40 CFR 86.240-94 - Exhaust sample analysis.

Code of Federal Regulations, 2010 CFR

2010-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for 1994 and Later Model Year Gasoline-Fueled New Light-Duty Vehicles, New Light-Duty Trucks and New Medium-Duty Passenger Vehicles; Cold Temperature Test Procedures § 86.240-94 Exhaust sample analysis. The...

Genome-wide scan of job-related exhaustion with three replication studies implicate a susceptibility variant at the UST gene locus

PubMed Central

Sulkava, Sonja; Ollila, Hanna M.; Ahola, Kirsi; Partonen, Timo; Viitasalo, Katriina; Kettunen, Johannes; Lappalainen, Maarit; Kivimäki, Mika; Vahtera, Jussi; Lindström, Jaana; Härmä, Mikko; Puttonen, Sampsa; Salomaa, Veikko; Paunio, Tiina

2013-01-01

Job-related exhaustion is the core dimension of burnout, a work-related stress syndrome that has several negative health consequences. In this study, we explored the molecular genetic background of job-related exhaustion. A genome-wide analysis of job-related exhaustion was performed in the GENMETS subcohort (n = 1256) of the Finnish population-based Health 2000 study. Replication analyses included an analysis of the strongest associations in the rest of the Health 2000 sample (n = 1660 workers) and in three independent populations (the FINRISK population cohort, n = 10 753; two occupational cohorts, total n = 1451). Job-related exhaustion was ascertained using a standard self-administered questionnaire (the Maslach Burnout Inventory (MBI)-GS exhaustion scale in the Health 2000 sample and the occupational cohorts) or a single question (FINRISK). A variant located in an intron of UST, uronyl-2-sulfotransferase (rs13219957), gave the strongest statistical evidence in the initial genome-wide study (P = 1.55 × 10−7), and was associated with job-related exhaustion in all the replication sets (P < 0.05; P = 6.75 × 10−7 from the meta-analysis). Consistent with studies of mood disorders, individual common genetic variants did not have any strong effect on job-related exhaustion. However, the nominally significant signals from the allelic variant of UST in four separate samples suggest that this variant might be a weak risk factor for job-related exhaustion. Together with the previously reported associations of other dermatan/chondroitin sulfate genes with mood disorders, these results indicate a potential molecular pathway for stress-related traits and mark a candidate region for further studies of job-related and general exhaustion. PMID:23620144

Rushed, unhappy, and drained: an experience sampling study of relations between time pressure, perceived control, mood, and emotional exhaustion in a group of accountants.

PubMed

Teuchmann, K; Totterdell, P; Parker, S K

1999-01-01

Experience sampling methodology was used to examine how work demands translate into acute changes in affective response and thence into chronic response. Seven accountants reported their reactions 3 times a day for 4 weeks on pocket computers. Aggregated analysis showed that mood and emotional exhaustion fluctuated in parallel with time pressure over time. Disaggregated time-series analysis confirmed the direct impact of high-demand periods on the perception of control, time pressure, and mood and the indirect impact on emotional exhaustion. A curvilinear relationship between time pressure and emotional exhaustion was shown. The relationships between work demands and emotional exhaustion changed between high-demand periods and normal working periods. The results suggest that enhancing perceived control may alleviate the negative effects of time pressure.

Sickness, colleagues' harassment in teachers' work and emotional exhaustion.

PubMed

Astrauskaite, Milda; Perminas, Aidas; Kern, Roy M

2010-01-01

The aim of this study was to assess the relationship among colleagues' harassment, emotional exhaustion, and sickness absence with a sample of teachers. The sample consisted of 351 teachers from 8 secondary schools in Kaunas. Instruments used in the study included the Work Harassment Scale (WHS) developed by Björkqvist and Osterman (1992), the Emotional Exhaustion Scale (the MBI-ES) by Maslach et al. (1996), and a questionnaire of demographic information. Data analysis indicated that a higher level of work harassment was related to higher emotional exhaustion. Regression analysis findings indicated that a higher level of emotional exhaustion was related to higher levels of disruption, humiliation, alienation, and indignity. Teachers who observed harassment reported higher levels of emotional exhaustion. Respondents who missed work due to illness reported higher levels of disruption on the WHS. The study indicated that work harassment could be an important aspect in teacher's health. The seriousness of the work harassment phenomenon may be supported by the results showing that teachers who witnessed others being harassed experienced a higher level of emotional exhaustion. The phenomenon appears to be an area that requires additional research.

40 CFR 89.301 - Scope; applicability.

Code of Federal Regulations, 2010 CFR

2010-07-01

... subpart B of part 89. (b) Exhaust gases, either raw or dilute, are sampled while the test engine is operated using an 8-mode test cycle on an engine dynamometer. The exhaust gases receive specific component analysis determining concentration of pollutant, exhaust volume, the fuel flow, and the power output during...

Influence of Rack Design and Disease Prevalence on Detection of Rodent Pathogens in Exhaust Debris Samples from Individually Ventilated Caging Systems.

PubMed

Bauer, Beth A; Besch-Williford, Cynthia; Livingston, Robert S; Crim, Marcus J; Riley, Lela K; Myles, Matthew H

2016-11-01

Sampling of bedding debris within the exhaust systems of ventilated racks may be a mechanism for detecting murine pathogens in colony animals. This study examined the effectiveness of detecting pathogens by PCR analysis of exhaust debris samples collected from ventilated racks of 2 different rack designs, one with unfiltered air flow from within the cage to the air-exhaust pathway, and the other had a filter between the cage and the air-exhaust pathway. For 12 wk, racks were populated with either 1 or 5 cages of mice (3 mice per cage) infected with one of the following pathogens: mouse norovirus (MNV), mouse parvovirus (MPV), mouse hepatitis virus (MHV), Helicobacter spp., Pasteurella pneumotropica, pinworms, Entamoeba muris, Tritrichomonas muris, and fur mites. Pathogen shedding by infected mice was monitored throughout the study. In the filter-containing rack, PCR testing of exhaust plenums yielded negative results for all pathogens at all time points of the study. In the rack with open air flow, pathogens detected by PCR analysis of exhaust debris included MHV, Helicobacter spp., P. pneumotropica, pinworms, enteric protozoa, and fur mites; these pathogens were detected in racks housing either 1 or 5 cages of infected mice. Neither MPV nor MNV was detected in exhaust debris, even though prolonged viral shedding was confirmed. These results demonstrate that testing rack exhaust debris from racks with unfiltered air flow detected MHV, enteric bacteria and parasites, and fur mites. However, this method failed to reliably detect MNV or MPV infection of colony animals.

Influence of Rack Design and Disease Prevalence on Detection of Rodent Pathogens in Exhaust Debris Samples from Individually Ventilated Caging Systems

PubMed Central

Bauer, Beth A; Besch-Williford, Cynthia; Livingston, Robert S; Crim, Marcus J; Riley, Lela K; Myles, Matthew H

2016-01-01

Sampling of bedding debris within the exhaust systems of ventilated racks may be a mechanism for detecting murine pathogens in colony animals. This study examined the effectiveness of detecting pathogens by PCR analysis of exhaust debris samples collected from ventilated racks of 2 different rack designs, one with unfiltered air flow from within the cage to the air-exhaust pathway, and the other had a filter between the cage and the air-exhaust pathway. For 12 wk, racks were populated with either 1 or 5 cages of mice (3 mice per cage) infected with one of the following pathogens: mouse norovirus (MNV), mouse parvovirus (MPV), mouse hepatitis virus (MHV), Helicobacter spp., Pasteurella pneumotropica, pinworms, Entamoeba muris, Tritrichomonas muris, and fur mites. Pathogen shedding by infected mice was monitored throughout the study. In the filter-containing rack, PCR testing of exhaust plenums yielded negative results for all pathogens at all time points of the study. In the rack with open air flow, pathogens detected by PCR analysis of exhaust debris included MHV, Helicobacter spp., P. pneumotropica, pinworms, enteric protozoa, and fur mites; these pathogens were detected in racks housing either 1 or 5 cages of infected mice. Neither MPV nor MNV was detected in exhaust debris, even though prolonged viral shedding was confirmed. These results demonstrate that testing rack exhaust debris from racks with unfiltered air flow detected MHV, enteric bacteria and parasites, and fur mites. However, this method failed to reliably detect MNV or MPV infection of colony animals. PMID:27931317

40 CFR 92.129 - Exhaust sample analysis.

Code of Federal Regulations, 2012 CFR

2012-07-01

... the span drift between the pre-analysis and post-analysis checks on any range used may exceed 3... (CONTINUED) CONTROL OF AIR POLLUTION FROM LOCOMOTIVES AND LOCOMOTIVE ENGINES Test Procedures § 92.129 Exhaust... and span each range to be used on each analyzer used prior to the beginning of the test sequence. The...

40 CFR 92.129 - Exhaust sample analysis.

Code of Federal Regulations, 2013 CFR

2013-07-01

... the span drift between the pre-analysis and post-analysis checks on any range used may exceed 3... (CONTINUED) CONTROL OF AIR POLLUTION FROM LOCOMOTIVES AND LOCOMOTIVE ENGINES Test Procedures § 92.129 Exhaust... and span each range to be used on each analyzer used prior to the beginning of the test sequence. The...

40 CFR 86.1340-90 - Exhaust sample analysis.

Code of Federal Regulations, 2010 CFR

2010-07-01

... may occur between the pre and post checks is not specified. However, the difference between pre... pre-analysis and post-analysis checks on any range used may exceed 3 percent for HC, or 2 percent for... Regulations for New Otto-Cycle and Diesel Heavy-Duty Engines; Gaseous and Particulate Exhaust Test Procedures...

40 CFR 86.1340-90 - Exhaust sample analysis.

Code of Federal Regulations, 2013 CFR

2013-07-01

... may occur between the pre and post checks is not specified. However, the difference between pre... pre-analysis and post-analysis checks on any range used may exceed 3 percent for HC, or 2 percent for... Regulations for New Otto-Cycle and Diesel Heavy-Duty Engines; Gaseous and Particulate Exhaust Test Procedures...

40 CFR 86.1340-90 - Exhaust sample analysis.

Code of Federal Regulations, 2012 CFR

2012-07-01

... may occur between the pre and post checks is not specified. However, the difference between pre... pre-analysis and post-analysis checks on any range used may exceed 3 percent for HC, or 2 percent for... Regulations for New Otto-Cycle and Diesel Heavy-Duty Engines; Gaseous and Particulate Exhaust Test Procedures...

40 CFR 92.129 - Exhaust sample analysis.

Code of Federal Regulations, 2011 CFR

2011-07-01

... the span drift between the pre-analysis and post-analysis checks on any range used may exceed 3... (CONTINUED) CONTROL OF AIR POLLUTION FROM LOCOMOTIVES AND LOCOMOTIVE ENGINES Test Procedures § 92.129 Exhaust... and span each range to be used on each analyzer used prior to the beginning of the test sequence. The...

40 CFR 86.1340-90 - Exhaust sample analysis.

Code of Federal Regulations, 2011 CFR

2011-07-01

... may occur between the pre and post checks is not specified. However, the difference between pre... pre-analysis and post-analysis checks on any range used may exceed 3 percent for HC, or 2 percent for... Regulations for New Otto-Cycle and Diesel Heavy-Duty Engines; Gaseous and Particulate Exhaust Test Procedures...

40 CFR 92.129 - Exhaust sample analysis.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the span drift between the pre-analysis and post-analysis checks on any range used may exceed 3... (CONTINUED) CONTROL OF AIR POLLUTION FROM LOCOMOTIVES AND LOCOMOTIVE ENGINES Test Procedures § 92.129 Exhaust... and span each range to be used on each analyzer used prior to the beginning of the test sequence. The...

40 CFR 91.301 - Scope; applicability.

Code of Federal Regulations, 2010 CFR

2010-07-01

... this part 91. (b) Exhaust gases are sampled while the test engine is operated using a steady state test... analysis determining concentration of pollutant, exhaust volume, the fuel flow, and the power output during...

40 CFR 91.413 - Exhaust sample procedure-gaseous components.

Code of Federal Regulations, 2011 CFR

2011-07-01

... that may occur between the pre and post checks is not specified. However, the difference between pre... drift nor the span drift between the pre-analysis and post-analysis checks on any range used may exceed... PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test...

40 CFR 91.413 - Exhaust sample procedure-gaseous components.

Code of Federal Regulations, 2014 CFR

2014-07-01

... that may occur between the pre and post checks is not specified. However, the difference between pre... drift nor the span drift between the pre-analysis and post-analysis checks on any range used may exceed... PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test...

40 CFR 91.413 - Exhaust sample procedure-gaseous components.

Code of Federal Regulations, 2010 CFR

2010-07-01

... that may occur between the pre and post checks is not specified. However, the difference between pre... drift nor the span drift between the pre-analysis and post-analysis checks on any range used may exceed... PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test...

40 CFR 91.413 - Exhaust sample procedure-gaseous components.

Code of Federal Regulations, 2012 CFR

2012-07-01

... that may occur between the pre and post checks is not specified. However, the difference between pre... drift nor the span drift between the pre-analysis and post-analysis checks on any range used may exceed... PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test...

40 CFR 91.413 - Exhaust sample procedure-gaseous components.

Code of Federal Regulations, 2013 CFR

2013-07-01

... that may occur between the pre and post checks is not specified. However, the difference between pre... drift nor the span drift between the pre-analysis and post-analysis checks on any range used may exceed... PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test...

A fast sampling device for the mass spectrometric analysis of liquid rocket engine exhaust

NASA Technical Reports Server (NTRS)

Ryason, P. R.

1975-01-01

The design of a device to obtain compositional data on rocket exhaust by direct sampling of reactive flow exhausts into a mass spectrometer is presented. Sampling at three stages differing in pressure and orifice angle and diameter is possible. Results of calibration with pure gases and gas mixtures are erratic and of unknown accuracy for H2, limiting the usefulness of the apparatus for determining oxidizer/fuel ratios from combustion product analysis. Deposition effects are discussed, and data obtained from rocket exhaust spectra are analyzed to give O/F ratios and mixture ratio distribution. The O/F ratio determined spectrometrically is insufficiently accurate for quantitative comparison with cold flow data. However, a criterion for operating conditions with improved mixing of fuel and oxidizer which is consistent with cold flow results may be obtained by inspection of contour plots. A chemical inefficiency in the combustion process when oxidizer is in excess is observed from reactive flow measurements. Present results were obtained with N2O4/N2H4 propellants.

40 CFR 90.420 - CVS concept of exhaust gas sampling system.

Code of Federal Regulations, 2013 CFR

2013-07-01

... sampling probe. (2) Exhaust flow metering system. A dilute exhaust flow metering system must be used to... exhaust. The background probe must draw a representative sample of the background air during each sampling... (bag) sampling system. If a critical flow venturi (CFV) is used on the dilute exhaust sample probe...

40 CFR 90.420 - CVS concept of exhaust gas sampling system.

Code of Federal Regulations, 2011 CFR

2011-07-01

... sampling probe. (2) Exhaust flow metering system. A dilute exhaust flow metering system must be used to... exhaust. The background probe must draw a representative sample of the background air during each sampling... (bag) sampling system. If a critical flow venturi (CFV) is used on the dilute exhaust sample probe...

40 CFR 90.420 - CVS concept of exhaust gas sampling system.

Code of Federal Regulations, 2014 CFR

2014-07-01

... sampling probe. (2) Exhaust flow metering system. A dilute exhaust flow metering system must be used to... exhaust. The background probe must draw a representative sample of the background air during each sampling... (bag) sampling system. If a critical flow venturi (CFV) is used on the dilute exhaust sample probe...

40 CFR 90.420 - CVS concept of exhaust gas sampling system.

Code of Federal Regulations, 2012 CFR

2012-07-01

... sampling probe. (2) Exhaust flow metering system. A dilute exhaust flow metering system must be used to... exhaust. The background probe must draw a representative sample of the background air during each sampling... (bag) sampling system. If a critical flow venturi (CFV) is used on the dilute exhaust sample probe...

40 CFR 90.420 - CVS concept of exhaust gas sampling system.

Code of Federal Regulations, 2010 CFR

2010-07-01

... sampling probe. (2) Exhaust flow metering system. A dilute exhaust flow metering system must be used to... exhaust. The background probe must draw a representative sample of the background air during each sampling... (bag) sampling system. If a critical flow venturi (CFV) is used on the dilute exhaust sample probe...

Understanding bioavailability and toxicity of sediment-associated contaminants by combining passive sampling with in vitro bioassays in an urban river catchment.

PubMed

Li, Juan-Ying; Tang, Janet Yat Man; Jin, Ling; Escher, Beate I

2013-12-01

Bioavailable and bioaccessible fractions of sediment-associated contaminants are considered as better dose metrics for sediment-quality assessment than total concentrations. The authors applied exhaustive solvent extraction and nondepletive equilibrium sampling techniques to sediment samples collected along the Brisbane River in South East Queensland, Australia, which range from pristine environments to urban and industry-impacted areas. The wide range of chemicals expected prevents comprehensive chemical analysis, but a battery of cell-based bioassays sheds light on mixture effects of chemicals in relation to various modes of toxic action. Toxic effects were expressed as bioanalytical equivalent concentrations (BEQs) normalized to the organic carbon content of each sediment sample. Bioanalytical equivalent concentrations from exhaustive extraction agreed fairly well with values estimated from polydimethylsiloxane passive sampling extracts via the constant organic carbon to polydimethylsiloxane partition coefficient. Agreement was best for bioassays indicative of photosynthesis inhibition and oxidative stress response and discrepancy within a factor of 3 for the induction of the aryl hydrocarbon receptor. For nonspecific cytotoxicity, BEQ from exhaustive extraction were 1 order of magnitude higher than values from equilibrium sampling, possibly because of coextraction of bioactive natural organic matter that led to an overestimation of toxicity in the exhaustive extracts, which suggests that passive sampling is better suited in combination with bioanalytical assessment than exhaustive extraction. © 2013 SETAC.

40 CFR 86.509-90 - Exhaust gas sampling system.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Exhaust gas sampling system. 86.509-90... 1978 and Later New Motorcycles; Test Procedures § 86.509-90 Exhaust gas sampling system. (a)(1) General. The exhaust gas sampling system is designed to measure the true mass emissions of vehicle exhaust. In...

40 CFR 86.509-90 - Exhaust gas sampling system.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Exhaust gas sampling system. 86.509-90... 1978 and Later New Motorcycles; Test Procedures § 86.509-90 Exhaust gas sampling system. (a)(1) General. The exhaust gas sampling system is designed to measure the true mass emissions of vehicle exhaust. In...

40 CFR 85.2218 - Preconditioned idle test-EPA 91.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 19 2012-07-01 2012-07-01 false Preconditioned idle test-EPA 91. 85... Tests § 85.2218 Preconditioned idle test—EPA 91. (a) General requirements—(1) Exhaust gas sampling algorithm. The analysis of exhaust gas concentrations begins ten seconds after the applicable test mode...

Compact high-speed MWIR spectrometer applied to monitor CO2 exhaust dynamics from a turbojet engine

NASA Astrophysics Data System (ADS)

Linares-Herrero, R.; Vergara, G.; Gutiérrez Álvarez, R.; Fernández Montojo, C.; Gómez, L. J.; Villamayor, V.; Baldasano Ramírez, A.; Montojo, M. T.; Archilla, V.; Jiménez, A.; Mercader, D.; González, A.; Entero, A.

2013-05-01

Dfgfdg Due to international environmental regulations, aircraft turbojet manufacturers are required to analyze the gases exhausted during engine operation (CO, CO2, NOx, particles, unburned hydrocarbons (aka UHC), among others).Standard procedures, which involve sampling the gases from the exhaust plume and the analysis of the emissions, are usually complex and expensive, making a real need for techniques that allow a more frequent and reliable emissions measurements, and a desire to move from the traditional gas sampling-based methods to real time and non-intrusive gas exhaust analysis, usually spectroscopic. It is expected that the development of more precise and faster optical methods will provide better solutions in terms of performance/cost ratio. In this work the analysis of high-speed infrared emission spectroscopy measurements of plume exhaust are presented. The data was collected during the test trials of commercial engines carried out at Turbojet Testing Center-INTA. The results demonstrate the reliability of the technique for studying and monitoring the dynamics of the exhausted CO2 by the observation of the infrared emission of hot gases. A compact (no moving parts), high-speed, uncooled MWIR spectrometer was used for the data collection. This device is capable to register more than 5000 spectra per second in the infrared band ranging between 3.0 and 4.6 microns. Each spectrum is comprised by 128 spectral subbands with aband width of 60 nm. The spectrometer operated in a passive stand-off mode and the results from the measurements provided information of both the dynamics and the concentration of the CO2 during engine operation.

40 CFR 90.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw gaseous exhaust sampling and... OR BELOW 19 KILOWATTS Gaseous Exhaust Test Procedures § 90.414 Raw gaseous exhaust sampling and... between the muffler and the sample probe. The mixing chamber is an optional component of the raw gas...

40 CFR 90.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw gaseous exhaust sampling and... OR BELOW 19 KILOWATTS Gaseous Exhaust Test Procedures § 90.414 Raw gaseous exhaust sampling and... between the muffler and the sample probe. The mixing chamber is an optional component of the raw gas...

40 CFR 86.210-08 - Exhaust gas sampling system; Diesel-cycle vehicles not requiring particulate emissions measurements.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Exhaust gas sampling system; Diesel... Vehicles; Cold Temperature Test Procedures § 86.210-08 Exhaust gas sampling system; Diesel-cycle vehicles not requiring particulate emissions measurements. (a) General applicability. The exhaust gas sampling...

40 CFR 86.210-08 - Exhaust gas sampling system; Diesel-cycle vehicles not requiring particulate emissions measurements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Exhaust gas sampling system; Diesel... Vehicles; Cold Temperature Test Procedures § 86.210-08 Exhaust gas sampling system; Diesel-cycle vehicles not requiring particulate emissions measurements. (a) General applicability. The exhaust gas sampling...

40 CFR 205.171-2 - Test exhaust system sample selection and preparation.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 26 2013-07-01 2013-07-01 false Test exhaust system sample selection... Systems § 205.171-2 Test exhaust system sample selection and preparation. (a)(1) Exhaust systems comprising the sample which are required to be tested under a test request in accordance with this subpart...

Impact of rail pressure and biodiesel fueling on the particulate morphology and soot nanostructures from a common-rail turbocharged direct injection diesel engine

DOE PAGES

Ye, Peng; Vander Wal, Randy; Boehman, Andre L.; ...

2014-12-26

The effect of rail pressure and biodiesel fueling on the morphology of exhaust particulate agglomerates and the nanostructure of primary particles (soot) was investigated with a common-rail turbocharged direct injection diesel engine. The engine was operated at steady state on a dynamometer running at moderate speed with both low (30%) and medium–high (60%) fixed loads, and exhaust particulate was sampled for analysis. Ultra-low sulfur diesel and its 20% v/v blends with soybean methyl ester biodiesel were used. Fuel injection occurred in a single event around top dead center at three different injection pressures. Exhaust particulate samples were characterized with TEMmore » imaging, scanning mobility particle sizing, thermogravimetric analysis, Raman spectroscopy, and XRD analysis. Particulate morphology and oxidative reactivity were found to vary significantly with rail pressure and with biodiesel blend level. Higher biodiesel content led to increases in the primary particle size and oxidative reactivity but did not affect nanoscale disorder in the as-received samples. For particulates generated with higher injection pressures, the initial oxidative reactivity increased, but there was no detectable correlation with primary particle size or nanoscale disorder.« less

Impact of rail pressure and biodiesel fueling on the particulate morphology and soot nanostructures from a common-rail turbocharged direct injection diesel engine

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ye, Peng; Vander Wal, Randy; Boehman, Andre L.

The effect of rail pressure and biodiesel fueling on the morphology of exhaust particulate agglomerates and the nanostructure of primary particles (soot) was investigated with a common-rail turbocharged direct injection diesel engine. The engine was operated at steady state on a dynamometer running at moderate speed with both low (30%) and medium–high (60%) fixed loads, and exhaust particulate was sampled for analysis. Ultra-low sulfur diesel and its 20% v/v blends with soybean methyl ester biodiesel were used. Fuel injection occurred in a single event around top dead center at three different injection pressures. Exhaust particulate samples were characterized with TEMmore » imaging, scanning mobility particle sizing, thermogravimetric analysis, Raman spectroscopy, and XRD analysis. Particulate morphology and oxidative reactivity were found to vary significantly with rail pressure and with biodiesel blend level. Higher biodiesel content led to increases in the primary particle size and oxidative reactivity but did not affect nanoscale disorder in the as-received samples. For particulates generated with higher injection pressures, the initial oxidative reactivity increased, but there was no detectable correlation with primary particle size or nanoscale disorder.« less

Associations between work family conflict, emotional exhaustion, musculoskeletal pain, and gastrointestinal problems in a sample of business travelers.

PubMed

Jensen, Maria Therese; Rundmo, Torbjørn

2015-02-01

The aim of the study was to examine the associations among work-family conflict (WFC), emotional exhaustion, musculoskeletal (MS) pain, and gastrointestinal problems on a sample of business travelers (n = 2,093). An additional aim was to examine differences in the mentioned relationships among three traveler groups: commuters, national travelers, and international travelers. The study was conducted in a large Norwegian oil and gas company, and the company's business travel database was utilized to examine business travel. Structural equation modeling (SEM) revealed significant relations between WFC and emotional exhaustion and between emotional exhaustion and health problems. Contrary to the expectations, no direct association was found between WFC and health problems. However, we found that emotional exhaustion mediated the relation between WFC and health outcomes. The results from multi-group analysis revealed that associations among WFC, emotional exhaustion, and health-outcomes showed a similar pattern for commuters, national travelers, and international travelers. However, the association between emotional exhaustion and MS pain proved to be significantly stronger for the commuter group compared to the national and international travel groups. Practical implications and the consequences of these findings for future research are discussed. © 2014 Scandinavian Psychological Associations and John Wiley & Sons Ltd.

40 CFR 86.1540 - Idle exhaust sample analysis.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) Emission... the CVS sampling system is used, the analysis procedures for dilute CO and CO2 specified in 40 CFR part 1065 apply. Follow the raw CO2 analysis procedure specified in 40 CFR part 1065, subpart F, for...

40 CFR 86.1540 - Idle exhaust sample analysis.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for... CVS sampling system is used, the analysis procedures for dilute CO and CO2 specified in 40 CFR part 1065 apply. Follow the raw CO2 analysis procedure specified in 40 CFR part 1065, subpart F, for the raw...

40 CFR 86.1540 - Idle exhaust sample analysis.

Code of Federal Regulations, 2012 CFR

2012-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES (CONTINUED) Emission... the CVS sampling system is used, the analysis procedures for dilute CO and CO2 specified in 40 CFR part 1065 apply. Follow the raw CO2 analysis procedure specified in 40 CFR part 1065, subpart F, for...

Relationship between Composition and Toxicity of Motor Vehicle Emission Samples

PubMed Central

McDonald, Jacob D.; Eide, Ingvar; Seagrave, JeanClare; Zielinska, Barbara; Whitney, Kevin; Lawson, Douglas R.; Mauderly, Joe L.

2004-01-01

In this study we investigated the statistical relationship between particle and semivolatile organic chemical constituents in gasoline and diesel vehicle exhaust samples, and toxicity as measured by inflammation and tissue damage in rat lungs and mutagenicity in bacteria. Exhaust samples were collected from “normal” and “high-emitting” gasoline and diesel light-duty vehicles. We employed a combination of principal component analysis (PCA) and partial least-squares regression (PLS; also known as projection to latent structures) to evaluate the relationships between chemical composition of vehicle exhaust and toxicity. The PLS analysis revealed the chemical constituents covarying most strongly with toxicity and produced models predicting the relative toxicity of the samples with good accuracy. The specific nitro-polycyclic aromatic hydrocarbons important for mutagenicity were the same chemicals that have been implicated by decades of bioassay-directed fractionation. These chemicals were not related to lung toxicity, which was associated with organic carbon and select organic compounds that are present in lubricating oil. The results demonstrate the utility of the PCA/PLS approach for evaluating composition–response relationships in complex mixture exposures and also provide a starting point for confirming causality and determining the mechanisms of the lung effects. PMID:15531438

40 CFR 86.540-90 - Exhaust sample analysis.

Code of Federal Regulations, 2013 CFR

2013-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for... appropriate, NOX. concentrations of samples. (6) Check zero and span points. If difference is greater than 2...

40 CFR 86.540-90 - Exhaust sample analysis.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (CONTINUED) CONTROL OF EMISSIONS FROM NEW AND IN-USE HIGHWAY VEHICLES AND ENGINES Emission Regulations for... appropriate, NOX. concentrations of samples. (6) Check zero and span points. If difference is greater than 2...

Murine norovirus detection in the exhaust air of IVCs is more sensitive than serological analysis of soiled bedding sentinels.

PubMed

Zorn, Julia; Ritter, Bärbel; Miller, Manuel; Kraus, Monika; Northrup, Emily; Brielmeier, Markus

2017-06-01

One limitation to housing rodents in individually ventilated cages (IVCs) is the ineffectiveness of traditional health monitoring programs that test soiled bedding sentinels every quarter. Aerogen transmission does not occur with this method. Moreover, the transmission of numerous pathogens in bedding is uncertain, and sentinel susceptibility to various pathogens varies. A novel method using particle collection from samples of exhaust air was developed in this study which was also systematically compared with routine health monitoring using soiled bedding sentinels. We used our method to screen these samples for the presence of murine norovirus (MNV), a mouse pathogen highly prevalent in laboratory animal facilities. Exhaust air particles from prefilters of IVC racks with known MNV prevalence were tested by quantitative reverse transcription polymerase chain reaction (RT-qPCR). MNV was detected in exhaust air as early as one week with one MNV-positive cage per rack, while sentinels discharged MNV RNA without seroconverting. MNV was reliably and repeatedly detected in particles collected from samples of exhaust air in all seven of the three-month sampling rounds, with increasing MNV prevalence, while sentinels only seroconverted in one round. Under field conditions, routine soiled bedding sentinel health monitoring in our animal facility failed to identify 67% ( n = 85) of positive samples by RT-qPCR of exhaust air particles. Thus, this method proved to be highly sensitive and superior to soiled bedding sentinels in the reliable detection of MNV. These results represent a major breakthrough in hygiene monitoring of rodent IVC systems and contribute to the 3R principles by reducing the number of animals used and by improving experimental conditions.

40 CFR 86.110-94 - Exhaust gas sampling system; diesel-cycle vehicles, and Otto-cycle vehicles requiring particulate...

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Exhaust gas sampling system; diesel... Heavy-Duty Vehicles; Test Procedures § 86.110-94 Exhaust gas sampling system; diesel-cycle vehicles, and..., this is indicated by the statement “[Reserved].” (a) General. The exhaust gas sampling system described...

Effect sizes and cut-off points: a meta-analytical review of burnout in latin American countries.

PubMed

García-Arroyo, Jose; Osca Segovia, Amparo

2018-05-02

Burnout is a highly prevalent globalized health issue that causes significant physical and psychological health problems. In Latin America research on this topic has increased in recent years, however there are no studies comparing results across countries, nor normative reference cut-offs. The present meta-analysis examines the intensity of burnout (emotional exhaustion, cynicism and personal accomplishment) in 58 adult nonclinical samples from 8 countries (Argentina, Brazil, Chile, Colombia, Ecuador, Mexico, Peru and Venezuela). We found low intensity of burnout but there are significant differences between countries in emotional exhaustion explained by occupation and language. Social and human service professionals (police officers, social workers, public administration staff) are more exhausted than health professionals (physicians, nurses) or teachers. The samples with Portuguese language score higher in emotional exhaustion than Spanish, supporting the theory of cultural relativism. Demographics (sex, age) and study variables (sample size, instrument), were not found significant to predict burnout. The effect size and confidence intervals found are proposed as a useful baseline for research and medical diagnosis of burnout in Latin American countries.

Physicochemical characterisation of combustion particles from vehicle exhaust and residential wood smoke

PubMed Central

Kocbach, Anette; Li, Yanjun; Yttri, Karl E; Cassee, Flemming R; Schwarze, Per E; Namork, Ellen

2006-01-01

Background Exposure to ambient particulate matter has been associated with a number of adverse health effects. Particle characteristics such as size, surface area and chemistry seem to influence the negative effects of particles. In this study, combustion particles from vehicle exhaust and wood smoke, currently used in biological experiments, were analysed with respect to microstructure and chemistry. Methods Vehicle exhaust particles were collected in a road tunnel during two seasons, with and without use of studded tires, whereas wood smoke was collected from a stove with single-stage combustion. Additionally, a reference diesel sample (SRM 2975) was analysed. The samples were characterised using transmission electron microscopy techniques (TEM/HRTEM, EELS and SAED). Furthermore, the elemental and organic carbon fractions were quantified using thermal optical transmission analysis and the content of selected PAHs was determined by gas chromatography-mass spectrometry. Results Carbon aggregates, consisting of tens to thousands of spherical primary particles, were the only combustion particles identified in all samples using TEM. The tunnel samples also contained mineral particles originating from road abrasion. The geometric diameters of primary carbon particles from vehicle exhaust were found to be significantly smaller (24 ± 6 nm) than for wood smoke (31 ± 7 nm). Furthermore, HRTEM showed that primary particles from both sources exhibited a turbostratic microstructure, consisting of concentric carbon layers surrounding several nuclei in vehicle exhaust or a single nucleus in wood smoke. However, no differences were detected in the graphitic character of primary particles from the two sources using SAED and EELS. The total PAH content was higher for combustion particles from wood smoke as compared to vehicle exhaust, whereas no source difference was found for the ratio of organic to total carbon. Conclusion Combustion particles from vehicle exhaust and residential wood smoke differ in primary particle diameter, microstructure, and PAH content. Furthermore, the analysed samples seem suitable for assessing the influence of physicochemical characteristics of particles on biological responses. PMID:16390554

40 CFR 91.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw gaseous exhaust sampling and... Gaseous Exhaust Test Procedures § 91.414 Raw gaseous exhaust sampling and analytical system description... the component systems. (g) The following requirements must be incorporated in each system used for raw...

40 CFR 91.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw gaseous exhaust sampling and... Gaseous Exhaust Test Procedures § 91.414 Raw gaseous exhaust sampling and analytical system description... the component systems. (g) The following requirements must be incorporated in each system used for raw...

40 CFR 89.412 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw gaseous exhaust sampling and...-IGNITION ENGINES Exhaust Emission Test Procedures § 89.412 Raw gaseous exhaust sampling and analytical... must be incorporated in each system used for raw testing under this subpart. (1) [Reserved] (2) The...

40 CFR 89.412 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw gaseous exhaust sampling and...-IGNITION ENGINES Exhaust Emission Test Procedures § 89.412 Raw gaseous exhaust sampling and analytical... must be incorporated in each system used for raw testing under this subpart. (1) [Reserved] (2) The...

40 CFR 86.1340-94 - Exhaust sample analysis.

Code of Federal Regulations, 2012 CFR

2012-07-01

... Section 86.1340-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... (except diesels), CH4 (natural gas-fueled engines only), CO, CO2. and NOX sample bag(s) with approximately... not require bag analysis.) (d)(8) through (h) [Reserved]. For guidance see § 86.1340-90. [59 FR 48534...

40 CFR 86.1340-94 - Exhaust sample analysis.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Section 86.1340-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... (except diesels), CH4 (natural gas-fueled engines only), CO, CO2. and NOX sample bag(s) with approximately... not require bag analysis.) (d)(8) through (h) [Reserved]. For guidance see § 86.1340-90. [59 FR 48534...

40 CFR 86.1340-94 - Exhaust sample analysis.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Section 86.1340-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... (except diesels), CH4 (natural gas-fueled engines only), CO, CO2. and NOX sample bag(s) with approximately... not require bag analysis.) (d)(8) through (h) [Reserved]. For guidance see § 86.1340-90. [59 FR 48534...

40 CFR 86.1340-94 - Exhaust sample analysis.

Code of Federal Regulations, 2013 CFR

2013-07-01

... Section 86.1340-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... (except diesels), CH4 (natural gas-fueled engines only), CO, CO2. and NOX sample bag(s) with approximately... not require bag analysis.) (d)(8) through (h) [Reserved]. For guidance see § 86.1340-90. [59 FR 48534...

The association between body mass index status and sick leave and the role of emotional exhaustion-a mediation analysis among a representative sample of dutch employees.

PubMed

Proper, Karin I; Koppes, Lando L J; Meijer, Sanne; Bemelmans, Wanda J E

2013-10-01

To investigate the associations between body mass index (BMI) and sick leave, and the mediating role of emotional exhaustion. Data were collected from a large survey among Dutch employees (n = 35,022). The causal pathway approach consisting of four regression analyses was applied. In women, moderate overweight and obesity were associated with higher sick leave; in men, obesity, but not moderate overweight, was associated with higher sick leave. Obese workers were at increased risk for emotional exhaustion. Emotional exhaustion was also associated with higher sick leave rates. Adjustment for emotional exhaustion in the association between BMI and sick leave hardly changed the effect size and significance remained. The association between BMI status and sick leave can be explained partially by the presence of emotional exhaustion. Workplace health promotion initiatives should take this into account.

40 CFR 91.420 - CVS concept of exhaust gas sampling system.

Code of Federal Regulations, 2013 CFR

2013-07-01

... that complete mixing of the engine exhaust and background air is assured prior to the sampling probe.... The background probe must draw a representative sample of the background air during each sampling mode...) sampling system. If a critical flow venturi (CFV) is used on the dilute exhaust sample probe, this system...

40 CFR 91.420 - CVS concept of exhaust gas sampling system.

Code of Federal Regulations, 2010 CFR

2010-07-01

... that complete mixing of the engine exhaust and background air is assured prior to the sampling probe.... The background probe must draw a representative sample of the background air during each sampling mode...) sampling system. If a critical flow venturi (CFV) is used on the dilute exhaust sample probe, this system...

40 CFR 91.420 - CVS concept of exhaust gas sampling system.

Code of Federal Regulations, 2014 CFR

2014-07-01

... that complete mixing of the engine exhaust and background air is assured prior to the sampling probe.... The background probe must draw a representative sample of the background air during each sampling mode...) sampling system. If a critical flow venturi (CFV) is used on the dilute exhaust sample probe, this system...

40 CFR 91.420 - CVS concept of exhaust gas sampling system.

Code of Federal Regulations, 2011 CFR

2011-07-01

... that complete mixing of the engine exhaust and background air is assured prior to the sampling probe.... The background probe must draw a representative sample of the background air during each sampling mode...) sampling system. If a critical flow venturi (CFV) is used on the dilute exhaust sample probe, this system...

40 CFR 91.420 - CVS concept of exhaust gas sampling system.

Code of Federal Regulations, 2012 CFR

2012-07-01

... that complete mixing of the engine exhaust and background air is assured prior to the sampling probe.... The background probe must draw a representative sample of the background air during each sampling mode...) sampling system. If a critical flow venturi (CFV) is used on the dilute exhaust sample probe, this system...

Evaluation of factors that affect diesel exhaust toxicity. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Norbeck, J.M.; Smith, M.R.; Arey, J.

1998-07-01

The scope of this project was to obtain a preliminary assessment of the potential impact of the fuel formulation on the speciation and toxic components of diesel exhaust. The test bed was a Cummins L10 engine operating over the heavy-duty transient test cycle using three diesel fuels: a pre-1993 diesel fuel, a low aromatic diesel fuel, and an alternative formulation diesel fuel. The sampling/analysis plan included: determination of the criteria pollutant emission rates (THC, CO, NOx, and PM); determination of PM(10) and PM(2.5) emission rates; collection and analysis of particulate samples for elemental, inorganic ion and elemental/organic carbon analyses; collectionmore » of bas samples for VOC speciation analyses; collection of 2,4-dinitrophenylhydrazine (DNPH) cartridges for determination of oxygenates; collection of nitrosomorpholine with Thermosorb N cartridges; collection of semi-volatiles on PF/XAD and particulate samples for PAH, nitro-PAH, and mutagenicity studies; and collection and analysis of dioxins for the pre-1993 and alternative formulation diesel fuels.« less

Computation of wake/exhaust mixing downstream of advanced transport aircraft

NASA Technical Reports Server (NTRS)

Quackenbush, Todd R.; Teske, Milton E.; Bilanin, Alan J.

1993-01-01

The mixing of engine exhaust with the vortical wake of high speed aircraft operating in the stratosphere can play an important role in the formation of chemical products that deplete atmospheric ozone. An accurate analysis of this type of interaction is therefore necessary as a part of the assessment of the impact of proposed High Speed Civil Transport (HSCT) designs on atmospheric chemistry. This paper describes modifications to the parabolic Navier-Stokes flow field analysis in the UNIWAKE unified aircraft wake model to accommodate the computation of wake/exhaust mixing and the simulation of reacting flow. The present implementation uses a passive chemistry model in which the reacting species are convected and diffused by the fluid dynamic solution but in which the evolution of the species does not affect the flow field. The resulting analysis, UNIWAKE/PCHEM (Passive CHEMistry) has been applied to the analysis of wake/exhaust flows downstream of representative HSCT configurations. The major elements of the flow field model are described, as are the results of sample calculations illustrating the behavior of the thermal exhaust plume and the production of species important to the modeling of condensation in the wake. Appropriate steps for further development of the UNIWAKE/PCHEM model are also outlined.

Performance evaluation of a biodiesel fuelled transportation engine retrofitted with a non-noble metal catalysed diesel oxidation catalyst for controlling unregulated emissions.

PubMed

Shukla, Pravesh Chandra; Gupta, Tarun; Agarwal, Avinash Kumar

2018-02-15

In present study, engine exhaust was sampled for measurement and analysis of unregulated emissions from a four cylinder transportation diesel engine using a state-of-the-art FTIR (Fourier transform infrared spectroscopy) emission analyzer. Test fuels used were Karanja biodiesel blend (B20) and baseline mineral diesel. Real-time emission measurements were performed for raw exhaust as well as exhaust sampled downstream of the two in-house prepared non-noble metal based diesel oxidation catalysts (DOCs) and a baseline commercial DOC based on noble metals. Two prepared non-noble metal based DOCs were based on Co-Ce mixed oxide and Lanthanum based perovskite catalysts. Perovskite based DOC performed superior compared to Co-Ce mixed oxide catalyst based DOC. Commercial noble metal based DOC was found to be the most effective in reducing unregulated hydrocarbon emissions in the engine exhaust, followed by the two in-house prepared non-noble metal based DOCs. Copyright © 2017 Elsevier B.V. All rights reserved.

Real-time exhaust gas modular flowmeter and emissions reporting system for mobile apparatus

NASA Technical Reports Server (NTRS)

Breton, Leo Alphonse Gerard (Inventor)

2002-01-01

A real-time emissions reporting system includes an instrument module adapted to be detachably connected to the exhaust pipe of a combustion engine to provide for flow of exhaust gas therethrough. The instrument module includes a differential pressure probe which allows for determination of flow rate of the exhaust gas and a gas sampling tube for continuously feeding a sample of the exhaust gas to a gas analyzer or a mounting location for a non-sampling gas analyzer. In addition to the module, the emissions reporting system also includes an elastomeric boot for detachably connecting the module to the exhaust pipe of the combustion engine, a gas analyzer for receiving and analyzing gases sampled within the module and a computer for calculating pollutant mass flow rates based on concentrations detected by the gas analyzer and the detected flowrate of the exhaust gas. The system may also include a particulate matter detector with a second gas sampling tube feeding same mounted within the instrument module.

14 CFR 34.64 - Sampling and analytical procedures for measuring gaseous exhaust emissions.

Code of Federal Regulations, 2010 CFR

2010-01-01

... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE ENGINE POWERED AIRPLANES Test Procedures for Engine Exhaust Gaseous Emissions (Aircraft and Aircraft Gas Turbine Engines) § 34.64 Sampling and analytical procedures for measuring gaseous exhaust emissions. The...

14 CFR 34.64 - Sampling and analytical procedures for measuring gaseous exhaust emissions.

Code of Federal Regulations, 2011 CFR

2011-01-01

... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE ENGINE POWERED AIRPLANES Test Procedures for Engine Exhaust Gaseous Emissions (Aircraft and Aircraft Gas Turbine Engines) § 34.64 Sampling and analytical procedures for measuring gaseous exhaust emissions. The...

A Novel Method to Handle the Effect of Uneven Sampling Effort in Biodiversity Databases

PubMed Central

Pardo, Iker; Pata, María P.; Gómez, Daniel; García, María B.

2013-01-01

How reliable are results on spatial distribution of biodiversity based on databases? Many studies have evidenced the uncertainty related to this kind of analysis due to sampling effort bias and the need for its quantification. Despite that a number of methods are available for that, little is known about their statistical limitations and discrimination capability, which could seriously constrain their use. We assess for the first time the discrimination capacity of two widely used methods and a proposed new one (FIDEGAM), all based on species accumulation curves, under different scenarios of sampling exhaustiveness using Receiver Operating Characteristic (ROC) analyses. Additionally, we examine to what extent the output of each method represents the sampling completeness in a simulated scenario where the true species richness is known. Finally, we apply FIDEGAM to a real situation and explore the spatial patterns of plant diversity in a National Park. FIDEGAM showed an excellent discrimination capability to distinguish between well and poorly sampled areas regardless of sampling exhaustiveness, whereas the other methods failed. Accordingly, FIDEGAM values were strongly correlated with the true percentage of species detected in a simulated scenario, whereas sampling completeness estimated with other methods showed no relationship due to null discrimination capability. Quantifying sampling effort is necessary to account for the uncertainty in biodiversity analyses, however, not all proposed methods are equally reliable. Our comparative analysis demonstrated that FIDEGAM was the most accurate discriminator method in all scenarios of sampling exhaustiveness, and therefore, it can be efficiently applied to most databases in order to enhance the reliability of biodiversity analyses. PMID:23326357

A novel method to handle the effect of uneven sampling effort in biodiversity databases.

PubMed

Pardo, Iker; Pata, María P; Gómez, Daniel; García, María B

2013-01-01

How reliable are results on spatial distribution of biodiversity based on databases? Many studies have evidenced the uncertainty related to this kind of analysis due to sampling effort bias and the need for its quantification. Despite that a number of methods are available for that, little is known about their statistical limitations and discrimination capability, which could seriously constrain their use. We assess for the first time the discrimination capacity of two widely used methods and a proposed new one (FIDEGAM), all based on species accumulation curves, under different scenarios of sampling exhaustiveness using Receiver Operating Characteristic (ROC) analyses. Additionally, we examine to what extent the output of each method represents the sampling completeness in a simulated scenario where the true species richness is known. Finally, we apply FIDEGAM to a real situation and explore the spatial patterns of plant diversity in a National Park. FIDEGAM showed an excellent discrimination capability to distinguish between well and poorly sampled areas regardless of sampling exhaustiveness, whereas the other methods failed. Accordingly, FIDEGAM values were strongly correlated with the true percentage of species detected in a simulated scenario, whereas sampling completeness estimated with other methods showed no relationship due to null discrimination capability. Quantifying sampling effort is necessary to account for the uncertainty in biodiversity analyses, however, not all proposed methods are equally reliable. Our comparative analysis demonstrated that FIDEGAM was the most accurate discriminator method in all scenarios of sampling exhaustiveness, and therefore, it can be efficiently applied to most databases in order to enhance the reliability of biodiversity analyses.

40 CFR 86.1309-90 - Exhaust gas sampling system; Otto-cycle and non-petroleum-fueled engines.

Code of Federal Regulations, 2011 CFR

2011-07-01

... gasoline-fueled, natural gas-fueled, liquefied petroleum gas-fueled or methanol-fueled engines. In the CVS... test period. (2) Engine exhaust to CVS duct. For methanol-fueled engines, reactions of the exhaust... samples for the bag sample, the methanol sample (Figure N90-2), and the formaldehyde sample (Figure N90-3...

[Polycyclic aromatic hydrocarbons and soluble organic fraction in fine particles from solid fraction of biodiesel exhaust fumes].

PubMed

Szewczyńska, Małgorzata; Pośniak, Małgorzata

2012-01-01

This paper presents the results of investigations into the distribution of fine particles in the biodiesel exhaust fumes (bio-DEP), as well as into the content of polycyclic aromatic hydrocarbons (PAHs) and soluble organic fraction (SOF) in the study fractions. Samples of biodiesel B20 and B40 exhaust combustion fumes were generated at the model station composed of a diesel engine from Diesel TDI 2007 Volkswagen. Sioutas personal cascade impactor (SPCI) with Teflon filters and low-pressure impactor ELIPI (Dekati Low Pressure Impactor) were used for sampling diesel exhaust fine particles. The analysis of PAHs adsorbed on particulate fractions was performed by high performance liquid chromatography with fluorescence detection (HPLC/FL). For the determination of dry residue soluble organic fraction of biodiesel exhaust particles the gravimetric method was used. The combustion exhaust fumes of 100% ON contained mainly naphthalene, acenaphthalene, fluorene, phenanthrene, fluoranthene, pyrene, benzo(a)anthracene and chrysene, whilst the exhaust of B40-single PAHs of 4 and 5 rings, such as chrysene, benzo(k)fluoranthene, dibenzo (ah)anthracene and benzo(ghi)perylene. The total content of PAHs in diesel exhaust particles averaged 910 ng/m3 for 100% ON and 340 ng/m3 for B40. The concentrations of benzo(a)antarcene were at the levels of 310 ng/m3 (100% ON) and 90 ng/m3 (B40). The investigations indicated that a fraction < 025 microm represents the main component of diesel exhaust particles, regardless of the used fuel. Bioester B 100 commonly added to diesel fuel (ON) causes a reduction of the total particulates emission and thus reduces the amount of toxic substances adsorbed on their surface.

Propane and butane emission sources to ambient air of Mexico City metropolitan area.

PubMed

Jaimes, L; Sandoval, J

2002-04-22

Samples of volatile organic compounds (VOCs) were collected in a smog chamber in order to determine whether automotive exhausts or LP Gas emissions play a greater role in the source of propane and butane, which affect ozone formation and other pollutants in the ambient air of the Mexico City metropolitan area (MCMA). These samples were collected in April 1995 during mornings and evenings. The testing methodology used for measuring exhaust emission were FTP or EPA-74 tests, and SHED type tests were also conducted in order to evaluate evaporative emissions. The finding from analysis of the VOCs collected in the morning demonstrate that in the atmosphere, propane concentrations are higher than that of butane but the reverse in evaporative and exhaust emissions, with the concentration of propane lower than that of butane. Our conclusion is that most of C3 and C4 in the ambient air comes from LP gas and not vehicle exhaust or evaporative emission, due to the higher levels of propane than butane in its formulation. The analysis of VOCs also indicates that although the conversion (in the smog chamber) of alkanes is low during the day, due to the high initial concentration, their contribution in the reaction mechanism to produce ozone can be appreciable.

Investigation of Deposit Formation Mechanisms for Engine In-cylinder Combustion and Exhaust Systems Using Quantitative Analysis and Sustainability Study

NASA Astrophysics Data System (ADS)

Ye, Z.; Meng, Q.; Mohamadian, H. P.; Wang, J. T.; Chen, L.; Zhu, L.

2007-06-01

The formation of SI engine combustion deposits is a complex phenomenon which depends on various factors of fuel, oil, additives, and engine. The goal of this study is to examine the effects of operating conditions, gasoline, lubricating oil, and additives on deposit formation. Both an experimental investigation and theoretical analysis are conducted on a single cylinder engine. As a result, the impact of deposits on engine performance and exhaust emissions (HC, NO x ) has been indicated. Using samples from a cylinder head and exhaust pipe as well as switching gases via the dual-gas method (N2, O2), the deposit formation mechanism is thoroughly investigated via the thermogravity analysis approach, where the roles of organic, inorganic, and volatile components of fuel, additives, and oil on deposit formation are identified from thermogravity curves. Sustainable feedback control design is then proposed for potential emission control and performance optimization

14 CFR 34.64 - Sampling and analytical procedures for measuring gaseous exhaust emissions.

Code of Federal Regulations, 2012 CFR

2012-01-01

... ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE... Turbine Engines) § 34.64 Sampling and analytical procedures for measuring gaseous exhaust emissions. The...

Personality, work characteristics, and employee well-being: a longitudinal analysis of additive and moderating effects.

PubMed

Houkes, Inge; Janssen, Peter P M; de Jonge, Jan; Bakker, Arnold B

2003-01-01

This study tested the longitudinal influence of personality (measured by the characteristics growth need strength, negative affectivity [NA], and upward striving) on 3 psychological outcomes (intrinsic work motivation, emotional exhaustion, and turnover intention), using a pattern of specific relationships between work characteristics and these outcomes as a framework. The study hypotheses were tested in a multioccupational sample consisting of bank employees and teachers, using a 2-wave panel design with a 1-year time interval and structural equation modeling. NA had a cross-lagged direct and additive relationship with emotional exhaustion and also moderated the relationship between Time 1 workload and Time 2 emotional exhaustion. The authors concluded that NA may have multiple effects on emotional exhaustion that persist over time.

Computer code for single-point thermodynamic analysis of hydrogen/oxygen expander-cycle rocket engines

NASA Technical Reports Server (NTRS)

Glassman, Arthur J.; Jones, Scott M.

1991-01-01

This analysis and this computer code apply to full, split, and dual expander cycles. Heat regeneration from the turbine exhaust to the pump exhaust is allowed. The combustion process is modeled as one of chemical equilibrium in an infinite-area or a finite-area combustor. Gas composition in the nozzle may be either equilibrium or frozen during expansion. This report, which serves as a users guide for the computer code, describes the system, the analysis methodology, and the program input and output. Sample calculations are included to show effects of key variables such as nozzle area ratio and oxidizer-to-fuel mass ratio.

Comparison of Fourier transform infrared spectrometry and 2,4-dinitrophenylhydrazine impinger techniques for the measurement of formaldehyde in vehicle exhaust

DOE Office of Scientific and Technical Information (OSTI.GOV)

Haack, L.P.; LaCourse, D.L.; Korniski, T.J.

1986-01-01

Experiments were conducted to validate a Fourier transform infrared (FT-IR) sampling and analysis system for measurement of trace gases in vehicle exhaust utilizing gasoline-, gasohol-, diesel-, and methanol-fueled vehicles as the emission source and formaldehyde (HCHO) as the test molecule. The 2,4-dinitrophenylhydrazine impinger method was chosen as the reference method. Diluted exhaust was drawn continuously though the FT-IR cell and measured every 3 s. The FT-IR signals were averaged over a complete driving-test cycle and compared to the concentration determined from concurrent impinger sampling. By impinger measurements it was shown that HCHO losses between the tailpipe and the FT-IR cellmore » were on the order of only 5%, independent of vehicle type or HCHO concentration (0.02-8.5 ppm). Comparisons between FT-IR and impinger measurements on 43 tests of methanol-fueled vehicles under transient conditions (diluted-exhaust HCHO 0.28-8.5 ppm) showed FT-IR/impinger = 1.055 +/- 0.095. 19 references, 5 figures, 5 tables.« less

Prevalence of burnout syndrome in oncology nursing: A meta-analytic study.

PubMed

Cañadas-De la Fuente, Guillermo A; Gómez-Urquiza, Jose L; Ortega-Campos, Elena M; Cañadas, Gustavo R; Albendín-García, Luis; De la Fuente-Solana, Emilia I

2018-05-01

To determine the prevalence of high levels of emotional exhaustion and depersonalization and low personal accomplishment in nursing professionals in oncology services. A meta-analytical study was performed. The search was carried out in March 2017 in Pubmed, CINAHL, Scopus, Scielo, Proquest, CUIDEN, and LILACS databases. Studies using Maslach Burnout Inventory for the assessment of burnout were included. The total sample of oncology nurses was n = 9959. The total number of included studies was n = 17, with n = 21 samples for the meta-analysis of emotional exhaustion and n = 18 for depersonalization and low personal accomplishment. The prevalence of emotional exhaustion and of depersonalization was 30% (95% CI = 26%-33%) and 15% (95% CI = 9%-23%), respectively, and that of low personal performance was 35% (95% CI = 27%-43%). The are many oncology nurses with emotional exhaustion and low levels of personal accomplishment. The presence and the risk of burnout among these staff members are considerable. Copyright © 2018 John Wiley & Sons, Ltd.

Facilities Management Guide for Asbestos and Lead

DTIC Science & Technology

2004-11-01

equipment such as HEPA filtered power tools, portable welding exhaust systems, and paint removal equipment when work disturbs lead. Do not dry sweep ...sampling and analysis of [______] paint bulk and wipe samples by atomic absorption spectrophotometry (AA) or anodic stripping voltametry (ASV...analysis. e. All bulk (destructive) collected for lead shall be analyzed by atomic absorption spectrophotometry (AA) or anodic stripping voltametry

Analysis of atmospheric paniculate matter; application of optical and selected geochemical techniques

USGS Publications Warehouse

Mastalerz, Maria; Glikson, M.; Simpson, R.W.

1999-01-01

An increase in participate matter in the atmosphere has been shown to be linked to increased mortality but this relationship is poorly understood. Light microscopy, electron microscopy, electron microprobe, and micro-FTIR techniques have been applied to study atmospheric particulates in Brisbane, Australia as a part of a study on asthma. The particulate matter samples were collected daily from April to August 1992, and the sampling covered the autumn period which is typically a time of high asthma incidence in Brisbane. Volumetrically, most atmospheric particulate matter is less than 2 ??m in size. The microscopic analysis reveals that this material is composed mainly of combusted and incompletely burned hydrocarbons from motor vehicle exhaust emissions, quiescent spores of Mucorales, soil bacteria, and inorganic matter in the form of quartz and other silicates. Elemental and functional group analyses confirm microscope identification, documenting carbon-rich, aromatic exhaust material, more aliphatic pollen and spore material and inorganic matter. Fungal spores dominate bioaerosol and are very abundant from the end of April through May to mid-June. The cytoplasmic content of pollens or fungal spores is commonly regarded as allergenic. Particulates from the exhaust emissions and crustal material in a sub-micrometer size range may act as carriers or dispersive mechanisms for cytoplasmic material from fungal spores and pollens, perhaps causing periods of the highest exhaust emission to be the most allergenic. ?? 1998 Elsevier Science B.V. All rights reserved.

40 CFR 264.347 - Monitoring and inspections.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Administrator, sampling and analysis of the waste and exhaust emissions must be conducted to verify that the... incinerator and associated equipment (pumps, valves, conveyors, pipes, etc.) must be subjected to thorough...

40 CFR 85.2224 - Exhaust analysis system-EPA 81.

Code of Federal Regulations, 2012 CFR

2012-07-01

... probe, moisture separator and analyzers for HC and CO. (2) Dual sample probe requirements. If used, a dual sample probe must provide equal flow in each leg. The equal flow criterion is considered to be met if the flow rate in each leg of the probe (or an identical model) has been measured under two sample...

40 CFR 85.2224 - Exhaust analysis system-EPA 81.

Code of Federal Regulations, 2013 CFR

2013-07-01

... probe, moisture separator and analyzers for HC and CO. (2) Dual sample probe requirements. If used, a dual sample probe must provide equal flow in each leg. The equal flow criterion is considered to be met if the flow rate in each leg of the probe (or an identical model) has been measured under two sample...

40 CFR 85.2224 - Exhaust analysis system-EPA 81.

Code of Federal Regulations, 2011 CFR

2011-07-01

... probe, moisture separator and analyzers for HC and CO. (2) Dual sample probe requirements. If used, a dual sample probe must provide equal flow in each leg. The equal flow criterion is considered to be met if the flow rate in each leg of the probe (or an identical model) has been measured under two sample...

40 CFR 86.110-90 - Exhaust gas sampling system; diesel vehicles.

Code of Federal Regulations, 2010 CFR

2010-07-01

... probe. The sensor shall have an accuracy and precision of ±2 °F (1.1 °C). (14) The dilute exhaust gas... probe. The sensor shall have an accuracy and precision of ±2 °F (1.1 °C). (14) The dilute exhaust gas... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Exhaust gas sampling system; diesel...

40 CFR 86.110-90 - Exhaust gas sampling system; diesel vehicles.

Code of Federal Regulations, 2011 CFR

2011-07-01

... probe. The sensor shall have an accuracy and precision of ±2 °F (1.1 °C). (14) The dilute exhaust gas... probe. The sensor shall have an accuracy and precision of ±2 °F (1.1 °C). (14) The dilute exhaust gas... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Exhaust gas sampling system; diesel...

Clinical supervision, emotional exhaustion, and turnover intention: A study of substance abuse treatment counselors in NIDA’s Clinical Trials Network

PubMed Central

Knudsen, Hannah K.; Ducharme, Lori J.; Roman, Paul M

2008-01-01

An intriguing hypothesis is that clinical supervision may protect against counselor turnover. This idea has been mentioned in recent discussions of the substance abuse treatment workforce. To test this hypothesis, we extend our previous research on emotional exhaustion and turnover intention among counselors by estimating the associations between clinical supervision and these variables in a large sample (n = 823). An exploratory analysis reveals that clinical supervision was negatively associated with emotional exhaustion and turnover intention. Given our previous findings that emotional exhaustion and turnover intention were associated with job autonomy, procedural justice, and distributive justice, we estimate a structural equation model to examine whether these variables mediated clinical supervision’s associations with emotional exhaustion and turnover intention. These data support the fully mediated model. We found the perceived quality of clinical supervision is strongly associated with counselors’ perceptions of job autonomy, procedural justice, and distributive justice, which are, in turn, associated with emotional exhaustion and turnover intention. These data offer support for the protective role of clinical supervision in substance abuse treatment counselors’ turnover and occupational wellbeing. PMID:18424048

40 CFR 86.540-90 - Exhaust sample analysis.

Code of Federal Regulations, 2012 CFR

2012-07-01

..., if appropriate, NOX: (1) Zero the analyzers and obtain a stable zero reading. Recheck after tests. (2... actual concentrations on chart. (3) Check zeros; repeat the procedure in paragraphs (a) (1) and (2) of... appropriate, NOX. concentrations of samples. (6) Check zero and span points. If difference is greater than 2...

40 CFR 86.540-90 - Exhaust sample analysis.

Code of Federal Regulations, 2010 CFR

2010-07-01

..., gasoline-fueled, natural gas-fueled, liquefied petroleum gas-fueled and methanol-fueled motorcycle HC and, if appropriate, NOX: (1) Zero the analyzers and obtain a stable zero reading. Recheck after tests. (2... CH3OH (methanol-fueled vehicles), introduce test samples into the gas chromatograph and measure the...

40 CFR 86.540-90 - Exhaust sample analysis.

Code of Federal Regulations, 2011 CFR

2011-07-01

..., gasoline-fueled, natural gas-fueled, liquefied petroleum gas-fueled and methanol-fueled motorcycle HC and, if appropriate, NOX: (1) Zero the analyzers and obtain a stable zero reading. Recheck after tests. (2... CH3OH (methanol-fueled vehicles), introduce test samples into the gas chromatograph and measure the...

40 CFR 86.1540 - Idle exhaust sample analysis.

Code of Federal Regulations, 2011 CFR

2011-07-01

... Regulations for Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New Methanol-Fueled...

30 CFR 36.43 - Determination of exhaust-gas composition.

Code of Federal Regulations, 2010 CFR

2010-07-01

... of fuel consumption, pressures, temperatures, and other data significant in the safe operation of diesel equipment. (b) Exhaust-gas samples shall be analyzed for carbon dioxide, oxygen, carbon monoxide....45). The engine shall be at temperature equilibrium before exhaust-gas samples are collected or other...

30 CFR 36.43 - Determination of exhaust-gas composition.

Code of Federal Regulations, 2013 CFR

2013-07-01

... of fuel consumption, pressures, temperatures, and other data significant in the safe operation of diesel equipment. (b) Exhaust-gas samples shall be analyzed for carbon dioxide, oxygen, carbon monoxide....45). The engine shall be at temperature equilibrium before exhaust-gas samples are collected or other...

30 CFR 36.43 - Determination of exhaust-gas composition.

Code of Federal Regulations, 2012 CFR

2012-07-01

... of fuel consumption, pressures, temperatures, and other data significant in the safe operation of diesel equipment. (b) Exhaust-gas samples shall be analyzed for carbon dioxide, oxygen, carbon monoxide....45). The engine shall be at temperature equilibrium before exhaust-gas samples are collected or other...

30 CFR 36.43 - Determination of exhaust-gas composition.

Code of Federal Regulations, 2014 CFR

2014-07-01

... of fuel consumption, pressures, temperatures, and other data significant in the safe operation of diesel equipment. (b) Exhaust-gas samples shall be analyzed for carbon dioxide, oxygen, carbon monoxide....45). The engine shall be at temperature equilibrium before exhaust-gas samples are collected or other...

30 CFR 36.43 - Determination of exhaust-gas composition.

Code of Federal Regulations, 2011 CFR

2011-07-01

... of fuel consumption, pressures, temperatures, and other data significant in the safe operation of diesel equipment. (b) Exhaust-gas samples shall be analyzed for carbon dioxide, oxygen, carbon monoxide....45). The engine shall be at temperature equilibrium before exhaust-gas samples are collected or other...

DEVELOPMENT OF A PROPORTIONAL SAMPLER FOR AUTOMOBILE EXHAUST EMISSIONS TESTING

EPA Science Inventory

The report describes the development of a device that is capable of sampling gaseous emissions from automobiles. The device samples exhaust gases at a mass rate that is proportional to the total exhaust gas mass flow rate, which is measured using an ultrasonic vortex flowmeter. T...

40 CFR 86.140-94 - Exhaust sample analysis.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) and (2) of this section if required. (4) Check flow rates and pressures. (5) Measure THC, CO, CO2, CH4... accomplished by either of the following methods: (i) Close heated valve in THC sample (see Figures B94-5 or B94... pressure. (ii) Connect zero and span line directly to THC sample probe and introduce gases at a flow rate...

40 CFR 86.140-94 - Exhaust sample analysis.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) and (2) of this section if required. (4) Check flow rates and pressures. (5) Measure THC, CO, CO2, CH4... accomplished by either of the following methods: (i) Close heated valve in THC sample (see Figures B94-5 or B94... pressure. (ii) Connect zero and span line directly to THC sample probe and introduce gases at a flow rate...

40 CFR 86.140-94 - Exhaust sample analysis.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) and (2) of this section if required. (4) Check flow rates and pressures. (5) Measure THC, CO, CO2, CH4... accomplished by either of the following methods: (i) Close heated valve in THC sample (see Figures B94-5 or B94... pressure. (ii) Connect zero and span line directly to THC sample probe and introduce gases at a flow rate...

40 CFR Appendix B to Subpart S of... - Test Procedures

Code of Federal Regulations, 2010 CFR

2010-07-01

... percent or the vehicle's engine stalls at any time during the test sequence. (4) Multiple exhaust pipes. Exhaust gas concentrations from vehicle engines equipped with multiple exhaust pipes shall be sampled... pipes. Exhaust gas concentrations from vehicle engines equipped with multiple exhaust pipes shall be...

[Polycyclic aromatic hydrocarbons in ultrafine particles of diesel exhaust fumes--the use of ultrafast liquid chromatography].

PubMed

Małgorzata Szewczyńska; Małgorzata Pośniak

2014-01-01

The article presents the results of the determination of polycyclic aromatic hydrocarbons (PAHs) in the fine par ticles fraction emitted from 3 types of diesel fuels using ultra-high pressure liquid chromatography. Samples of diesel Eco, Verwa and Bio exhaust combustion fumes were generated at the model station which consisted of a diesel engine from the 2007 Diesel TDI 2.0. Personal Cascade Sioutas Impactor (IPCSI) with Teflon filters was used to collect samples of exhaust fume ultrafine particles. PAHs adsorbed on particulate fractions were analyzed by ultra-high pressure liquid chromatography with fluorescence detection (UHPLC/FL). Phenanthrene, fluoranthene, pyrene and chrysene present the highest concentration in the particulate matter emitted by an engine. The total contents of fine particles collected during engine operation on fuels Eco, Verwa and Bio were 134.2 μg/g, 183.8 μg/g and 153.4 μg/g, respectively, which makes 75%, 90% and 83% of the total PAHs, respectively. The highest content of benzo(a)pyrene determined in particles emitted during the combustion of fuels Eco and Bio was 1.5 μg/g and 1 μg/g, respectively. The study of the PAH concentration in the particles of fine fraction below 0.25 μm emitted from different fuels designed for diesel engines indicate that the exhaust gas content of carcinogens, including PAHs deposited on particulates, is still significant, regardless of the fuel. Application of ultrahigh pressure liquid chromatography with fluorescence detection for the analysis ofPAHs in the particles emitted in the fine fraction of diesel exhaust allowed to shorten the analysis time from 35 min to 8 min.

40 CFR 1065.245 - Sample flow meter for batch sampling.

Code of Federal Regulations, 2011 CFR

2011-07-01

... POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Measurement Instruments Flow-Related Measurements § 1065.245... difference between a diluted exhaust sample flow meter and a dilution air meter to calculate raw exhaust flow...

40 CFR 1065.245 - Sample flow meter for batch sampling.

Code of Federal Regulations, 2014 CFR

2014-07-01

... POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Measurement Instruments Flow-Related Measurements § 1065.245... difference between a diluted exhaust sample flow meter and a dilution air meter to calculate raw exhaust flow...

40 CFR 1065.245 - Sample flow meter for batch sampling.

Code of Federal Regulations, 2013 CFR

2013-07-01

... POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Measurement Instruments Flow-Related Measurements § 1065.245... difference between a diluted exhaust sample flow meter and a dilution air meter to calculate raw exhaust flow...

40 CFR 1065.245 - Sample flow meter for batch sampling.

Code of Federal Regulations, 2012 CFR

2012-07-01

... POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Measurement Instruments Flow-Related Measurements § 1065.245... difference between a diluted exhaust sample flow meter and a dilution air meter to calculate raw exhaust flow...

Effluent sampling of Scout D and Delta launch vehicle exhausts

NASA Technical Reports Server (NTRS)

Hulten, W. C.; Storey, R. W.; Gregory, G. L.; Woods, D. C.; Harris, F. S., Jr.

1974-01-01

Characterization of engine-exhaust effluents (hydrogen chloride, aluminum oxide, carbon dioxide, and carbon monoxide) has been attempted by conducting field experiments monitoring the exhaust cloud from a Scout-Algol III vehicle launch and a Delta-Thor vehicle launch. The exhaust cloud particulate size number distribution (total number of particles as a function of particle diameter), mass loading, morphology, and elemental composition have been determined within limitations. The gaseous species in the exhaust cloud have been identified. In addition to the ground-based measurements, instrumented aircraft flights through the low-altitude, stabilized-exhaust cloud provided measurements which identified CO and HCI gases and Al2O3 particles. Measurements of the initial exhaust cloud during formation and downwind at several distances have established sampling techniques which will be used for experimental verification of model predictions of effluent dispersion and fallout from exhaust clouds.

Age as a Risk Factor for Burnout Syndrome in Nursing Professionals: A Meta-Analytic Study.

PubMed

Gómez-Urquiza, José L; Vargas, Cristina; De la Fuente, Emilia I; Fernández-Castillo, Rafael; Cañadas-De la Fuente, Guillermo A

2017-04-01

Although past research has highlighted the possibility of a direct relationship between the age of nursing professionals and burnout syndrome, results have been far from conclusive. The aim of this study was to conduct a wider analysis of the influence of age on the three dimensions of burnout syndrome (emotional exhaustion, depersonalization, and personal accomplishment) in nurses. We performed a meta-analysis of 51 publications extracted from health sciences and psychology databases that fulfilled the inclusion criteria. There were 47 reports of information on emotional exhaustion in 50 samples, 39 reports on depersonalization for 42 samples, and 31 reports on personal accomplishment in 34 samples. The mean effect sizes indicated that younger age was a significant factor in the emotional exhaustion and depersonalization of nurses, although it was somewhat less influential in the dimension of personal accomplishment. Because of heterogeneity in the effect sizes, moderating variables that might explain the association between age and burnout were also analyzed. Gender, marital status, and study characteristics moderated the relationship between age and burnout and may be crucial for the identification of high-risk groups. More research is needed on other variables for which there were only a small number of studies. Identification of burnout risk factors will facilitate establishment of burnout prevention programs for nurses. © 2016 Wiley Periodicals, Inc. © 2016 Wiley Periodicals, Inc.

40 CFR 90.421 - Dilute gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2011 CFR

2011-07-01

... filter and HFID. Determine these gas temperatures by a temperature sensor located immediately upstream of... analytical system description. (a) General. The exhaust gas sampling system described in this section is...-CVS must conform to all of the requirements listed for the exhaust gas PDP-CVS in § 90.420 of this...

40 CFR 90.421 - Dilute gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2010 CFR

2010-07-01

... filter and HFID. Determine these gas temperatures by a temperature sensor located immediately upstream of... analytical system description. (a) General. The exhaust gas sampling system described in this section is...-CVS must conform to all of the requirements listed for the exhaust gas PDP-CVS in § 90.420 of this...

Clinical supervision, emotional exhaustion, and turnover intention: a study of substance abuse treatment counselors in the Clinical Trials Network of the National Institute on Drug Abuse.

PubMed

Knudsen, Hannah K; Ducharme, Lori J; Roman, Paul M

2008-12-01

An intriguing hypothesis is that clinical supervision may protect against counselor turnover. This idea has been mentioned in recent discussions of the substance abuse treatment workforce. To test this hypothesis, we extend our previous research on emotional exhaustion and turnover intention among counselors by estimating the associations between clinical supervision and these variables in a large sample (N = 823). An exploratory analysis reveals that clinical supervision was negatively associated with emotional exhaustion and turnover intention. Given our previous findings that emotional exhaustion and turnover intention were associated with job autonomy, procedural justice, and distributive justice, we estimate a structural equation model to examine whether these variables mediated clinical supervision's associations with emotional exhaustion and turnover intention. These data support the fully mediated model. We found that the perceived quality of clinical supervision is strongly associated with counselors' perceptions of job autonomy, procedural justice, and distributive justice, which are, in turn, associated with emotional exhaustion and turnover intention. These data offer support for the protective role of clinical supervision in substance abuse treatment counselors' turnover and occupational well-being.

Sample treatments prior to capillary electrophoresis-mass spectrometry.

PubMed

Hernández-Borges, Javier; Borges-Miquel, Teresa M; Rodríguez-Delgado, Miguel Angel; Cifuentes, Alejandro

2007-06-15

Sample preparation is a crucial part of chemical analysis and in most cases can become the bottleneck of the whole analytical process. Its adequacy is a key factor in determining the success of the analysis and, therefore, careful selection and optimization of the parameters controlling sample treatment should be carried out. This work revises the different strategies that have been developed for sample preparation prior to capillary electrophoresis-mass spectrometry (CE-MS). Namely the present work presents an exhaustive and critical revision of the different samples treatments used together with on-line CE-MS including works published from January 2000 to July 2006.

40 CFR 86.210-08 - Exhaust gas sampling system; Diesel-cycle vehicles not requiring particulate emissions measurements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... detector (HFID) (375 °±20 °F (191 °±11 °C)) sample for total hydrocarbon (THC) analysis. The HFID sample... integrated measurement of diluted THC is required. Unless compensation for varying mass flow is made, a constant mass flow system must be used to ensure a proportional THC measurement. (2) For natural gas-fueled...

40 CFR 86.210-08 - Exhaust gas sampling system; Diesel-cycle vehicles not requiring particulate emissions measurements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... detector (HFID) (375 °±20 °F (191 °±11 °C)) sample for total hydrocarbon (THC) analysis. The HFID sample... integrated measurement of diluted THC is required. Unless compensation for varying mass flow is made, a constant mass flow system must be used to ensure a proportional THC measurement. (2) For natural gas-fueled...

40 CFR 90.313 - Analyzers required.

Code of Federal Regulations, 2010 CFR

2010-07-01

... of the exhaust gas at the sample probe is below 190 °C, the temperature of the valves, pipe work, and... temperature of the exhaust gas at the sample probe is above 190 °C, the temperature of the valves, pipe work... and carbon dioxide measurements must be made on a dry basis (for raw exhaust measurement only...

40 CFR 91.421 - Dilute gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2010 CFR

2010-07-01

... filter and HFID. Determine these gas temperatures by a temperature sensor located immediately upstream of.... (a) General. The exhaust gas sampling system described in this section is designed to measure the...-CVS must conform to all of the requirements listed for the exhaust gas PDP-CVS in § 91.420 of this...

40 CFR 91.421 - Dilute gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2011 CFR

2011-07-01

... filter and HFID. Determine these gas temperatures by a temperature sensor located immediately upstream of.... (a) General. The exhaust gas sampling system described in this section is designed to measure the...-CVS must conform to all of the requirements listed for the exhaust gas PDP-CVS in § 91.420 of this...

40 CFR 86.537-90 - Dynamometer test runs.

Code of Federal Regulations, 2014 CFR

2014-07-01

... “transient” formaldehyde exhaust sample, the “transient” dilution air sample bag, the “transient” methanol... start “transient” exhaust and dilution air bag samples to the analytical system and process the samples... Section 86.537-90 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS...

40 CFR 86.537-90 - Dynamometer test runs.

Code of Federal Regulations, 2012 CFR

2012-07-01

... “transient” formaldehyde exhaust sample, the “transient” dilution air sample bag, the “transient” methanol... start “transient” exhaust and dilution air bag samples to the analytical system and process the samples... Section 86.537-90 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS...

40 CFR 86.537-90 - Dynamometer test runs.

Code of Federal Regulations, 2013 CFR

2013-07-01

... “transient” formaldehyde exhaust sample, the “transient” dilution air sample bag, the “transient” methanol... start “transient” exhaust and dilution air bag samples to the analytical system and process the samples... Section 86.537-90 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS...

Getting something for nothing: Regeneration of peptide signals from apparently exhausted MALDI samples by “waterboarding"

USDA-ARS?s Scientific Manuscript database

An often cited advantage of MALDI-MS is the ability to archive and reuse sample plates after the initial analysis is complete. However, experience demonstrates that the peptide ion signals decay rapidly as the number of laser shots becomes large. Thus, the signal level obtainable from an archived sa...

Odor and odorous chemical emissions from dairy and swine facilities: Part 5-Simultaneous chemical and sensory analysis with Gas Chromatography - Mass Spectrometry - Olfactometry

USDA-ARS?s Scientific Manuscript database

Simultaneous chemical and sensory analyses using gas chromatography-mass spectrometry-olfactometry (GC-MS-O) for air samples collected at barn exhaust fans were used for quantification and ranking of odor impact of target odorous gases. Fifteen target odorous VOCs (odorants) were selected. Air sampl...

Exhaustive Search for Sparse Variable Selection in Linear Regression

NASA Astrophysics Data System (ADS)

Igarashi, Yasuhiko; Takenaka, Hikaru; Nakanishi-Ohno, Yoshinori; Uemura, Makoto; Ikeda, Shiro; Okada, Masato

2018-04-01

We propose a K-sparse exhaustive search (ES-K) method and a K-sparse approximate exhaustive search method (AES-K) for selecting variables in linear regression. With these methods, K-sparse combinations of variables are tested exhaustively assuming that the optimal combination of explanatory variables is K-sparse. By collecting the results of exhaustively computing ES-K, various approximate methods for selecting sparse variables can be summarized as density of states. With this density of states, we can compare different methods for selecting sparse variables such as relaxation and sampling. For large problems where the combinatorial explosion of explanatory variables is crucial, the AES-K method enables density of states to be effectively reconstructed by using the replica-exchange Monte Carlo method and the multiple histogram method. Applying the ES-K and AES-K methods to type Ia supernova data, we confirmed the conventional understanding in astronomy when an appropriate K is given beforehand. However, we found the difficulty to determine K from the data. Using virtual measurement and analysis, we argue that this is caused by data shortage.

Effects of developer exhaustion on DFL Contrast FV-58 and Kodak Insight dental films.

PubMed

de Carvalho, Fabiano Pachêco; da Silveira, M M F; Frazão, M A G; de Santana, S T; dos Anjos Pontual, M L

2011-09-01

The aim of this study was to compare the properties of the DFL Contrast FV-58 F-speed film (DFL Co., Rio de Janerio, Brazil) with the Kodak Insight E/F speed film (Eastman Kodak, Rochester, NY) in fresh and exhausted processing solutions. The parameters studied were the speed, average gradient and latitude. Five samples of each type of film were exposed under standardized conditions over 5 weeks. The films were developed in fresh and progressively exhausted processing solutions. Characteristic curves were constructed from values of optical density and radiation dose and were used to calculate the parameters. An analysis of variance was performed separately for film type and time. DFL Contrast FV-58 film has a speed and average gradient that is significantly higher than Insight film, whereas the values of latitude are lower. Exhausted processing solutions were not significant in the parameters studied. DFL Contrast FV-58 film has stable properties when exhausted manual processing solutions are used and can be recommended for use in dental practice, contributing to dose reduction.

Effects of developer exhaustion on DFL Contrast FV-58 and Kodak Insight dental films

PubMed Central

de Carvalho, FP; da Silveira, MMF; Frazão, MAG; de Santana, ST; dos Anjos Pontual, ML

2011-01-01

Objectives The aim of this study was to compare the properties of the DFL Contrast FV-58 F-speed film (DFL Co., Rio de Janerio, Brazil) with the Kodak Insight E/F speed film (Eastman Kodak, Rochester, NY) in fresh and exhausted processing solutions. The parameters studied were the speed, average gradient and latitude. Methods Five samples of each type of film were exposed under standardized conditions over 5 weeks. The films were developed in fresh and progressively exhausted processing solutions. Characteristic curves were constructed from values of optical density and radiation dose and were used to calculate the parameters. An analysis of variance was performed separately for film type and time. Results DFL Contrast FV-58 film has a speed and average gradient that is significantly higher than Insight film, whereas the values of latitude are lower. Exhausted processing solutions were not significant in the parameters studied. Conclusion DFL Contrast FV-58 film has stable properties when exhausted manual processing solutions are used and can be recommended for use in dental practice, contributing to dose reduction. PMID:21831975

Resilience as a Moderator of Psychological Health in Situations of Chronic Stress (Burnout) in a Sample of Hospital Nurses.

PubMed

García-Izquierdo, Mariano; Meseguer de Pedro, Mariano; Ríos-Risquez, Mª Isabel; Sánchez, Mª Isabel Soler

2018-03-01

To analyze the role played by resilience in the dimensions that constitute burnout syndrome and, through that, the psychological health of a sample of nurses working at hospital centers. Cross-sectional design, with a questionnaire as the tool. The sample consisted of 537 nurses from three public hospitals in Murcia, Spain. The questionnaire contained measures of the following variables: resilience, the three dimensions of burnout (emotional exhaustion, cynicism, and professional efficacy), and general psychological health, as well as sociodemographic and employment information. The emotional exhaustion and cynicism dimensions of burnout were significantly linked to psychological health in the manner expected, but this was not the case for professional efficacy. A stepwise multiple regression analysis revealed the moderating role of resilience on the emotional exhaustion and cynicism dimensions, as well as on psychological health. This study highlights the moderating role of resilience on burnout and psychological health. The practical implications of the results are discussed for the implementation of measures to increase resilience as a personal resource in order to improve the health and work performance of these professionals. © 2017 Sigma Theta Tau International.

Air pollution from aircraft. [jet exhaust - aircraft fuels/combustion efficiency

NASA Technical Reports Server (NTRS)

Heywood, J. B.; Chigier, N. A.

1975-01-01

A model which predicts nitric oxide and carbon monoxide emissions from a swirl can modular combustor is discussed. A detailed analysis of the turbulent fuel-air mixing process in the swirl can module wake region is reviewed. Hot wire anemometry was employed, and gas sampling analysis of fuel combustion emissions were performed.

40 CFR 86.1310-90 - Exhaust gas sampling and analytical system; diesel engines.

Code of Federal Regulations, 2012 CFR

2012-07-01

... petroleum fuel or a non-heated flame ionization detector may be used. (3) Methanol-fueled engines require...); or (iii) Omitting the duct and performing the exhaust gas dilution function at the engine exhaust... two steps to a temperature never greater than 125 °F (51.7 °C) at the primary sample filter. A backup...

40 CFR 86.1310-90 - Exhaust gas sampling and analytical system; diesel engines.

Code of Federal Regulations, 2013 CFR

2013-07-01

... petroleum fuel or a non-heated flame ionization detector may be used. (3) Methanol-fueled engines require...); or (iii) Omitting the duct and performing the exhaust gas dilution function at the engine exhaust... two steps to a temperature never greater than 125 °F (51.7 °C) at the primary sample filter. A backup...

Mass spectrometry profiling of oxylipins, endocannabinoids, and N-acylethanolamines in human lung lavage fluids reveals responsiveness of prostaglandin E2 and associated lipid metabolites to biodiesel exhaust exposure.

PubMed

Gouveia-Figueira, Sandra; Karimpour, Masoumeh; Bosson, Jenny A; Blomberg, Anders; Unosson, Jon; Pourazar, Jamshid; Sandström, Thomas; Behndig, Annelie F; Nording, Malin L

2017-04-01

The adverse effects of petrodiesel exhaust exposure on the cardiovascular and respiratory systems are well recognized. While biofuels such as rapeseed methyl ester (RME) biodiesel may have ecological advantages, the exhaust generated may cause adverse health effects. In the current study, we investigated the responses of bioactive lipid mediators in human airways after biodiesel exhaust exposure using lipidomic profiling methods. Lipid mediator levels in lung lavage were assessed following 1-h biodiesel exhaust (average particulate matter concentration, 159 μg/m 3 ) or filtered air exposure in 15 healthy individuals in a double-blinded, randomized, controlled, crossover study design. Bronchoscopy was performed 6 h post exposure and lung lavage fluids, i.e., bronchial wash (BW) and bronchoalveolar lavage (BAL), were sequentially collected. Mass spectrometry methods were used to detect a wide array of oxylipins (including eicosanoids), endocannabinoids, N-acylethanolamines, and related lipid metabolites in the collected BW and BAL samples. Six lipids in the human lung lavage samples were altered following biodiesel exhaust exposure, three from BAL samples and three from BW samples. Of these, elevated levels of PGE 2 , 12,13-DiHOME, and 13-HODE, all of which were found in BAL samples, reached Bonferroni-corrected significance. This is the first study in humans reporting responses of bioactive lipids following biodiesel exhaust exposure and the most pronounced responses were seen in the more peripheral and alveolar lung compartments, reflected by BAL collection. Since the responsiveness and diagnostic value of a subset of the studied lipid metabolites were established in lavage fluids, we conclude that our mass spectrometry profiling method is useful to assess effects of human exposure to vehicle exhaust.

Open port sampling interface

DOE Office of Scientific and Technical Information (OSTI.GOV)

Van Berkel, Gary J

A system for sampling a sample material includes a probe which can have an outer probe housing with an open end. A liquid supply conduit within the housing has an outlet positioned to deliver liquid to the open end of the housing. The liquid supply conduit can be connectable to a liquid supply for delivering liquid at a first volumetric flow rate to the open end of the housing. A liquid exhaust conduit within the housing is provided for removing liquid from the open end of the housing. A liquid exhaust system can be provided for removing liquid from themore » liquid exhaust conduit at a second volumetric flow rate, the first volumetric flow rate exceeding the second volumetric flow rate, wherein liquid at the open end will receive sample, liquid containing sample material will be drawn into and through the liquid exhaust conduit, and liquid will overflow from the open end.« less

Validation of Karolinska Exhaustion Scale: psychometric properties of a measure of exhaustion syndrome.

PubMed

Saboonchi, Fredrik; Perski, Aleksander; Grossi, Giorgio

2013-12-01

The syndrome of exhaustion is currently a medical diagnosis in Sweden. The description of the syndrome largely corresponds to the suggested core component of burnout, that is exhaustion. Karolinska Exhaustion Scale (KES) has been constructed to provide specific assessment of exhaustion in clinical and research settings. The purpose of the present study was to examine the psychometric properties of this scale in its original and revised versions by examining the factorial structure and measures of convergent and discriminant validity. Data gathered from two independent samples (n1 = 358 & n2 = 403) consisting of patients diagnosed with 'reaction to severe stress, and adjustment disorder' were subjected to confirmatory factor analysis. The study's instruments were Karolinska Exhaustion Scale and Shirom Melam Burnout Measure. Correlation analyses were employed to follow up the established factorial structure of the scale. The study was ethically approved by Karolinska Institute regional ethic committee. The findings demonstrated adequate fit of the data to the measurement model provided by the revised version of KES Limitations: The main limitation of the present study is the lack of a gold standard of exhaustion for direct comparison with KES. (KES-26) and partially supported convergent validity and discriminant validity of the scale. The demonstrated psychometric properties of KES-26 indicate sound construct validity for this scale encouraging use of this scale in assessment of exhaustion. The factorial structure of KES-26 may also be used to provide information concerning possible different clinical profiles. © 2012 The Authors Scandinavian Journal of Caring Sciences © 2012 Nordic College of Caring Science.

Development of naval diesel engine duty cycles for air exhaust emission environmental impact analysis. Master's thesis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Markle, S.P.

1994-05-01

A strategy for testing naval diesel engines for exhaust emissions was developed. A survey of existing international and national standard diesel engine duty cycles was conducted. All were found to be inadequate for testing and certification of engine exhaust emissions from naval diesel powered ships. Naval ship data covering 11,500 hours of engine operation of four U.S. Navy LSD 41 Class amphibious ships was analyzed to develop a 27 point class operating profile. A procedure combining ship hull form characteristics, ship propulsion plant parameters, and ship operating profile was detailed to derive an 11-Mode duty cycle representative for testing LSDmore » 41 Class propulsion diesel engines. A similar procedure was followed for ship service diesel engines. Comparisons with industry accepted duty cycles were conducted using exhaust emission contour plots for the Colt-Pielstick PC-4B diesel engines. Results showed the 11-Mode LSD 41 Class Duty Cycle best predicted ship propulsion engine emissions compared to the 27 point operating profile propeller curve. The procedure was applied to T-AO 187 Class with similar results. The application of civilian industry standards to measure naval diesel ship propulsion engine exhaust emissions was found to be inadequate. Engine exhaust flow chemistry post turbocharger was investigated using the SANDIA Lab computer tool CHEMKIN. Results showed oxidation and reduction reactions within exhaust gases are quenched in the exhaust stack. Since the exhaust stream in the stack is unreactive, emission sampling may be performed where most convenient. A proposed emission measurement scheme for LSD 41 Class ships was presented.« less

Psychosocial working conditions and exhaustion in a working population sample of Swedish middle-aged men and women.

PubMed

Lindeberg, Sara I; Rosvall, Maria; Choi, Bongkyoo; Canivet, Catarina; Isacsson, Sven-Olof; Karasek, Robert; Ostergren, Per-Olof

2011-04-01

Exhaustion is a concept of interest for both occupational health research and stress-disease theory research. The aim of the present study was to explore associations between chronic stressors, in terms of psychosocial working conditions, and exhaustion in a Swedish middle-aged population sample. A vocationally active population sample of the Malmö Shoulder and Neck Study cohort, comprising 2555 men and 2466 women between 45 and 64 years of age, was used. Psychosocial working conditions, assessed by means of the demand-control-support model, were measured longitudinally with a 1-year interval. Exhaustion was assessed by the SF-36 vitality scale and measured at follow-up, yielding a cross-sectional study design. Exhaustion was twice as common in women as in men. High psychological job demands, low job control and low job support were independently associated with exhaustion in both men and women. These associations remained after controlling for a variety of potential confounders and mediators, including socio-demographic factors, lifestyle factors, musculoskeletal pain, disease, other work-related factors (including physical workload) and non-work-related factors. High demands in combination with low control (job strain), and job strain combined with low job support (iso-strain), increased the risk for exhaustion. Psychosocial working conditions seem to contribute to exhaustion in middle-aged men and women. Future research should include exploration of exhaustion as a possible mediator between work stress and disease, as well as exploration of other chronic stressors, including non-work-related stressors, regarding their effects on exhaustion in men and women.

40 CFR 87.82 - Sampling and analytical procedures for measuring smoke exhaust emissions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) Definitions. Test Procedures for Engine Smoke Emissions (Aircraft Gas Turbine Engines) § 87.82 Sampling and analytical procedures for measuring smoke exhaust...

Sampling and physical characterization of diesel exhaust aerosols. SAE Paper 770720

DOE Office of Scientific and Technical Information (OSTI.GOV)

Verrant, J.A.; Kittelson, D.A.

Diesel exhaust aerosols are highly dynamic and therefore, difficult to sample without introducing falsification. This paper describes a study of these aerosols using a rapid dilution sampling system and an electrical aerosol analyzer. An Onan single cylinder indirect injection engine was used as an exhaust source. The sampler diluted the exhaust with clean air in ratios of 400:1 to 600:1 in order to prevent sample falsification by condensation and coagulation. The electrical aerosol analyzer was used to determine particle size and concentration. Volume concentration in the exhaust ranged from 2000 to 50,000 ..mu.. m/sup 3/ cm/sup -3/ which correspond tomore » mass loadings of 2.0 to 50 mg m/sup -3/ (assuming a density of 1 gm cm/sup -3/). Volume geometric mean diameters ranged from 0.12 to 0.19 ..mu..m. Evaporation and coagulation effects on diesel aerosols were observed by aging in a Teflon holding bag. A simple evaporation model was fit to the decrease of aerosol volume concentration with time. The fit revealed that the aerosols evaporated as if they were composed of normal paraffins in the 350 to 500 molecular weight range. Although the sample dilution system used in this study may alter the sample somewhat, it is probably analogous to what happens at the tailpipe of a vehicle. Measurements taken on a test track in the exhaust plume of a Peugeot 504 diesel showed aerosol size distributions very similar to those measured in our laboratory studies.« less

Correlates of Injury-forced Work Reduction for Massage Therapists and Bodywork Practitioners.

PubMed

Blau, Gary; Monos, Christopher; Boyer, Ed; Davis, Kathleen; Flanagan, Richard; Lopez, Andrea; Tatum, Donna S

2013-01-01

Injury-forced work reduction (IFWR) has been acknowledged as an all-too-common occurrence for massage therapists and bodywork practitioners (M & Bs). However, little prior research has specifically investigated demographic, work attitude, and perceptual correlates of IFWR among M & Bs. To test two hypotheses, H1 and H2. H1 is that the accumulated cost variables set ( e.g., accumulated costs, continuing education costs) will account for a significant amount of IFWR variance beyond control/demographic (e.g., social desirability response bias, gender, years in practice, highest education level) and work attitude/perception variables (e.g., job satisfaction, affective occupation commitment, occupation identification, limited occupation alternatives) sets. H2 is that the two exhaustion variables (i.e., physical exhaustion, work exhaustion) set will account for significant IFWR variance beyond control/demographic, work attitude/perception, and accumulated cost variables sets. An online survey sample of 2,079 complete-data M & Bs was collected. Stepwise regression analysis was used to test the study hypotheses. The research design first controlled for control/demographic (Step1) and work attitude/perception variables sets (Step 2), before then testing for the successive incremental impact of two variable sets, accumulated costs (Step 3) and exhaustion variables (Step 4) for explaining IFWR. RESULTS SUPPORTED BOTH STUDY HYPOTHESES: accumulated cost variables set (H1) and exhaustion variables set (H2) each significantly explained IFWR after the control/demographic and work attitude/perception variables sets. The most important correlate for explaining IFWR was higher physical exhaustion, but work exhaustion was also significant. It is not just physical "wear and tear", but also "mental fatigue", that can lead to IFWR for M & Bs. Being female, having more years in practice, and having higher continuing education costs were also significant correlates of IFWR. Lower overall levels of work exhaustion, physical exhaustion, and IFWR were found in the present sample. However, since both types of exhaustion significantly and positively impact IFWR, taking sufficient time between massages and, if possible, varying one's massage technique to replenish one's physical and mental energy seem important. Failure to take required continuing education units, due to high costs, also increases risk for IFWR. Study limitations and future research issues are discussed.

Ball assisted device for analytical surface sampling

DOEpatents

ElNaggar, Mariam S; Van Berkel, Gary J; Covey, Thomas R

2015-11-03

A system for sampling a surface includes a sampling probe having a housing and a socket, and a rolling sampling sphere within the socket. The housing has a sampling fluid supply conduit and a sampling fluid exhaust conduit. The sampling fluid supply conduit supplies sampling fluid to the sampling sphere. The sampling fluid exhaust conduit has an inlet opening for receiving sampling fluid carried from the surface by the sampling sphere. A surface sampling probe and a method for sampling a surface are also disclosed.

40 CFR 86.527-90 - Test procedures, overview.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Section 86.527-90 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... constant volume (variable dilution) sampler. (d) Except in cases of component malfunction or failure, all... emissions measurements are made. For exhaust testing, this requires sampling and analysis of the dilution...

Prevalence of Burnout Syndrome in Emergency Nurses: A Meta-Analysis.

PubMed

Gómez-Urquiza, Jose Luis; De la Fuente-Solana, Emilia I; Albendín-García, Luis; Vargas-Pecino, Cristina; Ortega-Campos, Elena M; Cañadas-De la Fuente, Guillermo A

2017-10-01

To determine the prevalence of burnout (based on the Maslach Burnout Inventory on the 3 dimensions of high Emotional Exhaustion, high Depersonalization, and low Personal Accomplishment) among emergency nurses. A search of the terms "emergency AND nurs* AND burnout" was conducted using the following databases: CINAHL, Cochrane, CUIDEN, IBECS, LILACS, PubMed, ProQuest, PsycINFO, SciELO, and Scopus. Thirteen studies were included for the Maslach Burnout Inventory subscales of Emotional Exhaustion and Depersonalization and 11 studies for the subscale of low Personal Accomplishment. The total sample of nurses was 1566. The estimated prevalence of each subscale was 31% (95% CI, 20-44) for Emotional Exhaustion, 36% (95% CI, 23-51) for Depersonalization, and 29% (95% CI, 15-44) for low Personal Accomplishment. The prevalence of burnout syndrome in emergency nurses is high; about 30% of the sample was affected with at least 1 of the 3 Maslach Burnout Inventory subscales. Working conditions and personal factors should be taken into account when assessing burnout risk profiles of emergency nurses. ©2017 American Association of Critical-Care Nurses.

SAMPLE CHARACTERIZATION OF AUTOMOBILE AND FORKLIFT DIESEL EXHAUST PARTICLES AND COMPARATIVE PULMONARY TOXICITY IN MICE

EPA Science Inventory

Abstract

Two samples of diesel exhaust particles (DEP) predominate in DEP health effects research: an automobile-source DEP (A-DEP) sample and the National Institute of Standards Technology (NIST) standard reference material (SRM 2975) generated from a forklift engine...

DOE Office of Scientific and Technical Information (OSTI.GOV)

Van Berkel, Gary J.

A system for sampling a sample material includes a probe which can have an outer probe housing with an open end. A liquid supply conduit within the housing has an outlet positioned to deliver liquid to the open end of the housing. The liquid supply conduit can be connectable to a liquid supply for delivering liquid at a first volumetric flow rate to the open end of the housing. A liquid exhaust conduit within the housing is provided for removing liquid from the open end of the housing. A liquid exhaust system can be provided for removing liquid from themore » liquid exhaust conduit at a second volumetric flow rate, the first volumetric flow rate exceeding the second volumetric flow rate, wherein liquid at the open end will receive sample, liquid containing sample material will be drawn into and through the liquid exhaust conduit, and liquid will overflow from the open end.« less

Analysis of particle and vapour phase PAHs from the personal air samples of bus garage workers exposed to diesel exhaust.

PubMed

Kuusimaki, Leea; Peltonen, Kimmo; Mutanen, Pertti; Savela, Kirsti

2003-07-01

The levels of particle and vapour phase polycyclic aromatic hydrocarbons (PAHs) derived from the diesel exhaust compounds in bus garage work were measured in winter and in summer. Five personal air samples were collected from the breathing zones of 22 garage workers every other day of consecutive weeks. Control samples (n = 22) were collected from office workers in Helsinki. Fifteen PAHs in the air samples were analysed by HPLC using a fluorescence detector. Statistically significant differences were observed between total PAH levels of the exposed workers (2241 and 1245 ng/m(3)) and the control group (254 and 275 ng/m(3)) in both winter (P < 0.001) and summer (P < 0.001). Phenanthrene, pyrene, benzo[ghi]perylene and fluoranthene were the major compounds in the particle phase, and naphthalene, phenanthrene and fluorene in the vapour phase. About 98% of PAHs measured were related to the vapour phase compounds, whereas the high molecular weight PAH compounds were detected only in the particle phase. The PAH levels in the garages were twice as high (P < 0.001) in winter as in summer. Even though the exposure levels were low in the bus garages, the low level does not allow conclusions to be drawn about the possible adverse health effects due to exposure to diesel exhaust.

On the contribution of polycyclic aromatic hydrocarbons to the carcinogenic impact of automobile exhaust condensate evaluated by local application onto mouse skin.

PubMed

Grimmer, G; Brune, H; Deutsch-Wenzel, R; Naujack, K W; Misfeld, J; Timm, J

1983-11-01

The objective of this investigation was to identify the substances chiefly responsible for the carcinogenicity of automobile exhaust condensate using topical application onto the skin of mice. This was performed by comparing the carcinogenic effect of various fractions with that of an unseparated sample of automobile exhaust condensate, tested in 3 different doses. The probit and Weibull analysis of the result shows: (a) The condensate, emitted from a gasoline-driven automobile provokes local tumors after long-term application to the dorsal skin of mice. The tumor incidence demonstrates a clear cut dose-response relationship. (b) The fraction of polycyclic aromatic hydrocarbons (PAH) containing more than 3 rings accounts for about 84-91% of the total carcinogenicity of automobile exhaust condensate. This fraction represents only about 3.5% by wt of the condensate. (c) The content of benzo[a]pyrene (BaP) (0.414 mg/g) accounts for 6-7.6% of the total carcinogenicity of automobile exhaust condensate, 15 selected PAHs for about 41%. (d) Regarding the minor effect of the PAH-free fraction (about 83% by wt), no hints for a cocarcinogenic activity were observed.

Burnout Syndrome Among Medical Students at One University in Serbia: Validity and Reliability of the Maslach Burnout Inventory-Student Survey.

PubMed

Ilic, Milena; Todorovic, Zeljko; Jovanovic, Milena; Ilic, Irena

2017-01-01

The Maslach Burnout Inventory-Student Survey (MBI-SS) contains 15 items that evaluate the following burnout dimensions: Emotional Exhaustion, Cynicism, and Academic Efficacy. The purpose of this study was to evaluate the dimensionality of the MBI-SS on a sample of Serbian medical students (N = 760). The overall Cronbach's α coefficient of the MBI-SS questionnaire was 0.757, while the Cronbach's α coefficients for Emotional Exhaustion, Cynicism, and Academic Efficacy were 0.869, 0.856, and 0.852, respectively. Principal Component Analysis with Oblimin rotation indicated 3 main components that explained 64.9% variance. The confirmatory factor analysis revealed good fit indices (χ 2 /df = 575.74/87, RMSEA = 0.086 (90% Confidence Interval for RMSEA = 0.079 to 0.092), CFI = 0.949, NNFI = 0.939, IFI = 0.949, GFI = 0.904) of the MBI-SS scale. The Serbian version of MBI-SS represents a valid and reliable instrument in the Serbian sample of medical students.

Fibrin clot structure remains unaffected in young, healthy individuals after transient exposure to diesel exhaust

PubMed Central

2010-01-01

Exposure to urban particulate matter has been associated with an increased risk of cardiovascular disease and thrombosis. We studied the effects of transient exposure to diesel particles on fibrin clot structure of 16 healthy individuals (age 21- 44). The subjects were randomly exposed to diesel exhaust and filtered air on two separate occasions. Blood samples were collected before exposure, and 2 and 6 hours after exposure. There were no significant changes on clot permeability, maximum turbidity, lag time, fibre diameter, fibre density and fibrinogen level between samples taken after diesel exhaust exposure and samples taken after filtered air exposure. These data show that there are no prothrombotic changes in fibrin clot structure in young, healthy individuals exposed to diesel exhaust. PMID:20565709

40 CFR 1065.130 - Engine exhaust.

Code of Federal Regulations, 2014 CFR

2014-07-01

....130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS... demonstrate compliance with the applicable standards. We recommend performing a chemical balance of fuel... before sampling. Extend the crankcase exhaust tube into the free stream of exhaust to avoid boundary...

40 CFR 1065.130 - Engine exhaust.

Code of Federal Regulations, 2013 CFR

2013-07-01

....130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS... ability to demonstrate compliance with the applicable standards. We recommend performing a chemical... before sampling. Extend the crankcase exhaust tube into the free stream of exhaust to avoid boundary...

40 CFR 1065.130 - Engine exhaust.

Code of Federal Regulations, 2012 CFR

2012-07-01

....130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS... ability to demonstrate compliance with the applicable standards. We recommend performing a chemical... before sampling. Extend the crankcase exhaust tube into the free stream of exhaust to avoid boundary...

40 CFR 1065.130 - Engine exhaust.

Code of Federal Regulations, 2011 CFR

2011-07-01

....130 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS... ability to demonstrate compliance with the applicable standards. We recommend performing a chemical... before sampling. Extend the crankcase exhaust tube into the free stream of exhaust to avoid boundary...

Associations between emotional exhaustion, social capital, workload, and latitude in decision-making among professionals working with people with disabilities.

PubMed

Kowalski, Christoph; Driller, Elke; Ernstmann, Nicole; Alich, Saskia; Karbach, Ute; Ommen, Oliver; Schulz-Nieswandt, Frank; Pfaff, Holger

2010-01-01

Many people working in human services in Western countries suffer from burnout, characterized by emotional exhaustion, depersonalization, and decreased personal performance. Prevention of emotional exhaustion (the first phase of burnout) constitutes a great challenge because emotional exhaustion may cause increasing turnover rates in staff and lead to a lesser quality of care. Prevention of emotional exhaustion requires knowledge of its predictors. The aim of this study was to investigate the associations between emotional exhaustion, social capital, workload, and latitude in decision-making among German professionals working in the care of persons with intellectual and physical disabilities. The study was based on a survey in a sheltered workshop and 5 homes for disabled persons with 175 professionals. Burnout was measured with the German version of the Maslach Burnout Inventory-General Survey (MBI-GS). A multivariate logistic regression analysis was computed. Logistic regression identified the following three significant predictors of emotional exhaustion in the sample: workload (OR, 4.192; CI, 2.136-8.227), latitude in decision-making (OR, 0.306; CI, 0.115-0.811), and male gender (OR, 4.123; CI, 1.796-9.462). Nagelkerke's Pseudo-R(2) was 0.344. The results of this study demonstrate that specific factors in work organization are associated with emotional exhaustion. Taking into account sociodemographic changes and the upcoming challenges for human services professionals, the results underline the importance of considering aspects of organization at the workplace to prevent burnout. Specific circumstances of male employees must be considered. Copyright 2009 Elsevier Ltd. All rights reserved.

Simultaneous determination of carbonyls and NO2 in exhausts of heavy-duty diesel trucks and transit buses by HPLC following 2,4-dinitrophenylhydrazine cartridge collection.

PubMed

Tang, Shida; Graham, Lisa; Shen, Ling; Zhou, Xianliang; Lanni, Thomas

2004-11-15

A method combining 2,4-dinitrophenylhydrazine (DNPH) cartridge sampling and high-performance liquid chromatography (HPLC) analysis has been used for the measurement of carbonyl and NO2 emissions from heavy-duty diesel trucks and transit buses. The reaction of NO2 with DNPH allows for the simultaneous and unambiguous determination of NO2 and carbonyl concentrations in exhaust samples. The potential coelution of the NO2-DNPH derivative with the formaldehyde-DNPH derivative under certain chromatographic conditions was investigated. Successful separation of these two species was achieved allowing for simultaneous determination of carbonyls and NO2 in the exhaust samples collected from heavy-duty diesel (HDD) trucks and diesel, diesel/electric hybrid, diesel equipped with the continuously regenerating technology (CRT) particle traps, and compressed natural gas (CNG) transit buses tested over various drive cycles. Elevated NO2 emissions from CRT-equipped buses were observed. The NO2/NOx volume ratios for HDD trucks and transit buses are discussed. A comparison of the DNPH derivatization with HPLC/UV-visible detection method with a chemiluminescence analyzer method for NO2 measurement is presented for a limited number of diesel/CRT and CNG buses.

A Comprehensive Program for Measurement of Military Aircraft Emissions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Mengdawn

2009-11-01

Emissions of gases and particulate matter by military aircraft were characterized inplume by 'extractive' and 'optical remote-sensing (ORS)' technologies. Non-volatile particle size distribution, number and mass concentrations were measured with good precision and reproducibly. Time-integrated particulate filter samples were collected and analyzed for smoke number, elemental composition, carbon contents, and sulfate. Observed at EEP the geometric mean diameter (as measured by the mobility diameter) generally increased as the engine power setting increased, which is consistent with downstream observations. The modal diameters at the downstream locations are larger than that at EEP at the same engine power level. The results indicatemore » that engine particles were processed by condensation, for example, leading to particle growth in-plume. Elemental analysis indicated little metals were present in the exhaust, while most of the exhaust materials in the particulate phase were carbon and sulfate (in the JP-8 fuel). CO, CO{sub 2}, NO, NO{sub 2}, SO{sub 2}, HCHO, ethylene, acetylene, propylene, and alkanes were measured. The last five species were most noticeable under engine idle condition. The levels of hydrocarbons emitted at high engine power level were generally below the detection limits. ORS techniques yielded real-time gaseous measurement, but the same techniques could not be extended directly to ultrafine particles found in all engine exhausts. The results validated sampling methodology and measurement techniques used for non-volatile particulate aircraft emissions, which also highlighted the needs for further research on sampling and measurement for volatile particulate matter and semi-volatile species in the engine exhaust especially at the low engine power setting.« less

40 CFR 86.209-94 - Exhaust gas sampling system; gasoline-fueled vehicles.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Exhaust gas sampling system; gasoline... Emission Regulations for 1994 and Later Model Year Gasoline-Fueled New Light-Duty Vehicles, New Light-Duty... sampling system; gasoline-fueled vehicles. The provisions of § 86.109-90 apply to this subpart. ...

40 CFR 86.209-94 - Exhaust gas sampling system; gasoline-fueled vehicles.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 19 2013-07-01 2013-07-01 false Exhaust gas sampling system; gasoline... Emission Regulations for 1994 and Later Model Year Gasoline-Fueled New Light-Duty Vehicles, New Light-Duty... sampling system; gasoline-fueled vehicles. The provisions of § 86.109-90 apply to this subpart. ...

40 CFR 86.209-94 - Exhaust gas sampling system; gasoline-fueled vehicles.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Exhaust gas sampling system; gasoline... Emission Regulations for 1994 and Later Model Year Gasoline-Fueled New Light-Duty Vehicles, New Light-Duty... sampling system; gasoline-fueled vehicles. The provisions of § 86.109-90 apply to this subpart. ...

40 CFR 86.209-94 - Exhaust gas sampling system; gasoline-fueled vehicles.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 19 2012-07-01 2012-07-01 false Exhaust gas sampling system; gasoline... Emission Regulations for 1994 and Later Model Year Gasoline-Fueled New Light-Duty Vehicles, New Light-Duty... sampling system; gasoline-fueled vehicles. The provisions of § 86.109-90 apply to this subpart. ...

Identification of brake wear particles and derivation of a quantitative tracer for brake dust at a major road

NASA Astrophysics Data System (ADS)

Gietl, Johanna K.; Lawrence, Roy; Thorpe, Alistair J.; Harrison, Roy M.

2010-01-01

Traffic-generated air pollutant emissions can be classified into exhaust and non-exhaust emissions. Increased attention is focussing on non-exhaust emissions as exhaust emissions are progressively limited by regulations. To characterise metal-rich emission from abrasion processes, size-segregated analysis of atmospheric aerosol particles sampled with micro-orifice uniform deposit impactors (MOUDI) in March 2007 in London was performed. The samples were collected at a roadside and a background site and were analysed for Al, Ba, Cu, Fe, Sb, Ti, V, Zn, Ca 2+, K +, Mg 2+, Na +, and NH 4+. Most components showed a clear roadside increment, which was evident as a higher mass concentration and a change in the size distribution. In particular, Fe, Cu, Ba, and Sb correlated highly, indicative of a common traffic-related source. Using complementary information on the fleet composition, vehicle number and average speed, the brake wear emission was calculated using the EMEP/CORINAIR emission database. The total PM 10 and barium emission of the traffic was determined by ratio to NO x whose source strength was estimated from published emission factors. Barium was found to comprise 1.1% of brake wear (PM 10) particles from the traffic fleet as a whole, allowing its use as a quantitative tracer of brake wear emissions at other traffic-influenced sites.

Damage of natural stone tablets exposed to exhaust gas under laboratory conditions

NASA Astrophysics Data System (ADS)

Farkas, Orsolya; Szabados, György; Török, Ákos

2016-04-01

Natural stone tablets were exposed to exhaust gas under laboratory conditions to assess urban stone damage. Cylindrical test specimens (3 cm in diameter) were made from travertine, non-porous limestone, porous limestone, rhyolite tuff, sandstone, andesite, granite and marble. The samples were exposed to exhaust gas that was generated from diesel engine combustion (engine type: RÁBA D10 UTSLL 160, EURO II). The operating condition of the internal combustion engine was: 1300 r/m (app 50%). The exhaust gas was diverted into a pipe system where the samples were placed perpendicular to main flow for 1, 2, 4, 8 and 10 hours, respectively. The exhaust emission was measured by using AVL particulate measurement technology; filter paper method (AVL 415). The stone samples were documented and selective parameters were measured prior to and after exhaust gas exposure. Density, volume, ultrasonic pulse velocity, mineral composition and penetration depth of emission related particulate matter were recorded. The first results indicate that after 10 hours of exposure significant amount of particulate matter deposited on the stone surface independently from the surface properties and porosity. The black soot particles uniformly covered all types of stones, making hard to differentiate the specimens.

40 CFR 86.160-00 - Exhaust emission test procedure for SC03 emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... simulates testing in an environmental test cell (see § 86.162-00 (a) for a discussion of simulation... exhaust and dilution air bag samples to the analytical system and process the samples according to § 86...

40 CFR 85.2217 - Loaded test-EPA 91.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Loaded test-EPA 91. 85.2217 Section 85.2217 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED....2217 Loaded test—EPA 91. (a) General requirements—(1) Exhaust gas sampling algorithm. The analysis of...

40 CFR 85.2213 - Idle test-EPA 91.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 18 2011-07-01 2011-07-01 false Idle test-EPA 91. 85.2213 Section 85.2213 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED....2213 Idle test—EPA 91. (a) General requirements—(1) Exhaust gas sampling algorithm. The analysis of...

40 CFR 85.2213 - Idle test-EPA 91.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 40 Protection of Environment 19 2013-07-01 2013-07-01 false Idle test-EPA 91. 85.2213 Section 85.2213 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED....2213 Idle test—EPA 91. (a) General requirements—(1) Exhaust gas sampling algorithm. The analysis of...

40 CFR 85.2217 - Loaded test-EPA 91.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 19 2012-07-01 2012-07-01 false Loaded test-EPA 91. 85.2217 Section 85.2217 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED....2217 Loaded test—EPA 91. (a) General requirements—(1) Exhaust gas sampling algorithm. The analysis of...

The Pollution Detectives, Part III: Roadside Lead Pollution.

ERIC Educational Resources Information Center

Sanderson, Phil

1989-01-01

Described is a simple test tube method developed lead analysis of samples of roadside soil. The relationship between the results and the traffic flow indicate car exhausts are the major source of lead pollution. Materials and procedures are detailed. An example of results is provided. (Author/CW)

Burnout syndrome and its prevalence in primary care nursing: a systematic review and meta-analysis.

PubMed

Monsalve-Reyes, Carolina S; San Luis-Costas, Concepción; Gómez-Urquiza, Jose L; Albendín-García, Luis; Aguayo, Raimundo; Cañadas-De la Fuente, Guillermo A

2018-05-10

burnout syndrome is a significant problem in nursing professionals. Although, the unit where nurses work may influence burnout development. Nurses that work in primary care units may be at higher risk of burnout. The aim of the study was to estimate the prevalence of emotional exhaustion, depersonalization and low personal accomplishment in primary care nurses. We performed a meta-analysis. We searched Pubmed, CINAHL, Scopus, Scielo, Proquest, CUIDEN and LILACS databases up to September 2017 to identify cross-sectional studies assessing primary care nurses' burnout with the Maslach Burnout Inventory were included. The search was done in September 2017. After the search process, n = 8 studies were included in the meta-analysis, representing a total sample of n = 1110 primary care nurses. High emotional exhaustion prevalence was 28% (95% Confidence Interval = 22-34%), high depersonalization was 15% (95% Confidence Interval = 9-23%) and 31% (95% Confidence Interval = 6-66%) for low personal accomplishment. Problems such as emotional exhaustion and low personal accomplishment are very common among primary care nurses, while depersonalization is less prevalent. Primary care nurses are a burnout risk group.

Burnout of Physicians Working in Primary Health Care Centers under Ministry of Health Jeddah, Saudi Arabia.

PubMed

Bawakid, Khalid; Abdulrashid, Ola; Mandoura, Najlaa; Shah, Hassan Bin Usman; Ibrahim, Adel; Akkad, Noura Mohammad; Mufti, Fauad

2017-11-25

Introduction The levels of physicians' job satisfaction and burnout directly affect their professionalism, punctuality, absenteeism, and ultimately, patients' care. Despite its crucial importance, little is known about professional burnout of the physicians in Saudi Arabia. The objectives of this research are two-fold: (1) To assess the prevalence of burnout in physicians working in primary health care centers under Ministry of Health; and (2) to find the modifiable factors which can decrease the burnout ratio. Methodology Through a cross-sectional study design, a representative sample of the physicians working in primary health care centers (PHCCs) Jeddah (n=246) was randomly selected. The overall burnout level was assessed using the validated abbreviated Maslach burnout inventory (aMBI) questionnaire. It measures the overall burnout prevalence based on three main domains i.e., emotional exhaustion, depersonalization, and personal accomplishment. Independent sample T-test, analysis of variance (ANOVA), and multivariate regression analysis were performed using Statistical Package for the Social Sciences (SPSS Version 22, IBM, Armonk, NY). Results Overall, moderate to high burnout was prevalent in 25.2% of the physicians. Emotional exhaustion was noted in 69.5%. Multivariate regression analysis showed that patient pressure/violence (p <0.001), unorganized patients flow to clinics (p=0.021), more paperwork (p<0.001), and less co-operative colleague doctors (p=0.045) were the significant predictors for high emotional exhaustion. A positive correlation was noted between the number of patients per day and burnout. The patient's pressure/violence was the only significant independent predictor of overall burnout. Conclusion Emotional exhaustion is the most prominent feature of overall burnout in the physicians of primary health care centers. The main reasons include patient's pressure/violence, unorganized patient flow, less cooperative colleague doctors, fewer support services at the PHCCs, more paperwork, and less cooperative colleagues. Addressing these issues could lead to a decrease in physician's burnout.

40 CFR 90.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2013 CFR

2013-07-01

... savers” or “protectors” with nonreactive diaphragms to reduce dead volumes is permitted. (b) Sample probe. (1) The sample probe must be a straight, closed end, stainless steel, multi-hole probe. The inside... probe may not be greater than 0.10 cm. The fitting that attaches the probe to the exhaust pipe must be...

40 CFR 90.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2012 CFR

2012-07-01

... savers” or “protectors” with nonreactive diaphragms to reduce dead volumes is permitted. (b) Sample probe. (1) The sample probe must be a straight, closed end, stainless steel, multi-hole probe. The inside... probe may not be greater than 0.10 cm. The fitting that attaches the probe to the exhaust pipe must be...

40 CFR 90.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2014 CFR

2014-07-01

... savers” or “protectors” with nonreactive diaphragms to reduce dead volumes is permitted. (b) Sample probe. (1) The sample probe must be a straight, closed end, stainless steel, multi-hole probe. The inside... probe may not be greater than 0.10 cm. The fitting that attaches the probe to the exhaust pipe must be...

Measurements of CO, CO2, OH, and H2O in room-temperature and combustion gases by use of a broadly current-tuned multisection InGaAsP diode laser.

PubMed

Upschulte, B L; Sonnenfroh, D M; Allen, M G

1999-03-20

A new laser technology that achieves nearly 100-nm quasi-continuous tuning with only injection-current control in a four-section grating-coupler sampled-reflector laser was used to detect CO and CO(2) simultaneously in room-temperature gas mixtures. The same grating-coupler sampled-reflector laser was used to perform in situ measurements of CO, H(2)O, and OH in the exhaust gases of a CH(4)-air flame. This laser is being evaluated for inclusion in a multispecies combustion-emissions exhaust-analysis sensor, and its operational characteristics as they have an impact on gas sensing are described. Preliminary results suggest that this single laser can be used to replace multilaser sensor configurations for some combustion-emissions monitoring applications.

Assessment of need for transport tubes when continuously monitoring for radioactive aerosols.

PubMed

Whicker, J J; Rodgers, J C; Lopez, R C

1999-09-01

Aerosol transport tubes are often used to draw aerosol from desirable sampling locations to nearby air sampling equipment that cannot be placed at that location. In many plutonium laboratories at Los Alamos National Laboratory, aerosol transport tubes are used to transport aerosol from the front of room ventilation exhaust registers to continuous air monitors (CAMs) that are mounted on nearby walls. Transport tubes are used because past guidance suggests that extraction of aerosol samples from exhaust locations provides the most sensitive and reliable detection under conditions where the rooms have unpredictable release locations and significant spatial variability in aerosol concentrations after releases, and where CAMs cannot be located in front of exhaust registers without blocking worker walkways. Despite designs to minimize particle loss in tubes, aerosol transport model predictions suggest losses occur lowering the sensitivity of CAMs to accidentally released plutonium aerosol. The goal of this study was to test the hypotheses that the reliability, speed, and sensitivity of aerosol detection would be equal whether the sample was extracted from the front of the exhaust register or from the wall location of CAMs. Polydisperse oil aerosols were released from multiple locations in two plutonium laboratories to simulate plutonium aerosol releases. Networked laser particle counters (LPCs) were positioned to simultaneously measure time-resolved aerosol concentrations at each exhaust register (representative of sampling with transport tubes) and at each wall-mounted CAM location (representative of sampling without transport tubes). Results showed no significant differences in detection reliability, speed, or sensitivity for LPCs positioned at exhaust locations when compared to LPCs positioned at the CAM wall location. Therefore, elimination of transport tubes would likely improve CAM performance.

40 CFR 86.1540 - Idle exhaust sample analysis.

Code of Federal Regulations, 2010 CFR

2010-07-01

... Regulations for Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Light-Duty Trucks; Idle Test...

40 CFR 90.423 - Exhaust gas analytical system; CVS grab sample.

Code of Federal Regulations, 2012 CFR

2012-07-01

... detector (HFID) for the measurement of hydrocarbons, non-dispersive infrared analyzers (NDIR) for the... converted to nitric oxide before analysis. Other types of analyzers may be used if shown to yield equivalent... room temperature, produces an equivalent CO response, as measured on the most sensitive CO range, which...

40 CFR 90.423 - Exhaust gas analytical system; CVS grab sample.

Code of Federal Regulations, 2010 CFR

2010-07-01

... detector (HFID) for the measurement of hydrocarbons, non-dispersive infrared analyzers (NDIR) for the... converted to nitric oxide before analysis. Other types of analyzers may be used if shown to yield equivalent... room temperature, produces an equivalent CO response, as measured on the most sensitive CO range, which...

40 CFR 86.140-94 - Exhaust sample analysis.

Code of Federal Regulations, 2011 CFR

2011-07-01

...-cycle and methanol-fueled, natural gas-fueled and liquefied petroleum gas-fueled (if non-heated FID option is used) diesel vehicle HC: (1) Zero the analyzers and obtain a stable zero reading. Recheck after...: (1) Zero HFID analyzer and obtain a stable zero reading. (2) Introduce span gas and set instrument...

40 CFR 86.140-94 - Exhaust sample analysis.

Code of Federal Regulations, 2010 CFR

2010-07-01

...-cycle and methanol-fueled, natural gas-fueled and liquefied petroleum gas-fueled (if non-heated FID option is used) diesel vehicle HC: (1) Zero the analyzers and obtain a stable zero reading. Recheck after...: (1) Zero HFID analyzer and obtain a stable zero reading. (2) Introduce span gas and set instrument...

40 CFR 89.404 - Test procedure overview.

Code of Federal Regulations, 2010 CFR

2010-07-01

... engine operating conditions to be conducted on an engine dynamometer. The exhaust gases, generated raw or... matter. For more information on particulate matter sampling see § 89.112(c). The test cycles consist of... (raw analysis), and the power output during each mode. The measured values are weighted and used to...

40 CFR 90.423 - Exhaust gas analytical system; CVS grab sample.

Code of Federal Regulations, 2014 CFR

2014-07-01

... PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NONROAD SPARK-IGNITION ENGINES AT OR BELOW 19 KILOWATTS... detector (HFID) for the measurement of hydrocarbons, non-dispersive infrared analyzers (NDIR) for the... converted to nitric oxide before analysis. Other types of analyzers may be used if shown to yield equivalent...

40 CFR 90.423 - Exhaust gas analytical system; CVS grab sample.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NONROAD SPARK-IGNITION ENGINES AT OR BELOW 19... detector (HFID) for the measurement of hydrocarbons, non-dispersive infrared analyzers (NDIR) for the... converted to nitric oxide before analysis. Other types of analyzers may be used if shown to yield equivalent...

40 CFR 90.423 - Exhaust gas analytical system; CVS grab sample.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) AIR PROGRAMS (CONTINUED) CONTROL OF EMISSIONS FROM NONROAD SPARK-IGNITION ENGINES AT OR BELOW 19... detector (HFID) for the measurement of hydrocarbons, non-dispersive infrared analyzers (NDIR) for the... converted to nitric oxide before analysis. Other types of analyzers may be used if shown to yield equivalent...

40 CFR 89.412 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) Sample probe. (1) The sample probe shall be a straight, closed-end, stainless steel, multi-hole probe... wall thickness of the probe shall not be greater than 0.10 cm. The fitting that attaches the probe to the exhaust pipe shall be as small as practical in order to minimize heat loss from the probe. (2) The...

40 CFR 89.412 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) Sample probe. (1) The sample probe shall be a straight, closed-end, stainless steel, multi-hole probe... wall thickness of the probe shall not be greater than 0.10 cm. The fitting that attaches the probe to the exhaust pipe shall be as small as practical in order to minimize heat loss from the probe. (2) The...

40 CFR 89.412 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) Sample probe. (1) The sample probe shall be a straight, closed-end, stainless steel, multi-hole probe... wall thickness of the probe shall not be greater than 0.10 cm. The fitting that attaches the probe to the exhaust pipe shall be as small as practical in order to minimize heat loss from the probe. (2) The...

Measuring self-pollution in school buses using a tracer gas technique

NASA Astrophysics Data System (ADS)

Behrentz, Eduardo; Fitz, Dennis R.; Pankratz, David V.; Sabin, Lisa D.; Colome, Steven D.; Fruin, Scott A.; Winer, Arthur M.

A potentially important, but inadequately studied, source of children's exposure to pollutants during school bus commutes is the introduction of a bus's own exhaust into the passenger compartment. We developed and applied a method to determine the amount of a bus's own exhaust penetrating into the cabin in a study of six in-use school buses over a range of routes, roadway types, fuels, and emission control technologies. A tracer gas, SF 6, was metered into the bus's exhaust system using a mass flow controller whose flow rate was logged by a data acquisition system and processed with the concurrent real-time pollutant measurement data. At the same time, the SF 6 concentration inside the bus was measured using an AeroVironment CTA-1000 continuous analyzer connected to a series of solenoids that switched the sample inlet between the front and rear of the bus cabin. To account for a baseline drift of the CTA-1000, SF 6-free air was also drawn through a line located outside at the front of the bus. Although this third sample line generally provided a reference zero value, it also showed that under certain wind conditions (i.e., wind from the rear) when the bus was stopped and was idling, significant amounts of the bus's own exhaust reached this location at the front of the bus. Self-pollution, the percentage of a bus's own exhaust that can be found inside its cabin, was a function of bus type and age, and a strong function of window position (i.e., open or closed). We estimated up to 0.3% of the air inside the cabin was from the bus's own exhaust in older buses, approximately 10 times the percentage observed for newer buses, and 25% of the black carbon concentration variance was explained by the buses' self-pollution. Analysis of the tracer gas concentrations provided a powerful tool for identifying potentially high-exposure conditions.

Modeling and Qualification of a Modified Emission Unit for Radioactive Air Emissions Stack Sampling Compliance.

PubMed

Barnett, J Matthew; Yu, Xiao-Ying; Recknagle, Kurtis P; Glissmeyer, John A

2016-11-01

A planned laboratory space and exhaust system modification to the Pacific Northwest National Laboratory Material Science and Technology Building indicated that a new evaluation of the mixing at the air sampling system location would be required for compliance to ANSI/HPS N13.1-2011. The modified exhaust system would add a third fan, thereby increasing the overall exhaust rate out the stack, thus voiding the previous mixing study. Prior to modifying the radioactive air emissions exhaust system, a three-dimensional computational fluid dynamics computer model was used to evaluate the mixing at the sampling system location. Modeling of the original three-fan system indicated that not all mixing criteria could be met. A second modeling effort was conducted with the addition of an air blender downstream of the confluence of the three fans, which then showed satisfactory mixing results. The final installation included an air blender, and the exhaust system underwent full-scale tests to verify velocity, cyclonic flow, gas, and particulate uniformity. The modeling results and those of the full-scale tests show agreement between each of the evaluated criteria. The use of a computational fluid dynamics code was an effective aid in the design process and allowed the sampling system to remain in its original location while still meeting the requirements for sampling at a well mixed location.

Concept of Heat Recovery from Exhaust Gases

NASA Astrophysics Data System (ADS)

Bukowska, Maria; Nowak, Krzysztof; Proszak-Miąsik, Danuta; Rabczak, Sławomir

2017-10-01

The theme of the article is to determine the possibility of waste heat recovery and use it to prepare hot water. The scope includes a description of the existing sample of coal-fired boiler plant, the analysis of working condition and heat recovery proposals. For this purpose, a series of calculations necessary to identify the energy effect of exhaust temperature decreasing and transferring recovery heat to hot water processing. Heat recover solutions from the exhaust gases channel between boiler and chimney section were proposed. Estimation for the cost-effectiveness of such a solution was made. All calculations and analysis were performed for typical Polish conditions, for coal-fired boiler plant. Typicality of this solution is manifested by the volatility of the load during the year, due to distribution of heat for heating and hot water, determining the load variation during the day. Analysed system of three boilers in case of load variation allows to operational flexibility and adaptation of the boilers load to the current heat demand. This adaptation requires changes in the operating conditions of boilers and in particular assurance of properly conditions for the combustion of fuel. These conditions have an impact on the existing thermal loss and the overall efficiency of the boiler plant. On the boiler plant efficiency affects particularly exhaust gas temperature and the excess air factor. Increasing the efficiency of boilers plant is possible to reach by following actions: limiting the excess air factor in coal combustion process in boilers and using an additional heat exchanger in the exhaust gas channel outside of boilers (economizer) intended to preheat the hot water.

Influence of surface properties on the mechanism of H2S removal by alkaline activated carbons.

PubMed

Yan, Rong; Chin, Terence; Ng, Yuen Ling; Duan, Huiqi; Liang, David Tee; Tay, Joo Hwa

2004-01-01

Alkaline activated carbons are widely used as adsorbents of hydrogen sulfide (H2S), one of the major odorous compounds arising from sewage treatment facilities. Although a number of studies have explored the effects of various parameters, mechanisms of H2S adsorption by alkaline carbons are not yet fully understood. The major difficulty seems to lie in the fact that little is known with certainty about the predominant reactions occurring on the carbon surface. In this study, the surface properties of alkaline activated carbons were systematically investigated to further exploit and better understand the mechanisms of H2S adsorption by alkaline activated carbons. Two commercially available alkaline activated carbons and their representative exhausted samples (8 samples collected at different height of the column after H2S breakthrough tests) were studied. The 8 portions of the exhausted carbon were used to represent the H2S/carbon reaction process. The surface properties of both the original and the exhausted carbons were characterized using the sorption of nitrogen (BET test), surface pH, Boehm titration, thermal and FTIR analysis. Porosity and surface area provide detailed information about the pore structure of the exhausted carbons with respect to the reaction extent facilitating the understanding of potential pore blockages. Results of Boehm titration and FTIR both demonstrate the significant effects of surface functional groups, and identification of oxidation products confirmed the different mechanisms involved with the two carbons. From the DTG curves of thermal analysis, two well-defined peaks representing two products of surface reactions (i.e., sulfur and sulfuric acid) were observed from the 8 exhausted portions with gradually changing patterns coinciding with the extent of the reaction. Surface pH values of the exhausted carbons show a clear trend of pH drop along the reaction extent, while pH around 2 was observed for the bottom of the bed indicating sulfuric acid as the predominant products. Although both carbons are coal-based and of KOH impregnated type, performances of different carbons differ significantly. A correlation is well established to link the reaction extent with various surface properties. In summary, not only the homogeneous alkali impregnation and physical porosity but also the carbon surface chemistry are significant factors influencing the performances of alkaline activated carbons as H2S adsorbents.

40 CFR 87.82 - Sampling and analytical procedures for measuring smoke exhaust emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Sampling and analytical procedures for measuring smoke exhaust emissions. 87.82 Section 87.82 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF AIR POLLUTION FROM AIRCRAFT AND AIRCRAFT ENGINES...

40 CFR 87.64 - Sampling and analytical procedures for measuring gaseous exhaust emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Sampling and analytical procedures for measuring gaseous exhaust emissions. 87.64 Section 87.64 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF AIR POLLUTION FROM AIRCRAFT AND AIRCRAFT ENGINES...

40 CFR 87.82 - Sampling and analytical procedures for measuring smoke exhaust emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Sampling and analytical procedures for measuring smoke exhaust emissions. 87.82 Section 87.82 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF AIR POLLUTION FROM AIRCRAFT AND AIRCRAFT ENGINES...

40 CFR 87.64 - Sampling and analytical procedures for measuring gaseous exhaust emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Sampling and analytical procedures for measuring gaseous exhaust emissions. 87.64 Section 87.64 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF AIR POLLUTION FROM AIRCRAFT AND AIRCRAFT ENGINES...

BIOASSAY-DIRECTED FRACTIONAL AND SALMONELLA MUTAGENICITY OF AUTOMOBILE AND FORKLIFT DIESEL EXHAUST PARTICLES

EPA Science Inventory

Abstract

Many pulmonary toxicity studies of diesel exhaust particles (DEP) have used an
automobile-generated sample (A-DEP) whose mutagenicity has not been reported. In contrast,
rnany inutagenicity studies of DEP have used a forklift-generated sample (SRM ...

Performance of a Line Loss Correction Method for Gas Turbine Emission Measurements

NASA Astrophysics Data System (ADS)

Hagen, D. E.; Whitefield, P. D.; Lobo, P.

2015-12-01

International concern for the environmental impact of jet engine exhaust emissions in the atmosphere has led to increased attention on gas turbine engine emission testing. The Society of Automotive Engineers Aircraft Exhaust Emissions Measurement Committee (E-31) has published an Aerospace Information Report (AIR) 6241 detailing the sampling system for the measurement of non-volatile particulate matter from aircraft engines, and is developing an Aerospace Recommended Practice (ARP) for methodology and system specification. The Missouri University of Science and Technology (MST) Center for Excellence for Aerospace Particulate Emissions Reduction Research has led numerous jet engine exhaust sampling campaigns to characterize emissions at different locations in the expanding exhaust plume. Particle loss, due to various mechanisms, occurs in the sampling train that transports the exhaust sample from the engine exit plane to the measurement instruments. To account for the losses, both the size dependent penetration functions and the size distribution of the emitted particles need to be known. However in the proposed ARP, particle number and mass are measured, but size is not. Here we present a methodology to generate number and mass correction factors for line loss, without using direct size measurement. A lognormal size distribution is used to represent the exhaust aerosol at the engine exit plane and is defined by the measured number and mass at the downstream end of the sample train. The performance of this line loss correction is compared to corrections based on direct size measurements using data taken by MST during numerous engine test campaigns. The experimental uncertainty in these correction factors is estimated. Average differences between the line loss correction method and size based corrections are found to be on the order of 10% for number and 2.5% for mass.

Subtypes in clinical burnout patients enrolled in an employee rehabilitation program: differences in burnout profiles, depression, and recovery/resources-stress balance.

PubMed

Bauernhofer, Kathrin; Bassa, Daniela; Canazei, Markus; Jiménez, Paulino; Paechter, Manuela; Papousek, Ilona; Fink, Andreas; Weiss, Elisabeth M

2018-01-17

Burnout is generally perceived a unified disorder with homogeneous symptomatology across people (exhaustion, cynicism, and reduced professional efficacy). However, increasing evidence points to intra-individual patterns of burnout symptoms in non-clinical samples such as students, athletes, healthy, and burned-out employees. Different burnout subtypes might therefore exist. Yet, burnout subtypes based on burnout profiles have hardly been explored in clinical patients, and the samples investigated in previous studies were rather heterogeneous including patients with various physical, psychological, and social limitations, symptoms, and disabilities. Therefore, the aim of this study is to explore burnout subtypes based on burnout profiles in clinically diagnosed burnout patients enrolled in an employee rehabilitation program, and to investigate whether the subtypes differ in depression, recovery/resources-stress balance, and sociodemographic characteristics. One hundred three patients (66 women, 37 men) with a clinical burnout diagnosis, who were enrolled in a 5 week employee rehabilitation program in two specialized psychosomatic clinics in Austria, completed a series of questionnaires including the Maslach Burnout Inventory - General Survey (MBI-GS), the Beck Depression Inventory, and the Recovery-Stress-Questionnaire for Work. Cluster analyses with the three MBI-GS subscales as clustering variables were used to identify the burnout subtypes. Subsequent multivariate/univariate analysis of variance and Pearson chi-square tests were performed to investigate differences in depression, recovery/resources-stress balance, and sociodemographic characteristics. Three different burnout subtypes were discovered: the exhausted subtype, the exhausted/cynical subtype, and the burned-out subtype. The burned-out subtype and the exhausted/cynical subtype showed both more severe depression symptoms and a worse recovery/resources-stress balance than the exhausted subtype. Furthermore, the burned-out subtype was more depressed than the exhausted/cynical subtype, but no difference was observed between these two subtypes with regard to perceived stress, recovery, and resources. Sociodemographic characteristics were not associated with the subtypes. The present study indicates that there are different subtypes in clinical burnout patients (exhausted, exhausted/cynical, and burned-out), which might represent patients at different developmental stages in the burnout cycle. Future studies need to replicate the current findings, investigate the stability of the symptom patterns, and examine the efficacy of rehabilitation interventions in different subtypes.

Mutagenicity of diesel exhaust particles and oil shale particles dispersed in lecithin surfactant.

PubMed

Wallace, W E; Keane, M J; Hill, C A; Xu, J; Ong, T M

1987-01-01

Diesel exhaust particulate material from exhaust pipe scrapings of two trucks, diluted automobile diesel exhaust particulate material collected on filters, and two oil shale ores were prepared for the Ames mutagenicity assay by dichloromethane (DCM) extraction, by dispersion into 0.85% saline, or by dispersion into dipalmitoyl lecithin (DPL) emulsion in saline. Salmonella typhimurium TA98 was used to detect frameshift mutagens in the samples. Samples of diesel soot gave positive mutagenic responses with both DCM extraction and DPL dispersion, with the DPL dispersion giving higher results in some cases. The results suggest that possible mutagens associated with inhaled particles may be dispersed or solubilized into the phospholipid component of pulmonary surfactant and become active in such a phase.

Optical Measurements on Solid Specimens of Solid Rocket Motor Exhaust and Solid Rocket Motor Slag

NASA Technical Reports Server (NTRS)

Roberts, F. E., III

1991-01-01

Samples of aluminum slag were investigated to aid the Earth Science and Applications Division at the Marshall Space Flight Center (MSFC). Alumina from space motor propellant exhaust and space motor propellant slag was examined as a component of space refuse. Thermal emittance and solar absorptivity measurements were taken to support their comparison with reflectance measurements derived from actual debris. To determine the similarity between the samples and space motor exhaust or space motor slag, emittance and absorbance results were correlated with an examination of specimen morphology.

Determination of aldehydes and ketones using derivatization with 2,4-dinitrophenylhydrazine and liquid chromatography-atmospheric pressure photoionization-mass spectrometry.

PubMed

van Leeuwen, Suze M; Hendriksen, Laurens; Karst, Uwe

2004-11-26

Atmospheric pressure photoionization-mass spectrometry (APPI-MS) is used for the analysis of aldehydes and ketones after derivatization with 2,4-dinitrophenylhydrazine (DNPH) and liquid chromatographic separation. In the negative ion mode, the [M - H]- pseudomolecular ions are most abundant for the carbonyls. Compared with the established atmospheric pressure chemical ionization (APCI)-MS, limits of detection are typically lower using similar conditions. Automobile exhaust and cigarette exhaust samples were analyzed with APPI-MS and APCI-MS in combination with an ion trap mass analyzer. Due to improved limits of detection, more of the less abundant long-chain carbonyls are detected with APPI-MS in real samples. While 2,4-dinitrophenylazide, a known reaction product of DNPH with nitrogen dioxide, is detected in APCI-MS due to dissociative electron capture, it is not observed at all in APPI-MS.

40 CFR 85.2213 - Idle test-EPA 91.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 40 Protection of Environment 19 2012-07-01 2012-07-01 false Idle test-EPA 91. 85.2213 Section 85...) CONTROL OF AIR POLLUTION FROM MOBILE SOURCES Emission Control System Performance Warranty Short Tests § 85.2213 Idle test—EPA 91. (a) General requirements—(1) Exhaust gas sampling algorithm. The analysis of...

40 CFR 85.2224 - Exhaust analysis system-EPA 81.

Code of Federal Regulations, 2010 CFR

2010-07-01

... are solely in effect. The following exceptions apply: In a state where the Administrator has approved... earlier model year vehicles or engines; in a state where the Administrator has approved a SIP revision... dual sample probe must provide equal flow in each leg. The equal flow criterion is considered to be met...

40 CFR 80.91 - Individual baseline determination.

Code of Federal Regulations, 2013 CFR

2013-07-01

...—6.45 Exhaust benzene emissions, complex model—33.03 mg/mile Exhaust toxics emissions, Phase I—50.67 mg/mile Exhaust toxics emissions, Phase II—104.5 mg/mile NOX emissions, Phase I—714.4 mg/mile NOX emissions, Phase II—1461. mg/mile (d) Data collection and testing requirements—(1) Minimum sampling...

40 CFR 80.91 - Individual baseline determination.

Code of Federal Regulations, 2014 CFR

2014-07-01

...—6.45 Exhaust benzene emissions, complex model—33.03 mg/mile Exhaust toxics emissions, Phase I—50.67 mg/mile Exhaust toxics emissions, Phase II—104.5 mg/mile NOX emissions, Phase I—714.4 mg/mile NOX emissions, Phase II—1461. mg/mile (d) Data collection and testing requirements—(1) Minimum sampling...

40 CFR 80.91 - Individual baseline determination.

Code of Federal Regulations, 2011 CFR

2011-07-01

...—6.45 Exhaust benzene emissions, complex model—33.03 mg/mile Exhaust toxics emissions, Phase I—50.67 mg/mile Exhaust toxics emissions, Phase II—104.5 mg/mile NOX emissions, Phase I—714.4 mg/mile NOX emissions, Phase II—1461. mg/mile (d) Data collection and testing requirements—(1) Minimum sampling...

40 CFR 80.91 - Individual baseline determination.

Code of Federal Regulations, 2010 CFR

2010-07-01

...—6.45 Exhaust benzene emissions, complex model—33.03 mg/mile Exhaust toxics emissions, Phase I—50.67 mg/mile Exhaust toxics emissions, Phase II—104.5 mg/mile NOX emissions, Phase I—714.4 mg/mile NOX emissions, Phase II—1461. mg/mile (d) Data collection and testing requirements—(1) Minimum sampling...

Identifying Predictors of Emotional Exhaustion among Special Education Paraeducators: A Preliminary Investigation

ERIC Educational Resources Information Center

Shyman, Eric

2010-01-01

The purpose of this preliminary study was to identify predictors of emotional exhaustion among special education paraeducators. A sample of 100 paraeducators in public and specialized alternative setting schools was used to determine whether self-reported levels of emotional exhaustion and other job-related factors were reported. Using…

Assessment of exhaust emissions from carbon nanotube production and particle collection by sampling filters.

PubMed

Tsai, Candace Su-Jung; Hofmann, Mario; Hallock, Marilyn; Ellenbecker, Michael; Kong, Jing

2015-11-01

This study performed a workplace evaluation of emission control using available air sampling filters and characterized the emitted particles captured in filters. Characterized particles were contained in the exhaust gas released from carbon nanotube (CNT) synthesis using chemical vapor deposition (CVD). Emitted nanoparticles were collected on grids to be analyzed using transmission electron microscopy (TEM). CNT clusters in the exhaust gas were collected on filters for investigation. Three types of filters, including Nalgene surfactant-free cellulose acetate (SFCA), Pall A/E glass fiber, and Whatman QMA quartz filters, were evaluated as emission control measures, and particles deposited in the filters were characterized using scanning transmission electron microscopy (STEM) to further understand the nature of particles emitted from this CNT production. STEM analysis for collected particles on filters found that particles deposited on filter fibers had a similar morphology on all three filters, that is, hydrophobic agglomerates forming circular beaded clusters on hydrophilic filter fibers on the collecting side of the filter. CNT agglomerates were found trapped underneath the filter surface. The particle agglomerates consisted mostly of elemental carbon regardless of the shapes. Most particles were trapped in filters and no particles were found in the exhaust downstream from A/E and quartz filters, while a few nanometer-sized and submicrometer-sized individual particles and filament agglomerates were found downstream from the SFCA filter. The number concentration of particles with diameters from 5 nm to 20 µm was measured while collecting particles on grids at the exhaust piping. Total number concentration was reduced from an average of 88,500 to 700 particle/cm(3) for the lowest found for all filters used. Overall, the quartz filter showed the most consistent and highest particle reduction control, and exhaust particles containing nanotubes were successfully collected and trapped inside this filter. As concern for the toxicity of engineered nanoparticles grows, there is a need to characterize emission from carbon nanotube synthesis processes and to investigate methods to prevent their environmental release. At this time, the particles emitted from synthesis were not well characterized when collected on filters, and limited information was available about filter performance to such emission. This field study used readily available sampling filters to collect nanoparticles from the exhaust gas of a carbon nanotube furnace. New agglomerates were found on filters from such emitted particles, and the performance of using the filters studied was encouraging in terms of capturing emissions from carbon nanotube synthesis.

Transformational leadership moderates the relationship between emotional exhaustion and turnover intention among community mental health providers.

PubMed

Green, Amy E; Miller, Elizabeth A; Aarons, Gregory A

2013-08-01

Public sector mental health care providers are at high risk for burnout and emotional exhaustion which negatively affect job performance and client satisfaction with services. Few studies have examined ways to reduce these associations, but transformational leadership may have a positive effect. We examine the relationships between transformational leadership, emotional exhaustion, and turnover intention in a sample of 388 community mental health providers. Emotional exhaustion was positively related to turnover intention, and transformational leadership was negatively related to both emotional exhaustion and turnover intention. Transformational leadership moderated the relationship between emotional exhaustion and turnover intention, indicating that having a transformational leader may buffer the effects of providers' emotional exhaustion on turnover intention. Investing in transformational leadership development for supervisors could reduce emotional exhaustion and turnover among public sector mental health providers.

Transformational Leadership Moderates the Relationship between Emotional Exhaustion and Turnover Intention among Community Mental Health Providers

PubMed Central

Green, Amy E.; Miller, Elizabeth A.; Aarons, Gregory A.

2014-01-01

Public sector mental health care providers are at high risk for burnout and emotional exhaustion which negatively affect job performance and client satisfaction with services. Few studies have examined ways to reduce these associations, but transformational leadership may have a positive effect. We examine the relationships between transformational leadership, emotional exhaustion, and turnover intention in a sample of 388 community mental health providers. Emotional exhaustion was positively related to turnover intention, and transformational leadership was negatively related to both emotional exhaustion and turnover intention. Transformational leadership moderated the relationship between emotional exhaustion and turnover intention, indicating that having a transformational leader may buffer the effects of providers’ emotional exhaustion on turnover intention. Investing in transformational leadership development for supervisors could reduce emotional exhaustion and turnover among public sector mental health providers. PMID:22052429

40 CFR 1065.750 - Analytical gases.

Code of Federal Regulations, 2010 CFR

2010-07-01

... O2 concentration in the exhaust sample is zero, we recommend using a balance gas of purified nitrogen... concentration in the exhaust sample is zero, we recommend using a balance gas of purified nitrogen. (3) Use the....41) mol/mol, balance He, and a stated total hydrocarbon concentration of 0.05 µmol/mol or less. (ii...

40 CFR 1065.750 - Analytical gases.

Code of Federal Regulations, 2012 CFR

2012-07-01

... O2 concentration in the exhaust sample is zero, we recommend using a balance gas of purified nitrogen... concentration in the exhaust sample is zero, we recommend using a balance gas of purified nitrogen. (3) Use the....41) mol/mol, balance He, and a stated total hydrocarbon concentration of 0.05 µmol/mol or less. (ii...

40 CFR 1065.750 - Analytical gases.

Code of Federal Regulations, 2013 CFR

2013-07-01

... O2 concentration in the exhaust sample is zero, we recommend using a balance gas of purified nitrogen... concentration in the exhaust sample is zero, we recommend using a balance gas of purified nitrogen. (3) Use the....41) mol/mol, balance He, and a stated total hydrocarbon concentration of 0.05 µmol/mol or less. (ii...

40 CFR 1065.750 - Analytical gases.

Code of Federal Regulations, 2011 CFR

2011-07-01

... O2 concentration in the exhaust sample is zero, we recommend using a balance gas of purified nitrogen... concentration in the exhaust sample is zero, we recommend using a balance gas of purified nitrogen. (3) Use the....41) mol/mol, balance He, and a stated total hydrocarbon concentration of 0.05 µmol/mol or less. (ii...

Factors to Consider in Designing Aerosol Inlet Systems for Engine Exhaust Plume Sampling

NASA Technical Reports Server (NTRS)

Anderson, Bruce

2004-01-01

This document consists of viewgraphs of charts and diagrams of considerations to take when sampling the engine exhaust plume. It includes a chart that compares the emissions from various fuels, a diagram and charts of the various processes and conditions that influence the particulate size and concentration,

40 CFR 600.211-08 - Sample calculation of fuel economy values for labeling.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 30 2011-07-01 2011-07-01 false Sample calculation of fuel economy... AGENCY (CONTINUED) ENERGY POLICY FUEL ECONOMY AND CARBON-RELATED EXHAUST EMISSIONS OF MOTOR VEHICLES Procedures for Calculating Fuel Economy and Carbon-Related Exhaust Emission Values for 1977 and Later Model...

40 CFR 86.1309-90 - Exhaust gas sampling system; Otto-cycle and non-petroleum-fueled engines.

Code of Federal Regulations, 2010 CFR

2010-07-01

...-cycle and non-petroleum-fueled engines. 86.1309-90 Section 86.1309-90 Protection of Environment... HIGHWAY VEHICLES AND ENGINES (CONTINUED) Emission Regulations for New Otto-Cycle and Diesel Heavy-Duty...-cycle and non-petroleum-fueled engines. (a)(1) General. The exhaust gas sampling system described in...

Tests of a High Temperature Sample Conditioner for the Waste Treatment Plant LV-S2, LV-S3, HV-S3A and HV-S3B Exhaust Systems

DOE Office of Scientific and Technical Information (OSTI.GOV)

Flaherty, Julia E.; Glissmeyer, John A.

2015-03-18

Tests were performed to evaluate a sample conditioning unit for stack monitoring at Hanford Tank Waste Treatment and Immobilization Plant (WTP) exhaust stacks with elevated air temperatures. The LV-S2, LV-S3, HV-S3A and HV-S3B exhaust stacks are expected to have elevated air temperature and dew point. At these emission points, exhaust temperatures are too high to deliver the air sample directly to the required stack monitoring equipment. As a result, a sample conditioning system is considered to cool and dry the air prior to its delivery to the stack monitoring system. The method proposed for the sample conditioning is a dilutionmore » system that will introduce cooler, dry air to the air sample stream. This method of sample conditioning is meant to reduce the sample temperature while avoiding condensation of moisture in the sample stream. An additional constraint is that the ANSI/HPS N13.1-1999 standard states that at least 50% of the 10 μm aerodynamic diameter (AD) particles present in the stack free stream must be delivered to the sample collector. In other words, depositional loss of particles should be limited to 50% in the sampling, transport, and conditioning systems. Based on estimates of particle penetration through the LV-S3 sampling system, the diluter should perform with about 80% penetration or better to ensure that the total sampling system passes the 50% or greater penetration criterion.« less

Structural validity of the Maslach Burnout Inventory and influence of depressive symptoms in banking workplace: Unfastening the occupational conundrum.

PubMed

Valente, Maria do Socorro da Silva; Wang, Yuan-Pang; Menezes, Paulo Rossi

2018-06-04

Burnout and mental disorders have been reported in the financial industry. This study aims to examine the structural validity of the Maslach Burnout Inventory (MBI) and to investigate the connection between the dimensions of burnout and depressive symptoms in a sample of 1046 bank employees from North Brazil who completed the MBI and the Patient Health Questionnaire-9 (PHQ-9. Exploratory factor analysis (EFA) and confirmatory factor analysis (CFA) were used to cross-check the factorial structure of the MBI. One-way analysis of variance and correlation analysis were applied to elucidate the relationship between burnout and depressive symptoms. Both 3-factor and 4-factor oblique solutions were plausible EFA models of the burnout syndrome. Results of CFA supported the 19-item 4-factor structure as the best fitting model to data, with two exhaustion factors ("exhausted" and "strained"), depersonalization, and personal accomplishment. The PHQ-9 total score and individual score of depressive items were significantly correlated with all MBI dimensions, notably with the emotional exhaustion dimension. The moderate-to-high correlation observed between burnout and depression suggest the potential utility of the MBI for evaluating burnout among bank employees as well as to point out the need to evaluate systematically the burnout and depressive symptoms given to their potential association. Copyright © 2018. Published by Elsevier B.V.

Exposure of miners to diesel exhaust particulates in underground nonmetal mines.

PubMed

Cohen, H J; Borak, J; Hall, T; Sirianni, G; Chemerynski, S

2002-01-01

A study was initiated to examine worker exposures in seven underground nonmetal mines and to examine the precision of the National Institute for Occupational Safety and Health (NIOSH) 5040 sampling and analytical method for diesel exhaust that has recently been adopted for compliance monitoring by the Mine Safety and Health Administration (MSHA). Approximately 1000 air samples using cyclones were taken on workers and in areas throughout the mines. Results indicated that worker exposures were consistently above the MSHA final limit of 160 micrograms/m3 (time-weighted average; TWA) for total carbon as determined by the NIOSH 5040 method and greater than the proposed American Conference of Governmental Industrial Hygienists TLV limit of 20 micrograms/m3 (TWA) for elemental carbon. A number of difficulties were documented when sampling for diesel exhaust using organic carbon: high and variable blank values from filters, a high variability (+/- 20%) from duplicate punches from the same sampling filter, a consistent positive interference (+26%) when open-faced monitors were sampled side-by-side with cyclones, poor correlation (r 2 = 0.38) to elemental carbon levels, and an interference from limestone that could not be adequately corrected by acid-washing of filters. The sampling and analytical precision (relative standard deviation) was approximately 11% for elemental carbon, 17% for organic carbon, and 11% for total carbon. An hypothesis is presented and supported with data that gaseous organic carbon constituents of diesel exhaust adsorb onto not only the submicron elemental carbon particles found in diesel exhaust, but also mining ore dusts. Such mining dusts are mostly nonrespirable and should not be considered equivalent to submicron diesel particulates in their potential for adverse pulmonary effects. It is recommended that size-selective sampling be employed, rather than open-faced monitoring, when using the NIOSH 5040 method.

How work-self conflict/facilitation influences exhaustion and task performance: A three-wave study on the role of personal resources.

PubMed

Demerouti, Evangelia; Sanz-Vergel, Ana Isabel; Petrou, Paraskevas; van den Heuvel, Machteld

2016-10-01

Although work and family are undoubtedly important life domains, individuals are also active in other life roles which are also important to them (like pursuing personal interests). Building on identity theory and the resource perspective on work-home interface, we examined whether there is an indirect effect of work-self conflict/facilitation on exhaustion and task performance over time through personal resources (i.e., self-efficacy and optimism). The sample was composed of 368 Dutch police officers. Results of the 3-wave longitudinal study confirmed that work-self conflict was related to lower levels of self-efficacy, whereas work-self facilitation was related to improved optimism over time. In turn, self-efficacy was related to higher task performance, whereas optimism was related to diminished levels of exhaustion over time. Further analysis supported the negative, indirect effect of work-self facilitation on exhaustion through optimism over time, and only a few reversed causal effects emerged. The study contributes to the literature on interrole management by showing the role of personal resources in the process of conflict or facilitation over time. (PsycINFO Database Record (c) 2016 APA, all rights reserved).

40 CFR 1065.546 - Validation of minimum dilution ratio for PM batch sampling.

Code of Federal Regulations, 2012 CFR

2012-07-01

... chemical balance terms as given in § 1065.655(e). You may determine the raw exhaust flow rate based on the measured intake air and dilute exhaust molar flow rates and the dilute exhaust chemical balance terms as... air, fuel rate measurements, and fuel properties, consistent with good engineering judgment. (b...

40 CFR 1065.546 - Validation of minimum dilution ratio for PM batch sampling.

Code of Federal Regulations, 2013 CFR

2013-07-01

... chemical balance terms as given in § 1065.655(e). You may determine the raw exhaust flow rate based on the measured intake air and dilute exhaust molar flow rates and the dilute exhaust chemical balance terms as... air, fuel rate measurements, and fuel properties, consistent with good engineering judgment. (b...

40 CFR 1065.546 - Verification of minimum dilution ratio for PM batch sampling.

Code of Federal Regulations, 2014 CFR

2014-07-01

... chemical balance terms as given in § 1065.655(e). You may determine the raw exhaust flow rate based on the measured intake air and dilute exhaust molar flow rates and the dilute exhaust chemical balance terms as... air, fuel rate measurements, and fuel properties, consistent with good engineering judgment. (b...

Chrysotile asbestos exposure associated with removal of automobile exhaust systems (ca. 1945-1975) by mechanics: results of a simulation study.

PubMed

Paustenbach, Dennis J; Madl, Amy K; Donovan, Ellen; Clark, Katherine; Fehling, Kurt; Lee, Terry C

2006-03-01

For decades, asbestos-containing gaskets were used in virtually every system that involved the transport of fluids or gases. Prior to the mid-1970s, some automobile exhaust systems contained asbestos gaskets either at flanges along the exhaust pipes or at the exhaust manifolds of the engine. A limited number of automobile mufflers were lined with asbestos paper. This paper describes a simulation study that characterized personal and bystander exposures to asbestos during the removal of automobile exhaust systems (ca. 1945-1975) containing asbestos gaskets. A total of 16 pre-1974 vehicles with old or original exhaust systems were studied. Of the 16 vehicles, 12 contained asbestos gaskets in the exhaust system and two vehicles had asbestos lining inside the muffler. A total of 82 samples (23 personal, 38 bystander, and 21 indoor background) were analyzed by Phase Contrast Microscopy (PCM) and 88 samples (25 personal, 41 bystander, and 22 indoor background) by Transmission Electron Microscopy (TEM). Only seven of 25 worker samples analyzed by TEM detected asbestos fibers and 18 were below the analytical sensitivity limit (mean 0.013 f/cc, range 0.001-0.074 f/cc). Applying the ratio of asbestos fibers:total fibers (including non-asbestos) as determined by TEM to the PCM results showed an average (1 h) adjusted PCM worker exposure of 0.018 f/cc (0.002-0.04 f/cc). The average (1 h) adjusted PCM airborne concentration for bystanders was 0.008 f/cc (range 0.0008-0.015 f/cc). Assuming a mechanic can replace four automobile single exhaust systems in 1 workday, the estimated 8-h time-weighted average (TWA) for a mechanic performing this work was 0.01 f/cc. Under a scenario where a mechanic might repeatedly conduct exhaust work, these results suggest that exposures to asbestos from work with automobile exhaust systems during the 1950s through the 1970s containing asbestos gaskets were substantially below 0.1 f/cc, the current PEL for chrysotile asbestos, and quite often were not detectable.

Generic particulate-monitoring system for retrofit to Hanford exhaust stacks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Camman, J.W.; Carbaugh, E.H.

1982-11-01

Evaluations of 72 sampling and monitoring systems were performed at Hanford as the initial phase of a program to upgrade such systems. Each evaluation included determination of theoretical sampling efficiencies for particle sizes ranging from 0.5 to 10 micrometers aerodynamic equivalent diameter, addressing anisokinetic bias, sample transport line losses, and collector device efficiency. Upgrades needed to meet current Department of Energy guidance for effluent sampling and monitoring were identified, and a cost for each upgrade was estimated. A relative priority for each system's upgrade was then established based on evaluation results, current operational status, and future plans for the facilitymore » being exhausted. Common system upgrade requirements lead to the development of a generic design for common components of an exhaust stack sampling and monitoring system for airborne radioactive particulates. The generic design consists of commercially available off-the-shelf components to the extent practical and will simplify future stack sampling and monitoring system design, fabrication, and installation efforts. Evaluation results and their significance to system upgrades are empasized. A brief discussion of the analytical models used and experience to date with the upgrade program is included. Development of the generic stack sampling and monitoring system design is outlined. Generic system design features and limitations are presented. Requirements for generic system retrofitting to existing exhaust stacks are defined and benefits derived from generic system application are discussed.« less

Evaluation of thermal optical analysis method of elemental carbon for marine fuel exhaust.

PubMed

Lappi, Maija K; Ristimäki, Jyrki M

2017-12-01

The awareness of black carbon (BC) as the second largest anthropogenic contributor in global warming and an ice melting enhancer has increased. Due to prospected increase in shipping especially in the Arctic reliability of BC emissions and their invented amounts from ships is gaining more attention. The International Maritime Organization (IMO) is actively working toward estimation of quantities and effects of BC especially in the Arctic. IMO has launched work toward constituting a definition for BC and agreeing appropriate methods for its determination from shipping emission sources. In our study we evaluated the suitability of elemental carbon (EC) analysis by a thermal-optical transmittance (TOT) method to marine exhausts and possible measures to overcome the analysis interferences related to the chemically complex emissions. The measures included drying with CaSO 4, evaporation at 40-180ºC, H 2 O treatment, and variation of the sampling method (in-stack and diluted) and its parameters (e.g., dilution ratio, Dr). A reevaluation of the nominal organic carbon (OC)/EC split point was made. Measurement of residual carbon after solvent extraction (TC-C SOF ) was used as a reference, and later also filter smoke number (FSN) measurement, which is dealt with in a forthcoming paper by the authors. Exhaust sources used for collecting the particle sample were mainly four-stroke marine engines operated with variable loads and marine fuels ranging from light to heavy fuel oils (LFO and HFO) with a sulfur content range of <0.1-2.4% S. The results were found to be dependent on many factors, namely, sampling, preparation and analysis method, and fuel quality. It was found that the condensed H 2 SO 4 + H 2 O on the particulate matter (PM) filter had an effect on the measured EC content, and also promoted the formation of pyrolytic carbon (PyC) from OC, affecting the accuracy of EC determination. Thus, uncertainty remained regarding the EC results from HFO fuels. The work supports one part of the decision making in black carbon (BC) determination methodology. If regulations regarding BC emissions from marine engines will be implemented in the future, a well-defined and at best unequivocal method of BC determination is required for coherent and comparable emission inventories and estimating BC effects. As the aerosol from marine emission sources may be very heterogeneous and low in BC, special attention to the effects of sampling conditions and sample pretreatments on the validity of the results was paid in developing the thermal-optical analysis methodology (TOT).

Solid propellant exhausted aluminum oxide and hydrogen chloride - Environmental considerations

NASA Technical Reports Server (NTRS)

Cofer, W. R., III; Winstead, E. L.; Purgold, G. C.; Edahl, R. A.

1993-01-01

Measurements of gaseous hydrogen chloride (HCl) and particulate aluminum oxide (Al2O3) were made during penetrations of five Space Shuttle exhaust clouds and one static ground test firing of a shuttle booster. Instrumented aircraft were used to penetrate exhaust clouds and to measure and/or collect samples of exhaust for subsequent analyses. The focus was on the primary solid rocket motor exhaust products, HCl and Al2O3, from the Space Shuttle's solid boosters. Time-dependent behavior of HCl was determined for the exhaust clouds. Composition, morphology, surface chemistry, and particle size distributions were determined for the exhausted Al2O3. Results determined for the exhaust cloud from the static test firing were complicated by having large amounts of entrained alkaline ground debris (soil) in the lofted cloud. The entrained debris may have contributed to neutralization of in-cloud HCl.

40 CFR 86.109-94 - Exhaust gas sampling system; Otto-cycle vehicles not requiring particulate emission measurements.

Code of Federal Regulations, 2010 CFR

2010-07-01

...-cycle vehicles not requiring particulate emission measurements. 86.109-94 Section 86.109-94 Protection... Year New Light-Duty Vehicles and New Light-Duty Trucks and New Otto-Cycle Complete Heavy-Duty Vehicles; Test Procedures § 86.109-94 Exhaust gas sampling system; Otto-cycle vehicles not requiring particulate...

Odor intensity and characterization of jet exhaust and chemical analytical measurements

NASA Technical Reports Server (NTRS)

Kendall, D. A.; Levins, P. L.

1973-01-01

Odor and chemical analyses were carried out on the exhaust samples from a J-57 combustor can operated over a range of inlet conditions, and with several fuel types and nozzle modifications. The odor characteristics and total intensity of odor for each exhaust were determined over a range of dilutions to allow for a least squares determination of the intensity at 1,000 to 1 dilutions. Analytical measures included the concentration of total hydrocarbons and the concentrations of aromatic organic species and oxygenated organic species from collected samples which were taken concurrently. A correlation was found between the concentration of the odorous oxygenated fraction and the total intensity of aroma. Inlet operating conditions and nozzle modifications which increase the efficiency of combustion as measured by exhaust gas analyses reduce the odor intensity and the quantity of oxygenates in the exhaust. The type of fuel burned altered the intensity of odor in relation to the quantity of oxygenates produced and, in some instances, changed the odor character.

40 CFR 86.1311-94 - Exhaust gas analytical system; CVS bag sample.

Code of Federal Regulations, 2011 CFR

2011-07-01

... desiccating silica gel to remove water vapor, and containing ascarite to remove carbon dioxide from the CO analysis stream. (i) If CO instruments are used which are essentially free of CO2 and water vapor... instrument will be considered to be essentially free of CO2 and water vapor interference if its response to a...

40 CFR 86.1311-94 - Exhaust gas analytical system; CVS bag sample.

Code of Federal Regulations, 2012 CFR

2012-07-01

... desiccating silica gel to remove water vapor, and containing ascarite to remove carbon dioxide from the CO analysis stream. (i) If CO instruments are used which are essentially free of CO2 and water vapor... instrument will be considered to be essentially free of CO2 and water vapor interference if its response to a...

40 CFR 86.1311-94 - Exhaust gas analytical system; CVS bag sample.

Code of Federal Regulations, 2010 CFR

2010-07-01

... desiccating silica gel to remove water vapor, and containing ascarite to remove carbon dioxide from the CO analysis stream. (i) If CO instruments are used which are essentially free of CO2 and water vapor... instrument will be considered to be essentially free of CO2 and water vapor interference if its response to a...

40 CFR 86.1311-94 - Exhaust gas analytical system; CVS bag sample.

Code of Federal Regulations, 2013 CFR

2013-07-01

... desiccating silica gel to remove water vapor, and containing ascarite to remove carbon dioxide from the CO analysis stream. (i) If CO instruments are used which are essentially free of CO2 and water vapor... instrument will be considered to be essentially free of CO2 and water vapor interference if its response to a...

Analysis, Verification, and Application of Equations and Procedures for Design of Exhaust-pipe Shrouds

NASA Technical Reports Server (NTRS)

Ellerbrock, Herman H.; Wcislo, Chester R.; Dexter, Howard E.

1947-01-01

Investigations were made to develop a simplified method for designing exhaust-pipe shrouds to provide desired or maximum cooling of exhaust installations. Analysis of heat exchange and pressure drop of an adequate exhaust-pipe shroud system requires equations for predicting design temperatures and pressure drop on cooling air side of system. Present experiments derive such equations for usual straight annular exhaust-pipe shroud systems for both parallel flow and counter flow. Equations and methods presented are believed to be applicable under certain conditions to the design of shrouds for tail pipes of jet engines.

Performance of particulate containment at nanotechnology workplaces

NASA Astrophysics Data System (ADS)

Lo, Li-Ming; Tsai, Candace S.-J.; Dunn, Kevin H.; Hammond, Duane; Marlow, David; Topmiller, Jennifer; Ellenbecker, Michael

2015-11-01

The evaluation of engineering controls for the production or use of carbon nanotubes (CNTs) was investigated at two facilities. These control assessments are necessary to evaluate the current status of control performance and to develop proper control strategies for these workplaces. The control systems evaluated in these studies included ventilated enclosures, exterior hoods, and exhaust filtration systems. Activity-based monitoring with direct-reading instruments and filter sampling for microscopy analysis were used to evaluate the effectiveness of control measures at study sites. Our study results showed that weighing CNTs inside the biological safety cabinet can have a 37 % reduction on the particle concentration in the worker's breathing zone, and produce a 42 % lower area concentration outside the enclosure. The ventilated enclosures used to reduce fugitive emissions from the production furnaces exhibited good containment characteristics when closed, but they failed to contain emissions effectively when opened during product removal/harvesting. The exhaust filtration systems employed for exhausting these ventilated enclosures did not provide promised collection efficiencies for removing engineered nanomaterials from furnace exhaust. The exterior hoods were found to be a challenge for controlling emissions from machining nanocomposites: the downdraft hood effectively contained and removed particles released from the manual cutting process, but using the canopy hood for powered cutting of nanocomposites created 15-20 % higher ultrafine (<500 nm) particle concentrations at the source and at the worker's breathing zone. The microscopy analysis showed that CNTs can only be found at production sources but not at the worker breathing zones during the tasks monitored.

Emotional Dissonance, Mental Health Complaints, and Sickness Absence Among Health- and Social Workers. The Moderating Role of Self-Efficacy

PubMed Central

Indregard, Anne-Marthe R.; Knardahl, Stein; Nielsen, Morten B.

2018-01-01

Health- and social workers are frequently exposed to emotionally demanding work situations that require emotion regulation. Studies have demonstrated a direct relationship between emotion regulation and health complaints and sickness absence. In order to prevent health complaints and to reduce sickness absence among health- and social workers, there is need for greater attention to mechanisms explaining when and how emotionally demanding work situations are related to employee health and sickness absence. The overarching aim of this study was therefore to examine the moderating role of generalized self-efficacy on the association between emotional dissonance, employee health (mental distress and exhaustion), and registry based sickness absence. The sample consisted of 937 health- and social workers. Data on emotional dissonance, generalized self-efficacy, exhaustion, and mental distress was collected through questionnaires, whereas official registry data were used to assess sickness absence. A two-step hierarchical regression analysis showed that emotional dissonance was significantly associated with exhaustion, mental distress, and sickness absence, after adjusting for sex, age, and occupation. Interaction analyses with simple slope tests found that self-efficacy moderated the association between emotional dissonance and both exhaustion and mental distress, but not the association with sickness absence. This study shows that health- and social workers who frequently experience emotional dissonance report higher levels of exhaustion and mental distress, and have a higher risk of medically certified sickness absence. Further, health- and social workers with lower self-efficacy beliefs are apparently more sensitive to the degree of emotional dissonance and experienced higher levels of exhaustion and mental distress. PMID:29740375

Emotional Dissonance, Mental Health Complaints, and Sickness Absence Among Health- and Social Workers. The Moderating Role of Self-Efficacy.

PubMed

Indregard, Anne-Marthe R; Knardahl, Stein; Nielsen, Morten B

2018-01-01

Health- and social workers are frequently exposed to emotionally demanding work situations that require emotion regulation. Studies have demonstrated a direct relationship between emotion regulation and health complaints and sickness absence. In order to prevent health complaints and to reduce sickness absence among health- and social workers, there is need for greater attention to mechanisms explaining when and how emotionally demanding work situations are related to employee health and sickness absence. The overarching aim of this study was therefore to examine the moderating role of generalized self-efficacy on the association between emotional dissonance, employee health (mental distress and exhaustion), and registry based sickness absence. The sample consisted of 937 health- and social workers. Data on emotional dissonance, generalized self-efficacy, exhaustion, and mental distress was collected through questionnaires, whereas official registry data were used to assess sickness absence. A two-step hierarchical regression analysis showed that emotional dissonance was significantly associated with exhaustion, mental distress, and sickness absence, after adjusting for sex, age, and occupation. Interaction analyses with simple slope tests found that self-efficacy moderated the association between emotional dissonance and both exhaustion and mental distress, but not the association with sickness absence. This study shows that health- and social workers who frequently experience emotional dissonance report higher levels of exhaustion and mental distress, and have a higher risk of medically certified sickness absence. Further, health- and social workers with lower self-efficacy beliefs are apparently more sensitive to the degree of emotional dissonance and experienced higher levels of exhaustion and mental distress.

14 CFR 34.82 - Sampling and analytical procedures for measuring smoke exhaust emissions.

Code of Federal Regulations, 2012 CFR

2012-01-01

..., DEPARTMENT OF TRANSPORTATION AIRCRAFT FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE ENGINE POWERED AIRPLANES Test Procedures for Engine Smoke Emissions (Aircraft Gas Turbine Engines) § 34.82...

A comparative study of the elemental composition of the exhaust emissions of cars powered by liquefied petroleum gas and unleaded petrol

NASA Astrophysics Data System (ADS)

Lim, McKenzie C. H.; Ayoko, Godwin A.; Morawska, Lidia; Ristovski, Zoran D.; Jayaratne, E. Rohan; Kokot, Serge

Elements emitted from the exhausts of new Ford Falcon Forte cars powered by unleaded petrol (ULP) and liquefied petroleum gas (LPG) were measured on a chassis dynamometer. The measurements were carried out in February, June and August 2001, and at two steady state driving conditions (60 and 80 km h -1). Thirty seven elements were quantified in the exhaust samples by inductively coupled plasma mass spectrometry (ICPMS). The total emission factors of the elements from the exhausts of ULP cars were higher than those of LPG cars at both engine speeds even though high variability in the exhaust emissions from different cars was noted. The effect of the operating conditions such as mileage of the cars, engine speed, fuel and lubricating oil compositions on the emissions was studied. To investigate the effects of these conditions, multivariate data analysis methods were employed including exploratory principal component analysis (PCA), and the multi-criteria decision making methods (MCDM), preference ranking organization method for enrichment evaluation (PROMETHEE) and geometrical analysis for interactive aid (GAIA), for ranking the cars on the basis of the emission factors of the elements. PCA biplot of the complete data matrix showed a clear discrimination of the February, June and August emission test results. In addition, (i) platinum group elements (PGE) emissions were separated from each other in the three different clusters viz. Pt with February, Pd with June and Rh with August; (ii) the motor oil related elements, Zn and P, were particularly associated with the June and August tests (these vectors were also grouped with V, Al and Cu); and (iii) highest emissions of most major elements were associated with the August test after the cars have recorded their highest mileage. Extensive analysis with the aid of the MCDM ranking methods demonstrated clearly that cars powered by LPG outperform those powered by ULP. In general, cars tested in June perform better than those tested in August, which suggested that mileage was the key criterion of car performance on the basis of elemental emission factors.

Morphologic and chemical composition of particulate matter in motorcycle engine exhaust.

PubMed

Chernyshev, V V; Zakharenko, A M; Ugay, S M; Hien, T T; Hai, L H; Kholodov, A S; Burykina, T I; Stratidakis, A K; Mezhuev, Ya O; Tsatsakis, A M; Golokhvast, K S

2018-01-01

Despite the fact that environmental pollution due to motorcycle exhaust gases reports a great increase, motorcycle production exhibits a great increase through the last years. Countries of Asia and Africa are reported to be the major regions where two-wheeled vehicles are a major transportation mode, with tens of millions of units sold per year. Motorcycle exhaust particles are considered to be the major contributor to environmental pollution due to their airborne dispersion, containing great amount of polycyclic aromatic hydrocarbons (PAHs). This study aims at reporting an objective analysis of the main sources of the ambient air pollution as also particle size distribution and chemical composition analysis of particulate matter originated from the exhausts of two-wheeled vehicles used in the territory of Vladivostok, Russia. Various types of two-wheeled vehicles were examined (motorcycles, ATVs, scooters and wet bikes) using different types of engine and fuel system. Experimental results showed that there was no clear relation to the particle size distribution with the engine displacement of motorcycle and the number of strokes and the fuel system. Instead, there were reported two clear assumptions. The first one is that regarding to the motorcycle brand, a few samples did not exhibit a great percentage of PM 10 fraction. The second one is that more modern vehicles, that have a harmful gas afterburning system, are usually the source of an increased percentage of PM 10 emitted particles. At last, it should be mentioned that the laser particle size analysis method is capable of determining the particle sizes after their agglomeration whereas the optical morphometry method allows to determine the real particle size of emissions. In conclusion, it can be pointed out that the agglomeration of particles can lead to the reduction in the toxicity of particles emissions originated from two wheeled-vehicles.

Assessment of the LV-S2 & LV-S3 Stack Sampling Probe Locations for Compliance with ANSI/HPS N13.1-1999

DOE Office of Scientific and Technical Information (OSTI.GOV)

Glissmeyer, John A.; Antonio, Ernest J.; Flaherty, Julia E.

2014-09-30

This document reports on a series of tests conducted to assess the proposed air sampling locations for the Hanford Tank Waste Treatment and Immobilization Plant (WTP) Group 1-2A exhaust stacks with respect to the applicable criteria regarding the placement of an air sampling probe. The LV-C2, LV-S2, and LV-S3 exhaust stacks were tested together as a group (Test Group 1-2A). This report only covers the results of LV-S2 and LV-S3; LV-C2 will be reported on separately. Federal regulations1 require that a sampling probe be located in the exhaust stack according to the criteria established by the American National Standards Institute/Healthmore » Physics Society (ANSI/HPS) N13.1-1999, Sampling and Monitoring Releases of Airborne Radioactive Substances from the Stack and Ducts of Nuclear Facilities. 2 These criteria address the capability of the sampling probe to extract a sample that represents the effluent stream.« less

Gene Expression Changes in the Olfactory Bulb of Mice Induced by Exposure to Diesel Exhaust Are Dependent on Animal Rearing Environment

PubMed Central

Yokota, Satoshi; Hori, Hiroshi; Umezawa, Masakazu; Kubota, Natsuko; Niki, Rikio; Yanagita, Shinya; Takeda, Ken

2013-01-01

There is an emerging concern that particulate air pollution increases the risk of cranial nerve disease onset. Small nanoparticles, mainly derived from diesel exhaust particles reach the olfactory bulb by their nasal depositions. It has been reported that diesel exhaust inhalation causes inflammation of the olfactory bulb and other brain regions. However, these toxicological studies have not evaluated animal rearing environment. We hypothesized that rearing environment can change mice phenotypes and thus might alter toxicological study results. In this study, we exposed mice to diesel exhaust inhalation at 90 µg/m3, 8 hours/day, for 28 consecutive days after rearing in a standard cage or environmental enrichment conditions. Microarray analysis found that expression levels of 112 genes were changed by diesel exhaust inhalation. Functional analysis using Gene Ontology revealed that the dysregulated genes were involved in inflammation and immune response. This result was supported by pathway analysis. Quantitative RT-PCR analysis confirmed 10 genes. Interestingly, background gene expression of the olfactory bulb of mice reared in a standard cage environment was changed by diesel exhaust inhalation, whereas there was no significant effect of diesel exhaust exposure on gene expression levels of mice reared with environmental enrichment. The results indicate for the first time that the effect of diesel exhaust exposure on gene expression of the olfactory bulb was influenced by rearing environment. Rearing environment, such as environmental enrichment, may be an important contributive factor to causation in evaluating still undefined toxic environmental substances such as diesel exhaust. PMID:23940539

Particulate exhaust emissions from an experimental combustor. [gas turbine engine

NASA Technical Reports Server (NTRS)

Norgren, C. T.; Ingebo, R. D.

1975-01-01

The concentration of dry particulates (carbon) in the exhaust of an experimental gas turbine combustor was measured at simulated takeoff operating conditions and correlated with the standard smoke-number measurement. Carbon was determined quantitatively from a sample collected on a fiberglass filter by converting the carbon in the smoke sample to carbon dioxide and then measuring the volume of carbon dioxide formed by gas chromatography. At a smoke of 25 (threshold of visibility of the smoke plume for large turbojets) the carbon concentration was 2.8 mg carbon/cu m exhaust gas, which is equivalent to an emission index of 0.17 g carbon/kg fuel.

40 CFR 86.159-00 - Exhaust emission test procedures for US06 emissions.

Code of Federal Regulations, 2010 CFR

2010-07-01

... for THC, CO, CO2, CH4, and NOX. For petroleum-fueled diesel-cycle vehicles, THC is sampled and... analyzed for THC, CO, CO2, CH4, and NOX. (b) Dynamometer activities. (1) All official US06 tests shall be... pumps, the temperature recorder, the vehicle cooling fan, and the heated THC analysis recorder (diesel...

40 CFR 86.159-00 - Exhaust emission test procedures for US06 emissions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... for THC, CO, CO2, CH4, and NOX. For petroleum-fueled diesel-cycle vehicles, THC is sampled and... analyzed for THC, CO, CO2, CH4, and NOX. (b) Dynamometer activities. (1) All official US06 tests shall be... pumps, the temperature recorder, the vehicle cooling fan, and the heated THC analysis recorder (diesel...

40 CFR 86.159-00 - Exhaust emission test procedures for US06 emissions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... for THC, CO, CO2, CH4, and NOX. For petroleum-fueled diesel-cycle vehicles, THC is sampled and... analyzed for THC, CO, CO2, CH4, and NOX. (b) Dynamometer activities. (1) All official US06 tests shall be... pumps, the temperature recorder, the vehicle cooling fan, and the heated THC analysis recorder (diesel...

40 CFR 86.159-00 - Exhaust emission test procedures for US06 emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

... for THC, CO, CO2, CH4, and NOX. For petroleum-fueled diesel-cycle vehicles, THC is sampled and... analyzed for THC, CO, CO2, CH4, and NOX. (b) Dynamometer activities. (1) All official US06 tests shall be... pumps, the temperature recorder, the vehicle cooling fan, and the heated THC analysis recorder (diesel...

40 CFR 86.1823-08 - Durability demonstration procedures for exhaust emissions.

Code of Federal Regulations, 2012 CFR

2012-07-01

... delivers the appropriate exhaust flow, exhaust constituents, and exhaust temperature to the face of the... vehicles. (2) This data set must consist of randomly procured vehicles from actual customer use. The... equivalency factor. (C) The manufacturer must submit an analysis which evaluates whether the durability...

The use of purposeful sampling in a qualitative evidence synthesis: A worked example on sexual adjustment to a cancer trajectory.

PubMed

Benoot, Charlotte; Hannes, Karin; Bilsen, Johan

2016-02-18

An increasing number of qualitative evidence syntheses papers are found in health care literature. Many of these syntheses use a strictly exhaustive search strategy to collect articles, mirroring the standard template developed by major review organizations such as the Cochrane and Campbell Collaboration. The hegemonic idea behind it is that non-comprehensive samples in systematic reviews may introduce selection bias. However, exhaustive sampling in a qualitative evidence synthesis has been questioned, and a more purposeful way of sampling papers has been proposed as an alternative, although there is a lack of transparency on how these purposeful sampling strategies might be applied to a qualitative evidence synthesis. We discuss in our paper why and how we used purposeful sampling in a qualitative evidence synthesis about 'sexual adjustment to a cancer trajectory', by giving a worked example. We have chosen a mixed purposeful sampling, combining three different strategies that we considered the most consistent with our research purpose: intensity sampling, maximum variation sampling and confirming/disconfirming case sampling. The concept of purposeful sampling on the meta-level could not readily been borrowed from the logic applied in basic research projects. It also demands a considerable amount of flexibility, and is labour-intensive, which goes against the argument of many authors that using purposeful sampling provides a pragmatic solution or a short cut for researchers, compared with exhaustive sampling. Opportunities of purposeful sampling were the possible inclusion of new perspectives to the line-of-argument and the enhancement of the theoretical diversity of the papers being included, which could make the results more conceptually aligned with the synthesis purpose. This paper helps researchers to make decisions related to purposeful sampling in a more systematic and transparent way. Future research could confirm or disconfirm the hypothesis of conceptual enhancement by comparing the findings of a purposefully sampled qualitative evidence synthesis with those drawing on an exhaustive sample of the literature.

An exploratory study of the relationship between resilience, academic burnout and psychological health in nursing students.

PubMed

Ríos-Risquez, Mª Isabel; García-Izquierdo, Mariano; Sabuco-Tebar, Emiliana de Los Angeles; Carrillo-Garcia, Cesar; Martinez-Roche, Maria Emilia

2016-08-01

The purpose of this study was to examine the relationship between resilience, academic burnout and psychological health in a sample of nursing students. A descriptive and cross-sectional design was applied, with questionnaires as tools. The convenience sample consisted of 113 nursing students in their final academic year, who voluntarily participated in the study. The results indicated a statistically significant relationship between resilience and both emotional exhaustion (r = -.55; p < .01) and psychological health (r = -.62; p < .01), as well as between all three dimensions of burnout and psychological health. Hierarchical multiple regression analysis indicated that high scores for resilience and low scores for emotional exhaustion predict better perceived psychological health [F (2.96)  = 17.75; p < .001]. Resilience was associated with lower levels of psychological discomfort and academic burnout. These findings highlight the importance of developing resilience and integrating it as an element in the nursing educational programme.

Resonant photoacoustic detection of NO2 traces with a Q-switched green laser

NASA Astrophysics Data System (ADS)

Slezak, Verónica; Codnia, Jorge; Peuriot, Alejandro L.; Santiago, Guillermo

2003-01-01

Resonant photoacoustic detection of NO2 traces by means of a high repetition pulsed green laser is presented. The resonator is a cylindrical Pyrex glass cell with a measured Q factor 380 for the first radial mode in air at atmospheric pressure. The system is calibrated with known mixtures in dry air and a minimum detectable volume concentration of 50 parts in 109 is obtained (S/N=1). Its sensitivity allows one to detect and quantify NO2 traces in the exhaust gases of cars. Previously, the analysis of gas adsorption and desorption on the walls and of changes in the sample composition is carried out in order to minimize errors in the determination of NO2 content upon application of the extractive method. The efficiency of catalytic converters of several models of automobiles is studied and the NO2 concentration in samples from exhausts of different types of engine (gasoline, diesel, and methane gas) at idling operation are measured.

Is cultural activity at work related to mental health in employees?

PubMed

Theorell, Töres; Osika, Walter; Leineweber, Constanze; Magnusson Hanson, Linda L; Bojner Horwitz, Eva; Westerlund, Hugo

2013-04-01

To examine relationships between work-based cultural activities and mental employee health in working Swedes. A positive relationship between frequent cultural activity at work and good employee health was expected. Random sample of working Swedish men and women in three waves, 2006, 2008 and 2010, on average 60 % participation rate. A postal questionnaire with questions about cultural activities organised for employees and about emotional exhaustion (Maslach) and depressive symptoms (short form of SCL). Employee assessments of "non-listening manager" and work environment ("psychological demands" and "decision latitude") as well as socioeconomic variables were covariates. Cross-sectional analyses for each study year as well as prospective analyses for 2006-2008 and 2008-2010 were performed. Lower frequency of cultural activities at work during the period of high unemployment. The effects of relationships with emotional exhaustion were more significant than those with depressive symptoms. The associations were attenuated when adjustments were made for manager function (does your manager listen?) and demand/control. Associations were more pronounced during the period with low unemployment and high cultural activity at work (2008). In a prospective analysis, cultural activity at work in 2008 had an independent statistically significant "protective" effect on emotional exhaustion in 2010. No corresponding such association was found between 2006 and 2008. Cultural activities at work vary according to business cycle and have a statistical association with mental employee health, particularly with emotional exhaustion. There are particularly pronounced statistical protective effects of frequent cultural activity at work on likelihood of emotional exhaustion among employees.

The ventilatory anaerobic threshold is related to, but is lower than, the critical power, but does not explain exercise tolerance at this workrate.

PubMed

Okudan, N; Gökbel, H

2006-03-01

The aim of the present study was to investigate the relationships between critical power (CP), maximal aerobic power and the anaerobic threshold and whether exercise time to exhaustion and work at the CP can be used as an index in the determination of endurance. An incremental maximal cycle exercise test was performed on 30 untrained males aged 18-22 years. Lactate analysis was carried out on capillary blood samples at every 2 minutes. From gas exchange parameters and heart rate and lactate values, ventilatory anaerobic thresholds, heart rate deflection point and the onset of blood lactate accumulation were calculated. CP was determined with linear work-time method using 3 loads. The subjects exercised until they could no longer maintain a cadence above 24 rpm at their CP and exercise time to exhaustion was determined. CP was lower than the power output corresponding to VO2max, higher than the power outputs corresponding to anaerobic threshold. CP was correlated with VO2max and anaerobic threshold. Exercise time to exhaustion and work at CP were not correlated with VO2max and anaerobic threshold. Because of the correlations of the CP with VO2max and anaerobic threshold and no correlation of exercise time to exhaustion and work at the CP with these parameters, we conclude that exercise time to exhaustion and work at the CP cannot be used as an index in the determination of endurance.

Work schedule flexibility is associated with emotional exhaustion among registered nurses in Swiss hospitals: A cross-sectional study.

PubMed

Dhaini, Suzanne R; Denhaerynck, Kris; Bachnick, Stefanie; Schwendimann, René; Schubert, Maria; De Geest, Sabina; Simon, Michael

2018-06-01

Emotional exhaustion among healthcare workers is a widely investigated, well-recognized problem, the incidence of which has recently been linked to work environment factors, particularly work/family conflict. However, another environmental feature that may be equally influential, but that is more amenable to nurse manager action, remains less recognized: shift schedule flexibility. This study's main purposes were to assess variations in work schedule flexibility between Swiss acute care hospital units, and to investigate associations between psychosocial work environment (e.g. work schedule flexibility) and self-reported emotional exhaustion among registered nurses. This is a secondary analysis of data collected for the multi-center observational cross-sectional Match RN study, which included a national sample of 23 hospitals and 1833 registered nurses across Switzerland. Overall, self-reported work schedule flexibility among registered nurses was limited: 32% of participants reported little or no influence in planning their own shifts. Work schedule flexibility (β -0.11; CI -0.16; -0.06) and perceived nurse manager ability (β -0.30; CI -0.49; -0.10) were negatively related to self-reported emotional exhaustion. Work-family conflict (β 0.39; CI 0.33; 0.45) was positively correlated to emotional exhaustion. The study results indicate that managerial efforts to improve working environments, including special efforts to improve work schedule flexibility, might play an important role in promoting nurses' emotional health. Copyright © 2018 Elsevier Ltd. All rights reserved.

Exhaustive Exercise-induced Oxidative Stress Alteration of Erythrocyte Oxygen Release Capacity.

PubMed

Xiong, Yanlian; Xiong, Yanlei; Wang, Yueming; Zhao, Yajin; Li, Yaojin; Ren, Yang; Wang, Ruofeng; Zhao, Mingzi; Hao, Yitong; Liu, Haibei; Wang, Xiang

2018-05-24

The aim of the present study is to explore the effect of exhaustive running exercise (ERE) in the oxygen release capacity of rat erythrocytes. Rats were divided into sedentary control (C), moderate running exercise (MRE) and exhaustive running exercise groups. The thermodynamics and kinetics properties of the erythrocyte oxygen release process of different groups were tested. We also determined the degree of band-3 oxidative and phosphorylation, anion transport activity and carbonic anhydrase isoform II(CAII) activity. Biochemical studies suggested that exhaustive running significantly increased oxidative injury parameters in TBARS and methaemoglobin levels. Furthermore, exhaustive running significantly decreased anion transport activity and carbonic anhydrase isoform II(CAII) activity. Thermodynamic analysis indicated that erythrocytes oxygen release ability also significantly increased due to elevated 2,3-DPG level after exhaustive running. Kinetic analysis indicated that exhaustive running resulted in significantly decreased T50 value. We presented evidence that exhaustive running remarkably impacted thermodynamics and kinetics properties of RBCs oxygen release. In addition, changes in 2,3-DPG levels and band-3 oxidation and phosphorylation could be the driving force for exhaustive running induced alterations in erythrocytes oxygen release thermodynamics and kinetics properties.

Neighborhood-Scale Spatial Models of Diesel Exhaust Concentration Profile Using 1-Nitropyrene and Other Nitroarenes

PubMed Central

Schulte, Jill K.; Fox, Julie R.; Oron, Assaf P.; Larson, Timothy V.; Simpson, Christopher D.; Paulsen, Michael; Beaudet, Nancy; Kaufman, Joel D.; Magzamen, Sheryl

2016-01-01

With emerging evidence that diesel exhaust exposure poses distinct risks to human health, the need for fine-scale models of diesel exhaust pollutants is growing. We modeled the spatial distribution of several nitrated polycyclic aromatic hydrocarbons (NPAHs) to identify fine-scale gradients in diesel exhaust pollution in two Seattle, WA neighborhoods. Our modeling approach fused land-use regression, meteorological dispersion modeling, and pollutant monitoring from both fixed and mobile platforms. We applied these modeling techniques to concentrations of 1-nitropyrene (1-NP), a highly specific diesel exhaust marker, at the neighborhood scale. We developed models of two additional nitroarenes present in secondary organic aerosol: 2-nitro-pyrene and 2-nitrofluoranthene. Summer predictors of 1-NP, including distance to railroad, truck emissions, and mobile black carbon measurements, showed a greater specificity to diesel sources than predictors of other NPAHs. Winter sampling results did not yield stable models, likely due to regional mixing of pollutants in turbulent weather conditions. The model of summer 1-NP had an R2 of 0.87 and cross-validated R2 of 0.73. The synthesis of high-density sampling and hybrid modeling was successful in predicting diesel exhaust pollution at a very fine scale and identifying clear gradients in NPAH concentrations within urban neighborhoods. PMID:26501773

The association between job strain and emotional exhaustion in a cohort of 1,028 Finnish teachers.

PubMed

Santavirta, Nina; Solovieva, Svetlana; Theorell, Töres

2007-03-01

Teachers' work overload has been the subject of intense research, and the results of these studies show that a substantial proportion of teachers perceive their job as very stressful. To investigate how different formulations of high demands and low decision latitude was related to teachers' burnout, and to estimate the possible interaction between these factors. The sample consisted of 1,028 school teachers. Multivariate covariant analyses (MANCOVA) was used to evaluate the relationship between a high-strain job defined by 3 different cut-off points and burnout. Logistical regression analysis was used to estimate the separate and joint effects of demand and decision authority on emotional exhaustion. Interaction between high demands and low decision authority was analysed using relative excess risk due to interaction (RERI). An attributable proportion (AP) was calculated in order to estimate the proportion of emotionally exhausted teachers among those exposed to both risk factors that was attributable to their synergistic interaction. The group of teachers who perceived their job as a low-strain job was used as the reference group in the analysis. The effect of job strain on burnout was proved to be consistent and robust across alternative formulations. The main effect of high demands exceeded that of low decision authority in relation to emotional exhaustion. Furthermore, the 2 factors acted synergistically to increase the risk of burnout. In the case of burnout, teachers who perceived their job as highly demanding and low in control, 69% of the effect could be attributed to the synergism of these 2 factors.

Performance of Particulate Containment at Nanotechnology Workplaces

PubMed Central

Lo, Li-Ming; Tsai, Candace S.-J.; Dunn, Kevin H.; Hammond, Duane; Marlow, David; Topmiller, Jennifer; Ellenbecker, Michael

2015-01-01

The evaluation of engineering controls for the production or use of carbon nanotubes (CNTs) was investigated at two facilities. These controls assessments are necessary to evaluate the current status of control performance and to develop proper control strategies for these workplaces. The control systems evaluated in these studies included ventilated enclosures, exterior hoods, and exhaust filtration systems. Activity-based monitoring with direct-reading instruments and filter sampling for microscopy analysis were used to evaluate the effectiveness of control measures at study sites. Our study results showed that weighing CNTs inside the biological safety cabinet can have a 37% reduction on the particle concentration in the worker’s breathing zone, and produce a 42% lower area concentration outside the enclosure. The ventilated enclosures used to reduce fugitive emissions from the production furnaces exhibited good containment characteristics when closed, but they failed to contain emissions effectively when opened during product removal/harvesting. The exhaust filtration systems employed for exhausting these ventilated enclosures did not provide promised collection efficiencies for removing engineered nanomaterials from furnace exhaust. The exterior hoods were found to be a challenge for controlling emissions from machining nanocomposites: the downdraft hood effectively contained and removed particles released from the manual cutting process, but using the canopy hood for powered cutting of nanocomposites created 15%–20% higher ultrafine (<500 nm) particle concentrations at the source and at the worker’s breathing zone. The microscopy analysis showed that CNTs can only be found at production sources but not at the worker breathing zones during the tasks monitored. PMID:26705393

Detection of ethene and other hydrocarbons in gas turbine engine exhaust using non-intrusive FTIR spectroscopy

NASA Astrophysics Data System (ADS)

Arrigone, Giovanni M.; Welch, Michael A.; Hilton, Moira; Miller, Michael N.; Wilson, Christopher W.

2003-04-01

As part of the EU funded project AEROJET2, a number of gas turbine engine tests were performed in different facilities around Europe. At Farnborough, UK a Spey engine was used to test a suite of prototype optically based instrumentation designed to measure exhaust gas emissions without using extractive probe systems. In addition to the AEROJET 2 prototype instrumentation, a Bruker Equinox 55 Fourier transform infrared (FTIR) spectrometer was used to obtain infrared spectra of the exhaust plume both in emission and absorption mode. The Bruker FTIR spectrometer was fitted with a periscope system so that different lines of sight could be monitored in the plume in a vertical plane 25 cm downstream from the nozzle exit and 20 cm upstream of the center line of sight of the AEROJET 2 prototype instrumentation. DERA (now QinetiQ) provided exhaust gas analysis data for different engine running conditions using samples extracted from the plume with an intrusive probe. The probe sampled along a horizontal plane across the centerline of the engine 45 cm downstream of the nozzle exit. The Bruker spectrometer used both InSb (indium antimonide) and MCT (mercury-cadmium-telluride) detectors to maximize the sensitivity across the IR range 600-4000 cm-1. Typically, CO2 and H2O IR signatures dominate the observed spectra of the plume. However, the engine tests showed that at low power engine conditions spectral features associated with CO around 2147 cm-1 and with hydrocarbons could be observed at around 3000 cm-1. In particular the presence of ethene (C2H2) was detected from observation of its characteristic in and out of plane vibration mode at 949 cm-1. At high engine powers the presence of NO was detected at 1900.3 cm-1. Species concentrations were calculated using a slab model for each line of sight compared against reference spectra. The engine plume was assumed to be symmetric about the centerline. On this basis, data from the extractive sampling gas analysis that had been obtained by traversing the probe across a horizontal plane through the centerline could be compared with non-intrusive measurements made by scanning vertically. Adjustments have been made to account for the 20 cm downstream offset in measurement planes of the probe and the spectrometer behind the nozzle exit.

Prediction of engine exhaust concentrations downwind from the Delta-Thor Telsat-A launch of 9 November 1972

NASA Technical Reports Server (NTRS)

Kaufman, J. W.; Susko, M.; Hill, C. K.

1973-01-01

Results are presented of the downwind concentrations of engine exhaust by-products from the Delta-Thor Telsat-A vehicle launched from Cape Kennedy, Florida on November 9, 1972 (2014 EST). The meteorological conditions which existed are identified as well as the exhaust cloud rise and the results from the MSFC Multilayer Diffusion Model calculations. These predictions are compared to exhaust cloud sampled data acquired by the Langley Research Center personnel. Values of the surface level concentrations show that very little hydrochloric acid, carbon monoxide, or aluminum oxide reached the ground.

Odor intensity and characterization studies of exhaust from a turbojet engine combustor

NASA Technical Reports Server (NTRS)

Butze, H. F.; Kendall, D. A.

1973-01-01

Sensory odor tests of the exhaust from a turbojet combustor operating at simulated idle conditions were made by a human panel sniffing diluted exhaust gas. Simultaneously, samples of undiluted exhaust gas were collected on adsorbent substrates, subsequently removed by solvent flushing, and analyzed chemically by liquid chromatographic methods. The concentrations of the principal malodorous species, the aromatic (unburned fuel-related) and the oxygenated (partially burned fuel) fractions, as determined chromatographically, correlated well with the intensity of the odor as determined by sniffing. Odor intensity increased as combustion efficiency decreased. Combustor modifications which increased combustion efficiency decreased odor intensity.

Jet Engine Exhaust Analysis by Subtractive Chromatography

DTIC Science & Technology

1978-12-01

FID B response = oxygenates + aromatics. Oxygenated compounds with 8 Tenax GC Carbosieve B Glass Wool Glass wool Glass Wool Sample Flow Desoption...sorbent samplinq. During the process of compiling this information a new series of sorbent materials that show promising sorbent characteristics was...produced by a process which "carbonizes" a porous polymer material. The pro- duct is a hard, shiny, black-beaded material. The promotional literature

Air flow quality analysis of modenas engine exhaust system

NASA Astrophysics Data System (ADS)

Shahriman A., B.; Mohamad Syafiq A., K.; Hashim, M. S. M.; Razlan, Zuradzman M.; Khairunizam W. A., N.; Hazry, D.; Afendi, Mohd; Daud, R.; Rahman, M. D. Tasyrif Abdul; Cheng, E. M.; Zaaba, S. K.

2017-09-01

The simulation process being conducted to determine the air flow effect between the original exhaust system and modified exhaust system. The simulations are conducted to investigate the flow distribution of exhaust gases that will affect the performance of the engine. The back flow pressure in the original exhaust system is predicted toward this simulation. The design modification to the exhaust port, exhaust pipe, and exhaust muffler has been done during this simulation to reduce the back flow effect. The new designs are introduced by enlarging the diameter of the exhaust port, enlarge the diameter of the exhaust pipe and created new design for the exhaust muffler. Based on the result obtained, there the pulsating flow form at the original exhaust port that will increase the velocity and resulting the back pressure occur. The result for new design of exhaust port, the velocity is lower at the valve guide in the exhaust port. New design muffler shows that the streamline of the exhaust flow move smoothly compare to the original muffler. It is proved by using the modification exhaust system, the back pressure are reduced and the engine performance can be improve.

Aerodynamic design and analysis of a highly loaded turbine exhaust

NASA Technical Reports Server (NTRS)

Huber, F. W.; Montesdeoca, X. A.; Rowey, R. J.

1993-01-01

The aerodynamic design and analysis of a turbine exhaust volute manifold is described. This turbine exhaust system will be used with an advanced gas generator oxidizer turbine designed for very high specific work. The elevated turbine stage loading results in increased discharge Mach number and swirl velocity which, along with the need for minimal circumferential variation of fluid properties at the turbine exit, represent challenging volute design requirements. The design approach, candidate geometries analyzed, and steady state/unsteady CFD analysis results are presented.

A Gas Chromatograph/Mass Spectrometer System for UltraLow-Emission Combustor Exhaust Studies

NASA Technical Reports Server (NTRS)

Brabbs, Theodore A.; Wey, Chowen Chou

1996-01-01

A gas chromatograph (GC)/mass spectrometer (MS) system that allows the speciation of unburnt hydrocarbons in the combustor exhaust has been developed at the NASA Lewis Research Center. Combustion gas samples are withdrawn through a water-cooled sampling probe which, when not in use, is protected from contamination by a high-pressure nitrogen purge. The sample line and its connecting lines, filters, and valves are all ultraclean and are heated to avoid condensation. The system has resolution to the parts-per-billion (ppb) level.

The characterisation of diesel exhaust particles - composition, size distribution and partitioning.

PubMed

Alam, Mohammed S; Zeraati-Rezaei, Soheil; Stark, Christopher P; Liang, Zhirong; Xu, Hongming; Harrison, Roy M

2016-07-18

A number of major research questions remain concerning the sources and properties of road traffic generated particulate matter. A full understanding of the composition of primary vehicle exhaust aerosol and its contribution to secondary organic aerosol (SOA) formation still remains elusive, and many uncertainties exist relating to the semi-volatile component of the particles. Semi-Volatile Organic Compounds (SVOCs) are compounds which partition directly between the gas and aerosol phases under ambient conditions. The SVOCs in engine exhaust are typically hydrocarbons in the C15-C35 range, and are largely uncharacterised because they are unresolved by traditional gas chromatography, forming a large hump in the chromatogram referred to as Unresolved Complex Mixture (UCM). In this study, thermal desorption coupled to comprehensive Two Dimensional Gas-Chromatography Time-of-Flight Mass-Spectrometry (TD-GC × GC-ToF-MS) was exploited to characterise and quantify the composition of SVOCs from the exhaust emission. Samples were collected from the exhaust of a diesel engine, sampling before and after a diesel oxidation catalyst (DOC), while testing at steady state conditions. Engine exhaust was diluted with air and collected using both filter and impaction (nano-MOUDI), to resolve total mass and size resolved mass respectively. Adsorption tubes were utilised to collect SVOCs in the gas phase and they were then analysed using thermal desorption, while particle size distribution was evaluated by sampling with a DMS500. The SVOCs were observed to contain predominantly n-alkanes, branched alkanes, alkyl-cycloalkanes, alkyl-benzenes, PAHs and various cyclic aromatics. Particle phase compounds identified were similar to those observed in engine lubricants, while vapour phase constituents were similar to those measured in fuels. Preliminary results are presented illustrating differences in the particle size distribution and SVOCs composition when collecting samples with and without a DOC. The results indicate that the DOC tested is of very limited efficiency, under the studied engine operating conditions, for removal of SVOCs, especially at the upper end of the molecular weight range.

Solid Phase Microextraction and Related Techniques for Drugs in Biological Samples

PubMed Central

Moein, Mohammad Mahdi; Said, Rana; Bassyouni, Fatma

2014-01-01

In drug discovery and development, the quantification of drugs in biological samples is an important task for the determination of the physiological performance of the investigated drugs. After sampling, the next step in the analytical process is sample preparation. Because of the low concentration levels of drug in plasma and the variety of the metabolites, the selected extraction technique should be virtually exhaustive. Recent developments of sample handling techniques are directed, from one side, toward automatization and online coupling of sample preparation units. The primary objective of this review is to present the recent developments in microextraction sample preparation methods for analysis of drugs in biological fluids. Microextraction techniques allow for less consumption of solvent, reagents, and packing materials, and small sample volumes can be used. In this review the use of solid phase microextraction (SPME), microextraction in packed sorbent (MEPS), and stir-bar sorbtive extraction (SBSE) in drug analysis will be discussed. In addition, the use of new sorbents such as monoliths and molecularly imprinted polymers will be presented. PMID:24688797

Diesel exhaust augments allergen-induced lower airway inflammation in allergic individuals: a controlled human exposure study.

PubMed

Carlsten, Chris; Blomberg, Anders; Pui, Mandy; Sandstrom, Thomas; Wong, Sze Wing; Alexis, Neil; Hirota, Jeremy

2016-01-01

Traffic-related air pollution has been shown to augment allergy and airway disease. However, the enhancement of allergenic effects by diesel exhaust in particular is unproven in vivo in the human lung, and underlying details of this apparent synergy are poorly understood. To test the hypothesis that a 2 h inhalation of diesel exhaust augments lower airway inflammation and immune cell activation following segmental allergen challenge in atopic subjects. 18 blinded atopic volunteers were exposed to filtered air or 300 µg PM(2.5)/m(3) of diesel exhaust in random fashion. 1 h post-exposure, diluent-controlled segmental allergen challenge was performed; 2 days later, samples from the challenged segments were obtained by bronchoscopic lavage. Samples were analysed for markers and modifiers of allergic inflammation (eosinophils, Th2 cytokines) and adaptive immune cell activation. Mixed effects models with ordinal contrasts compared effects of single and combined exposures on these end points. Diesel exhaust augmented the allergen-induced increase in airway eosinophils, interleukin 5 (IL-5) and eosinophil cationic protein (ECP) and the GSTT1 null genotype was significantly associated with the augmented IL-5 response. Diesel exhaust alone also augmented markers of non-allergic inflammation and monocyte chemotactic protein (MCP)-1 and suppressed activity of macrophages and myeloid dendritic cells. Inhalation of diesel exhaust at environmentally relevant concentrations augments allergen-induced allergic inflammation in the lower airways of atopic individuals and the GSTT1 genotype enhances this response. Allergic individuals are a susceptible population to the deleterious airway effects of diesel exhaust. NCT01792232. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://www.bmj.com/company/products-services/rights-and-licensing/

Monitoring of heavy metal particle emission in the exhaust duct of a foundry using LIBS.

PubMed

Dutouquet, C; Gallou, G; Le Bihan, O; Sirven, J B; Dermigny, A; Torralba, B; Frejafon, E

2014-09-01

Heavy metals have long been known to be detrimental to human health and the environment. Their emission is mainly considered to occur via the atmospheric route. Most of airborne heavy metals are of anthropogenic origin and produced through combustion processes at industrial sites such as incinerators and foundries. Current regulations impose threshold limits on heavy metal emissions. The reference method currently implemented for quantitative measurements at exhaust stacks consists of on-site sampling of heavy metals on filters for the particulate phase (the most prominent and only fraction considered in this study) prior to subsequent laboratory analysis. Results are therefore known only a few days after sampling. Stiffer regulations require the development of adapted tools allowing automatic, on-site or even in-situ measurements with temporal resolutions. The Laser-Induced Breakdown Spectroscopy (LIBS) technique was deemed as a potential candidate to meet these requirements. On site experiments were run by melting copper bars and monitoring emission of this element in an exhaust duct at a pilot-scale furnace in a French research center dedicated to metal casting. Two approaches designated as indirect and direct analysis were broached in these experiments. The former corresponds to filter enrichment prior to subsequent LIBS interrogation whereas the latter entails laser focusing right through the aerosol for detection. On-site calibration curves were built and compared with those obtained at laboratory scale in order to investigate possible matrix and analyte effects. Eventually, the obtained results in terms of detection limits and quantitative temporal monitoring of copper emission clearly emphasize the potentialities of the direct LIBS measurements. Copyright © 2014 Elsevier B.V. All rights reserved.

Road Environments: Impact of Metals on Human Health in Heavily Congested Cities of Poland

PubMed Central

Adamiec, Ewa

2017-01-01

Road dust as a by-product of exhaust and non-exhaust emissions can be a major cause of systemic oxidative stress and multiple disorders. Substantial amounts of road dust are repeatedly resuspended, in particular at traffic lights and junctions where more braking is involved, causing potential threat to pedestrians, especially children. In order to determine the degree of contamination in the heavily traffic-congested cities of Poland, a total of 148 samples of road dust (RD), sludge from storm drains (SL) and roadside soil (RS) were collected. Sixteen metals were analysed using inductively coupled plasma mass spectrometry (ICP-MS), inductively coupled plasma atomic emission spectroscopy (ICP-OES) and atomic absorption spectroscopy (AAS) in all samples. Chemical evaluation followed by Principal Component Analysis (PCA) revealed that road environments have been severely contaminated with traffic-related elements. Concentration of copper in all road-environment samples is even higher, exceeding even up to 15 times its average concentrations established for the surrounding soils. Non-carcinogenic health risk assessment revealed that the hazard index (HI) for children in all road-environment samples exceeds the safe level of 1. Therefore, greater attention should be paid to potential health risks caused by the ingestion of traffic-related particles during outdoor activities. PMID:28661464

Road Environments: Impact of Metals on Human Health in Heavily Congested Cities of Poland.

PubMed

Adamiec, Ewa

2017-06-29

Road dust as a by-product of exhaust and non-exhaust emissions can be a major cause of systemic oxidative stress and multiple disorders. Substantial amounts of road dust are repeatedly resuspended, in particular at traffic lights and junctions where more braking is involved, causing potential threat to pedestrians, especially children. In order to determine the degree of contamination in the heavily traffic-congested cities of Poland, a total of 148 samples of road dust (RD), sludge from storm drains (SL) and roadside soil (RS) were collected. Sixteen metals were analysed using inductively coupled plasma mass spectrometry (ICP-MS), inductively coupled plasma atomic emission spectroscopy (ICP-OES) and atomic absorption spectroscopy (AAS) in all samples. Chemical evaluation followed by Principal Component Analysis (PCA) revealed that road environments have been severely contaminated with traffic-related elements. Concentration of copper in all road-environment samples is even higher, exceeding even up to 15 times its average concentrations established for the surrounding soils. Non-carcinogenic health risk assessment revealed that the hazard index (HI) for children in all road-environment samples exceeds the safe level of 1. Therefore, greater attention should be paid to potential health risks caused by the ingestion of traffic-related particles during outdoor activities.

Variations in speciated emissions from spark-ignition and compression-ignition motor vehicles in California's south coast air basin.

PubMed

Fujita, Eric M; Zielinska, Barbara; Campbell, David E; Arnott, W Patrick; Sagebiel, John C; Mazzoleni, Lynn; Chow, Judith C; Gabele, Peter A; Crews, William; Snow, Richard; Clark, Nigel N; Wayne, W Scott; Lawson, Douglas R

2007-06-01

The U.S. Department of Energy Gasoline/Diesel PM Split Study examined the sources of uncertainties in using an organic compound-based chemical mass balance receptor model to quantify the contributions of spark-ignition (SI) and compression-ignition (CI) engine exhaust to ambient fine particulate matter (PM2.5). This paper presents the chemical composition profiles of SI and CI engine exhaust from the vehicle-testing portion of the study. Chemical analysis of source samples consisted of gravimetric mass, elements, ions, organic carbon (OC), and elemental carbon (EC) by the Interagency Monitoring of Protected Visual Environments (IMPROVE) and Speciation Trends Network (STN) thermal/optical methods, polycyclic aromatic hydrocarbons (PAHs), hopanes, steranes, alkanes, and polar organic compounds. More than half of the mass of carbonaceous particles emitted by heavy-duty diesel trucks was EC (IMPROVE) and emissions from SI vehicles contained predominantly OC. Although total carbon (TC) by the IMPROVE and STN protocols agreed well for all of the samples, the STN/IMPROVE ratios for EC from SI exhaust decreased with decreasing sample loading. SI vehicles, whether low or high emitters, emitted greater amounts of high-molecular-weight particulate PAHs (benzo[ghi]perylene, indeno[1,2,3-cd]pyrene, and coronene) than did CI vehicles. Diesel emissions contained higher abundances of two- to four-ring semivolatile PAHs. Diacids were emitted by CI vehicles but are also prevalent in secondary organic aerosols, so they cannot be considered unique tracers. Hopanes and steranes were present in lubricating oil with similar composition for both gasoline and diesel vehicles and were negligible in gasoline or diesel fuels. CI vehicles emitted greater total amounts of hopanes and steranes on a mass per mile basis, but abundances were comparable to SI exhaust normalized to TC emissions within measurement uncertainty. The combustion-produced high-molecular-weight PAHs were found in used gasoline motor oil but not in fresh oil and are negligible in used diesel engine oil. The contributions of lubrication oils to abundances of these PAHs in the exhaust were large in some cases and were variable with the age and consumption rate of the oil. These factors contributed to the observed variations in their abundances to total carbon or PM2.5 among the SI composition profiles.

Using GC×GC-ToF-MS to characterise SVOC from diesel exhaust emissions

NASA Astrophysics Data System (ADS)

Alam, M. S.; Ramadhas, A. S.; Stark, C. P.; Liu, D.; Xu, H.; Harrison, R. M.

2014-12-01

Despite intensive research over the last 20 years, a number of major research questions remain concerning the sources and properties of road traffic-generated particulate matter. There are major knowledge gaps concerning the composition of primary vehicle exhaust aerosol, and its contribution to secondary organic aerosol (SOA) formation. These uncertainties relate especially to the semi-volatile component of the particles. Semi-Volatile Organic Compounds (SVOC) are compounds which partition directly between the gas and aerosol phases under ambient conditions, and include compounds with saturation concentrations roughly between 0.1 and 104 μg m-3. The SVOC in engine exhaust are typically hydrocarbons in the C15-C35 range. They are largely uncharacterised, other than the n-alkanes, because they are unresolved by traditional gas chromatography and form a large hump in the chromatogram referred to as Unresolved Complex Mixture (UCM). In this study, samples were collected from the exhaust of a diesel engine with and without abatement devices fitted. Engine exhaust was diluted with air and collected using both filter and impaction (MOUDI), to resolve total mass and size resolved mass respectively. Particle size distribution was evaluated by sampling simultaneously with a Scanning Mobility Particle Sizer (SMPS). 2D Gas-Chromatography Time-of-Flight Mass-Spectrometry (GC×GC-ToF-MS) was exploited to characterise and quantify the composition of SVOC from the exhaust emission. The SVOC was observed to contain predominantly n-alkanes, alkyl-cyclohexanes and aromatics; similar to both fresh lubricating oil and fuel. Preliminary results indicate that the contribution of diesel fuel to the exhaust SVOC composition is dominant at high speeds, and a more pronounced contribution from lubricating oil is observed at low speeds. Differences were also observed in the SVOC composition when using different fuel types, engine lubricants, starting temperatures and collecting samples with and without abatement devices fitted. The wealth of compounds identified and quantified in the C15-C35 range included PAH, esters, carboxylic acids, alkanes, alkenes, alcohols and hopanes.

Assessing the depth of isoflurane anaesthesia during cardiopulmonary bypass.

PubMed

Ng, Ka Ting; Alston, R Peter; Just, George; McKenzie, Chris

2018-03-01

Bispectral index (BIS) and monitoring of end-tidal concentration may be associated with a reduction in the incidence of awareness during volatile-based general anaesthesia. An analogue of end-tidal concentration during cardiopulmonary bypass (CPB) is measuring exhausted isoflurane concentration from the oxygenator as an estimate to blood and, so, brain concentration. The aim of this study was to determine the relationships between oxygenator exhaust and blood concentrations of isoflurane and the BIS score during CPB when administering isoflurane into the sweep gas supply to the oxygenator. Seventeen patients undergoing elective cardiac surgery using CPB and isoflurane with BIS monitoring were recruited in a single-centre university hospital. Isoflurane gas was delivered via a calibrated vaporiser at the beginning of anaesthetic induction. Radial arterial blood samples were collected after the initiation of CPB and before aortic cross-clamping, which were analysed for isoflurane by gas chromatography and mass spectrometry. The BIS score and the concentration of exhausted isoflurane from the oxygenator membrane, as measured by an anaesthetic gas analyser, were recorded at the time of blood sampling. The mean duration of anaesthetic induction to arterial blood sampling was 90 min (95%CI: 80,100). On CPB, the median BIS was 39 (range, 7-43) and the mean oxygenator exhaust isoflurane concentration was 1.24 ± 0.21%. No significant correlation was demonstrated between BIS with arterial isoflurane concentration (r=-0.19, p=0.47) or oxygenator exhaust isoflurane concentration (r=0.07, p=0.80). Mixed-venous blood temperature was moderately correlated to BIS (r=0.50, p=0.04). Oxygenator exhaust isoflurane concentration was moderately, positively correlated with its arterial concentration (r=0.64, p<0.01). In conclusion, in patients undergoing heart surgery with CPB, the findings of this study indicate that, whilst oxygenator exhaust concentrations were significantly associated with arterial concentrations of isoflurane, neither had any association with the BIS scores, whereas body temperature has moderate positive correlation.

Are core self-evaluations a suitable moderator in stressor-detachment relationships? A study among managers' perceived job demands, detachment and strain reactions.

PubMed

Hentrich, Stephan; Zimber, Andreas; Sosnowsky-Waschek, Nadia; Gregersen, Sabine; Petermann, Franz

2018-01-01

The relationships among job demands, personality factors, recovery and psychological health receive increasing attention but are not well understoodOBJECTIVE:Therefore, the present study tests moderating effects among a sample of managers as proposed by the stressor-detachment model. We aimed to determine whether core self-evaluations (CSE) had an influence on the correlations between detachment and strain reactions (depressive symptoms, irritation, exhaustion) and between job demands and detachment. Further, we tested whether detachment attenuates the positive relation between job demands and strain reactions. A convenience sample of managers in three German settings (N = 282) participated in the cross-sectional study. Results based on hierarchical regression analysis showed that high CSE significantly weakened the negative relationship between detachment and depressive symptoms in this sample. However, CSE did not moderate the negative relationship between job demands and detachment. Moreover, results revealed that detachment moderated the positive relation between job demands and exhaustion. The authors tested whether CSE was able to moderate the relationship between job demands, psychological detachment and different stress reactions. Although we found a significant interaction effect, CSE may be too distal to moderate all respective associations.

Increased formaldehyde in jet engine exhaust with changes to JP-8, lower temperature, and lower humidity irritates eyes and respiratory tract.

PubMed

Kobayashi, A; Kikukawa, A

2000-04-01

Formaldehyde (FA) in exhaust from F-4 aircraft with low smoke combustor(LSC) J79 engines has been reported to be of sufficient concentration to cause irritation. It has also been noted that eye and respiratory irritation became more frequent and severe after the fuel was changed from JP-4 to JP-8. The present sturdy investigated the effect of jet fuel and power setting on formaldehyde concentrations in the exhaust. We also investigated the exposure to formaldehyde among pilots and flight line personnel. The exhaust from LSC J79 engines using different types of fuel (JP-8 and JP-4) was sampled 50 m behind the engine at different power settings in July (summer season in Japan) and February (winter season ). It was also sampled at 75% power settings using JP-8 in July. At an idle power setting, the FA concentration was higher in the exhaust of engines using JP-8 (1.31 ppm in July and 2.78 ppm in February) than in engines using JP-4 (0.95 ppm in July and 1.84 ppm in February). The FA concentration increased as both ambient temperature and relative humility decreased in the sampling atmosphere. The FA concentration of JP-8 fuel at an idle power setting (65%) was higher than that at a 71.5% power setting (1.32 ppm and 0.86 ppm, respectively). The FA concentrations in LSCJ79 engine exhaust varies depending on the type of fuel, engine power settings, and ambient air conditions. A high FA concentration at ground level due to a change in the fuel type, low temperature, and humidity, causes frequent severe eye respiratory irritation.

Decreasing carbon monoxide in the diving air of artisanal fishermen in the Yucatán peninsula by separation of engine exhaust from compressor intake.

PubMed

Chin, Walter; Huchim-Lara, Oswaldo; Salas, Silvia

2016-01-01

Artisanal fishermen in the Yucatán Peninsula utilize hookah dive systems (HDS). The air compressors in these HDS are not filtered, and the intake is near the engine exhaust. This proximity allows carbon monoxide (CO) from the exhaust to directly enter the HDS volume tank and contaminate the fishermen diver's air supply. Conservative safety standards permit a diver's air supply to contain 10 parts per million (ppm) of CO. This study quantified the levels of CO in the diver's air supply both before and after physical separation of the engine exhaust from the compressor intake. CO levels in seven volume tanks were analyzed before and after a 1-inch hose was attached to the compressor intake and elevated 5 feet above the engine exhaust. The tanks were drained and refilled before collecting each set of pre- and post-intervention gas samples. Four CO measurements were collected before and after the intervention from each volume tank. A C-Squared© CO Analyzer (± 1 ppm), calibrated with a Praxair 70 ppm CON2 gas (± 5%), was used to analyze the gas samples. A paired samples t-test shows a statistically significant difference in average CO values before and after the intervention (t = 6.8674, df: 27; p⟨0.0001). The physical separation of the engine exhaust from the compressor intake reduced the CO contamination of the diver air supply by 72%. This intervention could be applied to the hookah systems in the rest of the fishing cooperative to reduce the divers' risk of CO poisoning. Copyright© Undersea and Hyperbaric Medical Society.

Impact of Fire Resistant Fuel Blends on Compression Ignition Engine Performance

DTIC Science & Technology

2011-07-01

EFFECTS ON ENGINE PERFORMANCE FRF blends were tested in the CAT C7 and GEP 6.5L(T) engines to determine the effects of FRF on engine ...impact on efficiency of the Stanadyne rotary injection pump used in the GEP 6.5L(T) engine , thus largely effecting its power output when varying... exhaust backpressure .  Emissions are sampled from an exhaust probe installed between the engine and exhaust system butterfly valve. 

Assessment of analytical techniques for predicting solid propellant exhaust plumes and plume impingement environments

NASA Technical Reports Server (NTRS)

Tevepaugh, J. A.; Smith, S. D.; Penny, M. M.

1977-01-01

An analysis of experimental nozzle, exhaust plume, and exhaust plume impingement data is presented. The data were obtained for subscale solid propellant motors with propellant Al loadings of 2, 10 and 15% exhausting to simulated altitudes of 50,000, 100,000 and 112,000 ft. Analytical predictions were made using a fully coupled two-phase method of characteristics numerical solution and a technique for defining thermal and pressure environments experienced by bodies immersed in two-phase exhaust plumes.

A Flight Investigation of Exhaust-heat De-icing

NASA Technical Reports Server (NTRS)

Jones, Alun R; Rodert, Lewis A

1940-01-01

The National Advisory Committee for Aeronautics conducted exhaust-heat de-icing tests in flight to provide data needed in the application of this method. The capacity to extract heat from the exhaust gas for de-icing purposes, the quantity of heat required, and other factors were examined. The results indicate that a wing-heating system employing a spanwise exhaust tube within the leading edge of the wing removed 30 to 35 percent of the heat from exhaust gas entering the wing. Data are given from which the heat required for ice prevention can be calculated. Sample calculations have been made on the basis of existing engine power/wing area ratios to show that sufficient heating can be obtained for ice protection on modern transportation airplanes, provided that uniform distribution of the heat can be secured.

Display rule "regulators": the relationship between supervisors and worker emotional exhaustion.

PubMed

Wilk, Steffanie L; Moynihan, Lisa M

2005-09-01

This field study examined the effect of supervisory regulation of display rules--the rules about what kind of emotion to express on the job (R. Ekman, 1992; A. Rafaeli & R. I. Sutton, 1987)--on the emotional exhaustion of subordinates. On the basis of a sample of 940 call center employees, the authors found that worker emotional exhaustion varied across supervisors within jobs, suggesting that emotion work is influenced at the supervisory, rather than job, level. Moreover, the authors found that the importance supervisors place on interpersonal job demands of their workers was positively related to worker emotional exhaustion. Worker career identity moderated the interpersonal-job-demands--emotional-exhaustion relationship, but self-efficacy did not. Study conclusions and suggestions for future research are provided. Copyright 2005 APA, all rights reserved.

Burnout among Iranian school principals.

PubMed

Rashidzadeh, Mohammad Ali

2002-02-01

This study investigated burnout among Iranian school principals. Also, the relationships of sex, years of administration, age, and marital status were considered. The sample were 200 principals (100 men, 100 women) who completed the Friedman School Principal Burnout Scale. Analysis showed principals who completed the scale felt exhausted, aloof, and deprecated. The women scored lower. There were significant correlationships between marital status and years of administration with the scores on burnout.

40 CFR 86.1511 - Exhaust gas analysis system.

Code of Federal Regulations, 2014 CFR

2014-07-01

... (a)(1) of this section. Interference gas Concentration Applicable analyzer CO2 14 percent CO C3H8 1 percent CO H2O Saturated vapor at 100 °F CO NOX 1,000 ppm CO O2 5 percent CO (8) The analyzer shall be... humidity; and (iii) During variations of ±50 percent of nominal sample flow. (b) The inclusion of a raw CO2...

[Burnout syndrome and suicide risk among primary care nurses].

PubMed

Tomás-Sábado, Joaquín; Maynegre-Santaulària, Montserrat; Pérez-Bartolomé, Meritxell; Alsina-Rodríguez, Marta; Quinta-Barbero, Roser; Granell-Navas, Sergi

2010-01-01

To observe the prevalence of the burnout syndrome and the relationship with suicide risk, self-esteem, anxiety and depression, in a sample of primary care nurses. Observational, cross-sectional and correlational study. The sample consisted of 146 nursing professionals, 131 women and 15 men, with an average age of 44.02 years (SD=10.89). Participants responded to a questionnaire which included the Spanish forms of the Maslach burnout inventory (MBI), the Plutchik Suicide Risk Scale (SR), the Kuwait University Anxiety Scale (KUAS), the Self-Rating Depression Scale (SDS) and the Rosenberg Self-esteem Scale (RSES). In the inferential statistical analysis, Pearson's r coefficients and multiple linear regression were calculated. Significant correlations between suicidal risk and anxiety, depression, self-esteem, emotional exhaustion and personal performance, were obtained. In the multiple regression analysis, depression was the main predictor of suicidal risk, followed by anxiety and emotional exhaustion. The scores obtained in burnout and suicidal risk were, in general, lower than those observed in other studies, emphasising the high level observed in personal performance, which reflects reasonable professional satisfaction. The results show the important role of working atmosphere and early recognition of mental disorders in burnout and suicidal risk prevention. Copyright (c) 2009 Elsevier España, S.L. All rights reserved.

40 CFR 91.405 - Recorded information.

Code of Federal Regulations, 2014 CFR

2014-07-01

... addition to a pre- and post-test measurement. (4) Recorder chart or equivalent. Identify for each test... each mode, if applicable. (8) Exhaust sample line temperature, if applicable. (e) Test data; post-test...) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test Procedures § 91.405 Recorded...

40 CFR 91.405 - Recorded information.

Code of Federal Regulations, 2012 CFR

2012-07-01

... addition to a pre- and post-test measurement. (4) Recorder chart or equivalent. Identify for each test... each mode, if applicable. (8) Exhaust sample line temperature, if applicable. (e) Test data; post-test...) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test Procedures § 91.405 Recorded...

40 CFR 91.405 - Recorded information.

Code of Federal Regulations, 2011 CFR

2011-07-01

... addition to a pre- and post-test measurement. (4) Recorder chart or equivalent. Identify for each test... each mode, if applicable. (8) Exhaust sample line temperature, if applicable. (e) Test data; post-test...) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test Procedures § 91.405 Recorded...

40 CFR 91.405 - Recorded information.

Code of Federal Regulations, 2013 CFR

2013-07-01

... addition to a pre- and post-test measurement. (4) Recorder chart or equivalent. Identify for each test... each mode, if applicable. (8) Exhaust sample line temperature, if applicable. (e) Test data; post-test...) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test Procedures § 91.405 Recorded...

40 CFR 91.405 - Recorded information.

Code of Federal Regulations, 2010 CFR

2010-07-01

... addition to a pre- and post-test measurement. (4) Recorder chart or equivalent. Identify for each test... each mode, if applicable. (8) Exhaust sample line temperature, if applicable. (e) Test data; post-test...) CONTROL OF EMISSIONS FROM MARINE SPARK-IGNITION ENGINES Gaseous Exhaust Test Procedures § 91.405 Recorded...

Odor control in swine buildings: recycle flush vs. automated scraper

USDA-ARS?s Scientific Manuscript database

A research project was conducted to compare odor concentrations in exhaust of traditional flush barns and barns equipped with automated scrapers. The study was conducted at commercial tunnel-ventilated swine barns in northwest Missouri. Odor samples were collected from the barn exhaust in polyvinyl ...

14 CFR 34.82 - Sampling and analytical procedures for measuring smoke exhaust emissions.

Code of Federal Regulations, 2011 CFR

2011-01-01

..., DEPARTMENT OF TRANSPORTATION AIRCRAFT FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE ENGINE POWERED AIRPLANES Test Procedures for Engine Smoke Emissions (Aircraft Gas Turbine Engines) § 34.82..., Environmental Protection, Volume II, Aircraft Engine Emissions, Second Edition, July 1993, effective July 26...

14 CFR 34.82 - Sampling and analytical procedures for measuring smoke exhaust emissions.

Code of Federal Regulations, 2010 CFR

2010-01-01

..., DEPARTMENT OF TRANSPORTATION AIRCRAFT FUEL VENTING AND EXHAUST EMISSION REQUIREMENTS FOR TURBINE ENGINE POWERED AIRPLANES Test Procedures for Engine Smoke Emissions (Aircraft Gas Turbine Engines) § 34.82..., Environmental Protection, Volume II, Aircraft Engine Emissions, Second Edition, July 1993, effective July 26...

Airborne detection and quantification of swine influenza a virus in air samples collected inside, outside and downwind from swine barns.

PubMed

Corzo, Cesar A; Culhane, Marie; Dee, Scott; Morrison, Robert B; Torremorell, Montserrat

2013-01-01

Airborne transmission of influenza A virus (IAV) in swine is speculated to be an important route of virus dissemination, but data are scarce. This study attempted to detect and quantify airborne IAV by virus isolation and RRT-PCR in air samples collected under field conditions. This was accomplished by collecting air samples from four acutely infected pig farms and locating air samplers inside the barns, at the external exhaust fans and downwind from the farms at distances up to 2.1 km. IAV was detected in air samples collected in 3 out of 4 farms included in the study. Isolation of IAV was possible from air samples collected inside the barn at two of the farms and in one farm from the exhausted air. Between 13% and 100% of samples collected inside the barns tested RRT-PCR positive with an average viral load of 3.20E+05 IAV RNA copies/m³ of air. Percentage of exhaust positive air samples also ranged between 13% and 100% with an average viral load of 1.79E+04 RNA copies/m³ of air. Influenza virus RNA was detected in air samples collected between 1.5 and 2.1 Km away from the farms with viral levels significantly lower at 4.65E+03 RNA copies/m³. H1N1, H1N2 and H3N2 subtypes were detected in the air samples and the hemagglutinin gene sequences identified in the swine samples matched those in aerosols providing evidence that the viruses detected in the aerosols originated from the pigs in the farms under study. Overall our results indicate that pigs can be a source of IAV infectious aerosols and that these aerosols can be exhausted from pig barns and be transported downwind. The results from this study provide evidence of the risk of aerosol transmission in pigs under field conditions.

Airborne Detection and Quantification of Swine Influenza A Virus in Air Samples Collected Inside, Outside and Downwind from Swine Barns

PubMed Central

Corzo, Cesar A.; Culhane, Marie; Dee, Scott; Morrison, Robert B.; Torremorell, Montserrat

2013-01-01

Airborne transmission of influenza A virus (IAV) in swine is speculated to be an important route of virus dissemination, but data are scarce. This study attempted to detect and quantify airborne IAV by virus isolation and RRT-PCR in air samples collected under field conditions. This was accomplished by collecting air samples from four acutely infected pig farms and locating air samplers inside the barns, at the external exhaust fans and downwind from the farms at distances up to 2.1 km. IAV was detected in air samples collected in 3 out of 4 farms included in the study. Isolation of IAV was possible from air samples collected inside the barn at two of the farms and in one farm from the exhausted air. Between 13% and 100% of samples collected inside the barns tested RRT-PCR positive with an average viral load of 3.20E+05 IAV RNA copies/m3 of air. Percentage of exhaust positive air samples also ranged between 13% and 100% with an average viral load of 1.79E+04 RNA copies/m3 of air. Influenza virus RNA was detected in air samples collected between 1.5 and 2.1 Km away from the farms with viral levels significantly lower at 4.65E+03 RNA copies/m3. H1N1, H1N2 and H3N2 subtypes were detected in the air samples and the hemagglutinin gene sequences identified in the swine samples matched those in aerosols providing evidence that the viruses detected in the aerosols originated from the pigs in the farms under study. Overall our results indicate that pigs can be a source of IAV infectious aerosols and that these aerosols can be exhausted from pig barns and be transported downwind. The results from this study provide evidence of the risk of aerosol transmission in pigs under field conditions. PMID:23951164

Engine performance and exhaust emission analysis of a single cylinder diesel engine fuelled with water-diesel emulsion fuel blended with manganese metal additives

NASA Astrophysics Data System (ADS)

Muhsin Ithnin, Ahmad; Jazair Yahya, Wira; Baun Fletcher, Jasmine; Kadir, Hasannuddin Abd

2017-10-01

Water-in-diesel emulsion fuel (W/D) is one of the alternative fuels that capable to reduce the exhaust emission of diesel engine significantly especially the nitrogen oxides (NOx) and particulate matter (PM). However, the usage of W/D emulsion fuels contributed to higher CO emissions. Supplementing metal additive into the fuel is the alternate way to reduce the CO emissions and improve performance. The present paper investigates the effect of using W/D blended with organic based manganese metal additives on the diesel engine performance and exhaust emission. The test were carried out by preparing and analysing the results observed from five different tested fuel which were D2, emulsion fuel (E10: 89% D2, 10% - water, 1% - surfactant), E10Mn100, E10Mn150, E10Mn200. Organic based Manganese (100ppm, 150ppm, 200ppm) used as the additive in the three samples of the experiments. E10Mn200 achieved the maximum reduction of BSFC up to 13.66% and has the highest exhaust gas temperature. Whereas, E10Mn150 achieved the highest reduction of CO by 14.67%, and slightly increased of NOx emissions as compared to other emulsion fuels. Organic based manganese which act as catalyst promotes improvement of the emulsion fuel performance and reduced the harmful emissions discharged.

Argon/UF6 plasma exhaust gas reconstitution experiments using preheated fluorine and on-line diagnostics. [fissioning uranium plasma core reactor design

NASA Technical Reports Server (NTRS)

Roman, W. C.

1979-01-01

The feasibility of employing a flowing, high-temperature, pure fluorine/UF6 regeneration system to efficiently convert a large fraction of the effluent plasma exhaust back to pure UF6 was demonstrated. The custom built T.O.F. mass spectrometer sampling system permitted on-line measurements of the UF6 concentration at different locations in the exhaust system. Negligible amounts ( 100 ppm) of UF6 were detected in the axial bypass exhaust duct and the exhaust ducts downstream of the cryogenic trap system used to collect the UF6, thus verifying the overall system efficiency over a range of operating conditions. Use of a porous Monel duct as part of the exhaust duct system, including provision for injection of pure fluorine, provided a viable technique to eliminate uranium compound residue on the inside surface of the exhaust ducts. Typical uranium compound mass deposition per unit area of duct was 2 micron g/sq cm. This porous duct technique is directly applicable to future uranium compound transfer exhaust systems. Throughout these experiments, additional basic data on the corrosion aspects of hot, pressurized UF6/fluorine were also accumulated.

The effects of age and drug dependency on the emotional exhaustion and job satisfaction of adult streetworkers in australia.

PubMed

Cregan, Christina; Kulik, Carol T; Salinger, Dani

2013-07-01

This multi-method study investigated a sample of adult streetworkers (n = 107) in Melbourne, Australia in 2008. We contacted outdoor prostitutes through four "drop-in" centers run by not-for-profit organizations. Drug use was the over-riding common characteristic of most of these streetworkers. Using emotional labor theory as a theoretical framework, we hypothesized that individuals who worked on the streets solely to earn money to buy drugs would experience the highest levels of emotional exhaustion and the lowest levels of job satisfaction. We predicted these effects would be most evident for older drug dependent streetworkers. Content analysis of open-ended interview responses identified acting, age, and drug dependency as key themes. Moderator hierarchical regression analysis of responses to closed-ended questions with tests for mediation supported the hypotheses. It also demonstrated that older drug dependent streetworkers felt most trapped in their occupation and this sense of being locked-in was associated with emotional exhaustion but not with job satisfaction. The evidence that age and drug dependency affects the psychological outcomes associated with streetwork suggests that the efforts of police and the courts will be ineffective in dealing with people whose addiction traps them in an occupation that offers few intrinsic rewards. Decriminalization would encourage police to protect streetworkers from violence. Agencies could seek financial support to provide welfare and exit strategies.

Flow prediction for propfan engine installation effects on transport aircraft at transonic speeds

NASA Technical Reports Server (NTRS)

Samant, S. S.; Yu, N. J.

1986-01-01

An Euler-based method for aerodynamic analysis of turboprop transport aircraft at transonic speeds has been developed. In this method, inviscid Euler equations are solved over surface-fitted grids constructed about aircraft configurations. Propeller effects are simulated by specifying sources of momentum and energy on an actuator disc located in place of the propeller. A stripwise boundary layer procedure is included to account for the viscous effects. A preliminary version of an approach to embed the exhaust plume within the global Euler solution has also been developed for more accurate treatment of the exhaust flow. The resulting system of programs is capable of handling wing-body-nacelle-propeller configurations. The propeller disks may be tractors or pushers and may represent single or counterrotation propellers. Results from analyses of three test cases of interest (a wing alone, a wing-body-nacelle model, and a wing-nacelle-endplate model) are presented. A user's manual for executing the system of computer programs with formats of various input files, sample job decks, and sample input files is provided in appendices.

QCGAT mixer compound exhaust system design and static big model test report

NASA Technical Reports Server (NTRS)

Blackmore, W. L.; Thompson, C. E.

1978-01-01

A mixer exhaust system was designed to meet the proposed performance and exhaust jet noise goals for the AiResearch QCGAT engine. Some 0.35 scale models of the various nozzles were fabricated and aerodynamically and acoustically tested. Preliminary optimization, engine cycle matching, model test data and analysis are presented. A final mixer exhaust system is selected for optimum performance for the overall flight regime.

The Glass Half Empty: How Emotional Exhaustion Affects the State-Trait Discrepancy in Self-Reports of Teaching Emotions

PubMed Central

Goetz, Thomas; Becker, Eva S.; Bieg, Madeleine; Keller, Melanie M.; Frenzel, Anne C.; Hall, Nathan C.

2015-01-01

Following from previous research on intensity bias and the accessibility model of emotional self-report, the present study examined the role of emotional exhaustion in explaining the discrepancy in teachers’ reports of their trait (habitual) versus state (momentary, “real”) emotions. Trait reports (habitual emotions, exhaustion) were assessed via trait questionnaires, and state reports (momentary emotions) were assessed in real time via the experience sampling method by using personal digital assistants (N = 69 high school teachers; 1,089 measures within teachers). In line with our assumptions, multi-level analyses showed that, as compared to the state assessment, teachers reported higher levels of habitual teaching-related emotions of anger, anxiety, shame, boredom, enjoyment, and pride. Additionally, the state-trait discrepancy in self-reports of negative emotions was accounted for by teachers’ emotional exhaustion, with high exhaustion levels corresponding with a greater state-trait discrepancy. Exhaustion levels did not moderate the state-trait discrepancy in positive emotions indicating that perceived emotional exhaustion may reflect identity-related cognitions specific to the negative belief system. Implications for research and educational practice are discussed. PMID:26368911

The Glass Half Empty: How Emotional Exhaustion Affects the State-Trait Discrepancy in Self-Reports of Teaching Emotions.

PubMed

Goetz, Thomas; Becker, Eva S; Bieg, Madeleine; Keller, Melanie M; Frenzel, Anne C; Hall, Nathan C

2015-01-01

Following from previous research on intensity bias and the accessibility model of emotional self-report, the present study examined the role of emotional exhaustion in explaining the discrepancy in teachers' reports of their trait (habitual) versus state (momentary, "real") emotions. Trait reports (habitual emotions, exhaustion) were assessed via trait questionnaires, and state reports (momentary emotions) were assessed in real time via the experience sampling method by using personal digital assistants (N = 69 high school teachers; 1,089 measures within teachers). In line with our assumptions, multi-level analyses showed that, as compared to the state assessment, teachers reported higher levels of habitual teaching-related emotions of anger, anxiety, shame, boredom, enjoyment, and pride. Additionally, the state-trait discrepancy in self-reports of negative emotions was accounted for by teachers' emotional exhaustion, with high exhaustion levels corresponding with a greater state-trait discrepancy. Exhaustion levels did not moderate the state-trait discrepancy in positive emotions indicating that perceived emotional exhaustion may reflect identity-related cognitions specific to the negative belief system. Implications for research and educational practice are discussed.

The downside of goal-focused leadership: the role of personality in subordinate exhaustion.

PubMed

Perry, Sara Jansen; Witt, L A; Penney, Lisa M; Atwater, Leanne

2010-11-01

Exhaustion has a significant impact on employees and organizations, and leader behavior may affect it. We applied conservation of resources theory to test propositions regarding the joint effects of goal-focused leadership (GFL) and personality on employee exhaustion. We proposed that the relationship between GFL and exhaustion depends on employees' standing on both conscientiousness and emotional stability. Specifically, we expected that high-conscientiousness subordinates experience greater compatibility with a goal-focused leader because of their predisposition to direct resources toward achievement and goal setting, resulting in lower exhaustion under such a leader than among low-conscientiousness employees. Furthermore, high emotional stability may compensate for GFL incompatibility among low-conscientiousness employees by providing additional resources to manage GFL. In contrast, employees low on both traits likely experience greater exhaustion under a goal-focused leader compared with other employees. Results revealed a 3-way interaction in 2 independent samples and were generally supportive of our predictions. GFL was associated with heightened exhaustion among individuals in the low-emotional-stability, low-conscientiousness group but not among workers having any other trait combination. (c) 2010 APA, all rights reserved.

40 CFR 205.171-2 - Test exhaust system sample selection and preparation.

Code of Federal Regulations, 2010 CFR

2010-07-01

... be used for testing of exhaust systems must be of the subject class which has been assembled using...'s prescribed manufacturing and inspection procedures, and are documented in the manufacturer's... other motorcycles of that class which will be distributed in commerce, unless such procedures are...

40 CFR 89.401 - Scope; applicability.

Code of Federal Regulations, 2010 CFR

2010-07-01

... subpart B of this part. (b) Exhaust gases, either raw or dilute, are sampled while the test engine is operated using the appropriate test cycle on an engine dynamometer. The exhaust gases receive specific... the power output during each mode. Emissions are reported as grams per kilowatt hour (g/kW-hr). (c...

Chemical fractionation and mobility of traffic-related elements in road environments.

PubMed

Adamiec, Ewa

2017-12-01

Due to considerable progress in exhaust control emission technology and extensive regulatory work regarding this issue, non-exhaust sources of air pollution have become a growing concern. This research involved studying three types of road environment samples such as road dust, sludge from storm drains and roadside soil collected from heavily congested and polluted cities in Poland (Krakow, Warszawa, Opole and Wroclaw). Particles below 20 µm were examined since it was previously estimated that this fine fraction of road dust is polluted mostly by metals derived from non-exhaust sources of pollution such as brake linings wear. Chemical analysis of all samples was combined with a fractionation study using BCR protocol. It was concluded that the finest fractions of road environment samples were significantly contaminated with all of the investigated metals, in particular with Zn, Cu, both well-known key tracers of brake and tire wear. In Warszawa, the pollution index for Zn was on average 15-18 times the background value, in Krakow 12 times, in Wroclaw 8-12 times and in Opole 6-9 times the background value. The pollution index for Cu was on average 6-14 times the background in Warszawa, 7-8 times in Krakow, 4-6 times in Wroclaw and in Opole 5 times the background value. Fractionation study revealed that mobility of examined metals decreases in that order: Zn (43-62%) > Cd (25-42%) > Ni (6-16%) > Cu (3-14%) > Pb (1-8%). It should, however, be noted that metals even when not mobile in the environment can become a serious health concern when ingested or inhaled.

Spatial Patterns and Risk Assessment of Heavy Metals in Soils in a Resource-Exhausted City, Northeast China

PubMed Central

Chen, Hongwei; An, Jing; Wei, Shuhe; Gu, Jian

2015-01-01

Northeast China is an intensive area of resource-exhausted city, which is facing the challenges of industry conversion and sustainable development. In order to evaluate the soil environmental quality influenced by mining activities over decades, the concentration and spatial distribution of arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), and Zinc (Zn) in surface soils (0-20cm) of a typical resource-exhausted city were investigated by analyzing 306 soil samples. The results showed that the average concentrations in the samples were 6.17 mg/kg for As, 0.19 mg/kg for Cd, 51.08 mg/kg for Cr, 23.27 mg/kg for Cu, 31.15 mg/kg for Ni, 22.17 mg/kg for Pb, and 54.21 mg/kg for Zn. Metals distribution maps produced by using the inverse distance weighted interpolation method and results revealed that all investigated metals showed distinct geographical patterns, and the concentrations were higher in urban and industrial areas than in farmland. Pearson correlation and principal component analysis showed that there were significant positive correlations (p<0.05) between all of the metals, and As, Cd, Cr, Mn, Ni, Pb, and Zn were closely associated with the first principal component (PC1), which explained 39.81% of the total variance. Cu and As were mainly associated with the second component (PC2). Based on the calculated Nemerow pollution index, percentage for slightly polluted (1

Aircraft Particle Emissions eXperiment (APEX)

NASA Technical Reports Server (NTRS)

Wey, C. C.; Anderson, B. E.; Hudgins, C.; Wey, C.; Li-Jones, X.; Winstead, E.; Thornhill, L. K.; Lobo, P.; Hagen, D.; Whitefield, P.

2006-01-01

APEX systematically investigated the gas-phase and particle emissions from a CFM56-2C1 engine on NASA's DC-8 aircraft as functions of engine power, fuel composition, and exhaust plumage. Emissions parameters were measured at 11 engine power, settings, ranging from idle to maximum thrust, in samples collected at 1, 10, and 30 m downstream of the exhaust plane as the aircraft burned three fuels to stress relevant chemistry. Gas-phase emission indices measured at 1 m were in good agreement with the ICAO data and predictions provided by GEAE empirical modeling tools. Soot particles emitted by the engine exhibited a log-normal size distribution peaked between 15 and 40 nm, depending on engine power. Samples collected 30 m downstream of the engine exhaust plane exhibited a prominent nucleation mode.

Mapping and quantifying isomer sets of hydrocarbons (≥ C12) in diesel exhaust, lubricating oil and diesel fuel samples using GC × GC-ToF-MS

NASA Astrophysics Data System (ADS)

Alam, Mohammed S.; Zeraati-Rezaei, Soheil; Liang, Zhirong; Stark, Christopher; Xu, Hongming; MacKenzie, A. Rob; Harrison, Roy M.

2018-05-01

Airborne particles and vapours, like many other environmental samples including water, soils and sediments, contain complex mixtures of hydrocarbons, often deriving from crude oil either before or after fractionation into fuels, lubricants and feedstocks. Comprehensive 2D gas chromatography time-of-flight mass spectrometry (GC × GC-ToF-MS), offers a very powerful technique that separates and identifies many compounds in complicated hydrocarbon mixtures. However, quantification and identification of individual constituents at high ionization energies would require hundreds of expensive (when available) standards for calibration. Although the precise chemical structure of hydrocarbons does matter for their environmental impact and fate, strong similarities can be expected for compounds having very similar chemical structures and carbon numbers. There is, therefore, a clear benefit in an analytical technique which is specific enough to separate different classes of compounds and to distinguish homologous series while avoiding the need to handle each isomer individually. Varying EI (electron impact) ionization mass spectrometry significantly enhances the identification of individual isomers and homologous compound groups, which we refer to as isomer sets. Advances are reported in mapping and quantifying isomer sets of hydrocarbons (≥ C12) in diesel fuel, lubricating oil and diesel exhaust emissions. By using this analysis we report mass closures of ca. 90 and 75 % for diesel fuel and lubricating oil, and identify 85 and 75 % of the total ion current for gas- and particulate-phase diesel exhaust emissions.

Ice nuclei from automobile exhaust and iodine vapor.

PubMed

Schaefer, V J

1966-12-23

When exposed to a trace of iodine vapor, the submicroscopic particles of lead exhausted by automobiles produce nuclei for the formation of ice crystals. Concentrations of particles exceeding 10(6) per liter can be directly sampled from the exhaust pipe of an idling motor. Concentrations of from 10(4) to 10(5) per liter have been found in rural air downwind of auto roads; the concentration at one rural site has increased by an order of magnitude in 13 years. The phenomenon may provide a method of modifying clouds, and of determining ( and monitoring) the percentage of automobile exhaust in a polluted atmosphere. It may be an important factor in inadvertent modification by man of the climate.

Particle-bound benzene from diesel engine exhaust.

PubMed

Muzyka, V; Veimer, S; Shmidt, N

1998-12-01

The large surface area of the carbon core of diesel exhaust particles may contribute to the adsorption or condensation of such volatile carcinogenic organic compounds as benzene. The attention of this study focused on determining the distribution of benzene between the gas and particulate phases in the breathing zone of bus garage workers. Benzene and suspended particulate matter were evaluated jointly in the air of a municipal bus garage. Personal passive monitors were used for benzene sampling in the breathing zone of the workers. Active samplers were used for sampling diesel exhaust particles and the benzene associated with them. The benzene levels were measured by gas chromatography. Diesel engine exhaust from buses was the main source of air pollution caused by benzene and particles in this study. The concentration of benzene in the gas and particulate phases showed a wide range of variation, depending on the distance of the workplace from the operating diesel engine. Benzene present in the breathing zone of the workers was distributed between the gas and particulate phases. The amounts of benzene associated with particles were significantly lower in summer than in winter. The particulate matter of diesel exhaust contains benzene in amounts comparable to the concentrations of carcinogenic polycyclic aromatic hydrocarbons (PAH) and the usually found nitro-PAH. The concentration of benzene in the gas phase and in the suspended particulate matter of air can serve as an additional indicator of exposure to diesel exhaust and its carcinogenicity.

[Pollution Characteristics of Aldehydes and Ketones Compounds in the Exhaust of Beijing Typical Restaurants].

PubMed

Cheng, Jing-chen; Cui, Tong; He, Wan-qing; Nie, Lei; Wang, Jun-ling; Pan, Tao

2015-08-01

Aldehydes and ketones compounds, as one of the components in the exhaust of restaurants, are a class of volatile organic compounds (VOCs) with strong chemical reactivity. However, there is no systematic study on aldehydes and ketones compounds in the exhaust of restaurants. To further clarify the food source emission levels of aldehydes and ketones compounds and controlling measures, to access city group catering VOCs emissions control decision-making basis, this study selected 8 Beijing restaurants with different types. The aldehydes and ketones compounds were sampled using DNPH-silica tube, and then ultra performance liquid chromatography was used for quantitative measurement. The aldehydes and ketones concentrations of reference volume condition from 8 restaurants in descending order were Roasted Duck restaurant, Chinese Style Barbecue, Home Dishes, Western Fast-food, School Canteen, Chinese Style Fast-food, Sichuan Cuisine, Huaiyang Cuisine. The results showed that the range of aldehydes and ketones compounds (C1-C9) concentrations of reference volume condition in the exhaust of restaurants was 115.47-1035.99 microg x m(-3). The composition of aldehydes and ketones compounds in the exhaust of sampled restaurants was obviously different. The percentages of C1-C3 were above 40% in the exhaust from Chinese style restaurants. Fast food might emit more C4-C9 aldehydes and ketones compounds. From the current situation of existing aldehydes and ketones compounds control, the removal efficiency of high voltage electrostatic purifiers widely used in Beijing is limited.

Emotional exhaustion and medication administration work-arounds: the moderating role of nurse satisfaction with medication administration.

PubMed

Halbesleben, Jonathon R B; Rathert, Cheryl; Williams, Eric S

2013-01-01

Burnout is very common and has significant negative outcomes for both nurses and patients. However, this literature has only recently begun to address the processes that explain why health care provider burnout leads to negative patient outcomes. This article extends that literature by examining how satisfaction with work processes impacts the link between nurse burnout and work-arounds. The purpose of this study was to examine the relationships between emotional exhaustion and potentially unsafe work practices (work-arounds) in the context of nursing administration of medication. The data were collected using online survey software and pencil-and-paper surveys returned directly to the researchers. The study was conducted among nurses in 2 acute care hospitals in the Midwestern United States. For one of the samples, data on work-arounds were provided by the nurses' supervisors. For the other sample, data were collected at a 6-month interval. The survey included measures of emotional exhaustion (the Maslach Burnout Inventory), work-arounds, and nurse satisfaction with medication administration processes. We found that exhaustion was associated with greater use of work-arounds of medication administration processes. We also found that when nurses were more satisfied with the medication administration process, exhausted nurses were less likely to engage in work-arounds. The findings suggest that although exhaustion in nurses can lead to potentially unsafe practices, satisfaction with the work process can either exacerbate or reduce the problem.

Characterization and analysis of diesel exhaust odor

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shala, F.J.

1983-01-01

An instrumental method known as the Diesel Odor Analysis System or DOAS, has been developed at A.D. Little, Inc. for measuring diesel exhaust odor. It was of interest to determine which compound or compounds in the oxygenated fraction of the exhaust were primarily responsible for the odor correlation as developed at A.D. Little, Inc. This was accomplished by observing how the measurement of the exhaust odor intensity and number of chemical constituents of the oxygenate fraction were changing with respect to the odor values as measured by the DOAS. Benzaldehyde was found to give the best correlation (R = 0.98)more » with odor. A quantitative relationship between exhaust odor as measured by the total intensity of aroma (TIA) and the benzaldehyde concentration (B) in ppm in the exhaust is given by: TIA = 1.11 log/sub 10/(B) + 4.10. This correlation was supported by results obtained from two other diesel engine exhaust sources. A methyl benzaldehyde isomer also yielded a good correlation (R = 0.90) with odor. Air to fuel ratio correlations were determined for the tentatively identified compounds, cinnamaldehyde (R = 0.94) and a C2-benzaldehyde isomer (R = 0.94).« less

40 CFR 86.1823-08 - Durability demonstration procedures for exhaust emissions.

Code of Federal Regulations, 2014 CFR

2014-07-01

... judgement, a catalyst aging bench that follows the SBC and delivers the appropriate exhaust flow, exhaust... set must consist of randomly procured vehicles from actual customer use. The vehicles selected for... submit an analysis which evaluates whether the durability objective will be achieved for the vehicle...

Unemployment Benefit Exhaustion: Incentive Effects on Job-Finding Rates

ERIC Educational Resources Information Center

Filges, Trine; Geerdsen, Lars Pico; Knudsen, Anne-Sofie Due; Jørgensen, Anne-Marie Klint

2015-01-01

Purpose: This systematic review studied the impact of exhaustion of unemployment benefits on the exit rate out of unemployment and into employment prior to benefit exhaustion or shortly thereafter. Method: We followed Campbell Collaboration guidelines to prepare this review, and ultimately located 12 studies for final analysis and interpretation.…

A STUDY OF EXTRACTIVE AND REMOTE-SENSING SAMPLING AND MEASUREMENT OF EMISSIONS FROM MILITARY AIRCRAFT ENGINES

DOE Office of Scientific and Technical Information (OSTI.GOV)

Cheng, Mengdawn; Corporan, E.

2010-01-01

Aircraft emissions contribute to the increased atmospheric burden of particulate matter (e.g., black carbon and secondary organic compounds) that plays a role in air quality, contrail formation and climate change. Sampling and measurement of modern aircraft emissions at the engine exhaust plane (EEP) for to engine and fuel certification remains a daunting task, no agency-certified method is available for the task. In this paper we summarize the results of a recent study that was devoted to investigate both extractive and optical remote-sensing (ORS) technologies in sampling and measurement of gaseous and particulate matter (PM) emitted by a number of militarymore » aircraft engines operated with JP-8 and a Fischer-Tropsch (FT) fuel at various engine conditions. These engines include cargo, bomber, and helicopter types of military aircraft that consumes 70-80% of the military aviation fuel each year. The emission indices of selected pollutants are discussed as these data may be of interest for atmospheric modeling and for design of air quality control strategies around the airports and military bases. It was found that non-volatile particles in the engine emissions were all in the ultrafine range. The mean diameter of particles increased as the engine power increased; the mode diameters were in the 20nm range for the low power condition of a new helicopter engine to 80nm for the high power condition of a newly maintained bomber engine. Elemental analysis indicated little metals were present on particles in the exhaust, while most of the materials on the exhaust particles were based on carbon and sulfate. Carbon monoxide, carbon dioxide, nitrogen oxide, sulfur dioxide, formaldehyde, ethylene, acetylene, propylene, and alkanes were detected using both technologies. The last five species (in the air toxics category) were most noticeable only under the low engine power. The emission indices calculated based on the ORS data were however observed to differ significantly (up to 90%) from (typically lower than) those based on the extractive techniques. However, the ORS techniques were useful in providing non-intrusive real-time measurements of gaseous species in the exhaust plume, which warrants further development. The results obtained in this program validate sampling methodology and measurement techniques used for non-volatile PM aircraft emissions as described in the SAE AIR-6037.« less

Analyses of turbulent flow fields and aerosol dynamics of diesel engine exhaust inside two dilution sampling tunnels using the CTAG model.

PubMed

Wang, Yan Jason; Yang, Bo; Lipsky, Eric M; Robinson, Allen L; Zhang, K Max

2013-01-15

Experimental results from laboratory emission testing have indicated that particulate emission measurements are sensitive to the dilution process of exhaust using fabricated dilution systems. In this paper, we first categorize the dilution parameters into two groups: (1) aerodynamics (e.g., mixing types, mixing enhancers, dilution ratios, residence time); and (2) mixture properties (e.g., temperature, relative humidity, particle size distributions of both raw exhaust and dilution gas). Then we employ the Comprehensive Turbulent Aerosol Dynamics and Gas Chemistry (CTAG) model to investigate the effects of those parameters on a set of particulate emission measurements comparing two dilution tunnels, i.e., a T-mixing lab dilution tunnel and a portable field dilution tunnel with a type of coaxial mixing. The turbulent flow fields and aerosol dynamics of particles are simulated inside two dilution tunnels. Particle size distributions under various dilution conditions predicted by CTAG are evaluated against the experimental data. It is found that in the area adjacent to the injection of exhaust, turbulence plays a crucial role in mixing the exhaust with the dilution air, and the strength of nucleation dominates the level of particle number concentrations. Further downstream, nucleation terminates and the growth of particles by condensation and coagulation continues. Sensitivity studies reveal that a potential unifying parameter for aerodynamics, i.e., the dilution rate of exhaust, plays an important role in new particle formation. The T-mixing lab tunnel tends to favor the nucleation due to a larger dilution rate of the exhaust than the coaxial mixing field tunnel. Our study indicates that numerical simulation tools can be potentially utilized to develop strategies to reduce the uncertainties associated with dilution samplings of emission sources.

Effect of Operating and Sampling Conditions on the Exhaust Gas Composition of Small-Scale Power Generators

PubMed Central

Smits, Marianne; Vanpachtenbeke, Floris; Horemans, Benjamin; De Wael, Karolien; Hauchecorne, Birger; Van Langenhove, Herman; Demeestere, Kristof; Lenaerts, Silvia

2012-01-01

Small stationary diesel engines, like in generator sets, have limited emission control measures and are therefore responsible for 44% of the particulate matter (PM) emissions in the United States. The diesel exhaust composition depends on operating conditions of the combustion engine. Furthermore, the measurements are influenced by the used sampling method. This study examines the effect of engine loading and exhaust gas dilution on the composition of small-scale power generators. These generators are used in different operating conditions than road-transport vehicles, resulting in different emission characteristics. Experimental data were obtained for gaseous volatile organic compounds (VOC) and PM mass concentration, elemental composition and nitrate content. The exhaust composition depends on load condition because of its effect on fuel consumption, engine wear and combustion temperature. Higher load conditions result in lower PM concentration and sharper edged particles with larger aerodynamic diameters. A positive correlation with load condition was found for K, Ca, Sr, Mn, Cu, Zn and Pb adsorbed on PM, elements that originate from lubricating oil or engine corrosion. The nitrate concentration decreases at higher load conditions, due to enhanced nitrate dissociation to gaseous NO at higher engine temperatures. Dilution on the other hand decreases PM and nitrate concentration and increases gaseous VOC and adsorbed metal content. In conclusion, these data show that operating and sampling conditions have a major effect on the exhaust gas composition of small-scale diesel generators. Therefore, care must be taken when designing new experiments or comparing literature results. PMID:22442670

Exposures to quartz, diesel, dust, and welding fumes during heavy and highway construction.

PubMed

Woskie, Susan R; Kalil, Andrew; Bello, Dhimiter; Virji, M Abbas

2002-01-01

Personal samples for exposure to dust, diesel exhaust, quartz, and welding fume were collected on heavy and highway construction workers. The respirable, thoracic, and inhalable fractions of dust and quartz exposures were estimated from 260 personal impactor samples. Respirable quartz exposures exceeded the National Institute for Occupational Safety and Health (NIOSH) recommended exposure limit (REL) in 7-31% of cases for the trades sampled. More than 50% of the samples in the installation of drop ceilings and wall tiles and concrete finish operations exceeded the NIOSH REL for quartz. Thoracic exposures to quartz and dust exceeded respirable exposures by a factor of 4.5 and 2.8, respectively. Inhalable exposures to quartz and dust exceeded respirable exposures by a factor of 25.6 and 9.3, respectively. These findings are important due to the identification of quartz as a carcinogen by the National Toxicology Program and the International Agency for Research on Cancer. Fourteen percent of the personal samples for EC (n = 261), collected as a marker for diesel exhaust, exceeded the American Conference of Governmental Industrial Hygienists (ACGIH) threshold limit value (TLV) for diesel exhaust. Seventeen of the 22 (77%) samples taken during a partially enclosed welding operation reached or exceeded the ACGIH TLV of 5 mg/m3 for welding fume.

Prevalence of burnout in paediatric nurses: A systematic review and meta-analysis.

PubMed

Pradas-Hernández, Laura; Ariza, Tania; Gómez-Urquiza, José Luis; Albendín-García, Luis; De la Fuente, Emilia I; Cañadas-De la Fuente, Guillermo A

2018-01-01

Although burnout in paediatric nurses has been addressed in previous research, the heterogeneous nature of the results obtained and of the variables studied highlights the need for a detailed analysis of the literature. The aim of this study was to analyse the literature on burnout characteristics, reported prevalence, severity and risk factors, to achieve a better understanding of the risk of emotional exhaustion, depersonalisation and feelings of low personal accomplishment. For this purpose, we carried out a systematic review and meta-analysis of the literature. The databases consulted were CINAHL, LILACS, PubMed, the Proquest Platform (Proquest Health & Medical Complete), Scielo and Scopus. This study used the search equation "burnout AND "pediatric nurs*", and was conducted in July 2017. The search produced 34 studies targeting burnout in paediatric nurses, with no restrictions on the date of publication. Many of these studies detected moderate-high values for the three dimensions of burnout, and highlighted sociodemographic, psychological and job-related variables associated with this syndrome. The sample population for the meta-analysis was composed of 1600 paediatric nurses. The following prevalence values were obtained: (i) emotional exhaustion, 31% (95% CI: 25-37%); (ii) depersonalisation, 21% (95% CI: 11-33%); (iii) low personal accomplishment, 39% (95% CI: 28-50%). A significant number of paediatric nurses were found to have moderate-high levels of emotional exhaustion and depersonalisation, and low levels of personal accomplishment. These nurses, therefore, were either experiencing burnout or at high risk of suffering it in the future. These results support the need for further study of the risk factors for burnout in paediatric nurses. They also highlight the importance of developing interventions or therapies to help prevent or attenuate the above symptoms, thus helping nurses cope with the workplace environment and with situations that may lead to burnout.

Applications of derivatization reactions to trace organic compounds during sample preparation based on pressurized liquid extraction.

PubMed

Carro, Antonia M; González, Paula; Lorenzo, Rosa A

2013-06-28

Pressurized liquid extraction (PLE) is an exhaustive technique used for the extraction of analytes from solid samples. Temperature, pressure, solvent type and volume, and the addition of other reagents notably influence the efficiency of the extraction. The analytical applications of this technique can be improved by coupling with appropriate derivatization reactions. The aim of this review is to discuss the recent applications of the sequential combination of PLE with derivatization and the approaches that involve simultaneous extraction and in situ derivatization. The potential of the latest developments to the trace analysis of environmental, food and biological samples is also analyzed. Copyright © 2013 Elsevier B.V. All rights reserved.

Photoacoustic spectroscopy-based analysis of gas samples in a bus station

NASA Astrophysics Data System (ADS)

Sthel, M. S.; Schramm, D. U.; Faria, R. T., Jr.; Castro, M. P. P.; Carneiro, L. O.; Ribeiro, W. S.; Vargas, H.

2005-06-01

In Campos dos Goytacazes is a city located in the Northern region of Rio de Janeiro State, Brazil, the main source of air pollution are exhaust from vehicle engines powered by diesel oil, such as buses and trucks. It is known that the combustion of diesel oil is source of many contaminant gases such as: nitrogen oxides, SO2, CO and hydrocarbons. At this work, we use a SO2laser photoacoustic spectrometer to analyze gas samples collected in a bus characterized by an intense traffic. After this study, some gas species of environmental interest, such as SO2 and NO2, were detected and identified in the collected samples, at level of ppm.

From inequity to burnout: the role of job stress.

PubMed

Taris, T W; Peeters, M C; Le Blanc, P M; Schreurs, P J; Schaufeli, W B

2001-10-01

This research examined burnout (i.e., emotional exhaustion, depersonalization, and lack of personal accomplishment) among 2 samples of Dutch teachers as a function of inequity and experienced job stress in 3 different exchange relationships (with students, colleagues, and the school). It was hypothesized that inequity would be linked to burnout through the stress resulting from this inequity. Analysis of a cross-sectional sample (N = 271) revealed that this was indeed the case. Findings were replicated longitudinally using an independent sample of 940 teachers. It is concluded that the often-reported effect of inequity on burnout can partly be interpreted in terms of elevated levels of job stress. Implications of the findings are discussed.

A study of extractive and remote-sensing sampling and measurement of emissions from military aircraft engines

NASA Astrophysics Data System (ADS)

Cheng, Meng-Dawn; Corporan, Edwin

2010-12-01

Aircraft emissions contribute to the increased atmospheric burden of particulate matter (PM) that plays an important role in air quality, human health, visibility, contrail formation and climate change. Sampling and measurement of modern aircraft emissions at the engine exhaust plane (EEP) for engine and fuel certification remains challenging, as no agency-certified method is available. In this paper we summarize the results of three recent field studies devoted to investigate the consistency and applicability of "extractive" and "optical remote-sensing" (ORS) technologies in the sampling and measurement of gaseous and PM emitted by a number of military aircraft engines. Three classes of military engines were investigated; these include T56, TF33, and T700 & T701C types of engines, which consume 70-80% of the military aviation fuel each year. JP-8 and Fischer-Tropsch (FT)-derived paraffinic fuels were used to study the effect of fuels. It was found that non-volatile particles in the engine emissions were in the 20 nm range for the low power condition of new helicopter engines to 80 nm for the high power condition of legacy engines. Elemental analysis indicated little metals were present on particles, while most of the materials on the exhaust particles were carbon and sulfate based. Alkanes, carbon monoxide, carbon dioxide, nitrogen oxides, sulfur dioxide, formaldehyde, ethylene, acetylene and propylene were detected. The last five species were most noticeable only under low engine power. The emission indices calculated based on the ORS data deviate significantly from those based on the extractive data. Nevertheless, the ORS techniques were useful in the sense that it provided non-intrusive real-time detection of species in the exhaust plume, which warrants further development. The results obtained in this program help validate sampling methodology and measurement techniques used for non-volatile PM aircraft emissions as described in the SAE AIR6037 (2009).

Measurement of airborne concentrations of tire and road wear particles in urban and rural areas of France, Japan, and the United States

NASA Astrophysics Data System (ADS)

Panko, Julie M.; Chu, Jennifer; Kreider, Marisa L.; Unice, Ken M.

2013-06-01

In addition to industrial facilities, fuel combustion, forest fires and dust erosion, exhaust and non-exhaust vehicle emissions are an important source of ambient air respirable particulate matter (PM10). Non-exhaust vehicle emissions are formed from wear particles of vehicle components such as brakes, clutches, chassis and tires. Although the non-exhaust particles are relatively minor contributors to the overall ambient air particulate load, reliable exposure estimates are few. In this study, a global sampling program was conducted to quantify tire and road wear particles (TRWP) in the ambient air in order to understand potential human exposures and the overall contribution of these particles to the PM10. The sampling was conducted in Europe, the United States and Japan and the sampling locations were selected to represent a variety of settings including both rural and urban core; and within each residential, commercial and recreational receptors. The air samples were analyzed using validated chemical markers for rubber polymer based on a pyrolysis technique. Results indicated that TRWP concentrations in the PM10 fraction were low with averages ranging from 0.05 to 0.70 μg m-3, representing an average PM10 contribution of 0.84%. The TRWP concentration in air was associated with traffic load and population density, but the trend was not statistically significant. Further, significant differences across days were not observed. This study provides a robust dataset to understand potential human exposures to airborne TRWP.

Endothelial Inflammatory Transcriptional Responses Induced by Plasma Following Inhalation of Diesel Emissions

PubMed Central

Schisler, Jonathan C.; Ronnebaum, Sarah M.; Madden, Michael; Channell, Meghan M.; Campen, Matthew J.; Willis, Monte S.

2016-01-01

Background Air pollution, especially emissions derived from traffic sources, is associated with adverse cardiovascular outcomes. However, it remains unclear how inhaled factors drive extrapulmonary pathology. Objectives Previously, we found that canonical inflammatory response transcripts were elevated in cultured endothelial cells treated with plasma obtained after exposure compared with pre-exposure samples or filtered air (sham) exposures. While the findings confirmed the presence of bioactive factor(s) in the plasma after diesel inhalation, we wanted to better examine the complete genomic response to investigate 1) major responsive transcripts and 2) collected response pathways and ontogeny that may help to refine this method and inform the pathogenesis. Methods We assayed endothelial RNA with gene expression microarrays, examining the responses of cultured endothelial cells to plasma obtained from 6 healthy human subjects exposed to 100 μg/m3 diesel exhaust or filtered air for 2 h on separate occasions. In addition to pre-exposure baseline samples, we investigated samples obtained immediately-post and 24h-post exposure. Results Microarray analysis of the coronary artery endothelial cells challenged with plasma identified 855 probes that changed over time following diesel exhaust exposure. Over-representation analysis identified inflammatory cytokine pathways were upregulated both at the 2 and 24 h condition. Novel pathways related to FOX transcription factors and secreted extracellular factors were also identified in the microarray analysis. Conclusions These outcomes are consistent with our recent findings that plasma contains bioactive and inflammatory factors following pollutant inhalation. The specific study design implicates a novel pathway related to inflammatory blood borne components that may drive the extrapulmonary toxicity of ambient air pollutants. PMID:25942053

40 CFR 1065.546 - Validation of minimum dilution ratio for PM batch sampling.

Code of Federal Regulations, 2011 CFR

2011-07-01

... the raw exhaust flow rate based on the measured intake air molar flow rate and the chemical balance..., fuel rate measurements, and fuel properties, consistent with good engineering judgment. (b) Determine...) and dilute exhaust corrected for any removed water. (c) Use good engineering judgment to develop your...

40 CFR 86.127-96 - Test procedures; overview.

Code of Federal Regulations, 2012 CFR

2012-07-01

... or all of the following emissions: (1) Gaseous exhaust THC, CO, NOX. CO2 (for petroleum-fueled and... gaseous-fueled vehicles). (b) The Otto-cycle exhaust emission test is designed to determine gaseous THC... analyzed for THC using a heated sample line and analyzer; the other gaseous emissions (CH4, CO, CO2, and...

40 CFR 86.127-96 - Test procedures; overview.

Code of Federal Regulations, 2010 CFR

2010-07-01

... or all of the following emissions: (1) Gaseous exhaust THC, CO, NOX. CO2 (for petroleum-fueled and... gaseous-fueled vehicles). (b) The Otto-cycle exhaust emission test is designed to determine gaseous THC... analyzed for THC using a heated sample line and analyzer; the other gaseous emissions (CH4, CO, CO2, and...

40 CFR 86.127-96 - Test procedures; overview.

Code of Federal Regulations, 2013 CFR

2013-07-01

... or all of the following emissions: (1) Gaseous exhaust THC, CO, NOX. CO2 (for petroleum-fueled and... gaseous-fueled vehicles). (b) The Otto-cycle exhaust emission test is designed to determine gaseous THC... analyzed for THC using a heated sample line and analyzer; the other gaseous emissions (CH4, CO, CO2, and...

40 CFR 86.127-96 - Test procedures; overview.

Code of Federal Regulations, 2011 CFR

2011-07-01

... or all of the following emissions: (1) Gaseous exhaust THC, CO, NOX. CO2 (for petroleum-fueled and... gaseous-fueled vehicles). (b) The Otto-cycle exhaust emission test is designed to determine gaseous THC... analyzed for THC using a heated sample line and analyzer; the other gaseous emissions (CH4, CO, CO2, and...

A Teaching Approach from the Exhaustive Search Method to the Needleman-Wunsch Algorithm

ERIC Educational Resources Information Center

Xu, Zhongneng; Yang, Yayun; Huang, Beibei

2017-01-01

The Needleman-Wunsch algorithm has become one of the core algorithms in bioinformatics; however, this programming requires more suitable explanations for students with different major backgrounds. In supposing sample sequences and using a simple store system, the connection between the exhaustive search method and the Needleman-Wunsch algorithm…

A flow calorimeter for determining combustion efficiency from residual enthalpy of exhaust gases

NASA Technical Reports Server (NTRS)

Evans, Albert; Hibbard, Robert R

1954-01-01

A flow calorimeter for determining the combustion efficiency of turbojet and ram-jet combustors from measurement of the residual enthalpy of combustion of the exhaust gas is described. Briefly, the calorimeter catalytically oxidizes the combustible constituents of exhaust-gas samples, and the resultant temperature rise is measured. This temperature rise is related to the residual enthalpy of combustion of the sample by previous calibration of the calorimeter. Combustion efficiency can be calculated from a knowledge of the residual enthalpy of the exhaust gas and the combustor input enthalpy. An accuracy of +-0.2 Btu per cubic foot was obtained with prepared fuel-air mixtures, and the combustion efficiencies of single turbojet combustors measured by both the flow-calorimeter and heat-balance methods compared within 3 percentage units. Flow calorimetry appears to be a suitable method for determining combustion efficiencies at high combustor temperatures where ordinary thermocouples cannot be used. The method is fundamentally more accurate than heat-balance methods at high combustion efficiencies and can be used to verify near-100-percent efficiency data.

Mutagenicity of diesel exhaust particle extracts: influence of fuel composition in two diesel engines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Clark, C.R.; Henderson, T.R.; Royer, R.E.

The influence of diesel fuel composition on mutagenicity of exhaust particle associated organic compounds has been investigated using nine fuels varying in aromatic content and distillation properties. The tests were conducted with Oldsmobile Delta-88 and Peugot 504 diesel cars operated according to the EPA Federal Test Procedure. The particulate exhaust from each test was collected on a filter, extracted in dichloromethane and the resulting extract evaluated for mutagenicity in Salmonella strain TA-100. Mutagenicity of extracts of particles collected from the Oldsmobile were highest in the higher aromatic content fuels (greater than 30%) but similar for intermediate (20%) and low (13%)more » aromatic content fuels. No influence of aromaticity on mutagenicity was observed in samples collected from the Peugeot under the same conditions. Thus, fuel aromatic content may enhance the production of mutagenic combustion products at higher concentrations, but may be dependent upon engine type. A good correlation was observed between mutagenicity of the particle extracts and the initial boiling point of the fuel (r . 0.89). Gas chromatography/mass spectrometric analysis of the aromatic fraction of the fuels showed that the fuel producing the most mutagenic combustion products was highest in phenanthrene type compounds.« less

Mutagenicity of diesel exhaust particle extracts: influence of fuel composition in two diesel engines

DOE Office of Scientific and Technical Information (OSTI.GOV)

Clark, C.R.; Henderson, T.R.; Royer, R.E.

The influence of diesel fuel composition on mutagenicity of exhaust particle associated organic compounds has been investigated using nine fuels varying in aromatic content and distillation properties. The tests were conducted with Oldsmobile Delta-88 and Peugot 504 diesel cars operated according to the EPA Federal Test Procedure. The particulate exhaust from each test was collected on a filter, extracted in dichloromethane and the resulting extract evaluated for mutagenicity in Salmonella strain TA-100. Mutagenicity of extracts of particles collected from the Oldsmobile were highest in the higher aromatic content fuels (> 30%) but similar for intermediate (20%) and low (13%) aromaticmore » content fuels. No influence of aromaticity on mutagenicity was observed in samples collected from the Peugeot under the same conditions. Thus, fuel aromatic content may enhance the production of mutagenic combustion products at higher concentrations, but may be dependent upon engine type. A good correlation was observed between mutagenicity of the particle extracts and the initial boiling point of the fuel (r = 0.89). Gas chromatography/mass spectrometric analysis of the aromatic fraction of the fuels showed that the fuel producing the most mutagenic combustion products was highest in phenanthrene type compounds.« less

Control of diesel gaseous and particulate emissions with a tube-type wet electrostatic precipitator.

PubMed

Saiyasitpanich, Phirun; Keener, Tim C; Lu, Mingming; Liang, Fuyan; Khang, Soon-Jai

2008-10-01

In this study, experiments were performed with a bench-scale tube-type wet electrostatic precipitator (wESPs) to investigate its effectiveness for the removal of mass- and number-based diesel particulate matter (DPM), hydrocarbons (HCs), carbon monoxide (CO), and oxides of nitrogen (NOx) from diesel exhaust emissions. The concentration of ozone (O3) present in the exhaust that underwent a nonthermal plasma treatment process inside the wESP was also measured. A nonroad diesel generator operating at varying load conditions was used as a stationary diesel emission source. The DPM mass analysis was conducted by means of isokinetic sampling and the DPM mass concentration was determined by a gravimetric method. An electrical low-pressure impactor (ELPI) was used to quantify the DPM number concentration. The HC compounds, n-alkanes, and polycyclic aromatic hydrocarbons (PAHs) were collected on a moisture-free quartz filter together with a PUF/XAD/PUF cartridge and extracted in dichloromethane with sonication. Gas chromatography (GC)/mass spectroscopy (MS) was used to determine HC concentrations in the extracted solution. A calibrated gas combustion analyzer (Testo 350) and an O3 analyzer were used for quantifying the inlet and outlet concentrations of CO and NOx (nitric oxide [NO] + nitrogen dioxide [NO2]), and O3 in the diesel exhaust stream. The wESP was capable of removing approximately 67-86% of mass- and number-based DPM at a 100% exhaust volumetric flow rate generated from 0- to 75-kW engine loads. At 75-kW engine load, increasing gas residence time from approximately 0.1 to 0.4 sec led to a significant increase of DPM removal efficiency from approximately 67 to more than 90%. The removal of n-alkanes, 16 PAHs, and CO in the wESP ranged from 31 to 57% and 5 to 38%, respectively. The use of the wESP did not significantly affect NOx concentration in diesel exhaust. The O3 concentration in diesel exhaust was measured to be less than 1 ppm. The main mechanisms responsible for the removal of these pollutants from diesel exhaust are discussed.

Plasma mixing glow discharge device for analytical applications

DOEpatents

Pinnaduwage, Lal A.

1999-01-01

An instrument for analyzing a sample has an enclosure that forms a chamber containing an anode which divides the chamber into a discharge region and an analysis region. A gas inlet and outlet are provided to introduce and exhaust a rare gas into the discharge region. A cathode within the discharge region has a plurality of pins projecting in a geometric pattern toward the anode for exciting the gas and producing a plasma discharge between the cathode and the anode. Low energy electrons (e.g. <0.5 eV) pass into the analysis region through an aperture. The sample to be analyzed is placed into the analysis region and bombarded by the metastable rare gas atoms and the low energy electrons extracted into from the discharge region. A mass or optical spectrometer can be coupled to a port of the analysis region to analyze the resulting ions and light emission.

Plasma mixing glow discharge device for analytical applications

DOEpatents

Pinnaduwage, L.A.

1999-04-20

An instrument for analyzing a sample has an enclosure that forms a chamber containing an anode which divides the chamber into a discharge region and an analysis region. A gas inlet and outlet are provided to introduce and exhaust a rare gas into the discharge region. A cathode within the discharge region has a plurality of pins projecting in a geometric pattern toward the anode for exciting the gas and producing a plasma discharge between the cathode and the anode. Low energy electrons (e.g. <0.5 eV) pass into the analysis region through an aperture. The sample to be analyzed is placed into the analysis region and bombarded by the metastable rare gas atoms and the low energy electrons extracted into from the discharge region. A mass or optical spectrometer can be coupled to a port of the analysis region to analyze the resulting ions and light emission. 3 figs.

Development of methodologies for identification and quantification of hazardous air pollutants from turbine engine emissions.

PubMed

Anneken, David; Striebich, Richard; DeWitt, Matthew J; Klingshirn, Christopher; Corporan, Edwin

2015-03-01

Aircraft turbine engines are a significant source of particulate matter (PM) and gaseous emissions in the vicinity of airports and military installations. Hazardous air pollutants (HAPs) (e.g., formaldehyde, benzene, naphthalene and other compounds) associated with aircraft emissions are an environmental concern both in flight and at ground level. Therefore, effective sampling, identification, and accurate measurement of these trace species are important to assess their environmental impact. This effort evaluates two established ambient air sampling and analysis methods, U.S. Environmental Protection Agency (EPA) Method TO-11A and National Institute for Occupational Safety and Health (NIOSH) Method 1501, for potential use to quantify HAPs from aircraft turbine engines. The techniques were used to perform analysis of the exhaust from a T63 turboshaft engine, and were examined using certified gas standards transferred through the heated sampling systems used for engine exhaust gaseous emissions measurements. Test results show that the EPA Method TO-11A (for aldehydes) and NIOSH Method 1501 (for semivolatile hydrocarbons) were effective techniques for the sampling and analysis of most HAPs of interest. Both methods showed reasonable extraction efficiencies of HAP species from the sorbent tubes, with the exception of acrolein, styrene, and phenol, which were not well quantified. Formaldehyde measurements using dinitrophenylhydrazine (DNPH) tubes (EPA method TO-11A) were accurate for gas-phase standards, and compared favorably to measurements using gas-phase Fourier-transform infrared (FTIR) spectroscopy. In general, these two standard methodologies proved to be suitable techniques for field measurement of turbine engine HAPs within a reasonable (5-10 minutes) sampling period. Details of the tests, the analysis methods, calibration procedures, and results from the gas standards and T63 engine tested using a conventional JP-8 jet fuel are provided. HAPs from aviation-related sources are important because of their adverse health and environmental impacts in and around airports and flight lines. Simpler, more convenient techniques to measure the important HAPs, especially aldehydes and volatile organic HAPs, are needed to provide information about their occurrence and assist in the development of engines that emit fewer harmful emissions.

Dynamic Test Bed Analysis of Gas Energy Balance for a Diesel Exhaust System Fit with a Thermoelectric Generator

NASA Astrophysics Data System (ADS)

Fuc, Pawel; Lijewski, Piotr; Ziolkowski, Andrzej; Dobrzyński, Michal

2017-05-01

Analysis of the energy balance for an exhaust system of a diesel engine fit with an automotive thermoelectric generator (ATEG) of our own design has been carried out. A special measurement system and dedicated software were developed to measure the power generated by the modules. The research object was a 1.3-l small diesel engine with power output of 66 kW. The tests were carried out on a dynamic engine test bed that allows reproduction of an actual driving cycle expressed as a function V = f( t), simulating drivetrain (clutch, transmission) operating characteristics, vehicle geometrical parameters, and driver behavior. Measurements of exhaust gas thermodynamic parameters (temperature, pressure, and mass flow) as well as the voltage and current generated by the thermoelectric modules were performed during tests of our own design. Based on the results obtained, the flow of exhaust gas energy in the entire exhaust system was determined along with the ATEG power output. The ideal area of the exhaust system for location of the ATEG was defined to ensure the highest thermal energy recovery efficiency.

Assessment of airborne bacteria and noroviruses in air emission from a new highly-advanced hospital wastewater treatment plant.

PubMed

Uhrbrand, K; Schultz, A C; Koivisto, A J; Nielsen, U; Madsen, A M

2017-04-01

Exposure to bioaerosols can pose a health risk to workers at wastewater treatment plants (WWTPs) and to habitants of their surroundings. The main objective of this study was to examine the presence of harmful microorganisms in the air emission from a new type of hospital WWTP employing advanced wastewater treatment technologies. Air particle measurements and sampling of inhalable bacteria, endotoxin and noroviruses (NoVs) were performed indoor at the WWTP and outside at the WWTP ventilation air exhaust, downwind of the air exhaust, and upwind of the WWTP. No significant differences were seen in particle and endotoxin concentrations between locations. Bacterial concentrations were comparable or significantly lower in the exhaust air than inside the WWTP and in the upwind reference. Bacterial isolates were identified using matrix-assisted laser desorption-ionization time-of-flight mass spectrometry. In total, 35 different bacterial genera and 64 bacterial species were identified in the air samples. Significantly higher genus and species richness was found with an Andersen Cascade Impactor compared with filter-based sampling. No pathogenic bacteria were found in the exhaust air. Streptomyces was the only bacterium found in the air both inside the WWTP and at the air emission, but not in the upwind reference. NoV genomes were detected in the air inside the WWTP and at the air exhaust, albeit in low concentrations. As only traces of NoV genomes could be detected in the exhaust air they are unlikely to pose a health risk to surroundings. Hence, we assess the risk of airborne exposure to pathogenic bacteria and NoVs from the WWTP air emission to surroundings to be negligible. However, as a slightly higher NoV concentration was detected inside the WWTP, we cannot exclude the possibility that exposure to airborne NoVs can pose a health risk to susceptible to workers inside the WWTP, although the risk may be low. Copyright © 2017 Elsevier Ltd. All rights reserved.

Development of size-selective sampling of Bacillus anthracis surrogate spores from simulated building air intake mixtures for analysis via laser-induced breakdown spectroscopy.

PubMed

Gibb-Snyder, Emily; Gullett, Brian; Ryan, Shawn; Oudejans, Lukas; Touati, Abderrahmane

2006-08-01

Size-selective sampling of Bacillus anthracis surrogate spores from realistic, common aerosol mixtures was developed for analysis by laser-induced breakdown spectroscopy (LIBS). A two-stage impactor was found to be the preferential sampling technique for LIBS analysis because it was able to concentrate the spores in the mixtures while decreasing the collection of potentially interfering aerosols. Three common spore/aerosol scenarios were evaluated, diesel truck exhaust (to simulate a truck running outside of a building air intake), urban outdoor aerosol (to simulate common building air), and finally a protein aerosol (to simulate either an agent mixture (ricin/anthrax) or a contaminated anthrax sample). Two statistical methods, linear correlation and principal component analysis, were assessed for differentiation of surrogate spore spectra from other common aerosols. Criteria for determining percentages of false positives and false negatives via correlation analysis were evaluated. A single laser shot analysis of approximately 4 percent of the spores in a mixture of 0.75 m(3) urban outdoor air doped with approximately 1.1 x 10(5) spores resulted in a 0.04 proportion of false negatives. For that same sample volume of urban air without spores, the proportion of false positives was 0.08.

Turnover intention and emotional exhaustion "at the top": adapting the job demands-resources model to leaders of addiction treatment organizations.

PubMed

Knudsen, Hannah K; Ducharme, Lori J; Roman, Paul M

2009-01-01

Compared with the large literature on subordinate employees, there are few studies of emotional exhaustion and turnover intention for organizational leaders. There is little research that has extended the job demands-resources (JD-R) model of emotional exhaustion to leaders. In this study, the authors adapted the JD-R framework to analyze data collected from a sample of 410 leaders of addiction treatment organizations. The authors considered whether two job demands (performance demands and centralization) and two job resources (innovation in decision making and long-range strategic planning) were associated with emotional exhaustion and turnover intention. The authors also examined whether emotional exhaustion fully or partially mediated the associations between the job-related measures and turnover intention. The results supported the partially mediated model. Both job demands were positively associated with emotional exhaustion, and the association for long-range strategic planning was negative. Emotional exhaustion was positively associated with turnover intention. Centralization and innovation in decision making were also directly associated with turnover intention. Future research should continue to examine this theoretical framework among leaders of other types of organizations using more refined measures of demands and resources.

Turnover intention and emotional exhaustion “at the top”: Adapting the job demands-resources model to leaders of addiction treatment organizations

PubMed Central

Knudsen, Hannah K.; Ducharme, Lori J.; Roman, Paul M.

2009-01-01

Compared to the large literature on subordinate employees, there are few studies of emotional exhaustion and turnover intention for organizational leaders. There is little research that has extended the job demands-resources (JD-R) model of emotional exhaustion to leaders. In this study, we adapted the JD-R framework in order to analyze data collected from a sample of 410 leaders of addiction treatment organizations. We considered whether two job demands (performance demands and centralization) and two job resources (innovation in decision-making and long-range strategic planning) were associated with emotional exhaustion and turnover intention. We also examined whether emotional exhaustion fully or partially mediated the associations between the job-related measures and turnover intention. The results supported the partially mediated model. Both job demands were positively associated with emotional exhaustion, while the association for long-range strategic planning was negative. Emotional exhaustion was positively associated with turnover intention. Centralization and innovation in decision-making were also directly associated with turnover intention. Future research should continue to examine this theoretical framework among leaders of other types of organizations using more refined measures of demands and resources. PMID:19210050

Combustion of diesel fuel from a toxicological perspective. I. Origin of incomplete combustion products.

PubMed

Scheepers, P T; Bos, R P

1992-01-01

Since the use of diesel engines is still increasing, the contribution of their incomplete combustion products to air pollution is becoming ever more important. The presence of irritating and genotoxic substances in both the gas phase and the particulate phase constituents is considered to have significant health implications. The quantity of soot particles and the particle-associated organics emitted from the tail pipe of a diesel-powered vehicle depend primarily on the engine type and combustion conditions but also on fuel properties. The quantity of soot particles in the emissions is determined by the balance between the rate of formation and subsequent oxidation. Organics are absorbed onto carbon cores in the cylinder, in the exhaust system, in the atmosphere and even on the filter during sample collection. Diesel fuel contains polycyclic aromatic hydrocarbons (PAHs) and some alkyl derivatives. Both groups of compounds may survive the combustion process. PAHs are formed by the combustion of crankcase oil or may be resuspended from engine and/or exhaust deposits. The conversion of parent PAHs to oxygenated and nitrated PAHs in the combustion chamber or in the exhaust system is related to the vast amount of excess combustion air that is supplied to the engine and the high combustion temperature. Whether the occurrence of these derivatives is characteristic for the composition of diesel engine exhaust remains to be ascertained. After the emission of the particles, their properties may change because of atmospheric processes such as aging and resuspension. The particle-associated organics may also be subject to (photo)chemical conversions or the components may change during sampling and analysis. Measurement of emissions of incomplete combustion products as determined on a chassis dynamometer provides knowledge of the chemical composition of the particle-associated organics. This knowledge is useful as a basis for a toxicological evaluation of the health hazards of diesel engine emissions.

A study of job stress and burnout and related factors in the hospital personnel of Iran.

PubMed

Abarghouei, Mohammad Reza; Sorbi, Mohammad Hossein; Abarghouei, Mehdi; Bidaki, Reza; Yazdanpoor, Shirin

2016-07-01

Job stress has become one of the main factors in reducing efficiency and the loss of human resources that may cause physical and psychological adverse effects in employees. Hospital personnel are facing different stressful events, such as birth, pain and death, in a single day. Hence, identifying the job stress rates and related factors may be effective in offering proper strategies. Therefore, the present research was done to study the rate of job stress and burnout in hospital personnel and compare some of the related factors in hospitals personnel of Yazd, Iran. This cross-sectional study was conducted on 306 hospital personnel (Male: 114, Female: 192) in Yazd in 2015-16. The data were collected using a demographic questionnaire, Maslach Burnout Inventory (MBI), and Hospital Stress (HSS-35). SPSS-16 software and Pearson-product moment correlation and independent-samples t-test were used for data analysis. The mean job stress score was above average. The mean burnout dimensions that were above average included emotional exhaustion (21.7 ± 7.27), depersonalization (9.61 ± 3.74) and personal accomplishment (26.80 ± 6.17). While Pearson correlation revealed a significant positive relationship between job stress, emotional exhaustion, and depersonalization, there was a negative relationship between job stress and personal accomplishment (p < 0.01). Independent-samples t-test results showed that the rate of job stress, emotional exhaustion, and depersonalization in males is higher than females, married people have more emotional exhaustion than single ones, and, finally, health staff have more job stress than administrative staff. At the same time, the administrative staff and females have better personal accomplishment than other groups (p < 0.05). Since the rate of job stress in hospital personnel is worrying and it has adverse effects on personnel health, effective strategies on physical and mental health, such as employment support and stress management training, seem crucial to enhance physical and psychological health of hospital personnel.

A study of job stress and burnout and related factors in the hospital personnel of Iran

PubMed Central

Abarghouei, Mohammad Reza; Sorbi, Mohammad Hossein; Abarghouei, Mehdi; Bidaki, Reza; Yazdanpoor, Shirin

2016-01-01

Introduction Job stress has become one of the main factors in reducing efficiency and the loss of human resources that may cause physical and psychological adverse effects in employees. Hospital personnel are facing different stressful events, such as birth, pain and death, in a single day. Hence, identifying the job stress rates and related factors may be effective in offering proper strategies. Therefore, the present research was done to study the rate of job stress and burnout in hospital personnel and compare some of the related factors in hospitals personnel of Yazd, Iran. Methods This cross-sectional study was conducted on 306 hospital personnel (Male: 114, Female: 192) in Yazd in 2015–16. The data were collected using a demographic questionnaire, Maslach Burnout Inventory (MBI), and Hospital Stress (HSS-35). SPSS-16 software and Pearson-product moment correlation and independent-samples t-test were used for data analysis. Results The mean job stress score was above average. The mean burnout dimensions that were above average included emotional exhaustion (21.7 ± 7.27), depersonalization (9.61 ± 3.74) and personal accomplishment (26.80 ± 6.17). While Pearson correlation revealed a significant positive relationship between job stress, emotional exhaustion, and depersonalization, there was a negative relationship between job stress and personal accomplishment (p < 0.01). Independent-samples t-test results showed that the rate of job stress, emotional exhaustion, and depersonalization in males is higher than females, married people have more emotional exhaustion than single ones, and, finally, health staff have more job stress than administrative staff. At the same time, the administrative staff and females have better personal accomplishment than other groups (p < 0.05). Conclusion Since the rate of job stress in hospital personnel is worrying and it has adverse effects on personnel health, effective strategies on physical and mental health, such as employment support and stress management training, seem crucial to enhance physical and psychological health of hospital personnel. PMID:27648189

Analysis of the Theoretical Relationships Between Work Exhaustion, Job Satisfaction, and Turnover Intention of Air Force Information Systems Managers

DTIC Science & Technology

2003-03-01

were stimulated by Cordes and Dougherty (1993). A proposed theory of burnout facilitates such efforts ( Schaufeli et al., 1995). Schaufleli et al...as the depletion of mental resources. Moore’s study focuses on work exhaustion in technology professionals and, therefore, uses the Schaufeli et...al. concept and measure of exhaustion. To place emphasis on the workplace aspect of the Schaufeli et al.’s exhaustion construct, Moore’s research

How job demands affect absenteeism? The mediating role of work-family conflict and exhaustion.

PubMed

Vignoli, Michela; Guglielmi, Dina; Bonfiglioli, Roberta; Violante, Francesco Saverio

2016-01-01

To investigate how psychosocial factors (such as job demands and work-family conflict) produce absenteeism in the workplace, using the health impairment process of the job demands-resources model. According to this model, job demands lead to burnout (often measured with the emotional exhaustion component), which in turn could lead to outcomes (such as absenteeism). Work-family conflict (WFC) was also studied, because of contradictory results collected in the existing literature on absenteeism in the workplace, regarding the role of WFC in causing absenteeism. Data were collected on 245 workers using both subjective (questionnaire on psychological risk factors and work-related health) and objective data (sickness leave frequency records). To test the hypothesis that job demands and WFC contribute to absenteeism in the workplace, a subsequent mediation analysis was used, which analysed both (a) the subsequent mediation of WFC and emotional exhaustion and (b) the separate roles played by the mediators proposed (WFC and emotional exhaustion). Job demands affect absenteeism through the subsequent mediation of WFC and emotional exhaustion. In addition, emotional exhaustion mediates the relationship between job demands and absenteeism, while WFC does not. In conclusion, subsequent mediation highlights the role of emotional exhaustion in causing absenteeism; in fact, when emotional exhaustion is included in the analysis, job demands are associated with higher levels of absenteeism. The results of this study suggest that without the concurrent contribution of emotional exhaustion, WFC does not influence absenteeism in the workplace. Our findings are useful for organizations that aim to reduce absenteeism.

40 CFR 91.313 - Analyzers required.

Code of Federal Regulations, 2010 CFR

2010-07-01

... the heated flame ionization (HFID) type. (ii) For the HFID system, if the temperature of the exhaust gas at the sample probe is below 190 °C, the temperature of the valves, pipe work, and so forth, must be controlled so as to maintain a wall temperature of 190 ±11 °C. If the temperature of the exhaust...

40 CFR Table 4 to Subpart Aaaaa of... - Requirements for Performance Tests

Code of Federal Regulations, 2013 CFR

2013-07-01

... lime kiln and each associated lime cooler, if there is a separate exhaust to the atmosphere from the associated lime cooler Select the location of the sampling port and the number of traverse ports Method 1 or... each associated lime cooler, if there is a separate exhaust to the atmosphere from the associated lime...

40 CFR Table 4 to Subpart Aaaaa of... - Requirements for Performance Tests

Code of Federal Regulations, 2011 CFR

2011-07-01

... lime kiln and each associated lime cooler, if there is a separate exhaust to the atmosphere from the associated lime cooler Select the location of the sampling port and the number of traverse ports Method 1 or... each associated lime cooler, if there is a separate exhaust to the atmosphere from the associated lime...

40 CFR Table 4 to Subpart Aaaaa of... - Requirements for Performance Tests

Code of Federal Regulations, 2014 CFR

2014-07-01

... lime kiln and each associated lime cooler, if there is a separate exhaust to the atmosphere from the associated lime cooler Select the location of the sampling port and the number of traverse ports Method 1 or... each associated lime cooler, if there is a separate exhaust to the atmosphere from the associated lime...

40 CFR Table 4 to Subpart Aaaaa of... - Requirements for Performance Tests

Code of Federal Regulations, 2010 CFR

2010-07-01

... lime kiln and each associated lime cooler, if there is a separate exhaust to the atmosphere from the associated lime cooler Select the location of the sampling port and the number of traverse ports Method 1 or... each associated lime cooler, if there is a separate exhaust to the atmosphere from the associated lime...

40 CFR Table 4 to Subpart Aaaaa of... - Requirements for Performance Tests

Code of Federal Regulations, 2012 CFR

2012-07-01

... lime kiln and each associated lime cooler, if there is a separate exhaust to the atmosphere from the associated lime cooler Select the location of the sampling port and the number of traverse ports Method 1 or... each associated lime cooler, if there is a separate exhaust to the atmosphere from the associated lime...

40 CFR 86.160-00 - Exhaust emission test procedure for SC03 emissions.

Code of Federal Regulations, 2011 CFR

2011-07-01

....161-00. (ii) Turn on the solar heating system. (iii) All vehicle test phases of preconditioning, soak... percent relative humidity), a solar heat load intensity of 850 W/m2, and vehicle cooling air flow... all vehicle windows. (4) Connect the emission test sampling system to the vehicle's exhaust tail pipe...

40 CFR 1066.110 - Equipment specifications for emission sampling systems.

Code of Federal Regulations, 2014 CFR

2014-07-01

..., such as orifice plates or fins, to achieve good mixing; this may be necessary for good mixing if Re# is... condensation. (v) If you choose to dilute the exhaust by using a remote mix tee, which dilutes the exhaust at... polymer-based materials. (D) Use good engineering judgment to ensure that the materials you choose do not...

Multi-wavelength optical measurement to enhance thermal/optical analysis for carbonaceous aerosol

NASA Astrophysics Data System (ADS)

Chen, L.-W. A.; Chow, J. C.; Wang, X. L.; Robles, J. A.; Sumlin, B. J.; Lowenthal, D. H.; Zimmermann, R.; Watson, J. G.

2015-01-01

A thermal/optical carbon analyzer equipped with seven-wavelength light source/detector (405-980 nm) for monitoring spectral reflectance (R) and transmittance (T) of filter samples allowed "thermal spectral analysis (TSA)" and wavelength (λ)-dependent organic-carbon (OC)-elemental-carbon (EC) measurements. Optical sensing was calibrated with transfer standards traceable to absolute R and T measurements, adjusted for loading effects to report spectral light absorption (as absorption optical depth (τa, λ)), and verified using diesel exhaust samples. Tests on ambient and source samples show OC and EC concentrations equivalent to those from conventional carbon analysis when based on the same wavelength (~ 635 nm) for pyrolysis adjustment. TSA provides additional information that evaluates black-carbon (BC) and brown-carbon (BrC) contributions and their optical properties in the near infrared to the near ultraviolet parts of the solar spectrum. The enhanced carbon analyzer can add value to current aerosol monitoring programs and provide insight into more accurate OC and EC measurements for climate, visibility, or health studies.

Multi-wavelength optical measurement to enhance thermal/optical analysis for carbonaceous aerosol

NASA Astrophysics Data System (ADS)

Chen, L.-W. A.; Chow, J. C.; Wang, X. L.; Robles, J. A.; Sumlin, B.; Lowenthal, D. H.; Zimmermann, R.; Watson, J. G.

2014-09-01

A thermal/optical carbon analyzer equipped with seven-wavelength light source/detector (405-980 nm) for monitoring spectral reflectance (R) and transmittance (T) of filter samples allows "thermal spectral analysis (TSA)" and wavelength (λ)-dependent organic carbon (OC)-elemental carbon (EC) measurements. Optical sensing is calibrated with transfer standards traceable to absolute R and T measurements and adjusted for loading effects to determine spectral light absorption (as absorption optical depth [τa, λ]) using diesel exhaust samples as a reference. Tests on ambient and source samples show OC and EC concentrations equivalent to those from conventional carbon analysis when based on the same wavelength (~635 nm) for pyrolysis adjustment. TSA provides additional information that evaluates black carbon (BC) and brown carbon (BrC) contributions and their optical properties in the near-IR to the near-UV parts of the solar spectrum. The enhanced carbon analyzer can add value to current aerosol monitoring programs and provide insight into more accurate OC and EC measurements for climate, visibility, or health studies.

Exhaust Air Dust Monitoring is Superior to Soiled Bedding Sentinels for the Detection of Pasteurella pneumotropica in Individually Ventilated Cage Systems.

PubMed

Miller, Manuel; Ritter, Brbel; Zorn, Julia; Brielmeier, Markus

2016-11-01

Reliable detection of unwanted organisms is essential for meaningful health monitoring in experimental animal facilities. Currently, most rodents are housed in IVC systems, which prevent the aerogenic transmission of pathogens between cages. Typically soiled-bedding sentinels (SBS) exposed to soiled bedding collected from a population of animals within an IVC rack are tested as representatives, but infectious agents often go undetected due to inefficient transmission. Pasteurellaceae are among the most prevalent bacterial pathogens isolated from experimental mice, and the failure of SBS to detect these bacteria is well established. In this study, we investigated whether analysis of exhaust air dust (EAD) samples by using a sensitive and specific real-time PCR assay is superior to conventional SBS monitoring for the detection of Pasteurella pneumotropica (Pp) infections. In a rack with a known prevalence of Pp-positive mice, weekly EAD sampling was compared with the classic SBS method over 3 mo. In 6 rounds of testing, with a prevalence of 5 infected mice in each of 7 cages in a rack of 63 cages, EAD PCR detected Pp at every weekly time point; SBS failed to detect Pp in all cases. The minimal prevalence of Pp-infected mice required to obtain a reliable positive result by EAD PCR testing was determined to be 1 in 63 cages. Reliable detection of Pp was achieved after only 1 wk of exposure. Analysis of EAD samples by real-time PCR assay provides a sensitive, simple, and reliable approach for Pp identification in laboratory mice.

Exhaust Air Dust Monitoring is Superior to Soiled Bedding Sentinels for the Detection of Pasteurella pneumotropica in Individually Ventilated Cage Systems

PubMed Central

Miller, Manuel; Ritter, Bärbel; Zorn, Julia; Brielmeier, Markus

2016-01-01

Reliable detection of unwanted organisms is essential for meaningful health monitoring in experimental animal facilities. Currently, most rodents are housed in IVC systems, which prevent the aerogenic transmission of pathogens between cages. Typically soiled-bedding sentinels (SBS) exposed to soiled bedding collected from a population of animals within an IVC rack are tested as representatives, but infectious agents often go undetected due to inefficient transmission. Pasteurellaceae are among the most prevalent bacterial pathogens isolated from experimental mice, and the failure of SBS to detect these bacteria is well established. In this study, we investigated whether analysis of exhaust air dust (EAD) samples by using a sensitive and specific real-time PCR assay is superior to conventional SBS monitoring for the detection of Pasteurella pneumotropica (Pp) infections. In a rack with a known prevalence of Pp-positive mice, weekly EAD sampling was compared with the classic SBS method over 3 mo. In 6 rounds of testing, with a prevalence of 5 infected mice in each of 7 cages in a rack of 63 cages, EAD PCR detected Pp at every weekly time point; SBS failed to detect Pp in all cases. The minimal prevalence of Pp-infected mice required to obtain a reliable positive result by EAD PCR testing was determined to be 1 in 63 cages. Reliable detection of Pp was achieved after only 1 wk of exposure. Analysis of EAD samples by real-time PCR assay provides a sensitive, simple, and reliable approach for Pp identification in laboratory mice. PMID:27931316

Assessment of vital exhaustion and identification of subjects at increased risk of myocardial infarction in general practice.

PubMed

Schuitemaker, G E; Dinant, G J; van der Pol, G A; Appels, A

2004-01-01

Vital exhaustion, a state characterized by unusual fatigue, loss of energy, increased irritability, and feelings of demoralization, is one of the cardiovascular risk factors. The authors investigated whether vital exhaustion contributes to the identification of subjects at increased risk of myocardial infarction in general practice. In this prospective cohort study, vital exhaustion was assessed with the Maastricht Interview on Vital Exhaustion. Other cardiovascular risk factors established were age, gender, systolic and diastolic blood pressure, total cholesterol, body mass index, smoking habits, cardiovascular disease, and diabetes mellitus. A Cox regression analysis was used. The subjects were adults (41-66 years) in an average Dutch village population. Outcome measures were fatal and nonfatal myocardial infarction. At the univariate level, vital exhaustion doubled the risk of myocardial infarction. The effect of exhaustion was confounded by gender; women had higher exhaustion scores and a lower incidence of myocardial infarction. With control for gender, age, systolic blood pressure, total cholesterol, smoking habits, self-reported cardiovascular disease, and diabetes mellitus, vital exhaustion almost tripled the risk of myocardial infarction. Assessment of vital exhaustion contributes to the identification of subjects at increased risk of myocardial infarction in general practice.

Compressed-air power tools in orthopaedic surgery: exhaust air is a potential source of contamination.

PubMed

Sagi, H C; DiPasquale, Thomas; Sanders, Roy; Herscovici, Dolfi

2002-01-01

To determine if the exhaust from surgical compressed-air power tools contains bacteria and if the exhaust leads to contamination of sterile surfaces. Bacteriologic study of orthopaedic power tools. Level I trauma center operative theater. None. Part I. Exhaust from two sterile compact air drills was sampled directly at the exhaust port. Part II. Exhaust from the drills was directed at sterile agar plates from varying distances. The agar plates represented sterile surfaces within the operative field. Part III. Control cultures. A battery-powered drill was operated over open agar plates in similar fashion as the compressed-air drills. Agar plates left open in the operative theater served as controls to rule out atmospheric contamination. Random cultures were taken from agar plates, gloves, drills, and hoses. Incidence of positive cultures. In Part I, all filters from both compressed-air drill exhausts were culture negative ( = 0.008). In Part II, the incidence of positive cultures for air drills number one and number two was 73% and 82%, respectively. The most commonly encountered organisms were, coagulase-negative Staphylococcus, and Micrococcus species. All control cultures from agar plates, battery-powered drill, gloves, and hoses were negative ( < 0.01). Exhaust from compressed-air power tools in orthopaedic surgery may contribute to the dissemination of bacteria onto the surgical field. We do not recommend the use of compressed-air power tools that do not have a contained exhaust.

Psychobiological stress in vital exhaustion. Findings from the Men Stress 40+ study.

PubMed

Noser, Emilou; Fischer, Susanne; Ruppen, Jessica; Ehlert, Ulrike

2018-02-01

Despite the increased risk for cardiovascular morbidity associated with vital exhaustion (VE), the underlying pathophysiological mechanisms remain unclear. Allostatic load may constitute the missing link between VE and cardiovascular diseases. The aim of the present study was to investigate whether men with different degrees of VE would differ in terms of allostatic load, chronic stress, and social support. The Men Stress 40+ study sample consisted of N=121 apparently healthy men aged 40 to 75years. The following allostatic load markers were aggregated to create a cumulative index of biological stress: salivary cortisol, salivary dehydroepiandrosterone sulfate (DHEA-S), waist-to-hip-ratio, systolic and diastolic blood pressure. Long-term cortisol and DHEA were additionally measured in hair. Chronic stress and social support were assessed via validated questionnaires. Groups of mildly, substantially, and severely exhausted men were compared using one-way ANOVAs with appropriate post-hoc tests. Men who reported mild or severe levels of vital exhaustion had the highest scores on the cumulative index of biological stress. Hair cortisol was unrelated to vital exhaustion; hair DHEA was highest in men with substantial levels of exhaustion. Men with mild exhaustion reported the lowest levels of chronic stress, while men with severe exhaustion reported the lowest levels of social support. Signs of allostatic load are detectable in vitally exhausted men at a stage where no major cardiovascular consequences have yet ensued. Copyright © 2017 Elsevier Inc. All rights reserved.

[Target and non-target screening of volatile organic compounds in industrial exhaust gas using thermal desorption-gas chromatography-mass spectrometry].

PubMed

Ma, Huilian; Jin, Jing; Li, Yun; Chen, Jiping

2017-10-08

A method of comprehensive screening of the target and non-target volatile organic compounds (VOCs) in industrial exhaust gas using thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) has been developed. In this paper, two types of solid phase adsorption column were compared, and the Tenex SS TD Tube was selected. The analytes were enriched into the adsorption tube by constant flow sampling, and detected by TD-GC-MS in full scan mode. Target compounds were quantified by internal standard method, and the quantities of non-target compounds were calculated by response coefficient of toluene. The method detection limits (MDLs) for the 24 VOCs were 1.06 to 5.44 ng, and MDLs could also be expressed as 0.004 to 0.018 mg/m 3 assuming that the sampling volume was 300 mL. The average recoveries were in the range of 78.4% to 89.4% with the relative standard deviations (RSDs) of 3.9% to 14.4% ( n =7). The established analytical method was applied for the comprehensive screening of VOCs in a waste incineration power plant in Dalian city. Twenty-nine VOCs were identified. In these compounds, only five VOCs were the target compounds set in advance, which accounted for 26.7% of the total VOCs identified. Therefore, this study further proved the importance of screening non-target compounds in the analysis of VOCs in industrial exhaust gas, and has certain reference significance for the complete determination of VOCs distribution.

[Comparative study of burnout in Intensive Care and Emergency Care nursing staff].

PubMed

Ríos Risquez, M I; Godoy Fernández, C; Peñalver Hernández, F; Alonso Tovar, A R; López Alcaraz, F; López Romera, A; Garnés González, S; Salmerón Saura, E; López Real, M D; Ruiz Sánchez, R; Simón Domingo, P; Manzanera Nicolás, J L; Menchón Almagro, M A; Liébanas Bellón, R

2008-01-01

To assess and compare the burnout level between Intensive Care Unit and Emergency Unit, and study its association with the sociodemographic and work characteristics of the professionals surveyed. Cross-sectional, descriptive study. Emplacement. Intensive Care Unit of the university hospital Morales Meseguer, Murcia-Spain. STUDIED SAMPLE: 97 nursing professionals: 55 professionals belong to the Emergency Department, and 42 professionals belong to the Intensive Care Department. Two evaluation tools were used: a sociodemographic and work survey, and the Maslach Burnout Inventory, 1986. Quantitative variables expressed as mean +/- SD compared with the Student's T test and qualitative variables compared with the chi2 test. SPSS 12.0(c). The comparative analysis of the burnout dimensions shows that emotional exhaustion level is significantly higher in the intensive care service than in the emergency one (25.45 +/- 11.15 vs 22.09 +/- 10.99) p < 0.05. The rest of burnout dimensions do not show significant differences between both departments. The masculine gender obtains a higher score in the depersonalization dimension of burnout (10.12 +/- 5.38) than female one (6.7 +/- 5.21) p < 0.01. There is greater vulnerability to emotional exhaustion among the professional group with more than 15 years of work experience (F = 3.592; p = 0.031). The burnout levels are moderate to high among the nursing professionals studied. A total of 5.15% of the sample studied achieves a high score in the three dimensions of the burnout syndrome. The intensive care professionals are the most vulnerable to suffering high levels of emotional exhaustion, and the masculine gender is more susceptible to depersonalization attitudes.

Feasibility of corona discharge ion mobility spectrometry for direct analysis of samples extracted by dispersive liquid-liquid microextraction.

PubMed

Jafari, Mohammad T; Riahi, Farhad

2014-05-23

The capability of corona discharge ionization ion mobility spectrometry (CD-IMS) for direct analysis of the samples extracted by dispersive liquid-liquid microextraction (DLLME) was investigated and evaluated, for the first time. To that end, an appropriate new injection port was designed and constructed, resulting in possibility of direct injection of the known sample volume, without tedious sample preparation steps (e.g. derivatization, solvent evaporation, and re-solving in another solvent…). Malathion as a test compound was extracted from different matrices by a rapid and convenient DLLME method. The positive ion mobility spectra of the extracted malathion were obtained after direct injection of carbon tetrachloride or methanol solutions. The analyte responses were compared and the statistical results revealed the feasibility of direct analysis of the extracted samples in carbon tetrachloride, resulting in a convenient methodology. The coupled method of DLLME-CD-IMS was exhaustively validated in terms of sensitivity, dynamic range, recovery, and enrichment factor. Finally, various real samples of apple, river and underground water were analyzed, all verifying the feasibility and success of the proposed method for the easy extraction of the analyte using DLLME separation before the direct analysis by CD-IMS. Copyright © 2014 Elsevier B.V. All rights reserved.

The chemistry and diffusion of aircraft exhausts in the lower stratosphere during the first few hours after fly-by. [with attention to ozone depletion by SST exhaust plumes

NASA Technical Reports Server (NTRS)

Hilst, G. R.

1974-01-01

An analysis of the hydrogen-nitrogen-oxygen reaction systems in the lower stratosphere as they are initially perturbed by individual aircraft engine exhaust plumes was conducted in order to determine whether any significant chemical reactions occur, either among exhaust chemical species, or between these species and the environmental ozone, while the exhaust products are confined to intact plume segments at relatively high concentrations. The joint effects of diffusive mixing and chemical kinetics on the reactions were also studied, using the techniques of second-order closure diffusion/chemistry models. The focus of the study was on the larger problem of the potential depletion of ozone by supersonic transport aircraft exhaust materials emitted into the lower stratosphere.

Application of fault tree approach for the causation mechanism of urban haze in Beijing--Considering the risk events related with exhausts of coal combustion.

PubMed

Huang, Weiqing; Fan, Hongbo; Qiu, Yongfu; Cheng, Zhiyu; Qian, Yu

2016-02-15

Haze weather has become a serious environmental pollution problem which occurs in many Chinese cities. One of the most critical factors for the formation of haze weather is the exhausts of coal combustion, thus it is meaningful to figure out the causation mechanism between urban haze and the exhausts of coal combustion. Based on above considerations, the fault tree analysis (FAT) approach was employed for the causation mechanism of urban haze in Beijing by considering the risk events related with the exhausts of coal combustion for the first time. Using this approach, firstly the fault tree of the urban haze causation system connecting with coal combustion exhausts was established; consequently the risk events were discussed and identified; then, the minimal cut sets were successfully determined using Boolean algebra; finally, the structure, probability and critical importance degree analysis of the risk events were completed for the qualitative and quantitative assessment. The study results proved that the FTA was an effective and simple tool for the causation mechanism analysis and risk management of urban haze in China. Copyright © 2015 Elsevier B.V. All rights reserved.

A fuel-based approach to estimating motor vehicle exhaust emissions

NASA Astrophysics Data System (ADS)

Singer, Brett Craig

Motor vehicles contribute significantly to air pollution problems; accurate motor vehicle emission inventories are therefore essential to air quality planning. Current travel-based inventory models use emission factors measured from potentially biased vehicle samples and predict fleet-average emissions which are often inconsistent with on-road measurements. This thesis presents a fuel-based inventory approach which uses emission factors derived from remote sensing or tunnel-based measurements of on-road vehicles. Vehicle activity is quantified by statewide monthly fuel sales data resolved to the air basin level. Development of the fuel-based approach includes (1) a method for estimating cold start emission factors, (2) an analysis showing that fuel-normalized emission factors are consistent over a range of positive vehicle loads and that most fuel use occurs during loaded-mode driving, (3) scaling factors relating infrared hydrocarbon measurements to total exhaust volatile organic compound (VOC) concentrations, and (4) an analysis showing that economic factors should be considered when selecting on-road sampling sites. The fuel-based approach was applied to estimate carbon monoxide (CO) emissions from warmed-up vehicles in the Los Angeles area in 1991, and CO and VOC exhaust emissions for Los Angeles in 1997. The fuel-based CO estimate for 1991 was higher by a factor of 2.3 +/- 0.5 than emissions predicted by California's MVEI 7F model. Fuel-based inventory estimates for 1997 were higher than those of California's updated MVEI 7G model by factors of 2.4 +/- 0.2 for CO and 3.5 +/- 0.6 for VOC. Fuel-based estimates indicate a 20% decrease in the mass of CO emitted, despite an 8% increase in fuel use between 1991 and 1997; official inventory models predict a 50% decrease in CO mass emissions during the same period. Cold start CO and VOC emission factors derived from parking garage measurements were lower than those predicted by the MVEI 7G model. Current inventories in California appear to understate total exhaust CO and VOC emissions, while overstating the importance of cold start emissions. The fuel-based approach yields robust, independent, and accurate estimates of on-road vehicle emissions. Fuel-based estimates should be used to validate or adjust official vehicle emission inventories before society embarks on new, more costly air pollution control programs.

Analysis of possibilities of waste heat recovery in off-road vehicles

NASA Astrophysics Data System (ADS)

Wojciechowski, K. T.; Zybala, R.; Leszczynski, J.; Nieroda, P.; Schmidt, M.; Merkisz, J.; Lijewski, P.; Fuc, P.

2012-06-01

The paper presents the preliminary results of the waste heat recovery investigations for an agricultural tractor engine (7.4 dm3) and excavator engine (7.2 dm3) in real operating conditions. The temperature of exhaust gases and exhaust mass flow rate has been measured by precise portable exhaust emissions analyzer SEMTECH DS (SENSORS Inc.). The analysis shows that engines of tested vehicles operate approximately at constant speed and load. The average temperature of exhaust gases is in the range from 300 to 400 °C for maximum gas mass flows of 1100 kg/h and 1400 kg/h for tractor and excavator engine respectively. Preliminary tests show that application of TEGs in tested off-road vehicles offers much more beneficial conditions for waste heat recovery than in case of automotive engines.

40 CFR 1065.805 - Sampling system.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 33 2011-07-01 2011-07-01 false Sampling system. 1065.805 Section 1065... ENGINE-TESTING PROCEDURES Testing With Oxygenated Fuels § 1065.805 Sampling system. (a) Dilute engine exhaust, and use batch sampling to collect proportional flow-weighted dilute samples of the applicable...

40 CFR 1065.805 - Sampling system.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Sampling system. 1065.805 Section 1065... ENGINE-TESTING PROCEDURES Testing With Oxygenated Fuels § 1065.805 Sampling system. (a) Dilute engine exhaust, and use batch sampling to collect proportional flow-weighted dilute samples of the applicable...

Computer programs to predict induced effects of jets exhausting into a crossflow

NASA Technical Reports Server (NTRS)

Perkins, S. C., Jr.; Mendenhall, M. R.

1984-01-01

A user's manual for two computer programs was developed to predict the induced effects of jets exhausting into a crossflow. Program JETPLT predicts pressures induced on an infinite flat plate by a jet exhausting at angles to the plate and Program JETBOD, in conjunction with a panel code, predicts pressures induced on a body of revolution by a jet exhausting normal to the surface. Both codes use a potential model of the jet and adjacent surface with empirical corrections for the viscous or nonpotential effects. This program manual contains a description of the use of both programs, instructions for preparation of input, descriptions of the output, limitations of the codes, and sample cases. In addition, procedures to extend both codes to include additional empirical correlations are described.

Comparison of the toxicity of diesel exhaust produced by bio- and fossil diesel combustion in human lung cells in vitro

NASA Astrophysics Data System (ADS)

Steiner, Sandro; Czerwinski, Jan; Comte, Pierre; Popovicheva, Olga; Kireeva, Elena; Müller, Loretta; Heeb, Norbert; Mayer, Andreas; Fink, Alke; Rothen-Rutishauser, Barbara

2013-12-01

Alternative fuels are increasingly combusted in diesel- and gasoline engines and the contribution of such exhausts to the overall air pollution is on the rise. Recent findings on the possible adverse effects of biodiesel exhaust are contradictive, at least partly resulting from the various fuel qualities, engine types and different operation conditions that were tested. However, most of the studies are biased by undesired interactions between the exhaust samples and biological culture media. We here report how complete, freshly produced exhausts from fossil diesel (B0), from a blend of 20% rapeseed-methyl ester (RME) and 80% fossil diesel (B20) and from pure rapeseed methyl ester (B100) affect a complex 3D cellular model of the human airway epithelium in vitro by exposing the cells at the air-liquid interface. The induction of pro-apoptotic and necrotic cell death, cellular morphology, oxidative stress, and pro-inflammatory responses were assessed. Compared to B0 exhaust, B20 exhaust decreased oxidative stress and pro-inflammatory responses, whereas B100 exhaust, depending on exposure duration, decreased oxidative stress but increased pro-inflammatory responses. The effects are only very weak and given the compared to fossil diesel higher ecological sustainability of biodiesel, it appears that - at least RME - can be considered a valuable alternative to pure fossil diesel.

40 CFR 61.65 - Emission standard for ethylene dichloride, vinyl chloride and polyvinyl chloride plants.

Code of Federal Regulations, 2011 CFR

2011-07-01

... basis and analyzes the samples with gas chromatography or, if the owner or operator assumes that all... concentration of vinyl chloride in the exhaust gases does not exceed 10 ppm (average for 3-hour period), or... chloride in the exhaust gases does not exceed 10 ppm (average for 3-hour period), or equivalent as provided...

40 CFR 1066.125 - Data updating, recording, and control.

Code of Federal Regulations, 2014 CFR

2014-07-01

... minimum recording frequency, such as for sample flow rates from a CVS that does not have a heat exchanger... exhaust flow rate from a CVS with a heat exchanger upstream of the flow measurement 1 Hz. 40 CFR 1065.545§ 1066.425 Diluted exhaust flow rate from a CVS without a heat exchanger upstream of the flow measurement...

Enhanced atomic gas fractions in recently merged galaxies: quenching is not a result of post-merger gas exhaustion.

NASA Astrophysics Data System (ADS)

Ellison, Sara L.; Catinella, Barbara; Cortese, Luca

2018-05-01

We present a detailed assessment of the global atomic hydrogen gas fraction (fgas=log[MHI/M⋆]) in a sample of post-merger galaxies identified in the Sloan Digital Sky Survey (SDSS). Archival H I measurements of 47 targets are combined with new Arecibo observations of a further 51 galaxies. The stellar mass range of the post-merger sample, our observing strategy, detection thresholds and data analysis procedures replicate those of the extended GALEX Arecibo SDSS Survey (xGASS) which can therefore be used as a control sample. Our principal results are: 1) The post-merger sample shows a ˜ 50 per cent higher H I detection fraction compared with xGASS; 2) Accounting for non-detections, the median atomic gas fraction of the post-merger sample is larger than the control sample by 0.3 - 0.6 dex; 3) The median atomic gas fraction enhancement (Δfgas), computed on a galaxy-by-galaxy basis at fixed stellar mass, is 0.51 dex. Our results demonstrate that recently merged galaxies are typically a factor of ˜ 3 more H I rich than control galaxies of the same M⋆. If the control sample is additionally matched in star formation rate, the median H I excess is reduced to Δfgas = 0.2 dex, showing that the enhanced atomic gas fractions in post-mergers are not purely a reflection of changes in star formation activity. We conclude that merger-induced starbursts and outflows do not lead to prompt quenching via exhaustion/expulsion of the galactic gas reservoirs. Instead, we propose that if star formation ceases after a merger, it is more likely due to an enhanced turbulence which renders the galaxy unable to effectively form new stars.

Validity of the Parental Burnout Inventory Among Dutch Employees.

PubMed

Van Bakel, Hedwig J A; Van Engen, Marloes L; Peters, Pascale

2018-01-01

The purpose of this study was to validate the Parental Burnout Inventory (PBI) in a Dutch sample of working parents. The Dutch version of the PBI and questionnaires about work were administered to 627 working parents, with at least one child living at home. We investigated whether the tri-dimensional structure of the PBI held in a sample of male and female employed parents. Furthermore, we examined the relationships between PBI and the constructs work-related burnout, depressive mood, parenting stress and work-family conflict, which we assessed with widely used and validated instruments, i.e., emotional exhaustion [a subscale of the Dutch version of Maslach's Burnout Inventory], a Dutch Parental Stress Questionnaire and Work-Family Conflict. The results support the validity of a tri-dimensional parental burnout syndrome, including exhaustion, distancing and inefficacy. Low to moderate correlations between parents' burnout symptoms and professional exhaustion, parenting stress, depressive complaints and work-family conflict experiences were found, suggesting that the concept of PBI differs significantly from the concepts of job burnout, depression and stress, respectively. The current study confirms that some parents are extremely exhausted by their parental role. However, the number of Dutch employees reporting extreme parental burnout is rather low.

Validity of the Parental Burnout Inventory Among Dutch Employees

PubMed Central

Van Bakel, Hedwig J. A.; Van Engen, Marloes L.; Peters, Pascale

2018-01-01

The purpose of this study was to validate the Parental Burnout Inventory (PBI) in a Dutch sample of working parents. The Dutch version of the PBI and questionnaires about work were administered to 627 working parents, with at least one child living at home. We investigated whether the tri-dimensional structure of the PBI held in a sample of male and female employed parents. Furthermore, we examined the relationships between PBI and the constructs work-related burnout, depressive mood, parenting stress and work-family conflict, which we assessed with widely used and validated instruments, i.e., emotional exhaustion [a subscale of the Dutch version of Maslach’s Burnout Inventory], a Dutch Parental Stress Questionnaire and Work-Family Conflict. The results support the validity of a tri-dimensional parental burnout syndrome, including exhaustion, distancing and inefficacy. Low to moderate correlations between parents’ burnout symptoms and professional exhaustion, parenting stress, depressive complaints and work-family conflict experiences were found, suggesting that the concept of PBI differs significantly from the concepts of job burnout, depression and stress, respectively. The current study confirms that some parents are extremely exhausted by their parental role. However, the number of Dutch employees reporting extreme parental burnout is rather low. PMID:29875711

Dealing with Organizational Double Binds: Three-way Interactive Effects of Role Stressors and Coping on Worker Exhaustion.

PubMed

Hornung, Severin; Lampert, Bettina; Glaser, Jürgen

2016-04-01

Based on theory regarding the dynamics of organizational double binds, hypotheses were developed about interactive effects of role conflict, role ambiguity, and coping on psychological exhaustion. Hypotheses were tested in a sample of 948 civil servants employed by a government administration in Germany. The sample included 250 (26.4%) women (M age = 43.6 year, SD = 8.3) and average organizational tenure was 17.1 year (SD = 10.0). Moderated multiple regression supported the two hypothesized three-way interactions. Under conditions of high role conflict and high role ambiguity, exhaustion was lower in workers reporting high control coping than in workers reporting low control coping. Under conditions of high role conflict and high role ambiguity, worker exhaustion was more pronounced when support coping was high than when it was low. Problem-focused control coping seems crucial to maintain mental health in dealing with contradictory and unclear work role expectations. Emotion-focused support coping appears symptomatic of prolonged involvement in psychologically dysfunctional work situations that cannot otherwise be addressed. Implications are discussed in the context of growing awareness of the contradictory demands organizations impose on employees. © The Author(s) 2016.

Effects of the biodiesel blend fuel on aldehyde emissions from diesel engine exhaust

NASA Astrophysics Data System (ADS)

Peng, Chiung-Yu; Yang, Hsi-Hsien; Lan, Cheng-Hang; Chien, Shu-Mei

Interest in use of biodiesel fuels derived from vegetable oils or animal fats as alternative fuels for petroleum-based diesels has increased due to biodiesels having similar properties of those of diesels, and characteristics of renewability, biodegradability and potential beneficial effects on exhaust emissions. Generally, exhaust emissions of regulated pollutants are widely studied and the results favor biodiesels on CO, HC and particulate emissions; however, limited and inconsistent data are showed for unregulated pollutants, such as carbonyl compounds, which are also important indicators for evaluating available vehicle fuels. For better understanding biodiesel, this study examines the effects of the biodiesel blend fuel on aldehyde chemical emissions from diesel engine exhausts in comparison with those from the diesel fuel. Test engines (Mitsubishi 4M40-2AT1) with four cylinders, a total displacement of 2.84 L, maximum horsepower of 80.9 kW at 3700 rpm, and maximum torque of 217.6 N m at 2000 rpm, were mounted and operated on a Schenck DyNAS 335 dynamometer. Exhaust emission tests were performed several times for each fuel under the US transient cycle protocol from mileages of 0-80,000 km with an interval of 20,000 km, and two additional measurements were carried out at 40,000 and 80,000 km after maintenance, respectively. Aldehyde samples were collected from diluted exhaust by using a constant volume sampling system. Samples were extracted and analyzed by the HPLC/UV system. Dominant aldehydes of both fuels' exhausts are formaldehyde and acetaldehyde. These compounds together account for over 75% of total aldehyde emissions. Total aldehyde emissions for B20 (20% waste cooking oil biodiesel and 80% diesel) and diesel fuels are in the ranges of 15.4-26.9 mg bhp-h -1 and 21.3-28.6 mg bhp-h -1, respectively. The effects of increasing mileages and maintenance practice on aldehyde emissions are insignificant for both fuels. B20 generates slightly less emission than diesel does. Major difference in both fuels is formaldehyde emission which drops by 23% on the average. Lower aldehyde emissions found in B20 correspond to lower ozone formation potentials. As a result, use of biodiesel in diesel engines has the beneficial effect in terms of aldehyde emissions.

Effect of Perceived Politics and Perceived Support on Bullying and Emotional Exhaustion: The Moderating Role of Type A Personality.

PubMed

Naseer, Saima; Raja, Usman; Donia, Magda Bezerra Leite

2016-07-03

Recognizing that bullying can occur in varying degrees of severity, the current study suggest the importance of individual traits in individual perceptions of being targets of bullying and ensuing emotional exhaustion. The present study extends the work environment hypothesis and trait activation theory by a joint investigation of the mediating role of (a) workplace bullying in linking perceived organization politics and perceived organization support with emotional exhaustion and (b) the moderating role of Type A behavioral pattern in influencing the mediation. Using a field sample of 262 employees working in different organizations of Pakistan, this study tested a moderated mediation model. Results were consistent with the hypothesized model, in that workplace bullying mediated the relationship of perceived organization politics and perceived organization support with emotional exhaustion. Type A behavior moderated the perceived politics-bullying, perceived support-bullying, and bullying-emotional exhaustion relationships. The mediation of bullying varied with levels of Type A behavior in these relationships.

Estimation of the diesel exhaust exposures of railroad workers: I. Current exposures.

PubMed

Woskie, S R; Smith, T J; Hammond, S K; Schenker, M B; Garshick, E; Speizer, F E

1988-01-01

As a part of a series of epidemiological studies of railroad workers, measurements were made to characterize workers' exposures to diesel exhaust. Since diesel exhaust is not a single compound, an exposure marker was sought. The personal exposures to respirable particulate matter (RPM) of over 530 workers in 39 common jobs were measured in four U.S. railroads over a three-year period. Significant amounts of cigarette smoke (20-90%) were found in many of these samples. Therefore, the respirable particulate concentration, adjusted to remove the fraction of cigarette smoke (ARP), was chosen as a marker of diesel exhaust exposures. The geometric mean exposures to ARP ranged from 17 micrograms/m3 for clerks to 134 micrograms/m3 for locomotive shop workers. Significant interrailroad variations were observed in some job groups indicating that the different facilities, equipment, and work practices found among the railroads can affect a worker's exposure to diesel exhaust. Climate was also found to have a significant effect on exposure in some job groups.

Assessment of exhaustion and related risk factors in employees in the manufacturing industry--a cross-sectional study.

PubMed

Schnorpfeil, Pia; Noll, Alexander; Wirtz, Petra; Schulze, Renate; Ehlert, Ulrike; Frey, Karl; Fischer, Joachim E

2002-10-01

Vital exhaustion, a construct overlapping with burnout, is an independent risk factor for adverse health outcomes, including cardiovascular disease. We aimed to assess vital exhaustion in employees in the manufacturing industry and identify work characteristics associated with exhaustion. Cross-sectional study. A stratified, representative random sample of employees from a manufacturing plant for airplane parts and assemblies was invited ( n=647), of whom 537 employees (83% accrual) volunteered to participate. Scores obtained by the nine-item Shortened Maastricht Exhaustion Questionnaire were compared with the mental and physical summary scales of the SF-12 General Health Survey and to a list of 20 health complaints. Pathogenic and salutogenic work characteristics were assessed by the self-reported 52-item, 13-subscale SALSA questionnaire. Vital exhaustion correlated with the mental summary score of the SF-12 and the number of health complaints and was positively associated with age. Exhaustion was not associated with gender, position (socio-economic status) or being on a wage (paid per completed item up to a contracted amount) or salary (payment as fixed monthly income). The instrument identified departments with high levels of exhaustion. Of the observed variance in exhaustion, 29% was explained by age, department, and five work characteristics: High levels of exhaustion (score >10) were related to excessive workload or qualitative demands (scoring in the highest quartile; OR(adj) 7.5; 95% CI 2.4-23), to adverse physical work conditions (OR(adj) 6.9; 95% CI 2.2-21), to adverse co-worker behavior (OR(adj) 4.8; 95% CI 1.4-16), to qualification potential (OR(adj) 0.32; 95% CI 0.11-0.97), and to social support by co-workers (OR(adj) 0.34; 95% CI 0.13-0.99), respectively. The nine-item instrument allows rapid screening of employees for self-reported levels of exhaustion. Besides physical work conditions and workload, absence or presence of social support by co-workers is strongly associated with exhaustion.

Adsorption of hydrogen chloride on microcrystalline silica. [solid rocket propellant exhaust

NASA Technical Reports Server (NTRS)

Kang, Y.; Wightman, J. P.

1979-01-01

The interaction of hydrogen chloride with quartz was studied to determine the extent to which silica can irreversibly remove hydrogen chloride from the atmosphere. Adsorption isotherms were measured at 30 C for hydrogen chloride on silica outgassed between 100 C and 400 C. Readsorption isotherms were also measured. The silica surface was characterized further by infrared spectroscopy, electron spectroscopy for chemical analysis, scanning electron microscopy, and immersional calorimetry. Ground debris samples obtained from the Kennedy Space Center, were likewise examined.

A study of automobile exhaust noise preferences

NASA Astrophysics Data System (ADS)

Haire, Jay B.; Carney, Melinda J.; Cheenne, Dominique J.

2005-04-01

A study was conducted to investigate the relationship between preferences in automobile exhaust noise and the demographic factors of a listening jury. Noise samples of four different vehicles were recorded at idle as well as at 3000 RPM, and 1/3 octave sound spectra were acquired simultaneously. The recordings were presented to the jury using headphones and a preference survey was administered. Zwicker loudness was computed for all samples. Demographic factors such as gender, age, current and future vehicle ownership, were correlated to listening preferences, and unforeseen results were found, especially in regards to sport utility vehicles (SUV).

Headspace needle-trap analysis of priority volatile organic compounds from aqueous samples: application to the analysis of natural and waste waters.

PubMed

Alonso, Monica; Cerdan, Laura; Godayol, Anna; Anticó, Enriqueta; Sanchez, Juan M

2011-11-11

Combining headspace (HS) sampling with a needle-trap device (NTD) to determine priority volatile organic compounds (VOCs) in water samples results in improved sensitivity and efficiency when compared to conventional static HS sampling. A 22 gauge stainless steel, 51-mm needle packed with Tenax TA and Carboxen 1000 particles is used as the NTD. Three different HS-NTD sampling methodologies are evaluated and all give limits of detection for the target VOCs in the ng L⁻¹ range. Active (purge-and-trap) HS-NTD sampling is found to give the best sensitivity but requires exhaustive control of the sampling conditions. The use of the NTD to collect the headspace gas sample results in a combined adsorption/desorption mechanism. The testing of different temperatures for the HS thermostating reveals a greater desorption effect when the sample is allowed to diffuse, whether passively or actively, through the sorbent particles. The limits of detection obtained in the simplest sampling methodology, static HS-NTD (5 mL aqueous sample in 20 mL HS vials, thermostating at 50 °C for 30 min with agitation), are sufficiently low as to permit its application to the analysis of 18 priority VOCs in natural and waste waters. In all cases compounds were detected below regulated levels. Copyright © 2011 Elsevier B.V. All rights reserved.

Biomonitoring of polycyclic aromatic compounds in the urine of mining workers occupationally exposed to diesel exhaust.

PubMed

Seidel, Albrecht; Dahmann, Dirk; Krekeler, Horst; Jacob, Juergen

2002-02-01

Diesel exhaust is considered a probable human carcinogen by the IARC. Biomonitoring of workers occupationally exposed to diesel exhaust was performed to determine their internal burden of diesel associated aromatic compounds. Personal air sampling also allowed to determine the exposure of the miners at their work place towards several polycyclic aromatic hydrocarbons (PAH) and nitro-arenes, the latter of which are thought to be specific constituents of diesel exhaust. For biomonitoring the urine of 18 underground salt miners was collected during and after their shift for 24-hours. half of the 18 miners were smokers. The urinary levels of 1-hydroxypyrene and hydroxylated phenanthrene metabolites were determined as biomarkers of PAH exposure, whereas urinary levels of some aromatic amines were chosen to monitor exposure towards specific nitro-arenes from diesel exhaust like 1-nitropyrene and 3-nitrobenzanthrone and to monitor the human burden by these compounds from inhaled cigarette smoke. Non-smoking workers exposed to diesel exhaust excrete an average level of about 4 micrograms phenanthrene metabolites, whereas the urinary levels in smokers were up to 3-fold higher. In summary the results indicate that (i) diesel exposure led to an increase of PAH metabolism in the workers examined, most probably by an induction of cytochrome P450 (ii) smokers could be identified in accordance with earlier studies by their increased ratio of phenanthrene metabolites derived from 1,2- and 3,4-oxidation and their higher amounts of excreted 1-naphthylamine, and (iii) the excreted amounts of aromatic amines found as metabolites of the nitro-arenes were about 5- to 10-fold higher as one might expect from the levels determined by personal air sampling at the workplace of the individuals.

Analysis of the repeatability of the exhaust pollutants emission research results for cold and hot starts under controlled driving cycle conditions.

PubMed

Jaworski, Artur; Kuszewski, Hubert; Ustrzycki, Adam; Balawender, Krzysztof; Lejda, Kazimierz; Woś, Paweł

2018-04-20

Measurement of car engines exhaust pollutants emissions is very important because of their harmful effects on the environment. This article presents the assessment of repeatability of the passenger car engine exhaust pollutants emission research results obtained in the conditions of a chassis dynamometer. The research was conducted in a climate chamber, enabling the temperature conditions to be determined from - 20 to + 30 °C. The emission of CO, CH 4 , CO 2 , NO X , THC, and NMHC was subjected to the analysis. The aim of the research is to draw attention to the accuracy of the pollutant emission research results in driving cycles, and the comparison of pollutant emission results and their repeatability obtained in successive NEDC cycles under cold and hot start conditions. The results of the analysis show that, in the case of a small number of measurements, the results repeatability analysis is necessary for a proper interpretation of the pollutant emission results on the basis of the mean value. According to the authors' judgment, it is beneficial to determine the coefficient of variation for a more complete assessment of exhaust emission result repeatability obtained from a small number of measurements. This parameter is rarely presented by the authors of papers on exhaust components emission research.

The Lund University Checklist for Incipient Exhaustion-a cross-sectional comparison of a new instrument with similar contemporary tools.

PubMed

Persson, Roger; Österberg, Kai; Viborg, Njördur; Jönsson, Peter; Tenenbaum, Artur

2016-04-21

Stress-related health problems (e.g., work-related exhaustion) are a societal concern in many postindustrial countries. Experience suggests that early detection and intervention are crucial in preventing long-term negative consequences. In the present study, we benchmark a new tool for early identification of work-related exhaustion-the Lund University Checklist for Incipient Exhaustion (LUCIE)-against other contextually relevant inventories and two contemporary Swedish screening scales. A cross-sectional population sample (n = 1355) completed: LUCIE, Karolinska Exhaustion Disorder Scale (KEDS), Self-reported Exhaustion Disorder Scale (s-ED), Shirom-Melamed Burnout Questionnaire (SMBQ), Utrecht Work Engagement Scale (UWES-9), Job Content Questionnaire (JCQ), Big Five Inventory (BFI), and items concerning work-family interference and stress in private life. Increasing signs of exhaustion on LUCIE were positively associated with signs of exhaustion on KEDS and s-ED. The prevalence rates were 13.4, 13.8 and 7.8 %, respectively (3.8 % were identified by all three instruments). Increasing signs of exhaustion on LUCIE were also positively associated with reports of burnout, job demands, stress in private life, family-to-work interference and neuroticism as well as negatively associated with reports of job control, job support and work engagement. LUCIE, which is intended to detect pre-stages of ED, exhibits logical and coherent positive relations with KEDS and s-ED as well as other conceptually similar inventories. The results suggest that LUCIE has the potential to detect mild states of exhaustion (possibly representing pre-stages to ED) that if not brought to the attention of the healthcare system and treated, may develop in to ED. The prospective validity remains to be evaluated.

Diesel exhaust causing low-dose irritant asthma with latency?

PubMed

Adewole, Femi; Moore, Vicky C; Robertson, Alastair S; Burge, P S

2009-09-01

Diesel exhaust exposure may cause acute irritant-induced asthma and potentiate allergen-induced asthma. There are no previous reports of occupational asthma due to diesel exhaust. To describe occupational asthma with latency in workers exposed to diesel exhaust in bus garages. The Shield database of occupational asthma notifications in the West Midlands, UK, was searched between 1990 and 2006 for workers where diesel exhaust exposure was thought to be the cause of the occupational asthma. Those without other confounding exposures whose occupational asthma was validated by serial peak expiratory flow (PEF) analysis using Oasys software were included. Fifteen workers were identified with occupational asthma attributed to diesel exhaust. Three had validated new-onset asthma with latency. All worked in bus garages where diesel exhaust exposure was the only likely cause of their occupational asthma. Occupational asthma was confirmed by measures of non-specific reactivity and serial measurements of PEF with Oasys scores of 2.9, 3.73 and 4 (positive score > 2.5). The known non-specific irritant effects of diesel exhaust suggest that this is an example of low-dose irritant-induced asthma and that exposures to diesel exhaust in at least some bus garages are at a sufficient level to cause this.

40 CFR 600.208-77 - Sample calculation.

Code of Federal Regulations, 2010 CFR

2010-07-01

... ECONOMY AND CARBON-RELATED EXHAUST EMISSIONS OF MOTOR VEHICLES Fuel Economy Regulations for 1977 and Later Model Year Automobiles-Procedures for Calculating Fuel Economy Values § 600.208-77 Sample calculation...

Development of Imaging Fourier-Transform Spectroscopy for the Characterization of Turbulent Jet Flames

DTIC Science & Technology

2014-09-18

Spatially resolved infrared spectra of jet exhaust from an F109 turbofan engine...Appendix E contains a conference proceeding in its entirety [32]. This proceeding summarizes analysis of a turbofan engine exhaust via the Hyper-Cam and...demonstrated in a separate experiment. Recently, exhaust from an F109 turbofan engine was imaged with the IFTS[32]. Examination of the time-averaged

An examination of mobbing and burnout of residents.

PubMed

Dikmetaş, Elif; Top, Mehmet; Ergin, Gülpembe

2011-01-01

Mobbing and burnout in human resources management are important topics in labor psychology. It is important to research the levels of mobbing and burnout of human resources in the health sector, primarily in doctors. Although there have been some studies on the mobbing and burnout of doctors, there has been a limited number of studies on the relationship between mobbing and burnout in the health sector. This study aims to examine the relationship between mobbing and burnout (emotional exhaustion, depersonalization, personal accomplishment) levels of resident doctors at a public university research and training hospital in Turkey and to investigate whether mobbing and burnout levels vary significantly according to gender, marital status, medical branch and age. This study was conducted on resident doctors at the Ondokuz Mayıs University Research and Training Hospital between 01.04.2009 and 30.06.2009. Legal permission for the study was received from the Rector's Office of Ondokuz Mayıs University. The Maslach Burnout Inventory for measuring burnout levels in doctors and the Leymann Inventory of Psychological Terror for measuring doctors' mobbing levels were the research instruments employed. Sampling was not used in this study. The aim was to administer the research instruments to all the residents (the universe of this study consisted of 510 assistant doctors). 52.94 % of residents responded to all of the questions in these instruments. In the data analysis, a t-test, ANOVA, regression analysis and descriptive statistics were used. At the end of the analyses, it was found that the mean mobbing level of residents is 1.97; the mean emotional exhaustion level of residents is 2.97; the mean level of depersonalization is 2.95; and the mean level of personal accomplishment is 2.94. Mobbing and burnout levels of residents vary significantly in terms of medical branch. This study indicated that there are relationships between mobbing, emotional exhaustion, depersonalization and personal accomplishment. Mobbing is a significant regressor for emotional exhaustion, depersonalization and personal accomplishment in this study.

Experimental Analysis of Exhaust Manifold with Ceramic Coating for Reduction of Heat Dissipation

NASA Astrophysics Data System (ADS)

Saravanan, J.; Valarmathi, T. N.; Nathc, Rajdeep; Kumar, Prasanth

2017-05-01

Exhaust manifold plays an important role in the exhaust system, the manifold delivers the waste toxic gases to a safe distance and it is used to reduce the sound pollution and air pollution. Exhaust manifold suffers with lot of thermal stress, due to this blow holes occurs in the surface of the exhaust manifold and also more noise is developed. The waste toxic gases from the multiple cylinders are collected into a single pipe by the exhaust manifold. The waste toxic gases can damage the material of the manifold. In this study, to prevent the damage zirconia powder has been coated in the inner surface and alumina (60%) combined with titania (40%) has been used for coating the outer surface of the exhaust manifold. After coating experiments have been performed using a multiple-cylinder four stroke stationary petrol engine. The test results of hardness, emission, corrosion and temperature of the coated and uncoated manifolds have been compared. The result shows that the performance is improved and also emission is reduced in the coated exhaust manifold.

Scrutinizing the Expression and Blockade of Inhibitory Molecules Expressed on T Cells from Acute Myeloid Leukemia Patients.

PubMed

Abdolmaleki, Mohsen; Mojtabavi, Nazanin; Zavvar, Mahdi; Vaezi, Mohammad; Noorbakhsh, Farshid; Nicknam, Mohammad Hossein

2018-06-01

T cell exhaustion is an immunosuppressive mechanism which occurs in chronic viral infections, solid tumors and hematologic malignancies. Exhausted T cell has increased the expression of inhibitory receptors, and functional impairment. In this study, we investigated the expression from some of those inhibitory receptors being Programmed death 1 (PD-1), T cell immunoglobulin and mucin domain containing molecules 3 (TIM-3) and CD244 on T cells from Iranian acute myeloid leukemia (AML) patients. Peripheral blood samples were collected from Iranian newly diagnosed AML patients and flow cytometric analysis was accomplished for cell surface expression of PD-1, TIM-3, and CD244 on T lymphocytes. Functionality and proliferation assay were done in the presence of anti-PD-1 and anti-CD244 blocking antibodies. Immunophenotyping of T cells showed a significant increase of PD-1 and CD244 expression on CD4+ and CD8+ T cells of AML patients. Whereas blockade of PD1 and CD244 increased the proliferation of CD4+ and CD8+ T lymphocytes of AML patients but IFN-γ production was not significantly increased. In conclusion, our data indicate that CD4+ and CD8+ T cells from AML patients appeared to be exhausted and blockade of some immune checkpoints can improve the proliferation of those cells.

From Vitality to Vital Exhaustion and Other States of "Tense Tiredness": A New Biopsychosocial Risk Domain.

PubMed

Rozanski, Alan; Cohen, Randy

2017-04-01

Fatigue is a common prodromal symptom for various medical conditions, including acute myocardial infarction. Fatigue is also the core component of vital exhaustion, which consists of a specific triad: excessive fatigue, increased irritability, and feelings of demoralization. In this issue of Psychosomatic Medicine, Frestad and Prescott present a meta-analysis of 16 studies, involving 53,337 participants, which found vital exhaustion to be associated with an increased risk of incident coronary heart disease (CHD) and recurrent cardiac events among individuals with established CHD. After discussing methodological limitations of the studies included in this meta-analysis, we describe these findings in terms of a larger genre of risk that is biopsychosocial in origin and tied to two types of tiredness: "calm tiredness" and "tense tiredness." The former is regenerative, while the latter enhances disease risk. We propose that besides vital exhaustion, other symptoms of negative affect may combine with tiredness to produce increased clinical risk, such as the presence of depressed mood, an inability to relax or recover after work, and symptoms of burnout. We further propose that vital exhaustion can be considered as part of a larger paradigm, ranging from a positive state of vitality to a negative state of exhaustion of vitality. We conclude this editorial by emphasizing the importance of improving vitality and the need to clarify biobehavioral mechanisms that play a role in the association between vital exhaustion and adverse CHD outcomes. New interventions are needed that target reducing exhaustion and improving vitality for individuals at high risk of CHD.

Evaluation of an exposure assessment used in epidemiological studies of diesel exhaust and lung cancer in underground mines

PubMed Central

Crump, Kenny; Van Landingham, Cynthia

2012-01-01

NIOSH/NCI (National Institute of Occupational Safety and Health and National Cancer Institute) developed exposure estimates for respirable elemental carbon (REC) as a surrogate for exposure to diesel exhaust (DE) for different jobs in eight underground mines by year beginning in the 1940s—1960s when diesel equipment was first introduced into these mines. These estimates played a key role in subsequent epidemiological analyses of the potential relationship between exposure to DE and lung cancer conducted in these mines. We report here on a reanalysis of some of the data from this exposure assessment. Because samples of REC were limited primarily to 1998–2001, NIOSH/NCI used carbon monoxide (CO) as a surrogate for REC. In addition, because CO samples were limited, particularly in the earlier years, they used the ratio of diesel horsepower (HP) to the mine air exhaust rate as a surrogate for CO. There are considerable uncertainties connected with each of these surrogate-based steps. The estimates of HP appear to involve considerable uncertainty, although we had no data upon which to evaluate the magnitude of this uncertainty. A sizable percentage (45%) of the CO samples used in the HP to CO model was below the detection limit which required NIOSH/NCI to assign CO values to these samples. In their preferred REC estimates, NIOSH/NCI assumed a linear relation between C0 and REC, although they provided no credible support for that assumption. Their assumption of a stable relationship between HP and CO also is questionable, and our reanalysis found a statistically significant relationship in only one-half of the mines. We re-estimated yearly REC exposures mainly using NIOSH/NCI methods but with some important differences: (i) rather than simply assuming a linear relationship, we used data from the mines to estimate the CO—REC relationship; (ii) we used a different method for assigning values to nondetect CO measurements; and (iii) we took account of statistical uncertainty to estimate bounds for REC exposures. This exercise yielded significantly different exposure estimates than estimated by NIOSH/NCI. However, this analysis did not incorporate the full range of uncertainty in REC exposures because of additional uncertainties in the assumptions underlying the modeling and in the underlying data (e.g. HP and mine exhaust rates). Estimating historical exposures in a cohort is generally a very difficult undertaking. However, this should not prevent one from recognizing the uncertainty in the resulting estimates in any use made of them. PMID:22594934

40 CFR 89.424 - Dilute emission sampling calculations.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Dilute emission sampling calculations... Emission Test Procedures § 89.424 Dilute emission sampling calculations. (a) The final reported emission... concentration. For cases where exhaust sampling of CO2 is not performed, the following approximation is...

40 CFR 89.424 - Dilute emission sampling calculations.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Dilute emission sampling calculations... Emission Test Procedures § 89.424 Dilute emission sampling calculations. (a) The final reported emission... concentration. For cases where exhaust sampling of CO2 is not performed, the following approximation is...

[Job Demands-Resources, exhaustion and work engagement in a long-term care institution].

PubMed

Conway, P M; Neri, L; Campanini, P; Francioli, L; Camerino, D; Punzi, S; Fichera, G P; Costa, G

2012-01-01

In this study, we aimed at testing the main hypotheses of the Job Demands-Resources model (JD-R) in a sample of employees (n = 205, mainly healthcare workers) of a long-term care institution located in Northern Italy. Hierarchical linear regression analyses show that almost all job demands considered were significantly associated with higher general psycho-physical exhaustion (beta ranging from 0.14 to 0.29), whereas more unfavourable scores in all job resources were associated with lower work engagement (from -0.27 to -0.51). However, also significant cross-over associations were observed, mainly between job resources and exhaustion, with effect sizes comparable with those found for the relationships between job demands and exhaustion. Hence, our study only partially supports the JD-R model. Implications of results for work-related stress management are finally discussed.

Job Stressors, Emotional Exhaustion, and Need for Recovery: A Multi-Source Study on the Benefits of Psychological Detachment

ERIC Educational Resources Information Center

Sonnentag, Sabine; Kuttler, Iris; Fritz, Charlotte

2010-01-01

This paper examines psychological detachment (i.e., mentally "switching off") from work during non-work time as a partial mediator between job stressors and low work-home boundaries on the one hand and strain reactions (emotional exhaustion, need for recovery) on the other hand. Survey data were collected from a sample of protestant pastors (N =…

The Impact of Bundled High Performance Human Resource Practices on Intention to Leave: Mediating Role of Emotional Exhaustion

ERIC Educational Resources Information Center

Jyoti, Jeevan; Rani, Roomi; Gandotra, Rupali

2015-01-01

Purpose: The purpose of this paper is to examine the mediating effect of emotional exhaustion (EE) in between bundled high-performance human resource practices (HPHRPs) and intention to leave (ITL) in the education sector. Design/methodology/approach: A survey questionnaire method was used to collect data from a sample of 514 teachers working in…

Around Marshall

NASA Image and Video Library

1996-06-10

The dart and associated launching system was developed by engineers at MSFC to collect a sample of the aluminum oxide particles during the static fire testing of the Shuttle's solid rocket motor. The dart is launched through the exhaust and recovered post test. The particles are collected on sticky copper tapes affixed to a cylindrical shaft in the dart. A protective sleeve draws over the tape after the sample is collected to prevent contamination. The sample is analyzed under a scarning electron microscope under high magnification and a particle size distribution is determined. This size distribution is input into the analytical model to predict the radiative heating rates from the motor exhaust. Good prediction models are essential to optimizing the development of the thermal protection system for the Shuttle.

Rising to the challenge: Deep acting is more beneficial when tasks are appraised as challenging.

PubMed

Huang, Jason L; Chiaburu, Dan S; Zhang, Xin-an; Li, Ning; Grandey, Alicia A

2015-09-01

Cumulative research indicates that deep acting has a nonsignificant relationship with employee exhaustion, despite arguments that deep acting can be beneficial. To illuminate when deep acting leads to more positive employee outcomes, we draw on the resource conservation perspective to propose a within-individual model of deep acting that focuses on service employees' daily fluctuation of emotional labor and emotional exhaustion. Specifically, we propose that the ongoing experience of felt challenge is a within-person boundary condition that moderates deep acting's relationship with emotional exhaustion, and model emotional exhaustion as a mediating mechanism that subsequently predicts momentary job satisfaction and daily customer conflict handling. Using an experience sampling design, we collected data from 84 service employees over a 3-week period. Deep acting was less emotionally exhausting for service providers when they saw their tasks as more challenging. Furthermore, emotional exhaustion mediated the deep acting by felt challenge interaction effect on momentary job satisfaction and daily customer conflict handling. The findings contribute to a better understanding of the deep acting experience at work, while highlighting customer conflict handling as a key behavioral outcome of emotional labor. (c) 2015 APA, all rights reserved).

Passing the anaerobic threshold is associated with substantial changes in the gene expression profile in white blood cells.

PubMed

Sakharov, Dmitry A; Maltseva, Diana V; Riabenko, Evgeniy A; Shkurnikov, Maxim U; Northoff, Hinnak; Tonevitsky, Alexander G; Grigoriev, Anatoly I

2012-03-01

High and moderate intensity endurance exercise alters gene expression in human white blood cells (WBCs), but the understanding of how this effect occurs is limited. To increase our knowledge of the nature of this process, we investigated the effects of passing the anaerobic threshold (AnT) on the gene expression profile in WBCs of athletes. Nineteen highly trained skiers participated in a treadmill test with an incremental step protocol until exhaustion (ramp test to exhaustion, RTE). The average total time to exhaustion was 14:40 min and time after AnT was 4:50 min. Two weeks later, seven of these skiers participated in a moderate treadmill test (MT) at 80% peak O(2) uptake for 30 min, which was slightly below their AnTs. Blood samples were obtained before and immediately after both tests. RTE was associated with substantially greater leukocytosis and acidosis than MT. Gene expression in WBCs was measured using whole genome microarray expression analysis before and immediately after each test. A total of 310 upregulated genes were found after RTE, and 69 genes after MT of which 64 were identical to RTE. Both tests influenced a variety of known gene pathways related to inflammation, stress response, signal transduction and apoptosis. A large group of differentially expressed previously unknown small nucleolar RNA and small Cajal body RNA was found. In conclusion, a 15-min test to exhaustion was associated with substantially greater changes of gene expression than a 30-min test just below the AnT.

Work-family conflict and job burnout among correctional staff: a comment on Lambert and Hogan (2010)1.

PubMed

Smith, Kenneth J

2011-02-01

Lambert and Hogan (2010) examined the relations between work-family conflict, role stress, and other noted predictors, on reported emotional exhaustion among a sample of 272 correctional staff at a maximum security prison. Using an ordinary least squares (OLS) regression model, the authors found work-on-family conflict, perceived dangerousness of the job, and role strain to have positive relations with emotional exhaustion. However, contrary to expectation they found that custody officers reported lower exhaustion than did their noncustody staff counterparts. Suggestions are provided for follow-up efforts designed to extend this line of research and correct methodological issues.

Health hazard evaluation report heta 92-0160-2360, City of Lancaster, Division of Fire, Lancaster, Ohio

DOE Office of Scientific and Technical Information (OSTI.GOV)

Echt, A.; Blade, L.; Sheehy, J.

1993-10-01

In response to a request from the Division of Fire and the International Association of Firefighters Local 291, an evaluation was undertaken of exposure to diesel exhaust emissions in the engine houses of the City of Lancaster Division of Fire (SIC-9224) Lancaster, Ohio. At the time of the study, 77 uniformed employees and two secretaries worked in three engine houses. In Engine House 1, personal breathing zone (PBZ) samples ranged from 51.7 to 71.2 micrograms per cubic meter (microg/cu m) on the first night of sampling. PBZ samples in Engine House 2 ranged from 25.7 to 78.8 microg/cu m overmore » two nights of sampling. Results for Engine House 3 ranged from 24.0 to 60.5 microg/cu m. With the exception of one measurement of 4.6 parts per million (ppm) of carbon-monoxide (CO) measured in the smoking room of Engine House 2, only trace CO was detected. Benzene solubles measured in Engine House 2 ranged from less than the limit of detection to 313 microg/cu m. The authors conclude that exhaust emissions containing diesel particulate may present a potential risk to firefighters. The authors recommend the use of engineering controls and work practices to reduce diesel exhaust emission exposures.« less

A quantitative estimation of the exhaust, abrasion and resuspension components of particulate traffic emissions using electron microscopy

NASA Astrophysics Data System (ADS)

Weinbruch, Stephan; Worringen, Annette; Ebert, Martin; Scheuvens, Dirk; Kandler, Konrad; Pfeffer, Ulrich; Bruckmann, Peter

2014-12-01

The contribution of the three traffic-related components exhaust, abrasion, and resuspension to kerbside and urban background PM10 and PM1 levels was quantified based on the analysis of individual particles by scanning electron microscopy. A total of 160 samples was collected on 38 days between February and September 2009 at a kerbside and an urban background station in the urban/industrial Ruhr area (Germany). Based on size, morphology, chemical composition and stability under electron bombardment, the 111,003 particles studied in detail were classified into the following 14 particle classes: traffic/exhaust, traffic/abrasion, traffic/resuspension, carbonaceous/organic, industry/metallurgy, industry/power plants, secondary particles, (aged) sea salt, silicates, Ca sulfates, carbonates, Fe oxides/hydroxides, biological particles, and other particles. The traffic/exhaust component consists predominantly of externally mixed soot particles and soot internally mixed with secondary particles. The traffic/abrasion component contains all particles with characteristic tracer elements (Fe, Cu, Ba, Sb, Zn) for brake and tire abrasion. The traffic/resuspension component is defined by the mixing state and comprises all internally mixed particles with a high proportion of silicates or Fe oxides/hydroxides which contain soot or abrasion particles as minor constituent. In addition, silicates and Fe oxides/hydroxides internally mixed with chlorine and sulphur containing particles were also assigned to the traffic/resuspension component. The total contribution of traffic to PM10 was found to be 27% at the urban background station and 48% at the kerbside station, the corresponding values for PM1 are 15% and 39%. These values lie within the range reported in previous literature. The relative share of the different traffic components for PM10 at the kerbside station was 27% exhaust, 15% abrasion, and 58% resuspension (38%, 8%, 54% for PM1). For the urban background, the following relative shares were obtained for PM10: 22% exhaust, 22% abrasion and 56% resuspension (40%, 27%, 33% for PM1). Compared to previous publications we have observed a significantly lower portion of exhaust particles and a significantly higher portion of resuspension particles. The high abundance of resuspension particles underlines their significance for the observed adverse health effects of traffic emissions and for mitigation measures.

Dispersion of turbojet engine exhaust in flight

NASA Technical Reports Server (NTRS)

Holdeman, J. D.

1973-01-01

The dispersion of the exhaust of turbojet engines into the atmosphere is estimated by using a model developed for the mixing of a round jet with a parallel flow. The analysis is appropriate for determining the spread and dilution of the jet exhaust from the engine exit until it is entrained in the aircraft trailing vortices. Chemical reactions are not expected to be important and are not included in the flow model. Calculations of the dispersion of the exhaust plumes of three aircraft turbojet engines with and without afterburning at typical flight conditions are presented. Calculated average concentrations for the exhaust plume from a single engine jet fighter are shown to be in good agreement with measurements made in the aircraft wake during flight.

Determination of colloidal and dissolved silver in water samples using colorimetric solid-phase extraction.

PubMed

Hill, April A; Lipert, Robert J; Porter, Marc D

2010-03-15

The increase in bacterial resistance to antibiotics has led to resurgence in the use of silver as a biocidal agent in applications ranging from washing machine additives to the drinking water treatment system on the International Space Station (ISS). However, growing concerns about the possible toxicity of colloidal silver to bacteria, aquatic organisms and humans have led to recently issued regulations by the US EPA and FDA regarding the usage of silver. As part of an ongoing project, we have developed a rapid, simple method for determining total silver, both ionic (silver(I)) and colloidal, in 0.1-1mg/L aqueous samples, which spans the ISS potable water target of 0.3-0.5mg/L (total silver) and meets the US EPA limit of 0.1mg/L in drinking water. The method is based on colorimetric solid-phase extraction (C-SPE) and involves the extraction of silver(I) from water samples by passage through a solid-phase membrane impregnated with the colorimetric reagent DMABR (5-[4-(dimethylamino)benzylidene]rhodanine). Silver(I) exhaustively reacts with impregnated DMABR to form a colored compound, which is quantified using a handheld diffuse reflectance spectrophotometer. Total silver is determined by first passing the sample through a cartridge containing Oxone, which exhaustively oxidizes colloidal silver to dissolved silver(I). The method, which takes less than 2 min to complete and requires only approximately 1 mL of sample, has been validated through a series of tests, including a comparison with the ICP-MS analysis of a water sample from ISS that contained both silver(I) and colloidal silver. Potential earth-bound applications are also briefly discussed. Copyright (c) 2009 Elsevier B.V. All rights reserved.

40 CFR 1065.245 - Sample flow meter for batch sampling.

Code of Federal Regulations, 2010 CFR

2010-07-01

... rates or total flow sampled into a batch sampling system over a test interval. You may use the... rates or total raw exhaust flow over a test interval. (b) Component requirements. We recommend that you... averaging Pitot tube, or a hot-wire anemometer. Note that your overall system for measuring sample flow must...

Spectral fingerprinting of polycyclic aromatic hydrocarbons in high-volume ambient air samples by constant energy synchronous luminescence spectroscopy

USGS Publications Warehouse

Kerkhoff, M.J.; Lee, T.M.; Allen, E.R.; Lundgren, D.A.; Winefordner, J.D.

1985-01-01

A high-volume sampler fitted with a glass-fiber filter and backed by polyurethane foam (PUF) was employed to collect airborne particulate and gas-phase polycylic aromatic hydrocarbons (PAHs) in ambient air. Samples were collected from four sources representing a range of environmental conditions: gasoline engine exhaust, diesel engine exhaust, air near a heavily traveled interstate site, and air from a moderately polluted urban site. Spectral fingerprints of the unseparated particulate and gas-phase samples were obtained by constant energy synchronous luminescence spectroscopy (CESLS). Five major PAHs in the gas-phase extracts were characterized and estimated. The compatibility of a high-volume sampling method using polyurethane foam coupled with CESLS detection is explored for use as a screening technique for PAHs in ambient air. ?? 1985 American Chemical Society.

40 CFR 86.537-90 - Dynamometer test runs.

Code of Federal Regulations, 2010 CFR

2010-07-01

... phase of the test. Obtain methanol and formaldehyde sample analyses, if applicable, within 24 hours of... minutes of the end of the sample collection phase of the test. Obtain methanol and formaldehyde sample... the dilute exhaust and dilution air sample collection systems. (4) For methanol-fueled vehicles, with...

40 CFR 86.537-90 - Dynamometer test runs.

Code of Federal Regulations, 2011 CFR

2011-07-01

... phase of the test. Obtain methanol and formaldehyde sample analyses, if applicable, within 24 hours of... minutes of the end of the sample collection phase of the test. Obtain methanol and formaldehyde sample... the dilute exhaust and dilution air sample collection systems. (4) For methanol-fueled vehicles, with...

Computational models for the analysis of three-dimensional internal and exhaust plume flowfields

NASA Technical Reports Server (NTRS)

Dash, S. M.; Delguidice, P. D.

1977-01-01

This paper describes computational procedures developed for the analysis of three-dimensional supersonic ducted flows and multinozzle exhaust plume flowfields. The models/codes embodying these procedures cater to a broad spectrum of geometric situations via the use of multiple reference plane grid networks in several coordinate systems. Shock capturing techniques are employed to trace the propagation and interaction of multiple shock surfaces while the plume interface, separating the exhaust and external flows, and the plume external shock are discretely analyzed. The computational grid within the reference planes follows the trace of streamlines to facilitate the incorporation of finite-rate chemistry and viscous computational capabilities. Exhaust gas properties consist of combustion products in chemical equilibrium. The computational accuracy of the models/codes is assessed via comparisons with exact solutions, results of other codes and experimental data. Results are presented for the flows in two-dimensional convergent and divergent ducts, expansive and compressive corner flows, flow in a rectangular nozzle and the plume flowfields for exhausts issuing out of single and multiple rectangular nozzles.

40 CFR 86.109-94 - Exhaust gas sampling system; Otto-cycle vehicles not requiring particulate emission measurements.

Code of Federal Regulations, 2013 CFR

2013-07-01

... detection for the HPLC analyzer. Sampling systems for all phases shall be identical. (iii) The methanol and... detection for the HPLC analyzer. Sampling systems for all phases shall be identical. (iii) The methanol and...

40 CFR 86.109-94 - Exhaust gas sampling system; Otto-cycle vehicles not requiring particulate emission measurements.

Code of Federal Regulations, 2012 CFR

2012-07-01

... detection for the HPLC analyzer. Sampling systems for all phases shall be identical. (iii) The methanol and... detection for the HPLC analyzer. Sampling systems for all phases shall be identical. (iii) The methanol and...

40 CFR 86.109-94 - Exhaust gas sampling system; Otto-cycle vehicles not requiring particulate emission measurements.

Code of Federal Regulations, 2014 CFR

2014-07-01

... detection for the HPLC analyzer. Sampling systems for all phases shall be identical. (iii) The methanol and... detection for the HPLC analyzer. Sampling systems for all phases shall be identical. (iii) The methanol and...

Simulation of Wake Vortex Radiometric Detection via Jet Exhaust Proxy

NASA Technical Reports Server (NTRS)

Daniels, Taumi S.

2015-01-01

This paper describes an analysis of the potential of an airborne hyperspectral imaging IR instrument to infer wake vortices via turbine jet exhaust as a proxy. The goal was to determine the requirements for an imaging spectrometer or radiometer to effectively detect the exhaust plume, and by inference, the location of the wake vortices. The effort examines the gas spectroscopy of the various major constituents of turbine jet exhaust and their contributions to the modeled detectable radiance. Initially, a theoretical analysis of wake vortex proxy detection by thermal radiation was realized in a series of simulations. The first stage used the SLAB plume model to simulate turbine jet exhaust plume characteristics, including exhaust gas transport dynamics and concentrations. The second stage used these plume characteristics as input to the Line By Line Radiative Transfer Model (LBLRTM) to simulate responses from both an imaging IR hyperspectral spectrometer or radiometer. These numerical simulations generated thermal imagery that was compared with previously reported wake vortex temperature data. This research is a continuation of an effort to specify the requirements for an imaging IR spectrometer or radiometer to make wake vortex measurements. Results of the two-stage simulation will be reported, including instrument specifications for wake vortex thermal detection. These results will be compared with previously reported results for IR imaging spectrometer performance.

Work stress and emotional exhaustion in nurses: the mediating role of internal locus of control.

PubMed

Partlak Günüşen, Neslihan; Ustün, Besti; Erdem, Sabri

2014-01-01

Burnout is a major problem for nursing. There is a strong relationship between work stress and emotional exhaustion. Although studies report a negative correlation between the internal locus of control and emotional exhaustion and work stress, the number of studies available on the subject is limited. This study intends to examine the extent to which the relationship between work stress and emotional exhaustion is mediated by nurses' internal locus of control. The study adopted a cross-sectional survey design. The data were analyzed using structural equation modeling techniques. The study sample consisted of 347 nurses who worked in a university hospital in Izmir, Turkey and who agreed to participate in the study. The Work-Related Strain Inventory was used to evaluate the nurses' work stress level, Maslach Burnout Inventory was used to evaluate their emotional exhaustion levels, and the Locus of Control Scale was used to evaluate the internal locus of control. The variables of the study were based on the Neuman Systems Model. Work stress was positively related to internal locus of control (β3 = .21, p < .001), which was, in turn, negatively associated with emotional exhaustion (β = -.03, p > 0.1). Internal locus of control was negatively related to emotional exhaustion (β = -.14, p < .001). Work stress is directly (β = .87, p < .001) and indirectly related to emotional exhaustion (mediated by internal locus of control β = .84, p < .001). Work stress is directly (β = .87, p < .001) and indirectly related to emotional exhaustion (mediated by internal locus of control, β = .84, p < .001). Although the relationship between emotional exhaustion and work stress was mediated, the impact of internal locus of control was limited. It is recommended that different variables be included in future studies so that they can mediate the relationship between work stress and emotional exhaustion.

40 CFR 89.419 - Dilute gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) Continuous HC measurement system. (i) The continuous HC sample system (as shown in Figure 2 or 3 in appendix... this is not required. (ii) No other analyzers may draw a sample from the continuous HC sample probe... continuous HC sampling system shall consist of a probe (which must raise the sample to the specified...

Immunological biomarkers in salt miners exposed to salt dust, diesel exhaust and nitrogen oxides.

PubMed

Backé, Eva; Lotz, Gabriele; Tittelbach, Ulrike; Plitzko, Sabine; Gierke, Erhardt; Schneider, Wolfram Dietmar

2004-06-01

Air pollutants can affect lung function and also the immune system. In a study about lung function of salt miners in relation to the complex exposure in a salt mine, we also analysed selected immunological parameters and inflammation markers in the blood of miners. Effect of salt dust, diesel exhaust, nitrogen oxides (NOx) and smoking on the biomarkers was analysed. Blood was drawn from 286 salt miners, and the soluble intercellular adhesion molecule-1 (s-ICAM), monocyte chemotactic protein (MCP-1) and clara cell protein (CC16) were analysed by an immunoassay, blood profile was done and lymphocyte subpopulations (CD3, CD3/CD4, CD3/CD8, CD19, NK-cells, CD3/HLA-DR) were determined by flow cytometry. Salt dust was measured by two-step gravimetry (personal sampling). Diesel exhaust was measured as elemental carbon concentration by coulometry. NOx were determined by an electrochemical cell method. Differences between non-smokers, former smokers and active smokers were analysed by analysis of variance. Linear regression analysis to describe exposure-response relationships was done with regard to confounding factors [smoking, inflammatory diseases, time of blood drawing, respiratory infection and body-mass index (BMI)]. Significant differences between non-smokers and active smokers were found for most of the leukocyte types (e.g. granulocytes P = 0.000, lymphocytes P = 0.002, T-cells P = 0.033) and for some soluble parameters (ICAM P = 0.000, IgM P = 0.007, IgE P = 0.035). Increasing numbers of total lymphocytes, T-cells and HLA-DR positive T-cells in relation to exposure were found by linear regression analysis (e.g. for inhalable dust:total lymphocytes P = 0.011, T-cells P = 0.061, HLA-DR positive T-cells P = 0.007). CONCLUSION. Comparison of immunological markers in non-smokers and active smokers confirms leukocytosis and inflammation following tobacco consumption. The combined exposure of salt dust, diesel exhaust and NOx seems to influence the immune system. Together, the results suggest that the analysis of leukocytes and their subsets can complete other investigations (lung function, questionnaire) to monitor exposure-response relationships in occupational studies investigating the effect of inhaled substances. Longitudinal studies will be necessary to determine the predictive value of the immunological changes. Copyright 2004 Springer-Verlag

Emergency room nurses' pathway to turnover intention: a moderated serial mediation analysis.

PubMed

Bruyneel, Luk; Thoelen, Tom; Adriaenssens, Jef; Sermeus, Walter

2017-04-01

The aim of this study was to explore the association between the quality of the work environment, job characteristics, demographic characteristics and a pathway of job satisfaction, emotional exhaustion and turnover intention among nurses in emergency departments and perform subgroup analyses. Turnover intention among nurses is high. Multiple causes have been described, mostly in large studies of nurses working on general wards, often without considering complementarity of conceptual models and showing scant interest in the consistency of associations across subgroups of nurses. Cross-sectional multicentre survey. Convenience sample of 294 nurses in 11 Belgian emergency departments during 2014-2015. Indirect effects in the form of mediation and serial mediation were estimated to assess the association between work environment (Magnet model), job characteristics (Job Demand Control Support model) and turnover intention via job satisfaction and emotional exhaustion. Consistency of these indirect effects across subgroups of nurses was examined using moderated mediation analysis (conditional indirect effects). Several Magnet and Job Demand Control Support dimensions were related to turnover intention, either via job dissatisfaction (mediation) or via job satisfaction and emotional exhaustion (serial mediation). In the case of social support from supervisor, these indirect effects were only significant for female nurses, among whom turnover intention was higher. Last, nurses with more years of experience were less likely to indicate turnover intention. To maximize prevention of turnover intention at emergency departments, interventions could target early career nurses, work environment and job characteristics. Female nurses in particular may also benefit from improved social support from their supervisor. © 2016 John Wiley & Sons Ltd.

Identification and Mitigation of Generated Solid By-Products during Advanced Electrode Materials Processing

DOE PAGES

Tsai, Candace S. J.; Dysart, Arthur D.; Beltz, Jay H.; ...

2015-12-30

A scalable, solid-state elevated temperature process was developed to produce high capacity carbonaceous electrode materials for energy storage devices via decomposition of starch-based precursor in an inert atmosphere. The fabricated carbon-based architectures are useful as an excellent electrode material for lithium-ion, sodium-ion and lithium-sulfur batteries. This article focuses on the study and analysis of the formed nanometer-sized byproducts during the lab-scale production of carbonaceous electrode materials in the process design phase. The complete material production process was studied by operation, namely during heating, holding the reaction at elevated temperature, followed by cooling. The unknown downstream particles in the process exhaustmore » were collected and characterized via aerosol and liquid suspensions, and they were quantified using direct-reading instruments for number and mass concentrations. The airborne emissions were collected on polycarbonate filters and TEM grids using the Tsai diffusion sampler (TDS) for characterization and further analysis. Released byproduct aerosols collected in a deionized (DI) water trap were analyzed using a Nanosight real time nanoparticle characterization system and the aerosols emitted post water suspension were collected and characterized. Individual particles in the nanometer size range were found in exhaust aerosols, however, crystal structured aggregates were formed on the sampling substrate after a long-term sampling of emitted exhaust. After characterizing the released aerosol byproducts, methods were also identified to mitigate possible human and environmental exposures upon the industrial implementation of such a process.« less

Thermodynamic and chemical parameters of the exhaust effluents from the HARPOON booster motor

NASA Technical Reports Server (NTRS)

Stephens, J. B.; Goldford, A. I.

1978-01-01

The exhaust products from the Harpoon booster motors were analyzed using both thermodynamic analysis and finite-rate chemistry. The resulting constituents are presented together with a discussion of the techniques employed.

40 CFR 89.413 - Raw sampling procedures.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) The gaseous emission sampling probe must be installed at least 0.5 m or 3 times the diameter of the... multi-cylinder engine with a branched exhaust manifold, the inlet of the probe shall be located...

Prevalence of burnout in paediatric nurses: A systematic review and meta-analysis

PubMed Central

Pradas-Hernández, Laura; Gómez-Urquiza, José Luis; Albendín-García, Luis; De la Fuente, Emilia I.; Cañadas-De la Fuente, Guillermo A.

2018-01-01

Introduction Although burnout in paediatric nurses has been addressed in previous research, the heterogeneous nature of the results obtained and of the variables studied highlights the need for a detailed analysis of the literature. Objective The aim of this study was to analyse the literature on burnout characteristics, reported prevalence, severity and risk factors, to achieve a better understanding of the risk of emotional exhaustion, depersonalisation and feelings of low personal accomplishment. Method For this purpose, we carried out a systematic review and meta-analysis of the literature. The databases consulted were CINAHL, LILACS, PubMed, the Proquest Platform (Proquest Health & Medical Complete), Scielo and Scopus. This study used the search equation “burnout AND “pediatric nurs*””, and was conducted in July 2017. Results The search produced 34 studies targeting burnout in paediatric nurses, with no restrictions on the date of publication. Many of these studies detected moderate-high values for the three dimensions of burnout, and highlighted sociodemographic, psychological and job-related variables associated with this syndrome. The sample population for the meta-analysis was composed of 1600 paediatric nurses. The following prevalence values were obtained: (i) emotional exhaustion, 31% (95% CI: 25–37%); (ii) depersonalisation, 21% (95% CI: 11–33%); (iii) low personal accomplishment, 39% (95% CI: 28–50%). Conclusions A significant number of paediatric nurses were found to have moderate-high levels of emotional exhaustion and depersonalisation, and low levels of personal accomplishment. These nurses, therefore, were either experiencing burnout or at high risk of suffering it in the future. These results support the need for further study of the risk factors for burnout in paediatric nurses. They also highlight the importance of developing interventions or therapies to help prevent or attenuate the above symptoms, thus helping nurses cope with the workplace environment and with situations that may lead to burnout. PMID:29694375

Recovery of Waste Heat from Propellant Forced-Air Dry House

DTIC Science & Technology

1978-12-01

function of bulk air side film heat transfer coefficient and diffusivity 66 15. Dry house waste heat recovery system instrumentation 67 16. Sample data...inlet condition by, maintaining the exhaust temperature above the NG dew point. The set point is adjustable to accommodate various propel- lant and...system. In dry cycle operation, an overall energy recovery effectiveness of about 40% was measured for winter operation when the exhaust temperature

Entrepreneurial stressors as predictors of entrepreneurial burnout.

PubMed

Wei, Xueyan; Cang, Shuangxin; Hisrich, Robert D

2015-02-01

Research on the effects of entrepreneurial stressors is limited, especially regarding its relation to the burnout that frequently occurs in the process of starting and growing a venture. The effect of the role of entrepreneurial stressors (workload, competitive comparison, demands-of-knowledge, managing responsibility, and resource requirements) on burnout (emotional exhaustion, depersonalization, and reduced personal accomplishment) was examined in a Chinese sample of entrepreneurs. Entrepreneurial stressors emerged as a significant predictor of burnout in the process of entrepreneurship in a sample of 289 entrepreneurs (63.8% men; M age = 26.2 yr.; 39.6% of their parents have been self-employed). The findings clarify the functional relationship between entrepreneurial stressors and burnout. Entrepreneurial stressors played multiple roles. Managing responsibility was an active contributor to the sense of achievement and to emotional exhaustion. Workload was an active contributor to emotional exhaustion. Demands-of-knowledge negatively affected three of the dimensions of burnout. Theoretical and practical implications for management of the effect of these relationships are discussed.

Digital implementation of the TF30-P-3 turbofan engine control

NASA Technical Reports Server (NTRS)

Cwynar, D. S.; Batterton, P. G.

1975-01-01

The standard hydromechanical control modes for TF30-P-3 engine were implemented on a digital process control computer. Programming methods are described, and a method is presented to solve stability problems associated with fast response dynamic loops contained within the exhaust nozzle control. A modification of the exhaust nozzle control to provide for either velocity or position servoactuation systems is discussed. Transient response of the digital control was evaluated by tests on a real time hybrid simulation of the TF30-P-3 engine. It is shown that the deadtime produced by the calculation time delay between sampling and final output is more significant to transient response than the effects associated with sampling rate alone. For the main fuel control, extended update and calculation times resulted in a lengthened transient response to throttle bursts from idle to intermediate with an increase in high pressure compressor stall margin. Extremely long update intervals of 250 msec could be achieved without instability. Update extension for the exhaust nozzle control resulted in a delayed response of the afterburner light-off detector and exhaust nozzle overshoot with resulting fan oversuppression. Long update times of 150 msec caused failure of the control due to a false indication by the blowout detector.

Muscle damage, hydration, electrolyte balance and vasopressin concentrations in successful and exhausted endurance horses.

PubMed

Muñoz, A; Riber, C; Trigo, P; Castejón, F

2010-01-01

Arginine vasopressin (AVP) is released in response to depletion of the effective circulating blood volume. Endurance horses might develop exhaustion because loss of water and electrolytes in sweat with hypovolaemia and electrolytes abnormalities. Therefore, AVP should act in the control of volemia in these animals. This research evaluates the differences in AVP, hydration, electrolyte status and serum muscle enzymes in successful endurance horses in comparison with those eliminated from the competition because of exhaustion. Eighteen endurance horses, divided into two groups, successful (n = 13) and eliminated at the vet-gates because of exhaustion, dehydration and/or lack of recovery of heart rate (n = 5), were studied during a competition of 76.2 km. Jugular venous blood samples were collected before the event (BF), and at the vet-gates, at 30 km (PH1), 53.6 km (PH2) and at the end (PH3). Endurance exercise in successful horses induced significant increases from BF in Na at PH1, in Mg, CK, LDH at PH2 and microhaematocrit (MHT), total serum proteins (TSP), albumin (ALB), creatinine (CREAT) and lactate (LA) at PH3, together with a decreased in Cl at PH2 and Ca at PH3. Exhausted horses had higher MHT, Na, Ca, TSP, CREAT, LA, and AVP than successful at PH2 and PH3, whereas Cl was lower in exhausted horses. Velocity during the ride was higher in the exhausted group. These results indicate that exhausted endurance horses have laboratorial findings corresponding with a deeper dehydration and increased release of AVP. Therefore, this parameter could be used as a biomarker of early exhaustion and hypovolaemia. Additionally, AVP does not appear to be affected by exercise velocity or covered distance in successful horses.

Emotional exhaustion and defense mechanisms in intensive therapy unit nurses.

PubMed

Regan, Anna; Howard, Ruth A; Oyebode, Jan R

2009-05-01

Contrary to its original conceptualization, research has found that emotional demands do not lead to burnout in nurses. According to psychoanalytic theory, unconscious defense mechanisms may protect nurses from conscious awareness of work-related anxiety. This prevents self-report and may explain research findings. The maturity of defense style influences how anxiety is managed. Immature defenses prevent the conscious processing necessary for resolution of anxiety. Therefore, it is hypothesized that the use of immature defenses will lead to emotional exhaustion. This cross-sectional study used questionnaires to explore the defense mechanisms of 87 Intensive Therapy Unit nurses. Although the sample endorsed a predominantly mature defense style, the use of immature defenses predicted emotional exhaustion. Also, lower levels of reported stress associated with emotional demands predicted emotional exhaustion. Although this strongly implies the mediating role of immature defense mechanisms, the results were not statistically significant.

Validated method for the analysis of goji berry, a rich source of zeaxanthin dipalmitate.

PubMed

Karioti, Anastasia; Bergonzi, Maria Camilla; Vincieri, Franco F; Bilia, Anna Rita

2014-12-31

In the present study an HPLC-DAD method was developed for the determination of the main carotenoid, zeaxanthin dipalmitate, in the fruits of Lycium barbarum. The aim was to develop and optimize an extraction protocol to allow fast, exhaustive, and repeatable extraction, suitable for labile carotenoid content. Use of liquid N2 allowed the grinding of the fruit. A step of ultrasonication with water removed efficiently the polysaccharides and enabled the exhaustive extraction of carotenoids by hexane/acetone 50:50. The assay was fast and simple and permitted the quality control of a large number of commercial samples including fruits, juices, and a jam. The HPLC method was validated according to ICH guidelines and satisfied the requirements. Finally, the overall method was validated for precision (% RSD ranging between 3.81 and 4.13) and accuracy at three concentration levels. The recovery was between 94 and 107% with RSD values <2%, within the acceptable limits, especially if the difficulty of the matrix is taken into consideration.

Global measurements of gaseous and aerosol trace species in the upper troposphere and lower stratosphere from daily flights of 747 airliners

NASA Technical Reports Server (NTRS)

Perkins, P. J.

1976-01-01

A description is given of the NASA Global Atmospheric Sampling Program (GASP), taking into account the onboard system which collects atmospheric data automatically, the extensive atmospheric measurement capability, and the data handling and distribution procedure. GASP was implemented to assess the environmental impact of aircraft exhaust emissions in the upper troposphere and lower stratosphere. Global air quality data are to be obtained for a period of five to ten years. Measurements of pollutants not related to aircraft exhaust emissions, such as chlorofluoromethanes, are now included. GASP systems are operating on a United Airlines 747, two Pan Am 747s, and a Qantas Airways of Australia 747. Real-time, in-situ measurements are conducted of ozone, water vapor, carbon monoxide, and oxides of nitrogen. Chlorofluoromethanes are measured by laboratory analysis. Typical GASP data show significant changes in ozone, carbon monoxide, and water vapor related to crossings of the tropopause.

Work-life balance culture, work-home interaction, and emotional exhaustion: a structural equation modeling approach.

PubMed

Nitzsche, Anika; Pfaff, Holger; Jung, Julia; Driller, Elke

2013-01-01

To examine the relationships among employees' emotional exhaustion, positive and negative work-home interaction, and perceived work-life balance culture in companies. Data for this study were collected through online surveys of employees from companies in the micro- and nanotechnology sectors (N = 509). A structural equation modeling analysis was performed. A company culture perceived by employees as supportive of their work-life balance was found to have both a direct negative effect on emotional exhaustion and an indirect negative effect meditated by negative work-home interaction. In addition, whereas negative work-home interaction associated positively with emotional exhaustion, positive work-home interaction had no significant effect. The direct and indirect relationship between work-life balance culture and emotional exhaustion has practical implications for health promotion in companies.

Exhaust Plume Effects on Sonic Boom for a Delta Wing and a Swept Wing-Body Model

NASA Technical Reports Server (NTRS)

Castner, Raymond; Lake, Troy

2012-01-01

Supersonic travel is not allowed over populated areas due to the disturbance caused by the sonic boom. Research has been performed on sonic boom reduction and has included the contribution of the exhaust nozzle plume. Plume effect on sonic boom has progressed from the study of isolated nozzles to a study with four exhaust plumes integrated with a wing-body vehicle. This report provides a baseline analysis of the generic wing-body vehicle to demonstrate the effect of the nozzle exhaust on the near-field pressure profile. Reductions occurred in the peak-to-peak magnitude of the pressure profile for a swept wing-body vehicle. The exhaust plumes also had a favorable effect as the nozzles were moved outward along the wing-span.

Too drained to help: a resource depletion perspective on daily interpersonal citizenship behaviors.

PubMed

Trougakos, John P; Beal, Daniel J; Cheng, Bonnie Hayden; Hideg, Ivona; Zweig, David

2015-01-01

This article explores the role of within-person fluctuations in employees' daily surface acting and subsequent personal energy resources in the performance of organizational citizenship behaviors directed toward other individuals in the workplace (OCBI). Drawing on ego depletion theory (Muraven & Baumeister, 2000), we develop a resource-based model in which surface acting is negatively associated with daily OCBIs through the depletion of resources manifested in end-of-day exhaustion. Further integrating ego depletion theory, we consider the role of employees' baseline personal resource pool, as indicated by chronic exhaustion, as a critical between-person moderator of these within-person relationships. Using an experience-sampling methodology to test this model, we found that surface acting was indirectly related to coworker ratings of OCBI through the experience of exhaustion. We further found that chronic levels of exhaustion exacerbated the influence of surface acting on employees' end-of-day exhaustion. These findings demonstrate the importance of employees' regulatory resource pool for combating depletion and maintaining important work behaviors. Implications for theory and practice are discussed. (c) 2015 APA, all rights reserved.

Using a source-receptor approach to characterise VOC behaviour in a French urban area influenced by industrial emissions. Part II: source contribution assessment using the Chemical Mass Balance (CMB) model.

PubMed

Badol, Caroline; Locoge, Nadine; Galloo, Jean-Claude

2008-01-25

In Part I of this study (Badol C, Locoge N, Leonardis T, Gallo JC. Using a source-receptor approach to characterise VOC behaviour in a French urban area influenced by industrial emissions, Part I: Study area description, data set acquisition and qualitative data analysis of the data set. Sci Total Environ 2007; submitted as companion manuscript.) the study area, acquisition of the one-year data set and qualitative analysis of the data set have been described. In Part II a source profile has been established for each activity present in the study area: 6 profiles (urban heating, solvent use, natural gas leakage, biogenic emissions, gasoline evaporation and vehicle exhaust) have been extracted from literature to characterise urban sources, 7 industrial profiles have been established via canister sampling around industrial plants (hydrocarbon cracking, oil refinery, hydrocarbon storage, lubricant storage, lubricant refinery, surface treatment and metallurgy). The CMB model is briefly described and its implementation is discussed through the selection of source profiles and fitting species. Main results of CMB modellings for the Dunkerque area are presented. (1) The daily evolution of source contributions for the urban wind sector shows that the vehicle exhaust source contribution varies between 40 and 55% and its relative increase at traffic rush hours is hardly perceptible. (2) The relative contribution of vehicle exhaust varies from 55% in winter down to 30% in summer. This decrease is due to the increase of the relative contribution of hydrocarbon storage source reaching up to 20% in summer. (3) The evolution of source contributions with wind directions has confirmed that in urban wind sectors the contribution of vehicle exhaust dominate with around 45-55%. For the other wind sectors that include some industrial plants, the contribution of industrial sources is around 60% and could reach 80% for the sector 280-310 degrees , which corresponds to the most dense industrial area. (4) The pollution in Dunkerque has been globally characterised taking into account the frequency of wind directions and contributions of sources in each wind direction for the whole year. It has been concluded that contribution of industrial sources is below 20% whereas vehicle exhaust contribution is superior to 40%.

40 CFR 86.109-94 - Exhaust gas sampling system; Otto-cycle vehicles not requiring particulate emission measurements.

Code of Federal Regulations, 2011 CFR

2011-07-01

... concentration and total flow over the test period. (2) Vehicle tailpipe to CVS Duct. For methanol-fueled... proportional samples for the bag sample, and for methanol-fueled vehicles, the methanol sample (Figure B94-2... methanol-fueled vehicles, the sample lines for the methanol and formaldehyde samples are heated to prevent...

Metabolic profiling of rat hair and screening biomarkers using ultra performance liquid chromatography with electrospray ionization time-of-flight mass spectrometry.

PubMed

Inagaki, Shinsuke; Noda, Takumi; Min, Jun Zhe; Toyo'oka, Toshimasa

2007-12-28

An exhaustive analysis of metabolites in hair samples has been performed for the first time using ultra performance liquid chromatography with electrospray ionization time-of-flight mass spectrometry (UPLC-ESI-TOF-MS). The hair samples were collected from spontaneously hypertensive model rats (SHR/Izm), stroke-prone SHR (SHRSP/Izm) and Wistar Kyoto (WKY/Izm) rats, and were analyzed by UPLC-ESI-TOF-MS; a multivariate statistical analysis method, such as the principal component analysis (PCA), was then used for screening the biomarkers. From the samples derived from the group of SHRSP/Izm at weeks 10, 18, 26 and 34, we successfully detected a potential biomarker of stroke, which existed at much higher concentrations as compared with that in the other groups. However, a significant difference could not be found at weeks less than 7 before the rats were subjected to stroke and hypertension. In addition, the present method was applicable to screening not only the disease markers, but also the markers related to aging. The method utilizing hair samples is expected to be quite useful for screening biomarkers of many other diseases, and not limited to stroke and hypertension.

Automation of an ion chromatograph for precipitation analysis with computerized data reduction

USGS Publications Warehouse

Hedley, Arthur G.; Fishman, Marvin J.

1982-01-01

Interconnection of an ion chromatograph, an autosampler, and a computing integrator to form an analytical system for simultaneous determination of fluoride, chloride, orthophosphate, bromide, nitrate, and sulfate in precipitation samples is described. Computer programs provided with the integrator are modified to implement ionchromatographic data reduction and data storage. The liquid-flow scheme for the ion chromatograph is changed by addition of a second suppressor column for greater analytical capacity. An additional vave enables selection of either suppressor column for analysis, as the other column is regenerated and stabilized with concentrated eluent.Minimum limits of detection and quantitation for each anion are calculated; these limits are a function of suppressor exhaustion. Precision for replicate analyses of six precipitation samples for fluoride, chloride, orthophosphate, nitrate, and sulfate ranged from 0.003 to 0.027 milligrams per liter. To determine accuracy of results, the same samples were spiked with known concentrations of the above mentioned anions. Average recovery was 108 percent.

Chemical composition of gas-phase organic carbon emissions from motor vehicles and implications for ozone production.

PubMed

Gentner, Drew R; Worton, David R; Isaacman, Gabriel; Davis, Laura C; Dallmann, Timothy R; Wood, Ezra C; Herndon, Scott C; Goldstein, Allen H; Harley, Robert A

2013-10-15

Motor vehicles are major sources of gas-phase organic carbon, which includes volatile organic compounds (VOCs) and other compounds with lower vapor pressures. These emissions react in the atmosphere, leading to the formation of ozone and secondary organic aerosol (SOA). With more chemical detail than previous studies, we report emission factors for over 230 compounds from gasoline and diesel vehicles via two methods. First we use speciated measurements of exhaust emissions from on-road vehicles in summer 2010. Second, we use a fuel composition-based approach to quantify uncombusted fuel components in exhaust using the emission factor for total uncombusted fuel in exhaust together with detailed chemical characterization of liquid fuel samples. There is good agreement between the two methods except for products of incomplete combustion, which are not present in uncombusted fuels and comprise 32 ± 2% of gasoline exhaust and 26 ± 1% of diesel exhaust by mass. We calculate and compare ozone production potentials of diesel exhaust, gasoline exhaust, and nontailpipe gasoline emissions. Per mass emitted, the gas-phase organic compounds in gasoline exhaust have the largest potential impact on ozone production with over half of the ozone formation due to products of incomplete combustion (e.g., alkenes and oxygenated VOCs). When combined with data on gasoline and diesel fuel sales in the U.S., these results indicate that gasoline sources are responsible for 69-96% of emissions and 79-97% of the ozone formation potential from gas-phase organic carbon emitted by motor vehicles.

Electrets used to measure exhaust cloud effluents from Solid Rocket Motor (SRM) during demonstration model (DM-2) static test firing

NASA Technical Reports Server (NTRS)

Susko, M.

1978-01-01

Electrets were compared with fixed flow samplers during static test firing. The measurement of the rocket exhaust effluents by samplers and electrets indicated that the Solid Rocket Motor had no significant effect on the air quality in the area sampled. The results show that the electrets (a passive device which needs no power) can be used effectively alongside existing measuring devices (which need power). By placing electrets in areas where no power is available, measurements may be obtained. Consequently, it is a valuable complementary instrument in measuring rocket exhaust effluents in areas where other measuring devices may not be able to assess the contaminants.

Evaluation of Diesel Engine Performance with Intake and Exhaust System Throttling : Volume 2. Appendix 1.

DOT National Transportation Integrated Search

1975-11-01

The appendix to the preceding volume presents the data for the subject diesel engine noise study, including an engine sound power level analysis and sound spectrums showing the effect of intake and exhaust restrictions.

Analysis and design of three dimensional supersonic nozzles. Volume 2: Numerical program for analysis of nozzle-exhaust flow fields

NASA Technical Reports Server (NTRS)

Kalben, P.

1972-01-01

The FORTRAN IV Program developed to analyze the flow field associated with scramjet exhaust systems is presented. The instructions for preparing input and interpreting output are described. The program analyzes steady three dimensional supersonic flow by the reference plane characteristic technique. The governing equations and numerical techniques employed are presented in Volume 1 of this report.

Modeling of Engine Parameters for Condition-Based Maintenance of the MTU Series 2000 Diesel Engine

DTIC Science & Technology

2016-09-01

are suitable. To model the behavior of the engine, an autoregressive distributed lag (ARDL) time series model of engine speed and exhaust gas... time series model of engine speed and exhaust gas temperature is derived. The lag length for ARDL is determined by whitening of residuals using the...15 B. REGRESSION ANALYSIS ....................................................................15 1. Time Series Analysis

Effect of exercise intensity on cerebrospinal fluid interleukin-6 concentration during recovery from exhaustive exercise in rats.

PubMed

Kılıç, M; Ulusoy, Ö; Cırrık, S; Hindistan, I E; Ozkaya, Y Gül

2014-03-01

The purpose of this study was to investigate the possible role of moderate and strenuous swimming training on plasma and cerebrospinal fluid (CSF) IL-6 (interleukin-6) levels during recovery from exhaustive exercise in rats. Wistar rats were divided into three groups: sedentary control (C), moderately trained (MT) and strenuously trained (ST). MT rats underwent swimming exercise for one hour/day and 5 days/week for 8 weeks. Animals in the ST group began swimming with 1 h/day and swimming duration was progressively increased by 30 min/wk, reaching 2.5 h/day by week 4 and stayed constant for an additional 4 weeks. After all animals underwent an acute exhaustive swimming exercise, animals were divided into 3 groups, and decapitated immediately, 24 and 48 hours after exhaustion to obtain tissue samples. Muscle citrate synthase activity, plasma and CSF IL-6 levels were determined. The citrate synthase activity was found to be higher in MT and ST groups compared to the C group. Although plasma IL-6 levels were found unaltered among all groups, the CSF IL-6 concentration was found to be increased 24 hours after exhaustive exercise of the ST group. We conclude that exercise training intensity is an important factor determining cerebrospinal IL-6 concentration after exhaustive exercise.

In Vitro Exposures in Diesel Exhaust Atmospheres: Resuspension of PM from Filters Verses Direct Deposition of PM from Air

PubMed Central

Lichtveld, Kim M.; Ebersviller, Seth M.; Sexton, Kenneth G.; Vizuete, William; Jaspers, Ilona; Jeffries, Harvey E.

2012-01-01

One of the most widely used in vitro particulate matter (PM) exposures methods is the collection of PM on filters, followed by resuspension in a liquid medium, with subsequent addition onto a cell culture. To avoid disruption of equilibria between gases and PM, we have developed a direct in vitro sampling and exposure method (DSEM) capable of PM-only exposures. We hypothesize that the separation of phases and post-treatment of filter-collected PM significantly modifies the toxicity of the PM compared to direct deposition, resulting in a distorted view of the potential PM health effects. Controlled test environments were created in a chamber that combined diesel exhaust with an urban-like mixture. The complex mixture was analyzed using both the DSEM and concurrently-collected filter samples. The DSEM showed that PM from test atmospheres produced significant inflammatory response, while the resuspension exposures at the same exposure concentration did not. Increasing the concentration of resuspended PM sixteen times was required to yield measurable IL-8 expression. Chemical analysis of the resuspended PM indicated a total absence of carbonyl compounds compared to the test atmosphere during the direct-exposures. Therefore, collection and resuspension of PM into liquid modifies its toxicity and likely leads to underestimating toxicity. PMID:22834915

Characterization of Diesel Soot Aggregates by Scattering and Extinction Methods

NASA Astrophysics Data System (ADS)

Kamimoto, Takeyuki

2006-07-01

Characteristics of diesel soot particles sampled from diesel exhaust of a common-rail turbo-charged diesel engine are quantified by scattering and extinction diagnostics using newly build two laser-based instruments. The radius of gyration representing the aggregates size is measured by the angular distribution of scattering intensity, while the soot mass concentration is measured by a two-wavelength extinction method. An approach to estimate the refractive index of diesel soot by an analysis of the extinction and scattering data using an aggregates scattering theory is proposed.

Multipartite nonlocality and random measurements

NASA Astrophysics Data System (ADS)

de Rosier, Anna; Gruca, Jacek; Parisio, Fernando; Vértesi, Tamás; Laskowski, Wiesław

2017-07-01

We present an exhaustive numerical analysis of violations of local realism by families of multipartite quantum states. As an indicator of nonclassicality we employ the probability of violation for randomly sampled observables. Surprisingly, it rapidly increases with the number of parties or settings and even for relatively small values local realism is violated for almost all observables. We have observed this effect to be typical in the sense that it emerged for all investigated states including some with randomly drawn coefficients. We also present the probability of violation as a witness of genuine multipartite entanglement.

Design and Evaluation of a Turbojet Exhaust Simulator, Utilizing a Solid-Propellant Rocket Motor, for use in Free-Flight Aerodynamic Research Models

NASA Technical Reports Server (NTRS)

deMoraes, Carlos A.; Hagginbothom, William K., Jr.; Falanga, Ralph A.

1954-01-01

A method has been developed for modifying a rocket motor so that its exhaust characteristics simulate those of a turbojet engine. The analysis necessary to the design is presented along with tests from which the designs are evaluated. Simulation was found to be best if the exhaust characteristics to be duplicated were those of a turbojet engine at high altitudes and with the afterburner operative.

Energy Efficient Waste Heat Recovery from an Engine Exhaust System

DTIC Science & Technology

2016-12-01

targets. Since solar panels and wind turbines will not work for ships; the energy savings must come from making the existing power generation...achieve an approximate solution to the problem . The research for this thesis involved design by analysis of heat exchange in a gas turbine exhaust...effectiveness of a new style of heat exchanger for waste heat recovery. The new design sought to optimize heat recovery from a gas turbine engine exhaust as

Flight-determined engine exhaust characteristics of an F404 engine in an F-18 airplane

NASA Technical Reports Server (NTRS)

Ennix, Kimberly A.; Burcham, Frank W., Jr.; Webb, Lannie D.

1993-01-01

The exhaust characteristics of the F-18 aircraft with an F404 engine are examined with reference to the results of an acoustic flight testing program. The discussion covers an overview of the flight test planning, instrumentation, test procedures, data analysis, engine modeling codes, and results. In addition, the paper presents the exhaust velocity and Mach number data for the climb-to-cruise, Aircraft Noise Prediction Program validation, and ground tests.

Relation of Hydrogen and Methane to Carbon Monoxide in Exhaust Gases from Internal-Combustion Engines

NASA Technical Reports Server (NTRS)

Gerrish, Harold C; Tessmann, Arthur M

1935-01-01

The relation of hydrogen and methane to carbon monoxide in the exhaust gases from internal-combustion engines operating on standard-grade aviation gasoline, fighting-grade aviation gasoline, hydrogenated safety fuel, laboratory diesel fuel, and auto diesel fuel was determined by analysis of the exhaust gases. Two liquid-cooled single-cylinder spark-ignition, one 9-cylinder radial air-cooled spark-ignition, and two liquid-cooled single-cylinder compression-ignition engines were used.

40 CFR 86.127-12 - Test procedures; overview.

Code of Federal Regulations, 2012 CFR

2012-07-01

...: (1) Gaseous exhaust THC, NMHC, NMOG, CO, NOX, CO2, N2O, CH4, CH3OH, C2H5OH, C2H4O, and HCHO. (2... exhaust emission test is designed to determine gaseous THC, NMHC, NMOG, CO, CO2, CH4, NOX, N2O, and... THC using a heated sample line and analyzer; the other gaseous emissions (CH4, CO, CO2, N2O, and NOX...

40 CFR 86.127-12 - Test procedures; overview.

Code of Federal Regulations, 2013 CFR

2013-07-01

...: (1) Gaseous exhaust THC, NMHC, NMOG, CO, NOX, CO2, N2O, CH4, CH3OH, C2H5OH, C2H4O, and HCHO. (2... exhaust emission test is designed to determine gaseous THC, NMHC, NMOG, CO, CO2, CH4, NOX, N2O, and... THC using a heated sample line and analyzer; the other gaseous emissions (CH4, CO, CO2, N2O, and NOX...

40 CFR 86.127-12 - Test procedures; overview.

Code of Federal Regulations, 2014 CFR

2014-07-01

...: (1) Gaseous exhaust THC, NMHC, NMOG, CO, NOX, CO2, N2O, CH4, CH3OH, C2H5OH, C2H4O, and HCHO. (2... exhaust emission test is designed to determine gaseous THC, NMHC, NMOG, CO, CO2, CH4, NOX, N2O, and... THC using a heated sample line and analyzer; the other gaseous emissions (CH4, CO, CO2, N2O, and NOX...

A Method of Determining the Equilibrium Performance and the Stability of an Engine Equipped with an Exhaust Turbosupercharger

NASA Technical Reports Server (NTRS)

Rea, James Buchanan

1941-01-01

The performance of an exhaust turbine driving a supercharger is investigated by means of a sample calculation based on reasonable assumptions for the purpose of determining whether the assumed installation is stable with respect to changes in the mass of gas handled, boost pressure, etc. The arrangement was found to be stable throughout the entire range of operation. The method developed can be generally applied.

Milestone Report #2: Direct Evaporator Leak and Flammability Analysis Modifications and Optimization of the Organic Rankine Cycle to Improve the Recovery of Waste Heat

DOE Office of Scientific and Technical Information (OSTI.GOV)

Guillen, Donna Post

2013-09-01

The direct evaporator is a simplified heat exchange system for an Organic Rankine Cycle (ORC) that generates electricity from a gas turbine exhaust stream. Typically, the heat of the exhaust stream is transferred indirectly to the ORC by means of an intermediate thermal oil loop. In this project, the goal is to design a direct evaporator where the working fluid is evaporated in the exhaust gas heat exchanger. By eliminating one of the heat exchangers and the intermediate oil loop, the overall ORC system cost can be reduced by approximately 15%. However, placing a heat exchanger operating with a flammablemore » hydrocarbon working fluid directly in the hot exhaust gas stream presents potential safety risks. The purpose of the analyses presented in this report is to assess the flammability of the selected working fluid in the hot exhaust gas stream stemming from a potential leak in the evaporator. Ignition delay time for cyclopentane at temperatures and pressure corresponding to direct evaporator operation was obtained for several equivalence ratios. Results of a computational fluid dynamic analysis of a pinhole leak scenario are given.« less

40 CFR 89.418 - Raw emission sampling calculations.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 40 Protection of Environment 20 2011-07-01 2011-07-01 false Raw emission sampling calculations. 89... Test Procedures § 89.418 Raw emission sampling calculations. (a) The final test results shall be... measured on a wet basis. This section is applicable only for measurements made on raw exhaust gas...

40 CFR 89.418 - Raw emission sampling calculations.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw emission sampling calculations. 89... Test Procedures § 89.418 Raw emission sampling calculations. (a) The final test results shall be... measured on a wet basis. This section is applicable only for measurements made on raw exhaust gas...

40 CFR 92.114 - Exhaust gas and particulate sampling and analytical system.

Code of Federal Regulations, 2012 CFR

2012-07-01

.... (A) For diesel fueled and biodiesel fueled locomotives and engines, the wall temperature of the HC... fuels other than diesel or biodiesel, the heated components in the HC sample path shall be maintained at...

40 CFR 92.114 - Exhaust gas and particulate sampling and analytical system.

Code of Federal Regulations, 2013 CFR

2013-07-01

.... (A) For diesel fueled and biodiesel fueled locomotives and engines, the wall temperature of the HC... fuels other than diesel or biodiesel, the heated components in the HC sample path shall be maintained at...

40 CFR 92.114 - Exhaust gas and particulate sampling and analytical system.

Code of Federal Regulations, 2014 CFR

2014-07-01

.... (A) For diesel fueled and biodiesel fueled locomotives and engines, the wall temperature of the HC... fuels other than diesel or biodiesel, the heated components in the HC sample path shall be maintained at...

40 CFR 89.413 - Raw sampling procedures.

Code of Federal Regulations, 2013 CFR

2013-07-01

... emissions. (a) The gaseous emission sampling probe must be installed at least 0.5 m or 3 times the diameter... the case of a multi-cylinder engine with a branched exhaust manifold, the inlet of the probe shall be...

40 CFR 89.413 - Raw sampling procedures.

Code of Federal Regulations, 2012 CFR

2012-07-01

... emissions. (a) The gaseous emission sampling probe must be installed at least 0.5 m or 3 times the diameter... the case of a multi-cylinder engine with a branched exhaust manifold, the inlet of the probe shall be...

Atmospheric scavenging exhaust

NASA Technical Reports Server (NTRS)

Fenton, D. L.; Purcell, R. Y.

1977-01-01

Solid propellant rocket exhaust was directly utilized to ascertain raindrop scavenging rates for hydrogen chloride. The airborne HCl concentration varied from 0.2 to 10.0 ppm and the raindrop sizes tested included 0.55 mm, 1.1 mm, and 3.0 mm. Two chambers were used to conduct the experiments. A large, rigid walled, spherical chamber stored the exhaust constituents while the smaller chamber housing all the experiments was charged as required with rocket exhaust HCl. Surface uptake experiments demonstrated an HCl concentration dependence for distilled water. Sea water and brackish water HCl uptake was below the detection limit of the chlorine-ion analysis technique employed. Plant life HCl uptake experiments were limited to corn and soybeans. Plant age effectively correlated the HCl uptake data. Metallic corrosion was not significant for single 20 minute exposures to the exhaust HCl under varying relative humidity.

Atmospheric scavenging of solid rocket exhaust effluents

NASA Technical Reports Server (NTRS)

Fenton, D. L.; Purcell, R. Y.

1978-01-01

Solid propellant rocket exhaust was directly utilized to ascertain raindrop scavenging rates for hydrogen chloride. Two chambers were used to conduct the experiments; a large, rigid walled, spherical chamber stored the exhaust constituents, while the smaller chamber housing all the experiments was charged as required with rocket exhaust HCl. Surface uptake experiments demonstrated an HCl concentration dependence for distilled water. Sea water and brackish water HCl uptake was below the detection limit of the chlorine-ion analysis technique used. Plant life HCl uptake experiments were limited to corn and soybeans. Plant age effectively correlated the HCl uptake data. Metallic corrosion was not significant for single 20 minute exposures to the exhaust HCl under varying relative humidity. Characterization of the aluminum oxide particles substantiated the similarity between the constituents of the small scale rocket and the full size vehicles.

Chronic work stress and exhaustion is associated with higher allostastic load in female school teachers.

PubMed

Bellingrath, Silja; Weigl, Tobias; Kudielka, Brigitte M

2009-01-01

Epidemiological studies have shown that chronic work stress or unfavourable psychosocial work conditions are prospectively associated with different adverse health outcomes. The aim of the present cross-sectional study was to investigate the relationship between work-related chronic stress as well as exhaustion and a cumulative measure of physiological wear-and-tear called allostastic load (AL). AL could be a possible biological pathway for how chronic work stress and exhaustion lead to health impairments in the long run. As the teaching profession has been proposed to be a potentially high stressful occupation, chronic work stress (effort-reward-imbalance) and exhaustion were assessed in 104 female school teachers. AL was first analyzed according to McEwen's classical model comprised of ten parameters including cortisol, epinephrine and norepinephrine, dehydroepiandrosterone-sulphate (DHEA-S), waist/hip-ratio (WHR), glycosylated haemoglobin (HbA1c), high-density lipoprotein (HDL), total cholesterol/HDL-ratio, and systolic and diastolic blood pressure. Additionally it was extended to include tumor-necrosis-factor-alpha (TNF-alpha), C-reactive protein (CRP), fibrinogen, D-dimer, percent-body-fat, triglycerides, and glucose levels. A substantial proportion of our sample was highly exhausted whereas relatively few teachers showed high effort-reward-imbalance. AL scores were significantly higher in women high on effort-reward-imbalance or suffering from exhaustion. Although all teachers had been in a good health status, chronic work stress as well as exhaustion appears to be associated with changes in a multi-system summary indicator of physiological risk.

Exhaustive thin-layer cyclic voltammetry for absolute multianalyte halide detection.

PubMed

Cuartero, Maria; Crespo, Gastón A; Ghahraman Afshar, Majid; Bakker, Eric

2014-11-18

Water analysis is one of the greatest challenges in the field of environmental analysis. In particular, seawater analysis is often difficult because a large amount of NaCl may mask the determination of other ions, i.e., nutrients, halides, and carbonate species. We demonstrate here the use of thin-layer samples controlled by cyclic voltammetry to analyze water samples for chloride, bromide, and iodide. The fabrication of a microfluidic electrochemical cell based on a Ag/AgX wire (working electrode) inserted into a tubular Nafion membrane is described, which confines the sample solution layer to less than 15 μm. By increasing the applied potential, halide ions present in the thin-layer sample (X(-)) are electrodeposited on the working electrode as AgX, while their respective counterions are transported across the perm-selective membrane to an outer solution. Thin-layer cyclic voltammetry allows us to obtain separated peaks in mixed samples of these three halides, finding a linear relationship between the halide concentration and the corresponding peak area from about 10(-5) to 0.1 M for bromide and iodide and from 10(-4) to 0.6 M for chloride. This technique was successfully applied for the halide analysis in tap, mineral, and river water as well as seawater. The proposed methodology is absolute and potentially calibration-free, as evidenced by an observed 2.5% RSD cell to cell reproducibility and independence from the operating temperature.

40 CFR 91.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2012 CFR

2012-07-01

... “protectors” with nonreactive diaphragms to reduce dead volumes is permitted. (b) Sample probe. (1) The sample probe shall be a straight, closed end, stainless steel, multi-hole probe. The inside diameter shall not be greater than the inside diameter of the sample line + 0.03 cm. The wall thickness of the probe...

40 CFR 91.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2014 CFR

2014-07-01

... “protectors” with nonreactive diaphragms to reduce dead volumes is permitted. (b) Sample probe. (1) The sample probe shall be a straight, closed end, stainless steel, multi-hole probe. The inside diameter shall not be greater than the inside diameter of the sample line + 0.03 cm. The wall thickness of the probe...

40 CFR 91.414 - Raw gaseous exhaust sampling and analytical system description.

Code of Federal Regulations, 2013 CFR

2013-07-01

... “protectors” with nonreactive diaphragms to reduce dead volumes is permitted. (b) Sample probe. (1) The sample probe shall be a straight, closed end, stainless steel, multi-hole probe. The inside diameter shall not be greater than the inside diameter of the sample line + 0.03 cm. The wall thickness of the probe...

Numerical study on the effect of a lobed nozzle on the flow characteristics of submerged exhaust

NASA Astrophysics Data System (ADS)

Miao, T. C.; Du, T.; Wu, D. Z.; Wang, L. Q.

2016-05-01

In order to investigate the effecting mechanism of nozzle structure on the flow characteristics of submerged exhaust, the processes of air exhausted from a lobed nozzle and a round nozzle into water have been numerically simulated using realizable k - ɛ model under the framework of the volume of fluid (VOF) model. Both the flow structure and the upstream pressure fluctuations are taken into consideration. The calculated results are in good agreement with the experimental results, showing that gas exhausted from the lobed nozzle would flow along the axial direction easier. Flow structure of the gas exhausted from the lobed nozzle is more continuous and smoother. The pressure fluctuations in the upstream pipeline would also be reduced when gas exhausted from the lobed nozzle. The resulting analysis indicates that the lobed structure could deflect water flow into the gas jet. The induced water would be mixed into the gas jet in form of small droplets, making the jet more continuous. As a result, the mixed jet flow would be less obstructed by the surrounding water, and the upstream pressure fluctuation would be reduced. The work in this paper partly explained the effecting mechanism of nozzle structure on the flow characteristics of submerged exhaust. The results are useful in the designing of exhaust nozzles.

Infrared measurements of a scramjet exhaust. [to determine combustion efficiency

NASA Technical Reports Server (NTRS)

Reed, R. A.; Slack, M. W.

1980-01-01

Diagnostic 2 - 5 mm infrared spectra of a hydrogen burning scramjet exhaust were measured with an interferometer spectrometer. Exhaust gas temperatures and water vapor partial pressures were determined from the observed intensity and spectral profile of the H2O 2.7 mm infrared emission band. Overall engine combustion efficiencies were derived by combining these measurements with the known engine operating conditions. Efficiencies fall (70 - 50 percent) as fuel equivalence ratios rise (0.4 - 1.0). Data analysis techniques and sensitivity studies are also presented.

Use of a Chamber to Comprehensively Characterise Emissions and Subsequent Processes from a Light-Duty Diesel Engine

NASA Astrophysics Data System (ADS)

Allan, J. D.; Alfarra, M. R. R.; Whitehead, J.; McFiggans, G.; Kong, S.; Harrison, R. M.; Alam, M. S.; Hamilton, J. F.; Pereira, K. L.; Holmes, R. E.

2014-12-01

Around 1 in 3 light duty vehicles in the UK use diesel engines, meaning that on-road emissions of particulates, NOx and VOCs and subsequent chemical processes are substantially different to countries where gasoline engines dominate. As part of the Natural Environment Research Council (NERC) Com-Part project, emissions from a diesel engine dynamometer rig representative of the EURO 4 standard were studied. The exhaust was passed to the Manchester aerosol chamber, which consists of an 18 m3 teflon bag and by injecting a sample of exhaust fumes into filtered and chemically scrubbed air, a controllable dilution can be performed and the sample held in situ for analysis by a suite of instruments. The system also allows the injection of other chemicals (e.g. ozone, additional VOCs) and the initiation of photochemistry using a bank of halogen bulbs and a filtered Xe arc lamp to simulate solar light. Because a large volume of dilute emissions can be held for a period of hours, this permits a wide range of instrumentation to be used and relatively slow processes studied. Furthermore, because the bag is collapsible, the entire particulate contents can be collected on a filter for offline analysis. Aerosol microphysical properties are studied using a Scanning Mobility Particle Sizer (SMPS) and Centrifugal Particle Mass Analyser (CPMA); aerosol composition using a Soot Particle Aerosol Mass Spectrometer (SP-AMS), Single Particle Soot Photometer (SP2), Sunset Laboratories OC EC analyser and offline gas- and high performance liquid chromatography (employing advanced mass spectrometry such as ion trap and fourier transform ion cyclotron resonance); VOCs using comprehensive 2D gas chromatography; aerosol optical properties using a Cavity Attenuated Phase Shift Single Scattering Albedo monitor (CAPS-PMSSA), 3 wavelength Photoacoustic Soot Spectrometer (PASS-3) and Multi Angle Absorption Photometer (MAAP); particle hygroscopcity using a Hygroscopicity Tandem Differential Mobility Analyser (HTDMA) and monodisperse Cloud Condensation Nuclei counter (CCN); and measurements of ozone, NOx and CO2. Here we present the first results, where we explored the trends as a function of engine speed, load, exhaust treatment (an oxidizing catalytic converter), dilution factor and exposure to light.