Effects of acid impregnated steam explosion process on xylose recovery and enzymatic conversion of cellulose in corncob.

PubMed

Fan, Xiaoguang; Cheng, Gang; Zhang, Hongjia; Li, Menghua; Wang, Shizeng; Yuan, Qipeng

2014-12-19

Corncob residue is a cellulose-rich byproduct obtained from industrial xylose production via dilute acid hydrolysis processes. Enzymatic hydrolysis of cellulose in acid hydrolysis residue of corncob (AHRC) is often less efficient without further pretreatment. In this work, the process characteristics of acid impregnated steam explosion were studied in conjunction with a dilute acid process, and their effects on physiochemical changes and enzymatic saccharification of corncob residue were compared. With the acid impregnated steam explosion process, both higher xylose recovery and higher cellulose conversion were obtained. The maximum conversion of cellulose in acid impregnated steam explosion residue of corncob (ASERC) reached 85.3%, which was 1.6 times higher than that of AHRC. Biomass compositional analysis showed similar cellulose and lignin content in ASERC and AHRC. XRD analysis demonstrated comparable crystallinity of ASERC and AHRC. The improved enzymatic hydrolysis efficiency was attributed to higher porosity in ASERC, measured by mercury porosimetry. Copyright © 2014 Elsevier Ltd. All rights reserved.

Nanoplasmonic imaging of latent fingerprints with explosive RDX residues.

PubMed

Peng, Tianhuan; Qin, Weiwei; Wang, Kun; Shi, Jiye; Fan, Chunhai; Li, Di

2015-09-15

Explosive detection is a critical element in preventing terrorist attacks, especially in crowded and influential areas. It is probably more important to establish the connection of explosive loading with a carrier's personal identity. In the present work, we introduce fingerprinting as physical personal identification and develop a nondestructive nanoplasmonic method for the imaging of latent fingerprints. We further integrate the nanoplasmonic response of catalytic growth of Au NPs with NADH-mediated reduction of 1,3,5-trinitro-1,3,5-triazinane (RDX) for the quantitative analysis of RDX explosive residues in latent fingerprints. This generic nanoplasmonic strategy is expected to be used in forensic investigation to distinguish terrorists that carry explosives.

Installation-Restoration Program environmental-technology development. Task order 3. Use of activated carbon for treatment of explosives-contaminated ground water at the Badger Army Ammunition Plant (BAAP). Final report Jun 88-Aug 89

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wujcik, W.J.; Lowe, W.L.; Marks, P.J.

1989-08-01

The United States Army operates explosives manufacturing plants to produce various forms of explosives used in military ordnance. Manufacturing activities at such plants result in the production of organic wastewaters that contain both explosive residues and other organic chemicals. Several treatment technologies have been developed to treat these wastewaters for final discharge. Past waste handling practices at explosives manufacturing plants commonly included the use of the unlined lagoons or pits for containing process wastewaters. As a result of these past practices, some explosives residues may leach through the soil and contaminated groundwater. Therefore, the treatment of contaminated groundwater may bemore » required.« less

Progressing the analysis of Improvised Explosive Devices: Comparative study for trace detection of explosive residues in handprints by Raman spectroscopy and liquid chromatography.

PubMed

Zapata, Félix; de la Ossa, Mª Ángeles Fernández; Gilchrist, Elizabeth; Barron, Leon; García-Ruiz, Carmen

2016-12-01

Concerning the dreadful global threat of terrorist attacks, the detection of explosive residues in biological traces and marks is a current need in both forensics and homeland security. This study examines the potential of Raman microscopy in comparison to liquid chromatography (ion chromatography (IC) and reversed-phase high performance liquid chromatography (RP-HPLC)) to detect, identify and quantify residues in human handmarks of explosives and energetic salts commonly used to manufacture Improvised Explosive Devices (IEDs) including dynamite, ammonium nitrate, single- and double-smokeless gunpowders and black powder. Dynamite, ammonium nitrate and black powder were detected through the identification of the energetic salts by Raman spectroscopy, their respective anions by IC, and organic components by RP-HPLC. Smokeless gunpowders were not detected, either by Raman spectroscopy or the two liquid chromatography techniques. Several aspects of handprint collection, sample treatment and a critical comparison of the identification of compounds by both techniques are discussed. Raman microscopy and liquid chromatography were shown to be complementary to one another offering more comprehensive information for trace explosives analysis. Copyright © 2016 Elsevier B.V. All rights reserved.

The spatial distribution patterns of condensed phase post-blast explosive residues formed during detonation.

PubMed

Abdul-Karim, Nadia; Blackman, Christopher S; Gill, Philip P; Karu, Kersti

2016-10-05

The continued usage of explosive devices, as well as the ever growing threat of 'dirty' bombs necessitates a comprehensive understanding of particle dispersal during detonation events in order to develop effectual methods for targeting explosive and/or additive remediation efforts. Herein, the distribution of explosive analytes from controlled detonations of aluminised ammonium nitrate and an RDX-based explosive composition were established by systematically sampling sites positioned around each firing. This is the first experimental study to produce evidence that the post-blast residue mass can distribute according to an approximate inverse-square law model, while also demonstrating for the first time that distribution trends can vary depending on individual analytes. Furthermore, by incorporating blast-wave overpressure measurements, high-speed imaging for fireball volume recordings, and monitoring of environmental conditions, it was determined that the principle factor affecting all analyte dispersals was the wind direction, with other factors affecting specific analytes to varying degrees. The dispersal mechanism for explosive residue is primarily the smoke cloud, a finding which in itself has wider impacts on the environment and fundamental detonation theory. Copyright © 2016 The Authors. Published by Elsevier B.V. All rights reserved.

Gas generation at a municipal waste combustor ash monofill -- Franklin, New Hampshire

DOE Office of Scientific and Technical Information (OSTI.GOV)

Musselman, C.N.; Straub, W.A.; Bidwell, J.N.

1997-12-31

The characterization of landfill gas generated at municipal solid waste landfills has received significant attention in recent years. Generation of landfill gas at municipal waste combustor ash monofills is generally assumed to be negligible and there is little, if any, published information available concerning the characteristics of gas generated at ash monofills. The lined residue landfill in Franklin, New Hampshire, USA has been accepting combined ash (bottom ash, fly ash, scrubber product from direct dry lime injection) from a 500 ton per day mass burn waste to energy facility in Concord, NH from 1989 through the present. In March, 1996,more » landfill operators noticed gaseous emissions from cleanout lines connected to the landfill`s primary leachate collection system beneath the landfilled residue. The landfill staff tested these emissions with a hand-held LEL meter, which tripped alarms for low O{sub 2} and explosiveness. Subsequently, a comprehensive program was completed to sample and analyze the gaseous emissions. Temperatures within the landfill mass were unexpectedly found to be as high as 156 F, higher than typical in an MSW landfill, presumably due to exothermic chemical reactions within the residue. Methane concentrations were found to be very low, and oxygen was present, although at depressed concentrations. Methanogenic bacterial activity does not appear to play a major role in gas generation in a residue landfill. Hydrogen gas was measured at significant concentrations. The hydrogen gas is postulated to be generated by reactions of elemental aluminum within the landfilled residue. These hydrogen generating aluminum reactions may be accelerated at elevated pH levels resulting from the presence of dry lime scrubber product. Volatile organic compounds were present in concentrations at the low end of concentrations generally reported for MSW landfills.« less

Stand-off detection of trace explosives by infrared photothermal imaging

NASA Astrophysics Data System (ADS)

Papantonakis, Michael R.; Kendziora, Chris; Furstenberg, Robert; Stepnowski, Stanley V.; Rake, Matthew; Stepnowski, Jennifer; McGill, R. Andrew

2009-05-01

We have developed a technique for the stand-off detection of trace explosives using infrared photothermal imaging. In this approach, infrared quantum cascade lasers tuned to strong vibrational absorption bands of the explosive particles illuminate a surface of interest, preferentially heating the explosives material. An infrared focal plane array is used to image the surface and detect a small increase in the thermal intensity upon laser illumination. We have demonstrated the technique using TNT and RDX residues at several meters of stand-off distance under laboratory conditions, while operating the lasers below the eye-safe intensity limit. Sensitivity to explosives traces as small as a single grain (~100 ng) of TNT has been demonstrated using an uncooled bolometer array. We show the viability of this approach on a variety of surfaces which transmit, reflect or absorb the infrared laser light and have a range of thermal conductivities. By varying the incident wavelength slightly, we demonstrate selectivity between TNT and RDX. Using a sequence of lasers at different wavelengths, we increase both sensitivity and selectivity while reducing the false alarm rate. At higher energy levels we also show it is possible to generate vapor from solid materials with inherently low vapor pressures.

Steam explosion treatment for ethanol production from branches pruned from pear trees by simultaneous saccharification and fermentation.

PubMed

Sasaki, Chizuru; Okumura, Ryosuke; Asada, Chikako; Nakamura, Yoshitoshi

2014-01-01

This study investigated the production of ethanol from unutilized branches pruned from pear trees by steam explosion pretreatment. Steam pressures of 25, 35, and 45 atm were applied for 5 min, followed by enzymatic saccharification of the extracted residues with cellulase (Cellic CTec2). High glucose recoveries, of 93.3, 99.7, and 87.1%, of the total sugar derived from the cellulose were obtained from water- and methanol-extracted residues after steam explosion at 25, 35, and 45 tm, respectively. These values corresponded to 34.9, 34.3, and 27.1 g of glucose per 100 g of dry steam-exploded branches. Simultaneous saccharification and fermentation experiments were done on water-extracted residues and water- and methanol-extracted residues by Kluyveromyces marxianus NBRC 1777. An overall highest theoretical ethanol yield of 76% of the total sugar derived from cellulose was achieved when 100 g/L of water- and methanol-washed residues from 35 atm-exploded pear branches was used as substrate.

The Nuclear Barcode: a New Taggant for Identifying Explosives

NASA Astrophysics Data System (ADS)

Seman, James; Johnson, Catherine; Castaño, Carlos

2017-06-01

Creating an effective taggant system for explosives is a challenging problem since the taggant used must be designed to endure the detonation process. A new taggant for use in explosives has been recently developed and named the `nuclear barcode'. The nuclear barcode tags explosives by adding low concentrations of eight different elements to the explosive, and then reads the tag from the post-blast residue using neutron activation analysis (NAA) to identify the elements and their concentrations. The nuclear barcode can be used to identify explosives after detonation by sampling the post-blast residue that is deposited due to incomplete reaction of the explosives. This method of tagging explosives creates an identifying taggant that survives detonation as NAA detects atomic nuclei as opposed to using any chemical or physical properties of the taggant that don't always survive the detonation process. Additional advantages this taggant method offers is ease of recovery of the taggant after detonation, and a total of 25.6 billion possible taggants as currently conceived, which enables the nuclear barcode to be used to tag individual batches of explosives. This paper describes the development of the nuclear barcode taggant system and its potential use in the explosives industry.

Visual detection of trace nitroaromatic explosive residue using photoluminescent metallole-containing polymers.

PubMed

Toal, Sarah J; Sanchez, Jason C; Dugan, Regina E; Trogler, William C

2007-01-01

The detection of trace explosives is important for forensic, military, and homeland security applications. Detection of widely used nitroaromatic explosives (trinitrotoluene [TNT], 2,4-dinitrotoluene [DNT], picric acid [PA]) was carried out using photoluminescent metallole-containing polymers. The method of detection is through the quenching of fluorescence of thin films of the polymer, prepared by spray coating organic solutions of the polymer, by the explosive analyte. Visual quenching of luminescence (lambda(em) approximately 400-510 nm) in the presence of the explosive is seen immediately upon illumination with near-UV light (lambda(ex)=360 nm). Detection limits were observed to be as low as 5 ng for TNT, 20 ng for DNT, and 5 ng for PA. In addition, experiments with normal production line explosives and their components show that this technology is also able to detect composition B, Pyrodex, and nitromethane. This method offers a convenient and sensitive method of detection of trace nitroaromatic explosive residue.

Genetically engineered microorganisms for the detection of explosives’ residues

PubMed Central

Shemer, Benjamin; Palevsky, Noa; Yagur-Kroll, Sharon; Belkin, Shimshon

2015-01-01

The manufacture and use of explosives throughout the past century has resulted in the extensive pollution of soils and groundwater, and the widespread interment of landmines imposes a major humanitarian risk and prevents civil development of large areas. As most current landmine detection technologies require actual presence at the surveyed areas, thus posing a significant risk to personnel, diverse research efforts are aimed at the development of remote detection solutions. One possible means proposed to fulfill this objective is the use of microbial bioreporters: genetically engineered microorganisms “tailored” to generate an optical signal in the presence of explosives’ vapors. The use of such sensor bacteria will allow to pinpoint the locations of explosive devices in a minefield. While no study has yet resulted in a commercially operational system, significant progress has been made in the design and construction of explosives-sensing bacterial strains. In this article we review the attempts to construct microbial bioreporters for the detection of explosives, and analyze the steps that need to be undertaken for this strategy to be applicable for landmine detection. PMID:26579085

Signal processing for the detection of explosive residues on varying substrates using laser-induced breakdown spectroscopy

NASA Astrophysics Data System (ADS)

Morton, Kenneth D., Jr.; Torrione, Peter A.; Collins, Leslie

2011-05-01

Laser induced breakdown spectroscopy (LIBS) can provide rapid, minimally destructive, chemical analysis of substances with the benefit of little to no sample preparation. Therefore, LIBS is a viable technology for the detection of substances of interest in near real-time fielded remote sensing scenarios. Of particular interest to military and security operations is the detection of explosive residues on various surfaces. It has been demonstrated that LIBS is capable of detecting such residues, however, the surface or substrate on which the residue is present can alter the observed spectra. Standard chemometric techniques such as principal components analysis and partial least squares discriminant analysis have previously been applied to explosive residue detection, however, the classification techniques developed on such data perform best against residue/substrate pairs that were included in model training but do not perform well when the residue/substrate pairs are not in the training set. Specifically residues in the training set may not be correctly detected if they are presented on a previously unseen substrate. In this work, we explicitly model LIBS spectra resulting from the residue and substrate to attempt to separate the response from each of the two components. This separation process is performed jointly with classifier design to ensure that the classifier that is developed is able to detect residues of interest without being confused by variations in the substrates. We demonstrate that the proposed classification algorithm provides improved robustness to variations in substrate compared to standard chemometric techniques for residue detection.

What factors control the superficial lava dome explosivity?

NASA Astrophysics Data System (ADS)

Boudon, Georges; Balcone-Boissard, Hélène; Villemant, Benoit; Morgan, Daniel J.

2015-04-01

Dome-forming eruption is a frequent eruptive style; lava domes result from intermittent, slow extrusion of viscous lava. Most dome-forming eruptions produce highly microcrystallized and highly- to almost totally-degassed magmas which have a low explosive potential. During lava dome growth, recurrent collapses of unstable parts are the main destructive process of the lava dome, generating concentrated pyroclastic density currents (C-PDC) channelized in valleys. These C-PDC have a high, but localized, damage potential that largely depends on the collapsed volume. Sometimes, a dilute ash cloud surge develops at the top of the concentrated flow with an increased destructive effect because it may overflow ridges and affect larger areas. In some cases, large lava dome collapses can induce a depressurization of the magma within the conduit, leading to vulcanian explosions. By contrast, violent, laterally directed, explosions may occur at the base of a growing lava dome: this activity generates dilute and turbulent, highly-destructive, pyroclastic density currents (D-PDC), with a high velocity and propagation poorly dependent on the topography. Numerous studies on lava dome behaviors exist, but the triggering of lava dome explosions is poorly understood. Here, seven dome-forming eruptions are investigated: in the Lesser Antilles arc: Montagne Pelée, Martinique (1902-1905, 1929-1932 and 650 y. BP eruptions), Soufrière Hills, Montserrat; in Guatemala, Santiaguito (1929 eruption); in La Chaîne des Puys, France (Puy de Dome and Puy Chopine eruptions). We propose a new model of superficial lava-dome explosivity based upon a textural and geochemical study (vesicularity, microcrystallinity, cristobalite distribution, residual water contents, crystal transit times) of clasts produced by these key eruptions. Superficial explosion of a growing lava dome may be promoted through porosity reduction caused by both vesicle flattening due to gas escape and syn-eruptive cristobalite precipitation. Both processes generate an impermeable and rigid carapace allowing overpressurisation of the inner parts of the lava dome by the rapid input of vesiculated magma batches. The thickness of the cristobalite-rich carapace is an inverse function of the external lava dome surface area. Thus the probability of a superficial lava dome explosion inversely depends on its size; explosive activity more likely occurs at the onset of the lava dome extrusion in agreement with observations. We evidence a two-step process in magma ascent with edification of the lava dome that may be accompanied by a rapid ascent of an undegassed batch of magma some days prior the explosive activity. This new result is of interest for the whole volcanological community and for risk management.

Granular activated carbon pilot treatment studies for explosives removal from contaminated groundwater

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wujcik, W.J.; Lowe, W.L.; Marks, P.J.

1992-08-01

Manufacturing activities at Army Ammunition Plants (AAPs) result in the production of organic wastewaters that contain both explosive residues and other organic chemicals. As a result of past waste practices at such plants, explosive residues may leach through the soil and contaminate groundwater. Two pilot studies were performed to evaluate the use of granular activated carbon (GAC) to treat groundwater contaminated with explosives at Badger AAP and Milan AAP. An additional goal of the Badger AAP study was to examine the potential discharge of explosives 2,4-DNT and 2,6-DNT from a packed column air stripper used to remove volatile organic compoundsmore » from groundwater. A laboratory method was developed for the BAAP study to permit lower detection levels for 2,4-DNT and 2,6-DNT (0.46[mu]g/L and 0.017 [mu]g/L, respectively). The studies concluded that removal of explosives from groundwater using continuous flow GAC is feasible. 14 refs., 10 figs., 11 tabs.« less

Enzymatic saccharification and bioethanol production from Cynara cardunculus pretreated by steam explosion.

PubMed

Fernandes, Maria C; Ferro, Miguel D; Paulino, Ana F C; Mendes, Joana A S; Gravitis, Janis; Evtuguin, Dmitry V; Xavier, Ana M R B

2015-06-01

The correct choice of the specific lignocellulosic biomass pretreatment allows obtaining high biomass conversions for biorefinery implementations and cellulosic bioethanol production from renewable resources. Cynara cardunculus (cardoon) pretreated by steam explosion (SE) was involved in second-generation bioethanol production using separate hydrolysis and fermentation (SHF) or simultaneous saccharification and fermentation (SSF) processes. Steam explosion pretreatment led to partial solubilisation of hemicelluloses and increased the accessibility of residual polysaccharides towards enzymatic hydrolysis revealing 64% of sugars yield against 11% from untreated plant material. Alkaline extraction after SE pretreatment of cardoon (CSEOH) promoted partial removal of degraded lignin, tannins, extractives and hemicelluloses thus allowing to double glucose concentration upon saccharification step. Bioethanol fermentation in SSF mode was faster than SHF process providing the best results: ethanol concentration 18.7 g L(-1), fermentation efficiency of 66.6% and a yield of 26.6g ethanol/100 g CSEOH or 10.1 g ethanol/100 g untreated cardoon. Copyright © 2015 Elsevier Ltd. All rights reserved.

Environmental Review Guide for Operations (ERGO) - A Compliance Assessment Manual for Use at All USACE Civil-Funded Projects and Facilities

DTIC Science & Technology

1994-03-01

other Pickling liquor and other corrosive alkalies corrosive acids Lime wastewater Spent acid Lime and water Spent mixed acid Spent caustic Spent ...acid Spent caustic Spent sulfuric acid Potential Consequences: heat generation; violent reaction. 4 - 161 Appendix 4-6 (continued) Group 2-A Group 2-B1...topical bleach (STB) Ordnance, ammunition, explosives & residues Battery acid & caustics (in unserviceable batteries) Some pharmaceuticals Petroleum, oil

Production of D-lactic acid from sugarcane bagasse using steam-explosion

NASA Astrophysics Data System (ADS)

Sasaki, Chizuru; Okumura, Ryosuke; Asakawa, Ai; Asada, Chikako; Nakamura, Yoshitoshi

2012-03-01

This study investigated the production of D-lactic acid from unutilized sugarcane bagasse using steam explosion pretreatment. The optimal steam pressure for a steaming time of 5 min was determined. By enzymatic saccharification using Meicellase, the highest recovery of glucose from raw bagasse, 73.7%, was obtained at a steam pressure of 20 atm. For residue washed with water after steam explosion, the glucose recovery increased up to 94.9% at a steam pressure of 20 atm. These results showed that washing with water is effective in removing enzymatic reaction inhibitors. After steam pretreatment (steam pressure of 20 atm), D-lactic acid was produced by Lactobacillus delbrueckii NBRC 3534 from the enzymatic hydrolyzate of steam-exploded bagasse and washed residue. The conversion rate of D-lactic acid obtained from the initial glucose concentration was 66.6% for the hydrolyzate derived from steam-exploded bagasse and 90.0% for that derived from the washed residue after steam explosion. These results also demonstrated that the hydrolyzate of steam-exploded bagasse (without washing with water) contains fermentation inhibitors and washing with water can remove them.

Double-pulse standoff laser-induced breakdown spectroscopy for versatile hazardous materials detection

NASA Astrophysics Data System (ADS)

Gottfried, Jennifer L.; De Lucia, Frank C.; Munson, Chase A.; Miziolek, Andrzej W.

2007-12-01

We have developed a double-pulse standoff laser-induced breakdown spectroscopy (ST-LIBS) system capable of detecting a variety of hazardous materials at tens of meters. The use of a double-pulse laser improves the sensitivity and selectivity of ST-LIBS, especially for the detection of energetic materials. In addition to various metallic and plastic materials, the system has been used to detect bulk explosives RDX and Composition-B, explosive residues, biological species such as the anthrax surrogate Bacillus subtilis, and chemical warfare simulants at 20 m. We have also demonstrated the discrimination of explosive residues from various interferents on an aluminum substrate.

Advances in Analysis and Detection of Explosives. Proceedings of the International Symposium on Analysis and Detection of Explosives (4th), Held in Jerusalem, Israel on September 7-10, 1992

DTIC Science & Technology

1992-09-01

by Supercritical Fluid Extraction in Explosives; The Semtex-H Story; The Identification of Organic Peroxides; Slurry and Emulsion...Among the topics presented at this symposium were: Birmingham Six Pub Bombing Case (Keynote Lecture); A Scheme for the Analysis of Explosives and...Explosives: New Tools for Terrorists, New Challenges, for Detection and Identification; The Work of the Explosives and Gunshot Residues Unit of the Forensic Science Service (UK)

Selective detection of trace nitroaromatic, nitramine, and nitrate ester explosive residues using a three-step fluorimetric sensing process: a tandem turn-off, turn-on sensor.

PubMed

Sanchez, Jason C; Toal, Sarah J; Wang, Zheng; Dugan, Regina E; Trogler, William C

2007-11-01

Detection of trace quantities of explosive residues plays a key role in military, civilian, and counter-terrorism applications. To advance explosives sensor technology, current methods will need to become cheaper and portable while maintaining sensitivity and selectivity. The detection of common explosives including trinitrotoluene (TNT), cyclotrimethylenetrinitramine, cyclotetramethylene-tetranitramine, pentaerythritol tetranitrate, 2,4,6-trinitrophenyl-N-methylnitramine, and trinitroglycerin may be carried out using a three-step process combining "turn-off" and "turn-on" fluorimetric sensing. This process first detects nitroaromatic explosives by their quenching of green luminescence of polymetalloles (lambda em approximately 400-510 nm). The second step places down a thin film of 2,3-diaminonaphthalene (DAN) while "erasing" the polymetallole luminescence. The final step completes the reaction of the nitramines and/or nitrate esters with DAN resulting in the formation of a blue luminescent traizole complex (lambda(em) = 450 nm) providing a "turn-on" response for nitramine and nitrate ester-based explosives. Detection limits as low as 2 ng are observed. Solid-state detection of production line explosives demonstrates the applicability of this method to real world situations. This method offers a sensitive and selective detection process for a diverse group of the most common high explosives used in military and terrorist applications today.

Residual Stress Development in Explosive-Bonded Bi-Metal Composite Materials

DTIC Science & Technology

2014-03-01

at ANSTO, researching high temperature fatigue behaviour and modelling of ferritic pressure vessel steel , for which he was awarded the degree at...solidification cracking in steels and stainless steels . He has also undertaken extensive work on improving the weld zone toughness of high strength steels ...957. [3] I. Tatsukawa, I. Oda, ‘Residual Stress Measurements on Explosive Clad Stainless Steel ’, Trans. Japan Welding Soc., 2(2), 1971, p26-34

Bomb swab: Can trace explosive particle sampling and detection be improved?

PubMed

Fisher, Danny; Zach, Raya; Matana, Yossef; Elia, Paz; Shustack, Shiran; Sharon, Yarden; Zeiri, Yehuda

2017-11-01

The marked increase in international terror in recent years requires the development of highly efficient methods to detect trace amounts of explosives at airports, border crossings and check points. The preferred analytical method worldwide is the ion mobility spectrometry (IMS) that is capable of detecting most explosives at the nano-gram level. Sample collection for the IMS analysis is based on swabbing of a passenger's belongings to collect possible explosive residues. The present study examines a wide range of issues related to swab-based particle collection and analysis, in the hope of gaining deeper understanding into this technique that will serve to improve the detection process. The adhesion of explosive particles to three typical materials, plastic, metal and glass, were measured using atomic force microscopy (AFM). We found that a strong contribution of capillary forces to adhesion on glass and metal surfaces renders these substrates more promising materials upon which to find and collect explosive residues. The adhesion of explosives to different swipe materials was also examined. Here we found that Muslin, Nomex ® and polyamide membrane surfaces are the most promising materials for use as swipes. Subsequently, the efficiency of multiple swipe use - for collecting explosive residues from a glass surface using Muslin, Nomex ® and Teflon™ swipes - was examined. The study suggests that swipes used in about 5-10 "sampling and analysis cycles" have higher efficiency as compared to new unused swipes. The reason for this behavior was found to be related to the increased roughness of the swipe surface following a few swab measurements. Lastly, GC-MS analysis was employed to examine the nature of contaminants collected by the three types of swipe. The relative amounts of different contaminants are reported. The existence and interference of these contaminants have to be considered in relation to the detection efficiency of the various explosives by the IMS. Copyright © 2017 Elsevier B.V. All rights reserved.

Optimisation of recovery protocols for double-base smokeless powder residues analysed by total vaporisation (TV) SPME/GC-MS.

PubMed

Sauzier, Georgina; Bors, Dana; Ash, Jordan; Goodpaster, John V; Lewis, Simon W

2016-09-01

The investigation of explosive events requires appropriate evidential protocols to recover and preserve residues from the scene. In this study, a central composite design was used to determine statistically validated optimum recovery parameters for double-base smokeless powder residues on steel, analysed using total vaporisation (TV) SPME/GC-MS. It was found that maximum recovery was obtained using isopropanol-wetted swabs stored under refrigerated conditions, then extracted for 15min into acetone on the same day as sample collection. These parameters were applied to the recovery of post-blast residues deposited on steel witness surfaces following a PVC pipe bomb detonation, resulting in detection of all target components across the majority of samples. Higher overall recoveries were obtained from plates facing the sides of the device, consistent with the point of first failure occurring in the pipe body as observed in previous studies. The methodology employed here may be readily applied to a variety of other explosive compounds, and thus assist in establishing 'best practice' procedures for explosive investigations. Copyright © 2016 Elsevier B.V. All rights reserved.

Morphologically manipulated Ag/ZnO nanostructures as surface enhanced Raman scattering probes for explosives detection

NASA Astrophysics Data System (ADS)

Shaik, Ummar Pasha; Hamad, Syed; Ahamad Mohiddon, Md.; Soma, Venugopal Rao; Ghanashyam Krishna, M.

2016-03-01

The detection of secondary explosive molecules (e.g., ANTA, FOX-7, and CL-20) using Ag decorated ZnO nanostructures as surface enhanced Raman scattering (SERS) probes is demonstrated. ZnO nanostructures were grown on borosilicate glass substrates by rapid thermal oxidation of metallic Zn films at 500 °C. The oxide nanostructures, including nanosheets and nanowires, emerged over the surface of the Zn film leaving behind the metal residue. We demonstrate that SERS measurements with concentrations as low as 10 μM, of the three explosive molecules ANTA, FOX-7, and CL-20 over ZnO/Ag nanostructures, resulted in enhancement factors of ˜107, ˜107, and ˜104, respectively. These measurements validate the high sensitivity of detection of explosive molecules using Ag decorated ZnO nanostructures as SERS substrates. The Zn metal residue and conditions of annealing play an important role in determining the detection sensitivity.

Influence of Metal Substrates on the Detection of Explosive Residues With Laser-Induced Breakdown Spectroscopy

DTIC Science & Technology

2013-04-01

of explosives residues: a review of recent advances, challenges, and future prospects,” Anal. Bioanal. Chem. 395, 283–300 (2009). 2. D. A. Cremers and...L. J. Radziemski, Handbook of Laser- Induced Breakdown Spectroscopy (Wiley, 2006 ). 3. V. I. Babushok, F. C. De Lucia, Jr., P. J. Dagdigian, J. L...Gottfried, “Laser-induced plasma chemistry of the explo- sive RDX with various metallic nanoparticles,” Appl. Opt. 51, B13–B21 (2012). 10. D. A. Cremers

Pilot-scale steam explosion for xylose production from oil palm empty fruit bunches and the use of xylose for ethanol production.

PubMed

Duangwang, Sairudee; Ruengpeerakul, Taweesak; Cheirsilp, Benjamas; Yamsaengsung, Ram; Sangwichien, Chayanoot

2016-03-01

Pilot-scale steam explosion equipments were designed and constructed, to experimentally solubilize xylose from oil palm empty fruit bunches (OPEFB) and also to enhance an enzyme accessibility of the residual cellulose pulp. The OPEFB was chemically pretreated prior to steam explosion at saturated steam (SS) and superheated steam (SHS) conditions. The acid pretreated OPEFB gave the highest xylose recovery of 87.58 ± 0.21 g/kg dried OPEFB in the liquid fraction after explosion at SHS condition. These conditions also gave the residual cellulose pulp with high enzymatic accessibility of 73.54 ± 0.41%, which is approximately threefold that of untreated OPEFB. This study has shown that the acid pretreatment prior to SHS explosion is an effective method to enhance both xylose extraction and enzyme accessibility of the exploded OPEFB. Moreover, the xylose solution obtained in this manner could directly be fermented by Candida shehatae TISTR 5843 giving high ethanol yield of 0.30 ± 0.08 g/g xylose. Copyright © 2015 Elsevier Ltd. All rights reserved.

Quantification and aging of the post-blast residue of TNT landmines.

PubMed

Oxley, Jimmie C; Smith, James L; Resende, Elmo; Pearce, Evan

2003-07-01

Post-blast residues are potential interferents to chemical detection of landmines. To assess the potential problem related to 2,4,6-trinitrotoluene (TNT), its post-blast residue was identified and quantified. In the first part of this study laboratory-scale samples of TNT (2 g) were detonated in a small-scale explosivity device (SSED) to evaluate the explosive power and collect post-blast residue for chemical analysis. Initiator size was large relative to the TNT charge; thus, issues arose regarding choice of initiator, residue from the initiator, and afterburning of TNT. The second part of this study detonated 75 to 150 g of military-grade TNT (typical of antipersonnel mines) in 55-gal barrels containing various witness materials (metal plates, sand, barrel walls, the atmosphere). The witness materials were analyzed for explosive residue. In a third set of tests, 75-g samples of TNT were detonated over soil (from Fort Leonard Wood or Sandia National Laboratory) in an indoor firing chamber (100 by 4.6 by 2.7 m high). Targeted in these studies were TNT and four explosive-related compounds (ERC): 2,4-dinitrotoluene (DNT), 1,3-dinitrobenzene (DNB), 2- and 4-aminodinitrotoluene (2-ADNT and 4-ADNT). The latter two are microbial degradation products of TNT. Post-blast residue was allowed to age in the soils as a function of moisture contents (5 and 10%) in order to quantify the rate of degradation of the principal residues (TNT, DNT, and DNB) and formation of the TNT microbial degradation products (2-ADNT and 4-ADNT). The major distinction between landmine leakage and post-blast residue was not the identity of the species but relative ratios of amounts. In landmine leakage the DNT/TNT ratio was usually greater than 1. In post-blast residue it was on the order of 1 to 1/100th of a percent, and the total amount of pre-blast residue (landmine leakage) was a factor of 1/100 to 1/1000 less than post-blast. In addition, landmine leakage resulted in low DNT/ADNT ratios, usually less than 1, whereas pre-blast residues started with ratios above 20. Because with time DNT decreased and ADNT increased, over a month the ratio decreased by a factor of 2. The rate of TNT degradation in soil observed in this study was much slower than that reported when initial concentrations of TNT were lower. Degradation rates yielded half-lives of 40 and 100 days for 2,4-DNT and TNT, respectively.

Identification of improvised explosives residues using physical-chemical analytical methods under real conditions after an explosion

NASA Astrophysics Data System (ADS)

Kotrlý, Marek; Mareš, Bohumil; Turková, Ivana; Beroun, Ivo

2016-05-01

Within the analysis of cases relating to the use of explosives for crimes, we have experienced a shift from using industrial explosives towards substances made in amateur and illegal way. Availability of industrial explosives is increasingly limited to a narrow sphere of subjects with a relevant permission. Thus, on the part of perpetrators, terrorists, ever greater attention is paid to illegal production of explosives that are easily made from readily available raw materials. Another alarming fact is the availability of information found on the internet. Procedures of preparation are often very simple and do not require even a deeper professional knowledge. Explosive characteristics are not actually accessible for many of these substances (detonation velocity, sensitivity, working capacity, brisance, physical and chemical stability, etc.). Therefore, a project is being implemented, which on grounds of assessment of individual information available in literature and on the internet, aiming at choosing individual areas of potentially abusable substances (e.g. mixtures of nitric acid (98%) with organic substances, mixtures nitromethane and tetranitromethane with organic substances, mixtures of chlorates and perchlorates of alkali metals with organic substances, chemically individual compounds of organic base type of perchloric acid, azides, fulminates, acetylides, picrates, styphnates of heavy metals, etc.). It is directed towards preparation of these explosives also in non-stoichiometric mixtures, conducting test explosives, determination of explosive characteristics (if they are unknown) and analysis of both primary phases and post-blast residues through available analytical techniques, such as gas and liquid chromatography with mass detection, FTIR, micro-Raman spectrometry, electron microscopy with microanalysis and Raman microspectrometry directly in SEM chamber for analysis at the level of individual microparticles. The received characteristics will be used to extend knowledge database for security forces.

Analysis and Simulation of Near-Field Ground Motions from the Source Physics Experiment

NASA Astrophysics Data System (ADS)

Antoun, T. H.; Vorobiev, O.; Xu, H.; Herbold, E. B.; Glenn, L.; Lomov, I.

2011-12-01

The Source Physics Experiment (SPE) at the Nevada National Security Site is planned as a series of chemical explosions under a variety of emplacement conditions. The goal of the SPE is to improve our physical understanding and ability to model explosively generated seismic waves, particularly S-waves. The first SPE explosion (SPE1) consisted of a 100 kg shot at a depth of 60 meters in granite (Climax Stock). The shot was well-recorded by an array of over 150 instruments, including both near-field wave motion measurements as well as far-field seismic measurements. This paper focuses on measurements and modeling of the near-field data, which included triaxial acceleration measurements at eighteen different locations azimuthally distributed around the explosive charge. Three triaxial accelerometers were embedded in each of six vertical boreholes, distributed in two concentric rings around the charge. The inner ring consisted of three equidistant boreholes at a radius of 10 m from the charge, and the outer ring consisted of another three equidistant boreholes at a radius of 20 m. In each borehole, the accelerometers were vertically distributed at depths of 60 m (shot horizon), 50 m and 15 m. Surface accelerations were also recorded along a radial line centered at surface ground zero. A review of the SPE1 data shows that the peak radial velocity as a function of scaled range is consistent with previous nuclear explosion data but exhibits greater variability. The scaled peak radial displacement also exhibits greater variability but the mean values are significantly higher than exhibited in previous nuclear explosion data. These higher displacements were also observed in calculations performed with a constitutive model based on nuclear explosion data in hard rock, but employed a JWL equation of state for the ANFO explosive used in SPE1. The reason for this behavior is believed to be the higher effective ratio of specific heats in the explosion products of the chemical explosive, leading to higher residual cavity pressure. Azimuthal scatter in the velocity data correspond to joint orientation, and as anticipated, the joints appear to be the principal source of observed shear wave generation in the near field. Preliminary modeling of the SPE1 data shows that continuum simulations that do not explicitly account for the effect of joints will not successfully reproduce the observed directional variations in the recorded data. However, 2D and 3D simulations that explicitly account for joints and pre-existing fractures show that a low friction angle, derived with water-filled joints, may account for the observed variation in peak velocity and displacement. Waves appear to propagate more readily in the direction of persistent joints, as opposed to staggered joints. Furthermore, the anisotropy associated with wave propagation seems to be more pronounced when the friction angle was lowered to account for the effect of saturation. Further modeling is being conducted with continued focus on the effect of the presence of joints and their properties on shear wave generation. Simulation results will be compared to experimental measurements of both radial and non-radial motions from the SPE1 event, as well as from planned future SPE explosions.

Impact of ammunition and military explosives on human health and the environment.

PubMed

Lima, Débora R S; Bezerra, Marcio L S; Neves, Eduardo B; Moreira, Fátima R

2011-01-01

To review the literature concerning the risks associated with the main xenobiotics contained in military ammunition and explosive residues and damage to human and environmental health. Using "ammunition", "military", "environmental", "health", "explosive", "metal", "TNT", "RDX", "pollution", and "contamination" as search terms, a large database, namely ISI Web of Knowledge and PubMed, was searched for studies on military ammunition and explosive residues from 1989 to 2010. Other sources used to conduct the search included the library of the Toxicology Laboratory of the Center for Workers' Health and Human Ecology (CESTEH) at the National School of Public Health. In total, 15 different combinations were used with the search words above and 708 papers were found. Among them, 76 papers concerned this review. More than 12 references of interest were discovered in the library of the CESTEH. The results were organized into metals, dinitrotoluene, trinitrotoluene (TNT), and royal demolition explosive (RDX), showing their main uses, occurrence in the environment, the current toxic effects to human and environmental health, and remediation possibilities. Because military activities can cause the acute and chronic exposure of human beings, the public administration must aim politics towards suitable environmental management.

New possibilities to analyse non-standard explosives and post blast residues in forensic practice

NASA Astrophysics Data System (ADS)

Kotrlý, Marek; Turková, Ivana

2005-05-01

Nonstandard and home-made explosives always pose a considerable threat for security forces in terms of their practically unlimited variability, both in composition and in construction of explosive devises. Electron microscopy - SEM with EDS/WDS is one of the key techniques for an analysis of non-standard explosives and post-blast residues. If the amount of materials allows it, a number of other analytical techniques are utilized, such as XRD that is capable of a direct phase identification of a crystalline substance, namely in mixtures. TLC has constantly proved itself useful for laboratory screening. Furthermore, combinations of FTIR, Raman spectrometry, LC MS, GC MS, XRF, micro XRF and other ones are applied. In the case of identification of post-blast residues, where an investigation is often conducted at the level of separate microscopic particles, the role of SEM is unsubstitutable, whereas the analysis of the organic phase from these often sporadic microparticles has been infeasible until recently. One of the very interesting options appears to be Raman spectrometry technique, which is nowadays obtainable as a supplement to SEM EDX. Newly available is the device that is fully confocal, SEM keeps full functionality and scan range, very high resolution (for green laser resolution 360nm FWHM; 430nm Rayleigh), it is fitted with high quality objective lens, enhances mapping through Raman spectrometry in a volume 250μm x 250μm x 250μm by piezo driven scanner (capacitive feedback linearized) and obtaining a high quality white light image (250μm x 250μm) immediately in the SEM chamber. This technique is currently undergoing intensive testing and it seems that the method could significantly help to address issues with the analysis of organic phases in electron microscopy not only in the case of post-blast residues and explosives.

Chemical Sensing of Unexploded Ordnance with the Mobile Underwater Survey System (MUDSS)

NASA Technical Reports Server (NTRS)

Chutjian, A.; Darrach, M.

1999-01-01

The ability to sense explosives residues in the marine environment is a critical tool for identification and classification of underwater unexploded ordnance (UXO). Trace explosives signatures of TNT and DNT have been extracted from mulitple sediment samples adjacent to unexploded undersea ordnance at Halifax Harbor, Canada.

Influence of exothermic chemical reactions on laser-induced shock waves.

PubMed

Gottfried, Jennifer L

2014-10-21

Differences in the excitation of non-energetic and energetic residues with a 900 mJ, 6 ns laser pulse (1064 nm) have been investigated. Emission from the laser-induced plasma of energetic materials (e.g. triaminotrinitrobenzene [TATB], cyclotrimethylene trinitramine [RDX], and hexanitrohexaazaisowurtzitane [CL-20]) is significantly reduced compared to non-energetic materials (e.g. sugar, melamine, and l-glutamine). Expansion of the resulting laser-induced shock wave into the air above the sample surface was imaged on a microsecond timescale with a high-speed camera recording multiple frames from each laser shot; the excitation of energetic materials produces larger heat-affected zones in the surrounding atmosphere (facilitating deflagration of particles ejected from the sample surface), results in the formation of additional shock fronts, and generates faster external shock front velocities (>750 m s(-1)) compared to non-energetic materials (550-600 m s(-1)). Non-explosive materials that undergo exothermic chemical reactions in air at high temperatures such as ammonium nitrate and magnesium sulfate produce shock velocities which exceed those of the inert materials but are less than those generated by the exothermic reactions of explosive materials (650-700 m s(-1)). The most powerful explosives produced the highest shock velocities. A comparison to several existing shock models demonstrated that no single model describes the shock propagation for both non-energetic and energetic materials. The influence of the exothermic chemical reactions initiated by the pulsed laser on the velocity of the laser-induced shock waves has thus been demonstrated for the first time.

Effect of graphite particle size and content on the formation mechanism of detonation polycrystalline diamond

NASA Astrophysics Data System (ADS)

Tong, Y.; Cao, Y.; Liu, R.; Shang, S. Y.; Huang, F. L.

2018-03-01

The formation mechanism of detonation polycrystalline diamond (DPD) generated from the detonation of a mixed RDX/graphite explosive is investigated. It is found experimentally that the DPD conversion rate decreases with both the content and the particle size of the graphite. Moreover, the particle sizes of the generated DPD powder are analyzed, which shows that, with the decrease in the graphite particle size, the mean number diameter of DPD decreases, but the mean volume diameter increases. In addition, with the help of scanning electron microscopy, it is observed that the in situ phase change occurs in the graphite particles, by which the small particles combine to form numerous large DPD particles. Based on both the experimental data and the classical ZND detonation model, we divide such a DPD synthesis process into two stages: In the first stage, the in situ phase change from graphite to diamond is dominant, supplemented by some coalescence growth at high pressure and temperature, which is affected mainly by the detonation performance of the mixed explosive under consideration. In the second stage, the graphitization of DPD caused by the residual heat is dominant, which is affected mainly by the unloading rate of the particle temperature.

Pretreatment of paper tube residuals for improved biogas production.

PubMed

Teghammar, Anna; Yngvesson, Johan; Lundin, Magnus; Taherzadeh, Mohammad J; Horváth, Ilona Sárvári

2010-02-01

Paper tube residuals, which are lignocellulosic wastes, have been studied as substrate for biogas (methane) production. Steam explosion and nonexplosive hydrothermal pretreatment, in combination with sodium hydroxide and/or hydrogen peroxide, have been used to improve the biogas production. The treatment conditions of temperature, time and addition of NaOH and H(2)O(2) were statistically evaluated for methane production. Explosive pretreatment was more successful than the nonexplosive method, and gave the best results at 220 degrees C, 10 min, with addition of both 2% NaOH and 2% H(2)O(2). Digestion of the pretreated materials at these conditions yielded 493 N ml/g VS methane which was 107% more than the untreated materials. In addition, the initial digestion rate was improved by 132% compared to the untreated samples. The addition of NaOH was, besides the explosion effect, the most important factor to improve the biogas production.

Associating cooking additives with sodium hydroxide to pretreat bamboo residues for improving the enzymatic saccharification and monosaccharides production.

PubMed

Huang, Caoxing; He, Juan; Wang, Yan; Min, Douyong; Yong, Qiang

2015-10-01

Cooking additive pulping technique is used in kraft mill to increase delignification degree and pulp yield. In this work, cooking additives were firstly applied in the sodium hydroxide pretreatment for improving the bioconversion of bamboo residues to monosaccharides. Meanwhile, steam explosion and sulfuric acid pretreatments were also carried out on the sample to compare their impacts on monosaccharides production. Results indicated that associating anthraquinone with sodium hydroxide pretreatment showed the best performance in improving the original carbohydrates recovery, delignification, enzymatic saccharification, and monosaccharides production. After consecutive pretreatment and enzymatic saccharification process, 347.49 g, 307.48 g, 142.93 g, and 87.15 g of monosaccharides were released from 1000 g dry bamboo residues pretreated by sodium hydroxide associating with anthraquinone, sodium hydroxide, steam explosion and sulfuric acid, respectively. The results suggested that associating cooking additive with sodium hydroxide is an effective pretreatment for bamboo residues to enhance enzymatic saccharification for monosaccharides production. Copyright © 2015 Elsevier Ltd. All rights reserved.

Recent advances and remaining challenges for the spectroscopic detection of explosive threats.

PubMed

Fountain, Augustus W; Christesen, Steven D; Moon, Raphael P; Guicheteau, Jason A; Emmons, Erik D

2014-01-01

In 2010, the U.S. Army initiated a program through the Edgewood Chemical Biological Center to identify viable spectroscopic signatures of explosives and initiate environmental persistence, fate, and transport studies for trace residues. These studies were ultimately designed to integrate these signatures into algorithms and experimentally evaluate sensor performance for explosives and precursor materials in existing chemical point and standoff detection systems. Accurate and validated optical cross sections and signatures are critical in benchmarking spectroscopic-based sensors. This program has provided important information for the scientists and engineers currently developing trace-detection solutions to the homemade explosive problem. With this information, the sensitivity of spectroscopic methods for explosives detection can now be quantitatively evaluated before the sensor is deployed and tested.

Hypervelocity Impact Analysis of International Space Station Whipple and Enhanced Stuffed Whipple Shields

DTIC Science & Technology

2004-12-01

29 Figure 6. Flash Radiography Images of the Debris Cloud and Ejecta...hand, are not predictable. Explosions can occur because of the inadvertent mixing of propellant and oxidizer or the over-pressurization of...residual propellant due to spacecraft heating. Over-pressurized batteries may also cause explosions. Based on statistical analysis of known hypervelocity

Detection of Nuclear Explosions Using Infrasound Techniques

DTIC Science & Technology

2007-12-01

signal correlation between array elements in these arrays can seriously limit the reliable detection of infrasound generated ...goals of this investigation are to identify problems with the detection of explosion- generated infrasonic signals at stations in the global infrasound ...restricted to a thermospheric waveguide. The second part is focused on the limitations imposed on array detection of explosion- generated infrasound

Source spectral variation and yield estimation for small, near-source explosions

NASA Astrophysics Data System (ADS)

Yoo, S.; Mayeda, K. M.

2012-12-01

Significant S-wave generation is always observed from explosion sources which can lead to difficulty in discriminating explosions from natural earthquakes. While there are numerous S-wave generation mechanisms that are currently the topic of significant research, the mechanisms all remain controversial and appear to be dependent upon the near-source emplacement conditions of that particular explosion. To better understand the generation and partitioning of the P and S waves from explosion sources and to enhance the identification and discrimination capability of explosions, we investigate near-source explosion data sets from the 2008 New England Damage Experiment (NEDE), the Humble-Redwood (HR) series of explosions, and a Massachusetts quarry explosion experiment. We estimate source spectra and characteristic source parameters using moment tensor inversions, direct P and S waves multi-taper analysis, and improved coda spectral analysis using high quality waveform records from explosions from a variety of emplacement conditions (e.g., slow/fast burning explosive, fully tamped, partially tamped, single/ripple-fired, and below/above ground explosions). The results from direct and coda waves are compared to theoretical explosion source model predictions. These well-instrumented experiments provide us with excellent data from which to document the characteristic spectral shape, relative partitioning between P and S-waves, and amplitude/yield dependence as a function of HOB/DOB. The final goal of this study is to populate a comprehensive seismic source reference database for small yield explosions based on the results and to improve nuclear explosion monitoring capability.

Standoff detection of explosives: a challenging approach for optical technologies

NASA Astrophysics Data System (ADS)

Désilets, S.; Hô, N.; Mathieu, P.; Simard, J. R.; Puckrin, E.; Thériault, J. M.; Lavoie, H.; Théberge, F.; Babin, F.; Gay, D.; Forest, R.; Maheux, J.; Roy, G.; Châteauneuf, M.

2011-06-01

Standoff detection of explosives residues on surfaces at few meters was made using optical technologies based on Raman scattering, Laser-Induced Breakdown Spectroscopy (LIBS) and passive standoff FTIR radiometry. By comparison, detection and analysis of nanogram samples of different explosives was made with a microscope system where Raman scattering from a micron-size single point illuminated crystal of explosive was observed. Results from standoff detection experiments using a telescope were compared to experiments using a microscope to find out important parameters leading to the detection. While detection and spectral identification of the micron-size explosive particles was possible with a microscope, standoff detection of these particles was very challenging due to undesired light reflected and produced by the background surface or light coming from other contaminants. Results illustrated the challenging approach of detecting at a standoff distance the presence of low amount of micron or submicron explosive particles.

Projectile-generating explosive access tool

DOEpatents

Jakaboski, Juan-Carlos; Hughs, Chance G; Todd, Steven N

2013-06-11

A method for generating a projectile using an explosive device that can generate a projectile from the opposite side of a wall from the side where the explosive device is detonated. The projectile can be generated without breaching the wall of the structure or container. The device can optionally open an aperture in a solid wall of a structure or a container and form a high-kinetic-energy projectile from the portion of the wall removed to create the aperture.

Experimental investigation of powerful pulse current generators based on capacitive storage and explosive magnetic generators

NASA Astrophysics Data System (ADS)

Shurupov, A. V.; Zavalova, V. E.; Kozlov, A. V.; Shurupov, M. A.; Povareshkin, M. N.; Kozlov, A. A.; Shurupova, N. P.

2018-01-01

Experimental models of microsecond duration powerful generators of current pulses on the basis of explosive magnetic generators and voltage impulse generator have been developed for the electromagnetic pulse effects on energy facilities to verify their stability. Exacerbation of voltage pulse carried out through the use of electro explosive current interrupter made of copper wires with diameters of 80 and 120 μm. Experimental results of these models investigation are represented. Voltage fronts about 100 ns and the electric field strength of 800 kV/m are registered.

Capillary-driven microfluidic paper-based analytical devices for lab on a chip screening of explosive residues in soil.

PubMed

Ueland, Maiken; Blanes, Lucas; Taudte, Regina V; Stuart, Barbara H; Cole, Nerida; Willis, Peter; Roux, Claude; Doble, Philip

2016-03-04

A novel microfluidic paper-based analytical device (μPAD) was designed to filter, extract, and pre-concentrate explosives from soil for direct analysis by a lab on a chip (LOC) device. The explosives were extracted via immersion of wax-printed μPADs directly into methanol soil suspensions for 10min, whereby dissolved explosives travelled upwards into the μPAD circular sampling reservoir. A chad was punched from the sampling reservoir and inserted into a LOC well containing the separation buffer for direct analysis, avoiding any further extraction step. Eight target explosives were separated and identified by fluorescence quenching. The minimum detectable amounts for all eight explosives were between 1.4 and 5.6ng with recoveries ranging from 53-82% from the paper chad, and 12-40% from soil. This method provides a robust and simple extraction method for rapid identification of explosives in complex soil samples. Copyright © 2016 Elsevier B.V. All rights reserved.

Surface waves generated by shallow underwater explosions

NASA Technical Reports Server (NTRS)

Falade, A.; Holt, M.

1978-01-01

Surface water waves generated by surface and near surface point explosions are calculated. Taking the impulse distribution imparted at the water surface by the explosion as the overriding mechanism for transferring energy of the explosive to surface wave motion, the linearized theory of Kranzer and Keller is used to obtain the wave displacement in the far field. The impulse distribution is obtained by integrating the pressure wave over an appropriate time interval on a horizontal surface just beneath the undisturbed water surface. For surface explosions, a modified form of the similarity method first used by Collins and Holt is used to obtain the flow field. In the case of submerged explosions, the flow field is estimated by making necessary modifications to Sedov's similarity solution to account for the venting that accompanies the interaction of the leading (blast) wave with the ocean surface. Surface waves generated by a charge at six depths of placement (0.15 m, 0.30 m, 0.61 m, 0.91 m, 1.37 m, 3.05 m) are considered in addition to surface explosions. The results seem to support the existence of an upper critical depth phenomenon (of the type already established for chemical explosions) for point (nuclear) explosions.

Integral process assessment of sugarcane agricultural crop residues conversion to ethanol.

PubMed

Manfredi, Adriana Paola; Ballesteros, Ignacio; Sáez, Felicia; Perotti, Nora Inés; Martínez, María Alejandra; Negro, María José

2018-07-01

This work focuses a whole process assessment on post-harvesting sugarcane residues for 2G ethanol production by different saccharification-fermentation conditions at high solids loading, performed after steam explosion, alkaline and acidic pretreatments. Carbohydrate recoveries and enzymatic digestibility results showed that alkali and steam explosion pretreatments were effective for the biomass assayed. Due to a significant improvement (60%) of the glucose released by combining hemicellulases and cellulases only after the NaOH pretreatment, the most favorable process settled comprised an alkali-based pretreatment followed by a pre-saccharification and simultaneous saccharification and fermentation (PSSF). The produced ethanol reached 4.8% (w/w) as a result of an 80% conversion of the glucose from the pretreated biomass. Finally, an ethanol concentration of 3.2% (w/w) was obtained by means of a steam explosion followed by PSSF, representing a suitable start point to further develop a low environmental impact alternative for ethanol production. Copyright © 2018 Elsevier Ltd. All rights reserved.

Techno-economical study of biogas production improved by steam explosion pretreatment.

PubMed

Shafiei, Marzieh; Kabir, Maryam M; Zilouei, Hamid; Sárvári Horváth, Ilona; Karimi, Keikhosro

2013-11-01

Economic feasibility of steam explosion pretreatment for improvement of biogas production from wheat straw and paper tube residuals was investigated. The process was simulated by Aspen plus ®, and the economical feasibility of five different plant capacities was studied by Aspen Process Economic Analyzer. Total project investment of a plant using paper tube residuals or wheat straw was 63.9 or 61.8 million Euros, respectively. The manufacturing cost of raw biogas for these two feedstocks was calculated to 0.36 or 0.48 €/m(3) of methane, respectively. Applying steam explosion pretreatment resulted in 13% higher total capital investment while significantly improved the economy of the biogas plant and decreased the manufacturing cost of methane by 36%. The sensitivity analysis showed that 5% improvement in the methane yield and 20% decrease in the raw material price resulted in 5.5% and 8% decrease in the manufacturing cost of methane, respectively. Copyright © 2013 Elsevier Ltd. All rights reserved.

Simultaneous determination of inorganic anions and cations in explosive residues by ion chromatography.

PubMed

Meng, Hong-Bo; Wang, Tian-Ran; Guo, Bao-Yuan; Hashi, Yuki; Guo, Can-Xiong; Lin, Jin-Ming

2008-07-15

A non-suppressed ion chromatographic method by connecting anion-exchange and cation-exchange columns directly was developed for the separation and determination of five inorganic anions (sulfate, nitrate, chloride, nitrite, and chlorate) and three cations (sodium, ammonium, and potassium) simultaneously in explosive residues. The mobile phase was composed of 3.5mM phthalic acid with 2% acetonitrile and water at flow rate of 0.2 mL/min. Under the optimal conditions, the eight inorganic ions were completely separated and detected simultaneously within 16 min. The limits of detection (S/N=3) of the anions and cations were in the range of 50-100 microg/L and 150-320 microg/L, respectively, the linear correlation coefficients were 0.9941-0.9996, and the R.S.D. of retention time and peak area were 0.10-0.29% and 5.65-8.12%, respectively. The method was applied successfully to the analysis of the explosive samples with satisfactory results.

[Determination of inorganic ions in explosive residues by capillary zone electrophoresis].

PubMed

Feng, Junhe; Guo, Baoyuan; Lin, Jin-Ming; Xu, Jianzhong; Zhou, Hong; Sun, Yuyou; Liu, Yao; Quan, Yangke; Lu, Xiaoming

2008-11-01

Five anions (chlorate, perchlorate, nitrate, nitrite, and sulfate) and two cations (ammonium and potassium) in explosive residues have been separated and determined by capillary zone electrophoresis (CZE) with indirect ultraviolet detection. The electrolyte buffer for the cation separation was 10 mmol/L pyridine (pH 4.5) -3 mmol/L 18-crown-6-ether. Ammonium and potassium ions were baseline separated in less than 2.6 min with the detection limits of 0.10 mg/L and 0.25 mg/L (S/N = 3), respectively. The electrolyte buffer for the anion separation consisted of 40 mmol/L boric acid-1.8 mmol/L potassium dichromate-2 mmol/L sodium tetraborate (pH 8.6), and tetramethyl ammonium hydroxide (TMAOH) was used as electroosmotic flow modifier. All five anions were well separated in less than 4.6 min with the detection limit range of 0.10 - 1.85 mg/L (S/N = 3). The method was successfully used in real sample investigations to confirm the type of explosives.

Evaluation of a peat moss plus soybean oil (PMSO) technology for reducing explosive residue transport to groundwater at military training ranges under field conditions.

PubMed

Fuller, Mark E; Schaefer, Charles E; Steffan, Robert J

2009-11-01

An evaluation of peat moss plus crude soybean oil (PMSO) for mitigation of explosive contamination of soil at military facilities was performed using large soil lysimeters under field conditions. Actual range soils were used, and two PMSO preparations with different ratios of peat moss:soybean oil (1:1, PO1; 1:2, PO2) were compared to a control lysimeter that received no PMSO. PMSO was applied as a 10 cm layer on top of the soil, and Composition B detonation residues from a 55-mm mortar round were applied at the surface of each of the lysimeters. Dissolution of the residues occurred during natural precipitation events over the course of 18 months. Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) emanating from the Composition B residues were significantly reduced by the PO2 PMSO material compared to the untreated control. Soil pore water RDX concentrations and RDX fluxes were reduced over 100-fold compared to the control plots at comparable depths. Residual RDX in the soil profile was also significantly lower in the PMSO treated plots. PO1 PMSO resulted in lower reductions in RDX transport than the PO2 PMSO. The transport of the RDX breakdown product hexahydro-1-nitroso-3,5-dinitro-1,3,5-triazine (MNX) was also greatly reduced by the PMSO materials. Results were in general agreement with a previously developed fate and transport model describing PMSO effectiveness. These results demonstrate the potential effectiveness of the inexpensive and environmentally benign PMSO technology for reducing the subsurface loading of explosives at training ranges and other military facilities.

Near-Source Scattering of Explosion-Generated Rg: Insight From Difference Spectrograms of NTS Explosions

NASA Astrophysics Data System (ADS)

Gupta, I.; Chan, W.; Wagner, R.

2005-12-01

Several recent studies of the generation of low-frequency Lg from explosions indicate that the Lg wavetrain from explosions contains significant contributions from (1) the scattering of explosion-generated Rg into S and (2) direct S waves from the non-spherical spall source associated with a buried explosion. The pronounced spectral nulls observed in Lg spectra of Yucca Flats (NTS) and Semipalatinsk explosions (Patton and Taylor, 1995; Gupta et al., 1997) are related to Rg excitation caused by spall-related block motions in a conical volume over the shot point, which may be approximately represented by a compensated linear vector dipole (CLVD) source (Patton et al., 2005). Frequency-dependent excitation of Rg waves should be imprinted on all scattered P, S and Lg waves. A spectrogram may be considered as a three-dimensional matrix of numbers providing amplitude and frequency information for each point in the time series. We found difference spectrograms, derived from a normal explosion and a closely located over-buried shot recorded at the same common station, to be remarkably useful for an understanding of the origin and spectral contents of various regional phases. This technique allows isolation of source characteristics, essentially free from path and recording site effects, since the overburied shot acts as the empirical Green's function. Application of this methodology to several pairs of closely located explosions shows that the scattering of explosion-generated Rg makes significant contribution to not only Lg and its coda but also to the two other regional phases Pg (presumably by the scattering of Rg into P) and Sn. The scattered energy, identified by the presence of a spectral null at the appropriate frequency, generally appears to be more prominent in the somewhat later-arriving sections of Pg, Sn, and Lg than in the initial part. Difference spectrograms appear to provide a powerful new technique for understanding the mechanism of near-source scattering of explosion-generated Rg and its contribution to various regional phases.

Projectile-generating explosive access tool

DOEpatents

Jakaboski, Juan-Carlos [Albuquerque, NM; Hughs, Chance G [Tijeras, NM; Todd, Steven N [Rio Rancho, NM

2011-10-18

An explosive device that can generate a projectile from the opposite side of a wall from the side where the explosive device is detonated. The projectile can be generated without breaching the wall of the structure or container. The device can optionally open an aperture in a solid wall of a structure or a container and form a high-kinetic-energy projectile from the portion of the wall removed to create the aperture.

Explosively Generated Plasmas: Measurement and Models of Shock Generation and Material Interactions

NASA Astrophysics Data System (ADS)

Emery, Samuel; Elert, Mark; Giannuzzi, Paul; Le, Ryan; McCarthy, Daniel; Schweigert, Igor

2017-06-01

Explosively generated plasmas (EGPs) are created by the focusing of a shock produced from an explosive driver via a conical waveguide. In the waveguide, the gases from the explosive along with the trapped air are accelerated and compressed (via Mach stemming) to such extent that plasma is produced. These EGPs have been measured in controlled experiments to achieve temperatures on the order of 1 eV and velocities as high as 25 km/s. We have conducted a combined modeling and measurement effort to increase the understanding for design purposes of the shock generation of EGPs and the interaction of EGP with explosive materials. Such efforts have led to improved measures of pressure and temperature, spatial structure of the plasma, and the decomposition/deflagration behavior of RDX upon exposure to an EGP. Funding provided by the Environmental Security Technology Certification Program (ESTCP) Munitions Response program area.

Incorporation of 2,4,6-trinitrotoluene (TNT) transforming bacteria into explosive formulations.

PubMed

Nyanhongo, G S; Aichernig, N; Ortner, M; Steiner, Walter; Guebitz, G M

2009-06-15

Pseudomonas putida GG04 and Bacillus SF have been successfully incorporated into an explosive formulation to enhance biotransformation of TNT residues and/or explosives which fail to detonate due to technical faults. The incorporation of the microorganisms into the explosive did not affect the quality of the explosive (5 years storage) in terms of detonation velocity while complete biotransformation of TNT moieties upon transfer in liquid media was observed after 5 days. The incorporated microorganisms reduced TNT sequentially leading to the formation of hydroxylaminodinitrotoluenes (HADNT), 4-amino-2,6-dinitrotoluenes; 2-amino-4,6-dinitrotoluenes, different azoxy compounds; 2,6-diaminonitrotoluenes (2,4-DAMNT) and 2,4-diaminonitrotoluenes (2,6-DAMNT). However, the accumulation of AMDNT and DAMNT (major dead-end metabolites) was effectively prevented by incorporating guaiacol and catechol during the biotransformation process.

Generation of Shear Motion from an Isotropic Explosion Source by Scattering in Heterogeneous Media

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hirakawa, Evan; Pitarka, Arben; Mellors, Robert

One challenging task in explosion seismology is the development of physical models for explaining the generation of S waves during underground explosions. Recent analysis of ground motion from chemical explosions during the Source Physics Experiment (Pitarka et al., 2015) suggests that, although a large component of shear motion was generated directly at the source, additional scattering from heterogeneous velocity structure and topography is necessary to better match the recorded data. In our paper, we used a stochastic representation of small-scale velocity variability to produce high-frequency scattering and to analyze its implication on shear-motion generation during underground explosions. In our stochasticmore » velocity model, the key parameters that affect scattering are the correlation length and the relative amplitude of velocity perturbations. Finally, based on finite-difference simulations of elastic wave propagation from an isotropic explosion source, we find that higher velocity perturbations result in larger shear motion, whereas the correlation length, which controls the scatterers size, affects the frequency range at which relative transverse motion is larger.« less

Generation of Shear Motion from an Isotropic Explosion Source by Scattering in Heterogeneous Media

DOE PAGES

Hirakawa, Evan; Pitarka, Arben; Mellors, Robert

2016-07-19

One challenging task in explosion seismology is the development of physical models for explaining the generation of S waves during underground explosions. Recent analysis of ground motion from chemical explosions during the Source Physics Experiment (Pitarka et al., 2015) suggests that, although a large component of shear motion was generated directly at the source, additional scattering from heterogeneous velocity structure and topography is necessary to better match the recorded data. In our paper, we used a stochastic representation of small-scale velocity variability to produce high-frequency scattering and to analyze its implication on shear-motion generation during underground explosions. In our stochasticmore » velocity model, the key parameters that affect scattering are the correlation length and the relative amplitude of velocity perturbations. Finally, based on finite-difference simulations of elastic wave propagation from an isotropic explosion source, we find that higher velocity perturbations result in larger shear motion, whereas the correlation length, which controls the scatterers size, affects the frequency range at which relative transverse motion is larger.« less

Identification of homemade inorganic explosives by ion chromatographic analysis of post-blast residues.

PubMed

Johns, Cameron; Shellie, Robert A; Potter, Oscar G; O'Reilly, John W; Hutchinson, Joseph P; Guijt, Rosanne M; Breadmore, Michael C; Hilder, Emily F; Dicinoski, Greg W; Haddad, Paul R

2008-02-29

Anions and cations of interest for the post-blast identification of homemade inorganic explosives were separated and detected by ion chromatographic (IC) methods. The ionic analytes used for identification of explosives in this study comprised 18 anions (acetate, benzoate, bromate, carbonate, chlorate, chloride, chlorite, chromate, cyanate, fluoride, formate, nitrate, nitrite, perchlorate, phosphate, sulfate, thiocyanate and thiosulfate) and 12 cations (ammonium, barium(II), calcium(II), chromium(III), ethylammonium, magnesium(II), manganese(II), methylammonium, potassium(I), sodium(I), strontium(II), and zinc(II)). Two IC separations are presented, using suppressed IC on a Dionex AS20 column with potassium hydroxide as eluent for anions, and non-suppressed IC for cations using a Dionex SCS 1 column with oxalic acid/acetonitrile as eluent. Conductivity detection was used in both cases. Detection limits for anions were in the range 2-27.4ppb, and for cations were in the range 13-115ppb. These methods allowed the explosive residue ions to be identified and separated from background ions likely to be present in the environment. Linearity (over a calibration range of 0.05-50ppm) was evaluated for both methods, with r(2) values ranging from 0.9889 to 1.000. Reproducibility over 10 consecutive injections of a 5ppm standard ranged from 0.01 to 0.22% relative standard deviation (RSD) for retention time and 0.29 to 2.16%RSD for peak area. The anion and cation separations were performed simultaneously by using two Dionex ICS-2000 chromatographs served by a single autoinjector. The efficacy of the developed methods was demonstrated by analysis of residue samples taken from witness plates and soils collected following the controlled detonation of a series of different inorganic homemade explosives. The results obtained were also confirmed by parallel analysis of the same samples by capillary electrophoresis (CE) with excellent agreement being obtained.

Energetic Residues and Crater Geometries from the Firing of 120-mm High-Explosive Mortar Projectiles into Eagle River Flats, June 2007

DTIC Science & Technology

2008-07-01

samples. ERDC/CRREL TR-08-10 15 c. US DH-48 isokinetic sampler. Figure 7 (cont’d). The second activity was the collection of soil at the...3 0.28 Mc1/3 0.3 Mc1/3 Ra Apparent radius of the crater in meters Mc Mass of the explosive charge in kilograms Da Apparent depth of the crater in... meters The apparent depth and radius of a crater will increase with the depth of explosive charge below the surface down to a maximum depth called

Monte Carlo simulation of explosive detection system based on a Deuterium-Deuterium (D-D) neutron generator.

PubMed

Bergaoui, K; Reguigui, N; Gary, C K; Brown, C; Cremer, J T; Vainionpaa, J H; Piestrup, M A

2014-12-01

An explosive detection system based on a Deuterium-Deuterium (D-D) neutron generator has been simulated using the Monte Carlo N-Particle Transport Code (MCNP5). Nuclear-based explosive detection methods can detect explosives by identifying their elemental components, especially nitrogen. Thermal neutron capture reactions have been used for detecting prompt gamma emission (10.82MeV) following radiative neutron capture by (14)N nuclei. The explosive detection system was built based on a fully high-voltage-shielded, axial D-D neutron generator with a radio frequency (RF) driven ion source and nominal yield of about 10(10) fast neutrons per second (E=2.5MeV). Polyethylene and paraffin were used as moderators with borated polyethylene and lead as neutron and gamma ray shielding, respectively. The shape and the thickness of the moderators and shields are optimized to produce the highest thermal neutron flux at the position of the explosive and the minimum total dose at the outer surfaces of the explosive detection system walls. In addition, simulation of the response functions of NaI, BGO, and LaBr3-based γ-ray detectors to different explosives is described. Copyright © 2014 Elsevier Ltd. All rights reserved.

Fabrication of a self-assembled and flexible SERS nanosensor for explosive detection at parts-per-quadrillion levels from fingerprints.

PubMed

Liyanage, Thakshila; Rael, Ashur; Shaffer, Sidney; Zaidi, Shozaf; Goodpaster, John V; Sardar, Rajesh

2018-04-30

Apart from high sensitivity and selectivity of surface-enhanced Raman scattering (SERS)-based trace explosive detection, efficient sampling of explosive residue from real world surfaces is very important for homeland security applications. Herein, we demonstrate an entirely new SERS nanosensor fabrication approach. The SERS nanosensor was prepared by self-assembling chemically synthesized gold triangular nanoprisms (Au TNPs), which we show display strong electromagnetic field enhancements at the sharp tips and edges, onto a pressure-sensitive flexible adhesive film. Our SERS nanosensor provides excellent SERS activity (enhancement factor = ∼6.0 × 106) and limit of detection (as low as 56 parts-per-quadrillions) with high selectivity by chemometric analyses among three commonly military high explosives (TNT, RDX, and PETN). Furthermore, the SERS nanosensors present excellent reproducibility (<4.0% relative standard deviation at 1.0 μM concentration) and unprecedentedly high stability with a "shelf life" of at least 5 months. Finally, TNT and PETN were analyzed and quantified by transferring solid explosive residues from fingerprints left on solid surfaces to the SERS nanosensor. Taken together, the demonstrated sensitivity, selectivity, and reliability of the measurements as well as with the excellent shelf life of our SERS nanosensors obviate the need for complicated sample processing steps required for other analytical techniques, and thus these nanosensors have tremendous potential not only in the field of measurement science but also for homeland security applications to combat acts of terror and military threats.

Ultrafast Laser Interaction Processes for LIBS and Other Sensing Technologies

DTIC Science & Technology

2013-04-05

Propagation of ultrashort pulses through water, Optics Express, (02 2007): . doi: 12/02/2009 8.00 Z. Chen, S. Mao. Femtosecond laser -induced electronic...CO2 double- pulse laser -induced breakdown spectroscopy for explosive residues detection" SPIE Defense, Security, Sensing; Orlando, FL, USA; 04/07...Matthieu Baudelet, Michael Sigman, Paul J Dagdigian, Martin C. Richardson, "Nd:YAG-CO2 Double- Pulse Laser Induced Breakdown Spectroscopy for Explosive

Grapefruit photonic crystal fiber long period gratings sensor for DNT sensing application

NASA Astrophysics Data System (ADS)

Tao, Chuanyi; Li, Jingke; Zhu, Tenglong

2016-10-01

The detection of explosives and their residues is of great importance in public health, antiterrorism and homeland security applications. The vapor pressures of most explosive compounds are extremely low and attenuation of the available vapor is often great due to diffusion in the environment, making direct vapor detection difficult. In reality bomb dogs are still the most efficient way to quickly detect explosives on the spot. Many formulations of TNT-based explosives contain DNT residues. The use of long period gratings (LPGs) formed in grapefruit photonic crystal fiber (PCF) with thin-film overlay coated on the inner surface of air holes for gas sensing is demonstrated. A gas analyteinduced index variation of the thin-film immobilized on the inner surface of the holey region of the fiber can be observed by a shift of the resonance wavelength. We demonstrate a 2,4-dinitrotoluene (DNT) sensor using grapefruit PCF-LPGs. Coating with gas-sensitive thin-film on the inner surface of the air holes of the grapefruit PCF-LPG could provide a promising platform for rapid highly sensitive gas sensing. A rapid and highly sensitive detection of DNT has been demonstrated using the grapefruit PCF-LPG sensor to show the feasibility of the proposed approach.

Advanced recognition of explosives in traces on polymer surfaces using LIBS and supervised learning classifiers.

PubMed

Serrano, Jorge; Moros, Javier; Sánchez, Carlos; Macías, Jorge; Laserna, J Javier

2014-01-02

The large similarity existing in the spectral emissions collected from organic compounds by laser-induced breakdown spectroscopy (LIBS) is a limiting factor for the use of this technology in the real world. Specifically, among the most ambitious challenges of today's LIBS involves the recognition of an organic residue when neglected on the surface of an object of identical nature. Under these circumstances, the development of an efficient algorithm to disclose the minute differences within this highly complex spectral information is crucial for a realistic application of LIBS in countering explosive threats. An approach cemented on scatter plots of characteristic emission features has been developed to identify organic explosives when located on polymeric surfaces (teflon, nylon and polyethylene). By using selected spectral variables, the approach allows to design a concise classifier for alerting when one of four explosives (DNT, TNT, RDX and PETN) is present on the surface of the polymer. Ordinary products (butter, fuel oil, hand cream, olive oil and motor oil) cause no confusion in the decisions taken by the classifier. With rates of false negatives and false positives below 5%, results demonstrate that the classification algorithm enables to label residues according to their harmful nature in the most demanding scenario for a LIBS sensor. Copyright © 2013 Elsevier B.V. All rights reserved.

Chemical Sensing of Unexploded Ordnance with the Mobile Underwater Survey System (MUDSS)

NASA Technical Reports Server (NTRS)

Darrach, M. R.; Chutjian, A.

1995-01-01

The ability to sense explosives residues in the marine environment is a critical tool for identification and classification of underwater unexploded ordnance (UXO). Trace explosives signatures of TNT and DNT have been extracted from multiple sediment samples adjacent to unexploded undersea ordnance at Halifax Harbor, Canada. The ordnance was hurled into the harbor during a massive explosion fifty years earlier, in 1945 after World War II had ended. Laboratory sediment extractions were made using the solid-phase microextraction (SPME) method in seawater, and detection using the Reversal Electron Attachment Detection (READ) technique and, in the case of DNT, a commercial gas-chromatography/mass spectrometer (GC/MS). Results show that, after more than 50 years in the environment, ordnance which appeared to be physically intact gave good explosives signatures at the parts-per-billion level, whereas ordnance which had been cracked open during the explosion gave no signatures at the 10 parts-per-trillion sensitivity level. These measurements appear to provide the first reported data of explosives signatures from undersea UXOs.

Multivariate analysis of standoff laser-induced breakdown spectroscopy spectra for classification of explosive-containing residues

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Lucia, Frank C. Jr.; Gottfried, Jennifer L.; Munson, Chase A.

2008-11-01

A technique being evaluated for standoff explosives detection is laser-induced breakdown spectroscopy (LIBS). LIBS is a real-time sensor technology that uses components that can be configured into a ruggedized standoff instrument. The U.S. Army Research Laboratory has been coupling standoff LIBS spectra with chemometrics for several years now in order to discriminate between explosives and nonexplosives. We have investigated the use of partial least squares discriminant analysis (PLS-DA) for explosives detection. We have extended our study of PLS-DA to more complex sample types, including binary mixtures, different types of explosives, and samples not included in the model. We demonstrate themore » importance of building the PLS-DA model by iteratively testing it against sample test sets. Independent test sets are used to test the robustness of the final model.« less

SOLID PHASE MICROEXTRACTION SAMPLING OF HIGH EXPLOSIVE RESIDUES IN THE PRESENCE OF RADIONUCLIDES AND RADIONUCLIDE SURROGATE METALS

DOE Office of Scientific and Technical Information (OSTI.GOV)

Duff, M; S Crump, S; Robert02 Ray, R

2007-04-13

The Federal Bureau of Investigation (FBI) Laboratory currently does not have on site facilities for handling radioactive evidentiary materials and there are no established FBI methods or procedures for decontaminating high explosive (HE) evidence while maintaining evidentiary value. One experimental method for the isolation of HE residue involves using solid phase microextraction or SPME fibers to remove residue of interest. Due to their high affinity for organics, SPME fibers should have little affinity for most metals. However, no studies have measured the affinity of radionuclides for SPME fibers. The focus of this research was to examine the affinity of dissolvedmore » radionuclide ({sup 239/240}Pu, {sup 238}U, {sup 237}Np, {sup 85}Sr, {sup 133}Ba, {sup 137}Cs, {sup 60}Co and {sup 226}Ra) and stable radionuclide surrogate metals (Sr, Co, Ir, Re, Ni, Ba, Cs, Nb, Zr, Ru, and Nd) for SPME fibers at the exposure conditions that favor the uptake of HE residues. Our results from radiochemical and mass spectrometric analyses indicate these metals have little measurable affinity for these SPME fibers during conditions that are conducive to HE residue uptake with subsequent analysis by liquid or gas phase chromatography with mass spectrometric detection.« less

Identification of inorganic ions in post-blast explosive residues using portable CE instrumentation and capacitively coupled contactless conductivity detection.

PubMed

Hutchinson, Joseph P; Johns, Cameron; Breadmore, Michael C; Hilder, Emily F; Guijt, Rosanne M; Lennard, Chris; Dicinoski, Greg; Haddad, Paul R

2008-11-01

Novel CE methods have been developed on portable instrumentation adapted to accommodate a capacitively coupled contactless conductivity detector for the separation and sensitive detection of inorganic anions and cations in post-blast explosive residues from homemade inorganic explosive devices. The methods presented combine sensitivity and speed of analysis for the wide range of inorganic ions used in this study. Separate methods were employed for the separation of anions and cations. The anion separation method utilised a low conductivity 70 mM Tris/70 mM CHES aqueous electrolyte (pH 8.6) with a 90 cm capillary coated with hexadimethrine bromide to reverse the EOF. Fifteen anions could be baseline separated in 7 min with detection limits in the range 27-240 microg/L. A selection of ten anions deemed most important in this application could be separated in 45 s on a shorter capillary (30.6 cm) using the same electrolyte. The cation separation method was performed on a 73 cm length of fused-silica capillary using an electrolyte system composed of 10 mM histidine and 50 mM acetic acid, at pH 4.2. The addition of the complexants, 1 mM hydroxyisobutyric acid and 0.7 mM 18-crown-6 ether, enhanced selectivity and allowed the separation of eleven inorganic cations in under 7 min with detection limits in the range 31-240 microg/L. The developed methods were successfully field tested on post-blast residues obtained from the controlled detonation of homemade explosive devices. Results were verified using ion chromatographic analyses of the same samples.

Influence of variable selection on partial least squares discriminant analysis models for explosive residue classification

NASA Astrophysics Data System (ADS)

De Lucia, Frank C., Jr.; Gottfried, Jennifer L.

2011-02-01

Using a series of thirteen organic materials that includes novel high-nitrogen energetic materials, conventional organic military explosives, and benign organic materials, we have demonstrated the importance of variable selection for maximizing residue discrimination with partial least squares discriminant analysis (PLS-DA). We built several PLS-DA models using different variable sets based on laser induced breakdown spectroscopy (LIBS) spectra of the organic residues on an aluminum substrate under an argon atmosphere. The model classification results for each sample are presented and the influence of the variables on these results is discussed. We found that using the whole spectra as the data input for the PLS-DA model gave the best results. However, variables due to the surrounding atmosphere and the substrate contribute to discrimination when the whole spectra are used, indicating this may not be the most robust model. Further iterative testing with additional validation data sets is necessary to determine the most robust model.

The recovery and analysis of mitochondrial DNA from exploded pipe bombs.

PubMed

Foran, David R; Gehring, Michael E; Stallworth, Shawn E

2009-01-01

Improvised explosive devices (IEDs) represent one of the most common modes of arbitrarily injuring or killing human beings. Because of the heat generated by, and destruction to, an IED postconflagration, most methods for identifying who assembled the device are ineffective. In the research presented, steel pipe bombs were mock-assembled by volunteers, and the bombs detonated under controlled conditions. The resultant shrapnel was collected and swabbed for residual cellular material. Mitochondrial DNA profiles were generated and compared blind to the pool of individuals who assembled the bombs. Assemblers were correctly identified 50% of the time, while another 19% could be placed into a group of three individuals with shared haplotypes. Only one bomb was assigned incorrectly. In some instances a contaminating profile (mixture) was also observed. Taken together, the results speak to the extreme sensitivity the methods have for identifying those who assemble IEDs, along with precautions needed when collecting and processing such evidence.

Taming tosyl azide: the development of a scalable continuous diazo transfer process.

PubMed

Deadman, Benjamin J; O'Mahony, Rosella M; Lynch, Denis; Crowley, Daniel C; Collins, Stuart G; Maguire, Anita R

2016-04-07

Heat and shock sensitive tosyl azide was generated and used on demand in a telescoped diazo transfer process. Small quantities of tosyl azide were accessed in a 'one pot' batch procedure using shelf stable, readily available reagents. For large scale diazo transfer reactions tosyl azide was generated and used in a telescoped flow process, to mitigate the risks associated with handling potentially explosive reagents on scale. The in situ formed tosyl azide was used to rapidly perform diazo transfer to a range of acceptors, including β-ketoesters, β-ketoamides, malonate esters and β-ketosulfones. An effective in-line quench of sulfonyl azides was also developed, whereby a sacrificial acceptor molecule ensured complete consumption of any residual hazardous diazo transfer reagent. The telescoped diazo transfer process with in-line quenching was used to safely prepare over 21 g of an α-diazocarbonyl in >98% purity without any column chromatography.

Nanoengineered explosives

DOEpatents

Makowiecki, D.M.

1996-04-09

A complex modulated structure is described for reactive elements that have the capability of considerably more heat than organic explosives while generating a working fluid or gas. The explosive and method of fabricating same involves a plurality of very thin, stacked, multilayer structures, each composed of reactive components, such as aluminum, separated from a less reactive element, such as copper oxide, by a separator material, such as carbon. The separator material not only separates the reactive materials, but it reacts therewith when detonated to generate higher temperatures. The various layers of material, thickness of 10 to 10,000 angstroms, can be deposited by magnetron sputter deposition. The explosive detonates and combusts a high velocity generating a gas, such as CO, and high temperatures. 2 figs.

Electric generator

DOEpatents

Foster, Jr., John S.; Wilson, James R.; McDonald, Jr., Charles A.

1983-01-01

1. In an electrical energy generator, the combination comprising a first elongated annular electrical current conductor having at least one bare surface extending longitudinally and facing radially inwards therein, a second elongated annular electrical current conductor disposed coaxially within said first conductor and having an outer bare surface area extending longitudinally and facing said bare surface of said first conductor, the contiguous coaxial areas of said first and second conductors defining an inductive element, means for applying an electrical current to at least one of said conductors for generating a magnetic field encompassing said inductive element, and explosive charge means disposed concentrically with respect to said conductors including at least the area of said inductive element, said explosive charge means including means disposed to initiate an explosive wave front in said explosive advancing longitudinally along said inductive element, said wave front being effective to progressively deform at least one of said conductors to bring said bare surfaces thereof into electrically conductive contact to progressively reduce the inductance of the inductive element defined by said conductors and transferring explosive energy to said magnetic field effective to generate an electrical potential between undeformed portions of said conductors ahead of said explosive wave front.

Portable radiography system using a relativistic electron beam

DOEpatents

Hoeberling, Robert F.

1990-01-01

A portable radiographic generator is provided with an explosive magnetic flux compression generator producing the high voltage necessary to generate a relativistic electron beam. The relativistic electron beam is provided with target materials which generates the desired radiographic pulse. The magnetic flux compression generator may require at least two conventional explosively driven generators in series to obtain a desired output voltage of at least 1 MV. The cathode and anode configuration of the diode are selected to provide a switching action wherein a high impedance load is presented to the magnetic flux compression generator when the high voltage is being generated, and thereafter switching to a low impedance load to generate the relativistic electron beam. Magnetic flux compression generators can be explosively driven and provided in a relatively compact, portable form for use with the relativistic x-ray equipment.

Portable radiography system using a relativistic electron beam

DOEpatents

Hoeberling, R.F.

1987-09-22

A portable radiographic generator is provided with an explosive magnetic flux compression generator producing the high voltage necessary to generate a relativistic electron beam. The relativistic electron beam is provided with target materials which generates the desired radiographic pulse. The magnetic flux compression generator may require at least two conventional explosively driven generators in series to obtain a desired output voltage of at least 1 MV. The cathode and anode configuration of the diode are selected to provide a switching action wherein a high impedance load is presented to the magnetic flux compression generator when the high voltage is being generated, and thereafter switching to a low impedance load to generate the relativistic electron beam. Magnetic flux compression generators can be explosively driven and provided in a relatively compact, portable form for use with the relativistic x-ray equipment. 8 figs.

Effect of Velocity of Detonation of Explosives on Seismic Radiation

NASA Astrophysics Data System (ADS)

Stroujkova, A. F.; Leidig, M.; Bonner, J. L.

2014-12-01

We studied seismic body wave generation from four fully contained explosions of approximately the same yields (68 kg of TNT equivalent) conducted in anisotropic granite in Barre, VT. The explosions were detonated using three types of explosives with different velocities of detonation (VOD): Black Powder (BP), Ammonium Nitrate Fuel Oil/Emulsion (ANFO), and Composition B (COMP B). The main objective of the experiment was to study differences in seismic wave generation among different types of explosives, and to determine the mechanism responsible for these differences. The explosives with slow burn rate (BP) produced lower P-wave amplitude and lower corner frequency, which resulted in lower seismic efficiency (0.35%) in comparison with high burn rate explosives (2.2% for ANFO and 3% for COMP B). The seismic efficiency estimates for ANFO and COMP B agree with previous studies for nuclear explosions in granite. The body wave radiation pattern is consistent with an isotropic explosion with an added azimuthal component caused by vertical tensile fractures oriented along pre-existing micro-fracturing in the granite, although the complexities in the P- and S-wave radiation patterns suggest that more than one fracture orientation could be responsible for their generation. High S/P amplitude ratios and low P-wave amplitudes suggest that a significant fraction of the BP source mechanism can be explained by opening of the tensile fractures as a result of the slow energy release.

Optimization of biological and instrumental detection of explosives and ignitable liquid residues including canines, SPME/ITMS and GC/MSn

NASA Astrophysics Data System (ADS)

Furton, Kenneth G.; Harper, Ross J.; Perr, Jeannette M.; Almirall, Jose R.

2003-09-01

A comprehensive study and comparison is underway using biological detectors and instrumental methods for the rapid detection of ignitable liquid residues (ILR) and high explosives. Headspace solid phase microextraction (SPME) has been demonstrated to be an effective sampling method helping to identify active odor signature chemicals used by detector dogs to locate forensic specimens as well as a rapid pre-concentration technique prior to instrumental detection. Common ignitable liquids and common military and industrial explosives have been studied including trinitrotoluene, tetryl, RDX, HMX, EGDN, PETN and nitroglycerine. This study focuses on identifying volatile odor signature chemicals present, which can be used to enhance the level and reliability of detection of ILR and explosives by canines and instrumental methods. While most instrumental methods currently in use focus on particles and on parent organic compounds, which are often involatile, characteristic volatile organics are generally also present and can be exploited to enhance detection particularly for well-concealed devices. Specific examples include the volatile odor chemicals 2-ethyl-1-hexanol and cyclohexanone, which are readily available in the headspace of the high explosive composition C-4; whereas, the active chemical cyclo-1,3,5-trimethylene-2,4,6-trinitramine (RDX) is not. The analysis and identification of these headspace 'fingerprint' organics is followed by double-blind dog trials of the individual components using certified teams in an attempt to isolate and understand the target compounds to which dogs are sensitive. Studies to compare commonly used training aids with the actual target explosive have also been undertaken to determine their suitability and effectiveness. The optimization of solid phase microextraction (SPME) combined with ion trap mobility spectrometry (ITMS) and gas chromatography/mass spectrometry/mass spectrometry (GC/MSn) is detailed including interface development and comparisons of limits of detection. These instrumental methods are being optimized in order to detect the same target odor chemicals used by detector dogs to reliably locate explosives and ignitable liquids.

Treatment of Explosives Residues from Range Activities

DTIC Science & Technology

2009-09-01

on the specific proportions of peat moss and crude soybean oil in the PMSO. Detections of TNT, HMX, and the RDX degradation products MNX, DNX, and...83 Table 5.8.1-1. Summary of explosive compound detections in all samples collected over the duration of the demonstration...reduced 12- to 50-fold, depending on the depth. Dissolved TNT and HMX were not detected with enough frequency to allow calculation of fluxes of these

Comparison of Explosives Residues from the Blow-in-Place Detonation of 155-mm High-Explosive Projectiles

DTIC Science & Technology

2006-06-01

were M107 high-explosive deep-cavity 155-mm howitzer projectiles with a supplemental charge and an M739 point- detonating fuze mounted in the nose...M107, HE, w/o fuze IOP03E100-011 14 1390010809447 N340 Fuze, point-detonating, M739 MA-84B007-013 14 1375014151232 ML47 Cap, blasting, non-electric 30... M739 N340 0 21 0 ə Cap, blasting, M11 ML47 ə 27 ə ə Cap, blasting, M13 MN03 0 ə 0 ə Cap, blasting, M14 MN06 0 0 0 ə Cord, detonating M456 0

Noncontact optical detection of explosive particles via photodissociation followed by laser-induced fluorescence.

PubMed

Wynn, C M; Palmacci, S; Kunz, R R; Aernecke, M

2011-09-12

High-sensitivity (ng/cm²) optical detection of the explosive 2,4,6-trinitrotoluene (TNT) is demonstrated using photodissociation followed by laser-induced fluorescence (PD-LIF). Detection occurs rapidly, within 6 laser pulses (~7 ns each) at a range of 15 cm. Dropcasting is used to create calibrated samples covering a wide range of TNT concentrations; and a correspondence between fractional area covered by TNT and PD-LIF signal strength is observed. Dropcast data are compared to that of an actual fingerprint. These results demonstrate that PD-LIF could be a viable means of rapidly and remotely scanning surfaces for trace explosive residues.

Evaluation of Mediterranean Agricultural Residues as a Potential Feedstock for the Production of Biogas via Anaerobic Fermentation.

PubMed

Nitsos, Christos; Matsakas, Leonidas; Triantafyllidis, Kostas; Rova, Ulrika; Christakopoulos, Paul

2015-01-01

Hydrothermal, dilute acid, and steam explosion pretreatment methods, were evaluated for their efficiency to improve the methane production yield of three Mediterranean agricultural lignocellulosic residues such as olive tree pruning, grapevine pruning, and almond shells. Hydrothermal and dilute acid pretreatments provided low to moderate increase in the digestibility of the biomass samples, whereas steam explosion enabled the highest methane yields to be achieved for almond shells at 232.2 ± 13.0 mL CH4/gVS and olive pruning at 315.4 ± 0.0 mL CH4/gVS. Introduction of an enzymatic prehydrolysis step moderately improved methane yields for hydrothermal and dilute acid pretreated samples but not for the steam exploded ones.

Evaluation of Mediterranean Agricultural Residues as a Potential Feedstock for the Production of Biogas via Anaerobic Fermentation

PubMed Central

Nitsos, Christos; Triantafyllidis, Kostas

2015-01-01

Hydrothermal, dilute acid, and steam explosion pretreatment methods, were evaluated for their efficiency to improve the methane production yield of three Mediterranean agricultural lignocellulosic residues such as olive tree pruning, grapevine pruning, and almond shells. Hydrothermal and dilute acid pretreatments provided low to moderate increase in the digestibility of the biomass samples, whereas steam explosion enabled the highest methane yields to be achieved for almond shells at 232.2 ± 13.0 mL CH4/gVS and olive pruning at 315.4 ± 0.0 mL CH4/gVS. Introduction of an enzymatic prehydrolysis step moderately improved methane yields for hydrothermal and dilute acid pretreated samples but not for the steam exploded ones. PMID:26609521

Novel laser induced photoacoustic spectroscopy for instantaneous trace detection of explosive materials.

PubMed

El-Sharkawy, Yasser H; Elbasuney, Sherif

2017-08-01

Laser photoacoustic spectroscopy (LPAS) is an attractive technology in terms of simplicity, ruggedness, and overall sensitivity; it detects the time dependent heat generated (thermo-elastic effect) in the target via interaction with pulsed optical radiation. This study reports on novel LPAS technique that offers instant and standoff detection capabilities of trace explosives. Over the current study, light is generated using pulsed Q-switched Nd:YAG laser; the generated photoacoustic response in stimulated explosive material offers signature values that depend on the optical, thermal, and acoustical properties. The generated acoustic waves were captured using piezoelectric transducer as well as novel customized optical sensor with remotely laser interferometer probe. A digital signal processing algorithm was employed to identify explosive material signatures via calculation of characteristic optical properties (absorption coefficient), sound velocity, and frequency response of the generated photoacoustic signal. Customized LPAS technique was employed for instantaneous trace detection of three main different high explosive materials including TNT, RDX, and HMX. The main outcome of this study is that the novel customized optical sensor signals were validated with traditional piezoelectric transducer. Furthermore, the customized optical sensor offered standoff detection capabilities (10cm), fast response, high sensitivity, and enhanced signal to noise ratio. This manuscript shaded the light on the instant detection of trace explosive materials from significant standoffs using novel customized LPAS technique. Copyright © 2017 Elsevier B.V. All rights reserved.

Method and system for detecting explosives

DOEpatents

Reber, Edward L [Idaho Falls, ID; Jewell, James K [Idaho Falls, ID; Rohde, Kenneth W [Idaho Falls, ID; Seabury, Edward H [Idaho Falls, ID; Blackwood, Larry G [Idaho Falls, ID; Edwards, Andrew J [Idaho Falls, ID; Derr, Kurt W [Idaho Falls, ID

2009-03-10

A method of detecting explosives in a vehicle includes providing a first rack on one side of the vehicle, the rack including a neutron generator and a plurality of gamma ray detectors; providing a second rack on another side of the vehicle, the second rack including a neutron generator and a plurality of gamma ray detectors; providing a control system, remote from the first and second racks, coupled to the neutron generators and gamma ray detectors; using the control system, causing the neutron generators to generate neutrons; and performing gamma ray spectroscopy on spectra read by the gamma ray detectors to look for a signature indicative of presence of an explosive. Various apparatus and other methods are also provided.

Explosives detection system and method

DOEpatents

Reber, Edward L.; Jewell, James K.; Rohde, Kenneth W.; Seabury, Edward H.; Blackwood, Larry G.; Edwards, Andrew J.; Derr, Kurt W.

2007-12-11

A method of detecting explosives in a vehicle includes providing a first rack on one side of the vehicle, the rack including a neutron generator and a plurality of gamma ray detectors; providing a second rack on another side of the vehicle, the second rack including a neutron generator and a plurality of gamma ray detectors; providing a control system, remote from the first and second racks, coupled to the neutron generators and gamma ray detectors; using the control system, causing the neutron generators to generate neutrons; and performing gamma ray spectroscopy on spectra read by the gamma ray detectors to look for a signature indicative of presence of an explosive. Various apparatus and other methods are also provided.

Explosive volcanism may not be an inevitable consequence of magma fragmentation.

PubMed

Gonnermann, Helge M; Manga, Michael

2003-11-27

The fragmentation of magma, containing abundant gas bubbles, is thought to be the defining characteristic of explosive eruptions. When viscous stresses associated with the growth of bubbles and the flow of the ascending magma exceed the strength of the melt, the magma breaks into disconnected fragments suspended within an expanding gas phase. Although repeated effusive and explosive eruptions for individual volcanoes are common, the dynamics governing the transition between explosive and effusive eruptions remain unclear. Magmas for both types of eruptions originate from sources with similar volatile content, yet effusive lavas erupt considerably more degassed than their explosive counterparts. One mechanism for degassing during magma ascent, consistent with observations, is the generation of intermittent permeable fracture networks generated by non-explosive fragmentation near the conduit walls. Here we show that such fragmentation can occur by viscous shear in both effusive and explosive eruptions. Moreover, we suggest that such fragmentation may be important for magma degassing and the inhibition of explosive behaviour. This implies that, contrary to conventional views, explosive volcanism is not an inevitable consequence of magma fragmentation.

Design of Microstructured Conducting Polymer Films for Enhanced Trace Explosives Detection

NASA Astrophysics Data System (ADS)

Laster, Jennifer S.

The detection of trace amounts of explosive material is critical to national security. Ion mobility spectrometer (IMS)-based contact sampling continues to be a common method employed for the detection of explosives in high security checkpoint applications, such as airport security. In this process a surface of interest, such as a passenger's hands or luggage, is probed by a swab or particle trap to collect and transfer residue to an IMS for analysis. The collection of residue on a sampling swab has been shown to be a limiting step in this detection process. As such, there is significant need to develop new materials with increased adhesion to explosive analytes and with superior particle removal abilities. Here, the design of novel sampling swabs is presented for the enhanced collection of trace explosive residue from surfaces. First, the influence of the swab microstructure on the ability to remove particles from representative substrates is demonstrated. Free-standing microstructured polypyrrole (PPy) films of a variety of dimensions and form factors are fabricated using a templated electropolymerization process. The removal of polystyrene fluorescent particles from an aluminum substrate of varying surface roughness is examined as a function of the polymer microstructure. PPy microstructured films display enhanced particle removal abilities compared to PPy non-structured and current commercial films. This increase in particle removal is attributed to the increased particle-swab contact from the microstructured films. Next, the influence of the surface chemistry of sampling swabs on the collection of a representative explosive analyte, trinitrotoluene (TNT) is explored. The surface chemistry of PPy films is modified by electropolymerizaton of an N-substituted pyrrole monomer. The surface chemistries examined include a methyl, carboxylic acid, and amino-phenyl functionality. The vapor deposition of TNT on the surface of the functionalized PPy films is quantified through ultraviolet-visible (UV-vis) absorption and compared to commercial swabbing materials of varying chemistry and surface roughness. The PPy modified films with potential sites for hydrogen bonding display the highest deposition of TNT, while the Teflon coated commercial films display the lowest interaction with TNT. Finally, the desorption and release of TNT from sampling swabs is studied as an effect of temperature and of applied bias. For successful analyte detection within an IMS, the residue collected on a sampling swab must be released from the swab, typically through a thermal desorption process. In this work the release of TNT from sampling swabs is determined through solid-phase microextraction-gas chromatography mass spectrometry (SPME-GCMS). The results of this thesis provide important information on the design considerations for the development of novel particle sampling swabs with increased performance.

Peculiarity of convergence of shock wave generated by underwater electrical explosion of ring-shaped wire

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shafer, D.; Toker, G. R.; Gurovich, V. Tz.

2013-05-15

Nanosecond timescale underwater electrical wire explosions of ring-shaped Cu wires were investigated using a pulsed generator with a current amplitude up to 50 kA. It was shown that this type of wire explosion results in the generation of a toroidal shock wave (SW). Time- and space-resolved optical diagnostics were used to determine azimuthal uniformity of the shock wave front and its velocity. It was found that the shock wave preserves its circular front shape in the range of radii 50μm

Measurement of residual stress fields in FHPP welding: a comparison between DSPI combined with hole-drilling and neutron diffraction

NASA Astrophysics Data System (ADS)

Viotti, Matias R.; Albertazzi, Armando; Staron, Peter; Pisa, Marcelo

2013-04-01

This paper shows a portable device to measure mainly residual stress fields outside the optical bench. This system combines the traditional hole drilling technique with Digital Speckle Pattern Interferometry. The novel feature of this device is the high degree of compaction since only one base supports simultaneously the measurement module and the hole-drilling device. The portable device allows the measurement of non-uniform residual stresses in accordance with the ASTM standard. In oil and gas offshore industries, alternative welding procedures among them, the friction hydro pillar processing (FHPP) is highlighted and nowadays is an important maintenance tool since it has the capability to produce structure repairs without risk of explosions. In this process a hole is drilled and filled with a consumable rod of the same material. The rod, which could be cylindrical or conical, is rotated and pressed against the hole, leading to frictional heating. In order to assess features about the residual stress distribution generated by the weld into the rod as well as into the base material around the rod, welded samples were evaluated by neutron diffraction and by the hole drilling technique having a comparison between them. For the hole drilling technique some layers were removed by using electrical discharge machining (EDM) after diffraction measurements in order to assess the bulk stress distribution. Results have shown a good agreement between techniques.

Behavior and Release of Nitrogen at Mines and Quarries in Nordic Conditions

NASA Astrophysics Data System (ADS)

Karlsson, Teemu; Neitola, Raisa; Jermakka, Johannes; Merta, Elina; Mroueh, Ulla-Maija

2015-04-01

The increased extraction of mineral resources and mining activities creates added pressure on the environmental issues and a proper water management in mining areas in Finland. Among others, nitrogen compounds released from explosives or from mining processes can have a detrimental effect on the environment. Thus, this project aimed at comprehensive understanding on the nitrogen issue in the extractive industry. The project collected essential data on nitrogen compounds present in the environments of mines and quarries, and generated better understanding of the discharge and behaviour of nitrogen compounds in mining areas. The sources and balances of explosives-originated nitrogen compounds at mines and quarries of different sizes were investigated and compared. Additionally, the focus was in 'nitrogen smudging' problem of waste rocks and the intensity, as well as evolution and chemical characteristics of their nitrogen contamination. According to the results, the total load of potential nitrogen to the environment depends on the scale and type of the activity as well as the type of explosives used. The main emission sources of nitrogen are process and dewatering waters. A lysimeter study showed that the explosives originated nitrogen content of left over stones from natural stone quarrying is relatively low and ca. half of the nitrogen is leached within the first weeks after detonation. The "nitrogen smudging" of natural stone quarrying left over stones is relatively low to begin with and enhanced by the rapid flushing by rainwater, thus the residues of explosives should not be considered to prevent the utilization of otherwise mineralogically inert waste rocks of good technical quality. The overall nitrogen management should take into account the background concentrations and sensitivity of the local ecosystem. The research project "Solution for Control of Nitrogen Discharges at Mines and Quarries, (MINIMAN)" was realized during years 2012-2014 as a cooperative project with GTK, VTT and TTY together with several industrial and international partners and financed by Tekes Green Mining Programme.

Explosion Generated Seismic Waves and P/S Methods of Discrimination from Earthquakes with Insights from the Nevada Source Physics Experiments

NASA Astrophysics Data System (ADS)

Walter, W. R.; Ford, S. R.; Pitarka, A.; Pyle, M. L.; Pasyanos, M.; Mellors, R. J.; Dodge, D. A.

2017-12-01

The relative amplitudes of seismic P-waves to S-waves are effective at identifying underground explosions among a background of natural earthquakes. These P/S methods appear to work best at frequencies above 2 Hz and at regional distances ( >200 km). We illustrate this with a variety of historic nuclear explosion data as well as with the recent DPRK nuclear tests. However, the physical basis for the generation of explosion S-waves, and therefore the predictability of this P/S technique as a function of path, frequency and event properties such as size, depth, and geology, remains incompletely understood. A goal of current research, such as the Source Physics Experiments (SPE), is to improve our physical understanding of the mechanisms of explosion S-wave generation and advance our ability to numerically model and predict them. The SPE conducted six chemical explosions between 2011 and 2016 in the same borehole in granite in southern Nevada. The explosions were at a variety of depths and sizes, ranging from 0.1 to 5 tons TNT equivalent yield. The largest were observed at near regional distances, with P/S ratios comparable to much larger historic nuclear tests. If we control for material property effects, the explosions have very similar P/S ratios independent of yield or magnitude. These results are consistent with explosion S-waves coming mainly from conversion of P- and surface waves, and are inconsistent with source-size based models. A dense sensor deployment for the largest SPE explosion allowed this conversion to be mapped in detail. This is good news for P/S explosion identification, which can work well for very small explosions and may be ultimately limited by S-wave detection thresholds. The SPE also showed explosion P-wave source models need to be updated for small and/or deeply buried cases. We are developing new P- and S-wave explosion models that better match all the empirical data. Historic nuclear explosion seismic data shows that the media in which the explosion takes place is quite important. These material property effects can surprisingly degrade the seismic waveform correlation of even closely spaced explosions in different media. The next phase of the SPE will contrast chemical explosions in dry alluvium with the prior SPE explosions in granite and historic nuclear tests in a variety of media.

Air Blast Calculations

DTIC Science & Technology

2013-07-01

composition C-4 (C4), a polymer-bonded explosive (PBXN-109), and nitromethane (NM). Each charge diameter (CD) is assumed to be 17.46 cm (equivalent to a 10-lb... explosive detonates, the rapid expansion of reaction gases generates a shock wave that propagates into the surrounding medium. The pressure history at a...spherical explosive charge suspended in air. A comparison of the results obtained using CTH are made to ones generated using the Friedlander

Laser-based standoff detection of surface-bound explosive chemicals

NASA Astrophysics Data System (ADS)

Huestis, David L.; Smith, Gregory P.; Oser, Harald

2010-04-01

Avoiding or minimizing potential damage from improvised explosive devices (IEDs) such as suicide, roadside, or vehicle bombs requires that the explosive device be detected and neutralized outside its effective blast radius. Only a few seconds may be available to both identify the device as hazardous and implement a response. As discussed in a study by the National Research Council, current technology is still far from capable of meeting these objectives. Conventional nitrocarbon explosive chemicals have very low vapor pressures, and any vapors are easily dispersed in air. Many pointdetection approaches rely on collecting trace solid residues from dust particles or surfaces. Practical approaches for standoff detection are yet to be developed. For the past 5 years, SRI International has been working toward development of a novel scheme for standoff detection of explosive chemicals that uses infrared (IR) laser evaporation of surfacebound explosive followed by ultraviolet (UV) laser photofragmentation of the explosive chemical vapor, and then UV laser-induced fluorescence (LIF) of nitric oxide. This method offers the potential of long standoff range (up to 100 m or more), high sensitivity (vaporized solid), simplicity (no spectrometer or library of reference spectra), and selectivity (only nitrocompounds).

Tunable generation and adsorption of energetic compounds in the vapor phase at trace levels: a tool for testing and developing sensitive and selective substrates for explosive detection.

PubMed

Bonnot, Karine; Bernhardt, Pierre; Hassler, Dominique; Baras, Christian; Comet, Marc; Keller, Valérie; Spitzer, Denis

2010-04-15

Among various methods for landmine detection, as well as soil and water pollution monitoring, the detection of explosive compounds in air is becoming an important and inevitable challenge for homeland security applications, due to the threatening increase in terrorist explosive bombs used against civil populations. However, in the last case, there is a crucial need for the detection of vapor phase traces or subtraces (in the ppt range or even lower). A novel and innovative generator for explosive trace vapors was designed and developed. It allowed the generation of theoretical concentrations as low as 0.24 ppq for hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) in air according to Clapeyron equations. The accurate generation of explosive concentrations at subppt levels was verified for RDX and 2,4,6-trinitrotoluene (TNT) using a gas chromatograph coupled to an electron capture detector (GC-ECD). First, sensing material experiments were conducted on a nanostructured tungsten oxide. The sensing efficiency of this material determined as its adsorption capacity toward 54 ppb RDX was calculated to be five times higher than the sensing efficiency of a 54 ppb TNT vapor. The material sensing efficiency showed no dependence on the mass of material used. The results showed that the device allowed the calibration and discrimination between materials for highly sensitive and accurate sensing detection in air of low vapor pressure explosives such as TNT or RDX at subppb levels. The designed device and method showed promising features for nanosensing applications in the field of ultratrace explosive detection. The current perspectives are to decrease the testing scale and the detection levels to ppt or subppt concentration of explosives in air.

Two Sources of Nonisotropic Radiation From Underground Explosions in Granite

DOE PAGES

Vorobiev, O. Yu.

2017-10-23

Significant tangential ground motion observed during underground explosions makes it difficult to distinguish them from natural earthquakes. Such motion can be generated by the source geometry and emplacement conditions, by the heterogeneous nature of the rock mass (mechanical properties may vary in space due to the presence of cracks, joints, faults, and various geologic layers) and also by the nonuniform in situ stress state. The last mechanism is increasingly important with depth when the difference in main principal stresses becomes significant. This paper is focused on the role of material strength of the rock mass in generation of nonradial motionmore » during explosions in prestressed media. Numerical modeling of underground chemical explosions in granite at various depths has been conducted to compare two possible mechanisms of shear wave generation. The first, caused by rock mass anisotropy, is important at shallow depth. The second is related to elastic-plastic relaxation around the cavity created by the explosion. As a result, tangential motions for these two mechanisms have different signatures.« less

Two Sources of Nonisotropic Radiation From Underground Explosions in Granite

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vorobiev, O. Yu.

Significant tangential ground motion observed during underground explosions makes it difficult to distinguish them from natural earthquakes. Such motion can be generated by the source geometry and emplacement conditions, by the heterogeneous nature of the rock mass (mechanical properties may vary in space due to the presence of cracks, joints, faults, and various geologic layers) and also by the nonuniform in situ stress state. The last mechanism is increasingly important with depth when the difference in main principal stresses becomes significant. This paper is focused on the role of material strength of the rock mass in generation of nonradial motionmore » during explosions in prestressed media. Numerical modeling of underground chemical explosions in granite at various depths has been conducted to compare two possible mechanisms of shear wave generation. The first, caused by rock mass anisotropy, is important at shallow depth. The second is related to elastic-plastic relaxation around the cavity created by the explosion. As a result, tangential motions for these two mechanisms have different signatures.« less

Comparative simulation of switching regimes of magnetic explosion generators by copper and aluminum magnetodynamic current breakers taking into account elastoplastic properties of materials

NASA Astrophysics Data System (ADS)

Bazanov, A. A.; Ivanovskii, A. V.; Panov, A. I.; Samodolov, A. V.; Sokolov, S. S.; Shaidullin, V. Sh.

2017-06-01

We report on the results of the computer simulation of the operation of magnetodynamic break switches used as the second stage of current pulse formation in magnetic explosion generators. The simulation was carried out under the conditions when the magnetic field energy density on the surface of the switching conductor as a function of the current through it was close to but still did not exceed the critical value typical of the beginning of electric explosion. In the computational model, we used the parameters of experimentally tested sample of a coil magnetic explosion generator that can store energy of up to 2.7 MJ in the inductive storage circuit and equipped with a primary explosion stage of the current pulse formation. It has been shown that the choice of the switching conductor material, as well as its elastoplastic properties, considerably affects the breaker speed. Comparative results of computer simulation for copper and aluminum have been considered.

Simulations of Si-PIN photodiode based detectors for underground explosives enhanced by ammonium nitrate

NASA Astrophysics Data System (ADS)

Yücel, Mete; Bayrak, Ahmet; Yücel, Esra Barlas; Ozben, Cenap S.

2018-02-01

Massive Ammonium Nitrate (NH4-NO3) based explosives buried underground are commonly used in terror attacks. These explosives can be detected using neutron scattering method with some limitations. Simulations are very useful tools for designing a possible detection system for these kind of explosives. Geant4 simulations were used for generating neutrons at 14 MeV energy and tracking them through the scattering off the explosive embedded in soil. Si-PIN photodiodes were used as detector elements in the design for their low costs and simplicity for signal readout electronics. Various neutron-charge particle converters were applied on to the surface of the photodiodes to increase the detection efficiency. Si-PIN photodiodes coated with 6LiF provided the best result for a certain energy interval. Energy depositions in silicon detector from all secondary particles generated including photons were taken into account to generate a realistic background. Humidity of soil, one of the most important parameter for limiting the detection, was also studied.

Thermonuclear ignition by Z-pinch X-ray radiation produced by current of an explosive magnetic generator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Garanin, S. G.; Ivanovskiy, A. V., E-mail: ivanovsky@elph.vniief.ru

2015-12-15

The scheme of a device based a superpower disk-type magnetic explosion generator to produce a pulse of X-ray radiation with the energy exceeding the target ignition threshold is described and validated.

Thermonuclear ignition by Z-pinch X-ray radiation produced by current of an explosive magnetic generator

NASA Astrophysics Data System (ADS)

Garanin, S. G.; Ivanovskiy, A. V.

2015-12-01

The scheme of a device based a superpower disk-type magnetic explosion generator to produce a pulse of X-ray radiation with the energy exceeding the target ignition threshold is described and validated.

Portable chemical detection system with intergrated preconcentrator

DOEpatents

Baumann, Mark J.; Brusseau, Charles A.; Hannum, David W.; Linker, Kevin L.

2005-12-27

A portable system for the detection of chemical particles such as explosive residue utilizes a metal fiber substrate that may either be swiped over a subject or placed in a holder in a collection module which can shoot a jet of gas at the subject to dislodge residue, and then draw the air containing the residue into the substrate. The holder is then placed in a detection module, which resistively heats the substrate to evolve the particles, and provides a gas flow to move the particles to a miniature detector in the module.

Investigation Of Vapor Explosion Mechanisms Using High Speed Photography

NASA Astrophysics Data System (ADS)

Armstrong, Donn R.; Anderson, Richard P.

1983-03-01

The vapor explosion, a physical interaction between hot and cold liquids that causes the explosive vaporization of the cold liquid, is a hazard of concern in such diverse industries as metal smelting and casting, paper manufacture, and nuclear power generation. Intensive work on this problem worldwide, for the past 25 years has generated a number of theories and mechanisms proposed to explain vapor explosions. High speed photography has been the major instrument used to test the validity of the theories and to provide the observations that have lead to new theories. Examples are given of experimental techniques that have been used to investigate vapor explosions. Detailed studies of specific mechanisms have included microsecond flash photograph of contact boiling and high speed cinematography of shock driven breakup of liquid drops. Other studies looked at the explosivity of various liquid pairs using cinematography inside a pulsed nuclear reactor and x-ray cinematography of a thermite-sodium interaction.

Minutes of the Explosives Safety Seminar (22nd) Held in Anaheim, California on 26-28 August 1986. Volume 2

DTIC Science & Technology

1986-08-01

the U.S. Customs thermionic acetone vapor detector and a non -commercial Gas Chromatograph with electron capture detection as the main types. Each had...detector would only detect RDX or HMX or other explosives that had residual solvent with an alpha keto group like acetone or methylethyl ketone...8217.’=- evaluation for both vapor and non -vapor methods. The NAVSEA was not prepared to engage in r comprehensive study but did fund a reviev of improved

COBE looks back to the Big Bang

NASA Technical Reports Server (NTRS)

Mather, John C.

1993-01-01

An overview is presented of NASA-Goddard's Cosmic Background Explorer (COBE), the first NASA satellite designed to observe the primeval explosion of the universe. The spacecraft carries three extremely sensitive IR and microwave instruments designed to measure the faint residual radiation from the Big Bang and to search for the formation of the first galaxies. COBE's far IR absolute spectrophotometer has shown that the Big Bang radiation has a blackbody spectrum, proving that there was no large energy release after the explosion.

Residual Explosives Criteria for Treatment of Area P Soil, Louisiana Army Ammunition Plant

DTIC Science & Technology

1988-03-11

sorbed explosive in soil and water held in soil pores (called the soil solution ). Moreover, equilibrium is presumed to exist between soil slut’rion and...at a soil concentration of a pollutant equal to the product, water o’lub-iiLy*KKd. The soil solution could not become more saturated if the soil...to real behavior. More likely, as the soil solution approaches saturation, the relation between soil and soil solution concentration becomes non-linear

Continuation of the Ecological Risk Assessment of Explosive Residues in Rodents, Reptiles, Amphibians, Fish and Invertebrates: An Integrated Laboratory and Field Investigation Related to Live-Fire Ranges in the Department of Defense

DTIC Science & Technology

2008-08-01

malicum strain HAAP-1 isolated from a methanogenic mixed culture. Current Microbiology 48:332-340. Army. 1985h. HMX: Acute toxicity tests in...explosives: biotransformation versus mineralization. Applied Microbiology and Biotechnology 54:605-618. Hawari J, Halasz A, Sheremata T, Beaudet S...triazine (RDX) with municipal anaerobic sludge. Applied and Environmental Microbiology 66:2652-2657. Kudo, H., and Y. Oki. 1984. Microtus species

Phenotypic characterisation of Saccharomyces spp. yeast for tolerance to stresses encountered during fermentation of lignocellulosic residues to produce bioethanol

PubMed Central

2014-01-01

Background During industrial fermentation of lignocellulose residues to produce bioethanol, microorganisms are exposed to a number of factors that influence productivity. These include inhibitory compounds produced by the pre-treatment processes required to release constituent carbohydrates from biomass feed-stocks and during fermentation, exposure of the organisms to stressful conditions. In addition, for lignocellulosic bioethanol production, conversion of both pentose and hexose sugars is a pre-requisite for fermentative organisms for efficient and complete conversion. All these factors are important to maximise industrial efficiency, productivity and profit margins in order to make second-generation bioethanol an economically viable alternative to fossil fuels for future transport needs. Results The aim of the current study was to assess Saccharomyces yeasts for their capacity to tolerate osmotic, temperature and ethanol stresses and inhibitors that might typically be released during steam explosion of wheat straw. Phenotypic microarray analysis was used to measure tolerance as a function of growth and metabolic activity. Saccharomyces strains analysed in this study displayed natural variation to each stress condition common in bioethanol fermentations. In addition, many strains displayed tolerance to more than one stress, such as inhibitor tolerance combined with fermentation stresses. Conclusions Our results suggest that this study could identify a potential candidate strain or strains for efficient second generation bioethanol production. Knowledge of the Saccharomyces spp. strains grown in these conditions will aid the development of breeding programmes in order to generate more efficient strains for industrial fermentations. PMID:24670111

Ultrashort-pulse laser generated nanoparticles of energetic materials

DOEpatents

Welle, Eric J [Niceville, NM; Tappan, Alexander S [Albuquerque, NM; Palmer, Jeremy A [Albuquerque, NM

2010-08-03

A process for generating nanoscale particles of energetic materials, such as explosive materials, using ultrashort-pulse laser irradiation. The use of ultrashort laser pulses in embodiments of this invention enables one to generate particles by laser ablation that retain the chemical identity of the starting material while avoiding ignition, deflagration, and detonation of the explosive material.

Metal-Free Poly-Cycloaddition of Activated Azide and Alkynes toward Multifunctional Polytriazoles: Aggregation-Induced Emission, Explosive Detection, Fluorescent Patterning, and Light Refraction.

PubMed

Wu, Yongwei; He, Benzhao; Quan, Changyun; Zheng, Chao; Deng, Haiqin; Hu, Rongrong; Zhao, Zujin; Huang, Fei; Qin, Anjun; Tang, Ben Zhong

2017-09-01

The metal-free click polymerization (MFCP) of activated alkynes and azides or activated azide and alkynes have been developed into powerful techniques for the construction of polytriazoles without the obsession of metallic catalyst residues problem. However, the MFCP of activated azides and alkynes is rarely applied in preparation of functional polytriazoles. In this paper, soluble multifunctional polytriazoles (PIa and PIb) with high weight-average molecular weights (M w up to 32 000) are prepared via the developed metal-free poly-cycloaddition of activated azide and alkynes in high yields (up to 90%). The resultant PIa and PIb are thermally stable, and show aggregation-induced emission characteristics, enabling their aggregates to detect explosives with superamplification effect. Moreover, thanks to their containing aromatic rings and polar moieties, PIa and PIb exhibit high refractive indices. In addition, they can also be cross-linked upon UV irradiation to generate 2D fluorescent patterning due to their remaining azide groups and containing ester groups. Thus, these multifunctional polytriazoles are potentially applicable in the optoelectronic and sensing fields. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Compact pulse generators with soft ferromagnetic cores driven by gunpowder and explosive.

PubMed

Ben, Chi; He, Yong; Pan, Xuchao; Chen, Hong; He, Yuan

2015-12-01

Compact pulse generators which utilized soft ferromagnets as an initial energy carrier inside multi-turn coil and hard ferromagnets to provide the initial magnetic field outside the coil have been studied. Two methods of reducing the magnetic flux in the generators have been studied: (1) by igniting gunpowder to launch the core out of the generator, and (2) by detonating explosives that demagnetize the core. Several types of compact generators were explored to verify the feasibility. The generators with an 80-turn coil that utilize gunpowder were capable of producing pulses with amplitude 78.6 V and the full width at half maximum was 0.41 ms. The generators with a 37-turn coil that utilize explosive were capable of producing pulses with amplitude 1.41 kV and the full width at half maximum was 11.68 μs. These two methods were both successful, but produce voltage waveforms with significantly different characteristics.

Residual stresses in a stainless steel - titanium alloy joint made with the explosive technique

NASA Astrophysics Data System (ADS)

Taran, Yu V.; Balagurov, A. M.; Sabirov, B. M.; Evans, A.; Davydov, V.; Venter, A. M.

2012-02-01

Joining of pipes from stainless steel (SS) and titanium (Ti) alloy still experience serious technical problems. Recently, reliable and hermetic joining of SS and Ti pipes has been achieved with the explosive bonding technique in the Russian Federal Nuclear Center. Such adapters are earmarked for use at the future International Linear Collider. The manufactured SS-Ti adapters have excellent mechanical behavior at room and liquid nitrogen temperatures, during high-pressure tests and thermal cycling. We here report the first neutron diffraction investigation of the residual stresses in a SS-Ti adapter on the POLDI instrument at the SINQ spallation source. The strain scanning across the adapter walls into the SS-SS and SS-Ti pipes sections encompassed measurement of the axial, radial and hoop strain components, which were transformed into residual stresses. The full stress information was successfully determined for the three steel pipes involved in the joint. The residual stresses do not exceed 300 MPa in magnitude. All stress components have tensile values close to the adapter internal surface, whilst they are compressive close to the outer surface. The strong incoherent and weak coherent neutron scattering cross-sections of Ti did not allow for the reliable determination of stresses inside the titanic pipe.

Design of a Simple Blast Pressure Gauge Based on a Heterodyne Velocimetry Measuring Technique

DTIC Science & Technology

2016-08-01

deployed in an experiment during which the blast pressure was measured from detonation of 114 g of Primasheet 1000 high explosive. The gauge reported... detonation of high explosive where accelerated projectiles and debris may occur. Many times, overpressures generated by such events can be a nuisance to...as that generated by release of energy from a high-explosive detonation or deflagration, materials such as metals or ceramics may be needed. A

Current shunting and formation of stationary shock waves during electric explosions of metal wires in air

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ivanenkov, G. V.; Gus'kov, S. Yu.; Barishpol'tsev, D. V.

2010-01-15

Results of experiments on the generation of shock waves during electric explosions of fine copper and tungsten wires in air are analyzed. The generation mechanism of stationary shock wave by a plasma piston formed during the shunting breakdown of the electrode gap in the course of a wire explosion is investigated. The role of structural elements of such discharges, such as the core, corona, and wire environment, is analyzed.

Field Sampling Tools for Explosives Residues Developed at CRREL

DTIC Science & Technology

2004-04-01

4 Figure 2. Field cleaning supplies and equipment................................................. 5...Field Sampling Tools 5 Figure 2. Field cleaning supplies and equipment. Figure 3 depicts tools used for non-cohesive soils, such as sand or

Completely explosive ultracompact high-voltage nanosecond pulse-generating system

NASA Astrophysics Data System (ADS)

Shkuratov, Sergey I.; Talantsev, Evgueni F.; Baird, Jason; Rose, Millard F.; Shotts, Zachary; Altgilbers, Larry L.; Stults, Allen H.

2006-04-01

A conventional pulsed power technology has been combined with an explosive pulsed power technology to produce an autonomous high-voltage power supply. The power supply contained an explosive-driven high-voltage primary power source and a power-conditioning stage. The ultracompact explosive-driven primary power source was based on the physical effect of shock-wave depolarization of high-energy Pb (Zr52Ti48)O3 ferroelectric material. The volume of the energy-carrying ferroelectric elements in the shock-wave ferroelectric generators (SWFEGs) varied from 1.2 to 2.6cm3. The power-conditioning stage was based on the spiral vector inversion generator (VIG). The SWFEG-VIG system demonstrated successful operation and good performance. The amplitude of the output voltage pulse of the SWFEG-VIG system exceeded 90kV, with a rise time of 5.2ns.

Ethanol production from lignocellulosic byproducts of olive oil extraction.

PubMed

Ballesteros, I; Oliva, J M; Saez, F; Ballesteros, M

2001-01-01

The recent implementation of a new two-step centrifugation process for extracting olive oil in Spain has substantially reduced water consumption, thereby eliminating oil mill wastewater. However, a new high sugar content residue is still generated. In this work the two fractions present in the residue (olive pulp and fragmented stones) were assayed as substrate for ethanol production by the simultaneous saccharification and fermentation (SSF) process. Pretreatment of fragmented olive stones by sulfuric acid-catalyzed steam explosion was the most effective treatment for increasing enzymatic digestibility; however, a pretreatment step was not necessary to bioconvert the olive pulp into ethanol. The olive pulp and fragmented olive stones were tested by the SSF process using a fed-batch procedure. By adding the pulp three times at 24-h intervals, 76% of the theoretical SSF yield was obtained. Experiments with fed-batch pretreated olive stones provided SSF yields significantly lower than those obtained at standard SSF procedure. The preferred SSF conditions to obtain ethanol from olives stones (61% of theoretical yield) were 10% substrate and addition of cellulases at 15 filter paper units/g of substrate.

From Supernovae to Neutron Stars

NASA Astrophysics Data System (ADS)

Suwa, Yudai

A core-collapse supernova is a generation site of a neutron star as well as one of the largest explosions in the universe. This article gives a brief overview of the studies on supernova explosion mechanism. Basic picture of the explosion mechanism, the method to solve neutrino transfer equation, the impact of the nuclear equation of state on the explosion, and long-term simulation of neutron star evolution from the onset of the explosion are presented.

Hydrogen-Detection Apparatus

NASA Technical Reports Server (NTRS)

Ross, H. Richard; Bourgeois, Chris M.

1995-01-01

Apparatus continuously monitors concentration of hydrogen, at level ranging from few parts per million to several percent, in mixture of gases. Simple and fast, providing high sensitivity and linear response. Used to alert technicians to potentially explosive concentrations of residual hydrogen.

Residual radioactivity in the soil of the Semipalatinsk Nuclear Test Site in the former USSR.

PubMed

Yamamoto, M; Tsukatani, T; Katayama, Y

1996-08-01

This paper deals with our efforts to survey residual radioactivity in the soil sampled at the Semipalatinsk Nuclear Test Site and at off-site areas in Kazakhstan. The soil was sampled at the hypocenter where the first Soviet nuclear explosion was carried out on 29 August 1949, and at the bank of the crater called "Bolapan," which was formed by an underground nuclear detonation on 15 January 1965 along the Shagan River. As a comparison, other soil was also sampled in the cities of Kurchatov and Almaty. These data have allowed a preliminary evaluation of the contemporary radioactive contamination of the land in and around the test site. At the first nuclear explosion site and at Bolapan, higher than background levels of 239,240Pu with weapons-grade plutonium were detected together with fission and activation products such as 137Cs, 60Co, 152Eu, and 154Eu.

Subcritical water treatment of explosive and heavy metals co-contaminated soil: Removal of the explosive, and immobilization and risk assessment of heavy metals.

PubMed

Islam, Mohammad Nazrul; Jung, Ho-Young; Park, Jeong-Hun

2015-11-01

Co-contamination of explosives and heavy metals (HMs) in soil, particularly army shooting range soil, has received increasing environmental concern due to toxicity and risks to ecological systems. In this study, a subcritical water (SCW) extraction process was used to remediate the explosives-plus-HMs-co-contaminated soil. A quantitative evaluation of explosives in the treated soil, compared with untreated soil, was applied to assess explosive removal. The immobilization of HMs was assessed by toxicity characteristic leaching procedure tests, and by investigating the migration of HMs fractions. The environmental risk of HMs in the soil residue was assessed according to the risk assessment code (RAC) and ecological risk indices (Er and RI). The results indicated that SCW treatment could eliminate the explosives, >99%, during the remediation, while the HM was effectively immobilized. The effect of water temperature on reducing the explosives and the risk of HMs in soil was observed. A marked increase in the non-bioavailable concentration of each HM was observed, and the leaching rate of HMs was decreased by 70-97% after SCW treatment at 250 °C, showing the effective immobilization of HMs. According to the RAC or RI, each tested HM showed no or low risk to the environment after treatment. Copyright © 2015 Elsevier Ltd. All rights reserved.

Explosive force of primacord grid forms large sheet metal parts

NASA Technical Reports Server (NTRS)

1966-01-01

Primacord which is woven through fish netting in a grid pattern is used for explosive forming of large sheet metal parts. The explosive force generated by the primacord detonation is uniformly distributed over the entire surface of the sheet metal workpiece.

Standoff detection of explosive substances at distances of up to 150 m.

PubMed

Mukherjee, Anadi; Von der Porten, Steven; Patel, C Kumar N

2010-04-10

We report detection and identification of trace quantities of explosives at standoff distances up to 150 m with high sensitivity (signal-to-noise ratio of approximately 70) and high selectivity. The technique involves illuminating the target object with laser radiation at a wavelength that is strongly absorbed by the target. The resulting temperature rise is observed by remotely monitoring the increased blackbody radiation from the sample. An unambiguous determination of the target, TNT, in soil samples collected from an explosives test site in China Lake Naval Air Weapons Station is achieved through the use of a tunable CO(2) laser that scans over the absorption fingerprint of the target explosives. The theoretical analysis supports the observation and indicates that, with optimized detectors and data processing algorithms, the measurement capability can be improved significantly, permitting rapid standoff detection of explosives at distances approaching 1 km. The detection sensitivity varies as R(-2) and, thus, with the availability of high power, room-temperature, tunable mid-wave infrared and long-wave infrared quantum cascade lasers, this technology may play an important role in screening personnel and their belongings at short distances, such as in airports, for detecting and identifying explosives material residue on persons.

Airport testing an explosives detection portal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rhykerd, C.; Linker, K.; Hannum, D.

1998-08-01

At the direction of the US Congress, following the Pan Am 103 and TWA 800 crashes, the Federal Aviation Administration funded development of non-invasive techniques to screen airline passengers for explosives. Such an explosives detection portal, developed at Sandia National Laboratories, was field tested at the Albuquerque International airport in September 1997. During the 2-week field trial, 2,400 passengers were screened and 500 surveyed. Throughput, reliability, maintenance and sensitivity were studied. Follow-up testing at Sandia and at Idaho National Engineering and Environmental Laboratory was conducted. A passenger stands in the portal for five seconds while overhead fans blow air overmore » his body. Any explosive vapors or dislodged particles are collected in vents at the feet. Explosives are removed from the air in a preconcentrator and subsequently directed into an ion mobility spectrometer for detection. Throughput measured 300 passengers per hour. The non-invasive portal can detect subfingerprint levels of explosives residue on clothing. A survey of 500 passengers showed a 97% approval rating, with 99% stating that such portals, if effective, should be installed in airports to improve security. Results of the airport test, as well as operational issues, are discussed.« less

Explosive detonation causes an increase in soil porosity leading to increased TNT transformation.

PubMed

Yu, Holly A; Nic Daeid, Niamh; Dawson, Lorna A; DeTata, David A; Lewis, Simon W

2017-01-01

Explosives are a common soil contaminant at a range of sites, including explosives manufacturing plants and areas associated with landmine detonations. As many explosives are toxic and may cause adverse environmental effects, a large body of research has targeted the remediation of explosives residues in soil. Studies in this area have largely involved spiking 'pristine' soils using explosives solutions. Here we investigate the fate of explosives present in soils following an actual detonation process and compare this to the fate of explosives spiked into 'pristine' undetonated soils. We also assess the effects of the detonations on the physical properties of the soils. Our scanning electron microscopy analyses reveal that detonations result in newly-fractured planes within the soil aggregates, and novel micro Computed Tomography analyses of the soils reveal, for the first time, the effect of the detonations on the internal architecture of the soils. We demonstrate that detonations cause an increase in soil porosity, and this correlates to an increased rate of TNT transformation and loss within the detonated soils, compared to spiked pristine soils. We propose that this increased TNT transformation is due to an increased bioavailability of the TNT within the now more porous post-detonation soils, making the TNT more easily accessible by soil-borne bacteria for potential biodegradation. This new discovery potentially exposes novel remediation methods for explosive contaminated soils where actual detonation of the soil significantly promotes subsequent TNT degradation. This work also suggests previously unexplored ramifications associated with high energy soil disruption.

Acoustic wavefield and Mach wave radiation of flashing arcs in strombolian explosion measured by image luminance

NASA Astrophysics Data System (ADS)

Genco, Riccardo; Ripepe, Maurizio; Marchetti, Emanuele; Bonadonna, Costanza; Biass, Sebastien

2014-10-01

Explosive activity often generates visible flashing arcs in the volcanic plume considered as the evidence of the shock-front propagation induced by supersonic dynamics. High-speed image processing is used to visualize the pressure wavefield associated with flashing arcs observed in strombolian explosions. Image luminance is converted in virtual acoustic signal compatible with the signal recorded by pressure transducer. Luminance variations are moving with a spherical front at a 344.7 m/s velocity. Flashing arcs travel at the sound speed already 14 m above the vent and are not necessarily the evidence of a supersonic explosive dynamics. However, seconds later, the velocity of small fragments increases, and the spherical acousto-luminance wavefront becomes planar recalling the Mach wave radiation generated by large scale turbulence in high-speed jet. This planar wavefront forms a Mach angle of 55° with the explosive jet axis, suggesting an explosive dynamics moving at Mo = 1.22 Mach number.

Shallow magma diversions during explosive diatreme-forming eruptions.

PubMed

Le Corvec, Nicolas; Muirhead, James D; White, James D L

2018-04-13

The diversion of magma is an important mechanism that may lead to the relocation of a volcanic vent. Magma diversion is known to occur during explosive volcanic eruptions generating subterranean excavation and remobilization of country and volcanic rocks. However, feedbacks between explosive crater formation and intrusion processes have not been considered previously, despite their importance for understanding evolving hazards during volcanic eruptions. Here, we apply numerical modeling to test the impacts of excavation and subsequent infilling of diatreme structures on stress states and intrusion geometries during the formation of maar-diatreme complexes. Explosive excavation and infilling of diatremes affects local stress states which inhibits magma ascent and drives lateral diversion at various depths, which are expected to promote intra-diatreme explosions, host rock mixing, and vent migration. Our models demonstrate novel mechanisms explaining the generation of saucer-shaped sills, linked with magma diversion and enhanced intra-diatreme explosive fragmentation during maar-diatreme volcanism. Similar mechanisms will occur at other volcanic vents producing crater-forming eruptions.

Results of a Study Investigating the Plant Uptake of Explosive Residues From Compost of Explosives-Contaminated Soil Obtained from the Umatilla Army Depot Activity

DTIC Science & Technology

1998-11-01

Avoid contact with samples. Be aware of broken containers, corrosives, irritants, biohazards, flammability, pyrophoricity , reactivity, radioactivity...Revision RO 9/23/97 Page 3 NOj-N by Flow Injection Analysis 6.2.2.2 Low results may be obtained for samples that contain high concentrations of iron ...however, for analytes such as iron that may be found at high concentration, a more appropriate test would be to use a concentration near the upper

Shear Wave Generation by Explosions in Anisotropic Crystalline Rock

NASA Astrophysics Data System (ADS)

Rogers-Martinez, M. A.; Sammis, C. G.; Stroujkova, A. F.

2015-12-01

The use of seismic waves to discriminate between earthquakes and underground explosions is complicated by the observation that explosions routinely radiate strong S waves. Whether these S waves are primarily generated by non-linear processes at the source, or by mode conversions and scattering along the path remains an open question. It has been demonstrated that S waves are generated at the source by any mechanism that breaks the spherical symmetry of the explosion. Examples of such mechanisms include tectonic shear stress, spall, and anisotropy in the emplacement medium. Many crystalline rock massifs are transversely isotropic because they contain aligned fractures over a range of scales from microfractures at the grain scale (called the rift) to regional sets of joints. In this study we use a micromechanical damage mechanics to model the fracture damage patterns and seismic radiation generated by explosions in a material in which the initial distribution of fractures has a preferred direction. Our simulations are compared with a set of field experiments in a granite quarry in Barre, VT conducted by New England Research and Weston Geophysical. Barre granite has a strong rift plane of aligned microfractures. Our model captures two important results of these field studies: 1) the spatial extent of rock fracture and generation of S waves depends on the burn-rate of the explosion and 2) the resultant damage is anisotropic with most damage occurring in the preferred direction of the microfractures (the rift plane in the granite). The physical reason damage is enhanced in the rift direction is that the mode I stress intensity factor is large for each fracture in the array of parallel fractures in the rift plane. Tensile opening on the rift plane plus sliding on the preexisting fractures make strong non-spherical contributions to the moment tensor in the far-field.

Evaluation of the biomass potential for the production of lignocellulosic bioethanol from various agricultural residues in Austria and Worldwide

NASA Astrophysics Data System (ADS)

Kahr, Heike; Steindl, Daniel; Wimberger, Julia; Schürz, Daniel; Jäger, Alexander

2013-04-01

Due to the fact that the resources of fossil fuels are steadily decreasing, researchers have been trying to find alternatives over the past few years. As bioethanol of the first generation is based on potential food, its production has become an increasingly controversial topic. Therefore the focus of research currently is on the production of bioethanol of the second generation, which is made from cellulosic and lignocellulosic materials. However, for the production of bioethanol of the second generation the fibres have to be pre-treated. In this work the mass balances of various agricultural residues available in Austria were generated and examined in lab scale experiments for their bioethanol potential. The residues were pretreatment by means of state of the art technology (steam explosion), enzymatically hydrolysed and fermented with yeast to produce ethanol. Special attention was paid the mass balance of the overall process. Due to the pretreatment the proportion of cellulose increases with the duration of the pre-treatment, whereby the amount of hemicellulose decreases greatly. However, the total losses were increasing with the duration of the pre-treatment, and the losses largely consist of hemicellulose. The ethanol yield varied depending on the cellulose content of the substrates. So rye straw 200 °C 20 min reaches an ethanol yield of 169 kg/t, by far the largest yield. As result on the basis of the annual straw yield in Austria, approximately 210 000 t of bioethanol (266 million litres) could be produced from the straw of wheat (Triticum vulgare), rye (Secale cereale), oat (Avena sativa) and corn (Zea mays) as well as elephant grass (Miscanthus sinensis) using appropriate pre-treatment. So the greenhouse gas emissions produced by burning fossil fuels could be reduced significantly. About 1.8 million tons of motor gasoline are consumed in Austria every year. The needed quantity for a transition to E10 biofuels could thus be easily provided by bioethanol from straw. We also evaluated the production of world's most important grains (wheat, corn, rice, sugar cain) and we calculated the worldwide production of the relevant lignocellulosic residues. On the basis of our labs scale experiments on bioethanol production, the possible lignocellulosic bioethanol production word wide was determined.

Performance of an improved thermal neutron activation detector for buried bulk explosives

NASA Astrophysics Data System (ADS)

McFee, J. E.; Faust, A. A.; Andrews, H. R.; Clifford, E. T. H.; Mosquera, C. M.

2013-06-01

First generation thermal neutron activation (TNA) sensors, employing an isotopic source and NaI(Tl) gamma ray detectors, were deployed by Canadian Forces in 2002 as confirmation sensors on multi-sensor landmine detection systems. The second generation TNA detector is being developed with a number of improvements aimed at increasing sensitivity and facilitating ease of operation. Among these are an electronic neutron generator to increase sensitivity for deeper and horizontally displaced explosives; LaBr3(Ce) scintillators, to improve time response and energy resolution; improved thermal and electronic stability; improved sensor head geometry to minimize spatial response nonuniformity; and more robust data processing. The sensor is described, with emphasis on the improvements. Experiments to characterize the performance of the second generation TNA in detecting buried landmines and improvised explosive devices (IEDs) hidden in culverts are described. Performance results, including comparisons between the performance of the first and second generation systems are presented.

Ignition of a Deuterium Micro-Detonation with a Gigavolt Super Marx Generator

NASA Astrophysics Data System (ADS)

Winterberg, Friedwardt

2009-09-01

The Centurion-Halite experiment demonstrated the feasibility of igniting a deuterium-tritium micro-explosion with an energy of not more than a few megajoule, and the Mike test, the feasibility of a pure deuterium explosion with an energy of more than 106 MJ. In both cases the ignition energy was supplied by a fission bomb explosive. While an energy of a few megajoule, to be released in the time required of less than 10-9 s, can be supplied by lasers and intense particle beams, this is not enough to ignite a pure deuterium explosion. Because the deuterium-tritium reaction depends on the availability of lithium, the non-fission ignition of a pure deuterium fusion reaction would be highly desirable. It is shown that this goal can conceivably be reached with a "Super Marx Generator", where a large number of "ordinary" Marx generators charge (magnetically insulated) fast high voltage capacitors of a second stage Marx generator, called a "Super Marx Generator", ultimately reaching gigavolt potentials with an energy output in excess of 100 MJ. An intense 107 Ampere-GeV proton beam drawn from a "Super Marx Generator" can ignite a deuterium thermonuclear detonation wave in a compressed deuterium cylinder, where the strong magnetic field of the proton beam entraps the charged fusion reaction products inside the cylinder. In solving the stand-off problem, the stiffness of a GeV proton beam permits to place the deuterium target at a comparatively large distance from the wall of a cavity confining the deuterium micro-explosion.

Ballistically Initiated Fire Ball Generation Using M&S: Innovation Grant (Briefing Charts)

DTIC Science & Technology

2012-01-26

isotropic in nature Phenomenological models for explosives initiation. – HVRB, forest fire etc. Equation of state – Ideal gas, Mie-Gruneisen, JWL ...perfectly plastic description • EOS • Mie Gruneisen • JWL for explosive • Phenomenological Model for EFP • High Explosive input for programmed burn

Characterization of detonation soot produced during steady and overdriven conditions for three high explosive formulations

NASA Astrophysics Data System (ADS)

Podlesak, David W.; Huber, Rachel C.; Amato, Ronald S.; Dattelbaum, Dana M.; Firestone, Millicent A.; Gustavsen, Richard L.; Johnson, Carl E.; Mang, Joseph T.; Ringstrand, Bryan S.

2017-01-01

The detonation of high explosives (HE) produces a dense fluid of molecular gases and solid carbon. The solid detonation carbon contains various carbon allotropes such as detonation nanodiamonds, onion-like carbon, graphite and amorphous carbon, with the formation of the different forms dependent upon pressure, temperature and the environmental conditions of the detonation. We have collected solid carbon residues from controlled detonations of three HE formulations (Composition B-3, PBX 9501, and PBX 9502). Soot was collected from experiments designed to produce both steady and overdriven conditions, and from detonations in both an ambient (air) atmosphere and in an inert Ar atmosphere. Differences in solid carbon residues were quantified using X-ray photoelectron spectroscopy and carbon isotope measurements. Environmental conditions, HE formulation, and peak pressures influenced the amount of and isotopic composition of the carbon in the soot. Detonations in an Ar atmosphere produced greater amounts of carbon soot with lower δ13C values than those in ambient air. Therefore, solid carbon residues continued to evolve after detonation due to excess oxygen in the ambient air detonations. As well, higher peak pressures in overdriven conditions produced less carbon soot with, in general, higher δ13C values. Consequently, while overdriven conditions only produced peak pressures for a limited duration, it was enough to influence the composition of the solid carbon residues.

Analytical methods for characterization of explosives-contaminated sites on U.S. Army installations

NASA Astrophysics Data System (ADS)

Jenkins, Thomas F.; Walsh, Marianne E.; Thorne, Philip G.

1995-10-01

The U.S. Army manufactures munitions at facilities throughout the United States. Many of these facilities are contaminated with residues of explosives from production, disposal of off- specification, and out-of-data munitions. The first step in remediating these sites is careful characterization. Currently sites are being characterized using a combination of on-site field screening and off-site laboratory analysis. Most of the contamination is associated with TNT (2,4,6-trinitrotoluene) and RDX (hexahydro-1,3,5-tri-nitro-1,3,5-triazine) and their manufacturing impurities and environmental transformation products. Both colorimetric and enzyme immunoassay-based field screening methods have been used successfully for on-site characterization. These methods have similar detection capabilities but differ in their selectivity. Although field screening is very cost-effective, laboratory analysis is still required to fully characterize a site. Laboratory analysis for explosives residues in the United States is generally conducted using high-performance liquid chromatography equipped with a UV detector. Air-dried soils are extracted with acetonitrile in an ultrasonic bath. Water is analyzed directly if detection limits in the range of 10 - 20 (mu) g/L are acceptable, or preconcentrated using either salting-out solvent extraction with acetonitrile or solid phase extraction.

Explosive detonation causes an increase in soil porosity leading to increased TNT transformation

PubMed Central

Yu, Holly A.; Nic Daeid, Niamh; Dawson, Lorna A.; DeTata, David A.; Lewis, Simon W.

2017-01-01

Explosives are a common soil contaminant at a range of sites, including explosives manufacturing plants and areas associated with landmine detonations. As many explosives are toxic and may cause adverse environmental effects, a large body of research has targeted the remediation of explosives residues in soil. Studies in this area have largely involved spiking ‘pristine’ soils using explosives solutions. Here we investigate the fate of explosives present in soils following an actual detonation process and compare this to the fate of explosives spiked into ‘pristine’ undetonated soils. We also assess the effects of the detonations on the physical properties of the soils. Our scanning electron microscopy analyses reveal that detonations result in newly-fractured planes within the soil aggregates, and novel micro Computed Tomography analyses of the soils reveal, for the first time, the effect of the detonations on the internal architecture of the soils. We demonstrate that detonations cause an increase in soil porosity, and this correlates to an increased rate of TNT transformation and loss within the detonated soils, compared to spiked pristine soils. We propose that this increased TNT transformation is due to an increased bioavailability of the TNT within the now more porous post-detonation soils, making the TNT more easily accessible by soil-borne bacteria for potential biodegradation. This new discovery potentially exposes novel remediation methods for explosive contaminated soils where actual detonation of the soil significantly promotes subsequent TNT degradation. This work also suggests previously unexplored ramifications associated with high energy soil disruption. PMID:29281650

Explosive vapor detection payload for small robots

NASA Astrophysics Data System (ADS)

Stimac, Phil J.; Pettit, Michael; Wetzel, John P.; Haas, John W.

2013-05-01

Detection of explosive hazards is a critical component of enabling and improving operational mobility and protection of US Forces. The Autonomous Mine Detection System (AMDS) developed by the US Army RDECOM CERDEC Night Vision and Electronic Sensors Directorate (NVESD) is addressing this challenge for dismounted soldiers. Under the AMDS program, ARA has developed a vapor sampling system that enhances the detection of explosive residues using commercial-off-the-shelf (COTS) sensors. The Explosives Hazard Trace Detection (EHTD) payload is designed for plug-and-play installation and operation on small robotic platforms, addressing critical Army needs for more safely detecting concealed or exposed explosives in areas such as culverts, walls and vehicles. In this paper, we describe the development, robotic integration and performance of the explosive vapor sampling system, which consists of a sampling "head," a vapor transport tube and an extendable "boom." The sampling head and transport tube are integrated with the boom, allowing samples to be collected from targeted surfaces up to 7-ft away from the robotic platform. During sample collection, an IR lamp in the sampling head is used to heat a suspected object/surface and the vapors are drawn through the heated vapor transport tube to an ion mobility spectrometer (IMS) for detection. The EHTD payload is capable of quickly (less than 30 seconds) detecting explosives such as TNT, PETN, and RDX at nanogram levels on common surfaces (brick, concrete, wood, glass, etc.).

Constraining the Energetics of Explosive Lava-Water Interactions

NASA Astrophysics Data System (ADS)

Fitch, E. P.; Fagents, S. A.

2017-12-01

During volcanic eruptions, water, such as groundwater or melted ice or snow, may interact with magma within the conduit during eruption, generating explosions when the heat of the magma causes the water to rapidly turn to steam and expand, resulting in what we call a "phreatomagmatic" eruption. In 2010, the eruption of Eyjafjallajökull volcano in Iceland produced a plume of fine ash, through the interaction between magma and glacial melt water, which resulted in the closure of substantial airspace, ultimately costing a total of almost 5 billion dollars. Although an important area of study, it is difficult to quantify the effect of eternal water on eruption intensity when the gas inside of magma is also expanding and fragmenting the magma. In an attempt to understand the energetics of magma-water interactions, small-scale laboratory experiments have been performed. Explosion energy is found to depend mostly on kinetic energy, which is proportional to dispersal distance, and fragmentation energy, which is proportional to the mean grain size of the ejecta, and the mass percent of ash-sized grains. It is thought that in order to generate heat transfer rates sufficiently rapid to cause explosive detonation, the source melt must be finely fragmented, producing ash-sized grains. Those grains undergo brittle fragmentation due to rapid cooling and weak shock waves generated by the vaporization of superheated water. We take the novel approach of studying explosive interactions between lava and water to obtain additional explosion energy constraints. We identified and analyzed numerous beds of lava-water explosion ejecta of varying explosion energy, and we analyzed the ash-sized grains of these beds in detail. We verified that the mass of ash-sized grains increases with increasing explosion energy, and can form at the interface between lava and water. We found that brittle fragmentation occurs to a greater degree as grain size decreases and that the ash of highly-energetic explosions undergoes the most brittle fragmentation. Therefore, our next steps will be to use these results to constrain the fragmentation and kinetic energy, in order to calculate the total energy and heat-transfer rate of lava-water explosions as important analogs for phreatomagmatic eruptions.

Method for digesting a nitro-bearing explosive compound

DOEpatents

Shah, Manish M.

2000-01-01

The present invention is a process wherein superoxide radicals from superoxide salt are used to break down the explosive compounds. The process has an excellent reaction rate for degrading explosives, and operates at ambient temperature and atmospheric pressure in aqueous or non-aqueous conditions. Because the superoxide molecules are small, much smaller than an enzyme molecule for example, they can penetrate the microstructure of plastic explosives faster. The superoxide salt generates reactive hydroxyl radicals, which can destroy other organic contaminants, if necessary, along with digesting the explosive nitro-bearing compound.

Infrasound Studies for Yield Estimation of HE Explosions

DTIC Science & Technology

2012-06-05

AFRL-RV-PS- AFRL-RV-PS- TR-2012-0084 TR-2012-0084 INFRASOUND STUDIES FOR YIELD ESTIMATION OF HE EXPLOSIONS Paul Golden, et al...05 Mar 2010 to 05 Mar 2012 4. TITLE AND SUBTITLE 5a. CONTRACT NUMBER FA9453-10-C-0212 Infrasound Studies for Yield Estimation of HE...report we discuss the capability of estimating the yield of an explosion from infrasound signals generated by low yield chemical explosions. We used

Explosives detection and identification using surface plasmon-coupled emission

NASA Astrophysics Data System (ADS)

Ja, Shiou-Jyh

2012-06-01

To fight against the explosives-related threats in defense and homeland security applications, a smarter sensing device that not only detects but differentiates multiple true threats from false positives caused by environmental interferents is essential. A new optical detection system is proposed to address these issues by using the temporal and spectroscopic information generated by the surface plasmon coupling emission (SPCE) effect. Innovative SPCE optics have been designed using Zemax software to project the fluorescence signal into clear "rainbow rings" on a CCD with subnanometer wavelength resolution. The spectroscopic change of the fluorescence signal and the time history of such changes due to the presence of a certain explosive analyte are unique and can be used to identify explosives. Thanks to high optical efficiency, reporter depositions as small as 160-μm in diameter can generate a sufficient signal, allowing a dense array of different reporters to be interrogated with wavelength multiplexing and detect a wide range of explosives. We have demonstrated detection and classification of explosives, such as TNT, NT, NM, RDX, PETN, and AN, with two sensing materials in a prototype.

Rapid and slow: Varying magma ascent rates as a mechanism for Vulcanian explosions

NASA Astrophysics Data System (ADS)

Cassidy, Mike; Cole, Paul. D.; Hicks, Kelby E.; Varley, Nick R.; Peters, Nial; Lerner, Allan H.

2015-06-01

Vulcanian explosions are one of the most common types of volcanic activity observed at silicic volcanoes. Magma ascent rates are often invoked as being the fundamental control on their explosivity, yet this factor is poorly constrained for low magnitude end-member Vulcanian explosions, which are particularly poorly understood, partly due to the rarity of ash samples and low gas fluxes. We describe ash generated by small Vulcanian explosions at Volcán de Colima in 2013, where we document for the first time marked differences in the vesicularity, crystal characteristics (volume fraction, size and shape) and glass compositions in juvenile material from discrete events. We interpret these variations as representing differing ascent styles and speeds of magma pulses within the conduit. Heterogeneous degassing during ascent leads to fast ascending, gas-rich magma pulses together with slow ascending gas-poor magma pulses within the same conduit. This inferred heterogeneity is complemented by SO2 flux data, which show transient episodes of both open and closed system degassing, indicating efficient shallow fracture sealing mechanisms, which allows for gas overpressure to generate small Vulcanian explosions.

Next Generation Loading System for Detonators and Primers

DTIC Science & Technology

Designed , fabricated and installed next generation tooling to provide additional manufacturing capabilities for new detonators and other small...prototype munitions on automated, semi-automated and manual machines. Lead design effort, procured and installed a primary explosive Drying Oven for a pilot...facility. Designed , fabricated and installed a Primary Explosives Waste Treatment System in a pilot environmental processing facility. Designed

Modeling and Experimental Validation for 3D mm-wave Radar Imaging

NASA Astrophysics Data System (ADS)

Ghazi, Galia

As the problem of identifying suicide bombers wearing explosives concealed under clothing becomes increasingly important, it becomes essential to detect suspicious individuals at a distance. Systems which employ multiple sensors to determine the presence of explosives on people are being developed. Their functions include observing and following individuals with intelligent video, identifying explosives residues or heat signatures on the outer surface of their clothing, and characterizing explosives using penetrating X-rays, terahertz waves, neutron analysis, or nuclear quadrupole resonance. At present, mm-wave radar is the only modality that can both penetrate and sense beneath clothing at a distance of 2 to 50 meters without causing physical harm. Unfortunately, current mm-wave radar systems capable of performing high-resolution, real-time imaging require using arrays with a large number of transmitting and receiving modules; therefore, these systems present undesired large size, weight and power consumption, as well as extremely complex hardware architecture. The overarching goal of this thesis is the development and experimental validation of a next generation inexpensive, high-resolution radar system that can distinguish security threats hidden on individuals located at 2-10 meters range. In pursuit of this goal, this thesis proposes the following contributions: (1) Development and experimental validation of a new current-based, high-frequency computational method to model large scattering problems (hundreds of wavelengths) involving lossy, penetrable and multi-layered dielectric and conductive structures, which is needed for an accurate characterization of the wave-matter interaction and EM scattering in the target region; (2) Development of combined Norm-1, Norm-2 regularized imaging algorithms, which are needed for enhancing the resolution of the images while using a minimum number of transmitting and receiving antennas; (3) Implementation and experimental validation of new calibration techniques, which are needed for coherent imaging with multistatic configurations; and (4) Investigation of novel compressive antennas, which spatially modulate the wavefield in order to enhance the information transfer efficiency between sampling and imaging regions and use of Compressive Sensing algorithms.

Compressive strength after blast of sandwich composite materials

PubMed Central

Arora, H.; Kelly, M.; Worley, A.; Del Linz, P.; Fergusson, A.; Hooper, P. A.; Dear, J. P.

2014-01-01

Composite sandwich materials have yet to be widely adopted in the construction of naval vessels despite their excellent strength-to-weight ratio and low radar return. One barrier to their wider use is our limited understanding of their performance when subjected to air blast. This paper focuses on this problem and specifically the strength remaining after damage caused during an explosion. Carbon-fibre-reinforced polymer (CFRP) composite skins on a styrene–acrylonitrile (SAN) polymer closed-cell foam core are the primary composite system evaluated. Glass-fibre-reinforced polymer (GFRP) composite skins were also included for comparison in a comparable sandwich configuration. Full-scale blast experiments were conducted, where 1.6×1.3 m sized panels were subjected to blast of a Hopkinson–Cranz scaled distance of 3.02 m kg−1/3, 100 kg TNT equivalent at a stand-off distance of 14 m. This explosive blast represents a surface blast threat, where the shockwave propagates in air towards the naval vessel. Hopkinson was the first to investigate the characteristics of this explosive air-blast pulse (Hopkinson 1948 Proc. R. Soc. Lond. A 89, 411–413 (doi:10.1098/rspa.1914.0008)). Further analysis is provided on the performance of the CFRP sandwich panel relative to the GFRP sandwich panel when subjected to blast loading through use of high-speed speckle strain mapping. After the blast events, the residual compressive load-bearing capacity is investigated experimentally, using appropriate loading conditions that an in-service vessel may have to sustain. Residual strength testing is well established for post-impact ballistic assessment, but there has been less research performed on the residual strength of sandwich composites after blast. PMID:24711494

Thermally generated magnetic fields in laser-driven compressions and explosions

NASA Technical Reports Server (NTRS)

Tidman, D. A.

1975-01-01

The evolution of thermally generated magnetic fields in a plasma undergoing a nearly spherically symmetric adiabatic compression or expansion is calculated. The analysis is applied to obtain approximate results for the development of magnetic fields in laser-driven compression and explosion of a pellet of nuclear fuel. Localized sources, such as those occurring at composition boundaries in structured pellets or at shock fronts, give stronger fields than those deriving from smoothly distributed asymmetries. Although these fields may approach 10 million G in the late stages of compression, this is not expected to present difficulties for the compression process. Assuming ignition of a nuclear explosion occurs, the sources become much stronger, and values of approximately 10 billion G are obtained at tamper boundaries assuming a 20% departure from spherical symmetry during the explosion.

Potential Use of Passive Sampling for Environmental Monitoring of Petroleum E&P Operations

EPA Pesticide Factsheets

Traditional environmental monitoring relies on water or soil samples being taken at various time increments and sent to offsite laboratories for analysis. Reliance on grab samples generally captures limited “snapshots” of environmental contaminant concentrations, is time intensive, costly, and generates residual waste from excess sample and/or reagents used in the analysis procedures. As an alternative, we are evaluating swellable organosilica sorbents to create passive sampling systems for monitoring applications. Previous work has focused on absorption and detection of fuels, chlorinated solvents, endocrine disruptors, explosives, pesticides, fluorinated chemicals, and metals including Ba, Sr, Hg, Pb, Fe, Cu, and Zn. The advantages of swellable organosilica are that the material cancapture target compounds for an extended periods of time, does not absorb natural organic matter, and resists biofilm formation since the sorbent possesses an animated surface morphology.

Infrasound Observations from the Source Physics Experiment (Tests 1 and 2) at the Nevada National Security Site

DTIC Science & Technology

2012-09-01

series of explosions, we have the unique and rare opportunity to study infrasound generated by a well-characterized source from the same borehole ...opportunity to study infrasound generated by a well-characterized source from the same borehole . This reduces the number of variables that must be...experiment is to study the seismic waves generated from explosions in both damaged and undamaged rock and that the observed infrasound is a

Quantification of Rock Damage from Small Explosions and its Effect on Shear-Wave Generation: Phase I - Homogeneous Crystalline Rock

DTIC Science & Technology

2008-09-30

We hope to quantify crack nucleation and growth (Ashby and Sammis, 1990) as an S-wave generation mechanism in the far-field (Sammis, 2002) and to map...wave generation mechanism in the far-field (Sammis, 2002) and to map the cone of damage (Patton et al. 2005; Stevens et al. 2003) above a source...Two of the proposed mechanisms for S-wave generation involve secondary processes related to the damage and deformations caused by the explosions. First

Seismic Energy Generation and Partitioning into Various Regional Phases from Different Seismic Sources in the Middle East Region

DTIC Science & Technology

2007-09-20

phases. The power law parameter values were found to be in close agreement with the constants for nuclear explosions in Nevada and chemical explosions in...caused by the difference of lithostatic pressures between top and bottom of a vertical cylindrical explosive source, typical for borehole chemical ...NORSAR recorded several decoupled chemical explosions in large chambers of underground mines in Sweden (Stevens et al., 2003), however a reference

Efficient neutron generation from solid-nanoparticle explosions driven by DPSSL-pumped high-repetition rate femtosecond laser pulse

NASA Astrophysics Data System (ADS)

Watari, T.; Matsukado, K.; Sekine, T.; Takeuchi, Y.; Hatano, Y.; Yoshimura, R.; Satoh, N.; Nishihara, K.; Takagi, M.; Kawashima, T.

2016-03-01

We propose novel neutron source using high-intensity laser based on the cluster fusion scheme. We developed DPSSL-pumped high-repetition-rate 20-TW laser system and solid nanoparticle target for neutron generation demonstration. In our neutron generation experiment, high-energy deuterons were generated from coulomb explosion of CD solid- nanoparticles and neutrons were generated by DD fusion reaction. Efficient and stable neutron generation was obtained by irradiating an intense femtosecond laser pulse of >2×1018 W/cm2. A yield of ∼105 neutrons per shot was stably observed during 0.1-1 Hz continuous operation.

38 CFR 4.56 - Evaluation of muscle disabilities.

Code of Federal Regulations, 2012 CFR

2012-07-01

... shrapnel fragment, without explosive effect of high velocity missile, residuals of debridement, or... findings. Entrance and (if present) exit scars, small or linear, indicating short track of missile through... missile or large low-velocity missile, with debridement, prolonged infection, or sloughing of soft parts...

38 CFR 4.56 - Evaluation of muscle disabilities.

Code of Federal Regulations, 2014 CFR

2014-07-01

... shrapnel fragment, without explosive effect of high velocity missile, residuals of debridement, or... findings. Entrance and (if present) exit scars, small or linear, indicating short track of missile through... missile or large low-velocity missile, with debridement, prolonged infection, or sloughing of soft parts...

38 CFR 4.56 - Evaluation of muscle disabilities.

Code of Federal Regulations, 2013 CFR

2013-07-01

... shrapnel fragment, without explosive effect of high velocity missile, residuals of debridement, or... findings. Entrance and (if present) exit scars, small or linear, indicating short track of missile through... missile or large low-velocity missile, with debridement, prolonged infection, or sloughing of soft parts...

Environmental and Ecology Branch Progress Report, 1974 through 1976 Volume 2

DTIC Science & Technology

1978-06-01

nitrogen wastes generated by manufacture of Army explosives have been studied with reqard to aeration rates, residence times, nutrient requirements...STATES ...... ....... .......................... .. 18 vii BIOLOGICAL TREATMENT OF EXPLOSIVE WASTES ..... ............. ... 19 BIOLOGICAL AEROSOLS...1976, and the information was forwarded to Chemical Systems Laboratory for inclusion in the final report to ERDA. 13 BIOLOGICAL TREATMENT OF EXPLOSIVE

An automatic detection software for differential reflection spectroscopy

NASA Astrophysics Data System (ADS)

Yuksel, Seniha Esen; Dubroca, Thierry; Hummel, Rolf E.; Gader, Paul D.

2012-06-01

Recent terrorist attacks have sprung a need for a large scale explosive detector. Our group has developed differential reflection spectroscopy which can detect explosive residue on surfaces such as parcel, cargo and luggage. In short, broad band ultra-violet and visible light is shone onto a material (such as a parcel) moving on a conveyor belt. Upon reflection off the surface, the light intensity is recorded with a spectrograph (spectrometer in combination with a CCD camera). This reflected light intensity is then subtracted and normalized with the next data point collected, resulting in differential reflection spectra in the 200-500 nm range. Explosives show spectral finger-prints at specific wavelengths, for example, the spectrum of 2,4,6, trinitrotoluene (TNT) shows an absorption edge at 420 nm. Additionally, we have developed an automated software which detects the characteristic features of explosives. One of the biggest challenges for the algorithm is to reach a practical limit of detection. In this study, we introduce our automatic detection software which is a combination of principal component analysis and support vector machines. Finally we present the sensitivity and selectivity response of our algorithm as a function of the amount of explosive detected on a given surface.

Gas chromatography/ion mobility spectrometry as a hyphenated technique for improved explosives detection and analysis

NASA Technical Reports Server (NTRS)

Mercado, AL; Marsden, Paul

1995-01-01

Ion Mobility Spectrometry (IMS) is currently being successfully applied to the problem of on-line trace detection of plastic and other explosives in airports and other facilities. The methods of sample retrieval primarily consist of batch sampling for particulate residue on a filter card for introduction into the IMS. The sample is desorbed into the IMS using air as the carrier and negative ions of the explosives are detected, some as an adduct with a reagent ion such as Cl(-). Based on studies and tests conducted by different airport authorities, this method seems to work well for low vapor pressure explosives such as RDX and PETN, as well as TNT that are highly adsorptive and can be found in nanogram quantities on contaminated surfaces. Recently, the changing terrorist threat and the adoption of new marking agents for plastic explosives has meant that the sample introduction and analysis capabilities of the IMS must be enhanced in order to keep up with other detector developments. The IMS has sufficient analytical resolution for a few threat compounds but the IMS Plasmogram becomes increasingly more difficult to interpret when the sample mixture gets more complex.

Generation of ultra-fast cumulative water jets by sub-microsecond underwater electrical explosion of conical wire arrays

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shafer, D.; Gurovich, V. Tz.; Gleizer, S.

The results of experiments with underwater electrical explosion of modified conical arrays of copper and aluminum wires are presented. A pulsed generator producing a 550 kA-amplitude current with a 400 ns rise time was used in the explosion of the arrays. The array explosion generates water flows converging at the axis of the cone. This flow generates a fast-moving water jet with a velocity exceeding 1.8 × 10{sup 5 }cm/s, which was observed being ejected from the surface of the water covering the array. The positions of the water jet were measured by multiple-exposure fast framing imaging. In experiments, the apex angle of the array,more » the thickness of the water layer above the arrays, or the material of the wires was altered, which changed the resulting velocities and shapes of the emitted jets. A model that considers the converging stationary flow of a slightly compressible fluid is suggested. The velocities and shapes of the jets obtained by this model agree well with the experimentally measured jet velocities.« less

Apparatus and methods for real-time detection of explosives devices

DOEpatents

Blackburn, Brandon W [Idaho Falls, ID; Hunt, Alan W [Pocatello, ID; Chichester, David L [Idaho Falls, ID

2014-01-07

The present disclosure relates, according to some embodiments, to apparatus, devices, systems, and/or methods for real-time detection of a concealed or camouflaged explosive device (e.g., EFPs and IEDs) from a safe stand-off distance. Apparatus, system and/or methods of the disclosure may also be operable to identify and/or spatially locate and/or detect an explosive device. An apparatus or system may comprise an x-ray generator that generates high-energy x-rays and/or electrons operable to contact and activate a metal comprised in an explosive device from a stand-off distance; and a detector operable to detect activation of the metal. Identifying an explosive device may comprise detecting characteristic radiation signatures emitted by metals specific to an EFP, an IED or a landmine. Apparatus and systems of the disclosure may be mounted on vehicles and methods of the disclosure may be performed while moving in the vehicle and from a safe stand-off distance.

Development of multi-component explosive lenses for arbitrary phase velocity generation

NASA Astrophysics Data System (ADS)

Loiseau, Jason; Huneault, Justin; Petel, Oren; Goroshin, Sam; Frost, David; Higgins, Andrew; Zhang, Fan

2013-06-01

The combination of explosives with different detonation velocities and lens-like geometric shaping is a well-established technique for producing structured detonation waves. This technique can be extended to produce nearly arbitrary detonation phase velocities for the purposes of sequentially imploding pressurized tubes or driving Mach disks through high-density metalized explosives. The current study presents the experimental development of accelerating, multi-component lenses designed using simple geometric optics and idealized front curvature. The fast explosive component is either Composition C4 (VOD = 8 km/s) or Primasheet 1000 (VOD = 7 km/s), while the slow component varies from heavily amine-diluted nitromethane (amine mass fraction exceeding 20%) to packed metal and glass particle beds wetted with amine-sensitized nitromethane. The applicability of the geometric optic analog to such highly heterogeneous explosives is also investigated. The multi-layered lens technique is further developed as a means of generating a directed mass and momentum flux of metal particles via Mach-disk formation and jetting in circular and oval planar lenses.

Instant detection and identification of concealed explosive-related compounds: Induced Stokes Raman versus infrared.

PubMed

Elbasuney, Sherif; El-Sherif, Ashraf F

2017-01-01

The instant detection of explosives and explosive-related compounds has become an urgent priority in recent years for homeland security and counter-terrorism applications. Modern techniques should offer enhancement in selectivity, sensitivity, and standoff distances. Miniaturisation, portability, and field-ruggedisation are crucial requirements. This study reports on instant and standoff identification of concealed explosive-related compounds using customized Raman technique. Stokes Raman spectra of common explosive-related compounds were generated and spectrally resolved to create characteristic finger print spectra. The scattered Raman emissions over the band 400:2000cm -1 were compared to infrared absorption using FTIR. It has been demonstrated that the two vibrational spectroscopic techniques were opposite and completing each other. Molecular vibrations with strong absorption in infrared (those involve strong change in dipole moments) induced weak signals in Raman and vice versa. The tailored Raman offered instant detection, high sensitivity, and standoff detection capabilities. Raman demonstrated characteristic fingerprint spectra with stable baseline and sharp intense peaks. Complete correlations of absorption/scattered signals to certain molecular vibrations were conducted to generate an entire spectroscopic profile of explosive-related compounds. This manuscript shades the light on Raman as one of the prevailing technologies for instantaneous detection of explosive-related compounds. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

Experimental model of the role of cracks in the mechanism of explosive eruption of St. Helens-80

NASA Astrophysics Data System (ADS)

Kedrinskii, V. K.; Skulkin, A. A.

2017-07-01

A unique mini model of explosive volcano eruption through a formed system of cracks is developed. The process of crack formation and development is simulated by electric explosion of a conductor in a plate of optically transparent organic glass submerged into water. The explosion of a wire aligned with a through hole in the plate generates shock-wave loading along the plate and forms cracks. The fundamental role of high velocity flow in crack wedging by a high power hydrodynamic flow of a pulsating explosion cavity has been demonstrated.

Rg to Lg Scattering Observations and Modeling

NASA Astrophysics Data System (ADS)

Baker, G. E.; Stevens, J. L.; Xu, H.

2005-12-01

Lg is important to explosion yield estimation and earthquake/explosion discrimination, but the source of explosion generated Lg is still an area of active investigation. We investigate the contribution of Rg scattering to Lg. Common spectral nulls in vertical component Rg and Lg have been interpreted as evidence that scattered Rg is the dominant source of Lg in some areas. The nulls are assumed to result from non-spherical components of the explosion source, modeled as a CLVD located above the explosion. We compare Rg with 3-component Sg and Lg spectra in different source areas. Wavenumber synthetics and nonlinear source calculations constrain the predicted source spectra of Rg and directly generated Lg. Modal scattering calculations place bounds on the contribution of Rg to Lg relative to pS, S*, and directly generated S-waves. Rg recorded east and west of the Quartz 3 Deep Seismic Sounding explosion have persistent spectral nulls, but at different frequencies. The azimuthal dependence of the source spectra suggests that it may not be simply related to a CLVD source. The spectral nulls of Sg, Lg, and Lg coda do not correspond to the Rg spectral nulls, so for this overburied source, the spectral observations do not indicate that Rg scattering is a dominant contributor to Lg. Preliminary comparisons of Rg with Lg spectra for events from the Semipalatinsk Test Site yield a similar result. We compare Rg at 20-100 km with Lg at 650 km for Balapan and Degelen explosions with known yield and source depth. The events range from 130 to 50 percent of theoretical containment depth, so relative contributions from a CLVD are expected to vary significantly. For studied previously NTS and Kazakh depth of burial data, the use of 3-components provides further insight into scattering between components. In a complementary analysis, to assess whether S-wave generation is affected by source depth or scaled depth, we have examined regional phase amplitudes of 13 Degelen explosions with known yields and source depths. Initial Pn, the entire P wavetrain, Sn, Lg, and Lg coda have similar log amplitude vs. log yield curves. The slope of those curves varies with frequency, from approximately 0.84 at 0.6 Hz to 0.65 at 6 Hz. We will complement these results with similar observations of Balapan explosion records.

Explosion probability of unexploded ordnance: expert beliefs.

PubMed

MacDonald, Jacqueline Anne; Small, Mitchell J; Morgan, M G

2008-08-01

This article reports on a study to quantify expert beliefs about the explosion probability of unexploded ordnance (UXO). Some 1,976 sites at closed military bases in the United States are contaminated with UXO and are slated for cleanup, at an estimated cost of $15-140 billion. Because no available technology can guarantee 100% removal of UXO, information about explosion probability is needed to assess the residual risks of civilian reuse of closed military bases and to make decisions about how much to invest in cleanup. This study elicited probability distributions for the chance of UXO explosion from 25 experts in explosive ordnance disposal, all of whom have had field experience in UXO identification and deactivation. The study considered six different scenarios: three different types of UXO handled in two different ways (one involving children and the other involving construction workers). We also asked the experts to rank by sensitivity to explosion 20 different kinds of UXO found at a case study site at Fort Ord, California. We found that the experts do not agree about the probability of UXO explosion, with significant differences among experts in their mean estimates of explosion probabilities and in the amount of uncertainty that they express in their estimates. In three of the six scenarios, the divergence was so great that the average of all the expert probability distributions was statistically indistinguishable from a uniform (0, 1) distribution-suggesting that the sum of expert opinion provides no information at all about the explosion risk. The experts' opinions on the relative sensitivity to explosion of the 20 UXO items also diverged. The average correlation between rankings of any pair of experts was 0.41, which, statistically, is barely significant (p= 0.049) at the 95% confidence level. Thus, one expert's rankings provide little predictive information about another's rankings. The lack of consensus among experts suggests that empirical studies are needed to better understand the explosion risks of UXO.

Coulomb explosion of “hot spot”

DOE Office of Scientific and Technical Information (OSTI.GOV)

Oreshkin, V. I., E-mail: oreshkin@ovpe.hcei.tsc.ru; Tomsk Polytechnic University, Tomsk; Oreshkin, E. V.

The study presented in this paper has shown that the generation of hard x rays and high-energy ions, which are detected in pinch implosion experiments, may be associated with the Coulomb explosion of the hot spot that is formed due to the outflow of the material from the pinch cross point. During the process of material outflow, the temperature of the hot spot plasma increases, and conditions arise for the plasma electrons to become continuously accelerated. The runaway of electrons from the hot spot region results in the buildup of positive space charge in this region followed by a Coulombmore » explosion. The conditions for the hot spot plasma electrons to become continuously accelerated have been revealed, and the estimates have been obtained for the kinetic energy of the ions generated by the Coulomb explosion.« less

Calibration methods for explosives detectors

NASA Astrophysics Data System (ADS)

MacDonald, Stephen J.; Rounbehler, David P.

1992-05-01

Airport security has become an important concern to cultures in every corner of the world. Presently, efforts to improve airport security have brought additional technological solutions, in the form of advanced instrumentation for the detection of explosives, into use at airport terminals in many countries. This new generation of explosives detectors is often used to augment existing security measures and provide a more encompassing screening capability for airline passengers. This paper describes two calibration procedures used for the Thermedics' EGIS explosives detectors. The systems were designed to screen people, electronic components, luggage, automobiles, and other objects for the presence of concealed explosives. The detectors have the ability to detect a wide range of explosives in both the vapor state or as surface adsorbed solids, therefore, calibrations were designed to challenge the system with explosives in each form.

Synthesis of TiCx Powder via the Underwater Explosion of an Explosive

NASA Astrophysics Data System (ADS)

Tanaka, Shigeru; Bataev, Ivan; Hamashima, Hideki; Tsurui, Akihiko; Hokamoto, Kazuyuki

2018-05-01

In this study, a novel approach to the explosive synthesis of titanium carbide (TiC) is discussed. Nonstoichiometric TiCx powder was produced via the underwater explosion of a Ti powder encapsulated within a spherical explosive charge. The explosion process, bubble formation, and synthesis process were visualized using high-speed camera imaging. It was concluded that synthesis occurred within the detonation gas during the first expansion/contraction cycle of the bubble, which was accompanied by a strong emission of light. The recovered powders were studied using scanning electron microscopy and X-ray diffraction. Submicron particles were generated during the explosion. An increase in the carbon content of the starting powder resulted in an increase in the carbon content of the final product. No oxide byproducts were observed within the recovered powders.

Identification of inorganic improvised explosive devices by analysis of postblast residues using portable capillary electrophoresis instrumentation and indirect photometric detection with a light-emitting diode.

PubMed

Hutchinson, Joseph P; Evenhuis, Christopher J; Johns, Cameron; Kazarian, Artaches A; Breadmore, Michael C; Macka, Miroslav; Hilder, Emily F; Guijt, Rosanne M; Dicinoski, Greg W; Haddad, Paul R

2007-09-15

A commercial portable capillary electrophoresis (CE) instrument has been used to separate inorganic anions and cations found in postblast residues from improvised explosive devices (IEDs) of the type used frequently in terrorism attacks. The purpose of this analysis was to identify the type of explosive used. The CE instrument was modified for use with an in-house miniaturized light-emitting diode (LED) detector to enable sensitive indirect photometric detection to be employed for the detection of 15 anions (acetate, benzoate, carbonate, chlorate, chloride, chlorite, cyanate, fluoride, nitrate, nitrite, perchlorate, phosphate, sulfate, thiocyanate, thiosulfate) and 12 cations (ammonium, monomethylammonium, ethylammonium, potassium, sodium, barium, strontium, magnesium, manganese, calcium, zinc, lead) as the target analytes. These ions are known to be present in postblast residues from inorganic IEDs constructed from ammonium nitrate/fuel oil mixtures, black powder, and chlorate/perchlorate/sugar mixtures. For the analysis of cations, a blue LED (470 nm) was used in conjunction with the highly absorbing cationic dye, chrysoidine (absorption maximum at 453 nm). A nonaqueous background electrolyte comprising 10 mM chrysoidine in methanol was found to give greatly improved baseline stability in comparison to aqueous electrolytes due to the increased solubility of chrysoidine and its decreased adsorption onto the capillary wall. Glacial acetic acid (0.7% v/v) was added to ensure chrysoidine was protonated and to enhance separation selectivity by means of complexation with transition metal ions. The 12 target cations were separated in less than 9.5 min with detection limits of 0.11-2.30 mg/L (calculated at a signal-to-noise ratio of 3). The anions separation system utilized a UV LED (370 nm) in conjunction with an aqueous chromate electrolyte (absorption maximum at 371 nm) consisting of 10 mM chromium(VI) oxide and 10 mM sodium chromate, buffered with 40 mM tris(hydroxymethyl)aminomethane at pH 8.05. All 15 target anions were baseline separated in less than 9 min with limits of detection ranging from 0.24 to 1.15 mg/L (calculated at a signal-to-noise ratio of 3). Use of the portable instrumentation in the field was demonstrated by analyzing postblast residues in a mobile laboratory immediately after detonation of the explosive devices. Profiling the ionic composition of the inorganic IEDs allowed identification of the chemicals used in their construction.

Identification of inorganic improvised explosive devices using sequential injection capillary electrophoresis and contactless conductivity detection.

PubMed

Blanco, Gustavo A; Nai, Yi H; Hilder, Emily F; Shellie, Robert A; Dicinoski, Greg W; Haddad, Paul R; Breadmore, Michael C

2011-12-01

A simple sequential injection capillary electrophoresis (SI-CE) instrument with capacitively coupled contactless conductivity detection (C(4)D) has been developed for the rapid separation of anions relevant to the identification of inorganic improvised explosive devices (IEDs). Four of the most common explosive tracer ions, nitrate, perchlorate, chlorate, and azide, and the most common background ions, chloride, sulfate, thiocyanate, fluoride, phosphate, and carbonate, were chosen for investigation. Using a separation electrolyte comprising 50 mM tris(hydroxymethyl)aminomethane, 50 mM cyclohexyl-2-aminoethanesulfonic acid, pH 8.9 and 0.05% poly(ethyleneimine) (PEI) in a hexadimethrine bromide (HDMB)-coated capillary it was possible to partially separate all 10 ions within 90 s. The combination of two cationic polymer additives (PEI and HDMB) was necessary to achieve adequate selectivity with a sufficiently stable electroosmotic flow (EOF), which was not possible with only one polymer. Careful optimization of variables affecting the speed of separation and injection timing allowed a further reduction of separation time to 55 s while maintaining adequate efficiency and resolution. Software control makes high sample throughput possible (60 samples/h), with very high repeatability of migration times [0.63-2.07% relative standard deviation (RSD) for 240 injections]. The separation speed does not compromise sensitivity, with limits of detection ranging from 23 to 50 μg·L(-1) for all the explosive residues considered, which is 10× lower than those achieved by indirect absorbance detection and 2× lower than those achieved by C(4)D using portable benchtop instrumentation. The combination of automation, high sample throughput, high confidence of peak identification, and low limits of detection makes this methodology ideal for the rapid identification of inorganic IED residues.

Explosive laser light initiation of propellants

DOEpatents

Piltch, Martin S.

1993-01-01

A improved initiator for artillery shell using an explosively generated laser light to uniformly initiate the propellent. A small quantity of a high explosive, when detonated, creates a high pressure and temperature, causing the surrounding noble gas to fluoresce. This fluorescence is directed into a lasing material, which lases, and directs laser light into a cavity in the propellant, uniformly initiating the propellant.

Explosive laser light initiation of propellants

DOEpatents

Piltch, M.S.

1993-05-18

A improved initiator for artillery shell using an explosively generated laser light to uniformly initiate the propellent. A small quantity of a high explosive, when detonated, creates a high pressure and temperature, causing the surrounding noble gas to fluoresce. This fluorescence is directed into a lasing material, which lases, and directs laser light into a cavity in the propellant, uniformly initiating the propellant.

Laser vaporization of trace explosives for enhanced non-contact detection

NASA Astrophysics Data System (ADS)

Furstenberg, Robert; Papantonakis, Michael; Kendziora, Christopher A.; Bubb, Daniel M.; Corgan, Jeffrey; McGill, R. Andrew

2010-04-01

Trace explosives contamination is found primarily in the form of solid particulates on surfaces, due to the low vapor pressure of most explosives materials. Today, the standard sampling procedure involves physical removal of particulate matter from surfaces of interest. A variety of collection methods have been used including air-jetting or swabbing surfaces of interest. The sampled particles are typically heated to generate vapor for analysis in hand held, bench top, or portal detection systems. These sampling methods are time-consuming (and hence costly), require a skilled technician for optimal performance, and are inherently non-selective, allowing non-explosives particles to be co-sampled and analyzed. This can adversely affect the sensitivity and selectivity of detectors, especially those with a limited dynamic range. We present a new approach to sampling solid particles on a solid surface that is targeted, non-contact, and which selectively enhances trace explosive signatures thus improving the selectivity and sensitivity of existing detectors. Our method involves the illumination of a surface of interest with infrared laser light with a wavelength that matches a distinctive vibrational mode of an explosive. The resonant coupling of laser energy results in rapid heating of explosive particles and rapid release of a vapor plume. Neighboring particles unrelated to explosives are generally not directly heated as their vibrational modes are not resonant with the laser. As a result, the generated vapor plume includes a higher concentration of explosives than if the particles were heated with a non-selective light source (e.g. heat lamp). We present results with both benchtop infrared lasers as well as miniature quantum cascade lasers.

Effect of initial moisture content and chip size on the bioconversion efficiency of softwood lignocellulosics.

PubMed

Cullis, Ian F; Saddler, John N; Mansfield, Shawn D

2004-02-20

Previous optimization strategies for the bioconversion of lignocellulosics by steam explosion technologies have focused on the effects of temperature, pH, and treatment time, but have not accounted for changes in severity brought about by properties inherent in the starting feedstock. Consequently, this study evaluated the effects of chip properties, feedstock size (40-mesh, 1.5 x 1.5 cm, 5 x 5 cm), and moisture content (12% and 30%) on the overall bioconversion process, and more specifically on the efficacy of removal of recalcitrant lignin from the lignocellulosic substrates following steam explosion. Increasing chip size resulted in an improvement in the solids recovery, with concurrent increases in the water soluble, hemicellulose-derived sugar recovery (7.5%). This increased recovery is a result of a decrease in the "relative severity" of the pretreatment as chip size increases. Additionally, the decreased relative severity minimized the condensation of the recalcitrant residual lignin and therefore increased the efficacy of peroxide fractionation, where a 60% improvement in lignin removal was possible with chips of larger initial size. Similarly, increased initial moisture content reduced the relative severity of the pretreatment, generating improved solids and hemicellulose-derived carbohydrate recovery. Both increased chip size and higher initial moisture content results in a substrate that performs better during peroxide delignification, and consequently enzymatic hydrolysis. Furthermore, a post steam-explosion refining step increased hemicellulose-derived sugar recovery and was most effectively delignified (to as low as 6.5%). The refined substrate could be enzymatically hydrolyzed to very high levels (98%) and relatively fast rates (1.23 g/L/h). Copyright 2004 Wiley Periodicals, Inc.

Blast waves and how they interact with structures.

PubMed

Cullis, I G

2001-02-01

The paper defines and describes blast waves, their interaction with a structure and its subsequent response. Explosions generate blast waves, which need not be due to explosives. A blast wave consists of two parts: a shock wave and a blast wind. The paper explains how shock waves are formed and their basic properties. The physics of blast waves is non-linear and therefore non-intuitive. To understand how an explosion generates a blast wave a numerical modelling computer code, called a hydrocode has to be employed. This is briefly explained and the cAst Eulerian hydrocode is used to illustrate the formation and propagation of the blast wave generated by a 1 kg sphere of TNT explosive detonated 1 m above the ground. The paper concludes with a discussion of the response of a structure to a blast wave and shows that this response is governed by the structures natural frequency of vibration compared to the duration of the blast wave. The basic concepts introduced are illustrated in a second simulation that introduces two structures into the blast field of the TNT charge.

Improved thermal neutron activation sensor for detection of bulk explosives

NASA Astrophysics Data System (ADS)

McFee, John E.; Faust, Anthony A.; Andrews, H. Robert; Clifford, Edward T. H.; Mosquera, Cristian M.

2012-06-01

Defence R&D Canada - Suffield and Bubble Technology Industries have been developing thermal neutron activation (TNA) sensors for detection of buried bulk explosives since 1994. First generation sensors, employing an isotopic source and NaI(Tl) gamma ray detectors, were deployed by Canadian Forces in 2002 as confirmation sensors on the ILDS teleoperated, vehicle-mounted, multi-sensor anti-tank landmine detection systems. The first generation TNA could detect anti-tank mines buried 10 cm or less in no more than a minute, but deeper mines and those significantly displaced horizontally required considerably longer times. Mines as deep as 30 cm could be detected with long counting times (1000 s). The second generation TNA detector is being developed with a number of improvements aimed at increasing sensitivity and facilitating ease of operation. Among these are an electronic neutron generator to increase sensitivity for deeper and horizontally displaced explosives; LaBr3(Ce) scintillators, to improve time response and energy resolution; improved thermal and electronic stability; improved sensor head geometry to minimize spatial response nonuniformity; and more robust data processing. This improved sensitivity can translate to either decreased counting times, decreased minimum detectable explosive quantities, increased maximum sensor-to-target displacement, or a trade off among all three. Experiments to characterize the performance of the latest generation TNA in detecting buried landmines and IEDs hidden in culverts were conducted during 2011. This paper describes the second generation system. The experimental setup and methodology are detailed and preliminary comparisons between the performance of first and second generation systems are presented.

Regional Seismic Methods of Identifying Explosions

NASA Astrophysics Data System (ADS)

Walter, W. R.; Ford, S. R.; Pasyanos, M.; Pyle, M. L.; Hauk, T. F.

2013-12-01

A lesson from the 2006, 2009 and 2013 DPRK declared nuclear explosion Ms:mb observations is that our historic collection of data may not be representative of future nuclear test signatures (e.g. Selby et al., 2012). To have confidence in identifying future explosions amongst the background of other seismic signals, we need to put our empirical methods on a firmer physical footing. Here we review the two of the main identification methods: 1) P/S ratios and 2) Moment Tensor techniques, which can be applied at the regional distance (200-1600 km) to very small events, improving nuclear explosion monitoring and confidence in verifying compliance with the Comprehensive Nuclear-Test-Ban Treaty (CTBT). Amplitude ratios of seismic P-to-S waves at sufficiently high frequencies (~>2 Hz) can identify explosions among a background of natural earthquakes (e.g. Walter et al., 1995). However the physical basis for the generation of explosion S-waves, and therefore the predictability of this P/S technique as a function of event properties such as size, depth, geology and path, remains incompletely understood. Calculated intermediate period (10-100s) waveforms from regional 1-D models can match data and provide moment tensor results that separate explosions from earthquakes and cavity collapses (e.g. Ford et al. 2009). However it has long been observed that some nuclear tests produce large Love waves and reversed Rayleigh waves that complicate moment tensor modeling. Again the physical basis for the generation of these effects from explosions remains incompletely understood. We are re-examining regional seismic data from a variety of nuclear test sites including the DPRK and the former Nevada Test Site (now the Nevada National Security Site (NNSS)). Newer relative amplitude techniques can be employed to better quantify differences between explosions and used to understand those differences in term of depth, media and other properties. We are also making use of the Source Physics Experiments (SPE) at NNSS. The SPE chemical explosions are explicitly designed to improve our understanding of emplacement and source material effects on the generation of shear and surface waves (e.g. Snelson et al., 2013). Our goal is to improve our explosion models and our ability to understand and predict where P/S and moment tensor methods of identifying explosions work, and any circumstances where they may not. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Star formation in proto dwarf galaxies

NASA Technical Reports Server (NTRS)

Noriega-Crespo, A.; Bodenheimer, P.; Lin, D. N. C.; Tenorio-Tagle, G.

1990-01-01

The effects of the onset of star formation on the residual gas in primordial low-mass Local-Group dwarf spheroidal galaxies is studied by a series of hydrodynamical simulations. The models have concentrated on the effect of photoionization. The results indicate that photoionization in the presence of a moderate gas density gradient can eject most of the residual gas on a time scale of a few 10 to the 7th power years. High central gas density combined with inefficient star formation, however, may prevent mass ejection. The effect of supernova explosions is discussed briefly.

Explosives signatures and analysis

NASA Astrophysics Data System (ADS)

Fountain, Augustus Way, III; Oyler, Jonathan M.; Ostazeski, Stanley A.

2008-04-01

The challenge of sampling explosive materials for various high threat military and civilian operational scenarios requires the community to identify and exploit other chemical compounds within the mixtures that may be available to support stand-off detection techniques. While limited surface and vapor phase characterization of IEDs exist, they are insufficient to guide the future development and evaluation of field deployable explosives detection (proximity and standoff) capabilities. ECBC has conducted a limited investigation of three artillery ammunition types to determine what chemical vapors, if any, are available for sensing; the relative composition of the vapors which includes the more volatile compounds in munitions, i.e., plastersizers and binders; and the sensitivity needed detect these vapors at stand-off. Also in partnership with MIT-Lincoln Laboratory, we performed a background measurement campaign at the National Training Center to determine the baseline ambient amounts and variability of nitrates and nitro-ester compounds as vapors, particulates, and on surfaces; as well as other chemical compounds related to non-energetic explosive additives. Environmental persistence studies in contexts relevant to counter-IED sensing operations, such as surface residues, are still necessary.

A review on several key problems of standoff trace explosives detection by optical-related technology

NASA Astrophysics Data System (ADS)

Chen, Zhibin; Xiao, Cheng; Xiao, Wenjian; Qin, Mengze; Liu, Xianhong

2016-01-01

To prevent tragic disasters caused by terror acts and warfare threats, security check personnel must be capable of discovering, distinguishing and eliminating the explosives at multiple circumstances. Standoff technology for the remote detection of explosives and their traces on contaminated surfaces is a research field that has become a heightened priority in recent years for homeland security and counter-terrorism applications. There has been a huge increase in research within this area, the improvement of standoff trace explosives detection by optical-related technology. This paper provides a consolidation of information relating to recent advances in several key problems of, without being limited to one specific research area or explosive type. Working laser wavelength of detection system is discussed. Generation and collection of explosives spectra signal are summarized. Techniques for analysing explosives spectra signal are summed up.

Pyrophoric sulfides influence over the minimum ignition temperature of dust cloud

NASA Astrophysics Data System (ADS)

Prodan, Maria; Lupu, Leonard Andrei; Ghicioi, Emilian; Nalboc, Irina; Szollosi-Mota, Andrei

2017-12-01

The dust cloud is the main form of existence of combustible dust in the production area and together with the existence of effective ignition sources are the main causes of dust explosions in production processes. The minimum ignition temperature has an important role in the process of selecting the explosion-protected electrical equipment when performing the explosion risk assessment of combustible dusts. The heated surfaces are able to ignite the dust clouds that can form in process industry. The oil products usually contain hydrogen sulfide and thus on the pipe walls iron sulfides can form, which can be very dangerous from health and safety point of view. In order to study the influence of the pyrophoric sulfide over the minimum ignition temperature of combustible dusts for this work were performed several experiments on a residue collected from the oil pipes contaminated with commercially iron sulfide.

Thermally driven advection for radioxenon transport from an underground nuclear explosion

NASA Astrophysics Data System (ADS)

Sun, Yunwei; Carrigan, Charles R.

2016-05-01

Barometric pumping is a ubiquitous process resulting in migration of gases in the subsurface that has been studied as the primary mechanism for noble gas transport from an underground nuclear explosion (UNE). However, at early times following a UNE, advection driven by explosion residual heat is relevant to noble gas transport. A rigorous measure is needed for demonstrating how, when, and where advection is important. In this paper three physical processes of uncertain magnitude (oscillatory advection, matrix diffusion, and thermally driven advection) are parameterized by using boundary conditions, system properties, and source term strength. Sobol' sensitivity analysis is conducted to evaluate the importance of all physical processes influencing the xenon signals. This study indicates that thermally driven advection plays a more important role in producing xenon signals than oscillatory advection and matrix diffusion at early times following a UNE, and xenon isotopic ratios are observed to have both time and spatial dependence.

Characterization of an Explosion Source in a Complex Medium by Modeling and Wavelet Domain Inversion

DTIC Science & Technology

2006-06-01

1 2. Mechanisms on Scattering due to an Explosive Source...the S wave at the tunnel. TRA has great potential for determining the seismic source properties. 2 2. Mechanisms on Scattering due to an Explosive...and prominent SH and Love waves. Various mechanisms have been proposed to explain the generation of these transverse waves. 2.2 Objectives of This

Time Evolution of the Density Field of a Micro-Explosion Using Background Oriented Schlieren

NASA Astrophysics Data System (ADS)

Suriyanarayanan, P.; Venkatakrishnan, L.; Jagadeesh, G.

In recent years micro-explosions have found interesting trans-disciplinary applications in the areas of food preservation,wood science, drug delivery, gene therapy and bio-medical applications [1, 2]. Generating controlled micro-explosions in a laboratory environment in a reliable manner is essential; to study and understand some of the near field flow dynamics associated with blast waves.

Modeling Explosion Induced Aftershocks

NASA Astrophysics Data System (ADS)

Kroll, K.; Ford, S. R.; Pitarka, A.; Walter, W. R.; Richards-Dinger, K. B.

2017-12-01

Many traditional earthquake-explosion discrimination tools are based on properties of the seismic waveform or their spectral components. Common discrimination methods include estimates of body wave amplitude ratios, surface wave magnitude scaling, moment tensor characteristics, and depth. Such methods are limited by station coverage and noise. Ford and Walter (2010) proposed an alternate discrimination method based on using properties of aftershock sequences as a means of earthquakeexplosion differentiation. Previous studies have shown that explosion sources produce fewer aftershocks that are generally smaller in magnitude compared to aftershocks of similarly sized earthquake sources (Jarpe et al., 1994, Ford and Walter, 2010). It has also been suggested that the explosion-induced aftershocks have smaller Gutenberg- Richter b-values (Ryall and Savage, 1969) and that their rates decay faster than a typical Omori-like sequence (Gross, 1996). To discern whether these observations are generally true of explosions or are related to specific site conditions (e.g. explosion proximity to active faults, tectonic setting, crustal stress magnitudes) would require a thorough global analysis. Such a study, however, is hindered both by lack of evenly distributed explosion-sources and the availability of global seismicity data. Here, we employ two methods to test the efficacy of explosions at triggering aftershocks under a variety of physical conditions. First, we use the earthquake rate equations from Dieterich (1994) to compute the rate of aftershocks related to an explosion source assuming a simple spring-slider model. We compare seismicity rates computed with these analytical solutions to those produced by the 3D, multi-cycle earthquake simulator, RSQSim. We explore the relationship between geological conditions and the characteristics of the resulting explosion-induced aftershock sequence. We also test hypothesis that aftershock generation is dependent upon the frequency content of the passing dynamic seismic waves as suggested by Parsons and Velasco (2009). Lastly, we compare all results of explosion-induced aftershocks with aftershocks generated by similarly sized earthquake sources. Prepared by LLNL under Contract DE-AC52-07NA27344.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gisler, Galen R.; Weaver, R. P.; Mader, Charles L.

Kick-em Jenny, in the Eastern Caribbean, is a submerged volcanic cone that has erupted a dozen or more times since its discovery in 1939. The most likely hazard posed by this volcano is to shipping in the immediate vicinity (through volcanic missiles or loss-of-buoyancy), but it is of interest to estimate upper limits on tsunamis that might be produced by a catastrophic explosive eruption. To this end, we have performed two-dimensional simulations of such an event in a geometry resembling that of Kick-em Jenny with our SAGE adaptive mesh Eulerian multifluid compressible hydrocode. We use realistic equations of state formore » air, water, and basalt, and follow the event from the initial explosive eruption, through the generation of a transient water cavity and the propagation of waves away from the site. We find that even for extremely catastrophic explosive eruptions, tsunamis from Kick-em Jenny are unlikely to pose significant danger to nearby islands. For comparison, we have also performed simulations of explosive eruptions at the much larger shield volcano Vailuluu in the Samoan chain, where the greater energy available can produce a more impressive wave. In general, however, we conclude that explosive eruptions do not couple well to water waves. The waves that are produced from such events are turbulent and highly dissipative, and don't propagate well. This is consistent with what we have found previously in simulations of asteroid-impact generated tsunamis. Non-explosive events, however, such as landslides or gas hydrate releases, do couple well to waves, and our simulations of tsunamis generated by subaerial and sub-aqueous landslides demonstrate this.« less

Frequency selective detection of nuclear quadrupole resonance (NQR) spin echoes

NASA Astrophysics Data System (ADS)

Somasundaram, Samuel D.; Jakobsson, Andreas; Smith, John A. S.; Althoefer, Kaspar A.

2006-05-01

Nuclear Quadrupole Resonance (NQR) is a radio frequency (RF) technique that can be used to detect the presence of quadrupolar nuclei, such as the 14N nucleus prevalent in many explosives and narcotics. The technique has been hampered by low signal-to-noise ratios and is further aggravated by the presence of RF interference (RFI). To ensure accurate detection, proposed detectors should exploit the rich form of the NQR signal. Furthermore, the detectors should also be robust to any remaining residual interference, left after suitable RFI mitigation has been employed. In this paper, we propose a new NQR data model, particularly for the realistic case where multiple pulse sequences are used to generate trains of spin echoes. Furthermore, we refine two recently proposed approximative maximum likelihood (AML) detectors, enabling the algorithm to optimally exploit the data model of the entire echo train and also incorporate knowledge of the temperature dependent spin-echo decay time. The AML-based detectors ensure accurate detection and robustness against residual RFI, even when the temperature of the sample is not precisely known, by exploiting the dependencies of the NQR resonant lines on temperature. Further robustness against residual interference is gained as the proposed detector is frequency selective; exploiting only those regions of the spectrum where the NQR signal is expected. Extensive numerical evaluations based on both simulated and measured NQR data indicate that the proposed Frequency selective Echo Train AML (FETAML) detector offers a significant improvement as compared to other existing detectors.

Steam explosion of oil palm residues for the production of durable pellets

DOE PAGES

Lam, Pak Sui; Lam, Pak Yiu; Sokhansanj, Shahab; ...

2015-01-03

Here we investigated the effect of steam explosion pretreatment on the physical and mechanical properties of the pellets made from empty fruit bunch (EFB) and palm kernel shell (PKS) and we compared to that of softwood Douglas fir (DF). We found that the high heating value of the empty fruit bunch was increased by 21% after steam explosion pretreatment. The pellet density of EFB and Douglas fir pellets did not change while the pellet density of PKS increased from 1.13 to 1.21 g/cm 3 after steam explosion. That may be attributed to the rapid volatilization of high mass fraction extractivesmore » during high pressure steaming and lead to the shrinkage of micropores of the PKS fibers. The maximum brealdng strength of steam exploded EFB and PKS were increased by 63% and 45%, respectively. The required compaction energy for the steam exploded EFB pellet is 44.50 J/g while that of the untreated EFB pellet is 30.15 J/g. Similar to Douglas fir, the required extrusion energy for the steam exploded EFB pellet was about 6 times than that of the untreated EFB pellet. The increased extrusion energy is mainly contributed by the increase in mono-saccharides by auto-hydrolysis during steam explosion pretreatment.« less

Steam explosion of oil palm residues for the production of durable pellets

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lam, Pak Sui; Lam, Pak Yiu; Sokhansanj, Shahab

Here we investigated the effect of steam explosion pretreatment on the physical and mechanical properties of the pellets made from empty fruit bunch (EFB) and palm kernel shell (PKS) and we compared to that of softwood Douglas fir (DF). We found that the high heating value of the empty fruit bunch was increased by 21% after steam explosion pretreatment. The pellet density of EFB and Douglas fir pellets did not change while the pellet density of PKS increased from 1.13 to 1.21 g/cm 3 after steam explosion. That may be attributed to the rapid volatilization of high mass fraction extractivesmore » during high pressure steaming and lead to the shrinkage of micropores of the PKS fibers. The maximum brealdng strength of steam exploded EFB and PKS were increased by 63% and 45%, respectively. The required compaction energy for the steam exploded EFB pellet is 44.50 J/g while that of the untreated EFB pellet is 30.15 J/g. Similar to Douglas fir, the required extrusion energy for the steam exploded EFB pellet was about 6 times than that of the untreated EFB pellet. The increased extrusion energy is mainly contributed by the increase in mono-saccharides by auto-hydrolysis during steam explosion pretreatment.« less

Emerging Energetic Materials: Synthesis, Physicochemical, and Detonation Properties

USDA-ARS?s Scientific Manuscript database

This book summarizes the science and technology of new generation high energy and insensitive explosives. The objective is to provide the professionals with comprehensive information on synthesis, physicochemical, and detonation properties of the explosives. Potential technologies applicable for tre...

Application of paper spray ionization for explosives analysis.

PubMed

Tsai, Chia-Wei; Tipple, Christopher A; Yost, Richard A

2017-10-15

A desired feature in the analysis of explosives is to decrease the time of the entire analysis procedure, including sampling. A recently utilized ambient ionization technique, paper spray ionization (PSI), provides the possibility of combining sampling and ionization. However, an interesting phenomenon that occurs in generating negatively charged ions pose some challenges in applying PSI to explosives analysis. The goal of this work is to investigate the possible solutions for generating explosives ions in negative mode PSI. The analysis of 2,4,6-trinitrotoluene (TNT), pentaerythritol tetranitrate (PETN), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), and 1,3,5-trinitroperhydro-1,3,5-triazine (RDX) was performed. Several solvent systems with different surface tensions and additives were compared to determine their effect on the ionization of explosives. The solvents tested include tert-butanol, isopropanol, methanol, and acetonitrile. The additives tested were carbon tetrachloride and ammonium nitrate. Of the solvents tested, isopropanol yielded the best results. In addition, adding ammonium nitrate to the isopropanol enhanced the analyte signal. Experimentally determined limits of detection (LODs) as low as 0.06 ng for PETN, on paper, were observed with isopropanol and the addition of 0.4 mM ammonium nitrate as the spray solution. In addition, the explosive components of two plastic explosive samples, Composition 4 and Semtex, were successfully analyzed via surface sampling when using the developed method. The analysis of explosives using PSI-MS in negative ion mode was achieved. The addition of ammonium nitrate to isopropanol, in general, enhanced the analyte signal and yielded better ionization stability. Real-world explosive samples were analyzed, which demonstrates one of the potential applications of PSI-MS analysis. Copyright © 2017 John Wiley & Sons, Ltd.

Gas expulsion vs gas retention in young stellar clusters II: effects of cooling and mass segregation

NASA Astrophysics Data System (ADS)

Silich, Sergiy; Tenorio-Tagle, Guillermo

2018-05-01

Gas expulsion or gas retention is a central issue in most of the models for multiple stellar populations and light element anti-correlations in globular clusters. The success of the residual matter expulsion or its retention within young stellar clusters has also a fundamental importance in order to understand how star formation proceeds in present-day and ancient star-forming galaxies and if proto-globular clusters with multiple stellar populations are formed in the present epoch. It is usually suggested that either the residual gas is rapidly ejected from star-forming clouds by stellar winds and supernova explosions, or that the enrichment of the residual gas and the formation of the second stellar generation occur so rapidly, that the negative stellar feedback is not significant. Here we continue our study of the early development of star clusters in the extreme environments and discuss the restrictions that strong radiative cooling and stellar mass segregation provide on the gas expulsion from dense star-forming clouds. A large range of physical initial conditions in star-forming clouds which include the star-forming cloud mass, compactness, gas metallicity, star formation efficiency and effects of massive stars segregation are discussed. It is shown that in sufficiently massive and compact clusters hot shocked winds around individual massive stars may cool before merging with their neighbors. This dramatically reduces the negative stellar feedback, prevents the development of the global star cluster wind and expulsion of the residual and the processed matter into the ambient interstellar medium. The critical lines which separate the gas expulsion and the gas retention regimes are obtained.

Explosives Detection: Exploitation of the Physical Signatures

NASA Astrophysics Data System (ADS)

Atkinson, David

2010-10-01

Explosives based terrorism is an ongoing threat that is evolving with respect to implementation, configuration and materials used. There are a variety of devices designed to detect explosive devices, however, each technology has limitations and operational constraints. A full understanding of the signatures available for detection coupled with the array of detection choices can be used to develop a conceptual model of an explosives screening operation. Physics based sensors provide a robust approach to explosives detection, typically through the identification of anomalies, and are currently used for screening in airports around the world. The next generation of detectors for explosives detection will need to be more sensitive and selective, as well as integrate seamlessly with devices focused on chemical signatures. An appreciation for the details of the physical signature exploitation in cluttered environments with time, space, and privacy constraints is necessary for effective explosives screening of people, luggage, cargo, and vehicles.

Generation of High-Frequency P and S Wave Energy by Rock Fracture During a Buried Explosion

DTIC Science & Technology

2015-07-20

symmetry is broken. Spherical symmetry is broken by the following: tectonic pre-stress, preferred orientation of pre-existing fractures (anisotropic rock...generated by laboratory explosions in plates of “candy glass”. Candy glass (or break-away glass) is used in the movie industry to simulate glass fracture in...9 4.1. Experimental Results – Candy-Glass Plates .......................................................9 4.2. Measurements of the Mechanical

Dissipative rogue waves induced by soliton explosions in an ultrafast fiber laser.

PubMed

Liu, Meng; Luo, Ai-Ping; Xu, Wen-Cheng; Luo, Zhi-Chao

2016-09-01

We reported on the observation of dissipative rogue waves (DRWs) induced by soliton explosions in an ultrafast fiber laser. It was found that the soliton explosions could be obtained in the fiber laser at a critical pump power level. During the process of the soliton explosion, the high-amplitude waves that fulfill the rogue wave criteria could be detected. The appearance of the DRWs was identified by characterizing the intensity statistics of the time-stretched soliton profile based on the dispersive Fourier-transform method. Our findings provide the first experimental demonstration that the DRWs could be observed in the soliton explosion regime and further enhance the understanding of the physical mechanism of optical RW generation.

Theoretical Studies of Nanocluster Formation

DTIC Science & Technology

2016-05-26

background, technical approach 2. Core-shell nanoclusters (Mg/Cu, Si/Al, etc.) - energetic additives for propellants , explosives - gas generators...shell nanocluster synthesis Core-shell nanoclusters such as SiAln, NinAlm, Aln(CuO)m, etc. may be useful ingredients in propellants and explosives

Evaluation of soluble fraction and enzymatic residual fraction of dilute dry acid, ethylenediamine, and steam explosion pretreated corn stover on the enzymatic hydrolysis of cellulose.

PubMed

Qin, Lei; Liu, Li; Li, Wen-Chao; Zhu, Jia-Qing; Li, Bing-Zhi; Yuan, Ying-Jin

2016-06-01

This study is aimed to examine the inhibition of soluble fraction (SF) and enzymatic residual fraction (ERF) in dry dilute acid (DDA), ethylenediamine (EDA) and steam explosion (SE) pretreated corn stover (CS) on the enzymatic digestibility of cellulose. SF of DDA, EDA and SE pretreated CS has high xylose, soluble lignin and xylo-oligomer content, respectively. SF of EDA pretreated CS leads to the highest inhibition, followed by SE and DDA pretreated CS. Inhibition of ERF of DDA and SE pretreated CS is higher than that of EDA pretreated CS. The inhibition degree (A0/A) of SF is 1.76 and 1.21 times to that of ERF for EDA and SE pretreated CS, respectively. The inhibition degree of ERF is 1.05 times to that of SF in DDA pretreated CS. The quantitative analysis shows that SF of EDA pretreated CS, SF and ERF of SE pretreated CS cause significant inhibition during enzymatic hydrolysis. Copyright © 2016 Elsevier Ltd. All rights reserved.

Shear Wave Generation and Modeling Ground Motion From a Source Physics Experiment (SPE) Underground Explosion

NASA Astrophysics Data System (ADS)

Pitarka, Arben; Mellors, Robert; Rodgers, Arthur; Vorobiev, Oleg; Ezzedine, Souheil; Matzel, Eric; Ford, Sean; Walter, Bill; Antoun, Tarabay; Wagoner, Jeffery; Pasyanos, Mike; Petersson, Anders; Sjogreen, Bjorn

2014-05-01

We investigate the excitation and propagation of far-field (epicentral distance larger than 20 m) seismic waves by analyzing and modeling ground motion from an underground chemical explosion recorded during the Source Physics Experiment (SPE), Nevada. The far-field recorded ground motion is characterized by complex features, such as large azimuthal variations in P- and S-wave amplitudes, as well as substantial energy on the tangential component of motion. Shear wave energy is also observed on the tangential component of the near-field motion (epicentral distance smaller than 20 m) suggesting that shear waves were generated at or very near the source. These features become more pronounced as the waves propagate away from the source. We address the shear wave generation during the explosion by modeling ground motion waveforms recorded in the frequency range 0.01-20 Hz, at distances of up to 1 km. We used a physics based approach that combines hydrodynamic modeling of the source with anelastic modeling of wave propagation in order to separate the contributions from the source and near-source wave scattering on shear motion generation. We found that wave propagation scattering caused by the near-source geological environment, including surface topography, contributes to enhancement of shear waves generated from the explosion source. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-06NA25946/ NST11-NCNS-TM-EXP-PD15.

Binding of RDX to Cell Wall Components of Pinus sylvestris and Picea glauca and Three-Year Mineralisation Study of Tissue-Associated RDX Residues.

PubMed

Schoenmuth, Bernd; Schenke, Detlef; Scharnhorst, Tanja; Combrinck, Sandra; McCrindle, Robert I; Mueller, Jakob O; Büttner, Carmen; Pestemer, Wilfried

2015-01-01

Contamination of soils with the explosive hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX, Research Department Explosive) as a result of military applications is a large-area problem globally. Since coniferous trees dominate the vegetation of large areas of military land in Central Europe, particularly in Germany, the long-term fate of (14)C-RDX in the conifers Scots pine and Dwarf Alberta spruce was studied. Acetic acid was the most effective solvent for the removal of extractable RDX residues from homogenates of RDX-laden tree material (85%, 80-90% and 64-80% for roots, wood and needles, respectively). On average, only a fifth of RDX-derived (14)C was bound in non-extractable residues (NER). Within the main cell wall compartments, lignin was the dominant binding site for NER (needles: 32-62%; roots: 38-42%). Hemicellulose (needles: 11-18%; roots: 6-11%) and cellulose (needles: 12-24%; roots: 1-2%) were less involved in binding and a considerable proportion of NER (needles: 15-24%; roots: 59-51%) was indigestible. After three-year incubation in rot chambers, mineralisation of tree-associated (14)C-RDX to (14)CO2 clearly dominated the mass balance in both tree species with 48-83%. 13-33% of (14)C-RDX-derived radioactivity remained in an unleachable form and the remobilisation by water leaching was negligible (< 2%).

Explosive decomposition of hydrazine by rapid compression of a gas volume

NASA Technical Reports Server (NTRS)

Bunker, R. L.; Baker, D. L.; Lee, J. H. S.

1991-01-01

In the present investigation of the initiation mechanism and the explosion mode of hydrazine decomposition, a 20 cm-long column of liquid hydrazine was accelerated into a column of gaseous nitrogen, from which it was separated by a thin Teflon diaphragm, in a close-ended cylindrical chamber. Video data obtained reveal the formation of a froth generated by the acceleration of hydrazine into nitrogen at the liquid hydrazine-gaseous nitrogen interface. The explosive hydrazine decomposition had as its initiation mechanism the formation of a froth at a critical temperature; the explosion mode of hydrazine is a confined thermal runaway reaction.

Lithium niobate explosion monitor

DOEpatents

Bundy, Charles H.; Graham, Robert A.; Kuehn, Stephen F.; Precit, Richard R.; Rogers, Michael S.

1990-01-01

Monitoring explosive devices is accomplished with a substantially z-cut lithium niobate crystal in abutment with the explosive device. Upon impact by a shock wave from detonation of the explosive device, the crystal emits a current pulse prior to destruction of the crystal. The current pulse is detected by a current viewing transformer and recorded as a function of time in nanoseconds. In order to self-check the crystal, the crystal has a chromium film resistor deposited thereon which may be heated by a current pulse prior to detonation. This generates a charge which is detected by a charge amplifier.

Lithium niobate explosion monitor

DOEpatents

Bundy, C.H.; Graham, R.A.; Kuehn, S.F.; Precit, R.R.; Rogers, M.S.

1990-01-09

Monitoring explosive devices is accomplished with a substantially z-cut lithium niobate crystal in abutment with the explosive device. Upon impact by a shock wave from detonation of the explosive device, the crystal emits a current pulse prior to destruction of the crystal. The current pulse is detected by a current viewing transformer and recorded as a function of time in nanoseconds. In order to self-check the crystal, the crystal has a chromium film resistor deposited thereon which may be heated by a current pulse prior to detonation. This generates a charge which is detected by a charge amplifier. 8 figs.

The Shock and Vibration Bulletin. Part 4. Impact, Packaging and Shipping, Blast and Impulsive Loading

DTIC Science & Technology

1975-06-01

Explosive forces are completely through undisturbed air where appreciable dominant and the plate is rotated through an aerodynamic forces retard its...are relatively of the explosive system drops rapidly with dense compared to air , do produce sufficient flyer thickness, little is gained by increasing...impulsive loadings generated by a fuel air explosive . A membrane model based on a total plastic strain energy function, a rigid strain hardening

Next-Generation MDAC Discrimination Procedure Using Multi-Dimensional Spectral Analyses

DTIC Science & Technology

2007-09-01

explosions near the Lop Nor, Novaya Zemlya, Semipalatinsk , Nevada, and Indian test sites . We have computed regional phase spectra and are correcting... test sites as mainly due to differences in explosion P and S corner frequencies. Fisk (2007) used source model fits to estimate Pn, Pg, and Lg corner...frequencies for Nevada Test Site (NTS) explosions and found that Lg corner frequencies exhibit similar scaling with source size as for Pn and Pg

Evaluating Macro and Microscopic Rock Damage from Explosions and the Effects on Shear Wave Generation

DTIC Science & Technology

2014-06-30

using the NEDE2 data to generate this model, we used data collected during NEDE1 to study Rg propagation in Barre Granite and nearby metamorphic rocks ...explosion using the soft rock coupling curve shown in Figure 10-3. ................................................................... 196 Figure 10-5...experiment under contract AFRL-FA9453-10-C-0257. Special thanks goes to Don Murray and Rock of Ages Corp. for allowing us to return and impose on their

Microbial bioreporters of trace explosives.

PubMed

Shemer, Benjamin; Koshet, Ori; Yagur-Kroll, Sharon; Belkin, Shimshon

2017-06-01

Since its introduction as an explosive in the late 19th century, 2,4,6-trinitrotoluene (TNT), along with other explosive compounds, has left numerous environmental marks. One of these is widespread soil and water pollution by trace explosives in military proving grounds, manufacturing facilities, or actual battlefields. Another dramatic impact is that exerted by the millions of landmines and other explosive devices buried in large parts of the world, causing extensive loss of life, injuries, and economical damage. In this review we highlight recent advances in the design and construction of microbial bioreporters, molecularly engineered to generate a quantifiable dose-dependent signal in the presence of trace amounts of explosives. Such sensor strains may be employed for monitoring environmental pollution as well as for the remote detection of buried landmines. Copyright © 2017 Elsevier Ltd. All rights reserved.

Rg-Lg coupling as a Lg-wave excitation mechanism

NASA Astrophysics Data System (ADS)

Ge, Z.; Xie, X.

2003-12-01

Regional phase Lg is predominantly comprised of shear wave energy trapped in the crust. Explosion sources are expected to be less efficient for excitation of Lg phases than earthquakes to the extent that the source can be approximated as isotropic. Shallow explosions generate relatively large surface wave Rg compared to deeper earthquakes, and Rg is readily disrupted by crustal heterogeneity. Rg energy may thus scatter into trapped crustal S-waves near the source region and contribute to low-frequency Lg wave. In this study, a finite-difference modeling plus the slowness analysis are used for investigating the above mentioned Lg-wave excitation mechanism. The method allows us to investigate near source energy partitioning in multiple domains including frequency, slowness and time. The main advantage of this method is that it can be applied at close range, before Lg is actually formed, which allows us to use very fine near source velocity model to simulate the energy partitioning process. We use a layered velocity structure as the background model and add small near source random velocity patches to the model to generate the Rg to Lg coupling. Two types of simulations are conducted, (1) a fixed shallow explosion source vs. randomness at different depths and (2) a fixed shallow randomness vs. explosion sources at different depths. The results show apparent couplings between the Rg and Lg waves at lower frequencies (0.3-1.5 Hz). A shallow source combined with shallow randomness generates the maximum Lg-wave, which is consistent with the Rg energy distribution of a shallow explosion source. The Rg energy and excited Lg energy show a near linear relationship. The numerical simulation and slowness analysis suggest that the Rg to Lg coupling is an effective excitation mechanism for low frequency Lg-waves from a shallow explosion source.

The hard start phenomena in hypergolic engines. Volume 3: Physical and combustion characteristics of engine residuals

NASA Technical Reports Server (NTRS)

Miron, Y.; Perlee, H. E.

1974-01-01

An investigation was conducted to determine the cause of starting problems in the hypergolic rocket engines of the Apollo reaction control (RCS) engines. The scope of the investigation was as follows: (1) to establish that chemical reactions occurred during the preignition and post combustion periods, (2) to identify the chemical species of the products of preignition and post combustion reaction, and (3) to determine the explosive nature of the identified species. The methods used in identifying the chemical products are described species. The infrared spectra, X-ray spectra, and other signatures of the compounds are presented. The physical and explosion characteristics of various hypergolic agents are reported.

Detection of Gunshot Residues Using Mass Spectrometry

PubMed Central

Blanes, Lucas; Cole, Nerida; Doble, Philip; Roux, Claude

2014-01-01

In recent years, forensic scientists have become increasingly interested in the detection and interpretation of organic gunshot residues (OGSR) due to the increasing use of lead- and heavy metal-free ammunition. This has also been prompted by the identification of gunshot residue- (GSR-) like particles in environmental and occupational samples. Various techniques have been investigated for their ability to detect OGSR. Mass spectrometry (MS) coupled to a chromatographic system is a powerful tool due to its high selectivity and sensitivity. Further, modern MS instruments can detect and identify a number of explosives and additives which may require different ionization techniques. Finally, MS has been applied to the analysis of both OGSR and inorganic gunshot residue (IGSR), although the “gold standard” for analysis is scanning electron microscopy with energy dispersive X-ray microscopy (SEM-EDX). This review presents an overview of the technical attributes of currently available MS and ionization techniques and their reported applications to GSR analysis. PMID:24977168

A Design of Finite Memory Residual Generation Filter for Sensor Fault Detection

NASA Astrophysics Data System (ADS)

Kim, Pyung Soo

2017-04-01

In the current paper, a residual generation filter with finite memory structure is proposed for sensor fault detection. The proposed finite memory residual generation filter provides the residual by real-time filtering of fault vector using only the most recent finite measurements and inputs on the window. It is shown that the residual given by the proposed residual generation filter provides the exact fault for noisefree systems. The proposed residual generation filter is specified to the digital filter structure for the amenability to hardware implementation. Finally, to illustrate the capability of the proposed residual generation filter, extensive simulations are performed for the discretized DC motor system with two types of sensor faults, incipient soft bias-type fault and abrupt bias-type fault. In particular, according to diverse noise levels and windows lengths, meaningful simulation results are given for the abrupt bias-type fault.

Development of a flyer design to perform plate impact shock-release-shock experiments on explosives

NASA Astrophysics Data System (ADS)

Finnegan, Simon; Ferguson, James; Millett, Jeremy; Goff, Michael

2017-06-01

A flyer design to generate a shock-release-shock loading history within a gas gun target was developed before being used to study the response of an HMX based explosive. The flyer consisted of two flyer plates separated by a vacuum gap. This created a rear free surface that, with correct material choice, allowed the target to release to close to ambient pressure between the initial shock and subsequent re-shock. The design was validated by impacting piezoelectric pin arrays to record the front flyer deformation. Shots were performed on PCTFE targets to record the shock states generated in an inert material prior to subjecting an HMX based explosive to the same loading. The response of the explosive to this loading history was recorded using magnetic particle velocity (PV) gauges embedded within the targets. The behavior during the run to detonation is compared with the response to sustained shocks at similar input pressures.

Fuze for explosive magnetohydrodynamic generator

DOE Office of Scientific and Technical Information (OSTI.GOV)

Webb, G.

1976-12-23

An apparatus is examined by which high explosive charges are propelled into and detonated at the center of an MHD-X generator. The high explosive charge units are engaged and propelled by a reciprocating ram device. Detonating in each instance is achieved by striking with a firing pin a detonator charge that is in register with a booster charge, the booster charge being in detonating communication with the high explosive charge. Various safety requirements are satisfied by a spring loaded slider operating in a channel transverse and adjacent to the booster charge. The slide retains the detonator charge out of registermore » with the booster charge until a safety pin that holds the slider in place is pulled by a lanyard attached between the reciprocating ram and the safety pin. Removal of the safety pin permits the detonator charge to slide into alignment with the booster charge. Firing pin actuation is initiated by the slider at the instant the detonator charge and the booster charge come into register.« less

Modelling and Testing of Blast Effect On the Structures

NASA Astrophysics Data System (ADS)

Figuli, Lucia; Jangl, Štefan; Papán, Daniel

2016-10-01

As a blasting agent in the blasting and mining engineering, has been using one of so called new generation of explosives which offer greater flexibility in their range and application, and such explosive is ANFO. It is type of explosive consists of an oxidiser and a fuel (ammonium nitrate and fuel oil). One of such ANFO explosives which are industrially made in Slovakia is POLONIT. The explosive is a mixture of ammonium nitrate, methyl esters of higher fatty acids, vegetable oil and red dye. The paper deals with the analysis of structure subjected to the blast load created by the explosion of POLONIT charge. First part of paper is describing behaviour and characteristic of blast wave generated from the blast (detonation characteristics, physical characteristics, time-history diagram etc.) and the second part presents the behaviour of such loaded structures, because of the analysis of such dynamical loaded structure is required knowing the parameters of blast wave, its effect on structure and the tools for the solution of dynamic analysis. The real field tests of three different weight of charges and two different structures were done. The explosive POLONIT was used together with 25 g of ignition explosive PLNp10. Analytical and numerical model of blast loaded structure is compared with the results obtained from the field tests (is compared with the corresponding experimental accelerations). For the modelling structures were approximated as a one-degree system of freedom (SDOF), where the blast wave was estimated with linear decay and exponential decay using positive and negative phase of blast wave. Numerical solution of the steel beam dynamic response was performed via FEM (Finite Element Method) using standard software Visual FEA.

Local infrasound observations of large ash explosions at Augustine Volcano, Alaska, during January 11–28, 2006

USGS Publications Warehouse

Petersen, Tanja; De Angelis, Silvio; Tytgat, Guy; McNutt, Stephen R.

2006-01-01

We present and interpret acoustic waveforms associated with a sequence of large explosion events that occurred during the initial stages of the 2006 eruption of Augustine Volcano, Alaska. During January 11–28, 2006, 13 large explosion events created ash-rich plumes that reached up to 14 km a.s.l., and generated atmospheric pressure waves that were recorded on scale by a microphone located at a distance of 3.2 km from the active vent. The variety of recorded waveforms included sharp N-shaped waves with durations of a few seconds, impulsive signals followed by complex codas, and extended signals with emergent character and durations up to minutes. Peak amplitudes varied between 14 and 105 Pa; inferred acoustic energies ranged between 2×108 and 4×109 J. A simple N-shaped short-duration signal recorded on January 11, 2006 was associated with the vent-opening blast that marked the beginning of the explosive eruption sequence. During the following days, waveforms with impulsive onsets and extended codas accompanied the eruptive activity, which was characterized by explosion events that generated large ash clouds and pyroclastic flows along the flanks of the volcano. Continuous acoustic waveforms that lacked a clear onset were more common during this period. On January 28, 2006, the occurrence of four large explosion events marked the end of this explosive eruption phase at Augustine Volcano. After a transitional period of about two days, characterized by many small discrete bursts, the eruption changed into a stage of more sustained and less explosive activity accompanied by the renewed growth of a summit lava dome.

Method and apparatus for optimized sampling of volatilizable target substances

DOEpatents

Lindgren, Eric R.; Phelan, James M.

2004-10-12

An apparatus for capturing, from gases such as soil gas, target analytes. Target analytes may include emanations from explosive materials or from residues of explosive materials. The apparatus employs principles of sorption common to solid phase microextraction, and is best used in conjunction with analysis means such as a gas chromatograph. To sorb target analytes, the apparatus functions using various sorptive structures to capture target analyte. Depending upon the embodiment, those structures may include a capillary tube including an interior surface on which sorptive material (similar to that on the surface of a SPME fiber) is supported (along with means for moving gases through the capillary tube so that the gases come into close proximity to the sorptive material). In one disclosed embodiment, at least one such sorptive structure is associated with an enclosure including an opening in communication with the surface of a soil region potentially contaminated with buried explosive material such as unexploded ordnance. Emanations from explosive materials can pass into and accumulate in the enclosure where they are sorbed by the sorptive structures. Also disclosed is the use of heating means such as microwave horns to drive target analytes into the soil gas from solid and liquid phase components of the soil.

Influence of Molecular Structure on the Laser-Induced Plasma Emission of the Explosive RDX and Organic Polymers

NASA Astrophysics Data System (ADS)

De Lucia, Frank C.; Gottfried, Jennifer L.

2013-10-01

A series of organic polymers and the military explosive cyclotrimethylenetrinitramine (RDX) were studied using the light emission from a femtosecond laser-induced plasma under an argon atmosphere. The relationship between the molecular structure and plasma emission was established by using the percentages of the atomic species (C, H, N, O) and bond types (C-C, C═C, C-N, and C≡N) in combination with the atomic/molecular emission intensities and decay rates. In contrast to previous studies of organic explosives in which C2 was primarily formed by recombination, for the organic materials in this study the percentage of C-C (and C═C) bonds was strongly correlated to the molecular C2 emission. Time-resolved emission spectra were collected to determine the lifetimes of the atomic and molecular species in the plasma. Observed differences in decay rates were attributed to the differences in both the molecular structure of the organic polymers or RDX and the chemical reactions that occur within the plasma. These differences could potentially be exploited to improve the discrimination of explosive residues on organic substrates with laser-induced breakdown spectroscopy.

Detection of explosives on the surface of banknotes by Raman hyperspectral imaging and independent component analysis.

PubMed

Almeida, Mariana R; Correa, Deleon N; Zacca, Jorge J; Logrado, Lucio Paulo Lima; Poppi, Ronei J

2015-02-20

The aim of this study was to develop a methodology using Raman hyperspectral imaging and chemometric methods for identification of pre- and post-blast explosive residues on banknote surfaces. The explosives studied were of military, commercial and propellant uses. After the acquisition of the hyperspectral imaging, independent component analysis (ICA) was applied to extract the pure spectra and the distribution of the corresponding image constituents. The performance of the methodology was evaluated by the explained variance and the lack of fit of the models, by comparing the ICA recovered spectra with the reference spectra using correlation coefficients and by the presence of rotational ambiguity in the ICA solutions. The methodology was applied to forensic samples to solve an automated teller machine explosion case. Independent component analysis proved to be a suitable method of resolving curves, achieving equivalent performance with the multivariate curve resolution with alternating least squares (MCR-ALS) method. At low concentrations, MCR-ALS presents some limitations, as it did not provide the correct solution. The detection limit of the methodology presented in this study was 50 μg cm(-2). Copyright © 2014 Elsevier B.V. All rights reserved.

Common Low-cost IM Explosive Program. Development of Next Generation Insensitive Munitions: A Success Story

DTIC Science & Technology

2011-11-30

fuze separating from the shell body preventing high order detonations thus saving the lives of the Soldiers. Unit’s SPC Alan Ng  with his father Peter...Sensitive If not fully compliant, must show improvement over Baseline explosive Affordable Artillery Cost Drivers = Steel Body Material & Explosive Fill...Mortar Cost Drivers = Steel Body Material, Fuze & Propelling Charges Producible within the National Technology and Industrial Base Infrastructure

Analysis of Water Shock Data and Bubble Screen Effectiveness on the Blast Effect Mitigation Test Series, Wilmington Harbor, North Carolina

DTIC Science & Technology

2000-08-01

ERDC/SL ; TR-00-4) Includes bibliographic references. 1. Underwater explosions - Testing. 2. Shock waves. 3. Air curtains. 4. Wilmington, (N.C...water is the placement of air curtains or bubble screens around the underwater explosive source. Bubble screens are generated by pumping air into a...Geomechanics and Explosion Effects Division (GEED), Structures Laboratory (SL), Waterways Experiment Station (WES), U. S. Army Engineer Research and

Identity and distribution of residues of energetic compounds at army live-fire training ranges.

PubMed

Jenkins, Thomas F; Hewitt, Alan D; Grant, Clarence L; Thiboutot, Sonia; Ampleman, Guy; Walsh, Marianne E; Ranney, Thomas A; Ramsey, Charles A; Palazzo, Antonio J; Pennington, Judith C

2006-05-01

Environmental investigations have been conducted at 23 military firing ranges in the United States and Canada. The specific training facilities most frequently evaluated were hand grenade, antitank rocket, and artillery ranges. Energetic compounds (explosives and propellants) were determined and linked to the type of munition used and the major mechanisms of deposition.

Evaluation of various organic fertilizer substrates and hydraulic retention times for enhancing anaerobic degradation of explosives-contaminated groundwater while using constructed wetlands at the Milan Army Ammunition Plant, Milan, Tennessee. Final report

DOE Office of Scientific and Technical Information (OSTI.GOV)

Behrends, L.L.; Almond, R.A.; Kelly, D.A.

1998-05-01

This document describes studies conducted at the Milan Army Ammunition Plant (MAAP) to improve the design, operation, and cost of gravel-based anaerobic cells when phytoremediating explosives-contaminated groundwater. To conduct this study, small-scale anaerobic test cells were used to determine: (1) If the hydraulic retention time of a large demonstration-scale anaerobic cell at MAAP could be reduced, and (2) if other carbon sources could be used as an anaerobic feedstock. The study results indicated that: (1) The existing anaerobic cell`s 7.5-day retention time should not be reduced since residual explosive by-products were present in the effluent of treatments with a 3.5-daymore » retention time. (2) Daily application of a relatively soluble substrate, such as molasses syrup, will provide better explosives removal than periodic application of less soluble substrates like milk replacement starter and sewage sludge. (3) Molasses syrup could be, and should be, used as a substitute for milk replacement power. The recommendation to use molasses syrup was based on: (1) The lower cost of molasses syrup as compared to milk replacement starter, (2) molasses syrup`s higher solubility (which makes it easier to apply), and (3) molasses syrup`s ability to provide enhanced explosives removal.« less

30 CFR 56.6602 - Static electricity dissipation during loading.

Code of Federal Regulations, 2012 CFR

2012-07-01

... 30 Mineral Resources 1 2012-07-01 2012-07-01 false Static electricity dissipation during loading... Explosives Extraneous Electricity § 56.6602 Static electricity dissipation during loading. When explosive material is loaded pneumatically into a blasthole in a manner that generates a static electricity hazard...

30 CFR 56.6602 - Static electricity dissipation during loading.

Code of Federal Regulations, 2013 CFR

2013-07-01

... 30 Mineral Resources 1 2013-07-01 2013-07-01 false Static electricity dissipation during loading... Explosives Extraneous Electricity § 56.6602 Static electricity dissipation during loading. When explosive material is loaded pneumatically into a blasthole in a manner that generates a static electricity hazard...

30 CFR 56.6602 - Static electricity dissipation during loading.

Code of Federal Regulations, 2014 CFR

2014-07-01

... 30 Mineral Resources 1 2014-07-01 2014-07-01 false Static electricity dissipation during loading... Explosives Extraneous Electricity § 56.6602 Static electricity dissipation during loading. When explosive material is loaded pneumatically into a blasthole in a manner that generates a static electricity hazard...

30 CFR 56.6602 - Static electricity dissipation during loading.

Code of Federal Regulations, 2011 CFR

2011-07-01

... 30 Mineral Resources 1 2011-07-01 2011-07-01 false Static electricity dissipation during loading... Explosives Extraneous Electricity § 56.6602 Static electricity dissipation during loading. When explosive material is loaded pneumatically into a blasthole in a manner that generates a static electricity hazard...

30 CFR 56.6602 - Static electricity dissipation during loading.

Code of Federal Regulations, 2010 CFR

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Static electricity dissipation during loading... Explosives Extraneous Electricity § 56.6602 Static electricity dissipation during loading. When explosive material is loaded pneumatically into a blasthole in a manner that generates a static electricity hazard...

Explosive death of conjugate coupled Van der Pol oscillators on networks

NASA Astrophysics Data System (ADS)

Zhao, Nannan; Sun, Zhongkui; Yang, Xiaoli; Xu, Wei

2018-06-01

Explosive death phenomenon has been gradually gaining attention of researchers due to the research boom of explosive synchronization, and it has been observed recently for the identical or nonidentical coupled systems in all-to-all network. In this work, we investigate the emergence of explosive death in networked Van der Pol (VdP) oscillators with conjugate variables coupling. It is demonstrated that the network structures play a crucial role in identifying the types of explosive death behaviors. We also observe that the damping coefficient of the VdP system not only can determine whether the explosive death state is generated but also can adjust the forward transition point. We further show that the backward transition point is independent of the network topologies and the damping coefficient, which is well confirmed by theoretical analysis. Our results reveal the generality of explosive death phenomenon in different network topologies and are propitious to promote a better comprehension for the oscillation quenching behaviors.

Trace explosives sensor testbed (TESTbed)

NASA Astrophysics Data System (ADS)

Collins, Greg E.; Malito, Michael P.; Tamanaha, Cy R.; Hammond, Mark H.; Giordano, Braden C.; Lubrano, Adam L.; Field, Christopher R.; Rogers, Duane A.; Jeffries, Russell A.; Colton, Richard J.; Rose-Pehrsson, Susan L.

2017-03-01

A novel vapor delivery testbed, referred to as the Trace Explosives Sensor Testbed, or TESTbed, is demonstrated that is amenable to both high- and low-volatility explosives vapors including nitromethane, nitroglycerine, ethylene glycol dinitrate, triacetone triperoxide, 2,4,6-trinitrotoluene, pentaerythritol tetranitrate, and hexahydro-1,3,5-trinitro-1,3,5-triazine. The TESTbed incorporates a six-port dual-line manifold system allowing for rapid actuation between a dedicated clean air source and a trace explosives vapor source. Explosives and explosives-related vapors can be sourced through a number of means including gas cylinders, permeation tube ovens, dynamic headspace chambers, and a Pneumatically Modulated Liquid Delivery System coupled to a perfluoroalkoxy total-consumption microflow nebulizer. Key features of the TESTbed include continuous and pulseless control of trace vapor concentrations with wide dynamic range of concentration generation, six sampling ports with reproducible vapor profile outputs, limited low-volatility explosives adsorption to the manifold surface, temperature and humidity control of the vapor stream, and a graphical user interface for system operation and testing protocol implementation.

Method for attenuating seismic shock from detonating explosive in an in situ oil shale retort

DOEpatents

Studebaker, Irving G.; Hefelfinger, Richard

1980-01-01

In situ oil shale retorts are formed in formation containing oil shale by excavating at least one void in each retort site. Explosive is placed in a remaining portion of unfragmented formation within each retort site adjacent such a void, and such explosive is detonated in a single round for explosively expanding formation within the retort site toward such a void for forming a fragmented permeable mass of formation particles containing oil shale in each retort. This produces a large explosion which generates seismic shock waves traveling outwardly from the blast site through the underground formation. Sensitive equipment which could be damaged by seismic shock traveling to it straight through unfragmented formation is shielded from such an explosion by placing such equipment in the shadow of a fragmented mass in an in situ retort formed prior to the explosion. The fragmented mass attenuates the velocity and magnitude of seismic shock waves traveling toward such sensitive equipment prior to the shock wave reaching the vicinity of such equipment.

Liquid explosions induced by X-ray laser pulses

DOE PAGES

Stan, Claudiu A.; Milathianaki, Despina; Laksmono, Hartawan; ...

2016-05-23

Explosions are spectacular and intriguing phenomena that expose the dynamics of matter under extreme conditions. We investigated, using time-resolved imaging, explosions induced by ultraintense X-ray laser pulses in water drops and jets. Our observations revealed an explosive vaporization followed by high-velocity interacting flows of liquid and vapour, and by the generation of shock trains in the liquid jets. These flows are different from those previously observed in laser ablation, owing to a simpler spatial pattern of X-ray absorption. We show that the explosion dynamics in our experiments is consistent with a redistribution of absorbed energy, mediated by a pressure ormore » shock wave in the liquid, and we model the effects of explosions, including their adverse impact on X-ray laser experiments. As a result, X-ray laser explosions have predictable dynamics that may prove useful for controlling the state of pure liquids over broad energy scales and timescales, and for triggering pressure-sensitive molecular dynamics in solutions.« less

STUDY OF THERMAL SENSITIVITY AND THERMAL EXPLOSION VIOLENCE OF ENERGETIC MATERIALS IN THE LLNL ODTX SYSTEM

DOE Office of Scientific and Technical Information (OSTI.GOV)

HSU, P C; Hust, G; May, C

Some energetic materials may explode at fairly low temperatures and the violence from thermal explosion may cause a significant damage. Thus it is important to understand the response of energetic materials to thermal insults for safe handling and storage of energetic materials. The One Dimensional Time to Explosion (ODTX) system at the Lawrence Livermore National Laboratory can measure times to explosion, lowest explosion temperatures, and determine kinetic parameters of energetic materials. Samples of different configurations can be tested in the system. The ODTX testing can also generate useful data for determining thermal explosion violence of energetic materials. We also performedmore » detonation experiments of LX-10 in aluminum anvils to determine the detonation violence and validated the Zerilli Armstrong aluminum model. Results of the detonation experiments agreed well with the model prediction.« less

Controlled Detonation Dynamics in Additively Manufactured High Explosives

NASA Astrophysics Data System (ADS)

Schmalzer, Andrew; Tappan, Bryce; Bowden, Patrick; Manner, Virginia; Clements, Brad; Menikoff, Ralph; Ionita, Axinte; Branch, Brittany; Dattelbaum, Dana; Espy, Michelle; Patterson, Brian; Wu, Ruilian; Mueller, Alexander

2017-06-01

The effect of structure in explosives has long been a subject of interest to explosives engineers and scientists. Through structure, detonation dynamics in explosives can be manipulated, introducing a new level of safety and directed performance into these previously difficult to control materials. New advances in additive manufacturing (AM) allow the deliberate introduction of exact internal structures at dimensions approaching the mesoscale of these energetic materials. We show through simulation and experiment that this structure can be used to control detonation behavior by manipulating complex shockwave interactions. We use high-speed video and shorting mag-wires to determine the detonation velocity in AM generated explosive structures, demonstrating, for the first time, a method of controlling the directional propagation of reactive flow through the controlled introduction of structure within a high explosive. With ongoing improvement in the AM methods available coupled with guidance through modeling and simulations, more complex interactions are being explored. LANL LDRD Office.

Visualization of explosion phenomena using a high-speed video camera with an uncoupled objective lens by fiber-optic

NASA Astrophysics Data System (ADS)

Tokuoka, Nobuyuki; Miyoshi, Hitoshi; Kusano, Hideaki; Hata, Hidehiro; Hiroe, Tetsuyuki; Fujiwara, Kazuhito; Yasushi, Kondo

2008-11-01

Visualization of explosion phenomena is very important and essential to evaluate the performance of explosive effects. The phenomena, however, generate blast waves and fragments from cases. We must protect our visualizing equipment from any form of impact. In the tests described here, the front lens was separated from the camera head by means of a fiber-optic cable in order to be able to use the camera, a Shimadzu Hypervision HPV-1, for tests in severe blast environment, including the filming of explosions. It was possible to obtain clear images of the explosion that were not inferior to the images taken by the camera with the lens directly coupled to the camera head. It could be confirmed that this system is very useful for the visualization of dangerous events, e.g., at an explosion site, and for visualizations at angles that would be unachievable under normal circumstances.

HNS/Teflon, a new heat resistant explosive

NASA Technical Reports Server (NTRS)

Heller, H.; Bertram, A. L.

1973-01-01

HNS/Teflon (90/10) is a new pressed explosive developed for use in the Apollo program. The major advantages of HNS/Teflon are (1) excellent thermal stability at elevated temperatures, (2) superior resistance to sublimation at high temperatures and low pressures and (3) ease of molding powder preparation, pressing and machining. The impact sensitivity of HNS/Teflon is between that of Comp B and Comp A-3 while its explosive performance is about the same as TNT. Under the severe environmental conditions of the moon's surface, this explosive successfully performed its intended function of generating seismic waves in the Apollo ALSEP and LSPE experiments. (Modified author abstract)

Imaging standoff trace detection of explosives using IR-laser based backscattering

NASA Astrophysics Data System (ADS)

Fuchs, F.; Hugger, S.; Jarvis, J.; Yang, Q. K.; Ostendorf, R.; Schilling, Ch.; Bronner, W.; Driad, R.; Aidam, R.; Wagner, J.

2016-05-01

We perform active hyperspectral imaging using tunable mid-infrared (MIR) quantum cascade lasers for contactless identification of solid and liquid contaminations on surfaces. By collecting the backscattered laser radiation with a camera, a hyperspectral data cube, containing the spatially resolved spectral information of the scene is obtained. Data is analyzed using appropriate algorithms to find the target substances even on substrates with a priori unknown spectra. Eye-save standoff detection of residues of explosives and precursors over extended distances is demonstrated and the main purpose of our system. Using a MIR EC-QCL with a tuning range from 7.5 μm to 10 μm, detection of a large variety of explosives, e.g. TNT, PETN and RDX and precursor materials such as Ammonium Nitrate could be demonstrated. In a real world scenario stand-off detection over distances of up to 20 m could be successfully performed. This includes measurements in a post blast scenario demonstrating the potential of the technique for forensic investigations.

Predicting chemical bioavailability using microarray gene expression data and regression modeling: A tale of three explosive compounds.

PubMed

Gong, Ping; Nan, Xiaofei; Barker, Natalie D; Boyd, Robert E; Chen, Yixin; Wilkins, Dawn E; Johnson, David R; Suedel, Burton C; Perkins, Edward J

2016-03-08

Chemical bioavailability is an important dose metric in environmental risk assessment. Although many approaches have been used to evaluate bioavailability, not a single approach is free from limitations. Previously, we developed a new genomics-based approach that integrated microarray technology and regression modeling for predicting bioavailability (tissue residue) of explosives compounds in exposed earthworms. In the present study, we further compared 18 different regression models and performed variable selection simultaneously with parameter estimation. This refined approach was applied to both previously collected and newly acquired earthworm microarray gene expression datasets for three explosive compounds. Our results demonstrate that a prediction accuracy of R(2) = 0.71-0.82 was achievable at a relatively low model complexity with as few as 3-10 predictor genes per model. These results are much more encouraging than our previous ones. This study has demonstrated that our approach is promising for bioavailability measurement, which warrants further studies of mixed contamination scenarios in field settings.

Field detection capability of immunochemical assays during criminal investigations involving the use of TNT.

PubMed

Romolo, Francesco Saverio; Ferri, Elida; Mirasoli, Mara; D'Elia, Marcello; Ripani, Luigi; Peluso, Giuseppe; Risoluti, Roberta; Maiolini, Elisabetta; Girotti, Stefano

2015-01-01

The capability to collect timely information about the substances employed on-site at a crime scene is of fundamental importance during scientific investigations in crimes involving the use of explosives. TNT (2,4,6-trinitrotoluene) is one of the most employed explosives in the 20th century. Despite the growing use of improvised explosives, criminal use and access to TNT is not expected to decrease. Immunoassays are simple and selective analytical tests able to detect molecules and their immunoreactions can occur in portable formats for use on-site. This work demonstrates the application of three immunochemical assays capable of detecting TNT to typical forensic samples from experimental tests: an indirect competitive ELISA with chemiluminescent detection (CL-ELISA), a colorimetric lateral flow immunoassay (LFIA) based on colloidal gold nanoparticles label, and a chemiluminescent-LFIA (CL-LFIA). Under optimised working conditions, the LOD of the colorimetric LFIA and CL-LFIA were 1 μg mL(-1) and 0.05 μg mL(-1), respectively. The total analysis time for LFIAs was 15 min. ELISA proved to be a very effective laboratory approach, showing very good sensitivity (LOD of 0.4 ng mL(-1)) and good reproducibility (CV value about 7%). Samples tested included various materials involved in controlled explosions of improvised explosive devices (IEDs), as well as hand swabs collected after TNT handling tests. In the first group of tests, targets covered with six different materials (metal, plastic, cardboard, carpet fabric, wood and adhesive tape) were fixed on top of wooden poles (180 cm high). Samples of soil from the explosion area and different materials covering the targets were collected after each explosion and analysed. In the second group of tests, hand swabs were collected with and without hand washing after volunteers simulated the manipulation of small charges of TNT. The small amount of solution required for each assay allows for several analyses. Results of immunoassays confirmed that they were suitable to detect post-blast residues in soil and target materials and post transfer residues on hands, allowing further confirmation by more selective techniques. ELISA and LFIAs results obtained from the same solution were consistently in good agreement, and were confirmed by gas chromatography coupled to mass spectrometry (GC-MS). The reported immunoassays data demonstrates the suitability of LFIAs as on-site rapid and effective assays to detect TNT traces. The CL-ELISA proved useful in obtaining very sensitive detection in forensic investigations and testing, while CL-LFIA had performances in between LFIA and CL-ELISA. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

Phase velocity enhancement of linear explosive shock tubes

NASA Astrophysics Data System (ADS)

Loiseau, Jason; Serge, Matthew; Szirti, Daniel; Higgins, Andrew; Tanguay, Vincent

2011-06-01

Strong, high density shocks can be generated by sequentially detonating a hollow cylinder of explosives surrounding a thin-walled, pressurized tube. Implosion of the tube results in a pinch that travels at the detonation velocity of the explosive and acts like a piston to drive a shock into the gas ahead of it. In order to increase the maximum shock velocities that can be obtained, a phase velocity generator can be used to drag an oblique detonation wave along the gas tube at a velocity much higher than the base detonation velocity of the explosive. Since yielding and failure of the gas tube is the primary limitation of these devices, it is desirable to retain the dynamic confinement effects of a heavy-walled tamper without interfering with operation of the phase velocity generator. This was accomplished by cutting a slit into the tamper and introducing a phased detonation wave such that it asymmetrically wraps around the gas tube. This type of configuration has been previously experimentally verified to produce very strong shocks but the post-shock pressure and shock velocity limits have not been investigated. This study measured the shock trajectory for various fill pressures and phase velocities to ascertain the limiting effects of tube yield, detonation obliquity and pinch aspect ratio.

Helical Explosive Flux Compression Generator Research at the Air Force Research Laboratory

DTIC Science & Technology

1999-06-01

Air Force Research Laboratory Kirtland AFB...ORGANIZATION NAME(S) AND ADDRESS(ES) Directed Energy Directorate, Air Force Research Laboratory Kirtland AFB, NM 8. PERFORMING ORGANIZATION REPORT...in support of the Air Force Research Laboratory ( AFRL ) explosive pulsed power program. These include circuit codes such as Microcap and

Miniature plasma accelerating detonator and method of detonating insensitive materials

DOEpatents

Bickes, R.W. Jr.; Kopczewski, M.R.; Schwarz, A.C.

1985-01-04

The invention is a detonator for use with high explosives. The detonator comprises a pair of parallel rail electrodes connected to a power supply. By shorting the electrodes at one end, a plasma is generated and accelerated toward the other end to impact against explosives. A projectile can be arranged between the rails to be accelerated by the plasma. An alternative arrangement is to a coaxial electrode construction. The invention also relates to a method of detonating explosives. 3 figs.

Miniature plasma accelerating detonator and method of detonating insensitive materials

DOEpatents

Bickes, Jr., Robert W.; Kopczewski, Michael R.; Schwarz, Alfred C.

1986-01-01

The invention is a detonator for use with high explosives. The detonator comprises a pair of parallel rail electrodes connected to a power supply. By shorting the electrodes at one end, a plasma is generated and accelerated toward the other end to impact against explosives. A projectile can be arranged between the rails to be accelerated by the plasma. An alternative arrangement is to a coaxial electrode construction. The invention also relates to a method of detonating explosives.

Analysis and Simulation of Near-Field Wave Motion Data from the Source Physics Experiment Explosions

DTIC Science & Technology

2011-09-01

understanding and ability to model explosively generated seismic waves, particularly S-waves. The first SPE explosion (SPE1) consisted of a 100 kg shot at a...depth of 60 meters in granite (Climax Stock). The shot was well- recorded by an array of over 150 instruments, including both near-field wave motion...measurements as well as far- field seismic measurements. This paper focuses on measurements and modeling of the near-field data. A complimentary

Development of a plasma focus neutron source powered by an explosive magnetic generator

NASA Astrophysics Data System (ADS)

Ablesimov, V. E.; Andrianov, A. V.; Bazanov, A. A.; Glybin, A. M.; Dolin, Yu. N.; Drozdov, I. Yu.; Drozdov, Yu. M.; Duday, P. V.; Zimenkov, A. A.; Ivanov, V. A.; Ivanovskii, A. V.; Kalinychev, A. E.; Karpov, G. V.; Kraev, A. I.; Lomtev, S. S.; Nudikov, V. N.; Pak, S. V.; Pozdov, N. I.; Polyushko, S. M.; Rybakov, A. F.; Skobelev, A. N.; Turov, A. N.; Fevralev, A. Yu.

2015-01-01

This paper presents the results of laboratory and explosive experiments with a plasma focus discharge Mather-type chamber at a discharge current amplitude of 1.3-1.4 MA. It has been found that in laboratory experiments, the yield of a deuterium-deuterium neutrons reached 1011, and in an explosive experiment using the chamber filled with a deuterium-tritium gas mixture, the integral yield of a deuterium-tritium neutrons with an energy of 14 MeV was more than 1012 neutrons.

TNT and RDX degradation and extraction from contaminated soil using subcritical water.

PubMed

Islam, Mohammad Nazrul; Shin, Moon-Su; Jo, Young-Tae; Park, Jeong-Hun

2015-01-01

The use of explosives either for industrial or military operations have resulted in the environmental pollution, poses ecological and health hazard. In this work, a subcritical water extraction (SCWE) process at laboratory scale was used at varying water temperature (100-175 °C) and flow rate (0.5-1.5 mL min(-1)), to treat 2,4,6-trinitrotoluene (TNT) and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) contaminated soil, to reveal information with respect to the explosives removal (based on the analyses of soil residue after extraction), and degradation performance (based on the analyses of water extracts) of this process. Continuous flow subcritical water has been considered on removal of explosives to avoid the repartitioning of non-degraded compounds to the soil upon cooling which usually occurs in the batch system. In the SCWE experiments, near complete degradation of both TNT and RDX was observed at 175 °C based on analysis of water extracts and soil. Test results also indicated that TNT removal of >99% and a complete RDX removal were achieved by this process, when the operating conditions were 1 mL min(-1), and treatment time of 20 min, after the temperature reached 175 °C. HPLC-UV and ion chromatography analysis confirmed that the explosives underwent for degradation. The low concentration of explosives found in the process wastewater indicates that water recycling may be viable, to treat additional soil. Our results have shown in the remediation of explosives contaminated soil, the effectiveness of the continuous flow SCWE process. Copyright © 2014 Elsevier Ltd. All rights reserved.

Analytical redundancy and the design of robust failure detection systems

NASA Technical Reports Server (NTRS)

Chow, E. Y.; Willsky, A. S.

1984-01-01

The Failure Detection and Identification (FDI) process is viewed as consisting of two stages: residual generation and decision making. It is argued that a robust FDI system can be achieved by designing a robust residual generation process. Analytical redundancy, the basis for residual generation, is characterized in terms of a parity space. Using the concept of parity relations, residuals can be generated in a number of ways and the design of a robust residual generation process can be formulated as a minimax optimization problem. An example is included to illustrate this design methodology. Previously announcedd in STAR as N83-20653

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fisk, Mark D.; Pasyanos, Michael E.

Characterizing regional seismic signals continues to be a difficult problem due to their variability. Calibration of these signals is very important to many aspects of monitoring underground nuclear explosions, including detecting seismic signals, discriminating explosions from earthquakes, and reliably estimating magnitude and yield. Amplitude tomography, which simultaneously inverts for source, propagation, and site effects, is a leading method of calibrating these signals. A major issue in amplitude tomography is the data quality of the input amplitude measurements. Pre-event and prephase signal-to-noise ratio (SNR) tests are typically used but can frequently include bad signals and exclude good signals. The deficiencies ofmore » SNR criteria, which are demonstrated here, lead to large calibration errors. To ameliorate these issues, we introduce a semi-automated approach to assess the bandwidth of a spectrum where it behaves physically. We determine the maximum frequency (denoted as F max) where it deviates from this behavior due to inflections at which noise or spurious signals start to bias the spectra away from the expected decay. We compare two amplitude tomography runs using the SNR and new F max criteria and show significant improvements to the stability and accuracy of the tomography output for frequency bands higher than 2 Hz by using our assessments of valid S-wave bandwidth. We compare Q estimates, P/S residuals, and some detailed results to explain the improvements. Lastly, for frequency bands higher than 4 Hz, needed for effective P/S discrimination of explosions from earthquakes, the new bandwidth criteria sufficiently fix the instabilities and errors so that the residuals and calibration terms are useful for application.« less

Methane Explosion Mitigation in Coal Mines by Water Mist

NASA Astrophysics Data System (ADS)

Chikhradze, Nikoloz; Mataradze, Edgar; Chikhradze, Mikheil; Krauthammer, Ted; Mansurov, Zulkhair; Alyiev, Erhan

2017-12-01

Statistics shows that the majority of accidents with fatal outcome are caused by methane and/or coal dust explosion. This leads to assume that contemporary counter-explosion systems of various designs cannot be considered effective. Considering the growing threat of methane explosion in the coming years along with the development of deeper levels, the improvement of a system for protecting people in underground opening appears urgent. This paper focuses on technical solutions to be used in designing a protective system for minimizing the consequences of methane explosions in coalmines. The new protective system consists of three main modules: i) a high-speed shock wave suppression section; ii) a suppression section with a long-term action and iii) a system activating device. The shock wave suppressor contains a 200 litre volume water tank with a built-in gas generator and nozzles. It is activated after 12ms from the blast moment, the duration of discharge is 40 s. The suppression section with a long-term action contains a 2000 litre volume water tank, a high-pressure pump, a hydraulic accumulator, solenoid valves, and a system of pipes with built-in nozzles. It is activated after 4 s from the blast moment, the duration of discharge is 8 min. The activation device includes a detection block containing sensors, an emergency signal generation module, a signal transmission module, a signal receiving module and a power supply module. The system operates in a waiting mode and activates immediately upon the receipt of the start signal generated by the detector. The paper also addresses the preliminary results of the system prototype testing in the tunnel.

Location and detection of explosive-contaminated human fingerprints on distant targets using standoff laser-induced breakdown spectroscopy

NASA Astrophysics Data System (ADS)

Lucena, P.; Gaona, I.; Moros, J.; Laserna, J. J.

2013-07-01

Detection of explosive-contaminated human fingerprints constitutes an analytical challenge of high significance in security issues and in forensic sciences. The use of a laser-induced breakdown spectroscopy (LIBS) sensor working at 31 m distance to the target, fitted with 2D scanning capabilities and designed for capturing spectral information from laser-induced plasmas of fingerprints is presented. Distribution chemical maps based on Na and CN emissions are used to locate and detect chloratite, DNT, TNT, RDX and PETN residues that have been deposited on the surface of aluminum and glass substrates. An effectiveness of 100% on fingerprints detection, regardless the substrate scanned, is reached. Environmental factors that affect the prevalence of the fingerprint LIBS response are discussed.

Seismic Methods of Identifying Explosions and Estimating Their Yield

NASA Astrophysics Data System (ADS)

Walter, W. R.; Ford, S. R.; Pasyanos, M.; Pyle, M. L.; Myers, S. C.; Mellors, R. J.; Pitarka, A.; Rodgers, A. J.; Hauk, T. F.

2014-12-01

Seismology plays a key national security role in detecting, locating, identifying and determining the yield of explosions from a variety of causes, including accidents, terrorist attacks and nuclear testing treaty violations (e.g. Koper et al., 2003, 1999; Walter et al. 1995). A collection of mainly empirical forensic techniques has been successfully developed over many years to obtain source information on explosions from their seismic signatures (e.g. Bowers and Selby, 2009). However a lesson from the three DPRK declared nuclear explosions since 2006, is that our historic collection of data may not be representative of future nuclear test signatures (e.g. Selby et al., 2012). To have confidence in identifying future explosions amongst the background of other seismic signals, and accurately estimate their yield, we need to put our empirical methods on a firmer physical footing. Goals of current research are to improve our physical understanding of the mechanisms of explosion generation of S- and surface-waves, and to advance our ability to numerically model and predict them. As part of that process we are re-examining regional seismic data from a variety of nuclear test sites including the DPRK and the former Nevada Test Site (now the Nevada National Security Site (NNSS)). Newer relative location and amplitude techniques can be employed to better quantify differences between explosions and used to understand those differences in term of depth, media and other properties. We are also making use of the Source Physics Experiments (SPE) at NNSS. The SPE chemical explosions are explicitly designed to improve our understanding of emplacement and source material effects on the generation of shear and surface waves (e.g. Snelson et al., 2013). Finally we are also exploring the value of combining seismic information with other technologies including acoustic and InSAR techniques to better understand the source characteristics. Our goal is to improve our explosion models and our ability to understand and predict where methods of identifying explosions and estimating their yield work well, and any circumstances where they may not.

Identification of ovine ruminal microbes capable of biotransforming hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX)

USDA-ARS?s Scientific Manuscript database

Bioremediation is of great interest in the detoxification of soil contaminated with residues from explosives such as hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX). Although there are numerous forms of in situ and ex situ bioremediation, ruminants would provide the option of an in situ bioreactor tha...

Pulse Power Applications of Flux Compression Generators

DTIC Science & Technology

1981-06-01

Characteristics are presented for two different types of explosive driven flux compression generators and a megavolt pulse transformer. Status reports are given for rail gun and plasma focus programs for which the generators serve as power sources.

Explosive propulsion applications. [to future unmanned missions

NASA Technical Reports Server (NTRS)

Nakamura, Y.; Varsi, G.; Back, L. H.

1974-01-01

The feasibility and application of an explosive propulsion concept capable of supporting future unmanned missions in the post-1980 era were examined and recommendations made for advanced technology development tasks. The Venus large lander mission was selected as the first in which the explosive propulsion concept can find application. A conceptual design was generated and its performance, weight, costs, and interaction effects determined. Comparisons were made with conventional propulsion alternatives. The feasibility of the explosive propulsion system was verified for planetology experiments within the dense atmosphere of Venus as well as the outer planets. Additionally, it was determined that the Venus large lander mission could be augmented ballistically with a significant delivery margin.

High explosive corner turning performance and the LANL Mushroom test

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hill, L.G.; Seitz, W.L.; Forest, C.A.

1997-09-01

The Mushroom test is designed to characterize the corner turning performance of a new generation of less insensitive booster explosives. The test is described in detail, and three corner turning figures-of-merit are examined using pure TATB (both Livermore`s Ultrafine and a Los Alamos research blend) and PBX9504 as examples.

A single cell model for pretreatment of wood by microwave explosion

Treesearch

Xianjun Li; Yongdong Zhou; Yonglin Yan; Zhiyong Cai; Fu Feng

2010-01-01

A theoretical model was developed to better understand the process of microwave explosion treatment of wood cells. The cell expansion and critical conditions concerning pressure and temperature of ray parenchyma cells in Eucalyptus urophylla were simulated during microwave pretreatment. The results indicate that longitudinal and circumferential stresses were generated...

Internal friction peaks observed in explosively deformed polycrystalline Mo, Nb, and Cu

NASA Technical Reports Server (NTRS)

Rieu, G. E.; Grimes, H. H.; Romain, J. P.; Defouquet, J.

1974-01-01

Explosive deformation (50 kbar range) induced, in Cu, Mo and Nb, internal friction peaks identical to those observed after large normal deformation. The variation of the peaks with pressure for Mo and Nb lead to an explanation of these processes in terms of double kink generation in screw and edge dislocations.

New challenges and insights in the detection and spectral identification of organic explosives by laser induced breakdown spectroscopy

NASA Astrophysics Data System (ADS)

Lucena, P.; Doña, A.; Tobaria, L. M.; Laserna, J. J.

2011-01-01

With the objective of detection and identification of explosives, different organic compounds, including aromatic nitrocompounds, RDX, anthracene, 2,4-diaminotoluene (DAT), 4-methyl-3-nitroaniline (MNA) and pentaerythritol (PENT) have been analyzed by laser induced breakdown spectroscopy (LIBS). To avoid the secondary ionization and to discriminate between the spectral contribution due to air from that of the compound in the plasma generated in air, the emission signatures from atomic lines (C at 247.9 nm, H at 656.3 nm, N at 746.8 nm and O at 777.2 nm) and molecular bands (CN at 388.3 nm and C 2 at 516.5 nm) have been investigated in plasmas generated in air and in helium. The different possible pathways leading to the observation of molecular emissions have been studied, together with a discussion of the most useful tools for the explosives discrimination. Moreover, the effect of the laser fluence on the atomic and molecular emissions and their relationship with the oxygen balance of an organic explosive is presented.

A portable explosive detector based on fluorescence quenching of pyrene deposited on coloured wax-printed μPADs.

PubMed

Taudte, Regina Verena; Beavis, Alison; Wilson-Wilde, Linzi; Roux, Claude; Doble, Philip; Blanes, Lucas

2013-11-07

A new technique for the detection of explosives has been developed based on fluorescence quenching of pyrene on paper-based analytical devices (μPADs). Wax barriers were generated (150 °C, 5 min) using ten different colours. Magenta was found as the most suitable wax colour for the generation of the hydrophobic barriers with a nominal width of 120 μm resulting in fully functioning hydrophobic barriers. One microliter of 0.5 mg mL(-1) pyrene dissolved in an 80:20 methanol-water solution was deposited on the hydrophobic circle (5 mm diameter) to produce the active microchip device. Under ultra-violet (UV) illumination, ten different organic explosives were detected using the μPAD, with limits of detection ranging from 100-600 ppm. A prototype of a portable battery operated instrument using a 3 W power UV light-emitting-diode (LED) (365 nm) and a photodiode sensor was also built and evaluated for the successful automatic detection of explosives and potential application for field-based screening.

Numerical Simulation of Ionospheric Disturbances Generated by the Chelyabinsk and Tunguska Space Body Impacts

NASA Astrophysics Data System (ADS)

Shuvalov, V. V.; Khazins, V. M.

2018-03-01

Numerical simulation of atmospheric disturbances during the first hours after the Chelyabinsk and Tunguska space body impacts has been carried out. The results of detailed calculations, including the stages of destruction, evaporation and deceleration of the cosmic body, the generation of atmospheric disturbances and their propagation over distances of thousands of kilometers, have been compared with the results of spherical explosions with energy equal to the kinetic energy of meteoroids. It has been shown that in the case of the Chelyabinsk meteorite, an explosive analogy provides acceptable dimensions of the perturbed region and the perturbation amplitude. With a more powerful Tunguska fall, the resulting atmospheric flow is very different from the explosive one; an atmospheric plume emerges that releases matter from the meteoric trace to an altitude of the order of a thousand kilometers.

Simulation Study of Near-Surface Coupling of Nuclear Devices vs. Equivalent High-Explosive Charges

DOE Office of Scientific and Technical Information (OSTI.GOV)

Fournier, Kevin B; Walton, Otis R; Benjamin, Russ

2014-09-29

A computational study was performed to examine the differences in near-surface ground-waves and air-blast waves generated by high-explosive energy sources and those generated by much higher energy - density low - yield nuclear sources. The study examined the effect of explosive-source emplacement (i.e., height-of-burst, HOB, or depth-of-burial, DOB) over a range from depths of -35m to heights of 20m, for explosions with an explosive yield of 1-kt . The chemical explosive was modeled by a JWL equation-of-state model for a ~14m diameter sphere of ANFO (~1,200,000kg – 1 k t equivalent yield ), and the high-energy-density source was modeled asmore » a one tonne (1000 kg) plasma of ‘Iron-gas’ (utilizing LLNL’s tabular equation-of-state database, LEOS) in a 2m diameter sphere, with a total internal-energy content equivalent to 1 k t . A consistent equivalent-yield coupling-factor approach was developed to compare the behavior of the two sources. The results indicate that the equivalent-yield coupling-factor for air-blasts from 1 k t ANFO explosions varies monotonically and continuously from a nearly perfec t reflected wave off of the ground surface for a HOB ≈ 20m, to a coupling factor of nearly zero at DOB ≈ -25m. The nuclear air - blast coupling curve, on the other hand, remained nearly equal to a perfectly reflected wave all the way down to HOB’s very near zero, and then quickly dropped to a value near zero for explosions with a DOB ≈ -10m. The near - surface ground - wave traveling horizontally out from the explosive source region to distances of 100’s of meters exhibited equivalent - yield coupling - factors t hat varied nearly linearly with HOB/DOB for the simulated ANFO explosive source, going from a value near zero at HOB ≈ 5m to nearly one at DOB ≈ -25m. The nuclear-source generated near-surface ground wave coupling-factor remained near zero for almost all HOB’s greater than zero, and then appeared to vary nearly - linearly with depth-of-burial until it reached a value of one at a DOB between 15m and 20m. These simulations confirm the expected result that the variation of coupling to the ground, or the air, change s much more rapidly with emplacement location for a high-energy-density (i.e., nuclear-like) explosive source than it does for relatively low - energy - density chemical explosive sources. The Energy Partitioning, Energy Coupling (EPEC) platform at LLNL utilizes laser energy from one quad (i.e. 4-laser beams) of the 192 - beam NIF Laser bank to deliver ~10kJ of energy to 1mg of silver in a hohlraum creating an effective small-explosive ‘source’ with an energy density comparable to those in low-yield nuclear devices. Such experiments have the potential to provide direct experimental confirmation of the simulation results obtained in this study, at a physical scale (and time-scale) which is a factor of 1000 smaller than the spatial- or temporal-scales typically encountered when dealing with nuclear explosions.« less

Numerical investigation of particle-blast interaction during explosive dispersal of liquids and granular materials

NASA Astrophysics Data System (ADS)

Pontalier, Q.; Lhoumeau, M.; Milne, A. M.; Longbottom, A. W.; Frost, D. L.

2018-05-01

Experiments show that when a high-explosive charge with embedded particles or a charge surrounded by a layer of liquid or granular material is detonated, the flow generated is perturbed by the motion of the particles and the blast wave profile differs from that of an ideal Friedlander form. Initially, the blast wave overpressure is reduced due to the energy dissipation resulting from compaction, fragmentation, and heating of the particle bed, and acceleration of the material. However, as the blast wave propagates, particle-flow interactions collectively serve to reduce the rate of decay of the peak blast wave overpressure. Computations carried out with a multiphase hydrocode reproduce the general trends observed experimentally and highlight the transition between the particle acceleration/deceleration phases, which is not accessible experimentally, since the particles are obscured by the detonation products. The dependence of the particle-blast interaction and the blast mitigation effectiveness on the mitigant to explosive mass ratio, the particle size, and the initial solid volume fraction is investigated systematically. The reduction in peak blast overpressure is, as in experiments, primarily dependent on the mass ratio of material to explosive, with the particle size, density, and initial porosity of the particle bed playing secondary roles. In the near field, the blast overpressure decreases sharply with distance as the particles are accelerated by the flow. When the particles decelerate due to drag, energy is returned to the flow and the peak blast overpressure recovers and reaches values similar to that of a bare explosive charge for low mass ratios. Time-distance trajectory plots of the particle and blast wave motion with the pressure field superimposed, illustrate the weak pressure waves generated by the motion of the particle layer which travel upstream and perturb the blast wave motion. Computation of the particle and gas momentum flux in the multiphase flow generated during explosive particle dispersal indicates that the particle momentum flux is the dominant term in the near field. Both the gas and particle loading must be taken into account when determining the damage to nearby structures following the detonation of a high-explosive charge surrounded by a material layer.

Numerical investigation of particle-blast interaction during explosive dispersal of liquids and granular materials

NASA Astrophysics Data System (ADS)

Pontalier, Q.; Lhoumeau, M.; Milne, A. M.; Longbottom, A. W.; Frost, D. L.

2018-04-01

Experiments show that when a high-explosive charge with embedded particles or a charge surrounded by a layer of liquid or granular material is detonated, the flow generated is perturbed by the motion of the particles and the blast wave profile differs from that of an ideal Friedlander form. Initially, the blast wave overpressure is reduced due to the energy dissipation resulting from compaction, fragmentation, and heating of the particle bed, and acceleration of the material. However, as the blast wave propagates, particle-flow interactions collectively serve to reduce the rate of decay of the peak blast wave overpressure. Computations carried out with a multiphase hydrocode reproduce the general trends observed experimentally and highlight the transition between the particle acceleration/deceleration phases, which is not accessible experimentally, since the particles are obscured by the detonation products. The dependence of the particle-blast interaction and the blast mitigation effectiveness on the mitigant to explosive mass ratio, the particle size, and the initial solid volume fraction is investigated systematically. The reduction in peak blast overpressure is, as in experiments, primarily dependent on the mass ratio of material to explosive, with the particle size, density, and initial porosity of the particle bed playing secondary roles. In the near field, the blast overpressure decreases sharply with distance as the particles are accelerated by the flow. When the particles decelerate due to drag, energy is returned to the flow and the peak blast overpressure recovers and reaches values similar to that of a bare explosive charge for low mass ratios. Time-distance trajectory plots of the particle and blast wave motion with the pressure field superimposed, illustrate the weak pressure waves generated by the motion of the particle layer which travel upstream and perturb the blast wave motion. Computation of the particle and gas momentum flux in the multiphase flow generated during explosive particle dispersal indicates that the particle momentum flux is the dominant term in the near field. Both the gas and particle loading must be taken into account when determining the damage to nearby structures following the detonation of a high-explosive charge surrounded by a material layer.

Basaltic scoria fallout deposits from Ambrym volcano (Vanuatu archipelago): Textural and geochemical evidence of plinian eruptive styles

NASA Astrophysics Data System (ADS)

Balcone-Boissard, H.; Boudon, G.; Poulain, P.

2017-12-01

Plinian eruptions are among the most threatening volcanic hazard responsible of gas and solid particles release into atmosphere leading to potential damages at various spatial and time scales. Such explosive activity generally involves differentiated magmas, silica-rich enough to behave as viscous media and volatile-rich enough to generate significant overpressure in ascending magma. In some rare cases, Plinian eruptions can occur with more basic magmas as basalts. Few eruptions are now recognized on Earth, on Etna (122 BC), Masaya (Fontana) or Tarawera (1886). On Ambrym volcano (Vanuatu), the caldera formation was the result of several large eruptions including some Plinian events dated around 2000 yr. BP. By applying joint textural and geochemical investigations of a representative stratigraphic section of one of these eruptions we present new arguments to discuss the origin of such explosivity for basic magma. To achieve this goal we establish a degassing budget (H2O, CO2, SO2, F, Cl) through the petrological investigation by comparing melt inclusion and residual glass. We compare these results to those of quantitative textural description of pumice clasts through SEM images treated using Image J software, thus linking textural and geochemical arguments. We thus highlight that a low volatile content is not responsible of the overpressure leading to explosivity. Textural characteristics evidence vesicle organisation and low microlite content close that described for Plinian eruption involving differentiated melt. Degassing processes occur following a closed-system degassing evolution well correlated with textural parameters. By comparison to deposits of other basaltic Plinian eruptions, we show that for 122 BC eruption of Mt Etna, textural signature is diverse although we also evidence closed-system degassing processes. This study also permits to confirm that Ambrym is a valuable contributor to halogen release into the atmosphere at a time of reflexion on volcanic halogen contribution to atmosphere budget.

Analysis of the Effect of Prevailing Weather Conditions on the Occurrence of Grain Dust Explosions.

PubMed

Sanghi, Achint; Ambrose, R P Kingsly

2016-07-27

Grain dust explosions have been occurring in the U.S. for the past twenty years. In the past ten years, there have been an average of ten explosions a year, resulting in nine fatalities and 93 injuries. In more than half of these cases, the ignition source remains unidentified. The effect of ambient humidity on the likelihood of a dust explosion has been discussed for many years. However, no investigation into a possible link between the two has been carried out. In this study, we analyzed local weather data and grain dust explosions during the period 2006 to 2014 to measure potential relationships between the two events. The 84 analyzed explosions do not show any trend with regard to prevailing temperatures, or relative or absolute humidity. In addition, the ignition source could not be identified in 54 of the incidents. The majority of grain dust explosion incidents occurred at grain elevator facilities, where the dust generation potential was high compared with grain processing industries. Copyright© by the American Society of Agricultural Engineers.

Insights from the Source Physics Experiments on P/S Amplitude Ratio Methods of Identifying Explosions in a Background of Earthquakes

NASA Astrophysics Data System (ADS)

Walter, W. R.; Ford, S. R.; Xu, H.; Pasyanos, M. E.; Pyle, M. L.; Matzel, E.; Mellors, R. J.; Hauk, T. F.

2012-12-01

It is well established empirically that regional distance (200-1600 km) amplitude ratios of seismic P-to-S waves at sufficiently high frequencies (~>2 Hz) can identify explosions among a background of natural earthquakes. However the physical basis for the generation of explosion S-waves, and therefore the predictability of this P/S technique as a function of event properties such as size, depth, geology and path, remains incompletely understood. A goal of the Source Physics Experiments (SPE) at the Nevada National Security Site (NNSS, formerly the Nevada Test Site (NTS)) is to improve our physical understanding of the mechanisms of explosion S-wave generation and advance our ability to numerically model and predict them. Current models of explosion P/S values suggest they are frequency dependent with poor performance below the source corner frequencies and good performance above. This leads to expectations that small magnitude explosions might require much higher frequencies (>10 Hz) to identify them. Interestingly the 1-ton chemical source physics explosions SPE2 and SPE3 appear to discriminate well from background earthquakes in the frequency band 6-8 Hz, where P and S signals are visible at the NVAR array located near Mina, NV about 200 km away. NVAR is a primary seismic station in the International Monitoring System (IMS), part of the Comprehensive nuclear-Test-Ban Treaty (CTBT). The NVAR broadband element NV31 is co-located with the LLNL station MNV that recorded many NTS nuclear tests, allowing the comparison. We find the small SPE explosions in granite have similar Pn/Lg values at 6-8 Hz as the past nuclear tests mainly in softer rocks. We are currently examining a number of other stations in addition to NVAR, including the dedicated SPE stations that recorded the SPE explosions at much closer distances with very high sample rates, in order to better understand the observed frequency dependence as compared with the model predictions. We plan to use these observations to improve our explosion models and our ability to understand and predict where P/S methods of identifying explosions work and any circumstances where they may not. This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Using the spatial distribution and lithology of ballistic blocks to interpret eruption sequence and dynamics: August 6 2012 Upper Te Maari eruption, New Zealand

NASA Astrophysics Data System (ADS)

Breard, E. C. P.; Lube, G.; Cronin, S. J.; Fitzgerald, R.; Kennedy, B.; Scheu, B.; Montanaro, C.; White, J. D. L.; Tost, M.; Procter, J. N.; Moebis, A.

2014-10-01

The ballistic ejection of blocks during explosive eruptions constitutes a major hazard near active volcanoes. Fields of ballistic clasts can provide important clues towards quantifying the energy, dynamics and directionality of explosive events, but detailed datasets are rare. During the 6 August 2012 hydrothermal eruption of Upper Te Maari (Tongariro), New Zealand, three explosions occurred in rapid succession within less than 20 s. The first two produced laterally-directed pyroclastic density currents (PDC), and the final vertical explosion generated an ash plume. Each of these explosions was associated with the ejection of ballistic blocks. We present detailed maps of the resulting 5.1 km2 block impact field and the distribution of the > 2200 impact craters with diameters > 2.5 m. There are two distinct regions of high crater concentration, where crater densities reach more than six times the average background density. These occur at distances of 500-700 m east and 1000-1350 west of a 430-m-long fissure that was created during the eruption. The high-density fields are characterized by a narrow radial spread of < 45° and are located along the proximal transport direction of the pyroclastic density currents. A provenance analysis of ballistic blocks allowed us to reconstruct two different eruptive vents for the explosions. The first two laterally-directed explosions were sourced from the fissure, while the third explosion occurred through the pre-existing Upper Te Maari Crater, generating a roughly axisymmetric shower of ballistics. Stratigraphic relationships between impact craters, PDC and fall deposits suggest that the ballistic blocks were initially coupled with the rapidly expanding gas-particle mixtures that produced the PDCs. Ballistic trajectory modeling, reproducing the lateral extent and main impact density pattern of the western impact field, allows estimation of the vertical expansion angle of the second and largest explosion. The calculations show that the largest proportion of the explosion energy was strongly focused as a narrow and extremely shallow (from - 3 to 15° from the horizontal) laterally expanding hydrothermal blast. The results presented here constitute an important data set for ballistic hazard assessment at Tongariro volcano and they can provide further clues towards better understanding highly energetic laterally directed volcanic explosions at similar hydrothermal fields.

Detection of vehicle-based improvised explosives using ultra-trace detection equipment

NASA Astrophysics Data System (ADS)

Fisher, Mark; Sikes, John; Prather, Mark; Wichert, Clint

2005-05-01

Vehicle-borne improvised explosive devices (VBIEDs) have become the weapon of choice for insurgents in Iraq. At the same time, these devices are becoming increasingly sophisticated and effective. VBIEDs can be difficult to detect during visual inspection of vehicles. This is especially true when explosives have been hidden behind a vehicle"s panels, inside seat cushions, under floorboards, or behind cargo. Even though the explosive may not be visible, vapors of explosive emanating from the device are often present in the vehicle, but the current generation of trace detection equipment has not been sensitive enough to detect these low concentrations of vapor. This paper presents initial test results using the Nomadics Fido sensor for detection of VBIEDs. The sensor is a small, explosives detector with unprecedented levels of sensitivity for detection of nitroaromatic explosives. Fido utilizes fluorescence quenching of novel polymer materials to detect traces of explosive vapor emanating from targets containing explosives. These materials, developed by collaborators at the Massachusetts Institute of Technology (MIT), amplify the quenching response that occurs when molecules of explosive bind to films of the polymer. These materials have enabled development of sensors with performance approaching that of canines trained to detect explosives. The ability of the sensor to detect explosives in vehicles and on persons who have recently been in close proximity to explosives has recently been demonstrated. In these tests, simulated targets were quickly and easily detected using a Fido sensor in conjunction with both direct vapor and swipe sampling methods. The results of these tests suggest that chemical vapor sensing has utility as a means of screening vehicles for explosives at checkpoints and on patrols.

Can North Korean Nuclear Explosions Stir Baekdu (Changbai) Volcano to be Erupted?

NASA Astrophysics Data System (ADS)

Hong, T. K.; Choi, E.; Park, S.; Shin, J. S.

2015-12-01

Potential volcanic eruption in Mt. Baekdu (Changbai) hasbeen a long-lasting concern in the far-eastern Asia.There were several explosive eruptions historically. Themost recent eruption was made in 1903. The eruption in969 is believed to be the most violent with volcanicexplosivity index of 7. The volcano is located in ~130 kmaway from the North Korean nuclear explosion test sitewhere three moderate-size nuclear explosions withmagnitudes of 4.3, 4.7 and 5.1 were conducted in 2006,2009 and 2013. There is increasing concern that a largenuclear explosion may trigger volcanic eruption. Seismicwaveforms are subtle to vary with the crustal structure.The strong ground motions generated by a potential largenuclear explosion are difficult to be simulated forvolcanic regions where complex crustal structures areexpected. We calculate the ground motions by hypotheticallarge nuclear explosions using a nuclear-explosion sourcemodel and the seismic waveforms of prior nuclearexplosions. The validity of the method is examined bycomparing the observed and quasi-synthetic seismicwaveforms of prior nuclear explosions. The peak groundaccelerations (PGA) around the volcano are estimated froma PGA attenuation equation that was determined based onseismic waveforms from natural earthquakes. Thehorizontal and vertical PGAs by an M7.0 undergroundnuclear explosion are expected to reach 0.14 and 0.11m/s2 at the volcano, inducing a dynamic stress in themagma chamber. The induced pressure change in the magmachamber is verified by numerical modeling of dynamicstress changes.

Oxidative degradation of biorefinery lignin obtained after pretreatment of forest residues of Douglas Fir.

PubMed

Srinivas, Keerthi; de Carvalho Oliveira, Fernanda; Teller, Philip Johan; Gonҫalves, Adilson Roberto; Helms, Gregory L; Ahring, Birgitte Kaer

2016-12-01

Harvested forest residues are usually considered a fire hazards and used as "hog-fuel" which results in air pollution. In this study, the biorefinery lignin stream obtained after wet explosion pretreatment and enzymatic hydrolysis of forestry residues of Douglas Fir (FS-10) was characterized and further wet oxidized under alkaline conditions. The studies indicated that at 10% solids, 11.7wt% alkali and 15min residence time, maximum yields were obtained for glucose (12.9wt%), vanillin (0.4wt%) at 230°C; formic acid (11.6wt%) at 250°C; acetic acid (10.7wt%), hydroxybenzaldehyde (0.2wt%), syringaldehyde (0.13wt%) at 280°C; and lactic acid (12.4wt%) at 300°C. FTIR analysis of the solid residue after wet oxidation showed that the aromatic skeletal vibrations relating to lignin compounds increased with temperature indicating that higher severity could result in increased lignin oxidation products. The results obtained, as part of the study, is significant for understanding and optimizing processes for producing high-value bioproducts from forestry residues. Copyright © 2016 Elsevier Ltd. All rights reserved.

Defeating camouflage and finding explosives through spectral matched filtering of hyperspectral imagery

NASA Astrophysics Data System (ADS)

Dombrowski, Mark S.; Willson, Paul D.; LaBaw, Clayton C.

1997-01-01

In order to achieve their goal of surreptitious operation within a country, terrorist organizations attempt to hide themselves from public view. In many instances such masking takes the form of simply appearing like the surrounding populace. In others, such as training facilities, standard military camouflaging techniques are used to conceal the group's equipment and activities. To effectively monitor and suppress activities of terrorist organizations, defeating the groups' attempt to hide is essential. Although finding individuals hiding within a society is extremely problematic, discovering camouflaged equipment, facilities, and personnel is readily accomplished by proper exploitation of hyperspectral imagery. Camouflage techniques attempt to make an object appear similar to its background, thereby making it difficult to find. Although making an object have similar color to its background is fairly easy, making it have the same spectral appearance is nearly impossible, unless the object is covered in the same material as the background. Even attempting to hide an object by covering it in background material will not work against a spectral imager since the act of moving the background material, e.g., foliage cuttings, changes the material's spectral characteristics. Hence, by collecting and properly exploiting spectral imagery, camouflaged objects can be readily differentiated from their background. This paper presents development of this technique, and of the MIDIS (multi-band identification and discrimination imaging spectroradiometer) instrument capable of real-time discrimination of camouflaged objects throughout a scene. Spectral matched-filtering of hyperspectral imagery also has the potential to find vehicles or structures which may be laden with explosives. Many explosives contain volatile materials, the release of which can be imaged by viewing appropriate spectral regions. Volatiles from the fuel oil in readily-produced ANFO are an example. If such volatiles were seen emanating from a vehicle or structure where they would not normally be expected, closer inspection would be warranted. Additionally, packing a vehicle with explosives often leaves trace residues on the outside of the vehicle. Spectral imaging and matched filtering can be used to identify these residues. Incorporation of spectral imaging surveillance equipment at probable terrorist targets could avert disasters such as the tragic bombing of the Murrah Federal Building in Oklahoma City. Application of MIDIS technology to explosive identification is also detailed.

Calibrated vapor generator source

DOEpatents

Davies, John P.; Larson, Ronald A.; Goodrich, Lorenzo D.; Hall, Harold J.; Stoddard, Billy D.; Davis, Sean G.; Kaser, Timothy G.; Conrad, Frank J.

1995-01-01

A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet.

Trace detection of perchlorate in industrial-grade emulsion explosive with portable surface-enhanced Raman spectroscopy.

PubMed

Nuntawong, N; Eiamchai, P; Limwichean, S; Wong-ek, B; Horprathum, M; Patthanasettakul, V; Leelapojanaporn, A; Nakngoenthong, S; Chindaudom, P

2013-12-10

Recent analyses by ion-exchange chromatography (IC) showed that, beside nitrate, the majority of the industrial-grade emulsion explosives, extensively used by most separatists in the southern Thailand insurgency, contained small traces of perchlorate anions. In demand for the faster, reliable, and simple detection methods, the portable detection of nitrate and perchlorate became the great interest for the forensic and field-investigators. This work proposed a unique method to detect the trace amount of perchlorate in seven industrial-grade emulsion explosives under the field tests. We utilized the combination of the portable Raman spectroscope, the developed surfaced-enhanced Raman substrates, and the sample preparation procedures. The portable Raman spectroscope with a laser diode of 785 nm for excitation and a thermoelectric-cooled CCD spectrometer for detection was commercially available. The SERS substrates, with uniformly distributed nanostructured silver nanorods, were fabricated by the DC magnetron sputtering system, based on the oblique-angle deposition technique. The sample preparation procedures were proposed based on (1) pentane extraction technique and (2) combustion technique, prior to being dissolved in the purified water. In comparison to the ion chromatography and the conventional Raman measurements, our proposed methods successfully demonstrated the highly sensitive detectability of the minimal trace amount of perchlorate from five of the explosives with minimal operating time. This work was therefore highly practical to the development for the forensic analyses of the post-blast explosive residues under the field-investigations. Copyright © 2013 Elsevier Ireland Ltd. All rights reserved.

Stand-off detection of explosive particles by imaging Raman spectroscopy

NASA Astrophysics Data System (ADS)

Nordberg, Markus; Åkeson, Madeleine; Östmark, Henric; Carlsson, Torgny E.

2011-06-01

A multispectral imaging technique has been developed to detect and identify explosive particles, e.g. from a fingerprint, at stand-off distances using Raman spectroscopy. When handling IED's as well as other explosive devices, residues can easily be transferred via fingerprints onto other surfaces e.g. car handles, gear sticks and suite cases. By imaging the surface using multispectral imaging Raman technique the explosive particles can be identified and displayed using color-coding. The technique has been demonstrated by detecting fingerprints containing significant amounts of 2,4-dinitrotoulene (DNT), 2,4,6-trinitrotoulene (TNT) and ammonium nitrate at a distance of 12 m in less than 90 seconds (22 images × 4 seconds)1. For each measurement, a sequence of images, one image for each wave number, is recorded. The spectral data from each pixel is compared with reference spectra of the substances to be detected. The pixels are marked with different colors corresponding to the detected substances in the fingerprint. The system has now been further developed to become less complex and thereby less sensitive to the environment such as temperature fluctuations. The optical resolution has been improved to less than 70 μm measured at 546 nm wavelength. The total detection time is ranging from less then one minute to around five minutes depending on the size of the particles and how confident the identification should be. The results indicate a great potential for multi-spectral imaging Raman spectroscopy as a stand-off technique for detection of single explosive particles.

Method of digesting an explosive nitro compound

DOEpatents

Shah, Manish M.

2000-01-01

The present invention is a process wherein bleaching oxidants are used to digest explosive nitro compounds. The process has an excellent reaction rate for digesting explosives and operates under multivariate conditions. Reaction solutions may be aqueous, non-aqueous or a combination thereof, and can also be any pH, but preferably have a pH between 2 and 9. The temperature may be ambient as well as any temperature above which freezing of the solution would occur and below which any degradation of the bleaching oxidant would occur or below which any explosive reaction would be initiated. The pressure may be any pressure, but is preferably ambient or atmospheric, or a pressure above a vapor pressure of the aqueous solution to avoid boiling of the solution. Because the bleaching oxidant molecules are small, much smaller than an enzyme molecule for example, they can penetrate the microstructure of plastic explosives faster. The bleaching oxidants generate reactive hydroxyl radicals, which can destroy other organic contaminants, if necessary, along with digesting the explosive nitro compound.

Design Considerations for a Portable Raman Probe Spectrometer for Field Forensics

DOE PAGES

Kelly, James F.; Blake, Thomas A.; Bernacki, Bruce E.; ...

2012-01-01

Raman spectroscopy has been shown to be a viable method for explosives detection. Currently most forensic Raman systems are either large, powerful instruments for laboratory experiments or handheld instruments forin situpoint detection. We have chosen to examine the performance of certain benchtop Raman probe systems with the goal of developing an inexpensive, portable system that could be used to operate in a field forensics laboratory to examine explosives-related residues or samples. To this end, a rugged, low distortion line imaging dispersive Raman spectrograph was configured to work at 830 nm laser excitation and was used to determine whether the compositionmore » of thin films of plastic explosives or small (e.g., ≤10 μm) particles of RDX or other explosives or oxidizers can be detected, identified, and quantified in the field. With 300 mW excitation energy, concentrations of RDX and PETN can be detected and reconstructed in the case of thin Semtex smears, but further work is needed to push detection limits of areal dosages to the ~1μg/cm 2level. We describe the performance of several probe/spectrograph combinations and show preliminary data for particle detection, calibration and detection linearity for mixed compounds, and so forth.« less

The discrimination of man-made explosions from earthquakes using seismo-acoustic analysis in the Korean Peninsula

NASA Astrophysics Data System (ADS)

Che, Il-Young; Jeon, Jeong-Soo

2010-05-01

Korea Institute of Geoscience and Mineral Resources (KIGAM) operates an infrasound network consisting of seven seismo-acoustic arrays in South Korea. Development of the arrays began in 1999, partially in collaboration with Southern Methodist University, with the goal of detecting distant infrasound signals from natural and anthropogenic phenomena in and around the Korean Peninsula. The main operational purpose of this network is to discriminate man-made seismic events from seismicity including thousands of seismic events per year in the region. The man-made seismic events are major cause of error in estimating the natural seismicity, especially where the seismic activity is weak or moderate such as in the Korean Peninsula. In order to discriminate the man-made explosions from earthquakes, we have applied the seismo-acoustic analysis associating seismic and infrasonic signals generated from surface explosion. The observations of infrasound at multiple arrays made it possible to discriminate surface explosion, because small or moderate size earthquake is not sufficient to generate infrasound. Till now we have annually discriminated hundreds of seismic events in seismological catalog as surface explosions by the seismo-acoustic analysis. Besides of the surface explosions, the network also detected infrasound signals from other sources, such as bolide, typhoons, rocket launches, and underground nuclear test occurred in and around the Korean Peninsula. In this study, ten years of seismo-acoustic data are reviewed with recent infrasonic detection algorithm and association method that finally linked to the seismic monitoring system of the KIGAM to increase the detection rate of surface explosions. We present the long-term results of seismo-acoustic analysis, the detection capability of the multiple arrays, and implications for seismic source location. Since the seismo-acoustic analysis is proved as a definite method to discriminate surface explosion, the analysis will be continuously used for estimating natural seismicity and understanding infrasonic sources.

Optical observation of metal jet generated by high speed inclined collision

NASA Astrophysics Data System (ADS)

Mori, A.; Tanaka, S.; Hokamoto, K.

2017-02-01

Explosive welding, one of the high energy rate material processing, is known the technique to weld strongly for the dissimilar metal combinations. When a metal is collided to the other metal at high velocity with a certain angle, good welding is achieved in this technique. Important parameters of the explosive welding method are the collision velocity and the collision angle. And it is necessary to know these parameters to obtain the explosively welded materials of several metals combinations. However, the optical observation for the collision of metal plate accelerated by the explosive is difficult because of the obstruction by the spreading of detonation gas. In the present work a single-stage powder gun and high speed video camera were used to observe the inclined collision of metals at the high velocity. Projectile consisted by a metal disc and sabot was accelerated by the deflagration of a gunpowder and was collided to another metal disc set with a certain angle. Metal jet was generated at the collision point when the projectile was collided to the target disc in the range of suitable conditions. By using this observation system, a series of the flow from the high speed collision to the generation of metal jet could be taken photographs clearly. This investigation shows the experimental results of the similar and dissimilar metal collision, with comparing the visualization of a metal jet simulated numerically.

Energy Partitioning of Seismic Phases: Current Datasets and Techniques Aimed at Improving the Future of Event Identification

NASA Astrophysics Data System (ADS)

Bonner, J.

2006-05-01

Differences in energy partitioning of seismic phases from earthquakes and explosions provide the opportunity for event identification. In this talk, I will briefly review teleseismic Ms:mb and P/S ratio techniques that help identify events based on differences in compressional, shear, and surface wave energy generation from explosions and earthquakes. With the push to identify smaller yield explosions, the identification process has become increasingly complex as varied types of explosions, including chemical, mining, and nuclear, must be identified at regional distances. Thus, I will highlight some of the current views and problems associated with the energy partitioning of seismic phases from single- and delay-fired chemical explosions. One problem yet to have a universally accepted answer is whether the explosion and earthquake populations, based on the Ms:mb discriminants, should be separated at smaller magnitudes. I will briefly describe the datasets and theory that support either converging or parallel behavior of these populations. Also, I will discuss improvement to the currently used methods that will better constrain this problem in the future. I will also discuss the role of regional P/S ratios in identifying explosions. In particular, recent datasets from South Africa, Scandinavia, and the Western United States collected from earthquakes, single-fired chemical explosions, and/or delay-fired mining explosions have provide new insight into regional P, S, Lg, and Rg energy partitioning. Data from co-located mining and chemical explosions suggest that some mining explosions may be used for limited calibration of regional discriminants in regions where no historic explosion data is available.

Hydrocarbon generation and expulsion in shale Vs. carbonate source rocks

DOE Office of Scientific and Technical Information (OSTI.GOV)

Leythaeuser, D.; Krooss, B.; Hillebrand, T.

1993-09-01

For a number of commercially important source rocks of shale and of carbonate lithologies, which were studied by geochemical, microscopical, and petrophysical techniques, a systematic comparison was made of the processes on how hydrocarbon generation and migration proceed with maturity progress. In this way, several fundamental differences between both types of source rocks were recognized, which are related to differences of sedimentary facies and, more importantly, of diagenetic processes responsible for lithification. Whereas siliciclastic sediments lithify mainly by mechanical compaction, carbonate muds get converted into lithified rocks predominantly by chemical diagenesis. With respect to their role as hydrocarbon source rocks,more » pressure solution processes appear to be key elements. During modest burial stages and prior to the onset of hydrocarbon generation reactions by thermal decomposition of kerogen, pressure solution seams and stylolites. These offer favorable conditions for hydrocarbon generation and expulsion-a three-dimensional kerogen network and high organic-matter concentrations that lead to effective saturation of the internal pore fluid system once hydrocarbon generation has started. As a consequence, within such zones pore fluids get overpressured, leading ultimately to fracturing. Petroleum expulsion can then occur at high efficiencies and in an explosive fashion, whereby clay minerals and residual kerogen particles are squeezed in a toothpaste-like fashion into newly created fractures. In order to elucidate several of the above outlined steps of hydrocarbon generation and migration processes, open-system hydrous pyrolysis experiments were performed. This approach permits one to monitor changes in yield and composition of hydrocarbon products generated and expelled at 10[degrees]C temperature increments over temperature range, which mimics in the laboratory the conditions prevailing in nature over the entire liquid window interval.« less

Development of an FPGA-based multipoint laser pyroshock measurement system for explosive bolts

NASA Astrophysics Data System (ADS)

Abbas, Syed Haider; Jang, Jae-Kyeong; Lee, Jung-Ryul; Kim, Zaeill

2016-07-01

Pyroshock can cause failure to the objective of an aerospace structure by damaging its sensitive electronic equipment, which is responsible for performing decisive operations. A pyroshock is the high intensity shock wave that is generated when a pyrotechnic device is explosively triggered to separate, release, or activate structural subsystems of an aerospace architecture. Pyroshock measurement plays an important role in experimental simulations to understand the characteristics of pyroshock on the host structure. This paper presents a technology to measure a pyroshock wave at multiple points using laser Doppler vibrometers (LDVs). These LDVs detect the pyroshock wave generated due to an explosive-based pyrotechnical event. Field programmable gate array (FPGA) based data acquisition is used in the study to acquire pyroshock signals simultaneously from multiple channels. This paper describes the complete system design for multipoint pyroshock measurement. The firmware architecture for the implementation of multichannel data acquisition on an FPGA-based development board is also discussed. An experiment using explosive bolts was configured to test the reliability of the system. Pyroshock was generated using explosive excitation on a 22-mm-thick steel plate. Three LDVs were deployed to capture the pyroshock wave at different points. The pyroshocks captured were displayed as acceleration plots. The results showed that our system effectively captured the pyroshock wave with a peak-to-peak magnitude of 303 741 g. The contribution of this paper is a specialized architecture of firmware design programmed in FPGA for data acquisition of large amount of multichannel pyroshock data. The advantages of the developed system are the near-field, multipoint, non-contact, and remote measurement of a pyroshock wave, which is dangerous and expensive to produce in aerospace pyrotechnic tests.

Generation of extreme state of water by spherical wire array underwater electrical explosion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Antonov, O.; Gilburd, L.; Efimov, S.

2012-10-15

The results of the first experiments on the underwater electrical explosion of a spherical wire array generating a converging strong shock wave are reported. Using a moderate pulse power generator with a stored energy of {<=}6 kJ and discharge current of {<=}500 kA with a rise-time of {approx}300 ns, explosions of Cu and Al wire arrays of different diameters and with a different number and diameter of wires were tested. Electrical, optical, and destruction diagnostics were used to determine the energy deposited into the array, the time-of-flight of the shock wave to the origin of the implosion, and the parametersmore » of water at that location. The experimental and numerical simulation results indicate that the convergence of the shock wave leads to the formation of an extreme state of water in the vicinity of the implosion origin that is characterized by pressure, temperature, and compression factors of (2 {+-} 0.2) Multiplication-Sign 10{sup 12} Pa, 8 {+-} 0.5 eV, and 7 {+-} 0.5, respectively.« less

On the generation of tangential ground motion by underground explosions in jointed rocks

NASA Astrophysics Data System (ADS)

Vorobiev, Oleg; Ezzedine, Souheil; Antoun, Tarabay; Glenn, Lewis

2015-03-01

This paper describes computational studies of tangential ground motions generated by spherical explosions in a heavily jointed granite formation. Various factors affecting the shear wave generation are considered, including joint spacing, orientation and frictional properties. Simulations are performed both in 2-D for a single joint set to elucidate the basic response mechanisms, and in 3-D for multiple joint sets to realistically represent in situ conditions in a realistic geological setting. The joints are modelled explicitly using both contact elements and weakness planes in the material. Simulations are performed both deterministically and stochastically to quantify the effects of geological uncertainties on near field ground motions. The mechanical properties of the rock and the joints as well as the joint spacing and orientation are taken from experimental test data and geophysical logs corresponding to the Climax Stock granitic outcrop, which is the geological setting of the source physics experiment (SPE). Agreement between simulation results and near field wave motion data from SPE enables newfound understanding of the origin and extent of non-spherical motions associated with underground explosions in fractured geological media.

Explosive-residue compounds resulting from snow avalanche control in the Wasatch Mountains of Utah

USGS Publications Warehouse

Naftz, David L.; Kanagy, Leslie K.; Susong, David D.; Wydoski, Duane S.; Kanagy, Christopher J.

2003-01-01

A snow avalanche is a powerful force of nature that can play a significant role in developing mountain landscapes (Perla and Martinelli, 1975). More importantly, loss of life can occur when people are caught in the path of snow avalanches (Grossman, 1999). Increasing winter recreation, including skiing, snowboarding, snowmobiling, snowshoeing, and climbing in mountainous areas, has increased the likelihood of people encountering snow avalanches (fig. 1). Explosives are used by most ski areas and State highway departments throughout the Western United States to control the release of snow avalanches, thus minimizing the loss of human life during winter recreation and highway travel (fig. 2).Common explosives used for snow avalanche control include trinitrotoluene (TNT), pentaerythritoltetranitrate (PETN), cyclotrimethylenetrinitramine (RDX), tetrytol, ammonium nitrate, and nitroglycerin (Perla and Martinelli, 1975). During and after snowfall or wind loading of potential avalanche slopes, ski patrollers and Utah Department of Transportation personnel deliver explosive charges onto predetermined targets to artificially release snow avalanches, thereby rendering the slope safer for winter activities. Explosives can be thrown by hand onto target zones or shot from cannons for more remote delivery of explosive charges. Hand-delivered charges typically contain about 2 pounds of TNT or its equivalent (Perla and Martinelli, 1975).Depending on the size of the ski area, acreage of potential avalanche terrain, and weather conditions, the annual quantity of explosives used during a season of snow avalanche control can be substantial. For example, the three ski areas of Alta, Snowbird, and Brighton, plus the Utah Department of Transportation, may use as many as 11,200 hand charges per year (Wasatch Powderbird Guides, unpub. data, 1999) for snow avalanche control in Big and Little Cottonwood Canyons (fig. 3). If each charge is assumed to weigh 2 pounds, this equates to about 22,400 pounds of explosive hand charges per year. In addition, 2,240 to 3,160 Avalauncher rounds and 626 to 958 military artillery rounds (explosive mass not specified) are used each year by the three ski areas and the Utah Department of Transportation for snow avalanche control in Big and Little Cottonwood Canyons (Wasatch Powderbird Guides, unpub. data, 1999). The other ski area in Big Cottonwood Canyon, Brighton, uses about 2,000 pounds of explosives per year for snow avalanche control (Michele Weidner, Cirrus Ecological Solutions consultant, written commun., 2001).

The 2009 eruption of Redoubt Volcano, Alaska

USGS Publications Warehouse

Bull, Katharine F.; Cameron, Cheryl; Coombs, Michelle L.; Diefenbach, Angie; Lopez, Taryn; McNutt, Steve; Neal, Christina; Payne, Allison; Power, John A.; Schneider, David J.; Scott, William E.; Snedigar, Seth; Thompson, Glenn; Wallace, Kristi; Waythomas, Christopher F.; Webley, Peter; Werner, Cynthia A.; Schaefer, Janet R.

2012-01-01

Redoubt Volcano, an ice-covered stratovolcano on the west side of Cook Inlet, erupted in March 2009 after several months of escalating unrest. The 2009 eruption of Redoubt Volcano shares many similarities with eruptions documented most recently at Redoubt in 1966–68 and 1989–90. In each case, the eruptive phase lasted several months, consisted of multiple ashproducing explosions, produced andesitic lava and tephra, removed significant amounts of ice from the summit crater and Drift glacier, generated lahars that inundated the Drift River valley, and culminated with the extrusion of a lava dome in the summit crater. Prior to the 2009 explosive phase of the eruption, precursory seismicity lasted approximately six months with the fi rst weak tremor recorded on September 23, 2008. The first phreatic explosion was recorded on March 15, and the first magmatic explosion occurred seven days later, at 22:34 on March 22. The onset of magmatic explosions was preceded by a strong, shallow swarm of repetitive earthquakes that began about 04:00 on March 20, 2009, less than three days before an explosion. Nineteen major ash-producing explosions generated ash clouds that reached heights between 17,000 ft and 62,000 ft (5.2 and 18.9 km) ASL. During ash fall in Anchorage, the Ted Stevens International Airport was shut down for 20 hours, from ~17:00 on March 28 until 13:00 on March 29. On March 23 and April 4, lahars with fl ow depths to 10 m in the upper Drift River valley inundated parts of the Drift River Terminal (DRT). The explosive phase ended on April 4 with a dome collapse at 05:58. The April 4 ash cloud reached 50,000 ft (15.2 km) and moved swiftly to the southeast, depositing up to 2 mm of ash fall in Homer, Anchor Point, and Seldovia. At least two and possibly three lava domes grew and were destroyed by explosions prior to the final lava dome extrusion that began after the April 4 event. The fi nal lava dome ceased growth by July 1, 2009, with an estimated volume of 72 Mm3

Human Health and Ecological Risk Assessment for the Operation of the Explosives Waste Treatment Facility at Site 300 of the Lawrence Livermore National Laboratory Volume 1: Report of Results

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gallegos, G; Daniels, J; Wegrecki, A

2006-04-24

This document contains the human health and ecological risk assessment for the Resource Recovery and Conservation Act (RCRA) permit renewal for the Explosives Waste Treatment Facility (EWTF). Volume 1 is the text of the risk assessment, and Volume 2 (provided on a compact disc) is the supporting modeling data. The EWTF is operated by the Lawrence Livermore National Laboratory (LLNL) at Site 300, which is located in the foothills between the cities of Livermore and Tracy, approximately 17 miles east of Livermore and 8 miles southwest of Tracy. Figure 1 is a map of the San Francisco Bay Area, showingmore » the location of Site 300 and other points of reference. One of the principal activities of Site 300 is to test what are known as ''high explosives'' for nuclear weapons. These are the highly energetic materials that provide the force to drive fissionable material to criticality. LLNL scientists develop and test the explosives and the integrated non-nuclear components in support of the United States nuclear stockpile stewardship program as well as in support of conventional weapons and the aircraft, mining, oil exploration, and construction industries. Many Site 300 facilities are used in support of high explosives research. Some facilities are used in the chemical formulation of explosives; others are locations where explosive charges are mechanically pressed; others are locations where the materials are inspected radiographically for such defects as cracks and voids. Finally, some facilities are locations where the machined charges are assembled before they are sent to the on-site test firing facilities, and additional facilities are locations where materials are stored. Wastes generated from high-explosives research are treated by open burning (OB) and open detonation (OD). OB and OD treatments are necessary because they are the safest methods for treating explosives wastes generated at these facilities, and they eliminate the requirement for further handling and transportation that would be required if the wastes were treated off site.« less

Human Health and Ecological Risk Assessment for the Operation of the Explosives Waste Treatment Facility at Site 300 of the Lawrence Livermore National Laboratory

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gallegos, G; Daniels, J; Wegrecki, A

2007-10-01

This document contains the human health and ecological risk assessment for the Resource Recovery and Conservation Act (RCRA) permit renewal for the Explosives Waste Treatment Facility (EWTF). Volume 1 is the text of the risk assessment, and Volume 2 (provided on a compact disc) is the supporting modeling data. The EWTF is operated by the Lawrence Livermore National Laboratory (LLNL) at Site 300, which is located in the foothills between the cities of Livermore and Tracy, approximately 17 miles east of Livermore and 8 miles southwest of Tracy. Figure 1 is a map of the San Francisco Bay Area, showingmore » the location of Site 300 and other points of reference. One of the principal activities of Site 300 is to test what are known as 'high explosives' for nuclear weapons. These are the highly energetic materials that provide the force to drive fissionable material to criticality. LLNL scientists develop and test the explosives and the integrated non-nuclear components in support of the United States nuclear stockpile stewardship program as well as in support of conventional weapons and the aircraft, mining, oil exploration, and construction industries. Many Site 300 facilities are used in support of high explosives research. Some facilities are used in the chemical formulation of explosives; others are locations where explosive charges are mechanically pressed; others are locations where the materials are inspected radiographically for such defects as cracks and voids. Finally, some facilities are locations where the machined charges are assembled before they are sent to the onsite test firing facilities, and additional facilities are locations where materials are stored. Wastes generated from high-explosives research are treated by open burning (OB) and open detonation (OD). OB and OD treatments are necessary because they are the safest methods for treating explosives wastes generated at these facilities, and they eliminate the requirement for further handling and transportation that would be required if the wastes were treated off site.« less

Pressure Measurements for Tungsten Wire Explosions in Water

NASA Astrophysics Data System (ADS)

Afanas'ev, V. N.

2005-07-01

Successful wire array implosion experiments carried out on PBFA- Z accelerator [1], in which a record-breaking soft x-ray yield of more than 1.5 MJ was observed, stimulated interest in research of electric explosion of thin metal wires. The results of pressure measurements micron's tungsten wire explosion, which carried out in deionized water. Thin tungsten wire explosion was investigated experimentally at current pulse 100 ns duration. The shock waves from the 70 μm tungsten wire explosion were measured by the piezoceramic pressure gauge. The gauges were placed at a range from 3 to 15 mm of wire. The piezoceramic gauges were calibrated on the stable electron beams generator with nanoseconds duration. Experiments were carried out for verifying the tungsten plasma equation of state parameters under different values of the deposited energy. [1] R. B. Spielman, C. Deeney, G. A. Chandler et al., Phys.Plasmas #5, ð. 2105, 1998. The work was supported by ISTC # 1826

Effect of Shock Precompression on the Critical Diameter of Liquid Explosives

NASA Astrophysics Data System (ADS)

Petel, Oren E.; Higgins, Andrew J.; Yoshinaka, Akio C.; Zhang, Fan

2006-07-01

The critical diameter of both ambient and shock-precompressed liquid nitromethane confined in PVC tubing are measured experimentally. The experiment was conducted for both amine sensitized and neat NM. In the precompression experiments, the explosive is compressed by a strong shock wave generated by a donor explosive and reflected from a high impedance anvil prior to being detonated by a secondary event. The pressures reached in the test sections prior to detonation propagation was approximately 7 and 8 GPa for amine sensitized and neat NM respectively. The results demonstrated a 30% - 65% decrease in the critical diameter for the shock-compressed explosives. This critical diameter decrease is observed despite a significant decrease in the predicted Von Neumann temperature of the detonation in the precompressed explosive. The results are discussed in the context of theoretical predictions based on thermal ignition theory and previous critical diameter measurements.

Strength of the phase change materials on loading with the products of electric explosion of conductors

NASA Astrophysics Data System (ADS)

Savenkov, Georgiy; Morozov, Viktor; Kats, Victor

2018-05-01

Results of the experimentation on the destruction of the phase change materials (beeswax and paraffin) by the electric explosion of conductors are presented. The process of the explosion of copper and nickel titanium wires in both pure PCM and its mixture with nonosized additives of cuprous oxide is analyzed. The effect of this additive on the process of the expansion of the electric-discharge plasma during the electric explosion of conductors and on the strength of composite materials is demonstrated. The piezoprobe-based method of measurement of the radial pressure during samples destruction is developed. The experiments made it possible to determine the dimensions of the melting channel formed inside the samples during the explosion and the subsequent expansion of the electric-discharge plasma. The experiments are performed on the generator of short-term high-voltage pulses capable to shape the voltage of (10-24) kV.

Experimental study of the nonlinear diffusion of a magnetic field and skin explosion of cylindrical conductors

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chaikovsky, S. A.; Datsko, I. M.; Labetskaya, N. A.

The paper presents the results of an experimental study of the skin explosion of cylindrical conductors of diameter 1–3 mm (copper, aluminum, titanium, steel 3, and stainless steel) at a peak magnetic field of 200–600 T. The experiments were carried out on the MIG pulsed power generator at a current of up to 2.5 MA and a current rise time of 100 ns. The surface explosion of a conductor was identified by the appearance of a flash of extreme ultraviolet radiation. A minimum magnetic induction has been determined below which no plasma is generated at the conductor surface. For copper, aluminum, steel 3,more » titanium, and stainless steel, the minimum magnetic induction has been estimated to be (to within 10%) 375, 270, 280, 220, and 245 T, respectively.« less

Underwater electrical wire explosion: Shock wave from melting being overtaken by shock wave from vaporization

NASA Astrophysics Data System (ADS)

Li, Liuxia; Qian, Dun; Zou, Xiaobing; Wang, Xinxin

2018-05-01

The shock waves generated by an underwater electrical wire explosion were investigated. A microsecond time-scale pulsed current source was used to trigger the electrical explosion of copper wires with a length of 5 cm and a diameter of 200 μm. The energy-storage capacitor was charged to a relatively low energy so that the energy deposited onto the wire was not large enough to fully vaporize the whole wire. Two shock waves were recorded with a piezoelectric gauge that was located at a position of 100 mm from the exploding wire. The first and weak shock wave was confirmed to be the contribution from wire melting, while the second and stronger shock wave was the contribution from wire vaporization. The phenomenon whereby the first shock wave generated by melting being overtaken by the shock wave due to vaporization was observed.

The acoustic field in the ionosphere caused by an underground nuclear explosion

NASA Astrophysics Data System (ADS)

Krasnov, V. M.; Drobzheva, Ya. V.

2005-07-01

The problem of describing the generation and propagation of an infrasonic wave emitted by a finite extended source in the inhomogeneous absorbing atmosphere is the focus of this paper. It is of interest since the role of infrasonic waves in the energy balance of the upper atmosphere remains largely unknown. We present an algorithm, which allows adaptation of a point source model for calculating the infrasonic field from an underground nuclear explosion at ionospheric altitudes. Our calculations appear to agree remarkably well with HF Doppler sounding data measured for underground nuclear explosions at the Semipalatinsk Test Site. We show that the temperature and ionospheric electron density perturbation caused by an acoustic wave from underground nuclear explosion can reach 10% of background levels.

Coulomb explosion of the hot spot of micropinches

NASA Astrophysics Data System (ADS)

Oreshkin, V. I.; Oreshkin, E. V.

2017-01-01

It has been shown that the generation of hard X-ray radiation, electron beam, and high energy ions that have been detected in experiments on compressing pinches can be related to the Coulomb explosion of a micropinch hot spot, which is formed due to the outflow of the material. In the outflow process, the plasma temperature in the hot spot increases and conditions appear for the transition of electrons to the regime of continuous acceleration. The exit of runaway electrons from the hot spot region leads to the creation of a positive bulk charge, then to a Coulomb explosion. Conditions under which electrons pass to the continuous acceleration regime have been determined and estimates of the ion kinetic energy upon a Coulomb explosion have been obtained.

Isotopic anomalies from neutron reactions during explosive carbon burning

NASA Technical Reports Server (NTRS)

Lee, T.; Schramm, D. N.; Wefel, J. P.; Blake, J. B.

1978-01-01

The possibility that the newly discovered correlated isotopic anomalies for heavy elements in the Allende meteorite were synthesized in the secondary neutron capture episode during the explosive carbon burning, the possible source of the O-16 and Al-26 anomalies, is examined. Explosive carbon burning calculations under typical conditions were first performed to generate time profiles of temperature, density, and free particle concentrations. These quantities were inputted into a general neutron capture code which calculates the resulting isotopic pattern from exposing the preexisting heavy seed nuclei to these free particles during the explosive carbon burning conditions. The interpretation avoids the problem of the Sr isotopic data and may resolve the conflict between the time scales inferred from 1-129, Pu-244, and Al-26.

Widely tunable quantum cascade lasers for spectroscopic sensing

NASA Astrophysics Data System (ADS)

Wagner, J.; Ostendorf, R.; Grahmann, J.; Merten, A.; Hugger, S.; Jarvis, J.-P.; Fuchs, F.; Boskovic, D.; Schenk, H.

2015-01-01

In this paper recent advances in broadband-tuneable mid-infrared (MIR) external-cavity quantum cascade lasers (EC-QCL) technology are reported as well as their use in spectroscopic process analysis and imaging stand-off detection of hazardous substances, such as explosive and related precursors. First results are presented on rapid scan EC-QCL, employing a custom-made MOEMS scanning grating in Littrow-configuration as wavelength-selective optical feedback element. This way, a scanning rate of 1 kHz was achieved, which corresponds to 2000 full wavelength scans per second. Furthermore, exemplary case studies of EC-QCL based MIR spectroscopy will be presented. These include timeresolved analysis of catalytic reactions in chemical process control, as well as imaging backscattering spectroscopy for the detection of residues of explosives and related precursors in a relevant environment.

Imaging an Explosion with a 1000 Sensors: The SPE Large N Array

NASA Astrophysics Data System (ADS)

Mellors, R. J.; Snelson, C. M.; Pitarka, A.; Chen, T.; Matzel, E.; Walter, W. R.

2016-12-01

The Source Physics Experiment (SPE) is a series of heavily instrumented chemical explosions at the Nevada National Security Site (NNSS) designed to improve understanding of seismic wave generation and propagation from explosions. On April 26, 2016, a 5000 kg TNT equivalent chemical explosion (SPE5) was detonated at a depth of 76.5 meters (center) in a stemmed hole. The explosion was recorded by a temporary deployment of 1000 geophones with a variable spacing from 25 to 100 m and consisting of 500 vertical and 500 three-component 5 Hz geophones. Distance from ground zero to the geophones range from 400 to 3000 m. The shot is located in a weathered granite intrusive body surrounded by volcanic tuffs, Paleozoic carbonates, and alluvium. The purpose is to map the 3D waveform propagation with emphasis on the generation of S waves and to compare with synthetics. A focus is the transition from the granite to alluvium that occurs at a steeply dipping strike-slip fault. A secondary goal is to record ambient noise data for tomography. An active source experiment using a weight drop was also conducted. Data recovery was good, with approximately 95% of data recovered from the shot and up to 99% in the following weeks. In addition to the SPE5 shot, a variety of local earthquakes and teleseismic events were recorded. Prepared by LLNL under Contract DE-AC52-07NA27344.

Continuous-wave deep ultraviolet sources for resonance Raman explosive sensing

NASA Astrophysics Data System (ADS)

Yellampalle, Balakishore; Martin, Robert; Sluch, Mikhail; McCormick, William; Ice, Robert; Lemoff, Brian

2015-05-01

A promising approach to stand-off detection of explosive traces is using resonance Raman spectroscopy with Deepultraviolet (DUV) light. The DUV region offers two main advantages: strong explosive signatures due to resonant and λ- 4 enhancement of Raman cross-section, and lack of fluorescence and solar background. For DUV Raman spectroscopy, continuous-wave (CW) or quasi-CW lasers are preferable to high peak powered pulsed lasers because Raman saturation phenomena and sample damage can be avoided. In this work we present a very compact DUV source that produces greater than 1 mw of CW optical power. The source has high optical-to-optical conversion efficiency, greater than 5 %, as it is based on second harmonic generation (SHG) of a blue/green laser source using a nonlinear crystal placed in an external resonant enhancement cavity. The laser system is extremely compact, lightweight, and can be battery powered. Using two such sources, one each at 236.5 nm and 257.5 nm, we are building a second generation explosive detection system called Dual-Excitation-Wavelength Resonance-Raman Detector (DEWRRED-II). The DEWRRED-II system also includes a compact dual-band high throughput DUV spectrometer, and a highly-sensitive detection algorithm. The DEWRRED technique exploits the DUV excitation wavelength dependence of Raman signal strength, arising from complex interplay of resonant enhancement, self-absorption and laser penetration depth. We show sensor measurements from explosives/precursor materials at different standoff distances.

Divergence of Structure and Function in the Haloacid Dehalogenase Enzyme Superfamily: Bacteroides thetaiotaomicron BT2127 is an Inorganic Pyrophosphatase+

PubMed Central

Huang, Hua; Yury, Patskovsky; Toro, Rafael; Farelli, Jeremiah D.; Pandya, Chetanya; Almo, Steven C.; Allen, Karen N.; Dunaway-Mariano, Debra

2012-01-01

The explosion of protein sequence information requires that current strategies for function assignment must evolve to complement experimental approaches with computationally-based function prediction. This necessitates the development of strategies based on the identification of sequence markers in the form of specificity determinants and a more informed definition of orthologues. Herein, we have undertaken the function assignment of the unknown Haloalkanoate Dehalogenase superfamily member BT2127 (Uniprot accession # Q8A5V9) from Bacteroides thetaiotaomicron using an integrated bioinformatics/structure/mechanism approach. The substrate specificity profile and steady-state rate constants of BT2127 (with kcat/Km value for pyrophosphate of ∼1 × 105 M−1 s−1), together with the gene context, supports the assigned in vivo function as an inorganic pyrophosphatase. The X-ray structural analysis of the wild-type BT2127 and several variants generated by site-directed mutagenesis shows that substrate discrimination is based, in part, on active site space restrictions imposed by the cap domain (specifically by residues Tyr76 and Glu47). Structure guided site directed mutagenesis coupled with kinetic analysis of the mutant enzymes identified the residues required for catalysis, substrate binding, and domain-domain association. Based on this structure-function analysis, the catalytic residues Asp11, Asp13, Thr113, and Lys147 as well the metal binding residues Asp171, Asn172 and Glu47 were used as markers to confirm BT2127 orthologues identified via sequence searches. This bioinformatic analysis demonstrated that the biological range of BT2127 orthologue is restricted to the phylum Bacteroidetes/Chlorobi. The key structural determinants in the divergence of BT2127 and its closest homologue β-phosphoglucomutase control the leaving group size (phosphate vs. glucose-phosphate) and the position of the Asp acid/base in the open vs. closed conformations. HADSF pyrophosphatases represent a third mechanistic and fold type for bacterial pyrophosphatases. PMID:21894910

Dietary Exposure of Fathead Minnows to the Explosives TNT and RDX and to the Pesticide DDT using Contaminated Invertebrates

PubMed Central

Houston, Jerre G.; Lotufo, Guilherme R.

2005-01-01

Explosive compounds have been released into the environment during manufacturing, handling, and usage procedures. These compounds have been found to persist in the environment and potentially promote detrimental biological effects. The lack of research on bioaccumulation and bioconcentration and especially dietary transfer on aquatic life has resulted in challenges in assessing ecological risks. The objective of this study was to investigate the potential trophic transfer of the explosive compounds 2,4,6-trinitrotoluene (TNT) and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) using a realistic freshwater prey/predator model and using dichlorodiphenyltrichloroethane (DDT), a highly bioaccumulative compound, to establish relative dietary uptake potential. The oligochaete worm Lumbriculus variegatus was exposed to 14C-labeled TNT, RDX or DDT for 5 hours in water, frozen in meal-size packages and subsequently fed to individual juvenile fathead minnows (Pimephales promelas). Fish were sampled for body residue determination on days 1, 2, 3, 4, 7, and 14 following an 8-hour gut purging period. Extensive metabolism of the parent compound in worms occurred for TNT but not for RDX and DDT. Fish body residue remained relatively unchanged over time for TNT and RDX, but did not approach steady-state concentration for DDT during the exposure period. The bioaccumulation factor (concentration in fish relative to concentration in worms) was 0.018, 0.010, and 0.422 g/g for TNT, RDX and DDT, respectively, confirming the expected relatively low bioaccumulative potential for TNT and RDX through the dietary route. The experimental design was deemed successful in determining the potential for trophic transfer of organic contaminants via a realistic predator/prey exposure scenario. PMID:16705829

SN 2016coi/ASASSN-16fp: An example of residual helium in a type Ic supernova?

NASA Astrophysics Data System (ADS)

Prentice, S. J.; Ashall, C.; Mazzali, P. A.; Zhang, J.-J.; James, P. A.; Wang, X.-F.; Vinkó, J.; Percival, S.; Short, L.; Piascik, A.; Huang, F.; Mo, J.; Rui, L.-M.; Wang, J.-G.; Xiang, D.-F.; Xin, Y.-X.; Yi, W.-M.; Yu, X.-G.; Zhai, Q.; Zhang, T.-M.; Hosseinzadeh, G.; Howell, D. A.; McCully, C.; Valenti, S.; Cseh, B.; Hanyecz, O.; Kriskovics, L.; Pál, A.; Sárneczky, K.; Sódor, Á.; Szakáts, R.; Székely, P.; Varga-Verebélyi, E.; Vida, K.; Bradac, M.; Reichart, D. E.; Sand, D.; Tartaglia, L.

2018-05-01

The optical observations of Ic-4 supernova (SN) 2016coi/ASASSN-16fp, from ˜2 to ˜450 days after explosion, are presented along with analysis of its physical properties. The SN shows the broad lines associated with SNe Ic-3/4 but with a key difference. The early spectra display a strong absorption feature at ˜5400 Åwhich is not seen in other SNe Ic-3/4 at this epoch. This feature has been attributed to HeIin the literature. Spectral modelling of the SN in the early photospheric phase suggests the presence of residual He in a C/O dominated shell. However, the behaviour of the HeIlines is unusual when compared with He-rich SNe, showing relatively low velocities and weakening rather than strengthening over time. The SN is found to rise to peak ˜16 d after core-collapse reaching a bolometric luminosity of Lp ˜ 3 × 1042 erg s-1. Spectral models, including the nebular epoch, show that the SN ejected 2.5 - 4 M⊙of material, with ˜1.5 M⊙below 5000 km s-1, and with a kinetic energy of (4.5 - 7) × 1051 erg. The explosion synthesised ˜0.14 M⊙of 56Ni. There are significant uncertainties in E(B - V)host and the distance however, which will affect Lp and MNi. SN 2016coi exploded in a host similar to the Large Magellanic Cloud (LMC) and away from star-forming regions. The properties of the SN and the host-galaxy suggest that the progenitor had MZAMS of 23 - 28 M⊙and was stripped almost entirely down to its C/O core at explosion.

Significantly Improving Regional Seismic Amplitude Tomography at Higher Frequencies by Determining S -Wave Bandwidth

DOE PAGES

Fisk, Mark D.; Pasyanos, Michael E.

2016-05-03

Characterizing regional seismic signals continues to be a difficult problem due to their variability. Calibration of these signals is very important to many aspects of monitoring underground nuclear explosions, including detecting seismic signals, discriminating explosions from earthquakes, and reliably estimating magnitude and yield. Amplitude tomography, which simultaneously inverts for source, propagation, and site effects, is a leading method of calibrating these signals. A major issue in amplitude tomography is the data quality of the input amplitude measurements. Pre-event and prephase signal-to-noise ratio (SNR) tests are typically used but can frequently include bad signals and exclude good signals. The deficiencies ofmore » SNR criteria, which are demonstrated here, lead to large calibration errors. To ameliorate these issues, we introduce a semi-automated approach to assess the bandwidth of a spectrum where it behaves physically. We determine the maximum frequency (denoted as F max) where it deviates from this behavior due to inflections at which noise or spurious signals start to bias the spectra away from the expected decay. We compare two amplitude tomography runs using the SNR and new F max criteria and show significant improvements to the stability and accuracy of the tomography output for frequency bands higher than 2 Hz by using our assessments of valid S-wave bandwidth. We compare Q estimates, P/S residuals, and some detailed results to explain the improvements. Lastly, for frequency bands higher than 4 Hz, needed for effective P/S discrimination of explosions from earthquakes, the new bandwidth criteria sufficiently fix the instabilities and errors so that the residuals and calibration terms are useful for application.« less

Cover and startup gas supply system for solid oxide fuel cell generator

DOEpatents

Singh, P.; George, R.A.

1999-07-27

A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell. 4 figs.

Cover and startup gas supply system for solid oxide fuel cell generator

DOEpatents

Singh, Prabhakar; George, Raymond A.

1999-01-01

A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell.

Impact sensitivity test of liquid energetic materials

NASA Astrophysics Data System (ADS)

Tiutiaev, A.; Dolzhikov, A.; Zvereva, I.

2017-10-01

This paper presents new experimental method for sensitivity evaluation at the impact. A large number of researches shown that the probability of explosion initiating of liquid explosives by impact depends on the chemical nature and the various external characteristics. But the sensitivity of liquid explosive in the presence of gas bubbles increases many times as compared with the liquid without gas bubbles. In this case local chemical reaction focus are formed as a result of compression and heating of the gas inside the bubbles. In the liquid as a result of convection, wave motion, shock, etc. gas bubbles are easily generated, it is necessary to develop methods for determining sensitivity of liquid explosives to impact and to research the explosives ignition with bubbles. For the experimental investigation, the well-known impact machine and the so-called appliance 1 were used. Instead of the metal cup in the standard method in this paper polyurethane foam cylindrical container with liquid explosive was used. Polyurethane foam cylindrical container is easily deforms by impact. A large number of tests with different liquid explosives were made. It was found that the test liquid explosive to impact in appliance 1 with polyurethane foam to a large extent reflect the real mechanical sensitivity due to the small loss of impact energy on the deformation of the metal cup, as well as the best differentiation liquid explosive sensitivity due to the higher resolution method.

Understanding Laterally Varying Path Effects on P/S Ratios and their Effectiveness for Event Discrimination at Local Distances

NASA Astrophysics Data System (ADS)

Pyle, M. L.; Walter, W. R.

2017-12-01

Discrimination between underground explosions and naturally occurring earthquakes is an important endeavor for global security and test-ban treaty monitoring, and ratios of seismic P to S-wave amplitudes at regional distances have proven to be an effective discriminant. The use of the P/S ratio is rooted in the idea that explosive sources should theoretically only generate compressional energy. While, in practice, shear energy is observed from explosions, generally when corrections are made for magnitude and distance, P/S ratios from explosions are higher than those from surrounding earthquakes. At local distances (< 200 km) that might be needed to detect smaller events, however, this discriminant becomes less reliable. While ratios at some stations still show separation between earthquake and explosion populations, at other stations the populations are indistinguishable. There is no clear distance or azimuthal trend for which stations show discriminating abilities and which do not. A number of factors may play a role in differences we see between regional and local discrimination, including source effects such as depth and radiation pattern, and path effects such as laterally varying attenuation and focusing/defocusing from layers and scattering. We use data from the Source Physics Experiment (SPE) to investigate some of these effects. SPE is a series of chemical explosions at the Nevada National Security Site (NNSS) designed to improve our understanding and modeling capabilities of shear waves generated by explosions. Phase I consisted of 5 explosions in granite and Phase II will move to a contrasting dry alluvium geology. We apply a high-resolution 2D attenuation model to events near the NNSS to examine what effect path plays in local P/S ratios, and how well an earthquake-derived model can account for shallower explosion paths. The model incorporates both intrinsic attenuation and scattering effects and extends to 16 Hz, allowing us to make lateral path corrections and consider high-frequency ratios. Preliminary work suggests that while 2D path corrections modestly improve earthquake amplitude predictions, explosion amplitudes are not well matched, and so P/S ratios do not necessarily improve. Further work is needed to better understand the uses and limitation of 2D path corrections for local P/S ratios.

Calibrated vapor generator source

DOEpatents

Davies, J.P.; Larson, R.A.; Goodrich, L.D.; Hall, H.J.; Stoddard, B.D.; Davis, S.G.; Kaser, T.G.; Conrad, F.J.

1995-09-26

A portable vapor generator is disclosed that can provide a controlled source of chemical vapors, such as, narcotic or explosive vapors. This source can be used to test and calibrate various types of vapor detection systems by providing a known amount of vapors to the system. The vapor generator is calibrated using a reference ion mobility spectrometer. A method of providing this vapor is described, as follows: explosive or narcotic is deposited on quartz wool, placed in a chamber that can be heated or cooled (depending on the vapor pressure of the material) to control the concentration of vapors in the reservoir. A controlled flow of air is pulsed over the quartz wool releasing a preset quantity of vapors at the outlet. 10 figs.

GAP/CL-20-Based Compound Explosive: A New Booster Formulation Used in a Small-Sized Initiation Network

NASA Astrophysics Data System (ADS)

Yanju, Wei; Jingyu, Wang; Chongwei, An; Hequn, Li; Xiaomu, Wen; Binshuo, Yu

2017-01-01

With ε-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) and glycidyl azide polymer (GAP) as the solid filler and binder, respectively, GAP/CL-20-based compound explosives were designed and prepared. Using micro injection charge technology, the compound explosives were packed into small grooves to explore their application in a small-sized initiation network. The detonation reliability, detonation velocity, mechanical sensitivity, shock sensitivity, and brisance of the explosive were measured and analyzed. The results show that when the solid content of CL-20 is 82 wt%, the explosive charged in the groove has a smooth surface from a macroscopic view. From a microscopic view, a coarse surface is bonded with many CL-20 particles by GAP binder. The GAP/CL-20-based explosive charge successfully generates detonation waves in a groove larger than 0.6 mm × 0.6 mm. When the charge density in the groove is 1.68 g.cm-3 (90% theoretical maximum density), the detonation velocity reaches 7,290 m.s-1. Moreover, this kind of explosive is characterized by low impact and shock sensitivity.

The hydrodynamics of off-center explosions. [of supernovae

NASA Technical Reports Server (NTRS)

Fryxell, B. A.

1979-01-01

The behavior of off-center supernova explosions is investigated using a two-dimensional hydrodynamic code. An important application of these calculations is the possible formation of high-velocity pulsars. The dependence of the final velocity of the collapsed remnant on the location and energy of the explosion is computed. The largest remnant velocities result from explosions located at a mass fraction of 0.5. An explosion energy 50% greater than the binding energy of the star ejects 0.51 solar masses, producing a 1.4 solar mass remnant with a velocity of 400 km/s. However, this energy must be generated in a very small region of the star in order to create the required asymmetry in the explosion. Because of this, a specific energy of about 10 to the 20th ergs/g is needed. Nuclear reactions can produce no more than about 5 x 10 to the 17th erg/g, and it is unclear how the energy produced in gravitational collapse models can be sufficiently localized. Unless a supernova mechanism can be found which can produce enough energy in a small region of the star, off-center explosions do not provide a satisfactory explanation for high-velocity pulsars.

Bioethanol production: an integrated process of low substrate loading hydrolysis-high sugars liquid fermentation and solid state fermentation of enzymatic hydrolysis residue.

PubMed

Chu, Qiulu; Li, Xin; Ma, Bin; Xu, Yong; Ouyang, Jia; Zhu, Junjun; Yu, Shiyuan; Yong, Qiang

2012-11-01

An integrated process of enzymatic hydrolysis and fermentation was investigated for high ethanol production. The combination of enzymatic hydrolysis at low substrate loading, liquid fermentation of high sugars concentration and solid state fermentation of enzymatic hydrolysis residue was beneficial for conversion of steam explosion pretreated corn stover to ethanol. The results suggested that low substrate loading hydrolysis caused a high enzymatic hydrolysis yield; the liquid fermentation of about 200g/L glucose by Saccharomyces cerevisiae provided a high ethanol concentration which could significantly decrease cost of the subsequent ethanol distillation. A solid state fermentation of enzymatic hydrolysis residue was combined, which was available to enhance ethanol production and cellulose-to-ethanol conversion. The results of solid state fermentation demonstrated that the solid state fermentation process accompanied by simultaneous saccharification and fermentation. Copyright © 2012 Elsevier Ltd. All rights reserved.

Comparative analysis of the vapor headspace of military-grade TNT versus NESTT TNT under dynamic and static conditions

NASA Astrophysics Data System (ADS)

Edge, Cindy C.; Gibb, Julie; Wasserzug, Louis S.

1998-09-01

The Institute for Biological Detection Systems (IBDS) has developed a quantitative vapor delivery system that can aid in characterizing dog's sensitivity and ability to recognize odor signatures for explosives and contraband substances. Determining of the dog's odor signature for detection of explosives is important because it may aid in eliminating the risk of handling explosives and reducing cross-contamination. Progress is being made in the development of training aids that represent the headspace of the explosives. NESTTTM TNT materials have been proposed as an approach to developing training aid simulates. In order for such aids to be effective they must mimic the headspace of the target material. This study evaluates the NESTTTM TNT product with regard to this criterion. NESTTTM TNT vapor was generated by the IBDS vapor delivery system, which incorporates a vapor generation cell that enables the user to control the conditions under which a substance is tested. The NESTTTM TNT vapor was compared to the headspace of military-grade TNT. The findings identify and quantify major vapor constituents of military-grade TNT and NESTTTM TNT. A comparative analysis evaluated the degree to which the NESTTTM TNT mimics the headspace of an actual TNT sample.

Microshell-tipped optical fibers as sensors of high-pressure pulses in adverse environments

DOE Office of Scientific and Technical Information (OSTI.GOV)

Benjamin, R.F.; Mayer, F.J.; Maynard, R.L.

1984-01-01

An optical-fiber sensor for detecting the arrival of strong pressure pulses was developed. The sensor consists of an optical fiber, tipped with a gas-filled microballoon. They have been used successfully in adverse environments including explosives, ballistics and electromagnetic pulses (EMP). The sensor produces a bright optical pulse caused by the rapid shock-heating of a gas, typically argon or xenon, which is confined in the spherical glass or plastic microballoon. The light pulse is transmitted via the optical fiber to a photo detector, usually a streak camera or photomultiplier tube. The microballoon optical sensor (called an optical pin by analogy tomore » standard electrical pins), was originally developed for diagnosing an explosive, pulsed-power generator. Optical pins are required due to the EMP. The optical pins are economical arrival-time indicators because many channels can be recorded by one streak camera. The generator tests and related experiments, involving projectile velocities and detonation velocities of several kilometers per sec have demonstrated the usefulness of the sensors in explosives and ballistics applications. The technical and cost advantages of this optical pin make it potentially useful for many electromagnetic, explosive, and ballistics applications.« less

Modelling infrasound signal generation from two underground explosions at the Source Physics Experiment using the Rayleigh integral

DOE Office of Scientific and Technical Information (OSTI.GOV)

Jones, Kyle R.; Whitaker, Rodney W.; Arrowsmith, Stephen J.

2014-12-11

For this study, we use the Rayleigh integral (RI) as an approximation to the Helmholtz–Kirchoff integral to model infrasound generation and propagation from underground chemical explosions at distances of 250 m out to 5 km as part of the Source Physics Experiment (SPE). Using a sparse network of surface accelerometers installed above ground zero, we are able to accurately create synthetic acoustic waveforms and compare them to the observed data. Although the underground explosive sources were designed to be symmetric, the resulting seismic wave at the surface shows an asymmetric propagation pattern that is stronger to the northeast of themore » borehole. This asymmetric bias may be attributed to the subsurface geology and faulting of the area and is observed in the acoustic waveforms. We compare observed and modelled results from two of the underground SPE tests with a sensitivity study to evaluate the asymmetry observed in the data. This work shows that it is possible to model infrasound signals from underground explosive sources using the RI and that asymmetries observed in the data can be modelled with this technique.« less

Explosive shaped charge penetration into tuff rock

DOE Office of Scientific and Technical Information (OSTI.GOV)

Vigil, M.G.

1988-10-01

Analysis and data for the use of Explosive Shaped Charges (ESC) to generate holes in tuff rock formation is presented. The ESCs evaluated include Conical Shaped Charges (CSC) and Explosive Formed Projectiles (EFP). The CSCs vary in size from 0.158 to 9.1 inches inside cone diameter. The EFPs were 5.0 inches in diameter. Data for projectile impact angles of 30 and 90 degrees are presented. Analytically predicted depth of penetration data generally compared favorably with experimental data. Predicted depth of penetration versus ESC standoff data and hole profile dimensions in tuff are also presented. 24 refs., 45 figs., 6 tabs.

Two-Phase Model of Combustion in Explosions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kuhl, A L; Khasainov, B; Bell, J

2006-06-19

A two-phase model for Aluminum particle combustion in explosions is proposed. It combines the gas-dynamic conservation laws for the gas phase with the continuum mechanics laws of multi-phase media, as formulated by Nigmatulin. Inter-phase mass, momentum and energy exchange are prescribed by the Khasainov model. Combustion is specified as material transformations in the Le Chatelier diagram which depicts the locus of thermodynamic states in the internal energy-temperature plane according to Kuhl. Numerical simulations are used to show the evolution of two-phase combustion fields generated by the explosive dissemination of a powdered Al fuel.

Application of a catalytic combustion sensor (Pellistor) for the monitoring of the explosiveness of a hydrogen-air mixture in the upper explosive limit range

PubMed Central

Krawczyk, M.; Namiesnik, J.

2003-01-01

A new technique is presented for continuous measurements of hydrogen contamination by air in the upper explosive limit range. It is based on the application of a catalytic combustion sensor placed in a cell through which the tested sample passes. The air content is the function of the quantity of formed heat during catalytic combustion of hydrogen inside the sensor. There is the possibility of using the method in industrial installations by using hydrogen for cooling electric current generators. PMID:18924620

Ethanol production potential from AFEX™ and steam-exploded sugarcane residues for sugarcane biorefineries.

PubMed

Mokomele, Thapelo; da Costa Sousa, Leonardo; Balan, Venkatesh; van Rensburg, Eugéne; Dale, Bruce E; Görgens, Johann F

2018-01-01

Expanding biofuel markets are challenged by the need to meet future biofuel demands and mitigate greenhouse gas emissions, while using domestically available feedstock sustainably. In the context of the sugar industry, exploiting under-utilized cane leaf matter (CLM) in addition to surplus sugarcane bagasse as supplementary feedstock for second-generation ethanol production has the potential to improve bioenergy yields per unit land. In this study, the ethanol yields and processing bottlenecks of ammonia fibre expansion (AFEX™) and steam explosion (StEx) as adopted technologies for pretreating sugarcane bagasse and CLM were experimentally measured and compared for the first time. Ethanol yields between 249 and 256 kg Mg -1 raw dry biomass (RDM) were obtained with AFEX™-pretreated sugarcane bagasse and CLM after high solids loading enzymatic hydrolysis and fermentation. In contrast, StEx-pretreated sugarcane bagasse and CLM resulted in substantially lower ethanol yields that ranged between 162 and 203 kg Mg -1 RDM. The ethanol yields from StEx-treated sugarcane residues were limited by the aggregated effect of sugar degradation during pretreatment, enzyme inhibition during enzymatic hydrolysis and microbial inhibition of S. cerevisiae 424A (LNH-ST) during fermentation. However, relatively high enzyme dosages (> 20 mg g -1 glucan) were required irrespective of pretreatment method to reach 75% carbohydrate conversion, even when optimal combinations of Cellic ® CTec3, Cellic ® HTec3 and Pectinex Ultra-SP were used. Ethanol yields per hectare sugarcane cultivation area were estimated at 4496 and 3416 L ha -1 for biorefineries using AFEX™- or StEx-treated sugarcane residues, respectively. AFEX™ proved to be a more effective pretreatment method for sugarcane residues relative to StEx due to the higher fermentable sugar recovery and enzymatic hydrolysate fermentability after high solids loading enzymatic hydrolysis and fermentation by S. cerevisiae 424A (LNH-ST). The identification of auxiliary enzyme activities, adequate process integration and the use of robust xylose-fermenting ethanologens were identified as opportunities to further improve ethanol yields from AFEX™- and StEx-treated sugarcane residues.

Theoretical analysis of tsunami generation by pyroclastic flows

USGS Publications Warehouse

Watts, P.; Waythomas, C.F.

2003-01-01

Pyroclastic flows are a common product of explosive volcanism and have the potential to initiate tsunamis whenever thick, dense flows encounter bodies of water. We evaluate the process of tsunami generation by pyroclastic flow by decomposing the pyroclastic flow into two components, the dense underflow portion, which we term the pyroclastic debris flow, and the plume, which includes the surge and coignimbrite ash cloud parts of the flow. We consider five possible wave generation mechanisms. These mechanisms consist of steam explosion, pyroclastic debris flow, plume pressure, plume shear, and pressure impulse wave generation. Our theoretical analysis of tsunami generation by these mechanisms provides an estimate of tsunami features such as a characteristic wave amplitude and wavelength. We find that in most situations, tsunami generation is dominated by the pyroclastic debris flow component of a pyroclastic flow. This work presents information sufficient to construct tsunami sources for an arbitrary pyroclastic flow interacting with most bodies of water. Copyright 2003 by the American Geophysical Union.

Source Region Modeling of Explosions 2 and 3 from the Source Physics Experiment Using the Rayleigh Integral Method

NASA Astrophysics Data System (ADS)

Jones, K. R.; Arrowsmith, S.; Whitaker, R. W.

2012-12-01

The overall mission of the National Center for Nuclear Security (NCNS) Source Physics Experiment at the National Nuclear Security Site (SPE-N) near Las Vegas, Nevada is to improve upon and develop new physics based models for underground nuclear explosions using scaled, underground chemical explosions as proxies. To this end, we use the Rayleigh integral as an approximation to the Helmholz-Kirchoff integral, [Whitaker, 2007 and Arrowsmith et al., 2011], to model infrasound generation in the far-field. Infrasound generated by single-point explosive sources above ground can typically be treated as monopole point-sources. While the source is relatively simple, the research needed to model above ground point-sources is complicated by path effects related to the propagation of the acoustic signal and out of the scope of this study. In contrast, for explosions that occur below ground, including the SPE explosions, the source region is more complicated but the observation distances are much closer (< 5 km), thus greatly reducing the complication of path effects. In this case, elastic energy from the explosions radiates upward and spreads out, depending on depth, to a more distributed region at the surface. Due to this broad surface perturbation of the atmosphere we cannot model the source as a simple monopole point-source. Instead, we use the analogy of a piston mounted in a rigid, infinite baffle, where the surface area that moves as a result of the explosion is the piston and the surrounding region is the baffle. The area of the "piston" is determined by the depth and explosive yield of the event. In this study we look at data from SPE-N-2 and SPE-N-3. Both shots had an explosive yield of 1 ton at a depth of 45 m. We collected infrasound data with up to eight stations and 32 sensors within a 5 km radius of ground zero. To determine the area of the surface acceleration, we used data from twelve surface accelerometers installed within 100 m radially about ground zero. With the accelerometer data defining the vertical motion of the surface, we use the Rayleigh Integral Method, [Whitaker, 2007 and Arrowsmith et al., 2011], to generate a synthetic infrasound pulse to compare to the observed data. Because the phase across the "piston" is not necessarily uniform, constructive and destructive interference will change the shape of the acoustic pulse if observed directly above the source (on-axis) or perpendicular to the source (off-axis). Comparing the observed data to the synthetic data we note that the overall structure of the pulse agrees well and that the differences can be attributed to a number of possibilities, including the sensors used, topography, meteorological conditions, etc. One other potential source of error between the observed and calculated data is that we use a flat, symmetric source region for the "piston" where in reality the source region is not flat and not perfectly symmetric. A primary goal of this work is to better understand and model the relationships between surface area, depth, and yield of underground explosions.

A Physical Basis for M s-Yield Scaling in Hard Rock and Implications for Late-Time Damage of the Source Medium

DOE PAGES

Patton, Howard John

2016-04-11

Surface wave magnitude M s for a compilation of 72 nuclear tests detonated in hard rock media for which yields and burial depths have been reported in the literature is shown to scale with yield W as a + b × log[W], where a = 2.50 ± 0.08 and b = 0.80 ± 0.05. While the exponent b is consistent with an M s scaling model for fully coupled, normal containment-depth explosions, the intercept a is offset 0.45 magnitude units lower than the model. The cause of offset is important to understand in terms of the explosion source. Hard rockmore » explosions conducted in extensional and compressional stress regimes show similar offsets, an indication that the tectonic setting in which an explosion occurs plays no role causing the offset. The scaling model accounts for the effects of source medium material properties on the generation of 20-s period Rayleigh wave amplitudes. Aided by thorough characterizations of the explosion and tectonic release sources, an extensive analysis of the 1963 October 26 Shoal nuclear test detonated in granite 27 miles southeast of Fallon NV shows that the offset is consistent with the predictions of a material damage source model related to non-linear stress wave interactions with the free surface. This source emits Rayleigh waves with polarity opposite to waves emitted by the explosion. The Shoal results were extended to analyse surface waves from the 1962 February 15 Hardhat nuclear test, the 1988 September 14 Soviet Joint Verification Experiment, and the anomalous 1979 August 18 northeast Balapan explosion which exhibits opposite polarity, azimuth-independent source component U1 compared to an explosion. Modelling these tests shows that Rayleigh wave amplitudes generated by the damage source are nearly as large as or larger than amplitudes from the explosion. As such, destructive interference can be drastic, introducing metastable conditions due to the sensitivity of reduced amplitudes to Rayleigh wave initial phase angles of the explosion and damage sources. This meta-stability is a likely source of scatter in M s-yield scaling observations. The agreement of observed scaling exponent b with the model suggests that the damage source strength does not vary much with yield, in contrast to explosions conducted in weak media where Ms scaling rates are greater than the model predicts, and the yield dependence of the damage source strength is significant. This difference in scaling behaviour is a consequence of source medium material properties.« less

A Physical Basis for M s-Yield Scaling in Hard Rock and Implications for Late-Time Damage of the Source Medium

DOE Office of Scientific and Technical Information (OSTI.GOV)

Patton, Howard John

Surface wave magnitude M s for a compilation of 72 nuclear tests detonated in hard rock media for which yields and burial depths have been reported in the literature is shown to scale with yield W as a + b × log[W], where a = 2.50 ± 0.08 and b = 0.80 ± 0.05. While the exponent b is consistent with an M s scaling model for fully coupled, normal containment-depth explosions, the intercept a is offset 0.45 magnitude units lower than the model. The cause of offset is important to understand in terms of the explosion source. Hard rockmore » explosions conducted in extensional and compressional stress regimes show similar offsets, an indication that the tectonic setting in which an explosion occurs plays no role causing the offset. The scaling model accounts for the effects of source medium material properties on the generation of 20-s period Rayleigh wave amplitudes. Aided by thorough characterizations of the explosion and tectonic release sources, an extensive analysis of the 1963 October 26 Shoal nuclear test detonated in granite 27 miles southeast of Fallon NV shows that the offset is consistent with the predictions of a material damage source model related to non-linear stress wave interactions with the free surface. This source emits Rayleigh waves with polarity opposite to waves emitted by the explosion. The Shoal results were extended to analyse surface waves from the 1962 February 15 Hardhat nuclear test, the 1988 September 14 Soviet Joint Verification Experiment, and the anomalous 1979 August 18 northeast Balapan explosion which exhibits opposite polarity, azimuth-independent source component U1 compared to an explosion. Modelling these tests shows that Rayleigh wave amplitudes generated by the damage source are nearly as large as or larger than amplitudes from the explosion. As such, destructive interference can be drastic, introducing metastable conditions due to the sensitivity of reduced amplitudes to Rayleigh wave initial phase angles of the explosion and damage sources. This meta-stability is a likely source of scatter in M s-yield scaling observations. The agreement of observed scaling exponent b with the model suggests that the damage source strength does not vary much with yield, in contrast to explosions conducted in weak media where Ms scaling rates are greater than the model predicts, and the yield dependence of the damage source strength is significant. This difference in scaling behaviour is a consequence of source medium material properties.« less

Computing Q-D Relationships for Storage of Rocket Fuels

NASA Technical Reports Server (NTRS)

Jester, Keith

2005-01-01

The Quantity Distance Measurement Tool is a GIS BASEP computer program that aids safety engineers by calculating quantity-distance (Q-D) relationships for vessels that contain explosive chemicals used in testing rocket engines. (Q-D relationships are standard relationships between specified quantities of specified explosive materials and minimum distances by which they must be separated from persons, objects, and other explosives to obtain specified types and degrees of protection.) The program uses customized geographic-information-system (GIS) software and calculates Q-D relationships in accordance with NASA's Safety Standard For Explosives, Propellants, and Pyrotechnics. Displays generated by the program enable the identification of hazards, showing the relationships of propellant-storage-vessel safety buffers to inhabited facilities and public roads. Current Q-D information is calculated and maintained in graphical form for all vessels that contain propellants or other chemicals, the explosiveness of which is expressed in TNT equivalents [amounts of trinitrotoluene (TNT) having equivalent explosive effects]. The program is useful in the acquisition, siting, construction, and/or modification of storage vessels and other facilities in the development of an improved test-facility safety program.

Ultrafast Laser Interaction Processes for Libs and Other Sensing Technologies

DTIC Science & Technology

2013-04-05

Wang. Propagation of ultrashort pulses through water, Optics Express, (02 2007): . doi: 12/02/2009 8.00 Z. Chen, S. Mao. Femtosecond laser -induced...Richardson, "Nd:YAG-CO2 double- pulse laser -induced breakdown spectroscopy for explosive residues detection" SPIE Defense, Security, Sensing; Orlando, FL... Ultrashort Pulse Laser Workshop, Directed Energy Professional Society; Newton, MA, USA; 06/29,2009. 63. Martin C. Richardson, Michael Sigman

Path-Specific Effects on Shear Motion Generation Using LargeN Array Waveform Data at the Source Physics Experiment (SPE) Site

NASA Astrophysics Data System (ADS)

Pitarka, A.; Mellors, R. J.; Walter, W. R.

2016-12-01

Depending on emplacement conditions and underground structure, and contrary to what is theoretically predicted for isotropic sources, recorded local, regional, and teleseismic waveforms from chemical explosions often contain shear waves with substantial energy. Consequently, the transportability of empirical techniques for yield estimation and source discrimination to regions with complex underground structure becomes problematic. Understanding the mechanisms of generation and conversion of shear waves caused by wave path effects during explosions can help improve techniques used in nuclear explosion monitoring. We used seismic data from LargeN, a dense array of three and one component geophones, to analyze far-field waveforms from the underground chemical explosion recorded during shot 5 of the Source Physics Experiment (SPE-5) at the Nevada National Security Site. Combined 3D elastic wave propagation modeling and frequency-wavenumber beam-forming on small arrays containing selected stations were used to detect and identify several wave phases, including primary and secondary S waves, and Rgwaves, and determine their direction of propagation. We were able to attribute key features of the waveforms, and wave phases to either source processes or propagation path effects, such as focusing and wave conversions. We also found that coda waves were more likely generated by path effects outside the source region, rather than by interaction of source generated waves with the emplacement structure. Waveform correlation and statistical analysis were performed to estimate average correlation length of small-scale heterogeneity in the upper sedimentary layers of the Yucca Flat basin in the area covered by the array. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. LLNL-ABS- 699180

Advanced shortwave infrared and Raman hyperspectral sensors for homeland security and law enforcement operations

NASA Astrophysics Data System (ADS)

Klueva, Oksana; Nelson, Matthew P.; Gardner, Charles W.; Gomer, Nathaniel R.

2015-05-01

Proliferation of chemical and explosive threats as well as illicit drugs continues to be an escalating danger to civilian and military personnel. Conventional means of detecting and identifying hazardous materials often require the use of reagents and/or physical sampling, which is a time-consuming, costly and often dangerous process. Stand-off detection allows the operator to detect threat residues from a safer distance minimizing danger to people and equipment. Current fielded technologies for standoff detection of chemical and explosive threats are challenged by low area search rates, poor targeting efficiency, lack of sensitivity and specificity or use of costly and potentially unsafe equipment such as lasers. A demand exists for stand-off systems that are fast, safe, reliable and user-friendly. To address this need, ChemImage Sensor Systems™ (CISS) has developed reagent-less, non-contact, non-destructive sensors for the real-time detection of hazardous materials based on widefield shortwave infrared (SWIR) and Raman hyperspectral imaging (HSI). Hyperspectral imaging enables automated target detection displayed in the form of image making result analysis intuitive and user-friendly. Application of the CISS' SWIR-HSI and Raman sensing technologies to Homeland Security and Law Enforcement for standoff detection of homemade explosives and illicit drugs and their precursors in vehicle and personnel checkpoints is discussed. Sensing technologies include a portable, robot-mounted and standalone variants of the technology. Test data is shown that supports the use of SWIR and Raman HSI for explosive and drug screening at checkpoints as well as screening for explosives and drugs at suspected clandestine manufacturing facilities.

Pulsating aurora induced by upper atmospheric barium releases

NASA Technical Reports Server (NTRS)

Deehr, C.; Romick, G.

1977-01-01

The paper reports the apparent generation of pulsating aurora by explosive releases of barium vapor near 250 km altitude. This effect occurred only when the explosions were in the path of precipitating electrons associated with the visible aurora. Each explosive charge was a standard 1.5 kg thermite mixture of Ba and CuO with an excess of Ba metal which was vaporized and dispersed by the thermite explosion. Traces of Sr, Na, and Li were added to some of the charges, and monitoring was achieved by ground-based spectrophotometric observations. On March 28, 1976, an increase in emission at 5577 A and at 4278 A was observed in association with the first two bursts, these emissions pulsating with roughly a 10 sec period for approximately 60 to 100 sec after the burst.

Analysis of Ground Motion from An Underground Chemical Explosion

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pitarka, Arben; Mellors, Robert J.; Walter, William R.

Here in this paper we investigate the excitation and propagation of far-field seismic waves from the 905 kg trinitrotoluene equivalent underground chemical explosion SPE-3 recorded during the Source Physics Experiment (SPE) at the Nevada National Security Site. The recorded far-field ground motion at short and long distances is characterized by substantial shear-wave energy, and large azimuthal variations in P-and S-wave amplitudes. The shear waves observed on the transverse component of sensors at epicentral distances <50 m suggests they were generated at or very near the source. The relative amplitude of the shear waves grows as the waves propagate away frommore » the source. We analyze and model the shear-wave excitation during the explosion in the 0.01–10 Hz frequency range, at epicentral distances of up to 1 km. We used two simulation techniques. One is based on the empirical isotropic Mueller–Murphy (MM) (Mueller and Murphy, 1971) nuclear explosion source model, and 3D anelastic wave propagation modeling. The second uses a physics-based approach that couples hydrodynamic modeling of the chemical explosion source with anelastic wave propagation modeling. Comparisons with recorded data show the MM source model overestimates the SPE-3 far-field ground motion by an average factor of 4. The observations show that shear waves with substantial high-frequency energy were generated at the source. However, to match the observations additional shear waves from scattering, including surface topography, and heterogeneous shallow structure contributed to the amplification of far-field shear motion. Comparisons between empirically based isotropic and physics-based anisotropic source models suggest that both wave-scattering effects and near-field nonlinear effects are needed to explain the amplitude and irregular radiation pattern of shear motion observed during the SPE-3 explosion.« less

Analysis of Ground Motion from An Underground Chemical Explosion

DOE PAGES

Pitarka, Arben; Mellors, Robert J.; Walter, William R.; ...

2015-09-08

Here in this paper we investigate the excitation and propagation of far-field seismic waves from the 905 kg trinitrotoluene equivalent underground chemical explosion SPE-3 recorded during the Source Physics Experiment (SPE) at the Nevada National Security Site. The recorded far-field ground motion at short and long distances is characterized by substantial shear-wave energy, and large azimuthal variations in P-and S-wave amplitudes. The shear waves observed on the transverse component of sensors at epicentral distances <50 m suggests they were generated at or very near the source. The relative amplitude of the shear waves grows as the waves propagate away frommore » the source. We analyze and model the shear-wave excitation during the explosion in the 0.01–10 Hz frequency range, at epicentral distances of up to 1 km. We used two simulation techniques. One is based on the empirical isotropic Mueller–Murphy (MM) (Mueller and Murphy, 1971) nuclear explosion source model, and 3D anelastic wave propagation modeling. The second uses a physics-based approach that couples hydrodynamic modeling of the chemical explosion source with anelastic wave propagation modeling. Comparisons with recorded data show the MM source model overestimates the SPE-3 far-field ground motion by an average factor of 4. The observations show that shear waves with substantial high-frequency energy were generated at the source. However, to match the observations additional shear waves from scattering, including surface topography, and heterogeneous shallow structure contributed to the amplification of far-field shear motion. Comparisons between empirically based isotropic and physics-based anisotropic source models suggest that both wave-scattering effects and near-field nonlinear effects are needed to explain the amplitude and irregular radiation pattern of shear motion observed during the SPE-3 explosion.« less

High explosive corner turning performance and the LANL mushroom test

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hill, L.G.; Seitz, W.L.; Forest, C.A.

1998-07-01

The Mushroom test is designed to characterize the corner turning performance of a new generation of less sensitive booster explosives. The test is described in detail, and three corner turning figures-of-merit are examined using pure TATB (both Livermore{close_quote}s Ultrafine and a Los Alamos research blend) and PBX9504 as examples. {copyright} {ital 1998 American Institute of Physics.}

Note: The full function test explosive generator.

PubMed

Reisman, D B; Javedani, J B; Griffith, L V; Ellsworth, G F; Kuklo, R M; Goerz, D A; White, A D; Tallerico, L J; Gidding, D A; Murphy, M J; Chase, J B

2010-03-01

We have conducted three tests of a new pulsed power device called the full function test. These tests represented the culmination of an effort to establish a high energy pulsed power capability based on high explosive pulsed power (HEPP) technology. This involved an extensive computational modeling, engineering, fabrication, and fielding effort. The experiments were highly successful and a new U.S. record for magnetic energy was obtained.

The 1883 eruption of Krakatau

NASA Technical Reports Server (NTRS)

Self, S.; Rampino, M. R.

1981-01-01

The 1883 eruption of Krakatau was a modest ignimbrite-forming event. The deposits are primarily coarse-grained dacitic, non-welded ignimbrite. Large explosions produced pyroclastic flows that entered the sea, generating destructive tsunami. Grain-size studies of the ignimbrite suggest that these explosions were not driven by magma-seawater interaction. The total bulk volume of pyroclastic deposits, including co-ignimbrite ash, is estimated to be 18-21 cu km.

Finite-Difference Modeling of Seismic Wave Scattering in 3D Heterogeneous Media: Generation of Tangential Motion from an Explosion Source

NASA Astrophysics Data System (ADS)

Hirakawa, E. T.; Pitarka, A.; Mellors, R. J.

2015-12-01

Evan Hirakawa, Arben Pitarka, and Robert Mellors One challenging task in explosion seismology is development of physical models for explaining the generation of S-waves during underground explosions. Pitarka et al. (2015) used finite difference simulations of SPE-3 (part of Source Physics Experiment, SPE, an ongoing series of underground chemical explosions at the Nevada National Security Site) and found that while a large component of shear motion was generated directly at the source, additional scattering from heterogeneous velocity structure and topography are necessary to better match the data. Large-scale features in the velocity model used in the SPE simulations are well constrained, however, small-scale heterogeneity is poorly constrained. In our study we used a stochastic representation of small-scale variability in order to produce additional high-frequency scattering. Two methods for generating the distributions of random scatterers are tested. The first is done in the spatial domain by essentially smoothing a set of random numbers over an ellipsoidal volume using a Gaussian weighting function. The second method consists of filtering a set of random numbers in the wavenumber domain to obtain a set of heterogeneities with a desired statistical distribution (Frankel and Clayton, 1986). This method is capable of generating distributions with either Gaussian or von Karman autocorrelation functions. The key parameters that affect scattering are the correlation length, the standard deviation of velocity for the heterogeneities, and the Hurst exponent, which is only present in the von Karman media. Overall, we find that shorter correlation lengths as well as higher standard deviations result in increased tangential motion in the frequency band of interest (0 - 10 Hz). This occurs partially through S-wave refraction, but mostly by P-S and Rg-S waves conversions. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344

Contraction type influences the human ability to use the available torque capacity of skeletal muscle during explosive efforts

PubMed Central

Tillin, Neale A.; Pain, Matthew T. G.; Folland, Jonathan P.

2012-01-01

The influence of contraction type on the human ability to use the torque capacity of skeletal muscle during explosive efforts has not been documented. Fourteen male participants completed explosive voluntary contractions of the knee extensors in four separate conditions: concentric (CON) and eccentric (ECC); and isometric at two knee angles (101°, ISO101 and 155°, ISO155). In each condition, torque was measured at 25 ms intervals up to 150 ms from torque onset, and then normalized to the maximum voluntary torque (MVT) specific to that joint angle and angular velocity. Explosive voluntary torque after 50 ms in each condition was also expressed as a percentage of torque generated after 50 ms during a supramaximal 300 Hz electrically evoked octet in the same condition. Explosive voluntary torque normalized to MVT was more than 60 per cent larger in CON than any other condition after the initial 25 ms. The percentage of evoked torque expressed after 50 ms of the explosive voluntary contractions was also greatest in CON (ANOVA; p < 0.001), suggesting higher concentric volitional activation. This was confirmed by greater agonist electromyography normalized to Mmax (recorded during the explosive voluntary contractions) in CON. These results provide novel evidence that the ability to use the muscle's torque capacity explosively is influenced by contraction type, with concentric contractions being more conducive to explosive performance due to a more effective neural strategy. PMID:22258636

On the generation of horizontal shear waves by underground explosions in jointed rocks

DOE PAGES

Vorobiev, Oleg; Ezzedine, Souheil; Antoun, Tarabay; ...

2015-02-04

This paper describes computational studies of non-spherical ground motions generated by spherical explosions in a heavily jointed granite formation. Various factors affecting the shear wave generation are considered, including joint spacing, orientation, persistence and properties. Simulations are performed both in 2D for a single joint set to elucidate the basic response mechanisms, and in 3D for multiple joint sets to realistically represent in situ conditions in a realistic geologic setting. The joints are modeled explicitly using both contact elements and weakness planes in the material. Simulations are performed both deterministically and stochastically to quantify the effects of geologic uncertainties onmore » near field ground motions. The mechanical properties of the rock and the joints as well as the joint spacing and orientation are taken from experimental test data and geophysical logs corresponding to the Climax Stock granitic outcrop, which is the geologic setting of the Source Physics Experiment (SPE). Agreement between simulation results and near field wave motion data from SPE enables newfound understanding of the origin and extent of non-spherical motions associated with underground explosions in fractured geologic media.« less

Elastic parabolic equation solutions for underwater acoustic problems using seismic sources.

PubMed

Frank, Scott D; Odom, Robert I; Collis, Jon M

2013-03-01

Several problems of current interest involve elastic bottom range-dependent ocean environments with buried or earthquake-type sources, specifically oceanic T-wave propagation studies and interface wave related analyses. Additionally, observed deep shadow-zone arrivals are not predicted by ray theoretic methods, and attempts to model them with fluid-bottom parabolic equation solutions suggest that it may be necessary to account for elastic bottom interactions. In order to study energy conversion between elastic and acoustic waves, current elastic parabolic equation solutions must be modified to allow for seismic starting fields for underwater acoustic propagation environments. Two types of elastic self-starter are presented. An explosive-type source is implemented using a compressional self-starter and the resulting acoustic field is consistent with benchmark solutions. A shear wave self-starter is implemented and shown to generate transmission loss levels consistent with the explosive source. Source fields can be combined to generate starting fields for source types such as explosions, earthquakes, or pile driving. Examples demonstrate the use of source fields for shallow sources or deep ocean-bottom earthquake sources, where down slope conversion, a known T-wave generation mechanism, is modeled. Self-starters are interpreted in the context of the seismic moment tensor.

A study of transient flow turbulence generation during flame/wall interactions in explosions

NASA Astrophysics Data System (ADS)

Hargrave, G. K.; Jarvis, S.; Williams, T. C.

2002-07-01

Experimental data are presented for the turbulent velocity field generated during flame/solid wall interactions in explosions. The presence of turbulence in a flammable gas mixture can wrinkle a flame front, increasing the flame surface area and enhancing the burning rate. In congested process plant, any flame propagating through an accidental release of flammable mixture will encounter obstructions in the form of walls, pipe-work or storage vessels. The interaction between the gas movement and the obstacle creates turbulence by vortex shedding and local wake/recirculation, whereby the flame can be wrapped in on itself, increasing the surface area available for combustion. Particle image velocimetry (PIV) was used to characterize the turbulent flow field in the wake of the obstacles placed in the path of propagating flames. This allowed the quantification of the interaction of the propagating flame and the generated turbulent flow field. Due to the accelerating nature of the explosion flow field, the wake flows develop `transient' turbulent fields and PIV provided data to define the spatial and temporal variation of the velocity field ahead of the propagating flame, providing an understanding of the direct interaction between flow and flame.

Continuous flow, explosives vapor generator and sensor chamber.

PubMed

Collins, Greg E; Giordano, Braden C; Sivaprakasam, Vasanthi; Ananth, Ramagopal; Hammond, Mark; Merritt, Charles D; Tucker, John E; Malito, Michael; Eversole, Jay D; Rose-Pehrsson, Susan

2014-05-01

A novel liquid injection vapor generator (LIVG) is demonstrated that is amenable to low vapor pressure explosives, 2,4,6-trinitrotoluene and hexahydro-1,3,5-trinitro-1,3,5-triazine. The LIVG operates in a continuous manner, providing a constant and stable vapor output over a period of days and whose concentration can be extended over as much as three orders of magnitude. In addition, a large test atmosphere chamber attached to the LIVG is described, which enables the generation of a stable test atmosphere with controllable humidity and temperature. The size of the chamber allows for the complete insertion of testing instruments or arrays of materials into a uniform test atmosphere, and various electrical feedthroughs, insertion ports, and sealed doors permit simple and effective access to the sample chamber and its vapor.

Feasibility of culvert IED detection using thermal neutron activation

NASA Astrophysics Data System (ADS)

Faust, Anthony A.; McFee, John E.; Clifford, Edward T. H.; Andrews, Hugh Robert; Mosquera, Cristian; Roberts, William C.

2012-06-01

Bulk explosives hidden in culverts pose a serious threat to the Canadian and allied armies. Culverts provide an opportunity to conceal insurgent activity, avoid the need for detectable surface disturbances, and limit the applicability of conventional sub-surface sensing techniques. Further, in spite of the large masses of explosives that can be employed, the large sensor{target separation makes detection of the bulk explosive content challeng- ing. Defence R&D Canada { Sueld and Bubble Technology Industries have been developing thermal neutron activation (TNA) sensors for detection of buried bulk explosives for over 15 years. The next generation TNA sensor, known as TNA2, incorporates a number of improvements that allow for increased sensor-to-target dis- tances, making it potentially feasible to detect large improvised explosive devices (IEDs) in culverts using TNA. Experiments to determine the ability of TNA2 to detect improvised explosive devices in culverts are described, and the resulting signal levels observed for relevant quantities of explosives are presented. Observations conrm that bulk explosives detection using TNA against a culvert-IED is possible, with large charges posing a detection challenge at least as dicult as that of a deeply buried anti-tank landmine. Because of the prototype nature of the TNA sensor used, it is not yet possible to make denitive statements about the absolute sensitivity or detection time. Further investigation is warranted.

Fuse Selection for the Two-Stage Explosive Type Switches

NASA Astrophysics Data System (ADS)

Muravlev, I. O.; Surkov, M. A.; Tarasov, E. V.; Uvarov, N. F.

2017-04-01

In the two-level explosive switch destruction of a delay happens in the form of electric explosion. Criteria of similarity of electric explosion in transformer oil are defined. The challenge of protecting the power electrical equipment from short circuit currents is still urgent, especially with the growth of unit capacity. Is required to reduce the tripping time as much as possible, and limit the amplitude of the fault current, that is very important for saving of working capacity of life-support systems. This is particularly important when operating in remote stand-alone power supply systems with a high share of renewable energy, working through the inverter transducers, as well as inverter-type diesel generators. The explosive breakers copes well with these requirements. High-speed flow of transformer oil and high pressure provides formation rate of a contact gap of 20 - 100 m/s. In these conditions there is as a rapid increase in voltage on the discontinuity, and recovery of electric strength (Ures) after current interruption.

The point explosion with radiation transport

NASA Astrophysics Data System (ADS)

Lin, Zhiwei; Zhang, Lu; Kuang, Longyu; Jiang, Shaoen

2017-10-01

Some amount of energy is released instantaneously at the origin to generate simultaneously a spherical radiative heat wave and a spherical shock wave in the point explosion with radiation transport, which is a complicated problem due to the competition between these two waves. The point explosion problem possesses self-similar solutions when only hydrodynamic motion or only heat conduction is considered, which are Sedov solution and Barenblatt solution respectively. The point explosion problem wherein both physical mechanisms of hydrodynamic motion and heat conduction are included has been studied by P. Reinicke and A.I. Shestakov. In this talk we numerically investigate the point explosion problem wherein both physical mechanisms of hydrodynamic motion and radiation transport are taken into account. The radiation transport equation in one dimensional spherical geometry has to be solved for this problem since the ambient medium is optically thin with respect to the initially extremely high temperature at the origin. The numerical results reveal a high compression of medium and a bi-peak structure of density, which are further theoretically analyzed at the end.

Analysis of xRAGE and flag high explosive burn models with PBX 9404 cylinder tests

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harrier, Danielle; Andersen, Kyle Richard

High explosives are energetic materials that release their chemical energy in a short interval of time. They are able to generate extreme heat and pressure by a shock driven chemical decomposition reaction, which makes them valuable tools that must be understood. This study investigated the accuracy and performance of two Los Alamos National Laboratory hydrodynamic codes, which are used to determine the behavior of explosives within a variety of systems: xRAGE which utilizes an Eulerian mesh, and FLAG with utilizes a Lagrangian mesh. Various programmed and reactive burn models within both codes were tested using a copper cylinder expansion test.more » The test was based on a recent experimental setup which contained the plastic bonded explosive PBX 9404. Detonation velocity versus time curves for this explosive were obtained using Photon Doppler Velocimetry (PDV). The modeled results from each of the burn models tested were then compared to one another and to the experimental results. This study validate« less

Small explosions interrupt 3-year quiescence at Mount St. Helens, Washington

USGS Publications Warehouse

Myers, B.

1992-01-01

These ash-producing explosions are part of a series of at least 28 explosion-like seismic events that began on August 24, 989. Seismic signals from these events resemble those associated with confirmed ash-producing explosions in April-May 1986. Yet not all of the 1989-1991 events produced ash plumes. Excellent visual observations during four of the events indicated that neither a steam nor ash plume was generated. There is little information about the other events because they occurred when the mountain was not visible, nor was there physical evidence of ashfall or surface changes when scientists visited the crater days to weeks alter. Considerable deformation of the north side of the dome occurred during the series of explosion-like seismic events. Sections of the dome slumped northward and two new vents were formed. However, monitoring the changes associated with individual events was often impossible because several key electronic-distance-meter (EDM) targets and tiltmeters were destroyed by the series of events. 

Scaled experiments of explosions in cavities

DOE PAGES

Grun, J.; Cranch, G. A.; Lunsford, R.; ...

2016-05-11

Consequences of an explosion inside an air-filled cavity under the earth's surface are partly duplicated in a laboratory experiment on spatial scales 1000 smaller. The experiment measures shock pressures coupled into a block of material by an explosion inside a gas-filled cavity therein. The explosion is generated by suddenly heating a thin foil that is located near the cavity center with a short laser pulse, which turns the foil into expanding plasma, most of whose energy drives a blast wave in the cavity gas. Variables in the experiment are the cavity radius and explosion energy. Measurements and GEODYN code simulationsmore » show that shock pressuresmeasured in the block exhibit a weak dependence on scaled cavity radius up to ~25 m/kt 1/3, above which they decrease rapidly. Possible mechanisms giving rise to this behavior are described. As a result, the applicability of this work to validating codes used to simulate full-scale cavityexplosions is discussed.« less

The extimated presence of differentiated higly explosive magmas beneath Vesuvius and Campi Flegrei: evidence from geochemical and textural studies.

NASA Astrophysics Data System (ADS)

Pappalardo, Lucia; Mastrolorenzo, Giuseppe

2010-05-01

Highly catastrophic explosive eruptions are supplied by Si-rich magmas, generated at shallower level in crust by the evolution of mantle liquids. The timescale of these evolution processes is a crucial factor, because of its control on the length of volcano repose interval leading to high explosive events. Campi Flegrei and Somma-Vesuvius alkaline volcanic systems, located respectively at few kilometers west and east of Neapolitan metropolitan area, produced a variety of eruptions ranging from not explosive lava flows and domes to highly destructive eruptions. Both these high risk volcanoes are in repose time since the last eruption occurred in the 1538 and 1944 BP, respectively. Since that time, the volcanoes experienced fumarolic activity, low level of seismicity with rare earthquakes swarms, as well as two bradyseismic crisis (1969-1972 and 1982-1984) localized in the center of Campi Flegrei caldera, that generated a net uplift of 3.5 m around the town of Pozzuoli. A wide low velocity layer interpreted as an extended magmatic body has been detected at 8-10 km depth beneath these volcanoes by seismic data. The capability of this reservoir to erupt explosively again strongly depends on magma differentiation degree, therefore the knowledge of the time lapse necessary at not explosive mafic liquids to differentiate toward explosive magmas is very crucial to predict the size of a possible short-term future eruption in Campanian area. Our petrologic data indicate that a multi-depth supply system was active under the Campanian Plain since 39 ka. Fractional crystallization during magma cooling associated with upward migration of less dense evolved liquids appears to be the prevalent differentiation process. Our results indicate that huge steam exolution occurred during the late stage of trachyte and phonolite crystallization thus accounting for the high Volcanic Explosivity Index (VEI) of eruptions supplied by these melts. Moreover our CSD data on phenocrysts reveal rapid crystallization and differentiation time for alkaline Campanian magmas (in the order of decades to few centuries). This evidence implies that the 400 km2 partial melting zone detected by tomography study at 8-10 km depth beneath Vesuvius and Campi Flegrei, should consist of differentiated magma already capable to produce also large scale (plinian) explosive events in case of renewal of the activity from the present closed-conduit state.

Thin layer chromatography residue applicator sampler

DOEpatents

Nunes, Peter J [Danville, CA; Kelly, Fredrick R [Modesto, CA; Haas, Jeffrey S [San Ramon, CA; Andresen, Brian D [Livermore, CA

2007-07-24

A thin layer chromatograph residue applicator sampler. The residue applicator sampler provides for rapid analysis of samples containing high explosives, chemical warfare, and other analyses of interest under field conditions. This satisfied the need for a field-deployable, small, hand-held, all-in-one device for efficient sampling, sample dissolution, and sample application to an analytical technique. The residue applicator sampler includes a sampling sponge that is resistant to most chemicals and is fastened via a plastic handle in a hermetically sealed tube containing a known amount of solvent. Upon use, the wetted sponge is removed from the sealed tube and used as a swiping device across an environmental sample. The sponge is then replaced in the hermetically sealed tube where the sample remains contained and dissolved in the solvent. A small pipette tip is removably contained in the hermetically sealed tube. The sponge is removed and placed into the pipette tip where a squeezing-out of the dissolved sample from the sponge into the pipette tip results in a droplet captured in a vial for later instrumental analysis, or applied directly to a thin layer chromatography plate for immediate analysis.

Multicale modeling of the detonation of aluminized explosives using SPH-MD-QM method

NASA Astrophysics Data System (ADS)

Peng, Qing; Wang, Guangyu; Liu, Gui-Rong; de, Suvranu

Aluminized explosives have been applied in military industry since decades ago. Compared with ideal explosives, aluminized explosives feature both fast detonation and slow metal combustion chemistry, generating a complex multi-phase reactive flow. Here, we introduce a sequential multiscale model of SPH-MD-QM to simulate the detonation behavior of aluminized explosives. At the bottom level, first-principles quantum mechanics (QM) calculations are employed to obtain the training sets for fitting the ReaxFF potentials, which are used in turn in the reactive molecular dynamics (MD) simulations in the middle level to obtain the chemical reaction rates and equations of states. At the up lever, a smooth particle hydrodynamics (SPH) method incorporated ignition and growth model and afterburning model has been used for the simulation of the detonation and combustion of the aluminized explosive. Simulation is compared with experiment and good agreement is observed. The proposed multiscale method of SPH-MD-QM could be used to optimize the performance of aluminized explosives. The authors would like to acknowledge the generous financial support from the Defense Threat Reduction Agency (DTRA) Grant No. HDTRA1-13-1-0025 and the Office of Naval Research Grants ONR Award No. N00014-08-1-0462 and No. N00014-12-1-0527.

Preparation of graphene by electrical explosion of graphite sticks.

PubMed

Gao, Xin; Xu, Chunxiao; Yin, Hao; Wang, Xiaoguang; Song, Qiuzhi; Chen, Pengwan

2017-08-03

Graphene nanosheets were produced by electrical explosion of high-purity graphite sticks in distilled water at room temperature. The as-prepared samples were characterized by various techniques to find different forms of carbon phases, including graphite nanosheets, few-layer graphene, and especially, mono-layer graphene with good crystallinity. Delicate control of energy injection is critical for graphene nanosheet formation, whereas mono-layer graphene was produced under the charging voltage of 22.5-23.5 kV. On the basis of electrical wire explosion and our experimental results, the underlying mechanism that governs the graphene generation was carefully illustrated. This work provides a simple but innovative route for producing graphene nanosheets.

Martian rampart crater ejecta - Experiments and analysis of melt-water interaction

NASA Astrophysics Data System (ADS)

Wohletz, K. H.; Sheridan, M. F.

1983-10-01

Viking images of Martian craters with rampart-bordered ejecta deposits reveal distinct impact ejecta morphology when compared to that associated with similar-sized craters on the Moon and Mercury. It is suggested that target water explosively vaporized during impact alters initial ballistic trajectories of ejecta and produces surging flow emplacement. The dispersal of particulates during a series of controlled steam explosions generated by interaction of a thermite melt with water has been experimentally modeled. Study of terrestrial, lobate, volcanic ejecta produced by steam-blast explosions reveals that particle size and vapor to clast volume ratio are primary parameters characterizing the emplacement mechanism and deposit morphology.

The effect of a combined biological and thermo-mechanical pretreatment of wheat straw on energy yields in coupled ethanol and methane generation.

PubMed

Theuretzbacher, Franz; Blomqvist, Johanna; Lizasoain, Javier; Klietz, Lena; Potthast, Antje; Horn, Svein Jarle; Nilsen, Paal J; Gronauer, Andreas; Passoth, Volkmar; Bauer, Alexander

2015-10-01

Ethanol and biogas are energy carriers that could contribute to a future energy system independent of fossil fuels. Straw is a favorable bioenergy substrate as it does not compete with food or feed production. As straw is very resistant to microbial degradation, it requires a pretreatment to insure efficient conversion to ethanol and/or methane. This study investigates the effect of combining biological pretreatment and steam explosion on ethanol and methane yields in order to improve the coupled generation process. Results show that the temperature of the steam explosion pretreatment has a particularly strong effect on possible ethanol yields, whereas combination with the biological pretreatment showed no difference in overall energy yield. The highest overall energy output was found to be 10.86 MJ kg VS(-1) using a combined biological and steam explosion pretreatment at a temperature of 200°C. Copyright © 2015 Elsevier Ltd. All rights reserved.

Numerical Simulation of Energy Conversion Mechanism in Electric Explosion

NASA Astrophysics Data System (ADS)

Wanjun, Wang; Junjun, Lv; Mingshui, Zhu; Qiubo, Fu; EFIs Integration R&D Group Team

2017-06-01

Electric explosion happens when micron-scale metal films such as copper film is stimulated by short-time current pulse, while generating high temperature and high pressure plasma. The expansion process of the plasma plays an important role in the study of the generation of shock waves and the study of the EOS of matter under high pressure. In this paper, the electric explosion process is divided into two stages: the energy deposition stage and the quasi-isentropic expansion stage, and a dynamic EOS of plasma considering the energy replenishment is established. On this basis, flyer driven by plasma is studied numerically, the pressure and the internal energy of plasma in the energy deposition stage and the quasi - isentropic expansion stage are obtained by comparing the velocity history of the flyer with the experimental results. An energy conversion model is established, and the energy conversion efficiency of each process is obtained, and the influence of impedance matching relationship between flyer and metal plasma on the energy conversion efficiency is proposed in this paper.

Long-range acoustic observations of the Eyjafjallajökull eruption, Iceland, April-May 2010

NASA Astrophysics Data System (ADS)

Matoza, Robin S.; Vergoz, Julien; Le Pichon, Alexis; Ceranna, Lars; Green, David N.; Evers, Läslo G.; Ripepe, Maurizio; Campus, Paola; Liszka, Ludwik; Kvaerna, Tormod; Kjartansson, Einar; Höskuldsson, Ármann

2011-03-01

The April-May 2010 summit eruption of Eyjafjallajökull, Iceland, was recorded by 14 atmospheric infrasound sensor arrays at ranges between 1,700 and 3,700 km, indicating that infrasound from modest-size eruptions can propagate for thousands of kilometers in atmospheric waveguides. Although variations in both atmospheric propagation conditions and background noise levels at the sensors generate fluctuations in signal-to-noise ratios and signal detectability, array processing techniques successfully discriminate between volcanic infrasound and ambient coherent and incoherent noise. The current global infrasound network is significantly more dense and sensitive than any previously operated network and signals from large volcanic explosions are routinely recorded. Because volcanic infrasound is generated during the explosive release of fluid into the atmosphere, it is a strong indicator that an eruption has occurred. Therefore, long-range infrasonic monitoring may aid volcanic explosion detection by complementing other monitoring technologies, especially in remote regions with sparse ground-based instrument networks.

Acoustic waves in the atmosphere and ground generated by volcanic activity

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ichihara, Mie; Lyons, John; Oikawa, Jun

2012-09-04

This paper reports an interesting sequence of harmonic tremor observed in the 2011 eruption of Shinmoe-dake volcano, southern Japan. The main eruptive activity started with ashcloud forming explosive eruptions, followed by lava effusion. Harmonic tremor was transmitted into the ground and observed as seismic waves at the last stage of the effusive eruption. The tremor observed at this stage had unclear and fluctuating harmonic modes. In the atmosphere, on the other hand, many impulsive acoustic waves indicating small surface explosions were observed. When the effusion stopped and the erupted lava began explosive degassing, harmonic tremor started to be transmitted alsomore » to the atmosphere and observed as acoustic waves. Then the harmonic modes became clearer and more stable. This sequence of harmonic tremor is interpreted as a process in which volcanic degassing generates an open connection between the volcanic conduit and the atmosphere. In order to test this hypothesis, a laboratory experiment was performed and the essential features were successfully reproduced.« less

Single-photon Coulomb explosion of methanol using broad bandwidth ultrafast EUV pulses.

PubMed

Luzon, Itamar; Jagtap, Krishna; Livshits, Ester; Lioubashevski, Oleg; Baer, Roi; Strasser, Daniel

2017-05-31

Single-photon Coulomb explosion of methanol is instigated using the broad bandwidth pulse achieved through high-order harmonics generation. Using 3D coincidence fragment imaging of one molecule at a time, the kinetic energy release (KER) and angular distributions of the products are measured in different Coulomb explosion (CE) channels. Two-body CE channels breaking either the C-O or the C-H bonds are described as well as a proton migration channel forming H 2 O + , which is shown to exhibit higher KER. The results are compared to intense-field Coulomb explosion measurements in the literature. The interpretation of broad bandwidth single-photon CE data is discussed and supported by ab initio calculations of the predominant C-O bond breaking CE channel. We discuss the importance of these findings for achieving time resolved imaging of ultrafast dynamics.

Field emission and explosive electron emission process in focused ion beam fabricated platinum and tungsten three-dimensional overhanging nanostructure

NASA Astrophysics Data System (ADS)

Singh, Abhishek Kumar

2018-06-01

Three-dimensional platinum and tungsten overhanging nanogap (∼70 nm) electrodes are fabricated on a glass substrate using focused ion beam milling and chemical vapour deposition processes. Current-voltage (I-V) characteristics of the devices measured at a pressure of ∼10-6 mbar shows space-charge emission followed by the Fowler-Nordheim (F-N) field emission. After the F-N emission, the system enters into an explosive emission process, at a higher voltage generating a huge current. We observe a sharp and abrupt rise in the emission current which marks the transition from the F-N emission to the explosive emission state. The explosive emission process is destructive in nature and yields micro-/nano-size spherical metal particles. The chemical compositions and the size-distribution of such particles are performed.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kay, Jeffrey J.; Park, Samuel; Kohl, Ian Thomas

In this work, shock-induced reactions in high explosives and their chemical mechanisms were investigated using state-of-the-art experimental and theoretical techniques. Experimentally, ultrafast shock interrogation (USI, an ultrafast interferometry technique) and ultrafast absorption spectroscopy were used to interrogate shock compression and initiation of reaction on the picosecond timescale. The experiments yielded important new data that appear to indicate reaction of high explosives on the timescale of tens of picoseconds in response to shock compression, potentially setting new upper limits on the timescale of reaction. Theoretically, chemical mechanisms of shock-induced reactions were investigated using density functional theory. The calculations generated important insightsmore » regarding the ability of several hypothesized mechanisms to account for shock-induced reactions in explosive materials. The results of this work constitute significant advances in our understanding of the fundamental chemical reaction mechanisms that control explosive sensitivity and initiation of detonation.« less

Ecological Risk Assessment of Explosive Residues in Rodents, Reptiles, Amphibians, and Fish

DTIC Science & Technology

2004-03-01

oligonucleotide primers were designed according to the sequence for pendrin in Mus musculus . PCR was carried out using a Failsafe kit (Epicentre, WI). PCR...Project No. T9700 PERCHLORATE ANALYTICAL Phase V As a calibration curve is run each time a set of samples is analyzed, we routinely include an... Reset FINAL REPORT FY2002 SERDP Project: ER-1235 TABLE OF CONTENTS Topic Page IDENTIFICATION OF PERCHLORATE-CONTAMINATED AND REFERENCE SITES

The Residual Strength of a Ship after an Internal Explosion

DTIC Science & Technology

1988-05-01

uafcd by the presence of small holes, and is roughly equal to three times the critical buckling load. With regards to application , however, the...not be described by a single measure of failure. Several promising approaches to EPFM are being developed, however, which offer some insights into the...toughness so determined is a material property, and indicates that the rigid-plastic equation is valid for certain applications . From a global energy

Photochemical Degradation of Composition B and Its Components

DTIC Science & Technology

2007-09-01

recorded on the toluene (5.7 mg yield ), ether I (35 mg), and aceto- nitrile (17.8 mg) fractions. Irradiation of solution explosives in soils A...the soil was Soxhlet extracted with acetonitrile for 93 hours. The acetonitrile was removed with a rotary evaporator and the residue redissolved in...ionization to yield an anion of m/z 226. The traces show differences observed in samples with different initial preparation protocols at 15 days. Distance

Statistically generated weighted curve fit of residual functions for modal analysis of structures

NASA Technical Reports Server (NTRS)

Bookout, P. S.

1995-01-01

A statistically generated weighting function for a second-order polynomial curve fit of residual functions has been developed. The residual flexibility test method, from which a residual function is generated, is a procedure for modal testing large structures in an external constraint-free environment to measure the effects of higher order modes and interface stiffness. This test method is applicable to structures with distinct degree-of-freedom interfaces to other system components. A theoretical residual function in the displacement/force domain has the characteristics of a relatively flat line in the lower frequencies and a slight upward curvature in the higher frequency range. In the test residual function, the above-mentioned characteristics can be seen in the data, but due to the present limitations in the modal parameter evaluation (natural frequencies and mode shapes) of test data, the residual function has regions of ragged data. A second order polynomial curve fit is required to obtain the residual flexibility term. A weighting function of the data is generated by examining the variances between neighboring data points. From a weighted second-order polynomial curve fit, an accurate residual flexibility value can be obtained. The residual flexibility value and free-free modes from testing are used to improve a mathematical model of the structure. The residual flexibility modal test method is applied to a straight beam with a trunnion appendage and a space shuttle payload pallet simulator.

Monitoring Research in the Context of CTBT Negotiations and Networks,

DTIC Science & Technology

1995-08-14

1995) estimates, using infrasound and satellite data, that these sources generate explosion-like signals worldwide at a rate of approximately 1/yr at...coupling and the waveform appearance of atmospheric explosions. In infrasound there is the development of new array designs and of new automatic detection ...sensors. The principal daily use of the hydroacoustic network is for purposes of simple discrimination of those oceanic earthquakes detected by the seismic

Solvent-Free Off-On Detection of the Improvised Explosive Triacetone Triperoxide (TATP) with Fluorogenic Materials.

PubMed

Calvo-Gredilla, Patricia; García-Calvo, José; Cuevas, José V; Torroba, Tomás; Pablos, Jesús-Luis; García, Félix C; García, José-Miguel; Zink-Lorre, Nathalie; Font-Sanchis, Enrique; Sastre-Santos, Ángela; Fernández-Lázaro, Fernando

2017-10-09

A fluorogenic perylenediimide-functionalized polyacrylate capable of generating color and fluorescence changes in the presence of triacetone triperoxide TATP), an improvised explosive used in terrorist attacks, under solvent-free, solid-state conditions has been developed. The material works by accumulating volatile TATP until it reaches a threshold; therefore, triggering colorimetric and fluorescent responses. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Predicting Explosion-Generated SN and LG Coda Using Syntheic Seismograms

DTIC Science & Technology

2008-09-01

velocities in the upper crust are based on borehole data, geologic and gravity data, refraction studies and seismic experiments (McLaughlin et al. 1983...realizations of random media. We have estimated the heterogeneity parameters for the NTS using available seismic and geologic data. Lateral correlation...variance and coherence measures between seismic traces are estimated from clusters of nuclear explosions and well- log data. The horizontal von Karman

Volatile Transport by Volcanic Plumes on Earth, Venus and Mars

NASA Technical Reports Server (NTRS)

Glaze, Lori S.; Self, Stephen; Baloga, Steve; Stofan, Ellen R.

2012-01-01

Explosive volcanic eruptions can produce sustained, buoyant columns of ash and gas in the atmosphere (Fig. 1). Large flood basalt eruptions may also include significant explosive phases that generate eruption columns. Such eruptions can transport volcanic volatiles to great heights in the atmosphere. Volcanic eruption columns can also redistribute chemical species within the atmosphere by entraining ambient atmosphere at low altitudes and releasing those species at much higher altitudes.

Mitigation of Earth-asteroid collisions via explosive, intense radiation sources

NASA Astrophysics Data System (ADS)

Miles, Aaron; Sanders, James

2005-10-01

The Universe is continually producing astrophysical explosions that generate intense bursts of electromagnetic and particle radiation. Interaction of this radiation with nearby objects can effect significant changes to their dynamics through a variety of processes including ionization, ablation, and shock generation. The next time a large asteroid or comet is found to be approaching the Earth on an impact trajectory, humans may find it prudent to mimic nature by using the most intense radiation sources available to alter the incoming object's trajectory and avert a catastrophic collision. With this in mind, we consider the effect of nuclear explosives on nearby would-be Earth impactors. Neutrons and x-rays produced in the explosion are deposited in a thin layer of the asteroid's surface, resulting in ablation and shock and thereby imparting a deflection velocity. A Monte Carlo code is used for radiation transport and energy deposition, while the subsequent dynamic evolution of the asteroid is followed with the hydrodynamics code CALE. We consider the dependence of the deflection velocity on the source energy and spectrum, the asteroid or comet composition, and the standoff distance between the target and the source. This work was performed under the auspices of the U. S. Department of Energy by the University of California, Lawrence Livermore National Laboratory under contract No. W-7405-Eng-48.

Low cost mobile explosive/drug detection devices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gozani, T.; Bendahan, J.

1999-06-10

Inspection technologies based on Thermal Neutron Analysis (TNA) and/or Fast Neutron Analysis (FNA) are the basis for relatively compact and low-cost, material-sensitive devices for a wide variety of inspection needs. The TNA allows the use of either isotropic neutron sources such as a {sup 252}Cf, or electronic neutron generators such as the d-T sealed neutron generator tubes. The latter could be used in a steady state mode or in slow (>{mu}s) pulsing mode, to separate the thermal neutron capture signatures following the pulse from the combination of the FNA plus TNA signatures during the pulse. Over the years, Ancore Corporationmore » has built and is continuing to develop a variety of inspection devices based on its TNA and FNA technologies: SPEDS--an explosive detection device for small parcels, portable electronics, briefcases and other similar carry-on items; MDS - a system for the detection or confirmation of buried mines; VEDS - a system for the detection of varied amounts of explosives and/or drugs concealed in passenger vehicles, pallets, lightly loaded trucks or containers, etc.; ACD - a device to clear alarms from a primary, non-specific explosive detection system for passenger luggage. The principle and performance of these devices will be shown and discussed.« less

Development of a handheld widefield hyperspectral imaging (HSI) sensor for standoff detection of explosive, chemical, and narcotic residues

NASA Astrophysics Data System (ADS)

Nelson, Matthew P.; Basta, Andrew; Patil, Raju; Klueva, Oksana; Treado, Patrick J.

2013-05-01

The utility of Hyper Spectral Imaging (HSI) passive chemical detection employing wide field, standoff imaging continues to be advanced in detection applications. With a drive for reduced SWaP (Size, Weight, and Power), increased speed of detection and sensitivity, developing a handheld platform that is robust and user-friendly increases the detection capabilities of the end user. In addition, easy to use handheld detectors could improve the effectiveness of locating and identifying threats while reducing risks to the individual. ChemImage Sensor Systems (CISS) has developed the HSI Aperio™ sensor for real time, wide area surveillance and standoff detection of explosives, chemical threats, and narcotics for use in both government and commercial contexts. Employing liquid crystal tunable filter technology, the HSI system has an intuitive user interface that produces automated detections and real-time display of threats with an end user created library of threat signatures that is easily updated allowing for new hazardous materials. Unlike existing detection technologies that often require close proximity for sensing and so endanger operators and costly equipment, the handheld sensor allows the individual operator to detect threats from a safe distance. Uses of the sensor include locating production facilities of illegal drugs or IEDs by identification of materials on surfaces such as walls, floors, doors, deposits on production tools and residue on individuals. In addition, the sensor can be used for longer-range standoff applications such as hasty checkpoint or vehicle inspection of residue materials on surfaces or bulk material identification. The CISS Aperio™ sensor has faster data collection, faster image processing, and increased detection capability compared to previous sensors.

Source and path effects in the wave fields of tremor and explosions at Stromboli Volcano, Italy

USGS Publications Warehouse

Chouet, B.; Saccorotti, G.; Martini, M.; Dawson, P.; De Luca, G.; Milana, G.; Scarpa, R.

1997-01-01

The wave fields generated by Strombolian activity are investigated using data from small-aperture seismic arrays deployed on the north flank of Stromboli and data from seismic and pressure transducers set up near the summit crater. Measurements of slowness and azimuth as a function of time clearly indicate that the sources of tremor and explosions are located beneath the summit crater at depths shallower than 200 m with occasional bursts of energy originating from sources extending to a depth of 3 km. Slowness, azimuth, and particle motion measurements reveal a complex composition of body and surface waves associated with topography, structure, and source properties. Body waves originating at depths shallower than 200 m dominate the wave field at frequencies of 0.5-2.5 Hz, and surface waves generated by the surficial part of the source and by scattering sources distributed around the island dominate at frequencies above 2.5 Hz. The records of tremor and explosions are both dominated by SH motion. Far-field records from explosions start with radial motion, and near-field records from those events show dominantly horizontal motion and often start with a low-frequency (1-2 Hz) precursor characterized by elliptical particle motion, followed within a few seconds by a high-frequency radial phase (1-10 Hz) accompanying the eruption of pyroclastics. The dominant component of the near- and far-field particle motions from explosions, and the timing of air and body wave phases observed in the near field, are consistent with a gaspiston mechanism operating on a shallow (<200 m deep), vertical crack-like conduit. Models of a degassing fluid column suggest that noise emissions originating in the collective oscillations of bubbles ascending in the magma conduit may provide an adequate self-excitation mechanism for sustained tremor generation at Stromboli. Copyright 1997 by the American Geophysical Union.

Predicting Large-scale Effects During Cookoff of Plastic-Bonded Explosives (PBX 9501 PBX 9502 and LX-14)

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hobbs, Michael L.; Kaneshige, Michael J.; Erikson, William W.

In this study, we have made reasonable cookoff predictions of large-scale explosive systems by using pressure-dependent kinetics determined from small-scale experiments. Scale-up is determined by properly accounting for pressure generated from gaseous decomposition products and the volume that these reactive gases occupy, e.g. trapped within the explosive, the system, or vented. The pressure effect on the decomposition rates has been determined for different explosives by using both vented and sealed experiments at low densities. Low-density explosives are usually permeable to decomposition gases and can be used in both vented and sealed configurations to determine pressure-dependent reaction rates. In contrast, explosivesmore » that are near the theoretical maximum density (TMD) are not as permeable to decomposition gases, and pressure-dependent kinetics are difficult to determine. Ignition in explosives at high densities can be predicted by using pressure-dependent rates determined from the low-density experiments as long as gas volume changes associated with bulk thermal expansion are also considered. In the current work, cookoff of the plastic-bonded explosives PBX 9501 and PBX 9502 is reviewed and new experimental work on LX-14 is presented. Reactive gases are formed inside these heated explosives causing large internal pressures. The pressure is released differently for each of these explosives. For PBX 9501, permeability is increased and internal pressure is relieved as the nitroplasticizer melts and decomposes. Internal pressure in PBX 9502 is relieved as the material is damaged by cracks and spalling. For LX-14, internal pressure is not relieved until the explosive thermally ignites. The current paper is an extension of work presented at the 26th ICDERS symposium [1].« less

Study of thermal decomposition mechanisms and low-level detection of explosives using pulsed photoacoustic technique

NASA Astrophysics Data System (ADS)

Yehya, F.; Chaudhary, A. K.; Srinivas, D.; Muralidharan, K.

2015-11-01

We report a novel time-resolved photoacoustic-based technique for studying the thermal decomposition mechanisms of some secondary explosives such as RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine), picric acid, 4,6-dinitro-5-(4-nitro-1 H-imidazol-1-yl)-1 H-benzo[ d] [1-3] triazole, and 5-chloro-1-(4-nitrophenyl)-1 H-tetrazole. A comparison of the thermal decomposition mechanisms of these secondary explosives was made by detecting NO2 molecules released under controlled pyrolysis between 25 and 350 °C. The results show excellent agreement with the thermogravimetric and differential thermal analysis (TGA-DTA) results. A specially designed PA cell made of stainless steel was filled with explosive vapor and pumped using second harmonic, i.e., λ = 532 nm, pulses of duration 7 ns at a 10 Hz repetition rate, obtained using a Q-switched Nd:YAG laser. The use of a combination of PA and TGA-DTA techniques enables the study of NO2 generation, and this method can be used to scale the performance of these explosives as rocket fuels. The minimum detection limits of the four explosives were 38 ppmv to 69 ppbv, depending on their respective vapor pressures.

Physical explosion analysis in heat exchanger network design

NASA Astrophysics Data System (ADS)

Pasha, M.; Zaini, D.; Shariff, A. M.

2016-06-01

The failure of shell and tube heat exchangers is being extensively experienced by the chemical process industries. This failure can create a loss of production for long time duration. Moreover, loss of containment through heat exchanger could potentially lead to a credible event such as fire, explosion and toxic release. There is a need to analyse the possible worst case effect originated from the loss of containment of the heat exchanger at the early design stage. Physical explosion analysis during the heat exchanger network design is presented in this work. Baker and Prugh explosion models are deployed for assessing the explosion effect. Microsoft Excel integrated with process design simulator through object linking and embedded (OLE) automation for this analysis. Aspen HYSYS V (8.0) used as a simulation platform in this work. A typical heat exchanger network of steam reforming and shift conversion process was presented as a case study. It is investigated from this analysis that overpressure generated from the physical explosion of each heat exchanger can be estimated in a more precise manner by using Prugh model. The present work could potentially assist the design engineer to identify the critical heat exchanger in the network at the preliminary design stage.

An experimental study of an explosively driven flat plate launcher

NASA Astrophysics Data System (ADS)

Rae, Philip; Haroz, Erik; Armstrong, Chris; Perry, Lee; M Division Team

2017-06-01

For some upcoming experiments it is desired to impact a large explosive assembly with one or more moderate diameter flat metal plates traveling at high velocity (2-3 km s-1). The time of arrival of these plates will need to carefully controlled and delayed (i.e. the time(s) of arrival known to approximately a microsecond). For this reason, producing a flyer plate from more traditional gun assemblies is not possible. Previous researchers have demonstrated the ability to throw reasonably flat metal flyers from the so-called Forest flyer geometry. The defining characteristics of this design are a carefully controlled reduction in explosive area from a larger explosive plane-wave-lens and booster pad to a smaller flyer plate to improve the planarity of the drive available and an air gap between the explosive booster and the plate to reduce the peak tensile stresses generated in the plate to suppress spalling. This experimental series comprised a number of different design variants and plate and explosive drive materials. The aim was to calibrate a predictive computational modeling capability on this kind of system in preparation for later more radical design ideas best tested in a computer before undertaking the expensive business of construction.

Thermal safety characterization on PETN, PBX-9407, LX-10-2, LX-17-1 and detonator in the LLNL's P-ODTX system

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hsu, P. C.; Strout, S.; Reynolds, J. G.

Incidents caused by fire and other thermal events can heat energetic materials that may lead to thermal explosion and result in structural damage and casualty. Thus, it is important to understand the response of energetic materials to thermal insults. The One-Dimensional-Time to Explosion (ODTX) system at the Lawrence Livermore National Laboratory (LLNL) has been used for decades to characterize thermal safety of energetic materials. In this study, an integration of a pressure monitoring element has been added into the ODTX system (P-ODTX) to perform thermal explosion (cook-off) experiments (thermal runaway) on PETN powder, PBX-9407, LX-10-2, LX-17-1, and detonator samples (cupmore » tests). The P-ODTX testing generates useful data (thermal explosion temperature, thermal explosion time, and gas pressures) to assist with the thermal safety assessment of relevant energetic materials and components. This report summarizes the results of P-ODTX experiments that were performed from May 2015 to July 2017. Recent upgrades to the data acquisition system allows for rapid pressure monitoring in microsecond intervals during thermal explosion. These pressure data are also included in the report.« less

The Averno 2 fissure eruption: a recent small-size explosive event at the Campi Flegrei Caldera (Italy)

NASA Astrophysics Data System (ADS)

di Vito, Mauro Antonio; Arienzo, Ilenia; Braia, Giuseppe; Civetta, Lucia; D'Antonio, Massimo; di Renzo, Valeria; Orsi, Giovanni

2011-04-01

The Averno 2 eruption (3,700 ± 50 a B.P.) was an explosive low-magnitude event characterized by magmatic and phreatomagmatic explosions, generating mainly fall and surge beds, respectively. It occurred in the Western sector of the Campi Flegrei caldera (Campanian Region, South Italy) at the intersection of two active fault systems, oriented NE and NW. The morphologically complex crater area, largely filled by the Averno lake, resulted from vent activation and migration along the NE-trending fault system. The eruption generated a complex sequence of pyroclastic deposits, including pumice fall deposits in the lower portion, and prevailing surge beds in the intermediate-upper portion. The pyroclastic sequence has been studied through stratigraphical, morphostructural and petrological investigations, and subdivided into three members named A through C. Member A was emplaced during the first phase of the eruption mainly by magmatic explosions which generated columns reaching a maximum height of 10 km. During this phase the eruption reached its climax with a mass discharge rate of 3.2 106 kg/s. Intense fracturing and fault activation favored entry of a significant amount of water into the system, which produced explosions driven by variably efficient water-magma interaction. These explosions generated wet to dry surge deposits that emplaced Member B and C, respectively. Isopachs and isopleths maps, as well as areal distribution of ballistic fragments and facies variation of surge deposits allow definition of four vents that opened along a NE oriented, 2 km long fissure. The total volume of magma extruded during the eruption has been estimated at about 0.07 km3 (DRE). The erupted products range in composition from initial, weakly peralkaline alkali-trachyte, to last-emplaced alkali-trachyte. Isotopic data and modeling suggest that mixing occurred during the Averno 2 eruption between a more evolved, less radiogenic stored magma, and a less evolved, more radiogenic magma that entered the shallow reservoir to trigger the eruption. The early phases of the eruption, during which the vent migrated from SW to the center of the present lake, were fed by the more evolved, uppermost magma, while the following phases extruded the less evolved, lowermost magma. Integration of the geological and petrological results suggests that the Averno 2 complex eruption was fed from a dyke-shaped shallow reservoir intruded into the NE-SW fault system bordering to the west the La Starza resurgent block, within the caldera floor.

An unusual case of carbon monoxide poisoning.

PubMed Central

Auger, P L; Levesque, B; Martel, R; Prud'homme, H; Bellemare, D; Barbeau, C; Lachance, P; Rhainds, M

1999-01-01

Carbon monoxide, a gas originating from incomplete combustion of carbon-based fuels, is an important cause of human deaths. In this paper, we describe an unusual carbon monoxide poisoning in a dwelling without obvious sources of combustion gases, for which two adults had to be treated in a hyperbaric chamber. Carbon monoxide readings were taken in the house and in the neighboring homes. Methane gas and nitrogen oxide levels were also monitored in the house air. Soil samples were collected around the house and tested for hydrocarbon residues. The investigation revealed the presence of a pocket of carbon monoxide under the foundation of the house. The first readings revealed carbon monoxide levels of 500 ppm in the basement. The contamination lasted for a week. The investigation indicated that the probable source of contamination was the use of explosives at a nearby rain sewer construction site. The use of explosives in a residential area can constitute a major source of carbon monoxide for the neighboring populations. This must be investigated, and public health authorities, primary-care physicians, governmental authorities, and users and manufacturers of explosives must be made aware of this problem. Images Figure 1 Figure 2 PMID:10379009

Explosive Event in MON-3 Oxidizer System Resulting from Pressure Transducer Failure

NASA Technical Reports Server (NTRS)

Baker, David L.; Reynolds, Michael; Anderson, John

2006-01-01

In 2003, a Druck(Registered Trademark) pressure transducer failed catastrophically in a test system circulating nitrogen tetroxide at NASA Johnson Space Center White Sands Test Facility. The cause of the explosion was not immediately obvious since the wetted areas of the pressure transducer were constructed of materials compatible with nitrogen tetroxide. Chemical analysis of the resulting residue and a materials analysis of the diaphragm and its weld zones were used to determine the chain of events that led to the catastrophic failure. Due to excessive dynamic pressure loading in the test system, the diaphragm in the pressure transducer suffered cyclic failure and allowed the silicon oil located behind the isolation diaphragm to mix with the nitrogen tetroxide. The reaction between these two chemicals formed a combination of 2,4-di and 2,4,6-trinitrophenol, which are shock sensitive explosives that caused the failure of the pressure transducer. Further research indicated numerous manufacturers offer similar pressure transducers with silicone oil separated from the test fluid by a thin stainless steel isolation diaphragm. Caution must be exercised when purchasing a pressure transducer for a particular system to avoid costly failures and test system contamination.

Advancing Explosion Source Theory through Experimentation: Results from Seismic Experiments Since the Moratorium on Nuclear Testing

NASA Astrophysics Data System (ADS)

Bonner, J. L.; Stump, B. W.

2011-12-01

On 23 September 1992, the United States conducted the nuclear explosion DIVIDER at the Nevada Test Site (NTS). It would become the last US nuclear test when a moratorium ended testing the following month. Many of the theoretical explosion seismic models used today were developed from observations of hundreds of nuclear tests at NTS and around the world. Since the moratorium, researchers have turned to chemical explosions as a possible surrogate for continued nuclear explosion research. This talk reviews experiments since the moratorium that have used chemical explosions to advance explosion source models. The 1993 Non-Proliferation Experiment examined single-point, fully contained chemical-nuclear equivalence by detonating over a kiloton of chemical explosive at NTS in close proximity to previous nuclear explosion tests. When compared with data from these nearby nuclear explosions, the regional and near-source seismic data were found to be essentially identical after accounting for different yield scaling factors for chemical and nuclear explosions. The relationship between contained chemical explosions and large production mining shots was studied at the Black Thunder coal mine in Wyoming in 1995. The research led to an improved source model for delay-fired mining explosions and a better understanding of mining explosion detection by the International Monitoring System (IMS). The effect of depth was examined in a 1997 Kazakhstan Depth of Burial experiment. Researchers used local and regional seismic observations to conclude that the dominant mechanism for enhanced regional shear waves was local Rg scattering. Travel-time calibration for the IMS was the focus of the 1999 Dead Sea Experiment where a 10-ton shot was recorded as far away as 5000 km. The Arizona Source Phenomenology Experiments provided a comparison of fully- and partially-contained chemical shots with mining explosions, thus quantifying the reduction in seismic amplitudes associated with partial confinement. The Frozen Rock Experiment in 2006 found only minor differences in seismic coupling for explosions in frozen and unfrozen rock. The seismo-acoustic source function was the focus of the above- and below-ground Humble Redwood explosions (2007, 2009 ) in New Mexico and detonations of rocket motor explosions in Utah. Acoustic travel time calibration for the IMS was accomplished with the 2009 and 2011 100-ton surface explosions in southern Israel. The New England Damage Experiment in 2009 correlated increased shear wave generation with increased rock damage from explosions. Damage from explosions continues to be an important research topic at Nevada's National Center for Nuclear Security with the ongoing Source Physics Experiment. A number of exciting experiments are already planned for the future and thus continue the effort to improve global detection, location, and identification of nuclear explosions.

33 CFR 334.1190 - Hood Canal and Dabob Bay, Wash.; naval non-explosive torpedo testing area.

Code of Federal Regulations, 2013 CFR

2013-07-01

... southwesterly to the point of beginning. (2) The regulations. (i) Propeller-driven or other noise-generating craft shall not work their screws or otherwise generate other than incidental noise in the area during...

33 CFR 334.1190 - Hood Canal and Dabob Bay, Wash.; naval non-explosive torpedo testing area.

Code of Federal Regulations, 2012 CFR

2012-07-01

... southwesterly to the point of beginning. (2) The regulations. (i) Propeller-driven or other noise-generating craft shall not work their screws or otherwise generate other than incidental noise in the area during...

33 CFR 334.1190 - Hood Canal and Dabob Bay, Wash.; naval non-explosive torpedo testing area.

Code of Federal Regulations, 2014 CFR

2014-07-01

... southwesterly to the point of beginning. (2) The regulations. (i) Propeller-driven or other noise-generating craft shall not work their screws or otherwise generate other than incidental noise in the area during...

Laser based in-situ and standoff detection of chemical warfare agents and explosives

NASA Astrophysics Data System (ADS)

Patel, C. Kumar N.

2009-09-01

Laser based detection of gaseous, liquid and solid residues and trace amounts has been developed ever since lasers were invented. However, the lack of availability of reasonably high power tunable lasers in the spectral regions where the relevant targets can be interrogated as well as appropriate techniques for high sensitivity, high selectivity detection has hampered the practical exploitation of techniques for the detection of targets important for homeland security and defense applications. Furthermore, emphasis has been on selectivity without particular attention being paid to the impact of interfering species on the quality of detection. Having high sensitivity is necessary but not a sufficient condition. High sensitivity assures a high probability of detection of the target species. However, it is only recently that the sensor community has come to recognize that any measure of probability of detection must be associated with a probability of false alarm, if it is to have any value as a measure of performance. This is especially true when one attempts to compare performance characteristics of different sensors based on different physical principles. In this paper, I will provide a methodology for characterizing the performance of sensors utilizing optical absorption measurement techniques. However, the underlying principles are equally application to all other sensors. While most of the current progress in high sensitivity, high selectivity detection of CWAs, TICs and explosives involve identifying and quantifying the target species in-situ, there is an urgent need for standoff detection of explosives from safe distances. I will describe our results on CO2 and quantum cascade laser (QCL) based photoacoustic sensors for the detection of CWAs, TICs and explosives as well the very new results on stand-off detection of explosives at distances up to 150 meters. The latter results are critically important for assuring safety of military personnel in battlefield environment, especially from improvised explosive devices (IEDs), and of civilian personnel from terrorist attacks in metropolitan areas.

Evaluation of electricity generation from lignin residue and biogas in cellulosic ethanol production.

PubMed

Liu, Gang; Bao, Jie

2017-11-01

This study takes the first insight on the rigorous evaluation of electricity generation based on the experimentally measured higher heating value (HHV) of lignin residue, as well as the chemical oxygen demand (COD) and biological oxygen demand (BOD 5 ) of wastewater. For producing one metric ton of ethanol fuel from five typical lignocellulose substrates, including corn stover, wheat straw, rice straw, sugarcane bagasse and poplar sawdust, 1.26-1.85tons of dry lignin residue is generated from biorefining process and 0.19-0.27tons of biogas is generated from anaerobic digestion of wastewater, equivalent to 4335-5981kWh and 1946-2795kWh of electricity by combustion of the generated lignin residue and biogas, respectively. The electricity generation not only sufficiently meets the electricity needs of process requirement, but also generates more than half of electricity surplus selling to the grid. Copyright © 2017 Elsevier Ltd. All rights reserved.

Green primaries: Environmentally friendly energetic complexes

PubMed Central

Huynh, My Hang V.; Hiskey, Michael A.; Meyer, Thomas J.; Wetzler, Modi

2006-01-01

Primary explosives are used in small quantities to generate a detonation wave when subjected to a flame, heat, impact, electric spark, or friction. Detonation of the primary explosive initiates the secondary booster or main-charge explosive or propellant. Long-term use of lead azide and lead styphnate as primary explosives has resulted in lead contamination at artillery and firing ranges and become a major health hazard and environmental problem for both military and civilian personnel. Devices using lead primary explosives are manufactured by the tens of millions every year in the United States from primers for bullets to detonators for mining. Although substantial synthetic efforts have long been focused on the search for greener primary explosives, this unresolved problem has become a “holy grail” of energetic materials research. Existing candidates suffer from instability or excessive sensitivity, or they possess toxic metals or perchlorate. We report here four previously undescribed green primary explosives based on complex metal dianions and environmentally benign cations, (cat)2[MII(NT)4(H2O)2] (where cat is NH4+ or Na+, M is Fe2+ or Cu2+, and NT− is 5-nitrotetrazolato-N2). They are safer to prepare, handle, and transport than lead compounds, have comparable initiation efficiencies to lead azide, and offer rapid reliable detonation comparable with lead styphnate. Remarkably, they possess all current requirements for green primary explosives and are suitable to replace lead primary explosives in detonators. More importantly, they can be synthesized more safely, do not pose health risks to personnel, and cause much less pollution to the environment. PMID:16567623

How seismicity and shear stress-generated tilt can indicate imminent explosions on Tungurahua

NASA Astrophysics Data System (ADS)

Neuberg, Jurgen; Mothes, Patricia; Collinson, Amy; Marsden, Luke

2017-04-01

Seismic swarms and tilt measurement on active silicic volcanoes have been successfully used to assess their eruption potential. Swarms of low-frequency seismic events have been associated with brittle failure or stick-slip motion of magma during ascent and have been used to estimate qualitatively the magma ascent. Tilt signals are extremely sensitive indicators for volcano deformation and their interpretation includes shear stress as a generating source as well as inflation or deflation of a shallow magma reservoir. Here we use data sets from different tiltmeters deployed on Tungurahua volcano, Ecuador, and contrast the two source models for different locations and time intervals. We analyse a simultaneously recorded seismic data set and address the question of shear stress partitioning resulting in both the generation of tilt and low-frequency seismicity in critical phases prior to Vulcanion explosions.

Shock waves raised by explosions in space as sources of ultra-high-energy cosmic rays

NASA Astrophysics Data System (ADS)

Kichigin, Gennadiy

2015-03-01

The paper discusses the possibility of particle acceleration up to ultrahigh energies in the relativistic waves generated by various explosive processes in the interstellar medium. We propose to use the surfatron mechanism of acceleration (surfing) of charged particles trapped in the front of relativistic waves as a generator of high-energy cosmic rays (CRs). Conditions under which surfing in these waves can be made are studied thoroughly. Ultra-high-energy CRs (up to 10^20 eV) are shown to be obtained due to the surfing in the relativistic plane and spherical waves. Surfing is supposed to take place in nonlinear Langmuir waves excited by powerful electromagnetic radiation or relativistic beams of charged particles, as well as in strong shock waves generated by relativistic jets or spherical formations that expand fast (fireballs).

Quasi-isentropic compression using compressed water flow generated by underwater electrical explosion of a wire array

NASA Astrophysics Data System (ADS)

Gurovich, V.; Virozub, A.; Rososhek, A.; Bland, S.; Spielman, R. B.; Krasik, Ya. E.

2018-05-01

A major experimental research area in material equation-of-state today involves the use of off-Hugoniot measurements rather than shock experiments that give only Hugoniot data. There is a wide range of applications using quasi-isentropic compression of matter including the direct measurement of the complete isentrope of materials in a single experiment and minimizing the heating of flyer plates for high-velocity shock measurements. We propose a novel approach to generating quasi-isentropic compression of matter. Using analytical modeling and hydrodynamic simulations, we show that a working fluid composed of compressed water, generated by an underwater electrical explosion of a planar wire array, might be used to efficiently drive the quasi-isentropic compression of a copper target to pressures ˜2 × 1011 Pa without any complex target designs.

Brownfields and health risks--air dispersion modeling and health risk assessment at landfill redevelopment sites.

PubMed

Ofungwu, Joseph; Eget, Steven

2006-07-01

Redevelopment of landfill sites in the New Jersey-New York metropolitan area for recreational (golf courses), commercial, and even residential purposes seems to be gaining acceptance among municipal planners and developers. Landfill gas generation, which includes methane and potentially toxic nonmethane compounds usually continues long after closure of the landfill exercise phase. It is therefore prudent to evaluate potential health risks associated with exposure to gas emissions before redevelopment of the landfill sites as recreational, commercial, and, especially, residential properties. Unacceptably high health risks would call for risk management measures such as limiting the development to commercial/recreational rather than residential uses, stringent gas control mechanisms, interior air filtration, etc. A methodology is presented for applying existing models to estimate residual landfill hazardous compounds emissions and to quantify associated health risks. Besides the toxic gas constituents of landfill emissions, other risk-related issues concerning buried waste, landfill leachate, and explosive gases were qualitatively evaluated. Five contiguously located landfill sites in New Jersey intended for residential and recreational redevelopment were used to exemplify the approach.

Acoustic Full Waveform Inversion to Characterize Near-surface Chemical Explosions

NASA Astrophysics Data System (ADS)

Kim, K.; Rodgers, A. J.

2015-12-01

Recent high-quality, atmospheric overpressure data from chemical high-explosive experiments provide a unique opportunity to characterize near-surface explosions, specifically estimating yield and source time function. Typically, yield is estimated from measured signal features, such as peak pressure, impulse, duration and/or arrival time of acoustic signals. However, the application of full waveform inversion to acoustic signals for yield estimation has not been fully explored. In this study, we apply a full waveform inversion method to local overpressure data to extract accurate pressure-time histories of acoustics sources during chemical explosions. A robust and accurate inversion technique for acoustic source is investigated using numerical Green's functions that take into account atmospheric and topographic propagation effects. The inverted pressure-time history represents the pressure fluctuation at the source region associated with the explosion, and thus, provides a valuable information about acoustic source mechanisms and characteristics in greater detail. We compare acoustic source properties (i.e., peak overpressure, duration, and non-isotropic shape) of a series of explosions having different emplacement conditions and investigate the relationship of the acoustic sources to the yields of explosions. The time histories of acoustic sources may refine our knowledge of sound-generation mechanisms of shallow explosions, and thereby allow for accurate yield estimation based on acoustic measurements. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.

Design of a novel instrument for active neutron interrogation of artillery shells.

PubMed

Bélanger-Champagne, Camille; Vainionpää, Hannes; Peura, Pauli; Toivonen, Harri; Eerola, Paula; Dendooven, Peter

2017-01-01

The most common explosives can be uniquely identified by measuring the elemental H/N ratio with a precision better than 10%. Monte Carlo simulations were used to design two variants of a new prompt gamma neutron activation instrument that can achieve this precision. The instrument features an intense pulsed neutron generator with precise timing. Measuring the hydrogen peak from the target explosive is especially challenging because the instrument itself contains hydrogen, which is needed for neutron moderation and shielding. By iterative design optimization, the fraction of the hydrogen peak counts coming from the explosive under interrogation increased from [Formula: see text]% to [Formula: see text]% (statistical only) for the benchmark design. In the optimized design variants, the hydrogen signal from a high-explosive shell can be measured to a statistics-only precision better than 1% in less than 30 minutes for an average neutron production yield of 109 n/s.

Design of a novel instrument for active neutron interrogation of artillery shells

PubMed Central

Vainionpää, Hannes; Peura, Pauli; Toivonen, Harri; Eerola, Paula; Dendooven, Peter

2017-01-01

The most common explosives can be uniquely identified by measuring the elemental H/N ratio with a precision better than 10%. Monte Carlo simulations were used to design two variants of a new prompt gamma neutron activation instrument that can achieve this precision. The instrument features an intense pulsed neutron generator with precise timing. Measuring the hydrogen peak from the target explosive is especially challenging because the instrument itself contains hydrogen, which is needed for neutron moderation and shielding. By iterative design optimization, the fraction of the hydrogen peak counts coming from the explosive under interrogation increased from 53-7+7% to 74-10+8% (statistical only) for the benchmark design. In the optimized design variants, the hydrogen signal from a high-explosive shell can be measured to a statistics-only precision better than 1% in less than 30 minutes for an average neutron production yield of 109 n/s. PMID:29211773

Spectral signatures for RDX-based explosives in the 3 micron region

NASA Astrophysics Data System (ADS)

Osborn, Tabetha; Kaimal, Sindhu; Reeve, Scott W.; Burns, William

2008-04-01

Explosive compounds such as RDX, and HMX present significant challenges to optically based sensors. This difficulty is due in part to the low vapor pressures these compounds possess. One approach for sensing explosives that circumvents the low explosive vapor pressure problem, involves focusing on the trace amounts of relatively high vapor pressure impurities that will be present in the vapor signature. In order to effectively detect these volatile impurities, the spectral signature databases must be readily available. One of our goals therefore, is the generation of a database of high resolution spectral signatures for these volatile organic impurities. Some rather formidable spectroscopic measurement challenges have been encountered while working to extend the spectral signature effort to the 3 micron region. Here we will outline progress to date, with a focus on the volatile organic compounds formaldehyde, acetaldehyde, nitromethane, acetone, isobutene, and cyclohexanone.

PINS Testing and Modification for Explosive Identification

DOE Office of Scientific and Technical Information (OSTI.GOV)

E.H. Seabury; A.J. Caffrey

2011-09-01

The INL's Portable Isotopic Neutron Spectroscopy System (PINS)1 non-intrusively identifies the chemical fill of munitions and sealed containers. PINS is used routinely by the U.S. Army, the Defense Threat Reduction Agency, and foreign military units to determine the contents of munitions and other containers suspected to contain explosives, smoke-generating chemicals, and chemical warfare agents such as mustard and nerve gas. The objects assayed with PINS range from softball-sized M139 chemical bomblets to 200 gallon DOT 500X ton containers. INL had previously examined2 the feasibility of using a similar system for the identification of explosives, and based on this proof-of-principle test,more » the development of a dedicated system for the identification of explosives in an improvised nuclear device appears entirely feasible. INL has been tasked by NNSA NA-42 Render Safe Research and Development with the development of such a system.« less

Explosive east coast cyclogenesis over the west-central North Atlantic Ocean - A composite study derived from ECMWF operational analyses

NASA Technical Reports Server (NTRS)

Manobianco, John

1989-01-01

This paper describes the observational aspects of explosive east-coast cyclogenesis using composites constructed from the daily global analyses generated and archived by ECMWF. An explosively deepening storm or bomb is defined as an extratropical cyclone whose mean sea-level pressure falls at least 1 mb/h for 24 h. The ECMWF data sets are used to examine the three-dimensional kinematic and thermodynamic structure of bombs over the entire depth of the troposphere. The evolution and structure of the composite bomb is diagnosed using a moving coordinate system consisting of a box with dimensions of 35 x 35 deg of latitude-longitude. The results reveal that explosive cyclogenesis is a baroclinic phenomenon in which the rapid development in the presence of strong upper tropospheric forcing is most likely enhanced by a highly destabilized lower troposphere.

Design and Testing of the ARL Squeeze 4 Helical Flux Compression Generator

DTIC Science & Technology

2013-06-01

armature makes contact. Centering the armature inside the coil was accomplished with three machined polyurethane (4 lb/ft3 Lastafoam)3 foam rings. A...after shrinking was ~1 mm thick. The explosive charge was comprised of a paper- reinforced phenolic cylinder filled with Comp-B explosive fill. The...backfilled with polyester resin. Foam rubber was placed between coil windings (figure 3a). All other subsequent experiments used a custom rapid-prototyped

Advances in Explosively Formed Fuse Opening Switches

DTIC Science & Technology

1987-06-01

ADVANCES IN EXPLOSIVELY FORMED FUSE OPENING SWITCHES* J. H. Goforth, R. S. Caird, A. E. Greene, I. R. Lindemuth, S. P. Marsh, H. Oona, and R. E...conductor into a series of thin sections. Augmented by an undetermined amount of heating due to the extrusion process, Joule heating in the thin...with initial field fed directly into the generator by a capacitor bank. As described in Ref. 2, these tests demonstrated that the switch would

Computational Simulation of Explosively Generated Pulsed Power Devices

DTIC Science & Technology

2013-03-21

to practical applications. These are the magnetic flux compression generators (FCG), ferromagnetic generators (FMG) and ferroelectric generators (FEG...The first device works on the concept of field interaction between a conducting medium and a magnetic field. The last two devices make use of either... magnetic or electric fields stored in a prepared material (4). This research will focus on the ferroelectric generator as a high voltage source for

Initiation of insensitive explosives by laser energy

NASA Technical Reports Server (NTRS)

Menichelli, V. J.; Yang, L. C.

1972-01-01

Instantaneous longitudinal detonations were observed in confined columns of pentaerythritol tetranitrate (PETN), cyclotrimethylene trinitramine (RDX), and tetryl when these materials were pulsed with light energy from a focused Q-switch ruby laser. The laser energy ranged from 0.5 to 4.2 J with a pulse width of 25 ns. Enhancement of the ignition mechanism is hypothesized when a 100-nm (1000-A) thick aluminum film is vacuum-deposited on the explosive side of the window. Upon irradiation from the laser, a shock is generated at the aluminum explosive interface. Steady state detonations can be reached in less than 0.5 microseconds with less than 10% variation in detonation velocity for PETN and RDX.

Method and apparatus for optimized sampling of volatilizable target substances

DOEpatents

Lindgren, Eric R.; Phelan, James M.

2002-01-01

An apparatus for capturing, from gases such as soil gas, target analytes. Target analytes may include emanations from explosive materials or from residues of explosive materials. The apparatus employs principles of sorption common to solid phase microextraction, and is best used in conjunction with analysis means such as a gas chromatograph. To sorb target analytes, the apparatus functions using various sorptive structures to capture target analyte. Depending upon the embodiment, those structures may include 1) a conventional solid-phase microextraction (SPME) fiber, 2) a SPME fiber suspended in a capillary tube (with means provided for moving gases through the capillary tube so that the gases come into close proximity to the suspended fiber), and 3) a capillary tube including an interior surface on which sorptive material (similar to that on the surface of a SPME fiber) is supported (along with means for moving gases through the capillary tube so that the gases come into close proximity to the sorptive material). In one disclosed embodiment, at least one such sorptive structure is associated with an enclosure including an opening in communication with the surface of a soil region potentially contaminated with buried explosive material such as unexploded ordnance. Emanations from explosive materials can pass into and accumulate in the enclosure where they are sorbed by the sorptive structures. Also disclosed is the use of heating means such as microwave horns to drive target analytes into the soil gas from solid and liquid phase components of the soil.

Raman and photothermal spectroscopies for explosive detection

NASA Astrophysics Data System (ADS)

Finot, Eric; Brulé, Thibault; Rai, Padmnabh; Griffart, Aurélien; Bouhélier, Alexandre; Thundat, Thomas

2013-06-01

Detection of explosive residues using portable devices for locating landmine and terrorist weapons must sat- isfy the application criteria of high reproducibility, specificity, sensitivity and fast response time. Vibrational spectroscopies such as Raman and infrared spectroscopies have demonstrated their potential to distinguish the members of the chemical family of more than 30 explosive materials. The characteristic chemical fingerprints in the spectra of these explosives stem from the unique bond structure of each compound. However, these spectroscopies, developed in the early sixties, suffer from a poor sensitivity. On the contrary, MEMS-based chemical sensors have shown to have very high sensitivity lowering the detection limit down to less than 1 picogram, (namely 10 part per trillion) using sensor platforms based on microcantilevers, plasmonics, or surface acoustic waves. The minimum amount of molecules that can be detected depends actually on the transducer size. The selectivity in MEMS sensors is usually realized using chemical modification of the active surface. However, the lack of sufficiently selective receptors that can be immobilized on MEMS sensors remains one of the most critical issues. Microcantilever based sensors offer an excellent opportunity to combine both the infrared photothermal spectroscopy in their static mode and the unique mass sensitivity in their dynamic mode. Optical sensors based on localized plasmon resonance can also take up the challenge of addressing the selectivity by monitoring the Surface Enhanced Raman spectrum down to few molecules. The operating conditions of these promising localized spectroscopies will be discussed in terms of reliability, compactness, data analysis and potential for mass deployment.

Planning for the worst in Washington State: initial response planning for improvised nuclear device explosions.

PubMed

Poeton, Richard W; Glines, Wayne M; McBaugh, Debra

2009-01-01

Since 11 September 2001, improvised nuclear devices have become recognized as an important radiological threat requiring emergency response planning. Although Protective Action Guidance is well established for fixed nuclear facilities, correspondingly well-developed guidance does not exist for nuclear explosions. The Washington State Department of Health has developed preplanned Protective Action Recommendations for improvised nuclear device explosions. These recommendations recognize the need for advice to the public soon after such an event, before significant data are available. They can be used before significant outside support is available locally, and reference observable effects so people can use them if communications were disabled. The recommendations focus on early actions (24-48 h) and place priority on actions to avoid deterministic health effects due to residual fallout. Specific emphasis is placed on determining recommendations for evacuation, as well as the extent of the area for sheltering. The key recommendations developed for an initial public response are: (1) if there is ready access to robust shelter such as an underground basement or interior spaces in a multi-story structure, immediate sheltering in these areas is the best action, regardless of location; (2) if robust shelter is not available, and if fallout is observed in the area, then evacuation is the best general recommendation for locations within 16 km (10 miles) of the explosion; and (3) beyond 16 km (10 miles), the generally recommended protective action is to shelter in the best-protected location which is readily available.

Explosion-Induced Implosions of Cylindrical Shell Structures

NASA Astrophysics Data System (ADS)

Ikeda, C. M.; Duncan, J. H.

2010-11-01

An experimental study of the explosion-induced implosion of cylindrical shell structures in a high-pressure water environment was performed. The shell structures are filled with air at atmospheric pressure and are placed in a large water-filled pressure vessel. The vessel is then pressurized to various levels P∞=αPc, where Pc is the natural implosion pressure of the model and α is a factor that ranges from 0.1 to 0.9. An explosive is then set off at various standoff distances, d, from the model center line, where d varies from R to 10R and R is the maximum radius of the explosion bubble. High-speed photography (27,000 fps) was used to observe the explosion and resulting shell structure implosion. High-frequency underwater blast sensors recorded dynamic pressure waves at 6 positions. The cylindrical models were made from aluminum (diameter D = 39.1 mm, wall thickness t = 0.89 mm, length L = 240 mm) and brass (D = 16.7 mm, t = 0.36 mm, L=152 mm) tubes. The pressure records are interpreted in light of the high-speed movies. It is found that the implosion is induced by two mechanisms: the shockwave generated by the explosion and the jet formed during the explosion-bubble collapse. Whether an implosion is caused by the shockwave or the jet depends on the maximum bubble diameter and the standoff distance.

Trace Detection of RDX, HMX and PETN Explosives Using a Fluorescence Spot Sensor

PubMed Central

Wang, Chen; Huang, Helin; Bunes, Benjamin R.; Wu, Na; Xu, Miao; Yang, Xiaomei; Yu, Li; Zang, Ling

2016-01-01

1,3,5-trinitroperhydro-1,3,5-triazine (RDX), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), and pentaerythritol tetranitrate (PETN), the major components in plastic explosives, pose a significant threat to public safety. A quick, sensitive, and low-cost detection method for these non-volatile explosives is eagerly demanded. Here we present a fluo-spot approach, which can be employed for in situ detection of trace amount of explosives. The sensor molecule is a charge-transfer fluorophore, DCM, which is strongly fluorescent in its pristine state, but non-fluorescent after the quick reaction with NO2· (or NO2+) generated from the UV photolysis of RDX, HMX (or PETN). When fabricated within silica gel TLC plate, the fluo-spot sensor features high sensitivity owing to the large surface area and porous structure of the substrate. The sensor reaction mechanism was verified by various experimental characterizations, including chromatography, UV-Vis absorption and fluorescence spectroscopy, MS and 1H NMR spectrometry. The fluo-spot also demonstrated high selectivity towards RDX, HMX and PETN, as no significant fluorescence quenching was observed for other chemical compounds including common nitro-aromatic explosives and inorganic oxidative compounds. The DCM sensor can also be used as an economical spray kit to directly spot the explosives by naked eyes, implying great potential for quick, low-cost trace explosives detection. PMID:27146290

Trace Detection of RDX, HMX and PETN Explosives Using a Fluorescence Spot Sensor.

PubMed

Wang, Chen; Huang, Helin; Bunes, Benjamin R; Wu, Na; Xu, Miao; Yang, Xiaomei; Yu, Li; Zang, Ling

2016-05-05

1,3,5-trinitroperhydro-1,3,5-triazine (RDX), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), and pentaerythritol tetranitrate (PETN), the major components in plastic explosives, pose a significant threat to public safety. A quick, sensitive, and low-cost detection method for these non-volatile explosives is eagerly demanded. Here we present a fluo-spot approach, which can be employed for in situ detection of trace amount of explosives. The sensor molecule is a charge-transfer fluorophore, DCM, which is strongly fluorescent in its pristine state, but non-fluorescent after the quick reaction with NO2· (or NO2(+)) generated from the UV photolysis of RDX, HMX (or PETN). When fabricated within silica gel TLC plate, the fluo-spot sensor features high sensitivity owing to the large surface area and porous structure of the substrate. The sensor reaction mechanism was verified by various experimental characterizations, including chromatography, UV-Vis absorption and fluorescence spectroscopy, MS and (1)H NMR spectrometry. The fluo-spot also demonstrated high selectivity towards RDX, HMX and PETN, as no significant fluorescence quenching was observed for other chemical compounds including common nitro-aromatic explosives and inorganic oxidative compounds. The DCM sensor can also be used as an economical spray kit to directly spot the explosives by naked eyes, implying great potential for quick, low-cost trace explosives detection.

Low frequency acoustic waves from explosive sources in the atmosphere

NASA Astrophysics Data System (ADS)

Millet, Christophe; Robinet, Jean-Christophe; Roblin, Camille; Gloerfelt, Xavier

2006-11-01

In this study, a perturbative formulation of non linear euler equations is used to compute the pressure variation for low frequency acoustic waves from explosive sources in real atmospheres. Based on a Dispersion-Relation-Preserving (DRP) finite difference scheme, the discretization provides good properties for both sound generation and long range sound propagation over a variety of spatial atmospheric scales. It also assures that there is no wave mode coupling in the numerical simulation The background flow is obtained by matching the comprehensive empirical global model of horizontal winds HWM-93 (and MSISE-90 for the temperature profile) with meteorological reanalysis of the lower atmosphere. Benchmark calculations representing cases where there is downward and upward refraction (including shadow zones), ducted propagation, and generation of acoustic waves from low speed shear layers are considered for validation. For all cases, results show a very good agreement with analytical solutions, when available, and with other standard approaches, such as the ray tracing and the normal mode technique. Comparison of calculations and experimental data from the high explosive ``Misty Picture'' test that provided the scaled equivalent airblast of an 8 kt nuclear device (on May 14, 1987), is also considered. It is found that instability waves develop less than one hour after the wavefront generated by the detonation passes.

Probability of in-vessel steam explosion-induced containment failure for a KWU PWR

DOE Office of Scientific and Technical Information (OSTI.GOV)

Esmaili, H.; Khatib-Rahbar, M.; Zuchuat, O.

During postulated core meltdown accidents in light water reactors, there is a likelihood for an in-vessel steam explosion when the melt contacts the coolant in the lower plenum. The objective of the work described in this paper is to determine the conditional probability of in-vessel steam explosion-induced containment failure for a Kraftwerk Union (KWU) pressurized water reactor (PWR). The energetics of the explosion depends on the mass of the molten fuel that mixes with the coolant and participates in the explosion and on the conversion of fuel thermal energy into mechanical work. The work can result in the generation ofmore » dynamic pressures that affect the lower head (and possibly lead to its failure), and it can cause acceleration of a slug (fuel and coolant material) upward that can affect the upper internal structures and vessel head and ultimately cause the failure of the upper head. If the upper head missile has sufficient energy, it can reach the containment shell and penetrate it. The analysis, must therefore, take into account all possible dissipation mechanisms.« less

Can Plume-Forming Asteroid Airbursts Generate Meteotsunami in Deep Water?

NASA Astrophysics Data System (ADS)

Boslough, M.

2015-12-01

Hydrocode simulations suggest that the 1908 Tunguska explosion was a plume-forming airburst analogous to those caused by Comet Shoemaker-Levy 9 (SL9) collisions with Jupiter in 1994. A noctilucent cloud that appeared over Europe following the Tunguska event is similar to post-impact features on Jupiter, consistent with a collapsed plume containing condensation from the vaporized asteroid. Previous workers treated Tunguska as a point explosion and used seismic records, barograms, and extent of fallen trees to determine explosive yield. Estimates were based on scaling laws derived from nuclear weapons data, neglecting directionality, mass, and momentum of the asteroid. This point-source assumption, with other simplifications, led to a significant overestimate. Tunguska seismic data were consistent with ground motion from a vertical point impulse of 7×1018dyn sec caused by the downward blast wave of a 12.5-megaton nuclear explosion at an altitude of 8.5 km for an effective momentum multiplication factor (β) of ~80. However, simulations of a 3-megaton collisional airburst reveal that the upward-directed momentum contained in a ballistic plume can reach this level within the first minute after the explosion (β≈300). The reaction impulse from such an airburst is therefore similar to a much larger non-plume-forming nuclear explosion. Momentum is coupled through the atmosphere to the surface, generating disproportionately large seismic signatures. This result suggests that coupling from an over-water plume-forming airburst could be a more efficient tsunami source mechanism than a collapsing impact cavity or direct air blast because the characteristic time of the plume is closer to that of a long-period wave in deep water. As the plume accelerates upward, it creates a slowly-rising and sustained overpressure with a ramp wave that propagates outward at the speed of sound, generating a tsunami in deep ocean by the same mechanism that yields slower meteotsunami in shallow basins. This hypothesis is consistent with the observation of prominent internal waves observed propagating radially outward from several SL9 impacts, even though the waves were not in Proudman resonance. Because of slow compression, the SL9 waves grew with a Froude number of ~1.6, the same as that of the sound speed in air over ~4.6-km-deep water.

Spectrophotometric determination of cyclotrimethylenetrinitramine (RDX) in explosive mixtures and residues with the Berthelot reaction.

PubMed

Uzer, A; Erçağ, E; Apak, R

2008-03-31

On-site colorimetric methods are a valuable, cost-effective tool to assess the nature and extent of contamination in remediated sites and to enable on-site screening for police criminology laboratories. The existing colorimetric method for cyclotrimethylenetrinitramine (RDX) based on a Griess reaction suffers from the non-quantitative reduction to nitrite and from the unstable character of HNO2 in acidic medium. Thus we propose a novel spectrophotometric RDX assay in explosive mixtures and residues, based on (Zn+HCl) reduction of RDX in a microwave oven, followed by neutralization of the reduction products to ammonia and low molecular-weight amines, and Berthelot reaction of these amine-compounds with phenol and hypochlorite in alkaline medium to give an intensely blue indophenol dye absorbing at 631nm. The molar absorptivity and limit of detection (LOD) for RDX were (1.08+/-0.04)x10(4) L mol(-1) cm(-1) and 0.18 mg L(-1), respectively. Application of the method to synthetic mixture solutions of RDX and trinitrotoluene (TNT) at varying proportions showed that there was minimal interference from TNT (which could be compensated for by dicyclohexylamine colorimetry), since the Berthelot reaction was essentially non-responsive to m-substituted anilines derived from TNT upon (Zn+HCl) reduction. The proposed method was successfully applied to military-purpose explosive mixtures of (RDX+inert matter) such as Comp A5, Comp C4, and Hexal P30, and to (RDX+TNT) mixtures such as Comp B. The molar absorptivity of RDX was much higher than that of either ammonium or nitrate; RDX could be effectively separated from ammonium and nitrate in soil mixtures, based on solubility differences. The Berthelot method for RDX was statistically validated using Comp B mixtures against standard HPLC equipped with a Hypersil C-18 column with (40% MeOH-60% H2O) mobile phase, and against gas chromatography-thermal energy analysis (GC-TEA) system.

Correlating shaped charge performance with processing conditions and microstructure of an aluminum alloy 1100 liner enabled by a new method to arrest nascent jet formation

NASA Astrophysics Data System (ADS)

Scheid, James Eric

Aluminum-lined shaped charges are used in special applications where jet and / or slug residue in the target is undesired. The three different microstructures of the aluminum liners studied herein resulted from three different manufacturing interpretations of the same design. One interpretation was completely machining the liners from best available annealed round stock. The second was to cold-forge the liners from annealed round-stock in an open-die forge to near-final dimensions, and then machine the liners to the final dimensions. The third variant in this study was to use the above forged liner, but with annealing after the machining. These three manufacturing choices resulted in significant variations in shaped charge performance. The goal of this research was to clarify the relationships between the liner metal microstructure and properties, and the corresponding shaped charge dynamic flow behavior. What began as an investigation into user-reported performance problems associated inherently with liner manufacturing processes and resultant microstructure, resolved into new understandings of the relationships between aluminum liner microstructure and shaped charge collapse kinetics. This understanding was achieved through an extensive literature review and the comprehensive characterization of the material properties of three variants of an 1100 aluminum shaped charge liner with a focus on collapse and nascent jet formation. The machined liner had a microstructure with large millimeter-sized grains and fine particles aligned in bands parallel to the charge axis. The forged liner microstructure consisted of very small one micrometer-sized (1 mum) subgrains and fine particles aligned largely in bands elongated parallel to the liner contour. The annealed liner was characterized by ten micrometer (10 mum) sized equiaxed grains with residual fine particles in the forged alignment. This characterization was enabled by the development, execution and validation of a custom explosive experiment that delivered meaningful, full-scale shock deformed samples for analysis. The experiment arrested the collapse of actual, as-fabricated liners in the first microseconds of development. This experiment, performed with only 2% of the explosive mass of the full charge, revealed new insights into material-dependent variations in liner collapse including a striking image of the formation of a shaped charge jet axial hole. The highly strain-hardened and elongated forged liner was the best performer of the three. Less energy from the explosive was dissipated by dislocation generation. This translated to more efficient flow whereas the softer materials behaved as shock absorbers delaying flow. A set of hypotheses was formulated and critiqued based on these observations. The key findings were the effects of grain size, and shear bands induced in the microstructure through cold work enabled efficient liner flow. These bands provide highly localized dislocation highways enabling the matrix adjacent to the bands to deform plastically at higher velocity. Where such bands are unavailable, the pressure must first develop bands of smaller grains, thus decreasing energy available for flow. Collapse velocities were then associated with the number of shear bands, the organization of mobile dislocations, material strain, and liner geometry. Microstructures with the ability to deform with the direction of liner collapse at lower stresses will form jets with a higher velocity and elongate earlier. The effect is higher performance at shorter standoffs. This relationship can be used to predict material behavior under explosive load, guiding engineering choices while designing with respect to anticipated shock loading. The explosive experiment designed here has obvious application in refining the performance of other warheads, and in the hydrodynamic modeling of material properties.

MINEMOTION3D: A new set of Programs for Predicting Ground Motion From Explosions in Complex 3D Media

NASA Astrophysics Data System (ADS)

Tibuleac, I. M.; Bonner, J. L.; Orrey, J. L.; Yang, X.

2004-12-01

Predicting ground motion from complicated mining explosions is important for mines developing new blasting programs in regions where vibrations must be kept below certain levels. Additionally, predicting ground motion from mining explosions in complex 3D media is important for moment estimation for nuclear test treaty monitoring. Both problems have been addressed under the development of a new series of numerical prediction programs called MINEMOTION3D including 1) Generalized Fourier Methods to generate Green's functions in 3D media for a moment tensor source implementation and 2) MineSeis3D, a program that simulates seismograms for delay-fired mining explosions with a linear relationship between signals from small size individual shots. To test the programs, local recordings (5 - 23 km) of three production shots at a mine in northern Minnesota were compared to synthetic waveforms in 3D media. A non-zero value of the moment tensor component M12 was considered, to introduce a horizontal spall component into the waveform synthesis when the Green's functions were generated for each model. Methods using seismic noise crosscorrelation for improved inter-element subsurface structure estimation were also evaluated. Comparison of the observed and synthetic waveforms shows promising results. The shape and arrival times of the normalized synthetic and observed waveforms are similar for most of the stations. The synthetic and observed waveform amplitude fit is best for the vertical components in the mean 3D model and worst for the transversal components. The observed effect of spall on the waveform spectra was weak in the case of fragmentation delay fired commercial explosions. Commercial applications of the code could provide data needed for designing explosions which do not exceed ground vibration requirements posed by the U.S. Department of the Interior, Office of Surface Mining.

Pyroxene thermometry of rhyolite lavas of the Bruneau-Jarbidge eruptive center, Central Snake River Plain

NASA Astrophysics Data System (ADS)

Cathey, Henrietta E.; Nash, Barbara P.

2009-11-01

The Bruneau-Jarbidge eruptive center of the central Snake River Plain in southern Idaho, USA produced multiple rhyolite lava flows with volumes of <10 km 3 to 200 km 3 each from ~11.2 to 8.1 Ma, most of which follow its climactic phase of large-volume explosive volcanism, represented by the Cougar Point Tuff, from 12.7 to 10.5 Ma. These lavas represent the waning stages of silicic volcanism at a major eruptive center of the Yellowstone hotspot track. Here we provide pyroxene compositions and thermometry results from several lavas that demonstrate that the demise of the silicic volcanic system was characterized by sustained, high pre-eruptive magma temperatures (mostly ≥950 °C) prior to the onset of exclusively basaltic volcanism at the eruptive center. Pyroxenes display a variety of textures in single samples, including solitary euhedral crystals as well as glomerocrysts, crystal clots and annealed microgranular inclusions of pyroxene ± magnetite ± plagioclase. Pigeonite and augite crystals are unzoned, and there are no detectable differences in major and minor element compositions according to textural variety — mineral compositions in the microgranular inclusions and crystal clots are identical to those of phenocrysts in the host lavas. In contrast to members of the preceding Cougar Point Tuff that host polymodal glass and mineral populations, pyroxene compositions in each of the lavas are characterized by single rather than multiple discrete compositional modes. Collectively, the lavas reproduce and extend the range of Fe-Mg pyroxene compositional modes observed in the Cougar Point Tuff to more Mg-rich varieties. The compositionally homogeneous populations of pyroxene in each of the lavas, as well as the lack of core-to-rim zonation in individual crystals suggest that individual eruptions each were fed by compositionally homogeneous magma reservoirs, and similarities with the Cougar Point Tuff suggest consanguinity of such reservoirs to those that supplied the polymodal Cougar Point Tuff. Pyroxene thermometry results obtained using QUILF equilibria yield pre-eruptive magma temperatures of 905 to 980 °C, and individual modes consistently record higher Ca content and higher temperatures than pyroxenes with equivalent Fe-Mg ratios in the preceding Cougar Point Tuff. As is the case with the Cougar Point Tuff, evidence for up-temperature zonation within single crystals that would be consistent with recycling of sub- or near-solidus material from antecedent magma reservoirs by rapid reheating is extremely rare. Also, the absence of intra-crystal zonation, particularly at crystal rims, is not easily reconciled with cannibalization of caldera fill that subsided into pre-eruptive reservoirs. The textural, compositional and thermometric results rather are consistent with minor re-equilibration to higher temperatures of the unerupted crystalline residue from the explosive phase of volcanism, or perhaps with newly generated magmas from source materials very similar to those for the Cougar Point Tuff. Collectively, the data suggest that most of the pyroxene compositional diversity that is represented by the tuffs and lavas was produced early in the history of the eruptive center and that compositions across this range were preserved or duplicated through much of its lifetime. Mineral compositions and thermometry of the multiple lavas suggest that unerupted magmas residual to the explosive phase of volcanism may have been stored at sustained, high temperatures subsequent to the explosive phase of volcanism. If so, such persistent high temperatures and large eruptive magma volumes likewise require an abundant and persistent supply of basalt magmas to the lower and/or mid-crust, consistent with the tectonic setting of a continental hotspot.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Abbas, Syed Haider; Lee, Jung-Ryul; Jang, Jae-Kyeong

Pyroshock can cause failure to the objective of an aerospace structure by damaging its sensitive electronic equipment, which is responsible for performing decisive operations. A pyroshock is the high intensity shock wave that is generated when a pyrotechnic device is explosively triggered to separate, release, or activate structural subsystems of an aerospace architecture. Pyroshock measurement plays an important role in experimental simulations to understand the characteristics of pyroshock on the host structure. This paper presents a technology to measure a pyroshock wave at multiple points using laser Doppler vibrometers (LDVs). These LDVs detect the pyroshock wave generated due to anmore » explosive-based pyrotechnical event. Field programmable gate array (FPGA) based data acquisition is used in the study to acquire pyroshock signals simultaneously from multiple channels. This paper describes the complete system design for multipoint pyroshock measurement. The firmware architecture for the implementation of multichannel data acquisition on an FPGA-based development board is also discussed. An experiment using explosive bolts was configured to test the reliability of the system. Pyroshock was generated using explosive excitation on a 22-mm-thick steel plate. Three LDVs were deployed to capture the pyroshock wave at different points. The pyroshocks captured were displayed as acceleration plots. The results showed that our system effectively captured the pyroshock wave with a peak-to-peak magnitude of 303 741 g. The contribution of this paper is a specialized architecture of firmware design programmed in FPGA for data acquisition of large amount of multichannel pyroshock data. The advantages of the developed system are the near-field, multipoint, non-contact, and remote measurement of a pyroshock wave, which is dangerous and expensive to produce in aerospace pyrotechnic tests.« less

Orbital eccentricity in classical novae

NASA Technical Reports Server (NTRS)

Edwards, D. A.; Pringle, J. E.

1987-01-01

The effect on the orbital parameters of a classical nova of the ejection of mass during the nova explosion is considered. The most easily observable consequence is the generation of a small eccentricity in the orbit which leads to a luminosity modulation at a period just longer than the orbital period. Observation of such an effect would have implications not just for interpreting the dynamics of the explosion but also for measuring the secular effect of tidal interaction after the outburst.

Method of rubblization for in-situ oil shale processing

NASA Technical Reports Server (NTRS)

Yang, Lien C. (Inventor)

1985-01-01

A method that produces a uniformly rubblized oil shale bed of desirable porosity for underground, in-situ heat extraction of oil. Rubblization is the generation of rubble of various sized fragments. The method uses explosive loadings lying at different levels in adjacent holes and detonation of the explosives at different levels in sequence to achieve the fracturing and the subsequent expansion of the fractured oil shale into excavated rooms both above and below the hole pattern.

Explosive eruption, flank collapse and megatsunami at Tenerife ca. 170 ka.

PubMed

Paris, Raphaël; Bravo, Juan J Coello; González, María E Martín; Kelfoun, Karim; Nauret, François

2017-05-15

Giant mass failures of oceanic shield volcanoes that generate tsunamis potentially represent a high-magnitude but low-frequency hazard, and it is actually difficult to infer the mechanisms and dynamics controlling them. Here we document tsunami deposits at high elevation (up to 132 m) on the north-western slopes of Tenerife, Canary Islands, as a new evidence of megatsunami generated by volcano flank failure. Analyses of the tsunami deposits demonstrate that two main tsunamis impacted the coasts of Tenerife 170 kyr ago. The first tsunami was generated during the submarine stage of a retrogressive failure of the northern flank of the island, whereas the second one followed the debris avalanche of the subaerial edifice and incorporated pumices from an on-going ignimbrite-forming eruption. Coupling between a massive retrogressive flank failure and a large explosive eruption represents a new type of volcano-tectonic event on oceanic shield volcanoes and a new hazard scenario.

Magnetocumulative generator

DOEpatents

Pettibone, Joseph S.; Wheeler, Paul C.

1983-01-01

An improved magnetocumulative generator is described that is useful for producing magnetic fields of very high energy content over large spatial volumes. The polar directed pleated magnetocumulative generator has a housing (100, 101, 102, 103, 104, 105) providing a housing chamber (106) with an electrically conducting surface. The chamber (106) forms a coaxial system having a small radius portion and a large radius portion. When a magnetic field is injected into the chamber (106), from an external source, most of the magnetic flux associated therewith positions itself in the small radius portion. The propagation of an explosive detonation through high-explosive layers (107, 108) disposed adjacent to the housing causes a phased closure of the chamber (106) which sweeps most of the magnetic flux into the large radius portion of the coaxial system. The energy content of the magnetic field is greatly increased by flux stretching as well as by flux compression. The energy enhanced magnetic field is utilized within the housing chamber itself.

Magnetocumulative generator

DOEpatents

Pettibone, J.S.; Wheeler, P.C.

1981-06-08

An improved magnetocumulative generator is described that is useful for producing magnetic fields of very high energy content over large spatial volumes. The polar directed pleated magnetocumulative generator has a housing providing a housing chamber with an electrically conducting surface. The chamber forms a coaxial system having a small radius portion and a large radius portion. When a magnetic field is injected into the chamber, from an external source, most of the magnetic flux associated therewith positions itself in the small radius portion. The propagation of an explosive detonation through high-explosive layers disposed adjacent to the housing causes a phased closure of the chamber which sweeps most of the magnetic flux into the large radius portion of the coaxial system. The energy content of the magnetic field is greatly increased by flux stretching as well as by flux compression. The energy enhanced magnetic field is utilized within the housing chamber itself.

Impact-generated Tsunamis: An Over-rated Hazard

NASA Technical Reports Server (NTRS)

Melosh, H. J.

2003-01-01

A number of authors have suggested that oceanic waves (tsunami) created by the impact of relatively small asteroids into the Earth's oceans might cause widespread devastation to coastal cities. If correct, this suggests that asteroids > 100 m in diameter may pose a serious hazard to humanity and could require a substantial expansion of the current efforts to identify earth-crossing asteroids > 1 km in diameter. The debate on this hazard was recently altered by the release of a document previously inaccessible to the scientific community. In 1968 the US Office of Naval Research commissioned a summary of several decades of research into the hazard proposed by waves generated by nuclear explosions in the ocean. Authored by tsunami expert William Van Dorn, this 173-page report entitled Handbook of Explosion-Generated Water Waves affords new insight into the process of impact wave formation, propagation, and run up onto the shoreline.

Macroparticle generation in DC arc discharge from a WC cathode

NASA Astrophysics Data System (ADS)

Zhirkov, Igor; Polcik, Peter; Kolozsvári, Szilard; Rosen, Johanna

2017-03-01

We have studied macroparticle generation from a tungsten carbide cathode used in a dc vacuum arc discharge. Despite a relatively high decomposition/melting point (˜3100 K), there is an intensive generation of visible particles with sizes in the range 20-35 μm. Visual observations during the discharge and scanning electron microscopy of the cathode surface and of collected macroparticles indicate a new mechanism for particle formation and acceleration. Based on the W-C phase diagram, there is an intensive sublimation of carbon from the melt resulting from the cathode spot. The sublimation supports the formation of a sphere, which is accelerated upon an explosion initiated by Joule heating at the critical contact area between the sphere and the cathode body. The explosive nature of the particle acceleration is confirmed by surface features resembling the remains of a splash on the droplet surface.

APSTNG: neutron interrogation for detection of explosives, drugs, and nuclear and chemical warfare materials

NASA Astrophysics Data System (ADS)

Rhodes, Edgar A.; Peters, Charles W.

1993-02-01

A recently developed neutron diagnostic probe system has the potential to satisfy a significant number of van-mobile and fixed-portal requirements for nondestructive detection, including monitoring of contraband explosives, drugs, and weapon materials, and treaty verification of sealed munitions. The probe is based on a unique associated-particle sealed-tube neutron generator (APSTNG) that interrogates the object of interest with a low-intensity beam of 14- MeV neutrons generated from the deuterium-tritium reaction and that detects the alpha-particle associated with each neutron. Gamma-ray spectra of resulting neutron reactions identify nuclides associated with all major chemicals in explosives, drugs, and chemical warfare agents, as well as many pollutants and fissile and fertile special nuclear material. Flight times determined from detection times of the gamma-rays and alpha-particles yield a separate coarse tomographic image of each identified nuclide. The APSTNG also forms the basis for a compact fast-neutron transmission imaging system that can be used along with or instead of the emission imaging system. Proof-of-concept experiments have been performed under laboratory conditions for simulated nuclear and chemical warfare munitions and for explosives and drugs. The small and relatively inexpensive APSTNG exhibits high reliability and can be quickly replaced. Surveillance systems based on APSTNG technology can avoid the large physical size, high capital and operating expenses, and reliability problems associated with complex accelerators.

Novel high-fidelity realistic explosion damage simulation for urban environments

NASA Astrophysics Data System (ADS)

Liu, Xiaoqing; Yadegar, Jacob; Zhu, Youding; Raju, Chaitanya; Bhagavathula, Jaya

2010-04-01

Realistic building damage simulation has a significant impact in modern modeling and simulation systems especially in diverse panoply of military and civil applications where these simulation systems are widely used for personnel training, critical mission planning, disaster management, etc. Realistic building damage simulation should incorporate accurate physics-based explosion models, rubble generation, rubble flyout, and interactions between flying rubble and their surrounding entities. However, none of the existing building damage simulation systems sufficiently faithfully realize the criteria of realism required for effective military applications. In this paper, we present a novel physics-based high-fidelity and runtime efficient explosion simulation system to realistically simulate destruction to buildings. In the proposed system, a family of novel blast models is applied to accurately and realistically simulate explosions based on static and/or dynamic detonation conditions. The system also takes account of rubble pile formation and applies a generic and scalable multi-component based object representation to describe scene entities and highly scalable agent-subsumption architecture and scheduler to schedule clusters of sequential and parallel events. The proposed system utilizes a highly efficient and scalable tetrahedral decomposition approach to realistically simulate rubble formation. Experimental results demonstrate that the proposed system has the capability to realistically simulate rubble generation, rubble flyout and their primary and secondary impacts on surrounding objects including buildings, constructions, vehicles and pedestrians in clusters of sequential and parallel damage events.

Standoff detection of explosives: critical comparison for ensuing options on Raman spectroscopy-LIBS sensor fusion.

PubMed

Moros, J; Lorenzo, J A; Laserna, J J

2011-07-01

In general, any standoff sensor for the effective detection of explosives must meet two basic requirements: first, a capacity to detect the response generated from only a small amount of material located at a distance of several meters (high sensitivity) and second, the ability to provide easily distinguishable responses for different materials (high specificity). Raman spectroscopy and laser-induced breakdown spectroscopy (LIBS) are two analytical techniques which share similar instrumentation and, at the same time, generate complementary data. These factors have been taken into account recently for the design of sensors used in the detection of explosives. Similarly, research on the proper integration of both techniques has been around for a while. A priori, the different operational conditions required by the two techniques oblige the acquisition of the response for each sensor through sequential analysis, previously necessary to define the proper hierarchy of actuation. However, such an approach does not guarantee that Raman and LIBS responses obtained may relate to each other. Nonetheless, the possible advantages arising from the integration of the molecular and elemental spectroscopic information come with an obvious underlying requirement, simultaneous data acquisition. In the present paper, strong and weak points of Raman spectroscopy and LIBS for solving explosives detection problems, in terms of selectivity, sensitivity, and throughput, are critically examined, discussed, and compared for assessing the ensuing options on the fusion of the responses of both sensing technologies.

Computational Hydrocode Study of Target Damage due to Fragment-Blast Impact

DOE Office of Scientific and Technical Information (OSTI.GOV)

Hatch-Aguilar, T; Najjar, F; Szymanski, E

2011-03-24

A target's terminal ballistic effects involving explosively generated fragments, along with the original blast, are of critical importance for many different security and safety related applications. Personnel safety and protective building design are but a few of the practical disciplines that can gain from improved understanding combined loading effects. Traditionally, any engineering level analysis or design effort involving explosions would divide the target damage analysis into two correspondingly critical areas: blast wave and fragment related impact effects. The hypothesis of this paper lies in the supposition that a linear combination of a blast-fragment loading, coupled with an accurate target responsemore » description, can lead to a non-linear target damage effect. This non-linear target response could then stand as the basis of defining what a synergistic or combined frag-blast loading might actually look like. The table below, taken from Walters, et. al. categorizes some of the critical parameters driving any combined target damage effect and drives the evaluation of results. Based on table 1 it becomes clear that any combined frag-blast analysis would need to account for the target response matching similar ranges for the mechanics described above. Of interest are the critical times upon which a blast event or fragment impact loading occurs relative to the target's modal response. A blast, for the purposes of this paper is defined as the sudden release of chemical energy from a given material (henceforth referred to as an energetic material) onto its surrounding medium. During the coupling mechanism a discrete or discontinuous shockwave is generated. This shockwave travels outward from the source transferring energy and momentum to any surrounding objects including personnel and engineering structures. From an engineering perspective blast effects are typically characterized by way of physical characteristics such as Peak Pressure (PP), Time of Arrival (TOA), Pressure-Impulse (PI) and Time of Duration (TD). Other peculiarities include the radial decrease in pressure from the source, any fireball size measurement, and subsequent increase in temperature from the passing of the shockwave through the surrounding medium. In light of all of these metrics, the loading any object receives from a blast event becomes intricately connected to the distance between itself and the source. Because of this, a clear distinction is made between close-in effects and those from a source far away from the object of interest. Explosively generated fragments on the other hand are characterized by means of their localized damage potential. Metrics such as whether the fragment penetrates or perforates a given object is quantified as well as other variables including fragment's residual velocity, % kinetic energy decrease, residual fragment mass and other exit criteria. A fragment launched under such violent conditions could easily be traveling at speeds in excess of 2500 ft/s. Given these speeds it is conceivable to imagine how any given fragment could deliver a concentrated load to a target and penetrates through walls, vehicles or even the protection systems of nearby personnel. This study will focus on the individual fragment-target impact event with the hopes of expanding it to eventually include statistical procedures. Since this is a modeling excursion into the combined frag-blast target damage effects the numerical methods used to frame this problem become important in-so-far as the simulations are done in a consistent manner. For this study a Finite-Element based Hydrocode solution called ALE3D (ALE=Arbitrary Lagrangian-Eulerian) was utilized. ALE3D is developed by Lawrence Livermore National Laboratory (Livermore, CA), and as this paper will show, successfully implemented a converged ALE formulation including as many of the different aspects needed to query the synergistic damage on a given target. Further information on the modeling setup is included.« less

Convergence of shock waves generated by underwater electrical explosion of cylindrical wire arrays between different boundary geometries

DOE Office of Scientific and Technical Information (OSTI.GOV)

Yanuka, D.; Zinowits, H. E.; Krasik, Ya. E.

The results of experiments and numerical simulations of a shock wave propagating between either conical or parabolic bounding walls are presented. The shock wave was generated by a microsecond timescale underwater electrical explosion of a cylindrical wire array supplied by a current pulse having an amplitude of ∼230 kA and a rise time of ∼1 μs. It is shown that with the same energy density deposition into the exploding wire array, the shock wave converges faster between parabolic walls, and as a result, the pressure in the vicinity of convergence is ∼2.3 times higher than in the case of conical walls. Themore » results obtained are compared to those of earlier experiments [Antonov et al., Appl. Phys. Lett. 102, 124104 (2013)] with explosions of spherical wire arrays. It is shown that at a distance of ∼400 μm from the implosion origin the pressure obtained in the current experiments is higher than for the case of spherical wire arrays.« less

Analysis of Xrage and Flag High Explosive Burn Models with PBX 9404 Cylinder Tests

NASA Astrophysics Data System (ADS)

Harrier, Danielle; Fessenden, Julianna; Ramsey, Scott

2016-11-01

High explosives are energetic materials that release their chemical energy in a short interval of time. They are able to generate extreme heat and pressure by a shock driven chemical decomposition reaction, which makes them valuable tools that must be understood. This study investigated the accuracy and performance of two Los Alamos National Laboratory hydrodynamic codes, which are used to determine the behavior of explosives within a variety of systems: xRAGE which utilizes an Eulerian mesh, and FLAG with utilizes a Lagrangian mesh. Various programmed and reactive burn models within both codes were tested, using a copper cylinder expansion test. The test was based off of a recent experimental setup which contained the plastic bonded explosive PBX 9404. Detonation velocity versus time curves for this explosive were obtained from the experimental velocity data collected using Photon Doppler Velocimetry (PDV). The modeled results from each of the burn models tested were then compared to one another and to the experimental results using the Jones-Wilkins-Lee (JWL) equation of state parameters that were determined and adjusted from the experimental tests. This study is important to validate the accuracy of our high explosive burn models and the calibrated EOS parameters, which are important for many research topics in physical sciences.

New impact sensitivity test of liquid explosives

NASA Astrophysics Data System (ADS)

Tiutiaev, Andrei; Trebunskih, Valeri

The sensitivity of liquid explosive in the presence of gas bubbles increases many times as compared with the liquid without gas bubbles. Local hot spot in this case formed as a result of compression and heating of the gas inside the bubbles. If we consider that in the liquid as a result of convection, wave motion, shock, etc. gas bubbles are easily generated, the need to develop a method for determining sensitivity of liquid explosives to impact and a detailed study of the ignition explosives with bubbles is obvious. On a mathematical model of a single steam bubbles in the fluid theoretically considered the process of initiating explosive liquid systems to impact. For the experimental investigation, the well-known K-44 -II with the metal cap were used. Instead of the metal cap in the standard method in this paper there was polyurethane foam cylindrical container with LHE, which is easily deforms by impact. A large number of tests with different liquid explosives were made. It was found that the test LHE to impact with polyurethane foam to a large extent reflect the real mechanical sensitivity due to the small loss of impact energy on the deformation of the metal cap, as well as the best differentiation LHE sensitivity due to the higher resolution method . Results obtained in the samara state technical university.

Manipulating explosive sensitivity through structural modifications in a nitrate ester system

NASA Astrophysics Data System (ADS)

Manner, Virginia

2017-06-01

Understanding how condensed phase effects influence sensitivity is essential for developing next generation insensitive high explosives. However, the ability to predictably manipulate explosive sensitivity remains an elusive goal. Explosive sensitivity has been suggested to be governed by multiple factors, from intramolecular effects such as bond dissociation energy, oxygen balance, and the electrostatic potential of reactive functional groups, to larger scale effects, such as crystal structure and hot spot formation. We have developed derivatives of the explosive pentaerythritol tetranitrate (PETN) and examined them experimentally and theoretically, in order to better understand which properties influence sensitivity. With this molecular framework, we can evaluate how small changes to the structure of the molecule influence qualities such as oxygen balance, heat of formation, heat capacity, compressibility, crystal packing, and hydrogen bonding, through techniques such as differential scanning calorimetry, x-ray crystallography, and atomistic simulation. We have also used small-scale sensitivity testing as an initial tool to screen for large and consistent differences in handling sensitivity. We will discuss the many factors that contribute to sensitivity in this series of systematically-modified molecules as well as in existing well-studied explosive systems, such as triaminotrinitrobenzene (TATB) and nitroglycerin (NG). In collaboration with: Thomas Myers, Marc Cawkwell, Edward Kober, Bryce Tappan, Geoffrey Brown, Mary Sandstrom, LOS ALAMOS NATL LAB.

Patterns of volcanotectonic seismicity and stress during the ongoing eruption of the Soufrière Hills Volcano, Montserrat (1995-2007)

USGS Publications Warehouse

Roman, D.C.; De Angelis, S.; Latchman, J.L.; White, Rickie

2008-01-01

The ongoing eruption of the Soufrière Hills Volcano, Montserrat, has been accompanied throughout by varying levels of high-frequency, ‘volcanotectonic’ (VT), seismicity. These earthquakes reflect the brittle response of the host rock to stresses generated within the magmatic system and thus reveal interesting and useful information about the structure of the volcanic conduit system and processes occurring within it. In general, systematic changes in the rate, location, and fault-plane solutions of VT earthquakes correspond to changes in the volcano's behavior, and indicate that the main conduit for the eruption is a dike or system of dikes trending NE–SW and centered beneath the eruptive vent. To date, the eruption has comprised three extrusive phases, separated by two ~ 1–2 year-long periods of residual activity. Prior to the start of each extrusive phase, VT earthquakes with fault-plane solution p-axes oriented perpendicular to inferred regional maximum compression dominate the data set, consistent with stresses induced by the inflation of the mid-level conduit system. ~ 90°-rotated VT fault-plane solutions are also observed preceding a change in eruption style from effusive to explosive in 1997. While increases in the rate of VT earthquakes precede eruption phase onsets, high rates of VT seismicity are also observed during the first period of residual activity and in this case appear to reflect the relaxation of host rock following withdrawal of magma from the mid-crustal system. Most VT earthquakes are located directly beneath the eruptive vent, although two ‘distal VT clusters’ were observed during the first six months of the eruption (late 1995–early 1996). Both of these distal clusters likely resulted from stresses generated during the establishment of the main conduit system.

The Making of a Generation.

ERIC Educational Resources Information Center

Levine, Arthur

1993-01-01

Group interviews with college undergraduates revealed five social and political events that they felt had most influenced their generation: the "Challenger" shuttle explosion; the end of the Cold War; the Persian Gulf War; the Acquired Immune Deficiency Syndrome (AIDS) epidemic; and the Rodney King beating and subsequent trials. (MSE)

Toxicity and bioconcentration evaluation of RDX and HMX using sheepshead minnows in water exposures.

PubMed

Lotufo, Guilherme R; Gibson, Alfreda B; Yoo, J Leslie

2010-10-01

Lethal effects of the explosives RDX and HMX were assessed using ten-day water exposures to juvenile sheepshead minnows (Cyprinodon variegatus). For RDX, maximum mortality occurred during the first two days of exposure with a 10-d median lethal concentration (LC50) of 9.9 mg L(-1). The RDX 10-d median lethal residue (LR50) was 9.6 mg kg(-1) (34.9 μmol kg(-1)) wet weight (ww), the first RDX critical body residue reported for fish. Previous investigations reported that RDX body residues in marine amphipods up to 96 μmol kg(-1) ww and in marine mussels up to 86 μmol kg(-1) ww failed to result in significant mortality. The highest HMX concentration tested, corresponding to its apparent solubility limit in seawater (2.0 mg L(-1)), and the associated mean body residue (3 mg kg(-1) or 14 μmol kg(-1) ww) resulted in no significant mortality for exposed minnows. The mean 10-d bioconcentration factors for RDX (0.6-0.9 L kg(-1)) and HMX (0.3-1.6 L kg(-1)) were typically lower than 1, reflecting the low bioaccumulative potential for these compounds. Published by Elsevier Inc.

Explosive origin of silicic lava: Textural and δD-H2O evidence for pyroclastic degassing during rhyolite effusion

NASA Astrophysics Data System (ADS)

Castro, Jonathan M.; Bindeman, Ilya N.; Tuffen, Hugh; Ian Schipper, C.

2014-11-01

A long-standing challenge in volcanology is to explain why explosive eruptions of silicic magma give way to lava. A widely cited idea is that the explosive-to-effusive transition manifests a two-stage degassing history whereby lava is the product of non-explosive, open-system gas release following initial explosive, closed-system degassing. Direct observations of rhyolite eruptions indicate that effusive rhyolites are in fact highly explosive, as they erupt simultaneously with violent volcanic blasts and pyroclastic fountains for months from a common vent. This explosive and effusive overlap suggests that pyroclastic processes play a key role in rendering silicic magma sufficiently degassed to generate lava. Here we use precise H-isotope and magmatic H2O measurements and textural evidence to demonstrate that effusion results from explosion(s)-lavas are the direct product of brittle deformation that fosters batched degassing into transient pyroclastic channels (tuffisites) that repetitively and explosively vent from effusing lava. Our measurements show, specifically that D/H ratios and H2O contents of a broad suite of explosive and effusive samples from Chaitén volcano (hydrous bombs, Plinian pyroclasts, tuffisite veins, and lava) define a single and continuous degassing trend that links wet explosive pyroclasts (∼ 1.6 wt.% H2O, δD = - 76.4 ‰) to dry obsidian lavas (∼ 0.13 wt.% H2O, δD = - 145.7 ‰). This geochemical pattern is best fit with batched degassing model that comprises small repeated closed-system degassing steps followed by pulses of vapour extraction. This degassing mechanism is made possible by the action of tuffisite veins, which, by tapping already vesicular or brecciated magma, allow batches of exsolved gas to rapidly and explosively escape from relatively isolated closed-system domains and large tracts of conduit magma by giving them long-range connectivity. Even though tuffisite veins render magma degassed and capable of effusing, they are nonetheless the avenues of violent gas and particle transport and thus have the potential to drive explosions when they become blocked or welded shut. Thus the effusion of silicic lava, traditionally thought to be relatively benign process, presents a particularly hazardous form of explosive volcanism.

Stability of imploding shocks generated by underwater electrical explosion of cylindrical wire array

DOE Office of Scientific and Technical Information (OSTI.GOV)

Kozlov, M.; Gurovich, V. Tz.; Krasik, Ya. E.

2013-11-15

The results of two-dimensional hydrodynamic simulations of the dynamics and stability of azimuthal non-uniformities in converging shock waves generated by an underwater explosion of a cylindrical wire array and their effect on the cumulation of energy in the vicinity of the converging axis are presented. It has been shown that in spite of the fact that such non-uniformities are always weakly unstable, for a broad range of experimentally relevant regimes these non-uniformities remain small and do not significantly affect the cumulation of energy. Only the non-uniformities with wavelengths comparable to the distance from the axis of convergence exhibit substantial growthmore » that considerably attenuates the energy cumulation.« less

Management of the orbital environment

NASA Technical Reports Server (NTRS)

Loftus, Joseph P., Jr.; Kessler, Donald J.; Anz-Meador, Phillip D.

1991-01-01

Data regarding orbital debris are presented to shed light on the requirements of environmental management in space, and strategies are given for active intervention and operational strategies. Debris are generated by inadvertent explosions of upper stages, intentional military explosions, and collisional breakups. Design and operation practices are set forth for minimizing debris generation and removing useless debris from orbit in the low-earth and geosynchronous orbits. Self-disposal options include propulsive maneuvers, drag-augmentation devices, and tether systems, and the drag devices are described as simple and passive. Active retrieval and disposition are considered, and the difficulty is examined of removing small debris. Active intervention techniques are required since pollution prevention is more effective than remediation for the problems of both earth and space.

Source mechanisms of volcanic tsunamis.

PubMed

Paris, Raphaël

2015-10-28

Volcanic tsunamis are generated by a variety of mechanisms, including volcano-tectonic earthquakes, slope instabilities, pyroclastic flows, underwater explosions, shock waves and caldera collapse. In this review, we focus on the lessons that can be learnt from past events and address the influence of parameters such as volume flux of mass flows, explosion energy or duration of caldera collapse on tsunami generation. The diversity of waves in terms of amplitude, period, form, dispersion, etc. poses difficulties for integration and harmonization of sources to be used for numerical models and probabilistic tsunami hazard maps. In many cases, monitoring and warning of volcanic tsunamis remain challenging (further technical and scientific developments being necessary) and must be coupled with policies of population preparedness. © 2015 The Author(s).

Analysis of dynamics of vulcanian activity of Ubinas volcano, using multicomponent seismic antennas

NASA Astrophysics Data System (ADS)

Inza, L. A.; Métaxian, J. P.; Mars, J. I.; Bean, C. J.; O'Brien, G. S.; Macedo, O.; Zandomeneghi, D.

2014-01-01

A series of 16 vulcanian explosions occurred at Ubinas volcano between May 24 and June 14, 2009. The intervals between explosions were from 2.1 h to more than 6 days (mean interval, 33 h). Considering only the first nine explosions, the average time interval was 7.8 h. Most of the explosions occurred after a short time interval (< 8 h) and had low energy, which suggests that the refilling time was not sufficient for large accumulation of gas. A tremor episode followed 75% of the explosions, which coincided with pulses of ash emission. The durations of the tremors following the explosions were longer for the two highest energy explosions. To better understand the physical processes associated with these eruptive events, we localized the sources of explosions using two seismic antennas that were composed of three-component 10 and 12 sensors. We used the high-resolution MUSIC-3C algorithm to estimate the slowness vector for the first waves that composed the explosion signals recorded by the two antennas assuming propagation in a homogeneous medium. The initial part of the explosions was dominated by two frequencies, at 1.1 Hz and 1.5 Hz, for which we identified two separated sources located at 4810 m and 3890 m +/- 390 altitude, respectively. The position of these two sources was the same for the full 16 explosions. This implies the reproduction of similar mechanisms in the conduit. Based on the eruptive mechanisms proposed for other volcanoes of the same type, we interpret the position of these two sources as the limits of the conduit portion that was involved in the fragmentation process. Seismic data and ground deformation recorded simultaneously less than 2 km from the crater showed a decompression movement 2 s prior to each explosion. This movement can be interpreted as gas leakage at the level of the cap before its destruction. The pressure drop generated in the conduit could be the cause of the fragmentation process that propagated deeper. Based on these observations, we interpret the position of the highest source as the part of the conduit under the cap, and the deeper source as the limit of the fragmentation zone.

Laser-Induced Breakdown Spectroscopy for Detection of Explosives Residues: A Review of Recent Advances, Challenges, and Future Prospects

DTIC Science & Technology

2013-04-01

for discrimination [14, 15, 17]. Both Anzano et al . [18] and Tran et al . [21] analyzed the emission intensity ratios of several organic compounds for...A PC displays and ana- lyzes the recorded spectra, which are characteristic of the target material 284 J.L. Gottfried et al . The successful detection...energetic organic compounds 286 J.L. Gottfried et al . and experimental configuration. Several theoretical models have recently been developed to

Marine Casualty Report. Tankship Puerto Rican O.N. 535000, Explosion and Fire in the Pacific Ocean, on 31 October 1984 with Loss of Life.

DTIC Science & Technology

1985-06-15

Guard has "S " initiated a regulatory project which will clarify the intent of the regulations at 33 CFR 157.11(a) regarding fixed piping systems for...transferring cargo residues. Recommendation 6. This recommendation is concurred with. The Chief of the Survival Systems Branch has written the San...Francisco Bar Pilots Association * requesting information on their man overboard recovery system . Upon receipt of this information, the Coast Guard will

Treatment of Explosives Residues From Range Activities

DTIC Science & Technology

2010-01-01

plus 5 kg crude soybean oil), while three plots served as controls and received no PMSO (designated CON ). PMSO was prepared by thoroughly mixing...compounds. The topmost layers of soil in the CON plots were removed in 1.25 cm lifts. The PMSO in the PO1 and PO2 plots was collected in two portions...soil plots ( CON -2) was not behaving the same as the other two control plots based on a careful assessment of several parameters, including higher

Desorption and Transformation of Nitroaromatic (TNT) and Nitramine (RDX and HMX) Explosive Residues on Detonated Pure Mineral Phases

DTIC Science & Technology

2011-11-01

surface area measurements were used to compare the pristine and detonated mineral surfaces and to determine if the extreme heat and/or pressures of...gas (N2) in a liquid nitrogen atmosphere (−194.8°C). Results from six relative pressure points were reduced to surface area values applying BET theory...include the minerals quartz, calcite, and dolomite . However, in some detonated Ottawa sand samples the highest intensity peak for calcite at 29° 2Θ

Dynamic high pressure process for fabricating superconducting and permanent magnetic materials

DOEpatents

Nellis, William J.; Geballe, Theodore H.; Maple, M. Brian

1990-01-01

Shock wave formation of thin layers of materials with improved superconducting and permanent magnetic properties and improved microstructures. The material fabrication system includes a sandwiched structure including a powder material placed between two solid members to enable explosive shock consolidation. The two solid members are precooled to about 80.degree.-100.degree. K. to reduce the residual temperatures attained as a result of the shock wave treatment, and thereby increase the quench rate of the consolidated powder.

Single-Use Sensor Strips for Reliable Field Analysis of Gunshot Residue

DTIC Science & Technology

2013-10-13

3    List of Figures Fig. 1. Cyclic square-wave voltammogram at the bare GCE for a mixture of trace metals and explosives constituents of GSR: 3...variables obtained after CVA analysis of the GSR samples according to (B) exposure level or (C) 3-class response mode. Samples in (B) correspond to...to (A) exposure level or (B) 3-class response mode. Samples correspond to the same controls outlined in Fig. 6. Fig. 8. Score plot of the

Dynamic high pressure process for fabricating superconducting and permanent magnetic materials

DOEpatents

Nellis, W.J.; Geballe, T.H.; Maple, M.B.

1990-03-13

Shock wave formation of thin layers of materials with improved superconducting and permanent magnetic properties and improved microstructures is disclosed. The material fabrication system includes a sandwiched structure including a powder material placed between two solid members to enable explosive shock consolidation. The two solid members are precooled to about 80--100 K to reduce the residual temperatures attained as a result of the shock wave treatment, and thereby increase the quench rate of the consolidated powder. 9 figs.

Decontamination of Explosives-Contaminated Range Scrap Using a Transportable Hot Gas Decontamination System

DTIC Science & Technology

2003-05-01

I I I I FINAL • Composition B (TNT, RDX and wax), • Tetryl, • Smokeless Powder ( Nitrocellulose /Nitrogylcerin), and • HBX (TNT, RDX, aluminum...operating-cost system. Because of its temporary, on-site configuration, this is an inherently low-cost method to decontaminate range residue. On... methods ) were evaluated and progressively improved during each test run. 022/masterdocument.doc 4-12 I I I I I I I I I I I I I I I I

Sampling for Explosives Residues at Fort Greely, Alaska. Reconnaissance Visit July 2000

DTIC Science & Technology

2001-11-01

on lands withdrawn from the public domain under the Military Lands With- drawal Act (PL 106 -65). The Army has pledged to implement a program to...from the public domain under the Military Lands Withdrawal Act (Public Law 106 -65); the withdrawal of land was recently renewed. As part of the...option fuse Pellet booster comp A5 (RDX (98.5%)and stearic acid (1.5%) 8 g Lead charge PBXN -5 (HMX 95% and Binder 5%) 152 mg Detonator assembly HMX

Solid state gas sensors for detection of explosives and explosive precursors

NASA Astrophysics Data System (ADS)

Chu, Yun

The increased number of terrorist attacks using improvised explosive devices (IEDs) over the past few years has made the trace detection of explosives a priority for the Department of Homeland Security. Considerable advances in early detection of trace explosives employing spectroscopic detection systems and other sensing devices have been made and have demonstrated outstanding performance. However, modern IEDs are not easily detectable by conventional methods and terrorists have adapted to avoid using metallic or nitro groups in the manufacturing of IEDs. Instead, more powerful but smaller compounds, such as TATP are being more frequently used. In addition, conventional detection techniques usually require large capital investment, labor costs and energy input and are incapable of real-time identification, limiting their application. Thus, a low cost detection system which is capable of continuous online monitoring in a passive mode is needed for explosive detection. In this dissertation, a thermodynamic based thin film gas sensor which can reliably detect various explosive compounds was developed and demonstrated. The principle of the sensors is based on measuring the heat effect associated with the catalytic decomposition of explosive compounds present in the vapor phase. The decomposition mechanism is complicated and not well known, but it can be affected by many parameters including catalyst, reaction temperature and humidity. Explosives that have relatively high vapor pressure and readily sublime at room temperature, like TATP and 2, 6-DNT, are ideal candidate for vapor phase detection using the thermodynamic gas sensor. ZnO, W2O 3, V2O5 and SnO2 were employed as catalysts. This sensor exhibited promising sensitivity results for TATP, but poor selectivity among peroxide based compounds. In order to improve the sensitivity and selectivity of the thermodynamic sensor, a Pd:SnO2 nanocomposite was fabricated and tested as part of this dissertation. A combinatorial chemistry techniques were used for catalyst discovery. Specially, a series of tin oxide catalysts with continuous varying composition of palladium were fabricated to screen for the optimum Pd loading to maximize specificity. Experimental results suggested that sensors with a 12 wt.% palladium loading generated the highest sensitivity while a 8 wt.% palladium loading provided greatest selectivity. XPS and XRD were used to study how palladium doping level affects the oxidation state and crystal structure of the nanocomposite catalyst. As with any passive detection system, a necessary theme of this dissertation was the mitigation of false positive. Toward this end, an orthogonal detection system comprised of two independent sensing platforms sharing one catalyst was demonstrated using TATP, 2, 6-DNT and ammonium nitrate as target molecules. The orthogonal sensor incorporated a thermodynamic based sensing platform to measure the heat effect associated with the decomposition of explosive molecules, and a conductometric sensing platform that monitors the change in electrical conductivity of the same catalyst when exposed to the explosive substances. Results indicate that the orthogonal sensor generates an effective response to explosives presented at part per billion level. In addition, with two independent sensing platforms, a built-in redundancy of results could be expected to minimize false positive.

The dehydroalanine effect in the fragmentation of ions derived from polypeptides

PubMed Central

Pilo, Alice L.; Peng, Zhou; McLuckey, Scott A.

2016-01-01

The fragmentation of peptides and proteins upon collision-induced dissociation (CID) is highly dependent on sequence and ion type (e.g. protonated, deprotonated, sodiated, odd electron, etc.). Some amino acids, for example aspartic acid and proline, have been found to enhance certain cleavages along the backbone. Here, we show that peptides and proteins containing dehydroalanine, a non-proteinogenic amino acid with an unsaturated side-chain, undergo enhanced cleavage of the N—Cα bond of the dehydroalanine residue to generate c- and z-ions. Because these fragment ion types are not commonly observed upon activation of positively charged even-electron species, they can be used to identify dehydroalanine residues and localize them within the peptide or protein chain. While dehydroalanine can be generated in solution, it can also be generated in the gas phase upon CID of various species. Oxidized S-alkyl cysteine residues generate dehydroalanine upon activation via highly efficient loss of the alkyl sulfenic acid. Asymmetric cleavage of disulfide bonds upon collisional activation of systems with limited proton mobility also generates dehydroalanine. Furthermore, we show that gas-phase ion/ion reactions can be used to facilitate the generation of dehydroalanine residues via, for example, oxidation of S-alkyl cysteine residues and conversion of multiply-protonated peptides to radical cations. In the latter case, loss of radical side-chains to generate dehydroalanine from some amino acids gives rise to the possibility for residue-specific backbone cleavage of polypeptide ions. PMID:27484024

Iowa timber industry--an assessment of timber product output and use, 2000.

Treesearch

Ronald J. Piva; Dennis D. Michel

2003-01-01

Discusses recent Iowa forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, and pulpwood in 2000. Reports on logging residue generated from timber harvest operations. Also reports on wood and bark residue generated at primary wood using mills and on disposition of mill residues.

Indiana timber industry--an assessment of timber product output and use, 2000

Treesearch

Ronald J. Piva; Joey Gallion

2003-01-01

Discusses recent Indiana forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, and pulpwood in 2000. Reports on logging residue generated from timber harvest operations. Also reports on wood and bark residue generated at primary wood-using mills and on disposition of mill residues.

South Dakota timber industry--an assessment of timber product output and use, 1999.

Treesearch

Ronald J. Piva; Gregory J. Josten

2003-01-01

Discusses recent South Dakota forest industry trends; production and receipts of industrial roundwood; and production of saw logs in 1999. Reports on logging residue generated from timber harvest operations. Also reports on wood and bark residue generated at primary wood-using mills and on disposition of mill residues.

North Dakota timber industry: an assessment of timber product output and use, 2009

Treesearch

David E. Haugen; Robert A. Harsel

2013-01-01

Presents recent North Dakota forest industry trends; production and receipts of industrial roundwood; and production of saw logs and other products in 2009. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

Kansas timber industry: an assessment of timber product output and use, 2009

Treesearch

David E. Haugen

2013-01-01

Presents recent Kansas forest industry trends; production and receipts of industrial roundwood; and production of saw logs and other products in 2009. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

Wisconsin timber industry: an assessment of timber product output and use, 2008

Treesearch

David E. Haugen

2013-01-01

Presents recent Wisconsin forest industry trends; production and receipts of industrial roundwood; and production of saw logs, and other products in 2008. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

Indiana timber industry--an assessment of timber product output and use, 2005

Treesearch

Ronald J. Piva; Joey Gallion

2007-01-01

Presents recent Indiana forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, and pulpwood in 2005. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

Characteristics of seismic waves from Soviet peaceful nuclear explosions in salt

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adushkin, V.V.; Kaazik, P.B.; Kostyuchenko, V.N.

1995-04-01

The report is carried out by the Institute for Dynamics of the Geospheres, Russian Academy of Sciences under contract NB280344 with Lawrence Livermore National Laboratory, University of California. The work includes investigation of seismic waves generation and propagation from Soviet peaceful underground nuclear explosions in salt based on the data from temporary and permanent seismic stations. The explosions were conducted at the sites Azgir and Vega within the territory of the Caspian depression of the Russian platform. The data used were obtained in the following conditions of conduction: epicentral distance range from 0 to 60 degrees, yields from 1 tomore » 65 kt and depths of burial from 160 to 1500 m.« less

About plasma points' generation in Z-pinch

NASA Astrophysics Data System (ADS)

Afonin, V. I.; Potapov, A. V.; Lazarchuk, V. P.; Murugov, V. M.; Senik, A. V.

1997-05-01

The streak tube study results (at visible and x-ray ranges) of dynamics of fast Z-pinch formed at explosion of metal wire in diode of high current generator are presented. Amplitude of current in the load reached ˜180 kA at increase time ˜50 ns. The results' analysis points to capability of controlling hot plasma points generation process in Z-pinch.

The Anthropology of Anthropologists.

ERIC Educational Resources Information Center

Turner, Paul R.

Anthropology as an academic discipline in the United States experienced an explosive growth during the late 1960's and early 1970's, when the Woodstock generation embraced anthropology. However, interest in anthropology as a discipline declined in the late 1970's and early 1980's, when the new work-oriented generation held anthropologists at arms…

Bioenergy residues applied as soil amendments: N2O emissions and C sequestration potential

NASA Astrophysics Data System (ADS)

Cayuela, M.; Kuikman, P.; Oenema, O.; Bakker, R.; van Groenigen, J.

2009-12-01

Biofuels have been proposed as environmentally benign substitutes to fossil fuels. There is, however, substantial uncertainty in the scientific literature about how an expanding bioenergy sector would interact with other land uses and what could be the environmental consequences. In the particular case of greenhouse gas balance, the magnitude of discrepancy is tremendously high among different studies. Such controversy has been often attributed to the way the co-products generated were accounted for. It is likely that the intensification of bioenergy production will lead to an increased input of these co-products to the soil as alternative amendments or fertilizers. However, limited research has been done to determine how this will influence microbial transformation processes in soil and thereby the emissions of greenhouse gases. Neither have related issues such as the stabilization of soil organic matter, soil structure and soil fertility been adequately studied. Here, we report a laboratory study on the effects of the application of bioenergy residues on C and N mineralization and greenhouse gas emissions in an agricultural soil. Ten co-products were selected from different energy sectors: anaerobic digestion (digestates), first generation biofuel residues (rapeseed meal, distilled dried grains with solubles), second generation biofuel residues (non-fermentables from hydrolysis of different lignocellulosic materials) and pyrolysis (biochars). They were added at the same N rate (150 kg N ha-1) to a moist (80% water filled pore space) sandy soil and incubated at 20 C for 60 days. Most residues followed fast mineralization dynamics with a flush of CO2 respiration within the first week. The biochars were the exception: they showed very low respiration rates. After 60 days, first generation biofuel residues had emitted more than 80% of added C as CO2. Around 60% was emitted in the case of second generation biofuel residues and 40% with digestates. Biochars were the most stable residues with the lowest CO2 loss between 0.5 and 5.8 % of total added C. Regarding N2O emissions, first generation biofuel residues led to the highest total N2O emissions (between 2.5 - 6.0% of added N). Second generation biofuel residues emitted between 1.0-2.0% of added N, whereas anaerobic digestates led to emissions lower than 1% of added N. The two biochars used in this study led to negative N2O emissions, i.e. lower than the blank soil. We conclude that, at least in the short term, the effects of biofuel residues on the combined greenhouse gas balance of the soil ranges from beneficial (biochar) via mixed (digestates, second generation biofuels) to manifestly detrimental (first generation biofuels). These effects should be taken into account in life cycle analyses of biofuel production.

Ground Truth Collections for Explosions in Northern Fennoscandia and Russia

DOE Office of Scientific and Technical Information (OSTI.GOV)

Harris, D B; Ringdal, F; Kremenetskaya, E

2003-07-28

This project is providing ground-truth information on explosions conducted at the principal mines within 500 kilometers of the ARCES station, and is assembling a seismic waveform database for these events from local and regional stations. The principal mines of interest are in northwest Russia (Khibiny Massif, Olenogorsk, Zapolyamy, and Kovdor groups) and Sweden (Malmberget, Kiruna). These mines form a natural laboratory for examining the variation of mining explosion observations with source type, since they include colocated surface and underground mines and mines conducting a variety of different shot types. In September 2002 we deployed two lines of temporary stations frommore » the Khibiny Massif through and to the north of the ARCES station. This deployment is producing data that will allow researchers to examine the variation of discriminants caused by varying source-receiver distance and the diversity of explosion types. To date, we have collected ground-truth information on 1,118 explosions in the Kola Peninsula, and have assembled waveform data for approximately 700 of these. The database includes waveforms from instruments temporarily deployed in the Khibiny Massif mines, from the Apatity network just outside of the Massif, from LVZ, KEV and ARCES, and from the stations deployed along the two lines into northern Norway. In this paper we present representative waveforms for several types of shots recorded at various regional distances. We have conducted a preliminary study of the variation of phase ratios as a function of source type. This study shows significant differences in Pd/Sn and Pd/Lg ratios for two types of mining explosions: surface ripple-fired explosions and compact underground explosions. Compact explosions are, typically, underground explosions of a few tons with only one or two short delays, and are the closest approximation to single, well-tamped explosions available in the Khibiny mines. The surface shots typically are much larger (ranging up to hundreds of tons), with many delays. The surface mine that we present results for typically also conducts several distinct shots across the mine nearly simultaneously (with a few seconds or tens of seconds). Measured phase ratios are more consistent for compact underground explosions. This consistency is an expected result given the smaller scope for shot variation in these smaller events. In addition, Pd/Lg ratios appear more stable than Pd/Sn ratios for both types of events. The most interesting result is that the compact underground explosions are richer in shear energy (i.e. having smaller P/S ratios) than their surface ripple-fired counterparts. We continue to work on an approach for identifying the principal mines to be targeted for screening at a particular station. Often, routine industrial blasts constitute a large proportion of events detected by monitoring stations close to major mining districts. Many mines may be present, and it may be a problem to determine which subset of mines is responsible for the majority of the events, and should be prime candidates for the deployment of ground-truth collection resources. Our solution to this problem entails several steps. The first is to find geographic clusters of events that may correspond to major groups of mines. For this step, we use event density maps generated from existing network catalogs. This year we examined some of the tradeoffs in generating event density maps: use of automated bulletins to produce maps vs. analyst-reviewed bulletins, and the amount of time required to produce stables maps which can be used to identify significant mines.« less

Dynamic polarizability of tungsten atoms reconstructed from fast electrical explosion of fine wires in vacuum

DOE Office of Scientific and Technical Information (OSTI.GOV)

Sarkisov, G. S.; Rosenthal, S. E.; Struve, K. W.

For nanosecond electrical explosion of fine metal wires in vacuum generates calibrated, radially expanded gas cylinders of metal atoms are surrounded by low-density fast expanding plasma corona. Here, a novel integrated-phase technique, based on laser interferometry, provides the dynamic dipole polarizability of metal atoms. This data was previously unavailable for tungsten atoms. Furthermore, an extremely high melting temperature and significant pre-melt electronic emission make these measurements particularly complicated for this refractory metal.

Dynamic polarizability of tungsten atoms reconstructed from fast electrical explosion of fine wires in vacuum

DOE PAGES

Sarkisov, G. S.; Rosenthal, S. E.; Struve, K. W.

2016-10-12

For nanosecond electrical explosion of fine metal wires in vacuum generates calibrated, radially expanded gas cylinders of metal atoms are surrounded by low-density fast expanding plasma corona. Here, a novel integrated-phase technique, based on laser interferometry, provides the dynamic dipole polarizability of metal atoms. This data was previously unavailable for tungsten atoms. Furthermore, an extremely high melting temperature and significant pre-melt electronic emission make these measurements particularly complicated for this refractory metal.

Earthquakes induced by fluid injection and explosion

USGS Publications Warehouse

Healy, J.H.; Hamilton, R.M.; Raleigh, C.B.

1970-01-01

Earthquakes generated by fluid injection near Denver, Colorado, are compared with earthquakes triggered by nuclear explosion at the Nevada Test Site. Spatial distributions of the earthquakes in both cases are compatible with the hypothesis that variation of fluid pressure in preexisting fractures controls the time distribution of the seismic events in an "aftershock" sequence. We suggest that the fluid pressure changes may also control the distribution in time and space of natural aftershock sequences and of earthquakes that have been reported near large reservoirs. ?? 1970.

Analysis and Modeling of the Wavefield Generated by Explosions at the San Andreas Fault Observatory at Depth

DTIC Science & Technology

2010-09-01

method to ~ 4 Hz wave propagation using SAFOD borehole seismometers and the Parkfield Array Seismic Observatory (PASO) array (Thurber et al., 2004...limitations in mind, we apply our method to ~ 4 Hz wave propagation using SAFOD borehole seismometers and the Parkfield Array Seismic Observatory (PASO...Proposal No. BAA09-69 ABSTRACT Surface array and deep borehole recordings of chemical explosions in the near-source (0-20 km) region are studied to

Quantification of Rock Damage from Small Explosions and Its Effect on Shear-Wave Generation

DTIC Science & Technology

2009-06-15

close to a nearby cell /radio tower and the active quarry wall to detonate our planned 400 lb explosions. Core drilling at an alternative test site...Figure ) was conducted further away from the active quarry wall and a nearby cell /radio tower. The alternative site would be far enough away from...returned into the original location (Figure ). In order to reduce the projected ground vibrations at the cell /radio tower and high wall of the active

Finite Element Analysis of M15 and M19 Mines Under Wheeled Vehicle Load

DTIC Science & Technology

2008-03-01

the plate statically. An implicit finite element option in a code called LSDYNA was used to model the pressure generated in the explosive by the...figure 4 for the M19 mines. Maximum pressure in the explosive for each mine calculated by LSDYNA code shown for a variety of plate sizes and weights...Director U.S. Army TRADOC Analysis Center-WSMR ATTN: ATRC-WSS-R White Sands Missile Range, NM 88002 Chemical Propulsion Information Agency ATTN

Forensic analysis of explosives using isotope ratio mass spectrometry (IRMS)--discrimination of ammonium nitrate sources.

PubMed

Benson, Sarah J; Lennard, Christopher J; Maynard, Philip; Hill, David M; Andrew, Anita S; Roux, Claude

2009-06-01

An evaluation was undertaken to determine if isotope ratio mass spectrometry (IRMS) could assist in the investigation of complex forensic cases by providing a level of discrimination not achievable utilising traditional forensic techniques. The focus of the research was on ammonium nitrate (AN), a common oxidiser used in improvised explosive mixtures. The potential value of IRMS to attribute Australian AN samples to the manufacturing source was demonstrated through the development of a preliminary AN classification scheme based on nitrogen isotopes. Although the discrimination utilising nitrogen isotopes alone was limited and only relevant to samples from the three Australian manufacturers during the evaluated time period, the classification scheme has potential as an investigative aid. Combining oxygen and hydrogen stable isotope values permitted the differentiation of AN prills from three different Australian manufacturers. Samples from five different overseas sources could be differentiated utilising a combination of the nitrogen, oxygen and hydrogen isotope values. Limited differentiation between Australian and overseas prills was achieved for the samples analysed. The comparison of nitrogen isotope values from intact AN prill samples with those from post-blast AN prill residues highlighted that the nitrogen isotopic composition of the prills was not maintained post-blast; hence, limiting the technique to analysis of un-reacted explosive material.

Study of the laser-induced decomposition of energetic materials at static high-pressure by time-resolved absorption spectroscopy

NASA Astrophysics Data System (ADS)

Hebert, Philippe; Saint-Amans, Charles

2013-06-01

A detailed description of the reaction rates and mechanisms occurring in shock-induced decomposition of condensed explosives is very important to improve the predictive capabilities of shock-to-detonation transition models. However, direct measurements of such experimental data are difficult to perform during detonation experiments. By coupling pulsed laser ignition of an explosive in a diamond anvil cell (DAC) with time-resolved streak camera recording of transmitted light, it is possible to make direct observations of deflagration phenomena at detonation pressure. We have developed an experimental set-up that allows combustion front propagation rates and time-resolved absorption spectroscopy measurements. The decomposition reactions are initiated using a nanosecond YAG laser and their kinetics is followed by time-resolved absorption spectroscopy. The results obtained for two explosives, nitromethane (NM) and HMX are presented in this paper. For NM, a change in reactivity is clearly seen around 25 GPa. Below this pressure, the reaction products are essentially carbon residues whereas at higher pressure, a transient absorption feature is first observed and is followed by the formation of a white amorphous product. For HMX, the evolution of the absorption as a function of time indicates a multi-step reaction mechanism which is found to depend on both the initial pressure and the laser fluence.

Influence of steaming explosion time on the physic-chemical properties of cellulose from Lespedeza stalks (Lespedeza crytobotrya).

PubMed

Wang, Kun; Jiang, Jian-Xin; Xu, Feng; Sun, Run-Cang

2009-11-01

The synergistic effect of steam explosion pretreatment and sodium hydroxide post-treatment of Lespedeza stalks (Lespedeza crytobotrya) has been investigated in this study. In this case, Lespedeza stalks were firstly exploded at a fixed steam pressure (22.5 kg/m(2)) for 2-10 min. Then the steam-exploded Lespedeza stalks was extracted with 1 M NaOH at 50 degrees C for 3 h with a shrub to water ratio of 1:20 (g/ml), which yielded 57.3%, 53.1%, 55.4%, 52.8%, 53.2%, and 56.4% (% dry weight) cellulose rich fractions, comparing to 68.0% from non-steam-exploded material. The content of glucose in cellulose rich residues increased with increment of the steaming time and reached to 94.10% at the most severity. The similar increasing trend occurred during the dissolution of hemicelluloses. It is evident that at shorter steam explosion time, autohydrolysis mainly occurred on the hemicelluloses and the amorphous area of cellulose. The crystalline region of cellulose was depolymerized under a prolonged incubation time. The characteristics of the cellulose rich fractions in terms of FT-IR and CP/MAS (13)C NMR spectroscopy and thermal analysis were discussed, and the surface structure was also investigated by SEM.

Sensor data fusion for spectroscopy-based detection of explosives

NASA Astrophysics Data System (ADS)

Shah, Pratik V.; Singh, Abhijeet; Agarwal, Sanjeev; Sedigh, Sahra; Ford, Alan; Waterbury, Robert

2009-05-01

In-situ trace detection of explosive compounds such as RDX, TNT, and ammonium nitrate, is an important problem for the detection of IEDs and IED precursors. Spectroscopic techniques such as LIBS and Raman have shown promise for the detection of residues of explosive compounds on surfaces from standoff distances. Individually, both LIBS and Raman techniques suffer from various limitations, e.g., their robustness and reliability suffers due to variations in peak strengths and locations. However, the orthogonal nature of the spectral and compositional information provided by these techniques makes them suitable candidates for the use of sensor fusion to improve the overall detection performance. In this paper, we utilize peak energies in a region by fitting Lorentzian or Gaussian peaks around the location of interest. The ratios of peak energies are used for discrimination, in order to normalize the effect of changes in overall signal strength. Two data fusion techniques are discussed in this paper. Multi-spot fusion is performed on a set of independent samples from the same region based on the maximum likelihood formulation. Furthermore, the results from LIBS and Raman sensors are fused using linear discriminators. Improved detection performance with significantly reduced false alarm rates is reported using fusion techniques on data collected for sponsor demonstration at Fort Leonard Wood.

The evolution of young silicic lavas at Medicine Lake Volcano, California: Implications for the origin of compositional gaps in calc-alkaline series lavas

USGS Publications Warehouse

Grove, T.L.; Donnelly-Nolan, J. M.

1986-01-01

At Medicine Lake Volcano, California, the compositional gap between andesite (57-62 wt.% SiO2) and rhyolite (73-74 wt.% SiO2) has been generated by fractional crystallization. Assimilation of silicic crust has also occurred along with fractionation. Two varieties of inclusions found in Holocene rhyolite flows, hornblende gabbros and aphyric andesites, provide information on the crystallization path followed by lavas parental to the rhyolite. The hornblende gabbros are magmatic cumulate residues and their mineral assemblages are preserved evidence of the phases that crystallized from an andesitic precursor lava to generate the rhyolite lavas. The andesitic inclusions represent samples of a parental andesite and record the early part of the differentiation history. Olivine, plagioclase and augite crystallization begins the differentiation history, followed by the disappearance of olivine and augite through reaction with the liquid to form orthopyroxene and amphibole. Further crystallization of the assemblage plagioclase, amphibole, orthopyroxene, magnetite, and apatite from a high-SiO2 andesite leads to rhyolite. This final crystallization process occurs on a cotectic that is nearly horizontal in temperature-composition space. Since a large amount of crystallization occurs over a limited temperature interval, a compositional gap develops between rhyolite and high SiO2 andesite. Liquidus surfaces with shallow slopes in temperature-composition space are characteristic of several late-stage crystallization assemblages in the andesite to rhyolite compositional range. Experimentally produced plagioclase+ amphibole+orthopyroxene+magnetite and plagioclase+ augite+low-Ca pyroxene+magnetite cotectics have liquidus slopes that are nearly flat. At other calc-alkaline volcanic centers crystallization processes involving large compositional changes over small temperature intervals may also be important in the development of bimodal volcanism (i.e. the existence of a composition gap). At Mt. Mazama and Mt. St. Helens, USA and Aso Caldera and Shikotsu, Japan the amphibole-bearing assemblage was important. At Krakatau, Indonesia and Katmai, USA, an augite+orthopyroxene-bearing assemblage was important. In addition to its role in the production of a compositional gap between intermediate and rhyolitic lavas, the crystallization process increases the H2O content of the residual liquid. This rapid increase in residual liquid volatile content which results from the precipitation of a large proportion of crystalline solids may be an important factor among several that lead to explosive silicic eruptions. ?? 1986 Springer-Verlag.

IMPACT fragmentation model developments

NASA Astrophysics Data System (ADS)

Sorge, Marlon E.; Mains, Deanna L.

2016-09-01

The IMPACT fragmentation model has been used by The Aerospace Corporation for more than 25 years to analyze orbital altitude explosions and hypervelocity collisions. The model is semi-empirical, combining mass, energy and momentum conservation laws with empirically derived relationships for fragment characteristics such as number, mass, area-to-mass ratio, and spreading velocity as well as event energy distribution. Model results are used for several types of analysis including assessment of short-term risks to satellites from orbital altitude fragmentations, prediction of the long-term evolution of the orbital debris environment and forensic assessments of breakup events. A new version of IMPACT, version 6, has been completed and incorporates a number of advancements enabled by a multi-year long effort to characterize more than 11,000 debris fragments from more than three dozen historical on-orbit breakup events. These events involved a wide range of causes, energies, and fragmenting objects. Special focus was placed on the explosion model, as the majority of events examined were explosions. Revisions were made to the mass distribution used for explosion events, increasing the number of smaller fragments generated. The algorithm for modeling upper stage large fragment generation was updated. A momentum conserving asymmetric spreading velocity distribution algorithm was implemented to better represent sub-catastrophic events. An approach was developed for modeling sub-catastrophic explosions, those where the majority of the parent object remains intact, based on estimated event energy. Finally, significant modifications were made to the area-to-mass ratio distribution to incorporate the tendencies of different materials to fragment into different shapes. This ability enabled better matches between the observed area-to-mass ratios and those generated by the model. It also opened up additional possibilities for post-event analysis of breakups. The paper will discuss a number of the modifications that have been made to improve IMPACT and why these modifications were made. Comparisons between observational data and the IMPACT predictions will be discussed in the context of these model revisions and the overall behavior of model results. A number of future areas of investigation that were uncovered in the process of the analysis efforts will also be reviewed.

Near-field non-radial motion generation from underground chemical explosions in jointed granite

NASA Astrophysics Data System (ADS)

Vorobiev, Oleg; Ezzedine, Souheil; Hurley, Ryan

2018-01-01

This paper describes analysis of non-radial ground motion generated by chemical explosions in a jointed rock formation during the Source Physics Experiment (SPE). Such motion makes it difficult to discriminate between various subsurface events such as explosions, implosions (i.e. mine collapse) and earthquakes. We apply 3-D numerical simulations to understand experimental data collected during the SPEs. The joints are modelled explicitly as compliant thin inclusions embedded into the rock mass. Mechanical properties of the rock and the joints as well as the joint spacing and orientation are inferred from experimental test data, and geophysical and geological characterization of the SPE site which is dominantly Climax Stock granitic outcrop. The role of various factors characterizing the joints such as joint spacing, frictional properties, orientation and persistence in generation of non-radial motion is addressed. The joints in granite at the SPE site are oriented in nearly orthogonal directions with two vertical sets dipping at 70-80 degrees with the same strike angle, one vertical set almost orthogonal to the first two and one shallow angle joint set dipping 15 degrees. In this study we establish the relationship between the joint orientation and azimuthal variations in the polarity of the observed shear motion. The majority of the shear motion is generated due to the effects of non-elastic sliding on the joints near the source, where the wave can create significant shear stress to overcome the cohesive forces at the joints. Near the surface the joints are less confined and are subject to sliding when the pressure waves are reflected. In the far field, where the cohesive forces on the joints cannot be overcome, additional shear motion can be generated due to elastic anisotropy of the rock mass given by preferred spatial orientations of compliant joints.

Michigan timber industry—an assessment of timber product output and use, 2008

Treesearch

David E. Haugen; Brian F. Walters; Ronald J. Piva; David Neumann

2014-01-01

Presents recent Michigan forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, pulpwood, and other products in 2008. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

Maryland timber industry: an assessment of timber product output and use, 2008

Treesearch

Brian F. Walters; Daniel R. Rider; Ronald J. Piva

2012-01-01

Presents recent Maryland forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, pulpwood, and other products in 2008. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

Michigan timber industry: an assessment of timber product output and use, 2006

Treesearch

Ronald J. Piva; Anthony K. Weatherspoon

2010-01-01

Presents recent Michigan forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, pulpwood, and other products in 2006. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

Missouri timber industry: an assessment of timber product output and use, 2009

Treesearch

Ronald J. Piva; Thomas B. Treiman

2012-01-01

Presents recent Missouri forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, pulpwood, and other products in 2009. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

Minnesota timber industry: an assessment of timber product output and use, 2007

Treesearch

David E. Haugen; Keith. Jacobson

2012-01-01

Presents recent Minnesota forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, pulpwood, and other products in 2007. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

Indiana timber industry: an assessment of timber product output and use, 2008

Treesearch

Brian F. Walters; Jeff Settle; Ronald J. Piva

2012-01-01

Presents recent Indiana forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, pulpwood, and other products in 2008. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

Nebraska timber Industry--an assessment of timber product output and use, 2006

Treesearch

Ronald J. Piva; Dennis M. Adams

2008-01-01

Presents recent Nebraska forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, excelsior/shavings, and other products in 2006. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

South Dakota timber industry: an assessment of timber product output and use, 2009

Treesearch

Ronald J. Piva; Gregory J. Josten

2013-01-01

Presents recent South Dakota forest industry trends; production and receipts of industrial roundwood; and production of saw logs, veneer logs, pulpwood, and other products in 2009. Logging residue generated from timber harvest operations is reported, as well as wood and bark residue generated at primary wood-using mills and disposition of mill residues.

Standoff laser-induced thermal emission of explosives

NASA Astrophysics Data System (ADS)

Galán-Freyle, Nataly Y.; Pacheco-Londoño, Leonardo C.; Figueroa-Navedo, Amanda; Hernandez-Rivera, Samuel P.

2013-05-01

A laser mediated methodology for remote thermal excitation of analytes followed by standoff IR detection is proposed. The goal of this study was to determine the feasibility of using laser induced thermal emission (LITE) from vibrationally excited explosives residues deposited on surfaces to detect explosives remotely. Telescope based FT-IR spectral measurements were carried out to examine substrates containing trace amounts of threat compounds used in explosive devices. The highly energetic materials (HEM) used were PETN, TATP, RDX, TNT, DNT and ammonium nitrate with concentrations from 5 to 200 μg/cm2. Target substrates of various thicknesses were remotely heated using a high power CO2 laser, and their mid-infrared (MIR) thermally stimulated emission spectra were recorded. The telescope was configured from reflective optical elements in order to minimize emission losses in the MIR frequencies and to provide optimum overall performance. Spectral replicas were acquired at a distance of 4 m with an FT-IR interferometer at 4 cm- 1 resolution and 10 scans. Laser power was varied from 4-36 W at radiation exposure times of 10, 20, 30 and 60 s. CO2 laser powers were adjusted to improve the detection and identification of the HEM samples. The advantages of increasing the thermal emission were easily observed in the results. Signal intensities were proportional to the thickness of the coated surface (a function of the surface concentration), as well as the laser power and laser exposure time. For samples of RDX and PETN, varying the power and time of induction of the laser, the calculated low limit of detections were 2 and 1 μg/cm2, respectively.

Controlled biological and biomimetic systems for landmine detection.

PubMed

Habib, Maki K

2007-08-30

Humanitarian demining requires to accurately detect, locate and deactivate every single landmine and other buried mine-like objects as safely and as quickly as possible, and in the most non-invasive manner. The quality of landmine detection affects directly the efficiency and safety of this process. Most of the available methods to detect explosives and landmines are limited by their sensitivity and/or operational complexities. All landmines leak with time small amounts of their explosives that can be found on surrounding ground and plant life. Hence, explosive signatures represent the robust primary indicator of landmines. Accordingly, developing innovative technologies and efficient techniques to identify in real-time explosives residue in mined areas represents an attractive and promising approach. Biological and biologically inspired detection technology has the potential to compete with or be used in conjunction with other artificial technology to complement performance strengths. Biological systems are sensitive to many different scents concurrently, a property that has proven difficult to replicate artificially. Understanding biological systems presents unique opportunities for developing new capabilities through direct use of trained bio-systems, integration of living and non-living components, or inspiring new design by mimicking biological capabilities. It is expected that controlled bio-systems, biotechnology and microbial techniques will contribute to the advancement of mine detection and other application domains. This paper provides directions, evaluation and analysis on the progress of controlled biological and biomimetic systems for landmine detection. It introduces and discusses different approaches developed, underlining their relative advantages and limitations, and highlighting trends, safety and ecology concern, and possible future directions.

Pair-instability supernovae of fast rotating stars

NASA Astrophysics Data System (ADS)

Chen, Ke-Jung

2015-01-01

We present 2D simulations of pair-instability supernovae considering rapid rotation during their explosion phases. Recent studies of the Population III (Pop III) star formation suggested that these stars could be born with a mass scale about 100 M⊙ and with a strong rotation. Based on stellar evolution models, these massive Pop III stars might have died as highly energetic pair-instability supernovae. We perform 2D calculations to investigate the impact of rotation on pair-instability supernovae. Our results suggest that rotation leads to an aspherical explosion due to an anisotropic collapse. If the first stars have a 50% of keplerian rotational rate of the oxygen core before their pair-instability explosions, the overall 56Ni production can be significantly reduced by about two orders of magnitude. An extreme case of 100% keplerian rotational rate shows an interesting feature of fluid instabilities along the equatorial plane caused by non-synchronized and non-isotropic ignitions of explosions, so that the shocks run into the in-falling gas and generate the Richtmyer-Meshkov instability.

Wideband acoustic records of explosive volcanic eruptions at Stromboli: New insights on the explosive process and the acoustic source

NASA Astrophysics Data System (ADS)

Goto, A.; Ripepe, M.; Lacanna, G.

2014-06-01

Wideband acoustic waves, both inaudible infrasound (<20 Hz) and audible component (>20 Hz), generated by strombolian eruptions were recorded at 5 kHz and correlated with video images. The high sample rate revealed that in addition to the known initial infrasound, the acoustic signal includes an energetic high-frequency (typically >100 Hz) coda. This audible signal starts before the positive infrasound onset goes negative. We suggest that the infrasonic onset is due to magma doming at the free surface, whereas the immediate high-frequency signal reflects the following explosive discharge flow. During strong gas-rich eruptions, positively skewed shockwave-like components with sharp compression and gradual depression appeared. We suggest that successive bursting of overpressurized small bubbles and the resultant volcanic jets sustain the highly gas-rich explosions and emit the audible sound. When the jet is supersonic, microexplosions of ambient air entrained in the hot jet emit the skewed waveforms.

Large Scale Supernova Structure from Pre- and Post-Explosion Convection

NASA Astrophysics Data System (ADS)

Young, Patrick A.; Vance, Gregory; Ellinger, Carola; Fryer, Chris

2017-06-01

We present results of 3D supernova simulations with initial conditions drawn from 3D models of late stage stellar convection. Simulations are performed with the supernova-optimized smooth particle hydrodynamics code SNSPH and postprocessed using a 522 isotope nuclear reaction network. The simulations also have a non-fixed central compact object that is free to accrete momentum from fall back material. It has been established that neutrino-driven convection can produce large asymmetries in the explosion, but the effects caused by convective anisotropies in late burning shells in the progenitor star and time-varying gravitational potential after the explosion are less well explored. We find that convective motions can result in highly asymmetric overturn of deep layers that are not susceptible to large effects from explosion generated Rayleigh-Taylor and Richtmeyer-Meshkov instabilities. Such overturn can produce regions with a strong alpha-rich freezeout and high iron abundances morphologically similar to the iron-rich structure in the southeast quadrant of Cassiopeia A.

Explosive genetic evidence for explosive human population growth

PubMed Central

Gao, Feng; Keinan, Alon

2016-01-01

The advent of next-generation sequencing technology has allowed the collection of vast amounts of genetic variation data. A recurring discovery from studying larger and larger samples of individuals had been the extreme, previously unexpected, excess of very rare genetic variants, which has been shown to be mostly due to the recent explosive growth of human populations. Here, we review recent literature that inferred recent changes in population size in different human populations and with different methodologies, with many pointing to recent explosive growth, especially in European populations for which more data has been available. We also review the state-of-the-art methods and software for the inference of historical population size changes that lead to these discoveries. Finally, we discuss the implications of recent population growth on personalized genomics, on purifying selection in the non-equilibrium state it entails and, as a consequence, on the genetic architecture underlying complex disease and the performance of mapping methods in discovering rare variants that contribute to complex disease risk. PMID:27710906

Simulations of Heterogeneous Detonations and Post Detonation Turbulent Mixing and Afterburning

NASA Astrophysics Data System (ADS)

Menon, Suresh; Gottiparthi, Kalyana

2011-06-01

Most metal-loaded explosives and thermobaric explosives exploit the afterburning of metals to maintain pressure and temperature conditions.The use of such explosives in complex environment can result in post detonation flow containing many scales of vortical motion, flow jetting and shear, as well as plume-surface interactions due to flow impingement and wall flows. In general, all these interactions can lead to highly turbulent flow fields even if the initial ambient conditions were quiescent. Thus, turbulent mixing can dominate initial mixing and impact the final afterburn. We conduct three-dimensional numerical simulations of the propagation of detonation resulting from metal-loaded (inert or reacting) explosives and analyze the afterburn process as well as the generation of multiple scales of mixing in the post detonation flow field. Impact of the detonation and post-detonation flow field on solid surface is also considered for a variety of initial conditions. Comparison with available data is carried out to demonstrate validity of the simulation method. Supported by Defense Threat Reduction Agency

Numerical Study of Underwater Explosions and Following Bubble Pulses

NASA Astrophysics Data System (ADS)

Abe, Atsushi; Katayama, Masahide; Murata, Kenji; Kato, Yukio; Tanaka, Katsumi

2007-06-01

Underwater explosions and following bubble pulses were simulated by using the hydrocode AUTODYN. The pressure gradient depended on the water depth was applied to the water, and the effects of the atmospheric pressure and the gravity on the bubble properties were investigated numerically. In the deep and shallow water depth cases the bubble properties or pressure histories obtained numerically were compared with the empirical formula or the experimental data. Not only the pressure gradient in the water and the atmospheric pressure but also the application of the JWL EOS to slow energy release of the non-ideal explosive (Miller model) were found to be of great importance to simulate the generation of the bubble pulse precisely. Although the gravitational term during the dynamic analysis can be neglected in numerical analyses for very short time phenomena, it is indispensable to simulate the buoyancy of the bubble because the time range of the bubble behavior is some hundred times longer than that of the explosion phenomena.