Progress in standoff surface contaminant detector platform

NASA Astrophysics Data System (ADS)

Dupuis, Julia R.; Giblin, Jay; Dixon, John; Hensley, Joel; Mansur, David; Marinelli, William J.

2017-05-01

Progress towards the development of a longwave infrared quantum cascade laser (QLC) based standoff surface contaminant detection platform is presented. The detection platform utilizes reflectance spectroscopy with application to optically thick and thin materials including solid and liquid phase chemical warfare agents, toxic industrial chemicals and materials, and explosives. The platform employs an ensemble of broadband QCLs with a spectrally selective detector to interrogate target surfaces at 10s of m standoff. A version of the Adaptive Cosine Estimator (ACE) featuring class based screening is used for detection and discrimination in high clutter environments. Detection limits approaching 0.1 μg/cm2 are projected through speckle reduction methods enabling detector noise limited performance. The design, build, and validation of a breadboard version of the QCL-based surface contaminant detector are discussed. Functional test results specific to the QCL illuminator are presented with specific emphasis on speckle reduction.

Using unmanned aerial vehicle-borne magnetic sensors to detect and locate improvised explosive devices and unexploded ordnance

NASA Astrophysics Data System (ADS)

Trammell, Hoke S., III; Perry, Alexander R.; Kumar, Sankaran; Czipott, Peter V.; Whitecotton, Brian R.; McManus, Tobin J.; Walsh, David O.

2005-05-01

Magnetic sensors configured as a tensor magnetic gradiometer not only detect magnetic targets, but also determine their location and their magnetic moment. Magnetic moment information can be used to characterize and classify objects. Unexploded ordnance (UXO) and thus many types of improvised explosive device (IED) contain steel, and thus can be detected magnetically. Suitable unmanned aerial vehicle (UAV) platforms, both gliders and powered craft, can enable coverage of a search area much more rapidly than surveys using, for instance, total-field magnetometers. We present data from gradiometer passes over different shells using a gradiometer mounted on a moving cart. We also provide detection range and speed estimates for aerial detection by a UAV.

Prospects for infrasound bolide detections from balloon-borne platforms

NASA Astrophysics Data System (ADS)

Young, Eliot; Bowman, Daniel; Arrowsmith, Stephen; Boslough, Marc; Klein, Viliam; Ballard, Courtney; Lees, Jonathan

2017-04-01

We report on an experiment to assess whether balloon-borne instruments can improve sensitivities to bolides exploding in the Earth's atmosphere (essentially using the atmosphere as a witness plate to characterize the small end of the NEO (Near Earth Object) population). The CTBTO's infrasound network regularly detects infrasound disturbances caused by bolides, including the 15-FEB-2013 Chelybinsk impact. Balloon-borne infrasound sensors should have two important advantages over ground-based infrasound stations: there should be virtually no wind noise on a free-floating platform, and a sensor in the stratosphere should benefit from its location within the stratospheric duct. Balloon-borne sensors also have the disadvantage that the amplitude of infrasound waves will decrease as they ascend with altitude. To test the performance of balloon-borne sensors, we conducted an experiment on a NASA high altitude (35 km) balloon launched from Ft Sumner, NM on 28-SEP-2016. We were able to put two independent infrasound payloads on this flight. We arranged for three 3000-lb ANFO explosions to be detonated from Socorro, NM at 12:00, 14:00 and 16:29:59 MST. The first two explosions were detected from the NASA balloon, with the first explosion showing three separate waveforms arriving within a 25-s span. The peak-to-peak amplitude of the waveforms was about 0.06 Pa, and the cleanest microphone channel detected this waveform with an SNR greater than 20. A second balloon at 15 km altitude also detected the second explosion. We have signals from a dozen ground stations at various positions from Socorro to Ft Sumner. We will report on wave propagation models and how they compare with observations from the two balloons and the various ground-stations.

Autonomous mine detection system (AMDS) neutralization payload module

NASA Astrophysics Data System (ADS)

Majerus, M.; Vanaman, R.; Wright, N.

2010-04-01

The Autonomous Mine Detection System (AMDS) program is developing a landmine and explosive hazards standoff detection, marking, and neutralization system for dismounted soldiers. The AMDS Capabilities Development Document (CDD) has identified the requirement to deploy three payload modules for small robotic platforms: mine detection and marking, explosives detection and marking, and neutralization. This paper addresses the neutralization payload module. There are a number of challenges that must be overcome for the neutralization payload module to be successfully integrated into AMDS. The neutralizer must meet stringent size, weight, and power (SWaP) requirements to be compatible with a small robot. The neutralizer must be effective against a broad threat, to include metal and plastic-cased Anti-Personnel (AP) and Anti-Tank (AT) landmines, explosive devices, and Unexploded Explosive Ordnance (UXO.) It must adapt to a variety of threat concealments, overburdens, and emplacement methods, to include soil, gravel, asphalt, and concrete. A unique neutralization technology is being investigated for adaptation to the AMDS Neutralization Module. This paper will describe review this technology and how the other two payload modules influence its design for minimizing SWaP. Recent modeling and experimental efforts will be included.

A sensitive, handheld vapor sensor based on microcantilevers

NASA Astrophysics Data System (ADS)

Pinnaduwage, L. A.; Hedden, D. L.; Gehl, A.; Boiadjiev, V. I.; Hawk, J. E.; Farahi, R. H.; Thundat, T.; Houser, E. J.; Stepnowski, S.; McGill, R. A.; Deel, L.; Lareau, R. T.

2004-11-01

We report the development of a handheld sensor based on piezoresistive microcantilevers that does not depend on optical detection, yet has high detection sensitivity. The sensor is able to detect vapors from the plastic explosives pentaerythritol tetranitrate and hexahydro-1,3,5-triazine at levels below 10 parts per trillion within few seconds of exposure under ambient conditions. A differential measurement technique has yielded a rugged sensor that is unaffected by vibration and is able to function as a "sniffer." The microelectromechanical system sensor design allows for the incorporation of hundreds of microcantilevers with suitable coatings in order to achieve sufficient selectivity in the future, and thus could provide an inexpensive, unique platform for the detection of chemical, biological, and explosive materials.

Detection of Nonvolatile Inorganic Oxidizer-Based Explosives from Wipe Collections by Infrared Thermal Desorption-Direct Analysis in Real Time Mass Spectrometry.

PubMed

Forbes, Thomas P; Sisco, Edward; Staymates, Matthew

2018-05-07

Infrared thermal desorption (IRTD) was coupled with direct analysis in real time mass spectrometry (DART-MS) for the detection of both inorganic and organic explosives from wipe collected samples. This platform generated discrete and rapid heating rates that allowed volatile and semivolatile organic explosives to thermally desorb at relatively lower temperatures, while still achieving elevated temperatures required to desorb nonvolatile inorganic oxidizer-based explosives. IRTD-DART-MS demonstrated the thermal desorption and detection of refractory potassium chlorate and potassium perchlorate oxidizers, compounds difficult to desorb with traditional moderate-temperature resistance-based thermal desorbers. Nanogram to sub-nanogram sensitivities were established for analysis of a range of organic and inorganic oxidizer-based explosive compounds, with further enhancement limited by the thermal properties of the most common commercial wipe materials. Detailed investigations and high-speed visualization revealed conduction from the heated glass-mica base plate as the dominant process for heating of the wipe and analyte materials, resulting in thermal desorption through boiling, aerosolization, and vaporization of samples. The thermal desorption and ionization characteristics of the IRTD-DART technique resulted in optimal sensitivity for the formation of nitrate adducts with both organic and inorganic species. The IRTD-DART-MS coupling and IRTD in general offer promising explosive detection capabilities to the defense, security, and law enforcement arenas.

Transition-Metal-Doped p-Type ZnO Nanoparticle-Based Sensory Array for Instant Discrimination of Explosive Vapors.

PubMed

Qu, Jiang; Ge, Yuru; Zu, Baiyi; Li, Yuxiang; Dou, Xincun

2016-03-09

The development of portable, real-time, and cheap platforms to monitor ultratrace levels of explosives is of great urgence and importance due to the threat of terrorism attacks and the need for homeland security. However, most of the previous chemiresistor sensors for explosive detection are suffering from limited responses and long response time. Here, a transition-metal-doping method is presented to remarkably promote the quantity of the surface defect states and to significantly reduce the charge transfer distance by creating a local charge reservoir layer. Thus, the sensor response is greatly enhanced and the response time is remarkably shortened. The resulting sensory array can not only detect military explosives, such as, TNT, DNT, PNT, PA, and RDX with high response, but also can fully distinguish some of the improvised explosive vapors, such as AN and urea, due to the huge response reaching to 100%. Furthermore, this sensory array can discriminate ppb-level TNT and ppt-level RDX from structurally similar and high-concentration interfering aromatic gases in less than 12 s. Through comparison with the previously reported chemiresistor or Schottky sensors for explosive detection, the present transition-metal-doping method resulting ZnO sensor stands out and undoubtedly challenges the best. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Broadband infrared imaging spectroscopy for standoff detection of trace explosives

NASA Astrophysics Data System (ADS)

Kendziora, Christopher A.; Furstenberg, Robert; Papantonakis, Michael; Nguyen, Viet; McGill, R. Andrew

2016-05-01

This manuscript describes advancements toward a mobile platform for standoff detection of trace explosives on relevant substrates using broadband infrared spectroscopic imaging. In conjunction with this, we are developing a technology for detection based on photo-thermal infrared (IR) imaging spectroscopy (PT-IRIS). PT-IRIS leverages one or more IR quantum cascade lasers (QCL), tuned to strong absorption bands in the analytes and directed to illuminate an area on a surface of interest. An IR focal plane array is used to image the surface thermal emission upon laser illumination. The PT-IRIS signal is processed as a hyperspectral image cube comprised of spatial, spectral and temporal dimensions as vectors within a detection algorithm. Here we describe methods to increase both sensitivity to trace explosives and selectivity between different analyte types by exploiting a broader spectral range than in previous configurations. Previously we demonstrated PT-IRIS at several meters of standoff distance indoors and in field tests, while operating the lasers below the infrared eye-safe intensity limit (100 mW/cm2). Sensitivity to explosive traces as small as a single 10 μm diameter particle (~1 ng) has been demonstrated.

Underwater olfaction for real-time detection of submerged unexploded ordnance

NASA Astrophysics Data System (ADS)

Harper, Ross J.; Dock, Matthew L.

2007-04-01

The presence of Underwater Unexploded Ordnance (UUXO) represents a considerable threat in the marine environment. Elevated concentrations of dissolved explosive compounds, such as TNT and RDX, may be produced in the vicinity of degraded UUXO shell casings and are known to have significant toxicant effects on local marine organisms. During World War II and in subsequent years, the US military inadvertently or, in some cases intentionally, deposited many thousands of tons of UUXO in US coastal waters. Much of this material is difficult to locate by magnetometry or sonar imaging techniques, and can be extremely challenging to identify by visual means after lying on the bottom of the ocean for several decades. The present work is focused on advances in underwater olfaction, wherein trace amounts of dissolved explosive compounds may be detected and discriminated from other chemical species found in the marine environment, for the purpose of establishing safe cordons and/or neutralization of the explosives. ICx Nomadics has developed the first known real-time sensor system that is capable of detecting chemical signatures emanating from underwater explosives. The SeaPup sensor, which is based on the fluorescence-quenching transduction mechanism of an amplifying fluorescent polymer (AFP), is capable of real-time detection of the trace chemical signatures emanating from submerged explosive compounds. The SeaPup system has been successfully tested on various marine platforms, including a crawler robot, an autonomous underwater vehicle (AUV), and a remotely operated underwater vehicle (ROV). In one study, the SeaPup was shown to effectively map liquid phase "explosive scent plumes" emanating from an underwater source of TNT. The presented paper will provide an overview of the history, current status, and future development of explosive analyte detection in the underwater environment.

Microcantilever sensor platform for UGV-based detection

NASA Astrophysics Data System (ADS)

Lawrence, Tyson T.; Halleck, A. E.; Schuler, Peter S.; Mahmud, K. K.; Hicks, David R.

2010-04-01

The increased use of Unmanned Ground Vehicles (UGVs) drives the need for new lightweight, low cost sensors. Microelectromechanical System (MEMS) based microcantilever sensors are a promising technology to meet this need, because they can be manufactured at low cost on a mass scale, and are easily integrated into a UGV platform for detection of explosives and other threat agents. While the technology is extremely sensitive, selectivity is a major challenge and the response modes are not well understood. This work summarizes advances in characterizing ultrasensitive microcantilever responses, sampling considerations, and sensor design and cantilever coating methodologies consistent with UGV point detector needs.

Standardized UXO Technology Demonstration Site Scoring Record NO. 934 Technology Type/Platform: EM61 MKII/Towed

DTIC Science & Technology

2009-07-01

nonferrous metallic objects. The applicability of the instrument for ordnance and explosives (OE) detection has been widely demonstrated at sites...was cleared of all metallic items. This clearing of the metallic anomalies from the 2 acre Active Response Demonstration Site was broken into three...with their Multiple Towed Array Detection System (MTADS). This system is known for its effectiveness and ability to detect metallic items. Once the

Explosives remain preferred methods for platform abandonment

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pulsipher, A.; Daniel, W. IV; Kiesler, J.E.

1996-05-06

Economics and safety concerns indicate that methods involving explosives remain the most practical and cost-effective means for abandoning oil and gas structures in the Gulf of Mexico. A decade has passed since 51 dead sea turtles, many endangered Kemp`s Ridleys, washed ashore on the Texas coast shortly after explosives helped remove several offshore platforms. Although no relationship between the explosions and the dead turtles was ever established, in response to widespread public concern, the US Minerals Management Service (MMS) and National Marine Fisheries Service (NMFS) implemented regulations limiting the size and timing of explosive charges. Also, more importantly, they requiredmore » that operators pay for observers to survey waters surrounding platforms scheduled for removal for 48 hr before any detonations. If observers spot sea turtles or marine mammals within the danger zone, the platform abandonment is delayed until the turtles leave or are removed. However, concern about the effects of explosives on marine life remains.« less

Real time explosive hazard information sensing, processing, and communication for autonomous operation

DOEpatents

Versteeg, Roelof J; Few, Douglas A; Kinoshita, Robert A; Johnson, Doug; Linda, Ondrej

2015-02-24

Methods, computer readable media, and apparatuses provide robotic explosive hazard detection. A robot intelligence kernel (RIK) includes a dynamic autonomy structure with two or more autonomy levels between operator intervention and robot initiative A mine sensor and processing module (ESPM) operating separately from the RIK perceives environmental variables indicative of a mine using subsurface perceptors. The ESPM processes mine information to determine a likelihood of a presence of a mine. A robot can autonomously modify behavior responsive to an indication of a detected mine. The behavior is modified between detection of mines, detailed scanning and characterization of the mine, developing mine indication parameters, and resuming detection. Real time messages are passed between the RIK and the ESPM. A combination of ESPM bound messages and RIK bound messages cause the robot platform to switch between modes including a calibration mode, the mine detection mode, and the mine characterization mode.

Real time explosive hazard information sensing, processing, and communication for autonomous operation

DOEpatents

Versteeg, Roelof J.; Few, Douglas A.; Kinoshita, Robert A.; Johnson, Douglas; Linda, Ondrej

2015-12-15

Methods, computer readable media, and apparatuses provide robotic explosive hazard detection. A robot intelligence kernel (RIK) includes a dynamic autonomy structure with two or more autonomy levels between operator intervention and robot initiative A mine sensor and processing module (ESPM) operating separately from the RIK perceives environmental variables indicative of a mine using subsurface perceptors. The ESPM processes mine information to determine a likelihood of a presence of a mine. A robot can autonomously modify behavior responsive to an indication of a detected mine. The behavior is modified between detection of mines, detailed scanning and characterization of the mine, developing mine indication parameters, and resuming detection. Real time messages are passed between the RIK and the ESPM. A combination of ESPM bound messages and RIK bound messages cause the robot platform to switch between modes including a calibration mode, the mine detection mode, and the mine characterization mode.

Grapefruit photonic crystal fiber long period gratings sensor for DNT sensing application

NASA Astrophysics Data System (ADS)

Tao, Chuanyi; Li, Jingke; Zhu, Tenglong

2016-10-01

The detection of explosives and their residues is of great importance in public health, antiterrorism and homeland security applications. The vapor pressures of most explosive compounds are extremely low and attenuation of the available vapor is often great due to diffusion in the environment, making direct vapor detection difficult. In reality bomb dogs are still the most efficient way to quickly detect explosives on the spot. Many formulations of TNT-based explosives contain DNT residues. The use of long period gratings (LPGs) formed in grapefruit photonic crystal fiber (PCF) with thin-film overlay coated on the inner surface of air holes for gas sensing is demonstrated. A gas analyteinduced index variation of the thin-film immobilized on the inner surface of the holey region of the fiber can be observed by a shift of the resonance wavelength. We demonstrate a 2,4-dinitrotoluene (DNT) sensor using grapefruit PCF-LPGs. Coating with gas-sensitive thin-film on the inner surface of the air holes of the grapefruit PCF-LPG could provide a promising platform for rapid highly sensitive gas sensing. A rapid and highly sensitive detection of DNT has been demonstrated using the grapefruit PCF-LPG sensor to show the feasibility of the proposed approach.

Smart Phones: Platform Enabling Modular, Chemical, Biological, and Explosives Sensing

DTIC Science & Technology

2013-07-01

Smart phones: Platform Enabling Modular, Chemical, Biological, and Explosives Sensing by Amethist S. Finch , Matthew Coppock, Justin R...Chemical, Biological, and Explosives Sensing Amethist S. Finch , Matthew Coppock, Justin R. Bickford, Marvin A. Conn, Thomas J. Proctor, and...Explosives Sensing 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Amethist S. Finch , Matthew Coppock, Justin R

Numerical Modeling and Experimental Validation by Calorimetric Detection of Energetic Materials Using Thermal Bimorph Microcantilever Array: A Case Study on Sensing Vapors of Volatile Organic Compounds (VOCs)

PubMed Central

Kang, Seok-Won; Fragala, Joe; Banerjee, Debjyoti

2015-01-01

Bi-layer (Au-Si3N4) microcantilevers fabricated in an array were used to detect vapors of energetic materials such as explosives under ambient conditions. The changes in the bending response of each thermal bimorph (i.e., microcantilever) with changes in actuation currents were experimentally monitored by measuring the angle of the reflected ray from a laser source used to illuminate the gold nanocoating on the surface of silicon nitride microcantilevers in the absence and presence of a designated combustible species. Experiments were performed to determine the signature response of this nano-calorimeter platform for each explosive material considered for this study. Numerical modeling was performed to predict the bending response of the microcantilevers for various explosive materials, species concentrations, and actuation currents. The experimental validation of the numerical predictions demonstrated that in the presence of different explosive or combustible materials, the microcantilevers exhibited unique trends in their bending responses with increasing values of the actuation current. PMID:26334276

DART-MS analysis of inorganic explosives using high temperature thermal desorption†‡

PubMed Central

Sisco, Edward; Staymates, Matthew; Gillen, Greg

2018-01-01

An ambient mass spectrometry (MS) platform coupling resistive Joule heating thermal desorption (JHTD) and direct analysis in real time (DART) was implemented for the analysis of inorganic nitrite, nitrate, chlorate, and perchlorate salts. The resistive heating component generated discrete and rapid heating ramps and elevated temperatures, up to approximately 400 °C s−1 and 750 °C, by passing a few amperes of DC current through a nichrome wire. JHTD enhanced the utility and capabilities of traditional DART-MS for the trace detection of previously difficult to detect inorganic compounds. A partial factorial design of experiments (DOE) was implemented for the systematic evaluation of five system parameters. A base set of conditions for JHTD-DART-MS was derived from this evaluation, demonstrating sensitive detection of a range of inorganic oxidizer salts, down to single nanogram levels. DOE also identified JHTD filament current and in-source collision induced dissociation (CID) energy as inducing the greatest effect on system response. Tuning of JHTD current provided a method for controlling the relative degrees of thermal desorption and thermal decomposition. Furthermore, in-source CID provided manipulation of adduct and cluster fragmentation, optimizing the detection of molecular anion species. Finally, the differential thermal desorption nature of the JHTD-DART platform demonstrated efficient desorption and detection of organic and inorganic explosive mixtures, with each desorbing at its respective optimal temperature. PMID:29651308

Trace detection of explosives using an in-line high-volume sampler, preconcentrator, and Fido explosives detector

NASA Astrophysics Data System (ADS)

Ingram, Russ; Sikes, John

2010-04-01

This paper shall demonstrate the results of a prototype system to detect explosive objects and obscured contaminated targets. By combining a high volume sampling nozzle with an inline 2-stage preconcentrator and a Fido, greater standoff is achieved than with the Fido alone. The direct application of this system is on the Autonomous Mine Detection System (AMDS) but could be deployed on a large variety of robotic platforms. It is being developed under the auspices of the U.S. Army RDECOM CERDEC Night Vision and Electronic Sensors Directorate, Countermine Division. This device is one of several detection tools and technologies to be used on the AMDS. These systems will have multiple, and at times, overlapping objectives. One objective is trace detection on the surface of an unknown potential target. By increasing the standoff capabilities of the detector, the fine manipulation of the robot deploying the detector is less critical. Current detectors used on robotic systems must either be directly in the vapor plume or make direct contact with the target. By increasing the standoff, detection is more easily and quickly achieved. The end result detector must overcome cross-contamination, sample throughput, and environmental issues. The paper will provide preliminary results of the prototype system to include data, and where feasible, video of testing results.

Using Wireless Sensor Networks in Improvised Explosive Device Detection

DTIC Science & Technology

2007-12-01

data collection (permitting self - healing when a node failure occurs); Sensor nodes Gateway nodes 24 • Energy efficiency (necessary to maintain...Runner” robotic platform (see Figure 1). It is reported that this system can detect a wide range of IEDs, even those concealed in vehicles. However...be as simple as running over a rubber hose to produce enough air pressure to activate a switch. Some IEDs have been remotely detonated with radio

Microcantilever technology for law enforcement and anti-terrorism applications: chemical, biological, and explosive material detection

NASA Astrophysics Data System (ADS)

Adams, J. D.; Rogers, B.; Whitten, R.

2005-05-01

The remarkable sensitivity, compactness, low cost, low power-consumption, scalability, and versatility of microcantilever sensors make this technology among the most promising solutions for detection of chemical and biological agents, as well as explosives. The University of Nevada, Reno, and Nevada Nanotech Systems, Inc (NNTS) are currently developing a microcantilever-based detection system that will measure trace concentrations of explosives, toxic chemicals, and biological agents in air. A baseline sensor unit design that includes the sensor array, electronics, power supply and air handling has been created and preliminary demonstrations of the microcantilever platform have been conducted. The envisioned device would measure about two cubic inches, run on a small watch battery and cost a few hundred dollars. The device could be operated by untrained law enforcement personnel. Microcantilever-based devices could be used to "sniff out" illegal and/or hazardous chemical and biological agents in high traffic public areas, or be packaged as a compact, low-power system used to monitor cargo in shipping containers. Among the best detectors for such applications at present is the dog, an animal which is expensive, requires significant training and can only be made to work for limited time periods. The public is already accustomed to explosives and metal detection systems in airports and other public venues, making the integration of the proposed device into such security protocols straightforward.

Free-surface microfluidics for detection of airborne explosives

NASA Astrophysics Data System (ADS)

Meinhart, Carl; Piorek, Brian; Banerjee, Sanjoy; Lee, Seung Joon; Moskovits, Martin

2008-11-01

A novel microfluidic, remote-sensing, chemical detection platform has been developed for real-time sensing of airborne agents. The key enabling technology is a newly developed concept termed Free-Surface Fluidics (FSF), where one or more fluidic surfaces of a microchannel flow are confined by surface tension and exposed to the surrounding atmosphere. The result is a unique open channel flow environment that is driven by pressure through surface tension, and not subject to body forces, such as gravity. Evaporation and flow rates are controlled by microchannel geometry, surface chemistry and precisely-controlled temperature profiles. The free-surface fluidic architecture is combined with Surface-Enhanced Raman Spectroscopy (SERS) to allow for real-time profiling of atmospheric species and detection of airborne agents. The aggregation of SERS nanoparticles is controlled using microfluidics, to obtain dimer nanoparticle clusters at known streamwise positions in the microchannel. These dimers form SERS hot-spots, which amplify the Raman signal by 8 -- 10 orders of magnitude. Results indicate that explosive agents such as DNT, TNT, RDX, TATP and picric acid in the surrounding atmosphere can be readily detected by the SERS system. Due to the amplification of the SERS system, explosive molecules with concentrations of parts per trillion can be detected, even in the presence of interferent molecules having six orders of magnitude higher concentration.

QCL-based standoff and proximal chemical detectors

NASA Astrophysics Data System (ADS)

Dupuis, Julia R.; Hensley, Joel; Cosofret, Bogdan R.; Konno, Daisei; Mulhall, Phillip; Schmit, Thomas; Chang, Shing; Allen, Mark; Marinelli, William J.

2016-05-01

The development of two longwave infrared quantum cascade laser (QCL) based surface contaminant detection platforms supporting government programs will be discussed. The detection platforms utilize reflectance spectroscopy with application to optically thick and thin materials including solid and liquid phase chemical warfare agents, toxic industrial chemicals and materials, and explosives. Operation at standoff (10s of m) and proximal (1 m) ranges will be reviewed with consideration given to the spectral signatures contained in the specular and diffusely reflected components of the signal. The platforms comprise two variants: Variant 1 employs a spectrally tunable QCL source with a broadband imaging detector, and Variant 2 employs an ensemble of broadband QCLs with a spectrally selective detector. Each variant employs a version of the Adaptive Cosine Estimator for detection and discrimination in high clutter environments. Detection limits of 5 μg/cm2 have been achieved through speckle reduction methods enabling detector noise limited performance. Design considerations for QCL-based standoff and proximal surface contaminant detectors are discussed with specific emphasis on speckle-mitigated and detector noise limited performance sufficient for accurate detection and discrimination regardless of the surface coverage morphology or underlying surface reflectivity. Prototype sensors and developmental test results will be reviewed for a range of application scenarios. Future development and transition plans for the QCL-based surface detector platforms are discussed.

Portable and Reliable Surface-Enhanced Raman Scattering Silicon Chip for Signal-On Detection of Trace Trinitrotoluene Explosive in Real Systems.

PubMed

Chen, Na; Ding, Pan; Shi, Yu; Jin, Tengyu; Su, Yuanyuan; Wang, Houyu; He, Yao

2017-05-02

There is an increasing interest in the development of surface-enhanced Raman scattering (SERS) sensors for rapid and accurate on-site detection of hidden explosives. However, portable SERS methods for trace explosive detection in real systems remain scarce, mainly due to their relatively poor reliability and portability. Herein, we present the first demonstration of a portable silicon-based SERS analytical platform for signal-on detection of trace trinitrotoluene (TNT) explosives, which is made of silver nanoparticle (AgNP)-decorated silicon wafer chip (0.5 cm × 0.5 cm). In principle, under 514 nm excitation, the Raman signals of p-aminobenzenethiol (PABT) modified on the AgNP surface could be largely lit up due to the formation of electronic resonance-active TNT-PABT complex. In addition, the surface of AgNPs and silicon substrate-induced plasmon resonances also contribute the total SERS enhancement. For quantitative evaluation, the as-prepared chip features ultrahigh sensitivity [limit of detection is down to ∼1 pM (∼45.4 fg/cm 2 )] and adaptable reproducibility (relative standard deviation is less than 15%) in the detection of TNT standard solutions. More importantly, the developed chip can couple well with a hand-held Raman spectroscopic device using 785 nm excitation, suitable for qualitative analysis of trace TNT even at ∼10 -8 M level from environmental samples including lake water, soil, envelope, and liquor with a short data acquisition time (∼1 min). Furthermore, TNT vapors diffusing from TNT residues (∼10 -6 M) can be detected by using such a portable device, indicating its feasibility in determination of hidden samples.

Raman and photothermal spectroscopies for explosive detection

NASA Astrophysics Data System (ADS)

Finot, Eric; Brulé, Thibault; Rai, Padmnabh; Griffart, Aurélien; Bouhélier, Alexandre; Thundat, Thomas

2013-06-01

Detection of explosive residues using portable devices for locating landmine and terrorist weapons must sat- isfy the application criteria of high reproducibility, specificity, sensitivity and fast response time. Vibrational spectroscopies such as Raman and infrared spectroscopies have demonstrated their potential to distinguish the members of the chemical family of more than 30 explosive materials. The characteristic chemical fingerprints in the spectra of these explosives stem from the unique bond structure of each compound. However, these spectroscopies, developed in the early sixties, suffer from a poor sensitivity. On the contrary, MEMS-based chemical sensors have shown to have very high sensitivity lowering the detection limit down to less than 1 picogram, (namely 10 part per trillion) using sensor platforms based on microcantilevers, plasmonics, or surface acoustic waves. The minimum amount of molecules that can be detected depends actually on the transducer size. The selectivity in MEMS sensors is usually realized using chemical modification of the active surface. However, the lack of sufficiently selective receptors that can be immobilized on MEMS sensors remains one of the most critical issues. Microcantilever based sensors offer an excellent opportunity to combine both the infrared photothermal spectroscopy in their static mode and the unique mass sensitivity in their dynamic mode. Optical sensors based on localized plasmon resonance can also take up the challenge of addressing the selectivity by monitoring the Surface Enhanced Raman spectrum down to few molecules. The operating conditions of these promising localized spectroscopies will be discussed in terms of reliability, compactness, data analysis and potential for mass deployment.

Autonomous chemical and biological miniature wireless-sensor

NASA Astrophysics Data System (ADS)

Goldberg, Bar-Giora

2005-05-01

The presentation discusses a new concept and a paradigm shift in biological, chemical and explosive sensor system design and deployment. From large, heavy, centralized and expensive systems to distributed wireless sensor networks utilizing miniature platforms (nodes) that are lightweight, low cost and wirelessly connected. These new systems are possible due to the emergence and convergence of new innovative radio, imaging, networking and sensor technologies. Miniature integrated radio-sensor networks, is a technology whose time has come. These network systems are based on large numbers of distributed low cost and short-range wireless platforms that sense and process their environment and communicate data thru a network to a command center. The recent emergence of chemical and explosive sensor technology based on silicon nanostructures, coupled with the fast evolution of low-cost CMOS imagers, low power DSP engines and integrated radio chips, has created an opportunity to realize the vision of autonomous wireless networks. These threat detection networks will perform sophisticated analysis at the sensor node and convey alarm information up the command chain. Sensor networks of this type are expected to revolutionize the ability to detect and locate biological, chemical, or explosive threats. The ability to distribute large numbers of low-cost sensors over large areas enables these devices to be close to the targeted threats and therefore improve detection efficiencies and enable rapid counter responses. These sensor networks will be used for homeland security, shipping container monitoring, and other applications such as laboratory medical analysis, drug discovery, automotive, environmental and/or in-vivo monitoring. Avaak"s system concept is to image a chromatic biological, chemical and/or explosive sensor utilizing a digital imager, analyze the images and distribute alarm or image data wirelessly through the network. All the imaging, processing and communications would take place within the miniature, low cost distributed sensor platforms. This concept however presents a significant challenge due to a combination and convergence of required new technologies, as mentioned above. Passive biological and chemical sensors with very high sensitivity and which require no assaying are in development using a technique to optically and chemically encode silicon wafers with tailored nanostructures. The silicon wafer is patterned with nano-structures designed to change colors ad patterns when exposed to the target analytes (TICs, TIMs, VOC). A small video camera detects the color and pattern changes on the sensor. To determine if an alarm condition is present, an on board DSP processor, using specialized image processing algorithms and statistical analysis, determines if color gradient changes occurred on the sensor array. These sensors can detect several agents simultaneously. This system is currently under development by Avaak, with funding from DARPA through an SBIR grant.

Chemical analysis of pharmaceuticals and explosives in fingermarks using matrix-assisted laser desorption ionization/time-of-flight mass spectrometry.

PubMed

Kaplan-Sandquist, Kimberly; LeBeau, Marc A; Miller, Mark L

2014-02-01

Chemical analysis of latent fingermarks, "touch chemistry," has the potential of providing intelligence or forensically relevant information. Matrix-assisted laser desorption ionization/time-of-flight mass spectrometry (MALDI/TOF MS) was used as an analytical platform for obtaining mass spectra and chemical images of target drugs and explosives in fingermark residues following conventional fingerprint development methods and MALDI matrix processing. There were two main purposes of this research: (1) develop effective laboratory methods for detecting drugs and explosives in fingermark residues and (2) determine the feasibility of detecting drugs and explosives after casual contact with pills, powders, and residues. Further, synthetic latent print reference pads were evaluated as mimics of natural fingermark residue to determine if the pads could be used for method development and quality control. The results suggest that artificial amino acid and sebaceous oil residue pads are not suitable to adequately simulate natural fingermark chemistry for MALDI/TOF MS analysis. However, the pads were useful for designing experiments and setting instrumental parameters. Based on the natural fingermark residue experiments, handling whole or broken pills did not transfer sufficient quantities of drugs to allow for definitive detection. Transferring drugs or explosives in the form of powders and residues was successful for preparing analytes for detection after contact with fingers and deposition of fingermark residue. One downfall to handling powders was that the analyte particles were easily spread beyond the original fingermark during development. Analyte particles were confined in the original fingermark when using transfer residues. The MALDI/TOF MS was able to detect procaine, pseudoephedrine, TNT, and RDX from contact residue under laboratory conditions with the integration of conventional fingerprint development methods and MALDI matrix. MALDI/TOF MS is a nondestructive technique which provides chemical information in both the mass spectra and chemical images. Published by Elsevier Ireland Ltd.

Multiple kernel based feature and decision level fusion of iECO individuals for explosive hazard detection in FLIR imagery

NASA Astrophysics Data System (ADS)

Price, Stanton R.; Murray, Bryce; Hu, Lequn; Anderson, Derek T.; Havens, Timothy C.; Luke, Robert H.; Keller, James M.

2016-05-01

A serious threat to civilians and soldiers is buried and above ground explosive hazards. The automatic detection of such threats is highly desired. Many methods exist for explosive hazard detection, e.g., hand-held based sensors, downward and forward looking vehicle mounted platforms, etc. In addition, multiple sensors are used to tackle this extreme problem, such as radar and infrared (IR) imagery. In this article, we explore the utility of feature and decision level fusion of learned features for forward looking explosive hazard detection in IR imagery. Specifically, we investigate different ways to fuse learned iECO features pre and post multiple kernel (MK) support vector machine (SVM) based classification. Three MK strategies are explored; fixed rule, heuristics and optimization-based. Performance is assessed in the context of receiver operating characteristic (ROC) curves on data from a U.S. Army test site that contains multiple target and clutter types, burial depths and times of day. Specifically, the results reveal two interesting things. First, the different MK strategies appear to indicate that the different iECO individuals are all more-or-less important and there is not a dominant feature. This is reinforcing as our hypothesis was that iECO provides different ways to approach target detection. Last, we observe that while optimization-based MK is mathematically appealing, i.e., it connects the learning of the fusion to the underlying classification problem we are trying to solve, it appears to be highly susceptible to over fitting and simpler, e.g., fixed rule and heuristics approaches help us realize more generalizable iECO solutions.

Position-adaptive explosive detection concepts for swarming micro-UAVs

NASA Astrophysics Data System (ADS)

Selmic, Rastko R.; Mitra, Atindra

2008-04-01

We have formulated a series of position-adaptive sensor concepts for explosive detection applications using swarms of micro-UAV's. These concepts are a generalization of position-adaptive radar concepts developed for challenging conditions such as urban environments. For radar applications, this concept is developed with platforms within a UAV swarm that spatially-adapt to signal leakage points on the perimeter of complex clutter environments to collect information on embedded objects-of-interest. The concept is generalized for additional sensors applications by, for example, considering a wooden cart that contains explosives. We can formulate system-of-systems concepts for a swarm of micro-UAV's in an effort to detect whether or not a given cart contains explosives. Under this new concept, some of the members of the UAV swarm can serve as position-adaptive "transmitters" by blowing air over the cart and some of the members of the UAV swarm can serve as position-adaptive "receivers" that are equipped with chem./bio sensors that function as "electronic noses". The final objective can be defined as improving the particle count for the explosives in the air that surrounds a cart via development of intelligent position-adaptive control algorithms in order to improve the detection and false-alarm statistics. We report on recent simulation results with regard to designing optimal sensor placement for explosive or other chemical agent detection. This type of information enables the development of intelligent control algorithms for UAV swarm applications and is intended for the design of future system-of-systems with adaptive intelligence for advanced surveillance of unknown regions. Results are reported as part of a parametric investigation where it is found that the probability of contaminant detection depends on the air flow that carries contaminant particles, geometry of the surrounding space, leakage areas, and other factors. We present a concept of position-adaptive detection (i.e. based on the example in the previous paragraph) consisting of position-adaptive fluid actuators (fans) and position-adaptive sensors. Based on these results, a preliminary analysis of sensor requirements for these fluid actuators and sensors is presented for small-UAVs in a field-enabled explosive detection environment. The computational fluid dynamics (CFD) simulation software Fluent is used to simulate the air flow in the corridor model containing a box with explosive particles. It is found that such flow is turbulent with Reynolds number greater than 106. Simulation methods and results are presented which show particle velocity and concentration distribution throughout the closed box. The results indicate that the CFD-based method can be used for other sensor placement and deployment optimization problems. These techniques and results can be applied towards the development of future system-of-system UAV swarms for defense, homeland defense, and security applications.

Handheld and mobile hyperspectral imaging sensors for wide-area standoff detection of explosives and chemical warfare agents

NASA Astrophysics Data System (ADS)

Gomer, Nathaniel R.; Gardner, Charles W.; Nelson, Matthew P.

2016-05-01

Hyperspectral imaging (HSI) is a valuable tool for the investigation and analysis of targets in complex background with a high degree of autonomy. HSI is beneficial for the detection of threat materials on environmental surfaces, where the concentration of the target of interest is often very low and is typically found within complex scenery. Two HSI techniques that have proven to be valuable are Raman and shortwave infrared (SWIR) HSI. Unfortunately, current generation HSI systems have numerous size, weight, and power (SWaP) limitations that make their potential integration onto a handheld or field portable platform difficult. The systems that are field-portable do so by sacrificing system performance, typically by providing an inefficient area search rate, requiring close proximity to the target for screening, and/or eliminating the potential to conduct real-time measurements. To address these shortcomings, ChemImage Sensor Systems (CISS) is developing a variety of wide-field hyperspectral imaging systems. Raman HSI sensors are being developed to overcome two obstacles present in standard Raman detection systems: slow area search rate (due to small laser spot sizes) and lack of eye-safety. SWIR HSI sensors have been integrated into mobile, robot based platforms and handheld variants for the detection of explosives and chemical warfare agents (CWAs). In addition, the fusion of these two technologies into a single system has shown the feasibility of using both techniques concurrently to provide higher probability of detection and lower false alarm rates. This paper will provide background on Raman and SWIR HSI, discuss the applications for these techniques, and provide an overview of novel CISS HSI sensors focused on sensor design and detection results.

Portable SERS Instrument for Explosives Monitoring

DTIC Science & Technology

2008-01-01

groundwater monitoring from a cone penetrometer (CPT) platform (5) Demonstrate improved capability for discriminating explosives versus colorimetry ...interference, and better discrimination of individual explosives compared to colorimetry • Applicability to virtually any environmental water...chemicals such as nitroaromatics or nitramines. While this makes colorimetry more generally applicable at explosive sites, it also limits the ability to

Development of a QCL based IR polarimetric system for the stand-off detection and location of IEDs

NASA Astrophysics Data System (ADS)

Stokes, Robert J.; Normand, Erwan L.; Carrie, Iain D.; Foulger, Brian; Lewis, Colin

2009-09-01

Following the development of point sensing improvised explosive device (IED) technology[1] Cascade Technologies have initial work in the development of equivalent stand-off capability. Stand-off detection of IEDs is a very important technical requirement that would enable the safe identification and quantification of hazardous materials prior to a terrorist attack. This could provide advanced warning of potential danger allowing evacuation and mitigation measures to be implemented. With support from the UK government, Cascade Technologies is currently investigating technology developments aimed at addressing the above stand-off IED detection capability gap. To demonstrate and validate the concept, a novel stand-off platform will target the detection and identification of common high vapor pressure IED precursor compounds, such as hydrogen peroxide (H2O2), emanating from a point source. By actively probing a scene with polarized light, the novel platform will offer both enhanced selectivity and sensitivity as compared to traditional hyperspectral sensors, etc. The presentation will highlight the concept of this novel detection technique as well as illustrating preliminary results.

Structures to Resist the Effects of Accidental Explosions. Volume 6. Special Considerations in Explosive Facility Design

DTIC Science & Technology

1985-04-01

mass is taken to be a rigid body . It is assumed that the base of the system is subjected to a periodic sinusoidal motion whose frequency is f. The...Step 9. Verify rigid body motion of the platform. - ■■:’-^V’^’:-’ The natural frequency of the individual members of the platform should be at least...5 times greater than the natural frequency of the system for rigid body motion of the platform to occur. - .’ : To increase the frequency of the

The Shock and Vibration Bulletin. Part 2. Structural Analysis, Design Techniques

DTIC Science & Technology

1973-06-01

FLOATING SHOCK PLATFORM SUBJECTED TO UNDERWATER EXPLOSIONS R. P. Brooks, and B. C, McNalght Naval Air Engineering Center Philadelphia, Pa, A lumped...Lohwasser, Air Force Flight Dynamics Laboratory, Wright -Patterson APB, Ohio AN ALGORITHM FOR SEMI-INVERSE ANALYSIS OF NONLINEAR DYNAMIC SYSTEMS ... 65 R...MATHEMATICAL MODEL OF A TYPICAL.FOATING SHOCK PLATFORM SSUBJECTED TO-UNDERWATE- EXPLOSIONS .......... ...................... 143 R. P. Brooks and B. C

Silicon-nanomembrane-based photonic crystal nanostructures for chip-integrated open sensor systems

NASA Astrophysics Data System (ADS)

Chakravarty, Swapnajit; Lai, Wei-Cheng; Zou, Yi; Lin, Cheyun; Wang, Xiaolong; Chen, Ray T.

2011-11-01

We experimentally demonstrate two devices on the photonic crystal platform for chip-integrated optical absorption spectroscopy and chip-integrated biomolecular microarray assays. Infrared optical absorption spectroscopy and biomolecular assays based on conjugate-specific binding principles represent two dominant sensing mechanisms for a wide spectrum of applications in environmental pollution sensing in air and water, chem-bio agents and explosives detection for national security, microbial contamination sensing in food and beverages to name a few. The easy scalability of photonic crystal devices to any wavelength ensures that the sensing principles hold across a wide electromagnetic spectrum. Silicon, the workhorse of the electronics industry, is an ideal platform for the above optical sensing applications.

Detection of Explosive Devices using X-ray Backscatter Radiation

NASA Astrophysics Data System (ADS)

Faust, Anthony A.

2002-09-01

It is our goal to develop a coded aperture based X-ray backscatter imaging detector that will provide sufficient speed, contrast and spatial resolution to detect Antipersonnel Landmines and Improvised Explosive Devices (IED). While our final objective is to field a hand-held detector, we have currently constrained ourselves to a design that can be fielded on a small robotic platform. Coded aperture imaging has been used by the observational gamma astronomy community for a number of years. However, it has been the recent advances in the field of medical nuclear imaging which has allowed for the application of the technique to a backscatter scenario. In addition, driven by requirements in medical applications, advances in X-ray detection are continually being made, and detectors are now being produced that are faster, cheaper and lighter than those only a decade ago. With these advances, a coded aperture hand-held imaging system has only recently become a possibility. This paper will begin with an introduction to the technique, identify recent advances which have made this approach possible, present a simulated example case, and conclude with a discussion on future work.

Structures to Resist the Effects of Accidental Explosions

DTIC Science & Technology

1990-11-01

Mott, R.I., A Theory of Fragmentation, Army Operational Research Group Memorandun, 113-AC-6427, Great Britain, 1943. 77. Non -Nuclear Weapons Effects...58.1. General Elements which protect non -sensitive explosives may be designed for controlled post-failure fragments with a substantial cost savings...6-49.3.2. Platform Characteristics A platform for group mounted systems offers great flexibility in controlling the center of gravity of the

Chemical analysis kit for the presence of explosives

DOEpatents

Eckels, Joel Del [Livermore, CA; Nunes,; Peter, J [Danville, CA; Alcaraz, Armando [Livermore, CA; Whipple, Richard E [Livermore, CA

2011-05-10

A tester for testing for explosives associated with a test location comprising a first explosives detecting reagent; a first reagent holder, the first reagent holder containing the first explosives detecting reagent; a second explosives detecting reagent; a second reagent holder, the second reagent holder containing the second explosives detecting reagent; a sample collection unit for exposure to the test location, exposure to the first explosives detecting reagent, and exposure to the second explosives detecting reagent; and a body unit containing a heater for heating the sample collection unit for testing the test location for the explosives.

Advances in neutron based bulk explosive detection

NASA Astrophysics Data System (ADS)

Gozani, Tsahi; Strellis, Dan

2007-08-01

Neutron based explosive inspection systems can detect a wide variety of national security threats. The inspection is founded on the detection of characteristic gamma rays emitted as the result of neutron interactions with materials. Generally these are gamma rays resulting from thermal neutron capture and inelastic scattering reactions in most materials and fast and thermal neutron fission in fissile (e.g.235U and 239Pu) and fertile (e.g.238U) materials. Cars or trucks laden with explosives, drugs, chemical agents and hazardous materials can be detected. Cargo material classification via its main elements and nuclear materials detection can also be accomplished with such neutron based platforms, when appropriate neutron sources, gamma ray spectroscopy, neutron detectors and suitable decision algorithms are employed. Neutron based techniques can be used in a variety of scenarios and operational modes. They can be used as stand alones for complete scan of objects such as vehicles, or for spot-checks to clear (or validate) alarms indicated by another inspection system such as X-ray radiography. The technologies developed over the last two decades are now being implemented with good results. Further advances have been made over the last few years that increase the sensitivity, applicability and robustness of these systems. The advances range from the synchronous inspection of two sides of vehicles, increasing throughput and sensitivity and reducing imparted dose to the inspected object and its occupants (if any), to taking advantage of the neutron kinetic behavior of cargo to remove systematic errors, reducing background effects and improving fast neutron signals.

30 CFR 250.1727 - What information must I include in my final application to remove a platform or other facility?

Code of Federal Regulations, 2012 CFR

2012-07-01

....125. If you are proposing to use explosives, provide three copies of the application. If you are not proposing to use explosives, provide two copies of the application. Include the following information in the... use; (2) If you are using explosives, the following: (i) Type of explosives; (ii) Number and sizes of...

30 CFR 250.1727 - What information must I include in my final application to remove a platform or other facility?

Code of Federal Regulations, 2011 CFR

2011-07-01

... listed in § 250.125. If you are proposing to use explosives, provide three copies of the application. If you are not proposing to use explosives, provide two copies of the application. Include the following... will use; (2) If you are using explosives, the following: (i) Type of explosives; (ii) Number and sizes...

30 CFR 250.1727 - What information must I include in my final application to remove a platform or other facility?

Code of Federal Regulations, 2014 CFR

2014-07-01

....125. If you are proposing to use explosives, provide three copies of the application. If you are not proposing to use explosives, provide two copies of the application. Include the following information in the... use; (2) If you are using explosives, the following: (i) Type of explosives; (ii) Number and sizes of...

30 CFR 250.1727 - What information must I include in my final application to remove a platform or other facility?

Code of Federal Regulations, 2013 CFR

2013-07-01

....125. If you are proposing to use explosives, provide three copies of the application. If you are not proposing to use explosives, provide two copies of the application. Include the following information in the... use; (2) If you are using explosives, the following: (i) Type of explosives; (ii) Number and sizes of...

Historical Population Estimates For Several Fish Species At Offshore Oil and Gas Structures in the US Gulf of Mexico

NASA Astrophysics Data System (ADS)

Gitschlag, G.

2016-02-01

Population estimates were calculated for four fish species occurring at offshore oil and gas structures in water depths of 14-32 m off the Louisiana and upper Texas coasts in the US Gulf of Mexico. From 1993-1999 sampling was conducted at eight offshore platforms in conjunction with explosive salvage of the structures. To estimate fish population size prior to detonation of explosives, a fish mark-recapture study was conducted. Fish were captured on rod and reel using assorted hook sizes. Traps were occasionally used to supplement catches. Fish were tagged below the dorsal fin with plastic t-bar tags using tagging guns. Only fish that were alive and in good condition were released. Recapture sampling was conducted after explosives were detonated during salvage operations. Personnel operating from inflatable boats used dip nets to collect all dead fish that floated to the surface. Divers collected representative samples of dead fish that sank to the sea floor. Data provided estimates for red snapper (Lutjanus campechanus), Atlantic spadefish (Chaetodipterus faber), gray triggerfish (Balistes capriscus), and blue runner (Caranx crysos) at one or more of the eight platforms studied. At seven platforms, population size for red snapper was calculated at 503-1,943 with a 95% CI of 478. Abundance estimates for Atlantic spadefish at three platforms ranged from 1,432-1,782 with a 95% CI of 473. At three platforms, population size of gray triggerfish was 63-129 with a 95% CI of 82. Blue runner abundance at one platform was 558. Unlike the other three species which occur close to the platforms, blue runner range widely and recapture of this species was dependent on fish schools being in close proximity to the platform at the time explosives were detonated. Tag recapture was as high as 73% for red snapper at one structure studied.

Review of potential impacts to sea turtles from underwater explosive removal of offshore structures

DOE Office of Scientific and Technical Information (OSTI.GOV)

Viada, Stephen T.; Hammer, Richard M.; Racca, Roberto

2008-05-15

The purpose of this study was to collect and synthesize existing information relevant to the explosive removal of offshore structures (EROS) in aquatic environments. Data sources were organized and summarized by topic - explosive removal methods, physics of underwater explosions, sea turtle resources, documented impacts to sea turtles, and mitigation of effects. Information was gathered via electronic database searches and literature source review. Bulk explosive charges are the most commonly used technique in EROS. While the physical principles of underwater detonations and the propagation of pressure and acoustic waves are well understood, there are significant gaps in the application ofmore » this knowledge. Impacts to sea turtles from explosive removal operations may range from non-injurious effects (e.g. acoustic annoyance; mild tactile detection or physical discomfort) to varying levels of injury (i.e. non-lethal and lethal injuries). Very little information exists regarding the impacts of underwater explosions on sea turtles. Effects of explosions on turtles often must be inferred from documented effects to other vertebrates with lungs or other gas-containing organs, such as mammals and most fishes. However, a cautious approach should be used when determining impacts to sea turtles based on extrapolations from other vertebrates. The discovery of beached sea turtles and bottlenose dolphins following an explosive platform removal event in 1986 prompted the initiation of formal consultation between the U.S. Department of the Interior, Minerals Management Service (MMS) and the National Marine Fisheries Service (NMFS), authorized through the Endangered Species Act Section 7, to determine a mechanism to minimize potential impacts to listed species. The initial consultation resulted in a requirement for oil and gas companies to obtain a permit (through separate consultations on a case-by-case basis) prior to using explosives in Federal waters. Because many offshore structure removal operations are similar, a 'generic' Incidental Take Statement was established by the NMFS that describes requirements to protect sea turtles when an operator's individual charge weights did not exceed 50 lb (23 kg). Requirements associated with the Incidental Take Permit were revised in 2003 and 2006 to accommodate advances in explosive charge technologies, removals of structures in deeper waters, and adequate protection of deep water marine mammal species in Gulf of Mexico waters. Generally, these requirements include pre- and post-detonation visual monitoring using standard surface and aerial survey methods for sea turtles and marine mammals, and, in some scenarios, passive acoustic survey methods for marine mammals within a specified radius from an offshore structure. The survey program has been successful in mitigating impacts to sea turtles associated with EROS. However, even with these protective measures in place, there have been observations of sea turtles affected by explosive platform removals.« less

Development of a plug-type IMS-MS instrument and its applications in resolving problems existing in in-situ detection of illicit drugs and explosives by IMS.

PubMed

Du, Zhenxia; Sun, Tangqiang; Zhao, Jianan; Wang, Di; Zhang, Zhongxia; Yu, Wenlian

2018-07-01

Ion mobility spectrometry (IMS) which acts as a rapid analysis technique is widely used in the field detection of illicit drugs and explosives. Due to limited separation abilities of the pint-sized IMS challenges and problems still exist regarding high false positive and false negative responses due to the interference of the matrix. In addition, the gas-phase ion chemistry and special phenomena in the IMS spectra, such one substance showing two peaks, were not identified unambiguously. In order to explain or resolve these questions, in this paper, an ion mobility spectrometry was coupled to a mass spectrometry (IMS-MS). A commercial IMS is embedded in a custom-built ion chamber shell was attached to the mass spectrometer. The faraday plate of IMS was fabricated with a hole for the ions to passing through to the mass spectrometer. The ion transmission efficiency of IMS-MS was optimized by optimizing the various parameters, especially the distance between the faraday plate and the cone of mass spectrum. This design keeps the integrity of the two original instruments and the mass spectrometry still works with multimode ionization source (i.e., IMS-MS, ESI-MS, APCI-MS modes). The illicit drugs and explosive samples were analyzed by the IMS-MS with 63 Ni source. The results showed that the IMS-MS is of high sensitivity. The ionization mechanism of the illicit drug and explosive samples with 63 Ni source were systematically studied. In addition, the interferent which interfered the detection of cocaine was identified as dibutyl phthalate (DBP) by this platform. The reason why the acetone solution of amphetamine showed two peaks was explained. Copyright © 2018 Elsevier B.V. All rights reserved.

Graphene-Plasmonic Hybrid Platform for Label-Free SERS Biomedical Detection

NASA Astrophysics Data System (ADS)

Wang, Pu

Surface Enhanced Raman Scattering (SERS) has attracted explosive interest for the wealth of vibrational information it provides with minimal invasive effects to target analyte. Nanotechnology, especially in the form of noble metal nanoparticles exhibit unique electromagnetic and chemical characteristics that are explored to realize ultra-sensitive SERS detection in chemical and biological analysis. Graphene, atom-thick carbon monolayer, exhibits superior chemical stability and bio-compatibility. A combination of SERS-active metal nanostructures and graphene will create various synergies in SERS. The main objective of this research was to exploit the applications of the graphene-Au tip hybrid platform in SERS. The hybrid platform consists of a periodic Au nano-pyramid substrate to provide reproducible plasmonic enhancement, and the superimposed monolayer graphene sheet, serving as "built-in" Raman marker. Extensive theoretical and experimental studies were conducted to determine the potentials of the hybrid platform as SERS substrate. Results from both Finite-Domain Time-Domain (FDTD) numerical simulation and Raman scattering of graphene suggested that the hybrid platform boosted a high density of hotspots yielding 1000 times SERS enhancement of graphene bands. Ultra-high sensitivity of the hybrid platform was demonstrated by bio-molecules including dye, protein and neurotransmitters. Dopamine and serotonin can be detected and distinguished at 10-9 M concentration in the presence of human body fluid. Single molecule detection was obtained using a bi-analyte technique. Graphene supported a vibration mode dependent SERS chemical enhancement of ˜10 to the analyte. Quantitative evaluation of hotspots was presented using spatially resolved Raman mapping of graphene SERS enhancement. Graphene plays a crucial role in quantifying SERS hotspots and paves the path for defining SERS EF that could be universally applied to various SERS systems. A reproducible and statistically reliable SERS quantification approach using the hybrid platform was proposed. The SERS mapping based approach not only leverages the ultra-sensitivity but also minimizes the spot-to-spot variations. Feasibility of biomedical diagnosis with the hybrid platform was exploited by colon cancer cell sensing and time-dependent SERS of amyloid beta protein monomer. The capabilities of the platform are demonstrated by colon cancer cell detection in simulated body fluid background with cell concentration down to 50 cells /mL. Sensitivity of 95% was evidenced by Principle Components Analysis (PCA). Besides, a noticeable evolution profile of the Abeta SERS peaks was observed and attributed to the Abeta configurational change. Taken together, the results suggested the graphene-plasmonic hybrid platform can potentially deliver a biomedical detection and diagnostic imaging platform with superior sensitivity and resolution.

Effect of Heavy Dynamic Resistive Exercise on Acute Upper-Body Power.

ERIC Educational Resources Information Center

Hrysomallis, Con; Kidgell, Dawson

2001-01-01

Determined the influence of a heavy-load bench press on indicators of upper-body power during an explosive pushup, examining the influence of a set of 5 repetitions of 5 repetition maximum (RM) bench press preceding explosive pushups. There were no significant differences for any of the force platform data when explosive pushups were preceded by…

Comparison of spatial frequency domain features for the detection of side attack explosive ballistics in synthetic aperture acoustics

NASA Astrophysics Data System (ADS)

Dowdy, Josh; Anderson, Derek T.; Luke, Robert H.; Ball, John E.; Keller, James M.; Havens, Timothy C.

2016-05-01

Explosive hazards in current and former conflict zones are a threat to both military and civilian personnel. As a result, much effort has been dedicated to identifying automated algorithms and systems to detect these threats. However, robust detection is complicated due to factors like the varied composition and anatomy of such hazards. In order to solve this challenge, a number of platforms (vehicle-based, handheld, etc.) and sensors (infrared, ground penetrating radar, acoustics, etc.) are being explored. In this article, we investigate the detection of side attack explosive ballistics via a vehicle-mounted acoustic sensor. In particular, we explore three acoustic features, one in the time domain and two on synthetic aperture acoustic (SAA) beamformed imagery. The idea is to exploit the varying acoustic frequency profile of a target due to its unique geometry and material composition with respect to different viewing angles. The first two features build their angle specific frequency information using a highly constrained subset of the signal data and the last feature builds its frequency profile using all available signal data for a given region of interest (centered on the candidate target location). Performance is assessed in the context of receiver operating characteristic (ROC) curves on cross-validation experiments for data collected at a U.S. Army test site on different days with multiple target types and clutter. Our preliminary results are encouraging and indicate that the top performing feature is the unrolled two dimensional discrete Fourier transform (DFT) of SAA beamformed imagery.

Conjugated Polymer Nanoparticles for the Amplified Detection of Nitro-explosive Picric Acid on Multiple Platforms.

PubMed

Malik, Akhtar Hussain; Hussain, Sameer; Kalita, Anamika; Iyer, Parameswar Krishnan

2015-12-09

Spontaneously formed conjugated polymer nanoparticles (CPNs) or polymer dots displayed remarkable fluorescence response toward nitroexplosive-picric acid (PA) in multiple environments including 100% aqueous media, solid support using portable paper strips and vapor phase detection via two terminal device. This new cationic conjugated polyelectrolyte (CPE) poly(3,3'-((2-phenyl-9H-fluorene-9,9-diyl)bis(hexane-6,1-diyl))bis(1-methyl-1H-imidazol-3-ium)bromide) (PFMI) was synthesized by Suzuki coupling polymerization followed by post functionalization method without employing any hectic purification technique. Highest quenching constant value (K(sv)) of 1.12 × 10(8) M(-1) and a very low detection limit of 30.9 pM/7.07 ppt were obtained exclusively for PA in 100% aqueous environment which is rare and unique for any CPE/CPNs. Contact mode detection of PA was also performed using simple, cost-effective and portable fluorescent paper strips for achieving on-site detection. Furthermore, the two terminal sensor device fabricated with nanoparticles of PFMI (PFMI-NPs) provides an exceptional and unprecedented platform for the vapor mode detection of PA under ambient conditions. The mechanism for the ultrasensitivity of PFMI-NPs probe to detect PA is attributed to the "molecular-wire effect", electrostatic interaction, photoinduced electron transfer (PET), and possible resonance energy transfer (RET).

Detection of vehicle-based improvised explosives using ultra-trace detection equipment

NASA Astrophysics Data System (ADS)

Fisher, Mark; Sikes, John; Prather, Mark; Wichert, Clint

2005-05-01

Vehicle-borne improvised explosive devices (VBIEDs) have become the weapon of choice for insurgents in Iraq. At the same time, these devices are becoming increasingly sophisticated and effective. VBIEDs can be difficult to detect during visual inspection of vehicles. This is especially true when explosives have been hidden behind a vehicle"s panels, inside seat cushions, under floorboards, or behind cargo. Even though the explosive may not be visible, vapors of explosive emanating from the device are often present in the vehicle, but the current generation of trace detection equipment has not been sensitive enough to detect these low concentrations of vapor. This paper presents initial test results using the Nomadics Fido sensor for detection of VBIEDs. The sensor is a small, explosives detector with unprecedented levels of sensitivity for detection of nitroaromatic explosives. Fido utilizes fluorescence quenching of novel polymer materials to detect traces of explosive vapor emanating from targets containing explosives. These materials, developed by collaborators at the Massachusetts Institute of Technology (MIT), amplify the quenching response that occurs when molecules of explosive bind to films of the polymer. These materials have enabled development of sensors with performance approaching that of canines trained to detect explosives. The ability of the sensor to detect explosives in vehicles and on persons who have recently been in close proximity to explosives has recently been demonstrated. In these tests, simulated targets were quickly and easily detected using a Fido sensor in conjunction with both direct vapor and swipe sampling methods. The results of these tests suggest that chemical vapor sensing has utility as a means of screening vehicles for explosives at checkpoints and on patrols.

27 CFR 555.182 - Exceptions.

Code of Federal Regulations, 2013 CFR

2013-04-01

... testing of new or modified explosive materials; (2) Training in explosives detection or development or testing of explosives detection equipment; or (3) Forensic science purposes; or (b) Was plastic explosive... EXPLOSIVES, DEPARTMENT OF JUSTICE EXPLOSIVES COMMERCE IN EXPLOSIVES Marking of Plastic Explosives § 555.182...

27 CFR 555.182 - Exceptions.

Code of Federal Regulations, 2014 CFR

2014-04-01

... testing of new or modified explosive materials; (2) Training in explosives detection or development or testing of explosives detection equipment; or (3) Forensic science purposes; or (b) Was plastic explosive... EXPLOSIVES, DEPARTMENT OF JUSTICE EXPLOSIVES COMMERCE IN EXPLOSIVES Marking of Plastic Explosives § 555.182...

Spot test kit for explosives detection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Pagoria, Philip F; Whipple, Richard E; Nunes, Peter J

An explosion tester system comprising a body, a lateral flow membrane swab unit adapted to be removeably connected to the body, a first explosives detecting reagent, a first reagent holder and dispenser operatively connected to the body, the first reagent holder and dispenser containing the first explosives detecting reagent and positioned to deliver the first explosives detecting reagent to the lateral flow membrane swab unit when the lateral flow membrane swab unit is connected to the body, a second explosives detecting reagent, and a second reagent holder and dispenser operatively connected to the body, the second reagent holder and dispensermore » containing the second explosives detecting reagent and positioned to deliver the second explosives detecting reagent to the lateral flow membrane swab unit when the lateral flow membrane swab unit is connected to the body.« less

Flow-through nanohole array based sensor implemented on analogue smartphone components

NASA Astrophysics Data System (ADS)

Gomez-Cruz, Juan; Nair, Srijit; Ascanio, Gabriel; Escobedo, Carlos

2017-08-01

Mobile communications have massively populated the consumer electronics market over the past few years and it is now ubiquitous, providing a timeless opportunity for the development of smartphone-based technologies as point-of-care (POC) diagnosis tools1 . The expectation for a fully integrated smartphone-based sensor that enables applications such as environmental monitoring, explosive detection and biomedical analysis has increased among the scientific community in the past few years2,3. The commercialization forecast for smartphone-based sensing technologies is very promising, but reliable, miniature and cost-effective sensing platforms that can adapt to portable electronics in still under development. In this work, we present an integrated sensing platform based on flow-through metallic nanohole arrays. The nanohole arrays are 260 nm in diameter and 520 nm in pitch, fabricated using Focused Ion Beam (FIB) lithography. A white LED resembling a smartphone flash LED serves as light source to excite surface plasmons and the signal is recorded via a Complementary Metal-Oxide-Semiconductor (CMOS) module. The sensing abilities of the integrated sensing platform is demonstrated for the detection of (i) changes in bulk refractive index (RI), (ii) real-time monitoring of surface modification by receptor-analyte system of streptavidin-biotin.

On-site Rapid Detection of Trace Non-volatile Inorganic Explosives by Stand-alone Ion Mobility Spectrometry via Acid-enhanced Evaporization

PubMed Central

Peng, Liying; Hua, Lei; Wang, Weiguo; Zhou, Qinghua; Li, Haiyang

2014-01-01

New techniques for the field detection of inorganic improvised explosive devices (IEDs) are urgently developed. Although ion mobility spectrometry (IMS) has been proved to be the most effective method for screening organic explosives, it still faces a major challenge to detect inorganic explosives owing to their low volatilities. Herein, we proposed a strategy for detecting trace inorganic explosives by thermal desorption ion mobility spectrometry (TD-IMS) with sample-to-sample analysis time less than 5 s based on in-situ acidification on the sampling swabs. The responses for typical oxidizers in inorganic explosives, such as KNO3, KClO3 and KClO4 were at least enhanced by a factor of 3000 and their limits of detection were found to be subnanogram. The common organic explosives and their mixtures with inorganic oxidizers were detected, indicating that the acidification process did not affect the detection of organic explosives. Moreover, the typical inorganic explosives such as black powders, firecrackers and match head could be sensitively detected as well. These results demonstrated that this method could be easily employed in the current deployed IMS for on-site sensitive detection of either inorganic explosives or organic ones. PMID:25318960

27 CFR 555.180 - Prohibitions relating to unmarked plastic explosives.

Code of Federal Regulations, 2014 CFR

2014-04-01

... person shall manufacture any plastic explosive that does not contain a detection agent. (b) No person..., receive, or possess any plastic explosive that does not contain a detection agent. This paragraph does not... Plastic Explosives means the Convention on the Marking of Plastic Explosives for the Purposes of Detection...

27 CFR 555.180 - Prohibitions relating to unmarked plastic explosives.

Code of Federal Regulations, 2012 CFR

2012-04-01

... person shall manufacture any plastic explosive that does not contain a detection agent. (b) No person..., receive, or possess any plastic explosive that does not contain a detection agent. This paragraph does not... Plastic Explosives means the Convention on the Marking of Plastic Explosives for the Purposes of Detection...

27 CFR 555.180 - Prohibitions relating to unmarked plastic explosives.

Code of Federal Regulations, 2013 CFR

2013-04-01

... person shall manufacture any plastic explosive that does not contain a detection agent. (b) No person..., receive, or possess any plastic explosive that does not contain a detection agent. This paragraph does not... Plastic Explosives means the Convention on the Marking of Plastic Explosives for the Purposes of Detection...

Highly selective and sensitive fluorescent paper sensor for nitroaromatic explosive detection.

PubMed

Ma, Yingxin; Li, Hao; Peng, Shan; Wang, Leyu

2012-10-02

Rapid, sensitive, and selective detection of explosives such as 2,4,6-trinitrotoluene (TNT) and 2,4,6-trinitrophenol (TNP), especially using a facile paper sensor, is in high demand for homeland security and public safety. Although many strategies have been successfully developed for the detection of TNT, it is not easy to differentiate the influence from TNP. Also, few methods were demonstrated for the selective detection of TNP. In this work, via a facile and versatile method, 8-hydroxyquinoline aluminum (Alq(3))-based bluish green fluorescent composite nanospheres were successfully synthesized through self-assembly under vigorous stirring and ultrasonic treatment. These polymer-coated nanocomposites are not only water-stable but also highly luminescent. Based on the dramatic and selective fluorescence quenching of the nanocomposites via adding TNP into the aqueous solution, a sensitive and robust platform was developed for visual detection of TNP in the mixture of nitroaromatics including TNT, 2,4-dinitrotoluene (DNT), and nitrobenzene (NB). Meanwhile, the fluorescence intensity is proportional to the concentration of TNP in the range of 0.05-7.0 μg/mL with the 3σ limit of detection of 32.3 ng/mL. By handwriting or finger printing with TNP solution as ink on the filter paper soaked with the fluorescent nanocomposites, the bluish green fluorescence was instantly and dramatically quenched and the dark patterns were left on the paper. Therefore, a convenient and rapid paper sensor for TNP-selective detection was fabricated.

49 CFR 1544.213 - Use of explosives detection systems.

Code of Federal Regulations, 2011 CFR

2011-10-01

... 49 Transportation 9 2011-10-01 2011-10-01 false Use of explosives detection systems. 1544.213...: AIR CARRIERS AND COMMERCIAL OPERATORS Operations § 1544.213 Use of explosives detection systems. (a) Use of explosive detection equipment. If TSA so requires by an amendment to an aircraft operator's...

49 CFR 1544.213 - Use of explosives detection systems.

Code of Federal Regulations, 2014 CFR

2014-10-01

... 49 Transportation 9 2014-10-01 2014-10-01 false Use of explosives detection systems. 1544.213...: AIR CARRIERS AND COMMERCIAL OPERATORS Operations § 1544.213 Use of explosives detection systems. (a) Use of explosive detection equipment. If TSA so requires by an amendment to an aircraft operator's...

49 CFR 1544.213 - Use of explosives detection systems.

Code of Federal Regulations, 2013 CFR

2013-10-01

... 49 Transportation 9 2013-10-01 2013-10-01 false Use of explosives detection systems. 1544.213...: AIR CARRIERS AND COMMERCIAL OPERATORS Operations § 1544.213 Use of explosives detection systems. (a) Use of explosive detection equipment. If TSA so requires by an amendment to an aircraft operator's...

49 CFR 1544.213 - Use of explosives detection systems.

Code of Federal Regulations, 2012 CFR

2012-10-01

... 49 Transportation 9 2012-10-01 2012-10-01 false Use of explosives detection systems. 1544.213...: AIR CARRIERS AND COMMERCIAL OPERATORS Operations § 1544.213 Use of explosives detection systems. (a) Use of explosive detection equipment. If TSA so requires by an amendment to an aircraft operator's...

Increasing selectivity for TNT-based explosive detection by synchronous luminescence and derivative spectroscopy with quantum yields of selected aromatic amines.

PubMed

Sheaff, Chrystal N; Eastwood, Delyle; Wai, Chien M

2007-01-01

The detection of explosive material is at the forefront of current analytical problems. A detection method is desired that is not restricted to detecting only explosive materials, but is also capable of identifying the origin and type of explosive. It is essential that a detection method have the selectivity to distinguish among compounds in a mixture of explosives. The nitro compounds found in explosives have low fluorescent yields or are considered to be non-fluorescent; however, after reduction, the amino compounds exhibit relatively high fluorescence. We discuss how to increase selectivity of explosive detection using fluorescence; this includes synchronous luminescence and derivative spectroscopy with appropriate smoothing. By implementing synchronous luminescence and derivative spectroscopy, we were able to resolve the reduction products of one major TNT-based explosive compound, 2,4-diaminotoluene, and the reduction products of other minor TNT-based explosives in a mixture. We also report for the first time the quantum yields of these important compounds. Relative quantum yields are useful in establishing relative fluorescence intensities and are an important spectroscopic measurement of molecules. Our approach allows for rapid, sensitive, and selective detection with the discrimination necessary to distinguish among various explosives.

Genetically modified plants for tactical systems applications

NASA Astrophysics Data System (ADS)

Stewart, C. Neal, Jr.

2002-08-01

Plants are ubiquitous in the environment and have the ability to respond to their environment physiologically and through altered gene expression profiles (they cannot walk away). In addition, plant genetic transformation techniques and genomic information in plants are becoming increasingly advanced. We have been performing research to express the jellyfish green fluorescent protein (GFP) in plants. GFP emits green light when excited by blue or UV light. In addition, my group and collaborators have developed methods to detect GFP in plants by contact instruments and at a standoff. There are several tactical uses for this technology. Some obvious applications are using plants as sentinels for detecting biological and chemical warfare agents or their derivatives from a remote platform, as well as detecting explosives. Another tactical application is covert monitoring using individual plants. Different methods to detect GFP in transgenic plants will be discussed.

Laser-based standoff detection of explosives: a critical review.

PubMed

Wallin, Sara; Pettersson, Anna; Ostmark, Henric; Hobro, Alison

2009-09-01

A review of standoff detection technologies for explosives has been made. The review is focused on trace detection methods (methods aiming to detect traces from handling explosives or the vapours surrounding an explosive charge due to the vapour pressure of the explosive) rather than bulk detection methods (methods aiming to detect the bulk explosive charge). The requirements for standoff detection technologies are discussed. The technologies discussed are mostly laser-based trace detection technologies, such as laser-induced-breakdown spectroscopy, Raman spectroscopy, laser-induced-fluorescence spectroscopy and IR spectroscopy but the bulk detection technologies millimetre wave imaging and terahertz spectroscopy are also discussed as a complement to the laser-based methods. The review includes novel techniques, not yet tested in realistic environments, more mature technologies which have been tested outdoors in realistic environments as well as the most mature millimetre wave imaging technique.

A non-imaging polarized terahertz passive system for detecting and identifying concealed explosives

NASA Astrophysics Data System (ADS)

Karam, Mostafa A.; Meyer, Doug

2011-06-01

Existing terahertz THz systems for detecting concealed explosives are not capable of identifying explosive type which leads to higher false alarm rates. Moreover, some of those systems are imaging systems that invade personal privacy, and require more processing and computational resources. Other systems have no polarization preference which makes them incapable of capturing the geometric features of an explosive. In this study a non-imaging polarized THz passive system for detecting and identifying concealed explosives overcoming the forgoing shortcomings is developed. The system employs a polarized passive THz sensor in acquiring emitted data from a scene that may have concealed explosives. The acquired data are decomposed into their natural resonance frequencies, and the number of those frequencies is used as criteria in detecting the explosive presence. If the presence of an explosive is confirmed, a set of physically based retrieval algorithms is used in extracting the explosive dielectric constant/refractive index value from natural resonance frequencies and amplitudes of associated signals. Comparing the refractive index value against a database of refractive indexes of known explosives identifies the explosive type. As an application, a system having a dual polarized radiometer operating within the frequency band of 0.62- 0.82 THz is presented and used in detecting and identifying person borne C-4 explosive concealed under a cotton garment. The system showed higher efficiencies in detecting and identifying the explosive.

Raman scattering spectroscopy for explosives identification

NASA Astrophysics Data System (ADS)

Nagli, L.; Gaft, M.

2007-04-01

Real time detection and identification of explosives at a standoff distance is a major issue in efforts to develop defense against so-called Improvised Explosive Devices (IED). It is recognized that the only technique, which is potentially capable to standoff detection of minimal amounts of explosives is laser-based spectroscopy. LDS technique belongs to trace detection, namely to its micro-particles variety. We applied gated Raman and time-resolved luminescence spectroscopy for detection of main explosive materials, both factory and homemade. Raman system was developed and tested by LDS for field remote detection and identification of minimal amounts of explosives on relevant surfaces at a distance of up to 30 meters.

UV gated Raman spectroscopy for standoff detection of explosives

NASA Astrophysics Data System (ADS)

Gaft, M.; Nagli, L.

2008-07-01

Real-time detection and identification of explosives at a standoff distance is a major issue in efforts to develop defense against so-called improvised explosive devices (IED). It is recognized that the only method, which is potentially capable to standoff detection of minimal amounts of explosives is laser-based spectroscopy. LDS technique belongs to trace detection, namely to its micro-particles variety. It is based on commonly held belief that surface contamination was very difficult to avoid and could be exploited for standoff detection. We have applied gated Raman spectroscopy for detection of main explosive materials, both factory and homemade. We developed and tested a Raman system for the field remote detection and identification of minimal amounts of explosives on relevant surfaces at a distance of up to 30 m.

Portable thin layer chromatography for field detection of explosives and propellants

NASA Astrophysics Data System (ADS)

Satcher, Joe H.; Maienschein, Jon L.; Pagoria, Philip F.; Racoveanu, Ana; Carman, M. Leslie; Whipple, Richard E.; Reynolds, John G.

2012-06-01

A field deployable detection kit for explosives and propellants using thin layer chromatography (TLC) has been developed at Lawrence Livermore National Laboratory (LLNL). The chemistry of the kit has been modified to allow for field detection of propellants (through propellant stabilizers), military explosives, peroxide explosives, nitrates and inorganic oxidizer precursors. For many of these target analytes, the detection limit is in the μg to pg range. A new miniaturized, bench prototype, field portable TLC (Micro TLC) kit has also been developed for the detection and identification of common military explosives. It has been demonstrated in a laboratory environment and is ready for field-testing. The kit is comprised of a low cost set of commercially available components specifically assembled for rapid identification needed in the field and identifies the common military explosives: HMX, RDX, Tetryl, Explosive D or picric acid, and TNT all on one plate. Additional modifications of the Micro TLC system have been made with fluorescent organosilicon co-polymer coatings to detect a large suite of explosives.

27 CFR 555.182 - Exceptions.

Code of Federal Regulations, 2010 CFR

2010-04-01

... testing of new or modified explosive materials; (2) Training in explosives detection or development or testing of explosives detection equipment; or (3) Forensic science purposes; or (b) Was plastic explosive...

27 CFR 555.182 - Exceptions.

Code of Federal Regulations, 2012 CFR

2012-04-01

... or modified explosive materials; (2) Training in explosives detection or development or testing of explosives detection equipment; or (3) Forensic science purposes; or (b) Was plastic explosive that, by April... 555.182 Alcohol, Tobacco Products, and Firearms BUREAU OF ALCOHOL, TOBACCO, FIREARMS, AND EXPLOSIVES...

27 CFR 555.182 - Exceptions.

Code of Federal Regulations, 2011 CFR

2011-04-01

... or modified explosive materials; (2) Training in explosives detection or development or testing of explosives detection equipment; or (3) Forensic science purposes; or (b) Was plastic explosive that, by April... 555.182 Alcohol, Tobacco Products, and Firearms BUREAU OF ALCOHOL, TOBACCO, FIREARMS, AND EXPLOSIVES...

Explosives Detection: Exploitation of the Physical Signatures

NASA Astrophysics Data System (ADS)

Atkinson, David

2010-10-01

Explosives based terrorism is an ongoing threat that is evolving with respect to implementation, configuration and materials used. There are a variety of devices designed to detect explosive devices, however, each technology has limitations and operational constraints. A full understanding of the signatures available for detection coupled with the array of detection choices can be used to develop a conceptual model of an explosives screening operation. Physics based sensors provide a robust approach to explosives detection, typically through the identification of anomalies, and are currently used for screening in airports around the world. The next generation of detectors for explosives detection will need to be more sensitive and selective, as well as integrate seamlessly with devices focused on chemical signatures. An appreciation for the details of the physical signature exploitation in cluttered environments with time, space, and privacy constraints is necessary for effective explosives screening of people, luggage, cargo, and vehicles.

Explosive simulants for testing explosive detection systems

DOEpatents

Kury, John W.; Anderson, Brian L.

1999-09-28

Explosives simulants that include non-explosive components are disclosed that facilitate testing of equipment designed to remotely detect explosives. The simulants are non-explosive, non-hazardous materials that can be safely handled without any significant precautions. The simulants imitate real explosives in terms of mass density, effective atomic number, x-ray transmission properties, and physical form, including moldable plastics and emulsions/gels.

49 CFR 1544.205 - Acceptance and screening of cargo.

Code of Federal Regulations, 2013 CFR

2013-10-01

... provided in its security program. Such methods may include TSA-approved x-ray systems, explosives detection systems, explosives trace detection, explosives detection canine teams certified by TSA, or a physical...) Preventing or deterring the carriage of any explosive or incendiary. Each aircraft operator operating under a...

49 CFR 1544.205 - Acceptance and screening of cargo.

Code of Federal Regulations, 2011 CFR

2011-10-01

... provided in its security program. Such methods may include TSA-approved x-ray systems, explosives detection systems, explosives trace detection, explosives detection canine teams certified by TSA, or a physical...) Preventing or deterring the carriage of any explosive or incendiary. Each aircraft operator operating under a...

49 CFR 1544.205 - Acceptance and screening of cargo.

Code of Federal Regulations, 2012 CFR

2012-10-01

... provided in its security program. Such methods may include TSA-approved x-ray systems, explosives detection systems, explosives trace detection, explosives detection canine teams certified by TSA, or a physical...) Preventing or deterring the carriage of any explosive or incendiary. Each aircraft operator operating under a...

49 CFR 1544.205 - Acceptance and screening of cargo.

Code of Federal Regulations, 2014 CFR

2014-10-01

... provided in its security program. Such methods may include TSA-approved x-ray systems, explosives detection systems, explosives trace detection, explosives detection canine teams certified by TSA, or a physical...) Preventing or deterring the carriage of any explosive or incendiary. Each aircraft operator operating under a...

Real-time, wide-area hyperspectral imaging sensors for standoff detection of explosives and chemical warfare agents

NASA Astrophysics Data System (ADS)

Gomer, Nathaniel R.; Tazik, Shawna; Gardner, Charles W.; Nelson, Matthew P.

2017-05-01

Hyperspectral imaging (HSI) is a valuable tool for the detection and analysis of targets located within complex backgrounds. HSI can detect threat materials on environmental surfaces, where the concentration of the target of interest is often very low and is typically found within complex scenery. Unfortunately, current generation HSI systems have size, weight, and power limitations that prohibit their use for field-portable and/or real-time applications. Current generation systems commonly provide an inefficient area search rate, require close proximity to the target for screening, and/or are not capable of making real-time measurements. ChemImage Sensor Systems (CISS) is developing a variety of real-time, wide-field hyperspectral imaging systems that utilize shortwave infrared (SWIR) absorption and Raman spectroscopy. SWIR HSI sensors provide wide-area imagery with at or near real time detection speeds. Raman HSI sensors are being developed to overcome two obstacles present in standard Raman detection systems: slow area search rate (due to small laser spot sizes) and lack of eye-safety. SWIR HSI sensors have been integrated into mobile, robot based platforms and handheld variants for the detection of explosives and chemical warfare agents (CWAs). In addition, the fusion of these two technologies into a single system has shown the feasibility of using both techniques concurrently to provide higher probability of detection and lower false alarm rates. This paper will provide background on Raman and SWIR HSI, discuss the applications for these techniques, and provide an overview of novel CISS HSI sensors focusing on sensor design and detection results.

Standoff detection of explosives: a challenging approach for optical technologies

NASA Astrophysics Data System (ADS)

Désilets, S.; Hô, N.; Mathieu, P.; Simard, J. R.; Puckrin, E.; Thériault, J. M.; Lavoie, H.; Théberge, F.; Babin, F.; Gay, D.; Forest, R.; Maheux, J.; Roy, G.; Châteauneuf, M.

2011-06-01

Standoff detection of explosives residues on surfaces at few meters was made using optical technologies based on Raman scattering, Laser-Induced Breakdown Spectroscopy (LIBS) and passive standoff FTIR radiometry. By comparison, detection and analysis of nanogram samples of different explosives was made with a microscope system where Raman scattering from a micron-size single point illuminated crystal of explosive was observed. Results from standoff detection experiments using a telescope were compared to experiments using a microscope to find out important parameters leading to the detection. While detection and spectral identification of the micron-size explosive particles was possible with a microscope, standoff detection of these particles was very challenging due to undesired light reflected and produced by the background surface or light coming from other contaminants. Results illustrated the challenging approach of detecting at a standoff distance the presence of low amount of micron or submicron explosive particles.

Scientific Support for NQR Explosive Detection Development

DTIC Science & Technology

2006-07-01

Final 3. DATES COVERED (From - To) 8 March 2004 - 7 March 2006 4. TITLE AND SUBTITLE Scientific Support for NQR Explosive Detection Development...Laboratory (NRL) to improve explosive detection using nuclear quadrupole resonance ( NQR ) is summarized. The work includes studies of the effects...superconducting coils for explosive detection. Additional studies involving slowly rotating NQR measurements were also pursued. 15. SUBJECT TERMS Nuclear

Visual detection of trace nitroaromatic explosive residue using photoluminescent metallole-containing polymers.

PubMed

Toal, Sarah J; Sanchez, Jason C; Dugan, Regina E; Trogler, William C

2007-01-01

The detection of trace explosives is important for forensic, military, and homeland security applications. Detection of widely used nitroaromatic explosives (trinitrotoluene [TNT], 2,4-dinitrotoluene [DNT], picric acid [PA]) was carried out using photoluminescent metallole-containing polymers. The method of detection is through the quenching of fluorescence of thin films of the polymer, prepared by spray coating organic solutions of the polymer, by the explosive analyte. Visual quenching of luminescence (lambda(em) approximately 400-510 nm) in the presence of the explosive is seen immediately upon illumination with near-UV light (lambda(ex)=360 nm). Detection limits were observed to be as low as 5 ng for TNT, 20 ng for DNT, and 5 ng for PA. In addition, experiments with normal production line explosives and their components show that this technology is also able to detect composition B, Pyrodex, and nitromethane. This method offers a convenient and sensitive method of detection of trace nitroaromatic explosive residue.

49 CFR 1546.205 - Acceptance and screening of cargo.

Code of Federal Regulations, 2014 CFR

2014-10-01

... in its security program. Such methods may include TSA-approved x-ray systems, explosives detection systems, explosives trace detection, explosives detection canine teams certified by TSA, a physical search... of any explosive or incendiary. Each foreign air carrier operating a program under § 1546.101(a), (b...

49 CFR 1546.205 - Acceptance and screening of cargo.

Code of Federal Regulations, 2012 CFR

2012-10-01

... in its security program. Such methods may include TSA-approved x-ray systems, explosives detection systems, explosives trace detection, explosives detection canine teams certified by TSA, a physical search... of any explosive or incendiary. Each foreign air carrier operating a program under § 1546.101(a), (b...

49 CFR 1546.205 - Acceptance and screening of cargo.

Code of Federal Regulations, 2013 CFR

2013-10-01

... in its security program. Such methods may include TSA-approved x-ray systems, explosives detection systems, explosives trace detection, explosives detection canine teams certified by TSA, a physical search... of any explosive or incendiary. Each foreign air carrier operating a program under § 1546.101(a), (b...

49 CFR 1546.205 - Acceptance and screening of cargo.

Code of Federal Regulations, 2011 CFR

2011-10-01

... in its security program. Such methods may include TSA-approved x-ray systems, explosives detection systems, explosives trace detection, explosives detection canine teams certified by TSA, a physical search... of any explosive or incendiary. Each foreign air carrier operating a program under § 1546.101(a), (b...

75 FR 4578 - Extension of Agency Information Collection Activity Under OMB Review: National Explosives...

Federal Register 2010, 2011, 2012, 2013, 2014

2010-01-28

... Information Collection Activity Under OMB Review: National Explosives Detection Canine Team Program (NEDCTP... under the National Explosives Detection Canine Team Program. The data is collected electronically... feedback to the Chief of the National Explosives Detection Canine Team Program and instructional staff and...

Effectiveness of quality-control aids in verifying K-9-team explosive detection performance

NASA Astrophysics Data System (ADS)

Hallowell, Susan F.; Fischer, Douglas S.; Brasher, Jeffrey D.; Malone, Robert L.; Gresham, Garold L.; Rae, Cathy

1997-02-01

The Federal Aviation Administration (FAA) and supporting agencies conducted a developmental test and evaluation (DTE) to determine if quality control aids (QCAs) could be developed that would provide effective surrogates to actual explosives used for training and testing K-9 explosives detection teams. Non-detonable surrogates are required to alleviate logistics and contamination issues with explosives used sa training aids. Comparative K-9 team detection performance for explosives used as training aids and QCAs configurations of each explosive type were evaluated to determine the optimal configuration for the QCA configuration of each explosive type were evaluated to determine the optimal configuration for the QCAs. The configurations were a paper patch impregnated with a solution of the explosive, a cloth pouch filed with small amounts of solid explosive, and the non-hazardous explosive for security training and testing material. The DTE was conducted at Lackland Air Force Base in San Antonio, Texas, where the K-9 teams undergo initial training. Six FAA certified operational teams participated. All explosives and QCAs were presented to the K-9 teams using a 10 scent box protocol. The results show that K-9 team as are more sensitive to explosives than the candidate QCAs. More importantly, it was discovered that the explosives at Lackland AFB are cross-contaminated, meaning that explosives possessed volatile artifacts from other explosives. There are two potential hypotheses explaining why the dogs did not detect the QCAs. First, the cross-contamination of Lackland training explosives may mean that K-9 teams are only trained to detect the explosives with the most volatile chemical signatures. Alternatively, the QCA configurations may have been below the trained detection threshold of the K-9s. It is recommended that K-9 teams train on uncontaminated odors from properly designed QCAs to ensure that dogs respond to the appropriate explosive components, and not some other constituent or contaminant.

Explosives tester

DOEpatents

Haas, Jeffrey S [San Ramon, CA; Howard, Douglas E [Livermore, CA; Eckels, Joel D [Livermore, CA; Nunes, Peter J [Danville, CA

2011-01-11

An explosives tester that can be used anywhere as a screening tool by non-technical personnel to determine whether a surface contains explosives. First and second explosives detecting reagent holders and dispensers are provided. A heater is provided for receiving the first and second explosives detecting reagent holders and dispensers.

MixDroid: A multi-features and multi-classifiers bagging system for Android malware detection

NASA Astrophysics Data System (ADS)

Huang, Weiqing; Hou, Erhang; Zheng, Liang; Feng, Weimiao

2018-05-01

In the past decade, Android platform has rapidly taken over the mobile market for its superior convenience and open source characteristics. However, with the popularity of Android, malwares targeting on Android devices are increasing rapidly, while the conventional rule-based and expert-experienced approaches are no longer able to handle such explosive growth. In this paper, combining with the theory of natural language processing and machine learning, we not only implement the basic feature extraction of permission application features, but also propose two innovative schemes of feature extraction: Dalvik opcode features and malicious code image, and implement an automatic Android malware detection system MixDroid which is based on multi-features and multi-classifiers. According to our experiment results on 20,000 Android applications, detection accuracy of MixDroid is 98.1%, which proves our schemes' effectiveness in Android malware detection.

Determining the effects of routine fingermark detection techniques on the subsequent recovery and analysis of explosive residues on various substrates.

PubMed

King, Sam; Benson, Sarah; Kelly, Tamsin; Lennard, Chris

2013-12-10

An offender who has recently handled bulk explosives would be expected to deposit latent fingermarks that are contaminated with explosive residues. However, fingermark detection techniques need to be applied in order for these fingermarks to be detected and recorded. Little information is available in terms of how routine fingermark detection methods impact on the subsequent recovery and analysis of any explosive residues that may be present. If an identifiable fingermark is obtained and that fingermark is found to be contaminated with a particular explosive then that may be crucial evidence in a criminal investigation (including acts of terrorism involving improvised explosive devices). The principal aims of this project were to investigate: (i) the typical quantities of explosive material deposited in fingermarks by someone who has recently handled bulk explosives; and (ii) the effects of routine fingermark detection methods on the subsequent recovery and analysis of explosive residues in such fingermarks. Four common substrates were studied: paper, glass, plastic (polyethylene plastic bags), and metal (aluminium foil). The target explosive compounds were 2,4,6-trinitrotoluene (TNT), pentaerythritol tetranitrate (PETN), and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), as well as chlorate and nitrate ions. Recommendations are provided in terms of the application of fingermark detection methods on surfaces that may contain explosive residues. Copyright © 2013 Elsevier Ireland Ltd. All rights reserved.

Standoff laser-based spectroscopy for explosives detection

NASA Astrophysics Data System (ADS)

Gaft, M.; Nagli, L.

2007-10-01

Real time detection and identification of explosives at a standoff distance is a major issue in efforts to develop defense against so-called Improvised Explosive Devices (IED). It is recognized that the only technique, which is potentially capable to standoff detection of minimal amounts of explosives is laser-based spectroscopy. LDS activity is based on a combination of laser-based spectroscopic methods with orthogonal capabilities. Our technique belongs to trace detection, namely to its micro-particles variety. It is based on commonly held belief that surface contamination was very difficult to avoid and could be exploited for standoff detection. We has applied optical techniques including gated Raman and time-resolved luminescence spectroscopy for detection of main explosive materials, both factory and homemade. We developed and tested a Raman system for the field remote detection and identification of minimal amounts of explosives on relevant surfaces at a distance of up to 30 meters.

[Aging explosive detection using terahertz time-domain spectroscopy].

PubMed

Meng, Kun; Li, Ze-ren; Liu, Qiao

2011-05-01

Detecting the aging situation of stock explosive is essentially meaningful to the research on the capability, security and stability of explosive. Existing aging explosive detection techniques, such as scan microscope technique, Fourier transfer infrared spectrum technique, gas chromatogram mass spectrum technique and so on, are either not able to differentiate whether the explosive is aging or not, or not able to image the structure change of the molecule. In the present paper, using the density functional theory (DFT), the absorb spectrum changes after the explosive aging were calculated, from which we can clearly find the difference of spectrum between explosive molecule and aging ones in the terahertz band. The terahertz time-domain spectrum (THz-TDS) system as well as its frequency spectrum resolution and measured range are analyzed. Combined with the existing experimental results and the essential characters of the terahertz wave, the application of THz-TDS technique to the detection of aging explosive was demonstrated from the aspects of feasibility, veracity and practicability. On the base of that, the authors advance the new method of aging explosive detection using the terahertz time-domain spectrum technique.

Monte Carlo simulation of explosive detection system based on a Deuterium-Deuterium (D-D) neutron generator.

PubMed

Bergaoui, K; Reguigui, N; Gary, C K; Brown, C; Cremer, J T; Vainionpaa, J H; Piestrup, M A

2014-12-01

An explosive detection system based on a Deuterium-Deuterium (D-D) neutron generator has been simulated using the Monte Carlo N-Particle Transport Code (MCNP5). Nuclear-based explosive detection methods can detect explosives by identifying their elemental components, especially nitrogen. Thermal neutron capture reactions have been used for detecting prompt gamma emission (10.82MeV) following radiative neutron capture by (14)N nuclei. The explosive detection system was built based on a fully high-voltage-shielded, axial D-D neutron generator with a radio frequency (RF) driven ion source and nominal yield of about 10(10) fast neutrons per second (E=2.5MeV). Polyethylene and paraffin were used as moderators with borated polyethylene and lead as neutron and gamma ray shielding, respectively. The shape and the thickness of the moderators and shields are optimized to produce the highest thermal neutron flux at the position of the explosive and the minimum total dose at the outer surfaces of the explosive detection system walls. In addition, simulation of the response functions of NaI, BGO, and LaBr3-based γ-ray detectors to different explosives is described. Copyright © 2014 Elsevier Ltd. All rights reserved.

Development of a handheld widefield hyperspectral imaging (HSI) sensor for standoff detection of explosive, chemical, and narcotic residues

NASA Astrophysics Data System (ADS)

Nelson, Matthew P.; Basta, Andrew; Patil, Raju; Klueva, Oksana; Treado, Patrick J.

2013-05-01

The utility of Hyper Spectral Imaging (HSI) passive chemical detection employing wide field, standoff imaging continues to be advanced in detection applications. With a drive for reduced SWaP (Size, Weight, and Power), increased speed of detection and sensitivity, developing a handheld platform that is robust and user-friendly increases the detection capabilities of the end user. In addition, easy to use handheld detectors could improve the effectiveness of locating and identifying threats while reducing risks to the individual. ChemImage Sensor Systems (CISS) has developed the HSI Aperio™ sensor for real time, wide area surveillance and standoff detection of explosives, chemical threats, and narcotics for use in both government and commercial contexts. Employing liquid crystal tunable filter technology, the HSI system has an intuitive user interface that produces automated detections and real-time display of threats with an end user created library of threat signatures that is easily updated allowing for new hazardous materials. Unlike existing detection technologies that often require close proximity for sensing and so endanger operators and costly equipment, the handheld sensor allows the individual operator to detect threats from a safe distance. Uses of the sensor include locating production facilities of illegal drugs or IEDs by identification of materials on surfaces such as walls, floors, doors, deposits on production tools and residue on individuals. In addition, the sensor can be used for longer-range standoff applications such as hasty checkpoint or vehicle inspection of residue materials on surfaces or bulk material identification. The CISS Aperio™ sensor has faster data collection, faster image processing, and increased detection capability compared to previous sensors.

27 CFR 555.184 - Statements of process and samples.

Code of Federal Regulations, 2011 CFR

2011-04-01

... regard to any plastic explosive or to any detection agent that is to be introduced into a plastic... importer, upon request, to the Director. (b) Samples of any plastic explosive or detection agent shall be..., FIREARMS, AND EXPLOSIVES, DEPARTMENT OF JUSTICE EXPLOSIVES COMMERCE IN EXPLOSIVES Marking of Plastic...

27 CFR 555.184 - Statements of process and samples.

Code of Federal Regulations, 2012 CFR

2012-04-01

... regard to any plastic explosive or to any detection agent that is to be introduced into a plastic... importer, upon request, to the Director. (b) Samples of any plastic explosive or detection agent shall be..., FIREARMS, AND EXPLOSIVES, DEPARTMENT OF JUSTICE EXPLOSIVES COMMERCE IN EXPLOSIVES Marking of Plastic...

27 CFR 555.184 - Statements of process and samples.

Code of Federal Regulations, 2013 CFR

2013-04-01

... regard to any plastic explosive or to any detection agent that is to be introduced into a plastic... importer, upon request, to the Director. (b) Samples of any plastic explosive or detection agent shall be..., FIREARMS, AND EXPLOSIVES, DEPARTMENT OF JUSTICE EXPLOSIVES COMMERCE IN EXPLOSIVES Marking of Plastic...

27 CFR 555.184 - Statements of process and samples.

Code of Federal Regulations, 2014 CFR

2014-04-01

... regard to any plastic explosive or to any detection agent that is to be introduced into a plastic... importer, upon request, to the Director. (b) Samples of any plastic explosive or detection agent shall be..., FIREARMS, AND EXPLOSIVES, DEPARTMENT OF JUSTICE EXPLOSIVES COMMERCE IN EXPLOSIVES Marking of Plastic...

27 CFR 555.184 - Statements of process and samples.

Code of Federal Regulations, 2010 CFR

2010-04-01

... regard to any plastic explosive or to any detection agent that is to be introduced into a plastic... importer, upon request, to the Director. (b) Samples of any plastic explosive or detection agent shall be..., FIREARMS, AND EXPLOSIVES, DEPARTMENT OF JUSTICE EXPLOSIVES COMMERCE IN EXPLOSIVES Marking of Plastic...

Apparatus and method for rapid detection of explosives residue from the deflagration signature thereof

DOEpatents

Funsten, Herbert O.; McComas, David J.

1997-01-01

Apparatus and method for rapid detection of explosives residue from the deflagration signature thereof. A property inherent to most explosives is their stickiness, resulting in a strong tendency of explosive particulate to contaminate the environment of a bulk explosive. An apparatus for collection of residue particulate, burning the collected particulate, and measurement of the optical emission produced thereby is described. The present invention can be utilized for real-time screening of personnel, cars, packages, suspected devices, etc., and provides an inexpensive, portable, and noninvasive means for detecting explosives.

Apparatus and method for rapid detection of explosives residue from the deflagration signature thereof

DOEpatents

Funsten, Herbert O.; McComas, David J.

1999-01-01

Apparatus and method for rapid detection of explosives residue from the deflagration signature thereof. A property inherent to most explosives is their stickiness, resulting in a strong tendency of explosive particulate to contaminate the environment of a bulk explosive. An apparatus for collection of residue particulate, burning the collected particulate, and measurement of the ultraviolet emission produced thereby, is described. The present invention can be utilized for real-time screening of personnel, cars, packages, suspected devices, etc., and provides an inexpensive, portable, and noninvasive means for detecting explosives.

Advances in Analysis and Detection of Explosives. Proceedings of the International Symposium on Analysis and Detection of Explosives (4th), Held in Jerusalem, Israel on September 7-10, 1992

DTIC Science & Technology

1992-09-01

by Supercritical Fluid Extraction in Explosives; The Semtex-H Story; The Identification of Organic Peroxides; Slurry and Emulsion...Among the topics presented at this symposium were: Birmingham Six Pub Bombing Case (Keynote Lecture); A Scheme for the Analysis of Explosives and...Explosives: New Tools for Terrorists, New Challenges, for Detection and Identification; The Work of the Explosives and Gunshot Residues Unit of the Forensic Science Service (UK)

Feasibility of culvert IED detection using thermal neutron activation

NASA Astrophysics Data System (ADS)

Faust, Anthony A.; McFee, John E.; Clifford, Edward T. H.; Andrews, Hugh Robert; Mosquera, Cristian; Roberts, William C.

2012-06-01

Bulk explosives hidden in culverts pose a serious threat to the Canadian and allied armies. Culverts provide an opportunity to conceal insurgent activity, avoid the need for detectable surface disturbances, and limit the applicability of conventional sub-surface sensing techniques. Further, in spite of the large masses of explosives that can be employed, the large sensor{target separation makes detection of the bulk explosive content challeng- ing. Defence R&D Canada { Sueld and Bubble Technology Industries have been developing thermal neutron activation (TNA) sensors for detection of buried bulk explosives for over 15 years. The next generation TNA sensor, known as TNA2, incorporates a number of improvements that allow for increased sensor-to-target dis- tances, making it potentially feasible to detect large improvised explosive devices (IEDs) in culverts using TNA. Experiments to determine the ability of TNA2 to detect improvised explosive devices in culverts are described, and the resulting signal levels observed for relevant quantities of explosives are presented. Observations conrm that bulk explosives detection using TNA against a culvert-IED is possible, with large charges posing a detection challenge at least as dicult as that of a deeply buried anti-tank landmine. Because of the prototype nature of the TNA sensor used, it is not yet possible to make denitive statements about the absolute sensitivity or detection time. Further investigation is warranted.

Inspection tester for explosives

DOEpatents

Haas, Jeffrey S.; Simpson, Randall L.; Satcher, Joe H.

2007-11-13

An inspection tester that can be used anywhere as a primary screening tool by non-technical personnel to determine whether a surface contains explosives. It includes a body with a sample pad. First and second explosives detecting reagent holders and dispensers are operatively connected to the body and the sample pad. The first and second explosives detecting reagent holders and dispensers are positioned to deliver the explosives detecting reagents to the sample pad. A is heater operatively connected to the sample pad.

Inspection tester for explosives

DOEpatents

Haas, Jeffrey S.; Simpson, Randall L.; Satcher, Joe H.

2010-10-05

An inspection tester that can be used anywhere as a primary screening tool by non-technical personnel to determine whether a surface contains explosives. It includes a body with a sample pad. First and second explosives detecting reagent holders and dispensers are operatively connected to the body and the sample pad. The first and second explosives detecting reagent holders and dispensers are positioned to deliver the explosives detecting reagents to the sample pad. A is heater operatively connected to the sample pad.

A platform for exploding wires in different media

NASA Astrophysics Data System (ADS)

Han, Ruoyu; Wu, Jiawei; Qiu, Aici; Zhou, Haibin; Wang, Yanan; Yan, Jiaqi; Ding, Weidong

2017-10-01

A platform SWE-2 used for single wire explosion experiments has been designed, established, and commissioned. This paper describes the design and initial experiments of SWE-2. In summary, two pulsed current sources based on pulse capacitors and spark gaps are adopted to drive sub-microsecond and microsecond time scale wire explosions in a gaseous/liquid medium, respectively. In the initial experiments, a single copper wire was exploded in air, helium, and argon with a 0.1-0.3 MPa ambient pressure as well as tap water with a 283-323 K temperature, 184-11 000 μ S/cm conductivity, or 0.1-0.9 MPa hydrostatic pressure. In addition, the diagnostic system is introduced in detail. Energy deposition, optical emission, and shock wave characteristics are briefly discussed based on experimental results. The platform was demonstrated to operate successfully with a single wire load. These results provide the potential for further applications of this platform, such as plasma-matter interactions, shock wave effects, and reservoir simulations.

Manipulation of Molecular Quantum Wavepackets with Ultrashort Laser Pulses for Non-destructive Detection of Volatile Explosives

DTIC Science & Technology

2013-02-01

DTRA-TR-12-65 Manipulation of Molecular Quantum Wavepackets with Ultrashort Laser Pulses for Non-destructive Detection of Volatile Explosives ...Manipulation of Molecular Quantum Wavepackets with Ultrashort Laser Pulses for Non-destructive Detection of Volatile Explosives HDTRA1-09-1-0021 Valery...destructive detection of volatile explosives . Moshe Shapiro1, Valery Milner1 and Jun Ye2 1University of British Columbia, Vancouver, Canada 2JILA

Direct real-time detection of vapors from explosive compounds.

PubMed

Ewing, Robert G; Clowers, Brian H; Atkinson, David A

2013-11-19

The real-time detection of vapors from low volatility explosives including PETN, tetryl, RDX, and nitroglycerine along with various compositions containing these substances was demonstrated. This was accomplished with an atmospheric flow tube (AFT) using a nonradioactive ionization source coupled to a mass spectrometer. Direct vapor detection was accomplished in less than 5 s at ambient temperature without sample preconcentration. The several seconds of residence time of analytes in the AFT provided a significant opportunity for reactant ions to interact with analyte vapors to achieve ionization. This extended reaction time, combined with the selective ionization using the nitrate reactant ions (NO3(-) and NO3(-)·HNO3), enabled highly sensitive explosives detection from explosive vapors present in ambient laboratory air. Observed signals from diluted explosive vapors indicated detection limits below 10 ppqv using selected ion monitoring (SIM) of the explosive-nitrate adduct at m/z 349, 378, 284, and 289 for tetryl, PETN, RDX, and NG, respectively. Also provided is a demonstration of the vapor detection from 10 different energetic formulations sampled in ambient laboratory air, including double base propellants, plastic explosives, and commercial blasting explosives using SIM for the NG, PETN, and RDX product ions.

Apparatus and method for rapid detection of explosives residue from the deflagration signature thereof

DOEpatents

Funsten, H.O.; McComas, D.J.

1999-06-15

Apparatus and method are disclosed for rapid detection of explosives residue from the deflagration signature thereof. A property inherent to most explosives is their stickiness, resulting in a strong tendency of explosive particulate to contaminate the environment of a bulk explosive. An apparatus for collection of residue particulate, burning the collected particulate, and measurement of the ultraviolet emission produced thereby, is described. The present invention can be utilized for real-time screening of personnel, cars, packages, suspected devices, etc., and provides an inexpensive, portable, and noninvasive means for detecting explosives. 4 figs.

Advancing Explosives Detection Capabilities: Vapor Detection

ScienceCinema

Atkinson, David

2018-05-11

A new, PNNL-developed method provides direct, real-time detection of trace amounts of explosives such as RDX, PETN and C-4. The method selectively ionizes a sample before passing the sample through a mass spectrometer to detect explosive vapors. The method could be used at airports to improve aviation security.

Advancing Explosives Detection Capabilities: Vapor Detection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Atkinson, David

2012-10-15

A new, PNNL-developed method provides direct, real-time detection of trace amounts of explosives such as RDX, PETN and C-4. The method selectively ionizes a sample before passing the sample through a mass spectrometer to detect explosive vapors. The method could be used at airports to improve aviation security.

Selective detection of trace nitroaromatic, nitramine, and nitrate ester explosive residues using a three-step fluorimetric sensing process: a tandem turn-off, turn-on sensor.

PubMed

Sanchez, Jason C; Toal, Sarah J; Wang, Zheng; Dugan, Regina E; Trogler, William C

2007-11-01

Detection of trace quantities of explosive residues plays a key role in military, civilian, and counter-terrorism applications. To advance explosives sensor technology, current methods will need to become cheaper and portable while maintaining sensitivity and selectivity. The detection of common explosives including trinitrotoluene (TNT), cyclotrimethylenetrinitramine, cyclotetramethylene-tetranitramine, pentaerythritol tetranitrate, 2,4,6-trinitrophenyl-N-methylnitramine, and trinitroglycerin may be carried out using a three-step process combining "turn-off" and "turn-on" fluorimetric sensing. This process first detects nitroaromatic explosives by their quenching of green luminescence of polymetalloles (lambda em approximately 400-510 nm). The second step places down a thin film of 2,3-diaminonaphthalene (DAN) while "erasing" the polymetallole luminescence. The final step completes the reaction of the nitramines and/or nitrate esters with DAN resulting in the formation of a blue luminescent traizole complex (lambda(em) = 450 nm) providing a "turn-on" response for nitramine and nitrate ester-based explosives. Detection limits as low as 2 ng are observed. Solid-state detection of production line explosives demonstrates the applicability of this method to real world situations. This method offers a sensitive and selective detection process for a diverse group of the most common high explosives used in military and terrorist applications today.

A review on several key problems of standoff trace explosives detection by optical-related technology

NASA Astrophysics Data System (ADS)

Chen, Zhibin; Xiao, Cheng; Xiao, Wenjian; Qin, Mengze; Liu, Xianhong

2016-01-01

To prevent tragic disasters caused by terror acts and warfare threats, security check personnel must be capable of discovering, distinguishing and eliminating the explosives at multiple circumstances. Standoff technology for the remote detection of explosives and their traces on contaminated surfaces is a research field that has become a heightened priority in recent years for homeland security and counter-terrorism applications. There has been a huge increase in research within this area, the improvement of standoff trace explosives detection by optical-related technology. This paper provides a consolidation of information relating to recent advances in several key problems of, without being limited to one specific research area or explosive type. Working laser wavelength of detection system is discussed. Generation and collection of explosives spectra signal are summarized. Techniques for analysing explosives spectra signal are summed up.

Association of sea turtles with petroleum platforms in the north-central Gulf of Mexico

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lohoefener, R.; Hoggard, W.; Mullin, K.

1990-06-01

There are over 4,500 petroleum platforms in the north-central Gulf of Mexico. Explosives are commonly used to remove platforms and have the potential to kill nearby sea turtles. From June 1988-June 1990, the authors used aerial surveys to study turtle density and the spatial relationship between turtles and platforms offshore of Louisiana. They sighted 316 turtles most of which (92%) were loggerheads. Seventy-eight percent were sighted just east of the Mississippi River offshore of the Chandeleur Islands. East of the river, turtle densities ranged from 0.92 (winter) to 4.83 turtles/100 sq km (spring). West of the river, annual densities rangedmore » from 0.11-0.50 turtles/100 sq km. East of the river, three statistical tests indicated that turtles were generally closer to platforms than expected by chance alone. West of the river, turtles were randomly located with respect to platform locations. Before explosives are used, current mitigation measures require that no turtle can be sighted within 1,000 m of the platform. East of the river, the probability of a turtle being within 1,000 m of any platform selected at random was about 60%; west of the river, 2-7%. West of the river to about 92 W, the mitigation measures should protect turtles but offshore of the Chandeleur Islands, special precautions should be taken.« less

Detection and mapping of trace explosives on surfaces under ambient conditions using multiphoton electron extraction spectroscopy (MEES).

PubMed

Tang, Shisong; Vinerot, Nataly; Fisher, Danny; Bulatov, Valery; Yavetz-Chen, Yehuda; Schechter, Israel

2016-08-01

Multiphoton electron extraction spectroscopy (MEES) is an analytical method in which UV laser pulses are utilized for extracting electrons from solid surfaces in multiphoton processes under ambient conditions. Counting the emitted electrons as a function of laser wavelength results in detailed spectral features, which can be used for material identification. The method has been applied to detection of trace explosives on a variety of surfaces. Detection was possible on dusty swabs spiked with explosives and also in the standard dry-transfer contamination procedure. Plastic explosives could also be detected. The analytical limits of detection (LODs) are in the sub pmole range, which indicates that MEES is one of the most sensitive detection methods for solid surface under ambient conditions. Scanning the surface with the laser allows for its imaging, such that explosives (as well as other materials) can be located. The imaging mode is also useful in forensic applications, such as detection of explosives in human fingerprints. Copyright © 2016 Elsevier B.V. All rights reserved.

78 FR 18619 - Extension of Agency Information Collection Activity Under OMB Review: National Explosives...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-27

... DEPARTMENT OF HOMELAND SECURITY Transportation Security Administration Extension of Agency Information Collection Activity Under OMB Review: National Explosives Detection Canine Team Program (NEDCTP... Explosives Detection Canine Team Program (NEDCTP) canine handlers. Abstract: The FAMS/CTES Explosives...

LACED

Science.gov Websites

Search Site submit Feynman Center for Innovation Los Alamos National Laboratory Collaboration for Explosives Detection Los Alamos National Laboratory Los Alamos Collaboration for Explosives Detection Menu is built upon Los Alamos' unparalleled explosive detection capabilities derived from the expertise of

Semi-automated detection of trace explosives in fingerprints on strongly interfering surfaces with Raman chemical imaging.

PubMed

Tripathi, Ashish; Emmons, Erik D; Wilcox, Phillip G; Guicheteau, Jason A; Emge, Darren K; Christesen, Steven D; Fountain, Augustus W

2011-06-01

We have previously demonstrated the use of wide-field Raman chemical imaging (RCI) to detect and identify the presence of trace explosives in contaminated fingerprints. In this current work we demonstrate the detection of trace explosives in contaminated fingerprints on strongly Raman scattering surfaces such as plastics and painted metals using an automated background subtraction routine. We demonstrate the use of partial least squares subtraction to minimize the interfering surface spectral signatures, allowing the detection and identification of explosive materials in the corrected Raman images. The resulting analyses are then visually superimposed on the corresponding bright field images to physically locate traces of explosives. Additionally, we attempt to address the question of whether a complete RCI of a fingerprint is required for trace explosive detection or whether a simple non-imaging Raman spectrum is sufficient. This investigation further demonstrates the ability to nondestructively identify explosives on fingerprints present on commonly found surfaces such that the fingerprint remains intact for further biometric analysis.

Multi-Phenomenology Explosion Monitoring (Multi-PEM). Signal Detection. Research to target smaller sources for tomorrow’s missions

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carmichael, Joshua Daniel

2015-12-12

This a guide on how to detect and identify explosions from various sources. For example, nuclear explosions produce acoustic, optical, and EMP outputs. Each signal can be buried in noise, but fusing detection statistics from seismic, acoustic, and electromagnetic signals results in clear detection otherwise unobtainable.

Detection and dispersal of explosives by ants

NASA Astrophysics Data System (ADS)

McFee, John E.; Achal, Steve; Faust, Anthony A.; Puckrin, Eldon; House, Andrew; Reynolds, Damon; McDougall, William; Asquini, Adam

2009-05-01

The ability of animals to detect explosives is well documented. Mammalian systems, insects and even single celled organisms have all been studied and in a few cases employed to detect explosives. This paper will describe the potential ability of ants to detect, disperse and possibly neutralize bulk explosives. In spring 2008 a team of DRDC and Itres scientists conducted experiments on detecting surface-laid and buried landmines, improvised explosive devices (IEDs) and their components. Measurements were made using state-of-the-art short wave and thermal infrared hyperspectral imagers mounted on a personnel lift. During one of the early morning measurement sessions, a wispy, long linear trail was seen to emanate several meters from piles of explosives that were situated on the ground. Upon close visual inspection, it was observed that ants had found the piles of explosives and were carrying it to their ant hill, a distance of almost 20 meters from the piles. Initial analysis of the hyperspectral images clearly revealed the trail to the ant hill of explosives, despite being present in quantities not visible to the unaided eye. This paper details these observations and discusses them in the context of landmine and IED detection and neutralization. Possible reasons for such behaviour are presented. A number of questions regarding the behaviour, many pertinent to the use of ants in a counter-landmine/IED role, are presented and possible methods of answering them are discussed. Anecdotal evidence from deminers of detection and destruction of explosives by ants are presented.

Portable life support for instrumentation of an offshore platform

NASA Technical Reports Server (NTRS)

Mull, M. M.; Coffin, C. L.

1972-01-01

A compressor was used to supply air through a nylon hose to the offshore platform field engineer working at the bottom of the piling. Air quality in the pile was sampled periodically for carbon dioxide, carbon monoxide, hydrogen sulfide, and combustible gases by an universal tester and an explosion meter.

Novel CE-MS technique for detection of high explosives using perfluorooctanoic acid as a MEKC and mass spectrometric complexation reagent.

PubMed

Brensinger, Karen; Rollman, Christopher; Copper, Christine; Genzman, Ashton; Rine, Jacqueline; Lurie, Ira; Moini, Mehdi

2016-01-01

To address the need for the forensic analysis of high explosives, a novel capillary electrophoresis mass spectrometry (CE-MS) technique has been developed for high resolution, sensitivity, and mass accuracy detection of these compounds. The technique uses perfluorooctanoic acid (PFOA) as both a micellar electrokinetic chromatography (MEKC) reagent for separation of neutral explosives and as the complexation reagent for mass spectrometric detection of PFOA-explosive complexes in the negative ion mode. High explosives that formed complexes with PFOA included RDX, HMX, tetryl, and PETN. Some nitroaromatics were detected as molecular ions. Detection limits in the high parts per billion range and linear calibration responses over two orders of magnitude were obtained. For proof of concept, the technique was applied to the quantitative analysis of high explosives in sand samples. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

Fluorescence based explosive detection: from mechanisms to sensory materials.

PubMed

Sun, Xiangcheng; Wang, Ying; Lei, Yu

2015-11-21

The detection of explosives is one of the current pressing concerns in global security. In the past few decades, a large number of emissive sensing materials have been developed for the detection of explosives in vapor, solution, and solid states through fluorescence methods. In recent years, great efforts have been devoted to develop new fluorescent materials with various sensing mechanisms for detecting explosives in order to achieve super-sensitivity, ultra-selectivity, as well as fast response time. This review article starts with a brief introduction on various sensing mechanisms for fluorescence based explosive detection, and then summarizes in an exhaustive and systematic way the state-of-the-art of fluorescent materials for explosive detection with a focus on the research in the recent 5 years. A wide range of fluorescent materials, such as conjugated polymers, small fluorophores, supramolecular systems, bio-inspired materials and aggregation induced emission-active materials, and their sensing performance and sensing mechanism are the centerpiece of this review. Finally, conclusions and future outlook are presented and discussed.

Proboscis extension reflex platform for volatiles and semi-volatiles detection

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wingo, Robert M.; McCabe, Kirsten J.; Haarmann, Timothy K.

The present invention provides an apparatus for the detection of volatile and semi-volatile chemicals using the olfactory abilities of honey bees that are trained to respond to the presence of a specific chemical in a sample of gas with the proboscis extension reflex (PER). In particular, the geometry and arrangement of the parts of the apparatus are such that the amount of surface area in contact with the sample of gas prior to its introduction to the bees is minimized to improve the detection of particular volatile and semi-volatile that have a tendency to "stick" to contacting surfaces, especially certainmore » chemicals associated with explosives and narcotics. According to another aspect of the present invention, a pre-concentrating means is incorporated with the device to effectively increase the concentration of "sticky" chemicals presented to the insects.« less

Universal explosive detection system for homeland security applications

NASA Astrophysics Data System (ADS)

Lee, Vincent Y.; Bromberg, Edward E. A.

2010-04-01

L-3 Communications CyTerra Corporation has developed a high throughput universal explosive detection system (PassPort) to automatically screen the passengers in airports without requiring them to remove their shoes. The technical approach is based on the patented energetic material detection (EMD) technology. By analyzing the results of sample heating with an infrared camera, one can distinguish the deflagration or decomposition of an energetic material from other clutters such as flammables and general background substances. This becomes the basis of a universal explosive detection system that does not require a library and is capable of detecting trace levels of explosives with a low false alarm rate. The PassPort is a simple turnstile type device and integrates a non-intrusive aerodynamic sampling scheme that has been shown capable of detecting trace levels of explosives on shoes. A detailed description of the detection theory and the automated sampling techniques, as well as the field test results, will be presented.

Stand-off laser Raman spectroscopy and its advancement in explosives detection

NASA Astrophysics Data System (ADS)

Liu, Sheng-run; Xue, Bin; Li, Yi-zhe; Wang, Hui

2017-10-01

The explosives detection has been a hot and difficult issue in the field of security it is particularly important to detect explosives quickly and reliably. There are many methods to detect explosives currently, stand-off Raman spectroscopy is one of the most promising and practical technologies, this technique can be used for non-contact and nondestructive detection, ensure the safety of attendants, at the same time the precision and speed of detection are also very high and be characterized by rapid response. This paper mainly gives an account of the fundamental principle of Raman spectroscopy, as well as recount major challenges of Standoff Laser Raman Spectroscopy applied in explosives detection and corresponding solutions. From the perspective of the system, this paper sums up related theories and techniques of the excitation laser and telescopic system etc.. Ultimately, a brief analysis and summary of the development trend of this technology is given.

Detection of Nuclear Explosions Using Infrasound Techniques

DTIC Science & Technology

2007-12-01

signal correlation between array elements in these arrays can seriously limit the reliable detection of infrasound generated ...goals of this investigation are to identify problems with the detection of explosion- generated infrasonic signals at stations in the global infrasound ...restricted to a thermospheric waveguide. The second part is focused on the limitations imposed on array detection of explosion- generated infrasound

Raman detection of improvised explosive device (IED) material fabricated using drop-on-demand inkjet technology on several real world surfaces

NASA Astrophysics Data System (ADS)

Farrell, Mikella E.; Holthoff, Ellen L.; Pellegrino, Paul M.

2015-05-01

The requirement to detect hazardous materials (i.e., chemical, biological, and explosive) on a host of materials has led to the development of hazard detection systems. These new technologies and their capabilities could have immediate uses for the US military, national security agencies, and environmental response teams in efforts to keep people secure and safe. In particular, due to the increasing use by terrorists, the detection of common explosives and improvised explosive device (IED) materials have motivated research efforts toward detecting trace (i.e., particle level) quantities on multiple commonly encountered surfaces (e.g., textiles, metals, plastics, natural products, and even people). Non-destructive detection techniques can detect trace quantities of explosive materials; however, it can be challenging in the presence of a complex chemical background. One spectroscopic technique gaining increased attention for detection is Raman. One popular explosive precursor material is ammonium nitrate (AN). The material AN has many agricultural applications, however it can also be used in the fabrication of IEDs or homemade explosives (HMEs). In this paper, known amounts of AN will be deposited using an inkjet printer into several different common material surfaces (e.g., wood, human hair, textiles, metals, plastics). The materials are characterized with microscope images and by collecting Raman spectral data. In this report the detection and identification of AN will be demonstrated.

Detection of explosives in soils

DOEpatents

Chambers, William B.; Rodacy, Philip J.; Phelan, James M.; Woodfin, Ronald L.

2002-01-01

An apparatus and method for detecting explosive-indicating compounds in subsurface soil. The apparatus has a probe with an adsorbent material on some portion of its surface that can be placed into soil beneath the ground surface, where the adsorbent material can adsorb at least one explosive-indicating compound. The apparatus additional has the capability to desorb the explosive-indicating compound through heating or solvent extraction. A diagnostic instrument attached to the probe detects the desorbed explosive-indicating compound. In the method for detecting explosive-indicating compounds in soil, the sampling probe with an adsorbent material on at least some portion of a surface of the sampling probe is inserted into the soil to contact the adsorbent material with the soil. The explosive-indicating compounds are then desorbed and transferred as either a liquid or gas sample to a diagnostic tool for analysis. The resulting gas or liquid sample is analyzed using at least one diagnostic tool selected from the group consisting of an ion-mobility spectrometer, a gas chromatograph, a high performance liquid chromatograph, a capillary electrophoresis chromatograph, a mass spectrometer, a Fourier-transform infrared spectrometer and a Raman spectrometer to detect the presence of explosive-indicating compounds.

Direct Real-Time Detection of Vapors from Explosive Compounds

DOE Office of Scientific and Technical Information (OSTI.GOV)

Ewing, Robert G.; Clowers, Brian H.; Atkinson, David A.

2013-10-03

The real-time detection of vapors from low volatility explosives including PETN, tetryl, RDX and nitroglycerine along with various compositions containing these substances is demonstrated. This was accomplished with an atmospheric flow tube (AFT) using a non-radioactive ionization source and coupled to a mass spectrometer. Direct vapor detection was demonstrated in less than 5 seconds at ambient temperature without sample pre-concentration. The several seconds of residence time of analytes in the AFT provides a significant opportunity for reactant ions to interact with analyte vapors to achieve ionization. This extended reaction time, combined with the selective ionization using the nitrate reactant ionsmore » (NO3- and NO3-•HNO3), enables highly sensitive explosives detection. Observed signals from diluted explosive vapors indicate detection limits below 10 ppqv using selected ion monitoring (SIM) of the explosive-nitrate adduct at m/z 349, 378, 284 and 289 for tetryl, PETN, RDX and NG respectively. Also provided is a demonstration of the vapor detection from 10 different energetic formulations, including double base propellants, plastic explosives and commercial blasting explosives using SIM for the NG, PETN and RDX product ions.« less

Automation in airport security X-ray screening of cabin baggage: Examining benefits and possible implementations of automated explosives detection.

PubMed

Hättenschwiler, Nicole; Sterchi, Yanik; Mendes, Marcia; Schwaninger, Adrian

2018-10-01

Bomb attacks on civil aviation make detecting improvised explosive devices and explosive material in passenger baggage a major concern. In the last few years, explosive detection systems for cabin baggage screening (EDSCB) have become available. Although used by a number of airports, most countries have not yet implemented these systems on a wide scale. We investigated the benefits of EDSCB with two different levels of automation currently being discussed by regulators and airport operators: automation as a diagnostic aid with an on-screen alarm resolution by the airport security officer (screener) or EDSCB with an automated decision by the machine. The two experiments reported here tested and compared both scenarios and a condition without automation as baseline. Participants were screeners at two international airports who differed in both years of work experience and familiarity with automation aids. Results showed that experienced screeners were good at detecting improvised explosive devices even without EDSCB. EDSCB increased only their detection of bare explosives. In contrast, screeners with less experience (tenure < 1 year) benefitted substantially from EDSCB in detecting both improvised explosive devices and bare explosives. A comparison of all three conditions showed that automated decision provided better human-machine detection performance than on-screen alarm resolution and no automation. This came at the cost of slightly higher false alarm rates on the human-machine system level, which would still be acceptable from an operational point of view. Results indicate that a wide-scale implementation of EDSCB would increase the detection of explosives in passenger bags and automated decision instead of automation as diagnostic aid with on screen alarm resolution should be considered. Copyright © 2018 The Authors. Published by Elsevier Ltd.. All rights reserved.

Wireless sensor for detecting explosive material

DOE Office of Scientific and Technical Information (OSTI.GOV)

Lamberti, Vincent E; Howell, Jr., Layton N; Mee, David K

Disclosed is a sensor for detecting explosive devices. The sensor includes a ferromagnetic metal and a molecular recognition reagent coupled to the ferromagnetic metal. The molecular recognition reagent is operable to expand upon absorption of vapor from an explosive material such that the molecular recognition reagent changes a tensile stress upon the ferromagnetic metal. The explosive device is detected based on changes in the magnetic switching characteristics of the ferromagnetic metal caused by the tensile stress.

Design optimization of Cassegrain telescope for remote explosive trace detection

NASA Astrophysics Data System (ADS)

Bhavsar, Kaushalkumar; Eseller, K. E.; Prabhu, Radhakrishna

2017-10-01

The past three years have seen a global increase in explosive-based terror attacks. The widespread use of improvised explosives and anti-personnel landmines have caused thousands of civilian casualties across the world. Current scenario of globalized civilization threat from terror drives the need to improve the performance and capabilities of standoff explosive trace detection devices to be able to anticipate the threat from a safe distance to prevent explosions and save human lives. In recent years, laser-induced breakdown spectroscopy (LIBS) is an emerging approach for material or elemental investigations. All the principle elements on the surface are detectable in a single measurement using LIBS and hence, a standoff LIBS based method has been used to remotely detect explosive traces from several to tens of metres distance. The most important component of LIBS based standoff explosive trace detection system is the telescope which enables remote identification of chemical constituents of the explosives. However, in a compact LIBS system where Cassegrain telescope serves the purpose of laser beam delivery and light collection, need a design optimization of the telescope system. This paper reports design optimization of a Cassegrain telescope to detect explosives remotely for LIBS system. A design optimization of Schmidt corrector plate was carried out for Nd:YAG laser. Effect of different design parameters was investigated to eliminate spherical aberration in the system. Effect of different laser wavelengths on the Schmidt corrector design was also investigated for the standoff LIBS system.

Mid-IR DIAL for high-resolution mapping of explosive precursors

NASA Astrophysics Data System (ADS)

Mitev, V.; Babichenko, S.; Bennes, J.; Borelli, R.; Dolfi-Bouteyre, A.; Fiorani, L.; Hespel, L.; Huet, T.; Palucci, A.; Pistilli, M.; Puiu, A.; Rebane, O.; Sobolev, I.

2013-10-01

A DIAL instrument on a moving platform is seen as a valuable remote sensing component in a sensor network for area monitoring, targeting sites involved in unauthorised explosive manufacturing. Such instrument will perform the area mapping of the vapour concentration of key substances, known to be used as precursors in explosive fabrication, such as acetone and nitromethane. The IR spectra of acetone and nitromethane vapours have been defined from available spectroscopy databases and from laboratory measurements as showing optimal spectral band for the DIAL operation in the spectral range of 3.0 μm - 3.5 μm. The DIAL operation has been numerically simulated, with inputs based on the HITRAN database, the U.S. Standard Atmosphere and aerosol simulation software package OPAC. A combination of OPO and OPA has been chosen as a transmitter, where the idler wavelength is used for probing, with wavelength tuning in sequence. A scanner mounted on top of the coaxially aligned laser and receiver, is capable of covering almost 360 degrees horizontally and +/-30 degrees vertically. The detection is performed by a photovoltaic photodiode with 4-stage cooling, with a signal digitalisation having 14 bit amplitude resolution and 125 Ms/s sampling rate. Here we present the development and the first test of the DIAL instrument.

Detection of residues from explosive manipulation by near infrared hyperspectral imaging: a promising forensic tool.

PubMed

Fernández de la Ossa, Mª Ángeles; Amigo, José Manuel; García-Ruiz, Carmen

2014-09-01

In this study near infrared hyperspectral imaging (NIR-HSI) is used to provide a fast, non-contact, non-invasive and non-destructive method for the analysis of explosive residues on human handprints. Volunteers manipulated individually each of these explosives and after deposited their handprints on plastic sheets. For this purpose, classical explosives, potentially used as part of improvised explosive devices (IEDs) as ammonium nitrate, blackpowder, single- and double-base smokeless gunpowders and dynamite were studied. A partial-least squares discriminant analysis (PLS-DA) model was built to detect and classify the presence of explosive residues in handprints. High levels of sensitivity and specificity for the PLS-DA classification model created to identify ammonium nitrate, blackpowder, single- and double-base smokeless gunpowders and dynamite residues were obtained, allowing the development of a preliminary library and facilitating the direct and in situ detection of explosives by NIR-HSI. Consequently, this technique is showed as a promising forensic tool for the detection of explosive residues and other related samples. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

Ion spectrometric detection technologies for ultra-traces of explosives: a review.

PubMed

Mäkinen, Marko; Nousiainen, Marjaana; Sillanpää, Mika

2011-01-01

In recent years, explosive materials have been widely employed for various military applications and civilian conflicts; their use for hostile purposes has increased considerably. The detection of different kind of explosive agents has become crucially important for protection of human lives, infrastructures, and properties. Moreover, both the environmental aspects such as the risk of soil and water contamination and health risks related to the release of explosive particles need to be taken into account. For these reasons, there is a growing need to develop analyzing methods which are faster and more sensitive for detecting explosives. The detection techniques of the explosive materials should ideally serve fast real-time analysis in high accuracy and resolution from a minimal quantity of explosive without involving complicated sample preparation. The performance of the in-field analysis of extremely hazardous material has to be user-friendly and safe for operators. The two closely related ion spectrometric methods used in explosive analyses include mass spectrometry (MS) and ion mobility spectrometry (IMS). The four requirements-speed, selectivity, sensitivity, and sampling-are fulfilled with both of these methods. Copyright © 2011 Wiley Periodicals, Inc.

"Fooling fido"--chemical and behavioral studies of pseudo-explosive canine training aids.

PubMed

Kranz, William D; Strange, Nicholas A; Goodpaster, John V

2014-12-01

Genuine explosive materials are traditionally employed in the training and testing of explosive-detecting canines so that they will respond reliably to these substances. However, challenges arising from the acquisition, storage, handling, and transportation of explosives have given rise to the development of "pseudo-explosive" training aids. These products attempt to emulate the odor of real explosives while remaining inert. Therefore, a canine trained on a pseudo-explosive should respond to its real-life analog. Similarly, a canine trained on an actual explosive should respond to the pseudo-explosive as if it was real. This research tested those assumptions with a focus on three explosives: single-base smokeless powder, 2,4,6-trinitrotoluene (TNT), and a RDX-based plastic explosive (Composition C-4). Using gas chromatography-mass spectrometry with solid phase microextraction as a pre-concentration technique, we determined that the volatile compounds given off by pseudo-explosive products consisted of various solvents, known additives from explosive formulations, and common impurities present in authentic explosives. For example, simulated smokeless powders emitted terpenes, 2,4-dinitrotoluene, diphenylamine, and ethyl centralite. Simulated TNT products emitted 2,4- and 2,6-dinitrotoluene. Simulated C-4 products emitted cyclohexanone, 2-ethyl-1-hexanol, and dimethyldinitrobutane. We also conducted tests to determine whether canines trained on pseudo-explosives are capable of alerting to genuine explosives and vice versa. The results show that canines trained on pseudo-explosives performed poorly at detecting all but the pseudo-explosives they are trained on. Similarly, canines trained on actual explosives performed poorly at detecting all but the actual explosives on which they were trained.

The signature-based radiation-scanning approach to standoff detection of improvised explosive devices.

PubMed

Brewer, R L; Dunn, W L; Heider, S; Matthew, C; Yang, X

2012-07-01

The signature-based radiation-scanning technique for detection of improvised explosive devices is described. The technique seeks to detect nitrogen-rich chemical explosives present in a target. The technology compares a set of "signatures" obtained from a test target to a collection of "templates", sets of signatures for a target that contain an explosive in a specific configuration. Interrogation of nitrogen-rich fertilizer samples, which serve as surrogates for explosives, is shown experimentally to be able to discriminate samples of 3.8L and larger. Copyright © 2011 Elsevier Ltd. All rights reserved.

Deterrence Requirements and Arms Control Responsibilities: The United State’s Obligation to Ratify the Comprehensive Nuclear Test Ban Treaty

DTIC Science & Technology

2010-02-17

systems to detect a nuclear explosion; seismic, hydroacoustic, infrasound , and radionuclide. These stations are able to detect a nuclear explosion as...These sites detect thousands of seismic events a year, mainly from earthquakes and mining explosions, and have proved effective in detecting past...that detect sound waves in the oceans, and the 60 infrasound stations above ground that detect ultra-low frequency sound waves emitted by nuclear

Nuclear quadrupole resonance detection of explosives: an overview

NASA Astrophysics Data System (ADS)

Miller, Joel B.

2011-06-01

Nuclear Quadrupole Resonance (NQR) is a spectroscopic technique closely related to Nuclear Magnetic Resonance (NMR) and Magnetic Resonance Imaging (MRI). These techniques, and NQR in particular, induce signals from the material being interrogated that are very specific to the chemical and physical structure of the material, but are relatively insensitive to the physical form of the material. NQR explosives detection exploits this specificity to detect explosive materials, in contrast to other well known techniques that are designed to detect explosive devices. The past two decades have seen a large research and development effort in NQR explosives detection in the United States aimed at transportation security and military applications. Here, I will briefly describe the physical basis for NQR before discussing NQR developments over the past decade, with particular emphasis on landmine detection and the use of NQR in combating IED's. Potential future directions for NQR research and development are discussed.

Development of Photoacoustic Sensing Platforms at the US Army Research Laboratory

DTIC Science & Technology

2016-09-01

RDX and TNT explosives with carbon dioxide laser. J Appl Spectrosc. 2006;73(1):123–129. 45. Petzold A, Niessner R. Photoacoustic soot sensor for in...Development of Photoacoustic Sensing Platforms at the US Army Research Laboratory by Ellen L Holthoff and Paul M Pellegrino Sensors and Electron Devices...NOTES 14. ABSTRACT Traditionally, chemical sensing platforms have been hampered by the opposing concerns of increasing sensor capability while

Roadside IED detection using subsurface imaging radar and rotary UAV

NASA Astrophysics Data System (ADS)

Qin, Yexian; Twumasi, Jones O.; Le, Viet Q.; Ren, Yu-Jiun; Lai, C. P.; Yu, Tzuyang

2016-05-01

Modern improvised explosive device (IED) and mine detection sensors using microwave technology are based on ground penetrating radar operated by a ground vehicle. Vehicle size, road conditions, and obstacles along the troop marching direction limit operation of such sensors. This paper presents a new conceptual design using a rotary unmanned aerial vehicle (UAV) to carry subsurface imaging radar for roadside IED detection. We have built a UAV flight simulator with the subsurface imaging radar running in a laboratory environment and tested it with non-metallic and metallic IED-like targets. From the initial lab results, we can detect the IED-like target 10-cm below road surface while carried by a UAV platform. One of the challenges is to design the radar and antenna system for a very small payload (less than 3 lb). The motion compensation algorithm is also critical to the imaging quality. In this paper, we also demonstrated the algorithm simulation and experimental imaging results with different IED target materials, sizes, and clutters.

Remote detection of buried land-mines and IEDs using LWIR polarimetric imaging.

PubMed

Gurton, Kristan P; Felton, Melvin

2012-09-24

We report results of an ongoing study designed to assess the ability for enhanced detection of recently buried land-mines and/or improvised explosive devices (IED) devices using passive long-wave infrared (LWIR) polarimetric imaging. Polarimetric results are presented for a series of field tests conducted at various locations and soil types. Well-calibrated Stokes images, S0, S1, S2, and the degree-of-linear-polarization (DoLP) are recorded for different line-of-sight (LOS) slant paths at varying distances. Results span a three-year time period in which three different LWIR polarimetric camera systems are used. All three polarimetric imaging platforms used a spinning-achromatic-retarder (SAR) design capable of achieving high polarimetric frame rates and good radiometric throughput without the loss of spatial resolution inherent in other optical designs. Receiver-operating-characteristic (ROC) analysis and a standardized contrast parameter are used to compare detectability between conventional LWIR thermal and polarimetric imagery. Results suggest improved detectability, regardless of geographic location or soil type.

Recent advances and remaining challenges for the spectroscopic detection of explosive threats.

PubMed

Fountain, Augustus W; Christesen, Steven D; Moon, Raphael P; Guicheteau, Jason A; Emmons, Erik D

2014-01-01

In 2010, the U.S. Army initiated a program through the Edgewood Chemical Biological Center to identify viable spectroscopic signatures of explosives and initiate environmental persistence, fate, and transport studies for trace residues. These studies were ultimately designed to integrate these signatures into algorithms and experimentally evaluate sensor performance for explosives and precursor materials in existing chemical point and standoff detection systems. Accurate and validated optical cross sections and signatures are critical in benchmarking spectroscopic-based sensors. This program has provided important information for the scientists and engineers currently developing trace-detection solutions to the homemade explosive problem. With this information, the sensitivity of spectroscopic methods for explosives detection can now be quantitatively evaluated before the sensor is deployed and tested.

Contributed review: quantum cascade laser based photoacoustic detection of explosives.

PubMed

Li, J S; Yu, B; Fischer, H; Chen, W; Yalin, A P

2015-03-01

Detecting trace explosives and explosive-related compounds has recently become a topic of utmost importance for increasing public security around the world. A wide variety of detection methods and an even wider range of physical chemistry issues are involved in this very challenging area. Optical sensing methods, in particular mid-infrared spectrometry techniques, have a great potential to become a more desirable tools for the detection of explosives. The small size, simplicity, high output power, long-term reliability make external cavity quantum cascade lasers (EC-QCLs) the promising spectroscopic sources for developing analytical instrumentation. This work reviews the current technical progress in EC-QCL-based photoacoustic spectroscopy for explosives detection. The potential for both close-contact and standoff configurations using this technique is completely presented over the course of approximately the last one decade.

Contributed Review: Quantum cascade laser based photoacoustic detection of explosives

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, J. S., E-mail: jingsong-li@ahu.edu.cn; Yu, B.; Fischer, H.

2015-03-15

Detecting trace explosives and explosive-related compounds has recently become a topic of utmost importance for increasing public security around the world. A wide variety of detection methods and an even wider range of physical chemistry issues are involved in this very challenging area. Optical sensing methods, in particular mid-infrared spectrometry techniques, have a great potential to become a more desirable tools for the detection of explosives. The small size, simplicity, high output power, long-term reliability make external cavity quantum cascade lasers (EC-QCLs) the promising spectroscopic sources for developing analytical instrumentation. This work reviews the current technical progress in EC-QCL-based photoacousticmore » spectroscopy for explosives detection. The potential for both close-contact and standoff configurations using this technique is completely presented over the course of approximately the last one decade.« less

Effects of Whole-body Vibration Training on Sprint Running Kinematics and Explosive Strength Performance

PubMed Central

Giorgos, Paradisis; Elias, Zacharogiannis

2007-01-01

The aim of this study was to investigate the effect of 6 wk of whole body vibration (WBV) training on sprint running kinematics and explosive strength performance. Twenty-four volunteers (12 women and 12 men) participated in the study and were randomised (n = 12) into the experimental and control groups. The WBV group performed a 6-wk program (16-30 min·d-1, 3 times a week) on a vibration platform. The amplitude of the vibration platform was 2.5 mm and the acceleration was 2.28 g. The control group did not participate in any training. Tests were performed Pre and post the training period. Sprint running performance was measured during a 60 m sprint where running time, running speed, step length and step rate were calculated. Explosive strength performance was measured during a counter movement jump (CMJ) test, where jump height and total number of jumps performed in a period of 30 s (30CVJT). Performance in 10 m, 20 m, 40 m, 50 m and 60 m improved significantly after 6 wk of WBV training with an overall improvement of 2.7%. The step length and running speed improved by 5.1% and 3.6%, and the step rate decreased by 3.4%. The countermovement jump height increased by 3.3%, and the explosive strength endurance improved overall by 7.8%. The WBV training period of 6 wk produced significant changes in sprint running kinematics and explosive strength performance. Key pointsWBV training.Sprint running kinematics.Explosive strength performance PMID:24149223

Colorimetric chemical analysis sampler for the presence of explosives

DOEpatents

Nunes, Peter J [Danville, CA; Del Eckels, Joel [Livermore, CA; Reynolds, John G [San Ramon, CA; Pagoria, Philip F [Livermore, CA; Simpson, Randall L [Livermore, CA

2011-09-27

A tester for testing for explosives comprising a body, a lateral flow swab unit operably connected to the body, a explosives detecting reagent contained in the body, and a dispenser operatively connected to the body and the lateral flow swab unit. The dispenser selectively allows the explosives detecting reagent to be delivered to the lateral flow swab unit.

Colorimetric chemical analysis sampler for the presence of explosives

DOEpatents

Nunes, Peter J.; Eckels, Joel Del; Reynolds, John G.; Pagoria, Philip F.; Simpson, Randall L.

2014-07-01

A tester for testing for explosives comprising a body, a lateral flow swab unit operably connected to the body, a explosives detecting reagent contained in the body, and a dispenser operatively connected to the body and the lateral flow swab unit. The dispenser selectively allows the explosives detecting reagent to be delivered to the lateral flow swab unit.

Comparison of an antibody and its recombinant derivative for the detection of the small molecule explosive 2,4,6-trinitrotoluene.

PubMed

Liu, Jinny L; Zabetakis, Dan; Acevedo-Vélez, Glendalys; Goldman, Ellen R; Anderson, George P

2013-01-08

Antibodies are commonly used as recognition elements in immunoassays because of their high specificity and affinity, and have seen extensive use in competitive assays for the detection of small molecules. However, these complex molecules require production either in animals or by mammalian cell cultures, and are not easily tailored through genetic manipulation. Single chain antibodies (scFv), recombinantly expressed molecules consisting of only the antibody's binding region joined via a linking peptide, can provide an alternative to intact antibodies. We describe the characterization of a new monoclonal antibody (mAb), 2G5B5, able to detect the small molecule explosive 2,4,6-trinitrotoluene (TNT) and the scFv derived from its variable regions. The mAb and scFv were tested by surface plasmon resonance to determine their affinity for an immobilized TNT surrogate; dissociation constants were determined to be 1.5×10(-13) M and 4.8×10(-10) M respectively. Circular dichroism was used to determine their melting temperatures. The mAb is more stable melting at ∼75°C while the scFv melts at ∼65°C. The recognition elements were incorporated into a competitive assay format using a bead-based multiplexing platform to examine their sensitivity and specificity. The scFv was able to detect TNT ∼10-fold more sensitively than the mAb in this assay format, allowing detection of TNT concentrations down to at least 1 μg L(-1). The 2G5B gave similar detection limits to a commercial anti-TNT mAb, but was less specific, recognizing 1,3,5-trinitrobenzene (TNB) equally well as TNT. Published by Elsevier B.V.

Applications for the MATILDA robotic platform

NASA Astrophysics Data System (ADS)

Munkeby, Steve H.; Jones, Don; Bugg, George; Smith, Kathryn

2002-07-01

Most robotic platforms have, up to this point, been designed with emphasis placed on improving mobility technologies. Minimal emphasis has been placed on payloads and mission execution. Using a top-down approach, Mesa Associates, Inc. identified specific UGV mission applications and structured its MATILDA platform using these applications for vehicle mobility and motion control requirements. Specific applications identified for the MATILDA platform include: Target surveillance, explosive device neutralization, material pickup and transport, weapon transport and firing, and law enforcement. Current performance results, lessons-learned, technical hurdles, and future applications are examined.

Spectroscopic signatures of PETN in contact with sand particles

NASA Astrophysics Data System (ADS)

Ballesteros, Luz M.; Herrera, Gloria M.; Castro, Miguel E.; Briano, Julio; Mina, Nairmen; Hernandez-Rivera, Samuel P.

2005-06-01

The detection of explosive materials is not only important as an issue in landmines but also for global security reasons, unexploded ordnance, and Improvised Explosive Devices detection. In such areas, explosives detection has played a central role in ensuring the safety of the lives of citizens in many countries. Raman Spectroscopy is a well established tool for vibrational spectroscopic analysis and can be applied to the field of explosives identification and detection. The analysis of PETN is important because it is used in laminar form or mixed with RDX to manufacture Semtex plastic explosive and in the fabrication of Improvised Explosive Devices (IEDs). Our investigation is focused on the study of spectroscopic signatures of PETN in contact with soil. Ottawa sand mixed in different proportions with PETN together with the study of the influence of pH, temperature, humidity, and UV light on the vibrational signatures of the mixtures constitute the core of the investigation. The results reveal that the characteristic bands of PETN are not significantly shifted but rather appear constant with respect of the ubiquitous band of sand (~463 cm-1). These results will make possible the development of highly sensitive sensors for detection of explosives materials and IDEs.

Discrimination of smokeless powders by headspace SPME-GC-MS and SPME-GC-ECD, and the potential implications upon training canine detection of explosives

NASA Astrophysics Data System (ADS)

Harper, Ross J.; Almirall, Jose R.; Furton, Kenneth G.

2005-05-01

This presentation will provide an odour analysis of a variety of smokeless powders & communicate the rapid SPME-GC-ECD method utilized. This paper will also discuss the implications of the headspace analysis of Smokeless Powders upon the choice of training aids for Explosives Detection Canines. Canine detection of explosives relies upon the dogs" ability to equate finding a given explosive odour with a reward, usually in the form of praise or play. The selection of explosives upon which the dogs are trained thus determines which explosives the canines can and potentially cannot find. Commonly, the training is focussed towards high explosives such as TNT and Composition 4, and the low explosives such as Black and Smokeless Powders are added often only for completeness. Powder explosives constitute a major component of explosive incidents throughout the US, and canines trained to detect explosives must be trained across the entire range of powder products. Given the variability in the manufacture and product make-up many smokeless powders do not share common odour chemicals, giving rise to concerns over the extensiveness of canine training. Headspace analysis of a selection of Smokeless Powders by Solid Phase Microextraction Gas Chromatography using Mass Spectrometry (SPME-GC-MS) and Electron Capture Detectors (SPME-GC-ECD) has highlighted significant differences in the chemical composition of the odour available from different brands. This suggests that greater attention should be paid towards the choice of Powder Explosives when assigning canine training aids.

Seismicity and infrasound associated with explosions at Mount St. Helens, 2004-2005: Chapter 6 in A volcano rekindled: the renewed eruption of Mount St. Helens, 2004-2006

USGS Publications Warehouse

Moran, Seth C.; McChesney, Patrick J.; Lockhart, Andrew B.; Sherrod, David R.; Scott, William E.; Stauffer, Peter H.

2008-01-01

Six explosions occurred during 2004-5 in association with renewed eruptive activity at Mount St. Helens, Washington. Of four explosions in October 2004, none had precursory seismicity and two had explosion-related seismic tremor that marked the end of the explosion. However, seismicity levels dropped following each of the October explosions, providing the primary instrumental means for explosion detection during the initial vent-clearing phase. In contrast, explosions on January 16 and March 8, 2005, produced noticeable seismicity in the form of explosion-related tremor, infrasonic signals, and, in the case of the March 8 explosion, an increase in event size ~2 hours before the explosion. In both 2005 cases seismic tremor appeared before any infrasonic signals and was best recorded on stations located within the crater. These explosions demonstrated that reliable explosion detection at volcanoes like Mount St. Helens requires seismic stations within 1-2 km of the vent and stations with multiple acoustic sensors.

Current trends in explosive detection techniques.

PubMed

Caygill, J Sarah; Davis, Frank; Higson, Seamus P J

2012-01-15

The detection of explosives and explosive-related compounds has become a heightened priority in recent years for homeland security and counter-terrorism applications. There has been a huge increase in research within this area-through both the development of new, innovative detection approaches and the improvement of existing techniques. Developments for miniaturisation, portability, field-ruggedisation and improvements in stand-off distances, selectivity and sensitivity have been necessary to develop and improve techniques. This review provides a consolidation of information relating to recent advances in explosive detection techniques without being limited to one specific research area or explosive type. The focus of this review will be towards advances in the last 5 years, with the reader being referred to earlier reviews where appropriate. Copyright © 2011. Published by Elsevier B.V.

The Arizona Wallow Wildfire: Monitoring It's Progress, Extreme Behavior and Long Range Smoke Transport from Multiple Satellite Platforms

NASA Astrophysics Data System (ADS)

Ruminski, M. G.; Fromm, M. D.; Ramirez, E.

2011-12-01

The Wallow fire in southeast Arizona was the largest wildfire in Arizona history, consuming over 500,000 acres. The fire began on May 29, 2011 and quickly grew to nearly 70,000 acres in size by June 4. This event exhibited anomalous behavioral characteristics as deep pyroconvection was observed for an unprecedented six consecutive days. The rapid spread and extreme pyroconvection occurred in response to a unique confluence of high biomass fuel availability in arid conditions. Strong winds in combination with low relative humidity and atmospheric instability acted to create an environment conducive to explosive fire growth. The resultant smoke from the blaze reached an altitude of nearly 15 km into the upper troposphere/lower stratosphere and eventually crossed the Atlantic reaching Europe. This presentation focuses on the detection and characterization of the Wallow fire from a satellite perspective. Geostationary and polar orbiting satellite platforms have captured various aspects of the fire and resulting smoke plumes. An animation of nearly 100 NOAA polar orbiting 4 micron channel images during the first 2 weeks of the fire illustrate its explosive growth while GOES visible channel animations display the density and coverage of the pall of smoke and the development of pyroconvection. True color MODIS imagery provides higher resolution views of the pyrocumulonimbus clouds at different stages in their evolution. CALIPSO, GOME2, and OMI data detail the vertical structure and composition of the plume as it drifts eastward and expands in coverage, eventually reaching Europe.

The Expansion of Explosives Safety Education for the 21st Century

DTIC Science & Technology

2010-07-01

shape charges, explosive welding, thermite reaction – Sensitivity testing: drop hammer, electrospark discharge, friction – Physics of explosives, history... ATF ) • Phytoremediation workers use plants to remove explosives from soil and render the explosives harmless • Sales of explosives detection

Behavioural and Genetic Evidence for C. elegans' Ability to Detect Volatile Chemicals Associated with Explosives

PubMed Central

Liao, Chunyan; Gock, Andrew; Michie, Michelle; Morton, Bethany; Anderson, Alisha; Trowell, Stephen

2010-01-01

Background Automated standoff detection and classification of explosives based on their characteristic vapours would be highly desirable. Biologically derived odorant receptors have potential as the explosive recognition element in novel biosensors. Caenorhabditis elegans' genome contains over 1,000 uncharacterised candidate chemosensory receptors. It was not known whether any of these respond to volatile chemicals derived from or associated with explosives. Methodology/Principal Findings We assayed C. elegans for chemotactic responses to chemical vapours of explosives and compounds associated with explosives. C. elegans failed to respond to many of the explosive materials themselves but showed strong chemotaxis with a number of compounds associated with commercial or homemade explosives. Genetic mutant strains were used to identify the likely neuronal location of a putative receptor responding to cyclohexanone, which is a contaminant of some compounded explosives, and to identify the specific transduction pathway involved. Upper limits on the sensitivity of the nematode were calculated. A sensory adaptation protocol was used to estimate the receptive range of the receptor. Conclusions/Significance: The results suggest that C. elegans may be a convenient source of highly sensitive, narrowly tuned receptors to detect a range of explosive-associated volatiles. PMID:20830309

Method and apparatus for detecting explosives

DOEpatents

Moore, David Steven [Santa Fe, NM

2011-05-10

A method and apparatus is provided for detecting explosives by thermal imaging. The explosive material is subjected to a high energy wave which can be either a sound wave or an electromagnetic wave which will initiate a chemical reaction in the explosive material which chemical reaction will produce heat. The heat is then sensed by a thermal imaging device which will provide a signal to a computing device which will alert a user of the apparatus to the possibility of an explosive device being present.

Photo-vibrational sensing of trace chemicals and explosives by long-distance differential laser Doppler vibrometer

NASA Astrophysics Data System (ADS)

Fu, Yu; Liu, Huan; Hu, Qi; Xie, Jiecheng

2017-05-01

Photoacoustic/photothermal spectroscopy is an established technique for trace detection of chemicals and explosives. Normally high-sensitive microphone or PZT sensor is used to detect the signal in photoacoustic cell. In recent years, laser Doppler vibrometer (LDV) is proposed to remote-sense photoacoustic signal on various substrates. It is a highsensitivity sensor with a displacement resolution of <10pm. In this research, the photoacoustic effect of various chemicals and explosives is excited by a quantum cascade laser (QCL) at their absorbance peak. A home-developed differential LDV at 1550nm wavelength is applied to detect the vibration signal at 100m. A differential configuration is applied to minimize the environment factors, such as environment noise and vibration, air turbulence, etc. and increase the detection sensitivity. The photo-vibrational signal of chemicals and explosives on different substrates are detected. The results show the potential of the proposed technique on detection of trace chemicals and explosives at long standoff distance.

Photoacoustic Spectroscopy for Trace Vapor Detection and Standoff Detection of Explosives

DTIC Science & Technology

2016-08-01

ARL-RP-0577 ● AUG 2016 US Army Research Laboratory Photoacoustic Spectroscopy for Trace Vapor Detection and Standoff Detection...Photoacoustic Spectroscopy for Trace Vapor Detection and Standoff Detection of Explosives by Ellen L Holthoff and Paul M Pellegrino Sensors and Electron...

Evaluation of active and passive near-millimeter-wave radiometric imaging techniques for detection of concealed objects

NASA Astrophysics Data System (ADS)

Reber, E. E.; Foote, F. B.; Schellenbaum, R. L.; Bradley, R. G.

1981-07-01

The potential of radiometric imaging technique to detect shielded nuclear materials and explosives carried covertly by personnel was investigated. This method of detecting contraband depends upon the differences in emissivity and reflectivity of the contraband relative to human tissue. Explosives, unlike metals and metal composites, generally have high emissivities and low reflectivities that closely approximate those of human tissue making explosives difficult to detect. Samples of several common types of explosives (TNT, Detasheet, C4, and several types of water gels) were examined at the 1.4- and 3-mm wavelengths using active and passive radiometeric techniques.

Noncontact detection of homemade explosive constituents via photodissociation followed by laser-induced fluorescence.

PubMed

Wynn, C M; Palmacci, S; Kunz, R R; Rothschild, M

2010-03-15

Noncontact detection of the homemade explosive constituents urea nitrate, nitromethane and ammonium nitrate is achieved using photodissociation followed by laser-induced fluorescence (PD-LIF). Our technique utilizes a single ultraviolet laser pulse (approximately 7 ns) to vaporize and photodissociate the condensed-phase materials, and then to detect the resulting vibrationally-excited NO fragments via laser-induced fluorescence. PD-LIF excitation and emission spectra indicate the creation of NO in vibrationally-excited states with significant rotational energy, useful for low-background detection of the parent compound. The results for homemade explosives are compared to one another and 2,6-dinitrotoluene, a component present in many military explosives.

Explosives detection and identification using surface plasmon-coupled emission

NASA Astrophysics Data System (ADS)

Ja, Shiou-Jyh

2012-06-01

To fight against the explosives-related threats in defense and homeland security applications, a smarter sensing device that not only detects but differentiates multiple true threats from false positives caused by environmental interferents is essential. A new optical detection system is proposed to address these issues by using the temporal and spectroscopic information generated by the surface plasmon coupling emission (SPCE) effect. Innovative SPCE optics have been designed using Zemax software to project the fluorescence signal into clear "rainbow rings" on a CCD with subnanometer wavelength resolution. The spectroscopic change of the fluorescence signal and the time history of such changes due to the presence of a certain explosive analyte are unique and can be used to identify explosives. Thanks to high optical efficiency, reporter depositions as small as 160-μm in diameter can generate a sufficient signal, allowing a dense array of different reporters to be interrogated with wavelength multiplexing and detect a wide range of explosives. We have demonstrated detection and classification of explosives, such as TNT, NT, NM, RDX, PETN, and AN, with two sensing materials in a prototype.

The limit of detection for explosives in spectroscopic differential reflectometry

NASA Astrophysics Data System (ADS)

Dubroca, Thierry; Vishwanathan, Karthik; Hummel, Rolf E.

2011-05-01

In the wake of recent terrorist attacks, such as the 2008 Mumbai hotel explosion or the December 25th 2009 "underwear bomber", our group has developed a technique (US patent #7368292) to apply differential reflection spectroscopy to detect traces of explosives. Briefly, light (200-500 nm) is shone on a surface such as a piece of luggage at an airport. Upon reflection, the light is collected with a spectrometer combined with a CCD camera. A computer processes the data and produces in turn a differential reflection spectrum involving two adjacent areas of the surface. This differential technique is highly sensitive and provides spectroscopic data of explosives. As an example, 2,4,6, trinitrotoluene (TNT) displays strong and distinct features in differential reflectograms near 420 nm. Similar, but distinctly different features are observed for other explosives. One of the most important criteria for explosive detection techniques is the limit of detection. This limit is defined as the amount of explosive material necessary to produce a signal to noise ratio of three. We present here, a method to evaluate the limit of detection of our technique. Finally, we present our sample preparation method and experimental set-up specifically developed to measure the limit of detection for our technology. This results in a limit ranging from 100 nano-grams to 50 micro-grams depending on the method and the set-up parameters used, such as the detector-sample distance.

Real-time explosive particle detection using a cyclone particle concentrator.

PubMed

Hashimoto, Yuichiro; Nagano, Hisashi; Takada, Yasuaki; Kashima, Hideo; Sugaya, Masakazu; Terada, Koichi; Sakairi, Minoru

2014-06-30

There is a need for more rapid methods for the detection of explosive particles. We have developed a novel real-time analysis technique for explosive particles that uses a cyclone particle concentrator. This technique can analyze sample surfaces for the presence of particles from explosives such as TNT and RDX within 3 s, which is much faster than is possible by conventional methods. Particles are detached from the sample surface with air jet pulses, and then introduced into a cyclone particle concentrator with a high pumping speed of about 80 L/min. A vaporizer placed at the bottom of the cyclone particle concentrator immediately converts the particles into a vapor. The vapor is then ionized in the atmospheric pressure chemical ionization (APCI) source of a linear ion trap mass spectrometer. An online connection between the vaporizer and a mass spectrometer enables high-speed detection within a few seconds, compared with the conventional off-line heating method that takes more than 10 s to raise the temperature of a sample filter unit. Since the configuration enriched the number density of explosive particles by about 80 times compared with that without the concentrator, a sub-ng amount of TNT particles on a surface was detectable. The detection limit of our technique is comparable with that of an explosives trace detector using ion mobility spectrometry. The technique will be beneficial for trace detection in security applications, because it detects explosive particles on the surface more speedily than conventional methods. Copyright © 2014 John Wiley & Sons, Ltd.

Tunable generation and adsorption of energetic compounds in the vapor phase at trace levels: a tool for testing and developing sensitive and selective substrates for explosive detection.

PubMed

Bonnot, Karine; Bernhardt, Pierre; Hassler, Dominique; Baras, Christian; Comet, Marc; Keller, Valérie; Spitzer, Denis

2010-04-15

Among various methods for landmine detection, as well as soil and water pollution monitoring, the detection of explosive compounds in air is becoming an important and inevitable challenge for homeland security applications, due to the threatening increase in terrorist explosive bombs used against civil populations. However, in the last case, there is a crucial need for the detection of vapor phase traces or subtraces (in the ppt range or even lower). A novel and innovative generator for explosive trace vapors was designed and developed. It allowed the generation of theoretical concentrations as low as 0.24 ppq for hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) in air according to Clapeyron equations. The accurate generation of explosive concentrations at subppt levels was verified for RDX and 2,4,6-trinitrotoluene (TNT) using a gas chromatograph coupled to an electron capture detector (GC-ECD). First, sensing material experiments were conducted on a nanostructured tungsten oxide. The sensing efficiency of this material determined as its adsorption capacity toward 54 ppb RDX was calculated to be five times higher than the sensing efficiency of a 54 ppb TNT vapor. The material sensing efficiency showed no dependence on the mass of material used. The results showed that the device allowed the calibration and discrimination between materials for highly sensitive and accurate sensing detection in air of low vapor pressure explosives such as TNT or RDX at subppb levels. The designed device and method showed promising features for nanosensing applications in the field of ultratrace explosive detection. The current perspectives are to decrease the testing scale and the detection levels to ppt or subppt concentration of explosives in air.

Instant detection and identification of concealed explosive-related compounds: Induced Stokes Raman versus infrared.

PubMed

Elbasuney, Sherif; El-Sherif, Ashraf F

2017-01-01

The instant detection of explosives and explosive-related compounds has become an urgent priority in recent years for homeland security and counter-terrorism applications. Modern techniques should offer enhancement in selectivity, sensitivity, and standoff distances. Miniaturisation, portability, and field-ruggedisation are crucial requirements. This study reports on instant and standoff identification of concealed explosive-related compounds using customized Raman technique. Stokes Raman spectra of common explosive-related compounds were generated and spectrally resolved to create characteristic finger print spectra. The scattered Raman emissions over the band 400:2000cm -1 were compared to infrared absorption using FTIR. It has been demonstrated that the two vibrational spectroscopic techniques were opposite and completing each other. Molecular vibrations with strong absorption in infrared (those involve strong change in dipole moments) induced weak signals in Raman and vice versa. The tailored Raman offered instant detection, high sensitivity, and standoff detection capabilities. Raman demonstrated characteristic fingerprint spectra with stable baseline and sharp intense peaks. Complete correlations of absorption/scattered signals to certain molecular vibrations were conducted to generate an entire spectroscopic profile of explosive-related compounds. This manuscript shades the light on Raman as one of the prevailing technologies for instantaneous detection of explosive-related compounds. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

Chemical sensing system for classification of minelike objects by explosives detection

NASA Astrophysics Data System (ADS)

Chambers, William B.; Rodacy, Philip J.; Jones, Edwin E.; Gomez, Bernard J.; Woodfin, Ronald L.

1998-09-01

Sandia National Laboratories has conducted research in chemical sensing and analysis of explosives for many years. Recently, that experience has been directed towards detecting mines and unexploded ordnance (UXO) by sensing the low-level explosive signatures associated with these objects. Our focus has been on the classification of UXO in shallow water and anti-personnel/anti tank mines on land. The objective of this work is to develop a field portable chemical sensing system which can be used to examine mine-like objects (MLO) to determine whether there are explosive molecules associated with the MLO. Two sampling subsystems have been designed, one for water collection and one for soil/vapor sampling. The water sampler utilizes a flow-through chemical adsorbent canister to extract and concentrate the explosive molecules. Explosive molecules are thermally desorbed from the concentrator and trapped in a focusing stage for rapid desorption into an ion-mobility spectrometer (IMS). We will describe a prototype system which consists of a sampler, concentrator-focuser, and detector. The soil sampler employs a light-weight probe for extracting and concentrating explosive vapor from the soil in the vicinity of an MLO. The chemical sensing system is capable of sub-part-per-billion detection of TNT and related explosive munition compounds. We will present the results of field and laboratory tests on buried landmines, which demonstrate our ability to detect the explosive signatures associated with these objects.

Finite-Time Performance of Local Search Algorithms: Theory and Application

DTIC Science & Technology

2010-06-10

security devices deployed at airport security checkpoints are used to detect prohibited items (e.g., guns, knives, explosives). Each security device...security devices are deployed, the practical issue of determining how to optimally use them can be difficult. For an airport security system design...checked baggage), explosive detection systems (designed to detect explosives in checked baggage), and detailed hand search by an airport security official

Rarefaction Shock Wave Cutter for Offshore Oil-Gas Platform Removal Final Report CRADA No. TC02009.0

DOE Office of Scientific and Technical Information (OSTI.GOV)

Glenn, L. A.; Barker, J.

This was a collaborative effort between Lawrence Livermore National Security, LLC/Lawrence Livermore National Laboratory (LLNL) (formerly the University of California) and Jet Research Center, a wholly owned division of Halliburton Energy Services, Inc. to design and prototype an improved explosive cutter for cutting the support legs of offshore oil and gas platforms.

27 CFR 555.186 - Seizure or forfeiture.

Code of Federal Regulations, 2013 CFR

2013-04-01

... EXPLOSIVES, DEPARTMENT OF JUSTICE EXPLOSIVES COMMERCE IN EXPLOSIVES Marking of Plastic Explosives § 555.186 Seizure or forfeiture. Any plastic explosive that does not contain a detection agent in violation of 18 U... of this chapter for regulations on summary destruction of plastic explosives that do not contain a...

27 CFR 555.186 - Seizure or forfeiture.

Code of Federal Regulations, 2014 CFR

2014-04-01

... EXPLOSIVES, DEPARTMENT OF JUSTICE EXPLOSIVES COMMERCE IN EXPLOSIVES Marking of Plastic Explosives § 555.186 Seizure or forfeiture. Any plastic explosive that does not contain a detection agent in violation of 18 U... of this chapter for regulations on summary destruction of plastic explosives that do not contain a...

27 CFR 555.186 - Seizure or forfeiture.

Code of Federal Regulations, 2012 CFR

2012-04-01

... EXPLOSIVES, DEPARTMENT OF JUSTICE EXPLOSIVES COMMERCE IN EXPLOSIVES Marking of Plastic Explosives § 555.186 Seizure or forfeiture. Any plastic explosive that does not contain a detection agent in violation of 18 U... of this chapter for regulations on summary destruction of plastic explosives that do not contain a...

27 CFR 555.186 - Seizure or forfeiture.

Code of Federal Regulations, 2011 CFR

2011-04-01

... EXPLOSIVES, DEPARTMENT OF JUSTICE EXPLOSIVES COMMERCE IN EXPLOSIVES Marking of Plastic Explosives § 555.186 Seizure or forfeiture. Any plastic explosive that does not contain a detection agent in violation of 18 U... of this chapter for regulations on summary destruction of plastic explosives that do not contain a...

27 CFR 555.186 - Seizure or forfeiture.

Code of Federal Regulations, 2010 CFR

2010-04-01

... EXPLOSIVES, DEPARTMENT OF JUSTICE EXPLOSIVES COMMERCE IN EXPLOSIVES Marking of Plastic Explosives § 555.186 Seizure or forfeiture. Any plastic explosive that does not contain a detection agent in violation of 18 U... of this chapter for regulations on summary destruction of plastic explosives that do not contain a...

NQR detection of explosive simulants using RF atomic magnetometers

NASA Astrophysics Data System (ADS)

Monti, Mark C.; Alexson, Dimitri A.; Okamitsu, Jeffrey K.

2016-05-01

Nuclear Quadrupole Resonance (NQR) is a highly selective spectroscopic method that can be used to detect and identify a number of chemicals of interest to the defense, national security, and law enforcement community. In the past, there have been several documented attempts to utilize NQR to detect nitrogen bearing explosives using induction sensors to detect the NQR RF signatures. We present here our work on the NQR detection of explosive simulants using optically pumped RF atomic magnetometers. RF atomic magnetometers can provide an order of magnitude (or more) improvement in sensitivity versus induction sensors and can enable mitigation of RF interference, which has classically has been a problem for conventional NQR using induction sensors. We present the theory of operation of optically pumped RF atomic magnetometers along with the result of laboratory work on the detection of explosive simulant material. An outline of ongoing work will also be presented along with a path for a fieldable detection system.

Detection of bulk explosives using the GPR only portion of the HSTAMIDS system

NASA Astrophysics Data System (ADS)

Tabony, Joshua; Carlson, Douglas O.; Duvoisin, Herbert A., III; Torres-Rosario, Juan

2010-04-01

The legacy AN/PSS-14 (Army-Navy Portable Special Search-14) Handheld Mine Detecting Set (also called HSTAMIDS for Handheld Standoff Mine Detection System) has proven itself over the last 7 years as the state-of-the-art in land mine detection, both for the US Army and for Humanitarian Demining groups. Its dual GPR (Ground Penetrating Radar) and MD (Metal Detection) sensor has provided receiver operating characteristic curves (probability of detection or Pd versus false alarm rate or FAR) that routinely set the mark for such devices. Since its inception and type-classification in 2003 as the US (United States) Army standard, the desire for use of the AN/PSS-14 against alternate threats - such as bulk explosives - has recently become paramount. To this end, L-3 CyTerra has developed and tested bulk explosive detection and discrimination algorithms using only the Stepped Frequency Continuous Wave (SFCW) Ground Penetrating Radar (GPR) portion of the system, versus the fused version that is used to optimally detect land mines. Performance of the new bulk explosive algorithm against representative zero-metal bulk explosive target and clutter emplacements is depicted, with the utility to the operator also described.

NQR: From imaging to explosives and drugs detection

NASA Astrophysics Data System (ADS)

Osán, Tristán M.; Cerioni, Lucas M. C.; Forguez, José; Ollé, Juan M.; Pusiol, Daniel J.

2007-02-01

The main aim of this work is to present an overview of the nuclear quadrupole resonance (NQR) spectroscopy capabilities for solid state imaging and detection of illegal substances, such as explosives and drugs. We briefly discuss the evolution of different NQR imaging techniques, in particular those involving spatial encoding which permit conservation of spectroscopic information. It has been shown that plastic explosives and other forbidden substances cannot be easily detected by means of conventional inspection techniques, such as those based on conventional X-ray technology. For this kind of applications, the experimental results show that the information inferred from NQR spectroscopy provides excellent means to perform volumetric and surface detection of dangerous explosive and drug compounds.

Design of an explosive detection system using Monte Carlo method.

PubMed

Hernández-Adame, Pablo Luis; Medina-Castro, Diego; Rodriguez-Ibarra, Johanna Lizbeth; Salas-Luevano, Miguel Angel; Vega-Carrillo, Hector Rene

2016-11-01

Regardless the motivation terrorism is the most important risk for the national security in many countries. Attacks with explosives are the most common method used by terrorists. Therefore several procedures to detect explosives are utilized; among these methods are the use of neutrons and photons. In this study the Monte Carlo method an explosive detection system using a 241 AmBe neutron source was designed. In the design light water, paraffin, polyethylene, and graphite were used as moderators. In the work the explosive RDX was used and the induced gamma rays due to neutron capture in the explosive was estimated using NaI(Tl) and HPGe detectors. When light water is used as moderator and HPGe as the detector the system has the best performance allowing distinguishing between the explosive and urea. For the final design the Ambient dose equivalent for neutrons and photons were estimated along the radial and axial axis. Copyright © 2016 Elsevier Ltd. All rights reserved.

75 FR 5345 - Agency Information Collection Activities: Proposed Collection; Comments Requested

Federal Register 2010, 2011, 2012, 2013, 2014

2010-02-02

... of information collection under review: Statement of Process-Marking of Plastic Explosives for the... Process-Marking of Plastic Explosives for the Purpose of Detection. (3) Agency form number, if any, and... Public Law 104- 132. This information will be used to ensure that plastic explosives contain a detection...

Analysis of different materials subjected to open-air explosions in search of explosive traces by Raman microscopy.

PubMed

Zapata, Félix; García-Ruiz, Carmen

2017-06-01

Post-explosion scenes offer such chaos and destruction that evidence recovery and detection of post-blast residues from the explosive in the surrounding materials is highly challenging and difficult. The suitability of materials to retain explosives residues and their subsequent analysis has been scarcely investigated. Particularly, the use of explosive mixtures containing inorganic oxidizing salts to make improvised explosive devices (IEDs) is a current security concern due to their wide availability and lax control. In this work, a wide variety of materials such as glass, steel, plywood, plastic bag, brick, cardboard or cotton subjected to open-air explosions were examined using confocal Raman microscopy, aiming to detect the inorganic oxidizing salts contained in explosives as black powder, chloratite, dynamite, ammonium nitrate fuel oil and ammonal. Post-blast residues were detected through microscopic examination of materials surfaces. In general, the more homogeneous and smoother the surface was, the less difficulties and better results in terms of identification were obtained. However, those highly irregular surfaces were the most unsuitable collectors for the posterior identification of explosive traces by Raman microscopy. The findings, difficulties and some recommendations related to the identification of post-blast particles in the different materials studied are thoroughly discussed. Copyright © 2017 Elsevier B.V. All rights reserved.

Design and validation of inert homemade explosive simulants for X-ray-based inspection systems

NASA Astrophysics Data System (ADS)

Faust, Anthony A.; Nacson, Sabatino; Koffler, Bruce; Bourbeau, Éric; Gagne, Louis; Laing, Robin; Anderson, C. J.

2014-05-01

Transport Canada (TC), the Canadian Armed Forces, and other public security agencies have an interest in the assessment of the potential utility of advanced explosives detection technologies to aid in the detection and interdiction of commercial grade, military grade, and homemade or improvised explosives (HME or IE). The availability of suitable, non-hazardous, non-toxic, explosive simulants is of concern when assessing the potential utility of such detection systems. Lack of simulants limits the training opportunities, and ultimately the detection probability, of security personnel using these systems. While simulants for commercial and military grade explosives are available for a wide variety of detection technologies, the design and production of materials to simulate improvised explosives has not kept pace with this emerging threat. Funded by TC and the Canadian Safety and Security Program, Defence Research and Development Canada (DRDC), Visiontec Systems, and Optosecurity engaged in an effort to develop inert, non-toxic Xray interrogation simulants for IE materials such as ammonium nitrate, potassium chlorate, and triacetone triperoxide. These simulants were designed to mimic key X-ray interrogation-relevant material properties of real improvised explosives, principally their bulk density and effective atomic number. Different forms of the simulants were produced and tested, simulating the different explosive threat formulations that could be encountered by front line security workers. These simulants comply with safety and stability requirements, and as best as possible match form and homogeneity. This paper outlines the research program, simulant design, and validation.

Apparatus and methods for real-time detection of explosives devices

DOEpatents

Blackburn, Brandon W [Idaho Falls, ID; Hunt, Alan W [Pocatello, ID; Chichester, David L [Idaho Falls, ID

2014-01-07

The present disclosure relates, according to some embodiments, to apparatus, devices, systems, and/or methods for real-time detection of a concealed or camouflaged explosive device (e.g., EFPs and IEDs) from a safe stand-off distance. Apparatus, system and/or methods of the disclosure may also be operable to identify and/or spatially locate and/or detect an explosive device. An apparatus or system may comprise an x-ray generator that generates high-energy x-rays and/or electrons operable to contact and activate a metal comprised in an explosive device from a stand-off distance; and a detector operable to detect activation of the metal. Identifying an explosive device may comprise detecting characteristic radiation signatures emitted by metals specific to an EFP, an IED or a landmine. Apparatus and systems of the disclosure may be mounted on vehicles and methods of the disclosure may be performed while moving in the vehicle and from a safe stand-off distance.

Mass spectrometry detection and imaging of inorganic and organic explosive device signatures using desorption electro-flow focusing ionization.

PubMed

Forbes, Thomas P; Sisco, Edward

2014-08-05

We demonstrate the coupling of desorption electro-flow focusing ionization (DEFFI) with in-source collision induced dissociation (CID) for the mass spectrometric (MS) detection and imaging of explosive device components, including both inorganic and organic explosives and energetic materials. We utilize in-source CID to enhance ion collisions with atmospheric gas, thereby reducing adducts and minimizing organic contaminants. Optimization of the MS signal response as a function of in-source CID potential demonstrated contrasting trends for the detection of inorganic and organic explosive device components. DEFFI-MS and in-source CID enabled isotopic and molecular speciation of inorganic components, providing further physicochemical information. The developed system facilitated the direct detection and chemical mapping of trace analytes collected with Nomex swabs and spatially resolved distributions within artificial fingerprints from forensic lift tape. The results presented here provide the forensic and security sectors a powerful tool for the detection, chemical imaging, and inorganic speciation of explosives device signatures.

Laser-based standoff detection of surface-bound explosive chemicals

NASA Astrophysics Data System (ADS)

Huestis, David L.; Smith, Gregory P.; Oser, Harald

2010-04-01

Avoiding or minimizing potential damage from improvised explosive devices (IEDs) such as suicide, roadside, or vehicle bombs requires that the explosive device be detected and neutralized outside its effective blast radius. Only a few seconds may be available to both identify the device as hazardous and implement a response. As discussed in a study by the National Research Council, current technology is still far from capable of meeting these objectives. Conventional nitrocarbon explosive chemicals have very low vapor pressures, and any vapors are easily dispersed in air. Many pointdetection approaches rely on collecting trace solid residues from dust particles or surfaces. Practical approaches for standoff detection are yet to be developed. For the past 5 years, SRI International has been working toward development of a novel scheme for standoff detection of explosive chemicals that uses infrared (IR) laser evaporation of surfacebound explosive followed by ultraviolet (UV) laser photofragmentation of the explosive chemical vapor, and then UV laser-induced fluorescence (LIF) of nitric oxide. This method offers the potential of long standoff range (up to 100 m or more), high sensitivity (vaporized solid), simplicity (no spectrometer or library of reference spectra), and selectivity (only nitrocompounds).

Multichannel Discriminative Detection of Explosive Vapors with an Array of Nanofibrous Membranes Loaded with Quantum Dots.

PubMed

Wu, Zhaofeng; Duan, Haiming; Li, Zhijun; Guo, Jixi; Zhong, Furu; Cao, Yali; Jia, Dianzeng

2017-11-20

The multichannel fluorescent sensor array based on nanofibrous membranes loaded with ZnS quantum dots (QDs) was created and demonstrated for the discriminative detection of explosives. The synergistic effect of the high surface-to-volume ratio of QDs, the good permeability of nanofibrous membranes and the differential response introduced by surface ligands was played by constructing the sensing array using nanofibrous membranes loaded with ZnS QDs featuring several surface ligands. Interestingly, although the fluorescence quenching of the nanofibrous membranes is not linearly related to the exposure time, the fingerprint of each explosive at different times is very similar in shape, and the fingerprints of the three explosives show different shapes. Three saturated vapors of nitroaromatic explosives could be reliably detected and discriminated by the array at room temperature. This work is the first step toward devising a monitoring system for explosives in the field of public security and defense. It could, for example, be coupled with the technology of image recognition and large data analysis for a rapid diagnostic test of explosives. This work further highlights the power of differential, multichannel arrays for the rapid and discriminative detection of a wide range of chemicals.

Multichannel Discriminative Detection of Explosive Vapors with an Array of Nanofibrous Membranes Loaded with Quantum Dots

PubMed Central

Wu, Zhaofeng; Duan, Haiming; Li, Zhijun; Guo, Jixi; Zhong, Furu; Cao, Yali; Jia, Dianzeng

2017-01-01

The multichannel fluorescent sensor array based on nanofibrous membranes loaded with ZnS quantum dots (QDs) was created and demonstrated for the discriminative detection of explosives. The synergistic effect of the high surface-to-volume ratio of QDs, the good permeability of nanofibrous membranes and the differential response introduced by surface ligands was played by constructing the sensing array using nanofibrous membranes loaded with ZnS QDs featuring several surface ligands. Interestingly, although the fluorescence quenching of the nanofibrous membranes is not linearly related to the exposure time, the fingerprint of each explosive at different times is very similar in shape, and the fingerprints of the three explosives show different shapes. Three saturated vapors of nitroaromatic explosives could be reliably detected and discriminated by the array at room temperature. This work is the first step toward devising a monitoring system for explosives in the field of public security and defense. It could, for example, be coupled with the technology of image recognition and large data analysis for a rapid diagnostic test of explosives. This work further highlights the power of differential, multichannel arrays for the rapid and discriminative detection of a wide range of chemicals. PMID:29156627

Performance comparison of single and dual-excitation-wavelength resonance-Raman explosives detectors

NASA Astrophysics Data System (ADS)

Yellampalle, Balakishore; Martin, Robert; Witt, Kenneth; McCormick, William; Wu, Hai-Shan; Sluch, Mikhail; Ice, Robert; Lemoff, Brian

2017-05-01

Deep-ultraviolet Raman spectroscopy is a very useful approach for standoff detection of explosive traces. Using two simultaneous excitation wavelengths improves the specificity and sensitivity to standoff explosive detection. The High Technology Foundation developed a highly compact prototype of resonance Raman explosives detector. In this work, we discuss the relative performance of a dual-excitation sensor compared to a single-excitation sensor. We present trade space analysis comparing three representative Raman systems with similar size, weight, and power. The analysis takes into account, cost, spectral resolution, detection/identification time and the overall system benefit.

Detection of Explosives Using Differential Laser-Induced Perturbation Spectroscopy with a Raman-based Probe.

PubMed

Oztekin, Erman K; Burton, Dallas J; Hahn, David W

2016-04-01

Explosives detection is carried out with a novel spectral analysis technique referred to as differential laser-induced perturbation spectroscopy (DLIPS) on thin films of TNT, RDX, HMX, and PETN. The utility of Raman spectroscopy for detection of explosives is enhanced by inducing deep ultraviolet laser perturbation on molecular structures in combination with a differential Raman sensing scheme. Principal components analysis (PCA) is used to quantify the DLIPS method as benchmarked against a traditional Raman scattering probe, and the related photo-induced effects on the molecular structure of the targeted explosives are discussed in detail. Finally, unique detection is observed with TNT samples deposited on commonly available background substrates of nylon and polyester. Overall, the data support DLIPS as a noninvasive method that is promising for screening explosives in real-world environments and backgrounds. © The Author(s) 2016.

Atmospheric Pressure Chemical Ionization Sources Used in The Detection of Explosives by Ion Mobility Spectrometry

DOE Office of Scientific and Technical Information (OSTI.GOV)

Waltman, Melanie J.

2010-05-01

Explosives detection is a necessary and wide spread field of research. From large shipping containers to airline luggage, numerous items are tested for explosives every day. In the area of trace explosives detection, ion mobility spectrometry (IMS) is the technique employed most often because it is a quick, simple, and accurate way to test many items in a short amount of time. Detection by IMS is based on the difference in drift times of product ions through the drift region of an IMS instrument. The product ions are created when the explosive compounds, introduced to the instrument, are chemically ionizedmore » through interactions with the reactant ions. The identity of the reactant ions determines the outcomes of the ionization process. This research investigated the reactant ions created by various ionization sources and looked into ways to manipulate the chemistry occurring in the sources.« less

A Measurement Technique to Determine the Sensitivity of Trained Dogs to Explosive Vapor Concentration

DOE Office of Scientific and Technical Information (OSTI.GOV)

Reaugh, J E; Kury, J W

2002-04-02

Over the years canines have been used successfully to detect explosives. However, exactly what a canine detects in the many thousands of explosive formulations available is still not well understood. LLNL and Bureau of Alcohol, Tobacco and Firearms (BATF) studies over the past four years are beginning to provide better insight into this complex problem. One area that has been addressed is how low a molecular concentration of nitromethane explosive can a canine detect. Forty-one canine/handler teams were used in four test series with arrays containing dilute nitromethane-in-water solutions. (The canines had been trained on the amount of nitromethane vapormore » in equilibrium with the undiluted liquid explosive.) By diluting liquid nitromethane with water, the amount of explosive vapor can be reduced many orders of magnitude to test the lower limit of the canine's nitromethane vapor detection response. The results are summarized in the table in Appendix A. The probability of detecting nitromethane remained high until the vapor pressure fell below {approx} 1 x 10{sup 6} microns (one nitromethane molecule in a trillion nitrogen, oxygen and water molecules). This report describes a new approach to measuring this lower limit of detection using the diffusion of nitromethane in various length tubes containing air.« less

Development of a technique using MCNPX code for determination of nitrogen content of explosive materials using prompt gamma neutron activation analysis method

NASA Astrophysics Data System (ADS)

Nasrabadi, M. N.; Bakhshi, F.; Jalali, M.; Mohammadi, A.

2011-12-01

Nuclear-based explosive detection methods can detect explosives by identifying their elemental components, especially nitrogen. Thermal neutron capture reactions have been used for detecting prompt gamma 10.8 MeV following radioactive neutron capture by 14N nuclei. We aimed to study the feasibility of using field-portable prompt gamma neutron activation analysis (PGNAA) along with improved nuclear equipment to detect and identify explosives, illicit substances or landmines. A 252Cf radio-isotopic source was embedded in a cylinder made of high-density polyethylene (HDPE) and the cylinder was then placed in another cylindrical container filled with water. Measurements were performed on high nitrogen content compounds such as melamine (C3H6N6). Melamine powder in a HDPE bottle was placed underneath the vessel containing water and the neutron source. Gamma rays were detected using two NaI(Tl) crystals. The results were simulated with MCNP4c code calculations. The theoretical calculations and experimental measurements were in good agreement indicating that this method can be used for detection of explosives and illicit drugs.

USING CANINES IN SOURCE DETECTION OF INDOOR AIR POLLUTANTS EPA SCIENCE FORUM

EPA Science Inventory

Scent detection dogs have been used extensively in law enforcement and military applications to detect narcotics and explosives for over thirty years. Controlled laboratory studies have documented accurate detection by dogs of specific compounds associated with explosives and nar...

Interpenetrated Binary Supramolecular Nanofibers for Sensitive Fluorescence Detection of Six Classes of Explosives.

PubMed

Xiong, Wei; Zhu, Qijian; Gong, Yanjun; Wang, Chen; Che, Yanke; Zhao, Jincai

2018-04-03

In this work, we develop a sequential self-assembly approach to fabricate interpenetrated binary supramolecular nanofibers consisting of carbazole oligomer 1-cobalt(II) (1-Co 2+ ) coordination nanofibers and oligomer 2 nanofibers for the sensitive detection of six classes of explosives. When exposed to peroxide explosives (e.g., H 2 O 2 ), Co 2+ in 1-Co 2+ coordination nanofibers can be reduced to Co + that can transfer an electron to the excited 2 nanofibers and thereby quench their fluorescence. On the other hand, when exposed to the other five classes of explosives, the excited 2 nanofibers can transfer an electron to explosives to quench their fluorescence. On the basis of the distinct fluorescence quenching mechanisms, six classes of explosives can be sensitively detected. Herein, we provide a new strategy to design broad-band fluorescence sensors for a rich identification of threats.

Progressing the analysis of Improvised Explosive Devices: Comparative study for trace detection of explosive residues in handprints by Raman spectroscopy and liquid chromatography.

PubMed

Zapata, Félix; de la Ossa, Mª Ángeles Fernández; Gilchrist, Elizabeth; Barron, Leon; García-Ruiz, Carmen

2016-12-01

Concerning the dreadful global threat of terrorist attacks, the detection of explosive residues in biological traces and marks is a current need in both forensics and homeland security. This study examines the potential of Raman microscopy in comparison to liquid chromatography (ion chromatography (IC) and reversed-phase high performance liquid chromatography (RP-HPLC)) to detect, identify and quantify residues in human handmarks of explosives and energetic salts commonly used to manufacture Improvised Explosive Devices (IEDs) including dynamite, ammonium nitrate, single- and double-smokeless gunpowders and black powder. Dynamite, ammonium nitrate and black powder were detected through the identification of the energetic salts by Raman spectroscopy, their respective anions by IC, and organic components by RP-HPLC. Smokeless gunpowders were not detected, either by Raman spectroscopy or the two liquid chromatography techniques. Several aspects of handprint collection, sample treatment and a critical comparison of the identification of compounds by both techniques are discussed. Raman microscopy and liquid chromatography were shown to be complementary to one another offering more comprehensive information for trace explosives analysis. Copyright © 2016 Elsevier B.V. All rights reserved.

Standoff detection of explosive substances at distances of up to 150 m.

PubMed

Mukherjee, Anadi; Von der Porten, Steven; Patel, C Kumar N

2010-04-10

We report detection and identification of trace quantities of explosives at standoff distances up to 150 m with high sensitivity (signal-to-noise ratio of approximately 70) and high selectivity. The technique involves illuminating the target object with laser radiation at a wavelength that is strongly absorbed by the target. The resulting temperature rise is observed by remotely monitoring the increased blackbody radiation from the sample. An unambiguous determination of the target, TNT, in soil samples collected from an explosives test site in China Lake Naval Air Weapons Station is achieved through the use of a tunable CO(2) laser that scans over the absorption fingerprint of the target explosives. The theoretical analysis supports the observation and indicates that, with optimized detectors and data processing algorithms, the measurement capability can be improved significantly, permitting rapid standoff detection of explosives at distances approaching 1 km. The detection sensitivity varies as R(-2) and, thus, with the availability of high power, room-temperature, tunable mid-wave infrared and long-wave infrared quantum cascade lasers, this technology may play an important role in screening personnel and their belongings at short distances, such as in airports, for detecting and identifying explosives material residue on persons.

Multi-dimensional simulations of core-collapse supernova explosions with CHIMERA

NASA Astrophysics Data System (ADS)

Messer, O. E. B.; Harris, J. A.; Hix, W. R.; Lentz, E. J.; Bruenn, S. W.; Mezzacappa, A.

2018-04-01

Unraveling the core-collapse supernova (CCSN) mechanism is a problem that remains essentially unsolved despite more than four decades of effort. Spherically symmetric models with otherwise high physical fidelity generally fail to produce explosions, and it is widely accepted that CCSNe are inherently multi-dimensional. Progress in realistic modeling has occurred recently through the availability of petascale platforms and the increasing sophistication of supernova codes. We will discuss our most recent work on understanding neutrino-driven CCSN explosions employing multi-dimensional neutrino-radiation hydrodynamics simulations with the Chimera code. We discuss the inputs and resulting outputs from these simulations, the role of neutrino radiation transport, and the importance of multi-dimensional fluid flows in shaping the explosions. We also highlight the production of 48Ca in long-running Chimera simulations.

Detection of nitro-based and peroxide-based explosives by fast polarity-switchable ion mobility spectrometer with ion focusing in vicinity of Faraday detector.

PubMed

Zhou, Qinghua; Peng, Liying; Jiang, Dandan; Wang, Xin; Wang, Haiyan; Li, Haiyang

2015-05-29

Ion mobility spectrometer (IMS) has been widely deployed for on-site detection of explosives. The common nitro-based explosives are usually detected by negative IMS while the emerging peroxide-based explosives are better detected by positive IMS. In this study, a fast polarity-switchable IMS was constructed to detect these two explosive species in a single measurement. As the large traditional Faraday detector would cause a trailing reactant ion peak (RIP), a Faraday detector with ion focusing in vicinity was developed by reducing the detector radius to 3.3 mm and increasing the voltage difference between aperture grid and its front guard ring to 591 V, which could remove trailing peaks from RIP without loss of signal intensity. This fast polarity-switchable IMS with ion focusing in vicinity of Faraday detector was employed to detect a mixture of 10 ng 2,4,6-trinitrotoluene (TNT) and 50 ng hexamethylene triperoxide diamine (HMTD) by polarity-switching, and the result suggested that [TNT-H](-) and [HMTD+H](+) could be detected in a single measurement. Furthermore, the removal of trailing peaks from RIP by the Faraday detector with ion focusing in vicinity also promised the accurate identification of KClO4, KNO3 and S in common inorganic explosives, whose product ion peaks were fairly adjacent to RIP.

ENVIRONMENTAL TECHNOLOGY VERIFICATION REPORT, EXPLOSIVES DETECTION TECHNOLOGY, SRI INSTRUMENTS, MODEL 8610C, GAS CHROMATOGRAPH/THERMIONIC IONIZATION DETECTION

EPA Science Inventory

The SRI Model 86 1 OC gas chromatograph (GC) is a transportable instrument that can provide on-site analysis of soils for explosives. Coupling this transportable gas chromatograph with a thermionic ionization detector (TID) allows for the determination of explosives in soil matri...

78 FR 26655 - Agency Information Collection Activities; Proposed Collection; Comments Requested: Statement of...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-05-07

...-Marking of Plastic Explosives for the Purpose of Detection ACTION: 30-Day notice. The Department of...) Title of the Form/Collection: Statement of Process-Marking of Plastic Explosives for the Purpose of... used to ensure that plastic explosives contain a detection agent as required by law. (5) An estimate of...

Explosives tester with heater

DOEpatents

Del Eckels, Joel [Livermore, CA; Nunes, Peter J [Danville, CA; Simpson, Randall L [Livermore, CA; Whipple, Richard E [Livermore, CA; Carter, J Chance [Livermore, CA; Reynolds, John G [San Ramon, CA

2010-08-10

An inspection tester system for testing for explosives. The tester includes a body and a swab unit adapted to be removeably connected to the body. At least one reagent holder and dispenser is operatively connected to the body. The reagent holder and dispenser contains an explosives detecting reagent and is positioned to deliver the explosives detecting reagent to the swab unit. A heater is operatively connected to the body and the swab unit is adapted to be operatively connected to the heater.

Detection of explosives by positive corona discharge ion mobility spectrometry.

PubMed

Tabrizchi, Mahmoud; Ilbeigi, Vahideh

2010-04-15

In this work, thermal decomposition has been used to detect explosives by IMS in positive polarity. Explosives including Pentaerythritol Tetranitrate (PETN), Cyclo-1,3,5-Trimethylene-2,4,6-Trinitramine (RDX), 2,4,6-Trinitrotoluene (TNT), 2,4-Dihydro-5-nitro-3H-1,2,4-triazol-3-one (NTO), 1,3,5,7-Tetranitro-1,3,5,7-tetrazocine (HMX), have been evaluated at temperatures between 150 and 250 degrees C in positive polarity in air. Explosives yield NO(x) which causes NO(+) peak to increase. Additional peaks may be used to identify the type of explosive. The limit of detection for RDX, HMX, PETN, NTO, and TNT were obtained to be 1, 10, 40, 1000, and 1000 ng, respectively. 2009 Elsevier B.V. All rights reserved.

Calibration methods for explosives detectors

NASA Astrophysics Data System (ADS)

MacDonald, Stephen J.; Rounbehler, David P.

1992-05-01

Airport security has become an important concern to cultures in every corner of the world. Presently, efforts to improve airport security have brought additional technological solutions, in the form of advanced instrumentation for the detection of explosives, into use at airport terminals in many countries. This new generation of explosives detectors is often used to augment existing security measures and provide a more encompassing screening capability for airline passengers. This paper describes two calibration procedures used for the Thermedics' EGIS explosives detectors. The systems were designed to screen people, electronic components, luggage, automobiles, and other objects for the presence of concealed explosives. The detectors have the ability to detect a wide range of explosives in both the vapor state or as surface adsorbed solids, therefore, calibrations were designed to challenge the system with explosives in each form.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Park, Seong-Wook; Tian, Chao; Martini, Rainer, E-mail: rmartini@stevens.edu

We demonstrated highly sensitive detection of explosive dissolved in solvent with a portable spectroscopy system (Q-MACS) by tracing the explosive byproduct, N{sub 2}O, in combination with a pulsed electric discharge system for safe explosive decomposition. Using Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), the gas was monitored and analyzed by Q-MACS and the presence of the dissolved explosive clearly detected. While HMX presence could be identified directly in the air above the solutions even without plasma, much better results were achieved under the decomposition. The experiment results give an estimated detection limit of 10 ppb, which corresponds to a 15 pg of HMX.

Observations on military exploitation of explosives detection technologies

NASA Astrophysics Data System (ADS)

Faust, Anthony A.; de Ruiter, C. J.; Ehlerding, Anneli; McFee, John E.; Svinsås, Eirik; van Rheenen, Arthur D.

2011-06-01

Accurate and timely detection of explosives, energetic materials, and their associated compounds would provide valuable information to military commanders in a wide range of military operations: protection of fast moving convoys from mobile or static IED threats; more deliberate countermine and counter-IED operations during route or area clearance; and static roles such as hasty or deliberate checkpoints, critical infrastructure protection and support to public security. The detection of hidden explosive hazards is an extremely challenging problem, as evidenced by the fact that related research has been ongoing in many countries for at least seven decades and no general purpose solution has yet been found. Technologies investigated have spanned all major scientific fields, with emphasis on the physical sciences, life sciences, engineering, robotics, computer technology and mathematics. This paper will present a limited, operationally-focused overview of the current status of detection technologies. Emphasis will be on those technologies that directly detect the explosive hazard, as opposed to those that detect secondary properties of the threat, such as the casing, associated wires or electronics. Technologies that detect explosives include those based on nuclear radiation and terahertz radiation, as well as trace and biological detection techniques. Current research areas of the authors will be used to illustrate the practical applications.

Sub-Nanogram Detection of RDX Explosive by Monoclonal Antibodies.

PubMed

Ulaeto, David O; Hutchinson, Alistair P; Nicklin, Stephen

2015-08-01

Polyclonal and monoclonal antibodies were raised to protein carrier molecules haptenized with RDX, a major component of many plastic explosives including Semtex. Sera from immunized mice detected RDX protein conjugates in standard ELISA. Clonally purified monoclonal antibodies had detection limits in the sub-ng/mL range for underivatized RDX in competition ELISA. The monoclonal antibodies are not dependent on the presence of taggants added during the manufacturing process, and are likely to have utility in the detection of any explosive containing RDX, or RDX contamination of environmental sites.

Sub-Nanogram Detection of RDX Explosive by Monoclonal Antibodies

PubMed Central

Hutchinson, Alistair P.; Nicklin, Stephen

2015-01-01

Polyclonal and monoclonal antibodies were raised to protein carrier molecules haptenized with RDX, a major component of many plastic explosives including Semtex. Sera from immunized mice detected RDX protein conjugates in standard ELISA. Clonally purified monoclonal antibodies had detection limits in the sub-ng/mL range for underivatized RDX in competition ELISA. The monoclonal antibodies are not dependent on the presence of taggants added during the manufacturing process, and are likely to have utility in the detection of any explosive containing RDX, or RDX contamination of environmental sites. PMID:26252765

Fluorescence quenching as an indirect detection method for nitrated explosives.

PubMed

Goodpaster, J V; McGuffin, V L

2001-05-01

A novel approach based on fluorescence quenching is presented for the analysis of nitrated explosives. Seventeen common explosives and their degradation products are shown to be potent quenchers of pyrene, having Stern-Volmer constants that generally increase with the degree of nitration. Aromatic explosives such as 2,4,6-trinitrotoluene (2,4,6-TNT) are more effective quenchers than aliphatic or nitramine explosives. In addition, nitroaromatic explosives are found to have unique interactions with pyrene that lead to a wavelength dependence of their Stern-Volmer constants. This phenomenon allows for their differentiation from other nitrated explosives. The fluorescence quenching method is then applied to the determination of hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazine(HMX), 2,4,6-TNT, nitromethane, and ammonium nitrate in various commercial explosive samples. The samples are separated by capillary liquid chromatography with post-column addition of the pyrene solution and detection by laser-induced fluorescence. The indirect fluorescence quenching method shows increased sensitivity and selectivity over traditional UV-visible absorbance as well as the ability to detect a wider range of organic and inorganic nitrated compounds.

27 CFR 555.180 - Prohibitions relating to unmarked plastic explosives.

Code of Federal Regulations, 2010 CFR

2010-04-01

... unmarked plastic explosives. 555.180 Section 555.180 Alcohol, Tobacco Products, and Firearms BUREAU OF... Marking of Plastic Explosives § 555.180 Prohibitions relating to unmarked plastic explosives. (a) No person shall manufacture any plastic explosive that does not contain a detection agent. (b) No person...

Transport of explosives I: TNT in soil and its equilibrium vapor

NASA Astrophysics Data System (ADS)

Baez, Bibiana; Correa, Sandra N.; Hernandez-Rivera, Samuel P.; de Jesus, Maritza; Castro, Miguel E.; Mina, Nairmen; Briano, Julio G.

2004-09-01

Landmine detection is an important task for military operations and for humanitarian demining. Conventional methods for landmine detection involve measurements of physical properties. Several of these methods fail on the detection of modern mines with plastic enclosures. Methods based on the detection signature explosives chemicals such as TNT and DNT are specific to landmines and explosive devices. However, such methods involve the measurements of the vapor trace, which can be deceiving of the actual mine location because of the complex transport phenomena that occur in the soil neighboring the buried landmine. We report on the results of the study of the explosives subject to similar environmental conditions as the actual mines. Soil samples containing TNT were used to study the effects of aging, temperature and moisture under controlled conditions. The soil used in the investigation was Ottawa sand. A JEOL GCMate II gas chromatograph +/- mass spectrometer coupled to a Tunable Electron Energy Monochromator (TEEM-GC/MS) was used to develop the method of analysis of explosives under enhanced detection conditions. Simultaneously, a GC with micro cell 63Ni, Electron Capture Detector (μECD) was used for analysis of TNT in sand. Both techniques were coupled with Solid-Phase Micro Extraction (SPME) methodology to collect TNT doped sand samples. The experiments were done in both, headspace and immersion modes of SPME for sampling of explosives. In the headspace experiments it was possible to detect appreciable TNT vapors as early as 1 hour after of preparing the samples, even at room temperature (20 °C). In the immersion experiments, I-SPME technique allowed for the detection of concentrations as low as 0.010 mg of explosive per kilogram of soil.

Detection of an explosive simulant via electrical impedance spectroscopy utilizing the UiO-66-NH2 metal-organic framework.

PubMed

Peterson, G W; McEntee, M; Harris, C R; Klevitch, A D; Fountain, A W; Soliz, J R; Balboa, A; Hauser, A J

2016-11-01

Electrical impedance spectroscopy, in conjunction with the metal-organic framework (MOF) UiO-66-NH 2 , is used to detect trace levels of the explosive simulant 2,6-dinitrotoluene. The combination of porosity and functionality of the MOF provides an effective dielectric structure, resulting in changes of impedance magnitude and phase angle. The promising data indicate that MOFs may be used in low-cost, robust explosive detection devices.

Novel laser induced photoacoustic spectroscopy for instantaneous trace detection of explosive materials.

PubMed

El-Sharkawy, Yasser H; Elbasuney, Sherif

2017-08-01

Laser photoacoustic spectroscopy (LPAS) is an attractive technology in terms of simplicity, ruggedness, and overall sensitivity; it detects the time dependent heat generated (thermo-elastic effect) in the target via interaction with pulsed optical radiation. This study reports on novel LPAS technique that offers instant and standoff detection capabilities of trace explosives. Over the current study, light is generated using pulsed Q-switched Nd:YAG laser; the generated photoacoustic response in stimulated explosive material offers signature values that depend on the optical, thermal, and acoustical properties. The generated acoustic waves were captured using piezoelectric transducer as well as novel customized optical sensor with remotely laser interferometer probe. A digital signal processing algorithm was employed to identify explosive material signatures via calculation of characteristic optical properties (absorption coefficient), sound velocity, and frequency response of the generated photoacoustic signal. Customized LPAS technique was employed for instantaneous trace detection of three main different high explosive materials including TNT, RDX, and HMX. The main outcome of this study is that the novel customized optical sensor signals were validated with traditional piezoelectric transducer. Furthermore, the customized optical sensor offered standoff detection capabilities (10cm), fast response, high sensitivity, and enhanced signal to noise ratio. This manuscript shaded the light on the instant detection of trace explosive materials from significant standoffs using novel customized LPAS technique. Copyright © 2017 Elsevier B.V. All rights reserved.

Deterrence of ballistic missile systems and their effects on today's air operations

NASA Astrophysics Data System (ADS)

Durak, Hasan

2015-05-01

Lately, the effect-based approach has gained importance in executing air operations. Thus, it makes more successful in obtaining the desired results by breaking the enemy's determination in a short time. Air force is the first option to be chosen in order to defuse the strategic targets. However, the problems such as the defense of targets and country, radars, range…etc. becoming serious problems. At this level ballistic missiles emerge as a strategic weapon. Ultimate emerging technologies guided by the INS and GPS can also be embedded with multiple warheads and reinforced with conventional explosive, ballistic missiles are weapons that can destroy targets with precision. They have the advantage of high speed, being easily launched from every platform and not being easily detected by air defense systems contrary to other air platforms. While these are the advantages, there are also disadvantages of the ballistic missiles. The high cost, unavailability of nuclear, biological and chemical weapons, and its limited effect while using conventional explosives against destroying the fortified targets are the disadvantages. The features mentioned above should be considered as limitation to the impact of the ballistic missiles. The aim is to impose the requests on enemies without starting a war with all components and to ensure better implementation of the operation functions during the air operations. In this study, effects of ballistic missiles in the future on air battle theatre will be discussed in the beginning, during the process and at the end phase of air operations within the scope of an effect-based approach.

Detection and identification of explosive particles in fingerprints using attenuated total reflection-Fourier transform infrared spectromicroscopy.

PubMed

Mou, Yongyan; Rabalais, J Wayne

2009-07-01

The application of attenuated total reflection (ATR)-Fourier transform infrared (FTIR) spectromicroscopy for detection of explosive particles in fingerprints is described. The combined functions of ATR-FTIR spectromicroscopy are visual searching of particles in fingerprints and measuring the FTIR spectra of the particles. These functions make it possible to directly identify whether a suspect has handled explosives from the fingerprints alone. Particles in explosive contaminated fingerprints are either ingredients of the explosives, finger residues, or other foreign materials. These cannot normally be discriminated by their morphology alone. ATR-FTIR spectra can provide both particle morphology and composition. Fingerprints analyzed by ATR-FTIR can be used for further analysis and identification because of its non-destructive character. Fingerprints contaminated with three different types of explosives, or potential explosives, have been analyzed herein. An infrared spectral library was searched in order to identify the explosive residues. The acquired spectra are compared to those of finger residue alone, in order to differentiate such residue from explosive residue.

An automatic detection software for differential reflection spectroscopy

NASA Astrophysics Data System (ADS)

Yuksel, Seniha Esen; Dubroca, Thierry; Hummel, Rolf E.; Gader, Paul D.

2012-06-01

Recent terrorist attacks have sprung a need for a large scale explosive detector. Our group has developed differential reflection spectroscopy which can detect explosive residue on surfaces such as parcel, cargo and luggage. In short, broad band ultra-violet and visible light is shone onto a material (such as a parcel) moving on a conveyor belt. Upon reflection off the surface, the light intensity is recorded with a spectrograph (spectrometer in combination with a CCD camera). This reflected light intensity is then subtracted and normalized with the next data point collected, resulting in differential reflection spectra in the 200-500 nm range. Explosives show spectral finger-prints at specific wavelengths, for example, the spectrum of 2,4,6, trinitrotoluene (TNT) shows an absorption edge at 420 nm. Additionally, we have developed an automated software which detects the characteristic features of explosives. One of the biggest challenges for the algorithm is to reach a practical limit of detection. In this study, we introduce our automatic detection software which is a combination of principal component analysis and support vector machines. Finally we present the sensitivity and selectivity response of our algorithm as a function of the amount of explosive detected on a given surface.

Mobile TNA system to detect explosives and drugs concealed in cars and trucks

NASA Astrophysics Data System (ADS)

Bendahan, Joseph; Gozani, Tsahi

1998-12-01

The drug problem in the U.S. is serious and efforts to fight it are constrained by the lack of adequate means to curb the inflow of smuggled narcotics into the country through cargo containers. Also, events such as the disastrous explosion in Oklahoma City, the IRA bombing in London, and the bombing of the U.S. military residence in Dharan make the development of new tools for the detection of explosives and drugs in vehicles imperative. Thermal neutron analysis (TNA) technology, developed for the detection of explosives in suitcases, and detection of landmines and unexploded ordnance is presently being applied to the nonintrusive detection of significant amounts of explosives and drugs concealed in cars, trucks and large cargo containers. TNA technology is based on the analysis of characteristic gamma rays emitted following thermal neutron capture. A TNA system can be used in a variety of operational scenarios, such as inspection before an unloaded cargo container from a spit is moved to temporary storage, inspection of trucks unloaded from a ferry, or inspection of vehicles parked close to Federal building or military bases. This paper will discuss the detection process and operational scenarios, and will present results from recent simulations and measurements.

Detection of nitro-organic and peroxide explosives in latent fingermarks by DART- and SALDI-TOF-mass spectrometry.

PubMed

Rowell, Frederick; Seviour, John; Lim, Angelina Yimei; Elumbaring-Salazar, Cheryl Grace; Loke, Jason; Ma, Jan

2012-09-10

The ability of two mass spectrometric methods, surface-assisted laser desorption/ionization-time of flight-mass spectrometry (SALDI-TOF-MS) and direct analysis in real time (DART-MS), to detect the presence of seven common explosives (six nitro-organic- and one peroxide-type) in spiked latent fingermarks has been examined. It was found that each explosive could be detected with nanogram sensitivity for marks resulting from direct finger contact with a glass probe by DART-MS or onto stainless steel target plates using SALDI-TOF-MS for marks pre-dusted with one type of commercial black magnetic powder. These explosives also could be detected in latent marks lifted from six common surfaces (paper, plastic bag, metal drinks can, wood laminate, adhesive tape and white ceramic tile) whereas no explosive could be detected in equivalent pre-dusted marks on the surface of a commercial lifting tape by the DART-MS method due to high background interference from the tape material. The presence of TNT and Tetryl could be detected in pre-dusted latent fingermarks on a commercial lifting tape for up to 29 days sealed and stored under ambient conditions. Copyright © 2012 Elsevier Ireland Ltd. All rights reserved.

Multi-dimensional simulations of core-collapse supernova explosions with CHIMERA

DOE Office of Scientific and Technical Information (OSTI.GOV)

Messer, Bronson; Harris, James Austin; Hix, William Raphael

Unraveling the core-collapse supernova (CCSN) mechanism is a problem that remains essentially unsolved despite more than four decades of effort. Spherically symmetric models with otherwise high physical fidelity generally fail to produce explosions, and it is widely accepted that CCSNe are inherently multi-dimensional. Progress in realistic modeling has occurred recently through the availability of petascale platforms and the increasing sophistication of supernova codes. We will discuss our most recent work on understanding neutrino-driven CCSN explosions employing multi-dimensional neutrino-radiation hydrodynamics simulations with the Chimera code. We discuss the inputs and resulting outputs from these simulations, the role of neutrino radiation transport,more » and the importance of multi-dimensional fluid flows in shaping the explosions. We also highlight the production of 48Ca in long-running Chimera simulations.« less

Processing of Lewisite munitions in the explosive destruction system.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Shepodd, Timothy J.; Didlake, John E., Jr.; Bradshaw, Robert W., PhD

2005-03-01

The Explosive Destruction System (EDS) is a transportable system designed to treat chemical munitions. The EDS is transported on an open trailer that provides a mounting surface for major system components and an operator's work platform. The trailer is towed by a prime mover. An explosive containment vessel contains the shock, munition fragments, and the chemical agent during the munition opening process, and then provides a vessel for the subsequent chemical treatment of the agent. A fragmentation suppression system houses the chemical munition and protects the containment vessel from high velocity fragments. An explosive accessing system uses shaped charges tomore » cut the munition open and attack the burster. A firing system detonates the shaped charges. A chemical feed system supplies neutralizing reagents and water to the containment vessel. A waste handling system drains the treated effluent.« less

Idaho Explosive Detection System

ScienceCinema

Klinger, Jeff

2018-05-23

Learn how INL researchers are making the world safer by developing an explosives detection system that can inspect cargo. For more information about INL security research, visit http://www.facebook.com/idahonationallaboratory

Simulations of Si-PIN photodiode based detectors for underground explosives enhanced by ammonium nitrate

NASA Astrophysics Data System (ADS)

Yücel, Mete; Bayrak, Ahmet; Yücel, Esra Barlas; Ozben, Cenap S.

2018-02-01

Massive Ammonium Nitrate (NH4-NO3) based explosives buried underground are commonly used in terror attacks. These explosives can be detected using neutron scattering method with some limitations. Simulations are very useful tools for designing a possible detection system for these kind of explosives. Geant4 simulations were used for generating neutrons at 14 MeV energy and tracking them through the scattering off the explosive embedded in soil. Si-PIN photodiodes were used as detector elements in the design for their low costs and simplicity for signal readout electronics. Various neutron-charge particle converters were applied on to the surface of the photodiodes to increase the detection efficiency. Si-PIN photodiodes coated with 6LiF provided the best result for a certain energy interval. Energy depositions in silicon detector from all secondary particles generated including photons were taken into account to generate a realistic background. Humidity of soil, one of the most important parameter for limiting the detection, was also studied.

A Photoluminescence-Based Field Method for Detection of Traces of Explosives

PubMed Central

Menzel, E. Roland; Menzel, Laird W.; Schwierking, Jake R.

2004-01-01

We report a photoluminescence-based field method for detecting traces of explosives. In its standard version, the method utilizes a commercially available color spot test kit for treating explosive traces on filter paper after swabbing. The colored products are fluorescent under illumination with a laser that operates on three C-size flashlight batteries and delivers light at 532 nm. In the fluorescence detection mode, by visual inspection, the typical sensitivity gain is a factor of 100. The method is applicable to a wide variety of explosives. In its time-resolved version, intended for in situ work, explosives are tagged with europium complexes. Instrumentation-wise, the time-resolved detection, again visual, can be accomplished in facile fashion. The europium luminescence excitation utilizes a laser operating at 355 nm. We demonstrate the feasibility of CdSe quantum dot sensitization of europium luminescence for time-resolved purposes. This would allow the use of the above 532 nm laser. PMID:15349512

High-sensitivity explosives detection using dual-excitation-wavelength resonance-Raman detector

NASA Astrophysics Data System (ADS)

Yellampalle, Balakishore; McCormick, William B.; Wu, Hai-Shan; Sluch, Mikhail; Martin, Robert; Ice, Robert V.; Lemoff, Brian

2014-05-01

A key challenge for standoff explosive sensors is to distinguish explosives, with high confidence, from a myriad of unknown background materials that may have interfering spectral peaks. To meet this challenge a sensor needs to exhibit high specificity and high sensitivity in detection at low signal-to-noise ratio levels. We had proposed a Dual-Excitation- Wavelength Resonance-Raman Detector (DEWRRED) to address this need. In our previous work, we discussed various components designed at WVHTCF for a DEWRRED sensor. In this work, we show a completely assembled laboratory prototype of a DEWRRED sensor and utilize it to detect explosives from two standoff distances. The sensor system includes two novel, compact CW deep-Ultraviolet (DUV) lasers, a compact dual-band high throughput DUV spectrometer, and a highly-sensitive detection algorithm. We choose DUV excitation because Raman intensities from explosive traces are enhanced and fluorescence and solar background are not present. The DEWRRED technique exploits the excitation wavelength dependence of Raman signal strength, arising from complex interplay of resonant enhancement, self-absorption and laser penetration depth. We show measurements from >10 explosives/pre-cursor materials at different standoff distances. The sensor showed high sensitivity in explosive detection even when the signalto- noise ratio was close to one (~1.6). We measured receiver-operating-characteristics, which show a clear benefit in using the dual-excitation-wavelength technique as compared to a single-excitation-wavelength technique. Our measurements also show improved specificity using the amplitude variation information in the dual-excitation spectra.

Unambiguous detection of nitrated explosive vapours by fluorescence quenching of dendrimer films

NASA Astrophysics Data System (ADS)

Geng, Yan; Ali, Mohammad A.; Clulow, Andrew J.; Fan, Shengqiang; Burn, Paul L.; Gentle, Ian R.; Meredith, Paul; Shaw, Paul E.

2015-09-01

Unambiguous and selective standoff (non-contact) infield detection of nitro-containing explosives and taggants is an important goal but difficult to achieve with standard analytical techniques. Oxidative fluorescence quenching is emerging as a high sensitivity method for detecting such materials but is prone to false positives--everyday items such as perfumes elicit similar responses. Here we report thin films of light-emitting dendrimers that detect vapours of explosives and taggants selectively--fluorescence quenching is not observed for a range of common interferents. Using a combination of neutron reflectometry, quartz crystal microbalance and photophysical measurements we show that the origin of the selectivity is primarily electronic and not the diffusion kinetics of the analyte or its distribution in the film. The results are a major advance in the development of sensing materials for the standoff detection of nitro-based explosive vapours, and deliver significant insights into the physical processes that govern the sensing efficacy.

Unambiguous detection of nitrated explosive vapours by fluorescence quenching of dendrimer films.

PubMed

Geng, Yan; Ali, Mohammad A; Clulow, Andrew J; Fan, Shengqiang; Burn, Paul L; Gentle, Ian R; Meredith, Paul; Shaw, Paul E

2015-09-15

Unambiguous and selective standoff (non-contact) infield detection of nitro-containing explosives and taggants is an important goal but difficult to achieve with standard analytical techniques. Oxidative fluorescence quenching is emerging as a high sensitivity method for detecting such materials but is prone to false positives—everyday items such as perfumes elicit similar responses. Here we report thin films of light-emitting dendrimers that detect vapours of explosives and taggants selectively—fluorescence quenching is not observed for a range of common interferents. Using a combination of neutron reflectometry, quartz crystal microbalance and photophysical measurements we show that the origin of the selectivity is primarily electronic and not the diffusion kinetics of the analyte or its distribution in the film. The results are a major advance in the development of sensing materials for the standoff detection of nitro-based explosive vapours, and deliver significant insights into the physical processes that govern the sensing efficacy.

Unambiguous detection of nitrated explosive vapours by fluorescence quenching of dendrimer films

PubMed Central

Geng, Yan; Ali, Mohammad A.; Clulow, Andrew J.; Fan, Shengqiang; Burn, Paul L.; Gentle, Ian R.; Meredith, Paul; Shaw, Paul E.

2015-01-01

Unambiguous and selective standoff (non-contact) infield detection of nitro-containing explosives and taggants is an important goal but difficult to achieve with standard analytical techniques. Oxidative fluorescence quenching is emerging as a high sensitivity method for detecting such materials but is prone to false positives—everyday items such as perfumes elicit similar responses. Here we report thin films of light-emitting dendrimers that detect vapours of explosives and taggants selectively—fluorescence quenching is not observed for a range of common interferents. Using a combination of neutron reflectometry, quartz crystal microbalance and photophysical measurements we show that the origin of the selectivity is primarily electronic and not the diffusion kinetics of the analyte or its distribution in the film. The results are a major advance in the development of sensing materials for the standoff detection of nitro-based explosive vapours, and deliver significant insights into the physical processes that govern the sensing efficacy. PMID:26370931

Vibrational spectroscopy standoff detection of threat chemicals

NASA Astrophysics Data System (ADS)

Ortiz-Rivera, William; Pacheco-Londoño, Leonardo C.; Castro-Suarez, John R.; Felix-Rivera, Hilsamar; Hernandez-Rivera, Samuel P.

2011-06-01

Spectroscopy based standoff detection systems: Raman and FTIR have been tested for detection of threat chemicals, including highly energetic materials, homemade explosives, explosives formulations and high explosives mixtures. Other threat chemicals studied included toxic industrial compounds (TIC) and chemical agent simulants. Microorganisms and biological threat agent simulants have also been detected at standoff distances. Open Path FTIR has been used to detect vapors and chemicals deposited on metal surfaces at μg/cm2 levels at distances as far as 30 m in active mode and 60 m in passive mode. In the case of Raman telescope, standoff distances for acetonitrile and ammonium nitrate were 140 m.

Non-detonable explosive simulators

DOEpatents

Simpson, Randall L.; Pruneda, Cesar O.

1994-01-01

A simulator which is chemically equivalent to an explosive, but is not detonable. The simulator has particular use in the training of explosives detecting dogs and calibrating sensitive analytical instruments. The explosive simulants may be fabricated by different techniques, a first involves the use of standard slurry coatings to produce a material with a very high binder to explosive ratio without masking the explosive vapor, and the second involves coating inert beads with thin layers of explosive molecules.

Two luminescent Zn(II) metal-organic frameworks for exceptionally selective detection of picric acid explosives.

PubMed

Shi, Zhi-Qiang; Guo, Zi-Jian; Zheng, He-Gen

2015-05-14

Two luminescent Zn(II) metal-organic frameworks were prepared from a π-conjugated thiophene-containing carboxylic acid ligand. These two MOFs show strong luminescene and their luminescence could be quenched by a series of nitroaromatic explosives. Importantly, they exhibit very highly sensitive and selective detection of picric acid compared to other nitroaromatic explosives.

Airport testing an explosives detection portal

DOE Office of Scientific and Technical Information (OSTI.GOV)

Rhykerd, C.; Linker, K.; Hannum, D.

1998-08-01

At the direction of the US Congress, following the Pan Am 103 and TWA 800 crashes, the Federal Aviation Administration funded development of non-invasive techniques to screen airline passengers for explosives. Such an explosives detection portal, developed at Sandia National Laboratories, was field tested at the Albuquerque International airport in September 1997. During the 2-week field trial, 2,400 passengers were screened and 500 surveyed. Throughput, reliability, maintenance and sensitivity were studied. Follow-up testing at Sandia and at Idaho National Engineering and Environmental Laboratory was conducted. A passenger stands in the portal for five seconds while overhead fans blow air overmore » his body. Any explosive vapors or dislodged particles are collected in vents at the feet. Explosives are removed from the air in a preconcentrator and subsequently directed into an ion mobility spectrometer for detection. Throughput measured 300 passengers per hour. The non-invasive portal can detect subfingerprint levels of explosives residue on clothing. A survey of 500 passengers showed a 97% approval rating, with 99% stating that such portals, if effective, should be installed in airports to improve security. Results of the airport test, as well as operational issues, are discussed.« less

Nitromethane K-9 Detection Limit

DOE Office of Scientific and Technical Information (OSTI.GOV)

Strobel, R; Kury, J

2003-08-29

The Bureau of Alcohol, Tobacco and Firearms (ATF) trains canine/handler teams to detect explosives for government and other agencies worldwide. After completing the training program the teams are tested on an array containing explosives and numerous other samples designed to distract a canine. Passing this test results in a team's certification. These teams can be considered as ''detection instruments'' freshly calibrated just before leaving the ''factory''. Using these teams to examine special experimental arrays immediately following certification can lead to a better understanding of a canine's detection capabilities. Forty-one of these ''detection instruments'' were used in four test series withmore » arrays containing dilute nitromethane-in-water solutions. (The canines had been trained on the amount of nitromethane vapor in equilibrium with the undiluted liquid explosive.) By diluting liquid nitromethane with water, the amount of explosive vapor can be reduced many orders of magnitude to test the lower limit of the canine's nitromethane vapor detection response. The results are presented in this paper.« less

Method for fabricating non-detonable explosive simulants

DOEpatents

Simpson, Randall L.; Pruneda, Cesar O.

1995-01-01

A simulator which is chemically equivalent to an explosive, but is not detonable. The simulator has particular use in the training of explosives detecting dogs and calibrating sensitive analytical instruments. The explosive simulants may be fabricated by different techniques, a first involves the use of standard slurry coatings to produce a material with a very high binder to explosive ratio without masking the explosive vapor, and the second involves coating inert beads with thin layers of explosive molecules.

Non-detonable explosive simulators

DOEpatents

Simpson, R.L.; Pruneda, C.O.

1994-11-01

A simulator which is chemically equivalent to an explosive, but is not detonable. The simulator has particular use in the training of explosives detecting dogs and calibrating sensitive analytical instruments. The explosive simulants may be fabricated by different techniques, a first involves the use of standard slurry coatings to produce a material with a very high binder to explosive ratio without masking the explosive vapor, and the second involves coating inert beads with thin layers of explosive molecules. 5 figs.

Toward wearable sensors: optical sensor for detection of ammonium nitrate-based explosives, ANFO and ANNM.

PubMed

Sheykhi, Sara; Mosca, Lorenzo; Anzenbacher, Pavel

2017-05-04

Increasing security needs require compact and portable detection tools for the rapid and reliable identification of explosives used in improvised explosive devices (IEDs). We report of an easy-to-use optical sensor for both vapour-phase and solution-phase identification of explosive mixtures that uses a cross-reactive fluorimetric sensor array comprising chemically responsive fluorimetric indicators composed of aromatic aldehydes and polyethyleneimine. Ammonium nitrate-nitromethane (ANNM) was analyzed by paper microzone arrays and nanofiber sensor mats. Progress toward wearable sensors based on electrospun nanofiber mats is outlined.

Bomb swab: Can trace explosive particle sampling and detection be improved?

PubMed

Fisher, Danny; Zach, Raya; Matana, Yossef; Elia, Paz; Shustack, Shiran; Sharon, Yarden; Zeiri, Yehuda

2017-11-01

The marked increase in international terror in recent years requires the development of highly efficient methods to detect trace amounts of explosives at airports, border crossings and check points. The preferred analytical method worldwide is the ion mobility spectrometry (IMS) that is capable of detecting most explosives at the nano-gram level. Sample collection for the IMS analysis is based on swabbing of a passenger's belongings to collect possible explosive residues. The present study examines a wide range of issues related to swab-based particle collection and analysis, in the hope of gaining deeper understanding into this technique that will serve to improve the detection process. The adhesion of explosive particles to three typical materials, plastic, metal and glass, were measured using atomic force microscopy (AFM). We found that a strong contribution of capillary forces to adhesion on glass and metal surfaces renders these substrates more promising materials upon which to find and collect explosive residues. The adhesion of explosives to different swipe materials was also examined. Here we found that Muslin, Nomex ® and polyamide membrane surfaces are the most promising materials for use as swipes. Subsequently, the efficiency of multiple swipe use - for collecting explosive residues from a glass surface using Muslin, Nomex ® and Teflon™ swipes - was examined. The study suggests that swipes used in about 5-10 "sampling and analysis cycles" have higher efficiency as compared to new unused swipes. The reason for this behavior was found to be related to the increased roughness of the swipe surface following a few swab measurements. Lastly, GC-MS analysis was employed to examine the nature of contaminants collected by the three types of swipe. The relative amounts of different contaminants are reported. The existence and interference of these contaminants have to be considered in relation to the detection efficiency of the various explosives by the IMS. Copyright © 2017 Elsevier B.V. All rights reserved.

Direct Analysis in Real Time Mass Spectrometry of Potential By-Products from Homemade Nitrate Ester Explosive Synthesis

PubMed Central

Sisco, Edward; Forbes, Thomas P.

2016-01-01

This work demonstrates the coupling of direct analysis in real time (DART) ionization with time-of-flight mass spectrometry (MS) in an off-axis configuration for the trace detection and analysis of potential partially nitrated and dimerized by-products of homemade nitrate ester explosive synthesis. Five compounds relating to the synthesis of nitroglycerin (NG) and pentaerythritol tetranitrate (PETN) were examined. Deprotonated ions and adducts with molecular oxygen, nitrite, and nitrate were observed in the mass spectral responses of these compounds. A global optimum temperature of 350 °C for the by-products investigated here, enabled single nanogram to sub nanogram trace detection. Matrix effects were examined through a series of mixtures containing one or more compounds (sugar alcohol precursors, by-products, and/or explosives) across a range of mass loadings. The explosives MS responses experienced competitive ionization in the presence of all by-products. The magnitude of this influence corresponded to both the degree of by-product nitration and the relative mass loading of the by-product to the explosive. This work provides a characterization of potential by-products from homemade nitrate ester synthesis, including matrix effects and potential challenges that might arise from the trace detection of homemade explosives (HMEs) containing impurities. Detection and understanding of HME impurities and complex mixtures may provide valuable information for the screening and sourcing of homemade nitrate ester explosives. PMID:26838397

Trace Detection of RDX, HMX and PETN Explosives Using a Fluorescence Spot Sensor

PubMed Central

Wang, Chen; Huang, Helin; Bunes, Benjamin R.; Wu, Na; Xu, Miao; Yang, Xiaomei; Yu, Li; Zang, Ling

2016-01-01

1,3,5-trinitroperhydro-1,3,5-triazine (RDX), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), and pentaerythritol tetranitrate (PETN), the major components in plastic explosives, pose a significant threat to public safety. A quick, sensitive, and low-cost detection method for these non-volatile explosives is eagerly demanded. Here we present a fluo-spot approach, which can be employed for in situ detection of trace amount of explosives. The sensor molecule is a charge-transfer fluorophore, DCM, which is strongly fluorescent in its pristine state, but non-fluorescent after the quick reaction with NO2· (or NO2+) generated from the UV photolysis of RDX, HMX (or PETN). When fabricated within silica gel TLC plate, the fluo-spot sensor features high sensitivity owing to the large surface area and porous structure of the substrate. The sensor reaction mechanism was verified by various experimental characterizations, including chromatography, UV-Vis absorption and fluorescence spectroscopy, MS and 1H NMR spectrometry. The fluo-spot also demonstrated high selectivity towards RDX, HMX and PETN, as no significant fluorescence quenching was observed for other chemical compounds including common nitro-aromatic explosives and inorganic oxidative compounds. The DCM sensor can also be used as an economical spray kit to directly spot the explosives by naked eyes, implying great potential for quick, low-cost trace explosives detection. PMID:27146290

Trace Detection of RDX, HMX and PETN Explosives Using a Fluorescence Spot Sensor.

PubMed

Wang, Chen; Huang, Helin; Bunes, Benjamin R; Wu, Na; Xu, Miao; Yang, Xiaomei; Yu, Li; Zang, Ling

2016-05-05

1,3,5-trinitroperhydro-1,3,5-triazine (RDX), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX), and pentaerythritol tetranitrate (PETN), the major components in plastic explosives, pose a significant threat to public safety. A quick, sensitive, and low-cost detection method for these non-volatile explosives is eagerly demanded. Here we present a fluo-spot approach, which can be employed for in situ detection of trace amount of explosives. The sensor molecule is a charge-transfer fluorophore, DCM, which is strongly fluorescent in its pristine state, but non-fluorescent after the quick reaction with NO2· (or NO2(+)) generated from the UV photolysis of RDX, HMX (or PETN). When fabricated within silica gel TLC plate, the fluo-spot sensor features high sensitivity owing to the large surface area and porous structure of the substrate. The sensor reaction mechanism was verified by various experimental characterizations, including chromatography, UV-Vis absorption and fluorescence spectroscopy, MS and (1)H NMR spectrometry. The fluo-spot also demonstrated high selectivity towards RDX, HMX and PETN, as no significant fluorescence quenching was observed for other chemical compounds including common nitro-aromatic explosives and inorganic oxidative compounds. The DCM sensor can also be used as an economical spray kit to directly spot the explosives by naked eyes, implying great potential for quick, low-cost trace explosives detection.

Classification of group behaviors in social media via social behavior grammars

NASA Astrophysics Data System (ADS)

Levchuk, Georgiy; Getoor, Lise; Smith, Marc

2014-06-01

The increasing use of online collaboration and information sharing in the last decade has resulted in explosion of criminal and anti-social activities in online communities. Detection of such behaviors are of interest to commercial enterprises who want to guard themselves from cyber criminals, and the military intelligence analysts who desire to detect and counteract cyberwars waged by adversarial states and organizations. The most challenging behaviors to detect are those involving multiple individuals who share actions and roles in the hostile activities and individually appear benign. To detect these behaviors, the theories of group behaviors and interactions must be developed. In this paper we describe our exploration of the data from collaborative social platform to categorize the behaviors of multiple individuals. We applied graph matching algorithms to explore consistent social interactions. Our research led us to a conclusion that complex collaborative behaviors can be modeled and detected using a concept of group behavior grammars, in a manner analogous to natural language processing. These grammars capture constraints on how people take on roles in virtual environments, form groups, and interact over time, providing the building blocks for scalable and accurate multi-entity interaction analysis and social behavior hypothesis testing.

Artificial Olfactory System for Trace Identification of Explosive Vapors Realized by Optoelectronic Schottky Sensing.

PubMed

Guo, Linjuan; Yang, Zheng; Dou, Xincun

2017-02-01

A rapid, ultrasensitive artificial olfactory system based on an individual optoelectronic Schottky junction is demonstrated for the discriminative detection of explosive vapors, including military explosives and improvised explosives. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Micellar electrokinetic chromatography and capillary electrochromatography of nitroaromatic explosives in seawater.

PubMed

Giordano, Braden C; Copper, Christine L; Collins, Greg E

2006-02-01

The ability to separate nitroaromatic and nitramine explosives in seawater sample matrices is demonstrated using both MEKC and CEC. While several capillary-based separations exist for explosives, none address direct sampling from seawater, a sample matrix of particular interest in the detection of undersea mines. Direct comparisons are made between MEKC and CEC in terms of sensitivity and separation efficiency for the analysis of 14 explosives and explosive degradation products in seawater and diluted seawater. The use of high-salt stacking with MEKC results, on average, in a three-fold increase in the number of theoretical plates, and nearly double resolution for samples prepared in 25% seawater. By taking advantage of long injection times in conjunction with stacking, detection limits down to sub mg/L levels are attainable; however, resolution is sacrificed. CEC of explosive mixtures using sol-gels prepared from methyltrimethoxysilane does not perform as well as MEKC in terms of resolving power, but does permit extended injection times for concentrating analyte onto the head of the separation column with little or no subsequent loss in resolution. Electrokinetic injections of 8 min at high voltage allow for detection limits of explosives below 100 microg/L.

A simulation study of fast neutron interrogation for standoff detection of improvised explosive devices

NASA Astrophysics Data System (ADS)

Heider, S. A.; Dunn, W. L.

2015-11-01

The signature-based radiation-scanning technique utilizes radiation detector responses, called "signatures," and compares these to "templates" in order to differentiate targets that contain certain materials, such as explosives or drugs, from those that do not. Our investigations are aimed at the detection of nitrogen-rich explosives contained in improvised explosive devices. We use the term "clutter" to refer to any non-explosive materials with which the interrogating radiation may interact between source and detector. To deal with the many target types and clutter configurations that may be encountered in the field, the use of "artificial templates" is proposed. The MCNP code was used to simulate 14.1 MeV neutron source beams incident on one type of target containing various clutter and sample materials. Signatures due to inelastic-scatter and prompt-capture gamma rays from hydrogen, carbon, nitrogen, and oxygen and two scattered neutron signatures were considered. Targets containing explosive materials in the presence of clutter were able to be identified from targets that contained only non-explosive ("inert") materials. This study demonstrates that a finite number of artificial templates is sufficient for IED detection with fairly good sensitivity and specificity.

Eye-safe UV Raman spectroscopy for remote detection of explosives and their precursors in fingerprint concentration

NASA Astrophysics Data System (ADS)

Almaviva, S.; Angelini, F.; Chirico, R.; Palucci, A.; Nuvoli, M.; Schnuerer, F.; Schweikert, W.; Romolo, F. S.

2014-10-01

We report the results of Raman investigation performed at stand-off distance between 6-10 m with a new apparatus, capable to detect traces of explosives with surface concentrations similar to those of a single fingerprint. The device was developed as part of the RADEX prototype (RAman Detection of EXplosives) and is capable of detecting the Raman signal with a single laser shot of few ns (10-9 s) in the UV range (wavelength 266 nm), in conditions of safety for the human eye. This is because the maximum permissible exposure (MPE) for the human eye is established to be 3 mJ/cm2 in this wavelength region and pulse duration. Samples of explosives (PETN, TNT, Urea Nitrate, Ammonium Nitrate) were prepared starting from solutions deposited on samples of common fabrics or clothing materials such as blue jeans, leather, polyester or polyamide. The deposition process takes place via a piezoelectric-controlled plotter device, capable of producing drops of welldefined volume, down to nanoliters, on a surface of several cm2, in order to carefully control the amount of explosive released to the tissue and thus simulate a slight stain on a garment of a potential terrorist. Depending on the type of explosive sampled, the detected density ranges from 0.1 to 1 mg/cm2 and is comparable to the density measured in a spot on a dress or a bag due to the contact with hands contaminated with explosives, as it could happen in the preparation of an improvised explosive device (IED) by a terrorist. To our knowledge the developed device is at the highest detection limits nowadays achievable in the field of eyesafe, stand-off Raman instruments. The signals obtained show some vibrational bands of the Raman spectra of our samples with high signal-to-noise ratio (SNR), allowing us to identify with high sensitivity (high number of True Positives) and selectivity (low number of False Positives) the explosives, so that the instrument could represent the basis for an automated and remote monitoring device.

Feasibility studies on explosive detection and homeland security applications using a neutron and x-ray combined computed tomography system

NASA Astrophysics Data System (ADS)

Sinha, V.; Srivastava, A.; Lee, H. K.; Liu, X.

2013-05-01

The successful creation and operation of a neutron and X-ray combined computed tomography (NXCT) system has been demonstrated by researchers at the Missouri University of Science and Technology. The NXCT system has numerous applications in the field of material characterization and object identification in materials with a mixture of atomic numbers represented. Presently, the feasibility studies have been performed for explosive detection and homeland security applications, particularly in concealed material detection and determination of the light atomic number materials. These materials cannot be detected using traditional X-ray imaging. The new system has the capability to provide complete structural and compositional information due to the complementary nature of X-ray and neutron interactions with materials. The design of the NXCT system facilitates simultaneous and instantaneous imaging operation, promising enhanced detection capabilities of explosive materials, low atomic number materials and illicit materials for homeland security applications. In addition, a sample positioning system allowing the user to remotely and automatically manipulate the sample makes the system viable for commercial applications. Several explosives and weapon simulants have been imaged and the results are provided. The fusion algorithms which combine the data from the neutron and X-ray imaging produce superior images. This paper is a compete overview of the NXCT system for feasibility studies of explosive detection and homeland security applications. The design of the system, operation, algorithm development, and detection schemes are provided. This is the first combined neutron and X-ray computed tomography system in operation. Furthermore, the method of fusing neutron and X-ray images together is a new approach which provides high contrast images of the desired object. The system could serve as a standardized tool in nondestructive testing of many applications, especially in explosives detection and homeland security research.

Organic nanofibrils based on linear carbazole trimer for explosive sensing.

PubMed

Zhang, Chengyi; Che, Yanke; Yang, Xiaomei; Bunes, Benjamin R; Zang, Ling

2010-08-14

Organic fluorescent nanofibrils were fabricated from a linear carbazole trimer and employed for expedient detection of nitroaromatic explosives (DNT and TNT) and highly volatile nitroaliphatic explosives (nitromethane).

Laser based in-situ and standoff detection of chemical warfare agents and explosives

NASA Astrophysics Data System (ADS)

Patel, C. Kumar N.

2009-09-01

Laser based detection of gaseous, liquid and solid residues and trace amounts has been developed ever since lasers were invented. However, the lack of availability of reasonably high power tunable lasers in the spectral regions where the relevant targets can be interrogated as well as appropriate techniques for high sensitivity, high selectivity detection has hampered the practical exploitation of techniques for the detection of targets important for homeland security and defense applications. Furthermore, emphasis has been on selectivity without particular attention being paid to the impact of interfering species on the quality of detection. Having high sensitivity is necessary but not a sufficient condition. High sensitivity assures a high probability of detection of the target species. However, it is only recently that the sensor community has come to recognize that any measure of probability of detection must be associated with a probability of false alarm, if it is to have any value as a measure of performance. This is especially true when one attempts to compare performance characteristics of different sensors based on different physical principles. In this paper, I will provide a methodology for characterizing the performance of sensors utilizing optical absorption measurement techniques. However, the underlying principles are equally application to all other sensors. While most of the current progress in high sensitivity, high selectivity detection of CWAs, TICs and explosives involve identifying and quantifying the target species in-situ, there is an urgent need for standoff detection of explosives from safe distances. I will describe our results on CO2 and quantum cascade laser (QCL) based photoacoustic sensors for the detection of CWAs, TICs and explosives as well the very new results on stand-off detection of explosives at distances up to 150 meters. The latter results are critically important for assuring safety of military personnel in battlefield environment, especially from improvised explosive devices (IEDs), and of civilian personnel from terrorist attacks in metropolitan areas.

In-injection port thermal desorption for explosives trace evidence analysis.

PubMed

Sigman, M E; Ma, C Y

1999-10-01

A gas chromatographic method utilizing thermal desorption of a dry surface wipe for the analysis of explosives trace chemical evidence has been developed and validated using electron capture and negative ion chemical ionization mass spectrometric detection. Thermal desorption was performed within a split/splitless injection port with minimal instrument modification. Surface-abraded Teflon tubing provided the solid support for sample collection and desorption. Performance was characterized by desorption efficiency, reproducibility, linearity of the calibration, and method detection and quantitation limits. Method validation was performed with a series of dinitrotoluenes, trinitrotoluene, two nitroester explosives, and one nitramine explosive. The method was applied to the sampling of a single piece of debris from an explosion containing trinitrotoluene.

Overview: MURI Center on spectroscopic and time domain detection of trace explosives in condensed and vapor phases

NASA Astrophysics Data System (ADS)

Spicer, James B.; Dagdigian, Paul; Osiander, Robert; Miragliotta, Joseph A.; Zhang, Xi-Cheng; Kersting, Roland; Crosley, David R.; Hanson, Ronald K.; Jeffries, Jay

2003-09-01

The research center established by Army Research Office under the Multidisciplinary University Research Initiative program pursues a multidisciplinary approach to investigate and advance the use of complementary analytical techniques for sensing of explosives and/or explosive-related compounds as they occur in the environment. The techniques being investigated include Terahertz (THz) imaging and spectroscopy, Laser-Induced Breakdown Spectroscopy (LIBS), Cavity Ring Down Spectroscopy (CRDS) and Resonance Enhanced Multiphoton Ionization (REMPI). This suite of techniques encompasses a diversity of sensing approaches that can be applied to detection of explosives in condensed phases such as adsorbed species in soil or can be used for vapor phase detection above the source. Some techniques allow for remote detection while others have highly specific and sensitive analysis capabilities. This program is addressing a range of fundamental, technical issues associated with trace detection of explosive related compounds using these techniques. For example, while both LIBS and THz can be used to carry-out remote analysis of condensed phase analyte from a distance in excess several meters, the sensitivities of these techniques to surface adsorbed explosive-related compounds are not currently known. In current implementations, both CRDS and REMPI require sample collection techniques that have not been optimized for environmental applications. Early program elements will pursue the fundamental advances required for these techniques including signature identification for explosive-related compounds/interferents and trace analyte extraction. Later program tasks will explore simultaneous application of two or more techniques to assess the benefits of sensor fusion.

Solid-phase microextraction coupled to gas chromatography for the determination of 2,3-dimethyl-2,3-dinitrobutane as a marking agent for explosives.

PubMed

Li, Xiujuan; Zeng, Zhaorui; Zeng, Yi

2007-06-15

This paper investigates the detection of 2,3-dimethyl-2,3-dinitrobutane (DMNB), a marking agent in explosives, by gas chromatography (GC) with electron capture detection using solid-phase microextraction (SPME) as a sample preparation technique. The 25,27-dihydroxy-26,28-oxy (2',7'-dioxo-3',6'-diazaoctyl) oxy-p-tert-butylcalix[4]arene/hydroxy-terminated silicone oil coated fiber was highly sensitive to trap DMNB from ammonium nitrate matrix. The analysis was performed by extracting 2g of explosives for 30s at room temperature and then immediately introducing into the heated GC injector for 1min of thermal desorption. The method showed good linearity in the range from 0.01 to 1.0mug/g. The relative standard deviations for these extractions were <8%. The calculated limit of detection for DMNB (S/N=3) was 4.43x10(-4)mug/g, which illustrates that the proposed systems are suitable for explosive detection at trace level. This is the first report of an SPME-GC system shown to extract marking agent in explosives for subsequent detection in a simple, rapid, sensitive, and inexpensive manner.

Terrorism and Drug Trafficking: Technologies for Detecting Explosives and Narcotics

DOT National Transportation Integrated Search

1996-09-01

The General Accounting Office (GAO) examined information on explosives and narcotics detection technologies that are available or under development. This report discusses (1) funding for those technologies, (2) characteristics and limitations of avai...

Method for fabricating non-detonable explosive simulants

DOEpatents

Simpson, R.L.; Pruneda, C.O.

1995-05-09

A simulator is disclosed which is chemically equivalent to an explosive, but is not detonable. The simulator has particular use in the training of explosives detecting dogs and calibrating sensitive analytical instruments. The explosive simulants may be fabricated by different techniques, a first involves the use of standard slurry coatings to produce a material with a very high binder to explosive ratio without masking the explosive vapor, and the second involves coating inert beads with thin layers of explosive molecules. 5 figs.

A critical review of ion mobility spectrometry for the detection of explosives and explosive related compounds.

PubMed

Ewing, R G; Atkinson, D A; Eiceman, G A; Ewing, G J

2001-05-10

Ion mobility spectrometry has become the most successful and widely used technology for the detection of trace levels of nitro-organic explosives on handbags and carry on-luggage in airports throughout the US. The low detection limits are provided by the efficient ionization process, namely, atmospheric pressure chemical ionization (APCI) reactions in negative polarity. An additional level of confidence in a measurement is imparted by characterization of ions for mobilities in weak electric fields of a drift tube at ambient pressure. Findings from over 30 years of investigations into IMS response to these explosives have been collected and assessed to allow a comprehensive view of the APCI reactions characteristic of nitro-organic explosives. Also, the drift tube conditions needed to obtain particular mobility spectra have been summarized. During the past decade, improvements have occurred in IMS on the understanding of reagent gas chemistries, the influence of temperature on ion stability, and sampling methods. In addition, commercial instruments have been refined to provide fast and reliable measurements for on-site detection of explosives. The gas phase ion chemistry of most explosives is mediated by the fragile CONO(2) bonds or the acidity of protons. Thus, M(-) or M.Cl(-) species are found with only a few explosives and loss of NO(2), NO(3) and proton abstraction reactions are common and complicating pathways. However, once ions are formed, they appear to have stabilities on time scales equal to or longer than ion drift times from 5-20 ms. As such, peak shapes in IMS are suitable for high selectivity and sensitivity.

Microcantilever detector for explosives

DOEpatents

Thundat, Thomas G.

1999-01-01

Methods and apparatus for detecting the presence of explosives by analyzing a vapor sample from the suspect vicinity utilize at least one microcantilever. Explosive gas molecules which have been adsorbed onto the microcantilever are subsequently heated to cause combustion. Heat, along with momentum transfer from combustion, causes bending and a transient resonance response of the microcantilever which may be detected by a laser diode which is focused on the microcantilever and a photodetector which detects deflection of the reflected laser beam caused by heat-induced deflection and resonance response of the microcantilever.

Microcantilever detector for explosives

DOEpatents

Thundat, T.G.

1999-06-29

Methods and apparatus for detecting the presence of explosives by analyzing a vapor sample from the suspect vicinity utilize at least one microcantilever. Explosive gas molecules which have been adsorbed onto the microcantilever are subsequently heated to cause combustion. Heat, along with momentum transfer from combustion, causes bending and a transient resonance response of the microcantilever which may be detected by a laser diode which is focused on the microcantilever and a photodetector which detects deflection of the reflected laser beam caused by heat-induced deflection and resonance response of the microcantilever. 2 figs.

Ultrasensitive, Real-time and Discriminative Detection of Improvised Explosives by Chemiresistive Thin-film Sensory Array of Mn2+ Tailored Hierarchical ZnS

NASA Astrophysics Data System (ADS)

Zhou, Chaoyu; Wu, Zhaofeng; Guo, Yanan; Li, Yushu; Cao, Hongyu; Zheng, Xuefang; Dou, Xincun

2016-05-01

A simple method combing Mn2+ doping with a hierarchical structure was developed for the improvement of thin-film sensors and efficient detection of the explosives relevant to improvised explosive devices (IEDs). ZnS hierarchical nanospheres (HNs) were prepared via a solution-based route and their sensing performances were manipulated by Mn2+ doping. The responses of the sensors based on ZnS HNs towards 8 explosives generally increase firstly and then decrease with the increase of the doped Mn2+ concentration, reaching the climate at 5% Mn2+. Furthermore, the sensory array based on ZnS HNs with different doping levels achieved the sensitive and discriminative detection of 6 analytes relevant to IEDs and 2 military explosives in less than 5 s at room temperature. Importantly, the superior sensing performances make ZnS HNs material interesting in the field of chemiresistive sensors, and this simple method could be a very promising strategy to put the sensors based on thin-films of one-dimensional (1D) nanostructures into practical IEDs detection.

Ultrasensitive, Real-time and Discriminative Detection of Improvised Explosives by Chemiresistive Thin-film Sensory Array of Mn2+ Tailored Hierarchical ZnS

PubMed Central

Zhou, Chaoyu; Wu, Zhaofeng; Guo, Yanan; Li, Yushu; Cao, Hongyu; Zheng, Xuefang; Dou, Xincun

2016-01-01

A simple method combing Mn2+ doping with a hierarchical structure was developed for the improvement of thin-film sensors and efficient detection of the explosives relevant to improvised explosive devices (IEDs). ZnS hierarchical nanospheres (HNs) were prepared via a solution-based route and their sensing performances were manipulated by Mn2+ doping. The responses of the sensors based on ZnS HNs towards 8 explosives generally increase firstly and then decrease with the increase of the doped Mn2+ concentration, reaching the climate at 5% Mn2+. Furthermore, the sensory array based on ZnS HNs with different doping levels achieved the sensitive and discriminative detection of 6 analytes relevant to IEDs and 2 military explosives in less than 5 s at room temperature. Importantly, the superior sensing performances make ZnS HNs material interesting in the field of chemiresistive sensors, and this simple method could be a very promising strategy to put the sensors based on thin-films of one-dimensional (1D) nanostructures into practical IEDs detection. PMID:27161193

An explosives detection system for airline security using coherent x-ray scattering technology

NASA Astrophysics Data System (ADS)

Madden, Robert W.; Mahdavieh, Jacob; Smith, Richard C.; Subramanian, Ravi

2008-08-01

L-3 Communications Security and Detection Systems (SDS) has developed a new system for automated alarm resolution in airline baggage Explosive Detection Systems (EDS) based on coherent x-ray scattering spectroscopy. The capabilities of the system were demonstrated in tests with concealed explosives at the Transportation Security Laboratory and airline passenger baggage at Orlando International Airport. The system uses x-ray image information to identify suspicious objects and performs targeted diffraction measurements to classify them. This extra layer of detection capability affords a significant reduction in the rate of false alarm objects that must presently be resolved by opening passenger bags for hand inspection.

Real-time supernova neutrino burst monitor at Super-Kamiokande

NASA Astrophysics Data System (ADS)

Abe, K.; Haga, Y.; Hayato, Y.; Ikeda, M.; Iyogi, K.; Kameda, J.; Kishimoto, Y.; Miura, M.; Moriyama, S.; Nakahata, M.; Nakano, Y.; Nakayama, S.; Sekiya, H.; Shiozawa, M.; Suzuki, Y.; Takeda, A.; Tanaka, H.; Tomura, T.; Ueno, K.; Wendell, R. A.; Yokozawa, T.; Irvine, T.; Kajita, T.; Kametani, I.; Kaneyuki, K.; Lee, K. P.; McLachlan, T.; Nishimura, Y.; Richard, E.; Okumura, K.; Labarga, L.; Fernandez, P.; Berkman, S.; Tanaka, H. A.; Tobayama, S.; Gustafson, J.; Kearns, E.; Raaf, J. L.; Stone, J. L.; Sulak, L. R.; Goldhaber, M.; Carminati, G.; Kropp, W. R.; Mine, S.; Weatherly, P.; Renshaw, A.; Smy, M. B.; Sobel, H. W.; Takhistov, V.; Ganezer, K. S.; Hartfiel, B. L.; Hill, J.; Keig, W. E.; Hong, N.; Kim, J. Y.; Lim, I. T.; Akiri, T.; Himmel, A.; Scholberg, K.; Walter, C. W.; Wongjirad, T.; Ishizuka, T.; Tasaka, S.; Jang, J. S.; Learned, J. G.; Matsuno, S.; Smith, S. N.; Hasegawa, T.; Ishida, T.; Ishii, T.; Kobayashi, T.; Nakadaira, T.; Nakamura, K.; Oyama, Y.; Sakashita, K.; Sekiguchi, T.; Tsukamoto, T.; Suzuki, A. T.; Takeuchi, Y.; Bronner, C.; Hirota, S.; Huang, K.; Ieki, K.; Kikawa, T.; Minamino, A.; Murakami, A.; Nakaya, T.; Suzuki, K.; Takahashi, S.; Tateishi, K.; Fukuda, Y.; Choi, K.; Itow, Y.; Mitsuka, G.; Mijakowski, P.; Hignight, J.; Imber, J.; Jung, C. K.; Yanagisawa, C.; Wilking, M. J.; Ishino, H.; Kibayashi, A.; Koshio, Y.; Mori, T.; Sakuda, M.; Yamaguchi, R.; Yano, T.; Kuno, Y.; Tacik, R.; Kim, S. B.; Okazawa, H.; Choi, Y.; Nishijima, K.; Koshiba, M.; Suda, Y.; Totsuka, Y.; Yokoyama, M.; Martens, K.; Marti, Ll.; Vagins, M. R.; Martin, J. F.; de Perio, P.; Konaka, A.; Chen, S.; Zhang, Y.; Connolly, K.; Wilkes, R. J.

2016-08-01

We present a real-time supernova neutrino burst monitor at Super-Kamiokande (SK). Detecting supernova explosions by neutrinos in real time is crucial for giving a clear picture of the explosion mechanism. Since the neutrinos are expected to come earlier than light, a fast broadcasting of the detection may give astronomers a chance to make electromagnetic radiation observations of the explosions right at the onset. The role of the monitor includes a fast announcement of the neutrino burst detection to the world and a determination of the supernova direction. We present the online neutrino burst detection system and studies of the direction determination accuracy based on simulations at SK.

Double-pulse standoff laser-induced breakdown spectroscopy for versatile hazardous materials detection

NASA Astrophysics Data System (ADS)

Gottfried, Jennifer L.; De Lucia, Frank C.; Munson, Chase A.; Miziolek, Andrzej W.

2007-12-01

We have developed a double-pulse standoff laser-induced breakdown spectroscopy (ST-LIBS) system capable of detecting a variety of hazardous materials at tens of meters. The use of a double-pulse laser improves the sensitivity and selectivity of ST-LIBS, especially for the detection of energetic materials. In addition to various metallic and plastic materials, the system has been used to detect bulk explosives RDX and Composition-B, explosive residues, biological species such as the anthrax surrogate Bacillus subtilis, and chemical warfare simulants at 20 m. We have also demonstrated the discrimination of explosive residues from various interferents on an aluminum substrate.

Optimization of biological and instrumental detection of explosives and ignitable liquid residues including canines, SPME/ITMS and GC/MSn

NASA Astrophysics Data System (ADS)

Furton, Kenneth G.; Harper, Ross J.; Perr, Jeannette M.; Almirall, Jose R.

2003-09-01

A comprehensive study and comparison is underway using biological detectors and instrumental methods for the rapid detection of ignitable liquid residues (ILR) and high explosives. Headspace solid phase microextraction (SPME) has been demonstrated to be an effective sampling method helping to identify active odor signature chemicals used by detector dogs to locate forensic specimens as well as a rapid pre-concentration technique prior to instrumental detection. Common ignitable liquids and common military and industrial explosives have been studied including trinitrotoluene, tetryl, RDX, HMX, EGDN, PETN and nitroglycerine. This study focuses on identifying volatile odor signature chemicals present, which can be used to enhance the level and reliability of detection of ILR and explosives by canines and instrumental methods. While most instrumental methods currently in use focus on particles and on parent organic compounds, which are often involatile, characteristic volatile organics are generally also present and can be exploited to enhance detection particularly for well-concealed devices. Specific examples include the volatile odor chemicals 2-ethyl-1-hexanol and cyclohexanone, which are readily available in the headspace of the high explosive composition C-4; whereas, the active chemical cyclo-1,3,5-trimethylene-2,4,6-trinitramine (RDX) is not. The analysis and identification of these headspace 'fingerprint' organics is followed by double-blind dog trials of the individual components using certified teams in an attempt to isolate and understand the target compounds to which dogs are sensitive. Studies to compare commonly used training aids with the actual target explosive have also been undertaken to determine their suitability and effectiveness. The optimization of solid phase microextraction (SPME) combined with ion trap mobility spectrometry (ITMS) and gas chromatography/mass spectrometry/mass spectrometry (GC/MSn) is detailed including interface development and comparisons of limits of detection. These instrumental methods are being optimized in order to detect the same target odor chemicals used by detector dogs to reliably locate explosives and ignitable liquids.

Protection of Public Figures. Symposium Proceedings, May 16-18, 1972

DTIC Science & Technology

1972-01-01

192 EXPLOSIVE TRACE VAPOR DETECTION, Maryland D. Keyrw, USAMERDC.. 194 ATOMIC AND MOLECULAR DETECTION...subject through a doorway, a hallway, a portal, a fence, and thus subject him to co- vert surveillance for weapons or explosives concealed on his person...who has weapons or conceal- ed explosives on his person. So insofar as 4ERDC is concerned, the two broad scenarios that we will be talking about are

Nuclear technologies for explosives detection

NASA Astrophysics Data System (ADS)

Bell, Curtis J.

1992-12-01

This paper presents an exploration of several techniques for detection of Improvised Explosive Devices (IED) using interactions of specific nuclei with gammarays or fast neutrons. Techniques considered use these interactions to identify the device by measuring the densities and/or relative concentrations of the elemental constituents of explosives. These techniques are to be compared with selected other nuclear and non-nuclear methods. Combining of nuclear and non-nuclear techniques will also be briefly discussed.

Highly sensitive screening method for nitroaromatic, nitramine and nitrate ester explosives by high performance liquid chromatography-atmospheric pressure ionization-mass spectrometry (HPLC-API-MS) in forensic applications.

PubMed

Xu, Xiaoma; van de Craats, Anick M; de Bruyn, Peter C A M

2004-11-01

A highly sensitive screening method based on high performance liquid chromatography atmospheric pressure ionization mass spectrometry (HPLC-API-MS) has been developed for the analysis of 21 nitroaromatic, nitramine and nitrate ester explosives, which include the explosives most commonly encountered in forensic science. Two atmospheric pressure ionization (API) methods, atmospheric pressure chemical ionization (APCI) and electrospray ionization (ESI), and various experimental conditions have been applied to allow for the detection of all 21 explosive compounds. The limit of detection (LOD) in the full-scan mode has been found to be 0.012-1.2 ng on column for the screening of most explosives investigated. For nitrobenzene, an LOD of 10 ng was found with the APCI method in the negative mode. Although the detection of nitrobenzene, 2-, 3-, and 4-nitrotoluene is hindered by the difficult ionization of these compounds, we have found that by forming an adduct with glycine, LOD values in the range of 3-16 ng on column can be achieved. Compared with previous screening methods with thermospray ionization, the API method has distinct advantages, including simplicity and stability of the method applied, an extended screening range and a low detection limit for the explosives studied.

Infrared Spectroscopy of Explosives Residues: Measurement Techniques and Spectral Analysis

DOE Office of Scientific and Technical Information (OSTI.GOV)

Phillips, Mark C.; Bernacki, Bruce E.

2015-03-11

Infrared laser spectroscopy of explosives is a promising technique for standoff and non-contact detection applications. However, the interpretation of spectra obtained in typical standoff measurement configurations presents numerous challenges. Understanding the variability in observed spectra from explosives residues and particles is crucial for design and implementation of detection algorithms with high detection confidence and low false alarm probability. We discuss a series of infrared spectroscopic techniques applied toward measuring and interpreting the reflectance spectra obtained from explosives particles and residues. These techniques utilize the high spectral radiance, broad tuning range, rapid wavelength tuning, high scan reproducibility, and low noise ofmore » an external cavity quantum cascade laser (ECQCL) system developed at Pacific Northwest National Laboratory. The ECQCL source permits measurements in configurations which would be either impractical or overly time-consuming with broadband, incoherent infrared sources, and enables a combination of rapid measurement speed and high detection sensitivity. The spectroscopic methods employed include standoff hyperspectral reflectance imaging, quantitative measurements of diffuse reflectance spectra, reflection-absorption infrared spectroscopy, microscopic imaging and spectroscopy, and nano-scale imaging and spectroscopy. Measurements of explosives particles and residues reveal important factors affecting observed reflectance spectra, including measurement geometry, substrate on which the explosives are deposited, and morphological effects such as particle shape, size, orientation, and crystal structure.« less

Identification of Explosives from Porous Materials: Applications Using Reverse Phase High Performance Liquid Chromatography and Gas Chromatography

DOE Office of Scientific and Technical Information (OSTI.GOV)

C.J. Miller; G. Elias; N.C. Schmitt

2010-06-01

High performance liquid chromatography and gas chromatography techniques are well documented and widely used for the detection of trace explosives from organic solvents. These techniques were modified to specifically identify and quantify explosives extracted from various materials taken from people who had recently handled explosives. Documented techniques were modified to specifically detect and quantify RDX, TNT, and PETN from denim, colored flannel, vinyl, and canvas extracted in methanol using no sample cleanup prior to analysis. The methanol extracts were injected directly into several different column types and analyzed by HPLC-UV and/or GC-ECD. This paper describes general screening methods that weremore » used to determine the presence of explosives in unknown samples and techniques that have been optimized for quantification of each explosive from the substrate extracts.« less

Terrorism and Drug Trafficking: Responsibilities for Developing Explosives and Narcotics Detection Technologies

DOT National Transportation Integrated Search

1997-04-01

This report discusses (1) the roles, responsibilities, and authority of : agencies that establish policy, provide funds or oversee funding requests, : and develop explosives and narcotics detection technologies; : (2) mechanisms used to coordinate th...

Morphologically manipulated Ag/ZnO nanostructures as surface enhanced Raman scattering probes for explosives detection

NASA Astrophysics Data System (ADS)

Shaik, Ummar Pasha; Hamad, Syed; Ahamad Mohiddon, Md.; Soma, Venugopal Rao; Ghanashyam Krishna, M.

2016-03-01

The detection of secondary explosive molecules (e.g., ANTA, FOX-7, and CL-20) using Ag decorated ZnO nanostructures as surface enhanced Raman scattering (SERS) probes is demonstrated. ZnO nanostructures were grown on borosilicate glass substrates by rapid thermal oxidation of metallic Zn films at 500 °C. The oxide nanostructures, including nanosheets and nanowires, emerged over the surface of the Zn film leaving behind the metal residue. We demonstrate that SERS measurements with concentrations as low as 10 μM, of the three explosive molecules ANTA, FOX-7, and CL-20 over ZnO/Ag nanostructures, resulted in enhancement factors of ˜107, ˜107, and ˜104, respectively. These measurements validate the high sensitivity of detection of explosive molecules using Ag decorated ZnO nanostructures as SERS substrates. The Zn metal residue and conditions of annealing play an important role in determining the detection sensitivity.

Thin film sensor materials for detection of Nitro-Aromatic explosives

NASA Astrophysics Data System (ADS)

Ramdasi, Dipali; Mudhalwadkar, Rohini

2018-03-01

Many countries have experienced terrorist activities and innocent people have suffered. Timely detection of explosives can avoid this situation. This paper targets the detection of Nitrobenzene and Nitrotoluene, which are nitroaromatic compounds possessing explosive properties. As direct sensors for detecting these compounds are not available, Polyaniline based thin film sensors doped with palladium are developed using the spin coating technique. The response of the developed sensors is observed for varying concentrations of explosives. It is observed that zinc oxide based sensor is more sensitive to Nitrotoluene exhibiting a relative change in resistance of 0.78. The tungsten oxide sensor is more sensitive to Nitrobenzene with a relative change in resistance of 0.48. The sensor performance is assessed by measuring the response and recovery time. The cross sensitivity of the sensors is evaluated for ethanol, acetone and methanol which was observed as very low.

Improved explosive collection and detection with rationally assembled surface sampling materials

DOE Office of Scientific and Technical Information (OSTI.GOV)

Chouyyok, Wilaiwan; Bays, J. Timothy; Gerasimenko, Aleksandr A.

Sampling and detection of trace explosives is a key analytical process in modern transportation safety. In this work we have explored some of the fundamental analytical processes for collection and detection of trace level explosive on surfaces with the most widely utilized system, thermal desorption IMS. The performance of the standard muslin swipe material was compared with chemically modified fiberglass cloth. The fiberglass surface was modified to include phenyl functional groups. When compared to standard muslin, the phenyl functionalized fiberglass sampling material showed better analyte release from the sampling material as well as improved response and repeatability from multiple usesmore » of the same swipe. The improved sample release of the functionalized fiberglass swipes resulted in a significant increase in sensitivity. Various physical and chemical properties were systematically explored to determine optimal performance. The results herein have relevance to improving the detection of other explosive compounds and potentially to a wide range of other chemical sampling and field detection challenges.« less

Characteristics of seismic waves from Soviet peaceful nuclear explosions in salt

DOE Office of Scientific and Technical Information (OSTI.GOV)

Adushkin, V.V.; Kaazik, P.B.; Kostyuchenko, V.N.

1995-04-01

The report is carried out by the Institute for Dynamics of the Geospheres, Russian Academy of Sciences under contract NB280344 with Lawrence Livermore National Laboratory, University of California. The work includes investigation of seismic waves generation and propagation from Soviet peaceful underground nuclear explosions in salt based on the data from temporary and permanent seismic stations. The explosions were conducted at the sites Azgir and Vega within the territory of the Caspian depression of the Russian platform. The data used were obtained in the following conditions of conduction: epicentral distance range from 0 to 60 degrees, yields from 1 tomore » 65 kt and depths of burial from 160 to 1500 m.« less

Study on the Structures of Two Booster Pellets Having High Initiation Capacity

NASA Astrophysics Data System (ADS)

Shuang-Qi, Hu; Hong-Rong, Liu; Li-shuang, Hu; Xiong, Cao; Xiang-Chao, Mi; Hai-Xia, Zhao

2014-05-01

Insensitive munitions (IM) improve the survivability of both weapons and their associated platforms, which can lead to a reduction in casualties, mission losses, and whole life costs. All weapon systems contain an explosive train that needs to meet IM criteria but reliably initiate a main charge explosive. To ensure that these diametrically opposed requirements can be achieved, new highly effective booster charge structures were designed. The initiation capacity of the two booster pellets was studied using varied composition and axial-steel-dent methods. The results showed that the two new booster pellets can initiate standard main charge pellets with less explosive mass than the ordinary cylindrical booster pellet. The numerical simulation results were in good agreement with the experiment results.

Hidden explosives detector employing pulsed neutron and x-ray interrogation

DOEpatents

Schultz, F.J.; Caldwell, J.T.

1993-04-06

Methods and systems for the detection of small amounts of modern, highly-explosive nitrogen-based explosives, such as plastic explosives, hidden in airline baggage. Several techniques are employed either individually or combined in a hybrid system. One technique employed in combination is X-ray imaging. Another technique is interrogation with a pulsed neutron source in a two-phase mode of operation to image both nitrogen and oxygen densities. Another technique employed in combination is neutron interrogation to form a hydrogen density image or three-dimensional map. In addition, deliberately-placed neutron-absorbing materials can be detected.

Lithium niobate explosion monitor

DOEpatents

Bundy, Charles H.; Graham, Robert A.; Kuehn, Stephen F.; Precit, Richard R.; Rogers, Michael S.

1990-01-01

Monitoring explosive devices is accomplished with a substantially z-cut lithium niobate crystal in abutment with the explosive device. Upon impact by a shock wave from detonation of the explosive device, the crystal emits a current pulse prior to destruction of the crystal. The current pulse is detected by a current viewing transformer and recorded as a function of time in nanoseconds. In order to self-check the crystal, the crystal has a chromium film resistor deposited thereon which may be heated by a current pulse prior to detonation. This generates a charge which is detected by a charge amplifier.

Lithium niobate explosion monitor

DOEpatents

Bundy, C.H.; Graham, R.A.; Kuehn, S.F.; Precit, R.R.; Rogers, M.S.

1990-01-09

Monitoring explosive devices is accomplished with a substantially z-cut lithium niobate crystal in abutment with the explosive device. Upon impact by a shock wave from detonation of the explosive device, the crystal emits a current pulse prior to destruction of the crystal. The current pulse is detected by a current viewing transformer and recorded as a function of time in nanoseconds. In order to self-check the crystal, the crystal has a chromium film resistor deposited thereon which may be heated by a current pulse prior to detonation. This generates a charge which is detected by a charge amplifier. 8 figs.

Hidden explosives detector employing pulsed neutron and x-ray interrogation

DOEpatents

Schultz, Frederick J.; Caldwell, John T.

1993-01-01

Methods and systems for the detection of small amounts of modern, highly-explosive nitrogen-based explosives, such as plastic explosives, hidden in airline baggage. Several techniques are employed either individually or combined in a hybrid system. One technique employed in combination is X-ray imaging. Another technique is interrogation with a pulsed neutron source in a two-phase mode of operation to image both nitrogen and oxygen densities. Another technique employed in combination is neutron interrogation to form a hydrogen density image or three-dimensional map. In addition, deliberately-placed neutron-absorbing materials can be detected.

Remote explosive and chemical agent detection using broadly tunable mid-infrared external cavity quantum cascade lasers

NASA Astrophysics Data System (ADS)

Rayner, Timothy; Weida, Miles; Pushkarsky, Michael; Day, Timothy

2007-04-01

Terrorists both with IEDs and suicide bombers are targeting civilian infrastructures such as transportation systems. Although explosive detection technologies exist and are used effectively in aviation, these technologies do not lend themselves well to protecting open architecture soft targets, as they are focused on a checkpoint form factor that limits throughput. However, remote detection of explosives and other chemicals would enable these kinds of targets to be protected without interrupting the flow of commerce. Tunable mid-IR laser technology offers the opportunity to detect explosives and other chemicals remotely and quickly. Most chemical compounds, including explosives, have their fundamental vibrational modes in the mid-infrared region (3 to 15μm). There are a variety of techniques that focus on examining interactions that have proven effective in the laboratory but could never work in the field due to complexity, size, reliability and cost. Daylight Solutions has solved these problems by integrating quantum cascade gain media into external tunable cavities. This has resulted in miniaturized, broadly tunable mid-IR laser sources. The laser sources have a capability to tune to +/- 5% of their center wavelength, which means they can sweep through an entire absorption spectrum to ensure very good detection and false alarm performance compared with fixed wavelength devices. These devices are also highly portable, operate at room temperature, and generate 10's to 100's of mW in optical power, in pulsed and continuous wave configurations. Daylight Solutions is in the process of developing a variety of standoff explosive and chemical weapon detection systems using this technology.

An Online Change of Activity in Energy Spectrum for Detection on an Early Intervention Robot

DOE Office of Scientific and Technical Information (OSTI.GOV)

Boudergui, K.; Laine, F.; Montagu, T.

With the growth of industrial risks and the multiplication of CBRNe (Chemical Biological Radiological and explosive) attacks through toxic chemicals, biological or radiological threats, public services and military authorities face with increasingly critical situations, whose management is strongly conditioned by fast and reliable establishment of an informative diagnostic. Right after an attack, the five first minutes are crucial to define the various scenarios and the most dangerous for a human intervention. Therefore the use of robots is considered essential by all stakeholders of security. In this context, the SISPEO project (Systeme d'Intervention Sapeurs Pompiers Robotise) aims to create/build/design a robustmore » response through a robotic platform for early intervention services such as civil and military security in hostile environments. CEA LIST has proposed an adapted solution to detect and characterize nuclear and radiological risks online and in motion, using a miniature embedded CdZnTe (CZT) crystal Gamma-ray spectrometer. This paper presents experimental results for this miniature embedded CZT spectrometer and its associated mathematical method to detect and characterize radiological threats online and in motion. (authors)« less

The application of single particle aerosol mass spectrometry for the detection and identification of high explosives and chemical warfare agents

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martin, Audrey Noreen

2006-01-01

Single Particle Aerosol Mass Spectrometry (SPAMS) was evaluated as a real-time detection technique for single particles of high explosives. Dual-polarity time-of-flight mass spectra were obtained for samples of 2,4,6-trinitrotoluene (TNT), 1,3,5-trinitro-1,3,5-triazinane (RDX), and pentaerythritol tetranitrate (PETN); peaks indicative of each compound were identified. Composite explosives, Comp B, Semtex 1A, and Semtex 1H were also analyzed, and peaks due to the explosive components of each sample were present in each spectrum. Mass spectral variability with laser fluence is discussed. The ability of the SPAMS system to identify explosive components in a single complex explosive particle (~1 pg) without the need formore » consumables is demonstrated. SPAMS was also applied to the detection of Chemical Warfare Agent (CWA) simulants in the liquid and vapor phases. Liquid simulants for sarin, cyclosarin, tabun, and VX were analyzed; peaks indicative of each simulant were identified. Vapor phase CWA simulants were adsorbed onto alumina, silica, Zeolite, activated carbon, and metal powders which were directly analyzed using SPAMS. The use of metal powders as adsorbent materials was especially useful in the analysis of triethyl phosphate (TEP), a VX stimulant, which was undetectable using SPAMS in the liquid phase. The capability of SPAMS to detect high explosives and CWA simulants using one set of operational conditions is established.« less

Merging Infrasound and Electromagnetic Signals as a Means for Nuclear Explosion Detection

NASA Astrophysics Data System (ADS)

Ashkenazy, Joseph; Lipshtat, Azi; Kesar, Amit S.; Pistinner, Shlomo; Ben Horin, Yochai

2016-04-01

The infrasound monitoring network of the CTBT consists of 60 stations. These stations are capable of detecting atmospheric events, and may provide approximate location within time scale of a few hours. However, the nature of these events cannot be deduced from the infrasound signal. More than two decades ago it was proposed to use the electromagnetic pulse (EMP) as a means of discriminating nuclear explosion from other atmospheric events. An EMP is a unique signature of nuclear explosion and is not detected from chemical ones. Nevertheless, it was decided to exclude the EMP technology from the official CTBT verification regime, mainly because of the risk of high false alarm rate, due to lightning electromagnetic pulses [1]. Here we present a method of integrating the information retrieved from the infrasound system with the EMP signal which enables us to discriminate between lightning discharges and nuclear explosions. Furthermore, we show how spectral and other characteristics of the electromagnetic signal emitted from a nuclear explosion are distinguished from those of lightning discharge. We estimate the false alarm probability of detecting a lightning discharge from a given area of the infrasound event, and identifying it as a signature of a nuclear explosion. We show that this probability is very low and conclude that the combination of infrasound monitoring and EMP spectral analysis may produce a reliable method for identifying nuclear explosions. [1] R. Johnson, Unfinished Business: The Negotiation of the CTBT and the End of Nuclear Testing, United Nations Institute for Disarmament Research, 2009.

Direct analysis in real time mass spectrometry of potential by-products from homemade nitrate ester explosive synthesis.

PubMed

Sisco, Edward; Forbes, Thomas P

2016-04-01

This work demonstrates the coupling of direct analysis in real time (DART) ionization with time-of-flight mass spectrometry (MS) in an off-axis configuration for the trace detection and analysis of potential partially nitrated and dimerized by-products of homemade nitrate ester explosive synthesis. Five compounds relating to the synthesis of nitroglycerin (NG) and pentaerythritol tetranitrate (PETN) were examined. Deprotonated ions and adducts with molecular oxygen, nitrite, and nitrate were observed in the mass spectral responses of these compounds. A global optimum temperature of 350 °C for the by-products investigated here enabled single nanogram to sub nanogram trace detection. Matrix effects were examined through a series of mixtures containing one or more compounds (sugar alcohol precursors, by-products, and/or explosives) across a range of mass loadings. The explosives MS responses experienced competitive ionization in the presence of all by-products. The magnitude of this influence corresponded to both the degree of by-product nitration and the relative mass loading of the by-product to the explosive. This work provides a characterization of potential by-products from homemade nitrate ester synthesis, including matrix effects and potential challenges that might arise from the trace detection of homemade explosives (HMEs) containing impurities. Detection and understanding of HME impurities and complex mixtures may provide valuable information for the screening and sourcing of homemade nitrate ester explosives. Published by Elsevier B.V.

Evaluating the Capability of High-Altitude Infrasound Platforms to Cover Gaps in Existing Networks.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Bowman, Daniel

A variety of Earth surface and atmospheric sources generate low frequency sound waves that can travel great distances. Despite a rich history of ground-based sensor studies, very few experiments have investigated the prospects of free floating microphone arrays at high altitudes. However, recent initiatives have shown that such networks have very low background noise and may sample an acoustic wave field that is fundamentally different than that at the Earth's surface. The experiments have been limited to at most two stations at altitude, limiting their utility in acoustic event detection and localization. We describe the deployment of five drifting microphonemore » stations at altitudes between 21 and 24 km above sea level. The stations detected one of two regional ground-based explosions as well as the ocean microbarom while traveling almost 500 km across the American Southwest. The explosion signal consisted of multiple arrivals; signal amplitudes did not correlate with sensor elevation or source range. A sparse network method that employed curved wave front corrections was able to determine the backazimuth from the free flying network to the acoustic source. Episodic broad band signals similar to those seen on previous flights in the same region were noted as well, but their source remains unclear. Background noise levels were commensurate with those on infrasound stations in the International Monitoring System (IMS) below 2 seconds, but sensor self noise appears to dominate at higher frequencies.« less

Physical explosion analysis in heat exchanger network design

NASA Astrophysics Data System (ADS)

Pasha, M.; Zaini, D.; Shariff, A. M.

2016-06-01

The failure of shell and tube heat exchangers is being extensively experienced by the chemical process industries. This failure can create a loss of production for long time duration. Moreover, loss of containment through heat exchanger could potentially lead to a credible event such as fire, explosion and toxic release. There is a need to analyse the possible worst case effect originated from the loss of containment of the heat exchanger at the early design stage. Physical explosion analysis during the heat exchanger network design is presented in this work. Baker and Prugh explosion models are deployed for assessing the explosion effect. Microsoft Excel integrated with process design simulator through object linking and embedded (OLE) automation for this analysis. Aspen HYSYS V (8.0) used as a simulation platform in this work. A typical heat exchanger network of steam reforming and shift conversion process was presented as a case study. It is investigated from this analysis that overpressure generated from the physical explosion of each heat exchanger can be estimated in a more precise manner by using Prugh model. The present work could potentially assist the design engineer to identify the critical heat exchanger in the network at the preliminary design stage.

Ultrasensitive detection of explosives and chemical warfare agents by low-pressure photoionization mass spectrometry.

PubMed

Sun, Wanqi; Liang, Miao; Li, Zhen; Shu, Jinian; Yang, Bo; Xu, Ce; Zou, Yao

2016-08-15

On-spot monitoring of threat agents needs high sensitive instrument. In this study, a low-pressure photoionization mass spectrometer (LPPI-MS) was employed to detect trace amounts of vapor-phase explosives and chemical warfare agent mimetics under ambient conditions. Under 10-s detection time, the limits of detection of 2,4-dinitrotoluene, nitrotoluene, nitrobenzene, and dimethyl methyl phosphonate were 30, 0.5, 4, and 1 parts per trillion by volume, respectively. As compared to those obtained previously with PI mass spectrometric techniques, an improvement of 3-4 orders of magnitude was achieved. This study indicates that LPPI-MS will open new opportunities for the sensitive detection of explosives and chemical warfare agents. Copyright © 2016 Elsevier B.V. All rights reserved.

Detection of bottled explosives by near infrared

NASA Astrophysics Data System (ADS)

Itozaki, Hideo; Sato-Akaba, Hideo

2013-10-01

Bottled liquids are not allowed through the security gate in the airport, because liquid explosives have been used by the terrorists. However, passengers have a lot of trouble if they cannot bring their own bottles. For example, a mother would like to carry her own milk in the airplane for her baby. Therefore the detection technology of liquid explosives should be developed as soon as possible. This paper shows that near infrared spectroscopy can detect bottled explosives quickly. The transmission method cannot deal with milk in the sense of liquid inspection. Here we examined the reflection method to the test of milk. The inspection method with light cannot make test for the metal can. We also use ultrasonic method to check metal can simultaneously in order to expand test targets.

Spectroscopic characterization of nitroaromatic landmine signature explosives

NASA Astrophysics Data System (ADS)

Hernandez-Rivera, Samuel P.; Manrique-Bastidas, Cesar A.; Blanco, Alejandro; Primera, Oliva M.; Pacheco, Leonardo C.; Castillo-Chara, Jairo; Castro, Miguel E.; Mina, Nairmen

2004-09-01

TNT and DNT are important explosives used as base charges of landmines and other explosive devices. They are often combined with RDX in specific explosive formulations. Their detection in vapor phase as well as in soil in contact with the explosives is important in landmine detection technology. The spectroscopic signatures of nitroaromatic compounds in neat forms: crystals, droplets, and recrystallized samples were determined by Raman Microspectroscopy (RS), Fourier Transform Infrared Microscopy (FTIR) and Fiber Optics Coupled - Fourier Transform Infrared Spectroscopy (FOC-FTIR) using a grazing angle (GA) probe. TNT exhibits a series of characteristic bands: vibrational signatures, which allow its detection in soil. The spectroscopic signature of neat TNT is dominated by strong bands about 1380 and 2970 cm-1. The intensity and position of these bands were found remarkably different in soil samples spiked with TNT. The 1380 cm-1 band is split into a number of bands in that region. The 2970 cm-1 band is reduced in intensity and new bands are observed about 2880 cm-1. The results are consistent with a different chemical environment of TNT in soil as compared to neat TNT. Interactions were found to be dependent on the physical source of the explosive. In the case of DNT-sand interactions, shifts in vibrational frequencies of the explosives as well as the substrates were found.

Characterization of high explosive particles using cluster secondary ion mass spectrometry.

PubMed

Gillen, Greg; Mahoney, Christine; Wight, Scott; Lareau, Richard

2006-01-01

The use of secondary ion mass spectrometry (SIMS) for the detection and spatially resolved analysis of individual high explosive particles is described. A C(8) (-) carbon cluster primary ion beam was used in a commercial SIMS instrument to analyze samples of high explosives dispersed as particles on silicon substrates. In comparison with monatomic primary ion bombardment, the carbon cluster primary ion beam was found to greatly enhance characteristic secondary ion signals from the explosive compounds while causing minimal beam-induced degradation. The resistance of these compounds to degradation under ion bombardment allows explosive particles to be analyzed under high primary ion dose bombardment (dynamic SIMS) conditions, facilitating the rapid acquisition of spatially resolved molecular information. The use of cluster SIMS combined with computer control of the sample stage position allows for the automated identification and counting of explosive particle distributions on silicon surfaces. This will be useful for characterizing the efficiency of transfer of particulates in trace explosive detection portal collectors and/or swipes utilized for ion mobility spectrometry applications.

The discrimination of man-made explosions from earthquakes using seismo-acoustic analysis in the Korean Peninsula

NASA Astrophysics Data System (ADS)

Che, Il-Young; Jeon, Jeong-Soo

2010-05-01

Korea Institute of Geoscience and Mineral Resources (KIGAM) operates an infrasound network consisting of seven seismo-acoustic arrays in South Korea. Development of the arrays began in 1999, partially in collaboration with Southern Methodist University, with the goal of detecting distant infrasound signals from natural and anthropogenic phenomena in and around the Korean Peninsula. The main operational purpose of this network is to discriminate man-made seismic events from seismicity including thousands of seismic events per year in the region. The man-made seismic events are major cause of error in estimating the natural seismicity, especially where the seismic activity is weak or moderate such as in the Korean Peninsula. In order to discriminate the man-made explosions from earthquakes, we have applied the seismo-acoustic analysis associating seismic and infrasonic signals generated from surface explosion. The observations of infrasound at multiple arrays made it possible to discriminate surface explosion, because small or moderate size earthquake is not sufficient to generate infrasound. Till now we have annually discriminated hundreds of seismic events in seismological catalog as surface explosions by the seismo-acoustic analysis. Besides of the surface explosions, the network also detected infrasound signals from other sources, such as bolide, typhoons, rocket launches, and underground nuclear test occurred in and around the Korean Peninsula. In this study, ten years of seismo-acoustic data are reviewed with recent infrasonic detection algorithm and association method that finally linked to the seismic monitoring system of the KIGAM to increase the detection rate of surface explosions. We present the long-term results of seismo-acoustic analysis, the detection capability of the multiple arrays, and implications for seismic source location. Since the seismo-acoustic analysis is proved as a definite method to discriminate surface explosion, the analysis will be continuously used for estimating natural seismicity and understanding infrasonic sources.

Trace Explosives Signatures from World War II Unexploded Undersea Ordnance

NASA Technical Reports Server (NTRS)

Darrach, M. R.; Chutjian, A.; Plett, G. A.

1998-01-01

Trace explosives signatures of TNT and DNT have been extracted from multiple sediment samples adjacent to unexploded undersea ordnance at Halifax Harbor, Canada. The ordnance was hurled into the harbor during a massive explosion some 50 years earlier, in 1945 after World War II had ended. Laboratory sediment extractions were made using the solid-phase microextraction (SPME) method in seawater and detection using the Reversal Electron Attachment Detection (READ) technique and, in the case of DNT, a commercial gas chromatograph/mass spectrometer (GC/MS). Results show that, after more than 50 years in the environment, ordnance that appeared to be physically intact gave good explosives signatures at the parts per billion level, whereas ordnance that had been cracked open during the explosion gave no signatures at the 10 parts per trillion sensitivity level. These measurements appear to provide the first reported data of explosives signatures from undersea unexploded ordnance.

Automated detection and cataloging of global explosive volcanism using the International Monitoring System infrasound network

NASA Astrophysics Data System (ADS)

Matoza, Robin S.; Green, David N.; Le Pichon, Alexis; Shearer, Peter M.; Fee, David; Mialle, Pierrick; Ceranna, Lars

2017-04-01

We experiment with a new method to search systematically through multiyear data from the International Monitoring System (IMS) infrasound network to identify explosive volcanic eruption signals originating anywhere on Earth. Detecting, quantifying, and cataloging the global occurrence of explosive volcanism helps toward several goals in Earth sciences and has direct applications in volcanic hazard mitigation. We combine infrasound signal association across multiple stations with source location using a brute-force, grid-search, cross-bearings approach. The algorithm corrects for a background prior rate of coherent unwanted infrasound signals (clutter) in a global grid, without needing to screen array processing detection lists from individual stations prior to association. We develop the algorithm using case studies of explosive eruptions: 2008 Kasatochi, Alaska; 2009 Sarychev Peak, Kurile Islands; and 2010 Eyjafjallajökull, Iceland. We apply the method to global IMS infrasound data from 2005-2010 to construct a preliminary acoustic catalog that emphasizes sustained explosive volcanic activity (long-duration signals or sequences of impulsive transients lasting hours to days). This work represents a step toward the goal of integrating IMS infrasound data products into global volcanic eruption early warning and notification systems. Additionally, a better understanding of volcanic signal detection and location with the IMS helps improve operational event detection, discrimination, and association capabilities.

Chemosensors for detection of nitroaromatic compounds (explosives)

NASA Astrophysics Data System (ADS)

Zyryanov, G. V.; Kopchuk, D. S.; Kovalev, I. S.; Nosova, E. V.; Rusinov, V. L.; Chupakhin, O. N.

2014-09-01

The key types of low-molecular-mass chemosensors for the detection of nitroaromatic compounds representing energetic substances (explosives) are analyzed. The coordination and chemical properties of these chemosensors and structural features of their complexes with nitroaromatic compounds are considered. The causes and methods for attaining high selectivity of recognition are demonstrated. The primary attention is paid to the use of low-molecular-mass chemosensors for visual detection of explosives of this class by colorimetric and photometric methods. Examples of using photo- and chemiluminescence for this purpose are described. A separate section is devoted to electrochemical methods of detection of nitroaromatic compounds. Data published from 2000 to 2014 are mainly covered. The bibliography includes 245 references.

Genomic Medicine and Lung Diseases

PubMed Central

Center, David M.; Schwartz, David A.; Solway, Julian; Gail, Dorothy; Laposky, Aaron D.

2012-01-01

The recent explosion of genomic data and technology points to opportunities to redefine lung diseases at the molecular level; to apply integrated genomic approaches to elucidate mechanisms of lung pathophysiology; and to improve early detection, diagnosis, and treatment of lung diseases. Research is needed to translate genomic discoveries into clinical applications, such as detecting preclinical disease, predicting patient outcomes, guiding treatment choices, and most of all identifying potential therapeutic targets for lung diseases. The Division of Lung Diseases in the National Heart, Lung, and Blood Institute convened a workshop, “Genomic Medicine and Lung Diseases,” to discuss the potential for integrated genomics and systems approaches to advance 21st century pulmonary medicine and to evaluate the most promising opportunities for this next phase of genomics research to yield clinical benefit. Workshop sessions included (1) molecular phenotypes, molecular biomarkers, and therapeutics; (2) new technology and opportunity; (3) integrative genomics; (4) molecular anatomy of the lung; (5) novel data and information platforms; and (6) recommendations for exceptional research opportunities in lung genomics research. PMID:22652029

Analysis of Explosives in Soil Using Solid Phase Microextraction and Gas Chromatography: Environmental Analysis

DTIC Science & Technology

2006-01-01

ENVIRONMENTAL ANALYSIS Analysis of Explosives in Soil Using Solid Phase Microextraction and Gas Chromatography Howard T. Mayfield Air Force Research...Abstract: Current methods for the analysis of explosives in soils utilize time consuming sample preparation workups and extractions. The method detection...chromatography/mass spectrometry to provide a con- venient and sensitive analysis method for explosives in soil. Keywords: Explosives, TNT, solid phase

Wireless sensors and sensor networks for homeland security applications.

PubMed

Potyrailo, Radislav A; Nagraj, Nandini; Surman, Cheryl; Boudries, Hacene; Lai, Hanh; Slocik, Joseph M; Kelley-Loughnane, Nancy; Naik, Rajesh R

2012-11-01

New sensor technologies for homeland security applications must meet the key requirements of sensitivity to detect agents below risk levels, selectivity to provide minimal false-alarm rates, and response speed to operate in high throughput environments, such as airports, sea ports, and other public places. Chemical detection using existing sensor systems is facing a major challenge of selectivity. In this review, we provide a brief summary of chemical threats of homeland security importance; focus in detail on modern concepts in chemical sensing; examine the origins of the most significant unmet needs in existing chemical sensors; and, analyze opportunities, specific requirements, and challenges for wireless chemical sensors and wireless sensor networks (WSNs). We further review a new approach for selective chemical sensing that involves the combination of a sensing material that has different response mechanisms to different species of interest, with a transducer that has a multi-variable signal-transduction ability. This new selective chemical-sensing approach was realized using an attractive ubiquitous platform of battery-free passive radio-frequency identification (RFID) tags adapted for chemical sensing. We illustrate the performance of RFID sensors developed in measurements of toxic industrial materials, humidity-independent detection of toxic vapors, and detection of chemical-agent simulants, explosives, and strong oxidizers.

Stand-off detection of explosive particles by imaging Raman spectroscopy

NASA Astrophysics Data System (ADS)

Nordberg, Markus; Åkeson, Madeleine; Östmark, Henric; Carlsson, Torgny E.

2011-06-01

A multispectral imaging technique has been developed to detect and identify explosive particles, e.g. from a fingerprint, at stand-off distances using Raman spectroscopy. When handling IED's as well as other explosive devices, residues can easily be transferred via fingerprints onto other surfaces e.g. car handles, gear sticks and suite cases. By imaging the surface using multispectral imaging Raman technique the explosive particles can be identified and displayed using color-coding. The technique has been demonstrated by detecting fingerprints containing significant amounts of 2,4-dinitrotoulene (DNT), 2,4,6-trinitrotoulene (TNT) and ammonium nitrate at a distance of 12 m in less than 90 seconds (22 images × 4 seconds)1. For each measurement, a sequence of images, one image for each wave number, is recorded. The spectral data from each pixel is compared with reference spectra of the substances to be detected. The pixels are marked with different colors corresponding to the detected substances in the fingerprint. The system has now been further developed to become less complex and thereby less sensitive to the environment such as temperature fluctuations. The optical resolution has been improved to less than 70 μm measured at 546 nm wavelength. The total detection time is ranging from less then one minute to around five minutes depending on the size of the particles and how confident the identification should be. The results indicate a great potential for multi-spectral imaging Raman spectroscopy as a stand-off technique for detection of single explosive particles.

Contributions of Nimbus 7 TOMS Data to Volcanic Study and Hazard Mitigation

NASA Technical Reports Server (NTRS)

Krueger, Arlin J.; Bluth, G. J. S.; Schaefer, S. A.

1998-01-01

Nimbus TOMS data have led to advancements among many volcano-related scientific disciplines, from the initial ability to quantify SO2 clouds leading to derivations of eruptive S budgets and fluxes, to tracking of individual clouds, assessing global volcanism and atmospheric impacts. Some of the major aspects of TOMS-related research, listed below, will be reviewed and updated: (1) Measurement of volcanic SO2 clouds: Nimbus TOMS observed over 100 individual SO2 clouds during its mission lifetime; large explosive eruptions are now routinely and reliably measured by satellite. (2) Eruption processes: quantification of SO2 emissions have allowed assessments of eruption sulfur budgets, the evaluation of "excess" sulfur, and inferences of H2S emissions. (3) Detection of ash: TOMS data are now used to detect volcanic particulates in the atmosphere, providing complementary analyses to infrared methods of detection. Paired TOMS and AVHRR studies have provided invaluable information on volcanic cloud compositions and processes. (4) Cloud tracking and hazard mitigation: volcanic clouds can be considered gigantic tracers in the atmosphere, and studies of the fates of these clouds have led to new knowledge of their physical and chemical dispersion in the atmosphere for predictive models. (5) Global trends: the long term data set has provided researchers an unparalleled record of explosive volcanism, and forms a key component in assessing annual to decadal trends in global S emissions. (6) Atmospheric impacts: TOMS data have been linked to independent records of atmospheric change, in order to compare cause and effect processes following a massive injection of SO2 into the atmosphere. (7) Future TOMS instruments and applications: Nimbus TOMS has given way to new satellite platforms, with several wavelength and resolution modifications. New efforts to launch a geostationary TOMS could provide unprecedented observations of volcanic activity.

Phased Contrast X-Ray Imaging

ScienceCinema

Miller, Erin

2018-02-07

The Pacific Northwest National Laboratory is developing a range of technologies to broaden the field of explosives detection. Phased contrast X-ray imaging, which uses silicon gratings to detect distortions in the X-ray wave front, may be applicable to mail or luggage scanning for explosives; it can also be used in detecting other contraband, small-parts inspection, or materials characterization.

Nanomaterial-Based Biosensors for Detection of Pesticides and Explosives

DOE Office of Scientific and Technical Information (OSTI.GOV)

Wang, Jun; Lin, Yuehe

2009-01-01

In this chapter, we describe nanomaterial-based biosensors for detecting OP pesticides and explosives. CNTs and functionalized silica nanoparticles have been chosen for this study. The biosensors were combined with the flow-injection system, providing great advantages for onsite, real-time, and continuous detection of environmental pollutants such as OPs and TNT. The sensors take advantage of the electrocatalytic properties of CNTs, which makes it feasible to achieve a sensitive electrochemical detection of the products from enzymatic reactions at low potential. This approach uses a large aspect ratio of silica nanoparticles, which can be used as a carrier for loading a large amountmore » of electroactive species, such as poly(guanine), for amplified detection of explosives. These methods offer a new environmental monitoring tool for rapid, inexpensive, and highly sensitive detection of OPs or TNT compounds.« less

Reducing cross-sensitivity of TiO2-(B) nanowires to humidity using ultraviolet illumination for trace explosive detection.

PubMed

Wang, Danling; Chen, Antao; Jen, Alex K-Y

2013-04-14

Environmental humidity is an important factor that can influence the sensing performance of a metal oxide. TiO2-(B) in the form of nanowires has been demonstrated to be a promising material for the detection of explosive gases such as 2,4,6-trinitrotoluene (TNT). However, the elimination of cross-sensitivity of the explosive detectors based on TiO2-(B) toward environmental humidity is still a major challenge. It was found that the cross-sensitivity could be effectively modulated when the thin film of TiO2-(B) nanowires was exposed to ultraviolet (UV) light during the detection of explosives under operating conditions. Such a modulation of sensing responses of TiO2-(B) nanowires to explosives by UV light was attributed to a photocatalytic effect, with which the water adsorbed on the TiO2-(B) nanowire surface was split and therefore the sensor response performance was less affected. It was revealed that the cross-sensitivity could be suppressed up to 51% when exposed to UV light of 365 nm wavelength with an intensity of 40 mW cm(-2). This finding proves that the reduction of cross-sensitivity to humidity through UV irradiation is an effective approach that can improve the performance of a sensor based on TiO2-(B) nanowires for the detection of explosive gas.

Study of thermal decomposition mechanisms and low-level detection of explosives using pulsed photoacoustic technique

NASA Astrophysics Data System (ADS)

Yehya, F.; Chaudhary, A. K.; Srinivas, D.; Muralidharan, K.

2015-11-01

We report a novel time-resolved photoacoustic-based technique for studying the thermal decomposition mechanisms of some secondary explosives such as RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine), picric acid, 4,6-dinitro-5-(4-nitro-1 H-imidazol-1-yl)-1 H-benzo[ d] [1-3] triazole, and 5-chloro-1-(4-nitrophenyl)-1 H-tetrazole. A comparison of the thermal decomposition mechanisms of these secondary explosives was made by detecting NO2 molecules released under controlled pyrolysis between 25 and 350 °C. The results show excellent agreement with the thermogravimetric and differential thermal analysis (TGA-DTA) results. A specially designed PA cell made of stainless steel was filled with explosive vapor and pumped using second harmonic, i.e., λ = 532 nm, pulses of duration 7 ns at a 10 Hz repetition rate, obtained using a Q-switched Nd:YAG laser. The use of a combination of PA and TGA-DTA techniques enables the study of NO2 generation, and this method can be used to scale the performance of these explosives as rocket fuels. The minimum detection limits of the four explosives were 38 ppmv to 69 ppbv, depending on their respective vapor pressures.

The Comprehensive Nuclear Test Ban Treaty (Counterproliferation Papers, Future Warfare Series, Number 54)

DTIC Science & Technology

2010-06-01

parts to detect a nuclear explosion: seismic, hydroacoustic, infrasound and radionuclide. Figure 3. CTBTO International Monitoring System Sites26...Conference,” (Oct. 14, 2009), www.armscontrol.org.. [17] from earthquakes and mining explosions, but have proved effective in detecting past nuclear...hydroacoustic monitoring stations detect sound waves in the oceans, and the 60 infrasound stations detect above ground, ultra-low frequency sound waves

Detection of explosives, shielded nuclear materials and other hazardous substances in cargo containers

NASA Astrophysics Data System (ADS)

Kuznetsov, Andrey; Evsenin, Alexey; Vakhtin, Dmitry; Gorshkov, Igor; Osetrov, Oleg; Kalinin, Valery

2006-05-01

Nanosecond Neutron Analysis / Associated Particles Technique (NNA/APT) has been used to create devices for detection of explosives, radioactive and heavily shielded nuclear materials in cargo containers. Explosives and other hazardous materials are detected by analyzing secondary high-energy gamma-rays form reactions of fast neutrons with the materials inside the container. Depending on the dimensions of the inspected containers, the detecting system consists of one or several detection modules, each of which contains a small neutron generator with built-in position sensitive detector of associated alpha-particles and several scintillator-based gamma-ray detectors. The same gamma-ray detectors are used to detect unshielded radioactive and nuclear materials. Array of several detectors of fast neutrons is used to detect neutrons from spontaneous and induced fission of nuclear materials. These neutrons can penetrate thick layers of lead shielding, which can be used to conceal gamma-radioactivity from nuclear materials. Coincidence and timing analysis allows one to discriminate between fission neutrons and scattered probing neutrons. Mathematical modeling by MCNP5 code was used to estimate the sensitivity of the device and its optimal configuration. Capability of the device to detect 1 kg of explosive imitator inside container filled with suitcases and other baggage items has been confirmed experimentally. First experiments with heavily shielded nuclear materials have been carried out.

Explosives (and other threats) detection using pulsed neutron interrogation and optimized detectors

NASA Astrophysics Data System (ADS)

Strellis, Dan A.; Elsalim, Mashal; Gozani, Tsahi

2011-06-01

We have previously reported results from a human-portable system using neutron interrogation to detect contraband and explosives. We summarized our methodology for distinguishing threat materials such as narcotics, C4, and mustard gas in the myriad of backgrounds present in the maritime environment. We are expanding our mission for the Domestic Nuclear Detection Office (DNDO) to detect Special Nuclear Material (SNM) through the detection of multiple fission signatures without compromising the conventional threat detection performance. This paper covers our initial investigations into using neutrons from compact pulsed neutron generators via the d(D,n)3He or d(T,n)α reactions with energies of ~2.5 and 14 MeV, respectively, for explosives (and other threats) detection along with a variety of gamma-ray detectors. Fast neutrons and thermal neutrons (after successive collisions) can stimulate the emission of various threat detection signatures. For explosives detection, element-specific gamma-ray signatures via the (n,n'γ) inelastic scattering reaction and the (n,'γ) thermal capture reaction are detected. For SNM, delayed gamma-rays following fission can be measured with the same detector. Our initial trade-off investigations of several gamma-ray detectors types (NaI, CsI, LaBr3, HPGe) for measuring gamma-ray signatures in a pulsed neutron environment for potential application in a human-portable active interrogation system are covered in this paper.

Genetically engineered microorganisms for the detection of explosives’ residues

PubMed Central

Shemer, Benjamin; Palevsky, Noa; Yagur-Kroll, Sharon; Belkin, Shimshon

2015-01-01

The manufacture and use of explosives throughout the past century has resulted in the extensive pollution of soils and groundwater, and the widespread interment of landmines imposes a major humanitarian risk and prevents civil development of large areas. As most current landmine detection technologies require actual presence at the surveyed areas, thus posing a significant risk to personnel, diverse research efforts are aimed at the development of remote detection solutions. One possible means proposed to fulfill this objective is the use of microbial bioreporters: genetically engineered microorganisms “tailored” to generate an optical signal in the presence of explosives’ vapors. The use of such sensor bacteria will allow to pinpoint the locations of explosive devices in a minefield. While no study has yet resulted in a commercially operational system, significant progress has been made in the design and construction of explosives-sensing bacterial strains. In this article we review the attempts to construct microbial bioreporters for the detection of explosives, and analyze the steps that need to be undertaken for this strategy to be applicable for landmine detection. PMID:26579085

ASTER Views the Gulf of Mexico Oil Spill in Infrared May 1

NASA Image and Video Library

2010-05-04

NASA Terra spacecraft captured this image of the growing oil spill in the Gulf of Mexico on May 1, 2010. On April 20, 2010, an explosion destroyed the Deepwater Horizon oil platform operating offshore in the Gulf of Mexico.

GIS Story Maps : A Tool to Empower and Engage Stakeholders in Planning Sustainable Places

DOT National Transportation Integrated Search

2016-10-01

Public engagement continues to be transformed by the explosion of new digital technologies/tools, software platforms, social media networks, mobile devices, and mobile apps. Recent changes in geospatial technology offer new opportunities for use in p...

UV Raman detection of 2,4-DNT in contact with sand particles

NASA Astrophysics Data System (ADS)

Blanco, Alejandro; Pacheco-Londoño, Leonardo C.; Peña-Quevedo, Alvaro J.; Hernández-Rivera, Samuel P.

2006-05-01

Deep Ultra Violet Raman Spectroscopy (DUV-RS) is an emerging tool for vibrational spectroscopy analysis and can be used in Point Detection mode to detect explosive components of landmines and Improvised Explosive Devices (IED). Interactions of explosives with different substrates can be measured by using quantitative vibrational signal shift information of scattered Raman light associated with these interactions. In this research, grounds were laid for detection of explosives using UV-Raman Spectroscopy equipped with 244 nm laser excitation line from a 488 nm frequency doubled Coherent FreD laser. In other experiments, samples of 2,4-DNT were allowed to interact with Ottawa Sand and were studied using DUV-RS. Characteristic vibrational signals of energetic compounds were analyzed in the ranges: 400-1200 cm -1, 1200-1800 cm -1, and 2800-3500 cm -1. In addition these Raman spectra were compared with dispersive spectra that were acquired using Raman Microscopy equipped with 514.5 nm (VIS) 785 nm (NIR) and 1064 nm (NIR) excitation lasers.

The use of triangle diagram in the detection of explosive and illicit drugs

NASA Astrophysics Data System (ADS)

Sudac, Davorin; Baricevic, Martina; Obhodas, Jasmina; Franulovic, Andrej; Valkovic, Vladivoj

2010-04-01

A tagged neutron inspection system has been used for the detection of explosive and illicite drugs. Simulant of the RDX explosive was measured in different environments and its gamma ray spectra were compared with the gamma ray spectra of benign materials like paper, sugar and rise. "Fingerprint" of the RDX simulant was found by detecting the nitrogen as well as by making the triangle plot which coordinates show the carbon and oxygen content and density. Density was obtained by measuring the intensity of the transmited tagged neutrons. Hence, the presence of the simulant can be confirmed by using two different methods. The possibility of using the triangle plot for detection of illicit drugs like heroin, cocain and marihuana is also discused.

Monte Carlo Simulation of Soil Moisture Effects on Anti-Tank Landmines Detection by Neutron Backscattering Technique

NASA Astrophysics Data System (ADS)

Mowlawi, Ali Asghar; Yazdani, Majed

The detection of landmines using available technologies is a time consuming, expensive, and extremely dangerous job, so that there is a need for technological breakthroughs in this field. One of the safest and most effective technologies to landmine and explosive detection is the neutron backscattering technique. The slowing-down of fast neutrons to the thermal energy is a direct measure of the concentration of hydrogen, one of the main elements present in explosive materials. The elastic scattering of fast neutrons is affected by the strong resonances in the cross-section of the three other elements of explosives: nitrogen, oxygen, and carbon. In this work, Monte Carlo estimations of the soil moisture effects on landmine detection are presented.

Laser desorption with corona discharge ion mobility spectrometry for direct surface detection of explosives.

PubMed

Sabo, M; Malásková, M; Matejčík, S

2014-10-21

We present a new highly sensitive technique for the detection of explosives directly from the surface using laser desorption-corona discharge-ion mobility spectrometry (LD-CD-IMS). We have developed LD based on laser diode modules (LDM) and the technique was tested using three different LDM (445, 532 and 665 nm). The explosives were detected directly from the surface without any further preparation. We discuss the mechanism of the LD and the limitations of this technique such as desorption time, transport time and desorption area. After the evaluation of experimental data, we estimated the potential limits of detection of this method to be 0.6 pg for TNT, 2.8 pg for RDX and 8.4 pg for PETN.

Challenge of false alarms in nitroaromatic explosive detection--a detection device based on surface-enhanced Raman spectroscopy.

PubMed

Wackerbarth, Hainer; Gundrum, Lars; Salb, Christian; Christou, Konstantin; Viöl, Wolfgang

2010-08-10

A challenge in the detection of explosives is the differentiation between explosives and contaminants. Synthetic musk-containing perfumes can cause false alarms, as these perfumes are nitroaromatic compounds, which can be mistaken for trinitro toluene (TNT) by some detectors. We present a detection principle based on surface-enhanced Raman scattering (SERS). A stream of the airborne compounds is focused and resublimated on a cooled nanostructured gold surface. We recorded high-resolution SERS spectra of TNT, musk xylene, and musk ketone. The nitroaromatic compounds can be identified unambiguously by their SERS spectra. Even the dominant bands containing nitro-group scissoring and symmetric stretching modes are significantly shifted by the difference in molecular structure.

Mesoporous aluminium organophosphonates: a reusable chemsensor for the detection of explosives

NASA Astrophysics Data System (ADS)

Li, Dongdong; Yu, Xiang

2016-07-01

Rapid and sensitive detection of explosives is in high demand for homeland security and public safety. In this work, electron-rich of anthracene functionalized mesoporous aluminium organophosphonates (En-AlPs) were synthesized by a one-pot condensation process. The mesoporous structure and strong blue emission of En-AlPs were confirmed by the N2 adsorption-desorption isotherms, transmission electron microscopy images and fluorescence spectra. The materials En-AlPs can serve as sensitive chemosensors for various electron deficient nitroderivatives, with the quenching constant and the detection limit up to 1.5×106 M-1 and 0.3 ppm in water solution. More importantly, the materials can be recycled for many times by simply washed with ethanol, showing potential applications in explosives detection.

Laser-Based Remote Sensing of Explosives by a Differential Absorption and Scattering Method

NASA Astrophysics Data System (ADS)

Ayrapetyan, V. S.

2018-01-01

A multifunctional IR parametric laser system is developed and tested for remote detection and identification of atmospheric gases, including explosive and chemically aggressive substances. Calculations and experimental studies of remote determination of the spectroscopic parameters of the best known explosive substances TNT, RDX, and PETN are carried out. The feasibility of high sensitivity detection ( 1 ppm) of these substances with the aid of a multifunctional IR parametric light source by differential absorption and scattering is demonstrated.

Noncontact optical detection of explosive particles via photodissociation followed by laser-induced fluorescence.

PubMed

Wynn, C M; Palmacci, S; Kunz, R R; Aernecke, M

2011-09-12

High-sensitivity (ng/cm²) optical detection of the explosive 2,4,6-trinitrotoluene (TNT) is demonstrated using photodissociation followed by laser-induced fluorescence (PD-LIF). Detection occurs rapidly, within 6 laser pulses (~7 ns each) at a range of 15 cm. Dropcasting is used to create calibrated samples covering a wide range of TNT concentrations; and a correspondence between fractional area covered by TNT and PD-LIF signal strength is observed. Dropcast data are compared to that of an actual fingerprint. These results demonstrate that PD-LIF could be a viable means of rapidly and remotely scanning surfaces for trace explosive residues.

Tunable infrared laser detection of pyrolysis products of explosives in soils

NASA Astrophysics Data System (ADS)

Wormhoudt, J.; Shorter, J. H.; McManus, J. B.; Kebabian, P. L.; Zahniser, M. S.; Kolb, Charles E.; Davis, W. M.; Cespedes, E. R.

1996-07-01

A research program involving two applications of tunable infrared laser differential absorption spectroscopy (TILDAS) with multipass, long-path absorption cells to the detection of explosives contamination in soils is reported. In the first application, sensitive, specific real-time species concentration measurements by TILDAS have led to new understanding of the processes involved in explosives detection by the heating of contaminated soils and the quantification of the resulting pyrolysis gases. In the second, we present results of our calculations of the properties of astigmatic off-axis resonator absorption cells, which show that useful TILDAS path lengths can be achieved inside a cone penetrometer probe.

Trace detection of perchlorate in industrial-grade emulsion explosive with portable surface-enhanced Raman spectroscopy.

PubMed

Nuntawong, N; Eiamchai, P; Limwichean, S; Wong-ek, B; Horprathum, M; Patthanasettakul, V; Leelapojanaporn, A; Nakngoenthong, S; Chindaudom, P

2013-12-10

Recent analyses by ion-exchange chromatography (IC) showed that, beside nitrate, the majority of the industrial-grade emulsion explosives, extensively used by most separatists in the southern Thailand insurgency, contained small traces of perchlorate anions. In demand for the faster, reliable, and simple detection methods, the portable detection of nitrate and perchlorate became the great interest for the forensic and field-investigators. This work proposed a unique method to detect the trace amount of perchlorate in seven industrial-grade emulsion explosives under the field tests. We utilized the combination of the portable Raman spectroscope, the developed surfaced-enhanced Raman substrates, and the sample preparation procedures. The portable Raman spectroscope with a laser diode of 785 nm for excitation and a thermoelectric-cooled CCD spectrometer for detection was commercially available. The SERS substrates, with uniformly distributed nanostructured silver nanorods, were fabricated by the DC magnetron sputtering system, based on the oblique-angle deposition technique. The sample preparation procedures were proposed based on (1) pentane extraction technique and (2) combustion technique, prior to being dissolved in the purified water. In comparison to the ion chromatography and the conventional Raman measurements, our proposed methods successfully demonstrated the highly sensitive detectability of the minimal trace amount of perchlorate from five of the explosives with minimal operating time. This work was therefore highly practical to the development for the forensic analyses of the post-blast explosive residues under the field-investigations. Copyright © 2013 Elsevier Ireland Ltd. All rights reserved.

49 CFR 1544.103 - Form, content, and availability.

Code of Federal Regulations, 2013 CFR

2013-10-01

... regarding the use of explosives detection systems. (8) The procedures used to comply with the requirements... the introduction of explosives, incendiaries, or weapons aboard an aircraft. (2) Be in writing and... use of metal detection devices. (6) The procedures and description of the facilities and equipment...

49 CFR 1544.103 - Form, content, and availability.

Code of Federal Regulations, 2014 CFR

2014-10-01

... regarding the use of explosives detection systems. (8) The procedures used to comply with the requirements... the introduction of explosives, incendiaries, or weapons aboard an aircraft. (2) Be in writing and... use of metal detection devices. (6) The procedures and description of the facilities and equipment...

49 CFR 1544.103 - Form, content, and availability.

Code of Federal Regulations, 2012 CFR

2012-10-01

... regarding the use of explosives detection systems. (8) The procedures used to comply with the requirements... the introduction of explosives, incendiaries, or weapons aboard an aircraft. (2) Be in writing and... use of metal detection devices. (6) The procedures and description of the facilities and equipment...

77 FR 74201 - Intent to Request Renewal From OMB of One Current Public Collection of Information: National...

Federal Register 2010, 2011, 2012, 2013, 2014

2012-12-13

... DEPARTMENT OF HOMELAND SECURITY Transportation Security Administration Intent to Request Renewal From OMB of One Current Public Collection of Information: National Explosives Detection Canine Team.... Information Collection Requirement OMB Control Number 1652-0041; National Explosives Detection Canine Team...

Advanced shortwave infrared and Raman hyperspectral sensors for homeland security and law enforcement operations

NASA Astrophysics Data System (ADS)

Klueva, Oksana; Nelson, Matthew P.; Gardner, Charles W.; Gomer, Nathaniel R.

2015-05-01

Proliferation of chemical and explosive threats as well as illicit drugs continues to be an escalating danger to civilian and military personnel. Conventional means of detecting and identifying hazardous materials often require the use of reagents and/or physical sampling, which is a time-consuming, costly and often dangerous process. Stand-off detection allows the operator to detect threat residues from a safer distance minimizing danger to people and equipment. Current fielded technologies for standoff detection of chemical and explosive threats are challenged by low area search rates, poor targeting efficiency, lack of sensitivity and specificity or use of costly and potentially unsafe equipment such as lasers. A demand exists for stand-off systems that are fast, safe, reliable and user-friendly. To address this need, ChemImage Sensor Systems™ (CISS) has developed reagent-less, non-contact, non-destructive sensors for the real-time detection of hazardous materials based on widefield shortwave infrared (SWIR) and Raman hyperspectral imaging (HSI). Hyperspectral imaging enables automated target detection displayed in the form of image making result analysis intuitive and user-friendly. Application of the CISS' SWIR-HSI and Raman sensing technologies to Homeland Security and Law Enforcement for standoff detection of homemade explosives and illicit drugs and their precursors in vehicle and personnel checkpoints is discussed. Sensing technologies include a portable, robot-mounted and standalone variants of the technology. Test data is shown that supports the use of SWIR and Raman HSI for explosive and drug screening at checkpoints as well as screening for explosives and drugs at suspected clandestine manufacturing facilities.

Detection of land mines by amplified fluorescence quenching of polymer films: a man-portable chemical sniffer for detection of ultratrace concentrations of explosives emanating from land mines

NASA Astrophysics Data System (ADS)

la Grone, Marcus J.; Cumming, Colin J.; Fisher, Mark E.; Fox, Michael J.; Jacob, Sheena; Reust, Dennis; Rockley, Mark G.; Towers, Eric

2000-08-01

The explosive charge within a landmine is the source for a mixture of chemical vapors that form a distinctive 'chemical signature' indicative of a landmine. The concentration of these compounds in the air over landmines is extremely low, well below the minimum detection limits of most field- portable chemical sensors. Described in this paper is a man- portable landmine detection system that has for the first time demonstrated the ability to detect landmines by direct sensing of the vapors of signature compounds in the air over landmines. The system utilizes fluorescent polymers developed by collaborators at the MIT. The sensor can detect ultra-trace concentrations of TNT vapor and other nitroaromatic compounds found in many landmine explosives. Thin films of the polymers exhibit intense fluorescence, but when exposed to vapors of nitroaromatic explosives the intensity of the light emitted from the films decreases. A single molecule of TNT binding to a receptor site quenches the fluorescence from many polymer repeat units, increasing the sensitivity by orders of magnitude. A sensor prototype has been develop that response in near real-time to low femtogram quantities of nitroaromatic explosives. The prototype is portable, lightweight, has low power consumption, is simple to operate, and is relatively inexpensive. Simultaneous field testing of the sensor and experienced canine landmine detection teams was recently completed. Although the testing was limited in scope, the performance of the senor met or exceeded that of the canines against buried landmines.

Development of luminescent sensors based on transition metal complexes for the detection of nitroexplosives.

PubMed

Sathish, Veerasamy; Ramdass, Arumugam; Velayudham, Murugesan; Lu, Kuang-Lieh; Thanasekaran, Pounraj; Rajagopal, Seenivasan

2017-12-12

The detection of chemical explosives is a major area of research interest and is essential for the military as well as homeland security to counter the catastrophic effects of global terrorism. In recent years, tremendous effort has been devoted to the development of luminescent materials for the detection of explosives in the vapor, solution, and solid states with a high degree of selectivity and sensitivity and a rapid response time. Apart from the wide range of organic fluorescent chemosensors, transition metal complexes play a prominent role in the sensing of nitroaromatic explosives owing to their rich photophysical characteristics. This review briefly summarizes the salient features of the design and preparation of transition metal (Zn(ii), Ir(iii), Pd(ii), Pt(ii), Re(i) and Ru(ii)) complexes/metallacycles/metallosupramolecules with emphasis on their photophysical properties, sensing behavior, mechanism of action, and the driving forces for detecting explosives and future prospects and challenges. Most of the probes that have been reported to date act as "turn-off" luminescent sensors because their emission (intensity, lifetime, and quantum yield) is eventually quenched upon sensing with nitroaromatic compounds (NACs) through photo-induced electron or energy transfer. These unique properties of transition metal complexes in response to explosives open up new vistas for the development of real world applications such as on-site detection, in-field security, forensic research, etc.

Immobilized Biocatalyst for Detection and Destruction of the Insensitive Explosive, 2,4-Dinitroanisole (DNAN).

PubMed

Karthikeyan, Smruthi; Kurt, Zohre; Pandey, Gunjan; Spain, Jim C

2016-10-18

Accurate and convenient detection of explosive components is vital for a wide spectrum of applications ranging from national security and demilitarization to environmental monitoring and restoration. With the increasing use of DNAN as a replacement for 2,4,6-trinitrotoluene (TNT) in insensitive explosive formulations, there has been a growing interest in strategies to minimize its release and to understand and predict its behavior in the environment. Consequently, a convenient tool for its detection and destruction could enable development of more effective decontamination and demilitarization strategies. Biosensors and biocatalysts have limited applicability to the more traditional explosives because of the inherent limitations of the relevant enzymes. Here, we report a highly specific, convenient and robust biocatalyst based on a novel ether hydrolase enzyme, DNAN demethylase (that requires no cofactors), from a Nocardioides strain that can mineralize DNAN. Biogenic silica encapsulation was used to stabilize the enzyme and enable it to be packed into a model microcolumn for application as a biosensor or as a bioreactor for continuous destruction of DNAN. The immobilized enzyme was stable and not inhibited by other insensitive munitions constituents. An alternative method for DNAN detection involved coating the encapsulated enzyme on cellulose filter paper. The hydrolase based biocatalyst could provide the basis for a wide spectrum of applications including detection, identification, destruction or inertion of explosives containing DNAN (demilitarization operations), and for environmental restorations.

Non-detonable and non-explosive explosive simulators

DOEpatents

Simpson, Randall L.; Pruneda, Cesar O.

1997-01-01

A simulator which is chemically equivalent to an explosive, but is not detonable or explodable. The simulator is a combination of an explosive material with an inert material, either in a matrix or as a coating, where the explosive has a high surface ratio but small volume ratio. The simulator has particular use in the training of explosives detecting dogs, calibrating analytical instruments which are sensitive to either vapor or elemental composition, or other applications where the hazards associated with explosives is undesirable but where chemical and/or elemental equivalence is required. The explosive simulants may be fabricated by different techniques. A first method involves the use of standard slurry coatings to produce a material with a very high binder to explosive ratio without masking the explosive vapor, and a second method involves coating inert substrates with thin layers of explosive.

Design Considerations for a Portable Raman Probe Spectrometer for Field Forensics

DOE PAGES

Kelly, James F.; Blake, Thomas A.; Bernacki, Bruce E.; ...

2012-01-01

Raman spectroscopy has been shown to be a viable method for explosives detection. Currently most forensic Raman systems are either large, powerful instruments for laboratory experiments or handheld instruments forin situpoint detection. We have chosen to examine the performance of certain benchtop Raman probe systems with the goal of developing an inexpensive, portable system that could be used to operate in a field forensics laboratory to examine explosives-related residues or samples. To this end, a rugged, low distortion line imaging dispersive Raman spectrograph was configured to work at 830 nm laser excitation and was used to determine whether the compositionmore » of thin films of plastic explosives or small (e.g., ≤10 μm) particles of RDX or other explosives or oxidizers can be detected, identified, and quantified in the field. With 300 mW excitation energy, concentrations of RDX and PETN can be detected and reconstructed in the case of thin Semtex smears, but further work is needed to push detection limits of areal dosages to the ~1μg/cm 2level. We describe the performance of several probe/spectrograph combinations and show preliminary data for particle detection, calibration and detection linearity for mixed compounds, and so forth.« less

Stand-off explosive detection utilizing low power stimulated emission nuclear quadrupole resonance detection and subwavelength focusing wideband super lens

NASA Astrophysics Data System (ADS)

Apostolos, John; Mouyos, William; Feng, Judy; Chase, Walter

2015-05-01

The need for advanced techniques to detect improvised explosive devices (IED) at stand-off distances greater than ten (10) meters has driven AMI Research and Development (AMI) to develop a solution to detect and identify the threat utilizing a forward looking Synthetic Aperture Radar (SAR) combined with our CW radar technology Nuclear Quadrupole Resonance (NQR) detection system. The novel features include a near-field sub-wavelength focusing antenna, a wide band 300 KHz to 300 MHz rapidly scanning CW radar facilitated by a high Q antenna/tuner, and an advanced processor utilizing Rabi transitions where the nucleus oscillates between states under the time dependent incident electromagnetic field and alternately absorbs energy from the incident field while emitting coherent energy via stimulated emission. AMI's Sub-wavelength Focusing Wide Band Super Lens uses a Near-Field SAR, making detection possible at distances greater than ten (10) meters. This super lens is capable of operating on the near-field and focusing electromagnetic waves to resolutions beyond the diffraction limit. When applied to the case of a vehicle approaching an explosive hazard the methodologies of synthetic aperture radar is fused with the array based super resolution and the NQR data processing detecting the explosive hazard.

Method for selective detection of explosives in mass spectrometer or ion mobility spectrometer at parts-per-quadrillion level

DOEpatents

Ewing, Robert G.; Atkinson, David A.; Clowers, Brian H.

2015-09-01

A method for selective detection of volatile and non-volatile explosives in a mass spectrometer or ion mobility spectrometer at a parts-per-quadrillion level without preconcentration is disclosed. The method comprises the steps of ionizing a carrier gas with an ionization source to form reactant ions or reactant adduct ions comprising nitrate ions (NO.sub.3.sup.-); selectively reacting the reactant ions or reactant adduct ions with at least one volatile or non-volatile explosive analyte at a carrier gas pressure of at least about 100 Ton in a reaction region disposed between the ionization source and an ion detector, the reaction region having a length which provides a residence time (tr) for reactant ions therein of at least about 0.10 seconds, wherein the selective reaction yields product ions comprising reactant ions or reactant adduct ions that are selectively bound to the at least one explosive analyte when present therein; and detecting product ions with the ion detector to determine presence or absence of the at least one explosive analyte.

Advances in explosives analysis—part II: photon and neutron methods

DOE PAGES

Brown, Kathryn E.; Greenfield, Margo T.; McGrane, Shawn D.; ...

2015-10-07

The number and capability of explosives detection and analysis methods have increased dramatically since publication of the Analytical and Bioanalytical Chemistry special issue devoted to Explosives Analysis [Moore DS, Goodpaster JV, Anal Bioanal Chem 395:245–246, 2009]. Here we review and critically evaluate the latest (the past five years) important advances in explosives detection, with details of the improvements over previous methods, and suggest possible avenues towards further advances in, e.g., stand-off distance, detection limit, selectivity, and penetration through camouflage or packaging. Our review consists of two parts. Part I discussed methods based on animals, chemicals (including colorimetry, molecularly imprinted polymers,more » electrochemistry, and immunochemistry), ions (both ion-mobility spectrometry and mass spectrometry), and mechanical devices. In Part II, we review methods based on photons, from very energetic photons including X-rays and gamma rays down to the terahertz range, and neutrons.« less

A portable fluorescence detector for fast ultra trace detection of explosive vapors

NASA Astrophysics Data System (ADS)

Xin, Yunhong; He, Gang; Wang, Qi; Fang, Yu

2011-10-01

This paper developed a portable detector based on a specific material-based fluorescent sensing film for an ultra trace detection of explosives, such as 2,4,6-trinitrotoluene (TNT) or its derivate 2,4-dinitrotoluene (DNT), in ambient air or on objects tainted by explosives. The fluorescent sensing films are based on single-layer chemistry and the signal amplification effect of conjugated polymers, which exhibited higher sensitivity and shorter response time to TNT or DNT at their vapor pressures. Due to application of the light emitting diode and the solid state photomultiplier and the cross-correlation-based circuit design technology, the device has the advantages of low-power, low-cost, small size, and an improved signal to noise ratio. The results of the experiments showed that the detector can real-time detect and identify of explosive vapors at extremely low levels; it is suitable for the identification of suspect luggage, forensic analyses, or battlefields clearing.

Advances in explosives analysis—part I. animal, chemical, ion, and mechanical methods

DOE PAGES

Brown, Kathryn E.; Greenfield, Margo T.; McGrane, Shawn D.; ...

2015-10-13

The number and capability of explosives detection and analysis methods have increased substantially since the publication of the Analytical and Bioanalytical Chemistry special issue devoted to Explosives Analysis (Moore and Goodpaster, Anal Bioanal Chem 395(2):245–246, 2009). We review and critically evaluate the latest (the past five years) important advances in explosives detection, with details of the improvements over previous methods, and suggest possible avenues towards further advances in, e.g., stand-off distance, detection limit, selectivity, and penetration through camouflage or packaging. The review consists of two parts. Moreover, Part I, reviews methods based on animals, chemicals (including colorimetry, molecularly imprinted polymers,more » electrochemistry, and immunochemistry), ions (both ion-mobility spectrometry and mass spectrometry), and mechanical devices. Part II will review methods based on photons, from very energetic photons including X-rays and gamma rays down to the terahertz range, and neutrons.« less

A portable fluorescence detector for fast ultra trace detection of explosive vapors.

PubMed

Xin, Yunhong; He, Gang; Wang, Qi; Fang, Yu

2011-10-01

This paper developed a portable detector based on a specific material-based fluorescent sensing film for an ultra trace detection of explosives, such as 2,4,6-trinitrotoluene (TNT) or its derivate 2,4-dinitrotoluene (DNT), in ambient air or on objects tainted by explosives. The fluorescent sensing films are based on single-layer chemistry and the signal amplification effect of conjugated polymers, which exhibited higher sensitivity and shorter response time to TNT or DNT at their vapor pressures. Due to application of the light emitting diode and the solid state photomultiplier and the cross-correlation-based circuit design technology, the device has the advantages of low-power, low-cost, small size, and an improved signal to noise ratio. The results of the experiments showed that the detector can real-time detect and identify of explosive vapors at extremely low levels; it is suitable for the identification of suspect luggage, forensic analyses, or battlefields clearing.

29 CFR 1926.903 - Underground transportation of explosives.

Code of Federal Regulations, 2012 CFR

2012-07-01

...) Trucks used for the transportation of explosives underground shall have the electrical system checked weekly to detect any failures which may constitute an electrical hazard. A certification record which... powered by the truck's electrical system, shall be prohibited. (g) Explosives and blasting agents shall be...

29 CFR 1926.903 - Underground transportation of explosives.

Code of Federal Regulations, 2014 CFR

2014-07-01

...) Trucks used for the transportation of explosives underground shall have the electrical system checked weekly to detect any failures which may constitute an electrical hazard. A certification record which... powered by the truck's electrical system, shall be prohibited. (g) Explosives and blasting agents shall be...

29 CFR 1926.903 - Underground transportation of explosives.

Code of Federal Regulations, 2013 CFR

2013-07-01

...) Trucks used for the transportation of explosives underground shall have the electrical system checked weekly to detect any failures which may constitute an electrical hazard. A certification record which... powered by the truck's electrical system, shall be prohibited. (g) Explosives and blasting agents shall be...

29 CFR 1926.903 - Underground transportation of explosives.

Code of Federal Regulations, 2011 CFR

2011-07-01

...) Trucks used for the transportation of explosives underground shall have the electrical system checked weekly to detect any failures which may constitute an electrical hazard. A certification record which... powered by the truck's electrical system, shall be prohibited. (g) Explosives and blasting agents shall be...

29 CFR 1926.903 - Underground transportation of explosives.

Code of Federal Regulations, 2010 CFR

2010-07-01

...) Trucks used for the transportation of explosives underground shall have the electrical system checked weekly to detect any failures which may constitute an electrical hazard. A certification record which... powered by the truck's electrical system, shall be prohibited. (g) Explosives and blasting agents shall be...

Chemical Sensing of Unexploded Ordnance with the Mobile Underwater Survey System (MUDSS)

NASA Technical Reports Server (NTRS)

Darrach, M. R.; Chutjian, A.

1995-01-01

The ability to sense explosives residues in the marine environment is a critical tool for identification and classification of underwater unexploded ordnance (UXO). Trace explosives signatures of TNT and DNT have been extracted from multiple sediment samples adjacent to unexploded undersea ordnance at Halifax Harbor, Canada. The ordnance was hurled into the harbor during a massive explosion fifty years earlier, in 1945 after World War II had ended. Laboratory sediment extractions were made using the solid-phase microextraction (SPME) method in seawater, and detection using the Reversal Electron Attachment Detection (READ) technique and, in the case of DNT, a commercial gas-chromatography/mass spectrometer (GC/MS). Results show that, after more than 50 years in the environment, ordnance which appeared to be physically intact gave good explosives signatures at the parts-per-billion level, whereas ordnance which had been cracked open during the explosion gave no signatures at the 10 parts-per-trillion sensitivity level. These measurements appear to provide the first reported data of explosives signatures from undersea UXOs.

Research on application information system integration platform in medicine manufacturing enterprise.

PubMed

Deng, Wu; Zhao, Huimin; Zou, Li; Li, Yuanyuan; Li, Zhengguang

2012-08-01

Computer and information technology popularizes in the medicine manufacturing enterprise for its potentials in working efficiency and service quality. In allusion to the explosive data and information of application system in current medicine manufacturing enterprise, we desire to propose a novel application information system integration platform in medicine manufacturing enterprise, which based on a combination of RFID technology and SOA, to implement information sharing and alternation. This method exploits the application integration platform across service interface layer to invoke the RFID middleware. The loose coupling in integration solution is realized by Web services. The key techniques in RFID event components and expanded role-based security access mechanism are studied in detail. Finally, a case study is implemented and tested to evidence our understanding on application system integration platform in medicine manufacturing enterprise.

49 CFR 1544.213 - Use of explosives detection systems.

Code of Federal Regulations, 2010 CFR

2010-10-01

... inspection of photographic equipment and film. (1) At locations at which an aircraft operator or TSA uses an... and advise them to remove all X-ray, scientific, and high-speed film from checked baggage before... photographic equipment and film packages without exposure to an explosives detection system. (2) If the...

Critical Homeland Infrastructure Protection

DTIC Science & Technology

2007-01-01

talent. Examples include: * Detection of surveillance activities; * Stand-off detection of chemical, biological, nuclear, radiation and explosive ...Manager Guardian DARPA Overview Mr. Roger Gibbs DARPA LLNL Technologies in Support of Infrastructure Mr. Don Prosnitz LLNL Protection Sandia National...FP Antiterrorism/Force Protection CBRNE Chemical Biological Radiological Nuclear Explosive CERT Commuter Emergency Response Team CIA Central

Extremely fast and highly selective detection of nitroaromatic explosive vapours using fluorescent polymer thin films.

PubMed

Demirel, Gokcen Birlik; Daglar, Bihter; Bayindir, Mehmet

2013-07-14

A novel sensing material based on pyrene doped polyethersulfone worm-like structured thin film is developed using a facile technique for detection of nitroaromatic explosive vapours. The formation of π-π stacking in the thin fluorescent film allows a highly sensitive fluorescence quenching which is detectable by the naked eye in a response time of a few seconds.

Filter-based chemical sensors for hazardous materials

NASA Astrophysics Data System (ADS)

Major, Kevin J.; Ewing, Kenneth J.; Poutous, Menelaos K.; Sanghera, Jasbinder S.; Aggarwal, Ishwar D.

2014-05-01

The development of new techniques for the detection of homemade explosive devices is an area of intense research for the defense community. Such sensors must exhibit high selectivity to detect explosives and/or explosives related materials in a complex environment. Spectroscopic techniques such as FTIR are capable of discriminating between the volatile components of explosives; however, there is a need for less expensive systems for wide-range use in the field. To tackle this challenge we are investigating the use of multiple, overlapping, broad-band infrared (IR) filters to enable discrimination of volatile chemicals associated with an explosive device from potential background interferants with similar chemical signatures. We present an optical approach for the detection of fuel oil (the volatile component in ammonium nitrate-fuel oil explosives) that relies on IR absorption spectroscopy in a laboratory environment. Our proposed system utilizes a three filter set to separate the IR signals from fuel oil and various background interferants in the sample headspace. Filter responses for the chemical spectra are calculated using a Gaussian filter set. We demonstrate that using a specifically chosen filter set enables discrimination of pure fuel oil, hexanes, and acetone, as well as various mixtures of these components. We examine the effects of varying carrier gasses and humidity on the collected spectra and corresponding filter response. We study the filter response on these mixtures over time as well as present a variety of methods for observing the filter response functions to determine the response of this approach to detecting fuel oil in various environments.

Explosive detection technology

NASA Astrophysics Data System (ADS)

Doremus, Steven; Crownover, Robin

2017-05-01

The continuing proliferation of improvised explosive devices is an omnipresent threat to civilians and members of military and law enforcement around the world. The ability to accurately and quickly detect explosive materials from a distance would be an extremely valuable tool for mitigating the risk posed by these devices. A variety of techniques exist that are capable of accurately identifying explosive compounds, but an effective standoff technique is still yet to be realized. Most of the methods being investigated to fill this gap in capabilities are laser based. Raman spectroscopy is one such technique that has been demonstrated to be effective at a distance. Spatially Offset Raman Spectroscopy (SORS) is a technique capable of identifying chemical compounds inside of containers, which could be used to detect hidden explosive devices. Coherent Anti-Stokes Raman Spectroscopy (CARS) utilized a coherent pair of lasers to excite a sample, greatly increasing the response of sample while decreasing the strength of the lasers being used, which significantly improves the eye safety issue that typically hinders laser-based detection methods. Time-gating techniques are also being developed to improve the data collection from Raman techniques, which are often hindered fluorescence of the test sample in addition to atmospheric, substrate, and contaminant responses. Ultraviolet based techniques have also shown significant promise by greatly improved signal strength from excitation of resonance in many explosive compounds. Raman spectroscopy, which identifies compounds based on their molecular response, can be coupled with Laser Induced Breakdown Spectroscopy (LIBS) capable of characterizing the sample's atomic composition using a single laser.

Building a Predictive Capability for Decision-Making that Supports MultiPEM

DOE Office of Scientific and Technical Information (OSTI.GOV)

Carmichael, Joshua Daniel

Multi-phenomenological explosion monitoring (multiPEM) is a developing science that uses multiple geophysical signatures of explosions to better identify and characterize their sources. MultiPEM researchers seek to integrate explosion signatures together to provide stronger detection, parameter estimation, or screening capabilities between different sources or processes. This talk will address forming a predictive capability for screening waveform explosion signatures to support multiPEM.

Infrasound signals from the underground nuclear explosions of North Korea

NASA Astrophysics Data System (ADS)

Che, Il-Young; Park, Junghyun; Kim, Inho; Kim, Tae Sung; Lee, Hee-Il

2014-07-01

We investigated the infrasound signals from seismic ground motions induced by North Korea's underground nuclear explosions, including the recent third explosion on 2013 February 12. For the third explosion, the epicentral infrasound signals were detected not only by three infrasound network stations (KSGAR, ULDAR and YAGAR) in South Korea but also by two nearby International Monitoring System infrasound stations, IS45 and IS30. The detectability of the signals was limited at stations located on the relatively east side of the epicentre, with large azimuth deviations due to very favourable atmospheric conditions for eastward propagation at stratospheric height in 2013. The stratospheric wind direction was the reverse of that when the second explosion was conducted in 2009 May. The source location of the epicentral infrasound with wave parameters determined at the multiple stations has an offset by about 16.6 km from the reference seismic location. It was possible to determine the infrasonic location with moderate accuracy by the correction of the azimuth deviation due to the eastward winds in the stratosphere. In addition to the epicentral infrasonic signals, diffracted infrasound signals were observed from the second underground nuclear explosion in 2009. The exceptional detectability of the diffracted infrasound was a consequence of the temporal formation of a thin atmospheric inversion layer over the ocean surface when the event occurred.

Considerations for developing technologies for an integrated person-borne IED countermeasure architecture

NASA Astrophysics Data System (ADS)

Lombardo, Nicholas J.; Knudson, Christa K.; Rutz, Frederick C.; Pattison, Kerrie J.; Stratton, Rex C.; Wiborg, James C.

2010-04-01

Developing an integrated person-borne improvised explosive device (IED) countermeasure to protect unstructured crowds at large public venues is the goal of the Standoff Technology Integration and Demonstration Program (STIDP), sponsored in part by the U.S. Department of Homeland Security (DHS). The architecture being developed includes countermeasure technologies deployed as a layered defense and enabling technologies for operating the countermeasures as an integrated system. In the architecture, early recognition of potentially higher-risk individuals is crucial. Sensors must be able to detect, with high accuracy, explosives' threat signatures in varying environmental conditions, from a variety of approaches and with dense crowds and limited dwell time. Command-and-control technologies are needed to automate sensor operation, reduce staffing requirements, improve situational awareness, and automate/facilitate operator decisions. STIDP is developing technical and operational requirements for standoff and remotely operated sensors and is working with federal agencies and foreign governments to implement these requirements into their research and development programs. STIDP also is developing requirements for a software platform to rapidly integrate and control various sensors; acquire, analyze, and record their data; and present the data in an operationally relevant manner. Requirements also are being developed for spatial analysis, tracking and assessing threats with available screening resources, and data fusion for operator decision-making.

Dual-excitation wavelength resonance Raman explosives detector

NASA Astrophysics Data System (ADS)

Yellampalle, Balakishore; Sluch, Mikhail; Wu, Hai-Shan; Martin, Robert; McCormick, William; Ice, Robert; Lemoff, Brian E.

2013-05-01

Deep-ultraviolet resonance Raman spectroscopy (DUVRRS) is a promising approach to stand-off detection of explosive traces due to: 1) resonant enhancement of Raman cross-section, 2) λ-4-cross-section enhancement, and 3) fluorescence and solar background free signatures. For trace detection, these signal enhancements more than offset the small penetration depth due to DUV absorption. A key challenge for stand-off sensors is to distinguish explosives, with high confidence, from a myriad of unknown background materials that may have interfering spectral peaks. To address this, we are developing a stand-off explosive sensor using DUVRRS with two simultaneous DUV excitation wavelengths. Due to complex interplay of resonant enhancement, self-absorption and laser penetration depth, significant amplitude variation is observed between corresponding Raman bands with different excitation wavelengths. These variations with excitation wavelength provide an orthogonal signature that complements the traditional Raman signature to improve specificity relative to single-excitation-wavelength techniques. As part of this effort, we are developing two novel CW DUV lasers, which have potential to be compact, and a compact dual-band high throughput DUV spectrometer, capable of simultaneous detection of Raman spectra in two spectral windows. We have also developed a highly sensitive algorithm for the detection of explosives under low signal-to-noise situations.

Detection of explosives using negative ion mobility spectrometry in air based on dopant-assisted thermal ionization.

PubMed

Shahraki, Hassan; Tabrizchi, Mahmoud; Farrokhpor, Hossein

2018-05-26

The ionization source is an essential component of most explosive detectors based on negative ion mobility spectrometry. Conventional ion sources suffer from such inherent limitations as special safety regulations on radioactive sources or generating interfering ions (for non-radioactive sources) such as corona discharge operating in the air. In this study, a new negative ion source is introduced for ion mobility spectrometry that is based on thermal ionization and operates in the air, applicable to explosives detection. Our system consists of a heating filament powered by an isolated power supply connected to negative high voltage. The ionization is assisted by doping chlorinated compounds in the gas phase using chlorinated hydrocarbons in contact with the heating element to yield Cl - reactant ions. Several chlorinated hydrocarbons are evaluated as the reagent chemicals for providing Cl- reactant ions, of which CCl 4 is identified as the best ionizing reagent. The ion source is evaluated by recording the ion mobility spectra of common explosives, including TNT, RDX, and PETN in the air. A detection limit of 150 pg is obtained for TNT. Compared to other ionization sources, the new source is found to be low-cost, simple, and long-lived, making it suited to portable explosives detection devices. Copyright © 2018 Elsevier B.V. All rights reserved.

Fabrication and testing of a standoff trace explosives detection system

NASA Astrophysics Data System (ADS)

Waterbury, Robert; Rose, Jeremy; Vunck, Darius; Blank, Thomas; Pohl, Ken; Ford, Alan; McVay, Troy; Dottery, Ed

2011-05-01

In order to stop the transportation of materials used for IED manufacture, a standoff checkpoint explosives detection system (CPEDS) has recently been fabricated. The system incorporates multi-wavelength Raman spectroscopy and laser induced breakdown spectroscopy (LIBS) modalities with a LIBS enhancement technique called TEPS to be added later into a single unit for trace detection of explosives at military checkpoints. Newly developed spectrometers and other required sensors all integrated with a custom graphical user interface for producing simplified, real-time detection results are also included in the system. All equipment is housed in a military ruggedized shelter for potential deployment intheater for signature collection. Laboratory and performance data, as well as the construction of the CPEDS system and its potential deployment capabilities, will be presented in the current work.

A haptic sensing upgrade for the current EOD robotic fleet

NASA Astrophysics Data System (ADS)

Rowe, Patrick

2014-06-01

The past decade and a half has seen a tremendous rise in the use of mobile manipulator robotic platforms for bomb inspection and disposal, explosive ordnance disposal, and other extremely hazardous tasks in both military and civilian settings. Skilled operators are able to control these robotic vehicles in amazing ways given the very limited situational awareness obtained from a few on-board camera views. Future generations of robotic platforms will, no doubt, provide some sort of additional force or haptic sensor feedback to further enhance the operator's interaction with the robot, especially when dealing with fragile, unstable, and explosive objects. Unfortunately, the robot operators need this capability today. This paper discusses an approach to provide existing (and future) robotic mobile manipulator platforms, with which trained operators are already familiar and highly proficient, this desired haptic and force feedback capability. The goals of this technology are to be rugged, reliable, and affordable. It should also be able to be applied to a wide range of existing robots with a wide variety of manipulator/gripper sizes and styles. Finally, the presentation of the haptic information to the operator is discussed, given the fact that control devices that physically interact with the operators are not widely available and still in the research stages.

Non-detonable and non-explosive explosive simulators

DOEpatents

Simpson, R.L.; Pruneda, C.O.

1997-07-15

A simulator which is chemically equivalent to an explosive, but is not detonable or explodable is disclosed. The simulator is a combination of an explosive material with an inert material, either in a matrix or as a coating, where the explosive has a high surface ratio but small volume ratio. The simulator has particular use in the training of explosives detecting dogs, calibrating analytical instruments which are sensitive to either vapor or elemental composition, or other applications where the hazards associated with explosives is undesirable but where chemical and/or elemental equivalence is required. The explosive simulants may be fabricated by different techniques. A first method involves the use of standard slurry coatings to produce a material with a very high binder to explosive ratio without masking the explosive vapor, and a second method involves coating inert substrates with thin layers of explosive. 11 figs.

30 CFR 250.1727 - What information must I include in my final application to remove a platform or other facility?

Code of Federal Regulations, 2010 CFR

2010-07-01

... MANAGEMENT SERVICE, DEPARTMENT OF THE INTERIOR OFFSHORE OIL AND GAS AND SULPHUR OPERATIONS IN THE OUTER... are placing the explosives inside or outside of the pilings; (3) If you will use divers or acoustic...

Aerostat-Lofted Instrument Platform and Sampling Method for Determination of Emissions from Open Area Sources

EPA Science Inventory

Sampling emissions from open area sources, particularly sources of open burning, is difficult due to fast dilution of emissions and safety concerns for personnel. Representative emission samples can be difficult to obtain with flaming and explosive sources since personnel safety ...

Millimetre wave and terahertz technology for the detection of concealed threats: a review

NASA Astrophysics Data System (ADS)

Kemp, Michael C.

2006-09-01

There has been intense interest in the use of millimetre wave and terahertz technology for the detection of concealed weapons, explosives and other threats. Electromagnetic waves at these frequencies are safe, penetrate barriers and have short enough wavelengths to allow discrimination between objects. In addition, many solids including explosives have characteristic spectroscopic signatures at terahertz wavelengths which can be used to identify them. This paper reviews the progress which has been made in recent years and identifies the achievements, challenges and prospects for these technologies in checkpoint people screening, stand off detection of improvised explosive devices (IEDs) and suicide bombers as well as more specialized screening tasks.

A visual assay and spectrophotometric determination of LLM-105 explosive using detection of gold nanoparticle aggregation at two pH values.

PubMed

He, Yi; Cheng, Yang

2016-08-01

We report a simple, rapid, and sensitive assay for visual and spectrophotometric detection of the 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105) explosive. The assay is based on different interactions between LLM-105 and gold nanoparticle (AuNP) dispersions at two pH values, leading to the formation of dispersed or aggregated AuNPs. Two AuNP dispersions at two pH values were applied to recognize and detect LLM-105 instead of traditional AuNP dispersion under an aptotic pH to improve the anti-interference ability. The developed assay showed excellent sensitivity with a detection limit of 3 ng/mL, and the presence of as low as 0.2 μg/mL LLM-105 can be directly detected with the bare eye. This sensitivity is about six orders of magnitude higher than that of the reported traditional assays. Additionally, the assay exhibited good selectivity toward LLM-105 over other explosives, sulfur-containing compounds, and amines. Graphical abstract A simple, sensitive, and selective assay for LLM-105 was developed based on the pH-dependent interaction between the LLM-105 explosive and gold nanoparticle dispersion.

Multivariate analysis of standoff laser-induced breakdown spectroscopy spectra for classification of explosive-containing residues

DOE Office of Scientific and Technical Information (OSTI.GOV)

De Lucia, Frank C. Jr.; Gottfried, Jennifer L.; Munson, Chase A.

2008-11-01

A technique being evaluated for standoff explosives detection is laser-induced breakdown spectroscopy (LIBS). LIBS is a real-time sensor technology that uses components that can be configured into a ruggedized standoff instrument. The U.S. Army Research Laboratory has been coupling standoff LIBS spectra with chemometrics for several years now in order to discriminate between explosives and nonexplosives. We have investigated the use of partial least squares discriminant analysis (PLS-DA) for explosives detection. We have extended our study of PLS-DA to more complex sample types, including binary mixtures, different types of explosives, and samples not included in the model. We demonstrate themore » importance of building the PLS-DA model by iteratively testing it against sample test sets. Independent test sets are used to test the robustness of the final model.« less

Laminography using resonant neutron attenuation for detection of drugs and explosives

NASA Astrophysics Data System (ADS)

Loveman, R. A.; Feinstein, R. L.; Bendahan, J.; Gozani, T.; Shea, P.

1997-02-01

Resonant neutron attenuation has been shown to be usable for assaying elements which constitute explosives, cocaine, and heroin. By careful analysis of attenuation measurements, the determination of the presence or absence of explosives can be determined. Simple two dimensional radiographic techniques only give results for areal density and consequently will be limited in their effectiveness. Classical tomographic techniques are both computationally very intensive and place strict requirements on the quality and amount of data acquired. These requirements and computations take time and are likely to be very difficult to perform in real time. Simulation studies described in this article have shown that laminographic image reconstruction can be used effectively with resonant neutron attenuation measurements to interrogate luggage for explosives or drugs. The design of the system described in this article is capable of pseudo-three dimensional image reconstruction of all of the elemental densities pertinent to explosive and drug detection.

Fingerprinting postblast explosive residues by portable capillary electrophoresis with contactless conductivity detection.

PubMed

Kobrin, Eeva-Gerda; Lees, Heidi; Fomitšenko, Maria; Kubáň, Petr; Kaljurand, Mihkel

2014-04-01

A portable capillary electrophoretic system with contactless conductivity detection was used for fingerprint analysis of postblast explosive residues from commercial organic and improvised inorganic explosives on various surfaces (sand, concrete, metal witness plates). Simple extraction methods were developed for each of the surfaces for subsequent simultaneous capillary electrophoretic analysis of anions and cations. Dual-opposite end injection principle was used for fast (<4 min) separation of 10 common anions and cations from postblast residues using an optimized separation electrolyte composed of 20 mM MES, 20 mM l-histidine, 30 μM CTAB and 2 mM 18-crown-6. The concentrations of all ions obtained from the electropherograms were subjected to principal component analysis to classify the tested explosives on all tested surfaces, resulting in distinct cluster formations that could be used to verify (each) type of the explosive. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Development and validation of a solid phase extraction sample cleanup procedure for the recovery of trace levels of nitro-organic explosives in soil.

PubMed

Thomas, Jennifer L; Donnelly, Christopher C; Lloyd, Erin W; Mothershead, Robert F; Miller, Mark L

2018-03-01

An improved cleanup method has been developed for the recovery of trace levels of 12 nitro-organic explosives in soil, which is important not only for the forensic community, but also has environmental implications. A wide variety of explosives or explosive-related compounds were evaluated, including nitramines, nitrate esters, nitroaromatics, and a nitroalkane. Fortified soil samples were extracted with acetone, processed via solid phase extraction (SPE), and then analyzed by gas chromatography with electron capture detection. The following three SPE sorbents in cartridge format were compared: Empore™ SDB-XC, Oasis ® HLB, and Bond Elut NEXUS cartridges. The NEXUS cartridges provided the best overall recoveries for the 12 explosives in potting soil (average 48%) and the fastest processing times (<30min). It also rejected matrix components from spent motor oil on potting soil. The SPE method was validated by assessing limit of detection (LOD), processed sample stability, and interferences. All 12 compounds were detectable at 0.02μg explosive/gram of soil or lower in the three matrices tested (potting soil, sand, and loam) over three days. Seven explosives were stable up to seven days at 2μg/g and three were stable at 0.2μg/g, both in processed loam, which was the most challenging matrix. In the interference study, five interferences above the determined LOD for soil were detected in matrices collected across the United States and in purchased all-purpose sand, potting soil, and loam. This represented a 3.2% false positive rate for the 13 matrices processed by the screening method for interferences. The reported SPE cleanup method provides a fast and simple extraction process for separating organic explosives from matrix components, facilitating sample throughput and reducing instrument maintenance. In addition, a comparison study of the validated SPE method versus conventional syringe filtration was completed and highlighted the benefits of sample cleanup for removing matrix interferences, while also providing lower supply cost, order of magnitude lower LODs for most explosives, higher percent recoveries for complex matrices, and fewer instrument maintenance issues. Published by Elsevier B.V.

Nuclear Explosion and Infrasound Event Resources of the SMDC Monitoring Research Program

DTIC Science & Technology

2008-09-01

2008 Monitoring Research Review: Ground-Based Nuclear Explosion Monitoring Technologies 928 Figure 7. Dozens of detected infrasound signals from...investigate alternative detection schemes at the two infrasound arrays based on frequency-wavenumber (fk) processing and the F-statistic. The results of... infrasound signal - detection processing schemes. REFERENCES Bahavar, M., B. Barker, J. Bennett, R. Bowman, H. Israelsson, B. Kohl, Y-L. Kung, J. Murphy

IDD 2.0: Physiological Resilience

DTIC Science & Technology

2013-04-15

Descriptive and hypothesis-testing research into the improvement of physiological resilience of dogs used to detect improvised explosive devices (IDD...Detection Dog 2.0 5a. CONTRACT NUMBER N0001411C0493 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 0603640M 6. AUTHOR(S) Michael Davis 5d. PROJECT...unlimited 13. SUPPLEMENTARY NOTES 14. ABSTRACT Improvised explosive device detection dogs (IDDs) are used by dismounted Marine Corps patrols to facilitate

Novel Methods for Detecting Buried Explosive Devices

DTIC Science & Technology

2007-04-10

NQR ), and semiotic data fusion. Bioreporter bacteria look promising for third-world humanitarian applications; they are inexpensive, and...demining, NQR is a promising method for detecting explosive substances; of 50,000 substances that have been tested, none has an NQR signature that can be...approach to a cheap mine detector for humanitarian use. Real-time wavelet processing appears to be a key to extending NQR bomb detection into mine

Homeland Security and Contraband Detection

NASA Astrophysics Data System (ADS)

Lanza, R. C.

Detection of contraband and illicit materials has become increasingly important, especially since the terrorist attacks in the United States on September 11, 2001. The nature of the detection problem embodies both physics issues and a set of operational constraints that limit the practical application of neutrons. The issue under consideration is detection of materials that are considered serious threats; these may include explosives; radioactive materials, fissile materials, and other materials associated with nuclear weapons, often referred to as special nuclear material (SNM). The overriding constraint is in the physics: systems must be based on clean physics; but unlike physics experiments, detection systems work under the limitation that materials must be identified nonintrusively, without interrupting the normal flow of commerce and with a high probability of detection and a low probability of false alarms. A great deal of work has been reported in the literature on neutron-based techniques for detecting explosives and drugs. The largest impetus by far for detecting explosives comes from aviation industry requirements for inspecting luggage and, to a lesser extent, cargo. The major alternative techniques are either X-ray-based or chemical trace detection methods that look for small traces of explosive residues. The limitations of the X-ray and trace methods in detecting explosives are well known, but currently (2008) it is safe to say that no neutron- or nuclear-based technique is being used routinely for security inspection, despite extensive development of these methods. Smuggling of nuclear materials has become a concern, and neutron techniques are particularly attractive for detecting them. Given the limitations of X-ray techniques and the need for SNM detection, it is now useful to reexamine neutron methodologies, particularly imaging. A significant number of neutron-based techniques have been proposed and are under development for security applications, especially SNM detection, but describing how they work is beyond the scope of the chapter. Instead, one particular approach to neutron imaging, neutron resonance radiography (NRR), is discussed in detail as it illustrates many of the issues connected with imaging and detection.

78 FR 14120 - Agency Information Collection Activities: Proposed Collection; Comments Requested: Statement of...

Federal Register 2010, 2011, 2012, 2013, 2014

2013-03-04

...--Marking of Plastic Explosives for the Purpose of Detection ACTION: 60-Day notice. The Department of... currently approved collection. (2) Title of the Form/Collection: Statement of Process--Marking of Plastic... information will be used to ensure that plastic explosives contain a detection agent as required by law. (5...

Explosive and chemical threat detection by surface-enhanced Raman scattering: a review.

PubMed

Hakonen, Aron; Andersson, Per Ola; Stenbæk Schmidt, Michael; Rindzevicius, Tomas; Käll, Mikael

2015-09-17

Acts of terror and warfare threats are challenging tasks for defense agencies around the world and of growing importance to security conscious policy makers and the general public. Explosives and chemical warfare agents are two of the major concerns in this context, as illustrated by the recent Boston Marathon bombing and nerve gas attacks on civilians in the Middle East. To prevent such tragic disasters, security personnel must be able to find, identify and deactivate the threats at multiple locations and levels. This involves major technical and practical challenges, such as detection of ultra-low quantities of hazardous compounds at remote locations for anti-terror purposes and monitoring of environmental sanitation of dumped or left behind toxic substances and explosives. Surface-enhanced Raman scattering (SERS) is one of todays most interesting and rapidly developing methods for label-free ultrasensitive vibrational "fingerprinting" of a variety of molecular compounds. Performance highlights include attomolar detection of TNT and DNT explosives, a sensitivity that few, if any, other technique can compete with. Moreover, instrumentation needed for SERS analysis are becoming progressively better, smaller and cheaper, and can today be acquired for a retail price close to 10,000 US$. This contribution aims to give a comprehensive overview of SERS as a technique for detection of explosives and chemical threats. We discuss the prospects of SERS becoming a major tool for convenient in-situ threat identification and we summarize existing SERS detection methods and substrates with particular focus on ultra-sensitive real-time detection. General concepts, detection capabilities and perspectives are discussed in order to guide potential users of the technique for homeland security and anti-warfare purposes. Copyright © 2015 Elsevier B.V. All rights reserved.

Standoff detection of explosives and chemical agents using broadly tuned external-cavity quantum cascade lasers (EC-QCLs)

NASA Astrophysics Data System (ADS)

Takeuchi, Eric B.; Rayner, Timothy; Weida, Miles; Crivello, Salvatore; Day, Timothy

2007-10-01

Civilian soft targets such as transportation systems are being targeted by terrorists using IEDs and suicide bombers. Having the capability to remotely detect explosives, precursors and other chemicals would enable these assets to be protected with minimal interruption of the flow of commerce. Mid-IR laser technology offers the potential to detect explosives and other chemicals in real-time and from a safe standoff distance. While many of these agents possess "fingerprint" signatures in the mid-IR (i.e. in the 3-20 micron regime), their effective interrogation by a practical, field-deployable system has been limited by size, complexity, reliability and cost constraints of the base laser technology. Daylight Solutions has addressed these shortcomings by developing compact, portable, broadly tunable mid-IR laser sources based upon external-cavity quantum cascade technology. This technology is now being applied by Daylight in system level architectures for standoff and remote detection of explosives, precursors and chemical agents. Several of these architectures and predicted levels of performance will be presented.

Investigation of common fluorophores for the detection of nitrated explosives by fluorescence quenching.

PubMed

Meaney, Melissa S; McGuffin, Victoria L

2008-03-03

Previous studies have indicated that nitrated explosives may be detected by fluorescence quenching of pyrene and related compounds. The use of pyrene, however, invokes numerous health and waste disposal hazards. In the present study, ten safer fluorophores are identified for quenching detection of target nitrated compounds. Initially, Stern-Volmer constants are measured for each fluorophore with nitrobenzene and 4-nitrotoluene to determine the sensitivity of the quenching interaction. For quenching constants greater than 50 M(-1), sensitivity and selectivity are investigated further using an extended set of target quenchers. Nitromethane, nitrobenzene, 4-nitrotoluene, and 2,6-dinitrotoluene are chosen to represent nitrated explosives and their degradation products; aniline, benzoic acid, and phenol are chosen to represent potential interfering compounds. Among the fluorophores investigated, purpurin, malachite green, and phenol red demonstrate the greatest sensitivity and selectivity for nitrated compounds. Correlation of the quenching rate constants for these fluorophores to Rehm-Weller theory suggests an electron-transfer quenching mechanism. As a result of the large quenching constants, purpurin, malachite green, and phenol red are the most promising for future detection of nitrated explosives via fluorescence quenching.

A portable explosive detector based on fluorescence quenching of pyrene deposited on coloured wax-printed μPADs.

PubMed

Taudte, Regina Verena; Beavis, Alison; Wilson-Wilde, Linzi; Roux, Claude; Doble, Philip; Blanes, Lucas

2013-11-07

A new technique for the detection of explosives has been developed based on fluorescence quenching of pyrene on paper-based analytical devices (μPADs). Wax barriers were generated (150 °C, 5 min) using ten different colours. Magenta was found as the most suitable wax colour for the generation of the hydrophobic barriers with a nominal width of 120 μm resulting in fully functioning hydrophobic barriers. One microliter of 0.5 mg mL(-1) pyrene dissolved in an 80:20 methanol-water solution was deposited on the hydrophobic circle (5 mm diameter) to produce the active microchip device. Under ultra-violet (UV) illumination, ten different organic explosives were detected using the μPAD, with limits of detection ranging from 100-600 ppm. A prototype of a portable battery operated instrument using a 3 W power UV light-emitting-diode (LED) (365 nm) and a photodiode sensor was also built and evaluated for the successful automatic detection of explosives and potential application for field-based screening.

K-9 training aids made using additive manufacturing

DOEpatents

Reynolds, John G.; Durban, Matthew M.; Gash, Alexander E.; Grapes, Michael D.; Kelley, Ryan S.; Sullivan, Kyle T.

2018-02-20

Additive Manufacturing (AM) is used to make aids that target the training of K-9s to detect explosives. The process uses mixtures of explosives and matrices commonly used in AM. The explosives are formulated into a mixture with the matrix and printed using AM techniques and equipment. The explosive concentrations are kept less than 10% by wt. of the mixture to conform to requirements of shipping and handling.

Laser photoacoustic spectroscopy helps fight terrorism: High sensitivity detection of chemical Warfare Agent and explosives

NASA Astrophysics Data System (ADS)

Patel, C. K. N.

2008-01-01

Tunable laser photoacoustic spectroscopy is maturing rapidly in its applications to real world problems. One of the burning problems of the current turbulent times is the threat of terrorist acts against civilian population. This threat appears in two distinct forms. The first is the potential release of chemical warfare agents (CWA), such as the nerve agents, in a crowded environment. An example of this is the release of Sarin by Aum Shinrikyo sect in a crowded Tokyo subway in 1995. An example of the second terrorist threat is the ever-present possible suicide bomber in crowded environment such as airports, markets and large buildings. Minimizing the impact of both of these threats requires early detection of the presence of the CWAs and explosives. Photoacoustic spectroscopy is an exquisitely sensitive technique for the detection of trace gaseous species, a property that Pranalytica has extensively exploited in its CO2 laser based commercial instrumentation for the sub-ppb level detection of a number of industrially important gases including ammonia, ethylene, acrolein, sulfur hexafluoride, phosphine, arsine, boron trichloride and boron trifluoride. In this presentation, I will focus, however, on our recent use of broadly tunable single frequency high power room temperature quantum cascade lasers (QCL) for the detection of the CWAs and explosives. Using external grating cavity geometry, we have developed room temperature QCLs that produce continuously tunable single frequency CW power output in excess of 300 mW at wavelengths covering 5 μm to 12 μm. I will present data that show a CWA detection capability at ppb levels with false alarm rates below 1:108. I will also show the capability of detecting a variety of explosives at a ppb level, again with very low false alarm rates. Among the explosives, we have demonstrated the capability of detecting homemade explosives such as triacetone triperoxide and its liquid precursor, acetone which is a common household liquid. This capability, deployed at airports and other public places, will go a long way towards increasing public safety and minimizing inconveniences faced in airline travel.

Active sampling technique to enhance chemical signature of buried explosives

NASA Astrophysics Data System (ADS)

Lovell, John S.; French, Patrick D.

2004-09-01

Deminers and dismounted countermine engineers commonly use metal detectors, ground penetrating radar and probes to locate mines. Many modern landmines have a very low metal content, which severely limits the effectiveness of metal detectors. Canines have also been used for landmine detection for decades. Experiments have shown that canines smell the explosives which are known to leak from most types of landmines. The fact that dogs can detect landmines indicates that vapor sensing is a viable approach to landmine detection. Several groups are currently developing systems to detect landmines by "sniffing" for the ultra-trace explosive vapors above the soil. The amount of material that is available to passive vapor sensing systems is limited to no more than the vapor in equilibrium with the explosive related chemicals (ERCs) distributed in the surface soils over and near the landmine. The low equilibrium vapor pressure of TNT in the soil/atmosphere boundary layer and the limited volume of the boundary layer air imply that passive chemical vapor sensing systems require sensitivities in the picogram range, or lower. ADA is working to overcome many of the limitations of passive sampling methods, by the use of an active sampling method that employs a high-powered (1,200+ joules) strobe lamp to create a highly amplified plume of vapor and/or ERC-bearing fine particulates. Initial investigations have demonstrated that this approach can amplify the detectability of TNT by two or three orders of magnitude. This new active sampling technique could be used with any suitable explosive sensor.

Enhanced direct ambient analysis by differential mobility-filtered desorption electrospray ionization-mass spectrometry.

PubMed

Galhena, Asiri S; Harris, Glenn A; Kwasnik, Mark; Fernández, Facundo M

2010-11-15

Desorption electrospray ionization (DESI) is rapidly becoming established as one of the most powerful ionization techniques allowing direct surface analysis by mass spectrometry (MS) in the ambient environment. DESI provides a significant number of unique analytical capabilities for a broad range of applications, both quantitative and qualitative in nature including biological tissue imaging, pharmaceutical quality control, in vivo analysis, proteomics, metabolomics, forensics, and explosives detection. Despite its growing adoption as a powerful high throughput analysis tool, DESI-MS analysis at trace levels often suffers from background chemical interferences generated during the electrospray ionization processes. In order to improve sensitivity and selectivity, a differential mobility (DM) ion separation cell was successfully interfaced to a custom-built DESI ion source. This new hybrid platform can be operated in two modes: the "DM-off" mode for standard DESI analysis and "DM-on mode" where DESI-generated ions are detected after discrimination by the differential mobility cell. The performance of the DESI-DM-MS platform was tested with several samples typically amenable to DESI analysis, including counterfeit pharmaceuticals and binary mixtures of isobaric chemicals of importance in the pharmaceutical and food industries. In the DM-on mode, DESI-MS signal-to-noise ratios were improved by 70-190% when compared to the DM-off mode. Also, the addition of the DM cell enabled selective in-source ion activation of specific DESI-generated precursor ions, providing tandem MS-like spectra in a single stage mass spectrometer.

Rapid identification and desorption mechanisms of nitrogen-based explosives by ambient micro-fabricated glow discharge plasma desorption/ionization (MFGDP) mass spectrometry.

PubMed

Tian, CaiYan; Yin, JinWei; Zhao, ZhongJun; Zhang, Yinchenxi; Duan, YiXiang

2017-05-15

A novel technique of micro-fabricated glow discharge plasma desorption/ionization mass spectrometry was investigated for the first time in negative ion mode in this study. Negative ion micro-fabricated glow discharge plasma desorption/ionization mass spectrometry (NI-MFGDP-MS) was successfully applied to identify trace explosives in open air. Six explosives and explosives-related compounds were directly analyzed in seconds with this ion source. The ions of [M-H] - were predominant for 2-methyl-1,3,5-trinitrobenzene (trinitrotoluene, TNT) and 2,4,6-trinitrophenol (picric acid), and [M+NO 3 ] - were dominant ions for 1,3,5-trinitro-perhydro-1,3,5-triazine (cyclonite, RDX), octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (octogen, HMX), 1,2,3-trinitroxypropane (nitroglycerin, NG), and pentaerythritol tetranitrate (PETN). The limits of detection (LOD) were from 87.5pgmm -2 to 0.4 fg mm -2 and the relative standard deviation (RSD) ranged between 5.8% and 16.8% for the explosives involved in this study. The reliability of NI-MFGDP-MS was characterized by the analysis of a picric acid-RDX-PETN mixture and a mixture of RDX-pond water. NI-MFGDP-MS and ESI-MS were compared with these explosives and along with collision induced dissociation (CID) experiments. The results showed that electron capture, proton abstraction reaction, nucleophilic attack, ion-molecule attachment, decomposition and anion attachment took place during the NI-MFGDP-MS measurement. These findings provide a guideline and a supplement to the chemical libraries for rapid and accurate detection of explosives. The method shows great potential for fast, in situ, on-line and high throughput detection of explosives in the field of antiterrorism. Copyright © 2017 Elsevier B.V. All rights reserved.

Integrated development of light armored vehicles based on wargaming simulators

NASA Astrophysics Data System (ADS)

Palmarini, Marc; Rapanotti, John

2004-08-01

Vehicles are evolving into vehicle networks through improved sensors, computers and communications. Unless carefully planned, these complex systems can result in excessive crew workload and difficulty in optimizing the use of the vehicle. To overcome these problems, a war-gaming simulator is being developed as a common platform to integrate contributions from three different groups. The simulator, OneSAF, is used to integrate simplified models of technology and natural phenomena from scientists and engineers with tactics and doctrine from the military and analyzed in detail by operations analysts. This approach ensures the modelling of processes known to be important regardless of the level of information available about the system. Vehicle survivability can be improved as well with better sensors, computers and countermeasures to detect and avoid or destroy threats. To improve threat detection and reliability, Defensive Aids Suite (DAS) designs are based on three complementary sensor technologies including: acoustics, visible and infrared optics and radar. Both active armour and softkill countermeasures are considered. In a typical scenario, a search radar, providing continuous hemispherical coverage, detects and classifies the threat and cues a tracking radar. Data from the tracking radar is processed and an explosive grenade is launched to destroy or deflect the threat. The angle of attack and velocity from the search radar can be used by the soft-kill system to carry out an infrared search and track or an illuminated range-gated scan for the threat platform. Upon detection, obscuration, countermanoeuvres and counterfire can be used against the threat. The sensor suite is completed by acoustic detection of muzzle blast and shock waves. Automation and networking at the platoon level contribute to improved vehicle survivability. Sensor data fusion is essential in avoiding catastrophic failure of the DAS. The modular DAS components can be used with Light Armoured Vehicle (LAV) variants including: armoured personnel carriers and direct-fire support vehicles. OneSAF will be used to assess the performance of these DAS-equipped vehicles on a virtual battlefield.

Attogram sensing of trinitrotoluene with a self-assembled molecular gelator.

PubMed

Kartha, Kalathil K; Babu, Sukumaran S; Srinivasan, Sampath; Ajayaghosh, Ayyappanpillai

2012-03-14

Detection of explosives is of utmost importance due to the threat to human security as a result of illegal transport and terrorist activities. Trinitrotoluene (TNT) is a widely used explosive in landmines and military operations that contaminates the environment and groundwater, posing a threat to human health. Achieving the detection of explosives at a sub-femtogram level using a molecular sensor is a challenge. Herein we demonstrate that a fluorescent organogelator exhibits superior detection capability for TNT in the gel form when compared to that in the solution state. The gel when coated on disposable paper strips detects TNT at a record attogram (ag, 10(-18) g) level (∼12 ag/cm(2)) with a detection limit of 0.23 ppq. This is a simple and low-cost method for the detection of TNT on surfaces or in aqueous solutions in a contact mode, taking advantage of the unique molecular packing of an organogelator and the associated photophysical properties.

Optical detection of explosives: spectral signatures for the explosive bouquet

NASA Astrophysics Data System (ADS)

Osborn, Tabetha; Kaimal, Sindhu; Causey, Jason; Burns, William; Reeve, Scott

2009-05-01

Research with canines suggests that sniffer dogs alert not on the odor from a pure explosive, but rather on a set of far more volatile species present in an explosive as impurities. Following the explosive trained canine example, we have begun examining the vapor signatures for many of these volatile impurities utilizing high resolution spectroscopic techniques in several molecular fingerprint regions. Here we will describe some of these high resolution measurements and discuss strategies for selecting useful spectral signature regions for individual molecular markers of interest.

Stand-off detection of trace explosives by infrared photothermal imaging

NASA Astrophysics Data System (ADS)

Papantonakis, Michael R.; Kendziora, Chris; Furstenberg, Robert; Stepnowski, Stanley V.; Rake, Matthew; Stepnowski, Jennifer; McGill, R. Andrew

2009-05-01

We have developed a technique for the stand-off detection of trace explosives using infrared photothermal imaging. In this approach, infrared quantum cascade lasers tuned to strong vibrational absorption bands of the explosive particles illuminate a surface of interest, preferentially heating the explosives material. An infrared focal plane array is used to image the surface and detect a small increase in the thermal intensity upon laser illumination. We have demonstrated the technique using TNT and RDX residues at several meters of stand-off distance under laboratory conditions, while operating the lasers below the eye-safe intensity limit. Sensitivity to explosives traces as small as a single grain (~100 ng) of TNT has been demonstrated using an uncooled bolometer array. We show the viability of this approach on a variety of surfaces which transmit, reflect or absorb the infrared laser light and have a range of thermal conductivities. By varying the incident wavelength slightly, we demonstrate selectivity between TNT and RDX. Using a sequence of lasers at different wavelengths, we increase both sensitivity and selectivity while reducing the false alarm rate. At higher energy levels we also show it is possible to generate vapor from solid materials with inherently low vapor pressures.

Gas chromatography/ion mobility spectrometry as a hyphenated technique for improved explosives detection and analysis

NASA Technical Reports Server (NTRS)

Mercado, AL; Marsden, Paul

1995-01-01

Ion Mobility Spectrometry (IMS) is currently being successfully applied to the problem of on-line trace detection of plastic and other explosives in airports and other facilities. The methods of sample retrieval primarily consist of batch sampling for particulate residue on a filter card for introduction into the IMS. The sample is desorbed into the IMS using air as the carrier and negative ions of the explosives are detected, some as an adduct with a reagent ion such as Cl(-). Based on studies and tests conducted by different airport authorities, this method seems to work well for low vapor pressure explosives such as RDX and PETN, as well as TNT that are highly adsorptive and can be found in nanogram quantities on contaminated surfaces. Recently, the changing terrorist threat and the adoption of new marking agents for plastic explosives has meant that the sample introduction and analysis capabilities of the IMS must be enhanced in order to keep up with other detector developments. The IMS has sufficient analytical resolution for a few threat compounds but the IMS Plasmogram becomes increasingly more difficult to interpret when the sample mixture gets more complex.

Treatment of Explosives Residues from Range Activities

DTIC Science & Technology

2009-09-01

on the specific proportions of peat moss and crude soybean oil in the PMSO. Detections of TNT, HMX, and the RDX degradation products MNX, DNX, and...83 Table 5.8.1-1. Summary of explosive compound detections in all samples collected over the duration of the demonstration...reduced 12- to 50-fold, depending on the depth. Dissolved TNT and HMX were not detected with enough frequency to allow calculation of fluxes of these

Development Of An In Situ Passive Sampler For The Detection And Remediation of Explosive Compounds

DTIC Science & Technology

2016-06-07

FINAL REPORT Development of an In Situ Passive Sampler for the Detection and Remediation of Explosive Compounds SERDP Project ER-2539 MAY 2016...DATES COVERED (From - To) 4/24/15 – 12/1/2016 4. TITLE AND SUBTITLE Development of an In Situ Passive Sampler for the Detection and Remediation of...SUBJECT TERMS Passive samplers, Ethylene vinyl acetate, EVA sampler, Munitions, Monitoring, Remediation , Marine, Sediments 16. SECURITY

A New Network Modeling Tool for the Ground-based Nuclear Explosion Monitoring Community

NASA Astrophysics Data System (ADS)

Merchant, B. J.; Chael, E. P.; Young, C. J.

2013-12-01

Network simulations have long been used to assess the performance of monitoring networks to detect events for such purposes as planning station deployments and network resilience to outages. The standard tool has been the SAIC-developed NetSim package. With correct parameters, NetSim can produce useful simulations; however, the package has several shortcomings: an older language (FORTRAN), an emphasis on seismic monitoring with limited support for other technologies, limited documentation, and a limited parameter set. Thus, we are developing NetMOD (Network Monitoring for Optimal Detection), a Java-based tool designed to assess the performance of ground-based networks. NetMOD's advantages include: coded in a modern language that is multi-platform, utilizes modern computing performance (e.g. multi-core processors), incorporates monitoring technologies other than seismic, and includes a well-validated default parameter set for the IMS stations. NetMOD is designed to be extendable through a plugin infrastructure, so new phenomenological models can be added. Development of the Seismic Detection Plugin is being pursued first. Seismic location and infrasound and hydroacoustic detection plugins will follow. By making NetMOD an open-release package, it can hopefully provide a common tool that the monitoring community can use to produce assessments of monitoring networks and to verify assessments made by others.

Highly efficient SERS substrate for direct detection of explosive TNT using popcorn-shaped gold nanoparticle-functionalized SWCNT hybrid.

PubMed

Demeritte, Teresa; Kanchanapally, Rajashekhar; Fan, Zhen; Singh, Anant Kumar; Senapati, Dulal; Dubey, Madan; Zakar, Eugene; Ray, Paresh Chandra

2012-11-07

This paper reports for the first time the development of a large-scale SERS substrate from a popcorn-shaped gold nanoparticle-functionalized single walled carbon nanotubes hybrid thin film for the selective and highly sensitive detection of explosive TNT material at a 100 femtomolar (fM) level.

An AIEE fluorescent supramolecular cross-linked polymer network based on pillar[5]arene host-guest recognition: construction and application in explosive detection.

PubMed

Shao, Li; Sun, Jifu; Hua, Bin; Huang, Feihe

2018-05-08

Here a novel fluorescent supramolecular cross-linked polymer network with aggregation induced enhanced emission (AIEE) properties was constructed via pillar[5]arene-based host-guest recognition. Furthermore, the supramolecular polymer network can be used for explosive detection in both solution and thin films.

Development of a Miniature Mass Spectrometer and an Automated Detector for Sampling Explosive Materials

PubMed Central

Hashimoto, Yuichiro

2017-01-01

The development of a robust ionization source using the counter-flow APCI, miniature mass spectrometer, and an automated sampling system for detecting explosives are described. These development efforts using mass spectrometry were made in order to improve the efficiencies of on-site detection in areas such as security, environmental, and industrial applications. A development team, including the author, has struggled for nearly 20 years to enhance the robustness and reduce the size of mass spectrometers to meet the requirements needed for on-site applications. This article focuses on the recent results related to the detection of explosive materials where automated particle sampling using a cyclone concentrator permitted the inspection time to be successfully reduced to 3 s. PMID:28337396

Quantifying the Hydrodynamic Performance of an Explosively-Driven Two-Shock Source

NASA Astrophysics Data System (ADS)

Furlanetto, Michael; Bauer, Amy; King, Robert; Buttler, William; Olson, Russell; Hagelberg, Carl

2015-06-01

An explosively-driven experimental package capable of generating a tunable two-shock drive would enable a host of experiments in shock physics. To make the best use of such a platform, though, its symmetry, reproducibility, and performance must be characterized thoroughly. We report on a series of experiments on a particular two-shock design that used shock reverberation between the sample and a heavy anvil to produce a second shock. Drive package diameters were varied between 50 and 76 mm in order to investigate release wave propagation. We used proton radiography to characterize the detonation and reverberation fronts within the high explosive elements of the packages, as well as surface velocimetry to measure the resulting shock structure in the sample under study. By fielding more than twenty channels of velocimetry per shot, we were able to quantify the symmetry and reproducibility of the drive.

On the Use of Calibration Explosions at the Former Semipalatinsk Test Site for Compiling a Travel-time Model of the Crust and Upper Mantle

NASA Astrophysics Data System (ADS)

Belyashova, N. N.; Shacilov, V. I.; Mikhailova, N. N.; Komarov, I. I.; Sinyova, Z. I.; Belyashov, A. V.; Malakhova, M. N.

- Two chemical calibration explosions, conducted at the former Semipalatinsk nuclear test site in 1998 with charges of 25 tons and 100 tons TNT, have been used for developing travel-time curves and generalized one-dimensional velocity models of the crust and upper mantle of the platform region of Kazakhstan. The explosions were recorded by a number of digital seismic stations, located in Kazakhstan at distances ranging from 0 to 720km. The travel-time tables developed in this paper cover the phases P, Pn, Pg, S, Sn, Lg in a range of 0-740km and the velocity models apply to the crust down to 44km depth and to the mantle down to 120km. A comparison of the compiled travel-time tables with existing travel-time tables of CSE and IASPEI91 is presented.

The Detection And Analysis Of Blasting Problems Encountered In A Colliery Using High Speed Photography

NASA Astrophysics Data System (ADS)

Rorke, A. J.; Kohler, E. W.

1987-09-01

Premature initiation of ANFO (an explosive mixture of Ammonium Nitrate and Fuel Oil) at a large colliery, near Witbank, was first detected from routine high speed films taken of large mid-burden, and overburden blasts. The analysis of these films shows that the rapid migration of very hot gasses through cracks ahead of the blast may have caused the explosive to initiate prematurely. The problem was not seen in the less competent overburden rocks. A less sensitive explosive has been successfully tried. The assessment of these blasts using high speed photography is discussed.

Template-directed synthesis of silica nanotubes for explosive detection.

PubMed

Yildirim, Adem; Acar, Handan; Erkal, Turan S; Bayindir, Mehmet; Guler, Mustafa O

2011-10-01

Fluorescent porous organic-inorganic thin films are of interest of explosive detection because of their vapor phase fluorescence quenching property. In this work, we synthesized fluorescent silica nanotubes using a biomineralization process through self-assembled peptidic nanostructures. We designed and synthesized an amyloid-like peptide self-assembling into nanofibers to be used as a template for silica nanotube formation. The amine groups on the peptide nanofibrous system were used for nucleation of silica nanostructures. Silica nanotubes were used to prepare highly porous surfaces, and they were doped with a fluorescent dye by physical adsorption for explosive sensing. These porous surfaces exhibited fast, sensitive, and highly selective fluorescence quenching against nitro-explosive vapors. The materials developed in this work have vast potential in sensing applications due to enhanced surface area. © 2011 American Chemical Society

Concussive brain injury from explosive blast

PubMed Central

de Lanerolle, Nihal C; Hamid, Hamada; Kulas, Joseph; Pan, Jullie W; Czlapinski, Rebecca; Rinaldi, Anthony; Ling, Geoffrey; Bandak, Faris A; Hetherington, Hoby P

2014-01-01

Objective Explosive blast mild traumatic brain injury (mTBI) is associated with a variety of symptoms including memory impairment and posttraumatic stress disorder (PTSD). Explosive shock waves can cause hippocampal injury in a large animal model. We recently reported a method for detecting brain injury in soldiers with explosive blast mTBI using magnetic resonance spectroscopic imaging (MRSI). This method is applied in the study of veterans exposed to blast. Methods The hippocampus of 25 veterans with explosive blast mTBI, 20 controls, and 12 subjects with PTSD but without exposure to explosive blast were studied using MRSI at 7 Tesla. Psychiatric and cognitive assessments were administered to characterize the neuropsychiatric deficits and compare with findings from MRSI. Results Significant reductions in the ratio of N-acetyl aspartate to choline (NAA/Ch) and N-acetyl aspartate to creatine (NAA/Cr) (P < 0.05) were found in the anterior portions of the hippocampus with explosive blast mTBI in comparison to control subjects and were more pronounced in the right hippocampus, which was 15% smaller in volume (P < 0.05). Decreased NAA/Ch and NAA/Cr were not influenced by comorbidities – PTSD, depression, or anxiety. Subjects with PTSD without blast had lesser injury, which tended to be in the posterior hippocampus. Explosive blast mTBI subjects had a reduction in visual memory compared to PTSD without blast. Interpretation The region of the hippocampus injured differentiates explosive blast mTBI from PTSD. MRSI is quite sensitive in detecting and localizing regions of neuronal injury from explosive blast associated with memory impairment. PMID:25493283

"US-detonated nano bombs" facilitate targeting treatment of resistant breast cancer.

PubMed

Shi, Jinjin; Liu, Wei; Fu, Yu; Yin, Na; Zhang, Hongling; Chang, Junbiao; Zhang, Zhenzhong

2018-03-28

Reversal of drug resistance and targeted therapy are the keys but remain challenging in resistant breast cancer treatment. Herein, low frequency ultrasound detonated "nano bombs" were rationally designed and used for treatment of resistant breast cancer. For the 'nano bombs', the ammunition (Doxorubicin, DOX) was loaded into the ammunition depot (hollow mesoporous TiO 2 , MTNs), and the safety device (dsDNA) was wrapped on the surface of MTNs to avoid the unexpected DOX release. We found the "US-detonated explosive" abilities of "nano bomb" MTNs (NBMTNs), including explosive generation of ROS, explosive release of DOX, US-triggered lysosome escape and mitochondrial targeting in the in vitro and in vivo studies. More importantly, the drug resistance of MCF-7/ADR cells could be reversed via the inhibition of mitochondrial energy supply approach caused by the "explosion" of NBMTNs. Furthermore, NBMTNs combined the superior chemotherapy efficacy of DOX and potent SDT efficacy in one single platform and significantly enhanced the anticancer efficacy. Our results demonstrate an approach for reversing resistance and specific targeting of tumors using 'US-detonated nano bombs'. Copyright © 2018 Elsevier B.V. All rights reserved.

Atmospheric Transport Modelling assessing radionuclide detection chances after the nuclear test announced by the DPRK in January 2016

NASA Astrophysics Data System (ADS)

Ross, J. Ole; Ceranna, Lars

2016-04-01

The Comprehensive Nuclear-Test-Ban Treaty (CTBT) prohibits all kinds of nuclear explosions. The International Monitoring System (IMS) is in place and at about 90% complete to verify compliance with the CTBT. The stations of the waveform technologies are capable to detect seismic, hydro-acoustic and infrasonic signals for detection, localization, and characterization of explosions. The seismic signals of the DPRK event on 6 January 2016 were detected by many seismic stations around the globe and allow for localization of the event and identification as explosion (see poster by G. Hartmann et al.). However, the direct evidence for a nuclear explosion is only possible through the detection of nuclear fission products which may be released. For that 80 Radionuclide (RN) Stations are part of the designed IMS, about 60 are already operational. All RN stations are highly sensitive for tiny traces of particulate radionuclides in large volume air samplers. There are 40 of the RN stations designated to be equipped with noble gas systems detecting traces of radioactive xenon isotopes which are more likely to escape from an underground test cavity than particulates. Already 30 of the noble gas systems are operational. Atmospheric Transport Modelling supports the interpretation of radionuclide detections (and as appropriate non-detections) by connecting the activity concentration measurements with potential source locations and release times. In our study forecasts with the Lagrangian Particle Dispersion Model HYSPLIT (NOAA) and GFS (NCEP) meteorological data are considered to assess the plume propagation patterns for hypothetical releases at the known DPRK nuclear test site. The results show a considerable sensitivity of the IMS station RN 38 Takasaki (Japan) to a potential radionuclide release at the test site in the days and weeks following the explosion in January 2016. In addition, backtracking simulations with ECMWF analysis data in 0.2° horizontal resolution are performed for selected samples to get a complementary estimation of the sensitivities and the connected thresholds for detectable releases.The meteorological situation is compared to the aftermath of the nuclear explosion on 12 February 2013 after which a specific occurrence of an unusual 131mXe signature at RN 38 eight weeks after the test could be very likely attributed to a late release from the DPRK event.

Common IED exploitation target set ontology

NASA Astrophysics Data System (ADS)

Russomanno, David J.; Qualls, Joseph; Wowczuk, Zenovy; Franken, Paul; Robinson, William

2010-04-01

The Common IED Exploitation Target Set (CIEDETS) ontology provides a comprehensive semantic data model for capturing knowledge about sensors, platforms, missions, environments, and other aspects of systems under test. The ontology also includes representative IEDs; modeled as explosives, camouflage, concealment objects, and other background objects, which comprise an overall threat scene. The ontology is represented using the Web Ontology Language and the SPARQL Protocol and RDF Query Language, which ensures portability of the acquired knowledge base across applications. The resulting knowledge base is a component of the CIEDETS application, which is intended to support the end user sensor test and evaluation community. CIEDETS associates a system under test to a subset of cataloged threats based on the probability that the system will detect the threat. The associations between systems under test, threats, and the detection probabilities are established based on a hybrid reasoning strategy, which applies a combination of heuristics and simplified modeling techniques. Besides supporting the CIEDETS application, which is focused on efficient and consistent system testing, the ontology can be leveraged in a myriad of other applications, including serving as a knowledge source for mission planning tools.

Use of Mass Spectrometric Vapor Analysis To Improve Canine Explosive Detection Efficiency.

PubMed

Ong, Ta-Hsuan; Mendum, Ted; Geurtsen, Geoff; Kelley, Jude; Ostrinskaya, Alla; Kunz, Roderick

2017-06-20

Canines remain the gold standard for explosives detection in many situations, and there is an ongoing desire for them to perform at the highest level. This goal requires canine training to be approached similarly to scientific sensor design. Developing a canine training regimen is made challenging by a lack of understanding of the canine's odor environment, which is dynamic and typically contains multiple odorants. Existing methodology assumes that the handler's intention is an adequate surrogate for actual knowledge of the odors cuing the canine, but canines are easily exposed to unintentional explosive odors through training material cross-contamination. A sensitive, real-time (∼1 s) vapor analysis mass spectrometer was developed to provide tools, techniques, and knowledge to better understand, train, and utilize canines. The instrument has a detection library of nine explosives and explosive-related materials consisting of 2,4-dinitrotoluene (2,4-DNT), 2,6-dinitrotoluene (2,6-DNT), 2,4,6-trinitrotoluene (TNT), nitroglycerin (NG), 1,3,5-trinitroperhydro-1,3,5-triazine (RDX), pentaerythritol tetranitrate (PETN), triacetone triperoxide (TATP), hexamethylene triperoxide diamine (HMTD), and cyclohexanone, with detection limits in the parts-per-trillion to parts-per-quadrillion range by volume. The instrument can illustrate aspects of vapor plume dynamics, such as detecting plume filaments at a distance. The instrument was deployed to support canine training in the field, detecting cross-contamination among training materials, and developing an evaluation method based on the odor environment. Support for training material production and handling was provided by studying the dynamic headspace of a nonexplosive HMTD training aid that is in development. These results supported existing canine training and identified certain areas that may be improved.

Mesoporous aluminium organophosphonates: a reusable chemsensor for the detection of explosives

DOE Office of Scientific and Technical Information (OSTI.GOV)

Li, Dongdong, E-mail: lidongdong@jlu.edu.cn; Yu, Xiang

Rapid and sensitive detection of explosives is in high demand for homeland security and public safety. In this work, electron-rich of anthracene functionalized mesoporous aluminium organophosphonates (En-AlPs) were synthesized by a one-pot condensation process. The mesoporous structure and strong blue emission of En-AlPs were confirmed by the N{sub 2} adsorption-desorption isotherms, transmission electron microscopy images and fluorescence spectra. The materials En-AlPs can serve as sensitive chemosensors for various electron deficient nitroderivatives, with the quenching constant and the detection limit up to 1.5×10{sup 6} M{sup −1} and 0.3 ppm in water solution. More importantly, the materials can be recycled for manymore » times by simply washed with ethanol, showing potential applications in explosives detection. - Graphical abstract: Electron-rich of anthracene functionalized mesoporous aluminium organophosphonates can serve as sensitive and recycled chemosensors for nitroderivatives with the quenching constant up to 1.5×10{sup 6} M{sup −1} in water solution. Display Omitted - Highlights: • Anthracene functionalized mesoporous aluminium organophosphonates were synthesized. • The materials serve as sensitive chemosensors for nitroderivatives. • The materials can be recycled for many times by simply washed with ethanol. • The materials show potential applications in explosives detection.« less

Low cost mobile explosive/drug detection devices

DOE Office of Scientific and Technical Information (OSTI.GOV)

Gozani, T.; Bendahan, J.

1999-06-10

Inspection technologies based on Thermal Neutron Analysis (TNA) and/or Fast Neutron Analysis (FNA) are the basis for relatively compact and low-cost, material-sensitive devices for a wide variety of inspection needs. The TNA allows the use of either isotropic neutron sources such as a {sup 252}Cf, or electronic neutron generators such as the d-T sealed neutron generator tubes. The latter could be used in a steady state mode or in slow (>{mu}s) pulsing mode, to separate the thermal neutron capture signatures following the pulse from the combination of the FNA plus TNA signatures during the pulse. Over the years, Ancore Corporationmore » has built and is continuing to develop a variety of inspection devices based on its TNA and FNA technologies: SPEDS--an explosive detection device for small parcels, portable electronics, briefcases and other similar carry-on items; MDS - a system for the detection or confirmation of buried mines; VEDS - a system for the detection of varied amounts of explosives and/or drugs concealed in passenger vehicles, pallets, lightly loaded trucks or containers, etc.; ACD - a device to clear alarms from a primary, non-specific explosive detection system for passenger luggage. The principle and performance of these devices will be shown and discussed.« less

Dynamic planar solid phase microextraction-ion mobility spectrometry for rapid field air sampling and analysis of illicit drugs and explosives.

PubMed

Guerra-Diaz, Patricia; Gura, Sigalit; Almirall, José R

2010-04-01

A preconcentration device that targets the volatile chemical signatures associated with illicit drugs and explosives (high and low) has been designed to fit in the inlet of an ion mobility spectrometer (IMS). This is the first reporting of a fast and sensitive method for dynamic sampling of large volumes of air using planar solid phase microextraction (PSPME) incorporating a high surface area for absorption of analytes onto a sol-gel polydimethylsiloxane (PDMS) coating for direct thermal desorption into an IMS. This device affords high extraction efficiencies due to strong retention properties at ambient temperature, resulting in the detection of analyte concentrations in the parts per trillion range when as low as 3.5 L of air are sampled over the course of 10 s (absolute mass detection of less than a nanogram). Dynamic PSPME was used to sample the headspace over the following: 3,4-methylenedioxymethamphetamine (MDMA) tablets resulting in the detection of 12-40 ng of piperonal, high explosives (Pentolite) resulting in the detection of 0.6 ng of 2,4,6-trinitrotoluene (TNT), and low explosives (several smokeless powders) resulting in the detection of 26-35 ng of 2,4-dinitrotoluene (2,4-DNT) and 11-74 ng of diphenylamine (DPA).

Aspects of the Application of Cavity Enhanced Spectroscopy to Nitrogen Oxides Detection

PubMed Central

Wojtas, Jacek; Mikolajczyk, Janusz; Bielecki, Zbigniew

2013-01-01

This article presents design issues of high-sensitive laser absorption spectroscopy systems for nitrogen oxides (NOx) detection. Examples of our systems and their investigation results are also described. The constructed systems use one of the most sensitive methods, cavity enhanced absorption spectroscopy (CEAS). They operate at different wavelength ranges using a blue—violet laser diode (410 nm) as well as quantum cascade lasers (5.27 μm and 4.53 μm). Each of them is configured as a one or two channel measurement device using, e.g., time division multiplexing and averaging. During the testing procedure, the main performance features such as detection limits and measurements uncertainties have been determined. The obtained results are 1 ppb NO2, 75 ppb NO and 45 ppb N2O. For all systems, the uncertainty of concentration measurements does not exceed a value of 13%. Some experiments with explosives are also discussed. A setup equipped with a concentrator of explosives vapours was used. The detection method is based either on the reaction of the sensors to the nitrogen oxides directly emitted by the explosives or on the reaction to the nitrogen oxides produced during thermal decomposition of explosive vapours. For TNT, PETN, RDX and HMX a detection limit better than 1 ng has been achieved. PMID:23752566

Optical detection of buried explosive hazards: a longitudinal comparison of three types of imagery

NASA Astrophysics Data System (ADS)

Staszewski, James J.; Hibbitts, Charles H.; Davis, Luke; Bursley, James

2013-06-01

Visual detection of soil disturbances is a surprisingly effective, but far from perfect way of detecting buried explosive threats such as landmines and improvised explosive devices (IEDs). This effort builds upon the few systematic studies of optical detection in this area. It investigates observer sensitivity to optical information produced by the burial of anti-tank and small anti-personnel landmines asking "How detectable are disturbed soil signatures captured in visible (VIS), shortwave infrared (SWIR), and thermal infrared (TIR), bands?" "Which band or bands are most effective for detection?" and "How well does each band support detection in the natural environment over time?" Using signal detection procedures this study presented young adults photographs showing soil disturbed by landmine burial or adjacent undisturbed surfaces with instructions to make decisions about the presence or absence of a disturbance. Stimuli spanned a six-week time period over which VIS, SWIR, and TIR imagery was collected. Results show that (a) signal strength persists surprisingly well over the observation period, (b) generally, SWIR and VIS show consistently strong performance for large anti-tank mines and SWIR shows the soil signature for the small, anti-personnel mine remarkably well. TIR lags the other two bands when using d' to measure performance, but shows promising hit rates for anti-tank mine signatures under appropriate conditions. Generally, results show that the SWIR and VIS bands show most promise as a practical means of explosive hazards detection, although TIR can work effectively for large anti-tank mines under certain conditions. Limitations and implications for further research are discussed.

Standoff detection of explosive molecules using nanosecond gated Raman spectroscopy

NASA Astrophysics Data System (ADS)

Chung, Jin Hyuk; Cho, Soo Gyeong

2013-06-01

Recently, improvised explosive device (IED) has been a serious threat for many countries. One of the approaches to alleviate this threat is standoff detection of explosive molecules used in IEDs. Raman spectroscopy is a prospective method among many technologies under research to achieve this goal. It provides unique information of the target materials, through which the ingredients used in IEDs can be analyzed and identified. The main problem of standoff Raman spectroscopic detection is the large background noise hindering weak Raman signals from the target samples. Typical background noise comes from both ambient fluorescent lights indoor and sunlight outdoor whose intensities are usually much larger than that of Raman scattering from the sample. Under the proper condition using pulse laser and ICCD camera with nanosecond pulse width and gating technology, we succeed to separate and remove these background noises from Raman signals. For this experiment, we build an optical system for standoff detection of explosive molecules. We use 532 nm, 10 Hz, Q-switching Nd:YAG laser as light source, and ICCD camera triggered by laser Qswitching time with proper gate delay regarding the flight time of Raman from target materials. Our detection system is successfully applied to detect and identify more than 20 ingredients of IEDs including TNT, RDX, and HMX which are located 10 to 54 meters away from the system.

Maintenance energy requirements of odor detection, explosive detection and human detection working dogs.

PubMed

Mullis, Rebecca A; Witzel, Angela L; Price, Joshua

2015-01-01

Despite their important role in security, little is known about the energy requirements of working dogs such as odor, explosive and human detection dogs. Previous researchers have evaluated the energy requirements of individual canine breeds as well as dogs in exercise roles such as sprint racing. This study is the first to evaluate the energy requirements of working dogs trained in odor, explosive and human detection. This retrospective study evaluated twenty adult dogs who maintained consistent body weights over a six month period. During this time, the average energy consumption was [Formula: see text] or two times the calculated resting energy requirement ([Formula: see text]). No statistical differences were found between breeds, age or sex, but a statistically significant association (p = 0.0033, R-square = 0.0854) was seen between the number of searches a dog performs and their energy requirement. Based on this study's population, it appears that working dogs have maintenance energy requirements similar to the 1974 National Research Council's (NRC) maintenance energy requirement of [Formula: see text] (National Research Council (NRC), 1974) and the [Formula: see text] reported for young laboratory beagles (Rainbird & Kienzle, 1990). Additional research is needed to determine if these data can be applied to all odor, explosive and human detection dogs and to determine if other types of working dogs (tracking, search and rescue etc.) have similar energy requirements.

Computing Platforms for Big Biological Data Analytics: Perspectives and Challenges.

PubMed

Yin, Zekun; Lan, Haidong; Tan, Guangming; Lu, Mian; Vasilakos, Athanasios V; Liu, Weiguo

2017-01-01

The last decade has witnessed an explosion in the amount of available biological sequence data, due to the rapid progress of high-throughput sequencing projects. However, the biological data amount is becoming so great that traditional data analysis platforms and methods can no longer meet the need to rapidly perform data analysis tasks in life sciences. As a result, both biologists and computer scientists are facing the challenge of gaining a profound insight into the deepest biological functions from big biological data. This in turn requires massive computational resources. Therefore, high performance computing (HPC) platforms are highly needed as well as efficient and scalable algorithms that can take advantage of these platforms. In this paper, we survey the state-of-the-art HPC platforms for big biological data analytics. We first list the characteristics of big biological data and popular computing platforms. Then we provide a taxonomy of different biological data analysis applications and a survey of the way they have been mapped onto various computing platforms. After that, we present a case study to compare the efficiency of different computing platforms for handling the classical biological sequence alignment problem. At last we discuss the open issues in big biological data analytics.

SWAN - Detection of explosives by means of fast neutron activation analysis

NASA Astrophysics Data System (ADS)

Gierlik, M.; Borsuk, S.; Guzik, Z.; Iwanowska, J.; Kaźmierczak, Ł.; Korolczuk, S.; Kozłowski, T.; Krakowski, T.; Marcinkowski, R.; Swiderski, L.; Szeptycka, M.; Szewiński, J.; Urban, A.

2016-10-01

In this work we report on SWAN, the experimental, portable device for explosives detection. The device was created as part of the EU Structural Funds Project "Accelerators & Detectors" (POIG.01.01.02-14-012/08-00), with the goal to increase beneficiary's expertise and competencies in the field of neutron activation analysis. Previous experiences and budged limitations lead toward a less advanced design based on fast neutron interactions and unsophisticated data analysis with the emphasis on the latest gamma detection and spectrometry solutions. The final device has been designed as a portable, fast neutron activation analyzer, with the software optimized for detection of carbon, nitrogen and oxygen. SWAN's performance in the role of explosives detector is elaborated in this paper. We demonstrate that the unique features offered by neutron activation analysis might not be impressive enough when confronted with practical demands and expectations of a generic homeland security customer.

The 2014 Integrated Field Exercise of the Comprehensive Nuclear-Test-Ban Treaty revisited: The case for data fusion.

PubMed

Burnett, Jonathan L; Miley, Harry S; Bowyer, Theodore W; Cameron, Ian M

2018-09-01

The International Monitoring System of the Preparatory Commission for the Comprehensive Nuclear-Test-Ban Treaty Organization (CTBTO) uses a global network of radionuclide monitoring stations to detect evidence of a nuclear explosion. The two radionuclide technologies employed-particulate and noble gas (radioxenon) detection-have applications for data fusion to improve detection of a nuclear explosion. Using the hypothetical 0.5 kT nuclear explosive test scenario of the CTBTO 2014 Integrated Field Exercise, the intrinsic relationship between particulate and noble gas signatures has been examined. This study shows that, depending upon the time of the radioxenon release, the particulate progeny can produce the more detectable signature. Thus, as both particulate and noble gas signatures are inherently coupled, the authors recommend that the sample categorization schemes should be linked. Copyright © 2018 Elsevier Ltd. All rights reserved.

Nanoporous Substrate with Mixed Nanoclusters for Surface Enhanced Raman Scattering.

NASA Astrophysics Data System (ADS)

Chang, Sehoon; Ko, Hyunhyub; Singamaneni, Srikanth; Gunawidjaja, Ray; Tsukruk, Vladimir

2009-03-01

Rapid detection of plastic and liquid explosives is an urgent need due to various societal and technological reasons. We employed a novel design of surface enhanced Raman scattering (SERS)-active substrate based on porous alumina membranes decorated with mixed nanoclusters of gold nanorods and nanoparticles. We demonstrated trace level detection of several important explosives such as dinitrotolene (DNT), trinitrotoluene (TNT), and hexamethylenetriperoxidediamine (HMTD) by fast, sensitive, reliable Raman spectroscopic method. We achieved near molecular-level detection (about 15˜ 30 molecules) of DNT and TNT utilizing the SERS substrate. However, trace level detection is challenging due to the lack of common optical signatures (fluorescence, absorption in UV-vis range) or chemical functionality of peroxide-based explosives such as HMTD. To overcome this, we employed photochemical decomposition approach and analyzed chemical fragments using SERS. We suggest that tailored polymer coating, mixed nanoclusters, and laser-induced photocatalytic decomposition are all critical for achieving this unprecedented sensitivity level..

49 CFR 1542.221 - Records of law enforcement response.

Code of Federal Regulations, 2012 CFR

2012-10-01

..., explosives, or incendiaries discovered during any passenger-screening process, and the method of detection of..., explosive, or incendiary confiscated, as appropriate; and (iii) Identification of the aircraft operators or...

49 CFR 1542.221 - Records of law enforcement response.

Code of Federal Regulations, 2014 CFR

2014-10-01

..., explosives, or incendiaries discovered during any passenger-screening process, and the method of detection of..., explosive, or incendiary confiscated, as appropriate; and (iii) Identification of the aircraft operators or...

49 CFR 1542.221 - Records of law enforcement response.

Code of Federal Regulations, 2011 CFR

2011-10-01

..., explosives, or incendiaries discovered during any passenger-screening process, and the method of detection of..., explosive, or incendiary confiscated, as appropriate; and (iii) Identification of the aircraft operators or...

49 CFR 1542.221 - Records of law enforcement response.

Code of Federal Regulations, 2013 CFR

2013-10-01

..., explosives, or incendiaries discovered during any passenger-screening process, and the method of detection of..., explosive, or incendiary confiscated, as appropriate; and (iii) Identification of the aircraft operators or...

Use of UV Sources for Detection and Identification of Explosives

NASA Technical Reports Server (NTRS)

Hug, William; Reid, Ray; Bhartia, Rohit; Lane, Arthur

2009-01-01

Measurement of Raman and native fluorescence emission using ultraviolet (UV) sources (<400 nm) on targeted materials is suitable for both sensitive detection and accurate identification of explosive materials. When the UV emission data are analyzed using a combination of Principal Component Analysis (PCA) and cluster analysis, chemicals and biological samples can be differentiated based on the geometric arrangement of molecules, the number of repeating aromatic rings, associated functional groups (nitrogen, sulfur, hydroxyl, and methyl), microbial life cycles (spores vs. vegetative cells), and the number of conjugated bonds. Explosive materials can be separated from one another as well as from a range of possible background materials, which includes microbes, car doors, motor oil, and fingerprints on car doors, etc. Many explosives are comprised of similar atomic constituents found in potential background samples such as fingerprint oils/skin, motor oil, and soil. This technique is sensitive to chemical bonds between the elements that lead to the discriminating separability between backgrounds and explosive materials.

Deep belief networks for false alarm rejection in forward-looking ground-penetrating radar

NASA Astrophysics Data System (ADS)

Becker, John; Havens, Timothy C.; Pinar, Anthony; Schulz, Timothy J.

2015-05-01

Explosive hazards are one of the most deadly threats in modern conflicts. The U.S. Army is interested in a reliable way to detect these hazards at range. A promising way of accomplishing this task is using a forward-looking ground-penetrating radar (FLGPR) system. Recently, the Army has been testing a system that utilizes both L-band and X-band radar arrays on a vehicle mounted platform. Using data from this system, we sought to improve the performance of a constant false-alarm-rate (CFAR) prescreener through the use of a deep belief network (DBN). DBNs have also been shown to perform exceptionally well at generalized anomaly detection. They combine unsupervised pre-training with supervised fine-tuning to generate low-dimensional representations of high-dimensional input data. We seek to take advantage of these two properties by training a DBN on the features of the CFAR prescreener's false alarms (FAs) and then use that DBN to separate FAs from true positives. Our analysis shows that this method improves the detection statistics significantly. By training the DBN on a combination of image features, we were able to significantly increase the probability of detection while maintaining a nominal number of false alarms per square meter. Our research shows that DBNs are a good candidate for improving detection rates in FLGPR systems.

Surface scattering plasmon resonance fibre sensors: demonstration of rapid influenza A virus detection

NASA Astrophysics Data System (ADS)

Franςois, A.; Boehm, J.; Oh, S. Y.; Kok, T.; Monro, T. M.

2011-06-01

The management of threats such as pandemics and explosives, and of health and the environment requires the rapid deployment of highly sensitive detection tools. Sensors based on Surface Plasmon Resonance (SPR) allow rapid, labelfree, highly sensitive detection, and indeed this phenomenon underpins the only label-free optical biosensing technology that is available commercially. In these sensors, the existence of surface plasmons is inferred indirectly from absorption features that correspond to the coupling of light to the surface plasmon. Although SPR is not intrinsically a radiative process, under certain conditions the surface plasmon can itself couple to the local photon states, and emit light as first described byKretschmann. Here we show that by collecting and characterising this re-emitted light, it is possible to realise new SPR sensing architectures that are more compact, versatile and robust than existing approaches. This approach addresses existing practical limitations associated with current SPR technologies, including bulk, cost and calibration. It is applicable to a range of SPR geometries, including optical fibres, planar waveguides and prism configurations, and is in principle capable of detecting multiple analytes simultaneously. Moreover, this technique allows to combine SPR sensing and fluorescence sensing into a single platform which has never been demonstrated before and consequently use these two methods for a more reliable diagnostic. As an example, this approach has been used to demonstrate the rapid detection of the seasonal influenza virus.

Nanobioprobe mediated DNA aptamers for explosive detection.

PubMed

Priyanka; Shorie, Munish; Bhalla, Vijayender; Pathania, Preeti; Suri, C Raman

2014-02-04

Specific nucleic acid aptamers using the microtiter plate based modified SELEX method against explosive trinitrotoluene are reported. Efficient partitioning of dsDNA was carried out using streptavidin labeled gold nanoprobes for the selection of specific aptamers. The selected binders having an affinity of ~10(-7) M were used in the newly developed electrochemical aptasensor, exhibiting a detection limit of around 1 ppb for trinitrotoluene.

DOE Office of Scientific and Technical Information (OSTI.GOV)

Burrows, T.A.; Thoma, P.J.

Two types of ion-mobility detectors were evaluated in both laboratory and field tests. Laboratory test results show that these detectors are highly sensitive to dynamite and pistol powder and have good false-alarm agent rejection. Field tests of these two detectors revealed that they would detect dynamite and Ball-C-Propellent in free air. However, neither of the ion-mobility detectors would detect these explosives if the explosives were concealed.

Scientists Train Honeybees to Detect Explosives

ScienceCinema

None

2018-01-16

Members of the Los Alamos National Laboratory Stealthy Insect Sensor Project team have been able to harness the honeybee's exceptional olfactory sense by using the bees' natural reaction to nectar, a proboscis extension reflex (sticking out their tongue) to record an unmistakable response to a scent. Using Pavlovian techniques, researchers were able to train the bees to give a positive detection response via the PER when exposed to vapors from TNT, C4, and TATP explosives. The Stealthy Insect Sensor Project was born out of a global threat from the growing use of improvised explosive devices or IEDs, especially those that present a critical vulnerability for American military troops in Iraq and Afghanistan, and as an emerging danger for civilians worldwide. Current strategies to detect explosives are expensive and, in the case of trained detection dogs, too obtrusive to be used very discreetly. With bees however, they are small and discreet, offering the element of surprise. They're also are inexpensive to maintain and even easier to train than dogs. As a result of this need, initial funding for the work was provided by a development grant from the Defense Advanced Research Projects Agency.

Scientists Train Honeybees to Detect Explosives

DOE Office of Scientific and Technical Information (OSTI.GOV)

None

2008-03-21

Members of the Los Alamos National Laboratory Stealthy Insect Sensor Project team have been able to harness the honeybee's exceptional olfactory sense by using the bees' natural reaction to nectar, a proboscis extension reflex (sticking out their tongue) to record an unmistakable response to a scent. Using Pavlovian techniques, researchers were able to train the bees to give a positive detection response via the PER when exposed to vapors from TNT, C4, and TATP explosives. The Stealthy Insect Sensor Project was born out of a global threat from the growing use of improvised explosive devices or IEDs, especially those thatmore » present a critical vulnerability for American military troops in Iraq and Afghanistan, and as an emerging danger for civilians worldwide. Current strategies to detect explosives are expensive and, in the case of trained detection dogs, too obtrusive to be used very discreetly. With bees however, they are small and discreet, offering the element of surprise. They're also are inexpensive to maintain and even easier to train than dogs. As a result of this need, initial funding for the work was provided by a development grant from the Defense Advanced Research Projects Agency.« less

Monitoring non-thermal plasma processes for nanoparticle synthesis

NASA Astrophysics Data System (ADS)

Mangolini, Lorenzo

2017-09-01

Process characterization tools have played a crucial role in the investigation of dusty plasmas. The presence of dust in certain non-thermal plasma processes was first detected by laser light scattering measurements. Techniques like laser induced particle explosive evaporation and ion mass spectrometry have provided the experimental evidence necessary for the development of the theory of particle nucleation in silane-containing non-thermal plasmas. This review provides first a summary of these early efforts, and then discusses recent investigations using in situ characterization techniques to understand the interaction between nanoparticles and plasmas. The advancement of such monitoring techniques is necessary to fully develop the potential of non-thermal plasmas as unique materials synthesis and processing platforms. At the same time, the strong coupling between materials and plasma properties suggest that it is also necessary to advance techniques for the measurement of plasma properties while in presence of dust. Recent progress in this area will be discussed.

The GraVent DDT database

NASA Astrophysics Data System (ADS)

Boeck, Lorenz R.; Katzy, Peter; Hasslberger, Josef; Kink, Andreas; Sattelmayer, Thomas

2016-09-01

An open-access online platform containing data from experiments on deflagration-to-detonation transition conducted at the Institute of Thermodynamics, Technical University of Munich, has been developed and is accessible at http://www.td.mw.tum.de/ddt. The database provides researchers working on explosion dynamics with data for theoretical analyses and for the validation of numerical simulations.

An Improved Shock Model for Bare and Covered Explosives

NASA Astrophysics Data System (ADS)

Scholtes, Gert; Bouma, Richard

2017-06-01

TNO developed a toolbox to estimate the probability of a violent event on a ship or other platform, when the munition bunker is hit by e.g. a bullet or fragment from a missile attack. To obtain the proper statistical output, several millions of calculations are needed to obtain a reliable estimate. Because millions of different scenarios have to be calculated, hydrocode calculations cannot be used for this type of application, but a fast and good engineering solutions is needed. At this moment the Haskins and Cook-model is used for this purpose. To obtain a better estimate for covered explosives and munitions, TNO has developed a new model which is a combination of the shock wave model at high pressure, as described by Haskins and Cook, in combination with the expanding shock wave model of Green. This combined model gives a better fit with the experimental values for explosives response calculations, using the same critical energy fluence values for covered as well as for bare explosives. In this paper the theory is explained and results of the calculations for several bare and covered explosives will be presented. To show this, the results will be compared with the experimental values from literature for composition B, Composition B-3 and PBX-9404.

Monitoring of atmospheric nuclear explosions with infrasonic microphone arrays

NASA Astrophysics Data System (ADS)

Wilson, Charles R.

2002-11-01

A review is given of the various United States programs for the infrasonic monitoring of atmospheric nuclear explosions from their inception in 1946 to their termination in 1975. The US Atomic Energy Detection System (USAEDS) monitored all nuclear weapons tests that were conducted by the Soviet Union, France, China, and the US with arrays of sensitive microbarographs in a worldwide network of infrasonic stations. A discussion of the source mechanism for the creation and subsequent propagation around the globe of long wavelength infrasound from explosions (volcanic and nuclear) is given to show the efficacy of infrasonic monitoring for the detection of atmospheric nuclear weapons tests. The equipment that was used for infrasound detection, the design of the sensor arrays, and the data processing techniques that were used by USAEDS are all discussed.

On the prompt identification of traces of explosives

NASA Astrophysics Data System (ADS)

Trobajo, M. T.; López-Cabeceira, M. M.; Carriegos, M. V.; Díez-Machío, H.

2014-12-01

Some recent results in the use of Raman spectroscopy for recognition of explosives are reviewed. Experimental study using spectra data base has been developed. In order to simulate a more real situation, both blank substances and explosives substances have been considered in this research. Statistic classification techniques have been performed. Estimations of prediction errors were obtained by cross-validation methods. These results can be applied in airport security systems in order to prevent terror acts (by the detection of explosive/flammable substances).

Remote detection of explosives using Raman spectroscopy

NASA Astrophysics Data System (ADS)

Fulton, Jack

2011-05-01

Stand-off detection of potentially hazardous small molecules at distances that allow the user to be safe has many applications, including explosives and chemical threats. The Naval Surface Warfare Center, Crane Division, with EYZtek, Inc. of Ohio, developed a prototype stand-off, eye-safe Raman spectrometer. With a stand-off distance greater than twenty meters and scanning optics, this system has the potential of addressing particularly difficult challenges in small molecule detection. An overview of the system design and desired application space is presented.

YouTube as a participatory culture.

PubMed

Chau, Clement

2010-01-01

There is an explosion of youth subscriptions to original content-media-sharing Web sites such as YouTube. These Web sites combine media production and distribution with social networking features, making them an ideal place to create, connect, collaborate, and circulate. By encouraging youth to become media creators and social networkers, new media platforms such as YouTube offer a participatory culture in which youth can develop, interact, and learn. As youth development researchers, we must be cognizant of this context and critically examine what this platform offers that might be unique to (or redundant of) typical adolescent experiences in other developmental contexts.

Seismological analysis of the fourth North Korean nuclear test

NASA Astrophysics Data System (ADS)

Hartmann, Gernot; Gestermann, Nicolai; Ceranna, Lars

2016-04-01

The Democratic People's Republic of Korea has conducted its fourth underground nuclear explosions on 06.01.2016 at 01:30 (UTC). The explosion was clearly detected and located by the seismic network of the International Monitoring System (IMS) of the Comprehensive Nuclear-Test-Ban Treaty (CTBT). Additional seismic stations of international earthquake monitoring networks at regional distances, which are not part of the IMS, are used to precisely estimate the epicenter of the event in the North Hamgyong province (41.38°N / 129.05°E). It is located in the area of the North Korean Punggye-ri nuclear test site, where the verified nuclear tests from 2006, 2009, and 2013 were conducted as well. The analysis of the recorded seismic signals provides the evidence, that the event was originated by an explosive source. The amplitudes as well as the spectral characteristics of the signals were examined. Furthermore, the similarity of the signals with those from the three former nuclear tests suggests very similar source type. The seismograms at the 8,200 km distant IMS station GERES in Germany, for example, show the same P phase signal for all four explosions, differing in the amplitude only. The comparison of the measured amplitudes results in the increasing magnitude with the chronology of the explosions from 2006 (mb 4.2), 2009 (mb 4.8) until 2013 (mb 5.1), whereas the explosion in 2016 had approximately the same magnitude as that one three years before. Derived from the magnitude, a yield of 14 kt TNT equivalents was estimated for both explosions in 2013 and 2016; in 2006 and 2009 yields were 0.7 kt and 5.4 kt, respectively. However, a large inherent uncertainty for these values has to be taken into account. The estimation of the absolute yield of the explosions depends very much on the local geological situation and the degree of decoupling of the explosive from the surrounding rock. Due to the missing corresponding information, reliable magnitude-yield estimation for the North Korean test site is proved to be difficult. The direct evidence for the nuclear character of the explosion can only be found, if radioactive fission products of the explosion get released into the atmosphere and detected. The corresponding analysis by Atmospheric Transport Modelling is presented on the poster by O. Ross and L. Ceranna assessing the detection chances of IMS radionuclide stations.

Statistical Approach to Detection of Strombolian Activity in Satellite Data

NASA Astrophysics Data System (ADS)

Worden, A. K.; Dehn, J.; Ripepe, M.; Harris, A. J.

2010-12-01

Strombolian activity across the remote volcanoes of the Aleutian Islands and Kamchatka Peninsula cannot be monitored easily or safely by direct methods. Satellite remote sensing offers a useful means to routinely monitor these volcanoes. To model the expected time-dependent thermal signal recorded by the satellite-sensor, we carried out laboratory-based experiments and collected field data for cooling spatter and bomb fields. Preliminary laboratory work focused on finding an acceptable lava analog, as well as scaled pressures and vent sizes. Honey emitted from 0.5-3.8 cm diameter vents by explosions with pressures of around 0.05 MPa seemed to work the best. Scaled explosions were recorded with a FLIR thermal camera and a digital video camera. Explosions at Stromboli Volcano in Italy were also recorded with the same thermal camera over a period of days in May and June, 2010, and were compared to the scaled explosions. In both the modeled and actual explosions, vent diameter directly dictates the type of explosion and deposit distribution ranging from intense jetting from small vents to diffuse spattering from larger vents. The style of emission controls the area of, and distribution of bombs within, the resulting bomb field. This, in turn, influences the cooling rate of the bomb field. The cooling rate of spatter and bomb fields (most likely the source of thermal anomalies in satellite data) for both modeled and actual explosions compared well, and is on the order of seconds to minutes. For a single explosion of average size, the thermal signal is detectable by satellite for a time period in terms of tens of seconds. Thus, in order to see a thermal signature related to a strombolian explosion, a satellite must pass over the volcano (with acceptable geometries) within about a minute of an explosion. A volcano with 70 explosions per day would produce roughly an hour of detectable thermal anomalies. With about a dozen possible NOAA and NASA satellite overpasses daily, dependant on weather and viewing geometry, an anomaly would be seen every couple of days and almost certainly once a week. By calibrating events observed by satellite with events recorded in infrasonic, seismic, and FLIR data a tool can be developed to gauge increasing or decreasing strombolian activity at remote volcanoes.

Evaluation of sulfur dioxide emissions from explosive volcanism: the 1982-1983 eruptions of Galunggung, Java, Indonesia

USGS Publications Warehouse

Bluth, G.J.S.; Casadevall, T.J.; Schnetzler, C.C.; Doiron, S.D.; Walter, Louis S.; Krueger, A.J.; Badruddin, M.

1994-01-01

Galunggung volcano, Java, awoke from a 63-year quiescence in April 1982, and erupted sporadically through January 1983. During its most violent period from April to October, the Cikasasah Volcano Observatory reported 32 large and 56 moderate to small eruptions. From April 5 through September 19 the Total Ozone Mapping Spectrometer (TOMS), carried on NASA's Nimbus-7 satellite, detected and measured 24 different sulfur dioxide clouds; an estimated 1730 kilotons (kt) of SO2 were outgassed by these explosive eruptions. The trajectories, and rapid dispersion rates, of the SO2 clouds were consistent with injection altitudes below the tropopause. An additional 300 kt of SO2 were estimated to have come from 64 smaller explosive eruptions, based on the detection limit of the TOMS instrument. For the first time, an extended period of volcanic activity was monitored by remote sensing techniques which enabled observations of both the entire SO2 clouds produced by large explosive eruptions (using TOMS), and the relatively lower levels of SO2 emissions during non-explosive outgassing (using the Correlation Spectrometer, or COSPEC). Based on COSPEC measurements from August 1982 to January 1983, and on the relationship between explosive and non-explosive degassing, approximately 400 kt of SO2 were emitted during non-explosive activity. The total sulfur dioxide outgassed from Galunggung volcano from April 1982 to January 1983 is calculated to be 2500 kt (?? 30%) from both explosive and non-explosive activity. While Galunggung added large quantities of sulfur dioxide to the atmosphere, its sporadic emissions occurred in relatively small events distributed over several months, and reached relatively low altitudes, and are unlikely to have significantly affected aerosol loading of the stratosphere in 1982 by volcanic activity. ?? 1994.

Femtogram detection of explosive nitroaromatics: fluoranthene-based fluorescent chemosensors.

PubMed

Venkatramaiah, N; Kumar, Shiv; Patil, Satish

2012-11-12

Herein we report a novel fluoranthene-based fluorescent fluorophore 7,10-bis(4-bromophenyl)-8,9-bis[4-(hexyloxy)phenyl]fluoranthene (S(3)) and its remarkable properties in applications of explosive detection. The sensitivity towards the detection of nitroaromatics (NACs) was evaluated through fluorescence quenching in solution, vapor, and contact mode approaches. The contact mode approach using thin-layer silica chromatographic plates exhibited a femtogram (1.15 fg cm(-2)) detection limit for trinitrotoluene (TNT) and picric acid (PA), whereas the solution-phase quenching showed PA detection at the 2-20 ppb level. Fluorescence lifetime measurements revealed that the quenching is static in nature and the quenching process is fully reversible. Binding energies between model binding sites of the S(3) and analyte compounds reveal that analyte molecules enter into the cavity created by substituted phenyl rings of fluoranthene and are stabilized by strong intermolecular interactions with alkyl chains. It is anticipated that the sensor S(3) could be a promising material for the construction of portable optical devices for the detection of onsite explosive nitroaromatics. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Device for Detection of Explosives, Nuclear and Other Hazardous Materials in Luggage and Cargo Containers

NASA Astrophysics Data System (ADS)

Kuznetsov, Andrey; Evsenin, Alexey; Gorshkov, Igor; Osetrov, Oleg; Vakhtin, Dmitry

2009-12-01

Device for detection of explosives, radioactive and heavily shielded nuclear materials in luggage and cargo containers based on Nanosecond Neutron Analysis/Associated Particles Technique (NNA/APT) is under construction. Detection module consists of a small neutron generator with built-in position-sensitive detector of associated alpha-particles, and several scintillator-based gamma-ray detectors. Explosives and other hazardous chemicals are detected by analyzing secondary high-energy gamma-rays from reactions of fast neutrons with materials inside a container. The same gamma-ray detectors are used to detect unshielded radioactive and nuclear materials. An array of several neutron detectors is used to detect fast neutrons from induced fission of nuclear materials. Coincidence and timing analysis allows one to discriminate between fission neutrons and scattered probing neutrons. Mathematical modeling by MCNP5 and MCNP-PoliMi codes was used to estimate the sensitivity of the device and its optimal configuration. Comparison of the features of three gamma detector types—based on BGO, NaI and LaBr3 crystals is presented.

Design and fabrication of optical chemical sensor for detection of nitroaromatic explosives based on fluorescence quenching of phenol red immobilized poly(vinyl alcohol) membrane.

PubMed

Zarei, Ali Reza; Ghazanchayi, Behnam

2016-04-01

The present study developed a new optical chemical sensor for detection of nitroaromatic explosives in liquid phase. The method is based on the fluorescence quenching of phenol red as fluorophore in a poly(vinyl alcohol) (PVA) membrane in the presence of nitroaromatic explosives as quenchers, e.g., 2,4,6-trinitrotoluene (TNT), 2,4-dinitrotoluene (2,4-DNT), 4-nitrotoluene (4-NT), 2,4,6-trinitrobenzene (TNB), and nitrobenzene (NB). For chemical immobilization of phenol red in PVA, phenol red reacted with formaldehyde to produce hydroxymethyl groups and then attached to PVA membrane through the hydroxymethyl groups. The optical sensor showed strong quenching of nitroaromatic explosives. A Stern-Volmer graph for each explosive was constructed and showed that the range of concentration from 5.0 × 10(-6) to 2.5 × 10(-4) mol L(-1) was linear for each explosive and sensitivity varied as TNB >TNT>2,4-DNT>NB>4-NT. The response time of the sensor was within 1 min. The proposed sensor showed good reversibility and reproducibility. Copyright © 2015 Elsevier B.V. All rights reserved.

Laser vaporization of trace explosives for enhanced non-contact detection

NASA Astrophysics Data System (ADS)

Furstenberg, Robert; Papantonakis, Michael; Kendziora, Christopher A.; Bubb, Daniel M.; Corgan, Jeffrey; McGill, R. Andrew

2010-04-01

Trace explosives contamination is found primarily in the form of solid particulates on surfaces, due to the low vapor pressure of most explosives materials. Today, the standard sampling procedure involves physical removal of particulate matter from surfaces of interest. A variety of collection methods have been used including air-jetting or swabbing surfaces of interest. The sampled particles are typically heated to generate vapor for analysis in hand held, bench top, or portal detection systems. These sampling methods are time-consuming (and hence costly), require a skilled technician for optimal performance, and are inherently non-selective, allowing non-explosives particles to be co-sampled and analyzed. This can adversely affect the sensitivity and selectivity of detectors, especially those with a limited dynamic range. We present a new approach to sampling solid particles on a solid surface that is targeted, non-contact, and which selectively enhances trace explosive signatures thus improving the selectivity and sensitivity of existing detectors. Our method involves the illumination of a surface of interest with infrared laser light with a wavelength that matches a distinctive vibrational mode of an explosive. The resonant coupling of laser energy results in rapid heating of explosive particles and rapid release of a vapor plume. Neighboring particles unrelated to explosives are generally not directly heated as their vibrational modes are not resonant with the laser. As a result, the generated vapor plume includes a higher concentration of explosives than if the particles were heated with a non-selective light source (e.g. heat lamp). We present results with both benchtop infrared lasers as well as miniature quantum cascade lasers.

Report of the Defense Science Board Task Force on Critical Homeland Infrastructure Protection

DTIC Science & Technology

2007-01-01

nuclear, radiation and explosive hazards; • Monitoring “people of interest” while protecting civil liberties; • Detection of hostile intent; • Detect...Guardian DARPA Overview Mr. Roger Gibbs DARPA LLNL Technologies in Support of Infrastructure Protection Mr. Don Prosnitz LLNL Sandia National...Mechanical Engineers AT/FP Antiterrorism/Force Protection CBRNE Chemical Biological Radiological Nuclear Explosive CERT Commuter Emergency Response Team

Threshold Monitoring Maps for Under-Water Explosions

NASA Astrophysics Data System (ADS)

Arora, N. S.

2014-12-01

Hydro-acoustic energy in the 1-100 Hz range from under-water explosions can easily spread for thousands of miles due to the unique properties of the deep sound channel. This channel, aka SOFAR channel, exists almost everywhere in the earth's oceans where the water has at least 1500m depth. Once the energy is trapped in this channel it spreads out cylindrically, and hence experiences very little loss, as long as there is an unblocked path from source to receiver. Other losses such as absorption due to chemicals in the ocean (mainly boric acid and magnesium sulphate) are also quite minimal at these low frequencies. It is not surprising then that the International Monitoring System (IMS) maintains a global network of hydrophone stations listening on this particular frequency range. The overall objective of our work is to build a probabilistic model to detect and locate under-water explosions using the IMS network. A number of critical pieces for this model, such as travel time predictions, are already well known. We are extending the existing knowledge-base by building the remaining pieces, most crucially the models for transmission losses and detection probabilities. With a complete model for detecting under-water explosions we are able to combine it with our existing model for seismic events, NET-VISA. In the conference we will present threshold monitoring maps for explosions in the earth's oceans. Our premise is that explosive sources release an unknown fraction of their total energy into the SOFAR channel, and this trapped energy determines their detection probability at each of the IMS hydrophone stations. Our threshold monitoring maps compute the minimum amount of energy at each location that must be released into the deep sound channel such that there is a ninety percent probability that at least two of the IMS stations detect the event. We will also present results of our effort to detect and locate hydro-acoustic events. In particular, we will show results from a recent under-water volcanic eruption at the Ahyl Seamount (April-May 2014), and compare our work with the current processing, both automated and human, at the IDC.

Detection of explosives by differential hyperspectral imaging

NASA Astrophysics Data System (ADS)

Dubroca, Thierry; Brown, Gregory; Hummel, Rolf E.

2014-02-01

Our team has pioneered an explosives detection technique based on hyperspectral imaging of surfaces. Briefly, differential reflectometry (DR) shines ultraviolet (UV) and blue light on two close-by areas on a surface (for example, a piece of luggage on a moving conveyer belt). Upon reflection, the light is collected with a spectrometer combined with a charge coupled device (CCD) camera. A computer processes the data and produces in turn differential reflection spectra taken from these two adjacent areas on the surface. This differential technique is highly sensitive and provides spectroscopic data of materials, particularly of explosives. As an example, 2,4,6-trinitrotoluene displays strong and distinct features in differential reflectograms near 420 and 250 nm, that is, in the near-UV region. Similar, but distinctly different features are observed for other explosives. Finally, a custom algorithm classifies the collected spectral data and outputs an acoustic signal if a threat is detected. This paper presents the complete DR hyperspectral imager which we have designed and built from the hardware to the software, complete with an analysis of the device specifications.

Explosives signatures and analysis

NASA Astrophysics Data System (ADS)

Fountain, Augustus Way, III; Oyler, Jonathan M.; Ostazeski, Stanley A.

2008-04-01

The challenge of sampling explosive materials for various high threat military and civilian operational scenarios requires the community to identify and exploit other chemical compounds within the mixtures that may be available to support stand-off detection techniques. While limited surface and vapor phase characterization of IEDs exist, they are insufficient to guide the future development and evaluation of field deployable explosives detection (proximity and standoff) capabilities. ECBC has conducted a limited investigation of three artillery ammunition types to determine what chemical vapors, if any, are available for sensing; the relative composition of the vapors which includes the more volatile compounds in munitions, i.e., plastersizers and binders; and the sensitivity needed detect these vapors at stand-off. Also in partnership with MIT-Lincoln Laboratory, we performed a background measurement campaign at the National Training Center to determine the baseline ambient amounts and variability of nitrates and nitro-ester compounds as vapors, particulates, and on surfaces; as well as other chemical compounds related to non-energetic explosive additives. Environmental persistence studies in contexts relevant to counter-IED sensing operations, such as surface residues, are still necessary.

Rapid Quantitative Analysis of Multiple Explosive Compound Classes on a Single Instrument via Flow-Injection Analysis Tandem Mass Spectrometry.

PubMed

Ostrinskaya, Alla; Kunz, Roderick R; Clark, Michelle; Kingsborough, Richard P; Ong, Ta-Hsuan; Deneault, Sandra

2018-05-24

A flow-injection analysis tandem mass spectrometry (FIA MSMS) method was developed for rapid quantitative analysis of 10 different inorganic and organic explosives. Performance is optimized by tailoring the ionization method (APCI/ESI), de-clustering potentials, and collision energies for each specific analyte. In doing so, a single instrument can be used to detect urea nitrate, potassium chlorate, 2,4,6-trinitrotoluene, 2,4,6-trinitrophenylmethylnitramine, triacetone triperoxide, hexamethylene triperoxide diamine, pentaerythritol tetranitrate, 1,3,5-trinitroperhydro-1,3,5-triazine, nitroglycerin, and octohy-dro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine with sensitivities all in the picogram per milliliter range. In conclusion, FIA APCI/ESI MSMS is a fast (<1 min/sample), sensitive (~pg/mL LOQ), and precise (intraday RSD < 10%) method for trace explosive detection that can play an important role in criminal and attributional forensics, counterterrorism, and environmental protection areas, and has the potential to augment or replace several of the existing explosive detection methods. © 2018 American Academy of Forensic Sciences.

Advancing Explosion Source Theory through Experimentation: Results from Seismic Experiments Since the Moratorium on Nuclear Testing

NASA Astrophysics Data System (ADS)

Bonner, J. L.; Stump, B. W.

2011-12-01

On 23 September 1992, the United States conducted the nuclear explosion DIVIDER at the Nevada Test Site (NTS). It would become the last US nuclear test when a moratorium ended testing the following month. Many of the theoretical explosion seismic models used today were developed from observations of hundreds of nuclear tests at NTS and around the world. Since the moratorium, researchers have turned to chemical explosions as a possible surrogate for continued nuclear explosion research. This talk reviews experiments since the moratorium that have used chemical explosions to advance explosion source models. The 1993 Non-Proliferation Experiment examined single-point, fully contained chemical-nuclear equivalence by detonating over a kiloton of chemical explosive at NTS in close proximity to previous nuclear explosion tests. When compared with data from these nearby nuclear explosions, the regional and near-source seismic data were found to be essentially identical after accounting for different yield scaling factors for chemical and nuclear explosions. The relationship between contained chemical explosions and large production mining shots was studied at the Black Thunder coal mine in Wyoming in 1995. The research led to an improved source model for delay-fired mining explosions and a better understanding of mining explosion detection by the International Monitoring System (IMS). The effect of depth was examined in a 1997 Kazakhstan Depth of Burial experiment. Researchers used local and regional seismic observations to conclude that the dominant mechanism for enhanced regional shear waves was local Rg scattering. Travel-time calibration for the IMS was the focus of the 1999 Dead Sea Experiment where a 10-ton shot was recorded as far away as 5000 km. The Arizona Source Phenomenology Experiments provided a comparison of fully- and partially-contained chemical shots with mining explosions, thus quantifying the reduction in seismic amplitudes associated with partial confinement. The Frozen Rock Experiment in 2006 found only minor differences in seismic coupling for explosions in frozen and unfrozen rock. The seismo-acoustic source function was the focus of the above- and below-ground Humble Redwood explosions (2007, 2009 ) in New Mexico and detonations of rocket motor explosions in Utah. Acoustic travel time calibration for the IMS was accomplished with the 2009 and 2011 100-ton surface explosions in southern Israel. The New England Damage Experiment in 2009 correlated increased shear wave generation with increased rock damage from explosions. Damage from explosions continues to be an important research topic at Nevada's National Center for Nuclear Security with the ongoing Source Physics Experiment. A number of exciting experiments are already planned for the future and thus continue the effort to improve global detection, location, and identification of nuclear explosions.

Raman chemical imaging of explosive-contaminated fingerprints.

PubMed

Emmons, E D; Tripathi, A; Guicheteau, J A; Christesen, S D; Fountain, A W

2009-11-01

Raman chemical imaging (RCI) has been used to detect and identify explosives in contaminated fingerprints. Bright-field imaging is used to identify regions of interest within a fingerprint, which can then be examined to determine their chemical composition using RCI and fluorescence imaging. Results are presented where explosives in contaminated fingerprints are identified and their spatial distributions are obtained. Identification of explosives is obtained using Pearson's cosine cross-correlation technique using the characteristic region (500-1850 cm(-1)) of the spectrum. This study shows the ability to identify explosives nondestructively so that the fingerprint remains intact for further biometric analysis. Prospects for forensic examination of contaminated fingerprints are discussed.

Explosive Detection in Aviation Applications Using CT

DOE Office of Scientific and Technical Information (OSTI.GOV)

Martz, H E; Crawford, C R

2011-02-15

CT scanners are deployed world-wide to detect explosives in checked and carry-on baggage. Though very similar to single- and dual-energy multi-slice CT scanners used today in medical imaging, some recently developed explosives detection scanners employ multiple sources and detector arrays to eliminate mechanical rotation of a gantry, photon counting detectors for spectral imaging, and limited number of views to reduce cost. For each bag scanned, the resulting reconstructed images are first processed by automated threat recognition algorithms to screen for explosives and other threats. Human operators review the images only when these automated algorithms report the presence of possible threats.more » The US Department of Homeland Security (DHS) has requirements for future scanners that include dealing with a larger number of threats, higher probability of detection, lower false alarm rates and lower operating costs. One tactic that DHS is pursuing to achieve these requirements is to augment the capabilities of the established security vendors with third-party algorithm developers. A third-party in this context refers to academics and companies other than the established vendors. DHS is particularly interested in exploring the model that has been used very successfully by the medical imaging industry, in which university researchers develop algorithms that are eventually deployed in commercial medical imaging equipment. The purpose of this paper is to discuss opportunities for third-parties to develop advanced reconstruction and threat detection algorithms.« less

Remote laser drilling and sampling system for the detection of concealed explosives

NASA Astrophysics Data System (ADS)

Wild, D.; Pschyklenk, L.; Theiß, C.; Holl, G.

2017-05-01

The detection of hazardous materials like explosives is a central issue in national security in the field of counterterrorism. One major task includes the development of new methods and sensor systems for the detection. Many existing remote or standoff methods like infrared or raman spectroscopy find their limits, if the hazardous material is concealed in an object. Imaging technologies using x-ray or terahertz radiation usually yield no information about the chemical content itself. However, the exact knowledge of the real threat potential of a suspicious object is crucial for disarming the device. A new approach deals with a laser drilling and sampling system for the use as verification detector for suspicious objects. Central part of the system is a miniaturised, diode pumped Nd:YAG laser oscillator-amplifier. The system allows drilling into most materials like metals, synthetics or textiles with bore hole diameters in the micron scale. During the drilling process, the hazardous material can be sampled for further investigation with suitable detection methods. In the reported work, laser induced breakdown spectroscopy (LIBS) is used to monitor the drilling process and to classify the drilled material. Also experiments were carried out to show the system's ability to not ignite even sensitive explosives like triacetone triperoxide (TATP). The detection of concealed hazardous material is shown for different explosives using liquid chromatography and ion mobility spectrometry.

Standoff detection of explosives: critical comparison for ensuing options on Raman spectroscopy-LIBS sensor fusion.

PubMed

Moros, J; Lorenzo, J A; Laserna, J J

2011-07-01

In general, any standoff sensor for the effective detection of explosives must meet two basic requirements: first, a capacity to detect the response generated from only a small amount of material located at a distance of several meters (high sensitivity) and second, the ability to provide easily distinguishable responses for different materials (high specificity). Raman spectroscopy and laser-induced breakdown spectroscopy (LIBS) are two analytical techniques which share similar instrumentation and, at the same time, generate complementary data. These factors have been taken into account recently for the design of sensors used in the detection of explosives. Similarly, research on the proper integration of both techniques has been around for a while. A priori, the different operational conditions required by the two techniques oblige the acquisition of the response for each sensor through sequential analysis, previously necessary to define the proper hierarchy of actuation. However, such an approach does not guarantee that Raman and LIBS responses obtained may relate to each other. Nonetheless, the possible advantages arising from the integration of the molecular and elemental spectroscopic information come with an obvious underlying requirement, simultaneous data acquisition. In the present paper, strong and weak points of Raman spectroscopy and LIBS for solving explosives detection problems, in terms of selectivity, sensitivity, and throughput, are critically examined, discussed, and compared for assessing the ensuing options on the fusion of the responses of both sensing technologies.

Principles and status of neutron-based inspection technologies

NASA Astrophysics Data System (ADS)

Gozani, Tsahi

2011-06-01

Nuclear based explosive inspection techniques can detect a wide range of substances of importance for a wide range of objectives. For national and international security it is mainly the detection of nuclear materials, explosives and narcotic threats. For Customs Services it is also cargo characterization for shipment control and customs duties. For the military and other law enforcement agencies it could be the detection and/or validation of the presence of explosive mines, improvised explosive devices (IED) and unexploded ordnances (UXO). The inspection is generally based on the nuclear interactions of the neutrons (or high energy photons) with the various nuclides present and the detection of resultant characteristic emissions. These can be discrete gamma lines resulting from the thermal neutron capture process (n,γ) or inelastic neutron scattering (n,n'γ) occurring with fast neutrons. The two types of reactions are generally complementary. The capture process provides energetic and highly penetrating gamma rays in most inorganic substances and in hydrogen, while fast neutron inelastic scattering provides relatively strong gamma-ray signatures in light elements such as carbon and oxygen. In some specific important cases unique signatures are provided by the neutron capture process in light elements such as nitrogen, where unusually high-energy gamma ray is produced. This forms the basis for key explosive detection techniques. In some cases the elastically scattered source (of mono-energetic) neutrons may provide information on the atomic weight of the scattering elements. The detection of nuclear materials, both fissionable (e.g., 238U) and fissile (e.g., 235U), are generally based on the fissions induced by the probing neutrons (or photons) and detecting one or more of the unique signatures of the fission process. These include prompt and delayed neutrons and gamma rays. These signatures are not discrete in energy (typically they are continua) but temporally and energetically significantly different from the background, thus making them readily distinguishable. The penetrability of neutrons as probes and signatures as well as the gamma ray signatures make neutron interrogation applicable to the inspection of large conveyances such as cars, trucks, marine containers and also smaller objects like explosive mines concealed in the ground. The application of nuclear interrogation techniques greatly depends on operational requirements. For example explosive mines and IED detection clearly require one-sided inspection, which excludes transmission based inspection (e.g., transmission radiography) and greatly limits others. The technologies developed over the last decades are now being implemented with good results. Further advances have been made over the last several years that increase the sensitivity, applicability and robustness of these systems. The principle, applications and status of neutron-based inspection techniques will be reviewed.

[The error analysis and experimental verification of laser radar spectrum detection and terahertz time domain spectroscopy].

PubMed

Liu, Wen-Tao; Li, Jing-Wen; Sun, Zhi-Hui

2010-03-01

Terahertz waves (THz, T-ray) lie between far-infrared and microwave in electromagnetic spectrum with frequency from 0.1 to 10 THz. Many chemical agent explosives show characteristic spectral features in the terahertz. Compared with conventional methods of detecting a variety of threats, such as weapons and chemical agent, THz radiation is low frequency and non-ionizing, and does not give rise to safety concerns. The present paper summarizes the latest progress in the application of terahertz time domain spectroscopy (THz-TDS) to chemical agent explosives. A kind of device on laser radar detecting and real time spectrum measuring was designed which measures the laser spectrum on the bases of Fourier optics and optical signal processing. Wedge interferometer was used as the beam splitter to wipe off the background light and detect the laser and measure the spectrum. The result indicates that 10 ns laser radar pulse can be detected and many factors affecting experiments are also introduced. The combination of laser radar spectrum detecting, THz-TDS, modern pattern recognition and signal processing technology is the developing trend of remote detection for chemical agent explosives.

Liquids and homemade explosive detection

NASA Astrophysics Data System (ADS)

Ellenbogen, Michael; Bijjani, Richard

2009-05-01

Excerpt from the US Transportation Security Agency website: "The ban on liquids, aerosols and gels was implemented on August 10 after a terrorist plot was foiled. Since then, experts from around the government, including the FBI and our national labs have analyzed the information we now have and have conducted extensive explosives testing to get a better understanding of this specific threat." In order to lift the ban and ease the burden on the flying public, Reveal began an extensive effort in close collaboration with the US and several other governments to help identify these threats. This effort resulted in the successful development and testing of an automated explosive detection system capable of resolving these threats with a high probability of detection and a low false alarm rate. We will present here some of the methodology and approach we took to address this problem.

On-site comprehensive analysis of explosives using HPLC-UV-PAED

NASA Astrophysics Data System (ADS)

Marple, Ronita L.; LaCourse, William R.

2004-03-01

High-performance liquid chromatography with ultra violet and photo-assisted electrochemical detection (HPLC-UV-PAED) has been developed for the sensitive and selective detection of explosives in ground water and soil extracts. Fractionation and preconcentration of explosives is accomplished with on-line solid phase extraction (SPE), which minimizes sample pretreatment and enables faster and more accurate on-site assessment of a contaminated site. Detection limits are equivalent or superior (i.e., <1 part-per-trillion for HMX) to those achieved using the Environmental Protection Agency (EPA) Method 8330. This approach is more broadly applicable, as it is capable of determining a wider range of organic nitro compounds. Soil samples are extracted using pressurized fluid extraction (PFE), and this technique is automatable, field-compatible, and environmentally friendly, adding to the overall efficiency of the methodology.

Detecting underwater improvised explosive threats (DUIET)

NASA Astrophysics Data System (ADS)

Feeley, Terry

2010-04-01

Improvised Explosive Devices (IEDs) have presented a major threat in the wars in Afghanistan and Iraq. These devices are powerful homemade land mines that can be small and easily hidden near roadsides. They are then remotely detonated when Coalition Forces pass by either singly or in convoys. Their rapid detection, classification and destruction is key to the safety of troops in the area. These land based bombs will have an analogue in the underwater theater especially in ports, lakes, rivers and streams. These devices may be used against Americans on American soil as an element of the global war on terrorism (GWOT) Rapid detection and classification of underwater improvised explosive devices (UIED) is critical to protecting innocent lives and maintaining the day to day flow of commerce. This paper will discuss a strategy and tool set to deal with this potential threat.

Improved thermal neutron activation sensor for detection of bulk explosives

NASA Astrophysics Data System (ADS)

McFee, John E.; Faust, Anthony A.; Andrews, H. Robert; Clifford, Edward T. H.; Mosquera, Cristian M.

2012-06-01

Defence R&D Canada - Suffield and Bubble Technology Industries have been developing thermal neutron activation (TNA) sensors for detection of buried bulk explosives since 1994. First generation sensors, employing an isotopic source and NaI(Tl) gamma ray detectors, were deployed by Canadian Forces in 2002 as confirmation sensors on the ILDS teleoperated, vehicle-mounted, multi-sensor anti-tank landmine detection systems. The first generation TNA could detect anti-tank mines buried 10 cm or less in no more than a minute, but deeper mines and those significantly displaced horizontally required considerably longer times. Mines as deep as 30 cm could be detected with long counting times (1000 s). The second generation TNA detector is being developed with a number of improvements aimed at increasing sensitivity and facilitating ease of operation. Among these are an electronic neutron generator to increase sensitivity for deeper and horizontally displaced explosives; LaBr3(Ce) scintillators, to improve time response and energy resolution; improved thermal and electronic stability; improved sensor head geometry to minimize spatial response nonuniformity; and more robust data processing. This improved sensitivity can translate to either decreased counting times, decreased minimum detectable explosive quantities, increased maximum sensor-to-target displacement, or a trade off among all three. Experiments to characterize the performance of the latest generation TNA in detecting buried landmines and IEDs hidden in culverts were conducted during 2011. This paper describes the second generation system. The experimental setup and methodology are detailed and preliminary comparisons between the performance of first and second generation systems are presented.

Controlled biological and biomimetic systems for landmine detection.

PubMed

Habib, Maki K

2007-08-30

Humanitarian demining requires to accurately detect, locate and deactivate every single landmine and other buried mine-like objects as safely and as quickly as possible, and in the most non-invasive manner. The quality of landmine detection affects directly the efficiency and safety of this process. Most of the available methods to detect explosives and landmines are limited by their sensitivity and/or operational complexities. All landmines leak with time small amounts of their explosives that can be found on surrounding ground and plant life. Hence, explosive signatures represent the robust primary indicator of landmines. Accordingly, developing innovative technologies and efficient techniques to identify in real-time explosives residue in mined areas represents an attractive and promising approach. Biological and biologically inspired detection technology has the potential to compete with or be used in conjunction with other artificial technology to complement performance strengths. Biological systems are sensitive to many different scents concurrently, a property that has proven difficult to replicate artificially. Understanding biological systems presents unique opportunities for developing new capabilities through direct use of trained bio-systems, integration of living and non-living components, or inspiring new design by mimicking biological capabilities. It is expected that controlled bio-systems, biotechnology and microbial techniques will contribute to the advancement of mine detection and other application domains. This paper provides directions, evaluation and analysis on the progress of controlled biological and biomimetic systems for landmine detection. It introduces and discusses different approaches developed, underlining their relative advantages and limitations, and highlighting trends, safety and ecology concern, and possible future directions.

Gulf of Mexico

Atmospheric Science Data Center

2014-05-15

article title:  Gulf of Mexico Oil Slick       View ... 22, 2010, the Deepwater Horizon oil platform in the Gulf of Mexico sank in nearly 1,500 meters (4,900 feet) of water after an explosion ... appear lighter blue on the darker blue waters of the Gulf of Mexico. Some clouds are visible in the extreme lower left corner of the image. ...

Video-Based Learning Platforms: A Key to Educational Transformation in Emerging Markets

ERIC Educational Resources Information Center

Aji, Sandeep

2016-01-01

One of the most explosive areas of growth in the field of higher education is currently in emerging international markets. In developing nations, lack of access to high-quality teachers and educational materials is often the key obstacle preventing students from gaining the skills and knowledge they need to pursue new opportunities and advance in…

Explosive detection using high-volume vapor sampling and analysis by trained canines and ultra-trace detection equipment

NASA Astrophysics Data System (ADS)

Fisher, Mark; Sikes, John; Prather, Mark

2004-09-01

The dog's nose is an effective, highly-mobile sampling system, while the canine olfactory organs are an extremely sensitive detector. Having been trained to detect a wide variety of substances with exceptional results, canines are widely regarded as the 'gold standard' in chemical vapor detection. Historically, attempts to mimic the ability of dogs to detect vapors of explosives using electronic 'dogs noses' has proven difficult. However, recent advances in technology have resulted in development of detection (i.e., sampling and sensor) systems with performance that is rapidly approaching that of trained canines. The Nomadics Fido was the first sensor to demonstrate under field conditions the detection of landmines with performance approaching that of canines. More recently, comparative testing of Fido against canines has revealed that electronic vapor detection, when coupled with effective sampling methods, can produce results comparable to that of highly-trained canines. The results of these comparative tests will be presented, as will recent test results in which explosives hidden in cargo were detected using Fido with a high-volume sampling technique. Finally, the use of canines along with electronic sensors will be discussed as a means of improving the performance and expanding the capabilities of both methods.

The use of neutrons for the detection of explosives in Civil Security Applications

NASA Astrophysics Data System (ADS)

Pesente, S.; Fabris, D.; Lunardon, M.; Moretto, S.; Nebbia, G.; Viesti, G.

2007-02-01

The search for hidden explosives has been simulated in laboratory conditions by using our Tagged Neutron Inspection System (TNIS). Applications of the TNIS concept to Civil Security problems are discussed in the light of our projects for cargo container inspections. Moreover, neutron attenuation and scattering can be used to search in real time for large quantity of explosive hidden in vehicles.

Development of an Electron-capture Technique Specific for Explosives Detection

DOT National Transportation Integrated Search

1974-07-01

This document contains information on the design, fabrication, and testing of a prototype detector specific for explosives which employs electron-capture sensors. The technique used exploits the observation that the electronegative vapors from explos...

Towards an Electronic Dog Nose: Surface Plasmon Resonance Immunosensor for Security and Safety

PubMed Central

Onodera, Takeshi; Toko, Kiyoshi

2014-01-01

This review describes an “electronic dog nose” based on a surface plasmon resonance (SPR) sensor and an antigen–antibody interaction for security and safety. We have concentrated on developing appropriate sensor surfaces for the SPR sensor for practical use. The review covers different surface fabrications, which all include variations of a self-assembled monolayer containing oligo(ethylene glycol), dendrimer, and hydrophilic polymer. We have carried out detection of explosives using the sensor surfaces. For the SPR sensor to detect explosives, the vapor or particles of the target substances have to be dissolved in a liquid. Therefore, we also review the development of sampling processes for explosives, and a protocol for the measurement of explosives on the SPR sensor in the field. Additionally, sensing elements, which have the potential to be applied for the electronic dog nose, are described. PMID:25198004

Monitoring Research in the Context of CTBT Negotiations and Networks,

DTIC Science & Technology

1995-08-14

1995) estimates, using infrasound and satellite data, that these sources generate explosion-like signals worldwide at a rate of approximately 1/yr at...coupling and the waveform appearance of atmospheric explosions. In infrasound there is the development of new array designs and of new automatic detection ...sensors. The principal daily use of the hydroacoustic network is for purposes of simple discrimination of those oceanic earthquakes detected by the seismic

Bomb Detection System Study

DTIC Science & Technology

1965-01-01

cause the reduction in vapor pressure. To determine whether an explosive can be detected thi ugh its * vapor, it is necessary to know the vapor pressures...Smokeless powders are explosives normally used in shotgun powders and can vary widely in composition. Nitrocellulose is the major :oomponent. Dinitrotoluene...will not be inclined to undertake the risky process except under very unusual circum- stances. Black powder is an obvious choice and has been so in

Gas chromatographic detection of some nitro explosive compounds in soil samples after solid-phase microextraction with carbon ceramic copper nanoparticle fibers.

PubMed

Farhadi, Khalil; Bochani, Shayesteh; Hatami, Mehdi; Molaei, Rahim; Pirkharrati, Hossein

2014-07-01

In this research, a new solid-phase microextraction fiber based on carbon ceramic composites with copper nanoparticles followed by gas chromatography with flame ionization detection was applied for the extraction and determination of some nitro explosive compounds in soil samples. The proposed method provides an overview of trends related to synthesis of solid-phase microextraction sorbents and their applications in preconcentration and determination of nitro explosives. The sorbents were prepared by mixing of copper nanoparticles with a ceramic composite produced by mixture of methyltrimethoxysilane, graphite, methanol, and hydrochloric acid. The prepared sorbents were coated on copper wires by dip-coating method. The prepared nanocomposites were evaluated statistically and provided better limits of detection than the pure carbon ceramic. The limit of detection of the proposed method was 0.6 μg/g with a linear response over the concentration range of 2-160 μg/g and square of correlation coefficient >0.992. The new proposed fiber has been demonstrated to be a suitable, inexpensive, and sensitive candidate for extraction of nitro explosive compounds in contaminated soil samples. The constructed fiber can be used more than 100 times without the need for surface generation. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Detecting hidden volcanic explosions from Mt. Cleveland Volcano, Alaska with infrasound and ground-couples airwaves

USGS Publications Warehouse

De Angelis, Slivio; Fee, David; Haney, Matthew; Schneider, David

2012-01-01

In Alaska, where many active volcanoes exist without ground-based instrumentation, the use of techniques suitable for distant monitoring is pivotal. In this study we report regional-scale seismic and infrasound observations of volcanic activity at Mt. Cleveland between December 2011 and August 2012. During this period, twenty explosions were detected by infrasound sensors as far away as 1827 km from the active vent, and ground-coupled acoustic waves were recorded at seismic stations across the Aleutian Arc. Several events resulting from the explosive disruption of small lava domes within the summit crater were confirmed by analysis of satellite remote sensing data. However, many explosions eluded initial, automated, analyses of satellite data due to poor weather conditions. Infrasound and seismic monitoring provided effective means for detecting these hidden events. We present results from the implementation of automatic infrasound and seismo-acoustic eruption detection algorithms, and review the challenges of real-time volcano monitoring operations in remote regions. We also model acoustic propagation in the Northern Pacific, showing how tropospheric ducting effects allow infrasound to travel long distances across the Aleutian Arc. The successful results of our investigation provide motivation for expanded efforts in infrasound monitoring across the Aleutians and contributes to our knowledge of the number and style of vulcanian eruptions at Mt. Cleveland.

International Symposium on Analysis and Detection of Explosives (4th) Held in Jerusalem, Israel on September 7 - 10, 1992. Programs and Abstracts

DTIC Science & Technology

1992-09-01

chromatography. * DI EXPLOSIVE ANALYSIS USING CAPILLARY ELECTROPHORESIS Bruce R . McCord., Forensic Science Research Unit, FBI Academy, Quantico, VA...gel and emulsion explosives E. Bender, R . Strobel, and C.R. Midkiff. Ir, Bureau of ATF, Rockville, MD, USA 11.05 D3 The analysis of the explosives of...organic substrates . . - r __ A.D. Wright, K.R. Jennings and R . Peters, University of Warwick, Coventry, U.K. 16:40 F2 GC/MS analysis of PETN and NG

Trace vapor detection of hydrogen peroxide: An effective approach to identification of improvised explosive devices

NASA Astrophysics Data System (ADS)

Xu, Miao

Vapor detection has been proven as one of the practical, noninvasive methods suitable for explosives detection among current explosive detection technologies. Optical methods (especially colorimetric and fluorescence spectral methods) are low in cost, provide simple instrumentation alignment, while still maintaining high sensitivity and selectivity, these factors combined facilitate broad field applications. Trace vapor detection of hydrogen peroxide (H2O2) represents an effective approach to noninvasive detection of peroxide-based explosives, though development of such a sensor system with high reliability and sufficient sensitivity (reactivity) still remains challenging. Three vapor sensor systems for H2O2 were proposed and developed in this study, which exploited specific chemical reaction towards H2O2 to ensure the selectivity, and materials surface engineering to afford efficient air sampling. The combination of these features enables expedient, cost effective, reliable detection of peroxide explosives. First, an expedient colorimetric sensor for H2O2 vapor was developed, which utilized the specific interaction between Ti(oxo) and H2O2 to offer a yellow color development. The Ti(oxo) salt can be blended into a cellulose microfibril network to produce tunable interface that can react with H2O2. The vapor detection limit can reach 400 ppb. To further improve the detection sensitivity, a naphthalimide based fluorescence turn-on sensor was designed and developed. The sensor mechanism was based on H2O2-mediated oxidation of a boronate fluorophore, which is nonfluorescent in ICT band, but becomes strongly fluorescent upon conversion into the phenol state. The detection limit of this sensory material was improved to be below 10 ppb. However, some technical factors such as sensor concentration, local environment, and excitation intensity were found difficult to control to make the sensor system sufficiently reproducible. To solve the problem, we developed a ratiometric fluorescence sensor, which allows for dual-band emission monitoring and thus enhances the detection reliability. Moreover, the significant spectral overlap between the fluorescence of the pristine sensor and the absorption of the reacted state enables effective Foster Resonance Energy Transfer (FRET). This FRET process can significantly enhance the fluorescence sensing efficiency in comparison to the normal single-band sensor system, for which the sensing efficiency is solely determined by the stoichiometric conversion of sensor molecules.

Localisation of threat substances in urban society - LOTUS: a viable tool for finding illegal bomb factories in cities

NASA Astrophysics Data System (ADS)

Önnerud, Hans; Wallin, Sara; Östmark, Henric; Menning, Dennis; Ek, Stefan; Ellis, Hanna; Kölhed, Malin

2011-06-01

Results of dispersion experiments and dispersion modelling of explosives, drugs, and their precursors will be presented. The dispersion of chemicals evolving during preparation of home made explosives and a drug produced in an improvised manner in an ordinary kitchen has been measured. Experiments with concentration of hydrogen peroxide have been performed during spring and summer of 2009 and 2010 and further experiments with concentration of hydrogen peroxide, synthesis and drying of TATP and Methamphetamine are planned for the spring and summer of 2011. Results from the experiments are compared to dispersion modelling to achieve a better understanding of the dispersion processes and the resulting substances and amounts available for detection outside the kitchen at distances of 10-30 m and longer. Typical concentration levels have been determined as a function of environmental conditions. The experiments and modelling are made as a part of the LOTUS project aimed at detecting and locating the illicit production of explosives and drugs in an urban environment. It can be concluded that the proposed LOTUS system concept, using mobile automatic sensors, data transfer, location via GSM/GPS for on-line detection of illicit production of explosive or precursors to explosives and drugs is a viable approach and is in accordance with historical and today's illicit bomb manufacturing. The overall objective and approach of the LOTUS project will also be presented together with two more projects called PREVAIL and EMPHASIS both aiming at hindering or finding illicit production of home made explosives.

Risk assessment for stonecutting enterprises Accidental risks in the course of petroleum production and stone extraction

NASA Astrophysics Data System (ADS)

Aleksandrova, A. J.; Timofeeva, S. S.

2018-01-01

The paper is devoted to the assessment of accidental risks occurring at the works engaged in stone extracting and petroleum production. Two basic kinds of accidents common for stone extracting and petroleum production have been chosen to be discussed in the part under consideration. The most dangerous accidental situation characteristic for a stone milling line is an unsanctioned explosion, UE, of blasting agents used for the development of stone deposits. The analysis of a risk occurrence in certain accidental situations is to be carried out. With reference to petroleum extraction, a combustibles and lubricants (C & L) explosion is the most dangerous of characteristic accidental situations. To reveal the most probable causes of accidental situations to be realized, a graph of cause and effect relations has been constructed for each of the accidental situations most probable causes to real situation of an accident. Disasters of a natural origin are the most probable causes of unsanctioned explosions at the deposits of stone raw materials. Technology related natural disasters are the most probable causes of unsanctioned explosions to be realized at multiple well platforms engaged in petroleum production.

Detection of explosive remnants of war by neutron thermalisation.

PubMed

Brooks, F D; Drosg, M; Smit, F D; Wikner, C

2012-01-01

The HYDAD-D landmine detector (Brooks and Drosg, 2005) has been modified and field-tested for 17 months in a variety of soil conditions. Test objects containing about the same mass of hydrogen (20g) as small explosive remnants of war, such as antipersonnel landmines, were detected with efficiency 100% when buried at cover depths up to 10cm. The false alarm rate under the same conditions was 9%. Plots of detection efficiency versus false alarm rate are presented. Copyright © 2011 Elsevier Ltd. All rights reserved.

Highly sensitive detection of explosive triacetone triperoxide by an In2O3 sensor.

PubMed

Zhang, Wen-Hui; Zhang, Wei-De; Chen, Lu-Ya

2010-08-06

Triacetone triperoxide (TATP) is one of the most sensitive known explosives and can be easily synthesized using the commonly available chemicals acetone and hydrogen peroxide, but is difficult to be detected. In this study, In(2)O(3) nanoparticles were synthesized by a glucose-assisted solvothermal method at 120 degrees C for 18 h. The gas sensor based on In(2)O(3) nanoparticles exhibits a high response, fast response and recovery, a wide detecting range of 0.50-500 mg, good stability and excellent stability to TATP.

Imaging standoff trace detection of explosives using IR-laser based backscattering

NASA Astrophysics Data System (ADS)

Fuchs, F.; Hugger, S.; Jarvis, J.; Yang, Q. K.; Ostendorf, R.; Schilling, Ch.; Bronner, W.; Driad, R.; Aidam, R.; Wagner, J.

2016-05-01

We perform active hyperspectral imaging using tunable mid-infrared (MIR) quantum cascade lasers for contactless identification of solid and liquid contaminations on surfaces. By collecting the backscattered laser radiation with a camera, a hyperspectral data cube, containing the spatially resolved spectral information of the scene is obtained. Data is analyzed using appropriate algorithms to find the target substances even on substrates with a priori unknown spectra. Eye-save standoff detection of residues of explosives and precursors over extended distances is demonstrated and the main purpose of our system. Using a MIR EC-QCL with a tuning range from 7.5 μm to 10 μm, detection of a large variety of explosives, e.g. TNT, PETN and RDX and precursor materials such as Ammonium Nitrate could be demonstrated. In a real world scenario stand-off detection over distances of up to 20 m could be successfully performed. This includes measurements in a post blast scenario demonstrating the potential of the technique for forensic investigations.

Advances in quantum cascade lasers for security and crime-fighting

NASA Astrophysics Data System (ADS)

Normand, Erwan L.; Stokes, Robert J.; Hay, Kenneth; Foulger, Brian; Lewis, Colin

2010-10-01

Advances in the application of Quantum Cascade Lasers (QCL) to trace gas detection will be presented. The solution is real time (~1 μsec per scan), is insensitive to turbulence and vibration, and performs multiple measurements in one sweep. The QCL provides a large dynamic range, which is a linear response from ppt to % level. The concentration can be derived with excellent immunity from cross interference. Point sensing sensors developed by Cascade for home made and commercial explosives operate by monitoring key constituents in real time and matching this to a spatial event (i.e. sniffer device placed close to an object or person walking through portal (overt or covert). Programmable signature detection capability allows for detection of multiple chemical compounds along the most likely array of explosive chemical formulation. The advantages of configuration as "point sensing" or "stand off" will be discussed. In addition to explosives this method is highly applicable to the detection of mobile drugs labs through volatile chemical release.

Method and system for detecting explosives

DOEpatents

Reber, Edward L [Idaho Falls, ID; Jewell, James K [Idaho Falls, ID; Rohde, Kenneth W [Idaho Falls, ID; Seabury, Edward H [Idaho Falls, ID; Blackwood, Larry G [Idaho Falls, ID; Edwards, Andrew J [Idaho Falls, ID; Derr, Kurt W [Idaho Falls, ID

2009-03-10

A method of detecting explosives in a vehicle includes providing a first rack on one side of the vehicle, the rack including a neutron generator and a plurality of gamma ray detectors; providing a second rack on another side of the vehicle, the second rack including a neutron generator and a plurality of gamma ray detectors; providing a control system, remote from the first and second racks, coupled to the neutron generators and gamma ray detectors; using the control system, causing the neutron generators to generate neutrons; and performing gamma ray spectroscopy on spectra read by the gamma ray detectors to look for a signature indicative of presence of an explosive. Various apparatus and other methods are also provided.

Explosives detection system and method

DOEpatents

Reber, Edward L.; Jewell, James K.; Rohde, Kenneth W.; Seabury, Edward H.; Blackwood, Larry G.; Edwards, Andrew J.; Derr, Kurt W.

2007-12-11

A method of detecting explosives in a vehicle includes providing a first rack on one side of the vehicle, the rack including a neutron generator and a plurality of gamma ray detectors; providing a second rack on another side of the vehicle, the second rack including a neutron generator and a plurality of gamma ray detectors; providing a control system, remote from the first and second racks, coupled to the neutron generators and gamma ray detectors; using the control system, causing the neutron generators to generate neutrons; and performing gamma ray spectroscopy on spectra read by the gamma ray detectors to look for a signature indicative of presence of an explosive. Various apparatus and other methods are also provided.

Detection of circumstellar material in a normal type Ia supernova.

PubMed

Patat, F; Chandra, P; Chevalier, R; Justham, S; Podsiadlowski, Ph; Wolf, C; Gal-Yam, A; Pasquini, L; Crawford, I A; Mazzali, P A; Pauldrach, A W A; Nomoto, K; Benetti, S; Cappellaro, E; Elias-Rosa, N; Hillebrandt, W; Leonard, D C; Pastorello, A; Renzini, A; Sabbadin, F; Simon, J D; Turatto, M

2007-08-17

Type Ia supernovae are important cosmological distance indicators. Each of these bright supernovae supposedly results from the thermonuclear explosion of a white dwarf star that, after accreting material from a companion star, exceeds some mass limit, but the true nature of the progenitor star system remains controversial. Here we report the spectroscopic detection of circumstellar material in a normal type Ia supernova explosion. The expansion velocities, densities, and dimensions of the circumstellar envelope indicate that this material was ejected from the progenitor system. In particular, the relatively low expansion velocities suggest that the white dwarf was accreting material from a companion star that was in the red-giant phase at the time of the explosion.

SEARCH FOR PRECURSOR ERUPTIONS AMONG TYPE IIB SUPERNOVAE

DOE Office of Scientific and Technical Information (OSTI.GOV)

Strotjohann, Nora L.; Ofek, Eran O.; Gal-Yam, Avishay

2015-10-01

The progenitor stars of several Type IIb supernovae (SNe) show indications of extended hydrogen envelopes. These envelopes might be the outcome of luminous energetic pre-explosion events, so-called precursor eruptions. We use the Palomar Transient Factory (PTF) pre-explosion observations of a sample of 27 nearby SNe IIb to look for such precursors during the final years prior to the SN explosion. No precursors are found when combining the observations in 15-day bins, and we calculate the absolute-magnitude-dependent upper limit on the precursor rate. At the 90% confidence level, SNe IIb have on average <0.86 precursors as bright as an absolute R-bandmore » magnitude of −14 in the final 3.5 years before the explosion and <0.56 events over the final year. In contrast, precursors among SNe IIn have a ≳5 times higher rate. The kinetic energy required to unbind a low-mass stellar envelope is comparable to the radiated energy of a few-weeks-long precursor that would be detectable for the closest SNe in our sample. Therefore, mass ejections, if they are common in such SNe, are radiatively inefficient or have durations longer than months. Indeed, when using 60-day bins, a faint precursor candidate is detected prior to SN 2012cs (∼2% false-alarm probability). We also report the detection of the progenitor of SN 2011dh that does not show detectable variability over the final two years before the explosion. The suggested progenitor of SN 2012P is still present, and hence is likely a compact star cluster or an unrelated object.« less

Development of a Coded Aperture X-Ray Backscatter Imager for Explosive Device Detection

NASA Astrophysics Data System (ADS)

Faust, Anthony A.; Rothschild, Richard E.; Leblanc, Philippe; McFee, John Elton

2009-02-01

Defence R&D Canada has an active research and development program on detection of explosive devices using nuclear methods. One system under development is a coded aperture-based X-ray backscatter imaging detector designed to provide sufficient speed, contrast and spatial resolution to detect antipersonnel landmines and improvised explosive devices. The successful development of a hand-held imaging detector requires, among other things, a light-weight, ruggedized detector with low power requirements, supplying high spatial resolution. The University of California, San Diego-designed HEXIS detector provides a modern, large area, high-temperature CZT imaging surface, robustly packaged in a light-weight housing with sound mechanical properties. Based on the potential for the HEXIS detector to be incorporated as the detection element of a hand-held imaging detector, the authors initiated a collaborative effort to demonstrate the capability of a coded aperture-based X-ray backscatter imaging detector. This paper will discuss the landmine and IED detection problem and review the coded aperture technique. Results from initial proof-of-principle experiments will then be reported.

Explosives detection using photoneutrons produced by X-rays

NASA Astrophysics Data System (ADS)

Yang, Yigang; Li, Yuanjing; Wang, Haidong; Li, Tiezhu; Wu, Bin

2007-08-01

The detection of explosives has become a critical issue after recent terrorist attacks. This paper describes research on explosives detection using photoneutrons from a photoneutron convertor that consists of 20 kg heavy water in an aluminum container whose shape was optimized to most effectively convert X-rays to photoneutrons. The X-rays were produced by a 9 MeV electron accelerator with an average electron current of 100 μA, resulted in a photoneutron yield of >10 11 n/s. Monte-Carlo simulations show that the radiation field is composed of X-ray pulses, fast neutron pulses and thermal neutrons. Both the X-ray and fast neutron pulses are 5 μs wide with a 300 Hz repetition frequency. The thermal neutron flux, which is higher than 10 4 n/cm 2/s, is essentially time invariant. A time shielding circuit was developed for the spectrometry system to halt the sampling process during the intense X-ray pulses. Paraffin, boron carbide and lead were used to protect the detector from interference from the X-rays, fast neutrons, thermal neutrons and background γ-rays coming from the system materials induced by photoneutrons. 5″×5″ NaI (Tl) scintillators were chosen as the detectors to detect the photoneutrons induced γ-rays from the inspected explosive simulant. Nitrogen (6.01 cps) 10.828 MeV γ-rays were detected with one detector from a 50 kg carbamide block placed 60 cm in front of the detector. A collimator was used to reduce the number of background 10.828 MeV γ-rays coming from the nitrogen in the air to improve the signal to background ratio from 0.136 to 1.81. A detector array of seven 5″×5″ NaI (Tl) detectors was used to measure the 2-D distributions of N and H in the sample. The combination of photoneutron analysis and X-ray imaging shows promise for enhancing explosives detection capabilities.

Broadband seismology and the detection and verification of underground nuclear explosions

NASA Astrophysics Data System (ADS)

Tinker, Mark Andrew

1997-10-01

On September 24, 1996, President Clinton signed the Comprehensive Test Ban Treaty (CTBT), which bans the testing of all nuclear weapons thereby limiting their future development. Seismology is the primary tool used for the detection and identification of underground explosions and thus, will play a key role in monitoring a CTBT. The detection and identification of low yield explosions requires seismic stations at regional distances (<1500 km). However, because the regional wavefield propagates within the extremely heterogeneous crustal waveguide, the seismic waveforms are also very complicated. Therefore, it is necessary to have a solid understanding of how the phases used in regional discriminants develop within different tectonic regimes. Thus, the development of the seismic phases Pn and Lg, which compose the seismic discriminant Pn/Lg, within the western U.S. from the Non-Proliferation Experiment are evaluated. The most fundamental discriminant is event location as 90% of all seismic sources occur too deep within the earth to be unnatural. France resumed its nuclear testing program after a four year moratorium and conducted six tests during a five month period starting in September of 1995. Using teleseismic data, a joint hypocenter determination algorithm was used to determine the hypocenters of these six explosions. One of the most important problems in monitoring a CTBT is the detection and location of small seismic events. Although seismic arrays have become the central tool for event detection, in the context of a global monitoring treaty, there will be some dependence on sparse regional networks of three-component broadband seismic stations to detect low yield explosions. However, the full power of the data has not been utilized, namely using phases other than P and S. Therefore, the information in the surface wavetrain is used to improve the locations of small seismic events recorded on a sparse network in Bolivia. Finally, as a discrimination example in a complex region, P to S ratios are used to determine source parameters of the Msb{w} 8.3 deep Bolivia earthquake.

Multilevel composition fractionation process for high-value utilization of wheat straw cellulose.

PubMed

Chen, Hong-Zhang; Liu, Zhi-Hua

2014-01-01

Biomass refining into multiple products has gained considerable momentum due to its potential benefits for economic and environmental sustainability. However, the recalcitrance of biomass is a major challenge in bio-based product production. Multilevel composition fractionation processes should be beneficial in overcoming biomass recalcitrance and achieving effective conversion of multiple compositions of biomass. The present study concerns the fractionation of wheat straw using steam explosion, coupled with ethanol extraction, and that this facilitates the establishment of sugars and lignin platform and enables the production of regenerated cellulose films. The results showed that the hemicellulose fractionation yield was 73% under steam explosion at 1.6 MPa for 5.2 minutes, while the lignin fractionation yield was 90% by ethanol extraction at 160°C for 2 hours and with 60% ethanol (v/v). The cellulose yield reached up to 93% after steam explosion coupled with ethanol extraction. Therefore, cellulose sugar, hemicellulose sugar, and lignin platform were established effectively in the present study. Long fibers (retained by a 40-mesh screening) accounted for 90% of the total cellulose fibers, and the glucan conversion of short fibers was 90% at 9.0 hours with a cellulase loading of 25 filter paper units/g cellulose in enzymatic hydrolysis. Regenerated cellulose film was prepared from long fibers using [bmim]Cl, and the tensile strength and breaking elongation was 120 MPa and 4.8%, respectively. The cross-section of regenerated cellulose film prepared by [bmim]Cl displayed homogeneous structure, which indicated a dense architecture and a better mechanical performance. Multilevel composition fractionation process using steam explosion followed by ethanol extraction was shown to be an effective process by which wheat straw could be fractionated into different polymeric fractions with high yields. High-value utilization of wheat straw cellulose was achieved by preparing regenerated cellulose film using [bmim]Cl.

Continuous-wave deep ultraviolet sources for resonance Raman explosive sensing

NASA Astrophysics Data System (ADS)

Yellampalle, Balakishore; Martin, Robert; Sluch, Mikhail; McCormick, William; Ice, Robert; Lemoff, Brian

2015-05-01

A promising approach to stand-off detection of explosive traces is using resonance Raman spectroscopy with Deepultraviolet (DUV) light. The DUV region offers two main advantages: strong explosive signatures due to resonant and λ- 4 enhancement of Raman cross-section, and lack of fluorescence and solar background. For DUV Raman spectroscopy, continuous-wave (CW) or quasi-CW lasers are preferable to high peak powered pulsed lasers because Raman saturation phenomena and sample damage can be avoided. In this work we present a very compact DUV source that produces greater than 1 mw of CW optical power. The source has high optical-to-optical conversion efficiency, greater than 5 %, as it is based on second harmonic generation (SHG) of a blue/green laser source using a nonlinear crystal placed in an external resonant enhancement cavity. The laser system is extremely compact, lightweight, and can be battery powered. Using two such sources, one each at 236.5 nm and 257.5 nm, we are building a second generation explosive detection system called Dual-Excitation-Wavelength Resonance-Raman Detector (DEWRRED-II). The DEWRRED-II system also includes a compact dual-band high throughput DUV spectrometer, and a highly-sensitive detection algorithm. The DEWRRED technique exploits the DUV excitation wavelength dependence of Raman signal strength, arising from complex interplay of resonant enhancement, self-absorption and laser penetration depth. We show sensor measurements from explosives/precursor materials at different standoff distances.

Hand-Held Devices Detect Explosives and Chemical Agents

NASA Technical Reports Server (NTRS)

2010-01-01

Ion Applications Inc., of West Palm Beach, Florida, partnered with Ames Research Center through Small Business Innovation Research (SBIR) agreements to develop a miniature version ion mobility spectrometer (IMS). While NASA was interested in the instrument for detecting chemicals during exploration of distant planets, moons, and comets, the company has incorporated the technology into a commercial hand-held IMS device for use by the military and other public safety organizations. Capable of detecting and identifying molecules with part-per-billion sensitivity, the technology now provides soldiers with portable explosives and chemical warfare agent detection. The device is also being adapted for detecting drugs and is employed in industrial processes such as semiconductor manufacturing.

Method and apparatus for selective capture of gas phase analytes using metal .beta.-diketonate polymers

DOEpatents

Harvey, Scott D [Kennewick, WA

2011-06-21

A process and sensor device are disclosed that employ metal .beta.-diketonate polymers to selectively capture gas-phase explosives and weaponized chemical agents in a sampling area or volume. The metal .beta.-diketonate polymers can be applied to surfaces in various analytical formats for detection of: improvised explosive devices, unexploded ordinance, munitions hidden in cargo holds, explosives, and chemical weapons in public areas.

Sorbent Film-Coated Passive Samplers for Explosives Vapour Detection Part A: Materials Optimisation and Integration with Analytical Technologies.

PubMed

McEneff, Gillian L; Murphy, Bronagh; Webb, Tony; Wood, Dan; Irlam, Rachel; Mills, Jim; Green, David; Barron, Leon P

2018-04-11

A new thin-film passive sampler is presented as a low resource dependent and discrete continuous monitoring solution for explosives-related vapours. Using 15 mid-high vapour pressure explosives-related compounds as probes, combinations of four thermally stable substrates and six film-based sorbents were evaluated. Meta-aramid and phenylene oxide-based materials showed the best recoveries from small voids (~70%). Analysis was performed using liquid chromatography-high resolution accurate mass spectrometry which also enabled tentative identification of new targets from the acquired data. Preliminary uptake kinetics experiments revealed plateau concentrations on the device were reached between 3-5 days. Compounds used in improvised explosive devices, such as triacetone triperoxide, were detected within 1 hour and were stably retained by the sampler for up to 7 days. Sampler performance was consistent for 22 months after manufacture. Lastly, its direct integration with currently in-service explosives screening equipment including ion mobility spectrometry and thermal desorption mass spectrometry is presented. Following exposure to several open environments and targeted interferences, sampler performance was subsequently assessed and potential interferences identified. High-security building and area monitoring for concealed explosives using such cost-effective and discrete passive samplers can add extra assurance to search routines while minimising any additional burden on personnel or everyday site operation.