT exceeded 2000 ng Sn/g (dry weight) at two locations. At a depth of 8 cm TBT exceeded 8800 ng Sn/g in the marina complex sediment. Based on the ratio of tributyltin to total butyltins, it appears that the marina sediments are the source of contamination of the surrounding area. There is evidence that vessels from neighboring islands may also be a source of fresh TBT. Copper concentrations increase over time up to the present. Gradients of virtually all metals and metalloids extended away from the marina complex. NOAA sediment quality guidelines were exceeded for As, Pb, Cu, Zn, and Hg.

Effects of urbanization and long-term rainfall on the occurrence of organic compounds and trace elements in reservoir sediment cores, streambed sediment, and fish tissue from the Santa Ana River basin, California, 1998

USGS Publications Warehouse

Burton, Carmen A.

2002-01-01

Organcochlorine compounds, semivolatile-organic compounds (SVOC), and trace elements were analyzed in reservoir sediment cores, streambed sediment, and fish tissue in the Santa Ana River Basin as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Three reservoirs were sampled in areas that have different degrees of urbanization. Streambed sediment and fish tissue collected at 12 sites were divided into two groups, urban and nonurban. More organochlorine compounds were detected in reservoir sediment cores, streambed sediment and fish tissue, and at higher concentrations at urban sites than at nonurban sites. At all sites, except West Street Basin, concentrations of organochlorine compounds were lower than the probable-effect concentration (PEC). At the highly urbanized West Street Basin, chlordane and p,p'-DDE exceeded the PEC throughout the historical record. The less stringent threshold-effect concentration (TEC) was exceeded for six compounds at eight sites. Most of the organochlorine compounds detected in streambed sediment and fish tissue were at urban sites on the Santa Ana River as opposed to its tributaries, suggesting accumulation and persistence in the river. More SVOCs were detected in reservoir sediment cores and streambed sediment, and at higher concentrations, at urban sites than at nonurban sites. At all the sites, except West Street Basin, concentrations of SVOCs were lower than the PEC. At West Street Basin, chrysene, pyrene, and total polycyclic-aromatic hydrocarbons exceeded the PEC throughout the historical record. The TEC was exceeded for 10 compounds at 3 sites. Most of the SVOCs were detected in streambed sediment at urban sites on tributaries to the Santa Ana River rather than the mainstem itself. The less frequent occurrence and lower concentrations in the Santa Ana River suggest that SVOCs are less persistent than organochlorine compounds, possibly as a result of volatization, gradation, or dilution. Most trace-element detections in reservoir sediment cores and streambed sediment were at urban sites, and the concentrations were generally higher than at nonurban sites. Lead and zinc exceeded their PECs at West Street Basin throughout the historical record; copper exceeded its PEC at Canyon Lake, an area of urban growth. The TEC was exceeded for 10 compounds at 11 sites. Frequency of detection and concentration did not differ between tributary and Santa Ana River sites, which may be attributed to the fact that trace elements occur naturally. Four trace elements (arsenic, copper, mercury, and selenium) had higher concentrations in fish tissue at nonurban sites than at urban sites. Concentrations decreased over time for organochlorine compounds at all three reservoirs, probably a result of the discontinued use of many of the compounds. Decreasing trends in SVOCs and trace elements were observed at West Street Basin, but increasing trends were observed at Canyon Lake. Concentrations of organochlorine compounds, SVOCs, and trace elements were higher during periods of above average rainfall at both West Street Basin and Canyon Lake.

Chemical quality of the Saw Mill River, Westchester County, New York, 1981-83

USGS Publications Warehouse

Rogers, R.J.

1984-01-01

Surface waters, bottom sediments and coatings formed on artificial substrates (ceramic tiles) were analyzed to evaluate the chemical quality of the Saw Mill River, New York. Heavy metals, nutrients, and organic contaminants were studied. Dissolved orthophosphate concentrations were highest in the lower third of the river. Dissolved manganese was the only metal to exceed U.S. Environmental Protection Agency water-quality criteria. Arsenic, cadmium, copper, lead, and zinc concentrations were highest in waters from the lowest 4 river miles. Concentrations of copper, lead, and zinc in bottom sediments from the lowest 3 river miles were greater than in upstream sediments. Concentrations of nine heavy metals were higher on tiles emplaced below river mile 3 than on tiles upstream. Few organic compounds were detected in the water column; none persisted at all sites. Chlordane, DDD, DDE, DDT, dieldrin, and polychlorinated biphenyls (PCB's) were found in bottom sediments throughout the basin. PCB concentrations were highest in the lowest 6 river miles; the other organic compounds exhibited no spatial patterns. Polynuclear aromatic hydrocarbons were most abundant in bottom sediments from the lowest 2 river miles. Collectively the distribution of contaminants indicates that river quality deteriorates in the lower, more heavily urbanized reach. (USGS)

Spatial patterns of chemical contamination (metals, PAHs, PCBs, PCDDs/PCDFS) in sediments of a non-industrialized but densely populated coral atoll/small island state (Bermuda).

PubMed

Jones, Ross J

2011-06-01

There is a recognized dearth of standard environmental quality data in the wider Caribbean area, especially on coral atolls/small island states. Extensive surveys of sediment contamination (n=109 samples) in Bermuda revealed a wide spectrum of environmental quality. Zinc and especially copper levels were elevated at some locations, associated with boating (antifouling paints and boatyard discharges). Mercury contamination was surprisingly prevalent, with total levels as high as 12mg kg(-1)DW, although methyl mercury levels were quite low. PAH, PCB and PCDD/PCDF contamination was detected a several hotspots associated with road run-off, a marine landfill, and a former US Naval annexe. NOAA sediment quality guidelines were exceeded at several locations, indicating biological effects are possible, or at some locations probable. Overall, and despite lack of industrialization, anthropogenic chemicals in sediments of the atoll presented a risk to benthic biodiversity at a number of hotspots suggesting a need for sediment management strategies. Copyright © 2011 Elsevier Ltd. All rights reserved.

Sediment studies in the Assabet River, central Massachusetts, 2003

USGS Publications Warehouse

Zimmerman, Marc J.; Sorenson, Jason R.

2005-01-01

From its headwaters in Westborough, Massachusetts, to its confluence with the Sudbury River, the 53-kilometer-long Assabet River passes through a series of small towns and mixed land-use areas. Along the way, wastewater-treatment plants release nutrient-rich effluents that contribute to the eutrophic state of this waterway. This condition is most obvious where the river is impounded by a series of dams that have sequestered large amounts of sediment and support rooted and floating macrophytes and epiphytic algae. The water in parts of these impoundments may also have low concentrations of dissolved oxygen, another symptom of eutrophication. All of the impoundments had relatively shallow maximum water depths, which ranged from approximately 2.4 to 3.4 meters, and all had extensive shallow areas. Sediment volumes estimated for the six impoundments ranged from approximately 380 cubic meters in the Aluminum City impoundment to 580,000 cubic meters in the Ben Smith impoundment. The other impoundments had sediment volumes of 120,000 cubic meters (Powdermill), 67,000 cubic meters (Gleasondale), 55,000 cubic meters (Hudson), and 42,000 cubic meters (Allen Street). The principal objective of this study was the determination of sediment volume, extent, and chemistry, in particular, the characterization of toxic inorganic and organic chemicals in the sediments. To determine the bulk-sediment chemical-constituent concentrations, more than one hundred sediment cores were collected in pairs from the six impoundments. One core from each pair was sampled for inorganic constituents and the other for organic constituents. Most of the cores analyzed for inorganics were sectioned to provide information on the vertical distribution of analytes; a subset of the cores analyzed for organics was also sectioned. Approximately 200 samples were analyzed for inorganic constituents and 100 for organics; more than 10 percent were quality-control replicate or blank samples. Maximum bulk-sediment phosphorus concentrations in surface samples from the impoundments increased along a downstream gradient, with the exception of samples from the last impoundment, where the concentrations decreased. In addition, the highest phosphorus concentrations were generally in the surface samples; this finding may prove helpful if surface dredging is selected as a means to control phosphorus release from sediments. There is no known relation, however, between bulk-sediment concentration of phosphorus and the concentrations of phosphorus available to biota. Potentially toxic metals, including arsenic, cadmium, chromium, copper, nickel, lead, and zinc were frequently measured at concentrations that exceeded U.S. Environmental Protection Agency sediment-quality guidelines for the protection of aquatic life and that occasionally exceeded Massachusetts Department of Environmental Protection guidelines governing landfill disposal (reuse). Due to the effects of matrix interference and sample dilution on laboratory analyses, neither pesticides nor volatile organic compounds were detected at any sites. However, samples collected in other studies from nearby streams indicated the possibility that pesticides might have been detected in the impoundments if not for these analytical problems. Although polychlorinated biphenyl concentrations, as individual Aroclors, generally exceeded published U.S. Environmental Protection Agency guideline concentrations for potential effects on aquatic life, the U.S. Environmental Protection Agency guideline concentrations for human contact or the Massachusetts guidelines for landfill reuse were rarely exceeded. Concentrations of polycyclic aromatic hydrocarbons, both individually and total, frequently were greater than guideline concentrations. Concentrations of total extractable petroleum hydrocarbons did not exceed Massachusetts guideline concentrations in any samples. When the sediment analytes from surface samples are considered togethe

Habitat-based PCB environmental quality criteria for the protection of endangered killer whales (Orcinus orca).

PubMed

Alava, Juan José; Ross, Peter S; Lachmuth, Cara; Ford, John K B; Hickie, Brendan E; Gobas, Frank A P C

2012-11-20

The development of an area-based polychlorinated biphenyl (PCB) food-web bioaccumulation model enabled a critical evaluation of the efficacy of sediment quality criteria and prey tissue residue guidelines in protecting fish-eating resident killer whales of British Columbia and adjacent waters. Model-predicted and observed PCB concentrations in resident killer whales and Chinook salmon were in good agreement, supporting the model's application for risk assessment and criteria development. Model application shows that PCB concentrations in the sediments from the resident killer whale's Critical Habitats and entire foraging range leads to PCB concentrations in most killer whales that exceed PCB toxicity threshold concentrations reported for marine mammals. Results further indicate that current PCB sediment quality and prey tissue residue criteria for fish-eating wildlife are not protective of killer whales and are not appropriate for assessing risks of PCB-contaminated sediments to high trophic level biota. We present a novel methodology for deriving sediment quality criteria and tissue residue guidelines that protect biota of high trophic levels under various PCB management scenarios. PCB concentrations in sediments and in prey that are deemed protective of resident killer whale health are much lower than current criteria values, underscoring the extreme vulnerability of high trophic level marine mammals to persistent and bioaccumulative contaminants.

Stormwater Characterization and Lagoon Sediment Analysis, Grand Forks Air Force Base, North Dakota

DTIC Science & Technology

1990-08-01

tetrachloroethylene, and 0.0026 mg/l ethyl benzene. Analyses showed no pesticides . 4. Extraction Procedure (EP) Analysis. An AFOEHL contractor performed EP extraction ...runoff met North Dakota state stream standards. Lagoon sediment did not contain Extraction Procedure hazardous chemicals. Stormwater runoff exceeded...Standards for Water Quality for the State of North Dakota ( Extracts ) 39 D Site/Analysis Summary 69 E Lift Station Flow Records 73 F Wastewater

Contaminants of emerging concern in tributaries to the Laurentian Great Lakes: I. Patterns of occurrence

PubMed Central

Lee, Kathy E.; Banda, Jo A.; Choy, Steven J.; Gefell, Daniel J.; Minarik, Thomas A.; Moore, Jeremy N.; Jorgenson, Zachary G.

2017-01-01

Human activities introduce a variety of chemicals to the Laurentian Great Lakes including pesticides, pharmaceuticals, flame retardants, plasticizers, and solvents (collectively referred to as contaminants of emerging concern or CECs) potentially threatening the vitality of these valuable ecosystems. We conducted a basin-wide study to identify the presence of CECs and other chemicals of interest in 12 U.S. tributaries to the Laurentian Great Lakes during 2013 and 2014. A total of 292 surface-water and 80 sediment samples were collected and analyzed for approximately 200 chemicals. A total of 32 and 28 chemicals were detected in at least 30% of water and sediment samples, respectively. Concentrations ranged from 0.0284 (indole) to 72.2 (cholesterol) μg/L in water and 1.75 (diphenhydramine) to 20,800 μg/kg (fluoranthene) in sediment. Cluster analyses revealed chemicals that frequently co-occurred such as pharmaceuticals and flame retardants at sites receiving similar inputs such as wastewater treatment plant effluent. Comparison of environmental concentrations to water and sediment-quality benchmarks revealed that polycyclic aromatic hydrocarbon concentrations often exceeded benchmarks in both water and sediment. Additionally, bis(2-ethylhexyl) phthalate and dichlorvos concentrations exceeded water-quality benchmarks in several rivers. Results from this study can be used to understand organism exposure, prioritize river basins for future management efforts, and guide detailed assessments of factors influencing transport and fate of CECs in the Great Lakes Basin. PMID:28953889

Contaminants of emerging concern in tributaries to the Laurentian Great Lakes: I. Patterns of occurrence

USGS Publications Warehouse

Elliott, Sarah M.; Brigham, Mark E.; Lee, Kathy E.; Banda, Jo A.; Choy, Steven J.; Gefell, Daniel J.; Minarik, Thomas A.; Moore, Jeremy N.; Jorgenson, Zachary G.

2017-01-01

Human activities introduce a variety of chemicals to the Laurentian Great Lakes including pesticides, pharmaceuticals, flame retardants, plasticizers, and solvents (collectively referred to as contaminants of emerging concern or CECs) potentially threatening the vitality of these valuable ecosystems. We conducted a basin-wide study to identify the presence of CECs and other chemicals of interest in 12 U.S. tributaries to the Laurentian Great Lakes during 2013 and 2014. A total of 292 surface-water and 80 sediment samples were collected and analyzed for approximately 200 chemicals. A total of 32 and 28 chemicals were detected in at least 30% of water and sediment samples, respectively. Concentrations ranged from 0.0284 (indole) to 72.2 (cholesterol) μg/L in water and 1.75 (diphenhydramine) to 20,800 μg/kg (fluoranthene) in sediment. Cluster analyses revealed chemicals that frequently co-occurred such as pharmaceuticals and flame retardants at sites receiving similar inputs such as wastewater treatment plant effluent. Comparison of environmental concentrations to water and sediment-quality benchmarks revealed that polycyclic aromatic hydrocarbon concentrations often exceeded benchmarks in both water and sediment. Additionally, bis(2-ethylhexyl) phthalate and dichlorvos concentrations exceeded water-quality benchmarks in several rivers. Results from this study can be used to understand organism exposure, prioritize river basins for future management efforts, and guide detailed assessments of factors influencing transport and fate of CECs in the Great Lakes Basin.

Food Web Bioaccumulation Model for Resident Killer Whales from the Northeastern Pacific Ocean as a Tool for the Derivation of PBDE-Sediment Quality Guidelines.

PubMed

Alava, Juan José; Ross, Peter S; Gobas, Frank A P C

2016-01-01

Resident killer whale populations in the NE Pacific Ocean are at risk due to the accumulation of pollutants, including polybrominated diphenyl ethers (PBDEs). To assess the impact of PBDEs in water and sediments in killer whale critical habitat, we developed a food web bioaccumulation model. The model was designed to estimate PBDE concentrations in killer whales based on PBDE concentrations in sediments and the water column throughout a lifetime of exposure. Calculated and observed PBDE concentrations exceeded the only toxicity reference value available for PBDEs in marine mammals (1500 μg/kg lipid) in southern resident killer whales but not in northern resident killer whales. Temporal trends (1993-2006) for PBDEs observed in southern resident killer whales showed a doubling time of ≈5 years. If current sediment quality guidelines available in Canada for polychlorinated biphenyls are applied to PBDEs, it can be expected that PBDE concentrations in killer whales will exceed available toxicity reference values by a large margin. Model calculations suggest that a PBDE concentration in sediments of approximately 1.0 μg/kg dw produces PBDE concentrations in resident killer whales that are below the current toxicity reference value for 95 % of the population, with this value serving as a precautionary benchmark for a management-based approach to reducing PBDE health risks to killer whales. The food web bioaccumulation model may be a useful risk management tool in support of regulatory protection for killer whales.

Occurrence, distribution, and volume of metals-contaminated sediment of selected streams draining the Tri-State Mining District, Missouri, Oklahoma, and Kansas, 2011–12

USGS Publications Warehouse

Smith, D. Charlie

2016-12-14

Lead and zinc were mined in the Tri-State Mining District (TSMD) of southwest Missouri, northeast Oklahoma, and southeast Kansas for more than 100 years. The effects of mining on the landscape are still evident, nearly 50 years after the last mine ceased operation. The legacies of mining are the mine waste and discharge of groundwater from underground mines. The mine-waste piles and underground mines are continuous sources of trace metals (primarily lead, zinc, and cadmium) to the streams that drain the TSMD. Many previous studies characterized the horizontal extent of mine-waste contamination in streams but little information exists on the depth of mine-waste contamination in these streams. Characterizing the vertical extent of contamination is difficult because of the large amount of coarse-grained material, ranging from coarse gravel to boulders, within channel sediment. The U.S. Geological Survey, in cooperation with U.S. Fish and Wildlife service, collected channel-sediment samples at depth for subsequent analyses that would allow attainment of the following goals: (1) determination of the relation between concentration and depth for lead, zinc and cadmium in channel sediments and flood-plain sediments, and (2) determination of the volume of gravel-bar sediment from the surface to the maximum depth with concentrations of these metals that exceeded sediment-quality guidelines. For the purpose of this report, volume of gravel-bar sediment is considered to be distributed in two forms, gravel bars and the wetted channel, and this study focused on gravel bars. Concentrations of lead, zinc, and cadmium in samples were compared to the consensus probable effects concentration (CPEC) and Tri-State Mining District specific probable effects concentration (TPEC) sediment-quality guidelines.During the study, more than 700 sediment samples were collected from borings at multiple sites, including gravel bars and flood plains, along Center Creek, Turkey Creek, Shoal Creek, Tar Creek, and Spring River in order to characterize the vertical extent of mine waste in select streams in the TSMD. The largest concentrations of lead, zinc, and cadmium in gravel bar-sediment samples generally were detected in Turkey Creek and Tar Creek and the smallest concentrations were detected in Shoal Creek followed by the Spring River. Gravel bar-sediment samples from Turkey Creek exceeded the CPEC for cadmium (minimum of 70 percent of samples), lead (94 percent), and zinc (99 percent) at a slightly higher frequency than similar samples from Tar Creek (69 percent, 88 percent, and 96 percent, respectively). Gravel bar-sediment samples from Turkey Creek also contained the largest concentrations of cadmium (174 milligrams per kilogram [mg/kg]) and lead (7,520 mg/kg) detected; however, the largest zinc concentration (46,600 mg/kg) was detected in a gravel bar-sediment sample from Tar Creek. In contrast, none of the 65 gravel bar-sediment samples from Shoal Creek contained cadmium above the x-ray fluorescence reporting level of 12 mg/kg, and lead and zinc exceeded the CPEC in only 12 percent and 74 percent of samples, respectively. In most cases, concentrations of lead and zinc above the CPEC or TPEC were present at the maximum depth of boring, which indicated that nearly the entire thickness of sediment in the stream has been contaminated by mine wastes. Approximately 284,000 cubic yards of channel sediment from land surface to the maximum depth that exceeded the CPEC and approximately 236,000 cubic yards of channel sediment from land surface to the maximum depth that exceeded the TPEC were estimated along 37.6 of the 55.1 miles of Center Creek, Turkey Creek, Shoal Creek, and Tar Creek examined in this study. Mine-waste contamination reported along additional reaches of these streams is beyond the scope of this study. Flood-plain cores collected in the TSMD generally only had exceedances of the CPEC and TPEC for lead and zinc in the top 1 or 2 feet of soil with a few exceptions, such as cores in low areas near the stream or cores in areas disturbed by past mining.

Quality of bottom material and elutriates in the lower Willamette River, Portland Harbor, Oregon

USGS Publications Warehouse

Fuhrer, Gregory J.

1989-01-01

In October 1983 the U.S. Geological Survey, in cooperation with the U.S. Army Corp of Engineers, collected bottom-material and water samples from Portland Harbor, Oregon to determine concentrations of trace metals and organic compounds in elutriate-test filtrate and bottom material. Of the trace metals examined in bottom material, concentrations of cadmium slightly exceed those of local rocks, whereas lead and zinc exceedance is substantially larger. Of the organochlorine compounds examined in bottom material chlordane, DDD, DDE, DDT, dieldrin, and polychlorinated biphenyls (PCB's) were detected and quantified in at least 30% of the samples tested. A large DDT concentration (2,700 microgram/kilogram) near Doane Lake outlet is indicative of recent contamination. Polychlorinated biphenyls are ubiquitous in bottom sediments; median concentrations are nearly 65 micrograms/kilogram and as large as 550 microgram/kilogram. PCB loading to the Columbia River from Willamette River suspended sediment has been estimated to be 72 kilograms/year, nearly five times the PCB dredge load of 15 kilogram/year. The acid and base-neutral extractable di-n-butyl phthalate and bis (2-ethylhexyl)phthalate occur in sediments of Terminal No. 2 in concentrations as large as 1,965 and 2,200 micrograms/kilogram, respectively. Of the trace metals examined in both standard and oxic elutriate-test filtrate, only copper concentration in an oxic elutriate-test filtrate (19 micrograms/L) exceeded the water quality criteria (5.7 micrograms/L). (USGS)

Sediment quality in the north coastal basin of Massachusetts, 2003

USGS Publications Warehouse

Breault, Robert F.; Ashman, Mary S.; Heath, Douglas

2004-01-01

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, completed a reconnaissance-level study of bottom-sediment quality in selected lakes, rivers, and estuaries in the North Coastal Basin of Massachusetts. Bottom-sediment grab samples were collected from 20 sites in the North River, Lake Quannapowitt, Saugus River, Mill River, Shute Brook, Sea Plane Basin, Pines River, and Bear Creek. The samples were tested for various types of potentially harmful contaminants? including 33 elements, 17 polyaromatic hydrocarbons (PAHs), 22 organochlorine pesticides, and 7 polychlorinated biphenyl (PCB) mixtures (Aroclors)?to benthic organisms (bottom-dwelling) and humans. The results were compared among sampling sites, to background concentrations, and to concen-trations measured in other urban rivers, and sediment-quality guidelines were used to predict toxicity at the sampling sites to benthic organisms and humans. Because there are no standards for human toxicity for aquatic sediment, standards for contaminated upland soil were used. Contaminant concentrations measured in sediment collected from the North Coastal Basin generally were equal to or greater than concentrations in sediment from uncontaminated rivers throughout New England. Contaminants in North Coastal Basin sediment with elevated concentrations (above back-ground levels) included arsenic, chromium, copper, lead, nickel, and zinc, some of the PAHs, dichlorodiphenyltrichloro-ethane (DDT) and its metabolites, and dieldrin. No PCBs were measured above the detection limits. Measured concentrations of arsenic, chromium, and lead were also generally greater than those measured in other urban rivers throughout the conter-minous United States. With one exception (arsenic), local con-centrations measured in sediment samples collected from the North Coastal Basin were lower than concentrations measured in sediment collected from two of three urban rivers draining to Boston Harbor. The probable toxicity to benthic organisms ranged from about 33 to 91 percent across the study area. Of the elements analyzed, antimony, arsenic, beryllium, and lead exceeded the soil standards for risk to human health. Of the PAHs analyzed, four also exceeded soil standards. Organochlorine pesticide concentrations, however, were not high enough relative to the soil standards to pose a risk to human health. Some trace element and some organic compound concentrations in bottom sediment may be toxic to aquatic organisms and may pose a risk to human health.

Environmental setting, water quality, and ecological indicators of surface-water quality in the Mermentau River Basin, southwestern Louisiana, 1998-2001

USGS Publications Warehouse

Skrobialowski, Stanley C.; Mize, Scott V.; Demcheck, Dennis K.

2004-01-01

The U.S. Geological Survey collected data from 29 wells and 24 surface-water sites in the Mermentau River Basin, 1998-2001, to better understand ground-water and surface-water quality; aquatic invertebrate communities; and habitat conditions, in relation to land use. This study was apart of the National Water-Quality Assessment Program, which was designed to assess water quality as it relates to various land uses. Water-quality data were evaluated with criteria established for the protection of drinking water and aquatic life, and bed-sediment data were compared to aquatic life criteria. Water-quality and ecological data were analyzed statistically in relation to drainage area and agricultural land-use integrity. Concentrations of nutrients and major inorganic ions in ground water and surface water generally were highest in the southeastern part of the study area where soils contain thick loess deposits. Peak concentrations of nutrients in surface water occurred March-may at two sites with high agricultural intensity; the lowest concentrations occurred August-January. The greatest potential for eutrophic conditions in surface water, based on nutrient concentrations, existed March-May, at about the same time or shortly after ricefields were drained. Secondary Maximum Contaminant Levels established by the U.S. Environmental Protection Agency (USEPA) were exceeded for sulfate, chloride, iron, or manganese in samples from 20 wells, and for iron or manganese in samples from all surface-water sites. Fewer pesticides were detected in ground water than in surface water. In 11 of of the 29 wells sampled, at least one pesticide or pesticide degradation product was detected. The most frequently detected pesticides or pesticide degradation products in ground water were the herbicides benzaton and atrazine. Concentrations of 47 pesticides and degradation products were detected in surface water. At least 3 pesticides were detected in all surface-water samples. In 72 percent of the samples at least 5 hydrophilic pesticides were detected, and in more than 70 percent of the samples at least 3 hydrophobic pesticides were detected. Although atrazine concentrations in three samples collected in the spring exceeded 3 micrograms per liter, the USEPA Maximum Contaminant Level of 3 micrograms per liter was not exceeded because it is based on an annual average of quarterly samples. Concentrations larger than 3.0 micrograms per liter were not detected in samples collected during other times of the year. Tebuthiuron was detected at all surface-water sites; the largest concentration (6.33 micrograms per liter) was detected at a site on Bayou des Cannes, and was the only detection that exceeded the criterion (1.6 micrograms per liter) for the protection of aquatic life. Malathion was detected at 16 surface-water sites; the largest concentration (0.113 micrograms per liter) was detected at a site on Bayou Lacassine and was the only detection that exceeded the criterion (0.1 micrograms per liter) for the protection of aquatic life. Concentrations of fipronil exceeded numeric targets for acute total maximum daily loads (2.3 micrograms per liter) at 3 sites and chronic total maximum daily loads (4.6 micrograms per liter) at 14 sites. Maximum pesticide concentrations in surface water usually occurred in the spring at about the same time or shortly after ricefields were drained. Concentrations of DDE in bed sediment at two sites exceeded interim freshwater sediment quality guidelines for the protection of aquatic life. Fipronil sulfide and desulfinylpronil were detected at all 17 sites from which bed-sediment samples were collected, but there are no current (2002) guidelines with which to evaluate the environmental effects of fipronil and degradation products. Two methods were used to group the ecological data-collection sites: (1) Sites were grouped before data collection (according to the study design) using drainage area

Surface-water-quality assessment of the upper Illinois River basin in Illinois, Indiana, and Wisconsin; spatial distribution of geochemicals in the fine fraction of streambed sediment, 1987

USGS Publications Warehouse

Fitzpatrick, Faith A.; Arnold, Terri L.; Colman, John A.

1998-01-01

Geochemical data for the upper Illinois River Basin are presented for concentrations of 39 elements in streambed sediment collected by the U.S. Geological Survey in the fall of 1987. These data were collected as part of the pilot phase of the National Water-Quality Assessment Program. A total of 372 sites were sampled, with 238 sites located on first- and second-order streams, and 134 sites located on main stems. Spatial distribution maps and exceedance probability plots are presented for aluminum, antimony, arsenic, barium, beryllium, boron, cadmium, calcium, carbon (total, inorganic, and organic), cerium, chromium, cobalt, copper, gallium, iron, lanthanum, lead, lithium, magnesium, manganese, mercury, molybdenum, neodymium, nickel, niobium, phosphorus, potassium, scandium, selenium, silver, sodium, strontium, sulfur, thorium, titanium, uranium, vanadium, yttrium, and zinc. For spatial distribution maps, concentrations of the elements are grouped into four ranges bounded by the minimum concentration, the 10th, 50th, and 90th percentiles, and the maximum concentrations. These ranges were selected to highlight streambed sediment with very low or very high element concentrations relative to the rest of the streambed sediment in the upper Illinois River Basin. Exceedance probability plots for each element display the differences, if any, in distributions between high- and low-order streams and may be helpful in determining differences between background and elevated concentrations.

Water-quality assessment of the Albermarle-Pamlico drainage basin, North Carolina and Virginia; a summary of selected trace element, nutrient, and pesticide data for bed sediments, 1969-90

USGS Publications Warehouse

Skrobialowski, S.C.

1996-01-01

Spatial distributions of metals and trace elements, nutrients, and pesticides and polychiorinated biphenyls (PCB's) in bed sediment were characterized using data collected from 1969 through 1990 and stored in the U.S. Geological Survey's National Water Data Storage and Retrieval (WATSTORE) system and the U.S. Environmental Protection Agency's Storage and Retrieval (STORET) system databases. Bed-sediment data from WATSTORE and STORET were combined to form a single database of 1,049 records representing 301 sites. Data were examined for concentrations of 16 metals and trace elements, 4 nutrients, 10 pesticides, and PCB's. Maximum bed-sediment concentrations were evaluated relative to sediment-quality guidelines developed by the National Oceanic and Atmospheric Administration, the Ontario Ministry of Environment and Energy, and the Virginia Department of Environmental Quality. Sites were not selected randomly; therefore, results should not be interpreted as representing average conditions. Many sites were located in or around lakes and reservoirs, urban areas, and areas where special investigations were conducted. Lakes and reservoirs function as effective sediment traps, and elevated concentrations of some constituents occurred at these sites. High concentrations of many metals and trace elements also occurred near urban areas where streams receive runoff or inputs from industrial, residential, and municipal activities. Elevated nutrient concentrations occurred near lakes, reservoirs, and the mouths of major rivers. The highest concentrations of arsenic, beryllium, chromium, iron. mercury, nickel, and selenium occurred in the Roanoke River Basin and may be a result of geologic formations or accumulations of bed sediment in lakes and reservoirs. The highest concentrations of cadmium, lead, and thallium were detected in the Chowan River Basin; copper and zinc were reported highest in the Neuse River Basin. Total phosphorus and total ammonia plus organic nitrogen concentrations exceeded the sediment evaluation guidelines in each major river basin, possibly resulting from wastewater inputs and agricultural applications. Exceedances of pesticide guidelines were detected in the upper Neuse River Basin near Falls Lake and in the lower Tar River Basin.

Trace element, semivolatile organic, and chlorinated organic compound concentrations in bed sediments of selected streams at Fort Gordon, Georgia, February-April 2010

USGS Publications Warehouse

Thomas, Lashun K.; Journey, Celeste A.; Stringfield, Whitney J.; Clark, Jimmy M.; Bradley, Paul M.; Wellborn, John B.; Ratliff, Hagan; Abrahamsen, Thomas A.

2011-01-01

A spatial survey of streams was conducted from February to April 2010 to assess the concentrations of major ions, selected trace elements, semivolatile organic compounds, organochlorine pesticides, and polychlorinated biphenyls associated with the bed sediments of surface waters at Fort Gordon military installation near Augusta, Georgia. This investigation expanded a previous study conducted in May 1998 by the U.S. Geological Survey, in cooperation with the U.S. Department of the Army Environmental and Natural Resources Management Office of the U.S. Army Signal Center and Fort Gordon, that evaluated the streambed sediment quality of selected surface waters at Fort Gordon. The data presented in this report are intended to help evaluate bed sediment quality in relation to guidelines for the protection of aquatic life, and identify temporal trends in trace elements and semivolatile organic compound concentrations at streambed sites previously sampled. Concentrations of 34 major ions and trace elements and 102 semivolatile organic, organochlorine pesticide, and polychlorinated biphenyl compounds were determined in the fine-grained fraction of bed sediment samples collected from 13 of the original 29 sites in the previous study, and 22 additional sites at Fort Gordon. Three of the sites were considered reference sites as they were presumed to be located away from potential sources of contaminants and were selected to represent surface waters flowing onto the fort, and the remaining 32 nonreference sites were presumed to be located within the contamination area at the fort. Temporal trends in trace elements and semivolatile organic compound concentrations also were evaluated at 13 of the 32 nonreference sites to provide an assessment of the variability in the number of detections and concentrations of constituents in bed sediment associated with potential sources, accumulation, and attenuation processes. Major ion and trace element concentrations in fine-grained bed sediment samples from most nonreference sites exceeded concentrations in samples from reference sites at Fort Gordon. Bed sediments from one of the nonreference sites sampled contained the highest concentrations of copper and lead with elevated levels of zinc and chromium relative to reference sites. The percentage change of major ions, trace elements, and total organic carbon that had been detected at sites previously sampled in May 1998 and current bed sediment sites ranged from -4 to 8 percent with an average percentage change of less than 1 percent. Concentrations of major ions and trace elements in bed sediments exceeded probable effect levels for aquatic life (based on the amphipod Hyalella azteca) established by the U.S. Environmental Protection Agency at 46 and 69 percent of the current and previously sampled locations, respectively. The greatest frequency of exceedances for major ions and trace elements in bed sediments was observed for lead. Concentrations of semivolatile organic compounds, organochlorine pesticides, and polychlorinated biphenyls were detected in bed sediment samples at 94 percent of the sites currently sampled. Detections of these organic compounds were reported with greater frequency in bed sediments at upstream sampling locations, when compared to downstream locations. The greatest number of detections of these compounds was reported for bed sediment samples collected from two creeks above a lake. The percentage change of semivolatile organic compounds detected at previously sampled and current bed sediment sites ranged from -68 to 100 percent with the greatest percentage increase reported for one of the creeks above the lake. Concentrations of semivolatile organic compounds and polychlorinated biphenyls in bed sediments exceeded aquatic life criteria established by the U.S. Environmental Protection Agency at three sites. Contaminant compounds exceeding aquatic life criteria included fluoranthene, phenanthrene, anthracene, benzo(a)anthracene

Urban sprawl leaves its PAH signature

USGS Publications Warehouse

Van Metre, P.C.; Mahler, B.J.; Furlong, E.T.

2000-01-01

The increasing vehicle traffic associated with urban sprawl in the United States is frequently linked to degradation of air quality, but its effect on aquatic sediment is less well-recognized. This study evaluates trends in PAHs, a group of contaminants with multiple urban sources, in sediment cores from 10 reservoirs and lakes in six U.S. metropolitan areas. The watersheds chosen represent a range in degree and age of urbanization. Concentrations of PAHs in all 10 reservoirs and lakes increased during the past 20-40 years. PAH contamination of the most recently deposited sediment at all sites exceeded sediment-quality guidelines established by Environment Canada, in some cases by several orders of magnitude. These results add a new chapter to the story told by previous coring studies that reported decreasing concentrations of PAHs after reaching highs in the 1950s. Concurrent with the increase in concentrations is a change in the assemblage of PAHs that indicates the increasing trends are driven by combustion sources. The increase in PAH concentrations tracks closely with increases in automobile use, even in watersheds that have not undergone substantial changes in urban land-use levels since the 1970s.The increasing vehicle traffic associated with urban sprawl in the United States is frequently linked to degradation of air quality, but its effect on aquatic sediment is less well-recognized. This study evaluates trends in PAHs, a group of contaminants with multiple urban sources, in sediment cores from 10 reservoirs and lakes in six U.S. metropolitan areas. The watersheds chosen represent a range in degree and age of urbanization. Concentrations of PAHs in all 10 reservoirs and lakes increased during the past 20-40 years. PAH contamination of the most recently deposited sediment at all sites exceeded sediment-quality guidelines established by Environment Canada, in some cases by several orders of magnitude. These results add a new chapter to the story told by previous coring studies that reported decreasing concentrations of PAHs after reaching highs in the 1950s. Concurrent with the increase in concentrations is a change in the assemblage of PAHs that indicates the increasing trends are driven by combustion sources. The increase in PAH concentrations tracks closely with increases in automobile use, even in watersheds that have not undergone substantial changes in urban land-use levels since the 1970s.

Distribution of polychlorinated biphenyl residues in sediments and blue mussels (Mytilus galloprovincialis) from Port Elizabeth Harbour, South Africa.

PubMed

Kampire, E; Rubidge, G; Adams, J B

2015-02-15

Sediment and Mytilus galloprovincialis samples collected from the Port Elizabeth Harbour were analysed for six indicator PCB congeners to assess their contamination status. The concentrations of total PCBs in sediments and M. galloprovincialis ranged from 0.56 to 2.35 ng/g dry weight and 14.48 to 21.37 ng/g wet weight, respectively. Congeners 138 and 153 were dominant and accounted for an average of 29% and 24% of total PCBs in M. galloprovincialis; 32% and 30% in sediments, respectively. Sediments are home to a wide variety of aquatic life. None of the sediments analysed exceeded the PCB limits recommended the Canadian interim sediment quality guideline and the South African recommended sediment guidelines (21.6 ng/g). Both humans and aquatic life are sensitive to the toxic effects of PCBs. Copyright © 2014 Elsevier Ltd. All rights reserved.

Results of the basewide monitoring program at Wright-Patterson Air Force Base, Ohio, 1993-1994

USGS Publications Warehouse

Schalk, C.W.; Cunningham, W.L.

1996-01-01

Geologic and hydrologic data were collected at Wright-Patterson Air Force Base (WPAFB), Ohio, as part of Basewide Monitoring Program (BMP) that began in 1992. The BMP was designed as a long-term project to character ground-water and surface-water quality (including streambed sediments), describe water-quality changes as water enters, flows across, and exits the Base, and investigate the effects of activities at WPAFB on regional water quality. Ground water, surface ware, and streambed sediment were sampled in four rounds between August 1993 and September 1994 to provide the analytical data needed to address the objectives of the BMP. Surface-water-sampling rounds were designed to include most of the seasonal hydrologic conditions encountered in southwestern Ohio, including baseflow conditions and spring runoff. Ground-water-sampling rounds were scheduled for times of recession and recharfe. Ground-water data were used to construct water-table, potentiometric, and vertical gradient maps of the WPAFB area. Water levels have not changed significantly since 1987, but the effects of pumping on and near the Base can have a marked effect on water levels in localized areas. Ground-ware gradients generally were downward throughout Area B (the southwestern third of the Base) and in the eastern third of Areas A and C (the northeastern two-thirds of the Base), and were upward in the vicinity of Mad River. Stream-discharge measurements verified these gradients. Many of the U.S. Environmental Protection Agency maximum contaminant level (MCL) exceedances of inorganic constituents in ground water were associated with water from the bedrock. Exceedances of concentrations of chromium and nickel were found consistently in five wells completed in the glacial aquifer beneath the Base. Five organic compounds [trichloroethylene (TCE), tetrachloroethylene (PCE), vinyl chloride, benzene, and bis(2-ethylhexyl) phthalate] were detected at concentrations that exceeded MCLs; all of the TCE, PCE, and vinyl chloride exceedances were in water from glacial aquifer, whereas the benzene exceedance and most of the bis(2-ethylhexyl) phthalate exceedances were in water from the bedrock. TCE (16 exceedances) and PCE (11 exceedances) most frequently exceeded the MCLs and were detected in the most samples. A decrease in concentrations of inorganic and organic compounds with depth suggest that many constituents detected in ground-water samples are associated partly with human activities, in addition to their natural occurrence. Included in the list of these constituents are nickel, chromium, copper, lead vanadium, zinc, bromide, and nitrate. Many constituents are not found at depths greater than 60 to 80 feet, possibly indicating that human effects on ground-water quality are limited to shallow flow systems. Organic compounds detected in shallow or intermediate-depth wells were aligned mostly with flowpaths that pass through or near identified hazardous-waste sites. Few organic contaminants were detected in surface water. The only organic compound to exceed MCLs for drinking water was bis(2-ethylhexyl) phthalate, but it was detected at concentrations just above the MCL. Inorganic constituents detected at concentration exceeding MCLs include beryllium (twice), lead (once), thallium (once), and gross alpha radiation (once). No polycyclic aromatic (PAHs) were detected in surface-water samples. The highest concentrations of contaminants detected during a storm event were in samples from upgradient locations, indicating that off-Base sources may contribute to surface-water contamination. Inorganic and organic contaminants were found in streambed sediments at WPAFB, primarily in Areas A and C. Trace metals such as lead, mercury, arsenic, and cadmium were detected at 16 locations at concentrations considered 'elevated' according to a ranking scheme for sediments. PAHS were the organic compounds detected most frequently and in highest concentrations organo

Aquatic assessment of the Pike Hill Copper Mine Superfund site, Corinth, Vermont

USGS Publications Warehouse

Piatak, Nadine M.; Argue, Denise M.; Seal, Robert R.; Kiah, Richard G.; Besser, John M.; Coles, James F.; Hammarstrom, Jane M.; Levitan, Denise M.; Deacon, Jeffrey R.; Ingersoll, Christopher G.

2013-01-01

The Pike Hill Copper Mine Superfund site in Corinth, Orange County, Vermont, includes the Eureka, Union, and Smith mines along with areas of downstream aquatic ecosystem impairment. The site was placed on the U.S. Environmental Protection Agency (USEPA) National Priorities List in 2004. The mines, which operated from about 1847 to 1919, contain underground workings, foundations from historical structures, several waste-rock piles, and some flotation tailings. The mine site is drained to the northeast by Pike Hill Brook, which includes several wetland areas, and to the southeast by an unnamed tributary that flows to the south and enters Cookville Brook. Both brooks eventually drain into the Waits River, which flows into the Connecticut River. The aquatic ecosystem at the site was assessed using a variety of approaches that investigated surface-water quality, sediment quality, and various ecological indicators of stream-ecosystem health. The degradation of surface-water quality is caused by elevated concentrations of copper, and to a lesser extent cadmium, with localized effects caused by aluminum, iron, and zinc. Copper concentrations in surface waters reached or exceeded the USEPA national recommended chronic water-quality criteria for the protection of aquatic life in all of the Pike Hill Brook sampling locations except for the location farthest downstream, in half of the locations sampled in the tributary to Cookville Brook, and in about half of the locations in one wetland area located in Pike Hill Brook. Most of these same locations also contained concentrations of cadmium that exceeded the chronic water-quality criteria. In contrast, surface waters at background sampling locations were below these criteria for copper and cadmium. Comparison of hardness-based and Biotic Ligand Model (BLM)-based criteria for copper yields similar results with respect to the extent or number of stations impaired for surface waters in the affected area. However, the BLM-based criteria are commonly lower values than the hardness-based criteria and thus suggest a greater degree or magnitude of impairment at the sampling locations. The riffle-habitat benthic invertebrate richness and abundance data correlate strongly with the extent of impact based on water quality for both brooks. Similarly, the fish community assessments document degraded conditions throughout most of Pike Hill Brook, whereas the data for the tributary to Cookville Brook suggest less degradation to this brook. The sediment environment shows similar extents of impairment to the surface-water environment, with most sampling locations in Pike Hill Brook, including the wetland areas, and the tributary to Cookville Brook affected. Sediment impairment is caused by elevated copper concentrations, although localized degradation due to elevated cadmium and zinc concentrations was documented on the basis of exceedances of probable effects concentrations (PECs). In contrast to impairment determined by exceedances of PECs, equilibrium-partitioning sediment benchmarks (based on simultaneously extracted metals, acid volatile sulfides, and total organic carbon) predict no toxic effects in sediments at the background locations and uncertain toxic effects throughout Pike Hill Brook and the tributary to Cookville Brook, with the exception of the most downstream Cookville Brook location, which indicated no toxic effects. Acute laboratory toxicity testing using the amphipod Hyalella azteca and the midge Chironomus dilutus on pore waters extracted from sediment in situ indicate impairment (based on tests with H. azteca) at only one location in Pike Hill Brook and no impairment in the tributary to Cookville Brook. Chronic laboratory sediment toxicity testing using H. azteca and C. dilutus indicated toxicity in Pike Hill Brook at several locations in the lower reach and two locations in the tributary to Cookville Brook. Toxicity was not indicated for either species in sediment from the most acidic metal-rich location, likely due to the low lability of copper in that sediment, as indicated by a low proportion of extractable copper (simultaneously extracted metal (SEM) copper only 5 percent of total copper) and due to the flushing of acidic metal-rich pore water from experimental chambers as overlying test water was introduced before and replaced periodically during the toxicity tests. Depositional habitat invertebrate richness and abundance data generally agreed with the results of toxicity tests and with the extent of impact in the watersheds on the basis of sediment and pore waters. The information was used to develop an overall assessment of the impact of mine drainage on the aquatic system downstream from the Pike Hill copper mines. Most of Pike Hill Brook, including several wetland areas that are all downstream from the Eureka and Union mines, was found to be impaired on the basis of water-quality data and biological assessments of fish or benthic invertebrate communities. In contrast, only one location in the tributary to Cookville Brook, downstream from the Smith mine, is definitively impaired. The biological community begins to recover at the most downstream locations in both brooks due to natural attenuation from mixing with unimpaired streams. On the basis of water quality and biological assessment, the reference locations were of good quality. The sediment toxicity, chemistry, and aquatic community survey data suggest that the sediments could be a source of toxicity in Pike Hill Brook and the tributary to Cookville Brook. On the basis of water quality, sediment quality, and biologic communities, the impacts of mine drainage on the aquatic ecosystem health of the watersheds in the study area are generally consistent with the toxicity suggested from laboratory toxicity testing on pore water and sediments.

Water-quality assessment of the Ozark Plateaus study unit, Arkansas, Kansas, Missouri, and Oklahoma- summary of information on pesticides, 1970-90

USGS Publications Warehouse

Bell, Richard W.; Joseph, Robert L.; Freiwald, David A.

1996-01-01

Historical pesticide data from 1970-90 were compiled for 140 surface-water, 92 ground-water, 55 streambed-sediment, and 120 biological-tissue sampling sites within the Ozark Plateaus National Water-Quality Assessment Program study unit. Surface-water, bed-sediment, and biological-tissue sites have drainage basins predominantly in the Springfield and Salem Plateaus; ground-water sites are predominantly located in the Osage Plains and Mississippi Alluvial Plain. Many sites were sampled only once or twice during this period. A large percentage of the samples were collected in the mid-1970's and early 1980's for surface water, 1990 for ground water, the late 1980's for surface water, 1990 for ground water, the late 1980's for bed sediment, and the early 1980's for biological tissue. Pesticide use was approximately 4.2 million pounds per year of active ingredients from 1982-85 in the study unit and was generally greatest in the Springfield and Salem Plateaus pasturelands and in the Osage Plains and Mississippi Alluvial Plain cropland areas. The most frequently applied pesticide in the study unit was 2,4-D. Alachlor was the second most applied pesticide. Corn, pasture, rice, sorghum, and soybeans received approximately 90 percent of the pesticides applied within the study unit. The highest pesticide application rate per acre occurred on these crops in the Osage Plains and Mississippi Alluvial Plain. Pastureland was the predominant crop type in 50 of the 94 counties in the study unit. Toxaphene, the pesticide having the most number of detections in surface water, was found in 17 of 866 samples from 5 of 112 sites. Concentrations ranged from 0.1 to 6.0 micrograms per liter. Six other pesticides or pesticide metabolites were detected in 12 or more surface-water samples: DDE, dieldrin, DDT, aldrin, 2,4-D, and lindane. The maximum concentration for these pesticides was less than 1.0 micrograms per liter. Atrazine, the pesticide having the most number of detections in ground water, was found in 15 of 95 samples from 15 of 79 wells with concentrations ranging from 0.1 to 8.2 micrograms per liter. Metolachlor, alachlor, and prometon were detected more than once with maximum concentrations less than 1.0 micrograms per liter, except for prometon (2.4 micrograms per liter). Chlordane was the pesticide having the most number of detections in bed sediment and biological tissue. Chlordane was detected in 12 of 73 samples from 10 of 45 bed-sediment sites with concentrations ranging from 2.0 to 240 micrograms per kilogram. In biological tissue, chlordane was found in 93 of 151 samples from 39 of 53 sites with concentrations ranging from 0.009 to 8.6 milligrams per kilogram. Other pesticides or pesticide metabolites detected more than once in bed sediment include DDT, DDD, p,p'-DDE, DDE, and hexachlorobenzene and in biological tissue include DDT, p,p'-DDE, and hexachlorobenzene. Quality criteria or standards have been established for 15 of the pesticides detected in the study unit. For surface-water samples, the drinking water maximum contaminant level for alachlor was exceeded in one sample from one site in 1982. For ground-water samples, the drinking water maximum contaminant level for atrazine was exceeded in four samples from four wells in 1990. For biological-tissue samples collected during the years 1982-89, the fish tissue action levels for chlordane (19 sites; 26 samples), heptachlor epoxide (3 sites; 3 samples), p,p'-DDE (2 sites; 2 samples), dieldrin (2 sites, 2 samples), and mirex (1 site; 1 sample) were exceeded. For bed-sediment samples, quality criteria or standards were not exceeded for any pesticide. Pesticides do not pose any widespread or persistent problems in the study unit, based on the limited number of samples that exceeded quality criteria and standards.

Historical trends in organochlorine compounds in river basins identified using sediment cores from reservoirs

USGS Publications Warehouse

Van Metre, P.C.; Callender, E.; Fuller, C.C.

1997-01-01

This study used chemical analyses of dated sediment cores from reservoirs to define historical trends in water quality in the influent river basins. This work applies techniques from paleolimnology to reservoirs, and in the process, highlights differences between sediment-core interpretations for reservoirs and natural lakes. Sediment cores were collected from six reservoirs in the central and southeastern United States, sectioned, and analyzed for 137Cs and organochlorine compounds. 137Cs analyses were used to demonstrate limited post-depositional mixing, to indicate sediment deposition dates, and to estimate sediment focusing factors. Relative lack of mixing, high sedimentation rates, and high focusing factors distinguish reservoir sediment cores from cores collected in natural lakes. Temporal trends in concentrations of PCBs, total DDT (DDT + DDD + DDE), and chlordane reflect historical use and regulation of these compounds and differences in land use between reservoir drainages. PCB and total DDT core burdens, normalized for sediment focusing, greatly exceed reported cumulative regional atmospheric fallout of PCBs and total DDT estimated using cores from peat hogs and natural lakes, indicating the dominance of fluvial inputs of both groups of compounds to the reservoirs.This study used chemical analyses of dated sediment cores from reservoirs to define historical trends in water quality in the influent river basins. This work applies techniques from paleolimnology to reservoirs, and in the process, highlights differences between sediment-core interpretations for reservoirs and natural lakes. Sediment cores were collected from six reservoirs in the central and southeastern United States, sectioned, and analyzed for 137Cs and organochlorine compounds. 137Cs analyses were used to demonstrate limited post-depositional mixing, to indicate sediment deposition dates, and to estimate sediment focusing factors. Relative lack of mixing, high sedimentation rates, and high focusing factors distinguish reservoir sediment cores from cores collected in natural lakes. Temporal trends in concentrations of PCBs, total DOT (DDT+DDD+DDE), and chlordane reflect historical use and regulation of these compounds and differences in land use between reservoir drainages. PCB and total DDT core burdens, normalized for sediment focusing, greatly exceed reported cumulative regional atmospheric fallout of PCBs and total DDT estimated using cores from peat bogs and natural lakes, indicating the dominance of fluvial inputs of both groups of compounds to the reservoirs.

Water-quality and biological conditions in the Lower Boise River, Ada and Canyon Counties, Idaho, 1994-2002

USGS Publications Warehouse

MacCoy, Dorene E.

2004-01-01

The water quality and biotic integrity of the lower Boise River between Lucky Peak Dam and the river's mouth near Parma, Idaho, have been affected by agricultural land and water use, wastewater treatment facility discharge, urbanization, reservoir operations, and river channel alteration. The U.S. Geological Survey (USGS) and cooperators have studied water-quality and biological aspects of the lower Boise River in the past to address water-quality concerns and issues brought forth by the Clean Water Act of 1977. Past and present issues include preservation of beneficial uses of the river for fisheries, recreation, and irrigation; and maintenance of high-quality water for domestic and agricultural uses. Evaluation of the data collected from 1994 to 2002 by the USGS revealed increases in constituent concentrations in the lower Boise in a downstream direction. Median suspended sediment concentrations from Diversion Dam (downstream from Lucky Peak Dam) to Parma increased more than 11 times, nitrogen concentrations increased more than 8 times, phosphorus concentrations increased more than 7 times, and fecal coliform concentrations increased more than 400 times. Chlorophyll-a concentrations, used as an indicator of nutrient input and the potential for nuisance algal growth, also increased in a downstream direction; median concentrations were highest at the Middleton and Parma sites. There were no discernible temporal trends in nutrients, sediment, or bacteria concentrations over the 8-year study. The State of Idaho?s temperature standards to protect coldwater biota and salmonid spawning were exceeded most frequently at Middleton and Parma. Suspended sediment concentrations exceeded criteria proposed by Idaho Department of Environmental Quality most frequently at Parma and at all but three tributaries. Total nitrogen concentrations at Glenwood, Middleton, and Parma exceeded national background levels; median flow-adjusted total nitrogen concentrations at Middleton and Parma were higher than those in undeveloped basins sampled nationwide by the USGS. Total phosphorus concentrations at Glenwood, Middleton, and Parma also exceeded those in undeveloped basins. Macroinvertebrate and fish communities were used to evaluate the long-term integration of water-quality contaminants and loss of habitat in the lower Boise. Biological integrity of the macroinvertebrate population was assessed with the attributes (metrics) of Ephemeroptera, Plecoptera, and Trichoptera (EPT) richness and metrics used in the Idaho River Macroinvertebrate Index (RMI): taxa richness; EPT richness; percent dominant taxon; percent Elmidae (riffle beetles); and percent predators. Average EPT was about 10, and RMI scores were frequently below 16, which indicated intermediate or poor water quality. The number of EPT taxa and RMI scores for the lower Boise were half those for least-impacted streams in Idaho. The fine sediment bioassessment index (FSBI) was used to evaluate macroinvertebrate sediment tolerance. The FSBI scores were lower than those for a site upstream in the Boise River Basin near Twin Springs, a site not impacted by urbanization and agriculture, which indicated that the lower Boise macroinvertebrate population may be impacted by fine sediment. Macroinvertebrate functional feeding groups and percent tolerant species, mainly at Middleton and Parma, were typical of those in areas of degraded water quality and habitat. The biological integrity of the fish population was evaluated using the Idaho River Fish Index (RFI), which consists of the 10 metrics: number of coldwater native species, percent sculpin, percent coldwater species, percent sensitive native individuals, percent tolerant individuals, number of nonindigenous species, number of coldwater fish captured per minute of electrofishing, percent of fish with deformities (eroded fins, lesions, or tumors), number of trout age classes, and percent carp. RFI scores for lower Boise sites indicated a d

Production of Hexagenia limbata nymphs in contaminated sediments in the Upper Great Lakes connecting channels

USGS Publications Warehouse

Edsall, Thomas A.; Manny, Bruce A.; Schloesser, Donald W.; Nichols, Susan J.; Frank, Anthony M.

1991-01-01

In April through October 1986, we sampled sediments and populations of nymphs of the burrowing mayfly, Hexagenia limbata (Serville), at 11 locations throughout the connecting channels of the upper Great Lakes, to determine if sediment contaminants adversely affected nymph production. Production over this period was high (980 to 9231 mg dry wt m-2) at the five locations where measured sediment levels of oil, cyanide, and six metals were below the threshold criteria of the U.S. Environmental Protection Agency and the Ontario Ministry of Environment for contaminated or polluted sediments, and also where the criterion for visible oil given in the Water Quality Agreement between the U.S.A. and Canada for connecting waters of the Great Lakes was not exceeded. At the other six locations where sediments were polluted, production was markedly lower (359 to 872 mg dry wt m-2). This finding is significant because it indicates that existing sediment quality criteria can be applied to protect H. limbata from oil, cyanide, and metals in the Great Lakes and connecting channels where the species fulfills a major role in secondary production and trophic transfer of energy.

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the American Falls Reservoir area, Idaho, 1988-89. Water Resources Investigation

DOE Office of Scientific and Technical Information (OSTI.GOV)

Low, W.H.; Mullins, W.H.

1990-01-01

The report presents results of a reconnaissance investigation to determine whether potentially toxic concentrations of selected trace elements or organochlorine compounds associated with irrigation drainage exist in surface and ground water, bottom sediment, aquatic plants, benthic invertebrates, fish, and waterbirds in the American Falls Reservoir area. American Falls Reservoir was selected for investigation in part because several previous investigations of fish in the reservoir indicated that mercury and cadmium concentrations exceeded human health standards and periodic botulism-related die-offs of waterbirds have been known to occur. Also, rocks south and southeast of the reservoir contain naturally occurring selenium concentrations many timesmore » greater than those in the continental crust. Samples of water, bottom sediment, aquatic plants, benthic invertebrates, fish, and waterbirds were collected from nine sites in the American Falls Reservoir area. The samples were analyzed for selected inorganic and organic constituents to determine whether concentrations exceeded known standards or criteria.« less

Assessment of water quality, road runoff, and bulk atmospheric deposition, Guanella Pass area, Clear Creek and Park Counties, Colorado, water years 1995-97

USGS Publications Warehouse

Stevens, Michael R.

2001-01-01

The Guanella Pass road, located about 40 miles west of Denver, Colorado, between the towns of Georgetown and Grant, has been designated a scenic byway and is being considered for reconstruction. The purpose of this report is to present an assessment of hydrologic and water-quality conditions in the Guanella Pass area and provide baseline data for evaluation of the effects of the proposed road reconstruction. The data were collected during water years 1995-97 (October 1, 1995, to September 30, 1997).Based on Colorado water-quality standards, current surface-water quality near Guanella Pass road was generally acceptable for specified use classifications of recreation, water supply, agriculture, and aquatic life. Streams had small concentrations of dissolved solids, nutrients, trace elements, and suspended sediment. An exception was upper Geneva Creek, which was acidic and had relatively large concentrations of iron, zinc, and other trace elements related to acid-sulfate weathering. Concentrations of many water-quality constituents, especially particle-related phases and suspended sediment, increased during peak snowmelt and rainstorm events and decreased to prerunoff concentrations at the end of runoff periods. Some dissolved (filtered) trace-element loads in Geneva Creek decreased during rainstorms when total recoverable loads remained generally static or increased, indicating a phase change that might be explained by adsorption of trace elements to suspended sediment during storm runoff.Total recoverable iron and dissolved zinc exceeded Colorado stream-water-quality standards most frequently. Exceedances for iron generally occurred during periods of high suspended-sediment transport in several streams. Zinc standards were exceeded in about one-half the samples collected in Geneva Creek 1.5 miles upstream from Grant.Lake-water quality was generally similar to that of area streams. Nitrogen and phosphorus ratios calculated for Clear and Duck Lakes indicated that phytoplankton in the lakes were probably phosphorus-limited. Measures of trophic status (secchi depth, total phosphorus, and chlorophyll-a) indicated that Duck and Clear Lakes were oligotrophic in 1997.Ground water had relatively low specific conductance (range 24 to 584 microsiemens per centimeter) and did not exceed U.S. Environmental Protection Agency drinking-water standards, except for samples collected from a single well, which exceeded the Proposed Maximum Contaminant Level for uranium.Runoff from the Guanella Pass road enters streams through surface channels connected to culverts and roadside ditches. Fifty-six percent of the total number of culvert and roadside-ditch drainage features on the Guanella Pass road showed evidence of recent surface runoff connection to an adjacent stream. Road runoff is generated during snowmelt and during summer rainstorms.At a road cross-drain culvert monitored continuously for discharge (water years 1996-97), most runoff (77 to 96 percent) was a result of snowmelt, and runoff from the road preceded the basinwide peak streamflow, resulting in sediment and water-quality constituent inputs to the stream when the stream?s capacity for dilution of the road runoff was low. Specific conductance of road-runoff samples ranged from 14 to 468 microsiemens per centimeter. Major-ion composition of some samples indicated effects from deicing salt (sodium chloride) and dust inhibitor (magnesium chloride) applied to sections of the road, but changes in the stream concentrations that might be attributed to the runoff were brief and relatively small.Nutrients were commonly measured in road-runoff samples at larger concentrations than in streamflow. Concentrations of nitrate and ammonia, especially during rainfall-generated road runoff, were more similar to the concentrations in precipitation than to the concentrations in stream water. Concentrations of ammonia plus organic nitrogen (total as N) (range less than 0.2 to 24 milligrams per liter) and t

Organic Compounds and Trace Elements in Fish Tissue and Bed Sediment in the Delaware River Basin, New Jersey, Pennsylvania, New York, and Delaware, 1998-2000

USGS Publications Warehouse

Romanok, Kristin M.; Fischer, Jeffrey M.; Riva-Murray, Karen; Brightbill, Robin; Bilger, Michael

2006-01-01

As part of the National Water-Quality Assessment (NAWQA) program activities in the Delaware River Basin (DELR), samples of fish tissue from 21 sites and samples of bed sediment from 35 sites were analyzed for a suite of organic compounds and trace elements. The sampling sites, within subbasins ranging in size from 11 to 600 square miles, were selected to represent 5 main land-use categories in the DELR -forest, low-agricultural, agricultural, urban, and mixed use. Samples of both fish tissue and bed sediment were also collected from 4 'large-river' sites that represented drainage areas ranging from 1,300 to 6,800 square miles, areas in which the land is used for a variety of purposes. One or more of the organochlorine compounds-DDT and chlordane metabolites, polychlorinated biphenyls (total PCBs), and dieldrin- were detected frequently in samples collected over a wide geographic area. One or more of these compounds were detected in fish-tissue samples from 92 percent of the sites and in bed-sediment samples from 82 percent of the sites. Concentrations of total DDT, total chlordanes, total PCBs, and dieldrin in whole white suckers and in bed sediment were significantly related to urban/industrial basin characteristics, such as percentage of urban land use and population density. Semi-volatile organic compounds (SVOCs)-total polycyclic aromatic hydrocarbons (PAHs), total phthalates, and phenols- were detected frequently in bed-sediment samples. All three types of SVOCs were detected in samples from at least one site in each land-use category. The highest detection rates and concentrations typically were in samples from sites in the urban and mixed land-use categories, as well as from the large-river sites. Concentrations of total PAHs and total phthalates in bed-sediment samples were found to be statistically related to percentages of urban land use and to population density in the drainage areas represented by the sampling sites. The samples of fish tissue and bed sediment collected throughout the DELR were analyzed for a large suite of trace elements, but results of the analyses for eight elements-arsenic, cadmium, chromium, copper, lead, nickel, mercury, and zinc- that are considered contaminants of concern are described in this report. One or more of the eight trace elements were detected in samples from every fish tissue and bed-sediment sampling site, and all of the trace elements were detected in samples from 97 percent of the bed-sediment sites. The concentrations of organic compounds and trace elements in the DELR samples were compared to applicable guidelines for the protection of wildlife and other biological organisms. Concentrations of total DDT, total chlordanes, total PCBs, and dieldrin in fish-tissue samples from 14 sites exceeded one or more of the Wildlife Protective Guidelines established by the New York State Department of Environmental Conservation. Concentrations of one or more organic compounds in samples from 16 bed-sediment sites exceeded the Threshold Effects Concentrations (TEC) of the Canadian Sediment Quality Guidelines, and concentrations of one or more of the eight trace elements in samples from 38 bed-sediment sites exceeded the TEC. (The TEC is the concentration below which adverse biological effects in freshwater ecosystems are expected to be rare.) Concentrations of organic compounds in samples from some bed-sediment sites exceeded the Canadian Probable Effects Concentrations (PEC), and concentrations of trace elements in samples from 18 sites exceeded the PEC. (The PEC is the concentration above which adverse effects to biological organisms are expected to occur frequently). Concentrations of organic compounds and trace elements in samples from the DELR were compared to similar data from other NAWQA study units in the northeastern United States and also data from the Mobile River (Alabama) Basin and the Northern Rockies Intermontane Basin study units. Median concentrations of to

Spatiotemporal assessment (quarter century) of pulp mill metal(loid) contaminated sediment to inform remediation decisions.

PubMed

Hoffman, Emma; Lyons, James; Boxall, James; Robertson, Cam; Lake, Craig B; Walker, Tony R

2017-06-01

A bleached kraft pulp mill in Nova Scotia has discharged effluent wastewater into Boat Harbour, a former tidal estuary within Pictou Landing First Nation since 1967. Fifty years of effluent discharge into Boat Harbour has created >170,000 m 3 of unconsolidated sediment, impacted by inorganic and organic contaminants, including metal[loid]s, polycyclic aromatic hydrocarbons (PAHs), dioxins, and furans. This study aimed to characterize metal(loid)-impacted sediments to inform decisions for a $89 million CAD sediment remediation program. The remediation goals are to return this impacted aquatic site to pre-mill tidal conditions. To understand historical sediment characteristics, spatiotemporal variation covering ~quarter century, of metal(loid) sediment concentrations across 103 Boat Harbour samples from 81 stations and four reference locations, were assessed by reviewing secondary data from 1992 to 2015. Metal(loid) sediment concentrations were compared to current Canadian freshwater and marine sediment quality guidelines (SQGs). Seven metal(loid)s, As, Cd, Cr, Cu, Pb, Hg, and Zn, exceeded low effect freshwater and marine SQGs; six, As, Cd, Cr, Pb, Hg, and Zn, exceeded severe effect freshwater SQGs; and four, Cd, Cu, Hg, and Zn, exceeded severe effect marine SQGs. Metal(loid) concentrations varied widely across three distinct temporal periods. Significantly higher Cd, Cu, Pb, Hg, and Zn concentrations were measured between 1998 and 2000, compared to earlier, 1992-1996 and more recent 2003-2015 data. Most samples, 69%, were shallow (0-15 cm), leaving deeper horizons under-characterized. Geographic information system (GIS) techniques also revealed inadequate spatial coverage, presenting challenges for remedy decisions regarding vertical and horizontal delineation of contaminants. Review of historical monitoring data revealed that gaps still exist in our understanding of sediment characteristics in Boat Harbour, including spatial, vertical and horizontal, and temporal variation of sediment contamination. To help return Boat Harbour to a tidal estuary, more detailed sampling is required to better characterize these sediments and to establish appropriate reference (background) concentrations to help develop cost-effective remediation approaches for this decades-old problem.

Water quality and benthic macroinvertebrate bioassessment of Gallinas Creek, San Miguel County, New Mexico, 1987-90

USGS Publications Warehouse

Garn, H.S.; Jacobi, G.Z.

1996-01-01

Upper Gallinas Creek in north-central New Mexico serves as the public water supply for the City of Las Vegas. The majority of this 84-square-mile watershed is within national forest lands managed by the U.S. Forest Service. In 1985, the Forest Service planned to conduct timber harvesting in the headwaters of Gallinas Creek. The City of Las Vegas was concerned about possible effects from logging on water quality and on water-supply treatment costs. The U.S. Geological Survey began a cooperative study in 1987 to (1) assess the baseline water-quality characteristics of Gallinas Creek upstream from the Las Vegas water-supply diversion, (2) relate water quality to State water- quality standards, and (3) determine possible causes for spatial differences in quality. During 1987-90, water-quality constituents and aquatic benthic macroinvertebrates were collected and analyzed at five sampling sites in the watershed. Specific conductance, pH, total hardness, total alkalinity, and calcium concentrations increased in a downstream direction, probably in response to differences in geology in the watershed. The water-quality standard for temperature was exceeded at the two most downstream sites probably due to a lack of riparian vegetation and low streamflow conditions. The standards for pH and turbidity were exceeded at all sites except the most upstream one. Concentrations of nitrogen species and phosphorus generally were small at all sites. The maximum total nitrogen concentration of 2.1 milligrams per liter was at the mouth of Porvenir Canyon; only one sample at this site exceeded the water-quality standard for total inorganic nitrogen. At each of the sites, 10 to 15 percent of the samples exceeded the total phosphorus standard of less than 0.1 milligram per liter. Except for aluminum and iron, almost all samples tested for trace elements contained concentrations less than the laboratory detection limit. No trace-element concentrations exceeded the State standard for domestic water supplies. Suspended-sediment concentrations appeared to increase with distance downstream; suspended sediment increased significantly from the uppermost site to the second site near the national forest boundary, most probably caused by runoff from the unpaved forest road adjacent to Gallinas Creek. The aquatic macroinvertebrate assessment indicated that the three upstream sites had good biological conditions and were nonimpaired, whereas the two downstream sites had lowered biological conditions and were slightly impaired. The water- quality and biological assessments provided similar results.

Organochlorine compounds in streambed sediment and in biological tissue from streams and their relations to land use, central Arizona

USGS Publications Warehouse

Gebler, Joseph B.

2000-01-01

Streambed-sediment samples from 13 sites and biological-tissue samples from 11 sites in the Gila River Basin in central Arizona were analyzed for 32 organochlorine compounds in streambed sediment and 28 compounds in biological tissue during 1996 as part of the U.S. Geological Survey's National Water-Quality Assessment program. The objectives of the study were to determine the occurrence and distribution of organochlorine compounds and their relation to land use. Sampling sites were categorized on the basis of major land uses in the basin or the source of water in the stream. Because land uses were mixed or had changed over time, some land-use categories were combined. Sites were categorized as forest/rangeland (6), forest/urban (1), urban (4), or agricultural/urban (2). Thirteen organochlorine compounds were detected in streambed-sediment samples, and 10 were detected in tissue samples. The number of compounds found in streambed-sediment samples from individual sites ranged from 0 to 10, and the range for individual tissue samples was 0 to 7. Comparison of the number of detections in streambed-sediment samples to the number of detections in tissue samples from particular sites where both were sampled yielded five instances where more compounds were detected in streambed sediment, six instances where more compounds were detected in tissue, and five instances where the number of detections in streambed sediment and tissue were equal. The frequency of detection of particular compounds for sites where both streambed sediment and tissue were sampled resulted in five compounds being detected more frequently in streambed sediment, five more frequently in tissue, and three compounds that were equally frequent in streambed sediment and in tissue. Few contaminants were detected in samples from the forest/rangeland sites; greater numbers of compounds were detected at the urban sites and at the forest/urban site. The greatest number of compounds and the highest concentrations of many contaminants were detected at agriculture/urban sites. The compound detected most frequently in streambed-sediment and tissue samples was p,p'-DDE. Streambed-sediment guideline values for the protection of aquatic life for p,p'-DDE and total DDT were exceeded at both agricultural/urban sites, The streambed-sediment guideline value for the protection of aquatic life for total chlordane was exceeded at one agricultural/urban site, one urban site, and the forest/urban site. The streambed-sediment guideline value for the protection of aquatic life for total PCB’s was exceeded at one agricultural/urban site. Guideline values for the protection of fish-eating wildlife for total DDT and for toxaphene were exceeded only in samples from the two agricultural/urban sites. The guideline value for the protection of fish-eating wildlife for total PCB’s was equaled or exceeded in samples from two sites—one urban and one agricultural/urban site. Screening values established by the U.S. Environmental Protection Agency for the protection of human health for edible portions of fish were exceeded by total DDT and by toxaphene in fish-tissue samples from both agricultural/urban sites. The human-health criterion for total PCB’s was exceeded in two fish-tissue samples from an agricultural site and from an urban site. Tissue samples analyzed in this study were for whole fish, and thus, concentration data are not entirely comparable to the screening values of the U.S. Environmental Protection Agency. Because these exceedences were an order of magnitude above the criteria, however, it is possible that concentrations in the edible portions of fish from these locations could present a human- health risk. Analyses of samples of edible portions of fish from these locations would be needed to adequately assess the presence or absence of a human-health risk. The similarity of the results of this study to the results of other studies of organochlorine compounds in the environment suggests that there is a correlation between contaminants in sediment and biological-tissue samples and land uses. As with other studies of the occurrence and distribution of organochlorine contaminants in streambed sediments and biological tissue, this study shows that many organochlorine compounds continue to persist in the environment and thus could pose a threat to aquatic life, fish-eating wildlife, and possibly to humans who consume contaminated fish.

Environmental quality in sediments of Cadiz and Algeciras Bays based on a weight of evidence approach (southern Spanish coast).

PubMed

Usero, José Antonio; Rosado, Daniel; Usero, José; Morillo, José

2016-09-15

This research applies an integrated sediment quality assessment method using a weight of evidence approach to Cadiz and Algeciras Bays (southern Spain). The method is composed of several analyses (particle size profile, aqua regia extractable metals, acid labile metals, total organic carbon, toxicity bioassay with Photobacterium phosphoreum and macrobenthic community alteration). The proposed method provides a single result, the environmental degradation index (EDI). EDI defined samples as low degraded (outer areas of both bays) and moderately degraded (Inner Bay of Cadiz Bay, the surroundings of Algeciras port and the northern part of Algeciras Bay). These samples showed the highest concentration of aqua regia extractable metals, which exceeded effects range-low (ERL) for Zn (51-176mg/l), Cu (11-54mg/l), As (4.3-9.5mg/l), Hg (0.17-0.28mg/l), Ni (23-82mg/l), and. Cr (37-134mg/l). They also exceeded some quality criteria for total organic carbon (4.0-6.5%) and toxicity (120-240TU/g) and showed poor results for macrobenthic community. Copyright © 2016 Elsevier Ltd. All rights reserved.

Ecological risk of heavy metals in sediments of the Luan River source water.

PubMed

Liu, Jingling; Li, Yongli; Zhang, Bao; Cao, Jinling; Cao, Zhiguo; Domagalski, Joseph

2009-08-01

Distribution and characteristics of heavy metals enrichment in sediment were surveyed including the bio-available form analyzed for assessment of the Luan River source water quality. The approaches of sediment quality guidelines (SQG), risk assessment code and Hakanson potential ecological risk index were used for the ecological risk assessment. According to SQG, The results show that in animal bodies, Hg at the sampling site of Wuliehexia was 1.39 mg/kg, Cr at Sandaohezi was 152.37 mg/kg and Cu at Hanjiaying was 178.61 mg/kg exceeding the severe effect screening level. There were 90% of sampling sites of Cr and Pb and 50% sites of Cu exceeded the lowest effect screening level. At Boluonuo and Wuliehexia, the exchangeable and carbonate fractions for above 50% of sites were at high risk levels and that for above 30% of sites at Xiahenan and Wulieheshang were also at high risk levels. Other sites were at medium risk level. Compared to soil background values of China, Hg and Cd showed very strong ecological risk, and the seven heavy metals of Hg, Cd, Cu, As, Pb, Cr, Zn at ecological risk levels were in the descending order. The results could give insight into risk assessment of environmental pollution and decision-making for water source security.

Heavy metal contamination in an urban stream fed by contaminated air-conditioning and stormwater discharges.

PubMed

O'Sullivan, Aisling; Wicke, Daniel; Cochrane, Tom

2012-03-01

Urban waterways are impacted by diffuse stormwater runoff, yet other discharges can unintentionally contaminate them. The Okeover stream in Christchurch, New Zealand, receives air-conditioning discharge, while its ephemeral reach relies on untreated stormwater flow. Despite rehabilitation efforts, the ecosystem is still highly disturbed. It was assumed that stormwater was the sole contamination source to the stream although water quality data were sparse. We therefore investigated its water and sediment quality and compared the data with appropriate ecotoxicological thresholds from all water sources. Concentrations of metals (Zn, Cu and Pb) in stream baseflow, stormwater runoff, air-conditioning discharge and stream-bed sediments were quantified along with flow regimes to ascertain annual contaminant loads. Metals were analysed by ICP-MS following accredited techniques. Zn, Cu and Pb concentrations from stormflow exceeded relevant guidelines for the protection of 90% of aquatic species by 18-, 9- and 5-fold, respectively, suggesting substantial ecotoxicity potential. Sporadic copper (Cu) inputs from roof runoff exceeded these levels up to 3,200-fold at >4,000 μg L⁻¹ while Cu in baseflow from air-conditioning inputs exceeded them 5.4-fold. There was an 11-fold greater annual Cu load to the stream from air-conditioning discharge compared to stormwater runoff. Most Zn and Cu were dissolved species possibly enhancing metal bioavailability. Elevated metal concentrations were also found throughout the stream sediments. Environmental investigations revealed unsuspected contamination from air-conditioning discharge that contributed greater Cu annual loads to an urban stream compared to stormwater inputs. This discovery helped reassess treatment strategies for regaining ecological integrity in the ecosystem.

[Distribution Characteristics and Pollution Status Evaluation of Sediments Nutrients in a Drinking Water Reservoir].

PubMed

Huang, Ting-lin; Liu, Fei; Shi, Jian-chao

2016-01-15

The main purpose of this paper is to illustrate the influence of nutrients distribution in sediments on the eutrophication of drinking water reservoir. The sediments of three representative locations were field-sampled and analyzed in laboratory in March 2015. The distribution characteristics of TOC, TN and TP were measured, and the pollution status of sediments was evaluated by the comprehensive pollution index and the manual for sediment quality assessment. The content of TOC in sediments decreased with depth, and there was an increasing trend of the nitrogen content. The TP was enriched in surface sediment, implying the nutrients load in Zhoucun Reservoir was aggravating as the result of human activities. Regression analysis indicated that the content of TOC in sediments was positively correlated with contents of TN and TP in sediments. The TOC/TN values reflected that the vascular land plants, which contain cellulose, were the main source of organic matter in sediments. The comprehensive pollution index analysis result showed that the surface sediments in all three sampling sites were heavily polluted. The contents of TN and TP of surface sediments in three sampling sites were 3273-4870 mg x kg(-1) and 653-2969 mg x kg(-1), and the content of TOC was 45.65-83.00 mg x g(-1). According to the manual for sediment quality assessment, the TN, TP and TOC contents in sediments exceed the standard values for the lowest level of ecotoxicity, so there is a risk of eutrophication in Zhoucun Reservoir.

Use of spatial statistics and isotopic tracers to measure the influence of arsenical pesticide use on stream sediment chemistry in New England, USA

USGS Publications Warehouse

Robinson, G.R.; Ayuso, R.A.

2004-01-01

Arsenical pesticides and herbicides, principally Pb arsenate, Ca arsenate, and Na arsenate with lesser use of other metal-As pesticides, were widely applied on apple, blueberry, and potato crops in New England during the first half of the twentieth century. Agricultural census data for this time period is used to define an agricultural index that identifies areas that are inferred to have used arsenical pesticides extensively. Factor analysis on metal concentrations in 1597 stream sediment samples collected throughout New England, grouped by agricultural-index categories, indicate a positive association of areas with stream sediment sample populations that contain higher As and Pb concentrations than samples from the region as a whole with sample site settings having high agricultural-index values. Population statistics for As and Pb concentrations and factor scores for an As-Pb factor all increase systematically and significantly with increasing agricultural-index intensity in the region, as tested by Kruskal-Wallis analysis. Lead isotope compositions for 16 stream sediments from a range of agricultural-index settings generally overlap the observed variation in rock sulfides and their weathering products; however, sediments collected from high agricultural-index settings have slightly more radiogenic Pb compositions, consistent with an industrial Pb contribution to these samples. Although weathering products from rocks are likely to be the dominant source of As and metals to most of the stream sediment samples collected in the region, the widespread use of arsenical pesticides and herbicides in New England during the early 1900-1960s appears to be a significant anthropogenic source of As and metals to many sediments in agricultural areas in the region and has raised background levels of As in some regions. Elevated concentrations of As in stream sediments are of concern for two reasons. Stream sediments with elevated As concentrations delineate areas with elevated background concentrations of As from both natural rock and anthropogenic sources that may contribute As to groundwater systems used for drinking water supplies. Conversion of agricultural land contaminated with arsenical pesticide residues to residential development may increase the likelihood that humans will be exposed to As. In addition, many stream sediment sites have As concentrations that exceed sediment quality guidelines established for freshwater ecosystems. Thirteen percent of the New England sediment sample sites exceed 9.79 mg/kg As, the threshold effects concentration (TEC), below which harmful effects are unlikely to be observed. Arsenic concentrations exceed 33 mg/kg, the probable effects concentration (PEC), above which harmful effects on sediment-dwelling organisms are expected to occur frequently, at 1.25% of the sediment sample sites. The sample sites that exceed the PEC value occur predominately in agricultural areas that used arsenical pesticides.

Occurrence and concentrations of selected trace elements, halogenated organic compounds, and polycyclic aromatic hydrocarbons in streambed sediments and results of water-toxicity testing in Westside Creeks and the San Antonio River, San Antonio, Texas, 2014

USGS Publications Warehouse

Crow, Cassi L.; Wilson, Jennifer T.; Kunz, James L.

2016-12-01

Sediment samples and samples for water-toxicity testing were collected during 2014 from several streams in San Antonio, Texas, known locally as the Westside Creeks (Alazán, Apache, Martínez, and San Pedro Creeks) and from the San Antonio River. Samples were collected during base flow and after periods of stormwater runoff (poststorm conditions) to determine baseline sediment- and water-quality conditions. Streambed-sediment samples were analyzed for selected constituents, including trace elements and organic contaminants such as pesticides, polychlorinated biphenyls (PCBs), brominated flame retardants, and polycyclic aromatic hydrocarbons (PAHs). Potential risks of contaminants in sediment were evaluated by comparing concentrations of contaminants in sediment to two effects-based sediment-quality guidelines: (1) a lower level, called the threshold effect concentration, below which, harmful effects to benthic biota are not expected, and (2) a higher level, the probable effect concentration (PEC), above which harmful effects are expected to occur frequently. Samples for water-toxicity testing were collected from each stream to provide information about fish toxicity in the study area. The trace metal lead was detected at potentially toxic concentrations greater than the PEC in both the base-flow and poststorm samples collected at two sites sampled on San Pedro Creek. The PECs for the pesticides dichlorodiphenyldichloroethane, dichlorodiphenyldichloroethylene, dichlorodiphenyltrichloroethane, and chlordane were exceeded in some of the samples at the same two sites on San Pedro Creek. Brominated flame retardants and polybrominated diphenyl ether (PBDE) 85, 153, and 154 were found in all streambed-sediment samples. Federal Environmental Quality Guidelines established by Environment Canada for PBDE 99 and PBDE 100 were exceeded in all samples in which PBDE 99 was detected and in a majority of the samples in which PBDE 100 was detected; the greatest concentrations occurred in samples collected at the same two sites on San Pedro Creek where the samples containing elevated lead and pesticide concentrations were collected. All concentrations of total PCBs (computed as the sum of the 18 reported PCB congeners) in the individual streambed-sediment samples were less than the threshold effect concentration, but the concentrations were elevated in the two sites on San Pedro Creek compared to concentrations at other sites. At one site on Apache Creek, 6 of the individual PAHs measured in the sample collected during base-flow conditions exceeded the PECs and 8 of the 9 PECs were exceeded in the sample collected during poststorm conditions. The total PAH concentration in the sample collected at the site during poststorm conditions was 3.3 times greater than the PEC developed for total PAHs. Average PAH profiles computed for base-flow samples and poststorm samples most closely resemble the parking lot coal-tar sealcoat dust PAH source profile, defined as the average PAH concentrations in dust swept from parking lots in six cities in the United States that were sealed with a black, viscous liquid containing coal-tar pitch. Six of ten water samples collected during base-flow conditions caused reductions in Pimephales promelas (fathead minnow) survival and were considered to be toxic.

Water-quality assessment of part of the upper Mississippi River basin, Minnesota and Wisconsin - Pesticides in streams, streambed sediment, and ground water, 1974-94

USGS Publications Warehouse

Fallon, J.D.; Fong, A.L.; Andrews, W.J.

1997-01-01

Atrazine was the only pesticide that equaled or exceeded a maximum contaminant level (of 3.0 micrograms per liter) for drinking water. Two stream samples from a small urban watershed in Minneapolis had atrazine concentrations of 3.6 and 3.8 micrograms per liter, and one ground-water sample had a concentration of 3.0 micrograms per liter. Trace concentrations (less than 0.06 micrograms per liter) of the organochlorine insecticides chlordane, dieldrin, endrin, and heptachlor exceeded chronic freshwater-quality criteria in stream samples from the Mississippi, Minnesota, St. Croix, and Vemillion Rivers in 1981 and 1990.

Towards environmental management of water turbidity within open coastal waters of the Great Barrier Reef.

PubMed

Macdonald, Rachael K; Ridd, Peter V; Whinney, James C; Larcombe, Piers; Neil, David T

2013-09-15

Water turbidity and suspended sediment concentration (SSC) are commonly used as part of marine monitoring and water quality plans. Current management plans utilise threshold SSC values derived from mean-annual turbidity concentrations. Little published work documents typical ranges of turbidity for reefs within open coastal waters. Here, time-series turbidity measurements from 61 sites in the Great Barrier Reef (GBR) and Moreton Bay, Australia, are presented as turbidity exceedance curves and derivatives. This contributes to the understanding of turbidity and SSC in the context of environmental management in open-coastal reef environments. Exceedance results indicate strong spatial and temporal variability in water turbidity across inter/intraregional scales. The highest turbidity across 61 sites, at 50% exceedance (T50) is 15.3 NTU and at 90% exceedance (T90) 4.1 NTU. Mean/median turbidity comparisons show strong differences between the two, consistent with a strongly skewed turbidity regime. Results may contribute towards promoting refinement of water quality management protocols. Copyright © 2013 Elsevier Ltd. All rights reserved.

Assessment of metal and trace element contamination in water, sediment, plants, macroinvertebrates, and fish in Tavasci Marsh, Tuzigoot National Monument, Arizona

USGS Publications Warehouse

Beisner, Kimberly R.; Paretti, Nicholas V.; Brasher, Anne M.D.; Fuller, Christopher C.; Miller, Matthew P.

2014-01-01

Tavasci Marsh is a large freshwater marsh within the Tuzigoot National Monument in central Arizona. It is the largest freshwater marsh in Arizona that is unconnected to the Colorado River and is designated as an Important Bird Area by the Audubon Society. The marsh has been altered significantly by previous land use and the monument’s managers are evaluating the restoration of the marsh. In light of historical mining activities located near the marsh from the first half of the 20th century, evaluations of water, sediment, plant, and aquatic biota in the marsh were conducted. The evaluations were focused on nine metals and trace elements commonly associated with mining and other anthropogenic activities (As, Cd, Cr, Cu, Hg, Ni, Pb, Se, and Zn) together with isotopic analyses to understand the presence, sources and timing of water and sediment contaminants to the marsh and the occurrence in aquatic plants, dragonfly larvae, and fish. Results of water analyses indicate that there were two distinct sources of water contributing to the marsh during the study: one from older high elevation recharge entering the marsh at Shea Spring (as well as a number of unnamed seeps and springs on the northeastern edge of the marsh) and the other from younger low elevation recharge or from Pecks Lake. Water concentrations for arsenic exceeded the U.S. Environmental Protection Agency primary drinking water standard of 10 μg/L at all sampling sites. Surface waters at Tavasci Marsh may contain conditions favorable for methylmercury production. All surficial and core sediment samples exceeded or were within sample concentration variability of at least one threshold sediment quality guideline for As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn. Several sediment sites were also above or were within sample concentration variability of severe or probable effect sediment quality guidelines for As, Cd, and Cu. Three sediment cores collected in the marsh have greater metal and trace element concentrations at depth for Bi, Cd, Cu, Hg, In, Pb, Sb, Sn, Te, and Zn. Radioisotope dating indicates that the elevated metal and trace element concentrations are associated with sediments deposited before 1963. Arsenic concentration was greater in cattail roots compared with surrounding sediment at Tavasci Marsh. Concentrations of As, Ni, and Se from yellow bullhead catfish (Ameiurus natalis) in Tavasci Marsh exceeded the 75th percentile of several other regional studies. Mercury concentration in dragonfly larvae and fish from Tavasci Marsh were similar to or greater than in Tavasci Marsh sediment. Future work includes a biologic risk assessment utilizing the data collected in this study to provide the monument management with additional information for their restoration plan.

Spatial variability associated with shifting land use: water quality and sediment metals in La Parguera, Southwest Puerto Rico.

PubMed

Hertler, Heidi; Boettner, Adam R; Ramírez-Toro, Graciela I; Minnigh, Harvey; Spotila, James; Kreeger, Danielle

2009-05-01

Development in southwest Puerto Rico, as in many areas of the Caribbean, is outpacing the ability of upland flora, salt flats, and mangroves to capture sediments and intercept and transform nutrients. A comparative study to examine the effects of development on near-shore water quality in La Parguera, Puerto Rico, was initiated in 1998. Total suspended solids were significantly higher in the vicinity of developing areas compared to reference areas. Chlorophyll-a measurements near of the wastewater treatment plant averaged two times the level of other areas. The overall average concentrations of copper, chromium, nickel, and zinc in sediments collected from salt flats exceeded values reported to cause impairment of biological systems. Marine sediments near more developed locations had the highest metal concentrations, suggesting a greater transport in this area. Natural resources are the primary attraction in this area; therefore, protection of near-shore resources should receive greater attention in land use planning.

Geochemistry of Mine Waste and Mill Tailings, Meadow Deposits, Streambed Sediment, and General Hydrology and Water Quality for the Frohner Meadows Area, Upper Lump Gulch, Jefferson County, Montana

USGS Publications Warehouse

Klein, Terry L.; Cannon, Michael R.; Fey, David L.

2004-01-01

Frohner Meadows, an area of low-topographic gradient subalpine ponds and wetlands in glaciated terrane near the headwaters of Lump Gulch (a tributary of Prickly Pear Creek), is located about 15 miles west of the town of Clancy, Montana, in the Helena National Forest. Mining and ore treatment of lead-zinc-silver veins in granitic rocks of the Boulder batholith over the last 120 years from two sites (Frohner mine and the Nellie Grant mine) has resulted in accumulations of mine waste and mill tailings that have been distributed downslope and downstream by anthropogenic and natural processes. This report presents the results of an investigation of the geochemistry of the wetlands, streams, and unconsolidated-sediment deposits and the hydrology, hydrogeology, and water quality of the area affected by these sources of ore-related metals. Ground water sampled from most shallow wells in the meadow system contained high concentrations of arsenic, exceeding the Montana numeric water-quality standard for human health. Transport of cadmium and zinc in ground water is indicated at one site near Nellie Grant Creek based on water-quality data from one well near the creek. Mill tailings deposited in upper Frohner Meadow contribute large arsenic loads to Frohner Meadows Creek; Nellie Grant Creek contributes large arsenic, cadmium, and zinc loads to upper Frohner Meadows. Concentrations of total-recoverable cadmium, copper, lead, and zinc in most surface-water sites downstream from the Nellie Grant mine area exceeded Montana aquatic-life standards. Nearly all samples of surface water and ground water had neutral to slightly alkaline pH values. Concentrations of arsenic, cadmium, lead, and zinc in streambed sediment in the entire meadow below the mine waste and mill tailings accumulations are highly enriched relative to regional watershed-background concentrations and exceed consensus-based, probable-effects concentrations for streambed sediment at most sites. Cadmium, copper, and zinc typically are adsorbed to the surface coatings of streambed-sediment grains. Mine waste and mill tailings contain high concentrations of arsenic, cadmium, copper, lead, and zinc in a quartz-rich matrix. Most of the waste sites that were sampled had low acid-generating capacity, although one site (fine-grained mill tailings from the Nellie Grant mine deposited in the upper part of lower Frohner Meadows) had extremely high acid-generating potential because of abundant fine-grained pyrite. Two distinct sites were identified as metal sources based on streambed-sediment samples, cores in the meadow substrate, and mine and mill-tailings samples. The Frohner mine and mill site contribute material rich in arsenic and lead; similar material from the Nellie Grant mine and mill site is rich in cadmium and zinc.

Influence of a Brazilian sewage outfall on the toxicity and contamination of adjacent sediments

USGS Publications Warehouse

Abessa, D.M.S.; Carr, R.S.; Rachid, B.R.F.; Sousa, E.C.P.M.; Hortelani, M.A.; Sarkis, J.E.

2005-01-01

The submarine sewage outfall of Santos (SSOS) is situated in the Santos Bay (São Paulo, Brazil) and is potentially a significant source of contaminants to the adjacent marine ecosystem. The present study aimed to assess the influence of SSOS on the sediment toxicity and contamination at Santos Bay. At the disposal site, sediments tended to be finer, organically richer and exhibited higher levels of surfactants and metals, sometimes exceeding the “Threshold Effect Level” values. The SSOS influence was more evident toward the East, where the sediments exhibited higher levels of TOC, total S and metals during the summer 2000 sampling campaign. Sediment toxicity to amphipods was consistently detected in four of the five stations studied. Amphipod survival tended to correlate negatively to Hg, total N and % mud. This work provides evidence that the SSOS discharge affects the quality of sediments from Santos Bay, and that control procedures are warranted.

Surface-water-quality assessment of the upper Illinois River Basin in Illinois, Indiana, and Wisconsin; pesticides and other synthetic organic compounds in water, sediment, and biota, 1975-90

USGS Publications Warehouse

Sullivan, Daniel J.; Stinson, Troy W.; Crawford, J. Kent; Schmidt, Arthur R.; Colman, John A.

1998-01-01

The distribution of pesticides and other synthetic organic compounds in water, sediment, and biota in the upper Illinois River Basin in Illinois, Indiana, and Wisconsin was examined from 1987 through 1990 as part of the pilot National Water-Quality Assesssment Program conducted by the U.S. Geological Survey. Historical data for water and sediment collected from 1975 through 1986 were similar to data collected from 1987 through 1990. Some compounds were detected in concentrations that exceed U.S. Environmental Protection Agency water-quality criteria. Results from pesticide sampling at four stations in 1988 and 1989 identified several agricultural pesticides that were detected more frequently and at higher concentrations in urban areas than in agricultural areas. Results from herbicide sampling at 17 stations in the Kankakee and Iroquois River Basins in 1990 indicated that atrazine concentrations exceeded the U.S. Environmental Protection Agency's maximum contaminant level for drinking water during runoff periods. Results from sampling for volatile and semivolatile organic compounds in water indicate that, with one exception, all stations at which more than one compound was detected were within 2 miles downstream from the nearest point source. Detections at two stations in the Chicago urban area accounted for 37 percent of the total number of detections. Concentrations of tetrachloroethylene, trichloroethylene, and 1,2-dichlorethane from stations in the Des Plaines River Basin exceeded the U.S. Environmental Protection Agency's maximum contaminant level for drinking water in one and two samples from the two stations in the Chicago area. Phenols and pentachlorophenols were detected most frequently in the Des Plaines River Basin where point-source discharges were common. Phenol concentrations were significantly different among the Des Plaines, Kankakee, and Fox River Basins. Phenols and pentachlorophenols never exceeded the general use and secondary contact standards. Results from a 1989 synoptic survey of semivolatile organic compounds in sediment indicate that these compounds were detected most frequently at sites in the Chicago urban area. Of the 17 stations at which 10 or more compounds were detected, 14 were located in the Des Plaines River subbasin, and 1 was on the Illinois River mainstem. As was the case with organic compounds in water, each of these sites was located within 2 miles downstream from point sources. Biota samples were collected and analyzed for organochlorines and polynuclear aromatic hydrocarbons in 1989 and 1990. The most commonly detected compound in both years was p,p'-DDE. National Academy of Science recommendations for chlordane and dieldrin for protection of predators were exceeded in 19 and 10 samples, respectively, when the 1989 and 1990 data were combined. In the nine fish-fillet samples collected in 1989, concentrations exceeded U.S. Environmental Protection Agency fish-tissue criteria in nine fillets for p,p'-DDE and five fillets for dieldrin.

A summary of total mercury concentrations in flora and fauna near common contaminant sources in the Gulf of Mexico.

PubMed

Lewis, M; Chancy, C

2008-02-01

Total mercury concentrations are summarized for environmental media and biota collected from near-coastal areas, several impacted by contaminant sources common to the Gulf of Mexico. Water, sediment, fish, blue crabs, oysters, clams, mussels, periphyton and seagrasses were collected during 1993-2002 from targeted areas affected by point and non-point source contaminants. Mean concentrations in water and sediment were 0.02 (+/-1 standard deviation=0.06) microg l(-1) and 96.3 (230.8) ng g(-1) dry wt, respectively. Mean total mercury concentrations in fish, blue crabs, brackish clams and mussels were significantly greater than those in sediment, seagrass, colonized periphyton and oysters. Concentrations (ng g(-1) dry wt) averaged 23.1 (two seagrass species), 220.1 (oysters), 287.8 (colonized periphyton), 604.0 (four species of freshwater mussels), 772.4 (brackish clam), 857.9 (blue crabs) and 933.1 (nine fish species). Spatial, intraspecific and interspecific variability in results limited most generalizations concerning the relative mercury contributions of different stressor types. However, concentrations were significantly greater for some biota collected from areas receiving wastewater discharges and golf course runoff (fish), agricultural runoff (oysters) and urban stormwater runoff (colonized periphyton and sediment). Marine water quality criteria and proposed sediment quality guidelines were exceeded in 1-12% of total samples. At least one seafood consumption guideline, criteria or screening value were exceeded in edible tissues of blue crabs (6% total samples) and nine fish species (8-33% total samples) but all residues were less than the US Federal Drug Administration action limit of 1.0 ppm and the few reported toxic effect concentrations available for the targeted biota.

Concentrations of selected trace elements in fish tissue and streambed sediment in the Clark Fork-Pend Oreille and Spokane River basins, Washington, Idaho, and Montana, 1998

USGS Publications Warehouse

Maret, Terry R.; Skinner, K.D.

2000-01-01

Fish tissue and bed sediment samples were collected from 16 stream sites in the Northern Rockies Intermontane Basins study area in 1998 as part of the U.S. Geological Survey National Water-Quality Assessment Program. Bed sediment samples were analyzed for 45 trace elements, and fish livers and sportfish fillets were analyzed for 22 elements to characterize the occurrence and distribution of these elements in relation to stream characteristics and land use activities. Nine trace elements of environmental concern—arsenic, cadmium, chromium, copper, lead, mercury, nickel, selenium, and zinc—were detected in bed sediment, but not all of these elements were detected in fish tissue. Trace-element concentrations were highest in bed sediment samples collected at sites downstream from significant natural mineral deposits and (or) mining activities. Arsenic, cadmium, copper, lead, mercury, and zinc in bed sediment at some sites were elevated relative to national median concentrations, and some concentrations were at levels that can adversely affect aquatic biota. Although trace-element concentrations in bed sediment exceeded various guidelines, no concentrations in sportfish fillets exceeded U.S. Environmental Protection Agency screening values for the protection of human health. Correlations between most trace-element concentrations in bed sediment and fish tissue (liver and fillet) were not significant (r0.05). Concentrations of arsenic, cadmium, copper, lead, mercury, nickel, selenium, and zinc in bed sediment were significantly correlated (r=0.53 to 0.88, p2=0.95 and 0.99, p<0.001) that corresponded to trace-element enrichment categories. These strong relations warrant further study using mine density as an explanatory variable to predict trace-element concentrations in bed sediment.

Sediment quality and quantity issues related to the restoration of backwater lakes along the Illinois River waterway

USGS Publications Warehouse

Machesky, M.L.; Slowikowski, J.A.; Cahill, R.A.; Bogner, W.C.; Marlin, J.C.; Holm, T.R.; Darmody, R.G.

2005-01-01

Sedimentation has severely impacted backwater lakes along the Illinois River. The State of Illinois and the US Army Corps of Engineers are currently involved in a joint effort to address ecosystem degradation within the Illinois River Basin, and excessive sedimentation of backwater lakes and side channels is a primary cause of that degradation. Necessary parts of the overall restoration effort are to adequately characterize both the quality and quantity of backwater lake sediments prior to implementing any restoration efforts, and to identify potential beneficial reuses of dredged sediments. This paper summarizes some of our efforts in these areas with an emphasis on Peoria Lake which has received the most attention to date. Sediment characterization has included detailed bathymetric surveys, sediment dating with 137 Cs, chemical and mineralogical characterization of sediments to three meters depth, analysis of recent sediments (to 30 cm depth) for acid-volatile sulfide and simultaneously extracted metals, and analysis of ammonia and toxic metals in sediment pore waters. Dredged sediments have also been used in various trial projects to demonstrate potential handling and beneficial reuse strategies. Some significant findings of these studies are: 1) Long-term sedimentation rates are high, and average 1–3 cm y −1 ; 2) total concentrations of several trace metals (e.g., Pb, Cd, Ni) and PAH compounds sometimes exceed consensus-based probable effect levels for sensitive sediment-dwelling organisms; 3) pore water dissolved ammonia concentrations in Peoria Lake are potentially toxic to sensitive sediment-dwelling species; and 4) weathered sediments can make productive agricultural soils.

Water-quality study of Tulpehocken Creek, Berks County, Pennsylvania, prior to impoundment of Blue Marsh Lake

USGS Publications Warehouse

Barker, James L.

1977-01-01

Blue Marsh Lake is planned as a multipurpose impoundment to be constructed on Tulpehocken Creek near Bernville, Berks County, Pennsylvania. Prior to construction, samples of water, bed material, and soil were collected throughout the impoundment site to determine concentrations of nutrients, insecticides, trace metals, suspended sediment, and bacteria. Analyses of water suggest the Tulpehocken Creek basin to be a highly fertile environment. Nitrogen and phosphorus concentrations near the proposed dam site had median values of 4.5 and 0.13 mg/L, respectively. Suspended sediment discharges average between 100 and 200 tons (90.7 to 181.4 metric tons) per day during normal flows but may exceed 10,000 tons (9,070 metric tons) per day during storm runoff. Highest yields were measured during winter and early spring. Concentrations range from 3 mg/L to more than 500 mg/L. Bed material samples contain trace quantities of aldrin, DDT, DDD, DDE, dieldrin, and chlordane. Polychlorinated biphyenyls (PCB's) ranged from 10 to 100 μg/kg. Soils at the impoundment site are of average fertility. However, the silt loam texture is ideal for attachment and growth of aquatic plants. Bacteria populations indicative of recent fecal contamination are prevalent in the major inflows to the proposed lake. Fecal Coliform exceeded the standards recommended by the Federal Water Pollution Administration Committee on Water Quality Criteria for public water supply in 29 percent of the monthly samples, and exceeded the recommended public bathing waters standard in 83 percent of the samples collected from June to September. Arsenic from an industrial waste was found in the water, suspended sediment, and bed material of Tulpehocken Creek in concentrations of 0 to 30 μg/l, 2 to 879 μg/l, and 1 to 79 μg/g, respectively. It represents a potential environmental hazard; however, the measured concentrations are less than that known to be harmful to man, fish, or wildlife, according to published water quality criteria.

A ten year summary of concurrent ambient water column and sediment toxicity tests in the Chesapeake Bay watershed: 1990-1999.

PubMed

Hall, Lenwood W; Anderson, Ronald D; Alden, Raymond W

2002-06-01

The goal of this study was to identify the relative toxicity of ambient areas in the Chesapeake Bay watershed by using a suite of concurrent water column and sediment toxicity tests at seventy-five ambient stations in 20 Chesapeake Bay rivers from 1990 through 1999. Spatial and temporal variability was examined at selected locations throughout the 10 yr study. Inorganic and organic contaminants were evaluated in ambient water and sediment concurrently with water column and sediment tests to assess possible causes of toxicity although absolute causality can not be established. Multivariate statistical analysis was used to develop a multiple endpoint toxicity index (TOX-INDEX) at each station for both water column and sediment toxicity data. Water column tests from the 10 yr testing period showed that 49% of the time, some degree of toxicity was reported. The most toxic sites based on water column results were located in urbanized areas such as the Anacostia River, Elizabeth River and the Middle River. Water quality criteria for copper, lead, mercury, nickel and zinc were exceeded at one or more of these sites. Water column toxicity was also reported in localized areas of the South and Chester Rivers. Both spatial and temporal variability was reported from the suite of water column toxicity tests. Some degree of sediment toxicity was reported from 62% of the tests conducted during the ten year period. The Elizabeth River and Baltimore Harbor stations were reported as the most toxic areas based on sediment results. Sediment toxicity guidelines were exceeded for one or more of the following metals at these two locations: arsenic, cadmium, chromium, copper, lead, nickel and zinc. At the Elizabeth River stations nine of sixteen semi-volatile organics and two of seven pesticides measured exceeded the ER-M values in 1990. Ambient sediment toxicity tests in the Elizabeth River in 1996 showed reduced toxicity. Various semi-volatile organics exceeded the ER-M values at a number of Baltimore Harbor sites; pyrene and dibenzo(a,h)anthracene were particularly high at one of the stations (Northwest Harbor). Localized sediment toxicity was also reported in the Chester, James, Magothy, Rappahannock, and Potomac Rivers but the link with contaminants was not determined. Both spatial and temporal variability was less for sediment toxicity data when compared with water column toxicity data. A comparison of water column and sediment toxicity data for the various stations over the 10 yr study showed that approximately half the time agreement occurred (either both suite of tests showed toxicity or neither suite of tests showed toxicity).

Detailed study of selenium and selected constituents in water, bottom sediment, soil, and biota associated with irrigation drainage in the San Juan River area, New Mexico, 1991-95

USGS Publications Warehouse

Thomas, Carole L.; Wilson, R.M.; Lusk, J.D.; Bristol, R.S.; Shineman, A.R.

1998-01-01

In response to increasing concern about the quality of irrigation drainage and its potential effects on fish, wildlife, and human health, the U.S. Department of the Interior began the National Irrigation Water Quality Program (NIWQP) to investigate these concerns at irrigation projects sponsored by the Department. The San Juan River in northwestern New Mexico was one of the areas designated for study. Study teams composed of scientists from the U.S. Geological Survey, the U.S. Fish and Wildlife Service, the Bureau of Reclamation, and the Bureau of Indian Affairs collected water, bottom-sediment, soil, and biological samples at 61 sites in the San Juan River area during 1993-94. Supplemental data collection conducted during 1991-95 by the Bureau of Indian Affairs and its contractor extended the time period and sampling sites available for analysis. Analytical chemistry performed on samples indicated that most potentially toxic elements other than selenium generally were not high enough to be of concern to fish, wildlife, and human health. Element concentrations in some water, bottom-sediment, soil, and biological samples exceeded applicable standards and criteria suggested by researchers in current literature. Selenium concentrations in water samples from 28 sites in the study area exceeded the 2-microgram-per-liter wildlife-habitat standard. Vanadium concentrations in water exceeded the 100-microgram-per-liter standard for livestock-drinking water at one site. In biota, selenium and aluminum concentrations regularly equaled or exceeded avian dietary threshold concentrations. In bottom sediment and soil, element concentrations above the upper limit of the baseline range for western soils were: selenium, 24 exceedances; lead, 2 exceedances; molybdenum, 2 exceedances; strontium, 4 exceedances; and zinc, 4 exceedances. Concentrations of total selenium in bottom-sediment and soil samples were significantly greater for Cretaceous than for non-Cretaceous soil types in the study area and were generally similar for habitats within and outside irrigation-affected areas. Mean and median total-selenium concentrations in samples from areas with Cretaceous soil types were 4.6 and 2.2 micrograms per gram, respectively. Mean and median total-selenium concentrations in samples from areas with non-Cretaceous soil types were 0.6 and 0.15 microgram per gram, respectively. Samples from the study area had low concentrations of organic constituents. Organochlorine pesticides and polychlorinated biphenyls were detected in a few biological samples at low concentrations. Polycyclic aromatic hydrocarbon (PAH) compounds were not detected in whole-water samples collected using conventional water-sampling techniques. In tests involving the use of semipermeable-membrane devices to supplement conventional water assays for PAH's, low concentrations of PAH's were found at several locations in the Hammond Irrigation Supply Canal, but were not detected in the Hammond ponds at the downstream reach of the Hammond irrigation service area. PAH compounds do not appear to reach the San Juan River through the Hammond Canal. Data indicate that water samples from irrigation-drainage-affected habitats had increased mean selenium concentrations compared with samples from irrigation-delivery habitat. The mean selenium concentration in water was greatest at seeps and tributaries draining irrigated land (17 micrograms per liter); less in irrigation drains and in ponds on irrigated land (6 micrograms per liter); and least in backwater, the San Juan River, and irrigation-supply water (0.5 - 0.6 microgram per liter). Statistical tests imply that irrigation significantly increases selenium concentrations in water samples when a Department of the Interior irrigation project is developed on selenium-rich sediments. Water samples from sites with Cretaceous soils had signi

Precipitation, streamflow, suspended-sediment, and water-quality data for the U.S. Army Garrison Fort Carson and Piñon Canyon Maneuver Site, Colorado, 1966–2015

USGS Publications Warehouse

Arnold, L.R.

2017-08-03

The U.S. Army Garrison Fort Carson (AGFC) and the Piñon Canyon Maneuver Site (PCMS) are facilities operated by the U.S. Department of the Army in southern Colorado. The U.S. Geological Survey, in cooperation with the U.S. Department of the Army, established a hydrologic and water-quality data-collection network at the AGFC in June 1978 and at the PCMS in October 1982. The data-collection networks are designed to assess the quantity and quality of water resources and monitor the effects of military training activities on streamflow and water quality. Two preexisting U.S. Geological Survey streamgages at the PCMS were incorporated into the data-collection network at the time it was established, providing periods of record that begin as early as 1966. This report presents and summarizes precipitation, streamflow, suspended-sediment, and water-quality data from 34 U.S. Geological Survey sites on or near the AGFC and the PCMS for the period of record at each site. (Streamflow data are presented as discharge in cubic feet per second.)At AGFC, daily sum precipitation ranged from 0 to 11.85 inches, daily mean discharge ranged from 0 to 836 cubic feet per second, and daily mean suspended-sediment discharge ranged from 0 to 39,900 tons per day. With the exception of total (unfiltered) mercury and filtered sulfate at two sites and filtered manganese at three sites, 95th percentile trace element concentrations and median total (unfiltered) metal concentrations were less than regulatory numeric standards for all samples. However, individual water-quality results occasionally exceeded respective regulatory numeric standards.At the PCMS, daily sum precipitation ranged from 0 to 4.59 inches, daily mean discharge ranged from 0 to 4,190 cubic feet per second, and daily mean suspended-sediment discharge ranged from 0 to 21,100 tons per day. Water-quality results, 95th percentile trace element concentrations, and median total (unfiltered) metal concentrations were less than regulatory numeric standards for most properties and constituents except for filtered chloride at one site, filtered sulfate at six sites, filtered phosphorus at one site, filtered manganese at three sites, and total (unfiltered) iron at three sites. Individual water-quality values also occasionally exceeded respective regulatory numeric standards.

Chemical and Ecological Health of White Sucker (Catostomus Commersoni) in Rock Creek Park, Washington, D.C., 2003-04

USGS Publications Warehouse

Miller, Cherie V.; Weyers, Holly S.; Blazer, Vicki; Freeman, Mary E.

2006-01-01

Several classes of chemicals that are known or suspected contaminants were found in bed sediment in Rock Creek, including polyaromatic hydrocarbons (PAHs), phthalate esters, organochlorine pesticides, dioxins and furans, trace metals and metalloids (mercury, arsenic, cadmium, chromium, cobalt, copper, lead, nickel, silver, and zinc), and polychlorinated biphenyls (total PCBs and selected aroclors). Concentrations of many of these chemicals consistently exceeded threshold or chronic-effects guidelines for the protection of aquatic life and often exceeded probable effects levels (PELs). Exceedance of PELs was dependent on the amount of total organic carbon in the sediments. Concurrent with the collection of sediment-quality data, white sucker (Catostomus commersoni) were evaluated for gross-external and internal-organ anomalies, whole-body burdens of chemical contaminants, and gut contents to determine prey. The histopathology of internal tissues of white sucker was compared to contaminant levels in fish tissue and bed sediment. Gut contents were examined to determine preferential prey and thus potential pathways for the bioaccumulation of chemicals from bed sediments. Male and female fish were tested separately. Lesions and other necroses were observed in all fish collected during both years of sample collection, indicating that fish in Rock Creek have experienced some form of environmental stress. No direct cause and effect was determined for chemical exposure and compromised fish health, but a substantial weight of evidence indicates that white sucker, which are bottom-feeding fish and low-order consumers in Rock Creek, are experiencing some reduction in vitality, possibly due to immunosuppression. Abnormalities observed in gonads of both sexes of white sucker and observations of abnormal behavior during spawning indicated some interruption in reproductive success.

Chemical and ecological health of white sucker (Catostomus Commersoni) in Rock Creek Park, Washington, D.C., 2003?04

USGS Publications Warehouse

Miller, C.V.; Weyers, H.S.; Blazer, V.S.; Freeman, M.E.

2006-01-01

Several classes of chemicals that are known or suspected contaminants were found in bed sediment in Rock Creek, including polyaromatic hydrocarbons (PAHs), phthalate esters, organochlorine pesticides, dioxins and furans, trace metals and metalloids (mercury, arsenic, cadmium, chromium, cobalt, copper, lead, nickel, silver, and zinc), and polychlorinated biphenyls (total PCBs and selected aroclors). Concentrations of many of these chemicals consistently exceeded thresholdor chronic-effects guidelines for the protection of aquatic life and often exceeded probable effects levels (PELs). Exceedance of PELs was dependent on the amount of total organic carbon in the sediments. Concurrent with the collection of sediment-quality data, white sucker (Catostomus commersoni) were evaluated for gross-external and internal-organ anomalies, whole-body burdens of chemical contaminants, and gut contents to determine prey. The histopathology of internal tissues of white sucker was compared to contaminant levels in fish tissue and bed sediment. Gut contents were examined to determine preferential prey and thus potential pathways for the bioaccumulation of chemicals from bed sediments. Male and female fish were tested separately. Lesions and other necroses were observed in all fish collected during both years of sample collection, indicating that fish in Rock Creek have experienced some form of environmental stress. No direct cause and effect was determined for chemical exposure and compromised fish health, but a substantial weight of evidence indicates that white sucker, which are bottom-feeding fish and low-order consumers in Rock Creek, are experiencing some reduction in vitality, possibly due to immunosuppression. Abnormalities observed in gonads of both sexes of white sucker and observations of abnormal behavior during spawning indicated some interruption in reproductive success.

Sediment deposition and selected water-quality characteristics in Cedar Lake and Lake Olathe, Northeast Kansas, 2000

USGS Publications Warehouse

Mau, D.P.

2002-01-01

The Lake Olathe watershed, located in northeast Kansas, was investigated using bathymetric survey data and reservoir bottom-sediment cores to determine sediment deposition, water-quality trends, and transport of nutrients (phosphorus and nitrogen species), selected trace elements, selected pesticides, and diatoms as indicators of eutrophic (organic-enriched and depleted oxygen supply) conditions. To determine sediment deposition and loads, bathymetric data from Cedar Lake and Lake Olathe, both located in the Lake Olathe watershed, were collected in 2000 and compared to historical topographic data collected when the lakes were built. Approximately 338 acre-feet of sediment deposition has occurred in Cedar Lake since dam closure in 1938, and 317 acre-feet has occurred at Lake Olathe since 1956. Mean annual sediment deposition was 5.45 acre-feet per year (0.89 acre-feet per year per square mile) for Cedar Lake and 7.0 acre-feet per year (0.42 acre-feet per year per square mile) for Lake Olathe. Mean annual sediment loads for the two reservoirs were 9.6 million pounds per year for Cedar Lake and 12.6 million pounds per year for Lake Olathe. Mean concentrations of total phosphorus in bottom-sediment samples from Cedar Lake ranged from 1,370 to 1,810 milligrams per kilogram, and concentrations in bottom-sediment samples from Lake Olathe ranged from 588 to 1,030 milligrams per kilogram. The implication of large total phosphorus concentrations in the bottom sediment of Cedar Lake is that inflow into Cedar Lake is rich in phosphorus and that adverse water-quality conditions could affect water quality in downstream Lake Olathe through discharge of water from Cedar Lake to Lake Olathe via Cedar Creek. Mean annual phosphorus loads transported from the Lake Olathe watershed were estimated to be 14,700 pounds per year for Cedar Lake and 9,720 pounds per year for Lake Olathe. The mean annual phosphorus yields were estimated to be 3.74 pounds per acre per year for Cedar Lake and 0.91 pound per acre per year for Lake Olathe. Phosphorus yields in the Cedar Lake watershed were largest of the six Kansas impoundment watersheds recently studied. Concentrations of total ammonia plus organic nitrogen as nitrogen in bottom sediment increased from upstream to downstream in both Cedar Lake and Lake Olathe. Mean concentrations of total ammonia plus organic nitrogen as nitrogen (N) ranged from 2,000 to 2,700 milligrams per kilogram in bottom-sediment samples from Cedar Lake and from 1,300 to 2,700 milligrams per kilogram in samples from Lake Olathe. There was no statistical significance between total ammonia plus organic nitrogen as nitrogen and depth of bottom sediment. Concentrations of six trace elements in bottom sediment from Cedar Lake and Lake Olathe (arsenic, chromium, copper, lead, nickel, and zinc) exceeded the U.S. Environmental Protection Agency Threshold Effects Levels (TELs) sediment-quality guidelines for aquatic organisms in sediment except for one lead concentration. Probable Effects Levels (PELs) for trace elements, however, were not exceeded at either lake. Organochlorine and organophosphate insecticides were not detected in bottom-sediment samples from either Cedar Lake or Lake Olathe, but the acetanilide herbicides alachlor and metolachlor were detected in sediment from both lakes. The U.S. Environmental Protection Agency has not proposed TEL or PEL guideline concentrations for bottom sediment for any of the organophosphate, acetanilide, or triazine pesticides. The diatoms (microscopic, single-celled organisms) Cyclotella bodanica, an indicator of low organic-enriched water, and Cyclotella meneghiniana, an indicator of organic-enriched water, were both present in bottom sediment from Lake Olathe. The presence of both of these diatoms suggests varying periods of low and high eutrophication in Lake Olathe from 1956 to 2000. The concentrations of two species in bottom sediment from Cedar Lake, Aulacoseira cf alpigena and Cyclotella meneg

Relations of benthic macroinvertebrates to concentrations of trace elements in water, streambed sediments, and transplanted bryophytes and stream habitat conditions in nonmining and mining areas of the upper Colorado River basin, Colorado, 1995-98

USGS Publications Warehouse

Mize, Scott V.; Deacon, Jeffrey R.

2002-01-01

Intensive mining activity and highly mineralized rock formations have had significant impacts on surface-water and streambed-sediment quality and aquatic life within the upper reaches of the Uncompahgre River in western Colorado. A synoptic study by the U.S. Geological Survey National Water-Quality Assessment Program was completed in the upper Uncompahgre River Basin in 1998 to better understand the relations of trace elements (with emphasis on aluminum, arsenic, copper, iron, lead, and zinc concentrations) in water, streambed sediment, and aquatic life. Water-chemistry, streambed-sediment, and benthic macroinvertebrate samples were collected during low-flow conditions between October 1995 and July 1998 at five sites on the upper Uncompahgre River, all downstream from historical mining, and at three sites in drainage basins of the Upper Colorado River where mining has not occurred. Aquatic bryophytes were transplanted to all sites for 15 days of exposure to the water column during which time field parameters were measured and chemical water-quality and benthic macroinvertebrate samples were collected. Stream habitat characteristics also were documented at each site. Certain attributes of surface-water chemistry among streams were significantly different. Concentrations of total aluminum, copper, iron, lead, and zinc in the water column and concentrations of dissolved aluminum, copper, and zinc were significantly different between nonmining and mining sites. Some sites associated with mining exceeded Colorado acute aquatic-life standards for aluminum, copper, and zinc and exceeded Colorado chronic aquatic-life standards for aluminum, copper, iron, lead, and zinc. Concentrations of copper, lead, and zinc in streambed sediments were significantly different between nonmining and mining sites. Generally, concentrations of arsenic, copper, lead, and zinc in streambed sediments at mining sites exceeded the Canadian Sediment Quality Guidelines probable effect level (PEL), except at two mining sites where concentrations of copper and zinc were below the PEL. Concentrations of arsenic, copper, iron, and lead in transplanted bryophytes were significantly different between nonmining and mining sites. Bioconcentration factors calculated for 15-day exposure using one-half of the minimum reporting level were significantly different between nonmining and mining sites. In general, concentrations of trace elements in streambed sediment and transplanted bryophytes were more closely correlated than were the concentrations of trace elements in the water column with streambed sediments or concentrations in the water column with transplanted bryophytes. Stream habitat was rated as optimal to suboptimal using the U.S. Environmental Protection Agency Rapid Bioassessment Protocols for all sites in the study area. Generally, stream habitat conditions were similar at nonmining compared to mining sites and were suitable for diverse macroinvertebrate communities. All study sites had optimal instream habitat except two mining sites with suboptimal instream habitat because of disturbances in stream habitat. The benthic macroinvertebrate community composition at nonmining sites and mining sites differed. Mining sites had significantly lower total abundance of macroinvertebrates, fewer numbers of taxa, and lower dominance of Ephemeroptera (mayflies), Plecoptera (stoneflies), and Trichoptera (caddisflies), and a larger percentage of tolerant species than did nonmining sites. The predominance of Baetis sp. (mayflies), Hydropsychidae (caddisflies), and large percentage of Orthocladiinae chironomids (midges) at mining sites indicated that these species may be tolerant to elevated trace-element concentrations. The absence of Heptageniidae (mayflies), Chloroperlidae (stoneflies), and Rhyacophila sp. (caddisflies) at mining sites indicated that these species may be sensitive to elevated trace-element concentrations. Comparison of field parameters and

Breeding progress, environmental variation and correlation of winter wheat yield and quality traits in German official variety trials and on-farm during 1983-2014.

PubMed

Laidig, Friedrich; Piepho, Hans-Peter; Rentel, Dirk; Drobek, Thomas; Meyer, Uwe; Huesken, Alexandra

2017-01-01

Over the last 32 years, a large gain in grain yield (24 %) was achieved in official German variety trials, and despite considerable loss in protein concentration (-7.9 %), winter wheat baking quality was partially improved over the last 32 years. On-farm gain in grain yield (32 %) exceeded gain in trials, but at yield level about 25 dt ha -1 lower. Breeding progress was very successfully transferred into both progress in grain yield and on-farm baking quality. Long-term gains in grain yield and baking quality of 316 winter wheat varieties from German official trials were evaluated. We dissected progress into a genetic and a non-genetic part to quantify the contribution of genetic improvement. We further investigated the influence of genotype and environment on total variation by estimating variance components. We also estimated genetic and phenotypic correlation between quality traits. For trial data, we found a large gain in grain yield (24%), but a strong decline in protein concentration (-8.0%) and loaf volume (-8.5%) relative to 1983. Improvement of baking quality could be achieved for falling number (5.8%), sedimentation value (7.9%), hardness (13.4%), water absorption (1.2%) and milling yield (2.4%). Grain yield, falling number and protein concentration were highly influenced by environment, whereas for sedimentation value, hardness, water absorption and loaf volume genotypes accounted for more than 60% of total variation. Strong to very strong relations exist among protein concentration, sedimentation value, and loaf volume. On-farm yields were obtained from national statistics, and grain quality data from samples collected by national harvest survey. These on-farm data were compared with trial results. On-farm gain in grain yield was 31.6%, but at a mean level about 25 dt ha -1  lower. Improvement of on-farm quality exceeded trial results considerably. A shift to varieties with improved baking quality can be considered as the main reason for this remarkable improvement of on-farm baking quality.

Effects of hurricanes Katrina and Rita on the chemistry of bottom sediments in Lake Pontchartrain, Louisiana, USA

USGS Publications Warehouse

Van Metre, P.C.; Horowitz, A.J.; Mahler, B.J.; Foreman, W.T.; Fuller, C.C.; Burkhardt, M.R.; Elrick, K.A.; Furlong, E.T.; Skrobialowski, S.C.; Smith, J.J.; Wilson, J.T.; Zaugg, S.D.

2006-01-01

The effects of Hurricanes Katrina and Rita and the subsequent unwatering of New Orleans, Louisiana, on the sediment chemistry of Lake Pontchartrain were evaluated by chemical analysis of samples of street mud and suspended and bottom sediments. The highest concentrations of urban-related elements and compounds (e.g., Pb, Zn, polycyclic aromatic hydrocarbons, and chlordane) in bottom sediments exceeded median concentrations in U.S. urban lakes and sediment-quality guidelines. The extent of the elevated concentrations was limited, however, to within a few hundred meters of the mouth of the 17th Street Canal, similar to results of historical assessments. Chemical and radionuclide analysis of pre- and post-Hurricane Rita samples indicates that remobilization of near-shore sediment by lake currents and storms is an ongoing process. The effects of Hurricanes Katrina and Rita on the sediment chemistry of Lake Pontchartrain are limited spatially and are most likely transitory. ?? 2006 American Chemical Society.

Ecological risk of heavy metals in sediments of the luan river source water

USGS Publications Warehouse

Liu, J.; Li, Y.; Zhang, B.; Cao, J.; Cao, Z.; Domagalski, Joseph L.

2009-01-01

Distribution and characteristics of heavy metals enrichment in sediment were surveyed including the bio-available form analyzed for assessment of the Luan River source water quality. The approaches of sediment quality guidelines (SQG), risk assessment code and Hakanson potential ecological risk index were used for the ecological risk assessment. According to SQG, The results show that in animal bodies, Hg at the sampling site of Wuliehexia was 1.39 mg/kg, Cr at Sandaohezi was 152.37 mg/kg and Cu at Hanjiaying was 178.61 mg/kg exceeding the severe effect screening level. There were 90% of sampling sites of Cr and Pb and 50% sites of Cu exceeded the lowest effect screening level. At Boluonuo and Wuliehexia, the exchangeable and carbonate fractions for above 50% of sites were at high risk levels and that for above 30% of sites at Xiahenan and Wulieheshang were also at high risk levels. Other sites were at medium risk level. Compared to soil background values of China, Hg and Cd showed very strong ecological risk, and the seven heavy metals of Hg, Cd, Cu, As, Pb, Cr, Zn at ecological risk levels were in the descending order. The results could give insight into risk assessment of environmental pollution and decision-making for water source security. ?? 2009 Springer Science+Business Media, LLC.

Content Heavy Metal Pb, Cd In Perna viridis And Sediments In Semarang Bay

NASA Astrophysics Data System (ADS)

Suprapto, D.; Suryanti, S.; Latifah, N.

2018-02-01

Waste disposal from human activities, generally contain heavy metals such as Pb and Cd which derived from industrial activities. The aims of the study were to know the concentration of Pb and Cd heavy metals contained in Perna viridis tissue, sediment and water at Semarang Bay. This study was conducted in May 2017 at Semarang Bay. - Samples were collected using purposive sampling method. The heavy metal content in the water and clam was observed using- APHA method and was analyzed using AAS (Atomic Absorption Spectrophotometer). The results showed that concentration of heavy metal of Pb in the water was 0.00-50.5mg/L and the Cd content was of 26.9-51.7 mg/L, whereas the concentration of Pb in the sediment is 445.5-2.053.0mg/L and Cd 963.3-2,150.0 mg/L. Pb content in soft tissue of Perna viridis - is 67.1-1.933.9 mg/L and the concentration of Cd was 203.5-5.787.3 mg/L. The analysis of Pb and Cd in seawater, sediment and soft tissue of Perna viridis according to Enviroment Ministerial decree (KepMenLH ) number 51 of 2004 and applied by NOAA 1999 does not exceed the quality standard, that meant that the Perna viridis has been contaminated by metal Pb it is controversial with the above sentence and Cd. It concluded that the metal content of Pb and Cd in Perna viridis tissue exceeds the quality standard, so it is not suitable to be consumed, especially in high quantity

Spatial and temporal variation in suspended sediment, organic matter, and turbidity in a Minnesota prairie river: implications for TMDLs.

PubMed

Lenhart, Christian F; Brooks, Kenneth N; Heneley, Daniel; Magner, Joseph A

2010-06-01

The Minnesota River Basin (MRB), situated in the prairie pothole region of the Upper Midwest, contributes excessive sediment and nutrient loads to the Upper Mississippi River. Over 330 stream channels in the MRB are listed as impaired by the Minnesota Pollution Control Agency, with turbidity levels exceeding water quality standards in much of the basin. Addressing turbidity impairment requires an understanding of pollutant sources that drive turbidity, which was the focus of this study. Suspended volatile solids (SVS), total suspended solids (TSS), and turbidity were measured over two sampling seasons at ten monitoring stations in Elm Creek, a turbidity impaired tributary in the MRB. Turbidity levels exceeded the Minnesota standard of 25 nephelometric units in 73% of Elm Creek samples. Turbidity and TSS were correlated (r (2) = 0.76), yet they varied with discharge and season. High levels of turbidity occurred during periods of high stream flow (May-June) because of excessive suspended inorganic sediment from watershed runoff, stream bank, and channel contributions. Both turbidity and TSS increased exponentially downstream with increasing stream power, bank height, and bluff erosion. However, organic matter discharged from wetlands and eutrophic lakes elevated SVS levels and stream turbidity in late summer when flows were low. SVS concentrations reached maxima at lake outlets (50 mg/l) in August. Relying on turbidity measurements alone fails to identify the cause of water quality impairment whether from suspended inorganic sediment or organic matter. Therefore, developing mitigation measures requires monitoring of both TSS and SVS from upstream to downstream reaches.

Organic contaminants, trace and major elements, and nutrients in water and sediment sampled in response to the Deepwater Horizon oil spill

USGS Publications Warehouse

Nowell, Lisa H.; Ludtke, Amy S.; Mueller, David K.; Scott, Jonathon C.

2012-01-01

Beach water and sediment samples were collected along the Gulf of Mexico coast to assess differences in contaminant concentrations before and after landfall of Macondo-1 well oil released into the Gulf of Mexico from the sinking of the British Petroleum Corporation's Deepwater Horizon drilling platform. Samples were collected at 70 coastal sites between May 7 and July 7, 2010, to document baseline, or "pre-landfall" conditions. A subset of 48 sites was resampled during October 4 to 14, 2010, after oil had made landfall on the Gulf of Mexico coast, called the "post-landfall" sampling period, to determine if actionable concentrations of oil were present along shorelines. Few organic contaminants were detected in water; their detection frequencies generally were low and similar in pre-landfall and post-landfall samples. Only one organic contaminant--toluene--had significantly higher concentrations in post-landfall than pre-landfall water samples. No water samples exceeded any human-health benchmarks, and only one post-landfall water sample exceeded an aquatic-life benchmark--the toxic-unit benchmark for polycyclic aromatic hydrocarbons (PAH) mixtures. In sediment, concentrations of 3 parent PAHs and 17 alkylated PAH groups were significantly higher in post-landfall samples than pre-landfall samples. One pre-landfall sample from Texas exceeded the sediment toxic-unit benchmark for PAH mixtures; this site was not sampled during the post-landfall period. Empirical upper screening-value benchmarks for PAHs in sediment were exceeded at 37 percent of post-landfall samples and 22 percent of pre-landfall samples, but there was no significant difference in the proportion of samples exceeding benchmarks between paired pre-landfall and post-landfall samples. Seven sites had the largest concentration differences between post-landfall and pre-landfall samples for 15 alkylated PAHs. Five of these seven sites, located in Louisiana, Mississippi, and Alabama, had diagnostic geochemical evidence of Macondo-1 oil in post-landfall sediments and tarballs. For trace and major elements in water, analytical reporting levels for several elements were high and variable. No human-health benchmarks were exceeded, although these were available for only two elements. Aquatic-life benchmarks for trace elements were exceeded in 47 percent of water samples overall. The elements responsible for the most exceedances in post-landfall samples were boron, copper, and manganese. Benchmark exceedances in water could be substantially underestimated because some samples had reporting levels higher than the applicable benchmarks (such as cobalt, copper, lead and zinc) and some elements (such as boron and vanadium) were analyzed in samples from only one sampling period. For trace elements in whole sediment, empirical upper screening-value benchmarks were exceeded in 57 percent of post-landfall samples and 40 percent of pre-landfall samples, but there was no significant difference in the proportion of samples exceeding benchmarks between paired pre-landfall and post-landfall samples. Benchmark exceedance frequencies could be conservatively high because they are based on measurements of total trace-element concentrations in sediment. In the less than 63-micrometer sediment fraction, one or more trace or major elements were anthropogenically enriched relative to national baseline values for U.S. streams for all sediment samples except one. Sixteen percent of sediment samples exceeded upper screening-value benchmarks for, and were enriched in, one or more of the following elements: barium, vanadium, aluminum, manganese, arsenic, chromium, and cobalt. These samples were evenly divided between the sampling periods. Aquatic-life benchmarks were frequently exceeded along the Gulf of Mexico coast by trace elements in both water and sediment and by PAHs in sediment. For the most part, however, significant differences between pre-landfall and post-landfall samples were limited to concentrations of PAHs in sediment. At five sites along the coast, the higher post-landfall concentrations of PAHs were associated with diagnostic geochemical evidence of Deepwater Horizon Macondo-1 oil.

Assessment of interim flow water-quality data of the San Joaquin River restoration program and implications for fishes, California, 2009-11

USGS Publications Warehouse

Wulff, Marissa L.; Brown, Larry R.

2015-01-01

After more than 50 years of extensive water diversion for urban and agriculture use, a major settlement was reached among the U.S. Departments of the Interior and Commerce, the Natural Resources Defense Council, and the Friant Water Users Authority in an effort to restore the San Joaquin River. The settlement received Federal court approval in October 2006 and established the San Joaquin River Restoration Program, a multi-agency collaboration between State and Federal agencies to restore and maintain fish populations, including Chinook salmon, in the main stem of the river between Friant Dam and the confluence with the Merced River. This is to be done while avoiding or minimizing adverse water supply effects to all of the Friant Division contractors that could result from restoration flows required by the settlement. The settlement stipulates that water- and sediment-quality data be collected to help assess the restoration goals. This report summarizes and evaluates water-quality data collected in the main stem of the San Joaquin River between Friant Dam and the Merced River by the U.S. Bureau of Reclamation for the San Joaquin River Restoration Program during 2009-11. This summary and assessment consider sampling frequency for adequate characterization of variability, sampling locations for sufficient characterization of the San Joaquin River Restoration Program restoration reach, sampling methods for appropriate media (water and sediment), and constituent reporting limits. After reviewing the water- and sediment-quality results for the San Joaquin River Restoration Program, several suggestions were made to the Fisheries Management Work Group, a division of the San Joaquin River Restoration Program that focuses solely on the reintroduction strategies and health of salmon and other native fishes in the river. Water-quality results for lead and total organic carbon exceeded the Surface Water Ambient Monitoring Program Basin Plan Objectives for the San Joaquin Basin, and results for copper exceeded the U.S. Environmental Protection Agency Office of Pesticide Programs' aquatic-life chronic and acute benchmarks for invertebrates. One sediment sample contained detections of pyrethroid pesticides bifenthrin, lambda-cyhalothrin, and total permethrin at concentrations above published chronic toxicity thresholds.

Water-quality, sediment-quality, stream-habitat, and biological data for Mustang Bayou near Houston, Texas, 2004-05

USGS Publications Warehouse

Sneck-Fahrer, Debra A.; East, Jeffery W.

2007-01-01

The U.S. Geological Survey, in cooperation with the Houston-Galveston Area Council and the Texas Commission on Environmental Quality, collected water-quality, stream-habitat, and biological data from six sites (downstream order M6-M1) primarily in Brazoria County southeast of Houston, Texas, during September 2004-August 2005 and collected bed sediment data from one site in September 2005. Water-quality data collection consisted of continuously monitored (for periods of 24 hours to several days, six times) water temperature, pH, specific conductance, and dissolved oxygen and periodically collected samples of several properties and constituents. Monitored dissolved oxygen measurements were below minimum and 24-hour criteria at all sites except M2. Nitrogen compounds, phosphorus, biochemical oxygen demand, chlorophyll-a, E. coli, chloride, sulfate, solids, suspended sediment concentration, and pesticides were assessed at all sites. Concentrations of nitrogen compounds and phosphorus did not exceed Texas State screening levels. Biochemical oxygen demand was less than 4.0 milligrams per liter at all sites except M6, where the maximum concentration was 8.1 milligrams per liter. Concentrations of chlorophyll-a were less than the State screening level at all sites except M6, where four of eight samples equaled or exceeded the screening level. Twenty of 48 samples from Mustang Bayou had E. coli densities that exceeded the State single-sample water-quality standard. Median chloride concentrations from each site were between 42.2 and 123 milligrams per liter. Fifteen pesticide compounds (six herbicides and nine insecticides) were detected in 24 water samples. The most frequently detected pesticide was atrazine, which was found in every sample. Other frequently detected pesticides were 2-chloro-4-isopropylamino-6-amino-s-triazine (CIAT), prometon, tebuthiuron, fipronil, and the pesticide degradates, fipronil sulfide and fipronil sulfone. Sediment samples were collected from the stream bottom at M1 and analyzed for concentrations of trace elements (metals), polycyclic aromatic hydrocarbons, organochlorine pesticides, and polychlorinated biphenyls. No organochlorine pesticides or polychlorinated biphenyls were detected. No concentrations of metals exceeded State screening levels. Measurable concentrations of 11 polycyclic aromatic hydrocarbon (PAH) compounds were detected, and three other PAH compounds were detected but not quantified by the laboratory. Stream habitat and aquatic biota (benthic macroinvertebrates and fish) were surveyed at each site three times during the study to evaluate aquatic life use. Characteristics of habitat measured during each survey were scored using a habitat quality index. Average aquatic-life-use scores were 'limited' for M3-M6 and 'intermediate' for M1 and M2. A total of 2,557 macroinvertebrate individuals were identified from Mustang Bayou. Benthic macroinvertebrate assemblages were scored using indexes specified by the Texas Commission on Environmental Quality. Average aquatic-life-use scores were 'limited' at M1, 'intermediate' at M3-M6, and 'high' at M2. Forty-six species of fish representing 20 families were collected from Mustang Bayou. A total of 4,115 fish were collected. Sunfish (Centrarchidae) was the most abundant family, accounting for about 28 percent. Aquatic-life-use scores at sites in Mustang Bayou were determined using the regional index of biotic integrity for ecoregion 34 and were 'high' for all sites.

Characterization of bottom-sediment, water, and elutriate chemistry at selected stations at Reelfoot Lake, Tennessee

USGS Publications Warehouse

Broshears, R.E.

1991-01-01

To better-understand and predict the potential effect of dredging on water quality at Reelfoot Lake, chemical analyses were conducted on samples of lake water, bottom sediment, and elutriate water. Chemical analyses were conducted on samples of lake water, bottom sediment, and elutriate water collected at five stations in the lake during November 1988. Lake water was of the calcium magnesium bicarbonate type with an average dissolved-solids concentration of 120 milligrams per liter. Trace constituents were present in bottom sediments at concentrations representative of their average relative abundance in the earth?s crust. Elutriate waters prepared by mixing bottom sediment and lake water had suspended-solids concentrations as high as 2,000 milligrams per liter which exerted significant oxygen demand Trace constituents in the unfiltered elutriate waters were elevated with respect to lake water; elevated concentrations were attributable to the increased suspended-solids concentrations. Concentrations of total-recoverable copper, lead., and zinc in many elutriate waters exceeded U.S. Environmental Protection Agency?s water-quality criteria for the protection of freshwater aquatic life. The toxicity of elutriate waters, as measured by a 48-hour bioassay with Ceriodaphnia dubia, was low.

Assessment of streambed sediment contamination by heavy metals: The case of the Gabes Catchment, South-eastern Tunisia

NASA Astrophysics Data System (ADS)

Dahri, Noura; Atoui, Abdelfattah; Ellouze, Manel; Abida, Habib

2018-04-01

This study deals with the assessment of the behaviour of seven heavy metals (Cd, Zn, Cu, Pb, Ni, Cr and As) in streambed sediments within the Gabes Catchment, located in South-eastern Tunisia. To understand the effect of intense human activities in the Gabes Basin on the quality of the environment, 22 sediment samples, spread all over the study basin, were taken and analyzed for heavy metals. Heavy metal concentrations were shown to vary in the following order: Zn > Pb > Cu > Cr > Ni > Cd > As. Sediment quality was assessed based on the evaluation of various indices. A total of 27% of the sampling stations are characterised by sediment Enrichment Factors (EF) exceeding 40, reflecting extremely severe pollution. This result was also confirmed by different indices, including Sediment Pollution Index (SPI), Pollution Load Index (PLI) and Geo-accumulation index. The calculation of Mean Effect Range-Median Quotient (M-ERM-Q) indicated that in stream discharge, all metals have a probability of 21% to be toxic. The ecological toxicity risk of heavy metals increases close to urban (traffic activity) and industrial activities (industrial complex of Gabes). Close to Gabes City, the situation and the degree of contamination that may be transferred into marine ecosystems is worrisome and requires immediate intervention.

Assessment of sediment toxicity and chemical concentrations in the San Diego Bay region, California, USA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fairey, R.; Roberts, C.; Jacobi, M.

1998-08-01

Sediment quality within San Diego Bay, Mission Bay, and the Tijuana River Estuary of California was investigated as part of an ongoing statewide monitoring effort (Bay Protection and Toxic Cleanup Program). Study objectives were to determine the incidence, spatial patterns, and spatial extent of toxicity in sediments and porewater; the concentration and distribution of potentially toxic anthropogenic chemicals; and the relationships between toxicity and chemical concentrations. Rhepoxynius abronius survival bioassays, grain size, and total organic carbon analyses were performed on 350 sediment samples. Strongylocentrotus purpuratus development bioassays were performed on 164 pore-water samples. Toxicity was demonstrated throughout the San Diegomore » Bay region, with increased incidence and concordance occurring in areas of industrial and shipping activity. Trace metal and trace synthetic organic analyses were performed on 229 samples. Copper, zinc, mercury, polycyclic aromatic hydrocarbons, polychlorinated biphenyls, and chlordane were found to exceed ERM (effects range median) or PEL (probable effects level) sediment quality guidelines and were considered the six major chemicals or chemical groups of concern. Statistical analysis of the relationships between amphipod toxicity, bulk phase sediment chemistry, and physical parameters demonstrated few significant linear relationships. Significant differences in chemical levels were found between toxic and nontoxic responses using multivariate and univariate statistics. Potential sources of anthropogenic chemicals were discussed.« less

Effects of Alder Mine on the Water, Sediments, and Benthic Macroinvertebrates of Alder Creek, 1998 Annual Report.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Peplow, Dan

1999-05-28

The Alder Mine, an abandoned gold, silver, copper, and zinc mine in Okanogan County, Washington, produces heavy metal-laden effluent that affects the quality of water in a tributary of the Methow River. The annual mass loading of heavy metals from two audits at the Alder Mine was estimated to exceed 11,000 kg per year. In this study, water samples from stations along Alder Creek were assayed for heavy metals by ICP-AES and were found to exceed Washington State's acute freshwater criteria for cadmium (Cd), copper (Cu), selenium (Se), and zinc (Zn).

The occurrence and potential ecological risk assessment of bauxite mine-impacted water and sediments in Kuantan, Pahang,Malaysia.

PubMed

Kusin, Faradiella Mohd; Rahman, Muhammad Syazwan Abd; Madzin, Zafira; Jusop, Shamshuddin; Mohamat-Yusuff, Ferdaus; Ariffin, Mariani; Z, Mohd Syakirin Md

2017-01-01

Recent bauxite mining activities in the vicinity of Kuantan, Pahang, have been associated with apparent environmental quality degradation and have raised environmental concerns among the public. This study was carried out to evaluate the overall ecological impacts on water and sediment quality from the bauxite mining activities. Water and sediment samples were collected at seven sampling locations within the bauxite mining areas between June and December 2015. The water samples were analyzed for water quality index (WQI) and distribution of major and trace element geochemistry. Sediment samples were evaluated based on geochemical indices, i.e., the enrichment factor (EF) and geoaccumulation index (I geo ). Potential ecological risk index was estimated to assess the degree to which sediments of the mine-impacted areas have been contaminated with heavy metals. The results showed that WQIs of some locations were classified as slightly polluted and contained metal contents exceeding the recommended guideline values. The EFs indicated minimal to moderate enrichment of metals (Pb, Cu, Zn, Mn, As, Cd, Cr, Ni, Co, and Sr) in the sediments. I geo showed slightly to partially polluted sediments with respect to As at some locations. The potential ecological risk index (RI) showed that As posed the highest potential ecological risk with RI of 52.35-60.92 at two locations, while other locations indicated low risk. The findings from this study have demonstrated the impact of recent bauxite mining activities, which might be of importance to the local communities and relevant authorities to initiate immediate rehabilitation phase of the impacted area.

PAH occurrence in chalk river systems from the Jura region (France). Pertinence of suspended particulate matter and sediment as matrices for river quality monitoring.

PubMed

Chiffre, Axelle; Degiorgi, François; Morin-Crini, Nadia; Bolard, Audrey; Chanez, Etienne; Badot, Pierre-Marie

2015-11-01

This study investigates the variations of polycyclic aromatic hydrocarbon (PAH) levels in surface water, suspended particulate matter (SPM) and sediment upstream and downstream of the discharges of two wastewater treatment plant (WWTP) effluents. Relationships between the levels of PAHs in these different matrices were also investigated. The sum of 16 US EPA PAHs ranged from 73.5 to 728.0 ng L(-1) in surface water and from 85.4 to 313.1 ng L(-1) in effluent. In SPM and sediment, ∑16PAHs ranged from 749.6 to 2,463 μg kg(-1) and from 690.7 μg kg(-1) to 3,625.6 μg kg(-1), respectively. Investigations performed upstream and downstream of both studied WWTPs showed that WWTP discharges may contribute to the overall PAH contaminations in the Loue and the Doubs rivers. Comparison between gammarid populations upstream and downstream of WWTP discharge showed that biota was impacted by the WWTP effluents. When based only on surface water samples, the assessment of freshwater quality did not provide evidence for a marked PAH contamination in either of the rivers studied. However, using SPM and sediment samples, we found PAH contents exceeding sediment quality guidelines. We conclude that sediment and SPM are relevant matrices to assess overall PAH contamination in aquatic ecosystems. Furthermore, we found a positive linear correlation between PAH contents of SPM and sediment, showing that SPM represents an integrating matrix which is able to provide meaningful data about the overall contamination over a given time span.

Water and bed-sediment quality in the vicinity of Berlin Lake, Ohio, 2001

USGS Publications Warehouse

Darner, Robert A.

2002-01-01

Berlin Lake, in northeast Ohio, was created by the U.S. Army Corps of Engineers in 1943 and is used primarily for flood control for the upper reaches of the Mahoning River. The area surrounding and under the lake has been tapped for oil and natural gas production. One of the by-products of oil and gas production is concentrated salt water or brine, which might have an effect on the chemical quality of area potable-water sources. This report presents the results of a U.S. Geological Survey baseline study to collect current (2001) water and sediment-quality data and to characterize water quality in the Berlin Lake watershed. Chloride-to-bromide ratios were used to detect the presence of brine in water samples and to indicate possible adverse effects on water quality. Analyses of ground-water samples from domestic wells in the area indicate a source of chloride and bromide, but defining the source would require more data collection. Analyses of specific conductance and dissolved solids indicate that 78 percent (14 of 18) of the ground-water samples exceeded the Secondary Maximum Contaminant Level for dissolved solids in public water supplies of 500 milligrams per liter (mg/L), compared to 6 percent of samples exceeding 500 mg/L in two nearby studies. Surface water was analyzed twice, once each during low-flow and surface runoff conditions. A comparison of the 2001 data to historical chloride concentrations, accounting for seasonal changes, does not indicate an increase in chloride loads for surface water in the area of Berlin Lake. Polycyclic aromatic hydrocarbons were found in bed-sediment samples collected from the mouths of major tributaries to Berlin Lake. Polycyclic aromatic hydrocarbons are produced during the incomplete combustion of organic carbon materials such as wood and fossil fuels, and they are components of petroleum products.

Summary of Surface-Water Quality Data from the Illinois River Basin in Northeast Oklahoma, 1970-2007

USGS Publications Warehouse

Andrews, William J.; Becker, Mark F.; Smith, S. Jerrod; Tortorelli, Robert L.

2009-01-01

The quality of streams in the Illinois River Basin of northeastern Oklahoma is potentially threatened by increased quantities of wastes discharged from increasing human populations, grazing of about 160,000 cattle, and confined animal feeding operations raising about 20 million chickens. Increasing numbers of humans and livestock in the basin contribute nutrients and bacteria to surface water and groundwater, causing greater than the typical concentrations of those constituents for this region. Consequences of increasing contributions of these substances can include increased algal growth (eutrophication) in streams and lakes; impairment of habitat for native aquatic animals, including desirable game fish species; impairment of drinking-water quality by sediments, turbidity, taste-and-odor causing chemicals, toxic algal compounds, and bacteria; and reduction in the aesthetic quality of the streams. The U.S. Geological Survey, in cooperation with the Oklahoma Scenic Rivers Commission, prepared this report to summarize the surface-water-quality data collected by the U.S. Geological Survey at five long-term surface-water-quality monitoring sites. The data summarized include major ions, nutrients, sediment, and fecal-indicator bacteria from the Illinois River Basin in Oklahoma for 1970 through 2007. General water chemistry, concentrations of nitrogen and phosphorus compounds, chlorophyll-a (an indicator of algal biomass), fecal-indicator bacteria counts, and sediment concentrations were similar among the five long-term monitoring sites in the Illinois River Basin in northeast Oklahoma. Most water samples were phosphorus-limited, meaning that they contained a smaller proportion of phosphorus, relative to nitrogen, than typically occurs in algal tissues. Greater degrees of nitrogen limitation occurred at three of the five sites which were sampled back to the 1970s, probably due to use of detergents containing greater concentrations of phosphorus than in subsequent periods. Concentrations of nitrogen, phosphorus, and sediment, and counts of bacteria generally increased with streamflow at the five sites, probably due to runoff from the land surface and re-suspension of streambed sediments. Phosphorus concentrations typically exceeded the Oklahoma standard of 0.037 milligrams per liter for Scenic Rivers. Concentrations of chlorophyll-a in phytoplankton in water samples collected at the five sites were not well correlated with streamflow, nor to concentrations of the nutrients nitrogen and phosphorus, probably because much of the algae growing in these streams are periphyton attached to streambed cobbles and other debris, rather than phytoplankton in the water column. Sediment concentrations correlated with phosphorus concentrations in water samples collected at the sites, probably due to sorption of phosphorus to soil particles and streambed sediments and runoff of soils and animal wastes at the land surface and resuspension of streambed sediments and phosphorus during wet, high-flow periods. Fecal coliform bacteria counts at the five sites sometimes exceeded the Oklahoma Primary Body Contact Standard of 400 colonies per 100 milliliters when streamflows were greater than 1000 cubic feet per second. Ultimately, Lake Tenkiller, an important ecological and economic resource for the region, receives the compounds that runoff the land surface or seep to local streams from groundwater in the basin. Because of eutrophication from increased nutrient loading, Lake Tenkiller is listed for impairment by diminished dissolved oxygen concentrations, phosphorus, and chlorophyll-a by the State of Oklahoma in evaluation of surface-water quality required by section 303d of the Clean Water Act. Stored phosphorus in soils and streambed and lakebed sediments may continue to provide phosphorus to local streams and lakes for decades to come. Steps are being made to reduce local sources of phosphorus, including upgrades in capacity and effective

Aquatic ecosystems in Central Colorado are influenced by mineral forming processes and historical mining

USGS Publications Warehouse

Schmidt, T.S.; Church, S.E.; Clements, W.H.; Mitchell, K.A.; Fey, D. L.; Wanty, R.B.; Verplanck, P.L.; San, Juan C.A.; Klein, T.L.; deWitt, E.H.; Rockwell, B.W.

2009-01-01

Stream water and sediment toxicity to aquatic insects were quantified from central Colorado catchments to distinguish the effect of geologic processes which result in high background metals concentrations from historical mining. Our sampling design targeted small catchments underlain by rocks of a single lithology, which allowed the development of biological and geochemical baselines without the complication of multiple rock types exposed in the catchment. By accounting for geologic sources of metals to the environment, we were able to distinguish between the environmental effects caused by mining and the weathering of different mineralized areas. Elevated metal concentrations in water and sediment were not restricted to mined catchments. Impairment of aquatic communities also occurred in unmined catchments influenced by hydrothermal alteration. Hydrothermal alteration style, deposit type, and mining were important determinants of water and sediment quality and aquatic community structure. Weathering of unmined porphyry Cu-Mo occurrences resulted in water (median toxic unit (TU) = 108) and sediment quality (TU = 1.9) that exceeded concentrations thought to be safe for aquatic ecosystems (TU = 1). Metalsensitive aquatic insects were virtually absent from streams draining catchments with porphyry Cu-Mo occurrences (1.1 individuals/0.1 m2 ). However, water and sediment quality (TU = 0.1, 0.5 water and sediment, respectively) and presence of metalsensitive aquatic insects (204 individuals/0.1 m2 ) for unmined polymetallic vein occurrences were indistinguishable from that for unmined and unaltered streams (TU = 0.1, 0.5 water and sediment, respectively; 201 individuals/0.1 m2 ). In catchments with mined quartz-sericite-pyrite altered polymetallic vein deposits, water (TU = 8.4) and sediment quality (TU = 3.1) were degraded and more toxic to aquatic insects (36 individuals/0.1 m2 ) than water (TU = 0.4) and sediment quality (TU = 1.7) from mined propylitically altered polymetallic vein deposits. The sampling approach taken in this study distinguishes the effects of different mineral deposits on ecosystems and can be used to more accurately quantify the effect of mining on the environment. 

Characterization of water quality and suspended sediment during cold-season flows, warm-season flows, and stormflows in the Fountain and Monument Creek watersheds, Colorado, 2007–2015

USGS Publications Warehouse

Miller, Lisa D.; Stogner, Sr., Robert W.

2017-09-01

From 2007 through 2015, the U.S. Geological Survey, in cooperation with Colorado Springs City Engineering, conducted a study in the Fountain and Monument Creek watersheds, Colorado, to characterize surface-water quality and suspended-sediment conditions for three different streamflow regimes with an emphasis on characterizing water quality during storm runoff. Data collected during this study were used to evaluate the effects of stormflows and wastewater-treatment effluent discharge on Fountain and Monument Creeks in the Colorado Springs, Colorado, area. Water-quality samples were collected at 2 sites on Upper Fountain Creek, 2 sites on Monument Creek, 3 sites on Lower Fountain Creek, and 13 tributary sites during 3 flow regimes: cold-season flow (November–April), warm-season flow (May–October), and stormflow from 2007 through 2015. During 2015, additional samples were collected and analyzed for Escherichia coli (E. coli) during dry weather conditions at 41 sites, located in E. coli impaired stream reaches, to help identify source areas and scope of the impairment.Concentrations of E. coli, total arsenic, and dissolved copper, selenium, and zinc in surface-water samples were compared to Colorado in-stream standards. Stormflow concentrations of E. coli frequently exceeded the recreational use standard of 126 colonies per 100 milliliters at main-stem and tributary sites by more than an order of magnitude. Even though median E. coli concentrations in warm-season flow samples were lower than median concentrations in storm-flow samples, the water quality standard for E. coli was still exceeded at most main-stem sites and many tributary sites during warm-season flows. Six samples (three warm-season flow and three stormflow samples) collected from Upper Fountain Creek, upstream from the confluence of Monument Creek, and two stormflow samples collected from Lower Fountain Creek, downstream from the confluence with Monument Creek, exceeded the acute water-quality standard for total arsenic of 50 micrograms per liter. All concentrations of dissolved copper, selenium, and zinc measured in samples were below the water-quality standard.Concentrations of dissolved nitrate plus nitrite generally increased from upstream to downstream during all flow periods. The largest downstream increase in dissolved nitrate plus nitrite concentration was measured between sites 07103970 and 07104905 on Monument Creek. All but one tributary that drain into Monument Creek between the two sites had higher median nitrate plus nitrite concentrations than the nearest upstream site on Monument Creek, site 07103970 (MoCr_Woodmen). Increases in the concentration of dissolved nitrate plus nitrite were also evident below wastewater treatment plants located on Fountain Creek.Most stormflow concentrations of dissolved trace elements were smaller than concentrations from cold-season flow or warm-season samples. However, median concentrations of total arsenic, lead, manganese, nickel, and zinc generally were much larger during periods of stormflow than during cold-season flow or warm-season fl. Median concentrations of total arsenic, total copper, total lead, dissolved and total manganese, total nickel, dissolved and total selenium, and dissolved and total zinc concentrations increased from 1.5 to 28.5 times from site 07103700 (FoCr_Manitou) to 07103707 (FoCr_8th) during cold-season and warm-season flows, indicating a large source of trace elements between these two sites. Both of these sites are located on Fountain Creek, upstream from the confluence with Monument Creek.Median suspended-sediment concentrations and median suspended-sediment loads increased in the downstream direction during all streamflow regimes between Monument Creek sites 07103970 (MoCr_Woodmen) and 07104905 (MoCr_Bijou); however, statistically significant increase (p-value less than 0.05) were only present during warm-season flow and stormflow. Significant increases in median suspended sediment concentrations were measured during cold-season flow and warm-season flow between Upper Fountain Creek site 07103707 (FoCr_8th) and Lower Fountain Creek site 07105500 (FoCr_Nevada) because of inflows from Monument Creek with higher suspended-sediment concentrations. Median suspended-sediment concentrations between sites 07104905 (MoCr_Bijou) and 07105500 (FoCr_Nevada) increased significantly during warm-season flow but showed no significant differences during cold-season flow and stormflow. Significant decreases in median suspended-sediment concentrations were measured between sites 07105500 (FoCr_Nevada) and 07105530 (FoCr_Janitell) during all flow regimes.Suspended-sediment concentrations, discharges, and yields associated with stormflow were significantly larger than those associated with warm-season flow. Although large spatial variations in suspended-sediment yields occurred during warm-season flows, the suspended-sediment yield associated with stormflow were as much as 1,000 times larger than the suspended-sediment yields that occurred during warm-season flow. 

Contaminants in surface water and sediments near the Tynagh silver mine site, County Galway, Ireland.

PubMed

O'Neill, A; Phillips, D H; Bowen, J; Sen Gupta, B

2015-04-15

A former silver mine in Tynagh, Co. Galway, Ireland is one of the most contaminated mine sites in Europe with maximum concentrations of Zn, As, Pb, Mn, Ni, Cu, and Cd far exceeding guideline values for water and sediment. The aims of this research were to 1) further assess the contamination, particularly metals, in surface water and sediment around the site, and 2) determine if the contamination has increased 10 years after the Environmental Protection Agency Ireland (EPAI) identified off-site contamination. Site pH is alkaline to neutral because CaCO3-rich sediment and rock material buffer the exposed acid generating sulphide-rich ore. When this study was compared to the previous EPAI study conducted 10 years earlier, it appeared that further weathering of exposed surface sediment had increased concentrations of As and other potentially toxic elements. Water samples from the tailings ponds and adjacent Barnacullia Stream had concentrations of Al, Cd, Mn, Zn and Pb above guideline values. Lead and Zn concentrations from the tailings pond sediment were 16 and 5 times higher, respectively, than concentrations reported 10 years earlier. Pb and Zn levels in most sediment samples exceeded the Expert Group (EGS) guidelines of 1000 and 5000 mg/kg, respectively. Arsenic concentrations were as high as 6238 mg/kg in the tailings ponds sediment, which is 62 and 862 times greater than the EGS and Canadian Soil Quality Guidelines (CSQG), respectively. Cadmium, Cu, Fe, Mn, Pb and Zn concentrations in water and sediment were above guideline values downstream of the site. Additionally, Fe, Mn and organic matter (OM) were strongly correlated and correlated to Zn, Pb, As, Cd, Cu and Ni in stream sediment. Therefore, the nearby Barnacullia Stream is also a significant pathway for contaminant transport to downstream areas. Further rehabilitation of the site may decrease the contamination around the area. Copyright © 2015 Elsevier B.V. All rights reserved.

Present and Reference Concentrations and Yields of Suspended Sediment in Streams in the Great Lakes Region and Adjacent Areas

USGS Publications Warehouse

Robertson, Dale M.; Saad, David A.; Heisey, Dennis M.

2006-01-01

In-stream suspended sediment and siltation and downstream sedimentation are common problems in surface waters throughout the United States. The most effective way to improve surface waters impaired by sediments is to reduce the contributions from human activities rather than try to reduce loadings from natural sources. Total suspended sediment/solids (TSS) concentration data were obtained from 964 streams in the Great Lakes, Ohio, Upper Mississippi, and Souris-Red-Rainy River Basins from 1951 to 2002. These data were used to estimate median concentrations, loads, yields, and volumetrically (flow) weighted (VW) concentrations where streamflow data were available. SPAtial Regression-Tree Analysis (SPARTA) was applied to land-use-adjusted (residualized) TSS data and environmental-characteristic data to determine the natural factors that best described the distribution of median and VW TSS concentrations and yields and to delineate zones with similar natural factors affecting TSS, enabling reference or natural concentrations and yields to be estimated. Soil properties (clay and organic-matter content, erodibility, and permeability), basin slope, and land use (percentage of agriculture) were the factors most strongly related to the distribution of median and VW TSS concentrations. TSS yields were most strongly related to amount of precipitation and the resulting runoff, and secondarily to the factors related to high TSS concentrations. Reference median TSS concentrations ranged from 5 to 26 milligrams per liter (mg/L), reference median annual VW TSS concentrations ranged from 10 to 168 mg/L, and reference TSS yields ranged from about 980 to 90,000 kilograms per square kilometer per year. Independent streams (streams with no overlapping drainage areas) with TSS data were ranked by how much their water quality exceeded reference concentrations and yields. Most streams exceeding reference conditions were in the central part of the study area, where agricultural activities are the most intensive; however, other sites exceeding reference conditions were identified outside of this area. Whether concentrations or yields should be considered in guiding rehabilitation efforts depends on whether in-stream or downstream effects are more important. Although this study attempted to obtain all available water-quality data for the study area, any actual prioritization of sites for remediation would need to rely on more extensive data collection or numerical models that can accurately simulate the effects of various human activities in a range of environmental settings.

Spatial and temporal patterns in trace element deposition to lakes in the Athabasca oil sands region (Alberta, Canada)

NASA Astrophysics Data System (ADS)

Cooke, Colin A.; Kirk, Jane L.; Muir, Derek C. G.; Wiklund, Johan A.; Wang, Xiaowa; Gleason, Amber; Evans, Marlene S.

2017-12-01

The mining and processing of the Athabasca oil sands (Alberta, Canada) has been occurring for decades; however, a lack of consistent regional monitoring has obscured the long-term environmental impact. Here, we present sediment core results to reconstruct spatial and temporal patterns in trace element deposition to lakes in the Athabasca oil sands region. Early mining operations (during the 1970s and 1980s) led to elevated V and Pb inputs to lakes located <50 km from mining operations. Subsequent improvements to mining and upgrading technologies since the 1980s have reduced V and Pb loading to near background levels at many sites. In contrast, Hg deposition increased by a factor of ~3 to all 20 lakes over the 20th century, reflecting global-scale patterns in atmospheric Hg emissions. Base cation deposition (from fugitive dust emissions) has not measurably impacted regional lake sediments. Instead, results from a principal components analysis suggest that the presence of carbonate bedrock underlying lakes located close to development appears to exert a first-order control over lake sediment base cation concentrations and overall lake sediment geochemical composition. Trace element concentrations generally did not exceed Canadian sediment quality guidelines, and no spatial or temporal trends were observed in the frequency of guideline exceedence. Our results demonstrate that early mining efforts had an even greater impact on trace element cycling than has been appreciated previously, placing recent monitoring efforts in a critical long-term context.

Distribution of butyltins and alternative antifouling biocides in sediments from shipping and shipbuilding areas in South Korea.

PubMed

Kim, Nam Sook; Hong, Sang Hee; An, Joon Geon; Shin, Kyung-Hoon; Shim, Won Joon

2015-06-15

The occurrence and distribution of tributyltin (TBT) and alternative biocides were investigated in sediment from semi-enclosed bays, fishing ports, and large commercial harbors in Korea. Extremely high concentration of TBT (55,264ngSn/g) was detected near a large shipyard, even after a total ban on its use in Korea. Diuron was the biocide with the highest detection frequency and concentration levels, followed by Irgarol 1051. Sea-Nine 211 was detected at 3 of 32 stations surveyed. Dichlofluanid, zinc and copper pyrithiones levels were below the detection limits at all the stations surveyed. The relatively high levels of Diuron (9-62.3ng/g) and Irgarol 1051 (1.5-11.5ng/g) were detected in harbor and shipyard areas. Diuron and Irgarol 1051 levels including TBT in sediments from hot spots in Korea exceeded global sediment quality guidelines. Copyright © 2015 Elsevier Ltd. All rights reserved.

Heavy metal concentration in mangrove surface sediments from the north-west coast of South America.

PubMed

Fernández-Cadena, J C; Andrade, S; Silva-Coello, C L; De la Iglesia, R

2014-05-15

Mangrove ecosystems are coastal estuarine systems confined to the tropical and subtropical regions. The Estero Salado mangrove located in Guayaquil, Ecuador, has suffered constant disturbances during the past 20 years, due to industrial wastewater release. However, there are no published data for heavy metals present in its sediments and the relationship with anthropogenic disturbance. In the present study, metal concentrations were evaluated in surface sediment samples of the mangrove, showing that B, Cd, Cu, Pb, Se, V, and Zn levels exceeded those declared in international environmental quality standards. Moreover, several metals (Pb, Sn, Cd, Ag, Mo, Zn and Ni) could be linked to the industrial wastewater present in the studied area. In addition, heavy metal levels detected in this mangrove are higher than previous reports on mangrove sediments worldwide, indicating that this mangrove ecosystem is one of the most disrupted on earth. Copyright © 2014 Elsevier Ltd. All rights reserved.

Geochemistry of acid mine drainage from a coal mining area and processes controlling metal attenuation in stream waters, southern Brazil.

PubMed

Campaner, Veridiana P; Luiz-Silva, Wanilson; Machado, Wilson

2014-05-14

Acid drainage influence on the water and sediment quality was investigated in a coal mining area (southern Brazil). Mine drainage showed pH between 3.2 and 4.6 and elevated concentrations of sulfate, As and metals, of which, Fe, Mn and Zn exceeded the limits for the emission of effluents stated in the Brazilian legislation. Arsenic also exceeded the limit, but only slightly. Groundwater monitoring wells from active mines and tailings piles showed pH interval and chemical concentrations similar to those of mine drainage. However, the river and ground water samples of municipal public water supplies revealed a pH range from 7.2 to 7.5 and low chemical concentrations, although Cd concentration slightly exceeded the limit adopted by Brazilian legislation for groundwater. In general, surface waters showed large pH range (6 to 10.8), and changes caused by acid drainage in the chemical composition of these waters were not very significant. Locally, acid drainage seemed to have dissolved carbonate rocks present in the local stratigraphic sequence, attenuating the dispersion of metals and As. Stream sediments presented anomalies of these elements, which were strongly dependent on the proximity of tailings piles and abandoned mines. We found that precipitation processes in sediments and the dilution of dissolved phases were responsible for the attenuation of the concentrations of the metals and As in the acid drainage and river water mixing zone. In general, a larger influence of mining activities on the chemical composition of the surface waters and sediments was observed when enrichment factors in relation to regional background levels were used.

A risk assessment approach to contaminants in Port Curtis, Queensland, Australia.

PubMed

Jones, Mary-Anne; Stauber, Jenny; Apte, Simon; Simpson, Stuart; Vicente-Beckett, Vicky; Johnson, Rod; Duivenvoorden, Leo

2005-01-01

Port Curtis is one of Australia's leading ports for which substantial industrial expansion is proposed over the next decade. However, there has been little attempt to date to assess the extent of contamination in waters, sediments and biota or to characterize the potential impacts of contaminants on aquatic biota. Contaminants of potential concern to biota and human health were investigated in the Port Curtis estuary using a screening-level risk assessment approach. Dissolved metal concentrations in waters were below [ANZECC/ARMCANZ, 2000. Australian and New Zealand Guidelines for Fresh and Marine Water Quality, Vol. 1. The Guidelines, Australian and New Zealand Environment and Conservation Council and Agriculture and Resource Management Council of Australia and New Zealand] trigger values, suggesting low risk of these contaminants. In sediments, arsenic, nickel and chromium concentrations exceeded interim sediment quality guidelines-low (ISQG-low), but were also high in the reference zone suggesting a natural origin. Historical data on naphthalene in Harbour sediments showed that it was also of potential concern. Bioaccumulation of contaminants in a range of biota was also used as an indicator of contaminant exposure. Biota were generally enriched in metals and tributyltin, which was also elevated in water and sediments. Although not unique to Port Curtis, mercury in barramundi was identified as a potential risk to human health.

Heavy metal pollution and spatial distribution in surface sediments of Mustafakemalpaşa stream located in the world's largest borate basin (Turkey).

PubMed

Omwene, Philip Isaac; Öncel, Mehmet Salim; Çelen, Meltem; Kobya, Mehmet

2018-06-07

Mining activities in addition to the geology of Mustafakemalpaşa catchment have for long been linked to its deteriorating water and sediment quality. This study assessed contamination levels of heavy metals and other major elements (Pb, As, B, Cd, Zn, Cr, Mo, Co, Ni, Cu, and Ag) in surface sediments of the area, and identified possible pollution sources. Sediment quality indicators, such as contamination factor (CF), enrichment factor (EF), geo-accumulation index (I geo ) and sediment quality guidelines were used, in addition to multivariate statistical technics; Pearson Correlation Matrix (PCM), Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (HCA). The highest contamination (annual average > 110 mg kg -1 ) was revealed by B, Cr, Ni, Zn and As. Moreover, As, Cd and Ni levels exceeded their respective probable effect concentrations (PEC), posing a potential negative impact to biota. The highest I geo values were recorded for Cr, B, Ni, As and Zn, and occurred near urban settlements and mining sites, particularly of coal and chromium. The present study also suggests use of site rank index (SRI) as an alternative to pollution load index (PLI), since the former is derived from the data of interest and eliminates arbitrary classifications. The sources of heavy metals in the sediments were attributed to fly ashes of coal-powered plants, urban waste leachate and weathering of sulfide ore minerals for Pb, Zn and Cu; urban-industrial wastes and mining wastes for Ni. Although Cr, As, Cd and B were ascribed to natural occurrence, their presences in river sediment is accelerated by mining. Copyright © 2018 Elsevier Ltd. All rights reserved.

Assessing sediments from Upper Mississippi River navigational pools using a benthic invertebrate community evaluation and the sediment quality triad approach

USGS Publications Warehouse

Canfield, T.J.; Brunson, E.L.; Dwyer, F.J.; Ingersoll, C.G.; Kemble, N.E.

1998-01-01

Benthic invertebrate samples were collected from 23 pools in the Upper Mississippi River (UMR) and from one station in the Saint Croix River (SCR) as part of a study to assess the effects of the extensive flooding of 1993 on sediment contamination in the UMR system. Sediment contaminants of concern included both organic and inorganic compounds. Oligochaetes and chironomids constituted over 80% of the total abundance in samples from 14 of 23 pools in the UMR and SCR samples. Fingernail clams comprised a large portion of the community in three of 23 UMR pools and exceeded abundances of 1,000/m2 in five of 23 pools. Total abundance ranged from 250/m2 in samples from pool 1 to 22,389/m2 in samples from pool 19. Abundance values are comparable with levels previously reported in the literature for the UMR. Overall frequency of chironomid mouthpart deformities was 3% (range 0-13%), which is comparable to reported incidence of deformities in uncontaminated sediments previously evaluated. Sediment contamination was generally low in the UMR pools and the SCR site. Correlations between benthic measures and sediment chemistry and other abiotic parameters exhibited few significant or strong correlations. The sediment quality triad (Triad) approach was used to evaluate data from laboratory toxicity tests, sediment chemistry, and benthic community analyses; it showed that 88% of the samples were not scored as impacted based on sediment toxicity, chemistry, and benthic measures. Benthic invertebrate distributions and community structure within the UMR in the samples evaluated in the present study were most likely controlled by factors independent of contaminant concentrations in the sediments.

Sediment-associated aliphatic and aromatic hydrocarbons in coastal British Columbia, Canada: concentrations, composition, and associated risks to protected sea otters.

PubMed

Harris, Kate A; Yunker, Mark B; Dangerfield, Neil; Ross, Peter S

2011-10-01

Sediment-associated hydrocarbons can pose a risk to wildlife that rely on benthic marine food webs. We measured hydrocarbons in sediments from the habitat of protected sea otters in coastal British Columbia, Canada. Alkane concentrations were dominated by higher odd-chain n-alkanes at all sites, indicating terrestrial plant inputs. While remote sites were dominated by petrogenic polycyclic aromatic hydrocarbons (PAHs), small harbour sites within sea otter habitat and sites from an urban reference area reflected weathered petroleum and biomass and fossil fuel combustion. The partitioning of hydrocarbons between sediments and adjacent food webs provides an important exposure route for sea otters, as they consume ∼25% of their body weight per day in benthic invertebrates. Thus, exceedences of PAH sediment quality guidelines designed to protect aquatic biota at 20% of the sites in sea otter habitat suggest that sea otters are vulnerable to hydrocarbon contamination even in the absence of catastrophic oil spills. Copyright © 2011 Elsevier Ltd. All rights reserved.

Occurrence and transport of selected constituents in streams near the Stibnite mining area, Central Idaho, 2012–14

USGS Publications Warehouse

Etheridge, Alexandra B.

2015-12-07

Ninety-eight percent of the estimated total mercury load transported downstream of the study area is attributable to Sugar Creek. A maximum concentration of 26 micrograms per liter was measured in Sugar Creek during May 2013 when snowmelt runoff occurred during a single peak in the hydrograph. Monitoring and modeling results indicate sediment and sediment-associated constituent concentrations and loads increase along Meadow Creek, likely because of the inflow of the East Fork of Meadow Creek, and decrease between sites 3 and 4 because the Glory Hole is trapping sediments. Sugar Creek (site 5) accounted for most of the sediment and sediment-associated constituent loading leaving the study area because loads from the East Fork of Meadow Creek remained trapped in the Glory Hole. Additionally, total mercury was detected at all five streamflow-gaging stations, and sampled mercury concentrations exceeded Idaho ambient water-quality criteria at all five streamflow-gaging stations.

Trace Elements in the Marine Sediments of the La Paz Lagoon, Baja California Peninsula, Mexico: Pollution Status in 2013.

PubMed

Pérez-Tribouillier, Habacuc; Shumilin, Evgueni; Rodríguez-Figueroa, Griselda Margarita

2015-07-01

To determine the actual concentrations of trace elements in surface sediments from the La Paz Lagoon, as well as their associations and possible origins, 91 sediment samples were analyzed for more than 50 elements using a combination of ICP-MS and ICP-AES. The results of a principal component analysis are used to distinguish four associative groups within the elements. Natural enrichment of As, Cd and U occurs due to the supply of weathered phosphorites from the El Cien formation located to the north-west of the lagoon. Sediment quality indices for potentially toxic trace elements do not show any probable impact on the biota of the lagoon. Only the concentrations of As in 30 % of the stations and Cu in 20 % of them exceed related effect range low levels. The highest concentration of Pb (36.8 mg kg(-1)) was measured in the sediments near the City of La Paz.

Petroleum pollution in mangrove forests sediments from Qeshm Island and Khamir Port-Persian Gulf, Iran.

PubMed

Ebrahimi-Sirizi, Zohreh; Riyahi-Bakhtiyari, Alireza

2013-05-01

The concentrations of total polycyclic aromatic hydrocarbons (PAHs) and 22 individual PAH compounds in 42 surface sediments collected from the mangrove forest of Qeshm Island and Khamir Port (Persian Gulf) were analyzed. PAHs concentrations ranged from 259 to 5,376 ng g(-1) dry weight with mean and median values of 1,585 and 1,146 ng g(-1), respectively. The mangrove sediments had higher percentages of lower molecular weight PAHs and the PAH profiles were dominated by naphthalene. Ratio values of specific PAH compounds were calculated to evaluate the possible source of PAH contamination. This ratios suggesting that the mangrove sediments have a petrogenic input of PAHs. Sediment quality guidelines were conducted to assess the toxicity of PAH compounds. The levels of total PAHs at all of stations except one station, namely Q6, were below the effects range low. Also, concentrations of naphthalene in some stations exceeded the effects range median.

Heavy metal pollution in sediments of the largest reservoir (Three Gorges Reservoir) in China: a review.

PubMed

Zhao, Xingjuan; Gao, Bo; Xu, Dongyu; Gao, Li; Yin, Shuhua

2017-09-01

The Three Gorges Dam in China is the world's largest dam. Upon its completion in 2003, the Three Gorges Reservoir (TGR) became the largest reservoir in China and plays an important role in economic development and national drinking water safety. However, as a sink and source of heavy metals, there is a lack of continuous and comparative data on heavy metal pollution in sediments. This study reviewed all available literatures published on heavy metals in TGR sediments and further provided a comprehensive assessment of the pollution tendency of these heavy metals. The results showed that heavy metal concentrations in TGR sediments varied spatially and temporally. Temporal variations indicated that Hg in tributaries, as well as As, Cd, Cr, Cu, Ni, Pb, and Zn in the mainstream, exhibited a higher probability to exceed background values after the impoundment of TGR. Pollution assessments by contamination factor, geoaccumulation index, and potential ecological risk were similar. High Cd and Hg concentrations in both the mainstream and tributaries are a cause for much concern. However, sediment quality guidelines produced different results, as most previous studies adopted different sampling and measurement strategies. The data inconsistencies and lack of continuity regarding the reservoir confirm the need for a continuous monitoring network and the development of quality criteria relevant to the sediments of the TGR in the future.

Distribution and Potential Toxicity of Trace Metals in the Surface Sediments of Sundarban Mangrove Ecosystem, Bangladesh

NASA Astrophysics Data System (ADS)

Kumar, A.; Ramanathan, A.; Mathukumalli, B. K. P.; Datta, D. K.

2014-12-01

The distribution, enrichment and ecotoxocity potential of Bangladesh part of Sundarban mangrove was investigated for eight trace metals (As, Cd, Cr, Cu, Fe, Mn, Pb and Zn) using sediment quality assessment indices. The average concentration of trace metals in the sediments exceeded the crustal abundance suggesting sources other than natural in origin. Additionally, the trace metals profile may be a reflection of socio-economic development in the vicinity of Sundarban which further attributes trace metals abundance to the anthropogenic inputs. Geoaccumulation index suggests moderately polluted sediment quality w.r.t. Ni and As and background concentrations for Al, Fe, Mn, Cu, Zn, Pb, Co, As and Cd. Contamination factor analysis suggested low contamination by Zn, Cr, Co and Cd, moderate by Fe, Mn, Cu and Pb while Ni and As show considerable and high contamination, respectively. Enrichment factors for Ni, Pb and As suggests high contamination from either biota or anthropogenic inputs besides natural enrichment. As per the three sediment quality guidelines, Fe, Mn, Cu, Ni, Co and As would be more of a concern with respect to ecotoxicological risk in the Sundarban mangroves. The correlation between various physiochemical variables and trace metals suggested significant role of fine grained particles (clay) in trace metal distribution whereas owing to low organic carbon content in the region the organic complexation may not be playing significant role in trace metal distribution in the Sundarban mangroves.

Sedimentation, sediment quality, and upstream channel stability, John Redmond Reservoir, east-central Kansas, 1964-2009

USGS Publications Warehouse

Juracek, Kyle E.

2010-01-01

A combination of available bathymetric-survey information, bottom-sediment coring, and historical streamgage information was used to investigate sedimentation, sediment quality, and upstream channel stability for John Redmond Reservoir, east-central Kansas. Ongoing sedimentation is reducing the ability of the reservoir to serve several purposes including flood control, water supply, and recreation. The total estimated volume and mass of bottom sediment deposited between 1964 and 2009 in the conservation pool of the reservoir was 1.46 billion cubic feet and 55.8 billion pounds, respectively. The estimated sediment volume occupied about 41 percent of the conservation-pool, water-storage capacity of the reservoir. Water-storage capacity in the conservation pool has been lost to sedimentation at a rate of about 1 percent annually. Mean annual net sediment deposition since 1964 in the conservation pool of the reservoir was estimated to be 1.24 billion pounds per year. Mean annual net sediment yield from the reservoir basin was estimated to be 411,000 pounds per square mile per year Information from sediment cores shows that throughout the history of John Redmond Reservoir, total nitrogen concentrations in the deposited sediment generally were uniform indicating consistent nitrogen inputs to the reservoir. Total phosphorus concentrations in the deposited sediment were more variable than total nitrogen indicating the possibility of changing phosphorus inputs to the reservoir. As the principal limiting factor for primary production in most freshwater environments, phosphorus is of particular importance because increased inputs can contribute to accelerated reservoir eutrophication and the production of algal toxins and taste-and-odor compounds. The mean annual net loads of total nitrogen and total phosphorus deposited in the bottom sediment of the reservoir were estimated to be 2,350,000 pounds per year and 1,030,000 pounds per year, respectively. The estimated mean annual net yields of total nitrogen and total phosphorus from the reservoir basin were 779 pounds per square mile per year and 342 pounds per square mile per year, respectively. Trace element concentrations in the bottom sediment of John Redmond Reservoir generally were uniform over time. As is typical for eastern Kansas reservoirs, arsenic, chromium, and nickel concentrations typically exceeded the threshold-effects guidelines, which represent the concentrations above which toxic biological effects occasionally occur. Trace element concentrations did not exceed the probable-effects guidelines (available for eight trace elements), which represent the concentrations above which toxic biological effects usually or frequently occur. Organochlorine compounds either were not detected or were detected at concentrations that were less than the threshold-effects guidelines. Stream channel banks, compared to channel beds, likely are a more important source of sediment to John Redmond Reservoir from the upstream basin. Other sediment sources include surface-soil erosion in the basin and shoreline erosion in the reservoir.

Weight-of-evidence approach in assessment of ecotoxicological risks of acid sulphate soils in the Baltic Sea river estuaries.

PubMed

Wallin, Jaana; Karjalainen, Anna K; Schultz, Eija; Järvistö, Johanna; Leppänen, Matti; Vuori, Kari-Matti

2015-03-01

Acidity and leaching of metals from acid sulphate soils (ASSs) impair the water quality of receiving surface waters. The largest ASS areas in Europe are found in the coasts of the northern Baltic Sea. We used weight-of-evidence (WoE) approach to assess potential risks in 14 estuary sites affected by ASS in the Gulf of Finland, northern Baltic Sea. The assessment was based on exposure and effect profiles utilizing sediment and water metal concentrations and concurrent pH variation, sediment toxicity tests using the luminescent bacterium Vibrio fischeri and the midge Chironomus riparius, and the ecological status of benthic macroinvertebrate communities. Sediment metal concentrations were compared to national sediment quality criteria/guidelines, and water metal concentrations to environmental quality standards (EQSs). Hazard quotients (HQs) were established for maximum aluminium, cadmium and zinc concentrations at low pH based on applicable US EPA toxicity database. Sediment metal concentrations were clearly elevated in most of the studied estuaries. The EQS of cadmium (0.1 μg/l) was exceeded in 3 estuaries out of 14. The pH-minima were below the national threshold value (5.5) between good and satisfactory water quality in 10 estuaries. V. fischeri bioluminescence indicated toxicity of the sediments but toxic response was not observed in the C. riparius emergence test. Benthic invertebrate communities were deteriorated in 6 out of 14 sites based on the benthic invertebrate quality index. The overall ecotoxicological risk was assessed as low in five, moderate in three and high in five of the estuary sites. The risk assessment utilizing the WoE approach indicated that harmful effects of ASSs are likely to occur in the Baltic Sea river estuaries located at the ASS hotspot area. Copyright © 2014 Elsevier B.V. All rights reserved.

Water-quality assessment of the Sacramento River basin, California : water quality of fixed sites, 1996-1998

USGS Publications Warehouse

Domagalski, Joseph L.; Dileanis, Peter D.

2000-01-01

Water-quality samples were collected from 12 sites in the Sacramento River Basin, Cali-fornia, from February 1996 through April 1998. Field measurements (dissolved oxygen, pH, specific conductance, alkalinity, and water tem-perature) were completed on all samples, and laboratory analyses were done for suspended sediments, nutrients, dissolved and particulate organic carbon, major ions, trace elements, and mercury species. Samples were collected at four types of locations on the Sacramento River?large tributaries to the Sacramento River, agricul-tural drainage canals, an urban stream, and a flood control channel. The samples were collected across a range of flow conditions representative of those sites during the timeframe of the study. The water samples from the Sacramento River indi-cate that specific conductance increases slightly downstream but that the water quality is indicative of dilute water. Water temperature of the Sacramento River increases below Shasta Lake during the spring and summer irrigation season owing to diversion of water out of the river and subsequent lower flow. All 12 sites had generally low concentrations of nutrients, but chlorophyll concentrations were not measured; therefore, the actual consequences of nutrient loading could not be adequately assessed. Concentrations of dis-solved organic carbon in samples from the Sacramento River and the major tributaries were generally low; the formation of trihalomethanes probably does not currently pose a problem when water from the Sacramento River and its major tributaries is chlorinated for drinking-water purposes. However, dissolved organic carbon concentrations were higher in the urban stream and in agricultural drainage canals, but were diluted upon mixing with the Sacramento River. The only trace element that currently poses a water-quality problem in the Sacramento River is mercury. A federal criterion for the protection of aquatic life was exceeded during this study, and floodwater concentrations of mercury were mostly higher than the criterion. Exceedances of water-quality standards happened most frequently during winter when suspended-sediment concen-trations also were elevated. Most mercury is found in association with suspended sediment. The greatest loading or transport of mercury out of the Sacramento River Basin to the San Francisco Bay occurs in the winter and principally follows storm events.

Mobilisation of toxic trace elements under various beach nourishments.

PubMed

Pit, Iris R; Dekker, Stefan C; Kanters, Tobias J; Wassen, Martin J; Griffioen, Jasper

2017-12-01

To enhance protection and maintain wide beaches for recreation, beaches are replenished with sand: so-called beach nourishments. We compared four sites: two traditional beach nourishments, a mega beach nourishment and a reference without beach nourishment. Two sites contain calcareous-rich sand, whereas the other two sites have calcareous-poor sand. We aimed to understand hydrogeochemical processes to indicate factors critical for the mobility of trace elements at nourishments. We therefore analysed the chemical characteristics of sediment and pore water to ascertain the main drivers that mobilise toxic trace elements. With Dutch Quality Standards for soil and groundwater, the characteristics of sediment and pore water were compared to Target Values (the values at which there is a sustainable soil quality) and Intervention Values (the threshold above which the soil's functions are at risk). The pore water characteristics revealed that Target Values were regularly exceeded, especially for the nourishment sites and mainly for Mo (78%), Ni (24%), Cr (55%), and As (21%); Intervention Values for shallow groundwater were occasionally exceeded for As (2%), Cr (2%) and Zn (2%). The sediment characteristics did not exceed the Target Values and showed that trace elements were mainly present in the fine fraction of <150 μm. The oxidation of sulphide minerals such as pyrite resulted into the elevated concentration for all nourishment sites, especially when an unsaturated zone was present and influence of rainwater was apparent. To prevent trace metal mobility at a mega beach nourishment it is important to retain seawater influences and limit oxidation processes. In this respect, a shoreface nourishment is recommended rather than a mega beach nourishment with a thick unsaturated zone. Consequently, we conclude that whether a site is carbonate-rich or carbonate-poor is unimportant, as the influence of seawater will prevent decalcification, creating a low risk of mobilisation of trace elements. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

Ecological risk assessment of heavy metals from the surficial sediments of a shallow coastal lagoon, Egypt.

PubMed

Abdallah, Maha Ahmed Mohamed

2011-07-01

Sediment quality of Lake Maryout (one of the four Nile Delta shallow brackish water lakes on the south-eastern coast of the Mediterranean Sea) is of concern as this lake is used for land reclamation and aquaculture and is an important fishing source. The magnitude and ecological relevance of metal pollution in Lake Maryout Main Basin was investigated by applying different sediment quality assessment approaches. The aim of this study was to estimate ecological risk of trace elements (Cd, Ni, Pb, Cr, Cu and Zn) in the surficial sediments (<63 jtm fraction) of Lake Maryout. Heavily contaminated sediments were evaluated by the Sediment Quality Guideline (SQG) of the US Environmental Protection Agency. The degree of contamination (Cd) was estimated as very high for each site. Two sets of SQGs effect range-low/effect range-median values and threshold effect concentration (TEC) and probable effect concentration (PEC) values were used in this study. Sediments from each site were judged toxic when more of the PEC values exceeded EPA guidelines. Based on the geoaccumulation index (Ieo) of target trace elements, the Main Basin of Lake Maryout has to be considered as extremely polluted with Cd (Igeo > or =5), strongly polluted with Zn (2 < or = Igeo < or =3), moderately polluted with Cu (1 < or = Igeo < or = 2), unpolluted to moderately polluted with Cr and Pb (0 < or = Igeo < or = 1 for each) and unpolluted with Ni (Igeo < or = 0). Lake Maryout sediments had heavy accumulations of Cd, which apparently come from drains that include industrial and raw domestic wastes. Therefore, a sequential extraction technique was applied to assess the five fractions (exchangeable, metals bound to carbonate, acid-reducible, oxidizable-organic and residual) of Cd in surface sediments. The Cd concentration in most sampling stations was dominated by the non-resistant fraction (anthropogenic). The result showed that those stations located in the vicinity of municipal and mixed waste drains posed a high potential risk to fauna and flora of Maryout Lake.

Fractionation and potential toxic risk of metals from superficial sediment in Itaipu Lake--boundary between Brazil and Paraguay.

PubMed

Kalwa, Miguel; Quináia, Sueli Pércio; Pletsch, Adelmo L; Techy, Laura; Felsner, Maria Lurdes

2013-01-01

The objective of this study was to evaluate fractions of metals (labile and pseudo-total) extracted from sediment samples collected in Itaipu Lake (boundary between Brazil and Paraguay) and to assess the dynamics and mobility of these fractions by identifying the same bioavailability and ecological risk to metals in the aquatic environment. The concentrations of metal ions were determined by flame atomic absorption spectrometry. There was a correlation between the metal ions, both in the labile and the pseudo-total, with regard to particle size. To assess metals concentrations in sediment, numerical sediment-quality guidelines were applied. The concentrations of aluminum, cadmium, iron, manganese, lead, and zinc in all sediment samples are lower than the proposed probable effects level (PEL), thus possibly indicating that there are no harmful effects from these metals. In contrast, concentrations of copper, chromium, and nickel exceeded the PEL in some samples, thus indicating that these stations are at potential risk. The level of contamination in sediments of Itaipu Lake for all metals was evaluated using contamination factor, degree of contamination, and sum-of-metals toxic unit.

Investigation of water quality and aquatic-community structure in Village and Valley Creeks, City of Birmingham, Jefferson County, Alabama, 2000-01

USGS Publications Warehouse

McPherson, Ann K.; Abrahamsen, Thomas A.; Journey, Celeste A.

2002-01-01

The U.S. Geological Survey conducted a 16-month investigation of water quality, aquatic-community structure, bed sediment, and fish tissue in Village and Valley Creeks, two urban streams that drain areas of highly intensive residential, commercial, and industrial land use in Birmingham, Alabama. Water-quality data were collected between February 2000 and March 2001 at four sites on Village Creek, three sites on Valley Creek, and at two reference sites near Birmingham?Fivemile Creek and Little Cahaba River, both of which drain less-urbanized areas. Stream samples were analyzed for major ions, nutrients, fecal bacteria, trace and major elements, pesticides, and selected organic constituents. Bed-sediment and fish-tissue samples were analyzed for trace and major elements, pesticides, polychlorinated biphenyls, and additional organic compounds. Aquatic-community structure was evaluated by conducting one survey of the fish community and in-stream habitat and two surveys of the benthic-invertebrate community. Bed-sediment and fish-tissue samples, benthic-invertebrates, and habitat data were collected between June 2000 and October 2000 at six of the nine water-quality sites; fish communities were evaluated in April and May 2001 at the six sites where habitat and benthic-invertebrate data were collected. The occurrence and distribution of chemical constituents in the water column and bed sediment provided an initial assessment of water quality in the streams. The structure of the aquatic communities, the physical condition of the fish, and the chemical analyses of fish tissue provided an indication of the cumulative effects of water quality on the aquatic biota. Water chemistry was similar at all sites, characterized by strong calcium-bicarbonate component and magnesium components. Median concentrations of total nitrogen and total phosphorus were highest at the headwaters of Valley Creek and lowest at the reference site on Fivemile Creek. In Village Creek, median concentrations of nitrite and ammonia increased in a downstream direction. In Valley Creek, median concentrations of nitrate, nitrite, ammonia, organic nitrogen, suspended phosphorus, and orthophosphate decreased in a downstream direction. Median concentrations of Escherichia coli and fecal coliform bacteria were highest at the most upstream site of Valley Creek and lowest at the reference site on Fivemile Creek. Concentrations of enterococci exceeded the U.S. Environmental Protection Agency criterion in 80 percent of the samples; concentrations of Escherichia coli exceeded the criterion in 56 percent of the samples. Concentrations of bacteria at the downstream sites on Village and Valley Creeks were elevated during high flow rather than low flow, indicating the presence of nonpoint sources. Surface-water samples were analyzed for chemical compounds that are commonly found in wastewater and urban runoff. The median number of wastewater indicators was highest at the most upstream site on Valley Creek and lowest at the reference site on Fivemile Creek. Concentrations of total recoverable cadmium, copper, lead, and zinc in surface water exceeded acute and chronic aquatic life criteria in up to 24 percent of the samples that were analyzed for trace and major elements. High concentrations of trace and major elements in the water column were detected most frequently during high flow, indicating the presence of nonpoint sources. Of the 24 pesticides detected in surface water, 17 were herbicides and 7 were insecticides. Atrazine, simazine, and prometon were the most commonly detected herbicides; diazinon, chlorpyrifos, and carbaryl were the most commonly detected insecticides. Concentrations of atrazine, carbaryl, chlorpyrifos, diazinon, and malathion periodically exceeded criteria for the protection of aquatic life. Trace-element priority pollutants, pesticides, and other organic compounds were detected in higher concentrations in bed sediment at the Village and Valley Creek sites t

Water-quality investigations of the Jordan River, Salt Lake County, Utah, 1980-82

USGS Publications Warehouse

Stephens, D.W.

1984-01-01

Water-quality studies were conducted on the Jordan River, Utah, to investigate specific problems: dissolved oxygen, toxic substances, sanitary quality, and turbidity and suspended sediment. The dissolved oxygen decreased from 8 milligrams per liter at the Jordan Narrows to less than 5 milligrams per liter at 500 North Street. Chemical oxygen demand increased about 23 percent and biochemical oxygen demand increased 90 percent. Nearly 78 percent of the water samples analyzed for total mercury exceeded the State intended-use standard of 0.05 microgram per liter. Concentrations of ammonia, cadmium, copper, lead, and zinc exceeded the standards periodically. The pesticides DDD, DDE, DDT, dieldrin, methoxychlor, and 2,4-D were occasionally detected in bottom materials. Most were present in quantities of less than 15 micrograms per kilogram. Concentrations of three indicator bacteria (total coliform, fecal coliform, and fecal streptococcus) increased in a downstream direction. Concentrations of total coliform bacteria often exceeded 5,000 colonies per 100 milliliters and concentrations of fecal coliform bacteria often exceeded 2,000 colonies per 100 milliliters. The primary sources of turbidity in the Jordan River are Utah Lake and discharges from the wastewater-treatment plants. Large values of turbidity were measured at the Jordan Narrows with a summer mean value of 88 nephelometer turbidity units (NTU) and a winter mean value of 43 NTU. (USGS)

Estimation of constituent concentrations, densities, loads, and yields in lower Kansas River, northeast Kansas, using regression models and continuous water-quality monitoring, January 2000 through December 2003

USGS Publications Warehouse

Rasmussen, Teresa J.; Ziegler, Andrew C.; Rasmussen, Patrick P.

2005-01-01

The lower Kansas River is an important source of drinking water for hundreds of thousands of people in northeast Kansas. Constituents of concern identified by the Kansas Department of Health and Environment (KDHE) for streams in the lower Kansas River Basin include sulfate, chloride, nutrients, atrazine, bacteria, and sediment. Real-time continuous water-quality monitors were operated at three locations along the lower Kansas River from July 1999 through September 2004 to provide in-stream measurements of specific conductance, pH, water temperature, turbidity, and dissolved oxygen and to estimate concentrations for constituents of concern. Estimates of concentration and densities were combined with streamflow to calculate constituent loads and yields from January 2000 through December 2003. The Wamego monitoring site is located 44 river miles upstream from the Topeka monitoring site, which is 65 river miles upstream from the DeSoto monitoring site, which is 18 river miles upstream from where the Kansas River flows into the Missouri River. Land use in the Kansas River Basin is dominated by grassland and cropland, and streamflow is affected substantially by reservoirs. Water quality at the three monitoring sites varied with hydrologic conditions, season, and proximity to constituent sources. Nutrient and sediment concentrations and bacteria densities were substantially larger during periods of increased streamflow, indicating important contributions from nonpoint sources in the drainage basin. During the study period, pH remained well above the KDHE lower criterion of 6.5 standard units at all sites in all years, but exceeded the upper criterion of 8.5 standard units annually between 2 percent of the time (Wamego in 2001) and 65 percent of the time (DeSoto in 2003). The dissolved oxygen concentration was less than the minimum aquatic-life-support criterion of 5.0 milligrams per liter less than 1 percent of the time at all sites. Dissolved solids, a measure of the dissolved material in water, exceeded 500 milligrams per liter about one-half of the time at the three Kansas River sites. Larger dissolved-solids concentrations upstream likely were a result of water inflow from the highly mineralized Smoky Hill River that is diluted by tributary flow as it moves downstream. Concentrations of total nitrogen and total phosphorus at the three monitoring sites exceeded the ecoregion water-quality criteria suggested by the U.S. Environmental Protection Agency during the entire study period. Median nitrogen and phosphorus concentrations were similar at all three sites, and nutrient load increased moving from the upstream to downstream sites. Total nitrogen and total phosphorus yields were nearly the same from site to site indicating that nutrient sources were evenly distributed throughout the lower Kansas River Basin. About 11 percent of the total nitrogen load and 12 percent of the total phosphorus load at DeSoto during 2000-03 originated from wastewater-treatment facilities. Escherichia coli bacteria densities were largest at the middle site, Topeka. On average, 83 percent of the annual bacteria load at DeSoto during 2000-03 occurred during 10 percent of the time, primarily in conjunction with runoff. The average annual sediment loads at the middle and downstream monitoring sites (Topeka and DeSoto) were nearly double those at the upstream site (Wamego). The average annual sediment yield was largest at Topeka. On average, 64 percent of the annual suspended-sediment load at DeSoto during 2000-03 occurred during 10 percent of the time. Trapping of sediment by reservoirs located on contributing tributaries decreases transport of sediment and sediment-related constituents. The average annual suspended-sediment load in the Kansas River at DeSoto during 2000-03 was estimated at 1.66 million tons. An estimated 13 percent of this load consisted of sand-size particles, so approximately 216,000 tons of sand were transported

Quantifying suspended sediment loads delivered to Cheney Reservoir, Kansas: Temporal patterns and management implications

USGS Publications Warehouse

Stone, Mandy L.; Juracek, Kyle E.; Graham, Jennifer L.; Foster, Guy

2015-01-01

Cheney Reservoir, constructed during 1962 to 1965, is the primary water supply for the city of Wichita, the largest city in Kansas. Sediment is an important concern for the reservoir as it degrades water quality and progressively decreases water storage capacity. Long-term data collection provided a unique opportunity to estimate the annual suspended sediment loads for the entire history of the reservoir. To quantify and characterize sediment loading to Cheney Reservoir, discrete suspended sediment samples and continuously measured streamflow data were collected from the North Fork Ninnescah River, the primary inflow to Cheney Reservoir, over a 48-year period. Continuous turbidity data also were collected over a 15-year period. These data were used together to develop simple linear regression models to compute continuous suspended sediment concentrations and loads from 1966 to 2013. The inclusion of turbidity as an additional explanatory variable with streamflow improved regression model diagnostics and increased the amount of variability in suspended sediment concentration explained by 14%. Using suspended sediment concentration from the streamflow-only model, the average annual suspended sediment load was 102,517 t (113,006 tn) and ranged from 4,826 t (5,320 tn) in 1966 to 967,569 t (1,066,562 tn) in 1979. The sediment load in 1979 accounted for about 20% of the total load over the 48-year history of the reservoir and 92% of the 1979 sediment load occurred in one 24-hour period during a 1% annual exceedance probability flow event (104-year flood). Nearly 60% of the reservoir sediment load during the 48-year study period occurred in 5 years with extreme flow events (9% to 1% annual exceedance probability, or 11- to 104-year flood events). A substantial portion (41%) of sediment was transported to the reservoir during five storm events spanning only eight 24-hour periods during 1966 to 2013. Annual suspended sediment load estimates based on streamflow were, on average, within ±20% of estimates based on streamflow and turbidity combined. Results demonstrate that large suspended sediment loads are delivered to Cheney Reservoir in very short time periods, indicating that sediment management plans eventually must address large, infrequent inflow events to be effective.

Water-quality monitoring for a pilot piling removal field evaluation, Coal Creek Slough, Washington, 2008-09

USGS Publications Warehouse

Nilsen, Elena B.; Alvarez, David A.

2011-01-01

Significant Findings Water and sediment quality monitoring was conducted before and after the removal of a piling field located in Coal Creek Slough near Longview, Washington. Passive chemical samplers and continuous water-quality monitoring instruments were deployed at the piling removal site, Coal Creek Slough Site 1 (CCS1), and at a comparison site, Coal Creek Slough Site 2 (CCS2), before (2008) and after (2009) piling removal. Surface and subsurface (core) sediment samples were collected before and after piling removal and were analyzed for grain size, organic carbon content, and chemicals of concern. Significant findings from this study include: * Phenanthrene was the only compound detected in wood piling samples analyzed for a large suite of semivolatile organic compounds and polycyclic aromatic hydrocarbons (PAHs). Metals potentially associated with wood treatment were detected in the wood piling samples at low concentrations. * Organic carbon was slightly lower in core samples from CCS1 in pre-removal (2008) and post-removal (2009) samples than in surface samples from both sites in both years. * Grain-size class distributions were relatively uniform between sites and years. * Thirty-four out of 110 chemicals of concern were detected in sediments. Eight of those detected were anthropogenic waste indicator (AWI) compounds, 18 were PAHs, 4 were sterols, and 4 were metals potentially associated with wood treatment. * Nearly all reported concentrations of chemicals of concern in sediments are qualified as estimates, primarily due to interferences in extracts resulting from complex sample matrices. Indole, perylene, and fluoranthene are reported without qualification for some of the samples, and the metals are reported without qualification for all samples. * The highest frequency of detection of chemicals of concern was seen in the pre-removal surface samples at both sites. * AWI compounds were detected less frequently and at lower concentrations during the post-removal sampling compared to the pre-removal sampling. * Several PAHs were detected at relatively high concentrations in core samples, likely indicating historical sources. * Most commonly detected PAHs in sediments were 2,6-dimethylnaphthalene, fluoranthene, perylene, and pyrene. * Most commonly detected AWIs in sediments were 3-methyl-1h-indole (skatol), acetophenone, indole, phenol, and paracresol. * Sedimentary concentrations of perylene exceeded available sediment quality guidelines. Perylene is widespread in the environment and has large potential natural sources in addition to its anthropogenic sources. * Concentrations of metals did not exceed sediment quality guidelines. * Multiple organochlorine pesticides, both banned and currently used, were detected at each site using passive samplers. * Commonly detected pesticides included hexachlorobenzene, pentachloroanisole (a degradation product of pentachlorophenol), diazinon, cis-chlordane, endosulfan, DDD, and endosulfan sulfate. * PBDE concentrations detected in passive sampler extracts were less than the method detection limit at all sites with the exception of PBDE-99, detected at a concentration less than the reporting limit. * The fragrance galaxolide was detected at a concentration greater than the method detection limit. * Common PAHs, such as phenanthrene, fluoranthene, and pyrene, were detected in every passive sampler. * Dissolved oxygen concentration was slightly higher at site CCS1 compared to site CCS2 in both years. * Overall, there was no systematic increase in chemicals of concern at the restoration site during post-removal monitoring compared to conditions during pre-removal monitoring. Any immediate, short-duration effects of piling removal on water quality could not be determined because monitoring was not conducted during the removal.

Sedimentation and Occurrence and Trends of Selected Chemical Constituents in Bottom Sediment, Empire Lake, Cherokee County, Kansas, 1905-2005

USGS Publications Warehouse

Juracek, Kyle E.

2006-01-01

For about 100 years (1850-1950), the Tri-State Mining District in parts of southeast Kansas, southwest Missouri, and northeast Oklahoma was one of the primary sources of lead and zinc ore in the world. The mining activity in the Tri-State District has resulted in substantial historical and ongoing input of cadmium, lead, and zinc to the environment including Empire Lake in Cherokee County, southeast Kansas. The environmental contamination caused by the decades of mining activity resulted in southeast Cherokee County being listed on the U.S. Environmental Protection Agency's National Priority List as a superfund hazardous waste site in 1983. To provide some of the information needed to support efforts to restore the ecological health of Empire Lake, a 2-year study was begun by the U.S. Geological Survey in cooperation with the U.S. Fish and Wildlife Service and the Kansas Department of Health and Environment. A combination of sediment-thickness mapping and bottom-sediment coring was used to investigate sediment deposition and the occurrence of cadmium, lead, zinc, and other selected constituents in the bottom sediment of Empire Lake. The total estimated volume and mass of bottom sediment in Empire Lake were 44 million cubic feet and 2,400 million pounds, respectively. Most of the bottom sediment was located in the main body and the Shoal Creek arm of the reservoir. Minimal sedimentation was evident in the Spring River arm of the reservoir. The total mass of cadmium, lead, and zinc in the bottom sediment of Empire Lake was estimated to be 78,000 pounds, 650,000 pounds, and 12 million pounds, respectively. In the bottom sediment of Empire Lake, cadmium concentrations ranged from 7.3 to 76 mg/kg (milligrams per kilogram) with an overall median concentration of 29 mg/kg. Compared to an estimated background concentration of 0.4 mg/kg, the historical mining activity increased the median cadmium concentration by about 7,200 percent. Lead concentrations ranged from 100 to 950 mg/kg with an overall median concentration of 270 mg/kg. Compared to an estimated background concentration of 33 mg/kg, the median lead concentration was increased by about 720 percent as a result of mining activities. The range in zinc concentrations was 1,300 to 13,000 mg/kg with an overall median concentration of 4,900 mg/kg. Compared to an estimated background concentration of 92 mg/kg, the median zinc concentration was increased by about 5,200 percent. Within Empire Lake, the largest sediment concentrations of cadmium, lead, and zinc were measured in the main body of the reservoir. Within the Spring River arm of the reservoir, increased concentrations in the downstream direction likely were the result of tributary inflow from Short Creek, which drains an area that has been substantially affected by historical lead and zinc mining. Compared to nonenforceable sediment-quality guidelines, all Empire Lake sediment samples (representing 21 coring sites) had cadmium concentrations that exceeded the probable-effects guideline (4.98 mg/kg), which represents the concentration above which toxic biological effects usually or frequently occur. With one exception, cadmium concentrations exceeded the probable-effects guideline by about 180 to about 1,400 percent. With one exception, all sediment samples had lead concentrations that exceeded the probable-effects guideline (128 mg/kg) by about 10 to about 640 percent. All sediment samples had zinc concentrations that exceeded the probable-effects guideline (459 mg/kg) by about 180 to about 2,700 percent. Overall, cadmium, lead, and zinc concentrations in the bottom sediment of Empire Lake have decreased over time following the end of lead and zinc mining in the area. However, the concentrations in the most recently deposited bottom sediment (determined for 4 of 21 coring sites) still exceeded the probable-effects guideline by about 440 to 640 percent for cadmium, about 40 to 80 percent for lead, and about 580

Ground-Water Quality of the Northern High Plains Aquifer, 1997, 2002-04

USGS Publications Warehouse

Stanton, Jennifer S.; Qi, Sharon L.

2007-01-01

An assessment of ground-water quality in the northern High Plains aquifer was completed during 1997 and 2002-04. Ground-water samples were collected at 192 low-capacity, primarily domestic wells in four major hydrogeologic units of the northern High Plains aquifer-Ogallala Formation, Eastern Nebraska, Sand Hills, and Platte River Valley. Each well was sampled once, and water samples were analyzed for physical properties and concentrations of nitrogen and phosphorus compounds, pesticides and pesticide degradates, dissolved solids, major ions, trace elements, dissolved organic carbon (DOC), radon, and volatile organic compounds (VOCs). Tritium and microbiology were analyzed at selected sites. The results of this assessment were used to determine the current water-quality conditions in this subregion of the High Plains aquifer and to relate ground-water quality to natural and human factors affecting water quality. Water-quality analyses indicated that water samples rarely exceeded established U.S. Environmental Protection Agency public drinking-water standards for those constituents sampled; 13 of the constituents measured or analyzed exceeded their respective standards in at least one sample. The constituents that most often failed to meet drinking-water standards were dissolved solids (13 percent of samples exceeded the U.S. Environmental Protection Agency Secondary Drinking-Water Regulation) and arsenic (8 percent of samples exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level). Nitrate, uranium, iron, and manganese concentrations were larger than drinking-water standards in 6 percent of the samples. Ground-water chemistry varied among hydrogeologic units. Wells sampled in the Platte River Valley and Eastern Nebraska units exceeded water-quality standards more often than the Ogallala Formation and Sand Hills units. Thirty-one percent of the samples collected in the Platte River Valley unit had nitrate concentrations greater than the standard, 22 percent exceeded the manganese standard, 19 percent exceeded the sulfate standard, 26 percent exceeded the uranium standard, and 38 percent exceeded the dissolved-solids standard. In addition, 78 percent of samples had at least one detectable pesticide and 22 percent of samples had at least one detectable VOC. In the Eastern Nebraska unit, 30 percent of the samples collected had dissolved-solids concentrations larger than the standard, 23 percent exceeded the iron standard, 13 percent exceeded the manganese standard, 10 percent exceeded the arsenic standard, 7 percent exceeded the sulfate standard, 7 percent exceeded the uranium standard, and 7 percent exceeded the selenium standard. No samples exceeded the nitrate standard. Thirty percent of samples had at least one detectable pesticide compound and 10 percent of samples had at least one detectable VOC. In contrast, the Sand Hills and Ogallala Formation units had fewer detections of anthropogenic compounds and drinking-water exceedances. In the Sand Hills unit, 15 percent of the samples exceeded the arsenic standard, 4 percent exceeded the nitrate standard, 4 percent exceeded the uranium standard, 4 percent exceeded the iron standard, and 4 percent exceeded the dissolved-solids standard. Fifteen percent of samples had at least one pesticide compound detected and 4 percent had at least one VOC detected. In the Ogallala Formation unit, 6 percent of water samples exceeded the arsenic standard, 4 percent exceeded the dissolved-solids standard, 3 percent exceeded the nitrate standard, 2 percent exceeded the manganese standard, 1 percent exceeded the iron standard, 1 percent exceeded the sulfate standard, and 1 percent exceeded the uranium standard. Eight percent of samples collected in the Ogallala Formation unit had at least one pesticide detected and 6 percent had at least one VOC detected. Differences in ground-water chemistry among the hydrogeologic units were attributed to variable depth to water, depth of the well screen below the water table, reduction-oxidation conditions, ground-water residence time, interactions with surface water, composition of aquifer sediments, extent of cropland, extent of irrigated land, and fertilizer application rates.

Water-quality and biological conditions in selected tributaries of the Lower Boise River, southwestern Idaho, water years 2009-12

USGS Publications Warehouse

Etheridge, Alexandra B.; MacCoy, Dorene E.; Weakland, Rhonda J.

2014-01-01

Water-quality conditions were studied in selected tributaries of the lower Boise River during water years 2009–12, including Fivemile and Tenmile Creeks in 2009, Indian Creek in 2010, and Mason Creek in 2011 and 2012. Biological samples, including periphyton biomass and chlorophyll-a, benthic macroinvertebrates, and fish were collected in Mason Creek in October 2011. Synoptic water-quality sampling events were timed to coincide with the beginning and middle of the irrigation season as well as the non-irrigation season, and showed that land uses and irrigation practices affect water quality in the selected tributaries. Large increases in nutrient and sediment concentrations and loads occurred over relatively short stream reaches and affected nutrient and sediment concentrations downstream of those reaches. Escherichia coli (E. coli) values increased in study reaches adjacent to pastured lands or wastewater treatment plants, but increased E. coli values at upstream locations did not necessarily affect E. coli values at downstream locations. A spatial loading analysis identified source areas for nutrients, sediment, and E. coli, and might be useful in selecting locations for water-quality improvement projects. Effluent from wastewater treatment plants increased nutrient loads in specific reaches in Fivemile and Indian Creeks. Increased suspended-sediment loads were associated with increased discharge from irrigation returns in each of the studied tributaries. Samples collected during or shortly after storms showed that surface runoff, particularly during the winter, may be an important source of nutrients in tributary watersheds with substantial agricultural land use. Concentrations of total phosphorus, suspended sediment, and E. coli exceeded regulatory water-quality targets or trigger levels at one or more monitoring sites in each tributary studied, and exceedences occurred during irrigation season more often than during non-irrigation season. As with water-quality sampling results, bottom-sediment samples analyzed for contaminants of emerging concern indicated that adjacent land uses can affect in-stream conditions. Contaminants of emerging concern were detected in four categories: urban compounds, industrial compounds, fecal steroids, and personal care products. Compounds in one or more of the four contaminant categories were detected at higher concentrations in upstream sites than in downstream sites in the tributaries and in the lower Boise River. High concentrations of compounds in upstream locations indicated that adjacent land use might be an important factor in contributing contaminants of emerging concern to the lower Boise River watershed. Expanded monitoring at Mason Creek near the mouth included a streamgage, a continuous water-quality monitor, and monthly water-quality sample collection. Data collected during expanded monitoring efforts at Mason Creek near the mouth provided information to develop and compare water-quality models. Regression models were developed using turbidity, discharge, and seasonality as surrogates to estimate concentrations of water-quality constituents. Daily streamflow also was used in a load model to estimate daily loads of water-quality constituents. Surrogate regression models may be useful for long-term monitoring and generally performed better than other models to estimate concentrations and loads of total phosphorus, total nitrogen, and suspended sediment in Mason Creek. Biological sampling results from Mason Creek showed low periphyton biomass and chlorophyll-a concentrations compared to those historically measured in the Boise River near Parma, Idaho, during October and November. The most abundant invertebrate found in Mason Creek was the highly tolerant and invasive New Zealand mudsnail (Potamopyrgus antipodarum). The presence of small rainbow trout (90 millimeters) may indicate salmonid spawning in Mason Creek. The rangeland-fish-index score of 58 for Mason Creek is comparable to rangeland-fish-index scores calculated for the Boise River near Middleton, indicating intermediate biotic condition.

Use of sedimentary metals to predict metal concentrations in black mussel (Mytilus galloprovincialis) tissue and risk to human health (Sydney estuary, Australia).

PubMed

Birch, G F; Apostolatos, C

2013-08-01

Filter-feeding bivalves have been used extensively as an indicator of ecosystem condition and in management of estuarine environments. The current study aimed to determine whether sedimentary metals could predict metal concentrations in tissue of filter-feeding mussels (Mytilus galloprovincialis) and to identify areas of the estuary where mussel consumption posed a human health risk. Mussel tissue Cu and Zn concentrations (wet weight) were below guideline values for human consumption in all parts of the waterway, whereas Pb tissue concentrations exceed these guidelines (2.0 μg g(-1) wet weight) in the upper reaches of some embayments of the estuary. Concentrations of Cu and Pb in the fine fraction (<62.5 μm) of bottom sediment reasonably predicted concentrations (dry weight) of these metals in mussel tissue (r (2) =0.460 and p=0.001 and r (2) =0.669 and p<0.0001, respectively) as these materials are resuspendable and available to filter-feeding estuarine animals, whereas total sediment and mussel tissue were poorly related. Lead concentrations (>350 μg g(-1)) in fine sediments indicated areas of this estuary where human health was at risk due to high tissue concentrations of this metal. These results give encouragement for the use of the metal concentration in fine sediments as an indicator of estuarine condition and risk to human health in this waterway. Mussels were distributed in all parts of the estuary, even in areas where metal concentrations exceeded sediment quality guidelines.

Sediment quality assessment studies of Tampa bay, Florida

USGS Publications Warehouse

Carr, Scott R.; Chapman, Duane C.; Long, Edward R.; Windom, Herbert L.; Thursby, Glen; Sloane, Gail M.; Wolfe, Douglas A.

1996-01-01

A survey of the toxicity of sediments throughout the Tampa Bay estuary was performed as part of the National Oceanic and Atmospheric Administration's National Status and Trends Program. The objectives of the survey were to determine the spatial extent and severity of toxicity and to identify relationships between chemical contamination and toxicity. Three independent toxicity tests were performed: a 10-d amphipod survival test of the whole sediments with Ampelisca abdita, a sea urchin fertilization test of sediment pore water with Arbacia punctulata, and a 5-min Microtox® bioluminescence test with solvent extracts of the sediments. Seventy-three percent of the 165 undiluted sediment pore-water samples were significantly toxic relative to reference samples with the sea urchin fertilization test. In contrast, only 2% of the 165 samples were significantly toxic in the amphipod tests. The causes of toxicity were not determined. However, concentrations of numerous trace metals, pesticides, polychlorinated biphenyl (PCB) congeners, polycyclic aromatic hydrocarbons (PAHs), and ammonia were highly correlated with pore-water toxicity. Concentrations of many substances, especially total dichlorodiphenyltrichloroethanes (DDTs), endrin, total PCBs, certain PAHs, lead, and zinc, occurred at concentrations in the toxic samples that equaled or exceeded concentrations that have been previously associated with sediment toxicity.

Three decades of TBT contamination in sediments around a large scale shipyard.

PubMed

Kim, Nam Sook; Shim, Won Joon; Yim, Un Hyuk; Ha, Sung Yong; An, Joon Geon; Shin, Kyung Hoon

2011-08-30

Tributyltin (TBT) contamination in sediments was investigated in the vicinity of a large-scale shipyard in the years after the implementation of a total ban on the use of TBT based antifouling paints in Korea. Extremely high level of TBT (36,292ng Sn/g) in surface sediment was found at a station in front of a drydock and near surface runoff outfall of the shipyard. TBT concentration in surface sediments of Gohyeon Bay, where the shipyard is located, showed an apparent decreased TBT concentration gradient from the shipyard towards the outer bay. The vertical distribution of TBT contamination derived from a sediment core analysis demonstrated a significant positive correlation (r(2)=0.88; p<0.001) with the annual tonnage of ship-construction in the shipyard within the past three decades. TBT concentrations at six stations surveyed before (2003) and seven years after (2010) the total ban showed no significant differences (p>0.05). Despite the ban on the use of TBT, including ocean going vessels, surface sediments are still being heavily contaminated with TBT, and its levels well exceeded the sediment quality guideline or screening values. Copyright © 2011 Elsevier B.V. All rights reserved.

Effects-based spatial assessment of contaminated estuarine sediments from Bear Creek, Baltimore Harbor, MD, USA.

PubMed

Hartzell, Sharon E; Unger, Michael A; McGee, Beth L; Wilson, Sacoby M; Yonkos, Lance T

2017-10-01

Estuarine sediments in regions with prolonged histories of industrial activity are often laden to significant depths with complex contaminant mixtures, including trace metals and persistent organic pollutants. Given the complexity of assessing risks from multi-contaminant exposures, the direct measurement of impacts to biological receptors is central to characterizing contaminated sediment sites. Though biological consequences are less commonly assessed at depth, laboratory-based toxicity testing of subsurface sediments can be used to delineate the scope of contamination at impacted sites. The extent and depth of sediment toxicity in Bear Creek, near Baltimore, Maryland, USA, was delineated using 10-day acute toxicity tests with the estuarine amphipod Leptocheirus plumulosus, and chemical analysis of trace metals and persistent organic pollutants. A gradient of toxicity was demonstrated in surface sediments with 21 of 22 tested sites differing significantly from controls. Effects were most pronounced (100% lethality) at sites proximate to a historic industrial complex. Sediments from eight of nine core samples to depths of 80 cm were particularly impacted (i.e., caused significant lethality to L. plumulosus) even in locations overlain with relatively non-toxic surface sediments, supporting a conclusion that toxicity observed at the surface (top 2 cm) does not adequately predict toxicity at depth. In seven of nine sites, toxicity of surface sediments differed from toxicity at levels beneath by 28 to 69%, in five instances underestimating toxicity (28 to 69%), and in two instances overestimating toxicity (44 to 56%). Multiple contaminants exceeded sediment quality guidelines and correlated positively with toxic responses within surface sediments (e.g., chromium, nickel, polycyclic aromatic hydrocarbon (PAH), total petroleum hydrocarbon). Use of an antibody-based PAH biosensor revealed that porewater PAH concentrations also increased with depth at most sites. This study informs future management decisions concerning the extent of impact to Bear Creek sediments, and demonstrates the benefits of a spatial approach, relying primarily on toxicity testing to assess sediment quality in a system with complex contaminant mixtures.

An investigation of shallow ground-water quality near East Fork Poplar Creek, Oak Ridge, Tennessee

USGS Publications Warehouse

Carmichael, J.K.

1989-01-01

Alluvial soils of the flood plain of East Fork Poplar Creek in Oak Ridge, Tennessee, are contaminated with mercury and other metals, organic compounds, and radio-nuclides originating from the Y-12 Plant, a nuclear-processing facility located within the U.S. Department of Energy 's Oak Ridge Reservation. Observation wells were installed in the shallow aquifer of the flood plain, and water quality samples were collected to determine if contaminants are present in the shallow groundwater. Groundwater in the shallow aquifer occurs under water-table conditions. Recharge is primarily from precipitation and discharge is to East Fork Poplar Creek. Groundwater levels fluctuate seasonally in response to variations in recharge and evapotranspiration. During extremely dry periods, the water table drops below the base of the shallow aquifer in some flood-plain areas. Contaminants found in water samples from several of the wells in concentrations which equaled or exceeded drinking-water standards established by the U.S. Environmental Protection Agency are antimony, chromium, lead, mercury, selenium, phenols, and strontium-90. Total and dissolved uranium concentrations exceeded the analytical detection limit in nearly 70% of the wells in the flood plain. The results of water quality determinations demonstrate that elevated concentrations of most trace metals (and possibly organic compounds and radionuclides) were caused by contaminated sediments in the samples. The presence of contaminated sediment in samples is suspected to be the result of borehole contamination during well installation. (USGS)

Analysis of water-quality trends at two discharge stations; one within Big Cypress National Preserve and one near Biscayne Bay; southern Florida, 1966-94

USGS Publications Warehouse

Lietz, A.C.

2000-01-01

An analysis of water-quality trends was made at two U.S. Geological Survey daily discharge stations in southern Florida. The ESTREND computer program was the principal tool used for the determination of water-quality trends at the Miami Canal station west of Biscayne Bay in Miami and the Tamiami Canal station along U.S. Highway 41 in the Big Cypress National Preserve in Collier County. Variability in water quality caused by both seasonality and streamflow was compensated for by applying the nonparametric Seasonal Kendall trend test to unadjusted concentrations or flow-adjusted concentrations (residuals) determined from linear regression analysis. Concentrations of selected major inorganic constituents and physical characteristics; pH and dissolved oxygen; suspended sediment; nitrogen, phosphorus, and carbon species; trace metals; and bacteriological and biological characteristics were determined at the Miami and Tamiami Canal stations. Median and maximum concentrations of selected constituents were compared to the Florida Class III freshwater standards for recreation, propagation, and maintenance of a healthy, well-balanced population of fish and wildlife. The median concentrations of the water-quality constituents and characteristics generally were higher at the Miami Canal station than at the Tamiami Canal station. The maximum value for specific conductance at the Miami Canal station exceeded the State standard. The median and maximum concentrations for ammonia at the Miami and Tamiami Canal stations exceeded the State standard, whereas median dissolved-oxygen concentrations at both stations were below the State standard. Trend results were indicative of either improvement or deterioration in water quality with time. Improvement in water quality at the Miami Canal station was reflected by downward trends in suspended sediment (1987-94), turbidity, (1970-78), total ammonia (1971-94), total phosphorus (1987-94), barium (1978-94), iron (1969-94), and fecal coliform (1976-94). Deterioration in water quality at the same station was indicated by upward trends in specific conductance (1966-94), dissolved solids (1966-94, 1976-94, and 1987-94), chloride (1966-94), potassium (1966-94), magnesium (1966-94), sodium (1966-94), sulfate (1966-94), silica (1966-94), suspended sediment (1974-94), total organic carbon (1970-81), and fecal streptococcus (1987-94). The downward trend in pH (1966-94) was indicative of deterioration in water quality at the Miami Canal station. Improvement in water quality at the Tamiami Canal station was reflected by downward trends in fluoride (1967-93), total ammonia (1970-92), total nitrite plus nitrate (1975-85), and barium (1978-93). Deterioration in water quality at the same station was statistically significant by upward trends in specific conductance (1967-93), dissolved solids (1967-93), chloride (1967-93), sodium (1967-93), potassium (1967-93), magnesium (1967-93), strontium (1967-93), and suspended sediment (1976-93). The downward trend in dissolved oxygen (1970-93) was indicative of deterioration in water quality.

Water quality of the French Broad River, North Carolina : An analysis of data collected at Marshall, 1958-77

USGS Publications Warehouse

Daniel, C. C.; Wilder, H.B.; Weiner, M.S.

1979-01-01

An investigation of water quality in the industrialized French Broad River basin of western North Carolina has identified water-quality variations, the extent of man's influence on water quality, and trends in changes in the chemical quality of the river. The study centered on data collected during 1958-77 at the U.S. Geological Survey's station at Marshall, N.C. The French Broad is a clean river. Only occasionally have concentrations of some trace metals been observed to exceed drinking water standards. However, 58 percent of samples analyzed for fecal coliform bacteria during 1974-77 exceeded criteria levels for bathing waters. Most water-quality variations are associated with variations in streamflow. Concentrations of constituents transported in solution generally decrease at higher flows, whereas concentrations of materials associated with suspended sediment increase with flow. No correlation between discharge and nutrient concentrations has been observed. Man's activities in the basin have resulted in deterioration of water quality. In 1958, an estimated 64 percent of the inorganic dissolved-solids load in the river at Marshall was due to man-made pollution, and by 1966, it was 74 percent. As of 1977, water quality had returned to levels of 1958, apparently the result of new waste-water treatment facilities and improved industrial technology.

Water quality of streams draining abandoned and reclaimed mined lands in the Kantishna Hills area, Denali National Park and Preserve, Alaska, 2008–11

USGS Publications Warehouse

Brabets, Timothy P.; Ourso, Robert T.

2013-01-01

The Kantishna Hills are an area of low elevation mountains in the northwest part of Denali National Park and Preserve, Alaska. Streams draining the Kantishna Hills are clearwater streams that support several species of fish and are derived from rain, snowmelt, and subsurface aquifers. However, the water quality of many of these streams has been degraded by mining. Past mining practices generated acid mine drainage and excessive sediment loads that affected water quality and aquatic habitat. Because recovery through natural processes is limited owing to a short growing season, several reclamation projects have been implemented on several streams in the Kantishna Hills region. To assess the current water quality of streams in the Kantishna Hills area and to determine if reclamation efforts have improved water quality, a cooperative study between the U.S. Geological Survey and the National Park Service was undertaken during 2008-11. High levels of turbidity, an indicator of high concentrations of suspended sediment, were documented in water-quality data collected in the mid-1980s when mining was active. Mining ceased in 1985 and water-quality data collected during this study indicate that levels of turbidity have declined significantly. Turbidity levels generally were less than 2 Formazin Nephelometric Units and suspended sediment concentrations generally were less than 1 milligram per liter during the current study. Daily turbidity data at Rock Creek, an unmined stream, and at Caribou Creek, a mined stream, documented nearly identical patterns of turbidity in 2009, indicating that reclamation as well as natural revegetation in mined streams has improved water quality. Specific conductance and concentrations of dissolved solids and major ions were highest from streams that had been mined. Most of these streams flow into Moose Creek, which functions as an integrator stream, and dilutes the specific conductance and ion concentrations. Calcium and magnesium are the dominant cations, and bicarbonate and sulfate are the dominant anions. Water samples indicate that the water from Rock Creek, Moose Creek, Slate Creek, and Eldorado Creek is a calcium bicarbonate-type water. The remaining sites are a calcium sulfate type water. U.S. Environmental Protection Agency guidelines for arsenic and antimony in drinking water were exceeded in water at Slate Creek and Eureka Creek. Concentrations of arsenic, cadmium, chromium, copper, lead, nickel, and zinc in streambed sediments at many sites exceed sediment quality guideline thresholds that could be toxic to aquatic life. However, assessment of these concentrations, along with the level of organic carbon detected in the sediment, indicate that only concentrations of arsenic and chromium may be toxic to aquatic life at many sites. In 2008 and 2009, 104 macroinvertebrate taxa and 164 algae taxa were identified from samples collected from seven sites. Of the macroinvertebrates, 86 percent were insects and most of the algae consisted of diatoms. Based on the National Community Index, Rock Creek, a reference site, and Caribou Creek, and a mined stream that had undergone some reclamation, exhibited the best overall stream conditions; whereas Slate Creek and Friday Creek, two small streams that were mined extensively, exhibited the worst stream conditions. A non-metric multi-dimensional scaling analysis of the macroinvertebrate and algae data showed a distinct grouping between the 2008 and 2009 samples, likely because of differences between a wet, cool summer in 2008 and a dry, warm summer in 2009.

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Columbia Basin Project, Washington, 1991-92

USGS Publications Warehouse

Embrey, S.S.; Block, E.K.

1995-01-01

The reconnaissance investigation results indicated that irrigation drainage generally has not adversely affected biota in the Columbia Basin Project. Hazards to biota from large concentrations of certain trace elements in water and bottom sediment, and caused by high evaporation rates in irrigated arid lands, are reduced by imported, dilute Columbia River water. However, boron concentrations in aquatic plants might affect waterfowl feeding on these plants and arsenic concentrations in juvenile coots were similar to those in mallard ducklings who exhibited abnormalities after being fed an arsenic-supplemented diet. During irrigation season, concentrations of boron, nitrate, and dissolved solids in water were increased in the southern wasteways because of water reuse. During non-irrigation season, constituent concentrations were large when stream flows are sustained by return water from tile drains and ground water. However, concentrations of dissolved constituents typically did not exceed standards or criteria for humans, freshwater life, or beneficial uses of the water. In water, the herbicide 2,4-D was detected more than any other pesticide and in concentrations from 0.01 to 1.0 microgram per liter. In bottom sediment, organochlorine insecticides were detected in samples from 19 of 21 sites. In fish collected from some wasteways, chlordane, DDT, and dieldrin concentrations occasionally exceeded freshwater protection criteria.

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in and near Stillwater Wildlife Management Area, Churchill County, Nevada, 1986-87

USGS Publications Warehouse

Hoffman, R.J.; Hallock, R.J.; Rowe, T.G.; Lico, M.S.; Burge, H.L.; Thompson, S.P.

1990-01-01

A reconnaissance was initiated in 1986 to determine whether the quality of irrigation-drainage water in and near the Stillwater Wildlife Management Area, Nevada, has caused or has potential to cause harmful effects on human health, fish, wildlife, or other beneficial uses of water. Samples of surface and groundwater, bottom sediment, and biota were collected from sites upstream and downstream from the Fallon agricultural area in the Carson Desert, and analyzed for potentially toxic trace elements. Other analysis included radioactive substances, major dissolved constituents, and nutrients in water, and pesticide residues in bottom sediment and biota. In areas affected by irrigation drainage, the following constituents were found to commonly exceed baseline concentrations or recommended criteria for protection of aquatic life or propagation of wildlife: In water, arsenic, boron, dissolved solids, molybdenum, sodium, and un-ionized ammonia; in bottom sediments, arsenic, lithium, mercury, molybdenum, and selenium; and in biota, arsenic, boron, chromium, copper, mercury, selenium, and zinc. In some wetlands, selenium and mercury appeared to be biomagnified, and arsenic bioaccumulated. Pesticides contamination in bottom sediments and biota was insignificant. Adverse biological effects observed during this reconnaissance included gradual vegetative changes and species loss, fish die-offs, waterfowl disease epidemics, and persistent and unexplained deaths of migratory birds. (USGS)

Sedimentation and occurrence and trends of selected chemical constituents in bottom sediment of 10 small reservoirs, Eastern Kansas

USGS Publications Warehouse

Juracek, Kyle E.

2004-01-01

Many municipalities in Kansas rely on small reservoirs as a source of drinking water and for recreational activities. Because of their significance to the community, management of the reservoirs and the associated basins is important to protect the reservoirs from degradation. Effective reservoir management requires information about water quality, sedimentation, and sediment quality. A combination of bathymetric surveying and bottom-sediment coring during 2002 and 2003 was used to investigate sediment deposition and the occurrence of selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 26 trace elements, 15 organochlorine compounds, and 1 radionuclide in the bottom sediment of 10 small reservoirs in eastern Kansas. Original reservoir water-storage capacities ranged from 23 to 5,845 acre-feet. The mostly agricultural reservoir basins range in area from 0.6 to 14 square miles. The mean annual net volume of deposited sediment, estimated separately for several of the reservoirs, ranged from about 43,600 to about 531,000 cubic feet. The estimated mean annual net mass of deposited sediment ranged from about 1,360,000 to about 23,300,000 pounds. The estimated mean annual net sediment yields from the reservoir basins ranged from about 964,000 to about 2,710,000 pounds per square mile. Compared to sediment yield estimates provided by a statewide study published in 1965, the estimates determined in this study differed substantially and were typically smaller. A statistically significant positive correlation was determined for the relation between sediment yield and mean annual precipitation. Nutrient concentrations in the bottom sediment varied substantially among the 10 reservoirs. Median total nitrogen concentrations ranged from 1,400 to 3,700 milligrams per kilogram. Median total phosphorus concentrations ranged from 550 to 1,300 milligrams per kilogram. A statistically significant positive trend (that is, nutrient concentration increased toward the top of the sediment core) was indicated in one reservoir for total nitrogen and in two reservoirs for total phosphorus. Also, a possible positive trend for total nitrogen was indicated in two other reservoirs. These trends in nutrient concentrations may be related to a statewide increase in fertilizer use. Alternatively, the trends may be indicative of diagenesis (that is, postdepositional changes in the sediment caused by various processes including decomposition). Nutrient loads and yields also varied substantially among the five reservoirs for which loads and yields were estimated. Estimated mean annual net loads of total nitrogen deposited in the bottom sediment ranged from 4,080 to 49,100 pounds. Estimated mean annual net loads of total phosphorus deposited in the bottom sediment ranged from 1,120 to 20,800 pounds. Estimated mean annual net yields of total nitrogen from the basins ranged from 2,210 to 6,800 pounds per square mile. Estimated mean annual net yields of total phosphorus from the basins ranged from 598 to 2,420 pounds per square mile. Compared to nonenforceable sediment-quality guidelines adopted by the U.S. Environmental Protection Agency, bottom-sediment concentrations of arsenic, chromium, copper, and nickel in samples from all 10 reservoirs typically exceeded the threshold-effects levels (TELs) but were less than the probable-effects levels (PELs). TELs represent the concentrations above which toxic biological effects occasionally occur in aquatic organisms, whereas PELs represent the concentrations above which toxic biological effects usually or frequently occur. Concentrations of cadmium, lead, and zinc exceeded the TELs but were less than the PELs in sediment samples from about one-half of the reservoirs and were less than the TELs in samples from the remaining reservoirs. Mercury concentrations were less than the TEL (information only available for four reservoirs). Silver was not detected in the bottom sediment fro

Mining-Related Sediment and Soil Contamination in a Large Superfund Site: Characterization, Habitat Implications, and Remediation.

PubMed

Juracek, K E; Drake, K D

2016-10-01

Historical mining activity (1850-1970) in the now inactive Tri-State Mining District provided an ongoing source of lead and zinc to the environment including the US Environmental Protection Agency Superfund site located in Cherokee County, southeast Kansas, USA. The resultant contamination adversely affected biota and caused human health problems and risks. Remediation in the Superfund site requires an understanding of the magnitude and extent of contamination. To provide some of the required information, a series of sediment and soil investigations were conducted in and near the Superfund site to characterize lead and zinc contamination in the aquatic and floodplain environments along the main-stem Spring River and its major tributaries. In the Superfund site, the most pronounced lead and zinc contamination, with concentrations that far exceed sediment quality guidelines associated with potential adverse biological effects, was measured for streambed sediments and floodplain soils located within or downstream from the most intensive mining-affected areas. Tributary streambeds and floodplains in affected areas are heavily contaminated with some sites having lead and zinc concentrations that are an order of magnitude (or more) greater than the sediment quality guidelines. For the main-stem Spring River, the streambed is contaminated but the floodplain is mostly uncontaminated. Measured lead and zinc concentrations in streambed sediments, lakebed sediments, and floodplain soils documented a persistence of the post-mining contamination on a decadal timescale. These results provide a basis for the prioritization, development, and implementation of plans to remediate contamination in the affected aquatic and floodplain environments within the Superfund site.

Mining-Related Sediment and Soil Contamination in a Large Superfund Site: Characterization, Habitat Implications, and Remediation

NASA Astrophysics Data System (ADS)

Juracek, K. E.; Drake, K. D.

2016-10-01

Historical mining activity (1850-1970) in the now inactive Tri-State Mining District provided an ongoing source of lead and zinc to the environment including the US Environmental Protection Agency Superfund site located in Cherokee County, southeast Kansas, USA. The resultant contamination adversely affected biota and caused human health problems and risks. Remediation in the Superfund site requires an understanding of the magnitude and extent of contamination. To provide some of the required information, a series of sediment and soil investigations were conducted in and near the Superfund site to characterize lead and zinc contamination in the aquatic and floodplain environments along the main-stem Spring River and its major tributaries. In the Superfund site, the most pronounced lead and zinc contamination, with concentrations that far exceed sediment quality guidelines associated with potential adverse biological effects, was measured for streambed sediments and floodplain soils located within or downstream from the most intensive mining-affected areas. Tributary streambeds and floodplains in affected areas are heavily contaminated with some sites having lead and zinc concentrations that are an order of magnitude (or more) greater than the sediment quality guidelines. For the main-stem Spring River, the streambed is contaminated but the floodplain is mostly uncontaminated. Measured lead and zinc concentrations in streambed sediments, lakebed sediments, and floodplain soils documented a persistence of the post-mining contamination on a decadal timescale. These results provide a basis for the prioritization, development, and implementation of plans to remediate contamination in the affected aquatic and floodplain environments within the Superfund site.

Mining-related sediment and soil contamination in a large Superfund site: Characterization, habitat implications, and remediation

USGS Publications Warehouse

Juracek, Kyle E.; Drake, K. D.

2016-01-01

Historical mining activity (1850–1970) in the now inactive Tri-State Mining District provided an ongoing source of lead and zinc to the environment including the US Environmental Protection Agency Superfund site located in Cherokee County, southeast Kansas, USA. The resultant contamination adversely affected biota and caused human health problems and risks. Remediation in the Superfund site requires an understanding of the magnitude and extent of contamination. To provide some of the required information, a series of sediment and soil investigations were conducted in and near the Superfund site to characterize lead and zinc contamination in the aquatic and floodplain environments along the main-stem Spring River and its major tributaries. In the Superfund site, the most pronounced lead and zinc contamination, with concentrations that far exceed sediment quality guidelines associated with potential adverse biological effects, was measured for streambed sediments and floodplain soils located within or downstream from the most intensive mining-affected areas. Tributary streambeds and floodplains in affected areas are heavily contaminated with some sites having lead and zinc concentrations that are an order of magnitude (or more) greater than the sediment quality guidelines. For the main-stem Spring River, the streambed is contaminated but the floodplain is mostly uncontaminated. Measured lead and zinc concentrations in streambed sediments, lakebed sediments, and floodplain soils documented a persistence of the post-mining contamination on a decadal timescale. These results provide a basis for the prioritization, development, and implementation of plans to remediate contamination in the affected aquatic and floodplain environments within the Superfund site.

Quality of streams in Johnson County, Kansas, 2002--10

USGS Publications Warehouse

Rasmussen, Teresa J.; Stone, Mandy S.; Poulton, Barry C.; Graham, Jennifer L.

2012-01-01

Stream quality in Johnson County, northeastern Kansas, was assessed on the basis of land use, hydrology, stream-water and streambed-sediment chemistry, riparian and in-stream habitat, and periphyton and macroinvertebrate community data collected from 22 sites during 2002 through 2010. Stream conditions at the end of the study period are evaluated and compared to previous years, stream biological communities and physical and chemical conditions are characterized, streams are described relative to Kansas Department of Health and Environment impairment categories and water-quality standards, and environmental factors that most strongly correlate with biological stream quality are evaluated. The information is useful for improving water-quality management programs, documenting changing conditions with time, and evaluating compliance with water-quality standards, total maximum daily loads (TMDLs), National Pollutant Discharge Elimination System (NPDES) permit conditions, and other established guidelines and goals. Constituent concentrations in water during base flow varied across the study area and 2010 conditions were not markedly different from those measured in 2003, 2004, and 2007. Generally the highest specific conductance and concentrations of dissolved solids and major ions in water occurred at urban sites except the upstream Cedar Creek site, which is rural and has a large area of commercial and industrial land less than 1 mile upstream on both sides of the creek. The highest base-flow nutrient concentrations in water occurred downstream from wastewater treatment facilities. Water chemistry data represent base-flow conditions only, and do not show the variability in concentrations that occurs during stormwater runoff. Constituent concentrations in streambed sediment also varied across the study area and some notable changes occurred from previously collected data. High organic carbon and nutrient concentrations at the rural Big Bull Creek site in 2003 decreased to at least one-fourth of those concentrations in 2007 and 2010 likely because of the reduction in upstream wastewater discharge contributions. The highest concentrations of trace metals in 2010 occurred at urban sites on Mill and Indian Creeks. Zinc was the only metal to exceed the probable effects concentration in 2010, which occurred at a site on Indian Creek. In 2007, chromium and nickel at the upstream urban Cedar Creek site exceeded the probable effects concentrations, and in 2003, no metals exceeded the probable effects concentrations. Of 72 organic compounds analyzed in streambed sediment, 26 were detected including pesticides, polycyclic aromatic hydrocarbons (PAHs), fuel products, fragrances, preservatives, plasticizers, manufacturing byproducts, flame retardants, and disinfectants. All 6 PAH compounds analyzed were detected, and the probable effects concentrations for 4 of the 6 PAH compounds analyzed were exceeded in 2010. Only five pesticide compounds were detected in streambed sediment, including carbazole and four pyrethroid compounds. Chronic toxicity guidelines for pyrethroid compounds were exceeded at five sites. Biological conditions reflected a gradient in urban land use, with the less disturbed streams located in rural areas of Johnson County. About 19 percent of sites in 2010 (four sites) were fully supporting of aquatic life on the basis of the four metrics used by Kansas Department of Health and Environment to categorize sites. This is a notable difference compared to previous years when no sites (in 2003 and 2004) or just one site (in 2007) was fully supporting of aquatic life. Multimetric macroinvertebrate scores improved at the Big Bull Creek site where wastewater discharges were reduced in 2007. Environmental variables that consistently were highly negatively correlated with biological conditions were percent impervious surface and percent urban land use. In addition, density of stormwater outfall points adjacent to streams was significantly negatively correlated with biological conditions. Specific conductance of water and sum of PAH concentrations in streambed sediment also were significantly negatively correlated with biological conditions. Total nitrogen in water and total phosphorus in streambed sediment were correlated with most of the invertebrate variables, which is a notable difference from previous analyses using smaller datasets, in which nutrient relations were weak or not detected. The most important habitat variables were sinuosity, length and continuity of natural buffers, riffle substrate embeddedness, and substrate cover diversity, each of which was correlated with all invertebrate metrics including a 10-metric combined score. Correlation analysis indicated that if riparian and in-stream habitat conditions improve then so might invertebrate communities and stream biological quality. Sixty-two percent of the variance in macroinvertebrate community metrics was explained by the single environmental factor, percent impervious surface. Invertebrate responses to urbanization in Johnson County indicated linearity rather than identifiable thresholds. Multiple linear regression models developed for each of the four macroinvertebrate metrics used to determine aquatic-life-support status indicated that percent impervious surface, as a measure of urban land use, explained 34 to 67 percent of the variability in biological communities. Results indicate that although multiple factors are correlated with stream quality degradation, general urbanization, as indicated by impervious surface area or urban land use, consistently is determined to be the fundamental factor causing change in stream quality. Effects of urbanization on Johnson County streams are similar to effects described in national studies that assess effects of urbanization on stream health. Individually important environmental factors such as specific conductance of water, PAHs in streambed sediment, and stream buffer conditions, are affected by urbanization and, collectively, all contribute to stream impairments. Policies and management practices that may be most important in protecting the health of streams in Johnson County are those minimizing the effects of impervious surface, protecting stream corridors, and decreasing the loads of sediment, nutrients, and toxic chemicals that directly enter streams through stormwater runoff and discharges.

Macrobenthic community response to copper in Shelter Island Yacht Basin, San Diego Bay, California.

PubMed

Neira, Carlos; Mendoza, Guillermo; Levin, Lisa A; Zirino, Alberto; Delgadillo-Hinojosa, Francisco; Porrachia, Magali; Deheyn, Dimitri D

2011-04-01

We examined Cu contamination effects on macrobenthic communities and Cu concentration in invertebrates within Shelter Island Yacht Basin, San Diego Bay, California. Results indicate that at some sites, Cu in sediment has exceeded a threshold for "self defense" mechanisms and highlight the potential negative impacts on benthic faunal communities where Cu accumulates and persists in sediments. At sites with elevated Cu levels in sediment, macrobenthic communities were not only less diverse but also their total biomass and body size (individual biomass) were reduced compared to sites with lower Cu. Cu concentration in tissue varied between species and within the same species, reflecting differing abilities to "regulate" their body load. The spatial complexity of Cu effects in a small marina such as SIYB emphasizes that sediment-quality criteria based solely on laboratory experiments should be used with caution, as they do not necessarily reflect the condition at the community and ecosystem levels. Copyright © 2011 Elsevier Ltd. All rights reserved.

Environmental availability of potentially toxic elements in estuarine sediments of the Cananéia-Iguape coastal system, Southeastern Brazil.

PubMed

Tramonte, Keila Modesto; Figueira, Rubens Cesar Lopes; de Lima Ferreira, Paulo Alves; Ribeiro, Andreza Portella; Batista, Miriam Fernanda; de Mahiques, Michel Michaelovitch

2016-02-15

The Cananéia-Iguape system is located in a Southeastern Brazilian coastal region, acknowledged by UNESCO as Biosphere Reserve of the Atlantic Rainforest. This system underwent important environmental changes due to the opening of the artificial channel of Valo Grande and by past intensive Pb ore mining activities. In view of this scenario, this study evaluated Cu, Pb and Zn availability in sediments from Cananéia-Iguape system, based on the content associated with the main components of the sediments. Moreover, in order to assess local contamination, the metals' contents were compared to Canadian quality guidelines, the past levels of metals preceding the mining activities and background sediment values. Concerning Cu and Zn in a state of chemical remobilization, both elements would possibly present no harm to the local communities. However, Pb available content exceeded the comparison values in various sampling sites, suggesting the need of monitoring regarding its bioavailability. Copyright © 2015 Elsevier Ltd. All rights reserved.

Organic contaminants, trace and major elements, and nutrients in water and sediment sampled in response to the Deepwater Horizon oil spill

USGS Publications Warehouse

Nowell, Lisa H.; Ludtke, Amy S.; Mueller, David K.; Scott, Jonathon C.

2011-01-01

Considering all the information evaluated in this report, there were significant differences between pre-landfall and post-landfall samples for PAH concentrations in sediment. Pre-landfall and post-landfall samples did not differ significantly in concentrations or benchmark exceedances for most organics in water or trace elements in sediment. For trace elements in water, aquatic-life benchmarks were exceeded in almost 50 percent of samples, but the high and variable analytical reporting levels precluded statistical comparison of benchmark exceedances between sampling periods. Concentrations of several PAH compounds in sediment were significantly higher in post-landfall samples than pre-landfall samples, and five of seven sites with the largest differences in PAH concentrations also had diagnostic geochemical evidence of Deepwater Horizon Macondo-1 oil from Rosenbauer and others (2010).

Vertical distribution of trace-element concentrations and occurrence of metallurgical slag particles in accumulated bed sediments of Lake Roosevelt, Washington, September 2002

USGS Publications Warehouse

Cox, S.E.; Bell, P.R.; Lowther, J.S.; Van Metre, P.C.

2005-01-01

Sediment cores were collected from six locations in Lake Roosevelt to determine the vertical distributions of trace-element concentrations in the accumulated sediments of Lake Roosevelt. Elevated concentrations of arsenic, cadmium, copper, lead, mercury, and zinc occurred throughout much of the accumulated sediments. Concentrations varied greatly within the sediment core profiles, often covering a range of 5 to 10 fold. Trace-element concentrations typically were largest below the surficial sediments in the lower one-half of each profile, with generally decreasing concentrations from the 1964 horizon to the surface of the core. The trace-element profiles reflect changes in historical discharges of trace elements to the Columbia River by an upstream smelter. All samples analyzed exceeded clean-up guidelines adopted by the Confederated Tribes of the Colville Reservation for cadmium, lead, and zinc and more than 70 percent of the samples exceeded cleanup guidelines for mercury, arsenic, and copper. Although 100 percent of the samples exceeded sediment guidelines for cadmium, lead, and zinc, surficial concentrations of arsenic, copper, and mercury in some cores were less than the sediment-quality guidelines. With the exception of copper, the trace-element profiles of the five cores collected along the pre-reservoir Columbia River channel typically showed trends of decreasing concentrations in sediments deposited after the 1964 time horizon. The decreasing concentrations of trace elements in the upper half of cores from along the pre-reservoir Columbia River showed a pattern of decreasing concentrations similar to reductions in trace-element loading in liquid effluent from an upstream smelter. Except for arsenic, trace-element concentrations typically were smaller at downstream reservoir locations along the pre-reservoir Columbia River. Trace-element concentration in sediments from the Spokane Arm of the reservoir showed distinct differences compared to the similarities observed in cores from along the pre-reservoir Columbia River. Particles of slag, which have physical and chemical characteristics of slag discharged to the Columbia River by a lead-zinc smelter upstream of the reservoir at Trail, British Columbia, were found in sediments of Lake Roosevelt. Slag particles are more common in the upstream reaches of the reservoir. The chemical composition of the interior matrix of slag collected from Lake Roosevelt closely approximated the reported elemental concentrations of fresh smelter slag, although evidence of slag weathering was observed. Exfoliation flakes were observed on the surface of weathered slag particles isolated from the core sediments. The concentrations of zinc on the exposed surface of slag grains were smaller than concentrations on interior surfaces. Weathering rinds also were observed in the cross section of weathered slag grains, indicating that the glassy slag material was undergoing hydration and chemical weathering. Trace elements observed in accumulated sediments in the middle and lower reaches of the reservoir are more likely due to the input from liquid effluent discharges compared to slag discharges from the upstream smelter.

Mercury and cadmium contamination of irrigation water, sediment, soil and shallow groundwater in a wastewater-irrigated field in Tianjin, China.

PubMed

Wu, G-H; Cao, S-S

2010-03-01

We investigated the concentrations of Hg, Cd, Pb and As in samples of irrigation water, sediment, soil and groundwater from a field in Tianjin that was irrigated with wastewater. The results showed that the concentrations (Hg, 0.82 microg/L; Cd, 0.18 microg/L; Pb, 1.5 microg/L; As, 8.02 microg/L) in the irrigation water did not exceed the China Surface Water Quality Standard or the maximum concentrations in irrigation water recommended by the FAO. The concentrations of metals in the groundwater of wells (Hg, 0.016 microg/L; Cd, 0.128 microg/L; Pb, 0.25 microg/L; As, 4.65 microg/L) were lower than China Groundwater Quality Standard and the WHO guideline values for drinking water. The groundwater had not yet been contaminated through vertical infiltration-induced leaching. However, a substantial buildup of Hg and Cd in river sediments (I(geo) for Hg and Cd; 5.24 and 3.04, respectively) and wastewater-irrigated soils (I(geo) for Hg and Cd; 2.50 and 3.09, respectively) was observed. Taken together, these results indicated that irrigation with wastewater damaged the soil quality over the long term and that metals more easily accumulated in vegetable fields than rice fields.

Environmental impact of the Midia Port - Black Sea (Romania), on the coastal sediment quality

NASA Astrophysics Data System (ADS)

Catianis, Irina; Ungureanu, Constantin; Magagnini, Luca; Ulazzi, Elisa; Campisi, Tiziana; Stanica, Adrian

2016-03-01

The aim of the study was to evaluate the impact of potential pollution sources, mainly from the upstream anthropogenic sources and port-related activities. The in-vestigated area covered a wide range of anthropogenic im-pacts (e.g., industrial wastes, storm water runoff, acciden-tal oil spills, intentional discharges and shipping activities). The quality of water and Sediments was assessed us-ing Standard methods, as physical-chemical parameters, chemistry and biology (microbiology, ecotoxicology) aim-ing to figure the level of pollution and the effect of port-related activities. Seawater quality results agreed generally with environmental Standards. Though, in some samples the concentrations of sulphates (mg/1) and heavy metals (μg/1), as B, As and Se exceeded the recommended lim-its, without posing a serious environmental concern. Most of the surface sediment samples contain critical levels of hydrocarbons (C>12), (mg/kg), polycyclic aromatic hydrocarbons (ng/g) and polychlorobiphenyls (ng/g). For some heavy metals (mg/kg), exchangeable concentrations were found to be very close or above the regulations. The signifi-cance of this study is incontestable taking into account the lack of previous relevant historical data of this area. In this sense, it was possible to indicate, in general, good environmental conditions, despite the industrial and concentrated local port-related activities in the investigated area.

Fish assemblages and environmental variables associated with hard-rock mining in the Coeur d'Alene River basin, Idaho

USGS Publications Warehouse

Maret, Terry R.; MacCoy, Dorene E.

2002-01-01

As part of the U.S. Geological Survey's National Water Quality Assessment Program, fish assemblages, environmental variables, and associated mine densities were evaluated at 18 test and reference sites during the summer of 2000 in the Coeur d'Alene and St. Regis river basins in Idaho and Montana. Multimetric and multivariate analyses were used to examine patterns in fish assemblages and the associated environmental variables representing a gradient of mining intensity. The concentrations of cadmium (Cd), lead (Pb), and zinc (Zn) in water and streambed sediment found at test sites in watersheds where production mine densities were at least 0.2 mines/km2 (in a 500-m stream buffer) were significantly higher than the concentrations found at reference sites. Many of these metal concentrations exceeded Ambient Water Quality Criteria (AWQC) and the Canadian Probable Effect Level guidelines for streambed sediment. Regression analysis identified significant relationships between the production mine densities and the sum of Cd, Pb, and Zn concentrations in water and streambed sediment (r2 = 0.69 and 0.66, respectively; P < 0.01). Zinc was identified as the primary metal contaminant in both water and streambed sediment. Eighteen fish species in the families Salmonidae, Cottidae, Cyprinidae, Catostomidae, Centrarchidae, and Ictaluridae were collected. Principal components analysis of 11 fish metrics identified two distinct groups of sites corresponding to the reference and test sites, predominantly on the basis of the inverse relationship between percent cottids and percent salmonids (r = -0.64; P < 0.05). Streams located downstream from the areas of intensive hard-rock mining in the Coeur d'Alene River basin contained fewer native fish and lower abundances as a result of metal enrichment, not physical habitat degradation. Typically, salmonids were the predominant species at test sites where Zn concentrations exceeded the acute AWQC. Cottids were absent at these sites, which suggests that they are more severely affected by elevated metals than are salmonids.

Geochemical assessment of metals and dioxin in sediment from the San Carlos Reservoir and the Gila, San Carlos, and San Francisco Rivers, Arizona

USGS Publications Warehouse

Church, Stan E.; Choate, LaDonna M.; Marot, Marci E.; Fey, David L.; Adams, Monique; Briggs, Paul H.; Brown, Zoe Ann

2005-01-01

In October 2004, we sampled stream-bed sediment, terrace sediment, and sediment from the San Carlos Reservoir to determine the spatial and chronological variation of six potentially toxic metals-Cu, Pb, Zn, Cd, As, and Hg. Water levels in the San Carlos Reservoir were at a 20-year low at an elevation of 2,409 ft (734.3 m). Four cores were taken from the reservoir: one from the San Carlos River arm, one from the Gila River arm, and two from the San Carlos Reservoir just west of the Pinal County line. Radioisotope chronometry (7Be, 137Cs, and 210Pb) conducted on sediment from the reservoir cores provides a good chronological record back to 1959. Chronology prior to that, during the 1950s, is based on our interpretation of the 137Cs anomaly in reservoir cores. During and prior to the 1950s, the reservoir was dry and sediment-accumulation rates were irregular; age control based on radioisotope data was not possible. We recovered sediment at the base of one 4-m-long core that may date back to the late 1930s. The sedimentological record contains two discrete events, one about 1978-83 and one about 1957, where the Cu concentration in reservoir sediment exceeded recommended sediment quality guidelines and should have had an effect on sensitive aquatic and benthic organisms. Concentrations of Zn determined in sediment deposited during the 1957(?) event also exceeded recommended sediment quality guidelines. Concentration data for Cu from the four cores clearly indicate that the source of this material was upstream on the Gila River. Lead isotope data, coupled with the geochemical data from a 2M HCl-1 percent H2O2 leach of selected sediment samples, show two discrete populations of data. One represents the dominant sediment load derived from the Safford Valley, and a second reflects sediment derived from the San Francisco River. The Cu concentration spikes in the reservoir cores have chemical and Pb isotope signatures that indicate that deposits in a porphyry copper deposit from the Morenci district is the likely source of these Cu-rich sedimentary deposits. Copper concentrations and Pb isotope data in premining terrace-sediment deposits indicate that the Cu peaks could not have resulted from erosion of premining sediment from terrace deposits downstream on the Gila River. The chemical and Pb isotope data also indicate that agricultural practices in the Safford Valley have resulted in an increased sediment load to the Gila River since large-scale farming began, prior to the time when the San Carlos Reservoir was built. Analyses of dioxin, which is an impurity in one of the herbicides used in the late 1960s and early 1970s, were completed in sediment from one of the cores in the reservoir to determine whether any of these pesticide residues have accumulated in the reservoir sediment. Dioxin concentration is expressed in terms of its toxicity (toxic equivalent concentration or TEQ). Concentrations of dioxin in the sediment ranged from 0.68 to 1.37 pg/g and are less than any of the benchmark concentrations recommended as threshold values for adverse effects of dioxin in sediment (> 2.5-10 pg/g).

Sediment Loads and Yield, and Selected Water-Quality Parameters in Clear Creek, Carson City and Douglas County, Nevada, Water Years 2004-07

USGS Publications Warehouse

Seiler, Ralph L.; Wood, James L.

2009-01-01

Some reaches of Clear Creek above U.S. Highway 395 have experienced severe erosion as a result of fires, extreme precipitation events, and past and current human activities in the basin. Previous evaluations of erosion in the basin have concluded that most of the sediment produced and transported in the basin was associated with U.S. Highway 50, a four-lane highway that roughly parallels Clear Creek through much of the basin. During this study (water years 2004-07), construction of roads and a large residential area and golf course in the area began and are likely to affect water quality and sediment transport in the basin. Sediment data were collected between October 2003 and September 2007 (water years 2004-07) from three sites along Clear Creek. Annual suspended-sediment load was estimated to range from 1,456 tons in water year 2006 to only 100 tons in water year 2004, which corresponds to suspended-sediment yields of 93.9 tons per square mile per year in 2006 to 6.4 tons per square mile per year in 2004. In water year 2006, the suspended-sediment load on December 31, 2005, alone exceeded the combined annual load for water years 2004, 2005, and 2007. Bedload sediment was estimated to comprise 73 percent of total sediment load in the creek. Mean annual suspended-sediment yield in Clear Creek basin was much greater than yields in the Logan House, Edgewood, and Glenbrook Creek basins in the adjacent Lake Tahoe basin. Comparison of data collected during this study with data collected by university researchers in the 1970s is inconclusive as to whether fundamental changes in basin sediment characteristics have occurred during the 30-year period because different methods and sampling locations were used in the earlier studies.

Highly contaminated areas as sources of pollution for adjoining ecosystems: The case of Augusta Bay (Central Mediterranean).

PubMed

Di Leonardo, R; Mazzola, A; Tramati, C D; Vaccaro, A; Vizzini, S

2014-12-15

An assessment of trace element and polycyclic aromatic hydrocarbon (PAH) contamination based on surface sediments collected in summer 2012 was carried out in Priolo Bay adjoining one of the most polluted areas of the Mediterranean Sea, the industrial Augusta harbour (Italy, Central Mediterranean). Inorganic and organic contaminants were generally not remarkable. Occasional elevated concentrations of Hg, Cd, Ni and PAHs exceeding sediment quality guidelines were detected in the northern sector of Priolo Bay, close to Augusta harbour, possibly as a result of water drainage of industrialised and urbanised areas and/or potential direct export of contaminated material from Augusta harbour, whose influence on the adjoining Priolo Bay ecosystem cannot be ruled out. By domino effect, Priolo sediments may therefore become a potential source of pollutants and may represent a threat to the biota. Copyright © 2014 Elsevier Ltd. All rights reserved.

Water quality, organic chemistry of sediment, and biological conditions of streams near an abandoned wood-preserving plant site at Jackson, Tennessee

USGS Publications Warehouse

Bradfield, A.D.; Flexner, N.M.; Webster, D.A.

1993-01-01

An investigation of water quality, organic sediment chemistry, and biological conditions of streams near an abandoned wood-preserving plant site at Jackson, Tennessee, was conducted during December 1990. The study was designed to assess the extent of possible contamination of water and biota in the streams from creosote-related discharge originating at this Superfund site. Central Creek, adjacent to the plant, had degraded water quality and biological conditions. Water samples from the most downstream station on Central Creek contained 30 micrograms per liter of pentachlorophenol, which exceeds the State's criterion maximum concentrations of 9 micrograms per liter for fish and aquatic life. Bottom-sediment samples from stations on Central Creek contained concentrations of acenaphthene, napthalene, and phenanthrene ranging from 1,400 to 2,500 micrograms per kilogram. Chronic or acute toxicity resulted during laboratory experiments using test organisms exposed to creosote-related contaminants. Sediment elutriate samples from Central Creek caused slightly to highly toxic effects on Ceriodaphnia dubia. Pimephales promelas, and Photobacterium phosphoreum. Fish-tissue samples from this station contained concentrations of naphthalene. dibenzofuran, fluorene, and phenanthrene ranging from 1.5 to 3.9 micrograms per kilogram Blue-green algae at this station represented about 79 percent of the organisms counted, whereas diatoms accounted for only 11 percent. Benthic invertebrate and fish samples from Central Creek had low diversity and density. Sediment samples from a station on the South Fork Forked Deer River downstream from its confluence with Central Creek contained concentrations of acenaphthene, anthracene, chrysene, fluoranthene, fluorene, pyrere, and phenanthrene ranging from 2,800 to 69,000 micrograms per kilogram. Sediment elutriate samples using water as elutriate from this station contained concentrations of extractable organic compounds ranging from an estimated 43 to 420 micrograms per liter. Sediment elutriate samples were toxic to Ceriodaphnia dubta, Pimephales promelas, Photobacterium phosphoreum, and Salenastrum capricornulum.

Pesticide and trace metal occurrence and aquatic benchmark exceedances in surface waters and sediments of urban wetlands and retention ponds in Melbourne, Australia.

PubMed

Allinson, Graeme; Zhang, Pei; Bui, AnhDuyen; Allinson, Mayumi; Rose, Gavin; Marshall, Stephen; Pettigrove, Vincent

2015-07-01

Samples of water and sediments were collected from 24 urban wetlands in Melbourne, Australia, in April 2010, and tested for more than 90 pesticides using a range of gas chromatographic (GC) and liquid chromatographic (LC) techniques, sample 'hormonal' activity using yeast-based recombinant receptor-reporter gene bioassays, and trace metals using spectroscopic techniques. At the time of sampling, there was almost no estrogenic activity in the water column. Twenty-three different pesticide residues were observed in one or more water samples from the 24 wetlands; chemicals observed at more than 40% of sites were simazine (100%), atrazine (79%), and metalaxyl and terbutryn (46%). Using the toxicity unit (TU) concept, less than 15% of the detected pesticides were considered to pose an individual, short-term risk to fish or zooplankton in the ponds and wetlands. However, one pesticide (fenvalerate) may have posed a possible short-term risk to fish (log10TUf > -3), and three pesticides (azoxystrobin, fenamiphos and fenvalerate) may have posed a risk to zooplankton (logTUzp between -2 and -3); all the photosystem II (PSII) inhibiting herbicides may have posed a risk to primary producers in the ponds and wetlands (log10TUap and/or log10TUalg > -3). The wetland sediments were contaminated with 16 different pesticides; no chemicals were observed at more than one third of sites, but based on frequency of detection and concentrations, bifenthrin (33%, maximum 59 μg/kg) is the priority insecticide of concern for the sediments studied. Five sites returned a TU greater than the possible effect threshold (i.e. log10TU > 1) as a result of bifenthrin contamination of their sediments. Most sediments did not exceed Australian sediment quality guideline levels for trace metals. However, more than half of the sites had threshold effect concentration quotients (TECQ) values >1 for Cu (58%), Pb (50%), Ni (67%) and Zn (63%), and 75% of sites had mean probable effect concentration quotients (PECQ) >0.2, suggesting that the collected sediments may have been having some impact on sediment-dwelling organisms.

Field screening of water quality, bottom sediment, and biota associated with irrigation drainage in the Yuma Valley, Arizona, 1995

USGS Publications Warehouse

Tadayon, Saeid; King, K.A.; Andrews, Brenda; Roberts, William

1997-01-01

Because of concerns expressed by the U.S. Congress and the environmental community, the Department of the Interior began a program in late 1985 to identify the nature and extent of water-quality problems induced by irrigation that might exist in the western States. Surface water, bottom sediment, and biota were collected from March through September 1995 along the lower Colorado River and in agricultural drains at nine sites in the Yuma Valley, Arizona, and analyzed for selected inorganic and organic constituents. Analyses of water, bottom sediment, and biota were completed to determine if irrigation return flow has caused, or has the potential to cause, harmful effects on human health, fish, and wildlife in the study area. Concentrations of dissolved solids in surface-water samples collected in March generally did not vary substantially from surface-water samples collected in June. Concentrations of dissolved solids ranged from 712 to 3,000 milligrams per liter and exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 500 milligrams per liter for drinking water. Concentrations of chloride in 9 of 18 water samples and concentrations of sulfate in 16 of 18 water samples exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 250 milligrams per liter for drinking water. Calcium and sodium were the dominant cations, and chloride and sulfate were the dominant anions. The maximum selenium concentration of 8 micrograms per liter exceeded the U.S. Environmental Protection Agency aquatic-life chronic criterion of 5 micrograms per liter. Concentrations of lead in 7 of 18 water samples and concentrations of mercury in 4 of 18 water samples exceeded the aquatic-life cronic criteria of 3.2 and 0.012 micrograms per liter, respectively. Concentrations of antimony, beryllium, cadmium, and silver in the water samples were below analytical reporting limits. Arsenic was detected in 3 of 9 bottom-sediment samples, and concentrations ranged from 11 to 16 micrograms per gram. Concentrations ofaluminum, beryllium, boron, copper, lead, and zinc were highest in samples from Main Drain at southerly international boundary near San Luis, Arizona. Selenium was detected in all bottom-sediment samples, and concentrations ranged from 0.1 to 0.7 micrograms per gram. Concentrations of cadmium, europium, homium, mercury, molybdenum, silver, tantalum, tin, and uranium were below analytical reporting limits in the bottom-sediment samples. Concentrations of trace elements in bottom-sediment samples were within the ranges found in a study of soils of the western United States and did not indicate a significant accumulation of these constituents. p,p'Dichlorodiphenyldichloroethylene (commonly referred to as p,-p'-DDE) was detected in one bottom-sediment sample at a concentration of 1.4 micrograms per gram. No other organochlorine compounds were detected in the bottom-sediment samples. DDE was present in all fish and bird samples. Almost one-half of the fish samples contained DDE residues that were two times higher than the mean calculated for a national study in 1984-85. Twenty-tree percent of the fish contained more than three times the national mean. Fish from downstream parts of the Main Drain had the highest concentrations of DDE. Although concentrations of DDE in fish and in bird carcasses and eggs were above background levels, residues generally were below thresholds associated with chronic poisoning and reproductive problems in figh and wildlife. Concentrations of 18 trace elements were detected in cattail (Typha sp.) roots, freshwater clam (Corbicula fluminea), fish, and bird samples. Selenium in most fish and in livers of red-winged (Agelaius phoeniceus) and yellow-headed (Xanthocephalus xanthocephalus) blackbirds was above background concentrations but below toxic concentrations. In contrast, selenium was present in a killdeer (Charadrium vociferus) liver sample at potentially toxic con

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Pine River Project area, Southern Ute Indian Reservation, southwestern Colorado and northwestern New Mexico, 1988-89

USGS Publications Warehouse

Butler, D.L.; Krueger, R.P.; Osmundson, B.C.; Thompson, A.L.; Formea, J.J.; Wickman, D.W.

1993-01-01

During 1988-89, water, bottom sediment, biota, soil, and plants were sampled for a reconnaissance investigation of the Pine River Project area in southwestern Colorado. Irrigation drainage does not seem to be a major source of dissolved solids in streams. Concentrations of manganese, mercury, and selenium exceeded drinking-water regulations in some streams. The maximum selenium concentration in a stream sample was 94 microg/L in Rock Creek. Irrigation drainage and natural groundwater are sources of some trace elements to streams. Water from a well in a nonirrigated area had 4,800 microg/L of selenium. Selenium concentrations in soil on the Oxford Tract were greater in areas previously or presently irrigated than in areas never irrigated. Some forage plants on the Oxford Tract had large selenium concentrations, including 180 mg/km in alfalfa. Most fish samples had selenium concentrations greater than the National Contaminant Biomonitoring Program 85th percentile. Selenium concentrations in aquatic plants, aquatic inverte- brates, and small mammals may be of concern to fish and wildlife because of possible food-chain bioconcentration. Selenium concentrations in bird samples indicate selenium contamination of biota on the Oxford Tract. Mallard breasts had selenium concentrations exceeding a guideline for human consumption. The maximum selenium concentration in biota was 50 microg/g dry weight in a bird liver from the Oxford Tract. In some fish samples, arsenic, cadmium, copper, and zinc exceeded background concentrations, but concentrations were not toxic. Mercury concentrations in 16 fish samples exceeded the background concentration. Ten mercury concentrations in fish exceeded a guideline for mercury in food for consumption by pregnant women.

Detailed study of selenium in soil, water, bottom sediment, and biota in the Sun River Irrigation Project, Freezout Lake Wildlife Management Area, and Benton Lake National Wildlife Refuge, west-central Montana, 1990-92

USGS Publications Warehouse

Nimick, D.A.; Lambing, J.H.; Palawski, D.U.; Malloy, J.C.

1996-01-01

Selenium and other constituents are adversely affecting water quality and creating a potential hazard to wildlife in several areas of the Sun River Irrigation Project, Freezout Lake Wildlife Management Area, and Benton Lake National Wildlife Refuge in west-central Montana. Selenium derived from Cretaceous shale and Tertiary and Quaternary deposits containing shale detritus is transported in the oxic shallow ground-water systems. At Freezout Lake Wildlife Management Area, drainage from irrigated glacial deposits is the primary source of selenium; drainage from non-irrigated farmland is a significant source locally. Benton Lake generally receives more selenium from natural runoff from its non-irrigated basin than from the trans-basin diversion of irrigation return flow. Selenium has accumulated in aquatic plants and invertebrates, fish, and water birds, particularly in wetlands that receive the largest selenium loads. Although selenium residues in biological tissue from some wetland units exceeded biological risk levels, water-bird reproduction generally has not been impaired. The highest selenium residues in biota commonly occurred in samples from Priest Butte Lakes, which also had the highest selenium concentration in wetland water. Selenium concentrations in all invertebrate samples from Priest Butte Lakes and the south end of Freezeout Lake exceeded the critical dietary threshold for water birds. Selenium delivered to wetlands accumulates in bottom sediment, predominantly in near-shore areas. Potential impacts to water quality, and presumably biota, may be greatest near the mouths of inflows. Most selenium delivered to wetlands will continue to accumulate in bottom sediment and biota.

Natural and artificial radionuclides in the Suez Canal bottom sediments and stream water

NASA Astrophysics Data System (ADS)

El-Tahawy, M. S.; Farouk, M. A.; Ibrahiem, N. M.; El-Mongey, S. A. M.

1994-07-01

Concentration of natural and artificial radionuclides in Suez Canal bottom sediments and stream water have been measured using γ spectrometers based on a hyper-pure Ge detector. The activity concentrations of 238U series, 232Th series and 40K did not exceed 16.0, 15.5 and 500.0 Bq kg-1 dry weight for sediments. The activity concentration of 238U series and 40K did not exceed 0.6 and 18.0 Bq 1-1 for stream water.

Mining and urban impacts on semi-arid freshwater aquatic systems: the example of Mount Isa, Queensland.

PubMed

Taylor, Mark P; Mackay, Alana; Kuypers, Tabitha; Hudson-Edwards, Karen

2009-05-01

This paper examines the environmental risk and impact of trace metals affecting river water and sediment in and around Mount Isa, Queensland, Australia. Bacterial indicator densities are also analysed throughout the catchment to assess the impacts and the potential hazards arising from agricultural activities, sewage treatment plant releases and urban runoff. The area is drained by the ephemeral Leichhardt River, which bisects Mount Isa City and the major Pb, Zn, Cu and Ag Mount Isa Mine. Runoff is captured downstream in Lake Moondarra, with the water being used following natural filtration via a lagoon-reed bed system for potable purposes by the residents of Mount Isa City. During the dry season, the channel is characterised by numerous pools that act as storage zones for sediment and water-soluble metals as well as urban and agriculturally derived nutrients and pathogens. Our results show that sediment and water quality within the Leichhardt River adjacent to and downstream of the mine frequently exceed Australian government sediment guidelines with average values of Cu, Pb and Zn found adjacent to the footprint of the mine being 1550, 510 and 470 mg kg(-1), respectively. Dry season analysis of water-soluble Cu, Pb and Zn concentrations within pools showed that Australian government low trigger guidelines are exceeded in 100, 46 and 100% cases, respectively. The densities of bacterial indicators in remnant pools throughout the Leichhardt River also exceeded acceptable guidelines. Maximum dry season faecal coliform densities of 2000 colony forming units (CFU) per 100 mL and Enterococcus counts of 900 organisms per 100 mL were recorded in dry season remnant pools compared to wet season maximum faecal coliform and Enterococcus densities of 119 000 CFU per 100 mL and 95 000 organisms per 100 mL, respectively. The impacts on biota were also examined by assessing the metal content of the tissue of seven fish from Lake Moondarra for their Cd, Cu, Hg, Pb and Zn concentrations. Tissue metal values were generally low with only a few samples having Cu and Zn values in excess of the recommended Australian retail guideline values for fish suitable for human consumption. The effectiveness of the City's natural reed bed potable water processing facility for removing metals held within the water body (soluble and particulate) was also assessed. The results show that the treated water generally meets Australian drinking water guidelines. Overall it is clear that sediment and water quality in the area upstream of the potable water storage zone is seriously impaired. The combined effects of industrial, agricultural and urban activities present a considerable risk to the consistency and reliability of water quality, especially during highly turbid wet season flows, which transfer highly elevated concentrations of water-soluble metal and microbial contaminants.

Sediment quantity and quality in three impoundments in Massachusetts

USGS Publications Warehouse

Zimmerman, Marc James; Breault, Robert F.

2003-01-01

As part of a study with an overriding goal of providing information that would assist State and Federal agencies in developing screening protocols for managing sediments impounded behind dams that are potential candidates for removal, the U.S Geological Survey determined sediment quantity and quality at three locations: one on the French River and two on Yokum Brook, a tributary to the west branch of the Westfield River. Data collected with a global positioning system, a geographic information system, and sediment-thickness data aided in the creation of sediment maps and the calculation of sediment volumes at Perryville Pond on the French River in Webster, Massachusetts, and at the Silk Mill and Ballou Dams on Yokum Brook in Becket, Massachusetts. From these data the following sediment volumes were determined: Perryville Pond, 71,000 cubic yards, Silk Mill, 1,600 cubic yards, and Ballou, 800 cubic yards. Sediment characteristics were assessed in terms of grain size and concentrations of potentially hazardous organic compounds and metals. Assessment of the approaches and methods used at study sites indicated that ground-penetrating radar produced data that were extremely difficult and time-consuming to interpret for the three study sites. Because of these difficulties, a steel probe was ultimately used to determine sediment depth and extent for inclusion in the sediment maps. Use of these methods showed that, where sampling sites were accessible, a machine-driven coring device would be preferable to the physically exhausting, manual sediment-coring methods used in this investigation. Enzyme-linked immunosorbent assays were an effective tool for screening large numbers of samples for a range of organic contaminant compounds. An example calculation of the number of samples needed to characterize mean concentrations of contaminants indicated that the number of samples collected for most analytes was adequate; however, additional analyses for lead, copper, silver, arsenic, total petroleum hydrocarbons, and chlordane are needed to meet the criteria determined from the calculations. Particle-size analysis did not reveal a clear spatial distribution pattern at Perryville Pond. On average, less than 65 percent of each sample was greater in size than very fine sand. The sample with the highest percentage of clay-sized particles (24.3 percent) was collected just upstream from the dam and generally had the highest concentrations of contaminants determined here. In contrast, more than 90 percent of the sediment samples in the Becket impoundments had grain sizes larger than very fine sand; as determined by direct observation, rocks, cobbles, and boulders constituted a substantial amount of the material impounded at Becket. In general, the highest percentages of the finest particles, clays, occurred in association with the highest concentrations of contaminants. Enzyme-linked immunosorbent assays of the Perryville samples showed the widespread presence of petroleum hydrocarbons (16 out of 26 samples), polycyclic aromatic hydrocarbons (23 out of 26 samples), and chlordane (18 out of 26 samples); polychlorinated biphenyls were detected in five samples from four locations. Neither petroleum hydrocarbons nor polychlorinated biphenyls were detected at Becket, and chlordane was detected in only one sample. All 14 Becket samples contained polycyclic aromatic hydrocarbons. Replicate quality-control analyses revealed consistent results between paired samples. Samples from throughout Perryville Pond contained a number of metals at potentially toxic concentrations. These metals included arsenic, cadmium, copper, lead, nickel, and zinc. At Becket, no metals were found in elevated concentrations. In general, most of the concentrations of organic compounds and metals detected in Perryville Pond exceeded standards for benthic organisms, but only rarely exceeded standards for human contact. The most highly contaminated samples were

From streets to streams: assessing the toxicity potential of urban sediment by particle size

USGS Publications Warehouse

Corsi, Steven R.; Selbig, William R.; Roger T. Bannerman,; ,

2013-01-01

Urban sediment can act as a transport mechanism for a variety of pollutants to move towards a receiving water body. The concentrations of these pollutants oftentimes exceed levels that are toxic to aquatic organisms. Many treatment structures are designed to capture coarse sediment but do not work well to similarly capture the fines. This study measured concentrations of select trace metals and PAHs in both the silt and sand fractions of urban sediment from four sources: stormwater bed, stormwater suspended, street dirt, and streambed. Concentrations were used to assess the toxic potential of sediment based on published sediment quality guidelines. All sources of sediment showed some level of toxic potential with stormwater bed sediment the highest followed by stormwater suspended, street dirt, and streambed. Both metal and PAH concentration distributions were highly correlated between the four sampling locations suggesting the presence of one or perhaps only a few sources of these pollutants which remain persistent as sediment is transported from street to stream. Comparison to other forms of combustion- and vehicle-related sources of PAHs revealed coal tar sealants to have the strongest correlation, in both the silt and sand fractions, at all four sampling sites. This information is important for environmental managers when selecting the most appropriate Best Management Practice (BMP) as a way to mitigate pollution conveyed in urban stormwater from source to sink.

Sedimentation and occurrence and trends of selected nutrients, other chemical constituents, and cyanobacteria in bottom sediment, Clinton Lake, northeast Kansas, 1977-2009

USGS Publications Warehouse

Juracek, Kyle E.

2011-01-01

A combination of available bathymetric-survey information and bottom-sediment coring was used to investigate sedimentation and the occurrence of selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 25 trace elements, cyanobacterial akinetes, and the radionuclide cesium-137 in the bottom sediment of Clinton Lake, northeast Kansas. The total estimated volume and mass of bottom sediment deposited from 1977 through 2009 in the conservation (multi-purpose) pool of the reservoir was 438 million cubic feet and 18 billion pounds, respectively. The estimated sediment volume occupied about 8 percent of the conservation-pool, water-storage capacity of the reservoir. Sedimentation in the conservation pool has occurred about 70 percent faster than originally projected at the time the reservoir was completed. Water-storage capacity in the conservation pool has been lost to sedimentation at a rate of about 0.25 percent annually. Mean annual net sediment deposition since 1977 in the conservation pool of the reservoir was estimated to be 563 million pounds per year. Mean annual net sediment yield from the Clinton Lake Basin was estimated to be 1.5 million pounds per square mile per year. Typically, the bottom sediment sampled in Clinton Lake was at least 99 percent silt and clay. The mean annual net loads of total nitrogen and total phosphorus deposited in the bottom sediment of Clinton Lake were estimated to be 1.29 million pounds per year and 556,000 pounds per year, respectively. The estimated mean annual net yields of total nitrogen and total phosphorus from the Clinton Lake Basin were 3,510 pounds per square mile per year and 1,510 pounds per square mile per year, respectively. Throughout the history of Clinton Lake, total nitrogen concentrations in the deposited sediment generally were uniform and indicated consistent inputs to the reservoir over time. Likewise, total phosphorus concentrations in the deposited sediment generally were uniform. Although, for two of three coring sites, a possible positive trend in phosphorus deposition was indicated. The Wakarusa River possibly was a larger contributor of nitrogen and phosphorus to Clinton Lake than was Rock Creek. As a principal limiting factor for primary production in most freshwater environments, phosphorus is of particular importance because increased inputs can contribute to accelerated reservoir eutrophication and the production of algal toxins and taste-and-odor compounds. Trace-element concentrations in the bottom sediment of Clinton Lake generally were uniform over time. As is typical for eastern Kansas reservoirs, arsenic, chromium, and nickel concentrations typically exceeded the threshold-effects guidelines, which represent the concentrations above which toxic biological effects occasionally occur. Zinc concentrations frequently exceeded the threshold-effects guideline. Trace-element concentrations did not exceed the probable-effects guidelines (available for eight trace elements), which represent the concentrations above which toxic biological effects usually or frequently occur. Cyanobacterial akinetes (cyanobacteria resting stage) in the bottom sediment of Clinton Lake, combined with historical water-quality data on chlorophyll-a and total phosphorus concentrations, indicated that the reservoir likely has been eutrophic throughout most of its history. A statistically significant increase in cyanobacterial akinetes in the bottom sediment indicated that Clinton Lake may have become more eutrophic over the life of the reservoir. The increase in cyanobacterial akinetes may, in part, be related to a possible increase in total phosphorus concentrations.

Assessment of trace metals contamination level, bioavailability and toxicity in sediments from Dakar coast and Saint Louis estuary in Senegal, West Africa.

PubMed

Diop, Cheikh; Dewaelé, Dorothée; Cazier, Fabrice; Diouf, Amadou; Ouddane, Baghdad

2015-11-01

Trace metals have the potential to associate with sediments that have been recognised as significant source of contamination for the benthic environment. The current study aims assessing the trace metals contamination level in sediments from Dakar coast and Saint Louis estuary, and to examine their bioavailability to predict potential toxicity of sediments. Surface sediment samples were collected between June 2012 and January 2013 in three sampling periods from eight stations. Trace metals were analysed using inductively coupled plasma-optical emission spectrometer. Geoaccumulation indexes (Igeo) showed strong pollution by Cd, Cr, Cu and Pb confirmed by enrichment factor (EF) suggesting that these metals derived from anthropogenic sources. Toxicity indexes exceeded one in several sites suggesting the potential effects on sediment-dwelling organisms, which may constitute a risk to populations' health. However, seasonal variability of metal bioavailability was noted, revealing the best period to monitor metal contamination. From an ecotoxicological point of view, concentrations of Cd, Cr, Cu and Pb were above the effects range low threshold limit of the sediment quality guidelines for adverse biological effects. In addition, with Pb concentrations above the effect range medium values in some sites, biological effects may occur. Copyright © 2014 Elsevier Ltd. All rights reserved.

Sediment retention in a bottomland hardwood wetland in Eastern Arkansas

USGS Publications Warehouse

Kleiss, B.A.

1996-01-01

One of the often-stated functions of wetlands is their ability to remove sediments and other particulates from water, thus improving water quality in the adjacent aquatic system. However, actual rates of suspended sediment removal have rarely been measured in freshwater wetland systems. To address this issue, suspended sediment dynamics were measured in a 85-km2 bottomland hardwood (BLH) wetland adjacent to the highly turbid Cache River in eastern Arkansas during the 1988-1990 water years. A suspended sediment mass balance was calculated using depth-integrated, flow-weighted daily measurements at wetland inflow and outflow points. Over the three-year period, suspended sediment load decreased an average of 14% between upstream and downstream sampling points. To test the idea that the suspended sediments were retained by the adjacent wetland and to determine what portion of the BLH forest was most responsible for retaining the suspended sediments, concurrent measurements of sediment accretion were made at 30 sites in the wetland using feldspar clay marker horizons, sedimentation disks, the 137cesium method, and dendrogeomorphic techniques. Sedimentation rates exceeding 1 cm/yr were measured in frequently flooded areas dominated by Nyssa aquatica and Taxodium distichum. Maximum sedimentation rates did not occur on the natural levee, as would be predicted by classical fluvial geomorphology, but in the "first bottom," where retention time of the water reached a maximum. Multiple regression was used to relate sedimentation rates with several physical and biological factors. A combination of distance from the river, flood duration, and tree basal area accounted for nearly 90% of the variation in sedimentation rates.

Continuous real-time water-quality monitoring and regression analysis to compute constituent concentrations and loads in the North Fork Ninnescah River upstream from Cheney Reservoir, south-central Kansas, 1999–2012

USGS Publications Warehouse

Stone, Mandy L.; Graham, Jennifer L.; Gatotho, Jackline W.

2013-01-01

Cheney Reservoir, located in south-central Kansas, is the primary water supply for the city of Wichita. The U.S. Geological Survey has operated a continuous real-time water-quality monitoring station since 1998 on the North Fork Ninnescah River, the main source of inflow to Cheney Reservoir. Continuously measured water-quality physical properties include streamflow, specific conductance, pH, water temperature, dissolved oxygen, and turbidity. Discrete water-quality samples were collected during 1999 through 2009 and analyzed for sediment, nutrients, bacteria, and other water-quality constituents. Regression models were developed to establish relations between discretely sampled constituent concentrations and continuously measured physical properties to compute concentrations of those constituents of interest that are not easily measured in real time because of limitations in sensor technology and fiscal constraints. Regression models were published in 2006 that were based on data collected during 1997 through 2003. This report updates those models using discrete and continuous data collected during January 1999 through December 2009. Models also were developed for four new constituents, including additional nutrient species and indicator bacteria. In addition, a conversion factor of 0.68 was established to convert the Yellow Springs Instruments (YSI) model 6026 turbidity sensor measurements to the newer YSI model 6136 sensor at the North Ninnescah River upstream from Cheney Reservoir site. Newly developed models and 14 years of hourly continuously measured data were used to calculate selected constituent concentrations and loads during January 1999 through December 2012. The water-quality information in this report is important to the city of Wichita because it allows the concentrations of many potential pollutants of interest to Cheney Reservoir, including nutrients and sediment, to be estimated in real time and characterized over conditions and time scales that would not be possible otherwise. In general, model forms and the amount of variance explained by the models was similar between the original and updated models. The amount of variance explained by the updated models changed by 10 percent or less relative to the original models. Total nitrogen, nitrate, organic nitrogen, E. coli bacteria, and total organic carbon models were newly developed for this report. Additional data collection over a wider range of hydrological conditions facilitated the development of these models. The nitrate model is particularly important because it allows for comparison to Cheney Reservoir Task Force goals. Mean hourly computed total suspended solids concentration during 1999 through 2012 was 54 milligrams per liter (mg/L). The total suspended solids load during 1999 through 2012 was 174,031 tons. On an average annual basis, the Cheney Reservoir Task Force runoff (550 mg/L) and long-term (100 mg/L) total suspended solids goals were never exceeded, but the base flow goal was exceeded every year during 1999 through 2012. Mean hourly computed nitrate concentration was 1.08 mg/L during 1999 through 2012. The total nitrate load during 1999 through 2012 was 1,361 tons. On an annual average basis, the Cheney Reservoir Task Force runoff (6.60 mg/L) nitrate goal was never exceeded, the long-term goal (1.20 mg/L) was exceeded only in 2012, and the base flow goal of 0.25 mg/L was exceeded every year. Mean nitrate concentrations that were higher during base flow, rather than during runoff conditions, suggest that groundwater sources are the main contributors of nitrate to the North Fork Ninnescah River above Cheney Reservoir. Mean hourly computed phosphorus concentration was 0.14 mg/L during 1999 through 2012. The total phosphorus load during 1999 through 2012 was 328 tons. On an average annual basis, the Cheney Reservoir Task Force runoff goal of 0.40 mg/L for total phosphorus was exceeded in 2002, the year with the largest yearly mean turbidity, and the long-term goal (0.10 mg/L) was exceeded in every year except 2011 and 2012, the years with the smallest mean streamflows. The total phosphorus base flow goal of 0.05 mg/L was exceeded every year. Given that base flow goals for total suspended solids, nitrate, and total phosphorus were exceeded every year despite hydrologic conditions, the established base flow goals are either unattainable or substantially more best management practices will need to be implemented to attain them. On an annual average basis, no discernible patterns were evident in total suspended sediment, nitrate, and total phosphorus concentrations or loads over time, in large part because of hydrologic variability. However, more rigorous statistical analyses are required to evaluate temporal trends. A more rigorous analysis of temporal trends will allow evaluation of watershed investments in best management practices.

Shifting Gravel and the Acoustic Detection Range of Killer Whale Calls

NASA Astrophysics Data System (ADS)

Bassett, C.; Thomson, J. M.; Polagye, B. L.; Wood, J.

2012-12-01

In environments suitable for tidal energy development, strong currents result in large bed stresses that mobilize sediments, producing sediment-generated noise. Sediment-generated noise caused by mobilization events can exceed noise levels attributed to other ambient noise sources at frequencies related to the diameters of the mobilized grains. At a site in Admiralty Inlet, Puget Sound, Washington, one year of ambient noise data (0.02 - 30 kHz) and current velocity data are combined. Peak currents at the site exceed 3.5 m/s. During slack currents, vessel traffic is the dominant noise source. When currents exceed 0.85 m/s noise level increases between 2 kHz and 30 kHz are correlated with near-bed currents and bed stress estimates. Acoustic spectrum levels during strong currents exceed quiescent slack tide conditions by 20 dB or more between 2 and 30 kHz. These frequencies are consistent with sound generated by the mobilization of gravel and pebbles. To investigate the implications of sediment-generated noise for post-installation passive acoustic monitoring of a planned tidal energy project, ambient noise conditions during slack currents and strong currents are combined with the characteristics of Southern Resident killer whale (Orcinus orca) vocalizations and sound propagation modeling. The reduction in detection range is estimated for common vocalizations under different ambient noise conditions. The importance of sediment-generated noise for passive acoustic monitoring at tidal energy sites for different marine mammal functional hearing groups and other sediment compositions are considered.

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in and near Humboldt Wildlife Management Area, Churchill and Pershing Counties, Nevada, 1990-91

USGS Publications Warehouse

Seiler, R.L.; Ekechukwu, G.A.; Hallock, R.J.

1993-01-01

A reconnaissance investigation was begun in 1990 to determine whether the quality of irrigation drainage in and near the Humboldt Wildlife Management Area, Nevada, has caused or has the potential to cause harmful effects on human health, fish, and wildlife or to impair beneficial uses of water. Samples of surface and ground water, bottom sediment, and biota collected from sites upstream and downstream from the Lovelock agricultural area were analyzed for potentially toxic trace elements. Also analyzed were radioactive substances, major dissolved constitu- ents, and nutrients in water, as well as pesticide residues in bottom sediment and biota. In samples from areas affected by irrigation drainage, the following constituents equaled or exceeded baseline concentrations or recommended standards for protection of aquatic life or propagation of wildlife--in water: arsenic, boron, dissolved solids, mercury, molybdenum, selenium, sodium, and un-ionized ammonia; in bottom sediment; arsenic and uranium; and in biota; arsenic, boron, and selenium. Selenium appears to be biomagnified in the Humboldt Sink wetlands. Biological effects observed during the reconnaissance included reduced insect diversity in sites receiving irrigation drainage and acute toxicity of drain water and sediment to test organisms. The current drought and upstream consumption of water for irrigation have reduced water deliveries to the wetlands and caused habitat degradation at Humboldt Wildlife Management Area. During this investigation. Humboldt and Toulon Lakes evaporated to dryness because of the reduced water deliveries.

Heavy metals in waters and suspended sediments affected by a mine tailing spill in the upper San Lorenzo River, Northwestern México.

PubMed

Páez-Osuna, F; Bojórquez-Leyva, H; Bergés-Tiznado, M; Rubio-Hernández, O A; Fierro-Sañudo, J F; Ramírez-Rochín, J; León-Cañedo, J A

2015-05-01

Concentrations of arsenic (As), cadmium (Cd), copper (Cu), lead (Pb), mercury (Hg), silver (Ag) and zinc (Zn) were evaluated in water and suspended sediments of the upper waters of San Lorenzo River in NW Mexico following a mine tailing spill. Except As (6.64-35.9 µg L(-1)), dissolved metal concentrations were low (Ag <0.06-0.22; Cd 0.01-0.34; Cu 4.71-10.2; Hg 0.02-0.24; Pb <0.15-0.65; Zn 86-1,080 µg L(-1)) and were less than the upper limits established by UNEP (Water quality for ecosystem and human health, 2nd edn. United Nations Environment Programme Global Environment Monitoring System/Water Programme, Burlington, 2008), EPA (2014) and the Mexican regulation (NOM 1994). In contrast, the suspended metal concentrations were high (As 91.4-130; Ag 22.1-531; Cd 3.14-6.30; Cu 65-123; Hg 0.47-1.09; Pb 260-818; Zn 742-1,810 mg kg(-1)) and most of samples exceeded the probable effect level of the Canadian Sediment Quality Guidelines for the Protection of Aquatic Life.

Potential human health risks from metals and As via Odontesthes bonariensis consumption and ecological risk assessments in a eutrophic lake.

PubMed

Monferran, Magdalena V; Garnero, Paola Lorena; Wunderlin, Daniel A; Bistoni, María de los Angeles

2016-07-01

The concentration of Al, Cr, Fe, Mn, Ni, Cu, Zn, Hg, Sr, Mo, Ag, Cd, Pb and As was analyzed in water, sediment, and muscle of Odontesthes bonariensis from the eutrophic San Roque Lake (Córdoba-Argentina). The monitoring campaign was performed during the wet, dry and intermediate season. The concentration of Cr, Fe, Pb, Zn, Al and Cd in water exceeded the limits considered as hazardous for aquatic life. The highest metal concentrations were observed in sediment, intermediate concentrations, in fish muscle, and the lowest in water, with the exception of Cr, Zn, As and Hg, which were the highest in fish muscle. Potential ecological risk analysis of heavy metal concentrations in sediment indicated that the San Roque Lake posed a low ecological risk in all sampling periods. The target hazard quotients (THQs) and carcinogenic risk (CR) for individual metals showed that As in muscle was particularly hazardous, posing a potential risk for fishermen and the general population during all sampling periods. Hg poses a potential risk for fishermen only in the intermediate season. It is important to highlight that none of these two elements exceeded the limits considered as hazardous for aquatic life in water and sediment. This result proves the importance of performing measurements of contaminants, in both abiotic and biotic compartments, to assess the quality of food resources. These results suggest that the consumption of this fish species from this reservoir is not completely safe for human health. Copyright © 2016 Elsevier Inc. All rights reserved.

Hazardous metal pollution in a protected coastal area from Northern Patagonia (Argentina).

PubMed

Marinho, C H; Giarratano, E; Esteves, J L; Narvarte, M A; Gil, M N

2017-03-01

The San Antonio Bay is a protected natural coastal area of Argentina that has been exposed to mining wastes over the last three decades. Iron and trace metals of potential concern to biota and human health (Cd, Pb, Cu, and Zn) were investigated in the sediments from the bay and in the soils of the Pile (mining wastes). Concentrations of Cd (45 mg kg -1 ), Pb (42,853 mg kg -1 ), Cu (24,505 mg kg -1 ), and Zn (28,686 mg kg -1 ) in the soils Pile exceeded guidelines for agricultural, residential, and industrial land uses. Risk assessment due to exposure to contaminated soils (Pile) was performed. Hazard quotients were superior to non-risk (HQ >1) for all trace metals, while accumulative hazard quotient index indicated a high risk for children (HI = 93) and moderate for adults (HI = 9). In the bay, sediments closest to the Pile (mudflat and salt marsh) exceeded sediment quality guidelines for protection of biota. Results of different acid extraction methods suggest that most of the pseudototal content was potentially mobile. Principal component analysis indicated that the sites near the Pile (Encerrado channel) were more polluted than the distal ones. Tissues of Spartina spp. located within Encerrado channel showed the highest metal levels among all studied sites. These results show that the problem still persists and the mining wastes are the sources of the pollution. Furthermore, the Encerrado channel is a highly impacted area, as it is shown by their metal enriched sediments.

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico and Texas; organic compounds and trace elements in bed sediment and fish tissue, 1992-93

USGS Publications Warehouse

Carter, L.F.; Anderholm, S.K.

1997-01-01

The occurrence and distribution of contaminants in aquatic systems are major components of the National Water-Quality Assessment (NAWQA) Program. Bed-sediment samples were collected at 18 sites in the Rio Grande Valley study unit between September 1992 and March 1993 to characterize the geographic distribution of organic compounds, including chlorinated insecticides, polychlorinated biphenyls (PCB's), and other chlorinated hydrocarbons, and also trace elements. Two-millimeter-size- fraction sediment was analyzed for organic compounds and less than 63-micron-size-fraction sediment was analyzed for trace elements. Concentrations of p,p'-DDE were detected in 33 percent of the bed-sediment samples. With the exception of DDT-related compounds, no other organochlorine insecticides or polychlorinated biphenyls were detected in samples of bed sediment. Whole-body fish samples were collected at 11 of the bed- sediment sites and analyzed for organic compounds. Organic compounds were reported more frequently in samples of fish, and more types of organic compounds were found in whole-body fish samples than in bed-sediment samples. Concentrations of p,p'-DDE were detected in 91 percent of whole-body fish samples. Polychlorinated biphenyls, cis-chlordane, trans-chlordane, trans- nonachlor, and hexachlorobenzene were other organic compounds detected in whole-body samples of fish from at least one site. Because of the extent of mineralized areas in the Rio Grande Basin arsenic, cadmium, copper, lead, mercury, selenium, and zinc concentrations in bed-sediment samples could represent natural conditions at most sites. However, a combination of natural conditions and human activities appears to be associated with elevated trace-element concentrations in the bed-sediment sample from the site Rio Grande near Creede, Colorado, because this sample exceeded the background trace-element concentrations calculated for this study. Fish-liver samples were collected at 12 of the bed-sediment sites and analyzed for trace elements. Certain trace elements were detected at higher concentrations in fish-liver samples than in bed-sediment samples from the same site. Both bed-sediment and fish-tissue samples are necessary for a complete environmental assessment of the occurrence and distribution of trace elements.

Water-quality characteristics of Montana streams in a statewide monitoring network, 1999-2003

USGS Publications Warehouse

Lambing, John H.; Cleasby, Thomas E.

2006-01-01

A statewide monitoring network of 38 sites was operated during 1999-2003 in cooperation with the Montana Department of Environmental Quality to provide a broad geographic base of water-quality information on Montana streams. The purpose of this report is to summarize and describe the water-quality characteristics for those sites. Samples were collected at U.S. Geological Survey streamflow-gaging stations in the Missouri, Yellowstone, and Columbia River basins for stream properties, nutrients, suspended sediment, major ions, and selected trace elements. Mean annual streamflows were below normal during the period, which likely influenced water quality. Continuous water-temperature monitors were operated at 26 sites. The median of daily mean water temperatures for the June-August summer period ranged from 12.5 degC at Kootenai River below Libby Dam to 23.0 degC at Poplar River near Poplar and Tongue River at Miles City. In general, sites in the Missouri River basin commonly had the highest water temperatures. Median daily mean summer water temperatures at four sites (Jefferson River near Three Forks, Missouri River at Toston, Judith River near Winifred, and Poplar River near Poplar) classified as supporting or marginally supporting cold-water biota exceeded the general guideline of 19.4 degC for cold-water biota. Median daily mean temperatures at sites in the network classified as supporting warm-water biota did not exceed the guideline of 26.7 degC for warm-water biota, although several sites exceeded the warm-water guideline on several days during the summer. More...

Predicting dredging-associated effects to coral reefs in Apra Harbor, Guam - Part 2: Potential coral effects.

PubMed

Nelson, Deborah Shafer; McManus, John; Richmond, Robert H; King, David B; Gailani, Joe Z; Lackey, Tahirih C; Bryant, Duncan

2016-03-01

Coral reefs are in decline worldwide due to anthropogenic stressors including reductions in water and substratum quality. Dredging results in the mobilization of sediments, which can stress and kill corals via increasing turbidity, tissue damage and burial. The Particle Tracking Model (PTM) was applied to predict the potential impacts of dredging-associated sediment exposure on the coral reef ecosystems of Apra Harbor, Guam. The data were interpreted using maps of bathymetry and coral abundance and distribution in conjunction with impact parameters of suspended sediment concentration (turbidity) and sedimentation using defined coral response thresholds. The results are presented using a "stoplight" model of negligible or limited impacts to coral reefs (green), moderate stress from which some corals would be expected to recover while others would not (yellow) and severe stress resulting in mortality (red). The red conditions for sediment deposition rate and suspended sediment concentration (SSC) were defined as values exceeding 25 mg cm(-2) d(-1) over any 30 day window and >20 mg/l for any 18 days in any 90 day period over a column of water greater than 2 m, respectively. The yellow conditions were defined as values >10 mg cm(-2) d(-1) and <25 mg cm(-2) d(-1) over any 30 day period, and as 20% of 3 months' concentration exceeding 10 mg/l for the deposition and SSC, respectively. The model also incorporates the potential for cumulative effects on the assumption that even sub-lethal stress levels can ultimately lead to mortality in a multi-stressor system. This modeling approach can be applied by resource managers and regulatory agencies to support management decisions related to planning, site selection, damage reduction, and compensatory mitigation. Published by Elsevier Ltd.

Habitat quality of historic Snake River fall Chinook salmon spawning locations and implications for incubation survival: part 1, substrate quality

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hanrahan, Timothy P.; Geist, David R.; Arntzen, Evan V.

2005-07-01

We evaluated substrate quality at two historic fall Chinook salmon (Oncorhynchus tshawytscha) spawning sites in the Snake River, Idaho, USA. The primary objective of this evaluation was to measure sediment permeability within these areas to determine the potential quality of the habitat in the event that anadromous salmonids are reintroduced to the upper Snake River. Riverbed sediments within the two sites in the upper Snake River were sampled using freeze cores and hydraulic slug tests. Sediment grain size distributions at both sites were typical of gravel-bed rivers with the surface layer coarser than the underlying substrate, suggesting the riverbed surfacemore » was armored. Despite the armored nature of the bed, the size of the largest material present on the riverbed surface was well within the size limit of material capable of being excavated by spawning fall Chinook salmon. The percentage of fines was low, suggesting good quality substrate for incubating salmon embryos. Geometric mean particle sizes found in this study compared to a 55% to 80% survival to emergence based on literature values. Hydraulic slug tests showed moderate to high hydraulic conductivity and were comparable to values from current fall Chinook salmon spawning areas in the Hells Canyon Reach of the Snake River and the Hanford Reach of the Columbia River. Predicted estimates of mean egg survival at both sites (48% and 74%) equaled or exceeded estimates from fall Chinook salmon spawning areas in the Hells Canyon Reach and the Hanford Reach.« less

The checkered puffer (Spheroides testudineus) and its helminths as bioindicators of chemical pollution in Yucatan coastal lagoons.

PubMed

Pech, Daniel; Vidal-Martínez, Víctor M; Aguirre-Macedo, M Leopoldina; Gold-Bouchot, Gerardo; Herrera-Silveira, Jorge; Zapata-Pérez, Omar; Marcogliese, David J

2009-03-15

The suitability of using helminth communities as bioindicators of environmental quality of the Yucatan coastal lagoons status was tested on the checkered puffer (Spheroides testudineus) in four coastal lagoons along the Yucatan coast. The concentration of chemical pollutants in sediments, water quality parameters, helminth infracommunity characteristics, as well as fish physiological biomarkers, including EROD (7-ethoxyresorufin-O-deethylase) and catalase activities, were measured. Results from sediment analyses demonstrated the presence of hydrocarbons, organochlorine pesticides and polychlorinated biphenyls at varying concentrations, some of which exceeded the Probability Effect Level (PEL). Significant negative associations among organochlorine pesticides, infracommunity characteristics and fish physiological responses were observed in most of the lagoons. Results suggest that EROD activity and parasite infracommunity characteristics could be useful tools to evaluate the effects of chemical pollutants on the fish host and in the environment. Importantly, certain parasites appear to influence biomarker measurements, indicating that parasites should be considered in ecotoxicological studies.

Organic compounds and trace elements in fish tissue and bed sediment from streams in the Yellowstone River basin, Montana and Wyoming, 1998

USGS Publications Warehouse

Peterson, David A.; Boughton, Gregory K.

2000-01-01

A comprehensive water-quality investigation of the Yellowstone River Basin began in 1997, under the National Water-Quality Assessment (NAWQA) Program. Twenty-four sampling sites were selected for sampling of fish tissue and bed sediment during 1998. Organic compounds analyzed included organochlorine insecticides and their metabolites and total polychlorinated biphenyls (PCBs) from fish-tissue and bed-sediment samples, and semivolatile organic compounds from bed-sediment samples. A broad suite of trace elements was analyzed from both fish-tissue and bed-sediment samples, and a special study related to mercury also was conducted. Of the 12 organochlorine insecticides and metabolites detected in the fish-tissue samples, the most compounds per site were detected in samples from integrator sites which represent a mixture of land uses. The presence of DDT, and its metabolites DDD and DDE, in fish collected in the Yellowstone Park area likely reflects long-term residual effects from historical DDT-spraying programs for spruce budworm. Dieldrin, chlordane, and other organic compounds also were detected in the fish-tissue samples. The compound p, p'-DDE was detected at 71 percent of the sampling sites, more than any other compound. The concentrations of total DDT in fish samples were low, however, compared to concentrations from historical data from the study area, other NAWQA studies in the Rocky Mountains, and national baseline concentrations. Only 2 of the 27 organochlorine insecticides and metabolites and total PCBs analyzed in bed sediment were detected. Given that 12 of the compounds were detected in fish-tissue samples, fish appeared to be more sensitive indicators of contamination than bed sediment.Concentrations of some trace elements in fish and bed sediment were higher at sites in mineralized areas than at other sites. Concentrations of selenium in fish tissue from some sites were above background levels. Concentrations of arsenic, chromium, copper, and lead in some of the bed-sediment samples potentially exceeded criteria for the protection of aquatic life.

Laboratory performance in the Sediment Laboratory Quality-Assurance Project, 1996-98

USGS Publications Warehouse

Gordon, John D.; Newland, Carla A.; Gagliardi, Shane T.

2000-01-01

Analytical results from all sediment quality-control samples are compiled and statistically summarized by the USGS, Branch of Quality Systems, both on an intra- and interlaboratory basis. When evaluating these data, the reader needs to keep in mind that every measurement has an error component associated with it. It is premature to use the data from the first five SLQA studies to judge any of the laboratories as performing in an unacceptable manner. There were, however, some notable differences in the results for the 12 laboratories that participated in the five SLQA studies. For example, the overall median percent difference for suspended-sediment concentration on an individual laboratory basis ranged from –18.04 to –0.33 percent. Five of the 12 laboratories had an overall median percent difference for suspended-sediment concentration of –2.02 to –0.33 percent. There was less variability in the median difference for the measured fine-size material mass. The overall median percent difference for fine-size material mass ranged from –10.11 to –4.27 percent. Except for one laboratory, the median difference for fine-size material mass was within a fairly narrow range of –6.76 to –4.27 percent. The median percent difference for sand-size material mass differed among laboratories more than any other physical sediment property measured in the study. The overall median percent difference for the sand-size material mass ranged from –1.49 percent to 26.39 percent. Five of the nine laboratories that do sand/fine separations had overall median percent differences that ranged from –1.49 to 2.98 percent for sand-size material mass. Careful review of the data reveals that certain laboratories consistently produced data within statistical control limits for some or all of the physical sediment properties measured in this study, whereas other laboratories occasionally produced data that exceeded the control limits.

Anthropogenic waste indicators (AWIs), particularly PAHs and LABs, in Malaysian sediments: Application of aquatic environment for identifying anthropogenic pollution.

PubMed

Masood, Najat; Zakaria, Mohamad Pauzi; Halimoon, Normala; Aris, Ahmad Zaharin; Magam, Sami M; Kannan, Narayanan; Mustafa, Shuhaimi; Ali, Masni Mohd; Keshavarzifard, Mehrzad; Vaezzadeh, Vahab; Alkhadher, Sadeq Abdullah Abdo; Al-Odaini, Najat Ahmed

2016-01-15

Polycyclic aromatic hydrocarbons (PAHs) and linear alkylbenzenes (LABs) were used as anthropogenic markers of organic chemical pollution of sediments in the Selangor River, Peninsular Malaysia. This study was conducted on sediment samples from the beginning of the estuary to the upstream river during dry and rainy seasons. The concentrations of ƩPAHs and ƩLABs ranged from 203 to 964 and from 23 to 113 ng g(-1) dry weight (dw), respectively. In particular, the Selangor River was found to have higher sedimentary levels of PAHs and LABs during the wet season than in the dry season, which was primarily associated with the intensity of domestic wastewater discharge and high amounts of urban runoff washing the pollutants from the surrounding area. The concentrations of the toxic contaminants were determined according to the Sediment Quality Guidelines (SQGs). The PAH levels in the Selangor River did not exceed the SQGs, for example, the effects range low (ERL) value, indicating that they cannot exert adverse biological effects. Copyright © 2015 Elsevier Ltd. All rights reserved.

Levels and sources of heavy metals and PAHs in sediment of Djibouti-city (Republic of Djibouti).

PubMed

Mahdi Ahmed, Moussa; Doumenq, Pierre; Awaleh, Mohamed Osman; Syakti, Agung Dhamar; Asia, Laurence; Chiron, Serge

2017-07-15

Selected heavy metals and polycyclic aromatic hydrocarbons (PAHs) were determined in marine sediment from 28 sites Djibouti city. The concentrations of trace elements varied from 0 to 288.1mg/kg with relative abundance of trace metals in sediments was in the order of Zn>Cu>Ni>Cr>Co>Pb>Cd. Zn, Cu and Ni exceeded consensus based sediment quality guideline values 7, 14, 15 sites respectively. Enrichment factor and pollution load index showed relatively low to moderate contamination. The concentrations of total 16 PAHs varied widely depending on the sample location and ranged from 2.65 to 3760.11ng·g -1 , with the mean concentration value of 387.87ng·g -1 . Compositions and relative abundance of individual PAH using molecular diagnostic ratio using congener's m/z 178 and 202 indicated pyrolytic origin and reflecting a petroleum combustion, grass/wood and coal combustion and a petrogenic source. This study represents the first pollution baseline and a reference for future studies in Djibouti. Copyright © 2017 Elsevier Ltd. All rights reserved.

Enrichment and geo-accumulation of heavy metals and risk assessment of sediments of the Kurang Nallah--feeding tributary of the Rawal Lake Reservoir, Pakistan.

PubMed

Zahra, Azmat; Hashmi, Muhammad Zaffar; Malik, Riffat Naseem; Ahmed, Zulkifl

2014-02-01

Heavy metal concentrations in sediments of the Kurang stream: a principal feeding tributary of the Rawal Lake Reservoir were investigated using enrichment factor (EF), geoaccumulation index (Igeo) and metal pollution index (MPI) to determine metal accumulation, distribution and its pollution status. Sediment samples were collected from twenty one sites during two year monitoring in pre- and post-monsoon seasons (2007-2008). Heavy metal toxicity risk was assessed using Sediment Quality Guidelines (SQGs), effect range low/effect range median values (ERL/ERM), and threshold effect level/probable effect level (TEL/PEL). Greater mean concentrations of Ni, Mn and Pb were recorded in post-monsoon season whereas metal accumulation pattern in pre-monsoon season followed the order: Zn>Mn>Ni>Cr>Co>Cd>Pb>Cu>Li. Enrichment factor (EF) and geoaccumulation (Igeo) values showed that sediments were loaded with Cd, Zn, Ni and Mn. Comparison with uncontaminated background values showed higher concentrations of Cd, Zn and Ni than respective average shale values. Concentrations of Ni and Zn were above ERL values; however, Ni concentration exceeded the ERM values. Sediment contamination was attributed to anthropogenic and natural processes. The results can be used for effective management of fresh water hilly streams of Pakistan. © 2013.

Characterization of groundwater resources in the Trinity and Woodbine aquifers in Texas.

PubMed

Chaudhuri, Sriroop; Ale, Srinivasulu

2013-05-01

A vast region in north-central Texas, centering on Dallas-Fort Worth metroplex, suffers from intense groundwater drawdown and water quality degradation, which led to inclusion of 18 counties of this region into Priority Groundwater Management Areas. We combined aquifer-based and county-based hydrologic analyses to (1) assess spatio-temporal changes in groundwater level and quality between 1960 and 2010 in the Trinity and Woodbine aquifers underlying the study region, (2) delve into major hydrochemical facies with reference to aquifer hydrostratigraphy, and (3) identify county-based spatial zones to aid in future groundwater management initiatives. Water-level and quality data was obtained from the Texas Water Development Board (TWDB) and analyzed on a decadal scale. Progressive water-level decline was the major concern in the Trinity aquifer with >50% of observations occurring at depths >100 m since the 1980s, an observation becoming apparent only in the 2000s in the Woodbine aquifer. Water quality degradation was the major issue in the Woodbine aquifer with substantially higher percentage of observations exceeding the secondary maximum contaminant levels (SMCL; a non-enforceable threshold set by the United State Environmental Protection Agency (USEPA)) and/or maximum contaminant level (MCL, a legally enforceable drinking water standard set by the USEPA) for sulfate (SO4(2-)), chloride (Cl(-)), and fluoride (F(-)) in each decade. In both aquifers, however, >70% of observations exceeded the SMCL for total dissolved solids indicating high groundwater salinization. Water-level changes in Trinity aquifer also had significant negative impact on water quality. Hydrochemical facies in this region sequentially evolved from Ca-Mg-HCO3 and Ca-HCO3 in the fluvial sediments of the west to Na-SO4-Cl in the deltaic sediments to the east. Sequentially evolving hydrogeochemical facies and increasing salinization closely resembled regional groundwater flow pattern. Distinct spatial zones based on homogenous hydrologic characteristics have become increasingly apparent over time indicating necessity of zone-specific groundwater management strategies. Copyright © 2013 Elsevier B.V. All rights reserved.

The chemical response of particle-associated contaminants in aquatic sediments to urbanization in New England, U.S.A.

NASA Astrophysics Data System (ADS)

Chalmers, A. T.; Van Metre, P. C.; Callender, E.

2007-04-01

Relations between urbanization and particle-associated contaminants in New England were evaluated using a combination of samples from sediment cores, streambed sediments, and suspended stream sediments. Concentrations of PAHs, PCBs, DDT, and seven trace metals (Cd, Cr, Cu, Hg, Ni, Pb, Zn) were correlated strongly with urbanization, with the strongest relations to percentage commercial, industrial, and transportation (CIT) land use. Average PAH and metal concentrations in the most urbanized watersheds were approximately 30 and 6 times the reference concentrations, respectively, in remote, undeveloped watersheds. One-quarter to one-half of sampling sites had concentrations of PAHs, Cu, Pb, or Zn above the probable effects concentration, a set of sediment quality guidelines for adverse effects to aquatic biota, and sediments were predicted to be toxic, on average, when CIT land use exceeded about 10%. Trends in metals in cores from urban watersheds were dominantly downward, whereas trends in PAHs in a suburban watershed were upward. A regional atmospheric-fallout gradient was indicated by as much as order-of-magnitude-greater concentrations and accumulation rates of contaminants in cores from an undeveloped reference lake in Boston compared to those from remote reference watersheds. Contaminant accumulation rates in the lakes with urbanization in their watersheds, however, were 1-3 orders of magnitude greater than those of reference lakes, which indicate the dominance of local sources and fluvial transport of contaminants to urban lakes. These analyses demonstrate the magnitude of urban contamination of aquatic systems and air sheds, and suggest that, despite reductions in contaminant emissions in urban settings, streams and lakes will decline in quality as urbanization of their watersheds takes place.

A model for assessing water quality risk in catchments prone to wildfire

NASA Astrophysics Data System (ADS)

Langhans, Christoph; Smith, Hugh; Chong, Derek; Nyman, Petter; Lane, Patrick; Sheridan, Gary

2017-04-01

Post-fire debris flows can have erosion rates up to three orders of magnitude higher than background rates. They are major sources of fine suspended sediment, which is critical to the safety of water supply from forested catchments. Fire can cover parts or all of these large catchments and burn severity is often heterogeneous. The probability of spatial and temporal overlap of fire disturbance and rainfall events, and the susceptibility of hillslopes to severe erosion determine the risk to water quality. Here we present a model to calculate recurrence intervals of high magnitude sediment delivery from runoff-generated debris flows to a reservoir in a large catchment (>100 km2) accounting for heterogeneous burn conditions. Debris flow initiation was modelled with indicators of surface runoff and soil surface erodibility. Debris flow volume was calculated with an empirical model, and fine sediment delivery was calculated using simple, expert-based assumptions. In a Monte-Carlo simulation, wildfire was modelled with a fire spread model using historic data on weather and ignition probabilities for a forested catchment in central Victoria, Australia. Multiple high intensity storms covering the study catchment were simulated using Intensity-Frequency-Duration relationships, and the runoff indicator calculated with a runoff model for hillslopes. A sensitivity analysis showed that fine sediment is most sensitive to variables related to the texture of the source material, debris flow volume estimation, and the proportion of fine sediment transported to the reservoir. As a measure of indirect validation, denudation rates of 4.6 - 28.5 mm ka-1 were estimated and compared well to other studies in the region. From the results it was extrapolated that in the absence of fire management intervention the critical sediment concentrations in the studied reservoir could be exceeded in intervals of 18 - 124 years.

The chemical response of particle-associated contaminants in aquatic sediments to urbanization in New England, U.S.A.

USGS Publications Warehouse

Chalmers, A.T.; Van Metre, P.C.; Callender, E.

2007-01-01

Relations between urbanization and particle-associated contaminants in New England were evaluated using a combination of samples from sediment cores, streambed sediments, and suspended stream sediments. Concentrations of PAHs, PCBs, DDT, and seven trace metals (Cd, Cr, Cu, Hg, Ni, Pb, Zn) were correlated strongly with urbanization, with the strongest relations to percentage commercial, industrial, and transportation (CIT) land use. Average PAH and metal concentrations in the most urbanized watersheds were approximately 30 and 6 times the reference concentrations, respectively, in remote, undeveloped watersheds. One-quarter to one-half of sampling sites had concentrations of PAHs, Cu, Pb, or Zn above the probable effects concentration, a set of sediment quality guidelines for adverse effects to aquatic biota, and sediments were predicted to be toxic, on average, when CIT land use exceeded about 10%. Trends in metals in cores from urban watersheds were dominantly downward, whereas trends in PAHs in a suburban watershed were upward. A regional atmospheric-fallout gradient was indicated by as much as order-of-magnitude-greater concentrations and accumulation rates of contaminants in cores from an undeveloped reference lake in Boston compared to those from remote reference watersheds. Contaminant accumulation rates in the lakes with urbanization in their watersheds, however, were 1-3 orders of magnitude greater than those of reference lakes, which indicate the dominance of local sources and fluvial transport of contaminants to urban lakes. These analyses demonstrate the magnitude of urban contamination of aquatic systems and air sheds, and suggest that, despite reductions in contaminant emissions in urban settings, streams and lakes will decline in quality as urbanization of their watersheds takes place. ?? 2006 Elsevier B.V. All rights reserved.

Trace elements and organic compounds in sediment and fish tissue from the Great Salt Lake basins, Utah, Idaho, and Wyoming, 1998-99

USGS Publications Warehouse

Waddell, Kidd M.; Giddings, Elise M.

2004-01-01

A study to determine the occurrence and distribution of trace elements, organochlorine pesticides, polychlorinated biphenyls (PCBs), and semivolatile organic compounds in sediment and in fish tissue was conducted in the Great Salt Lake Basins study unit of the National Water-Quality Assessment (NAWQA) program during 1998-99. Streambed-sediment and fish-tissue samples were collected concurrently at 11 sites and analyzed for trace-element concentration. An additional four sites were sampled for streambed sediment only and one site for fish tissue only. Organic compounds were analyzed from streambed-sediment and fish-tissue samples at 15 sites concurrently.Bed-sediment cores from lakes, reservoirs, and Farmington Bay collected by the NAWQA program in 1998 and by other researchers in 1982 were used to examine historical trends in trace-element concentration and to determine anthropogenic sources of contaminants. Cores collected in 1982 from Mirror Lake, a high-mountain reference location, showed an enrichment of arsenic, cadmium, copper, lead, tin, and zinc in the surface sediments relative to the deeper sediments, indicating that enrichment likely began after about 1900. This enrichment was attributed to atmospheric deposition during the period of metal-ore mining and smelting. A core from Echo Reservoir, in the Weber River Basin, however, showed a different pattern of trace-element concentration that was attributed to a local source. This site is located downstream from the Park City mining district, which is the most likely historical source of trace elements. Cores collected in 1998 from Farmington Bay show that the concentration of lead began to increase after 1842 and peaked during the mid-1980s and has been in decline since. Recent sediments deposited during 1996-98 indicate a 41- to 62-percent reduction since the peak in the mid-1980s.The concentration of trace elements in streambed sediment was greatest at sites that have been affected by historic mining, including sites on Little Cottonwood Creek in the Jordan River basin, Silver Creek in the Weber River basin, and the Weber River below the confluence with Silver Creek. There was significant correlation of lead concentrations in streambed sediment and fish tissue, but other trace elements did not correlate well. Streambed sediment and fish tissue collected from sites in the Bear River basin, which is predominantly rangeland and agriculture, generally had low concentrations of most elements.Sediment-quality guidelines were used to assess the relative toxicity of streambed-sediment sites to aquatic communities. Sites affected by mining exceeded the Probable Effect Concentration (PEC), the concentration at which it is likely there will be a negative effect on the aquatic community, for arsenic, cadmium, copper, lead, silver, mercury, and zinc. Sites that were not affected by mining did not exceed these criteria. Concentrations of trace elements in samples collected from the Great Salt Lake Basins study unit (GRSL) are high compared to those of samples collected nationally with the NAWQA program. Nine of 15 streambed-sediment samples and 11 of 14 fish-tissue samples had concentrations of at least one trace element greater than the concentration of 90 percent of the samples collected nationally during 1993-2000.Organic compounds that were examined in streambed sediment and fish-tissue samples also were examined in bed-sediment cores. A bed-sediment core from Farmington Bay of Great Salt Lake showed an increase in total polycyclic aromatic hydrocarbon (PAH) concentrations coincident with the increase in population in Salt Lake Valley, which drains into this bay. Analysis of streambed-sediment samples showed that the highest concentrations of PAHs were detected at urban sites, including two sites in the lower Jordan River (the Jordan River flows into Farmington Bay), the Weber River at Ogden Bay, and the Provo River near Provo. Other organic compounds detected in streambed sediment in the lower Jordan River were PCBs, DDT compounds, and chlordane compounds.Organic compounds were detected more frequently in fish tissue than in streambed sediment. Chlordane compounds and PCBs were detected more frequently at urban sites. DDT compounds were detected at 13 of 15 sites including urban and agricultural sites. Concentrations of total DDT in fish tissue exceeded the guideline for protection of fish-eating wildlife at two urban sites. The concentration of organic compounds in the GRSL study unit is low compared with that of samples collected nationally.

Global Assessment of Bisphenol A in the Environment

PubMed Central

Corrales, Jone; Kristofco, Lauren A.; Steele, W. Baylor; Yates, Brian S.; Breed, Christopher S.; Williams, E. Spencer

2015-01-01

Because bisphenol A (BPA) is a high production volume chemical, we examined over 500 peer-reviewed studies to understand its global distribution in effluent discharges, surface waters, sewage sludge, biosolids, sediments, soils, air, wildlife, and humans. Bisphenol A was largely reported from urban ecosystems in Asia, Europe, and North America; unfortunately, information was lacking from large geographic areas, megacities, and developing countries. When sufficient data were available, probabilistic hazard assessments were performed to understand global environmental quality concerns. Exceedances of Canadian Predicted No Effect Concentrations for aquatic life were >50% for effluents in Asia, Europe, and North America but as high as 80% for surface water reports from Asia. Similarly, maximum concentrations of BPA in sediments from Asia were higher than Europe. Concentrations of BPA in wildlife, mostly for fish, ranged from 0.2 to 13 000 ng/g. We observed 60% and 40% exceedences of median levels by the US Centers for Disease Control and Prevention’s National Health and Nutrition Examination Survey in Europe and Asia, respectively. These findings highlight the utility of coordinating global sensing of environmental contaminants efforts through integration of environmental monitoring and specimen banking to identify regions for implementation of more robust environmental assessment and management programs. PMID:26674671

Distribution of Cu, Co, As, and Fe in mine waste, sediment, soil, and water in and around mineral deposits and mines of the Idaho Cobalt Belt, USA

USGS Publications Warehouse

Gray, John E.; Eppinger, Robert G.

2012-01-01

The distribution of Cu, Co, As and Fe was studied downstream from mines and deposits in the Idaho Cobalt Belt (ICB), the largest Co resource in the USA. To evaluate potential contamination in ecosystems in the ICB, mine waste, stream sediment, soil, and water were collected and analyzed for Cu, Co, As and Fe in this area. Concentrations of Cu in mine waste and stream sediment collected proximal to mines in the ICB ranged from 390 to 19,000 μg/g, exceeding the USEPA target clean-up level and the probable effect concentration (PEC) for Cu of 149 μg/g in sediment; PEC is the concentration above which harmful effects are likely in sediment dwelling organisms. In addition concentrations of Cu in mine runoff and stream water collected proximal to mines were highly elevated in the ICB and exceeded the USEPA chronic criterion for aquatic organisms of 6.3 μg/L (at a water hardness of 50 mg/L) and an LC50 concentration for rainbow trout of 14 μg/L for Cu in water. Concentrations of Co in mine waste and stream sediment collected proximal to mines varied from 14 to 7400 μg/g and were highly elevated above regional background concentrations, and generally exceeded the USEPA target clean-up level of 80 μg/g for Co in sediment. Concentrations of Co in water were as high as in 75,000 μg/L in the ICB, exceeding an LC50 of 346 μg/L for rainbow trout for Co in water by as much as two orders of magnitude, likely indicating an adverse effect on trout. Mine waste and stream sediment collected in the ICB also contained highly elevated As concentrations that varied from 26 to 17,000 μg/g, most of which exceeded the PEC of 33 μg/g and the USEPA target clean-up level of 35 μg/g for As in sediment. Conversely, most water samples had As concentrations that were below the 150 μg/L chronic criterion for protection of aquatic organisms and the USEPA target clean-up level of 14 μg/L. There is abundant Fe oxide in streams in the ICB and several samples of mine runoff and stream water exceeded the chronic criterion for protection of aquatic organisms of 1000 μg/L for Fe. There has been extensive remediation of mined areas in the ICB, but because some mine waste remaining in the area contains highly elevated Cu, Co, As and Fe, inhalation or ingestion of mine waste particulates may lead to human exposure to these elements.

Monitoring urban impacts on suspended sediment, trace element, and nutrient fluxes within the City of Atlanta, Georgia, USA: Program design, methodological considerations, and initial results

USGS Publications Warehouse

Horowitz, A.J.; Elrick, K.A.; Smith, J.J.

2008-01-01

Atlanta, Georgia (City of Atlanta, COA), is one of the most rapidly growing urban areas in the US. Beginning in 2003, the US Geological Survey established a long-term water-quantity/quality monitoring network for the COA. The results obtained during the first 2 years have provided insights into the requirements needed to determine the extent of urban impacts on water quality, especially in terms of estimating the annual fluxes of suspended sediment, trace/major elements, and nutrients. During 2004/2005, suspended sediment fluxes from the City of Atlanta (COA) amounted to about 150 000 t year-1; ??? 94% of the transport occurred in conjunction with storm-flow, which also accounted for ??? 65% of the annual discharge. Typically, storm-flow averaged ??? 20% of theyear. Normally, annual suspended sediment fluxes are determined by summing daily loads based on a single calculation step using mean-daily discharge and a single rating curve-derived suspended sediment concentration. Due to the small and 'flashy' nature of the COAs streams, this approach could produce underestimates ranging from 25% to 64%. Accurate estimates (?? 15%) require calculation time-steps as short as every 2-3 h. Based on annual median base-flow/storm-flow chemical concentrations, the annual fluxes of ??? 75% of trace elements (e.g. Cu, Pb, Zn), major elements (e.g. Fe, Al), and total P occur in association with suspended sediment; in turn, ??? 90% of the transport of these constituents occur in conjunction with storm-flow. As such, base-flow sediment-associated and dissolved contributions represent relatively insignificant portions of the total annual load. An exception is total N, whose sediment-associated fluxes range from 50% to 60%; even so, storm-related transport typically exceeds 80%. Hence, in urban environments, non-point-source appear to be the dominant contributors to the fluxes of these constituents.

Spatial Variability of Metals in Surface Water and Sediment in the Langat River and Geochemical Factors That Influence Their Water-Sediment Interactions

PubMed Central

Lim, Wan Ying; Aris, Ahmad Zaharin; Zakaria, Mohamad Pauzi

2012-01-01

This paper determines the controlling factors that influence the metals' behavior water-sediment interaction facies and distribution of elemental content (75As, 111Cd, 59Co, 52Cr, 60Ni, and 208Pb) in water and sediment samples in order to assess the metal pollution status in the Langat River. A total of 90 water and sediment samples were collected simultaneously in triplicate at 30 sampling stations. Selected metals were analyzed using ICP-MS, and the metals' concentration varied among stations. Metal concentrations of water ranged between 0.08–24.71 μg/L for As, <0.01–0.53 μg/L for Cd, 0.06–6.22 μg/L for Co, 0.32–4.67 μg/L for Cr, 0.80–24.72 μg/L for Ni, and <0.005–6.99 μg/L for Pb. Meanwhile, for sediment, it ranged between 4.47–30.04 mg/kg for As, 0.02–0.18 mg/kg for Cd, 0.87–4.66 mg/kg for Co, 4.31–29.04 mg/kg for Cr, 2.33–8.25 mg/kg for Ni and 5.57–55.71 mg/kg for Pb. The average concentration of studied metals in the water was lower than the Malaysian National Standard for Drinking Water Quality proposed by the Ministry of Health. The average concentration for As in sediment was exceeding ISQG standards as proposed by the Canadian Sediment Quality Guidelines. Statistical analyses revealed that certain metals (As, Co, Ni, and Pb) were generally influenced by pH and conductivity. These results are important when making crucial decisions in determining potential hazardous levels of these metals toward humans. PMID:22919346

Heavy metals in soils and sediments from Dongting Lake in China: occurrence, sources, and spatial distribution by multivariate statistical analysis.

PubMed

Zhang, Yaxin; Tian, Ye; Shen, Maocai; Zeng, Guangming

2018-05-01

Heavy metal contamination in soils/sediments and its impact on human health and ecological environment have aroused wide concerns. Our study investigated 30 samples of soils and sediments around Dongting Lake to analyze the concentration of As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn in the samples and to distinguish the natural and anthropogenic sources. Also, the relationship between heavy metals and the physicochemical properties of samples was studied by multivariate statistical analysis. Concentration of Cd at most sampling sites were more than five times that of national environmental quality standard for soil in China (GB 15618-1995), and Pb and Zn levels exceeded one to two times. Moreover, Cr in the soil was higher than the national environmental quality standards for one to two times while in sediment was lower than the national standard. The investigation revealed that the accumulations of As, Cd, Mn, and Pb in the soils, and sediments were affected apparently by anthropogenic activities; however, Cr, Fe, and Ni levels were impacted by parent materials. Human activities around Dongting Lake mainly consisted of industrial activities, mining and smelting, sewage discharges, fossil fuel combustion, and agricultural chemicals. The spatial distribution of heavy metal in soil followed the rule of geographical gradient, whereas in sediments, it was significantly affected by the river basins and human activities. The result of principal component analysis (PCA) demonstrated that heavy metals in soils were associated with pH and total phosphorus (TP), while in sediments, As, Cr, Fe, and Ni were closely associated with cation exchange capacity (CEC) and pH, where Pb, Zn, and Cd were associated with total nitrogen (TN), TP, total carbon (TC), moisture content (MC), soil organic matter (SOM), and ignition lost (IL). Our research provides comprehensive approaches to better understand the potential sources and the fate of contaminants in lakeshore soils and sediments.

Weak acid extractable metals in Bramble Bay, Queensland, Australia: temporal behaviour, enrichment and source apportionment.

PubMed

Brady, James P; Ayoko, Godwin A; Martens, Wayde N; Goonetilleke, Ashantha

2015-02-15

Sediment samples were taken from six sampling sites in Bramble Bay, Queensland, Australia between February and November in 2012. They were analysed for a range of heavy metals including Al, Fe, Mn, Ti, Ce, Th, U, V, Cr, Co, Ni, Cu, Zn, As, Cd, Sb, Te, Hg, Tl and Pb. Fraction analysis, Enrichment Factors and Principal Component Analysis-Absolute Principal Component Scores (PCA-APCS) were carried out in order to assess metal pollution, potential bioavailability and source apportionment. Cr and Ni exceeded the Australian Interim Sediment Quality Guidelines at some sampling sites, while Hg was found to be the most enriched metal. Fraction analysis identified increased weak acid soluble Hg and Cd during the sampling period. Source apportionment via PCA-APCS found four sources of metals pollution, namely, marine sediments, shipping, antifouling coatings and a mixed source. These sources need to be considered in any metal pollution control measure within Bramble Bay. Copyright © 2014 Elsevier Ltd. All rights reserved.

Water quality of least-impaired lakes in eastern and southern Arkansas.

PubMed

Justus, Billy

2010-09-01

A three-phased study identified one least-impaired (reference) lake for each of four Arkansas lake classifications: three classifications in the Mississippi Alluvial Plain (MAP) ecoregion and a fourth classification in the South Central Plains (SCP) ecoregion. Water quality at three of the least-impaired lakes generally was comparable and also was comparable to water quality from Kansas and Missouri reference lakes and Texas least-impaired lakes. Water quality of one least-impaired lake in the MAP ecoregion was not as good as water quality in other least-impaired lakes in Arkansas or in the three other states: a probable consequence of all lakes in that classification having a designated use as a source of irrigation water. Chemical and physical conditions for all four lake classifications were at times naturally harsh as limnological characteristics changed temporally. As a consequence of allochthonous organic material, oxbow lakes isolated within watersheds comprised of swamps were susceptible to low dissolved oxygen concentrations to the extent that conditions would be limiting to some aquatic biota. Also, pH in lakes in the SCP ecoregion was <6.0, a level exceeding current Arkansas water-quality standards but typical of black water systems. Water quality of the deepest lakes exceeded that of shallow lakes. N/P ratios and trophic state indices may be less effective for assessing water quality for shallow lakes (<2 m) than for deep lakes because there is an increased exposure of sediment (and associated phosphorus) to disturbance and light in the former.

Surface-water-quality assessment of the upper Illinois River Basin in Illinois, Indiana, and Wisconsin; results of investigations through April 1992

USGS Publications Warehouse

Schmidt, Arthur R.; Blanchard, Stephen F.

1997-01-01

A water-quality assessment of the upper Illinois River Basin (10,949 square miles) was conducted during water years 1987-91. This assessment involved interpretation of available data; 4 years of intensive data collection, including monthly sample collection at eight fixed-monitoring stations in the basin; and synoptic studies of selected water-quality constituents at many sites. The number of exceedances of water-quality criteria for chromium, copper, lead, mercury, silver, and zinc in water was essentially the same at similar stations between 1978-86 and 1987-90. For water and sediment, a large signature for many trace inorganic constituents was observed from the Chicago metropolitan area, mainly from the Des Plaines River Basin and continuing down the Illinois River. Loads of trace inorganic constituents in water were 2-13 times greater from the Chicago metropolitan area than from rural areas in the upper Illinois River Basin. Concentrations of cadmium, mercury, nickel, selenium, and zinc appeared to be relatively enriched in biota in the upper Illinois River Basin compared to other river basins. Biota from some urban sites were enriched with respect to several elements. For example, relatively large concentrations of cadmium, chromium, copper, lead, and nickel were observed in biota from sites in the Chicago River in the metropolitan area and the Calumet River. Results of pesticide sampling in 1988 and 1989 identified the pesticides bromacil, diazinon, malathion, prometon, and simazine as urban related and alachlor, atrazine, cyanazine, metolachlor, and metribuzin as agricultural related. Phenol concentrations never exceeded general-use and secondary-contact water-quality standards of 100 and 300 micrograms per liter, respectively. Pentachlorophenol concentrations observed at the Illinois River at Marseilles, Ill., between 1981 and 1992 decreased beginning in 1987. A breakdown product of the organochlorine pesticide dichloro-diphenyl-trichloroethane (DDT), p,p'-DDE was the most commonly detected organic compound in biota in both 1989 and 1990. In the nine fish-fillet samples collected in 1989, exceedances of U.S. Environmental Protection Agency (USEPA) fish tissue concentrations were noted for p,p'-DDE in all nine fillets and for dieldrin in five of the nine fillets. Nutrient concentrations in water in the study area generally were larger than concentrations typically found in natural waters. The Des Plaines River Basin contributed approximately 41 percent of the total nitrogen load to the upper Illinois River Basin, whereas the Kankakee River and Iroquois River Basins contributed about 34 and 14 percent of the total load, respectively. Dissolved-oxygen concentrations measured during a 1988 synoptic sampling exceeded State water-quality standards at 76 percent of the sampled sites. Bacteria densities greater than water-quality standards were observed at all of the fixed-monitoring stations, but densities greater than water-quality criteria and standards were observed more often at stations in the Des Plaines River Basin. Results from the analysis of changes in water quality following changes in wastewater-treatment practices indicated that current monitoring programs, although sufficient for their intended purposes, are not suitable for this type of retrospective assessment in large-scale water-quality assessments. Changes were not indicated in fish-community structure and population following changes in wastewater-treatment practices. A strong relation between the quality of the fish community and overall water-quality conditions was observed, although USEPA acute criteria for the protection of freshwater aquatic life were rarely exceeded. Analyses of fish-community data clearly showed that water quality in the urbanized parts of the study area were degraded relative to those in agricultural areas. Total chromium in streambed sediments and total recoverable sodium in water were highly correlated

Sediment concentration and turbidity changes during culvert removals

Treesearch

Randy B. Foltz; Kristina A. Yanosek; Timothy M. Brown

2008-01-01

The concentrations of sediment and turbidity in stream water were monitored during culvert removals to determine the short term effects of road obliteration. Sediment concentration was measured at 11 stream crossings among two locations in Idaho and one in Washington. Sediment concentration immediately below the culvert outlet exceeded levels above the culvert outlet...

Erosion, sedimentation, and cumulative effects in the Northern Rocky Mountains

Treesearch

Walter F. Megahan; John G. King

2004-01-01

Erosion and sedimentation are natural geomorphic processes characterized by large temporal and spatial variability. Recent radionuclide studies suggest that rare episodic events, such as large wildfires, produce massive sediment yields over time scales of thousands of years, thereby causing long-term average sediment production to exceed present-day average erosion...

Sedimentation History of Halfway Creek Marsh, Upper Mississippi River National Wildlife and Fish Refuge, Wisconsin, 1846-2006

USGS Publications Warehouse

Fitzpatrick, Faith A.; Knox, James C.; Schubauer-Berigan, Joseph P.

2007-01-01

The history of overbank sedimentation in the vicinity of Halfway Creek Marsh near La Crosse, Wis., was examined during 2005?06 by the U.S. Geological Survey and University of Wisconsin?Madison as part of a broader study of sediment and nutrient loadings to the Upper Mississippi River bottomlands by the U.S. Environmental Protection Agency, U.S. Fish and Wildlife Service, and U.S. Geological Survey. Historical sedimentation patterns and rates were interpreted from field-scale topographic surveys and sediment cores collected from the marsh and upstream flood plains. Historical maps and aerial photographs were used to establish the timing of disturbances and to document changes in channel patterns after Euro-American settlement (post 1846). Episodic overbank sedimentation patterns and rates were linked to watershed agricultural activity, large floods, artificial levee construction, channel alterations, and dam failures over the past 160 years. These forces affected sedimentation on and between levees, the development of alluvial fans and flood-plain splays, and the general pattern of flood-plain sedimentation through the upper and lower marsh. Historical overbank deposits, episodically deposited after about 1860, are as much as 6 feet thick in the upper marsh and as much as 4 feet thick in the lower marsh, representing a total volume of approximately 1.8 million cubic yards. These stratified deposits consist of multiple layers of silt and clay, very fine to fine sand, and some medium to very coarse sand. Coarse-grained deposits are associated with flood-plain splays caused by breaches in artificial levees during large floods. Estimated sedimentation rates were highest from 1919 to 1936 [26,890 cubic yards per year (yd3/yr)] and exceeded by about 30 times the 1846?85 rate of 920 yd3/yr and exceeded by 7 times the 1994?2006 rate of 3,740 yd3/yr. The 1994?2006 sedimentation rate was the lowest since Euro-American settlement, but natural levees along the 1994?2006 channel of Halfway Creek through the lower marsh continued to form and are currently (2006) about 1 foot higher than the surrounding marsh. Natural levee building in the lower marsh from 1994?2006 was accentuated by the lack of overbank sediment storage in the upper marsh. The historical storage of sediment in the upper and lower marsh affects modern streamflow and sediment transport processes of Halfway Creek and Sand Lake Coulee through the marsh, and it also affects marsh vegetation and wildlife habitat. Results from this investigation will help improve the understanding of how past overbank sedimentation patterns continue to influence modern and future water quality, sediment transport, nutrient loads, and water-related resources in riparian habitats common to the Upper Mississippi River National Wildlife and Fish Refuge.

Bacteria in beach sands: an emerging challenge in protecting coastal water quality and bather health

PubMed Central

Gast, Rebecca J.

2011-01-01

To protect bather health at recreational beaches, fecal indicator bacterial standards are used to monitor water quality, and waters exceeding the standards are subsequently closed to bathers. However beachgoers are also in contact with beach sands, the sanitary quality of which is not included within beach monitoring programs. In fact, sands and sediments provide habitat where fecal bacterial populations may persist, and in some cases grow, in the coastal zone. Specific pathogens are less well studied in beach sands and sediments, but there is a body of evidence that they too may persist in these environments. This paper reviews the current state of knowledge regarding the abundance and distribution of fecal indicator bacteria and pathogens in beach sands of diverse climatological regions, and at beaches subjected to varied levels of anthropogenic impact. In all regions fecal indicator bacteria are nearly ubiquitous in beach sands, and similar relationships emerge between fecal indicator abundance in dry sand, submerged sands, and water. Taken together, these studies contextualize a potential public health issue and identify research questions that must be addressed in order to support future policy decisions. PMID:21162561

Study of copper (Cu) contents in blood cockles (Anadara sp.) at Surabaya coastal waters

NASA Astrophysics Data System (ADS)

Alfionita, S.; Pursetyo, K. T.; Sahidu, A. M.

2018-04-01

Heavy metal pollution categorized as harmful effect on the environment. This study aims to determine the content and the rate of accumulation of heavy metals copper (Cu) in the mussel of cockles (Anadara sp.) This study uses observation method with descriptive analysis. The test results Cu in sea water was <0.0223 mg/L. The results have exceeded the water quality standard according to state environmental ministerial decree number 51 2004 on marine water quality standards for marine biota maximum limit of Cu in sea water is 0.008 mg/L. Copper concentration in the sediment of 6.16 mg/kg at the Wonokromo station and at the Dadapan station is 4.03 mg/kg. According to the US-EPA in 2004 on the instructions of sediment pollution classification 49.98 mg Cu/kg. The results of shells fur Cu on Wonokromo was 1.833 mg/kg and Dadapan was 1.352 mg/kg. According to the MOH Decree No.0375/B/SK/1989 about Quality Standard Biota Consumption of Metals to the maximum limit of the existing Cu concentrations in marine biota was 20 ppm or 20 mg / kg so that the content of Cu in shellfish feathers still below the limit of existing quality standards.

Micro-spatial variation of elemental distribution in estuarine sediment and their accumulation in mangroves of Indian Sundarban.

PubMed

Bakshi, Madhurima; Ram, S S; Ghosh, Somdeep; Chakraborty, Anindita; Sudarshan, M; Chaudhuri, Punarbasu

2017-05-01

This work describes the micro-spatial variation of elemental distribution in estuarine sediment and bioaccumulation of those elements in different mangrove species of the Indian Sundarbans. The potential ecological risk due to such elemental load on this mangrove-dominated habitat is also discussed. The concentrations of elements in mangrove leaves and sediments were determined using energy-dispersive X-ray fluorescence spectroscopy. Sediment quality and potential ecological risks were assessed from the calculated indices. Our data reflects higher concentration of elements, e.g., Al, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, and Pb, in the sediment, as compared to that reported by earlier workers. Biological concentration factors for K, Ca, Mn, Fe, Cu, and Zn in different mangroves indicated gradual elemental bioaccumulation in leaf tissues (0.002-1.442). Significant variation was observed for elements, e.g., Ni, Mn, and Ca, in the sediments of all the sites, whereas in the plants, significant variation was found for P, S, Cl, K, Ca, Mn, Fe, Cu, and Zn. This was mostly due to the differences in uptake and accumulation potential of the plants. Various sediment quality indices suggested the surface sediments to be moderately contaminated and suffering from progressive deterioration. Cu, Cr, Zn, Mn, and Ni showed higher enrichment factors (0.658-1.469), contamination factors (1.02-2.7), and geo-accumulation index (0.043-0.846) values. The potential ecological risk index values considering Cu, Cr, Pb, and Zn were found to be within "low ecological risk" category (20.04-24.01). However, Cr and Ni in the Sundarban mangroves exceeded the effect range low and probable effect level limits. Strong correlation of Zn with Fe and K was observed, reflecting their similar transportation and accumulation process in both sediment and plant systems. The plant-sediment elemental correlation was found to be highly non-linear, suggesting role of some physiological and edaphic factors in the accumulation process. Overall, the study of micro-spatial distribution of elements can act as a useful tool for determining health of estuarine ecosystem.

The role of precipitation type, intensity, and spatial distribution in source water quality after wildfire

NASA Astrophysics Data System (ADS)

Murphy, Sheila F.; Writer, Jeffrey H.; Blaine McCleskey, R.; Martin, Deborah A.

2015-08-01

Storms following wildfires are known to impair drinking water supplies in the southwestern United States, yet our understanding of the role of precipitation in post-wildfire water quality is far from complete. We quantitatively assessed water-quality impacts of different hydrologic events in the Colorado Front Range and found that for a three-year period, substantial hydrologic and geochemical responses downstream of a burned area were primarily driven by convective storms with a 30 min rainfall intensity >10 mm h-1. These storms, which typically occur several times each year in July-September, are often small in area, short-lived, and highly variable in intensity and geographic distribution. Thus, a rain gage network with high temporal resolution and spatial density, together with high-resolution stream sampling, are required to adequately characterize post-wildfire responses. We measured total suspended sediment, dissolved organic carbon (DOC), nitrate, and manganese concentrations that were 10-156 times higher downstream of a burned area compared to upstream during relatively common (50% annual exceedance probability) rainstorms, and water quality was sufficiently impaired to pose water-treatment concerns. Short-term water-quality impairment was driven primarily by increased surface runoff during higher intensity convective storms that caused erosion in the burned area and transport of sediment and chemical constituents to streams. Annual sediment yields downstream of the burned area were controlled by storm events and subsequent remobilization, whereas DOC yields were closely linked to annual runoff and thus were more dependent on interannual variation in spring runoff. Nitrate yields were highest in the third year post-wildfire. Results from this study quantitatively demonstrate that water quality can be altered for several years after wildfire. Because the southwestern US is prone to wildfires and high-intensity rain storms, the role of storms in post-wildfire water-quality impacts must be considered when assessing water-quality vulnerability.

The role of precipitation type, intensity, and spatial distribution in source water quality after wildfire

USGS Publications Warehouse

Murphy, Sheila F.; Writer, Jeffrey H.; McCleskey, R. Blaine; Martin, Deborah A.

2015-01-01

Storms following wildfires are known to impair drinking water supplies in the southwestern United States, yet our understanding of the role of precipitation in post-wildfire water quality is far from complete. We quantitatively assessed water-quality impacts of different hydrologic events in the Colorado Front Range and found that for a three-year period, substantial hydrologic and geochemical responses downstream of a burned area were primarily driven by convective storms with a 30 min rainfall intensity >10 mm h−1. These storms, which typically occur several times each year in July–September, are often small in area, short-lived, and highly variable in intensity and geographic distribution. Thus, a rain gage network with high temporal resolution and spatial density, together with high-resolution stream sampling, are required to adequately characterize post-wildfire responses. We measured total suspended sediment, dissolved organic carbon (DOC), nitrate, and manganese concentrations that were 10–156 times higher downstream of a burned area compared to upstream during relatively common (50% annual exceedance probability) rainstorms, and water quality was sufficiently impaired to pose water-treatment concerns. Short-term water-quality impairment was driven primarily by increased surface runoff during higher intensity convective storms that caused erosion in the burned area and transport of sediment and chemical constituents to streams. Annual sediment yields downstream of the burned area were controlled by storm events and subsequent remobilization, whereas DOC yields were closely linked to annual runoff and thus were more dependent on interannual variation in spring runoff. Nitrate yields were highest in the third year post-wildfire. Results from this study quantitatively demonstrate that water quality can be altered for several years after wildfire. Because the southwestern US is prone to wildfires and high-intensity rain storms, the role of storms in post-wildfire water-quality impacts must be considered when assessing water-quality vulnerability.

Sediment storage and severity of contamination in a shallow reservoir affected by historical lead and zinc mining

USGS Publications Warehouse

Juracek, K.E.

2008-01-01

A combination of sediment-thickness measurement and bottom-sediment coring was used to investigate sediment storage and severity of contamination in Empire Lake (Kansas), a shallow reservoir affected by historical Pb and Zn mining. Cd, Pb, and Zn concentrations in the contaminated bottom sediment typically exceeded baseline concentrations by at least an order of magnitude. Moreover, the concentrations of Cd, Pb, and Zn typically far exceeded probable-effects guidelines, which represent the concentrations above which toxic biological effects usually or frequently occur. Despite a pre-1954 decrease in sediment concentrations likely related to the end of major mining activity upstream by about 1920, concentrations have remained relatively stable and persistently greater than the probable-effects guidelines for at least the last 50 years. Cesium-137 evidence from sediment cores indicated that most of the bottom sediment in the reservoir was deposited prior to 1954. Thus, the ability of the reservoir to store the contaminated sediment has declined over time. Because of the limited storage capacity, Empire Lake likely is a net source of contaminated sediment during high-inflow periods. The contaminated sediment that passes through, or originates from, Empire Lake will be deposited in downstream environments likely as far as Grand Lake O' the Cherokees (Oklahoma). ?? 2007 Springer-Verlag.

Sediment concentration and turbidity changes during culvert removals.

PubMed

Foltz, Randy B; Yanosek, Kristina A; Brown, Timothy M

2008-05-01

The concentrations of sediment and turbidity in stream water were monitored during culvert removals to determine the short term effects of road obliteration. Sediment concentration was measured at 11 stream crossings among two locations in Idaho and one in Washington. Sediment concentration immediately below the culvert outlet exceeded levels above the culvert outlet by at least three orders of magnitude at all stream crossings. Sediment yields ranged from 170 to less than 1kg in the 24-h period following culvert removal. Turbidity exceeded the regulatory limits during culvert removal at all locations monitored in this study and remained above the limits beyond the monitoring periods of 24h at four of the locations. Sediment concentrations 100m downstream of the culvert outlet were reduced by an order of magnitude, but did not change the turbidity values sufficiently to meet regulatory limits. Sediment concentrations an average of 810m downstream of the culvert outlet were similar to sediment concentrations above the culvert for the entire excavation period and turbidity regulations were met. Mitigation consisting of two straw bales placed in the stream caused a significant reduction in sediment yield from an average of 67kg to an average of 1.6kg.

Widespread legacy brine contamination from oil production reduces survival of chorus frog larvae

USGS Publications Warehouse

Hossack, Blake R.; Puglis, Holly J.; Battaglin, William A.; Anderson, Chauncey; Honeycutt, Richard; Smalling, Kelly

2017-01-01

Advances in drilling techniques have facilitated a rapid increase in hydrocarbon extraction from energy shales, including the Williston Basin in central North America. This area overlaps with the Prairie Pothole Region, a region densely populated with wetlands that provide numerous ecosystem services. Historical (legacy) disposal practices often released saline co-produced waters (brines) with high chloride concentrations, affecting wetland water quality directly or persisting in sediments. Despite the potential threat of brine contamination to aquatic habitats, there has been little research into its ecological effects. We capitalized on a gradient of legacy brine-contaminated wetlands in northeast Montana to conduct laboratory experiments to assess variation in survival of larval Boreal Chorus Frogs (Pseudacris maculata) reared on sediments from 3 local wetlands and a control source. To help provide environmental context for the experiment, we also measured chloride concentrations in 6 brine-contaminated wetlands in our study area, including the 2 contaminated sites used for sediment exposures. Survival of frog larvae during 46- and 55-day experiments differed by up to 88% among sediment sources (Site Model) and was negatively correlated with potential chloride exposure (Chloride Model). Five of the 6 contaminated wetlands exceeded the U.S. EPA acute benchmark for chloride in freshwater (860 mg/L) and all exceeded the chronic benchmark (230 mg/L). However, the Wetland Site model explained more variation in survival than the Chloride Model, suggesting that chloride concentration alone does not fully reflect the threat of contamination to aquatic species. Because the profiles of brine-contaminated sediments are complex, further surveys and experiments are needed across a broad range of conditions, especially where restoration or remediation actions have reduced brine-contamination. Information provided by this study can help quantify potential ecological threats and help land managers prioritize conservation strategies as part of responsible and sustainable energy development.

Characterization of Stormflows and Wastewater Treatment-Plant Effluent Discharges on Water Quality, Suspended Sediment, and Stream Morphology for Fountain and Monument Creek Watersheds, Colorado, 1981-2006

USGS Publications Warehouse

Mau, David P.; Stogner, Sr., Robert W.; Edelmann, Patrick

2007-01-01

In 1998, the U.S. Geological Survey, in cooperation with Colorado Springs City Engineering, began a study of the Fountain and Monument Creek watersheds to characterize water quality and suspended-sediment conditions in the watershed for different flow regimes, with an emphasis on characterizing water quality during storm runoff. Water-quality and suspended-sediment samples were collected in the Fountain and Monument Creek watersheds from 1981 through 2006 to evaluate the effects of stormflows and wastewater-treatment effluent on Fountain and Monument Creeks in the Colorado Springs, Colorado, area. Water-quality data were collected at 11 sites between 1981 and 2001, and 14 tributary sites were added in 2003 to increase spatial coverage and characterize water quality throughout the watersheds. Suspended-sediment samples collected daily at 7 sites from 1998 through 2001, 6 sites daily from 2003 through 2006, and 13 tributary sites intermittently from 2003 through 2006 were used to evaluate the effects of stormflow on suspended-sediment concentrations, discharges, and yields. Data were separated into three flow regimes: base flow, normal flow, and stormflow. Stormflow concentrations from 1998 through 2006 were compared to Colorado acute instream standards and, with the exception of a few isolated cases, did not exceed water-quality standards for inorganic constituents that were analyzed. However, stormflow concentrations of both fecal coliform and Escherichia coli (E. coli) frequently exceeded water-quality standards during 1998 through 2006 on main-stem and tributary sites by more than an order of magnitude. There were two sites on Cottonwood Creek, a tributary to Monument Creek, with elevated concentrations of dissolved nitrite plus nitrate: site 07103985 (TbCr), a tributary to Cottonwood Creek and site 07103990 (lower_CoCr), downstream from site 07103985 (TbCr), and near the confluence with Monument Creek. During base-flow and normal-flow conditions, the median concentrations of dissolved nitrite plus nitrate ranged from 5.1 to 6.1 mg/L and were 4 to 7 times larger than concentrations at the nearest upstream site on Monument Creek, site 07103970 (MoCr_Woodmen). The source of these larger dissolved nitrite plus nitrate concentrations has not been identified, but the fact that all measurements had elevated dissolved nitrite plus nitrate concentrations indicates a relatively constant source. Most stormflow concentrations of dissolved trace elements were smaller than concentrations from base-flow or normal-flow samples. However, median concentrations of total arsenic, copper, lead, manganese, nickel, and zinc generally were much larger during periods of stormflow than during base flow or normal flow. Concentrations of dissolved and total copper, total manganese, total nickel, dissolved and total selenium, and dissolved and total zinc ranged from 3 to 27 times larger at site 07103707 (FoCr_8th) than site 07103700 (FoCr_Manitou) during base flow, indicating a large source of trace elements between these two sites. Both of these sites are located on Fountain Creek, upstream from the confluence with Monument Creek. The likely source area is Gold Hill Mesa, a former tailings pile for a gold refinery located just upstream from the confluence with Monument Creek, and upstream from site 07103707 (FoCr_8th). Farther downstream in Fountain Creek, stormflow samples for total copper, manganese, lead, nickel, and zinc were larger at the downstream site near the city of Security, site 07105800 (FoCr_Security), than at the upstream site near Janitell Road, site 07105530 (FoCr_Janitell), compared with other main-stem sites and indicated a relatively large source of these metals between the two sites. Nitrogen, phosphorus, and trace-element loads substantially increased during stormflow. Suspended-sediment concentrations, discharges, and yields associated with stormflow were significantly larger than those associated with normal flow. The Apr

Degree of contamination and sources of polychlorinated biphenyls in Meandering Road Creek and Woods Inlet of Lake Worth, Fort Worth, Texas, 2004 and 2006-07

USGS Publications Warehouse

Braun, Christopher L.; Wilson, Jennifer T.; Van Metre, Peter C.

2008-01-01

Lake Worth is a reservoir on the West Fork Trinity River on the western edge of Fort Worth, Texas. Air Force Plant 4 (AFP4) is on the eastern shore of Woods Inlet, an arm of Lake Worth that extends south from the main body of the lake. Two previous reports documented ele-vated polychlorinated biphenyl (PCB) concentrations in surficial sediment in Woods Inlet relative to those in surficial sediment in other parts of Lake Worth. This report presents the results of another USGS study, done in cooperation with the U.S. Air Force, to indicate the degree of PCB contamination of Meandering Road Creek and Woods Inlet and to identify possible sources of PCBs in Meandering Road Creek and Woods Inlet on the basis of suspended, streambed, and lake-bottom sediment samples collected there in 2004 and 2006-07. About 40 to 80 percent of total PCB concentrations (depending on how total PCB concentration is computed) in suspended sediment exceed the threshold effect concentration, a concentration below which adverse effects to benthic biota rarely occur. About 20 percent of total PCB concentrations (computed as sum of three Aroclors) in suspended sediment exceed the probable effect concentration, a concentration above which adverse effects to benthic biota are expected to occur frequently. About 20 to 30 percent of total PCB concentrations in streambed sediment exceed the threshold effect concentration; and about 6 to 20 percent of total PCB concentrations in lake-bottom (Woods Inlet) sediment exceed the threshold effect concentration. No streambed or lake-bottom sediment concentrations exceed the probable effect concentration. The sources of PCBs to Meandering Road Creek and Woods Inlet were investigated by comparing the relative distributions of PCB congeners of suspended sediment to those of streambed and lake-bottom sediment. The sources of PCBs were identified using graphical analysis of normalized concentrations (congener ratios) of 11 congeners. For graphical analysis, the sampling sites were divided into three groups with each group associated with one of the three outfalls sampled: SSO, OF4, and OF5. The variations of normalized PCB congener concentrations from Woods Inlet, from outfalls along Meandering Road Creek, and from streambed sediment sampling sites along Meandering Road Creek generally form similar patterns within sample groups, which is indicative of a common source of PCBs to each group. Overall, the variations in congener ratios indicate that PCBs in surficial lake-bottom sediment of Woods Inlet probably entered Woods Inlet primarily from Meandering Road Creek, and that runoff from AFP4 is a prominent source of PCBs in Meandering Road Creek. Sixteen of the 20 box core sites in Woods Inlet had lower PCB concentrations in the 2006 cores compared to those in the 2003 cores.

Anthropogenic effects on sedimentary facies in Lake Baldeney, West Germany

NASA Astrophysics Data System (ADS)

Neumann-Mahlkau, Peter; Niehaus, Heinz Theo

1983-12-01

Analysis of well logs of Lake Baldeney, a reservoir of the Ruhr River, yields four facies factors that reflect the effect of anthropogenic processes on the sediment. First, the sedimentation rate is directly related to the subsidence caused by mining. The extent of the subsidence was such that the sediment load of the river could not compensate for the sinking of the lake bottom. Discharged sediment filled about one-fifth of the basin within 40 years. In certain areas of the basin the sedimentation rate reached up to 10 cm per year. Second, the grain-size distribution of the sediment was influenced by long-term and short-term events. During the subsidence, grain-size distribution remained relatively constant. The destruction of the Möhne River dam during World War II resulted in the presence of an extremely large grain size as evidenced by the so-called Möhnelage. The filling of the lake after 1961 was accompanied by a continual increase in medium grain size. Third, until 1975, the mode of the lake sediment reflects the effect of mining in the vicinity of the lake. High coal content can be traced to its origin. The introduction of modern production processes, modernization of coal dressing, and hydraulic hauling is documented in the sediment. Finally, the heavy metal content of the sediment corresponds to the industrial development in the drainage area the Ruhr River. The accumulation of Cd reached an extreme concentration, exceeding the natural content by a thousand times. Variation in concentration reflects an increase in industrial production, as well as measures undertaken to restore water quality.

Subsurface sediment contamination during borehole drilling with an air-actuated down-hole hammer.

PubMed

Malard, Florian; Datry, Thibault; Gibert, Janine

2005-10-01

Drilling methods can severely alter physical, chemical, and biological properties of aquifers, thereby influencing the reliability of water samples collected from groundwater monitoring wells. Because of their fast drilling rate, air-actuated hammers are increasingly used for the installation of groundwater monitoring wells in unconsolidated sediments. However, oil entrained in the air stream to lubricate the hammer-actuating device can contaminate subsurface sediments. Concentrations of total hydrocarbons, heavy metals (Cu, Ni, Cr, Zn, Pb, and Cd), and nutrients (particulate organic carbon, nitrogen, and phosphorus) were measured in continuous sediment cores recovered during the completion of a 26-m deep borehole drilled with a down-hole hammer in glaciofluvial deposits. Total hydrocarbons, Cu, Ni, Cr and particulate organic carbon (POC) were all measured at concentrations far exceeding background levels in most sediment cores. Hydrocarbon concentration averaged 124 +/- 118 mg kg(-1) dry sediment (n = 78 samples) with peaks at depths of 8, 14, and 20 m below the soil surface (maximum concentration: 606 mg kg(-1)). The concentrations of hydrocarbons, Cu, Ni, Cr, and POC were positively correlated and exhibited a highly irregular vertical pattern, that probably reflected variations in air loss within glaciofluvial deposits during drilling. Because the penetration of contaminated air into the formation is unpreventable, the representativeness of groundwater samples collected may be questioned. It is concluded that air percussion drilling has strong limitations for well installation in groundwater quality monitoring surveys.

Effect of salinity on heavy metal mobility and availability in intertidal sediments of the Scheldt estuary

NASA Astrophysics Data System (ADS)

Du Laing, G.; De Vos, R.; Vandecasteele, B.; Lesage, E.; Tack, F. M. G.; Verloo, M. G.

2008-05-01

The effect of the flood water salinity on the mobility of heavy metals was studied for intertidal sediments of the Scheldt estuary (Belgium). Soils and sediments of 4 sampling sites were flooded with water of different salinities (0.5, 2.5, and 5 g NaCl L -1). Metal concentrations were monitored in pore water and surface water. To study the potential effects of flood water salinity on metal bioavailability, duckweed ( Lemna minor) was grown in the surface water. The salinity was found to primarily enhance the mobility of Cd and its uptake by duckweed. Cadmium concentrations in pore water of soils and sediments and surrounding surface waters significantly exceeded sanitation thresholds and quality standards during flooding of initially oxidized sediments. Moreover, the effect was observed already at lower salinities of 0.5 g NaCl L -1. This implies that risks related to Cd uptake by organisms and Cd leaching to ground water are relevant when constructing flooding areas in the brackish zones of estuaries. These risks can be reduced by inducing sulphide precipitation because Cd is then immobilised as sulphide and its mobility becomes independent of flood water salinity. This could be achieved by permanently flooding the polluted sediments, because sulphates are sufficiently available in the river water of the brackish part of the estuary.

History of metal contamination in Lake Illawarra, NSW, Australia.

PubMed

Schneider, Larissa; Maher, William; Potts, Jaimie; Batley, Graeme; Taylor, Anne; Krikowa, Frank; Chariton, Anthony; Zawadzki, Atun; Heijnis, Henk; Gruber, Bernd

2015-01-01

Lake Illawarra has a long history of sediment contamination, particularly by metals, as a result of past and current industrial operations and land uses within the catchment. In this study, we examined the history of metal contamination in sediments using metal analysis and (210)Pb and (137)Cs dating. The distributions of copper, zinc, arsenic, selenium, cadmium and lead concentrations within sediment cores were in agreement with historical events in the lake, and indicated that metal contamination had been occurring since the start of industrial activities in Port Kembla in the late 1800 s. Most metal contamination, however, has occurred since the 1960s. Sedimentation rates were found to be 0.2 cm year(-1) in Griffins Bay and 0.3 cm year(-1) in the centre of the lake. Inputs from creeks bringing metals from Port Kembla in the northeast of the lake and a copper slag emplacement from a former copper refinery on the Windang Peninsula were the main sources of metal inputs to Lake Illawarra. The metals of highest concern were zinc and copper, which exceeded the Australian and New Zealand sediment quality guideline values at some sites. Results showed that while historical contamination persists, current management practices have resulted in reduced metal concentrations in surface sediments in the depositional zones in the centre of the lake. Copyright © 2014 Elsevier Ltd. All rights reserved.

Individual and cumulative effects of agriculture, forestry and metal mining activities on the metal and phosphorus content of fluvial fine-grained sediment; Quesnel River Basin, British Columbia, Canada.

PubMed

Smith, Tyler B; Owens, Philip N

2014-10-15

The impact of agriculture, forestry and metal mining on the quality of fine-grained sediment (<63 μm) was investigated in the Quesnel River Basin (QRB) (~11,500 km(2)) in British Columbia, Canada. Samples of fine-grained sediment were collected monthly during the snow-free season in 2008 using time-integrated samplers at replicate sites representative of agriculture, forestry and mining activities in the basin (i.e. "impacted" sites). Samples were also collected from replicate reference sites and also from the main stem of the Quesnel River at the downstream confluence with the Fraser River. Generally, metal(loid) and phosphorus (P) concentrations for "impacted" sites were greater than for reference sites. Furthermore, concentrations of copper (forestry and mining sites), manganese (agriculture and forestry sites) and selenium (agriculture, forestry and mining sites) exceeded upper sediment quality guideline (SQG) thresholds. These results suggest that agriculture, forestry and metal mining activities are having an influence on the concentrations of sediment-associated metal(loid)s and P in the Quesnel basin. Metal(loid) and P concentrations of sediment collected from the downstream site were not significantly greater than values for the reference sites, and were typically lower than the values for the impacted sites. This suggests that the cumulative effects of agriculture, forestry and mining activities in the QRB are presently not having a measureable effect at the river basin-scale. The lack of a cumulative effect at the basin-scale is thought to reflect: (i) the relatively recent occurrence of land use disturbances in this basin; (ii) the dominance of sediment contributions from natural forest and agriculture; and (iii) the potential for storage of contaminants on floodplains and other storage elements between the locations of disturbance activities and the downstream sampling site, which may be attenuating the disturbance signal. Copyright © 2014 Elsevier B.V. All rights reserved.

Water quality and hydrology of the Silver River Watershed, Baraga County, Michigan, 2005-08

USGS Publications Warehouse

Weaver, Thomas L.; Sullivan, Daniel J.; Rachol, Cynthia M.; Ellis, James M.

2010-01-01

The Silver River Watershed comprises about 69 square miles and drains part of northeastern Baraga County, Michigan. For generations, tribal members of the Keweenaw Bay Indian Community have hunted and fished in the watershed. Tribal government and members of Keweenaw Bay Indian Community are concerned about the effect of any development within the watershed, which is rural, isolated, and lightly populated. For decades, the area has been explored for various minerals. Since 2004, several mineral-exploration firms have been actively investigating areas within the watershed; property acquisition, road construction, and subsurface drilling have taken place close to tributary streams of the Silver River. The U.S. Geological Survey, in cooperation with Keweenaw Bay Indian Community, conducted a multi-year water-resources investigation of the Silver River Watershed during 2005-08. Methods of investigation included analyses of streamflow, water-quality sampling, and ecology at eight discrete sites located throughout the watershed. In addition, three continuous-record streamgages located within the watershed provided stage, discharge, specific conductance, and water-temperature data on an hourly basis. Water quality of the Silver River Watershed is typical of many streams in undeveloped areas of Upper Michigan. Concentrations of most analytes typically were low, although several exceeded applicable surface-water-quality standards. Seven samples had concentrations of copper that exceeded the Michigan Department of Environmental Quality standards for wildlife, and one sample had concentrations of cyanide that exceeded the same standards. Concentrations of total mercury at all eight sampling sites exceeded the Great Lakes Basin water-quality standard, but the ratio of methylmercury to total mercury was similar to the 5 to 10 percent found in most natural waters. Concentrations of arsenic and chromium in bed sediments were near the threshold-effect concentration. A qualitative ecological assessment of fishes and macroinvertebrates showed that intolerant salmonids were present at most sampled sites, and macroinvertebrate communities were indicative of near-excellent or excellent conditions at all eight sites. This baseline information will aid in an ongoing monitoring effort designed to protect the water resources of the

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the American Falls Reservoir area, Idaho, 1988-89

USGS Publications Warehouse

Low, Walton H.; Mullins, William H.

1990-01-01

Increased concern about the quality of irrigation drainage and its potential effects on human health, fish, and wildlife prompted the Department of the Interior to begin a program during late 1985 to identify irrigation-induced water-quality problems that might exist in the Western States. During `988, the Task Group on Irrigation Drainage selected the American Falls Reservoir area, Idaho, for study to determine whether potentially toxic concentrations of trace elements or organochlorine compounds existed in water, bottom sediment, and biota. The 91-square mile American Falls Reservoir has a total capacity of 1.7 million acre-feet and is used primarily for irrigation-water supply and power generation. Irrigated land upstream from the reservoir totals about 550,000 acres. Total water inflow to the reservoir is about 5.8 million acre-feet per year, of which about 63 percent is from surface-water runoff, 33 percent is from ground-water discharge, and about 4 percent is from ungaged tributaries, canals, ditches, sloughs, and precipitation. Ground-water discharge to the reservoir originates, in part, from irrigation of land upstream from and adjacent to the reservoir. The 1988 water year was a drought year, and water discharge was about 34 percent less than during 1939-88. Water samples were collected during the post-irrigation (October 1987) and irrigation (July 1988) seasons and were analyzed for major ions and trace elements. Bottom-sediment samples were collected during the irrigation season and were analyzed for trace elements and organochlorine compounds. Biota samples were collected during May, June, July, and August 1988 and were analyzed for trace elements and organochlorine compounds. Dissolved-solids concentrations in water ranged from 216 to 561 milligrams per liter. The similarity of dissolved-solids concentrations between the irrigation and post-irrigation seasons can be attributed to the large volume of ground-water discharge in the study area. Most trace-element concentrations in water were near analytical reporting limits; none exceeded State or Federal water-quality standards or criteria. Trace elements that were present at all sites in analytically detectable concentrations (in micrograms per liter) included arsenic (2 to 7), boron (40 to 130), uranium (0.7 to 3.5), vanadium (1 to 6) and zinc (less than 3 to 42). The ranges of arsenic, cadmium, and mercury concentrations in water analyzed during previous investigations. Selenium concentrations ranged from less than 1 (the reporting limit) to 6 micrograms per liter and did not exceed State of Federal water-quality standards or criteria. Concentrations of most trace elements in bottom sediment were similar to geometric mean concentrations in study area soils and were within the expected 95-percent range of concentrations in soils in the Western United States. Mercury concentrations in 9 of the 18 bottom-sediment samples exceeded the 95th-percentile concentration for mercury in area soils. Selenium concentration for selenium in area soils and, in 1 sample, exceeded the upper limit of the expected 95-percent range for selenium in Western United States soils. Most organochlorine compunds in bottom sediment were lower than analytical reporting limits. Only DDE (0.2 micrograms per kilogram) and DDT (0.3 micrograms per kilogram) were detected in bottom sediment from the Portneuf River. Except for mercury and selenium, concentrations of most trace elements in biota were not considered high enough to be harmful to humans or wildlife. Some mercury concentrations in fish exceeded the U.S. Fish and Wildlife Service National Contaminant Biomonitoring Program 85th-percentile concentration and were at levels that might not be safe for human consumption, especially for pregnant women. Elevated mercury concentrations in fish-eating waterbirds, such as double-crested cormorants, indicates biomagnification in the food chain. Selenium concentrations generally were low except in mallard livers (6.6 to 41.8 micrograms per gram, dry weight). This range is within the range of selenium concentrations (19 to 43 micrograms per gram, dry weight) reported in livers of ducks from Kesterson National Wildlife Refuge, California, where waterbird deformities, moralities, and reproductive impairment were observed. Selenium concentrations in mayfly nymphs were at or near dietary concentrations (5 to 8 micrograms per gram, dry weight) that had adverse reproductive effects on mallards during laboratory toxicity studies. p,p'DDE was detected in all waterbird eggs and juvenile mallared carcasses. Highest concentrations were in cormorant eggs (0.59 to 5.70 micrograms per gram, wet weight). p,p'DDE concentrations in four of five cormorant eggs exceeded the National Academy of Sciences, National Academy of Engineering criterion for protection of aquatic wildlife (1 microgram per gram, wet weight, for p,p'DDT and its metabolites). p,p'DDE was detected in all fish samples except rainbow trout. p,p'DDE was detected in one sample of Utah suckers. No concentrations of p,p'DDE or p,p'DDT in fish exceeded the criterion for protection of aquatic life. Total PCB's were detected in all cormorant eggs and all fish samples. PCB's were not detected in other waterbird eggs. PCB concentrations in cormorant eggs (0.28 to 1.8 micro per gram, wet weight) were lower than concentrations that would be expected to cause adverse effects. Two of the three carp samples contained PCB concntrations higher than the recommended level for protection of fish and wildlife (0.4 micrograms per gram, wet weight). Eggshell thinning was noted in cormorant and mallard eggs but was not considered great enough to cause reporductive problems. Observations of the general health of fish and waterbird populations during the study indicated that the area did not appear to have a serious contaminant problem that could be associated with irrigation grainage. No waterbird or fish die-offs were observed, and nesting waterbird populations were noted to be increasing. Selenium concentrations in mallard livers, however, are of concern, as are p,p'DDE residues in cormorant eggs.

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Vermejo Project area and the Maxwell National Wildlife Refuge, Colfax County, northeastern New Mexico, 1993

USGS Publications Warehouse

Bartolino, J.R.; Garrabrant, L.A.; Wilson, Mark; Lusk, J.D.

1996-01-01

Based on findings of limited studies during 1989-92, a reconnaissance investigation was conducted in 1993 to assess the effects of the Vermejo Irrigation Project on water quality in the area of the project, including the Maxwell National Wildlife Refuge. This project was part of a U.S. Department of the Interior National Irrigation Water-Quality Program to determine whether irrigation drainage has caused or has the potential to cause significant harmful effects on human health, fish, and wildlife and whether irrigation drainage may adversely affect the suitability of water for other beneficial uses. For this study, samples of water, sediment, and biota were collected from 16 sites in and around the Vermejo Irrigation Project prior to, during the latter part of, and after the 1993 irrigation season (April, August-September, and November, respectively). No inorganic constituents exceeded U.S. Environmental Protection Agency drinking-water standards. The State of New Mexico standard of 750 micrograms per liter for boron in irrigation water was exceeded at three sites (five samples), though none exceeded the livestock water standard of 5,000 micrograms per liter. Selenium concentrations exceeded the State of New Mexico chronic standard of 2 micrograms per liter for wildlife and fisheries water in at least eight samples from five sites. Bottom-sediment samples were collected and analyzed for trace elements and compared to concentrations of trace elements in soils of the Western United States. Concentrations of three trace elements at eight sites exceeded the upper values of the expected 95-percent ranges for Western U.S. soils. These included molybdenum at one site, selenium at seven sites, and uranium at four sites. Cadmium and copper concentrations exceeded the National Contaminant Biomonitoring Program 85th percentile in fish from six sites. Average concentrations of selenium in adult brine flies (33.7 mg/g dry weight) were elevated above concentrations in other invertebrates. Concentrations of other elements were below their respective toxicity levels. Plants, invertebrates, fish, and fish fillets were collected and analyzed. These analyses were compared to diagnostic criteria and to each other to determine the extent of bioaccumulation of trace elements. Plants contained larger dry weight concentrations of aluminum, arsenic, boron, chromium, iron, lead, magnesium, manganese, nickel, and vanadium than invertebrates and fish. Adult brine flies, gathered from playas, contained larger geometric mean dry weight concentrations of boron, magnesium, and selenium than other invertebrates. Of all samples collected, the largest mercury concentrations were found in fish fillets, although these concentrations were below levels of concern. Mercury and selenium bioaccumulation was evident in various habitats of the study area. Biological samples from Natural playa, an endemic wetland, and Half playa, a playa that receives additional water through seepage and irrigation delivery canals, generally had elevated concentrations of boron, iron, magnesium, and selenium than samples from reservoir and river sites. Selenium concentrations were lowest in biota from the two reservoir sites, although a wetland immediately downstream from the dam impounding Lake No. 13 (created by seepage from the reservoir) had elevated concentrations of selenium in biota. The geometric mean selenium concentration of whole-fish samples, except those from Lakes No. 13 and No. 14, exceeded the 5-mg/g dry weight selenium concentration that demarcates the approximate lower limit of the threshold range of concentrations that have been associated with adverse effects on piscine reproduction. Biota collected on and in the area around Maxwell National Wildlife Refuge contained concentrations of selenium that are in the low

Water quality in the lower Puyallup River valley and adjacent uplands, Pierce County, Washington

USGS Publications Warehouse

Ebbert, J.C.; Bortleson, Gilbert C.; Fuste, L.A.; Prych, E.A.

1987-01-01

The quality of most ground and surface water within and adjacent to the lower Puyallup River valley is suitable for most typical uses; however, some degradation of shallow groundwater quality has occurred. High concentrations of iron and manganese were found in groundwater, sampled at depths of < 40 ft, from wells tapping alluvial aquifers and in a few wells tapping deeper aquifers. Volatile and acid- and base/neutral-extractable organic compounds were not detected in either shallow or deep groundwater samples. The quality of shallow groundwater was generally poorer than that of deep water. Deep ground water (wells set below 100 ft) appears suitable as a supplementary water supply for fish-hatchery needs. Some degradation of water quality, was observed downstream from river mile 1.7 where a municipal wastewater-treatment plant discharges into the river. In the Puyallup River, the highest concentrations of most trace elements were found in bed sediments collected downstream from river mile 1.7. Median concentrations of arsenic, lead, and zinc were higher in bed sediments from small streams compared with those from the Puyallup River, possibly because the small stream drainages, which are almost entirely within developed areas, receive more urban runoff as a percentage of total flow. Total-recoverable trace-element concentrations exceeded water-quality criteria for acute toxicity in the Puyallup River and in some of the small streams. In most cases, high concentrations of total-recoverable trace elements occurred when suspended-sediment concentrations were high. Temperatures in all streams except Wapato Creek and Fife Dutch were within limits (18 C) for Washington State class A water. Minimum dissolved oxygen concentrations were relatively low at 5.6 and 2.0 mg/L, respectively, for Wapato Creek and Fife Dutch. The poorest surface-water quality, which can be characterized as generally unsuitable for fish, was in Fife Dutch, a manmade channel and therefore uncharacteristic of other small streams. (Author 's abstract)

Ground-water conditions and quality in the western part of Kenai Peninsula, southcentral Alaska

USGS Publications Warehouse

Glass, R.L.

1996-01-01

The western part of Kenai Peninsula in southcentral Alaska is bounded by Cook Inlet and the Kenai Mountains. Ground water is the predominant source of water for commercial, industrial, and domestic uses on the peninsula. Mean daily water use in an oil, gas, and chemical processing area north of Kenai is more than 3.5 million gallons. Unconsolidated sediments of glacial and fluvial origin are the most productive aquifers. In the upper (northwestern) peninsula, almost all water used is withdrawn from unconsolidated sediments, which may be as thick as 750 feet. In the lower peninsula, unconsolidated sediments are thinner and are absent on many hills. Water supplies in the lower peninsula are obtained from unconsolidated sediments and bedrock, and a public-water supply in parts of Homer is obtained from Bridge Creek. Throughout the peninsula, ground-water flow occurs primarily as localized flow controlled by permeability of aquifer materials and surface topography. The concentration of constituents analyzed in water from 312 wells indicated that the chemical quality of ground water for human consumption varies from marginal to excellent. Even though the median concentration of dissolved solids is low (152 milligrams per liter), much of the ground water on the peninsula does not meet water-quality regulations for public drinking water established by the U.S. Environmental Protection Agency (USEPA). About 8 percent of wells sampled yielded water having concentrations of dissolved arsenic that exceeded the USEPA primary maximum contaminant level of 50 micrograms per liter. Concentrations of dissolved arsenic were as great as 94 micrograms per liter. Forty-six percent of wells sampled yielded water having concentrations of dissolved iron greater than the USEPA secondary maximum contaminant level of 300 micrograms per liter. Unconsolidated sediments generally yield water having calcium, magnesium, and bicarbonate as its predominant ions. In some areas, ground water at depths greater than a few hundred feet may be naturally too salty for human consumption. The leaking and spilling of fuel and chemical products and the disposal of industrial wastes has degraded the quality of ground water at numerous sites.

Analysis of heavy metals from water, sediment, and tissues of Labeo angra (Hamilton, 1822), from an Ox-box lake- an wetland site from Assam, India.

PubMed

Das, Suchismita; Choudhury, Shamim Sultana

2016-01-01

The aim of this study was to assess the regional impacts of heavy metals (Mn, Fe, Mg, Ca, Cu, Zn, Cd, Cr, Pb and Ni) on water, sediment and a native, teleost fish species, Labeo angra, inhabiting a flood plain wetland of Barak River in Assam, India. Heavy metal concentrations in the water, sediments and fish were measured; bioaccumulation factor, metal pollution index as well as condition indices were calculated, to assess the pollution load and health status of the fish. Multivariate statistical analysis was used on wetland water and sediment heavy metals to ascertain the possible sources and seasonal variations of the pollutants. Results showed that most heavy metals in the wetland water and sediments exceeded the water (drinking and irrigation) and sediment quality guidelines, respectively. Seasonal variations were observed for geogenic heavy metals, Mn, Fe, Mg and Ca while no seasonal variations were observed for anthropogenic heavy metals, Cu, Cd, Cr, Pb and Ni. Multivariate statistical analysis showed that there was strong correlation between geogenic and anthropogenic heavy metals in water and sediment, both originating from the common anthropogenic sources. Accumulation of most of the metals in all the tissues was above the safe limits as recommended by the Food and Agriculture Organization. High bioaccumulation factors and metal pollution index for these metals in the different tissues revealed that metals were extensively bio-accumulated and bioconcentrated. Condition indices in fish from the wetland suggested metabolic abnormalities.

Review of Oceanographic and Geochemical Data Collected in Massachusetts Bay during a Large Discharge of Total Suspended Solids from Boston's Sewage-Treatment System and Ocean Outfall in August 2002

USGS Publications Warehouse

Bothner, Michael H.; Butman, Bradford; Casso, Michael A.

2010-01-01

During the period August 14-23, 2002, the discharge of total suspended solids (TSS) from the Massachusetts Water Resources Authority sewage-treatment plant ranged from 32 to 132 milligrams per liter, causing the monthly average discharge to exceed the limit specified in the National Pollution Discharge Elimination System permit. Time-series monitoring data collected by the U.S. Geological Survey in western Massachusetts Bay were examined to evaluate changes in environmental conditions during and after this exceedance event. The rate of sediment trapping and the concentrations of near-bottom suspended sediment measured near the outfall in western Massachusetts Bay increased during this period. Because similar increases in sediment-trapping rate were observed in the summers of 2003 and 2004, however, the increase in 2002 cannot be definitively attributed to the increased TSS discharge. Concentrations of copper and silver in trapped sediment collected 10 and 20 days following the 2002 TSS event were elevated compared to those in pre-event samples. Maximum concentrations were less than 50 percent of toxicity guidelines. Photographs of surficial bottom sediments obtained before and after the TSS event do not show sediment accumulation on the sea floor. Concentrations of silver, Clostridium perfringens, and clay in surficial bottom sediments sampled 10 weeks after the discharge event at a depositional site 3 kilometers west of the outfall were unchanged from those in samples obtained before the event. Simulation of the TSS event by using a coupled hydrodynamic-wave-sediment-transport model could enhance understanding of these observations and of the effects of the exceedance on the local marine environment.

Assessment of Water-Quality Conditions in Fivemile Creek in the Vicinity of the Fivemile Creek Greenway, Jefferson County, Alabama, 2003-2005

USGS Publications Warehouse

Gill, Amy C.; Robinson, John A.; Redmond, Jymalyn E.; Bradley, Michael W.

2008-01-01

The watershed of Fivemile Creek (FMC), a tributary to the Locust Fork of the Black Warrior River, is located north of Birmingham, Alabama. Areas that have been previously coal-mined border the creek, and portions of the upper watershed have been and are currently (2007) being used for industrial and urban uses. The U.S. Geological Survey (USGS), in cooperation with the City of Tarrant, the Freshwater Land Trust, and the Jefferson County Commission, conducted a water-quality assessment of 12 sites along FMC during 2003?2005. Water samples were analyzed for basic physical and chemical properties and concentrations of major ions, nutrients, fecal indicator bacteria, organic wastewater compounds, pesticides, trace elements, and semivolatile organic compounds. Streambed-sediment samples were analyzed for concentrations of trace elements and semivolatile organic compounds. Benthic invertebrate communities were evaluated for taxonomic composition and relation to water-quality conditions. Nutrient concentrations in the FMC watershed reflect the influences of natural and anthropogenic sources. Concentrations of total nitrogen in all samples and total Kjeldahl nitrogen in at least one sample each collected from FMC at Hewitt Park, FMC below Springdale Road, FMC at Lewisburg, FMC near Republic, FMC at Brookside, and FMC at Linn Crossing exceeded U.S. Environmental Protection Agency (USEPA) ecoregion nutrient criteria. Total phosphorus concentrations in about 58 percent of all samples were above the ecoregion nutrient criteria. Concentrations of chlorophyll a, an indicator of algal biomass, in the FMC watershed were below the appropriate USEPA ecoregion criteria. Fecal indicator bacteria concentrations occasionally exceeded criteria established by the Alabama Department of Environmental Management (ADEM) and the USEPA to protect human health and aquatic life. Median fecal-coliform concentrations equaled or exceeded USEPA criteria at four of the six sites with multiple samples. Maximum Escherichia coli (E. coli) concentrations usually occurred during high-flow conditions and exceeded the single-sample criterion for infrequently-used whole-body contact (576 colonies per 100 milliliters) at all but one site. Median E. coli concentrations for two of the seven sites with multiple samples exceeded USEPA criteria. Twenty-nine samples were collected from sites along FMC and analyzed by the USGS National Water Quality Laboratory for the presence of 57 organic wastewater compounds. Forty-six of the 57 organic wastewater compounds, representing all 11 general-use categories, were detected in samples from FMC. All detections of organic wastewater compounds were estimated below laboratory reporting limits except for several detections of the herbicide bromacil. Herbicides accounted for approximately 62 percent of the number of pesticide detections in the FMC study area. Two herbicides, atrazine and simazine, were detected most frequently, in 100 percent of the surface-water samples. Fipronil sulfide was the most commonly detected insecticide-derived compound, occurring in 52 percent of the surface-water samples. Concentrations of one insecticide, dieldrin, exceeded the USEPA?s health advisory level for drinking water in one sample at FMC at Hewitt Park and in one sample at FMC below Springdale Road. Concentrations of carbaryl in two samples and malathion in one sample exceeded aquatic-life criteria. Only a few trace element concentrations measured in FMC exceeded established standards or criteria. Some concentrations of aluminum and manganese were above secondary drinking-water standards. One cadmium concentration and three selenium concentrations measured at FMC at Lewisburg exceeded ADEM chronic aquatic-life criteria. Streambed-sediment samples were collected at seven sites along FMC, and analyzed for selected semivolatile organic compounds and trace elements. Forty-nine of 98 semivolatile organic compounds were detected in stre

Quality of water on the Prairie Band Potawatomi Reservation, northeastern Kansas, May 2001 through August 2003

USGS Publications Warehouse

Ross Schmidt, Heather C.

2004-01-01

Water-quality samples were collected from 20 surface-water sites and 11 ground-water sites on the Prairie Band Potawatomi Reservation in northeastern Kansas in an effort to describe existing water-quality conditions on the reservation and to compare water-quality conditions to results from previous reports published as part of a multiyear cooperative study with the Prairie Band Potawatomi Nation. Water is a valuable resource to the Prairie Band Potawatomi Nation as tribal members use the streams draining the reservation, Soldier, Little Soldier, and South Cedar Creeks, to fulfill subsistence hunting and fishing needs and as the tribe develops an economic base on the reservation. Samples were collected once at 20 surface-water monitoring sites during June 2001, and quarterly samples were collected at 5 of the 20 monitoring sites from May 2001 through August 2003. Ground-water-quality samples were collected once from seven wells and twice from four wells during April through May 2003 and in August 2003. Surface-water-quality samples collected from May through August 2001 were analyzed for physical properties, nutrients, pesticides, fecal indicator bacteria, and total suspended solids. In November 2001, an additional analysis for dissolved solids, major ions, trace elements, and suspended-sediment concentration was added for surface-water samples. Ground-water samples were analyzed for physical properties, dissolved solids, major ions, nutrients, trace elements, pesticides, and fecal indicator bacteria. Chemical oxygen demand and volatile organic compounds were analyzed in a sample from one monitoring well located near a construction and demolition landfill on the reservation. Previous reports published as a part of this ongoing study identified total phosphorus, triazine herbicides, and fecal coliform bacteria as exceeding their respective water-quality criteria in surface water on the reservation. Previous ground-water assessments identified occasional sample concentrations of dissolved solids, sodium, sulfate, boron, iron, and manganese as exceeding their respective water-quality criteria. Forty percent of the 65 surface-water samples analyzed for total phosphorus exceeded the aquatic-life goal of 0.1 mg/L (milligrams per liter) established by the U.S. Environmental Protection Agency (USEPA). Concentrations of dissolved solids and sodium occasionally exceeded USEPA Secondary Drinking-Water Regulations and Drinking-Water Advisory Levels, respectively. One of the 20 samples analyzed for atrazine concentrations exceeded the Maximum Contaminant Level (MCL) of 3.0 ?g/L (micrograms per liter) as an annual average established for drinking water by USEPA. A triazine herbicide screen was used on 63 surface-water samples, and triazine compounds were frequently detected. Triazine herbicides and their degradates are listed on the USEPA Contaminant Candidate List. Nitrite plus nitrate concentrations in two ground-water samples from one monitoring well exceeded the MCL of 10 mg/L established by USEPA for drinking water. Arsenic concentrations in two samples from one monitoring well also exceeded the proposed MCL of 10 ?g/L established by the USEPA for drinking water. Concentrations of dissolved solids and sulfate in some ground-water samples exceeded their respective Secondary Drinking-Water Regulations, and concentrations exceeded the taste threshold of the USEPA?s Drinking-Water Advisory Level for sodium. Consequently, in the event that ground water on the reservation is to be used as a drinking-water source, additional treatment may be necessary to remove excess dissolved solids, sulfate, and sodium.

Development and application of an innovative expert decision support system to manage sediments and to assess environmental risk in freshwater ecosystems.

PubMed

Dagnino, Alessandro; Bo, Tiziano; Copetta, Andrea; Fenoglio, Stefano; Oliveri, Caterina; Bencivenga, Mauro; Felli, Angelo; Viarengo, Aldo

2013-10-01

With the aim of supporting decision makers to manage contamination in freshwater environments, an innovative expert decision support system (EDSS) was developed. The EDSS was applied in a sediment quality assessment along the Bormida river (NW, Italy) which has been heavily contaminated by an upstream industrial site for more than a century. Sampling sites were classified by means of comparing chemical concentrations with effect-based target values (threshold and probable effect concentrations). The level of each contaminant and the combined toxic pressure were used to rank sites into three categories: (i) uncontaminated (8 sites), (ii) mildly contaminated (4) and (iii) heavily contaminated (19). In heavily contaminated sediments, an environmental risk index (EnvRI) was determined by means of integrating chemical data with ecotoxicological and ecological parameters (triad approach). In addition a sediment risk index (SedRI) was computed from combining chemical and ecotoxicological data. Eight sites exhibited EnvRI values ≥0.25, the safety threshold level (range of EnvRI values: 0.14-0.31) whereas SedRI exceeded the safety threshold level at 6 sites (range of SedRI values: 0.16-0.36). At sites classified as mildly contaminated, sublethal biomarkers were integrated with chemical data into a biological vulnerability index (BVI), which exceeded the safety threshold level at one site (BVI value: 0.28). Finally, potential human risk was assessed in selected stations (11 sites) by integrating genotoxicity biomarkers (GTI index falling in the range 0.00-0.53). General conclusions drawn from the EDSS data include: (i) in sites classified as heavily contaminated, only a few exhibited some significant, yet limited, effects on biodiversity; (ii) restrictions in re-using sediments from heavily contaminated sites found little support in ecotoxicological data; (iii) in the majority of the sites classified as mildly contaminated, tested organisms exhibited low response levels; (iv) preliminary results on genotoxicity biomarkers indicate possible negative consequences for humans if exposed to river sediments from target areas. © 2013.

Effects of three highway-runoff detention methods on water quality of the surficial aquifer system in central Florida

USGS Publications Warehouse

Schiffer, D.M.

1989-01-01

Water quality of the surficial aquifer system in central Florida was evaluated at one exfiltration pipe, two ponds (detention and retention), and two swales in central Florida, representing three runoff-detention methods, to detect any effect from infiltrating highway runoff. Concentrations of major ions, metals, and nutrients in groundwater and bottom sediments were measured from 1984 through 1986. At each study area, constituent concentrations in groundwater near the structure were compared to concentrations in groundwater from an upgradient control site. Groundwater quality data were also pooled by detention method and statistically compared to detect any significant differences between methods. Significantly greater mean phosphorus concentrations in groundwater near the exfiltration pipe than those in the control well was the only evidence of increasing constituent concentrations in groundwater near structures. The quality of water was more variable, and had greater constituent concentrations in the unsaturated zone than in the saturated zone near the exfiltration pipe. Values of water quality variables measured in groundwater at all study areas generally were within State drinking water standards. The main exception was dissolved iron, which commonly exceeded 300 micrograms/L at one swale and the detention pond. Results of the study indicate that natural processes occurring in soils attenuate inorganic constituent concentrations prior to reaching the receiving groundwater. However, organic compounds detected in bottom sediments at the retention pond indicate a potential problem that may eventually affect the quality of the receiving groundwater. (USGS)

Streamflow and Water-Quality Characteristics for Wind Cave National Park, South Dakota, 2002-03

USGS Publications Warehouse

Heakin, Allen J.

2004-01-01

A 2-year study of streamflow and water-quality characteristics in Wind Cave National Park was performed by the U.S. Geological Survey in cooperation with the National Park Service. During this study, streamflow and water-quality data were collected for three of the park's perennial streams (Cold Spring, Beaver, and Highland Creeks) from January 2002 through November 2003. The potential influence of parking lot runoff on cave drip within Wind Cave also was investigated by collecting and analyzing several time-dependent samples from a drainage culvert downstream from the parking lot and from Upper Minnehaha Falls inside the cave following a series of simulated runoff events. The primary focus of the report is on data collected during the 2-year study from January 2002 to November 2003; however, data collected previously also are summarized. Losing reaches occur on both Beaver and Highland Creeks as these streams flow across outcrops of bedrock aquifers within the park. No streamflow losses occur along Cold Spring Creek because its confluence with Beaver Creek is located upstream from the outcrop of the Madison aquifer, where most streamflow losses occur. Physical properties, major ions, trace elements, nutrients, bacteria, benthic macroinvertebrates, organic (wastewater) compounds, bottom sediment, and suspended sediment are summarized for samples collected from 2 sites on Cold Spring Creek, 2 sites on Beaver Creek, and 1 site on Highland Creek. None of the constituent concentrations for any of the samples collected during 2002-03 exceeded any of the U.S. Environmental Protection Agency drinking-water standards, with the exception of the Secondary Maximum Contaminant Level for pH, which was exceeded in numerous samples from Beaver Creek and Highland Creek. Additionally, the pH values in several of these same samples also exceeded beneficial-use criteria for coldwater permanent fisheries and coldwater marginal fisheries. Water temperature exceeded the coldwater permanent fisheries criterion in numerous samples from all three streams. Two samples from Highland Creek also exceeded the coldwater marginal fisheries criterion for water temperature. Mean concentrations of ammonia, orthophosphate, and phosphorous were higher for the upstream site on Beaver Creek than for other water-quality sampling sites. Concentrations of E. coli, fecal coliform, and total coliform bacteria also were higher at the upstream site on Beaver Creek than for any other site. Samples for the analysis of benthic macroinvertebrates were collected from one site on each of the three streams during July 2002 and May 2003. The benthic macroinvertebrate data showed that Beaver Creek had lower species diversity and a higher percentage of tolerant species than the other two streams during 2002, but just the opposite was found during 2003. However, examination of the complete data set indicates that the quality of water at the upstream site was generally poorer than the quality of water at the downstream site. Furthermore, the quality of water at the upstream site on Beaver Creek is somewhat degraded when compared to the quality of water from Highland and Cold Spring Creeks, indicating that anthropogenic activities outside the park probably are affecting the quality of water in Beaver Creek. Samples for the analysis of wastewater compounds were collected at least twice from four of the five water-quality sampling sites. Bromoform, phenol, caffeine, and cholesterol were detected in samples from Cold Spring Creek, but only phenol was detected at concentrations greater than the minimum reporting level. Concentrations of several wastewater compounds were estimated in samples collected from sites on Beaver Creek, including phenol, para-cresol, and para-nonylphenol-total. Phenol was detected at both sites on Beaver Creek at concentrations greater than the minimum reporting level. Bromoform; para-cresol; ethanol,2-butoxy-phosphate; and cholesterol were detected

Water quality of least-impaired lakes in eastern and southern Arkansas

USGS Publications Warehouse

Justus, B.

2010-01-01

A three-phased study identified one least-impaired (reference) lake for each of four Arkansas lake classifications: three classifications in the Mississippi Alluvial Plain (MAP) ecoregion and a fourth classification in the South Central Plains (SCP) ecoregion. Water quality at three of the least-impaired lakes generally was comparable and also was comparable to water quality from Kansas and Missouri reference lakes and Texas least-impaired lakes. Water quality of one least-impaired lake in the MAP ecoregion was not as good as water quality in other least-impaired lakes in Arkansas or in the three other states: a probable consequence of all lakes in that classification having a designated use as a source of irrigation water. Chemical and physical conditions for all four lake classifications were at times naturally harsh as limnological characteristics changed temporally. As a consequence of allochthonous organic material, oxbow lakes isolated within watersheds comprised of swamps were susceptible to low dissolved oxygen concentrations to the extent that conditions would be limiting to some aquatic biota. Also, pH in lakes in the SCP ecoregion was <6.0, a level exceeding current Arkansas water-quality standards but typical of black water systems. Water quality of the deepest lakes exceeded that of shallow lakes. N/P ratios and trophic state indices may be less effective for assessing water quality for shallow lakes (<2 m) than for deep lakes because there is an increased exposure of sediment (and associated phosphorus) to disturbance and light in the former. ?? 2009 Springer Science+Business Media B.V.

Empirical models based on the universal soil loss equation fail to predict sediment discharges from Chesapeake Bay catchments.

PubMed

Boomer, Kathleen B; Weller, Donald E; Jordan, Thomas E

2008-01-01

The Universal Soil Loss Equation (USLE) and its derivatives are widely used for identifying watersheds with a high potential for degrading stream water quality. We compared sediment yields estimated from regional application of the USLE, the automated revised RUSLE2, and five sediment delivery ratio algorithms to measured annual average sediment delivery in 78 catchments of the Chesapeake Bay watershed. We did the same comparisons for another 23 catchments monitored by the USGS. Predictions exceeded observed sediment yields by more than 100% and were highly correlated with USLE erosion predictions (Pearson r range, 0.73-0.92; p < 0.001). RUSLE2-erosion estimates were highly correlated with USLE estimates (r = 0.87; p < 001), so the method of implementing the USLE model did not change the results. In ranked comparisons between observed and predicted sediment yields, the models failed to identify catchments with higher yields (r range, -0.28-0.00; p > 0.14). In a multiple regression analysis, soil erodibility, log (stream flow), basin shape (topographic relief ratio), the square-root transformed proportion of forest, and occurrence in the Appalachian Plateau province explained 55% of the observed variance in measured suspended sediment loads, but the model performed poorly (r(2) = 0.06) at predicting loads in the 23 USGS watersheds not used in fitting the model. The use of USLE or multiple regression models to predict sediment yields is not advisable despite their present widespread application. Integrated watershed models based on the USLE may also be unsuitable for making management decisions.

Distribution and grain-size partitioning of metals in bovfom sediments of an experimentally acidified Wisconsin lake

USGS Publications Warehouse

Elder, John F.

2007-01-01

A study of concentrations and distribution of major and trace elements in surficial bottom sediments of Little Rock Lake in northern Wisconsin included examination of spatial variation and grain-size effects. No significant differences with respect to metal distribution in sediments were observed between the two basins of the lake, despite the experimental acidification of one of the basins from pH 6.1 to 4.6. The concentrations of most elements in the lake sediments were generally similar to soil concentrations in the area and were well below sediment quality criteria. Two exceptions were lead and zinc, whose concentrations in July 1990 exceeded the criteria of 50 μg/g and 100 μg/g, respectively, in both littoral and pelagic sediments. Concentrations of some elements, particularly Cu, Pb, and Zn, increased along transects from nearshore to midlake, following a similar gradient of sedimentary organic carbon. In contrast, Mn, Fe, and alkali/alkaline-earth elements were at maximum concentrations in nearshore sediments. These elements are less likely to partition to organic particles, and their distribution is more dependent on mineralogical composition, grain size, and other factors. Element concentrations varied among different sediment grain-size fractions, although a simple inverse relation to grain size was not observed. Fe, Mn, Pb, and Zn were more concentrated in a grain-size range 20–60 tm than in either the very fine or the coarse fractions, possibly because of the aggregation of smaller particles cemented together by organic and Fe/Mn hydrous-oxide coatings.

Toxicity of sediment cores collected from the Ashtabula River in northeastern Ohio, USA, to the amphipod Hyalella azteca

USGS Publications Warehouse

Ingersoll, C.G.; Kemble, N.E.; Kunz, J.L.; Brumbaugh, W.G.; MacDonald, D.D.; Smorong, D.

2009-01-01

This study was conducted to support a Natural Resource Damage Assessment and Restoration project associated with the Ashtabula River in Ohio. The objective of the study was to evaluate the chemistry and toxicity of 50 sediment samples obtained from five cores collected from the Ashtabula River (10 samples/core, with each 10-cm-diameter core collected to a total depth of about 150 cm). Effects of chemicals of potential concern (COPCs) measured in the sediment samples were evaluated by measuring whole-sediment chemistry and whole-sediment toxicity in the sediment samples (including polycyclic aromatic hydrocarbons [PAHs], polychlorinated biphenyls [PCBs], organochlorine pesticides, and metals). Effects on the amphipod Hyalella azteca at the end of a 28-day sediment toxicity test were determined by comparing survival or length of amphipods in individual sediment samples in the cores to the range of responses of amphipods exposed to selected reference sediments that were also collected from the cores. Mean survival or length of amphipods was below the lower limit of the reference envelope in 56% of the sediment samples. Concentrations of total PCBs alone in some samples or concentrations of total PAHs alone in other samples were likely high enough to have caused the reduced survival or length of amphipods (i.e., concentrations of PAHs or PCBs exceeded mechanistically based and empirically based sediment quality guidelines). While elevated concentrations of ammonia in pore water may have contributed to the reduced length of amphipods, it is unlikely that the reduced length was caused solely by elevated ammonia (i.e., concentrations of ammonia were not significantly correlated with the concentrations of PCBs or PAHs and concentrations of ammonia were elevated both in the reference sediments and in the test sediments). Results of this study show that PAHs, PCBs, and ammonia are the primary COPCs that are likely causing or substantially contributing to the toxicity to sediment-dwelling organisms. ?? 2009 US Government.

Assessment of Fish Habitat, Water Quality, and Selected Contaminants in Streambed Sediments in Noyes Slough, Fairbanks, Alaska, 2001-2002

USGS Publications Warehouse

Kennedy, Ben W.; Whitman, Matthew S.; Burrows, Robert L.; Richmond, Sharon A.

2004-01-01

During 2001-2002, the U.S. Geological Survey sampled streambed sediment at 23 sites, measured water quality at 26 sites, and assessed fish habitat for the entire length of Noyes Slough, a 5.5-mile slough of the Chena River in Fairbanks, Alaska. These studies were undertaken to document the environmental condition of the slough and to provide information to the public for consideration in plans to improve environmental conditions of the waterway. The availability of physical habitat for fish in the slough does not appear to be limited, although some beaver dams and shallow water may restrict movement, particularly during low flow. Elevated water temperatures in summer and low dissolved-oxygen concentrations are the principle factors adversely affecting water quality in Noyes Slough. Increased flow mitigated poor water-quality conditions and reduced the number of possible fish barriers. Flow appears to be the most prominent mechanism shaping water quality and fish habitat in Noyes Slough. Streambed sediment samples collected at 23 sites in 2001 were analyzed for 24 trace elements. Arsenic, lead, and zinc were the only trace elements detected in concentrations that exceed probable effect levels for the protection of aquatic life. The background concentration for arsenic in Noyes Slough is naturally elevated because of significant concentrations of arsenic in local bedrock and ground water. Sources of the zinc and lead contamination are uncertain, however both lead and zinc are common urban contaminants. Streambed-sediment samples from 12 sites in 2002 were analyzed for organochlorine pesticides, polychlorinated biphenyls (PCBs), and semivolatile organic compounds (SVOCs). The concentration of bis(2-ethylhexyl)phthalate of 2,600 micrograms per kilogram (?g/kg) for one sample from the site above Aurora Drive approached the aquatic-life criterion of 2,650 ?g/kg. Low concentrations of p-cresol, chrysene, and fluoranthene were detected in most of the sediment samples. The presence of these compounds in Noyes Slough sediment was expected because cresols are emitted to the atmosphere in the exhaust from motor vehicles and chrysene and fluoranthene are formed during the incomplete burning of coal, oil, gas, wood, garbage, or other organic substances. Low-level concentrations of DDT or its degradation products DDD and DDE were detected in all samples collected during 2002. However, total DDT (DDT+DDD+DDE) concentrations are less than the effects range median aquatic-life criterion of 46.1 ?g/kg. In general, total DDT concentrations were less than 10 ?g/kg, except for samples from two sites that have estimated concentrations of about 14 and 20 ?g/kg.

A new instrument system to investigate sediment dynamics on continental shelves

USGS Publications Warehouse

Cacchione, D.A.; Drake, D.E.

1979-01-01

A new instrumented tripod, the GEOPROBE system, has been constructed and used to collect time-series data on physical and geological parameters that are important in bottom sediment dynamics on continental shelves. Simultaneous in situ digital recording of pressure, temperature, light scattering, and light transmission, in combination with current velocity profiles measured with a near-bottom vertical array of electromagnetic current meters, is used to correlate bottom shear generated by a variety of oceanic processes (waves, tides, mean flow, etc.) with incipient movement and resuspension of bottom sediment. A bottom camera system that is activated when current speeds exceed preset threshold values provides a unique method to identify initial sediment motion and bed form development. Data from a twenty day deployment of the GEOPROBE system in Norton Sound, Alaska, during the period September 24 - October 14, 1976 show that threshold conditions for sediment movement are commonly exceeded, even in calm weather periods, due to the additive effects of tidal currents, mean circulation, and surface waves. ?? 1979.

Water quality of North Carolina streams

USGS Publications Warehouse

Harned, Douglas; Meyer, Dann

1983-01-01

Interpretation of water quality data collected by the U.S. Geological Survey and the North Carolina Department of Natural Resources and Community Development, for the Yadkin-Pee Dee River system, has identified water quality variations, characterized the current condition of the river in reference to water quality standards, estimated the degree of pollution caused by man, and evaluated long-term trends in concentrations of major dissolved constituents. Three stations, Yadkin River at Yadkin College (02116500), Rocky River near Norwood (02126000), and Pee Dee River near Rockingham (02129000) have been sampled over different periods of time beginning in 1906. Overall, the ambient water quality of the Yadkin-Pee Dee River system is satisfactory for most water uses. Iron and manganese concentrations are often above desirable levels, but they are not unusually high in comparison to other North Carolina streams. Lead concentrations also periodically rise above the recommended criterion for domestic water use. Mercury concentrations frequently exceed, and pH levels fall below, the recommended criteria for protection of aquatic life. Dissolved oxygen levels, while generally good, are lowest at the Pee Dee near Rockingham, due to the station 's location not far downstream from a lake. Suspended sediment is the most significant water quality problem of the Yadkin-Pee Dee River. The major cation in the river is sodium and the major anions are bicarbonate and carbonate. Eutrophication is currently a problem in the Yadkin-Pee Dee, particularly in High Rock Lake. An estimated nutrient and sediment balance of the system indicates that lakes along the Yadkin-Pee Dee River serve as a sink for sediment, ammonia, and phosphorus. Pollution makes up approximately 59% of the total dissolved solids load of the Yadkin River at Yadkin College, 43% for the Rocky River near Norwood, and 29% for the Pee Dee River near Rockingham. Statistically significant trends show a pattern of increasing concentration of most dissolved constituents over time, with a leveling off and decline in the middle to late 1970's.

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Lower Rio Grande Valley and Laguna Atascosa National Wildlife Refuge, Texas, 1986-87

USGS Publications Warehouse

Wells, Frank C.; Jackson, Gerry A.; Rogers, William J.

1988-01-01

Toxaphene was detected in 11 fish samples; detectable concentrations ranged from 0.98 to 5.1 micrograms per gram, wet weight. DOT also was detected in 11 fish samples with concentrations ranging from 0.021 to 0.066 micrograms per gram, wet weight. ODD was detected in 21 fish samples; concentrations ranged from 0.015 to 0.16 micrograms per gram, wet weight. DDE was detected in all 22 fish samples, and concentrations ranged from 0.36 to 9.9 micrograms per gram, wet weight. The maximum concentrations of DOT and ODD exceeded the 1980-81 baseline concentrations. The median and maximum concentrations of toxaphene and DDE exceeded the 1980-81 baseline concentrations. The largest concentrations of toxaphene, ODD, and DDE in fish were all measured in samples collected at the Main Floodway near Progreso.

Predicting the particle size distribution of eroded sediment using artificial neural networks.

PubMed

Lagos-Avid, María Paz; Bonilla, Carlos A

2017-03-01

Water erosion causes soil degradation and nonpoint pollution. Pollutants are primarily transported on the surfaces of fine soil and sediment particles. Several soil loss models and empirical equations have been developed for the size distribution estimation of the sediment leaving the field, including the physically-based models and empirical equations. Usually, physically-based models require a large amount of data, sometimes exceeding the amount of available data in the modeled area. Conversely, empirical equations do not always predict the sediment composition associated with individual events and may require data that are not always available. Therefore, the objective of this study was to develop a model to predict the particle size distribution (PSD) of eroded soil. A total of 41 erosion events from 21 soils were used. These data were compiled from previous studies. Correlation and multiple regression analyses were used to identify the main variables controlling sediment PSD. These variables were the particle size distribution in the soil matrix, the antecedent soil moisture condition, soil erodibility, and hillslope geometry. With these variables, an artificial neural network was calibrated using data from 29 events (r 2 =0.98, 0.97, and 0.86; for sand, silt, and clay in the sediment, respectively) and then validated and tested on 12 events (r 2 =0.74, 0.85, and 0.75; for sand, silt, and clay in the sediment, respectively). The artificial neural network was compared with three empirical models. The network presented better performance in predicting sediment PSD and differentiating rain-runoff events in the same soil. In addition to the quality of the particle distribution estimates, this model requires a small number of easily obtained variables, providing a convenient routine for predicting PSD in eroded sediment in other pollutant transport models. Copyright © 2017 Elsevier B.V. All rights reserved.

Influence of mining-related activities on concentrations of metals in water and sediment from streams of the Black Hills, South Dakota.

PubMed

May, T W; Wiedmeyer, R H; Gober, J; Larson, S

2001-01-01

Water and sediment samples were collected from streams in Spearfish Creek, Whitewood Creek, and Bear Butte Creek watersheds in the Black Hills, SD, an area impacted by gold mining operations. Arsenic concentrations that exceeded the U.S. Environmental Protection Agency's Maximum Concentration Limit of 50 microg/L for drinking water were found in water from Annie Creek, a tributary of Spearfish Creek, and from Whitewood Creek. Gold Run, a tributary of Whitewood Creek, and Annie Creek contained Se concentrations in water that exceeded the EPA Ecotox threshold of 5 microg/L and were classified as a high hazard for Se accumulation from water into the planktonic food chain and for resultant toxicity to fish and aquatic birds. Concentrations of As, Cd, Cu, Hg, Ni, Pb, and Zn in sediment exceeded EPA Ecotox thresholds in one or more of the watersheds suggesting potential adverse ecological effects. Sediment from Rubicon Creek, a tributary of Spearfish Creek, contained Se concentrations high enough (4.0 microg/g) to be a moderate hazard for accumulation from sediments into the benthic food chain, with resultant dietary toxicity to fish and aquatic birds. These results are discussed in light of historical mining activities and recent clean-up and reclamation efforts. Based on the results and comparisons to Ecotox tresholds, further studies of ecological effects are warranted.

Influence of mining-related activities on concentrations of metals in water and sediment from streams of the Black Hills, South Dakota

USGS Publications Warehouse

May, T.W.; Wiedmeyer, Ray H.; Gober, J.; Larson, S.

2001-01-01

Water and sediment samples were collected from streams in Spearfish Creek, Whitewood Creek, and Bear Butte Creek watersheds in the Black Hills, SD, an area impacted by gold mining operations. Arsenic concentrations that exceeded the U.S. Environmental Protection Agency's Maximum Concentration Limit of 50 μg/L for drinking water were found in water from Annie Creek, a tributary of Spearfish Creek, and from Whitewood Creek. Gold Run, a tributary of Whitewood Creek, and Annie Creek contained Se concentrations in water that exceeded the EPA Ecotox threshold of 5 μg/L and were classified as a high hazard for Se accumulation from water into the planktonic food chain and for resultant toxicity to fish and aquatic birds. Concentrations of As, Cd, Cu, Hg, Ni, Pb, and Zn in sediment exceeded EPA Ecotox thresholds in one or more of the watersheds suggesting potential adverse ecological effects. Sediment from Rubicon Creek, a tributary of Spearfish Creek, contained Se concentrations high enough (4.0 μg/g) to be a moderate hazard for accumulation from sediments into the benthic food chain, with resultant dietary toxicity to fish and aquatic birds. These results are discussed in light of historical mining activities and recent clean-up and reclamation efforts. Based on the results and comparisons to Ecotox tresholds, further studies of ecological effects are warranted.

Technical note: False low turbidity readings from optical probes during high suspended-sediment concentrations

NASA Astrophysics Data System (ADS)

Voichick, Nicholas; Topping, David J.; Griffiths, Ronald E.

2018-03-01

Turbidity, a measure of water clarity, is monitored for a variety of purposes including (1) to help determine whether water is safe to drink, (2) to establish background conditions of lakes and rivers and detect pollution caused by construction projects and stormwater discharge, (3) to study sediment transport in rivers and erosion in catchments, (4) to manage siltation of water reservoirs, and (5) to establish connections with aquatic biological properties, such as primary production and predator-prey interactions. Turbidity is typically measured with an optical probe that detects light scattered from particles in the water. Probes have defined upper limits of the range of turbidity that they can measure. The general assumption is that when turbidity exceeds this upper limit, the values of turbidity will be constant, i.e., the probe is pegged; however, this assumption is not necessarily valid. In rivers with limited variation in the physical properties of the suspended sediment, at lower suspended-sediment concentrations, an increase in suspended-sediment concentration will cause a linear increase in turbidity. When the suspended-sediment concentration in these rivers is high, turbidity levels can exceed the upper measurement limit of an optical probe and record a constant pegged value. However, at extremely high suspended-sediment concentrations, optical turbidity probes do not necessarily stay pegged at a constant value. Data from the Colorado River in Grand Canyon, Arizona, USA, and a laboratory experiment both demonstrate that when turbidity exceeds instrument-pegged conditions, increasing suspended-sediment concentration (and thus increasing turbidity) may cause optical probes to record decreasing false turbidity values that appear to be within the valid measurement range of the probe. Therefore, under high-turbidity conditions, other surrogate measurements of turbidity (e.g., acoustic-attenuation measurements or suspended-sediment samples) are necessary to correct these low false turbidity measurements and accurately measure turbidity.

Technical note: False low turbidity readings from optical probes during high suspended-sediment concentrations

USGS Publications Warehouse

Voichick, Nicholas; Topping, David; Griffiths, Ronald

2018-01-01

Turbidity, a measure of water clarity, is monitored for a variety of purposes including (1) to help determine whether water is safe to drink, (2) to establish background conditions of lakes and rivers and detect pollution caused by construction projects and stormwater discharge, (3) to study sediment transport in rivers and erosion in catchments, (4) to manage siltation of water reservoirs, and (5) to establish connections with aquatic biological properties, such as primary production and predator–prey interactions. Turbidity is typically measured with an optical probe that detects light scattered from particles in the water. Probes have defined upper limits of the range of turbidity that they can measure. The general assumption is that when turbidity exceeds this upper limit, the values of turbidity will be constant, i.e., the probe is pegged; however, this assumption is not necessarily valid. In rivers with limited variation in the physical properties of the suspended sediment, at lower suspended-sediment concentrations, an increase in suspended-sediment concentration will cause a linear increase in turbidity. When the suspended-sediment concentration in these rivers is high, turbidity levels can exceed the upper measurement limit of an optical probe and record a constant pegged value. However, at extremely high suspended-sediment concentrations, optical turbidity probes do not necessarily stay pegged at a constant value. Data from the Colorado River in Grand Canyon, Arizona, USA, and a laboratory experiment both demonstrate that when turbidity exceeds instrument-pegged conditions, increasing suspended-sediment concentration (and thus increasing turbidity) may cause optical probes to record decreasing false turbidity values that appear to be within the valid measurement range of the probe. Therefore, under high-turbidity conditions, other surrogate measurements of turbidity (e.g., acoustic-attenuation measurements or suspended-sediment samples) are necessary to correct these low false turbidity measurements and accurately measure turbidity.

Sediment contamination of residential streams in the metropolitan kansas city area, USA: Part II. whole-sediment toxicity to the amphipod hyalella azteca

USGS Publications Warehouse

Tao, J.; Ingersoll, C.G.; Kemble, N.E.; Dias, J.R.; Murowchick, J.B.; Welker, G.; Huggins, D.

2010-01-01

This is the second part of a study that evaluates the influence of nonpoint sources on the sediment quality of five adjacent streams within the metropolitan Kansas City area, central United States. Physical, chemical, and toxicity data (Hyalella azteca 28-day whole-sediment toxicity test) for 29 samples collected in 2003 were used for this evaluation, and the potential causes for the toxic effects were explored. The sediments exhibited a low to moderate toxicity, with five samples identified as toxic to H. azteca. Metals did not likely cause the toxicity based on low concentrations of metals in the pore water and elevated concentrations of acid volatile sulfide in the sediments. Although individual polycyclic aromatic hydrocarbons (PAHs) frequently exceeded effect-based sediment quality guidelines [probable effect concentrations (PECs)], only four of the samples had a PEC quotient (PEC-Q) for total PAHs over 1.0 and only one of these four samples was identified as toxic. For the mean PEC-Q for organochlorine compounds (chlordane, dieldrin, sum DDEs), 4 of the 12 samples with a mean PEC-Q above 1.0 were toxic and 4 of the 8 samples with a mean PEC-Q above 3.0 were toxic. Additionally, four of eight samples were toxic, with a mean PEC-Q above 1.0 based on metals, PAHs, polychlorinated biphenyls (PCBs), and organochlorine pesticides. The increase in the incidence of toxicity with the increase in the mean PEC-Q based on organochlorine pesticides or based on metals, PAHs, PCBs, and organochlorine pesticides suggests that organochlorine pesticides might have contributed to the observed toxicity and that the use of a mean PEC-Q, rather than PEC-Qs for individual compounds, might be more informative in predicting toxic effects. Our study shows that stream sediments subject to predominant nonpoint sources contamination can be toxic and that many factors, including analysis of a full suite of PAHs and pesticides of both past and present urban applications and the origins of these organic compounds, are important to identify the causes of toxicity. ?? 2010 Springer Science+Business Media, LLC.

Response of benthic invertebrate assemblages to metal exposure and bioaccumulation associated with hard-rock mining in northwestern streams, USA

USGS Publications Warehouse

Maret, T.R.; Cain, D.J.; MacCoy, D.E.; Short, T.M.

2003-01-01

Benthic macroinvertebrate assemblages, environmental variables, and associated mine density were evaluated during the summer of 2000 at 18 reference and test sites in the Coeur d'Alene and St. Regis River basins, northwestern USA as part of the US Geological Survey's National Water-Quality Assessment Program. Concentrations of Cd, Pb, and Zn in water and (or) streambed sediment at test sites in basins where production mine density was ???0.2 mines/km2 (in a 500-m stream buffer) were significantly higher than concentrations at reference sites. Zn and Pb were identified as the primary contaminants in water and streambed sediment, respectively. These metal concentrations often exceeded acute Ambient Water Quality Criteria for aquatic life and the National Oceanic and Atmospheric Administration Probable Effect Level for streambed sediment. Regression analysis identified significant correlations between production mine density in each basin and Zn concentrations in water and Pb in streambed sediment (r2 = 0.69 and 0.65, p < 0.01). Metal concentrations in caddisfly tissue, used to verify site-specific exposures of benthos, also were highest at sites downstream from intensive mining. Benthic invertebrate taxa richness and densities were lower at sites downstream than upstream of areas of intensive hard-rock mining and associated metal enrichment. Benthic invertebrate metrics that were most effective in discriminating changes in assemblage structure between reference and mining sites were total number of taxa, number of Ephemeroptera, Plecoptera, and Trichoptera (EPT) taxa, and densities of total individuals, EPT individuals, and metal-sensitive Ephemeroptera individuals.

Evaluation of the effects of Middleton's stormwater-management activities on streamflow and water-quality characteristics of Pheasant Branch, Dane County, Wisconsin 1975-2008

USGS Publications Warehouse

Gebert, Warren A.; Rose, William J.; Garn, Herbert S.

2012-01-01

Few long-term data sets are available for evaluating the effects of urban stormwater-management practices. Over 30 years of data are available for evaluating the effectiveness of such practices by the city of Middleton, Wis. Analysis of streamflow and water-quality data collected on Pheasant Branch, demonstrates the relation between the changes in the watershed to the structural and nonstructural best management practices put in place during 1975-2008. A comparison of the data from Pheasant Branch with streamflow and water-quality data (suspended sediment and total phosphorus) collected at other nearby streams was made to assist in the determination of the possible causes of the changes in Pheasant Branch. Based on 34 years of streamflow data collected at the Pheasant Branch at Middleton streamflow-gaging station, flood peak discharges increased 37 percent for the 2-year flood and 83 percent for the 100-year flood. A comparison of data for the same period from an adjacent rural stream, Black Earth at Black Earth had a 43 percent increase in the 2-year flood peak discharge and a 140-percent increase in the 100-year flood peak discharge. Because the flood peak discharges on Pheasant Branch have not increased as much as Black Earth Creek it appears that the stormwater management practices have been successful in mitigating the effects of urbanization. Generally urbanization results in increased flood peak discharges. The overall increase in flood peak discharges seen in both streams probably is the result of the substantial increase in precipitation during the study period. Average annual runoff in Pheasant Branch has also been increasing due to increasing average annual precipitation and urbanization. The stormwater-management practices in Middleton have been successful in decreasing the suspended-sediment and total phosphorus loads to Lake Mendota from the Pheasant Branch watershed. These loads decreased in spite of increased annual runoff and flood peaks, which are often expected to produce higher sediment and phosphorus loads. The biggest decreases in sediment and phosphorus loads occurred after 2001 when a large detention pond, the Confluence Pond, began operation. Since 2001, the annual suspended-sediment load has decreased from 2,650 tons per year to 1,450 tons per year for a 45-percent decrease. The annual total phosphorus load has decreased from 12,200 pounds per year to 6,300 pounds per year for a 48-percent decrease. A comparison of Pheasant Branch at Middleton with two other streams, Spring Harbor Storm Sewer and Yahara River at Windsor, that drain into Lake Mendota shows that suspended-sediment and total phosphorus load decreases were greatest at Pheasant Branch at Middleton. Prior to the construction of the Confluence Pond, annual suspended-sediment yield and total phosphorus yield from Pheasant Branch watershed was the largest of the three watersheds. After 2001, suspended-sediment yield was greatest at Spring Harbor Storm Sewer, and lowest at Yahara at Windsor; annual total phosphorus yield was greater at Yahara River at Windsor than that of Pheasant Branch. The stormwater-quality plan for Middleton shows that the city has met the present State of Wisconsin Administrative Code chap. NR216/NR151 requirements of reducing total suspended solids by 20 percent for the developed area in Middleton. In addition, the city already has met the 40-percent reduction in total suspended solids required by 2013. Snow and ice melt runoff from road surfaces and parking lots following winter storms can effect water quality because the runoff contains varying amounts of road salt. To evaluate the effect of road deicing on stream water quality in Pheasant Branch, specific conductance and chloride were monitored during two winter seasons. The maximum estimated concentration of chloride during the monitoring period was 931 milligrams per liter, which exceeded the U.S. Environmental Protection Agency acute criterion of 860 milligrams per liter. Chloride concentrations exceeded the U.S. Environmental Protection Agency chronic criterion of 230 milligrams per liter for at least 10 days during February and March 2007 and for 45 days during the 2007-8 winter seasons. The total sodium chloride load for the monitoring period was 1,720 tons and the largest sodium chloride load occurred in March and April of each year.

Effects of land use on the water quality and biota of three streams in the Piedmont province of North Carolina

USGS Publications Warehouse

Crawford, J.K.; Lenat, D.R.

1989-01-01

Three small streams in North Carolina 's northern Piedmont were studied to compare the effects of land use in their watersheds on water quality characteristics and aquatic biota. Devil 's Cradle Creek (agricultural watershed) had more than two times the sediment yield of Smith Creek (forested watershed) (0.34 tons/acre compared to 0.13 tons/acre), and Marsh Creek (urban watershed) had more than four times the yield of Smith Creek (0.59 tons/acre). Concentrations of nutrients were consistently highest in Devil 's Craddle Creek. Concentrations of total copper, iron, and lead in samples from each of the three streams at times exceeded State water quality standards as did concentrations of total zinc in samples from both Smith and Marsh Creeks. Successively lower aquatic invertebrate taxa richness was found in the forested, the agricultural, and the urban watershed streams. Invertebrate biota in Smith Creek was dominated by insects, such as Ephemeroptera, that are intolerant to stress from pollution, whereas Devil 's Cradle Creek was dominated by the more tolerant Diptera, and Marsh Creek was dominated by the most pollution-tolerant group, the Oligochaeta. Fish communities in the forested and agricultural watershed streams were characterized by more species and more individuals of each species, relative to a limited community in urban Marsh Creek. Three independent variables closely linked to land use--suspended-sediment yield, suspended-sediment load, and total lead concentrations in stream water--are inversely associated with the biological communities of the streams.

Heavy metal concentrations and toxicity in water and sediment from stormwater ponds and sedimentation tanks.

PubMed

Karlsson, Kristin; Viklander, Maria; Scholes, Lian; Revitt, Mike

2010-06-15

Sedimentation is a widely used technique in structural best management practices to remove pollutants from stormwater. However, concerns have been expressed about the environmental impacts that may be exerted by the trapped pollutants. This study has concentrated on stormwater ponds and sedimentation tanks and reports on the accumulated metal concentrations (Cd, Cr, Ni, Pb, and Zn) and the associated toxicity to the bacteria Vibrio fischeri. The metal concentrations are compared with guidelines and the toxicity results are assessed in relation to samples for which metal concentrations either exceed or conform to these values. The water phase metal concentrations were highest in the ponds whereas the sedimentation tanks exhibited a distinct decrease towards the outlet. However, none of the water samples demonstrated toxicity even though the concentrations of Cu, Pb, and Zn exceeded the threshold values for the compared guidelines. The facilities with higher traffic intensities had elevated sediment concentrations of Cr, Cu, Ni, and Zn which increased towards the outlet for the sedimentation tanks in agreement with the highest percentage of fine particles. The sediments in both treatment facilities exhibited the expected toxic responses in line with their affinity for heavy metals but the role of organic carbon content is highlighted. Copyright 2010 Elsevier B.V. All rights reserved.

Irrigation-induced contamination of water, sediment, and biota in the western United States-synthesis of data from the National Irrigation Water Quality Program

USGS Publications Warehouse

Seiler, Ralph L.; Skorupa, Joseph P.; Naftz, David L.; Nolan, B. Thomas

2003-01-01

In October 1985 the U.S. Department of the Interior (DOI), through the National Irrigation Water Quality Program (NIWQP), began a series of field investigations at 26 areas in the Western United States to determine whether irrigation drainage has had harmful effects on fish, wildlife, and humans or has reduced beneficial uses of water. In 1992 NIWQP initiated the Data Synthesis Project to evaluate data collected during the field investigations. Geologic, climatologic, and hydrologic data were evaluated and water, sediment, and biota from the 26 areas were analyzed to identify commonalities and dominant factors that result in irrigation-induced contamination of water and biota. Data collected for the 26 area investigations have been compiled and merged into a common data base. The structure of the data base is designed to enable assessment of relations between contaminant concentrations in water, sediment, and biota. The data base is available to the scientific community through the World Wide Web at URL http://www.usbr.gov/niwqp. Analysis of the data base for the Data Synthesis included use of summary statistics, factor analysis, and logistic regression. A Geographic Information System was used to store and analyze spatially oriented digital data such as land use, geology and evaporation rates. In the U.S. Department of the Interior (DOI) study areas, samples of water, bottom sediment, and biota were collected for trace-element and pesticide analysis. Contaminants most commonly associated with irrigation drainage were identified by comparing concentrations in water with established criteria. For surface water, the criteria used were typically chronic criteria for the protection of freshwater aquatic life. Because ground water can discharge to the surface where wildlife can be exposed to it, the criteria used for ground water were both the maximum contaminant levels (MCL's) for drinking water and the chronic criteria for the protection of freshwater aquatic life. Data collected by the NIWQP studies indicated that, in surface water, filtered and unfiltered samples had nearly the same concentrations of arsenic, boron, molybdenum, and selenium for concentrations greater than about 10 micrograms per liter. Therefore, in this concentration range, filtered concentrations can be directly compared to biological-effect levels developed for unfiltered samples. In the range of 1 to 10 micrograms per liter there may be a tendency for unfiltered arsenic concentrations to be greater than filtered concentrations. For selenium, however, the data suggest differences from equality in that range result from analytical imprecision and not a general tendency for unfiltered concentrations to be greater than filtered concentrations. This relation may not be true in lentic, nutrient-rich waters because in such settings algae can bioaccumulate large amounts of selenium and other trace elements. Selenium was the trace element in surface water that most commonly exceeded chronic criteria for the protection of freshwater aquatic life; more than 40 percent of the selenium concentrations in surface-water samples exceeded the U.S. Environmental Protection Agency (USEPA) aquatic-life chronic criterion (5 micrograms per liter). In 12 of the 26 areas at least 25 percent of the surface water-samples had selenium concentrations that either equaled or exceeded the chronic criterion (5 micrograms per liter). More than 28 percent of boron concentrations and almost 17 percent of the molybdenum concentrations exceeded the aquatic life criteria established by the State of California (550 and 19 micrograms per liter, respectively). In ground water, more than 22 percent of the arsenic concentrations and more than 35 percent of the selenium concentrations exceeded the MCL (10 and 50 micrograms per liter, respectively). Few samples of uranium in surface water exceeded a criterion for the protection of aquatic life (300 micrograms per liter), but 44 percent

Changing sources of polychlorinated dibenzo-p-dioxins and furans in sediments and ecological risk for nekton in the lower Passaic River and Newark Bay, New Jersey, USA.

PubMed

Khairy, Mohammed; Barrett, Kirk; Lohmann, Rainer

2016-03-01

Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) were measured in sediments (surface and deeper sediments) and porewater of the lower Passaic River and Newark Bay (New Jersey, USA) to apportion their sources and conduct an ecological risk assessment. Positive matrix factorization was applied to identify sources of PCDD/Fs. Five source profiles were extracted from the positive matrix factorization model applied to the sediment samples including chloranil, combustion, polychlorinated biphenyl impurities, mixed urban sources, and the historical contamination from the former Diamond Alkali plant. The ecological risk assessment was estimated using several lines of evidence depending on site-specific data (blue crab and fish samples representing different feeding habits and positions in the trophic wood web of the river). Porewater concentrations gave the best estimates of lipid concentrations especially in the blue crab samples (with an average factor difference of 3.8). Calculated hazard quotients (HQs) for the fish samples and blue crab were >1 based on the no-effect concentration and tissue screening concentration approaches. At the same time, calculated porewater toxic units were >1. Sediment concentrations exceeded the published sediment quality guidelines for the protection of fish and benthic species, indicating the existence of significant risk to the aquatic life in the Passaic River. Accordingly, further actions and control measures are needed to reduce the emission of PCDD/Fs from ongoing sources. © 2015 SETAC.

Determination of selected heavy metal concentrations and distribution in a southwestern stream using macrophytes.

PubMed

Martinez, Edward A; Shu-Nyamboli, Chemanji

2011-09-01

Since the reduction of the arsenic standard from 50 to 10 μg L(-1) by the US Environmental Protection Agency in 2006 many small town and rural water municipalities were left with the task of preventing or mitigating arsenic contamination of drinking water supplies. In this study macrophytes and sediments were used to determine the concentration and distribution of heavy metals (As, Cd, Cu, Pb, and Zn) within the primary source of drinking water (Gallinas River watershed) to the residents of Las Vegas, New Mexico. Sampling was done in the spring and fall at four sites, two above the city and two below, and samples were analyzed using ICP-MS. Results showed significantly higher (p<.05) metal concentrations in plant roots than shoots for most metals. Spearman's correlation showed positive correlations (r>.3) between plant and sediment concentrations of Cd, Pb, Zn, As, and a negative correlation for Cu. The site above waste water treatment plant (AWWTP) had the highest plant tissue concentrations of Cd, Pb, Zn, and As. All of these concentrations attained critical toxicity levels exceeding sediment quality guidelines. High concentration factor values and levels of metals detected in macrophyte tissues indicate that heavy metals within sediments in the Gallinas River occur in bioavailable forms. Correlations between plant and sediment metal concentrations indicate that metal concentrations in macrophyte tissues are a good reflection of metal concentrations within the sediment in the Gallinas River. Copyright © 2011 Elsevier Inc. All rights reserved.

The use of Ampelisca abdita growth rate as an indicator of sediment quality

DOE Office of Scientific and Technical Information (OSTI.GOV)

Weston, D.P.; Thompson, B.

1995-12-31

Acute lethal bioassays with amphipod crustaceans are routinely used to assess toxicity of bulk sediments. A study within the San Francisco Bay Regional Monitoring Program (RMP) is in progress to develop a chronic bioassay with the amphipod Ampelisca abdita, measuring both survivorship and growth rates. This approach is attractive because depression of growth rate is likely to be a more sensitive indicator of toxic effects than acute lethality, and natural populations of A. abdita exist throughout the Bay. Spiked sediment bioassays, using cadmium and crude oil, were used to demonstrate the relative sensitivity of the standard 10-day lethal test vs.more » the 30-day growth test. Sediments were also collected from 9 sites throughout the Bay, ranging from areas adjacent to municipal wastewater discharges to areas distant from known point source inputs. These samples were then split, and used for side-by-side comparison of acute (lethal) and chronic (growth) toxicity tests. Survivorship exceeded 90% in all tests, including those sediments collected nearest the wastewater outfalls. Growth rates were contrasted among the various treatments to examine the utility of this end point in discriminating the outfall sites. Data on the spatial distribution, abundance, and size-frequency distribution of native populations was examined within the context of using growth rate as an indicator of toxic effects in natural populations as well.« less

Water quality of streams in the Red River of the North Basin, Minnesota, North Dakota, and South Dakota, 1970-2001

USGS Publications Warehouse

Tornes, Lan H.

2005-01-01

Data for the Red River of the North (Red River) Basin in Minnesota, North Dakota, and South Dakota were analyzed to determine whether the water quality of streams in the basin is adequate to meet future needs. For the Red River at Emerson, Manitoba, site, pH values, water temperatures, and dissolved-oxygen concentrations generally were within the criteria established for the protection of aquatic life. Dissolved-solids concentrations ranged from 245 to 1,100 milligrams per liter. Maximum sulfate and chloride concentrations were near, but did not exceed, the established secondary maximum contaminant level. The trace elements considered potentially harmful generally were at concentrations that were less than the established guidelines, standards, and criteria. The concentrations of lead that were detected may have occurred as a result of sample contamination.  For the Red River upstream from Emerson, Manitoba, sites, pH and other field values rarely exceeded the criteria established for the protection of aquatic life. Many constituent concentrations for the Red River below Fargo, N. site exceeded water-quality guidelines, standards, and criteria. However, the trace-element exceedances could be natural or could be related to pollution or sample contamination. Many of the tributaries in the western part of the Red River Basin had median specific-conductance values that were greater than 1,000 microsiemens per centimeter. Sulfate concentrations occasionally exceeded the established drinking-water standard. Median arsenic concentrations were 6 micrograms per liter or less, and maximum concentrations rarely exceeded the 10-microgram-per-liter drinking-water standard that is scheduled to take effect in 2006. The small concentrations of lead, mercury, and selenium that occasionally were detected may have been a result of sample contamination or other factors. The tributaries in the eastern part of the Red River Basin had median specific-conductance values that were less than 1,000 microsiemens per centimeter.  Concentrations of pesticides that were detected and that had regulatory limits were less than the cited water-quality guidelines, standards, and criteria. Concentrations of compounds that were detected generally were less than the sediment- quality standards and criteria. The data considered in this report generally provide a good baseline from which to evaluate changes in water-quality conditions. However, because many of the trace elements detected, including lead and mercury, may have been the result of sample contamination, additional data are needed to confirm that trace-element concentrations generally are low. Concentrations of major ions, including sulfate, and specific conductance may continue to approach drinking-water standards during periods of low flow because the streams, particularly those in the western part of the basin, are sustained mostly by ground-water discharge that generally has large dissolved-solids concentrations.

Toxicity of sediments and pore water from Brunswick Estuary, Georgia

USGS Publications Warehouse

Winger, Parley V.; Lasier, Peter J.; Geitner, Harvey

1993-01-01

A chlor-alkali plant in Brunswick, Georgia, USA, discharged >2 kg mercury/d into a tributary of the Turtle River-Brunswick Estuary from 1966 to 1971. Mercury concentrations in sediments collected in 1989 along the tributary near the chlor-alkali plant ranged from 1 to 27 μg/g (dry weight), with the highest concentrations found in surface (0–8 cm) sediments of subtidal zones in the vicinity of the discharge site. Toxicity screening in 1990 using Microtox® bioassays on pore water extracted on site from sediments collected at six stations distributed along the tributary indicated that pore water was highly toxic near the plant discharge. Ten-day toxicity tests on pore water from subsequent sediment samples collected near the plant discharge confirmed high toxicity to Hyalella azteca, and feeding activity was significantly reduced in whole-sediment tests. In addition to mercury in the sediments, other metals (chromium, lead, and zinc) exceeded 50 μg/g, and polychlorobiphenyl (PCB) concentrations ranged from 67 to 95 μg/g. On a molar basis, acid-volatile sulfide concentrations (20–45 μmol/g) in the sediments exceeded the metal concentrations. Because acid-volatile sulfides bind with cationic metals and form metal sulfides, which are generally not bioavailable, toxicities shown by these sediments were attributed to the high concentrations of PCBs and possibly methylmercury.

Concentrations, loads, and yields of select constituents from major tributaries of the Mississippi and Missouri Rivers in Iowa, water years 2004-2008

USGS Publications Warehouse

Garrett, Jessica D.

2012-01-01

Excess nutrients, suspended-sediment loads, and the presence of pesticides in Iowa rivers can have deleterious effects on water quality in State streams, downstream major rivers, and the Gulf of Mexico. Fertilizer and pesticides are used to support crop growth on Iowa's highly productive agricultural landscape and for household and commercial lawns and gardens. Water quality was characterized near the mouths of 10 major Iowa tributaries to the Mississippi and Missouri Rivers from March 2004 through September 2008. Stream loads were calculated for select ions, nutrients, and sediment using approximately monthly samples, and samples from storm and snowmelt events. Water-quality samples collected using standard streamflow-integrated protocols were analyzed for major ions, nutrients, carbon, pesticides, and suspended sediment. Statistical data summaries of sample data used parametric and nonparametric techniques to address potential bias related to censored data and multiple levels of censoring of data below analytical detection limits. Constituent stream loads were computed using standard pre-defined models in S-LOADEST that include streamflow and time terms plus additional terms for streamflow variability and streamflow anomalies. Streamflow variability terms describe the difference in streamflow from recent average conditions, whereas streamflow anomaly terms account for deviations from average conditions from long- to short-term sequentially. Streamflow variability or anomaly terms were included in 44 of 80 site/constituent individual models, demonstrating the usefulness of these terms in increasing accuracy of the load estimates. Constituent concentrations in Iowa streams exhibit streamflow, seasonal, and spatial patterns related to the landform and climate gradients across the studied basins. The streamflow-concentration relation indicated dilution for ions such as chloride and sulfate. Other constituent concentrations, such as dissolved organic carbon and suspended sediment, increased with streamflow. Nitrogen concentrations (total nitrogen and nitrate plus nitrite) increased with low and moderate streamflows, but decreased with high streamflows. Seasonal patterns observed in constituent concentrations were affected by streamflow, algae blooms, and pesticide application. The various landform regions produced different water-quality responses across the study basins; for example, total phosphorus, suspended sediment, and turbidity were greatest from the steep, loess-dominated southwestern Iowa basins. Nutrient concentrations, though not regulated for drinking water at the study sites, were high compared to drinking-water limits and criteria for protection of aquatic life proposed for other Midwestern states (Iowa criteria for aquatic life have not been proposed). Nitrate plus nitrite concentrations exceeded the drinking-water limit [10 milligrams per liter (mg/L)] in 11 percent of all samples at the 10 sites, and exceeded Minnesota's proposed aquatic life criteria (4.9 mg/L) in 68 percent of samples. The Wisconsin standard for total phosphorus (0.1 mg/L) was exceeded in 92 percent of samples. Ammonia standards, current during sample collection and at publication of this report, for protection of aquatic life were met for all samples, but draft criteria proposed in 2009 to protect more sensitive species like mussels, were exceeded at three sites. Loads and yields also differed among sites and years. The Big Sioux, Little Sioux, and Des Moines Rivers produced the greatest sulfate yields. Mississippi River tributaries had greater chloride yields than Missouri River tributaries. The Big Sioux River also had the lowest silica yields and total nitrogen and nitrate yields, whereas nitrogen yields were greater in the northeastern rivers. The Boyer and Nishnabotna River total phosphorus yields were the greatest in the study. The Boyer River orthophosphate yields were greatest except in 2008, when the Maquoketa River produced the greatest yield. Rivers in southwestern Iowa's Western Loess Hills and Steeply Rolling Loess Prairie ecoregions had the greatest suspended-sediment yields, whereas the smallest yields were in the Big Sioux and Wapsipinicon Rivers. In the 10 Iowa rivers studied, combined annual total nitrogen stream transport ranged from 3.68 to 9.95 tons per square mile per year, and total phosphorus transport ranged from 0.138 to 0.570 tons per square mile per year. Six-month loads relative to fertilizer use ranged from 8 to 56 percent for nitrogen, and 1.0 to 11.1 percent for phosphorus. The smallest loads relative to fertilizer use for both nitrogen and phosphorus occurred in July-December of dry years, and the largest nitrogen and phosphorus loads relative to use were in wet years from January-June.

Persistent organic pollutants associated to water fluxes and sedimentary processes in the Colorado River delta, Baja California, México.

PubMed

Lugo-Ibarra, K C; Daesslé, L W; Macías-Zamora, J V; Ramírez-Álvarez, N

2011-09-01

Polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) were studied in sediment cores from two distinctive modern channels of the Colorado River (CR) delta. Their abundance and temporal changes are associated with flood-flows from the CR across the USA-Mexico border. The CR channel is directly exposed to river flood-flows while the Hardy River (HR) is a local channel derived mainly from agricultural runoff, geothermal effluents, and treated urban wastewater. Different headwater compositions and degrees of exposure to flood-flows appear to be the factors controlling the composition of persistent organic pollutants (POPs). Enrichment of OCPs (46 ng g(-1) dwt in HR and 4.37 ng g(-1) dwt in CR) occurred during or a few years after flooding. PCB-138 (4.2 ng g(-1)dwt) is enriched in HR suggesting its origin in dielectric oils from the geothermal power plant. PCB-28 (2.1 ng g(-1)dwt) in CR may be related with atmospheric input and/or re-deposition of upstream sediments. In surficial sediments (0-3 cm), only HR exceeds international sediment quality guidelines (4,4'-DDE=8.16 ng g(-1)dwt and ΣDDT=8.34 ng g(-1)dwt). Copyright © 2011 Elsevier Ltd. All rights reserved.

Water quality and landscape processes of four watersheds in eastern Puerto Rico

USGS Publications Warehouse

Murphy, Sheila F.; Stallard, Robert F.; Contributions by Buss, Heather L.; Gould, William A.; Larsen, Matthew C.; Liu, Zhigang; Martinuzzi, Sebastian; Pares-Ramos, Isabel K.; White, Arthur F.; Zou, Xiaoming

2012-01-01

Humid tropical regions occupy about a quarter of Earth's land surface, yet they contribute a substantially higher fraction of the water, solutes, and sediment discharged to the world's oceans. Nearly half of Earth's population lives in the tropics, and development stresses can potentially harm soil resources, water quality, and water supply and in addition increase landslide and flood hazards. Owing to Puerto Rico's steep topography, low water storage capacity, and dependence on trade-wind precipitation, the island's people, ecosystems, and water supply are vulnerable to extreme weather such as hurricanes, floods, and droughts. Eastern Puerto Rico offers a natural laboratory for separating geologic and land-cover influences from regional- and global-scale influences because of its various bedrock types and the changing land cover surrounding intact, mature forest of the Luquillo Experimental Forest. Accordingly, a multiyear assessment of hydrological and biogeochemical processes was designed to develop an understanding of the effects of these differences on local climate, streamflow, water quality, and ecosystems, and to form the basis for a long-term and event-based program of climate and hydrologic monitoring. Because infrequent, large storms play a major role in this landscape, we focused on high-runoff events, sampling 263 storms, including all major hurricanes from 1991 through 2005. The largest storms have profound geomorphic consequences, such as landslides, debris flows, deep gullying on deforested lands, excavation and suspension of sediment in stream channels, and delivery of a substantial fraction of annual stream sediment load. Large storms sometimes entrain ocean foam and spray causing high concentrations of seasalt-derived constituents in stream waters during the storm. Past deforestation and agricultural activities in the Cayaguás and Canóvanas watersheds accelerated erosion and soil loss, and this material continues to be remobilized during large storms. Nearly 5,000 routine and event samples were analyzed for parameters that allow determination of denudation rates based on suspended and dissolved loads; 860 of these samples were analyzed for a comprehensive suite of chemical constituents. The rivers studied are generally similar in water-quality characteristics, and windward or leeward aspect appears to exert a stronger influence on water quality than geology or land cover. Of samples analyzed for comprehensive chemistry and for sediment, 543 were collected at runoff rates greater than 1 millimeter per hour, 256 at rates exceeding 10 millimeters per hour, and 3 at rates exceeding 90 millimeters per hour. Streams have rarely been sampled during events with such high runoff rates. Rates of physical and chemical weathering are especially high, and physical denudation rates, forested watersheds included, are considerably greater than is expected for a steady-state system. The elevated physical erosion drives an increased particulate organic carbon flux, one that is large, important to the carbon cycle, and sustainable, because soil-carbon regeneration is rapid. The 15-year Water, Energy, and Biogeochemical Budget dataset, which includes discharge, field parameters, suspended sediment, major cations and anions, and nutrients, is available from the U.S. Geological Survey's National Water Information System (http://waterdata.usgs.gov/nwis). The dataset provides a baseline for characterizing future environmental change and will improve our understanding of the interdependencies of land, water, and biological resources and their responses to changes in climate and land use. Because eastern Puerto Rico resembles many tropical regions in terms of geology and patterns of development, implications from this study are transferable to other tropical regions facing deforestation, rapid land-use change, and climate change.

Assessment of heavy metal contamination in water and sediments of Trepça and Sitnica rivers, Kosovo, using pollution indicators and multivariate cluster analysis.

PubMed

Ferati, Flora; Kerolli-Mustafa, Mihone; Kraja-Ylli, Arjana

2015-06-01

The concentrations of As, Cd, Cr, Co, Cu, Ni, Pb, and Zn in water and sediment samples from Trepça and Sitnica rivers were determined to assess the level of contamination. Six water and sediment samples were collected during the period from April to July 2014. Most of the water samples was found within the European and Kosovo permissible limits. The highest concentration of As, Cd, Pb, and Zn originates primarily from anthropogenic sources such discharge of industrial water from mining flotation and from the mine waste eroded from the river banks. Sediment contamination assessment was carried out using the pollution indicators such as contamination factor (CF), degree of contamination (Cd), modified degree of contamination (mCd), pollution load index (PLI), and geo-accumulation index (Igeo). The CF values for the investigated metals indicated a high contaminated nature of sediments, while the Cd values indicated a very high contamination degree of sediments. The mCd values indicate a high degree of contamination of Sitnica river sediment to ultrahigh degree of contamination of Trepça river sediment. The PLI values ranged from 1.89 to 14.1 which indicate that the heavy metal concentration levels in all investigated sites exceeded the background values and sediment quality guidelines. The average values of Igeo revealed the following ranking of intensity of heavy metal contamination of the Trepça and Sitnica river sediments: Cd > As > Pb > Zn > Cu > Co > Cr > Ni. Cluster analysis suggests that As, Cd, Cr, Co, Cu, Ni, Pb, and Zn are derived from anthropogenic sources, particularly discharges from mining flotation and erosion form waste from a zinc mine plant. In order to protect the sediments from further contamination, the designing of a monitoring network and reducing the anthropogenic discharges are suggested.

Nutrient, sediment, and pesticide data collected at four small agricultural basins in the Beaver Creek watershed, West Tennessee, 1990-1995

USGS Publications Warehouse

Williams, Shannon D.; Harris, Robin M.

1996-01-01

In 1989, the U.S. Geological Survey began a cooperative study with the Tennessee Department of Agriculture to assess the impact of agricultural activities on water quality in the Beaver Creek watershed in West Tennessee. Quantification of the transport of nutrients, sediment, and pesticides from agricultural fields was one of the objectives of the study. This report presents nutrient, sediment, and pesticide data collected during selected storm events from 1990 through 1995 at four relatively small, agricultural basins (28 to 422 acres) in the Beaver Creek watershed. Approximately 3,000 water samples (500 to 1,000 at each site) were analyzed for nitrogen and phosphorus species. Total nitrogen (N) concentrations ranged from 0.2 to 41.2 milligrams per liter (mg/L). Median concentrations for samples from each site ranged from 2.0 to 2.7 mg/L for total nitrogen, 1.2 to 1.9 mg/L for organic nitrogen, 0.05 to 0.14 mg/L for ammonia (measured as N), and 0.2 to 0.8 mg/L for nitrate plus nitrite (measured as N). Total phosphorus (P) concentrations ranged from 0.03 to 16.0 mg/L. Median concentrations for samples from each site ranged from 0.80 to 1.2 mg/L for total phosphorus and 0.15 to 0.72 for orthophosphate (measured as P). Approximately 6,000 water samples (1,300 to 1,800 at each site) were analyzed for suspended sediment. Suspended-sediment concentrations ranged from 8.0 to 98,353 mg/L. Concentrations exceeded 1,000 mg/L in 33 percent of the samples collected and exceeded 10,000 mg/L in 6 percent of the samples. Median concentrations ranged from 347 to 713 mg/L at the four sites. Several herbicides and insecticides were detected in water samples. Maximum concentrations detected were 37 micrograms per liter for metolachlor, 3.2 for trifluralin, 150 for fluometuron, and 430 for aldicarb. Aldicarb metabolites were also detected in several samples. The maximum aldicarb sulfoxide and aldicarb sulfone concentrations detected were 68.4 and 14.3 micrograms per liter, respectively.

Spatial distribution of chemical constituents in the Kuskokwim River, Alaska

USGS Publications Warehouse

Wang, Bronwen

1999-01-01

The effects of lithologic changes on the water quality of the Kuskokwim River, Alaska, were evaluated by the U.S. Geological Survey in June 1997. Water, suspended sediments, and bed sediments were sampled from the Kusko-kwim River and from three tributaries, the Holitna River, Red Devil Creek, and Crooked Creek. Dissolved boron, chromium, copper, manganese, zinc, aluminum, lithium, barium, iron, antimony, arsenic, mercury, and strontium were detected. Dissolved manganese and iron concentrations were three and four times higher in the Holitna River than in the Kusko-kwim River. Finely divided ferruginous materials found in the graywacke and shale units of the Kuskokwim Group are the probable source of the iron. The highest concentrations of dissolved strontium and barium were found at McGrath, and the limestone present in the upper basin was the most probable source of strontium. The total mercury concentrations on the Kuskokwim River decreased downstream from McGrath. Dissolved mercury was 24 to 32 percent of the total concentration. The highest concentrations of total mercury, and of dissolved antimony and arsenic were found in Red Devil Creek. The higher concentrations from Red Devil Creek did not affect the main stem mercury transport because the tributary was small relative to the Kuskokwim River. In Red Devil Creek, total mercury exceeded the concentration at which the U.S. Environmental Protection Agency (USEPA) indicates that aquatic life is affected and dissolved arsenic exceeded the USEPA's drinking-water standard. Background mercury and antimony concentrations in bed sediments ranged from 0.09 to 0.15 micrograms per gram for mercury and from 1.6 to 2.1 micrograms per gram for antimony. Background arsenic concentrations were greater than 27 micrograms per gram. Sites near the Red Devil mercury mine had mercury and antimony concentrations greater than background concentrations. These concentrations probably reflect the proximity to the ore body and past mining. Crooked Creek had mercury concentrations greater than the background concentration. The transport of suspended sediment-associated trace elements was lower for all elements in the lower river than in the upper river, indicating storage of sediments and their associated metals within the river system.

Assessment of injury to fish and wildlife resources in the Grand Calumet River and Indiana Harbor Area of Concern, USA

USGS Publications Warehouse

MacDonald, D.D.; Ingersoll, C.G.; Smorong, D.E.; Lindskoog, R.A.; Sparks, D.W.; Smith, J.R.; Simon, T.P.; Hanacek, M.A.

2002-01-01

This article is the second in a series of three that describes the results of a Natural Resource Damage Assessment (NRDA) conducted in the Grand Calumet River and Indiana Harbor Area of Concern (IHAOC). The assessment area is located in northwest Indiana and was divided into nine reaches to facilitate the assessment. This component of the NRDA was undertaken to determine if fish and wildlife resources have been injured due to exposure to contaminants that are associated with discharges of oil or releases of other hazardous substances. To support this assessment, information was compiled on the chemical composition of sediment and tissues; on the toxicity of whole sediments, pore water, and elutriates to fish; on the status of fish communities; and on fish health. The data on each of these indicators were compared to regionally relevant benchmarks to assess the presence and extent of injury to fish and wildlife resources. The results of this assessment indicate that injury to fish and wildlife resources has occurred throughout the assessment area, with up to five distinct lines of evidence demonstrating injury within the various reaches. Based on the frequency of exceedance of the benchmarks for assessing sediment and tissue chemistry data, total polychlorinated biphenyls is the primary bioaccumulative contaminant of concern in the assessment area. It is important to note, however, that this assessment was restricted by the availability of published bioaccumulation-based sediment quality guidelines, tissue residue guidelines, and other benchmarks of sediment quality conditions. The availability of chemistry data for tissues also restricted this assessment in certain reaches of the assessment area. Furthermore, insufficient information was located to facilitate identification of the substances that are causing or substantially contributing to effects on fish (i.e., sediment toxicity, impaired fish health, or impaired fish community structure). Therefore, substances not included on the list of COCs cannot necessarily be considered to be of low priority with respect to sediment injury (e.g., metals, polycyclic aromatic hydrocarbons, alkanes, alkenes, organochlorine pesticides, phthalates, dioxins, and furans, etc.).

Partitioning of Total Dissolved Salts, Boron and Selenium in Pariette Wetland Water, Sediments and Benthic Organisms

NASA Astrophysics Data System (ADS)

Jacobson, A. R.; Jones, C. P.; Vasudeva, P.; Powelson, D.; Grossl, P.

2014-12-01

The Pariette Wetlands located in the Uinta Basin, UT, were developed by the BLM in part to mitigate salinity associated with irrigation drainage and runoff from flowing to the Green River, a tributary of the Colorado River. The wetlands are fed by runoff from upstream agricultural irrigation, and natural subsurface and overland flow through the Uintah formation, which is seleniferous, and saline. Concentrations of Total Dissolved Salts (TDS), boron (B) and selenium (Se) in the wetlands exceed the total maximum daily loads developed to meet the US EPA's water quality planning and management regulations (40CFR 130). This is of concern because the wetlands are home to populations of migratory birds, waterfowl, raptors, and numerous small mammals. A mass balance of the Se concentrations of water flowing into and out of the wetlands indicates that 80% of the Se is stored or lost within the system. Additional data suggest that the majority of the Se is associated with the sediments. Little information is available regarding the TDS and B. Therefore we will determine the whether B and other salts are accumulating in the wetland systems, and if so where. We sampled water, sediment, benthic organisms, and wetland plants, in 4 of the 23 ponds from the flood control inlet to water flowing out to the Green River. Sediments were collected at 3 depths (0-2 cm, 2-7 cm, and 7+ cm) at 3-4 locations within each pond including the inlet, outlet and at least one site near a major wetland plant community. Benthic organisms were sampled from the 0-2 cm and 2-7 cm sediment layers. Sediment and organism samples were digested with HNO3 and HClO4 prior to analysis of total Se by HGAAS. Hot water extractable B and DPTA extractable B were analyzed by ICP-AES. TDS was estimated from EC in the sediment and organisms extracts and direct analysis in the water. Preliminary results found that Se in the sediments decreases with depth. Se concentrations in the benthic organisms is approximately 4 times higher than in the associated sediments. Data from this study will contribute to a water quality risk assessment to the wetland fish and birds.

Spatial and temporal variations in landscape evolution: historic and longer-term sediment flux through global catchments

USGS Publications Warehouse

Covault, Jacob A.; Craddock, William H.; Romans, Brian W.; Fildani, Andrea; Gosai, Mayur

2013-01-01

Sediment generation and transport through terrestrial catchments influence soil distribution, geochemical cycling of particulate and dissolved loads, and the character of the stratigraphic record of Earth history. To assess the spatiotemporal variation in landscape evolution, we compare global compilations of stream gauge–derived () and cosmogenic radionuclide (CRN)–derived (predominantly 10Be; ) denudation of catchments (mm/yr) and sediment load of rivers (Mt/yr). Stream gauges measure suspended sediment loads of rivers during several to tens of years, whereas CRNs provide catchment-integrated denudation rates at 102–105-yr time scales. Stream gauge–derived and CRN-derived sediment loads in close proximity to one another (<500 km) exhibit broad similarity ( stream gauge samples; CRN samples). Nearly two-thirds of CRN-derived sediment loads exceed historic loads measured at the same locations (). Excessive longer-term sediment loads likely are a result of longer-term recurrence of large-magnitude sediment-transport events. Nearly 80% of sediment loads measured at approximately the same locations exhibit stream gauge loads that are within an order of magnitude of CRN loads, likely as a result of the buffering capacity of large flood plains. Catchments in which space for deposition exceeds sediment supply have greater buffering capacity. Superior locations in which to evaluate anthropogenic influences on landscape evolution might be buffered catchments, in which temporary storage of sediment in flood plains can provide stream gauge–based sediment loads and denudation rates that are applicable over longer periods than the durations of gauge measurements. The buffering capacity of catchments also has implications for interpreting the stratigraphic record; delayed sediment transfer might complicate the stratigraphic record of external forcings and catchment modification.

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the lower-Colorado River valley, Arizona, California, and Nevada

USGS Publications Warehouse

Radtke, D.B.; Kepner, W.G.; Effertz, R.J.

1988-01-01

The Lower Colorado River Valley Irrigation Drainage Project area included the Colorado River and its environs from Davis Dam to just above Imperial Dam. Water, bottom sediment, and biota were sampled at selected locations within the study area and analyzed for selected inorganic and synthetic organic constituents that are likely to be present at toxic concentrations. With the exceptions of selenium and DDE, this study found sampling locations to be relatively free of large concentrations of toxic constituents that could be a threat to humans, fish, and wildlife. Selenium was the only inorganic constituent to exceed any existing standard, criterion, or guideline for protection of fish and wildlife resources. Concentrations of DDE in double-crested cormorants, however, exceeded the criterion of 1.0 microgram per gram established by the National Academy of Sciences and the National Academy of Engineering for DDT and its metabolites for protection of wildlife. Dissolved-selenium concentrations in water from the lower Colorado River appear to be derived from sources above Davis Dam. At this time, therefore , agricultural practices in the lower Colorado River valley do not appear to exacerbate selenium concentrations. This fact, however, does not mean that the aquatic organisms and their predators are not in jeopardy. Continued selenium loading to the lower Colorado environment could severely affect important components of the ecosystem. (Author 's abstract)

Undergraduates in the lab: Analyzing metal and organic contaminants in oysters and sediments from southeastern North Carolina

NASA Astrophysics Data System (ADS)

Mead, R. N.; Kipp, L. E.; Liberatore, H.; Sherard, S.; Steagall, M.; Skrabal, S. A.

2016-02-01

A state-funded project to analyze a suite of metal and organic contaminants in oyster tissues and ambient sediments was carried out nearly exclusively by over 10 undergraduates at the University of North Carolina Wilmington. This study will present Concentrations of various trace metals (most notably arsenic, copper, mercury, and zinc) and organic contaminants (polycyclic aromatic hydrocarbons and the antibacterial, triclosan) have been determined in oyster tissues and adjacent sediments in New Hanover and Brunswick counties, southeastern North Carolina. Trace metals that exceeded national median levels at multiple sites in this study included arsenic, copper, and zinc. Elevated levels of arsenic (exceeding the national median and, often, the national 85th percentiles) in oyster tissues are characteristic of much of the southeastern United States; these elevations are attributed to high natural background levels in the underlying bedrock and sediments as well as historical contamination by arsenic-containing agricultural pesticides. Another metal of national concern is mercury; however, concentrations of this metal were mostly at the national median for oyster tissue. Polycyclic aromatic hydrocarbons (PAHs) barely exceeded or were near the national median at only 3 sites, 2 in Lockwood Folly estuary, Brunswick County and 1 at Bradley Creek, New Hanover County. Concentrations at the remaining sites were 4 to >10 times less than the national median. Triclosan, an antibacterial compound used in many consumer products, was found in oyster tissues and sediments at the 4 sites at which it was examined. Oyster tissues contained triclosan at levels 2 to 43 times as high as adjacent sediments, indicating its bioaccumulation potential. Levels of metals and PAHs in oyster tissues are consistently elevated near more urbanized areas but are unlikely to be at levels harmful for human consumption.

Suspended sediment transport in the freshwater reach of the Hudson river estuary in eastern New York

USGS Publications Warehouse

Wall, G.R.; Nystrom, E.A.; Litten, S.

2008-01-01

Deposition of Hudson River sediment into New York Harbor interferes with navigation lanes and requires continuous dredging. Sediment dynamics at the Hudson estuary turbidity maximum (ETM) have received considerable study, but delivery of sediment to the ETM through the freshwater reach of the estuary has received relatively little attention and few direct measurements. An acoustic Doppler current profiler was positioned at the approximate limit of continuous freshwater to develop a 4-year time series of water velocity, discharge, suspended sediment concentration, and suspended sediment discharge. This data set was compared with suspended sediment discharge data collected during the same period at two sites just above the Hudson head-of-tide (the Federal Dam at Troy) that together represent the single largest source of sediment entering the estuary. The mean annual suspended sediment-discharge from the freshwater reach of the estuary was 737,000 metric tons. Unexpectedly, the total suspended sediment discharge at the study site in November and December slightly exceeded that observed during March and April, the months during which rain and snowmelt typically result in the largest sediment discharge to the estuary. Suspended sediment discharge at the study site exceeded that from the Federal Dam, even though the intervening reach appears to store significant amounts of sediment, suggesting that 30-40% of sediment discharge observed at the study site is derived from tributaries to the estuary between the Federal Dam and study site. A simple model of sediment entering and passing through the freshwater reach on a timescale of weeks appears reasonable during normal hydrologic conditions in adjoining watersheds; however, this simple model may dramatically overestimate sediment delivery during extreme tributary high flows, especially those at the end of, or after, the "flushing season" (October through April). Previous estimates of annual or seasonal sediment delivery from tributaries and the Federal Dam to the ETM and harbor may be high for those years with extreme tributary high-flow events. ?? 2008 Coastal and Estuarine Research Federation.

Use of enzymatic tools for biomonitoring inorganic pollution in aquatic sediments: a case study (Bor, Serbia)

PubMed Central

2013-01-01

Background Sediment bacterial communities are key players in biogeochemical cycling of elements in the aquatic environment. Copper mining, smelting, and processing operations located in Bor area (Serbia) are major environmental hot spots in the lower Danube Basin and Western Balkans. In the present study, we evaluate the influence of trace element (TE) concentration in sediments and physico-chemical properties of water on sediment microbial communities in water streams adjacent to the Copper Smelter Complex Bor (RTB Bor, Serbia). The degree to which metabolic activities of bacterial biota inhabiting differently polluted sites is inhibited by inorganic pollution were compared using selected enzymatic bioindicators. Results Cu, Zn, Pb, and As concentrations systematically exceeded the target values for metal loadings in aquatic sediments. Water electrical conductivity (WEC) followed the same pattern of spatial variation, irrespective of season. Interestingly, the most intense enzymatic activity occurred at the reference site although this site showed the greatest TE levels in aquatic sediments. Catalase activity (CA), potential dehydrogenase activity (PDA), actual dehydrogenase activity (ADA), urease activity (UA), and phosphatase activity (PA) in aquatic sediments displayed heterogeneous patterns of spatio-temporal variation. Inorganic pollution greatly affected CA, ADA, and PDA, but much less so UA and PA. Canonical correlation analysis showed that pH and WEC were the strongest determinants of enzymatic activity in bacterial biota, with the latter variable being reversely correlated with the enzymatic indicator of sediment quality (EISQ). The median values of EISQ increased with distance from the major sources of pollution. In addition, it was found that sites with different degrees of inorganic pollution can be appropriately classified by applying cluster analysis to EISQ, TE levels in sediments, and physico-chemical properties of water. Conclusions Because EISQ can precisely identify changes in overall enzymatic activity of sediment bacterial communities, this enzymatic bioindicator has a great potential for biomonitoring the current status of inorganic pollution in aquatic ecosystems. PMID:23536970

Concentrations of chlorinated organic compounds in biota and bed sediment in streams of the San Joaquin Valley, California

USGS Publications Warehouse

Brown, L.R.

1997-01-01

Samples of resident biota and bed sediments were collected in 1992 from 18 sites on or near the floor of the San Joaquin Valley, California, for analysis of 33 organochlorine compounds. The sites were divided into five groups on the basis of physiographic region and land use. Ten compounds were detected in tissue, and 15 compounds were detected in bed sediment. The most frequently detected compound in both media was p,p'-DDE. Concentrations of ??DDT (sum of o,p'- and p, p' forms of DDD, DDE, and DDT) were statistically different among groups of sites for both tissue and sediment (Kruskal- Wallis, p < 0.05). Concentrations in both media were highest in streams draining the west side of the valley. Concentrations of ??DDT in tissue were significantly correlated with specific conductance, pH, and total alkalinity (p < 0.05), which are indicators of the proportion of irrigation return flows in stream discharge. Concentrations in sediment on a dry-weight basis were not correlated with these water-quality parameters, but total organic carbon (TOC) normalized concentrations were significantly correlated with specific conductance and pH (p < 0.05). Regressions of the concentration of ??DDT in tissue, as a function of ??DDT in bed sediment, were significant and explained up to 76% of the variance in the data. The concentration of ??DDT in sediment may be related to mechanisms of soil transport to surface water with bioavailability of compounds related to the concentration of TOC in sediment. The results of this study did not indicate any clear advantage to using either bed sediment or tissues in studies of organochlorine chemicals in the environment. Some guidelines for protection of fish and wildlife were exceeded. Concentrations of organochlorine chemicals in biota, and perhaps sediment, have declined from concentrations measured in the 1970s and 1980s, but remain high compared to other regions of the United States.

Floods of May 1978 in southeastern Montana and northeastern Wyoming

USGS Publications Warehouse

Parrett, Charles; Carlson, D.D.; Craig, G.S.; Chin, E.H.

1984-01-01

Heavy rain and some snow fell on previously saturated ground over southeastern Montana and northeastern Wyoming during May 16-19, 1978. The maximum amount of 7.60 inches within a 72-hour period observed at Lame Deer, Montana, set a record for the month of May in that region. Heavy flooding occurred in the drainages of the Yellowstone River and its tributaries as well as the Belle Fourche, Cheyenne, and North Platte Rivers. The previous maximum flood of record was exceeded at 48 gaged sites, and the 1-percent chance flood was equaled or exceeded at 24 sites. Flood damage was extensive, exceeding $33 million. Nineteen counties in the two States were declared major disaster areas. Mean daily suspended-sediment discharges exceeded previously recorded maximum mean daily values at four sites on the Powder River. The maximum daily suspended-sediment discharge of 2,810,000 tons per day occurred on May 20 at the Site Powder River near Arvada, Wyoming. (USGS)

High Levels of Sediment Contamination Have Little Influence on Estuarine Beach Fish Communities

PubMed Central

McKinley, Andrew C.; Dafforn, Katherine A.; Taylor, Matthew D.; Johnston, Emma L.

2011-01-01

While contaminants are predicted to have measurable impacts on fish assemblages, studies have rarely assessed this potential in the context of natural variability in physico-chemical conditions within and between estuaries. We investigated links between the distribution of sediment contamination (metals and PAHs), physico-chemical variables (pH, salinity, temperature, turbidity) and beach fish assemblages in estuarine environments. Fish communities were sampled using a beach seine within the inner and outer zones of six estuaries that were either heavily modified or relatively unmodified by urbanization and industrial activity. All sampling was replicated over two years with two periods sampled each year. Shannon diversity, biomass and abundance were all significantly higher in the inner zone of estuaries while fish were larger on average in the outer zone. Strong differences in community composition were also detected between the inner and outer zones. Few differences were detected between fish assemblages in heavily modified versus relatively unmodified estuaries despite high concentrations of sediment contaminants in the inner zones of modified estuaries that exceeded recognized sediment quality guidelines. Trends in species distributions, community composition, abundance, Shannon diversity, and average fish weight were strongly correlated to physico-chemical variables and showed a weaker relationship to sediment metal contamination. Sediment PAH concentrations were not significantly related to the fish assemblage. These findings suggest that variation in some physico-chemical factors (salinity, temperature, pH) or variables that co-vary with these factors (e.g., wave activity or grain size) have a much greater influence on this fish assemblage than anthropogenic stressors such as contamination. PMID:22039470

Assessment of heavy metals in sediment of Aguamilpa Dam, Mexico.

PubMed

Rangel-Peraza, Jesús Gabriel; de Anda, José; González-Farías, Fernando A; Rode, Michael; Sanhouse-García, Antonio; Bustos-Terrones, Yaneth A

2015-03-01

The Aguamilpa Dam is part of the reservoir cascade system formed by four reservoirs in the middle and lower part of the Santiago River. For decades, this system has received urban and industrial wastewater from the metropolitan area of Guadalajara and the runoff of agricultural fields located in the river basin. The present study was carried out to obtain a preliminary assessment on the concentration distribution of heavy metals (Al, Ba, Cd, Cr, Cu, Fe, Hg, Mg, Ni, Pb, and Zn) in surface sediments of the Aguamilpa reservoir collected from 10 sampling stations. The metal concentrations (mg kg(-1)) in the sampling stations ranged as follows: Al, 27,600-7760; Ba, 190.0-15.9; Cd, 0.27-0.02; Cr, 18.30-0.22; Cu, 60.80-0.79; Fe, 15,900-4740; Hg, 0.04-0.01; Mg, 7590-8.05; Ni, 189.00-0.24; Pb, 13.6-1.64; and Zn, 51.8-14.8. Significant spatial variation in concentrations was observed for Al, Fe, and Pb. Sediment pollution was evaluated using the enrichment factor, the geo-accumulation index, the pollution load index, and sediment quality guidelines. Based on geo-accumulation and pollution load indexes, Aguamilpa sediments were found, in some sampling stations, as unpolluted to moderately polluted with Ni, Cd, Cu, and Mg. Enrichment factors showed that Cd is highly related to agricultural activities that take place in the surrounding areas of the Aguamilpa reservoir. Despite these results, none of the heavy metals evaluated exceeded international concentrations limits, indicating that the Aguamilpa reservoir surface sediments are not contaminated.

Concentration and spatial distribution of selected constituents in Detroit River bed sediment adjacent to Grassy Island, Michigan, August 2006

USGS Publications Warehouse

Hoard, C.J.

2008-01-01

In August 2006, the U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service, collected sediment?core samples from the bed of the Detroit River adjacent to Grassy Island. The goal of the sampling was to assess the distribution and concentration of chemical constituents in sediment adjacent to Grassy Island, which was operated from 1960 to 1982 as a confined disposal facility to hold dredge spoils. On August 31, 2006, seven samples were collected at four locations in the Detroit River on the north, south, east, and west sides of the island. Metals concentrations in the riverbed sediment tended to be higher on the west side of the island, whereas organic?compound concentrations were generally higher on the east side. Comparison of results from this sampling to concentrations reported in previous studies indicates that the concentrations of inorganic constituents, mainly metals, in the riverbed sediment around Grassy Island fell within the range of concentrations found regionally throughout the Detroit River and in most cases have lower mean and median values than found elsewhere regionally in the Detroit River. Comparison of results from the August 31, 2006, sampling to U.S. Environmental Protection Agency risk?based sediment?quality guidelines indicates that 18 organic constituents for which an ecological screening level (ESL), and (or) a threshold effect concentration (TEC), and (or) a probable effect concentration (PEC) has been defined exceeded one or more of these guidelines at least once. Further work would be needed to determine whether constituent concentrations in the river sediment are related to constituent runoff from Grassy Island.

Bacterial pathogen gene abundance and relation to recreational water quality at seven Great Lakes beaches.

PubMed

Oster, Ryan J; Wijesinghe, Rasanthi U; Haack, Sheridan K; Fogarty, Lisa R; Tucker, Taaja R; Riley, Stephen C

2014-12-16

Quantitative assessment of bacterial pathogens, their geographic variability, and distribution in various matrices at Great Lakes beaches are limited. Quantitative PCR (qPCR) was used to test for genes from E. coli O157:H7 (eaeO157), shiga-toxin producing E. coli (stx2), Campylobacter jejuni (mapA), Shigella spp. (ipaH), and a Salmonella enterica-specific (SE) DNA sequence at seven Great Lakes beaches, in algae, water, and sediment. Overall, detection frequencies were mapA>stx2>ipaH>SE>eaeO157. Results were highly variable among beaches and matrices; some correlations with environmental conditions were observed for mapA, stx2, and ipaH detections. Beach seasonal mean mapA abundance in water was correlated with beach seasonal mean log10 E. coli concentration. At one beach, stx2 gene abundance was positively correlated with concurrent daily E. coli concentrations. Concentration distributions for stx2, ipaH, and mapA within algae, sediment, and water were statistically different (Non-Detect and Data Analysis in R). Assuming 10, 50, or 100% of gene copies represented viable and presumably infective cells, a quantitative microbial risk assessment tool developed by Michigan State University indicated a moderate probability of illness for Campylobacter jejuni at the study beaches, especially where recreational water quality criteria were exceeded. Pathogen gene quantification may be useful for beach water quality management.

Evaluating sedimentation problems in activated sludge treatment plants operating at complete sludge retention time.

PubMed

Amanatidou, Elisavet; Samiotis, Georgios; Trikoilidou, Eleni; Pekridis, George; Taousanidis, Nikolaos

2015-02-01

Zero net sludge growth can be achieved by complete retention of solids in activated sludge wastewater treatment, especially in high strength and biodegradable wastewaters. When increasing the solids retention time, MLSS and MLVSS concentrations reach a plateau phase and observed growth yields values tend to zero (Yobs ≈ 0). In this work, in order to evaluate sedimentation problems arised due to high MLSS concentrations and complete sludge retention operational conditions, two identical innovative slaughterhouse wastewater treatment plants were studied. Measurements of wastewaters' quality characteristics, treatment plant's operational conditions, sludge microscopic analysis and state point analysis were conducted. Results have shown that low COD/Nitrogen ratios increase sludge bulking and flotation phenomena due to accidental denitrification in clarifiers. High return activated sludge rate is essential in complete retention systems as it reduces sludge condensation and hydraulic retention time in the clarifiers. Under certain operational conditions sludge loading rates can greatly exceed literature limit values. The presented methodology is a useful tool for estimation of sedimentation problems encountered in activated sludge wastewater treatment plants with complete retention time. Copyright © 2014 Elsevier Ltd. All rights reserved.

Establishing the environmental risk of metal contaminated river bank sediments

NASA Astrophysics Data System (ADS)

Lynch, Sarah; Batty, Lesley; Byrne, Patrick

2016-04-01

Climate change predictions indicate an increase in the frequency and duration of flood events along with longer dry antecedent conditions, which could alter patterns of trace metal release from contaminated river bank sediments. This study took a laboratory mesocosm approach. Chemical analysis of water and sediment samples allowed the patterns of Pb and Zn release and key mechanisms controlling Pb and Zn mobility to be determined. Trace metal contaminants Pb and Zn were released throughout flooded periods. The highest concentrations of dissolved Pb were observed at the end of the longest flood period and high concentrations of dissolved Zn were released at the start of a flood. These concentrations were found to exceed environmental quality standards. Key mechanisms controlling mobility were (i) evaporation, precipitation and dissolution of Zn sulphate salts, (ii) anglesite solubility control of dissolved Pb, (iii) oxidation of galena and sphalerite, (iv) reductive dissolution of Mn/Fe hydroxides and co-precipitation/adsorption with Zn. In light of climate change predictions these results indicate future scenarios may include larger or more frequent transient 'pulses' of dissolved Pb and Zn released to river systems. These short lived pollution episodes could act as a significant barrier to achieving the EU Water Framework Directive objectives.

Trace-element concentrations in streambed sediment across the conterminous United States

USGS Publications Warehouse

Rice, Karen C.

1999-01-01

Trace-element concentrations in 541 streambed-sediment samples collected from 20 study areas across the conterminous United States were examined as part of the National Water-Quality Assessment Program of the U.S. Geological Survey. Sediment samples were sieved and the <63-μm fraction was retained for determination of total concentrations of trace elements. Aluminum, iron, titanium, and organic carbon were weakly or not at all correlated with the nine trace elements examined:  arsenic, cadmium, chromium, copper, lead, mercury, nickel, selenium, and zinc. Four different methods of accounting for background/baseline concentrations were examined; however, normalization was not required because field sieving removed most of the background differences between samples. The sum of concentrations of trace elements characteristic of urban settings - copper, mercury, lead, and zinc - was well correlated with population density, nationwide. Median concentrations of seven trace elements (all nine examined except arsenic and selenium) were enriched in samples collected from urban settings relative to agricultural or forested settings. Forty-nine percent of the sites sampled in urban settings had concentrations of one or more trace elements that exceeded levels at which adverse biological effects could occur in aquatic biota.

Geochemistry and mercury contamination in receiving environments of artisanal mining wastes and identified concerns for food safety.

PubMed

Reichelt-Brushett, Amanda J; Stone, Jane; Howe, Pelli; Thomas, Bernard; Clark, Malcolm; Male, Yusthinus; Nanlohy, Albert; Butcher, Paul

2017-01-01

Artisanal small-scale gold mining (ASGM) using mercury (Hg) amalgamation has been occurring on Buru Island, Indonesia since early 2012, and has caused rapid accumulation of high Hg concentrations in river, estuary and marine sediments. In this study, sediment samples were collected from several sites downstream of the Mount Botak ASGM site, as well as in the vicinity of the more recently established site at Gogrea where no sampling had previously been completed. All sediment samples had total Hg (THg) concentrations exceeding Indonesian sediment quality guidelines and were up to 82 times this limit at one estuary site. The geochemistry of sediments in receiving environments indicates the potential for Hg-methylation to form highly bioavailable Hg species. To assess the current contamination threat from consumption of local seafood, samples of fish, molluscs and crustaceans were collected from the Namlea fish market and analysed for THg concentrations. The majority of edible tissue samples had elevated THg concentrations, which raises concerns for food safety. This study shows that river, estuary and marine ecosystems downstream of ASGM operations on Buru Island are exposed to dangerously high Hg concentrations, which are impacting aquatic food chains, and fisheries resources. Considering the high dietary dependence on marine protein in the associated community and across the Mollucas Province, and the short time period since ASGM operations commenced in this region, the results warrant urgent further investigation, risk mitigation, and community education. Copyright © 2016 Elsevier Inc. All rights reserved.

Metal accumulation in the greentail prawn, Metapenaeus bennettae, in Sydney and Port Hacking estuaries, Australia.

PubMed

Lewtas, K L M; Birch, G F; Foster-Thorpe, C

2014-01-01

Metal concentrations of the inshore greentail prawn, Metapenaeus bennettae, and surface sediments from locations within Sydney estuary and Port Hacking (Australia) were assessed for bioaccumulation and contamination. The current study aimed to assess metal concentrations in prawn tissue (tail muscle, exoskeleton, hepatopancreas and gills), relate whole body prawn tissue metal concentrations to sediment metal concentrations and animal size, as well as assess prawn consumption as a risk to human health. Metal concentrations were highest in sediment and prawns from contaminated locations (Iron Cove, Hen and Chicken Bay and Lane Cove) in Sydney estuary compared with the reference estuary (Port Hacking). Concentrations in sediments varied considerably between sites and between metals (As, Cd, Cr, Cu, Ni, Pb and Zn), and although concentrations exceeded Interim Sediment Quality Guideline-Low values, metals (As, Cd, Cr, Cu, Ni, Pb and Zn) were below Australian National Health and Medical Research Council human consumption guidelines in prawn tail muscle tissue. Metal concentrations in prawn tail muscle tissue were significantly different (p ≤ 0.05) amongst locations for Pb, Zn and Cd, and metal concentrations were generally highest in gills tissue, followed by the hepatopancreas, exoskeleton and tail muscle. The exoskeleton contained the highest Sr concentration; the hepatopancreas contained the highest As, Cu and Mo concentrations; and the gills contained the highest Al, Cr, Fe and Pb concentrations. Concentrations of Pb, As and Sr were significantly different (p ≤ 0.05) between size groups amongst locations.

Source identification, environmental risk assessment and human health risks associated with toxic elements present in a coastal industrial environment, India.

PubMed

Satapathy, Shreemayee; Panda, C R

2018-03-26

This study investigated the source and contamination levels of toxic elements (Cd, Cr, As, Pb, Ni and Hg) present in a coastal environment, Paradip-an industrial hub of the east coast of India. The ecological risk assessment indices and human exposure models were used to evaluate the pollution status. Enrichment factor indicated that all the metal(loid)s found in the sediment are mostly derived from the anthropogenic source. According to the sediment quality quotient, 8.33% of sediments have crossed the ERM limit for Ni that can be fatal to biota. Meanwhile, 66.66, 41.66 and 8.33% of sediments have exceeded PEL range for Cr, Ni and As, respectively, that can register frequent lethal toxicity to benthic biota. As had the highest potential ecological harm coefficient (Er f  > 80), and Hg had moderate ecological harm coefficient (40 < Er f  < 80). Summarily, the sediment quality of this site is moderate to heavily toxic to benthic organisms. The concentration of toxic metals in seawater was below the permissible limit (CCC and CMC) set by USEPA indicating that water is relatively safer for free floating aquatic biota. The health risk index of toxic metal (loid)s present in soils of the residential sites has confirmed that there is a severe non-carcinogenic threat for children (HI child > 1) and a borderline carcinogenic risk for both adult and children. THQ Cr possesses highest non-carcinogenic threat, which contributed approximately 50% to HI followed by THQ As . The contribution of carcinogenic risk of chromium (CR Cr ) to TCR is approximately 60%. Cr is the significant contaminant of this site that has highest health effects. Highest exposure risks were associated with ingestion pathway accounting for about 85% of the total for most of the elements.

Occurrence of Selected Nutrients, Trace Elements, and Organic Compounds in Streambed Sediment in the Lower Chena River Watershed near Fairbanks, Alaska, 2002-03

USGS Publications Warehouse

Kennedy, Ben W.; Hall, Cassidee C.

2009-01-01

In 2002-03, the U.S. Geological Survey collected samples of streambed sediment at 18 sites in the lower Chena River watershed for analysis of selected nutrients, traces elements, and organic compounds. The purpose of the project was to provide Federal, State, and local agencies as well as neighborhood committees, with information for consideration in plans to improve environmental conditions in the watershed. The exploratory sampling program included analysis of streambed sediment from the Chena River and Chena Slough, a tributary to the Chena River. Results were compared to streambed-sediment guidelines for the protection of aquatic life and to 2001-02 sediment data from Noyes Slough, a side channel of the lower Chena River. The median total phosphorus concentration in Chena Slough sediment samples, 680 milligrams per kilogram (mg/kg), was two orders of magnitude greater than median total phosphorus concentration in Chena River sediment samples of 5.2 mg/kg. Median concentrations of chloride and sulfate also were greater in Chena Slough samples. Low concentrations of nitrate were detected in most of the Chena Slough samples; nitrate concentrations were below method reporting limits or not detected in Chena River sediment samples. Streambed-sediment samples were analyzed for 24 trace elements. Arsenic, nickel, and zinc were the only trace elements detected in concentrations that exceeded probable-effect levels for the protection of aquatic life. Concentrations of arsenic in Chena Slough samples ranged from 11 to 70 mg/kg and concentrations in most of the samples exceeded the probable-effect guideline for arsenic of 17 mg/kg. Arsenic concentrations in samples from the Chena River ranged from 9 to 12 mg/kg. The background level for arsenic in the lower Chena River watershed is naturally elevated because of significant concentrations of arsenic in local bedrock and ground water. Sources of elevated concentrations of zinc in one sample, and of nickel in two samples, are unknown. With the exception of elevated arsenic levels in samples from Chena Slough, the occurrence and concentration of trace elements in the streambed sediments of Chena Slough and Chena River were similar to those in Noyes Slough sediment. Sediment samples were analyzed for 78 semivolatile organic compounds and 32 organochlorine pesticides and polychlorinated biphenyls (PCBs). Low concentrations of dimethylnaphthalene and p-Cresol were detected in most Chena Slough and Chena River sediment samples. The number of semivolatile organic compounds detected ranged from 5 to 21 in most Chena Slough sediment samples. In contrast, three or fewer semivolatile organic compounds were detected in Chena River sediment samples, most likely because chemical-matrix interference resulted in elevated reporting limits for organochlorine compounds in the Chena River samples. Low concentrations of fluoranthene, pyrene, and phenanthrene were detected in Chena Slough sediment. Relatively low concentrations of DDT or its degradation products, DDD and DDE, were detected in all Chena Slough samples. Concentrations of total DDT (DDT+DDD+DDE) in two Chena Slough sediment samples exceeded the effectsrange median aquatic-life criteria of 46.1 micrograms per kilogram (ug/kg). DDT concentrations in Chena River streambed-sediment samples were less than 20 ug/kg. Low concentrations of PCB were detected in two Chena Slough streambed-sediment samples. None of the concentrations of the polychlorinated biphenyls or semivolatile organic compounds for which the samples were analyzed exceeded available guidelines for the protection of aquatic life. With the exception of elevated total DDT in two Chena Slough samples, the occurrence and concentration of organochlorine compounds in Chena Slough and Chena River sediment were similar to those in samples collected from Noyes Slough in 2001-02.

Spatiotemporal trend analysis of metal concentrations in sediments of a residential California stream with toxicity and regulatory implications.

PubMed

Hall, Lenwood W; Anderson, Ronald D; Killen, William D

2017-06-07

The objective of this study was to determine if concentrations of arsenic, cadmium, chromium, copper, lead, nickel and zinc measured in the sediments of a residential stream in California (Pleasant Grove Creek) have changed temporally or spatially from 2006 to 2016. Threshold Effect Levels (TELs), conservative ecological effects benchmarks, and exceedances for the seven metals were also evaluated over the 11-year time period to provide insight into potential metal toxicity to resident benthic communities. In addition, the bioavailability of metals in sediments was also determined by calculating Simultaneous Extracted Metal/Acid Volatle Sulfide (SEM/AVS) ratios to allow an additional assessment of toxicity. Regulatory implications of this data set and the role of metal toxicity are also discussed. Stream-wide temporal trend analysis showed no statistically significant trends for any of the metals. However, spatial analysis for several sites located near storm drains did show a significant increase for most metals over the 11-year period. TEL exceedances during the 7 years of sampling, spanning 2006-2016, were reported for all metals with the number of exceedances ranging from 47 for copper and zinc to 1 for lead. A spatial analysis showed that the highest number of TEL exceedances and the highest number of SEM/AVS ratios greater than one with at least one metal exceeding a TEL occurred at upstream sites. The potentially toxic metal concentrations reported in Pleasant Grove Creek should be used in the 303 (d) listing process for impaired water bodies in California.

Water quality in the Old Plantation Water Control District, Broward County, Florida; progress report, July 1976-June 1977

USGS Publications Warehouse

Russell, Gary M.; Hanson, Chris E.; Pitt, William A.J.

1978-01-01

Water quality in the Old Plantation Water Control District in Broward County, Florida has been affected by effluent from sewage-treatment plants, agriculture, and storm-water runoff. Effect of effluent from sewage-treatment plants on water quality was evident at 3 sites where concentrations of nutrients and bacteria in the Broward County canals exceeded State standards of 2,400 colonies per 100 milliliters for total coliform bacteria. At 2 of the 3 sites the fecal coliform/fecal streptococcus ratios indicated possible human contamination. The effect of agriculture on water quality was evident where relatively high levels of chlorinated hydrocarbon insecticides had concentrated in the bottom sediments, of the canals. For example, DDD reached levels of 330 micrograms per kilogram at one site. The effects of storm-water runoff on water quality were detected during the wet season when concentrations of several trace elements increased. For example, zinc averaged 30 micrograms per milliliter in the wet season compared with 20 micrograms per milliliter during the dry season. (Woodard-USGS)

Reconstructing the history of mining and remediation in the Coeur d'Alene, Idaho Mining District using lake sediments.

PubMed

Morra, Matthew J; Carter, Meghan M; Rember, William C; Kaste, James M

2015-09-01

Mining that began in the late 1800s intensified during World War II contaminating Lake Coeur d'Alene sediments with potentially toxic elements. We used 80y of the sediment record to reconstruct metal(loid) loadings to the lake and quantitatively evaluate the effectiveness of tailings management. Sediment core analysis for pollen, chronological markers, and metal(loid)s permitted stratigraphic reconstruction showing that contaminant loading decreased after tailings pond construction, but that most metal(loid) concentrations exceed recommended limits. Arsenic concentrations (250-450 mg kg(-)(1)) at the sediment-water interface are potentially toxic; however, low P concentrations in recent sediments (1.0-1.4 mg kg(-)(1)) inhibit eutrophication and the concomitant release of soluble As. Zinc (3 g kg(-)(1)), Cd (10 mg kg(-)(1)), Ag (10 mg kg(-)(1)), and Cu (90 mg kg(-)(1)) concentrations are now lower than in sediments deposited during active mining, but remain an environmental concern. Sedimentary Cr and Pb concentrations have not changed in the last 50y, because tailings continue to enter the lake. Although modern Cr concentrations (40 mg kg(-)(1)) are unlikely to cause toxicity, current Pb concentrations (4 g kg(-)(1)) exceed acceptable limits, creating challenges for remediation. Strategies to manage other mining-contaminated watersheds should include consideration of elemental differences when evaluating remediation effectiveness. Copyright © 2015 Elsevier Ltd. All rights reserved.

Chemical and biological quality of surface water at the U.S. Army Atterbury Reserve Forces Training Area near Edinburgh, Indiana, September 2000 through July 2001

USGS Publications Warehouse

Risch, Martin R.

2004-01-01

A base-wide assessment of surface-water quality at the U.S. Army Atterbury Reserve Forces Training Area near Edinburgh, Indiana, examined short-term and long-term quality of surface water flowing into, across, and out of a 33,760-acre study area. The 30-day geometric-mean concentrations of fecal-indicator bacteria (Escherichia coli) in water samples from all 16 monitoring sites on streams in the study area were greater than the Indiana recreational water-quality standard. None of the bacteria concentrations in samples from four lakes exceeded the standard. Half the samples with bacteria concentrations greater than the single-sample standard contained chemical tracers potentially associated with human sewage. Increased turbidity of water samples was related statistically to increased bacteria concentration. Lead concentrations ranging from 0.5 to 2.0 micrograms per liter were detected in water samples at seven monitoring sites. Lead in one sample collected during high-streamflow conditions was greater than the calculated Indiana water-quality standard. With the exception of Escherichia coli and lead, 211 of 213 chemical constituents analyzed in water samples did not exceed Indiana water-quality standards. Out of 131 constituents analyzed in streambed-sediment and fish-tissue samples from three sites in the Common Impact Area for weapons training, the largest concentrations overall were detected for copper, lead, manganese, strontium, and zinc. Fish-community integrity, based on diversity and pollution tolerance, was rated poor at one of those three sites. Compared with State criteria, the fish-community data indicated 8 of 10 stream reaches in the study area could be categorized as "fully supporting" aquatic-life uses.

Reconnaissance of chemical and biological quality in the Owyhee River from the Oregon State line to the Owyhee Reservoir, Oregon, 2001–02

USGS Publications Warehouse

Hardy, Mark A.; Maret, Terry R.; George, David L.

2004-01-01

The Owyhee River drains an extremely rugged and sparsely populated landscape in northern Nevada, southwestern Idaho, and eastern Oregon. Most of the segment between the Oregon State line and Lake Owyhee is part of the National Wild and Scenic Rivers System, and few water-quality data exist for evaluating environmental impacts. As a result, the U.S. Geological Survey, in cooperation with the Bureau of Land Management, assessed this river segment to characterize chemical and biological quality of the river, identify where designated beneficial uses are met and where changes in stream quality occur, and provide data needed to address activities related to environmental impact assessments and Total Maximum Daily Loads. Water-quality issues identified at one or more sites were water temperature, suspended sediment, dissolved oxygen, pH, nutrients, trace elements, fecal bacteria, benthic invertebrate communities, and periphyton communities. Generally, summer water temperatures routinely exceeded Oregon's maximum 7-day average criteria of 17.8 degrees Celsius. The presence of few coldwater taxa in benthic invertebrate communities supports this observation. Suspended-sediment concentrations during summer base flow were less than 10 milligrams per liter (mg/L). Dissolved solids concentrations ranged from 46 to 222 mg/L, were highest during base flow, and tended to increase in a downstream direction. Chemical compositions of water samples indicated that large proportions of upland-derived water extend to the lower reaches of the study area during spring runoff. Dissolved fluoride and arsenic concentrations were highest during base flow and may be a result of geothermal springs discharging to the river. No dissolved selenium was detected. Upstream from the Rome area, spring runoff concentrations of suspended sediment ranged from 0 to 52 mg/L, and all except at the Three Forks site were typically below 20 mg/L. Stream-bottom materials from the North Fork Owyhee River, an area with no mines, were enriched with nine trace elements, which indicates that this basin may be a natural source of these elements. Near Rome, the part of the study area not included in the National Wild and Scenic Rivers System, land-use impacts resulted in elevated populations of Escherichia coli bacteria (E. coli) during base flow and elevated concentrations of nitrogen and phosphorus during spring runoff. Sites in this area had the highest numbers of benthic invertebrates; the fewest Ephemeroptera, Plecoptera, and Trichoptera taxa; and the highest Hilsenhoff Biotic Index scores. These results suggest degraded stream quality. Periphyton communities at sites in this area approached nuisance levels and could cause significant dissolved oxygen depletions and pH values that exceed Oregon's recommended criteria. Stream-bottom materials from Jordan Creek were enriched with mercury and manganese, which probably were ultimately caused by past mining in that basin. Below Crooked Creek, elevated suspended sediment concentrations (142 mg/L), phosphorus concentrations (0.23 mg/L), and E. coli populations (370 most probable number per 100 milliliters) during the largest spring runoff event could be the result of inputs at the lower end of Jordan Valley and (or) inputs from Crooked Creek. The New Zealand Mud Snail, a highly competitive gastropod introduced to the Snake River in the 1980s, was collected just downstream from the Crooked Creek confluence.

Preliminary assessment of contaminants in the sediment and organisms of the Swartkops Estuary, South Africa.

PubMed

Nel, L; Strydom, N A; Bouwman, H

2015-12-30

Urban estuaries are susceptible to metal and organic pollution, yet most remain understudied in South Africa with respect to the presence, concentrations and distribution of contaminants. Metal and organic chemical concentrations were assessed in sediment and organisms from different trophic levels in the lower reaches of the Swartkops Estuary. Species sampled included Upogebia africana (Malacostraca: Upogebiidae), Gilchristella aestuaria (Clupeidae), Psammogobius knysnaensis (Gobiidae), Mugil cephalus (Mugilidae), Lichia amia (Carangidae), Argyrosomus japonicus (Sciaenidae), Pomadasys commersonnii (Haemulidae) and Larus dominicanus (Avis: Laridae). This study is one of the most comprehensive studies to date assessing pollution levels in a food web in estuaries in South Africa. Due to biomagnification, higher concentrations of Arsenic, Lead, Mercury and Cadmium were found in the juveniles stages of popular angling fishes. High concentrations of Cadmium and Arsenic were recorded in the liver of L. amia, A. japonicus and P. commersonnii which exceed international quality food guidelines. Eggs from the gull, L. dominicanus, showed detectable concentrations of PCBs. Copyright © 2015 Elsevier Ltd. All rights reserved.

Metallothionein Induction as Indicator of Low Level Metal Exposure to Aquatic Macroinvertebrates from a Relatively Unimpacted River System in South Africa.

PubMed

Kemp, M; Wepener, V; de Kock, K N; Wolmarans, C T

2017-12-01

The Marico River is relatively unaffected by anthropogenic activities. However, metal concentrations-mainly from natural sources-occasionally exceed environmental quality guidelines. Macroinvertebrates are capable to react to these metals through processes such as the induction of metallothioneins (MTs). The aims of this study were to determine whether the induction of MTs can be used as indicator of natural metal exposure in not anthropogenically impacted systems and whether there are relationships between metal concentrations in water, sediment and macroinvertebrates and concomitant MT levels. Positive correlations were found between metals in sediment and macroinvertebrates, while there were no correlations between metal concentrations in water and macroinvertebrates. Even in a not anthropogenically impacted system, a positive correlation existed between trace metal bioaccumulation (e.g. Ni, Pb, Zn) in macroinvertebrates and the induction of MTs. There were, however, no correlations between MTs and bioaccumulation of earth metals (e.g. Al, Fe, Mn, Ti).

Hospital and urban effluent waters as a source of accumulation of toxic metals in the sediment receiving system of the Cauvery River, Tiruchirappalli, Tamil Nadu, India.

PubMed

Devarajan, Naresh; Laffite, Amandine; Ngelikoto, Patience; Elongo, Vicky; Prabakar, Kandasamy; Mubedi, Josué I; Piana, Pius T M; Wildi, Walter; Poté, John

2015-09-01

Hospital and urban effluents contain a variety of toxic and/or persistent substances in a wide range of concentrations, and most of these compounds belong to the group of emerging contaminants. The release of these substances into the aquatic ecosystem can lead to the pollution of water resources and may place aquatic organisms and human health at risk. Sediments receiving untreated and urban effluent waters from the city of Tiruchirappalli in the state of Tamil Nadu, India, are analyzed for potential environmental and human health risks. The sediment samples were collected from five hospital outlet pipes (HOP) and from the Cauvery River Basin (CRB) both of which receive untreated municipal effluent waters (Tiruchirappalli, Tamil Nadu, India). The samples were characterized for grain size, organic matter, toxic metals, and ecotoxicity. The results highlight the high concentration of toxic metals in HOP, reaching values (mg kg(-1)) of 1851 (Cr), 210 (Cu), 986 (Zn), 82 (Pb), and 17 (Hg). In contrast, the metal concentrations in sediments from CRB were lower than the values found in the HOP (except for Cu, Pb), with maximum values (mg kg(-1)) of 75 (Cr), 906 (Cu), 649 (Zn), 111 (Pb), and 0.99 (Hg). The metal concentrations in all sampling sites largely exceed the Sediment Quality Guidelines (SQGs) and the Probable Effect Concentration (PEC) for the Protection of Aquatic Life recommendation. The ecotoxicity test with ostracods exposed to the sediment samples presents a mortality rate ranging from 22 to 100 % (in sediments from HOP) and 18-87 % (in sediments from CRB). The results of this study show the variation of toxic metal levels as well as toxicity in sediment composition related to both the type of hospital and the sampling period. The method of elimination of hospital and urban effluents leads to the pollution of water resources and may place aquatic organisms and human health at risk.

Organochlorine compounds and trace elements in fish tissue and bed sediments in the lower Snake River basin, Idaho and Oregon

USGS Publications Warehouse

Clark, Gregory M.; Maret, Terry R.

1998-01-01

Fish-tissue and bed-sediment samples were collected to determine the occurrence and distribution of organochlorine compounds and trace elements in the lower Snake River Basin. Whole-body composite samples of suckers and carp from seven sites were analyzed for organochlorine compounds; liver samples were analyzed for trace elements. Fillets from selected sportfish were analyzed for organochlorine compounds and trace elements. Bed-sediment samples from three sites were analyzed for organochlorine compounds and trace elements. Twelve different organochlorine compounds were detected in 14 fish-tissue samples. All fish-tissue samples contained DDT or its metabolites. Concentrations of total DDT ranged from 11 micrograms per kilogram wet weight in fillets of yellow perch from C.J. Strike Reservoir to 3,633 micrograms per kilogram wet weight in a whole-body sample of carp from Brownlee Reservoir at Burnt River. Total DDT concentrations in whole-body samples of sucker and carp from the Snake River at C.J. Strike Reservoir, Snake River at Swan Falls, Snake River at Nyssa, and Brownlee Reservoir at Burnt River exceeded criteria established for the protection of fish-eating wildlife. Total PCB concentrations in a whole-body sample of carp from Brownlee Reservoir at Burnt River also exceeded fish-eating wildlife criteria. Concentrations of organochlorine compounds in whole-body samples, in general, were larger than concentrations in sportfish fillets. However, concentrations of dieldrin and total DDT in fillets of channel catfish from the Snake River at Nyssa and Brownlee Reservoir at Burnt River, and concentrations of total DDT in fillets of smallmouth bass and white crappie from Brownlee Reservoir at Burnt River exceeded a cancer risk screening value of 10-6 established by the U.S. Environmental Protection Agency. Concentrations of organochlorine compounds in bed sediment were smaller than concentrations in fish tissue. Concentrations of p,p'DDE, the only compound detected in all three bed-sediment samples, ranged from 1.1 micrograms per kilogram dry weight in C.J. Strike Reservoir to 11 micrograms per kilogram dry weight in Brownlee Reservoir at Burnt River. Data from this study, compared with data collected in the upper Snake River Basin from 1992 to 1994, indicates that, in general, organochlorine concentrations in fish tissue and bed sediment increased from the headwaters of the Snake River in Wyoming downstream to Brownlee Reservoir. The largest trace-element concentrations in fish tissue were in liver samples from carp from Brownlee Reservoir at Burnt River and suckers from the Boise River near Twin Springs. Concentrations of most trace elements were larger in livers than in the sport- fish fillets. However, mercury concentrations were generally larger in the sportfish fillets; they ranged from 0.08 microgram per gram wet weight in yellow perch from C.J. Strike Reservoir to 0.32 microgram per gram wet weight in channel catfish from Brownlee Reservoir at Burnt River. None of the trace-element concentrations in fillets exceeded median international standards or U.S. Food and Drug Administration action levels. Large trace-element concentrations in the upper Snake River Basin were reported in liver samples from suckers from headwater streams, probably a result of historical mining and weathering of metal-rich rocks. Concentrations of most trace elements in the bed-sediment samples were largest in Brownlee Reservoir at Mountain Man Lodge. Concentrations of arsenic, cadmium, chromium, copper, nickel, and zinc in bed sediment from the Mountain Man Lodge site exceeded either the threshold effect level or probable effect level established by the Canadian Government for the protection of benthic life. Arsenic, chromium, copper, and nickel concentrations in bed sediment from Brownlee Reservoir at Burnt River and chromium, copper, and nickel in bed sediment from C.J. Strike Reservoir also exceeded the threshold effect level.

Water-quality assessment of the Kentucky River Basin, Kentucky; distribution of metals and other trace elements in sediment and water, 1987-90

USGS Publications Warehouse

Porter, Stephen D.; White, Kevin D.; Clark, J.R.

1995-01-01

The U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Program is designed to provide a nationally consistent description of the current status of water quality, to define water-quality trends, and to relate past and present water-quality conditions to natural features, uses of land and water, and other water-quality effects from human activities. The Kentucky River Basin is one of four NAWQA pilot projects that focused primarily on the quality of surface water. Water, sediment, and bedrock samples were collected in the Kentucky River Basin during 1987-90 for the purpose of (1) describing the spatial distribution, transport, and temporal variability of metals and other trace elements in streams of the basin; (2) estimating mean annual loads, yields, and trends of constituent concentrations and identifying potential causes (or sources) of spatial patterns; (3) providing baseline information for concentrations of metals in streambed and suspended sediments; (4) identifying stream reaches in the Kentucky River Basin with chronic water-quality problems; and (5) evaluating the merits of the NAWQA pilot study-approach for the assessment of metals and other trace elements in a river system. The spatial distribution of metals and other trace elements in streambed sediments of the Kentucky River Basin is associated with regional differences of geology, land use and cover, and the results of human activities. Median concentrations of constituents differed significantly among physiographic regions of the basin because of relations to bedrock geochemistry and land disturbance. Concentrations of potentially toxic metals were large in urban and industrial areas of the basin. Elevated concentrations of certain metals were also found in streambed sediments of the Knobs Region because of the presence of Devonian shale bedrock. Elevated concentrations of lead and zinc found in streambed sediments of the Bluegrass Region are likely associated with urban stormwater runoff, point-source discharges, and waste-management practices. Concentrations of cadmium, chromium, copper, mercury, and silver were elevated in streambed sediments downstream from wastewater-treatment plant discharges. Streambed-sediment concentrations of barium, chromium, and lithium were elevated in streams that receive brine discharges from oil production. Elevated concentrations of antimony, arsenic, molybdenum, selenium, strontium, uranium, and vanadium in streambed sediments of the Kentucky River Basin were generally associated with natural sources. Concentrations of metals and other trace elements in water samples from fixed stations (stations where water-quality samples were collected for 3.5 years) in the Kentucky River Basin were generally related to stream discharge and the concentration of suspended sediment, whereas constituent concentrations in the suspended-sediment matrix were indicative of natural and human sources. Estimated mean annual loads and yields for most metals and other trace elements were associated with the transport of suspended sediment. Land disturbance, such as surface mining and agriculture, contribute to increased transport of sediment in streams, thereby increasing concentrations of metals in water samples during periods of intense or prolonged rainfall and increased stream discharge. Concentrations of many metals and trace elements were reduced during low streamflow. Although total-recoverable and dissolved concentrations of certain metals and trace elements were large in streams affected by land disturbance, concentrations of constituents in the suspendedsediment matrix were commonly large in streams in the Knobs and Eastern Coal Field Regions (because of relations with bedrock geochemistry) and in streams that receive wastewater or oil-well-brine discharges. Concentrations and mean annual load estimates for aluminum, chromium, copper, iron, lead, manganese, and mercury were larger than those obtained from data collected by a State agency, probably because of differences in sample-collection methodology, the range of discharge associated with water-quality samples, and laboratory analytical procedures. However, concentrations, loads, and yields of arsenic, barium, and zinc were similar to those determined from the State data. Significant upward trends in the concentrations of aluminum, iron, magnesium, manganese, and zinc were indicated at one or more fixed stations in the Kentucky River Basin during the past 10 to 15 years. Upward trends for concentrations of aluminum, iron, and manganese were found at sites that receive drainage from coal mines in the upper Kentucky River Basin, whereas upward trends for zinc may be associated with urban sources. Water-quality criteria established by the U.S. Environmental Protection Agency (USEPA) or the State of Kentucky for concentrations of aluminum, beryllium, cadmium, chromium, copper, iron, manganese, nickel, silver, and zinc were exceeded at one or more fixed stations in the Kentucky River Basin. On a qualitative basis, dissolved concentrations of certain metals and trace elements were large during low streamflow at sites where (1) concentrations of these constituents in underlying streambed sediments were large, or (2) dissolvedoxygen concentrations were small. Concentrations of barium, lithium, and strontium were large during low streamflow, which indicates the influence of ground-water baseflows on the quality of surface water during low flow. The effects of point-source discharges, landfills, and other wastemanagement practices are somewhat localized in the Kentucky River Basin and are best indicated by the spatial distribution of metals and other trace elements in streambed sediments and in the suspended-sediment fraction of water samples at stream locations near the source. It was not possible to quantify the contribution of point sources to the total transport of metals and other trace elements at fixed stations because data were not available for wastewater effluents. Quantification of baseline concentrations of metals and other trace elements in streambed sediments provides a basis for the detection of water-quality changes that may result from improvements in wastewater treatment or the implementation of best-management practices for controlling contamination from nonpoint sources in the Kentucky River Basin.

Arsenic in sediments, groundwater, and streamwater of a glauconitic Coastal Plain terrain, New Jersey, USA-Chemical " fingerprints" for geogenic and anthropogenic sources

USGS Publications Warehouse

Barringer, J.L.; Reilly, P.A.; Eberl, D.D.; Blum, A.E.; Bonin, J.L.; Rosman, R.; Hirst, B.; Alebus, M.; Cenno, K.; Gorska, M.

2011-01-01

Glauconite-bearing deposits are found worldwide, but As levels have been determined for relatively few. The As content of glauconites in sediments of the Inner Coastal Plain of New Jersey can exceed 100mg/kg, and total As concentrations (up to 5.95??g/L) found historically and recently in streamwaters exceed the State standard. In a major watershed of the Inner Coastal Plain, chemical " fingerprints" were developed for streambed sediments and groundwater to identify contributions of As to the watershed from geologic and anthropogenic sources. The fingerprint for streambed sediments, which included Be, Cr, Fe and V, indicated that As was predominantly of geologic origin. High concentrations of dissolved organic C, nutrients (and Cl-) in shallow groundwater indicated anthropogenic inputs that provided an environment where microbial activity released As from minerals to groundwater discharging to the stream. Particulates in streamwater during high flow constituted most of the As load; the chemical patterns for these particulates resembled the geologic fingerprint of the streambed sediments. The As/Cr ratio of these suspended particles likely indicates they derived not only from runoff, but from groundwater inputs, because As contributed by groundwater is sequestered on streambed sediments. Agricultural inputs of As were not clearly identified, although chemical characteristics of some sediments indicated vehicle-related inputs of metals. Sediment sampling during dry and wet years showed that, under differing hydrologic conditions, local anthropogenic fingerprints could be obscured but the geologic fingerprint, indicating glauconitic sediments as an As source, was robust. ?? 2011.

Occurrence, sources, and ecological risks of PBDEs, PCBs, OCPs, and PAHs in surface sediments of the Yangtze River Delta city cluster, China.

PubMed

Zhang, Ting; Yang, Wen-Long; Chen, She-Jun; Shi, Dian-Long; Zhao, Hu; Ding, Yi; Huang, Ye-Ru; Li, Nan; Ren, Yue; Mai, Bi-Xian

2014-08-01

Polybrominated diphenyl ethers (PBDEs), organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), and polycyclic aromatic hydrocarbons (PAHs) in 25 surface sediments in three cities (Nantong, Wuxi, and Suzhou) in the Yangtze River Delta, eastern China were measured. The mean concentrations were 378, 45.8, 1.98, 4,002 ng/g for PBDEs, OCPs, PCBs, and PAHs, respectively. Their levels in the sediments in the three cities were generally consistent with the city industrialization. PBDEs and OCPs were markedly dominated by deca-BDE (>90 %) and DDTs (>70 %). A principle component analysis of the analytes identified three major factors suggesting different sources of the contaminants in the sediments. PBDEs and the organic carbon in the sediments have common sources from industrial activities; whereas OCPs and PCBs, correlated with the second factor, were mainly from historical sources. The third factor with loadings of PAHs is indicative of various combustion sources. Ecological risk assessment indicated that the potential highest risk is from DDTs, for which 22 sites exceed the effects range low (ERL) values and three sites exceed the effects range median (ERM) value.

Effects of urbanization on stream water quality in the city of Atlanta, Georgia, USA

USGS Publications Warehouse

Peters, N.E.

2009-01-01

A long-term stream water quality monitoring network was established in the city of Atlanta, Georgia during 2003 to assess baseline water quality conditions and the effects of urbanization on stream water quality. Routine hydrologically based manual stream sampling, including several concurrent manual point and equal width increment sampling, was conducted ???12 times annually at 21 stations, with drainage areas ranging from 3.7 to 232 km2. Eleven of the stations are real-time (RT) stations having continuous measures of stream stage/ discharge, pH, dissolved oxygen, specific conductance, water temperature and turbidity, and automatic samplers for stormwater collection. Samples were analyzed for field parameters, and a broad suite of water quality and sediment-related constituents. Field parameters and concentrations of major ions, metals, nutrient species and coliform bacteria among stations were evaluated and with respect to watershed characteristics and plausible sources from 2003 through September 2007. Most constituent concentrations are much higher than nearby reference streams. Concentrations are statistically different among stations for several constituents, despite high variability both within and among stations. Routine manual sampling, automatic sampling during stormflows and RT water quality monitoring provided sufficient information about urban stream water quality variability to evaluate causes of water quality differences among streams. Fecal coliform bacteria concentrations of most samples exceeded Georgia's water quality standard for any water-usage class. High chloride concentrations occur at three stations and are hypothesized to be associated with discharges of chlorinated combined sewer overflows, drainage of swimming pool(s) and dissolution and transport during rainstorms of CaCl2, a deicing salt applied to roads during winter storms. One stream was affected by dissolution and transport of ammonium alum [NH4Al(SO4)2] from an alum-manufacturing plant; streamwater has low pH (<5), low alkalinity and high metals concentrations. Several trace metals exceed acute and chronic water quality standards and high concentrations are attributed to washoff from impervious surfaces.

Water-quality and bottom-material characteristics of Cross Lake, Caddo Parish, Louisiana, 1997-99

USGS Publications Warehouse

McGee, Benton D.

2004-01-01

Cross Lake is a shallow, monomictic lake that was formed in 1926 by the impoundment of Cross Bayou. The lake is the primary drinking-water supply for the City of Shreveport, Louisiana. In recent years, the lakeshore has become increasinginly urbanized. In addition, the land use of the watershed contributing runoff to Cross Lake has changed. Changes in land use and urbanization could affect the water chemistry and biology of the Lake. Water-quality data were collected at 10 sites on Cross Lake from February 1997 to February 1999. Water-column and bottom-material samples were collected. The water-column samples were collected at least four times per year. These samples included physical and chemical-related properties such as water temperature, dissolved oxygen, pH, and specific conductance; selected major inorganic ions; nutrients; minor elements; organic chemical constituents; and bacteria. Suspended-sediment samples were collected seven times during the sampling period. The bottom-material samples, which were collected once during the sampling period, were analyzed for selected minor elements and inorganic carbon. Aside from the nutrient-enriched condition of Cross Lake, the overall water-quality of Cross Lake is good. No primary Federal or State water-quality criteria were exceeded by any of the water-quality constituents analyzed for this report. Concentrations of major inorganic constituents, except iron and manganese, were low. Water from the lake is a sodium-bicarbonate type and is soft. Minor elements and organic compounds were present in low concentrations, many below detection limits. Nitrogen and phosphorus were the nutrients occurring in the highest concentrations. Nutrients were evenly distributed across the lake with no particular water-quality site indicating consistently higher or lower nutrient concentrations. No water samples analyzed for nitrate exceeded the U.S. Environmental Protection Agency's Maximum Contaminant Level of 10 milligrams per liter. Based on nitrogen to phosphorus ratios calculated for Cross Lake, median values for all water-quality sites were within the nitrogen-limited range (less than or equal to 5). Historical Trophic State Indexes for Cross Lake classified the lake as eutrophic. Recent (1998-99) Trophic State Indexes classify Cross Lake as mesotrophic-eutrophic, which might indicate a recution in eutrophication. Sedimentation traps indicate that Cross Lake is filling at an average rate of 0.41 inches per year. Concentrations of fecal-coliform and streptococci bacteria generally were low. Fecal coliform was detected in higher concentrations than fecal streptococci. High bacterial concentrations were measured shortly after rainfall-runoff events, possibly washing bacteria from surrounding areas into the lake.

Flood Plain Lakes Along the Elbe River - a Forgotten Risk

NASA Astrophysics Data System (ADS)

Heise, Susanne

2014-05-01

Flood Plain Lakes Along the Elbe River - a Forgotten Risk Introduction: Along the German part of the Elbe River, more than 1000 "side structures" form potential sinks of contaminated sediment. They are mostly remains of previous river courses which have been cut off by natural causes or anthropogenic alterations of the river (oxbow lakes), or are floodplain lakes that were formed during high water conditions. These water bodies sometimes have a small opening towards the Elbe, or are hydrodynamically connected only in situations of high discharges. High discharges in the Elbe River, however, are mainly responsible for transporting historic contaminants along with suspended matter from former historic sources in the middle Elbe downstream. As these may settle when the current dies down at the end of a high discharge period, side structures have been under suspicion to have accumulated contaminated material over the last decades. Until this study was conducted, nothing was known about erodibility and contamination of sediment in these lakes even though they could have a large impact on the Elbe River itself: A preliminary investigation showed that the total surface of side structures in the Elbe floodplain adds up to about 50 km2. In case that deposited sediment is contaminated and only the upper 20 cm are prone to resuspension and transport during flooding, 10 Mio m3 of contaminated sediment could potentially be added to the contaminant load during a high water event. This study was carried out to evaluate the risk from these side structures for the environmental quality of the Elbe River. Methods: 15 side structures were investigated. Sediment cores were taken on 1 to 3 locations per water body in order to obtain the following information: • Depth of sediment layer • Erodibility of surface sediment, measured immediately after sampling - using the "Gust Microcosm", • Eroded mass at over-critical shear stress, measured in the lab by eroding a sediment core for one hour and collecting the suspended sediment matter. • Chemical contamination • Ecotoxicological effects Results and Discussion All side structures that were sampled exceeded the national quality guidelines for sediments which have been set by the International Commission for the Protection of the Elbe. In some cases very high concentrations were reached such as 1300 µg/kg dw for p,p-DDD, up to 61 mg/kg for Hg and 39 mg/kg for Cd. Erodibility varied a lot with critical shear stresses of less than 1 cm/s to more than 2 cm/s. Ecotoxicological data were also very different between side structures and sampling locations, but partly indicating very high inhibitions. Methanol extracts of sediments on all locations were screened using the luminescence bacteria test with Vibrio fischeri. Selected sediemt samples were tested applying the sediment contact test with Arthrobacter globiformes and the algae growth inhibition test with Pseudokirchneriella subcapitata. An integrated evaluation of all information led to a classification of 7 sites out of 15 to be of high risk, 7 to be of medium risk and only one site to be of low risk for the environmental quality of the Elbe River.

Terrestrial source to deep-sea sink sediment budgets at high and low sea levels: Insights from tectonically active Southern California

USGS Publications Warehouse

Covault, J.A.; Romans, B.W.; Graham, S.A.; Fildani, A.; Hilley, G.E.

2011-01-01

Sediment routing from terrestrial source areas to the deep sea influences landscapes and seascapes and supply and filling of sedimentary basins. However, a comprehensive assessment of land-to-deep-sea sediment budgets over millennia with significant climate change is lacking. We provide source to sink sediment budgets using cosmogenic radionuclide-derived terrestrial denudation rates and submarine-fan deposition rates through sea-level fluctuations since oxygen isotope stage 3 (younger than 40 ka) in tectonically active, spatially restricted sediment-routing systems of Southern California. We show that source-area denudation and deep-sea deposition are balanced during a period of generally falling and low sea level (40-13 ka), but that deep-sea deposition exceeds terrestrial denudation during the subsequent period of rising and high sea level (younger than 13 ka). This additional supply of sediment is likely owed to enhanced dispersal of sediment across the shelf caused by seacliff erosion during postglacial shoreline transgression and initiation of submarine mass wasting. During periods of both low and high sea level, land and deep-sea sediment fluxes do not show orders of magnitude imbalances that might be expected in the wake of major sea-level changes. Thus, sediment-routing processes in a globally significant class of small, tectonically active systems might be fundamentally different from those of larger systems that drain entire orogens, in which sediment storage in coastal plains and wide continental shelves can exceed millions of years. Furthermore, in such small systems, depositional changes offshore can reflect onshore changes when viewed over time scales of several thousand years to more than 10 k.y. ?? 2011 Geological Society of America.

A giant sediment trap in the Florida keys

USGS Publications Warehouse

Shinn, E.A.; Reich, C.D.; Locker, S.D.; Hine, A.C.

1996-01-01

Aerial photography, high-resolution seismic profiling, coring and jet probing have revealed a large sediment-filled sinkhole in the Key Largo National Marine Sanctuary off Key Largo, Florida. The 600-m-diameter feature straddles coral reef and carbonate-sand facies and contains >55 m of marine lime sand and aragonite mud. Bulk 14C age determinations of mud from a 30- m sediment core indicate infilling rates exceeding 20 m/ka between 3 and 5.6 ka. The total thickness and nature of the sediment near the base of the sinkhole are not known.

Development and application of freshwater sediment-toxicity benchmarks for currently used pesticides

USGS Publications Warehouse

Nowell, Lisa H.; Norman, Julia E.; Ingersoll, Christopher G.; Moran, Patrick W.

2016-01-01

Sediment-toxicity benchmarks are needed to interpret the biological significance of currently used pesticides detected in whole sediments. Two types of freshwater sediment benchmarks for pesticides were developed using spiked-sediment bioassay (SSB) data from the literature. These benchmarks can be used to interpret sediment-toxicity data or to assess the potential toxicity of pesticides in whole sediment. The Likely Effect Benchmark (LEB) defines a pesticide concentration in whole sediment above which there is a high probability of adverse effects on benthic invertebrates, and the Threshold Effect Benchmark (TEB) defines a concentration below which adverse effects are unlikely. For compounds without available SSBs, benchmarks were estimated using equilibrium partitioning (EqP). When a sediment sample contains a pesticide mixture, benchmark quotients can be summed for all detected pesticides to produce an indicator of potential toxicity for that mixture. Benchmarks were developed for 48 pesticide compounds using SSB data and 81 compounds using the EqP approach. In an example application, data for pesticides measured in sediment from 197 streams across the United States were evaluated using these benchmarks, and compared to measured toxicity from whole-sediment toxicity tests conducted with the amphipod Hyalella azteca (28-d exposures) and the midge Chironomus dilutus (10-d exposures). Amphipod survival, weight, and biomass were significantly and inversely related to summed benchmark quotients, whereas midge survival, weight, and biomass showed no relationship to benchmarks. Samples with LEB exceedances were rare (n = 3), but all were toxic to amphipods (i.e., significantly different from control). Significant toxicity to amphipods was observed for 72% of samples exceeding one or more TEBs, compared to 18% of samples below all TEBs. Factors affecting toxicity below TEBs may include the presence of contaminants other than pesticides, physical/chemical characteristics of sediment, and uncertainty in TEB values. Additional evaluations of benchmarks in relation to sediment chemistry and toxicity are ongoing.

Infiltration and quality of water for two arroyo channels, Albuquerque, New Mexico, 1988-92

USGS Publications Warehouse

Thomas, Carole L.

1995-01-01

Selected reaches of Grant Line Arroyo and Tijeras Arroyo in Albuquerque, New Mexico, were studied to collect information about the amount and quality of infiltration through arroyo channels. Infiltration rate was calculated for selected reaches of Grant Line Arroyo and Tijeras Arroyo based on instantaneous streamflow-loss volumes, wetted channel area, and instantaneous evaporation rates measured during 1988-92. Infiltration rates at Grant Line Arroyo ranged from 0.0 to 0.6 foot per day, and at Tijeras Arroyo from 2.28 to 30 feet per day. The evaporation rate ranged from one-tenth of 1 percent to 2 percent of the infiltration rate. Infiltration rates differed with the location of the reach isolated for measurement and with the time of day of the infiltration-rate measurement. Differences in intrinsic permeability of the sediments may be the most important factor affecting spatial variations in infiltration. The most important factor affecting temporal variations in infiltration may be the temperature of the water and sediment where infiltration occurs. Annual evaporation rates were greatest over saturated stream sediments and ranged from 802 to 1,025 millimeters per year or from 31.57 to 40.35 inches per year. Annual evaporation rates were least over unsaturated, unvegetated soil and ranged from 174 to 291 millimeters per year or from 6.85 to 11.46 inches per year. Annual evapotranspiration rates over grasses or shrubs or both were about one-half the rates over saturated stream sediments. Rates were similar for Grant Line and Tijeras Arroyos. The land- surface vegetation, availability of water at the land surface, availability of energy to enable a change of state from water to vapor, existence of a vapor concentration gradient, and a turbulent atmosphere to carry the vapor away may be the factors that determine the amount of evaporation and evapotranspiration. Water in Grant Line Arroyo and Tijeras Arroyo met U. S. Environmental Protection Agency drinking-water regulations for nitrate, volatile organic compounds, dissolved lead, and dissolved and total arsenic, barium, cadmium, chromium, copper, iron, silver, zinc, selenium, chloride, and sulfate concentrations. Total lead concentration in one sample from Tramway Floodway Channel, a tributary to Tijeras Arroyo, was 55 micrograms per liter, exceeding the Environmental Protection Agency drinking-water regulation of 50 micrograms per liter. Dissolved-solids concentrations calculated from the sum of cations and anions usually exceeded the Environmental Protection Agency drinking-water dissolved-solids regulation of 500 milligrams per liter at Tijeras Arroyo above Four Hills Bridge.

Integrated Assessment of Artisanal and Small-Scale Gold Mining in Ghana-Part 2: Natural Sciences Review.

PubMed

Rajaee, Mozhgon; Obiri, Samuel; Green, Allyson; Long, Rachel; Cobbina, Samuel J; Nartey, Vincent; Buck, David; Antwi, Edward; Basu, Niladri

2015-07-31

This paper is one of three synthesis documents produced via an integrated assessment (IA) that aims to increase understanding of artisanal and small-scale gold mining (ASGM) in Ghana. Given the complexities surrounding ASGM, an integrated assessment (IA) framework was utilized to analyze socio-economic, health, and environmental data, and co-develop evidence-based responses with stakeholders. This paper focuses on the causes, status, trends, and consequences of ecological issues related to ASGM activity in Ghana. It reviews dozens of studies and thousands of samples to document evidence of heavy metals contamination in ecological media across Ghana. Soil and water mercury concentrations were generally lower than guideline values, but sediment mercury concentrations surpassed guideline values in 64% of samples. Arsenic, cadmium, and lead exceeded guideline values in 67%, 17%, and 24% of water samples, respectively. Other water quality parameters near ASGM sites show impairment, with some samples exceeding guidelines for acidity, turbidity, and nitrates. Additional ASGM-related stressors on environmental quality and ecosystem services include deforestation, land degradation, biodiversity loss, legacy contamination, and potential linkages to climate change. Though more research is needed to further elucidate the long-term impacts of ASGM on the environment, the plausible consequences of ecological damages should guide policies and actions to address the unique challenges posed by ASGM.

40 CFR 435.15 - Standards of performance for new sources (NSPS).

Code of Federal Regulations, 2012 CFR

2012-07-01

... toxicity ratio 6 shall not exceed 1.0. Biodegradation rate Biodegradation rate ratio 7 shall not exceed 1.0...) and (uu). 7 Biodegradation rate ratio = Cumulative headspace gas production (ml) of C16-C18 internal... fluids that meet the base fluid sediment toxicity ratio (Footnote 6), biodegradation rate ratio (Footnote...

40 CFR 435.15 - Standards of performance for new sources (NSPS).

Code of Federal Regulations, 2013 CFR

2013-07-01

... toxicity ratio 6 shall not exceed 1.0. Biodegradation rate Biodegradation rate ratio 7 shall not exceed 1.0...) and (uu). 7 Biodegradation rate ratio = Cumulative headspace gas production (ml) of C16-C18 internal... fluids that meet the base fluid sediment toxicity ratio (Footnote 6), biodegradation rate ratio (Footnote...

40 CFR 435.15 - Standards of performance for new sources (NSPS).

Code of Federal Regulations, 2014 CFR

2014-07-01

... toxicity ratio 6 shall not exceed 1.0. Biodegradation rate Biodegradation rate ratio 7 shall not exceed 1.0...) and (uu). 7 Biodegradation rate ratio = Cumulative headspace gas production (ml) of C16-C18 internal... fluids that meet the base fluid sediment toxicity ratio (Footnote 6), biodegradation rate ratio (Footnote...

Human health risk assessment in relation to environmental pollution of two artificial freshwater lakes in The Netherlands.

PubMed

Albering, H J; Rila, J P; Moonen, E J; Hoogewerff, J A; Kleinjans, J C

1999-01-01

A human health risk assessment has been performed in relation to recreational activities on two artificial freshwater lakes along the river Meuse in The Netherlands. Although the discharges of contaminants into the river Meuse have been reduced in the last decades, which is reflected in decreasing concentrations of pollutants in surface water and suspended matter, the levels in sediments are more persistent. Sediments of the two freshwater lakes appear highly polluted and may pose a health risk in relation to recreational activities. To quantify health risks for carcinogenic (e.g., polycyclic aromatic hydrocarbons) as well as noncarcinogenic compounds (e.g., heavy metals), an exposure assessment model was used. First, we used a standard model that solely uses data on sediment pollution as the input parameter, which is the standard procedure in sediment quality assessments in The Netherlands. The highest intake appeared to be associated with the consumption of contaminated fish and resulted in a health risk for Pb and Zn (hazard index exceeded 1). For the other heavy metals and for benzo(a)pyrene, the total averaged exposure levels were below levels of concern. Secondly, input data for a more location-specific calculation procedure were provided via analyses of samples from sediment, surface water, and suspended matter. When these data (concentrations in surface water) were taken into account, the risk due to consumption of contaminated fish decreased by more than two orders of magnitude and appeared to be negligible. In both exposure assessments, many assumptions were made that contribute to a major degree to the uncertainty of this risk assessment. However, this health risk evaluation is useful as a screening methodology for assessing the urgency of sediment remediation actions.

Geochemistry and mercury contamination in receiving environments of artisanal mining wastes and identified concerns for food safety

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reichelt-Brushett, Amanda J., E-mail: amanda.reich

Artisanal small-scale gold mining (ASGM) using mercury (Hg) amalgamation has been occurring on Buru Island, Indonesia since early 2012, and has caused rapid accumulation of high Hg concentrations in river, estuary and marine sediments. In this study, sediment samples were collected from several sites downstream of the Mount Botak ASGM site, as well as in the vicinity of the more recently established site at Gogrea where no sampling had previously been completed. All sediment samples had total Hg (THg) concentrations exceeding Indonesian sediment quality guidelines and were up to 82 times this limit at one estuary site. The geochemistry ofmore » sediments in receiving environments indicates the potential for Hg-methylation to form highly bioavailable Hg species. To assess the current contamination threat from consumption of local seafood, samples of fish, molluscs and crustaceans were collected from the Namlea fish market and analysed for THg concentrations. The majority of edible tissue samples had elevated THg concentrations, which raises concerns for food safety. This study shows that river, estuary and marine ecosystems downstream of ASGM operations on Buru Island are exposed to dangerously high Hg concentrations, which are impacting aquatic food chains, and fisheries resources. Considering the high dietary dependence on marine protein in the associated community and across the Mollucas Province, and the short time period since ASGM operations commenced in this region, the results warrant urgent further investigation, risk mitigation, and community education. - Highlights: • Mercury contamination of sediments and seafood due to artisanal gold mining. • Considerable risks to human and ecosystem health are identified. • Results emphasise the urgent need for risk mitigation and community education.« less

An integrated assessment of pollution and biological effects in flounder, mussels and sediment in the southern Baltic Sea coastal area.

PubMed

Dabrowska, Henryka; Kopko, Orest; Lehtonen, Kari K; Lang, Thomas; Waszak, Ilona; Balode, Maija; Strode, Evita

2017-02-01

Organic and metal contaminants and biological effects were investigated in flounder, mussels, and sediments in the southern Baltic Sea coastal area in order to assess environmental quality status in that area. Four sites were selected, including two within the Gulf of Gdańsk (GoG). In biota and sediment at each site, DDTs dominated over PCBs and PBDEs were the least abundant among organic contaminants. Their concentrations decreased progressively outward from GoG. Among metal contaminants, the levels of Hg, Pb, and Cd were elevated in GoG. Biomarkers in flounder, EROD activity and DNA SB, showed moderate positive correlations with organic and metal contaminants. In flounder, the integrated biomarker index (IBR/n) presented a spatial trend coherent with chemical pollution index (CPI), but there was no clear spatial correspondence between IBR/n and CPI in mussels nor between sediment toxicity index (STI) and sediment CPI. The integrated assessment of contaminant and biological effect data against available assessment criteria indicated that in biota, the contaminant assessment thresholds were most often exceeded by CB-118, heptachlor, PBDE, and Hg (in the GoG sediments by p,p'-DDT, Hg and Cd), while of the biological determinants, the threshold was breeched by AChE activity in mussels in GoG. Applying the ICES/OSPAR traffic-light approach showed that of the 50 parameters assessed at each site, there were 18% of determinants in the red color category in the two GoG sites and 8% of determinants in the two sites outside GoG, which indicated that none of the four investigated sites attained good environmental status (GES).

Human health risk assessment in relation to environmental pollution of two artificial freshwater lakes in The Netherlands.

PubMed Central

Albering, H J; Rila, J P; Moonen, E J; Hoogewerff, J A; Kleinjans, J C

1999-01-01

A human health risk assessment has been performed in relation to recreational activities on two artificial freshwater lakes along the river Meuse in The Netherlands. Although the discharges of contaminants into the river Meuse have been reduced in the last decades, which is reflected in decreasing concentrations of pollutants in surface water and suspended matter, the levels in sediments are more persistent. Sediments of the two freshwater lakes appear highly polluted and may pose a health risk in relation to recreational activities. To quantify health risks for carcinogenic (e.g., polycyclic aromatic hydrocarbons) as well as noncarcinogenic compounds (e.g., heavy metals), an exposure assessment model was used. First, we used a standard model that solely uses data on sediment pollution as the input parameter, which is the standard procedure in sediment quality assessments in The Netherlands. The highest intake appeared to be associated with the consumption of contaminated fish and resulted in a health risk for Pb and Zn (hazard index exceeded 1). For the other heavy metals and for benzo(a)pyrene, the total averaged exposure levels were below levels of concern. Secondly, input data for a more location-specific calculation procedure were provided via analyses of samples from sediment, surface water, and suspended matter. When these data (concentrations in surface water) were taken into account, the risk due to consumption of contaminated fish decreased by more than two orders of magnitude and appeared to be negligible. In both exposure assessments, many assumptions were made that contribute to a major degree to the uncertainty of this risk assessment. However, this health risk evaluation is useful as a screening methodology for assessing the urgency of sediment remediation actions. Images Figure 1 Figure 2 Figure 3 PMID:9872714

Impacts of climate-induced changes on the distribution of pesticides residues in water and sediment of Lake Naivasha, Kenya.

PubMed

Otieno, Peter O; Owuor, P Okinda; Lalah, Joseph O; Pfister, Gerd; Schramm, Karl-Werner

2013-03-01

This study reports evidence of increased chlorpyrifos contamination in sediment and water in Lake Naivasha following its intensive application in the horticultural farms in the catchment area. Analytical results show that levels of chlorpyrifos residues were influenced by climate-induced rainfall pattern with higher levels reported during period of heavy precipitation with significant decrease during low rainfall. On average, the levels ranged between 14.8 and 32.8 ng g(-1) in sediment during rainy season compared to a range of 8.5-16.6 ng g(-1) in the dry season. Additionally, the mean concentration of chlorpyrifos in water ranged between 8.61 and 22.4 μg L(-1) during rainy season and below detection limit (bdl) -13.6 μg L(-1) in dry season as quantified by enzyme-linked immunosorbent assay. Meanwhile, independent t test analysis indicated that there was significant difference in concentration at p ≤ 0.05 between the seasons with respect to sediment and water samples. This demonstrated that climate-induced variations had considerable influence on contamination. While diazinon and carbofuran were equally applied intensively, their levels were below the detection limit in the all the samples analyzed. ELISA results were validated by the capillary-HPLC photodiode-array detector instrument analysis, and statistical comparison showed no significant difference between them. It was evident that chlorpyrifos residues determination in water and sediment by ELISA can be a useful strategy in environmental management and monitoring program, and a complimentary analytical tool to high performance liquid chromatography. Levels of chlorpyrifos detected in sediment and water were found to exceed recommended criteria for protection of aquatic life and preservation of water quality and may be hazardous if not regularly monitored.

Hydrology of the U.S. Army Pinon Canyon maneuver site, Las Animas County, Colorado

USGS Publications Warehouse

Von Guerard, Paul; Abbott, P.O.; Nickless, Raymond C.

1987-01-01

The U.S. Department of the Army (Fort Carson Military Reservation) has acquired 381 sq mi of semiarid rangeland in southeastern Colorado for mechanized military maneuvers. The study area, known as the Pinon Canyon Maneuver Site, drains into the Purgatoire River, a major tributary of the upper Arkansas River. A multidisciplined hydrologic investigation began in October 1982. The primary aquifer in the Maneuver Site is the Dakota-Purgatoire. Well yields generally range from 10 to 500 gal/min. Dissolved solids concentrations in groundwater ranged from 195 to 6,150 mg/L. Streamflow in the Purgatoire River is perennial. Tributaries draining the Maneuver Site are intermittent or ephemeral and contribute only about 4.4% of the streamflow of the Purgatoire River downstream from the Maneuver Site. Flood frequencies were calculated by using the log Pearson III procedure and compared well with a regional estimating technique that was developed that uses physical drainage-basin characteristics. Calcium and sulfate are the predominant ions in the surface water of the area. Time-series plots indicate that instream water-quality standards for nitrate and metals are exceeded. About 80% of the suspended-sediment load is transported by rainfall runoff, which occurs less than 8% of the time. Ephermal tributaries contributed less than 25% of the suspended-sediment load transported to the Purgatoire River downstream from the Maneuver Site. Historic annual mean sediment yields were measured for 29 small watersheds. Sediment yields were measured for 29 small watersheds. Sediment yields ranged from 9.5 to 1,700 tons/sq mi. Sediment yields were estimated by a multiple-linear-regression model developed by using physical drainage-basin characteristics and by the Pacific Southwest Interagency Committee method. (USGS)

Anthropogenic impacts on the quality of streambed sediments in the lower Sacramento River watershed, California.

PubMed

Hwang, Hyun-Min; Green, Peter G; Holmes, Robert W

2009-01-01

To investigate the occurrence of contaminants and to assess their toxicity potential to benthic organisms, streambed sediments were collected from three agricultural and one urban influenced small waterways in the lower Sacramento River watershed and analyzed for PAHs, organochlorine (OC) and organophosphorus (OP) pesticides, pyrethroids, and metals. These sites had low benthic biotic index scores in earlier field surveys. The occurrence patterns of these contaminants and iron normalized enrichment factors of metals reflect the land use patterns around study sites. DDTs were detected in all samples while chlordanes were found only at the urban influenced site. No OP pesticides were found in any sediment presumably due to their high water solubilities and low solid-water partitioning. DDTs, PAHs, and metals at sites in the Biggs/West Gridley Canal showed a gradient increasing toward downstream. Distribution patterns of individual PAHs and their ratios found in sediment from the Biggs/West Gridley Canal downstream site resemble those of petroleum. PAHs in this site might originate from petroleum oils that have been used as agricultural pesticides. The enrichment factor of vanadium, which is an indicator of petroleum residue, was also higher in this site. The anthropogenic enrichment of copper at all Biggs/West Gridley Canal sites might be because of significant use of copper based pesticides. The high enrichment factor of lead at the urban influenced Dry Creek site might be related to historical use of leaded gasoline. All sediment samples had at least one chemical that exceed the threshold effects concentration (TEC). Total probable effects concentration quotients (tPECQs) were greater than 1 at all sites, indicating that sediment bound contaminants in the study sites can possibly pose toxic effects. This finding can be linked to lower biotic index scores observed in previous regional monitoring studies.

Effects of Offshore Oil Exploration and Development in the Alaskan Beaufort Sea: A Three-Decade Record for Sediment Metals.

PubMed

Trefry, John H; Neff, Jerry M

2018-06-19

Impacts from oil exploration, development and production in the Beaufort Sea, Alaska, are assessed using concentrations of metals in sediments collected during 2014-15, combined with a large dataset for 1985-2006. Concentrations of 7 (1980 s) or 17 (1999-2015) metals in 423 surface sediments from 134 stations, plus 563 samples from 30 cores were highly variable, primarily as a function of sediment granulometry with naturally greater metal concentrations in fine-grained, Al-rich sediment. Metals versus Al correlation plots were used to normalize metal concentrations and identify values significantly above background. Barium, Cr, Cu, Hg and Pb concentrations were above background, but variable, within 250 m of some offshore sites where drilling occurred between 1981-2001; these areas totaled <6 km 2 of 11,000 km 2 in the total lease area. Random and fixed sampling along the coastal Beaufort Sea from 1985-2015 yielded 40 positive anomalies for metals in surface sediments (∼0.8% of 5,082 data points). About 85% of the anomalies were from developed areas. Half the anomalies were for the five metals found enhanced near drilling sites. No metals concentrations, except As, exceeded accepted sediment quality criteria. Interannual shifts in metals values for surface sediments at inner shelf sites were common and linked to storm-induced transitions in granulometry; however, metal/Al ratios were uniform during these shifts. Sediment cores generally recorded centuries of background values, except for As, Fe and Mn. These three metals were naturally enriched in sediments from deeper water (>100 m) via diagenetic remobilization at sediment depths of 5-15 cm, upward diffusion, and precipitation in surface oxic layers. Minimal evidence for anthropogenic inputs of metals, except near some exploratory drilling sites, is consistent with extraction of most oil from land or barrier islands in the Alaskan Arctic and restricted offshore activity to date. This article is protected by copyright. All rights reserved. This article is protected by copyright. All rights reserved.

Freeze-thaw processes and intense winter rainfall: The one-two punch for high streambank legacy sediment and nutrient loads from Mid-Atlantic watersheds

NASA Astrophysics Data System (ADS)

Inamdar, S. P.; Johnson, E. R.; Rowland, R. D.; Walter, R. C.; Merritts, D.

2017-12-01

Historic and contemporary anthropogenic soil erosion combined with early-American milldams resulted in large deposits of legacy sediments in the valley bottoms of Piedmont watersheds of the eastern US. Breaching of milldams subsequently yielded highly incised streams with exposed vertical streambanks that are vulnerable to erosion. Streambank erosion is attributed to fluvial scouring, freeze-thaw processes and mass wasting. While streambanks represent a large reservoir of fine sediments and nutrients, there is considerable uncertainty about the contribution of these sources to watershed nonpoint source pollution. Using high-frequency hydrologic, sediment, and turbidity data we show that freeze-thaw events followed by intense winter rainstorms can export unusually high concentrations of suspended sediment and particulate nutrients from watersheds. Data from a 12 ha forested, Piedmont, stream following an intense rain event (54 mm) on February 2016 yielded suspended sediment and particulate nutrient (organic carbon and nitrogen) concentrations and exports that exceeded those from tropical storms Irene, Lee, and Sandy that had much greater rainfall and discharge amounts, but which occurred later in the year. A similar response was also observed with regards to turbidity data for USGS stream monitoring locations at Brandywine Creek (813 km2) and White Clay Creek (153 km2). We hypothesize that much of the sediment export associated with winter storms is likely due to erosion of streambank sediments and was driven by the coupled occurrence of freeze-thaw conditions and intense rainfall events. We propose that freeze-thaw erosion represents an important and underappreciated mechanism in streams that "recharges" the sediment supply, which then is available for flushing by moderate to large storms. Future climate projections indicate increased intensification of storm events and increased variability of winter temperatures. Freeze-thaw cycles coupled with winter rain events could increase erosion and transport of streambank sediments with detrimental consequences for water quality and health of downstream aquatic ecosystems. This study underscores the need to better understand the mechanisms of legacy sediment erosion and transport along with appropriate restoration strategies.

Total mercury, methyl mercury, and heavy metal concentrations in Hyeongsan River and its tributaries in Pohang city, South Korea.

PubMed

Bailon, Mark Xavier; David, Anneschel Sheehan; Park, Yeongeon; Kim, Eunhee; Hong, Yongseok

2018-04-11

Heavy metal contamination in aquatic systems is a big problem in many areas around the world. In 2016, high mercury concentrations were reported in bivalves (Corbicula leana) and sediments near the confluence of the Hyeongsan River and Chilseong Creek located in Pohang, a steel industrial city in the south-east coast of the Korean peninsula. Given that both the Chilseong and Gumu creeks run through the Pohang industrial complex and ultimately flow to the Hyeongsan River, it is imperative to determine if the industrial effluents have any impact on the mercury contamination in these two streams and the Hyeongsan River. In this work, we investigated the concentration levels of different heavy metals using cold vapor atomic fluorescence spectroscopy and inductively coupled plasma-mass spectroscopy. The metal concentration in the water samples from the Hyeongsan River, Gumu Creek, and Chilseong Creek did not exceed the limits for drinking water quality set by the US EPA and World Health Organization. However, the sediment samples were found to be heavily contaminated by Hg with levels exceeding the toxic effect threshold. Gumu Creek was found to be heavily contaminated. The concentrations of the different heavy metals increased downstream, and the samples collected from the sites in the Hyeongsan River near the Gumu Creek, an open channel for wastewater discharge of companies in the Pohang Industrial Complex, showed higher contamination levels, indicating that the effluents from the industrial complex are a possible source of contamination in the river.

Polychlorinated biphenyls (PCBs) in sediments/soils of different wetlands along 100-year coastal reclamation chronosequence in the Pearl River Estuary, China.

PubMed

Zhao, Qingqing; Bai, Junhong; Lu, Qiongqiong; Gao, Zhaoqin; Jia, Jia; Cui, Baoshan; Liu, Xinhui

2016-06-01

PCBs (polychlorinated biphenyls) were determined in sediment/soil profiles to a depth of 30 cm from three different wetlands (i.e., ditch wetlands, riparian wetlands and reclaimed wetlands) of the Pearl River Estuary to elucidate their levels, distribution and toxic risks along a 100-year chronosequence of reclamation. All detected PCB congeners and the total 15 PCBs (∑15 PCBs) decreased with depth along sediment/soil profiles in these three wetlands. The ∑15 PCBs concentrations ranged from 17.68 to 169.26 ng/g in surface sediments/soils. Generally, old wetlands tended to have higher PCB concentrations than younger ones. The dominant PCB congeners at all sampling sites were light PCB homologues (i.e., tetra-CBs and tri-CBs). According to the sediment quality guideline, the average PCB concentrations exceeded the threshold effects level (TEL, 21.6 ng/g) at most of the sampling sites, exhibiting possible adverse biological effects, which were dominantly caused by light PCB congeners. The total toxic equivalent (TEQ) concentrations of 10 dioxin-like PCBs (DL-PCBs) detected at all sampling sites ranged from 0.04 to 852.7 (10(-3) ng/g), mainly affected by PCB126. Only DL-PCB concentrations in ditch and riparian wetland sediments with 40-year reclamation histories (i.e., D40 and Ri40) exhibited moderate adverse biological effects according to SQGQ values. Principal component analysis indicated that PCBs in three wetland sediments/soils mainly originated from Aroclor 1016, 1242, and 1248. Correlation analysis showed that sediment/soil organic carbon content had a significant correlation with the concentrations of several PCB congeners (P < 0.05), whereas no significant correlations were observed between any PCBs congeners and grain size or aggregate content (P > 0.05). Copyright © 2016 Elsevier Ltd. All rights reserved.

Water Quality on the Prairie Band Potawatomi Reservation, Northeastern Kansas, June 1996 through August 2006

USGS Publications Warehouse

Schmidt, Heather C. Ross; Mehl, Heidi E.; Pope, Larry M.

2007-01-01

This report describes surface- and ground-water-quality data collected on the Prairie Band Potawatomi Reservation in northeastern Kansas from November 2003 through August 2006 (hereinafter referred to as the 'current study period'). Data from this study period are compared to results from June 1996 through August 2003, which are published in previous reports as part of a multiyear cooperative study with the Prairie Band Potawatomi Nation. Surface and ground water are valuable resources to the Prairie Band Potawatomi Nation as tribal members currently (2007) use area streams to fulfill subsistence hunting and fishing needs and because ground water potentially could support expanding commercial enterprise and development. Surface-water-quality samples collected from November 2003 through August 2006 were analyzed for physical properties, dissolved solids, major ions, nutrients, trace elements, pesticides, fecal-indicator bacteria, suspended-sediment concentration, and total suspended solids. Ground-water samples were analyzed for physical properties, dissolved solids, major ions, nutrients, trace elements, pesticides, and fecal-indicator bacteria. Chemical oxygen demand and volatile organic compounds were analyzed in all three samples from one monitoring well located near a construction and demolition landfill on the reservation, and in one sample from another well in the Soldier Creek drainage basin. Previous reports published as a part of this ongoing study identified total phosphorus, triazine herbicides, and fecal coliform bacteria as exceeding their respective water-quality criteria in surface water on the reservation. Previous ground-water assessments identified occasional sample concentrations of dissolved solids, sodium, sulfate, boron, iron, and manganese as exceeding their respective water-quality criteria. Fifty-six percent of the 55 surface-water samples collected during the current study period and analyzed for total phosphorus exceeded the goal of 0.1 mg/L (milligram per liter) established by the U.S. Environmental Protection Agency (USEPA) to limit cultural eutrophication in flowing water. Concentrations of dissolved solids frequently exceeded the USEPA Secondary Drinking-Water Regulation (SDWR) of 500 mg/L in samples from two sites. Concentrations of sodium exceeded the Drinking-Water Advisory of 20 mg/L set by USEPA in almost 50 percent of the surface-water samples. All four samples analyzed for atrazine concentrations showed some concentration of the pesticide, but none exceeded the Maximum Contaminant Level (MCL) established for drinking water by USEPA of 3.0 ?g/L (micrograms per liter) as an annual average. A triazine herbicide screen was used on 55 surface-water samples, and triazine compounds were frequently detected. Triazine herbicides and their degradates are listed on the USEPA Contaminant Candidate List. In 41 percent of surface-water samples, densities of Escherichia coli (E. coli) bacteria exceeded the primary contact, single-sample maximum in public-access bodies of water (1,198 colonies per 100 milliliters of water for samples collected between April 1 and October 31) set by the Kansas Department of Health and Environment (KDHE). Nitrite plus nitrate concentrations in all three water samples from 1 of 10 monitoring wells exceeded the MCL of 10 mg/L established by USEPA for drinking water. Arsenic concentrations in all three samples from one well exceeded the proposed MCL of 10 ?g/L established by USEPA for drinking water. Boron also exceeded the drinking-water advisory in three samples from one well, and iron concentrations were higher than the SDWR in water from four wells. There was some detection of pesticides in ground-water samples from three of the wells, and one detection of the volatile organic compound diethyl ether in one well. Concentrations of dissolved solids exceeded the SDWR in 20 percent of ground-water samples collected during the current study period, and concentration

Exchanges of sediment between the flood plain and channel of the Amazon River in Brazil

USGS Publications Warehouse

Dunne, T.; Mertes, L.A.K.; Meade, R.H.; Richey, J.E.; Forsberg, B.R.

1998-01-01

Sediment transport through the Brazilian sector of the Amazon River valley, a distance of 2010 km, involves exchanges between the channel and the flood plain that in each direction exceed the annual flux of sediment out of the river at O??bidos (???1200 Mt yr-1). The exchanges occur through bank erosion, bar deposition, settling from diffuse overbank flow, and sedimentation in flood-plain channels. We estimated the magnitude of these exchanges for each of 10 reaches of the valley, and combined them with calculations of sediment transport into and out of the reaches based on sediment sampling and flow records to define a sediment budget for each reach. Residuals in the sediment budget of a reach include errors of estimation and erosion or deposition within the channel. The annual supply of sediment entering the channel from bank erosion was estimated to average 1570 Mt yr-1 (1.3 ?? the O??bidos flux) and the amount transferred from channel transport to the bars (380 Mt yr-1) and the flood plain (460 Mt yr-1 in channelized flow; 1230 Mt yr-1 in diffuse overbank flow) totaled 2070 Mt yr-1 (1.7 ?? the O??bidos flux). Thus, deposition on the bars and flood plain exceeded bank erosion by 500 Mt yr-1 over a 10-16 yr period. Sampling and calculation of sediment loads in the channel indicate a net accumulation in the valley floor of approximately 200 Mt yr-1 over 16 yr, crudely validating the process-based calculations of the sediment budget, which in turn illuminate the physical controls on each exchange process. Another 300-400 Mt yr-1 are deposited in a delta plain downstream of O??bidos. The components of the sediment budget reflect hydrologie characteristics of the valley floor and geomorphic characteristics of the channel and flood plain, which in turn are influenced by tectonic features of the Amazon structural trough.

Quality-assurance plan for the analysis of fluvial sediment by the U.S. Geological Survey Kentucky Water Science Center Sediment Laboratory

USGS Publications Warehouse

Shreve, Elizabeth A.; Downs, Aimee C.

2005-01-01

This report describes laboratory procedures used by the U.S. Geological Survey Kentucky Water Science Center Sediment Laboratory for the processing and analysis of fluvial-sediment samples for concentration of sand and finer material. The report details the processing of a sediment sample through the laboratory from receiving the sediment sample, through the analytical process, to compiling results of the requested analysis. Procedures for preserving sample integrity, calibrating and maintaining of laboratory and field instruments and equipment, analyzing samples, internal quality assurance and quality control, and validity of the sediment-analysis results also are described. The report includes a list of references cited and a glossary of sediment and quality-assurance terms.

A Field Investigation of Water and Salt Movement in Permafrost and the Active Layer

DTIC Science & Technology

1993-02-01

in the submerged continental shelves of the Arctic and Antarctic land masses where pore water salinities of shelf sediments may exceed that of the...thawed sediments would have wanned at all depths, and permafrost would have started to thaw from both the top and the bottom. Eventually, gas...exploration wells (Osterkamp at al., 1985). Destabilization of gas hydrates (by warming the sediments in the continental shelves) during periods of high

Priority-pollutant trace elements in streambed sediments of the Cook Inlet basin, Alaska, 1998-2000

USGS Publications Warehouse

Frenzel, Steven A.

2002-01-01

Trace element concentrations in 48 streambed sediment samples collected at 47 sites in the Cook Inlet Basin, Alaska, were compared to concentrations from studies in the conterminous United States using identical methods and to Probable Effect Concentrations. Concentrations of arsenic, chromium, mercury, and nickel in the 0.063-mm size fraction of streambed sediments from the Cook Inlet Basin were elevated relative to reference sites in the conterminous United States. Concentrations of cadmium, lead, and zinc were highest at the most urbanized site in Anchorage and at two sites downstream from an ore body in Lake Clark National Park and Preserve. At least 35 percent of the 48 samples collected in the Cook Inlet Basin exceeded the Probable Effect Concentration for arsenic, chromium, or nickel. More than 50 percent of the samples were considered to have low potential toxicity for cadmium, lead, mercury, nickel, selenium, and zinc. A Probable Effect Concentration quotient that reflects the combined toxicity of arsenic, cadmium, chromium, copper, lead, mercury, nickel, and zinc was exceeded in 44 percent of the samples from the Cook Inlet Basin. The potential toxicity was high in the Denali and Lake Clark National Parks and Preserves where organic carbon concentrations in streambed sediments were low. However, potential toxicity results should be considered in context with the very small amounts of fine-grained sediment present in the streambed sediments of the Cook Inlet Basin.

The distribution, contamination and risk assessment of heavy metals in sediment and shellfish from the Red Sea coast, Egypt.

PubMed

El Nemr, Ahmed; El-Said, Ghada F; Ragab, Safaa; Khaled, Azza; El-Sikaily, Amany

2016-12-01

Zn, Cu, Ni, V, Al, Pb, Cd, Hg, lipid and water contents were determined in the soft tissues of different shellfish species collected along the Red Sea shoreline. Metal contents showed a descending order of Zn > Cu > Ni > Al > V > Pb > Cd > Hg. The leachable concentrations found in the sediments gathered from the studied locations gave another descending order: Al > Zn > Ni > Pb > V > Cu > Cd. The determined leachable heavy metal contents in the sediment did not exceed the NOAA and CCME (Anonymous 1999) sediment quality guidelines. Accordingly, the sediments along the Egyptian Red Sea area did not pose any adverse impacts on the biological life. According to the hazard quotient (HQ) calculations for heavy metal contents in the soft tissue of shellfish, mercury did not pose any risk on human health; whereas, the other determined heavy metals gave HQ values of 1 < HQ < 10 and showed a possibility of risk on the long term. Cu is above the desirable levels in mussels. The RQ calculations of toddlers and adults reflected that Cu was the only heavy metal that had an adverse effect on toddlers' health. Based on the human organizations (EPA, BOE, MAFF, and NHMRC) that proposed safety concentrations of heavy metals, the studied shellfish were somewhat safe for human consumption. Copyright © 2016 Elsevier Ltd. All rights reserved.

Water-quality conditions of the lower Boise River, Ada and Canyon Counties, Idaho, May 1994 through February 1997

USGS Publications Warehouse

Mullins, William H.

1998-01-01

Agricultural land and water use, wastewater treatment facility discharges, land development, road construction, urban runoff, confined-animal feeding operations, reservoir operations, and river channelization affect the water quality and biotic integrity of the lower Boise River between Lucky Peak Dam and the river's mouth at Parma, Idaho. During May 1994 through February 1997, 4 sites on the Boise River, 12 tributary/drain sites, and 3 wastewater treatment facilities were sampled at various intervals during the irrigation (high-flow) and post-irrigation (low-flow) seasons to determine sources, concentrations, and relative loads of nutrients and suspended sediment. Discharge entering the Boise River from the 12 tributary/drain sites and 3 wastewater treatment facilities was measured to determine the nutrient loads being contributed from each source. Total nitrogen, total phosphorus, and suspended sediment concentrations and loads tended to increase in a downstream direction along the Boise River. Among the 15 sources of discharge to the Boise River, 3 southside tributary/drains and the West Boise wastewater treatment facility contributed the largest loads of total nitrogen; the median daily load was more than 2,000 pounds per day. The West Boise wastewater treatment facility contributed the largest median daily load of total phosphorus (810 pounds per day); Dixie Drain contributed the largest median daily load of suspended sediment (26.4 tons per day). Nitrogen-to-phosphorus ratios at the four Boise River sites indicated that phosphorus could be limiting algal growth at the Diversion Dam site, whereas nitrogen could be limiting algal growth at the Glenwood and Middleton sites during some parts of the year. Algal growth in the Boise River near Parma did not appear to be nutrient limited. Because of the complexity of the plumbing system in the lower Boise River (numerous diversions and inflow points), accurate comparisons between discharge and nutrient loads entering the river at measured sites during high-flow sampling periods were difficult. During low-flow sampling periods, southside tributary/drains contributed most of the discharge and total nitrogen load, and wastewater treatment facilities contributed most of the total phosphorus load to the Boise River. During the 50-day period July 18 through September 5, 1996, the Idaho State standard for maximum daily average temperature for coldwater biota was exceeded by 34 percent at Middleton, 48 percent at Caldwell, and 80 percent near Parma. Violations of State standards for primary and secondary contact recreation were observed at all tributary/ drains and in the Boise River near Parma. Median instantaneous concentrations of fecal coliform bacteria exceeded State standards for primary contact recreation at five tributary/drains and exceeded standards for secondary contact recreation at one tributary/drain (Dixie Drain).

Spatial variation, speciation and sedimentary records of mercury in the Guanabara Bay (Rio de Janeiro, Brazil)

NASA Astrophysics Data System (ADS)

Covelli, Stefano; Protopsalti, Ioanna; Acquavita, Alessandro; Sperle, Marcelo; Bonardi, Maurizio; Emili, Andrea

2012-03-01

As part of the "TAGUBAR" (TAngential GUanabara Bay Aeration Recovery) project, surface and long core sediments of the Guanabara Bay (Rio de Janeiro, Brazil) were investigated for mercury (Hg). The main, but not the only, input of Hg into the Bay's waters is known to be a Chlor-Alkali Plant (CAP) located in the Acarì-São João de Merití River system, on the northwestern side of the Bay. Mercury distribution in surface sediments (<0.1-3.22 mg kg-1, average 0.87±0.80, n=40) seems to be controlled by the organic component, along with sulfur rather than grain-size, where Hg concentrations are less than 1 mg kg-1. Conversely, where the metal contents are higher than 1 mg kg-1, accumulation in surface sediments is mostly related to the presence of nearby contamination sources, such as industrial and urban settlements in the western sector of the Bay. Although total Hg contents in surface sediments exceed the values suggested by the effects-based standard quality guidelines as potentially toxic for the benthic community, results from a sequential extraction procedure showed that the contribution of the more soluble, easily exchangeable and eventually bioavailable Hg phases was found almost negligible (<0.1%). Most of the metal is strongly bound to the mineral lattice of the sedimentary matrix and should therefore be considered almost immobilized. The reduction in Hg accumulation in bottom sediments, expected as a consequence of the adoption of contamination control policies (i.e. Hg-free technologies in the CAP and sewage treating facilities), has not been clearly observed in the core profiles. Current estimates of Hg accumulation rates at the core top range from approximately 1 to 18 mg m-2 yr-1. Pre-industrial bottom core samples indicate that the central and northeastern sectors of the Bay are strongly affected by Hg enrichment: concentrations exceed the estimated baseline concentration by up to 20 factors. A cumulative Hg inventory suggests that the metal content has increased with the same order of magnitude in the vicinity of potential contamination sources on the western side of the Bay, but at a different rate; this is apparently determined by local conditions. A natural attenuation of Hg concentrations to background levels is not predictable in the near future.

An Investigation into Heavy Metal Contamination and Mobilization in the Lower Rouge River, Michigan

NASA Astrophysics Data System (ADS)

Shihadeh, M.; Forrester, J.; Napieralski, J. A.

2010-12-01

Similar to many densely populated watersheds in the Great Lakes Basin, the Rouge River in Michigan drains a heavily urbanized watershed, which, over time, has accumulated a substantial amount of contamination due to decades of manufacturing and refining industries. Statistically significant levels of heavy metals have been found in the bed sediment of the Rouge; however, little is known about the mobilization of these contaminated bed sediments. The goal of this study was to ascertain the extent to which these potentially contaminated sediments are mobilized and transported downstream. Suspended sediment samples were collected at four sites along the lower Rouge River using composite depth integrated sediment samples three times per week, resulting in a total of twenty samples from each site. Turbidity was measured simultaneously using a YSI datalogger at all sampling locations. Sediment was also extracted from floodplain soil pits and silted vegetation, as well as river bed sediment cores along stream channel cross-sections. Heavy metal concentrations (As, Cd, Cr, Cu, Fe, Pb, Hg, Ni, Se, Zn) were analyzed using ICP-MS and compared against both background characteristics for Michigan soils and EPA Hazardous Criteria Limits. As expected, a positive correlation exists between turbidity and heavy metal concentrations. Even in the sampling sites furthest upstream, heavy metal concentrations exceeded background soil characteristics, with a few also exceeding hazardous criteria limits. The heavy metal concentrations found in the Lower Rouge affirm the elevated pollution classification of the river, depict the overall influence of industrialization on stream health, and verify that contaminated sediments are being deposited in aquatic and floodplain environments during variable flow or high discharge events. Results from this study emphasize the need to remediate bed sediments in the Rouge and suggest that there may be significant bioaccumulation potential for organisms inhabiting the floodplain corridor.

Distribution of mercury in molluscs, seawaters and coastal sediments of Tarut Island, Arabian Gulf, Saudi Arabia

NASA Astrophysics Data System (ADS)

Youssef, Mohamed; El-Sorogy, Abdelbaset; Al-Kahtany, Khaled

2016-12-01

In order to assess the distribution of mercury along the Tarut coast, Arabian Gulf, Thirty eight (38) sediment samples, twenty six (26) seawater samples, and forty (40) Mollusca specimens were collected from the Tarut coast. The concentrations of Mercury in the sediments of the studied area (average = 0.55 μg/g) are generally high comparing to the reported values from the Gulf of Oman, Red Sea, and the Gulf of Finland. The concentrations of Hg exceeded the wet threshold safety values (median effect concentration (MEC), and probable effect concentration (PEC) indicating possible Hg contamination. According to the Swedish Environmental Protection Agency (SEPA), thirty four (34) samples occur in class 4 and four (4) samples occur in class 5, which means that the sediments of the Tarut Island are largely contaminated with Hg. Enrichment factor (EF) results (average = 1.76) suggested that, the coastal sediments of the Tarut Island are considered to entirely originate from the crustal materials or natural processes. The studied sediments show lower values (Igeo<0) indicating that the sediments are unpolluted. These sediments according to contamination factor (Cf) are considered contaminated with Hg (1 < CF < 3). The Hg concentration in water samples (average = 30 μg/g) considered high. Comparison with Hg contents in coastal sediments, seawaters and molluscs in the Red Sea, the Arabian Gulf suggested that the studied samples have higher concentrations of Hg. The suggested natural sources of Hg in the study area are the weathering and decomposition of neighboring deserts. The anthropogenic sources are the land reclamation, petrochemical industries, boat exhaust emissions, oil leakage, desalination plants and sewage effluents exceeded in the study area and in Al Jubail industrial city to the north.

Observations of pockmark flow structure in Belfast Bay, Maine, Part 3: implications for sediment transport

USGS Publications Warehouse

Fandel, Christina L.; Lippmann, Thomas C.; Foster, Diane L.; Brothers, Laura L.

2017-01-01

Current observations and sediment characteristics acquired within and along the rim of two pockmarks in Belfast Bay, Maine, were used to characterize periods of sediment transport and to investigate conditions favorable to the settling of suspended sediment. Hourly averaged Shields parameters determined from horizontal current velocity profiles within the center of each pockmark never exceed the critical value (approximated with the theoretical model of Dade et al. 1992). However, Shields parameters estimated at the pockmark rims periodically exceed the critical value, consistent with conditions that support the onset of sediment transport and suspension. Below the rim in the near-center of each pockmark, depth-averaged vertical velocities were less than zero (downward) 60% and 55% of the time in the northern and southern pockmarks, and were often comparable to depth-averaged horizontal velocities. Along the rim, depth-averaged vertical velocities over the lower 8 m of the water column were primarily downward but much less than depth-averaged horizontal velocities indicating that suspended sediment may be moved to distant locations. Maximum grain sizes capable of remaining in suspension under terminal settling flow conditions (ranging 10–170 μm) were typically much greater than the observed median grain diameter (about 7 μm) at the bed. During upwelling flow within the pockmarks, and in the absence of flocculation, suspended sediment would not settle. The greater frequency of predicted periods of sediment transport along the rim of the southern pockmark is consistent with pockmark morphology in Belfast Bay, which transitions from more spherical to more elongated toward the south, suggesting near-bed sediment transport may contribute to post-formation pockmark evolution during typical conditions in Belfast Bay.

Comparability and accuracy of fluvial-sediment data - A view from the U.S. Geological Survey

USGS Publications Warehouse

Gray, J.R.; Glysson, G.D.; Mueller, D.S.; ,

2002-01-01

The quality of historical fluvial-sediment data cannot be taken for granted, based on a review of upper Colorado River basin suspended-sediment discharges, and on an evaluation of the reliability of Total Suspended Solids (TSS) data. Additionally, the quality of future fluvial-sediment data are not assured. Sediment-surrogate technologies, including those that operate on acoustic, laser, bulk optic, digital optic, or pressure differential principles, are being used with increasing frequency to measure in-stream and (or) laboratory fluvial-sediment characteristics. Data from sediment-surrogate technologies may yield results that differ significantly from those obtained by traditional methods for the same sedimentary conditions. Development of national sediment data-quality criteria and rigorous comparisons of data derived from sediment-surrogate technologies to those obtained by traditional techniques will minimize the potential for future fluvial-sediment data-quality concerns.

Concentration, distribution, and translocation of mercury and methylmercury in mine-waste, sediment, soil, water, and fish collected near the Abbadia San Salvatore mercury mine, Monte Amiata district, Italy

USGS Publications Warehouse

Rimondi, V.; Gray, J.E.; Costagliola, P.; Vaselli, O.; Lattanzi, P.

2012-01-01

The distribution and translocation of mercury (Hg) was studied in the Paglia River ecosystem, located downstream from the inactive Abbadia San Salvatore mine (ASSM). The ASSM is part of the Monte Amiata Hg district, Southern Tuscany, Italy, which was one of the world’s largest Hg districts. Concentrations of Hg and methyl-Hg were determined in mine-waste calcine (retorted ore), sediment, water, soil, and freshwater fish collected from the ASSM and the downstream Paglia River. Concentrations of Hg in calcine samples ranged from 25 to 1500 μg/g, all of which exceeded the industrial soil contamination level for Hg of 5 μg/g used in Italy. Stream and lake sediment samples collected downstream from the ASSM ranged in Hg concentration from 0.26 to 15 μg/g, of which more than 50% exceeded the probable effect concentration for Hg of 1.06 μg/g, the concentration above which harmful effects are likely to be observed in sediment-dwelling organisms. Stream and lake sediment methyl-Hg concentrations showed a significant correlation with TOC indicating considerable methylation and potential bioavailability of Hg. Stream water contained Hg as high as 1400 ng/L, but only one water sample exceeded the 1000 ng/L drinking water Hg standard used in Italy. Concentrations of Hg were elevated in freshwater fish muscle samples and ranged from 0.16 to 1.2 μg/g (wet weight), averaged 0.84 μg/g, and 96% of these exceeded the 0.3 μg/g (methyl-Hg, wet weight) USEPA fish muscle standard recommended to protect human health. Analysis of fish muscle for methyl-Hg confirmed that > 90% of the Hg in these fish is methyl-Hg. Such highly elevated Hg concentrations in fish indicated active methylation, significant bioavailability, and uptake of Hg by fish in the Paglia River ecosystem. Methyl-Hg is highly toxic and the high Hg concentrations in these fish represent a potential pathway of Hg to the human food chain.

An evaluation of the relative quality of dike pools for benthic macroinvertebrates in the Lower Missouri River, USA

USGS Publications Warehouse

Poulton, B.C.; Allert, A.L.

2012-01-01

A habitat-based aquatic macroinvertebrate study was initiated in the Lower Missouri River to evaluate relative quality and biological condition of dike pool habitats. Water-quality and sediment-quality parameters and macroinvertebrate assemblage structure were measured from depositional substrates at 18 sites. Sediment porewater was analysed for ammonia, sulphide, pH and oxidation-reduction potential. Whole sediments were analysed for particle-size distribution, organic carbon and contaminants. Field water-quality parameters were measured at subsurface and at the sediment-water interface. Pool area adjacent and downstream from each dike was estimated from aerial photography. Macroinvertebrate biotic condition scores were determined by integrating the following indicator response metrics: % of Ephemeroptera (mayflies), % of Oligochaeta worms, Shannon Diversity Index and total taxa richness. Regression models were developed for predicting macroinvertebrate scores based on individual water-quality and sediment-quality variables and a water/sediment-quality score that integrated all variables. Macroinvertebrate scores generated significant determination coefficients with dike pool area (R2=0.56), oxidation–reduction potential (R2=0.81) and water/sediment-quality score (R2=0.71). Dissolved oxygen saturation, oxidation-reduction potential and total ammonia in sediment porewater were most important in explaining variation in macroinvertebrate scores. The best two-variable regression models included dike pool size + the water/sediment-quality score (R2=0.84) and dike pool size + oxidation-reduction potential (R2=0.93). Results indicate that dike pool size and chemistry of sediments and overlying water can be used to evaluate dike pool quality and identify environmental conditions necessary for optimizing diversity and productivity of important aquatic macroinvertebrates. A combination of these variables could be utilized for measuring the success of habitat enhancement activities currently being implemented in this system.

Water Quality in Big Cypress National Preserve and Everglades National Park - Trends and Spatial Characteristics of Selected Constituents

USGS Publications Warehouse

Miller, Ronald L.; McPherson, Benjamin F.; Sobczak, Robert; Clark, Christine

2004-01-01

Seasonal changes in water levels and flows in Big Cypress National Preserve (BICY) and Everglades National Park (EVER) affect water quality. As water levels and flows decline during the dry season, physical, geochemical and biological processes increase the breakdown of organic materials and the build-up of organic waste, nutrients, and other constituents in the remaining surface water. For example, concentrations of total phosphorus in the marsh are less than 0.01 milligram per liter (mg/L) during much of the year. Concentrations can rise briefly above this value during the dry season and occasionally exceed 0.1 mg/L under drought conditions. Long-term changes in water levels, flows, water management, and upstream land use also affect water quality in BICY and EVER, based on analysis of available data (1959-2000). During the 1980's and early 1990's, specific conductance and concentrations of chloride increased in the Taylor Slough and Shark River Slough. Chloride concentrations more than doubled from 1960 to 1990, primarily due to greater canal transport of high dissolved solids into the sloughs. Some apparent long-term trends in sulfate and total phosphorus were likely attributable, at least in part, to high percentages of less-than and zero values and to changes in reporting levels over the period of record. High values in nutrient concentrations were evident during dry periods of the 1980's and were attributable either to increased canal inflows of nutrient-rich water, increased nutrient releases from breakdown of organic bottom sediment, or increased build-up of nutrient waste from concentrations of aquatic biota and wildlife in remaining ponds. Long-term changes in water quality over the period of record are less pronounced in the western Everglades and the Big Cypress Swamp; however, short-term seasonal and drought-related changes are evident. Water quality varies spatially across the region because of natural variations in geology, hydrology, and vegetation and because of differences in water management and land use. Nutrient concentrations are relatively low in BICY and EVER compared with concentrations in parts of the northern Everglades that are near agricultural and urban lands. Concentrations of total phosphorus generally are higher in BICY (median values, 1991-2000, were mostly greater than 0.015 mg/L) than in EVER (median values, 1991-2000, less than 0.01 mg/L), probably because of higher phosphorus in natural sources such as shallow soils, rocks, and ground water in the Big Cypress region than in the Everglades region. Conversely, concentrations of chloride and sulfate are higher in EVER (median values in Shark River Slough, 1991-2000, mostly greater than 2 mg/L sulfate and 50 mg/L chloride) than in BICY (median values, 1991-2000, less than 1 mg/L sulfate and at most sites less than 20 mg/L chloride), probably because of the canal transport system, which conveys more water from an agricultural source into EVER than into BICY. Trace elements and contaminants such as pesticides and other toxic organic compounds are in relatively low concentrations in BICY and EVER compared with concentrations in parts of the northern Everglades near agricultural and urban sources. Concentrations rarely exceeded aquatic life criteria in BICY and EVER. Atrazine was the only pesticide found in water that exceeded the criteria (in 2 out of 304 samples). The pesticides heptachlor expoxide, lindane, and p,p?-DDE exceeded criteria in canal bed sediments in 1, 2, and 16 percent of the samples, respectively.

Sedimentation rates and patterns in beaver ponds in a mountain environment

NASA Astrophysics Data System (ADS)

Butler, David R.; Malanson, George P.

1995-09-01

Sediment depth was measured at several sites within each of eight beaver ponds in Glacier National Park, Montana, and sediment samples wen; collected from five of these ponds. Accumulation rates of sediments far exceeded published rates from boreal forest landscapes in eastem and central North America. Pond area strongly predicts volume of sedimentation. Textural differences illustrated spatial variations associated with position in a pond and along a pond sequence. Organic matter content was significantly higher in older ponds, and has ramifications for the development of the benthos and the long-term storage of matter in ponds. The role of beavers as biogeomorphic agents is profound, but requires further elucidation to distinguish between fluvial sediment deposition in ponds and sediment deposition associated with beaver excavational activity.

Fecal-indicator bacteria in the Newfound Creek watershed, western North Carolina, during a high and low streamflow condition, 2003

USGS Publications Warehouse

Giddings, Elise M.; Oblinger, Carolyn J.

2004-01-01

Water quality in the Newfound Creek watershed has been shown to be affected by bacteria, sediment, and nutrients. In this study, Escherichia coli (E. coli) bacteria were sampled at five sites in Newfound Creek and five tributary sites during low flow on May 28, 2003, and high flow on November 19, 2003. In addition, a subset of five sites was sampled for fecal coliform bacteria, E. coli bacteria in streambed sediments (low flow only), and coliphage virus for serotyping. Coliphage virus serotyping has been used to identify human and animal sources of bacterial contamination. A streamflow gage was installed and operated to support ongoing water-quality studies in the watershed. Fecal coliform densities ranged from 92 to 27,000 colony-forming units per 100 milliliters of water for E. coli and 140 to an estimated 29,000 colony-forming units per 100 milliliters of water for fecal coliform during the two sampling visits. Ninety percent of the E. coli and fecal coliform samples exceeded corresponding U.S. Environmental Protection Agency or North Carolina water-quality criteria for recreational and ambient waters. During low flow, the middle part of the Newfound Creek watershed and the Dix Creek tributary had the highest densities of E. coli bacteria. During the high-flow sampling, all tributaries contained high densities of E. coli bacteria, although Dix Creek and Round Hill Branch were the largest contributors of these bacteria to Newfound Creek. Coliphage virus serotyping results were inconclusive because most samples did not contain the male-specific RNA coliphage needed for serotyping. Positive results indicated, however, that during low flow, non-human sources of bacteria were present in Sluder Branch, and during high flow, human sources of bacteria were present in Round Hill Branch. Sampling of bacteria in streambed sediments during low flow indicated that sediments do not appear to be a substantial source of bacteria relative to the water column, with the exception of an area near the confluence of Sluder Branch and Newfound Creek.

Chemical quality of surface waters and sedimentation in the Saline River basin, Kansas

USGS Publications Warehouse

Jordan, Paul Robert; Jones, B.F.; Petri, Lester R.

1964-01-01

This report gives the results of an investigation of the sediment and dissolved minerals that are transported by the Saline River and its tributaries. The Saline River basin is in western and central Kansas; it is long and narrow and covers 3,420 square miles of rolling plains, which is broken in some places by escarpments and small areas of badlands. In the western part the uppermost bedrock consists predominantly of calcareous elastic sedimentary rocks of continental origin of Pliocene age and in most places is covered by eolian deposits of Pleistocene and Recent age. In the central part the ex posed bedrock consists predominantly of calcareous marine sedimentary rocks of Late Cretaceous age. In the eastern part the exposed bedrock consists mainly of noncalcareous continental and littoral elastic sedimentary rocks of Early Cretaceous and Permian age. Fluvial deposits are in the valleys, and eolian materials are present over much of the uplands. Average precipitation increases rather uniformly from about 18 inches per year in the west to almost 28 inches per year in the east. Runoff is not affected by irrigation nor regulated by large structures, but it is closely related to precipitation. Average runoff increases from less than 0.2 inch per year in the west to more than 1.5 inches per year in the east. Aquifers of the flood-plain and terrace deposits and of the Cretaceous Dakota Sandstone are the major sources of ground-water accretion to the streams. In the upper reaches of the Saline River, the water is only slightly mineralized; during the period of record the specific conductance near Wakeeney never exceeded 750 micromhos per centimeter. In the lower reaches, however, the water is slightly mineralized during periods of high flow and is highly mineralized during periods of low flow; the specific conductance near Russell exceeded 1,500 micromhos per centimeter more than 80 percent of the time. Near Russell, near Wilson, and at Tescott the water is of the calcium bicarbonate type when the specific conductance is less than about 1,000 micromhos per centimeter, but it is of the sodium chloride type when the specific conductance is more than about 1,500 micromhos per centimeter. The water is off the calcium bicarbonate, sodium bicarbonate, or sodium chloride type when the conductance is between 1,000 and 1,500 micromhos per centimeter. Most of the increase in mineralization of the water is caused by inflow of highly mineralized ground water. The ground-water inflow was estimated to be 22 percent of the total streamflow at Tescott in 1948 and 60 percent in 1952. Mineralization increases and water quality deteriorates progressively downstream along nearly the entire Saline River, especially in the part of the area directly underlain by the Dakota Sandstone between the vicinities of Fairport and Wilson: sodium and chloride are the principal constituents of water contributed by the Dakota. The total percentage of the salt in the Saline River that comes from oil-field brines is considered to be small. The water in the upper Saline River is of good quality for domestic use except that it is hard; the water in the lower Saline River is of poor quality for domestic use because most of the time it is highly mineralized, is hard, and contains high concentrations of chloride and sulfate. In the upper reaches of the river, the water is of good quality for irrigation. In the lower reaches, if the water were impounded in a reservoir, it would be of good quality for irrigation during years of high flow and of very poor quality during years of low flow. The water in the lower reaches is of poor quality for industrial use because it is highly mineralized most of the tinge. Relations of suspended-sediment discharge to water discharge were used with the long-term streamflow duration curves to compute the long-term aver age suspended-sediment discharges and concentrations at five indications. Sediment discharge is closely related to runoff. S

Occurrence, trends, and sources in particle-associated contaminants in selected streams and lakes in Fort Worth, Texas

USGS Publications Warehouse

Van Metre, Peter C.; Wilson, Jennifer T.; Harwell, Glenn R.; Gary, Marcus O.; Heitmuller, Franklin T.; Mahler, Barbara J.

2003-01-01

Several lakes and stream segments in Fort Worth, Texas, have fish consumption bans because of elevated levels of chlordane, dieldrin, DDE, and polychlorinated biphenyls (PCBs). This study was undertaken to evaluate current loading, trends, and sources in these long-banned contaminants and other particle-associated contaminants commonly found in urban areas. Sampling included suspended sediments at 11 sites in streams and bottom-sediment cores in three lakes. Samples were analyzed for chlorinated hydrocarbons, major and trace elements, and polycyclic aromatic hydrocarbons (PAHs). All four legacy pollutants responsible for fish consumption bans were detected frequently. Concentrations of chlordane, lead, and PAHs most frequently exceeded sediment-quality guidelines. Trends in DDE and PCBs since the 1960s generally are decreasing; and trends in chlordane are mixed with a decreasing trend in Lake Como, no trend in Echo Lake, and an increasing trend in Fosdic Lake. All significant trends in trace elements are decreasing, and most significant trends in PAHs are increasing. Sedimentation surveys were conducted on each of the three lakes and used in combination with sediment core data to compute sediment mass balances for the lakes, to estimate long-term-average loads and yields of sediment, and to estimate recent loads and yields of selected contaminants.Concentrations of most trace elements in suspended sediments were similar to those at the tops of cores, but concentrations of many hydrophobic organic contaminants were two to three times larger. As a result, for these fluvial systems, sediment cores probably provide a historical record of trace element contamination but could underestimate historical concentrations of organic contaminants. However, down-core profiles suggest that relative concentration histories are preserved in these sediment cores for many organic contaminants (such as chlordane and total DDT) but not for all (such as dieldrin).Percent urban land use correlates strongly with selected contaminant concentrations in sediments. Organochlorine pesticides had significant correlations to residential land use, whereas PCBs, cadmium, lead, zinc, and PAHs more often correlate significantly with commercial and industrial land uses, which suggests different urban sources for different contaminants. The amount of enrichment in these contaminants associated with urban land use predicted from regression equations, expressed as the ratio of concentrations predicted for 100 percent urban to 30 percent urban, ranges from 3.6 to 6.9 for PCBs and heavy metals to about 15 for chlordane, total DDT, and PAHs. These data indicate that urbanization is having a substantial negative effect on sediment and water quality and that legacy pollutants are being actively transported to streams and lakes 13 to 30 years after their use was restricted or banned. They further suggest that fish in the lakes and these water bodies will continue to be exposed to legacy pollutants in sediment for many years to come.

Heavy metal contamination of sediments in the upper connecting channels of the Great Lakes

USGS Publications Warehouse

Nichols, S. Jerrine; Manny, Bruce A.; Schloesser, Donald W.; Edsall, Thomas A.

1991-01-01

In 1985, sampling at 250 stations throughout the St. Marys, St. Clair, and Detroit rivers and Lake St. Clair — the connecting channels of the upper Great Lakes — revealed widespread metal contamination of the sediments. Concentrations of cadmium, chromium, copper, lead, mercury, nickel, and zinc each exceeded U.S. Environmental Protection Agency sediment pollution guidelines at one or more stations throughout the study area. Sediments were polluted more frequently by copper, nickel, zinc, and lead than by cadmium, chromium, or mercury. Sediments with the highest concentrations of metals were found (in descending order) in the Detroit River, the St. Marys River, the St. Clair River, and Lake St. Clair. Although metal contamination of sediments was most common and sediment concentrations of metals were generally highest near industrial areas, substantial contamination of sediments by metals was present in sediment deposition areas up to 60 km from any known source of pollution.

A comparison of sediment quality results with acid volatile sulfide (AVS) and simultaneously extracted metals (SEM) ratio in Vojvodina (Serbia) sediments.

PubMed

Prica, M; Dalmacija, B; Roncević, S; Krcmar, D; Becelić, M

2008-01-25

The acid-volatile sulfide (AVS), simultaneously extracted metals (SEM), total metals, and pore-water metal concentrations were studied in Vojvodina (Serbia) sediments. In Serbia, there are no regulations concerning sediment quality standards and sediment management. Harmonization of legislation in the domain of environmental protection with EU requirements will increase the significance of the sediment issue. Sediment quality was assessed according to Dutch standards, but the results were also compared with Canadian and USEPA (United States Environmental Protection Agency) guidelines for sediment quality. A comparison of the results based on different criteria for sediment quality assessment shows that they are sometimes contradictory. Therefore, a single approach to quality assessment may be insufficient. The Sigma[SEM]/[AVS] ratio was found to be greater than one at several locations that were already recognized as places of high risk based on Dutch standards. Some other samples had Sigma[SEM]/[AVS]<1, despite of the high risk classification based on the Dutch evaluation. However, not all sediments with Sigma[SEM]/[AVS]>1 can cause increased toxicity because there are many other metal-binding phases in sediments. Metals that are associated with AVS may be released within sediments through storms, dredging activities, oxidation, etc., and may have adverse environmental impacts. This has to be taken into account during dredging, which is for some sediments necessary because the sediment is of class 4 (Dutch evaluation), because the dredging process will certainly increase the concentration of bioavailable heavy metals and disturb the sedimentation dynamics. The obtained results will be invaluable for future activities regarding dredging and sediment management in the country.

The environmental impacts of one of the largest tailing dam failures worldwide.

PubMed

Hatje, Vanessa; Pedreira, Rodrigo M A; de Rezende, Carlos Eduardo; Schettini, Carlos Augusto França; de Souza, Gabriel Cotrim; Marin, Danieli Canaver; Hackspacher, Peter Christian

2017-09-06

The impacts of the SAMARCO iron tailing spill along more than 650 km, between the dam and the plume of the Doce River in the Atlantic, were assessed by the determination of toxic metals. The tailing spill caused a substantial increase in suspended sediment loads (up to 33,000 mg L -1 ), in addition to large depositions of waste along the Doce basin. The highest estimated transport of dissolved metals was observed for Fe (58.8 μg s -1 ), Ba (37.9 μg s -1 ) and Al (25.0 μg s -1 ). Sediments reached the highest enrichment factors (EFs) for Hg (4,234), Co (133), Fe (43), and Ni (16), whereas As (55), Ba (64), Cr (16), Cu (17), Mn (41), Pb (38) and Zn (82) highest EFs were observed for suspended particulate matter (SPM). Iron, As, Hg, Mn exceeded sediment quality guidelines. Therefore, the risk of occurrence of adverse effects is highly possible, not only due to the dam failure, but also due to the Fe mining and the artisan Au mining. Heavy rain episodes will likely cause enhanced erosion, remobilization, and transport of contaminated particles, sustaining high inputs of SPM and metals for the years to come and threatening the ecosystem services.

Role of a Streambed's Benthic Biolayer in Enhancing Chemical Reactions in Hyporheic Flow

NASA Astrophysics Data System (ADS)

Harvey, J. W.

2016-12-01

Chemical processing of metals, nutrients, and organic compounds occurs throughout natural waters, however the rate of reactions often is greater at the streambed interface compared with surface water or deeper groundwater. Hydrologic exchange across the sediment interface brings reactive solutes and fine particulate organic matter from surface waters into contact with the streambed biolayer, a zone with algae and other living microflora and fauna, microbial communities, and reactive geochemical coatings on granular sediments. Compared with surface water or deeper hyporheic sediments, the intrinsic rate of reactions may be stimulated in biolayers because of higher rates of metabolic processing and associated redox reactions. Also, hydrologic transport may enhance reaction rates by relieving potential transport limitations through the re-supply of reactive substrates from surface water. As a result the chemical processing that occurs in the biolayer may far exceed processing that occurs in deeper hyporheic flow. Here I highlight new understanding of enhancement of reaction rates and their hydrologic and biogeochemical controls in streambed biolayers compared with hyporheic flow as a whole. The approach distinguishes and quantifies reaction limitation and transport limitation both at the centimeter-scale within the hyporheic zone and at the river network scale where the effect of streambed reactions accumulates and influences downstream water quality.

DDT residue contamination in sediments from Lake Sibaya in northern KwaZulu-Natal, South Africa: implications for conservation in a World Heritage Site.

PubMed

Humphries, Marc S

2013-11-01

Maputaland in northern KwaZulu-Natal is a biodiversity hotspot and host to a number of ecologically important systems, including Lake Sibaya, southern Africa's largest natural freshwater lake. The region is malaria endemic and this study reports the presence of DDT and its metabolites in the sediments of Lake Sibaya that have resulted from the widespread and continued use of DDT in the region. DDT residues (p,p'-DDT, p,p'-DDD, and p,p'-DDE) were detected at all 11 sites sampled, with total concentrations ranging from 0.8 to 123 ng g(-1). Total DDT concentrations at Lake Sibaya represent some of the highest levels reported in South Africa, with most samples exceeding sediment quality guideline values. The findings from this study raise concerns and indicate that urgent further work is needed to investigate the potential for bioaccumulation, which could adversely affect breeding fish, bird, and crocodile populations in the region. While this study represents the first report on DDT contamination in Lake Sibaya, results have important implications for a number of other aquatic ecosystems within the Maputaland ecoregion, as well as the many local people who depend on them. Copyright © 2013 Elsevier Ltd. All rights reserved.

Water Quality, Sediment Characteristics and Benthic Status of the Razim-Sinoie Lagoon System, Romania

NASA Astrophysics Data System (ADS)

Catianis, Irina; Secrieru, Dan; Pojar, Iulian; Grosu, Dumitru; Scrieciu, Albert; Pavel, Ana Bianca; Vasiliu, Dan

2018-03-01

Razim Lake is the biggest of Romania's freshwater lakes and along with other basins as Golovita, Zmeica and Sinoie constitutes a system of great ecological significance, playing also an essential role in the supply of water for irrigation, fishery exploitation, farming, flood prevention, recreational navigation and water tourism. Due to their importance, the environmental conditions in the Razim - Sinoie coastal lakes have attracted an increased public attention in contemporary society. To assess the levels, dissemination and potential sources of contamination in the above-mentioned lagoon system, random sampling was used to collect water and sediment samples from every lake and several analytical techniques were performed to investigate their environmental characteristics. The results obtained from this study indicated that, in water, concentrations of various physico-chemical parameters are, mostly, in agreement with correlated environmental standards. Slight variations and/or occasional exceeding of the maximum admissible limits were generally limited to small areas showing levels that would not warrant special concern. In sediments, the mean concentrations of some specific trace metals were below the levels of potential effect. Benthic samples revealed 31 taxa belonging to 16 zoo-benthal subdivisions. The results of this study showed good ecological status despite local several natural and anthropogenic stressors as fishery exploitation, farming, recreational navigation and water tourism.

Sedimentary organic biomarkers suggest detrimental effects of PAHs on estuarine microbial biomass during the 20th century in San Francisco Bay, CA, USA

USGS Publications Warehouse

Nilsen, Elena B.; Rosenbauer, Robert J.; Fuller, Christopher C.; Jaffe, Bruce E.

2014-01-01

Hydrocarbon contaminants are ubiquitous in urban aquatic ecosystems, and the ability of some microbial strains to degrade certain polycyclic aromatic hydrocarbons (PAHs) is well established. However, detrimental effects of petroleum hydrocarbon contamination on nondegrader microbial populations and photosynthetic organisms have not often been considered. In the current study, fatty acid methyl ester (FAME) biomarkers in the sediment record were used to assess historical impacts of petroleum contamination on microbial and/or algal biomass in South San Francisco Bay, CA, USA. Profiles of saturated, branched, and monounsaturated fatty acids had similar concentrations and patterns downcore. Total PAHs in a sediment core were on average greater than 20× higher above ∼200 cm than below, which corresponds roughly to the year 1900. Isomer ratios were consistent with a predominant petroleum combustion source for PAHs. Several individual PAHs exceeded sediment quality screening values. Negative correlations between petroleum contaminants and microbial and algal biomarkers – along with high trans/cis ratios of unsaturated FA, and principle component analysis of the PAH and fatty acid records – suggest a negative impacts of petroleum contamination, appearing early in the 20th century, on microbial and/or algal ecology at the site.

Irrigation drainage studies of the Angostura Reclamation Unit and the Belle Fourche Reclamation Project, western South Dakota : results of 1994 sampling and comparisons with 1988 data

USGS Publications Warehouse

Sando, Steven K.; Williamson, Joyce E.; Dickerson, Kimberly K.; Wesolowski, Edwin A.

2001-01-01

The U.S. Department of the Interior started the National Irrigation Water Quality Program in 1985 to identify the nature and extent of irrigation-induced water-quality problems that might exist in the western U.S. The Angostura Reclamation Unit (ARU) and Belle Fourche Reclamation Project (BFRP) in western South Dakota were included as part of this program. The ARU and BFRP reconnaissance studies were initiated in 1988, during below-normal streamflow conditions in both study areas. Surface water, bottom sediment, and fish were resampled in 1994 at selected sites in both study areas during generally near-normal streamflow conditions to compare with 1988 study results. Concentrations of major ions in water for both the ARU and BFRP study areas are high relative to national baseline levels. Major-ion concentrations for both areas generally are lower for 1994 than for 1988, when low-flow conditions prevailed, but ionic proportions are similar between years. For ARU, dissolved-solids concentrations probably increase slightly downstream from Angostura Reservoir; however, the available data sets are insufficient to confidently discern effects of ARU operations on dissolved-solids loading. For BFRP, dissolved-solids concentrations are slightly higher at sites that are affected by irrigation drainage; again, however, the data are inconclusive to determine whether BFRP operations increase dissolved-solids loading. Most trace-element concentrations in water samples for both study areas are similar between 1988 and 1994, and do not show strong relations with discharge. ARU operations probably are not contributing discernible additional loads of trace elements to the Cheyenne River. For BFRP, concentrations of some trace elements are slightly higher at sites downstream from irrigation operations than at a site upstream from irrigation operations. BFRP operations might contribute to trace-element concentrations in the Belle Fourche River, but available data are insufficient to quantify increases. For both study areas, concentrations of several trace elements occasionally exceed National Irrigation Water Quality Program guidelines. Selenium routinely occurs in concentrations that could be problematic at sites upstream and downstream from both study areas. Elevated selenium concentrations at sites upstream from irrigation operations indicate that naturally occurring selenium concentrations are relatively high in and near the study areas. While ARU operations probably do not contribute discernible additional loads of selenium to the Cheyenne River, BFRP operations might contribute additional selenium loads to the Belle Fourche River. Concentrations of most trace elements in bottom sediment, except arsenic and selenium, are similar to typical concentrations for western U.S. soils for both study areas. Bottom-sediment arsenic and selenium (1988) concentrations in both study areas can reach levels that might be of concern; however, there is insufficient information to determine whether irrigation operations contribute to these elevated concentrations. Concentrations of most trace elements in fish in both study areas are less than values known to adversely affect fish or birds, although there are occasional exceedances of established criteria. However, selenium concentrations in fish samples routinely are within the National Irrigation Water Quality Program level of concern, and also commonly exceed the dietary guideline for avian consumers for both study areas. Selenium concentrations in fish samples generally are higher at sites downstream from irrigation operations. For BFRP, arsenic and mercury concentrations are elevated in fish samples from site B-18, which is influenced by mine tailings.

Comparison of turbidity to multi-frequency sideways-looking acoustic-Doppler data and suspended-sediment data in the Colorado River in Grand Canyon

USGS Publications Warehouse

Voichick, Nicholas; Topping, David J.

2010-01-01

Water clarity is important to biologists when studying fish and other fluvial fauna and flora. Turbidity is an indicator of the cloudiness of water, or reduced water clarity, and is commonly measured using nephelometric sensors that record the scattering and absorption of light by particles in the water. Unfortunately, nephelometric sensors only operate over a narrow range of the conditions typically encountered in rivers dominated by suspended-sediment transport. For example, sediment inputs into the Colorado River in Grand Canyon caused by tributary floods often result in turbidity levels that exceed the maximum recording level of nephelometric turbidity sensors. The limited range of these sensors is one reason why acoustic Doppler profiler instrument data, not turbidity, has been used as a surrogate for suspended sediment concentration and load of the Colorado River in Grand Canyon. However, in addition to being an important water-quality parameter to biologists, turbidity of the Colorado River in Grand Canyon has been used to strengthen the suspended-sediment record through the process of turbidity-threshold sampling; high turbidity values trigger a pump sampler to collect samples of the river at critical times for gathering suspended-sediment data. Turbidity depends on several characteristics of suspended sediment including concentration, particle size, particle shape, color, and the refractive index of particles. In this paper, turbidity is compared with other parameters coupled to suspended sediment, namely suspended-silt and clay concentration and multifrequency acoustic attenuation. These data have been collected since 2005 at four stations with different sediment-supply characteristics on the Colorado River in Grand Canyon. These comparisons reveal that acoustic attenuation is a particularly useful parameter, because it is strongly related to turbidity and it can be measured by instruments that experience minimal fouling and record over the entire range of turbidity encountered in the Colorado River in Grand Canyon. Relating turbidity to acoustic attenuation and suspended-silt and clay concentration provides an additional benefit in that data outliers are revealed that likely identify inflow events from anomalous sources with unusual sediment characteristics.

40 CFR 435.13 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2013 CFR

2013-07-01

... sediment toxicity ratio 6 shall not exceed 1.0. Biodegradation rate Biodegradation rate ratio 7 shall not...). 7 Biodegradation rate ratio = Cumulative headspace gas production (ml) of C16-C18 internal olefin... fluids that meet the base fluid sediment toxicity ratio (Footnote 6), biodegradation rate ratio (Footnote...

40 CFR 435.13 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2014 CFR

2014-07-01

... sediment toxicity ratio 6 shall not exceed 1.0. Biodegradation rate Biodegradation rate ratio 7 shall not...). 7 Biodegradation rate ratio = Cumulative headspace gas production (ml) of C16-C18 internal olefin... fluids that meet the base fluid sediment toxicity ratio (Footnote 6), biodegradation rate ratio (Footnote...

40 CFR 435.13 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the...

Code of Federal Regulations, 2012 CFR

2012-07-01

... sediment toxicity ratio 6 shall not exceed 1.0. Biodegradation rate Biodegradation rate ratio 7 shall not...). 7 Biodegradation rate ratio = Cumulative headspace gas production (ml) of C16-C18 internal olefin... fluids that meet the base fluid sediment toxicity ratio (Footnote 6), biodegradation rate ratio (Footnote...

Advanced Water Quality Modelling in Marine Systems: Application to the Wadden Sea, the Netherlands

NASA Astrophysics Data System (ADS)

Boon, J.; Smits, J. G.

2006-12-01

There is an increasing demand for knowledge and models that arise from water management in relation to water quality, sediment quality (ecology) and sediment accumulation (ecomorphology). Recently, models for sediment diagenesis and erosion developed or incorporated by Delft Hydraulics integrates the relevant physical, (bio)chemical and biological processes for the sediment-water exchange of substances. The aim of the diagenesis models is the prediction of both sediment quality and the return fluxes of substances such as nutrients and micropollutants to the overlying water. The resulting so-called DELWAQ-G model is a new, generic version of the water and sediment quality model of the DELFT3D framework. One set of generic water quality process formulations is used to calculate process rates in both water and sediment compartments. DELWAQ-G involves the explicit simulation of sediment layers in the water quality model with state-of-the-art process kinetics. The local conditions in a water layer or sediment layer such as the dissolved oxygen concentration determine if and how individual processes come to expression. New processes were added for sulphate, sulphide, methane and the distribution of the electron-acceptor demand over dissolved oxygen, nitrate, sulphate and carbon dioxide. DELWAQ-G also includes the dispersive and advective transport processes in the sediment and across the sediment-water interface. DELWAQ-G has been applied for the Wadden Sea. A very dynamic tidal and ecologically active estuary with a complex hydrodynamic behaviour located at the north of the Netherlands. The predicted profiles in the sediment reflect the typical interactions of diagenesis processes.

Streamflow transport of radionuclides and other chemical constituents in the Puerco and the Little Colorado river basins, Arizona and New Mexico

USGS Publications Warehouse

Graf, Julia B.; Wirt, Laurie; Swanson, E.K.; Fisk, G.G.; Gray, J.R.

1996-01-01

Samples collected at streamflow-gaging stations in the Puerco and Little Colorado rivers show that radioactivity of suspended sediment at gaging stations downstream from inactive uranium mines was not significantly higher than at gaging stations where no mining has occurred upstream. Drinking-water standards for many constituents, however, commonly are exceeded during runoff because concentration of these constituents on sediment from natural processes is high and suspended-sediment loads are high during runoff.

Effects of anthropogenic activities on chemical contamination within the Grand Canal, China.

PubMed

Wang, Xiaolong; Han, Jingyi; Xu, Ligang; Gao, Junfeng; Zhang, Qi

2011-06-01

Contamination of nutrients and heavy metals within aquatic system is of great concern due to its potential impact on human and animal health. The Grand Canal of China, the largest artificial river in the world, is of great importance in supplying water resource, transporting cargo, and recreating resident, as well as great historical heritage. This study assessed and examined the impact of human activities on characters of contamination distribution within the section of the Canal in Taihu watershed. Physicochemical parameters of surface water quality were determined monthly from the year 2004 to 2006 at 11 sites that were influenced by different anthropogenic activities along the Canal. Moreover, contaminations at surface sediments (20 cm) at the same locations were also analyzed in September 2006. Results showed that the Canal had been seriously polluted, which was characterized with high spatial variations in contaminations distribution. The sites influenced mainly by industry and urbanization showed higher contents of nutrients and lower levels of dissolve oxygen than other sites. Concentrations of nitrogen at all studied sites exceeded the worst level of surface water quality according to the National Criterion of Surface Water Quality, China, with the average values varying from 2.27 to 10.34 mg/L. Furthermore, the site influenced mainly by industry (i.e., Site 4) presented the highest contents of cadmium (3.453 mg/kg), chromium (196.87 mg/kg), nickel (87.12 mg/kg), zinc (381.8 mg/kg), and copper (357.32 mg/kg). While sites in vicinity to cities had presented relatively higher contents of metals, especially for the site located downstream of Changzhou City (Site 3) had presented the highest contents of mercury (1.64 mg/kg) and lead (197.62 mg/kg). Copper at Sites 2 to 6, Nickel at Sites 2 to 9 except for Site 7, chromium, lead, and zinc at Sites 3 to 6 had exceeded New York State Department of Environmental Conservation (NYSDEC) Severe Effect Level (SEL). By multivariate statistical, nutrient variables, companied with V-phen, had contributed the most variation of water quality, while nutrient and metals had explained the most part of total variance of contaminations in sediment. This study indicated that the canal had been polluted severely and urgently need to control.

Fluvial sediment in the environment: a national challenge

USGS Publications Warehouse

Larsen, Matthew C.; Gellis, Allen C.; Glysson, G. Douglas; Gray, John R.; Horowitz, Arthur J.

2010-01-01

Sediment and sediment-associated constituents can contribute substantially to water-quality impairment. In the past, sediment was viewed mainly as an engineering problem that affected reservoir storage capacity, shipping channel maintenance, and bridge scour, as well as the loss of agricultural soil. Sediment is now recognized as a major cause of aquatic system degradation in many rivers and streams as a result of light attenuation, loss of spawning substrate due to fine-grained sediment infilling, reduction in primary productivity, decreases in biotic diversity, and effects from sediment-associated chemical constituents. Recent advances in sediment measurement, assessment, source-identification, and analytical protocols provide new capabilities to quantify sediment and solid-phase chemical fluxes in aquatic systems. Developing, maintaining, and augmenting current sediment- and water-quality-monitoring networks is essential for determining the health of U.S. waterways and for evaluating the effectiveness of management actions in reducing sediment-related problems. The application of new scientific capabilities that address the adverse effects of sediment and sediment- associated constituents represents a major step in managing the Nation’s water quality. A robust Federal, national-scale eff rt, in collaboration with vested stakeholders, is needed to address these sediment-related water-quality issues across the United States.

Quality-assurance plan for the analysis of fluvial sediment by laboratories of the U.S. Geological Survey

USGS Publications Warehouse

Matthes, Wilbur J.; Sholar, Clyde J.; George, John R.

1992-01-01

This report describes procedures used by the Iowa District sediment laboratory of the U.S. Geological Survey to assure the quality of sediment-laboratory data. These procedures can be used by other U.S. Geological Survey laboratories regardless of size and type of operation for quality assurance and quality control of specific sediment-laboratory processes. Also described are the equipment, specifications, calibration and maintenance, and the protocol for methods used in the analyses of fluvial sediment for concentration or particle size.

Quality-assurance plan for the analysis of suspended sediment by the U.S. Geological Survey in Montana

USGS Publications Warehouse

Dodge, Kent A.; Lambing, John H.

2006-01-01

A quality-assurance plan has been developed for use by the sediment laboratory of the U.S. Geological Survey Montana Water Science Center in conducting activities related to the analysis of suspended sediment. The plan documents quality-assurance policies for sediment-laboratory certification, personnel responsibilities and training, documentation requirements, and laboratory safety. The plan also documents quality-assurance procedures related to laboratory equipment and supplies, sample management, sample analysis, analytical quality control, and data management.

Deposition behavior, risk assessment and source identification of heavy metals in reservoir sediments of Northeast China.

PubMed

Zhu, Lin; Liu, Jianwei; Xu, Shiguo; Xie, Zaigang

2017-08-01

Sediment cores from five reservoirs, located in the Liaoning and Jilin Provinces in Northeast China, were collected to investigate the accumulation and potential toxicity of heavy metals (Fe, Mn, Cu, Cd, Pb, Zn, and Cr) during a sampling campaign in February, 2015. The results showed that all the detected metals accumulated significantly, especially Cd, compared to their respective background values. Among these reservoirs, Biliuhe Reservoir had markedly increasing trends for organic matter and all the metals, among which Mn was elevated by 280% to 3411mg/kg in a core of only 18cm in depth. Xinlicheng Reservoir was characterized by heavy siltation and varying metal distribution due to its regular geometric features and pulsed flood events. The Enrichment factor (EF) and geo-accumulation index (I geo ) indicated Cd was strongly enriched by anthropogenic inputs, with the values of EF and I geo greater than 8 and 3, respectively. The toxicity assessment calculated using consensus-based sediment quality guidelines (SQGs) implied the whole cores of Tanghe and Dahuofang and the upper cores of Biliuhe, Xinlicheng and Fengman exhibited toxicity to sediment-dwelling organisms. Cr contributed more to Q m-PEC than the other heavy metals, because only Cr exceeded the probable effect concentration (PEC) despite its low enrichment. According to the results of correlation analysis (CA) and principal components analysis (PCA), mining industries and agricultural activities within the basin were the main anthropogenic pollution sources for these heavy metals. Copyright © 2017 Elsevier Inc. All rights reserved.

Microbial dechlorination of polychlorinated biphenyls, dibenzo-p-dioxins, and -furans at the Portland Harbor Superfund site, Oregon, USA.

PubMed

Rodenburg, Lisa A; Krumins, Valdis; Curran, Joanna Crowe

2015-06-16

The Portland Harbor (Oregon, USA) has been declared a "Superfund" site because it is impacted by a variety of contaminants, including polychlorinated biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins and -furans (PCDD/Fs). Using data collected in the remedial investigation, concentrations of PCBs and PCDD/Fs in sediment and water were examined using positive matrix factorization to look for evidence that PCBs and PCDD/Fs are dechlorinated by anaerobic bacteria. This process has long been known to occur in sediments. Recently, it has been recognized that PCB and PCDD/F dechlorination may also occur in other anaerobic environments, such as in landfills, sewers, and groundwater. The results indicate that a factor related to the dechlorination of PCBs and PCDD/Fs was present in the water but not in the sediment. Spatial patterns in dechlorination products suggest that they come primarily from groundwater. Dechlorination products comprise 22% of the PCBs in the water. The Portland Harbor therefore represents the third major US watershed in which PCBs appear to undergo dechlorination in an environment other than sediment, suggesting that the microbial dechlorination of PCBs and PCDD/Fs is more common than previously assumed. In addition, the Portland Harbor is impacted by PCBs generated inadvertently during the production of pigments, such as PCB 11, which alone exceeded the 64 pg/L federal water quality standard for the sum of PCBs in two of 120 whole water samples.

Compilation, quality control, analysis, and summary of discrete suspended-sediment and ancillary data in the United States, 1901-2010

USGS Publications Warehouse

Lee, Casey J.; Glysson, G. Douglas

2013-01-01

Human-induced and natural changes to the transport of sediment and sediment-associated constituents can degrade aquatic ecosystems and limit human uses of streams and rivers. The lack of a dedicated, easily accessible, quality-controlled database of sediment and ancillary data has made it difficult to identify sediment-related water-quality impairments and has limited understanding of how human actions affect suspended-sediment concentrations and transport. The purpose of this report is to describe the creation of a quality-controlled U.S. Geological Survey suspended-sediment database, provide guidance for its use, and summarize characteristics of suspended-sediment data through 2010. The database is provided as an online application at http://cida.usgs.gov/sediment to allow users to view, filter, and retrieve available suspended-sediment and ancillary data. A data recovery, filtration, and quality-control process was performed to expand the availability, representativeness, and utility of existing suspended-sediment data collected by the U.S. Geological Survey in the United States before January 1, 2011. Information on streamflow condition, sediment grain size, and upstream landscape condition were matched to sediment data and sediment-sampling sites to place data in context with factors that may influence sediment transport. Suspended-sediment and selected ancillary data are presented from across the United States with respect to time, streamflow, and landscape condition. Examples of potential uses of this database for identifying sediment-related impairments, assessing trends, and designing new data collection activities are provided. This report and database can support local and national-level decision making, project planning, and data mining activities related to the transport of suspended-sediment and sediment-associated constituents.

An evaluation of selenium concentrations in water, sediment, invertebrates, and fish from the Republican River Basin: 1997-1999.

PubMed

May, T W; Walther, M J; Petty, J D; Fairchild, J F; Lucero, J; Delvaux, M; Manring, J; Armbruster, M; Hartman, D

2001-11-01

The Republican River Basin of Colorado, Nebraska, and Kansas lies in a valley which contains Pierre Shale as part of its geological substrata. Selenium is an indigenous constituent in the shale and is readily leached into surrounding groundwater. The Basin is heavily irrigated through the pumping of groundwater, some of which is selenium-contaminated, onto fields in agricultural production. Water, sediment, benthic invertebrates, and/or fish were collected from 46 sites in the Basin and were analyzed for selenium to determine the potential for food-chain bioaccumulation, dietary toxicity, and reproductive effects of selenium in biota. Resulting selenium concentrations were compared to published guidelines or biological effects thresholds. Water from 38% of the sites (n = 18) contained selenium concentrations exceeding 5 microg L(-1), which is reported to be a high hazard for selenium accumulation into the planktonic food chain. An additional 12 sites (26% of the sites) contained selenium in water between 3-5 microg L(-1), constituting a moderate hazard. Selenium concentrations in sediment indicated little to no hazard for selenium accumulation from sediments into the benthic food chain. Ninety-five percent of benthic invertebrates collected exhibited selenium concentrations exceeding 3 microg g(-1), a level reported as potentially lethal to fish and birds that consume them. Seventy-five percent of fish collected in 1997, 90% in 1998, and 64% in 1999 exceeded 4 microg g(-1) selenium, indicating a high potential for toxicity and reproductive effects. However, examination of weight profiles of various species of collected individual fish suggested successful recruitment in spite of selenium concentrations that exceeded published biological effects thresholds for health and reproductive success. This finding suggested that universal application of published guidelines for selenium may be inappropriate or at least may need refinement for systems similar to the Republican River Basin. Additional research is needed to determine the true impact of selenium on fish and wildlife resources in the Basin.

Water-Quality and Biological Assessment of the Iowa River and Tributaries Within and Contiguous to the Meskwaki Settlement of the Sac and Fox Tribe of the Mississippi in Iowa, 2006-07

USGS Publications Warehouse

Littin, Gregory R.; McVay, Jason C.

2009-01-01

In cooperation with the Sac and Fox Tribe of the Mississippi in Iowa (Meskwaki Nation), the U.S. Geological Survey conducted a 2-year baseline assessment of the chemical and biological quality of streams within the Meskwaki Settlement in central Iowa. The Meskwaki Nation is a federally recognized tribe that wishes to establish water-quality standards to safeguard the integrity of surface waters and aquatic biota within the settlement for the health and welfare of the tribal community. The settlement is drained by the Iowa River and four tributaries (Onion, Cattail, Raven, and Bennett Creeks). Water-quality samples were collected at three sites on the Iowa River, two sites on Onion Creek, and one site each on Cattail, Raven, and Bennett Creeks from April 2006 through July 2007. Biological and habitat assessments were conducted at all three sites on the Iowa River and the downstream-most site on Onion Creek from June through August 2007. Analysis of physical properties, major ions, nutrients, trace compounds, bacteria, and total suspended solids in water, and trace metals and organic compounds in streambed sediment provided information about the effects of anthropogenic (human related) activities on the water quality of settlement streams. Analysis of biological samples collected during the summer of 2007, including fish community, benthic macroinvertebrates, and periphyton samples, as well as physical habitat characteristics, provided information on the effects of water quality on the condition of the aquatic environment. The majority of surface water sampled within the settlement was predominately a calcium bicarbonate type. Nitrates (nitrate plus nitrite as nitrogen) exceeded the U.S. Environmental Protection Agency's (USEPA) primary drinking-water Maximum Contaminant Level of 10 ug/L in 19 of 36 samples from sites on the Iowa River and Raven and Bennett Creeks but not in samples from Onion and Cattail Creeks. None of the samples analyzed for pesticides, trace metals, wastewater, or fuel contaminants were found to exceed drinking-water regulations for the USEPA or State of Iowa targeted constituents. Bacteria densities for Escherichia coli (E. coli) ranged from less than 10 to more than 600,000 colony-forming units per 100 milliliters of water and were largest following intense rainfall runoff. The largest densities were recorded in samples collected from the tributaries, most notably from Cattail Creek downstream from the tribal headquarters area and Onion Creek downstream from the sewage lagoons. Arsenic and nickel concentrations in bottom sediment from Onion Creek exceeded the USEPA threshold effects level in a composite sample collected during the habitat assessment in July 2007. Suspended-sediment concentration was estimated in terms of total suspended solids. Overall, Onion and Bennett Creeks were the least turbid, whereas the ephemeral Cattail Creek had the most turbid samples. Aquatic-community data were collected at four sites on the Meskwaki Settlement during the summer of 2007 to provide a baseline biological assessment of stream conditions. This assessment was based on sampling of the fish, benthic macroinvertebrate, and periphyton communities along with physical habitat characteristics. Individual biological metrics were derived from the data collected during the community surveys. These metrics were used to calculate Indexes of Biological Integrity (IBIs). The calculated values from the IBIs provided a numerical value that was used to provide an assessment of the biological condition at each biological sampling site. The fish community samples indicated that all of the sampling sites would be considered in fair condition, with one exception being a collection site on the Iowa River at Highway 49 near Tama, Iowa, which was classified in poor condition. The benthic macroinvertebrate IBI indicated a classification of good for three of the four biological sampling sites, with the Iowa River near Montour, Iowa,

Water-quality, bed-sediment, and biological data (October 2012 through September 2013) and statistical summaries of data for streams in the Clark Fork Basin, Montana

USGS Publications Warehouse

Dodge, Kent A.; Hornberger, Michelle I.; Dyke, Jessica

2014-01-01

This report presents the analytical results and quality-assurance data for water-quality, bed-sediment, and biota samples collected at sites from October 2012 through September 2013. Water-quality data include concentrations of selected major ions, trace elements, and suspended sediment. Turbidity and dissolved organic carbon were analyzed for water samples collected at the four sites where seasonal daily values of turbidity were being determined. Daily values of mean suspended-sediment concentration and suspended-sediment discharge were determined for four sites. Bed-sediment data include trace-element concentrations in the fine-grained fraction. Biological data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Statistical sum-maries of water-quality, bed-sediment, and biological data for sites in the upper Clark Fork Basin are provided for the period of record.

Characterization of water quality in Government Highline Canal at Camp 7 Diversion and Highline Lake, Mesa County, Colorado, July 2000 through September 2003

USGS Publications Warehouse

Ortiz, Roderick F.

2004-01-01

The U.S. Geological Survey, in cooperation with the Colorado Division of Parks and Recreation, collected and analyzed water-quality data for the Government Highline Canal and Highline Lake from July 2000 through September 2003. Implementation of modernization strategies for the canal, which supplies most of the water to the lake, would decrease the amount of water spilled to Highline Lake from August through October. A reduction in spill water into Highline Lake could adversely affect the recreational uses of the lake. To address this concern and to characterize the water quality in the Government Highline Canal and Highline Lake, the U.S. Geological Survey conducted a study to evaluate limnological conditions prior to implementation of the modernization strategies. This report characterizes the water quality of inflow from the Government Canal and in Highline Lake prior to implementation of modernization strategies in the Government Canal. Flow entering the lake from the Government Canal was characterized using field properties and available chemical, sediment, and bacteria concentrations. Data collected at Highline Lake were used to characterize the seasonal stratification patterns, water-quality chemistry, bacteria populations, and phytoplankton community structure in the lake. Data used for this report were collected at one inflow site to the lake and four sites in Highline Lake. Highline Lake is a mesotrophic/eutrophic lake that has dimictic thermal stratification patterns. Samples collected in the photic zone indicated that there was little physical, chemical, or biological variability at this depth at any of the sampled sites in Highline Lake. Strong thermal and dissolved-oxygen stratification patterns were observed during summer. Dissolved-oxygen concentrations of less than 1 milligram per liter were observed during the summer. Ammonia likely was released from the bottom sediments of Highline Lake. The limiting nutrient in Highline Lake could be nitrogen or phosphorus. In general, the seasonal succession of phytoplankton was similar to that of other lakes in the temperate zone. Several types of algae associated with taste and odor issues were identified in samples, but critical concentrations were not exceeded for any listed algal group with the exception of the diatom genus Cyclotella in one sample. Bacteria concentrations were determined at the public swim beach at Highline Lake. E. coli samples were collected periodically by the USGS and weekly by the Colorado Division of Parks and Recreation. During the study period, no reported E. coli concentration exceeded the standard for natural swimming areas. Inflow water quality was characterized by samples collected at the Camp 7 check structure on the Government Canal. Inflow water temperatures reflected the seasonal patterns of the source water in the Colorado River. The water was well oxygenated. Nitrogen and phosphorus concentrations were low, and concentrations did not differ substantially from year to year or seasonally within a year. All samples had reportable numbers of fecal streptococcus. The maximum reported concentration of E. coli was reported at 77 colonies per 100 milliliters of sample. Suspended-sediment concentrations were relatively low.

Selected organic compounds and trace elements in streambed sediments and fish tissues, Cook Inlet Basin, Alaska

USGS Publications Warehouse

Frenzel, Steven A.

2000-01-01

Organochlorines, semivolatile organic compounds (SVOCs), and trace elements were investigated in streambed sediments and fish tissues at selected sites in the Cook Inlet Basin, Alaska, during 1998. At most sites, SVOCs and organochlorine compounds were either not detected or detected at very low concentrations. Chester Creek at Arctic Boulevard at Anchorage, which was the only site sampled with a significant degree of development in the watershed, had elevated levels of many SVOCs in streambed sediment. Coring of sediments from two ponds on Chester Creek confirmed the presence of elevated concentrations of a variety of organic compounds. Moose Creek, a stream with extensive coal deposits in its watershed, had low concentrations of numerous SVOCs in streambed sediment. Three sites located in national parks or in a national wildlife refuge had no detectable concentrations of SVOCs. Trace elements were analyzed in both streambed sediments and tissues of slimy sculpin. The two media provided similar evidence for elevated concentrations of cadmium, lead, and zinc at Chester Creek. In this study, 'probable effect levels '(PELs) were determined from sediments finer than 0.063 millimeters, where concentrations tend to be greatest. Arsenic and chromium concentrations exceeded the PEL at eight and six sites respectively. Zinc exceeded the PEL at one site. Cadmium and copper concentrations were smaller than the PEL at all sites. Mercury concentrations in streambed sediments from the Deshka River were near the PEL, and selenium concentrations at that site also appear to be elevated above background levels. At half the sites where slimy sculpin were sampled, selenium concentrations were at levels that may cause adverse effects in some species.

Surficial geology and distribution of post-impoundment sediment of the western part of Lake Mead based on a sidescan sonar and high-resolution seismic-reflection survey

USGS Publications Warehouse

Twichell, David C.; Cross, VeeAnn A.; Rudin, Mark J.; Parolski, Kenneth F.

1999-01-01

Sidescan sonar imagery and high-resolution seismic-reflection profiles were collected in Las Vegas Bay and Boulder Basin of Lake Mead to determine the surficial geology as well as the distribution and thickness of sediment that has accumulated in these areas of the lake since the completion of Hoover Dam in 1935 (Gould, 1951). Results indicate that the accumulation of post-impoundment sediment is restricted to the original Colorado River bed which runs down the axis of Boulder Basin from Boulder Canyon to Hoover Dam, and the old Las Vegas Creek bed that bisects Las Vegas Bay. The sediment cover along the original Colorado River bed is continuous and is typically greater than 10-m thick throughout much of its length with the thickness in some areas exceeding 35 meters. The flat-lying nature of the deposits suggests that they are the result of turbidity currents that flow the length of the lake. The sediment cover in Las Vegas Bay is much thinner (rarely exceeding 2 m in thickness) and more discontinuous. The source for these sediments presumably is Las Vegas Wash and a series of other ephemeral washes that empty into this part of the lake. The presence of sediments along the entire length of the Las Vegas Creek bed suggests that turbidity currents probably are active here as well, and that sediment has been transported from these streams at least 10 km down the axis of this valley to where it enters Boulder Basin. Alluvial deposits and rock outcrops are still exposed on large parts of the lake floor.

Characterizing Cretaceous Glaciation Events: K-Ar Ages of Southern Ocean Sediments

NASA Astrophysics Data System (ADS)

Wright, M. A.; Hemming, S. R.; Barbeau, D. L.; Torfstein, A.; Pierce, E. L.; Williams, T.; McManus, J. F.; Gombiner, J.

2012-12-01

Evidence from paleosols and carbonate weathering models suggest that the Late Cretaceous had a supergreenhouse climate due to atmospheric CO2 concentrations two to four times greater than modern levels, tropical sea surface temperatures exceeding 35°C, and high-latitude temperatures exceeding 20°C. Despite this warmth, the Late Cretaceous was apparently punctuated by large (>25 m) and rapid (<<1 million year) sea-level changes, as recorded by marginal marine stratigraphic architectures and pelagic stable isotope compositions. The magnitude and tempo of these changes suggest a glacio-eustatic control, presumably from the growth and decay of continental ice sheets on Antarctica. Because continental glaciation tends to increase the weathering of bedrock and production of sediment delivered to the oceans, circum-Antarctic marine sediment flux would be expected to increase during periods of glaciation. In order to identify a Late Cretaceous glaciation signal from such marine records, we must first constrain the compositional signal of continental detritus in marine sediments. Here we report the results of downcore K-Ar analysis of the terrigenous sediments of Quaternary Weddell Sea cores PS1170-1 and PS1388-3 in order to identify the compositional signature of continent-derived detritus deposited in the Weddell Sea during a known glacial period. Further, we use our K-Ar analyses of circum-Antarctic Quaternary sediment cores to pinpoint potential sediment source areas. Having constrained this glaciation signal, we also present preliminary K-Ar and Sm-Nd analysis of the Campanian-Maastrictian boundary event (69 Ma) at Ocean Drilling Project site 690C to assess the controversial hypothesis of Late Cretaceous glaciation of Antarctica.

Radioactivity in the environment; a case study of the Puerco and Little Colorado River basins, Arizona and New Mexico

USGS Publications Warehouse

Wirt, Laurie

1994-01-01

This report, written for the nontechnical reader, summarizes the results of a study from 1988-91 of the occurrence and transport of selected radionuclides and other chemical constituents in the Puerco and Little Colorado River basins, Arizona and New Mexico. More than two decades of uranium mining and the 1979 failure of an earthen dam containing mine tailings released high levels of radionuclides and other chemical constituents to the Puerco River, a tributary of the Little Colorado River. Releases caused public concern that ground water and streamflow downstream from mining were contaminated. Study findings show which radioactive elements are present, how these elements are distributed between water and sediment in the environment, how concentrations of radioactive elements vary naturally within basins, and how levels of radioactivity have changed since the end of mining. Although levels of radioactive elements and other trace elements measured in streamflow commonly exceed drinking-water standards, no evidence was found to indicate that the high concentrations were still related to uraniurn mining. Sediment radioactivity was higher at sample sites on streams that drain the eastern part of the Little Colorado River basin than that of samples from the western part. Radioactivity of suspended sediment measured in this study, therefore, represents natural conditions for the streams sampled rather than an effect of mining. Because ground water beneath the Puerco River channel is shallow, the aquifer is vulnerable to contamination. A narrow zone of ground water beneath the Puerco River containing elevated uranium concentrations was identified during the study. The highest concentrations were nearest the mines and in samples collected in the first few feet beneath the streambed. Natuxal radiation levels in a few areas of the underlying sedimentary aquifer not connected to the Puerco River also exceeded water quality standards. Water testing would enable those residents not using public water supplies to determine if their water is safe to use.

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the middle Green River basin, Utah, 1986-87

USGS Publications Warehouse

Stephens, D.W.; Waddell, Bruce; Miller, J.B.

1988-01-01

Reconnaissance of wildlife areas in the middle Green River basin of Utah was conducted during 1986 and 1987 to determine whether irrigation drainage has caused, or has the potential to cause significant harmful effects on human health, fish, and wildlife, or may adversely affect the suitability of water for beneficial uses. Studies at Stewart Lake Waterfowl Management Area and Ouray National Wildlife Refuge indicated that concentrations of boron, selenium, and zinc in water, bottom sediment, and biological tissue were sufficiently large to be harmful to fish and wildlife, and to adversely affect beneficial uses of water. Selenium is the principal element of concern in both areas. Concentrations of dissolved selenium in irrigation drain water entering Stewart Lake Waterfowl Management Area ranged from 14-140 micrograms/L (ug/L) and consistently exceeded Utah standards for wildlife protection in water in two of the four drains. Concentrations of boron and zinc exceeded Utah standards only occasionally in the drain waters. Concentrations of total selenium in sediments collected where the drains discharge into the lake were 10-85 ug/gm. Liver tissue collected from American coots at Stewart Lake Waterfowl Management Area contained concentrations of selenium from 4.9-26 ug/gm (dry weight), and whole body samples of carp contained as much as 31 ug/gm (dry weight). Concentrations of selenium in Potamogeton and blue-green algae ranged from 2.1-27 ug/gm. Concentrations of boron, selenium, and zinc were also measured in water from Ouray National Wildlife Refuge. Liver tissue of American coots from the North Roadside Pond, which receives irrigation tailwater, contained a geometric-mean concentration of selenium of 32 ug/gm (dry weight). Five water-bird eggs collected from the North and South Roadside Ponds contained selenium concentrations of 63-120 ug/gm (dry weight). (Lantz-PTT)

Sedimentation and Its Impacts/Effects on River System and Reservoir Water Quality: case Study of Mazowe Catchment, Zimbabwe

NASA Astrophysics Data System (ADS)

Tundu, Colleta; Tumbare, Michael James; Kileshye Onema, Jean-Marie

2018-04-01

Sediment delivery into water sources and bodies results in the reduction of water quantity and quality, increasing costs of water purification whilst reducing the available water for various other uses. The paper gives an analysis of sedimentation in one of Zimbabwe's seven rivers, the Mazowe Catchment, and its impact on water quality. The Revised Universal Soil Loss Equation (RUSLE) model was used to compute soil lost from the catchment as a result of soil erosion. The model was used in conjunction with GIS remotely sensed data and limited ground observations. The estimated annual soil loss in the catchment indicates soil loss ranging from 0 to 65 t ha yr-1. Bathymetric survey at Chimhanda Dam showed that the capacity of the dam had reduced by 39 % as a result of sedimentation and the annual sediment deposition into Chimhanda Dam was estimated to be 330 t with a specific yield of 226 t km-2 yr-1. Relationship between selected water quality parameters, TSS, DO, NO3, pH, TDS, turbidity and sediment yield for selected water sampling points and Chimhanda Dam was analyzed. It was established that there is a strong positive relationship between the sediment yield and the water quality parameters. Sediment yield showed high positive correlation with turbidity (0.63) and TDS (0.64). Water quality data from Chimhanda treatment plant water works revealed that the quality of water is deteriorating as a result of increase in sediment accumulation in the dam. The study concluded that sedimentation can affect the water quality of water sources.

Oscillatory erosion and transport flume with superimposed unidirectional flow

DOEpatents

Jepsen, Richard A.; Roberts, Jesse D.

2004-01-20

A method and apparatus for measuring erosion rates of sediments and at high shear stresses due to complex wave action with, or without, a superimposed unidirectional current. Water is forced in a channel past an exposed sediment core sample, which erodes sediments when a critical shear stress has been exceeded. The height of the core sample is adjusted during testing so that the sediment surface remains level with the bottom of the channel as the sediments erode. Complex wave action is simulated by driving tandom piston/cylinder mechanisms with computer-controlled stepper motors. Unidirectional flow, forced by a head difference between two open tanks attached to each end of the channel, may be superimposed on to the complex wave action. Sediment traps may be used to collect bedload sediments. The total erosion rate equals the change in height of the sediment core sample divided by a fixed period of time.

Scaling oxygen microprofiles at the sediment interface of deep stratified waters

NASA Astrophysics Data System (ADS)

Schwefel, Robert; Hondzo, Miki; Wüest, Alfred; Bouffard, Damien

2017-02-01

Dissolved oxygen microprofiles at the sediment-water interface of Lake Geneva were measured concurrently with velocities 0.25 to 2 m above the sediment. The measurements and scaling analyses indicate dissolved oxygen fluctuations and turbulent fluxes in exceedance of molecular diffusion in the proximity of the sediment-water interface. The measurements allowed the parameterization of the turbulent diffusion as a function of the dimensionless height above the sediment and the turbulence above the sediment-water interface. Turbulent diffusion depended strongly on the friction velocity and differed from formulations reported in the literature that are based on concepts of turbulent and developed wall-bounded flows. The dissolved oxygen microprofiles and proposed parameterization of turbulent diffusion enable a foundation for the similarity scaling of oxygen microprofiles in proximity to the sediment. The proposed scaling allows the estimation of diffusive boundary layer thickness, oxygen flux, and oxygen microprofile distribution in the near-sediment boundary layer.

A field survey-Staroe lake suffering from atmospheric deposition in the region north of the Arctic Circle.

PubMed

Kikuchi, Ryunosuke; Gorbacheva, Tamara T

2009-06-01

The Arctic holds large stores of minerals, and extracted materials are provided to the world's economy; in this sense, the Arctic issue associated with mining is not local but global. In a part of the Arctic region (the Kola Peninsula, 66-70 degrees N and 28-41 degrees E), metal levels are generally elevated in the lake sediment. There is a question as to what results in elevated metal levels-a natural process (naturally abundant minerals) or an anthropogenic process (mining and metallurgy). In terms of solving this question, Staroe lake located on the Kola Peninsula was researched as a case study. The following parameters were determined in relation with Staroe lake: (1) the current quality of the lake's water-each 1,000-ml sample was collected at a surface point and a deep point (near the bottom layer), and the collected samples were directly analyzed after filtration; (2) atmospheric bulk deposition-bulk deposition was collected using a set of three rainwater samplers near the lake. In addition, bulk deposition was collected in a background site (250 km to the southwest of the smelter complex) as a reference; and (3) sediment profile (plus principal component analysis)-lake-bottom sediment was collected by an open-gravimetric column sampler equipped with an automatic diaphragm. After collection, the sample columns were cut at a 1-cm interval for analysis. Eigenvalues and variances by factor were calculated from the correlation coefficients. The obtained data show that (1) naturally poor elements (Cu, Ni, Si, and SO(4) (2-)) dominantly influence the lake's water quality; (2) they are transported from the anthropogenic sources to the study lake through the atmospheric pathway; (3) mainly the contents of Cu, Ni, Sr, and Ca have influenced the sediment quality since the 1950s, corresponding to the industrial movement; and (4) Cu, Ni, and Sr originate from an anthropogenic source (smelter), and Ca originates from both natural and anthropogenic sources. As compared with the Russian standard (San Pin 2.1.980-00), the contents of NO(3) (-) (50.3 +/- 0.1 mg l(-1)) and particulates (2.3 +/- 0.2 mg l(-1)) exceeded the standard levels (0.7 mg l(-1) NO(3) (-) and 45 mg l(-1) particulates); Staroe lake may be slightly contaminated. However, the contamination factor (comparison with the background data) implies that Staroe lake is considerably contaminated. There is a strong possibility that fine overburden detritus (<0.1 mm diameter) may be transported from an open pit to the study lake by natural forces such as wind. Although it is difficult to suppose that one factor dominantly affects the sediment quality, it follows from a factor analysis that factors 1 and 2 account for about 70% of the total variance: Factor 1 is the most dominant, and factor 2 is the second most dominant in the variability of sediment quality. It is considered that Cu, Sr, and Ni in factor 1 originate from anthropogenic sources because they are poor in sediment rocks. The field survey conducted in Staroe lake can give the following answers to the key objectives: (1) The present water quality is affected by Cu, Ni, Si, and SO(4) (2-) in light of the contamination factor, and these elements originate from anthropogenic sources (the smelter and the open pit) and are transported to the lake through the atmospheric pathway; (2) the sediment profile and statistic analysis show that the lake quality has been influenced by deposition of metals since the 1950s; and (3) Cu, Ni, Sr, and Ca have influenced the sediment quality in light of the most dominant factor-Cu, Ni, and Sr originate from an anthropogenic source, whereas Ca comes from both natural and anthropogenic sources. The presented lake survey shows that the dispersion of human-related pollutants via the atmospheric pathway takes place in the Arctic region. If the current pollution continues without countermeasures, the high-latitude environment may lose its original characteristics; hence, this subject is important when considering how to implement a wide range of environmental protection measures in the Arctic.

Occurrence of selected contaminants in water, fish tissue, and streambed sediments in central Nebraska, 1992-95

USGS Publications Warehouse

Frenzel, Steven A.

1996-01-01

Surface and ground water in Nebraska may contain contaminants resulting from human activities. For purposes of this publication, a contaminant is any element or compound whose presence may affect the water's suitability for certain uses. For example, herbicide concentrations may exceeed the U.S. Environmental Protection Agency's (USEPA) Health Advisory Levels (HAL) for drinking water or trace-element concentrations may exceed guidelines for the protection of aquatic life. In general, the contaminats discussed in this report enter the aquatic system through nonpoint-source runoff from agricultural lands that dominate the Nebraska landscape. However,because this assessment was conducted as part of a larger, national program, a screening for contaminants with non-agricultural origins was included.The measurement of water quality involves a variety of steps, each contributing unique information while also aggregating to an overall assessment. One aspect of water-quality assesment is to describe the occurrence and distribution of contaminants. Some contaminants may be hundreds or thousands of times more concentrated in the tissues of aquatic organisms or in fine sediments than they are in the water. As a result, fish tissue and streambed sediments are well suited for the detection of certain contaminants. For example, pesticides used in the United States prior to the early 1970's, such as DDT, may have degraded into more stable but still toxic compounds that are highly concentrated in fish tissues. Conversely, other contaminants are not concentrated in sediments or tissues but are readily detected in water samples. Organonitrogen herbicides (such as atrazine), the most commonly used herbicides in Nebraska, are examples of water-soluble contaminants.Several sampling strategies were used to address specific questions. Some sites were sampled repeatedly through time and during all hydrologic conditions, whereas others were sampled only once to determine presence of contaminants. Because a strong relation between concentration and streamflow often exists for contaminants originating from nonpoint sources, streams typically were sampled near gaging stations that monitor streamflow.

Monitoring of green infrastructure at The Grove in Bloomington, Illinois

USGS Publications Warehouse

Roseboom, Donald P.; Straub, Timothy D.

2013-01-01

The City of Bloomington, Illinois, restored Kickapoo Creek to a more natural state by incorporating green infrastructure—specifically flood-plain reconnection, riparian wetlands, meanders, and rock riffles—at a 90-acre park within The Grove residential development. A team of State and Federal agencies and contractors are collecting data to monitor the effectiveness of this stream restoration in improving water quality and stream habitat. The U.S. Geological Survey (USGS) is collecting and analyzing water resources data; Illinois Department of Natural Resources (IDNR) is collecting fish population data; Illinois Environmental Protection Agency (IEPA) is collecting macroinvertebrates and riparian habitat data; and Prairie Engineers of Illinois, P.C., is collecting vegetation data. The data collection includes conditions upstream, within, and downstream of the development and restoration. The 480-acre development was designed by the Farnsworth Group to reduce peak stormwater flows by capturing runoff in the reconnected flood plains with shallow wetland basins. Also, an undersized park bridge was built at the downstream end of the park to pass the 20-percent annual exceedance probability flows (historically referred to as the 5-year flood), but detain larger floods. This design also helps limit sediment deposition from sediments transported in the drainage ditches in the upper 9,000 acres of agricultural row crops. Maintaining sediment-transport capacity minimizes sediment deposition in the restored stream segments, which reduces the loss of riparian and wetland-plant communities and instream habitat. Two additional goals of the restoration were to reduce nutrient loads and maintain water quality to support a diverse community of biotic species. Overall, 2 miles of previously managed agricultural-drainage ditches of Kickapoo Creek were restored, and the park landscape maximizes the enhancement of native riparian, wetland, and aquatic species for the park’s trail system. The purpose of this fact sheet is to give an overview and examples of the data being collected.

Organic Matter Remineralization Predominates Phosphorus Cycling in the Mid-Bay Sediments in the Chesapeake Bay

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sunendra, Joshi R.; Kukkadapu, Ravi K.; Burdige, David J.

2015-05-19

The Chesapeake Bay, the largest and most productive estuary in the US, suffers from varying degrees of water quality issues fueled by both point and non–point source nutrient sources. Restoration of the bay is complicated by the multitude of nutrient sources, their variable inputs and hydrological conditions, and complex interacting factors including climate forcing. These complexities not only restrict formulation of effective restoration plans but also open up debates on accountability issues with nutrient loading. A detailed understanding of sediment phosphorus (P) dynamics enables one to identify the exchange of dissolved constituents across the sediment- water interface and aid tomore » better constrain mechanisms and processes controlling the coupling between the sediments and the overlying waters. Here we used phosphate oxygen isotope ratios (δ18Op) in concert with sediment chemistry, XRD, and Mössbauer spectroscopy on the sediment retrieved from an organic rich, sulfidic site in the meso-haline portion of the mid-bay to identify sources and pathway of sedimentary P cycling and to infer potential feedback effect on bottom water hypoxia and surface water eutrophication. Isotope data indicate that the regeneration of inorganic P from organic matter degradation (remineralization) is the predominant, if not sole, pathway for authigenic P precipitation in the mid-bay sediments. We interpret that the excess inorganic P generated by remineralization should have overwhelmed any bottom-water and/or pore-water P derived from other sources or biogeochemical processes and exceeded saturation with respect to authigenic P precipitation. It is the first research that identifies the predominance of remineralization pathway against remobilization (coupled Fe-P cycling) pathway in the Chesapeake Bay. Therefore, these results are expected to have significant implications for the current understanding of P cycling and benthic-pelagic coupling in the bay, particularly on the source and pathway of P that sustains hypoxia and supports phytoplankton growth in the surface water.« less

Bioavailability of heavy metals in water and sediments from a typical Mediterranean Bay (Málaga Bay, Region of Andalucía, Southern Spain).

PubMed

Alonso Castillo, M L; Sánchez Trujillo, I; Vereda Alonso, E; García de Torres, A; Cano Pavón, J M

2013-11-15

Concentrations of heavy metals were measured in sediment and water from Málaga Bay (South Spain). In the later twentieth century, cities such as Málaga, have suffered the impact of mass summer tourism. The ancient industrial activities, and the actual urbanization and coastal development, recreation and tourism, wastewaters treatment facilities, have been sources of marine pollution. In sediments, Ni was the most disturbing metal because Ni concentrations exceeded the effects range low (ERL), concentration at which toxicity could start to be observed in 85% of the samples analyzed. The metal bioavailability decreased in the order: Cd>Ni>Pb>Cu>Cr. In the sea water samples, Cd and Pb were the most disturbing metals because they exceeded the continuous criteria concentration (CCC) of US EPA in a 22.5% and 10.0% of the samples, respectively. Statistical analyses (ANOVA, PCA, CA) were performed. Copyright © 2013 Elsevier Ltd. All rights reserved.

Use of Clostridium perfringens as a fecal indicator to detect intertidal disposal at backcountry marine campsites in Prince William Sound, Alaska

Treesearch

Gino Graziano; Paul Twardock; Rusty Myers; Roman Dial; David Scheel

2007-01-01

Human waste disposal is a health concern in many backcountry areas. This study measured Clostridium perfringens in beach sediments of Prince William Sound, Alaska, to detect fecal contamination resulting from intertidal disposal. Analysis involved holding times that exceeded eight hours. In repeatedly sampled stored sediments, C. perfringens...

20th-century glacial-marine sedimentation in Vitus Lake, Bering Glacier, Alaska, U.S.A.

USGS Publications Warehouse

Molnia, B.F.; Post, A.; Carlson, P.R.

1996-01-01

Vitus Lake, the ice-marginal basin at the southeastern edge of Bering Glacier, Alaska, U.S.A., is a site of modern, rapid, glacial-marine sedimentation. Rather than being a fresh-water lake, Vitus Lake is a tidally influenced, marine to brackish embayment connected to the Pacific Ocean by an inlet, the Seal River. Vitus Lake consists of five deep bedrock basins, separated by interbasinal highs. Glacial erosion has cut these basins as much as 250 m below sea level. High-resolution seismic reflection surveys conducted in 1991 and 1993 of four of Vitus Lake's basins reveal a complex, variable three-component acoustic stratigraphy. Although not fully sampled, the stratigraphy is inferred to be primarily glacial-marine units of (1) basal contorted and deformed glacial-marine and glacial sediments deposited by basal ice-contact processes and submarine mass-wasting; (2) acoustically well-stratified glacial-marine sediment, which unconformably overlies the basal unit and which grades upward into (3) acoustically transparent or nearly transparent glacial-marine sediment. Maximum thicknesses of conformable glacial-marine sediment exceed 100 m. All of the acoustically transparent and stratified deposits in Vitus Lake are modern in age, having accumulated between 1967 and 1993. The basins where these three-part sequences of "present-day" glacial-marine sediment are accumulating are themselves cut into older sequences of stratified glacial and glacial-marine deposits. These older units outcrop on the islands in Vitus Lake. In 1967, as the result of a major surge, glacier ice completely filled all five basins. Subsequent terminus retreat, which continued through August 1993, exposed these basins, providing new locations for glacial-marine sediment accumulation. A correlation of sediment thicknesses measured from seismic profiles at specific locations within the basins, with the year that each location became ice-free, shows that the sediment accumulation at some locations exceeds 10 m year-1.

Storm-event-transport of urban-use pesticides to streams likely impairs invertebrate assemblages.

PubMed

Carpenter, Kurt D; Kuivila, Kathryn M; Hladik, Michelle L; Haluska, Tana; Cole, Michael B

2016-06-01

Insecticide use in urban areas results in the detection of these compounds in streams following stormwater runoff at concentrations likely to cause toxicity for stream invertebrates. In this 2013 study, stormwater runoff and streambed sediments were analyzed for 91 pesticides dissolved in water and 118 pesticides on sediment. Detections included 33 pesticides, including insecticides, fungicides, herbicides, degradates, and a synergist. Patterns in pesticide occurrence reveal transport of dissolved and sediment-bound pesticides, including pyrethroids, from upland areas through stormwater outfalls to receiving streams. Nearly all streams contained at least one insecticide at levels exceeding an aquatic-life benchmark, most often for bifenthrin and (or) fipronil. Multiple U.S. EPA benchmark or criterion exceedances occurred in 40 % of urban streams sampled. Bed sediment concentrations of bifenthrin were highly correlated (p < 0.001) with benthic invertebrate assemblages. Non-insects and tolerant invertebrates such as amphipods, flatworms, nematodes, and oligochaetes dominated streams with relatively high concentrations of bifenthrin in bed sediments, whereas insects, sensitive invertebrates, and mayflies were much more abundant at sites with no or low bifenthrin concentrations. The abundance of sensitive invertebrates, % EPT, and select mayfly taxa were strongly negatively correlated with organic-carbon normalized bifenthrin concentrations in streambed sediments. Our findings from western Clackamas County, Oregon (USA), expand upon previous research demonstrating the transport of pesticides from urban landscapes and linking impaired benthic invertebrate assemblages in urban streams with exposure to pyrethroid insecticides.

Storm-event-transport of urban-use pesticides to streams likely impairs invertebrate assemblages

USGS Publications Warehouse

Carpenter, Kurt; Kuivila, Kathryn; Hladik, Michelle; Haluska, Tana L.; Michael B. Cole,

2016-01-01

Insecticide use in urban areas results in the detection of these compounds in streams following stormwater runoff at concentrations likely to cause toxicity for stream invertebrates. In this 2013 study, stormwater runoff and streambed sediments were analyzed for 91 pesticides dissolved in water and 118 pesticides on sediment. Detections included 33 pesticides, including insecticides, fungicides, herbicides, degradates, and a synergist. Patterns in pesticide occurrence reveal transport of dissolved and sediment-bound pesticides, including pyrethroids, from upland areas through stormwater outfalls to receiving streams. Nearly all streams contained at least one insecticide at levels exceeding an aquatic-life benchmark, most often for bifenthrin and (or) fipronil. Multiple U.S. EPA benchmark or criterion exceedances occurred in 40 % of urban streams sampled. Bed sediment concentrations of bifenthrin were highly correlated (p < 0.001) with benthic invertebrate assemblages. Non-insects and tolerant invertebrates such as amphipods, flatworms, nematodes, and oligochaetes dominated streams with relatively high concentrations of bifenthrin in bed sediments, whereas insects, sensitive invertebrates, and mayflies were much more abundant at sites with no or low bifenthrin concentrations. The abundance of sensitive invertebrates, % EPT, and select mayfly taxa were strongly negatively correlated with organic-carbon normalized bifenthrin concentrations in streambed sediments. Our findings from western Clackamas County, Oregon (USA), expand upon previous research demonstrating the transport of pesticides from urban landscapes and linking impaired benthic invertebrate assemblages in urban streams with exposure to pyrethroid insecticides.

Numerical Simulation of Sediment-Associated Water Quality Processes for a Mississippi Delta Lake

USDA-ARS?s Scientific Manuscript database

Three major sediment-associated processes were presented to describe the effects of sediment on lake water quality processes: the effect of suspended sediment on the light intensity for the growth of phytoplankton (PHYTO), the adsorption–desorption of nutrients by sediment, and the release of nutrie...

Fractionation and ecological risk of metals in urban river sediments in Zhongshan City, Pearl River Delta.

PubMed

Cai, Jiannan; Cao, Yingzi; Tan, Haijian; Wang, Yanman; Luo, Jiaqi

2011-09-01

Surface sediments collected from nine urban rivers located in Zhongshan City, Pearl River Delta, were analyzed for total concentration of metals with digestion and chemical fractionation adopting the modified European Community Bureau of Reference (BCR) sequential extraction procedure. The results showed that concentration and fractionation of metals varied significantly among the rivers. The total concentration of eight metals in most rivers did not exceed the China Environmental Quality Standard for Soil, Grade III. The potential ecological risk of metals to rivers were related to the land use patterns, in the order of manufacturing areas > residential areas > agriculture areas. The concentration of Pb in the reducible fraction was relatively high (60.0-84.3%). The dominant proportions of Cd, Zn and Cu were primary in the non-residual fraction (67.0%, 71.8% and 81.4% on average respectively), while the percentages of the residual fractions of Cr and Ni varied over a wide range (43-85% and 24-71% respectively). The approaches of the Håkanson ecological risk index and Secondary Phase Enrichment Factor were applied for ecological risk assessment and metal enrichment calculation. The results indicated Hg and Cd had posed high potential ecological risk to urban rivers in this region. Meanwhile, there was widespread pollution and high enrichment of Cu in river sediments in this region. Multiple regression analysis showed that five water quality parameters (pH, DO, COD(Mn), NH(4)(+)-N, TP) had little influence on the distribution of metal fractionation. This result revealed that the ecological risk of metals was not eliminated along with the improvement in water quality. Correlation studies showed that among the metals, Group A (Cd, As, Pb, Zn Hg, r = 0.730-0.924) and Group B (Cr, Cu, Ni, r = 0.815-0.948) were obtained, and the metal contaminations were from industrial activities rather than residential.

Ground Motion Relations While TBM Drilling in Unconsolidated Sediments

NASA Astrophysics Data System (ADS)

Grund, Michael; Ritter, Joachim R. R.; Gehrig, Manuel

2016-05-01

The induced ground motions due to the tunnel boring machine (TBM), which has been used for the drilling of the urban metro tunnel in Karlsruhe (SW Germany), has been studied using the continuous recordings of seven seismological monitoring stations. The drilling has been undertaken in unconsolidated sediments of the Rhine River system, relatively close to the surface at 6-20 m depth and in the vicinity of many historic buildings. Compared to the reference values of DIN 4150-3 (1-80 Hz), no exceedance of the recommended peak ground velocity (PGV) limits (3-5 mm/s) was observed at the single recording site locations on building basements during the observation period between October 2014 and February 2015. Detailed analyses in the time and frequency domains helped with the detection of the sources of several specific shaking signals in the recorded time series and with the comparison of the aforementioned TBM-induced signals. The amplitude analysis allowed for the determination of a PGV attenuation relation (quality factor Q ~ 30-50) and the comparison of the TBM-induced ground motion with other artificially induced and natural ground motions of similar amplitudes.

Pollutants in Plastics within the North Pacific Subtropical Gyre.

PubMed

Chen, Qiqing; Reisser, Julia; Cunsolo, Serena; Kwadijk, Christiaan; Kotterman, Michiel; Proietti, Maira; Slat, Boyan; Ferrari, Francesco F; Schwarz, Anna; Levivier, Aurore; Yin, Daqiang; Hollert, Henner; Koelmans, Albert A

2018-01-16

Here we report concentrations of pollutants in floating plastics from the North Pacific accumulation zone (NPAC). We compared chemical concentrations in plastics of different types and sizes, assessed ocean plastic potential risks using sediment quality criteria, and discussed the implications of our findings for bioaccumulation. Our results suggest that at least a fraction of the NPAC plastics is not in equilibrium with the surrounding seawater. For instance, "hard plastic" samples had significantly higher PBDE concentrations than "nets and ropes" samples, and 29% of them had PBDE composition similar to a widely used flame-retardant mixture. Our findings indicate that NPAC plastics may pose a chemical risk to organisms as 84% of the samples had at least one chemical exceeding sediment threshold effect levels. Furthermore, our surface trawls collected more plastic than biomass (180 times on average), indicating that some NPAC organisms feeding upon floating particles may have plastic as a major component of their diets. If gradients for pollutant transfer from NPAC plastic to predators exist (as indicated by our fugacity ratio calculations), plastics may play a role in transferring chemicals to certain marine organisms.

Effects of metal mining and milling on boundary waters of Yellowstone National Park, USA

USGS Publications Warehouse

Nimmo, D.R.; Willox, M.J.; Lafrancois, T.D.; Chapman, P.L.; Brinkman, S.F.; Greene, J.C.

1998-01-01

Aquatic resources in Soda Butte Creek within Yellowstone National Park, USA, continue to be threatened by heavy metals from historical mining and milling activities that occurred upstream of the park's boundary. This includes the residue of gold, silver, and copper ore mining and processing in the early 1900s near Cooke City, Montana, just downstream of the creek's headwaters. Toxicity tests, using surrogate test species, and analyses of metals in water, sediments, and macroinvertebrate tissue were conducted from 1993 to 1995. Chronic toxicity to test species was greater in the spring than the fall and metal concentrations were elevated in the spring with copper exceeding water quality criteria in 1995. Tests with amphipods using pore water and whole sediment from the creek and copper concentrations in the tissue of macroinvertebrates and fish also suggest that copper is the metal of concern in the watershed. In order to understand current conditions in Soda Butte Creek, heavy metals, especially copper, must be considered important factors in the aquatic and riparian ecosystems within and along the creek extending into Yellowstone National Park.

Remobilization of polycyclic aromatic hydrocarbons and organic matter in seawater during sediment resuspension experiments from a polluted coastal environment: Insights from Toulon Bay (France).

PubMed

Guigue, Catherine; Tedetti, Marc; Dang, Duc Huy; Mullot, Jean-Ulrich; Garnier, Cédric; Goutx, Madeleine

2017-10-01

Polycyclic aromatic hydrocarbons (PAHs) and organic matter contents were measured in seawater during resuspension experiments using sediments collected from Toulon Bay (Northwestern Mediterranean Sea, France). The studied sediments were very highly contaminated in PAHs, especially in 4-ring compounds emitted from combustion processes. The sediments used for resuspension experiments were collected at 0-2 cm (diagenetically new organic matter, OM) and 30-32 cm depths (diagenetically transformed OM). They were both mostly composed of fine particles (<63 μm), enriched in organic carbon (8.2 and 6.3%, respectively) and in PAHs (concentration of Σ34 PAHs: 38.2 and 35.7 × 10 3  ng g -1 , respectively). The resuspension of these sediments led to an increase in concentrations of dissolved Σ34 PAHs, dissolved organic carbon (DOC) and dissolved humic- and tryptophan-like fluorophores in seawater up to 10-, 1.3-, 4.4- and 5.7-fold, respectively. The remobilization in seawater was higher for 4-6 ring PAHs, especially benzo(g,h,i)perylene, whose concentration exceeded the threshold values of the European Water Framework Directive. This noted the potential harmful effects of sediment resuspension on marine biota. From these sediment resuspension experiments, we determined OC-normalized partition coefficients of PAHs between sediment and water (K oc ) and found that during such events, the transfer of PAHs from sediment particles to seawater was lower than that predicted from octanol-water partition coefficients (K ow ) (i.e., measured K oc  > K oc predicted from K ow ). The results confirmed the sequestration role of sedimentary OC quality and grain size on PAHs; the OM diagenetic state seemed to impact the partition process but in a relatively minor way. Furthermore, differences were observed between 2-4 ring and 5-6 ring PAHs, with the latter displaying a relatively higher mobility towards seawater. These differences may be explained by the distribution of these two PAH pools within different OM moieties, such as humic substances and black carbon. Copyright © 2017 Elsevier Ltd. All rights reserved.

Levels and mass burden of DDTs in sediments from fishing harbors: the importance of DDT-containing antifouling paint to the coastal environment of China.

PubMed

Lin, Tian; Hu, Zhaohui; Zhang, Gan; Li, Xiangdong; Xu, Weihai; Tang, Jianhui; Li, Jun

2009-11-01

DDT remains an important type of persistent organic pollutant (POP) in the environment of China. One of the current applications of DDT in China has been through antifouling paint for fishing ships as an active component. It has been estimated that approximately 5000 t of DDT was released into the Chinese coastal environment during the last two decades. Therefore, sediments in coastal fishing harbors of China may be the important sinks of DDT. In this study, DDT and its metabolites in 58 sediment samples from nine typical fishing harbors along the coastal line of China were characterized to assess their accumulation levels, sediment burdens, and potential ecological risks. The concentrations of DDTs ranged from 9 to 7350 ng/g dry weight, which were generally 1-2 orders of magnitude higher than those of the adjacent estuarine/marine sediments. The high concentrations of DDT coupled with the lower concentrations of HCH and TOC clearly indicated a strong local DDT input, i.e., DDT-containing antifouling paint, within the fishing harbors. A significant correlation between the total DDT concentrations and p,p'-DDT concentrations further confirmed the existence of fresh DDT input. The overall burden of DDTs within the upper 10 cm sediment layer in the fishing harbors of the Pearl River Delta, southern China, was estimated to be 1.0-5.7 t, which was several times higher than the DDT accumulation in the surface sediment of the Pearl River estuary. The concentrations of DDTs in the fishing harbor sediments significantly exceeded the sediment quality guidelines on the basis of adverse biological effects. The absence or low concentrations of p,p'-DDD in aquatic organisms and human may imply that either p,p'-DDD may be less bioaccumulated by fish and human, or is biotransformed to other metabolites. A national ban of DDT as an additive to antifouling paint was implemented in 2009 in China; however, the legacy high DDT burden in the coastal fishing harbors needs further monitoring and proper management.

Surface sediment quality relative to port activities: A contaminant-spectrum assessment.

PubMed

Yu, Shen; Hong, Bing; Ma, Jun; Chen, Yongshan; Xi, Xiuping; Gao, Jingbo; Hu, Xiuqin; Xu, Xiangrong; Sun, Yuxin

2017-10-15

Ports are facing increasing environmental concerns with their importance to the global economy. Numerous studies indicated sediment quality deterioration in ports; however, the deterioration is not discriminated for each port activity. This study investigated a spectrum of contaminants (metals and organic pollutants) in surface sediments at 20 sampling points in Port Ningbo, China, one of the top five world ports by volume. The spectrum of contaminants (metals and organic pollutants) was quantified following marine sediment quality guidelines of China and USA and surface sediment quality was assessed according to thresholds of the two guidelines. Coupling a categorical matrix of port activities with the matrix of sedimentary contaminants revealed that contaminants were highly associated with the port operations. Ship repair posed a severe chemical risk to sediment. Operations of crude oil and coal loadings were two top activities related to organic pollutants in sediments while port operations of ore and container loadings discharged metals. Among the 20 sampling points, Cu, Zn, Pb, and DDT and its metabolites were the priority contaminants influencing sediment quality. Overall, surface sediments in Port Ningbo had relatively low environmental risks but ship repair is an environmental concern that must be addressed. This study provides a practical approach for port activity-related quality assessment of surface sediments in ports that could be applicable in many world sites. Copyright © 2017 Elsevier B.V. All rights reserved.

Geology and geochemistry of gas-charged sediment on Kodiak Shelf, Alaska

USGS Publications Warehouse

Hampton, M.A.; Kvenvolden, K.A.

1981-01-01

Methane concentrations in some sediment cores from the Kodiak Shelf and adjacent continental slope increase with depth by three or four orders of magnitude and exceed the solubility in water at ambient conditions. Acoustic anomalies in seismic-reflection records imply that methane-rich sediment is widespread. Molecular composition of hydrocarbon gases and isotopic composition of methane indicate gas formation by shallow biogenic processes. Stratigraphic positions of acoustic anomalies in Quaternary glacial and posttransgressive sediments suggest that these units are likely sources of gas. A seep along the extension of a fault may be gas venting from a deeper thermogenic source. ?? 1981 A.M. Dowden, Inc.

DEVELOPING WATER QUALITY CRITERIA FOR SUSPENDED AND BEDDED SEDIMENTS

EPA Science Inventory

The U.S. EPA’s Framework for Developing Suspended and Bedded Sediments (SABS) Water Quality Criteria (SABS Framework) is a nationally-consistent process for developing ambient sediment quality criteria for surface waters. The SABS Framework accommodates natural variation among wa...

Development, evaluation, and application of sediment quality targets for assessing and managing contaminated sediments in Tampa Bay, Florida

USGS Publications Warehouse

MacDonald, D.D.; Carr, R.S.; Eckenrod, D.; Greening, H.; Grabe, S.; Ingersoll, C.G.; Janicki, S.; Janicki, T.; Lindskoog, R.A.; Long, E.R.; Pribble, R.; Sloane, G.; Smorong, D.E.

2004-01-01

Tampa Bay is a large, urban estuary that is located in west central Florida. Although water quality conditions represent an important concern in this estuary, information from numerous sources indicates that sediment contamination also has the potential to adversely affect aquatic organisms, aquatic-dependent wildlife, and human health. As such, protecting relatively uncontaminated areas of the bay from contamination and reducing the amount of toxic chemicals in contaminated sediments have been identified as high-priority sediment management objectives for Tampa Bay. To address concerns related to sediment contamination in the bay, an ecosystem-based framework for assessing and managing sediment quality conditions was developed that included identification of sediment quality issues and concerns, development of ecosystem goals and objectives, selection of ecosystem health indicators, establishment of metrics and targets for key indicators, and incorporation of key indicators, metrics, and targets into watershed management plans and decision-making processes. This paper describes the process that was used to select and evaluate numerical sediment quality targets (SQTs) for assessing and managing contaminated sediments. These SQTs included measures of sediment chemistry, whole-sediment and pore-water toxicity, and benthic invertebrate community structure. In addition, the paper describes how the SQTs were used to develop site-specific concentration-response models that describe how the frequency of adverse biological effects changes with increasing concentrations of chemicals of potential concern. Finally, a key application of the SQTs for defining sediment management areas is discussed.

Water quality in the St. Croix National Scenic Riverway, Wisconsin

DOE Office of Scientific and Technical Information (OSTI.GOV)

Graczyk, D.J.

1986-01-01

A water quality study of the St. Croix National Scenic Riverway, was conducted during the period 1975-83. Concentrations of most constituents analyzed, and constituent loads and yields were lower in the Scenic Riverway than in other Wisconsin streams. Water quality samples were collected at 10 stations throughout the study area and were compared to analyses of samples from selected National Stream Quality Accounting Network stations (NASWAN) and the Hydrologic Bench-Mark Network (HBMN) station in Wisconsin. The average suspended sediment (SS) concentration for 9 of the 10 stations in this study was 7.7 mg/L. The concentrations of major cations and anionsmore » at two of the stations were similar to concentrations at the HBMN station Popple River near Fence. Mean total phosphorus concentrations ranged from 0.02 to 0.08 mg/L at the study stations and from 0.03 to 0.16 mg/L at selected NASQAN stations. Concentrations of trace metals were below safe drinking water standards at all the study sites, except for iron and manganese which exceeded drinking water standards at some of the study sites. Pesticides were sampled at the St. Croix River at St. Croix Falls and above and below cranberry bogs that drain into the Namekagon River. Average annual loads of SS, total phosphorus, total nitrogen, and dissolved solids were calculated by a flow duration curve method. Suspended sediment yields ranged from 1.9 to 13.3 tons/sq mi. The average SS yield for Wisconsin is 80 tons/sq mi. total phosphorus and other constituents exhibited the same trend. 26 refs., 10 figs., 12 tabs.« less

Organic pollutant levels in an agricultural watershed: the importance of analyzing multiple matrices for assessing stream water pollution.

PubMed

Gonzalez, Mariana; Miglioranza, Karina S B; Grondona, Sebastían I; Silva Barni, Maria Florencia; Martinez, Daniel E; Peña, Aránzazu

2013-04-01

This study is aimed at analyzing the occurrence and transport of organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) in the Quequén Grande river basin, as representative of a catchment under diffuse pollution sources. Pollutant levels in soils, river bottom sediments (RBS), streamwater (Sw), suspended particle materials (SPMs), macrophytes and muscle of silverside were determined by GC-ECD. Soil K(d) values for the current-used insecticides, endosulfans and cypermethrin, were established. Total levels (ng g(-1) dry weight) in soil ranged between 0.07–0.9 for OCPs, 0.03–0.37 for PCBs and 0.01–0.05 for PBDEs. Endosulfan insecticide (α- + b- + sulfate metabolite) represented up to 72.5% of OCPs. The low soil retention for α-endosulfan (K(d): 77) and endosulfan sulfate (K(d): 100) allows their transport to Sw, SPM and RBS. Levels of endosulfan in Sw in some cases exceeded the value postulated by international guidelines for aquatic biota protection (3 ng L(-1)). PCB and PBDE pollution was related to harbour, dumping sites and pile tire burning. Tri and hexa PCB congeners predominated in all matrices and exceeded the quality guideline value of 0.04 ng L(-1) in Sw. Considering levels in silverside muscle, none of the oral reference doses were exceeded, however, PCBs accounted for 18.6% of the total daily allowed ingest for a 70 kg individual. Although the levels of PCBs and OCPs in soil and RBS were low and did not go beyond quality guidelines, these compounds could still represent a risk to aquatic biota and humanbeings, and thus actions towards preventing this situation should be undertaken.

Assessment of metal and nutrient concentrations in river water and sediment collected from the cities in the Pearl River Delta, South China.

PubMed

Cheung, K C; Poon, B H T; Lan, C Y; Wong, M H

2003-09-01

The effects of anthropogenic activities, industrialization and urbanization on the accumulation of heavy metals and nutrients in sediments and water of rivers in the Pearl River Delta region were examined. Most sediments were seriously contaminated with Cd, Pb, and Zn in accordance with the classification by Hong Kong Environmental Protection Department. Total phosphorus (P) and nitrogen (N) concentrations in sediments ranged from 0.02% to 0.12% and 0.06% to 0.64%, respectively. High carbon (C), N, P and sulphur (S) levels at Yuen Long Creek were related to the discharge of industrial effluents along the river. The enrichment of P and ammoniacal-nitrogen (NH4+-N) in water were obvious. For most sites, the P concentration exceeded 0.1 mg/l, which is the recommended concentration in flowing water to encourage excessive growth of aquatic plants. Nine out of the 16 sites studied had NH4+-N concentration over 2 mg/l. The rivers in the south of Deep Bay (Hong Kong) had high nutrient exports compared with the rivers in the east region and western oceanic water. The concentrations of nitrate-nitrogen NO3--N in surface water were under the maximum contaminant level in public drinking water supplies (10 mg/l) except for one site. Although the concentrations of heavy metals in overlying water were low, their accumulations were significant. High contents of nickel (Ni) and zinc (Zn) in water were found at certain locations, suggesting the occurrence of some local contamination. These preliminary results indicated that river and sediment transported pollutants is likely one of the factors for the water quality degradation of Deep Bay water.

[Distribution patterns and pollution assessments of heavy metals in the Spartina alterniflora salt-marsh wetland of Rudong, Jiangsu province].

PubMed

Zhang, Long-Hui; Du, Yong-Fen; Wang, Dan-Dan; Gao, Shu; Gao, Wen-Hua

2014-06-01

To understand the ecological impact of Spartina alterniflora on the coastal wetland environment, field survey was carried out in July, 2010, over the intertidal areas of Rudong coast, Jiangsu province; sediment samples were collected from a series of stations with different conditions of vegetation cover and S. alterniflora growth. The contents of eight heavy metals, together with sediment composition and total organic carbon were analyzed to reveal the distribution patterns of the heavy metals. Environmental quality status was evaluated using both the index of geoaccumulation (I(geo)) and the index of the Håkanson ecological risk. The analytical results showed that the average contents of Pb, Cd, As, Hg, Cr, Cu, Ni and Zn were below the standard for the Category I sediment quality, among which Cd, Hg, Ni and Zn exceeded the sediment background value of the region. On the whole, the contents of eight heavy metals in vegetation areas were higher than those associated with the adjacent bare flat areas. These data sets indicate a non-polluted condition in term of I(geo) estimation; however, a critical state of low to moderate degrees of pollution and a low level of risk were deduced according to the index of the Håkanson potential ecological risk. Both indices suggested that the pollution level of Hg and Cd were the highest among the eight metals measured. Along the transection from seaward to landward, the contents of As, Cu and Hg, their indices of I(geo) and Håkanson ecological risk all showed an increasing tread, in accordance with the condition of vegetation cover. Along the coastline with S. alterniflora being distributed in patchiness, all metal contents and their ecological risk level values for the marshes were higher than those for the unvegetated sediments nearby; moreover, except for Hg, other seven metals exhibited relatively low values than those in the shore-normal section with a better S. alterniflora growth. These findings indicate that S. alterniflora is one of important factors to enrich the heavy metal in tidal flat sediment. Thus, ecological risk of the heavy metal is reduced or blocked, due to the filtering effect of salt-marsh, which prevents metals from entering the open sea directly. The distribution of heavy metal is influenced by a combination of colonization time of vegetation, chemical form of metals and their origins.

Integrated Assessment of Artisanal and Small-Scale Gold Mining in Ghana—Part 2: Natural Sciences Review

PubMed Central

Rajaee, Mozhgon; Obiri, Samuel; Green, Allyson; Long, Rachel; Cobbina, Samuel J.; Nartey, Vincent; Buck, David; Antwi, Edward; Basu, Niladri

2015-01-01

This paper is one of three synthesis documents produced via an integrated assessment (IA) that aims to increase understanding of artisanal and small-scale gold mining (ASGM) in Ghana. Given the complexities surrounding ASGM, an integrated assessment (IA) framework was utilized to analyze socio-economic, health, and environmental data, and co-develop evidence-based responses with stakeholders. This paper focuses on the causes, status, trends, and consequences of ecological issues related to ASGM activity in Ghana. It reviews dozens of studies and thousands of samples to document evidence of heavy metals contamination in ecological media across Ghana. Soil and water mercury concentrations were generally lower than guideline values, but sediment mercury concentrations surpassed guideline values in 64% of samples. Arsenic, cadmium, and lead exceeded guideline values in 67%, 17%, and 24% of water samples, respectively. Other water quality parameters near ASGM sites show impairment, with some samples exceeding guidelines for acidity, turbidity, and nitrates. Additional ASGM-related stressors on environmental quality and ecosystem services include deforestation, land degradation, biodiversity loss, legacy contamination, and potential linkages to climate change. Though more research is needed to further elucidate the long-term impacts of ASGM on the environment, the plausible consequences of ecological damages should guide policies and actions to address the unique challenges posed by ASGM. PMID:26264012

Effects of landuse and precipitation on pesticides and water quality in playa lakes of the southern high plains.

PubMed

Anderson, Todd A; Salice, Christopher J; Erickson, Richard A; McMurry, Scott T; Cox, Stephen B; Smith, Loren M

2013-06-01

The 25000 playa wetlands within the Southern High Plains (SHP) of the United States of America (USA) are the dominant hydrogeomorphic feature in the region, providing habitat for numerous plants and wildlife. The SHP are among the most intensively cultivated regions; there are concerns over the degradation and/or loss of playa wetland habitat. We examined water quality in playa wetlands surrounded by both grassland and agriculture and measured water concentrations of pesticides used on cotton (acephate, trifluralin, malathion, pendimethalin, tribufos, bifenthrin, λ-cyhalothrin, acetamiprid, and thiamethoxam), the dominant crop in the SHP. Pesticides used on cotton were detected in water samples collected from all playas. Precipitation events and the amount of cultivation were related to pesticide concentrations in sediment and water. Our results show that pesticide concentrations were related in some circumstances to time, precipitation, and tilled-index for some but not all pesticides. We further compared measured pesticide concentrations in playas to toxicity benchmarks used by the US EPA in pesticide ecological risk assessments to obtain some insight into the potential for ecological effects. For all pesticides in water, the maximum measured concentrations exceeded at least one toxicity benchmark, while median concentrations did not exceed any benchmarks. This analysis indicates that there is a potential for adverse effects of pesticides to aquatic organisms. Copyright © 2013 Elsevier Ltd. All rights reserved.

Suspended sediment and organic contaminants in the San Lorenzo River, California, water years 2009-2010

USGS Publications Warehouse

Draut, Amy E.; Conaway, Christopher H.; Echols, Kathy R.; Storlazzi, Curt D.; Ritchie, Andrew

2011-01-01

This report presents analyses of suspended sediment and organic contaminants measured during a two-year study of the San Lorenzo River, central California, which discharges into the Pacific Ocean within the Monterey Bay National Marine Sanctuary. Most suspended-sediment transport occurred during flooding caused by winter storms; 55 percent of the sediment load was transported by the river during a three-day flood in January 2010. Concentrations of polyaromatic hydrocarbons can exceed regulatory criteria during high-flow events in the San Lorenzo River. These results highlight the importance of episodic sediment and contaminant transport in steep, mountainous, coastal watersheds and emphasize the importance of understanding physical processes and quantifying chemical constituents in discharge from coastal watersheds on event-scale terms.

Occurrence and Trends of Selected Chemical Constituents in Bottom Sediment, Grand Lake O' the Cherokees, Northeast Oklahoma, 1940-2008

USGS Publications Warehouse

Juracek, Kyle E.; Becker, Mark F.

2009-01-01

After over 100 years of continuous activity, lead and zinc mining in the Tri-State Mining District (hereafter referred to as the TSMD) in parts of southeast Kansas, southwest Missouri, and northeast Oklahoma ended in the 1970s. The mining activity resulted in substantial historical and ongoing input of cadmium, lead, and zinc to the environment including Grand Lake O' the Cherokees (hereafter referred to as Grand Lake), a large reservoir in northeast Oklahoma. To help determine the extent and magnitude of contamination in Grand Lake, a one-year study was conducted by the U.S. Geological Survey in cooperation with the U.S. Fish and Wildlife Service. Bottom-sediment coring at five sites was used to investigate the occurrence of cadmium, lead, zinc, and other selected constituents in the bottom sediment of Grand Lake. Cadmium concentrations in the bottom sediment of Grand Lake ranged from 2.3 to 3.6 mg/kg (milligrams per kilogram) with a median of 3.5 mg/kg (5 samples). Compared to an estimated local background concentration of 0.6 mg/kg, the historical mining activity increased cadmium concentrations by about 280 to 500 percent. Lead concentrations ranged from 35 to 102 mg/kg with a median of 59 mg/kg (50 samples). Compared to an estimated local background concentration of 20 mg/kg, the historical mining activity increased lead concentrations by about 75 to 410 percent. The range in zinc concentrations was 380 to 986 mg/kg with a median of 765 mg/kg (50 samples). Compared to an estimated local background concentration of 100 mg/kg, the historical mining activity increased zinc concentrations by about 280 to 890 percent. With the exception of the most upstream coring site, the lead and zinc depositional profiles generally were similar in terms of the range in concentrations measured and the temporal pattern observed. Depositional profiles for lead and zinc indicated mid-core peaks followed by concentrations that decreased since about the 1980s. The depositional profiles reflect the complex interaction of several factors including historical mining and related activities, mine drainage, remediation, landscape stabilization, precipitation and associated runoff, and the erosion and transport of contaminated and clean sediments within the basin. Compared to sediment-quality guidelines, the Grand Lake samples had cadmium concentrations that were substantially less than the general probable-effects concentration (PEC) (4.98 mg/kg) and a TSMD-specific PEC (11.1 mg/kg). The PECs represent the concentration above which toxic biological effects are likely to occur. Likewise, all sediment samples had lead concentrations that were substantially less than the general PEC (128 mg/kg) and a TSMD-specific PEC (150 mg/kg). Zinc concentrations typically exceeded the general PEC (459 mg/kg), but were substantially less than a TSMD-specific PEC (2,083 mg/kg). Throughout the history of Grand Lake, lead and zinc concentrations in the deposited sediment did not approach or exceed the TSMD-specific PECs. As of 2008, legacy effects of mining still included the delivery of contaminated sediment to Grand Lake by the Spring and Neosho Rivers. The Neosho River, with its larger flows and less-contaminated sediment, likely dilutes the load of contaminated sediment delivered to Grand Lake by the Spring River. The information contained in this report provides a baseline of Grand Lake conditions with which to compare future conditions that may represent a response to changes in mining-related activity in the Grand Lake Basin.

Incorporating Contaminant Bioavailability into Sediment Quality Assessment Frameworks

EPA Science Inventory

The recently adopted sediment quality assessment framework for evaluating bay and estuarine sediments in the State of California incorporates bulk sediment chemistry as a key line of evidence(LOE) but does not address the bioavailability of measured contaminants. Thus, the chemis...

Removing Dams: Project-Level Policy and Scientific Research Needs (Invited)

NASA Astrophysics Data System (ADS)

Graber, B.

2010-12-01

More than 800 dams have been removed around the country, mostly “small” dams, under 25 feet in height. The total number of removals, however, is small relative to the number of deteriorating dams and the ecological impacts those structures continue to have on native riverine species and natural river function. The number of dam removal projects is increasing as aging dams continue to deteriorate and riverine species continue to decline. Practitioners and regulators need to find cost-effective project approaches that minimize short-term environmental impacts and maximize long-term benefits while keeping project costs manageable. Dam removals can be a regulatory challenge because they inherently have short-term impacts in order to achieve larger, self-sustaining, long-term benefits. These short-term impacts include sediment movement, construction access roads, and habitat conversion from lacustrine to riverine. Environmental regulations are designed to prevent degradation and have presented challenges for projects designed to benefit the environment. For example, a short-term release of sediment may exceed water quality standards for some period of time, but lead to a long-term beneficial project. Other regulatory challenges include permitting the loss of wetland area for increased native river function, or allowing the release of some level of contaminated sediment when the downstream sediment is similarly contaminated. Dam removal projects raise a range of engineering and scientific questions on effective implementation techniques such as appropriate sediment management approaches, construction equipment access approaches, invasive species management, channel/floodplain reconstruction, and active versus passive habitat rehabilitation. While practitioners have learned and refined implementation approaches over the last decade, more input is needed from researchers to help assess the effectiveness of those techniques, and to provide more effective techniques. Applied research is needed to provide management tools for practitioners on questions such as: How do we determine the quantity of sediment that is acceptable to release downstream without causing long-term harm to habitat? How can we estimate how much sediment rivers naturally carry in places where there are no sediment gauges? Will the release of coarse-grain sediment help build habitat structure downstream or will it smother habitat? What is the trajectory of habitat quality in an impoundment wetland and is it justifiable to use self-sustainability as an argument to allow a reduction in wetland area for native river habitat? Will having construction equipment working in the flowing river channel do less harm than dewatering a river channel for a longer period of time? American Rivers staff have collectively had an active involvement in more than one hundred dam removal projects. In this presentation, an American Rivers geomorphologist will pose the questions that need to be answered to reduce project-level policy challenges and allow the implementation of cost-effective dam removal projects.

Coastal change from a massive sediment input: Dam removal, Elwha River, Washington, USA

USGS Publications Warehouse

Warrick, Jonathan A.; Gelfenbaum, Guy R.; Stevens, Andrew; Miller, Ian M.; Kaminsky, George M.; Foley, Melissa M.

2015-01-01

The removal of two large dams on the Elwha River, Washington, provides an ideal opportunity to study coastal morphodynamics during increased sediment supply. The dam removal project exposed ~21 million cubic meters (~30 million tonnes) of sediment in the former reservoirs, and this sediment was allowed to erode by natural river processes. Elevated rates of sand and gravel sediment transport in the river occurred during dam removal. Most of the sediment was transported to the coast, and this renewed sediment supply resulted in hundreds of meters of seaward expansion of the river delta since 2011. Our most recent survey in January 2015 revealed that a cumulative ~3.5 million m3 of sediment deposition occurred at the delta since the beginning of the dam removal project, and that aggradation had exceeded 8 m near the river mouth. Some of the newly deposited sediment has been shaped by waves and currents into a series of subaerial berms that appear to move shoreward with time.

River pollution caused by natural stone industry

NASA Astrophysics Data System (ADS)

Oktriani, Ani; Darmajanti, Linda; Soesilo, Tri Edhi Budhi

2017-03-01

The natural stone industry is classified as small industry. Current wastewater treatment still causes pollution in the river. This thesis aims to analyze the performance of wastewater treatment in natural stones industry. The data was collected from water quality test (parameters: temperature, pH, DO, and TSS). The wastewater treatment performance was in a slightly higher position compared to the 2nd class quality standards of Government Regulation No. 82/2001. The parameter that exceeded quality standards was the concentration of TSS, which was up to 240.8 mg/l. The high concentration of TSS was affected by the absence of sludge management schedule, which resulted in non-optimal precipitation. Besides that, the design of sedimentation basin was still not adapted with wastewater debit. Referring to the results, this study suggests the government of Cirebon District to provide wastewater treatment development through the village staff. Furthermore, the government also needs to give strict punishment to business owner who does not treat waste correctly and does not have a business license. Moreover, the sale value of sludge as byproduct of wastewater treatment needs to be increased.

Sediment deposition and occurrence of selected nutrients, other chemical constituents, and diatoms in bottom sediment, Perry Lake, northeast Kansas, 1969-2001

USGS Publications Warehouse

Juracek, Kyle E.

2003-01-01

A combination of bathymetric surveying and bottom-sediment coring was used to investigate sediment deposition and the occurrence of selected nutrients (total nitrogen and total phosphorus), organic and total carbon, 26 metals and trace elements, 15 organochlorine compounds, 1 radionuclide, and diatoms in bottom sediment of Perry Lake, northeast Kansas. The total estimated volume and mass of bottom sediment deposited from 1969 through 2001 in the original conservation-pool area of the lake was 2,470 million cubic feet (56,700 acre-feet) and 97,200 million pounds (44,100 million kilograms), respectively. The estimated sediment volume occupied about 23 percent of the original conservation-pool, water-storage capacity of the lake. Mean annual net sediment deposition since 1969 was estimated to be 3,040 million pounds (1,379 million kilograms). Mean annual sediment yield from the Perry Lake Basin was estimated to be 2,740,000 pounds per square mile (4,798 kilograms per hectare). The estimated mean annual net loads of total nitrogen and total phosphorus deposited in the bottom sediment of Perry Lake were 7,610,000 pounds per year (3,450,000 kilograms per year) and 3,350,000 pounds per year (1,520,000 kilograms per year), respectively. The estimated mean annual yields of total nitrogen and total phosphorus from the Perry Lake Basin were 6,850 pounds per square mile per year (12.0 kilograms per hectare per year) and 3,020 pounds per square mile per year (5.29 kilograms per hectare per year), respectively. A statistically significant positive trend for total nitrogen deposition in the bottom sediment of Perry Lake was indicated. However, the trend may be due solely to analytical variance. No statistically significant trend for total phosphorus deposition was indicated. Overall, the transport and deposition of these constituents have been relatively uniform throughout the history of Perry Lake. On the basis of nonenforceable sediment-quality guidelines established by the U.S. Environmental Protection Agency, concentrations of arsenic, chromium, copper, and nickel in the bottom sediment of Perry Lake typically exceeded the threshold-effects levels, which represent the concentrations above which toxic biological effects occasionally occur. Most nickel concentrations also exceeded the probable-effects level, which represents the concentration above which toxic biological effects usually or frequently occur. Sediment concentrations of metals and trace elements were relatively uniform over time. Statistically significant positive depositional trends for arsenic and manganese and statistically significant negative depositional trends for beryllium, chromium, titanium, and vanadium were indicated. However, the trends may be due solely to analytical variance. Organochlorine compounds either were not detected or were detected at concentrations less than the threshold-effects levels. Evidence of a negative depositional trend for DDE (degradation product of DDT) was consistent with the history of DDT use. Other organochlorine compounds detected were DDD and dieldrin. Diatom occurrence in the bottom sediment of Perry Lake was dominated by species that are indicators of eutrophic (nutrient-rich) conditions. Thus, it was concluded that eutrophic conditions have existed during much of the history of Perry Lake. However, an increase in the relative percentage abundance of the oligotrophic (nutrient-poor) species, combined with the significant positive depositional trends for two oligotrophic species (Aulacoseira islandica and Cyclotella radiosa) and the significant negative depositional trend for one eutrophic species (Stephanodiscus niagarae), indicated that conditions in Perry Lake may have become less eutrophic in recent years. Notable changes in human activity within the basin included a substantial decrease in alfalfa production and a substantial increase in soybean production from 1965 to 2000. These and other changes in human activi

Rock-Bound Arsenic Influences Ground Water and Sediment Chemistry Throughout New England

USGS Publications Warehouse

Robinson, Gilpin R.; Ayotte, Joseph D.

2007-01-01

The information in this report was presented at the Northeastern Region Geological Society of America meeting held March 11-14, 2007, in Durham, New Hampshire. In the New England crystalline bedrock aquifer, concentrations of arsenic that exceed the drinking water standard of 10 ?g/L occur most frequently in ground water from wells sited in specific metamorphic and igneous rock units. Geochemical investigations indicate that these geologic units typically have moderately elevated whole-rock concentrations of arsenic compared to other rocks in the region. The distribution of ground water wells with As > 5 ?g/L has a strong spatial correlation with specific bedrock units where average whole-rock concentrations of arsenic exceed 1.1 mg/kg and where geologic and geochemical factors produce high pH ground water. Arsenic concentrations in stream sediments collected from small drainages reflect the regional distribution of this natural arsenic source and have a strong correlation with both rock chemistry and the distribution of bedrock units with elevated arsenic chemistry. The distribution of ground water wells with As > 5 ?g/L has a strong spatial correlation with the distribution of stream sediments where concentrations of arsenic exceed 6 mg/kg. Stream sediment chemistry also has a weak correlation with the distribution of agricultural lands where arsenical pesticides were used on apple, blueberry, and potato crops. Elevated arsenic concentrations in bedrock wells, however, do not correlate with agricultural areas where arsenical pesticides were used. These results indicate that both stream sediment chemistry and the solubility and mobility of arsenic in ground water in bedrock are influenced by host-rock arsenic concentrations. Stream sediment chemistry and the distribution of geologic units have been found to be useful parameters to predict the areas of greatest concern for elevated arsenic in ground water and to estimate the likely levels of human exposure to elevated arsenic in drinking water in New England. However, the extreme local variability of arsenic concentrations in ground water from these rock sources indicate that arsenic concentrations in ground water are affected by other factors in addition to arsenic concentrations in rock.

Water-quality, bed-sediment, and biological data (October 1992 through September 1993) and statistical summaries of water-quality data (March 1985 through September 1993) for streams in the upper Clark Fork basin, Montana

USGS Publications Warehouse

Lambing, John H.

1994-01-01

Water, bed sediment, and biota were sampled in streams from Butte to below Missoula as part of a program to characterize aquatic resources in the upper Clark Fork basin of western Montana. Water-quality data were obtained periodically at 16 stations during October 1992 through September 1993 (water year 1993); daily suspended-sediment data were obtained at six of these stations. Bed-sediment and biological data were obtained at 11 stations in August 1993. Sampling stations were located on the Clark Fork and major tributaries. The primary constituents analyzed were trace elements associated with mine tailings from historic mining and smelting activities. Water-quality data include concentra- tions of major ions, trace elements, and suspended sediment in samples collected periodically during water year 1993. A statistical summary of water- quality data is provided for the period of record at each station since 1985. Daily values of streamflow, suspended-sediment concentration, and suspended-sediment discharge are given for six stations. Bed-sediment data include trace- element concentrations in the fine and bulk fractions. Biological data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Quality-assurance data are reported for analytical results of water, bed sediment, and biota.

Pesticides and PCBs in sediments and fish from the Salton Sea, California, USA.

PubMed

Sapozhnikova, Yelena; Bawardi, Ola; Schlenk, Daniel

2004-05-01

The Salton Sea, the largest manmade lake in California, is officially designated by the State of California as an agricultural drainage reservoir. The purpose of this study was to determine organochlorine and organophosphorous pesticides, as well as polychlorinated biphenyl (PCB) concentrations in sediments and fish tissues in the Salton Sea and evaluate the relative ecological risk of these compounds. Sediment samples were taken during 2000-2001 and fish tissues (Tilapia mossambique, Cynoscion xanthulu) were collected in May 2001. All samples were analyzed for 12 chlorinated pesticides, 6 organophosphorus pesticides, and 55 polychlorinated biphenyl (PCB) congeners. SigmaDichlorodiphenyltrichloroethane (SigmaDDT) and total PCB concentrations observed in sediments ranged from 10 to 40 and 116 to 304 ng/g dry wt, respectively. DDT/DDD ratios in sediments and fish tissues of the northern Sea in 2001 indicated recent DDT exposure. Lindane, dieldrin, dichlorodiphenylethane (DDE) and total PCB concentrations detected in sediments exceeded probable effect levels established for freshwater ecosystems, and pp-DDE and total PCB concentrations were higher than effect range-median values developed for marine and estuarine sediments. In fish liver, concentrations of endrin and SigmaDDT exceeded threshold effect level established for invertebrates. SigmaDDT concentrations detected in fish tissues were higher than threshold concentrations for the protection of wildlife consumers of aquatic biota. DDE concentrations in fish muscles tissues were above the 50 ng/g concentration threshold for the protection of predatory birds. Dimethoate, diazinon, malathion, chlorpyrifos, disulfoton varied from < or = 0.15 to 9.5 ng/g dry wt in sediments and from < or = 0.1 to 80.3 ng/g wet wt in fish tissues. Disulfoton was found in relatively high concentrations (up to 80.3 ng/g) in all organs from Tilapia and Corvina. These results demonstrate continued contamination of specific organochlorine compounds in sediments and resident fish species of the Salton Sea.

Modelling environment contamination with heavy metals in flathead grey mullet Mugil cephalus and upper sediments from north African coasts of the Mediterranean Sea.

PubMed

Ouali, Naouel; Belabed, Bourhane-Eddine; Chenchouni, Haroun

2018-05-18

Heavy metals are a serious hazard for aquatic ecosystems and human health. They negatively affect aquatic life functioning through accumulation resulting physiological/growth disturbances in aquatic lifeforms. This survey focused on the assessment of heavy metal pollution in the Gulf of Annaba (northeastern Algeria), the largest and most diversified industrial hub in Africa, using a multi-compartment approach (water-sediment-biota). The study aims to characterize the spatiotemporal variation of trace metal (TM) contamination and its effects on the growth of the Flathead grey mullet (Mugil cephalus). It reviewed TM concentrations in upper sediments and organs of M. cephalus from various hydrosystems worldwide. Five sites distributed along the Gulf were sampled to determine water physicochemical parameters as well as the contamination of surficial sediments and muscles of M. cephalus by zinc, copper, lead, cadmium and mercury. The spatiotemporal variations of the measured parameters were tested and discussed following the synergetic effects of water, sediment and muscle variables on fish biometrics. The sediments at the Port, Joinoville and Sidi-Salem sites were classified as heavily polluted by lead, copper, zinc and cadmium, whereas only at the Port by mercury. Muscular lead concentrations exceeded international standard values in Joinoville and Port, and zinc in Port. The increase of water dissolved oxygen induced a significant decrease in sediment TM. The increase of sediment TM caused a significant increase in muscle TM levels. The S-shaped logistic models indicated that muscle contaminations reached a saturation plateaus following the current sediment pollution. TM concentrations in fish muscles negatively affected fish weight, but only copper and cadmium significantly influenced fish length. The consumption of fish from the Port, Joinoville and Sidi-Salem can be dangerous because concentrations of lead, zinc and cadmium exceeded the international standards. This study validates the effectiveness of biomonitoring using M. cephalus as bioindicator in polluted coasts. Copyright © 2018 Elsevier B.V. All rights reserved.

Bacterial pathogen gene abundance and relation to recreational water quality at seven Great Lakes beaches

USGS Publications Warehouse

Oster, Ryan J.; Wijesinghe, Rasanthi U.; Fogarty, Lisa Reynolds; Haack, Sheridan K.; Fogarty, Lisa R.; Tucker, Taaja R.; Riley, Stephen

2014-01-01

Quantitative assessment of bacterial pathogens, their geographic variability, and distribution in various matrices at Great Lakes beaches are limited. Quantitative PCR (qPCR) was used to test for genes from E. coli O157:H7 (eaeO157), shiga-toxin producing E. coli (stx2), Campylobacter jejuni (mapA), Shigella spp. (ipaH), and a Salmonella enterica-specific (SE) DNA sequence at seven Great Lakes beaches, in algae, water, and sediment. Overall, detection frequencies were mapA>stx2>ipaH>SE>eaeO157. Results were highly variable among beaches and matrices; some correlations with environmental conditions were observed for mapA, stx2, and ipaH detections. Beach seasonal mean mapA abundance in water was correlated with beach seasonal mean log10E. coli concentration. At one beach, stx2 gene abundance was positively correlated with concurrent daily E. coli concentrations. Concentration distributions for stx2, ipaH, and mapA within algae, sediment, and water were statistically different (Non-Detect and Data Analysis in R). Assuming 10, 50, or 100% of gene copies represented viable and presumably infective cells, a quantitative microbial risk assessment tool developed by Michigan State University indicated a moderate probability of illness for Campylobacter jejuni at the study beaches, especially where recreational water quality criteria were exceeded. Pathogen gene quantification may be useful for beach water quality management.

An examination of short-term variations in water quality at a karst spring in Kentucky

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ryan, M.; Meiman, J.

1996-01-01

Water quality at many karst springs undergoes very high amplitude but relatively brief degradation following influxes of runoff. Accurately recording transient variations requires more rigorous sampling strategies than traditional methods. A pilot study to determine the usefulness of high-frequency, flow-dependent sampling strategies, combined with coincidental quantitative dye tracer tests, was implemented in the Big Spring Ground-Water Basin in Mammoth Cave National Park, Kentucky. Data recorded following two separate runoff events showed that the concentrations of two nonpoint source pollutants, fecal coliform bacteria and suspended sediment, greatly exceeded prerunoff event values for very short periods of time. A phreatic conduit segment,more » calculated at 17 million liters in volume, instantaneously propagated head changes, caused by direct runoff entering the aquifer, from the ground-water inputs to Big Spring. A significant delay between the initial increases in discharge and the arrival of direct runoff, as indicated by a steady decrease in specific conductance, represented the time required to displace this volume of phreatic water. The delay showed that sampling a karst spring only during peak discharge would be an unreliable sampling method. Runoff from two different subcatchments was tagged with tracer dye and the timing of the passage of the resultant dye clouds through Big Spring were compared to water quality variations. Distinct lag times between the arrival of direct runoff at Big Spring and the bacteria and suspended sediment waveforms were shown through the concurrent quantitative tracer tests to be related to the areal distribution of land-cover type within the basin.« less

The Beaver Creek story

USGS Publications Warehouse

Doyle, W.H.; Whitworth, B.G.; Smith, G.F.; Byl, T.D.

1996-01-01

Beaver Creek watershed in West Tennessee includes about 95,000 acres of the Nation's most productive farmland and most highly erodible soils. In 1989 the U.S. Geological Survey, in cooperation with the Tennessee Department of Agriculture, began a study to evaluate the effect of agricultural activities on water quality in the watershed and for best management practices designed to reduce agricultural nonpoint-source pollution. Agrichemical monitoring included testing the soils, ground water, and streams at four farm sites ranging from 27 to 420 acres. Monitoring stations were operated downstream to gain a better understanding of the water chemistry as runoff moved from small ditches into larger streams to the outlet of the Beaver Creek watershed. Prior to the implementation of best management practices at one of the farm study sites, some storms produced an average suspended-sediment concentration of 70,000 milligrams per liter. After the implementation of BMP's, however, the average value never exceeded 7,000 milligrams per liter. No-till crop production was the most effective best management practice for conserving soil on the farm fields tested. A natural bottomland hardwood wetland and a constructed wetland were evaluated as instream resource-management systems. The wetlands improved water quality downstream by acting as a filter and removing a significant amount of nonpoint-source pollution from the agricultural runoff. The constructed wetland reduced the sediment, pesticide, and nutrient load by approximately 50 percent over a 4-month period. The results of the Beaver Creek watershed study have increased the understanding of the effects of agriculture on water resources. Study results also demonstrated that BMP's do protect and improve water quality.

Field flume reveals aquatic vegetation's role in sediment and particulate phosphorus transport in a shallow aquatic ecosystem

USGS Publications Warehouse

Harvey, J.W.; Noe, G.B.; Larsen, L.G.; Nowacki, D.J.; McPhillips, L.E.

2011-01-01

Flow interactions with aquatic vegetation and effects on sediment transport and nutrient redistribution are uncertain in shallow aquatic ecosystems. Here we quantified sediment transport in the Everglades by progressively increasing flow velocity in a field flume constructed around undisturbed bed sediment and emergent macrophytes. Suspended sediment 100 μm became dominant at higher velocity steps after a threshold shear stress for bed floc entrainment was exceeded. Shedding of vortices that had formed downstream of plant stems also occurred on that velocity step which promoted additional sediment detachment from epiphyton. Modeling determined that the potentially entrainable sediment reservoir, 46 g m−2, was similar to the reservoir of epiphyton (66 g m−2) but smaller than the reservoir of flocculent bed sediment (330 g m−2). All suspended sediment was enriched in phosphorus (by approximately twenty times) compared with bulk sediment on the bed surface and on plant stems, indicating that the most easily entrainable sediment is also the most nutrient rich (and likely the most biologically active).

Surface-water-quality assessment of the lower Kansas River basin, Kansas and Nebraska; results of investigations, 1987-90

USGS Publications Warehouse

Helgesen, J.O.

1995-01-01

Surface-water-quality conditions and trends were assessed in the lower Kansas River Basin, which drains about 15,300 square miles of mainly agricultural land in southeast Nebraska and northeast Kansas. On the basis of established water-quality criteria, most streams in the basin were suitable for uses such as public-water supply, irrigation, and maintenance of aquatic life. However, most concerns identified from a previous analysis of available data through 1986 are substantiated by analysis of data for May 1987 through April 1990. Less-than-normal precipitation and runoff during 1987-90 affected surface-water quality and are important factors in the interpretation of results.Dissolved-solids concentrations in the main stem Kansas River during May 1987 through April 1990 commonly exceeded 500 milligrams per liter, which may be of concern for public-water supplies and for the irrigation of sensitive crops. Large concentrations of chloride in the Kansas River are derived from ground water discharging in the Smoky Hill River Basin west of the study unit. Trends of increasing concentrations of some dissolved major ions were statistically significant in the northwestern part of the study unit, which could reflect substantial increases in irrigated acreage.The largest concentrations of suspended sediment in streams during May 1987 through April 1990 were associated with high-density cropland in areas of little local relief and medium-density irrigated cropland in more dissected areas. The smallest concentrations were measured downstream from large reservoirs and in streams draining areas having little or no row-crop cultivation. Mean annual suspended-sediment transport rates in the main stem Kansas River increased substantially in the downstream direction. No conclusions could be reached concerning the relations of suspended-sediment transport, yields, or trends to natural and human factors.The largest sources of nitrogen and phosphorus in the study unit were fertilizer and livestock. Nitrate-nitrogen concentrations in stream-water samples did not exceed 10 milligams per liter; relatively large concentrations in the northwestern part of the study unit were associated with fertilizer application. Concentrations of total phosphorus generally were largest in the northwestern part of the study unit, which probably relates to the prevalence of cultivated land, fertilizer application, and livestock wastes.Deficiencies in dissolved-oxygen concentrations in streams occurred locally, as a result of discharges from wastewater-treatment plants, algal respiration, and inadequate reaeration associated with small streamflow. Large densities of a fecal-indicator bacterium, Escherichia coli, were associated with discharges from municipal wastewater-treatment plants and, especially in the northwestern part of the study unit, with transport of fecaThe largest concentrations of the herbicide atrazine generally were measured where the largest quantities of atrazine were applied to the land. Large atrazine concentrations, 10 to 20 micrograms per liter, were measured most frequently in unregulated principal streams during May and June. Downstream of reservoirs, the seasonal variability of atrazine concentrations was decreased compared to that of inflowing streams.

Activity and Diversity of Methanotrophic Bacteria at Methane Seeps in Eastern Lake Constance Sediments ▿

PubMed Central

Deutzmann, Jörg S.; Wörner, Susanne; Schink, Bernhard

2011-01-01

The activity and community structure of aerobic methanotrophic communities were investigated at methane seeps (pockmarks) in the littoral and profundal zones of an oligotrophic freshwater lake (Lake Constance, Germany). Measurements of potential methane oxidation rates showed that sediments inside littoral pockmarks are hot spots of methane oxidation. Potential methane oxidation rates at littoral pockmark sites exceeded the rates of the surrounding sediment by 2 orders of magnitude. Terminal restriction fragment length polymorphism (T-RFLP) analysis of the pmoA gene revealed major differences in the methanotrophic community composition between littoral pockmarks and the surrounding sediments. Clone library analysis confirmed that one distinct Methylobacter-related group dominates the community at littoral pockmarks. In profundal sediments, the differences between pockmarks and surrounding sediments were found to be less pronounced. PMID:21335392

Water-quality, bed-sediment, and biological data (October 2013 through September 2014) and statistical summaries of data for streams in the Clark Fork Basin, Montana

USGS Publications Warehouse

Dodge, Kent A.; Hornberger, Michelle I.

2015-12-24

This report presents the analytical results and qualityassurance data for water-quality, bed-sediment, and biota samples collected at sites from October 2013 through September 2014. Water-quality data include concentrations of selected major ions, trace elements, and suspended sediment. At 12 sites, dissolved organic carbon and turbidity samples were collected. In addition, nitrogen (nitrate plus nitrite) samples were collected at two sites. Daily values of mean suspended-sediment concentration and suspended-sediment discharge were determined for four sites. Seasonal daily values of turbidity were determined for four sites. Bed-sediment data include trace-ele­ment concentrations in the fine-grained fraction. Biological data include trace-element concentrations in wholebody tissue of aquatic benthic insects. Statistical summaries of water-quality, bed-sediment, and biological data for sites in the upper Clark Fork Basin are provided for the period of record.

Field screening of water, soil, bottom sediment, and biota associated with irrigation drainage in the Dolores Project and the Macos River basin, southwestern Colorado, 1994

USGS Publications Warehouse

Butler, D.L.; Osmundson, B.C.; Krueger, R.P.

1997-01-01

A reconnaissance investigation for the National Irrigation Water Quality Program in 1990 indicated elevated selenium concentrations in some water and biota samples collected in the Dolores Project in southwestern Colorado. High selenium concentrations also were indicated in bird samples collected in the Mancos Project in 1989. In 1994, field screenings were done in parts of the Dolores Project and Mancos River Basin to collect additional selenium data associated with irrigation inthose areas. Selenium is mobilized from soils in newly irrigated areas of the Dolores Project called the Dove Creek area, which includes newly (since 1987) irrigated land north of Cortez and south of Dove Creek.Selenium was detected in 18 of 20stream samples, and the maximum concentration was 12micrograms per liter. The Dove Creek area is unique compared to other study areas of the National Irrigation Water Quality Program becauseselenium concentrations probably are indicative of initial leaching conditions in a newly irrigated area.Selenium concentrations in nine shallow soil samples from the Dove Creek area ranged from 0.13 to 0.20 micrograms per gram. Selenium concentrations in bottom sediment from six ponds were less than the level of concern for fish and wildlife of 4 micrograms per gram. Many biota samples collected in the Dove Creek area had elevated selenium concentrations when compared to various guidelines and effect levels,although selenium concentrations in water, soil, and bottom sediment were relatively low. Selenium concentrations in 12 of 14 aquatic-invertebratesamples from ponds exceeded 3 micrograms per gram dry weight, a dietary guideline for protection of fish and wildlife. The mean seleniumconcentration of 10.3 micrograms per gram dry weight in aquatic bird eggs exceeded the guideline for reduced hatchability of 8 micrograms per gramdry weight. Two ponds in the Dove Creek area had a high selenium hazard rating based on a new protocol for assessing selenium hazard in theenvironment; however, waterfowl were reproducing at the two ponds. Three tributary streams of Mc Elmo Creek that drain irrigated areas of the Montezuma Valley south of the creek were sampled in 1994. Mud Creek probably is the largest source of selenium to Mc Elmo Creek. Most biota samples from Mud Creek had elevated selenium concentrations when compared to guidelines for dietary items and freshwater fish. Selenium concentrations in water samples collected in the Mancos River Basin upstream from Navajo Wash, which includes the Mancos Project, ranged from less than 1 to 10 micrograms per liter. Mud Creek contributed about 74 percent of the selenium load to the upper Mancos River in March 1994.Selenium concentrations were much higher in Navajo Wash; a sample collected in March had 97 micrograms per liter of selenium. Bottom-sediment samples from two ponds in the Mancos Projectexceeded the concentration of concern of 4 micrograms per gram. The highest selenium concentrations in biota samples from streams in the Mancos River Basin were for samples from Navajo Wash. Mostconcentrations in biota in the upper Mancos River Basin were less than guidelines. Mean selenium concentrations in eggs from aquatic birds collected at three ponds in the Mancos Project slightly exceed the guideline associated with reduced hatchability.Five bird livers had a mean selenium concentration of 32.6 micrograms per gram dry weight, whichslightly exceeded the mean concentration of 30 micrograms per gram dry weight that is associated with reproductive impairment. Two of the pondshad a high selenium hazard rating; however, mallard reproduction was observed in 1994 at one of the ponds that had a high selenium-hazard rating.

STAND, A DYNAMIC MODEL FOR SEDIMENT TRANSPORT AND WATER QUALITY. (R825758)

EPA Science Inventory

We introduce a new model–STAND (Sediment-Transport-Associated Nutrient Dynamics)–for simulating stream flow, sediment transport, and the interactions of sediment with other attributes of water quality. In contrast to other models, STAND employs a fully dynamic ba...

Water-quality variability and constituent transport and processes in streams of Johnson County, Kansas, using continuous monitoring and regression models, 2003-11

USGS Publications Warehouse

Rasmussen, Teresa; Gatotho, Jackline

2014-01-01

The population of Johnson County, Kansas increased by about 24 percent between 2000 and 2012, making it one of the most rapidly developing areas of Kansas. The U.S. Geological Survey, in cooperation with the Johnson County Stormwater Management Program, began a comprehensive study of Johnson County streams in 2002 to evaluate and monitor changes in stream quality. The purpose of this report is to describe water-quality variability and constituent transport for streams representing the five largest watersheds in Johnson County, Kansas during 2003 through 2011. The watersheds ranged in urban development from 98.3 percent urban (Indian Creek) to 16.7 percent urban (Kill Creek). Water-quality conditions are quantified among the watersheds of similar size (50.1 square miles to 65.7 square miles) using continuous, in-stream measurements, and using regression models developed from continuous and discrete data. These data are used to quantify variability in concentrations and loads during changing streamflow and seasonal conditions, describe differences among sites, and assess water quality relative to water-quality standards and stream management goals. Water quality varied relative to streamflow conditions, urbanization in the upstream watershed, and contributions from wastewater treatment facilities and storm runoff. Generally, as percent impervious surface (a measure of urbanization) increased, streamflow yield increased. Water temperature of Indian Creek, the most urban site which is also downstream from wastewater facility discharges, was higher than the other sites about 50 percent of the time, particularly during winter months. Dissolved oxygen concentrations were less than the Kansas Department of Health and Environment minimum criterion of 5 milligrams per liter about 15 percent of the time at the Indian Creek site. Dissolved oxygen concentrations were less than the criterion about 10 percent of the time at the rural Blue River and Kill Creek sites, and less than 5 percent of the time at the other sites. Low dissolved oxygen at all sites generally coincided with lowest streamflow and warmer water temperatures. Hourly dissolved oxygen concentrations less than 5 milligrams per liter were measured at all sites every year, indicating that even under normal climate conditions in non-urban watersheds such as Kill Creek, dissolved oxygen concentrations may not meet State aquatic-life criterion. Specific conductance was nearly always highest in Indian and Mill Creeks, which were the most urban streams with the largest upstream discharges from wastewater treatment facilities. The largest chloride concentrations and variability were recorded at urban sites and during winter. Each winter during the study period, chloride concentrations in the most urban site, Indian Creek, exceeded the U.S. Environmental Protection Agency-recommended criterion of 230 milligrams per liter for at least 10 consecutive days. The U.S. Environmental Protection Agency-recommended ecoregion criterion for turbidity was exceeded 30 (Indian Creek) to 50 (Blue River) percent of the time. The highest average annual streamflow-weighted suspendedsediment concentration during the study period was in Mill Creek, which has undergone rapid development that likely contributed to higher sediment concentrations. One of the largest suspended-sediment load events in Indian Creek was recorded in early May 2007 when about 25 percent of the total annual sediment load was transported during a period of about 2.25 days. A simultaneous load event was recorded in Kill Creek, when about 75 percent of the total annual sediment load was transported. Sediment yields generally increased as percent impervious surface increased. Computed hourly total nitrogen and total phosphorus concentrations and yields and streamflow-weighted concentrations generally were largest in Indian and Mill Creeks. Annual percent contribution of total nitrogen in the Blue River from wastewater treatment facility discharges ranged from 19 percent in 2010 to 60 percent in 2006. Annual percent contribution of total nitrogen in Indian Creek from wastewater treatment facility discharges ranged from 35 percent in 2010 to 93 percent in 2006. The largest percent nutrient contributions from wastewater discharges coincided with the smallest annual precipitation and streamflow volume, resulting in less contribution originating from runoff. Fecal indicator bacteria Escherichia coli density at the urban Indian Creek site was usually the largest of the five monitoring sites, with an annual median density that consistently exceeded the State primary contact criterion value but was less than the secondary contact criterion. Less than 1 percent of the total annual bacteria load in the Blue River and Indian Creek originated from wastewater discharges, except during 2006 when about 6 percent of the Indian Creek load originated from wastewater. Continuous water-quality monitoring provides a foundation for comprehensive evaluation and understanding of variability and loading characteristics in streams in Johnson County. Because several directly measured parameters are strongly correlated with particular constituents of interest, regression models provide a valuable tool for evaluating variability and loading on the basis of computed continuous data. Continuous data are particularly useful for characterizing nonpoint-source contributions from stormwater runoff. Transmission of continuous data in real-time makes it possible to rapidly detect and respond to potential environmental concerns. As monitoring technologies continue to improve, so does the ability to monitor additional constituents of interest, with smaller measurement error, and at lower operational cost. Continuous water-quality data including model information and computed concentrations and loads during the study period are available at http://nrtwq.usgs.gov/ks/.

Analysis of the transport of sediment by the Suncook River in Epsom, Pembroke, and Allenstown, New Hampshire, after the May 2006 flood

USGS Publications Warehouse

Flynn, Robert H.

2011-01-01

During May 13-16, 2006, rainfall in excess of 8.8 inches flooded central and southern New Hampshire. On May 15, 2006, a breach in a bank of the Suncook River in Epsom, New Hampshire, caused the river to follow a new path. In order to assess and predict the effect of the sediment in, and the subsequent flooding on, the river and flood plain, a study by the U.S. Geological Survey (USGS) characterizing sediment transport in the Suncook River was undertaken in cooperation with the Federal Emergency Management Agency (FEMA) and the New Hampshire Department of Environmental Services (NHDES). The U.S. Army Corps of Engineers (USACE) Hydrologic Engineering Center-River Analysis System (HEC-RAS) model was used to simulate flow and the transport of noncohesive sediments in the Suncook River from the upstream corporate limit of Epsom to the river's confluence with the Merrimack River in the Village of Suncook (Allenstown and Pembroke, N.H.), a distance of approximately 16 miles. In addition to determining total sediment loads, analyses in this study reflect flooding potentials for selected recurrence intervals that are based on the Suncook River streamgage flow data (streamgage 01089500) and on streambed elevations predicted by HEC-RAS for the end of water year 2010 (September 30, 2010) in the communities of Epsom, Pembroke, and Allenstown. This report presents changes in streambed and water-surface elevations predicted by the HEC-RAS model using data through the end of water year 2010 for the 50-, 10-, 2-, 1-, 0.2-percent annual exceedence probabilities (2-, 10-, 50-, 100-, and 500-year recurrence-interval floods, respectively), calculated daily and annual total sediment loads, and a determination of aggrading and degrading stream reaches. The model was calibrated and evaluated for a 400-day span from May 8, 2008 through June 11, 2009; these two dates coincided with field collection of stream cross-sectional elevation data. Seven sediment-transport functions were evaluated in the model with the Laursen (Copeland) sediment-transport function best describing the sediment load, transport behavior, and changes in streambed elevation for the specified spatial and temporal conditions of the 400-day calibration period. Simulation results from the model and field-collected sediment data indicate that, downstream of the avulsion channel, for the average daily mean flow during the study period, approximately 100 to 400 tons per day of sediment (varying with daily mean flow) was moving past the Short Falls Road Bridge over the Suncook River in Epsom, while approximately 0.05 to 0.5 tons per day of sediment was moving past the Route 28 bridge in Pembroke and Allenstown, and approximately 1 to 10 tons per day was moving past the Route 3 bridge in Pembroke and Allenstown. Changes in water-surface elevation that the model predicted for the end of water year 2010 to be a result of changes in streambed elevation ranged from a mean increase of 0.20 feet (ft) for the 50-percent annual exceedence-probability flood (2-year recurrence-interval flood) due to an average thalweg increase of 0.88 ft between the Short Falls Road Bridge and the Buck Street Dams in Pembroke and Allenstown to a mean decrease of 0.41 ft for the 50-percent annual exceedence-probability flood due to an average thalweg decrease of 0.49 ft above the avulsion in Epsom. An analysis of shear stress (force created by a fluid acting on sediment particles) was undertaken to determine potential areas of erosion and deposition. Based on the median grain size (d50) and shear stress analysis, the study found that in general, for floods greater than the 50-percent annual exceedence probability flood, the shear stress in the streambed is greater than the critical shear stress in much of the river study reach. The result is an expectation of streambed-sediment movement and erosion even at high exceedence-probability events, pending although the stream ultimately attains equilibrium through stream-stabilization measures or the adjustment of the river over time. The potential for aggradation in the Suncook River is greatest in the reach downstream of the avulsion. Specifically, these reaches are (1) downstream of the former sand pit from adjacent to Round Pond to downstream of the flood chute at the large meander bends, and (2) downstream of the Short Falls Road Bridge to approximately 3,800 ft upstream of the Route 28 bridge. The potential for degradation-net lowering of the streambed-is greatest for the reach upstream of the avulsion to the Route 4 bridge.

GENERAL GUIDELINES FOR USING THE SEDIMENT QUALITY TRIAD

EPA Science Inventory

The Sediment Quality Triad(Fig. 1),developed in the mid-1980s (Long and Chapman, 1985), is now widely used for conducting integrated assessments of sediment quality based on measures of chemistry,toxicity and benthos(e.g.,Canfield et al., 1994,1996,submitted; Carr et al., 1996;Ch...

Water Resources Data for California, 1965; Part 2: Water Quality Records

USGS Publications Warehouse

1965-01-01

Water quality information is presented for chemical quality, fluvial sediment, and water temperatures. The chemical quality includes concentrations of individual dissolved constituents and certain properties or characteristics such as hardness, sodium-adsorption-ratio, specific conductance, and pH. Fluvial sediment information is given for suspended-sediment discharges and concentrations and for particle-size distribution of suspended sediment and bed material. Water temperature data represent once-daily observations except for stations where a continuous temperature recorder furnishes information from which daily minimums and maximums are obtained.

Water Resources Data for California, 1966; Part 2: Water Quality Records

USGS Publications Warehouse

1967-01-01

Water-quality information is presented for chemical quality, fluvial sediment, and water temperatures. The chemical quality includes concentrations of individual dissolved constituents and certain properties or characteristics such as hardness, sodium-adsorption ratio, specific conductance, and pH. Fluvial-sediment information is given for suspended-sediment discharges and concentrations and for particle-size distribution of suspended sediment and bed material. Water-temperature data represent once-daily observations except for stations where a continuous temperature recorder furnishes information from which daily minimums and maximums are obtained.

Integrated quality assessment of sediments from harbour areas in Santos-São Vicente Estuarine System, Southern Brazil

NASA Astrophysics Data System (ADS)

Buruaem, Lucas Moreira; de Castro, Ítalo Braga; Hortellani, Marcos Antonio; Taniguchi, Satie; Fillmann, Gilberto; Sasaki, Silvio Tarou; Varella Petti, Mônica Angélica; Sarkis, Jorge Eduardo de Souza; Bícego, Márcia Caruso; Maranho, Luciane Alves; Davanso, Marcela Bergo; Nonato, Edmundo Ferraz; Cesar, Augusto; Costa-Lotufo, Leticia Veras; Abessa, Denis Moledo de Souza

2013-09-01

Santos-São Vicente Estuarine System is a highly populated coastal zone in Brazil and where it is located the major port of Latin America. Historically, port activities, industrial and domestic effluents discharges have constituted the main sources of contaminants to estuarine system. This study aimed to assess the recent status of sediment quality from 5 zones of Port of Santos by applying a lines-of-evidence approach through integrating results of: (1) acute toxicity of whole sediment and chronic toxicity of liquid phases; (2) grain size, organic matter, organic carbon, nitrogen, phosphorus, trace metals, polycyclic aromatic hydrocarbons, linear alkylbenzenes and butyltins; (3) benthic community descriptors. Results revealed a gradient of increasing contamination for metals and organic compounds, alongside with their geochemical carriers. Sediment liquid phases were more toxic compared to whole sediment. Low number of species and individuals indicated the impoverishment of benthic community. The use of site-specific sediment quality guidelines was more appropriate to predict sediment toxicity. The integration of results through Sediment Quality Triad approach and principal component analysis allowed observing the effects of natural stressors and dredging on sediment quality and benthic distribution. Even with recent governmental efforts to control, pollution is still relevant in Port of Santos and a threat to local ecosystems.

Effects of urbanization, construction activity, management practices, and impoundments on suspended-sediment transport in Johnson County, northeast Kansas, February 2006 through November 2008

USGS Publications Warehouse

Lee, Casey J.; Ziegler, Andrew C.

2010-01-01

The U.S. Geological Survey, in cooperation with the Johnson County, Kansas, Stormwater Management Program, investigated the effects of urbanization, construction activity, management practices, and impoundments on suspended-sediment transport in Johnson County from February 2006 through November 2008. Streamgages and continuous turbidity sensors were operated at 15 sites within the urbanizing 57-square-mile Mill Creek Basin, and 4 sites downstream from the other largest basins (49 to 66 square miles) in Johnson County. The largest sediment yields in Johnson County were observed downstream from basins with increased construction activity. Sediment yields attributed to the largest (68 acre) active construction site in the study area were 9,300 tons per square mile in 2007 and 12,200 tons per square mile in 2008; 5 to 55 times larger than yields observed at other sampling sites. However, given erodible soils and steep slopes at this site, sediment yields were relatively small compared to the range in historic values from construction sites without erosion and sediment controls in the United States (2,300 to 140,000 tons per square mile). Downstream from this construction site, a sediment forebay and wetland were constructed in series upstream from Shawnee Mission Lake, a 120-acre reservoir within Shawnee Mission Park. Although the original intent of the sediment forebay and constructed wetland were unrelated to upstream construction, they were nonetheless evaluated in 2008 to characterize sediment removal before stream entry into the lake. The sediment forebay was estimated to reduce 33 percent of sediment transported to the lake, whereas the wetland did not appear to decrease downstream sediment transport. Comparisons of time-series data and relations between turbidity and sediment concentration indicate that larger silt-sized particles were deposited within the sediment forebay, whereas smaller silt and clay-sized sediments were transported through the wetland and into the lake. Data collected at sites up and downstream from the constructed wetland indicated that hydraulic retention alone did not substantially reduce sediment loading to Shawnee Mission Lake. Mean-daily turbidity values at sampling sites downstream from basins with increased construction activity were compared to U.S. Environmental Protection Agency turbidity criteria designed to reduce discharge of pollutants from construction sites. The U.S. Environmental Protection Agency numeric turbidity criteria specifies that effluent from construction sites greater than 20 acres not exceed a mean-daily turbidity value of 280 nephelometric turbidity units beginning in 2011; this criteria will apply to sites greater than 10 acres beginning in 2014. Although numeric criteria would not have been applicable to data from sampling sites in Johnson County because they were not directly downstream from construction sites and because individual states still have to determine additional details as to how this criteria will be enforced, comparisons were made to characterize the potential of construction site effluent in Johnson County to exceed U.S. Environmental Protection Agency Criteria, even under extensive erosion and sediment controls. Numeric criteria were exceeded at sampling sites downstream from basins with increased construction activity for multiple days during the study period, potentially indicating the need for additional erosion and sediment controls and (or) treatment to bring discharges from construction sites into compliance with future numeric turbidity criteria. Among sampling sites in the Mill Creek Basin, sediment yields from the urbanizing Clear Creek Basin were approximately 2 to 3 times those from older, more stable urban or rural basins. Sediments eroded from construction sites adjacent to or surrounding streams appear to be more readily transported downstream, whereas sediments eroded from construction sites in headwater areas are more likely to

Distribution of pesticides and PCBs in sediments of agricultural drains in the Culiacan Valley, Sinaloa, Mexico.

PubMed

García-de la Parra, Luz María; Cervantes-Mojica, L Juleny; González-Valdivia, Carolina; Martínez-Cordero, Francisco J; Aguilar-Zárate, Gabriela; Bastidas-Bastidas, Pedro; Betancourt-Lozano, Miguel

2012-10-01

Agriculture is one of the most important economic activities in Sinaloa, Mexico. The Culiacan Valley is an extensive agricultural region characterized by a variety of crops with high-yield productions. In this study, concentrations of organochlorine (OCPs) and organophosphorus (OPs) pesticides and polychlorobiphenyls (PCBs) were determined in sediments of the agricultural drainage system of Culiacan Valley. Overall, 32 compounds were detected, with concentrations widely ranging from 0.03 to 1 294 ng g(-1) dry weight. OCP concentrations (15) ranged from 0.1 to 20.19 ng g(-1) dw. OP concentrations (8) ranged from 0.03 to 1294 ng g(-1) dw, and diazinon was the compound with the highest concentration. PCB concentrations were also determined and varied from 0.05 to 3.29 ng g(-1) dw. Other compounds detected included permethrin, triadimefon, and fipronil. The central zone registered the higher concentrations and the greatest number of compounds, which could be related to the occurrence of horticultural fields in this zone. According to sediment quality guidelines, the compounds exceeding the probable effect level were γ-HCH, p,p'-DDT and p,p'-DDE, while the pesticides above the maximum permissible concentration were endosulfan, azinphos methyl, diazinon, dichlorvos, and permethrin. Although Sinaloa is an important agricultural crop producer in northwest Mexico, there are not many studies dealing with pesticide distribution in agricultural areas.

Water-quality conditions near the confluence of the Snake and Boise Rivers, Canyon County, Idaho

USGS Publications Warehouse

Wood, Molly S.; Etheridge, Alexandra

2011-01-01

Total Maximum Daily Loads (TMDLs) have been established under authority of the Federal Clean Water Act for the Snake River-Hells Canyon reach, on the border of Idaho and Oregon, to improve water quality and preserve beneficial uses such as public consumption, recreation, and aquatic habitat. The TMDL sets targets for seasonal average and annual maximum concentrations of chlorophyll-a at 14 and 30 micrograms per liter, respectively. To attain these conditions, the maximum total phosphorus concentration at the mouth of the Boise River in Idaho, a tributary to the Snake River, has been set at 0.07 milligrams per liter. However, interactions among chlorophyll-a, nutrients, and other key water-quality parameters that may affect beneficial uses in the Snake and Boise Rivers are unknown. In addition, contributions of nutrients and chlorophyll-a loads from the Boise River to the Snake River have not been fully characterized. To evaluate seasonal trends and relations among nutrients and other water-quality parameters in the Boise and Snake Rivers, a comprehensive monitoring program was conducted near their confluence in water years (WY) 2009 and 2010. The study also provided information on the relative contribution of nutrient and sediment loads from the Boise River to the Snake River, which has an effect on water-quality conditions in downstream reservoirs. State and site-specific water-quality standards, in addition to those that relate to the Snake River-Hells Canyon TMDL, have been established to protect beneficial uses in both rivers. Measured water-quality conditions in WY2009 and WY2010 exceeded these targets at one or more sites for the following constituents: water temperature, total phosphorus concentrations, total phosphorus loads, dissolved oxygen concentration, pH, and chlorophyll-a concentrations (WY2009 only). All measured total phosphorus concentrations in the Boise River near Parma exceeded the seasonal target of 0.07 milligram per liter. Data collected during the study show seasonal differences in all measured parameters. In particular, surprisingly high concentrations of chlorophyll-a were measured at all three main study sites in winter and early spring, likely due to changes in algal populations. Discharge conditions and dissolved orthophosphorus concentrations are key drivers for chlorophyll-a on a seasonal and annual basis on the Snake River. Discharge conditions and upstream periphyton growth are most likely the key drivers for chlorophyll-a in the Boise River. Phytoplankton growth is not limited or driven by nutrient availability in the Boise River. Lower discharges and minimal substrate disturbance in WY2010 in comparison with WY2009 may have caused prolonged and increased periphyton and macrophyte growth and a reduced amount of sloughed algae in suspension in the summer of WY2010. Chlorophyll-a measured in samples commonly is used as an indicator of sestonic algae biomass, but chlorophyll-a concentrations and fluorescence may not be the most appropriate surrogates for algae growth, eutrophication, and associated effects on beneficial uses. Assessment of the effects of algae growth on beneficial uses should evaluate not only sestonic algae, but also benthic algae and macrophytes. Alternatively, continuous monitoring of dissolved oxygen detects the influence of aquatic plant respiration for all types of algae and macrophytes and is likely a more direct measure of effects on beneficial uses such as aquatic habitat. Most measured water-quality parameters in the Snake River were statistically different upstream and downstream of the confluence with the Boise River. Higher concentrations and loads were measured at the downstream site (Snake River at Nyssa) than the upstream site (Snake River near Adrian) for total phosphorus, dissolved orthophosphorus, total nitrogen, dissolved nitrite and nitrate, suspended sediment, and turbidity. Higher dissolved oxygen concentrations and pH were measured at the upstream site (Snake River near Adrian) than the downstream site (Snake River at Nyssa). Contributions from the Boise River measured at Parma do not constitute all of the increase in nutrient and sediment loads in the Snake River between the upstream and downstream sites. Surrogate models were developed using a combination of continuously monitored variables to estimate concentrations of nutrients and suspended sediment when samples were not possible. The surrogate models explained from 66 to 95 percent of the variability in nutrient and suspended sediment concentrations, depending on the site and model. Although the surrogate models could not always represent event-based changes in modeled parameters, they generally were successful in representing seasonal and annual patterns. Over a longer period, the surrogate models could be a useful tool for measuring compliance with state and site-specific water-quality standards and TMDL targets, for representing daily and seasonal variability in constituents, and for assessing effects of phosphorus reduction measures within the watershed.

Water-quality characteristics for selected streams in Lawrence County, South Dakota, 1988-92

USGS Publications Warehouse

Williamson, Joyce E.; Hayes, Timothy Scott

2000-01-01

During the 1980?s, significant economic development and population growth began to occur in Lawrence County in the northern part of the Black Hills of western South Dakota. Rising gold prices and heap-leach extraction methods allowed the economic recovery of marginal gold ore deposits, resulting in development of several large-scale, open-pit gold mines in Lawrence County. There was increasing local concern regarding potential impacts on the hydrologic system, especially relating to the quantity and quality of water in the numerous streams and springs of Lawrence County. In order to characterize the water quality of selected streams within Lawrence County, samples were collected from 1988 through 1992 at different times of the year and under variable hydrologic conditions. During the time of this study, the Black Hills area was experiencing a drought; thus, most samples were collected during low-flow conditions.Streamflow and water-quality characteristics in Lawrence County are affected by both geologic conditions and precipitation patterns. Most streams that cross outcrops of the Madison Limestone and Minnelusa Formation lose all or large part of their streamflow to aquifer recharge. Streams that are predominantly spring fed have relatively stable streamflow, varying slightly with dry and wet precipitation cycles.Most streams in Lawrence County generally have calcium magnesium bicarbonate type waters. The sites from the mineralized area of central Lawrence County vary slightly from other streams in Lawrence County by having higher concentrations of sodium, less bicarbonate, and more sulfate. False Bottom Creek near Central City has more sulfate than bicarbonate. Nitrogen, phosphorous, and cyanide concentrations were at or near the laboratory reporting limits for most sites and did not exceed any of the water-quality standards. Nitrite plus nitrate concentrations at Annie Creek near Lead, Whitetail Creek at Lead, Squaw Creek near Spearfish, and Spearfish Creek below Robison Gulch were somewhat higher than at other sites. Mining activity, agricultural activity, and domestic development are possible sources of nitrogen to the streams. Increased mining activities were identified as the probable cause of increased nitrogen concentrations in Annie Creek.In the mineralized area of the northern Black Hills, detectable concentrations of trace elements are common in stream water, occasionally exceeding beneficial-use and aquatic-life criteria. In addition, many basins have been disturbed by both historical and recent mining operations and cleanup activities. The maximum dissolved arsenic concentration at Annie Creek near Lead (48 micrograms per liter) approached the current arsenic drinking-water standard. Concentrations at or greater than 5 micrograms per liter were found in samples from Annie Creek near Lead, Spearfish Creek above Spearfish, Whitetail Creek at Lead, and False Bottom Creek near Spearfish. Bear Butte Creek near Deadwood had one sample with a dissolved copper concentration that exceeded acute and chronic aquatic-life criteria. Bear Butte Creek near Deadwood had several manganese concentrations that exceeded the secondary maximum contaminant level of 50 micrograms per liter.Bed-sediment and water-quality data from selected sites in small drainage basins were used to determine if factors such as pH, arsenic concentrations in bed sediments, and calcite saturation control dissolved arsenic concentrations. Arsenic solubility is controlled by adsorption, mainly on ferrihydrite. In addition, adsorption/desorption of arsenic is controlled by the pH of the stream, with high arsenic concentrations appearing only at higher pH conditions (above 8). There are significant arsenic sources available to almost all the small streams of the northern Black Hills mining area, but arsenic is less mobile in streams that are not influenced to the higher pH values by calcite. Streams where arsenic is more mobile have lower iron concentrations i

Water quality in the central Columbia Plateau, Washington and Idaho, 1992-95

USGS Publications Warehouse

Williamson, Alex K.; Munn, Mark D.; Ryker, Sarah J.; Wagner, Richard J.; Ebbert, James C.; Vanderpool, Ann M.

1998-01-01

Water quality in the Central Columbia Plateau of eastern Washington and western Idaho has been adversely affected by agriculture, especially in irrigated areas, according to the results of a five-year investigation by the U. S. Geological Survey (USGS). Some improvements, however, are noticeable, such as less sediment being washed into streams. These improvements may be the result of increased use of best management practices (BMPs) by area farmers. Areas with intensive fertilizer use and irrigation, such as in the Columbia Basin Irrigation Project (CBIP), showed the greatest impacts on ground-water quality. (The CBIP includes parts of Franklin, Grant, and Adams counties in eastern Washington.)

Escherichia coli at Ohio Bathing Beaches--Distribution, Sources, Wastewater Indicators, and Predictive Modeling

USGS Publications Warehouse

Francy, Donna S.; Gifford, Amie M.; Darner, Robert A.

2003-01-01

Results of studies during the recreational seasons of 2000 and 2001 strengthen the science that supports monitoring of our Nation?s beaches. Water and sediment samples were collected and analyzed for concentrations of Escherichia coli (E. coli). Ancillary water-quality and environmental data were collected or compiled to determine their relation to E. coli concentrations. Data were collected at three Lake Erie urban beaches (Edgewater, Villa Angela, and Huntington), two Lake Erie beaches in a less populated area (Mentor Headlands and Fairport Harbor), and one inland-lake beach (Mosquito Lake). The distribution of E. coli in water and sediments within the bathing area, outside the bathing area, and near the swash zone was investigated at the three Lake Erie urban beaches and at Mosquito Lake. (The swash zone is the zone that is alternately covered and exposed by waves.) Lake-bottom sediments from outside the bathing area were not significant deposition areas for E. coli. In contrast, interstitial water and subsurface sediments from near the swash zone were enriched with E. coli. For example, E. coli concentrations were as high as 100,000 colonies per 100 milliliters in some interstitial waters. Although there are no standards for E. coli in swash-zone materials, the high concentrations found at some locations warrant concern for public health. Studies were done at Mosquito Lake to identify sources of fecal contamination to the lake and bathing beach. Escherichia coli concentrations decreased with distance from a suspected source of fecal contamination that is north of the beach but increased at the bathing beach. This evidence indicated that elevated E. coli concentrations at the bathing beach are of local origin rather than from transport of bacteria from sites to the north. Samples collected from the three Lake Erie urban beaches and Mosquito Lake were analyzed to determine whether wastewater indicators could be used as surrogates for E. coli at bathing beaches. None of the concentrations of wastewater indicators of fecal contamination, including 3b-coprostanol and cholesterol, were significantly correlated (a=0.05) to concentrations of E. coli. Concentrations of the two compounds that were significantly correlated to E. coli were components of coal tar and asphalt, which are not necessarily indicative of fecal contamination. Data were collected to build on an earlier 1997 study to develop and test multiple-linear-regression models to predict E. coli concentrations using water-quality and environmental variables as explanatory variables. The probability of exceeding the single-sample bathing-water standard for E. coli (235 colonies per 100 milliliters) was used as the model output variable. Threshold probabilities for each model were established. Computed probabilities that are less than a threshold probability indicate that bacterial water quality is most likely acceptable. Computed probabilities equal to or above the threshold probability indicate that the water quality is most likely not acceptable and that a water-quality advisory may be needed. Models were developed at each beach, whenever possible, using combinations of 1997, 2000, and (or) 2001 data. The models developed and tested in this study were shown to be beach specific; that is, different explanatory variables were used to predict the probability of exceeding the standard at each beach. At Mentor Headlands and Fairport Harbor, models were not developed because water quality was generally good. At the three Lake Erie urban beaches, models were developed with variable lists that included the number of birds on the beach at the time of sampling, lake-current direction, wave height, turbidity, streamflow of a nearby river, and rainfall. The models for Huntington explained a larger percentage of the variability in E. coli concentrations than the models for Edgewater and Villa Angela. At Mosquito Lake, a model based on 2000 and 2001 data contained the

Quantifying suspended sediment flux in a mixed-land-use urbanizing watershed using a nested-scale study design.

PubMed

Zeiger, Sean; Hubbart, Jason A

2016-01-15

Suspended sediment (SS) remains the most pervasive water quality problem globally and yet, despite progress, SS process understanding remains relatively poor in watersheds with mixed-land-use practices. The main objective of the current work was to investigate relationships between suspended sediment and land use types at multiple spatial scales (n=5) using four years of suspended sediment data collected in a representative urbanized mixed-land-use (forest, agriculture, urban) watershed. Water samples were analyzed for SS using a nested-scale experimental watershed study design (n=836 samples×5 gauging sites). Kruskal-Wallis and Dunn's post-hoc multiple comparison tests were used to test for significant differences (CI=95%, p<0.05) in SS levels between gauging sites. Climate extremes (high precipitation/drought) were observed during the study period. Annual maximum SS concentrations exceeded 2387.6 mg/L. Median SS concentrations decreased by 60% from the agricultural headwaters to the rural/urban interface, and increased by 98% as urban land use increased. Multiple linear regression analysis results showed significant relationships between SS, annual total precipitation (positive correlate), forested land use (negative correlate), agricultural land use (negative correlate), and urban land use (negative correlate). Estimated annual SS yields ranged from 16.1 to 313.0 t km(-2) year(-1) mainly due to differences in annual total precipitation. Results highlight the need for additional studies, and point to the need for improved best management practices designed to reduce anthropogenic SS loading in mixed-land-use watersheds. Copyright © 2015 Elsevier B.V. All rights reserved.

Distribution of organochlorine compounds in superficial sediments from the Gulf of Lion, northwestern Mediterranean Sea

NASA Astrophysics Data System (ADS)

Salvadó, Joan A.; Grimalt, Joan O.; López, Jordi F.; Durrieu de Madron, Xavier; Pasqual, Catalina; Canals, Miquel

2013-11-01

Superficial sediments from Cap de Creus to the Rhone Delta, in the Gulf of Lion, Northwestern Mediterranean Sea, including the mid-shelf mud belt and the continental slope were collected between 2005 and 2008 to assess the levels, main sources and distribution patterns of organochlorine pollutants. Discharges from the Rhone River are the main source for all these compounds around the area. The spatial distribution of organochlorine pollutants was also related to their physicochemical properties and to sediment grain size and composition. The concentrations of polychlorobiphenyls (PCBs), dichlorodiphenyltrichloroethane (DDT) and its metabolites (DDD and DDE), and the chlorobenzenes (CBzs) - pentachlorobenzene (PeCB) and hexachlorobenzene (HCB) - decreased westwards along the mid-shelf mud belt. In contrast, hexachlorocyclohexane isomers (HCHs), namely lindane (γ-HCH), followed another concentration pattern suggesting a different transport mode. The major concentrations of organochlorine compounds were observed off the Rhone River mouth, in the prodelta, where PCB, DDT and CBz concentrations reached 38, 29 and 8.3 ng g-1, respectively. These average concentrations in the mid continental shelf were two to ten times lower than those found in a study performed about 20 years ago, albeit in almost all the sites the values of PCBs and DDTs still exceed the NOAA’s Sediment Quality Guidelines. In contrast, the concentrations in the continental slope were nearly the same as 20 years ago, which may evidence that even most of these compounds were banned decades ago, their background concentrations associated to diffuse pollution have not decreased in the deep continental margin.

Metal Concentrations in Sediment And Biota of the Huludao Coast in Liaodong Bay and Associated Human and Ecological Health Risks.

PubMed

Gao, Mi; Klerks, Paul L; Wu, Xing; Chen, Hongxing; Xie, Lingtian

2016-07-01

This study assessed the contamination extent and potential ecological and human health impacts for chromium (Cr), manganese (Mn), nickel (Ni), copper (Cu), zinc (Zn), cadmium (Cd), and lead (Pb) in sediments and indigenous benthic organisms along the coastal area of Huludao, China. We analyzed a total of eight species: two benthic fish species, two bivalves, two snails, and two decapod crustaceans. Cu, Zn, and Cd levels in sediment exceeded the Chinese marine sediment quality criteria. The geoaccumulation index was highest for Cd followed in a decreasing order by Zn, Pb, Cu, Ni, and Cr. Metal levels were highest in the four mollusk species. The oyster and veined rapa whelk had the highest bioaccumulation factors, indicating that these two species would be well suited for monitoring the metal pollution in this area. Our comparison of estimated daily intake values for human consumption of the seafood species to the Food and Agricultural Organization-recommended daily dietary allowances indicate potential health risks from the intake of Cd from all shellfish other than our crab species and Zn intake from oyster consumption. An analysis of target hazard quotients identified noncarcinogenic health risks from Cd (in all shellfish analyzed except for our crab species), Cu, and Zn (in oysters and veined rapa whelks). Moreover, an analysis of cancer risk from Pb ingestion detected an increased risk for consumption of all shellfish except for the crab species. Health risks seem especially pronounced for the consumption of oysters and the veined rapa whelks; a seafood advisory may be warranted for these mollusks.

Global rates of marine sulfate reduction and implications for sub-sea-floor metabolic activities

NASA Astrophysics Data System (ADS)

Bowles, Marshall W.; Mogollón, José M.; Kasten, Sabine; Zabel, Matthias; Hinrichs, Kai-Uwe

2014-05-01

Sulfate reduction is a globally important redox process in marine sediments, yet global rates are poorly quantified. We developed an artificial neural network trained with 199 sulfate profiles, constrained with geomorphological and geochemical maps to estimate global sulfate-reduction rate distributions. Globally, 11.3 teramoles of sulfate are reduced yearly (~15% of previous estimates), accounting for the oxidation of 12 to 29% of the organic carbon flux to the sea floor. Combined with global cell distributions in marine sediments, these results indicate a strong contrast in sub-sea-floor prokaryote habitats: In continental margins, global cell numbers in sulfate-depleted sediment exceed those in the overlying sulfate-bearing sediment by one order of magnitude, whereas in the abyss, most life occurs in oxic and/or sulfate-reducing sediments.

Causes of toxicity to Hyalella azteca in a stormwater management facility receiving highway runoff and snowmelt. Part I: polycyclic aromatic hydrocarbons and metals.

PubMed

Bartlett, A J; Rochfort, Q; Brown, L R; Marsalek, J

2012-01-01

The Terraview-Willowfield Stormwater Management Facility (TWSMF) receives inputs of multiple contaminants, including metals, polycyclic aromatic hydrocarbons (PAHs), road salt, and nutrients, via highway and residential runoff. Contaminant concentrations in runoff are seasonally dependent, and are typically high in early spring, coinciding with the snowmelt. In order to investigate the seasonal fluctuations of contaminant loading and related changes in toxicity to benthic invertebrates, overlying water and sediment samples were collected in the fall and spring, reflecting low and high contaminant loading, respectively, and four-week sediment toxicity tests were conducted with Hyalella azteca. The effects of metals and PAHs are discussed here; the effects of salts, nutrients, and water quality are discussed in a companion paper. Survival and growth of Hyalella after exposure to fall samples were variable: survival was significantly reduced (64-74% of controls) at three out of four sites, but there were no significant growth effects. More dramatic effects were observed after Hyalella were exposed to spring samples: survival was significantly reduced at the two sites furthest downstream (0-75% of controls), and growth was significantly lower in four out of five sites when comparing Hyalella exposed to site sediment with overlying site water versus site sediment with overlying control water. These seasonal changes in toxicity were not related to metals or PAHs: 1. levels of bioavailable metals were below those expected to cause toxicity, and 2. levels of PAHs in sediment were lowest at sites with the greatest toxicity and highest in water and sediment at sites with no toxicity. Although not associated with toxicity, some metals and PAHs exceeded probable and severe effect levels, and could be a cause for concern if contaminant bioavailability changes. Toxicity in the TWSMF appeared to be primarily associated with water-borne contaminants. The cause(s) of these effects are discussed in our companion manuscript. Crown Copyright © 2011. Published by Elsevier B.V. All rights reserved.

Geomorphic versus land use controls on suspended sediment rating curves

NASA Astrophysics Data System (ADS)

Belmont, P.; Vaughan, A. A.; Fisher, A. C. N.

2017-12-01

The relation between river discharge (Q) and suspended sediment (SS) concentration reflects the degree to which sediment sources are accessed or depleted across the range of flow conditions. Increased availability of high resolution topography and land use data greatly enhance our ability to evaluate linkages between characteristics of these sediment rating curves (SRCs) and the geomorphic features that influence them. We evaluated Q-SS relations at 45 gages throughout Minnesota, USA representing a wide variety of landscape settings in terms of topography, land use, and geologic history. We characterized the SRCs according to the overall shape, steepness (exponent), vertical offset (coefficient) and SS concentration under low flow (90% exceedance) conditions. Rivers exhibited three distinct SRC shapes, simple power functions, threshold power functions and peaked power functions. We used random forest models to analyze relations between SRC parameters and attributes of the watershed as well as the near-channel environment. The model correctly classified 78% of SRC shapes and explained 60% of variance in the SRC exponent, 43% of the SRC coefficient for rising limb samples, and 45% of variance under low flow conditions. Notably, the random forest models predict that near-channel morphology predominately controls both the shape and steepness of the sediment rating curves. Land use predominately controls the vertical offset (coefficient) and SS concentration under low flow conditions. These findings suggest that land use and watershed restoration practices may have little capacity to alter the shape and steepness of these curves as these characteristics may be dictated by the geologic and geomorphic setting. Rather, human influences in the watershed may exhibit the greatest influence on suspended sediment concentrations at moderate to low flows. Criteria to evaluate improvements in water quality as a result of changes in land management might be most meaningful if they target these moderate to low flow conditions.

Hydrogeomorphic responses to explosive volcanic eruptions-what have we learned?

NASA Astrophysics Data System (ADS)

Major, J. J.

2011-12-01

Explosive eruptions can greatly alter landscape hydrology and geomorphology. Analyses of hydrogeomorphic responses to four major eruptions, spanning two orders of magnitude in eruption volume, reveal patterns in the timing, pace, and style of landscape response to explosive eruptions. Tephra fall can blanket broad swaths of landscape with sediment having a low-permeability surface, and can cause significant tree damage. Volcanic blasts can also deposit many tens of cm of fines-capped sediment across the landscape, and can raze or completely remove vast tracts of forest. Debris avalanches, pyroclastic flows, and lahars can fill channels and valley floors with meters to tens of meters of gravelly sand for tens of kilometers from source; straighten, smooth or obliterate channel planforms; and remove, bury, or smother riparian vegetation. Such disturbances can radically alter runoff regimes and the manner in which water is routed along channels. Surface-infiltration capacities of landscapes denuded by volcanic blast and pyroclastic flows following eruptions of Mount St. Helens (MSH) and Unzen were reduced 1-2 orders of magnitude (from >100 mm/hr to as little as 2-5 mm/hr). Altered hydrologic processes promoted substantial overland flow in basins normally dominated by subsurface flow; measurements at Unzen showed overland flow 3-5 times greater from barren, tephra-covered ground compared to vegetated ground. Hydrological analysis at MSH showed that post-eruption wet-season peakflow discharges increased by a few to tens of percent in eruption-affected basins. Changes in hydrological processes alter sediment erosion and transport; extensive hillslope and channel erosion can lead to sediment yields that exceed preeruption yields by orders of magnitude. Indeed, sediment yields from volcanically disturbed watersheds rival those of great sediment-producing rivers worldwide. Short-term landscape-denudation rates following explosive eruptions are typically 10-104 times greater than estimated long-term denudation rates, reflecting great mobility of highly erodible sediment delivered by eruptions. Despite sometimes cataclysmic eruption-induced disturbance, landscapes are resilient. Owing to erosional, biogenic, and cryogenic modifications of tephra surfaces, eruption-induced changes in runoff and river discharge commonly relax substantially within a decade. Elevated sediment transport, however, can persist for decades. Observations following eruption of MSH show that magnitude and duration of enhanced sediment transport varied chiefly with the nature of disturbance-high yields from basins bearing significant channel disturbance persist far longer than those from basins bearing only hillslope disturbance. Observations from MSH and Mount Pinatubo show that excessive sediment yields from severely disturbed landscapes decay considerably within a decade of eruption, but appear to plateau at levels that can exceed preeruption yields by tens of percent for at least a few decades. Studies at Mount Hood show that distal aggraded channels can take up to a century to return to preeruption base level. Prolonged excessive sediment transport following eruptions can cause environmental and socioeconomic harm that equals or exceeds that caused directly by eruptions.

Evaluation of the Contamination by Explosives and Metals in Soils, Vegetation, Surface Water and Sediment at Cold Lake Air Weapons Range (CLAWR), Alberta, Phase 2

DTIC Science & Technology

2004-10-01

severe ISQG, but were of the same order of magnitude. For mercury , only 3 samples, all in Jimmy Lake, exceeded the ISQG. Sed-JL-3 even exceeded the most...but can also be part of bomb painting as pointed out by Boggs [29]. The vegetation analyses revealed that some metals are phytoremediated from

Water-Quality, Bed-Sediment, and Biological Data (October 2004 through September 2005) and Statistical Summaries of Data for Streams in the Upper Clark Fork Basin, Montana

USGS Publications Warehouse

Dodge, Kent A.; Hornberger, Michelle I.; Dyke, Jessica

2006-01-01

Water, bed sediment, and biota were sampled in streams from Butte to below Missoula as part of a long-term monitoring program, conducted in cooperation with the U.S. Environmental Protection Agency, to characterize aquatic resources in the upper Clark Fork basin of western Montana. Sampling sites were located on the Clark Fork, six major tributaries, and three smaller tributaries. Water-quality samples were collected periodically at 18 sites during October 2004 through September 2005 (water year 2005). Bed-sediment and biological samples were collected once in August 2005. The primary constituents analyzed were trace elements associated with tailings from historical mining and smelting activities. This report summarizes the results of water-quality, bed-sediment, and biota samples col-lected in water year 2005 and provides statistical summaries of data collected since 1985. Water-quality data for samples collected periodically from streams include concentrations of selected major ions, trace ele-ments, and suspended sediment. Daily values of suspended-sed-iment concentration and suspended-sediment discharge were determined for three sites. Bed-sediment data include trace-ele-ment concentrations in the fine-grained fraction. Bio-logical data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Quality-assurance data are reported for analytical results of water, bed sediment, and biota. Statistical summaries of water-quality, bed-sediment, and biological data are provided for the period of record since 1985 for each site.

The vulnerability of Indo-Pacific mangrove forests to sea-level rise

USGS Publications Warehouse

Lovelock, Catherine E.; Cahoon, Donald R.; Friess, Daniel A.; Guntenspergen, Glenn R.; Krauss, Ken W.; Reef, Ruth; Rogers, Kerrylee; Saunders, Megan L.; Sidik, Frida; Swales, Andrew; Saintilan, Neil; Thuyen, Le Xuan; Triet, Tran

2015-01-01

Sea-level rise can threaten the long-term sustainability of coastal communities and valuable ecosystems such as coral reefs, salt marshes and mangroves. Mangrove forests have the capacity to keep pace with sea-level rise and to avoid inundation through vertical accretion of sediments, which allows them to maintain wetland soil elevations suitable for plant growth. The Indo-Pacific region holds most of the world’s mangrove forests, but sediment delivery in this region is declining, owing to anthropogenic activities such as damming of rivers. This decline is of particular concern because the Indo-Pacific region is expected to have variable, but high, rates of future sea-level rise. Here we analyse recent trends in mangrove surface elevation changes across the Indo-Pacific region using data from a network of surface elevation table instruments. We find that sediment availability can enable mangrove forests to maintain rates of soil-surface elevation gain that match or exceed that of sea-level rise, but for 69 per cent of our study sites the current rate of sea-level rise exceeded the soil surface elevation gain. We also present a model based on our field data, which suggests that mangrove forests at sites with low tidal range and low sediment supply could be submerged as early as 2070.

The vulnerability of Indo-Pacific mangrove forests to sea-level rise.

PubMed

Lovelock, Catherine E; Cahoon, Donald R; Friess, Daniel A; Guntenspergen, Glenn R; Krauss, Ken W; Reef, Ruth; Rogers, Kerrylee; Saunders, Megan L; Sidik, Frida; Swales, Andrew; Saintilan, Neil; Thuyen, Le Xuan; Triet, Tran

2015-10-22

Sea-level rise can threaten the long-term sustainability of coastal communities and valuable ecosystems such as coral reefs, salt marshes and mangroves. Mangrove forests have the capacity to keep pace with sea-level rise and to avoid inundation through vertical accretion of sediments, which allows them to maintain wetland soil elevations suitable for plant growth. The Indo-Pacific region holds most of the world's mangrove forests, but sediment delivery in this region is declining, owing to anthropogenic activities such as damming of rivers. This decline is of particular concern because the Indo-Pacific region is expected to have variable, but high, rates of future sea-level rise. Here we analyse recent trends in mangrove surface elevation changes across the Indo-Pacific region using data from a network of surface elevation table instruments. We find that sediment availability can enable mangrove forests to maintain rates of soil-surface elevation gain that match or exceed that of sea-level rise, but for 69 per cent of our study sites the current rate of sea-level rise exceeded the soil surface elevation gain. We also present a model based on our field data, which suggests that mangrove forests at sites with low tidal range and low sediment supply could be submerged as early as 2070.

Mechanisms of Sediment Transport to an Abandoned Distributary Channel on the Huanghe (Yellow River) Delta, China

NASA Astrophysics Data System (ADS)

Kumpf, L. L.; Kineke, G. C.; Carlson, B.; Mullane, M.

2017-12-01

Avulsions on the fine-grained Huanghe delta have left it scarred with traces of abandoned distributary channels that become intertidal systems, open to water and sediment exchange with the sea. In 1996, an engineered avulsion of the Huanghe left a 30 km long abandoned channel to the south of the modern active river channel. Though all fluvial input was cut off, present-day sedimentation on the new tidal flats has been observed at rates around 2 cm/yr. The source must be suspended-sediment from the Bohai Sea conveyed by the tidal channel network, but the mechanisms promoting sediment import are unknown. Possible mechanisms include (A) import sourced from the sediment-rich buoyant coastal plume, (B) wave resuspension on the shallow shelf, (C) reverse-estuarine residual circulation in the tidal channel, and (D) tidal asymmetry in the channel. Over three summers, in situ measurements of current velocity, suspended-sediment concentration (SSC), and wave climate were made on the delta front, and measurements of velocity, SSC, and salinity were made within the tidal channel. Results suggest that the buoyant plume from the active Huanghe channel can transport sediment south toward the tidal channel mouth (A). Additionally, wave resuspension (B) takes place on the subaqueous topset beds when the significant wave height exceeds 1 m, providing potential sources of suspended-sediment to the tidal channel. Within the abandoned channel, the tidal channel can become hypersaline and exhibit reverse-estuarine circulation (C), which would promote import of turbid coastal water near the surface. Time-series of velocity in the tidal channel indicate that ebb currents are consistently higher than flood currents through the spring-neap cycle (D), with maximum velocities exceeding 1 m/s and corresponding maximum SSC reaching 2 g/L during spring tide. While ebb dominance would typically tend to flush the system of its sediment over time, sediment supplied to the tidal flats may not be removed during the ebb, leading to net accumulation. Flocculation may also enhance settling over the inundated mudflats, contributing to the observed sedimentation. If import and sedimentation proceed at current rates, this abandoned channel may eventually anneal, contributing to the stability of the Huanghe delta.

NEAR-COASTAL SEDIMENT AS A HABITAT IN THE GULF OF MEXICO: CHEMICAL QUALITY, TOXICITY, AND BENTHIC COMMUNITY COMPOSITION

EPA Science Inventory

Sediment quality was determined in a multiyear study for 108 near-coastal sites located in Mississippi, Alabama and Florida. The primary objective of the study was to determine the relative impact of common stressor sources on sediment quality utilizing a weight-of-evidence appro...

IMPACT OF STORM-WATER OUTFALLS ON SEDIMENT QUALITY IN CORPUS CHRISTI BAY, TEXAS, USA

EPA Science Inventory

To determine the quality of sediments and extent of contaminant impacts, a Sediment Quality Triad (SQT) study was conducted at 36 sites in the Corpus Christi Bay, Texas, USA, system. Fifteen of the 36 sites were located near storm-water outfalls, but 13 other sites (i.e., industr...

Hydrology and water quality of Little Cross Creek, Cumberland County, North Carolina, 1996-98

USGS Publications Warehouse

Giorgino, Mary J.; Middleton, Terry L.

2000-01-01

Little Cross Creek is a small stream located in Cumberland County, North Carolina, in the Sand Hills area of the Coastal Plain Province. From August 1996 through August 1998, the U.S. Geological Survey collected streamflow, water-quality, and time-of-travel data at 10 sites in Little Cross Creek Basin to assess ambient conditions and compute loads of suspended sediment, total nitrogen, total phosphorus, and total organic carbon. Streamflows in the Little Cross Creek Basin responded to climatic factors and to human activities such as water withdrawals and controlled releases from impoundments. Peak streamflows were observed during the passages of Hurricane Fran in September 1996 and Hurricane Josephine in October 1996. Streamflows generally were lowest during the summer and early fall of 1997, reflecting drought conditions associated with a prevailing El Nino. At most sites, average streamflow per unit drainage area, or yield, was higher than yields reported previously for the Sand Hills. High yields may have resulted from unidentified inputs of water to the study basins or from underestimation of the contributing drainage area. Bonnie Doone Lake, Kornbow Lake, Mintz Pond, and Glenville Lake, four impoundments of Little Cross Creek, notably influence hydrology and water quality in the basin. Streamflow records indicate that these impoundments dampen peak stormflows and delay the downstream release of stormwater. Time of travel also is affected by seasonal stratification in the reservoirs. In general, sites downstream from reservoirs have lower concentrations of suspended sediment, turbidity, and total phosphorus than sites upstream from reservoirs or sites that receive stormwater runoff. Few water-quality problems were observed in the Little Cross Creek Basin for the constituents that were sampled. However, fecal coliform bacteria commonly exceeded 200 colonies per 100 milliliters at two of the seven monitored sites during the study. Relatively high concentrations of specific conductance, total phosphorus, and total ammonia plus organic nitrogen were observed in Clark Pond Creek, a tributary to Little Cross Creek. Loads and yields of suspended sediment, total nitrogen, total phosphorus, and total organic carbon were computed for the period from October 1996 through September 1997. The highest suspended-sediment yield (230 tons per square mile per year) occurred upstream from Bonnie Doone Lake, probably because there were no impoundments upstream from this site to intercept sediment. Sediment yields at the remaining Little Cross Creek sites were low relative to yields reported from other urban basins in North Carolina. Downstream from Kornbow Lake, yields of suspended sediment (9.50 tons per square mile per year) and total phosphorus (0.011 ton per square mile per year) were very low. Clark Pond Creek had the highest yields ot total phosphorus (0.081 ton per square mile per year) and total organic carbon (11.5 tons per square mile per year). However, total phosphorus yields at all of the Little Cross Creek sites generally were lower than yields measured in other urban basins in the State. Comparison of inflow and outflow loads for the four Little Cross Creek reservoirs from October 1996 through September 1997 indicated that Bonnie Doone Lake trapped 92 percent of incoming sediment and 37 percent of incoming total phosphorus. Kornbow Lake trapped 57 percent of incoming sediment and 77 percent of total phosphorus inputs. Nitrogen was not effectively trapped by any of the reservoirs. An influx of sediment, total phosphorus, and total organic carbon was noted at a site downstream from Mintz Pond, and may have resulted from stormwater discharge from the U.S. Highway 401 bypass or from additional, unidentified sources in the watershed downstream from Kornbow Lake.

Multi-scale landscape factors influencing stream water quality in the state of Oregon.

PubMed

Nash, Maliha S; Heggem, Daniel T; Ebert, Donald; Wade, Timothy G; Hall, Robert K

2009-09-01

Enterococci bacteria are used to indicate the presence of human and/or animal fecal materials in surface water. In addition to human influences on the quality of surface water, a cattle grazing is a widespread and persistent ecological stressor in the Western United States. Cattle may affect surface water quality directly by depositing nutrients and bacteria, and indirectly by damaging stream banks or removing vegetation cover, which may lead to increased sediment loads. This study used the State of Oregon surface water data to determine the likelihood of animal pathogen presence using enterococci and analyzed the spatial distribution and relationship of biotic (enterococci) and abiotic (nitrogen and phosphorous) surface water constituents to landscape metrics and others (e.g. human use, percent riparian cover, natural covers, grazing, etc.). We used a grazing potential index (GPI) based on proximity to water, land ownership and forage availability. Mean and variability of GPI, forage availability, stream density and length, and landscape metrics were related to enterococci and many forms of nitrogen and phosphorous in standard and logistic regression models. The GPI did not have a significant role in the models, but forage related variables had significant contribution. Urban land use within stream reach was the main driving factor when exceeding the threshold (> or =35 cfu/100 ml), agriculture was the driving force in elevating enterococci in sites where enterococci concentration was <35 cfu/100 ml. Landscape metrics related to amount of agriculture, wetlands and urban all contributed to increasing nutrients in surface water but at different scales. The probability of having sites with concentrations of enterococci above the threshold was much lower in areas of natural land cover and much higher in areas with higher urban land use within 60 m of stream. A 1% increase in natural land cover was associated with a 12% decrease in the predicted odds of having a site exceeding the threshold. Opposite to natural land cover, a one unit change in each of manmade barren and urban land use led to an increase of the likelihood of exceeding the threshold by 73%, and 11%, respectively. Change in urban land use had a higher influence on the likelihood of a site exceeding the threshold than that of natural land cover.

A Tool for Assessing Future Capacity Loss Due to Sedimentation in the United States' Reservoirs

NASA Astrophysics Data System (ADS)

Pinson, A. O.; Baker, B.; White, K. D.

2017-12-01

Federal reservoirs are critical components of the United States' water supply, flood risk management, hydropower and navigation infrastructure. These reservoirs included capacity for storage loss due to the deposition of sediment by inflowing streams in their original design. However, the actual rate of capacity loss experienced is controlled in part by climate, topography, soils, and land use/land cover, and may vary from the design. To assess the current and future vulnerability of its reservoirs to sedimentation. USACE has developed an online planning tool to identify USACE reservoirs where sedimentation is currently a problem (e.g., sedimentation rate exceeds design sedimentation rate, or zone losses disproportionately affect authorized purposes), and reservoirs where rates are expected to increase significantly in the future. The goal is to be able to prioritize operation and maintenance actions to minimize the effects of reservoir capacity loss on authorized purposes and help maximize reservoir use life.

Use of sediment quality guidelines

USGS Publications Warehouse

Wenning, R. J.; Batley, G. E.; Ingersoll, Christopher G.; Moore, David W.

2005-01-01

Are sediment quality guidelines (SQGs) adequately able to predict the presence or absence of chronic toxicity to sediment-dwelling organisms in field-collected sediments? Can SQGs predict effects resulting from the bioaccumulation of sediment-associated contaminants? Do SQGs define cause-and-effect relationships? Can they predict effects on organisms exposed in the field on the basis of amphipod mortality measured in the laboratory?These and other questions brought together 55 scientists from 8 countries for a Pellston Workshop convened by the Society of Environmental Toxicology and Chemistry (SETAC) in Fairmont, Montana, USA. In this book, these experts in ecology, ecotoxicology, engineering, environmental regulation, and risk assessment examine the scientific underpinnings of sediment quality guidelines and provide recommendations on the appropriate use of SQGs in the assessment and management of contaminated sediments.

STORAGE DURATION AND TEMPERATURE AND THE ACUTE TOXICITIES OF ESTUARINE SEDIMENTS TO MYSIDOPSIS BAHIA AND LEPTOCHEIRUS PLUMULOSUS.

EPA Science Inventory

Many statutory needs for sediment quality assessment exist (U.S. EPA 1996). A variety of sediment toxicity tests have been used to support the development of sediment quality guidelines and to determine the benthic impacts of dredging activities and point and non-point source tox...

STORAGE DURATION AND TEMPERATURE AND THE ACUTE TOXICITIES OF ESTUARINE SEDIMENTS TO MYSIDOPSIS BAHIA AND LEPTOCHEIRUS PLUMULOSUS

EPA Science Inventory

Many statutory needs for sediment quality assessment exist (U.S. EPA 1996). A variety of sediment toxicity tests have been used to support the development of sediment quality guidelines and to determine the benthic impacts of dredging activities and point and non-point source tox...

Water-quality assessment of part of the Upper Mississippi River Basin Study Unit, Minnesota and Wisconsin- Nutrients, chlorophyll a, phytoplankton, and suspended sediment in streams, 1996-98

USGS Publications Warehouse

Kroening, Sharon E.; Lee, Kathy E.; Goldstein, R.M.

2003-01-01

The greatest chlorophyll-a concentrations and algal abundances generally were measured in the Little Cobb River near Beauford, Minnesota; Minnesota River near Jordan, Minnesota; Mississippi River at Hastings, Minnesota; and the Mississippi River at Red Wing, Minnesota. Greater concentrations and algal abundances at these sites may have been the result of increased nitrogen and phosphorus concentrations. Total phosphorus concentrations at these sites most frequently exceeded the goal of 0.1 mg/L set by the USEPA to prevent eutrophication. Phytoplankton communities at these sites primarily were dominated by blue-green algae during the summer of 1996. In contrast, at most of the other sites, the phytoplankton community was dominated by diatoms.

Predictions and Observations of Munitions Burial Under Intense Storm Waves at Duck, NC

NASA Astrophysics Data System (ADS)

Calantoni, J.; Klammer, H.; Sheremet, A.

2017-12-01

The fate of munitions or unexploded ordnance (UXO) resting on a submarine sediment bed is a critical safety concern. Munitions may remain in place or completely disappear for significant but unknown periods, after becoming buried in the sediment bed. Clearly, burial of munitions drastically complicates the detection and removal of potential threats. Here, we present field data of wave height and surrogate munitions burial depths near the 8-m isobath at the U.S. Army Corps of Engineers, Field Research Facility, Duck, North Carolina, observed between January and March 2015. The experiment captured a remarkable sequence of storms that included at least 10 events, of which 6 were characterized by wave fields of significant heights exceeding 2 m and with peak periods of approximately 10 s. During the strongest storm, waves of 14 s period and heights exceeding 2 m were recorded for more than 3 days; significant wave height reached 5 m at the peak of activity. At the end of the experiment, divers measured munition burial depths of up to 60 cm below the seabed level. However, the local bathymetry showed less than 5 cm variation between the before and after-storm states, suggesting the local net sediment accumulation / loss was negligible. The lack of bathymetric variability strongly suggests that the munitions sank into the bed, which would suggest an extreme state of sand agitation during the storm. We explore existing analytical solutions for the dynamic interaction between waves and sediment to predict munitions burial depths. Measured time series of wave pressure near the sediment bed were converted into wave-induced changes in pore pressures and the effective stress states of the sediment. Different sediment failure criteria based on minimum normal and maximum shear stresses were then applied to evaluate the appropriateness of individual failure criteria to predict observed burial depths. Results are subjected to a sensitivity analysis with respect to uncertain sediment parameters and summarized by representing cumulative failure times as a function of depth.

Phosphorus losses from agricultural land to natural waters are reduced by immobilization in iron-rich sediments of drainage ditches.

PubMed

Baken, Stijn; Verbeeck, Mieke; Verheyen, Dries; Diels, Jan; Smolders, Erik

2015-03-15

Redox reactions involving iron (Fe) strongly affect the mobility of phosphorus (P) and its migration from agricultural land to freshwater. We studied the transfer of P from groundwater to open drainage ditches in an area where, due to Fe(II) rich groundwater, the sediments of these ditches contain accumulated Fe oxyhydroxides. The average P concentrations in the groundwater feeding two out of three studied drainage ditches exceeded environmental limits for freshwaters by factors 11 and 16, but after passing through the Fe-rich sediments, the P concentrations in the ditch water were below these limits. In order to identify the processes which govern Fe and P mobility in these systems, we used diffusive equilibration in thin films (DET) to measure the vertical concentration profiles of P and Fe in the sediment pore water and in the ditchwater. The Fe concentrations in the sediment pore water ranged between 10 and 200 mg L(-1) and exceeded those in the inflowing groundwater by approximately one order of magnitude, due to reductive dissolution of Fe oxyhydroxides in the sediment. The dissolved P concentrations only marginally increased between groundwater and sediment pore water. In the poorly mixed ditchwater, the dissolved Fe concentrations decreased towards the water surface due to oxidative precipitation of fresh Fe oxyhydroxides, and the P concentrations decreased more sharply than those of Fe. These observations support the view that the dynamics of Fe and P are governed by reduction reactions in the sediment and by oxidation reactions in the ditchwater. In the sediment, reductive dissolution of P-containing Fe oxyhydroxides causes more efficient solubilization of Fe than of P, likely because P is buffered by adsorption on residual Fe oxyhydroxides. Conversely, in the ditchwater, oxidative precipitation causes more efficient immobilization of P than of Fe, due to ferric phosphate formation. The combination of these processes yields a natural and highly efficient sink for P. It is concluded that, in Fe-rich systems, the fate of P at the sediment-water interface is determined by reduction and oxidation of Fe. Copyright © 2015 Elsevier Ltd. All rights reserved.

Water-quality data for the Clark Fork and selected tributaries from Deer Lodge to Milltown, Montana, March 1985 through June 1986

USGS Publications Warehouse

Lambing, J.H.

1987-01-01

A sampling program was conducted at six stream sites. The purpose of the study was to collect baseline data on concentrations of suspended sediment and selected trace metals in streamflow. Included in this report are tables of daily data for mean streamflow, suspended sediment concentration, and suspended sediment discharge at two streamflow gaging stations on the Clark Fork; periodic data for instantaneous streamflow, onsite water quality, and trace metal and suspended sediment concentrations in the Clark Fork and tributaries; and summary statistics for all the water quality data. Also included are graphs for each site showing median concentrations of trace metals, relationship of concentrations of trace metals to suspended sediment, and median concentrations of trace metals in suspended sediments. Hydrographs for two sites on the main stem show daily mean streamflow, suspended sediment concentration, and suspended sediment discharge for the period of study. (Author 's abstract)

Development of a hybrid pollution index for heavy metals in marine and estuarine sediments.

PubMed

Brady, James P; Ayoko, Godwin A; Martens, Wayde N; Goonetilleke, Ashantha

2015-05-01

Heavy metal pollution of sediments is a growing concern in most parts of the world, and numerous studies focussed on identifying contaminated sediments by using a range of digestion methods and pollution indices to estimate sediment contamination have been described in the literature. The current work provides a critical review of the more commonly used sediment digestion methods and identifies that weak acid digestion is more likely to provide guidance on elements that are likely to be bioavailable than other traditional methods of digestion. This work also reviews common pollution indices and identifies the Nemerow Pollution Index as the most appropriate method for establishing overall sediment quality. Consequently, a modified Pollution Index that can lead to a more reliable understanding of whole sediment quality is proposed. This modified pollution index is then tested against a number of existing studies and demonstrated to give a reliable and rapid estimate of sediment contamination and quality.

Sediment transport and deposition in the lower Missouri River during the 2011 flood

USGS Publications Warehouse

Alexander, Jason S.; Jacobson, Robert B.; Rus, David L.

2013-01-01

Floodwater in the Missouri River in 2011 originated in upper-basin regions and tributaries, and then travelled through a series of large flood-control reservoirs, setting records for total runoff volume entering all six Missouri River main-stem reservoirs. The flooding lasted as long as 3 months. The U.S Geological Survey (USGS) examined sediment transport and deposition in the lower Missouri River in 2011 to investigate how the geography of floodwater sources, in particular the decanting effects of the Missouri River main-stem reservoir system, coupled with the longitudinal characteristics of civil infrastructure and valley-bottom topography, affected sediment transport and deposition in this large, regulated river system. During the flood conditions in 2011, the USGS, in cooperation with the U.S. Army Corps of Engineers, monitored suspended-sediment transport at six primary streamgages along the length of the lower Missouri River. Measured suspended-sediment concentration (SSC) in the lower Missouri River varied from approximately 150 milligrams per liter (mg/L) to 2,000 mg/L from January 1 to September 30, 2011. Median SSC increased in the downstream direction from 355 mg/L at Sioux City, Iowa, to 490 mg/L at Hermann, Missouri. The highest SSCs were measured downstream from Omaha, Nebraska, in late February when snowmelt runoff from tributaries, which were draining zones of high-sediment production, was entering the lower Missouri River, and releases of water at Gavins Point Dam were small. The combination of dilute releases of water at Gavins Point Dam and low streamflows in lower Missouri River tributaries caused sustained lowering of SSC at all streamgages from early July through late August. Suspended-sediment ranged from 5 percent washload (PW; percent silt and clay) to as much as 98 percent in the lower Missouri River from January 1 to September 30, 2011. Median PW increased in the downstream direction from 24 percent at Sioux City, Iowa, to 78 percent at Hermann, Missouri. Measurements made in early January, when SSC was low, indicate that suspended sediment mostly was composed of bed material, but by mid-February, runoff from the plains caused PW to increase at most streamgages. Total suspended-sediment discharge (SSD) during water year 2011 at the selected streamgages in the lower Missouri River ranged from approximately 29 to 64 million tons. Total estimated SSD had the lowest exceedance frequencies in the reaches between Gavins Point Dam and Nebraska City, Nebraska, but exceedance frequencies increased substantially downstream. In 2011, total SSD with low exceedance frequencies were reported at Sioux City, Iowa, Omaha, Nebraska, and Nebraska City, Nebraska, despite moderate-to-high exceedance frequencies for annual average SSC, indicating that the duration of high-magnitude flooding was the primary driver of total SSD. Comparison of median SSC for samples from water year 2011 with samples in the 20 years prior indicated that median SSC for high-action streamflows (streamflows likely to produce a stage exceeding the National Weather Service’s “action stage”) in 2011 were lower than those typical for high-action streamflows. Multiple-comparison analysis indicated that median SSC values for low-action streamflows (streamflows likely to produce stages lower than the National Weather Service’s “action stage”) and high-action streamflows sampled in 2011 at 4 of 6 streamgages were not significantly distinguishable from median SSC values for low-action streamflows in the previous 20 years. Longitudinal comparison of streamflow and SSD exceedance frequencies for 2011 with corresponding frequencies for 2008 and 1993 indicated the important role of tributary contributions to total SSD in the lower Missouri River. In 1993 and 2008, tributaries were the primary source of floodwater in the lower Missouri River, which resulted in a 20-fold increase in total SSD from Sioux City, Iowa, to Hermann, Missouri. In 2011, releases at Gavins Point Dam were the primary source of floodwater in the lower Missouri River, and total SSD at Hermann, Missouri, was only twice that estimated for Sioux City, Iowa. Sand deposition was estimated using analysis of multispectral satellite imagery collected in October and November 2011. Distributions of sand in the flood plain of the lower Missouri River also were quantified in relation to distance from the banks of the main channel for seven discrete river segments bounded by Gavins Point Dam and selected downstream tributaries. The areal extent of overbank flooding and flood-plain sand deposits increased downstream from Sioux City, Iowa to a broad peak near Rulo, Nebraska, and then decreased to levels near the lower limit of quantification downstream from Kansas City, Missouri. Most of the flood plain inundation and sediment-deposition damage to agricultural fields was observed between river miles 480 and 700, where 2011 peak streamflows had low exceedance frequencies, and the lower Missouri River channel was less incised or had aggraded recently. As channel capacity increased in the downstream direction, the relative magnitude of the flood decreased downstream, and overbank flooding was less extensive. In the constricted reaches, flood-plain sand deposits mainly were observed in association with levee breaks.

Water-quality, bed-sediment, and biological data (October 1993 through September 1994) and statistical summaries of data for streams in the Upper Clark Fork basin, Montana

USGS Publications Warehouse

Lambing, J.H.; Hornberger, Michelle I.; Axtmann, E.V.; Dodge, K.A.

1995-01-01

Water, bed sediment, and biota were sampled in streams from Butte to below Missoula as part of a program to characterize aquatic resources in the upper Clark Fork basin of western Montana. Water- quality data were obtained periodically at 16 stations during October 1993 through September 1994 (water year 1994); daily suspended-sediment data were obtained at six of these stations. Bed-sediment and biological data were obtained at 11 stations in August 1994. Sampling stations were located on the Clark Fork and major tributaries. The primary constituents analyzed were trace elements associated with mine tailings from historical mining and smelting activities. Water-quality data include concentrations of major ions, trace elements, and suspended sediment in samples collected periodically during water year 1994. Daily values of streamflow, suspended-sediment concentration, and suspended- sediment discharge are given for six stations. Bed- sediment data include trace-element concentrations in the fine and bulk fractions. Biological data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Quality-assurance data are reported for analytical results of water, bed sediment, and biota. Statistical summaries of bed sediment, and biological data are provided for the period of record at each station since 1985.

Toxicological assessment of aquatic ecosystems: application to watercraft contaminants in shallow water environments

USGS Publications Warehouse

Winger, P.V.; Kemmish, Michael J.

2002-01-01

Recreational boating and personal watercraft use have the potential to adversely impact shallow water systems through contaminant release and physical disturbance of bottom sediments. These nearshore areas are often already degraded by surface runoff, municipal and industrial effluents, and other anthropogenic activities. For proper management, information is needed on the level of contamination and environmental quality of these systems. A number of field and laboratory procedures can be used to provide this much needed information. Contaminants, such as metals, pesticides, polychlorinated biphenyls and polycyclic aromatic hydrocarbons, entering aquatic environments generally attach to particulate matter that eventually settles and becomes incorporated into the bottom sediments. Because bottom sediments serve as a sink and as a source for contaminants, environmental assessments generally focus on this matrix. While contaminant residues in sediments and sediment pore waters can reflect environmental quality, characteristics of sediment (redox potential, sediment/pore-water chemistry, acid volatile sulfides, percent organic matter, and sediment particle size) influence their bioavailability and make interpretation of environmental significance difficult. Comparisons of contaminant concentrations in pore water (interstitial water) and sediment with water quality criteria and sediment quality guidelines, respectively, can provide insight into potential biological effects. Laboratory bioaccumulation studies and residue concentrations in resident or caged biota also yield information on potential biological impacts. The usefulness of these measurements may increase as data are developed relating in-situ concentrations, tissue residue levels, and biological responses. Exposure of test organisms in situ or to field-collected sediment and pore water are additional procedures that can be used to assess the biological effects of contaminants. A battery of tests using multi-species and/or various life stages with different sensitivities to contaminants may offer a more conservative assessment of toxicity than single species testing. Using a ?weight of evidence? approach, the Sediment Quality Trial produces a robust evaluation of habitat quality and includes a measure of contaminant concentrations in the sediment, an assessment of sediment/pore-water toxicity to laboratory animals, and an evaluation of in situ biological assemblages. Field and laboratory procedures are available that can be used to ascertain habitat quality, identify contaminants causing environmental degradation and delineate aquatic systems requiring mitigation of protective efforts. These studies provide the scientific data that are integral to developing an environmental risk assessment of contaminants from watercraft use in shallow water systems.

Water-Quality, Bed-Sediment, and Biological Data (October 2005 through September 2006) and Statistical Summaries of Long-Term Data for Streams in the Clark Fork Basin, Montana

USGS Publications Warehouse

Dodge, Kent A.; Hornberger, Michelle I.; Dyke, Jessica

2007-01-01

Water, bed sediment, and biota were sampled in streams from Butte to below Milltown Reservoir as part of a long-term monitoring program in the upper Clark Fork basin; additional water-quality samples were collected in the Clark Fork basin from sites near Milltown Reservoir downstream to near the confluence of the Clark Fork and Flathead River as part of a supplemental sampling program. The sampling programs were conducted in cooperation with the U.S. Environmental Protection Agency to characterize aquatic resources in the Clark Fork basin of western Montana, with emphasis on trace elements associated with historic mining and smelting activities. Sampling sites were located on the Clark Fork and selected tributaries. Water-quality samples were collected periodically at 22 sites from October 2005 through September 2006. Bed-sediment and biological samples were collected once at 12 sites during August 2006. This report presents the analytical results and quality-assurance data for water-quality, bed-sediment, and biota samples collected at all long-term and supplemental monitoring sites from October 2005 through September 2006. Water-quality data include concentrations of selected major ions, trace ele-ments, and suspended sediment. Nutrients also were analyzed in the supplemental water-quality samples. Daily values of suspended-sed-iment concentration and suspended-sediment discharge were determined for four sites, and seasonal daily values of turbidity were determined for four sites. Bed-sediment data include trace-ele-ment concentrations in the fine-grained fraction. Bio-logical data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Statistical summaries of long-term water-quality, bed-sediment, and biological data for sites in the upper Clark Fork basin are provided for the period of record since 1985.

Effects of Urbanization on Stream Water Quality in the City of Atlanta, Georgia, USA

NASA Astrophysics Data System (ADS)

Peters, N. E.

2009-05-01

A long-term stream water-quality monitoring network was established in the City of Atlanta (COA) during 2003 to assess baseline water-quality conditions and the effects of urbanization on stream water quality. Routine hydrologically-based manual stream sampling, including several concurrent manual point and equal width increment sampling, was conducted approximately 12 times per year at 21 stations, with drainage areas ranging from 3.7 to 232 km2. Eleven of the stations are real-time (RT) water-quality stations having continuous measures of stream stage/discharge, pH, dissolved oxygen, specific conductance, water temperature, and turbidity, and automatic samplers for stormwater collection. Samples were analyzed for field parameters, and a broad suite of water-quality and sediment-related constituents. This paper summarizes an evaluation of field parameters and concentrations of major ions, minor and trace metals, nutrient species (nitrogen and phosphorus), and coliform bacteria among stations and with respect to watershed characteristics and plausible sources from 2003 through September 2007. The concentrations of most constituents in the COA streams are statistically higher than those of two nearby reference streams. Concentrations are statistically different among stations for several constituents, despite high variability both within and among stations. The combination of routine manual sampling, automatic sampling during stormflows, and real-time water-quality monitoring provided sufficient information about the variability of urban stream water quality to develop hypotheses for causes of water-quality differences among COA streams. Fecal coliform bacteria concentrations of most individual samples at each station exceeded Georgia's water-quality standard for any water-usage class. High chloride concentrations occur at three stations and are hypothesized to be associated with discharges of chlorinated combined sewer overflows, drainage of swimming pool(s), and dissolution and transport during rainstorms of CaCl2, a deicing salt applied to roads during winter storms. Water quality of one stream was highly affected by the dissolution and transport of ammonium alum [NH4Al(SO4)2] from an alum manufacturing plant in the watershed; streamwater has low pH (<5), low alkalinity and high concentrations of minor and trace metals. Several trace metals (Cu, Pb and Zn) exceed acute and chronic water-quality standards and the high concentrations are attributed to washoff from impervious surfaces.

Water-quality data (October 1988 through September 1989) and statistical summaries (March 1985 through September 1989) for the Clark Fork and selected tributaries from Galen to Missoula, Montana

USGS Publications Warehouse

Lambing, J.H.

1990-01-01

Water quality sampling was conducted at eight sites on the Clark Fork and selected tributaries from Galen to Missoula, from October 1988 through September 1989. This report presents tabulations and statistical summaries of the water quality data. Included are tabulations of streamflow, onsite water quality, and concentrations of trace elements and suspended sediment for periodic samples. Also included are tables and hydrographs of daily mean values for streamflow, suspended-sediment concentration, and suspended-sediment discharge at three mainstem stations and one tributary. Statistical summaries are presented for periodic water quality data collected from March 1985 through September 1989. Selected data are illustrated by graphs showing median concentrations of trace elements in water, relation of trace-element concentrations to suspended-sediment concentrations, and median concentrations of trace elements in suspended sediment. (USGS)

Water-quality data (October 1987 through September 1988) and statistical summaries (March 1985 through September 1988) for the Clark Fork and selected tributaries from Galen to Missoula, Montana

USGS Publications Warehouse

Lambing, John H.

1989-01-01

Water quality sampling was conducted at eight sites on the Clark Fork and selected tributaries from Galen to Missoula, Mont., from October 1987 through September 1988. This report presents tabulations and statistical summaries of the water quality data. Included in this report are tabulations of streamflow, onsite water quality, and concentrations of trace elements and suspended sediment for periodic samples. Also included are tables and hydrographs of daily mean values for streamflow, suspended-sediment concentration, and suspended-sediment discharge at three mainstream stations and one tributary. Statistical summaries are presented for periodic water quality data collected from March 1985 through September 1988. Selected data are illustrated by graphs showing median concentrations of trace elements in water, relation of trace element concentrations to suspended-sediment concentrations, and median concentrations of trace elements in suspended sediments. (USGS)

30 CFR 715.14 - Backfilling and grading.

Code of Federal Regulations, 2011 CFR

2011-07-01

... configuration and the outslopes of the plateau shall not exceed 1v:2h, except where engineering data... land use or may result in additional erosion and sedimentation. (j) Covering coal and acid-forming...

An Integrated Assessment of Sediment Remediation in a Midwestern U.S. Stream Using Sediment Chemistry, Water Quality, Bioassessment and Fish Biomarkers

EPA Science Inventory

A comprehensive biological, sediment and water quality study of the lower Little Scioto River near Marion, Ohio, USA was undertaken in July 2007 to evaluate the effectiveness of removal of creosote-contaminated sediment. The study area covered 7.5 river miles (RMs) of the river, ...

Evaluation of Pollution Level in Zolotoy Rog Bay (Peter the Great Gulf, the Sea of Japan)

NASA Astrophysics Data System (ADS)

Kazachkova, Y.; Lazareva, L.; Petukhov, V.

2017-11-01

The results of the hydrochemical research of water and bottom sediments of the Zolotoy Rog Bay in July 2015 are presented below. It is shown that, as a result of a large amount of polluted sewage entering The Zolotoy Rog Bay, the concentrations of organic substances (BOD5) and petroleum hydrocarbons in the water exceed the MPC. The concentrations of heavy metals in soils exceed both the background level and the level of permissible values. As a result of the calculation of the bottom accumulation (CBA) coefficient for oil hydrocarbons, the situation in the Zolotoy Rog Bay can be classified as an ecological disaster. According to the total pollution index (Zc) of heavy metals, the bottom sediments of the Zolotoy Rog Bay are characterized as strongly and very strongly polluted.

Arsenic in the health of ecosystems: spatial distribution in water, sediment and aquatic biota of Pampean streams.

PubMed

Rodríguez Castro, M C; Marcó P, L; Ranieri, M C; Vázquez, C; Giorgi, A

2017-10-07

A survey of arsenic and phosphorus in Pampean streams of Buenos Aires province was performed. Nitrates and ammonia were also determined. Stream water was sampled as well as stream sediment and filamentous algae. Results show that 32 streams exceeded the arsenic recommended guidelines for human consumption of 10 μg L -1 and six exceeded recommended values for aquatic organisms' protection of 50 μg L -1 . The average concentration found was 36.54 μg L -1 and areas with more concentration of As are located in the southern region of the province, in streams that are tributaries of the Atlantic Ocean. Other regions with high As concentration are the Matanza River tributaries and the Arrecifes River tributaries. No differences of As concentration was found between stream sediments. Also, no seasonal pattern of As concentration was observed in one stream sampled during a year, but a positive correlation between As and the conductivity (p = 0.0002) and pH (p = 0.01) of the streams was found. Also, As bioaccumulation was detected for all the algae sampled, but no correlation between As accumulated and As in the stream water was found. Ammonia levels exceeded recommended guidelines for human consumption in the Argentinean law in 30 streams. The characterization performed in this study provides relevant information on the distribution of arsenic and its origin and mobility.

Geochemistry of polycyclic aromatic hydrocarbons in the bottom sediments of the eastern Arctic shelf

NASA Astrophysics Data System (ADS)

Petrova, V. I.; Batova, G. I.; Kursheva, A. V.; Litvinenko, I. V.; Savinov, V. M.; Savinova, T. N.

2008-04-01

Sources and pathways of supply of polycyclic aromatic hydrocarbons (PAH) in the surface sediments of the Laptev and East Siberian seas were identified based on an analysis of the lithological-geochemical characteristics and distribution of organic matter (OM). The distribution of organic carbon, humic acids, bitumoids, and hydrocarbons demonstrates the determining role of the riverine runoff in the formation of the recent sediments. The total average content of PAH in the sediments of this region approximates 37 ng/g, not exceeding 80 ng/g of dry sediment. The biogenic components of the PAH (alkylphenanthrenes, alkylchrysenes, perylene) dominate in the estuarine-shelf and coastal-shelf sediments enriched with plant detritus and significantly decrease in the pelagic zone. The anthropogenic influence is observed in sediments of the port of Tiksi, where the total content of PAH with dominant pyrogenic components is two orders of magnitude higher as compared with the background values in the study region.

Nitrogen deposition effects on diatom communities in lakes from three National Parks in Washington State

USGS Publications Warehouse

Sheibley, Richard W.; Enache, Mihaela; Swarzenski, Peter W.; Moran, Patrick W.; Foreman, James R.

2014-01-01

The goal of this study was to document if lakes in National Parks in Washington have exceeded critical levels of nitrogen (N) deposition, as observed in other Western States. We measured atmospheric N deposition, lake water quality, and sediment diatoms at our study lakes. Water chemistry showed that our study lakes were ultra-oligotrophic with ammonia and nitrate concentrations often at or below detection limits with low specific conductance (−1 year−1 and were variable both within and across the parks. Diatom assemblages in a single sediment core from Hoh Lake (Olympic National Park) displayed a shift to increased relative abundances of Asterionella formosa and Fragilaria tenera beginning in the 1969–1975 timeframe, whereas these species were not found at the remaining (nine) sites. These diatom species are known to be indicative of N enrichment and were used to determine an empirical critical load of N deposition, or threshold level, where changes in diatom communities were observed at Hoh Lake. However, N deposition at the remaining nine lakes does not seem to exceed a critical load at this time. At Milk Lake, also in Olympic National Park, there was some evidence that climate change might be altering diatom communities, but more research is needed to confirm this. We used modeled precipitation for Hoh Lake and annual inorganic N concentrations from a nearby National Atmospheric Deposition Program station, to calculate elevation-corrected N deposition for 1980–2009 at Hoh Lake. An exponential fit to this data was hindcasted to the 1969–1975 time period, and we estimate a critical load of 1.0 to 1.2 kg N ha−1 year−1 for wet deposition for this lake.

Toxicity assessment of sediments from the Grand Calumet River and Indiana Harbor Canal in northwestern Indiana, USA

USGS Publications Warehouse

Ingersoll, C.G.; MacDonald, D.D.; Brumbaugh, W.G.; Johnson, B. Thomas; Kemble, N.E.; Kunz, J.L.; May, T.W.; Wang, N.; Smith, J.R.; Sparks, D.W.; Ireland, D.S.

2002-01-01

The objective of this study was to evaluate the toxicity of sediments from the Grand Calumet River and Indiana Harbor Canal located in northwestern Indiana, USA. Toxicity tests used in this assessment included 10-day sediment exposures with the amphipod Hyalella azteca, 31-day sediment exposures with the oligochaete Lumbriculus variegatus, and the Microtox® Solid-Phase Sediment Toxicity Test. A total of 30 sampling stations were selected in locations that had limited historic matching toxicity and chemistry data. Toxic effects on amphipod survival were observed in 60% of the samples from the assessment area. Results of a toxicity test with oligochaetes indicated that sediments from the assessment area were too toxic to be used in proposed bioaccumulation testing. Measurement of amphipod length after the 10-day exposures did not provide useful information beyond that provided by the survival endpoint. Seven of the 15 samples that were identified as toxic in the amphipod tests were not identified as toxic in the Microtox test, indicating that the 10-day H. azteca test was more sensitive than the Microtox test. Samples that were toxic tended to have the highest concentrations of metals, polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyls (PCBs). The toxic samples often had an excess of simultaneously extracted metals (SEM) relative to acid volatile sulfide (AVS) and had multiple exceedances of probable effect concentrations (PECs). Metals may have contributed to the toxicity of samples that had both an excess molar concentration of SEM relative to AVS and elevated concentrations of metals in pore water. However, of the samples that had an excess of SEM relative to AVS, only 38% of these samples had elevated concentration of metals in pore water. The lack of correspondence between SEM-AVS and pore water metals indicates that there are variables in addition to AVS controlling the concentrations of metals in pore water. A mean PEC quotient of 3.4 (based on concentrations of metals, PAHs, and PCBs) was exceeded in 33% of the sediment samples and a mean quotient of 0.63 was exceeded in 70% of the thirty sediment samples from the assessment area. A 50% incidence of toxicity has been previously reported in a database for sediment tests with H. azteca at a mean quotient of 3.4 in 10-day exposures and at a mean quotient of 0.63 in 28-day exposures. Among the Indiana Harbor samples, most of the samples with a mean PEC quotient above 0.63 (i.e., 15 of 21; 71%) and above 3.4 (i.e., 10 of 10; 100%) were toxic to amphipods. Results of this study and previous studies demonstrate that sediments from this assessment area are among the most contaminated and toxic that have ever been reported.

Water-Quality, Bed-Sediment, and Biological Data (October 2006 through September 2007) and Statistical Summaries of Long-Term Data for Streams in the Clark Fork Basin, Montana

USGS Publications Warehouse

Dodge, Kent A.; Hornberger, Michelle I.; Dyke, Jessica

2008-01-01

Water, bed sediment, and biota were sampled in streams from Butte to below Milltown Reservoir as part of a long-term monitoring program in the upper Clark Fork basin; additional water-quality samples were collected in the Clark Fork basin from sites near Milltown Reservoir downstream to near the confluence of the Clark Fork and Flathead River as part of a supplemental sampling program. The sampling programs were conducted in cooperation with the U.S. Environmental Protection Agency to characterize aquatic resources in the Clark Fork basin of western Montana, with emphasis on trace elements associated with historic mining and smelting activities. Sampling sites were located on the Clark Fork and selected tributaries. Water-quality samples were collected periodically at 22 sites from October 2006 through September 2007. Bed-sediment and biological samples were collected once at 12 sites during August 2007. This report presents the analytical results and quality-assurance data for water-quality, bed-sediment, and biota samples collected at all long-term and supplemental monitoring sites from October 2006 through September 2007. Water-quality data include concentrations of selected major ions, trace elements, and suspended sediment. Turbidity was analyzed for samples collected at sites where seasonal daily values of turbidity were being determined. Nutrients also were analyzed in the supplemental water-quality samples. Daily values of suspended-sediment concentration and suspended-sediment discharge were determined for four sites, and seasonal daily values of turbidity were determined for five sites. Bed-sediment data include trace-element concentrations in the fine-grained fraction. Biological data include trace-element concentrations in whole-body tissue of aquatic benthic insects. Statistical summaries of long-term water-quality, bed-sediment, and biological data for sites in the upper Clark Fork basin are provided for the period of record since 1985.

Resiliency of the Chesapeake Bay to Pollution Levels Following Storms and Based on Land-Use

NASA Astrophysics Data System (ADS)

Hasan, M.; Pavelsky, T.

2015-12-01

As pollution levels, transformations in land use, and ecological loss continue to increase in the Chesapeake Bay, questions arise as to whether this estuary, the largest in North America, will experience a change in the duration and levels of storm-related sediment and nutrient spikes. We use a combination of satellite data and previously-collected field measurements to study this question. We compare same-day and same-pixel NASA MODIS satellite data to in situ observations of sediment and nutrient concentrations over 20 years, and found that for at least 6 tributaries, the r2 value for a linear regression between the satellite reflectance and fieldwork measures of nitrogen, phosphorus, or suspended sediment concentrations exceeded 0.7, while for at least 12 tributaries, the r2 value exceeded 0.5. We took advantage of this relationship to estimate sediment and nutrient concentrations in the Chesapeake following major storm events, even in the absence of continuous in situ data. We studied sediment/nutrient levels daily following the storm, for every date on which a cloud-free MODIS image was available, for a month. The storms included 2003's Hurricane Isabel, 2011's Hurricane Irene, and 2012's Superstorm Sandy. The tributaries we focused on were the York and Piankatank Rivers of southern Virginia (heavily forested), the Potomac River (heavily urban), and the Nanticoke River of the Eastern Shore (heavily farmed). Results show that in the Potomac River, which over the last 15 years has experience a signifiant increase in urbanization, sediments and nutrients persist for longer periods and at higher levels compared to less urbanized rivers.

Flood risk analysis for flood control and sediment transportation in sandy regions: A case study in the Loess Plateau, China

NASA Astrophysics Data System (ADS)

Guo, Aijun; Chang, Jianxia; Wang, Yimin; Huang, Qiang; Zhou, Shuai

2018-05-01

Traditional flood risk analysis focuses on the probability of flood events exceeding the design flood of downstream hydraulic structures while neglecting the influence of sedimentation in river channels on regional flood control systems. This work advances traditional flood risk analysis by proposing a univariate and copula-based bivariate hydrological risk framework which incorporates both flood control and sediment transport. In developing the framework, the conditional probabilities of different flood events under various extreme precipitation scenarios are estimated by exploiting the copula-based model. Moreover, a Monte Carlo-based algorithm is designed to quantify the sampling uncertainty associated with univariate and bivariate hydrological risk analyses. Two catchments located on the Loess plateau are selected as study regions: the upper catchments of the Xianyang and Huaxian stations (denoted as UCX and UCH, respectively). The univariate and bivariate return periods, risk and reliability in the context of uncertainty for the purposes of flood control and sediment transport are assessed for the study regions. The results indicate that sedimentation triggers higher risks of damaging the safety of local flood control systems compared with the event that AMF exceeds the design flood of downstream hydraulic structures in the UCX and UCH. Moreover, there is considerable sampling uncertainty affecting the univariate and bivariate hydrologic risk evaluation, which greatly challenges measures of future flood mitigation. In addition, results also confirm that the developed framework can estimate conditional probabilities associated with different flood events under various extreme precipitation scenarios aiming for flood control and sediment transport. The proposed hydrological risk framework offers a promising technical reference for flood risk analysis in sandy regions worldwide.

Sources and transport of sediment, nutrients, and oxygen-demanding substances in the Minnesota River basin, 1989-92

USGS Publications Warehouse

Payne, G.A.

1994-01-01

The Minnesota River, 10 major tributaries, and 21 springs were sampled to determine the sources and transport of sediment, nutrients, and oxygen- demanding substances. The study was part of a four-year assessment of non-point source pollution in the Minnesota River Basin. Runoff from tributary watersheds was identified as the primary source of suspended sediment and nutrients in the Minnesota River mainstem. Suspended-sediment, phosphorus, and nitrate concentrations were elevated in all major tributaries during runoff, but tributaries in the south-central and eastern part of the basin produce the highest annual loading to the mainstem because of higher annual precipitation and runoff in that part of the basin. Particle-size analyses showed that most of the suspended sediment in transport consisted of silt- and clay-size material. Phosphorus enrichment was indicated throughout the mainstem by total phosphorus concentrations that ranged from 0.04 to 0.48 mg/L with a median value of 0.22 mg/L, and an interquartile range of 0.15 to 0.29 mg/L. Nitrate concentrations periodically exceeded drinking water standards in tributaries draining the south-central and eastern part of the basin. Oxygen demand was most elevated during periods of summer low flow. Correlations between levels of biochemical oxygen demand and levels of algal productivity suggest that algal biomass comprises much of the oxygen-demanding material in the mainstem. Transport of sediment, nutrients, and organic carbon within the mainstem was found to be conservative, with nearly all tributary inputs being transported downstream. Uptake and utilization of nitrate and orthophosphorus was indicated during low flow, but at normal and high flow, inputs of these constituents greatly exceeded biological utilization.

Controls on subsurface methane fluxes and shallow gas formation in Baltic Sea sediment (Aarhus Bay, Denmark)

NASA Astrophysics Data System (ADS)

Flury, Sabine; Røy, Hans; Dale, Andrew W.; Fossing, Henrik; Tóth, Zsuzsanna; Spiess, Volkhard; Jensen, Jørn Bo; Jørgensen, Bo Barker

2016-09-01

Shallow gas accumulates in coastal marine sediments when the burial rate of reactive organic matter beneath the sulfate zone is sufficiently high and the methanogenic zone is sufficiently deep. We investigated the controls on methane production and free methane gas accumulation along a 400 m seismo-acoustic transect across a sharp transition from gas-free into gas-bearing sediment in Aarhus Bay (Denmark). Twelve gravity cores were taken, in which the pore water was analyzed for inorganic solutes while rates of organic carbon mineralization were measured experimentally by 35SO42- radiotracer method. The thickness of organic-rich Holocene mud increased from 5 to 10 m along the transect concomitant with a shallowing of the depth of the sulfate-methane transition from >4 m to 2.5 m. In spite of drastic differences in the distribution of methane and sulfate in the sediment along the transect, there were only small differences in total mineralization, and methanogenesis was only equivalent to about 1% of sulfate reduction. Shallow gas appeared where the mud thickness exceeded 8-9 m. Rates of methanogenesis increased along the transect as did the upward diffusive flux of methane. Interestingly, the increase in the sedimentation rate and Holocene mud thickness had only a modest direct effect on methanogenesis rates in deep sediments. This increase in methane flux, however, triggered a shallowing of the sulfate-methane transition which resulted in a large increase in methanogenesis at the top of the methanogenic zone. Thus, our results demonstrate a positive feedback mechanism that causes a strong enhancement of methanogenesis and explains the apparently abrupt appearance of gas when a threshold thickness of organic-rich mud is exceeded.

The Saguenay Fjord, Quebec, Canada: Integrating marine geotechnical and geophysical data for spatial seismic slope stability and hazard assessment

USGS Publications Warehouse

Urgeles, R.; Locat, J.; Lee, H.J.; Martin, F.

2002-01-01

In 1996 a major flood occurred in the Saguenay region, Quebec, Canada, delivering several km3 of sediment to the Saguenay Fjord. Such sediments covered large areas of the, until then, largely contaminated fjord bottom, thus providing a natural capping layer. Recent swath bathymetry data have also shown that sediment landslides are widely present in the upper section of the Saguenay Fjord, and therefore, should a new event occur, it would probably expose the old contaminated sediments. Landslides in the Upper Saguenay Fjord are most probably due to earthquakes given its proximity to the Charlevoix seismic region and to that of the 1988 Saguenay earthquake. In consequence, this study tries to characterize the permanent ground deformations induced by different earthquake scenarios from which shallow sediment landslides could be triggered. The study follows a Newmark analysis in which, firstly, the seismic slope performance is assessed, secondly, the seismic hazard analyzed, and finally an evaluation of the seismic landslide hazard is made. The study is based on slope gradients obtained from EM1000 multibeam bathymetry data as well as water content and undrained shear strength measurements made in box and gravity cores. Ground motions integrating local site conditions were simulated using synthetic time histories. The study assumes the region of the 1988 Saguenay earthquake as the most likely source area for earthquakes capable of inducing large ground motions in the Upper Saguenay region. Accordingly, we have analyzed several shaking intensities to deduce that generalized sediment displacements will begin to occur when moment magnitudes exceed 6. Major displacements, failure, and subsequent landslides could occur only from earthquake moment magnitudes exceeding 6.75. ?? 2002 Elsevier Science B.V. All rights reserved.

Application of dimensionless sediment rating curves to predict suspended-sediment concentrations, bedload, and annual sediment loads for rivers in Minnesota

USGS Publications Warehouse

Ellison, Christopher A.; Groten, Joel T.; Lorenz, David L.; Koller, Karl S.

2016-10-27

Consistent and reliable sediment data are needed by Federal, State, and local government agencies responsible for monitoring water quality, planning river restoration, quantifying sediment budgets, and evaluating the effectiveness of sediment reduction strategies. Heightened concerns about excessive sediment in rivers and the challenge to reduce costs and eliminate data gaps has guided Federal and State interests in pursuing alternative methods for measuring suspended and bedload sediment. Simple and dependable data collection and estimation techniques are needed to generate hydraulic and water-quality information for areas where data are unavailable or difficult to collect.The U.S. Geological Survey, in cooperation with the Minnesota Pollution Control Agency and the Minnesota Department of Natural Resources, completed a study to evaluate the use of dimensionless sediment rating curves (DSRCs) to accurately predict suspended-sediment concentrations (SSCs), bedload, and annual sediment loads for selected rivers and streams in Minnesota based on data collected during 2007 through 2013. This study included the application of DSRC models developed for a small group of streams located in the San Juan River Basin near Pagosa Springs in southwestern Colorado to rivers in Minnesota. Regionally based DSRC models for Minnesota also were developed and compared to DSRC models from Pagosa Springs, Colorado, to evaluate which model provided more accurate predictions of SSCs and bedload in Minnesota.Multiple measures of goodness-of-fit were developed to assess the effectiveness of DSRC models in predicting SSC and bedload for rivers in Minnesota. More than 600 dimensionless ratio values of SSC, bedload, and streamflow were evaluated and delineated according to Pfankuch stream stability categories of “good/fair” and “poor” to develop four Minnesota-based DSRC models. The basis for Pagosa Springs and Minnesota DSRC model effectiveness was founded on measures of goodness-of-fit that included proximity of the model(s) fitted line to the 95-percent confidence intervals of the site-specific model, Nash-Sutcliffe Efficiency values, model biases, and deviation of annual sediment loads from each model to the annual sediment loads calculated from measured data.Composite plots comparing Pagosa Springs DSRCs, Minnesota DSRCs, site-specific regression models, and measured data indicated that regionally developed DSRCs (Minnesota DSRC models) more closely approximated measured data for nearly every site. Pagosa Springs DSRC models had markedly larger exponents (slopes) when compared to the Minnesota DSRC models and the site-specific regression models, and over-represent SSC and bedload at streamflows exceeding bankfull. The Nash-Sutcliffe Efficiency values for the Minnesota DSRC model for suspended-sediment concentrations closely matched Nash-Sutcliffe Efficiency values of the site-specific regression models for 12 out of 16 sites. Nash-Sutcliffe Efficiency values associated with Minnesota DSRCs were greater than those associated with Pagosa Springs DSRCs for every site except the Whitewater River near Beaver, Minnesota site. Pagosa Springs DSRC models were less accurate than the mean of the measured data at predicting SSC values for one-half of the sites for good/fair stability sites and one-half of the sites for poor stability sites. Relative model biases were calculated and determined to be substantial (greater than 5 percent) for Pagosa Springs and Minnesota models, with Minnesota models having a lower mean model bias. For predicted annual suspended-sediment loads (SSL), the Minnesota DSRC models for good/fair and poor stream stability sites more closely approximated the annual SSLs calculated from the measured data as compared to the Pagosa Springs DSRC model.Results of data analyses indicate that DSRC models developed using data collected in Minnesota were more effective at compensating for differences in individual stream characteristics across a variety of basin sizes and flow regimes than DSRC models developed using data collected for Pagosa Springs, Colorado. Minnesota DSRC models retained a substantial portion of the unique sediment signatures for most rivers, although deviations were observed for streams with limited sediment supply and for rivers in southeastern Minnesota, which had markedly larger regression exponents. Compared to Pagosa Springs DSRC models, Minnesota DSRC models had regression slopes that more closely matched the slopes of site-specific regression models, had greater Nash-Sutcliffe Efficiency values, had lower model biases, and approximated measured annual sediment loads more closely. The results presented in this report indicate that regionally based DSRCs can be used to estimate reasonably accurate values of SSC and bedload.Practitioners are cautioned that DSRC reliability is dependent on representative measures of bankfull streamflow, SSC, and bedload. It is, therefore, important that samples of SSC and bedload, which will be used for estimating SSC and bedload at the bankfull streamflow, are collected over a range of conditions that includes the ascending and descending limbs of the event hydrograph. The use of DSRC models may have substantial limitations for certain conditions. For example, DSRC models should not be used to predict SSC and sediment loads for extreme streamflows, such as those that exceed twice the bankfull streamflow value because this constitutes conditions beyond the realm of current (2016) empirical modeling capability. Also, if relations between SSC and streamflow and between bedload and streamflow are not statistically significant, DSRC models should not be used to predict SSC or bedload, as this could result in large errors. For streams that do not violate these conditions, DSRC estimates of SSC and bedload can be used for stream restoration planning and design, and for estimating annual sediment loads for streams where little or no sediment data are available.

Factors affecting Escherichia coli concentrations at Lake Erie public bathing beaches

USGS Publications Warehouse

Francy, Donna S.; Darner, Robert A.

1998-01-01

The environmental and water-quality factors that affect concentrations of Escherichia coli (E. coli) in water and sediment were investigated at three public bathing beachesEdgewater Park, Villa Angela, and Sims Parkin the Cleveland, Ohio metropolitan area. This study was done to aid in the determination of safe recreational use and to help water- resource managers assess more quickly and accurately the degradation of recreational water quality. Water and lake-bottom sediments were collected and ancillary environmental data were compiled for 41 days from May through September 1997. Water samples were analyzed for E. coli concentrations, suspended sediment concentrations, and turbidity. Lake- bottom sediment samples from the beach area were analyzed for E. coli concentrations and percent dry weight. Concentrations of E. coli were higher and more variable at Sims Park than at Villa Angela or Edgewater Park; concentrations were lowest at Edgewater Park. Time-series plots showed that short-term storage (less than one week) of E. coli in lake-bottom sediments may have occurred, although no evidence for long-term storage was found during the sampling period. E. coli concentrations in water were found to increase with increasing wave height, but the resuspension of E. coli from lake-bottom sediments by wave action could not be adequately assessed; higherwave heights were often associated with the discharge of sewage containing E. coli during or after a rainfall and wastewater-treatment plant overflow. Multiple linear regression (MLR) was used to develop models to predict recreational water quality at the in water. The related variables included turbidity, antecedent rainfall, antecedent weighted rainfall, volumes of wastewater-treatment plant overflows and metered outfalls (composed of storm-water runoff and combined-sewer overflows), a resuspension index, and wave heights. For the beaches in this study, wind speed, wind direction, water temperature, and the prswimmers were not included in the model because they were shown to be statistically unrelated to E. coli concentrations. From the several models developed, one model was chosen that accounted for 58 percent of the variability in E. coli concentrations. The chosen MLR model contained weighted categorical rainfall, beach-specific turbidity, wave height, and terms to correct for the different magnitudes of E. coli concentrations among the three beaches. For 1997, the MLR model predicted the recreational water quality as well as, and in some cases better than, antecedent E. coli concentrations (the current method). The MLR model improved the sensitivity of the prediction and the percentage of correct predictions over the current method; however, the MLR model predictions still erred to a similar degree as the current method with regard to false negatives. A false negative would allow swimming when, in fact, the bathing water standard was exceeded. More work needs to be done to validate the MLR model with data collected during other recreational seasons, especially during a season with a greater frequency and intensity of summer rains. Studies could focus on adding to the MLR model other environmental and water-quality variables that improve the predictive ability of the model. These variables might include concentrations of E. coli in deeper sediments outside the bathing area, the direction of lake currents, site-specific-rainfall amounts, time-of-day information on overflows and metered outfalls, concentrations of E. coli in treated wastewater-treatment plant effluents, and occurrences of sewage-line breaks. Rapid biological or chemical methods for determination of recreational water quality could also be used as variables in model refinements. Possible methods include the use of experimental rapid assay methods for determination of E. coli concentrations or other fecal indicators and the use of chemical tracers for fecal contamination, such as coprostanol (a degradation

Environmental impact of the largest petroleum terminal in SE Brazil: A multiproxy analysis based on sediment geochemistry and living benthic foraminifera

PubMed Central

Duleba, Wânia; Teodoro, Andreia C.; Debenay, Jean-Pierre; Gubitoso, Silas; Pregnolato, Leonardo Antônio; Lerena, Laura Misailidis; Prada, Silvio Miranda; Bevilacqua, José Eduardo

2018-01-01

The Dutos e Terminais do Centro Sul (DTCS) is one of the largest petroleum terminals of the South America located in the São Sebastião Channel (SSC) on the southeastern Brazilian coast. The aims of this study were to compare the sediment quality near the DTCS with that of several sites in the SSC region including the Araçá (AR) domestic sewage outfall and to assess the efficiency of the DTCS wastewater treatment plant. To achieve these goals, textural, geochemical, and living benthic foraminifera results were analyzed for the DTCS, AR, and SSC regions. Sediments in the DTCS area were silty with high concentrations of total organic carbon (1.7–2.4%), total nitrogen (0.2–0.3%), total sulfur (0.4–0.6%), and total (0.12–0.18%) and inorganic phosphorous (0.07–0.11%). These values were higher than those in sediments collected in the SSC and Araçá regions. The sediments’ concentrations of As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn in the SSC and AR regions were lower than their corresponding probable effect levels (PELs). However, sediments near the DTCS were enriched with As, Cu, and Ni, whose concentrations exceeded their corresponding threshold effect levels (TELs). Around the DTCS outfall diffusers, living foraminiferal densities and diversities were lower than those for the other areas studied. In the DTCS area, it was necessary to search 50 to 190 cm3 of sediment to find 100 live specimens. In the SSC and Araçá areas, a maximum of 40 cm3 of sediment was enough to locate 100 live specimens. The lower density and diversity of living foraminifera around the DTCS than around the other areas illustrates the impact of the environmental stress caused by the presence of pollutants. These results indicate that the wastewater treatment plant efficiency is low and its discharge of pollutants from petrochemical waste liquids affects the benthic fauna around the DTCS in a potentially harmful manner. PMID:29432425

In vitro and in vivo toxicities of sediment and surface water in an area near a major steel industry of Korea: endocrine disruption, reproduction, or survival effects combined with instrumental analysis.

PubMed

Kim, Sunmi; Lee, Sangwoo; Kim, Cheolmin; Liu, Xiaoshan; Seo, Jihyun; Jung, Hyorin; Ji, Kyunghee; Hong, Seongjin; Park, Jinsoon; Khim, Jong Seong; Yoon, Seokmin; Lee, Woojin; Park, Jeongim; Choi, Kyungho

2014-02-01

The influence of industrial and/or municipal contaminant inputs on the aquatic environment of Pohang, Korea was investigated, with a focus on bioassay combined with instrumental analysis. Pohang is the most heavily populated city in Gyeongsangbuk-do province of Korea, with more than half a million residents, and also hosts the nation's biggest steel manufacturer and related industries. Sediment (n=15) and surface water samples (n=17) were collected from Hyeongsan River which runs across the Pohang city, in two separate events, i.e., June 2010 and February 2011. Sediment samples were first Soxhlet-extracted (raw extract) and were measured for estrogenicity using H295R cell line, and also analyzed for alkylphenols (APs), bisphenol A (BPA), PAHs, and PCBs. For sediment samples which exhibited greatest effects in the cell line, further fractionation was performed into non-polar, mid-polar, and polar portions. In surface water samples, heavy metals were also analyzed. Among 15 sediment samples, station S2 near the steel industry complex and station M3 near the municipal area showed the greatest sex hormone changes, and these changes were generally explained by the fractions which contained APs and BPA. Principal component analysis (PCA) however suggests that chemicals that were not analyzed in the present study would better explain endocrine disruption capacity of sediments. In water samples, adverse effects on hatchability and growth of Japanese medaka fish, and on Daphnia reproduction were noted following exposure to six water samples collected from stations near industrial and municipal areas. Several heavy metals and nonylphenol (NP) concentrations exceeded surface water quality guidelines, suggesting adverse effects of contamination inputs from both industrial and municipal activities. Observed estrogenicities in stations such as S2 and M3 warrant further investigations on longer term ecosystem impacts near industrial and municipal areas. The levels of major organic chemicals in sediments are quite comparable to those reported in ~10 years ago, emphasizing a need for source control. © 2013 Elsevier B.V. All rights reserved.

A SURVEY OF CHEMICAL AND BIOLOGICAL STRUCTURE IN THREE FLORIDA BAYOU-ESTUARIES

EPA Science Inventory

Structural and functional characteristics of the benthic biota were determined and compared for three urbanized bayous, in conjuction with sediment chemical quality and acute toxicity. Sediment chemical contamination in the bayous was common. Numerical sediment quality assessmen...

Sediment quality assessment using survival and embryo malformation tests in amphipod crustaceans: The Gulf of Riga, Baltic Sea AS case study

NASA Astrophysics Data System (ADS)

Strode, Evita; Jansons, Mintauts; Purina, Ingrida; Balode, Maija; Berezina, Nadezhda A.

2017-08-01

The aim of this study was to assess the toxicity of bottom sediment and to estimate the potential effects of contaminated sediment on health of benthic organisms in the Gulf of Riga (eastern Baltic Sea). Two endpoints were used: survival rate (acute toxicity test) of five crustacean amphipod species and frequency of embryo malformation (samples were collected from the field) in the two species. Toxic resistance of living animals to sediment quality was measured as survival rate (%) at 25 study sites from 2010-2012. Significant differences in the toxic resistance between species were found: 80-100% for Monoporeia affinis, 70-95% for Corophium volutator, 38-88% for Pontogammarus robustoides, 38-100% for Bathyporeia pilosa and 60-100% for Hyalella azteca. Reproductive disorders, measured as percentage (%) of malformed embryos per female, varied in the ranges of 0.0-9.5% in deep water species M. affinis and 0.3-7.5% in littoral species P. robustoides. Both the acute toxicity test and embryo malformation test (only M. affinis was used) indicated moderate and poor sediment quality at 20% and 12% accordingly in the study sites, low toxicity of sediment was estimated in 64% of cases, and no toxicity was recorded in the rest of the cases (4%). Additionally, sediment toxicity test using aquatic organisms was combined with sediment chemical analysis (trace metals) and the Benthic Quality Index (macrozoobenthos) was based on data collected from 13 sites in the Gulf of Riga in 2010 and used for triad sediment quality assessment. According to this combined approach, 23% of the bottom sediments were classified as likely impacted and 23% as possibly impacted (central and southern part of the Gulf). However, the remaining 54% was identified as likely un-impacted. The sediment quality assessment with single survival test or chemical analyses showed better sediment quality in the Gulf than the triad method. The embryo malformation test appeared to be more sensitive to pollution than acute toxicity survival test, that allow us to recommend the inclusion of this novel biomarker in environmental monitoring, while combining it with other tests. In general, our results indicate good or moderate states of sediments and minimal effects of the toxic contamination in them on the Gulf of Riga ecosystem.

76 FR 72377 - Approval and Promulgation of Air Quality Implementation Plans; Connecticut; Determinations of...

Federal Register 2010, 2011, 2012, 2013, 2014

2011-11-23

... recorded in EPA's Air Quality System (AQS) database. To account for missing data, the procedures found in... Site Year exceedance exceedance expected days over days for exceedance 0.124 ppm missing data rate... for exceedance 0.124 ppm missing data rate 090050006 Cornwall........ 2006 0 0.0 0.3 2007 1 1.0 2008 0...

Ground-water quality, Cook Inlet Basin, Alaska, 1999

USGS Publications Warehouse

Glass, Roy L.

2001-01-01

As part of the U.S. Geological Survey?s National Water-Quality Assessment Program, ground-water samples were collected from 34 existing wells in the Cook Inlet Basin in south-central Alaska during 1999. All ground-water samples were from aquifers composed of glacial or alluvial sediments. The water samples were used to determine the occurrence and distribution of selected major ions, nutrients, trace elements, volatile organic compounds, pesticides, radioisotopes, and environmental isotopes. Of 34 samples, 29 were from wells chosen by using a grid-based random-selection process. Water samples from five major public-supply wells also were collected. Radon-222 and arsenic concentrations exceeded drinking-water standards proposed by the U.S. Environmental Protection Agency in 39 and 18 percent of sampled wells, respectively. The highest radon concentration measured during this study was 610 picocuries per liter; 12 of 31 samples exceeded the proposed maximum contaminant level of 300 picocuries per liter. The highest arsenic concentration was 29 micrograms per liter; 6 of 34 samples exceeded the proposed maximum contaminant level of 10 micrograms per liter. Human activities may be increasing the concen- tration of nitrate in ground water, but nitrate concentrations in all samples were less than the maximum contaminant level of 10 milligrams per liter as nitrogen. Concentrations of nitrate were highest in Anchorage and were as great as 4.8 milligrams per liter as nitrogen. Dissolved-solids concentrations ranged from 77 to 986 milligrams per liter; only 2 of 34 wells yielded water having greater than 500 milligrams per liter. Iron and manganese concentrations exceeded secondary maximum contaminant levels in 18 and 42 percent of samples, respectively. Concentrations of all pesticides and volatile organic compounds detected in ground-water samples were very low, less than 1 microgram per liter. No pesticide or volatile organic compounds were detected at concentrations exceeding drinking-water standards or guidelines. Water samples from one-half of the wells sampled had no detectable concentrations of pesticides or volatile organic carbons, at the parts-per-billion level. Concentrations of stable isotopes of hydrogen and oxygen in ground-water samples were similar to concentrations expected for modern precipitation and for water that has been affected by evaporation. Tritium activities and concentrations of chlorofluorocarbons indicated that the water samples collected from most wells were recharged less than 50 years ago.

Dioxin in the Elbe river basin: policy and science under the water framework directive 2000-2015 and toward 2021.

PubMed

Förstner, Ulrich; Hollert, Henner; Brinkmann, Markus; Eichbaum, Kathrin; Weber, Roland; Salomons, Wim

2016-01-01

A critical review of the last 25 years of dioxin policy in the Elbe river catchment is presented along seven main theses of the River Basin Community (RBC)-Elbe background document "Pollutants" for the Management Plan 2016-2021. In this period, polychlorinated dibenzodioxins/-furans (PCDD/Fs) and dioxin-like polychlorinated biphenyls (dl-PCBs) will play a major role: (i) as new priority substances for which environmental quality standards (EQSs) need to be derived (Directive 2013/39/EC); (ii) in the search for innovative solutions in sediment remediation (i.e., respecting the influence of mechanical processes; Flood Risk Directive 2007/60/EC); and (iii) as indicators at the land-sea interface (Marine Strategy Framework Directive 2008/56/EC). In the Elbe river catchment, aspects of policy and science are closely connected, which became particularly obvious in a classic example of dioxin hot spot contamination, the case of the Spittelwasser creek. Here, the "source-first principle" of the first cycle of the European Water Framework Directive (WFD) had to be confirmed in a controversy on the dioxin hot spots with Saxony-Anhalt's Agency for Contaminated Sites (LAF). At the Spittelwasser site, the move from "inside the creek" to "along the river banks" goes parallel to a general paradigm shift in retrospective risk assessment frameworks and remediation techniques for organic chemicals (Ortega-Calvo et al. 2015). With respect to dioxin, large-scale stabilization applying activated carbon additions is particularly promising. Another important aspect is the assessment of the ecotoxicology of dioxins and dl- PCBs in context of sediment mobility and flood risk assessment, which has been studied in the project framework FloodSearch. Currently, the quality goals of the WFD to reach a "good chemical status" are not met in many catchment areas because substances such as mercury do and others probably will (PCDD/Fs and dl-PCB) exceed biota-EQS values catchment area-wide. So far, relating biota-EQS values to sediment-EQSs is not possible. To overcome these limitations, the DioRAMA project was initiated, which has led to improved approaches for the assessment of dioxin-contaminated sediment using in vitro bioassays and to a robust dataset on the interrelation between dioxins and dioxin-like compounds in sediments and biota.

Sedimentary controls on modern sand grain coat formation

NASA Astrophysics Data System (ADS)

Dowey, Patrick J.; Worden, Richard H.; Utley, James; Hodgson, David M.

2017-05-01

Coated sand grains can influence reservoir quality evolution during sandstone diagenesis. Porosity can be reduced and fluid flow restricted where grain coats encroach into pore space. Conversely pore-lining grain coats can restrict the growth of pore-filling quartz cement in deeply buried sandstones, and thus can result in unusually high porosity in deeply buried sandstones. Being able to predict the distribution of coated sand grains within petroleum reservoirs is thus important to help find good reservoir quality. Here we report a modern analogue study of 12 sediment cores from the Anllóns Estuary, Galicia, NW Spain, collected from a range of sub-environments, to help develop an understanding of the occurrence and distribution of coated grains. The cores were described for grain size, bioturbation and sedimentary structures, and then sub-sampled for electron and light microscopy, laser granulometry, and X-ray diffraction analysis. The Anllóns Estuary is sand-dominated with intertidal sand flats and saltmarsh environments at the margins; there is a shallowing/fining-upwards trend in the estuary-fill succession. Grain coats are present in nearly every sample analysed; they are between 1 μm and 100 μm thick and typically lack internal organisation. The extent of grain coat coverage can exceed 25% in some samples with coverage highest in the top 20 cm of cores. Samples from muddy intertidal flat and the muddy saltmarsh environments, close to the margins of the estuary, have the highest coat coverage (mean coat coverage of 20.2% and 21.3%, respectively). The lowest mean coat coverage occurs in the sandy saltmarsh (10.4%), beyond the upper tidal limit and sandy intertidal flat environments (8.4%), close to the main estuary channel. Mean coat coverage correlates with the concentration of clay fraction. The primary controls on the distribution of fine-grained sediment, and therefore grain coat distribution, are primary sediment transport and deposition processes that concentrate the clay fraction in the sediment towards the margins of the estuary. Bioturbation and clay illuviation/mechanical infiltration are secondary processes that may redistribute fine-grained sediment and produce grain coats. Here we have shown that detrital grain coats are more likely in marginal environments of ancient estuary-fills, which are typically found in the fining-upward part of progradational successions.

Streamflow, dissolved solids, suspended sediment, and trace elements, San Joaquin River, California, June 1985-September 1988

USGS Publications Warehouse

Hill, B.R.; Gilliom, R.J.

1993-01-01

The 1985-88 study period included hydrologic extremes throughout most of central California. Except for an 11-month period during and after the 1986 flood, San Joaquin River streamflows during 1985-88 were generally less than median for 1975-88. The Merced Tuolumne, and Stanislaus Rivers together comprised 56 to 69 percent of the annual San Joaquin River flow, Salt and Mud Sloughs together comprised 6 to 19 percent, the upper San Joaquin River comprised 2 to 25 percent, and unmeasured sources from agricultural discharges and ground water accounted for 13 to 20 percent. Salt and Mud Sloughs and the unmeasured sources contribute most of the dissolved-solids load. The Merced, Tuolumne, and Stanislaus Rivers greatly dilute dissolved-solids concentrations. Suspended-sediment concentration peaked sharply at more than 600 milligrams per liter during the flood of February 1986. Concentrations and loads varied seasonally during low-flow conditions, with concentrations highest during the early summer irrigation season. Trace elements present primarily in dissolved phases are arsenic, boron, lithium, molybdenum, and selenium. Boron concentrations exceeded the irrigation water-quality criterion of 750 micrograms per liter more than 75 percent of the time in Salt and Mud Sloughs and more than 50 percent of the time at three sites on the San Joaquin River. Selenium concentrations exceeded the aquatic-life criterion of 5 micrograms per liter more than 75 percent of the time in Salt Slough and more than 50 percent of the time in Mud Slough and in the San Joaquin River from Salt Slough to the Merced River confluence. Concentrations of dissolved solids, boron, and selenium usually are highest during late winter to early spring, lower in early summer, higher again in mid-to-late summer, and the lowest in autumn, and generally correspond to seasonal inflows of subsurface tile-drain water to Salt and Mud Sloughs. Trace elements present primarily in particulate phases are aluminum, chromium, copper, iron, manganese, nickel, and zinc, none of which cause significant water-quality problems in the river.