Science.gov

Sample records for exhaust gas pollutants

  1. 40 CFR 1037.241 - Demonstrating compliance with exhaust emission standards for greenhouse gas pollutants.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... emission standards for greenhouse gas pollutants. 1037.241 Section 1037.241 Protection of Environment... standards for greenhouse gas pollutants. (a) For purposes of certification, your vehicle family is... below the applicable standards. See 40 CFR part 86, subpart S, for showing compliance with the...

  2. 40 CFR 1037.241 - Demonstrating compliance with exhaust emission standards for greenhouse gas pollutants.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... emission standards for greenhouse gas pollutants. 1037.241 Section 1037.241 Protection of Environment... standards for greenhouse gas pollutants. (a) For purposes of certification, your vehicle family is... below the applicable standards. See 40 CFR part 86, subpart S, for showing compliance with the...

  3. 40 CFR 1037.241 - Demonstrating compliance with exhaust emission standards for greenhouse gas pollutants.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... emission standards for greenhouse gas pollutants. 1037.241 Section 1037.241 Protection of Environment... standards for greenhouse gas pollutants. (a) For purposes of certification, your vehicle family is... below the applicable standards. See 40 CFR part 86, subpart S, for showing compliance with the...

  4. Exhaust gas purifying device

    SciTech Connect

    Sakurai, S.; Hamada, S.

    1985-04-23

    An exhaust gas purifying device for use with a diesel engine comprising a filter block disposed in an engine exhaust passage for collecting exhaust gas particulates, and a heater for incinerating the collected exhaust gas particulates. The filter block has parallel channels defined therein and separated from one another by porous partition walls, some of the channels being closed at their inlet ends with blind plugs while the other channels are closed at their outlet ends with blind plugs. The heater is supported by the blind plugs.

  5. Exhaust gas recirculation system

    SciTech Connect

    Minoura, M.; Yorioka, K.

    1980-11-18

    An exhaust gas recirculation system for cleaning exhaust gas from an internal combustion engine is provided in which a variable constriction is provided between an intake pipe and a pressure control valve in operative connection to a throttle valve in the carburetor and the pressure differential across said variable constriction is maintained constant to keep off any influence of the exhaust gas pressure while the ratio of the exhaust gas flow rate to the air intake into the engine is varied in correspondence to the intake pipe negative pressure. This exhaust gas recirculation system can be adapted to a fuel injection type intake system as well as other intake systems provided with an air valve for regulating air intake or having no venturi constriction such as employed in an su type carburetor.

  6. Exhaust gas purification device

    SciTech Connect

    Fujiwara, H.; Hibi, T.; Sayo, S.; Sugiura, Y.; Ueda, K.

    1980-02-19

    The exhaust gas purification device includes an exhaust manifold , a purification cylinder connected with the exhaust manifold through a first honey-comb shaped catalyst, and a second honeycomb shaped catalyst positioned at the rear portion of the purification cylinder. Each catalyst is supported by steel wool rings including coarse and dense portions of steel wool. The purification device further includes a secondary air supplying arrangement.

  7. Exhaust gas recirculator

    SciTech Connect

    Suda, K.

    1983-01-04

    An exhaust gas recirculator for an internal combustion engine having an exhaust pipe, an intake manifold and a carburetor throttle valve. The exhaust gas recirculator comprises an egr passage which makes the exhaust pipe communicate with the intake manifold, an egr controlling valve and an egr valve respectively arranged in the upper and lower portions of the egr passage. The egr valve operates in association with the carburetor throttle valve for metering the flow of egr gas. The egr controlling valve is separated by a diaphragm into an egr gas chamber communicating with the egr passage between the egr controlling valve and the egr valve and a negative pressure chamber communicating with the intake manifold. The negative pressure chamber contains a compression spring, and the diaphragm is connected with a valve member through a rod upon which is disposed a stopper to serve as a different seal in place of the valve member to close off the exhaust gas passage, which valve member and stopper are constructed to be opened and closed by pressure difference between the egr gas chamber and the negative pressure chamber and by elastic force of the compression spring. The egr controlling valve functions to control the pressure difference around the egr valve to be constant.

  8. Ship exhaust gas plume cooling

    NASA Astrophysics Data System (ADS)

    Schleijpen, H. M. A.; Neele, Filip P.

    2004-08-01

    The exhaust gas plume is an important and sometimes dominating contributor to the infrared signature of ships. Suppression of the infrared ship signatures has been studied by TNO for the Royal Netherlands Navy over considerable time. This study deals with the suppression effects, which can be achieved using a spray of cold water in the inner parts of the exhaust system. The effects are compared with the effect of cooling with air. A typical frigate size diesel engine serves as an example for gas flow, composition and temperature of the plume. The infrared emission of the cooled an un-cooled exhaust gases is calculated. Both the spectral behaviour and the integrated values over typical bands are discussed. Apart from the signature also some advantages of water exhaust gas cooling for the ship design are discussed.

  9. 40 CFR 1065.127 - Exhaust gas recirculation.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 33 2011-07-01 2011-07-01 false Exhaust gas recirculation. 1065.127 Section 1065.127 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Equipment Specifications § 1065.127 Exhaust gas recirculation. Use...

  10. 40 CFR 1065.127 - Exhaust gas recirculation.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Exhaust gas recirculation. 1065.127 Section 1065.127 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Equipment Specifications § 1065.127 Exhaust gas recirculation. Use...

  11. 40 CFR 1065.127 - Exhaust gas recirculation.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 33 2014-07-01 2014-07-01 false Exhaust gas recirculation. 1065.127 Section 1065.127 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Equipment Specifications § 1065.127 Exhaust gas recirculation. Use...

  12. 40 CFR 1065.127 - Exhaust gas recirculation.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 34 2013-07-01 2013-07-01 false Exhaust gas recirculation. 1065.127 Section 1065.127 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Equipment Specifications § 1065.127 Exhaust gas recirculation. Use...

  13. 40 CFR 1065.127 - Exhaust gas recirculation.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 34 2012-07-01 2012-07-01 false Exhaust gas recirculation. 1065.127 Section 1065.127 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Equipment Specifications § 1065.127 Exhaust gas recirculation. Use...

  14. High speed exhaust gas recirculation valve

    DOEpatents

    Fensom, Rod; Kidder, David J.

    2005-01-18

    In order to minimize pollutants such as Nox, internal combustion engines typically include an exhaust gas recirculation (EGR) valve that can be used to redirect a portion of exhaust gases to an intake conduit, such as an intake manifold, so that the redirected exhaust gases will be recycled. It is desirable to have an EGR valve with fast-acting capabilities, and it is also desirable to have the EGR valve take up as little space as possible. An exhaust gas recirculation valve is provided that includes an exhaust passage tube, a valve element pivotally mounted within the exhaust passage tube, a linear actuator; and a gear train. The gear train includes a rack gear operatively connected to the linear actuator, and at least one rotatable gear meshing with the rack gear and operatively connected to the valve element to cause rotation of the valve element upon actuation of the linear actuator. The apparatus provides a highly compact package having a high-speed valve actuation capability.

  15. System for Removing Pollutants from Incinerator Exhaust

    NASA Technical Reports Server (NTRS)

    Wickham, David t.; Bahr, James; Dubovik, Rita; Gebhard, Steven C.; Lind, Jeffrey

    2008-01-01

    A system for removing pollutants -- primarily sulfur dioxide and mixed oxides of nitrogen (NOx) -- from incinerator exhaust has been demonstrated. The system is also designed secondarily to remove particles, hydrocarbons, and CO. The system is intended for use in an enclosed environment, for which a prior NOx-and-SO2-removal system designed for industrial settings would not be suitable.

  16. Exhaust gas clean up process

    DOEpatents

    Walker, R.J.

    1988-06-16

    A method of cleaning an exhaust gas containing particulates, SO/sub 2/ and NO/sub x/ is described. The method involves prescrubbing with water to remove HCl and most of the particulates, scrubbing with an aqueous absorbent containing a metal chelate and dissolved sulfite salt to remove NO/sub x/ and SO/sub 2/, and regenerating the absorbent solution by controlled heating, electrodialysis and carbonate salt addition. The NO/sub x/ is removed as N/sub 2/ gas or nitrogen sulfonate ions and the oxides of sulfur are removed as a valuable sulfate salt. 4 figs.

  17. Turbocharged engine exhaust gas recirculation system

    SciTech Connect

    Stachowicz, R.W.

    1984-01-24

    Improved exhaust gas recirculation systems for turbocharged gas engines that include an exhaust pipe, a turbocharger connected thereto, and a carburetor connected with a source of gas for the engine. The recirculation system includes an air conduit extending from the turbocharger compressor discharge to a venturi, an exhaust gas conduit that extends from a connection with the exhaust pipe between the engine and the turbocharger to the venturi, a second air conduit that extends from the exhaust pipe to a connection with the first air conduit, and control valves located in the exhaust gas conduit and in the second air conduit. The valves are closed when the engine is being started or idling at no load and open when a load is imposed or when engine rpm's are increased. No pumps, blowers, etc. are needed because the system operates on a differential in pressure created within the system to cause the exhaust gas recirculation.

  18. Exhaust gas recirculation control system

    SciTech Connect

    Yamada, K.

    1981-02-03

    An E.G.R. control system includes a pressure modulator operative to modulate the magnitude of the port vacuum as applied to a diaphragm type actuator of an E.G.R. valve. The modulator comprises a housing and a diaphragm assembly disposed in the housing and consisting of a pair of diaphragms and a member connecting the diaphragms so that they are deformed simultaneously. The diaphragm assembly divides the interior of the housing into first, second and third chambers which are communicated with the engine carburetor venturi, vented to the atmosphere and communicated with the E.G.R. passage between the E.G.R. valve and a fixed restriction in the E.G.R. passage upstream of the E.G.R. valve, respectively, so that the diaphragm assembly is moved in response to variation in the venturi vacuum and also in response to variation in the exhaust gas pressure in the E.G.R. passage between the restriction and the E.G.R. valve. A valve member is mounted on the diaphragm assembly for movement therewith to control the flow of the atmospheric air from the second chamber into the E.G.R. valve actuator so that the port vacuum as applied to the E.G.R. valve actuator is modulated. The controlled flow of the recirculated exhaust gases through the E.G.R. passage from the exhaust pipe into the intake pipe is in proportion to the intake air flow.

  19. Exhaust gas clean up process

    DOEpatents

    Walker, Richard J.

    1989-01-01

    A method of cleaning an exhaust gas containing particulates, SO.sub.2 and NO.sub.x includes prescrubbing with water to remove HCl and most of the particulates, scrubbing with an aqueous absorbent containing a metal chelate and dissolved sulfite salt to remove NO.sub.x and SO.sub.2, and regenerating the absorbent solution by controlled heating, electrodialysis and carbonate salt addition. The NO.sub.x is removed as N.sub.2 or nitrogen-sulfonate ions and the oxides of sulfur are removed as a vaulable sulfate salt.

  20. Apparatus for totally recycling engine exhaust gas

    SciTech Connect

    Suzuki, N.

    1986-05-13

    A method is described of burning fuel in the combustion chamber of an engine using an apparatus of the type which comprises an electrostatic precipitator connected to the exhaust manifold of the engine; a dissociation chamber connected to the electrostatic precipitator and to the intake manifold of the engine and including a dissociated gas control reservoir connected to the dissociation chamber and to the engine intake manifold; and a cyclone drum connected to the electrostatic precipitator for removing particles from the exhaust gases in the electrostatic precipitator. The method consists of: dissociating the molecules of the exhaust gas from the engine in the dissociation chamber into monomolecules by subjecting the exhaust gas to the effects of a corona discharge in the dissociation chamber; removing carbon and other particulate matter from the exhaust in the electrostatic precipitator and cyclone drum to dedust the exhaust gas; and igniting a mixture of fuel and the dedusted exhaust gas in the combustion chamber of the engine, whereby fuel is initially oxidized solely by an oxygen component of the dissociated exhaust gas.

  1. Exhaust gas recirculation system for an internal combustion engine

    DOEpatents

    Wu, Ko-Jen

    2013-05-21

    An exhaust gas recirculation system for an internal combustion engine comprises an exhaust driven turbocharger having a low pressure turbine outlet in fluid communication with an exhaust gas conduit. The turbocharger also includes a low pressure compressor intake and a high pressure compressor outlet in communication with an intake air conduit. An exhaust gas recirculation conduit fluidly communicates with the exhaust gas conduit to divert a portion of exhaust gas to a low pressure exhaust gas recirculation branch extending between the exhaust gas recirculation conduit and an engine intake system for delivery of exhaust gas thereto. A high pressure exhaust gas recirculation branch extends between the exhaust gas recirculation conduit and the compressor intake and delivers exhaust gas to the compressor for mixing with a compressed intake charge for delivery to the intake system.

  2. Gas exhaust nozzle for ARC furnaces

    SciTech Connect

    Buhler, K.

    1984-10-09

    Arc furnace has a furnace shell, a furnace lid with lid ring and a lid lifting and swivelling means as well as a lid opening in the furnace lid for exhausting the flue gas from the interior of the furnace and a flue gas exhaust nozzle for removing the flue gases above the lid opening, the nozzle being supported on the furnace lid ring. By means of this design feature as well as a guide arrangement and a locking means the flue gas exhaust nozzle can be completely integrated into the operating steps of the arc furnace in a simple and economical fashion.

  3. 46 CFR 52.25-20 - Exhaust gas boilers.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Exhaust gas boilers. 52.25-20 Section 52.25-20 Shipping... Types § 52.25-20 Exhaust gas boilers. Exhaust gas boilers with a maximum allowable working pressure... part. The design temperature of parts exposed to the exhaust gas must be the maximum temperature...

  4. 40 CFR 89.416 - Raw exhaust gas flow.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 20 2014-07-01 2013-07-01 true Raw exhaust gas flow. 89.416 Section 89... Procedures § 89.416 Raw exhaust gas flow. The exhaust gas flow shall be determined by one of the methods... procedure has been incorporated by reference. See § 89.6.) and calculation of the exhaust gas flow...

  5. 46 CFR 52.25-20 - Exhaust gas boilers.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 2 2011-10-01 2011-10-01 false Exhaust gas boilers. 52.25-20 Section 52.25-20 Shipping... Types § 52.25-20 Exhaust gas boilers. Exhaust gas boilers with a maximum allowable working pressure... part. The design temperature of parts exposed to the exhaust gas must be the maximum temperature...

  6. 46 CFR 52.25-20 - Exhaust gas boilers.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 2 2012-10-01 2012-10-01 false Exhaust gas boilers. 52.25-20 Section 52.25-20 Shipping... Types § 52.25-20 Exhaust gas boilers. Exhaust gas boilers with a maximum allowable working pressure... part. The design temperature of parts exposed to the exhaust gas must be the maximum temperature...

  7. 46 CFR 52.25-20 - Exhaust gas boilers.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 2 2014-10-01 2014-10-01 false Exhaust gas boilers. 52.25-20 Section 52.25-20 Shipping... Types § 52.25-20 Exhaust gas boilers. Exhaust gas boilers with a maximum allowable working pressure... part. The design temperature of parts exposed to the exhaust gas must be the maximum temperature...

  8. 40 CFR 89.416 - Raw exhaust gas flow.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw exhaust gas flow. 89.416 Section... Procedures § 89.416 Raw exhaust gas flow. The exhaust gas flow shall be determined by one of the methods... procedure has been incorporated by reference. See § 89.6.) and calculation of the exhaust gas flow...

  9. 46 CFR 52.25-20 - Exhaust gas boilers.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 2 2013-10-01 2013-10-01 false Exhaust gas boilers. 52.25-20 Section 52.25-20 Shipping... Types § 52.25-20 Exhaust gas boilers. Exhaust gas boilers with a maximum allowable working pressure... part. The design temperature of parts exposed to the exhaust gas must be the maximum temperature...

  10. 40 CFR 89.416 - Raw exhaust gas flow.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 21 2012-07-01 2012-07-01 false Raw exhaust gas flow. 89.416 Section... Procedures § 89.416 Raw exhaust gas flow. The exhaust gas flow shall be determined by one of the methods... procedure has been incorporated by reference. See § 89.6.) and calculation of the exhaust gas flow...

  11. 40 CFR 86.509-90 - Exhaust gas sampling system.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Exhaust gas sampling system. 86.509-90... 1978 and Later New Motorcycles; Test Procedures § 86.509-90 Exhaust gas sampling system. (a)(1) General. The exhaust gas sampling system is designed to measure the true mass emissions of vehicle exhaust....

  12. Reducing exhaust gas emissions from Citydiesel busses

    NASA Astrophysics Data System (ADS)

    Mikkonen, Seppo

    The effect of fuel composition and exhaust gas aftertreatment on the emissions was measured from truck and bus engines. Possibilities to measure unregulated emissions (aldehydes, polyaromatic hydrocarbons, mutagenicity) were built. A reformulated diesel fuel 'Citydiesel' was developed. Citydiesel was able to reduce emissions compared to standard diesel fuel as follows: particulates by 10 to 30%, nitrogen oxides by 2 to 10%, sulphur dioxide by 97%, polyaromatic hydrocarbons (PAH) over 50%, mutagenicity of the exhaust particulates clearly, odor of the exhaust, and smoke after a cold start. The use of Citydiesel fuel reduces emissions of the existing vehicles immediately which is a remarkable benefit. The very low sulphur content (below 50 ppm) makes it possible to use oxidation. catalytic converters to reduce emissions of diesel vehicles. The new Euro 2 exhaust regulations coming into force during 1996 can be met with a modern diesel engine, Citydiesel fuel, and exhaust gas aftertreatment. Properties of Citydiesel fuel were verified in a three year field test with 140 city buses. Experience was good; e.g., engine oil change interval could be lengthened. Total value of the exhaust was estimated with different fuels and aftertreatment device in order to find out cheap ways to reduce emissions.

  13. Exhaust gas turbocharger for diesel engines

    SciTech Connect

    Regar, K.N.

    1982-01-26

    An exhaust gas turbocharger is described for a diesel engine, the turbocharger including a compressor, an exhaust gas turbine, and a shaft joining the compressor and turbine. A flywheel is mounted on another shaft, and a device, such as a freewheel, alternatively couples and uncouples the flywheel shaft and turbocharger shaft. The flywheel shaft is in two sections, and a summation mechanism, such as a planetary gear arrangement, is between the two shaft sections. The summation mechanism is controlled by a hydrostatic device and/or an electronic device. A brake is provided for selectively preventing rotation of the flywheel shaft section between the summation mechanism and the turbocharger shaft.

  14. SST-1 Gas feed and Gas Exhaust system

    NASA Astrophysics Data System (ADS)

    Raval, Dilip C.; Khan, Ziauddin; Thankey, Prashant L.; Dhanani, Kalpesh R.; Pathan, Firozkhan S.; Semwal, Pratibha; George, Siju; Yuvakiran, Paravastu; Manthena, Himabindu; Pradhan, Subrata

    2012-11-01

    SST-1 tokamak is a long pulse tokamak designed for the plasma operation up to 1000 sec duration. Gas feed system and gas exhaust management will play a very crucial role during plasma discharge. During the different type of operations of tokamak like wall conditioning, diverter operation and neutral beam injection, a large amount of gas will be fed into the vacuum chamber at different locations. Also during plasma operations, the gas will be fed both in continues and pulse mode. Gas feed will be carried out mainly using piezo-electric valves controlled by PXI based data acquisition and control system. Such operations will lead to a huge amount gas exhaust by the main system which requires good exhaust facility to searches, great care should be taken in constructing both. Also initial pumping of cryostat and vacuum vessel of SST-1 will release a large amount of gas. Exhausted gases from SST -1 will be Hydrogen, Nitrogen, Mixture gases or some toxic gases. Dedicated exhaust system controlling the different gases are installed. Special treatment of hazardous/explosive gases is done before releasing to the atmosphere. This paper describes design and implementations of the complete gas feed and exhaust system of SST-1.

  15. Reduction of Fuel Consumption and Exhaust Pollutant Using Intelligent Transport Systems

    PubMed Central

    Nasir, Mostofa Kamal; Md Noor, Rafidah; Kalam, M. A.; Masum, B. M.

    2014-01-01

    Greenhouse gas emitted by the transport sector around the world is a serious issue of concern. To minimize such emission the automobile engineers have been working relentlessly. Researchers have been trying hard to switch fossil fuel to alternative fuels and attempting to various driving strategies to make traffic flow smooth and to reduce traffic congestion and emission of greenhouse gas. Automobile emits a massive amount of pollutants such as Carbon Monoxide (CO), hydrocarbons (HC), carbon dioxide (CO2), particulate matter (PM), and oxides of nitrogen (NOx). Intelligent transport system (ITS) technologies can be implemented to lower pollutant emissions and reduction of fuel consumption. This paper investigates the ITS techniques and technologies for the reduction of fuel consumption and minimization of the exhaust pollutant. It highlights the environmental impact of the ITS application to provide the state-of-art green solution. A case study also advocates that ITS technology reduces fuel consumption and exhaust pollutant in the urban environment. PMID:25032239

  16. Reduction of fuel consumption and exhaust pollutant using intelligent transport systems.

    PubMed

    Nasir, Mostofa Kamal; Md Noor, Rafidah; Kalam, M A; Masum, B M

    2014-01-01

    Greenhouse gas emitted by the transport sector around the world is a serious issue of concern. To minimize such emission the automobile engineers have been working relentlessly. Researchers have been trying hard to switch fossil fuel to alternative fuels and attempting to various driving strategies to make traffic flow smooth and to reduce traffic congestion and emission of greenhouse gas. Automobile emits a massive amount of pollutants such as Carbon Monoxide (CO), hydrocarbons (HC), carbon dioxide (CO2), particulate matter (PM), and oxides of nitrogen (NO x ). Intelligent transport system (ITS) technologies can be implemented to lower pollutant emissions and reduction of fuel consumption. This paper investigates the ITS techniques and technologies for the reduction of fuel consumption and minimization of the exhaust pollutant. It highlights the environmental impact of the ITS application to provide the state-of-art green solution. A case study also advocates that ITS technology reduces fuel consumption and exhaust pollutant in the urban environment.

  17. Reduction of fuel consumption and exhaust pollutant using intelligent transport systems.

    PubMed

    Nasir, Mostofa Kamal; Md Noor, Rafidah; Kalam, M A; Masum, B M

    2014-01-01

    Greenhouse gas emitted by the transport sector around the world is a serious issue of concern. To minimize such emission the automobile engineers have been working relentlessly. Researchers have been trying hard to switch fossil fuel to alternative fuels and attempting to various driving strategies to make traffic flow smooth and to reduce traffic congestion and emission of greenhouse gas. Automobile emits a massive amount of pollutants such as Carbon Monoxide (CO), hydrocarbons (HC), carbon dioxide (CO2), particulate matter (PM), and oxides of nitrogen (NO x ). Intelligent transport system (ITS) technologies can be implemented to lower pollutant emissions and reduction of fuel consumption. This paper investigates the ITS techniques and technologies for the reduction of fuel consumption and minimization of the exhaust pollutant. It highlights the environmental impact of the ITS application to provide the state-of-art green solution. A case study also advocates that ITS technology reduces fuel consumption and exhaust pollutant in the urban environment. PMID:25032239

  18. The Effects of Diesel Exhaust Pollution on Floral Volatiles and the Consequences for Honey Bee Olfaction.

    PubMed

    Lusebrink, Inka; Girling, Robbie D; Farthing, Emily; Newman, Tracey A; Jackson, Chris W; Poppy, Guy M

    2015-10-01

    There is growing evidence of a substantial decline in pollinators within Europe and North America, most likely caused by multiple factors such as diseases, poor nutrition, habitat loss, insecticides, and environmental pollution. Diesel exhaust could be a contributing factor to this decline, since we found that diesel exhaust rapidly degrades floral volatiles, which honey bees require for flower recognition. In this study, we exposed eight of the most common floral volatiles to diesel exhaust in order to investigate whether it can affect volatile mediated plant-pollinator interaction. Exposure to diesel exhaust altered the blend of common flower volatiles significantly: myrcene was considerably reduced, β-ocimene became undetectable, and β-caryophyllene was transformed into its cis-isomer isocaryophyllene. Proboscis extension response (PER) assays showed that the alterations of the blend reduced the ability of honey bees to recognize it. The chemically reactive nitrogen oxides fraction of diesel exhaust gas was identified as capable of causing degradation of floral volatiles.

  19. Diesel exhaust-gas purification system

    SciTech Connect

    Doherty, B.J.

    1982-07-01

    The design of a diesel exhaust gas purification system is presented. It will provide 2000 scfm of dry, anerobic gas (essentially nitrogen) for use in air drilling operations where drill pipe corrosion is a problem, such as geothermal applications. The system is operable in the field and may be transported via highways. It will operate at ambient temperatures up to 110/sup 0/F and requires no water - diesel fuel is used to combust excess oxygen and to generate electricity for the system. Gas production costs, including capital amortization, operations, fuel and maintenance (for reasonable utilization) are about $1.50/1000 scf.

  20. 30 CFR 36.26 - Composition of exhaust gas.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Composition of exhaust gas. 36.26 Section 36.26... EQUIPMENT Construction and Design Requirements § 36.26 Composition of exhaust gas. (a) Preliminary engine... the engine shall be adjusted so that the undiluted exhaust gas shall contain not more than...

  1. 40 CFR 86.211-94 - Exhaust gas analytical system.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Exhaust gas analytical system. 86.211... New Medium-Duty Passenger Vehicles; Cold Temperature Test Procedures § 86.211-94 Exhaust gas... optional. The exhaust gas analytical system must contain components necessary to determine...

  2. 46 CFR 63.25-7 - Exhaust gas boilers.

    Code of Federal Regulations, 2011 CFR

    2011-10-01

    ... 46 Shipping 2 2011-10-01 2011-10-01 false Exhaust gas boilers. 63.25-7 Section 63.25-7 Shipping... Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-7 Exhaust gas boilers. (a) Construction. An auxiliary exhaust gas boiler must meet the applicable construction requirements of part 52 or...

  3. 46 CFR 63.25-7 - Exhaust gas boilers.

    Code of Federal Regulations, 2014 CFR

    2014-10-01

    ... 46 Shipping 2 2014-10-01 2014-10-01 false Exhaust gas boilers. 63.25-7 Section 63.25-7 Shipping... Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-7 Exhaust gas boilers. (a) Construction. An auxiliary exhaust gas boiler must meet the applicable construction requirements of part 52 or...

  4. 40 CFR 86.511-90 - Exhaust gas analytical system.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Exhaust gas analytical system. 86.511... Regulations for 1978 and Later New Motorcycles; Test Procedures § 86.511-90 Exhaust gas analytical system. (a) Schematic drawings. Figure F90-3 is a schematic drawing of the exhaust gas analytical system for analysis...

  5. 46 CFR 63.25-7 - Exhaust gas boilers.

    Code of Federal Regulations, 2012 CFR

    2012-10-01

    ... 46 Shipping 2 2012-10-01 2012-10-01 false Exhaust gas boilers. 63.25-7 Section 63.25-7 Shipping... Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-7 Exhaust gas boilers. (a) Construction. An auxiliary exhaust gas boiler must meet the applicable construction requirements of part 52 or...

  6. 30 CFR 36.26 - Composition of exhaust gas.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Composition of exhaust gas. 36.26 Section 36.26... EQUIPMENT Construction and Design Requirements § 36.26 Composition of exhaust gas. (a) Preliminary engine... the engine shall be adjusted so that the undiluted exhaust gas shall contain not more than...

  7. 46 CFR 63.25-7 - Exhaust gas boilers.

    Code of Federal Regulations, 2013 CFR

    2013-10-01

    ... 46 Shipping 2 2013-10-01 2013-10-01 false Exhaust gas boilers. 63.25-7 Section 63.25-7 Shipping... Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-7 Exhaust gas boilers. (a) Construction. An auxiliary exhaust gas boiler must meet the applicable construction requirements of part 52 or...

  8. 46 CFR 63.25-7 - Exhaust gas boilers.

    Code of Federal Regulations, 2010 CFR

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Exhaust gas boilers. 63.25-7 Section 63.25-7 Shipping... Requirements for Specific Types of Automatic Auxiliary Boilers § 63.25-7 Exhaust gas boilers. (a) Construction. An auxiliary exhaust gas boiler must meet the applicable construction requirements of part 52 or...

  9. 30 CFR 36.26 - Composition of exhaust gas.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Composition of exhaust gas. 36.26 Section 36.26... EQUIPMENT Construction and Design Requirements § 36.26 Composition of exhaust gas. (a) Preliminary engine... the engine shall be adjusted so that the undiluted exhaust gas shall contain not more than...

  10. 40 CFR 89.416 - Raw exhaust gas flow.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 21 2013-07-01 2013-07-01 false Raw exhaust gas flow. 89.416 Section... Procedures § 89.416 Raw exhaust gas flow. The exhaust gas flow shall be determined by one of the methods...) Measurement of the air flow and the fuel flow by suitable metering systems (for details see SAE J244....

  11. Parametric modeling of exhaust gas emission from natural gas fired gas turbines

    SciTech Connect

    Bakken, L.E.; Skogly, L.

    1996-07-01

    Increased focus on air pollution from gas turbines in the Norwegian sector of the North Sea has resulted in taxes on CO{sub 2}. Statements made by the Norwegian authorities imply regulations and/or taxes on NO{sub x} emissions in the near future. The existing CO{sub 2} tax of NOK 0.82/Sm{sup 3} (US Dollars 0.12/Sm{sup 3}) and possible future tax on NO{sub x} are analyzed mainly with respect to operating and maintenance costs for the gas turbine. Depending on actual tax levels, the machine should be operated on full load/optimum thermal efficiency or part load to reduce specific exhaust emissions. Based on field measurements, exhaust emissions (CO{sub 2}, CO, NO{sub x}, N{sub 2}O, UHC, etc.) are established with respect to load and gas turbine performance, including performance degradation. Different NO{sub x} emission correlations are analyzed based on test results, and a proposed prediction model presented. The impact of machinery performance degradation on emission levels is particularly analyzed. Good agreement is achieved between measured and predicted NO{sub x} emissions from the proposed correlation. To achieve continuous exhaust emission control, the proposed NO{sub x} model is implemented to the on-line condition monitoring system on the Sleipner A platform, rather than introducing sensitive emission sensors in the exhaust gas stack. The on-line condition monitoring system forms an important tool in detecting machinery condition/degradation and air pollution, and achieving optimum energy conservation.

  12. Boosting devices with integral features for recirculating exhaust gas

    SciTech Connect

    Wu, Ko-Jen

    2015-12-22

    According to one embodiment of the invention, a turbine housing includes a turbine inlet in fluid communication with a turbine volute configured to house a turbine wheel, the turbine inlet configured to direct an exhaust gas flow from an engine to the turbine wheel. The turbine housing also includes a turbine outlet in fluid communication with the turbine volute, the turbine outlet configured to direct the exhaust gas flow to an exhaust gas conduit and a first exhaust gas recirculation supply port located on and in fluid communication with the turbine outlet, the first exhaust gas recirculation supply port being configured to direct a portion of the exhaust gas flow to an exhaust gas recirculation supply conduit.

  13. 30 CFR 70.1900 - Exhaust Gas Monitoring.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Director of the Federal Register in accordance with 5 U.S.C. 552(a) and 1 CFR part 51. In addition, copies... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Exhaust Gas Monitoring. 70.1900 Section 70.1900... MANDATORY HEALTH STANDARDS-UNDERGROUND COAL MINES Diesel Exhaust Gas Monitoring § 70.1900 Exhaust...

  14. 30 CFR 70.1900 - Exhaust Gas Monitoring.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... Director of the Federal Register in accordance with 5 U.S.C. 552(a) and 1 CFR part 51. In addition, copies... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Exhaust Gas Monitoring. 70.1900 Section 70.1900... MANDATORY HEALTH STANDARDS-UNDERGROUND COAL MINES DIESEL EXHAUST GAS MONITORING § 70.1900 Exhaust...

  15. 40 CFR 89.416 - Raw exhaust gas flow.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw exhaust gas flow. 89.416 Section 89.416 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE NONROAD COMPRESSION-IGNITION ENGINES Exhaust Emission Test Procedures § 89.416 Raw exhaust gas flow....

  16. Internal combustion engine with an exhaust gas turbocharger

    SciTech Connect

    Hiereth, H.; Withalm, G.

    1981-06-09

    An internal combustion engine with an exhaust-gas turbocharger, particularly a mixture-compressing internal combustion engine, is disclosed in which a bleeder valve is provided which during the operation of the internal combustion engine in the partial load range conducts the exhaust gases in bypassing relationship to the turbine of the exhaust gas turbocharger.

  17. Device for controlling supercharging pressure of an exhaust gas turbocharger

    SciTech Connect

    Iwasa, Y.

    1988-04-12

    A supercharge pressure control apparatus is described comprising: a turbocharger having an exhaust turbine rotated by exhaust gas flow of an internal combustion engine and a compressor rotated by the exhaust gas flow toward the turbine and having a valve member disposed in the turbine.

  18. 30 CFR 70.1900 - Exhaust Gas Monitoring.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Exhaust Gas Monitoring. 70.1900 Section 70.1900 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY HEALTH STANDARDS-UNDERGROUND COAL MINES DIESEL EXHAUST GAS MONITORING § 70.1900 Exhaust...

  19. 30 CFR 70.1900 - Exhaust Gas Monitoring.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Exhaust Gas Monitoring. 70.1900 Section 70.1900 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY HEALTH STANDARDS-UNDERGROUND COAL MINES DIESEL EXHAUST GAS MONITORING § 70.1900 Exhaust...

  20. 30 CFR 70.1900 - Exhaust Gas Monitoring.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Exhaust Gas Monitoring. 70.1900 Section 70.1900 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR COAL MINE SAFETY AND HEALTH MANDATORY HEALTH STANDARDS-UNDERGROUND COAL MINES Diesel Exhaust Gas Monitoring § 70.1900 Exhaust...

  1. Interrelation of exhaust-gas constituents

    NASA Technical Reports Server (NTRS)

    Gerrish, Harold C; Voss, Fred

    1938-01-01

    This report presents the results of an investigation conducted to determine the interrelation of the constituents of the exhaust gases of internal-combustion engines and the effect of engine performance on these relations. Six single-cylinder, liquid-cooled tests engines and one 9-cylinder radial air-cooled engine were tested. Various types of combustion chambers were used and the engines were operated at compression ratios from 5.1 to 7.0 using spark ignition and from 13.5 to 15.6 using compression ignition. The investigation covered a range of engine speeds from 1,500 to 2,100 r.p.m. The fuels used were two grades of aviation gasoline, auto diesel fuel, and laboratory diesel fuel. Power, friction, and fuel-consumption data were obtained from the single-cylinder engines at the same time that the exhaust-gas samples were collected.

  2. Exhaust gas recirculation in a homogeneous charge compression ignition engine

    DOEpatents

    Duffy, Kevin P.; Kieser, Andrew J.; Rodman, Anthony; Liechty, Michael P.; Hergart, Carl-Anders; Hardy, William L.

    2008-05-27

    A homogeneous charge compression ignition engine operates by injecting liquid fuel directly in a combustion chamber, and mixing the fuel with recirculated exhaust and fresh air through an auto ignition condition of the fuel. The engine includes at least one turbocharger for extracting energy from the engine exhaust and using that energy to boost intake pressure of recirculated exhaust gas and fresh air. Elevated proportions of exhaust gas recirculated to the engine are attained by throttling the fresh air inlet supply. These elevated exhaust gas recirculation rates allow the HCCI engine to be operated at higher speeds and loads rendering the HCCI engine a more viable alternative to a conventional diesel engine.

  3. Numerical simulation of the pollution formed by exhaust jets at the ground running procedure

    NASA Astrophysics Data System (ADS)

    Korotaeva, T. A.; Turchinovich, A. O.

    2016-10-01

    The paper presents an approach that is new for aviation-related ecology. The approach allows defining spatial distribution of pollutant concentrations released at engine ground running procedure (GRP) using full gas-dynamic models. For the first time such a task is modeled in three-dimensional approximation in the framework of the numerical solution of the Navier-Stokes equations with taking into account a kinetic model of interaction between the components of engine exhaust and air. The complex pattern of gas-dynamic flow that occurs at the flow around an aircraft with the jet exhausts that interact with each other, air, jet blast deflector (JBD), and surface of the airplane has been studied in the present work. The numerical technique developed for calculating the concentrations of pollutants produced at the GRP stage permits to define level, character, and area of contamination more reliable and increase accuracy in definition of sanitary protection zones.

  4. Real-time exhaust gas modular flowmeter and emissions reporting system for mobile apparatus

    NASA Technical Reports Server (NTRS)

    Breton, Leo Alphonse Gerard (Inventor)

    2002-01-01

    A real-time emissions reporting system includes an instrument module adapted to be detachably connected to the exhaust pipe of a combustion engine to provide for flow of exhaust gas therethrough. The instrument module includes a differential pressure probe which allows for determination of flow rate of the exhaust gas and a gas sampling tube for continuously feeding a sample of the exhaust gas to a gas analyzer or a mounting location for a non-sampling gas analyzer. In addition to the module, the emissions reporting system also includes an elastomeric boot for detachably connecting the module to the exhaust pipe of the combustion engine, a gas analyzer for receiving and analyzing gases sampled within the module and a computer for calculating pollutant mass flow rates based on concentrations detected by the gas analyzer and the detected flowrate of the exhaust gas. The system may also include a particulate matter detector with a second gas sampling tube feeding same mounted within the instrument module.

  5. Short review on heat recovery from exhaust gas

    NASA Astrophysics Data System (ADS)

    Jaber, Hassan; Khaled, Mahmoud; Lemenand, Thierry; Ramadan, Mohamad

    2016-07-01

    The increasing growth of energy demand leads to issues associated with energy demand reduction and propose new energy efficient solutions. Heat recovery consists the most promising solution especially in regions where renewable energy resources are not available. That is why the domain of heat recovery has shown a tremendous improvement during the recent years. On the other hand, few works have been dedicated to heat recovery from exhaust gas. This paper presents a review on heat recovery from exhaust gas. The authors propose to classify exhaust gas heat recovery systems within three different classifications that are exhaust gas temperature, utilized equipment and recovery purposes.

  6. Subsonic Jet Noise Reduced With Improved Internal Exhaust Gas Mixers

    NASA Technical Reports Server (NTRS)

    1996-01-01

    Aircraft noise pollution is becoming a major environmental concern for the world community. The Federal Aviation Administration (FAA) is responding to this concern by imposing more stringent noise restrictions for aircraft certification then ever before to keep the U.S. industry competitive with the rest of the world. At the NASA Lewis Research Center, attempts are underway to develop noise-reduction technology for newer engines and for retrofitting existing engines so that they are as quiet as (or quieter than) required. Lewis conducted acoustic and Laser Doppler Velocimetry (LDV) tests using Pratt & Whitney's Internal Exhaust Gas Mixers (IEGM). The IEGM's mix the core flow with the fan flow prior to their common exhaust. All tests were conducted in Lewis' Aero-Acoustic Propulsion Laboratory--a semihemispheric dome open to the ambient atmosphere. This was the first time Laser Doppler Velocimetry was used in such a facility at Lewis. Jet exhaust velocity and turbulence and the internal velocity fields were detailed. Far-field acoustics were also measured. Pratt & Whitney provided 1/7th scale model test hardware (a 12-lobe mixer, a 20-lobe mixer, and a splitter) for 1.7 bypass ratio engines, and NASA provided the research engineers, test facility, and test time. The Pratt & Whitney JT8D-200 engine power conditions were used for all tests.

  7. Pollutant Removal Efficiency of Residential Cooking Exhaust Hoods

    SciTech Connect

    Singer, Brett C.; Sherman, Alexander D.; Hotchi, Toshifumi; Sullivan, Douglas P.

    2011-07-01

    Capture efficiency (CE) of exhaust from a natural gas cooking range was quantified for three common designs of residential range hoods in laboratory experiments: (A) microwave exhaust combination; (B) short hood with grease-screen-covered air inlet at bottom; and (C) deep, open hood exhausting at top. Devices were evaluated at varying installation heights, at highest and lowest fan settings, and with the hood installed 15 cm away from back wall with intent to improve CE for front burners. Each configuration was evaluated for the oven and for three cooktop burner combinations (two back, two front, one front and one back). At highest fan settings and standard installation against the wall, Hoods A and C captured back cooktop burner exhaust at > 90 percent and Hood B at > 80 percent. In this configuration, CE for front burner exhaust was 73-78 percent for Hoods A and C but only 46-63 percent for Hood B. CEs followed similar patterns but were substantially lower on the lowest fan speed. Installing the hood away from the wall improved CE for oven and front burners on Hood A at low speed, but substantially reduced CE for back burners for all hoods at low and high speed.

  8. Exhaust gas recirculation method for internal combustion engines

    SciTech Connect

    Kawanabe, T.; Kimura, K.; Asakura, M.; Shiina, T.

    1988-07-19

    This patent describes a method of controlling exhaust gas recirculation in an internal combustion engine having an exhaust passage, an intake passage, an exhaust gas recirculating passage communicating the exhaust passage with the intake passage, and exhaust gas recirculating valve; and a transmission having a shift lever. The valve opening of the exhaust gas recirculating valve is controlled in response to operating conditions of the engine so as to regulate the amount of exhaust gas recirculation to values appropriate to the operating conditions of the engine. The method comprising the steps of (1) determining whether or not the engine is in at least one of a predetermined accelerating condition and a predetermined decelerating condition; (2) varying the valve opening of the exhaust gas recirculating valve by a predetermined value when the engine is determined to be in at least one of the predetermined accelerating condition and the predetermined decelerating condition; (3) detecting a position of the shift lever of the transmission; and (4) correcting the predetermined value in accordance with the detected position of the shift lever so as to increase the valve opening of the exhaust gas recirculating valve as the shift lever of the transmission is set to a higher speed position.

  9. Exhaust gas purification system for lean burn engine

    DOEpatents

    Haines, Leland Milburn

    2002-02-19

    An exhaust gas purification system for a lean burn engine includes a thermal mass unit and a NO.sub.x conversion catalyst unit downstream of the thermal mass unit. The NO.sub.x conversion catalyst unit includes at least one catalyst section. Each catalyst section includes a catalytic layer for converting NO.sub.x coupled to a heat exchanger. The heat exchanger portion of the catalyst section acts to maintain the catalytic layer substantially at a desired temperature and cools the exhaust gas flowing from the catalytic layer into the next catalytic section in the series. In a further aspect of the invention, the exhaust gas purification system includes a dual length exhaust pipe upstream of the NO.sub.x conversion catalyst unit. The dual length exhaust pipe includes a second heat exchanger which functions to maintain the temperature of the exhaust gas flowing into the thermal mass downstream near a desired average temperature.

  10. 40 CFR 86.1511 - Exhaust gas analysis system.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Exhaust gas analysis system. 86.1511... Procedures § 86.1511 Exhaust gas analysis system. (a) Analyzers used for this subpart shall meet the following specifications: (1) The analyzer used shall conform to the accuracy provisions of 40 CFR part...

  11. 30 CFR 36.26 - Composition of exhaust gas.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Composition of exhaust gas. 36.26 Section 36.26 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR TESTING, EVALUATION, AND... EQUIPMENT Construction and Design Requirements § 36.26 Composition of exhaust gas. (a) Preliminary...

  12. 30 CFR 36.26 - Composition of exhaust gas.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Composition of exhaust gas. 36.26 Section 36.26 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR TESTING, EVALUATION, AND... EQUIPMENT Construction and Design Requirements § 36.26 Composition of exhaust gas. (a) Preliminary...

  13. Boosting devices with integral features for recirculating exhaust gas

    SciTech Connect

    Wu, Ko -Jen

    2015-09-15

    According to one embodiment of the invention, a compressor housing includes a compressor inlet in fluid communication with a compressor volute configured to house a compressor wheel, the compressor inlet configured to provide a first air flow to the compressor wheel and a compressor outlet in fluid communication with the compressor volute, the compressor outlet configured to direct a compressed gas to an intake manifold. The compressor housing further includes an exhaust gas recirculation inlet port in fluid communication with the compressor volute, the exhaust gas recirculation inlet port being configured to combine an exhaust gas flow with the air flow to the compressor wheel.

  14. Control logic for exhaust gas driven turbocharger

    SciTech Connect

    Adeff, G.A.

    1991-12-31

    This patent describes a method of controlling an exhaust gas driven turbocharger supplying charge air for an internal combustion engine powering vehicle, the turbocharger being adjustable from a normal mode to a power mode in which the charge air available to the engine during vehicle acceleration is increased over that available when the turbocharger is in the normal mode, the vehicle including engine power control means switchable by the vehicle operator from a normal mode to a power mode so that the vehicle operator may selectively elect either the normal mode or the power mode, comprising the steps of measuring the speed of the vehicle, permitting the vehicle operator to elect either the power mode or the normal mode for a subsequent vehicle acceleration, and then adjusting the turbocharger to the power mode when the speed of the vehicle is less than a predetermined reference speed and the vehicle operator has elected to power mode to increase the charge air available to the engine and thereby increasing engine power on a subsequent acceleration of the vehicle.

  15. The Effects of Diesel Exhaust Pollution on Floral Volatiles and the Consequences for Honey Bee Olfaction.

    PubMed

    Lusebrink, Inka; Girling, Robbie D; Farthing, Emily; Newman, Tracey A; Jackson, Chris W; Poppy, Guy M

    2015-10-01

    There is growing evidence of a substantial decline in pollinators within Europe and North America, most likely caused by multiple factors such as diseases, poor nutrition, habitat loss, insecticides, and environmental pollution. Diesel exhaust could be a contributing factor to this decline, since we found that diesel exhaust rapidly degrades floral volatiles, which honey bees require for flower recognition. In this study, we exposed eight of the most common floral volatiles to diesel exhaust in order to investigate whether it can affect volatile mediated plant-pollinator interaction. Exposure to diesel exhaust altered the blend of common flower volatiles significantly: myrcene was considerably reduced, β-ocimene became undetectable, and β-caryophyllene was transformed into its cis-isomer isocaryophyllene. Proboscis extension response (PER) assays showed that the alterations of the blend reduced the ability of honey bees to recognize it. The chemically reactive nitrogen oxides fraction of diesel exhaust gas was identified as capable of causing degradation of floral volatiles. PMID:26424685

  16. An assessment of consistence of exhaust gas emission test results obtained under controlled NEDC conditions

    NASA Astrophysics Data System (ADS)

    Balawender, K.; Jaworski, A.; Kuszewski, H.; Lejda, K.; Ustrzycki, A.

    2016-09-01

    Measurements concerning emissions of pollutants contained in automobile combustion engine exhaust gases is of primary importance in view of their harmful impact on the natural environment. This paper presents results of tests aimed at determining exhaust gas pollutant emissions from a passenger car engine obtained under repeatable conditions on a chassis dynamometer. The test set-up was installed in a controlled climate chamber allowing to maintain the temperature conditions within the range from -20°C to +30°C. The analysis covered emissions of such components as CO, CO2, NOx, CH4, THC, and NMHC. The purpose of the study was to assess repeatability of results obtained in a number of tests performed as per NEDC test plan. The study is an introductory stage of a wider research project concerning the effect of climate conditions and fuel type on emission of pollutants contained in exhaust gases generated by automotive vehicles.

  17. Removal of nitric oxide from exhaust gas with cyanuric acid--

    SciTech Connect

    Siebers, D.L. . Combustion Research Faclity); Caton, J.A. . Dept. of Mechanical Engineering)

    1990-01-01

    Addition of gaseous isocyanic acid (HNCO) to the exhaust of combustion systems or chemical process is proposed as a method for reducing nitric oxide (NO) emissions. The HNCO selectively reduces NO in the exhaust through a multistep chemical reaction mechanism. This article presents an experimental investigation of the proposed NO reduction process using cyanuric acid as the source of HNCO. At elevated temperature cyanuric acid decomposes and forms HNCO. The effects of temperature, exhaust gas composition, cyanuric acid concentration (i.e., HNCO concentration), and surfaces were examined. The experiments were conducted in an electrically heated quartz flow reactor using either exhaust from a diesel engine or simulated exhaust gas. The results demonstrate that gas phase NO reduction approaching 100% can be obtained.

  18. 40 CFR 86.211-94 - Exhaust gas analytical system.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Exhaust gas analytical system. 86.211-94 Section 86.211-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... New Medium-Duty Passenger Vehicles; Cold Temperature Test Procedures § 86.211-94 Exhaust...

  19. Gas flow means for improving efficiency of exhaust hoods

    DOEpatents

    Gadgil, A.J.

    1994-01-11

    Apparatus is described for inhibiting the flow of contaminants in an exhaust enclosure toward an individual located adjacent an opening into the exhaust enclosure by providing a gas flow toward a source of contaminants from a position in front of an individual to urge said contaminants away from the individual toward a gas exit port. The apparatus comprises a gas manifold which may be worn by a person as a vest. The manifold has a series of gas outlets on a front face thereof facing away from the individual and toward the contaminants to thereby provide a flow of gas from the front of the individual toward the contaminants. 15 figures.

  20. Gas flow means for improving efficiency of exhaust hoods

    DOEpatents

    Gadgil, Ashok J.

    1994-01-01

    Apparatus for inhibiting the flow of contaminants in an exhaust enclosure toward an individual located adjacent an opening into the exhaust enclosure by providing a gas flow toward a source of contaminants from a position in front of an individual to urge said contaminants away from the individual toward a gas exit port. The apparatus comprises a gas mani-fold which may be worn by a person as a vest. The manifold has a series of gas outlets on a front face thereof facing away from the individual and toward the contaminants to thereby provide a flow of gas from the front of the individual toward the contaminants.

  1. Exhaust Gas Energy Recovery Technology Applications

    SciTech Connect

    Wagner, Robert M; Szybist, James P

    2014-01-01

    Exhaust waste heat recovery systems have the potential to significantly improve vehicle fuel economy for conventional and hybrid electric powertrains spanning passenger to heavy truck applications. This chapter discusses thermodynamic considerations and three classes of energy recovery technologies which are under development for vehicle applications. More specifically, this chapter describes the state-of-the-art in exhaust WHR as well as challenges and opportunities for thermodynamic power cycles, thermoelectric devices, and turbo-compounding systems.

  2. Measuring Carbon Monoxide in Auto Exhaust by Gas Chromatography.

    ERIC Educational Resources Information Center

    Jaffe, Dan; Herndon, Scott

    1995-01-01

    Presents a simple and reliable technique using commonly available equipment for monitoring carbon monoxide in automobile exhaust. The experiment utilizes a gas chromatograph and a thermal conductivity detector (TCD). (DDR)

  3. Method and apparatus for processing exhaust gas with corona discharge

    DOEpatents

    Barlow, Stephan E.; Orlando, Thomas M.; Tonkyn, Russell G.

    1999-01-01

    The present invention is placing a catalyst coating upon surfaces surrounding a volume containing corona discharge. In addition, the electrodes are coated with a robust dielectric material. Further, the electrodes are arranged so that at least a surface portion of each electrode extends into a flow path of the exhaust gas to be treated and there is only exhaust gas in the volume between each pair of electrodes.

  4. Method and apparatus for processing exhaust gas with corona discharge

    DOEpatents

    Barlow, S.E.; Orlando, T.M.; Tonkyn, R.G.

    1999-06-22

    The present invention is placing a catalyst coating upon surfaces surrounding a volume containing corona discharge. In addition, the electrodes are coated with a robust dielectric material. Further, the electrodes are arranged so that at least a surface portion of each electrode extends into a flow path of the exhaust gas to be treated and there is only exhaust gas in the volume between each pair of electrodes. 12 figs.

  5. Removal of particulates from diesel engine exhaust gas

    SciTech Connect

    Wade, W.R.

    1983-09-20

    A method and apparatus is disclosed for periodically oxidizing particulate matter trapped in and on an exhaust gas purifying device used in conjunction with a diesel engine. Fuel normally delivered to selected combustion chambers is diverted to a fuel burning device associated with the purifying device. The diversion deactivates the combustion process in the selected chambers. The diverted fuel is then burned by the burning device to increase the exhaust gas temperature flowing through the purifying device and effect oxidation of collected particles.

  6. Physiological changes in certain test plants under automobile exhaust pollution.

    PubMed

    Mandal, Madhumanjari

    2006-01-01

    Plants are the only living organisms which have to suffer a lot from automobile exhaust pollution because they remain static at their habitat. But such roadside plants like Nerium indicum Mill., Boerhaavia diffusa L., Amaranthus spinosus L., Cephalandra indica Naud., and Tabemaemontana divaricata L. can easily avoid the effects of air pollution by altering their physiological pathways pertaining to photosynthesis and respiration. Stomatal closure in Boerhaavia, Amaranthus, Cephlandra and stomatal clogging in Nerium and Tabemaemontana help these plants in preventing the entry of poisonous gases. The increased activity of the enzyme Phosphoenol Pyruvate Carboxylase (PEPCase) belonging to C4 pathway helps Nerium and Boerhaavia (both C3 plants) in carbon fixation under stress condition. Photorespiration is favoured in Amaranthus, Cephalandra and Tabernaemontana to compensate for the over production of ATP in them. Owing an inefficient gaseous exchange in Boerhaavia and Tabemaemontana, the activity of Glucose 6--Phosphate Dehydrogenase (G6-PD) also increases for the preferential shift to Pentose Phosphate Pathway to produce excess NADPH+H+ which are likely to re-oxidize by metabolic reactions not linked to electron transport chain. PMID:16850874

  7. Real-Time Measurement of Vehicle Exhaust Gas Flow

    SciTech Connect

    Hardy, J.E.; Hylton, J.O.; Joy, R.D.; McKnight, T.E.

    1999-06-28

    A flow measurement system was developed to measure, in real-time, the exhaust gas flow from vehicies. This new system was based on the vortex shedding principle using ultrasonic detectors for sensing the shed vortices. The flow meter was designed to measure flow over a range of 1 to 366 Ips with an inaccuracy of ~1o/0 of reading. Additionally, the meter was engineered to cause minimal pressure drop (less than 125mm of water), to function in a high temperature environment (up to 650oC) with thermal transients of 15 oC/s, and to have a response time of 0.1 seconds for a 10% to 90!40 step change. The flow meter was also configured to measure hi-directional flow. Several flow meter prototypes were fabricated, tested, and calibrated in air, simulated exhaust gas, and actual exhaust gas. Testing included gas temperatures to 600oC, step response experiments, and flow rates from O to 360 lps in air and exhaust gas. Two prototypes have been tested extensively at NIST and two additional meters have been installed in exhaust gas flow lines for over one year. This new flow meter design has shown to be accurate, durabIe, fast responding, and to have a wide rangeabi~ity.

  8. Particulate exhaust emissions from an experimental combustor. [gas turbine engine

    NASA Technical Reports Server (NTRS)

    Norgren, C. T.; Ingebo, R. D.

    1975-01-01

    The concentration of dry particulates (carbon) in the exhaust of an experimental gas turbine combustor was measured at simulated takeoff operating conditions and correlated with the standard smoke-number measurement. Carbon was determined quantitatively from a sample collected on a fiberglass filter by converting the carbon in the smoke sample to carbon dioxide and then measuring the volume of carbon dioxide formed by gas chromatography. At a smoke of 25 (threshold of visibility of the smoke plume for large turbojets) the carbon concentration was 2.8 mg carbon/cu m exhaust gas, which is equivalent to an emission index of 0.17 g carbon/kg fuel.

  9. Low-pressure-ratio regenerative exhaust-heated gas turbine

    SciTech Connect

    Tampe, L.A.; Frenkel, R.G.; Kowalick, D.J.; Nahatis, H.M.; Silverstein, S.M.; Wilson, D.G.

    1991-01-01

    A design study of coal-burning gas-turbine engines using the exhaust-heated cycle and state-of-the-art components has been completed. In addition, some initial experiments on a type of rotary ceramic-matrix regenerator that would be used to transfer heat from the products of coal combustion in the hot turbine exhaust to the cool compressed air have been conducted. Highly favorable results have been obtained on all aspects on which definite conclusions could be drawn.

  10. Current Techniques of Growing Algae Using Flue Gas from Exhaust Gas Industry: a Review.

    PubMed

    Huang, Guanhua; Chen, Feng; Kuang, Yali; He, Huan; Qin, An

    2016-03-01

    The soaring increase of flue gas emission had caused global warming, environmental pollution as well as climate change. Widespread concern on reduction of flue gas released from industrial plants had considered the microalgae as excellent biological materials for recycling the carbon dioxide directly emitted from exhaust industries. Microalgae also have the potential to be the valuable feedback for renewable energy production due to their high growth rate and abilities to sequester inorganic carbon through photosynthetic process. In this review article, we will illustrate important relative mechanisms in the metabolic processes of biofixation by microalgae and their recent experimental researches and advances of sequestration of carbon dioxide by microalgae on actual industrial and stimulate flue gases, novel photobioreactor cultivation systems as well as the perspectives and limitations of microalgal cultivation in further development.

  11. Assessment and prediction of urban air pollution caused by motor transport exhaust gases using computer simulation methods

    NASA Astrophysics Data System (ADS)

    Boyarshinov, Michael G.; Vaismana, Yakov I.

    2016-10-01

    The following methods were used in order to identify the pollution fields of urban air caused by the motor transport exhaust gases: the mathematical model, which enables to consider the influence of the main factors that determine pollution fields formation in the complex spatial domain; the authoring software designed for computational modeling of the gas flow, generated by numerous mobile point sources; the results of computing experiments on pollutant spread analysis and evolution of their concentration fields. The computational model of exhaust gas distribution and dispersion in a spatial domain, which includes urban buildings, structures and main traffic arteries, takes into account a stochastic character of cars apparition on the borders of the examined territory and uses a Poisson process. The model also considers the traffic lights switching and permits to define the fields of velocity, pressure and temperature of the discharge gases in urban air. The verification of mathematical model and software used confirmed their satisfactory fit to the in-situ measurements data and the possibility to use the obtained computing results for assessment and prediction of urban air pollution caused by motor transport exhaust gases.

  12. Power recovery from turbine and gas engine exhausts

    SciTech Connect

    Lawson, G.L.

    1985-02-01

    Due to the energy consciousness of the United States and to the ever increasing cost of engine fuels, power recovery from turbine and gas engine exhausts has come of age. The addition of waste recovery systems to these exhausts increases the thermal efficiencies of typical systems from the range of 21% to 39% up to the range of 28% to 49%. The new ''expander'' type power recovery system includes a waste heat recovery exchanger which will transfer heat from the engine exhaust into any of numerous thermal fluids. The recovered heat energy now in the thermal fluid medium can, in turn, be used to produce power for any desired application (i.e. gas compression, process refrigeration, electrical power generation, etc.). The particular systems put forth in this paper concentrate on the use of expansion fluids (other than steam) driving ''expanders'' as motive devices.

  13. 30 CFR 7.102 - Exhaust gas cooling efficiency test.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Exhaust gas cooling efficiency test. 7.102 Section 7.102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR TESTING, EVALUATION, AND APPROVAL OF MINING PRODUCTS TESTING BY APPLICANT OR THIRD PARTY Diesel Power...

  14. IET exhaust gas duct, system layout, plan, and section. shows ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    IET exhaust gas duct, system layout, plan, and section. shows mounting brackets, concrete braces, divided portion of duct, other details. Ralph M. Parsons 902-5-ANP-712-S 429. Date: May 1954. Approved by INEEL Classification Office for public release. INEEL index code no. 035-0712-60-693-106980 - Idaho National Engineering Laboratory, Test Area North, Scoville, Butte County, ID

  15. 40 CFR 86.1511 - Exhaust gas analysis system.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... following specifications: (1) The analyzer used shall conform to the accuracy provisions of 40 CFR part 1065... flow. (b) The inclusion of a raw CO2 analyzer as specified in 40 CFR part 1065 is required in order to... 40 Protection of Environment 19 2011-07-01 2011-07-01 false Exhaust gas analysis system....

  16. 30 CFR 7.102 - Exhaust gas cooling efficiency test.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Exhaust gas cooling efficiency test. 7.102 Section 7.102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR TESTING... Intended for Use in Areas of Underground Coal Mines Where Permissible Electric Equipment is Required §...

  17. 30 CFR 7.102 - Exhaust gas cooling efficiency test.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Exhaust gas cooling efficiency test. 7.102 Section 7.102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR TESTING... Intended for Use in Areas of Underground Coal Mines Where Permissible Electric Equipment is Required §...

  18. IET exhaust gas stack. Section, west elevation, foundation plan, access ...

    Library of Congress Historic Buildings Survey, Historic Engineering Record, Historic Landscapes Survey

    IET exhaust gas stack. Section, west elevation, foundation plan, access ladder, airplane warning light. Ralph M. Parsons 902-5-ANP-712-S 433. Date: May 1954. Approved by INEEL Classification Office for public release. INEEL index code no. 035-0712-60-693-106984 - Idaho National Engineering Laboratory, Test Area North, Scoville, Butte County, ID

  19. 40 CFR 91.420 - CVS concept of exhaust gas sampling system.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... exhaust temperature and pressure. (c) For the testing described in this subpart, a CVS must consist of: A... 40 Protection of Environment 20 2011-07-01 2011-07-01 false CVS concept of exhaust gas sampling... Procedures § 91.420 CVS concept of exhaust gas sampling system. (a) A dilute exhaust sampling system...

  20. 40 CFR 91.420 - CVS concept of exhaust gas sampling system.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... exhaust temperature and pressure. (c) For the testing described in this subpart, a CVS must consist of: A... 40 Protection of Environment 21 2012-07-01 2012-07-01 false CVS concept of exhaust gas sampling... Procedures § 91.420 CVS concept of exhaust gas sampling system. (a) A dilute exhaust sampling system...

  1. 40 CFR 91.420 - CVS concept of exhaust gas sampling system.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... exhaust temperature and pressure. (c) For the testing described in this subpart, a CVS must consist of: A... 40 Protection of Environment 21 2013-07-01 2013-07-01 false CVS concept of exhaust gas sampling... Procedures § 91.420 CVS concept of exhaust gas sampling system. (a) A dilute exhaust sampling system...

  2. 40 CFR 91.420 - CVS concept of exhaust gas sampling system.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... exhaust temperature and pressure. (c) For the testing described in this subpart, a CVS must consist of: A... 40 Protection of Environment 20 2014-07-01 2013-07-01 true CVS concept of exhaust gas sampling... Procedures § 91.420 CVS concept of exhaust gas sampling system. (a) A dilute exhaust sampling system...

  3. 40 CFR 90.420 - CVS concept of exhaust gas sampling system.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... dilute exhaust temperature and pressure. (c) For the testing described in this subpart, a CVS must... 40 Protection of Environment 20 2014-07-01 2013-07-01 true CVS concept of exhaust gas sampling... Gaseous Exhaust Test Procedures § 90.420 CVS concept of exhaust gas sampling system. (a) A dilute...

  4. 40 CFR 90.420 - CVS concept of exhaust gas sampling system.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... dilute exhaust temperature and pressure. (c) For the testing described in this subpart, a CVS must... 40 Protection of Environment 20 2011-07-01 2011-07-01 false CVS concept of exhaust gas sampling... Gaseous Exhaust Test Procedures § 90.420 CVS concept of exhaust gas sampling system. (a) A dilute...

  5. 40 CFR 90.420 - CVS concept of exhaust gas sampling system.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... dilute exhaust temperature and pressure. (c) For the testing described in this subpart, a CVS must... 40 Protection of Environment 21 2013-07-01 2013-07-01 false CVS concept of exhaust gas sampling... Gaseous Exhaust Test Procedures § 90.420 CVS concept of exhaust gas sampling system. (a) A dilute...

  6. 40 CFR 90.420 - CVS concept of exhaust gas sampling system.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... dilute exhaust temperature and pressure. (c) For the testing described in this subpart, a CVS must... 40 Protection of Environment 21 2012-07-01 2012-07-01 false CVS concept of exhaust gas sampling... Gaseous Exhaust Test Procedures § 90.420 CVS concept of exhaust gas sampling system. (a) A dilute...

  7. Reduction of low temperature engine pollutants by understanding the exhaust species interactions in a diesel oxidation catalyst.

    PubMed

    Lefort, I; Herreros, J M; Tsolakis, A

    2014-02-18

    The interactions between exhaust gas species and their effect (promotion or inhibition) on the light-off and activity of a diesel oxidation catalyst (DOC) for the removal of pollutants are studied, using actual engine exhaust gases from the combustion of diesel, alternative fuels (rapeseed methyl ester and gas-to-liquid fuel) and diesel/propane dual fuel combustion. The activity of the catalyst was recorded during a heating temperature ramp where carbon monoxide (CO) and hydrocarbon (HC) light-off curves were obtained. From the catalyst activity tests, it was found that the presence of species including CO, medium-heavy HC, alkenes, alkanes, and NOx and their concentration influence the catalyst ability to reduce CO and total HC emissions before release to the atmosphere. CO could inhibit itself and other species oxidation (e.g., light and medium-heavy hydrocarbons) while suffering from competitive adsorption with NO. Hydrocarbon species were also found to inhibit their own oxidation as well as CO through adsorption competition. On the other hand, NO2 was found to promote low temperature HC oxidation through its partial reduction, forming NO. The understanding of these exhaust species interactions within the DOC could aid the design of an efficient aftertreatment system for the removal of diesel exhaust pollutants.

  8. Test Program for High Efficiency Gas Turbine Exhaust Diffuser

    SciTech Connect

    Norris, Thomas R.

    2009-12-31

    This research relates to improving the efficiency of flow in a turbine exhaust, and thus, that of the turbine and power plant. The Phase I SBIR project demonstrated the technical viability of “strutlets” to control stalls on a model diffuser strut. Strutlets are a novel flow-improving vane concept intended to improve the efficiency of flow in turbine exhausts. Strutlets can help reduce turbine back pressure, and incrementally improve turbine efficiency, increase power, and reduce greenhouse gas emmission. The long-term goal is a 0.5 percent improvement of each item, averaged over the US gas turbine fleet. The strutlets were tested in a physical scale model of a gas turbine exhaust diffuser. The test flow passage is a straight, annular diffuser with three sets of struts. At the end of Phase 1, the ability of strutlets to keep flow attached to struts was demonstrated, but the strutlet drag was too high for a net efficiency advantage. An independently sponsored followup project did develop a highly-modified low-drag strutlet. In combination with other flow improving vanes, complicance to the stated goals was demonstrated for for simple cycle power plants, and to most of the goals for combined cycle power plants using this particular exhaust geometry. Importantly, low frequency diffuser noise was reduced by 5 dB or more, compared to the baseline. Appolicability to other diffuser geometries is yet to be demonstrated.

  9. Electron beam treatment of exhaust gas with high NOx concentration

    NASA Astrophysics Data System (ADS)

    Licki, Janusz; Chmielewski, Andrzej G.; Pawelec, Andrzej; Zimek, Zbigniew; Witman, Sylwia

    2014-05-01

    Simulated exhaust gases with a high NOx concentration, ranging from 200 to 1700 ppmv, were irradiated by an electron beam from an accelerator. In the first part of this study, only exhaust gases were treated. Low NOx removal efficiencies were obtained for high NOx concentrations, even with high irradiation doses applied. In the second part of study, gaseous ammonia or/and vapor ethanol were added to the exhaust gas before its inlet to the plasma reactor. These additions significantly enhanced the NOx removal efficiency. The synergistic effect of high SO2 concentration on NOx removal was observed. The combination of electron beam treatment with the introduction of the above additions and with the performance of irradiation under optimal parameters ensured high NOx removal efficiency without the application of a solid-state catalyst.

  10. Integrated exhaust gas recirculation and charge cooling system

    SciTech Connect

    Wu, Ko-Jen

    2013-12-10

    An intake system for an internal combustion engine comprises an exhaust driven turbocharger configured to deliver compressed intake charge, comprising exhaust gas from the exhaust system and ambient air, through an intake charge conduit and to cylinders of the internal combustion engine. An intake charge cooler is in fluid communication with the intake charge conduit. A cooling system, independent of the cooling system for the internal combustion engine, is in fluid communication with the intake charge cooler through a cooling system conduit. A coolant pump delivers a low temperature cooling medium from the cooling system to and through the intake charge cooler for the transfer of heat from the compressed intake charge thereto. A low temperature cooler receives the heated cooling medium through the cooling system conduit for the transfer or heat therefrom.

  11. Effects of injection pressure and injection timing to exhaust gas opacity for a conventional indirect diesel engine

    NASA Astrophysics Data System (ADS)

    Budiman, Agus; Majid, Akmal Irfan; Pambayun, Nirmala Adhi Yoga; Yuswono, Lilik Chaerul; Sukoco

    2016-06-01

    In relation to pollution control and environmental friendliness, the quality of exhaust gas from diesel engine needs to be considered. The influences of injection pressure and timing to exhaust gas opacity were investigated. A series of experiments were conducted in a one-cylinder conventional diesel engine with a naturally aspirated system and indirect injection. The default specification of injection pressure was 120 kg/cm2. To investigate the injection pressure, the engine speed was retained on 1000 rpm with pressure variations from 80 to 215 kg/cm2. On the other hand, the various injection timing (8, 10, 12, 16 degrees before TDC point and exact 18 degrees before TDC point) were used to determine their effects to exhaust gas opacity. In this case, the engine speed was varied from 1000 to 2400 rpm. The injector tester was used to measure injection pressure whereas the exhaust gas opacity was determined by the smoke meter. Those data were also statistically analyzed by product moment correlation. As the results, the injection pressure of diesel engine had a non-significant positive correlation to the exhaust gas opacity with r = 0.113 and p > 5 %. Injection pressure should be adjusted to the specification listed on the diesel engine as if it was too high or too low will lead to the higher opacity. Moreover, there was a significant positive correlation between injection timing and the exhaust gas opacity in all engine speeds.

  12. Power plant including an exhaust gas recirculation system for injecting recirculated exhaust gases in the fuel and compressed air of a gas turbine engine

    DOEpatents

    Anand, Ashok Kumar; Nagarjuna Reddy, Thirumala Reddy; Shaffer, Jason Brian; York, William David

    2014-05-13

    A power plant is provided and includes a gas turbine engine having a combustor in which compressed gas and fuel are mixed and combusted, first and second supply lines respectively coupled to the combustor and respectively configured to supply the compressed gas and the fuel to the combustor and an exhaust gas recirculation (EGR) system to re-circulate exhaust gas produced by the gas turbine engine toward the combustor. The EGR system is coupled to the first and second supply lines and configured to combine first and second portions of the re-circulated exhaust gas with the compressed gas and the fuel at the first and second supply lines, respectively.

  13. 30 CFR 36.47 - Tests of exhaust-gas cooling system.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... air mixture. All parts of the engine and exhaust-gas cooling system shall be at their respective... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Tests of exhaust-gas cooling system. 36.47... TRANSPORTATION EQUIPMENT Test Requirements § 36.47 Tests of exhaust-gas cooling system. (a) The adequacy of...

  14. 30 CFR 36.47 - Tests of exhaust-gas cooling system.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... air mixture. All parts of the engine and exhaust-gas cooling system shall be at their respective... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Tests of exhaust-gas cooling system. 36.47... TRANSPORTATION EQUIPMENT Test Requirements § 36.47 Tests of exhaust-gas cooling system. (a) The adequacy of...

  15. 75 FR 82040 - Notice of Public Meeting on the International Maritime Organization Guidelines for Exhaust Gas...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2010-12-29

    ... Exhaust Gas Cleaning Systems for Marine Engines To Comply with Annex VI to MARPOL 73/78 AGENCY: Coast... meeting on the International Maritime Organization guidelines for exhaust gas cleaning systems for marine...-543 policy letter 09-01 that provide guidance for exhaust gas cleaning systems under MARPOL Annex...

  16. Field test comparison of natural gas engine exhaust valves

    SciTech Connect

    Bicknell, W.B.; Hay, S.C.; Shade, W.N.; Statler, G.R.

    1996-12-31

    As part of a product improvement program, an extensive spark-ignited, turbocharged, natural gas engine exhaust valve test program was conducted using laboratory and field engines. Program objectives were to identify a valve and seat insert combination that increased mean time between overhauls (MTBO) while reducing the risk of premature valve cracking and failure. Following a thorough design review, a large number of valve and seat insert configurations were tested in a popular 900 RPM, 166 BHP (0.123 Mw) per cylinder industrial gas engine series. Material, head geometry, seat angle and other parameters were compared. Careful in-place measurements and post-test inspections compared various configurations and identified optimal exhaust valving for deployment in new units and upgrades of existing engines.

  17. Exhaust gas emissions of a vortex breakdown stabilized combustor

    NASA Technical Reports Server (NTRS)

    Yetter, R. A.; Gouldin, F. C.

    1976-01-01

    Exhaust gas emission data are described for a swirl stabilized continuous combustor. The combustor consists of confined concentric jets with premixed fuel and air in the inner jet and air in the outer jet. Swirl may be induced in both inner and outer jets with the sense of rotation in the same or opposite directions (co-swirl and counter-swirl). The combustor limits NO emissions by lean operation without sacrificing CO and unburned hydrocarbon emission performance, when commercial-grade methane and air fired at one atmosphere without preheat are used. Relative swirl direction and magnitude are found to have significant effects on exhaust gas concentrations, exit temperatures, and combustor efficiencies. Counter-swirl gives a large recirculation zone, a short luminous combustion zone, and large slip velocities in the interjet shear layer. For maximum counter-swirl conditions, the efficiency is low.

  18. Vehicle exhaust gas chemical sensors using acoustic wave resonators

    SciTech Connect

    Cernosek, R.W.; Small, J.H.; Sawyer, P.S.; Bigbie, J.R.; Anderson, M.T.

    1998-03-01

    Under Sandia`s Laboratory Directed Research and Development (LDRD) program, novel acoustic wave-based sensors were explored for detecting gaseous chemical species in vehicle exhaust streams. The need exists for on-line, real-time monitors to continuously analyze the toxic exhaust gases -- nitrogen oxides (NOx), carbon monoxide (CO), and hydrocarbons (HC) -- for determining catalytic converter efficiency, documenting compliance to emission regulations, and optimizing engine performance through feedback control. In this project, the authors adapted existing acoustic wave chemical sensor technology to the high temperature environment and investigated new robust sensor materials for improving gas detection sensitivity and selectivity. This report describes one new sensor that has potential use as an exhaust stream residual hydrocarbon monitor. The sensor consists of a thickness shear mode (TSM) quartz resonator coated with a thin mesoporous silica layer ion-exchanged with palladium ions. When operated at temperatures above 300 C, the high surface area film catalyzes the combustion of the hydrocarbon vapors in the presence of oxygen. The sensor acts as a calorimeter as the exothermic reaction slightly increases the temperature, stressing the sensor surface, and producing a measurable deviation in the resonator frequency. Sensitivities as high as 0.44 (ppm-{Delta}f) and (ppm-gas) have been measured for propylene gas, with minimum detectable signals of < 50 ppm of propylene at 500 C.

  19. Apparatus and method to inject a reductant into an exhaust gas feedstream

    DOEpatents

    Viola, Michael B.

    2009-09-22

    An exhaust aftertreatment system for an internal combustion engine is provided including an apparatus and method to inject a reductant into the exhaust gas feedstream. Included is a fuel metering device adapted to inject reductant into the exhaust gas feedstream and a controllable pressure regulating device. A control module is operatively connected to the reductant metering device and the controllable pressure regulating device, and, adapted to effect flow of reductant into the exhaust gas feedstream over a controllable flow range.

  20. 40 CFR 90.423 - Exhaust gas analytical system; CVS grab sample.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    .... Analysis systems meeting the specifications and requirements of this subpart for dilute sampling may be... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Exhaust gas analytical system; CVS... KILOWATTS Gaseous Exhaust Test Procedures § 90.423 Exhaust gas analytical system; CVS grab sample....

  1. 40 CFR 91.420 - CVS concept of exhaust gas sampling system.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 20 2010-07-01 2010-07-01 false CVS concept of exhaust gas sampling system. 91.420 Section 91.420 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Procedures § 91.420 CVS concept of exhaust gas sampling system. (a) A dilute exhaust sampling system...

  2. 40 CFR 90.420 - CVS concept of exhaust gas sampling system.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 20 2010-07-01 2010-07-01 false CVS concept of exhaust gas sampling system. 90.420 Section 90.420 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... Gaseous Exhaust Test Procedures § 90.420 CVS concept of exhaust gas sampling system. (a) A dilute...

  3. Exhaust gas bypass valve control for thermoelectric generator

    DOEpatents

    Reynolds, Michael G; Yang, Jihui; Meisner, Greogry P.; Stabler, Francis R.; De Bock, Hendrik Pieter Jacobus; Anderson, Todd Alan

    2012-09-04

    A method of controlling engine exhaust flow through at least one of an exhaust bypass and a thermoelectric device via a bypass valve is provided. The method includes: determining a mass flow of exhaust exiting an engine; determining a desired exhaust pressure based on the mass flow of exhaust; comparing the desired exhaust pressure to a determined exhaust pressure; and determining a bypass valve control value based on the comparing, wherein the bypass valve control value is used to control the bypass valve.

  4. Treating exhaust gas from a pressurized fluidized bed reaction system

    DOEpatents

    Isaksson, J.; Koskinen, J.

    1995-08-22

    Hot gases from a pressurized fluidized bed reactor system are purified. Under super atmospheric pressure conditions hot exhaust gases are passed through a particle separator, forming a filtrate cake on the surface of the separator, and a reducing agent--such as an NO{sub x} reducing agent (like ammonia)--is introduced into the exhaust gases just prior to or just after particle separation. The retention time of the introduced reducing agent is enhanced by providing a low gas velocity (e.g. about 1--20 cm/s) during passage of the gas through the filtrate cake while at super atmospheric pressure. Separation takes place within a distinct pressure vessel, the interior of which is at a pressure of about 2--100 bar, and introduction of reducing agent can take place at multiple locations (one associated with each filter element in the pressure vessel), or at one or more locations just prior to passage of clean gas out of the pressure vessel (typically passed to a turbine). 8 figs.

  5. Treating exhaust gas from a pressurized fluidized bed reaction system

    SciTech Connect

    Isaksson, Juhani; Koskinen, Jari

    1995-01-01

    Hot gases from a pressurized fluidized bed reactor system are purified. Under superatmospheric pressure conditions hot exhaust gases are passed through a particle separator, forming a flitrate cake on the surface of the separator, and a reducing agent--such as an NO.sub.x reducing agent (like ammonia), is introduced into the exhaust gases just prior to or just after particle separation. The retention time of the introduced reducing agent is enhanced by providing a low gas velocity (e.g. about 1-20 cm/s) during passage of the gas through the filtrate cake while at superatmospheric pressure. Separation takes place within a distinct pressure vessel the interior of which is at a pressure of about 2-100 bar, and-introduction of reducing agent can take place at multiple locations (one associated with each filter element in the pressure vessel), or at one or more locations just prior to passage of clean gas out of the pressure vessel (typically passed to a turbine).

  6. Cardiovascular effects of diesel exhaust and ozone in a multi-pollutant context

    EPA Science Inventory

    The cardiovascular effects of two common pollutants, diesel exhaust (DE) and ozone (O3), were examined alone and in combination. Healthy subjects (n=15) were exposed for 2 hrs with intermittent, moderate exercise on Day 1 to 0.3 ppm O3, 300 µg/m3 DE, both O3 and DE, or fil...

  7. Diesel Exhaust Activates & Primes Microglia: Air Pollution, Neuroinflammation, & Regulation of Dopaminergic Neurotoxicity

    EPA Science Inventory

    Air pollution is linked to central nervous system (CNS) disease, but the mechanisms responsible are poorly understood. Rats exposed to Diesel Exhaust (DE, 2.0,0.5, and 0 mg/m3) by inhalation over 4 weeks demonstrated elevated levels of whole brain IL-6 protein, nitrated proteins,...

  8. Measurement of Gas-phase Acids in Diesel Exhaust

    NASA Astrophysics Data System (ADS)

    Wentzell, J. J.; Liggio, J.; Li, S.; Vlasenko, A. L.; Staebler, R. M.; Brook, J.; Lu, G.; Poitras, M.; Chan, T.

    2012-12-01

    Gas-phase acids were measured using chemical ionization mass spectrometry (CIMS) as part of the Diesel Engine Emission Research Experiment (DEERE). The CIMS technique, utilizing acetate ion (CH3COO-) as a reagent ion, proved to be a rapid (measurements on the order of seconds) and sensitive (several counts/pptv) method of quantifying the acid emissions. Diluted diesel exhaust measurements were made from a Constant Volume Sampling dilution tunnel using a light duty (1.9L turbocharged Volkswagen Jetta TDI) diesel engine equipped with an OEM diesel oxidation catalyst and exhaust gas recirculation, mounted on an engine dynamometer. Acids measured included isocyanic, nitrous, nitric, propionic and sum of lactic and oxalic, as well as other unidentified compounds. Complimentary measurements of CO, CO2, Total Hydrocarbon (THC), and NOx, were also performed. Several engine modes (different engine rpm and torque outputs) at steady state were examined to determine their effect on acid emissions. Emission rates with respect to NOx and fuel based emission factors were determined. Measurements of HONO fuel emission factors agree well with real-world measurements within a traffic tunnel.1 The first estimate of isocyanic acid emission factors from a diesel engine is reported, and suggests that the emission of this highly toxic compound in diesel exhaust should not be ignored. 1. Kurtenbach, R., Becker, K. H., Gomes, J. A. G., Kleffmann, J.,Lorzer, J. C., Spittler, M., Wiesen, P., Ackermann, R., Geyer, A.,and Platt, U.: Investigations of emissions and heterogeneous formation of HONO in a road traffic tunnel, Atmos. Environ., 35, 3385-3394, doi:10.1016/S1352-2310(01)00138-8, 2001.

  9. 30 CFR 36.43 - Determination of exhaust-gas composition.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... volume, of Pittsburgh natural gas (see footnote 3) in the air. Test observations shall include the rate... prescribed by MSHA to determine the volume of air (ventilation) required to dilute the exhaust gas (see § 36... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Determination of exhaust-gas composition....

  10. 30 CFR 36.43 - Determination of exhaust-gas composition.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... volume, of Pittsburgh natural gas (see footnote 3) in the air. Test observations shall include the rate... prescribed by MSHA to determine the volume of air (ventilation) required to dilute the exhaust gas (see § 36... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Determination of exhaust-gas composition....

  11. Exhaust gas measurements in a propane fueled swirl stabilized combustor

    NASA Technical Reports Server (NTRS)

    Aanad, M. S.

    1982-01-01

    Exhaust gas temperature, velocity, and composition are measured and combustor efficiencies are calculated in a lean premixed swirl stabilized laboratory combustor. The radial profiles of the data between the co- and the counter swirl cases show significant differences. Co-swirl cases show evidence of poor turbulent mixing across the combustor in comparison to the counter-swirl cases. NO sub x levels are low in the combustor but substantial amounts of CO are present. Combustion efficiencies are low and surprisingly constant with varying outer swirl in contradiction to previous results under a slightly different inner swirl condition. This difference in the efficiency trends is expected to be a result of the high sensitivity of the combustor to changes in the inner swirl. Combustor operation is found to be the same for propane and methane fuels. A mechanism is proposed to explain the combustor operation and a few important characteristics determining combustor efficiency are identified.

  12. Ion beam analyses of particulate matter in exhaust gas of a ship diesel engine

    NASA Astrophysics Data System (ADS)

    Furuyama, Yuichi; Fujita, Hirotsugu; Taniike, Akira; Kitamura, Akira

    2011-12-01

    There is an urgent need to reduce emission of the particulate matter (PM) in the exhaust gas from ship diesel engines causing various health hazards and serious environmental pollution. Usually the heavy fuel oil (HFO) for ships is of low quality, and contains various kinds of impurities. Therefore, the emission of PM along with exhaust gas from ship diesel engines is one of the most serious environmental issues. However, the PM fundamental properties are not well known. Therefore, it is important to perform elemental analysis of the PM. The HFO contains sulfur with a relatively high concentration of a few percent. It is important to make quantitative measurements of sulfur in the PM, because this element is poisonous for the human body. In the present work, PM samples were collected from exhaust gas of a test engine, and RBS and PIXE analyses were applied successfully to quantitative analysis of the PM samples. The RBS analysis enabled quantitative analysis of sulfur and carbon in the collected PM, while heavier elements such as vanadium and iron were analyzed quantitatively with the PIXE analysis. It has been found that the concentration ratio of sulfur to carbon was between 0.007 and 0.012, and did not strongly depend on the output power of the engine. The S/ C ratio is approximately equal to the original composition of the HFO used in the present work, 0.01. From the known conversion ratio 0.015 of sulfur in the HFO to sulfates, the conversion ratio of carbon in the HFO to the PM is found to be 0.01-0.02 by the RBS measurements. On the other hand, the PIXE analysis revealed a vanadium enrichment of one order of magnitude in the PM.

  13. 40 CFR 91.423 - Exhaust gas analytical system; CVS grab sample.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    .... Analysis systems meeting the specifications and requirements of this subpart for dilute sampling may be... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Exhaust gas analytical system; CVS... Procedures § 91.423 Exhaust gas analytical system; CVS grab sample. (a) Schematic drawings. Figure 4...

  14. 30 CFR 36.49 - Tests of exhaust-gas dilution system.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Tests of exhaust-gas dilution system. 36.49 Section 36.49 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR TESTING... TRANSPORTATION EQUIPMENT Test Requirements § 36.49 Tests of exhaust-gas dilution system. The performance...

  15. 30 CFR 36.49 - Tests of exhaust-gas dilution system.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Tests of exhaust-gas dilution system. 36.49 Section 36.49 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR TESTING... TRANSPORTATION EQUIPMENT Test Requirements § 36.49 Tests of exhaust-gas dilution system. The performance...

  16. Characterization of SnO2 ceramic gas sensor for exhaust gas monitoring of SVE process.

    PubMed

    Yang, Ji-Won; Cho, Hyun-Jeong; Lee, Sang-Hyun; Lee, Jae-Young

    2004-03-01

    A Figaro-type gas sensor system was investigated for the monitoring of volatile organic contaminants (VOC) in the exhaust gas from a soil vapor extraction (SVE) process. Benzene, toluene, ethyl benzene and xylene (BTEX), and their mixtures, were tested as representative contaminants. Reasonably good correlation factors >0.98 were obtained between the GC analyses and the sensor responses for each component, and for the total gas concentrations. Although the composition of the exhaust gas from SVE process, as well as the amount of each component, change with time, the sensor can be used to estimate the residual amount of contaminants by measuring the total concentrations in the exhaust gas. The sensor can be utilized as a valuable tool for the monitoring of SVE process by indicating when the operation to remediate a contaminated site should be stopped. The proposed ceramic gas sensor system may be a good alternative to existing methods, because it can satisfy the essential monitoring necessities of SVE processes, and has many advantages over other fully equipped instrumentation, as a cost-effective device, with long-term monitoring stability.

  17. Method for controlling exhaust gas heat recovery systems in vehicles

    DOEpatents

    Spohn, Brian L.; Claypole, George M.; Starr, Richard D

    2013-06-11

    A method of operating a vehicle including an engine, a transmission, an exhaust gas heat recovery (EGHR) heat exchanger, and an oil-to-water heat exchanger providing selective heat-exchange communication between the engine and transmission. The method includes controlling a two-way valve, which is configured to be set to one of an engine position and a transmission position. The engine position allows heat-exchange communication between the EGHR heat exchanger and the engine, but does not allow heat-exchange communication between the EGHR heat exchanger and the oil-to-water heat exchanger. The transmission position allows heat-exchange communication between the EGHR heat exchanger, the oil-to-water heat exchanger, and the engine. The method also includes monitoring an ambient air temperature and comparing the monitored ambient air temperature to a predetermined cold ambient temperature. If the monitored ambient air temperature is greater than the predetermined cold ambient temperature, the two-way valve is set to the transmission position.

  18. On the thermodynamics of waste heat recovery from internal combustion engine exhaust gas

    NASA Astrophysics Data System (ADS)

    Meisner, G. P.

    2013-03-01

    The ideal internal combustion (IC) engine (Otto Cycle) efficiency ηIC = 1-(1/r)(γ - 1) is only a function of engine compression ratio r =Vmax/Vmin and exhaust gas specific heat ratio γ = cP/cV. Typically r = 8, γ = 1.4, and ηIC = 56%. Unlike the Carnot Cycle where ηCarnot = 1-(TC/TH) for a heat engine operating between hot and cold heat reservoirs at TH and TC, respectively, ηIC is not a function of the exhaust gas temperature. Instead, the exhaust gas temperature depends only on the intake gas temperature (ambient), r, γ, cV, and the combustion energy. The ejected exhaust gas heat is thermally decoupled from the IC engine and conveyed via the exhaust system (manifold, pipe, muffler, etc.) to ambient, and the exhaust system is simply a heat engine that does no useful work. The maximum fraction of fuel energy that can be extracted from the exhaust gas stream as useful work is (1-ηIC) × ηCarnot = 32% for TH = 850 K (exhaust) and TC = 370 K (coolant). This waste heat can be recovered using a heat engine such as a thermoelectric generator (TEG) with ηTEG> 0 in the exhaust system. A combined IC engine and TEG system can generate net useful work from the exhaust gas waste heat with efficiency ηWH = (1-ηIC) × ηCarnot ×ηTEG , and this will increase the overall fuel efficiency of the total system. Recent improvements in TEGs yield ηTEG values approaching 15% giving a potential total waste heat conversion efficiency of ηWH = 4.6%, which translates into a fuel economy improvement approaching 5%. This work is supported by the US DOE under DE-EE0005432.

  19. 30 CFR 36.49 - Tests of exhaust-gas dilution system.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Tests of exhaust-gas dilution system. 36.49 Section 36.49 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR TESTING... carbon dioxide, carbon monoxide, oxides of nitrogen, and aldehydes in the diluted exhaust shall be...

  20. 30 CFR 36.49 - Tests of exhaust-gas dilution system.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Tests of exhaust-gas dilution system. 36.49 Section 36.49 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR TESTING... carbon dioxide, carbon monoxide, oxides of nitrogen, and aldehydes in the diluted exhaust shall be...

  1. 40 CFR 86.1310-90 - Exhaust gas sampling and analytical system; diesel engines.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    .... (4) For methanol-fueled engines, cooling or reaction of the exhaust gases in the exhaust duct... unless compensation for varying flow rate is made). The sample collection lines shall be heated to a... overflow gas flow rates into the sample line shall be at least 105 percent of the sample system flow...

  2. 40 CFR 86.209-94 - Exhaust gas sampling system; gasoline-fueled vehicles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Exhaust gas sampling system; gasoline-fueled vehicles. 86.209-94 Section 86.209-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Trucks and New Medium-Duty Passenger Vehicles; Cold Temperature Test Procedures § 86.209-94 Exhaust...

  3. Interplay of air pollution and asthma immunopathogenesis: a focused review of diesel exhaust and ozone.

    PubMed

    Alexis, Neil E; Carlsten, Chris

    2014-11-01

    Controlled human exposure experiments with diesel exhaust particles (DEPs) and ozone serve to illustrate the important role pollutants play in modulating both allergic mechanisms and immune responses to affect the immunopathogenesis of airway diseases such as asthma. For DEP, evidence is stronger for the exacerbation of existing asthma rather than for the development of new disease. To the extent that this enhancement occurs, the augmentation of Th2-type immunity seems to be a common element. For ozone, neutrophilic inflammation, altered immune cell phenotype and function and oxidative stress are all marked responses that likely contribute to underlying immune-inflammatory features of asthma. Evidence is also emerging that unique gene signatures and epigenetic control of immune and inflammatory-based genes are playing important roles in the magnitude of the impact ozone is having on respiratory health. Indeed, the interplay between air pollutants such as DEP and ozone and asthma immunopathogenesis is an ongoing concern in terms of understanding how exposure to these agents can lead to worsening of disease. To this end, asthmatics may be pre-disposed to the deleterious effects of pollutants like ozone, having constitutively modified host defense functions and gene signatures. Although this review has utilized DEP and ozone as example pollutants, more research is needed to better understand the interplay between air pollution in general and asthma immumopathogenesis.

  4. 40 CFR 90.423 - Exhaust gas analytical system; CVS grab sample.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... converted to nitric oxide before analysis. Other types of analyzers may be used if shown to yield equivalent...)) for the measurement of oxides of nitrogen. The exhaust gas analytical system must conform to...

  5. Method for generating a highly reactive plasma for exhaust gas after treatment and enhanced catalyst reactivity

    SciTech Connect

    Whealton, John H.; Hanson, Gregory R.; Storey, John M.; Raridon, Richard J.; Armfield, Jeffrey S.; Bigelow, Timothy S.; Graves, Ronald L.

    2000-07-01

    This patent application describes a method and apparatus of exhaust gas remediation that enhance the reactivity of the material catalysts found within catalytic converters of cars, trucks, and power stations.

  6. 30 CFR 36.43 - Determination of exhaust-gas composition.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... of fuel consumption, pressures, temperatures, and other data significant in the safe operation of....45). The engine shall be at temperature equilibrium before exhaust-gas samples are collected or...

  7. 30 CFR 36.43 - Determination of exhaust-gas composition.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... of fuel consumption, pressures, temperatures, and other data significant in the safe operation of....45). The engine shall be at temperature equilibrium before exhaust-gas samples are collected or...

  8. 30 CFR 36.43 - Determination of exhaust-gas composition.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... of fuel consumption, pressures, temperatures, and other data significant in the safe operation of....45). The engine shall be at temperature equilibrium before exhaust-gas samples are collected or...

  9. Gas separation process using membranes with permeate sweep to remove CO.sub.2 from gaseous fuel combustion exhaust

    DOEpatents

    Wijmans Johannes G.; Merkel, Timothy C.; Baker, Richard W.

    2012-05-15

    A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

  10. High-Octane Fuel from Refinery Exhaust Gas: Upgrading Refinery Off-Gas to High-Octane Alkylate

    SciTech Connect

    2009-12-01

    Broad Funding Opportunity Announcement Project: Exelus is developing a method to convert olefins from oil refinery exhaust gas into alkylate, a clean-burning, high-octane component of gasoline. Traditionally, olefins must be separated from exhaust before they can be converted into another source of useful fuel. Exelus’ process uses catalysts that convert the olefin to alkylate without first separating it from the exhaust. The ability to turn up to 50% of exhaust directly into gasoline blends could result in an additional 46 million gallons of gasoline in the U.S. each year.

  11. Use of exhaust gas as sweep flow to enhance air separation membrane performance

    DOEpatents

    Dutart, Charles H.; Choi, Cathy Y.

    2003-01-01

    An intake air separation system for an internal combustion engine is provided with purge gas or sweep flow on the permeate side of separation membranes in the air separation device. Exhaust gas from the engine is used as a purge gas flow, to increase oxygen flux in the separation device without increasing the nitrogen flux.

  12. Glutathione peroxidase inhibitory assay for electrophilic pollutants in diesel exhaust and tobacco smoke.

    PubMed

    Staimer, Norbert; Nguyen, Tran B; Nizkorodov, Sergey A; Delfino, Ralph J

    2012-04-01

    We developed a rapid kinetic bioassay demonstrating the inhibition of glutathione peroxidase 1 (GPx-1) by organic electrophilic pollutants, such as acrolein, crotonaldehyde, and p-benzoquinone, that are frequently found as components of tobacco smoke, diesel exhaust, and other combustion sources. In a complementary approach, we applied a high-resolution proton-transfer reaction time-of-flight mass spectrometer to monitor in real-time the generation of electrophilic volatile carbonyls in cigarette smoke. The new bioassay uses the important antioxidant selenoenzyme GPx-1, immobilized to 96-well microtiter plates, as a probe. The selenocysteine bearing subunits of the enzyme's catalytic site are viewed as cysteine analogues and are vulnerable to electrophilic attack by compounds with conjugated carbonyl systems. The immobilization of GPx-1 to microtiter plate wells enabled facile removal of excess reactive inhibitory compounds after incubation with electrophilic chemicals or aqueous extracts of air samples derived from different sources. The inhibitory response of cigarette smoke and diesel exhaust particle extracts were compared with chemical standards of a group of electrophilic carbonyls and the arylating p-benzoquinone. GPx-1 activity was directly inactivated by millimolar concentrations of highly reactive electrophilic chemicals (including acrolein, glyoxal, methylglyoxal, and p-benzoquinone) and extracts of diesel and cigarette smoke. We conclude that the potential of air pollutant components to generate oxidative stress may be, in part, a result of electrophile-derived covalent modifications of enzymes involved in the cytosolic antioxidant defense.

  13. Use of gas-turbine exhaust for the direct drying of food products. Final report

    SciTech Connect

    Not Available

    1988-06-01

    This report describes an investigation of the use of gas-turbine exhaust as a substitute for conventional burners in the direct drying of food products. Four different equipment configurations were examined, including: diluting exhaust gases with air to achieve suitable temperatures; directing exhaust through a heat exchanger; moving the exhaust through a heat recovery boiler and then a drying system; and utilizing a conventional gas turbine cogeneration system. The study determined that diluting exhaust with air and the heat recovery boiler/drying system were economically attractive. The concern with direct drying using gas turbine exhaust is that the presence of elevated nitrogen oxides in the gas may be found in the food products or cause the formation of nitrosamines (a potent carcinogen) in these products. The study concluded that for direct drying using turbine exhaust to be commercialized for food products, either methods for reducing nitrogren oxides levels must be developed for the turbines of pilot tests combined with food-product analysis have to be performed.

  14. The effect of exhaust gas recirculation on the combustion noise level of an indirect injection diesel engine

    SciTech Connect

    Bowen, C.E.; Reader, G.T.; Potter, I.J.

    1997-12-31

    A pollutant that has not yet received as much public or regulatory attention as gaseous or solid particulate emissions is engine generated noise. Excessive levels of noise can, however, be as harmful to human health and the environment as noxious gases. In a well-designed engine, mechanical noise can be kept to a minimum but the combustion process itself still generates noise, combustion noise. Thus, if the combustion process is modified for exhaust emission control it can be expected that the level of noise generated by combustion will also be affected, albeit not necessarily adversely. As exhaust gas recirculation (EGR) is becoming an essential technology for NOx emission control in diesel engines, and, as this technique modifies the combustion process, it is important that the effects of using EGR on noise generation be identified.

  15. The effects of vehicular exhaust buoyancy during worst case pollution scenarios near roadways

    SciTech Connect

    Held, A.E.; Chang, D.P.Y.; Carroll, J.J.

    1998-12-31

    The California Department of Transportation (CALTRANS) has been using CALINE4, a gaussian finite line-source dispersion model, to estimate air pollutant concentrations near roadways given an estimate of traffic flow rates, vehicular emission factors, roadway geometry, and local meteorology. Modelers have typically used CALINE4 to simulate low wind near parallel thermally stable conditions to estimate a worst case pollution scenario (i.e., highest predicted pollutant concentrations) for a proposed roadway. In October 1995, the University of California, Davis (UCD), in conjunction with the CALTRANS Environmental Program, began a two-year investigation to determine if CALINE4 was adequately predicting CO concentrations during worst case meteorological conditions. Based on physical reasoning and a literature review of several highway dispersion studies conducted in the late 1970`s, it was reasoned that gaussian models may over-predict CO concentrations during worst case scenarios because these models do not adequately parameterize the increased vertical dispersion of pollutants due to vehicular emission buoyancy. To explore the role that exhaust buoyancy plays in roadway pollutant dispersion, a series of experiments were conducted on I-80 (near Sacramento) during winter pre-dawn commute hours. Results of the dispersion studies were inconclusive due to difficulty in capturing sufficiently low wind speed conditions during the sampling effort, however, in a compare-contrast study of field measurements versus CALINE4 predictions it was verified that CALINE4 adequately predicts both the magnitude and qualitative shape of non-worst case pollution scenarios. In addition, based on integrated mass flux from downwind CO concentration and wind profiles it was found that the use of CT-EMFAC, a regional scale emission factor model, overpredicted observed modal emissions by as much as 250 to 480%.

  16. Control method for turbocharged diesel engines having exhaust gas recirculation

    DOEpatents

    Kolmanovsky, Ilya V.; Jankovic, Mrdjan J; Jankovic, Miroslava

    2000-03-14

    A method of controlling the airflow into a compression ignition engine having an EGR and a VGT. The control strategy includes the steps of generating desired EGR and VGT turbine mass flow rates as a function of the desired and measured compressor mass airflow values and exhaust manifold pressure values. The desired compressor mass airflow and exhaust manifold pressure values are generated as a function of the operator-requested fueling rate and engine speed. The EGR and VGT turbine mass flow rates are then inverted to corresponding EGR and VGT actuator positions to achieve the desired compressor mass airflow rate and exhaust manifold pressure. The control strategy also includes a method of estimating the intake manifold pressure used in generating the EGR valve and VGT turbine positions.

  17. Turbine exhaust diffuser with region of reduced flow area and outer boundary gas flow

    DOEpatents

    Orosa, John

    2014-03-11

    An exhaust diffuser system and method for a turbine engine. The outer boundary may include a region in which the outer boundary extends radially inwardly toward the hub structure and may direct at least a portion of an exhaust flow in the diffuser toward the hub structure. At least one gas jet is provided including a jet exit located on the outer boundary. The jet exit may discharge a flow of gas downstream substantially parallel to an inner surface of the outer boundary to direct a portion of the exhaust flow in the diffuser toward the outer boundary to effect a radially outward flow of at least a portion of the exhaust gas flow toward the outer boundary to balance an aerodynamic load between the outer and inner boundaries.

  18. Aircraft engine exhaust emissions and other airport-related contributions to ambient air pollution: A review

    NASA Astrophysics Data System (ADS)

    Masiol, Mauro; Harrison, Roy M.

    2014-10-01

    Civil aviation is fast-growing (about +5% every year), mainly driven by the developing economies and globalisation. Its impact on the environment is heavily debated, particularly in relation to climate forcing attributed to emissions at cruising altitudes and the noise and the deterioration of air quality at ground-level due to airport operations. This latter environmental issue is of particular interest to the scientific community and policymakers, especially in relation to the breach of limit and target values for many air pollutants, mainly nitrogen oxides and particulate matter, near the busiest airports and the resulting consequences for public health. Despite the increased attention given to aircraft emissions at ground-level and air pollution in the vicinity of airports, many research gaps remain. Sources relevant to air quality include not only engine exhaust and non-exhaust emissions from aircraft, but also emissions from the units providing power to the aircraft on the ground, the traffic due to the airport ground service, maintenance work, heating facilities, fugitive vapours from refuelling operations, kitchens and restaurants for passengers and operators, intermodal transportation systems, and road traffic for transporting people and goods in and out to the airport. Many of these sources have received inadequate attention, despite their high potential for impact on air quality. This review aims to summarise the state-of-the-art research on aircraft and airport emissions and attempts to synthesise the results of studies that have addressed this issue. It also aims to describe the key characteristics of pollution, the impacts upon global and local air quality and to address the future potential of research by highlighting research needs.

  19. 40 CFR 86.1509 - Exhaust gas sampling system.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Regulations for Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Light-Duty Trucks; Idle...

  20. 40 CFR 86.1509 - Exhaust gas sampling system.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Regulations for Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Light-Duty Trucks; Idle...

  1. Experimental observation of carbon dioxide reduction in exhaust gas from hydrocarbon fuel burning

    SciTech Connect

    Uhm, Han S.; Kim, Chul H.

    2009-11-15

    A high-negative voltage at the cathode initiates a dark discharge, resulting in a reduction of the carbon dioxide concentration in exhaust gas from the burning of hydrocarbon fuel. An experiment indicated that nearly 44% of the carbon dioxide in exhaust gas disappears after a high-voltage application to the cathode. The energy needed for the endothermic reaction of the carbon dioxide dissociation corresponding to this concentration reduction is provided mainly by the internal energy reduction of the discharge gas, which is nearly 20 times the electrical energy for electron emission.

  2. Oxygen Smelting of Copper Concentrate With Exhaust SO2 Gas Recycling

    NASA Astrophysics Data System (ADS)

    Yazawa, Akira; Tozawa, Kazuteru

    1982-03-01

    In the conventional copper smelting process, the concentrate is usually oxidized by air, and heat is supplied by the combustion of fuel. Considerable dust and heat losses, due to the large quantity of exhaust gas, are inevitable. The use of oxygen greatly decreases such losses, but the copper matte grade is limited to around 50% to keep the furnace temperature at an optimum level. An oxygen smelting process, with exhaust SO2 recycling, is proposed based upon material and heat balance calculations. When 60% Cu matte is produced, the participating amounts of heat and gas are around 62% and 28% (14% if final gas is considered) of those of the conventional process. A considerable decrease in capital and operating costs can be expected when considering a new smelter. Because a small volume of high-strength SO2 exhaust gas is produced, this process has large flexibility with respect to sulfur by-products and offers a major advantage in environmentally sensitive locations.

  3. Exhaust Gas Modeling Effects on Hypersonic Powered Simulation at Mach 10

    NASA Technical Reports Server (NTRS)

    Tatum, Kenneth E.; Huebner, Lawrence D.

    1995-01-01

    A numerical study was performed to investigate the accuracy and validity of cold-gas simulation of actual hot scramjet exhaust within a Mach 10 free stream over a representative single-stage-to-orbit airbreathing configuration. In particular, exhausts of various noncombusting chemistry models were studied to characterize their effects on the vehicle aftbody performance and the plume flow field definition. Two approximations of the hot scramjet combustion products were utilized to determine the requirement for expensive, multi-species numerical modeling, and to establish a baseline for the validation of cold-gas simulation. Cold-gas simulation at Mach 10 is shown to be a viable technique using an appropriate thermally perfect gas mixture for reproducing hot scramjet exhaust effects.

  4. Method for generating a highly reactive plasma for exhaust gas aftertreatment and enhanced catalyst reactivity

    DOEpatents

    Whealton, John H.; Hanson, Gregory R.; Storey, John M.; Raridon, Richard J.; Armfield, Jeffrey S.; Bigelow, Timothy S.; Graves, Ronald L.

    2002-01-01

    A method for non-thermal plasma aftertreatment of exhaust gases the method comprising the steps of providing short risetime, high frequency, high power bursts of low-duty factor microwaves sufficient to generate a plasma discharge and passing a gas to be treated through the discharge so as to cause dissociative reduction of the exhaust gases and enhanced catalyst reactivity through application of the pulsed microwave fields directly to the catalyst material sufficient to cause a polarizability catastrophe and enhanced heating of the metal crystallite particles of the catalyst, and in the presence or absence of the plasma. The invention also includes a reactor for aftertreatment of exhaust gases.

  5. Workshop on an Assessment of Gas-Side Fouling in Fossil Fuel Exhaust Environments

    NASA Technical Reports Server (NTRS)

    Marner, W. J. (Editor); Webb, R. L. (Editor)

    1982-01-01

    The state of the art of gas side fouling in fossil fuel exhaust environments was assessed. Heat recovery applications were emphasized. The deleterious effects of gas side fouling including increased energy consumption, increased material losses, and loss of production were identified.

  6. Carbon dioxide capture and use: organic synthesis using carbon dioxide from exhaust gas.

    PubMed

    Kim, Seung Hyo; Kim, Kwang Hee; Hong, Soon Hyeok

    2014-01-13

    A carbon capture and use (CCU) strategy was applied to organic synthesis. Carbon dioxide (CO2) captured directly from exhaust gas was used for organic transformations as efficiently as hyper-pure CO2 gas from a commercial source, even for highly air- and moisture-sensitive reactions. The CO2 capturing aqueous ethanolamine solution could be recycled continuously without any diminished reaction efficiency.

  7. Diesel emission reduction using internal exhaust gas recirculation

    SciTech Connect

    He, Xin; Durrett, Russell P.

    2012-01-24

    A method for controlling combustion in a direct-injection diesel engine includes monitoring a crankshaft rotational position of a cylinder of the engine, monitoring an engine load, determining an intake stroke within the cylinder based upon the crankshaft rotational position, and when the engine load is less than a threshold engine load, opening an exhaust valve for the cylinder during a portion of the intake stroke.

  8. Method for generating a highly reactive plasma for exhaust gas aftertreatment and enhanced catalyst reactivity

    DOEpatents

    Whealton, John H.; Hanson, Gregory R.; Storey, John M.; Raridon, Richard J.; Armfield, Jeffrey S.; Bigelow, Timothy S.; Graves, Ronald L.

    2001-01-01

    A method for non-thermal plasma aftertreatment of exhaust gases the method comprising the steps of providing short risetime (about 40 ps), high frequency (about 5G hz), high power bursts of low-duty factor microwaves sufficient to generate a dielectric barrier discharge and passing a gas to treated through the discharge so as to cause dissociative reduction of the exhaust gases. The invention also includes a reactor for generating the non-thermal plasma.

  9. Low-pressure-ratio regenerative exhaust-heated gas turbine. Final report

    SciTech Connect

    Tampe, L.A.; Frenkel, R.G.; Kowalick, D.J.; Nahatis, H.M.; Silverstein, S.M.; Wilson, D.G.

    1991-01-01

    A design study of coal-burning gas-turbine engines using the exhaust-heated cycle and state-of-the-art components has been completed. In addition, some initial experiments on a type of rotary ceramic-matrix regenerator that would be used to transfer heat from the products of coal combustion in the hot turbine exhaust to the cool compressed air have been conducted. Highly favorable results have been obtained on all aspects on which definite conclusions could be drawn.

  10. 40 CFR 86.109-94 - Exhaust gas sampling system; Otto-cycle vehicles not requiring particulate emission measurements.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... vehicles, cooling of the exhaust gases in the duct connecting the vehicle tailpipe to the CVS shall be... and may be required for natural gas-fueled and liquefied petroleum gas-fueled vehicles. Procedures for.... Hearing the dilution air is also allowed, provided: (i) The air (or air plus exhaust gas) temperature...

  11. An Experimental Investigation of an Exhaust-gas-to-air Heat Exchanger for Use on Jet-stack-equipped Engines

    NASA Technical Reports Server (NTRS)

    Stalder, Jackson R; Spies, Ray J , Jr

    1948-01-01

    Tests were made to determine the loss in exhaust-jet thrust and engine power resulting from the insertion of an exhaust-gas-to-air heat exchanger in a jet-type exhaust stack of an aircraft engine. The thermal performance of the heat exchanger was also determined.

  12. FTIR Determination of Pollutants in Automobile Exhaust: An Environmental Chemistry Experiment Comparing Cold-Start and Warm-Engine Conditions

    ERIC Educational Resources Information Center

    Medhurst, Laura L.

    2005-01-01

    An experiment developed from the Advanced Integrated Environmental Laboratory illustrates the differences in automobile exhaust before and after the engine is warmed, using gas-phase Fourier transform infrared spectroscopy (FTIR). The apparatus consists of an Avatar 360 FTIR spectrometer from Nicolet fitted with a variable path length gas cell,…

  13. Thermoelectric exhaust-gas energy recovery: An integrated approach

    NASA Astrophysics Data System (ADS)

    Powell, A. V.; Kaltzoglou, A.; Vaqueiro, P.; Min, G.; Garcia-Cañadas, J.; Stobart, R. K.; Li, J.; Dong, G.; Wijewardane, A.

    2012-06-01

    Here we describe the first results from an interdisciplinary project that seeks to develop a skutterudite-based thermoelectric (TE) energy recovery system for a vehicle exhaust stream. Filled skutterudites have been prepared and characterised and their thermal stability evaluated. Thermoelements fabricated from these skutterudites have been used to evaluate the compatibility of materials required for the construction of TE modules. The results of modelling studies for the optimization of heat exchanger design and the creation of a component in the loop test facility are also described.

  14. Damage of natural stone tablets exposed to exhaust gas under laboratory conditions

    NASA Astrophysics Data System (ADS)

    Farkas, Orsolya; Szabados, György; Török, Ákos

    2016-04-01

    Natural stone tablets were exposed to exhaust gas under laboratory conditions to assess urban stone damage. Cylindrical test specimens (3 cm in diameter) were made from travertine, non-porous limestone, porous limestone, rhyolite tuff, sandstone, andesite, granite and marble. The samples were exposed to exhaust gas that was generated from diesel engine combustion (engine type: RÁBA D10 UTSLL 160, EURO II). The operating condition of the internal combustion engine was: 1300 r/m (app 50%). The exhaust gas was diverted into a pipe system where the samples were placed perpendicular to main flow for 1, 2, 4, 8 and 10 hours, respectively. The exhaust emission was measured by using AVL particulate measurement technology; filter paper method (AVL 415). The stone samples were documented and selective parameters were measured prior to and after exhaust gas exposure. Density, volume, ultrasonic pulse velocity, mineral composition and penetration depth of emission related particulate matter were recorded. The first results indicate that after 10 hours of exposure significant amount of particulate matter deposited on the stone surface independently from the surface properties and porosity. The black soot particles uniformly covered all types of stones, making hard to differentiate the specimens.

  15. Investigation of the Performance of HEMT-Based NO, NO₂ and NH₃ Exhaust Gas Sensors for Automotive Antipollution Systems.

    PubMed

    Halfaya, Yacine; Bishop, Chris; Soltani, Ali; Sundaram, Suresh; Aubry, Vincent; Voss, Paul L; Salvestrini, Jean-Paul; Ougazzaden, Abdallah

    2016-01-01

    We report improved sensitivity to NO, NO₂ and NH₃ gas with specially-designed AlGaN/GaN high electron mobility transistors (HEMT) that are suitable for operation in the harsh environment of diesel exhaust systems. The gate of the HEMT device is functionalized using a Pt catalyst for gas detection. We found that the performance of the sensors is enhanced at a temperature of 600 °C, and the measured sensitivity to 900 ppm-NO, 900 ppm-NO₂ and 15 ppm-NH₃ is 24%, 38.5% and 33%, respectively, at 600 °C. We also report dynamic response times as fast as 1 s for these three gases. Together, these results indicate that HEMT sensors could be used in a harsh environment with the ability to control an anti-pollution system in real time. PMID:26907298

  16. Investigation of the Performance of HEMT-Based NO, NO₂ and NH₃ Exhaust Gas Sensors for Automotive Antipollution Systems.

    PubMed

    Halfaya, Yacine; Bishop, Chris; Soltani, Ali; Sundaram, Suresh; Aubry, Vincent; Voss, Paul L; Salvestrini, Jean-Paul; Ougazzaden, Abdallah

    2016-02-23

    We report improved sensitivity to NO, NO₂ and NH₃ gas with specially-designed AlGaN/GaN high electron mobility transistors (HEMT) that are suitable for operation in the harsh environment of diesel exhaust systems. The gate of the HEMT device is functionalized using a Pt catalyst for gas detection. We found that the performance of the sensors is enhanced at a temperature of 600 °C, and the measured sensitivity to 900 ppm-NO, 900 ppm-NO₂ and 15 ppm-NH₃ is 24%, 38.5% and 33%, respectively, at 600 °C. We also report dynamic response times as fast as 1 s for these three gases. Together, these results indicate that HEMT sensors could be used in a harsh environment with the ability to control an anti-pollution system in real time.

  17. Performance of Blowdown Turbine Driven by Exhaust Gas of Nine-Cylinder Radial Engine

    NASA Technical Reports Server (NTRS)

    Turner, L Richard; Desmon, Leland G

    1944-01-01

    An investigation was made of an exhaust-gas turbine having four separate nozzle boxes each covering a 90 degree arc of the nozzle diaphragm and each connected to a pair of adjacent cylinders of a nine-cylinder radial engine. This type of turbine has been called a "blowdown" turbine because it recovers the kinetic energy developed in the exhaust stacks during the blowdown period, that is the first part of the exhaust process when the piston of the reciprocating engine is nearly stationary. The purpose of the investigation was to determine whether the blow turbine could develop appreciable power without imposing any large loss in engine power arising from restriction of the engine exhaust by the turbine.

  18. Influence of increased exhaust gas recirculation ratio on the thermodynamic processes in CI DI engine

    NASA Astrophysics Data System (ADS)

    Pielecha, I.; Skowron, M.; Bueschke, W.; Cieślik, W.; Wisłocki, K.

    2016-09-01

    The aim of the conducted research was the thermodynamic identification of combustion process involving up to 50-60% recirculated exhaust gasses in compression ignition engine. The values of the respective indicators obtained for the high share of exhaust gasses in the cylinder were compared to the values obtained in the engine working without EGR. The research was conducted on the single-cylinder AVL 5804 engine equipped with recirculated gas cooling system. The conditions of combustion process were determined using indicators of engine operation and measurements of fast-varying cylinder pressure. The evaluation of the influence of different share of exhaust gases in the cylinder on the combustion course and heat release was conducted. As a result of the conducted research the possibility of utilizing the high share of exhaust gasses (50-60%) with simultaneous ecological benefits, not only in relation to nitrogen oxides, was demonstrated.

  19. 40 CFR 86.1509 - Exhaust gas sampling system.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... carbon dioxide (CO2) analyzer as specified in 40 CFR part 1065 is required if the CVS system is used, in... Regulations for Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New...

  20. 40 CFR 86.1509 - Exhaust gas sampling system.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... carbon dioxide (CO2) analyzer as specified in 40 CFR part 1065 is required if the CVS system is used, in... Regulations for Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New...

  1. 40 CFR 86.1511 - Exhaust gas analysis system.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) Emission Regulations for Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New...

  2. 40 CFR 86.1511 - Exhaust gas analysis system.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) Emission Regulations for Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New...

  3. 40 CFR 86.1511 - Exhaust gas analysis system.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New Methanol-Fueled...

  4. 40 CFR 86.1509 - Exhaust gas sampling system.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... specified in 40 CFR part 1065 is permitted as applicable. The inclusion of an additional raw carbon dioxide... Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New Methanol-Fueled...

  5. Specific features of unsteady exhaustion of a gas-particle medium into vacuum

    NASA Astrophysics Data System (ADS)

    Sadin, D. V.; Varvarskii, V. M.

    2016-05-01

    Results of an analysis of two-dimensional unsteady exhaustion of a one-velocity gas-particle medium into vacuum for limiting equilibrium cases of heat transfer between the phases are reported. Domains of existence of a one-dimensional Riemann wave and a lateral expansion wave, as well as boundaries of the flow expansion region are determined. Under thermal equilibrium conditions, the reverse flow is found to occupy a large domain extending beyond the boundaries defined by angles of expansion for an ideal gas and for a gas-particle mixture with thermally insulated phases. Exhaustion of a nonequilibrium (in terms of velocities and temperatures) two-phase medium into vacuum is numerically simulated. It is demonstrated that a barrel-shaped structure with wave expansion of the gas and a combined discontinuity in the expanding gas-particle mixture is formed.

  6. A Mathematical Model for the Exhaust Gas Temperature Profile of a Diesel Engine

    NASA Astrophysics Data System (ADS)

    Brito, C. H. G.; Maia, C. B.; Sodré, J. R.

    2015-09-01

    This work presents a heat transfer model for the exhaust gas of a diesel power generator to determine the gas temperature profile in the exhaust pipe. The numerical methodology to solve the mathematical model was developed using a finite difference method approach for energy equation resolution and determination of temperature profiles considering turbulent fluid flow and variable fluid properties. The simulation was carried out for engine operation under loads from 0 kW to 40 kW. The model was compared with results obtained using the multidimensional Ansys CFX software, which was applied to solve the governor equations of turbulent fluid flow. The results for the temperature profiles in the exhaust pipe show a good proximity between the mathematical model developed and the multidimensional software.

  7. 40 CFR 86.210-08 - Exhaust gas sampling system; Diesel-cycle vehicles not requiring particulate emissions measurements.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Exhaust gas sampling system; Diesel-cycle vehicles not requiring particulate emissions measurements. 86.210-08 Section 86.210-08 Protection... Vehicles; Cold Temperature Test Procedures § 86.210-08 Exhaust gas sampling system; Diesel-cycle...

  8. 40 CFR 86.210-08 - Exhaust gas sampling system; Diesel-cycle vehicles not requiring particulate emissions measurements.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 19 2012-07-01 2012-07-01 false Exhaust gas sampling system; Diesel-cycle vehicles not requiring particulate emissions measurements. 86.210-08 Section 86.210-08 Protection... Vehicles; Cold Temperature Test Procedures § 86.210-08 Exhaust gas sampling system; Diesel-cycle...

  9. 30 CFR 36.49 - Tests of exhaust-gas dilution system.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Tests of exhaust-gas dilution system. 36.49 Section 36.49 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR TESTING, EVALUATION, AND APPROVAL OF MINING PRODUCTS APPROVAL REQUIREMENTS FOR PERMISSIBLE MOBILE DIESEL-POWERED TRANSPORTATION EQUIPMENT Test Requirements...

  10. 40 CFR 89.421 - Exhaust gas analytical system; CVS bag sample.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... converted to nitric oxide before analysis. Other types of analyzers may be used if shown to yield equivalent...) for the measurement of oxides of nitrogen. The exhaust gas analytical system shall conform to the... 40 CFR part 1065, subpart D.) (3) A CO instrument will be considered to be essentially free of...

  11. 40 CFR 91.423 - Exhaust gas analytical system; CVS grab sample.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... oxides of nitrogen. The exhaust gas analytical system shall conform to the following requirements: (1) The CLD (or HCLD) requires that the nitrogen dioxide present in the sample be converted to nitric oxide before analysis. Other types of analyzers may be used if shown to yield equivalent results and...

  12. 30 CFR 36.47 - Tests of exhaust-gas cooling system.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... cooling water shall be filled with the quantity of water recommended by the applicant. No cooling air... water consumption, high-water level when the system sprays excess water, and low-water level when the... saturation, if this temperature is lower. (d) Water consumed in cooling the exhaust gas under the...

  13. 30 CFR 36.47 - Tests of exhaust-gas cooling system.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... cooling water shall be filled with the quantity of water recommended by the applicant. No cooling air... water consumption, high-water level when the system sprays excess water, and low-water level when the... saturation, if this temperature is lower. (d) Water consumed in cooling the exhaust gas under the...

  14. 30 CFR 36.47 - Tests of exhaust-gas cooling system.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... cooling water shall be filled with the quantity of water recommended by the applicant. No cooling air... water consumption, high-water level when the system sprays excess water, and low-water level when the... saturation, if this temperature is lower. (d) Water consumed in cooling the exhaust gas under the...

  15. 40 CFR 90.423 - Exhaust gas analytical system; CVS grab sample.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...)) for the measurement of oxides of nitrogen. The exhaust gas analytical system must conform to the following requirements: (1) The CLD (or HCLD) requires that the nitrogen dioxide present in the sample be... essentially free of CO2 and water vapor interference, the use of the conditioning column may be deleted....

  16. 40 CFR 90.423 - Exhaust gas analytical system; CVS grab sample.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...)) for the measurement of oxides of nitrogen. The exhaust gas analytical system must conform to the following requirements: (1) The CLD (or HCLD) requires that the nitrogen dioxide present in the sample be... essentially free of CO2 and water vapor interference, the use of the conditioning column may be deleted....

  17. 40 CFR 91.423 - Exhaust gas analytical system; CVS grab sample.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... oxides of nitrogen. The exhaust gas analytical system shall conform to the following requirements: (1) The CLD (or HCLD) requires that the nitrogen dioxide present in the sample be converted to nitric... and water vapor interference, the use of the conditioning column may be deleted. (See §§ 91.317 and...

  18. 40 CFR 91.423 - Exhaust gas analytical system; CVS grab sample.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... oxides of nitrogen. The exhaust gas analytical system shall conform to the following requirements: (1) The CLD (or HCLD) requires that the nitrogen dioxide present in the sample be converted to nitric... and water vapor interference, the use of the conditioning column may be deleted. (See §§ 91.317 and...

  19. 40 CFR 91.423 - Exhaust gas analytical system; CVS grab sample.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... oxides of nitrogen. The exhaust gas analytical system shall conform to the following requirements: (1) The CLD (or HCLD) requires that the nitrogen dioxide present in the sample be converted to nitric... and water vapor interference, the use of the conditioning column may be deleted. (See §§ 91.317 and...

  20. 40 CFR 90.423 - Exhaust gas analytical system; CVS grab sample.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ...)) for the measurement of oxides of nitrogen. The exhaust gas analytical system must conform to the following requirements: (1) The CLD (or HCLD) requires that the nitrogen dioxide present in the sample be... essentially free of CO2 and water vapor interference, the use of the conditioning column may be deleted....

  1. 40 CFR 86.209-94 - Exhaust gas sampling system; gasoline-fueled vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Exhaust gas sampling system; gasoline... Emission Regulations for 1994 and Later Model Year Gasoline-Fueled New Light-Duty Vehicles, New Light-Duty... sampling system; gasoline-fueled vehicles. The provisions of § 86.109-90 apply to this subpart....

  2. 40 CFR 86.209-94 - Exhaust gas sampling system; gasoline-fueled vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... 40 Protection of Environment 19 2012-07-01 2012-07-01 false Exhaust gas sampling system; gasoline... Emission Regulations for 1994 and Later Model Year Gasoline-Fueled New Light-Duty Vehicles, New Light-Duty... sampling system; gasoline-fueled vehicles. The provisions of § 86.109-90 apply to this subpart....

  3. 40 CFR 86.209-94 - Exhaust gas sampling system; gasoline-fueled vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 19 2013-07-01 2013-07-01 false Exhaust gas sampling system; gasoline... Emission Regulations for 1994 and Later Model Year Gasoline-Fueled New Light-Duty Vehicles, New Light-Duty... sampling system; gasoline-fueled vehicles. The provisions of § 86.109-90 apply to this subpart....

  4. Method of producing monolithic catalyst for purification of exhaust gas

    SciTech Connect

    Sawamura, K.; Eto, Y.; Mine, J.; Masuda, K.

    1986-05-06

    A method is described of producing a monolithic catalyst for simultaneous oxidation of carbon monoxide and hydrocarbons and reduction of nitrogen oxides in exhaust gases of internal combustion engines, the method including the steps of providing an active alumina base coating to a monlithic carrier by treating the monolithic carrier with a coating slip in which an active alumina powder containing cerium oxide, which is formed by thermal decomposition of a cerium salt applied to the active alumina as a solution, is dispersed and then baking the treated carrier, and depositing at least one noble metal selected from the group consisting of Pt, Rh and Pd on the coating by thermal decomposition of an aqueous solution of a compound of each selected noble metal on the coating, characterized in that a ceria powder is additionally dispersed in the coating slip; wherein the amount of the ceria powder is such that, in the coating, Ce of the ceria powder amounts to 5 to 50% by weight of the coating, and wherin the content of Ce in the active alumina powder is in the range from 1 to 5% by weight.

  5. Characteristics and photochemical potentials of volatile organics emission from stack exhaust gas of industrial processes

    SciTech Connect

    Hsu, Y.C.; Tsai, J.H.; Lin, T.C.; Cheng, C.C.; Huang, Y.H.

    1999-07-01

    The main objective of this project was to measure the main volatile organic compounds (VOCs) in stack gas from the downstream petrochemical plants. Six pollution sources of industrial processes, including Acrylonitrile-Butadiene-Styrene (ABS), Vinyl Chloride(VC), Polyvinyl Chloride (PVC), Acrylic Resin, para-Terephthalic Acid (PTA) and Polyurethane (PU) synthetic manufacturing processes, were measured by using USEPA Method 18. The concentration and emission rate database of twenty-seven VOCs has been established. Fifty-two selected stacks were sampled and analyzed for VOCs. Analysis of emission factors and characteristics of the twenty-seven VOCs in these stacks show that the emission characteristics are various among different industrial processes. The order of the single-stack VOCs average emission factor are ABS (1.109 lbs VOCs/ton-ABS; 22 stacks) {gt} Acrylic Resin (0.651 lbs VOCs/ton-acrylic resin; 7 stacks) {gt} PU Synthetic (0.606 lbs VOCs/ton-PU synthetic; 4 stacks) {gt} PTA (0.054 lbs VOCs/ton-PTA; 4 stacks) {gt} PVC (0.014 lbs VOCs/ton-PVC; 11 stacks) {gt} VC ({lt} 0.001; 4 stacks) manufacturing processes. The emission factors of VOC in AP-42 database for the processes of are 5 to 40 times higher than those of VOCs in this research. Because of the equipment of pollutant control setting up before the emitted exhaust gas, their average emission factors in these measured processes are almost lower than those of VOCs in AP-42 database. Compared with the characteristics of VOCs, there is little similarity in VOC characteristics for the stacks of six processes between the results from this research and the data from US EPA SPECIATE data system. Furthermore, according to maximum incremental reactivities (MIR) of VOCs probed into photochemical reaction potentials, the results show that those of PTA manufacturing process have an ozone formation potential of 2.33 g O{sub 3}/g VOCs, which is higher than other processes.

  6. 40 CFR 86.111-94 - Exhaust gas analytical system.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ..., a heated particulate filter and a heated hydrocarbon instrument (HFID) complete with heated pump... liquefied petroleum gas-fueled diesel vehicles, the sample line and filter shall be heated to maintain a... methanol-fueled diesel-cycle vehicles, the sample line and filter shall be heated to maintain a sample...

  7. Method and apparatus to selectively reduce NO.sub.x in an exhaust gas feedstream

    DOEpatents

    Schmieg, Steven J.; Blint, Richard J.; Den, Ling; Viola, Michael B.; Lee, Jong-Hwan

    2011-08-30

    A method and apparatus are described to selectively reduce NO.sub.x emissions of an internal combustion engine. An exhaust aftertreatment system includes an injection device operative to dispense a hydrocarbon reductant upstream of a silver-alumina catalytic reactor device. A control system determines a NO.sub.x concentration and hydrocarbon/NOx ratio based upon selected parameters of the exhaust gas feedstream and dispenses hydrocarbon reductant during lean engine operation. Included is a method to control elements of the feedstream during lean operation. The hydrocarbon reductant may include engine fuel.

  8. Turbine exhaust diffuser with a gas jet producing a coanda effect flow control

    DOEpatents

    Orosa, John; Montgomery, Matthew

    2014-02-11

    An exhaust diffuser system and method for a turbine engine includes an inner boundary and an outer boundary with a flow path defined therebetween. The inner boundary is defined at least in part by a hub structure that has an upstream end and a downstream end. The outer boundary may include a region in which the outer boundary extends radially inward toward the hub structure and may direct at least a portion of an exhaust flow in the diffuser toward the hub structure. The hub structure includes at least one jet exit located on the hub structure adjacent to the upstream end of the tail cone. The jet exit discharges a flow of gas substantially tangential to an outer surface of the tail cone to produce a Coanda effect and direct a portion of the exhaust flow in the diffuser toward the inner boundary.

  9. Reduction of NOx and PM in marine diesel engine exhaust gas using microwave plasma

    NASA Astrophysics Data System (ADS)

    Balachandran, W.; FInst, P.; Manivannan, N.; Beleca, R.; Abbod, M.

    2015-10-01

    Abatement of NOx and particulate matters (PM) of marine diesel exhaust gas using microwave (MW) non-thermal plasma is presented in this paper. NOx mainly consist of NO and less concentration of NO2 in a typical two stoke marine diesel engine and microwave plasma generation can completely remove NO. MW was generated using two 2kW microwave sources and a saw tooth passive electrode. Passive electrode was used to generate high electric field region within microwave environment where high energetic electrons (1-3eV) are produced for the generation of non-thermal plasma (NTP). 2kW gen-set diesel exhaust gas was used to test our pilot-scale MW plasma reactor. The experimental results show that almost 100% removal of NO is possible for the exhaust gas flow rate of 60l/s. It was also shown that MW can significantly remove soot particles (PM, 10nm to 365nm) entrained in the exhaust gas of 200kW marine diesel engine with 40% engine load and gas flow rate of 130l/s. MW without generating plasma showed reduction up to 50% reduction of PM and with the plasma up to 90% reduction. The major challenge in these experiments was that igniting the desired plasma and sustaining it with passive electrodes for longer period (10s of minutes) as it required fine tuning of electrode position, which was influenced by many factors such as gas flow rate, geometry of reactor and MW power.

  10. The effect of EGR ratio on a spray combustion and emission[Exhaust Gas Recirculation

    SciTech Connect

    Ogawa, Hirokatsu; Ogiwara, Goro; Arai, Masataka

    1998-07-01

    It was widely known that preheating of primary air and EGR were effective to reduce NOx emission in a combustion system. Then the authors proposed the effective system of the external EGR for a spray combustion system such as a gas turbine combustor. In this paper, they tried to obtain various combustion characteristic related to the EGR effect. The EFR ratio was defined by the O{sub 2} concentrations of the EGR gas and the total inlet gas to which EGR gas was added. The combustion characteristics at 0% to 20% of the EGR ratio were measured to investigate the effect of the external EGR. The total inlet gas was the mixture, in which a fresh air was mixed with a hot burned gas recirculated externally. The O{sub 2} concentration in the total inlet gas decreased from 21% to 19%. The temperature of the total inlet gas increased from room temperature to about 110 C. The results showed that the combustion characteristics were improved by the EGR. At a high level of the EGR ratio, hot EGR gas promoted to vaporize the kerosene spray. This kerosene vapor and combustion air formed a homogeneous mixture gas which stabilized high intensity flame. It resulted flame stabilization in wide range of the EGR. Flame which was filled up fully in the combustion chamber was non-luminous flame like a gaseous fuel combustion. Also, the level of NO concentration in the exhaust gas was reduced. IN the flame of high EGR ratio, hot spots which caused NO formation in the flame were highly reduced. And the residence time in the combustion chamber was also reduced, because of the average sectional velocity increased with an increase of the recirculating gas flow in the system. So the maximum values of NO concentration in the combustion chamber were reduced in all cases of experimental conditions with EGR. The level of NO concentration in the exhaust gas was suppressed to about 60% compared with no EGR combustion states.

  11. Health effects of acute exposure to air pollution. Part I: Healthy and asthmatic subjects exposed to diesel exhaust.

    PubMed

    Holgate, Stephen T; Sandström, Thomas; Frew, Anthony J; Stenfors, Nikolai; Nördenhall, Charlotta; Salvi, Sundeep; Blomberg, Anders; Helleday, Ragnberth; Söderberg, Margaretha

    2003-12-01

    The purpose of this study was to assess the impact of short-term exposure to diluted diesel exhaust on inflammatory parameters in human airways. We previously exposed control subjects for 1 hour to a high ambient concentration of diesel exhaust (particle concentration 300 pg/m3--a level comparable with that found in North Sea ferries, highway underpasses, etc). Although these exposures did not have any measurable effect on standard indices of lung function, there was a marked neutrophilic inflammatory response in the airways accompanied by increases in blood neutrophil and platelet counts. Endothelial adhesion molecules were upregulated, and the expression of interleukin 8 messenger RNA (IL-8 mRNA*) was increased in a pattern consistent with neutrophilia. Individuals with asthma have inflamed airways and are clinically more sensitive to air pollutants than are control subjects. The present study was designed to assess whether this clinical sensitivity can be explained by acute neutrophilic inflammation or an increase in allergic airway inflammation resulting from diesel exhaust exposure. For this study, we used a lower concentration of diesel exhaust (100 microg/m3 PM10) for a 2-hour exposure. At this concentration, both the control subjects and those with asthma demonstrated a modest but statistically significant increase in airway resistance following exposure to diesel exhaust. This increase in airway resistance was associated with an increased number of neutrophils in the bronchial wash (BW) fluid obtained from control subjects (median after diesel exhaust 22.0 vs median after air 17.2; P = 0.015), as well as an increase in lymphocytes obtained through bronchoalveolar lavage (BAL) (15.0% after diesel exhaust vs 12.3% after air; P = 0.017). Upregulation of the endothelial adhesion molecule P-selectin was noted in bronchial biopsy tissues from control subjects (65.4% of vessels after diesel exhaust vs 52.5% after air). There was also a significant increase in IL

  12. Thermoelectric Power Generation System for Future Hybrid Vehicles Using Hot Exhaust Gas

    NASA Astrophysics Data System (ADS)

    Kim, Sun-Kook; Won, Byeong-Cheol; Rhi, Seok-Ho; Kim, Shi-Ho; Yoo, Jeong-Ho; Jang, Ju-Chan

    2011-05-01

    The present experimental and computational study investigates a new exhaust gas waste heat recovery system for hybrid vehicles, using a thermoelectric module (TEM) and heat pipes to produce electric power. It proposes a new thermoelectric generation (TEG) system, working with heat pipes to produce electricity from a limited hot surface area. The current TEG system is directly connected to the exhaust pipe, and the amount of electricity generated by the TEMs is directly proportional to their heated area. Current exhaust pipes fail to offer a sufficiently large hot surface area for the high-efficiency waste heat recovery required. To overcome this, a new TEG system has been designed to have an enlarged hot surface area by the addition of ten heat pipes, which act as highly efficient heat transfer devices and can transmit the heat to many TEMs. As designed, this new waste heat recovery system produces a maximum 350 W when the hot exhaust gas heats the evaporator surface of the heat pipe to 170°C; this promises great possibilities for application of this technology in future energy-efficient hybrid vehicles.

  13. 40 CFR 86.1309-90 - Exhaust gas sampling system; Otto-cycle and non-petroleum-fueled engines.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... gasoline-fueled, natural gas-fueled, liquefied petroleum gas-fueled or methanol-fueled engines. In the CVS... uncharacterized CVS, addition of an unknown inlet restriction on the dilution air, etc.). (2) The gas mixture... allowed. Heating is also allowed, provided: (i) The air (or air plus exhaust gas) temperature does...

  14. 4-Nitrophenol, 1-nitropyrene, and 9-nitroanthracene emissions in exhaust particles from diesel vehicles with different exhaust gas treatments

    NASA Astrophysics Data System (ADS)

    Inomata, Satoshi; Fushimi, Akihiro; Sato, Kei; Fujitani, Yuji; Yamada, Hiroyuki

    2015-06-01

    The dependence of nitro-organic compound emissions in automotive exhaust particles on the type of aftertreatment used was investigated. Three diesel vehicles with different aftertreatment systems (an oxidation catalyst, vehicle-DOC; a particulate matter and NOx reduction system, vehicle-DPNR; and a urea-based selective catalytic reduction system, vehicle-SCR) and a gasoline car with a three-way catalyst were tested. Nitro-polycyclic aromatic hydrocarbons (nitro-PAHs) and nitrophenols in the particles emitted were analyzed by thermal desorption gas chromatography/mass spectrometry and liquid chromatography/mass spectrometry. The secondary production of nitro-organic compounds on the filters used to collect particles and the adsorption of gaseous nitro-organic compounds by the filters were evaluated. Emissions of 1-nitropyrene, 9-nitroanthracene, and 4-nitrophenol in the diesel exhaust particles were then quantified. The NOx reduction process in vehicle-DPNR appeared to remove nitro-hydrocarbons efficiently but not to remove nitro-oxygenated hydrocarbons efficiently. The nitro-PAH emission factors were lower for vehicle-DOC when it was not fitted with a catalyst than when it was fitted with a catalyst. The 4-nitrophenol emission factors were also lower for vehicle-DOC with a catalyst than vehicle-DOC without a catalyst, suggesting that the oxidation catalyst was a source of both nitro-PAHs and 4-nitrophenol. The time-resolved aerosol mass spectrometry data suggested that nitro-organic compounds are mainly produced when an engine is working under load. The presence of 4-nitrophenol in the particles was not confirmed statistically because of interference from gaseous 4-nitrophenol. Systematic errors in the estimated amounts of gaseous 1-nitropyrene and 9-nitroanthracene adsorbed onto the filters and the estimated amounts of volatile nitro-organic compounds that evaporated during sampling and during post-sampling conditioning could not be excluded. An analytical method

  15. Diagnosing system for an exhaust gas recirculation system of an automotive engine

    SciTech Connect

    Tamura, I.

    1988-02-09

    This patent describes a diagnosing system for an exhaust gas recirculation system having an EGR passage communicating an exhaust pipe of an engine with an intake passage of the engine, an EGR valve provided in the EGR passage, control means for opening the EGR valve in accordance with enigne operating conditions comprising: first means for detecting flow rate of recirculated gas in the EGR passage and for producing an actual EGR rate signal dependent on the flow rate; second means for producing a desired EGR rate signal including an allowable range in accordance with engine operating conditions; and third means responsive to the actual EGR rate signal and the desired EGR rate signal for producing a trouble signal as an alarm signal when the actual EGR rate signal is out of the allowable range.

  16. Apparatus for measuring rotor exhaust gas bulk temperature in a combustion turbine and method therefore

    SciTech Connect

    Allen, J.M.

    1993-07-13

    Apparatus is described for measuring rotor exhaust gas bulk total temperature in a combustion turbine which includes first and last stages of rotating turbine blades comprising: optical pyrometer means for measuring the circumferentially total gas averaged temperature relative to said last stage turbine blades at a plurality of common radial points from the turbine hub to tip where said optical pyrometer means includes a single optical pyrometer having a line of sight along with means for rotating such pyrometer around an axis of rotation, with the pyrometer being tilted from said axis so that the line of sight of said pyrometer rotates around said axis thereby providing a radial traverse of said last stage turbine blades; means for calculating said rotor exhaust bulk total temperature relative to said last stage blades by flow weight averaging said measured temperatures of said radial points.

  17. Real-time measurement of nitrogen dioxide in vehicle exhaust gas by mid-infrared cavity ring-down spectroscopy

    NASA Astrophysics Data System (ADS)

    Yamamoto, Y.; Sumizawa, H.; Yamada, H.; Tonokura, K.

    2011-12-01

    The application of pulsed cavity ring-down spectroscopy (CRDS) was demonstrated for the measurement of nitrogen dioxide (NO2) in automotive exhaust gas. The transition of the ν 3 vibrational band assigned to the antisymmetric stretching mode of NO2 was probed with a thermoelectrically cooled, pulsed, mid-infrared, distributed feedback, quantum cascade laser (QCL) at 6.13 μm. The measurement of NO2 in the exhaust gas from two diesel vehicles equipped with different aftertreatment devices was demonstrated using a CRDS-based NO2 sensor, which employs a HEPA filter and a membrane gas dryer to remove interference from water as well as particulates in the exhaust gas. Stable and sensitive measurement of NO2 in the exhaust gas was achieved for more than 30 minutes with a time resolution of 1 s.

  18. 40 CFR 86.1309-90 - Exhaust gas sampling system; Otto-cycle and non-petroleum-fueled engines.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... HIGHWAY VEHICLES AND ENGINES (CONTINUED) Emission Regulations for New Otto-Cycle and Diesel Heavy-Duty Engines; Gaseous and Particulate Exhaust Test Procedures § 86.1309-90 Exhaust gas sampling system; Otto... including the systems described in § 86.1310 for petroleum-fueled diesel engines may be used if shown...

  19. 40 CFR Table 1 to Subpart Ja of... - Molar Exhaust Volumes and Molar Heat Content of Fuel Gas Constituents

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 40 Protection of Environment 7 2013-07-01 2013-07-01 false Molar Exhaust Volumes and Molar Heat... Exhaust Volumes and Molar Heat Content of Fuel Gas Constituents Constituent MEVa dscf/mol MHCb Btu/mol... standard conditions of 68 °F and 1 atmosphere. b MHC = molar heat content (higher heating value basis),...

  20. 40 CFR Table 1 to Subpart Ja of... - Molar Exhaust Volumes and Molar Heat Content of Fuel Gas Constituents

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... 40 Protection of Environment 7 2014-07-01 2014-07-01 false Molar Exhaust Volumes and Molar Heat... Exhaust Volumes and Molar Heat Content of Fuel Gas Constituents Constituent MEVa dscf/mol MHCb Btu/mol... standard conditions of 68 °F and 1 atmosphere. b MHC = molar heat content (higher heating value basis),...

  1. The significance of vehicle emissions standards for levels of exhaust pollution from light vehicles in an urban area

    NASA Astrophysics Data System (ADS)

    Rhys-Tyler, G. A.; Legassick, W.; Bell, M. C.

    2011-06-01

    This paper addresses the research question "Are more stringent exhaust emissions standards, as applied to light vehicle type approval, resulting in reduced vehicle pollution in an urban area?" The exhaust emissions of a sample of over fifty thousand road vehicles operating in London were measured using roadside remote sensing absorption spectroscopy techniques (infrared and ultraviolet), combined with Automatic Number Plate Recognition for vehicle identification. Levels of carbon monoxide (CO), hydrocarbons (HC), nitric oxide (NO), and smoke (particulate) exhaust emissions are reported by vehicle class, fuel type, and Euro emissions standard. Emissions from petrol cars of each pollutant were all observed to display a statistically significant reduction with the introduction of each successive Euro emissions standard from Euro 1 onwards. However, Euro 2 diesel cars were observed to emit statistically higher rates of NO than either Euro 1 or Euro 3 standard diesel cars. The study also confirms the continuing 'dieselisation' of the UK passenger car fleet. Mean NO emissions from Euro 4 diesel cars were found to be 6 times higher than Euro 4 petrol cars, highlighting the need to develop a sound understanding of the current and future 'in-use' emissions characteristics of diesel vehicles, and their influence on local air quality. Smoke emissions from TXII London taxis (black cabs) were found to be statistically higher than either earlier TX1 or later TX4 model variants, with possible implications for local air quality policy interventions such as maximum age limits for taxis.

  2. The Measurement of Fuel-Air Ratio by Analysis for the Oxidized Exhaust Gas

    NASA Technical Reports Server (NTRS)

    Gerrish, Harold C.; Meem, J. Lawrence, Jr.

    1943-01-01

    An investigation was made to determine a method of measuring fuel-air ratio that could be used for test purposes in flight and for checking conventional equipment in the laboratory. Two single-cylinder test engines equipped with typical commercial engine cylinders were used. The fuel-air ratio of the mixture delivered to the engines was determined by direct measurement of the quantity of air and of fuel supplied and also by analysis of the oxidized exhaust gas and of the normal exhaust gas. Five fuels were used: gasoline that complied with Army-Navy fuel Specification No. AN-VV-F-781 and four mixtures of this gasoline with toluene, benzene, and xylene. The method of determining the fuel-air ratio described in this report involves the measurement of the carbon-dioxide content of the oxidized exhaust gas and the use of graphs for the presented equation. This method is considered useful in aircraft, in the field, or in the laboratory for a range of fuel-air ratios from 0.047 to 0.124.

  3. The Measurement of Fuel-air Ratio by Analysis of the Oxidized Exhaust Gas

    NASA Technical Reports Server (NTRS)

    Memm, J. Lawrence, Jr.

    1943-01-01

    An investigation was made to determine a method of measuring fuel-air ratio that could be used for test purposes in flight and for checking conventional equipment in the laboratory. Two single-cylinder test engines equipped with typical commercial engine cylinders were used. The fuel-air ratio of the mixture delivered to the engines was determined by direct measurement of the quantity of air and of fuel supplied and also by analysis of the oxidized exhaust gas and of the normal exhaust gas. Five fuels were used: gasoline that complied with Army-Navy Fuel Specification, No. AN-VV-F-781 and four mixtures of this gasoline with toluene, benzene, and xylene. The method of determining the fuel-air ratio described in this report involves the measurement of the carbon-dioxide content of the oxidized exhaust gas and the use of graphs or the presented equation. This method is considered useful in aircraft, in the field, or in the laboratory for a range of fuel-air ratios from 0.047 to 0.124

  4. Source reconciliation of atmospheric gas-phase and particle-phase pollutants during a severe photochemical smog episode.

    PubMed

    Schauer, James J; Fraser, Matthew P; Cass, Glen R; Simoneit, Bernd R T

    2002-09-01

    A comprehensive organic compound-based receptor model is developed that can simultaneously apportion the source contributions to atmospheric gas-phase organic compounds, semivolatile organic compounds, fine particle organic compounds, and fine particle mass. The model is applied to ambient data collected at four sites in the south coast region of California during a severe summertime photochemical smog episode, where the model determines the direct primary contributions to atmospheric pollutants from 11 distinct air pollution source types. The 11 sources included in the model are gasoline-powered motor vehicle exhaust, diesel engine exhaust, whole gasoline vapors, gasoline headspace vapors, organic solvent vapors, whole diesel fuel, paved road dust, tire wear debris, meat cooking exhaust, natural gas leakage, and vegetative detritus. Gasoline engine exhaust plus whole gasoline vapors are the predominant sources of volatile organic gases, while gasoline and diesel engine exhaust plus diesel fuel vapors dominate the emissions of semivolatile organic compounds from these sources during the episode studied at all four air monitoring sites. The atmospheric fine particle organic compound mass was composed of noticeable contributions from gasoline-powered motor vehicle exhaust, diesel engine exhaust, meat cooking, and paved road dust with smaller but quantifiable contributions from vegetative detritus and tire wear debris. In addition, secondary organic aerosol, which is formed from the low-vapor pressure products of gas-phase chemical reactions, is found to be a major source of fine particle organic compound mass under the severe photochemical smog conditions studied here. The concentrations of secondary organic aerosol calculated in the present study are compared with previous fine particle source apportionment results for less intense photochemical smog conditions. It is shown that estimated secondary organic aerosol concentrations correlate fairly well with the

  5. Integrated exhaust gas analysis system for aircraft turbine engine component testing

    NASA Technical Reports Server (NTRS)

    Summers, R. L.; Anderson, R. C.

    1985-01-01

    An integrated exhaust gas analysis system was designed and installed in the hot-section facility at the Lewis Research Center. The system is designed to operate either manually or automatically and also to be operated from a remote station. The system measures oxygen, water vapor, total hydrocarbons, carbon monoxide, carbon dioxide, and oxides of nitrogen. Two microprocessors control the system and the analyzers, collect data and process them into engineering units, and present the data to the facility computers and the system operator. Within the design of this system there are innovative concepts and procedures that are of general interest and application to other gas analysis tasks.

  6. A Gas Chromatograph/Mass Spectrometer System for UltraLow-Emission Combustor Exhaust Studies

    NASA Technical Reports Server (NTRS)

    Brabbs, Theodore A.; Wey, Chowen Chou

    1996-01-01

    A gas chromatograph (GC)/mass spectrometer (MS) system that allows the speciation of unburnt hydrocarbons in the combustor exhaust has been developed at the NASA Lewis Research Center. Combustion gas samples are withdrawn through a water-cooled sampling probe which, when not in use, is protected from contamination by a high-pressure nitrogen purge. The sample line and its connecting lines, filters, and valves are all ultraclean and are heated to avoid condensation. The system has resolution to the parts-per-billion (ppb) level.

  7. Effects of Exhaust Gas Recirculation on SI Engines at Wide Open Throttle

    NASA Astrophysics Data System (ADS)

    Bronson, Sydney; Puzinauskas, Paulius

    2011-11-01

    Exhaust gas recirculation, a charge dilution technique, has proven to be an effective method of reducing NOx emissions and fuel consumption of spark ignition engines. Wide open throttle operation also increases overall engine efficiency by reducing the pumping losses caused by throttling. In this study, the emissions and fuel economy benefits of exhaust gas recirculation (EGR) at wide open throttle conditions were quantified using a 2.4L port-injected engine. Engine performance and emissions data were recorded as the percentage of EGR in the intake charge was increased from zero to just above thirty percent (the EGR limit). This EGR percentage, in-cylinder pressure measurements, and the temperatures and pressures of the intake and exhaust were all recorded to ensure stable operating conditions. These tests were performed with a stoichiometric air-fuel ratio at a constant speed of 2000 rpm at wide open throttle. The variation of brake specific fuel consumption and emissions (in particular NOx) with increasing EGR percentages was analyzed.

  8. Collection and analysis of organic acids in exhaust gas. Comparison of different methods

    NASA Astrophysics Data System (ADS)

    Zervas, E.; Montagne, X.; Lahaye, J.

    This paper reports the development of a specific method to identify organic acids in exhaust gases. The organic acids are collected in two impingers containing liquids (pure water or Na 2CO 3 1% aqueous solution) and four cartridges containing solids (silica, fluorisil, alumina B and alumina N). Once collected, the acids are eluted of the solids by a hot water stream. These traps performances, in terms of organic acids collection and elution efficiency, are evaluated and compared. Two sources are used to produce the gas flow containing organic acids: one generates a flow whose concentration is known and stable, the other produces organic acids among other combustion products. For eluted solutions analysis, two methods are used: isocratic ionic chromatography/conductivity detection and GC/FID. Their efficiency in separating 10 aliphatic acids are compared. Their characteristics such as detection limits, detection linearity, repeatability and possible interferences with other components found in exhaust gases are determined. The stability of the organic acids solutions is also studied. Lastly, the use of these methods is illustrated by the analysis of the gas-phase organic acids exhausted by a spark ignition and by a diesel engine.

  9. [Pollution Characteristics of Aldehydes and Ketones Compounds in the Exhaust of Beijing Typical Restaurants].

    PubMed

    Cheng, Jing-chen; Cui, Tong; He, Wan-qing; Nie, Lei; Wang, Jun-ling; Pan, Tao

    2015-08-01

    Aldehydes and ketones compounds, as one of the components in the exhaust of restaurants, are a class of volatile organic compounds (VOCs) with strong chemical reactivity. However, there is no systematic study on aldehydes and ketones compounds in the exhaust of restaurants. To further clarify the food source emission levels of aldehydes and ketones compounds and controlling measures, to access city group catering VOCs emissions control decision-making basis, this study selected 8 Beijing restaurants with different types. The aldehydes and ketones compounds were sampled using DNPH-silica tube, and then ultra performance liquid chromatography was used for quantitative measurement. The aldehydes and ketones concentrations of reference volume condition from 8 restaurants in descending order were Roasted Duck restaurant, Chinese Style Barbecue, Home Dishes, Western Fast-food, School Canteen, Chinese Style Fast-food, Sichuan Cuisine, Huaiyang Cuisine. The results showed that the range of aldehydes and ketones compounds (C1-C9) concentrations of reference volume condition in the exhaust of restaurants was 115.47-1035.99 microg x m(-3). The composition of aldehydes and ketones compounds in the exhaust of sampled restaurants was obviously different. The percentages of C1-C3 were above 40% in the exhaust from Chinese style restaurants. Fast food might emit more C4-C9 aldehydes and ketones compounds. From the current situation of existing aldehydes and ketones compounds control, the removal efficiency of high voltage electrostatic purifiers widely used in Beijing is limited.

  10. Catalysts as sensors--a promising novel approach in automotive exhaust gas aftertreatment.

    PubMed

    Moos, Ralf

    2010-01-01

    Sensors that detect directly and in situ the status of automotive exhaust gas catalysts by monitoring the electrical properties of the catalyst coating itself are overviewed. Examples included in this review are the in-situ determination of the electrical impedance of three-way catalysts based on ceria-zirconia solutions and of lean NO(x) traps of earth-alkaline based coatings, as well as approaches to determine the ammonia loading in Fe-SCR-zeolites with electrical ac measurements. Even more sophisticated approaches based on interactions with electromagnetic waves are also reviewed. For that purpose, metallic stick-like antennas are inserted into the exhaust pipe. The catalyst properties are measured in a contactless manner, directly indicating the catalyst status. The radio frequency probes gauge the oxygen loading degree of three-way catalysts, the NO(x)-loading of lean NO(x) traps, and the soot loading of Diesel particulate filters. PMID:22163575

  11. Catalysts as Sensors—A Promising Novel Approach in Automotive Exhaust Gas Aftertreatment

    PubMed Central

    Moos, Ralf

    2010-01-01

    Sensors that detect directly and in situ the status of automotive exhaust gas catalysts by monitoring the electrical properties of the catalyst coating itself are overviewed. Examples included in this review are the in-situ determination of the electrical impedance of three-way catalysts based on ceria-zirconia solutions and of lean NOx traps of earth-alkaline based coatings, as well as approaches to determine the ammonia loading in Fe-SCR-zeolites with electrical ac measurements. Even more sophisticated approaches based on interactions with electromagnetic waves are also reviewed. For that purpose, metallic stick-like antennas are inserted into the exhaust pipe. The catalyst properties are measured in a contactless manner, directly indicating the catalyst status. The radio frequency probes gauge the oxygen loading degree of three-way catalysts, the NOx-loading of lean NOx traps, and the soot loading of Diesel particulate filters. PMID:22163575

  12. Catalysts as sensors--a promising novel approach in automotive exhaust gas aftertreatment.

    PubMed

    Moos, Ralf

    2010-01-01

    Sensors that detect directly and in situ the status of automotive exhaust gas catalysts by monitoring the electrical properties of the catalyst coating itself are overviewed. Examples included in this review are the in-situ determination of the electrical impedance of three-way catalysts based on ceria-zirconia solutions and of lean NO(x) traps of earth-alkaline based coatings, as well as approaches to determine the ammonia loading in Fe-SCR-zeolites with electrical ac measurements. Even more sophisticated approaches based on interactions with electromagnetic waves are also reviewed. For that purpose, metallic stick-like antennas are inserted into the exhaust pipe. The catalyst properties are measured in a contactless manner, directly indicating the catalyst status. The radio frequency probes gauge the oxygen loading degree of three-way catalysts, the NO(x)-loading of lean NO(x) traps, and the soot loading of Diesel particulate filters.

  13. Environmental policy constraints for acidic exhaust gas scrubber discharges from ships.

    PubMed

    Ülpre, H; Eames, I

    2014-11-15

    Increasingly stringent environmental legislation on sulphur oxide emissions from the combustion of fossil fuels onboard ships (International Maritime Organization (IMO) Regulation 14) can be met by either refining the fuel to reduce sulphur content or by scrubbing the exhaust gases. Commonly used open loop marine scrubbers discharge warm acidic exhaust gas wash water into the sea, depressing its pH. The focus on this paper is on the physics and chemistry behind the disposal of acidic discharges in seawater. The IMO Marine Environment Protection Committee (MEPC 59/24/Add.1 Annex 9) requires the wash water to reach a pH greater than 6.5 at a distance of 4m from the point of discharge. We examine the engineering constraints, specifically size and number of ports, to identify the challenges of meeting regulatory compliance. PMID:25284442

  14. Environmental policy constraints for acidic exhaust gas scrubber discharges from ships.

    PubMed

    Ülpre, H; Eames, I

    2014-11-15

    Increasingly stringent environmental legislation on sulphur oxide emissions from the combustion of fossil fuels onboard ships (International Maritime Organization (IMO) Regulation 14) can be met by either refining the fuel to reduce sulphur content or by scrubbing the exhaust gases. Commonly used open loop marine scrubbers discharge warm acidic exhaust gas wash water into the sea, depressing its pH. The focus on this paper is on the physics and chemistry behind the disposal of acidic discharges in seawater. The IMO Marine Environment Protection Committee (MEPC 59/24/Add.1 Annex 9) requires the wash water to reach a pH greater than 6.5 at a distance of 4m from the point of discharge. We examine the engineering constraints, specifically size and number of ports, to identify the challenges of meeting regulatory compliance.

  15. Exhaust-Gas Pressure and Temperature Survey of F404-GE-400 Turbofan Engine

    NASA Technical Reports Server (NTRS)

    Walton, James T.; Burcham, Frank W., Jr.

    1986-01-01

    An exhaust-gas pressure and temperature survey of the General Electric F404-GE-400 turbofan engine was conducted in the altitude test facility of the NASA Lewis Propulsion System Laboratory. Traversals by a survey rake were made across the exhaust-nozzle exit to measure the pitot pressure and total temperature. Tests were performed at Mach 0.87 and a 24,000-ft altitude and at Mach 0.30 and a 30,000-ft altitude with various power settings from intermediate to maximum afterburning. Data yielded smooth pressure and temperature profiles with maximum jet temperatures approximately 1.4 in. inside the nozzle edge and maximum jet temperatures from 1 to 3 in. inside the edge. A low-pressure region located exactly at engine center was noted. The maximum temperature encountered was 3800 R.

  16. Application of local exhaust ventilation system and integrated collectors for control of air pollutants in mining company.

    PubMed

    Ghorbani Shahna, Farshid; Bahrami, Abdulrahman; Farasati, Farhad

    2012-01-01

    Local exhaust ventilation (LEV) systems and integrated collectors were designed and implemented in a mining company in order to control emitted air pollutant from furnaces. The LEV was designed for capture and transition of air pollutants emitted from furnaces to the integrated collectors. The integrated collectors including four high efficiency Stairmand model cyclones for control of particulate matter, a venturi scrubber for control of the fine particles, SO(2) and a part of H(2)S to follow them, and a packed scrubber for treatment of the residual H(2)S and SO(2) were designed. Pollutants concentration were measured to determine system effectiveness. The results showed that the effectiveness of LEV for reducing workplace pollution is 91.83%, 96.32% and 83.67% for dust, SO(2) and H(2)S, respectively. Average removal efficiency of particles by combination of cyclone and venturi scrubber was 98.72%. Average removal efficiency of SO(2) and H(2)S were 95.85% and 47.13% for the venturi scrubber and 68.45% and 92.7% for the packed bed scrubber. The average removal efficiency of SO(2) and H(2)S were increased to 99.1% and 95.95% by the combination of venturi and packed bed scrubbers. According to the results, integrated collectors are a good air pollution control option for industries with economic constraints and ancient technologies. PMID:22878358

  17. The Natural Gas Vehicle Challenge '92: Exhaust emissions testing and results

    SciTech Connect

    Rimkus, W.A.; Larsen, R.P. ); Zammit, M.G. ); Davies, J.G.; Salmon, G.S. ); Bruetsch, R.I. )

    1992-01-01

    The Natural Gas Vehicle (NGV) Challenge '92, was organized by Argonne National Laboratory. The main sponsors were the US Department of Energy the Energy, Mines, and Resources -- Canada, and the Society of Automotive Engineers. It resulted in 20 varied approaches to the conversion of a gasoline-fueled, spark-ignited, internal combustion engine to dedicated natural gas use. Starting with a GMC Sierra 2500 pickup truck donated by General Motors, teams of college and university student engineers worked to optimize Chevrolet V-8 engines operating on natural gas for improved emissions, fuel economy, performance, and advanced design features. This paper focuses on the results of the emission event, and compares engine mechanical configurations, engine management systems, catalyst configurations and locations, and approaches to fuel control and the relationship of these parameters to engine. out and tailpipe emissions of regulated exhaust constituents. Nine of the student modified trucks passed the current levels of exhaust emission standards, and some exceeded the strictest future emissions standards envisioned by the US Environmental Protection Agency. Factors contributing to good emissions control using natural gas are summarized, and observations concerning necessary components of a successful emissions control strategy are presented.

  18. The Natural Gas Vehicle Challenge `92: Exhaust emissions testing and results

    SciTech Connect

    Rimkus, W.A.; Larsen, R.P.; Zammit, M.G.; Davies, J.G.; Salmon, G.S.; Bruetsch, R.I.

    1992-11-01

    The Natural Gas Vehicle (NGV) Challenge `92, was organized by Argonne National Laboratory. The main sponsors were the US Department of Energy the Energy, Mines, and Resources -- Canada, and the Society of Automotive Engineers. It resulted in 20 varied approaches to the conversion of a gasoline-fueled, spark-ignited, internal combustion engine to dedicated natural gas use. Starting with a GMC Sierra 2500 pickup truck donated by General Motors, teams of college and university student engineers worked to optimize Chevrolet V-8 engines operating on natural gas for improved emissions, fuel economy, performance, and advanced design features. This paper focuses on the results of the emission event, and compares engine mechanical configurations, engine management systems, catalyst configurations and locations, and approaches to fuel control and the relationship of these parameters to engine. out and tailpipe emissions of regulated exhaust constituents. Nine of the student modified trucks passed the current levels of exhaust emission standards, and some exceeded the strictest future emissions standards envisioned by the US Environmental Protection Agency. Factors contributing to good emissions control using natural gas are summarized, and observations concerning necessary components of a successful emissions control strategy are presented.

  19. Role of snow and cold environment in the fate and effects of nanoparticles and select organic pollutants from gasoline engine exhaust.

    PubMed

    Nazarenko, Yevgen; Kurien, Uday; Nepotchatykh, Oleg; Rangel-Alvarado, Rodrigo B; Ariya, Parisa A

    2016-02-01

    Exposure to vehicle exhaust can drive up to 70 % of excess lifetime cancer incidences due to air pollution in urban environments. Little is known about how exhaust-derived particles and organic pollutants, implicated in adverse health effects, are affected by freezing ambient temperatures and the presence of snow. Airborne particles and (semi)volatile organic constituents in dilute exhaust were studied in a novel low-temperature environmental chamber system containing natural urban snow under controlled cold environmental conditions. The presence of snow altered the aerosol size distributions of dilute exhaust in the 10 nm to 10 μm range and decreased the number density of the nanoparticulate (<100 nm) fraction of exhaust aerosols, yet increased the 100-150 nm fraction. Upon 1 hour exhaust exposure, the total organic carbon increased in the natural snow from 0.218 ± 0.014 to 0.539 ± 0.009 mg L(-1), and over 40 additional (semi)volatile organic compounds and a large number of exhaust-derived carbonaceous and likely organic particles were identified. The concentrations of benzene, toluene, ethylbenzene, and xylenes (BTEX) increased from near the detection limit to 52.48, 379.5, 242.7, and 238.1 μg kg(-1) (± 10 %), respectively, indicating the absorption of exhaust-derived toxic organic compounds by snow. The alteration of exhaust aerosol size distributions at freezing temperatures and in the presence of snow, accompanied by changes of the organic pollutant content in snow, has potential to alter health effects of human exposure to vehicle exhaust. PMID:26758961

  20. Role of snow and cold environment in the fate and effects of nanoparticles and select organic pollutants from gasoline engine exhaust.

    PubMed

    Nazarenko, Yevgen; Kurien, Uday; Nepotchatykh, Oleg; Rangel-Alvarado, Rodrigo B; Ariya, Parisa A

    2016-02-01

    Exposure to vehicle exhaust can drive up to 70 % of excess lifetime cancer incidences due to air pollution in urban environments. Little is known about how exhaust-derived particles and organic pollutants, implicated in adverse health effects, are affected by freezing ambient temperatures and the presence of snow. Airborne particles and (semi)volatile organic constituents in dilute exhaust were studied in a novel low-temperature environmental chamber system containing natural urban snow under controlled cold environmental conditions. The presence of snow altered the aerosol size distributions of dilute exhaust in the 10 nm to 10 μm range and decreased the number density of the nanoparticulate (<100 nm) fraction of exhaust aerosols, yet increased the 100-150 nm fraction. Upon 1 hour exhaust exposure, the total organic carbon increased in the natural snow from 0.218 ± 0.014 to 0.539 ± 0.009 mg L(-1), and over 40 additional (semi)volatile organic compounds and a large number of exhaust-derived carbonaceous and likely organic particles were identified. The concentrations of benzene, toluene, ethylbenzene, and xylenes (BTEX) increased from near the detection limit to 52.48, 379.5, 242.7, and 238.1 μg kg(-1) (± 10 %), respectively, indicating the absorption of exhaust-derived toxic organic compounds by snow. The alteration of exhaust aerosol size distributions at freezing temperatures and in the presence of snow, accompanied by changes of the organic pollutant content in snow, has potential to alter health effects of human exposure to vehicle exhaust.

  1. Variable-geometry turbocharger with asymmetric divided volute for engine exhaust gas pulse optimization

    DOEpatents

    Serres, Nicolas

    2010-11-09

    A turbine assembly for a variable-geometry turbocharger includes a turbine housing defining a divided volute having first and second scrolls, wherein the first scroll has a substantially smaller volume than the second scroll. The first scroll feeds exhaust gas to a first portion of a turbine wheel upstream of the throat of the wheel, while the second scroll feeds gas to a second portion of the wheel at least part of which is downstream of the throat. Flow from the second scroll is regulated by a sliding piston. The first scroll can be optimized for low-flow conditions such that the turbocharger can operate effectively like a small fixed-geometry turbocharger when the piston is closed. The turbine housing defines an inlet that is divided by a dividing wall into two portions respectively feeding gas to the two scrolls, a leading edge of the dividing wall being downstream of the inlet mouth.

  2. Multiple Exhaust Nozzle Effects on J-2X Gas Generator Outlet Impedance

    NASA Technical Reports Server (NTRS)

    Kenny, R. Jeremy; Muss, Jeffrey; Hulka, James R.; Casiano, Matthew

    2010-01-01

    The current test setup of the J-2X gas generator system uses a multiple nozzle configuration to exhaust hot gases to drive the propellant supply turbines. Combustion stability assessment of this gas generator design requires knowledge of the impedance effects the multiple nozzle configuration creates on the combustion chamber acoustic modes. Parallel work between NASA and Sierra Engineering is presented, showing two methods used to calculate the effective end impedance resulting from multiple nozzle configurations. The NASA method is a simple estimate of the effective impedance using the long wavelength approximation. Sierra Engineering has developed a more robust numerical integration method implemented in ROCCID to accommodate for multiple nozzles. Analysis using both methods are compared to J-2X gas generator test data collected over the past year.

  3. Estimation and validation of PM 2.5/PM 10 exhaust and non-exhaust emission factors for practical street pollution modelling

    NASA Astrophysics Data System (ADS)

    Ketzel, Matthias; Omstedt, Gunnar; Johansson, Christer; Düring, Ingo; Pohjola, Mia; Oettl, Dietmar; Gidhagen, Lars; Wåhlin, Peter; Lohmeyer, Achim; Haakana, Mervi; Berkowicz, Ruwim

    In order to carry out efficient traffic and air quality management, validated models and PM emission estimates are needed. This paper compares current available emission factor estimates for PM 10 and PM 2.5 from emission databases and different emission models, and validates these against eight high quality street pollution measurements in Denmark, Sweden, Germany, Finland and Austria. The data sets show large variation of the PM concentration and emission factors with season and with location. Consistently at all roads the PM 10 and PM 2.5 emission factors are lower in the summer month than the rest of the year. For example, PM 10 emission factors are in average 5-45% lower during the month 6-10 compared to the annual average. The range of observed total emission factors (including non-exhaust emissions) for the different sites during summer conditions are 80-130 mg km -1 for PM 10, 30-60 mg km -1 for PM 2.5 and 20-50 mg km -1 for the exhaust emissions. We present two different strategies regarding modelling of PM emissions: (1) For Nordic conditions with strong seasonal variations due to studded tyres and the use of sand/salt as anti-skid treatment a time varying emission model is needed. An empirical model accounting for these Nordic conditions was previously developed in Sweden. (2) For other roads with a less pronounced seasonal variation (e.g. in Denmark, Germany, Austria) methods using a constant emission factor maybe appropriate. Two models are presented here. Further, we apply the different emission models to data sets outside the original countries. For example, we apply the "Swedish" model for two streets without studded tyre usage and the "German" model for Nordic data sets. The "Swedish" empirical model performs best for streets with studded tyre use, but was not able to improve the correlation versus measurements in comparison to using constant emission factors for the Danish side. The "German" method performed well for the streets without clear

  4. Exhaust gas monitoring based on absorption spectroscopy in the process industry

    NASA Astrophysics Data System (ADS)

    Zhang, Shuai; Liu, Wen-qing; Zhang, Yu-jun; Shu, Xiao-wen; Kan, Rui-feng; Cui, Yi-ben; He, Ying; Xu, Zhen-yu; Geng, Hui; Liu, Jian-guo

    2009-07-01

    This non-invasive gas monitor for exhaust gas monitoring must has high reliability and requires little maintenance. Monitor for in-situ measurements using tunable diode laser absorption spectroscopy (TDLAS) in the near infrared, can meet these requirements. TDLAS has evolved over the past decade from a laboratory especially to an accepted, robust and reliable technology for trace gas sensing. With the features of tunability and narrow linewidth of the distributed feedback (DFB) diode laser and by precisely tuning the laser output wavelength to a single isolated absorption line of the gas, TDLAS technique can be utilized to measure gas concentration with high sensitivity. Typical applications for monitoring of H2S, NH3, HC1 and HF are described here together by wavelength modulation spectroscopy with second-harmonic(WMS-2F) detection. This paper will illustrate the problems related to on-line applications, in particular, the overfall effects, automatic light intensity correction, temperature correction, which impacted on absorption coefficient and give details of how effect of automatic correction is necessary. The system mainly includes optics and electronics, optical system mainly composed of fiber, fiber coupler and beam expander, the electron part has been placed in safe analysis room not together with the optical part. Laser merely passes through one-meter-long pipes by the fiber coupling technology, so the system itself has anti-explosion. The results of the system are also presented in the end, the system's response time is only 0.5s, and can be achieved below 1×10-5 the detection limit at the volume fraction, it can entirely replace the traditional methods of detection exhaust gas in the process industry.

  5. High Speed H2O Concentration Measurements Using Absorption Spectroscopy to Monitor Exhaust Gas

    SciTech Connect

    Kranendonk, Laura; Parks, II, James E; Prikhodko, Vitaly Y; Partridge Jr, William P

    2008-01-01

    This paper demonstrates the potential for fast absorption spectroscopy measurements in diesel-engine exhaust to track H2O concentration transients. Wavelength-agile absorption spectroscopy is an optical technique that measures broadband absorption spectra between 10kHz and 100 MHz. From these measured spectra, gas temperature and absorber concentration can be determined. The Fourier-domain mode-locking (FDML) laser is becoming recognized as one of the most robust and reliable wavelength-agile sources available. H2O concentration measurements during combustion events at crank angle resolved speeds are beneficial for a wide variety of applications, such as product improvements for industry, control and reliability checks for experimental researchers, and measures of fit for numerical simulations. The difficulties associated with measuring diesel exhaust compared to in-cylinder measurements are discussed. A full description of the experimental configuration and data processing is explained. Measurements of engine exhaust H2O transients with 10- s temporal resolution are presented for a range of engine conditions.

  6. Use of a remote plasma source for CVD chamber clean and exhaust gas abatement applications

    SciTech Connect

    Holber, W.; Chen, X.; Smith, D.; Besen, M.

    1999-07-01

    Remote plasma sources have traditionally been used in semiconductor processing applications such as dry removal of photoresist, where the capability of delivering a large flux of atomic oxygen into a semiconductor process chamber, with little of the associated plasma used to dissociate the oxygen, has made them attractive. With the development of fluorine-compatible remote plasma sources, a range of new application opportunities has opened up. In remote cleaning of CVD chambers, the remote plasma source is positioned before the process chamber, and a stream of atomic fluorine from the source is flowed into the chamber, where it can effectively clean a wide variety of materials such as SiO{sub 2}, Si{sub 3}N{sub 4}, and W. The cleaning process is purely chemical, with no associated in-situ plasma which can cause degradation of the process chamber. In exhaust gas abatement, the remote plasma source is located between the outlet of the etch or deposition process chamber and the mechanical pump. By adding appropriate gases, the exhaust stream from the chamber can be converted to form which can be managed more readily. Using a robust toroidal plasma source design, the ASTRON{trademark} remote plasma source has been used to address both of these areas. As an atomic fluorine source, over the typical operating range of 2--10 Torr several SLM of gases such as NF{sub 3} can be fully dissociated. As an exhaust gas abatement device, with operating pressure in the 0.1--1.0 Torr regime, abatement of perfluorocompounds (PFC's) at greater than 95% levels has been demonstrated. Using a variety of techniques--FTIR, RGA, and sample etching--the operation of this source technology and issues such as transport of atomic fluorine over substantial distances has been investigated.

  7. Fuel composition and secondary organic aerosol formation: gas-turbine exhaust and alternative aviation fuels.

    PubMed

    Miracolo, Marissa A; Drozd, Greg T; Jathar, Shantanu H; Presto, Albert A; Lipsky, Eric M; Corporan, Edwin; Robinson, Allen L

    2012-08-01

    A series of smog chamber experiments were performed to investigate the effects of fuel composition on secondary particulate matter (PM) formation from dilute exhaust from a T63 gas-turbine engine. Tests were performed at idle and cruise loads with the engine fueled on conventional military jet fuel (JP-8), Fischer-Tropsch synthetic jet fuel (FT), and a 50/50 blend of the two fuels. Emissions were sampled into a portable smog chamber and exposed to sunlight or artificial UV light to initiate photo-oxidation. Similar to previous studies, neat FT fuel and a 50/50 FT/JP-8 blend reduced the primary particulate matter emissions compared to neat JP-8. After only one hour of photo-oxidation at typical atmospheric OH levels, the secondary PM production in dilute exhaust exceeded primary PM emissions, except when operating the engine at high load on FT fuel. Therefore, accounting for secondary PM production should be considered when assessing the contribution of gas-turbine engine emissions to ambient PM levels. FT fuel substantially reduced secondary PM formation in dilute exhaust compared to neat JP-8 at both idle and cruise loads. At idle load, the secondary PM formation was reduced by a factor of 20 with the use of neat FT fuel, and a factor of 2 with the use of the blend fuel. At cruise load, the use of FT fuel resulted in no measured formation of secondary PM. In every experiment, the secondary PM was dominated by organics with minor contributions from sulfate when the engine was operated on JP-8 fuel. At both loads, FT fuel produces less secondary organic aerosol than JP-8 because of differences in the composition of the fuels and the resultant emissions. This work indicates that fuel reformulation may be a viable strategy to reduce the contribution of emissions from combustion systems to secondary organic aerosol production and ultimately ambient PM levels. PMID:22732009

  8. Fuel composition and secondary organic aerosol formation: gas-turbine exhaust and alternative aviation fuels.

    PubMed

    Miracolo, Marissa A; Drozd, Greg T; Jathar, Shantanu H; Presto, Albert A; Lipsky, Eric M; Corporan, Edwin; Robinson, Allen L

    2012-08-01

    A series of smog chamber experiments were performed to investigate the effects of fuel composition on secondary particulate matter (PM) formation from dilute exhaust from a T63 gas-turbine engine. Tests were performed at idle and cruise loads with the engine fueled on conventional military jet fuel (JP-8), Fischer-Tropsch synthetic jet fuel (FT), and a 50/50 blend of the two fuels. Emissions were sampled into a portable smog chamber and exposed to sunlight or artificial UV light to initiate photo-oxidation. Similar to previous studies, neat FT fuel and a 50/50 FT/JP-8 blend reduced the primary particulate matter emissions compared to neat JP-8. After only one hour of photo-oxidation at typical atmospheric OH levels, the secondary PM production in dilute exhaust exceeded primary PM emissions, except when operating the engine at high load on FT fuel. Therefore, accounting for secondary PM production should be considered when assessing the contribution of gas-turbine engine emissions to ambient PM levels. FT fuel substantially reduced secondary PM formation in dilute exhaust compared to neat JP-8 at both idle and cruise loads. At idle load, the secondary PM formation was reduced by a factor of 20 with the use of neat FT fuel, and a factor of 2 with the use of the blend fuel. At cruise load, the use of FT fuel resulted in no measured formation of secondary PM. In every experiment, the secondary PM was dominated by organics with minor contributions from sulfate when the engine was operated on JP-8 fuel. At both loads, FT fuel produces less secondary organic aerosol than JP-8 because of differences in the composition of the fuels and the resultant emissions. This work indicates that fuel reformulation may be a viable strategy to reduce the contribution of emissions from combustion systems to secondary organic aerosol production and ultimately ambient PM levels.

  9. Exhaust-gas measurements from NASAs HYMETS arc jet.

    SciTech Connect

    Miller, Paul Albert

    2010-11-01

    Arc-jet wind tunnels produce conditions simulating high-altitude hypersonic flight such as occurs upon entry of space craft into planetary atmospheres. They have traditionally been used to study flight in Earth's atmosphere, which consists mostly of nitrogen and oxygen. NASA is presently using arc jets to study entry into Mars' atmosphere, which consists of carbon dioxide and nitrogen. In both cases, a wide variety of chemical reactions take place among the gas constituents and with test articles placed in the flow. In support of those studies, we made measurements using a residual gas analyzer (RGA) that sampled the exhaust stream of a NASA arc jet. The experiments were conducted at the HYMETS arc jet (Hypersonic Materials Environmental Test System) located at the NASA Langley Research Center, Hampton, VA. This report describes our RGA measurements, which are intended to be used for model validation in combination with similar measurements on other systems.

  10. Use of exhaust gas recirculation as a control approach for thermoacoustic instabilities

    SciTech Connect

    Ranalli, J.; Ferguson, D.

    2011-10-09

    Investigation into exhaust gas recirculation (EGR) as a method for reducing costs of postcombustion carbon capture in gas turbine systems reveals that EGR offers potential applications as a control strategy for thermoacoustic instabilities. Introduction of EGR allows semi-independent variation of the operating parameter of flame temperature and characteristic flame length scales, known to play a primary role in the phase of the thermoacoustic coupling mechanism. Measurements were made showing the ability of EGR to reduce the amplitude of thermoacoustic oscillations over a range of operating conditions in a laboratory scale, swirled dump combustor, without affecting the flame temperature. Theoretical analysis was also performed to investigate the limitations on the ability of this approach to influence dynamics.

  11. Experimental studies of the dilution of vehicle exhaust pollutants by environment-protecting pervious pavement.

    PubMed

    Liu, Chung-Ming; Chen, Jui-Wen; Tsai, Jen-Hui; Lin, Wei-Shian; Yen, M-T; Chen, Ting-Hao

    2012-01-01

    This study determines whether environment-protecting pervious pavement can dilute pollutants immediately after emissions from vehicle. The turbulence-driven dry-deposition process is too slow to be considered in this aspect. The pavement used is the JW pavement (according to its inventors name), a high-load-bearing water-permeable pavement with patents in over 100 countries, which has already been used for more than 8 years in Taiwan and is well suited to replacing conventional road pavement, making the potential implementation of the study results feasible. The design of this study included two sets of experiments. Variation of the air pollutant concentrations within a fenced area over the JW pavement with one vehicle discharging emissions into was monitored and compared with results over a non-JW pavement. The ambient wind speed was low during the first experiment, and the results obtained were highly credible. It was found that the JW pavement diluted vehicle pollutant emissions near the ground surface by 40%-87% within 5 min of emission; whereas the data at 2 m height suggested that about 58%-97% of pollutants were trapped underneath the pavement 20 min after emission. Those quantitative estimations may be off by +/- 10%, if errors in emissions and measurements were considered. SO2 and CO2 underwent the most significant reduction. Very likely, pollutants were forced to move underneath due to the special design of the pavement. During the second experiment, ambient wind speeds were high and the results obtained had less credibility, but they did not disprove the pollutant dilution capacity of the JW pavement. In order to track the fate of pollutants, parts of the pavement were removed to reveal a micro version of wetland underneath, which could possibly hold the responsibility of absorbing and decomposing pollutants to forms harmless to the environment and human health.

  12. Integrated capture of fossil fuel gas pollutants including CO.sub.2 with energy recovery

    DOEpatents

    Ochs, Thomas L.; Summers, Cathy A.; Gerdemann, Steve; Oryshchyn, Danylo B.; Turner, Paul; Patrick, Brian R.

    2011-10-18

    A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO.sub.x, residual NO.sub.x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N.sub.2 and O.sub.2 if CO2 purification is needed. The final product stream is a mixture comprising predominantly CO.sub.2 with smaller amounts of H.sub.2O, Ar, N.sub.2, O.sub.2, SO.sub.X, NO.sub.X, Hg, and other trace gases.

  13. Method for simultaneously removing SO.sub.2 and NO.sub.X pollutants from exhaust of a combustion system

    DOEpatents

    Levendis, Yiannis A.; Wise, Donald L.

    1994-05-17

    A method is disclosed for removing pollutants from the exhaust of combustion systems burning fuels containing substantial amounts of sulfur and nitrogen. An exemplary method of the invention involves the formation and reaction of a sorbent comprising calcium magnesium acetate (CMA). The CMA is either dry-sprayed (in the form of a fine powder) or wet-sprayed in an aqueous solution in a high temperature environment such as a combustion chamber. The latter technique is feasible since CMA is a uniquely water-soluble form of calcium and magnesium. When the dispersed particles of CMA are heated to a high temperature, fine calcium and magnesium oxide particles, which are hollow with thin and highly porous walls are formed, affording optimum external and internal accessibility for reacting with toxic gaseous emissions such as SO.sub.2. Further, the combustion of the organic acetate portion of the sorbent results in the conversion of NO.sub.x to N.sub.2.

  14. Design of a diesel exhaust-gas purification system for inert-gas drilling

    SciTech Connect

    Caskey, B.C.

    1982-01-01

    To combat the serious oxygen corrosion of drill pipe when a low density drilling fluid (air or mist) is used in geothermal drilling, a system has been designed that produces an inert gas (essentially nitrogen) to be substituted for air. The system fits on three flatbed trailers, is roadable and produces 2000 scfm of gas. The projected cost for gas is slightly less than $2.00 per thousand standard cubic feet.

  15. Effects of lead pollution from vehicular exhaust fumes against sentinel juvenile Achatina achatina.

    PubMed

    Ebenso, I E; Ologhobo, A D

    2008-11-01

    We investigated lead metal pollution induced by traffic fumes along roads with differing traffic intensity near abandoned battery factory (Niger Delta, Nigeria). Juvenile Achatina achatina were positioned as sentinels in plastic snaileries 2 m on road sides. Lead contamination in snail tissue by atomic absorption spectrophotometer increased with increasing vehicular traffic intensity. Snails showed low positive (r (2) = 0.40) relationship and significant (p < 0.05) accumulation of atmospheric lead pollution. Edible snails sold along road sides are prone to lead contamination. PMID:18784896

  16. Toward gas exhaustion in the W51 high-mass protoclusters

    NASA Astrophysics Data System (ADS)

    Ginsburg, A.; Goss, W. M.; Goddi, C.; Galván-Madrid, R.; Dale, J. E.; Bally, J.; Battersby, C. D.; Youngblood, A.; Sankrit, R.; Smith, R.; Darling, J.; Kruijssen, J. M. D.; Liu, H. B.

    2016-10-01

    We present new JVLA observations of the high-mass cluster-forming region W51A from 2 to 16 GHz with resolution θfwhm ≈ 0.3-0.5″. The data reveal a wealth of observational results: (1) Currently forming, very massive (proto-O) stars are traced by o - H2CO21,1-21,2 emission, suggesting that this line can be used efficiently as a massive protostar tracer; (2) there is a spatially distributed population of ≲mJy continuum sources, including hypercompact H ii regions and candidate colliding wind binaries, in and around the W51 proto-clusters; and (3) there are two clearly detected protoclusters, W51e and W51 IRS2, that are gas-rich but may have most of their mass in stars within their inner ≲0.05 pc. The majority of the bolometric luminosity in W51 most likely comes from a third population of OB stars between these clusters. The presence of a substantial population of exposed O-stars coincident with a population of still-forming massive stars, together with a direct measurement of the low mass loss rate via ionized gas outflow from W51 IRS2, implies that feedback is ineffective at halting star formation in massive protoclusters. Instead, feedback may shut off the large-scale accretion of diffuse gas onto the W51 protoclusters, implying that they are evolving toward a state of gas exhaustion rather than gas expulsion. Recent theoretical models predict gas exhaustion to be a necessary step in the formation of gravitationally bound stellar clusters, and our results provide an observational validation of this process. This paper and all related analysis code are available on the web at http://https://github.com/adamginsburg/paper_w51_evlaTable A.1 and final data (FITS files) are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/595/A27

  17. Investigation of the Performance of HEMT-Based NO, NO2 and NH3 Exhaust Gas Sensors for Automotive Antipollution Systems

    PubMed Central

    Halfaya, Yacine; Bishop, Chris; Soltani, Ali; Sundaram, Suresh; Aubry, Vincent; Voss, Paul L.; Salvestrini, Jean-Paul; Ougazzaden, Abdallah

    2016-01-01

    We report improved sensitivity to NO, NO2 and NH3 gas with specially-designed AlGaN/GaN high electron mobility transistors (HEMT) that are suitable for operation in the harsh environment of diesel exhaust systems. The gate of the HEMT device is functionalized using a Pt catalyst for gas detection. We found that the performance of the sensors is enhanced at a temperature of 600 °C, and the measured sensitivity to 900 ppm-NO, 900 ppm-NO2 and 15 ppm-NH3 is 24%, 38.5% and 33%, respectively, at 600 °C. We also report dynamic response times as fast as 1 s for these three gases. Together, these results indicate that HEMT sensors could be used in a harsh environment with the ability to control an anti-pollution system in real time. PMID:26907298

  18. Effect of the Sequence of the Thermoelectric Generator and the Three-Way Catalytic Converter on Exhaust Gas Conversion Efficiency

    NASA Astrophysics Data System (ADS)

    Su, Chuqi; Tong, Naiqiang; Xu, Yuman; Chen, Shan; Liu, Xun

    2013-07-01

    The potential for thermoelectric exhaust heat recovery in vehicles has increased with recent improvements in the efficiency of thermoelectric generators (TEGs). The problem with using thermoelectric generators for vehicle applications is whether the device is compatible with the original vehicle exhaust system, which determines the quality of the exhaust gas treatment and the realization of energy conservation and emission reduction. Based on ANSYS CFX simulation analysis of the impact of two positional relationships between the TEG and three-way catalytic converter in the exhaust system on the working efficiency of both elements, it is concluded that the layout with the front three-way catalytic converter has an advantage over the other layout mode under current conditions. New ideas for an improvement program are proposed to provide the basis for further research.

  19. Platform for a hydrocarbon exhaust gas sensor utilizing a pumping cell and a conductometric sensor.

    PubMed

    Biskupski, Diana; Geupel, Andrea; Wiesner, Kerstin; Fleischer, Maximilian; Moos, Ralf

    2009-01-01

    Very often, high-temperature operated gas sensors are cross-sensitive to oxygen and/or they cannot be operated in oxygen-deficient (rich) atmospheres. For instance, some metal oxides like Ga(2)O(3) or doped SrTiO(3) are excellent materials for conductometric hydrocarbon detection in the rough atmosphere of automotive exhausts, but have to be operated preferably at a constant oxygen concentration. We propose a modular sensor platform that combines a conductometric two-sensor-setup with an electrochemical pumping cell made of YSZ to establish a constant oxygen concentration in the ambient of the conductometric sensor film. In this paper, the platform is introduced, the two-sensor-setup is integrated into this new design, and sensing performance is characterized. Such a platform can be used for other sensor principles as well. PMID:22423212

  20. Effect of operating conditions on the exhaust emissions from a gas turbine combustor

    NASA Technical Reports Server (NTRS)

    Briehl, D.; Papathakos, L.; Strancar, R. J.

    1972-01-01

    Exhaust concentrations of total unburned hydrocarbons, carbon monoxide, and nitric oxide were measured from a single J-57 combustor liner installed in a 30 diameter test section. Tests were conducted over a range of inlet total pressures from 1 to 20 atmospheres, inlet total temperatures from 310 to 590 K, reference velocities from 8 to m/sec, and fuel-air ratios from 0.004 to 0.015. Most of the data were obtained using ASTM A-1 fuel; however, a limited number of tests was performed with natural gas fuel. Combustion efficiency and emission levels are correlated with operating conditions. Sampling error at operating conditions for which combustion efficiency was below about 90 percent resulted in abnormally low readings for hydrocarbon emissions.

  1. Platform for a Hydrocarbon Exhaust Gas Sensor Utilizing a Pumping Cell and a Conductometric Sensor

    PubMed Central

    Biskupski, Diana; Geupel, Andrea; Wiesner, Kerstin; Fleischer, Maximilian; Moos, Ralf

    2009-01-01

    Very often, high-temperature operated gas sensors are cross-sensitive to oxygen and/or they cannot be operated in oxygen-deficient (rich) atmospheres. For instance, some metal oxides like Ga2O3 or doped SrTiO3 are excellent materials for conductometric hydrocarbon detection in the rough atmosphere of automotive exhausts, but have to be operated preferably at a constant oxygen concentration. We propose a modular sensor platform that combines a conductometric two-sensor-setup with an electrochemical pumping cell made of YSZ to establish a constant oxygen concentration in the ambient of the conductometric sensor film. In this paper, the platform is introduced, the two-sensor-setup is integrated into this new design, and sensing performance is characterized. Such a platform can be used for other sensor principles as well. PMID:22423212

  2. Dynamic instabilities in spark-ignited combustion engines with high exhaust gas recirculation

    NASA Astrophysics Data System (ADS)

    Daw, C. Stuart; Finney, Charles E. A.

    2011-04-01

    We propose a cycle-resolved dynamic model for combustion instabilities in spark-ignition engines operating with high levels of exhaust gas recirculation (EGR). We account for the complex combustion response to cycle-to-cycle feedback by utilizing a global probability distribution that describes the pre-spark state of in-cylinder fuel mixing. The proposed model does a good job of simulating combustion instabilities observed in both lean-fueling engine experiments and in experiments where nitrogen dilution is used to simulate some of the combustion inhibition of EGR. When used to simulate high internal EGR operation, the model exhibits a range of global bifurcations and chaos that appear to be very robust. We use the model to show that it should be possible to reduce high EGR combustion instabilities by switching from internal to external EGR.

  3. Fuel flow regulator control for a diesel engine with exhaust gas driven turbocharger

    SciTech Connect

    Ludwig, G.C.

    1984-03-06

    A fuel flow regulator for an internal combustion engine having an exhaust gas turbocharger is disclosed. The fuel flow regulator responds to intake manifold pressure. Thus the fuel flow regulator increases the maximum fuel flow to the internal combustion engine from a first maximum predetermined fuel flow rate when the intake manifold pressure is at a first predetermined intake air pressure level to a second predetermined maximum fuel flow rate when the intake air manifold pressure is at a second predetermined intake air pressure level. Additionally, the fuel flow regulator decreases fuel flow to a third maximum fuel flow rate which is less than the first predetermined maximum fuel flow rate when the intake manifold pressure is greater than the second predetermined intake air pressure level. Therefore, the fuel flow regulator protects the internal combustion engine from overboost of the engine by the turbocharger and for overfueling the engine.

  4. Impact of exhaust gas recirculation (EGR) on the oxidative reactivity of diesel engine soot

    SciTech Connect

    Al-Qurashi, Khalid; Boehman, Andre L.

    2008-12-15

    This paper expands the consideration of the factors affecting the nanostructure and oxidative reactivity of diesel soot to include the impact of exhaust gas recirculation (EGR). Past work showed that soot derived from oxygenated fuels such as biodiesel carries some surface oxygen functionality and thereby possesses higher reactivity than soot from conventional diesel fuel. In this work, results show that EGR exerts a strong influence on the physical properties of the soot which leads to enhanced oxidation rate. HRTEM images showed a dramatic difference between the burning modes of the soot generated under 0 and 20% EGR. The soot produced under 0% EGR strictly followed an external burning mode with no evidence of internal burning. In contrast, soot generated under 20% EGR exhibited dual burning modes: slow external burning and rapid internal burning. The results demonstrate clearly that highly reactive soot can be achieved by manipulating the physical properties of the soot via EGR. (author)

  5. Measurement of exhaust gas recirculation rate by laser-induced fluorescence in engine

    NASA Astrophysics Data System (ADS)

    Morin, C.; Modica, V.; Guibert, P.

    2008-10-01

    The objective of this study is to measure by planar laser-induced fluorescence the exhaust gas recirculation (EGR) rate in the combustion chamber of an optical engine to quantify the stratification phenomena used in the new combustion strategy. From the results obtained in a high pressure-high temperature (HP-HT) facility, the tracer chosen for this aim is 3-pentanone. This paper presents a quantitative measurement of the EGR rate in the engine and a post-processing model with a correction and calibration procedure by considering the influence of temperature and pressure on the absorption cross-section and the 3-pentanone fluorescence quantum yield from the results established in the HP-HT facility. The stratification phenomena are quantified by using 3-pentanone fluorescence for two different configurations of EGR introduction in the engine. The local fluorescence measurements in the HP-HT facility are also compared with planar fluorescence measurements in the optical engine.

  6. Apparatus for controlling the flow of exhaust gas in an internal combustion engine with a turbocharger and a catalytic converter

    SciTech Connect

    Iwamoto, K.; Omata, K.

    1984-03-20

    An apparatus for controlling the flow of the exhaust gas in an internal combustion engine including a turbocharger, a catalytic converter in an exhaust duct, and a throttle valve in an intake duct, wherein the apparatus comprises a bypass passage bypassing a turbine of the turbocharger, a waste gate valve which controls the amount of the exhaust gas passing therethrough, an actuator for actuating the waste gate valve which has first and second pressure chambers separated from one another, and a switching valve which selectively connects the second pressure chamber to the atmosphere or to the intake vacuum area, the first pressure chamber being connected to the delivery pressure area of the turbocharger by means of a conduit which is connected to an atmospheric pressure area via a restriction.

  7. Calculations of economy of 18-cylinder radial aircraft engine with exhaust-gas turbine geared to the crankshaft

    NASA Technical Reports Server (NTRS)

    Hannum, Richard W; Zimmerman, Richard H

    1945-01-01

    Calculations based on dynamometer test-stand data obtained on an 18-cylinder radial engine were made to determine the improvement in fuel consumption that can be obtained at various altitudes by gearing an exhaust-gas turbine to the engine crankshaft in order to increase the engine-shaft work.

  8. RE-ENTRAINMENT AND DISPERSION OF EXHAUSTS FROM INDOOR RADON REDUCTION SYSTEMS: ANALYSIS OF TRACER GAS DATA

    EPA Science Inventory

    Tracer gas studies were conducted around four model houses in a wind tunnel, and around one house in the field, to quantify re-entrainment and dispersion of exhaust gases released from residential indoor radon reduction systems. Re-entrainment tests in the field suggest that acti...

  9. Air pollution from aircraft. [jet exhaust - aircraft fuels/combustion efficiency

    NASA Technical Reports Server (NTRS)

    Heywood, J. B.; Chigier, N. A.

    1975-01-01

    A model which predicts nitric oxide and carbon monoxide emissions from a swirl can modular combustor is discussed. A detailed analysis of the turbulent fuel-air mixing process in the swirl can module wake region is reviewed. Hot wire anemometry was employed, and gas sampling analysis of fuel combustion emissions were performed.

  10. Impact of Natural Gas Appliances on Pollutant Levels in California Homes

    SciTech Connect

    Mullen, Nasim A.; Li, Jina; Singer, Brett C.

    2012-12-01

    This report presents results from the first year of a 2-year study, investigating associations of five air pollutants (CO, NO2, NOX, formaldehyde and acetaldehyde) with the presence of natural gas appliances in California homes. From November 2011 to March 2012, pollutant concentration and occupant activity data were collected in 155 homes for 6-day periods. The sample population included both single-family (68%) and multi-family (32%) dwellings, with 87% having at least one gas appliance and 77% having an unvented gas cooking appliance. The geometric mean (GM) NO2 levels measured in the kitchen, bedroom and outside of homes were similar at values of 15, 12 and 11 ppb, respectively. In contrast, the GM NOx levels measured in the kitchen and bedroom of homes were much higher than levels measured outdoors, at levels of 42 and 41 ppb, compared to 19 ppb, respectively. Roughly 10% of sampled homes had 6-day average NO2 levels that exceeded the outdoor annual average limit set by the California Ambient Air Quality Standards (CAAQS) (30 ppb). The GMs of the highest 1-h and 8-h CO level measured in homes were 2.5 and 1.1 ppm, respectively. Four homes had a 1-h or 8-h concentration that exceeded the outdoor limits set by the CAAQS. The GM formaldehyde and acetaldehyde concentrations measured in homes were 15 and 7 ppb, respectively. Roughly 95% of homes had average formaldehyde levels indoors that exceeded the Chronic Reference Exposure Level set by the California EPA (7 ppb). Concentrations of NO2 and NOx, and to a lesser extent CO were associated with use of gas appliances, particularly unvented gas cooking appliances. Based on first principles, it is expected that effective venting of cooking pollutant emissions at the source will lead to a reduction of pollutant concentrations. However, no statistical association was detected between kitchen exhaust fan use and pollutant concentrations in homes in this study where gas cooking occurred frequently. The lack of

  11. Dynamic instabilities in spark-ignited combustion engines with high exhaust gas recirculation

    SciTech Connect

    Daw, C Stuart; FINNEY, Charles E A

    2011-01-01

    We propose a cycle-resolved dynamic model for combustion instabilities in spark-ignition engines operating with high levels of exhaust gas recirculation (EGR). High EGR is important for increasing fuel efficiency and implementing advanced low-emission combustion modes such as homogenous charge compression ignition (HCCI). We account for the complex combustion response to cycle-to-cycle feedback by utilizing a global probability distribution that describes the pre-spark state of in-cylinder fuel mixing. The proposed model does a good job of simulating combustion instabilities observed in both lean-fueling engine experiments and in experiments where nitrogen dilution is used to simulate some of the combustion inhibition of EGR. When used to simulate high internal EGR operation, the model exhibits a range of global bifurcations and chaos that appear to be very robust. We use the model to show that it should be possible to reduce high EGR combustion instabilities by switching from internal to external EGR. We also explain why it might be helpful to deliberately stratify the fuel in the pre-spark gas mixture. It might be possible to extend the simple approach used in this model to other chemical reaction systems with spatial inhomogeneity.

  12. Air pollution & the brain: Subchronic diesel exhaust exposure causes neuroinflammation and elevates early markers of neurodegenerative disease

    PubMed Central

    2011-01-01

    Background Increasing evidence links diverse forms of air pollution to neuroinflammation and neuropathology in both human and animal models, but the effects of long-term exposures are poorly understood. Objective We explored the central nervous system consequences of subchronic exposure to diesel exhaust (DE) and addressed the minimum levels necessary to elicit neuroinflammation and markers of early neuropathology. Methods Male Fischer 344 rats were exposed to DE (992, 311, 100, 35 and 0 μg PM/m3) by inhalation over 6 months. Results DE exposure resulted in elevated levels of TNFα at high concentrations in all regions tested, with the exception of the cerebellum. The midbrain region was the most sensitive, where exposures as low as 100 μg PM/m3 significantly increased brain TNFα levels. However, this sensitivity to DE was not conferred to all markers of neuroinflammation, as the midbrain showed no increase in IL-6 expression at any concentration tested, an increase in IL-1β at only high concentrations, and a decrease in MIP-1α expression, supporting that compensatory mechanisms may occur with subchronic exposure. Aβ42 levels were the highest in the frontal lobe of mice exposed to 992 μg PM/m3 and tau [pS199] levels were elevated at the higher DE concentrations (992 and 311 μg PM/m3) in both the temporal lobe and frontal lobe, indicating that proteins linked to preclinical Alzheimer's disease were affected. α Synuclein levels were elevated in the midbrain in response to the 992 μg PM/m3 exposure, supporting that air pollution may be associated with early Parkinson's disease-like pathology. Conclusions Together, the data support that the midbrain may be more sensitive to the neuroinflammatory effects of subchronic air pollution exposure. However, the DE-induced elevation of proteins associated with neurodegenerative diseases was limited to only the higher exposures, suggesting that air pollution-induced neuroinflammation may precede preclinical markers of

  13. Vascular and Cardiac Impairments in Rats Inhaling Ozone and Diesel Exhaust Particles

    EPA Science Inventory

    Background -Mechanisms of cardiovascular injuries from exposure to gas and particulate air pollutants are unknown. Objective -We hypothesized that episodic exposure of rats to ozone or diesel exhaust particles (DEP) will cause differential cardiovascular impairments, which will b...

  14. Exposure to hazardous volatile pollutants back diffusing from automobile exhaust systems.

    PubMed

    Rahman, Md Mahmudur; Kim, Ki-Hyun

    2012-11-30

    As back diffusion gases from automobiles are significant sources of in-vehicular pollution, we investigated eight automobiles, five for back diffusion (driving) measurements and three for reference conditions (non-driving). To characterize the back diffusion emission conditions, seven volatile organic compounds (VOC) and four carbonyl compounds (CCs) were measured along with dilution-to-threshold (D/T) ratio. The data obtained from back diffusion measurements were examined after having been divided into three subcategories: (i) driving and non-driving, (ii) with and without automobile upgrading (sealing the inner line), and (iii) differences in CO emission levels. Among the VOCs, the concentrations of toluene (T) was found to be the highest (range: 13.6-155 ppb), while benzene (0.19-1.47 ppb) was hardly distinguishable from its ambient levels. Other VOCs (xylene, trimethylbenzene, and styrene) were generally below <1 ppb. Unlike VOCs, the concentrations (ppb) of CCs were seen at fairly enhanced levels: 30.1-95 (formaldehyde), 34.6-87.2 (acetaldehyde), 4.56-34.7 (propionaldehyde), and 3.45-68.8 (butyraldehyde). The results of our study suggest that the back diffusion phenomenon, if occurring, can deteriorate in-vehicle air, especially with the most imminent health hazards from a compound such as formaldehyde in view of its exceedance pattern over common guidelines. PMID:23072984

  15. Exposure to hazardous volatile pollutants back diffusing from automobile exhaust systems.

    PubMed

    Rahman, Md Mahmudur; Kim, Ki-Hyun

    2012-11-30

    As back diffusion gases from automobiles are significant sources of in-vehicular pollution, we investigated eight automobiles, five for back diffusion (driving) measurements and three for reference conditions (non-driving). To characterize the back diffusion emission conditions, seven volatile organic compounds (VOC) and four carbonyl compounds (CCs) were measured along with dilution-to-threshold (D/T) ratio. The data obtained from back diffusion measurements were examined after having been divided into three subcategories: (i) driving and non-driving, (ii) with and without automobile upgrading (sealing the inner line), and (iii) differences in CO emission levels. Among the VOCs, the concentrations of toluene (T) was found to be the highest (range: 13.6-155 ppb), while benzene (0.19-1.47 ppb) was hardly distinguishable from its ambient levels. Other VOCs (xylene, trimethylbenzene, and styrene) were generally below <1 ppb. Unlike VOCs, the concentrations (ppb) of CCs were seen at fairly enhanced levels: 30.1-95 (formaldehyde), 34.6-87.2 (acetaldehyde), 4.56-34.7 (propionaldehyde), and 3.45-68.8 (butyraldehyde). The results of our study suggest that the back diffusion phenomenon, if occurring, can deteriorate in-vehicle air, especially with the most imminent health hazards from a compound such as formaldehyde in view of its exceedance pattern over common guidelines.

  16. Vehicle Exhaust Gas Clearance by Low Temperature Plasma-Driven Nano-Titanium Dioxide Film Prepared by Radiofrequency Magnetron Sputtering

    PubMed Central

    Yu, Shuang; Liang, Yongdong; Sun, Shujun; Zhang, Kai; Zhang, Jue; Fang, Jing

    2013-01-01

    A novel plasma-driven catalysis (PDC) reactor with special structure was proposed to remove vehicle exhaust gas. The PDC reactor which consisted of three quartz tubes and two copper electrodes was a coaxial dielectric barrier discharge (DBD) reactor. The inner and outer electrodes firmly surrounded the outer surface of the corresponding dielectric barrier layer in a spiral way, respectively. Nano-titanium dioxide (TiO2) film prepared by radiofrequency (RF) magnetron sputtering was coated on the outer wall of the middle quartz tube, separating the catalyst from the high voltage electrode. The spiral electrodes were designed to avoid overheating of microdischarges inside the PDC reactor. Continuous operation tests indicated that stable performance without deterioration of catalytic activity could last for more than 25 h. To verify the effectiveness of the PDC reactor, a non-thermal plasma(NTP) reactor was employed, which has the same structure as the PDC reactor but without the catalyst. The real vehicle exhaust gas was introduced into the PDC reactor and NTP reactor, respectively. After the treatment, compared with the result from NTP, the concentration of HC in the vehicle exhaust gas treated by PDC reactor reduced far more obviously while that of NO decreased only a little. Moreover, this result was explained through optical emission spectrum. The O emission lines can be observed between 870 nm and 960 nm for wavelength in PDC reactor. Together with previous studies, it could be hypothesized that O derived from catalytically O3 destruction by catalyst might make a significant contribution to the much higher HC removal efficiency by PDC reactor. A series of complex chemical reactions caused by the multi-components mixture in real vehicle exhaust reduced NO removal efficiency. A controllable system with a real-time feedback module for the PDC reactor was proposed to further improve the ability of removing real vehicle exhaust gas. PMID:23560062

  17. Pollutant swapping: greenhouse gas emissions from wetland systems constructed to mitigate agricultural pollution

    NASA Astrophysics Data System (ADS)

    Freer, Adam; Quinton, John; Surridge, Ben; McNamara, Niall

    2014-05-01

    Diffuse (non-point) water pollution from agricultural land continues to challenge water quality management, requiring the adoption of new land management practices. The use of constructed agricultural wetlands is one such practice, designed to trap multiple pollutants mobilised by rainfall prior to them reaching receiving water. Through capturing and storing pollutants in bottom sediments, it could be hypothesised that the abundance of nutrients stored in the anoxic conditions commonly found in these zones may lead to pollutant swapping. Under these circumstances, trapped material may undergo biogeochemical cycling to change chemical or physical form and thereby become more problematic or mobile within the environment. Thus, constructed agricultural wetlands designed to mitigate against one form of pollution may in fact offset the created benefits by 'swapping' this pollution into other forms and pathways, such as through release to the atmosphere. Pollutant swapping to the atmosphere has been noted in analogous wetland systems designed to treat municipal and industrial wastewaters, with significant fluxes of CO2, CH4 and N2O being recorded in some cases. However the small size, low level of engineering and variable nutrient/sediment inputs which are features of constructed agricultural wetlands, means that this knowledge is not directly transferable. Therefore, more information is required when assessing whether a wetland's potential to act as hotspot for pollution swapping outweighs its potential to act as a mitigation tool for surface water pollution. Here we present results from an on-going monitoring study at a trial agricultural wetland located in small a mixed-use catchment in Cumbria, UK. Estimates were made of CH4, CO2 and N2O flux from the wetland surface using adapted floating static chambers, which were then directly compared with fluxes from an undisturbed riparian zone. Results indicate that while greenhouse gas flux from the wetland may be

  18. Establishing isokinetic flow for a plasma torch exhaust gas diagnostic for a plasma hearth furnace

    SciTech Connect

    Pollack, B.R.

    1996-05-01

    Real time monitoring of toxic metallic effluents in confined gas streams can be accomplished through use of Microwave Induced Plasmas to perform atomic emission spectroscopy, For this diagnostic to be viable it is necessary that it sample from the flowstream of interest in an isokinetic manner. A method of isokinetic sampling was established for this device for use in the exhaust system of a plasma hearth vitrification furnace. The flow and entrained particulate environment were simulated in the laboratory setting using a variable flow duct of the same dimensions (8-inch diameter, schedule 40) as that in the field and was loaded with similar particulate (less than 10 {mu}m in diameter) of lake bed soil typically used in the vitrification process. The flow from the furnace was assumed to be straight flow. To reproduce this effect a flow straightener was installed in the device. An isokinetic sampling train was designed to include the plasma torch, with microwave power input operating at 2.45 GHz, to match local freestream velocities between 800 and 2400 ft/sec. The isokinetic sampling system worked as planned and the plasma torch had no difficulty operating at the required flowrates. Simulation of the particulate suspension was also successful. Steady particle feeds were maintained over long periods of time and the plasma diagnostic responded as expected.

  19. Fuel-Specific Effect of Exhaust Gas Residuals on HCCI Combustion: A Modeling Study

    SciTech Connect

    Szybist, James P

    2008-01-01

    A modeling study was performed to investigate fuel-specific effects of exhaust gas recirculation (EGR) components on homogeneous charge compression ignition (HCCI) combustion at conditions relevant to the negative valve overlap (NVO) strategy using CHEMKIN-PRO. Four single-component fuels with well-established kinetic models were chosen: n-heptane, iso-octane, ethanol, and toluene. These fuels were chosen because they span a wide range of fuel chemistries, and produce a wide compositions range of complete stoichiometric products (CSP). The simulated engine conditions combined a typical spark ignition engine compression ratio (11.34) and high intake charge temperatures (500-550 K) that are relevant to NVO HCCI. It was found that over the conditions investigated, all the fuels had overlapping start of combustion (SOC) phasing, despite the wide range in octane number (RON = 0 to 120). The effect of the EGR components CO2 and H2O was to suppress the compression temperature because of their higher heat capacities, which retarded SOC. For a concentration of O2 higher than the stoichiometric amount, or excess O2, there was an effect of advancing SOC for n-heptane, iso-octane, and toluene, but SOC for ethanol was not advanced. Low temperature heat release (LTHR) for n-heptane was also found to be highly dependent on excess O2, and mild endothermic reaction was observed for cases when excess O2 was not present.

  20. Measurements of gas phase acids in diesel exhaust: a relevant source of HNCO?

    PubMed

    Wentzell, Jeremy J B; Liggio, John; Li, Shao-Meng; Vlasenko, A; Staebler, Ralf; Lu, Gang; Poitras, Marie-Josée; Chan, Tak; Brook, Jeffrey R

    2013-07-16

    Gas-phase acids in light duty diesel (LDD) vehicle exhaust were measured using chemical ionization mass spectrometry (CIMS). Fuel based emission factors (EF) and NOx ratios for these species were determined under differing steady state engine operating conditions. The derived HONO and HNO3 EFs agree well with literature values, with HONO being the single most important acidic emission. Of particular importance is the quantification of the EF for the toxic species, isocyanic acid (HNCO). The emission factors for HNCO ranged from 0.69 to 3.96 mg kgfuel(-1), and were significantly higher than previous biomass burning emission estimates. Further ambient urban measurements of HNCO demonstrated a clear relationship with the known traffic markers of benzene and toluene, demonstrating for the first time that urban commuter traffic is a source of HNCO. Estimates based upon the HNCO-benzene relationship indicate that upward of 23 tonnes of HNCO are released annually from commuter traffic in the Greater Toronto Area, far exceeding the amount possible from LDD alone. Nationally, 250 to 770 tonnes of HNCO may be emitted annually from on-road vehicles, likely representing the dominant source of exposure in urban areas, and with emissions comparable to that of biomass burning. PMID:23781923

  1. Development and characterization of a mobile photoacoustic sensor for on-line soot emission monitoring in diesel exhaust gas.

    PubMed

    Beck, H A; Niessner, R; Haisch, C

    2003-04-01

    Upcoming regulations for vehicle exhaust emission demand substantial reduction of particle emission in diesel exhaust. To achieve these emission levels, the car manufacturing industry is developing new combustion concepts and exhaust after-treatment techniques such as the use of catalysts and particle filters. Many of the state-of-the-art analytical instruments do not meet the required detection limits, in combination with a high temporal resolution necessary for engine optimization. This paper reports a new detection system and the first results of its application to on-line diesel exhaust soot measurements on a engine test bench (MAN diesel engine facility Nürnberg, Germany). The instrument is based on differential photoacoustic (PA) spectroscopy of black carbon aerosol. It contains two identical PA cells, one for the measurement of the aerosol particles and one which analyses the particle-free gas. Thus, a potential cross-sensitivity to gaseous absorbers in the exhaust gas can be excluded. The PA cells were characterized in a laboratory set-up, with water vapor as reference gas and artificial soot generated by a spark discharge generator. The detection limit was found to be 2 microg m(-3) BC (for diesel soot) with a sampling rate of 3 Hz. The temporal response of the system was found to be in the order of 1 s. After full characterization of the cells, the system was transferred into a mobile 19"-rack. Characterization of the mobile sensor system under real-world conditions was performed during several measurement campaigns at an engine test bench for heavy-duty diesel engines. Results for the limit of detection, the time resolution, accuracy, repeatability, and robustness of the sensor system are very promising with regards to a routine application of the system in engine development. PMID:12733029

  2. Effect of operating and sampling conditions on the exhaust gas composition of small-scale power generators.

    PubMed

    Smits, Marianne; Vanpachtenbeke, Floris; Horemans, Benjamin; De Wael, Karolien; Hauchecorne, Birger; Van Langenhove, Herman; Demeestere, Kristof; Lenaerts, Silvia

    2012-01-01

    Small stationary diesel engines, like in generator sets, have limited emission control measures and are therefore responsible for 44% of the particulate matter (PM) emissions in the United States. The diesel exhaust composition depends on operating conditions of the combustion engine. Furthermore, the measurements are influenced by the used sampling method. This study examines the effect of engine loading and exhaust gas dilution on the composition of small-scale power generators. These generators are used in different operating conditions than road-transport vehicles, resulting in different emission characteristics. Experimental data were obtained for gaseous volatile organic compounds (VOC) and PM mass concentration, elemental composition and nitrate content. The exhaust composition depends on load condition because of its effect on fuel consumption, engine wear and combustion temperature. Higher load conditions result in lower PM concentration and sharper edged particles with larger aerodynamic diameters. A positive correlation with load condition was found for K, Ca, Sr, Mn, Cu, Zn and Pb adsorbed on PM, elements that originate from lubricating oil or engine corrosion. The nitrate concentration decreases at higher load conditions, due to enhanced nitrate dissociation to gaseous NO at higher engine temperatures. Dilution on the other hand decreases PM and nitrate concentration and increases gaseous VOC and adsorbed metal content. In conclusion, these data show that operating and sampling conditions have a major effect on the exhaust gas composition of small-scale diesel generators. Therefore, care must be taken when designing new experiments or comparing literature results.

  3. Effect of Operating and Sampling Conditions on the Exhaust Gas Composition of Small-Scale Power Generators

    PubMed Central

    Smits, Marianne; Vanpachtenbeke, Floris; Horemans, Benjamin; De Wael, Karolien; Hauchecorne, Birger; Van Langenhove, Herman; Demeestere, Kristof; Lenaerts, Silvia

    2012-01-01

    Small stationary diesel engines, like in generator sets, have limited emission control measures and are therefore responsible for 44% of the particulate matter (PM) emissions in the United States. The diesel exhaust composition depends on operating conditions of the combustion engine. Furthermore, the measurements are influenced by the used sampling method. This study examines the effect of engine loading and exhaust gas dilution on the composition of small-scale power generators. These generators are used in different operating conditions than road-transport vehicles, resulting in different emission characteristics. Experimental data were obtained for gaseous volatile organic compounds (VOC) and PM mass concentration, elemental composition and nitrate content. The exhaust composition depends on load condition because of its effect on fuel consumption, engine wear and combustion temperature. Higher load conditions result in lower PM concentration and sharper edged particles with larger aerodynamic diameters. A positive correlation with load condition was found for K, Ca, Sr, Mn, Cu, Zn and Pb adsorbed on PM, elements that originate from lubricating oil or engine corrosion. The nitrate concentration decreases at higher load conditions, due to enhanced nitrate dissociation to gaseous NO at higher engine temperatures. Dilution on the other hand decreases PM and nitrate concentration and increases gaseous VOC and adsorbed metal content. In conclusion, these data show that operating and sampling conditions have a major effect on the exhaust gas composition of small-scale diesel generators. Therefore, care must be taken when designing new experiments or comparing literature results. PMID:22442670

  4. 3-Nitrobenzanthrone, a potential human cancer hazard in diesel exhaust and urban air pollution: a review of the evidence.

    PubMed

    Arlt, Volker M

    2005-11-01

    Epidemiological studies have shown that exposure to diesel exhaust and urban air pollution is associated with an increased risk of lung cancer. 3-Nitrobenzanthrone [3-nitro-7H-benz[de]anthracen-7-one (3-NBA)] is an extremely potent mutagen and suspected human carcinogen identified in diesel exhaust and ambient air particulate matter. The main metabolite of 3-NBA, 3-aminobenzanthrone (3-ABA), was found in the urine of salt mine workers occupationally exposed to diesel emissions, indicating that human exposure to 3-NBA due to diesel emissions can be significant and is detectable. There is clear evidence that 3-NBA is a genotoxic mutagen forming DNA adducts after metabolic activation through simple reduction of the nitro group. Several human enzymes have been shown to activate 3-NBA and its metabolites in vitro and in cells to form electrophilic arylnitrenium and rearranged carbenium ions, leading to the formation of purine adducts at the C8 and N2 position of guanine and at the C8 and N6 position of adenine. The predominant DNA adducts in vivo, 2-(2'-deoxyguanosin-N2-yl)-3-aminobenzanthrone and N-(2'-deoxyguanosin-8-yl)-3-aminobenzanthrone are also the most persistent adducts in target tissue in rodents, and are most probably responsible for the induction of GC-->TA transversion mutations observed in vivo. It is concluded that these adducts not only represent premutagenic lesions in DNA but are of primary importance for the initiation of the carcinogenic process and subsequent tumour formation in target tissue. Indeed, 3-NBA is carcinogenic in rats after intratracheal instillation, inducing mainly squamous cell carcinoma in lung. The intention of this article is to provide a critical review on the potential genotoxic effects of 3-NBA on human health. However, in general, there is a need for more mechanistic studies that relate 3-NBA to all processes that are considered to orchestrate tumour development and of studies on the ability of particles to promote 3-NBA

  5. The use of gas separation membranes for pollution control

    SciTech Connect

    Logsdon, B.W.; Stull, D.; Pellegrino, J.

    1993-04-01

    Rocky Flats is considering the use of a fluidized bed oxidation unit (FBU) for the destruction of mixed waste. Public concerns about the health effects of such destruction have been intense. In order to allay such concerns and minimize the possible health impacts of the proposed mixed waste destruction, RFP has been investigating novel methods of air pollution control. Among the most promising of these techniques is the use of gas separation membranes, which is described in this report.

  6. Near-explicit Gas-phase Chemistry Coupled with Extensive Aqueous Mechanism: Looking at Ethanol (E85) Exhaust in a Fog

    NASA Astrophysics Data System (ADS)

    Ginnebaugh, D. L.; Jacobson, M. Z.

    2011-12-01

    We combine a near-explicit gas-phase chemical mechanism with an extensive aqueous mechanism in a chemical solver to examine the effects of ethanol (E85) versus gasoline on the fate of pollutants in the presence of a fog. We use the Master Chemical Mechanism (MCM, version 3.1, Leeds University) and the Chemical Aqueous Phase Radical Mechanism, CAPRAM 3.0, with the SMVGEAR II chemical ordinary differential solver to provide the speed necessary to simulate complex chemistry. The MCM has over 13, 500 organic reactions and 4,600 species, while CAPRAM treats aqueous chemistry among 390 species and 829 reactions (including 51 gas-to-aqueous phase reactions). We validate a simplified version of the model against results from a comprehensive intercomparison by Barth et al (2003). In previous work on ethanol (E85), we analyzed the temperature-dependence of ethanol and gasoline exhaust chemistry and its impact on urban air pollution considering only gas-phase chemistry. In addition to the air pollution findings, we verified that using the MCM with SMVGEAR is practical in a 3-D model. Here, we extend our study to include aqueous chemistry in the presence of a fog. We investigate the impact aqueous reactions have on unburned ethanol and acetaldehyde mixing ratios in the atmosphere in particular because acetaldehyde is an ozone precursor and carcinogen, and aqueous oxidation has potential to speed the conversion of unburned ethanol to acetaldehyde. Acetaldehyde also forms acetic acid in aqueous solution. Acetic acid vapor is an eye, nose, and lung irritant, so both species contribute negatively to human health. We look at the impact of fog liquid water content and temperature on the degradation of emitted aromatic and other species as well, from both gasoline and E85.

  7. Apparatus and methods of reheating gas turbine cooling steam and high pressure steam turbine exhaust in a combined cycle power generating system

    DOEpatents

    Tomlinson, Leroy Omar; Smith, Raub Warfield

    2002-01-01

    In a combined cycle system having a multi-pressure heat recovery steam generator, a gas turbine and steam turbine, steam for cooling gas turbine components is supplied from the intermediate pressure section of the heat recovery steam generator supplemented by a portion of the steam exhausting from the HP section of the steam turbine, steam from the gas turbine cooling cycle and the exhaust from the HP section of the steam turbine are combined for flow through a reheat section of the HRSG. The reheated steam is supplied to the IP section inlet of the steam turbine. Thus, where gas turbine cooling steam temperature is lower than optimum, a net improvement in performance is achieved by flowing the cooling steam exhausting from the gas turbine and the exhaust steam from the high pressure section of the steam turbine in series through the reheater of the HRSG for applying steam at optimum temperature to the IP section of the steam turbine.

  8. 40 CFR 86.1710-99 - Fleet average non-methane organic gas exhaust emission standards for light-duty vehicles and...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... exhaust emission standards for light-duty vehicles and light light-duty trucks. 86.1710-99 Section 86.1710... the Voluntary National Low Emission Vehicle Program for Light-Duty Vehicles and Light-Duty Trucks § 86.1710-99 Fleet average non-methane organic gas exhaust emission standards for light-duty vehicles...

  9. Influence of an Optimized Thermoelectric Generator on the Back Pressure of the Subsequent Exhaust Gas System of a Vehicle

    NASA Astrophysics Data System (ADS)

    Kühn, Roland; Koeppen, Olaf; Kitte, Jens

    2014-06-01

    Numerous research projects in automotive engineering focus on the industrialization of the thermoelectric generator (TEG). The development and the implementation of thermoelectric systems into the vehicle environment are commonly supported by virtual design activities. In this paper a customized simulation architecture is presented that includes almost all vehicle parts which are influenced by the TEG (overall system simulation) but is nevertheless capable of real-time use. Moreover, an optimized planar TEG with minimum nominal power output of about 580 W and pressure loss at nominal conditions of 10 mbar, synthesized using the overall system simulation, and the overall system simulation itself are used to answer a generally neglected question: What influence does the position of a TEG have on the back pressure of the subsequent exhaust gas system of the vehicle? It is found that the influence of the TEG on the muffler is low, but the catalytic converter is strongly influenced. It is shown that the TEG can reduce the back pressure of an exhaust gas system so much that its overall back pressure is less than the back pressure of a standard exhaust gas system.

  10. Lightweight Exhaust Manifold and Exhaust Pipe Ducting for Internal Combustion Engines

    NASA Technical Reports Server (NTRS)

    Northam, G. Burton (Inventor); Ransone, Philip O. (Inventor); Rivers, H. Kevin (Inventor)

    1999-01-01

    An improved exhaust system for an internal combustion gasoline-and/or diesel-fueled engine includes an engine exhaust manifold which has been fabricated from carbon- carbon composite materials in operative association with an exhaust pipe ducting which has been fabricated from carbon-carbon composite materials. When compared to conventional steel. cast iron. or ceramic-lined iron paris. the use of carbon-carbon composite exhaust-gas manifolds and exhaust pipe ducting reduces the overall weight of the engine. which allows for improved acceleration and fuel efficiency: permits operation at higher temperatures without a loss of strength: reduces the "through-the wall" heat loss, which increases engine cycle and turbocharger efficiency and ensures faster "light-off" of catalytic converters: and, with an optional thermal reactor, reduces emission of major pollutants, i.e. hydrocarbons and carbon monoxide.

  11. A temperature correlation for the radiation resistance of a thick-walled circular duct exhausting a hot gas

    NASA Technical Reports Server (NTRS)

    Mahan, J. R.; Cline, J. G.; Jones, J. D.

    1984-01-01

    It is often useful to know the radiation impedance of an unflanged but thick-walled circular duct exhausting a hot gas into relatively cold surroundings. The reactive component is shown to be insensitive to temperature, but the resistive component is shown to be temperature dependent. A temperature correlation is developed permitting prediction of the radiation resistance from a knowledge of the temperature difference between the ambient air and the gas flowing from the duct, and a physical basis for this correlation is presented.

  12. *GAS-PHASE AND PARTICULATE COMPONENTS OF DIESEL EXHAUST PRODUCE DIFFERENTIAL CARDIOPHYSIOLOGICAL IMPAIRMENTS IN HEALTHY RATS

    EPA Science Inventory

    We recently showed that inhalation exposure of normotensive Wistar Kyoto (WKY) rats to whole diesel exhaust (DE) elicited changes in cardiac gene expression pattern that broadly mimicked gene expression in non-exposed spontaneously hypertensive rats. We hypothesized that healthy ...

  13. Role of average speed in N₂O exhaust emissions as greenhouse gas in a huge urban zone (MVMZ): would we need a cold sun?

    PubMed

    Castillo, S; Mac-Beath, I; Mejia, I; Camposeco, R; Bazan, G; Morán-Pineda, M; Carrera, R; Gómez, R

    2012-05-15

    Nowadays, the drastic pollution problems, some of them related with greenhouse gas emissions, have promoted important attempts to face and diminish the global warming effects on the Mexico Valley Metropolitan Zone (MVMZ) as well as on the huge urban zones around the world. To reduce the exhaust gas emissions, many efforts have been carried out to reformulate fuels and design new catalytic converters; however, it is well known that other variables such as socio-economic and transport structure factors also play an important role around this problem. The present study analyzes the roles played by several commonly-used three-way catalytic converters (TWC) and the average traffic speed in the emission of N(2)O as greenhouse gas. According to this study, by increasing the average traffic flow and avoiding constant decelerations (frequent stops) during common trips, remarkable environmental and economic benefits could be obtained due to the diminution of N(2)O and other contaminant emissions such as ammonia (NH(3)) and even CO(2) with the concomitant reduced fossil fuel consumption. The actions mentioned above could be highly viable to diminish, in general, the global warming effects and contamination problems. PMID:22245865

  14. Role of average speed in N₂O exhaust emissions as greenhouse gas in a huge urban zone (MVMZ): would we need a cold sun?

    PubMed

    Castillo, S; Mac-Beath, I; Mejia, I; Camposeco, R; Bazan, G; Morán-Pineda, M; Carrera, R; Gómez, R

    2012-05-15

    Nowadays, the drastic pollution problems, some of them related with greenhouse gas emissions, have promoted important attempts to face and diminish the global warming effects on the Mexico Valley Metropolitan Zone (MVMZ) as well as on the huge urban zones around the world. To reduce the exhaust gas emissions, many efforts have been carried out to reformulate fuels and design new catalytic converters; however, it is well known that other variables such as socio-economic and transport structure factors also play an important role around this problem. The present study analyzes the roles played by several commonly-used three-way catalytic converters (TWC) and the average traffic speed in the emission of N(2)O as greenhouse gas. According to this study, by increasing the average traffic flow and avoiding constant decelerations (frequent stops) during common trips, remarkable environmental and economic benefits could be obtained due to the diminution of N(2)O and other contaminant emissions such as ammonia (NH(3)) and even CO(2) with the concomitant reduced fossil fuel consumption. The actions mentioned above could be highly viable to diminish, in general, the global warming effects and contamination problems.

  15. Evaluation of Energy Saving Characteristics of a High-Efficient Cogeneration System Utilizing Gas Engine Exhaust Heat

    NASA Astrophysics Data System (ADS)

    Pak, Pyong Sik

    A high efficiency cogeneration system (CGS) utilizing high temperature exhaust gas from a gas engine is proposed. In the proposed CGS, saturated steam produced in the gas engine is superheated with a super heater utilizing regenerative burner and used to drive a steam turbine generator. The heat energy is supplied by extracting steam from the steam turbine and turbine outlet low-temperature steam. Both of the energy saving characteristics of the proposed CGS and a CGS constructed by using the original gas engine (GE-CGS) were investigated and compared, by taking a case where energy for office buildings was supplied by the conventional energy systems. It was shown that the proposed CGS has energy saving rate of 24.5%, higher than 1.83 times, compared with that of the original GE-CGS.

  16. Time-resolved nature of exhaust gas emissions and piston wall temperature under transient operation in a small diesel engine

    SciTech Connect

    Reksowardojo, I.K.; Ogawa, Hideyuki; Miyamoto, Noboru; Enomoto, Yoshiteru; Kitamura, Toru

    1996-09-01

    Diesel combustion and exhaust gas emissions under transient operation (when fuel amounts abruptly increased) were investigated under a wide range of operating conditions with a newly developed gas sampling system. The relation between gas emissions and piston wall temperatures was also investigated. The results indicated that after the start of acceleration NOx, THC and smoke showed transient behaviors before reaching the steady state condition. Of the three gases, THC was most affected by piston wall temperature; its concentration decreased as the wall temperature increased throughout the acceleration except immediately after the start of acceleration. The number of cycles, at which gas concentrations reach the steady-state value after the start of acceleration, were about 1.2 times the cycle constant of the piston wall temperature for THC, and 2.3 times for smoke.

  17. MODELING THE POLLUTION OF PRISTINE GAS IN THE EARLY UNIVERSE

    SciTech Connect

    Pan, Liubin; Scannapieco, Evan; Scalo, Jon E-mail: evan.scannapieco@asu.edu

    2013-10-01

    We conduct a comprehensive theoretical and numerical investigation of the pollution of pristine gas in turbulent flows, designed to provide useful new tools for modeling the evolution of the first generation of stars. The properties of such Population III (Pop III) stars are thought to be very different than those of later stellar generations, because cooling is dramatically different in gas with a metallicity below a critical value Z{sub c}, which lies between ∼10{sup –6} and ∼10{sup –3} Z{sub ☉}. The critical value is much smaller than the typical overall average metallicity, , and therefore the mixing efficiency of the pristine gas in the interstellar medium plays a crucial role in determining the transition from Pop III to normal star formation. The small critical value, Z{sub c}, corresponds to the far left tail of the probability distribution function (PDF) of the metal abundance. Based on closure models for the PDF formulation of turbulent mixing, we derive evolution equations for the fraction of gas, P, lying below Z{sub c}, in statistically homogeneous compressible turbulence. Our simulation data show that the evolution of the pristine fraction P can be well approximated by a generalized 'self-convolution' model, which predicts that P-dot = - (n/τ{sub con}) P (1-P{sup 1/n}), where n is a measure of the locality of the mixing or PDF convolution events and the convolution timescale τ{sub con} is determined by the rate at which turbulence stretches the pollutants. Carrying out a suite of numerical simulations with turbulent Mach numbers ranging from M = 0.9 to 6.2, we are able to provide accurate fits to n and τ{sub con} as a function of M, Z{sub c}/(Z), and the length scale, L{sub p}, at which pollutants are added to the flow. For pristine fractions above P = 0.9, mixing occurs only in the regions surrounding blobs of pollutants, such that n = 1. For smaller values of P, n is larger as the mixing process becomes more global. We show how

  18. Implementation of an experimental pilot reproducing the fouling of the exhaust gas recirculation system in diesel engines

    NASA Astrophysics Data System (ADS)

    Gaborieau, Cécile; Sommier, Alain; Toutain, Jean; Anguy, Yannick; Crepeau, Gérald; Gobin, Benoît

    2012-04-01

    The European emission standards EURO 5 and EURO 6 define more stringent acceptable limits for exhaust emissions of new vehicles. The Exhaust Gas Recirculation (EGR) system is a partial but essential solution for lowering the emission of nitrogen oxides and soot particulates. Yet, due to a more intensive use than in the past, the fouling of the EGR system is increased. Ensuring the reliability of the EGR system becomes a main challenge. In partnership with PSA Peugeot Citroën, we designed an experimental setup that mimics an operating EGR system. Its distinctive features are (1) its ability to reproduce precisely the operating conditions and (2) its ability to measure the temperature field on the heat exchanger surface with an Infra Red camera for detecting in real time the evolution of the fooling deposit based on its thermal resistance. Numerical codes are used in conjunction with this experimental setup to determine the evolution of the fouling thickness from its thermal resistance.

  19. Shock propagation in the exhaust gas handling system of the proposed large altitude rocket cell: methods and preliminary analysis

    SciTech Connect

    Sutton, S.B.; Pierce, R.E.

    1984-10-04

    Numerical predictions are to be performed of the shock pressures that would result from the detonation of 100,000 lbm TNT. The initial phase of the project was to develop the methodology for analyzing the problem, develop a preliminary conceptual design to use in initial simulations, and estimate over-pressures, inside the conceptual facility, resulting from the propellant detonation. This report discusses the methods of analysis used to study the problem of the detonation of the propellant, and the propagation of the shock wave inside the exhaust gas processing system, and presents preliminary results. The KOVEC computer code was used to simulate the detonation of 100,000 lbm TNT and develop a boundary prescription for use in the gas dynamics code GASP which models the propagation of the shock wave through the LARC exhaust gas processing system. Results are presented showing the effect of cross-sectional area changes and variations in the initial pressure in the gas processing system on the shock wave peak pressure and propagation speed.

  20. Natural Gas Variability In California: Environmental Impacts And Device Performance Combustion Modeling of Pollutant Emissions From a Residential Cooking Range

    SciTech Connect

    Tonse, S. R.; Singer, B. C.

    2011-07-01

    As part of a larger study of liquefied natural gas impacts on device performance and pollutant emissions for existing equipment in California, this report describes a cmoputer modeling study of a partially premixed flame issueing from a single cooktop burner port. The model consisted of a reactive computational fluid dynamics three-dimensional spatial grid and a 71-species chemical mechanism with propane combustion capability. Simulations were conducted with a simplified fuel mixture containing methane, ethane, and propane in proportions that yield properties similar to fuels distributed throughout much of California now and in recent years (baseline fuel), as well as with two variations of simulated liquefied natural gas blends. A variety of simulations were conducted with baseline fuel to explore the effect of several key parameters on pollutant formation and other flame characteristics. Simulations started with fuel and air issuing through the burner port, igniting, and continuing until the flame was steady with time. Conditions at this point were analyzed to understand fuel, secondary air and reaction product flows, regions of pollutant formation, and exhaust concentrations of carbon monoxide, nitric oxide and formaldehyde. A sensitivity study was conducted, varying the inflow parameters of this baseline gs about real-world operating conditions. Flame properties responded as expected from reactive flow theory. In the simulation, carbon monoxide levels were influenced more by the mixture's inflow velocity than by the gas-to-air ratio in the mixture issuing from the inflow port. Additional simulations were executed at two inflow conditions - high heat release and medium heat release - to examine the impact of replacing the baseline gas with two mixtures representative of liquefied natural gas. Flame properties and pollutant generation rates were very similar among the three fuel mixtures.

  1. Tank exhaust comparison with 40 CFR 61.93, Subpart H, and other referenced guidelines for Tank Farms National Emission Standards for Hazardous Air Pollutant (NESHAP) designated stacks

    SciTech Connect

    Bachand, D.D.; Crummel, G.M.

    1994-07-01

    The US Environmental Protection Agency (EPA) promulgated National Emission Standards other than Radon from US Department of Energy (DOE) Facilities (40 CFR 61, Subpart H) on December 15, 1989. The regulations specify procedures, equipment, and test methods that.are to be used to measure radionuclide emissions from exhaust stacks that are designated as National Emission Standards for Hazardous Air Pollutant (NESHAP) stacks. Designated NESHAP stacks are those that have the potential to cause any member of the public to receive an effective dose equivalent (EDE) greater than or equal to 0.1 mrem/year, assuming all emission controls were removed. Tank Farms currently has 33 exhaust stacks, 15 of which are designated NESHAP stacks. This document assesses the compliance status of the monitoring and sampling systems for the designated NESHAP stacks.

  2. Efficiency of thermoelectric recuperators of the exhaust gas energy of internal combustion engines

    NASA Astrophysics Data System (ADS)

    Anatychuk, L. I.; Kuz, R. V.; Rozver, Yu. Yu.

    2012-06-01

    Results of computer simulation of thermoelectric generators (TEG) using the exhaust heat of internal combustion engines are presented. Sectionalized generator schematics whereby maximum efficiency is achieved for cases of real temperature dependences of the most suitable thermoelectric materials are considered. A model optimized for minimum cost is considered as well. Results of experimental research on generator that employs exhaust heat from heat and electricity cogeneration plant with a diesel engine are presented. Computer simulation is verified by the test results. The outlook for application of such heat recuperators in stationary plants is considered.

  3. Catalysts, systems and methods to reduce NOX in an exhaust gas stream

    DOEpatents

    Castellano, Christopher R.; Moini, Ahmad; Koermer, Gerald S.; Furbeck, Howard

    2010-07-20

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having an SCR catalyst comprising silver tungstate on an alumina support. The emissions treatment system may be used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines. An emissions treatment system may further comprise an injection device operative to dispense a hydrocarbon reducing agent upstream of the catalyst.

  4. Pollutant emissions from and within a model gas turbine combustor at elevated pressures and temperatures

    NASA Technical Reports Server (NTRS)

    Drennan, S. A.; Peterson, C. O.; Khatib, F. M.; Sowa, W. A.; Samuelsen, G. S.

    1993-01-01

    Conventional and advanced gas turbine engines are coming under increased scrutiny regarding pollutant emissions. This, in turn, has created a need to obtain in-situ experimental data at practical conditions, as well as exhaust data, and to obtain the data in combustors that reflect modern designs. The in-situ data are needed to (1) assess the effects of design modifications on pollutant formation, and (2) develop a detailed data base on combustor performance for the development and verification of computer modeling. This paper reports on a novel high pressure, high temperature facility designed to acquire such data under controlled conditions and with access (optical and extractive) for in-situ measurements. To evaluate the utility of the facility, a model gas turbine combustor was selected which features practical hardware design, two rows of jets (primary and dilution) with four jets in each row, and advanced wall cooling techniques with laser drilled effusive holes. The dome is equipped with a flat-vaned swirler with vane angles of 60 degrees. Data are obtained at combustor pressures ranging from 2 to 10 atmospheres of pressure, levels of air preheat to 427 C, combustor reference velocities from 10.0 to 20.0 m/s, and an overall equivalence ratio of 0.3. Exit plane and in-situ measurements are presented for HC, O2, CO2, CO, and NO(x). The exit plane emissions of NO(x) correspond to levels reported from practical combustors and the in-situ data demonstrate the utility and potential for detailed flow field measurements.

  5. Exhaust bypass flow control for exhaust heat recovery

    SciTech Connect

    Reynolds, Michael G.

    2015-09-22

    An exhaust system for an engine comprises an exhaust heat recovery apparatus configured to receive exhaust gas from the engine and comprises a first flow passage in fluid communication with the exhaust gas and a second flow passage in fluid communication with the exhaust gas. A heat exchanger/energy recovery unit is disposed in the second flow passage and has a working fluid circulating therethrough for exchange of heat from the exhaust gas to the working fluid. A control valve is disposed downstream of the first and the second flow passages in a low temperature region of the exhaust heat recovery apparatus to direct exhaust gas through the first flow passage or the second flow passage.

  6. 40 CFR 86.110-90 - Exhaust gas sampling system; diesel vehicles.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...) Filter acceptance criteria. Valid diesel particulate net filter weights shall be accepted according to... measure the true mass of both gaseous and particulate emissions in the exhaust of either diesel light-duty.... (vi) Configured so that a clean particulate filter (including back-up filter) can be...

  7. 40 CFR 86.110-90 - Exhaust gas sampling system; diesel vehicles.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ...) Filter acceptance criteria. Valid diesel particulate net filter weights shall be accepted according to... measure the true mass of both gaseous and particulate emissions in the exhaust of either diesel light-duty.... (vi) Configured so that a clean particulate filter (including back-up filter) can be...

  8. 40 CFR 86.110-90 - Exhaust gas sampling system; diesel vehicles.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ...) Filter acceptance criteria. Valid diesel particulate net filter weights shall be accepted according to... measure the true mass of both gaseous and particulate emissions in the exhaust of either diesel light-duty.... (vi) Configured so that a clean particulate filter (including back-up filter) can be...

  9. 77 FR 76842 - Exhaust Emissions Standards for New Aircraft Gas Turbine Engines and Identification Plate for...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2012-12-31

    ... action revises the standards for oxides of nitrogen and test procedures for exhaust emissions based on... Environmental Protection Agency (EPA) proposed new aircraft engine emission standards for oxides of nitrogen (NO... turbojet engines with rated thrusts greater than 26.7 kilonewtons (kN) (76 FR 45012, July 27, 2011)....

  10. Exhaust gas diverter for divided volute turbocharger of internal combustion engine

    SciTech Connect

    Jain, A.; Meistrick, Z.S.; Pitzi, V.J.

    1992-09-15

    This patent describes a divided volute turbocharger diverter disposed between the exhaust manifold of an internal combustion engine and the turbine of the turbocharger, it comprises: first and second volute passageways; an interconnection passageway interconnecting the first and second volute passageways; an a diverter member disposed in only the first of the first and second volute passageways.

  11. 40 CFR 86.110-90 - Exhaust gas sampling system; diesel vehicles.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... 355 °F). This will be determined by a temperature sensor located on a section of the probe wall outside of the dilution tunnel. The temperature sensor shall be insulated from any heating elements on the probe. The sensor shall have an accuracy and precision of ±2 °F (1.1 °C). (14) The dilute exhaust...

  12. Fast spatially resolved exhaust gas recirculation (EGR) distribution measurements in an internal combustion engine using absorption spectroscopy.

    PubMed

    Yoo, Jihyung; Prikhodko, Vitaly; Parks, James E; Perfetto, Anthony; Geckler, Sam; Partridge, William P

    2015-09-01

    Exhaust gas recirculation (EGR) in internal combustion engines is an effective method of reducing NOx emissions while improving efficiency. However, insufficient mixing between fresh air and exhaust gas can lead to cycle-to-cycle and cylinder-to-cylinder non-uniform charge gas mixtures of a multi-cylinder engine, which can in turn reduce engine performance and efficiency. A sensor packaged into a compact probe was designed, built and applied to measure spatiotemporal EGR distributions in the intake manifold of an operating engine. The probe promotes the development of more efficient and higher-performance engines by resolving high-speed in situ CO2 concentration at various locations in the intake manifold. The study employed mid-infrared light sources tuned to an absorption band of CO2 near 4.3 μm, an industry standard species for determining EGR fraction. The calibrated probe was used to map spatial EGR distributions in an intake manifold with high accuracy and monitor cycle-resolved cylinder-specific EGR fluctuations at a rate of up to 1 kHz. PMID:26253286

  13. Fast spatially resolved exhaust gas recirculation (EGR) distribution measurements in an internal combustion engine using absorption spectroscopy.

    PubMed

    Yoo, Jihyung; Prikhodko, Vitaly; Parks, James E; Perfetto, Anthony; Geckler, Sam; Partridge, William P

    2015-09-01

    Exhaust gas recirculation (EGR) in internal combustion engines is an effective method of reducing NOx emissions while improving efficiency. However, insufficient mixing between fresh air and exhaust gas can lead to cycle-to-cycle and cylinder-to-cylinder non-uniform charge gas mixtures of a multi-cylinder engine, which can in turn reduce engine performance and efficiency. A sensor packaged into a compact probe was designed, built and applied to measure spatiotemporal EGR distributions in the intake manifold of an operating engine. The probe promotes the development of more efficient and higher-performance engines by resolving high-speed in situ CO2 concentration at various locations in the intake manifold. The study employed mid-infrared light sources tuned to an absorption band of CO2 near 4.3 μm, an industry standard species for determining EGR fraction. The calibrated probe was used to map spatial EGR distributions in an intake manifold with high accuracy and monitor cycle-resolved cylinder-specific EGR fluctuations at a rate of up to 1 kHz.

  14. Fast Spatially Resolved Exhaust Gas Recirculation (EGR) Distribution Measurements in an Internal Combustion Engine Using Absorption Spectroscopy

    DOE PAGES

    Yoo, Jihyung; Prikhodko, Vitaly; Parks, James E.; Perfetto, Anthony; Geckler, Sam; Partridge, William P.

    2015-09-01

    One effective method of reducing NOx emissions while improving efficiency is exhaust gas recirculation (EGR) in internal combustion engines. But, insufficient mixing between fresh air and exhaust gas can lead to cycle-to-cycle and cylinder-to-cylinder nonuniform charge gas mixtures of a multi-cylinder engine, which can in turn reduce engine performance and efficiency. Furthermore, a sensor packaged into a compact probe was designed, built and applied to measure spatiotemporal EGR distributions in the intake manifold of an operating engine. The probe promotes the development of more efficient and higher-performance engines by resolving high-speed in situ CO2 concentration at various locations in themore » intake manifold. Our study employed mid-infrared light sources tuned to an absorption band of CO2 near 4.3 μm, an industry standard species for determining EGR fraction. The calibrated probe was used to map spatial EGR distributions in an intake manifold with high accuracy and monitor cycle-resolved cylinder-specific EGR fluctuations at a rate of up to 1 kHz.« less

  15. Fast Spatially Resolved Exhaust Gas Recirculation (EGR) Distribution Measurements in an Internal Combustion Engine Using Absorption Spectroscopy

    SciTech Connect

    Yoo, Jihyung; Prikhodko, Vitaly; Parks, James E.; Perfetto, Anthony; Geckler, Sam; Partridge, William P.

    2015-09-01

    One effective method of reducing NOx emissions while improving efficiency is exhaust gas recirculation (EGR) in internal combustion engines. But, insufficient mixing between fresh air and exhaust gas can lead to cycle-to-cycle and cylinder-to-cylinder nonuniform charge gas mixtures of a multi-cylinder engine, which can in turn reduce engine performance and efficiency. Furthermore, a sensor packaged into a compact probe was designed, built and applied to measure spatiotemporal EGR distributions in the intake manifold of an operating engine. The probe promotes the development of more efficient and higher-performance engines by resolving high-speed in situ CO2 concentration at various locations in the intake manifold. Our study employed mid-infrared light sources tuned to an absorption band of CO2 near 4.3 μm, an industry standard species for determining EGR fraction. The calibrated probe was used to map spatial EGR distributions in an intake manifold with high accuracy and monitor cycle-resolved cylinder-specific EGR fluctuations at a rate of up to 1 kHz.

  16. Impact of oxidation catalysts on exhaust NO2/NOx ratio from lean-burn natural gas engines.

    PubMed

    Olsen, Daniel B; Kohls, Morgan; Arney, Gregg

    2010-07-01

    Oxides of nitrogen (NOx) emitted from internal combustion engines are composed primarily of nitric oxide (NO) and nitrogen dioxide (NO2). Exhaust from most combustion sources contains NOx composed primarily of NO. There are two important scenarios specific to lean-burn natural gas engines in which the NO2/NOx ratio can be significant: (1) when the engine is operated at ultralean conditions and (2) when an oxidation catalyst is used. Large NO2/NOx ratios may result in additional uncertainty in NOx emissions measurements because the most common technique (chemiluminescence) was developed for low NO2/NOx ratios. In this work, scenarios are explored in which the NO2/NOx ratio can be large. Additionally, three NOx measurement approaches are compared for exhaust with various NO2/NOx ratios. The three measurement approaches are chemiluminescence, chemical cell, and Fourier-transform infrared spectroscopy. A portable analyzer with chemical cell technology was found to be the most accurate for measuring exhaust NOx with large NO2/NOx ratios. PMID:20681434

  17. Impact of oxidation catalysts on exhaust NO2/NOx ratio from lean-burn natural gas engines.

    PubMed

    Olsen, Daniel B; Kohls, Morgan; Arney, Gregg

    2010-07-01

    Oxides of nitrogen (NOx) emitted from internal combustion engines are composed primarily of nitric oxide (NO) and nitrogen dioxide (NO2). Exhaust from most combustion sources contains NOx composed primarily of NO. There are two important scenarios specific to lean-burn natural gas engines in which the NO2/NOx ratio can be significant: (1) when the engine is operated at ultralean conditions and (2) when an oxidation catalyst is used. Large NO2/NOx ratios may result in additional uncertainty in NOx emissions measurements because the most common technique (chemiluminescence) was developed for low NO2/NOx ratios. In this work, scenarios are explored in which the NO2/NOx ratio can be large. Additionally, three NOx measurement approaches are compared for exhaust with various NO2/NOx ratios. The three measurement approaches are chemiluminescence, chemical cell, and Fourier-transform infrared spectroscopy. A portable analyzer with chemical cell technology was found to be the most accurate for measuring exhaust NOx with large NO2/NOx ratios.

  18. Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions

    SciTech Connect

    D. Straub; D. Ferguson; K. Casleton; G. Richards

    2006-03-01

    U.S. natural gas composition is expected to be more variable in the future. Liquefied natural gas (LNG) imports to the U.S. are expected to grow significantly over the next 10-15 years. Unconventional gas supplies, like coal-bed methane, are also expected to grow. As a result of these anticipated changes, the composition of fuel sources may vary significantly from existing domestic natural gas supplies. To allow the greatest use of gas supplies, end-use equipment should be able to accommodate the widest possible gas composition. For this reason, the effect of gas composition on combustion behavior is of interest. This paper will examine the effects of fuel variability on pollutant emissions for premixed gas turbine conditions. The experimental data presented in this paper have been collected from a pressurized single injector combustion test rig at the National Energy Technology Laboratory (NETL). The tests are conducted at 7.5 atm with a 589K air preheat. A propane blending facility is used to vary the Wobbe Index of the site natural gas. The results indicate that propane addition of about five (vol.) percent does not lead to a significant change in the observed NOx emissions. These results vary from data reported in the literature for some engine applications and potential reasons for these differences are discussed.

  19. Response to 'Comment on 'Experimental observation of carbon dioxide reduction in exhaust gas from hydrocarbon fuel burning'' [Phys. Plasmas 17, 014701 (2010)

    SciTech Connect

    Uhm, Han S.; Kim, Chul H.

    2010-01-15

    A high-voltage cathode initiates an electron emission, resulting in a reduction in the carbon dioxide concentration in exhaust gas from the burning of hydrocarbon fuel. Assuming that the observed carbon dioxide reduction is originated from the molecular decomposition, the energy needed for the endothermic reaction of this carbon dioxide reduction may stem primarily from the internal energy reduction in the exhaust gas in accordance of the first law of the thermodynamics. An oxygen increase due to the reduction in carbon dioxide in a discharge gas was observed in real time.

  20. 40 CFR 86.110-94 - Exhaust gas sampling system; diesel-cycle vehicles, and Otto-cycle vehicles requiring particulate...

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ...-fueled and liquefied petroleum gas-fueled diesel-cycle vehicles), and particulate sampling capabilities... that a clean particulate filter (including back up filter) can be selected simultaneously with the... 40 Protection of Environment 19 2012-07-01 2012-07-01 false Exhaust gas sampling system;...

  1. 40 CFR 86.110-94 - Exhaust gas sampling system; diesel-cycle vehicles, and Otto-cycle vehicles requiring particulate...

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ...-fueled and liquefied petroleum gas-fueled diesel-cycle vehicles), and particulate sampling capabilities... that a clean particulate filter (including back up filter) can be selected simultaneously with the... 40 Protection of Environment 19 2013-07-01 2013-07-01 false Exhaust gas sampling system;...

  2. 40 CFR 86.1710-99 - Fleet average non-methane organic gas exhaust emission standards for light-duty vehicles and...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Fleet average non-methane organic gas....1710-99 Fleet average non-methane organic gas exhaust emission standards for light-duty vehicles and light light-duty trucks. (a) Fleet average NMOG standards and compliance. (1) Each manufacturer...

  3. Catalysts to reduce NO.sub.x in an exhaust gas stream and methods of preparation

    DOEpatents

    Castellano, Christopher R.; Moini, Ahmad; Koermer, Gerald S.; Furbeck, Howard; Schmieg, Steven J.; Blint, Richard J.

    2011-05-17

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having a catalyst comprising silver and a platinum group metal on a particulate alumina support, the atomic fraction of the platinum group metal being less than or equal to about 0.25. Methods of manufacturing catalysts are described in which silver is impregnated on alumina particles.

  4. Catalysts to reduce NO.sub.x in an exhaust gas stream and methods of preparation

    DOEpatents

    Koermer, Gerald S.; Moini, Ahmad; Furbeck, Howard; Castellano, Christopher R.

    2012-05-08

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having a catalyst comprising silver on a particulate alumina support, the silver having a diameter of less than about 20 nm. Methods of manufacturing catalysts are described in which ionic silver is impregnated on particulate hydroxylated alumina particles.

  5. Unified account of gas pollutants and greenhouse gas emissions: Chinese transportation 1978-2004

    NASA Astrophysics Data System (ADS)

    Ji, Xi; Chen, G. Q.

    2010-09-01

    To facilitate the aggregation of both quantity and quality of waste emissions, the concept of chemical exergy combining the first and second laws of thermodynamics is introduced for a unified account of gas pollutants and greenhouse gases, by a case study for the Chinese transportation system 1978-2004 with main gas pollutants of NO, SO2, CO and main greenhouse gases of CO2 and CH4. With chemical exergy emission factors concretely estimated, the total emission as well as emission intensity by exergy of the overall transportation system and of its four modes of highways, railways, waterways and civil aviation are accounted in full detail and compared with those by the conventionally prevailing metrics of mass, with essential implications for environmental policy making.

  6. Exhaust Gas Recirculation Cooler Fouling in Diesel Applications: Fundamental Studies Deposit Properties and Microstructure

    SciTech Connect

    Storey, John Morse; Sluder, Scott; Lance, Michael J; Styles, Dan; Simko, Steve

    2013-01-01

    This paper reports on the results of experimental efforts aimed at improving the understanding of the mechanisms and conditions at play in the fouling of EGR coolers. An experimental apparatus was constructed to utilize simplified surrogate heat exchanger tubes in lieu of full-size heat exchangers. The use of these surrogate tubes allowed removal of the tubes after exposure to engine exhaust for study of the deposit layer and its properties. The exhaust used for fouling the surrogate tubes was produced using a modern medium-duty diesel engine fueled with both ultra-low sulfur diesel and biodiesel blends. At long exposure times, no significant difference in the fouling rate was observed between fuel types and HC levels. Surface coatings for the tubes were also evaluated to determine their impact on deposit growth. No surface treatment or coating produced a reduction in the fouling rate or any evidence of deposit removal. In addition, microstructural analysis of the fouling layers was performed using optical and electron microscopy in order to better understand the deposition mechanism. The experimental results are consistent with thermophoretic deposition for deposit formation, and van der Waals attraction between the deposit surface and exhaust-borne particulate.

  7. Meeting future exhaust emissions standards using natural gas as a vehicle fuel: Lessons learned from the natural gas vehicle challenge `92

    SciTech Connect

    Rimkus, W.A.; Larsen, R.P.

    1992-09-01

    The Natural Gas Vehicle Challenge `92, organized by Argonne National Laboratory and sponsored by the US Department of Energy, the Energy, Mines, and Resources - Canada, the Society of Automotive Engineers, and many others, resulted in 20 varied approaches to the conversion of a gasoline-fueled, spark-ignited, internal combustion engine to dedicated natural gas use. Starting with a GMC Sierra 2500 pickup truck, donated by General Motors, teams of college and university student engineers strived to optimize Chevrolet V-8 engines operating on natural gas for improved emissions, fuel economy, performance, and advanced design features. This paper focuses on the results of the emission event, and compares engine mechanical configurations, engine management systems, catalyst configurations and locations, and approaches to fuel control and the relationship of these parameters to engine-out and tailpipe emissions of regulated exhaust constituents. Nine of the student-modified trucks passed the current levels of exhaust emission standards, and some exceeded the strictest future emissions standards envisioned by the US Environmental Protection Agency. Factors in achieving good emissions control using natural gas are summarized, and observations concerning necessary components of a successful emissions control strategy are presented.

  8. Meeting future exhaust emissions standards using natural gas as a vehicle fuel: Lessons learned from the natural gas vehicle challenge '92

    SciTech Connect

    Rimkus, W.A.; Larsen, R.P.

    1992-01-01

    The Natural Gas Vehicle Challenge '92, organized by Argonne National Laboratory and sponsored by the US Department of Energy, the Energy, Mines, and Resources - Canada, the Society of Automotive Engineers, and many others, resulted in 20 varied approaches to the conversion of a gasoline-fueled, spark-ignited, internal combustion engine to dedicated natural gas use. Starting with a GMC Sierra 2500 pickup truck, donated by General Motors, teams of college and university student engineers strived to optimize Chevrolet V-8 engines operating on natural gas for improved emissions, fuel economy, performance, and advanced design features. This paper focuses on the results of the emission event, and compares engine mechanical configurations, engine management systems, catalyst configurations and locations, and approaches to fuel control and the relationship of these parameters to engine-out and tailpipe emissions of regulated exhaust constituents. Nine of the student-modified trucks passed the current levels of exhaust emission standards, and some exceeded the strictest future emissions standards envisioned by the US Environmental Protection Agency. Factors in achieving good emissions control using natural gas are summarized, and observations concerning necessary components of a successful emissions control strategy are presented.

  9. Onboard Plasmatron Generation of Hydrogen rich Gas for Diesel Engine Exhaust Aftertreatment and Other Applications

    SciTech Connect

    Bromberg, L.; Cohn, D.R.; Heywood,J.; Rabinovich, A.

    2002-08-25

    Plasmatron reformers can provide attractive means for conversion of diesel fuel into hydrogen rich gas. The hydrogen rich gas can be used for improved NOx trap technology and other aftertreatment applications.

  10. 40 CFR 86.1311-94 - Exhaust gas analytical system; CVS bag sample.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... ionization detector. The analysis for formaldehyde is performed using high pressure liquid chromatography..., “Methane Measurement Using Gas Chromatography.” (Incorporated by reference pursuant to § 86.1(b)(2).) (ii) For natural gas vehicles, the manufacturer has the option of using gas chromatography to measure...

  11. 40 CFR 86.1311-94 - Exhaust gas analytical system; CVS bag sample.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... ionization detector. The analysis for formaldehyde is performed using high pressure liquid chromatography..., “Methane Measurement Using Gas Chromatography.” (Incorporated by reference pursuant to § 86.1(b)(2).) (ii) For natural gas vehicles, the manufacturer has the option of using gas chromatography to measure...

  12. 40 CFR 86.1311-94 - Exhaust gas analytical system; CVS bag sample.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... ionization detector. The analysis for formaldehyde is performed using high pressure liquid chromatography..., “Methane Measurement Using Gas Chromatography.” (Incorporated by reference pursuant to § 86.1(b)(2).) (ii) For natural gas vehicles, the manufacturer has the option of using gas chromatography to measure...

  13. Detection of ethene and other hydrocarbons in gas turbine engine exhaust using non-intrusive FTIR spectroscopy

    NASA Astrophysics Data System (ADS)

    Arrigone, Giovanni M.; Welch, Michael A.; Hilton, Moira; Miller, Michael N.; Wilson, Christopher W.

    2003-04-01

    As part of the EU funded project AEROJET2, a number of gas turbine engine tests were performed in different facilities around Europe. At Farnborough, UK a Spey engine was used to test a suite of prototype optically based instrumentation designed to measure exhaust gas emissions without using extractive probe systems. In addition to the AEROJET 2 prototype instrumentation, a Bruker Equinox 55 Fourier transform infrared (FTIR) spectrometer was used to obtain infrared spectra of the exhaust plume both in emission and absorption mode. The Bruker FTIR spectrometer was fitted with a periscope system so that different lines of sight could be monitored in the plume in a vertical plane 25 cm downstream from the nozzle exit and 20 cm upstream of the center line of sight of the AEROJET 2 prototype instrumentation. DERA (now QinetiQ) provided exhaust gas analysis data for different engine running conditions using samples extracted from the plume with an intrusive probe. The probe sampled along a horizontal plane across the centerline of the engine 45 cm downstream of the nozzle exit. The Bruker spectrometer used both InSb (indium antimonide) and MCT (mercury-cadmium-telluride) detectors to maximize the sensitivity across the IR range 600-4000 cm-1. Typically, CO2 and H2O IR signatures dominate the observed spectra of the plume. However, the engine tests showed that at low power engine conditions spectral features associated with CO around 2147 cm-1 and with hydrocarbons could be observed at around 3000 cm-1. In particular the presence of ethene (C2H2) was detected from observation of its characteristic in and out of plane vibration mode at 949 cm-1. At high engine powers the presence of NO was detected at 1900.3 cm-1. Species concentrations were calculated using a slab model for each line of sight compared against reference spectra. The engine plume was assumed to be symmetric about the centerline. On this basis, data from the extractive sampling gas analysis that had been

  14. Manganese accumulation in soil and plants along Utah roadways: A possible indication of motor vehicle exhaust pollution

    SciTech Connect

    Lytle, C.M.; Smith, B.N.; McKinnon, C.Z.

    1995-06-01

    An organic manganese compound is currently added to gasoline to replace tetraethyl lead as an antiknock fuel additive in the U.S. and Canada. Combustion exhaust gases contain manganese oxides. Manganese oxides are known to cause various deleterious health effects in experimental animals and humans. A field survey of roadside soil and plants in central Utah revealed that soil manganese concentrations in high traffic areas were up to 100-fold higher than historic lead levels. Soil manganese concentrations were highly correlated with distance from the roadway. In addition, roadside aquatic plants were higher in leaf tissue manganese than herbs or grasses. Submerged and emergent aquatic plants were sensitive bioindicators of manganese contamination. Manganese concentrations in soil and in some plant species along impacted roadsides often exceeded levels known to cause toxicity. We conclude that roadside soil and plants were apparently contaminated by manganese oxides from Mn-containing motor vehicle exhaust.

  15. CFD Investigation of Pollutant Emission in Can-Type Combustor Firing Natural Gas, LNG and Syngas

    NASA Astrophysics Data System (ADS)

    Hasini, H.; Fadhil, SSA; Mat Zian, N.; Om, NI

    2016-03-01

    CFD investigation of flow, combustion process and pollutant emission using natural gas, liquefied natural gas and syngas of different composition is carried out. The combustor is a can-type combustor commonly used in thermal power plant gas turbine. The investigation emphasis on the comparison of pollutant emission such in particular CO2, and NOx between different fuels. The numerical calculation for basic flow and combustion process is done using the framework of ANSYS Fluent with appropriate model assumptions. Prediction of pollutant species concentration at combustor exit shows significant reduction of CO2 and NOx for syngas combustion compared to conventional natural gas and LNG combustion.

  16. Non-Thermal Removal of Gaseous Pollutants

    NASA Technical Reports Server (NTRS)

    Srivastava, S.; McGowan, J. William; Chiu, K. C. Ray

    1995-01-01

    The removal of fluorine based exhaust gases such as CFC's, PFC's, NF3, and SF6 used for plasma etching of and deposition on semi-conductors is a subject of increasing interest because of safety, air pollution, and global warming issues. Conventional treatment methods for removing exhaust gas pollutants are wet scrubbing, carbon and resin adsorption, catalytic oxidation, and thermal incineration. However, there are drawbacks associated with each of these methods which include difficulties in implementation, problems with the disposal of solid and liquid pollutant waste, large water and fuel consumption, and additional pollutants such as NOx emissions which are generated in thermal incineration processes.

  17. Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions

    SciTech Connect

    Straub, D.L.; Ferguson, D.H.; Casleton, K.H.; Richards, G.A.

    2007-03-01

    Liquefied natural gas (LNG) imports to the U.S. are expected to grow significantly over the next 10-15 years. Likewise, it is expected that changes to the domestic gas supply may also introduce changes in natural gas composition. As a result of these anticipated changes, the composition of fuel sources may vary significantly from conventional domestic natural gas supplies. This paper will examine the effects of fuel variability on pollutant emissions for premixed gas turbine conditions. The experimental data presented in this paper have been collected from a pressurized single injector combustion test rig at the National Energy Technology Laboratory (NETL). The tests are conducted at 7.5 atm with a 588 K air preheat. A propane blending facility is used to vary the Wobbe Index of the site natural gas. The results indicate that propane addition of about five (vol.) percent does not lead to a significant change in the observed NOx or CO emissions. These results are different from data collected on some engine applications and potential reasons for these differences will be described.

  18. Market structure and exhaustible resources: The case of natural gas and crude oil in California

    NASA Astrophysics Data System (ADS)

    Czastkiewicz, Carolina

    Using a dataset of natural gas and crude oil production in the state of California, evidence shows overextraction incentives among market participants that shared a common pool. Due to these incentives the supply of gas and crude oil extraction tends to become more inelastic as the number of firms in the pool increases. Using an instrumental variables estimation of the supply function, the results show that the common pool externality caused an average overproduction rate of 11% and 4% over the 1977--2001 period, in natural gas and crude oil, respectively. These figures imply 1 year and 4 years of additional production for natural gas and crude oil, respectively.

  19. 40 CFR 600.112-08 - Exhaust sample analysis.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... FUEL ECONOMY AND GREENHOUSE GAS EXHAUST EMISSIONS OF MOTOR VEHICLES Fuel Economy and Carbon-Related Exhaust Emission Test Procedures § 600.112-08 Exhaust sample analysis. The exhaust sample analysis must...

  20. 76 FR 58288 - International Maritime Organization Guidelines for Exhaust Gas Cleaning Systems for Marine...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2011-09-20

    ... 4 of the International Convention for the Prevention of Pollution by Ships, 1973 as modified by the... effective in reducing sulfur oxide emissions as the requirements of MARPOL Annex VI regulation 14. DATES... systems for marine engines to remove sulfur oxide emissions. Annex VI regulation 4 of the...

  1. Effects of prevaporized fuel on exhaust emissions of an experimental gas turbine combustor

    NASA Technical Reports Server (NTRS)

    Norgren, C. T.; Ingebo, R. D.

    1973-01-01

    Effects of fuel vaporization on the exhaust emission levels of oxides of nitrogen (NOX), carbon monoxide, total hydrocarbons, and smoke number were obtained in an experimental turbojet combustor segment. Two fuel injector types were used in which liquid ASTM A-1 jet fuel and vapor propane fuel were independently controlled to simulate varying degrees of vaporization. Tests were conducted over a range of inlet-air temperatures from 478 to 700 K (860 to 1260 R), pressures from 4 to 20 atmospheres, and combustor reference velocities from 15.3 to 27.4 m/sec (50 to 90 ft/sec). Converting from liquid to complete vapor fuel resulted in NOX reductions as much as 22 percent and smoke number reductions up to 51 percent.

  2. Mixing effectiveness test of an exhaust gas mixer in a high bypass turbofan at altitude

    NASA Technical Reports Server (NTRS)

    Cullom, R. R.; Bobula, G. A.; Burkardt, L. A.

    1981-01-01

    Thermal mixing effectiveness characteristics of an eighteen lobe, scalloped and unscalloped, partial, forced mixer were measured in a high-bypass turbofan engine. Data were also obtained without the mixer installed, i.e., free mixing. Tests were conducted at four combinations of simulated flight conditions from 0.3 to 0.8 Mach number and from 6,096 meters (20,000 ft) to 13,715 m (45,000 ft) altitude, mixing chamber lengths of L/D=0.52 and 0.65 were tested. For this range of test conditions and mixer configurations, the forced mixing effectiveness varied from 59 to 68 percent. Values of mixing effectiveness and total pressure loss were calculated from temperature and pressure data obtained at the mixer inlet and exhaust nozzle exit.

  3. Review of homogeneous charge compression ignition (HCCI) combustion engines and exhaust gas recirculation (EGR) effects on HCCI

    NASA Astrophysics Data System (ADS)

    Akma Tuan Kamaruddin, Tengku Nordayana; Wahid, Mazlan Abdul; Sies, Mohsin Mohd

    2012-06-01

    This paper describes the development in ICE which leads to the new advanced combustion mode named Homogeneous Charge Compression Ignition (HCCI). It explains regarding the theory and working principle of HCCI plus the difference of the process in gasoline and diesel fuelled engines. Many of pioneer and recent research works are discussed to get the current state of art about HCCI. It gives a better indication on the potential of this method in improving the fuel efficiency and emission produced by the vehicles' engine. Apart from the advantages, the challenges and future trend of this technology are also included. HCCI is applying few types of control strategy in producing the optimum performance. This paper looks into Exhaust Gas Recirculation (EGR) as one of the control strategies.

  4. The study of heat transfer for nanofluid with carbon nano particle in an exhaust gas recirculation (EGR) cooler

    NASA Astrophysics Data System (ADS)

    Kim, Seongsoo; Chung, Hanshik; Jeong, Hyomin; Lee, Byungho; Ochirkhuyag, Bayanjargal; Lee, Jehyun; Choi, Heekyu

    2013-07-01

    A carbon nanofluid was adapted to examine the characteristics of its cooling performance in an exhaust gas recirculation (EGR) cooler, compared with that of the usual working fluid water. After steady state, the heat transfer rate of water became nearly constant; however, that of the nanofluid showed a slight increase, suggesting that something happened to the nanofluid. The result shows that the cooling performance of the carbon nanofluid was a little better than that of water; however, its performance data improved with time while those of water were stable. It shows that assembly of the carbon nanoparticles changed with its circulation through the EGR cooler and the shape of the particle assembly depended on the dispersion method employed.

  5. The Use of Exhaust Gas Recirculation to Optimize Fuel Economy and Minimize Emission in Engines Operating on E85 Fuel

    SciTech Connect

    Wu, Ko-Jen

    2011-12-31

    This report summarizes activities conducted for the project “The Use of Exhaust Gas Recirculation to Optimized Fuel Economy and Minimize Emissions in Engines Operating on E85 Fuel” under COOPERATIVE AGREEMENT NUMBER DE-FC26-07NT43271, which are as outlined in the STATEMENT OF PROJECT OBJECTIVES (SOPO) dated March 2007 and in the supplemental SOPO dated October 2010. The project objective was to develop and demonstrate an internal combustion engine that is optimized for E85 (85% ethanol and 15% gasoline) fuel operation to achieve substantially improved fuel economy while operating with E85 fuel and that is also production viable in the near- to medium-term. The key engine technology selected for research and development was turbocharging, which is known to improve fuel economy thru downsizing and is in particular capable of exploiting ethanol fuel’s characteristics of high octane number and high latent heat of vaporization. The engine further integrated synergistic efficiency improving technologies of cooled exhaust gas recirculation (EGR), direct fuel injection and dual continuously variable intake and exhaust cam phasers. On the vehicle level, fuel economy was furthered thru powertrain system optimization by mating a state-of-the-art six-speed automatic transmission to the engine. In order to achieve the project’s objective of near- to medium-term production viability, it was essential to develop the engine to be flex-fuel capable of operating with fuels ranging from E0 (0% ethanol and 100% gasoline) to E85 and to use three-way type of catalyst technology for exhaust aftertreatment. Within these scopes, various technologies were developed through systems approach to focus on ways to help accelerate catalyst light-off. Significant amount of development took place during the course of the project within General Motors, LLC. Many prototype flex-fuel engines were designed, built and developed with various hardware configurations selected to achieve the project

  6. Estimation of current density distribution of PAFC by analysis of cell exhaust gas

    SciTech Connect

    Kato, S.; Seya, A.; Asano, A.

    1996-12-31

    To estimate distributions of Current densities, voltages, gas concentrations, etc., in phosphoric acid fuel cell (PAFC) stacks, is very important for getting fuel cells with higher quality. In this work, we leave developed a numerical simulation tool to map out the distribution in a PAFC stack. And especially to Study Current density distribution in the reaction area of the cell, we analyzed gas composition in several positions inside a gas outlet manifold of the PAFC stack. Comparing these measured data with calculated data, the current density distribution in a cell plane calculated by the simulation, was certified.

  7. Device for the removal of sulfur dioxide from exhaust gas by pulsed energization of free electrons

    SciTech Connect

    Mizuno, A.; Clements, J.S.; Davis, R.H.

    1984-01-01

    The performance of a new device using pulsed streamer corona for the removal of sulfur dioxide from humid air has been evaluated. The pulsed streamer corona produced free electrons which enhance gas-phase chemical reactions, and convert SO/sub 2/ to sulfuric acid mist. The SO/sub 2/ removal efficiency was compared with that of the electron-beam flue-gas treatment process. The comparison demonstrates the advantage of the novel device.

  8. 40 CFR 1036.241 - Demonstrating compliance with greenhouse gas pollutant standards.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... greenhouse gas pollutant standards. 1036.241 Section 1036.241 Protection of Environment ENVIRONMENTAL... HIGHWAY ENGINES Certifying Engine Families § 1036.241 Demonstrating compliance with greenhouse gas... deterioration factors as follows: (1) Additive deterioration factor for greenhouse gas emissions. Except...

  9. 40 CFR 1036.241 - Demonstrating compliance with greenhouse gas pollutant standards.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... greenhouse gas pollutant standards. 1036.241 Section 1036.241 Protection of Environment ENVIRONMENTAL... HIGHWAY ENGINES Certifying Engine Families § 1036.241 Demonstrating compliance with greenhouse gas... deterioration factors as follows: (1) Additive deterioration factor for greenhouse gas emissions. Except...

  10. 40 CFR 1036.241 - Demonstrating compliance with greenhouse gas pollutant standards.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... greenhouse gas pollutant standards. 1036.241 Section 1036.241 Protection of Environment ENVIRONMENTAL... HIGHWAY ENGINES Certifying Engine Families § 1036.241 Demonstrating compliance with greenhouse gas... deterioration factors as follows: (1) Additive deterioration factor for greenhouse gas emissions. Except...

  11. Near-highway pollutants in motor vehicle exhaust: A review of epidemiologic evidence of cardiac and pulmonary health risks

    PubMed Central

    Brugge, Doug; Durant, John L; Rioux, Christine

    2007-01-01

    There is growing evidence of a distinct set of freshly-emitted air pollutants downwind from major highways, motorways, and freeways that include elevated levels of ultrafine particulates (UFP), black carbon (BC), oxides of nitrogen (NOx), and carbon monoxide (CO). People living or otherwise spending substantial time within about 200 m of highways are exposed to these pollutants more so than persons living at a greater distance, even compared to living on busy urban streets. Evidence of the health hazards of these pollutants arises from studies that assess proximity to highways, actual exposure to the pollutants, or both. Taken as a whole, the health studies show elevated risk for development of asthma and reduced lung function in children who live near major highways. Studies of particulate matter (PM) that show associations with cardiac and pulmonary mortality also appear to indicate increasing risk as smaller geographic areas are studied, suggesting localized sources that likely include major highways. Although less work has tested the association between lung cancer and highways, the existing studies suggest an association as well. While the evidence is substantial for a link between near-highway exposures and adverse health outcomes, considerable work remains to understand the exact nature and magnitude of the risks. PMID:17688699

  12. E-Alerts: Environmental pollution and control (air pollution and control). E-mail newsletter

    SciTech Connect

    1999-04-01

    Topics of discussion include the following: Air pollution from flue gases, exhaust gases, odors, dust, smog, microorganisms, etc.; Control techniques and equipment; Sampling and analytical techniques, and equipment; Waste gas recovery; Biological and ecological effects; Air pollution chemistry; Acid precipitation; Atmospheric motion; Laws, legislation, and regulations; Public administration; Economics; Land use.

  13. Gas-particle partitioning of primary organic aerosol emissions: (1) Gasoline vehicle exhaust

    NASA Astrophysics Data System (ADS)

    May, Andrew A.; Presto, Albert A.; Hennigan, Christopher J.; Nguyen, Ngoc T.; Gordon, Timothy D.; Robinson, Allen L.

    2013-10-01

    The gas-particle partitioning of the primary organic aerosol (POA) emissions from fifty-one light-duty gasoline vehicles (model years 1987-2012) was investigated at the California Air Resources Board Haagen-Smit Laboratory. Each vehicle was operated over the cold-start unified cycle on a chassis dynamometer and its emissions were sampled using a constant volume sampler. Four independent yet complementary approaches were used to investigate POA gas-particle partitioning: sampling artifact correction of quartz filter data, dilution from the constant volume sampler into a portable environmental chamber, heating in a thermodenuder, and thermal desorption/gas chromatography/mass spectrometry analysis of quartz filter samples. This combination of techniques allowed gas-particle partitioning measurements to be made across a wide range of atmospherically relevant conditions - temperatures of 25-100 °C and organic aerosol concentrations of <1-600 μg m-3. The gas-particle partitioning of the POA emissions varied continuously over this entire range of conditions and essentially none of the POA should be considered non-volatile. Furthermore, for most vehicles, the low levels of dilution used in the constant volume sampler created particle mass concentrations that were greater than a factor of 10 or higher than typical ambient levels. This resulted in large and systematic partitioning biases in the POA emission factors compared to more dilute atmospheric conditions, as the POA emission rates may be over-estimated by nearly a factor of four due to gas-particle partitioning at higher particle mass concentrations. A volatility distribution was derived to quantitatively describe the measured gas-particle partitioning data using absorptive partitioning theory. Although the POA emission factors varied by more than two orders of magnitude across the test fleet, the vehicle-to-vehicle differences in gas-particle partitioning were modest. Therefore, a single volatility distribution

  14. METHANE EMISSIONS FROM THE NATURAL GAS INDUSTRY VOLUME 11: COMPRESSOR DRIVER EXHAUST

    EPA Science Inventory

    The 15-volume report summarizes the results of a comprehensive program to quantify methane (CH4) emissions from the U.S. natural gas industry for the base year. The objective was to determine CH4 emissions from the wellhead and ending downstream at the customer's meter. The accur...

  15. 78 FR 63015 - Exhaust Emissions Standards for New Aircraft Gas Turbine Engines and Identification Plate for...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-10-23

    ... kilonewtons (kN) (76 FR 45012). The EPA also proposed adopting the gas turbine engine test procedures of the... 18, 2012 (77 FR 36342), and was effective July 18, 2012. On December 31, 2012, the FAA published a final rule with a request for comments (77 FR 76842) adopting the EPA's new emissions standards in...

  16. Mutagenicity of diesel engine exhaust is eliminated in the gas phase by an oxidation catalyst but only slightly reduced in the particle phase.

    PubMed

    Westphal, Götz A; Krahl, Jürgen; Munack, Axel; Ruschel, Yvonne; Schröder, Olaf; Hallier, Ernst; Brüning, Thomas; Bünger, Jürgen

    2012-06-01

    Concerns about adverse health effects of diesel engine emissions prompted strong efforts to minimize this hazard, including exhaust treatment by diesel oxidation catalysts (DOC). The effectiveness of such measures is usually assessed by the analysis of the legally regulated exhaust components. In recent years additional analytical and toxicological tests were included in the test panel with the aim to fill possible analytical gaps, for example, mutagenic potency of polycyclic aromatic hydrocarbons (PAH) and their nitrated derivatives (nPAH). This investigation focuses on the effect of a DOC on health hazards from combustion of four different fuels: rapeseed methyl ester (RME), common mineral diesel fuel (DF), SHELL V-Power Diesel (V-Power), and ARAL Ultimate Diesel containing 5% RME (B5ULT). We applied the European Stationary Cycle (ESC) to a 6.4 L turbo-charged heavy load engine fulfilling the EURO III standard. The engine was operated with and without DOC. Besides regulated emissions we measured particle size and number distributions, determined the soluble and solid fractions of the particles and characterized the bacterial mutagenicity in the gas phase and the particles of the exhaust. The effectiveness of the DOC differed strongly in regard to the different exhaust constituents: Total hydrocarbons were reduced up to 90% and carbon monoxide up to 98%, whereas nitrogen oxides (NO(X)) remained almost unaffected. Total particle mass (TPM) was reduced by 50% with DOC in common petrol diesel fuel and by 30% in the other fuels. This effect was mainly due to a reduction of the soluble organic particle fraction. The DOC caused an increase of the water-soluble fraction in the exhaust of RME, V-Power, and B5ULT, as well as a pronounced increase of nitrate in all exhausts. A high proportion of ultrafine particles (10-30 nm) in RME exhaust could be ascribed to vaporizable particles. Mutagenicity of the exhaust was low compared to previous investigations. The DOC reduced

  17. Fuel-air mixing apparatus for reducing gas turbine combustor exhaust emissions

    NASA Technical Reports Server (NTRS)

    Zupanc, Frank J. (Inventor); Yankowich, Paul R. (Inventor)

    2006-01-01

    A fuel-air mixer for use in a combustion chamber of a gas turbine engine is provided. The fuel air mixing apparatus comprises an annular fuel injector having a plurality of discrete plain jet orifices, a first swirler wherein the first swirler is located upstream from the fuel injector and a second swirler wherein the second swirler is located downstream from the fuel injector. The plurality of discrete plain jet orifices are situated between the highly swirling airstreams generated by the two radial swirlers. The distributed injection of the fuel between two highly swirling airstreams results in rapid and effective mixing to the desired fuel-air ratio and prevents the formation of local hot spots in the combustor primary zone. A combustor and a gas turbine engine comprising the fuel-air mixer of the present invention are also provided as well as a method using the fuel-air mixer of the present invention.

  18. Hanford Site radionuclide national emission standards for hazardous ari pollutants registered and and unregistered stack (powered exhaust) source assessment

    SciTech Connect

    Davis, W.E.

    1995-12-01

    On February 3, 1993, US DOE Richland Operations Office received a Compliance Order and Information Request from the Director of the Air and Toxics Div. of US EPA, Region X. The compliance order requires the Richland Operations Office to evaluate all radionuclide emission points at the Hanford site to determine which are subject to the continuous emission measurement requirements in Title 40, Code of Federal Regulations (CFR), Part 61, Subpart H, and to continuously measure radionuclide emissions in accordance with 40 CFR 61.93. The Information Request required The provision of a written compliance plan to meet the requirements of the compliance order. A compliance plan was submitted to EPA, Region X, on April 30, 1993. It set as one of the milestones, the complete assessment of the Hanford Site 84 stacks registered with the Washington State Department of Health, by December 17, 1993. This milestone was accomplished. The compliance plan also called for reaching a Federal Facility Compliance Agreement; this was reached on February 7, 1994, between DOE Richland Operations and EPA, Region X. The milestone to assess the unregistered stacks (powered exhaust) by August 31, 1994, was met. This update presents assessments for 72 registered and 22 unregistered stacks with potential emissions > 0.1 mrem/yr.

  19. Recommended launch-hold criteria for protecting public health from hydrogen chloride (HC1) gas produced by rocket exhaust

    SciTech Connect

    Daniels, J.I.; Baskett, R.L.

    1995-11-01

    Solid-fuel rocket motors used by the United States Air Force (USAF) to launch missiles and spacecraft can produce ambient-air concentrations of hydrogen chloride (HCI) gas. The HCI gas is a reaction product exhausted from the rocket motor during normal launch or emitted as a result of a catastrophic abort destroying the launch vehicle. Depending on the concentration in ambient air, the HCI gas can be irritating or toxic to humans. The diagnostic and complex-terrain wind field and particle dispersion model used by the Lawrence Livermore National Laboratory`s (LLNL`s) Atmospheric Release Advisory Capability (ARAC) Program was applied to the launch of a Peacekeeper missile from Vandenberg Air Force Base (VAFB) in California. Results from this deterministic model revealed that under specific meteorological conditions, cloud passage from normal-launch and catastropic-abort situations can yield measureable ground-level air concentrations of HCI where the general public is located. To protect public health in the event of such cloud passage, scientifically defensible, emergency ambient-air concentration limits for HCI were developed and recommended to the USAF for use as launch-hold criteria. Such launch-hold criteria are used to postpone a launch unless the forecasted meteorological conditions favor the prediction of safe ground-level concentrations of HCl for the general public. The recommended concentration limits are a 2 ppM 1-h time-weighted average (TWA) concentration constrained by a 1-min 10-ppM average concentration. This recommended criteria is supported by human dose-response information, including data for sensitive humans (e.g., asthmatics), and the dose response exhibited experimentally by animal models with respiratory physiology or responses considered similar to humans.

  20. Gas Turbine Engine Having Fan Rotor Driven by Turbine Exhaust and with a Bypass

    NASA Technical Reports Server (NTRS)

    Suciu, Gabriel L. (Inventor); Chandler, Jesse M. (Inventor)

    2016-01-01

    A gas turbine engine has a core engine incorporating a core engine turbine. A fan rotor is driven by a fan rotor turbine. The fan rotor turbine is in the path of gases downstream from the core engine turbine. A bypass door is moveable from a closed position at which the gases from the core engine turbine pass over the fan rotor turbine, and moveable to a bypass position at which the gases are directed away from the fan rotor turbine. An aircraft is also disclosed.

  1. Gas flaring and resultant air pollution: A review focusing on black carbon.

    PubMed

    Fawole, Olusegun G; Cai, X-M; MacKenzie, A R

    2016-09-01

    Gas flaring is a prominent source of VOCs, CO, CO2, SO2, PAH, NOX and soot (black carbon), all of which are important pollutants which interact, directly and indirectly, in the Earth's climatic processes. Globally, over 130 billion cubic metres of gas are flared annually. We review the contribution of gas flaring to air pollution on local, regional and global scales, with special emphasis on black carbon (BC, "soot"). The temporal and spatial characteristics of gas flaring distinguishes it from mobile combustion sources (transport), while the open-flame nature of gas flaring distinguishes it from industrial point-sources; the high temperature, flame control, and spatial compactness distinguishes gas flaring from both biomass burning and domestic fuel-use. All of these distinguishing factors influence the quantity and characteristics of BC production from gas flaring, so that it is important to consider this source separately in emissions inventories and environmental field studies. Estimate of the yield of pollutants from gas flaring have, to date, paid little or no attention to the emission of BC with the assumption often being made that flaring produces a smokeless flame. In gas flares, soot yield is known to depend on a number of factors, and there is a need to develop emission estimates and modelling frameworks that take these factors into consideration. Hence, emission inventories, especially of the soot yield from gas flaring should give adequate consideration to the variation of fuel gas composition, and to combustion characteristics, which are strong determinants of the nature and quantity of pollutants emitted. The buoyant nature of gas flaring plume, often at temperatures in the range of 2000 K, coupled with the height of the stack enables some of the pollutants to escape further into the free troposphere aiding their long-range transport, which is often not well-captured by model studies.

  2. Gas flaring and resultant air pollution: A review focusing on black carbon.

    PubMed

    Fawole, Olusegun G; Cai, X-M; MacKenzie, A R

    2016-09-01

    Gas flaring is a prominent source of VOCs, CO, CO2, SO2, PAH, NOX and soot (black carbon), all of which are important pollutants which interact, directly and indirectly, in the Earth's climatic processes. Globally, over 130 billion cubic metres of gas are flared annually. We review the contribution of gas flaring to air pollution on local, regional and global scales, with special emphasis on black carbon (BC, "soot"). The temporal and spatial characteristics of gas flaring distinguishes it from mobile combustion sources (transport), while the open-flame nature of gas flaring distinguishes it from industrial point-sources; the high temperature, flame control, and spatial compactness distinguishes gas flaring from both biomass burning and domestic fuel-use. All of these distinguishing factors influence the quantity and characteristics of BC production from gas flaring, so that it is important to consider this source separately in emissions inventories and environmental field studies. Estimate of the yield of pollutants from gas flaring have, to date, paid little or no attention to the emission of BC with the assumption often being made that flaring produces a smokeless flame. In gas flares, soot yield is known to depend on a number of factors, and there is a need to develop emission estimates and modelling frameworks that take these factors into consideration. Hence, emission inventories, especially of the soot yield from gas flaring should give adequate consideration to the variation of fuel gas composition, and to combustion characteristics, which are strong determinants of the nature and quantity of pollutants emitted. The buoyant nature of gas flaring plume, often at temperatures in the range of 2000 K, coupled with the height of the stack enables some of the pollutants to escape further into the free troposphere aiding their long-range transport, which is often not well-captured by model studies. PMID:27262132

  3. Semiconducting Metal Oxide Based Sensors for Selective Gas Pollutant Detection

    PubMed Central

    Kanan, Sofian M.; El-Kadri, Oussama M.; Abu-Yousef, Imad A.; Kanan, Marsha C.

    2009-01-01

    A review of some papers published in the last fifty years that focus on the semiconducting metal oxide (SMO) based sensors for the selective and sensitive detection of various environmental pollutants is presented. PMID:22408500

  4. Atmospheric pressure glow discharge generated in nitrogen-methane gas mixture: PTR-MS analyzes of the exhaust gas

    NASA Astrophysics Data System (ADS)

    Torokova, Lucie; Mazankova, Vera; Krcma, Frantisek; Mason, Nigel J.; Matejcik, Stefan

    2015-07-01

    This paper reports the results of an extensive study of with the in situ mass spectrometry analysis of gaseous phase species produced by an atmospheric plasma glow discharge in N2-CH4 gas mixtures (with methane concentrations ranging from 1% to 4%). The products are studied using proton-transfer-reaction mass spectrometry (PTR-MS). HCN and CH3CN are identified as the main gaseous products. Hydrazine, methanimine, methyldiazene, ethylamine, cyclohexadiene, pyrazineacetylene, ethylene, propyne and propene are identified as minor compounds. All the detected compounds and their relative abundances are determined with respect to the experimental conditions (gas composition and applied power). The same molecules were observed by the Cassini-Huygens probe in Titan's atmosphere (which has same N2-CH4 gas mixtures). Such, experiments show that the formation of such complex organics in atmospheres containing C, N and H, like that of Titan, could be a source of prebiotic molecules. Contribution to the topical issue "The 14th International Symposium on High Pressure Low Temperature Plasma Chemistry (HAKONE XIV)", edited by Nicolas Gherardi, Ronny Brandenburg and Lars Stollenwark

  5. Effect of Ambient Temperature on Total Organic Gas Speciation Profiles from Light-Duty Gasoline Vehicle Exhaust.

    PubMed

    Roy, Anirban; Sonntag, Darrell; Cook, Richard; Yanca, Catherine; Schenk, Charles; Choi, Yunsoo

    2016-06-21

    Total organic gases (TOG) emissions from motor vehicles include air toxic compounds and contribute to formation of ground-level ozone and secondary organic aerosol (SOA). These emissions are known to be affected by temperature; however previous studies have typically focused only on the temperature dependence of total emission factors and select toxic compounds. This study builds on the previous research by performing an evaluation of a comprehensive set of gas-phase organic compounds present in gasoline motor vehicle exhaust. A fleet of five vehicles using port fuel injection engine technology and running on E10 fuel was tested. Overall, three temperatures (0, 20, and 75 °F; or -18, -7, and 24 °C), two driving conditions (urban-FTP75 and aggressive driving-US06) and 161 compounds were evaluated; the emissions distributions were used to construct speciation profiles for each driving cycle and temperature. Overall, the speciation results indicated a significant increase in alkane and methane content, and decrease in alcohol, aldehyde and ketone content with decreasing temperature. These were verified using a statistical significance test. The fraction and composition of Mobile Source Air Toxics (MSATs) were significantly affected by temperature for both driving cycles. The ozone forming potentials of these profiles were evaluated using the maximum incremental reactivity (MIR) scale. Aromatic content was predicted to be a major driver behind the ozone forming potentials. Additionally, the decreasing ozone potential could be attributed to increased methane fractions with increasing temperature. PMID:27203618

  6. Effect of Ambient Temperature on Total Organic Gas Speciation Profiles from Light-Duty Gasoline Vehicle Exhaust.

    PubMed

    Roy, Anirban; Sonntag, Darrell; Cook, Richard; Yanca, Catherine; Schenk, Charles; Choi, Yunsoo

    2016-06-21

    Total organic gases (TOG) emissions from motor vehicles include air toxic compounds and contribute to formation of ground-level ozone and secondary organic aerosol (SOA). These emissions are known to be affected by temperature; however previous studies have typically focused only on the temperature dependence of total emission factors and select toxic compounds. This study builds on the previous research by performing an evaluation of a comprehensive set of gas-phase organic compounds present in gasoline motor vehicle exhaust. A fleet of five vehicles using port fuel injection engine technology and running on E10 fuel was tested. Overall, three temperatures (0, 20, and 75 °F; or -18, -7, and 24 °C), two driving conditions (urban-FTP75 and aggressive driving-US06) and 161 compounds were evaluated; the emissions distributions were used to construct speciation profiles for each driving cycle and temperature. Overall, the speciation results indicated a significant increase in alkane and methane content, and decrease in alcohol, aldehyde and ketone content with decreasing temperature. These were verified using a statistical significance test. The fraction and composition of Mobile Source Air Toxics (MSATs) were significantly affected by temperature for both driving cycles. The ozone forming potentials of these profiles were evaluated using the maximum incremental reactivity (MIR) scale. Aromatic content was predicted to be a major driver behind the ozone forming potentials. Additionally, the decreasing ozone potential could be attributed to increased methane fractions with increasing temperature.

  7. An Approach to the Prototyping of an Optimized Limited Stroke Actuator to Drive a Low Pressure Exhaust Gas Recirculation Valve.

    PubMed

    Gutfrind, Christophe; Dufour, Laurent; Liebart, Vincent; Vannier, Jean-Claude; Vidal, Pierre

    2016-05-20

    The purpose of this article is to describe the design of a limited stroke actuator and the corresponding prototype to drive a Low Pressure (LP) Exhaust Gas Recirculation (EGR) valve for use in Internal Combustion Engines (ICEs). The direct drive actuator topology is an axial flux machine with two air gaps in order to minimize the rotor inertia and a bipolar surface-mounted permanent magnet in order to respect an 80° angular stroke. Firstly, the actuator will be described and optimized under constraints of a 150 ms time response, a 0.363 N·m minimal torque on an angular range from 0° to 80° and prototyping constraints. Secondly, the finite element method (FEM) using the FLUX-3D(®) software (CEDRAT, Meylan, France) will be used to check the actuator performances with consideration of the nonlinear effect of the iron material. Thirdly, a prototype will be made and characterized to compare its measurement results with the analytical model and the FEM model results. With these electromechanical behavior measurements, a numerical model is created with Simulink(®) in order to simulate an EGR system with this direct drive actuator under all operating conditions. Last but not least, the energy consumption of this machine will be estimated to evaluate the efficiency of the proposed EGR electromechanical system.

  8. Reduction of regulated and unregulated exhaust gas emission components from diesel engines running with rapeseedmethylester using oxidation catalyst technologies

    SciTech Connect

    May, H.; Huettenberger, P.

    1996-12-31

    Up to now all engine research was based on engines, which are adapted to Diesel fuel but not to vegetableoilmethylester (VME). Caused by the special climate conditions in Europe rapeseed and sunflowers, in the US soya-beans and in the tropical countries palm trees are the favorable plants for vegetable oil production. The physical and chemical properties of Diesel fuel and VME are quite different. Therefore an engine adaption and redesign to VME is a suitable way of further reduction of noxious and climate-influencing emissions. To prove the effectiveness of the emission reduction the European test-cycle ECE/EUDC, the US-FTP 75 test for passenger cars and the European 13-stage-test-cycle for heavy duty-truck-engines has been used with and without an oxidation catalyst in each case. The results of the exhaust gas measurement both concerning regulated and unregulated components are shown. A comparison between engines fueled with fossil diesel fuel and rapeseedmethylester (RME) is given.

  9. An Approach to the Prototyping of an Optimized Limited Stroke Actuator to Drive a Low Pressure Exhaust Gas Recirculation Valve.

    PubMed

    Gutfrind, Christophe; Dufour, Laurent; Liebart, Vincent; Vannier, Jean-Claude; Vidal, Pierre

    2016-01-01

    The purpose of this article is to describe the design of a limited stroke actuator and the corresponding prototype to drive a Low Pressure (LP) Exhaust Gas Recirculation (EGR) valve for use in Internal Combustion Engines (ICEs). The direct drive actuator topology is an axial flux machine with two air gaps in order to minimize the rotor inertia and a bipolar surface-mounted permanent magnet in order to respect an 80° angular stroke. Firstly, the actuator will be described and optimized under constraints of a 150 ms time response, a 0.363 N·m minimal torque on an angular range from 0° to 80° and prototyping constraints. Secondly, the finite element method (FEM) using the FLUX-3D(®) software (CEDRAT, Meylan, France) will be used to check the actuator performances with consideration of the nonlinear effect of the iron material. Thirdly, a prototype will be made and characterized to compare its measurement results with the analytical model and the FEM model results. With these electromechanical behavior measurements, a numerical model is created with Simulink(®) in order to simulate an EGR system with this direct drive actuator under all operating conditions. Last but not least, the energy consumption of this machine will be estimated to evaluate the efficiency of the proposed EGR electromechanical system. PMID:27213398

  10. Effect of exhaust gas recirculation on emissions from a flame-tube combustor using Liquid Jet A fuel

    NASA Technical Reports Server (NTRS)

    Marek, C. J.; Tacina, R. R.

    1976-01-01

    The effects of uncooled exhaust gas recirculation as an inert diluent on emissions of oxides of nitrogen (NO + NO2) and on combustion efficiency were investigated. Ratios of recirculated combustion products to inlet airflow were varied from 10 to 80 percent by using an inlet air ejector nozzle. Liquid Jet A fuel was used. The flame-tube combustor was 10.2 cm in diameter. It was operated with and without a flameholder present. The combustor pressure was maintained constant at 0.5 MPa. The equivalence ratio was varied from 0.3 to 1.0. The inlet air temperature was varied from 590 to 800 K, and the reference velocity from 10 to 30 m/sec. Increasing the percent recirculation from 10 to 25 had the following effects: (1) the peak NOx emission was decreased by 37 percent, from 8 to 5 g NO2/kg fuel, at an inlet air temperature of 590 K and a reference velocity of 15 m/sec; (2) the combustion efficiency was increased, particularly at the higher equivalence ratios; and (3) for a high combustion efficiency of greater than 99.5 percent, the range of operation of the combustor was nearly doubled in terms of equivalence ratio. Increasing the recirculation from 25 to 50 percent did not change the emissions significantly.

  11. An Approach to the Prototyping of an Optimized Limited Stroke Actuator to Drive a Low Pressure Exhaust Gas Recirculation Valve

    PubMed Central

    Gutfrind, Christophe; Dufour, Laurent; Liebart, Vincent; Vannier, Jean-Claude; Vidal, Pierre

    2016-01-01

    The purpose of this article is to describe the design of a limited stroke actuator and the corresponding prototype to drive a Low Pressure (LP) Exhaust Gas Recirculation (EGR) valve for use in Internal Combustion Engines (ICEs). The direct drive actuator topology is an axial flux machine with two air gaps in order to minimize the rotor inertia and a bipolar surface-mounted permanent magnet in order to respect an 80° angular stroke. Firstly, the actuator will be described and optimized under constraints of a 150 ms time response, a 0.363 N·m minimal torque on an angular range from 0° to 80° and prototyping constraints. Secondly, the finite element method (FEM) using the FLUX-3D® software (CEDRAT, Meylan, France) will be used to check the actuator performances with consideration of the nonlinear effect of the iron material. Thirdly, a prototype will be made and characterized to compare its measurement results with the analytical model and the FEM model results. With these electromechanical behavior measurements, a numerical model is created with Simulink® in order to simulate an EGR system with this direct drive actuator under all operating conditions. Last but not least, the energy consumption of this machine will be estimated to evaluate the efficiency of the proposed EGR electromechanical system. PMID:27213398

  12. CRITERIA POLLUTANT EMISSIONS FROM INTERNAL COMBUSTION ENGINES IN THE NATURAL GAS INDUSTRY VOLUME 1. TECHNICAL REPORT

    EPA Science Inventory

    The report summarizes emission factors for criteria pollutants (NOx, CO, CH4, C2H6, THC, NMHC, and NMEHC) from stationary internal combustion engines and gas turbines used in the natural gas industry. The emission factors were calculated from test results from five test campaigns...

  13. Airborne measurements of gas and particle pollutants during CAREBeijing-2008

    NASA Astrophysics Data System (ADS)

    Zhang, W.; Zhu, T.; Yang, W.; Bai, Z.; Sun, Y. L.; Xu, Y.; Yin, B.; Zhao, X.

    2014-01-01

    Measurements of gaseous pollutants - including ozone (O3), sulfur dioxide (SO2), nitrogen oxides (NOX = NO + NO2), carbon monoxide (CO), particle number concentrations (5.6-560 nm and 0.47-30 μm) - and meteorological parameters (T, RH, P) were conducted during the Campaigns of Air Quality Research in Beijing and Surrounding Regions in 2008 (CAREBeijing-2008), from 27 August through 13 October 2008. The data from a total 18 flights (70 h flight time) from near the surface to 2100 m altitude were obtained with a Yun-12 aircraft in the southern surrounding areas of Beijing (38-40° N, 114-118° E). The objectives of these measurements were to characterize the regional variation of air pollution during and after the Olympics of 2008, determine the importance of air mass trajectories and to evaluate of other factors that influence the pollution characteristics. The results suggest that there are primarily four distinct sources that influenced the magnitude and properties of the pollutants in the measured region based on back-trajectory analysis: (1) southerly transport of air masses from regions with high pollutant emissions, (2) northerly and northeasterly transport of less pollutant air from further away, (3) easterly transport from maritime sources where emissions of gaseous pollutant are less than from the south but still high in particle concentrations, and (4) the transport of air that is a mixture from different regions; that is, the air at all altitudes measured by the aircraft was not all from the same sources. The relatively long-lived CO concentration is shown to be a possible transport tracer of long-range transport from the northwesterly direction, especially at the higher altitudes. Three factors that influenced the size distribution of particles - i.e., air mass transport direction, ground source emissions and meteorological influences - are also discussed.

  14. 40 CFR 86.1309-90 - Exhaust gas sampling system; Otto-cycle and non-petroleum-fueled engines.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... test period. (2) Engine exhaust to CVS duct. For methanol-fueled engines, reactions of the exhaust...), as applicable are achieved by sampling at a constant flow rate. For methanol-fueled engines, the... analyzed using a HFID calibrated with methanol. The variable mixture flow rate is maintained at choked...

  15. Use of aromatic salts for simultaneously removing SO.sub.2 and NO.sub.x pollutants from exhaust of a combustion system

    DOEpatents

    Levendis, Yiannis A.; Wise, Donald L.

    1994-10-04

    A method is disclosed for removing pollutants from the exhaust of combustion systems burning fuels containing substantial amounts of sulfur and nitrogen. An exemplary method of the invention involves the formation and reaction of a sorbent comprising calcium benzoate. The calcium benzoate is either dry-sprayed (in the form of a fine powder) or wet-sprayed in an aqueous solution in a high temperature environment such as a combustion chamber. The latter technique is feasible since calcium benzoate is a water-soluble form of calcium. When the dispersed particles of calcium benzoate are heated to a high temperature, the organic benzoate burns off and fine calcium oxide particles are formed. These particles are cenospheric (hollow) and have thin and highly porous walls, thus, affording optimum external and internal accessibility for reacting with toxic gaseous emissions such as SO.sub.2. Further, the combustion of the organic benzoate portion of the sorbent results in the conversion of NO.sub.x to N.sub.2.

  16. Pollutant Emission Factors from Residential Natural Gas Appliances: A Literature Review

    SciTech Connect

    Traynor, G.W.; Apte, M.G.; Chang, G.-M.

    1996-08-01

    There is a need to reduce air pollutant emissions in some U.S. urban regions to meet federal and state air quality guidelines. Opportunities exist for reducing pollutant emissions from natural gas appliances in the residential sector. A cost-benefit analysis on various pollutant-reducing strategies is needed to evaluate these opportunities. The effectiveness of these pollutant-reducing strategies (e.g., low-emission burners, energy conservation) can then be ranked among themselves and compared with other pollutant-reducing strategies available for the region. A key step towards conducting a cost-benefit analysis is to collect information on pollutant emissions from existing residential natural gas appliances. An extensive literature search was conducted to collect data on residential natural-gas-appliance pollutant emission factors. The literature primarily describes laboratory tests and may not reflect actual emission factor distributions in the field. Pollutant emission factors for appliances operated at over 700 test conditions are summarized for nitrogen oxides, carbon monoxide, fine particulate matter, formaldehyde, and methane. The appliances for which pollutant emissions are summarized include forced-air furnaces; stand-alone space heaters (vented and unvented); water heaters; cooking range burners, ovens, and broilers; and pilot lights. The arithmetic means of the nitrogen oxides and fine particulate matter emission factor distributions agree well with the Environmental Protection Agency published emission factor values for domestic gas appliances (in report AP-42). However, the carbon monoxide and methane distribution means are much higher than the relevant AP-42 values. Formaldehyde emission factors are not addressed in AP-42, but the emission factor mean for formaldehyde is comparable to the AP-42 emission factor value for total hydrocarbon emissions.

  17. Diesel exhaust particles and airway inflammation

    EPA Science Inventory

    Purpose of review. Epidemiologic investigation has associated traffic-related air pollution with adverse human health outcomes. The capacity ofdiesel exhaust particles (DEP), a major emission source air pollution particle, to initiate an airway inflammation has subsequently been ...

  18. 40 CFR 1065.130 - Engine exhaust.

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ....130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS... exhaust tubing that has either a wall thickness of less than 2 mm or is air gap-insulated to minimize... balance of fuel, intake air, and exhaust according to § 1065.655 to verify exhaust system integrity....

  19. 40 CFR 1065.130 - Engine exhaust.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ....130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS... exhaust tubing that has either a wall thickness of less than 2 mm or is air gap-insulated to minimize... balance of fuel, intake air, and exhaust according to § 1065.655 to verify exhaust system integrity....

  20. 40 CFR 1065.130 - Engine exhaust.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ....130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS... exhaust tubing that has either a wall thickness of less than 2 mm or is air gap-insulated to minimize... balance of fuel, intake air, and exhaust according to § 1065.655 to verify exhaust system integrity....

  1. 40 CFR 1065.130 - Engine exhaust.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ....130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS... exhaust tubing that has either a wall thickness of less than 2 mm or is air gap-insulated to minimize..., intake air, and exhaust according to § 1065.655 to verify exhaust system integrity. (f)...

  2. 40 CFR 1065.130 - Engine exhaust.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ....130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS... exhaust tubing that has either a wall thickness of less than 2 mm or is air gap-insulated to minimize... balance of fuel, intake air, and exhaust according to § 1065.655 to verify exhaust system integrity....

  3. Method for converting noxious pollutants from flue gas into merchantable by-products

    SciTech Connect

    Johnson, A.F.

    1993-07-27

    A method is described for removing pollutants from boiler plant flue gases comprising the steps of: (a) exchanging heat between a flue gas which contains SO[sub 2], SO[sub 3] and NO pollutants and a first fluid to cool the flue gas down to a first temperature whereat substantially all SO[sub 3] in the flue gas is combined with H[sub 2]O; (b) condensing the SO[sub 3] and H[sub 2]O from the flue gas as a first condensate; (c) adding a solution containing an ammoniacal substance and a detergent to said flue gas to produce soapsuds and sulfates including ammonium bisulfate; (d) collecting the soap suds and ammonium bisulfate produced after said adding step and the first condensate as a first solution; and (e) separating ammonium bisulfate from said first solution.

  4. Design and test of an exhaust gas clean-up system for power plants using high sulphur content fuels. Final report

    SciTech Connect

    Chang, C.N.

    1980-10-10

    This experimental program, initially designated to study an exhaust gas cleanup and water recovery system for a Cheng Cycle Dual-Fluid (CCDF) turbine power plant using sulfur rich fuels, has shown the potential of a general Flue Gas Desulfurization (FGD) system applicable to utility and industrial boilers as well. The process was studied both theoretically and experimentaly. Experiments were performed using a bench scale (25k equivalent) apparatus and a pilot scale (1Mw equivalent) apparatus. Data obtained indicated the IPT process potentially can out-perform the conventional FGD process with significant cost savings.

  5. Pollution

    ERIC Educational Resources Information Center

    Rowbotham, N.

    1973-01-01

    Presents the material given in one class period in a course on Environmental Studies at Chesterfield School, England. The topics covered include air pollution, water pollution, fertilizers, and insecticides. (JR)

  6. Pollution

    ERIC Educational Resources Information Center

    Terry, Luther L.

    1970-01-01

    Our mechanized environment has produced a variety of man-made pollutants. Prevention of pollution and resulting health hazards is a primary challenge. The Federal Government undertakes a large responsibility in the field of environmental control. (CK)

  7. Inhalation of Whole Diesel Exhaust but not Gas-Phase Components Affects In Vitro Platelet Aggregation in Hypertensive Rats

    EPA Science Inventory

    Rationale: Intravascular thrombosis and platelet aggregation are enhanced following exposure to diesel exhaust (DE) and other respirable particulate matter; however, the roles of endothelial and circulating mediators on platelet aggregation remain unclear. We hypothesized that ad...

  8. Exhaust purification with on-board ammonia production

    DOEpatents

    Robel, Wade J.; Driscoll, James Joshua; Coleman, Gerald N.

    2008-05-13

    A system of ammonia production for a selective catalytic reduction system is provided. The system includes producing an exhaust gas stream within a cylinder group, wherein the first exhaust gas stream includes NOx. The exhaust gas stream may be supplied to an exhaust passage and cooled to a predetermined temperature range, and at least a portion of the NOx within the exhaust gas stream may be converted into ammonia.

  9. Exhaust purification with on-board ammonia production

    DOEpatents

    Robel, Wade J.; Driscoll, James Joshua; Coleman, Gerald N.

    2010-10-12

    A method of ammonia production for a selective catalytic reduction system is provided. The method includes producing an exhaust gas stream within a cylinder group, wherein the first exhaust gas stream includes NOx. The exhaust gas stream may be supplied to an exhaust passage and cooled to a predetermined temperature range, and at least a portion of the NOx within the exhaust gas stream my be converted into ammonia.

  10. Controlling exhaust gas recirculation

    DOEpatents

    Zurlo, James Richard; Konkle, Kevin Paul; May, Andrew

    2012-01-31

    In controlling an engine, an amount of an intake charge provided, during operation of the engine, to a combustion chamber of the engine is determined. The intake charge includes an air component, a fuel component and a diluent component. An amount of the air component of the intake charge is determined. An amount of the diluent component of the intake charge is determined utilizing the amount of the intake charge, the amount of the air component and, in some instances, the amount of the fuel component. An amount of a diluent supplied to the intake charge is adjusted based at least in part on the determined amount of diluent component of the intake charge.

  11. Exhaust gas recirculation system

    SciTech Connect

    Rachedi, S.H.

    1983-10-18

    There is disclosed an EGR assembly of a sonic flow EGR valve and a fluid pressure actuated servo operated by air pressure modified by an air bleed device controlled in response to changes in carburetor venturi vacuum levels to provide EGR valve openings in proportion to engine air flow increases.

  12. Exhaust gas recirculation system

    SciTech Connect

    Rachedi, S.H.

    1983-08-16

    An EGR assembly is disclosed of a sonic flow EGR valve and a fluid pressure actuated servo operated by air pressure modified by an air bleed device controlled in response to changes in carburetor venturi vacuum levels to provide EGR valve openings in proportion to engine air flow increases.

  13. Combatting urban air pollution through Natural Gas Vehicle (NGV) analysis, testing, and demonstration

    SciTech Connect

    1995-03-01

    Deteriorating urban air quality ranks as a top concern worldwide, since air pollution adversely affects both public health and the environment. The outlook for improving air quality in the world`s megacities need not be bleak, however, The use of natural gas as a transportation fuel can measurably reduce urban pollution levels, mitigating chronic threats to health and the environment. Besides being clean burning, natural gas vehicles (NGVs) are economical to operate and maintain. The current cost of natural gas is lower than that of gasoline. Natural gas also reduces the vehicle`s engine wear and noise level, extends engine life, and decreases engine maintenance. Today, about 700,000 NGVs operate worldwide, the majority of them converted from gasoline or diesel fuel. This article discusses the economic, regulatory and technological issues of concern to the NGV industry.

  14. High-Speed Multiplexed Spatiotemporally Resolved Measurements of Exhaust Gas Recirculation Dynamics in a Multi-Cylinder Engine Using Laser Absorption Spectroscopy.

    PubMed

    Yoo, Jihyung; Prikhodko, Vitaly; Parks, James E; Perfetto, Anthony; Geckler, Sam; Partridge, William P

    2016-04-01

    The need for more environmentally friendly and efficient energy conversion is of paramount importance in developing and designing next-generation internal combustion (IC) engines for transportation applications. One effective solution to reducing emissions of mono-nitrogen oxides (NOx) is exhaust gas recirculation (EGR), which has been widely implemented in modern vehicles. However, cylinder-to-cylinder and cycle-to-cycle variations in the charge-gas uniformity can be a major barrier to optimum EGR implementation on multi-cylinder engines, and can limit performance, stability, and efficiency. Precise knowledge and fine control over the EGR system is therefore crucial, particularly for optimizing advanced engine concepts such as reactivity controlled compression ignition (RCCI). An absorption-based laser diagnostic was developed to study spatiotemporal charge-gas distributions in an IC engine intake manifold in real-time. The laser was tuned to an absorption band of carbon dioxide (CO2), a standard exhaust-gas marker, near 2.7 µm. The sensor was capable of probing four separate measurement locations simultaneously, and independently analyzing EGR fraction at speeds of 5 kHz (1.2 crank-angle degree (CAD) at 1 k RPM) or faster with high accuracy. The probes were used to study spatiotemporal EGR non-uniformities in the intake manifold and ultimately promote the development of more efficient and higher performance engines. PMID:27091946

  15. High-Speed Multiplexed Spatiotemporally Resolved Measurements of Exhaust Gas Recirculation Dynamics in a Multi-Cylinder Engine Using Laser Absorption Spectroscopy

    DOE PAGES

    Yoo, Jihyung; Prikhodko, Vitaly; Parks, James E.; Perfetto, Anthony; Geckler, Sam; Partridge, William P.

    2016-04-01

    The need for more environmentally friendly and efficient energy conversion is of paramount importance in developing and designing next-generation internal combustion (IC) engines for transportation applications. One effective solution to reducing emissions of mono-nitrogen oxides (NOx) is exhaust gas recirculation (EGR), which has been widely implemented in modern vehicles. However, cylinder-to-cylinder and cycle-to-cycle variations in the charge-gas uniformity can be a major barrier to optimum EGR implementation on multi-cylinder engines, and can limit performance, stability, and efficiency. Precise knowledge and fine control over the EGR system is thus crucial, particularly for optimizing advanced engine concepts such as reactivity controlled compressionmore » ignition (RCCI). An absorption-based laser diagnostic was developed to study spatiotemporal charge-gas distributions in an IC engine intake manifold in real-time. The laser was tuned to an absorption band of carbon dioxide (CO2), a standard exhaust-gas marker, near 2.7 µm. The sensor was capable of probing four separate measurement locations simultaneously, and independently analyzing EGR fraction at speeds of 5 kHz (1.2 crank-angle degree (CAD) at 1 k RPM) or faster with high accuracy. Lastly, the probes were used to study spatiotemporal EGR non-uniformities in the intake manifold and ultimately promote the development of more efficient and higher performance engines.« less

  16. High-Speed Multiplexed Spatiotemporally Resolved Measurements of Exhaust Gas Recirculation Dynamics in a Multi-Cylinder Engine Using Laser Absorption Spectroscopy.

    PubMed

    Yoo, Jihyung; Prikhodko, Vitaly; Parks, James E; Perfetto, Anthony; Geckler, Sam; Partridge, William P

    2016-04-01

    The need for more environmentally friendly and efficient energy conversion is of paramount importance in developing and designing next-generation internal combustion (IC) engines for transportation applications. One effective solution to reducing emissions of mono-nitrogen oxides (NOx) is exhaust gas recirculation (EGR), which has been widely implemented in modern vehicles. However, cylinder-to-cylinder and cycle-to-cycle variations in the charge-gas uniformity can be a major barrier to optimum EGR implementation on multi-cylinder engines, and can limit performance, stability, and efficiency. Precise knowledge and fine control over the EGR system is therefore crucial, particularly for optimizing advanced engine concepts such as reactivity controlled compression ignition (RCCI). An absorption-based laser diagnostic was developed to study spatiotemporal charge-gas distributions in an IC engine intake manifold in real-time. The laser was tuned to an absorption band of carbon dioxide (CO2), a standard exhaust-gas marker, near 2.7 µm. The sensor was capable of probing four separate measurement locations simultaneously, and independently analyzing EGR fraction at speeds of 5 kHz (1.2 crank-angle degree (CAD) at 1 k RPM) or faster with high accuracy. The probes were used to study spatiotemporal EGR non-uniformities in the intake manifold and ultimately promote the development of more efficient and higher performance engines.

  17. On-road measurement of gas and particle phase pollutant emission factors for individual heavy-duty diesel trucks.

    PubMed

    Dallmann, Timothy R; DeMartini, Steven J; Kirchstetter, Thomas W; Herndon, Scott C; Onasch, Timothy B; Wood, Ezra C; Harley, Robert A

    2012-08-01

    Pollutant concentrations in the exhaust plumes of individual diesel trucks were measured at high time resolution in a highway tunnel in Oakland, CA, during July 2010. Emission factors for individual trucks were calculated using a carbon balance method, in which pollutants measured in each exhaust plume were normalized to measured concentrations of carbon dioxide. Pollutants considered here include nitric oxide, nitrogen dioxide (NO(2)), carbon monoxide, formaldehyde, ethene, and black carbon (BC), as well as optical properties of emitted particles. Fleet-average emission factors for oxides of nitrogen (NO(x)) and BC respectively decreased 30 ± 6 and 37 ± 10% relative to levels measured at the same location in 2006, whereas a 34 ± 18% increase in the average NO(2) emission factor was observed. Emissions distributions for all species were skewed with a small fraction of trucks contributing disproportionately to total emissions. For example, the dirtiest 10% of trucks emitted half of total NO(2) and BC emissions. Emission rates for NO(2) were found to be anticorrelated with all other species considered here, likely due to the use of catalyzed diesel particle filters to help control exhaust emissions. Absorption and scattering cross-section emission factors were used to calculate the aerosol single scattering albedo (SSA, at 532 nm) for individual truck exhaust plumes, which averaged 0.14 ± 0.03. PMID:22799607

  18. 78 FR 51724 - California State Motor Vehicle Pollution Control Standards; Tractor-Trailer Greenhouse Gas...

    Federal Register 2010, 2011, 2012, 2013, 2014

    2013-08-21

    ... AGENCY California State Motor Vehicle Pollution Control Standards; Tractor-Trailer Greenhouse Gas...: The California Air Resources Board (CARB) has notified EPA that it has adopted a tractor-trailer... new and in-use tractors that haul such trailers on California highways (HD Tractor-Trailer...

  19. Greenhouse gas emission and groundwater pollution potentials of soils amended with different swine biochars

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The objective of this research was to study the greenhouse gas emission and groundwater pollution potentials of the soils amended with various biochars using different biomass feedstocks and thermal processing conditions. Triplicate sets of small pots were designed; control soil consisting of Histi...

  20. Greenhouse gas emission and groundwater pollution potentials of soils amended with raw and carbonized swine solids

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The objective of this research is to study the greenhouse gas emission and groundwater pollution potentials of the soils amended with raw swine solids and swine biochars made from different thermochemical conditions. Triplicate sets of small pots were designed: 1) control soil with a 50/50 mixture o...

  1. Groundwater pollution potential and greenhouse gas emission from soils amended with different swine biochars

    Technology Transfer Automated Retrieval System (TEKTRAN)

    Although there exist numerous research studies in the literature on greenhouse gas emission and groundwater pollution potentials of soils amended with plant-based biochar made from traditional dry pyrolysis (hereafter referred as pyrochar), a very few such studies exist for hydrochar made from hydro...

  2. Air Pollutant Emissions from Oil and Gas Production pads (Investigating Low Cost Passive Samplers)

    EPA Science Inventory

    To help achieve the goal of sustainable, environmentally responsible development of oil and gas resources, it isnecessary to understand the potential for air pollutant emissions from various extraction and production (E&P)processes at the upstream, wellpad level. Upstream oil and...

  3. DESIGN, FABRICATION, AND TESTING OF AN ADVANCED, NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    SciTech Connect

    Unknown

    2002-03-31

    The objectives of this report period were to complete the development of the Gas Generator design, which was done; fabricate and test of the non-polluting unique power turbine drive gas Gas Generator, which has been postponed. Focus during this report period has been to complete the brazing and bonding necessary to fabricate the Gas Generator hardware, continue making preparations for fabricating and testing the Gas Generator, and continuing the fabrication of the Gas Generator hardware and ancillary hardware in preparation for the test program. Fabrication is more than 95% complete and is expected to conclude in early May 2002. the test schedule was affected by relocation of the testing to another test supplier. The target test date for hot fire testing is now not earlier than June 15, 2002.

  4. Simultaneous film and convection cooling of a plate inserted in the exhaust stream of a gas turbine combustor

    NASA Technical Reports Server (NTRS)

    Marek, C. J.; Juhasz, A. J.

    1973-01-01

    Data were obtained on a parallel-flow film- and convection-cooled test section placed in the exhaust stream of a rectangular-sector combustor. The combustor was operated at atmospheric pressure and at exhaust temperatures of 589 and 1033 K (600 and 1400 F). The cooling air was at ambient pressure and temperature. Test results indicate that it is better to use combined film and convection cooling rather than either film or convection cooling alone for a fixed total coolant flow. An optimum ratio of film to convection cooling flow rates was determined for the particular geometry tested. The experimental results compared well with calculated results.

  5. Diesel exhaust exposures in port workers.

    PubMed

    Debia, Maximilien; Neesham-Grenon, Eve; Mudaheranwa, Oliver C; Ragettli, Martina S

    2016-07-01

    Exposure to diesel engine exhaust has been linked to increased cancer risk and cardiopulmonary diseases. Diesel exhaust is a complex mixture of chemical substances, including a particulate fraction mainly composed of ultrafine particles, resulting from the incomplete combustion of fuel. Diesel trucks are known to be an important source of diesel-related air pollution, and areas with heavy truck traffic are associated with higher air pollution levels and increased public health problems. Several indicators have been proposed as surrogates for estimating exposures to diesel exhaust but very few studies have focused specifically on monitoring the ultrafine fraction through the measurement of particle number concentrations. The aim of this study is to assess occupational exposures of gate controllers at the port of Montreal, Canada, to diesel engine emissions from container trucks by measuring several surrogates through a multimetric approach which includes the assessment of both mass and number concentrations and the use of direct reading devices. A 10-day measurement campaign was carried out at two terminal checkpoints at the port of Montreal. Respirable elemental and organic carbon, PM1, PM2.5, PMresp (PM4), PM10, PMtot (inhalable fraction), particle number concentrations, particle size distributions, and gas concentrations (NO2, NO, CO) were monitored. Gate controllers were exposed to concentrations of contaminants associated with diesel engine exhaust (elemental carbon GM = 1.6 µg/m(3); GSD = 1.6) well below recommended occupational exposure limits. Average daily particle number concentrations ranged from 16,544-67,314 particles/cm³ (GM = 32,710 particles/cm³; GSD = 1.6). Significant Pearson correlation coefficients were found between daily elemental carbon, PM fractions and particle number concentrations, as well as between total carbon, PM fractions and particle number concentrations. Significant correlation coefficients were found between particle number

  6. Diesel exhaust exposures in port workers.

    PubMed

    Debia, Maximilien; Neesham-Grenon, Eve; Mudaheranwa, Oliver C; Ragettli, Martina S

    2016-07-01

    Exposure to diesel engine exhaust has been linked to increased cancer risk and cardiopulmonary diseases. Diesel exhaust is a complex mixture of chemical substances, including a particulate fraction mainly composed of ultrafine particles, resulting from the incomplete combustion of fuel. Diesel trucks are known to be an important source of diesel-related air pollution, and areas with heavy truck traffic are associated with higher air pollution levels and increased public health problems. Several indicators have been proposed as surrogates for estimating exposures to diesel exhaust but very few studies have focused specifically on monitoring the ultrafine fraction through the measurement of particle number concentrations. The aim of this study is to assess occupational exposures of gate controllers at the port of Montreal, Canada, to diesel engine emissions from container trucks by measuring several surrogates through a multimetric approach which includes the assessment of both mass and number concentrations and the use of direct reading devices. A 10-day measurement campaign was carried out at two terminal checkpoints at the port of Montreal. Respirable elemental and organic carbon, PM1, PM2.5, PMresp (PM4), PM10, PMtot (inhalable fraction), particle number concentrations, particle size distributions, and gas concentrations (NO2, NO, CO) were monitored. Gate controllers were exposed to concentrations of contaminants associated with diesel engine exhaust (elemental carbon GM = 1.6 µg/m(3); GSD = 1.6) well below recommended occupational exposure limits. Average daily particle number concentrations ranged from 16,544-67,314 particles/cm³ (GM = 32,710 particles/cm³; GSD = 1.6). Significant Pearson correlation coefficients were found between daily elemental carbon, PM fractions and particle number concentrations, as well as between total carbon, PM fractions and particle number concentrations. Significant correlation coefficients were found between particle number

  7. Controlling automotive exhaust emissions: successes and underlying science.

    PubMed

    Twigg, Martyn V

    2005-04-15

    Photochemical reactions of vehicle exhaust pollutants were responsible for photochemical smog in many cities during the 1960s and 1970s. Engine improvements helped, but additional measures were needed to achieve legislated emissions levels. First oxidation catalysts lowered hydrocarbon and carbon monoxide, and later nitrogen oxides were reduced to nitrogen in a two-stage process. By the 1980s, exhaust gas could be kept stoichiometric and hydrocarbons, carbon monoxide and nitrogen oxides were simultaneously converted over a single 'three-way catalyst'. Today, advanced three-way catalyst systems emissions are exceptionally low. NOx control from lean-burn engines demands an additional approach because NO cannot be dissociated under lean conditions. Current lean-burn gasoline engine NOx control involves forming a nitrate phase and periodically enriching the exhaust to reduce it to nitrogen, and this is being modified for use on diesel engines. Selective catalytic reduction with ammonia is an alternative that can be very efficient, but it requires ammonia or a compound from which it can be obtained. Diesel engines produce particulate matter, and, because of health concerns, filtration processes are being introduced to control these emissions. On heavy duty diesel engines the exhaust gas temperature is high enough for NO in the exhaust to be oxidised over a catalyst to NO2 that smoothly oxidises particulate material (PM) in the filter. Passenger cars operate at lower temperatures, and it is necessary to periodically burn the PM in air at high temperatures.

  8. APPARATUS AND METHOD FOR TREATING POLLUTANTS IN A GAS USING HYDROGEN PEROXIDE AND UV LIGHT

    NASA Technical Reports Server (NTRS)

    Cooper, Charles David (Inventor); Clauseu, christian Anthony (Inventor)

    2005-01-01

    An apparatus for treating pollutants in a gas may include a source of hydrogen peroxide, and a treatment injector for creating and injecting dissociated hydrogen peroxide into the flow of gas. The treatment injector may further include an injector housing having an inlet, an outlet, and a hollow interior extending there between. The inlet may be connected in fluid communication with the source of hydrogen peroxide so that hydrogen peroxide flows through the hollow interior and toward the outlet. At least one ultraviolet (UV) lamp may be positioned within the hollow interior of the injector housing. The at least one UV lamp may dissociate the hydrogen peroxide flowing through the tube. The dissociated hydrogen peroxide may be injected into the flow of gas from the outlet for treating pollutants, such as nitrogen oxides.

  9. Apparatus and method for treating pollutants in a gas using hydrogen peroxide and UV light

    NASA Technical Reports Server (NTRS)

    Cooper, Charles David (Inventor); Clausen, Christian Anthony (Inventor)

    2005-01-01

    An apparatus for treating pollutants in a gas may include a source of hydrogen peroxide, and a treatment injector for creating and injecting dissociated hydrogen peroxide into the flow of gas. The treatment injector may further include an injector housing having an inlet, an outlet, and a hollow interior extending therebetween. The inlet may be connected in fluid communication with the source of hydrogen peroxide so that hydrogen peroxide flows through the hollow interior and toward the outlet. At least one ultraviolet (UV) lamp may be positioned within the hollow interior of the injector housing. The at least one UV lamp may dissociate the hydrogen peroxide flowing through the tube. The dissociated hydrogen peroxide may be injected into the flow of gas from the outlet for treating pollutants, such as nitrogen oxides.

  10. 14 CFR 34.21 - Standards for exhaust emissions.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE ENGINE POWERED AIRPLANES Exhaust Emissions (New Aircraft Gas Turbine Engines) § 34.21 Standards for exhaust emissions. (a) Exhaust emissions of smoke from each new aircraft gas turbine engine of class T8 manufactured on or after February 1,...

  11. 14 CFR 34.31 - Standards for exhaust emissions.

    Code of Federal Regulations, 2011 CFR

    2011-01-01

    ... FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE ENGINE POWERED AIRPLANES Exhaust Emissions (In-use Aircraft Gas Turbine Engines) § 34.31 Standards for exhaust emissions. (a) Exhaust emissions of smoke from each in-use aircraft gas turbine engine of Class T8, beginning February 1, 1974,...

  12. 14 CFR 34.31 - Standards for exhaust emissions.

    Code of Federal Regulations, 2012 CFR

    2012-01-01

    ... FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE ENGINE POWERED AIRPLANES Exhaust Emissions (In-use Aircraft Gas Turbine Engines) § 34.31 Standards for exhaust emissions. (a) Exhaust emissions of smoke from each in-use aircraft gas turbine engine of Class T8, beginning February 1, 1974,...

  13. 14 CFR 34.31 - Standards for exhaust emissions.

    Code of Federal Regulations, 2010 CFR

    2010-01-01

    ... FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE ENGINE POWERED AIRPLANES Exhaust Emissions (In-use Aircraft Gas Turbine Engines) § 34.31 Standards for exhaust emissions. (a) Exhaust emissions of smoke from each in-use aircraft gas turbine engine of Class T8, beginning February 1, 1974,...

  14. Gas-phase photocatalytic oxidation: Cost comparison with other air pollution control technologies

    SciTech Connect

    Turchi, C S; Wolfrum, E J; Miller, R A

    1994-11-01

    Gas-phase photocatalytic oxidation (PCO) appears to be particularly well suited for waste streams with low pollutant concentrations (1000 ppm or less) and low to moderate flow rates (< 20,000 cubic feet per minute, cfm). The PCO technology is modular in nature and thus is well suited to treat dispersed or low flow rate streams. This same attribute minimizes the advantages of scale for PCO and makes the technology comparatively less attractive for high volume waste streams. Key advantages for PCO lie in its low operating cost and ability to completely destroy pollutants at ambient temperature and pressure.

  15. High winter ozone pollution from carbonyl photolysis in an oil and gas basin

    NASA Astrophysics Data System (ADS)

    Edwards, Peter M.; Brown, Steven S.; Roberts, James M.; Ahmadov, Ravan; Banta, Robert M.; Degouw, Joost A.; Dubé, William P.; Field, Robert A.; Flynn, James H.; Gilman, Jessica B.; Graus, Martin; Helmig, Detlev; Koss, Abigail; Langford, Andrew O.; Lefer, Barry L.; Lerner, Brian M.; Li, Rui; Li, Shao-Meng; McKeen, Stuart A.; Murphy, Shane M.; Parrish, David D.; Senff, Christoph J.; Soltis, Jeffrey; Stutz, Jochen; Sweeney, Colm; Thompson, Chelsea R.; Trainer, Michael K.; Tsai, Catalina; Veres, Patrick R.; Washenfelder, Rebecca A.; Warneke, Carsten; Wild, Robert J.; Young, Cora J.; Yuan, Bin; Zamora, Robert

    2014-10-01

    The United States is now experiencing the most rapid expansion in oil and gas production in four decades, owing in large part to implementation of new extraction technologies such as horizontal drilling combined with hydraulic fracturing. The environmental impacts of this development, from its effect on water quality to the influence of increased methane leakage on climate, have been a matter of intense debate. Air quality impacts are associated with emissions of nitrogen oxides (NOx = NO + NO2) and volatile organic compounds (VOCs), whose photochemistry leads to production of ozone, a secondary pollutant with negative health effects. Recent observations in oil- and gas-producing basins in the western United States have identified ozone mixing ratios well in excess of present air quality standards, but only during winter. Understanding winter ozone production in these regions is scientifically challenging. It occurs during cold periods of snow cover when meteorological inversions concentrate air pollutants from oil and gas activities, but when solar irradiance and absolute humidity, which are both required to initiate conventional photochemistry essential for ozone production, are at a minimum. Here, using data from a remote location in the oil and gas basin of northeastern Utah and a box model, we provide a quantitative assessment of the photochemistry that leads to these extreme winter ozone pollution events, and identify key factors that control ozone production in this unique environment. We find that ozone production occurs at lower NOx and much larger VOC concentrations than does its summertime urban counterpart, leading to carbonyl (oxygenated VOCs with a C = O moiety) photolysis as a dominant oxidant source. Extreme VOC concentrations optimize the ozone production efficiency of NOx. There is considerable potential for global growth in oil and gas extraction from shale. This analysis could help inform strategies to monitor and mitigate air quality impacts

  16. High winter ozone pollution from carbonyl photolysis in an oil and gas basin.

    PubMed

    Edwards, Peter M; Brown, Steven S; Roberts, James M; Ahmadov, Ravan; Banta, Robert M; deGouw, Joost A; Dubé, William P; Field, Robert A; Flynn, James H; Gilman, Jessica B; Graus, Martin; Helmig, Detlev; Koss, Abigail; Langford, Andrew O; Lefer, Barry L; Lerner, Brian M; Li, Rui; Li, Shao-Meng; McKeen, Stuart A; Murphy, Shane M; Parrish, David D; Senff, Christoph J; Soltis, Jeffrey; Stutz, Jochen; Sweeney, Colm; Thompson, Chelsea R; Trainer, Michael K; Tsai, Catalina; Veres, Patrick R; Washenfelder, Rebecca A; Warneke, Carsten; Wild, Robert J; Young, Cora J; Yuan, Bin; Zamora, Robert

    2014-10-16

    The United States is now experiencing the most rapid expansion in oil and gas production in four decades, owing in large part to implementation of new extraction technologies such as horizontal drilling combined with hydraulic fracturing. The environmental impacts of this development, from its effect on water quality to the influence of increased methane leakage on climate, have been a matter of intense debate. Air quality impacts are associated with emissions of nitrogen oxides (NOx = NO + NO2) and volatile organic compounds (VOCs), whose photochemistry leads to production of ozone, a secondary pollutant with negative health effects. Recent observations in oil- and gas-producing basins in the western United States have identified ozone mixing ratios well in excess of present air quality standards, but only during winter. Understanding winter ozone production in these regions is scientifically challenging. It occurs during cold periods of snow cover when meteorological inversions concentrate air pollutants from oil and gas activities, but when solar irradiance and absolute humidity, which are both required to initiate conventional photochemistry essential for ozone production, are at a minimum. Here, using data from a remote location in the oil and gas basin of northeastern Utah and a box model, we provide a quantitative assessment of the photochemistry that leads to these extreme winter ozone pollution events, and identify key factors that control ozone production in this unique environment. We find that ozone production occurs at lower NOx and much larger VOC concentrations than does its summertime urban counterpart, leading to carbonyl (oxygenated VOCs with a C = O moiety) photolysis as a dominant oxidant source. Extreme VOC concentrations optimize the ozone production efficiency of NOx. There is considerable potential for global growth in oil and gas extraction from shale. This analysis could help inform strategies to monitor and mitigate air quality impacts

  17. High winter ozone pollution from carbonyl photolysis in an oil and gas basin.

    PubMed

    Edwards, Peter M; Brown, Steven S; Roberts, James M; Ahmadov, Ravan; Banta, Robert M; deGouw, Joost A; Dubé, William P; Field, Robert A; Flynn, James H; Gilman, Jessica B; Graus, Martin; Helmig, Detlev; Koss, Abigail; Langford, Andrew O; Lefer, Barry L; Lerner, Brian M; Li, Rui; Li, Shao-Meng; McKeen, Stuart A; Murphy, Shane M; Parrish, David D; Senff, Christoph J; Soltis, Jeffrey; Stutz, Jochen; Sweeney, Colm; Thompson, Chelsea R; Trainer, Michael K; Tsai, Catalina; Veres, Patrick R; Washenfelder, Rebecca A; Warneke, Carsten; Wild, Robert J; Young, Cora J; Yuan, Bin; Zamora, Robert

    2014-10-16

    The United States is now experiencing the most rapid expansion in oil and gas production in four decades, owing in large part to implementation of new extraction technologies such as horizontal drilling combined with hydraulic fracturing. The environmental impacts of this development, from its effect on water quality to the influence of increased methane leakage on climate, have been a matter of intense debate. Air quality impacts are associated with emissions of nitrogen oxides (NOx = NO + NO2) and volatile organic compounds (VOCs), whose photochemistry leads to production of ozone, a secondary pollutant with negative health effects. Recent observations in oil- and gas-producing basins in the western United States have identified ozone mixing ratios well in excess of present air quality standards, but only during winter. Understanding winter ozone production in these regions is scientifically challenging. It occurs during cold periods of snow cover when meteorological inversions concentrate air pollutants from oil and gas activities, but when solar irradiance and absolute humidity, which are both required to initiate conventional photochemistry essential for ozone production, are at a minimum. Here, using data from a remote location in the oil and gas basin of northeastern Utah and a box model, we provide a quantitative assessment of the photochemistry that leads to these extreme winter ozone pollution events, and identify key factors that control ozone production in this unique environment. We find that ozone production occurs at lower NOx and much larger VOC concentrations than does its summertime urban counterpart, leading to carbonyl (oxygenated VOCs with a C = O moiety) photolysis as a dominant oxidant source. Extreme VOC concentrations optimize the ozone production efficiency of NOx. There is considerable potential for global growth in oil and gas extraction from shale. This analysis could help inform strategies to monitor and mitigate air quality impacts

  18. Promoted decomposition of NOx in automotive diesel-like exhausts by electro-catalytic honeycombs.

    PubMed

    Huang, Ta-Jen; Chiang, De-Yi; Shih, Chi; Lee, Cheng-Chin; Mao, Chih-Wei; Wang, Bo-Chung

    2015-03-17

    NO and NO2 (collectively called NOx) are major air pollutants in automotive emissions. More effective and easier treatments of NOx than those achieved by the present methods can offer better protection of human health and higher fuel efficiency that can reduce greenhouse gas emissions. However, currently commercialized technologies for automotive NOx emission control cannot effectively treat diesel-like exhausts with high NOx concentrations. Thus, exhaust gas recirculation (EGR) has been used extensively, which reduces fuel efficiency and increases particulate emission considerably. Our results show that the electro-catalytic honeycomb (ECH) promotes the decomposition of NOx to nitrogen and oxygen, without consuming reagents or other resources. NOx can be converted to nitrogen and oxygen almost completely. The ECHs are shown to effectively remove NOx from gasoline-fueled diesel-like exhausts. A very high NO concentration is preferred in the engine exhaust, especially during engine cold-start. Promoted NOx decomposition (PND) technology for real-world automotive applications is established in this study by using the ECH. With PND, EGR is no longer needed. Diesel-like engines can therefore achieve superior fuel efficiency, and all major automotive pollutants can be easily treated due to high concentration of oxygen in the diesel-like exhausts, leading to zero pollution. PMID:25719390

  19. Promoted decomposition of NOx in automotive diesel-like exhausts by electro-catalytic honeycombs.

    PubMed

    Huang, Ta-Jen; Chiang, De-Yi; Shih, Chi; Lee, Cheng-Chin; Mao, Chih-Wei; Wang, Bo-Chung

    2015-03-17

    NO and NO2 (collectively called NOx) are major air pollutants in automotive emissions. More effective and easier treatments of NOx than those achieved by the present methods can offer better protection of human health and higher fuel efficiency that can reduce greenhouse gas emissions. However, currently commercialized technologies for automotive NOx emission control cannot effectively treat diesel-like exhausts with high NOx concentrations. Thus, exhaust gas recirculation (EGR) has been used extensively, which reduces fuel efficiency and increases particulate emission considerably. Our results show that the electro-catalytic honeycomb (ECH) promotes the decomposition of NOx to nitrogen and oxygen, without consuming reagents or other resources. NOx can be converted to nitrogen and oxygen almost completely. The ECHs are shown to effectively remove NOx from gasoline-fueled diesel-like exhausts. A very high NO concentration is preferred in the engine exhaust, especially during engine cold-start. Promoted NOx decomposition (PND) technology for real-world automotive applications is established in this study by using the ECH. With PND, EGR is no longer needed. Diesel-like engines can therefore achieve superior fuel efficiency, and all major automotive pollutants can be easily treated due to high concentration of oxygen in the diesel-like exhausts, leading to zero pollution.

  20. Application of modern online instrumentation for chemical analysis of gas and particulate phases of exhaust at the European Commission heavy-duty vehicle emission laboratory.

    PubMed

    Adam, T W; Chirico, R; Clairotte, M; Elsasser, M; Manfredi, U; Martini, G; Sklorz, M; Streibel, T; Heringa, M F; Decarlo, P F; Baltensperger, U; De Santi, G; Krasenbrink, A; Zimmermann, R; Prevot, A S H; Astorga, C

    2011-01-01

    The European Commission recently established a novel test facility for heavy-duty vehicles to enhance more sustainable transport. The facility enables the study of energy efficiency of various fuels/scenarios as well as the chemical composition of evolved exhaust emissions. Sophisticated instrumentation for real-time analysis of the gas and particulate phases of exhaust has been implemented. Thereby, gas-phase characterization was carried out by a Fourier transform infrared spectrometer (FT-IR; carbonyls, nitrogen-containing species, small hydrocarbons) and a resonance-enhanced multiphoton ionization time-of-flight mass spectrometer (REMPI-TOFMS; monocyclic and polycyclic aromatic hydrocarbons). For analysis of the particulate phase, a high-resolution time-of-flight aerosol mass spectrometer (HR-TOF-AMS; organic matter, chloride, nitrate), a condensation particle counter (CPC; particle number), and a multiangle absorption photometer (MAAP; black carbon) were applied. In this paper, the first application of the new facility in combination with the described instruments is presented, whereby a medium-size truck was investigated by applying different driving cycles. The goal was simultaneous chemical characterization of a great variety of gaseous compounds and particulate matter in exhaust on a real-time basis. The time-resolved data allowed new approaches to view the results; for example, emission factors were normalized to time-resolved consumption of fuel and were related to emission factors evolved during high speeds. Compounds could be identified that followed the fuel consumption, others showed very different behavior. In particular, engine cold start, engine ignition (unburned fuel), and high-speed events resulted in unique emission patterns.

  1. Functionalized single wall carbon nanotube sensor in a perturbed microwave resonant cavity based toxin/pollutant gas pressure sensor

    NASA Astrophysics Data System (ADS)

    Tooski, S. B.

    2010-02-01

    The Vlasov and Maxwell's equations are established and solved numerically to describe the effects of toxin/pollutant gas pressure and functionalized single wall carbon nanotube (SWCNT) sensor in a perturbed microwave resonant cavity. The dependence of the absorption coefficient on incident frequency, toxin/pollutant gas pressure, electron density, and collision frequency is presented. The numerical results illustrate that the resonant frequency shifts by a suitable amount for modest changes in toxin/pollutant gas pressure. It is also illustrated that high density and low collision of the blend of toxin/pollutant gas and SWCNT sensor in a microwave resonant cavity can be employed as broadband absorption of microwave and the detection of toxin/pollutant gas characteristics through adjustments of the amount of toxin/pollutant gas pressure and functionalized SCWNT sensor. The numerical results additionally illustrate that the microwave absorption spectra of the blend of toxin/pollutant gas and SWCNT sensor in a microwave resonant cavity are in good agreement with the available experimental data. The present method is, in principle, applicable to any kind of a single nanofiber, nanowire, silica gel, cotton fiber, and even various types of nanotubes.

  2. Coke-free dry reforming of model diesel fuel by a pulsed spark plasma at low temperatures using an exhaust gas recirculation (EGR) system

    NASA Astrophysics Data System (ADS)

    Sekine, Yasushi; Furukawa, Naotsugu; Matsukata, Masahiko; Kikuchi, Eiichi

    2011-07-01

    Dry reforming of diesel fuel, an endothermic reaction, is an attractive process for on-board hydrogen/syngas production to increase energy efficiency. For operating this dry reforming process in a vehicle, we can use the exhaust gas from an exhaust gas recirculation (EGR) system as a source of carbon dioxide. Catalytic dry reforming of heavy hydrocarbon is a very difficult reaction due to the high accumulation of carbon on the catalyst. Therefore, we attempted to use a non-equilibrium pulsed plasma for the dry reforming of model diesel fuel without a catalyst. We investigated dry reforming of model diesel fuel (n-dodecane) with a low-energy pulsed spark plasma, which is a kind of non-equilibrium plasma at a low temperature of 523 K. Through the reaction, we were able to obtain syngas (hydrogen and carbon monoxide) and a small amount of C2 hydrocarbon without coke formation at a ratio of CO2/Cfuel = 1.5 or higher. The reaction can be conducted at very low temperatures such as 523 K. Therefore, it is anticipated as a novel and effective process for on-board syngas production from diesel fuel using an EGR system.

  3. Air Pollution

    MedlinePlus

    Air pollution is a mixture of solid particles and gases in the air. Car emissions, chemicals from factories, ... Ozone, a gas, is a major part of air pollution in cities. When ozone forms air pollution, it's ...

  4. Pollutant exposures from unvented gas cooking burners: A Simulation-based Assessment for Southern California

    SciTech Connect

    Logue, Jennifer M.; Klepeis, Neil E.; Lobscheid, Agnes B.; Singer, Brett C.

    2014-01-01

    Residential natural gas cooking burners (NGCBs) can emit substantial quantities of pollutants, and they are typically used without venting range hoods. In this study, LBNL researchers quantified pollutant concentrations and occupant exposures resulting from NGCB use in California homes.The simulation model estimated that—in homes using NGCBs without coincident use of venting range hoods -- 62%, 9%, and 53% of occupants are routinely exposed to NO2, CO, and HCHO levels that exceed acute health-based standards and guidelines. NGCB use increased the sample median of the highest simulated 1-hr indoor concentrations by 100, 3,000, and 20 ppb for NO2, CO, and HCHO, respectively. The study recommends that reducing pollutant exposures from NGCBs should be a public health priority. Simulation results suggest that regular use of even moderately effective venting range hoods would dramatically reduce the percentage of homes in which concentrations exceed health-based standards.

  5. Gas-phase advanced oxidation for effective, efficient in situ control of pollution.

    PubMed

    Johnson, Matthew S; Nilsson, Elna J K; Svensson, Erik A; Langer, Sarka

    2014-01-01

    In this article, gas-phase advanced oxidation, a new method for pollution control building on the photo-oxidation and particle formation chemistry occurring in the atmosphere, is introduced and characterized. The process uses ozone and UV-C light to produce in situ radicals to oxidize pollution, generating particles that are removed by a filter; ozone is removed using a MnO2 honeycomb catalyst. This combination of in situ processes removes a wide range of pollutants with a comparatively low specific energy input. Two proof-of-concept devices were built to test and optimize the process. The laboratory prototype was built of standard ventilation duct and could treat up to 850 m(3)/h. A portable continuous-flow prototype built in an aluminum flight case was able to treat 46 m(3)/h. Removal efficiencies of >95% were observed for propane, cyclohexane, benzene, isoprene, aerosol particle mass, and ozone for concentrations in the range of 0.4-6 ppm and exposure times up to 0.5 min. The laboratory prototype generated a OH(•) concentration derived from propane reaction of (2.5 ± 0.3) × 10(10) cm(-3) at a specific energy input of 3 kJ/m(3), and the portable device generated (4.6 ± 0.4) × 10(9) cm(-3) at 10 kJ/m(3). Based on these results, in situ gas-phase advanced oxidation is a viable control strategy for most volatile organic compounds, specifically those with a OH(•) reaction rate higher than ca. 5 × 10(-13) cm(3)/s. Gas-phase advanced oxidation is able to remove compounds that react with OH and to control ozone and total particulate mass. Secondary pollution including formaldehyde and ultrafine particles might be generated, depending on the composition of the primary pollution.

  6. DESIGN, FABRICATION, AND TESTING OF AN ADVANCED, NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    SciTech Connect

    E.W. Baxter

    2002-06-30

    The objective of this report period was to continue the development of the Gas Generator design, completion of the hardware and ancillary hardware fabrication and commence the Test Preparations for the testing of the non-polluting unique power turbine driven Gas Generator. Focus during this report period has been on completing the Gas Generator fabrication of hardware and ancillary hardware, and completion of unit closeout brazing and bonding. Because of unacceptable delays encountered in a previously competitively selected test site, CES initiated a re-competition of our testing program and selected an alternate test site. Following that selection, CES used all available resources to make preparations for testing the 10 Mw Gas Generator at the new testing site facilities of NTS at Saugus, CA.

  7. Modeling of Air Pollution Systems with Chemical Reactions: Application to Gas Flares in Nigeria

    NASA Astrophysics Data System (ADS)

    Susu, Alfred A.; Abhulimen, Kingsley E.; Adereti, Adedayo B.

    2005-09-01

    The Eulerian model was used for the prediction of air pollutants in some gas flare locations in the Niger Delta region of Nigeria. A continuity equation (mass balance) that incorporates second order reaction schemes for the generation of pollutants at source or in the ensuing atmosphere was used to characterize the n species in the fluid element and the finite difference method (the Crank-Nicholson formulation) was applied for the numerical scheme. Thus, the spatial and transient concentration profiles of key contaminants were obtained for the meteorological conditions under consideration. The first series of simulations were carried out at ground level and at altitudes of 30 and 90 m, for a simulation time of 10 min. The second series of simulations were identical to the first, except that the simulation time was 20 min. The third series of simulations were carried out for 50 min at ground level and at an altitude of 30 m. The concentration profiles were parabolic for at least one of the pollutants at the ground level for 10, 20 and 50 min simulation times, and additionally at an altitude of 30 m for a simulation time of 50 min. Other concentration profiles are exponential in nature. The deterministic Eulerian model provided a satisfactory prediction of the spatial and transient concentration profiles for the pollutants in the gas flares.

  8. FABRICATE AND TEST AN ADVANCED NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    SciTech Connect

    Eugene Baxter; Roger E. Anderson; Stephen E. Doyle

    2003-06-01

    In September 2000 the Department of Energy's National Energy Technology Laboratory (DOE/NETL) contracted with Clean Energy Systems, Inc. (CES) of Sacramento, California to design, fabricate, and test a 20 MW{sub t} (10 MW{sub e}) gas generator. Program goals were to demonstrate a non-polluting gas generator at temperatures up to 3000 F at 1500 psi, and to demonstrate resulting drive gas composition, comprising steam and carbon dioxide substantially free of pollutants. Following hardware design and fabrication, testing, originally planned to begin in the summer of 2001, was delayed by unavailability of the contracted test facility. CES designed, fabricated, and tested the proposed gas generator as originally agreed. The CES process for producing near-zero-emissions power from fossil fuels is based on the near-stoichiometric combustion of a clean gaseous fuel with oxygen in the presence of recycled water, to produce a high-temperature, high-pressure turbine drive fluid comprising steam and carbon dioxide. Tests demonstrated igniter operation over the prescribed ranges of pressure and mixture ratios. Ignition was repeatable and reliable through more than 100 ignitions. Injector design ''A'' was operated successfully at both low power ({approx}20% of rated power) and at rated power ({approx}20 MW{sub t}) in more than 95 tests. The uncooled gas generator configuration (no diluent injectors or cooldown chambers installed) produced drive gases at temperatures approaching 3000 F and at pressures greater than 1550 psia. The fully cooled gas generator configuration, with cooldown chambers and injector ''A'', operated consistently at pressures from 1100 to 1540 psia and produced high pressure, steam-rich turbine drive gases at temperatures ranging from {approx}3000 to as low as 600 F. This report includes description of the intended next steps in the gas generator technology demonstration and traces the anticipated pathway to commercialization for the gas generator technology

  9. 40 CFR 87.31 - Standards for exhaust emissions.

    Code of Federal Regulations, 2014 CFR

    2014-07-01

    ... Gas Turbine Engines) § 87.31 Standards for exhaust emissions. (a) Exhaust emissions of smoke from each in-use aircraft gas turbine engine of Class T8, beginning February 1, 1974, shall not exceed: Smoke number of 30. (b) Exhaust emissions of smoke from each in-use aircraft gas turbine engine of class TF...

  10. 40 CFR 87.31 - Standards for exhaust emissions.

    Code of Federal Regulations, 2013 CFR

    2013-07-01

    ... Gas Turbine Engines) § 87.31 Standards for exhaust emissions. (a) Exhaust emissions of smoke from each in-use aircraft gas turbine engine of Class T8, beginning February 1, 1974, shall not exceed: Smoke number of 30. (b) Exhaust emissions of smoke from each in-use aircraft gas turbine engine of class TF...

  11. 40 CFR 87.31 - Standards for exhaust emissions.

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... Gas Turbine Engines) § 87.31 Standards for exhaust emissions. (a) Exhaust emissions of smoke from each in-use aircraft gas turbine engine of Class T8, beginning February 1, 1974, shall not exceed: Smoke number of 30. (b) Exhaust emissions of smoke from each in-use aircraft gas turbine engine of class TF...

  12. 40 CFR 87.31 - Standards for exhaust emissions.

    Code of Federal Regulations, 2012 CFR

    2012-07-01

    ... (CONTINUED) Definitions. Exhaust Emissions (In-Use Aircraft Gas Turbine Engines) § 87.31 Standards for exhaust emissions. (a) Exhaust emissions of smoke from each in-use aircraft gas turbine engine of Class T8... in-use aircraft gas turbine engine of class TF and of rated output of 129 kilonewtons thrust...

  13. Posttranslational modification of bioaerosol protein by common gas pollutants: NO2 and O3

    NASA Astrophysics Data System (ADS)

    Abdullahi Mahmood, Marliyyah; Bloss, William; Pope, Francis

    2016-04-01

    Air pollution can exacerbate several medical conditions, for example, hay fever and asthma. The global incidence of hay fever has been rising for decades; however, the underlying reasons behind this rise remain unclear. It is hypothesized that the exposure of pollen to common gas phase pollutants, such as nitrogen dioxide (NO2) and ozone (O3), increases the allergenicity of the pollen and thus increases hay fever incidence (Reinmuth-Selzle et al., 2014, Franze, et al., 2005). Since atmospheric pollutants often have greater concentrations within urban areas (in particular NO2) the hypothesis suggests that greater allergenicity should occur in urban areas. Certainly, several studies do suggest higher hay fever incidence within urban areas compared to rural areas (Schröder et al., 2015). Previous published work suggests a link between increased allergies and changes in the chemical composition of pollen protein via posttranslational modification of the protein (Reinmuth-Selzle et al., 2014). This study investigates the posttranslational modification of two highly allergenic pollen species (Birch and Ragweed) that are common in Europe. Within the laboratory, we expose pollen grains to atmospherically relevant exposures of gas phase NO2, O3 and other common gas phase oxidants under a range of environmentally relevant conditions. The effects of the exposures on the biochemistry of the pollen grains were probed using a proteomic approach (liquid chromatography coupled ultra-high resolution spectrometer). Our findings indicate the interaction between gas phase pollutants and pollen cause protein specific modifications; in particular nitration that occurs upon tyrosine residues and nitrosylation on cysteine residues. These modifications may affect human immune response to the pollen protein, which may suggest a possible reason for increased allergies in reaction to such chemically altered protein. Quantification of the relative degree of PTMs, from a variety of

  14. DESIGN, FABRICATION, AND TESTING OF AN ADVANCED, NON-POLLUTING TURBINE DRIVE GAS GENERATOR

    SciTech Connect

    Unknown

    2002-01-31

    The objective of this report period was to continue the development of the Gas Generator design, fabrication and test of the non-polluting unique power turbine drive Gas Generator. Focus during this past report period has been to continue completion the Gas Generator design, completing the brazing and bonding experiments to determine the best method and materials necessary to fabricate the Gas Generator hardware, continuing to making preparations for fabricating and testing this Gas Generator and commencing with the fabrication of the Gas Generator hardware and ancillary hardware. Designs have been completed sufficiently such that Long Lead Items [LLI] have been ordered and upon arrival will be readied for the fabrication process. The keys to this design are the platelet construction of the injectors that precisely measures/meters the flow of the propellants and water all throughout the steam generating process and the CES patented gas generating cycle. The Igniter Assembly injector platelets fabrication process has been completed and bonded to the Igniter Assembly and final machined. The Igniter Assembly is in final assembly and is being readied for testing in the October 2001 time frame. Test Plan dated August 2001, was revised and finalized, replacing Test Plan dated May 2001.

  15. EVALUATION OF A PORTABLE FOURIER TRANSFORM INFRARED GAS ANALYZER FOR MEASUREMENTS OF AIR TOXICS IN POLLUTION PREVENTION RESEARCH

    EPA Science Inventory

    A portable Fourier transform infrared gas analyzer with a photoacoustic detector performed reliably during pollution prevention research at two industrial facilities. It exhibited good agreement (within approximately 6%) with other analytical instruments (dispersive infrared and ...

  16. Estimated times to exhaustion and power outputs at the gas exchange threshold, physical working capacity at the rating of perceived exertion threshold, and respiratory compensation point.

    PubMed

    Bergstrom, Haley C; Housh, Terry J; Zuniga, Jorge M; Camic, Clayton L; Traylor, Daniel A; Schmidt, Richard J; Johnson, Glen O

    2012-10-01

    The purposes of this study were to compare the power outputs and estimated times to exhaustion (T(lim)) at the gas exchange threshold (GET), physical working capacity at the rating of perceived exertion threshold (PWC(RPE)), and respiratory compensation point (RCP). Three male and 5 female subjects (mean ± SD: age, 22.4 ± 2.8 years) performed an incremental test to exhaustion on an electronically braked cycle ergometer to determine peak oxygen consumption rate, GET, and RCP. The PWC(RPE) was determined from ratings of perceived exertion data recorded during 3 continuous workbouts to exhaustion. The estimated T(lim) values for each subject at GET, PWC(RPE), and RCP were determined from power curve analyses (T(lim) = ax(b)). The results indicated that the PWC(RPE) (176 ± 55 W) was not significantly different from RCP (181 ± 54 W); however, GET (155 ± 42 W) was significantly less than PWC(RPE) and RCP. The estimated T(lim) for the GET (26.1 ± 9.8 min) was significantly greater than PWC(RPE) (14.6 ± 5.6 min) and RCP (11.2 ± 3.1 min). The PWC(RPE) occurred at a mean power output that was 13.5% greater than the GET and, therefore, it is likely that the perception of effort is not driven by the same mechanism that underlies the GET (i.e., lactate buffering). Furthermore, the PWC(RPE) and RCP were not significantly different and, therefore, these thresholds may be associated with the same mechanisms of fatigue, such as increased levels of interstitial and (or) arterial [K⁺]. PMID:22716291

  17. Polycyclic aromatic hydrocarbon emissions in diesel exhaust using gas chromatography-mass spectrometry with programmed temperature vaporization and large volume injection

    NASA Astrophysics Data System (ADS)

    Vieira de Souza, Carolina; Corrêa, Sergio Machado

    2015-02-01

    Diesel engines are significant sources of Polycyclic Aromatic Compounds (PAHs) in urban atmospheres. These compounds are widely known for their carcinogenic potential and mutagenic properties. In this study, a method was developed for the analysis of 16 priorities PAHs using gas chromatography-mass spectrometry (GC-MS) with programmable temperature vaporizer large volume injection (PTV-LVI), which allowed to be obtained detection limits below 2.0 ng mL-1. This method was evaluated in samples from stratified particulate matter and gas phase from the emissions of diesel vehicle employing diesel commercial S10 (sulfur 10 mg L-1) and B5 (biodiesel 5% v/v). A sampling system that does not employ exhaust products dilution was used to evaluate the PAHs gas-particle partition. Six PAHs were identified in extracts and gas-phase PAHs took percentage of 80% in the total PAHs emissions. The sampling system without dilution not caused a strong nucleation/condensation of the most volatile PAHs. PAHs size-particle distribution was found in higher levels in the accumulation mode.

  18. [Passive detection of aeroengine exhaust based on Fourier transform infrared system].

    PubMed

    Li, Shao-cheng; Zuo, Hong-fu; Xia, Qing

    2008-10-01

    Since the composition and concentration of aeroengine exhaust can reflect the combustion efficiency, they can provide the basis for condition based maintenance, and also the basis for the analysis of environment pollution caused by aeroengine exhaust. So the importance of aeroengine exhaust detection is evident. Up to now, the measurement of aeroengine exhaust is based on sampling analysis which is not convenient and can't meet the detection requirements when an aeroplane is flying-off or flying in the sky. Hence, new methods of exhaust detection must be studied. The passive measurement technology based on Fourier transform infrared spectroscopy (FTIR) was applied to the measurement of aeroengine exhaust in the present paper. At first, the principle of passive measurement based on FTIR was introduced in detail. On this basis, a model algorithm for gas concentration calculation was deduced based on the principle of infrared transmission. Then the feasibility of aeroengine exhaust measurement based on passive FTIR was analyzed, and the passive measurement method of aeroengine exhaust based on FTIR was given. In the end, an experiment of aeroengine exhaust passive measurement was carried out by a FTIR with the type of Tensor 27 produced by BRUKER. Good quality spectra of the exhaust and the background were measured. Based on the model algo rithm of passive measurement, the absorbance spectra of CO and NO were obtained respectively, and the concentrations of CO and NO were figured out. To check up the veracity of this method, a comparison was made with another apparatus. There were only little differences between the results of the two experiments, showing that the passive measurement technology based on FTIR could meet the requirements of aeroengine exhaust detection.

  19. Sequestration of flue gas CO₂ by direct gas-solid carbonation of air pollution control system residues.

    PubMed

    Tian, Sicong; Jiang, Jianguo

    2012-12-18

    Direct gas-solid carbonation reactions of residues from an air pollution control system (APCr) were conducted using different combinations of simulated flue gas to study the impact on CO₂ sequestration. X-ray diffraction analysis of APCr determined the existence of CaClOH, whose maximum theoretical CO₂ sequestration potential of 58.13 g CO₂/kg APCr was calculated by the reference intensity ratio method. The reaction mechanism obeyed a model of a fast kinetics-controlled process followed by a slow product layer diffusion-controlled process. Temperature is the key factor in direct gas-solid carbonation and had a notable influence on both the carbonation conversion and the CO₂ sequestration rate. The optimal CO₂ sequestrating temperature of 395 °C was easily obtained for APCr using a continuous heating experiment. CO₂ content in the flue gas had a definite influence on the CO₂ sequestration rate of the kinetics-controlled process, but almost no influence on the final carbonation conversion. Typical concentrations of SO₂ in the flue gas could not only accelerate the carbonation reaction rate of the product layer diffusion-controlled process, but also could improve the final carbonation conversion. Maximum carbonation conversions of between 68.6% and 77.1% were achieved in a typical flue gas. Features of rapid CO₂ sequestration rate, strong impurities resistance, and high capture conversion for direct gas-solid carbonation were proved in this study, which presents a theoretical foundation for the applied use of this encouraging technology on carbon capture and storage.

  20. Effect of cooled EGR on performance and exhaust gas emissions in EFI spark ignition engine fueled by gasoline and wet methanol blends

    NASA Astrophysics Data System (ADS)

    Rohadi, Heru; Syaiful, Bae, Myung-Whan

    2016-06-01

    Fuel needs, especially the transport sector is still dominated by fossil fuels which are non-renewable. However, oil reserves are very limited. Furthermore, the hazardous components produced by internal combustion engine forces many researchers to consider with alternative fuel which is environmental friendly and renewable sources. Therefore, this study intends to investigate the impact of cooled EGR on the performance and exhaust gas emissions in the gasoline engine fueled by gasoline and wet methanol blends. The percentage of wet methanol blended with gasoline is in the range of 5 to 15% in a volume base. The experiment was performed at the variation of engine speeds from 2500 to 4000 rpm with 500 intervals. The re-circulated exhaust gasses into combustion chamber was 5%. The experiment was performed at the constant engine speed. The results show that the use of cooled EGR with wet methanol of 10% increases the brake torque up to 21.3%. The brake thermal efficiency increases approximately 39.6% using cooled EGR in the case of the engine fueled by 15% wet methanol. Brake specific fuel consumption for the engine using EGR fueled by 10% wet methanol decreases up to 23% at the engine speed of 2500 rpm. The reduction of CO, O2 and HC emissions was found, while CO2 increases.

  1. Pollutant Exposures from Natural Gas Cooking Burners: A Simulation-Based Assessment for Southern California

    SciTech Connect

    Logue, Jennifer M.; Klepeis, Neil E.; Lobscheid, Agnes B.; Singer, Brett C.

    2014-06-01

    Residential natural gas cooking burners (NGCBs) can emit substantial quantities of pollutants and they are typically used without venting. The objective of this study is to quantify pollutant concentrations and occupant exposures resulting from NGCB use in California homes. A mass balance model was applied to estimate time-dependent pollutant concentrations throughout homes and the "exposure concentrations" experienced by individual occupants. The model was applied to estimate nitrogen dioxide (NO{sub 2}), carbon monoxide (CO), and formaldehyde (HCHO) concentrations for one week each in summer and winter for a representative sample of Southern California homes. The model simulated pollutant emissions from NGCBs, NO{sub 2} and CO entry from outdoors, dilution throughout the home, and removal by ventilation and deposition. Residence characteristics and outdoor concentrations of CO and NO{sub 2} were obtained from available databases. Ventilation rates, occupancy patterns, and burner use were inferred from household characteristics. Proximity to the burner(s) and the benefits of using venting range hoods were also explored. Replicate model executions using independently generated sets of stochastic variable values yielded estimated pollutant concentration distributions with geometric means varying less than 10%. The simulation model estimates that in homes using NGCBs without coincident use of venting range hoods, 62%, 9%, and 53% of occupants are routinely exposed to NO{sub 2}, CO, and HCHO levels that exceed acute health-based standards and guidelines. NGCB use increased the sample median of the highest simulated 1-hr indoor concentrations by 100, 3000, and 20 ppb for NO{sub 2}, CO, and HCHO, respectively. Reducing pollutant exposures from NGCBs should be a public health priority. Simulation results suggest that regular use of even moderately effective venting range hoods would dramatically reduce the percentage of homes in which concentrations exceed health

  2. Pollutant Exposures from Natural Gas Cooking Burners: A Simulation-Based Assessment for Southern California

    PubMed Central

    Klepeis, Neil E.; Lobscheid, Agnes B.; Singer, Brett C.

    2013-01-01

    Background: Residential natural gas cooking burners (NGCBs) can emit substantial quantities of pollutants, and they are typically used without venting range hoods. Objective: We quantified pollutant concentrations and occupant exposures resulting from NGCB use in California homes. Methods: A mass-balance model was applied to estimate time-dependent pollutant concentrations throughout homes in Southern California and the exposure concentrations experienced by individual occupants. We estimated nitrogen dioxide (NO2), carbon monoxide (CO), and formaldehyde (HCHO) concentrations for 1 week each in summer and winter for a representative sample of Southern California homes. The model simulated pollutant emissions from NGCBs as well as NO2 and CO entry from outdoors, dilution throughout the home, and removal by ventilation and deposition. Residence characteristics and outdoor concentrations of NO2 and CO were obtained from available databases. We inferred ventilation rates, occupancy patterns, and burner use from household characteristics. We also explored proximity to the burner(s) and the benefits of using venting range hoods. Replicate model executions using independently generated sets of stochastic variable values yielded estimated pollutant concentration distributions with geometric means varying by < 10%. Results: The simulation model estimated that—in homes using NGCBs without coincident use of venting range hoods—62%, 9%, and 53% of occupants are routinely exposed to NO2, CO, and HCHO levels that exceed acute health-based standards and guidelines. NGCB use increased the sample median of the highest simulated 1-hr indoor concentrations by 100, 3,000, and 20 ppb for NO2, CO, and HCHO, respectively. Conclusions: Reducing pollutant exposures from NGCBs should be a public health priority. Simulation results suggest that regular use of even moderately effective venting range hoods would dramatically reduce the percentage of homes in which concentrations exceed

  3. A comparative study of the elemental composition of the exhaust emissions of cars powered by liquefied petroleum gas and unleaded petrol

    NASA Astrophysics Data System (ADS)

    Lim, McKenzie C. H.; Ayoko, Godwin A.; Morawska, Lidia; Ristovski, Zoran D.; Jayaratne, E. Rohan; Kokot, Serge

    Elements emitted from the exhausts of new Ford Falcon Forte cars powered by unleaded petrol (ULP) and liquefied petroleum gas (LPG) were measured on a chassis dynamometer. The measurements were carried out in February, June and August 2001, and at two steady state driving conditions (60 and 80 km h -1). Thirty seven elements were quantified in the exhaust samples by inductively coupled plasma mass spectrometry (ICPMS). The total emission factors of the elements from the exhausts of ULP cars were higher than those of LPG cars at both engine speeds even though high variability in the exhaust emissions from different cars was noted. The effect of the operating conditions such as mileage of the cars, engine speed, fuel and lubricating oil compositions on the emissions was studied. To investigate the effects of these conditions, multivariate data analysis methods were employed including exploratory principal component analysis (PCA), and the multi-criteria decision making methods (MCDM), preference ranking organization method for enrichment evaluation (PROMETHEE) and geometrical analysis for interactive aid (GAIA), for ranking the cars on the basis of the emission factors of the elements. PCA biplot of the complete data matrix showed a clear discrimination of the February, June and August emission test results. In addition, (i) platinum group elements (PGE) emissions were separated from each other in the three different clusters viz. Pt with February, Pd with June and Rh with August; (ii) the motor oil related elements, Zn and P, were particularly associated with the June and August tests (these vectors were also grouped with V, Al and Cu); and (iii) highest emissions of most major elements were associated with the August test after the cars have recorded their highest mileage. Extensive analysis with the aid of the MCDM ranking methods demonstrated clearly that cars powered by LPG outperform those powered by ULP. In general, cars tested in June perform better than

  4. Applications of optical measurement technology in pollution gas monitoring at thermal power plants

    NASA Astrophysics Data System (ADS)

    Wang, Jian; Yu, Dahai; Ye, Huajun; Yang, Jianhu; Ke, Liang; Han, Shuanglai; Gu, Haitao; Chen, Yingbin

    2011-11-01

    This paper presents the work of using advanced optical measurement techniques to implement stack gas emission monitoring and process control. A system is designed to conduct online measurement of SO2/NOX and mercury emission from stacks and slipping NH3 of de-nitrification process. The system is consisted of SO2/NOX monitoring subsystem, mercury monitoring subsystem, and NH3 monitoring subsystem. The SO2/NOX monitoring subsystem is developed based on the ultraviolet differential optical absorption spectroscopy (UV-DOAS) technique. By using this technique, a linearity error less than +/-1% F.S. is achieved, and the measurement errors resulting from optical path contamination and light fluctuation are removed. Moreover, this subsystem employs in situ extraction and hot-wet line sampling technique to significantly reduce SO2 loss due to condensation and protect gas pipeline from corrosion. The mercury monitoring subsystem is used to measure the concentration of element mercury (Hg0), oxidized mercury (Hg2+), and total gaseous mercury (HgT) in the flue gas exhaust. The measurement of Hg with a low detection limit (0.1μg/m3) and a high sensitivity is realized by using cold vapor atom fluorescence spectroscopy (CVAFS) technique. This subsystem is also equipped with an inertial separation type sampling technique to prevent gas pipeline from being clogged and to reduce speciation mercury measurement error. The NH3 monitoring subsystem is developed to measure the concentration of slipping NH3 and then to help improving the efficiency of de-nitrification. The NH3 concentration as low as 0.1ppm is able to be measured by using the off-axis integrated cavity output spectroscopy (ICOS) and the tunable diode laser absorption spectroscopy (TDLAS) techniques. The problem of trace NH3 sampling loss is solved by applying heating the gas pipelines when the measurement is running.

  5. Statistical evaluation of the impact of shale gas activities on ozone pollution in North Texas.

    PubMed

    Ahmadi, Mahdi; John, Kuruvilla

    2015-12-01

    Over the past decade, substantial growth in shale gas exploration and production across the US has changed the country's energy outlook. Beyond its economic benefits, the negative impacts of shale gas development on air and water are less well known. In this study the relationship between shale gas activities and ground-level ozone pollution was statistically evaluated. The Dallas-Fort Worth (DFW) area in north-central Texas was selected as the study region. The Barnett Shale, which is one the most productive and fastest growing shale gas fields in the US, is located in the western half of DFW. Hourly meteorological and ozone data were acquired for fourteen years from monitoring stations established and operated by the Texas Commission on Environmental Quality (TCEQ). The area was divided into two regions, the shale gas region (SGR) and the non-shale gas (NSGR) region, according to the number of gas wells in close proximity to each monitoring site. The study period was also divided into 2000-2006 and 2007-2013 because the western half of DFW has experienced significant growth in shale gas activities since 2007. An evaluation of the raw ozone data showed that, while the overall trend in the ozone concentration was down over the entire region, the monitoring sites in the NSGR showed an additional reduction of 4% in the annual number of ozone exceedance days than those in the SGR. Directional analysis of ozone showed that the winds blowing from areas with high shale gas activities contributed to higher ozone downwind. KZ-filtering method and linear regression techniques were used to remove the effects of meteorological variations on ozone and to construct long-term and short-term meteorologically adjusted (M.A.) ozone time series. The mean value of all M.A. ozone components was 8% higher in the sites located within the SGR than in the NSGR. These findings may be useful for understanding the overall impact of shale gas activities on the local and regional ozone

  6. Statistical evaluation of the impact of shale gas activities on ozone pollution in North Texas.

    PubMed

    Ahmadi, Mahdi; John, Kuruvilla

    2015-12-01

    Over the past decade, substantial growth in shale gas exploration and production across the US has changed the country's energy outlook. Beyond its economic benefits, the negative impacts of shale gas development on air and water are less well known. In this study the relationship between shale gas activities and ground-level ozone pollution was statistically evaluated. The Dallas-Fort Worth (DFW) area in north-central Texas was selected as the study region. The Barnett Shale, which is one the most productive and fastest growing shale gas fields in the US, is located in the western half of DFW. Hourly meteorological and ozone data were acquired for fourteen years from monitoring stations established and operated by the Texas Commission on Environmental Quality (TCEQ). The area was divided into two regions, the shale gas region (SGR) and the non-shale gas (NSGR) region, according to the number of gas wells in close proximity to each monitoring site. The study period was also divided into 2000-2006 and 2007-2013 because the western half of DFW has experienced significant growth in shale gas activities since 2007. An evaluation of the raw ozone data showed that, while the overall trend in the ozone concentration was down over the entire region, the monitoring sites in the NSGR showed an additional reduction of 4% in the annual number of ozone exceedance days than those in the SGR. Directional analysis of ozone showed that the winds blowing from areas with high shale gas activities contributed to higher ozone downwind. KZ-filtering method and linear regression techniques were used to remove the effects of meteorological variations on ozone and to construct long-term and short-term meteorologically adjusted (M.A.) ozone time series. The mean value of all M.A. ozone components was 8% higher in the sites located within the SGR than in the NSGR. These findings may be useful for understanding the overall impact of shale gas activities on the local and regional ozone

  7. Multipass open-path Fourier-transform infrared measurements for nonintrusive monitoring of gas turbine exhaust composition.

    PubMed

    Schäfer, Klaus; Brockmann, Klaus; Heland, Jörg; Wiesen, Peter; Jahn, Carsten; Legras, Olivier

    2005-04-10

    The detection limits for NO and NO2 in turbine exhausts by nonintrusive monitoring have to be improved. Multipass mode Fourier-transform infrared (FTIR) absorption spectrometry and use of a White mirror system were found from a sensitivity study with spectra simulations in the mid-infrared to be essential for the retrieval of NO2 abundances. A new White mirror system with a parallel infrared beam was developed and tested successfully with a commercial FTIR spectrometer in different turbine test beds. The minimum detection limits for a typical turbine plume of 50 cm in diameter are approximately 6 parts per million (ppm) for NO and 9 ppm for NO2 (as well 100 ppm for CO2 and 4 ppm for CO).

  8. Radon and Thoron Measured in Petrol and Gas-oil Exhaust Fumes by Using CR-39 and LR-115 II Nuclear Track Detectors: Radiation Doses to the Respiratory Tract of Mechanic Workers.

    PubMed

    Misdaq, M A; Chaouqi, A; Ouguidi, J; Touti, R; Mortassim, A

    2015-06-01

    Mechanic workers are exposed to exhaust fumes when controlling vehicle engines in motion inside repair shops. To assess radiation doses due to radon short-lived progeny from the inhalation of exhaust fumes by mechanic workers, concentrations of these radionuclides were measured in petrol (gasoline) and gas-oil exhaust fumes by evaluating mean critical angles of etching of the CR-39 and LR-115 type II SSNTDs for alpha particles emitted by the radon and thoron decay series. Committed effective doses due to ²¹⁸Po and ²¹⁴Po short-lived radon decay products from the inhalation of petrol and gas-oil exhaust fumes by workers were evaluated. A maximum value of 1.35 mSv y⁻¹ due to radon short-lived decay products from the inhalation of gas-oil exhaust fumes by mechanic workers was found, which is lower than the (3-10 mSv y⁻¹) dose limit interval for workers.

  9. Inverted Fuel Cell: Room-Temperature Hydrogen Separation from an Exhaust Gas by Using a Commercial Short-Circuited PEM Fuel Cell without Applying any Electrical Voltage.

    PubMed

    Friebe, Sebastian; Geppert, Benjamin; Caro, Jürgen

    2015-06-26

    A short-circuited PEM fuel cell with a Nafion membrane has been evaluated in the room-temperature separation of hydrogen from exhaust gas streams. The separated hydrogen can be recovered or consumed in an in situ olefin hydrogenation when the fuel cell is operated as catalytic membrane reactor. Without applying an outer electrical voltage, there is a continuous hydrogen flux from the higher to the lower hydrogen partial pressure side through the Nafion membrane. On the feed side of the Nafion membrane, hydrogen is catalytically split into protons and electrons by the Pt/C electrocatalyst. The protons diffuse through the Nafion membrane, the electrons follow the short-circuit between the two brass current collectors. On the cathode side, protons and electrons recombine, and hydrogen is released.

  10. NOx abatement in the exhaust of lean-burn natural gas engines over Ag-supported γ-Al2O3 catalysts

    NASA Astrophysics Data System (ADS)

    Azizi, Y.; Kambolis, A.; Boréave, A.; Giroir-Fendler, A.; Retailleau-Mevel, L.; Guiot, B.; Marchand, O.; Walter, M.; Desse, M.-L.; Marchin, L.; Vernoux, P.

    2016-04-01

    A series of Ag catalysts supported on γ-Al2O3, including two different γ-Al2O3 supports and various Ag loadings (2-8 wt.%), was prepared, characterized (SEM, TEM, BET, physisorption, TPR, NH3-TPD) and tested for the selective catalytic reduction of NOx by CH4 for lean-burn natural gas engines exhausts. The catalysts containing 2 wt.% Ag supported on γ-Al2O3 were found to be most efficient for the NOx reduction into N2 with a maximal conversion of 23% at 650 °C. This activity was clearly linked with the ability of the catalyst to concomitantly produce CO, via the methane steam reforming, and NO2. The presence of small AgOx nanoparticles seems to be crucial for the methane activation and NOx reduction.

  11. Quantification of benzene, toluene, ethylbenzene and o-xylene in internal combustion engine exhaust with time-weighted average solid phase microextraction and gas chromatography mass spectrometry.

    PubMed

    Baimatova, Nassiba; Koziel, Jacek A; Kenessov, Bulat

    2015-05-11

    A new and simple method for benzene, toluene, ethylbenzene and o-xylene (BTEX) quantification in vehicle exhaust was developed based on diffusion-controlled extraction onto a retracted solid-phase microextraction (SPME) fiber coating. The rationale was to develop a method based on existing and proven SPME technology that is feasible for field adaptation in developing countries. Passive sampling with SPME fiber retracted into the needle extracted nearly two orders of magnitude less mass (n) compared with exposed fiber (outside of needle) and sampling was in a time weighted-averaging (TWA) mode. Both the sampling time (t) and fiber retraction depth (Z) were adjusted to quantify a wider range of Cgas. Extraction and quantification is conducted in a non-equilibrium mode. Effects of Cgas, t, Z and T were tested. In addition, contribution of n extracted by metallic surfaces of needle assembly without SPME coating was studied. Effects of sample storage time on n loss was studied. Retracted TWA-SPME extractions followed the theoretical model. Extracted n of BTEX was proportional to Cgas, t, Dg, T and inversely proportional to Z. Method detection limits were 1.8, 2.7, 2.1 and 5.2 mg m(-3) (0.51, 0.83, 0.66 and 1.62 ppm) for BTEX, respectively. The contribution of extraction onto metallic surfaces was reproducible and influenced by Cgas and t and less so by T and by the Z. The new method was applied to measure BTEX in the exhaust gas of a Ford Crown Victoria 1995 and compared with a whole gas and direct injection method. PMID:25911428

  12. Quantification of benzene, toluene, ethylbenzene and o-xylene in internal combustion engine exhaust with time-weighted average solid phase microextraction and gas chromatography mass spectrometry.

    PubMed

    Baimatova, Nassiba; Koziel, Jacek A; Kenessov, Bulat

    2015-05-11

    A new and simple method for benzene, toluene, ethylbenzene and o-xylene (BTEX) quantification in vehicle exhaust was developed based on diffusion-controlled extraction onto a retracted solid-phase microextraction (SPME) fiber coating. The rationale was to develop a method based on existing and proven SPME technology that is feasible for field adaptation in developing countries. Passive sampling with SPME fiber retracted into the needle extracted nearly two orders of magnitude less mass (n) compared with exposed fiber (outside of needle) and sampling was in a time weighted-averaging (TWA) mode. Both the sampling time (t) and fiber retraction depth (Z) were adjusted to quantify a wider range of Cgas. Extraction and quantification is conducted in a non-equilibrium mode. Effects of Cgas, t, Z and T were tested. In addition, contribution of n extracted by metallic surfaces of needle assembly without SPME coating was studied. Effects of sample storage time on n loss was studied. Retracted TWA-SPME extractions followed the theoretical model. Extracted n of BTEX was proportional to Cgas, t, Dg, T and inversely proportional to Z. Method detection limits were 1.8, 2.7, 2.1 and 5.2 mg m(-3) (0.51, 0.83, 0.66 and 1.62 ppm) for BTEX, respectively. The contribution of extraction onto metallic surfaces was reproducible and influenced by Cgas and t and less so by T and by the Z. The new method was applied to measure BTEX in the exhaust gas of a Ford Crown Victoria 1995 and compared with a whole gas and direct injection method.

  13. Synergistic effect of Brønsted acid and platinum on purification of automobile exhaust gases.

    PubMed

    Fu, Wei; Li, Xin-Hao; Bao, Hong-Liang; Wang, Kai-Xue; Wei, Xiao; Cai, Yi-Yu; Chen, Jie-Sheng

    2013-01-01

    The catalytic purification of automobile exhaust gases (CO, NOx and hydrocarbons) is one of the most practiced conversion processes used to lower the emissions and to reduce the air pollution. Nevertheless, the good performance of exhaust gas purification catalysts often requires the high consumption of noble metals such as platinum. Here we report that the Brønsted acid sites on the external surface of a microporous silicoaluminophosphate (SAPO) act as a promoter for exhaust gas purification, effectively cutting the loading amount of platinum in the catalyst without sacrifice of performance. It is revealed that in the Pt-loaded SAPO-CHA catalyst, there exists a remarkable synergistic effect between the Brønsted acid sites and the Pt nanoparticles, the former helping to adsorb and activate the hydrocarbon molecules for NO reduction during the catalytic process. The thermal stability of SAPO-CHA also makes the composite catalyst stable and reusable without activity decay. PMID:23907148

  14. Synergistic effect of Brønsted acid and platinum on purification of automobile exhaust gases

    NASA Astrophysics Data System (ADS)

    Fu, Wei; Li, Xin-Hao; Bao, Hong-Liang; Wang, Kai-Xue; Wei, Xiao; Cai, Yi-Yu; Chen, Jie-Sheng

    2013-08-01

    The catalytic purification of automobile exhaust gases (CO, NOx and hydrocarbons) is one of the most practiced conversion processes used to lower the emissions and to reduce the air pollution. Nevertheless, the good performance of exhaust gas purification catalysts often requires the high consumption of noble metals such as platinum. Here we report that the Brønsted acid sites on the external surface of a microporous silicoaluminophosphate (SAPO) act as a promoter for exhaust gas purification, effectively cutting the loading amount of platinum in the catalyst without sacrifice of performance. It is revealed that in the Pt-loaded SAPO-CHA catalyst, there exists a remarkable synergistic effect between the Brønsted acid sites and the Pt nanoparticles, the former helping to adsorb and activate the hydrocarbon molecules for NO reduction during the catalytic process. The thermal stability of SAPO-CHA also makes the composite catalyst stable and reusable without activity decay.

  15. Synergistic effect of Brønsted acid and platinum on purification of automobile exhaust gases.

    PubMed

    Fu, Wei; Li, Xin-Hao; Bao, Hong-Liang; Wang, Kai-Xue; Wei, Xiao; Cai, Yi-Yu; Chen, Jie-Sheng

    2013-01-01

    The catalytic purification of automobile exhaust gases (CO, NOx and hydrocarbons) is one of the most practiced conversion processes used to lower the emissions and to reduce the air pollution. Nevertheless, the good performance of exhaust gas purification catalysts often requires the high consumption of noble metals such as platinum. Here we report that the Brønsted acid sites on the external surface of a microporous silicoaluminophosphate (SAPO) act as a promoter for exhaust gas purification, effectively cutting the loading amount of platinum in the catalyst without sacrifice of performance. It is revealed that in the Pt-loaded SAPO-CHA catalyst, there exists a remarkable synergistic effect between the Brønsted acid sites and the Pt nanoparticles, the former helping to adsorb and activate the hydrocarbon molecules for NO reduction during the catalytic process. The thermal stability of SAPO-CHA also makes the composite catalyst stable and reusable without activity decay.

  16. Synergistic effect of Brønsted acid and platinum on purification of automobile exhaust gases

    PubMed Central

    Fu, Wei; Li, Xin-Hao; Bao, Hong-Liang; Wang, Kai-Xue; Wei, Xiao; Cai, Yi-Yu; Chen, Jie-Sheng

    2013-01-01

    The catalytic purification of automobile exhaust gases (CO, NOx and hydrocarbons) is one of the most practiced conversion processes used to lower the emissions and to reduce the air pollution. Nevertheless, the good performance of exhaust gas purification catalysts often requires the high consumption of noble metals such as platinum. Here we report that the Brønsted acid sites on the external surface of a microporous silicoaluminophosphate (SAPO) act as a promoter for exhaust gas purification, effectively cutting the loading amount of platinum in the catalyst without sacrifice of performance. It is revealed that in the Pt-loaded SAPO-CHA catalyst, there exists a remarkable synergistic effect between the Brønsted acid sites and the Pt nanoparticles, the former helping to adsorb and activate the hydrocarbon molecules for NO reduction during the catalytic process. The thermal stability of SAPO-CHA also makes the composite catalyst stable and reusable without activity decay. PMID:23907148

  17. CRITERIA POLLUTANT EMISSIONS FROM INTERNAL COMBUSTION ENGINES IN THE NATURAL GAS INDUSTRY VOLUME II. APPENDICES A-I

    EPA Science Inventory

    The report summarizes emission factors for criteria pollutants (NOx, CO, CH4, C2H6, THC, NMHC, and NMEHC) from stationary internal combustion engines and gas turbines used in the natural gas industry. The emission factors were calculated from test results from five test campaigns...

  18. Fate of hazardous air pollutants in oxygen-fired coal combustion with different flue gas recycling.

    PubMed

    Zhuang, Ye; Pavlish, John H

    2012-04-17

    Experiments were performed to characterize transformation and speciation of hazardous air pollutants (HAPs), including SO(2)/SO(3), NO(x), HCl, particulate matter, mercury, and other trace elements in oxygen-firing bituminous coal with recirculation flue gas (RFG) from 1) an electrostatic precipitator outlet or 2) a wet scrubber outlet. The experimental results showed that oxycombustion with RFG generated a flue gas with less volume and containing HAPs at higher levels, while the actual emissions of HAPs per unit of energy produced were much less than that of air-blown combustion. NO(x) reduction was achieved in oxycombustion because of the elimination of nitrogen and the destruction of NO in the RFG. The elevated SO(2)/SO(3) in flue gas improved sulfur self-retention. SO(3) vapor could reach its dew point in the flue gas with high moisture, which limits the amount of SO(3) vapor in flue gas and possibly induces material corrosion. Most nonvolatile trace elements were less enriched in fly ash in oxycombustion than air-firing because of lower oxycombustion temperatures occurring in the present study. Meanwhile, Hg and Se were found to be enriched on submicrometer fly ash at higher levels in oxy-firing than in air-blown combustion.

  19. Fate of hazardous air pollutants in oxygen-fired coal combustion with different flue gas recycling.

    PubMed

    Zhuang, Ye; Pavlish, John H

    2012-04-17

    Experiments were performed to characterize transformation and speciation of hazardous air pollutants (HAPs), including SO(2)/SO(3), NO(x), HCl, particulate matter, mercury, and other trace elements in oxygen-firing bituminous coal with recirculation flue gas (RFG) from 1) an electrostatic precipitator outlet or 2) a wet scrubber outlet. The experimental results showed that oxycombustion with RFG generated a flue gas with less volume and containing HAPs at higher levels, while the actual emissions of HAPs per unit of energy produced were much less than that of air-blown combustion. NO(x) reduction was achieved in oxycombustion because of the elimination of nitrogen and the destruction of NO in the RFG. The elevated SO(2)/SO(3) in flue gas improved sulfur self-retention. SO(3) vapor could reach its dew point in the flue gas with high moisture, which limits the amount of SO(3) vapor in flue gas and possibly induces material corrosion. Most nonvolatile trace elements were less enriched in fly ash in oxycombustion than air-firing because of lower oxycombustion temperatures occurring in the present study. Meanwhile, Hg and Se were found to be enriched on submicrometer fly ash at higher levels in oxy-firing than in air-blown combustion. PMID:22439940

  20. Experiences with a new soil gas technique for detecting petroleum pollution

    SciTech Connect

    Mazac, O.; Landa, I.; Rohde, J.R.; Kelly, W.E.; Blaha, J.H.

    1996-12-31

    This paper presents field experiences obtained with a new technology for detecting petroleum pollution in soil and ground water based on in situ determination of hydrocarbon concentrations in soil air. Ecoprobe is a new soil gas device from RS-Dynamics in the Czech Republic. The rugged waterproof device is equipped with a built-in computer-controlled semiconductor sensor. Three case histories are presented that demonstrate the use of the equipment under typical conditions. Two case histories present the use of the device under typical field conditions; the third case history compares results from the Ecoprobe and a commercial photoionization detector (PID) device.

  1. Partially integrated exhaust manifold

    SciTech Connect

    Hayman, Alan W; Baker, Rodney E

    2015-01-20

    A partially integrated manifold assembly is disclosed which improves performance, reduces cost and provides efficient packaging of engine components. The partially integrated manifold assembly includes a first leg extending from a first port and terminating at a mounting flange for an exhaust gas control valve. Multiple additional legs (depending on the total number of cylinders) are integrally formed with the cylinder head assembly and extend from the ports of the associated cylinder and terminate at an exit port flange. These additional legs are longer than the first leg such that the exit port flange is spaced apart from the mounting flange. This configuration provides increased packaging space adjacent the first leg for any valving that may be required to control the direction and destination of exhaust flow in recirculation to an EGR valve or downstream to a catalytic converter.

  2. INCREASED SUSCEPTIBILITY TO INFLUENZA INFECTION AFTER DIESEL EXHAUST EXPOSURE

    EPA Science Inventory

    Inhaled environmental pollutants have a possible role in modulating the susceptibility of humans to respiratory infections. Diesel exhaust (DE) is a major component of urban air pollution and their effects on pulmonary infections is of great concern. Influenza infections cause ...

  3. INCREASED SUSCEPTIBILITY TO INFLUENZA INFECTION AFTER DIESEL EXHAUST EXPOSURE.

    EPA Science Inventory

    Inhaled environmental pollutants have a possible role in modulating the susceptibility of humans to respiratory infections. Diesel exhaust (DE) is a major component of urban air pollution and their effects on pulmonary infections is of great concern. Influenza infections cause ...

  4. Assessing and controlling the effect of aircraft on the environment: Pollution

    NASA Technical Reports Server (NTRS)

    Poppoff, I. G.; Grobman, J. S.

    1975-01-01

    The air pollution created by aircraft engines around airports and the global atmospheric problem of supersonic aircraft operating in the stratosphere are discussed. Methods for assessing the air pollution impact are proposed. The use of atmospheric models to determine the air pollution extent is described. Methods for controlling the emissions of aircraft engines are examined. Diagrams of the atmospheric composition resulting from exhaust gas emissions are developed.

  5. A survey of laser and selected optical systems for remote measurement of pollutant gas concentrations

    NASA Technical Reports Server (NTRS)

    Grant, W. B.; Menzies, R. T.

    1983-01-01

    Applications of the Differential Absorption Lidar (DIAL) technique to the remote sensing of pollutant gases are surveyed. In the DIAl technique, the differential absorption of two laser beams reflected back to a receiver from a target determines the concentration of the gas being studied. The types of instruments available are considered in detail: dye lidar (to measure nitrogen dioxide, sulfur dioxide, and ozone); carbon dioxide laser (for ozone, ethylene, ammonia, and hydrazine), helium-neon laser (for methane); hydrogen fluoride laser (for HF); and tunable diode laser (for nitric oxide and carbon monoxide). DIAL instruments are compared with other optical remote sensors such as Fourier-transform infrared spectrometers, correlation spectrometers (COSPEC and GASPEC), and grating spectrometers; and criteria for the selection of an appropriate gas measuring system are suggested. Laser and other optical remote sensors are found to be cost effective in many cases, despite the fact that they are more costly than point-monitoring systems.

  6. Predictive estimation of upward pollutant migration during shale gas production using satellite image processing

    NASA Astrophysics Data System (ADS)

    Lyalko, Vadim; Azimov, Oleksandr; Yakovlev, Yevgen

    2016-07-01

    The report considers the relevance of the application of modern remote aerospace and hydrogeological methods in the problems of the ecological safety for the hydrosphere during shale gas production in Ukraine. Case studies of pilot implementation of these methods are present for the Bilyaivska area adjacent to the Yuzivka licensed site within the Dnieper-Donets Depression. A number of the hydrogeological filtration parameters and the thematic processing for remote sensing data of the Earth enable to obtain the rough estimate of the temporal indices for the upward pollutant migration from the fracturing zone to the groundwater aquifers in the potential process of shale gas production (as an example the 400-Bilyaivska well). It is found that the possible variety of the active permeability in tectonic zone, which may be predicted by using remote sensing of the Earth image interpretation in vicinity of the well, is responsible for the passage time of pollution from the fracturing zone level to the groundwater aquifers one and this time interval spans 50˜5 years.

  7. Verification of greenhouse gas emission reductions: the prospect of atmospheric monitoring in polluted areas.

    PubMed

    Levin, Ingeborg; Hammer, Samuel; Eichelmann, Elke; Vogel, Felix R

    2011-05-28

    Independent verification of greenhouse gas emissions reporting is a legal requirement of the Kyoto Protocol, which has not yet been fully accomplished. Here, we show that dedicated long-term atmospheric measurements of greenhouse gases, such as carbon dioxide (CO(2)) and methane (CH(4)), continuously conducted at polluted sites can provide the necessary tool for this undertaking. From our measurements at the semi-polluted Heidelberg site in the upper Rhine Valley, we find that in the catchment area CH(4) emissions decreased on average by 32±6% from the second half of the 1990s until the first half of the 2000s, but the observed long-term trend of emissions is considerably smaller than that previously reported for southwest Germany. In contrast, regional fossil fuel CO(2) levels, estimated from high-precision (14)CO(2) observations, do not show any significant decreasing trend since 1986, in agreement with the reported emissions for this region. In order to provide accurate verification, these regional measurements would best be accompanied by adequate atmospheric transport modelling as required to precisely determine the relevant catchment area of the measurements. Furthermore, reliable reconciliation of reported emissions will only be possible if these are known at high spatial resolution in the catchment area of the observations. This information should principally be available in all countries that regularly report their greenhouse gas emissions to the United Nations Framework Convention on Climate Change.

  8. Curbing Air Pollution and Greenhouse Gas Emissions from Industrial Boilers in China

    SciTech Connect

    Shen, Bo; Price, Lynn K; Lu, Hongyou; Liu, Xu; Tsen, Katherine; Xiangyang, Wei; Yunpeng, Zhang; Jian, Guan; Rui, Hou; Junfeng, Zhang; Yuqun, Zhuo; Shumao, Xia; Yafeng, Han; Manzhi, Liu

    2015-10-28

    China’s industrial boiler systems consume 700 million tons of coal annually, accounting for 18% of the nation’s total coal consumption. Together these boiler systems are one of the major sources of China’s greenhouse gas (GHG) emissions, producing approximately 1.3 gigatons (Gt) of carbon dioxide (CO2) annually. These boiler systems are also responsible for 33% and 27% of total soot and sulfur dioxide (SO2) emissions in China, respectively, making a substantial contribution to China’s local environmental degradation. The Chinese government - at both the national and local level - is taking actions to mitigate the significant greenhouse gas (GHG) emissions and air pollution related to the country’s extensive use of coal-fired industrial boilers. The United States and China are pursuing a collaborative effort under the U.S.-China Climate Change Working Group to conduct a comprehensive assessment of China’s coal-fired industrial boilers and to develop an implementation roadmap that will improve industrial boiler efficiency and maximize fuel-switching opportunities. Two Chinese cities – Ningbo and Xi’an – have been selected for the assessment. These cities represent coastal areas with access to liquefied natural gas (LNG) imports and inland regions with access to interprovincial natural gas pipelines, respectively.

  9. Numerical methods for assessment of the ship's pollutant emissions

    NASA Astrophysics Data System (ADS)

    Jenaru, A.; Acomi, N.

    2016-08-01

    The maritime transportation sector constitutes a source of atmospheric pollution. To avoid or minimize ships pollutant emissions the first step is to assess them. Two methods of estimation of the ships’ emissions are proposed in this paper. These methods prove their utility for shipboard and shore based management personnel from the practical perspective. The methods were demonstrated for a product tanker vessel where a permanent monitoring system for the pollutant emissions has previously been fitted. The values of the polluting agents from the exhaust gas were determined for the ship from the shipyard delivery and were used as starting point. Based on these values, the paper aimed at numerical assessing of ship's emissions in order to determine the ways for avoiding environmental pollution: the analytical method of determining the concentrations of the exhaust gas components, by using computation program MathCAD, and the graphical method of determining the concentrations of the exhaust gas components, using variation diagrams of the parameters, where the results of the on board measurements were introduced, following the application of pertinent correction factors. The results should be regarded as a supporting tool during the decision making process linked to the reduction of ship's pollutant emissions.

  10. Satellite observation of pollutant emissions from gas flaring activities near the Arctic

    NASA Astrophysics Data System (ADS)

    Li, Can; Hsu, N. Christina; Sayer, Andrew M.; Krotkov, Nickolay A.; Fu, Joshua S.; Lamsal, Lok N.; Lee, Jaehwa; Tsay, Si-Chee

    2016-05-01

    Gas flaring is a common practice in the oil industry that can have significant environmental impacts, but has until recently been largely overlooked in terms of relevance to climate change. We utilize data from various satellite sensors to examine pollutant emissions from oil exploitation activities in four areas near the Arctic. Despite the remoteness of these sparsely populated areas, tropospheric NO2 retrieved from the Ozone Monitoring Instrument (OMI) is substantial at ˜1 × 1015 molecules cm-2, suggesting sizeable emissions from these industrial activities. Statistically significant (at the 95% confidence level, corresponding uncertainties in parentheses) increasing trends of 0.017 (±0.01) × 1015 and 0.015 (±0.006) × 1015 molecules cm-2 year-1 over 2004-2015 were found for Bakken (USA) and Athabasca (Canada), two areas having recently experienced fast expansion in the oil industry. This rapid change has implications for emission inventories, which are updated less frequently. No significant trend was found for the North Sea (Europe), where oil production has been declining since the 1990s. For northern Russia, the trend was just under the 95% significance threshold at 0.0057 (±0.006) × 1015 molecules cm-2 year-1. This raises an interesting inconsistency as prior studies have suggested that, in contrast to the continued, albeit slow, expansion of Russian oil/gas production, gas flaring in Russia has decreased in recent years. However, only a fraction of oil fields in Russia were covered in our analysis. Satellite aerosol optical depth (AOD) data revealed similar tendencies, albeit at a weaker level of statistical significance, due to the longer lifetime of aerosols and contributions from other sources. This study demonstrates that synergetic use of data from multiple satellite sensors can provide valuable information on pollutant emission sources that is otherwise difficult to acquire.

  11. Remote sensing of temperature and concentration profiles of a gas jet by coupling infrared emission spectroscopy and LIDAR for characterization of aircraft engine exhaust

    NASA Astrophysics Data System (ADS)

    Offret, J.-P.; Lebedinsky, J.; Navello, L.; Pina, V.; Serio, B.; Bailly, Y.; Hervé, P.

    2015-05-01

    Temperature data play an important role in the combustion chamber since it determines both the efficiency and the rate of pollutants emission of engines. Air pollution problem concerns the emissions of gases such as CO, CO2, NO, NO2, SO2 and also aerosols, soot and volatile organic compounds. Flame combustion occurs in hostile environments where temperature and concentration profiles are often not easy to measure. In this study, a temperature and CO2 concentration profiles optical measurement method, suitable for combustion analysis, is discussed and presented. The proposed optical metrology method presents numerous advantages when compared to intrusive methods. The experimental setup comprises a passive radiative emission measurement method combined with an active laser-measurement method. The passive method is based on the use of gas emission spectroscopy. The experimental spectrometer device is coupled with an active method. The active method is used to investigate and correct complex flame profiles. This method similar to a LIDAR (Light Detection And Ranging) device is based on the measurement of Rayleigh scattering of a short laser pulse recorded using a high-speed streak camera. The whole experimental system of this new method is presented. Results obtained on a small-scale turbojet are shown and discussed in order to illustrate the potentials deliver by the sophisticated method. Both temperature and concentration profiles of the gas jet are presented and discussed.

  12. Comment on 'Experimental observation of carbon dioxide reduction in exhaust gas from hydrocarbon fuel burning' [Phys. Plasmas 16, 114502 (2009)

    SciTech Connect

    Byun, Youngchul; Shin, Dong Nam

    2010-01-15

    The following comments are intended to clarify whether it is possible to convert CO{sub 2} into C+O{sub 2} by supplying just one-twentieth of energy required thermodynamically, only under the condition that the negative high voltage of dc is applied to the gas stream perpendicularly, in a recent article by Uhm and Kim [H. S. Uhm and C. H. Kim, Phys. Plasmas 16, 114502 (2009)]. Of particular concern is the disobedience of the first and second laws of thermodynamics together with the indistinct measurement of experimental data.

  13. Characteristics of pollutant gas releases from swine, dairy, beef, and layer manure, and municipal wastewater.

    PubMed

    Dai, Xiao-Rong; Saha, Chayan Kumer; Ni, Ji-Qin; Heber, Albert J; Blanes-Vidal, Victoria; Dunn, James L

    2015-06-01

    Knowledge about characteristics of gas releases from various types of organic wastes can assist in developing gas pollution reduction technologies and establishing environmental regulations. Five different organic wastes, i.e., four types of animal manure (swine, beef, dairy, and layer hen) and municipal wastewater, were studied for their characteristics of ammonia (NH3), carbon dioxide (CO2), hydrogen sulfide (H2S), and sulfur dioxide (SO2) releases for 38 or 43 days in reactors under laboratory conditions. Weekly waste additions and continuous reactor headspace ventilation were supplied to simulate waste storage conditions. Results demonstrated that among the five waste types, layer hen manure and municipal wastewater had the highest and lowest NH3 release potentials, respectively. Layer manure had the highest and dairy manure had the lowest CO2 release potentials. Dairy manure and layer manure had the highest and lowest H2S release potentials, respectively. Beef manure and layer manure had the highest and lowest SO2 releases, respectively. The physicochemical characteristics of the different types of wastes, especially the total nitrogen, total ammoniacal nitrogen, dry matter, and pH, had strong influence on the releases of the four gases. Even for the same type of waste, the variation in physicochemical characteristics affected the gas releases remarkably. PMID:25794466

  14. Anti-air pollution & energy conservation system for automobiles using leaded or unleaded gasoline, diesel or alternate fuel

    DOEpatents

    Bose, Ranendra K.

    2002-06-04

    Exhaust gases from an internal combustion engine operating with leaded or unleaded gasoline or diesel or natural gas, are used for energizing a high-speed gas turbine. The convoluting gas discharge causes a first separation stage by stratifying of heavier and lighter exhaust gas components that exit from the turbine in opposite directions, the heavier components having a second stratifying separation in a vortex tube to separate combustible pollutants from non-combustible components. The non-combustible components exit a vortex tube open end to atmosphere. The lighter combustible, pollutants effected in the first separation are bubbled through a sodium hydroxide solution for dissolving the nitric oxide, formaldehyde impurities in this gas stream before being piped to the engine air intake for re-combustion, thereby reducing the engine's exhaust pollution and improving its fuel economy. The combustible, heavier pollutants from the second separation stage are piped to air filter assemblies. This gas stream convoluting at a high-speed through the top stator-vanes of the air filters, centrifugally separates the coalescent water, aldehydes, nitrogen dioxides, sulfates, sulfur, lead particles which collect at the bottom of the bowl, wherein it is periodically released to the roadway. Whereas, the heavier hydrocarbon, carbon particles are piped through the air filter's porous element to the engine air intake for re-combustion, further reducing the engine's exhaust pollution and improving its fuel economy.

  15. METHODOLOGIES FOR QUANTIFYING POLLUTION PREVENTION BENEFITS FROM LANDFILL GAS CONTROL AND UTILIZATION

    EPA Science Inventory

    The report describes developing emission factors for controlled primary pollutants (e.g., nonmethane organic compounds) and secondary air pollutants (e.g., carbon monoxide). The report addresses the following criteria air pollutants and greenhouse gases: carbon dioxide, carbon mo...

  16. Comparative evaluation of the impacts of domestic gas and electric heat pump heating on air pollution in California

    SciTech Connect

    Ganji, A. . Div. of Engineering)

    1992-07-01

    Residential space and water heating accounts for approximately 12% of California's and 15% of the United States, energy consumption. most Of the residential heating is by direct use of natural gas. combustion of natural gas is a contributor to the overall air pollution,, especially CO and NO{sub x} in the urban areas. Another efficient method for domestic water and space heating is use of electric heat pumps, the most popular category of which uses air as its heat source. Electric heat pumps do not emit air pollutants at the point of use, but use electric power, which is a major contributor to air pollution at its point of generation from fossil fuels. It is the specific objective of this report to evaluate and compare the energy efficiency and source air pollutants of natural gas heaters and electric heat pumps used for domestic heating. Effect of replacing natural gas heaters with electric heat pumps on air pollutant emissions due to domestic heating in two urban areas and in California as a whole has also been evaluated. The analysis shows that with the present state of technology, electric heat pumps have higher heating efficiencies than natural gas heaters. Considering the current electricity generation mix in the US, electric heat pumps produce two to four times more NO{sub x}, much less CO, and comparable amount of CO{sub 2} per unit of useful heating energy compared to natural gas heaters. With California mix, electric heat pumps produce comparable NO{sub x} and much less CO and approximately 30% less CO{sub 2} per unit heat output. Replacement of natural gas heaters with electric heat pumps will slightly increase the overall NO{sub x}, and reduce CO and CO{sub 2} emissions in California. The effect of advanced technology power generation and heat pump heating has also been analyzed.

  17. Comparative evaluation of the impacts of domestic gas and electric heat pump heating on air pollution in California. Final report

    SciTech Connect

    Ganji, A.

    1992-07-01

    Residential space and water heating accounts for approximately 12% of California`s and 15% of the United States, energy consumption. most Of the residential heating is by direct use of natural gas. combustion of natural gas is a contributor to the overall air pollution,, especially CO and NO{sub x} in the urban areas. Another efficient method for domestic water and space heating is use of electric heat pumps, the most popular category of which uses air as its heat source. Electric heat pumps do not emit air pollutants at the point of use, but use electric power, which is a major contributor to air pollution at its point of generation from fossil fuels. It is the specific objective of this report to evaluate and compare the energy efficiency and source air pollutants of natural gas heaters and electric heat pumps used for domestic heating. Effect of replacing natural gas heaters with electric heat pumps on air pollutant emissions due to domestic heating in two urban areas and in California as a whole has also been evaluated. The analysis shows that with the present state of technology, electric heat pumps have higher heating efficiencies than natural gas heaters. Considering the current electricity generation mix in the US, electric heat pumps produce two to four times more NO{sub x}, much less CO, and comparable amount of CO{sub 2} per unit of useful heating energy compared to natural gas heaters. With California mix, electric heat pumps produce comparable NO{sub x} and much less CO and approximately 30% less CO{sub 2} per unit heat output. Replacement of natural gas heaters with electric heat pumps will slightly increase the overall NO{sub x}, and reduce CO and CO{sub 2} emissions in California. The effect of advanced technology power generation and heat pump heating has also been analyzed.

  18. Design of a high temperature chemical vapor deposition reactor in which the effect of the condensation of exhaust gas in the outlet is minimized using computational modeling

    NASA Astrophysics Data System (ADS)

    Yoon, Ji-Young; Geun Kim, Byeong; Nam, Deok-Hui; Yoo, Chang-Hyoung; Lee, Myung-Hyun; Seo, Won-Seon; Shul, Yong-Gun; Lee, Won-Jae; Jeong, Seong-Min

    2016-02-01

    Tetramethylsilane (TMS) was recently proposed as a safe precursor for SiC single crystal growth through high temperature chemical vapor deposition (HTCVD). Because the C content of TMS is much higher than Si, the exhaust gas from the TMS-based HTCVD contains large amounts of C which is condensed in the outlet. Because the condensed C close to the crystal growth front will influence on the thermodynamic equilibrium in the crystal growth, an optimal reactor design was highly required to exclude the effect of the condensed carbon. In this study, we report on a mass/heat transfer analysis using the finite element method (FEM) in an attempt to design an effective reactor that will minimize the effect of carbon condensation in the outlet. By applying the proposed reactor design to actual growth experiments, single 6H-SiC crystals with diameters of 50 mm were successfully grown from a 6H-SiC seed. This result confirms that the proposed reactor design can be used to effectively grow 6H-SiC crystals using TMS-based HTCVD.

  19. [Experimental research of oil vapor pollution control for gas station with membrane separation technology].

    PubMed

    Zhu, Ling; Chen, Jia-Qing; Zhang, Bao-Sheng; Wang, Jian-Hong

    2011-12-01

    Two kinds of membranes modules, vapor retained glassy membrane based on PEEK hollow fiber membrane modules and vapor permeated rubbery membrane system based on GMT plate-and-frame membrane modules, were used to control the oil vapor pollution during the course of receiving and transferring gasoline in oil station. The efficiencies of the membrane module and the membrane system of them were evaluated and compared respectively in the facilities which were developed by ourselves. It was found that both the two kinds of membranes modules had high efficiency for the separation of VOCs-air mixed gases, and the outlet vapor after treatment all can meet the national standard. When the vapor-enriched gas was returned to the oil tank to simulate the continuously cycle test, the concentration of VOCs in the outlet was also below 25 g x m(-3).

  20. [Experimental research of oil vapor pollution control for gas station with membrane separation technology].

    PubMed

    Zhu, Ling; Chen, Jia-Qing; Zhang, Bao-Sheng; Wang, Jian-Hong

    2011-12-01

    Two kinds of membranes modules, vapor retained glassy membrane based on PEEK hollow fiber membrane modules and vapor permeated rubbery membrane system based on GMT plate-and-frame membrane modules, were used to control the oil vapor pollution during the course of receiving and transferring gasoline in oil station. The efficiencies of the membrane module and the membrane system of them were evaluated and compared respectively in the facilities which were developed by ourselves. It was found that both the two kinds of membranes modules had high efficiency for the separation of VOCs-air mixed gases, and the outlet vapor after treatment all can meet the national standard. When the vapor-enriched gas was returned to the oil tank to simulate the continuously cycle test, the concentration of VOCs in the outlet was also below 25 g x m(-3). PMID:22468544

  1. Reduction of gaseous pollutant emissions from gas turbine combustors using hydrogen-enriched jet fuel

    NASA Technical Reports Server (NTRS)

    Clayton, R. M.

    1976-01-01

    Recent progress in an evaluation of the applicability of the hydrogen enrichment concept to achieve ultralow gaseous pollutant emission from gas turbine combustion systems is described. The target emission indexes for the program are 1.0 for oxides of nitrogen and carbon monoxide, and 0.5 for unburned hydrocarbons. The basic concept utilizes premixed molecular hydrogen, conventional jet fuel, and air to depress the lean flammability limit of the mixed fuel. This is shown to permit very lean combustion with its low NOx production while simulataneously providing an increased flame stability margin with which to maintain low CO and HC emission. Experimental emission characteristics and selected analytical results are presented for a cylindrical research combustor designed for operation with inlet-air state conditions typical for a 30:1 compression ratio, high bypass ratio, turbofan commercial engine.

  2. Active differential optical absorption spectroscopy for NO2 gas pollution using blue light emitting diodes

    NASA Astrophysics Data System (ADS)

    Aljalal, Abdulaziz; Gasmi, Khaled; Al-Basheer, Watheq

    2015-05-01

    Availability of high intensity light emitting diodes in the blue region offer excellent opportunity for using them in active Differential Optical Absorption Spectroscopy (DOAS) to detect air pollution. Their smooth and relatively broad spectral emissions as well as their long life make them almost ideal light sources for active DOAS. In this study, we report the usage of a blue light emitting diode in an active DOAS setup to measure traces of NO2 gas and achieving few parts per billion detection limit for a path length of 300 m. Details of the setup will be presented along with the effects on measurement accuracy due to shifts in the measured spectra calibration and due to using theoretical instrument Gaussian function instead of the measured instrument function.

  3. Measurement comparison of gas phase pollutants during field campaign in Pearl River Delta, China

    NASA Astrophysics Data System (ADS)

    Shao, M.; Zeng, L.; Hu, M.; Zhang, Y.

    2005-12-01

    Pearl River delta, an economically developed region in Guangdong province China, has been suffering from serious ground-level ozone pollution. To understand the formation mechanisms of the photochemical smog in this area, a field measurement campaign involving 12 separate institutes, was performed from Oct. 1 to Nov. 4, 2004. Measurements of gas phase pollutants, performed by the different research groups using several different methods, were inter-compared. Ambient SO2, O3 and NO were measured by Peking University and Hong Kong Polytechnic University using the same methods: chemiluminescence for NOx, pulsed fluorescence for SO2, and UV photometric method for O3. VOC speciation was accomplished using canister sampling followed by GC-MS measurement by Peking University and on-line GC-FID technology by National Central University in Taiwan. Ambient concentrations of HONO, the photolysis of which is the most important source of OH radical in Pearl River delta, was measured by two wet chemical methods: one from Energy Research Foundation of the Netherlands and one developed in Peking University. Based on these inter-comparisons, the co-variation of O3, NO and VOCs at an urban site and one rural site in Pearl River delta and estimates of the relative contributions to OH production from photolysis of O3, HONO and HCHO will be presented.

  4. Ecotoxicological assessment of soils of former manufactured gas plant sites: Bioremediation potential and pollutant mobility

    SciTech Connect

    Haeseler, F.; Blanchet, D.; Druelle, V.; Werner, P.; Vandecasteele, J.P.

    1999-12-15

    Analytically well-characterized soils from four different former manufactured gas plants (MGP) sites contaminated by coal tars were used in tests of extensive biodegradation of polycyclic aromatic hydrocarbons (PAHs) in stirred reactors. In all cases, the extent of biodegradation was limited to 80--100% for 2- and 3-ring PAHs, 40--70% for 4-ring PAHs, and below 20% for 5- and 6-ring PAHs. The capacities to transfer pollutants to water were compared for leachates from soils that had or had not undergone biological treatment. Leachate analysis involved determination of PAHs and bacterial tests of acute toxicity (Microtox) and genotoxicity (SOS Chromotest). For some untreated soils, PAH leaching was observed, and positive responses to the Microtox test were well correlated to the concentrations of naphthalene and phenanthrene. Biologically treated soils had lost all capacities for leaching as concluded from PAH determinations and responses to the Microtox test. All soil leachates were devoid of genotoxic effect, in accordance with the low concentrations observed of mutagenic PAHs. The results of this risk-based approach for assessment of MGP soils showed that pollutants remaining after biological treatment were unavailable for further biodegradation and that the extent of leaching had been reduced to the level that it did not represent a significant threat to groundwater.

  5. Design and Performance of a Gas Chromatograph for Automatic Monitoring of Pollutants in Ambient Air

    NASA Technical Reports Server (NTRS)

    Villalobos, R.; Stevens, D.; LeBlanc, R.; Braun, L.

    1971-01-01

    In recent years, interest in air pollution constituents has focused on carbon monoxide and hydrocarbons as prime components of polluted air. Instrumental methods have been developed, and commercial instruments for continuous monitoring of these components have been available for a number of years. For the measurement of carbon monoxide, non-dispersive infrared spectroscopy has been the accepted tool, in spite of its marginal sensitivity at low parts-per-million levels. For continuously monitoring total hydrocarbons, the hydrogen flame ionization analyzer has been widely accepted as the preferred method. The inadequacy of this latter method became evident when it was concluded that methane is non-reactive and cannot be considered a contaminant even though present at over 1 ppm in the earth's atmosphere. Hence, the need for measuring methane separately became apparent as a means of measuring the reactive and potentially harmful non-methane hydrocarbons fraction. A gas chromatographic method for the measurement of methane and total hydrocarbons which met these requirements has been developed. In this technique, methane was separated on conventional gas chromatographic columns and detected by a hydrogen flame ionization detector (FID) while the total hydrocarbons were obtained by introducing a second sample directly into the FID without separating the various components. The reactive, or non-methane hydrocarbons, were determined by difference. Carbon monoxide was also measured after converting to methane over a heated catalyst to render it detectable by the FID. The development of this method made it possible to perform these measurements with a sensitivity of as much as 1 ppm full scale and a minimum detectability of 20 ppb. Incorporating this technique, criteria were developed by APCO for a second generation continuous automatic instrument for atmospheric monitoring stations.

  6. 40 CFR 86.1310-2007 - Exhaust gas sampling and analytical system for gaseous emissions from heavy-duty diesel-fueled...

    Code of Federal Regulations, 2010 CFR

    2010-07-01

    ... system must provide sufficient secondary dilution air to maintain the double-diluted exhaust stream at a... subtracted from the values measured in the diluted exhaust stream. In the case of primary dilution air, the... stream and the transfer tube wall should be minimized). Double-wall, thin-wall, air-gap insulated, or...

  7. 40 CFR 86.1310-2007 - Exhaust gas sampling and analytical system for gaseous emissions from heavy-duty diesel-fueled...

    Code of Federal Regulations, 2011 CFR

    2011-07-01

    ... system must provide sufficient secondary dilution air to maintain the double-diluted exhaust stream at a... subtracted from the values measured in the diluted exhaust stream. In the case of primary dilution air, the... stream and the transfer tube wall should be minimized). Double-wall, thin-wall, air-gap insulated, or...

  8. An investigation of the effects of smoke suppressant fuel additives on engine and test cell exhaust gas opacities. Final report for 1981

    SciTech Connect

    Thornburg, D.W.; Darnell, T.R.; Netzer, D.W.

    1982-05-01

    Tests were conducted in a one-eighth scale turbojet test cell with a ramjet type combustor to investigate the effects of fuel additives on smoke reduction. Particle size and mass concentrations were determined at the engine and stack exhausts using three wavelength optical detector systems. Particulate samples were also collected at the engine exhaust and analyzed with a scanning electron microscope. Combustor temperature and fuel additives were found to significantly affect particulate mass concentrations emitted from the engine while particle size appeared to be unaffected. No significant changes in the particulate size or mass occurred from the engine exhaust to the stack exhaust. The optical determination of exhaust mean particulate size/mass concentration with three wavelength optical detector systems appears to be reasonably accurate technique for evaluating the effects of engine and test cell operating conditions and fuel composition changes on the emitted particulates.

  9. Gas sampling method for determining pollutant concentrations in the flame zone of two swirl-can combustor modules

    NASA Technical Reports Server (NTRS)

    Duerr, R. A.

    1975-01-01

    A gas sampling probe and traversing mechanism were developed to obtain detailed measurements of gaseous pollutant concentrations in the primary and mixing regions of combustors in order to better understand how pollutants are formed. The gas sampling probe was actuated by a three-degree-of-freedom traversing mechanism and the samples obtained were analyzed by an on-line gas analysis system. The pollutants in the flame zone of two different swirl-can combustor modules were measured at an inlet-air temperature of 590 K, pressure of 6 atmospheres, and reference velocities of 23 and 30 meters per second at a fuel-air ratio of 0.02. Typical results show large spatial gradients in the gaseous pollutant concentration close to the swirl-can module. Average concentrations of unburned hydrocarbons and carbon monoxide decrease rapidly in the downstream wake regions of each module. By careful and detailed probing, the effect of various module design features on pollutant formation can be assessed. The techniques presently developed seem adequate to obtain the desired information.

  10. Experimental Study on In-situ Concentration Monitoring of Flue Gas from the Fixed Pollution Source Based on DOAS

    NASA Astrophysics Data System (ADS)

    Tang, Guanghua; Xu, Chuanlong; Wang, Shimin

    2007-06-01

    The air pollution is mainly derived from the flue gas from fixed pollution source and there has been no appropriate method to measure the concentration of flue gas in bad conditions for a long time. Based on the differential optical absorption spectroscopy (DAOS), an improved inversion algorithm, which is applied to the measurement of flue gas concentration at normal temperature and pressure, is put forward according to the characteristics of the flue gas from fixed pollution source and the experimental study of gas concentration measurement is performed combining the continuous transmittance spectrum from ultraviolet to visible region presented by avantes-2048 spectrometer with the absorption cross sections of sulfur dioxide and nitrogen dioxide derived form the experiment. Research results are shown the algorithm can not only be utilized to measure the concentration of sulfur dioxide with the interference of nitrogen dioxide but also be applied to simultaneously measure the concentration of sulfur dioxide and nitrogen dioxide in flue gas containing dust particles of high concentration.

  11. Seasonal characteristics of gas-phase air pollutants: implications for public health in northeastern New Jersey

    NASA Astrophysics Data System (ADS)

    Roberts-Semple, D. A.; Gao, Y.

    2011-12-01

    To characterize the impact of urban air pollution and local weather conditions on human health, the ambient air concentrations of nitrogen oxide (NOx) and ground-level ozone (O3) were measured at the Meadowlands in Lyndhurst, NJ (41N, 74W) from June 1, 2007 to May 31, 2008. Meteorological data, mainly temperature, wind speed, relative humidity and barometric pressure, were supplemented with data from Weather Underground. Public health data were obtained from the New Jersey Department of Health and Senior Services (NJDHSS). The relationship between gas-phase pollutants and hospital admissions were examined through path analytic models by using multiple regressions and bivariate correlations. The meteorological conditions and air pollutants that may be associated with human respiratory health effects are analyzed. Preliminary results demonstrate that the ambient levels of NOx and O3 are influenced by certain meteorological conditions in the Meadowlands, and that there is a strong relationship between hospital admission and personal exposure to NO2 over the short-term. There is no direct relationship between O3 and hospital admission (r=-0.092), whereas hospital admission and NOx correlate (r=0.317) but more significantly with NO2 (r=.359) at a significance level of 0.01. Hospital admission rates are indirectly affected by humidity (r=-0.077). The seasonal dependence of pollutants is caused mainly by low wind speed and differences in chemical processing, making them interdependent. The monthly average O3 ranged from 11.1ppb to 36.2ppb with the highest values in summer; NOx ranged from 17.0ppb to 29.0ppb with no marked seasonal variations and were lower on weekends than on week days. There were dissimilar diurnal patterns and an inverse relationship between the hourly average of NOx and O3 concentrations, suggesting that O3 formation was not limited by the availability of NOx but is likely influenced by a VOC-sensitive chemical regime. This study provides a basis for

  12. Effect of flame stabilizer design on performance and exhaust pollutants of a two-row 72-module swirl-can combustor

    NASA Technical Reports Server (NTRS)

    Biaglow, J. A.; Trout, A. M.

    1976-01-01

    A test program was conducted to evaluate the effects of four flame stabilizer designs on the performance and gaseous pollutant levels of an experimental full-annular swirl-can combustor. Combustor operating parameters, including inlet-air temperature, reference velocity, and fuel-air ratio, were set to simulate conditions in a 30:1 pressure ratio engine. Combustor inlet total pressure was held constant at 6 atm due to the facility limit. Combustor performance and gaseous pollutant levels were strongly affected by the geometry and resulting total pressure loss of the four flame stabilizer designs investigated. The addition of shrouds to two designs produced an 18 to 22% decrease in the combustion chamber pressure loss and thus resulted in doubling the exit temperature pattern factor and up to 42% higher levels of oxides of nitrogen. A previously developed oxides of nitrogen correlating parameter agreed with each model within an emission index of plus or minus 1 but was not capable of correlating all models together.

  13. Fast automotive diesel exhaust measurement using quantum cascade lasers

    NASA Astrophysics Data System (ADS)

    Herbst, J.; Brunner, R.; Lambrecht, A.

    2013-12-01

    Step by step, US and European legislations enforce the further reduction of atmospheric pollution caused by automotive exhaust emissions. This is pushing automotive development worldwide. Fuel efficient diesel engines with SCRtechnology can impede NO2-emission by reduction with NH3 down to the ppm range. To meet the very low emission limits of the Euro6 resp. US NLEV (National Low Emission Vehicle) regulations, automotive manufacturers have to optimize continuously all phases of engine operation and corresponding catalytic converters. Especially nonstationary operation holds a high potential for optimizing gasoline consumption and further reducing of pollutant emissions. Test equipment has to cope with demanding sensitivity and speed requirements. In the past Fraunhofer IPM has developed a fast emission analyzer called DEGAS (Dynamic Exhaust Gas Analyzer System), based on cryogenically cooled lead salt lasers. These systems have been used at Volkswagen AG`s test benches for a decade. Recently, IPM has developed DEGAS-Next which is based on cw quantum cascade lasers and thermoelectrically cooled detectors. The system is capable to measure three gas components (i.e. NO, NO2, NH3) in two channels with a time resolution of 20 ms and 1 ppm detection limits. We shall present test data and a comparison with fast FTIR measurements.

  14. Greenhouse gas emission and groundwater pollution potential of soils amended with raw swine manure, dry and wet pyrolyzed swine biochars

    Technology Transfer Automated Retrieval System (TEKTRAN)

    The objective of this research is to study the greenhouse gas emission and groundwater pollution potentials of the soils amended with raw swine solid and swine biochars made from different thermochemical conditions. Triplicate sets of small pots were designed: 1) control soil with a 50/50 mixture of...

  15. Water pollution risk associated with natural gas extraction from the Marcellus Shale.

    PubMed

    Rozell, Daniel J; Reaven, Sheldon J

    2012-08-01

    In recent years, shale gas formations have become economically viable through the use of horizontal drilling and hydraulic fracturing. These techniques carry potential environmental risk due to their high water use and substantial risk for water pollution. Using probability bounds analysis, we assessed the likelihood of water contamination from natural gas extraction in the Marcellus Shale. Probability bounds analysis is well suited when data are sparse and parameters highly uncertain. The study model identified five pathways of water contamination: transportation spills, well casing leaks, leaks through fractured rock, drilling site discharge, and wastewater disposal. Probability boxes were generated for each pathway. The potential contamination risk and epistemic uncertainty associated with hydraulic fracturing wastewater disposal was several orders of magnitude larger than the other pathways. Even in a best-case scenario, it was very likely that an individual well would release at least 200 m³ of contaminated fluids. Because the total number of wells in the Marcellus Shale region could range into the tens of thousands, this substantial potential risk suggested that additional steps be taken to reduce the potential for contaminated fluid leaks. To reduce the considerable epistemic uncertainty, more data should be collected on the ability of industrial and municipal wastewater treatment facilities to remove contaminants from used hydraulic fracturing fluid.

  16. Exhaust catalyst selection for small two-stroke engines

    SciTech Connect

    Prigent, M.; Castagna, F.; Durand, D.

    1995-12-31

    A laboratory test has been used to evaluate the behavior of different oxidation catalyst formulations for conventional two-stroke engines. The test gas composition was as close as possible to the real exhaust gas composition with respect to its hydrocarbon and oxygen contents. Small size catalyst samples were located inside a quartz tube and heated by an electric furnace. Several wash-coat types and noble metal formulations applied on metallic substrates were compared. Determinations included light-off temperature and pollutant conversion rates. It was generally observed that the most active catalysts for hydrocarbon elimination produced the highest amount of CO at temperatures between 350 and 500 C. This was due to the substoichiometric oxygen content of the simulated exhaust gas. Some tests were then performed to evaluate the possibility of converting the CO produced, back to CO{sub 2} and H{sub 2}, by the water gas-shift reaction. CO conversion rates were determined using two different catalysts in series, with the second being at a lower temperature than the first one. Several formulations were compared for the second catalyst bed with an offset of temperature between the two beds of about 300 C.

  17. Evaluating the potential of CNT-supported Co catalyst used for gas pollution removal in the incineration flue gas.

    PubMed

    Lu, Chi-Yuan; Tseng, Hui-Hsin; Wey, Ming-Yen; Chuang, Kui-Hao; Kuo, Jia-Hong

    2009-04-01

    This study investigated the use of Cu/Al(2)O(3), Co/Al(2)O(3), Fe/Al(2)O(3), and Ni/Al(2)O(3) catalysts for the growth of carbon nanotubes (CNTs). These CNTs were used as support for Co catalyst preparation and Co/CNT catalysts were applied to a catalytic reaction to remove BTEX, PAHs, SO(2), NO, and CO simultaneously in a pilot-scale incineration system. The analyzed results of EDS and XRD showed low metal content and good dispersion characteristics of the Al(2)O(3)-supported catalysts by excess-solution impregnation. FESEM analyzed results showed that the CNTs that were synthesized from Co, Fe, and Ni catalysts had a diameter of 20nm, whereas those synthesized from Cu/Al(2)O(3) had a diameter of 50nm. Pilot-scale test results demonstrated that the Co/CNT catalyst effectively removed air pollutants in the catalytic reaction and that there was no obvious deactivation by Pb, water vapor, and coke deposited in the process. The thermal stabilization at 250 degrees C and hydrophobicity properties of CNTs enhanced the application of CNT catalysts in flue gas.

  18. CONTROL OF POLLUTANT EMISSIONS IN NATURAL GAS DIFFUSION FLAMES BY USING CASCADE BURNERS

    SciTech Connect

    Dr. Ala Qubbaj

    2001-12-30

    The goal of this exploratory research project is to control the pollutant emissions of diffusion flames by modifying the air infusion rate into the flame. The modification was achieved by installing a cascade of venturis around the burning gas jet. The basic idea behind this technique is controlling the stoichiometry of the flame through changing the flow dynamics and rates of mixing in the combustion zone with a set of venturis surrounding the flame. A natural gas jet diffusion flame at burner-exit Reynolds number of 5100 was examined with a set of venturis of specific sizes and spacing arrangement. The thermal and composition fields of the baseline and venturi-cascaded flames were numerically simulated using CFD-ACE+, an advanced computational environment software package. The instantaneous chemistry model was used as the reaction model. The concentration of NO was determined through CFD-POST, a post processing utility program for CFD-ACE+. The numerical results showed that, in the near-burner, midflame and far-burner regions, the venturi-cascaded flame had lower temperature by an average of 13%, 19% and 17%, respectively, and lower CO{sub 2} concentration by 35%, 37% and 32%, respectively, than the baseline flame. An opposite trend was noticed for O{sub 2} concentration; the cascaded flame has higher O{sub 2} concentration by 7%, 26% and 44%, in average values, in the near-burner, mid-flame and far-burner regions, respectively, than in the baseline case. The results also showed that, in the near-burner, mid-flame, and far-burner regions, the venturi-cascaded flame has lower NO concentrations by 89%, 70% and 70%, in average values, respectively, compared to the baseline case. The numerical results substantiate that venturi-cascading is a feasible method for controlling the pollutant emissions of a burning gas jet. In addition, the numerical results were useful to understand the thermo-chemical processes involved. The results showed that the prompt-NO mechanism

  19. Satellite observation of pollutant emissions from gas flaring activities near the Arctic

    NASA Astrophysics Data System (ADS)

    Li, Can; Hsu, N. Christina; Sayer, Andrew M.; Krotkov, Nickolay A.; Fu, Joshua S.; Lamsal, Lok N.; Lee, Jaehwa; Tsay, Si-Chee

    2016-05-01

    Gas flaring is a common practice in the oil industry that can have significant environmental impacts, but has until recently been largely overlooked in terms of relevance to climate change. We utilize data from various satellite sensors to examine pollutant emissions from oil exploitation activities in four areas near the Arctic. Despite the remoteness of these sparsely populated areas, tropospheric NO2 retrieved from the Ozone Monitoring Instrument (OMI) is substantial at ∼1 × 1015 molecules cm-2, suggesting sizeable emissions from these industrial activities. Statistically significant (at the 95% confidence level, corresponding uncertainties in parentheses) increasing trends of 0.017 (±0.01) × 1015 and 0.015 (±0.006) × 1015 molecules cm-2 year-1 over 2004-2015 were found for Bakken (USA) and Athabasca (Canada), two areas having recently experienced fast expansion in the oil industry. This rapid change has implications for emission inventories, which are updated less frequently. No significant trend was found for the North Sea (Europe), where oil production has been declining since the 1990s. For northern Russia, the trend was just under the 95% significance threshold at 0.0057 (±0.006) × 1015 molecules cm-2 year-1. This raises an interesting inconsistency as prior studies have suggested that, in contrast to the continued, albeit slow, expansion of Russian oil/gas production, gas flaring in Russia has decreased in recent years. However, only a fraction of oil fields in Russia were covered in our analysis. Satellite aerosol optical depth (AOD) data revealed similar tendencies, albeit at a weaker level of statistical significance, due to the longer lifetime of aerosols and contributions from other sources. This study demonstrates that synergetic use of data from multiple satellite sensors can provide valuable information on pollutant emission sources that is otherwise difficult to acquire.

  20. Simultaneous high-speed gas property measurements at the exhaust gas recirculation cooler exit and at the turbocharger inlet of a multicylinder diesel engine using diode-laser-absorption spectroscopy.

    PubMed

    Jatana, Gurneesh S; Magee, Mark; Fain, David; Naik, Sameer V; Shaver, Gregory M; Lucht, Robert P

    2015-02-10

    A diode-laser-absorption-spectroscopy-based sensor system was used to perform high-speed (100 Hz to 5 kHz) measurements of gas properties (temperature, pressure, and H(2)O vapor concentration) at the turbocharger inlet and at the exhaust gas recirculation (EGR) cooler exit of a diesel engine. An earlier version of this system was previously used for high-speed measurements of gas temperature and H(2)O vapor concentration in the intake manifold of the diesel engine. A 1387.2 N m tunable distributed feedback diode laser was used to scan across multiple H(2)O absorption transitions, and the direct absorption signal was recorded using a high-speed data acquisition system. Compact optical connectors were designed to conduct simultaneous measurements in the intake manifold, the EGR cooler exit, and the turbocharger inlet of the engine. For measurements at the turbocharger inlet, these custom optical connectors survived gas temperatures as high as 800 K using a simple and passive arrangement in which the temperature-sensitive components were protected from high temperatures using ceramic insulators. This arrangement reduced system cost and complexity by eliminating the need for any active water or oil cooling. Diode-laser measurements performed during steady-state engine operation were within 5% of the thermocouple and pressure sensor measurements, and within 10% of the H(2)O concentration values derived from the CO(2) gas analyzer measurements. Measurements were also performed in the engine during transient events. In one such transient event, where a step change in fueling was introduced, the diode-laser sensor was able to capture the 30 ms change in the gas properties; the thermocouple, on the other hand, required 7.4 s to accurately reflect the change in gas conditions, while the gas analyzer required nearly 600 ms. To the best of our knowledge, this is the first implementation of such a simple and passive arrangement of high-temperature optical connectors as well