Sample records for exceptional physical properties

  1. 25 CFR 276.2 - Definitions.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... means property of any kind except real property. It may be tangible—having physical existence, or intangible—having no physical existence, such as patents, inventions, and copyrights. (m) Real property means... AFFAIRS, DEPARTMENT OF THE INTERIOR INDIAN SELF-DETERMINATION AND EDUCATION ASSISTANCE ACT PROGRAM UNIFORM...

  2. 25 CFR 276.2 - Definitions.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... means property of any kind except real property. It may be tangible—having physical existence, or intangible—having no physical existence, such as patents, inventions, and copyrights. (m) Real property means... AFFAIRS, DEPARTMENT OF THE INTERIOR INDIAN SELF-DETERMINATION AND EDUCATION ASSISTANCE ACT PROGRAM UNIFORM...

  3. Dirac(-Pauli), Fokker-Planck equations and exceptional Laguerre polynomials

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Ho, Choon-Lin, E-mail: hcl@mail.tku.edu.tw

    2011-04-15

    Research Highlights: > Physical examples involving exceptional orthogonal polynomials. > Exceptional polynomials as deformations of classical orthogonal polynomials. > Exceptional polynomials from Darboux-Crum transformation. - Abstract: An interesting discovery in the last two years in the field of mathematical physics has been the exceptional X{sub l} Laguerre and Jacobi polynomials. Unlike the well-known classical orthogonal polynomials which start with constant terms, these new polynomials have lowest degree l = 1, 2, and ..., and yet they form complete set with respect to some positive-definite measure. While the mathematical properties of these new X{sub l} polynomials deserve further analysis, it ismore » also of interest to see if they play any role in physical systems. In this paper we indicate some physical models in which these new polynomials appear as the main part of the eigenfunctions. The systems we consider include the Dirac equations coupled minimally and non-minimally with some external fields, and the Fokker-Planck equations. The systems presented here have enlarged the number of exactly solvable physical systems known so far.« less

  4. 41 CFR 109-27.5104-2 - Physical protection and storage.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 41 Public Contracts and Property Management 3 2013-07-01 2013-07-01 false Physical protection and... PROCUREMENT 27-INVENTORY MANAGEMENT 27.51-Management of Precious Metals § 109-27.5104-2 Physical protection and storage. Precious metals shall be afforded exceptional physical protection from time of receipt...

  5. 41 CFR 109-27.5104-2 - Physical protection and storage.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 41 Public Contracts and Property Management 3 2011-01-01 2011-01-01 false Physical protection and... PROCUREMENT 27-INVENTORY MANAGEMENT 27.51-Management of Precious Metals § 109-27.5104-2 Physical protection and storage. Precious metals shall be afforded exceptional physical protection from time of receipt...

  6. 41 CFR 109-27.5104-2 - Physical protection and storage.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 41 Public Contracts and Property Management 3 2014-01-01 2014-01-01 false Physical protection and... PROCUREMENT 27-INVENTORY MANAGEMENT 27.51-Management of Precious Metals § 109-27.5104-2 Physical protection and storage. Precious metals shall be afforded exceptional physical protection from time of receipt...

  7. 41 CFR 109-27.5104-2 - Physical protection and storage.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Physical protection and... PROCUREMENT 27-INVENTORY MANAGEMENT 27.51-Management of Precious Metals § 109-27.5104-2 Physical protection and storage. Precious metals shall be afforded exceptional physical protection from time of receipt...

  8. 41 CFR 109-27.5104-2 - Physical protection and storage.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 41 Public Contracts and Property Management 3 2012-01-01 2012-01-01 false Physical protection and... PROCUREMENT 27-INVENTORY MANAGEMENT 27.51-Management of Precious Metals § 109-27.5104-2 Physical protection and storage. Precious metals shall be afforded exceptional physical protection from time of receipt...

  9. Some strength and related properties of yagrumo hembra (Cecropia peltata) from Puerto Rico

    Treesearch

    B. A. Bendtsen

    1964-01-01

    Evaluations of several mechanical and physical properties were conducted on specimens from five yagrumo hembra (Cecropia peltata) trees from Puerto Rico. With the exception of toughness and modulus of elasticity in both bending and compression parallel to grain, these specimens were lower in specific gravity and in strength properties than material reported previously...

  10. Plasmonics of 2D Nanomaterials: Properties and Applications

    PubMed Central

    Li, Yu; Li, Ziwei; Chi, Cheng; Shan, Hangyong; Zheng, Liheng

    2017-01-01

    Plasmonics has developed for decades in the field of condensed matter physics and optics. Based on the classical Maxwell theory, collective excitations exhibit profound light‐matter interaction properties beyond classical physics in lots of material systems. With the development of nanofabrication and characterization technology, ultra‐thin two‐dimensional (2D) nanomaterials attract tremendous interest and show exceptional plasmonic properties. Here, we elaborate the advanced optical properties of 2D materials especially graphene and monolayer molybdenum disulfide (MoS2), review the plasmonic properties of graphene, and discuss the coupling effect in hybrid 2D nanomaterials. Then, the plasmonic tuning methods of 2D nanomaterials are presented from theoretical models to experimental investigations. Furthermore, we reveal the potential applications in photocatalysis, photovoltaics and photodetections, based on the development of 2D nanomaterials, we make a prospect for the future theoretical physics and practical applications. PMID:28852608

  11. Effect of extrusion conditions and lipoxygenase inactivation treatment on the physical and nutritional properties of corn/cowpea (Vigna unguiculata) blends.

    PubMed

    Sosa-Moguel, Odri; Ruiz-Ruiz, Jorge; Martínez-Ayala, Alma; González, Rolando; Drago, Silvina; Betancur-Ancona, David; Chel-Guerrero, Luis

    2009-01-01

    The influence of lipoxygenase inactivation and extrusion cooking on the physical and nutritional properties of corn/cowpea (Vigna unguiculata) blends was studied. Corn was blended in an 80:15 proportion with cowpea flour treated to inactivate lipoxygenase (CI) or non-inactivated cowpea flour (CNI). Extrusion variables were temperature (150 degrees C, 165 degrees C and 180 degrees C) and moisture (15%, 17% and 19%). Based on their physical properties, the 165 degrees C/15% corn:CNI, and 165 degrees C/15% corn:CI, and 150 degrees C/15% corn:CI blends were chosen for nutritional quality analysis. Extrudate chemical composition indicated high crude protein levels compared with standard corn-based products. With the exception of lysine, essential amino acids content in the three treatments met FAO requirements. Extrusion and lipoxygenase inactivation are promising options for developing corn/cowpea extruded snack products with good physical properties and nutritional quality.

  12. OBSERVATIONS OF ENANTIOSELECTIVITY IN THE FATE, PERSISTENCE AND EFFECTS OF MODERN PESTICIDES

    EPA Science Inventory

    Chiral pollutants exist as 2 (or more) species, -- enantiomers -- that are non-superimposable mirror images of each other. Enantiomers have identical physical and chemical properties except when they interact with enzymes or other chiral molecules; then they usually react select...

  13. CAPILLARY ELECTROPHORESIS FOR ENANTIOMER SEPARATION AND MEASUREMENT OF ENANTIOSELECTIVITY OF CHIRAL POLLUTANTS IN THE ENVIRONMENT

    EPA Science Inventory

    Chiral pollutants exist as 2 species, -- enantiomers - that have identical physical and chemical properties except when they interact with enzymes or other chiral molecules; then they usually react selectively. This enantioselectivity results in different rates of microbial trans...

  14. The Mysteries of Diamonds: Bizarre History, Amazing Properties, Unique Applications

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Kagan, Harris

    2008-06-24

    Diamonds have been a prized material throughout history. They are scarce and beautiful, wars have been fought over them, and they remain today a symbol of wealth and power. Diamonds also have exceptional physical properties which can lead to unique applications in science. There are now techniques to artificially synthesize diamonds of extraordinarily high quality. In this talk, Professor Kagan will discuss the history of diamonds, their bizarre properties, and their manufacture and use for 21st century science.

  15. Water, something peculiar.

    USGS Publications Warehouse

    Van Hylckama, T. E. A.

    1979-01-01

    Some chemical and physical properties of water are discussed and compared with those of other fluids. For instance, the boiling point is much higher than one would expect considering the molecular weight of water. The heat capacity is also much higher but the viscosity is not. The dielectric constant is exceptionally high. These and other properties of water can be explained by the geometry of the water molecule and the structure of water or ice. -Author

  16. A physicochemical investigation of ionic liquid mixtures† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c4sc02931c Click here for additional data file.

    PubMed Central

    Clough, Matthew T.; Crick, Colin R.; Gräsvik, John; Niedermeyer, Heiko; Whitaker, Oliver P.

    2015-01-01

    Ionic liquids have earned the reputation of being ‘designer solvents’ due to the wide range of accessible properties and the degree of fine-tuning afforded by varying the constituent ions. Mixtures of ionic liquids offer the opportunity for further fine-tuning of properties. A broad selection of common ionic liquid cations and anions are employed to create a sample of binary and reciprocal binary ionic liquid mixtures, which are analysed and described in this paper. Physical properties such as the conductivity, viscosity, density and phase behaviour (glass transition temperatures) are examined. In addition, thermal stabilities of the mixtures are evaluated. The physical properties examined for these formulations are found to generally adhere remarkably closely to ideal mixing laws, with a few consistent exceptions, allowing for the facile prediction and control of properties of ionic liquid mixtures. PMID:29560198

  17. Effect of Sintering on Mechanical and Physical Properties of Plasma-Sprayed Thermal Barrier Coatings

    NASA Technical Reports Server (NTRS)

    Choi, Sung R.; Zhu, Dong-Ming; Miller, Robert A.

    2004-01-01

    The effect of sintering on mechanical and physical properties of free-standing plasma-sprayed ZrO2-8 wt% Y2O3 thermal barrier coatings (TBCs) was determined by annealing them at 1316 C in air. Mechanical and physical properties of the TBCs, including strength, modes I and II fracture toughness, elastic modulus, Poisson s response, density, microhardness, fractography, and phase stability, were determined at ambient temperature as a function of annealing time ranging from 0 to 500 h. All mechanical and physical properties, except for the amount of monoclinic phase, increased significantly in 5 to 100 h and then reached a plateau above 100 h. Annealing resulted in healing of microcracks and pores and in grain growth, accompanying densification of the TBC s body due to the sintering effect. However, an inevitable adverse effect also occurred such that the desired lower thermal conductivity and good expansivity, which makes the TBCs unique in thermal barrier applications, were degraded upon annealing. A model was proposed to assess and quantify all the property variables in response to annealing in a normalized scheme. Directionality of as-sprayed TBCs appeared to have an insignificant effect on their properties, as determined via fracture toughness, microhardness, and elastic modulus measurements.

  18. Effect of water volume based on water absorption and mixing time on physical properties of tapioca starch – wheat composite bread

    NASA Astrophysics Data System (ADS)

    Prameswari, I. K.; Manuhara, G. J.; Amanto, B. S.; Atmaka, W.

    2018-05-01

    Tapioca starch application in bread processing change water absorption level by the dough, while sufficient mixing time makes the optimal water absorption. This research aims to determine the effect of variations in water volume and mixing time on physical properties of tapioca starch – wheat composite bread and the best method for the composite bread processing. This research used Complete Randomized Factorial Design (CRFD) with two factors: variations of water volume (111,8 ml, 117,4 ml, 123 ml) and mixing time (16 minutes, 17 minutes 36 seconds, 19 minutes 12 seconds). The result showed that water volume significantly affected on dough volume, bread volume and specific volume, baking expansion, and crust thickness. Mixing time significantly affected on dough volume and specific volume, bread volume and specific volume, baking expansion, bread height, and crust thickness. While the combination of water volume and mixing time significantly affected for all physical properties parameters except crust thickness.

  19. Triple modifier effect on physical, optical and structural properties of boro tellurite zinc lithium glasses

    NASA Astrophysics Data System (ADS)

    Naresh, P.; Srinivasu, D.; Narsimlu, N.; Ch. Srinivas, Kavitha, B.; Deshpandhe, Uday; Kumar, K. Siva

    2018-05-01

    To investigate physical, optical and structural properties of glass samples of the Quaternary system (60-x)B2O3-xTeO2-10ZnO-30Li2O with x=0,5,10,15, and 20 mol% were prepared by conventional melt quenching technique. XRD confirmed the amorphous nature of all samples. Physical parameters like density, molar volume, Oxygen packing density and etc. calculated. Density of glass samples increased with the increase of TeO2 concentration due to the replacement of lighter B2O3 with heavier TeO2. Optical properties has studied with the help of UV-Visible spectra. Cut off wavelength is increases whereas Eopt and Urbache energies is decreased except intermediate mole fraction of TeO2 at which the triple modifier effect can be observed. Fourier Transform Infrared spectroscopy reveals that the network consists of TeO3 and TeO6 structural units along with BO3 and BO4 units.

  20. The development of graphene-based devices for cell biology research

    NASA Astrophysics Data System (ADS)

    Yan, Zhi-Qin; Zhang, Wei

    2014-06-01

    Graphene has emerged as a new carbon nanoform with great potential in many applications due to its exceptional physical and chemical properties. Especially, graphene and its derivatives are also gaining a lot of interest in the biomedical field as new components for biosensors, tissue engineering, and drug delivery. This review presents unique properties of graphene, the bio-effects of graphene and its derivatives, especially their interactions with cells and the development of graphene-based biosensors and nanomedicines for cancer diagnosis and treatment.

  1. Cellulosic Nanomaterials in Food and Nutraceutical Applications: A Review.

    PubMed

    Khan, Avik; Wen, Yangbing; Huq, Tanzina; Ni, Yonghao

    2018-01-10

    Cellulosic nanomaterials (CNMs) are organic, green nanomaterials that are obtained from renewable sources and possess exceptional mechanical strength and biocompatibility. The associated unique physical and chemical properties have made these nanomaterials an intriguing prospect for various applications including the food and nutraceutical industry. From the immobilization of various bioactive agents and enzymes, emulsion stabilization, direct food additives, to the development of intelligent packaging systems or pathogen or pH detectors, the potential food related applications for CNMs are endless. Over the past decade, there have been several reviews published covering different aspects of cellulosic nanomaterials, such as processing-structure-property relationship, physical and chemical properties, rheology, extraction, nanocomposites, etc. In this critical review, we have discussed and provided a summary of the recent developments in the utilization of cellulosic nanomaterials in applications related to food and nutraceuticals.

  2. 12 CFR 225.63 - Appraisals required; transactions requiring a State certified or licensed appraiser.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ...-related financial transactions except those in which: (1) The transaction value is $250,000 or less; (2) A... extension of credit at the lending institution, provided that: (i) There has been no obvious and material change in market conditions or physical aspects of the property that threatens the adequacy of the...

  3. Replacement of Asbestos Aboard Naval Aircraft.

    DTIC Science & Technology

    1981-11-10

    braided -sleeving hose coverings, tapes, wire insulation, furnace linings, blankets, gaskets, and seals. CHEMICAL ANALYSIS A12 03 62% Si0 2 24...Physical, Chemical, and Mineralogical Properties of Varieties of Asbestos ............................................ 7 III Inorganic (Non- Metal ...all types Gakets (for sealing nonmoving parts) Asbestos, asbetos- metallic , and asbetos-ubber Packing (except leather, rubber, and metal ) and abestos

  4. Effect of cooking conditions on fiber bonding in dry-formed binderless hardboard

    Treesearch

    Otto Suchsland; George E. Woodson; Charles W. McMillin

    1987-01-01

    Binderless dry-formed hardboards were manufactured in the laboratory from refined Masonite pulp cooked for 2.5 minutes at steam pressures varying from 200 to 500 psi. Increasing steam pressure caused a general improvement in mechanical and physical properties except that linear expanaion increased with increasing steam pressures and that bending strength and stiffness...

  5. Carbon nanotube biosensors

    PubMed Central

    Tîlmaciu, Carmen-Mihaela; Morris, May C.

    2015-01-01

    Nanomaterials possess unique features which make them particularly attractive for biosensing applications. In particular, carbon nanotubes (CNTs) can serve as scaffolds for immobilization of biomolecules at their surface, and combine several exceptional physical, chemical, electrical, and optical characteristics properties which make them one of the best suited materials for the transduction of signals associated with the recognition of analytes, metabolites, or disease biomarkers. Here we provide a comprehensive review on these carbon nanostructures, in which we describe their structural and physical properties, functionalization and cellular uptake, biocompatibility, and toxicity issues. We further review historical developments in the field of biosensors, and describe the different types of biosensors which have been developed over time, with specific focus on CNT-conjugates engineered for biosensing applications, and in particular detection of cancer biomarkers. PMID:26579509

  6. Carbon Nanotube Biosensors

    NASA Astrophysics Data System (ADS)

    Tilmaciu, Carmen-Mihaela; Morris, May

    2015-10-01

    Nanomaterials possess unique features which make them particularly attractive for biosensing applications. In particular Carbon Nanotubes (CNTs) can serve as scaffolds for immobilization of biomolecules at their surface, and combine several exceptional physical, chemical, electrical and optical characteristics properties which make them one of the best suited materials for the transduction of signals associated with the recognition of analytes, metabolites or disease biomarkers. Here we provide a comprehensive review on these carbon nanostructures, in which we will describe their structural and physical properties, discuss functionalization and cellular uptake, biocompatibility and toxicity issues. We further review historical developments in the field of biosensors, and describe the different types of biosensors which have been developed over time, with specific focus on CNT-conjugates engineered for biosensing applications, and in particular detection of cancer biomarkers.

  7. Influence of different emulsifiers on characteristics of eggless cake containing soy milk: Modeling of physical and sensory properties by mixture experimental design.

    PubMed

    Rahmati, Nazanin Fatemeh; Mazaheri Tehrani, Mostafa

    2014-09-01

    Emulsifiers of different structures and functionalities are important ingredients usually used in baking cakes with satisfactory properties. In this study, three emulsifiers including distilled glycerol mono stearate (DGMS), lecithin and sorbitan mono stearate (SMS) were used to bake seven eggless cakes containing soy milk and optimization was performed by using mixture experimental design to produce an eggless cake sample with optimized properties. Physical properties of cake batters (viscosity, specific gravity and stability), cake quality parameters (moisture loss, density, specific volume, volume index, contour, symmetry, color and texture) and sensory attributes of eggless cakes were analyzed to investigate functional potential of the emulsifiers and results were compared with those of control cake containing egg. Almost in all cases emulsifiers, compared to the control cake, changed properties of eggless cakes significantly. Regarding models of different response variables (except for some properties) and their high R(2) (99.51-100), it could be concluded that models obtained by mixture design were significantly fitted for the studied responses.

  8. Close encounters with DNA

    PubMed Central

    Maffeo, C.; Yoo, J.; Comer, J.; Wells, D. B.; Luan, B.; Aksimentiev, A.

    2014-01-01

    Over the past ten years, the all-atom molecular dynamics method has grown in the scale of both systems and processes amenable to it and in its ability to make quantitative predictions about the behavior of experimental systems. The field of computational DNA research is no exception, witnessing a dramatic increase in the size of systems simulated with atomic resolution, the duration of individual simulations and the realism of the simulation outcomes. In this topical review, we describe the hallmark physical properties of DNA from the perspective of all-atom simulations. We demonstrate the amazing ability of such simulations to reveal the microscopic physical origins of experimentally observed phenomena and we review the frustrating limitations associated with imperfections of present atomic force fields and inadequate sampling. The review is focused on the following four physical properties of DNA: effective electric charge, response to an external mechanical force, interaction with other DNA molecules and behavior in an external electric field. PMID:25238560

  9. Close encounters with DNA.

    PubMed

    Maffeo, C; Yoo, J; Comer, J; Wells, D B; Luan, B; Aksimentiev, A

    2014-10-15

    Over the past ten years, the all-atom molecular dynamics method has grown in the scale of both systems and processes amenable to it and in its ability to make quantitative predictions about the behavior of experimental systems. The field of computational DNA research is no exception, witnessing a dramatic increase in the size of systems simulated with atomic resolution, the duration of individual simulations and the realism of the simulation outcomes. In this topical review, we describe the hallmark physical properties of DNA from the perspective of all-atom simulations. We demonstrate the amazing ability of such simulations to reveal the microscopic physical origins of experimentally observed phenomena. We also discuss the frustrating limitations associated with imperfections of present atomic force fields and inadequate sampling. The review is focused on the following four physical properties of DNA: effective electric charge, response to an external mechanical force, interaction with other DNA molecules and behavior in an external electric field.

  10. Physical properties of the natural satellites. [excluding the Moon and including Saturnian Rings

    NASA Technical Reports Server (NTRS)

    Morrison, D.; Cruikshank, D. P.

    1974-01-01

    Review of the physical nature of all of the known satellites except the moon. Following a summary of the basic data regarding the size, mass, and density of satellite systems and a description of models that have been proposed for the composition and structure of these systems, a detailed analysis is made of the satellites of Mars, the Galilean satellites, Titan, the other satellites of Saturn, the rings of Saturn, and the remaining objects, with emphasis on studies of their surfaces by imaging, photometry, spectrophotometry, polarimetry, and radiometry.

  11. Environmental Assessment for the Space Complex-5 SCOUT Launcher Relocation, Vandenberg Air Force Base, California

    DTIC Science & Technology

    2009-01-01

    Agreement (L,nderJ) ;ng PA) stipu atmg thaI Cold War propertIes significant for their distir.c:ivc physical characteristics and ~hclr historic function...launch complex th t dir Iy upported ooerational missions 0 the exceptionally imp rtant Cold War program. n You l1ave aiso submi tea a map that outlines

  12. Physical properties of galaxies: towards a consistent comparison between hydrodynamical simulations and SDSS

    NASA Astrophysics Data System (ADS)

    Guidi, Giovanni; Scannapieco, Cecilia; Walcher, Jakob; Gallazzi, Anna

    2016-10-01

    We study the effects of applying observational techniques to derive the properties of simulated galaxies, with the aim of making an unbiased comparison between observations and simulations. For our study, we used 15 galaxies simulated in a cosmological context using three different feedback and chemical enrichment models, and compared their z = 0 properties with data from the Sloan Digital Sky Survey (SDSS). We show that the physical properties obtained directly from the simulations without post-processing can be very different from those obtained mimicking observational techniques. In order to provide simulators a way to reliably compare their galaxies with SDSS data, for each physical property that we studied - colours, magnitudes, gas and stellar metallicities, mean stellar ages and star formation rates - we give scaling relations that can be easily applied to the values extracted from the simulations; these scalings have in general a high correlation, except for the gas oxygen metallicities. Our simulated galaxies are photometrically similar to galaxies in the blue sequence/green valley, but in general they appear older, passive and with lower metal content compared to most of the spirals in SDSS. As a careful assessment of the agreement/disagreement with observations is the primary test of the baryonic physics implemented in hydrodynamical codes, our study shows that considering the observational biases in the derivation of the galaxies' properties is of fundamental importance to decide on the failure/success of a galaxy formation model.

  13. Data requirements for simulation of hydrogeologic effects of liquid waste injection, Harrison and Jackson Counties, Mississippi

    USGS Publications Warehouse

    Rebich, Richard A.

    1994-01-01

    Available literature and data were reviewed to quantify data requirements for computer simulation of hydrogeologic effects of liquid waste injection in southeastern Mississippi. Emphasis of each review was placed on quantifying physical properties of current Class I injection zones in Harrison and Jackson Counties. Class I injection zones are zones that are used for injection of hazardous or non-hazardous liquid waste below a formation containing the lowermost underground source of drinking water located within one-quarter of a mile of the injection well. Several mathematical models have been developed to simulate injection effects. The Basic Plume Method was selected because it is commonly used in permit applications, and the Intercomp model was selected because it is generally accepted and used in injection-related research. The input data requirements of the two models were combined into a single data requirement list inclusive of physical properties of injection zones only; injected waste and well properties are not included because such information is site-specific by industry, which is beyond the scope of this report. Results of the reviews of available literature and data indicated that Class I permit applications and standard-reference chemistry and physics texts were the primary sources of information to quantify physical properties of injection zones in Harrison and Jackson Counties. With the exception of a few reports and supplementary data for one injection zone in Jackson County, very little additional information pertaining to physical properties of the injection zones was available in sources other than permit applications and standard-reference texts.

  14. [Changes of soil physical properties during the conversion of cropland to agroforestry system].

    PubMed

    Wang, Lai; Gao, Peng Xiang; Liu, Bin; Zhong, Chong Gao; Hou, Lin; Zhang, Shuo Xin

    2017-01-01

    To provide theoretical basis for modeling and managing agroforestry systems, the influence of conversion of cropland to agroforestry system on soil physical properties was investigated via a walnut (Juglans regia)-wheat (Triticum aestivum) intercropping system, a wide spreading local agroforestry model in northern Weihe River of loess area, with the walnut and wheat monoculture systems as the control. The results showed that the improvement of the intercropping system on soil physical properties mainly appeared in the 0-40 cm soil layer. The intercropping system could prevent soil bulk density rising in the surface soil (0-20 cm), and the plow pan in the 20-40 cm soil layer could be significantly alleviated. The intercropping system had conti-nuous improvement on soil field capacity in each soil layer with the planting age increase, and the soil field capacity was higher than that of each monoculture system in each soil layer (except 20-40 cm soil layer) since the 5th year after planting. The intercropping system had continuous improvement on soil porosity in each soil layer, but mainly in the 0-20 and 20-40 cm soil layer, and the ratio of capillary porosity was also improved. The soil bulk density, field capacity and soil porosity obtained continuous improvement during the conversion of cropland to agroforestry system, and the improvement on soil physical properties was stronger in shallow soil layer than in deep soil.

  15. The large-scale structure of the asteroid belt

    NASA Technical Reports Server (NTRS)

    Zellner, B.; Thirunagari, A.; Bender, D.

    1985-01-01

    The distributions of 2888 numbered minor planets over orbital inclination, eccentricity, and semimajor axis are examined, and 19 zones believed to adequately isolate the selection biases in survey programs of the physical properties of minor planets are defined. Six numbered asteroids have exceptional orbits and fall into no zone. Attention is called to rather sharp upper limits, which become increasingly stringent at larger heliocentric distances, on orbital inclinations and eccentricity.

  16. Physical, Rheological, Functional, and Film Properties of a Novel Emulsifier: Frost Grape Polysaccharide from Vitis riparia Michx.

    PubMed

    Hay, William T; Vaughn, Steven F; Byars, Jeffrey A; Selling, Gordon W; Holthaus, Derek M; Price, Neil P J

    2017-10-04

    A novel emulsifier, Frost grape polysaccharide (FGP), isolated from natural exudate of the species Vitis riparia Michx, was physically and rheologically characterized. The determination of the physical, structural, thermodynamic, emulsification, film, and rheological properties of FGP provide essential details for the commercial adoption of this novel plant polysaccharide. FGP is capable of producing exceptionally stable emulsions when compared with the industrially ubiquitous gum arabic (GA). The FGP isolate contained a negligible amount of nitrogen (0.03%), indicating that it does not contain an associated glycoprotein, unlike GA. Solutions of FGP have a high degree of thermostability, displaying no loss in viscosity with temperature cycling and no thermal degradation when held at 90 °C. FGP is an excellent film former, producing high tensile strength films which remain intact at temperatures up to 200 °C. This work identified a number of potential food and pharmaceutical applications where FGP is significantly superior to GA.

  17. Physical characterization of whole and skim dried milk powders.

    PubMed

    Pugliese, Alessandro; Cabassi, Giovanni; Chiavaro, Emma; Paciulli, Maria; Carini, Eleonora; Mucchetti, Germano

    2017-10-01

    The lack of updated knowledge about the physical properties of milk powders aimed us to evaluate selected physical properties (water activity, particle size, density, flowability, solubility and colour) of eleven skim and whole milk powders produced in Europe. These physical properties are crucial both for the management of milk powder during the final steps of the drying process, and for their use as food ingredients. In general, except for the values of water activity, the physical properties of skim and whole milk powders are very different. Particle sizes of the spray-dried skim milk powders, measured as volume and surface mean diameter were significantly lower than that of the whole milk powders, while the roller dried sample showed the largest particle size. For all the samples the size distribution was quite narrow, with a span value less than 2. The loose density of skim milk powders was significantly higher than whole milk powders (541.36 vs 449.75 kg/m 3 ). Flowability, measured by Hausner ratio and Carr's index indicators, ranged from passable to poor when evaluated according to pharmaceutical criteria. The insolubility index of the spray-dried skim and whole milk powders, measured as weight of the sediment (from 0.5 to 34.8 mg), allowed a good discrimination of the samples. Colour analysis underlined the relevant contribution of fat content and particle size, resulted in higher lightness ( L *) for skim milk powder than whole milk powder, which, on the other hand, showed higher yellowness ( b *) and lower greenness (- a *). In conclusion a detailed knowledge of functional properties of milk powders may allow the dairy to tailor the products to the user and help the food processor to perform a targeted choice according to the intended use.

  18. Single-layer nanosheets with exceptionally high and anisotropic hydroxyl ion conductivity

    PubMed Central

    Sun, Pengzhan; Ma, Renzhi; Bai, Xueyin; Wang, Kunlin; Zhu, Hongwei; Sasaki, Takayoshi

    2017-01-01

    When the dimensionality of layered materials is reduced to the physical limit, an ultimate two-dimensional (2D) anisotropy and/or confinement effect may bring about extraordinary physical and chemical properties. Layered double hydroxides (LDHs), bearing abundant hydroxyl groups covalently bonded within 2D host layers, have been proposed as inorganic anion conductors. However, typical hydroxyl ion conductivities for bulk or lamellar LDHs, generally up to 10−3 S cm−1, are considered not high enough for practical applications. We show that single-layer LDH nanosheets exhibited exceptionally high in-plane conductivities approaching 10−1 S cm−1, which were the highest among anion conductors and comparable to proton conductivities in commercial proton exchange membranes (for example, Nafion). The in-plane conductivities were four to five orders of magnitude higher than the cross-plane or cross-membrane values of restacked LDH nanosheets. This 2D superionic transport characteristic might have great promises in a variety of applications including alkaline fuel cells and water electrolysis. PMID:28439551

  19. Enhanced sensitivity at higher-order exceptional points

    NASA Astrophysics Data System (ADS)

    Hodaei, Hossein; Hassan, Absar U.; Wittek, Steffen; Garcia-Gracia, Hipolito; El-Ganainy, Ramy; Christodoulides, Demetrios N.; Khajavikhan, Mercedeh

    2017-08-01

    Non-Hermitian degeneracies, also known as exceptional points, have recently emerged as a new way to engineer the response of open physical systems, that is, those that interact with the environment. They correspond to points in parameter space at which the eigenvalues of the underlying system and the corresponding eigenvectors simultaneously coalesce. In optics, the abrupt nature of the phase transitions that are encountered around exceptional points has been shown to lead to many intriguing phenomena, such as loss-induced transparency, unidirectional invisibility, band merging, topological chirality and laser mode selectivity. Recently, it has been shown that the bifurcation properties of second-order non-Hermitian degeneracies can provide a means of enhancing the sensitivity (frequency shifts) of resonant optical structures to external perturbations. Of particular interest is the use of even higher-order exceptional points (greater than second order), which in principle could further amplify the effect of perturbations, leading to even greater sensitivity. Although a growing number of theoretical studies have been devoted to such higher-order degeneracies, their experimental demonstration in the optical domain has so far remained elusive. Here we report the observation of higher-order exceptional points in a coupled cavity arrangement—specifically, a ternary, parity-time-symmetric photonic laser molecule—with a carefully tailored gain-loss distribution. We study the system in the spectral domain and find that the frequency response associated with this system follows a cube-root dependence on induced perturbations in the refractive index. Our work paves the way for utilizing non-Hermitian degeneracies in fields including photonics, optomechanics, microwaves and atomic physics.

  20. Tailoring the physical properties of Ni-based single-phase equiatomic alloys by modifying the chemical complexity

    DOE PAGES

    Jin, Ke; Sales, Brian C.; Stocks, George Malcolm; ...

    2016-02-01

    We discovered that equiatomic alloys (e.g. high entropy alloys) have recently attracted considerable interest due to their exceptional properties, which might be closely related to their extreme disorder induced by the chemical complexity. To understand the effects of chemical complexity on their fundamental physical properties, a family of (eight) Ni-based, face-center-cubic (FCC), equiatomic alloys, extending from elemental Ni to quinary high entropy alloys, has been synthesized, and their electrical, thermal, and magnetic properties are systematically investigated in the range of 4–300 K by combining experiments with ab initio Korring-Kohn-Rostoker coherent-potential-approximation (KKR-CPA) calculations. The scattering of electrons is significantly increased duemore » to the chemical (especially magnetic) disorder. It has weak correlation with the number of elements but strongly depends on the type of elements. Thermal conductivities of the alloys are largely lower than pure metals, primarily because the high electrical resistivity suppresses the electronic thermal conductivity. Moreover, the temperature dependence of the electrical and thermal transport properties is further discussed, and the magnetization of five alloys containing three or more elements is measured in magnetic fields up to 4 T.« less

  1. Role of physical bolus properties as sensory inputs in the trigger of swallowing.

    PubMed

    Peyron, Marie-Agnès; Gierczynski, Isabelle; Hartmann, Christoph; Loret, Chrystel; Dardevet, Dominique; Martin, Nathalie; Woda, Alain

    2011-01-01

    Swallowing is triggered when a food bolus being prepared by mastication has reached a defined state. However, although this view is consensual and well supported, the physical properties of the swallowable bolus have been under-researched. We tested the hypothesis that measuring bolus physical changes during the masticatory sequence to deglutition would reveal the bolus properties potentially involved in swallowing initiation. Twenty normo-dentate young adults were instructed to chew portions of cereal and spit out the boluses at different times in the masticatory sequence. The mechanical properties of the collected boluses were measured by a texture profile analysis test currently used in food science. The median particle size of the boluses was evaluated by sieving. In a simultaneous sensory study, twenty-five other subjects expressed their perception of bolus texture dominating at any mastication time. Several physical changes appeared in the food bolus as it was formed during mastication: (1) in rheological terms, bolus hardness rapidly decreased as the masticatory sequence progressed, (2) by contrast, adhesiveness, springiness and cohesiveness regularly increased until the time of swallowing, (3) median particle size, indicating the bolus particle size distribution, decreased mostly during the first third of the masticatory sequence, (4) except for hardness, the rheological changes still appeared in the boluses collected just before swallowing, and (5) physical changes occurred, with sensory stickiness being described by the subjects as a dominant perception of the bolus at the end of mastication. Although these physical and sensory changes progressed in the course of mastication, those observed just before swallowing seem to be involved in swallowing initiation. They can be considered as strong candidates for sensory inputs from the bolus that are probably crucially involved in the triggering of swallowing, since they appeared in boluses prepared in various mastication strategies by different subjects.

  2. Influence of population density on the concentration and speciation of metals in the soil and street dust from urban areas.

    PubMed

    Acosta, J A; Gabarrón, M; Faz, A; Martínez-Martínez, S; Zornoza, R; Arocena, J M

    2015-09-01

    Street dust and soil from high, medium and low populated cities and natural area were analysed for selected physical-chemical properties, total and chemical speciation of Zn, Pb, Cu, Cr, Cd, Co, Ni to understand the influence of human activities on metal accumulation and mobility in the environment. The pH, salinity, carbonates and organic carbon contents were similar between soil and dust from the same city. Population density increases dust/soil salinity but has no influence on metals concentrations in soils. Increases in metal concentrations with population density were observed in dusts. Cu, Zn, Pb, Cr can be mobilized more easily from dust compared to the soil. In addition, population density increase the percentage of Pb and Zn associated to reducible and carbonate phase in the dust. The behaviour of metals except Cd in soil is mainly affected by physico-chemical properties, while total metal influenced the speciation except Cr and Ni in dusts. Copyright © 2015 Elsevier Ltd. All rights reserved.

  3. A review on green synthesis of silver nanoparticles and their applications.

    PubMed

    Rafique, Muhammad; Sadaf, Iqra; Rafique, M Shahid; Tahir, M Bilal

    2017-11-01

    Development of reliable and eco-accommodating methods for the synthesis of nanoparticles is a vital step in the field of nanotechnology. Silver nanoparticles are important because of their exceptional chemical, physical, and biological properties, and hence applications. In the last decade, numerous efforts were made to develop green methods of synthesis to avoid the hazardous byproducts. This review describes the methods of green synthesis for Ag-NPs and their numerous applications. It also describes the comparison of efficient synthesis methods via green routes over physical and chemical methods, which provide strong evidence for the selection of suitable method for the synthesis of Ag-NPs.

  4. Estimating ankle rotational constraints from anatomic structure

    NASA Astrophysics Data System (ADS)

    Baker, H. H.; Bruckner, Janice S.; Langdon, John H.

    1992-09-01

    Three-dimensional biomedical data obtained through tomography provide exceptional views of biological anatomy. While visualization is one of the primary purposes for obtaining these data, other more quantitative and analytic uses are possible. These include modeling of tissue properties and interrelationships, simulation of physical processes, interactive surgical investigation, and analysis of kinematics and dynamics. As an application of our research in modeling tissue structure and function, we have been working to develop interactive and automated tools for studying joint geometry and kinematics. We focus here on discrimination of morphological variations in the foot and determining the implications of these on both hominid bipedal evolution and physical therapy treatment for foot disorders.

  5. A study of degradation of plates for nickel-cadmium spacecraft cells. [feasibility of coining

    NASA Technical Reports Server (NTRS)

    Scott, W. R.

    1973-01-01

    The relative merits of coining and not coining of sintered nickel-oxide and cadmium plates was investigated. A survey of the industry including cell manufactures and users was made and results summarized. Sample plate materials from most commercial cell suppliers were obtained and characterized for properties that may correlate with the tendency toward physical disintegration during handling and over long periods of time in the cell. Special test methods were developed to obtain comparative data in a short time. A wide range of physical properties and coining thicknesses was observed, resulting in a range of responses. The stronger, less brittle materials resisted loss of sinter better than weaker materials whether or not coined. Coining improved handling and resistance to electrochemical cycling in all materials tested. An apparent exception was found to be due to improper coining of a tapered edge.

  6. Engineering of Semiconductor Nanocrystals for Light Emitting Applications

    PubMed Central

    Todescato, Francesco; Fortunati, Ilaria; Minotto, Alessandro; Signorini, Raffaella; Jasieniak, Jacek J.; Bozio, Renato

    2016-01-01

    Semiconductor nanocrystals are rapidly spreading into the display and lighting markets. Compared with liquid crystal and organic LED displays, nanocrystalline quantum dots (QDs) provide highly saturated colors, wide color gamut, resolution, rapid response time, optical efficiency, durability and low cost. This remarkable progress has been made possible by the rapid advances in the synthesis of colloidal QDs and by the progress in understanding the intriguing new physics exhibited by these nanoparticles. In this review, we provide support to the idea that suitably engineered core/graded-shell QDs exhibit exceptionally favorable optical properties, photoluminescence and optical gain, while keeping the synthesis facile and producing QDs well suited for light emitting applications. Solid-state laser emitters can greatly profit from QDs as efficient gain materials. Progress towards fabricating low threshold, solution processed DFB lasers that are optically pumped using one- and two-photon absorption is reviewed. In the field of display technologies, the exploitation of the exceptional photoluminescence properties of QDs for LCD backlighting has already advanced to commercial levels. The next big challenge is to develop the electroluminescence properties of QD to a similar state. We present an overview of QLED devices and of the great perspectives for next generation display and lighting technologies. PMID:28773794

  7. Muscle-derived Decellularised Extracellular Matrix Improves Functional Recovery in a Rat Latissimus Dorsi Muscle Defect Model

    DTIC Science & Technology

    2013-12-01

    battlefield wounds, often involving volumetric muscle loss (VML). The physical loss of muscle results in functional deficits and cosmetic ...repair with M-ECM and 3) sham (all procedures except muscle excision). Four and 8 weeks post- surgery , the isometric contractile properties of the LD... Surgery (2013) 66, 1750e1758 Report Documentation Page Form ApprovedOMB No. 0704-0188 Public reporting burden for the collection of information is

  8. Role of differential physical properties in the collective mechanics and dynamics of tissues

    NASA Astrophysics Data System (ADS)

    Das, Moumita

    Living cells and tissues are highly mechanically sensitive and active. Mechanical stimuli influence the shape, motility, and functions of cells, modulate the behavior of tissues, and play a key role in several diseases. In this talk I will discuss how collective biophysical properties of tissues emerge from the interplay between differential mechanical properties and statistical physics of underlying components, focusing on two complementary tissue types whose properties are primarily determined by (1) the extracellular matrix (ECM), and (2) individual and collective cell properties. I will start with the structure-mechanics-function relationships in articular cartilage (AC), a soft tissue that has very few cells, and its mechanical response is primarily due to its ECM. AC is a remarkable tissue: it can support loads exceeding ten times our body weight and bear 60+ years of daily mechanical loading despite having minimal regenerative capacity. I will discuss the biophysical principles underlying this exceptional mechanical response using the framework of rigidity percolation theory, and compare our predictions with experiments done by our collaborators. Next I will discuss ongoing theoretical work on how the differences in cell mechanics, motility, adhesion, and proliferation in a co-culture of breast cancer cells and healthy breast epithelial cells may modulate experimentally observed differential migration and segregation. Our results may provide insights into the mechanobiology of tissues with cell populations with different physical properties present together such as during the formation of embryos or the initiation of tumors. This work was partially supported by a Cottrell College Science Award.

  9. Recent advances in molecular electronics based on carbon nanotubes.

    PubMed

    Bourgoin, Jean-Philippe; Campidelli, Stéphane; Chenevier, Pascale; Derycke, Vincent; Filoramo, Arianna; Goffman, Marcelo F

    2010-01-01

    Carbon nanotubes (CNTs) have exceptional physical properties that make them one of the most promising building blocks for future nanotechnologies. They may in particular play an important role in the development of innovative electronic devices in the fields of flexible electronics, ultra-high sensitivity sensors, high frequency electronics, opto-electronics, energy sources and nano-electromechanical systems (NEMS). Proofs of concept of several high performance devices already exist, usually at the single device level, but there remain many serious scientific issues to be solved before the viability of such routes can be evaluated. In particular, the main concern regards the controlled synthesis and positioning of nanotubes. In our opinion, truly innovative use of these nano-objects will come from: (i) the combination of some of their complementary physical properties, such as combining their electrical and mechanical properties, (ii) the combination of their properties with additional benefits coming from other molecules grafted on the nanotubes, and (iii) the use of chemically- or bio-directed self-assembly processes to allow the efficient combination of several devices into functional arrays or circuits. In this article, we outline the main issues concerning the development of carbon nanotubes based electronics applications and review our recent results in the field.

  10. Radiopacifier Particle Size Impacts the Physical Properties of Tricalcium Silicate–based Cements

    PubMed Central

    Saghiri, Mohammad Ali; Gutmann, James L.; Orangi, Jafar; Asatourian, Armen; Sheibani, Nader

    2016-01-01

    Introduction The aim of this study was to evaluate the impact of radiopaque additive, bismuth oxide, particle size on the physical properties, and radiopacity of tricalcium silicate–based cements. Methods Six types of tricalcium silicate cement (CSC) including CSC without bismuth oxide, CSC + 10% (wt%) regular bismuth oxide (particle size 10 μm), CSC + 20% regular bismuth oxide (simulating white mineral trioxide aggregate [WMTA]) as a control, CSC + 10% nano bismuth oxide (particle size 50–80 nm), CSC + 20% nano-size bismuth oxide, and nano WMTA (a nano modification of WMTA comprising nanoparticles in the range of 40–100 nm) were prepared. Twenty-four samples from each group were divided into 4 groups and subjected to push-out, surface microhardness, radiopacity, and compressive strength tests. Data were analyzed by 1-way analysis of variance with the post hoc Tukey test. Results The push-out and compressive strength of CSC without bismuth oxide and CSC with 10% and 20% nano bismuth oxide were significantly higher than CSC with 10% or 20% regular bismuth oxide (P < .05). The surface micro-hardness of CSC without bismuth oxide and CSC with 10% regular bismuth oxide had the lowest values (P < .05). The lowest radiopacity values were seen in CSC without bismuth oxide and CSC with 10% nano bismuth oxide (P < .05). Nano WMTA samples showed the highest values for all tested properties (P < .05) except for radiopacity. Conclusions The addition of 20% nano bismuth oxide enhanced the physical properties of CSC without any significant changes in radiopacity. Regular particle-size bismuth oxide reduced the physical properties of CSC material for tested parameters. PMID:25492489

  11. 41 CFR 50-201.602 - Decisions concerning exceptions and exemptions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 1 2010-07-01 2010-07-01 true Decisions concerning exceptions and exemptions. 50-201.602 Section 50-201.602 Public Contracts and Property Management Other...-201.602 Decisions concerning exceptions and exemptions. Decisions concerning exceptions and exemptions...

  12. 41 CFR 50-203.14 - Decisions concerning exceptions and exemptions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 1 2010-07-01 2010-07-01 true Decisions concerning exceptions and exemptions. 50-203.14 Section 50-203.14 Public Contracts and Property Management Other... Decisions concerning exceptions and exemptions. Decisions concerning exceptions and exemptions shall be in...

  13. Anosov C-systems and random number generators

    NASA Astrophysics Data System (ADS)

    Savvidy, G. K.

    2016-08-01

    We further develop our previous proposal to use hyperbolic Anosov C-systems to generate pseudorandom numbers and to use them for efficient Monte Carlo calculations in high energy particle physics. All trajectories of hyperbolic dynamical systems are exponentially unstable, and C-systems therefore have mixing of all orders, a countable Lebesgue spectrum, and a positive Kolmogorov entropy. These exceptional ergodic properties follow from the C-condition introduced by Anosov. This condition defines a rich class of dynamical systems forming an open set in the space of all dynamical systems. An important property of C-systems is that they have a countable set of everywhere dense periodic trajectories and their density increases exponentially with entropy. Of special interest are the C-systems defined on higher-dimensional tori. Such C-systems are excellent candidates for generating pseudorandom numbers that can be used in Monte Carlo calculations. An efficient algorithm was recently constructed that allows generating long C-system trajectories very rapidly. These trajectories have good statistical properties and can be used for calculations in quantum chromodynamics and in high energy particle physics.

  14. Solar system plasma waves

    NASA Technical Reports Server (NTRS)

    Gurnett, Donald A.

    1995-01-01

    An overview is given of spacecraft observations of plasma waves in the solar system. In situ measurements of plasma phenomena have now been obtained at all of the planets except Mercury and Pluto, and in the interplanetary medium at heliocentric radial distances ranging from 0.29 to 58 AU. To illustrate the range of phenomena involved, we discuss plasma waves in three regions of physical interest: (1) planetary radiation belts, (2) planetary auroral acceleration regions and (3) the solar wind. In each region we describe examples of plasma waves that are of some importance, either due to the role they play in determining the physical properties of the plasma, or to the unique mechanism involved in their generation.

  15. The physical properties and ion release of CPP-ACP-modified calcium silicate-based cements.

    PubMed

    Dawood, A E; Manton, D J; Parashos, P; Wong, Rhk; Palamara, Jea; Stanton, D P; Reynolds, E C

    2015-12-01

    This study investigated the physical properties and ion release of casein phosphopeptide-amorphous calcium phosphate (CPP-ACP)-modified calcium silicate-based cements (CSCs) and compared the properties of a trial mineral trioxide aggregate (MTA) with two commercially available CSCs, Biodentine(™) and Angelus(®) MTA. The setting time, solubility, compressive strength and Vickers surface microhardness of the three CSCs incorporated with 0%, 0.5%, 1.0%, 2.0% and 3.0% (w/w) CPP-ACP were investigated. Release of calcium (Ca(2+) ), phosphate ions (Pi ) and pH of the test cements were measured after 24, 72, 168 and 336 h of storage. The addition of up to 1.0% CPP-ACP into Biodentine(™) and 0.5% into the other cements did not adversely affect their physical properties except for the setting time. The addition of 0.5% CPP-ACP increased Ca(2+) released from Biodentine(™) (after 168 and 336 h), Angelus(®) MTA (after 168 h) and the trial MTA (after 72 h). The addition of 1.0-3.0% CPP-ACP increased Ca(2+) and Pi released from all the cements. Biodentine(™) released more Ca(2+) particularly in the early stages and showed shorter setting time and higher mechanical properties than the other cements. The mechanical properties of Angelus(®) MTA and the trial MTA were similar. All the cements produced highly alkaline storage solutions. Up to 1.0% CPP-ACP in Biodentine(™) improves Ca(2+) and Pi release and 0.5% CPP-ACP in Angelus(®) MTA and the trial MTA improves Ca(2+) release without altering the mechanical properties and solubility. The addition of CPP-ACP into CSCs prolonged the setting time. © 2015 Australian Dental Association.

  16. Unsteady Thermocapillary Migration of Isolated Drops in Creeping Flow

    NASA Technical Reports Server (NTRS)

    Dill, Loren H.; Balasubramaniam, R.

    1992-01-01

    The problem of an isolated immiscible drop that slowly migrates due to unsteady thermocapillary stresses is considered. All physical properties except for interfacial tension are assumed constant for the two Newtonian fluids. Explicit expressions are found for the migration rate and stream functions in the Laplace domain. The resulting microgravity theory is useful, e.g., in predicting the distance a drop will migrate due to an impulsive interfacial temperature gradient as well as the time required to attain steady flow conditions from an initially resting state.

  17. The slow X-ray pulsar SXP 1062 and associated supernova remnant in the Wing of the Small Magellanic Cloud

    NASA Astrophysics Data System (ADS)

    Oskinova, L. M.; Guerrero, M. A.; Hénault-Brunet, V.; Sun, W.; Chu, Y.-H.; Evans, C.; Gallagher, J. S.; Gruendl, R. A.; Reyes-Iturbide, J.

    2013-03-01

    SXP 1062 is an exceptional case of a young neutron star in a wind-fed high-mass X-ray binary associated with a supernova remnant. A unique combination of measured spin period, its derivative, luminosity and young age makes this source a key probe for the physics of accretion and neutron star evolution. Theoretical models proposed to explain the properties of SXP 1062 shall be tested with new data.

  18. 5 CFR 532.313 - Private sector industries.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... the physical, engineering, and life sciences (except biotechnology). 56172 Janitorial services. 62191... Research and development in the physical, engineering, and life sciences (except biotechnology). Heavy Duty...

  19. 5 CFR 532.313 - Private sector industries.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... the physical, engineering, and life sciences (except biotechnology). 56172 Janitorial services. 62191... Research and development in the physical, engineering, and life sciences (except biotechnology). Heavy Duty...

  20. 5 CFR 532.313 - Private sector industries.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... the physical, engineering, and life sciences (except biotechnology). 56172 Janitorial services. 62191... Research and development in the physical, engineering, and life sciences (except biotechnology). Heavy Duty...

  1. 5 CFR 532.313 - Private sector industries.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... the physical, engineering, and life sciences (except biotechnology). 56172 Janitorial services. 62191... Research and development in the physical, engineering, and life sciences (except biotechnology). Heavy Duty...

  2. Characteristics of W-26% Re Target Material(LCC-0103)

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Sunwoo, A.

    2003-10-07

    The W-26 wt-% Re alloy was selected as a Stanford Linear Collider (SLC) target material for its exceptional physics properties and for the high strength and good ductility at the anticipated target operating temperatures, above the DBTT. After several years of operation, the target failed catastrophically. A detailed microstructural and mechanical characterization of the non-irradiated disk indicates that the material has been PM processed, nonuniformly mechanically worked and stress relieved. As a result, the ductility of the material varies through the thickness of the disk, making it difficult to determine the DBTT. The results of tensile and fatigue properties aremore » reported with the corresponding fractography of the fracture surfaces.« less

  3. Role of Physical Bolus Properties as Sensory Inputs in the Trigger of Swallowing

    PubMed Central

    Peyron, Marie-Agnès; Gierczynski, Isabelle; Hartmann, Christoph; Loret, Chrystel; Dardevet, Dominique; Martin, Nathalie; Woda, Alain

    2011-01-01

    Background Swallowing is triggered when a food bolus being prepared by mastication has reached a defined state. However, although this view is consensual and well supported, the physical properties of the swallowable bolus have been under-researched. We tested the hypothesis that measuring bolus physical changes during the masticatory sequence to deglutition would reveal the bolus properties potentially involved in swallowing initiation. Methods Twenty normo-dentate young adults were instructed to chew portions of cereal and spit out the boluses at different times in the masticatory sequence. The mechanical properties of the collected boluses were measured by a texture profile analysis test currently used in food science. The median particle size of the boluses was evaluated by sieving. In a simultaneous sensory study, twenty-five other subjects expressed their perception of bolus texture dominating at any mastication time. Findings Several physical changes appeared in the food bolus as it was formed during mastication: (1) in rheological terms, bolus hardness rapidly decreased as the masticatory sequence progressed, (2) by contrast, adhesiveness, springiness and cohesiveness regularly increased until the time of swallowing, (3) median particle size, indicating the bolus particle size distribution, decreased mostly during the first third of the masticatory sequence, (4) except for hardness, the rheological changes still appeared in the boluses collected just before swallowing, and (5) physical changes occurred, with sensory stickiness being described by the subjects as a dominant perception of the bolus at the end of mastication. Conclusions Although these physical and sensory changes progressed in the course of mastication, those observed just before swallowing seem to be involved in swallowing initiation. They can be considered as strong candidates for sensory inputs from the bolus that are probably crucially involved in the triggering of swallowing, since they appeared in boluses prepared in various mastication strategies by different subjects. PMID:21738616

  4. Temporal and vertical variability in optical properties of New England shelf waters during late summer and spring

    NASA Astrophysics Data System (ADS)

    Sosik, Heidi M.; Green, Rebecca E.; Pegau, W. Scott; Roesler, Collin S.

    2001-05-01

    Relationships between optical and physical properties were examined on the basis of intensive sampling at a site on the New England continental shelf during late summer 1996 and spring 1997. During both seasons, particles were found to be the primary source of temporal and vertical variability in optical properties since light absorption by dissolved material, though significant in magnitude, was relatively constant. Within the particle pool, changes in phytoplankton were responsible for much of the observed optical variability. Physical processes associated with characteristic seasonal patterns in stratification and mixing contributed to optical variability mostly through effects on phytoplankton. An exception to this generalization occurred during summer as the passage of a hurricane led to a breakdown in stratification and substantial resuspension of nonphytoplankton particulate material. Prior to the hurricane, conditions in summer were highly stratified with subsurface maxima in absorption and scattering coefficients. In spring, stratification was much weaker but increased over the sampling period, and a modest phytoplankton bloom caused surface layer maxima in absorption and scattering coefficients. These seasonal differences in the vertical distribution of inherent optical properties were evident in surface reflectance spectra, which were elevated and shifted toward blue wavelengths in the summer. Some seasonal differences in optical properties, including reflectance spectra, suggest that a significant shift toward a smaller particle size distribution occurred in summer. Shorter timescale optical variability was consistent with a variety of influences including episodic events such as the hurricane, physical processes associated with shelfbreak frontal dynamics, biological processes such as phytoplankton growth, and horizontal patchiness combined with water mass advection.

  5. Nanofluidic transport through isolated carbon nanotube channels: Advances, controversies, and challenges

    DOE PAGES

    Guo, Shirui; Meshot, Eric R.; Kuykendall, Tevye; ...

    2015-06-02

    Owing to their simple chemistry and structure, controllable geometry, and a plethora of unusual yet exciting transport properties, carbon nanotubes (CNTs) have emerged as exceptional channels for fundamental nanofluidic studies, as well as building blocks for future fluidic devices that can outperform current technology in many applications. Leveraging the unique fluidic properties of CNTs in advanced systems requires a full understanding of their physical origin. Recent advancements in nanofabrication technology enable nanofluidic devices to be built with a single, nanometer-wide CNT as a fluidic pathway. These novel platforms with isolated CNT nanochannels offer distinct advantages for establishing quantitative structure–transport correlationsmore » in comparison with membranes containing many CNT pores. In addition, they are promising components for single-molecule sensors as well as for building nanotube-based circuits wherein fluidics and electronics can be coupled. With such advanced device architecture, molecular and ionic transport can be manipulated with vastly enhanced control for applications in sensing, separation, detection, and therapeutic delivery. Recent achievements in fabricating isolated-CNT nanofluidic platforms are highlighted, along with the most-significant findings each platform enables for water, ion, and molecular transport. Furthermore, the implications of these findings and remaining open questions on the exceptional fluidic properties of CNTs are also discussed.« less

  6. 7 CFR 1955.81 - Exception authority.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 14 2010-01-01 2009-01-01 true Exception authority. 1955.81 Section 1955.81 Agriculture Regulations of the Department of Agriculture (Continued) RURAL HOUSING SERVICE, RURAL BUSINESS...) PROGRAM REGULATIONS (CONTINUED) PROPERTY MANAGEMENT Management of Property § 1955.81 Exception authority...

  7. 41 CFR 109-38.403-3 - Exceptions.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 41 Public Contracts and Property Management 3 2011-01-01 2011-01-01 false Exceptions. 109-38.403-3 Section 109-38.403-3 Public Contracts and Property Management Federal Property Management Regulations System (Continued) DEPARTMENT OF ENERGY PROPERTY MANAGEMENT REGULATIONS AVIATION, TRANSPORTATION, AND...

  8. 41 CFR 109-38.403-3 - Exceptions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Exceptions. 109-38.403-3 Section 109-38.403-3 Public Contracts and Property Management Federal Property Management Regulations System (Continued) DEPARTMENT OF ENERGY PROPERTY MANAGEMENT REGULATIONS AVIATION, TRANSPORTATION, AND...

  9. Direct Preparation of Few Layer Graphene Epoxy Nanocomposites from Untreated Flake Graphite.

    PubMed

    Throckmorton, James; Palmese, Giuseppe

    2015-07-15

    The natural availability of flake graphite and the exceptional properties of graphene and graphene-polymer composites create a demand for simple, cost-effective, and scalable methods for top-down graphite exfoliation. This work presents a novel method of few layer graphite nanocomposite preparation directly from untreated flake graphite using a room temperature ionic liquid and laminar shear processing regimen. The ionic liquid serves both as a solvent and initiator for epoxy polymerization and is incorporated chemically into the matrix. This nanocomposite shows low electrical percolation (0.005 v/v) and low thickness (1-3 layers) graphite/graphene flakes by TEM. Additionally, the effect of processing conditions by rheometry and comparison with solvent-free conditions reveal the interactions between processing and matrix properties and provide insight into the theory of the chemical and physical exfoliation of graphite crystals and the resulting polymer matrix dispersion. An interaction model that correlates the interlayer shear physics of graphite flakes and processing parameters is proposed and tested.

  10. Comparative study of the physical properties of core materials.

    PubMed

    Saygili, Gülbin; Mahmali, Sevil M

    2002-08-01

    This study was undertaken to measure physical properties of materials used for direct core buildups, including high-copper amalgam, visible light-cured resin composite, autocured titanium-containing composite, polyacid-modified composite, resin-modified glass-ionomer, and silver cermet cement. Compressive strength, diametral tensile strength, and flexural strength of six core materials of various material classes were measured for each material as a function of time up to 3 months at different storage conditions, using a standard specification test designed for the materials. Three different storage conditions (dry, humid, wet) at 37 degrees C were chosen. Materials were manipulated according to manufacturers' instructions for use as cores. Mean compressive, diametral tensile, and flexural strengths with associated standard deviations were calculated for each material. Multiple comparison and Newman-Keuls tests discerned many differences among materials. All materials were found to meet the minimum specification requirements, except in terms of flexural strength for amalgam after 1 hour and the silver cermet at all time intervals.

  11. Valley excitons in two-dimensional semiconductors

    DOE PAGES

    Yu, Hongyi; Cui, Xiaodong; Xu, Xiaodong; ...

    2014-12-30

    Monolayer group-VIB transition metal dichalcogenides have recently emerged as a new class of semiconductors in the two-dimensional limit. The attractive properties include: the visible range direct band gap ideal for exploring optoelectronic applications; the intriguing physics associated with spin and valley pseudospin of carriers which implies potentials for novel electronics based on these internal degrees of freedom; the exceptionally strong Coulomb interaction due to the two-dimensional geometry and the large effective masses. The physics of excitons, the bound states of electrons and holes, has been one of the most actively studied topics on these two-dimensional semiconductors, where the excitons exhibitmore » remarkably new features due to the strong Coulomb binding, the valley degeneracy of the band edges, and the valley dependent optical selection rules for interband transitions. Here we give a brief overview of the experimental and theoretical findings on excitons in two-dimensional transition metal dichalcogenides, with focus on the novel properties associated with their valley degrees of freedom.« less

  12. Vacuum thermal evaporation of polyaniline doped with camphor sulfonic acid

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Boyne, Devon; Menegazzo, Nicola; Pupillo, Rachel C.

    2015-05-15

    Intrinsically conducting polymers belong to a class of organic polymers with intriguing electronic and physical properties specifically for electro-optical applications. Significant interest into doped polyaniline (PAni) can be attributed to its high conductivity and environmental stability. Poor dissolution in most solvents has thus far hindered the successful integration of PAni into commercial applications, which in turn, has led to the investigations of various deposition and acidic doping methods. Physical vapor deposition methods, including D.C. magnetron sputtering and vacuum thermal evaporation, have shown exceptional control over physical film properties (thickness and morphology). However, resulting films are less conductive than films depositedmore » by conventional methods (i.e., spin and drop casting) due to interruption of the hyperconjugation of polymer chains. Specifically, vacuum thermal evaporation requires a postdoping process, which results in incorporation of impurities and oxidation of surface moieties. In this contribution, thermally evaporated films, sequentially doped by vacuum evaporation of an organic acid (camphorsulfonic acid, CSA) is explored. Spectroscopic evidence confirms the successful doping of PAni with CSA while physical characterization (atomic force microscopy) suggests films retain good morphology and are not damaged by the doping process. The procedure presented herein also combines other postpreparation methods in an attempt to improve conductivity and/or substrate adhesion.« less

  13. Development of a SaaS application probe to the physical properties of the Earth's interior: An attempt at moving HPC to the cloud

    NASA Astrophysics Data System (ADS)

    Huang, Qian

    2014-09-01

    Scientific computing often requires the availability of a massive number of computers for performing large-scale simulations, and computing in mineral physics is no exception. In order to investigate physical properties of minerals at extreme conditions in computational mineral physics, parallel computing technology is used to speed up the performance by utilizing multiple computer resources to process a computational task simultaneously thereby greatly reducing computation time. Traditionally, parallel computing has been addressed by using High Performance Computing (HPC) solutions and installed facilities such as clusters and super computers. Today, it has been seen that there is a tremendous growth in cloud computing. Infrastructure as a Service (IaaS), the on-demand and pay-as-you-go model, creates a flexible and cost-effective mean to access computing resources. In this paper, a feasibility report of HPC on a cloud infrastructure is presented. It is found that current cloud services in IaaS layer still need to improve performance to be useful to research projects. On the other hand, Software as a Service (SaaS), another type of cloud computing, is introduced into an HPC system for computing in mineral physics, and an application of which is developed. In this paper, an overall description of this SaaS application is presented. This contribution can promote cloud application development in computational mineral physics, and cross-disciplinary studies.

  14. ADAPTED PHYSICAL EDUCATION, PRINCIPLES AND PRACTICE OF PHYSICAL EDUCATION FOR EXCEPTIONAL STUDENTS. SECOND EDITION.

    ERIC Educational Resources Information Center

    DANIELS, ARTHUR S.; DAVIES, EVELYN A.

    THIS BOOK HAS THREE PURPOSES--(1) TO SHOW HOW PHYSICAL EDUCATION ACTIVITIES MAY BE ADAPTED FOR EXCEPTIONAL STUDENTS AT ALL LEVELS OF SCHOOL, (2) TO SERVE AS A PRACTICAL GUIDE TO PHYSICAL EDUCATION PERSONNEL WHO WISH TO WORK FOR FULL DEVELOPMENT OF EACH STUDENT, AND (3) TO SERVE AS A TEXT FOR STUDENTS IN TRAINING, TEACHERS, AND THERAPISTS. PART ONE…

  15. Production of drug nanosuspensions: effect of drug physical properties on nanosizing efficiency.

    PubMed

    Liu, Tao; Müller, Rainer H; Möschwitzer, Jan P

    2018-02-01

    Drug nanosuspension is one of the established methods to improve the bioavailability of poorly soluble drugs. Drug physical properties aspect (morphology, solid state, starting size et al) is a critical parameter determining the production efficiency. Some drug modification approaches such as spray-drying were proved to improve the millability of drug powders. However, the mechanism behind those improved performances is unclear. This study is to systematically investigate the influence of those physical properties. Five different APIs (active pharmaceutical ingredients) with different millabilities, i.e. resveratrol, hesperetin, glibenclamide, rutin, and quercetin, were processed by standard high pressure homogenization (HPH), wet bead milling (WBM), and a combinative method of spray-drying and HPH. Smaller starting sizes of certain APIs could accelerate the particle size reduction velocity during both HPH and WBM processes. Spherical particles were observed for almost all spray-dried powders (except spray-dried hesperetin) after spray-drying. The crystallinity of some spray-dried samples such as rutin and glibenclamide became much lower than their corresponding unmodified powders. Almost all spray-dried drug powders after HPH processes could lead to smaller nanocrystal particle size than unmodified APIs. The modified microstructure instead of solid state after spray-drying explained the potential reason for improved nanosizing efficiency. In addition, the contribution of starting size on the production efficiency was also critical according to both HPH and WBM results.

  16. Association of exceptional parental longevity and physical function in aging.

    PubMed

    Ayers, Emmeline; Barzilai, Nir; Crandall, Jill P; Milman, Sofiya; Verghese, Joe

    2014-01-01

    Offspring of parents with exceptional longevity (OPEL), who are more likely to carry longevity-associated genotypes, may age more successfully than offspring of parents with usual survival (OPUS). Maintenance of physical function is a key attribute of successful aging. While many genetic and non-genetic factors interact to determine physical phenotype in aging, examination of the contribution of exceptional parental longevity to physical function in aging is limited. The LonGenity study recruited a relatively genetically homogenous cohort of Ashkenazi Jewish (AJ) adults age 65 and older, who were defined as either OPEL (having at least one parent who lived to age 95 or older) or OPUS (neither parent survived to age 95). Subjective and objective measures of physical function were compared between the two groups, accounting for potential confounders. Of the 893 LonGenity subjects, 365 were OPEL and 528 were OPUS. OPEL had better objective and subjective measures of physical function than OPUS, especially on unipedal stance (p = 0.009) and gait speed (p = 0.002). Results support the protective role of exceptional parental longevity in preventing decline in physical function, possibly via genetic mechanisms that should be further explored.

  17. The Effect of Different Mixing Methods on Working Time, Setting Time, Dimensional Changes and Film Thickness of Mineral Trioxide Aggregate and Calcium-Enriched Mixture.

    PubMed

    Shahi, Shahriar; Ghasemi, Negin; Rahimi, Saeed; Yavari, Hamidreza; Janani, Maryam; Mokhtari, Hadi; Bahari, Mahmood; Rabbani, Parastu

    2015-01-01

    The aim of the present study was to evaluate the effect of different mixing techniques (conventional, amalgamator and ultrasonic mixing) on the physical properties the working time (WT), setting time (ST), dimensional changes (DC) and film thickness (FT)] of calcium-enriched mixture (CEM) cement and mineral trioxide aggregate (MTA). The mentioned physical properties were determined using the ISO 6786:2001 specification. Six samples of each material were prepared for three mixing techniques (totally 36 samples). Data were analyzed using descriptive statistics, two-way ANOVA and Post Hoc Tukey's tests. The level of significance was defined at 0.05. Irrespective of mixing technique, there was no significant difference between the WT and FT of the tested materials. Except for the DC of MTA and the FT of the all materials, other properties were significantly affected with mixing techniques (P<0.05). The ultrasonic technique decreased the ST of MTA and CEM cement and increased the WT of CEM cement (P<0.05). The mixing technique of the materials had no significant effect on the dimensional changes of MTA and the film thickness of both materials.

  18. Characterization of maximally random jammed sphere packings. III. Transport and electromagnetic properties via correlation functions

    NASA Astrophysics Data System (ADS)

    Klatt, Michael A.; Torquato, Salvatore

    2018-01-01

    In the first two papers of this series, we characterized the structure of maximally random jammed (MRJ) sphere packings across length scales by computing a variety of different correlation functions, spectral functions, hole probabilities, and local density fluctuations. From the remarkable structural features of the MRJ packings, especially its disordered hyperuniformity, exceptional physical properties can be expected. Here we employ these structural descriptors to estimate effective transport and electromagnetic properties via rigorous bounds, exact expansions, and accurate analytical approximation formulas. These property formulas include interfacial bounds as well as universal scaling laws for the mean survival time and the fluid permeability. We also estimate the principal relaxation time associated with Brownian motion among perfectly absorbing traps. For the propagation of electromagnetic waves in the long-wavelength limit, we show that a dispersion of dielectric MRJ spheres within a matrix of another dielectric material forms, to a very good approximation, a dissipationless disordered and isotropic two-phase medium for any phase dielectric contrast ratio. We compare the effective properties of the MRJ sphere packings to those of overlapping spheres, equilibrium hard-sphere packings, and lattices of hard spheres. Moreover, we generalize results to micro- and macroscopically anisotropic packings of spheroids with tensorial effective properties. The analytic bounds predict the qualitative trend in the physical properties associated with these structures, which provides guidance to more time-consuming simulations and experiments. They especially provide impetus for experiments to design materials with unique bulk properties resulting from hyperuniformity, including structural-color and color-sensing applications.

  19. 26 CFR 1.367(a)-2 - Exception for transfers of property for use in the active conduct of a trade or business.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 26 Internal Revenue 4 2014-04-01 2014-04-01 false Exception for transfers of property for use in the active conduct of a trade or business. 1.367(a)-2 Section 1.367(a)-2 Internal Revenue INTERNAL...) Effects on Corporation § 1.367(a)-2 Exception for transfers of property for use in the active conduct of a...

  20. Involvement & Participation. National Conference on Physical Activity for the Exceptional Individual (11th, San Diego, California, November 19-20, 1982).

    ERIC Educational Resources Information Center

    Greaves, Edward R.; Richmond, Alan

    This publication contains papers, presented at a conference about physical activities for the exceptional individual, concerning: (1) student interest/motivation; (2) swimming; (3) games; (4) wheelchairs; (5) movement education; (6) physical stress and bone growth; (7) parent involvement; (8) meningomyelocele; (9) blind athletes; (10) Project…

  1. 41 CFR 102-74.170 - May exceptions to the energy conservation policies in this subpart be granted?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... and Property Management Federal Property Management Regulations System (Continued) FEDERAL MANAGEMENT REGULATION REAL PROPERTY 74-FACILITY MANAGEMENT Facility Management Energy Conservation § 102-74.170 May... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false May exceptions to the...

  2. Tissue deposition and toxicological effects of commercially significant rare earth oxide nanomaterials: Material and physical properties.

    PubMed

    Das, Soumen; Reed McDonagh, Philip; Selvan Sakthivel, Tamil; Barkam, Swetha; Killion, Kelsey; Ortiz, Julian; Saraf, Shashank; Kumar, Amit; Gupta, Ankur; Zweit, Jamal; Seal, Sudipta

    2017-03-01

    Rare earth oxide (REO) materials are found naturally in earth's crust and at the nanoscale these REO nanoparticles exhibit unique thermal, electrical, and physicochemical properties. REO nanoparticles are widely used in different industrial sectors for ceramics, glass polishing, metallurgy, lasers, and magnets. Recently, some of these REO nanoparticles have been identified for their potential application in medicine, including therapy, imaging, and diagnostics. Concurrent research into the REO nanomaterials' toxicities has also raised concern for their environmental impacts. The correlation of REO nanoparticles mediated toxicity with their physiochemical properties can help to design nanoparticles with minimal effect on the environment and living organisms. In vitro assay revealed toxicity toward Human squamous epithelial cell line (CCL30) and Human umbilical vascular endothelial cells (HUVEC) at a concentration of 100 µM and higher. In vivo results showed, with the exception of CeO 2 and Gd 2 O 3 , most of the naoparticles did not clear or had minimum clearance (10-20%) from the system. Elevated levels of alanine transferase were seen for animals given each different nanoparticle, however the increases were not significant for CeO 2 and Dy 2 O 3 . Nephrotoxicity was only seen in case of Dy 2 O 3 and Gd 2 O 3 . Lastly, histological examination revealed presence of swollen hepatocytes which further confirms toxicity of the commercial REO nanomaterials. The in vivo toxicity is mainly due to excessive tissue deposition (70-90%) due to the commercial REO nanoparticles' poor physical properties (shape, stability, and extent of agglomeration). Therefore, optimization of nanoparticles physical properties is very important. © 2016 Wiley Periodicals, Inc. Environ Toxicol 32: 904-917, 2017. © 2016 Wiley Periodicals, Inc.

  3. Correlating Microstructure and Optoelectronic Performance of Carbon-Based Nanomaterials

    NASA Astrophysics Data System (ADS)

    Rochford, Caitlin

    There is a great deal of interest in carbon nanostructures such as graphene and various forms of carbon nanotubes due to their exceptional physical, electronic, and optical properties. Many technological applications have been proposed for these nanostructures, but despite the promise many carbon nanostructure-based optoelectronic devices fail to compete with their conventional counterparts. This is often due in large part to a non-optimized material or device microstructure. Factors such as crystallinity, contact quality, defect structure, and device configuration can critically affect device performance due to the high sensitivity and extreme surface to volume ratio of carbon nanostructures. In order for the exceptional intrinsic properties of the nanostructures to be exploited, a clear understanding of the microstructure and its correlation with device-relevant optoelectronic properties is needed. This dissertation presents four projects which demonstrate this principle. First, a TiO 2-coated carbon nanofiber is studied in order to optimize its structure for use in a novel dye-sensitized solar cell. Second, the electrode configuration of an individual multiwall carbon nanotube infrared sensor is investigated in order to surpass the limitations of disordered nanotube film-based infrared sensors. Third, the properties of defect structures in large area transferred graphene films grown by chemical vapor deposition are correlated with carrier diffusion in order to understand the film's low mobility compared to exfoliated graphene. Fourth, the effect of deposition conditions on graphene-metal contact was studied with the goal of achieving sufficiently transparent contacts for investigation of the superconducting proximity effect. All four projects highlight the unique properties of carbon nanostructures as well as the need to correlate their optoelectronic properties with microstructural details in order to achieve the desired device performance.

  4. Two-Dimensional Semiconductor Optoelectronics Based on van der Waals Heterostructures.

    PubMed

    Lee, Jae Yoon; Shin, Jun-Hwan; Lee, Gwan-Hyoung; Lee, Chul-Ho

    2016-10-27

    Two-dimensional (2D) semiconductors such as transition metal dichalcogenides (TMDCs) and black phosphorous have drawn tremendous attention as an emerging optical material due to their unique and remarkable optical properties. In addition, the ability to create the atomically-controlled van der Waals (vdW) heterostructures enables realizing novel optoelectronic devices that are distinct from conventional bulk counterparts. In this short review, we first present the atomic and electronic structures of 2D semiconducting TMDCs and their exceptional optical properties, and further discuss the fabrication and distinctive features of vdW heterostructures assembled from different kinds of 2D materials with various physical properties. We then focus on reviewing the recent progress on the fabrication of 2D semiconductor optoelectronic devices based on vdW heterostructures including photodetectors, solar cells, and light-emitting devices. Finally, we highlight the perspectives and challenges of optoelectronics based on 2D semiconductor heterostructures.

  5. Properties of ultra low frequency upstream waves at Venus and Saturn: A comparison

    NASA Technical Reports Server (NTRS)

    Orlowski, D. S.; Russell, C. T.; Krauss-Varban, D.; Omidi, N.

    1995-01-01

    The upstream regions of all planets, except Pluto, have been investigated, using in situ spacecraft measurements and a variety of analysis techniques. The detailed studies at Earth indicate that these waves are generated locally in the magnetically connected solar wind by the interaction with ions backstreaming from the shock. However, since the properties of the solar wind vary with heliocentric distance and since properties of planetary shocks depend on plasma beta, interplanetary magnetic field (IMF) spiral angle and Mach number, the amount of heating, acceleration efficiencies, etc. significantly change with heliocentric distance. In turn the waves seen at each planet propagate not in the same but different (physical) propagation modes. In this paper we compare the ULF wave observations at an outer and an inner planet. We use the results of the ratio, quantites easily derivable with sufficient accuracy at each planet. We use the full electromagnetic dispersion relation for comparison with theoretical predictions.

  6. Two-Dimensional Semiconductor Optoelectronics Based on van der Waals Heterostructures

    PubMed Central

    Lee, Jae Yoon; Shin, Jun-Hwan; Lee, Gwan-Hyoung; Lee, Chul-Ho

    2016-01-01

    Two-dimensional (2D) semiconductors such as transition metal dichalcogenides (TMDCs) and black phosphorous have drawn tremendous attention as an emerging optical material due to their unique and remarkable optical properties. In addition, the ability to create the atomically-controlled van der Waals (vdW) heterostructures enables realizing novel optoelectronic devices that are distinct from conventional bulk counterparts. In this short review, we first present the atomic and electronic structures of 2D semiconducting TMDCs and their exceptional optical properties, and further discuss the fabrication and distinctive features of vdW heterostructures assembled from different kinds of 2D materials with various physical properties. We then focus on reviewing the recent progress on the fabrication of 2D semiconductor optoelectronic devices based on vdW heterostructures including photodetectors, solar cells, and light-emitting devices. Finally, we highlight the perspectives and challenges of optoelectronics based on 2D semiconductor heterostructures. PMID:28335321

  7. Few effects of invasive plants Reynoutria japonica, Rudbeckia laciniata and Solidago gigantea on soil physical and chemical properties.

    PubMed

    Stefanowicz, Anna M; Stanek, Małgorzata; Nobis, Marcin; Zubek, Szymon

    2017-01-01

    Biological invasions are an important problem of human-induced changes at a global scale. Invasive plants can modify soil nutrient pools and element cycling, creating feedbacks that potentially stabilize current or accelerate further invasion, and prevent re-establishment of native species. The aim of this study was to compare the effects of Reynoutria japonica, Rudbeckia laciniata and Solidago gigantea, invading non-forest areas located within or outside river valleys, on soil physical and chemical parameters, including soil moisture, element concentrations, organic matter content and pH. Additionally, invasion effects on plant species number and total plant cover were assessed. The concentrations of elements in shoots and roots of invasive and native plants were also measured. Split-plot ANOVA revealed that the invasions significantly reduced plant species number, but did not affect most soil physical and chemical properties. The invasions decreased total P concentration and increased N-NO 3 concentration in soil in comparison to native vegetation, though the latter only in the case of R. japonica. The influence of invasion on soil properties did not depend on location (within- or outside valleys). The lack of invasion effects on most soil properties does not necessarily imply the lack of influence of invasive plants, but may suggest that the direction of the changes varies among replicate sites and there are no general patterns of invasion-induced alterations for these parameters. Tissue element concentrations, with the exception of Mg, did not differ between invasive and native plants, and were not related to soil element concentrations. Copyright © 2016 Elsevier B.V. All rights reserved.

  8. Physical-Mechanical Properties and Micromorphology of Calcium Cements Exposed to Polyacrylic and Phosphoric Acids.

    PubMed

    de Souza, Gustavo Fernandes; Arrais, Ana Beatriz; Aragão, Cícero Flávio Soares; Ferreira, Isana Alvares; Borges, Boniek Castillo Dutra

    2018-01-01

    To evaluate if physical and mechanical properties of self-curing calcium hydroxide cements were affected by contact with polyacrylic and phosphoric acids. Resin-containing (Life (LF)) and resin-free (Hydro C (HyC)) materials were subjected to polyacrylic acid conditioning and rinsing (POL); phosphoric acid conditioning and rinsing (PHO); rinsing only; and no treatment ( n = 10). Water sorption/solubility, release of hydroxyl ions (pH), roughness (Ra), and impact resistance were evaluated. Additional samples ( n = 1) were prepared for scanning electron microscopy (SEM) analysis of the surface morphology. Data were analyzed by two-way ANOVA and Tukey post hoc test ( P < 0.05). Water sorption was significantly higher for LF when in contact with PHO and lower for POL ( P < 0.05). The mean solubility was higher with POL for both cements ( P < 0.05). PHO increased the mean surface roughness for HyC ( P < 0.01); a significant decrease was noted for LF after contact with both acids ( P < 0.01). PHO promoted lower release of hydroxyl ions on both cements ( P < 0.05). For LF, rinsing, PHO, and POL presented similar morphology, differing from the control group. For HyC, PHO and POL presented similar morphology, differing from the control group. PHO had a negative effect on the physical properties of the cements tested, except for the solubility test. POL affected roughness and solubility of HyC cement. Clinical procedures that require polyacrylic and phosphoric acid conditioning must be done carefully on self-curing calcium hydroxide cements in order to avoid negative impact on their properties.

  9. 41 CFR 60-30.19 - Objections; exceptions; offer of proof.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 41 Public Contracts and Property Management 1 2011-07-01 2009-07-01 true Objections; exceptions; offer of proof. 60-30.19 Section 60-30.19 Public Contracts and Property Management Other Provisions... EXECUTIVE ORDER 11246 Hearings and Related Matters § 60-30.19 Objections; exceptions; offer of proof. (a...

  10. 41 CFR 60-30.19 - Objections; exceptions; offer of proof.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 1 2010-07-01 2010-07-01 true Objections; exceptions; offer of proof. 60-30.19 Section 60-30.19 Public Contracts and Property Management Other Provisions... EXECUTIVE ORDER 11246 Hearings and Related Matters § 60-30.19 Objections; exceptions; offer of proof. (a...

  11. Fuel Thermo-physical Characterization Project. Fiscal Year 2014 Final Report

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Burkes, Douglas; Casella, Andrew M.; Buck, Edgar C.

    2015-03-15

    The Office of Material Management and Minimization (M3) Reactor Conversion Fuel Thermo-Physical Characterization Project at Pacific Northwest National Laboratory (PNNL) was tasked with using PNNL facilities and processes to receive irradiated low enriched uranium–molybdenum (LEU-Mo) fuel plate samples and perform analysis in support of the M3 Reactor Conversion Program. This work is in support of the M3 Reactor Conversion Fuel Development Pillar that is managed by Idaho National Laboratory. The primary research scope was to determine the thermo-physical properties as a function of temperature and burnup. Work conducted in Fiscal Year (FY) 2014 complemented measurements performed in FY 2013 onmore » four additional irradiated LEU-Mo fuel plate samples. Specifically, the work in FY 2014 investigated the influence of different processing methods on thermal property behavior, the absence of aluminum alloy cladding on thermal property behavior for additional model validation, and the influence of higher operating surface heat flux / more aggressive irradiation conditions on thermal property behavior. The model developed in FY 2013 and refined in FY 2014 to extract thermal properties of the U-Mo alloy from the measurements conducted on an integral fuel plate sample (i.e., U-Mo alloy with a thin Zr coating and clad in AA6061) continues to perform very well. Measurements conducted in FY 2014 on samples irradiated under similar conditions compare well to measurements performed in FY 2013. In general, there is no gross influence of fabrication method on thermal property behavior, although the difference in LEU-Mo foil microstructure does have a noticeable influence on recrystallization of grains during irradiation. Samples irradiated under more aggressive irradiation conditions, e.g., higher surface heat flux, revealed lower thermal conductivity when compared to samples irradiated at moderate surface heat fluxes, with the exception of one sample. This report documents thermal property measurements conducted in FY 2014 and compares results to values obtained from literature and measurements performed in FY 2013, where applicable, along with appropriate discussion.« less

  12. Effect of annealing over optoelectronic properties of graphene based transparent electrodes

    NASA Astrophysics Data System (ADS)

    Yadav, Shriniwas; Kaur, Inderpreet

    2016-04-01

    Graphene, an atom-thick two dimensional graphitic material have led various fundamental breakthroughs in the field of science and technology. Due to their exceptional optical, physical and electrical properties, graphene based transparent electrodes have shown several applications in organic light emitting diodes, solar cells and thin film transistors. Here, we are presenting effect of annealing over optoelectronic properties of graphene based transparent electrodes. Graphene based transparent electrodes have been prepared by wet chemical approach over glass substrates. After fabrication, these electrodes tested for optical transmittance in visible region. Sheet resistance was measured using four probe method. Effect of thermal annealing at 200 °C was studied over optical and electrical performance of these electrodes. Optoelectronic performance was judged from ratio of direct current conductivity to optical conductivity (σdc/σopt) as a figure of merit for transparent conductors. The fabricated electrodes display good optical and electrical properties. Such electrodes can be alternatives for doped metal oxide based transparent electrodes.

  13. 41 CFR 102-75.210 - What must a transferee agency include in its request for an exception from the 100 percent...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Section 102-75.210 Public Contracts and Property Management Federal Property Management Regulations System (Continued) FEDERAL MANAGEMENT REGULATION REAL PROPERTY 75-REAL PROPERTY DISPOSAL Utilization of Excess Real... exception would further essential agency program objectives and at the same time be consistent with...

  14. Models of violently relaxed galaxies

    NASA Astrophysics Data System (ADS)

    Merritt, David; Tremaine, Scott; Johnstone, Doug

    1989-02-01

    The properties of spherical self-gravitating models derived from two distribution functions that incorporate, in a crude way, the physics of violent relaxation are investigated. The first distribution function is identical to the one discussed by Stiavelli and Bertin (1985) except for a change in the sign of the 'temperature', i.e., e exp(-aE) to e exp(+aE). It is shown that these 'negative temperature' models provide a much better description of the end-state of violent relaxation than 'positive temperature' models. The second distribution function is similar to the first except for a different dependence on angular momentum. Both distribution functions yield single-parameter families of models with surface density profiles very similar to the R exp 1/4 law. Furthermore, the central concentration of models in both families increases monotonically with the velocity anisotropy, as expected in systems that formed through cold collapse.

  15. Physical properties and solubility parameters of 1-ethyl-3-methylimidazolium based ionic liquids/DMSO mixtures at 298.15 K

    NASA Astrophysics Data System (ADS)

    Saba, H.; Yumei, Z.; Huaping, W.

    2015-12-01

    Densities, refractive indices, conductivities and viscosities of binary mixtures of 1-ethyl-3-methylimidazolium-based ionic liquids (ILs) with dimethyl sulfoxide at 298.15 K are reported. Excess molar volumes have been calculated from experimental data and were fitted with Redlich-Kister equation. The density and refractive index were found to increase with increasing concentration in all cases except [EMIM]COOH. The free mobility of ions has found to enhance conductivity and decrease viscosity to varying extent in all mixtures being studied. It has been observed that solubility parameters, dielectric constants and nature of anions of ILs being used play a vital role in determining the subsequent characteristics. As DMSO has high dielectric constant therefore, it was able to form interactions with most of ILs except with [EMIM]COOH due to anomalous nature of anion.

  16. Dynamically encircling an exceptional point for asymmetric mode switching.

    PubMed

    Doppler, Jörg; Mailybaev, Alexei A; Böhm, Julian; Kuhl, Ulrich; Girschik, Adrian; Libisch, Florian; Milburn, Thomas J; Rabl, Peter; Moiseyev, Nimrod; Rotter, Stefan

    2016-09-01

    Physical systems with loss or gain have resonant modes that decay or grow exponentially with time. Whenever two such modes coalesce both in their resonant frequency and their rate of decay or growth, an 'exceptional point' occurs, giving rise to fascinating phenomena that defy our physical intuition. Particularly intriguing behaviour is predicted to appear when an exceptional point is encircled sufficiently slowly, such as a state-flip or the accumulation of a geometric phase. The topological structure of exceptional points has been experimentally explored, but a full dynamical encircling of such a point and the associated breakdown of adiabaticity have remained out of reach of measurement. Here we demonstrate that a dynamical encircling of an exceptional point is analogous to the scattering through a two-mode waveguide with suitably designed boundaries and losses. We present experimental results from a corresponding waveguide structure that steers incoming waves around an exceptional point during the transmission process. In this way, mode transitions are induced that transform this device into a robust and asymmetric switch between different waveguide modes. This work will enable the exploration of exceptional point physics in system control and state transfer schemes at the crossroads between fundamental research and practical applications.

  17. 22 CFR 11.4 - Medical examination for appointment to class 7 or 8.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... physical, nervous, or mental disease or defect of such a nature as to make it unlikely that the candidate... exceptions to these physical requirements as are in the interest of the Service. All such exceptions shall be...

  18. 42 CFR 423.578 - Exceptions process.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... and medical and scientific evidence and the known relevant physical or mental characteristics of the... evidence and medical and scientific evidence and the known relevant physical or mental characteristics of... reasonable and complete exceptions procedures subject to CMS' approval for this type of coverage...

  19. 42 CFR 423.578 - Exceptions process.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... and medical and scientific evidence and the known relevant physical or mental characteristics of the... evidence and medical and scientific evidence and the known relevant physical or mental characteristics of... maintain reasonable and complete exceptions procedures subject to CMS' approval for this type of coverage...

  20. 41 CFR 105-8.154 - Program accessibility: Exceptions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Program accessibility: Exceptions. 105-8.154 Section 105-8.154 Public Contracts and Property Management Federal Property Management... any action that it can demonstrate would result in a fundamental alteration in the nature of a program...

  1. 41 CFR 105-74.515 - Are there any exceptions to those actions?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Are there any exceptions to those actions? 105-74.515 Section 105-74.515 Public Contracts and Property Management Federal Property Management Regulations System (Continued) GENERAL SERVICES ADMINISTRATION Regional Offices-General...

  2. Recent Advances in Doping of Molybdenum Disulfide: Industrial Applications and Future Prospects.

    PubMed

    Pham, Viet Phuong; Yeom, Geun Young

    2016-11-01

    Owing to their excellent physical properties, atomically thin layers of molybdenum disulfide (MoS 2 ) have recently attracted much attention due to their nonzero-gap property, exceptionally high electrical conductivity, good thermal stability, and excellent mechanical strength, etc. MoS 2 -based devices exhibit great potential for applications in optoelectronics and energy harvesting. Here, a comprehensive review of various doping strategies is presented, including wet doping and dry doping of atomically crystalline MoS 2 thin layers, and the progress made so far for their doping-based prospective applications is also discussed. Finally, several significant research issues for the prospects of doped-MoS 2 in industry, as a guide for 2D material community, are also provided. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Mechanical properties of the fiberglass prepreg system used for the National Transonic Facility replacement blade set

    NASA Technical Reports Server (NTRS)

    Young, Clarence P., Jr.; Wallace, John W.

    1991-01-01

    The results are presented of mechanical and physical properties characterization testing for the fiber glass prepreg system used to fabricate 15 of the replacement set of 25 fan blades for the National Transonic Facility. The fan blades were fabricated to be identical to the original blade set with the exception that the 7576 style E glass cloth used for the replacement set has a different surface finish than the original 7576 cloth. The 7781 E glass cloth and resin system were unchanged. The data are presented for elevated, room, and cryogenic temperatures. The results are compared with data from the original blade set and evaluated against selected structural design criteria. Test experience is described along with recommendations for future testing of these materials if required.

  4. Optimisation des proprietes physiques d'un composite carbone epoxy fabrique par le procede RFI

    NASA Astrophysics Data System (ADS)

    Koanda, Mahamat Mamadou Lamine

    The RFI (Resin Film Infusion) process is a composite materials manufacturing process. Especially known for the small investment it requires, RFI processes are more and more widely used in the aeronautical industry. However a number of aspects of this process are still not well controlled. The quality of the final part depends on which process is used. In the case of RFI, controlling physical characteristics such as thickness, fiber volume fraction or void content remains a major challenge. This dissertation deals with the optimization of the physical properties of a carbon composite manufactured with RFI processes. The ASTMD3171 and ASTMD792 standards were used to measure the void content and fiber volume fraction. First, we introduced different layup sequences in the RFI process and evaluate their impact on the physical properties of the final product. The experiments show the primary mode A, with the resin film at the bottom, resulting in much better quality with controlled fiber volume fraction and void content. Mode B (film in the symmetrical plane) yields results identical to mode A except more irregular thicknesses. Mode C (symmetrical film in the laminate) produces locally unacceptable void contents. Mode D (resin film on the top of the laminate) yields much better results than mode A with the exception of the more irregular thicknesses. Making gaps and overlaps with the resin film has negative effects beyond 2.54cm (one inch) and should be avoided. Several C-scan observations of the manufactured samples showed a large accumulation of porosity in the resin rich areas, as well as surface defects. Ultimately we analyzed the cure cycle in light of the thermodynamic porosity models. It is evident that the diffusion phenomenon is essential in this process. Therefore a better conditioning of the resin film made by Cytec is required. An optimal design with a cycle stop and pressure lag yields the optimal cure cycle for the RFI process.

  5. Fundamental Principles of Classical Mechanics: a Geometrical Perspectives

    NASA Astrophysics Data System (ADS)

    Lam, Kai S.

    2014-07-01

    Classical mechanics is the quantitative study of the laws of motion for oscopic physical systems with mass. The fundamental laws of this subject, known as Newton's Laws of Motion, are expressed in terms of second-order differential equations governing the time evolution of vectors in a so-called configuration space of a system (see Chapter 12). In an elementary setting, these are usually vectors in 3-dimensional Euclidean space, such as position vectors of point particles; but typically they can be vectors in higher dimensional and more abstract spaces. A general knowledge of the mathematical properties of vectors, not only in their most intuitive incarnations as directed arrows in physical space but as elements of abstract linear vector spaces, and those of linear operators (transformations) on vector spaces as well, is then indispensable in laying the groundwork for both the physical and the more advanced mathematical - more precisely topological and geometrical - concepts that will prove to be vital in our subject. In this beginning chapter we will review these properties, and introduce the all-important related notions of dual spaces and tensor products of vector spaces. The notational convention for vectorial and tensorial indices used for the rest of this book (except when otherwise specified) will also be established...

  6. Transcultural adaptation and psychometric properties of Spanish version of Pregnancy Physical Activity Questionnaire: the PregnActive project.

    PubMed

    Oviedo-Caro, Miguel Ángel; Bueno-Antequera, Javier; Munguía-Izquierdo, Diego

    2018-03-19

    To transculturally adapt the Spanish version of Pregnancy Physical Activity Questionnaire (PPAQ) analyzing its psychometric properties. The PPAQ was transculturally adapted into Spanish. Test-retest reliability was evaluated in a subsample of 109 pregnant women. The validity was evaluated in a sample of 208 pregnant women who answered the questionnaire and wore the multi-sensor monitor for 7 valid days. The reliability (intraclass correlation coefficient), concordance (concordance correlation coefficient), correlation (Pearson correlation coefficient), agreement (Bland-Altman plots) and relative activity levels (Jonckheere-Terpstra test) between both administrations and methods were examined. Intraclass correlation coefficients between both administrations were good for all categories except transportation. A low but significant correlation was found for total activity (light and above) whereas no correlation was found for other intensities between both methods. Relative activity levels analysis showed a significant linear trend for increased total activity between both methods. Spanish version of PPAQ is a brief and easily interpretable questionnaire with good reliability and ability to rank individuals, and poor validity compared with multi-sensor monitor. The use of PPAQ provides information of pregnancy-specific activities in order to establish physical activity levels of pregnant women and adapt health promotion interventions. Copyright © 2018 SESPAS. Publicado por Elsevier España, S.L.U. All rights reserved.

  7. Size of graphene sheets determines the structural and mechanical properties of 3D graphene foams

    NASA Astrophysics Data System (ADS)

    Shen, Zhiqiang; Ye, Huilin; Zhou, Chi; Kröger, Martin; Li, Ying

    2018-03-01

    Graphene is recognized as an emerging 2D nanomaterial for many applications. Assembly of graphene sheets into 3D structures is an attractive way to enable their macroscopic applications and to preserve the exceptional mechanical and physical properties of their constituents. In this study, we develop a coarse-grained (CG) model for 3D graphene foams (GFs) based on the CG model for a 2D graphene sheet by Ruiz et al (2015 Carbon 82 103-15). We find that the size of graphene sheets plays an important role in both the structural and mechanical properties of 3D GFs. When their size is smaller than 10 nm, the graphene sheets can easily stack together under the influence of van der Waals interactions (vdW). These stacks behave like building blocks and are tightly packed together within 3D GFs, leading to high density, small pore radii, and a large Young’s modulus. However, if the sheet sizes exceed 10 nm, they are staggered together with a significant amount of deformation (bending). Therefore, the density of 3D GFs has been dramatically reduced due to the loosely packed graphene sheets, accompanied by large pore radii and a small Young’s modulus. Under uniaxial compression, rubber-like stress-strain curves are observed for all 3D GFs. This material characteristic is dominated by the vdW interactions between different graphene layers and slightly affected by the out-of-plane deformation of the graphene sheets. We find a simple scaling law E˜ {ρ }4.2 between the density ρ and Young’s modulus E for a model of 3D GFs. The simulation results reveal structure-property relations of 3D GFs, which can be applied to guide the design of 3D graphene assemblies with exceptional properties.

  8. Liposome Formulation of Fullerene-Based Molecular Diagnostic and Therapeutic Agents

    PubMed Central

    Zhou, Zhiguo

    2013-01-01

    Fullerene medicine is a new but rapidly growing research subject. Fullerene has a number of desired structural, physical and chemical properties to be adapted for biological use including antioxidants, anti-aging, anti-inflammation, photodynamic therapy, drug delivery, and magnetic resonance imaging contrast agents. Chemical functionalization of fullerenes has led to several interesting compounds with very promising preclinical efficacy, pharmacokinetic and safety data. However, there is no clinical evaluation or human use except in fullerene-based cosmetic products for human skincare. This article summarizes recent advances in liposome formulation of fullerenes for the use in therapeutics and molecular imaging. PMID:24300561

  9. Composition and physical properties of Enceladus' surface

    USGS Publications Warehouse

    Brown, R.H.; Clark, R.N.; Buratti, B.J.; Cruikshank, D.P.; Barnes, J.W.; Mastrapa, R.M.E.; Bauer, J.; Newman, S.; Momary, T.; Baines, K.H.; Bellucci, G.; Capaccioni, F.; Cerroni, P.; Combes, M.; Coradini, A.; Drossart, P.; Formisano, V.; Jaumann, R.; Langavin, Y.; Matson, D.L.; McCord, T.B.; Nelson, R.M.; Nicholson, P.D.; Sicardy, B.; Sotin, Christophe

    2006-01-01

    Observations of Saturn's satellite Enceladus using Cassini's Visual and Infrared Mapping Spectrometer instrument were obtained during three flybys of Enceladus in 2005. Enceladus' surface is composed mostly of nearly pure water ice except near its south pole, where there are light organics, CO2, and amorphous and crystalline water ice, particularly in the region dubbed the "tiger stripes." An upper limit of 5 precipitable nanometers is derived for CO in the atmospheric column above Enceladus, and 2% for NH 3 in global surface deposits. Upper limits of 140 kelvin (for a filled pixel) are derived for the temperatures in the tiger stripes.

  10. Seventh National Conference on Physical Activity for the Exceptional Individual.

    ERIC Educational Resources Information Center

    Los Angeles County Superintendent of Schools, CA. Div. of Special Education.

    A variety of physical activities and their applications to special education situations are presented and discussed in this collection of papers. Topics include--games for exceptional populations, mime and movement, behavioral management techniques, motor development programs for the handicapped, teacher and student motivation, yoga for the…

  11. Standards for Teachers of Students with Physical and Health Disabilities

    ERIC Educational Resources Information Center

    Baldwin, Joni L.

    2007-01-01

    The Council for Exceptional Children (CEC) has been involved in the development of standards for teachers of students with exceptional learning needs since 1922. These standards drive the curriculum of institutions of higher education and state licensing requirements. The Division for Physical and Health Disabilities assisted in developing…

  12. The art of transparency.

    PubMed

    Sayim, Bilge; Cavanagh, Patrick

    2011-01-01

    Artists throughout the ages have discovered a number of techniques to depict transparency. With only a few exceptions, these techniques follow closely the properties of physical transparency. The two best known properties are X-junctions and the luminance relations described by Metelli. X-junctions are seen where the contours of a transparent material cross contours of the surface behind; Metelli's constraints on the luminance relations between the direct and filtered portions of the surface specify a range of luminance values that are consistent with transparency. These principles have been used by artists since the time of ancient Egypt. However, artists also discovered that stimuli can be seen as transparent even when these physical constraints are not met. Ancient Greek artists, for example, were able to depict transparent materials in simple black-and-white line drawings. Artists also learned how to represent transparency in cases where neither X-junctions nor Metelli's constraints could apply: for example, where no portions of the objects behind the transparent material extend beyond it. Many painters convincingly portrayed transparency in these cases by depicting the effects the transparent medium would have on material or object properties. Here, we show how artists employed these and other techniques revealing their anticipation of current formalizations of perceived transparency, and we suggest new, as-yet-untested principles.

  13. The art of transparency

    PubMed Central

    Sayim, Bilge; Cavanagh, Patrick

    2011-01-01

    Artists throughout the ages have discovered a number of techniques to depict transparency. With only a few exceptions, these techniques follow closely the properties of physical transparency. The two best known properties are X-junctions and the luminance relations described by Metelli. X-junctions are seen where the contours of a transparent material cross contours of the surface behind; Metelli's constraints on the luminance relations between the direct and filtered portions of the surface specify a range of luminance values that are consistent with transparency. These principles have been used by artists since the time of ancient Egypt. However, artists also discovered that stimuli can be seen as transparent even when these physical constraints are not met. Ancient Greek artists, for example, were able to depict transparent materials in simple black-and-white line drawings. Artists also learned how to represent transparency in cases where neither X-junctions nor Metelli's constraints could apply: for example, where no portions of the objects behind the transparent material extend beyond it. Many painters convincingly portrayed transparency in these cases by depicting the effects the transparent medium would have on material or object properties. Here, we show how artists employed these and other techniques revealing their anticipation of current formalizations of perceived transparency, and we suggest new, as-yet-untested principles. PMID:23145252

  14. Effects of 1-Alkyl-3-Methylimidazolium Nitrate on Soil Physical and Chemical Properties and Microbial Biomass.

    PubMed

    Zhou, Tongtong; Wang, Jun; Ma, Zhiqiang; Du, Zhongkun; Zhang, Cheng; Zhu, Lusheng; Wang, Jinhua

    2018-05-01

    Ionic liquids (ILs), also called room temperature ILs, are widely applied in many fields on the basis of their unique physical and chemical properties. However, numerous ILs may be released into and gradually accumulate in the environment due to their extensive use and absolute solubility. The effects of 1-alkyl-3-methylimidazolium nitrate ([C n mim]NO 3 , n = 4, 6, 8) on soil pH, conductivity, cation exchange capacity, microbial biomass carbon, and microbial biomass nitrogen were examined at the doses of 1, 10, and 100 mg/kg on days 10, 20, 30, and 40. The results demonstrated that the soil pH decreased and the conductivity increased with increasing IL doses. No significant differences were observed in the soil cation-exchange capacity. All three of the tested ILs decreased the soil microbial biomass carbon and nitrogen. Additionally, there were few differences among the ILs with different alkyl chain lengths on the tested indicators except for the microbial biomass nitrogen. The present study addressed a gap in the literature regarding the effects of the aforementioned ILs with different alkyl side chains on the physicochemical properties of soil, and the results could provide the basic data for future studies on their toxicity to soil organisms, such as earthworms and soil microbes.

  15. Physical properties and estimated glycemic index of protein-enriched sorghum based chips.

    PubMed

    Jiang, Hongrui; Hettiararchchy, Navam S; Horax, Ronny

    2018-03-01

    Sorghum is a gluten-free grain and more attention has been given to the nutritional properties and recently its usage as a wheat replacement in food products. In the present work, protein-enriched sorghum based snack chips, prepared from sorghum meal with soy protein isolates and soy flour to meet the final protein content of 35.7%, were produced. The effect of varying baking powder (1.5-2.5%), dough sheet thickness (0.7-1.7 mm), and baking time (6-12 min) on the physical properties of the snack chips was investigated using a central composite design of response surface methodology. Under baking temperature of 160 °C, with baking powder added, the water activity and puffiness of chips significantly increased. Baking time was the most significant factor for all the parameters detected except for puffiness. The optimized conditions of preparing protein-enriched sorghum chips were baking powder 2.5%, dough sheet thickness 0.7 mm, and baking time 7.66 min. The estimated glycemic index (eGI) of the protein-enriched sorghum chips (eGI = 59.8) was significantly lower than soybean-free sorghum chips. The gluten-free protein-enriched sorghum chips developed could be considered as protein rich with lower intermediate-glycemic index classified healthy snacks and potential commercialization.

  16. Sea Water Characterization at Ujung Kulon Coastal Depth as Raw Water Source for Desalination and Potential Energy

    NASA Astrophysics Data System (ADS)

    Mugisidi, Dan; Heriyani, Okatrina

    2018-02-01

    Fresh water is basic need for life while the source is limited. Therefore, sea water is used as fresh water through desalination process. Sea water has different physical and chemical properties ranging from the surface to the seabed. The energy potential that can be obtained from the hydrostatic pressure also changes according to the depth. As part of the research of the utilization of sea water into fresh water, the aim of this study is to know the characteristics of sea water in the depth that can be utilized as source of fresh water. The sea water samples were taken at 11km from Ujung Kulon beach with depth of 0m, 20m, 40m, 60m, 80m, and 100m under the surface. The results showed that the physical properties at every depth were below the maximum allowable drinking water except for the amount of dissolved solids. Chemical characteristics at any depth above allowable level were fluoride, hardness (CaCo3), chloride, sodium, sulphate, and (KMnO4). In addition to the properties, pressure is one of the considerations in this study to determine the depth of sea water as sources for desalination. Pressure increased by 36.11% as the depth of the sea increased.

  17. Development of lightweight reinforced plastic laminates for spacecraft interior applications

    NASA Technical Reports Server (NTRS)

    Hertz, J.

    1975-01-01

    Lightweight, Kevlar - reinforced laminating systems that are non-burning, generate little smoke in the space shuttle environment, and are physically equivalent to the fiberglass/polyimide system used in the Apollo program for non-structural cabin panels, racks, etc. Resin systems representing five generic classes were screened as matrices for Kevlar 49 reinforced laminates. Of the systems evaluated, the polyimides were the most promising with the phenolics a close second. Skybond 703 was selected as the most promising resin candidate. With the exception of compression strength, all program goals of physical and mechanical properties were exceeded. Several prototype space shuttle mobility and translation handrail segments were manufactured using Kevlar/epoxy and Kevlar-graphite/epoxy. This application shows significant weight savings over the baseline aluminum configuration used previous. The hybrid Kevlar-graphite/epoxy is more suitable from a processing standpoint.

  18. Silicon and germanium nanowire electronics: physics of conventional and unconventional transistors

    NASA Astrophysics Data System (ADS)

    Weber, Walter M.; Mikolajick, Thomas

    2017-06-01

    Research in the field of electronics of 1D group-IV semiconductor structures has attracted increasing attention over the past 15 years. The exceptional combination of the unique 1D electronic transport properties with the mature material know-how of highly integrated silicon and germanium technology holds the promise of enhancing state-of-the-art electronics. In addition of providing conduction channels that can bring conventional field effect transistors to the uttermost scaling limits, the physics of 1D group IV nanowires endows new device principles. Such unconventional silicon and germanium nanowire devices are contenders for beyond complementary metal oxide semiconductor (CMOS) computing by virtue of their distinct switching behavior and higher expressive value. This review conveys to the reader a systematic recapitulation and analysis of the physics of silicon and germanium nanowires and the most relevant CMOS and CMOS-like devices built from silicon and germanium nanowires, including inversion mode, junctionless, steep-slope, quantum well and reconfigurable transistors.

  19. Physical properties of particulate matter (PM) from late model heavy-duty diesel vehicles operating with advanced PM and NO x emission control technologies

    NASA Astrophysics Data System (ADS)

    Biswas, Subhasis; Hu, Shaohua; Verma, Vishal; Herner, Jorn D.; Robertson, William H.; Ayala, Alberto; Sioutas, Constantinos

    Emission control technologies designed to meet the 2007 and 2010 emission standards for heavy-duty diesel vehicles (HDDV) remove effectively the non-volatile fraction of particles, but are comparatively less efficient at controlling the semi-volatile components. A collaborative study between the California Air Resources Board (CARB) and the University of Southern California was initiated to investigate the physicochemical and toxicological characteristics of the semi-volatile and non-volatile particulate matter (PM) fractions from HDDV emissions. This paper reports the physical properties, including size distribution, volatility (in terms of number and mass), surface diameter, and agglomeration of particles emitted from HDDV retrofitted with advanced emission control devices. Four vehicles in combination with six after-treatment devices (V-SCRT ®, Z-SCRT ®, CRT ®, DPX, Hybrid-CCRT ®, EPF) were tested under three driving cycles: steady state (cruise), transient (urban dynamometer driving schedule, UDDS), and idle. An HDDV without any control device is served as the baseline vehicle. Substantial reduction of PM mass emissions (>90%) was accomplished for the HDDV operating with advanced emission control technologies. This reduction was not observed for particle number concentrations under cruise conditions, with the exceptions of the Hybrid-CCRT ® and EPF vehicles, which were efficient in controlling both—mass and number emissions. In general, significant nucleation mode particles (<50 nm) were formed during cruise cycles in comparison with the UDDS cycles, which emit higher PM mass in the accumulation mode. The nucleation mode particles (<50 nm) were mainly internally mixed, and evaporated considerably between 150 and 230 °C. Compared to the baseline vehicle, particles from vehicles with controls (except of the Hybrid-CCRT ®) had a higher mass specific surface area.

  20. 41 CFR 102-75.210 - What must a transferee agency include in its request for an exception from the 100 percent...

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... (Continued) FEDERAL MANAGEMENT REGULATION REAL PROPERTY 75-REAL PROPERTY DISPOSAL Utilization of Excess Real... exception would further essential agency program objectives and at the same time be consistent with...

  1. 36 CFR 1194.3 - General exceptions.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 36 Parks, Forests, and Public Property 3 2011-07-01 2011-07-01 false General exceptions. 1194.3 Section 1194.3 Parks, Forests, and Public Property ARCHITECTURAL AND TRANSPORTATION BARRIERS COMPLIANCE... (including payroll, finance, logistics, and personnel management applications). (b) This part does not apply...

  2. 36 CFR 1194.3 - General exceptions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 36 Parks, Forests, and Public Property 3 2012-07-01 2012-07-01 false General exceptions. 1194.3 Section 1194.3 Parks, Forests, and Public Property ARCHITECTURAL AND TRANSPORTATION BARRIERS COMPLIANCE... (including payroll, finance, logistics, and personnel management applications). (b) This part does not apply...

  3. 36 CFR 1194.3 - General exceptions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 36 Parks, Forests, and Public Property 3 2014-07-01 2014-07-01 false General exceptions. 1194.3 Section 1194.3 Parks, Forests, and Public Property ARCHITECTURAL AND TRANSPORTATION BARRIERS COMPLIANCE... (including payroll, finance, logistics, and personnel management applications). (b) This part does not apply...

  4. 12 CFR 1228.1 - Definitions.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... continuing basis each time a property is transferred (except for transfers specifically excepted) for a period of time or indefinitely. A private transfer fee does not include fees, charges, payments, or other... SECURITY INTERESTS IN, MORTGAGES ON PROPERTIES ENCUMBERED BY CERTAIN PRIVATE TRANSFER FEE COVENANTS AND...

  5. Spatial variability structure of soil CO2 emission and soil physical and chemical properties characterized by fractal dimension in sugarcane areas

    NASA Astrophysics Data System (ADS)

    Bicalho, E. S.; Teixeira, D. B.; Panosso, A. R.; Perillo, L. I.; Iamaguti, J. L.; Pereira, G. T.; La Scala, N., Jr.

    2012-04-01

    Soil CO2 emission (FCO2) is influenced by chemical, physical and biological factors that affect the production of CO2 in the soil and its transport to the atmosphere, varying in time and space depending on environmental conditions, including the management of agricultural area. The aim of this study was to investigate the structure of spatial variability of FCO2 and soil properties by using fractal dimension (DF), derived from isotropic variograms at different scales, and construction of fractograms. The experimental area consisted of a regular grid of 60 × 60 m on sugarcane area under green management, containing 141 points spaced at minimum distances ranging from 0.5 to 10 m. Soil CO2 emission, soil temperature and soil moisture were evaluated over a period of 7 days, and soil chemical and physical properties were determined by sampling at a depth of 0.0 to 0.1 m. FCO2 showed an overall average of 1.51 µmol m-2 s-1, correlated significantly (p < 0.05) with soil physical factors such as soil bulk density, air-filled pore space, macroporosity and microporosity. Significant DF values were obtained in the characterization of FCO2 in medium and large scales (from 20 m). Variations in DF with the scale, which is the fractogram, indicate that the structure of FCO2 variability is similar to that observed for the soil temperature and total pore volume, and reverse for the other soil properties, except for macroporosity, sand content, soil organic matter, carbon stock, C/N ratio and CEC, which fractograms were not significantly correlated to the FCO2 fractogram. Thus, the structure of spatial variability for most soil properties, characterized by fractogram, presents a significant relationship with the structure of spatial variability of FCO2, generally with similar or dissimilar behavior, indicating the possibility of using the fractogram as tool to better observe the behavior of the spatial dependence of the variables along the scale.

  6. A Palladium free method to create a Nickel coated electrode for electrochemical application

    NASA Astrophysics Data System (ADS)

    Tran, Thien Khanh; Vu, Thanh, Vi; Vo, Minh Xuan

    2018-04-01

    For many generations, the coating of metals provides many applications in the industry: decoration, functional, electroforming. Electroless plating of Nickel with the supports of Palladium/Tin is famous for its properties and effects. In this study, we provide another catalysis solution for the electroless plating process of Nickel. With plastic Polyvinyl Chloride substrate controlled in thickness (2 mm) and scale (200x400 mm), the efficiency of the coating process was carried out under simple lab scale condition. The result of the process is a thin film layer of Nickel coated on the surface of the substrate with exceptional adhesion and strong physical properties also. The product sample then was tested by many methods such as SEM, XRD, EDS, and FTIR to clarify its properties. According to our observation and the result we obtained, we believe there is still more room for improvement to this method, and a further investigation on its application as well can be carried on in the future.

  7. Mechanical and Physical Properties of Recombinant Spider Silk Films Using Organic and Aqueous Solvents

    PubMed Central

    2015-01-01

    Spider silk has exceptional mechanical and biocompatibility properties. The goal of this study was optimization of the mechanical properties of synthetic spider silk thin films made from synthetic forms of MaSp1 and MaSp2, which compose the dragline silk of Nephila clavipes. We increased the mechanical stress of MaSp1 and 2 films solubilized in both HFIP and water by adding glutaraldehyde and then stretching them in an alcohol based stretch bath. This resulted in stresses as high as 206 MPa and elongations up to 35%, which is 4× higher than the as-poured controls. Films were analyzed using NMR, XRD, and Raman, which showed that the secondary structure after solubilization and film formation in as-poured films is mainly a helical conformation. After the post-pour stretch in a methanol/water bath, the MaSp proteins in both the HFIP and water-based films formed aligned β-sheets similar to those in spider silk fibers. PMID:25030809

  8. Investigation of sources, properties and preparation of distillate test fuels

    NASA Technical Reports Server (NTRS)

    Bowden, J. N.; Erwin, J.

    1983-01-01

    Distillate test fuel blends were generated for prescribed variations in composition and physical properties. Fuels covering a wide range in properties and composition which would provide a matrix of fuels for possible use in future combustion research programs were identified. Except for tetralin the blending components were all from typical refinery streams. Property variation blends span a boiling range within 150 C to 335 C, freezing point -23 C to -43 C, aromatic content 20 to 50 volume percent, hydrogen content 11.8 to 14.2 mass percent, viscosity 4 and 11 cSt (-20 C), and naphthalenes 8 and 16 volume percent. Composition variation blends were made with two base stocks, one paraffinic and the other napthenic. To each base stock was added each of three aromatic type fuels (alkyl benzenes, tetralin, and naphthalenes) for assigned initial boiling point, final boiling point, and hydrogen content. The hydrogen content was 13.5 mass percent for the paraffinic base stock blends and 12.5 mass percent and 11.5 mass percent for the naphthenic base stock blends. Sample 5-gallon quantities of all blends were prepared and analyzed.

  9. Mechanical properties of several neat polymer matrix materials and unidirectional carbon fiber-reinforced composites

    NASA Technical Reports Server (NTRS)

    Coguill, Scott L.; Adams, Donald F.

    1989-01-01

    The mechanical and physical properties of three neat matrix materials, i.e., PEEK (polyetheretherketone) thermoplastic, Hexcel F155 rubber-toughened epoxy and Hercules 8551-7 rubber-toughened epoxy, were experimentally determined. Twelve unidirectional carbon fiber composites, incorporating matrix materials characterized in this or earlier studies (with one exception; the PISO(sub 2)-TPI matrix itself was not characterized), were also tested. These composite systems included AS4/2220-1, AS4/2220-3, T500/R914, IM6/HX1504, T300/4901A (MDA), T700/4901A (MDA), T300/4901B (MPDA), T700/4901B (MPDA), APC2 (AS4/PEEK, ICI), APC2 (AS4/PEEK, Langley Research Center), AS4/8551-7, and AS4/PISO(sub 2)-TPI. For the neat matrix materials, the tensile, shear, fracture toughness, coefficient of thermal expansion, and coefficient of moisture expansion properties were measured as a function of both temperature and moisture content. For the unidirectional composites, axial and transverse tensile, longitudinal shear, coefficient of thermal expansion, and coefficient of moisture expansion properties were determined, at room temperature and 100 C.

  10. Prospects for graphene–nanoparticle-based hybrid sensors

    PubMed Central

    Yin, Perry T.; Kim, Tae-Hyung; Choi, Jeong-Woo; Lee, Ki-Bum

    2014-01-01

    Graphene is a single-atom thick, two-dimensional sheet of carbon that is characterized by exceptional chemical, electrical, material, optical, and physical properties. As a result, graphene and related materials, such as graphene oxide and reduced graphene oxide, have been brought to the forefront in the field of sensing. Recently, a number of reports have demonstrated that graphene–nanoparticle hybrid structures can act synergistically to offer a number of unique physicochemical properties that are desirable and advantageous for sensing applications. These graphene–nanoparticle hybrid structures are particularly interesting because not only do they display the individual properties of the nanoparticles and of graphene, but they can also exhibit additional synergistic properties thereby enhancing the achievable sensitivity and selectivity using a variety of sensing mechanisms. As such, in this perspective, we will discuss the progress that has been made in the development and application of graphene–nanoparticle hybrid sensors and their future prospects. In particular, we will focus on the preparation of graphene–nanoparticle hybrid structures as well as their application in electronic, electrochemical, and optical sensors. PMID:23828095

  11. Chemical and electrical passivation of Si(1 1 1) surfaces

    NASA Astrophysics Data System (ADS)

    Tian, Fangyuan; Yang, Dan; Opila, Robert L.; Teplyakov, Andrew V.

    2012-01-01

    This paper compares the physical and chemical properties of hydrogen-passivated Si(1 1 1) single crystalline surfaces prepared by two main chemical preparation procedures. The modified RCA cleaning is commonly used to prepare atomically flat stable surfaces that are easily identifiable spectroscopically and are the standard for chemical functionalization of silicon. On the other hand electronic properties of these surfaces are sometimes difficult to control. A much simpler silicon surface preparation procedure includes HF dipping for a short period of time. This procedure yields an atomically rough surface, whose chemical identity is not well-defined. However, the surfaces prepared by this approach often exhibit exceptionally attractive electronic properties as determined by long charge carrier lifetimes. This work utilizes infrared spectroscopy and X-ray photoelectron spectroscopy to investigate chemical modification of the surfaces prepared by these two different procedures with PCl5 (leading to surface chlorination) and with short- and long-alkyl-chain alkenes (1-decene and 1-octodecene, respectively) and follows the electronic properties of the starting surfaces produced by measuring charge-carrier lifetimes.

  12. Towards computational materials design from first principles using alchemical changes and derivatives.

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    von Lilienfeld-Toal, Otto Anatole

    2010-11-01

    The design of new materials with specific physical, chemical, or biological properties is a central goal of much research in materials and medicinal sciences. Except for the simplest and most restricted cases brute-force computational screening of all possible compounds for interesting properties is beyond any current capacity due to the combinatorial nature of chemical compound space (set of stoichiometries and configurations). Consequently, when it comes to computationally optimizing more complex systems, reliable optimization algorithms must not only trade-off sufficient accuracy and computational speed of the models involved, they must also aim for rapid convergence in terms of number of compoundsmore » 'visited'. I will give an overview on recent progress on alchemical first principles paths and gradients in compound space that appear to be promising ingredients for more efficient property optimizations. Specifically, based on molecular grand canonical density functional theory an approach will be presented for the construction of high-dimensional yet analytical property gradients in chemical compound space. Thereafter, applications to molecular HOMO eigenvalues, catalyst design, and other problems and systems shall be discussed.« less

  13. 26 CFR 1.367(a)-2 - Exception for transfers of property for use in the active conduct of a trade or business.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 26 Internal Revenue 4 2012-04-01 2012-04-01 false Exception for transfers of property for use in the active conduct of a trade or business. 1.367(a)-2 Section 1.367(a)-2 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES (Continued) Effects on Corporation § 1.367(a)-2 Exception...

  14. 26 CFR 1.367(a)-2 - Exception for transfers of property for use in the active conduct of a trade or business.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 26 Internal Revenue 4 2013-04-01 2013-04-01 false Exception for transfers of property for use in the active conduct of a trade or business. 1.367(a)-2 Section 1.367(a)-2 Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES (CONTINUED) Effects on Corporation § 1.367(a)-2 Exception...

  15. Physical Education Opportunity Program for Exceptional Learners (PEOPEL): A Teacher's Guide for Secondary Schools. Second Edition.

    ERIC Educational Resources Information Center

    Irmer, Larry D.; And Others

    The instructional guide for PEOPEL (Physical Education Opportunity Program for Exceptional Learners) contains 36 units of instruction for use with handicapped junior and senior high school students. The units contain basic performance objectives which have been task analyzed in an effort to individualize instruction. Each unit is divided into four…

  16. Assessing the physical-chemical properties and stability of dapivirine-loaded polymeric nanoparticles.

    PubMed

    das Neves, José; Amiji, Mansoor; Bahia, Maria Fernanda; Sarmento, Bruno

    2013-11-18

    Nanocarriers may provide interesting delivery platforms for microbicide drugs and their characterization should be addressed early in development. Differently surface-engineered dapivirine-loaded, poly(epsilon-caprolactone) (PCL)-based nanoparticles (NPs) were obtained by nanoprecipitation using polyethylene oxide (PEO), sodium lauryl sulfate (SLS), or cetyltrimethylammonium bromide (CTAB) as surface modifiers. Physical-chemical properties of NP aqueous dispersions were evaluated upon storage at -20-40 °C for one year. NPs presented 170-200 nm in diameter, roundish-shape, low polydispersity index (≤0.18), and high drug association efficiency (≥97%) and loading (≥12.7%). NPs differed in zeta potential, depending on surface modifier (PEO: -27.9 mV; SLS: -54.7 mV; CTAB: +42.4 mV). No interactions among formulation components were detected by differential scanning calorimetry (DSC) and Fourier transform infrared spectroscopy (FTIR), except for SLS-PCL NPs. Colloidal properties of NPs were lost at -20 °C storage. Negatively charged NPs were stable up to one year at 5-40°C; as for CTAB-PCL NPs, particle aggregation was observed from 30 to 90 days of storage depending on temperature. Colloidal instability affected the in vitro drug release of CTAB-PCL NPs after 360 days. In any case, no degradation of dapivirine was apparent. Overall, PEO-PCL and SLS-PCL NPs presented suitable properties as nanocarriers for dapivirine. Conversely, CTAB-PCL NPs require additional strategies in order to increase stability. Copyright © 2013 Elsevier B.V. All rights reserved.

  17. 12 CFR 1228.1 - Definitions.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... of title to real estate, and payable on a continuing basis each time a property is transferred (except for transfers specifically excepted) for a period of time or indefinitely. A private transfer fee... SECURITY INTERESTS IN, MORTGAGES ON PROPERTIES ENCUMBERED BY CERTAIN PRIVATE TRANSFER FEE COVENANTS AND...

  18. Swift and Fermi observations of the early afterglow of the short gamma-ray burst 090510

    DOE PAGES

    De Pasquale, M.

    2010-01-14

    Here, we present the observations of GRB090510 performed by the Fermi Gamma-Ray Space Telescope and the Swift observatory. In a GeV range, we detected a bright, short burst that shows an extended emission. Furthermore, its optical emission initially rises, a feature so far observed only in long bursts, while the X-ray flux shows an initial shallow decrease, followed by a steeper decay. This exceptional behavior enables us to investigate the physical properties of the gamma-ray burst outflow, poorly known in short bursts. Here, we discuss internal and external shock models for the broadband energy emission of this object.

  19. Role of the CMS electromagnetic calorimeter in the measurement of the Higgs boson properties and search for new physics

    NASA Astrophysics Data System (ADS)

    Ferri, F.; CMS Collaboration

    2016-04-01

    The precise determination of the mass, the width and the couplings of the particle discovered in 2012 with a mass around 125 GeV is of capital importance to clarify the nature of such a particle, in particular to establish precisely if it is a Standard Model Higgs boson. In several new physics scenarios, in fact, the Higgs boson may behave differently with respect to the Standard Model one, or may not be unique, i.e. there can be more than one Higgs boson. In order to achieve the precision needed to discriminate between different models, the energy resolution, the scale uncertainty and the position resolution for electrons and photons are required to be as good as possible. The CMS scintillating lead-tungstate electromagnetic calorimeter (ECAL) was built as a precise tool with an exceptional energy resolution and a very good position resolution that improved over the years with the knowledge of the detector. Moreover, thanks to the fact that most of the lead-tungstate scintillation light is emitted in about 25 ns, the ECAL can be used to accurately determine the time of flight of photons. We present the current performance of the CMS ECAL, with a special emphasis on the impact on the measurement of the properties of the Higgs boson and on searches for new physics.

  20. Interplay between defects, disorder and flexibility in metal-organic frameworks

    NASA Astrophysics Data System (ADS)

    Bennett, Thomas D.; Cheetham, Anthony K.; Fuchs, Alain H.; Coudert, François-Xavier

    2017-01-01

    Metal-organic frameworks are a novel family of chemically diverse materials, which are of interest across engineering, physics, chemistry, biology and medicine-based disciplines. Since the development of the field in its current form more than two decades ago, priority has been placed on the synthesis of new structures. However, more recently, a clear trend has emerged in shifting the emphasis from material design to exploring the chemical and physical properties of structures already known. In particular, although such nanoporous materials were traditionally seen as rigid crystalline structures, there is growing evidence that large-scale flexibility, the presence of defects and long-range disorder are not the exception in metal-organic frameworks, but the rule. Here we offer some perspective into how these concepts are perhaps inescapably intertwined, highlight recent advances in our understanding and discuss how a consideration of the interfaces between them may lead to enhancements of the materials' functionalities.

  1. Multidimensional supersymmetric quantum mechanics: spurious states for the tensor sector two Hamiltonian.

    PubMed

    Chou, Chia-Chun; Kouri, Donald J

    2013-04-25

    We show that there exist spurious states for the sector two tensor Hamiltonian in multidimensional supersymmetric quantum mechanics. For one-dimensional supersymmetric quantum mechanics on an infinite domain, the sector one and two Hamiltonians have identical spectra with the exception of the ground state of the sector one. For tensorial multidimensional supersymmetric quantum mechanics, there exist normalizable spurious states for the sector two Hamiltonian with energy equal to the ground state energy of the sector one. These spurious states are annihilated by the adjoint charge operator, and hence, they do not correspond to physical states for the original Hamiltonian. The Hermitian property of the sector two Hamiltonian implies the orthogonality between spurious and physical states. In addition, we develop a method for construction of a specific form of the spurious states for any quantum system and also generate several spurious states for a two-dimensional anharmonic oscillator system and for the hydrogen atom.

  2. Exceptional Pupils. Special Education Bulletin Number 1.

    ERIC Educational Resources Information Center

    Indiana State Dept. of Public Instruction, Indianapolis. Div. of Special Education.

    An introduction to exceptional children precedes a discussion of each of the following areas of exceptionality; giftedness, mental retardation, physical handicaps and special health problems, blindness and partial vision, aural handicaps, speech handicaps, emotional disturbance, and learning disabilities. Each chapter is followed by a bibliography…

  3. NMR and Electrochemical Investigation of the Transport Properties of Methanol and Water in Nafion and Clay-Nanocomposites Membranes for DMFCs

    PubMed Central

    Nicotera, Isabella; Angjeli, Kristina; Coppola, Luigi; Aricò, Antonino S.; Baglio, Vincenzo

    2012-01-01

    Water and methanol transport behavior, solvents adsorption and electrochemical properties of filler-free Nafion and nanocomposites based on two smectite clays, were investigated using impedance spectroscopy, DMFC tests and NMR methods, including spin-lattice relaxation and pulsed-gradient spin-echo (PGSE) diffusion under variable temperature conditions. Synthetic (Laponite) and natural (Swy-2) smectite clays, with different structural and physical parameters, were incorporated into the Nafion for the creation of exfoliated nanocomposites. Transport mechanism of water and methanol appears to be influenced from the dimensions of the dispersed platelike silicate layers as well as from their cation exchange capacity (CEC). The details of the NMR results and the effect of the methanol solution concentration are discussed. Clays particles, and in particular Swy-2, demonstrate to be a potential physical barrier for methanol cross-over, reducing the methanol diffusion with an evident blocking effect yet nevertheless ensuring a high water mobility up to 130 °C and for several hours, proving the exceptional water retention property of these materials and their possible use in the DMFCs applications. Electrochemical behavior is investigated by cell resistance and polarization measurements. From these analyses it is derived that the addition of clay materials to recast Nafion decreases the ohmic losses at high temperatures extending in this way the operating range of a direct methanol fuel cell. PMID:24958179

  4. 41 CFR 102-118.295 - What are the limited exceptions to every bill undergoing a prepayment audit?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... exceptions to every bill undergoing a prepayment audit? 102-118.295 Section 102-118.295 Public Contracts and Property Management Federal Property Management Regulations System (Continued) FEDERAL MANAGEMENT REGULATION TRANSPORTATION 118-TRANSPORTATION PAYMENT AND AUDIT Prepayment Audits of Transportation Services...

  5. 36 CFR 13.1156 - Exceptions from vessel permit requirement.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 36 Parks, Forests, and Public Property 1 2013-07-01 2013-07-01 false Exceptions from vessel permit requirement. 13.1156 Section 13.1156 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR NATIONAL PARK SYSTEM UNITS IN ALASKA Special Regulations-Glacier Bay National Park and...

  6. 36 CFR § 1194.3 - General exceptions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 36 Parks, Forests, and Public Property 3 2013-07-01 2012-07-01 true General exceptions. § 1194.3 Section § 1194.3 Parks, Forests, and Public Property ARCHITECTURAL AND TRANSPORTATION BARRIERS COMPLIANCE... (including payroll, finance, logistics, and personnel management applications). (b) This part does not apply...

  7. 41 CFR 51-5.4 - Purchase exceptions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 1 2010-07-01 2010-07-01 true Purchase exceptions. 51-5... Contracts COMMITTEE FOR PURCHASE FROM PEOPLE WHO ARE BLIND OR SEVERELY DISABLED 5-CONTRACTING REQUIREMENTS § 51-5.4 Purchase exceptions. (a) A central nonprofit agency will normally grant a purchase exception...

  8. 26 CFR 20.2010-2T - Portability provisions applicable to estate of a decedent survived by a spouse (temporary).

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... executor is not required to report a value for such property on the estate tax return (except to the extent... with regard to establishing the value of the property) and the instructions for the estate tax return... tax return and § 20.2056(a)-1(b) (except with regard to establishing the value of the property). In...

  9. 26 CFR 20.2010-2T - Portability provisions applicable to estate of a decedent survived by a spouse (temporary).

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... executor is not required to report a value for such property on the estate tax return (except to the extent... with regard to establishing the value of the property) and the instructions for the estate tax return... tax return and § 20.2056(a)-1(b) (except with regard to establishing the value of the property). In...

  10. Label-Free Electrochemical Detection of Vanillin through Low-Defect Graphene Electrodes Modified with Au Nanoparticles.

    PubMed

    Gao, Jingyao; Yuan, Qilong; Ye, Chen; Guo, Pei; Du, Shiyu; Lai, Guosong; Yu, Aimin; Jiang, Nan; Fu, Li; Lin, Cheng-Te; Chee, Kuan W A

    2018-03-25

    Graphene is an excellent modifier for the surface modification of electrochemical electrodes due to its exceptional physical properties and, for the development of graphene-based chemical and biosensors, is usually coated on glassy carbon electrodes (GCEs) via drop casting. However, the ease of aggregation and high defect content of reduced graphene oxides degrade the electrical properties. Here, we fabricated low-defect graphene electrodes by catalytically thermal treatment of HPHT diamond substrate, followed by the electrodeposition of Au nanoparticles (AuNPs) with an average size of ≈60 nm on the electrode surface using cyclic voltammetry. The Au nanoparticle-decorated graphene electrodes show a wide linear response range to vanillin from 0.2 to 40 µM with a low limit of detection of 10 nM. This work demonstrates the potential applications of graphene-based hybrid electrodes for highly sensitive chemical detection.

  11. Compressed glassy carbon: An ultrastrong and elastic interpenetrating graphene network

    PubMed Central

    Hu, Meng; He, Julong; Zhao, Zhisheng; Strobel, Timothy A.; Hu, Wentao; Yu, Dongli; Sun, Hao; Liu, Lingyu; Li, Zihe; Ma, Mengdong; Kono, Yoshio; Shu, Jinfu; Mao, Ho-kwang; Fei, Yingwei; Shen, Guoyin; Wang, Yanbin; Juhl, Stephen J.; Huang, Jian Yu; Liu, Zhongyuan; Xu, Bo; Tian, Yongjun

    2017-01-01

    Carbon’s unique ability to have both sp2 and sp3 bonding states gives rise to a range of physical attributes, including excellent mechanical and electrical properties. We show that a series of lightweight, ultrastrong, hard, elastic, and conductive carbons are recovered after compressing sp2-hybridized glassy carbon at various temperatures. Compression induces the local buckling of graphene sheets through sp3 nodes to form interpenetrating graphene networks with long-range disorder and short-range order on the nanometer scale. The compressed glassy carbons have extraordinary specific compressive strengths—more than two times that of commonly used ceramics—and simultaneously exhibit robust elastic recovery in response to local deformations. This type of carbon is an optimal ultralight, ultrastrong material for a wide range of multifunctional applications, and the synthesis methodology demonstrates potential to access entirely new metastable materials with exceptional properties. PMID:28630918

  12. Insight into the Tribological Behavior of Liposomes in Artificial Joints.

    PubMed

    Duan, Yiqin; Liu, Yuhong; Zhang, Caixia; Chen, Zhe; Wen, Shizhu

    2016-10-10

    Liposomes are widely used in drug delivery and gene therapy, and their new role as boundary lubricant in natural/artificial joints has been found in recent years. In this study, the tribological properties of liposomes on titanium alloy (Ti6Al4 V)/UHMWPE interface were studied by a ball-on-disc tribometer. The efficient reduction of friction coefficient and wear on both surfaces under various velocities and loads is found. A multilayer structure of physically adsorbed liposomes on Ti6Al4 V surface was also observed by atomic force microscope (AFM). Except for the hydration mechanism by phosphatidylcholine (PC) groups, the well-performed tribological properties by liposomes is also attributed to the existence of adsorbed liposome layers on both surfaces, which could reduce asperities contact and show great bearing capacity. This work enriches the research on liposomes for lubrication improvement on artificial surface and shows their value in clinical application.

  13. Atomically Thin Mesoporous Nanomesh of Graphitic C₃N₄ for High-Efficiency Photocatalytic Hydrogen Evolution.

    PubMed

    Han, Qing; Wang, Bing; Gao, Jian; Cheng, Zhihua; Zhao, Yang; Zhang, Zhipan; Qu, Liangti

    2016-02-23

    Delamination of layer materials into two-dimensional single-atom sheets has induced exceptional physical properties, including large surface area, ultrahigh intrinsic carrier mobility, pronounced changes in the energy band structure, and other properties. Here, atomically thin mesoporous nanomesh of graphitic carbon nitride (g-C3N4) is fabricated by solvothermal exfoliation of mesoporous g-C3N4 bulk made from thermal polymerization of freeze-drying assembled Dicyandiamide nanostructure precursor. With the unique structural advantages for aligned energy levels, electron transfer, light harvesting, and the richly available reaction sites, the as-prepared monolayer of mesoporous g-C3N4 nanomesh exhibits a superior photocatalytic hydrogen evolution rate of 8510 μmol h(-1) g(-1) under λ > 420 nm and an apparent quantum efficiency of 5.1% at 420 nm, the highest of all the metal-free g-C3N4 nanosheets photocatalysts.

  14. Antimicrobial Lemongrass Essential Oil-Copper Ferrite Cellulose Acetate Nanocapsules.

    PubMed

    Liakos, Ioannis L; Abdellatif, Mohamed H; Innocenti, Claudia; Scarpellini, Alice; Carzino, Riccardo; Brunetti, Virgilio; Marras, Sergio; Brescia, Rosaria; Drago, Filippo; Pompa, Pier Paolo

    2016-04-20

    Cellulose acetate (CA) nanoparticles were combined with two antimicrobial agents, namely lemongrass (LG) essential oil and Cu-ferrite nanoparticles. The preparation method of CA nanocapsules (NCs), with the two antimicrobial agents, was based on the nanoprecipitation method using the solvent/anti-solvent technique. Several physical and chemical analyses were performed to characterize the resulting NCs and to study their formation mechanism. The size of the combined antimicrobial NCs was found to be ca. 220 nm. The presence of Cu-ferrites enhanced the attachment of LG essential oil into the CA matrix. The magnetic properties of the combined construct were weak, due to the shielding of Cu-ferrites from the polymeric matrix, making them available for drug delivery applications where spontaneous magnetization effects should be avoided. The antimicrobial properties of the NCs were significantly enhanced with respect to CA/LG only. This work opens novel routes for the development of organic/inorganic nanoparticles with exceptional antimicrobial activities.

  15. Physical Properties of Massive, Star-Forming Galaxies When the Universe Was Only Two Billion Years Old

    NASA Astrophysics Data System (ADS)

    Fu, Nicole Christina

    Due to the finite speed of light and a vast, expanding universe, telescopes are just now receiving the light emitted by galaxies as they were forming in the very early universe. The light from these galaxies has been redshifted (stretched to longer, redder wavelengths) as a result of its journey through expanding space. Using sophisticated techniques and exceptional multi-wavelength optical and infrared data, we isolate a population of 378 galaxies in the process of formation when the Universe was only two billion years old. By matching the distinctive properties of the light spectra of these galaxies to models, the redshift, age, dust content, star formation rate and total stellar mass of each galaxy are determined. Comparing our results to similar surveys of galaxy populations at other redshifts, a picture emerges of the growth and evolution of massive, star-forming galaxies over the course of billions of years.

  16. The mechanical behavior of nanoscale metallic multilayers: A survey

    NASA Astrophysics Data System (ADS)

    Zhou, Q.; Xie, J. Y.; Wang, F.; Huang, P.; Xu, K. W.; Lu, T. J.

    2015-06-01

    The mechanical behavior of nanoscale metallic multilayers (NMMs) has attracted much attention from both scientific and practical views. Compared with their monolithic counterparts, the large number of interfaces existing in the NMMs dictates the unique behavior of this special class of structural composite materials. While there have been a number of reviews on the mechanical mechanism of microlaminates, the rapid development of nanotechnology brought a pressing need for an overview focusing exclusively on a property-based definition of the NMMs, especially their size-dependent microstructure and mechanical performance. This article attempts to provide a comprehensive and up-to-date review on the microstructure, mechanical property and plastic deformation physics of NMMs. We hope this review could accomplish two purposes: (1) introducing the basic concepts of scaling and dimensional analysis to scientists and engineers working on NMM systems, and (2) providing a better understanding of interface behavior and the exceptional qualities the interfaces in NMMs display at atomic scale.

  17. Domestic and Industrial Water Disinfection Using Boron-Doped Diamond Electrodes

    NASA Astrophysics Data System (ADS)

    Rychen, Philippe; Provent, Christophe; Pupunat, Laurent; Hermant, Nicolas

    This chapter first describes main properties and manufacturing process (production using HF-CVD, quality-control measurements, etc.) of diamond electrodes and more specifically boron-doped diamond (BDD) electrodes. Their exceptional properties make such electrodes particularly suited for many disinfection applications as thanks to their wide working potential window and their high anodic potential, they allow generating a mixture of powerful oxidizing species mainly based on active oxygen and peroxides. Such mixture of disinfecting agents is far more efficient than conventional chemical or physical known techniques. Their efficiency was tested against numerous microorganisms and then proved to be greater than conventional methods. All bacteria and viruses tested up to date were inactivated 3-5 times faster with a treatment based on with BDD electrodes and the DiaCellⓇ technology than with other techniques. Several applications, either industrial or private (wellness and home use), are discussed with a focus on the dedicated products and the main technology advantages.

  18. Chemical principles underpinning the performance of the metal-organic framework HKUST-1.

    PubMed

    Hendon, Christopher H; Walsh, Aron

    2015-07-15

    A common feature of multi-functional metal-organic frameworks is a metal dimer in the form of a paddlewheel, as found in the structure of Cu 3 ( btc ) 2 (HKUST-1). The HKUST-1 framework demonstrates exceptional gas storage, sensing and separation, catalytic activity and, in recent studies, unprecedented ionic and electrical conductivity. These results are a promising step towards the real-world application of metal-organic materials. In this perspective, we discuss progress in the understanding of the electronic, magnetic and physical properties of HKUST-1, representative of the larger family of Cu···Cu containing metal-organic frameworks. We highlight the chemical interactions that give rise to its favourable properties, and which make this material well suited to a range of technological applications. From this analysis, we postulate key design principles for tailoring novel high-performance hybrid frameworks.

  19. Chemical principles underpinning the performance of the metal–organic framework HKUST-1

    PubMed Central

    Hendon, Christopher H.

    2015-01-01

    A common feature of multi-functional metal–organic frameworks is a metal dimer in the form of a paddlewheel, as found in the structure of Cu3(btc)2 (HKUST-1). The HKUST-1 framework demonstrates exceptional gas storage, sensing and separation, catalytic activity and, in recent studies, unprecedented ionic and electrical conductivity. These results are a promising step towards the real-world application of metal–organic materials. In this perspective, we discuss progress in the understanding of the electronic, magnetic and physical properties of HKUST-1, representative of the larger family of Cu···Cu containing metal–organic frameworks. We highlight the chemical interactions that give rise to its favourable properties, and which make this material well suited to a range of technological applications. From this analysis, we postulate key design principles for tailoring novel high-performance hybrid frameworks. PMID:28706713

  20. Spatial relationships among cereal yields and selected soil physical and chemical properties.

    PubMed

    Lipiec, Jerzy; Usowicz, Bogusław

    2018-08-15

    Sandy soils occupy large area in Poland (about 50%) and in the world. This study aimed at determining spatial relationships of cereal yields and the selected soil physical and chemical properties in three study years (2001-2003) on low productive sandy Podzol soil (Podlasie, Poland). The yields and soil properties in plough and subsoil layers were determined at 72-150 points. The test crops were: wheat, wheat and barley mixture and oats. To explore the spatial relationship between cereal yields and each soil property spatial statistics was used. The best fitting models were adjusted to empirical semivariance and cross-semivariance, which were used to draw maps using kriging. Majority of the soil properties and crop yields exhibited low and medium variability (coefficient of variation 5-70%). The effective ranges of the spatial dependence (the distance at which data are autocorrelated) for yields and all soil properties were 24.3-58.5m and 10.5-373m, respectively. Nugget to sill ratios showed that crop yields and soil properties were strongly spatially dependent except bulk density. Majority of the pairs in cross-semivariograms exhibited strong spatial interdependence. The ranges of the spatial dependence varied in plough layer between 54.6m for yield×pH up to 2433m for yield×silt content. Corresponding ranges in subsoil were 24.8m for crop yield×clay content in 2003 and 1404m for yield×bulk density. Kriging maps allowed separating sub-field area with the lowest yield and soil cation exchange capacity, organic carbon content and pH. This area had lighter color on the aerial photograph due to high content of the sand and low content of soil organic carbon. The results will help farmers at identifying sub-field areas for applying localized management practices to improve these soil properties and further spatial studies in larger scale. Copyright © 2018 The Authors. Published by Elsevier B.V. All rights reserved.

  1. Some Exploitation Properties of Wood Plastic Hybrid Composites Based on Polypropylene and Plywood Production Waste

    NASA Astrophysics Data System (ADS)

    Kajaks, Janis; Kalnins, Karlis; Uzulis, Sandris; Matvejs, Juris

    2015-12-01

    During the last 20-30 years many researchers have paid attention to the studies of properties of thewood polymer composites (WPC). A lot of works are closely related to investigations of exploitation properties of wood fibres or wood flour containing polyolefine composites [1, 2]. The most useful from wide selection of polyolefines are polypropylenes, but timber industry waste materials comprising lignocellulose fibres are often used as reinforcement of WPC [3-12]. Plywood industry is not an exception - part of waste materials (by-products) are used for heat energy, i.e. burned. In this work we have approbated reinforcing of polypropylene (PP) with one of the plywood industry by-products, such as birch plywood sawdust (PSWD),which containswood fibre fractions with different length [13]. The main fraction (50%) includes fibres with length l = 0.5 - 1 mm. Our previous study [13] has confirmed that PSWD is a promising filler for PP reinforcing. Addition of PSWD up to 40-50 wt.% has increased WPC tensile and flexural modulus, but decreased deformation ability of PP matrix, impact strength, water resistance and fluidity of composite melts. It was shown [13] that modification of the composites with interfacial modifier - coupling agent maleated polypropylene (MAPP content up to 5-7 wt.%) considerably improved all the abovementioned properties. SEM investigations also confirmed positive action of coupling agent on strengthening of adhesion interaction between components wood and PP matrix. Another way how to make better properties of the WPC is to form hybridcomposites [1, 14-24]. Very popular WPC modifiers are nanoparticle additions like organonanoclays, which increase WPC physical-mechanical properties - microhardness, water resistance and diminish barrier properties and combustibility [1, 2, 14-17, 19, 20]. The goal of this study was to investigate organonanoclays influence on plywood production industry by-product birch plywood sawdust (PSWD) containing polypropylenewood hybrid composites (WPHC) physical-mechanical and other exploitation properties.

  2. A novel method to produce nonlinear empirical physical formulas for experimental nonlinear electro-optical responses of doped nematic liquid crystals: Feedforward neural network approach

    NASA Astrophysics Data System (ADS)

    Yildiz, Nihat; San, Sait Eren; Okutan, Mustafa; Kaya, Hüseyin

    2010-04-01

    Among other significant obstacles, inherent nonlinearity in experimental physical response data poses severe difficulty in empirical physical formula (EPF) construction. In this paper, we applied a novel method (namely layered feedforward neural network (LFNN) approach) to produce explicit nonlinear EPFs for experimental nonlinear electro-optical responses of doped nematic liquid crystals (NLCs). Our motivation was that, as we showed in a previous theoretical work, an appropriate LFNN, due to its exceptional nonlinear function approximation capabilities, is highly relevant to EPF construction. Therefore, in this paper, we obtained excellently produced LFNN approximation functions as our desired EPFs for above-mentioned highly nonlinear response data of NLCs. In other words, by using suitable LFNNs, we successfully fitted the experimentally measured response and predicted the new (yet-to-be measured) response data. The experimental data (response versus input) were diffraction and dielectric properties versus bias voltage; and they were all taken from our previous experimental work. We conclude that in general, LFNN can be applied to construct various types of EPFs for the corresponding various nonlinear physical perturbation (thermal, electronic, molecular, electric, optical, etc.) data of doped NLCs.

  3. High-Performance Thermoelectric Semiconductors

    NASA Technical Reports Server (NTRS)

    Fleurial, Jean-Pierre; Caillat, Thierry; Borshchevsky, Alexander

    1994-01-01

    Figures of merit almost double current state-of-art thermoelectric materials. IrSb3 is semiconductor found to exhibit exceptional thermoelectric properties. CoSb3 and RhSb3 have same skutterudite crystallographic structure as IrSb3, and exhibit exceptional transport properties expected to contribute to high thermoelectric performance. These three compounds form solid solutions. Combination of properties offers potential for development of new high-performance thermoelectric materials for more efficient thermoelectric power generators, coolers, and detectors.

  4. Carbon nanotube chemistry and assembly for electronic devices

    NASA Astrophysics Data System (ADS)

    Derycke, Vincent; Auvray, Stéphane; Borghetti, Julien; Chung, Chia-Ling; Lefèvre, Roland; Lopez-Bezanilla, Alejandro; Nguyen, Khoa; Robert, Gaël; Schmidt, Gregory; Anghel, Costin; Chimot, Nicolas; Lyonnais, Sébastien; Streiff, Stéphane; Campidelli, Stéphane; Chenevier, Pascale; Filoramo, Arianna; Goffman, Marcelo F.; Goux-Capes, Laurence; Latil, Sylvain; Blase, Xavier; Triozon, François; Roche, Stephan; Bourgoin, Jean-Philippe

    2009-05-01

    Carbon nanotubes (CNTs) have exceptional physical properties that make them one of the most promising building blocks for future nanotechnologies. They may in particular play an important role in the development of innovative electronic devices in the fields of flexible electronics, ultra-high sensitivity sensors, high frequency electronics, opto-electronics, energy sources and nano-electromechanical systems (NEMS). Proofs of concept of several high performance devices already exist, usually at the single device level, but there remain many serious scientific issues to be solved before the viability of such routes can be evaluated. In particular, the main concern regards the controlled synthesis and positioning of nanotubes. In our opinion, truly innovative use of these nano-objects will come from: (i) the combination of some of their complementary physical properties, such as combining their electrical and mechanical properties; (ii) the combination of their properties with additional benefits coming from other molecules grafted on the nanotubes (this route being particularly relevant for gas- and bio-sensors, opto-electronic devices and energy sources); and (iii) the use of chemically- or bio-directed self-assembly processes to allow the efficient combination of several devices into functional arrays or circuits. In this article, we review our recent results concerning nanotube chemistry and assembly and their use to develop electronic devices. In particular, we present carbon nanotube field effect transistors and their chemical optimization, high frequency nanotube transistors, nanotube-based opto-electronic devices with memory capabilities and nanotube-based nano-electromechanical systems (NEMS). The impact of chemical functionalization on the electronic properties of CNTs is analyzed on the basis of theoretical calculations. To cite this article: V. Derycke et al., C. R. Physique 10 (2009).

  5. Visualization of 3-D tensor fields

    NASA Technical Reports Server (NTRS)

    Hesselink, L.

    1996-01-01

    Second-order tensor fields have applications in many different areas of physics, such as general relativity and fluid mechanics. The wealth of multivariate information in tensor fields makes them more complex and abstract than scalar and vector fields. Visualization is a good technique for scientists to gain new insights from them. Visualizing a 3-D continuous tensor field is equivalent to simultaneously visualizing its three eigenvector fields. In the past, research has been conducted in the area of two-dimensional tensor fields. It was shown that degenerate points, defined as points where eigenvalues are equal to each other, are the basic singularities underlying the topology of tensor fields. Moreover, it was shown that eigenvectors never cross each other except at degenerate points. Since we live in a three-dimensional world, it is important for us to understand the underlying physics of this world. In this report, we describe a new method for locating degenerate points along with the conditions for classifying them in three-dimensional space. Finally, we discuss some topological features of three-dimensional tensor fields, and interpret topological patterns in terms of physical properties.

  6. [Effect of ozonated water on physical and chemical properties of vacuum sealing drainage material].

    PubMed

    Jiang, Nan; Ma, Yunfei; Lin, Qingrong; Chen, Anfu; Zhao, Peiran; Ni, Guoxin; Yu, Bin

    2013-02-01

    To investigate the influence of ozonated water on physical and chemical properties of vacuum sealing drainage (VSD) materials. VSD materials (foam and sealing membrane) were immersed in 10 µg/ml ozonated water for 1 h twice daily for 8 days. The foam appearance and microscopic structure of the materials were observed, and tensile tests and Raman spectrum scan were performed assess the effect of ozonated water. Simulated VSD devices were prepared and tested for leakproofness under negative pressure after ozonated water treatment. zonated water treatment for 8 days caused no obvious abnormal changes in the foam appearance or microscopic structure of the materials. The maximum tensile load of foam before and after ozonated water treatment was 4.25∓0.73 kgf and 2.44∓0.19 kgf (P=0.000), the momentary distance when the foam torn before and after intervention was 92.54∓12.83 mm and 64.44∓4.60 mm, respectively (P=0.000). The corresponding results for VSD sealing membrane were 0.70∓0.58 kgf and 0.71∓0.08 kgf (P=0.698), and 99.30∓10.27 mm and 100.95∓18.22 mm (P=0.966), respectively. Raman spectroscopy revealed changes in only several wave intensities and no new chemical groups appeared within the scan range of 400-4000 cm(-1). The VSD device was well hermetic after treatment with ozonated water. Except for a decreased stretch resistance property of the foam, VSD materials display no obvious changes in physical and chemical characteristics after treatment with ozonated water for 8 days.

  7. Chemical and physical properties of dry flue gas desulfurization products.

    PubMed

    Kost, David A; Bigham, Jerry M; Stehouwer, Richard C; Beeghly, Joel H; Fowler, Randy; Traina, Samuel J; Wolfe, William E; Dick, Warren A

    2005-01-01

    Beneficial and environmentally safe recycling of flue gas desulfurization (FGD) products requires detailed knowledge of their chemical and physical properties. We analyzed 59 dry FGD samples collected from 13 locations representing four major FGD scrubbing technologies. The chemistry of all samples was dominated by Ca, S, Al, Fe, and Si and strong preferential partitioning into the acid insoluble residue (i.e., coal ash residue) was observed for Al, Ba, Be, Cr, Fe, Li, K, Pb, Si, and V. Sulfur, Ca, and Mg occurred primarily in water- or acid-soluble forms associated with the sorbents or scrubber reaction products. Deionized water leachates (American Society for Testing and Materials [ASTM] method) and dilute acetic acid leachates (toxicity characteristic leaching procedure [TCLP] method) had mean pH values of >11.2 and high mean concentrations of S primarily as SO(2-)4 and Ca. Concentrations of Ag, As, Ba, Cd, Cr, Hg, Pb, and Se (except for ASTM Se in two samples) were below drinking water standards in both ASTM and TCLP leachates. Total toxicity equivalents (TEQ) of dioxins, for two FGD products used for mine reclamation, were 0.48 and 0.53 ng kg(-1). This was similar to the background level of the mine spoil (0.57 ng kg(-1)). The FGD materials were mostly uniform in particle size. Specific surface area (m2 g(-1)) was related to particle size and varied from 1.3 for bed ash to 9.5 for spray dryer material. Many of the chemical and physical properties of these FGD samples were associated with the quality of the coal rather than the combustion and SO2 scrubbing processes used.

  8. Integrated Formulation of Beacon-Based Exception Analysis for Multimissions

    NASA Technical Reports Server (NTRS)

    Mackey, Ryan; James, Mark; Park, Han; Zak, Mickail

    2003-01-01

    Further work on beacon-based exception analysis for multimissions (BEAM), a method of real-time, automated diagnosis of a complex electromechanical systems, has greatly expanded its capability and suitability of application. This expanded formulation, which fully integrates physical models and symbolic analysis, is described. The new formulation of BEAM expands upon previous advanced techniques for analysis of signal data, utilizing mathematical modeling of the system physics, and expert-system reasoning,

  9. Trends and exceptions of physical properties on antibacterial activity for Gram-positive and Gram-negative pathogens.

    PubMed

    Brown, Dean G; May-Dracka, Tricia L; Gagnon, Moriah M; Tommasi, Ruben

    2014-12-11

    To better understand the difficulties surrounding the identification of novel antibacterial compounds from corporate screening collections, physical properties of ∼3200 antibacterial project compounds with whole cell activity against Gram-negative or Gram-positive pathogens were profiled and compared to actives found from high throughput (HTS) screens conducted on both biochemical and phenotypic bacterial targets. The output from 23 antibacterial HTS screens illustrated that when compared to the properties of the antibacterial project compounds, the HTS actives were significantly more hydrophobic than antibacterial project compounds (typically 2-4 log units higher), and furthermore, for 14/23 HTS screens, the average clogD was higher than the screening collection average (screening collection clogD = 2.45). It was found that the consequences of this were the following: (a) lead identification programs often further gained hydrophobic character with increased biochemical potency, making the separation even larger between the physicochemical properties of known antibacterial agents and the HTS active starting point, (b) the probability of plasma protein binding and cytotoxicity are often increased, and (c) cell-based activity in Gram-negative bacteria was severely limited or, if present, demonstrated significant efflux. Our analysis illustrated that compounds least susceptible to efflux were those which were highly polar and small in MW or very large and typically zwitterionic. Hydrophobicity was often the dominant driver for HTS actives but, more often than not, precluded whole cell antibacterial activity. However, simply designing polar compounds was not sufficient for antibacterial activity and pointed to a lack of understanding of complex and specific bacterial penetration mechanisms.

  10. Effect of plasticizers on properties of pregelatinised starch acetate (Amprac 01) free films.

    PubMed

    Bonacucina, Giulia; Di Martino, Piera; Piombetti, Martina; Colombo, Angela; Roversi, Francesco; Palmieri, Giovanni F

    2006-04-26

    Film coating is a technique widely used in the pharmaceutical field to improve and modify technological and release characteristics of capsules, tablets and granules. In this paper physical and mechanical properties of free films of Amprac 01, obtained by the solvent cast method, were studied in order to investigate the film forming ability of this modified starch and the effects of the addition of different plasticizers. A morphological microscopical analysis (SEM) was performed to study surface properties of the films, while thermal analysis (DSC) was carried out to investigate the influence of different types of plasticizers on the glass transition temperature of the polymer. Then a mechanical characterization permitted to evaluate important parameters such as film crack resistance and deformation at break. Extensional creep/relaxation tests were also performed to investigate the viscoelastic characteristics. As clearly demonstrated by the T(g) values, the residual water present in the films acted as plasticizers, making possible the formation of free films characterised by good macroscopical and mechanical properties. Except glycerol, the kind and amount of the other tested plasticizers did not markedly improve the mechanical and crack resistance of the films.

  11. Atomistic modeling of interphases in spider silk fibers

    NASA Astrophysics Data System (ADS)

    Fossey, Stephen Andrew

    The objective of this work is to create an atomistic model to account for the unusual physical properties of silk fibers. Silk fibers have exceptional mechanical toughness, which makes them of interest as high performance fibers. In order to explain the toughness, a model for the molecular structure based on simple geometric reasoning was formulated. The model consists of very small crystallites, on the order of 5 nm, connected by a noncrystalline interphase. The interphase is a region between the crystalline phase and the amorphous phase, which is defined by the geometry of the system. The interphase is modeled as a very thin (<5 nm) film of noncrystalline polymer constructed using a Monte Carlo, rotational isomeric states approach followed by simulated annealing in order to achieve equilibrium chain configurations and density. No additional assumptions are made about density, orientation, or packing. The mechanical properties of the interphase are calculated using the method of Theodoreau and Suter. Finally, observable properties such as wide angle X-ray scattering and methyl rotation rates are calculated and compared with experimental data available in the literature.

  12. Feasibility study of the production of biomedical Ti-6Al-4V alloy by powder metallurgy.

    PubMed

    Bolzoni, L; Ruiz-Navas, E M; Gordo, E

    2015-04-01

    Titanium and its alloys are characterized by an exceptional combination of properties like high strength, good corrosion resistance and biocompatibility which makes them suitable materials for biomedical prosthesis and devices. The wrought Ti-6Al-4V alloy is generally favored in comparison to other metallic biomaterials due to its relatively low elastic modulus and it has been long used to obtain products for biomedical applications. In this work an alternative route to fabricate biomedical implants made out of the Ti-6Al-4V alloy is investigated. Specifically, the feasibility of the conventional powder metallurgy route of cold uniaxial pressing and sintering is addressed by considering two types of powders (i.e. blended elemental and prealloyed). The characterization of physical properties, chemical analysis, mechanical behavior and microstructural analysis is carried out in-depth and the properties are correlated among them. On the base of the results found, the produced alloys are promising materials for biomedical applications as well as cheaper surgical devices and tools. Copyright © 2015 Elsevier B.V. All rights reserved.

  13. Modification of electrical properties of silicon dioxide through intrinsic nano-patterns

    NASA Astrophysics Data System (ADS)

    Majee, Subimal; Barshilia, Devesh; Banerjee, Debashree; Kumar, Sanjeev; Mishra, Prabhash; Akhtar, Jamil

    2018-05-01

    The inherent network of nanopores and voids in silicon dioxide (SiO2) is generally undesirable for aspects of film quality, electrical insulation and dielectric performance. However, if we view these pores as natural nano-patterns embedded in a dielectric matrix then that opens up new vistas for exploration. The nano-pattern platform can be used to tailor electrical, optical, magnetic and mechanical properties of the carrier film. In this article we report the tunable electrical properties of thermal SiO2 thin-film achieved through utilization of the metal-nanopore network where the pores are filled with metallic Titanium (Ti). Without any intentional chemical doping, we have shown that the electrical resistivity of the oxide film can be controlled through physical filling up of the intrinsic oxide nanopores with Ti. The electrical resistivity of the composite film remains constant even after complete removal of the metal from the film surface except the pores. Careful morphological, electrical and structural analyses are carried out to establish that the presence of Ti in the nanopores play a crucial role in the observed conductive nature of the nanoporous film.

  14. The effects of axial displacement on fracture callus morphology and MSC homing depend on the timing of application.

    PubMed

    Weaver, Aaron S; Su, Yu-Ping; Begun, Dana L; Miller, Joshua D; Alford, Andrea I; Goldstein, Steven A

    2010-07-01

    The local mechanical environment and the availability of mesenchymal stem cells (MSC) have both been shown to be important factors in bone fracture healing. This study was designed to investigate how the timing of an applied axial displacement across a healing fracture affects callus properties as well as the migration of systemically introduced MSC. Bilateral osteotomies were created in male, Sprague-Dawley rats. Exogenous MSC were injected via the tail vein, and a controlled micro-motion was applied to one defect starting 0, 3, 10, or 24 days after surgery. The results showed that fractures stimulated 10 days after surgery had more mineral, less cartilage, and greater mechanical properties at 48 days than other groups. Populations of MSC were found in osteotomies 48 days after surgery, with the exception of the group that was stimulated 10 days after surgery. These results demonstrate that the timing of mechanical stimulation affects the physical properties of the callus and the migration of MSC to the fracture site. Published by Elsevier Inc.

  15. Property rights in human gametes in Australia.

    PubMed

    White, Vanessa

    2013-03-01

    It has long been a basic tenet of the common law that there can be no property interest in human bodies or body parts. However, exceptions to the rule have been recognised from the mid-19th century and developed over time. In the early 21st century, there have been interesting developments in the common law of Australia and England, with Australian Supreme Court judges and the English Court of Appeal casting aside existing exceptions, and finding property rights in human body parts, including gametes, by relying instead on a "rational" and "logical" basis to identify property interests in human body parts.

  16. Preparation and characterization of azithromycin--Aerosil 200 solid dispersions with enhanced physical stability.

    PubMed

    Li, Xuechao; Peng, Huanhuan; Tian, Bin; Gou, Jingxin; Yao, Qing; Tao, Xiaoguang; He, Haibing; Zhang, Yu; Tang, Xing; Cai, Cuifang

    2015-01-01

    The main purpose of this study was to investigate the feasibility of azithromycin (AZI)--Aerosil 200 solid dispersions specifically with high stability under accelerated condition (40 °C/75% RH). Ball milling (BM) and hot-melt extrusion (HME) were used to prepare AZI solid dispersions. The physical properties of solid dispersions were evaluated by differential scanning calorimetry (DSC), scanning electron microscopy (SEM), powder X-ray diffraction (PXRD), Fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA). For solid dispersions prepared with both methods, no crystalline of AZI was detected (except for AZI: Aerosil 200=75:25) by DSC or PXRD, indicating the amorphous state of AZI in solid dispersions. The FT-IR results demonstrated the loss of crystallization water and the formation of hydrogen bonds between Aerosil 200 and AZI during the preparation of solid dispersions. After 4 weeks storage under accelerated condition, the degree of crystallinity of AZI increased in solid dispersions prepared by BM, whereas for solid dispersions containing AZI, Aerosil 200 and glyceryl behenate (GB) prepared by HME, no crystalline of AZI was identified. This high stability can be attributed to the hydrophobic properties of GB and the presence of hydrogen bonds. Based on the above results, it is inferred the protection of hydrogen bonds between AZI and Aerosil 200 formed during preparation process effectively inhibited the recrystallization of AZI and improved the physical stability of amorphous AZI in the presence of Aerosil 200. Copyright © 2015 Elsevier B.V. All rights reserved.

  17. Mechanical properties of silk of the Australian golden orb weavers Nephila pilipes and Nephilaplumipes.

    PubMed

    Kerr, Genevieve G; Nahrung, Helen F; Wiegand, Aaron; Kristoffersen, Joanna; Killen, Peter; Brown, Cameron; Macdonald, Joanne

    2018-02-22

    Silks from orb-weaving spiders are exceptionally tough, producing a model polymer for biomimetic fibre development. The mechanical properties of naturally spun silk threads from two species of Australian orb-weavers, Nephila pilipes and Nephila plumipes , were examined here in relation to overall thread diameter, the size and number of fibres within threads, and spider size. N. pilipes , the larger of the two species, had significantly tougher silk with higher strain capacity than its smaller congener, producing threads with average toughness of 150 MJ m -3 , despite thread diameter, mean fibre diameter and number of fibres per thread not differing significantly between the two species. Within N. pilipes , smaller silk fibres were produced by larger spiders, yielding tougher threads. In contrast, while spider size was correlated with thread diameter in N. plumipes , there were no clear patterns relating to silk toughness, which suggests that the differences in properties between the silk of the two species arise through differing molecular structure. Our results support previous studies that found that the mechanical properties of silk differ between distantly related spider species, and extends on that work to show that the mechanical and physical properties of silk from more closely related species can also differ remarkably. © 2018. Published by The Company of Biologists Ltd.

  18. Mechanical Properties of Stable Glasses Using Nanoindentation

    NASA Astrophysics Data System (ADS)

    Wolf, Sarah; Liu, Tianyi; Jiang, Yijie; Ablajan, Keyume; Zhang, Yue; Walsh, Patrick; Turner, Kevin; Fakhraai, Zahra

    Glasses with enhanced stability over ordinary, liquid quenched glasses have been formed via the process of Physical Vapor Deposition (PVD) by using a sufficiently slow deposition rate and a substrate temperature slightly below the glass transition temperature. These stable glasses have been shown to exhibit higher density, lower enthalpy, and better kinetic stability over ordinary glass, and are typically optically birefringent, due to packing and orientational anisotropy. Given these exceptional properties, it is of interest to further investigate how the properties of stable glasses compare to those of ordinary glass. In particular, the mechanical properties of stable glasses remain relatively under-investigated. While the speed of sound and elastic moduli have been shown to increase with increased stability, little is known about their hardness and fracture toughness compared to ordinary glasses. In this study, glasses of 9-(3,5-di(naphthalen-1-yl)phenyl)anthracene were deposited at varying temperatures relative to their glass transition temperature, and their mechanical properties measured by nanoindentation. Hardness and elastic modulus of the glasses were compared across substrate temperatures. After indentation, the topography of these films were studied using Atomic Force Microscopy (AFM) in order to further compare the relationship between thermodynamic and kinetic stability and mechanical failure. Z.F. and P.W. acknowledge funding from NSF(DMREF-1628407).

  19. Discrimination of orange beverage emulsions with different formulations using multivariate analysis.

    PubMed

    Mirhosseini, Hamed; Tan, Chin Ping

    2010-06-01

    The constituents in a food emulsion interact with each other, either physically or chemically, determining the overall physico-chemical and organoleptic properties of the final product. Thus, the main objective of present study was to investigate the effect of emulsion components on beverage emulsion properties. In most cases, the second-order polynomial regression models with no significant (P > 0.05) lack of fit and high adjusted coefficient of determination (adjusted R(2), 0.851-0.996) were significantly fitted to explain the beverage emulsion properties as function of main emulsion components. The main effect of gum arabic was found to be significant (P < 0.05) in all response regression models. Orange beverage emulsion containing 222.0 g kg(-1) gum arabic, 2.4 g kg(-1) xanthan gum and 152.7 g kg(-1) orange oil was predicted to provide the desirable emulsion properties. The present study suggests that the concentration of gum arabic should be considered as a primary critical factor for the formulation of orange beverage emulsion. This study also indicated that the interaction effect between xanthan gum and orange oil showed the most significant (P < 0.05) effect among all interaction effects influencing all the physicochemical properties except for density. Copyright (c) 2010 Society of Chemical Industry.

  20. 78 FR 12219 - Excepted Service-Appointment of Persons With Intellectual Disabilities, Severe Physical...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-02-22

    ... Intellectual Disabilities, Severe Physical Disabilities, and Psychiatric Disabilities AGENCY: U.S. Office of... physical disabilities, and psychiatric disabilities. The regulation removes an unnecessary burden for these... appointment of people with mental retardation, severe physical disabilities, and psychiatric disabilities. As...

  1. Preparation of olanzapine and methyl-β-cyclodextrin complexes using a single-step, organic solvent-free supercritical fluid process: An approach to enhance the solubility and dissolution properties.

    PubMed

    Rudrangi, Shashi Ravi Suman; Trivedi, Vivek; Mitchell, John C; Wicks, Stephen Richard; Alexander, Bruce David

    2015-10-15

    The purpose of this study was to evaluate a single-step, organic solvent-free supercritical fluid process for the preparation of olanzapine-methyl-β-cyclodextrin complexes with an express goal to enhance the dissolution properties of olanzapine. The complexes were prepared by supercritical carbon dioxide processing, co-evaporation, freeze drying and physical mixing. The prepared complexes were then analysed by differential scanning calorimetry, X-ray powder diffraction, scanning electron microscopy, solubility and dissolution studies. Computational molecular docking studies were performed to study the formation of molecular inclusion complexation of olanzapine with methyl-β-cyclodextrin. All the binary mixtures of olanzapine with methyl-β-cyclodextrin, except physical mixture, exhibited a faster and greater extent of drug dissolution than the drug alone. Products obtained by the supercritical carbon dioxide processing method exhibited the highest apparent drug dissolution. The characterisation by different analytical techniques suggests complete complexation or amorphisation of olanzapine and methyl-β-cyclodextrin complexes prepared by supercritical carbon dioxide processing method. Therefore, organic solvent-free supercritical carbon dioxide processing method proved to be novel and efficient for the preparation of solid inclusion complexes of olanzapine with methyl-β-cyclodextrin. The preliminary data also suggests that the complexes of olanzapine with methyl-β-cyclodextrin will lead to better therapeutic efficacy due to better solubility and dissolution properties. Copyright © 2015 Elsevier B.V. All rights reserved.

  2. Thermal annealing evolution to physical properties of ZnS thin films as buffer layer for solar cell applications

    NASA Astrophysics Data System (ADS)

    Kaushalya; Patel, S. L.; Purohit, A.; Chander, S.; Dhaka, M. S.

    2018-07-01

    The conventional CdS window layer in solar cells is found to be hazardous for the environment due to toxic nature of the cadmium. Therefore, in order to seek an alternative, a study on effect of post-annealing treatment on physical properties of e-beam evaporated ZnS thin films has been carried out where films of thickness 150 nm were deposited on glass and indium tin oxide (ITO) substrates. The post annealing treatment was performed in air atmosphere within the temperature range from 100 °C to 500 °C. X-ray diffraction analysis reveals that the films on glass substrate are found to be amorphous at low temperature annealing (≤300 °C) while have α-ZnS hexagonal phase (wurtzite structure) at higher annealing. The patterns also show that the possibility of oxidation is increased significantly at temperature 500 °C which leads to decrease in direct band gap from 3.28 eV to 3.18 eV except films annealed at 300 °C (i.e. 3.39 eV). The maximum transmittance is found about 95% as a result of Doppler blue shift while electrical analysis indicated almost ohmic behavior between current and voltage and surface roughness is increased with post-annealing treatment.

  3. Mixing and the fractal geometry of piecewise isometries.

    PubMed

    Park, Paul P; Lynn, Thomas F; Umbanhowar, Paul B; Ottino, Julio M; Lueptow, Richard M

    2017-04-01

    Mathematical concepts often have applicability in areas that may have surprised their original developers. This is the case with piecewise isometries (PWIs), which transform an object by cutting it into pieces that are then rearranged to reconstruct the original object, and which also provide a paradigm to study mixing via cutting and shuffling in physical sciences and engineering. Every PWI is characterized by a geometric structure called the exceptional set, E, whose complement comprises nonmixing regions in the domain. Varying the parameters that define the PWI changes both the structure of E as well as the degree of mixing the PWI produces, which begs the question of how to determine which parameters produce the best mixing. Motivated by mixing of yield stress materials, for example granular media, in physical systems, we use numerical simulations of PWIs on a hemispherical shell and examine how the fat fractal properties of E relate to the degree of mixing for any particular PWI. We present numerical evidence that the fractional coverage of E negatively correlates with the intensity of segregation, a standard measure for the degree of mixing, which suggests that fundamental properties of E such as fractional coverage can be used to predict the effectiveness of a particular PWI as a mixing mechanism.

  4. Genotoxicity of Graphene in Escherichia coli

    NASA Astrophysics Data System (ADS)

    Sharma, Ananya

    Rapid advances in nanotechnology necessitate assessment of the safety of nanomaterials in the resulting products and applications. One key nanomaterial attracting much interest in many areas of science and technology is graphene. Graphene is a one atom thick carbon allotrope arranged in a two-dimensional honeycomb lattice. In addition to being extremely thin, graphene has several extraordinary physical properties such as its exceptional mechanical strength, thermal stability, and high electrical conductivity. Graphene itself is relatively chemically inert and therefore pristine graphene must undergo a process called functionalization, which is combination of chemical and physical treatments that change the properties of graphene, to make it chemically active. Functionalization of graphene is of crucial importance as the end application of graphene depends on proper functionalization. In the field of medicine, graphene is currently a nanomaterial of high interest for building biosensors, DNA transistors, and probes for cancer detection. Despite the promising applications of graphene in several areas of biomedicine, there have been only few studies in recent years that focus on evaluating cytotoxicity of graphene on cells, and almost no studies that investigate how graphene exposure affects cellular genetic material. Therefore, in this study we used a novel approach to evaluate the genotoxicity, i.e., the effects of graphene on DNA, using Escherichia coli as a prokaryotic model organism.

  5. Cross-cultural adaptation and construct validity of the Korean version of a physical activity measure for community-dwelling elderly.

    PubMed

    Choi, Bongsam

    2018-01-01

    [Purpose] This study aimed to cross-cultural adapt and validate the Korean version of an physical activity measure (K-PAM) for community-dwelling elderly. [Subjects and Methods] One hundred and thirty eight community-dwelling elderlies, 32 males and 106 female, participated in the study. All participants were asked to fill out a fifty-one item questionnaire measuring perceived difficulty in the activities of daily living (ADL) for the elderly. One-parameter model of item response theory (Rasch analysis) was applied to determine the construct validity and to inspect item-level psychometric properties of 51 ADL items of the K-PAM. [Results] Person separation reliability (analogous to Cronbach's alpha) for internal consistency was ranging 0.93 to 0.94. A total of 16 items was misfit to the Rasch model. After misfit item deletion, 35 ADL items of the K-PAM were placed in an empirically meaningful hierarchy from easy to hard. The item-person map analysis delineated that the item difficulty was well matched for the elderlies with moderate and low ability except for high ceilings. [Conclusion] Cross-cultural adapted K-PAM was shown to be sufficient for establishing construct validity and stable psychometric properties confirmed by person separation reliability and fit statistics.

  6. Deposition velocities and impact of physical properties on ozone removal for building materials

    NASA Astrophysics Data System (ADS)

    Lin, Chi-Chi; Hsu, Shu-Chen

    2015-01-01

    This study aims to estimate the ozone deposition velocities of eight commonly used building materials (BMs) which include calcium silicate board (CSB), green calcium silicate board (GCSB), mineral fiber ceiling (MFC), green mineral fiber ceiling (GMFC), gypsum board (GB), green gypsum board (GGB), wooden flooring (WF) and green wooden flooring (GWF). In addition, the impact of physical properties (specific surface area and total pore volume of BM) on ozone removal ability was also explored and discussed. Studies were conducted in a small-scale environmental stainless steel chamber. CSB and GCSB showed the highest ozone deposition velocities, while WF and GWF showed the lowest ozone deposition velocities among test BMs materials. All reaction probabilities were estimated to fall within the order of magnitude of 10-6. Green BMs showed lower reaction probabilities with ozone comparing with non-green BMs except for GGB. Consistent with the trends for deposition velocity, fleecy and porous materials exhibit higher reaction probabilities than smooth, non-porous surfaces. Specific surface area of BM is more closely related to ozone removal than total pore volume of BM with R2 of 0.93 vs. R2 of 0.84. Discussion of Thiele modulus for all test BMs indicates surface reactions are occurring quickly relative to internal diffusion and ozone removal is internal diffusion-limited.

  7. The Underlying Physics in Wetted Particle Collisions

    NASA Astrophysics Data System (ADS)

    Donahue, Carly; Hrenya, Christine; Davis, Robert

    2008-11-01

    Wetted granular particles are relevant in many industries including the pharmaceutical and chemical industries and has applications to granulation, filtration, coagulation, spray coating, drying and pneumatic transport. In our current focus, we investigate the dynamics of a three-body normal wetted particle collision. In order to conduct collisions we use an apparatus called a ``Stokes Cradle,'' similar to the Newton's Cradle (desktop toy) except that the target particles are covered with oil. Here, we are able to vary the oil thickness, oil viscosity, and material properties. With a three particle collision there are four possible outcomes: fully agglomerated (FA); Newton's Cradle (NC), the striker and the first target ball are agglomerated and the last target ball is separated; Reverse Newton's Cradle (RNC), the striker is separated and the two targets are agglomerated; and fully separated (FS). Varying the properties of the collisions, we have observed all four outcomes. We use elastohydrodynamics as a theoretical basis for modeling the system. We also have considered the glass transition of the oil as the pressure increases upon impact and the cavitation of the oil as the pressure drops below the vapor pressure upon rebound. A toy model has been developed where the collision is modeled as a series of two-body collisions. A qualitative agreement between the toy model and experiments gives insight into the underlying physics.

  8. Relating physical and chemical properties of four different biochars and their application rate to biomass production of Lolium perenne on a Calcic Cambisol during a pot experiment of 79 days.

    PubMed

    de la Rosa, José M; Paneque, Marina; Miller, Ana Z; Knicker, Heike

    2014-11-15

    Three pyrolysis biochars (B1: wood, B2: paper-sludge, B3: sewage-sludge) and one kiln-biochar (B4: grapevine wood) were characterized by determining different chemical and physical properties which were related to the germination rates and to the plant biomass production during a pot experiment of 79 days in which a Calcic Cambisol from SW Spain was amended with 10, 20 and 40 t ha(-1) of the four biochars. Biochar 1, B2 and B4 revealed comparable elemental composition, pH, water holding capacity and ash content. The H/C and O/C atomic ratios suggested high aromaticity of all biochars, which was confirmed by (13)C solid-state NMR spectroscopy. The FT-IR spectra confirmed the aromaticity of all the biochars as well as several specific differences in their composition. The FESEM-EDS distinguished compositional and structural differences of the studied biochars such as macropores on the surface of B1, collapsed structures in B2, high amount of mineral deposits (rich in Al, Si, Ca and Fe) and organic phases in B3 and vessel structures for B4. Biochar amendment improved germination rates and soil fertility (excepting for B4), and had no negative pH impact on the already alkaline soil. Application of B3, the richest in minerals and nitrogen, resulted in the highest soil fertility. In this case, increase of the dose went along with an enhancement of plant production. Considering costs due to production and transport of biochar, for all used chars with the exception of B3, the application of 10 t ha(-1) turned out as the most efficient for the crop and soil used in the present incubation experiment. Copyright © 2014 Elsevier B.V. All rights reserved.

  9. 41 CFR 60-30.36 - Exceptions to recommendations.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... recommendations. 60-30.36 Section 60-30.36 Public Contracts and Property Management Other Provisions Relating to... EXECUTIVE ORDER 11246 Expedited Hearing Procedures § 60-30.36 Exceptions to recommendations. Within 10 days... said recommendations. Exceptions may be responded to by other parties within 7 days after receipt by...

  10. 41 CFR 60-30.36 - Exceptions to recommendations.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... recommendations. 60-30.36 Section 60-30.36 Public Contracts and Property Management Other Provisions Relating to... EXECUTIVE ORDER 11246 Expedited Hearing Procedures § 60-30.36 Exceptions to recommendations. Within 10 days... said recommendations. Exceptions may be responded to by other parties within 7 days after receipt by...

  11. 36 CFR 51.42 - Are there exceptions to this compensable interest prohibition?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... compensable interest prohibition? 51.42 Section 51.42 Parks, Forests, and Public Property NATIONAL PARK... exceptions to this compensable interest prohibition? Two exceptions to this compensable interest prohibition... owned in fee simple by a concessioner or owned in fee simple by a concessioner's predecessor before the...

  12. Students' Understanding of Advanced Properties of Java Exceptions

    ERIC Educational Resources Information Center

    Rashkovits, Rami; Lavy, Ilana

    2012-01-01

    This study examines how Information Systems Engineering School students on the verge of their graduation understand the mechanism of exception handling. The main contributions of this paper are as follows: we construct a questionnaire aimed at examining students' level of understanding concerning exceptions; we classify and analyse the students'…

  13. 26 CFR 1.367(a)-2T - Exception for transfers of property for use in the active conduct of a trade or business...

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... Procedure 68-23 that tax avoidance was not one of the principal purposes of the transaction. (e) Special... Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES Effects on Corporation § 1.367(a)-2T Exception for transfers of property for use in the active...

  14. 39 CFR 601.103 - Applicability and coverage.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...: INTELLECTUAL PROPERTY RIGHTS OTHER THAN PATENTS PURCHASING OF PROPERTY AND SERVICES § 601.103 Applicability and coverage. The regulations contained in this part apply to all Postal Service acquisition of property (except real property) and services. ...

  15. 39 CFR 601.103 - Applicability and coverage.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...: INTELLECTUAL PROPERTY RIGHTS OTHER THAN PATENTS PURCHASING OF PROPERTY AND SERVICES § 601.103 Applicability and coverage. The regulations contained in this part apply to all Postal Service acquisition of property (except real property) and services. ...

  16. Comparative anatomy, physiology, and mechanisms of disease production of the esophagus, stomach, and small intestine.

    PubMed

    Gelberg, Howard B

    2014-01-01

    The alimentary system may be thought of as an open-ended tube within a tube that begins at the oral cavity and ends at the anus. Gastrointestinal lumens are potential spaces that accommodate ingested substances and are lined by polarized epithelium that is smooth and shiny (with the exception of the rumen) when healthy and intact. Because xenobiotics most frequently enter the body via ingestion, the gastrointestinal system and its ancillary glands are the first line of defense against foreign materials and pathogens of all types. The anatomic, biochemical, physical, secretory, and endocrinologic properties of the epithelium, resident, and blood-borne effector cells, microbiota, genetic polymorphisms, and gut-associated lymphoid tissue (which comprises one-quarter of the body's total) must be physically or functionally altered for diarrhea to occur. The average person ingests 700 tons of antigens in their lifetime. That enteritis does not occur more often than it does is testimony to the efficacy of gastrointestinal protective systems.

  17. 45 CFR 707.8 - Physical access.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 45 Public Welfare 3 2012-10-01 2012-10-01 false Physical access. 707.8 Section 707.8 Public... § 707.8 Physical access. (a) Discrimination prohibited. Except as otherwise provided in this section, no... shall be made available for public inspection. The plan shall, at a minimum— (i) Identify physical...

  18. 42 CFR 410.60 - Outpatient physical therapy services: Conditions.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 42 Public Health 2 2012-10-01 2012-10-01 false Outpatient physical therapy services: Conditions... Services § 410.60 Outpatient physical therapy services: Conditions. (a) Basic rule. Except as specified in paragraph (a)(3)(iii) of this section, Medicare Part B pays for outpatient physical therapy services only if...

  19. 42 CFR 410.60 - Outpatient physical therapy services: Conditions.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 42 Public Health 2 2013-10-01 2013-10-01 false Outpatient physical therapy services: Conditions... Services § 410.60 Outpatient physical therapy services: Conditions. (a) Basic rule. Except as specified in paragraph (a)(3)(iii) of this section, Medicare Part B pays for outpatient physical therapy services only if...

  20. 45 CFR 707.8 - Physical access.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 45 Public Welfare 3 2014-10-01 2014-10-01 false Physical access. 707.8 Section 707.8 Public... § 707.8 Physical access. (a) Discrimination prohibited. Except as otherwise provided in this section, no... shall be made available for public inspection. The plan shall, at a minimum— (i) Identify physical...

  1. 42 CFR 410.60 - Outpatient physical therapy services: Conditions.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 42 Public Health 2 2011-10-01 2011-10-01 false Outpatient physical therapy services: Conditions... Services § 410.60 Outpatient physical therapy services: Conditions. (a) Basic rule. Except as specified in paragraph (a)(3)(iii) of this section, Medicare Part B pays for outpatient physical therapy services only if...

  2. 45 CFR 707.8 - Physical access.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 45 Public Welfare 3 2010-10-01 2010-10-01 false Physical access. 707.8 Section 707.8 Public... § 707.8 Physical access. (a) Discrimination prohibited. Except as otherwise provided in this section, no... shall be made available for public inspection. The plan shall, at a minimum— (i) Identify physical...

  3. 42 CFR 410.60 - Outpatient physical therapy services: Conditions.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 42 Public Health 2 2010-10-01 2010-10-01 false Outpatient physical therapy services: Conditions... Services § 410.60 Outpatient physical therapy services: Conditions. (a) Basic rule. Except as specified in paragraph (a)(3)(iii) of this section, Medicare Part B pays for outpatient physical therapy services only if...

  4. 42 CFR 410.60 - Outpatient physical therapy services: Conditions.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 42 Public Health 2 2014-10-01 2014-10-01 false Outpatient physical therapy services: Conditions... Services § 410.60 Outpatient physical therapy services: Conditions. (a) Basic rule. Except as specified in paragraph (a)(3)(iii) of this section, Medicare Part B pays for outpatient physical therapy services only if...

  5. 45 CFR 707.8 - Physical access.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 45 Public Welfare 3 2013-10-01 2013-10-01 false Physical access. 707.8 Section 707.8 Public... § 707.8 Physical access. (a) Discrimination prohibited. Except as otherwise provided in this section, no... shall be made available for public inspection. The plan shall, at a minimum— (i) Identify physical...

  6. 45 CFR 707.8 - Physical access.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 45 Public Welfare 3 2011-10-01 2011-10-01 false Physical access. 707.8 Section 707.8 Public... § 707.8 Physical access. (a) Discrimination prohibited. Except as otherwise provided in this section, no... shall be made available for public inspection. The plan shall, at a minimum— (i) Identify physical...

  7. Architectural Considerations for Classrooms for Exceptional Children.

    ERIC Educational Resources Information Center

    Texas Education Agency, Austin.

    Definitions are provided of the following exceptionalities: blind, partially sighted, physically handicapped, minimally brain injured, deaf, educable mentally retarded (primary, junior, and senior high levels), trainable mentally retarded, speech handicapped, and emotionally disturbed. Architectural guidelines specify classroom location, size,…

  8. 28 CFR 63.9 - Exception.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Exception. Nothing in these guidelines shall apply to assistance provided for emergency work essential to save lives and protect property and public health and safety performed pursuant to sections 305 and 306...

  9. The Effects of CO2 Injection and Barrel Temperatures on the Physiochemical and Antioxidant Properties of Extruded Cereals

    PubMed Central

    Thin, Thazin; Myat, Lin; Ryu, Gi-Hyung

    2016-01-01

    The effects of CO2 injection and barrel temperatures on the physiochemical and antioxidant properties of extruded cereals (sorghum, barley, oats, and millet) were studied. Extrusion was carried out using a twin-screw extruder at different barrel temperatures (80, 110, and 140°C), CO2 injection (0 and 500 mL/min), screw speed of 200 rpm, and moisture content of 25%. Extrusion significantly increased the total flavonoid content (TFC) of extruded oats, and β-glucan and protein digestibility (PD) of extruded barley and oats. In contrast, there were significant reductions in 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging activity, PD of extruded sorghum and millet, as well as resistant starch (RS) of extruded sorghum and barley, and total phenolic content (TPC) of all extrudates, except extruded millet. At a barrel temperature of 140°C, TPC in extruded barley was significantly increased, and there was also an increase in DPPH and PD in extruded millet with or without CO2 injection. In contrast, at a barrel temperature of 140°C, the TPC of extruded sorghum decreased, TFC of extruded oats decreased, and at a barrel temperature of 110°C, PD of extruded sorghum without CO2 decreased. Some physical properties [expansion ratio (ER), specific length, piece density, color, and water absorption index] of the extrudates were significantly affected by the increase in barrel temperature. The CO2 injection significantly affected some physical properties (ER, specific length, piece density, water solubility index, and water absorption index), TPC, DPPH, β-glucan, and PD. In conclusion, extruded barley and millet had higher potential for making value added cereal-based foods than the other cereals. PMID:27752504

  10. 41 CFR 109-1.5101 - Official use of personal property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... property. Personal property shall be used only in the performance of official work of the United States Government, except: (a) In emergencies threatening loss of life or property as authorized by law; (b) As...

  11. Organically linked iron oxide nanoparticle supercrystals with exceptional isotropic mechanical properties.

    PubMed

    Dreyer, Axel; Feld, Artur; Kornowski, Andreas; Yilmaz, Ezgi D; Noei, Heshmat; Meyer, Andreas; Krekeler, Tobias; Jiao, Chengge; Stierle, Andreas; Abetz, Volker; Weller, Horst; Schneider, Gerold A

    2016-05-01

    It is commonly accepted that the combination of the anisotropic shape and nanoscale dimensions of the mineral constituents of natural biological composites underlies their superior mechanical properties when compared to those of their rather weak mineral and organic constituents. Here, we show that the self-assembly of nearly spherical iron oxide nanoparticles in supercrystals linked together by a thermally induced crosslinking reaction of oleic acid molecules leads to a nanocomposite with exceptional bending modulus of 114 GPa, hardness of up to 4 GPa and strength of up to 630 MPa. By using a nanomechanical model, we determined that these exceptional mechanical properties are dominated by the covalent backbone of the linked organic molecules. Because oleic acid has been broadly used as nanoparticle ligand, our crosslinking approach should be applicable to a large variety of nanoparticle systems.

  12. Proton acceleration: new developments for focusing and energy selection, and applications in plasma physics

    NASA Astrophysics Data System (ADS)

    Audebert, P.

    2007-11-01

    In the last few years, intense research has been conducted on laser-accelerated ion sources and their applications. These sources have exceptional properties, i.e. high brightness and high spectral cut-off, high directionality and laminarity, short burst duration. We have shown that for proton energies >10 MeV, the transverse and longitudinal emittance are respectively <0.004 mm-mrad and <10-4 eV-s, i.e. at least 100-fold and may be as much as 10^4-fold better than conventional accelerators beams. Thanks to these properties, these sources allow for example point-projection radiography with unprecedented resolution. We will show example of such time and space-resolved radiography of fast evolving fields, either of associated with the expansion of a plasma in vacuum [*] or with the propagation of a ICF-relevant laser beam in an underdense plasma. These proton sources also open new opportunities for ion beam generation and control, and could stimulate development of compact ion accelerators for many applications.

  13. Thermoplastic composites for veneering posterior teeth-a feasibility study.

    PubMed

    Gegauff, Anthony G; Garcia, Jose L; Koelling, Kurt W; Seghi, Robert R

    2002-09-01

    This pilot study was conducted to explore selected commercially-available thermoplastic composites that potentially had physical properties superior to currently available dental systems for restoring esthetic posterior crowns. Polyurethane, polycarbonate, and poly(ethylene/tetrafluoroethylene) (ETFE) composites and unfilled polyurethane specimens were injection molded to produce shapes adaptive to five standardized mechanical tests. The mechanical testing included abrasive wear rate, yield strength, apparent fracture toughness (strength ratio), flexural strength, and compressive strength. Compared to commercially available dental composites, abrasion wear rates were lower for all materials tested, yield strength was greater for the filled polycarbonates and filled polyurethane resins, fracture toughness testing was invalid (strength ratios were calculated for comparison of the pilot test materials), flexural strength was roughly similar except for the filled ETFE which was significantly greater, and compressive strength was lower. Commercially available thermoplastic resin composites, such as polyurethane, demonstrate the potential for development of an artificial crown material which exceeds the mechanical properties of currently available esthetic systems, if compressive strength can be improved.

  14. Terapascal static pressure generation with ultrahigh yield strength nanodiamond.

    PubMed

    Dubrovinskaia, Natalia; Dubrovinsky, Leonid; Solopova, Natalia A; Abakumov, Artem; Turner, Stuart; Hanfland, Michael; Bykova, Elena; Bykov, Maxim; Prescher, Clemens; Prakapenka, Vitali B; Petitgirard, Sylvain; Chuvashova, Irina; Gasharova, Biliana; Mathis, Yves-Laurent; Ershov, Petr; Snigireva, Irina; Snigirev, Anatoly

    2016-07-01

    Studies of materials' properties at high and ultrahigh pressures lead to discoveries of unique physical and chemical phenomena and a deeper understanding of matter. In high-pressure research, an achievable static pressure limit is imposed by the strength of available strong materials and design of high-pressure devices. Using a high-pressure and high-temperature technique, we synthesized optically transparent microballs of bulk nanocrystalline diamond, which were found to have an exceptional yield strength (~460 GPa at a confining pressure of ~70 GPa) due to the unique microstructure of bulk nanocrystalline diamond. We used the nanodiamond balls in a double-stage diamond anvil cell high-pressure device that allowed us to generate static pressures beyond 1 TPa, as demonstrated by synchrotron x-ray diffraction. Outstanding mechanical properties (strain-dependent elasticity, very high hardness, and unprecedented yield strength) make the nanodiamond balls a unique device for ultrahigh static pressure generation. Structurally isotropic, homogeneous, and made of a low-Z material, they are promising in the field of x-ray optical applications.

  15. Electron-beam induced nano-etching of suspended graphene

    PubMed Central

    Sommer, Benedikt; Sonntag, Jens; Ganczarczyk, Arkadius; Braam, Daniel; Prinz, Günther; Lorke, Axel; Geller, Martin

    2015-01-01

    Besides its interesting physical properties, graphene as a two-dimensional lattice of carbon atoms promises to realize devices with exceptional electronic properties, where freely suspended graphene without contact to any substrate is the ultimate, truly two-dimensional system. The practical realization of nano-devices from suspended graphene, however, relies heavily on finding a structuring method which is minimally invasive. Here, we report on the first electron beam-induced nano-etching of suspended graphene and demonstrate high-resolution etching down to ~7 nm for line-cuts into the monolayer graphene. We investigate the structural quality of the etched graphene layer using two-dimensional (2D) Raman maps and demonstrate its high electronic quality in a nano-device: A 25 nm-wide suspended graphene nanoribbon (GNR) that shows a transport gap with a corresponding energy of ~60 meV. This is an important step towards fast and reliable patterning of suspended graphene for future ballistic transport, nano-electronic and nano-mechanical devices. PMID:25586495

  16. Production of Biodiesel from Lipid of Phytoplankton Chaetoceros calcitrans through Ultrasonic Method

    PubMed Central

    Kwangdinata, Raymond; Raya, Indah; Zakir, Muhammad

    2014-01-01

    A research on production of biodiesel from lipid of phytoplankton Chaetoceros calcitrans through ultrasonic method has been done. In this research, we carried out a series of phytoplankton cultures to determine the optimum time of growth and biodiesel synthesis process from phytoplankton lipids. Process of biodiesel synthesis consists of two steps, that is, isolation of phytoplankton lipids and biodiesel synthesis from those lipids. Oil isolation process was carried out by ultrasonic extraction method using ethanol 96%, while biodiesel synthesis was carried out by transesterification reaction using methanol and KOH catalyst under sonication. Weight of biodiesel yield per biomass Chaetoceros calcitrans is 35.35%. Characterization of biodiesel was well carried out in terms of physical properties which are density and viscosity and chemical properties which are FFA content, saponification value, and iodine value. These values meet the American Society for Testing and Materials (ASTM D6751) standard levels, except for the viscosity value which was 1.14 g·cm−3. PMID:24688372

  17. Terapascal static pressure generation with ultrahigh yield strength nanodiamond

    PubMed Central

    Dubrovinskaia, Natalia; Dubrovinsky, Leonid; Solopova, Natalia A.; Abakumov, Artem; Turner, Stuart; Hanfland, Michael; Bykova, Elena; Bykov, Maxim; Prescher, Clemens; Prakapenka, Vitali B.; Petitgirard, Sylvain; Chuvashova, Irina; Gasharova, Biliana; Mathis, Yves-Laurent; Ershov, Petr; Snigireva, Irina; Snigirev, Anatoly

    2016-01-01

    Studies of materials’ properties at high and ultrahigh pressures lead to discoveries of unique physical and chemical phenomena and a deeper understanding of matter. In high-pressure research, an achievable static pressure limit is imposed by the strength of available strong materials and design of high-pressure devices. Using a high-pressure and high-temperature technique, we synthesized optically transparent microballs of bulk nanocrystalline diamond, which were found to have an exceptional yield strength (~460 GPa at a confining pressure of ~70 GPa) due to the unique microstructure of bulk nanocrystalline diamond. We used the nanodiamond balls in a double-stage diamond anvil cell high-pressure device that allowed us to generate static pressures beyond 1 TPa, as demonstrated by synchrotron x-ray diffraction. Outstanding mechanical properties (strain-dependent elasticity, very high hardness, and unprecedented yield strength) make the nanodiamond balls a unique device for ultrahigh static pressure generation. Structurally isotropic, homogeneous, and made of a low-Z material, they are promising in the field of x-ray optical applications. PMID:27453944

  18. Magnetic resonance fingerprinting.

    PubMed

    Ma, Dan; Gulani, Vikas; Seiberlich, Nicole; Liu, Kecheng; Sunshine, Jeffrey L; Duerk, Jeffrey L; Griswold, Mark A

    2013-03-14

    Magnetic resonance is an exceptionally powerful and versatile measurement technique. The basic structure of a magnetic resonance experiment has remained largely unchanged for almost 50 years, being mainly restricted to the qualitative probing of only a limited set of the properties that can in principle be accessed by this technique. Here we introduce an approach to data acquisition, post-processing and visualization--which we term 'magnetic resonance fingerprinting' (MRF)--that permits the simultaneous non-invasive quantification of multiple important properties of a material or tissue. MRF thus provides an alternative way to quantitatively detect and analyse complex changes that can represent physical alterations of a substance or early indicators of disease. MRF can also be used to identify the presence of a specific target material or tissue, which will increase the sensitivity, specificity and speed of a magnetic resonance study, and potentially lead to new diagnostic testing methodologies. When paired with an appropriate pattern-recognition algorithm, MRF inherently suppresses measurement errors and can thus improve measurement accuracy.

  19. Optical Fibre Sensors Using Graphene-Based Materials: A Review

    PubMed Central

    Hernaez, Miguel; Zamarreño, Carlos R.; Melendi-Espina, Sonia; Bird, Liam R.; Mayes, Andrew G.; Arregui, Francisco J.

    2017-01-01

    Graphene and its derivatives have become the most explored materials since Novoselov and Geim (Nobel Prize winners for Physics in 2010) achieved its isolation in 2004. The exceptional properties of graphene have attracted the attention of the scientific community from different research fields, generating high impact not only in scientific journals, but also in general-interest newspapers. Optical fibre sensing is one of the many fields that can benefit from the use of these new materials, combining the amazing morphological, chemical, optical and electrical features of graphene with the advantages that optical fibre offers over other sensing strategies. In this document, a review of the current state of the art for optical fibre sensors based on graphene materials is presented. PMID:28098825

  20. Mg II chromospheric-emission dating of HR 1614 moving-group stars

    NASA Technical Reports Server (NTRS)

    Hufnagel, Beth; Smith, Graeme H.

    1994-01-01

    A 2800 A Mg II line index I(Mg II) that is sensitive to chromospheric activity has been measured from International Ultraviolet Explorer spectra of a sample of eight HR 1614 moving-group dwarfs. All of these dwarfs have values of I(Mg II) indicative of ages greater than or equal to 3 Gyr. The relatively old ages of these dwarfs, together with their similar and peculiar kinematics and high metal abundance, is consistent with, although not conclusive proof of, coeval formation in close physical proximity to each other. The age, chemical abundance, and kinematics of the HR 1614 moving group -- with the notable exception of height above the Galactic plane -- are similar to the properties of the old open cluster NGC 6791.

  1. Faithful Transfer Arbitrary Pure States with Mixed Resources

    NASA Astrophysics Data System (ADS)

    Luo, Ming-Xing; Li, Lin; Ma, Song-Ya; Chen, Xiu-Bo; Yang, Yi-Xian

    2013-09-01

    In this paper, we show that some special mixed quantum resource experience the same property of pure entanglement such as Bell state for quantum teleportation. It is shown that one mixed state and three bits of classical communication cost can be used to teleport one unknown qubit compared with two bits via pure resources. The schemes are easily implement with model physical techniques. Moreover, these resources are also optimal and typical for faithfully remotely prepare an arbitrary qubit, two-qubit and three-qubit states with mixed quantum resources. Our schemes are completed as same as those with pure quantum entanglement resources except only 1 bit additional classical communication cost required. The success probability is independent of the form of the mixed resources.

  2. Optical Fibre Sensors Using Graphene-Based Materials: A Review.

    PubMed

    Hernaez, Miguel; Zamarreño, Carlos R; Melendi-Espina, Sonia; Bird, Liam R; Mayes, Andrew G; Arregui, Francisco J

    2017-01-14

    Graphene and its derivatives have become the most explored materials since Novoselov and Geim (Nobel Prize winners for Physics in 2010) achieved its isolation in 2004. The exceptional properties of graphene have attracted the attention of the scientific community from different research fields, generating high impact not only in scientific journals, but also in general-interest newspapers. Optical fibre sensing is one of the many fields that can benefit from the use of these new materials, combining the amazing morphological, chemical, optical and electrical features of graphene with the advantages that optical fibre offers over other sensing strategies. In this document, a review of the current state of the art for optical fibre sensors based on graphene materials is presented.

  3. Laser absorption spectroscopy of oxygen confined in highly porous hollow sphere xerogel.

    PubMed

    Yang, Lin; Somesfalean, Gabriel; He, Sailing

    2014-02-10

    An Al2O3 xerogel with a distinctive microstructure is studied for the application of laser absorption spectroscopy of oxygen. The xerogel has an exceptionally high porosity (up to 88%) and a large pore size (up to 3.6 µm). Using the method of gas-in-scattering media absorption spectroscopy (GASMAS), a long optical path length (about 3.5m) and high enhancement factor (over 300 times) are achieved as the result of extremely strong multiple-scattering when the light is transmitted through the air-filled, hollow-sphere alumina xerogel. We investigate how the micro-physical feature influences the optical property. As part of the optical sensing system, the material's gas exchange dynamics are also experimentally studied.

  4. 42 CFR 485.58 - Condition of participation: Comprehensive rehabilitation program.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... the services on its premises. (2) Exceptions. Physical therapy, occupational therapy, and speech... rehabilitation program that includes, at a minimum, physicians' services, physical therapy services, and social... patient and the physical therapist, occupational therapist, or speech-language pathologist, as appropriate...

  5. Mineral Physics and Mantle Evolution

    NASA Astrophysics Data System (ADS)

    Liebermann, R. C.; Bass, J. D.; Weidner, D. J.

    2003-12-01

    Don Anderson has been a steadfast patron and constructive critic of mineral physics for more than 40 years. Although he has never actually done an experiment himself [except for perhaps some early work on ice when he was working in Greenland], he has nurtured and supported two generations of experimental mineral physicists throughout the U.S. His role and influence have been especially evident in studies of the elasticity and anelasticity of minerals and the use of such data for interpretation of seismic models of the Earth's mantle. In the 1960s, such acoustic experiments required specimens of centimeter dimensions and could achieve elevated conditions of less than 1 Gigapascal in pressure and a few hundred degrees of Celsius temperature. Today, one can perform such experiments on specimens only a fraction of a milimeter in size and reach pressures of tens of GPa and temperatures in excess of two thousand degrees C. In addition, Anderson's contributions to organized scientific endeavors have extended far beyond his founding role in IRIS to include advising on the establishment of the new Consortium for Materials Properties Research in Earth Sciences [COMPRES]. We ilustrate his remarkable contributions to mineral physics with examples of our own research, some of it done in collaboration with Anderson.

  6. 22 CFR 9a.8 - Physical protection.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 22 Foreign Relations 1 2012-04-01 2012-04-01 false Physical protection. 9a.8 Section 9a.8 Foreign Relations DEPARTMENT OF STATE GENERAL SECURITY INFORMATION REGULATIONS APPLICABLE TO CERTAIN INTERNATIONAL ENERGY PROGRAMS; RELATED MATERIAL § 9a.8 Physical protection. Except as provided in § 9a.7, the physical...

  7. 22 CFR 9a.8 - Physical protection.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 22 Foreign Relations 1 2010-04-01 2010-04-01 false Physical protection. 9a.8 Section 9a.8 Foreign Relations DEPARTMENT OF STATE GENERAL SECURITY INFORMATION REGULATIONS APPLICABLE TO CERTAIN INTERNATIONAL ENERGY PROGRAMS; RELATED MATERIAL § 9a.8 Physical protection. Except as provided in § 9a.7, the physical...

  8. 22 CFR 9a.8 - Physical protection.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 22 Foreign Relations 1 2013-04-01 2013-04-01 false Physical protection. 9a.8 Section 9a.8 Foreign Relations DEPARTMENT OF STATE GENERAL SECURITY INFORMATION REGULATIONS APPLICABLE TO CERTAIN INTERNATIONAL ENERGY PROGRAMS; RELATED MATERIAL § 9a.8 Physical protection. Except as provided in § 9a.7, the physical...

  9. 22 CFR 9a.8 - Physical protection.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 22 Foreign Relations 1 2014-04-01 2014-04-01 false Physical protection. 9a.8 Section 9a.8 Foreign Relations DEPARTMENT OF STATE GENERAL SECURITY INFORMATION REGULATIONS APPLICABLE TO CERTAIN INTERNATIONAL ENERGY PROGRAMS; RELATED MATERIAL § 9a.8 Physical protection. Except as provided in § 9a.7, the physical...

  10. 22 CFR 9a.8 - Physical protection.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 22 Foreign Relations 1 2011-04-01 2011-04-01 false Physical protection. 9a.8 Section 9a.8 Foreign Relations DEPARTMENT OF STATE GENERAL SECURITY INFORMATION REGULATIONS APPLICABLE TO CERTAIN INTERNATIONAL ENERGY PROGRAMS; RELATED MATERIAL § 9a.8 Physical protection. Except as provided in § 9a.7, the physical...

  11. The Preparation of Regular Physical Educators for Mainstreaming. Final Report.

    ERIC Educational Resources Information Center

    Winnick, Joseph P., Ed.; Hurwitz, Jan, Ed.

    The monograph reports on a 3-year project to develop competencies in physical education teachers for dealing with mainstream exceptional students. Results of a survey of physical educators on the types of competencies needed to teach in mainstreamed settings are presented. Adjustments made to the undergraduate physical education program at State…

  12. 41 CFR 102-75.230 - Who is responsible for property protection and maintenance costs while the request for exception...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Section 102-75.230 Public Contracts and Property Management Federal Property Management Regulations System (Continued) FEDERAL MANAGEMENT REGULATION REAL PROPERTY 75-REAL PROPERTY DISPOSAL Utilization of Excess Real... landholding agency at that time. ...

  13. 42 CFR 410.105 - Requirements for coverage of CORF services.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    .... (3) Exceptions. (i) Physical therapy, occupational therapy, and speech-language pathology services... 60 days for respiratory therapy services and every 90 days for physical therapy, occupational therapy...

  14. Novel models on fluid's variable thermo-physical properties for extensive study on convection heat and mass transfer

    NASA Astrophysics Data System (ADS)

    Shang, De-Yi; Zhong, Liang-Cai

    2017-01-01

    Our novel models for fluid's variable physical properties are improved and reported systematically in this work for enhancement of theoretical and practical value on study of convection heat and mass transfer. It consists of three models, namely (1) temperature parameter model, (2) polynomial model, and (3) weighted-sum model, respectively for treatment of temperature-dependent physical properties of gases, temperature-dependent physical properties of liquids, and concentration- and temperature-dependent physical properties of vapour-gas mixture. Two related components are proposed, and involved in each model for fluid's variable physical properties. They are basic physic property equations and theoretical similarity equations on physical property factors. The former, as the foundation of the latter, is based on the typical experimental data and physical analysis. The latter is built up by similarity analysis and mathematical derivation based on the former basic physical properties equations. These models are available for smooth simulation and treatment of fluid's variable physical properties for assurance of theoretical and practical value of study on convection of heat and mass transfer. Especially, so far, there has been lack of available study on heat and mass transfer of film condensation convection of vapour-gas mixture, and the wrong heat transfer results existed in widespread studies on the related research topics, due to ignorance of proper consideration of the concentration- and temperature-dependent physical properties of vapour-gas mixture. For resolving such difficult issues, the present novel physical property models have their special advantages.

  15. Observation of strong Kondo like features and co-tunnelling in superparamagnetic GdCl3 filled 1D nanomagnets

    NASA Astrophysics Data System (ADS)

    Ncube, S.; Coleman, C.; de Sousa, A. S.; Nie, C.; Lonchambon, P.; Flahaut, E.; Strydom, A.; Bhattacharyya, S.

    2018-06-01

    Filling of carbon nanotubes has been tailored over years to modify the exceptional properties of the 1-dimensional conductor for magnetic property based applications. Hence, such a system exploits the spin and charge property of the electron, analogous to a quantum conductor coupled to magnetic impurities, which poses an interesting scenario for the study of Kondo physics and related phenomena. We report on the electronic transport properties of MWNTs filled with GdCl3 nanomagnets, which clearly show the co-existence of Kondo correlation and cotunelling within the superparamagnetic limit. The Fermi liquid description of the Kondo effect and the interpolation scheme are fitted to the resistance-temperature dependence yielding the onset of the Kondo scattering temperature and a Kondo temperature for this nanocomposite, respectively. Cotunneling of conduction electrons interfering with a Kondo type interaction has been verified from the exponential decay of the intensity of the fano shaped nonzero bias anomalous conductance peaks, which also show strong resonant features observed only in GdCl3 filled MWNT devices. Hence, these features are explained in terms of magnetic coherence and spin-flip effects along with the competition between the Kondo effect and co-tunneling. This study raises a new possibility of tailoring magnetic interactions for spintronic applications in carbon nanotube systems.

  16. Separating the effects of repulsive and attractive forces on the phase diagram, interfacial, and critical properties of simple fluids

    NASA Astrophysics Data System (ADS)

    Fuentes-Herrera, M.; Moreno-Razo, J. A.; Guzmán, O.; López-Lemus, J.; Ibarra-Tandi, B.

    2016-06-01

    Molecular simulations in the canonical and isothermal-isobaric ensembles were performed to study the effect of varying the shape of the intermolecular potential on the phase diagram, critical, and interfacial properties of model fluids. The molecular interactions were modeled by the Approximate Non-Conformal (ANC) theory potentials. Unlike the Lennard-Jones or Morse potentials, the ANC interactions incorporate parameters (called softnesses) that modulate the steepness of the potential in their repulsive and attractive parts independently. This feature allowed us to separate unambiguously the role of each region of the potential on setting the thermophysical properties. In particular, we found positive linear correlation between all critical coordinates and the attractive and repulsive softness, except for the critical density and the attractive softness which are negatively correlated. Moreover, we found that the physical properties related to phase coexistence (such as span of the liquid phase between the critical and triple points, variations in the P-T vaporization curve, interface width, and surface tension) are more sensitive to changes in the attractive softness than to the repulsive one. Understanding the different roles of attractive and repulsive forces on phase coexistence may contribute to developing more accurate models of liquids and their mixtures.

  17. Co-Processed Chitin-Mannitol as a New Excipient for Oro-Dispersible Tablets

    PubMed Central

    Daraghmeh, Nidal; Chowdhry, Babur Z.; Leharne, Stephen A.; Al Omari, Mahmoud M. H.; Badwan, Adnan A.

    2015-01-01

    This study describes the preparation, characterization and performance of a novel excipient for use in oro-dispersible tablets (ODT). The excipient (Cop–CM) consists of chitin and mannitol. The excipient with optimal physicochemical properties was obtained at a chitin: mannitol ratio of 2:8 (w/w) and produced by roll compaction (RC). Differential scanning calorimetry (DSC), Fourier transform-Infrared (FT-IR), X-ray powder diffraction (XRPD) and scanning electron microscope (SEM) techniques were used to characterize Cop–CM, in addition to characterization of its powder and ODT dosage form. The effect of particle size distribution of Cop–CM was investigated and found to have no significant influence on the overall tablet physical properties. The compressibility parameter (a) for Cop–CM was calculated from a Kawakita plot and found to be higher (0.661) than that of mannitol (0.576) due to the presence of the highly compressible chitin (0.818). Montelukast sodium and domperidone ODTs produced, using Cop–CM, displayed excellent physicochemical properties. The exceptional binding, fast wetting and superdisintegration properties of Cop–CM, in comparison with commercially available co-processed ODT excipients, results in a unique multifunctional base which can successfully be used in the formulation of oro-dispersible and fast immediate release tablets. PMID:25830680

  18. Psychometric properties of the Chinese version of the Pediatric Quality of Life Inventory 4.0 generic core scales.

    PubMed

    Hao, Yuantao; Tian, Qi; Lu, Yiyun; Chai, Yiming; Rao, Shaoqi

    2010-10-01

    The aim of this study was to evaluate the psychometric properties of the Chinese version of the Pediatric Quality of Life Inventory 4.0 (PedsQL 4.0) generic core scales. The standard procedure of cross-culture adaptation was used to develop the Chinese version PedsQL4.0. We enrolled 1583 healthy children and 1335 pediatric patients (aged from 5 to 18 years) and 325 proxies. The psychometric properties of the measure were evaluated. The subscales of physical functioning, social functioning and psychosocial showed alpha coefficients above 0.7 for self-report in healthy children and the total pediatric patients, and all coefficients were higher than 0.7 for proxy report for all subscales. There were higher correlations between items and hypothesized subscales than with other subscales. Healthy children reported higher scores than pediatric patients in all subscales. Confirmatory factor analysis showed that some of the indices of goodness of fit did not reach the standard of acceptable construct validity. Moderate to high correlations were found between self-reported and proxy-reported scores. The Chinese version PedsQL4.0 has acceptable psychometric properties except the construct validity tested by confirmatory factor analysis and the internal reliability for self-report in pediatric patients with migraine or Gilles and Tourette's syndrome.

  19. Separating the effects of repulsive and attractive forces on the phase diagram, interfacial, and critical properties of simple fluids.

    PubMed

    Fuentes-Herrera, M; Moreno-Razo, J A; Guzmán, O; López-Lemus, J; Ibarra-Tandi, B

    2016-06-07

    Molecular simulations in the canonical and isothermal-isobaric ensembles were performed to study the effect of varying the shape of the intermolecular potential on the phase diagram, critical, and interfacial properties of model fluids. The molecular interactions were modeled by the Approximate Non-Conformal (ANC) theory potentials. Unlike the Lennard-Jones or Morse potentials, the ANC interactions incorporate parameters (called softnesses) that modulate the steepness of the potential in their repulsive and attractive parts independently. This feature allowed us to separate unambiguously the role of each region of the potential on setting the thermophysical properties. In particular, we found positive linear correlation between all critical coordinates and the attractive and repulsive softness, except for the critical density and the attractive softness which are negatively correlated. Moreover, we found that the physical properties related to phase coexistence (such as span of the liquid phase between the critical and triple points, variations in the P-T vaporization curve, interface width, and surface tension) are more sensitive to changes in the attractive softness than to the repulsive one. Understanding the different roles of attractive and repulsive forces on phase coexistence may contribute to developing more accurate models of liquids and their mixtures.

  20. 7 CFR 3015.163 - Real property.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 15 2012-01-01 2012-01-01 false Real property. 3015.163 Section 3015.163 Agriculture... AGRICULTURE UNIFORM FEDERAL ASSISTANCE REGULATIONS Property § 3015.163 Real property. Except as stated otherwise by Federal statutes, real property applicable to this subpart shall be subject to the following...

  1. 7 CFR 3015.163 - Real property.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 15 2011-01-01 2011-01-01 false Real property. 3015.163 Section 3015.163 Agriculture... AGRICULTURE UNIFORM FEDERAL ASSISTANCE REGULATIONS Property § 3015.163 Real property. Except as stated otherwise by Federal statutes, real property applicable to this subpart shall be subject to the following...

  2. 7 CFR 3015.163 - Real property.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 15 2014-01-01 2014-01-01 false Real property. 3015.163 Section 3015.163 Agriculture... AGRICULTURE UNIFORM FEDERAL ASSISTANCE REGULATIONS Property § 3015.163 Real property. Except as stated otherwise by Federal statutes, real property applicable to this subpart shall be subject to the following...

  3. 7 CFR 3015.163 - Real property.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 15 2013-01-01 2013-01-01 false Real property. 3015.163 Section 3015.163 Agriculture... AGRICULTURE UNIFORM FEDERAL ASSISTANCE REGULATIONS Property § 3015.163 Real property. Except as stated otherwise by Federal statutes, real property applicable to this subpart shall be subject to the following...

  4. 7 CFR 3015.163 - Real property.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 15 2010-01-01 2010-01-01 false Real property. 3015.163 Section 3015.163 Agriculture... AGRICULTURE UNIFORM FEDERAL ASSISTANCE REGULATIONS Property § 3015.163 Real property. Except as stated otherwise by Federal statutes, real property applicable to this subpart shall be subject to the following...

  5. Postfire soil erosion processes are conditioned by aridity

    NASA Astrophysics Data System (ADS)

    Jordán, Antonio; Zavala, Lorena M.; Gordillo-Rivero, Ángel J.; Muñoz-Rojas, Miriam; Keesstra, Saskia; Cerdà, Artemi

    2017-04-01

    In this work we have studied the runoff and rate of erosion in severely burnt Mediterranean shrublands of southern Spain by simulating high intensity rainfall over a period of 5 years. We have also observed temporal changes in soil surface properties (0-10 mm) of two scrub areas in different years. In both cases, surface runoff increased appreciably during the first year after the fire, compared to burning bushes in more rainy areas. Although differences in the rate of infiltration (determined by a mini-disk infiltrometer with ethanol, to avoid the effect of hydrophobicity) were observed, the increase in the rate of runoff was related to the increase of water repellency in the first millimeters of the soil surface, regardless of other physical properties (texture or percentage of rock fragments), chemical (acidity, organic matter content) or fire severity. Sediment loss was also exceptionally high during the first year. Then, runoff and soil loss rates were progressively approaching the values observed in the control zones. However, most of the physical and chemical properties of the soil after the fire did not change during the post-fire period, suggesting erosion of sediment depletion. No large differences were observed between the study points along the precipitation gradient, suggesting that, independently of this and other factors, the impact of high severity fires can be long over time. Although other authors have shown that relatively small changes in aridity have great impacts on erosion processes, this does not seem to be valid in the case of high severity fires in Mediterranean areas.

  6. Holocene environmental change and development of the nutrient budget of histosols in North Iceland

    NASA Astrophysics Data System (ADS)

    Möckel, Susanne Claudia; Erlendsson, Egill; Gísladóttir, Guðrún

    2017-04-01

    Backround and aims: Little is known about vegetation changes in Icelandic peatlands in the context of soil chemical properties. By connecting soil chemical and physical characteristics with palaeobotanical data we examined interactions between climate, histosols, vegetation and land use during the Holocene. Methods: Exchangeable base cations, cation exchange capacity (CEC), base saturation (BS), and decomposition rates using carbon:nitrogen ratio (C:N) and von Post humification and soil physical properties were determined. Vegetation development was reconstructed based on pollen analysis. The impact of geographic location was examined by comparing results from three sloping fens (coastal, inland and highland fringe). Results: Minerogenic content was highest in the proximity of the active volcanic belt, reflected in higher C:N and nutrient content. The site closest to the sea revealed exceptionally high BS. C:N was either stable throughout the profile or increased with depth. Plant species richness, species evenness, and pollen concentrations were greatest at the site with lowest nutrient levels. Conclusions: Minerogenic content facilitates the ability to bind nutrients. Lower fertility levels optimize plant growth. C:N alone is not a reliable indicator of decomposition rates, but depends on the quality of the organic parent material. Environmental conditions driven by climate changes caused alterations in vegetation and soil properties before the settlement. Nevertheless, overall the histosols showed resilience towards severe degradation. After the settlement (c. AD 870), the soils struggled to buffer the impact caused by destruction of vegetation and increased erosion. This study increases our understanding of environmental and anthropogenic determinants of soil- and vegetation development.

  7. Contribution to the physical-mechanical study of cement CRS basis of dune-sand powder and other minerals

    NASA Astrophysics Data System (ADS)

    Dahmani, Saci; Kriker, Abdelouahed

    2016-07-01

    The Portland cements are increasingly used for the manufacture of cement materials (mortar or concrete). Sighting the increasing demand of the cement in the field of construction, and the wealth of our country of minerals. It is time to value these local materials in construction materials and in the manufacture of cement for the manufacture of a new type of cement or for the improvement of the cement of characteristics for several reasons either technical, or ecological or economic or to improve certain properties to the State fees or hardened. The uses of mineral additions remain associated to disadvantages on the time of solidification and the development of the mechanical resistance at the young age [8]. The objective of our work is to study the effects of the incorporation of additions minerals such the pozzolan (active addition) [3], slag of blast furnace (active addition) [4] and the sand dune powder (inert addition) on the physico-mechanical properties of compositions of mortar collaborated compositions according to different binary combinations basis of these additions. This will allow selecting of optimal dosages of these combinations the more efficient, from the point of view of mechanical resistanceas well. The results of this research work confirm that the rate of 10% of pozzolan, slag or powder of dune sand contributes positively on the development of resistance in the long term, at of this proportion time,there is a decrease in the latter except for the slag (20 - 40%) [4]Seems the more effective resistors and physical properties.

  8. 7 CFR 3015.10 - Physical segregation and eligibility.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 15 2011-01-01 2011-01-01 false Physical segregation and eligibility. 3015.10 Section 3015.10 Agriculture Regulations of the Department of Agriculture (Continued) OFFICE OF THE CHIEF....10 Physical segregation and eligibility. Except as provided in § 3015.11, awarding agencies shall not...

  9. 7 CFR 3015.10 - Physical segregation and eligibility.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 15 2013-01-01 2013-01-01 false Physical segregation and eligibility. 3015.10 Section 3015.10 Agriculture Regulations of the Department of Agriculture (Continued) OFFICE OF THE CHIEF....10 Physical segregation and eligibility. Except as provided in § 3015.11, awarding agencies shall not...

  10. 7 CFR 3015.10 - Physical segregation and eligibility.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 15 2014-01-01 2014-01-01 false Physical segregation and eligibility. 3015.10 Section 3015.10 Agriculture Regulations of the Department of Agriculture (Continued) OFFICE OF THE CHIEF....10 Physical segregation and eligibility. Except as provided in § 3015.11, awarding agencies shall not...

  11. 7 CFR 3015.10 - Physical segregation and eligibility.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 15 2012-01-01 2012-01-01 false Physical segregation and eligibility. 3015.10 Section 3015.10 Agriculture Regulations of the Department of Agriculture (Continued) OFFICE OF THE CHIEF....10 Physical segregation and eligibility. Except as provided in § 3015.11, awarding agencies shall not...

  12. Access: Exceptional Children and Technology.

    ERIC Educational Resources Information Center

    North Carolina State Dept. of Public Instruction, Raleigh. Div. for Exceptional Children.

    The Exceptional Children and New Technology project sought to meet the instructional needs of physically handicapped, emotionally disturbed, learning disabled, and mentally handicapped children through the use of computer technology. The goals of the project were to test the instructional value of adaptive/assistive devices with exceptional…

  13. Unraveling the Molecular Requirements for Macroscopic Silk Supercontraction.

    PubMed

    Giesa, Tristan; Schuetz, Roman; Fratzl, Peter; Buehler, Markus J; Masic, Admir

    2017-10-24

    Spider dragline silk is a protein material that has evolved over millions of years to achieve finely tuned mechanical properties. A less known feature of some dragline silk fibers is that they shrink along the main axis by up to 50% when exposed to high humidity, a phenomenon called supercontraction. This contrasts the typical behavior of many other materials that swell when exposed to humidity. Molecular level details and mechanisms of the supercontraction effect are heavily debated. Here we report a molecular dynamics analysis of supercontraction in Nephila clavipes silk combined with in situ mechanical testing and Raman spectroscopy linking the reorganization of the nanostructure to the polar and charged amino acids in the sequence. We further show in our in silico approach that point mutations of these groups not only suppress the supercontraction effect, but even reverse it, while maintaining the exceptional mechanical properties of the silk material. This work has imminent impact on the design of biomimetic equivalents and recombinant silks for which supercontraction may or may not be a desirable feature. The approach applied is appropriate to explore the effect of point mutations on the overall physical properties of protein based materials.

  14. Does gamma irradiation affect physicochemical properties of honey?

    PubMed

    Hussein, S Z; Yusoff, K M; Makpol, S; Mohd Yusof, Y A

    2014-01-01

    Honey is a supersaturated solution of sugars, enriched with proteins, minerals, vitamins, organic acids and polyphenols. Gamma irradiation is a physical technique of food preservation which protects the honey from insects' and microbial contamination during storage. We investigated the effect of gamma irradiation on physicochemical properties in two types of Malaysian honey, Gelam and Nenas. Both honeys were irradiated at the dose 25 kGy in a cobalt-60 irradiator. The physicochemical properties pH, moisture, acidity, color, and sugar content as well as vitamins C and E, hydroxymethylfurfural (HMF) and mineral contents, for the irradiated and non-irradiated honeys were assessed. The results revealed that pH, acidity, minerals and sugar contents in both types of honey were not affected significantly by gamma irradiation, while moisture, vitamin E contents and HMF level decreased significantly with gamma irradiation. However, significant increased in color intensity and vitamin C were observed after gamma irradiation for both types of honey. In summary, gamma irradiation treatment of honey (in the dose mentioned above) did not cause significant changes in the physicochemical and mineral contents, except for significant alterations in color intensity, moisture, vitamins (C and E), and HMF contents.

  15. Effect of myristoylated N-terminus of Arf1 on the bending rigidity of phospholipid membranes

    NASA Astrophysics Data System (ADS)

    Burrola Gabilondo, Beatriz; Zhou, Hernan; Randazzo, Paul A.; Losert, Wolfgang

    2010-03-01

    The protein Arf1 is part of the COPI vesicle transport process from the Golgi to the ER. It binds to membranes via a myristoylated N-terminus and it has been shown to tubulate Large Unilamellar Vesicles. The effect of the N-terminus of Arf1 on physical properties of membranes has not been studied, with the exception of curvature. We previously found that the myristoylated N-terminus increases the packing of the lipid molecules, but has no effect on the lateral mobility. We tested the hypothesis that myristoylated peptides affect the bending rigidity of phospholipid Giant Unilamellar Vesicles (GUV). We use optical tweezers to pull tethers from GUV and measure the force of pulling the tether, as well as the retraction speed of the tether once it is released. We also used flicker spectroscopy to estimate the values of the mechanical properties of GUV. We will present results of the force and tether retraction measurements, as well as mechanical properties estimates from flicker, for GUV in the presence of varying concentrations of myristoylated and non-myristoylated N-terminus of Arf1, and compare these with measurements for GUV in the absence of peptide.

  16. Property-tax incentives for implementing soil-conservation programs under constitutional taxing limitations

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Massey, D.T.; Silver, M.B.

    1982-01-01

    This article describes how property-tax incentives can be used to implement soil-conservation programs on agricultural and open-space lands under the differential-assessment statutes and other exceptions to constitutional limitations on taxation powers. The article describes restrictions imposed on taxing powers by the constitutional uniformity clauses and methods for circumventing those limitations; various property-tax incentives available for conservation programs; types of differential or use-value assessments providing property-tax relief for farm, forest, and open-space land preservation; eligibility of lands for differential assessments; methods available to landowners for participation in differential assessments; and determination of value under differential assessment. The article next details howmore » each of the three primary types of differential or use-value assessment statutes for farm, forest, and open-space land preservation provides exceptions to the uniformity clauses for property tax incentives to implement soil-conservation programs. Other methods available for providing exceptions to the uniformity clauses to permit property-tax incentives are also described for each of the three states. Each of these states has statutes giving favorable tax treatment to certain types of property, such as pollution-abatement equipment, alternative energy-producing devices, and even country clubs. These statutes can be used as examples of finding a constitutional method for providing favorabe tax treatment to promote participation in soil-conservation programs.« less

  17. WE-D-204-00: Session in Memory of Franca Kuchnir: Excellence in Medical Physics Residency Education

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    NONE

    Speakers in this session will present overview and details of a specific rotation or feature of their Medical Physics Residency Program that is particularly exceptional and noteworthy. The featured rotations include foundational topics executed with exceptional acumen and innovative educational rotations perhaps not commonly found in Medical Physics Residency Programs. A site-specific clinical rotation will be described, where the medical physics resident follows the physician and medical resident for two weeks into patient consultations, simulation sessions, target contouring sessions, planning meetings with dosimetry, patient follow up visits, and tumor boards, to gain insight into the thought processes of the radiationmore » oncologist. An incident learning rotation will be described where the residents learns about and practices evaluating clinical errors and investigates process improvements for the clinic. The residency environment at a Canadian medical physics residency program will be described, where the training and interactions with radiation oncology residents is integrated. And the first month rotation will be described, where the medical physics resident rotates through the clinical areas including simulation, dosimetry, and treatment units, gaining an overview of the clinical flow and meeting all the clinical staff to begin the residency program. This session will be of particular interest to residency programs who are interested in adopting or adapting these curricular ideas into their programs and to residency candidates who want to learn about programs already employing innovative practices. Learning Objectives: To learn about exceptional and innovative clinical rotations or program features within existing Medical Physics Residency Programs. To understand how to adopt/adapt innovative curricular designs into your own Medical Physics Residency Program, if appropriate.« less

  18. 41 CFR 109-1.5110 - Physical inventories of personal property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Physical inventories of...-INTRODUCTION 1.51-Personal Property Management Standards and Practices § 109-1.5110 Physical inventories of personal property. (a) Physical inventories of those categories of personal property as specified in...

  19. 41 CFR 109-1.5110 - Physical inventories of personal property.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 41 Public Contracts and Property Management 3 2014-01-01 2014-01-01 false Physical inventories of...-INTRODUCTION 1.51-Personal Property Management Standards and Practices § 109-1.5110 Physical inventories of personal property. (a) Physical inventories of those categories of personal property as specified in...

  20. 41 CFR 109-1.5110 - Physical inventories of personal property.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 41 Public Contracts and Property Management 3 2012-01-01 2012-01-01 false Physical inventories of...-INTRODUCTION 1.51-Personal Property Management Standards and Practices § 109-1.5110 Physical inventories of personal property. (a) Physical inventories of those categories of personal property as specified in...

  1. 41 CFR 109-1.5110 - Physical inventories of personal property.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 41 Public Contracts and Property Management 3 2011-01-01 2011-01-01 false Physical inventories of...-INTRODUCTION 1.51-Personal Property Management Standards and Practices § 109-1.5110 Physical inventories of personal property. (a) Physical inventories of those categories of personal property as specified in...

  2. 41 CFR 109-1.5110 - Physical inventories of personal property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 41 Public Contracts and Property Management 3 2013-07-01 2013-07-01 false Physical inventories of...-INTRODUCTION 1.51-Personal Property Management Standards and Practices § 109-1.5110 Physical inventories of personal property. (a) Physical inventories of those categories of personal property as specified in...

  3. Adaptive Physical Education: Instructional Module for Special Education Minors.

    ERIC Educational Resources Information Center

    Smyser, Sheryl; And Others

    This module is designed to familiarize students preparing to be special education teachers with the physical needs of the exceptional student. Information is given on how to structure an adaptive physical education program designed to meet those needs, including development of an individualized education program (IEP). The module covers such…

  4. 49 CFR 240.231 - Requirements for locomotive engineers unfamiliar with physical characteristics in other than...

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... with physical characteristics in other than joint operations. 240.231 Section 240.231 Transportation... Process § 240.231 Requirements for locomotive engineers unfamiliar with physical characteristics in other... characteristics of the territory pursuant to the railroad's certification program. (b) Except as provided in...

  5. 49 CFR 240.231 - Requirements for locomotive engineers unfamiliar with physical characteristics in other than...

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... with physical characteristics in other than joint operations. 240.231 Section 240.231 Transportation... Process § 240.231 Requirements for locomotive engineers unfamiliar with physical characteristics in other... characteristics of the territory pursuant to the railroad's certification program. (b) Except as provided in...

  6. Physical Disabilities: Education and Related Services, Fall 1999-Spring 2000.

    ERIC Educational Resources Information Center

    Kulik, Barbara J., Ed.

    2000-01-01

    These two journal issues discuss topics relating to the physical and health disabilities of children and adults. The first issue contains the following articles: (1) "Position Statement on Specialized Health Care Procedures," by the Council for Exceptional Children's Division on Physical and Health Disabilities that calls for all…

  7. 26 CFR 1.367(a)-2T - Exception for transfers of property for use in the active conduct of a trade or business...

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 26 Internal Revenue 4 2012-04-01 2012-04-01 false Exception for transfers of property for use in the active conduct of a trade or business (temporary). 1.367(a)-2T Section 1.367(a)-2T Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES (Continued) Effects on Corporation § 1.367(a)...

  8. 26 CFR 1.367(a)-2T - Exception for transfers of property for use in the active conduct of a trade or business...

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 26 Internal Revenue 4 2011-04-01 2011-04-01 false Exception for transfers of property for use in the active conduct of a trade or business (temporary). 1.367(a)-2T Section 1.367(a)-2T Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES Effects on Corporation § 1.367(a)-2T Exceptio...

  9. 26 CFR 1.367(a)-2T - Exception for transfers of property for use in the active conduct of a trade or business...

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... 26 Internal Revenue 4 2013-04-01 2013-04-01 false Exception for transfers of property for use in the active conduct of a trade or business (temporary). 1.367(a)-2T Section 1.367(a)-2T Internal Revenue INTERNAL REVENUE SERVICE, DEPARTMENT OF THE TREASURY (CONTINUED) INCOME TAX (CONTINUED) INCOME TAXES (CONTINUED) Effects on Corporation § 1.367(a)...

  10. 32 CFR 34.2 - Definitions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ..., the Government and subsequently made available to the recipient. Funding period. The period of time... required. Personal property. Property of any kind except real property. It may be: (1) Tangible, having... limited to, income from fees for services performed, the use or rental of real or personal property...

  11. Giant crystal-electric-field effect and complex magnetic behavior in single-crystalline CeRh3Si2

    NASA Astrophysics Data System (ADS)

    Pikul, A. P.; Kaczorowski, D.; Gajek, Z.; Stȩpień-Damm, J.; Ślebarski, A.; Werwiński, M.; Szajek, A.

    2010-05-01

    Single-crystalline CeRh3Si2 was investigated by means of x-ray diffraction, magnetic susceptibility, magnetization, electrical resistivity, and specific-heat measurements carried out in wide temperature and magnetic field ranges. Moreover, the electronic structure of the compound was studied at room temperature by cerium core-level x-ray photoemission spectroscopy (XPS). The physical properties were analyzed in terms of crystalline electric field and compared with results of ab initio band-structure calculations performed within the density-functional theory approach. The compound was found to crystallize in the orthorhombic unit cell of the ErRh3Si2 type (space group Imma No.74, Pearson symbol: oI24 ) with the lattice parameters a=7.1330(14)Å , b=9.7340(19)Å , and c=5.6040(11)Å . Analysis of the magnetic and XPS data revealed the presence of well-localized magnetic moments of trivalent cerium ions. All the physical properties were found to be highly anisotropic over the whole temperature range studied and influenced by exceptionally strong crystalline electric field with the overall splitting of the 4f1 ground multiplet exceeding 5700 K. Antiferromagnetic order of the cerium magnetic moments at TN=4.70(1)K and their subsequent spin rearrangement at Tt=4.48(1)K manifest themselves as distinct anomalies in the temperature characteristic of all the physical properties investigated and exhibit complex evolution in an external magnetic field. A tentative magnetic B-T phase diagram, constructed for B parallel to the b axis being the easy magnetization direction, shows very complex magnetic behavior of CeRh3Si2 , similar to that recently reported for an isostructural compound CeIr3Si2 . The electronic band-structure calculations corroborated the antiferromagnetic ordering of the cerium magnetic moments and well-reproduced the experimental XPS valence-band spectrum.

  12. Screened hybrid functional applied to 3d0→3d8 transition-metal perovskites LaMO3 (M = Sc-Cu): Influence of the exchange mixing parameter on the structural, electronic, and magnetic properties

    NASA Astrophysics Data System (ADS)

    He, Jiangang; Franchini, Cesare

    2012-12-01

    We assess the performance of the Heyd-Scuseria-Ernzerhof (HSE) screened hybrid density functional scheme applied to the perovskite family LaMO3 (M = Sc-Cu) and discuss the role of the mixing parameter α [which determines the fraction of exact Hartree-Fock exchange included in the density functional theory (DFT) exchange-correlation functional] on the structural, electronic, and magnetic properties. The physical complexity of this class of compounds, manifested by the largely varying electronic characters (band/Mott-Hubbard/charge-transfer insulators and metals), magnetic orderings, structural distortions (cooperative Jahn-Teller-type instabilities), as well as by the strong competition between localization/delocalization effects associated with the gradual filling of the t2g and eg orbitals, symbolize a critical and challenging case for theory. Our results indicate that HSE is able to provide a consistent picture of the complex physical scenario encountered across the LaMO3 series and significantly improve the standard DFT description. The only exceptions are the correlated paramagnetic metals LaNiO3 and LaCuO3, which are found to be treated better within DFT. By fitting the ground-state properties with respect to α, we have constructed a set of “optimum” values of α from LaScO3 to LaCuO3: it is found that the optimum mixing parameter decreases with increasing filling of the d manifold (LaScO3: 0.25; LaTiO3 and LaVO3: 0.10-0.15; LaCrO3, LaMnO3, and LaFeO3: 0.15; LaCoO3: 0.05; LaNiO3 and LaCuO3: 0). This trend can be nicely correlated with the modulation of the screening and dielectric properties across the LaMO3 series, thus providing a physical justification to the empirical fitting procedure. Finally, we show that by using this set of optimum mixing parameter, HSE predict dielectric constants in very good agreement with the experimental ones.

  13. The Portuguese version of the Epilepsy Surgery Inventory (ESI-55): cross-cultural adaptation and evaluation of psychometric properties.

    PubMed

    Alonso, Neide Barreira; Ciconelli, Rozana Mesquita; da Silva, Tatiana Indelicato; Westphal-Guitti, Ana Carolina; Azevedo, Auro Mauro; da Silva Noffs, Maria Helena; Caboclo, Luís Otávio Sales Ferreira; Sakamoto, Américo Ceiki; Targas Yacubian, Elza Márcia

    2006-08-01

    The purpose of this study was to develop a Portuguese version of the Epilepsy Surgery Inventory (ESI-55) and to assess its psychometric properties. Sixty patients with temporal lobe epilepsy related to unilateral mesial temporal sclerosis who underwent presurgical evaluation at the Universidade Federal de São Paulo (UNIFESP) formed the sample for this study. The psychometric properties of the ESI-55 included: reliability, validity, and responsiveness. Internal consistency was high in all domains (Cronbach's alpha ranging from 0.76 for Social Function to 0.88 for Physical Function) except Overall Quality of Life (alpha=0.45). Test-retest reliability after 1 week was good, with the intraclass correlation coefficient ranging from 0.79 (Energy/Fatigue) to 0.92 (Role Limitations due to Emotional Problems). Interrater reliability ranged from 0.84 (Cognitive Function) to 0.94 (Role Limitations due to Physical Problems). For construct validity, we verified a high correlation between the ESI-55 and Health Assessment Questionnaire-8 for the Physical Function domain (Pearson linear correlation=-0.84), and a moderate correlation for the Pain domain (P=-0.58), but for the other subscales no correlation was detected. Beck Depression Inventory and ESI-55 domains were highly statistically correlated (ANOVA: P<0.005), but there was no association of the Cognitive Function and Role Limitations due to Memory Problems subscales with neuropsychological evaluation (Pearson coefficient: P>0.05). With respect to demographic characteristics, a statistically significant correlation was observed for the variable educational level (Student t, P<0.005) and ESI-55 scores. There was a high correlation between seizure frequency and ESI-55 domains for clinical variables (ANOVA, P<0.005). Surgical treatment in this series improved health-related quality of life in the seizure-free group in three domains--Health Perception (1.24), Emotional Well-Being (1.32), and Energy/Fatigue (1.48)-as reflected by the standard response mean and the effect size of the sample. Our results support the psychometric properties of the Portuguese version of the ESI-55 as a measure of health-related quality of life.

  14. Physical and chemical properties of pyrethroids.

    PubMed

    Laskowski, Dennis A

    2002-01-01

    The physical and chemical properties of the pyrethroids bifenthrin, cyfluthrin, cypermethrin (also zetacypermethrin), deltamethrin, esfenvalerate (also fenvalerate), fenpropathrin, lambda-cyhalothrin (also cyhalothrin), permethrin, and tralomethrin have been reviewed and summarized in this paper. Physical properties included molecular weight, octanol-water partition coefficient, vapor pressure, water solubility, Henry's law constant, fish biocencentration factor, and soil sorption, desorption, and Freundlich coefficients. Chemical properties included rates of degradation in water as a result of hydrolysis, photodecomposition, aerobic or anaerobic degradation by microorganisms in the absence of light, and also rates of degradation in soil incubated under aerobic or anaerobic conditions. Collectively, the pyrethroids display a highly nonpolar nature of low water solubility, low volatility, high octanol-water partition coefficients, and have high affinity for soil and sediment particulate matter. Pyrethroids have low mobility in soil and are sorbed strongly to the sediments of natural water systems. Although attracted to living organisms because of their nonpolar nature, their capability to bioconcentrate is mitigated by their metabolism and subsequent elimination by the organisms. In fish, bioconcentration factors (BCF) ranged from 360 and 6000. Pyrethroids in water solution tend to be stable at acid and neutral pH but [table: see text] become increasingly susceptible to hydrolysis at pH values beyond neutral. Exceptions at higher pH are bifenthrin (stable), esfenvalerate (stable), and permethrin (half-life, 240 d). Pyrethroids vary in susceptibility to sunlight. Cyfluthrin and tralomethrin in water had half-lives of 0.67 and 2.5 d; lambda-cyhalothrin, esfenvalerate, deltamethrin, permethrin, and cypermethrin were intermediate with a range of 17-110 d; and bifenthrin and fenpropathrin showed the least susceptibility with half-lives of 400 and 600 d, respectively. Pyrethroids on soil can also undergo photolysis, often at rates similar to that in water. Half-lives ranged from 5 to 170 d. [table: see text] Pyrethroids are degradable in soils with half-lives ranging from 3 to 96 d aerobically, and 5 to 430 d anaerobically. For those pyrethroids studied in water (cypermethrin, deltamethrin, esfenvalerate, fenpropathrin, and lambda-cyhalothrin), aerobic and anaerobic degradation often continued at rates similar to that displayed in soil.

  15. Interannual (2009-2013) variability of winter-spring phytoplankton in the open South Adriatic Sea: Effects of deep convection and lateral advection

    NASA Astrophysics Data System (ADS)

    Ljubimir, Stijepo; Jasprica, Nenad; Čalić, Marijeta; Hrustić, Enis; Dupčić Radić, Iris; Car, Ana; Batistić, Mirna

    2017-07-01

    The South Adriatic (SA) is an entry point for water masses originating from the Ionian Sea (IS) and a place of dense water formation for the eastern Mediterranean deep circulation cell. Water masses, entering the SA in larger amount during the winter, show decadal variability explained by different circulating regimes (cyclonic and anticyclonic) in the IS, referred to as "Bimodal Oscillating System" (BiOS). Sampling station was situated in the South Adriatic Pit (SAP) with depth of 1200 m. Micro- and nano-phytoplankton abundances, community structure, chlorophyll a concentrations, physical and chemical properties are presented in the winter and spring months for five consecutive years (2009-2013) during different circulating regimes of BiOS. Vertical convective mixing was regularly observed in winter except in 2011 which had effect on nutrient availability and consequently on biomass of primary producers. Effect of strong vertical mixing in February 2012 resulted with exceptionally high phytoplankton abundance and chlorophyll a concentrations in March of 2012. Strong convective mixing resulted in higher diatom abundances, comparing to winter when mixing did not occur. No such bloom was observed during investigated spring.

  16. Experimental observation of the topological structure of exceptional points in an ultrathin hybridized metamaterial

    NASA Astrophysics Data System (ADS)

    Kang, Ming; Zhu, Weiren; Rukhlenko, Ivan D.

    2017-12-01

    The exceptional point (EP), which is one of the most important branch-type singularities exclusive to non-Hermitian systems, has been observed recently in various synthetic materials, giving rise to counterintuitive phenomena due to the nontrivial topology of the EP. Here, we present a direct experimental observation of the topological structure of the EPs via the angle-resolved transmission measurement of a hybridized metamaterial. Both eigenvalues and eigenvectors show branch-point singularities in the investigated biparametric space of frequency and incident angle. Importantly, the angle-resolved transmission coefficients provide all the information about the eigenvalues as well as the corresponding eigenvectors in the biparametric space, revealing the nontrivial topological structure of the EP, such as mode switching and the topological phase for a parameter loop encircling the EP. It is shown that the appearance of the EP in the scattering matrix is related directly to the perfect unidirectional transmission and the chirality of the EP corresponds to the maximum or minimum value of the asymmetric factor. Our investigation uncovers the capabilities of metamaterials for exploring the physics of EPs and their potential for having extreme optical properties, which provide potential applications in the spectral band ranging from microwaves to visible frequencies.

  17. 10 CFR 603.680 - Purchase of real property and equipment by for-profit firms.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 10 Energy 4 2010-01-01 2010-01-01 false Purchase of real property and equipment by for-profit... INVESTMENT AGREEMENTS Award Terms Affecting Participants' Financial, Property, and Purchasing Systems Property § 603.680 Purchase of real property and equipment by for-profit firms. (a) With the two exceptions...

  18. 24 CFR 35.620 - Multifamily insured property constructed before 1960.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 24 Housing and Urban Development 1 2011-04-01 2011-04-01 false Multifamily insured property... STRUCTURES Multifamily Mortgage Insurance § 35.620 Multifamily insured property constructed before 1960. Except as provided in § 35.630, the following requirements apply to multifamily insured property...

  19. 24 CFR 35.620 - Multifamily insured property constructed before 1960.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... 24 Housing and Urban Development 1 2014-04-01 2014-04-01 false Multifamily insured property... STRUCTURES Multifamily Mortgage Insurance § 35.620 Multifamily insured property constructed before 1960. Except as provided in § 35.630, the following requirements apply to multifamily insured property...

  20. 24 CFR 35.620 - Multifamily insured property constructed before 1960.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... 24 Housing and Urban Development 1 2012-04-01 2012-04-01 false Multifamily insured property... STRUCTURES Multifamily Mortgage Insurance § 35.620 Multifamily insured property constructed before 1960. Except as provided in § 35.630, the following requirements apply to multifamily insured property...

  1. Observation of non-Hermitian degeneracies in a chaotic exciton-polariton billiard.

    PubMed

    Gao, T; Estrecho, E; Bliokh, K Y; Liew, T C H; Fraser, M D; Brodbeck, S; Kamp, M; Schneider, C; Höfling, S; Yamamoto, Y; Nori, F; Kivshar, Y S; Truscott, A G; Dall, R G; Ostrovskaya, E A

    2015-10-22

    Exciton-polaritons are hybrid light-matter quasiparticles formed by strongly interacting photons and excitons (electron-hole pairs) in semiconductor microcavities. They have emerged as a robust solid-state platform for next-generation optoelectronic applications as well as for fundamental studies of quantum many-body physics. Importantly, exciton-polaritons are a profoundly open (that is, non-Hermitian) quantum system, which requires constant pumping of energy and continuously decays, releasing coherent radiation. Thus, the exciton-polaritons always exist in a balanced potential landscape of gain and loss. However, the inherent non-Hermitian nature of this potential has so far been largely ignored in exciton-polariton physics. Here we demonstrate that non-Hermiticity dramatically modifies the structure of modes and spectral degeneracies in exciton-polariton systems, and, therefore, will affect their quantum transport, localization and dynamical properties. Using a spatially structured optical pump, we create a chaotic exciton-polariton billiard--a two-dimensional area enclosed by a curved potential barrier. Eigenmodes of this billiard exhibit multiple non-Hermitian spectral degeneracies, known as exceptional points. Such points can cause remarkable wave phenomena, such as unidirectional transport, anomalous lasing/absorption and chiral modes. By varying parameters of the billiard, we observe crossing and anti-crossing of energy levels and reveal the non-trivial topological modal structure exclusive to non-Hermitian systems. We also observe mode switching and a topological Berry phase for a parameter loop encircling the exceptional point. Our findings pave the way to studies of non-Hermitian quantum dynamics of exciton-polaritons, which may uncover novel operating principles for polariton-based devices.

  2. Statistical Analyses of Satellite Cloud Object Data from CERES. Part III; Comparison with Cloud-Resolving Model Simulations of Tropical Convective Clouds

    NASA Technical Reports Server (NTRS)

    Luo, Yali; Xu, Kuan-Man; Wielicki, Bruce A.; Wong, Takmeng; Eitzen, Zachary A.

    2007-01-01

    The present study evaluates the ability of a cloud-resolving model (CRM) to simulate the physical properties of tropical deep convective cloud objects identified from a Clouds and the Earth s Radiant Energy System (CERES) data product. The emphasis of this study is the comparisons among the small-, medium- and large-size categories of cloud objects observed during March 1998 and between the large-size categories of cloud objects observed during March 1998 (strong El Ni o) and March 2000 (weak La Ni a). Results from the CRM simulations are analyzed in a way that is consistent with the CERES retrieval algorithm and they are averaged to match the scale of the CERES satellite footprints. Cloud physical properties are analyzed in terms of their summary histograms for each category. It is found that there is a general agreement in the overall shapes of all cloud physical properties between the simulated and observed distributions. Each cloud physical property produced by the CRM also exhibits different degrees of disagreement with observations over different ranges of the property. The simulated cloud tops are generally too high and cloud top temperatures are too low except for the large-size category of March 1998. The probability densities of the simulated top-of-the-atmosphere (TOA) albedos for all four categories are underestimated for high albedos, while those of cloud optical depth are overestimated at its lowest bin. These disagreements are mainly related to uncertainties in the cloud microphysics parameterization and inputs such as cloud ice effective size to the radiation calculation. Summary histograms of cloud optical depth and TOA albedo from the CRM simulations of the large-size category of cloud objects do not differ significantly between the March 1998 and 2000 periods, consistent with the CERES observations. However, the CRM is unable to reproduce the significant differences in the observed cloud top height while it overestimates the differences in the observed outgoing longwave radiation and cloud top temperature between the two periods. Comparisons between the CRM results and the observations for most parameters in March 1998 consistently show that both the simulations and observations have larger differences between the large- and small-size categories than between the large- and medium-size, or between the medium- and small-size categories. However, the simulated cloud properties do not change as much with size as observed. These disagreements are likely related to the spatial averaging of the forcing data and the mismatch in time and in space between the numerical weather prediction model from which the forcing data are produced and the CERES observed cloud systems.

  3. [Biodegradation of polyethylene].

    PubMed

    Yang, Jun; Song, Yi-ling; Qin, Xiao-yan

    2007-05-01

    Plastic material is one of the most serious solid wastes pollution. More than 40 million tons of plastics produced each year are discarded into environment. Plastics accumulated in the environment is highly resistant to biodegradation and not be able to take part in substance recycle. To increase the biodegradation efficiency of plastics by different means is the main research direction. This article reviewed the recent research works of polyethylene biodegradation that included the modification and pretreatment of polyethylene, biodegradation pathway, the relevant microbes and enzymes and the changes of physical, chemical and biological properties after biodegradation. The study directions of exploiting the kinds of life-forms of biodegradation polyethylene except the microorganisms, isolating and cloning the key enzymes and gene that could produce active groups, and enhancing the study on polyethylene biodegradation without additive were proposed.

  4. Quantum Dots in Diagnostics and Detection: Principles and Paradigms

    PubMed Central

    Pisanic, T. R.; Zhang, Y.; Wang, T. H.

    2014-01-01

    Quantum dots are semiconductor nanocrystals that exhibit exceptional optical and electrical behaviors not found in their bulk counterparts. Following seminal work in the development of water-soluble quantum dots in the late 1990's, researchers have sought to develop interesting and novel ways of exploiting the extraordinary properties of quantum dots for biomedical applications. Since that time, over 10,000 articles have been published related to the use of quantum dots in biomedicine, many of which regard their use in detection and diagnostic bioassays. This review presents a didactic overview of fundamental physical phenomena associated with quantum dots and paradigm examples of how these phenomena can and have been readily exploited for manifold uses in nanobiotechnology with a specific focus on their implementation in in vitro diagnostic assays and biodetection. PMID:24770716

  5. Duality in Power-Law Localization in Disordered One-Dimensional Systems

    NASA Astrophysics Data System (ADS)

    Deng, X.; Kravtsov, V. E.; Shlyapnikov, G. V.; Santos, L.

    2018-03-01

    The transport of excitations between pinned particles in many physical systems may be mapped to single-particle models with power-law hopping, 1 /ra . For randomly spaced particles, these models present an effective peculiar disorder that leads to surprising localization properties. We show that in one-dimensional systems almost all eigenstates (except for a few states close to the ground state) are power-law localized for any value of a >0 . Moreover, we show that our model is an example of a new universality class of models with power-law hopping, characterized by a duality between systems with long-range hops (a <1 ) and short-range hops (a >1 ), in which the wave function amplitude falls off algebraically with the same power γ from the localization center.

  6. Holmium hafnate: An emerging electronic device material

    NASA Astrophysics Data System (ADS)

    Pavunny, Shojan P.; Sharma, Yogesh; Kooriyattil, Sudheendran; Dugu, Sita; Katiyar, Rajesh K.; Scott, James F.; Katiyar, Ram S.

    2015-03-01

    We report structural, optical, charge transport, and temperature properties as well as the frequency dependence of the dielectric constant of Ho2Hf2O7 (HHO) which make this material desirable as an alternative high-k dielectric for future silicon technology devices. A high dielectric constant of ˜20 and very low dielectric loss of ˜0.1% are temperature and voltage independent at 100 kHz near ambient conditions. The Pt/HHO/Pt capacitor exhibits exceptionally low Schottky emission-based leakage currents. In combination with the large observed bandgap Eg of 5.6 eV, determined by diffuse reflectance spectroscopy, our results reveal fundamental physics and materials science of the HHO metal oxide and its potential application as a high-k dielectric for the next generation of complementary metal-oxide-semiconductor devices.

  7. Maria Goeppert Mayer and the Nobel Prize

    NASA Astrophysics Data System (ADS)

    Johnson, Karen E.

    2013-04-01

    When Maria Goeppert Mayer was awarded the Nobel Prize in Physics in 1963, she was only the second woman to receive that award and there have been no additional female physics laureates since. Mayer was uniquely prepared to carry out her prize-winning work on the nuclear shell model. Furthermore, she worked with some of the most well-known figures in mid-twentieth century physics, and her award came at a time when American science was in ascendance. Why, then, is her name so little known beyond the physics community? There are several possible answers to this question, ranging from the personal (her modest reaction to public acclaim) and the scientific (the mathematically abstract nature of her prize-winning work), to the national (the nature of the issues commanding public attention in the 1960s). In this talk I will present an overview of the circumstances that enabled Mayer to make exceptional contributions to nuclear physics, and then examine some of the possible reasons why her exceptional status is not more widely known.

  8. 41 CFR 301-73.104 - May further exceptions to the required use of the E-Gov Travel Service be approved?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 41 Public Contracts and Property Management 4 2011-07-01 2011-07-01 false May further exceptions to the required use of the E-Gov Travel Service be approved? 301-73.104 Section 301-73.104 Public... further exceptions to the required use of the E-Gov Travel Service be approved? (a) The Administrator of...

  9. 41 CFR 301-73.104 - May further exceptions to the required use of the E-Gov Travel Service be approved?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 41 Public Contracts and Property Management 4 2012-07-01 2012-07-01 false May further exceptions to the required use of the E-Gov Travel Service be approved? 301-73.104 Section 301-73.104 Public... further exceptions to the required use of the E-Gov Travel Service be approved? (a) The Administrator of...

  10. 41 CFR 301-73.104 - May further exceptions to the required use of the E-Gov Travel Service be approved?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 41 Public Contracts and Property Management 4 2013-07-01 2012-07-01 true May further exceptions to the required use of the E-Gov Travel Service be approved? 301-73.104 Section 301-73.104 Public... further exceptions to the required use of the E-Gov Travel Service be approved? (a) The Administrator of...

  11. 41 CFR 301-73.104 - May further exceptions to the required use of the E-Gov Travel Service be approved?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 4 2010-07-01 2010-07-01 false May further exceptions to the required use of the E-Gov Travel Service be approved? 301-73.104 Section 301-73.104 Public... further exceptions to the required use of the E-Gov Travel Service be approved? (a) The Administrator of...

  12. 41 CFR 301-73.104 - May further exceptions to the required use of the E-Gov Travel Service be approved?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 41 Public Contracts and Property Management 4 2014-07-01 2014-07-01 false May further exceptions to the required use of the E-Gov Travel Service be approved? 301-73.104 Section 301-73.104 Public... further exceptions to the required use of the E-Gov Travel Service be approved? (a) The Administrator of...

  13. Generator Set Durability Testing Using 25% ATJ Fuel Blend

    DTIC Science & Technology

    2016-02-01

    Table Page Table 1. Chemical & Physical Properties of Evaluated 25% ATJ Blend .................................................... 3 Table 2... Chemical & Physical Properties of Evaluated 25% ATJ Blend .................................................... 4 Table 3. Chemical & Physical...Properties of Evaluated 25% ATJ Blend .................................................... 5 Table 4. Chemical & Physical Properties of Evaluated 25

  14. Cloning Nacre's 3D Interlocking Skeleton in Engineering Composites to Achieve Exceptional Mechanical Properties.

    PubMed

    Zhao, Hewei; Yue, Yonghai; Guo, Lin; Wu, Juntao; Zhang, Youwei; Li, Xiaodong; Mao, Shengcheng; Han, Xiaodong

    2016-07-01

    Ceramic/polymer composite equipped with 3D interlocking skeleton (3D IL) is developed through a simple freeze-casting method, exhibiting exceptionally light weight, high strength, toughness, and shock resistance. Long-range crack energy dissipation enabled by 3D interlocking structure is considered as the primary reinforcing mechanism for such superior properties. The smart composite design strategy should hold a place in developing future structural engineering materials. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. M4Ag44(p-MBA)30 Molecular Nanoparticles

    NASA Astrophysics Data System (ADS)

    Conn, Brian E.

    In recent years, molecular nanoparticles have attracted much attention due to their unique physical, optical, and electronic properties. The properties of molecular nanoparticles are shown to deviate from their larger bulk counterparts, due to quantum confinement effects and large surface-to-volume ratios. As the size of the nanoparticle shrinks to a cluster of metal atoms (<3 nm in diameter), there is an emergence of a HOMO-LUMO band gap, which is not present in transitional d-block metals. The HOMO-LUMO band gap gives rise to discrete electronic states, leading to new chemical and physical properties. Molecular nanoparticles have had a substantial impact across a diverse range of fields, including catalysis, sensing, photochemistry, optoelectronic, energy conversion, and medicine. Currently many of the synthetic procedures for molecular nanoparticles require low temperatures, long incubation times, multistep purification and hazardous reagents that produce low yields and polydisperse molecular nanoparticles with poor stability. Although silver has very desirable physical properties, good relative abundance and low cost, gold molecular nanoparticles have been widely favored owing to their proved stability and ease of use. Unlike gold, silver is notorious for its susceptibility to oxidation, i.e., tarnishing, which has limited the development of silver-based nanotechnologies. Despite two decades of synthetic efforts, silver molecular nanoparticles that are inert or have long-term stability have remained unrealized. Herein we report a simple synthetic protocol for producing ultrastable M4Ag44(p-MBA)30 nanoparticles as a single-sized molecular product and in exceptionally large quantities. The stability, purity, and yield are substantially better than other metal nanoparticles, including gold, due to several stabilization mechanisms. Also, reported are the structural and mechanical properties of extended crystalline solids of Na4Ag44(p-MBA)30 from large-scale quantum-mechanical simulations based on the atomically-precise X-ray measured structure. Calculations show that cohesion is derived from hydrogen bonds between bundled p-MBA ligands and that the superlattice's mechanical response to hydrostatic compression is characterized by a molecular-solid-like bulk modulus B0 = 16.7 GPa, exhibiting anomalous pressure softening and a compression-induced transition to a soft-solid phase. Such a transition involves ligand flexure, which causes gear-like correlated chiral rotation of the nanoparticles.

  16. Homogeneous studies of transiting extrasolar planets - IV. Thirty systems with space-based light curves

    NASA Astrophysics Data System (ADS)

    Southworth, John

    2011-11-01

    I calculate the physical properties of 32 transiting extrasolar planet and brown-dwarf systems from existing photometric observations and measured spectroscopic parameters. The systems studied include 15 observed by the CoRoT satellite, 10 by Kepler and five by the Deep Impact spacecraft. Inclusion of the objects studied in previous papers leads to a sample of 58 transiting systems with homogeneously measured properties. The Kepler data include observations from Quarter 2, and my analyses of several of the systems are the first to be based on short-cadence data from this satellite. The light curves are modelled using the JKTEBOP code, with attention paid to the treatment of limb darkening, contaminating light, orbital eccentricity, correlated noise and numerical integration over long exposure times. The physical properties are derived from the light-curve parameters, spectroscopic characteristics of the host star and constraints from five sets of theoretical stellar model predictions. An alternative approach using a calibration from eclipsing binary star systems is explored and found to give comparable results whilst imposing a much smaller computational burden. My results are in good agreement with published properties for most of the transiting systems, but discrepancies are identified for CoRoT-5, CoRoT-8, CoRoT-13, Kepler-5 and Kepler-7. Many of the error bars quoted in the literature are underestimated. Refined orbital ephemerides are given for CoRoT-8 and for the Kepler planets. Asteroseismic constraints on the density of the host stars are in good agreement with the photometric equivalents for HD 17156 and TrES-2, but not for HAT-P-7 and HAT-P-11. Complete error budgets are generated for each transiting system, allowing identification of the observations best-suited to improve measurements of their physical properties. Whilst most systems would benefit from further photometry and spectroscopy, HD 17156, HD 80606, HAT-P-7 and TrES-2 are now extremely well characterized. HAT-P-11 is an exceptional candidate for studying starspots. The orbital ephemerides of some transiting systems are becoming uncertain and they should be re-observed in the near future. The primary results from the current work and from previous papers in the series have been placed in an online catalogue, from where they can be obtained in a range of formats for reference and further study. TEPCat is available at

  17. 44 CFR 80.19 - Land use and oversight.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... activities; wetlands management; nature reserves; cultivation; grazing; camping (except where adequate...: Walled buildings, levees, dikes, or floodwalls, paved roads, highways, bridges, cemeteries, landfills... allowable uses. (2) No new structures or improvements will be built on the property except as indicated...

  18. 13 CFR 314.4 - Unauthorized Use of Property.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 13 Business Credit and Assistance 1 2010-01-01 2010-01-01 false Unauthorized Use of Property. 314.4 Section 314.4 Business Credit and Assistance ECONOMIC DEVELOPMENT ADMINISTRATION, DEPARTMENT OF COMMERCE PROPERTY General § 314.4 Unauthorized Use of Property. (a) Except as provided in §§ 314.3...

  19. Using Humor in Physical Education

    ERIC Educational Resources Information Center

    Barney, David; Christenson, Robert

    2013-01-01

    Humor can be extremely beneficial in everyday life, whether giving or receiving it. It can be used to lighten the mood, give encouragement, or make corrections. Humor in physical education is no exception. Physical educators can use humor as a teaching tool and to create an environment for students to acquire the knowledge to practice a lifetime…

  20. Physical-chemical property based sequence motifs and methods regarding same

    DOEpatents

    Braun, Werner [Friendswood, TX; Mathura, Venkatarajan S [Sarasota, FL; Schein, Catherine H [Friendswood, TX

    2008-09-09

    A data analysis system, program, and/or method, e.g., a data mining/data exploration method, using physical-chemical property motifs. For example, a sequence database may be searched for identifying segments thereof having physical-chemical properties similar to the physical-chemical property motifs.

  1. WE-D-204-04: Learning the Ropes: Clinical Immersion in the First Month of Residency

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Dieterich, S.

    Speakers in this session will present overview and details of a specific rotation or feature of their Medical Physics Residency Program that is particularly exceptional and noteworthy. The featured rotations include foundational topics executed with exceptional acumen and innovative educational rotations perhaps not commonly found in Medical Physics Residency Programs. A site-specific clinical rotation will be described, where the medical physics resident follows the physician and medical resident for two weeks into patient consultations, simulation sessions, target contouring sessions, planning meetings with dosimetry, patient follow up visits, and tumor boards, to gain insight into the thought processes of the radiationmore » oncologist. An incident learning rotation will be described where the residents learns about and practices evaluating clinical errors and investigates process improvements for the clinic. The residency environment at a Canadian medical physics residency program will be described, where the training and interactions with radiation oncology residents is integrated. And the first month rotation will be described, where the medical physics resident rotates through the clinical areas including simulation, dosimetry, and treatment units, gaining an overview of the clinical flow and meeting all the clinical staff to begin the residency program. This session will be of particular interest to residency programs who are interested in adopting or adapting these curricular ideas into their programs and to residency candidates who want to learn about programs already employing innovative practices. Learning Objectives: To learn about exceptional and innovative clinical rotations or program features within existing Medical Physics Residency Programs. To understand how to adopt/adapt innovative curricular designs into your own Medical Physics Residency Program, if appropriate.« less

  2. WE-D-204-03: CAMPEP Residencies in a Canadian Context: Comprehensive Cancer Centers and Integrated Learning Environments

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Parker, W.

    Speakers in this session will present overview and details of a specific rotation or feature of their Medical Physics Residency Program that is particularly exceptional and noteworthy. The featured rotations include foundational topics executed with exceptional acumen and innovative educational rotations perhaps not commonly found in Medical Physics Residency Programs. A site-specific clinical rotation will be described, where the medical physics resident follows the physician and medical resident for two weeks into patient consultations, simulation sessions, target contouring sessions, planning meetings with dosimetry, patient follow up visits, and tumor boards, to gain insight into the thought processes of the radiationmore » oncologist. An incident learning rotation will be described where the residents learns about and practices evaluating clinical errors and investigates process improvements for the clinic. The residency environment at a Canadian medical physics residency program will be described, where the training and interactions with radiation oncology residents is integrated. And the first month rotation will be described, where the medical physics resident rotates through the clinical areas including simulation, dosimetry, and treatment units, gaining an overview of the clinical flow and meeting all the clinical staff to begin the residency program. This session will be of particular interest to residency programs who are interested in adopting or adapting these curricular ideas into their programs and to residency candidates who want to learn about programs already employing innovative practices. Learning Objectives: To learn about exceptional and innovative clinical rotations or program features within existing Medical Physics Residency Programs. To understand how to adopt/adapt innovative curricular designs into your own Medical Physics Residency Program, if appropriate.« less

  3. WE-D-204-02: Errors and Process Improvements in Radiation Therapy

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Fontenla, D.

    2016-06-15

    Speakers in this session will present overview and details of a specific rotation or feature of their Medical Physics Residency Program that is particularly exceptional and noteworthy. The featured rotations include foundational topics executed with exceptional acumen and innovative educational rotations perhaps not commonly found in Medical Physics Residency Programs. A site-specific clinical rotation will be described, where the medical physics resident follows the physician and medical resident for two weeks into patient consultations, simulation sessions, target contouring sessions, planning meetings with dosimetry, patient follow up visits, and tumor boards, to gain insight into the thought processes of the radiationmore » oncologist. An incident learning rotation will be described where the residents learns about and practices evaluating clinical errors and investigates process improvements for the clinic. The residency environment at a Canadian medical physics residency program will be described, where the training and interactions with radiation oncology residents is integrated. And the first month rotation will be described, where the medical physics resident rotates through the clinical areas including simulation, dosimetry, and treatment units, gaining an overview of the clinical flow and meeting all the clinical staff to begin the residency program. This session will be of particular interest to residency programs who are interested in adopting or adapting these curricular ideas into their programs and to residency candidates who want to learn about programs already employing innovative practices. Learning Objectives: To learn about exceptional and innovative clinical rotations or program features within existing Medical Physics Residency Programs. To understand how to adopt/adapt innovative curricular designs into your own Medical Physics Residency Program, if appropriate.« less

  4. WE-D-204-01: Site-Specific Clinical Rotation: Into the Minds of the Radiation Oncologists

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Hendrickson, K.

    2016-06-15

    Speakers in this session will present overview and details of a specific rotation or feature of their Medical Physics Residency Program that is particularly exceptional and noteworthy. The featured rotations include foundational topics executed with exceptional acumen and innovative educational rotations perhaps not commonly found in Medical Physics Residency Programs. A site-specific clinical rotation will be described, where the medical physics resident follows the physician and medical resident for two weeks into patient consultations, simulation sessions, target contouring sessions, planning meetings with dosimetry, patient follow up visits, and tumor boards, to gain insight into the thought processes of the radiationmore » oncologist. An incident learning rotation will be described where the residents learns about and practices evaluating clinical errors and investigates process improvements for the clinic. The residency environment at a Canadian medical physics residency program will be described, where the training and interactions with radiation oncology residents is integrated. And the first month rotation will be described, where the medical physics resident rotates through the clinical areas including simulation, dosimetry, and treatment units, gaining an overview of the clinical flow and meeting all the clinical staff to begin the residency program. This session will be of particular interest to residency programs who are interested in adopting or adapting these curricular ideas into their programs and to residency candidates who want to learn about programs already employing innovative practices. Learning Objectives: To learn about exceptional and innovative clinical rotations or program features within existing Medical Physics Residency Programs. To understand how to adopt/adapt innovative curricular designs into your own Medical Physics Residency Program, if appropriate.« less

  5. The mobility gap between older men and women: the embodiment of gender.

    PubMed

    Zunzunegui, M V; Alvarado, B E; Guerra, R; Gómez, J F; Ylli, A; Guralnik, J M

    2015-01-01

    To present the study design and baseline results of the longitudinal International Mobility in Aging Study (IMIAS) on gender differences in physical performance and mobility disability prevalence in five diverse societies. Data are from surveys on random samples of people aged 65-74 years at Canadian (Kingston, Ontario; Saint-Hyacinthe, Quebec), Mediterranean (Tirana, Albania) and Latin American sites (Natal, Brazil; Manizales, Colombia) (N=1995). Mobility disability was defined as reporting difficulty in walking 400m or climbing stairs. Activities of daily living (ADL) disability was based on any self-reported difficulty in five mobility-related ADLs. The short physical performance battery (SPPB) was used to assess physical performance. Poisson regression models were fitted to estimate prevalence ratios. Age-adjusted prevalence of low SPPB, mobility disability and ADL disability were higher in women than in men in all sites except for Kingston. After adjustment for education and income, gender differences in SPPB and ADL disability attenuated or disappeared in Saint-Hyacinthe and Manizales but remained large in Tirana and Natal and mobility disability remained more frequent in women than in men at all sites except Kingston. After further adjustment by chronic conditions and depressive symptoms, gender differences in mobility remained large at all sites except Kingston but only in Tirana did women have significantly poorer physical performance than men. Results provide evidence for gender as a risk factor to explain poorer physical function in women and suggest that moving toward gender equality could attenuate the gender gap in physical function in old age. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

  6. Prevalence, characteristics, and impacts of work-related musculoskeletal disorders: a survey among physical therapists in the State of Kuwait

    PubMed Central

    2010-01-01

    Background Physical therapists working in the State of Kuwait are at risk of work-related musculoskeletal disorders (WMSDs). However, prevalence rates and risk factors are not well documented. The objective of this study was to determine the prevalence, characteristics, and impacts of WMSDs among physical therapists in the State of Kuwait. Methods A self-administered questionnaire was distributed to 350 physical therapists. The questionnaire gathered demographic data as well as information on occurrence of musculoskeletal complaints in the previous 12 months. Descriptive statistics, frequency, and Chi-square analyses were used. Results The response rate to the questionnaire was 63% (222/350). Of the 212 responders included in the study, the one-year prevalence of WMSDs was 47.6%, with lower back complaints as the most common (32%). This was followed by neck (21%), upper back (19%), shoulder (13%), hand/wrist (11%), knee (11%), ankle/foot (6%), elbow (4%), and hip/thigh (3%) complaints. The frequency of WMSDs was not gender related (except lower back, neck, and shoulder complaints) nor was it related to age (except lower back complaints), working venues (except hand/wrist), working hours, area of specialty, or exercise. WMSDs' impact on work was minor. Conclusions WMSDs among physical therapists in Kuwait were common, with lower back and neck affected most. Lower back and neck WMSDs were related to the participant's demographics. Hand/wrist WMSDs were related to work settings. Further research is needed to investigate the effect of risk factors as physical load, psychosocial load, and general health status on prevalence musculoskeletal disorders. PMID:20540724

  7. 41 CFR 109-1.5107 - Physical protection of personal property.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 41 Public Contracts and Property Management 3 2012-01-01 2012-01-01 false Physical protection of personal property. 109-1.5107 Section 109-1.5107 Public Contracts and Property Management Federal Property...-INTRODUCTION 1.51-Personal Property Management Standards and Practices § 109-1.5107 Physical protection of...

  8. 41 CFR 109-1.5107 - Physical protection of personal property.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 41 Public Contracts and Property Management 3 2014-01-01 2014-01-01 false Physical protection of personal property. 109-1.5107 Section 109-1.5107 Public Contracts and Property Management Federal Property...-INTRODUCTION 1.51-Personal Property Management Standards and Practices § 109-1.5107 Physical protection of...

  9. 41 CFR 109-1.5107 - Physical protection of personal property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Physical protection of personal property. 109-1.5107 Section 109-1.5107 Public Contracts and Property Management Federal Property...-INTRODUCTION 1.51-Personal Property Management Standards and Practices § 109-1.5107 Physical protection of...

  10. 41 CFR 109-1.5107 - Physical protection of personal property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 41 Public Contracts and Property Management 3 2013-07-01 2013-07-01 false Physical protection of personal property. 109-1.5107 Section 109-1.5107 Public Contracts and Property Management Federal Property...-INTRODUCTION 1.51-Personal Property Management Standards and Practices § 109-1.5107 Physical protection of...

  11. 41 CFR 109-1.5107 - Physical protection of personal property.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 41 Public Contracts and Property Management 3 2011-01-01 2011-01-01 false Physical protection of personal property. 109-1.5107 Section 109-1.5107 Public Contracts and Property Management Federal Property...-INTRODUCTION 1.51-Personal Property Management Standards and Practices § 109-1.5107 Physical protection of...

  12. Observational physics of mirror world

    NASA Technical Reports Server (NTRS)

    Khlopov, M. YA.; Beskin, G. M.; Bochkarev, N. E.; Pustilnik, L. A.; Pustilnik, S. A.

    1989-01-01

    The existence of the whole world of shadow particles, interacting with each other and having no mutual interactions with ordinary particles except gravity is a specific feature of modern superstring models, being considered as models of the theory of everything. The presence of shadow particles is the necessary condition in the superstring models, providing compensation of the asymmetry of left and right chirality states of ordinary particles. If compactification of additional dimensions retains the symmetry of left and right states, shadow world turns to be the mirror one, with particles and fields having properties strictly symmetrical to the ones of corresponding ordinary particles and fields. Owing to the strict symmetry of physical laws for ordinary and mirror particles, the analysis of cosmological evolution of mirror matter provides rather definite conclusions on possible effects of mirror particles in the universe. A general qualitative discussion of possible astronomical impact of mirror matter is given, in order to make as wide as possible astronomical observational searches for the effects of mirror world, being the unique way to test the existence of mirror partners of ordinary particles in the Nature.

  13. OSO-8 X-ray spectra of clusters of galaxies. 1. Observations of twenty clusters: Physical correlations

    NASA Technical Reports Server (NTRS)

    Mushotzky, R. F.; Serlemitsos, P. J.; Smith, B. W.; Boldt, E. A.; Holt, S. S.

    1978-01-01

    OSO-8 X-ray spectra from 2 to 20 keV were analyzed for 26 clusters of galaxies. Temperature, emission integrals, iron abundances, and low energy absorption measurements are given. Eight clusters have positive iron emission line detections at the 90% confidence level, and all twenty cluster spectra are consistent with Fe/H=0.000014 by number with the possible exception of Virgo. Physical correlations between X-ray spectral parameters and other cluster properties are examined. It is found that: (1) the X-ray temperature is approximately proportional to the square of the velocity dispersion of the galaxies; (2) the emission integral and therefore the bolometric X-ray luminosity is a strong function of the X-ray temperature; (3) the X-ray temperature and emission integral are better correlated with cluster central galaxy density than with richness; (4) temperature and emission integral are separately correlated with Rood-Sastry type; and (5) the fraction of galaxies which are spirals is correlated with the observed ram pressure in the cluster core.

  14. Bambara-wheat composite flour: rheological behavior of dough and functionality in bread.

    PubMed

    Erukainure, Ochuko L; Okafor, Jane N C; Ogunji, Akinyele; Ukazu, Happiness; Okafor, Ebele N; Eboagwu, Ijeoma L

    2016-11-01

    The rheological behavior and functional properties of doughs from bambara-wheat composite flour was investigated. Bambara-wheat composite flour was prepared by substituting wheat with 0%, 10%, 15%, and 20% of bambara flour. The rheological behavior of their dough was analyzed with Mixolab. Breads produced from the flour were analyzed for physical characteristics. Organoleptic analysis was carried out by 20 panelists. Mixolab analysis revealed, except for stability time, depreciating values for dough consistency (C1), protein weakening (C2), starch gelatinization (C3), amylase activity (C4), and retrogradation (C5) as the inclusion of bambara flour increased. Physical characteristics of the loaves revealed significant ( P  < 0.05) decreasing bread volume and increasing specific volume, respectively, as bambara inclusion increased. There was significant ( P  < 0.05) difference between wheat bread and the bambara-wheat composites in all the studied quality attributes. 15% bambara-wheat composite bread was the most accepted amongst the composite breads. Inclusion of bambara flour improved the protein behavior of the composite, but did not evidently show benefits in the baking characteristics.

  15. Simple fundamental equation of state for liquid, gas, and fluid of argon, nitrogen, and carbon dioxide

    NASA Astrophysics Data System (ADS)

    Kaplun, A. B.; Meshalkin, A. B.

    2017-07-01

    A new fundamental low-parametric equation of state in the form of reduced Helmholtz function for describing thermodynamic properties of normal substances was obtained using the methods and approaches developed earlier by the authors. It allows us to describe the thermal properties of gas, liquid, and fluid in the range from the density in ideal-gas state to the density at a triple point (except the critical region) with sufficiently high accuracy close to the accuracy of experiment. The caloric properties and sound velocity of argon, nitrogen, and carbon dioxide are calculated without involving any caloric data, except the ideal gas enthalpy. The obtained values of isochoric heat capacity, sound velocity, and other thermodynamic properties are in good agreement with experimental (reliable tabular) data.

  16. A low-parametric state equation for calculating the thermodynamic properties of substances in liquid and gaseous state

    NASA Astrophysics Data System (ADS)

    Kaplun, A. B.; Meshalkin, A. B.

    2013-08-01

    Using methods and approaches developed by the authors, a new low-parametric state equation for describing the thermal properties of normal substances is obtained that allows us to describe the thermal properties of gases, liquids, and fluids over a range of densities from the ideal gas state to the triple point, except for a critical region, with a high degree of accuracy close to that of an experiment. The caloric properties and speed of sound are calculated for argon, nitrogen, and carbon dioxide without using any caloric data except for the enthalpy of an ideal gas. It is established that the calculated values of enthalpy, heat capacity, the speed of speed of sound, etc., are in good agreement with the experimental (reliably tabulated) data.

  17. Soil micromorphology, geochemistry and microbiology at two sites on James Ross Island, Maritime Antarctica

    NASA Astrophysics Data System (ADS)

    Meier, Lars A.; Krauze, Patryk; Prater, Isabel; Scholten, Thomas; Wagner, Dirk; Kühn, Peter; Mueller, Carsten W.

    2017-04-01

    Referring to the fundamental question in ecosystem research, how biotic and abiotic processes interact, only a few studies exist for polar regions that integrate microbiological and soil scientific studies . Soils comprise the complex structure and environment that fosters water storage and nutrient cycling determined by its unique chemical, physical and biological properties with respect to the specific climate and parent material. In the extreme environment of Antarctica, soil biological processes are primarily controlled by microbial communities (Bacteria, Archaea and Fungi), and thus microbiota may also determine soils chemical and physical properties in a landscape lacking higher plants at an average air temperature below 0°C. James Ross Island, Maritime Antarctica, offers a pristine laboratory and an exceptional opportunity to study pedogenesis without the influence of vascular plants and burrowing animals. We analysed micromorphological features, chemical and microbiological measures at two sites on James Ross Island (Brandy Bay and St. Martha Cove) with similar substrates (mostly fine-grained calcareous sandstones and siltstones of the Alpha Member of the Santa Martha Formation with varying amounts of conglomerates and mudstones) at similar topographic positions (small plateaus at similar elevation (80m a.s.l.)). The sites represent luv- and leeward conditions with respect to the main southwesterly winds. The climate on James Ross Island is to be described as semi-arid polar-continental, which is in clear contrast to the Southern Shetlands (e.g. King George Island) north of the Antarctic Peninsula. We will present first results of soil physical (bulk density, soil moisture and grains size distribution), pedochemical (SOC, total N and S, pH, CECeff, and pedogenic oxides) micromorphological and microbial analyses (Microbial DNA content, microbial abundances).

  18. Cross-cultural adaptation, reliability, and validity of the work role functioning questionnaire to Brazilian Portuguese.

    PubMed

    Gallasch, Cristiane Helena; Alexandre, Neusa Maria Costa; Amick, Benjamin

    2007-12-01

    The study objectives were to translate and adapt the Work Role Functioning Questionnaire (WRFQ) into the Brazilian Portuguese language and evaluate its reliability in patients experiencing musculoskeletal disorders. The cross-cultural adaptation was performed according to the internationally recommended methodology, using the following guidelines: translation, back-translation, revision by a committee, and pretest. At first, the questionnaire was independently translated by two bilingual translators, who had Portuguese as their mother language. Subsequently, two other translators whose mother language was English did the back-translation. A committee composed of five specialists revised and compared the translations obtained, developing the final version for pretest application. The pretest was carried out with 30 patients experiencing musculoskeletal disorders. Psychometric properties were evaluated by administering the questionnaire to 105 subjects with musculoskeletal disorders and receiving physical therapy treatment. The reliability was estimated through stability and homogeneity assessment. The construct validity was tested comparing subjects experiencing musculoskeletal disorders to healthy workers. The results indicated good content validity and internal consistency (Cronbach alpha = 0.95). Cronbach alpha for each scale was >0.85, except for the social demand scale. The Intraclass Correlation Coefficient for the test-retest reliability was satisfactory for mental demands (ICC = 0.68) and excellent for the others (0.82-0.91). In relation to the construct validity, the mean score obtained for each scale was lower for physical, work scheduling, and output demands in the subjects with musculoskeletal disorders. There was a significant difference (p < 0.001) between the groups in comparison to work scheduling, physical, and output demands. The data showed that the cross-cultural adaptation process was successful and the adapted instrument demonstrated psychometric properties making it reliable to use in Brazilian culture.

  19. Increasing Fathers' Participation in Therapeutic Intervention Programs for Exceptional Children.

    ERIC Educational Resources Information Center

    Revelj, Elizabeth O.

    In response to a research review indicating that few programs address the father's role in early intervention and preschool programs for the young exceptional child, a three-month practicum was designed which included fathers in physical therapy sessions and in daily home exercise programming for their developmentally disabled children. Practicum…

  20. Review of mechanisms, methods, and theory for determining recharge to shallow aquifers in North Dakota

    USGS Publications Warehouse

    Horak, W.F.

    1988-01-01

    Effective management of ground-water resources requires knowledge of all components of the water budget for the aquifer of interest. Efforts to simulate ground-water flow prior to development and the effects of proposed pumping in several of North Dakota's shallow glacial aquifers have been hindered by the lack of reliable estimates of ground-water recharge. This study was done to (1) review the methods that have been used to measure recharge, (2) review the theory of unsaturated flow and the methods for characterizing the physical properties of unsaturated media, (3) consider the relative merits of a rigorous data-intensive approach versus an estimation approach to the study of recharge, and (4) review past and current agronomic research in North Dakota for applicability of the research and the data generated to the study of recharge.Direct, quantitative techniques for evaluating recharge are rarely applied. The theory for computing fluxes in unsaturated media is well established and numerous physics-based models that effectively implement the theory are available, but the data required for the models generally are lacking. Many parametric approaches have been developed to avoid the large data requirements of the physics-based approaches for analyzing flow in the unsaturated zone. However, the parametric approaches normally include fitting coefficients that must be calibrated for every study site, thereby detracting from the general utility of the parametric approach. The functional relation of matric potential to moisture content is required for physics-based soil-water models, whether analytic or numeric. Laboratory methods to determine these relations are tedious, costly, and may not give results representative of the soils as they occur in the field. Many models have been proposed to estimate the moisture-characteristic curve and hydraulic-conductivity function from basic soil properties, but none yield results that are universally satisfactory. In situ methods, because they require minimal disturbance of the soil profile and may be used repeatedly on the same soil mass, have become the preferred means for acquiring physical data, especially hydraulic conductivity. Hydro logic investigations, except for recent studies of hazardous-waste disposal sites, rarely have included physical characterizations of unsaturated media. Any of four phenomena could hinder attempts to simulate unsaturated flow in settings typical of North Dakota; variability of soil properties, hysteresis, frozen ground, and macropore development. The spatial and temporal variability of soil properties probably is the greatest complicating phenomenon and must be dealt with by detailed characterization of the properties. Hysteresis can detract from the accuracy of flow calculations for some soils under certain conditions but, for the present, our scant knowledge of soil physical properties is a greater hindrance to reliable soi1-water mode 1 ing than is the hysteresis phenomenon. A1 though seasona1ly frozen ground undoubtedly affects hydrologic processes in North Dakota, much more research is needed before meaningful quantitative treatment is possible. Finally, macropores can influence soil-water movement significantly, but macropore development may not be common on the intensively farmed, coarse-textured soils that typically overlie North Dakota's glacial aquifers. Lysimetry currently is the only reliable means of analyzing macropore flow.The soil-related research that has been conducted in North Dakota to date (1983) provides little of the type of information required to estimate ground-water recharge. Useful data could be developed by systematically evaluating the hydraulic characteristics of the prominent soil types overlying North Dakota's shallow glacial aquifers. These data would be required to enable use of a physics-based approach to estimating recharge. The size of the aquifer under study, its economic value, and the resources available for data collection should be considered when choosing between parametric or physics-based methods.

  1. Validity and Reliability of Malay Version of the Job Content Questionnaire among Public Hospital Female Nurses in Malaysia.

    PubMed

    Amin, N A; Quek, K F; Oxley, J A; Noah, R M; Nordin, R

    2015-10-01

    The Job Content Questionnaire (M-JCQ) is an established self-reported instrument used across the world to measure the work dimensions based on the Karasek's demand-control-support model. To evaluate the psychometrics properties of the Malay version of M-JCQ among nurses in Malaysia. This cross-sectional study was carried out on nurses working in 4 public hospitals in Klang Valley area, Malaysia. M-JCQ was used to assess the perceived psychosocial stressors and physical demands of nurses at their workplaces. Construct validity of the questionnaire was examined using exploratory factor analysis (EFA). Cronbach's α values were used to estimate the reliability (internal consistency) of the M-JCQ. EFA showed that 34 selected items were loaded in 4 factors. Except for psychological job demand (Cronbach's α 0.51), the remaining 3 α values for 3 subscales (job control, social support, and physical demand) were greater than 0.70, indicating acceptable internal consistency. However, an item was excluded due to poor item-total correlation (r<0.3). The final M-JCQ was consisted of 33 items. The M-JCQ is a reliable and valid instrument to measure psychosocial and physical stressors in the workplace of public hospital nurses in Malaysia.

  2. 24 CFR 203.378 - Property condition.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... the Commissioner, the property shall be undamaged by fire, earthquake, flood, or tornado, except as... mortgagee shall be responsible for: (1) Damage by fire, flood, earthquake, hurricane, or tornado; (2) Damage...

  3. 24 CFR 203.378 - Property condition.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... the Commissioner, the property shall be undamaged by fire, earthquake, flood, or tornado, except as... mortgagee shall be responsible for: (1) Damage by fire, flood, earthquake, hurricane, or tornado; (2) Damage...

  4. 24 CFR 203.378 - Property condition.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... the Commissioner, the property shall be undamaged by fire, earthquake, flood, or tornado, except as... mortgagee shall be responsible for: (1) Damage by fire, flood, earthquake, hurricane, or tornado; (2) Damage...

  5. 24 CFR 203.378 - Property condition.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... the Commissioner, the property shall be undamaged by fire, earthquake, flood, or tornado, except as... mortgagee shall be responsible for: (1) Damage by fire, flood, earthquake, hurricane, or tornado; (2) Damage...

  6. 24 CFR 203.378 - Property condition.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... the Commissioner, the property shall be undamaged by fire, earthquake, flood, or tornado, except as... mortgagee shall be responsible for: (1) Damage by fire, flood, earthquake, hurricane, or tornado; (2) Damage...

  7. 24 CFR 203.32 - Mortgage lien.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... obligations contracted in connection with the mortgage transaction or the purchase of the mortgaged property, except obligations that are secured by property or collateral owned by the mortgagor independently of the...

  8. Photonics and optoelectronics of two-dimensional materials beyond graphene.

    PubMed

    Ponraj, Joice Sophia; Xu, Zai-Quan; Dhanabalan, Sathish Chander; Mu, Haoran; Wang, Yusheng; Yuan, Jian; Li, Pengfei; Thakur, Siddharatha; Ashrafi, Mursal; Mccoubrey, Kenneth; Zhang, Yupeng; Li, Shaojuan; Zhang, Han; Bao, Qiaoliang

    2016-11-18

    Apart from conventional materials, the study of two-dimensional (2D) materials has emerged as a significant field of study for a variety of applications. Graphene-like 2D materials are important elements of potential optoelectronics applications due to their exceptional electronic and optical properties. The processing of these materials towards the realization of devices has been one of the main motivations for the recent development of photonics and optoelectronics. The recent progress in photonic devices based on graphene-like 2D materials, especially topological insulators (TIs) and transition metal dichalcogenides (TMDs) with the methodology level discussions from the viewpoint of state-of-the-art designs in device geometry and materials are detailed in this review. We have started the article with an overview of the electronic properties and continued by highlighting their linear and nonlinear optical properties. The production of TIs and TMDs by different methods is detailed. The following main applications focused towards device fabrication are elaborated: (1) photodetectors, (2) photovoltaic devices, (3) light-emitting devices, (4) flexible devices and (5) laser applications. The possibility of employing these 2D materials in different fields is also suggested based on their properties in the prospective part. This review will not only greatly complement the detailed knowledge of the device physics of these materials, but also provide contemporary perception for the researchers who wish to consider these materials for various applications by following the path of graphene.

  9. Photonics and optoelectronics of two-dimensional materials beyond graphene

    NASA Astrophysics Data System (ADS)

    Ponraj, Joice Sophia; Xu, Zai-Quan; Chander Dhanabalan, Sathish; Mu, Haoran; Wang, Yusheng; Yuan, Jian; Li, Pengfei; Thakur, Siddharatha; Ashrafi, Mursal; Mccoubrey, Kenneth; Zhang, Yupeng; Li, Shaojuan; Zhang, Han; Bao, Qiaoliang

    2016-11-01

    Apart from conventional materials, the study of two-dimensional (2D) materials has emerged as a significant field of study for a variety of applications. Graphene-like 2D materials are important elements of potential optoelectronics applications due to their exceptional electronic and optical properties. The processing of these materials towards the realization of devices has been one of the main motivations for the recent development of photonics and optoelectronics. The recent progress in photonic devices based on graphene-like 2D materials, especially topological insulators (TIs) and transition metal dichalcogenides (TMDs) with the methodology level discussions from the viewpoint of state-of-the-art designs in device geometry and materials are detailed in this review. We have started the article with an overview of the electronic properties and continued by highlighting their linear and nonlinear optical properties. The production of TIs and TMDs by different methods is detailed. The following main applications focused towards device fabrication are elaborated: (1) photodetectors, (2) photovoltaic devices, (3) light-emitting devices, (4) flexible devices and (5) laser applications. The possibility of employing these 2D materials in different fields is also suggested based on their properties in the prospective part. This review will not only greatly complement the detailed knowledge of the device physics of these materials, but also provide contemporary perception for the researchers who wish to consider these materials for various applications by following the path of graphene.

  10. Impacts of Near-Future Ocean Acidification and Warming on the Shell Mechanical and Geochemical Properties of Gastropods from Intertidal to Subtidal Zones.

    PubMed

    Leung, Jonathan Y S; Connell, Sean D; Nagelkerken, Ivan; Russell, Bayden D

    2017-11-07

    Many marine organisms produce calcareous shells as the key structure for defense, but the functionality of shells may be compromised by ocean acidification and warming. Nevertheless, calcifying organisms may adaptively modify their shell properties in response to these impacts. Here, we examined how reduced pH and elevated temperature affect shell mechanical and geochemical properties of common grazing gastropods from intertidal to subtidal zones. Given the greater environmental fluctuations in the intertidal zone, we hypothesized that intertidal gastropods would exhibit more plastic responses in shell properties than subtidal gastropods. Overall, three out of five subtidal gastropods produced softer shells at elevated temperature, while intertidal gastropods maintained their shell hardness at both elevated pCO 2 (i.e., reduced pH) and temperature. Regardless of pH and temperature, degree of crystallization was maintained (except one subtidal gastropod) and carbonate polymorph remained unchanged in all tested species. One intertidal gastropod produced less soluble shells (e.g., higher calcite/aragonite) in response to reduced pH. In contrast, subtidal gastropods produced only aragonite which has higher solubility than calcite. Overall, subtidal gastropods are expected to be more susceptible than intertidal gastropods to shell dissolution and physical damage under future seawater conditions. The increased vulnerability to shell dissolution and predation could have serious repercussions for their survival and ecological contributions in the future subtidal environment.

  11. A Comparative Study of Chemically and Biologically Synthesized MgO Nanomaterial for Liquefied Petroleum Gas Detection

    NASA Astrophysics Data System (ADS)

    Thirupathi, Rampelly; Solleti, Goutham; Sreekanth, Tirumala; Sadasivuni, Kishor Kumar; Venkateswara Rao, Kalagadda

    2018-03-01

    The exceptional chemical and physical properties of nanostructured materials are extremely suitable for designing new and enhanced sensing devices, particularly gas sensors and biosensors. The present work describes the synthesis of magnesium oxide (MgO) nanoparticles through two methods: a green synthesis using aloe vera plant extract and a chemical method using a glycine-based solution combustion route. In a single step, the extracted organic molecules from aloe vera plants were used to reduce metal ions by the green method. MgO nanoparticles were coated onto the interdigital electrode using the drop-drying method. The dynamic gas-sensing characteristics were measured for liquefied petroleum gas (LPG) at different concentrations and various temperatures. The MgO nanoparticles were characterized by using x-ray diffraction, field emission scanning electron microscopy, and high-resolution transmission electron microscopy to determine the size and structure of the particles. The product's functional properties were analyzed by Fourier transform-infrared spectroscopy and UV-visible spectroscopy. We found that the LPG sensing behavior of biologically synthesized MgO registers excellent sensitivity at various operating temperatures.

  12. A Comparative Study of Chemically and Biologically Synthesized MgO Nanomaterial for Liquefied Petroleum Gas Detection

    NASA Astrophysics Data System (ADS)

    Thirupathi, Rampelly; Solleti, Goutham; Sreekanth, Tirumala; Sadasivuni, Kishor Kumar; Venkateswara Rao, Kalagadda

    2018-07-01

    The exceptional chemical and physical properties of nanostructured materials are extremely suitable for designing new and enhanced sensing devices, particularly gas sensors and biosensors. The present work describes the synthesis of magnesium oxide (MgO) nanoparticles through two methods: a green synthesis using aloe vera plant extract and a chemical method using a glycine-based solution combustion route. In a single step, the extracted organic molecules from aloe vera plants were used to reduce metal ions by the green method. MgO nanoparticles were coated onto the interdigital electrode using the drop-drying method. The dynamic gas-sensing characteristics were measured for liquefied petroleum gas (LPG) at different concentrations and various temperatures. The MgO nanoparticles were characterized by using x-ray diffraction, field emission scanning electron microscopy, and high-resolution transmission electron microscopy to determine the size and structure of the particles. The product's functional properties were analyzed by Fourier transform-infrared spectroscopy and UV-visible spectroscopy. We found that the LPG sensing behavior of biologically synthesized MgO registers excellent sensitivity at various operating temperatures.

  13. CONCEPTUAL DESIGN REPORT

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    ROBINSON,K.

    2006-12-31

    Brookhaven National Laboratory has prepared a conceptual design for a world class user facility for scientific research using synchrotron radiation. This facility, called the ''National Synchrotron Light Source II'' (NSLS-II), will provide ultra high brightness and flux and exceptional beam stability. It will also provide advanced insertion devices, optics, detectors, and robotics, and a suite of scientific instruments designed to maximize the scientific output of the facility. Together these will enable the study of material properties and functions with a spatial resolution of {approx}1 nm, an energy resolution of {approx}0.1 meV, and the ultra high sensitivity required to perform spectroscopymore » on a single atom. The overall objective of the NSLS-II project is to deliver a research facility to advance fundamental science and have the capability to characterize and understand physical properties at the nanoscale, the processes by which nanomaterials can be manipulated and assembled into more complex hierarchical structures, and the new phenomena resulting from such assemblages. It will also be a user facility made available to researchers engaged in a broad spectrum of disciplines from universities, industries, and other laboratories.« less

  14. NUMERICAL SIMULATIONS OF KELVIN–HELMHOLTZ INSTABILITY: A TWO-DIMENSIONAL PARAMETRIC STUDY

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Tian, Chunlin; Chen, Yao, E-mail: chunlin.tian@sdu.edu.cn

    2016-06-10

    Using two-dimensional simulations, we numerically explore the dependences of Kelvin–Helmholtz (KH) instability upon various physical parameters, including viscosity, the width of the sheared layer, flow speed, and magnetic field strength. In most cases, a multi-vortex phase exists between the initial growth phase and the final single-vortex phase. The parametric study shows that the evolutionary properties, such as phase duration and vortex dynamics, are generally sensitive to these parameters, except in certain regimes. An interesting result is that for supersonic flows, the phase durations and saturation of velocity growth approach constant values asymptotically as the sonic Mach number increases. We confirmmore » that the linear coupling between magnetic field and KH modes is negligible if the magnetic field is weak enough. The morphological behavior suggests that the multi-vortex coalescence might be driven by the underlying wave–wave interaction. Based on these results, we present a preliminary discussion of several events observed in the solar corona. The numerical models need to be further improved to perform a practical diagnostic of the coronal plasma properties.« less

  15. 7 CFR 1955.56 - Real property located in Coastal Barrier Resources System (CBRS).

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 7 Agriculture 14 2010-01-01 2009-01-01 true Real property located in Coastal Barrier Resources... Management of Property § 1955.56 Real property located in Coastal Barrier Resources System (CBRS). (a... Coastal Barrier Resources Act (CBRA). Pursuant to the requirements of the CBRA, and except as specified in...

  16. 49 CFR 397.7 - Parking.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... traveled portion of a public street or highway; (2) On private property (including premises of fueling or... bridge, tunnel, dwelling, or place where people work, congregate, or assemble, except for brief periods... public street or highway except for brief periods when the necessities of operation require the vehicle...

  17. The Effect of Professional Development on Physical Education Instruction in Middle Schools

    ERIC Educational Resources Information Center

    Sears, Jack V.; Edgington, William D.; Hynes, James W.

    2013-01-01

    Most teachers want to learn and improve, and physical education teachers are no exception. Although their teaching field is not subject to standardized testing, physical education teachers seek to find support structures and development opportunities from within their schools and districts so that they feel connected and a part of the professional…

  18. 77 FR 33098 - Hours of Service of Drivers of Commercial Motor Vehicles; Regulatory Guidance for Oilfield Exception

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-06-05

    ... their ability to operate the vehicles safely; (3) the physical condition of operators of CMVs is adequate to enable them to operate the vehicles safely and the periodic physical examinations required of such operators are performed by medical examiners who have received training in physical and medical...

  19. Thermal Analysis of Nanofluids Using Modeling and Molecular Dynamics Simulation

    NASA Astrophysics Data System (ADS)

    Namboori, P. K. Krishnan; Vasavi, C. S.; Gopal, K. Varun; Gopakumar, Deepa; Ramachandran, K. I.; Narayanan, B. Sabarish

    2010-10-01

    Nanofluids are nanotechnology-based heat transfer fluids obtained by suspending nanometer-sized particles in conventional heat transfer fluids in a stable manner. In many of the physical phenomena such as boiling and properties such as latent heat, thermal conductivity and heat transfer coefficient, there is significant change on addition of nanoparticles. These exceptional qualities of Nanofluids mainly depend on the atomic level mechanisms, which in turn govern all mechanical properties like strength, Young's modulus, Poisson's ratio, compressibility etc. Control over the fundamental thermo physical properties of the working medium will help to understand these unique phenomena of nanofluids to a great extent. Macroscopic modeling approaches, which are based on conventional relations of thermodynamics, have been proved to be incompetent to explain this difference. Atomistic `modeling and simulation' has been emerged out as an efficient alternative for this. The enhancement of thermal conductivity of water by suspending nanoparticle inclusions has been experimented and proved to be an effective method of enhancing convective heat dissipation. This work mainly deals with characterization of the thermal conductivity of nanofluids. Nano particle sized aluminium oxide; copper oxide and titanium dioxide have been taken in this work for the analysis of thermal conductivity. The effect of thermal conductivity on parameters like volume concentration of the fluid, nature of particle material and size of the particle has been computationally formulated. It has been found that there is an increase in effective thermal conductivity of the fluid by the addition of nanomaterials ascertaining an improvement in the heat transfer behavior of nanofluids. This facilitates the reduction in size of such heat transfer systems (radiators) and lead to increased energy and fuel efficiency, lower pollution and improved reliability.

  20. Waveguides with Absorbing Boundaries: Nonlinearity Controlled by an Exceptional Point and Solitons

    NASA Astrophysics Data System (ADS)

    Midya, Bikashkali; Konotop, Vladimir V.

    2017-07-01

    We reveal the existence of continuous families of guided single-mode solitons in planar waveguides with weakly nonlinear active core and absorbing boundaries. Stable propagation of TE and TM-polarized solitons is accompanied by attenuation of all other modes, i.e., the waveguide features properties of conservative and dissipative systems. If the linear spectrum of the waveguide possesses exceptional points, which occurs in the case of TM polarization, an originally focusing (defocusing) material nonlinearity may become effectively defocusing (focusing). This occurs due to the geometric phase of the carried eigenmode when the surface impedance encircles the exceptional point. In its turn, the change of the effective nonlinearity ensures the existence of dark (bright) solitons in spite of focusing (defocusing) Kerr nonlinearity of the core. The existence of an exceptional point can also result in anomalous enhancement of the effective nonlinearity. In terms of practical applications, the nonlinearity of the reported waveguide can be manipulated by controlling the properties of the absorbing cladding.

  1. Broadcasting a message in a parallel computer

    DOEpatents

    Archer, Charles J; Faraj, Ahmad A

    2013-04-16

    Methods, systems, and products are disclosed for broadcasting a message in a parallel computer that includes: transmitting, by the logical root to all of the nodes directly connected to the logical root, a message; and for each node except the logical root: receiving the message; if that node is the physical root, then transmitting the message to all of the child nodes except the child node from which the message was received; if that node received the message from a parent node and if that node is not a leaf node, then transmitting the message to all of the child nodes; and if that node received the message from a child node and if that node is not the physical root, then transmitting the message to all of the child nodes except the child node from which the message was received and transmitting the message to the parent node.

  2. Broadcasting a message in a parallel computer

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    None

    Methods, systems, and products are disclosed for broadcasting a message in a parallel computer that includes: transmitting, by the logical root to all of the nodes directly connected to the logical root, a message; and for each node except the logical root: receiving the message; if that node is the physical root, then transmitting the message to all of the child nodes except the child node from which the message was received; if that node received the message from a parent node and if that node is not a leaf node, then transmitting the message to all of the childmore » nodes; and if that node received the message from a child node and if that node is not the physical root, then transmitting the message to all of the child nodes except the child node from which the message was received and transmitting the message to the parent node.« less

  3. 41 CFR 101-8.307 - Employment criteria.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 2 2010-07-01 2010-07-01 true Employment criteria. 101-8.307 Section 101-8.307 Public Contracts and Property Management Federal Property Management... speaking skills except where those skills are the factors that the test purports to measure. ...

  4. 41 CFR 101-8.307 - Employment criteria.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 41 Public Contracts and Property Management 2 2011-07-01 2007-07-01 true Employment criteria. 101-8.307 Section 101-8.307 Public Contracts and Property Management Federal Property Management... speaking skills except where those skills are the factors that the test purports to measure. ...

  5. Patterns and determinants of wood physical and mechanical properties across major tree species in China.

    PubMed

    Zhu, JiangLing; Shi, Yue; Fang, LeQi; Liu, XingE; Ji, ChengJun

    2015-06-01

    The physical and mechanical properties of wood affect the growth and development of trees, and also act as the main criteria when determining wood usage. Our understanding on patterns and controls of wood physical and mechanical properties could provide benefits for forestry management and bases for wood application and forest tree breeding. However, current studies on wood properties mainly focus on wood density and ignore other wood physical properties. In this study, we established a comprehensive database of wood physical properties across major tree species in China. Based on this database, we explored spatial patterns and driving factors of wood properties across major tree species in China. Our results showed that (i) compared with wood density, air-dried density, tangential shrinkage coefficient and resilience provide more accuracy and higher explanation power when used as the evaluation index of wood physical properties. (ii) Among life form, climatic and edaphic variables, life form is the dominant factor shaping spatial patterns of wood physical properties, climatic factors the next, and edaphic factors have the least effects, suggesting that the effects of climatic factors on spatial variations of wood properties are indirectly induced by their effects on species distribution.

  6. Power-law scaling of extreme dynamics near higher-order exceptional points

    NASA Astrophysics Data System (ADS)

    Zhong, Q.; Christodoulides, D. N.; Khajavikhan, M.; Makris, K. G.; El-Ganainy, R.

    2018-02-01

    We investigate the extreme dynamics of non-Hermitian systems near higher-order exceptional points in photonic networks constructed using the bosonic algebra method. We show that strong power oscillations for certain initial conditions can occur as a result of the peculiar eigenspace geometry and its dimensionality collapse near these singularities. By using complementary numerical and analytical approaches, we show that, in the parity-time (PT ) phase near exceptional points, the logarithm of the maximum optical power amplification scales linearly with the order of the exceptional point. We focus in our discussion on photonic systems, but we note that our results apply to other physical systems as well.

  7. 42 CFR 485.58 - Condition of participation: Comprehensive rehabilitation program.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... rehabilitation program that includes, at a minimum, physicians' services, physical therapy services, and social or psychological services. These services must be furnished by personnel that meet the qualifications... the services on its premises. (2) Exceptions. Physical therapy, occupational therapy, and speech...

  8. Physical Education Programming for Exceptional Learners.

    ERIC Educational Resources Information Center

    Folio, M. Rhonda

    This book provides programming ideas, methods, strategies, and adaptations of the learning environment for implementing physical education programs for handicapped students. Part I, "Legislation and the Challenge," introduces Public Law 94-142, the Education for All Handicapped Children Act, its mandates, and its procedures for…

  9. 22 CFR 34.3 - Exceptions.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... DEPARTMENT OF STATE CLAIMS AND STOLEN PROPERTY DEBT COLLECTION General Provisions § 34.3 Exceptions. (a) Debts arising from the audit of transportation accounts pursuant to 31 U.S.C. 3726 shall be determined... 102-118. (b) Debts arising out of acquisition contracts subject to the Federal Acquisition Regulation...

  10. 41 CFR 101-8.706 - Exceptions to the rules against age discrimination.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... against age discrimination. 101-8.706 Section 101-8.706 Public Contracts and Property Management Federal... IN PROGRAMS RECEIVING FEDERAL FINANCIAL ASSISTANCE 8.7-Discrimination Prohibited on the Basis of Age § 101-8.706 Exceptions to the rules against age discrimination. ...

  11. 41 CFR 101-8.706 - Exceptions to the rules against age discrimination.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... against age discrimination. 101-8.706 Section 101-8.706 Public Contracts and Property Management Federal... IN PROGRAMS RECEIVING FEDERAL FINANCIAL ASSISTANCE 8.7-Discrimination Prohibited on the Basis of Age § 101-8.706 Exceptions to the rules against age discrimination. ...

  12. 41 CFR 101-8.706 - Exceptions to the rules against age discrimination.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... against age discrimination. 101-8.706 Section 101-8.706 Public Contracts and Property Management Federal... IN PROGRAMS RECEIVING FEDERAL FINANCIAL ASSISTANCE 8.7-Discrimination Prohibited on the Basis of Age § 101-8.706 Exceptions to the rules against age discrimination. ...

  13. 41 CFR 101-8.706 - Exceptions to the rules against age discrimination.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... against age discrimination. 101-8.706 Section 101-8.706 Public Contracts and Property Management Federal... IN PROGRAMS RECEIVING FEDERAL FINANCIAL ASSISTANCE 8.7-Discrimination Prohibited on the Basis of Age § 101-8.706 Exceptions to the rules against age discrimination. ...

  14. 41 CFR 101-8.706 - Exceptions to the rules against age discrimination.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... against age discrimination. 101-8.706 Section 101-8.706 Public Contracts and Property Management Federal... IN PROGRAMS RECEIVING FEDERAL FINANCIAL ASSISTANCE 8.7-Discrimination Prohibited on the Basis of Age § 101-8.706 Exceptions to the rules against age discrimination. ...

  15. An evaluation of the interfacial bond properties between carbon phenolic and glass phenolic composites

    NASA Technical Reports Server (NTRS)

    Jordan, Kelvin; Clinton, Raymond; Jeelani, Shaik

    1989-01-01

    The effects of moisture and surface finish on the mechanical and physical properties of the interfacial bond between the carbon/phenolic (C/P) and glass/phenolic (G/P) composite materials are presented. Four flat panel laminates were fabricated using the C/P and G/P materials. Of the four laminates, one panel was fabricated in which the C/P and G/P materials were cured simultaneously. It was identified as the cocure. The remaining laminates were processed with an initial simultaneous cure of the three C/P billets. Two surface finishes, one on each half, were applied to the top surface. Prior to the application and cure of the G/P material to the machined surface of the three C/P panels, each was subjected to the specific environmental conditioning. Types of conditioning included: (1) nominal fabrication environment, (2) a prescribed drying cycle, and (3) a total immersion in water at 160 F. Physical property tests were performed on specimens removed from the C/P materials of each laminate for determination of the specific gravity, residual volatiles and and resin content. Comparisons of results with shuttle solid rocket motor (SRM) nozzle material specifications verified that the materials used in fabricating the laminates met acceptance criteria and were representative of SRM nozzle materials. Mechanical property tests were performed at room temperature on specimens removed from the G/P, the C/P and the interface between the two materials for each laminate. The double-notched shear strength test was used to determine the ultimate interlaminar shear strength. Results indicate no appreciable difference in the C/P material of the four laminates with the exception of the cocure laminate, where 20 percent reduction in the strength was observed. The most significant effect and the ultimate strength was significantly reduced in the wet material. No appreciable variation was noted between the surface finishes in the wet laminate.

  16. Effect of Toothpaste Application Prior to Dental Bleaching on Whitening Effectiveness and Enamel Properties.

    PubMed

    Vieira-Junior, W F; Lima, D A N L; Tabchoury, C P M; Ambrosano, G M B; Aguiar, F H B; Lovadino, J R

    2016-01-01

    The purpose of this study was to investigate the effects on the enamel properties and effectiveness of bleaching using 35% hydrogen peroxide (HP) when applying toothpastes with different active agents prior to dental bleaching. Seventy enamel blocks (4 × 4 × 2 mm) were submitted to in vitro treatment protocols in a tooth-brushing machine (n=10): with distilled water and exposure to placebo gel (negative control [NC]) or HP bleaching (positive control [PC]); and brushing with differing toothpastes prior to HP bleaching, including potassium nitrate toothpaste (PN) containing NaF, conventional sodium monofluorophosphate toothpaste (FT), arginine-based toothpastes (PA and SAN), or a toothpaste containing bioactive glass (NM). Color changes were determined using the CIE L*a*b* system (ΔE, ΔL, Δa, and Δb), and a roughness (Ra) analysis was performed before and after treatments. Surface microhardness (SMH) and cross-sectional microhardness (CSMH) were analyzed after treatment. Data were analyzed with repeated measures ANOVA for Ra, one-way ANOVA (SMH, ΔE, ΔL, Δa, and Δb), split-plot ANOVA (CSMH), and Tukey post hoc test (α<0.05). The relationship between the physical surface properties and color properties was evaluated using a multivariate Canonical correlation analysis. Color changes were statistically similar in the bleached groups. After treatments, SMH and CSMH decreased in PC. SMH increased significantly in the toothpaste groups vs the negative and positive control (NM > PA = SAN > all other groups) or decreased HP effects (CSMH). Ra increased in all bleached groups, with the exception of NM, which did not differ from the NC. The variation in the color variables (ΔL, Δa, and Δb) explained 21% of the variation in the physical surface variables (Ra and SMH). The application of toothpaste prior to dental bleaching did not interfere with the effectiveness of treatment. The bioactive glass based toothpaste protected the enamel against the deleterious effects of dental bleaching.

  17. Effect of hydroprocessing severity on characteristics of jet fuel from OSCO 2 and Paraho distillates

    NASA Technical Reports Server (NTRS)

    Prok, G. M.; Flores, F. J.; Seng, G. T.

    1981-01-01

    Jet A boiling range fuels and broad-property research fuels were produced by hydroprocessing shale oil distillates, and their properties were measured to characterize the fuels. The distillates were the fraction of whole shale oil boiling below 343 C from TOSCO 2 and Paraho syncrudes. The TOSCO 2 was hydroprocessed at medium severity, and the Paraho was hydroprocessed at high, medium, and low severities. Fuels meeting Jet A requirements except for the freezing point were produced from the medium severity TOSCO 2 and the high severity Paraho. Target properties of a broad property research fuel were met by the medium severity TOSCO 2 and the high severity Paraho except for the freezing point and a high hydrogen content. Medium and low severity Paraho jet fuels did not meet thermal stability and freezing point requirements.

  18. Changes in the Qualifications of Medical School Applicants, 1981 to 1985.

    ERIC Educational Resources Information Center

    Beran, Robert L.

    1987-01-01

    Changes were analyzed using both Medical College Admission Test (MCAT) scores and grade point average. Modest gains were shown: in the men and women applicants' scores on the MCAT biology, chemistry, physics, and science problems subtests; in all age categories except over 32; and for all ethnic or racial groups except blacks. (Author/LB)

  19. How One Exceptional Teacher Navigated Her Working Environment as the Teacher of a Marginal Subject

    ERIC Educational Resources Information Center

    Lux, Karen; McCullick, Bryan A.

    2011-01-01

    The purpose of this study was to analyze how one exceptional elementary physical education teacher navigated her working environment as the teacher of a marginal subject. Structuration Theory (Giddens, 1984) was used to make meaning of how the teacher functioned within her school community allowing her to remain motivated and effective. Data…

  20. Characteristics of Difficult-to-Place Youth in State Custody: A Profile of the Exceptional Care Pilot Project Population

    ERIC Educational Resources Information Center

    Armour, Marilyn P.; Schwab, James

    2007-01-01

    This study examines the characteristics of Texas youth designated as "most difficult to place" recipients of service under the "Exceptional Care Pilot Project" (N = 46). Findings include, among others, high levels of comorbid psychiatric disturbance (greater than 3 diagnostic groupings), physical (78.3%) and sexual (88%)…

  1. Layer and doping tunable ferromagnetic order in two-dimensional Cr S2 layers

    NASA Astrophysics Data System (ADS)

    Wang, Cong; Zhou, Xieyu; Pan, Yuhao; Qiao, Jingsi; Kong, Xianghua; Kaun, Chao-Cheng; Ji, Wei

    2018-06-01

    Interlayer coupling is of vital importance for manipulating physical properties, e.g., electronic band gap, in two-dimensional materials. However, tuning magnetic properties in these materials is yet to be addressed. Here, we found the in-plane magnetic orders of Cr S2 mono and few layers are tunable between striped antiferromagnetic (sAFM) and ferromagnetic (FM) orders by manipulating charge transfer between Cr t2 g and eg orbitals. Such charge transfer is realizable through interlayer coupling, direct charge doping, or substituting S with Cl atoms. In particular, the transferred charge effectively reduces a portion of Cr4 + to Cr3 +, which, together with delocalized S p orbitals and their resulting direct S-S interlayer hopping, enhances the double-exchange mechanism favoring the FM rather than sAFM order. An exceptional interlayer spin-exchange parameter was revealed over -10 meV , an order of magnitude stronger than available results of interlayer magnetic coupling. It addition, the charge doping could tune Cr S2 between p - and n -doped magnetic semiconductors. Given these results, several prototype devices were proposed for manipulating magnetic orders using external electric fields or mechanical motion. These results manifest the role of interlayer coupling in modifying magnetic properties of layered materials and shed considerable light on manipulating magnetism in these materials.

  2. Manipulation of the Geometry and Modulation of the Optical Response of Surfactant-Free Gold Nanostars: A Systematic Bottom-Up Synthesis

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    De Silva Indrasekara, Agampodi S.; Johnson, Sean F.; Odion, Ren A.

    Among plasmonic nanoparticles, surfactant-free branched gold nanoparticles have exhibited exceptional properties as a nanoplatform for a wide variety of applications ranging from surface-enhanced Raman scattering sensing and imaging applications to photothermal treatment and photoimmunotherapy for cancer treatments. The effectiveness and reliability of branched gold nanoparticles in biomedical applications strongly rely on the consistency and reproducibility of physical, chemical, optical, and therapeutic properties of nanoparticles, which are mainly governed by their morphological features. Herein, we present an optimized bottom-up synthesis that improves the reproducibility and homogeneity of the gold-branched nanoparticles with desired morphological features and optical properties. We identified that themore » order of reagent addition is crucial for improved homogeneity of the branched nature of nanoparticles that enable a high batch-to-batch reproducibility and reliability. In addition, a different combination of the synthesis parameters, in particular, additive halides and concentration ratios of reactive Au to Ag and Au to Au seeds, which yield branched nanoparticle of similar localized surface plasmon resonances but with distinguishable changes in the dimensions of the branches, was realized. Overall, our study introduces the design parameters for the purpose-tailored manufacturing of surfactant-free gold nanostars in a reliable manner.« less

  3. Manipulation of the Geometry and Modulation of the Optical Response of Surfactant-Free Gold Nanostars: A Systematic Bottom-Up Synthesis

    DOE PAGES

    De Silva Indrasekara, Agampodi S.; Johnson, Sean F.; Odion, Ren A.; ...

    2018-02-22

    Among plasmonic nanoparticles, surfactant-free branched gold nanoparticles have exhibited exceptional properties as a nanoplatform for a wide variety of applications ranging from surface-enhanced Raman scattering sensing and imaging applications to photothermal treatment and photoimmunotherapy for cancer treatments. The effectiveness and reliability of branched gold nanoparticles in biomedical applications strongly rely on the consistency and reproducibility of physical, chemical, optical, and therapeutic properties of nanoparticles, which are mainly governed by their morphological features. Herein, we present an optimized bottom-up synthesis that improves the reproducibility and homogeneity of the gold-branched nanoparticles with desired morphological features and optical properties. We identified that themore » order of reagent addition is crucial for improved homogeneity of the branched nature of nanoparticles that enable a high batch-to-batch reproducibility and reliability. In addition, a different combination of the synthesis parameters, in particular, additive halides and concentration ratios of reactive Au to Ag and Au to Au seeds, which yield branched nanoparticle of similar localized surface plasmon resonances but with distinguishable changes in the dimensions of the branches, was realized. Overall, our study introduces the design parameters for the purpose-tailored manufacturing of surfactant-free gold nanostars in a reliable manner.« less

  4. Development and characterization of biodegradable chitosan films containing two essential oils.

    PubMed

    Shen, Zhu; Kamdem, Donatien Pascal

    2015-03-01

    Active biodegradable films from chitosan containing 10% to 30% w/w of citronella essential oil (CEO) and cedarwood oil (CWO) were developed by casting and solvent-evaporation method, and their physical, mechanical and thermal properties were investigated. Possible interactions between the chitosan chains and the essential oils were confirmed using Fourier-transform infrared spectroscopy (FTIR). Various amounts of CEO or CWO had significant effects on the films' mechanical properties, with the exception of 10% of CEO, which did not significantly affect the tensile strength of the films. The incorporation of the two tested oils provoked a remarkable reduction in the water-vapor permeability properties, with a decrease of about 63% when 30% CEO was added in chitosan films. Thermogravimetric analysis showed that degradation temperatures of the films containing CEO and CWO improved only slightly in comparison to control films without essential oils. FTIR spectra analysis provided some insights on the possible interactions between chitosan and the two essential oils used. This study suggests that active films can be developed by including CEO and CWO in a chitosan matrix. Such films can provide new formulation options for packaging industries in developing active packaging with potential food-technology applications. Copyright © 2014 Elsevier B.V. All rights reserved.

  5. Luminosity Dependence and Search Doppler

    NASA Technical Reports Server (NTRS)

    VanParadijs, Johannes A.

    1998-01-01

    The research supported by this grant covered two projects: (1) a study of the luminosity dependence of the properties of atoll sources; and (2) a search for Doppler shifts in the pulse arrival times of the anomalous pulsar 4U 0142+61. Following the discovery of kilohertz quasi-periodic oscillations (QPOS) in Sco X-1 studies of the X-ray properties of atoll sources have been dominated by searches for these QPOS, and the study of their dependence on other source properties, such as X-ray luminosity and spectral state. In the project supported by grant NAG5-3269 we have detected kHz QPOs for several atoll sources. The physical interpretation of these QPO is as yet unclear, but simple models (such as the Keplerian beat frequency model) can probably be excluded. The results of this research have been reported. We have studied the X-ray pulsations of the anomalous X-ray pulsar 4U 0142+61 using the Rossi XTE. A detailed search for Doppler shifts did not lead to a positive detection. The upper limits exclude almost all types of possible companion stars, except white dwarfs. However, the latter can be excluded since anomalous X-ray pulsars are very young objects. We therefore conclude that anomalous X-ray pulsars are single neutron stars.

  6. Complement-fixing Activity of Fulvic Acid from Shilajit and Other Natural Sources

    PubMed Central

    Schepetkin, Igor A.; Xie, Gang; Jutila, Mark A.; Quinn, Mark T.

    2008-01-01

    Shilajit has been used traditionally in folk medicine for treatment of a variety of disorders, including syndromes involving excessive complement activation. Extracts of Shilajit contain significant amounts of fulvic acid (FA), and it has been suggested that FA is responsible for many therapeutic properties of Shilajit. However, little is known regarding physical and chemical properties of Shilajit extracts, and nothing is known about their effects on the complement system. To address this issue, we fractionated extracts of commercial Shilajit using anion exchange and size-exclusion chromatography. One neutral (S-I) and two acidic (S-II and S-III) fractions were isolated, characterized, and compared with standardized FA samples. The most abundant fraction (S-II) was further fractionated into three sub-fractions (S-II-1 to S-II-3). The van Krevelen diagram showed that the Shilajit fractions are products of polysaccharide degradation, and all fractions, except S-II-3, contained type II arabinogalactan. All Shilajit fractions exhibited dose-dependent complement-fixing activity in vitro with high potency. Furthermore, we found a strong correlation between complement-fixing activity and carboxylic group content in the Shilajit fractions and other FA sources. These data provide a molecular basis to explain at least part of the beneficial therapeutic properties of Shilajit and other humic extracts. PMID:19107845

  7. Physical properties of forest soils

    Treesearch

    Charles H. Perry; Michael C. Amacher

    2007-01-01

    Why Are Physical Properties of the Soil Important? The soil quality indicator, when combined with other data collected by the FIA program, can indicate the current rates of soil erosion, the extent and intensity of soil compaction, and some basic physical properties of the forest floor and the top 20 cm of soil. In this report, two particular physical properties of the...

  8. Work characteristics predict the development of multi-site musculoskeletal pain.

    PubMed

    Oakman, Jodi; de Wind, Astrid; van den Heuvel, Swenne G; van der Beek, Allard J

    2017-10-01

    Musculoskeletal pain in more than one body region is common and a barrier to sustaining employment. We aimed to examine whether work characteristics predict the development of multi-site pain (MSP), and to determine differences in work-related predictors between age groups. This study is based on 5136 employees from the Study on Transitions in Employment, Ability and Motivation (STREAM) who reported no MSP at baseline. Measures included physical, emotional, mental, and psychological job demands, social support and autonomy. Predictors of MSP were studied by logistic regression analyses. Univariate and multivariate analyses with age stratification (45-49, 50-54, 55-59, and 60-64 years) were done to explore differences between age groups. All work characteristics with the exception of autonomy were predictive of the development of MSP, with odds ratios varying from 1.21 (95% CI 1.04-1.40) for mental job demands to 1.63 (95% CI 1.43-1.86) for physical job demands. No clear pattern of age-related differences in the predictors of MSP emerged, with the exception of social support, which was predictive of MSP developing in all age groups except for the age group 60-64 years. Adverse physical and psychosocial work characteristics are associated with MSP. Organisations need to comprehensively assess work environments to ensure that all relevant workplace hazards, physical and psychosocial, are identified and then controlled for across all age groups.

  9. 31 CFR 598.203 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 31 Money and Finance:Treasury 3 2014-07-01 2014-07-01 false Prohibited transactions involving blocked property. 598.203 Section 598.203 Money and Finance: Treasury Regulations Relating to Money and... SANCTIONS REGULATIONS Prohibitions § 598.203 Prohibited transactions involving blocked property. (a) Except...

  10. 31 CFR 598.203 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 31 Money and Finance: Treasury 3 2010-07-01 2010-07-01 false Prohibited transactions involving blocked property. 598.203 Section 598.203 Money and Finance: Treasury Regulations Relating to Money and... SANCTIONS REGULATIONS Prohibitions § 598.203 Prohibited transactions involving blocked property. (a) Except...

  11. 31 CFR 598.203 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 31 Money and Finance:Treasury 3 2013-07-01 2013-07-01 false Prohibited transactions involving blocked property. 598.203 Section 598.203 Money and Finance: Treasury Regulations Relating to Money and... SANCTIONS REGULATIONS Prohibitions § 598.203 Prohibited transactions involving blocked property. (a) Except...

  12. 31 CFR 598.203 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 31 Money and Finance:Treasury 3 2011-07-01 2011-07-01 false Prohibited transactions involving blocked property. 598.203 Section 598.203 Money and Finance: Treasury Regulations Relating to Money and... SANCTIONS REGULATIONS Prohibitions § 598.203 Prohibited transactions involving blocked property. (a) Except...

  13. 31 CFR 598.203 - Prohibited transactions involving blocked property.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 31 Money and Finance:Treasury 3 2012-07-01 2012-07-01 false Prohibited transactions involving blocked property. 598.203 Section 598.203 Money and Finance: Treasury Regulations Relating to Money and... SANCTIONS REGULATIONS Prohibitions § 598.203 Prohibited transactions involving blocked property. (a) Except...

  14. 7 CFR 1955.148 - Auction sales.

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... 7 Agriculture 14 2014-01-01 2014-01-01 false Auction sales. 1955.148 Section 1955.148 Agriculture... REGULATIONS (CONTINUED) PROPERTY MANAGEMENT Disposal of Inventory Property General § 1955.148 Auction sales. This section provides guidance on the sale of all inventory property by auction, except FSA real...

  15. 7 CFR 1955.148 - Auction sales.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... 7 Agriculture 14 2011-01-01 2011-01-01 false Auction sales. 1955.148 Section 1955.148 Agriculture... REGULATIONS (CONTINUED) PROPERTY MANAGEMENT Disposal of Inventory Property General § 1955.148 Auction sales. This section provides guidance on the sale of all inventory property by auction, except FSA real...

  16. 7 CFR 1955.148 - Auction sales.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... 7 Agriculture 14 2012-01-01 2012-01-01 false Auction sales. 1955.148 Section 1955.148 Agriculture... REGULATIONS (CONTINUED) PROPERTY MANAGEMENT Disposal of Inventory Property General § 1955.148 Auction sales. This section provides guidance on the sale of all inventory property by auction, except FSA real...

  17. 7 CFR 1955.148 - Auction sales.

    Code of Federal Regulations, 2013 CFR

    2013-01-01

    ... 7 Agriculture 14 2013-01-01 2013-01-01 false Auction sales. 1955.148 Section 1955.148 Agriculture... REGULATIONS (CONTINUED) PROPERTY MANAGEMENT Disposal of Inventory Property General § 1955.148 Auction sales. This section provides guidance on the sale of all inventory property by auction, except FSA real...

  18. 41 CFR 102-39.60 - What restrictions and prohibitions apply to the exchange/sale of personal property?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... code of scrap, as defined at FMR 102-36.40, except: (1) Property that had utility and value at the... disaster); or (3) Scrap gold for fine gold. (f) Property that was originally acquired as excess or...

  19. 41 CFR 102-39.60 - What restrictions and prohibitions apply to the exchange/sale of personal property?

    Code of Federal Regulations, 2014 CFR

    2014-01-01

    ... code of scrap, as defined at FMR 102-36.40, except: (1) Property that had utility and value at the... disaster); or (3) Scrap gold for fine gold. (f) Property that was originally acquired as excess or...

  20. 41 CFR 102-39.60 - What restrictions and prohibitions apply to the exchange/sale of personal property?

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... code of scrap, as defined at FMR 102-36.40, except: (1) Property that had utility and value at the... disaster); or (3) Scrap gold for fine gold. (f) Property that was originally acquired as excess or...

  1. 32 CFR 228.10 - Prohibition on alcohol.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...) MISCELLANEOUS SECURITY PROTECTIVE FORCE § 228.10 Prohibition on alcohol. Entering or being on protected property... on protected property by a person under the influence of alcoholic beverages is prohibited. The use of alcoholic beverages on protected property is also prohibited, except on occasions and on protected...

  2. 32 CFR 228.10 - Prohibition on alcohol.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) MISCELLANEOUS SECURITY PROTECTIVE FORCE § 228.10 Prohibition on alcohol. Entering or being on protected property... on protected property by a person under the influence of alcoholic beverages is prohibited. The use of alcoholic beverages on protected property is also prohibited, except on occasions and on protected...

  3. 32 CFR 228.10 - Prohibition on alcohol.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) MISCELLANEOUS SECURITY PROTECTIVE FORCE § 228.10 Prohibition on alcohol. Entering or being on protected property... on protected property by a person under the influence of alcoholic beverages is prohibited. The use of alcoholic beverages on protected property is also prohibited, except on occasions and on protected...

  4. 32 CFR 228.10 - Prohibition on alcohol.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...) MISCELLANEOUS SECURITY PROTECTIVE FORCE § 228.10 Prohibition on alcohol. Entering or being on protected property... on protected property by a person under the influence of alcoholic beverages is prohibited. The use of alcoholic beverages on protected property is also prohibited, except on occasions and on protected...

  5. Association of Family History of Exceptional Longevity With Decline in Physical Function in Aging.

    PubMed

    Ayers, Emmeline; Barzilai, Nir; Crandall, Jill P; Milman, Sofiya; Verghese, Joe

    2017-11-09

    Although many genetic and nongenetic factors interact to determine an individual's physical phenotype, there has been limited examination of the contribution of family history of exceptional parental longevity on decline in physical function in aging. The LonGenity study recruited a relatively genetically homogenous cohort of Ashkenazi Jewish adults age 65 and older, who were defined as either offspring of parents with exceptional longevity ([OPEL]: having at least one parent who lived to age 95 or older) or offspring of parents with usual survival ([OPUS]: neither parent survived to age 95). Decline in performance on objective measures of strength (grip strength), balance (unipedal stance), and mobility (gait speed) as well as a composite physical function measure, the Short physical performance battery (SPPB), were compared between the two groups over a median follow-up of 3.2 years, accounting for age, sex, education, and comorbidities. Of the 984 LonGenity participants (mean age 76, 55% women), 448 were OPEL and 536 were OPUS. Compared to OPUS, OPEL had slower decline on measures of unipedal stance (-0.03 log-units/year, p = .026), repeated chair rise (0.13 s/year, p = .020) and SPPB (-0.11 points/year, p = .002). OPEL women had slower decline on chair rise and SPPB scores compared to OPUS women, although OPEL men had slower decline on unipedal stance compared to OPUS men. Our findings provide evidence that variation in late-life decline in physical function is associated with familial longevity, and may vary for men and women. © The Author 2017. Published by Oxford University Press on behalf of The Gerontological Society of America. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  6. 26 CFR 301.7505-1 - Sale of personal property acquired by the United States.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... 26 Internal Revenue 18 2010-04-01 2010-04-01 false Sale of personal property acquired by the... Actions by the United States § 301.7505-1 Sale of personal property acquired by the United States. (a) Sale—(1) In general. Any personal property (except bonds, notes, checks, and other securities) acquired...

  7. 26 CFR 301.7505-1 - Sale of personal property acquired by the United States.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... 26 Internal Revenue 18 2011-04-01 2011-04-01 false Sale of personal property acquired by the... Actions by the United States § 301.7505-1 Sale of personal property acquired by the United States. (a) Sale—(1) In general. Any personal property (except bonds, notes, checks, and other securities) acquired...

  8. A Comprehensive Study of Chelyabinsk Meteorite: Physical, Mineralogical, Spectral Properties and Solar System Orbit

    NASA Astrophysics Data System (ADS)

    Gritsevich, Maria; Kohout, T.; Grokhovsky, V.; Yakovlev, G.; Lyytinen, E.; Vinnikov, V.; Haloda, J.; Halodova, P.; Michallik, R.; Penttilä, A.; Muinonen, K.; Peltoniemi, J.; Lupovka, V.; Dmitriev, V.

    2013-10-01

    On February 15, 2013, at 9:22 am, an exceptionally bright and long duration fireball was observed by many eyewitnesses in the Chelyabinsk region, Russia. A strong shock wave associated with the fireball caused significant damage such as destroyed windows and parts of buildings in Chelyabinsk and the surrounding territories. A number of video records of the event are available and have been used to reconstruct atmospheric trajectory, velocity, deceleration rate, and parent asteroid Apollo-type orbit in the Solar System. Two types of meteorite material are present among recovered fragments of the Chelyabinsk meteorite. These are described as the light-colored and dark-colored lithology. Both types are of LL5 composition with the dark-colored one being an impact-melt shocked to a higher level. Based on the magnetic susceptibility measurements, the Chelyabinsk meteorite is richer in metallic iron as compared to other LL chondrites. The measured bulk and grain densities and the porosity closely resemble other LL chondrites. Shock darkening does not have a significant effect on the material physical properties, but causes a decrease of reflectance and decrease in silicate absorption bands in the reflectance spectra. This is similar to the space weathering effects observed on asteroids. However, no spectral slope change similar to space weathering is observed as a result of shock-darkening. Thus, it is possible that some dark asteroids with invisible silicate absorption bands may be composed of relatively fresh shock darkened chondritic material.

  9. Effect of incorporation of a new antimicrobial nanomaterial on the physical-chemical properties of endodontic sealers

    PubMed Central

    Vilela Teixeira, Ana Beatriz; Vidal, Carla Larissa; de Castro, Denise Tornavoi; da Costa Valente, Mariana Lima; Oliveira-Santos, Christiano; Alves, Oswaldo Luis; dos Reis, Andréa Cândido

    2017-01-01

    Objectives: The objective of the study is to incorporate the nanostructured silver vanadate (AgVO3) decorated with silver nanoparticles at endodontic sealers AH Plus, Sealapex, Sealer 26, and Endofill, at concentrations of 2.5%, 5%, and 10%, and to evaluate physical-chemical properties. Materials and Methods: The study was to evaluate the radiopacity using digital radiography (n = 5), the tooth color change in 48 incisors (n = 3) for 7, 30, 90, and 180 days in a spectrophotometer, and the topographic distribution in a confocal laser (n = 5). The radiopacity was analyzed by Kruskal–Wallis test and the permutation (α = 0.05) and the color and topographical distribution by descriptive statistical analysis. Results: The AgVO3 had no effect on the radiopacity of Endofill and Sealapex (P > 0.05) and at 2.5% concentrations increased the radiopacity of Sealer 26 and AH Plus (P < 0.05). The Endofill 10% showed less color change, and the major changes were the modified groups in 180 days. The AgVO3 showed a circular topographic distribution in areas of the sealers. Conclusion: It was found that the addition of AgVO3 did not affect the radiopacity of Endofill and Sealapex however, increased the radipacity of Sealer 26 and AH Plus. For modified groups, the greatest color change was promoted after 180 days, except for Endofill with 10%. Topographic distribution of nanomaterial affected the color change of theevaluated sealers. PMID:29430089

  10. Huge photoresistance in transparent and conductive indium titanium oxide films prepared by electron beam-physical vapor deposition.

    PubMed

    Martínez-Morillas, Rocío; Ramírez, Rafael; Sánchez-Marcos, Jorge; Fonda, Emiliano; de Andrés, Alicia; Prieto, Carlos

    2014-02-12

    Transparent and conductive indium titanium oxide (ITiO) films have been obtained by electron beam physical vapour deposition with Ti content from 5 at % up to 28 at %. X-ray absorption spectroscopy techniques have been used to identify the local environment of Ti ions. Even at the lowest concentrations Ti is not incorporated into the In2O3 structure but forms clusters of a Ti-In mixed oxide that present a distorted rutile TiO2 short-range order. The optical transmittance of the annealed samples reaches 95 % and no significant variation of the gap energy (around 3.7 eV) is observed with Ti content. The electronic conductivity under light irradiation is studied evidencing a huge photo-resistance in the samples with Ti content above 22 at % reaching more than two orders of magnitude for the 26 at % Ti under illumination with few μW/cm(2) at 365 nm. Hall and conductivity results are analyzed using a model that takes into account both electron and hole carriers as well as the conductivity enhancement by carrier photogeneration. The electron carrier density decreases with Ti content while its mobility increases up to values of 1000 cm(2)/(V s). Oxygen annealed ITiO films obtained by this technique with Ti content below 10 at % have properties adequate as transparent semiconductors and those with Ti content higher than 22 at % have exceptional photoresistive properties relevant for numerous applications.

  11. The Impact Of Galactic Environment On Star Formation

    NASA Astrophysics Data System (ADS)

    Kreckel, Kathryn

    2016-09-01

    While spiral arms are the most prominent sites for star formation in disk galaxies, interarm star formation contributes significantly to the overall star formation budget. However, it is still an open question if the star formation proceeds differently in the arm and inter-arm environment. We use deep VLT/MUSE optical IFU spectroscopy to resolve and fully characterize the physical properties of 428 interarm and arm HII regions in the nearby grand design spiral galaxy NGC 628. Unlike molecular clouds (the fuel for star formation) which exhibit a clear dependence on galactic environment, we find that most HII region properties (luminosity, size, metallicity, ionization parameter) are independent of environment. One clear exception is the diffuse ionized gas (DIG) contribution to the arm and interarm flux (traced via the temperature sensitive [SII]/Halpha line ratio inside and outside of the HII region boundaries). We find a systematically higher DIG background within HII regions, particularly on the spiral arms. Correcting for this DIG contamination can result in significant (70%) changes to the star formation rate measured. We also show preliminary results comparing well@corrected star formation rates from our MUSE HII regions to ALMA CO(2-1) molecular gas observations at matched 1"=35pc resolution, tracing the Kennicutt-Schmidt star formation law at the scales relevant to the physics of star formation. We estimate the timescales relevant for GMC evolution using distance from the spiral arm as a proxy for age, and test whether star formation feedback or galactic@scale dynamical processes dominate GMC disruption.

  12. The impact of galactic environment on star formation

    NASA Astrophysics Data System (ADS)

    Kreckel, Kathryn; Blanc, Guillermo A.; Schinnerer, Eva; Groves, Brent; Adamo, Angela; Hughes, Annie; Meidt, Sharon; SFNG Collaboration

    2017-01-01

    While spiral arms are the most prominent sites for star formation in disk galaxies, interarm star formation contributes significantly to the overall star formation budget. However, it is still an open question if the star formation proceeds differently in the arm and inter-arm environment. We use deep VLT/MUSE optical IFU spectroscopy to resolve and fully characterize the physical properties of 428 interarm and arm HII regions in the nearby grand design spiral galaxy NGC 628. Unlike molecular clouds (the fuel for star formation) which exhibit a clear dependence on galactic environment, we find that most HII region properties (luminosity, size, metallicity, ionization parameter) are independent of environment. One clear exception is the diffuse ionized gas (DIG) contribution to the arm and interarm flux (traced via the temperature sensitive [SII]/Halpha line ratio inside and outside of the HII region boundaries). We find a systematically higher DIG background within HII regions, particularly on the spiral arms. Correcting for this DIG contamination can result in significant (70%) changes to the star formation rate measured. We also show preliminary results comparing well-corrected star formation rates from our MUSE HII regions to ALMA CO(2-1) molecular gas observations at matched 1"=50pc resolution, tracing the Kennicutt-Schmidt star formation law at the scales relevant to the physics of star formation. We estimate the timescales relevant for GMC evolution using distance from the spiral arm as a proxy for age, and test whether star formation feedback or galactic-scale dynamical processes dominate GMC disruption.

  13. Proton beam radiotherapy of uveal melanoma

    PubMed Central

    Damato, Bertil; Kacperek, Andrzej; Errington, Doug; Heimann, Heinrich

    2013-01-01

    Proton beam radiotherapy of uveal melanoma can be administered as primary treatment, as salvage therapy for recurrent tumor, and as neoadjuvant therapy prior to surgical resection. The physical properties of proton beams make it possible to deliver high-doses of radiation to the tumor with relative sparing of adjacent tissues. This form of therapy is effective for a wider range of uveal melanoma than any other modality, providing exceptionally-high rates of local tumor control. This is particularly the case with diffuse iris melanomas, many of which are unresectable. The chances of survival, ocular conservation, visual preservation and avoidance of iatrogenic morbidity depend greatly on the tumor size, location and extent. When treating any side-effects and/or complications, it is helpful to consider whether these are the result of collateral damage or persistence of the irradiated tumor (‘toxic tumor syndrome’). PMID:24227980

  14. Patterns of leisure time and non-leisure time physical activity of Korean immigrant women.

    PubMed

    Choi, Jiwon; Wilbur, Joellen; Kim, Mi Ja

    2011-02-01

    Our purpose in this study was to examine the patterns of physical activity and demographic characteristics associated with those patterns in Korean immigrants in the United States. Participants were 197 women, and the International Physical Activity Questionnaire was utilized. The inactive pattern was the most frequent pattern in all domains of physical activity except household physical activity. There were differences among the patterns of physical activity that were associated with variations in demographic characteristics. Health care providers who serve immigrants should assess physical activity level and demographic characteristics of the immigrants to enhance their physical activity.

  15. Physics in Movies: Awareness Levels of Teacher Candidates

    ERIC Educational Resources Information Center

    Kizilcik, Hasan Sahin; Damli, Volkan; Unsal, Yasin

    2014-01-01

    The aim of this study is to draw attention to the informal education aspect of the movies shown and to determine the awareness levels about physics in movies of a small group composed of university students. That is an evaluation had been made among the films dealing explicitly with the basic content of physics, except for science fiction movies,…

  16. 36 CFR 327.8 - Hunting, fishing, and trapping.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 36 Parks, Forests, and Public Property 3 2011-07-01 2011-07-01 false Hunting, fishing, and... THE CHIEF OF ENGINEERS § 327.8 Hunting, fishing, and trapping. (a) Hunting is permitted except in... areas and during periods where prohibited by the District Commander. (c) Fishing is permitted except in...

  17. 36 CFR 327.8 - Hunting, fishing, and trapping.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 36 Parks, Forests, and Public Property 3 2010-07-01 2010-07-01 false Hunting, fishing, and... THE CHIEF OF ENGINEERS § 327.8 Hunting, fishing, and trapping. (a) Hunting is permitted except in... areas and during periods where prohibited by the District Commander. (c) Fishing is permitted except in...

  18. 36 CFR 327.8 - Hunting, fishing, and trapping.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 36 Parks, Forests, and Public Property 3 2012-07-01 2012-07-01 false Hunting, fishing, and... THE CHIEF OF ENGINEERS § 327.8 Hunting, fishing, and trapping. (a) Hunting is permitted except in... areas and during periods where prohibited by the District Commander. (c) Fishing is permitted except in...

  19. 36 CFR 327.8 - Hunting, fishing, and trapping.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 36 Parks, Forests, and Public Property 3 2014-07-01 2014-07-01 false Hunting, fishing, and... THE CHIEF OF ENGINEERS § 327.8 Hunting, fishing, and trapping. (a) Hunting is permitted except in... areas and during periods where prohibited by the District Commander. (c) Fishing is permitted except in...

  20. 44 CFR 67.6 - Basis of appeal.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... absolute (except where mathematical or measurement error or changed physical conditions can be demonstrated... a mathematical or measurement error or changed physical conditions, then the specific source of the... registered professional engineer or licensed land surveyor, of the new data necessary for FEMA to conduct a...

  1. Microgravity

    NASA Image and Video Library

    1997-06-27

    This is a computer generated model of a ground based casting. The objective of the therophysical properties program is to measure thermal physical properties of commercial casting alloys for use in computer programs that predict soldification behavior. This could reduce trial and error in casting design and promote less scrap, sounder castings, and less weight. In order for the computer models to reliably simulate the details of industrial alloy solidification, the input thermophysical property data must be absolutely reliable. Recently Auburn University and TPRL Inc. formed a teaming relationship to establish reliable measurement techniques for the most critical properties of commercially important alloys: transformation temperatures, thermal conductivity, electrical conductivity, specific heat, latent heat, density, solid fraction evolution, surface tension, and viscosity. A new initiative with the American Foundrymens Society has been started to measure the thermophysical properties of commercial ferrous and non-ferrous casting alloys and make the thermophysical property data widely available. Development of casting processes for the new gamma titanium aluminide alloys as well as existing titanium alloys will remain a trial-and-error procedure until accurate thermophysical properties can be obtained. These molten alloys react with their containers on earth and change their composition - invalidating the measurements even while the data are being acquired in terrestrial laboratories. However, measurements on the molten alloys can be accomplished in space using freely floating droplets which are completely untouched by any container. These data are expected to be exceptionally precise because of the absence of impurity contamination and buoyancy convection effects. Although long duration orbital experiments will be required for the large scale industrial alloy measurement program that results from this research, short duration experiments on NASA's KC-135 low-g aircraft are already providing preliminary data and experience.

  2. 41 CFR 105-71.144 - Termination for convenience.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 3 2010-07-01 2010-07-01 false Termination for convenience. 105-71.144 Section 105-71.144 Public Contracts and Property Management Federal Property... Termination for convenience. Except as provided in § 105-71.143 awards may be terminated in whole or in part...

  3. 26 CFR 1.1250-3 - Exceptions and limitations.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... following examples: Example 1. (i) Green transfers section 1250 property on March 1, 1968, to a corporation... subparagraph may be illustrated by the following example: Example: (a) Green owns property consisting of land and a fully equipped factory building thereon. The property is condemned and proceeds of $100,000 are...

  4. 36 CFR 2.14 - Sanitation and refuse.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 36 Parks, Forests, and Public Property 1 2012-07-01 2012-07-01 false Sanitation and refuse. 2.14 Section 2.14 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR... washing food, clothing, dishes, or other property at public water outlets, fixtures or pools, except at...

  5. 36 CFR 2.14 - Sanitation and refuse.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 36 Parks, Forests, and Public Property 1 2013-07-01 2013-07-01 false Sanitation and refuse. 2.14 Section 2.14 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR... washing food, clothing, dishes, or other property at public water outlets, fixtures or pools, except at...

  6. 36 CFR 2.14 - Sanitation and refuse.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 36 Parks, Forests, and Public Property 1 2014-07-01 2014-07-01 false Sanitation and refuse. 2.14 Section 2.14 Parks, Forests, and Public Property NATIONAL PARK SERVICE, DEPARTMENT OF THE INTERIOR... washing food, clothing, dishes, or other property at public water outlets, fixtures or pools, except at...

  7. 20 CFR 416.1245 - Exceptions to required disposition of real property.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... property. 416.1245 Section 416.1245 Employees' Benefits SOCIAL SECURITY ADMINISTRATION SUPPLEMENTAL... geographic area covered by the media serving the area in which the property is located, unless the individual has good cause for not taking these steps. More specifically, making a reasonable effort to sell means...

  8. 20 CFR 416.1245 - Exceptions to required disposition of real property.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... property. 416.1245 Section 416.1245 Employees' Benefits SOCIAL SECURITY ADMINISTRATION SUPPLEMENTAL... geographic area covered by the media serving the area in which the property is located, unless the individual has good cause for not taking these steps. More specifically, making a reasonable effort to sell means...

  9. 20 CFR 416.1245 - Exceptions to required disposition of real property.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... property. 416.1245 Section 416.1245 Employees' Benefits SOCIAL SECURITY ADMINISTRATION SUPPLEMENTAL... geographic area covered by the media serving the area in which the property is located, unless the individual has good cause for not taking these steps. More specifically, making a reasonable effort to sell means...

  10. 20 CFR 416.1245 - Exceptions to required disposition of real property.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... property. 416.1245 Section 416.1245 Employees' Benefits SOCIAL SECURITY ADMINISTRATION SUPPLEMENTAL... geographic area covered by the media serving the area in which the property is located, unless the individual has good cause for not taking these steps. More specifically, making a reasonable effort to sell means...

  11. 20 CFR 416.1245 - Exceptions to required disposition of real property.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... property. 416.1245 Section 416.1245 Employees' Benefits SOCIAL SECURITY ADMINISTRATION SUPPLEMENTAL... geographic area covered by the media serving the area in which the property is located, unless the individual has good cause for not taking these steps. More specifically, making a reasonable effort to sell means...

  12. Multifunctional Nanostructured Conductive Polymer Gels: Synthesis, Properties, and Applications

    DOE PAGES

    Zhao, Fei; Shi, Ye; Pan, Lijia; ...

    2017-06-26

    Conductive polymers have attracted significant interest over the past few decades because they synergize the advantageous features of conventional polymeric materials and organic conductors. With rationally designed nanostructures, conductive polymers can further exhibit exceptional mechanical, electrical, and optical properties because of their confined dimensions at the nanoscale level. Among various nanostructured conductive polymers, conductive polymer gels (CPGs) with synthetically tunable hierarchical 3D network structures show great potential for a wide range of applications, such as bioelectronics, and energy storage/conversion devices owing to their structural features. CPGs retain the properties of nanosized conductive polymers during the assembly of the nanobuilding blocksmore » into a monolithic macroscopic structure while generating structure-derived features from the highly cross-linked network. In this Account, we review our recent progress on the synthesis, properties, and novel applications of dopant cross-linked CPGs. We first describe the synthetic strategies, in which molecules with multiple functional groups are adopted as cross-linkers to cross-link conductive polymer chains into a 3D molecular network. These cross-linking molecules also act as dopants to improve the electrical conductivity of the gel network. The microstructure and physical/chemical properties of CPGs can be tuned by controlling the synthetic conditions such as species of monomers and cross-linkers, reaction temperature, and solvents. By incorporating other functional polymers or particles into the CPG matrix, hybrid gels have been synthesized with tailored structures. These hybrid gel materials retain the functionalities from each component, as well as enable synergic effects to improve mechanical and electrical properties of CPGs. We then introduce the unique structure-derived properties of the CPGs. The network facilitates both electronic and ionic transport owing to the continuous pathways for electrons and hierarchical pores for ion diffusion. CPGs also provide high surface area and solvent compatibility, similar to natural gels. With these improved properties, CPGs have been explored to enable novel conceptual devices in diverse applications from smart electronics and ultrasensitive biosensors, to energy storage and conversion devices. CPGs have also been adopted for developing hybrid materials with multifunctionalities, such as stimuli responsiveness, self-healing properties, and super-repellency to liquid. With synthetically tunable physical/chemical properties, CPGs emerge as a unique material platform to develop novel multifunctional materials that have the potential to impact electronics, energy, and environmental technologies. Our hope is that this Account promotes further efforts toward synthetic control, fundamental investigation, and application exploration of CPGs.« less

  13. Multifunctional Nanostructured Conductive Polymer Gels: Synthesis, Properties, and Applications

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Zhao, Fei; Shi, Ye; Pan, Lijia

    Conductive polymers have attracted significant interest over the past few decades because they synergize the advantageous features of conventional polymeric materials and organic conductors. With rationally designed nanostructures, conductive polymers can further exhibit exceptional mechanical, electrical, and optical properties because of their confined dimensions at the nanoscale level. Among various nanostructured conductive polymers, conductive polymer gels (CPGs) with synthetically tunable hierarchical 3D network structures show great potential for a wide range of applications, such as bioelectronics, and energy storage/conversion devices owing to their structural features. CPGs retain the properties of nanosized conductive polymers during the assembly of the nanobuilding blocksmore » into a monolithic macroscopic structure while generating structure-derived features from the highly cross-linked network. In this Account, we review our recent progress on the synthesis, properties, and novel applications of dopant cross-linked CPGs. We first describe the synthetic strategies, in which molecules with multiple functional groups are adopted as cross-linkers to cross-link conductive polymer chains into a 3D molecular network. These cross-linking molecules also act as dopants to improve the electrical conductivity of the gel network. The microstructure and physical/chemical properties of CPGs can be tuned by controlling the synthetic conditions such as species of monomers and cross-linkers, reaction temperature, and solvents. By incorporating other functional polymers or particles into the CPG matrix, hybrid gels have been synthesized with tailored structures. These hybrid gel materials retain the functionalities from each component, as well as enable synergic effects to improve mechanical and electrical properties of CPGs. We then introduce the unique structure-derived properties of the CPGs. The network facilitates both electronic and ionic transport owing to the continuous pathways for electrons and hierarchical pores for ion diffusion. CPGs also provide high surface area and solvent compatibility, similar to natural gels. With these improved properties, CPGs have been explored to enable novel conceptual devices in diverse applications from smart electronics and ultrasensitive biosensors, to energy storage and conversion devices. CPGs have also been adopted for developing hybrid materials with multifunctionalities, such as stimuli responsiveness, self-healing properties, and super-repellency to liquid. With synthetically tunable physical/chemical properties, CPGs emerge as a unique material platform to develop novel multifunctional materials that have the potential to impact electronics, energy, and environmental technologies. Our hope is that this Account promotes further efforts toward synthetic control, fundamental investigation, and application exploration of CPGs.« less

  14. Multifunctional Nanostructured Conductive Polymer Gels: Synthesis, Properties, and Applications.

    PubMed

    Zhao, Fei; Shi, Ye; Pan, Lijia; Yu, Guihua

    2017-07-18

    Conductive polymers have attracted significant interest over the past few decades because they synergize the advantageous features of conventional polymeric materials and organic conductors. With rationally designed nanostructures, conductive polymers can further exhibit exceptional mechanical, electrical, and optical properties because of their confined dimensions at the nanoscale level. Among various nanostructured conductive polymers, conductive polymer gels (CPGs) with synthetically tunable hierarchical 3D network structures show great potential for a wide range of applications, such as bioelectronics, and energy storage/conversion devices owing to their structural features. CPGs retain the properties of nanosized conductive polymers during the assembly of the nanobuilding blocks into a monolithic macroscopic structure while generating structure-derived features from the highly cross-linked network. In this Account, we review our recent progress on the synthesis, properties, and novel applications of dopant cross-linked CPGs. We first describe the synthetic strategies, in which molecules with multiple functional groups are adopted as cross-linkers to cross-link conductive polymer chains into a 3D molecular network. These cross-linking molecules also act as dopants to improve the electrical conductivity of the gel network. The microstructure and physical/chemical properties of CPGs can be tuned by controlling the synthetic conditions such as species of monomers and cross-linkers, reaction temperature, and solvents. By incorporating other functional polymers or particles into the CPG matrix, hybrid gels have been synthesized with tailored structures. These hybrid gel materials retain the functionalities from each component, as well as enable synergic effects to improve mechanical and electrical properties of CPGs. We then introduce the unique structure-derived properties of the CPGs. The network facilitates both electronic and ionic transport owing to the continuous pathways for electrons and hierarchical pores for ion diffusion. CPGs also provide high surface area and solvent compatibility, similar to natural gels. With these improved properties, CPGs have been explored to enable novel conceptual devices in diverse applications from smart electronics and ultrasensitive biosensors, to energy storage and conversion devices. CPGs have also been adopted for developing hybrid materials with multifunctionalities, such as stimuli responsiveness, self-healing properties, and super-repellency to liquid. With synthetically tunable physical/chemical properties, CPGs emerge as a unique material platform to develop novel multifunctional materials that have the potential to impact electronics, energy, and environmental technologies. We hope that this Account promotes further efforts toward synthetic control, fundamental investigation, and application exploration of CPGs.

  15. 41 CFR 301-73.103 - What must we do when we approve an exception to the use of the E-Gov Travel Service?

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 41 Public Contracts and Property Management 4 2010-07-01 2010-07-01 false What must we do when we approve an exception to the use of the E-Gov Travel Service? 301-73.103 Section 301-73.103 Public... What must we do when we approve an exception to the use of the E-Gov Travel Service? The head of your...

  16. 41 CFR 301-73.103 - What must we do when we approve an exception to the use of the E-Gov Travel Service?

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 41 Public Contracts and Property Management 4 2012-07-01 2012-07-01 false What must we do when we approve an exception to the use of the E-Gov Travel Service? 301-73.103 Section 301-73.103 Public... What must we do when we approve an exception to the use of the E-Gov Travel Service? The head of your...

  17. 41 CFR 301-73.103 - What must we do when we approve an exception to the use of the E-Gov Travel Service?

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 41 Public Contracts and Property Management 4 2011-07-01 2011-07-01 false What must we do when we approve an exception to the use of the E-Gov Travel Service? 301-73.103 Section 301-73.103 Public... What must we do when we approve an exception to the use of the E-Gov Travel Service? The head of your...

  18. 41 CFR 301-73.103 - What must we do when we approve an exception to the use of the E-Gov Travel Service?

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 41 Public Contracts and Property Management 4 2013-07-01 2012-07-01 true What must we do when we approve an exception to the use of the E-Gov Travel Service? 301-73.103 Section 301-73.103 Public... What must we do when we approve an exception to the use of the E-Gov Travel Service? The head of your...

  19. 41 CFR 301-73.103 - What must we do when we approve an exception to the use of the E-Gov Travel Service?

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 41 Public Contracts and Property Management 4 2014-07-01 2014-07-01 false What must we do when we approve an exception to the use of the E-Gov Travel Service? 301-73.103 Section 301-73.103 Public... What must we do when we approve an exception to the use of the E-Gov Travel Service? The head of your...

  20. Accessing the exceptional points of parity-time symmetric acoustics

    PubMed Central

    Shi, Chengzhi; Dubois, Marc; Chen, Yun; Cheng, Lei; Ramezani, Hamidreza; Wang, Yuan; Zhang, Xiang

    2016-01-01

    Parity-time (PT) symmetric systems experience phase transition between PT exact and broken phases at exceptional point. These PT phase transitions contribute significantly to the design of single mode lasers, coherent perfect absorbers, isolators, and diodes. However, such exceptional points are extremely difficult to access in practice because of the dispersive behaviour of most loss and gain materials required in PT symmetric systems. Here we introduce a method to systematically tame these exceptional points and control PT phases. Our experimental demonstration hinges on an active acoustic element that realizes a complex-valued potential and simultaneously controls the multiple interference in the structure. The manipulation of exceptional points offers new routes to broaden applications for PT symmetric physics in acoustics, optics, microwaves and electronics, which are essential for sensing, communication and imaging. PMID:27025443

  1. Health Related Quality of Life in a Dutch Rehabilitation Population: Reference Values and the Effect of Physical Activity.

    PubMed

    Krops, Leonie A; Jaarsma, Eva A; Dijkstra, Pieter U; Geertzen, Jan H B; Dekker, Rienk

    2017-01-01

    To establish reference values for Health Related Quality of Life (HRQoL) in a Dutch rehabilitation population, and to study effects of patient characteristics, diagnosis and physical activity on HRQoL in this population. Former rehabilitation patients (3169) were asked to fill in a questionnaire including the Dutch version of the RAND-36. Differences between our rehabilitation patients and Dutch reference values were analyzed (t-tests). Effects of patient characteristics, diagnosis and movement intensity on scores on the subscales of the RAND-36 were analyzed using block wise multiple regression analyses. In total 1223 patients (39%) returned the questionnaire. HRQoL was significantly poorer in the rehabilitation patients compared to Dutch reference values on all subscales (p<0.001) except for health change (p = 0.197). Longer time between questionnaire and last treatment was associated with a smaller health change (p = 0.035). Higher age negatively affected physical functioning (p<0.001), social functioning (p = 0.004) and health change (p = 0.001). Diagnosis affected outcomes on all subscales except role limitations physical, and mental health (p ranged <0.001 to 0.643). Higher movement intensity was associated with better outcomes on all subscales except for mental health (p ranged <0.001 to 0.190). HRQoL is poorer in rehabilitation patients compared to Dutch reference values. Physical components of HRQoL are affected by diagnosis. In rehabilitation patients an association between movement intensity and HRQoL was found. For clinical purposes, results of this study can be used as reference values for HRQoL in a rehabilitation setting.

  2. Physical stability of drugs after storage above and below the glass transition temperature: Relationship to glass-forming ability.

    PubMed

    Alhalaweh, Amjad; Alzghoul, Ahmad; Mahlin, Denny; Bergström, Christel A S

    2015-11-10

    Amorphous materials are inherently unstable and tend to crystallize upon storage. In this study, we investigated the extent to which the physical stability and inherent crystallization tendency of drugs are related to their glass-forming ability (GFA), the glass transition temperature (Tg) and thermodynamic factors. Differential scanning calorimetry was used to produce the amorphous state of 52 drugs [18 compounds crystallized upon heating (Class II) and 34 remained in the amorphous state (Class III)] and to perform in situ storage for the amorphous material for 12h at temperatures 20°C above or below the Tg. A computational model based on the support vector machine (SVM) algorithm was developed to predict the structure-property relationships. All drugs maintained their Class when stored at 20°C below the Tg. Fourteen of the Class II compounds crystallized when stored above the Tg whereas all except one of the Class III compounds remained amorphous. These results were only related to the glass-forming ability and no relationship to e.g. thermodynamic factors was found. The experimental data were used for computational modeling and a classification model was developed that correctly predicted the physical stability above the Tg. The use of a large dataset revealed that molecular features related to aromaticity and π-π interactions reduce the inherent physical stability of amorphous drugs. Copyright © 2015 Elsevier B.V. All rights reserved.

  3. Physical properties of dust particles in different comets inferred from observations and experimental simulations

    NASA Astrophysics Data System (ADS)

    Hadamcik, E.; Levasseur-Regourd, A. C.

    2007-08-01

    1.Introduction Remote observations of solar light scattered by cometary dust particles provide information on the dust properties for a large variety of comets, in complement to the exceptional in-situ observations (with or without sample returns). The scattered light is partially linearly polarized, with a polarization degree depending on the geometry of observations (phase angle ?) and on the physical properties of the particles. Differences in polarization have been found in cometary comae, pointing to different physical properties of the dust (e.g. sizes of the grains, of the aggregates, structures and porosities, complex refractive indices) [1, 2]. Such differences, as well as an observed polarimetric wavelength effect, tend to show that large aggregates made of submicron-sized grains could be present in some cometary comae regions [3, 4]. On the opposite, more compact particles seem to be present in other comae regions and/or comets [5, 6]. 2. Results We will present observations of different comets. The variations of the dust properties in the coma and their evolution will be discussed. The results will be compared to the results obtained by other observational techniques. On the images of comet 9P/Tempel 1 (at ?=41°) some hours after Deep Impact, two kinds of dust particles are detected: more compact particles with small velocities and fluffy particles ejected by the impact with larger velocities. On the images of comet 73P/Schwassmann-Wachmann 3, in the tail direction of fragment B, a disruption is observed. The dust coma around fragment C is more symmetric. For both A and B, important dust jets are ejected by the nucleus, which are visible on the intensity images in the solar and antisolar directions, and on the polarization maps. 3. Interpretation and conclusion Numerical (7,8,9) and experimental simulations provide an interpretation of the observations in terms of the physical properties of the particles. Experimental simulations have been performed on numerous levitating samples (compact and fluffy) with the PROGRA2 experiment, either in reduced gravity conditions (parabolic flights) [10,11], or lifted by an air-draught (laboratory conditions) [12,13]. The variations of the polarization are correlated to variations in the size of the grains and aggregates and are a function of the complex refractive index and its evolution. The correlation between the variations of the scattered intensity and the linear polarization maps allows us to disentangle different physical properties of the dust. The results are compared to results obtained from previous observations by the same methods. References [1] E. Hadamcik and A.C. Levasseur-Regourd, JQSRT 79-80, 661-678 (2003) [2] A.C. Levasseur-Regourd, E. Hadamcik, JQSRT 79-80, 903-910 (2003) [3] E. Hadamcik, A.C. Levasseur-Regourd, A&A 403, 757- 768 (2003) [4] L. Kolokolova et al., In: Comets II, M.C. Festou et al. (eds), pp 577 (2004) [5] E. Hadamcik, A.C. Levasseur-Regourd, Icarus 166, 188-194 (2003) [6] E. Hadamcik et al., Icarus, accepted. [7] J. Lasue, A.C. Levasseur-Regourd, JQSRT 100, 220-236 (2006) [8] H. Kimura et al., A&A 449, 1243-1254 (2006) [9] A.C. Levasseur-Regourd et al., PSS, in press, available on line (2007) [10] J.-B. Renard et al. Appl. Opt 41, 609-618 (2002) [11] J.-B. Renard et al., Adv. Space Res. 31, 2511-2518 (2003) [12] E. Hadamcik et al., JQSRT 100, 143-156 (2006) [13] E. Hadamcik et al., Icarus, in press, available on line (2007)

  4. 40 CFR 716.50 - Reporting physical and chemical properties.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 31 2014-07-01 2014-07-01 false Reporting physical and chemical... SUBSTANCES CONTROL ACT HEALTH AND SAFETY DATA REPORTING General Provisions § 716.50 Reporting physical and chemical properties. Studies of physical and chemical properties must be reported under this subpart if...

  5. 40 CFR 716.50 - Reporting physical and chemical properties.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Reporting physical and chemical... SUBSTANCES CONTROL ACT HEALTH AND SAFETY DATA REPORTING General Provisions § 716.50 Reporting physical and chemical properties. Studies of physical and chemical properties must be reported under this subpart if...

  6. 40 CFR 716.50 - Reporting physical and chemical properties.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 32 2012-07-01 2012-07-01 false Reporting physical and chemical... SUBSTANCES CONTROL ACT HEALTH AND SAFETY DATA REPORTING General Provisions § 716.50 Reporting physical and chemical properties. Studies of physical and chemical properties must be reported under this subpart if...

  7. 40 CFR 716.50 - Reporting physical and chemical properties.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 32 2013-07-01 2013-07-01 false Reporting physical and chemical... SUBSTANCES CONTROL ACT HEALTH AND SAFETY DATA REPORTING General Provisions § 716.50 Reporting physical and chemical properties. Studies of physical and chemical properties must be reported under this subpart if...

  8. 40 CFR 716.50 - Reporting physical and chemical properties.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 31 2011-07-01 2011-07-01 false Reporting physical and chemical... SUBSTANCES CONTROL ACT HEALTH AND SAFETY DATA REPORTING General Provisions § 716.50 Reporting physical and chemical properties. Studies of physical and chemical properties must be reported under this subpart if...

  9. Comparative studies on the performance and emissions of a direct injection diesel engine fueled with neem oil and pumpkin seed oil biodiesel with and without fuel preheater.

    PubMed

    Ramakrishnan, Muneeswaran; Rathinam, Thansekhar Maruthu; Viswanathan, Karthickeyan

    2018-02-01

    In the present experimental analysis, two non-edible oils namely neem oil and pumpkin seed oil were considered. They are converted into respective biodiesels namely neem oil methyl ester (B1) and pumpkin seed oil methyl ester (B2) through transesterification process and their physical and chemical properties were examined using ASTM standards. Diesel was used as a baseline fuel in Kirloskar TV1 model direct injection four stroke diesel engine. A fuel preheater was designed and fabricated to operate at various temperatures (60, 70, and 80 °C). Diesel showed higher brake thermal efficiency (BTE) than biodiesel samples. Lower brake specific fuel consumption (BSFC) was obtained with diesel than B1 sample. B1 exhibited lower BSFC than B2 sample without preheating process. High preheating temperature (80 °C) results in lower fuel consumption for B1 sample. The engine emission characteristics like carbon monoxide (CO), hydrocarbon (HC), and smoke were found lower with B1 sample than diesel and B2 except oxides of nitrogen (NOx) emission. In preheating of fuel, B1 sample with high preheating temperature showed lower CO, HC, and smoke emission (except NOx) than B2 sample.

  10. 24 CFR 235.1214 - Mortgage lien.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ...: Contract Rights and Obligations; Assistance Payments Contracts; Servicing Responsibilities-Refinancing... unpaid obligations contracted in connection with the mortgage transaction or the purchase of the mortgaged property, except obligations that are secured by property or collateral owned by the mortgagor...

  11. 31 CFR 515.203 - Effect of transfers violating the provisions of this part.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... purpose of this section the term property includes gold, silver, bullion, currency, coin, credit... commodities, and evidences of any of the foregoing. The term property shall not, except to the extent...

  12. Physical mechanisms may be as important as brain mechanisms in evolution of speech.

    PubMed

    de Boer, Bart; Perlman, Marcus

    2014-12-01

    We present two arguments why physical adaptations for vocalization may be as important as neural adaptations. First, fine control over vocalization is not easy for physical reasons, and modern humans may be exceptional. Second, we present an example of a gorilla that shows rudimentary voluntary control over vocalization, indicating that some neural control is already shared with great apes.

  13. Parental Roles in Provision of Mobility and Educational Resources for Children with Physical Challenges a Case of Joytown Special School, Kiambu County, Kenya

    ERIC Educational Resources Information Center

    Kamau, Joyce

    2017-01-01

    Children with physical challenges have developmental needs and rights like other children and due to their exceptionality they call for more attention in provision of adequate quality mobility and educational resources to enhance their holistic development. However, it is apparent that provision of resources to children with physical challenges…

  14. Keeping the Physical Educator "Connected" an Examination of Comfort Level, Usage and Professional Development Available for Technology Integration in the Curricular Area of Physical Education

    ERIC Educational Resources Information Center

    Adkins, Megan; Bice, Matthew R.; Worrell, Vicki; Unruh, Nita

    2017-01-01

    Schools continue to integrate the use of technology, and gymnasiums are not an exception. The purpose of the study was to determine the comfort level of Physical Education teachers integrating technology in the gymnasium, determine types of professional development provided for technology use, and potential barriers associated with technology…

  15. Crosscultural Adaptation and Validation of the Korean Version of the New Knee Society Knee Scoring System.

    PubMed

    Kim, Seok Jin; Basur, Mohnish Singh; Park, Chang Kyu; Chong, Suri; Kang, Yeon Gwi; Kim, Moon Ju; Jeong, Jeong Seong; Kim, Tae Kyun

    2017-06-01

    The 2011 Knee Society Score © (2011 KS Score © ) is used to characterize the expectations, symptoms, physical activity, and satisfaction of patients who undergo TKA and is widely used to assess the outcome of TKA. However, it has not been adapted or validated for use in Korea. We developed a Korean version of the 2011 KS Score and evaluated the (1) test-retest reliability, (2) convergent validity, and (3) responsiveness of the Korean version. The Korean version of the 2011 KS Score was derived by using a well-established translational procedure based on international guidelines, which include translation, synthesis, back-translation, expert committee review, pretesting, and submission for appraisal. A total of 123 patients with knee osteoarthritis who were scheduled to undergo TKA were recruited for the study. Ninety percent of the patients (111 of 123) were women, which is an exact representation of the Korean population having TKAs. To evaluate reliability, the patients were evaluated twice during a 4-week interval using the questionnaire. Reliability was assessed by using intraclass correlation coefficients (ICCs) and internal consistency by using Cronbach's alpha to determine the validity of the Korean version of the 2011 KS Score. The patients were evaluated by using the validated Korean versions of the WOMAC and SF-36 questionnaires. Spearman's correlation coefficient was used for validation. Responsiveness was determined by calculating the standardized response mean from the preoperative and postoperative test scores in the Korean version of the 2011 KS Score. To address the gender disparity in our study we identified 53 males who underwent TKA for osteoarthritis after completion of this study and generated age-matched controlled groups to evaluate construct validity and responsiveness in Korean males. The reliability proved good to excellent with an ICC between 0.69 and 0.85, depending on the clinical properties tested, which included the following: symptoms, satisfaction, expectation, and total functional activity consisting of functional activity, standard activity, advanced activity, and discretionary activity. All subscales showed good to excellent internal consistency indicated by Chronbach's alpha (range, 0.83-0.92). For validity, three of the four domains (the exception was expectation) of the 2011 KS Score, correlated either strongly or moderately with the Korean WOMAC score (r ≥ 0.35). When compared with the SF-36, the satisfaction domain showed a weak positive correlation with all the subscales of the SF-36 except general health (r < 0.35). The activity domain showed a strong positive correlation with physical function (r = 0.62) and physical component summary (r = 0.52), moderate with physical role (r = 0.46), and weak with bodily pain (r = 0.26) and social function (r = 0.31). The symptom domain also exhibited a similar moderate positive correlation with physical function (r = 0.41) and weak positive correlation with bodily pain, social function, and physical component summary (r = 0.22, 0.20, and 0.26, respectively). For responsiveness, all the domains of Korean version of the 2011 KS Score, except for expectation, showed large changes (> 0.8), calculated as standardized response mean. The total amount of the Korean version of the 2011 KS Score (2.03, p < 0.001) showed higher responsiveness when compared with the WOMAC total (1.88, p < 0.001) and SF-36 physical and mental component summaries (1.14, p < 0.001; and 0.68, p < 0.001, respectively). The Korean version of the 2011 KS Score was successfully developed using a process of crosscultural adaptation for the Korean-speaking population who had undergone TKA for osteoarthritis of the knee. The Korean version of the 2011 KS Score was shown to be a reliable, valid, and responsive tool and can be used to assess functional outcomes and expectations of Korean patients who undergo TKA. The demographic features of TKA in the Korean population should be taken into account with additional studies recommended to further investigate these psychometric properties in Korean men. Level II, diagnostic study.

  16. 48 CFR 1852.245-78 - Physical inventory of capital personal property.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 48 Federal Acquisition Regulations System 6 2011-10-01 2011-10-01 false Physical inventory of... Provisions and Clauses 1852.245-78 Physical inventory of capital personal property. As prescribed in 1845.107-70(i), insert the following clause. Physical Inventory of Capital Personal Property (JAN 2011) (a) In...

  17. 36 CFR 520.4 - Protection of zoo animals.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 36 Parks, Forests, and Public Property 3 2014-07-01 2014-07-01 false Protection of zoo animals... Protection of zoo animals. Except for official purposes, no person shall: (a) Kill, injure, or disturb any exhibit or research animal by any means except to secure personal safety; (b) Pet, attempt to pet, handle...

  18. 36 CFR 520.4 - Protection of zoo animals.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 36 Parks, Forests, and Public Property 3 2011-07-01 2011-07-01 false Protection of zoo animals... Protection of zoo animals. Except for official purposes, no person shall: (a) Kill, injure, or disturb any exhibit or research animal by any means except to secure personal safety; (b) Pet, attempt to pet, handle...

  19. 36 CFR 520.4 - Protection of zoo animals.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 36 Parks, Forests, and Public Property 3 2012-07-01 2012-07-01 false Protection of zoo animals... Protection of zoo animals. Except for official purposes, no person shall: (a) Kill, injure, or disturb any exhibit or research animal by any means except to secure personal safety; (b) Pet, attempt to pet, handle...

  20. 36 CFR 520.4 - Protection of zoo animals.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 36 Parks, Forests, and Public Property 3 2010-07-01 2010-07-01 false Protection of zoo animals... Protection of zoo animals. Except for official purposes, no person shall: (a) Kill, injure, or disturb any exhibit or research animal by any means except to secure personal safety; (b) Pet, attempt to pet, handle...

  1. 26 CFR 1.1245-4 - Exceptions and limitations.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... limitations. (a) Exception for gifts—(1) General rule. Section 1245(b)(1) provides that no gain shall be recognized under section 1245(a)(1) upon a disposition by gift. For purposes of this paragraph, the term gift...) or (d) (relating to basis of property acquired by gifts). For reduction in amount of charitable...

  2. 36 CFR § 327.8 - Hunting, fishing, and trapping.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 36 Parks, Forests, and Public Property 3 2013-07-01 2012-07-01 true Hunting, fishing, and trapping... THE CHIEF OF ENGINEERS § 327.8 Hunting, fishing, and trapping. (a) Hunting is permitted except in... areas and during periods where prohibited by the District Commander. (c) Fishing is permitted except in...

  3. 41 CFR 50-203.13 - Requests for exceptions and exemptions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... and exemptions. 50-203.13 Section 50-203.13 Public Contracts and Property Management Other Provisions... Exemptions Pursuant to Section 6 of the Walsh-Healey Public Contracts Act § 50-203.13 Requests for exceptions... finding by him setting forth reasons why such inclusion or application will seriously impair the conduct...

  4. Introduction to physical properties and elasticity models: Chapter 20

    USGS Publications Warehouse

    Dvorkin, Jack; Helgerud, Michael B.; Waite, William F.; Kirby, Stephen H.; Nur, Amos

    2003-01-01

    Estimating the in situ methane hydrate volume from seismic surveys requires knowledge of the rock physics relations between wave speeds and elastic moduli in hydrate/sediment mixtures. The elastic moduli of hydrate/sediment mixtures depend on the elastic properties of the individual sedimentary particles and the manner in which they are arranged. In this chapter, we present some rock physics data currently available from literature. The unreferenced values in Table I were not measured directly, but were derived from other values in Tables I and II using standard relationships between elastic properties for homogeneous, isotropic material. These derivations allow us to extend the list of physical property estimates, but at the expense of introducing uncertainties due to combining property values measured under different physical conditions. This is most apparent in the case of structure II (sII) hydrate for which very few physical properties have been measured under identical conditions.

  5. Physical approaches to biomaterial design

    PubMed Central

    Mitragotri, Samir; Lahann, Joerg

    2009-01-01

    The development of biomaterials for drug delivery, tissue engineering and medical diagnostics has traditionally been based on new chemistries. However, there is growing recognition that the physical as well as the chemical properties of materials can regulate biological responses. Here, we review this transition with regard to selected physical properties including size, shape, mechanical properties, surface texture and compartmentalization. In each case, we present examples demonstrating the significance of these properties in biology. We also discuss synthesis methods and biological applications for designer biomaterials, which offer unique physical properties. PMID:19096389

  6. 42 CFR 440.130 - Diagnostic, screening, preventive, and rehabilitative services.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ...) Promote physical and mental health and efficiency. (d) “Rehabilitative services,” except as otherwise... reduction of physical or mental disability and restoration of a recipient to his best possible functional... under State law, to enable him to identify the existence, nature, or extent of illness, injury, or other...

  7. Making a Difference? Education and "Ability" in Physical Education

    ERIC Educational Resources Information Center

    Evans, John

    2004-01-01

    This paper brings a speculative, sociological perspective to the nature of "ability" in physical education (PE) and asks why this aspect of embodiment, with notable exceptions, has received so little critical attention in the professional discourse of PE and associated research in recent years. It is suggested that thinking about…

  8. 24 CFR 968.112 - Eligible costs.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ...) Demonstration of viability. Except in the case of emergency work, a PHA shall only expend funds on a development... physical and social viability of the development at a reasonable cost (as defined in § 968.105), or for... for the long-term physical and social viability of the individual development. Development specific...

  9. 24 CFR 968.112 - Eligible costs.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ...) Demonstration of viability. Except in the case of emergency work, a PHA shall only expend funds on a development... physical and social viability of the development at a reasonable cost (as defined in § 968.105), or for... for the long-term physical and social viability of the individual development. Development specific...

  10. 24 CFR 968.112 - Eligible costs.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ...) Demonstration of viability. Except in the case of emergency work, a PHA shall only expend funds on a development... physical and social viability of the development at a reasonable cost (as defined in § 968.105), or for... for the long-term physical and social viability of the individual development. Development specific...

  11. 38 CFR 51.200 - Physical environment.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...) PER DIEM FOR NURSING HOME CARE OF VETERANS IN STATE HOMES Standards § 51.200 Physical environment. The...), except that the requirement in paragraph 19.3.5.1 for all buildings containing nursing homes to have an... be designed and equipped for adequate nursing care, comfort, and privacy of residents: (1) Bedrooms...

  12. 38 CFR 51.200 - Physical environment.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...) PER DIEM FOR NURSING HOME CARE OF VETERANS IN STATE HOMES Standards § 51.200 Physical environment. The...), except that the requirement in paragraph 19.3.5.1 for all buildings containing nursing homes to have an... be designed and equipped for adequate nursing care, comfort, and privacy of residents: (1) Bedrooms...

  13. 38 CFR 51.200 - Physical environment.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) PER DIEM FOR NURSING HOME CARE OF VETERANS IN STATE HOMES Standards § 51.200 Physical environment. The...), except that the requirement in paragraph 19.3.5.1 for all buildings containing nursing homes to have an... be designed and equipped for adequate nursing care, comfort, and privacy of residents: (1) Bedrooms...

  14. 38 CFR 51.200 - Physical environment.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...) PER DIEM FOR NURSING HOME CARE OF VETERANS IN STATE HOMES Standards § 51.200 Physical environment. The...), except that the requirement in paragraph 19.3.5.1 for all buildings containing nursing homes to have an... be designed and equipped for adequate nursing care, comfort, and privacy of residents: (1) Bedrooms...

  15. 38 CFR 51.200 - Physical environment.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) PER DIEM FOR NURSING HOME CARE OF VETERANS IN STATE HOMES Standards § 51.200 Physical environment. The...), except that the requirement in paragraph 19.3.5.1 for all buildings containing nursing homes to have an... be designed and equipped for adequate nursing care, comfort, and privacy of residents: (1) Bedrooms...

  16. 26 CFR 1.1254-2 - Exceptions and limitations.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... property acquired by gift). For rules concerning the potential reduction in the amount of the charitable....1254-3(b)(1) for determination of potential recapture of section 1254 costs on property acquired by... resource recapture property is in part a sale or exchange and in part a gift, the gain that is treated as...

  17. 26 CFR 5c.168(f)(8)-1 - Special rules for leases.

    Code of Federal Regulations, 2014 CFR

    2014-04-01

    ... under section 38 with respect to the leased property. (b) Exception for qualified research expenditures... to another person for the right to use personal property in the conduct of qualified research shall... (e.g., has legal title to the property) and retains the burdens, benefits, and incidents of ownership...

  18. 26 CFR 5c.168(f)(8)-1 - Special rules for leases.

    Code of Federal Regulations, 2011 CFR

    2011-04-01

    ... under section 38 with respect to the leased property. (b) Exception for qualified research expenditures... to another person for the right to use personal property in the conduct of qualified research shall... (e.g., has legal title to the property) and retains the burdens, benefits, and incidents of ownership...

  19. 26 CFR 5c.168(f)(8)-1 - Special rules for leases.

    Code of Federal Regulations, 2012 CFR

    2012-04-01

    ... under section 38 with respect to the leased property. (b) Exception for qualified research expenditures... to another person for the right to use personal property in the conduct of qualified research shall... (e.g., has legal title to the property) and retains the burdens, benefits, and incidents of ownership...

  20. 26 CFR 5c.168(f)(8)-1 - Special rules for leases.

    Code of Federal Regulations, 2013 CFR

    2013-04-01

    ... under section 38 with respect to the leased property. (b) Exception for qualified research expenditures... to another person for the right to use personal property in the conduct of qualified research shall... (e.g., has legal title to the property) and retains the burdens, benefits, and incidents of ownership...

  1. 26 CFR 5c.168(f)(8)-1 - Special rules for leases.

    Code of Federal Regulations, 2010 CFR

    2010-04-01

    ... under section 38 with respect to the leased property. (b) Exception for qualified research expenditures... to another person for the right to use personal property in the conduct of qualified research shall... (e.g., has legal title to the property) and retains the burdens, benefits, and incidents of ownership...

  2. 5 CFR 6701.103 - Prohibited purchases of property sold by GSA.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... 5 Administrative Personnel 3 2010-01-01 2010-01-01 false Prohibited purchases of property sold by... STANDARDS OF ETHICAL CONDUCT FOR EMPLOYEES OF THE GENERAL SERVICES ADMINISTRATION § 6701.103 Prohibited purchases of property sold by GSA. (a) General prohibition. Except as provided in paragraphs (b) and (c) of...

  3. Sensitivity analysis of non-cohesive sediment transport formulae

    NASA Astrophysics Data System (ADS)

    Pinto, Lígia; Fortunato, André B.; Freire, Paula

    2006-10-01

    Sand transport models are often based on semi-empirical equilibrium transport formulae that relate sediment fluxes to physical properties such as velocity, depth and characteristic sediment grain sizes. In engineering applications, errors in these physical properties affect the accuracy of the sediment fluxes. The present analysis quantifies error propagation from the input physical properties to the sediment fluxes, determines which ones control the final errors, and provides insight into the relative strengths, weaknesses and limitations of four total load formulae (Ackers and White, Engelund and Hansen, van Rijn, and Karim and Kennedy) and one bed load formulation (van Rijn). The various sources of uncertainty are first investigated individually, in order to pinpoint the key physical properties that control the errors. Since the strong non-linearity of most sand transport formulae precludes analytical approaches, a Monte Carlo method is validated and used in the analysis. Results show that the accuracy in total sediment transport evaluations is mainly determined by errors in the current velocity and in the sediment median grain size. For the bed load transport using the van Rijn formula, errors in the current velocity alone control the final accuracy. In a final set of tests, all physical properties are allowed to vary simultaneously in order to analyze the combined effect of errors. The combined effect of errors in all the physical properties is then compared to an estimate of the errors due to the intrinsic limitations of the formulae. Results show that errors in the physical properties can be dominant for typical uncertainties associated with these properties, particularly for small depths. A comparison between the various formulae reveals that the van Rijn formula is more sensitive to basic physical properties. Hence, it should only be used when physical properties are known with precision.

  4. Development and psychometric properties of the Y-PASS questionnaire to assess correlates of lunchtime and after-school physical activity in children

    PubMed Central

    2014-01-01

    Background To frame interventions, it is useful to understand context- and time-specific correlates of children’s physical activity. To do this, we need accurate assessment of these correlates. There are currently no measures that assess correlates at all levels of the social ecological model, contain items that are specifically worded for the lunchtime and/or after-school time periods, and assess correlates that have been conceptualised and defined by children. The aim of this study was to develop and evaluate the psychometric properties of the lunchtime and after-school Youth Physical Activity Survey for Specific Settings (Y-PASS) questionnaires. Methods The Y-PASS questionnaire was administered to 264 South Australian children (146 boys, 118 girls; mean age = 11.7 ± 0.93 years). Factorial structure and internal consistency of the intrapersonal, sociocultural and physical environmental/policy lunchtime and after-school subscales were examined through an exploratory factor analysis. The test-retest reliability of the Y-PASS subscales was assessed over a one-week period on a subsample of children (lunchtime Y-PASS: n = 12 boys, 12 girls, mean age of 11.6 ± 0.8 years; after-school Y-PASS: n = 9 boys, 13 girls; mean age = 11.4 ± 0.9 years). Results For the lunchtime Y-PASS, three factors were identified under each of the intrapersonal, sociocultural and physical environmental/policy subscales. For the after-school Y-PASS, six factors were identified in the intrapersonal subscale, four factors in the sociocultural subscale and seven factors in the physical environmental/policy subscale. Following item reduction, all subscales demonstrated acceptable internal consistency (Cronbach alpha = 0.78 – 0.85), except for the lunchtime sociocultural subscale (Cronbach alpha = 0.55). The factors and items demonstrated fair to very high test-retest reliability (ICC = 0.26 – 0.93). Conclusion The preliminary reliability and factorial structure evidence suggests the Y-PASS correlate questionnaires are robust tools for measuring correlates of context-specific physical activity in children. The multi-dimensional factor structure provides justification for exploring physical activity correlates from a social ecological perspective and demonstrates the importance of developing items that are context specific. Further development and refinement of the Y-PASS questionnaires is recommended, including a confirmatory factor analysis and exploring the inclusion of additional items. PMID:24885601

  5. 7 CFR 1955.2 - Policy.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... of the Department of Agriculture (Continued) RURAL HOUSING SERVICE, RURAL BUSINESS-COOPERATIVE... REGULATIONS (CONTINUED) PROPERTY MANAGEMENT Liquidation of Loans Secured by Real Estate and Acquisition of... sale of the property by the borrower (except for Multiple Family Housing (MFH) loans subject to...

  6. 13 CFR 314.9 - Recorded statement-title.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... PROPERTY Personal Property § 314.9 Recorded statement—title. For all Projects which EDA determines involve... ships, machinery, equipment, removable fixtures or structural components of buildings, the Recipient... part of the Project, except as otherwise provided in this part. ...

  7. Compensation for noise damaged property.

    DOT National Transportation Integrated Search

    1974-01-01

    The U.S. Constitution and the constitution of every state, except North Carolina, requires "just compensation" to be made for property taken by eminent domain. Courts both in Virginia and elsewhere have taken a very narrow view of this requirement wh...

  8. Modelling of the Thermo-Physical and Physical Properties for Solidification of Al-Alloys

    NASA Astrophysics Data System (ADS)

    Saunders, N.; Li, X.; Miodownik, A. P.; Schillé, J.-P.

    The thermo-physical and physical properties of the liquid and solid phases are critical components in casting simulations. Such properties include the fraction solid transformed, enthalpy release, thermal conductivity, volume and density, all as a function of temperature. Due to the difficulty in experimentally determining such properties at solidification temperatures, little information exists for multi-component alloys. As part of the development of a new computer program for modelling of materials properties (JMatPro) extensive work has been carried out on the development of sound, physically based models for these properties. Wide ranging results will presented for Al-based alloys, which will include more detailed information concerning the density change of the liquid that intrinsically occurs during solidification due to its change in composition.

  9. Thermoelectric properties of SnSe1-xSx(0

    NASA Astrophysics Data System (ADS)

    Nguyen, Thi Minh Hai; Duong, Anh Tuan; Duvjir, Ganbat; Trinh, Thi Ly; Nguyen, Van Quang; Kim, Jungdae; Cho, Sunglae

    Tin selenide (SnSe), a p-type semiconductor, has attracted many attention due to its excellent thermoelectric efficiency, i.e., ZT = 2.6 along the b-axis of its high temperature phase. This issue has renewed interests in thermoelectric properties of the materials which adopted the same layered structure as SnSe, such as SnS, GeS, and GeSe. Among these compounds, tin (II) sulfide (SnS) is exceptionally attractive because of its natural abundance and low toxicity. However, the experimental results show that SnS has possessed a small value of the figure of merit. To optimize the thermoelectric performance of SnS, making solid solution is a potential way. That is our motivation for the investigation of SnSe1-xSx single crystals' thermoelectric properties. In this study, SnSe1-xSx (0

  10. Molecular and supramolecular control of the work function of an inorganic electrode with self-assembled monolayer of umbrella-shaped fullerene derivatives.

    PubMed

    Lacher, Sebastian; Matsuo, Yutaka; Nakamura, Eiichi

    2011-10-26

    The surface properties of inorganic substrates can be altered by coating with organic molecules, which may result in the improvement of the properties suitable for electronic or biological applications. This article reports a systematic experimental study on the influence of the molecular and supramolecular properties of umbrella-shaped penta(organo)[60]fullerene derivatives, and on the work function and the water contact angle of indium-tin oxide (ITO) and gold surfaces. We could relate these macroscopic characteristics to single-molecular level properties, such as ionization potential and molecular dipole. The results led us to conclude that the formation of a SAM of a polar compound generates an electronic field through intermolecular interaction of the molecular charges, and this field makes the overall dipole of the SAM much smaller than the one expected from the simple sum of the dipoles of all molecules in the SAM. This effect, which was called depolarization and previously discussed theoretically, is now quantitatively probed by experiments. The important physical properties in surface science such as work function, ionization potential, and water contact angles have been mutually correlated at the level of molecular structures and molecular orientations on the substrate surface. We also found that the SAMs on ITO and gold operate under the same principle except that the "push-back" effect operates specifically for gold. The study also illustrates the ability of the photoelectron yield spectroscopy technique to rapidly measure the work function of a SAM-covered substrate and the ionization potential value of a molecule on the surface.

  11. Additively manufactured metallic porous biomaterials based on minimal surfaces: A unique combination of topological, mechanical, and mass transport properties.

    PubMed

    Bobbert, F S L; Lietaert, K; Eftekhari, A A; Pouran, B; Ahmadi, S M; Weinans, H; Zadpoor, A A

    2017-04-15

    Porous biomaterials that simultaneously mimic the topological, mechanical, and mass transport properties of bone are in great demand but are rarely found in the literature. In this study, we rationally designed and additively manufactured (AM) porous metallic biomaterials based on four different types of triply periodic minimal surfaces (TPMS) that mimic the properties of bone to an unprecedented level of multi-physics detail. Sixteen different types of porous biomaterials were rationally designed and fabricated using selective laser melting (SLM) from a titanium alloy (Ti-6Al-4V). The topology, quasi-static mechanical properties, fatigue resistance, and permeability of the developed biomaterials were then characterized. In terms of topology, the biomaterials resembled the morphological properties of trabecular bone including mean surface curvatures close to zero. The biomaterials showed a favorable but rare combination of relatively low elastic properties in the range of those observed for trabecular bone and high yield strengths exceeding those reported for cortical bone. This combination allows for simultaneously avoiding stress shielding, while providing ample mechanical support for bone tissue regeneration and osseointegration. Furthermore, as opposed to other AM porous biomaterials developed to date for which the fatigue endurance limit has been found to be ≈20% of their yield (or plateau) stress, some of the biomaterials developed in the current study show extremely high fatigue resistance with endurance limits up to 60% of their yield stress. It was also found that the permeability values measured for the developed biomaterials were in the range of values reported for trabecular bone. In summary, the developed porous metallic biomaterials based on TPMS mimic the topological, mechanical, and physical properties of trabecular bone to a great degree. These properties make them potential candidates to be applied as parts of orthopedic implants and/or as bone-substituting biomaterials. Bone-substituting biomaterials aim to mimic bone properties. Although mimicking some of bone properties is feasible, biomaterials that could simultaneously mimic all or most of the relevant bone properties are rare. We used rational design and additive manufacturing to develop porous metallic biomaterials that exhibit an interesting combination of topological, mechanical, and mass transport properties. The topology of the developed biomaterials resembles that of trabecular bone including a mean curvature close to zero. Moreover, the developed biomaterials show an unusual combination of low elastic modulus to avoid stress shielding and high strength to provide mechanical support. The fatigue resistance of the developed biomaterials is also exceptionally high, while their permeability is in the range of values reported for bone. Copyright © 2017 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

  12. Effect of fertiliser on functional properties of flour from four rice varieties grown in Sri Lanka.

    PubMed

    Gunaratne, Anil; Sirisena, Nihal; Ratnayaka, Upul Kumari; Ratnayaka, Jennet; Kong, Xiangli; Vidhana Arachchi, Lal Peruma; Corke, Harold

    2011-05-01

    Fertiliser is an essential agro-chemical input in modern rice farming. Fertiliser affects the grain quality and yield of rice. Although much research has been carried out to investigate the influence of fertiliser (recommended NPK addition) on yield and quality of rice grain, little is known about the effect of fertiliser on thermal, pasting, gelling and retrogradation properties of rice flour. The aim of this study was to investigate the influence of recommended fertilisation on functional properties of rice flour from four popular high yielding rice varieties grown in Sri Lanka. Fertiliser (recommended NPK addition) increased the protein content but reduced the apparent amylose content in rice flour except in BG 357. Swelling power and amylose leaching were decreased by fertilizer. [corrected] Pasting onset temperature, cold paste viscosity and setback were increased but peak viscosity and granular breakdown decreased. In response to the fertiliser application, gelatinisation peak temperature was reduced in all varieties except BG 300. However, compared to pasting properties, gelatinisation parameters were not much affected by fertilisation. The extent of amylopectin retrogradation was decreased by fertiliser in BG 305 and BG 352 but unchanged in the other two varieties. Except in BG 305, fertiliser reduced the gel hardness of rice flour but increased the gel cohesiveness. It is apparent that the increased protein and reduced amylose content caused by fertiliser affect the functional properties of rice flour. Copyright © 2011 Society of Chemical Industry.

  13. Laser-assisted immobilization of colloid silver nanoparticles on polyethyleneterephthalate

    NASA Astrophysics Data System (ADS)

    Siegel, Jakub; Lyutakov, Oleksiy; Polívková, Markéta; Staszek, Marek; Hubáček, Tomáš; Švorčík, Václav

    2017-10-01

    Immobilization of nanoobjects on the surface of underlying material belongs to current issues of material science. Such altered materials exhibits completely exceptional properties exploitable in a broad spectrum of industrially important applications ranging from catalysts up to health-care industry. Here we present unique approach for immobilization of electrochemically synthesized silver nanoparticles on polyethyleneterephthalate (PET) foil whose essence lies in physical incorporation of particles into thin polymer surface layer induced by polarized excimer laser light. Changes in chemical composition and surface structure of polymer after particle immobilization were recorded by wide range of analytical techniques such as ARXPS, EDX, RBS, AAS, Raman, ICP-MS, DLS, UV-vis, SEM, TEM, and AFM. Thorough analysis of both nanoparticles entering the immobilization step as well as modified PET surface allowed revealing the mechanism of immobilization process itself. Silver nanoparticles were physically embedded into a thin surface layer of polymer reaching several nanometers beneath the surface rather than chemically bonded to PET macromolecules. Laser-implanted nanoparticles open up new possibilities especially in the development of the next generation cell-conform antimicrobial coatings of polymeric materials, namely due to the considerable immobilization strength which is strong enough to prevent particle release into the surrounding environment.

  14. Simulation of Strain Induced Pseudomagnetic Fields in Graphene Suspended on MEMS Chevron Actuators

    NASA Astrophysics Data System (ADS)

    Vutukuru, Mounika; Christopher, Jason; Bishop, David; Swan, Anna

    Graphene has been shown to withstand remarkable levels of mechanical strain an order of magnitude larger than bulk crystalline materials. This exceptional stretchability of graphene allows for the direct tuning of fundamental material properties, as well as for the investigation of novel physics such as generation of strain induced pseudomagnetic fields. However, current methods for strain such as polymer elongation or pressurized wells do not integrate well into devices. We propose microelectromechanical (MEMS) Chevron actuators as a reliable platform for applying strain to graphene. In addition to their advantageous controllable output force, low input power and ease of integration into existing technologies, MEMS allow for different strain orientations to optimize pseudomagnetic field generation in graphene. Here, we model nonuniform strain in suspended graphene on Chevron actuators using COMSOL Multiphysics. By simulating the deformation of the graphene geometry under the device actuation, we explore the pseudomagnetic field map induced by numerically calculating the components of the strain tensor. Our models provide the theoretical framework with which experimental analysis is compared, and optimize our MEMS designs for further exploration of novel physics in graphene. The authors would like to thank NSF DMR 1411008 for their support on this project.

  15. OSO 8 X-ray spectra of clusters of galaxies. I - Observations of twenty clusters: Physical correlations

    NASA Technical Reports Server (NTRS)

    Mushotzky, R. F.; Serlemitsos, P. J.; Boldt, E. A.; Holt, S. S.; Smith, B. W.

    1978-01-01

    OSO 8 X-ray spectra from 2 to 20 keV have been analyzed for 26 clusters of galaxies. For 20 clusters temperatures, emission integrals, iron abundances, and low-energy absorption measurements are presented. The data give, in general, better fits to thermal bremsstrahlung than to power-law models. Eight clusters have positive iron emission-line detections at the 90% confidence level, and all 20 cluster spectra are consistent with Fe/H = 0.000014 by number with the possible exception of Virgo. Thus it is confirmed that X-ray emission in this energy band is predominantly thermal radiation from hot intracluster gas rather than inverse Compton radiation. Physical correlations between X-ray spectral parameters and other cluster properties are examined. It is found that (1) the X-ray temperature is approximately proportional to the square of the velocity dispersion of the galaxies; (2) the emission integral is a strong function of the X-ray temperature; (3) the X-ray temperature and emission integral are better correlated with cluster central-galaxy density than with richness; and (4) the fraction of galaxies which are spirals is correlated with the observed ram pressure in the cluster core.

  16. Semantic modeling of the structural and process entities during plastic deformation of crystals and rocks

    NASA Astrophysics Data System (ADS)

    Babaie, Hassan; Davarpanah, Armita

    2016-04-01

    We are semantically modeling the structural and dynamic process components of the plastic deformation of minerals and rocks in the Plastic Deformation Ontology (PDO). Applying the Ontology of Physics in Biology, the PDO classifies the spatial entities that participate in the diverse processes of plastic deformation into the Physical_Plastic_Deformation_Entity and Nonphysical_Plastic_Deformation_Entity classes. The Material_Physical_Plastic_Deformation_Entity class includes things such as microstructures, lattice defects, atoms, liquid, and grain boundaries, and the Immaterial_Physical_Plastic_Deformation_Entity class includes vacancies in crystals and voids along mineral grain boundaries. The objects under the many subclasses of these classes (e.g., crystal, lattice defect, layering) have spatial parts that are related to each other through taxonomic (e.g., Line_Defect isA Lattice_Defect), structural (mereological, e.g., Twin_Plane partOf Twin), spatial-topological (e.g., Vacancy adjacentTo Atom, Fluid locatedAlong Grain_Boundary), and domain specific (e.g., displaces, Fluid crystallizes Dissolved_Ion, Void existsAlong Grain_Boundary) relationships. The dynamic aspect of the plastic deformation is modeled under the dynamical Process_Entity class that subsumes classes such as Recrystallization and Pressure_Solution that define the flow of energy amongst the physical entities. The values of the dynamical state properties of the physical entities (e.g., Chemical_Potential, Temperature, Particle_Velocity) change while they take part in the deformational processes such as Diffusion and Dislocation_Glide. The process entities have temporal parts (phases) that are related to each other through temporal relations such as precedes, isSubprocessOf, and overlaps. The properties of the physical entities, defined under the Physical_Property class, change as they participate in the plastic deformational processes. The properties are categorized into dynamical, constitutive, spatial, temporal, statistical, and thermodynamical. The dynamical properties, categorized under the Dynamical_Rate_Property and Dynamical_State_Property classes, subsume different classes of properties (e.g., Fluid_Flow_Rate, Temperature, Chemical_Potential, Displacement, Electrical_Charge) based on the physical domain (e.g., fluid, heat, chemical, solid, electrical). The properties are related to the objects under the Physical_Entity class through diverse object type (e.g., physicalPropertyOf) and data type (e.g., Fluid_Pressure unit 'MPa') properties. The changes of the dynamical properties of the physical entities, described by the empirical laws (equations) modeled by experimental structural geologists, are modeled through the Physical_Property_Dependency class that subsumes the more specialized constitutive, kinetic, and thermodynamic expressions of the relationships among the dynamic properties. Annotation based on the PDO will make it possible to integrate and reuse experimental plastic deformation data, knowledge, and simulation models, and conduct semantic-based search of the source data originating from different rock testing laboratories.

  17. Role of Gravity Waves in Determining Cirrus Cloud Properties

    NASA Technical Reports Server (NTRS)

    OCStarr, David; Singleton, Tamara; Lin, Ruei-Fong

    2008-01-01

    Cirrus clouds are important in the Earth's radiation budget. They typically exhibit variable physical properties within a given cloud system and from system to system. Ambient vertical motion is a key factor in determining the cloud properties in most cases. The obvious exception is convectively generated cirrus (anvils), but even in this case, the subsequent cloud evolution is strongly influenced by the ambient vertical motion field. It is well know that gravity waves are ubiquitous in the atmosphere and occur over a wide range of scales and amplitudes. Moreover, researchers have found that inclusion of statistical account of gravity wave effects can markedly improve the realism of simulations of persisting large-scale cirrus cloud features. Here, we use a 1 -dimensional (z) cirrus cloud model, to systematically examine the effects of gravity waves on cirrus cloud properties. The model includes a detailed representation of cloud microphysical processes (bin microphysics and aerosols) and is run at relatively fine vertical resolution so as to adequately resolve nucleation events, and over an extended time span so as to incorporate the passage of multiple gravity waves. The prescribed gravity waves "propagate" at 15 m s (sup -1), with wavelengths from 5 to 100 km, amplitudes range up to 1 m s (sup -1)'. Despite the fact that the net gravity wave vertical motion forcing is zero, it will be shown that the bulk cloud properties, e.g., vertically-integrated ice water path, can differ quite significantly from simulations without gravity waves and that the effects do depend on the wave characteristics. We conclude that account of gravity wave effects is important if large-scale models are to generate realistic cirrus cloud property climatology (statistics).

  18. TEACHING PHYSICS: The quantum understanding of pre-university physics students

    NASA Astrophysics Data System (ADS)

    Ireson, Gren

    2000-01-01

    Students in England and Wales wishing to read for a physics-based degree will, in all but the more exceptional situations, be required to follow the two-year GCE Advanced-level physics course. This course includes, in its mandatory core, material that addresses the topic of `quantum phenomena'. Over the years journals such as this have published teaching strategies, for example Lawrence (1996), but few studies addressing what students understand of quantum phenomena can be found. This paper aims to address just this problem.

  19. IT-based Physics Education in Korea

    NASA Astrophysics Data System (ADS)

    Lee, Keum-Hwi; Kim, Jin-Seung; Song, Hi-Sung

    2001-04-01

    Up to the mid-nineties, Korean education could be characterized by quantitative expansion, in line with the industrial development, and physics education was no exception. However, the rapid change in technology and international relations led to an ongoing educational reform for qualitative improvement. It strives for customer-oriented education, program divesification, and IT-rich training to prepare people for the future. This paper summarizes the current status of IT-based physics education with emphasis on collaborative effort recently initiated in the Korean physics community.

  20. Fat or Fit: Is There a Correlation?

    DTIC Science & Technology

    1990-04-18

    Body Composition/Weight Control Program, 9 except for the exercise programs prescribed to assist soldiers with weight control problems. It is intended...more exercise will automatically result in decreased body fat. A soldier who exceeds body fat standards may be able to pass the Army Physical Fitness...have attitude problems toward physical exercise .(8) The results of AR 350-15 defining physical fitness as having the appropriate amounts of fat and

  1. Anomalous thermal hysteresis in the high-field magnetic moments of magnetic nanoparticles embedded in multi-walled carbon nanotubes

    NASA Astrophysics Data System (ADS)

    Zhao, Guo-Meng; Wang, Jun; Ren, Yang; Beeli, Pieder

    2012-02-01

    We report high-temperature (300-1120 K) magnetic properties of Fe and Fe3O4 nanoparticles embedded in multi-walled carbon nanotubes. We unambiguously show that the magnetic moments of Fe and Fe3O4 nanoparticles are seemingly enhanced by a factor of about 3 compared with what they would be expected to have for free (unembedded) magnetic nanoparticles. What is more intriguing is that the enhanced moments were completely lost when the sample was heated up to 1120 K and the lost moments at 1120 K were completely recovered through several thermal cycles below 1020 K. The anomalous thermal hysteresis of the high-field magnetic moments is unlikely to be explained by existing physical models except for the high-field paramagnetic Meissner effect due to the existence of ultrahigh temperature superconductivity in the multi-walled carbon nanotubes.

  2. Reductionist Approach in Peptide-Based Nanotechnology.

    PubMed

    Gazit, Ehud

    2018-06-20

    The formation of ordered nanostructures by molecular self-assembly of proteins and peptides represents one of the principal directions in nanotechnology. Indeed, polyamides provide superior features as materials with diverse physical properties. A reductionist approach allowed the identification of extremely short peptide sequences, as short as dipeptides, which could form well-ordered amyloid-like β-sheet-rich assemblies comparable to supramolecular structures made of much larger proteins. Some of the peptide assemblies show remarkable mechanical, optical, and electrical characteristics. Another direction of reductionism utilized a natural noncoded amino acid, α-aminoisobutryic acid, to form short superhelical assemblies. The use of this exceptional helix inducer motif allowed the fabrication of single heptad repeats used in various biointerfaces, including their use as surfactants and DNA-binding agents. Two additional directions of the reductionist approach include the use of peptide nucleic acids (PNAs) and coassembly techniques. The diversified accomplishments of the reductionist approach, as well as the exciting future advances it bears, are discussed.

  3. Silver Nanoparticles: Technological Advances, Societal Impacts, and Metrological Challenges

    PubMed Central

    Calderón-Jiménez, Bryan; Johnson, Monique E.; Montoro Bustos, Antonio R.; Murphy, Karen E.; Winchester, Michael R.; Vega Baudrit, José R.

    2017-01-01

    Silver nanoparticles (AgNPs) show different physical and chemical properties compared to their macroscale analogs. This is primarily due to their small size and, consequently, the exceptional surface area of these materials. Presently, advances in the synthesis, stabilization, and production of AgNPs have fostered a new generation of commercial products and intensified scientific investigation within the nanotechnology field. The use of AgNPs in commercial products is increasing and impacts on the environment and human health are largely unknown. This article discusses advances in AgNP production and presents an overview of the commercial, societal, and environmental impacts of this emerging nanoparticle (NP), and nanomaterials in general. Finally, we examine the challenges associated with AgNP characterization, discuss the importance of the development of NP reference materials (RMs) and explore their role as a metrological mechanism to improve the quality and comparability of NP measurements. PMID:28271059

  4. Silver nanoparticles: technological advances, societal impacts, and metrological challenges

    NASA Astrophysics Data System (ADS)

    Calderón-Jiménez, Bryan; Johnson, Monique E.; Montoro Bustos, Antonio R.; Murphy, Karen E.; Winchester, Michael R.; Vega Baudrit, José R.

    2017-02-01

    Silver nanoparticles (AgNPs) show different physical and chemical properties compared to their macroscale analogs. This is primarily due to their small size and, consequently, the exceptional surface area of these materials. Presently, advances in the synthesis, stabilization, and production of AgNPs have fostered a new generation of commercial products and intensified scientific investigation within the nanotechnology field. The use of AgNPs in commercial products is increasing and impacts on the environment and human health are largely unknown. This article discusses advances in AgNP production and presents an overview of the commercial, societal, and environmental impacts of this emerging nanoparticle (NP), and nanomaterials in general. Finally, we examine the challenges associated with AgNP characterization, discuss the importance of the development of NP reference materials (RMs) and explore their role as a metrological mechanism to improve the quality and comparability of NP measurements.

  5. Structural features of biomass in a hybrid MBBR reactor.

    PubMed

    Xiao, G Y; Ganczarczyk, J

    2006-03-01

    The structural features of biomass present in the hybrid MBBR (Moving Bed Biofilm Reactor) aeration tank were studied in two subsequent periods, which differed in hydraulic and substrate loads. The physical characteristics of attached-growth biomass, such as, biofilm thickness, density, porosity, inner and surface fractal dimensions, and those of suspended-growth biomass, such as, floc size distribution, density, porosity, inner and surface fractal dimensions, were investigated in each study period and then compared. The results indicated that biofilm always had a higher density, geometric porosity, and a larger boundary fractal dimension than flocs. Both types of biomass were found to exhibit at least two distinct Sierpinski fractal dimensions, indicating two major different pore space populations. With the increasing wastewater flow, both types of biomass were found to shift their structural properties to larger values, except porosity and surface roughness, which decreased. Floc density and biomass Sierpinski fractals were not affected much by the system loadings.

  6. Indole Compounds Related to Auxins and Goitrogens of Woad (Isatis tinctoria L.) 1

    PubMed Central

    Elliott, Malcolm C.; Stowe, Bruce B.

    1971-01-01

    Five conspicuous indole derivatives are present in leaves and other tissues of woad (Isatis tinctoria L.). They were identified as tryptophan, isatan B, glucobrassicin, neoglucobrassicin, and glucobrassicin-1-sulfonate. The latter three indole glucosinolates are present at levels of at least 260, 69, and 200 milligrams per kilogram fresh weight and were isolated as crystalline salts. Comparison of physical and chemical properties, particularly NMR spectral analysis, confirms that the 1-methoxyglucobrassicin structure suggested for neoglucobrassicin is correct, whereas further evidence for the even more unusual sulfonation of the ring nitrogen in glucobrassicin-1-sulfonate was obtained. Glucobrassicin-1-sulfonate has an enzymic degradation pattern identical to that of glucobrassicin. As it too releases thiocyanate, it must be added to the list of known plant goitrogens. These studies and the techniques described establish woad as exceptionally suitable higher plant material for metabolic studies of indoles related to goitrogens and auxins. PMID:16657624

  7. Indole Compounds Related to Auxins and Goitrogens of Woad (Isatis tinctoria L.).

    PubMed

    Elliott, M C; Stowe, B B

    1971-03-01

    Five conspicuous indole derivatives are present in leaves and other tissues of woad (Isatis tinctoria L.). They were identified as tryptophan, isatan B, glucobrassicin, neoglucobrassicin, and glucobrassicin-1-sulfonate. The latter three indole glucosinolates are present at levels of at least 260, 69, and 200 milligrams per kilogram fresh weight and were isolated as crystalline salts. Comparison of physical and chemical properties, particularly NMR spectral analysis, confirms that the 1-methoxyglucobrassicin structure suggested for neoglucobrassicin is correct, whereas further evidence for the even more unusual sulfonation of the ring nitrogen in glucobrassicin-1-sulfonate was obtained. Glucobrassicin-1-sulfonate has an enzymic degradation pattern identical to that of glucobrassicin. As it too releases thiocyanate, it must be added to the list of known plant goitrogens. These studies and the techniques described establish woad as exceptionally suitable higher plant material for metabolic studies of indoles related to goitrogens and auxins.

  8. Interstitial atoms enable joint twinning and transformation induced plasticity in strong and ductile high-entropy alloys.

    PubMed

    Li, Zhiming; Tasan, Cemal Cem; Springer, Hauke; Gault, Baptiste; Raabe, Dierk

    2017-01-12

    High-entropy alloys (HEAs) consisting of multiple principle elements provide an avenue for realizing exceptional mechanical, physical and chemical properties. We report a novel strategy for designing a new class of HEAs incorporating the additional interstitial element carbon. This results in joint activation of twinning- and transformation-induced plasticity (TWIP and TRIP) by tuning the matrix phase's instability in a metastable TRIP-assisted dual-phase HEA. Besides TWIP and TRIP, such alloys benefit from massive substitutional and interstitial solid solution strengthening as well as from the composite effect associated with its dual-phase structure. Nanosize particle formation and grain size reduction are also utilized. The new interstitial TWIP-TRIP-HEA thus unifies all metallic strengthening mechanisms in one material, leading to twice the tensile strength compared to a single-phase HEA with similar composition, yet, at identical ductility.

  9. Soil experiment

    NASA Technical Reports Server (NTRS)

    Hutcheson, Linton; Butler, Todd; Smith, Mike; Cline, Charles; Scruggs, Steve; Zakhia, Nadim

    1987-01-01

    An experimental procedure was devised to investigate the effects of the lunar environment on the physical properties of simulated lunar soil. The test equipment and materials used consisted of a vacuum chamber, direct shear tester, static penetrometer, and fine grained basalt as the simulant. The vacuum chamber provides a medium for applying the environmental conditions to the soil experiment with the exception of gravity. The shear strength parameters are determined by the direct shear test. Strength parameters and the resistance of soil penetration by static loading will be investigated by the use of a static cone penetrometer. In order to conduct a soil experiment without going to the moon, a suitable lunar simulant must be selected. This simulant must resemble lunar soil in both composition and particle size. The soil that most resembles actual lunar soil is basalt. The soil parameters, as determined by the testing apparatus, will be used as design criteria for lunar soil engagement equipment.

  10. Preparation, Single-Molecule Manipulation, and Energy Transfer Investigation of a Polyfluorene-graft-DNA polymer.

    PubMed

    Madsen, Mikael; Christensen, Rasmus S; Krissanaprasit, Abhichart; Bakke, Mette R; Riber, Camilla F; Nielsen, Karina S; Zelikin, Alexander N; Gothelf, Kurt V

    2017-08-04

    Conjugated polymers have been intensively studied due to their unique optical and electronic properties combined with their physical flexibility and scalable bottom up synthesis. Although the bulk qualities of conjugated polymers have been extensively utilized in research and industry, the ability to handle and manipulate conjugated polymers at the nanoscale lacks significantly behind. Here, the toolbox for controlled manipulation of conjugated polymers was expanded through the synthesis of a polyfluorene-DNA graft-type polymer (poly(F-DNA)). The polymer possesses the characteristics associated with the conjugated polyfluorene backbone, but the protruding single-stranded DNA provides the material with an exceptional addressability. This study demonstrates controlled single-molecule patterning of poly(F-DNA), as well as energy transfer between two different polymer-DNA conjugates. Finally, highly efficient DNA-directed quenching of polyfluorene fluorescence was shown. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Interstitial atoms enable joint twinning and transformation induced plasticity in strong and ductile high-entropy alloys

    NASA Astrophysics Data System (ADS)

    Li, Zhiming; Tasan, Cemal Cem; Springer, Hauke; Gault, Baptiste; Raabe, Dierk

    2017-01-01

    High-entropy alloys (HEAs) consisting of multiple principle elements provide an avenue for realizing exceptional mechanical, physical and chemical properties. We report a novel strategy for designing a new class of HEAs incorporating the additional interstitial element carbon. This results in joint activation of twinning- and transformation-induced plasticity (TWIP and TRIP) by tuning the matrix phase’s instability in a metastable TRIP-assisted dual-phase HEA. Besides TWIP and TRIP, such alloys benefit from massive substitutional and interstitial solid solution strengthening as well as from the composite effect associated with its dual-phase structure. Nanosize particle formation and grain size reduction are also utilized. The new interstitial TWIP-TRIP-HEA thus unifies all metallic strengthening mechanisms in one material, leading to twice the tensile strength compared to a single-phase HEA with similar composition, yet, at identical ductility.

  12. Chemical Foundations of Hydrogen Sulfide Biology

    PubMed Central

    Li, Qian; Lancaster, Jack R.

    2013-01-01

    Following nitric oxide (nitrogen monoxide) and carbon monoxide, hydrogen sulfide (or its newer systematic name sulfane, H2S) became the third small molecule that can be both toxic and beneficial depending on the concentration. In spite of its impressive therapeutic potential, the underlying mechanisms for its beneficial effects remain unclear. Any novel mechanism has to obey fundamental chemical principles. H2S chemistry was studied long before its biological relevance was discovered, however, with a few exceptions, these past works have received relatively little attention in the path of exploring the mechanistic conundrum of H2S biological functions. This review calls attention to the basic physical and chemical properties of H2S, focuses on the chemistry between H2S and its three potential biological targets: oxidants, metals and thiol derivatives, discusses the applications of these basics into H2S biology and methodology, and introduces the standard terminology to this youthful field. PMID:23850631

  13. Ecology of red maple swamps in the glaciated northeast: A community profile

    DOE Office of Scientific and Technical Information (OSTI.GOV)

    Golet, F.C.; Calhoun, A.J.K.; DeRagon, W.R.

    1993-06-01

    In many areas of the glaciated northeastern United States, forested wetlands dominated by red maple (Acer rubrum) cover more of the landscape than all other nontidal wetland types combined. Yet surprisingly little of their ecology, functions, or social significance has been documented. Bogs, salt marshes, Atlantic white cedar swamps, and other less common types of wetlands have received considerable attention from scientists, but, except for botanical surveys, red maple swamps have been largely ignored. The report conveys what is known about these common wetlands and identifies topics most in need of investigation. Red maple swamps are so abundant and somore » widely distributed in the Northeast that their physical, chemical, and biological properties range widely as well, and their values to society are diverse. The central focus of the U.S. Fish and Wildlife Service community profile series is the plant and animal communities of wetlands and deepwater habitats.« less

  14. Layered and scrolled nanocomposites with aligned semi-infinite graphene inclusions at the platelet limit

    NASA Astrophysics Data System (ADS)

    Liu, Pingwei; Jin, Zhong; Katsukis, Georgios; Drahushuk, Lee William; Shimizu, Steven; Shih, Chih-Jen; Wetzel, Eric D.; Taggart-Scarff, Joshua K.; Qing, Bo; Van Vliet, Krystyn J.; Li, Richard; Wardle, Brian L.; Strano, Michael S.

    2016-07-01

    Two-dimensional (2D) materials can uniquely span the physical dimensions of a surrounding composite matrix in the limit of maximum reinforcement. However, the alignment and assembly of continuous 2D components at high volume fraction remain challenging. We use a stacking and folding method to generate aligned graphene/polycarbonate composites with as many as 320 parallel layers spanning 0.032 to 0.11 millimeters in thickness that significantly increases the effective elastic modulus and strength at exceptionally low volume fractions of only 0.082%. An analogous transverse shear scrolling method generates Archimedean spiral fibers that demonstrate exotic, telescoping elongation at break of 110%, or 30 times greater than Kevlar. Both composites retain anisotropic electrical conduction along the graphene planar axis and transparency. These composites promise substantial mechanical reinforcement, electrical, and optical properties at highly reduced volume fraction.

  15. Layered and scrolled nanocomposites with aligned semi-infinite graphene inclusions at the platelet limit.

    PubMed

    Liu, Pingwei; Jin, Zhong; Katsukis, Georgios; Drahushuk, Lee William; Shimizu, Steven; Shih, Chih-Jen; Wetzel, Eric D; Taggart-Scarff, Joshua K; Qing, Bo; Van Vliet, Krystyn J; Li, Richard; Wardle, Brian L; Strano, Michael S

    2016-07-22

    Two-dimensional (2D) materials can uniquely span the physical dimensions of a surrounding composite matrix in the limit of maximum reinforcement. However, the alignment and assembly of continuous 2D components at high volume fraction remain challenging. We use a stacking and folding method to generate aligned graphene/polycarbonate composites with as many as 320 parallel layers spanning 0.032 to 0.11 millimeters in thickness that significantly increases the effective elastic modulus and strength at exceptionally low volume fractions of only 0.082%. An analogous transverse shear scrolling method generates Archimedean spiral fibers that demonstrate exotic, telescoping elongation at break of 110%, or 30 times greater than Kevlar. Both composites retain anisotropic electrical conduction along the graphene planar axis and transparency. These composites promise substantial mechanical reinforcement, electrical, and optical properties at highly reduced volume fraction. Copyright © 2016, American Association for the Advancement of Science.

  16. Synthesis of Composite Adsorbent from Calcium Carbonate and Cocos Nucifera Carbon Powder Crosslinked with Biopolymer Matrix

    NASA Astrophysics Data System (ADS)

    Kamaruddin, M. A.; Bakri, M. M. A.; Norashiddin, F. A.; Zawawi, M. H.; Zainol, M. R. R. A.

    2018-03-01

    The use of coconut shell based adsorbent for removing various pollutants from wastewater offers attractive advantages such as exceptional adsorption capacity with larger surface area, low-cost and biocompatibility for a wide range of pollutants. The same goes for calcium carbonate based adsorbent, which provides better removal for metals ions through precipitation method. In fact, recycling of waste material is considered environmentally preferable and is supported by public opinion and government policy. However, because of unit operations mechanisms and effectiveness are different to one another in downstream process, it is quite difficult to provide good adsorbent that exhibits dual attributes of hydrophobic and hydrophilic characters. This paper provides brief process for sintering of composite adsorbent for separation and purification of industrial wastewater application. Characterization was performed by physical and chemical approach. Results prove that the inclusion of biopolymer as composite binder improved mechanical properties of the composite adsorbent.

  17. High quality thin films of thermoelectric misfit cobalt oxides prepared by a chemical solution method

    PubMed Central

    Rivas-Murias, Beatriz; Manuel Vila-Fungueiriño, José; Rivadulla, Francisco

    2015-01-01

    Misfit cobaltates ([Bi/Ba/Sr/Ca/CoO]nRS[CoO2]q) constitute the most promising family of thermoelectric oxides for high temperature energy harvesting. However, their complex structure and chemical composition makes extremely challenging their deposition by high-vacuum physical techniques. Therefore, many of them have not been prepared as thin films until now. Here we report the synthesis of high-quality epitaxial thin films of the most representative members of this family of compounds by a water-based chemical solution deposition method. The films show an exceptional crystalline quality, with an electrical conductivity and thermopower comparable to single crystals. These properties are linked to the epitaxial matching of the rock-salt layers of the structure to the substrate, producing clean interfaces free of amorphous phases. This is an important step forward for the integration of these materials with complementary n-type thermoelectric oxides in multilayer nanostructures. PMID:26153533

  18. Magnetic Resonance Fingerprinting

    PubMed Central

    Ma, Dan; Gulani, Vikas; Seiberlich, Nicole; Liu, Kecheng; Sunshine, Jeffrey L.; Duerk, Jeffrey L.; Griswold, Mark A.

    2013-01-01

    Summary Magnetic Resonance (MR) is an exceptionally powerful and versatile measurement technique. The basic structure of an MR experiment has remained nearly constant for almost 50 years. Here we introduce a novel paradigm, Magnetic Resonance Fingerprinting (MRF) that permits the non-invasive quantification of multiple important properties of a material or tissue simultaneously through a new approach to data acquisition, post-processing and visualization. MRF provides a new mechanism to quantitatively detect and analyze complex changes that can represent physical alterations of a substance or early indicators of disease. MRF can also be used to specifically identify the presence of a target material or tissue, which will increase the sensitivity, specificity, and speed of an MR study, and potentially lead to new diagnostic testing methodologies. When paired with an appropriate pattern recognition algorithm, MRF inherently suppresses measurement errors and thus can improve accuracy compared to previous approaches. PMID:23486058

  19. Silver Nanoparticles: Technological Advances, Societal Impacts, and Metrological Challenges.

    PubMed

    Calderón-Jiménez, Bryan; Johnson, Monique E; Montoro Bustos, Antonio R; Murphy, Karen E; Winchester, Michael R; Vega Baudrit, José R

    2017-01-01

    Silver nanoparticles (AgNPs) show different physical and chemical properties compared to their macroscale analogs. This is primarily due to their small size and, consequently, the exceptional surface area of these materials. Presently, advances in the synthesis, stabilization, and production of AgNPs have fostered a new generation of commercial products and intensified scientific investigation within the nanotechnology field. The use of AgNPs in commercial products is increasing and impacts on the environment and human health are largely unknown. This article discusses advances in AgNP production and presents an overview of the commercial, societal, and environmental impacts of this emerging nanoparticle (NP), and nanomaterials in general. Finally, we examine the challenges associated with AgNP characterization, discuss the importance of the development of NP reference materials (RMs) and explore their role as a metrological mechanism to improve the quality and comparability of NP measurements.

  20. 36 CFR § 520.4 - Protection of zoo animals.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 36 Parks, Forests, and Public Property 3 2013-07-01 2012-07-01 true Protection of zoo animals. Â... § 520.4 Protection of zoo animals. Except for official purposes, no person shall: (a) Kill, injure, or disturb any exhibit or research animal by any means except to secure personal safety; (b) Pet, attempt to...

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