2002-12-21
This image of a xenon ion engine prototype, photographed through a port of the vacuum chamber where it was being tested at NASA's Jet Propulsion Laboratory, shows the faint blue glow of charged atoms being emitted from the engine. The engine is now in an ongoing extended- life test, in a vacuum test chamber at JPL, and has run for almost 500 days (12,000 hours) and is scheduled to complete nearly 625 days (15,000 hours) by the end of 2001. A similar engine powers the New Millennium Program's flagship mission, Deep Space 1, which uses the ion engine in a trip through the solar system. The engine, weighing 17.6 pounds (8 kilograms), is 15.7 inches (40 centimeters) in diameter and 15.7 inches long. The actual thrust comes from accelerating and expelling positively charged xenon atoms, or ions. While the ions are fired in great numbers out the thruster at more than 110,000 kilometers (68,000 miles) per hour, their mass is so low that the engine produces a gentle thrust of only 90 millinewtons (20-thousandths of a pound). http://photojournal.jpl.nasa.gov/catalog/PIA04238
Extending Ion Engine Technology to NEXT and Beyond
NASA Technical Reports Server (NTRS)
Domonkos, Matthew T.; Patterson, Michael J.; Foster, John E.; Rawlin, Vince K.; Soulas, George C.; Sovey, James S.; Kovaleski, Scott D.; Roman, Robert F.; Williams, George J., Jr.; Lyons, Valerie J. (Technical Monitor)
2002-01-01
Extending ion engine technology beyond the current state-of-the art primary interplanetary electric propulsion system, the 2.3-kW NASA Solar Electric Propulsion Technology and Applications Readiness (NSTAR) system, will require thrusters with improved propellant throughput and total impulse capability. Many of the design choices that culminated in the NSTAR thrusters must be revisited, and their application to next generation ion engine technology must be evaluated. The concept of derating, which was successfully employed in NSTAR, has been applied to the 40 cm NASA Evolutionary Xenon Thruster (NEXT) currently under development at NASA Glenn Research Center (GRC). At 5-kW, NEXT operates with the same average beam current density as NSTAR, and at 10-kW, the peak beam current density is only ten percent greater than NSTAR. The result is that similar Ion optics technology is expected to yield comparable lifetime. Thick-accelerator- grid ion optics are also being tested to realize additional lifetime benefits. A 40-A discharge cathode is being developed for NEXT based on scaling the NSTAR design. Nevertheless, the experiences of the NSTAR ground tests and the thruster on the Deep Space One spacecraft indicate that the discharge cathode wear must be studied experimentally and theoretically to ensure that it meets the lifetime requirements. Although NEXT is in its infancy, investigations have already begun to examine possible modifications to engine design for even higher-power and higher-specific impulse engines. Ion optics using alternate materials such as titanium, graphite, or carbon-carbon composite are currently being investigated due to their low sputter yields at high voltage. To avoid the difficulties encountered using electrodes at high-currents, the use of a microwave-based ion thruster is under investigation for potential high-power ion thruster systems requiring long lifetimes. Additionally, alternative propellants are being considered for applications requiring high-specific impulse (>> 5000 s) and extremely long-life (>> 15,000 hr). Testing requirements make condensable propellants attractive for high-power engines. Although the NSTAR ion engine demonstrated the flight maturity of ion thruster technology, many challenges remain for the development of thrusters with improved propellant throughput and power handling capabilities.
A Synopsis of Ion Propulsion Development Projects in the United States: SERT 1 to Deep Space I
NASA Technical Reports Server (NTRS)
Sovey, James S.; Rawlin, Vincent K.; Patterson, Michael J.
1999-01-01
The historical background and characteristics of the experimental flights of ion propulsion systems and the major ground-based technology demonstrations were reviewed. The results of the first successful ion engine flight in 1964, SERT I which demonstrated ion beam neutralization, are discussed along with the extended operation of SERT II starting in 1970. These results together with the technology employed on the early cesium engine flights. the Applications Technology Satellite (ATS) series, and the ground-test demonstrations, have provided the evolutionary path for the development of xenon ion thruster component technologies, control systems, and power circuit implementations. In the 1997-1999 period, the communication satellite flights using ion engine systems and the Deep Space I flight confirmed that these auxiliary and primary propulsion systems have advanced to a high-level of flight-readiness.
Ion Propulsion Development Projects in US: Space Electric Rocket Test I to Deep Space 1
NASA Technical Reports Server (NTRS)
Sovey, James S.; Rawlin, Vincent K.; Patterson, Michael J.
2001-01-01
The historical background and characteristics of the experimental flights of ion propulsion systems and the major ground-based technology demonstrations are reviewed. The results of the first successful ion engine flight in 1964, Space Electric Rocket Test (SERT) I, which demonstrated ion beam neutralization, are discussed along with the extended operation of SERT II starting in 1970. These results together with the technologies employed on the early cesium engine flights, the applications technology satellite series, and the ground-test demonstrations, have provided the evolutionary path for the development of xenon ion thruster component technologies, control systems, and power circuit implementations. In the 1997-1999 period, the communication satellite flights using ion engine systems and the Deep Space 1 flight confirmed that these auxiliary and primary propulsion systems have advanced to a high level of flight readiness.
Manufacturing of 57cm carbon-carbon composite ion optics for the NEXIS ion engine
NASA Technical Reports Server (NTRS)
Beatty, John S.; Snyder, John Steven; Shih, Wei
2005-01-01
Exploration of the outer planets can be taxing on the ion optics of ion propulsion systems because of the higher power and propellant throughout than the present state-of-the art. Carbon-carbon composite ion optics are an enabling technology extending the life of ion optics operated at high specific impulse, power, and propellant throughout because of their low erosion rates compared to molybdenum ion optics.
Retention of Sputtered Molybdenum on Ion Engine Discharge Chamber Surfaces
NASA Technical Reports Server (NTRS)
Sovey, James S.; Dever, Joyce A.; Power, John L.
2001-01-01
Grit-blasted anode surfaces are commonly used in ion engines to ensure adherence of sputtered coatings. Next generation ion engines will require higher power levels, longer operating times, and thus there will likely be thicker sputtered coatings on their anode surfaces than observed to date on 2.3 kW-class xenon ion engines. The thickness of coatings on the anode of a 10 kW, 40-centimeter diameter thruster, for example, may be 22 micrometers or more after extended operation. Grit-blasted wire mesh, titanium, and aluminum coupons were coated with molybdenum at accelerated rates to establish coating stability after the deposition process and after thermal cycling tests. These accelerated deposition rates are roughly three orders of magnitude more rapid than the rates at which the screen grid is sputtered in a 2.3 kW-class, 30-centimeter diameter ion engine. Using both RF and DC sputtering processes, the molybdenum coating thicknesses ranged from 8 to 130 micrometers, and deposition rates from 1.8 micrometers per hour to 5.1 micrometers per hour. In all cases, the molybdenum coatings were stable after the deposition process, and there was no evidence of spalling of the coatings after 20 cycles from about -60 to +320 C. The stable, 130 micrometer molybdenum coating on wire mesh is 26 times thicker than the thickest coating found on the anode of a 2.3 kW, xenon ion engine that was tested for 8200 hr. Additionally, this coating on wire mesh coupon is estimated to be a factor of greater than 4 thicker than one would expect to obtain on the anode of the next generation ion engine which may have xenon throughputs as high as 550 kg.
Solar-Powered Electric Propulsion Systems: Engineering and Applications
NASA Technical Reports Server (NTRS)
Stearns, J. W.; Kerrisk, D. J.
1966-01-01
Lightweight, multikilowatt solar power arrays in conjunction with electric propulsion offer potential improvements to space exploration, extending the usefulness of existing launch vehicles to higher-energy missions. Characteristics of solar-powered electric propulsion missions are outlined, and preliminary performance estimates are shown. Spacecraft system engineering is discussed with respect to parametric trade-offs in power and propulsion system design. Relationships between mission performance and propulsion system performance are illustrated. The present state of the art of electric propulsion systems is reviewed and related to the mission requirements identified earlier. The propulsion system design and test requirements for a mission spacecraft are identified and discussed. Although only ion engine systems are currently available, certain plasma propulsion systems offer some advantages in over-all system design. These are identified, and goals are set for plasma-thrustor systems to make them competitive with ion-engine systems for mission applications.
Ion Mass Spectroscopy for the Outer Solar System
NASA Astrophysics Data System (ADS)
Reisenfeld, D. B.; Elphic, R. C.; McComas, D. J.; Nordholt, J. E.; Steinberg, J. T.; Wiens, R. C.
2001-01-01
A proven method for determination of the exospheric and surface composition of moons and comets is ion mass spectroscopy. Ions are produced via sputtering of surface constituents by the ambient plasma (solar wind or planetary magnetospheres), and via photo- and electron impact ionization of neutral exospheric/atmospheric constituents. A promising emergent technology in the field of space-based ion mass spectrometry is the low-cost, miniaturized but high-performance ion mass spectrometer (IMS) as exhibited by the Plasma Experiment for Planetary Exploration (PEPE) on Deep Space 1 (DS-1). A technology demonstration instrument, the PEPE IMS realized a mass resolution (M/delta(M)) of approximately 10. Its energy range extends from 5 eV to 9 keV at this mass resolution, and up to 33.5 keV in a lower mass resolution mode. With minimal development, these capabilities can be greatly extended. Already, we have produced a fully functional engineering model having a M/delta(M) = 20 and an energy range extending to 18 keV in the high-mass resolution mode. Further design modifications anticipate extending the mass resolution to 30-40 while still maintaining a miniaturized design. This makes possible many more isotopic and molecular differentiations than achievable with the original PEPE design. A PEPE-class spectrometer can address a significant number of the OPP key strategic objectives. In particular, in situ cometary nucleus analysis, studies of Triton's atmospheric and surface composition, and Europa surface composition analysis, can all be performed through IMS measurements. Additional information is contained in the original extended abstract.
NASA Astrophysics Data System (ADS)
Islam, A. E.; Nikolaev, P.; Amama, P. B.; Zakharov, D.; Sargent, G.; Saber, S.; Huffman, D.; Erford, M.; Semiatin, S. L.; Stach, E. A.; Maruyama, B.
2015-09-01
Carbon nanotube growth depends on the catalytic activity of metal nanoparticles on alumina or silica supports. The control on catalytic activity is generally achieved by variations in water concentration, carbon feed, and sample placement on a few types of alumina or silica catalyst supports obtained via thin film deposition. We have recently expanded the choice of catalyst supports by engineering inactive substrates like c-cut sapphire via ion beam bombardment. The deterministic control on the structure and chemistry of catalyst supports obtained by tuning the degree of beam-induced damage have enabled better regulation of the activity of Fe catalysts only in the ion beam bombarded areas and hence enabled controllable super growth of carbon nanotubes. A wide range of surface characterization techniques were used to monitor the catalytically active surface engineered via ion beam bombardment. The proposed method offers a versatile way to control carbon nanotube growth in patterned areas and also enhances the current understanding of the growth process. With the right choice of water concentration, carbon feed and sample placement, engineered catalyst supports may extend the carbon nanotube growth yield to a level that is even higher than the ones reported here, and thus offers promising applications of carbon nanotubes in electronics, heat exchanger, and energy storage.
Performance Evaluation of the T6 Ion Engine
NASA Technical Reports Server (NTRS)
Snyder, John Steven; Goebel, Dan M.; Hofer, Richard R.; Polk, James E.; Wallace, Neil C.; Simpson, Huw
2010-01-01
The T6 ion engine is a 22-cm diameter, 4.5-kW Kaufman-type ion thruster produced by QinetiQ, Ltd., and is baselined for the European Space Agency BepiColombo mission to Mercury and is being qualified under ESA sponsorship for the extended range AlphaBus communications satellite platform. The heritage of the T6 includes the T5 ion thruster now successfully operating on the ESA GOCE spacecraft. As a part of the T6 development program, an engineering model thruster was subjected to a suite of performance tests and plume diagnostics at the Jet Propulsion Laboratory. The engine was mounted on a thrust stand and operated over its nominal throttle range of 2.5 to 4.5 kW. In addition to the typical electrical and flow measurements, an E x B mass analyzer, scanning Faraday probe, thrust vector probe, and several near-field probes were utilized. Thrust, beam divergence, double ion content, and thrust vector movement were all measured at four separate throttle points. The engine performance agreed well with published data on this thruster. At full power the T6 produced 143 mN of thrust at a specific impulse of 4120 seconds and an efficiency of 64%; optimization of the neutralizer for lower flow rates increased the specific impulse to 4300 seconds and the efficiency to nearly 66%. Measured beam divergence was less than, and double ion content was greater than, the ring-cusp-design NSTAR thruster that has flown on NASA missions. The measured thrust vector offset depended slightly on throttle level and was found to increase with time as the thruster approached thermal equilibrium.
Deep Space 1 Using its Ion Engine (Artist's Concept)
NASA Technical Reports Server (NTRS)
2003-01-01
NASA's New Millennium Deep Space 1 spacecraft approaching the comet 19P/Borrelly. With its primary mission to serve as a technology demonstrator--testing ion propulsion and 11 other advanced technologies--successfully completed in September 1999, Deep Space 1 is now headed for a risky, exciting rendezvous with Comet Borrelly. NASA extended the mission, taking advantage of the ion propulsion and other systems to target the daring encounter with the comet in September 2001. Once a sci-fi dream, the ion propulsion engine has powered the spacecraft for over 12,000 hours. Another onboard experiment includes software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. The first flight in NASA's New Millennium Program, Deep Space 1 was launched October 24, 1998 aboard a Boeing Delta 7326 rocket from Cape Canaveral Air Station, FL. Deep Space 1 successfully completed and exceeded its mission objectives in July 1999 and flew by a near-Earth asteroid, Braille (1992 KD), in September 1999.Islam, A. E.; Zakharov, D.; Stach, E. A.; ...
2015-09-16
Carbon nanotube growth depends on the catalytic activity of metal nanoparticles on alumina or silica supports. The control on catalytic activity is generally achieved by variations in water concentration, carbon feed, and sample placement on a few types of alumina or silica catalyst supports obtained via thin film deposition. We have recently expanded the choice of catalyst supports by engineering inactive substrates like c-cut sapphire via ion beam bombardment. The deterministic control on the structure and chemistry of catalyst supports obtained by tuning the degree of beam-induced damage have enabled better regulation of the activity of Fe catalysts only inmore » the ion beam bombarded areas and hence enabled controllable super growth of carbon nanotubes. A wide range of surface characterization techniques were used to monitor the catalytically active surface engineered via ion beam bombardment. The proposed method offers a versatile way to control carbon nanotube growth in patterned areas and also enhances the current understanding of the growth process. As a result, with the right choice of water concentration, carbon feed and sample placement, engineered catalyst supports may extend the carbon nanotube growth yield to a level that is even higher than the ones reported here, and thus offers promising applications of carbon nanotubes in electronics, heat exchanger, and energy storage.« less
NASA Technical Reports Server (NTRS)
Kaufman, H. R.; Carruth, M. R., Jr.
1979-01-01
The charge exchange plasma environment around a spacecraft that uses mercury ion thrusters for propulsion is described. The interactions between the plasma environment and the spacecraft are determined and a model which describes the propagation of the mercury charge exchange plasma is discussed. The model is extended to describe the flow of the molybdenum component of the charge exchange plasma. The uncertainties in the models for various conditions are discussed and current drain to the solar array, charge exchange plasma material deposition, and the effects of space plasma on the charge exchange plasma propagation are addressed.
Deep Space 1 Using its Ion Engine Artist Concept
2003-07-02
NASA's New Millennium Deep Space 1 spacecraft approaching the comet 19P/Borrelly. With its primary mission to serve as a technology demonstrator--testing ion propulsion and 11 other advanced technologies--successfully completed in September 1999, Deep Space 1 is now headed for a risky, exciting rendezvous with Comet Borrelly. NASA extended the mission, taking advantage of the ion propulsion and other systems to target the daring encounter with the comet in September 2001. Once a sci-fi dream, the ion propulsion engine has powered the spacecraft for over 12,000 hours. Another onboard experiment includes software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. The first flight in NASA's New Millennium Program, Deep Space 1 was launched October 24, 1998 aboard a Boeing Delta 7326 rocket from Cape Canaveral Air Station, FL. Deep Space 1 successfully completed and exceeded its mission objectives in July 1999 and flew by a near-Earth asteroid, Braille (1992 KD), in September 1999. http://photojournal.jpl.nasa.gov/catalog/PIA04604
Ion Thruster Power Levels Extended by a Factor of 10
NASA Technical Reports Server (NTRS)
Patterson, Michael J.
2004-01-01
In response to two NASA Office of Space Science initiatives, the NASA Glenn Research Center is now developing a 7-kW-class xenon ion thruster system for near-term solar-powered spacecraft and a 25-kW ion engine for nuclear-electric spacecraft. The 7-kW ion thruster and power processor can be throttled down to 1 kW and are applicable to 25-kW flagship missions to the outer planets, asteroids, and comets. This propulsion system was scaled up from the 2.5-kW ion thruster and power processor that was developed successfully by Glenn, Boeing, the Jet Propulsion Laboratory (JPL), and Spectrum Astro for the Deep Space 1 spacecraft. The 7-kW ion thruster system is being developed under NASA's Evolutionary Xenon Thruster (NEXT) project, which includes partners from JPL, Aerojet, Boeing, the University of Michigan, and Colorado State University.
Moreau, Christophe J.; Revilloud, Jean; Caro, Lydia N.; Dupuis, Julien P.; Trouchet, Amandine; Estrada-Mondragón, Argel; Nieścierowicz, Katarzyna; Sapay, Nicolas; Crouzy, Serge; Vivaudou, Michel
2017-01-01
Ligand-gated ion channels enable intercellular transmission of action potential through synapses by transducing biochemical messengers into electrical signal. We designed artificial ligand-gated ion channels by coupling G protein-coupled receptors to the Kir6.2 potassium channel. These artificial channels called ion channel-coupled receptors offer complementary properties to natural channels by extending the repertoire of ligands to those recognized by the fused receptors, by generating more sustained signals and by conferring potassium selectivity. The first artificial channels based on the muscarinic M2 and the dopaminergic D2L receptors were opened and closed by acetylcholine and dopamine, respectively. We find here that this opposite regulation of the gating is linked to the length of the receptor C-termini, and that C-terminus engineering can precisely control the extent and direction of ligand gating. These findings establish the design rules to produce customized ligand-gated channels for synthetic biology applications. PMID:28145461
Experimental Methods for Trapping Ions Using Microfabricated Surface Ion Traps
Hong, Seokjun; Lee, Minjae; Kwon, Yeong-Dae; Cho, Dong-il "Dan"; Kim, Taehyun
2017-01-01
Ions trapped in a quadrupole Paul trap have been considered one of the strong physical candidates to implement quantum information processing. This is due to their long coherence time and their capability to manipulate and detect individual quantum bits (qubits). In more recent years, microfabricated surface ion traps have received more attention for large-scale integrated qubit platforms. This paper presents a microfabrication methodology for ion traps using micro-electro-mechanical system (MEMS) technology, including the fabrication method for a 14 µm-thick dielectric layer and metal overhang structures atop the dielectric layer. In addition, an experimental procedure for trapping ytterbium (Yb) ions of isotope 174 (174Yb+) using 369.5 nm, 399 nm, and 935 nm diode lasers is described. These methodologies and procedures involve many scientific and engineering disciplines, and this paper first presents the detailed experimental procedures. The methods discussed in this paper can easily be extended to the trapping of Yb ions of isotope 171 (171Yb+) and to the manipulation of qubits. PMID:28872137
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zhang, Shen; Kang, Wei, E-mail: weikang@pku.edu.cn; College of Engineering, Peking University, Beijing 100871
An extended first-principles molecular dynamics (FPMD) method based on Kohn-Sham scheme is proposed to elevate the temperature limit of the FPMD method in the calculation of dense plasmas. The extended method treats the wave functions of high energy electrons as plane waves analytically and thus expands the application of the FPMD method to the region of hot dense plasmas without suffering from the formidable computational costs. In addition, the extended method inherits the high accuracy of the Kohn-Sham scheme and keeps the information of electronic structures. This gives an edge to the extended method in the calculation of mixtures ofmore » plasmas composed of heterogeneous ions, high-Z dense plasmas, lowering of ionization potentials, X-ray absorption/emission spectra, and opacities, which are of particular interest to astrophysics, inertial confinement fusion engineering, and laboratory astrophysics.« less
NSTAR Extended Life Test Discharge Chamber Flake Analysis
NASA Technical Reports Server (NTRS)
deGroh, Kim K.; Banks, Bruce A.; Karniotis, Christina A.
2005-01-01
The Extended Life Test (ELT) of the NASA Solar Electric Propulsion Technology Readiness (NSTAR) ion thruster was concluded after 30,352 hours of operation. The ELT was conducted using the Deep Space 1 (DS1) back-up flight engine, a 30 cm diameter xenon ion thruster. Post-test inspection of the ELT engine revealed numerous contaminant flakes distributed over the bottom of the cylindrical section of the anode within the discharge chamber (DC). Extensive analyses were conducted to determine the source of the particles, which is critical to the understanding of degradation mechanisms of long life ion thruster operation. Analyses included: optical microscopy (OM) and particle length histograms, field emission scanning electron microscopy (FESEM) combined with energy dispersive spectroscopy (EDS), and atomic oxygen plasma exposure tests. Analyses of the particles indicate that the majority of the DC flakes consist of a layered structure, typically with either two or three layers. The flakes comprising two layers were typically found to have a molybdenum-rich (Mo-rich) layer on one side and a carbon-rich (C-rich) layer on the other side. The flakes comprising three layers were found to be sandwich-like structures with Mo-rich exterior layers and a C-rich interior layer. The presence of the C-rich layers indicates that these particles were produced by sputter deposition build-up on a surface external to the discharge chamber from ion sputter erosion of the graphite target in the test chamber. This contaminant layer became thick enough that particles spalled off, and then were electro-statically attracted into the ion thruster interior, where they were coated with Mo from internal sputter erosion of the screen grid and cathode components. Atomic oxygen tests provided evidence that the DC chamber flakes are composed of a significant fraction of carbon. Particle size histograms further indicated that the source of the particles was spalling of carbon flakes from downstream surfaces. Analyses of flakes taken from the downstream surface of the accelerator grid provided additional supportive information. The production of the downstream carbon flakes, and hence the potential problems associated with the flake particles in the ELT ion thruster engine is a facility induced effect and would not occur in the space environment.
Developing Battery Computer Aided Engineering Tools for Military Vehicles
2013-12-01
Task 1.b Modeling Bullet penetration. The purpose of Task 1.a was to extend the chemical kinetics models of CoO2 cathodes developed under CAEBAT to...lithium- ion batteries. The new finite element model captures swelling/shrinking in cathodes /anodes due to thermal expansion and lithium intercalation...Solid Electrolyte Interphase (SEI) layer decomposition 80 2 Anode — electrolyte 100 3 Cathode — electrolyte 130 4 Electrolyte decomposition 180
2014-04-01
surrogate model generation is difficult for high -dimensional problems, due to the curse of dimensionality. Variable screening methods have been...a variable screening model was developed for the quasi-molecular treatment of ion-atom collision [16]. In engineering, a confidence interval of...for high -level radioactive waste [18]. Moreover, the design sensitivity method can be extended to the variable screening method because vital
Investigation of Keeper Erosion in the NSTAR Ion Thruster
NASA Technical Reports Server (NTRS)
Domonkos, Matthew T.; Foster, John E.; Patterson, Michael J.; Williams, George J., Jr.
2001-01-01
The goal of the present investigation was to determine the cause for the difference in the observed discharge keeper erosion between the 8200 hr wear test of a NASA Solar Electric Propulsion Technology Applications Readiness (NSTAR) engineering model thruster and the ongoing extended life test (ELT) of the NSTAR flight spare thruster. During the ELT, the NSTAR flight spare ion thruster experienced unanticipated erosion of the discharge cathode keeper. Photographs of the discharge keeper show that the orifice has enlarged to slightly more than twice the original diameter. Several differences between the ELT and the 8200 hr wear test were initially identified to determine any effects which could lead to the erosion in the ELT. In order to identify the cause of the ELT erosion, emission spectra from an engineering model thruster were collected to assess the dependence of keeper erosion on operating conditions. Keeper ion current was measured to estimate wear. Additionally, post-test inspection of both a copper keeper-cap was conducted, and the results are presented. The analysis indicated that the bulk of the ion current was collected within 2-mm radially of the orifice. The estimated volumetric wear in the ELT was comparable to previous wear tests. Redistribution of the ion current on the discharge keeper was determined to be the most likely cause of the ELT erosion. The change in ion current distribution was hypothesized to caused by the modified magnetic field of the flight assemblies.
NASA Technical Reports Server (NTRS)
Brophy, John R. (Inventor)
1993-01-01
Apparatus and methods for large-area, high-power ion engines comprise dividing a single engine into a combination of smaller discharge chambers (or segments) configured to operate as a single large-area engine. This segmented ion thruster (SIT) approach enables the development of 100-kW class argon ion engines for operation at a specific impulse of 10,000 s. A combination of six 30-cm diameter ion chambers operating as a single engine can process over 100 kW. Such a segmented ion engine can be operated from a single power processor unit.
Li, Juchuan; Zhang, Qinglin; Xiao, Xingcheng; ...
2015-10-18
The intercalation compounds are generally considered as ideal electrode materials for lithium-ion batteries thanks to their minimum volume expansion and fast lithium ion diffusion. However, cracking still occurs in those compounds and has been identified as one of the critical issues responsible for their capacity decay and short cycle life, although the diffusion-induced stress and volume expansion are much smaller than those in alloying-type electrodes. Here, we designed a thin-film model system that enables us to tailor the cation ordering in LiNi 0.5Mn 1.5O 4 spinels and correlate the stress patterns, phase evolution, and cycle performances. Surprisingly, we found thatmore » distinct reaction paths cause negligible difference in the overall stress patterns but significantly different cracking behaviors and cycling performances: 95% capacity retention for disordered LiNi 0.5Mn 1.5O 4 and 48% capacity retention for ordered LiNi 0.5Mn 1.5O 4 after 2000 cycles. We were able to pinpoint that the extended solid-solution region with suppressed phase transformation attributed to the superior electrochemical performance of disordered spinel. Furthermore, this work envisions a strategy for rationally designing stable cathodes for lithium-ion batteries through engineering the atomic structure that extends the solid-solution region and suppresses phase transformation.« less
2016-09-01
HPCMP will continue to be a key resource in solving challenging problems for the Department of Defense . 1 Fall 2016 High-F idel i ty Simulat ions of...laser interactions. The group had studied plasma expansion experimentally, but this wasn’t sufficient to understand the problem . Feister adapted and...focused on increasing the efficiency of jet turbine engines and extending aircraft flight ranges by changing the shape (articulation) of the turbine
A segmented ion engine design for solar electric propulsion systems
NASA Technical Reports Server (NTRS)
Brophy, John R.
1992-01-01
A new ion engine design, called a segmented ion engine, is described which is capable of reducing the required ion source life time for small body rendezvous missions from 18,000 h to about 8,000 h. The use of SAND ion optics for the engine accelerator system makes it possible to substantially reduce the cost of demonstrating the required engine endurance. It is concluded that a flight test of a 5-kW xenon ion propulsion system on the ELITE spacecraft would enormously reduce the cost and risk of using ion propulsion on a planetary vehicle by addressing systems level issues associated with flying a spacecraft radically different from conventional planetary vehicles.
Mechanism of Na-Ion Storage in Hard Carbon Anodes Revealed by Heteroatom Doping
DOE Office of Scientific and Technical Information (OSTI.GOV)
Li, Zhifei; Bommier, Clement; Chong, Zhi Sen
Hard carbon is the candidate anode material for the commercialization of Na-ion batteries the batteries that by virtue of being constructed from inexpensive and abundant components open the door for massive scale up of battery-based storage of electrical energy. Holding back the development of these batteries is that a complete understanding of the mechanism of Na-ion storage in hard carbon has remained elusive. Although as an amorphous carbon, hard carbon possesses a subtle and complex structure composed of domains of layered rumpled sheets that have local order resembling graphene within each layer but complete disorder along the c-axis between layers.more » Here, we present two key discoveries: first that characteristics of hard carbon s structure can be modified systematically by heteroatom doping, and second, that these changes greatly affect Na-ion storage properties, which reveal the mechanisms for Na storage in hard carbon. Specifically, P, S and B doping was used to engineer the density of local defects in graphenic layers, and to modify the spacing between the layers. While opening the interlayer spacing through P or S doping extends the low-voltage capacity plateau, and increasing the defect concentration with P or B doping high first sodiation capacity is achieved. Furthermore, we observe that the highly defective B-doped hard carbon suffers a tremendous irreversible capacity in the first desodiation cycle. Our combined first principles calculations and experimental studies revealed a new trapping mechanism, showing that the high binding energies between B-doping induced defects and Na-ions are responsible for the irreversible capacity. The understanding generated in this work provides a totally new set of guiding principles for materials engineers working to optimize hard carbon for Na-ion battery applications.« less
Mechanism of Na-Ion Storage in Hard Carbon Anodes Revealed by Heteroatom Doping
Li, Zhifei; Bommier, Clement; Chong, Zhi Sen; ...
2017-05-23
Hard carbon is the candidate anode material for the commercialization of Na-ion batteries the batteries that by virtue of being constructed from inexpensive and abundant components open the door for massive scale up of battery-based storage of electrical energy. Holding back the development of these batteries is that a complete understanding of the mechanism of Na-ion storage in hard carbon has remained elusive. Although as an amorphous carbon, hard carbon possesses a subtle and complex structure composed of domains of layered rumpled sheets that have local order resembling graphene within each layer but complete disorder along the c-axis between layers.more » Here, we present two key discoveries: first that characteristics of hard carbon s structure can be modified systematically by heteroatom doping, and second, that these changes greatly affect Na-ion storage properties, which reveal the mechanisms for Na storage in hard carbon. Specifically, P, S and B doping was used to engineer the density of local defects in graphenic layers, and to modify the spacing between the layers. While opening the interlayer spacing through P or S doping extends the low-voltage capacity plateau, and increasing the defect concentration with P or B doping high first sodiation capacity is achieved. Furthermore, we observe that the highly defective B-doped hard carbon suffers a tremendous irreversible capacity in the first desodiation cycle. Our combined first principles calculations and experimental studies revealed a new trapping mechanism, showing that the high binding energies between B-doping induced defects and Na-ions are responsible for the irreversible capacity. The understanding generated in this work provides a totally new set of guiding principles for materials engineers working to optimize hard carbon for Na-ion battery applications.« less
Measurements of ion concentration in gasoline and diesel engine exhaust
NASA Astrophysics Data System (ADS)
Yu, Fangqun; Lanni, Thomas; Frank, Brian P.
The nanoparticles formed in motor vehicle exhaust have received increasing attention due to their potential adverse health effects. It has been recently proposed that combustion-generated ions may play a critical role in the formation of these volatile nanoparticles. In this paper, we design an experiment to measure the total ion concentration in motor vehicle engine exhaust, and report some preliminary measurements in the exhaust of a gasoline engine (K-car) and a diesel engine (diesel generator). Under the experimental set-up reported in this study and for the specific engines used, the total ion concentration is ca. 3.3×10 6 cm -3 with almost all of the ions smaller than 3 nm in the gasoline engine exhaust, and is above 2.7×10 8 cm -3 with most of the ions larger than 3 nm in the diesel engine exhaust. This difference in the measured ion properties is interpreted as a result of the different residence times of exhaust inside the tailpipe/connecting pipe and the different concentrations of soot particles in the exhaust. The measured ion concentrations appear to be within the ranges predicted by a theoretical model describing the evolution of ions inside a pipe.
A Roadmap for Aircraft Engine Life Extending Control
NASA Technical Reports Server (NTRS)
Guo, Ten-Huei
2001-01-01
The concept of Aircraft Engine Life Extending Control is introduced. A brief description of the tradeoffs between performance and engine life are first explained. The overall goal of the life extending controller is to reduce the engine operating cost by extending the on-wing engine life while improving operational safety. The research results for NASA's Rocket Engine life extending control program are also briefly described. Major building blocks of the Engine Life Extending Control architecture are examined. These blocks include: life prediction models, engine operation models, stress and thermal analysis tools, control schemes, and intelligent control systems. The technology areas that would likely impact the successful implementation of an aircraft engine life extending control are also briefly described. Near, intermediate, and long term goals of NASA's activities are also presented.
Measurements of C V flows from thermal charge-exchange excitation in divertor plasmas
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zaniol, B.; Isler, R. C.; Brooks, N. H.
2001-10-01
Certain transitions of C IV (C{sup 3+}) from n=7 to n=6 ({approx}7226 {angstrom}) and from n=6 to n=5 ({approx}4660 {angstrom}) sometimes appear much brighter in tokamak divertors than expected for electron-impact excitation from the ground state. This situation occurs because of charge exchange between C V (C{sup 4+}) and recycling thermal deuterium atoms in the n=2 level. As a result, it is possible to extend parallel flow measurements of carbon, which have previously been performed on C II--C IV ions using Doppler shift spectroscopy, to include flows of the He-like C V ions. The work described here includes modeling ofmore » the spectral features, correlation of state populations with classical Monte Carlo trajectory (CTMC) predictions, and applications to flow measurements in the DIII-D divertor [Plasma Physics Controlled Nuclear Fusion Research 1986 (International Atomic Energy Agency, Vienna, 1987), Vol. I, p. 159; Proceedings of the 18th IEEE/NPSS Symposium on Fusion Engineering, Albuquerque (Institute of Electrical and Electronic Engineers, Piscataway, 1999), p. 515].« less
Measurements of C V flows from thermal charge-exchange excitation in divertor plasmas
NASA Astrophysics Data System (ADS)
Zaniol, B.; Isler, R. C.; Brooks, N. H.; West, W. P.; Olson, R. E.
2001-10-01
Certain transitions of C IV (C3+) from n=7 to n=6 (≈7226 Å) and from n=6 to n=5 (≈4660 Å) sometimes appear much brighter in tokamak divertors than expected for electron-impact excitation from the ground state. This situation occurs because of charge exchange between C V (C4+) and recycling thermal deuterium atoms in the n=2 level. As a result, it is possible to extend parallel flow measurements of carbon, which have previously been performed on C II-C IV ions using Doppler shift spectroscopy, to include flows of the He-like C V ions. The work described here includes modeling of the spectral features, correlation of state populations with classical Monte Carlo trajectory (CTMC) predictions, and applications to flow measurements in the DIII-D divertor [Plasma Physics Controlled Nuclear Fusion Research 1986 (International Atomic Energy Agency, Vienna, 1987), Vol. I, p. 159; Proceedings of the 18th IEEE/NPSS Symposium on Fusion Engineering, Albuquerque (Institute of Electrical and Electronic Engineers, Piscataway, 1999), p. 515].
Spatially-Resolved Beam Current and Charge-State Distributions for the NEXT Ion Engine
NASA Technical Reports Server (NTRS)
Pollard, James E.; Diamant, Kevin D.; Crofton, Mark W.; Patterson, Michael J.; Soulas, George C.
2010-01-01
Plume characterization tests with the 36-cm NEXT ion engine are being performed at The Aerospace Corporation using engineering-model and prototype-model thrusters. We have examined the beam current density and xenon charge-state distribution as functions of position on the accel grid. To measure the current density ratio j++/j+, a collimated Eprobe was rotated through the plume with the probe oriented normal to the accel electrode surface at a distance of 82 cm. The beam current density jb versus radial position was measured with a miniature planar probe at 3 cm from the accel. Combining the j++/j+ and jb data yielded the ratio of total Xe+2 current to total Xe+1 current (J++/J+) at forty operating points in the standard throttle table. The production of Xe+2 and Xe+3 was measured as a function of propellant utilization to support performance and lifetime predictions for an extended throttle table. The angular dependence of jb was measured at intermediate and far-field distances to assist with plume modeling and to evaluate the thrust loss due to beam divergence. Thrust correction factors were derived from the total doubles-to-singles current ratio and from the far-field divergence data
1998-09-30
KENNEDY SPACE CENTER, FLA. -- Deep Space 1 is lifted from its work platform, giving a closer view of the experimental solar-powered ion propulsion engine. The ion propulsion engine is the first non-chemical propulsion to be used as the primary means of propelling a spacecraft. Above the engine is one of the two solar wings, folded for launch, that will provide the power for it. When fully extended, the wings measure 38.6 feet from tip to tip. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century. Another onboard experiment includes software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. Deep Space 1 will complete most of its mission objectives within the first two months, but may also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched aboard a Boeing Delta 7326 rocket from Launch Pad 17A, Cape Canaveral Air Station, in October. Delta II rockets are medium capacity expendable launch vehicles derived from the Delta family of rockets built and launched since 1960. Since then there have been more than 245 Delta launches
NASA Technical Reports Server (NTRS)
Meserole, J. S.; Keefer, Dennis; Ruyten, Wilhelmus; Peng, Xiaohang
1995-01-01
An ion engine is a plasma thruster which produces thrust by extracting ions from the plasma and accelerating them to high velocity with an electrostatic field. The ions are then neutralized and leave the engine as high velocity neutral particles. The advantages of ion engines are high specific impulse and efficiency and their ability to operate over a wide range of input powers. In comparison with other electric thrusters, the ion engine has higher efficiency and specific impulse than thermal electric devices such as the arcjet, microwave, radiofrequency and laser heated thrusters and can operate at much lower current levels than the MPD thruster. However, the thrust level for an ion engine may be lower than a thermal electric thruster of the same operating power, consistent with its higher specific impulse, and therefore ion engines are best suited for missions which can tolerate longer duration propulsive phases. The critical issue for the ion engine is lifetime, since the prospective missions may require operation for several thousands of hours. The critical components of the ion engine, with respect to engine lifetime, are the screen and accelerating grid structures. Typically, these are large metal screens that must support a large voltage difference and maintain a small gap between them. Metallic whisker growth, distortion and vibration can lead to arcing, and over a long period of time ion sputtering will erode the grid structures and change their geometry. In order to study the effects of long time operation of the grid structure, we are developing computer codes based on the Particle-In-Cell (PIC) technique and Laser Induced Fluorescence (LIF) diagnostic techniques to study the physical processes which control the performance and lifetime of the grid structures.
NASA Technical Reports Server (NTRS)
Herman, Daniel A.; Gallimore, Alec D.
2006-01-01
Floating emissive probe plasma potential data are presented over a two-dimensional array of locations in the near Discharge Cathode Assembly (DCA) region of a 30-cm diameter ring-cusp ion thruster. Discharge plasma data are presented with beam extraction at throttling conditions comparable to the NASA TH Levels 8, 12, and 15. The operating conditions of the Extended Life Test (ELT) of the Deep Space One (DS1) flight spare ion engine, where anomalous discharge keeper erosion occurred, were TH 8 and TH 12 consequently they are of specific interest in investigating discharge keeper erosion phenomena. The data do not validate the presence of a potential hill plasma structure downstream of the DCA, which has been proposed as a possible erosion mechanism. The data are comparable in magnitude to data taken by other researchers in ring-cusp electron-bombardment ion thrusters. The plasma potential structures are insensitive to thruster throttling level with a minimum as low as 14 V measured at the DCA exit plane and increasing gradually in the axial direction. A sharp increase in plasma potential to the bulk discharge value of 26 to 28 volts, roughly 10 mm radially from DCA centerline, was observed. Plasma potential measurements indicate a low-potential plume structure that is roughly 20 mm in diameter emanating from the discharge cathode that may be attributed to a free-standing plasma double layer.
Engineering Risk Assessment of Space Thruster Challenge Problem
NASA Technical Reports Server (NTRS)
Mathias, Donovan L.; Mattenberger, Christopher J.; Go, Susie
2014-01-01
The Engineering Risk Assessment (ERA) team at NASA Ames Research Center utilizes dynamic models with linked physics-of-failure analyses to produce quantitative risk assessments of space exploration missions. This paper applies the ERA approach to the baseline and extended versions of the PSAM Space Thruster Challenge Problem, which investigates mission risk for a deep space ion propulsion system with time-varying thruster requirements and operations schedules. The dynamic mission is modeled using a combination of discrete and continuous-time reliability elements within the commercially available GoldSim software. Loss-of-mission (LOM) probability results are generated via Monte Carlo sampling performed by the integrated model. Model convergence studies are presented to illustrate the sensitivity of integrated LOM results to the number of Monte Carlo trials. A deterministic risk model was also built for the three baseline and extended missions using the Ames Reliability Tool (ART), and results are compared to the simulation results to evaluate the relative importance of mission dynamics. The ART model did a reasonable job of matching the simulation models for the baseline case, while a hybrid approach using offline dynamic models was required for the extended missions. This study highlighted that state-of-the-art techniques can adequately adapt to a range of dynamic problems.
Performance Evaluation of the NEXT Ion Engine
NASA Technical Reports Server (NTRS)
Soulas, George C.; Domonkos, Matthew T.; Patterson, Michael J.
2003-01-01
The performance test results of three NEXT ion engines are presented. These ion engines exhibited peak specific impulse and thrust efficiency ranges of 4060 4090 s and 0.68 0.69, respectively, at the full power point of the NEXT throttle table. The performance of the ion engines satisfied all project requirements. Beam flatness parameters were significantly improved over the NSTAR ion engine, which is expected to improve accelerator grid service life. The results of engine inlet pressure and temperature measurements are also presented. Maximum main plenum, cathode, and neutralizer pressures were 12,000 Pa, 3110 Pa, and 8540 Pa, respectively, at the full power point of the NEXT throttle table. Main plenum and cathode inlet pressures required about 6 hours to increase to steady-state, while the neutralizer required only about 0.5 hour. Steady-state engine operating temperature ranges throughout the power throttling range examined were 179 303 C for the discharge chamber magnet rings and 132 213 C for the ion optics mounting ring.
NEXT Ion Engine 2000 Hour Wear Test Results
NASA Technical Reports Server (NTRS)
Soulas, George C.; Kamhawi, Hani; Patterson, Michael J.; Britton, Melissa A.; Frandina, Michael M.
2004-01-01
The results of the NEXT 2000 h wear test are presented. This test was conducted with a 40 cm engineering model ion engine, designated EM1, at a 3.52 A beam current and 1800 V beam power supply voltage. Performance tests, which were conducted over a throttling range of 1.1 to 6.9 kW throughout the wear test, demonstrated that EM1 satisfied all thruster performance requirements. The ion engine accumulated 2038 h of operation at a thruster input power of 6.9 kW, processing 43 kg of xenon. Overall ion engine performance, which includes thrust, thruster input power, specific impulse, and thrust efficiency, was steady with no indications of performance degradation. The ion engine was also inspected following the test. This paper presents these findings.
Increasing the Extracted Beam Current Density in Ion Thrusters
NASA Astrophysics Data System (ADS)
Arthur, Neil Anderson
Ion thrusters have seen application on space science missions and numerous satellite missions. Ion engines offer higher electrical efficiency and specific impulse capability coupled with longer demonstrated lifetime as compared to other space propulsion technologies. However, ion engines are considered to have low thrust. This work aims to address the low thrust conception; whereby improving ion thruster performance and thrust density will lead to expanded mission capabilities for ion thruster technology. This goal poses a challenge because the mechanism for accelerating ions, the ion optics, is space charge limited according to the Child-Langmuir law-there is a finite number of ions that can be extracted through the grids for a given voltage. Currently, ion thrusters operate at only 40% of this limit, suggesting there is another limit artificially constraining beam current. Experimental evidence suggests the beam current can become source limited-the ion density within the plasma is not large enough to sustain high beam currents. Increasing the discharge current will increase ion density, but ring cusp ion engines become anode area limited at high discharge currents. The ring cusp magnetic field increases ionization efficiency but limits the anode area available for electron collection. Above a threshold current, the plasma becomes unstable. Increasing the engine size is one approach to increasing the operational discharge current, ion density, and thus the beam current, but this presents engineering challenges. The ion optics are a pair of closely spaced grids. As the engine diameter increases, it becomes difficult to maintain a constant grid gap. Span-to-gap considerations for high perveance optics limit ion engines to 50 cm in diameter. NASA designed the annular ion engine to address the anode area limit and scale-up problems by changing the discharge chamber geometry. The annular engine provides a central mounting structure for the optics, allowing the beam area to increase while maintaining a fixed span-to-gap. The central stalk also provides additional surface area for electron collection. Circumventing the anode area limitation, the annular ion engine can operate closer to the Child-Langmuir limit as compared to a conventional cylindrical ion thruster. Preliminary discharge characterization of a 65 cm annular ion engine shows >90% uniformity and validates the scalability of the technology. Operating beyond the Child-Langmuir limit would allow for even larger performance gains. This classic law does not consider the ion injection velocity into the grid sheath. The Child-Langmuir limit shifts towards higher current as the ion velocity increases. Ion drift velocity can be created by enhancing the axially-directed electric field. One method for creating this field is to modify the plasma potential distribution. This can be accomplished by biasing individual magnetic cusps, through isolated, conformal electrodes placed on each magnet ring. Experiments on a 15 cm ion thruster have shown that plasma potential in the bulk can be modified by as much as 5 V and establish ion drift towards the grid plane. Increases in ion current density at the grid by up to 20% are demonstrated. Performance implications are also considered, and increases in simulated beam current of 15% and decreases in discharge losses of 5% are observed. Electron density measurements within the magnetic cusps revealed, surprisingly, as cusp current draw increases, the leak width does not change. This suggests that instead of increasing the electron collection area, cusp bias enhances electron mobility along field lines.
Performance Evaluation of 40 cm Ion Optics for the NEXT Ion Engine
NASA Technical Reports Server (NTRS)
Soulas, George C.; Haag, Thomas W.; Patterson, Michael J.
2002-01-01
The results of performance tests with two 40 cm ion optics sets are presented and compared to those of 30 cm ion optics with similar aperture geometries. The 40 cm ion optics utilized both NSTAR and TAG (Thick-Accelerator-Grid) aperture geometries. All 40 cm ion optics tests were conducted on a NEXT (NASA's Evolutionary Xenon Thruster) laboratory model ion engine. Ion optics performance tests were conducted over a beam current range of 1.20 to 3.52 A and an engine input power range of 1.1 to 6.9 kW. Measured ion optics' performance parameters included near-field radial beam current density profiles, impingement-limited total voltages, electron backstreaming limits, screen grid ion transparencies, beam divergence angles, and start-up transients. Impingement-limited total voltages for 40 cm ion optics with the NSTAR aperture geometry were 60 to 90 V lower than those with the TAG aperture geometry. This difference was speculated to be due to an incomplete burn-in of the TAG ion optics. Electron backstreaming limits for the 40 cm ion optics with the TAG aperture geometry were 8 to 19 V higher than those with the NSTAR aperture geometry due to the thicker accelerator grid of the TAG geometry. Because the NEXT ion engine provided beam flatness parameters that were 40 to 63 percent higher than those of the NSTAR ion engine, the 40 cm ion optics outperformed the 30 cm ion optics.
Electron Bombardment Ion Thruster
1970-08-21
Researchers at the Lewis Research Center had been studying different methods of electric rocket propulsion since the mid-1950s. Harold Kaufman created the first successful engine, the electron bombardment ion engine, in the early 1960s. Over the ensuing decades Lewis researchers continued to advance the original ion thruster concept. A Space Electric Rocket Test (SERT) spacecraft was launched in June 1964 to test Kaufman’s engine in space. SERT I had one cesium engine and one mercury engine. The suborbital flight was only 50 minutes in duration but proved that the ion engine could operate in space. This was followed in 1966 by the even more successful SERT II, which operated on and off for over ten years. Lewis continued studying increasingly more powerful ion thrusters. These electric engines created and accelerated small particles of propellant material to high exhaust velocities. Electric engines have a very small amount of thrust and are therefore not capable of lifting a spaceship from the surface of the Earth. Once lofted into orbit, however, electric engines are can produce small, continuous streams of thrust for several years.
Performance and driveline analyses of engine capacity in range extender engine hybrid vehicle
NASA Astrophysics Data System (ADS)
Praptijanto, Achmad; Santoso, Widodo Budi; Nur, Arifin; Wahono, Bambang; Putrasari, Yanuandri
2017-01-01
In this study, range extender engine designed should be able to meet the power needs of a power generator of hybrid electrical vehicle that has a minimum of 18 kW. Using this baseline model, the following range extenders will be compared between conventional SI piston engine (Baseline, BsL), engine capacity 1998 cm3, and efficiency-oriented SI piston with engine capacity 999 cm3 and 499 cm3 with 86 mm bore and stroke square gasoline engine in the performance, emission prediction of range extender engine, standard of charge by using engine and vehicle simulation software tools. In AVL Boost simulation software, range extender engine simulated from 1000 to 6000 rpm engine loads. The highest peak engine power brake reached up to 38 kW at 4500 rpm. On the other hand the highest torque achieved in 100 Nm at 3500 rpm. After that using AVL cruise simulation software, the model of range extended electric vehicle in series configuration with main components such as internal combustion engine, generator, electric motor, battery and the arthemis model rural road cycle was used to simulate the vehicle model. The simulation results show that engine with engine capacity 999 cm3 reported the economical performances of the engine and the emission and the control of engine cycle parameters.
Mouriño, Viviana; Cattalini, Juan Pablo; Boccaccini, Aldo R.
2012-01-01
This article provides an overview on the application of metallic ions in the fields of regenerative medicine and tissue engineering, focusing on their therapeutic applications and the need to design strategies for controlling the release of loaded ions from biomaterial scaffolds. A detailed summary of relevant metallic ions with potential use in tissue engineering approaches is presented. Remaining challenges in the field and directions for future research efforts with focus on the key variables needed to be taken into account when considering the controlled release of metallic ions in tissue engineering therapeutics are also highlighted. PMID:22158843
2002-12-21
This image of a xenon ion engine, photographed through a port of the vacuum chamber where it was being tested at NASA's Jet Propulsion Laboratory, shows the faint blue glow of charged atoms being emitted from the engine. The ion propulsion engine is the first non-chemical propulsion to be used as the primary means of propelling a spacecraft. Though the thrust of the ion propulsion is about the same as the downward pressure of a single sheet of paper, by the end of the mission, the ion engine will have changed the spacecraft speed by about 13,700 kilometers/hour (8500 miles/hour). Even then, it will have expended only about 64 kg of its 81.5 kg supply of xenon propellant. http://photojournal.jpl.nasa.gov/catalog/PIA04247
Test bed ion engine development
NASA Technical Reports Server (NTRS)
Aston, G.; Deininger, W. D.
1984-01-01
A test bed ion (TBI) engine was developed to serve as a tool in exploring the limits of electrostatic ion thruster performance. A description of three key ion engine components, the decoupled extraction and amplified current (DE-AC) accelerator system, field enhanced refractory metal (FERM) hollow cathode and divergent line cusp (DLC) discharge chamber, whose designs and operating philosophies differ markedly from conventional thruster technology is given. Significant program achievements were: (1) high current density DE-AC accelerator system operation at low electric field stress with indicated feasibility of a 60 mA/sq cm argon ion beam; (2) reliable FERM cathode start up times of 1 to 2 secs. and demonstrated 35 ampere emission levels; (3) DLC discharge chamber plasma potentials negative of anode potential; and (4) identification of an efficient high plasma density engine operating mode. Using the performance projections of this program and reasonable estimates of other parameter values, a 1.0 Newton thrust ion engine is identified as a realizable technology goal. Calculations show that such an engine, comparable in beam area to a J series 30 cm thruster, could, operating on Xe or Hg, have thruster efficiencies as high as 0.76 and 0.78 respectively, with a 100 eV/ion discharge loss.
Gold dendrites Co-deposited with M13 virus as a biosensor platform for nitrite ions.
Seo, Yeji; Manivannan, Shanmugam; Kang, Inhak; Lee, Seung-Wuk; Kim, Kyuwon
2017-08-15
We developed a biosensor for nitrite ion on an electrode surface modified with M13 viruses and gold nanostructures. Gold dendritic nanostructures (Au-DNs) are electrochemically co-deposited from 4E peptides engineered M13 virus (M13 4E ) mixed electrolyte on to the ITO electrode. The M13 4E could specifically nucleate Au precursor (Gold (III) chloride), which enable the efficient growth of dendritic nanostructures, whereas such dendritic structures were not obtained in the presence of wild-type and Y3E peptides engineered M13 viruses. The structural features of the Au-DNs and their interfacing mechanism with ITO electrode are characterized by SEM, EDX and XRD analyses. The growth of Au-DNs at ITO electrode has been monitored by time dependent SEM study. The M13 4E induces the formation and plays a crucial role in shaping the dendritic morphology for Au. Biosensor electrode was constructed using Au-DNs modified electrode for nitrite ions and found improved sensitivity relative to the sensor electrode prepared from wild-type M13, Y3E peptides engineered M13 and without M13. Sensor electrode exhibited good selectivity toward target analyte from the possible interferences. Furthermore, 4E native peptides were used as additive to deposit Au nanostructures and it is compared with the structure and reactivity of the Au nanostructures prepared in the presence of M13 4E . Our novel biosensor fabrication can be extended to other metal and metal oxide nanostructures and its application might be useful to develop novel biosensor electrode for variety of biomolecules. Copyright © 2017 Elsevier B.V. All rights reserved.
Status of the NEXT Ion Engine Wear Test
NASA Technical Reports Server (NTRS)
Soulas, George C.; Domonkos, Matthew T.; Kamhawi, Hani; Patterson, Michael J.; Gardner, Michael M.
2003-01-01
The status of the NEXT 2000 hour wear test is presented. This test is being conducted with a 40 cm engineering model ion engine, designated EM1, at a beam current higher than listed on the NEXT throttle table. Pretest performance assessments demonstrated that EM1 satisfies all thruster performance requirements. As of 7/3/03, the ion engine has accumulated 406 hours of operation at a thruster input power of 6.9 kW. Overall ion engine performance, which includes thrust, thruster input power, specific impulse, and thrust efficiency, has been steady to date with no indications of performance degradation. Images of the downstream discharge cathode, neutralizer, and accelerator aperture surfaces have exhibited no significant erosion to date.
Three-grid accelerator system for an ion propulsion engine
NASA Technical Reports Server (NTRS)
Brophy, John R. (Inventor)
1994-01-01
An apparatus is presented for an ion engine comprising a three-grid accelerator system with the decelerator grid biased negative of the beam plasma. This arrangement substantially reduces the charge-exchange ion current reaching the accelerator grid at high tank pressures, which minimizes erosion of the accelerator grid due to charge exchange ion sputtering, known to be the major accelerator grid wear mechanism. An improved method for life testing ion engines is also provided using the disclosed apparatus. In addition, the invention can also be applied in materials processing.
1992-10-27
AD-A27O 238 T Of DTIC ELECTE 8OCT 06 1993 E O F F ICE OF THE 1NSPECTOR GENERAL QUICK REAC.7ION REPORT ON THE AUDIT OF THE ARMY CONTRACT WITH THE...ENGINEERING INSPECTOR GENERAL, DEPARTMENT OF TH, ARMY SUBJECT: Quick-Reaction Report on the Audit of the Army Contract with the University of Texas at Austin...comments on Recommendation 3. by November 27, 1992. The courtesies extended to the audit staff are appreciated. If you have any questions on this final
Development of the Engineering Test Satellite-3 (ETS-3) ion engine system
NASA Technical Reports Server (NTRS)
Kitamura, S.
1984-01-01
The ion engine system onboard the ETS-3 is discussed. The system consists of two electron bombardment type mercury ion engines with 2 mN thrust and 2,000 sec specific impulse and a power conditioner with automatic control functions. The research and development of the system, development of its EM, PM and FM, the system test and the technical achievements leading up to final launch are discussed.
Power processor for a 20CM ion thruster
NASA Technical Reports Server (NTRS)
Biess, J. J.; Schoenfeld, A. D.; Cohen, E.
1973-01-01
A power processor breadboard for the JPL 20CM Ion Engine was designed, fabricated, and tested to determine compliance with the electrical specification. The power processor breadboard used the silicon-controlled rectifier (SCR) series resonant inverter as the basic power stage to process all the power to the ion engine. The breadboard power processor was integrated with the JPL 20CM ion engine and complete testing was performed. The integration tests were performed without any silicon-controlled rectifier failure. This demonstrated the ruggedness of the series resonant inverter in protecting the switching elements during arcing in the ion engine. A method of fault clearing the ion engine and returning back to normal operation without elaborate sequencing and timing control logic was evolved. In this method, the main vaporizer was turned off and the discharge current limit was reduced when an overload existed on the screen/accelerator supply. After the high voltage returned to normal, both the main vaporizer and the discharge were returned to normal.
The History of Ion Chromatography: The Engineering Perspective
ERIC Educational Resources Information Center
Evans, Barton
2004-01-01
The development of ion chromatography from an engineering perspective is presented. As ion chromatography became more widely accepted, researchers developed dozens of standard applications that enabled the creation of many low-end instruments.
Single-ion quantum Otto engine with always-on bath interaction
NASA Astrophysics Data System (ADS)
Chand, Suman; Biswas, Asoka
2017-06-01
We demonstrate how the reciprocating heat cycle of a quantum Otto engine (QOE) can be implemented using a single ion and an always-on thermal environment. The internal degree of freedom of the ion is chosen as the working fluid, while the motional degree of freedom can be used as the cold bath. We show, that by adiabatically changing the local magnetic field, the work efficiency can be asymptotically made unity. We propose a projective measurement of the internal state of the ion that mimics the release of heat from the working fluid during the engine cycle. In our proposal, the coupling to the hot and the cold baths need not be switched off and on in an alternate fashion during the engine cycle, unlike other existing proposals of QOE. This renders the proposal experimentally feasible using the available tapped-ion engineering technology.
Tong, Liping; Zhou, Wenhua; Zhao, Yuetao; Yu, Xuefeng; Wang, Huaiyu; Chu, Paul K
2016-12-01
Polydimethylsiloxane(PDMS) is a common industrial polymer with advantages such as ease of fabrication, tunable hardness, and other desirable properties, but the basic (-OSi(CH 3 ) 2 -) n structure in PDMS is inherently hydrophobic thereby hampering application to biomedical engineering. In this study, plasma immersion ion implantation (PIII) is conducted on PDMS to improve the biological properties. PIII forms wrinkled "herringbone" patterns and abundant O-containing functional groups on PDMS to alter the surface hydrophilicity. The biocompatibility of the modified PDMS is assessed with Chinese hamster ovarian cells and compared to that of the untreated PDMS. Our results reveal that the PDMS samples after undergoing PIII have better cytocompatibility and lower genotoxicity. PIII which is a non-line-of-sight technique extends the application of PDMS to the biomedical field. Copyright © 2016 Elsevier B.V. All rights reserved.
Spatiotemporal pH dynamics in concentration polarization near ion-selective membranes.
Andersen, Mathias B; Rogers, David M; Mai, Junyu; Schudel, Benjamin; Hatch, Anson V; Rempe, Susan B; Mani, Ali
2014-07-08
We present a detailed analysis of the transient pH dynamics for a weak, buffered electrolyte subject to voltage-driven transport through an ion-selective membrane. We show that pH fronts emanate from the concentration polarization zone next to the membrane and that these propagating fronts change the pH in the system several units from its equilibrium value. The analysis is based on a 1D model using the unsteady Poisson-Nernst-Planck equations with nonequilibrium chemistry and without assumptions of electroneutrality or asymptotically thin electric double layers. Nonequilibrium chemical effects, especially for water splitting, are shown to be important for the dynamical and spatiotemporal evolution of the pH fronts. Nonetheless, the model also shows that at steady state the assumption of chemical equilibrium can still lead to good approximations of the global pH distribution. Moreover, our model shows that the transport of the hydronium ion in the extended space charge region is governed by a balance between electromigration and water self-ionization. On the basis of this observation, we present a simple model showing that the net flux of the hydronium ion is proportional to the length of the extended space charge region and the water self-ionization rate. To demonstrate these effects in practice, we have adopted the experiment of Mai et al. (Mai, J.; Miller, H.; Hatch, A. V. Spatiotemporal Mapping of Concentration Polarization Induced pH Changes at Nanoconstrictions. ACS Nano 2012, 6, 10206) as a model problem, and by including the full chemistry and transport, we show that the present model can capture the experimentally observed pH fronts. Our model can, among other things, be used to predict and engineer pH dynamics, which can be essential to the performance of membrane-based systems for biochemical separation and analysis.
Convert Ten Foot Environmental Test Chamber into an Ion Engine Test Chamber
NASA Technical Reports Server (NTRS)
VanVelzer, Paul
2006-01-01
The 10 Foot Space Simulator at the Jet Propulsion Laboratory has been used for the last 40 years to test numerous spacecraft, including the Ranger series, several Mariner class, among many others and finally, the Spirit and Opportunity Mars Rovers. The request was made to convert this facility to an Ion Engine test facility, with a possible long term life test. The Ion engine was to propel the Prometheus spacecraft to Jupiter's moons. This paper discusses the challenges that were met, both from a procedural and physical standpoint. The converted facility must operate unattended, support a 30 Kw Ion Engine, operate economically, and be easily converted back to former operation as a spacecraft test facility.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Bulanov, S. V.; A. M. Prokhorov Institute of General Physics RAS, Moscow, 119991; Esirkepov, T. Zh.
When ions are accelerated by the radiation pressure of a laser pulse, their velocity cannot exceed the pulse group velocity which can be considerably smaller than the speed of light in vacuum. This is demonstrated in two cases corresponding to a thin foil target irradiated by high intensity laser light and to the hole boring produced in an extended plasma by the laser pulse. It is found that the beams of accelerated ions are unstable against Buneman-like and Weibel-like instabilities which results in the broadening of the ion energy spectrum.
Flight evaluation of an extended engine life mode on an F-15 airplane
NASA Technical Reports Server (NTRS)
Myers, Lawrence P.; Conners, Timothy R.
1992-01-01
An integrated flight and propulsion control system designed to reduce the rate of engine deterioration was developed and evaluated in flight on the NASA Dryden F-15 research aircraft. The extended engine life mode increases engine pressure ratio while reducing engine airflow to lower the turbine temperature at constant thrust. The engine pressure ratio uptrim is modulated in real time based on airplane maneuver requirements, flight conditions, and engine information. The extended engine life mode logic performed well, significantly reducing turbine operating temperature. Reductions in fan turbine inlet temperature of up to 80 F were obtained at intermediate power and up to 170 F at maximum augmented power with no appreciable loss in thrust. A secondary benefit was the considerable reduction in thrust-specific fuel consumption. The success of the extended engine life mode is one example of the advantages gained from integrating aircraft flight and propulsion control systems.
A Segmented Ion-Propulsion Engine
NASA Technical Reports Server (NTRS)
Brophy, John R.
1992-01-01
New design approach for high-power (100-kW class or greater) ion engines conceptually divides single engine into combination of smaller discharge chambers integrated to operate as single large engine. Analogous to multicylinder automobile engine, benefits include reduction in required accelerator system span-to-gap ratio for large-area engines, reduction in required hollow-cathode emission current, mitigation of plasma-uniformity problem, increased tolerance to accelerator system faults, and reduction in vacuum-system pumping speed.
NASA Technical Reports Server (NTRS)
Sellen, J. M., Jr.; Kemp, R. F.; Hall, D. F.
1973-01-01
The analysis of ion exhaust beam current flow for multiply charged ion species and the application to propellant utilization for the thruster are discussed. The ion engine in use in the experiments is a twenty centimeter diameter electromagnet electron bombardment engine. The experimental technique to determine the multiply charged ion abundance ratios using ion time of flight is described. An analytical treatment of the discharge action in producing various ion species has been carried out.
2007-07-22
KENNEDY SPACE CENTER, FLA. — Sitting on a transporter, the Dawn spacecraft arrives at the Astrotech payload processing facility. Dawn was returned from Launch Pad 17-B at Cape Canaveral Air Force Station to Astrotech to await a new launch date. The launch opportunity extends from Sept. 7 to Oct. 15. Dawn is the ninth mission in NASA's Discovery Program. The spacecraft will be the first to orbit two planetary bodies, asteroid Vesta and dwarf planet Ceres, during a single mission. Vesta and Ceres lie in the asteroid belt between Mars and Jupiter. It is also NASA’s first purely scientific mission powered by three solar electric ion propulsion engines. NASA/Charisse Nahser
2007-07-22
KENNEDY SPACE CENTER, FLA. — The Dawn spacecraft is moved inside the Astrotech payload processing facility. Dawn was returned from Launch Pad 17-B at Cape Canaveral Air Force Station to Astrotech to await a new launch date. The launch opportunity extends from Sept. 7 to Oct. 15. Dawn is the ninth mission in NASA's Discovery Program. The spacecraft will be the first to orbit two planetary bodies, asteroid Vesta and dwarf planet Ceres, during a single mission. Vesta and Ceres lie in the asteroid belt between Mars and Jupiter. It is also NASA’s first purely scientific mission powered by three solar electric ion propulsion engines. NASA/Charisse Nahser
A 2.5 kW advanced technology ion thruster
NASA Technical Reports Server (NTRS)
Poeschel, R. L.
1974-01-01
A program has been conducted in order to improve the performance characteristics of 30 cm thrusters. This program was divided into three distinct, but related tasks: (1) the discharge chamber and component design modifications proposed for inclusion in the engineering model thruster were evaluated and engineering specifications were verified; (2) thrust losses which result from the contributions of double charged ions and nonaxial ion trajectories to the ion beam current were measured and (3) the specification and verification of power processor and control requirements of the engineering model thruster design were demonstrated. Proven design modifications which provide improved efficiencies are incorporated into the engineering model thruster during a structural re-design without introducing additional delay in schedule or new risks. In addition, a considerable amount of data is generated on the relation of double ion production and beam divergence to thruster parameters. Overall thruster efficiency is increased from 68% to 71% at full power, including corrections for double ion and beam divergence thrust losses.
1998-09-30
KENNEDY SPACE CENTER, FLA. -- Deep Space 1 rests on its work platform after being fitted with thermal insulation. The reflective insulation is designed to protect the spacecraft as this side faces the sun. At either side of the spacecraft are its solar wings, folded for launch. When fully extended, the wings measure 38.6 feet from tip to tip. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century. Onboard experiments include a solar-powered ion propulsion engine and software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. The ion propulsion engine is the first non-chemical propulsion to be used as the primary means of propelling a spacecraft. Deep Space 1 will complete most of its mission objectives within the first two months, but may also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched aboard a Boeing Delta 7326 rocket from Launch Pad 17A, Cape Canaveral Air Station, in October. Delta II rockets are medium capacity expendable launch vehicles derived from the Delta family of rockets built and launched since 1960. Since then there have been more than 245 Delta launches
Deep Space 1 moves to CCAS for testing
NASA Technical Reports Server (NTRS)
1998-01-01
Workers in the Payload Hazardous Servicing Facility lower Deep Space 1 onto its transporter, for movement to the Defense Satellite Communications System Processing Facility (DPF), Cape Canaveral Air Station, where it will undergo testing. At either side of the spacecraft are its solar wings, folded for launch. When fully extended, the wings measure 38.6 feet from tip to tip. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century. Onboard experiments include a solar-powered ion propulsion engine and software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. The ion propulsion engine is the first non-chemical propulsion to be used as the primary means of propelling a spacecraft. Deep Space 1 will complete most of its mission objectives within the first two months, but may also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched aboard a Boeing Delta 7326 rocket from Launch Pad 17A, Cape Canaveral Air Station, in October. Delta II rockets are medium capacity expendable launch vehicles derived from the Delta family of rockets built and launched since 1960. Since then there have been more than 245 Delta launches.
1998-09-30
KENNEDY SPACE CENTER, FLA. -- Workers in the Payload Hazardous Servicing Facility lower Deep Space 1 onto its transporter, for movement to the Defense Satellite Communications System Processing Facility (DPF), Cape Canaveral Air Station, where it will undergo testing. At either side of the spacecraft are its solar wings, folded for launch. When fully extended, the wings measure 38.6 feet from tip to tip. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century. Onboard experiments include a solar-powered ion propulsion engine and software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. The ion propulsion engine is the first non-chemical propulsion to be used as the primary means of propelling a spacecraft. Deep Space 1 will complete most of its mission objectives within the first two months, but may also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched aboard a Boeing Delta 7326 rocket from Launch Pad 17A, Cape Canaveral Air Station, in October. Delta II rockets are medium capacity expendable launch vehicles derived from the Delta family of rockets built and launched since 1960. Since then there have been more than 245 Delta launches
1998-09-30
KENNEDY SPACE CENTER, FLA. -- Deep Space 1 rests on its work platform after being fitted with thermal insulation. The dark insulation is designed to protect the side of the spacecraft that faces away from the sun. At either side of the spacecraft are its solar wings, folded for launch. When fully extended, the wings measure 38.6 feet from tip to tip. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century. Onboard experiments include a solar-powered ion propulsion engine and software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. The ion propulsion engine is the first non-chemical propulsion to be used as the primary means of propelling a spacecraft. Deep Space 1 will complete most of its mission objectives within the first two months, but may also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched aboard a Boeing Delta 7326 rocket from Launch Pad 17A, Cape Canaveral Air Station, in October. Delta II rockets are medium capacity expendable launch vehicles derived from the Delta family of rockets built and launched since 1960. Since then there have been more than 245 Delta launches
Ion Engine Grid Gap Measurements
NASA Technical Reports Server (NTRS)
Soulas, Gerge C.; Frandina, Michael M.
2004-01-01
A simple technique for measuring the grid gap of an ion engine s ion optics during startup and steady-state operation was demonstrated with beam extraction. The grid gap at the center of the ion optics assembly was measured with a long distance microscope that was focused onto an alumina pin that protruded through the center accelerator grid aperture and was mechanically attached to the screen grid. This measurement technique was successfully applied to a 30 cm titanium ion optics assembly mounted onto an NSTAR engineering model ion engine. The grid gap and each grid s movement during startup from room temperature to both full and low power were measured. The grid gaps with and without beam extraction were found to be significantly different. The grid gaps at the ion optics center were both significantly smaller than the cold grid gap and different at the two power levels examined. To avoid issues associated with a small grid gap during thruster startup with titanium ion optics, a simple method was to operate the thruster initially without beam extraction to heat the ion optics. Another possible method is to apply high voltage to the grids prior to igniting the discharge because power deposition to the grids from the plasma is lower with beam extraction than without. Further testing would be required to confirm this approach.
Federal Register 2010, 2011, 2012, 2013, 2014
2013-09-24
... Operations (ETOPS) of Multi-Engine Airplanes AGENCY: Federal Aviation Administration (FAA), DOT. ACTION... Number: 2120-0718 Title: Extended Operations (ETOPS) of Multi-Engine Airplanes Form Numbers: There are no... operate two-engine airplanes over these long-range routes and extended the procedures for extended...
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zheng, Yiqun; Luo, Ming; Tao, Jing
We report our observation of changes to the crystallinity or morphology during seed-mediated growth of Au nanocrystals. When single-crystal Au seeds with a spherical or rod-like shape were treated with a chemical species such as S₂O₃²⁻ ions, twin defects were developed during the growth process to generate multiply twinned nanostructures. X-ray photoelectron spectroscopy analysis indicated that the S₂O₃²⁻ ions were chemisorbed on the surfaces of the seeds during the treatment. The chemisorbed S₂O₃²⁻ ions somehow influenced the crystallization of Au atoms added onto the surface during a growth process, leading to the formation of twin defects. In contrast to themore » spherical and rod-like Au seeds, the single-crystal structure was retained to generate a concave morphology when single-crystal Au seeds with a cubic or octahedral shape were used for a similar treatment and then seed-mediated growth. The different outcomes are likely related to the difference in spatial distribution of S₂O₃²⁻ ions chemisorbed on the surface of a seed. This approach based on surface modification is potentially extendable to other noble metals for engineering the crystallinity and morphology of nanocrystals formed via seed-mediated growth.« less
NASA Astrophysics Data System (ADS)
Pfammatter, Sibylle; Bonneil, Eric; McManus, Francis P.; Thibault, Pierre
2018-04-01
The small ubiquitin-like modifier (SUMO) is a member of the family of ubiquitin-like modifiers (UBLs) and is involved in important cellular processes, including DNA damage response, meiosis and cellular trafficking. The large-scale identification of SUMO peptides in a site-specific manner is challenging not only because of the low abundance and dynamic nature of this modification, but also due to the branched structure of the corresponding peptides that further complicate their identification using conventional search engines. Here, we exploited the unusual structure of SUMO peptides to facilitate their separation by high-field asymmetric waveform ion mobility spectrometry (FAIMS) and increase the coverage of SUMO proteome analysis. Upon trypsin digestion, branched peptides contain a SUMO remnant side chain and predominantly form triply protonated ions that facilitate their gas-phase separation using FAIMS. We evaluated the mobility characteristics of synthetic SUMO peptides and further demonstrated the application of FAIMS to profile the changes in protein SUMOylation of HEK293 cells following heat shock, a condition known to affect this modification. FAIMS typically provided a 10-fold improvement of detection limit of SUMO peptides, and enabled a 36% increase in SUMO proteome coverage compared to the same LC-MS/MS analyses performed without FAIMS. [Figure not available: see fulltext.
Zheng, Yiqun; Luo, Ming; Tao, Jing; ...
2014-12-11
We report our observation of changes to the crystallinity or morphology during seed-mediated growth of Au nanocrystals. When single-crystal Au seeds with a spherical or rod-like shape were treated with a chemical species such as S₂O₃²⁻ ions, twin defects were developed during the growth process to generate multiply twinned nanostructures. X-ray photoelectron spectroscopy analysis indicated that the S₂O₃²⁻ ions were chemisorbed on the surfaces of the seeds during the treatment. The chemisorbed S₂O₃²⁻ ions somehow influenced the crystallization of Au atoms added onto the surface during a growth process, leading to the formation of twin defects. In contrast to themore » spherical and rod-like Au seeds, the single-crystal structure was retained to generate a concave morphology when single-crystal Au seeds with a cubic or octahedral shape were used for a similar treatment and then seed-mediated growth. The different outcomes are likely related to the difference in spatial distribution of S₂O₃²⁻ ions chemisorbed on the surface of a seed. This approach based on surface modification is potentially extendable to other noble metals for engineering the crystallinity and morphology of nanocrystals formed via seed-mediated growth.« less
NASA Technical Reports Server (NTRS)
VanNoord, Jonathan L.; Soulas, George C.; Sovey, James S.
2010-01-01
The results of the NEXT wear test are presented. This test was conducted with a 36-cm ion engine (designated PM1R) and an engineering model propellant management system. The thruster operated with beam extraction for a total of 1680 hr and processed 30.5 kg of xenon during the wear test, which included performance testing and some operation with an engineering model power processing unit. A total of 1312 hr was accumulated at full power, 277 hr at low power, and the remainder was at intermediate throttle levels. Overall ion engine performance, which includes thrust, thruster input power, specific impulse, and thrust efficiency, was steady with no indications of performance degradation. The propellant management system performed without incident during the wear test. The ion engine and propellant management system were also inspected following the test with no indication of anomalous hardware degradation from operation.
Purification/annealing of graphene with 100-MeV Ag ion irradiation
2014-01-01
Studies on interaction of graphene with radiation are important because of nanolithographic processes in graphene-based electronic devices and for space applications. Since the electronic properties of graphene are highly sensitive to the defects and number of layers in graphene sample, it is desirable to develop tools to engineer these two parameters. We report swift heavy ion (SHI) irradiation-induced annealing and purification effects in graphene films, similar to that observed in our studies on fullerenes and carbon nanotubes (CNTs). Raman studies after irradiation with 100-MeV Ag ions (fluences from 3 × 1010 to 1 × 1014 ions/cm2) show that the disorder parameter α, defined by ID/IG ratio, decreases at lower fluences but increases at higher fluences beyond 1 × 1012 ions/cm2. This indicates that SHI induces annealing effects at lower fluences. We also observe that the number of graphene layers is reduced at fluences higher than 1 × 1013 ions/cm2. Using inelastic thermal spike model calculations, we estimate a radius of 2.6 nm for ion track core surrounded by a halo extending up to 11.6 nm. The transient temperature above the melting point in the track core results in damage, whereas lower temperature in the track halo is responsible for annealing. The results suggest that SHI irradiation fluence may be used as one of the tools for defect annealing and manipulation of the number of graphene layers. PACS 60.80.x; 81.05.ue PMID:24636520
Current Density Measurements of an Annular-Geometry Ion Engine
NASA Technical Reports Server (NTRS)
Shastry, Rohit; Patterson, Michael J.; Herman, Daniel A.; Foster, John E.
2012-01-01
The concept of the annular-geometry ion engine, or AGI-Engine, has been shown to have many potential benefits when scaling electric propulsion technologies to higher power. However, the necessary asymmetric location of the discharge cathode away from thruster centerline could potentially lead to non-uniformities in the discharge not present in conventional geometry ion thrusters. In an effort to characterize the degree of this potential nonuniformity, a number of current density measurements were taken on a breadboard AGI-Engine. Fourteen button probes were used to measure the ion current density of the discharge along a perforated electrode that replaced the ion optics during conditions of simulated beam extraction. Three Faraday probes spaced apart in the vertical direction were also used in a separate test to interrogate the plume of the AGI-Engine during true beam extraction. It was determined that both the discharge and the plume of the AGI-Engine are highly uniform, with variations under most conditions limited to 10% of the average current density in the discharge and 5% of the average current density in the plume. Beam flatness parameter measured 30 mm from the ion optics ranged from 0.85 0.95, and overall uniformity was shown to generally increase with increasing discharge and beam currents. These measurements indicate that the plasma is highly uniform despite the asymmetric location of the discharge cathode.
Current Density Measurements of an Annular-Geometry Ion Engine
NASA Technical Reports Server (NTRS)
Shastry, Rohit; Patterson, Michael J.; Herman, Daniel A.; Foster, John E.
2012-01-01
The concept of the annular-geometry ion engine, or AGI-Engine, has been shown to have many potential benefits when scaling electric propulsion technologies to higher power. However, the necessary asymmetric location of the discharge cathode away from thruster centerline could potentially lead to non-uniformities in the discharge not present in conventional geometry ion thrusters. In an effort to characterize the degree of this potential non-uniformity, a number of current density measurements were taken on a breadboard AGI-Engine. Fourteen button probes were used to measure the ion current density of the discharge along a perforated electrode that replaced the ion optics during conditions of simulated beam extraction. Three Faraday probes spaced apart in the vertical direction were also used in a separate test to interrogate the plume of the AGI-Engine during true beam extraction. It was determined that both the discharge and the plume of the AGI-Engine are highly uniform, with variations under most conditions limited to +/-10% of the average current density in the discharge and +/-5% of the average current density in the plume. Beam flatness parameter measured 30 mm from the ion optics ranged from 0.85 - 0.95, and overall uniformity was shown to generally increase with increasing discharge and beam currents. These measurements indicate that the plasma is highly uniform despite the asymmetric location of the discharge cathode.
NASA Astrophysics Data System (ADS)
Marjani, Azam
2016-07-01
For biomolecules and cell particles purification and separation in biological engineering, besides the chromatography as mostly applied process, aqueous two-phase systems (ATPS) are of the most favorable separation processes that are worth to be investigated in thermodynamic theoretically. In recent years, thermodynamic calculation of ATPS properties has attracted much attention due to their great applications in chemical industries such as separation processes. These phase calculations of ATPS have inherent complexity due to the presence of ions and polymers in aqueous solution. In this work, for target ternary systems of polyethylene glycol (PEG4000)-salt-water, thermodynamic investigation for constituent systems with three salts (NaCl, KCl and LiCl) has been carried out as PEG is the most favorable polymer in ATPS. The modified perturbed hard sphere chain (PHSC) equation of state (EOS), extended Debye-Hückel and Pitzer models were employed for calculation of activity coefficients for the considered systems. Four additional statistical parameters were considered to ensure the consistency of correlations and introduced as objective functions in the particle swarm optimization algorithm. The results showed desirable agreement to the available experimental data, and the order of recommendation of studied models is PHSC EOS > extended Debye-Hückel > Pitzer. The concluding remark is that the all the employed models are reliable in such calculations and can be used for thermodynamic correlation/predictions; however, by using an ion-based parameter calculation method, the PHSC EOS reveals both reliability and universality of applications.
Amorphization resistance of nano-engineered SiC under heavy ion irradiation
NASA Astrophysics Data System (ADS)
Imada, Kenta; Ishimaru, Manabu; Xue, Haizhou; Zhang, Yanwen; Shannon, Steven C.; Weber, William J.
2016-09-01
Silicon carbide (SiC) with a high-density of planar defects (hereafter, 'nano-engineered SiC') and epitaxially-grown single-crystalline 3C-SiC were simultaneously irradiated with Au ions at room temperature, in order to compare their relative resistance to radiation-induced amorphization. It was found that the local threshold dose for amorphization is comparable for both samples under 2 MeV Au ion irradiation; whereas, nano-engineered SiC exhibits slightly greater radiation tolerance than single crystalline SiC under 10 MeV Au irradiation. Under 10 MeV Au ion irradiation, the dose for amorphization increased by about a factor of two in both nano-engineered and single crystal SiC due to the local increase in electronic energy loss that enhanced dynamic recovery.
NASA Technical Reports Server (NTRS)
Mahalingam, Sudhakar; Menart, James A.
2005-01-01
Computational modeling of the plasma located in the discharge chamber of an ion engine is an important activity so that the development and design of the next generation of ion engines may be enhanced. In this work a computational tool called XOOPIC is used to model the primary electrons, secondary electrons, and ions inside the discharge chamber. The details of this computational tool are discussed in this paper. Preliminary results from XOOPIC are presented. The results presented include particle number density distributions for the primary electrons, the secondary electrons, and the ions. In addition the total number of a particular particle in the discharge chamber as a function of time, electric potential maps and magnetic field maps are presented. A primary electron number density plot from PRIMA is given in this paper so that the results of XOOPIC can be compared to it. PRIMA is a computer code that the present investigators have used in much of their previous work that provides results that compare well to experimental results. PRIMA only models the primary electrons in the discharge chamber. Modeling ions and secondary electrons, as well as the primary electrons, will greatly increase our ability to predict different characteristics of the plasma discharge used in an ion engine.
SMART-1: the first spacecraft of the future
NASA Astrophysics Data System (ADS)
2003-09-01
This is the first of a series of missions designed to test key technologies for future spacecraft —SMART stands for 'Small Missions for Advanced Research and Technology'. In the case of SMART-1, the two main new technologies to be tested are a new 'solar-electric propulsion' system and miniaturised spacecraft and instrumentation. Together, these technologies make up a spacecraft with revolutionary qualities: smaller, lighter, capable of carrying more scientific instruments, greater fuel efficiency. All of which also considerably reduces the cost of the mission. So, the idea behind SMART-1 is to pioneer a futuristic philosophy, the motto of which could be: 'more science for less money'. Even though it is the first of a kind, SMART-1 has been developed in less than four years, and at about a fifth of the cost of a major science mission for ESA: only 110 million euros. That includes the launch, the operations and a dozen scientific experiments. This was achieved partly by using new management methods — such as working with smaller teams both within ESA and in the industry — and partly because of some of the new features inherent in SMART-1, such as the miniaturisation and novel design. Giuseppe Racca, SMART-1 Project Manager, explains: "What has been our trick? First, a short development period in itself means less money. But also, with its small size — which was a requirement of the mission because we are testing miniaturised hardware — the spacecraft is able to 'share' a commercial Ariane flight with two other passengers. Besides, since we were not constrained by any existing design or heritage, we could be more innovative and elegant in our architecture. For example, the new SMART-1 electrical architecture has enabled us to simplify the system tests considerably." SMART-1 could almost be a toy spacecraft — it weighs only 367 kilograms and fits into a cube just one metre across (the solar panel wings extend about 14 metres) — although one able to gather high-value scientific and technological data. Another innovation lies in the industrial policy applied to this mission. SMART-1 is a good example of an ESA mission in which a comparatively small company such as the Swedish Space Corporation (SSC) has been selected as prime contractor. “The experience of SSC in highly successful projects at national level was a key factor in the decision, as was ESA's goal of fostering a balanced industrial landscape in Europe,” says Niels Jensen of ESA’s Directorate of Industrial Matters and Technology Programmes. The magic of ion engines Solar-electric propulsion, one of the main technologies to be tested by SMART-1, is a new technique that uses 'ion engines'. These work by expelling a continuous beam of charged particles --ions-- at the back of the engine, which produces a thrust in the opposite direction and therefore pushes the spacecraft forward. The energy to feed the engine comes from the solar panels, hence the name 'solar-electric propulsion'. Engineers have been working on ion engines for decades, but only recently have obstacles such as the lack of power availability from a spacecraft’s solar panels been overcome. Recent missions have been using ion thrusters mainly for attitude control and orbit station keeping. In the recent case of ESA’s telecommunication satellite Artemis, the onboard availability of ion thrusters was actually what allowed the mission to be rescued. Having been left by the launcher on an unplanned orbit, Artemis was slowly - but safely - brought up to its final working orbit by the power of its ion engines, initially designed for orbit maintenance only. Starting with SMART-1, the first European spacecraft to use an ion engine as its main propulsion system, the amazing advantages of this method can now be fully exploited. Ion engines are very efficient: they deliver about ten times as much impulse per kilogram of propellant used. This gives a substantial reduction in the mass of the fuel carried on the spacecraft, which in turn leaves more room — more weight — for scientific instrumentation. Also, ion engines allow scope for designing trajectories to travel very long distances in less time, thereby opening the door to deeper space exploration. Another advantage is that these engines make for very accurate spacecraft control, which is essential for missions that require highly precise target pointing. Such qualities stem from the fact that ion engines generate a very gentle thrust. SMART-1 will be accelerated just 0.2 millimetres per second per second, with a push equivalent to the weight of a postcard. This is why solar-electric propulsion cannot be used for taking off from Earth, for example; it only works in the vacuum of space. For very distant destinations, this is not a problem. Compared to conventional chemical rockets, which burn for a few minutes, ion engines work for years, or for as long as the solar panels keep providing electricity. So the ion ‘tortoise’ will eventually overtake the chemical ‘hare’. Long, energy-demanding interplanetary missions will benefit most from solar-electric primary propulsion. In such cases, spacecraft need an enormous amount of chemical fuel on board, leaving very little capacity for scientific instruments. Moreover, to make the most economical use of this fuel, they need to take maximum advantage of gravity-assist manoeuvres, making space journeys longer and more complex. With solar-electric propulsion, in contrast, much less fuel is needed on board, with the advantages of more room for instruments and the ability to avoid complex gravity-assist manoeuvres. But these advantages do not come into play on short distances, such as from the Earth to the Moon. So why is SMART-1 testing its ion engine on a trip to the Moon? The answer is threefold. First, the Moon is a very interesting scientific target. Secondly, SMART-1 has the opportunity to share the cost of an Ariane-5 launch with other passengers heading for the geostationary transfer orbit (GTO), from which the Moon can be reached. Last but not least, the spiral orbit which SMART-1 has to take to reach the Moon from GTO is a long and complex trajectory, so that the ion engine will be fully tested in conditions representative of a deep-space mission. Good news for the whole space sector The technology to be tested on SMART-1 is a strategic investment for ESA. In particular, development of the solar-electric propulsion technology was followed by ESA directly. The experience gained with SMART-1 will be useful to many aspects of space technology, providing thorough groundwork for future ESA programmes. As ESA engineer Denis Estublier explains, "SMART-1 will provide answers to technological questions that affect the whole sector. It will demonstrate the use and the lifetime in space of electric thrusters; the ground control of a quasi-continuously thrusting satellite, the performance of the solar panels in the radiation belts; the interactions of the ion beam with the spacecraft surface and instruments." Many kinds of spacecraft, including commercial telecommunication satellites, will benefit from such technology. Ion engines will find an immediate application in future ESA scientific missions to distant destinations that could not be reached otherwise, as conventional chemical-propulsion spacecraft could not carry the required payload mass. Other scientific missions will have to rely completely on the accurate spacecraft control provided by the very gentle thrust of the ion engines. SMART-1’s journey starts on Saturday 27 September at 08.02 p.m. local time in Kourou (Sunday 28 September at 01:02 a.m. CEST) with a launch an Ariane 5 rocket from the European launch base in Kourou, French Guiana. The trip itself will be part of the adventure, with the engineers checking on the performance of the new technology. But for the scientifically curious the real thrill will begin in December 2004, when SMART-1 reaches the Moon. Then it will be the turn of the scientific instruments, which will help to solve such questions as the origin of the Moon, the existence of water on the Moon, and the possibility of building a permanent human base on the lunar surface. Note to editors SMART-1 was developed for ESA by the Swedish Space Corporation, as prime contractor, with contributions from almost 30 contractors from 11 European countries and the United States. The spacecraft carries 19 kilograms of science payload consisting of experiments led by Principal Investigators from Finland, Germany, Italy, Switzerland and the United Kingdom.
Tracking and Control of Gas Turbine Engine Component Damage/Life
NASA Technical Reports Server (NTRS)
Jaw, Link C.; Wu, Dong N.; Bryg, David J.
2003-01-01
This paper describes damage mechanisms and the methods of controlling damages to extend the on-wing life of critical gas turbine engine components. Particularly, two types of damage mechanisms are discussed: creep/rupture and thermo-mechanical fatigue. To control these damages and extend the life of engine hot-section components, we have investigated two methodologies to be implemented as additional control logic for the on-board electronic control unit. This new logic, the life-extending control (LEC), interacts with the engine control and monitoring unit and modifies the fuel flow to reduce component damages in a flight mission. The LEC methodologies were demonstrated in a real-time, hardware-in-the-loop simulation. The results show that LEC is not only a new paradigm for engine control design, but also a promising technology for extending the service life of engine components, hence reducing the life cycle cost of the engine.
Engineer Examines Cluster of Ion Engines in the Electric Propulsion Laboratory
1963-01-21
New staff member Paul Margosian inspects a cluster of ion engines in the Electric Propulsion Laboratory’s 25-foot diameter vacuum tank at the National Aeronautics and Space Administration (NASA) Lewis Research Center. Lewis researchers had been studying different methods of electric rocket propulsion since the mid-1950s. Harold Kaufman created the first successful engine, the electron bombardment ion engine, in the early 1960s. These engines used electric power to create and accelerate small particles of propellant material to high exhaust velocities. Electric engines have a very small thrust, and but can operate for long periods of time. The ion engines are often clustered together to provide higher levels of thrust. The Electric Propulsion Laboratory contained two large vacuum tanks capable of simulating the space environment. The tanks were designed especially for testing ion and plasma thrusters and spacecraft. The larger 25-foot diameter tank was intended for testing electric thrusters with condensable propellants. The tank’s test compartment, seen here, was 10 feet in diameter. Margosian joined Lewis in late 1962 during a major NASA hiring phase. The Agency reorganized in 1961 and began expanding its ranks through a massive recruiting effort. Lewis personnel increased from approximately 2,700 in 1961 to over 4,800 in 1966. Margosian, who worked with Bill Kerslake in the Electromagnetic Propulsion Division’s Propulsion Systems Section, wrote eight technical reports on mercury and electron bombardment thrusters, thermoelectrostatic generators, and a high voltage insulator.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Deng, Liulin; Webb, Ian K.; Garimella, Sandilya V. B.
Ion mobility (IM) separations have a broad range of analytical applications, but insufficient resolution limits many applications. Here we report on traveling wave (TW) ion mobility (IM) separations in a Serpentine Ultra-long Path with Extended Routing (SUPER) Structures for Lossless Ion Manipulations (SLIM) module in conjunction with mass spectrometry (MS). The extended routing utilized multiple passes was facilitated by the introduction of a lossless ion switch at the end of the ion path that either directed ions to the MS detector or to another pass through the serpentine separation region, providing theoretically unlimited TWIM path lengths. Ions were confined inmore » the SLIM by rf fields in conjunction with a DC guard bias, enabling essentially lossless TW transmission over greatly extended paths (e.g., ~1094 meters over 81 passes through the 13.5 m serpentine path). In this multi-pass SUPER TWIM provided resolution approximately proportional to the square root of the number of passes (or path length). More than 30-fold higher IM resolution for Agilent tuning mix m/z 622 and 922 ions (~340 vs. ~10) was achieved for 40 passes compared to commercially available drift tube IM and other TWIM-based platforms. An initial evaluation of the isomeric sugars Lacto-N-hexaose and Lacto-N-neohexaose showed the isomeric structures to be baseline resolved, and a new conformational feature for Lacto-N-neohexaose was revealed after 9 passes. The new SLIM SUPER high resolution TWIM platform has broad utility in conjunction with MS and is expected to enable a broad range of previously challenging or intractable separations.« less
Sun, Dan; Tang, Yougen; Ye, Delai; Yan, Jun; Zhou, Haoshen; Wang, Haiyan
2017-02-15
Morphology controllable fabrication of electrode materials is of great significance but is still a major challenge for constructing advanced Li ion batteries. Herein, we propose a novel space constraint assembly approach to tune the morphology of Mn(terephthalic acid) (PTA)-MOF, in which benzonic acid was employed as a modulator to adjust the available MOF assembly directions. As a result, Mn(PTA)-MOFs with microquadrangulars, microflakes, and spindle-like microrods morphologies have been achieved. MnO/C hybrids with preserved morphologies were further obtained by self-sacrificial and thermal transformation of Mn(PTA)-MOFs. As anodes for Li ion batteries, these morphologies showed great influence on the electrochemical properties. Owing to the abundant porous structure and unique architecture, the MnO/C spindle-like microrods demonstrated superior electrochemical properties with a high reversible capacity of 1165 mAh g -1 at 0.3 A g -1 , excellent rate capability of 580 mAh g -1 at 3 A g -1 , and no considerable capacity loss after 200 cycles at 1 A g -1 . This strategy could be extended to engineering the morphology of other MOF-derived functional materials in various structure-dependent applications.
Ion engine auxiliary propulsion applications and integration study
NASA Technical Reports Server (NTRS)
Zafran, S. (Editor)
1977-01-01
The benefits derived from application of the 8-cm mercury electron bombardment ion thruster were assessed. Two specific spacecraft missions were studied. A thruster was tested to provide additional needed information on its efflux characteristics and interactive effects. A Users Manual was then prepared describing how to integrate the thruster for auxiliary propulsion on geosynchronous satellites. By incorporating ion engines on an advanced communications mission, the weight available for added payload increases by about 82 kg (181 lb) for a 100 kg (2200 lb) satellite which otherwise uses electrothermal hydrazine. Ion engines can be integrated into a high performance propulsion module that is compatible with the multimission modular spacecraft and can be used for both geosynchronous and low earth orbit applications. The low disturbance torques introduced by the ion engines permit accurate spacecraft pointing with the payload in operation during thrusting periods. The feasibility of using the thruster's neutralizer assembly for neutralization of differentially charged spacecraft surfaces at geosynchronous altitude was demonstrated during the testing program.
Shteynberg, David; Mendoza, Luis; Hoopmann, Michael R.; Sun, Zhi; Schmidt, Frank; Deutsch, Eric W.; Moritz, Robert L.
2016-01-01
Most shotgun proteomics data analysis workflows are based on the assumption that each fragment ion spectrum is explained by a single species of peptide ion isolated by the mass spectrometer; however, in reality mass spectrometers often isolate more than one peptide ion within the window of isolation that contributes to additional peptide fragment peaks in many spectra. We present a new tool called reSpect, implemented in the Trans-Proteomic Pipeline (TPP), that enables an iterative workflow whereby fragment ion peaks explained by a peptide ion identified in one round of sequence searching or spectral library search are attenuated based on the confidence of the identification, and then the altered spectrum is subjected to further rounds of searching. The reSpect tool is not implemented as a search engine, but rather as a post search engine processing step where only fragment ion intensities are altered. This enables the application of any search engine combination in the following iterations. Thus, reSpect is compatible with all other protein sequence database search engines as well as peptide spectral library search engines that are supported by the TPP. We show that while some datasets are highly amenable to chimeric spectrum identification and lead to additional peptide identification boosts of over 30% with as many as four different peptide ions identified per spectrum, datasets with narrow precursor ion selection only benefit from such processing at the level of a few percent. We demonstrate a technique that facilitates the determination of the degree to which a dataset would benefit from chimeric spectrum analysis. The reSpect tool is free and open source, provided within the TPP and available at the TPP website. PMID:26419769
Shteynberg, David; Mendoza, Luis; Hoopmann, Michael R; Sun, Zhi; Schmidt, Frank; Deutsch, Eric W; Moritz, Robert L
2015-11-01
Most shotgun proteomics data analysis workflows are based on the assumption that each fragment ion spectrum is explained by a single species of peptide ion isolated by the mass spectrometer; however, in reality mass spectrometers often isolate more than one peptide ion within the window of isolation that contribute to additional peptide fragment peaks in many spectra. We present a new tool called reSpect, implemented in the Trans-Proteomic Pipeline (TPP), which enables an iterative workflow whereby fragment ion peaks explained by a peptide ion identified in one round of sequence searching or spectral library search are attenuated based on the confidence of the identification, and then the altered spectrum is subjected to further rounds of searching. The reSpect tool is not implemented as a search engine, but rather as a post-search engine processing step where only fragment ion intensities are altered. This enables the application of any search engine combination in the iterations that follow. Thus, reSpect is compatible with all other protein sequence database search engines as well as peptide spectral library search engines that are supported by the TPP. We show that while some datasets are highly amenable to chimeric spectrum identification and lead to additional peptide identification boosts of over 30% with as many as four different peptide ions identified per spectrum, datasets with narrow precursor ion selection only benefit from such processing at the level of a few percent. We demonstrate a technique that facilitates the determination of the degree to which a dataset would benefit from chimeric spectrum analysis. The reSpect tool is free and open source, provided within the TPP and available at the TPP website. Graphical Abstract ᅟ.
NASA Astrophysics Data System (ADS)
Shteynberg, David; Mendoza, Luis; Hoopmann, Michael R.; Sun, Zhi; Schmidt, Frank; Deutsch, Eric W.; Moritz, Robert L.
2015-11-01
Most shotgun proteomics data analysis workflows are based on the assumption that each fragment ion spectrum is explained by a single species of peptide ion isolated by the mass spectrometer; however, in reality mass spectrometers often isolate more than one peptide ion within the window of isolation that contribute to additional peptide fragment peaks in many spectra. We present a new tool called reSpect, implemented in the Trans-Proteomic Pipeline (TPP), which enables an iterative workflow whereby fragment ion peaks explained by a peptide ion identified in one round of sequence searching or spectral library search are attenuated based on the confidence of the identification, and then the altered spectrum is subjected to further rounds of searching. The reSpect tool is not implemented as a search engine, but rather as a post-search engine processing step where only fragment ion intensities are altered. This enables the application of any search engine combination in the iterations that follow. Thus, reSpect is compatible with all other protein sequence database search engines as well as peptide spectral library search engines that are supported by the TPP. We show that while some datasets are highly amenable to chimeric spectrum identification and lead to additional peptide identification boosts of over 30% with as many as four different peptide ions identified per spectrum, datasets with narrow precursor ion selection only benefit from such processing at the level of a few percent. We demonstrate a technique that facilitates the determination of the degree to which a dataset would benefit from chimeric spectrum analysis. The reSpect tool is free and open source, provided within the TPP and available at the TPP website.
Amorphization resistance of nano-engineered SiC under heavy ion irradiation
DOE Office of Scientific and Technical Information (OSTI.GOV)
Imada, Kenta; Ishimaru, Manabu; Xue, Haizhou
Silicon carbide (SiC) with a high-density of planar defects (hereafter, ‘nano-engineered SiC’) and epitaxially-grown single-crystalline 3C-SiC were simultaneously irradiated with Au ions at room temperature, in order to compare their relative resistance to radiation-induced amorphization. Furthermore, it was found that the local threshold dose for amorphization is comparable for both samples under 2 MeV Au ion irradiation; whereas, nano-engineered SiC exhibits slightly greater radiation tolerance than single crystalline SiC under 10 MeV Au irradiation. Under 10 MeV Au ion irradiation, the dose for amorphization increased by about a factor of two in both nano-engineered and single crystal SiC due tomore » the local increase in electronic energy loss that enhanced dynamic recovery.« less
Amorphization resistance of nano-engineered SiC under heavy ion irradiation
Imada, Kenta; Ishimaru, Manabu; Xue, Haizhou; ...
2016-06-19
Silicon carbide (SiC) with a high-density of planar defects (hereafter, ‘nano-engineered SiC’) and epitaxially-grown single-crystalline 3C-SiC were simultaneously irradiated with Au ions at room temperature, in order to compare their relative resistance to radiation-induced amorphization. Furthermore, it was found that the local threshold dose for amorphization is comparable for both samples under 2 MeV Au ion irradiation; whereas, nano-engineered SiC exhibits slightly greater radiation tolerance than single crystalline SiC under 10 MeV Au irradiation. Under 10 MeV Au ion irradiation, the dose for amorphization increased by about a factor of two in both nano-engineered and single crystal SiC due tomore » the local increase in electronic energy loss that enhanced dynamic recovery.« less
NASA Astrophysics Data System (ADS)
Suzuki, Kunihiro
2009-04-01
Ion implantation profiles are expressed by the Pearson function with first, second, third, and fourth moment parameters of Rp, ΔRp, γ, and β. We derived an analytical model for these profile moments by solving a Lindhard-Scharf-Schiott (LSS) integration equation using perturbation approximation. This analytical model reproduces Monte Carlo data that were well calibrated to reproduce a vast experimental database. The extended LSS theory is vital for instantaneously predicting ion implantation profiles with any combination of incident ions and substrate atoms including their energy dependence.
2007-07-22
KENNEDY SPACE CENTER, FLA. — On Pad 17-B at Cape Canaveral Air Force Station, the Dawn spacecraft is safely secured on a transporter for its trip to Astrotech. Dawn is being returned to the Astrotech payload processing facility to await a new launch date. The launch opportunity extends from Sept. 7 to Oct. 15. Dawn is the ninth mission in NASA's Discovery Program. The spacecraft will be the first to orbit two planetary bodies, asteroid Vesta and dwarf planet Ceres, during a single mission. Vesta and Ceres lie in the asteroid belt between Mars and Jupiter. It is also NASA’s first purely scientific mission powered by three solar electric ion propulsion engines. NASA/George Shelton
2007-07-22
KENNEDY SPACE CENTER, FLA. — On Pad 17-B at Cape Canaveral Air Force Station, the Dawn spacecraft is lowered from the mobile service tower to the ground. Dawn is being returned to the Astrotech payload processing facility to await a new launch date. The launch opportunity extends from Sept. 7 to Oct. 15. Dawn is the ninth mission in NASA's Discovery Program. The spacecraft will be the first to orbit two planetary bodies, asteroid Vesta and dwarf planet Ceres, during a single mission. Vesta and Ceres lie in the asteroid belt between Mars and Jupiter. It is also NASA’s first purely scientific mission powered by three solar electric ion propulsion engines. NASA/George Shelton
2007-07-22
KENNEDY SPACE CENTER, FLA. — On Pad 17-B at Cape Canaveral Air Force Station, the Dawn spacecraft is lowered from the mobile service tower to the ground. Dawn is being returned to the Astrotech payload processing facility to await a new launch date. The launch opportunity extends from Sept. 7 to Oct. 15. Dawn is the ninth mission in NASA's Discovery Program. The spacecraft will be the first to orbit two planetary bodies, asteroid Vesta and dwarf planet Ceres, during a single mission. Vesta and Ceres lie in the asteroid belt between Mars and Jupiter. It is also NASA’s first purely scientific mission powered by three solar electric ion propulsion engines. NASA/George Shelton
NASA Technical Reports Server (NTRS)
Gershman, D.J.; Block, B.P.; Rubin, M.; Benna, M.; Mahaffy, P. R.; Zurbuchen, T. H.
2012-01-01
This work applies higher order auxiliary excitation techniques to two types of quadrupole mass spectrometers (QMSs): commercial systems and spaceborne instruments. The operational settings of a circular rod geometry commercial system and an engineering test-bed for a hyperbolic rod geometry spaceborne instrument were matched, with the relative performance of each sensor characterized with and without applied excitation using isotopic measurements of Kr+. Each instrument was operated at the limit of the test electronics to determine the effect of auxiliary excitation on extending instrument capabilities. For the circular rod sensor, with applied excitation, a doubling of the mass resolution at 1% of peak transmission resulted from the elimination of the low-mass side peak tail typical of such rod geometries. The mass peak stability and ion rejection efficiency were also increased by factors of 2 and 10, respectively, with voltage scan lines passing through the center of stability islands formed from auxiliary excitation. Auxiliary excitation also resulted in factors of 6 and 2 in peak stability and ion rejection efficiency, respectively, for the hyperbolic rod sensor. These results not only have significant implications for the use of circular rod quadrupoles with applied excitation as a suitable replacement for traditional hyperbolic rod sensors, but also for extending the capabilities of existing hyperbolic rod QMSs for the next generation of spaceborne instruments and low-mass commercial systems.
NASA Astrophysics Data System (ADS)
Conde, L.; Domenech-Garret, J. L.; Donoso, J. M.; Damba, J.; Tierno, S. P.; Alamillo-Gamboa, E.; Castillo, M. A.
2017-12-01
The characteristics of supersonic ion beams from the alternative low power hybrid ion engine (ALPHIE) are discussed. This simple concept of a DC powered plasma accelerator that only needs one electron source for both neutral gas ionization and ion beam neutralization is also examined. The plasma production and space charge neutralization processes are thus coupled in this plasma thruster that has a total DC power consumption of below 450 W, and uses xenon or argon gas as a propellant. The operation parameters of the plasma engine are studied in the laboratory in connection with the ion energy distribution function obtained with a retarding-field energy analyzer. The ALPHIE plasma beam expansion produces a mesothermal plasma flow with two-peaked ion energy distribution functions composed of low and high speed ion groups. The characteristic drift velocities of the fast ion groups, in the range 36.6-43.5 Km/s, are controlled by the acceleration voltage. These supersonic speeds are higher than the typical ion sound velocities of the low energy ion group produced by the expansion of the plasma jet. The temperatures of the slow ion population lead to ion Debye lengths longer than the electron Debye lengths. Furthermore, the electron impact ionization can coexist with collisional ionization by fast ions downstream the grids. Finally, the performance characteristics and comparisons with other plasma accelerator schemes are also discussed.
Graphene engineering by neon ion beams
Iberi, Vighter; Ievlev, Anton V.; Vlassiouk, Ivan; ...
2016-02-18
Achieving the ultimate limits of materials and device performance necessitates the engineering of matter with atomic, molecular, and mesoscale fidelity. While common for organic and macromolecular chemistry, these capabilities are virtually absent for 2D materials. In contrast to the undesired effect of ion implantation from focused ion beam (FIB) lithography with gallium ions, and proximity effects in standard e-beam lithography techniques, the shorter mean free path and interaction volumes of helium and neon ions offer a new route for clean, resist free nanofabrication. Furthermore, with the advent of scanning helium ion microscopy, maskless He + and Ne + beam lithographymore » of graphene based nanoelectronics is coming to the forefront. Here, we will discuss the use of energetic Ne ions in engineering graphene devices and explore the mechanical, electromechanical and chemical properties of the ion-milled devices using scanning probe microscopy (SPM). By using SPM-based techniques such as band excitation (BE) force modulation microscopy, Kelvin probe force microscopy (KPFM) and Raman spectroscopy, we demonstrate that the mechanical, electrical and optical properties of the exact same devices can be quantitatively extracted. Additionally, the effect of defects inherent in ion beam direct-write lithography, on the overall performance of the fabricated devices is elucidated.« less
Generic comparison of protein inference engines.
Claassen, Manfred; Reiter, Lukas; Hengartner, Michael O; Buhmann, Joachim M; Aebersold, Ruedi
2012-04-01
Protein identifications, instead of peptide-spectrum matches, constitute the biologically relevant result of shotgun proteomics studies. How to appropriately infer and report protein identifications has triggered a still ongoing debate. This debate has so far suffered from the lack of appropriate performance measures that allow us to objectively assess protein inference approaches. This study describes an intuitive, generic and yet formal performance measure and demonstrates how it enables experimentalists to select an optimal protein inference strategy for a given collection of fragment ion spectra. We applied the performance measure to systematically explore the benefit of excluding possibly unreliable protein identifications, such as single-hit wonders. Therefore, we defined a family of protein inference engines by extending a simple inference engine by thousands of pruning variants, each excluding a different specified set of possibly unreliable identifications. We benchmarked these protein inference engines on several data sets representing different proteomes and mass spectrometry platforms. Optimally performing inference engines retained all high confidence spectral evidence, without posterior exclusion of any type of protein identifications. Despite the diversity of studied data sets consistently supporting this rule, other data sets might behave differently. In order to ensure maximal reliable proteome coverage for data sets arising in other studies we advocate abstaining from rigid protein inference rules, such as exclusion of single-hit wonders, and instead consider several protein inference approaches and assess these with respect to the presented performance measure in the specific application context.
NASA Technical Reports Server (NTRS)
Beattie, J. R.
1983-01-01
An investigation of short term measurement techniques for predicting the wearout of ion thrusters resulting from sputter erosion damage is described. The previously established laminar thin film techniques to provide high precision erosion rate data. However, the erosion rates obtained using this technique are generally substantially higher than those obtained during long term endurance tests (by virtue of the as deposited nature of the thin films), so that the results must be interpreted in a relative sense. Absolute measurements can be performed using a new masked substrate arrangement which was developed during this study. This new technique provides a means for estimating the lifetimes of critical discharge chamber components based on direct measurements of sputter erosion depths obtained during short duration (10 hour) tests. The method enables the effects on lifetime of thruster design and operating parameters to be inferred without the investment of the time and capital required to conduct long term (1000 hour) endurance tests. Results obtained using the direct measurement technique are shown to agree with sputter erosion depths calculated for the plasma conditions of the test and also with lifetest results. The direct measurement approach is shown to be applicable to both mercury and argon discharge plasma environments and should be useful in estimating the lifetimes of inert gas and extended performance mercury ion thrusters presently under development.
NASA Technical Reports Server (NTRS)
Soulas, George C.; Patterson, Michael J.; Herman, Daniel A.
2009-01-01
The NASA s Evolutionary Xenon Thruster (NEXT) program is developing the next-generation ion propulsion system with significant enhancements beyond the state-of-the-art in ion propulsion to provide future NASA science missions with enhanced mission capabilities at a low total development cost. As part of a comprehensive thruster service life assessment utilizing both testing and analyses, a Long-Duration Test (LDT) was initiated to verify the NEXT propellant throughput capability to a qualification-level of 450 kg, 1.5 times the anticipated throughput requirement of 300 kg from mission analyses conducted utilizing the NEXT propulsion system. The LDT is being conducted with a modified, flight-representative NEXT engineering model ion thruster, designated EM3. As of June 25, 2008, the thruster has accumulated 16,550 h of operation: the first 13,042 h at the thruster full-input-power of 6.9 kW with 3.52 A beam current and 1800 V beam power supply voltage. Operation since 13,042 h, i.e., the most recent 3,508 h, has been at an input power of 4.7 kW with 3.52 A beam current and 1180 V beam power supply voltage. The thruster has processed 337 kg of xenon (Xe) surpassing the NSTAR propellant throughput demonstrated during the extended life testing of the Deep Space 1 flight spare ion thruster. The NEXT LDT has demonstrated a total impulse of 13.3 106 N s; the highest total impulse ever demonstrated by an ion thruster. Thruster performance tests are conducted periodically over the entire NEXT throttle table with input power ranging 0.5 to 6.9 kW. Thruster performance parameters including thrust, input power, specific impulse, and thruster efficiency have been nominal with little variation to date. This paper presents the performance of the NEXT LDT to date with emphasis on performance variations following throttling of the thruster to the new operating condition and comparison of performance to the NSTAR extended life test.
Ultralow-power switching via defect engineering in germanium telluride phase-change memory devices.
Nukala, Pavan; Lin, Chia-Chun; Composto, Russell; Agarwal, Ritesh
2016-01-25
Crystal-amorphous transformation achieved via the melt-quench pathway in phase-change memory involves fundamentally inefficient energy conversion events; and this translates to large switching current densities, responsible for chemical segregation and device degradation. Alternatively, introducing defects in the crystalline phase can engineer carrier localization effects enhancing carrier-lattice coupling; and this can efficiently extract work required to introduce bond distortions necessary for amorphization from input electrical energy. Here, by pre-inducing extended defects and thus carrier localization effects in crystalline GeTe via high-energy ion irradiation, we show tremendous improvement in amorphization current densities (0.13-0.6 MA cm(-2)) compared with the melt-quench strategy (∼50 MA cm(-2)). We show scaling behaviour and good reversibility on these devices, and explore several intermediate resistance states that are accessible during both amorphization and recrystallization pathways. Existence of multiple resistance states, along with ultralow-power switching and scaling capabilities, makes this approach promising in context of low-power memory and neuromorphic computation.
Ultralow-power switching via defect engineering in germanium telluride phase-change memory devices
Nukala, Pavan; Lin, Chia-Chun; Composto, Russell; Agarwal, Ritesh
2016-01-01
Crystal–amorphous transformation achieved via the melt-quench pathway in phase-change memory involves fundamentally inefficient energy conversion events; and this translates to large switching current densities, responsible for chemical segregation and device degradation. Alternatively, introducing defects in the crystalline phase can engineer carrier localization effects enhancing carrier–lattice coupling; and this can efficiently extract work required to introduce bond distortions necessary for amorphization from input electrical energy. Here, by pre-inducing extended defects and thus carrier localization effects in crystalline GeTe via high-energy ion irradiation, we show tremendous improvement in amorphization current densities (0.13–0.6 MA cm−2) compared with the melt-quench strategy (∼50 MA cm−2). We show scaling behaviour and good reversibility on these devices, and explore several intermediate resistance states that are accessible during both amorphization and recrystallization pathways. Existence of multiple resistance states, along with ultralow-power switching and scaling capabilities, makes this approach promising in context of low-power memory and neuromorphic computation. PMID:26805748
The Ion Propulsion System on NASA's Space Technology 4/Champollion Comet Rendezvous Mission
NASA Technical Reports Server (NTRS)
Brophy, John R.; Garner, Charles E.; Weiss, Jeffery M.
1999-01-01
The ST4/Champollion mission is designed to rendezvous with and land on the comet Tempel 1 and return data from the first-ever sampling of a comet surface. Ion propulsion is an enabling technology for this mission. The ion propulsion system on ST4 consists of three ion engines each essentially identical to the single engine that flew on the DS1 spacecraft. The ST4 propulsion system will operate at a maximum input power of 7.5 kW (3.4 times greater than that demonstrated on DS1), will produce a maximum thrust of 276 mN, and will provide a total (Delta)V of 11.4 km/s. To accomplish this the propulsion system will carry 385 kg of xenon. All three engines will be operated simultaneously for the first 168 days of the mission. The nominal mission requires that each engine be capable of processing 118 kg. If one engine fails after 168 days, the remaining two engines can perform the mission, but must be capable of processing 160 kg of xenon, or twice the original thruster design requirement. Detailed analyses of the thruster wear-out failure modes coupled with experience from long-duration engine tests indicate that the thrusters have a high probability of meeting the 160-kg throughput requirement.
NREL Kicks Off Next Phase of Advanced Computer-Aided Battery Engineering |
lithium-ion (Li-ion) batteries, known as a multi-scale multi-domain (GH-MSMD) model framework, was News | NREL Kicks Off Next Phase of Advanced Computer-Aided Battery Engineering NREL Kicks Off Next Phase of Advanced Computer-Aided Battery Engineering March 16, 2016 NREL researcher looks across
Ion Engine Plume Interaction Calculations for Prototypical Prometheus 1
NASA Technical Reports Server (NTRS)
Mandell, Myron J.; Kuharski, Robert A.; Gardner, Barbara M.; Katz, Ira; Randolph, Tom; Dougherty, Ryan; Ferguson, Dale C.
2005-01-01
Prometheus 1 is a conceptual mission to demonstrate the use of atomic energy for distant space missions. The hypothetical spacecraft design considered in this paper calls for multiple ion thrusters, each with considerably higher beam energy and beam current than have previously flown in space. The engineering challenges posed by such powerful thrusters relate not only to the thrusters themselves, but also to designing the spacecraft to avoid potentially deleterious effects of the thruster plumes. Accommodation of these thrusters requires good prediction of the highest angle portions of the main beam, as well as knowledge of clastically scattered and charge exchange ions, predictions for grid erosion and contamination of surfaces by eroded grid material, and effects of the plasma plume on radio transmissions. Nonlinear interactions of multiple thrusters are also of concern. In this paper we describe two- and three-dimensional calculations for plume structure and effects of conceptual Prometheus 1 ion engines. Many of the techniques used have been validated by application to ground test data for the NSTAR and NEXT ion engines. Predictions for plume structure and possible sputtering and contamination effects will be presented.
Power processor for a 30cm ion thruster
NASA Technical Reports Server (NTRS)
Biess, J. J.; Inouye, L. Y.
1974-01-01
A thermal vacuum power processor for the NASA Lewis 30cm Mercury Ion Engine was designed, fabricated and tested to determine compliance with electrical specifications. The power processor breadboard used the silicon controlled rectifier (SCR) series resonant inverter as the basic power stage to process all the power to an ion engine. The power processor includes a digital interface unit to process all input commands and internal telemetry signals so that operation is compatible with a central computer system. The breadboard was tested in a thermal vacuum environment. Integration tests were performed with the ion engine and demonstrate operational compatibility and reliable operation without any component failures. Electromagnetic interference data were also recorded on the design to provide information on the interaction with total spacecraft.
2016-01-01
release; distribution is unlimited. 1 1. Introduction Lithium (Li)- ion batteries are currently one of the leading energy storage device technologies...ARL-TR-7584 ● JAN 2016 US Army Research Laboratory Grain Boundary Engineering of Lithium - Ion - Conducting Lithium Lanthanum...Titanate for Lithium -Air Batteries by Victoria L Blair, Claire V Weiss Brennan, and Joseph M Marsico Approved for public
Interior of Vacuum Tank at the Electric Propulsion Laboratory
1961-08-21
Interior of the 20-foot diameter vacuum tank at the NASA Lewis Research Center’s Electric Propulsion Laboratory. Lewis researchers had been studying different electric rocket propulsion methods since the mid-1950s. Harold Kaufman created the first successful ion engine, the electron bombardment ion engine, in the early 1960s. These engines used electric power to create and accelerate small particles of propellant material to high exhaust velocities. Electric engines have a very small thrust, but can operate for long periods of time. The ion engines are often clustered together to provide higher levels of thrust. The Electric Propulsion Laboratory, which began operation in 1961, contained two large vacuum tanks capable of simulating a space environment. The tanks were designed especially for testing ion and plasma thrusters and spacecraft. The larger 25-foot diameter tank included a 10-foot diameter test compartment to test electric thrusters with condensable propellants. The portals along the chamber floor lead to the massive exhauster equipment that pumped out the air to simulate the low pressures found in space.
Organic positive ions in aircraft gas-turbine engine exhaust
NASA Astrophysics Data System (ADS)
Sorokin, Andrey; Arnold, Frank
Volatile organic compounds (VOCs) represent a significant fraction of atmospheric aerosol. However the role of organic species emitted by aircraft (as a consequence of the incomplete combustion of fuel in the engine) in nucleation of new volatile particles still remains rather speculative and requires a much more detailed analysis of the underlying mechanisms. Measurements in aircraft exhaust plumes have shown the presence of both different non-methane VOCs (e.g. PartEmis project) and numerous organic cluster ions (MPIK-Heidelberg). However the link between detected organic gas-phase species and measured mass spectrum of cluster ions is uncertain. Unfortunately, up to now there are no models describing the thermodynamics of the formation of primary organic cluster ions in the exhaust of aircraft engines. The aim of this work is to present first results of such a model development. The model includes the block of thermodynamic data based on proton affinities and gas basicities of organic molecules and the block of non-equilibrium kinetics of the cluster ions evolution in the exhaust. The model predicts important features of the measured spectrum of positive ions in the exhaust behind aircraft. It is shown that positive ions emitted by aircraft engines into the atmosphere mostly consist of protonated and hydrated organic cluster ions. The developed model may be explored also in aerosol investigations of the background atmosphere as well as in the analysis of the emission of fine aerosol particles by automobiles.
NASA Technical Reports Server (NTRS)
Aston, Graeme; Brophy, John R.
1987-01-01
Results from a series of experiments to determine the effect of accelerator grid mount geometry on the performance of the J-series ion optics assembly are described. Three mounting schemes, two flexible and one rigid, are compared for their relative ion extraction capability over a range of total accelerating voltages. The largest ion beam current, for the maximum total voltage investigated, is shown to occur using one of the flexible grid mounting geometries. However, at lower total voltages and reduced engine input power levels, the original rigid J-series ion optics accelerator grid mounts result in marginally better grid system performance at the same cold interelectrode gap.
Closeup side view of Space Shuttle Main Engine (SSME) 2059 ...
Close-up side view of Space Shuttle Main Engine (SSME) 2059 mounted in a SSME Engine Handler near the Drying Area in the High Bay section of the SSME Processing Facility. The prominent features of the SSME in this view are the hot-gas expansion nozzle extending from the approximate image center toward the image right. The main-engine components extend from the approximate image center toward image right until it meets up with the mount for the SSME Engine Handler. The engine is rotated to a position where the major components in the view are the Low-Pressure Fuel Turbopump Discharge Duct with reflective foil insulation on the upper side of the engine, the Low-Pressure Oxidizer Turbopump and its Discharge Duct on the right side of the engine assembly extending itself down and wrapping under the bottom side of the assembly to the High-Pressure Oxidizer Turbopump pump. The High-Pressure Oxidizer Turbopump Discharge Duct exists the turbopump and extends up to the top side of the assembly where it enters the main oxidizer valve. The sphere on the lower side of the engine assembly is an accumulator that is part of the SSMEs POGO suppression system. - Space Transportation System, Space Shuttle Main Engine, Lyndon B. Johnson Space Center, 2101 NASA Parkway, Houston, Harris County, TX
DOE Office of Scientific and Technical Information (OSTI.GOV)
Deng, Liulin; Ibrahim, Yehia M.; Garimella, Sandilya V. B.
The initial use of traveling waves (TW) for ion mobility (IM) separations using a structures for lossless ion manipulations (SLIM) employed an ion funnel trap (IFT) to accumulate ions from a continuous electrospray ionization source, and limited to injected ion populations of ~106 charges due to the onset of space charge effects in the trapping region. Additional limitations arise due to the loss of resolution for the injection of ions over longer periods (e.g. in extended pulses). In this work a new SLIM ‘flat funnel’ (FF) module has been developed and demonstrated to enable the accumulation of much larger ionmore » populations and their injection for IM separations. Ion current measurements indicate a capacity of ~3.2×108 charges for the extended trapping volume, over an order of magnitude greater than the IFT. The orthogonal ion injection into a funnel shaped separation region can greatly reduce space charge effects during the initial IM separation stage, and the gradually reduced width of the path allows the ion packet to be increasingly compressed in the lateral dimension as the separation progresses, allowing e.g. efficient transmission through conductance limits or compatibility with subsequent ion manipulations. This work examined the TW, RF, and DC confining field SLIM parameters involved in ion accumulation, injection, transmission and separation in the FF IM module using both direct ion current and MS measurements. Wide m/z range ion transmission is demonstrated, along with significant increases in signal to noise (S/N) ratios due to the larger ion populations injected. Additionally, we observed a reduction in the chemical background, which was attributed to more efficient desolvation of solvent related clusters over the extended ion accumulation periods. The TW SLIM FF IM module is anticipated to be especially effective as a front end for long path SLIM IM separation modules.« less
The Successful Conclusion of the Deep Space 1 Mission: Important Results without a Flashy Title
NASA Astrophysics Data System (ADS)
Rayman, Marc D.
2002-01-01
Conceived in 1995, Deep Space 1 (DS1) was the first mission of NASA s New Millennium program. Its purpose was to test high-risk, advanced technologies important for space and Earth science missions. DS1 s payload included ion propulsion, solar concentrator arrays, autonomous navigation and other autonomous systems, miniaturized telecommunications and microelectronic systems, and two highly integrated, compact science instruments. DS1 was launched in October 1998, only 39 months after the initial concept study began, and during its 11-month primary mission it exceeded its requirements. All technologies were rigorously exercised and characterized, thus reducing the cost and risk of subsequent science missions that could consider taking advantage of the capabilities offered by these new systems. Following its primary mission, DS1 embarked on an extended mission devoted to comet science, although it had not been designed for a comet encounter. Less than two months after the beginning of the extended mission, the spacecraft suffered a critical failure with the loss of its star tracker, its only source of 3-axis attitude knowledge. Although this was initially considered to be a catastrophic failure, the project completed an ambitious two-phase, seven-month recovery that included the development of extensive new software and new operations procedures. In September 2001, the spacecraft flawlessly completed a high-risk encounter with comet 19P/Borrelly. Using the two instruments included on the flight for technology tests as well as reprogrammed sensors originally intended for monitoring the effects of the ion propulsion system on the space environment, DS1 returned a rich harvest of data, with panchromatic images, infrared spectra, energy and angle distributions of electron and ion fluxes, ion compositions, and magnetic field and plasma wave measurements. These data constitute the most detailed view of a comet and offer surprising and exciting insights. In addition to the direct scientific return, the comet encounter is of engineering value to other missions planning comet encounters. With the successful conclusion of its extended mission, DS1 undertook a hyperextended mission. This phase of its flight was dedicated to final testing of the advanced technologies on board. With the mission at more than three times its planned lifetime, this offered an excellent opportunity to obtain unplanned data on the effects of long-term operation in space. All nine of the hardware technologies were used during the hyperextended mission, with a focus on the ion propulsion system. Following this period of extremely aggressive testing, with no further technology or science objectives, the mission was terminated on December 18, 2001, with the powering off of the spacecraft s transmitter, although the receiver was left on. By the end of its mission, DS1 had returned a wealth of important science data and engineering data for future missions. It did so following the shortest time from pre-phase A through launch of any NASA interplanetary mission in the modern era and the lowest cost of any NASA interplanetary mission ever conducted (measured in same year dollars, including the launch cost). This paper will describe the encounter with comet Borrelly, the hyperextended mission, and summarize the overall results of the Deep Space 1 project.
NASA Astrophysics Data System (ADS)
Jadan, M.; Chelyadinskii, A. R.; Odzhaev, V. B.
2013-02-01
The possibility to control the localization of implanted carbon in sites and interstices in silicon immediately during the implantation has been demonstrated. The formation of residual extended defects in silicon implanted separately with C+ and B+ ions and jointly with C+ and B+ ions has been shown. It has been found that the formation of residual defects can be suppressed due to annihilation of point defects at C atoms (the Watkins effect). The positive effect is attained if implanted carbon is localized over lattice sites, which is provided by its implantation with the effective current density of the scanning ion beam no lower than 1.0 μA cm-2.
2007-07-22
KENNEDY SPACE CENTER, FLA. — At the Astrotech payload processing facility, workers guide the movement of the upper canister being lifted from the Dawn spacecraft, seen encased in a protective cover. Dawn was returned from Launch Pad 17-B at Cape Canaveral Air Force Station to Astrotech to await a new launch date. The launch opportunity extends from Sept. 7 to Oct. 15. Dawn is the ninth mission in NASA's Discovery Program. The spacecraft will be the first to orbit two planetary bodies, asteroid Vesta and dwarf planet Ceres, during a single mission. Vesta and Ceres lie in the asteroid belt between Mars and Jupiter. It is also NASA’s first purely scientific mission powered by three solar electric ion propulsion engines. NASA/Charisse Nahser
Electrofluidics in Micro/Nanofluidic Systems
NASA Astrophysics Data System (ADS)
Guan, Weihua
This work presents the efforts to study the electrofluidics, with a focus on the electric field - matter interactions in microfluidic and nanofluidic systems for lab-on-a-chip applications. The field of electrofluidics integrates the multidisciplinary knowledge in silicon technology, solid and soft condensed matter physics, fluidics, electrochemistry, and electronics. The fundamental understanding of electrofluidics in engineered micro and nano structures opens up wide opportunities for biomedical sensing and actuation devices integrated on a single chip. Using spatial and temporal properties of electric fields in top-down engineered micro/nana structures, we successfully demonstrated the precise control over a single macro-ion and a collective group of ions in aqueous solutions. In the manipulation of a single macro-ion, we revisited the long-time overlooked AC electrophoretic (ACEP) phenomena. We proved that the widely held notion of vanishing electrophoretic (EP) effects in AC fields does not apply to spatially non-uniform electric fields. In contrast to dielectrophoretic (DEP) traps, ACEP traps favor the downscaling of the particle size if it is sufficiently charged. We experimentally demonstrated the predicted ACEP trap by recognizing that the ACEP dynamics is equivalent to that of Paul traps working in an aqueous solution. Since all Paul traps realized so far have only been operated in vacuum or gaseous phase, our experimental effort represents the world's first aqueous Paul trap device. In the manipulation of a collective group of ions, we demonstrated that the ion transport in nanochannels can be directly gated by DC electric fields, an impossible property in microscale geometries. Successful fabrication techniques were developed to create the nanochannel structures with gating ability. Using the gated nanochannel structures, we demonstrated a field effect reconfigurable nanofluidic diode, whose forward/reverse direction as well as the rectification degree can be significantly modulated. We also demonstrated a solid-state protocell, whose ion selectivity and membrane potential can be modulated by external electric field. Moreover, by recognizing the key role played by the surface charge density in electrofluidic gating of nanochannels, a low-cost, off-chip extended gate field effect transistor (FET) structure to measure the surface charges at the dielectric-electrolyte interface is demonstrated. This technique simplifies and accelerates the process of dielectric selection for effective electrofluidic gating.
Long pulse operation of the Kamaboko negative ion source on the MANTIS test bed
DOE Office of Scientific and Technical Information (OSTI.GOV)
Tramham, R.; Jacquot, C.; Riz, D.
1998-08-20
Advanced Tokamak concepts and steady state plasma scenarios require external plasma heating and current drive for extended time periods. This poses several problems for the neutral beam injection systems that are currently in use. The power loading of the ion source and accelerator are especially problematic. The Kamaboko negative ion source, a small scale model of the ITER arc source, is being prepared for extended operation of deuterium beams for up to 1000 seconds. The operating conditions of the plasma grid prove to be important for reducing electron power loading of the accelerator. Operation of deuterium beams for extended periodsmore » also poses radiation safety risks which must be addressed.« less
NASA Technical Reports Server (NTRS)
Kawaguchi, Jun'ichiro; Kominato, Takashi; Shirakawa, Ken'ichi
2007-01-01
The paper presents the attitude reorientation taking the advantage of solar radiation pressure without use of any fuel aboard. The strategy had been adopted to make Hayabusa spacecraft keep pointed toward the Sun for several months, while spinning. The paper adds the above mentioned results reported in Sedona this February showing another challenge of combining ion engines propulsion tactically balanced with the solar radiation torque with no spin motion. The operation has been performed since this March for a half year successfully. The flight results are presented with the estimated solar array panel diffusion coefficient and the ion engine's swirl torque.
Derated ion thruster design issues
NASA Technical Reports Server (NTRS)
Patterson, Michael J.; Rawlin, Vincent K.
1991-01-01
Preliminary activities to develop and refine a lightweight 30 cm engineering model ion thruster are discussed. The approach is to develop a 'derated' ion thruster capable of performing both auxiliary and primary propulsion roles over an input power range of at least 0.5 to 5.0 kilo-W. Design modifications to a baseline thruster to reduce mass and volume are discussed. Performance data over an order of magnitude input power range are presented, with emphasis on the performance impact of engine throttling. Thruster design modifications to optimize performance over specific power envelopes are discussed. Additionally, lifetime estimates based on wear test measurements are made for the operation envelope of the engine.
Deep Space 1 Ion Engine Completed a 3-Year Journey
NASA Technical Reports Server (NTRS)
Sovey, James S.; Patterson, Michael J.; Rawlin, Vincent K.; Hamley, John A.
2001-01-01
A xenon ion engine and power processor system, which was developed by the NASA Glenn Research Center in partnership with the Jet Propulsion Laboratory and Boeing Electron Dynamic Devices, completed nearly 3 years of operation aboard the Deep Space 1 spacecraft. The 2.3-kW ion engine, which provided primary propulsion and two-axis attitude control, thrusted for more than 16,000 hr and consumed more than 70 kg of xenon propellant. The Deep Space 1 spacecraft was launched on October 24, 1998, to validate 12 futuristic technologies, including the ion-propulsion system. After the technology validation process was successfully completed, the Deep Space 1 spacecraft flew by the small asteroid Braille on July 29, 1999. The final objective of this mission was to encounter the active comet Borrelly, which is about 6 miles long. The ion engine was on a thrusting schedule to navigate the Deep Space 1 spacecraft to within 1400 miles of the comet. Since the hydrazine used for spacecraft attitude control was in short supply, the ion engine also provided two-axis attitude control to conserve the hydrazine supply for the Borrelly encounter. The comet encounter took place on September 22, 2001. Dr. Marc Rayman, project manager of Deep Space 1 at the Jet Propulsion Laboratory said, "Deep Space 1 plunged into the heart of the comet Borrelly and has lived to tell every detail of its spinetingling adventure! The images are even better than the impressive images of comet Halley taken by Europe's Giotto spacecraft in 1986." The Deep Space 1 mission, which successfully tested the 12 high-risk, advanced technologies and captured the best images ever taken of a comet, was voluntarily terminated on December 18, 2001. The successful demonstration of the 2-kW-class ion propulsion system technology is now providing mission planners with off-the-shelf flight hardware. Higher power, next generation ion propulsion systems are being developed for large flagship missions, such as outer planet explorers and sample-return missions.
Ehlers, K.W.; Voelker, F. III
1961-12-19
A thrust generating engine utilizing cesium vapor as the propellant fuel is designed. The cesium is vaporized by heat and is passed through a heated porous tungsten electrode whereby each cesium atom is fonized. Upon emergfng from the tungsten electrode, the ions are accelerated rearwardly from the rocket through an electric field between the tungsten electrode and an adjacent accelerating electrode grid structure. To avoid creating a large negative charge on the space craft as a result of the expulsion of the positive ions, a source of electrons is disposed adjacent the ion stream to neutralize the cesium atoms following acceleration thereof. (AEC)
Status of Real-Time Laser Based Ion Engine Diagnostics at NASA Glenn Research Center
NASA Technical Reports Server (NTRS)
Domonkos, Matthew T.; Williams, George J., Jr.
2001-01-01
The development status of laser based erosion diagnostics for ion engines at the NASA Glenn Research Center is discussed. The diagnostics are being developed to enhance component life-prediction capabilities. A direct measurement of the erosion product density using laser induced fluorescence (LIF) is described. Erosion diagnostics based upon evaluation of the ion dynamics are also under development, and the basic approach is presented. The planned implementation of the diagnostics is discussed.
State of Charge estimation of lithium ion battery based on extended Kalman filtering algorithm
NASA Astrophysics Data System (ADS)
Yang, Fan; Feng, Yiming; Pan, Binbiao; Wan, Renzhuo; Wang, Jun
2017-08-01
Accurate estimation of state-of-charge (SOC) for lithium ion battery is crucial for real-time diagnosis and prognosis in green energy vehicles. In this paper, a state space model of the battery based on Thevenin model is adopted. The strategy of estimating state of charge (SOC) based on extended Kalman fil-ter is presented, as well as to combine with ampere-hour counting (AH) and open circuit voltage (OCV) methods. The comparison between simulation and experiments indicates that the model’s performance matches well with that of lithium ion battery. The algorithm of extended Kalman filter keeps a good accura-cy precision and less dependent on its initial value in full range of SOC, which is proved to be suitable for online SOC estimation.
Deep Space 1 moves to CCAS for testing
NASA Technical Reports Server (NTRS)
1998-01-01
After covering the bulk of Deep Space 1 in thermal insulating blankets, workers in the Payload Hazardous Servicing Facility lift it from its work platform before moving it onto its transporter (behind workers at left). Deep Space 1 is being moved to the Defense Satellite Communications System Processing Facility (DPF), Cape Canaveral Air Station, for testing. At either side of the spacecraft are its solar wings, folded for launch. When fully extended, the winds measure 38.6 feet from tip to tip. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century. Onboard experiments include a solar-powered ion propulsion engine and software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. The ion propulsion engine is the first non-chemical propulsion to be used as the primary means of propelling a spacecraft. Deep Space 1 will complete most of its mission objectives within the first two months, but may also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched aboard a Boeing Delta 7326 rocket from Launch Pad 17A, Cape Canaveral Air Station, in October. Delta II rockets are medium capacity expendable launch vehicles derived from the Delta family of rockets built and launched since 1960. Since then there have been more than 245 Delta launches.
1998-09-30
KENNEDY SPACE CENTER, FLA. -- After covering the bulk of Deep Space 1 in thermal insulating blankets, workers in the Payload Hazardous Servicing Facility lift it from its work platform before moving it onto its transporter (behind workers at left). Deep Space 1 is being moved to the Defense Satellite Communications System Processing Facility (DPF), Cape Canaveral Air Station, for testing. At either side of the spacecraft are its solar wings, folded for launch. When fully extended, the wings measure 38.6 feet from tip to tip. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century. Onboard experiments include a solar-powered ion propulsion engine and software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. The ion propulsion engine is the first non-chemical propulsion to be used as the primary means of propelling a spacecraft. Deep Space 1 will complete most of its mission objectives within the first two months, but may also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched aboard a Boeing Delta 7326 rocket from Launch Pad 17A, Cape Canaveral Air Station, in October. Delta II rockets are medium capacity expendable launch vehicles derived from the Delta family of rockets built and launched since 1960. Since then there have been more than 245 Delta launches
Extending the Dynamic Range of the Ion Trap by Differential Mobility Filtration
Hall, Adam B.; Coy, Stephen L.; Kafle, Amol; Glick, James; Nazarov, Erkinjon
2013-01-01
A miniature, planar, differential ion mobility spectrometer (DMS) was interfaced to an LCQ classic ion trap to conduct selective ion filtration prior to mass analysis in order to extend the dynamic range of the trap. Space charge effects are known to limit the functional ion storage capacity of ion trap mass analyzers and this, in turn, can affect the quality of the mass spectral data generated. This problem is further exacerbated in the analysis of mixtures where the indiscriminate introduction of matrix ions results in premature trap saturation with non-targeted species, thereby reducing the number of parent ions that may be used to conduct MS/MS experiments for quantitation or other diagnostic studies. We show that conducting differential mobility-based separations prior to mass analysis allows the isolation of targeted analytes from electrosprayed mixtures preventing the indiscriminate introduction of matrix ions and premature trap saturation with analytically unrelated species. Coupling these two analytical techniques is shown to enhance the detection of a targeted drug metabolite from a biological matrix. In its capacity as a selective ion filter, the DMS can improve the analytical performance of analyzers such as quadrupole (3-D or linear) and ion cyclotron resonance (FT-ICR) ion traps that depend on ion accumulation. PMID:23797861
Ion-plasma protective coatings for gas-turbine engine blades
NASA Astrophysics Data System (ADS)
Kablov, E. N.; Muboyadzhyan, S. A.; Budinovskii, S. A.; Lutsenko, A. N.
2007-10-01
Evaporated, diffusion, and evaporation—diffusion protective and hardening multicomponent ionplasma coatings for turbine and compressor blades and other gas-turbine engine parts are considered. The processes of ion surface treatment (ion etching and ion saturation of a surface in the metallic plasma of a vacuum arc) and commercial equipment for the deposition of coatings and ion surface treatment are analyzed. The specific features of the ion-plasma coatings deposited from the metallic plasma of a vacuum arc are described, and the effect of the ion energy on the phase composition of the coatings and the processes occurring in the surface layer of an article to be treated are discussed. Some properties of ion-plasma coatings designed for various purposes are presented. The ion surface saturation of articles made from structural materials is shown to change the structural and phase states of their surfaces and, correspondingly, the related properties of these materials (i.e., their heat resistance, corrosion resistance, fatigue strength, and so on).
Code of Federal Regulations, 2011 CFR
2011-07-01
.... You may extend the sampling time to improve measurement accuracy of PM emissions, using good...-speed engines whose design prevents full-load operation for extended periods, you may ask for approval... designed to operate for extended periods. (e) See 40 CFR part 1065 for detailed specifications of...
Bio-inspired voltage-dependent calcium channel blockers.
Yang, Tingting; He, Lin-Ling; Chen, Ming; Fang, Kun; Colecraft, Henry M
2013-01-01
Ca(2+) influx via voltage-dependent CaV1/CaV2 channels couples electrical signals to biological responses in excitable cells. CaV1/CaV2 channel blockers have broad biotechnological and therapeutic applications. Here we report a general method for developing novel genetically encoded calcium channel blockers inspired by Rem, a small G-protein that constitutively inhibits CaV1/CaV2 channels. We show that diverse cytosolic proteins (CaVβ, 14-3-3, calmodulin and CaMKII) that bind pore-forming α1-subunits can be converted into calcium channel blockers with tunable selectivity, kinetics and potency, simply by anchoring them to the plasma membrane. We term this method 'channel inactivation induced by membrane-tethering of an associated protein' (ChIMP). ChIMP is potentially extendable to small-molecule drug discovery, as engineering FK506-binding protein into intracellular sites within CaV1.2-α1C permits heterodimerization-initiated channel inhibition with rapamycin. The results reveal a universal method for developing novel calcium channel blockers that may be extended to develop probes for a broad cohort of unrelated ion channels.
NASA Astrophysics Data System (ADS)
Varnhagen, Scott; Same, Adam; Remillard, Jesse; Park, Jae Wan
2011-03-01
Series plug-in hybrid electric vehicles of varying engine configuration and battery capacity are modeled using Advanced Vehicle Simulator (ADVISOR). The performance of these vehicles is analyzed on the bases of energy consumption and greenhouse gas emissions on the tank-to-wheel and well-to-wheel paths. Both city and highway driving conditions are considered during the simulation. When simulated on the well-to-wheel path, it is shown that the range extender with a Wankel rotary engine consumes less energy and emits fewer greenhouse gases compared to the other systems with reciprocating engines during many driving cycles. The rotary engine has a higher power-to-weight ratio and lower noise, vibration and harshness compared to conventional reciprocating engines, although performs less efficiently. The benefits of a Wankel engine make it an attractive option for use as a range extender in a plug-in hybrid electric vehicle.
2009 Joint Service Power Expo volume 2 video
2009-05-07
8483 - “A Field-Portable Lithium Ion Battery Charger with UPS Back-up Capability”, Mr. Neil Steven Graves, Acumentrics · 8394 - “Kestrel...Control”, Mr. Rick Silva, Sr. System Engineer, Custom Manufacturing & Engineering, Inc · 8371 - “New Application of Lithium - Ion Battery in Hybrid Power Supply System”, Mr. Takefumi Inoue, GS Yuasa Corporation
Characterization of advanced electric propulsion systems
NASA Technical Reports Server (NTRS)
Ray, P. K.
1982-01-01
Characteristics of several advanced electric propulsion systems are evaluated and compared. The propulsion systems studied are mass driver, rail gun, MPD thruster, hydrogen free radical thruster and mercury electron bombardment ion engine. These are characterized by specific impulse, overall efficiency, input power, average thrust, power to average thrust ratio and average thrust to dry weight ratio. Several important physical characteristics such as dry system mass, accelerator length, bore size and current pulse requirement are also evaluated in appropriate cases. Only the ion engine can operate at a specific impulse beyond 2000 sec. Rail gun, MPD thruster and free radical thruster are currently characterized by low efficiencies. Mass drivers have the best performance characteristics in terms of overall efficiency, power to average thrust ratio and average thrust to dry weight ratio. But, they can only operate at low specific impulses due to large power requirements and are extremely long due to limitations of driving current. Mercury ion engines have the next best performance characteristics while operating at higher specific impulses. It is concluded that, overall, ion engines have somewhat better characteristics as compared to the other electric propulsion systems.
Analyzing system safety in lithium-ion grid energy storage
NASA Astrophysics Data System (ADS)
Rosewater, David; Williams, Adam
2015-12-01
As grid energy storage systems become more complex, it grows more difficult to design them for safe operation. This paper first reviews the properties of lithium-ion batteries that can produce hazards in grid scale systems. Then the conventional safety engineering technique Probabilistic Risk Assessment (PRA) is reviewed to identify its limitations in complex systems. To address this gap, new research is presented on the application of Systems-Theoretic Process Analysis (STPA) to a lithium-ion battery based grid energy storage system. STPA is anticipated to fill the gaps recognized in PRA for designing complex systems and hence be more effective or less costly to use during safety engineering. It was observed that STPA is able to capture causal scenarios for accidents not identified using PRA. Additionally, STPA enabled a more rational assessment of uncertainty (all that is not known) thereby promoting a healthy skepticism of design assumptions. We conclude that STPA may indeed be more cost effective than PRA for safety engineering in lithium-ion battery systems. However, further research is needed to determine if this approach actually reduces safety engineering costs in development, or improves industry safety standards.
Lean-rich axial stage combustion in a can-annular gas turbine engine
DOE Office of Scientific and Technical Information (OSTI.GOV)
Laster, Walter R.; Szedlacsek, Peter
2016-06-14
An apparatus and method for lean/rich combustion in a gas turbine engine (10), which includes a combustor (12), a transition (14) and a combustor extender (16) that is positioned between the combustor (12) and the transition (14) to connect the combustor (12) to the transition (14). Openings (18) are formed along an outer surface (20) of the combustor extender (16). The gas turbine (10) also includes a fuel manifold (28) to extend along the outer surface (20) of the combustor extender (16), with fuel nozzles (30) to align with the respective openings (18). A method (200) for axial stage combustionmore » in the gas turbine engine (10) is also presented.« less
Environmental Testing of the NEXT PM1R Ion Engine
NASA Technical Reports Server (NTRS)
Snyder, John S.; Anderson, John R.; VanNoord, Jonathan L.; Soulas, George C.
2007-01-01
The NEXT propulsion system is an advanced ion propulsion system presently under development that is oriented towards robotic exploration of the solar system using solar electric power. The subsystem includes an ion engine, power processing unit, feed system components, and thruster gimbal. The Prototype Model engine PM1 was subjected to qualification-level environmental testing in 2006 to demonstrate compatibility with environments representative of anticipated mission requirements. Although the testing was largely successful, several issues were identified including the fragmentation of potting cement on the discharge and neutralizer cathode heater terminations during vibration which led to abbreviated thermal testing, and generation of particulate contamination from manufacturing processes and engine materials. The engine was reworked to address most of these findings, renamed PM1R, and the environmental test sequence was repeated. Thruster functional testing was performed before and after the vibration and thermal-vacuum tests. Random vibration testing, conducted with the thruster mated to the breadboard gimbal, was executed at 10.0 Grms for 2 min in each of three axes. Thermal-vacuum testing included three thermal cycles from 120 to 215 C with hot engine re-starts. Thruster performance was nominal throughout the test program, with minor variations in a few engine operating parameters likely caused by facility effects. There were no significant changes in engine performance as characterized by engine operating parameters, ion optics performance measurements, and beam current density measurements, indicating no significant changes to the hardware as a result of the environmental testing. The NEXT PM1R engine and the breadboard gimbal were found to be well-designed against environmental requirements based on the results reported herein. The redesigned cathode heater terminations successfully survived the vibration environments. Based on the results of this test program and confidence in the engineering solutions available for the remaining findings of the first test program, specifically the particulate contamination, the hardware environmental qualification program can proceed with confidence
ELF: An Extended-Lagrangian Free Energy Calculation Module for Multiple Molecular Dynamics Engines.
Chen, Haochuan; Fu, Haohao; Shao, Xueguang; Chipot, Christophe; Cai, Wensheng
2018-06-18
Extended adaptive biasing force (eABF), a collective variable (CV)-based importance-sampling algorithm, has proven to be very robust and efficient compared with the original ABF algorithm. Its implementation in Colvars, a software addition to molecular dynamics (MD) engines, is, however, currently limited to NAMD and LAMMPS. To broaden the scope of eABF and its variants, like its generalized form (egABF), and make them available to other MD engines, e.g., GROMACS, AMBER, CP2K, and openMM, we present a PLUMED-based implementation, called extended-Lagrangian free energy calculation (ELF). This implementation can be used as a stand-alone gradient estimator for other CV-based sampling algorithms, such as temperature-accelerated MD (TAMD) and extended-Lagrangian metadynamics (MtD). ELF provides the end user with a convenient framework to help select the best-suited importance-sampling algorithm for a given application without any commitment to a particular MD engine.
Peng, Lele; Zhu, Yue; Peng, Xu; Fang, Zhiwei; Chu, Wangsheng; Wang, Yu; Xie, Yujun; Li, Yafei; Cha, Judy J; Yu, Guihua
2017-10-11
Two-dimensional (2D) energy materials have shown the promising electrochemical characteristics for lithium ion storage. However, the decreased active surfaces and the sluggish charge/mass transport for beyond-lithium ion storage that has potential for large-scale energy storage systems, such as sodium or potassium ion storage, caused by the irreversible restacking of 2D materials during electrode processing remain a major challenge. Here we develop a general interlayer engineering strategy to address the above-mentioned challenges by using 2D ultrathin vanadyl phosphate (VOPO 4 ) nanosheets as a model material for challenging sodium ion storage. Via controlled intercalation of organic molecules, such as triethylene glycol and tetrahydrofuran, the sodium ion transport in VOPO 4 nanosheets has been significantly improved. In addition to advanced characterization including X-ray diffraction, high-resolution transmission electron microscopy, and X-ray absorption fine structure to characterize the interlayer and the chemical bonding/configuration between the organic intercalants and the VOPO 4 host layers, density functional theory calculations are also performed to understand the diffusion behavior of sodium ions in the pure and TEG intercalated VOPO 4 nanosheets. Because of the expanded interlayer spacing in combination with the decreased energy barriers for sodium ion diffusion, intercalated VOPO 4 nanosheets show much improved sodium ion transport kinetics and greatly enhanced rate capability and cycling stability for sodium ion storage. Our results afford deeper understanding of the interlayer-engineering strategy to improve the sodium ion storage performance of the VOPO 4 nanosheets. Our results may also shed light on possible multivalent-ion based energy storage such as Mg 2+ and Al 3+ .
Electric Propulsion Laboratory Vacuum Chamber
1964-06-21
Engineer Paul Reader and his colleagues take environmental measurements during testing of a 20-inch diameter ion engine in a vacuum tank at the Electric Propulsion Laboratory (EPL). Researchers at the Lewis Research Center were investigating the use of a permanent-magnet circuit to create the magnetic field required power electron bombardment ion engines. Typical ion engines use a solenoid coil to create this magnetic field. It was thought that the substitution of a permanent magnet would create a comparable magnetic field with a lower weight. Testing of the magnet system in the EPL vacuum tanks revealed no significant operational problems. Reader found the weight of the two systems was similar, but that the thruster’s efficiency increased with the magnet. The EPL contained a series of large vacuum tanks that could be used to simulate conditions in space. Large vacuum pumps reduced the internal air pressure, and a refrigeration system created the cryogenic temperatures found in space.
Liu, Jianming; Chan, Siu Hung Joshua; Brock-Nannestad, Theis; Chen, Jun; Lee, Sang Yup; Solem, Christian; Jensen, Peter Ruhdal
2016-07-01
Biocompatible chemistry is gaining increasing attention because of its potential within biotechnology for expanding the repertoire of biological transformations carried out by enzymes. Here we demonstrate how biocompatible chemistry can be used for synthesizing valuable compounds as well as for linking metabolic pathways to achieve redox balance and rescued growth. By comprehensive rerouting of metabolism, activation of respiration, and finally metal ion catalysis, we successfully managed to convert the homolactic bacterium Lactococcus lactis into a homo-diacetyl producer with high titer (95mM or 8.2g/L) and high yield (87% of the theoretical maximum). Subsequently, the pathway was extended to (S,S)-2,3-butanediol (S-BDO) through efficiently linking two metabolic pathways via chemical catalysis. This resulted in efficient homo-S-BDO production with a titer of 74mM (6.7g/L) S-BDO and a yield of 82%. The diacetyl and S-BDO production rates and yields obtained are the highest ever reported, demonstrating the promising combination of metabolic engineering and biocompatible chemistry as well as the great potential of L. lactis as a new production platform. Copyright © 2016 International Metabolic Engineering Society. Published by Elsevier Inc. All rights reserved.
Extending the Dynamic Range of a Time Projection Chamber
NASA Astrophysics Data System (ADS)
Estee, Justin; S πRIT Collaboration
2017-09-01
The use of Time Projection Chambers (TPCs) in intermediate heavy ion reactions faces some challenges in addressing the energy losses that range from the small energy loss of relativistic pions to the large energy loss of slow moving heavy ions. A typical trade-off can be to set the smallest desired signals to be well within the lower limits of the dynamic range of the electronics while allowing for some larger signals to saturate the electronics. With wire plane anodes, signals from readout pads further away from the track remain unsaturated and allow signals from tracks with saturated pads to be accurately recovered. We illustrate this technique using data from the SAMURAI Pion-Reconstruction and Ion-Tracker (S πRIT) TPC , which recently measured pions and light charged particles in collisions of Sn+Sn isotopes. Our method exploits knowledge of how the induced charge distribution depends on the distance from the track to smoothly extend dynamic range even when some of the pads in the track are saturated. To accommodate the analysis of slow moving heavy ions, we have extended the Bichsel energy loss distributions to handle slower moving ions as well. In this talk, I will discuss a combined approach which successfully extends the dynamic range of the TPC electronics. This work is supported by the U.S. DOE under Grant Nos. DE-SC0014530, DE-NA0002923, US NSF Grant No. PHY-1565546 and the Japan MEXT KAKENHI Grant No. 24105004.
Battery Power Management in Heavy-duty HEVs based on the Estimated Critical Surface Charge
2011-03-01
health prospects without any penalty on fuel efficiency. Keywords: Lithium - ion battery ; power management; critical surface charge; Lithium-ion...fuel efficiency. 15. SUBJECT TERMS Lithium - ion battery ; power management; critical surface charge; Lithium-ion concentration; estimation; extended...Di Domenico, D., Fiengo, G., and Stefanopoulou, A. (2008) ’ Lithium - ion battery state of charge estimation with a kalman filter based on a
Combining results of multiple search engines in proteomics.
Shteynberg, David; Nesvizhskii, Alexey I; Moritz, Robert L; Deutsch, Eric W
2013-09-01
A crucial component of the analysis of shotgun proteomics datasets is the search engine, an algorithm that attempts to identify the peptide sequence from the parent molecular ion that produced each fragment ion spectrum in the dataset. There are many different search engines, both commercial and open source, each employing a somewhat different technique for spectrum identification. The set of high-scoring peptide-spectrum matches for a defined set of input spectra differs markedly among the various search engine results; individual engines each provide unique correct identifications among a core set of correlative identifications. This has led to the approach of combining the results from multiple search engines to achieve improved analysis of each dataset. Here we review the techniques and available software for combining the results of multiple search engines and briefly compare the relative performance of these techniques.
Combining Results of Multiple Search Engines in Proteomics*
Shteynberg, David; Nesvizhskii, Alexey I.; Moritz, Robert L.; Deutsch, Eric W.
2013-01-01
A crucial component of the analysis of shotgun proteomics datasets is the search engine, an algorithm that attempts to identify the peptide sequence from the parent molecular ion that produced each fragment ion spectrum in the dataset. There are many different search engines, both commercial and open source, each employing a somewhat different technique for spectrum identification. The set of high-scoring peptide-spectrum matches for a defined set of input spectra differs markedly among the various search engine results; individual engines each provide unique correct identifications among a core set of correlative identifications. This has led to the approach of combining the results from multiple search engines to achieve improved analysis of each dataset. Here we review the techniques and available software for combining the results of multiple search engines and briefly compare the relative performance of these techniques. PMID:23720762
Yang, Xiaoyu; Neta, Pedatsur; Stein, Stephen E
2017-11-01
Tandem mass spectral library searching is finding increased use as an effective means of determining chemical identity in mass spectrometry-based omics studies. We previously reported on constructing a tandem mass spectral library that includes spectra for multiple precursor ions for each analyte. Here we report our method for expanding this library to include MS 2 spectra of fragment ions generated during the ionization process (in-source fragment ions) as well as MS 3 and MS 4 spectra. These can assist the chemical identification process. A simple density-based clustering algorithm was used to cluster all significant precursor ions from MS 1 scans for an analyte acquired during an infusion experiment. The MS 2 spectra associated with these precursor ions were grouped into the same precursor clusters. Subsequently, a new top-down hierarchical divisive clustering algorithm was developed for clustering the spectra from fragmentation of ions in each precursor cluster, including the MS 2 spectra of the original precursors and of the in-source fragments as well as the MS n spectra. This algorithm starts with all the spectra of one precursor in one cluster and then separates them into sub-clusters of similar spectra based on the fragment patterns. Herein, we describe the algorithms and spectral evaluation methods for extending the library. The new library features were demonstrated by searching the high resolution spectra of E. coli extracts against the extended library, allowing identification of compounds and their in-source fragment ions in a manner that was not possible before. Graphical Abstract ᅟ.
Stähli, Christoph; Muja, Naser; Nazhat, Showan N
2013-02-01
The success of tissue engineering is dependent on rapid scaffold vascularization after engraftment. Copper ions are well known to be angiogenic but exhibit cytotoxicity at elevated doses. The high sensitivity to copper concentration underlines the need of a controlled release mechanism. This study investigated the effect of copper ions released from phosphate-based glasses (PGs) on human umbilical vein endothelial cells (HUVECs) under standard growth conditions (SGC), as well as in a reduced nutrient environment (RNE) with decreased bovine serum and growth factor concentrations to approximate conditions in the core of large volume scaffolds where nutrient diffusion is limited. Initially, HUVECs were exposed to a range of CuCl(2) concentrations in order to identify an optimal response in terms of their metabolism, viability, and apoptotic activity. Under SGC, HUVEC metabolic activity and viability were reduced in a dose-dependent manner in the presence of 0.44-12 ppm Cu(2+). In contrast, HUVEC death induced by the RNE was delayed by an optimal dose of 4 ppm Cu(2+), which was associated with a down-regulation of apoptosis as evidenced by caspase-3/7 activity. Copper ion release from soluble PGs of the formulation 50P(2)O(5)-30CaO-(20-x)Na(2)O-xCuO [mol%] (x=0, 1, 5 and 10) demonstrated a controllable increase with CuO content. The presence of 4 ppm copper ions released from the 10% CuO PG composition reproduced the delay in HUVEC death in the RNE, suggesting the potential of these materials to extend survival of transplanted endothelial cells in large volume scaffolds.
Sensitivity Testing of the NSTAR Ion Thruster
NASA Technical Reports Server (NTRS)
Sengupta, Anita; Anderson, John; Brophy, John
2007-01-01
During the Extended Life Test of the DS1 flight spare ion thruster, the engine was subjected to sensitvity testing in order to characterize the macroscopic dependence of discharge chamber sensitivity to a +\\-3% vatiation in main flow, cathode flow and beam current, and to +\\5% variation in beam and accelerator voltage, was determined for the minimum- (THO), half- (TH8) and full power (TH15) throttle levels. For each power level investigared, 16 high/low operating conditions were chosen to vary the flows, beam current, and grid voltages in in a matrix that mapped out the entire parameter space. The matrix of data generated was used to determine the partial derivative or senitivity of the dependent parameters--discharge voltage, discharge current, discharge loss, double-to-single-ion current ratio, and neutralizer-keeper voltage--to the variation in the independent parameters--main flow, cathode flow, beam current, and beam voltage. The sensititivities of each dependent parameter with respect to each independent parameter were determined using a least-square fit routine. Variation in these sensitivities with thruster runtime was recorded over the duration of the ELT, to detemine if discharge performance changed with thruster wear. Several key findings have been ascertained from the sensitivity testing. Discharge operation is most sensitve to changes in cathode flow and to a lesser degree main flow. The data also confirms that for the NSTAR configuration plasma production is limited by primary electron input due to the fixed neutral population. Key sensitivities along with their change with thruster wear (operating time) will be presented. In addition double ion content measurements with an ExB probe will also be presented to illustrate beam ion production and content sensitivity to the discharge chamber operating parameteres.
Engineering an FMN-based iLOV protein for the detection of arsenic ions.
Ravikumar, Yuvaraj; Nadarajan, Saravanan Prabhu; Lee, Chong-Soon; Yun, Hyungdon
2017-05-15
Over the past few decades, genetically encoded fluorescent proteins have been widely used as efficient probes to explore and investigate the roles of metal ions in biological processes. The discovery of small FMN-based fluorescent proteins, such as iLOV and FbFP, has enabled researchers to exploit these fluorescent reporter proteins for metal-sensing applications. In this study, we report the inherent binding properties of iLOV towards arsenic ions. The fluorescence quenching of iLOV was linearly related to the concentration of arsenic ions, and engineered proteins showed better sensitivity than the wild-type protein. Engineering key residues around the chromophore converted the iLOV protein into a highly sensitive sensor for As 3+ ions. iLOV N468S exhibited an improved binding affinity with a dissociation constant of 1.5 μM. Furthermore, the circular dichroism spectra indicated that the fluorescence quenching mechanism might be related to arsenic-protein complex formation. Thus, the reagentless sensing of arsenic can potentially be exploited to determine intracellular or environmental arsenic using a genetically encoded biosensing approach. Copyright © 2017 Elsevier Inc. All rights reserved.
Conceptual Design of the Nuclear Electronic Xenon Ion System (NEXIS)
NASA Technical Reports Server (NTRS)
Monheiser, Jeff; Polk, Jay; Randolph, Tom
2004-01-01
In support of the NEXIS program, Aerojet-Redmond Operations, with review and input from the JPL and Boeing, has completed the design for a development model (DM) discharge chamber assembly and main discharge cathode assembly. These efforts along with the work by JPL to develop the carbon-carbon-composite ion optics assembly have resulted in a complete ion engine design. The goal of the NEXIS program is to significantly advance the current state of the art by developing an ion engine capable of operating at an input power of 20kW, an Isp of 7500 sec and have a total xenon through put capability of 2000 kg. In this paper we will describe the methodology used to design the discharge chamber and cathode assemblies and describe the resulting final design. Specifics will include the concepts used for the mounting of the ion optics along with the concepts used for the gimbal mounts. In addition, we will present results of a vibrational analysis showing how the engine will respond to a typical Delta IV heavy vibration spectrum.
Performance and Safety of Lithium Ion Cells
NASA Technical Reports Server (NTRS)
Ratnakumar, B. V.; Smart, M. C.; Whitcanack, L.; Surampudi, S.; Marsh, R.
2001-01-01
This report evaluates the performance and safety of Lithium Ion (Li-Ion) cells when used in batteries. Issues discussed include the cycle life, energy efficiency, tolerance to higher charge voltage, tolerance to extended tapered charge voltage, charge on cycling, specific energy, low temperature discharge, low temperature charge, various charge characteristics, storage characteristics, and more of Li-Ion cells.
Ion manipulation method and device
DOE Office of Scientific and Technical Information (OSTI.GOV)
Anderson, Gordon A.; Baker, Erin M.; Smith, Richard D.
2017-11-07
An ion manipulation method and device is disclosed. The device includes a pair of substantially parallel surfaces. An array of inner electrodes is contained within, and extends substantially along the length of, each parallel surface. The device includes a first outer array of electrodes and a second outer array of electrodes. Each outer array of electrodes is positioned on either side of the inner electrodes, and is contained within and extends substantially along the length of each parallel surface. A DC voltage is applied to the first and second outer array of electrodes. A RF voltage, with a superimposed electricmore » field, is applied to the inner electrodes by applying the DC voltages to each electrode. Ions either move between the parallel surfaces within an ion confinement area or along paths in the direction of the electric field, or can be trapped in the ion confinement area.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Anderson, Gordon A.; Baker, Erin M.; Smith, Richard D.
2018-05-08
An ion manipulation method and device is disclosed. The device includes a pair of substantially parallel surfaces. An array of inner electrodes is contained within, and extends substantially along the length of, each parallel surface. The device includes a first outer array of electrodes and a second outer array of electrodes. Each outer array of electrodes is positioned on either side of the inner electrodes, and is contained within and extends substantially along the length of each parallel surface. A DC voltage is applied to the first and second outer array of electrodes. A RF voltage, with a superimposed electricmore » field, is applied to the inner electrodes by applying the DC voltages to each electrode. Ions either move between the parallel surfaces within an ion confinement area or along paths in the direction of the electric field, or can be trapped in the ion confinement area.« less
NASA Astrophysics Data System (ADS)
Roenn, John; Karvonen, Lasse; Pyymäki-Perros, Alexander; Peyghambarian, Nasser; Lipsanen, Harri; Säynätjoki, Antti; Sun, Zhipei
2016-05-01
Recently, rare-earth doped waveguide amplifiers (REDWAs) have drawn significant attention as a promising solution to on-chip amplification of light in silicon photonics and integrated optics by virtue of their high excited state lifetime (up to 10 ms) and broad emission spectrum (up to 200 nm) at infrared wavelengths. In the family of rare-earths, at least erbium, holmium, thulium, neodymium and ytterbium have been demonstrated to be good candidates for amplifier operation at moderate concentrations (< 0.1 %). However, efficient amplifier operation in REDWAs is a very challenging task because high concentration of ions (<0.1%) is required in order to produce reasonable amplification over short device length. Inevitably, high concentration of ions leads to energy-transfer between neighboring ions, which results as decreased gain and increased noise in the amplifier system. It has been shown that these energy-transfer mechanisms in highly-doped gain media are inversely proportional to the sixth power of the distance between the ions. Therefore, novel fabrication techniques with the ability to control the distribution of the rare-earth ions within the gain medium are urgently needed in order to fabricate REDWAs with high efficiency and low noise. Here, we show that atomic layer deposition (ALD) is an excellent technique to fabricate highly-doped (<1%) RE:Al2O3 gain materials by using its nanoscale engineering ability to delicately control the incorporation of RE ions during the deposition. In our experiment, we fabricated Er:Al2O3 and Tm:Al2O3 thin films with ALD by varying the concentration of RE ions from 1% to 7%. By measuring the photoluminescence response of the fabricated samples, we demonstrate that it is possible to incorporate up to 5% of either Er- or Tm-ions in Al2O3 host before severe quenching occurs. We believe that this technique can be extended to other RE ions as well. Therefore, our results show the exceptionality of ALD as a deposition technique for REDWA technology.
Linear Ion Traps in Space: The Mars Organic Molecule Analyzer (MOMA) Instrument and Beyond
NASA Astrophysics Data System (ADS)
Arevalo, Ricardo; Brinckerhoff, William; Mahaffy, Paul; van Amerom, Friso; Danell, Ryan; Pinnick, Veronica; Li, Xiang; Hovmand, Lars; Getty, Stephanie; Grubisic, Andrej; Goesmann, Fred; Cottin, Hervé
2015-11-01
Historically, quadrupole mass spectrometer (QMS) instruments have been used to explore a wide survey of planetary targets in our solar system, from Venus (Pioneer Venus) to Saturn (Cassini-Huygens). However, linear ion trap (LIT) mass spectrometers have found a niche as smaller, versatile alternatives to traditional quadrupole analyzers.The core astrobiological experiment of ESA’s ExoMars Program is the Mars Organic Molecule Analyzer (MOMA) onboard the ExoMars 2018 rover. The MOMA instrument is centered on a linear (or 2-D) ion trap mass spectrometer. As opposed to 3-D traps, LIT-based instruments accommodate two symmetrical ion injection pathways, enabling two complementary ion sources to be used. In the case of MOMA, these two analytical approaches are laser desorption mass spectrometry (LDMS) at Mars ambient pressures, and traditional gas chromatography mass spectrometry (GCMS). The LIT analyzer employed by MOMA also offers: higher ion capacity compared to a 3-D trap of the same volume; redundant detection subassemblies for extended lifetime; and, a link to heritage QMS designs and assembly logistics. The MOMA engineering test unit (ETU) has demonstrated the detection of organics in the presence of wt.%-levels of perchlorate, effective ion enhancement via stored waveform inverse Fourier transform (SWIFT), and derivation of structural information through tandem mass spectrometry (MS/MS).A more progressive linear ion trap mass spectrometer (LITMS), funded by the NASA ROSES MatISSE Program, is being developed at NASA GSFC and promises to augment the capabilities of the MOMA instrument by way of: an expanded mass range (i.e., 20 - 2000 Da); detection of both positive and negative ions; spatially resolved (<1 mm) characterization of individual rock core layers; and, evolved gas analysis and GCMS with pyrolysis up to 1300° C (enabling breakdown of refractory phases). The Advanced Resolution Organic Molecule Analyzer (AROMA) instrument, being developed through NASA PICASSO and ESA Research and Development Programs, combines a highly capable LIT front end (a la LITMS) with a high-resolution OrbitrapTM (a la CosmOrbitrap) mass analyzer to enable disambiguation of complex molecular signals in organic-rich targets.
Vacuum chamber for ion manipulation device
Chen, Tsung-Chi; Tang, Keqi; Ibrahim, Yehia M; Smith, Richard D; Anderson, Gordon A; Baker, Erin M
2014-12-09
An ion manipulation method and device is disclosed. The device includes a pair of substantially parallel surfaces. An array of inner electrodes is contained within, and extends substantially along the length of, each parallel surface. The device includes a first outer array of electrodes and a second outer array of electrodes. Each outer array of electrodes is positioned on either side of the inner electrodes, and is contained within and extends substantially along the length of each parallel surface. A DC voltage is applied to the first and second outer array of electrodes. A RF voltage, with a superimposed electric field, is applied to the inner electrodes by applying the DC voltages to each electrode. Ions either move between the parallel surfaces within an ion confinement area or along paths in the direction of the electric field, or can be trapped in the ion confinement area. A predetermined number of pairs of surfaces are disposed in one or more chambers, forming a multiple-layer ion mobility cyclotron device.
NASA Astrophysics Data System (ADS)
Phan, T. D.; Shay, M. A.; Haggerty, C. C.; Gosling, J. T.; Eastwood, J. P.; Fujimoto, M.; Malakit, K.; Mozer, F. S.; Cassak, P. A.; Oieroset, M.; Angelopoulos, V.
2016-09-01
We report a Time History of Events and Macroscale Interactions during Substorms (THEMIS-D) spacecraft crossing of a magnetopause reconnection exhaust ~9 ion skin depths (di) downstream of an X line. The crossing was characterized by ion jetting at speeds substantially below the predicted reconnection outflow speed. In the magnetospheric inflow region THEMIS detected (a) penetration of magnetosheath ions and the resulting flows perpendicular to the reconnection plane, (b) ion outflow extending into the magnetosphere, and (c) enhanced electron parallel temperature. Comparison with a simulation suggests that these signatures are associated with the gyration of magnetosheath ions onto magnetospheric field lines due to the shift of the flow stagnation point toward the low-density magnetosphere. Our observations indicate that these effects, ~2-3 di in width, extend at least 9 di downstream of the X line. The detection of these signatures could indicate large-scale proximity of the X line but do not imply that the spacecraft was upstream of the electron diffusion region.
Turbine blade tip gap reduction system
Diakunchak, Ihor S.
2012-09-11
A turbine blade sealing system for reducing a gap between a tip of a turbine blade and a stationary shroud of a turbine engine. The sealing system includes a plurality of flexible seal strips extending from a pressure side of a turbine blade generally orthogonal to the turbine blade. During operation of the turbine engine, the flexible seal strips flex radially outward extending towards the stationary shroud of the turbine engine, thereby reducing the leakage of air past the turbine blades and increasing the efficiency of the turbine engine.
Ion thruster system (8-cm) cyclic endurance test
NASA Technical Reports Server (NTRS)
Dulgeroff, C. R.; Beattie, J. R.; Poeschel, R. L.; Hyman, J., Jr.
1984-01-01
This report describes the qualification test of an Engineering-Model 5-mN-thrust 8-cm-diameter mercury ion thruster which is representative of the Ion Auxiliary Propulsion System (IAPS) thrusters. Two of these thrusters are scheduled for future flight test. The cyclic endurance test described herein was a ground-based test performed in a vacuum facility with a liquid-nitrogen-cooled cryo-surface and a frozen mercury target. The Power Electronics Unit, Beam Shield, Gimal, and Propellant Tank that were used with the thruster in the endurance test are also similar to those of the IAPS. The IAPS thruster that will undergo the longest beam-on-time during the actual space test will be subjected to 7,055 hours of beam-on-time and 2,557 cycles during the flight test. The endurance test was successfully concluded when the mercury in the IAPS Propellant Tank was consumed. At that time, 8,471 hours of beam-on-time and 599 cycles had been accumulated. Subsequent post-test-evaluation operations were performed (without breaking vacuum) which extended the test values to 652 cycles and 9,489 hours of beam-on-time. The Power Electronic Unit (PEU) and thruster were in the same vacuum chamber throughout the test. The PEU accumulated 10,268 hr of test time with high voltage applied to the operating thruster or dummy load.
Cradle-to-Gate Emissions from a Commercial Electric Vehicle Li-Ion Battery: A Comparative Analysis.
Kim, Hyung Chul; Wallington, Timothy J; Arsenault, Renata; Bae, Chulheung; Ahn, Suckwon; Lee, Jaeran
2016-07-19
We report the first cradle-to-gate emissions assessment for a mass-produced battery in a commercial battery electric vehicle (BEV); the lithium-ion battery pack used in the Ford Focus BEV. The assessment was based on the bill of materials and primary data from the battery industry, that is, energy and materials input data from the battery cell and pack supplier. Cradle-to-gate greenhouse gas (GHG) emissions for the 24 kWh Ford Focus lithium-ion battery are 3.4 metric tonnes of CO2-eq (140 kg CO2-eq per kWh or 11 kg CO2-eq per kg of battery). Cell manufacturing is the key contributor accounting for 45% of the GHG emissions. We review published studies of GHG emissions associated with battery production to compare and contrast with our results. Extending the system boundary to include the entire vehicle we estimate a 39% increase in the cradle-to-gate GHG emissions of the Focus BEV compared to the Focus internal combustion engine vehicle (ICEV), which falls within the range of literature estimates of 27-63% increases for hypothetical nonproduction BEVs. Our results reduce the uncertainties associated with assessment of BEV battery production, serve to identify opportunities to reduce emissions, and confirm previous assessments that BEVs have great potential to reduce GHG emissions over the full life cycle and provide local emission free mobility.
Li, Keyan; Xie, Hui; Liu, Jun; Ma, Zengsheng; Zhou, Yichun; Xue, Dongfeng
2013-10-28
Toward engineering high performance anode alloys for Li-ion batteries, we proposed a useful method to quantitatively estimate the bulk modulus of binary alloys in terms of metallic electronegativity (EN), alloy composition and formula volume. On the basis of our proposed potential viewpoint, EN as a fundamental chemistry concept can be extended to be an important physical parameter to characterize the mechanical performance of Li-Si and Li-Sn alloys as anode materials for Li-ion batteries. The bulk modulus of binary alloys is linearly proportional to the combination of average metallic EN and atomic density of alloys. We calculated the bulk moduli of Li-Si and Li-Sn alloys with different Li concentrations, which can agree well with the reported data. The bulk modulus of Li-Si and Li-Sn alloys decreases with increasing Li concentration, leading to the elastic softening of the alloys, which is essentially caused by the decreased strength of constituent chemical bonds in alloys from the viewpoint of EN. This work provides a deep understanding of mechanical failure of Si and Sn anodes for Li-ion batteries, and permits the prediction of the composition dependent bulk modulus of various lithiated alloys on the basis of chemical formula, metallic EN and cell volume (or alloy density), with no structural details required.
Current technology in ion and electrothermal propulsion
NASA Technical Reports Server (NTRS)
Finke, R. C.; Murch, C. K.
1973-01-01
High performance propulsion devices, such as electrostatic ion engines and electrothermal thrusters, are achieving wide user acceptance. The current technology and projected development trends in the areas of ion and electrothermal propulsion systems and components are surveyed.
Annular Ion Engine Concept and Development Status
NASA Technical Reports Server (NTRS)
Patterson, Michael J.
2016-01-01
The Annular Ion Engine (AIE) concept represents an evolutionary development in gridded ion thruster technology with the potential for delivering revolutionary capabilities. It has this potential because the AIE concept: (a) enables scaling of ion thruster technology to high power at specific impulse (Isp) values of interest for near-term mission applications, 5000 sec; and (b) it enables an increase in both thrust density and thrust-to-power (FP) ratio exceeding conventional ion thrusters and other electric propulsion (EP) technology options, thereby yielding the highest performance over a broad range in Isp. The AIE concept represents a natural progression of gridded ion thruster technology beyond the capabilities embodied by NASAs Evolutionary Xenon Thruster (NEXT) [1]. The AIE would be appropriate for: (a) applications which require power levels exceeding NEXTs capabilities (up to about 14 kW [2]), with scalability potentially to 100s of kW; and/or (b) applications which require FP conditions exceeding NEXTs capabilities.
Compact Microwave Mercury Ion Clock for Space Applications
NASA Technical Reports Server (NTRS)
Prestage, John D.; Tu, Meirong; Chung, Sang K.; MacNeal, Paul
2007-01-01
We review progress in developing a small Hg ion clock for space operation based on breadboard ion-clock physics package where Hg ions are shuttled between a quadrupole and a 16-pole rf trap. With this architecture we have demonstrated short-term stability approx.1-2x10(exp -13) at 1 second, averaging to 10-15 at 1 day. This development shows that H-maser quality stabilities can be produced in a small clock package, comparable in size to an ultra-stable quartz oscillator required or holding 1-2x10(exp -13) at 1 second. We have completed an ion clock physics package designed to withstand vibration of launch and are currently building a approx. 1 kg engineering model for test. We also discuss frequency steering software algorithms that simultaneously measure ion signal size and lamp light output, useful for long term operation and self-optimization of microwave power and return engineering data.
Long-pulse beam acceleration of MeV-class H(-) ion beams for ITER NB accelerator.
Umeda, N; Kashiwagi, M; Taniguchi, M; Tobari, H; Watanabe, K; Dairaku, M; Yamanaka, H; Inoue, T; Kojima, A; Hanada, M
2014-02-01
In order to realize neutral beam systems in International Thermonuclear Experimental Reactor whose target is to produce a 1 MeV, 200 A/m(2) during 3600 s D(-) ion beam, the electrostatic five-stages negative ion accelerator so-called "MeV accelerator" has been developed at Japan Atomic Energy Agency. To extend pulse length, heat load of the acceleration grids was reduced by controlling the ion beam trajectory. Namely, the beam deflection due to the residual magnetic field of filter magnet was suppressed with the newly developed extractor with a 0.5 mm off-set aperture displacement. The new extractor improved the deflection angle from 6 mrad to 1 mrad, resulting in the reduction of direct interception of negative ions from 23% to 15% of the total acceleration power, respectively. As a result, the pulse length of 130 A/m(2), 881 keV H(-) ion beam has been successfully extended from a previous value of 0.4 s to 8.7 s. This is the first long pulse negative ion beam acceleration over 100 MW/m(2).
NASA Astrophysics Data System (ADS)
Pyo, Ju-Young; Cho, Won-Ju
2017-03-01
In this paper, we propose a high-performance separative extended gate ion-sensitive field-effect transistor (SEGISFET) that consists of a tin dioxide (SnO2) SEG sensing part and a double-gate structure amorphous indium gallium zinc oxide (a-IGZO) thin-film transistor (TFT) with tantalum pentoxide/silicon dioxide (Ta2O5/SiO2)-engineered top-gate oxide. To increase sensitivity, we maximized the capacitive coupling ratio by applying high-k dielectric at the top-gate oxide layer. As an engineered top-gate oxide, a stack of 25 nm-thick Ta2O5 and 10 nm-thick SiO2 layers was found to simultaneously satisfy a small equivalent oxide thickness (˜17.14 nm), a low leakage current, and a stable interfacial property. The threshold-voltage instability, which is a fundamental issue in a-IGZO TFTs, was improved by low-temperature post-deposition annealing (˜87 °C) using microwave irradiation. The double-gate structure a-IGZO TFTs with engineered top-gate oxide exhibited high mobility, small subthreshold swing, high drive current, and larger on/off current ratio. The a-IGZO SEGISFETs with a dual-gate sensing mode showed a pH sensitivity of 649.04 mV pH-1, which is far beyond the Nernst limit. The non-ideal behavior of ISFETs, hysteresis, and drift effect also improved. These results show that the double-gate structure a-IGZO TFTs with engineered top-gate oxide can be a good candidate for cheap and disposable SEGISFET sensors.
NASA Radiation Protection Research for Exploration Missions
NASA Technical Reports Server (NTRS)
Wilson, John W.; Cucinotta, Francis A.; Tripathi, Ram K.; Heinbockel, John H.; Tweed, John; Mertens, Christopher J.; Walker, Steve A.; Blattnig, Steven R.; Zeitlin, Cary J.
2006-01-01
The HZETRN code was used in recent trade studies for renewed lunar exploration and currently used in engineering development of the next generation of space vehicles, habitats, and EVA equipment. A new version of the HZETRN code capable of simulating high charge and energy (HZE) ions, light-ions and neutrons with either laboratory or space boundary conditions with enhanced neutron and light-ion propagation is under development. Atomic and nuclear model requirements to support that development will be discussed. Such engineering design codes require establishing validation processes using laboratory ion beams and space flight measurements in realistic geometries. We discuss limitations of code validation due to the currently available data and recommend priorities for new data sets.
Ion-plasma gun for ion-milling machine
Kaminsky, Manfred S.; Campana, Jr., Thomas J.
1976-01-01
An ion gun includes an elongated electrode with a hollow end portion closed by a perforated end plate. The end plate is positioned parallel to a perforated flat electrode of opposite electrical polarity. An insulated sleeve encompasses the elongated electrode and extends outwardly from the perforated end towards the flat electrode. The sleeve length is separated into two portions of different materials. The first is formed of a high-temperature material that extends over the hollow portion of the elongated electrode where the arc is initiated by a point source electrode. The second sleeve portion extending over the remainder of the elongated electrode is of a resilient material for enhanced seal-forming ability and retention of plasma gas. Perforations are arranged in the flat electrode in a mutually opposing triangular pattern to project a plasma beam having a generally flat current profile towards a target requiring precision milling.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schnack, D. D.; Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin 53706; Cheng, J.
We perform linear stability studies of the ion temperature gradient (ITG) instability in unsheared slab geometry using kinetic and extended magnetohydrodynamics (MHD) models, in the regime k{sub ∥}/k{sub ⊥}≪1. The ITG is a parallel (to B) sound wave that may be destabilized by finite ion Larmor radius (FLR) effects in the presence of a gradient in the equilibrium ion temperature. The ITG is stable in both ideal and resistive MHD; for a given temperature scale length L{sub Ti0}, instability requires that either k{sub ⊥}ρ{sub i} or ρ{sub i}/L{sub Ti0} be sufficiently large. Kinetic models capture FLR effects to all ordersmore » in either parameter. In the extended MHD model, these effects are captured only to lowest order by means of the Braginskii ion gyro-viscous stress tensor and the ion diamagnetic heat flux. We present the linear electrostatic dispersion relations for the ITG for both kinetic Vlasov and extended MHD (two-fluid) models in the local approximation. In the low frequency fluid regime, these reduce to the same cubic equation for the complex eigenvalue ω=ω{sub r}+iγ. An explicit solution is derived for the growth rate and real frequency in this regime. These are found to depend on a single non-dimensional parameter. We also compute the eigenvalues and the eigenfunctions with the extended MHD code NIMROD, and a hybrid kinetic δf code that assumes six-dimensional Vlasov ions and isothermal fluid electrons, as functions of k{sub ⊥}ρ{sub i} and ρ{sub i}/L{sub Ti0} using a spatially dependent equilibrium. These solutions are compared with each other, and with the predictions of the local kinetic and fluid dispersion relations. Kinetic and fluid calculations agree well at and near the marginal stability point, but diverge as k{sub ⊥}ρ{sub i} or ρ{sub i}/L{sub Ti0} increases. There is good qualitative agreement between the models for the shape of the unstable global eigenfunction for L{sub Ti0}/ρ{sub i}=30 and 20. The results quantify how far fluid calculations can be extended accurately into the kinetic regime. We conclude that for the linear ITG problem in slab geometry with unsheared magnetic field when k{sub ∥}/k{sub ⊥}≪1, the extended MHD model may be a reliable physical model for this problem when ρ{sub i}/L{sub Ti0}<10{sup −2} and k{sub ⊥}ρ{sub i}<0.2.« less
Analyzing system safety in lithium-ion grid energy storage
Rosewater, David; Williams, Adam
2015-10-08
As grid energy storage systems become more complex, it grows more di cult to design them for safe operation. This paper first reviews the properties of lithium-ion batteries that can produce hazards in grid scale systems. Then the conventional safety engineering technique Probabilistic Risk Assessment (PRA) is reviewed to identify its limitations in complex systems. To address this gap, new research is presented on the application of Systems-Theoretic Process Analysis (STPA) to a lithium-ion battery based grid energy storage system. STPA is anticipated to ll the gaps recognized in PRA for designing complex systems and hence be more e ectivemore » or less costly to use during safety engineering. It was observed that STPA is able to capture causal scenarios for accidents not identified using PRA. Additionally, STPA enabled a more rational assessment of uncertainty (all that is not known) thereby promoting a healthy skepticism of design assumptions. Lastly, we conclude that STPA may indeed be more cost effective than PRA for safety engineering in lithium-ion battery systems. However, further research is needed to determine if this approach actually reduces safety engineering costs in development, or improves industry safety standards.« less
Brobeck, W.M.
1959-02-24
An ion source is described wherein a portion of the filament serving as a cathode for the arc is protected from the effects of non-ionized particles escaping from the ionizing mechanism. In the described ion source, the source block has a gas chamber and a gas passage extending from said gas chamber to two adjacent faces of the source block. A plate overlies the passage and abuts one of the aforementioned block faces, while extending beyond the other face. In addition, the plate is apertured in line with the block passage. The filament overlies the aperture to effectively shield the portion of the filament not directiy aligned with the passage where the arc is produced.
Ion Beam Characterization of a NEXT Multi-Thruster Array Plume
NASA Technical Reports Server (NTRS)
Pencil, Eric J.; Foster, John E.; Patterson, Michael J.; Diaz, Esther M.; Van Noord, Jonathan L.; McEwen, Heather K.
2006-01-01
Three operational, engineering model, 7-kW ion thrusters and one instrumented, dormant thruster were installed in a cluster array in a large vacuum facility at NASA Glenn Research Center. A series of engineering demonstration tests were performed to evaluate the system performance impacts of operating various multiple-thruster configurations in an array. A suite of diagnostics was installed to investigate multiple-thruster operation impact on thruster performance and life, thermal interactions, and alternative system modes and architectures. The ion beam characterization included measuring ion current density profiles and ion energy distribution with Faraday probes and retarding potential analyzers, respectively. This report focuses on the ion beam characterization during single thruster operation, multiple thruster operation, various neutralizer configurations, and thruster gimbal articulation. Comparison of beam profiles collected during single and multiple thruster operation demonstrated the utility of superimposing single engine beam profiles to predict multi-thruster beam profiles. High energy ions were detected in the region 45 off the thruster axis, independent of thruster power, number of operating thrusters, and facility background pressure, which indicated that the most probable ion energy was not effected by multiple-thruster operation. There were no significant changes to the beam profiles collected during alternate thruster-neutralizer configurations, therefore supporting the viability of alternative system configuration options. Articulation of one thruster shifted its beam profile, whereas the beam profile of a stationary thruster nearby did not change, indicating there were no beam interactions which was consistent with the behavior of a collisionless beam expansion.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Springer, J.; Allen, B.; Wriggins, W.
Coatings play multiple key roles in the proper functioning of mature and current ion implanters. Batch and serial implanters require strategic control of elemental and particulate contamination which often includes scrutiny of the silicon surface coatings encountering direct beam contact. Elastomeric Silicone Coatings must accommodate wafer loading and unloading as well as direct backside contact during implant plus must maintain rigid elemental and particulate specifications. The semiconductor industry has had a significant and continuous effort to obtain ultra-pure silicon coatings with sustained process performance and long life. Low particles and reduced elemental levels for silicon coatings are a major requirementmore » for process engineers, OEM manufacturers, and second source suppliers. Relevant data will be presented. Some emphasis and detail will be placed on the structure and characteristics of a relatively new PVD Silicon Coating process that is very dense and homogeneous. Wear rate under typical ion beam test conditions will be discussed. The PVD Silicon Coating that will be presented here is used on disk shields, wafer handling fingers/fences, exclusion zones of heat sinks, beam dumps and other beamline components. Older, legacy implanters can now provide extended process capability using this new generation PVD silicon - even on implanter systems that were shipped long before the advent of silicon coating for contamination control. Low particles and reduced elemental levels are critical performance criteria for the silicone elastomers used on disk heatsinks and serial implanter platens. Novel evaluation techniques and custom engineered tools are used to investigate the surface interaction characteristics of multiple Elastomeric Silicone Coatings currently in use by the industry - specifically, friction and perpendicular stiction. These parameters are presented as methods to investigate the critical wafer load and unload function. Unique tools and test methods have been developed that deliver accurate and repeatable data, which will be described.« less
NASA Astrophysics Data System (ADS)
Springer, J.; Allen, B.; Wriggins, W.; Kuzbyt, R.; Sinclair, R.
2012-11-01
Coatings play multiple key roles in the proper functioning of mature and current ion implanters. Batch and serial implanters require strategic control of elemental and particulate contamination which often includes scrutiny of the silicon surface coatings encountering direct beam contact. Elastomeric Silicone Coatings must accommodate wafer loading and unloading as well as direct backside contact during implant plus must maintain rigid elemental and particulate specifications. The semiconductor industry has had a significant and continuous effort to obtain ultra-pure silicon coatings with sustained process performance and long life. Low particles and reduced elemental levels for silicon coatings are a major requirement for process engineers, OEM manufacturers, and second source suppliers. Relevant data will be presented. Some emphasis and detail will be placed on the structure and characteristics of a relatively new PVD Silicon Coating process that is very dense and homogeneous. Wear rate under typical ion beam test conditions will be discussed. The PVD Silicon Coating that will be presented here is used on disk shields, wafer handling fingers/fences, exclusion zones of heat sinks, beam dumps and other beamline components. Older, legacy implanters can now provide extended process capability using this new generation PVD silicon - even on implanter systems that were shipped long before the advent of silicon coating for contamination control. Low particles and reduced elemental levels are critical performance criteria for the silicone elastomers used on disk heatsinks and serial implanter platens. Novel evaluation techniques and custom engineered tools are used to investigate the surface interaction characteristics of multiple Elastomeric Silicone Coatings currently in use by the industry - specifically, friction and perpendicular stiction. These parameters are presented as methods to investigate the critical wafer load and unload function. Unique tools and test methods have been developed that deliver accurate and repeatable data, which will be described.
Sources and Losses of Ring Current Ions
NASA Technical Reports Server (NTRS)
Chen, Sheng-Hsien; Fok, Mei-Ching H.; Angeloupoulos, Vassilis
2010-01-01
During geomagnetic quiet times, in-situ measurements of ring current energetic ions (few to few tens of keVs) from THEMIS spacecraft often exhibit multiple ion populations at discrete energies that extend from the inner magnetosphere to the magnetopause at dayside or plasma sheet at nightside. During geomagnetic storm times, the levels of fluxes as well as the mean energies of these ions elevated dramatically and the more smooth distributions in energies and distances during quiet times are disrupted into clusters of ion populations with more confined spatial extends. This reveals local plasma heating processes that might have come into play. Several processes have been proposed. Magnetotail dipolarization, sudden enhancement of field-aligned current, local current disruptions, and plasma waves are possible mechanisms to heat the ions locally as well as strong convections of energetic ions directly from the magnetotail due to reconnections. We will examine two geomagnetic storms on October 11, 2008 and July 22, 2009 to reveal possible heating mechanisms. We will analyze in-situ plasma and magnetic field measurements from THEMIS, GOES, and DMSP for the events to study the ion pitch angle distributions and magnetic field perturbations in the auroral ionosphere and inner magnetosphere where the plasma heating processes occur.
(Surface engineering by high energy beams)
DOE Office of Scientific and Technical Information (OSTI.GOV)
McHargue, C.J.
1989-10-23
A paper entitled Structure-Mechanical Property relationships in Ion-Implanted Ceramics'' was presented at the 2nd International Seminar on Surface Engineering by High Energy Beams in Lisbon, Portugal. This seminar was sponsored by the International Federation of Heat Treatment and Surface Engineering and included discussions on surface modifications using laser, electron, and ion beams. The visit to the University of Lisbon and LNETI-Sacavem included discussions regarding collaborative research in which Professor J.C. Soares and Dr. M.F. da Silva would conduct perturbed angular correlation (PAC) studies on ion-implanted samples supplied by the traveler. The collaboration between researchers at ORNL and the University Claudemore » Bernard-Lyon 1 (France) continues. Data were analyzed during this visit, plans for further experiments were developed, and a paper was drafted for publication.« less
Air Intake Performance of Air Breathing Ion Engines
NASA Astrophysics Data System (ADS)
Fujita, Kazuhisa
The air breathing ion engine (ABIE) is a new type of electric propulsion system which can be used to compensate the aerodynamic drag of the satellite orbiting at extremely low altitudes. In this propulsion system, the low-density atmosphere surrounding the satellite is taken in and used as the propellant of ion engines to reduce the propellant mass for a long operation lifetime. Since feasibility and performance of the ABIE are subject to the compression ratio and the air intake efficiency, a numerical analysis has been conducted by means of the direct-simulation Monte-Carlo method to clarify the characteristics of the air-intake performance in highly rarefied flows. Influences of the flight altitude, the aspect-ratio of the air intake duct, the angle of attack, and the wall conditions are investigated.
Moroni, Mirko; Biro, Istvan; Giugliano, Michele; Vijayan, Ranjit; Biggin, Philip C.; Beato, Marco; Sivilotti, Lucia G.
2011-01-01
In the vertebrate CNS, fast synaptic inhibition is mediated by GABA and glycine receptors. We recently reported that the time course of these synaptic currents is slower when intracellular chloride is high. Here we extend these findings to measure the effects of both extracellular and intracellular chloride on the deactivation of glycine and GABA currents at both negative and positive holding potentials. Currents were elicited by fast agonist application to outside-out patches from HEK293 cells expressing rat glycine or GABA receptors. The slowing effect of high extracellular chloride on current decay was detectable only in low intracellular chloride (4 mM). Our main finding is that glycine and GABA receptors “sense” chloride concentrations because of interactions between the M2 pore-lining domain and the permeating ions. This hypothesis is supported by the observation that the sensitivity of channel gating to intracellular chloride is abolished if the channel is engineered to become cation-selective, or if positive charges in the external pore vestibule are eliminated by mutagenesis. The appropriate interaction between permeating ions and channel pore is also necessary to maintain the channel voltage sensitivity of gating, which prolongs current decay at depolarized potentials. Voltage-dependence is abolished by the same mutations that suppress the effect of intracellular chloride and also by replacing chloride with another permeant ion, thiocyanate. These observations suggest that permeant chloride affects gating by a foot-in-the-door effect, binding to a channel site with asymmetrical access from the intracellular and extracellular sides of the membrane. PMID:21976494
Ion-ion Recombination and Chemiion Concentrations In Aircraft Exhaust
NASA Astrophysics Data System (ADS)
Turco, R. P.; Yu, F.
Jet aircraft emit large quantities of ultrafine volatile aerosols, as well as soot parti- cles, into the environment. To determine the long-term effects of these emissions, a better understanding of the mechanisms that control particle formation and evolution is needed, including the number and size dispersion. A recent explanation for aerosol nucleation in a jet wake involves the condensation of sulfuric acid vapor, and cer- tain organic compounds, onto charged molecular clusters (chemiions) generated in the engine combustors (Yu and Turco, 1997). Massive charged aggregates, along with sulfuric acid and organic precursor vapors, have been detected in jet plumes under cruise conditions. In developing the chemiion nucleation theory, Yu and Turco noted that ion-ion recombination in the engine train and jet core should limit the chemiion emission index to 1017/kg-fuel. This value is consistent with ion-ion recombination coefficients of 1×10-7 cm3/s over time scales of 10-2 s. However, the evolution of the ions through the engine has not been adequately studied. The conditions at the combustor exit are extreme-temperatures approach 1500 K, and pressures can reach 30 atmospheres. In this presentation, we show that as the combustion gases expand and cool, two- and three-body ion-ion recombination processes control the chemiion concentration. The concepts of mutual neutralization and Thomson recombination are first summarized, and appropriate temperature and pressure dependent recombination rate coefficients are derived for the aircraft problem. A model for ion losses in jet exhaust is then formulated using an "invariance" principle discussed by Turco and Yu (1997) in the context of a coagulating aerosol in an expanding plume. This recombina- tion model is applied to estimate chemiion emission indices for a range of operational engine conditions. The predicted ion emission rates are found to be consistent with observations. We discuss the sources of variance in chemiion exhaust concentrations based on the physical processes occurring in the exhaust stream. References: Turco, R. P., and F. Yu, Aerosol invariance in expanding, coagulating plumes, Geo- phys. Res. Lett., 24, 1223-1226, 1997. Yu, F., and R. P. Turco, The role of ions in the formation and evolution of particles in aircraft plumes, Geophys. Res. Lett., 24, 1927-1930, 1997.
Transportation Research News | Transportation News | Transportation
Engineering has yielded new insights for lithium-ion (Li-ion) battery electrodes at the microstructural level -Phase Stochastics in Lithium-Ion Battery Electrodes" detailing the research and resulting revolutionizes the way lithium-ion (Li-ion) batteries are evaluated so designs can be improved before batteries
Model-Based Engine Control Architecture with an Extended Kalman Filter
NASA Technical Reports Server (NTRS)
Csank, Jeffrey T.; Connolly, Joseph W.
2016-01-01
This paper discusses the design and implementation of an extended Kalman filter (EKF) for model-based engine control (MBEC). Previously proposed MBEC architectures feature an optimal tuner Kalman Filter (OTKF) to produce estimates of both unmeasured engine parameters and estimates for the health of the engine. The success of this approach relies on the accuracy of the linear model and the ability of the optimal tuner to update its tuner estimates based on only a few sensors. Advances in computer processing are making it possible to replace the piece-wise linear model, developed off-line, with an on-board nonlinear model running in real-time. This will reduce the estimation errors associated with the linearization process, and is typically referred to as an extended Kalman filter. The non-linear extended Kalman filter approach is applied to the Commercial Modular Aero-Propulsion System Simulation 40,000 (C-MAPSS40k) and compared to the previously proposed MBEC architecture. The results show that the EKF reduces the estimation error, especially during transient operation.
Model-Based Engine Control Architecture with an Extended Kalman Filter
NASA Technical Reports Server (NTRS)
Csank, Jeffrey T.; Connolly, Joseph W.
2016-01-01
This paper discusses the design and implementation of an extended Kalman filter (EKF) for model-based engine control (MBEC). Previously proposed MBEC architectures feature an optimal tuner Kalman Filter (OTKF) to produce estimates of both unmeasured engine parameters and estimates for the health of the engine. The success of this approach relies on the accuracy of the linear model and the ability of the optimal tuner to update its tuner estimates based on only a few sensors. Advances in computer processing are making it possible to replace the piece-wise linear model, developed off-line, with an on-board nonlinear model running in real-time. This will reduce the estimation errors associated with the linearization process, and is typically referred to as an extended Kalman filter. The nonlinear extended Kalman filter approach is applied to the Commercial Modular Aero-Propulsion System Simulation 40,000 (C-MAPSS40k) and compared to the previously proposed MBEC architecture. The results show that the EKF reduces the estimation error, especially during transient operation.
Long-pore Electrostatics in Inward-rectifier Potassium Channels
Robertson, Janice L.; Palmer, Lawrence G.; Roux, Benoît
2008-01-01
Inward-rectifier potassium (Kir) channels differ from the canonical K+ channel structure in that they possess a long extended pore (∼85 Å) for ion conduction that reaches deeply into the cytoplasm. This unique structural feature is presumably involved in regulating functional properties specific to Kir channels, such as conductance, rectification block, and ligand-dependent gating. To elucidate the underpinnings of these functional roles, we examine the electrostatics of an ion along this extended pore. Homology models are constructed based on the open-state model of KirBac1.1 for four mammalian Kir channels: Kir1.1/ROMK, Kir2.1/IRK, Kir3.1/GIRK, and Kir6.2/KATP. By solving the Poisson-Boltzmann equation, the electrostatic free energy of a K+ ion is determined along each pore, revealing that mammalian Kir channels provide a favorable environment for cations and suggesting the existence of high-density regions in the cytoplasmic domain and cavity. The contribution from the reaction field (the self-energy arising from the dielectric polarization induced by the ion's charge in the complex geometry of the pore) is unfavorable inside the long pore. However, this is well compensated by the electrostatic interaction with the static field arising from the protein charges and shielded by the dielectric surrounding. Decomposition of the static field provides a list of residues that display remarkable correspondence with existing mutagenesis data identifying amino acids that affect conduction and rectification. Many of these residues demonstrate interactions with the ion over long distances, up to 40 Å, suggesting that mutations potentially affect ion or blocker energetics over the entire pore. These results provide a foundation for understanding ion interactions in Kir channels and extend to the study of ion permeation, block, and gating in long, cation-specific pores. PMID:19001143
Moriwaki, Hiroshi; Masuda, Reiko; Yamazaki, Yuki; Horiuchi, Kaoru; Miyashita, Mari; Kasahara, Jun; Tanaka, Tatsuhito; Yamamoto, Hiroki
2016-10-12
The adsorption behaviors of the rare earth metal ions onto freeze-dried powders of genetically engineered microbial strains were compared. Cell powders obtained from four kinds of strains, Bacillus subtilis 168 wild type (WT), lipoteichoic acid-defective (ΔLTA), wall teichoic acid-defective (ΔWTA), and cell wall hydrolases-defective (EFKYOJLp) strains, were used as an adsorbent of the rare earth metal ions at pH 3. The adsorption ability of the rare earth metal ions was in the order of EFKYOJLp > WT > ΔLTA > ΔWTA. The order was the same as the order of the phosphorus quantity of the strains. This result indicates that the main adsorption sites for the ions are the phosphate groups and the teichoic acids, LTA and WTA, that contribute to the adsorption of the rare earth metal ions onto the cell walls. The contribution of WTA was clearly greater than that of LTA. Each microbial powder was added to a solution containing 16 kinds of rare earth metal ions, and the removals (%) of each rare earth metal ion were obtained. The scandium ion showed the highest removal (%), while that of the lanthanum ion was the lowest for all the microbial powders. Differences in the distribution coefficients between the kinds of lanthanide ions by the EFKYOJLp and ΔWTA powders were greater than those of the other strains. Therefore, the EFKYOJLp and ΔWTA powders could be applicable for the selective extraction of the lanthanide ions. The ΔLTA powder coagulated by mixing with a rare earth metal ion, although no sedimentation of the WT or ΔWTA powder with a rare earth metal ion was observed under the same conditions. The EFKYOJLp powder was also coagulated, but its flocculating activity was lower than that of ΔLTA. The ΔLTA and EFKYOJLp powders have a long shape compared to those of the WT or ΔWTA strain. The shapes of the cells will play an important role in the sedimentation of the microbial powders with rare earth metal ions. As the results, three kinds of the genetically engineered microbial powders revealed unique adsorption behaviors of the rare earth metal ions.
Federal Register 2010, 2011, 2012, 2013, 2014
2011-07-13
... Company Model M680 Airplane; Lithium-ion Battery Installations AGENCY: Federal Aviation Administration... design feature associated with Lithium-ion batteries. The applicable airworthiness regulations do not...) T00012WI for installation of Lithium-ion batteries in the Model 680. The Model 680 is a twin-engine, medium...
Boggs, D.L.; Baraszu, D.J.; Foulkes, D.M.; Gomes, E.G.
1998-12-29
An internal combustion engine includes separated oil drain-back and crankcase ventilation passages. The oil drain-back passages extend from the cylinder head to a position below the top level of oil in the engine`s crankcase. The crankcase ventilation passages extend from passages formed in the main bearing bulkheads from positions above the oil level in the crankcase and ultimately through the cylinder head. Oil dams surrounding the uppermost portions of the crankcase ventilation passages prevent oil from running downwardly through the crankcase ventilation passages. 4 figs.
Status of the NEXT Ion Thruster Long-Duration Test After 10,100 hr and 207 kg Demonstrated
NASA Technical Reports Server (NTRS)
Herman, Daniel A.; Soulas, George C.; Patterson, Michael J.
2008-01-01
The NASA s Evolutionary Xenon Thruster (NEXT) program is developing the next-generation ion propulsion system with significant enhancements beyond the state-of-the-art in ion propulsion to provide future NASA science missions with enhanced mission capabilities at a low total development cost. As part of a comprehensive thruster service life assessment utilizing both testing and analyses, a Long-Duration Test (LDT) was initiated to validate and qualify the NEXT propellant throughput capability to a qualification-level of 450 kg, 1.5 times the mission-derived throughput requirement of 300 kg. This wear test is being conducted with a modified, flight-representative NEXT engineering model ion thruster, designated EM3. As of June 21, 2007, the thruster has accumulated 10,100 hr of operation at the thruster full-input-power of 6.9 kW with 3.52 A beam current and 1800 V beam power supply voltage. The thruster has processed 207 kg of xenon and demonstrated a total impulse of 8.5 106 N-s; the highest total impulse ever demonstrated by an ion thruster in the history of space propulsion. Thruster performance tests are conducted periodically over the entire NEXT throttle table with input power ranging 0.5 to 6.9 kW. Overall ion thruster performance parameters including thrust, input power, specific impulse, and thruster efficiency have been nominal with little variation to date. Lifetime-limiting component erosion rates have been consistent with the NEXT service life assessment, which predicts the earliest failure sometime after 750 kg of xenon propellant throughput; well beyond the mission-derived lifetime requirement. The NEXT wear test data confirm that the erosion of the discharge keeper orifice, enlarging of nominal-current-density accelerator grid aperture cusps, and the decrease in cold grid-gap observed during the NSTAR Extended Life Test have been mitigated. This paper presents the status of the NEXT LDT to date.
Ruthenium oxide ion selective thin-film electrodes for engine oil acidity monitoring
NASA Astrophysics Data System (ADS)
Maurya, D. K.; Sardarinejad, A.; Alameh, K.
2015-06-01
We demonstrate the concept of a low-cost, rugged, miniaturized ion selective electrode (ISE) comprising a thin film RuO2 on platinum sensing electrode deposited using RF magnetron sputtered in conjunction with an integrated Ag/AgCl and Ag reference electrodes for engine oil acidity monitoring. Model oil samples are produced by adding nitric acid into fresh fully synthetic engine oil and used for sensor evaluation. Experimental results show a linear potential-versus-acid-concentration response for nitric acid concentration between 0 (fresh oil) to 400 ppm, which demonstrate the accuracy of the RuO2 sensor in real-time operation, making it attractive for use in cars and industrial engines.
NASA Astrophysics Data System (ADS)
Budzyński, P.; Kamiński, M.; Pyszniak, K.
2016-09-01
The implantation of nitrogen, carbon, and oxygen can be used for enhancing the tribological properties of critical components for internal combustion engines. Hardox and Raex steels have very similar strength parameters as for steel used for piston rings in internal combustion engines. An essential criterion when selecting material for the production of piston rings is a low friction factor and a low wear index. The aim of this study was to determine the extent to which these parameters can be enhanced by nitrogen ion implantation. Samples were implanted with nitrogen ions with 65 keV energy and the fluence of implanted ions set to 1.1017 N + /cm2. Friction and wear measurements were performed on a pin-on disc stand. The results demonstrate that implantation with nitrogen ions significantly reduces the friction factor and wear of Hardox 450 and Raex 400 steels. Implantation can and should be used for enhancing the tribological properties of steel used for friction elements in internal combustion engines, particularly when heat treatment is excluded. Final elements can be subjected to implantation, as the process does not change their dimensions.
Fully-kinetic Ion Simulation of Global Electrostatic Turbulent Transport in C-2U
NASA Astrophysics Data System (ADS)
Fulton, Daniel; Lau, Calvin; Bao, Jian; Lin, Zhihong; Tajima, Toshiki; TAE Team
2017-10-01
Understanding the nature of particle and energy transport in field-reversed configuration (FRC) plasmas is a crucial step towards an FRC-based fusion reactor. The C-2U device at Tri Alpha Energy (TAE) achieved macroscopically stable plasmas and electron energy confinement time which scaled favorably with electron temperature. This success led to experimental and theoretical investigation of turbulence in C-2U, including gyrokinetic ion simulations with the Gyrokinetic Toroidal Code (GTC). A primary objective of TAE's new C-2W device is to explore transport scaling in an extended parameter regime. In concert with the C-2W experimental campaign, numerical efforts have also been extended in A New Code (ANC) to use fully-kinetic (FK) ions and a Vlasov-Poisson field solver. Global FK ion simulations are presented. Future code development is also discussed.
Charged particle measurements on a 30-CM diameter mercury ion engine thrust beam
NASA Technical Reports Server (NTRS)
Sellen, J. M., Jr.; Komatsu, G. K.; Hoffmaster, D. K.; Kemp, R. F.
1974-01-01
Measurements of both thrust ions and charge exchange ions were made in the beam of a 30 centimeter diameter electron bombardment mercury ion thruster. A qualitative model is presented which describes magnitudes of charge exchange ion formation and motions of these ions in the weak electric field structure of the neutralized thrust beam plasma. Areas of agreement and discrepancy between observed and modeled charge exchange properties are discussed.
INTERIOR VIEW WITH GRINDING MILL AND CONVEYOR EXTENDING UP TO ...
INTERIOR VIEW WITH GRINDING MILL AND CONVEYOR EXTENDING UP TO SORTING DRUM. DRIVE ENGINE AT LOWER LEFT. RADIATOR FOR ENGINE AT RIGHT. - F. & H. Benning Company Oyster Mill, 14430 Solomons Island Road (moved from 1014 Benning Road, Galesville, Anne Arundel County, Maryland), Solomons, Calvert County, MD
ERIC Educational Resources Information Center
Juricic, Davor; Barr, Ronald E.
1996-01-01
Reports on a project that extended the Engineering Design Graphics curriculum to include instruction and laboratory experience in computer-aided design, analysis, and manufacturing (CAD/CAM). Discusses issues in project implementation, including introduction of finite element analysis to lower-division students, feasibility of classroom prototype…
Systems for delivering liquified natural gas to an engine
Bingham, Dennis N.; Wilding, Bruce M.; O'Brien, James E.; Siahpush, Ali S.; Brown, Kevin B.
2000-01-01
A fuel delivery system includes a fuel tank configured to receive liquid natural gas. A first conduit extends from a vapor holding portion of the fuel tank to an economizer valve. A second conduit extends from a liquid holding portion of the fuel tank to the economizer valve. Fluid coupled to the economizer valve is a vaporizer which is heated by coolant from the engine and is positioned below the fuel tank. The economizer valve selectively withdraws either liquid natural gas or vaporized natural gas from the fuel tank depending on the pressure within the vapor holding portion of the fuel tank. A delivery conduit extends from the vaporizer to the engine. A return conduit having a check valve formed therein extends from the delivery conduit to the vapor holding portion of the fuel tank for pressurizing the fuel tank.
Coulomb interaction rules timescales in potassium ion channel tunneling
NASA Astrophysics Data System (ADS)
De March, N.; Prado, S. D.; Brunnet, L. G.
2018-06-01
Assuming the selectivity filter of KcsA potassium ion channel may exhibit quantum coherence, we extend a previous model by Vaziri and Plenio (2010 New J. Phys. 12 085001) to take into account Coulomb repulsion between potassium ions. We show that typical ion transit timescales are determined by this interaction, which imposes optimal input/output parameter ranges. Also, as observed in other examples of quantum tunneling in biological systems, the addition of moderate noise helps coherent ion transport.
Space Electric Research Test in the Electric Propulsion Laboratory
1964-06-21
Technicians prepare the Space Electric Research Test (SERT-I) payload for a test in Tank Number 5 of the Electric Propulsion Laboratory at the National Aeronautics and Space Administration (NASA) Lewis Research Center. Lewis researchers had been studying different methods of electric rocket propulsion since the mid-1950s. Harold Kaufman created the first successful engine, the electron bombardment ion engine, in the early 1960s. These electric engines created and accelerated small particles of propellant material to high exhaust velocities. Electric engines have a very small amount of thrust, but once lofted into orbit by workhorse chemical rockets, they are capable of small, continuous thrust for periods up to several years. The electron bombardment thruster operated at a 90-percent efficiency during testing in the Electric Propulsion Laboratory. The package was rapidly rotated in a vacuum to simulate its behavior in space. The SERT-I mission, launched from Wallops Island, Virginia, was the first flight test of Kaufman’s ion engine. SERT-I had one cesium engine and one mercury engine. The suborbital flight was only 50 minutes in duration but proved that the ion engine could operate in space. The Electric Propulsion Laboratory included two large space simulation chambers, one of which is seen here. Each uses twenty 2.6-foot diameter diffusion pumps, blowers, and roughing pumps to remove the air inside the tank to create the thin atmosphere. A helium refrigeration system simulates the cold temperatures of space.
Convoluted nozzle design for the RL10 derivative 2B engine
NASA Technical Reports Server (NTRS)
1985-01-01
The convoluted nozzle is a conventional refractory metal nozzle extension that is formed with a portion of the nozzle convoluted to show the extendible nozzle within the length of the rocket engine. The convoluted nozzle (CN) was deployed by a system of four gas driven actuators. For spacecraft applications the optimum CN may be self-deployed by internal pressure retained, during deployment, by a jettisonable exit closure. The convoluted nozzle is included in a study of extendible nozzles for the RL10 Engine Derivative 2B for use in an early orbit transfer vehicle (OTV). Four extendible nozzle configurations for the RL10-2B engine were evaluated. Three configurations of the two position nozzle were studied including a hydrogen dump cooled metal nozzle and radiation cooled nozzles of refractory metal and carbon/carbon composite construction respectively.
Ion Mobility Separation of Variant Histone Tails Extending to the “Middle-down” Range
Shvartsburg, Alexandre A.; Zheng, Yupeng; Smith, Richard D.; Kelleher, Neil L.
2012-01-01
Differential ion mobility spectrometry (FAIMS) can baseline-resolve multiple variants of post-translationally modified peptides extending to the 3 - 4 kDa range, which differ in the localization of a PTM as small as acetylation. Essentially orthogonal separations for different charge states expand the total peak capacity in proportion to the number of observed states that increases for longer polypeptides. This might enable resolving localization variants for yet larger peptides and even intact proteins. PMID:22559289
Separation of organic ion exchange resins from sludge -- engineering study
DOE Office of Scientific and Technical Information (OSTI.GOV)
Duncan, J.B.
1998-08-25
This engineering study evaluates the use of physical separation technologies to separate organic ion exchange resin from KE Basin sludge prior to nitric acid dissolution. This separation is necessitate to prevent nitration of the organics in the acid dissolver. The technologies under consideration are: screening, sedimentation, elutriation. The recommended approach is to first screen the Sludge and resin 300 microns then subject the 300 microns plus material to elutriation.
Balogun, Muhammad-Sadeeq; Luo, Yang; Lyu, Feiyi; Wang, Fuxin; Yang, Hao; Li, Haibo; Liang, Chaolun; Huang, Miao; Huang, Yongchao; Tong, Yexiang
2016-04-20
The use of electrode materials in their powdery form requires binders and conductive additives for the fabrication of the cells, which leads to unsatisfactory energy storage performance. Recently, a new strategy to design flexible, binder-, and additive-free three-dimensional electrodes with nanoscale surface engineering has been exploited in boosting the storage performance of electrode materials. In this paper, we design a new type of free-standing carbon quantum dot coated VO2 interwoven nanowires through a simple fabrication process and demonstrate its potential to be used as cathode material for lithium and sodium ion batteries. The versatile carbon quantum dots that are vastly flexible for surface engineering serve the function of protecting the nanowire surface and play an important role in the diffusion of electrons. Also, the three-dimensional carbon cloth coated with VO2 interwoven nanowires assisted in the diffusion of ions through the inner and the outer surface. With this unique architecture, the carbon quantum dot nanosurface engineered VO2 electrode exhibited capacities of 420 and 328 mAh g(-1) at current density rate of 0.3 C for lithium and sodium storage, respectively. This work serves as a milestone for the potential replacement of lithium ion batteries and next generation postbatteries.
30 cm Engineering Model thruster design and qualification tests
NASA Technical Reports Server (NTRS)
Schnelker, D. E.; Collett, C. R.
1975-01-01
Development of a 30-cm mercury electron bombardment Engineering Model ion thruster has successfully brought the thruster from the status of a laboratory experimental device to a point approaching flight readiness. This paper describes the development progress of the Engineering Model (EM) thruster in four areas: (1) design features and fabrication approaches, (2) performance verification and thruster to thruster variations, (3) structural integrity, and (4) interface definition. The design of major subassemblies, including the cathode-isolator-vaporizer (CIV), main isolator-vaporizer (MIV), neutralizer isolator-vaporizer (NIV), ion optical system, and discharge chamber/outer housing is discussed along with experimental results.
NASA Technical Reports Server (NTRS)
Sovey, J.
1997-01-01
Time-resolved, in situ measurements of the charge exchange ion erosion pattern on the downstream face of the accelerator grid have been made during an ongoin wear test of the NSTAR 30 cm ion thruster.
NASA Technical Reports Server (NTRS)
Manzo, Michelle A.
2007-01-01
In 2007, the NASA Engineering Safety Center (NESC) chartered the NASA Aerospace Flight Battery Systems Working Group to bring forth and address critical battery-related performance/manufacturing issues for NASA and the aerospace community. A suite of tasks identifying and addressing issues related to Ni-H2 and Li-ion battery chemistries was submitted and selected for implementation. The current NESC funded are: (1) Wet Life of Ni-H2 Batteries (2) Binding Procurement (3) NASA Lithium-Ion Battery Guidelines (3a) Li-Ion Performance Assessment (3b) Li-Ion Guidelines Document (3b-i) Assessment of Applicability of Pouch Cells for Aerospace Missions (3b-ii) High Voltage Risk Assessment (3b-iii) Safe Charge Rates for Li-Ion Cells (4) Availability of Source Material for Li-Ion Cells (5) NASA Aerospace Battery Workshop This presentation provides a brief overview of the tasks in the 2007 plan and serves as an introduction to more detailed discussions on each of the specific tasks.
Sandia technology: Engineering and science applications
NASA Astrophysics Data System (ADS)
Maydew, M. C.; Parrot, H.; Dale, B. C.; Floyd, H. L.; Leonard, J. A.; Parrot, L.
1990-12-01
This report discusses: protecting environment, safety, and health; Sandia's quality initiative; Sandia vigorously pursues technology transfer; scientific and technical education support programs; nuclear weapons development; recognizing battlefield targets with trained artificial neural networks; battlefield robotics: warfare at a distance; a spinning shell sizes up the enemy; thwarting would-be nuclear terrorists; unattended video surveillance system for nuclear facilities; making the skies safer for travelers; onboard instrumentation system to evaluate performance of stockpile bombs; keeping track with lasers; extended-life lithium batteries; a remote digital video link acquires images securely; guiding high-performance missiles with laser gyroscopes; nonvolatile memory chips for space applications; initiating weapon explosives with lasers; next-generation optoelectronics and microelectronics technology developments; chemometrics: new methods for improving chemical analysis; research team focuses ion beam to record-breaking intensities; standardizing the volt to quantum accuracy; new techniques improve robotic software development productivity; a practical laser plasma source for generating soft x-rays; exploring metal grain boundaries; massively parallel computing; modeling the amount of desiccant needed for moisture control; attacking pollution with sunshine; designing fuel-conversion catalysts with computers; extending a nuclear power plant's useful life; plasma-facing components for the International Thermonuclear Experimental Reactor.
Engineering Heteromaterials to Control Lithium Ion Transport Pathways
Liu, Yang; Vishniakou, Siarhei; Yoo, Jinkyoung; ...
2015-12-21
Safe and efficient operation of lithium ion batteries requires precisely directed flow of lithium ions and electrons to control the first directional volume changes in anode and cathode materials. Understanding and controlling the lithium ion transport in battery electrodes becomes crucial to the design of high performance and durable batteries. Some recent work revealed that the chemical potential barriers encountered at the surfaces of heteromaterials play an important role in directing lithium ion transport at nanoscale. We utilize in situ transmission electron microscopy to demonstrate that we can switch lithiation pathways from radial to axial to grain-by-grain lithiation through themore » systematic creation of heteromaterial combinations in the Si-Ge nanowire system. Furthermore, our systematic studies show that engineered materials at nanoscale can overcome the intrinsic orientation-dependent lithiation, and open new pathways to aid in the development of compact, safe, and efficient batteries.« less
Engineering Heteromaterials to Control Lithium Ion Transport Pathways
Liu, Yang; Vishniakou, Siarhei; Yoo, Jinkyoung; Dayeh, Shadi A.
2015-01-01
Safe and efficient operation of lithium ion batteries requires precisely directed flow of lithium ions and electrons to control the first directional volume changes in anode and cathode materials. Understanding and controlling the lithium ion transport in battery electrodes becomes crucial to the design of high performance and durable batteries. Recent work revealed that the chemical potential barriers encountered at the surfaces of heteromaterials play an important role in directing lithium ion transport at nanoscale. Here, we utilize in situ transmission electron microscopy to demonstrate that we can switch lithiation pathways from radial to axial to grain-by-grain lithiation through the systematic creation of heteromaterial combinations in the Si-Ge nanowire system. Our systematic studies show that engineered materials at nanoscale can overcome the intrinsic orientation-dependent lithiation, and open new pathways to aid in the development of compact, safe, and efficient batteries. PMID:26686655
Ion propulsion engine installed on Deep Space 1 at CCAS
NASA Technical Reports Server (NTRS)
1998-01-01
Workers at the Defense Satellite Communications System Processing Facility (DPF), Cape Canaveral Air Station (CCAS), attach a strap during installation of the ion propulsion engine on Deep Space 1. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century, including the engine. Propelled by the gas xenon, the engine is being flight-tested for future deep space and Earth-orbiting missions. Deceptively powerful, the ion drive emits only an eerie blue glow as ionized atoms of xenon are pushed out of the engine. While slow to pick up speed, over the long haul it can deliver 10 times as much thrust per pound of fuel as liquid or solid fuel rockets. Other onboard experiments include software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. Deep Space 1 will complete most of its mission objectives within the first two months, but will also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched aboard a Boeing Delta 7326 rocket from Launch Pad 17A, CCAS, in October.
Ion propulsion engine installed on Deep Space 1 at CCAS
NASA Technical Reports Server (NTRS)
1998-01-01
Workers in the Defense Satellite Communications Systems Processing Facility (DPF) at Cape Canaveral Air Station (CCAS) finish installing the ion propulsion engine on Deep Space 1. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century, including the engine. Propelled by the gas xenon, the engine is being flight-tested for future deep space and Earth-orbiting missions. Deceptively powerful, the ion drive emits only an eerie blue glow as ionized atoms of xenon are pushed out of the engine. While slow to pick up speed, over the long haul it can deliver 10 times as much thrust per pound of fuel as liquid or solid fuel rockets. Other onboard experiments include software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. Deep Space 1 will complete most of its mission objectives within the first two months, but will also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched Oct. 25 aboard a Boeing Delta 7326 rocket from Launch Pad 17A, CCAS.
Ion propulsion engine installed on Deep Space 1 at CCAS
NASA Technical Reports Server (NTRS)
1998-01-01
Workers at the Defense Satellite Communications System Processing Facility (DPF), Cape Canaveral Air Station (CCAS), maneuver the ion propulsion engine into place before installation on Deep Space 1. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century, including the engine. Propelled by the gas xenon, the engine is being flight- tested for future deep space and Earth-orbiting missions. Deceptively powerful, the ion drive emits only an eerie blue glow as ionized atoms of xenon are pushed out of the engine. While slow to pick up speed, over the long haul it can deliver 10 times as much thrust per pound of fuel as liquid or solid fuel rockets. Other onboard experiments include software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. Deep Space 1 will complete most of its mission objectives within the first two months, but will also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched aboard a Boeing Delta 7326 rocket from Launch Pad 17A, CCAS, in October.
Ion propulsion engine installed on Deep Space 1 at CCAS
NASA Technical Reports Server (NTRS)
1998-01-01
Workers at the Defense Satellite Communications System Processing Facility (DPF), Cape Canaveral Air Station (CCAS), install an ion propulsion engine on Deep Space 1. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century, including the engine. Propelled by the gas xenon, the engine is being flight-tested for future deep space and Earth-orbiting missions. Deceptively powerful, the ion drive emits only an eerie blue glow as ionized atoms of xenon are pushed out of the engine. While slow to pick up speed, over the long haul it can deliver 10 times as much thrust per pound of fuel as liquid or solid fuel rockets. Other onboard experiments include software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. Deep Space 1 will complete most of its mission objectives within the first two months, but will also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched aboard a Boeing Delta 7326 rocket from Launch Pad 17A, CCAS, in October.
Ion propulsion engine installed on Deep Space 1 at CCAS
NASA Technical Reports Server (NTRS)
1998-01-01
Workers in the Defense Satellite Communications Systems Processing Facility (DPF) at Cape Canaveral Air Station (CCAS) make adjustments while installing the ion propulsion engine on Deep Space 1. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century, including the engine. Propelled by the gas xenon, the engine is being flight- tested for future deep space and Earth-orbiting missions. Deceptively powerful, the ion drive emits only an eerie blue glow as ionized atoms of xenon are pushed out of the engine. While slow to pick up speed, over the long haul it can deliver 10 times as much thrust per pound of fuel as liquid or solid fuel rockets. Other onboard experiments include software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. Deep Space 1 will complete most of its mission objectives within the first two months, but will also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched Oct. 25 aboard a Boeing Delta 7326 rocket from Launch Pad 17A, CCAS.
Ion propulsion engine installed on Deep Space 1 at CCAS
NASA Technical Reports Server (NTRS)
1998-01-01
Workers at the Defense Satellite Communications System Processing Facility (DPF), Cape Canaveral Air Station (CCAS), make adjustments while installing the ion propulsion engine on Deep Space 1. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century, including the engine. Propelled by the gas xenon, the engine is being flight- tested for future deep space and Earth-orbiting missions. Deceptively powerful, the ion drive emits only an eerie blue glow as ionized atoms of xenon are pushed out of the engine. While slow to pick up speed, over the long haul it can deliver 10 times as much thrust per pound of fuel as liquid or solid fuel rockets. Other onboard experiments include software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. Deep Space 1 will complete most of its mission objectives within the first two months, but will also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched aboard a Boeing Delta 7326 rocket from Launch Pad 17A, CCAS, in October.
Nonlinear Control of a Reusable Rocket Engine for Life Extension
NASA Technical Reports Server (NTRS)
Lorenzo, Carl F.; Holmes, Michael S.; Ray, Asok
1998-01-01
This paper presents the conceptual development of a life-extending control system where the objective is to achieve high performance and structural durability of the plant. A life-extending controller is designed for a reusable rocket engine via damage mitigation in both the fuel (H2) and oxidizer (O2) turbines while achieving high performance for transient responses of the combustion chamber pressure and the O2/H2 mixture ratio. The design procedure makes use of a combination of linear and nonlinear controller synthesis techniques and also allows adaptation of the life-extending controller module to augment a conventional performance controller of the rocket engine. The nonlinear aspect of the design is achieved using non-linear parameter optimization of a prescribed control structure. Fatigue damage in fuel and oxidizer turbine blades is primarily caused by stress cycling during start-up, shutdown, and transient operations of a rocket engine. Fatigue damage in the turbine blades is one of the most serious causes for engine failure.
Toghraee, Reza; Lee, Kyu-Il; Papke, David; Chiu, See-Wing; Jakobsson, Eric; Ravaioli, Umberto
2009-01-01
Ion channels, as natures’ solution to regulating biological environments, are particularly interesting to device engineers seeking to understand how natural molecular systems realize device-like functions, such as stochastic sensing of organic analytes. What’s more, attaching molecular adaptors in desired orientations inside genetically engineered ion channels, enhances the system functionality as a biosensor. In general, a hierarchy of simulation methodologies is needed to study different aspects of a biological system like ion channels. Biology Monte Carlo (BioMOCA), a three-dimensional coarse-grained particle ion channel simulator, offers a powerful and general approach to study ion channel permeation. BioMOCA is based on the Boltzmann Transport Monte Carlo (BTMC) and Particle-Particle-Particle-Mesh (P3M) methodologies developed at the University of Illinois at Urbana-Champaign. In this paper, we have employed BioMOCA to study two engineered mutations of α-HL, namely (M113F)6(M113C-D8RL2)1-β-CD and (M113N)6(T117C-D8RL3)1-β-CD. The channel conductance calculated by BioMOCA is slightly higher than experimental values. Permanent charge distributions and the geometrical shape of the channels gives rise to selectivity towards anions and also an asymmetry in I-V curves, promoting a rectification largely for cations. PMID:20938493
Extending Serum Half-life of Albumin by Engineering Neonatal Fc Receptor (FcRn) Binding*
Andersen, Jan Terje; Dalhus, Bjørn; Viuff, Dorthe; Ravn, Birgitte Thue; Gunnarsen, Kristin Støen; Plumridge, Andrew; Bunting, Karen; Antunes, Filipa; Williamson, Rebecca; Athwal, Steven; Allan, Elizabeth; Evans, Leslie; Bjørås, Magnar; Kjærulff, Søren; Sleep, Darrell; Sandlie, Inger; Cameron, Jason
2014-01-01
A major challenge for the therapeutic use of many peptides and proteins is their short circulatory half-life. Albumin has an extended serum half-life of 3 weeks because of its size and FcRn-mediated recycling that prevents intracellular degradation, properties shared with IgG antibodies. Engineering the strictly pH-dependent IgG-FcRn interaction is known to extend IgG half-life. However, this principle has not been extensively explored for albumin. We have engineered human albumin by introducing single point mutations in the C-terminal end that generated a panel of variants with greatly improved affinities for FcRn. One variant (K573P) with 12-fold improved affinity showed extended serum half-life in normal mice, mice transgenic for human FcRn, and cynomolgus monkeys. Importantly, favorable binding to FcRn was maintained when a single-chain fragment variable antibody was genetically fused to either the N- or the C-terminal end. The engineered albumin variants may be attractive for improving the serum half-life of biopharmaceuticals. PMID:24652290
NEXT Single String Integration Test Results
NASA Technical Reports Server (NTRS)
Soulas, George C.; Patterson, Michael J.; Pinero, Luis; Herman, Daniel A.; Snyder, Steven John
2010-01-01
As a critical part of NASA's Evolutionary Xenon Thruster (NEXT) test validation process, a single string integration test was performed on the NEXT ion propulsion system. The objectives of this test were to verify that an integrated system of major NEXT ion propulsion system elements meets project requirements, to demonstrate that the integrated system is functional across the entire power processor and xenon propellant management system input ranges, and to demonstrate to potential users that the NEXT propulsion system is ready for transition to flight. Propulsion system elements included in this system integration test were an engineering model ion thruster, an engineering model propellant management system, an engineering model power processor unit, and a digital control interface unit simulator that acted as a test console. Project requirements that were verified during this system integration test included individual element requirements ; integrated system requirements, and fault handling. This paper will present the results of these tests, which include: integrated ion propulsion system demonstrations of performance, functionality and fault handling; a thruster re-performance acceptance test to establish baseline performance: a risk-reduction PMS-thruster integration test: and propellant management system calibration checks.
Extended Performance 8-cm Mercury Ion Thruster
NASA Technical Reports Server (NTRS)
Mantenieks, M. A.
1981-01-01
A slightly modified 8-cm Hg ion thruster demonstrated significant increase in performance. Thrust was increased by almost a factor of five over that of the baseline thruster. Thruster operation with various three grid ion optics configurations; thruster performance as a function of accelerator grid open area, cathode baffle, and cathode orifice size; and a life test of 614 hours at a beam current of 250 mA (17.5 mN thrust) are discussed. Highest thruster efficiency was obtained with the smallest open area accelerator grid. The benefits in efficiency from the low neutral loss grids were mitigated, however, by the limitation such grids place on attainable ion beam current densities. The thruster components suffered negligible weight losses during a life test, which indicated that operation of the 8-cm thruster at extended levels of thrust and power is possible with no significant loss of lifetime.
Development of an 18 GHz superconducting electron cyclotron resonance ion source at RCNP.
Yorita, Tetsuhiko; Hatanaka, Kichiji; Fukuda, Mitsuhiro; Kibayashi, Mitsuru; Morinobu, Shunpei; Okamura, Hiroyuki; Tamii, Atsushi
2008-02-01
An 18 GHz superconducting electron cyclotron resonance ion source has recently been developed and installed in order to extend the variety and the intensity of ions at the RCNP coupled cyclotron facility. Production of several ions such as O, N, Ar, Kr, etc., is now under development and some of them have already been used for user experiments. For example, highly charged heavy ion beams like (86)Kr(21+,23+) and intense (16)O(5+,6+) and (15)N(6+) ion beams have been provided for experiments. The metal ion from volatile compounds method for boron ions has been developed as well.
NASA Astrophysics Data System (ADS)
Hsu, Chen-Chih; Wang, Jiaqing; Teague, Marcus; Chen, Chien-Chang; Yeh, Nai-Chang
2015-03-01
Ideal graphene is strain-free whereas non-trivial strain can induce pseudo-magnetic fields as predicted theoretically and manifested experimentally. Here we employ nearly strain-free single-domain graphene, grown by plasma-enhanced chemical vapor deposition (PECVD) at low temperatures, to induce controlled strain by placing the PECVD-graphene on substrates containing engineered nanostructures. We fabricate periodic pyramid nanostructures (typically 100 ~ 200 nm laterally and 10 ~ 60 nm in height) on Si substrates by focused ion beam, and determine the topography of these nanostructures using atomic force microscopy and scanning electron microscopy after we transferred monolayer h-BN followed by PECVD-graphene onto these substrates. We find both layers conform well to the nanostructures so that we can control the size, arrangement, separation, and shape of the nanostructures to generate desirable pseudo-magnetic fields. We also employ molecular dynamics simulation to determine the displacement of carbon atoms under a given nanostructure. The pseudo-magnetic field thus obtained is ~150T in the center, relatively homogeneous over 50% of the area, and drops off precipitously near the edge. These findings are extended to arrays of nanostructures and compared with topographic and spectroscopic studies by STM. Supported by NSF.
Variable mixture ratio performance through nitrogen augmentation
NASA Technical Reports Server (NTRS)
Beichel, R.; Obrien, C. J.; Bair, E. K.
1988-01-01
High/variable mixture ratio O2/H2 candidate engine cycles are examined for earth-to-orbit vehicle application. Engine performance and power balance information are presented for the candidate cycles relative to chamber pressure, bulk density, and mixture ratio. Included in the cycle screening are concepts where a third fluid (liquid nitrogen) is used to achieve a variable mixture ratio over the trajectory from liftoff to earth orbit. The third fluid cycles offer a very low risk, fully reusable, low operation cost alternative to high/variable mixture ratio bipropellant cycles. Variable mixture ratio engines with extendible nozzle are slightly lower performing than a single mixture ratio engine (MR = 7:1) with extendible nozzle. Dual expander engines (MR = 7:1) have slightly better performance than the single mixture ratio engine. Dual fuel dual expander engines offer a 16 percent improvement over the single mixture ratio engine.
CAEBAT Model Featured on American Chemical Society Journal Tenth
University's School of Mechanical Engineering has yielded new insights for lithium-ion (Li-ion) battery corresponding article, "Secondary-Phase Stochastics in Lithium-Ion Battery Electrodes" detailing the microstructural modifications can greatly improve overall Li-ion battery performance. The value of this work is
Energy Storage News | Transportation | Transportation Research | NREL
NREL/Purdue team's corresponding article, "Secondary-Phase Stochastics in Lithium-Ion Battery by NREL and NASA, the Battery ISC Device revolutionizes the way lithium-ion (Li-ion) batteries are collaboration with Purdue University's School of Mechanical Engineering has yielded new insights for lithium-ion
Molecular carbon nitride ion beams for enhanced corrosion resistance of stainless steel
NASA Astrophysics Data System (ADS)
Markwitz, A.; Kennedy, J.
2017-10-01
A novel approach is presented for molecular carbon nitride beams to coat stainless surfaces steel using conventional safe feeder gases and electrically conductive sputter targets for surface engineering with ion implantation technology. GNS Science's Penning type ion sources take advantage of the breaking up of ion species in the plasma to assemble novel combinations of ion species. To test this phenomenon for carbon nitride, mixtures of gases and sputter targets were used to probe for CN+ ions for simultaneous implantation into stainless steel. Results from mass analysed ion beams show that CN+ and a variety of other ion species such as CNH+ can be produced successfully. Preliminary measurements show that the corrosion resistance of stainless steel surfaces increased sharply when implanting CN+ at 30 keV compared to reference samples, which is interesting from an application point of view in which improved corrosion resistance, surface engineering and short processing time of stainless steel is required. The results are also interesting for novel research in carbon-based mesoporous materials for energy storage applications and as electrode materials for electrochemical capacitors, because of their high surface area, electrical conductivity, chemical stability and low cost.
The NDCX-II engineering design
NASA Astrophysics Data System (ADS)
Waldron, W. L.; Abraham, W. J.; Arbelaez, D.; Friedman, A.; Galvin, J. E.; Gilson, E. P.; Greenway, W. G.; Grote, D. P.; Jung, J.-Y.; Kwan, J. W.; Leitner, M.; Lidia, S. M.; Lipton, T. M.; Reginato, L. L.; Regis, M. J.; Roy, P. K.; Sharp, W. M.; Stettler, M. W.; Takakuwa, J. H.; Volmering, J.; Vytla, V. K.
2014-01-01
The Neutralized Drift Compression Experiment (NDCX-II) is a user facility located at Lawrence Berkeley National Laboratory which is uniquely designed for ion-beam-driven high energy density laboratory physics and heavy ion fusion research. Construction was completed in March 2012 and the facility is now in the commissioning phase. A significant amount of engineering was carried out in order to meet the performance parameters required for a wide range of target heating experiments while making the most cost-effective use of high-value hardware available from a decommissioned high current electron induction accelerator. The technical challenges and design of this new ion induction accelerator facility are described.
An engineering model 30 cm ion thruster
NASA Technical Reports Server (NTRS)
Poeschel, R. L.; King, H. J.; Schnelker, D. E.
1973-01-01
Thruster development at Hughes Research Laboratories and NASA Lewis Research Center has brought the 30-cm mercury bombardment ion thruster to the state of an engineering model. This thruster has been designed to have sufficient internal strength for direct mounting on gimbals, to weigh 7.3 kg, to operate with a corrected overall efficiency of 71%, and to have 10,000 hours lifetime. Subassemblies, such as the ion optical system, isolators, etc., have been upgraded to meet launch qualification standards. This paper presents a summary of the design specifications and performance characteristics which define the interface between the thruster module and the remainder of the propulsion system.
Spectral Engineering of Slow Light, Cavity Line Narrowing, and Pulse Compression
NASA Astrophysics Data System (ADS)
Sabooni, Mahmood; Li, Qian; Rippe, Lars; Mohan, R. Krishna; Kröll, Stefan
2013-11-01
More than 4 orders of magnitude of cavity-linewidth narrowing in a rare-earth-ion-doped crystal cavity, emanating from strong intracavity dispersion caused by off-resonant interaction with dopant ions, is demonstrated. The dispersion profiles are engineered using optical pumping techniques creating significant semipermanent but reprogrammable changes of the rare-earth absorption profiles. Several cavity modes are shown within the spectral transmission window. Several possible applications of this phenomenon are discussed.
NASA Technical Reports Server (NTRS)
Grodzka, P. G.
1977-01-01
Ion thruster engines for spacecraft propulsion can serve as ion beam sources for potential space processing applications. The advantages of space vacuum environments and the possible gravity effects on thruster ion beam materials operations such as thin film growth, ion milling, and surface texturing were investigated. The direct gravity effect on sputter deposition and vapor deposition processes are discussed as well as techniques for cold and warm welding.
Upgrading and extended testing of the MSC integrated water and waste management hardware
NASA Technical Reports Server (NTRS)
Bambenek, R. A.; Nuccio, P. P.; Hurley, T. L.; Jasionowski, W. J.
1972-01-01
The results are presented of upgrading and testing an integrated water and waste management system, which uses the compression distillation, reverse osmosis, adsorption filtration and ion-exchange processes to recover potable water from urine, flush water and used wash water. Also included is the development of techniques for extending the useful biological life of biological filters, activated carbon filters and ion-exchange resins to at least 30 days, and presterilizing ion-exchange resins so that sterile water can be recovered from waste water. A wide variety of reverse osmosos materials, surfactants and germicides were experimentally evaluated to determine the best combination for a wash water subsystem. Full-scale module tests with real wash water demonstrated that surface fouling is a major problem.
Center for Extended Magnetohydrodynamics Modeling - Final Technical Report
DOE Office of Scientific and Technical Information (OSTI.GOV)
Parker, Scott
This project funding supported approximately 74 percent of a Ph.D. graduate student, not including costs of travel and supplies. We had a highly successful research project including the development of a second-order implicit electromagnetic kinetic ion hybrid model [Cheng 2013, Sturdevant 2016], direct comparisons with the extended MHD NIMROD code and kinetic simulation [Schnack 2013], modeling of slab tearing modes using the fully kinetic ion hybrid model and finally, modeling global tearing modes in cylindrical geometry using gyrokinetic simulation [Chen 2015, Chen 2016]. We developed an electromagnetic second-order implicit kinetic ion fluid electron hybrid model [Cheng 2013]. As a firstmore » step, we assumed isothermal electrons, but have included drift-kinetic electrons in similar models [Chen 2011]. We used this simulation to study the nonlinear evolution of the tearing mode in slab geometry, including nonlinear evolution and saturation [Cheng 2013]. Later, we compared this model directly to extended MHD calculations using the NIMROD code [Schnack 2013]. In this study, we investigated the ion-temperature-gradient instability with an extended MHD code for the first time and got reasonable agreement with the kinetic calculation in terms of linear frequency, growth rate and mode structure. We then extended this model to include orbit averaging and sub-cycling of the ions and compared directly to gyrokinetic theory [Sturdevant 2016]. This work was highlighted in an Invited Talk at the International Conference on the Numerical Simulation of Plasmas in 2015. The orbit averaging sub-cycling multi-scale algorithm is amenable to hybrid architectures with GPUS or math co-processors. Additionally, our participation in the Center for Extend Magnetohydrodynamics motivated our research on developing the capability for gyrokinetic simulation to model a global tearing mode. We did this in cylindrical geometry where the results could be benchmarked with existing eigenmode calculations. First, we developed a gyrokinetic code capable of simulating long wavelengths using a fluid electron model [Chen 2015]. We benchmarked this code with an eigenmode calculation. Besides having to rewrite the field solver due to the breakdown in the gyrokinetic ordering for long wavelengths, very high radial resolution was required. We developed a technique where we used the solution from the eigenmode solver to specify radial boundary conditions allowing for a very high radial resolution of the inner solution. Using this technique enabled us to use our direct algorithm with gyrokinetic ions and drift kinetic electrons [Chen 2016]. This work was highlighted in an Invited Talk at the American Physical Society - Division of Plasma Physics in 2015.« less
Weidman, Jacob L; Mulvenna, Ryan A; Boudouris, Bryan W; Phillip, William A
2017-06-07
Heavy metal contamination of water supplies poses a serious threat to public health, prompting the development of novel and sustainable treatment technologies. One promising approach is to molecularly engineer the chemical affinity of a material for the targeted removal of specific molecules from solution. In this work, nanoporous polymer thin films generated from tailor-made block polymers were functionalized with the bio-inspired moieties glutathione and cysteamine for the removal of heavy metal ions, including lead and cadmium, from aqueous solutions. In a single equilibrium stage, the films achieved removal rates of the ions in excess of 95%, which was consistent with predictions based on the engineered material properties. In a flow-through configuration, the thin films achieved an even greater removal rate of the metal ions. Furthermore, in mixed ion solutions the capacity of the thin films, and corresponding removal rates, did not demonstrate any reduction due to competitive adsorption effects. After such experiments the material was repeatedly regenerated quickly with no observed loss in capacity. Thus, these membranes provide a sustainable platform for the efficient purification of lead- and cadmium-contaminated water sources to safe levels. Moreover, their straightforward chemical modifications suggest that they could be engineered to treat sources containing other recalcitrant environmental contaminants as well.
University Nanosatellite Program ION-F Constellation
NASA Technical Reports Server (NTRS)
Swenson, Charles; Fullmer, Rees; Redd, Frank
2002-01-01
The Space Engineering program at Utah State University has developed a small satellite, known as USUSat, under funding from AFOSR, AFRL, NASA and Utah State University's Space Dynamics Laboratory. This satellite was designed and significantly manufactured by students in the Mechanical and Aerospace Engineering and the Electrical and Computer Engineering Departments within the College of Engineering. USUSat is one of three spacecraft being designed for the Ionospheric Observation Nanosatellite Formation (ION- F). This formation comprises three 15 kg. spacecraft designed and built in cooperation by Utah State University, University of Washington, and Virginia Polytechnic Institute. The ION-F satellites are being designed and built by students at the three universities, with close coordination to insure compatibility for launch, deployment, and the formation flying mission. The JON-F mission is part of the U.S. Air Force Research Laboratory (AFRL) University Nanosatellite Program, which provides technology development and demonstrations for the TechSat2l Program. The University Nanosatellite Program involves 10 universities building nanosatellites for a launch in 2004 on two separate space shuttle missions. Additional support for the formation flying demonstration has been provided by NASA's Goddard Space Flight Center.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lettry J.; Alessi J.; Faircloth, D.
2012-02-23
Linac4 accelerator of Centre Europeen de Recherches Nucleaires is under construction and a RF-driven H{sup -} ion source is being developed. The beam current requirement for Linac4 is very challenging: 80 mA must be provided. Cesiated plasma discharge ion sources such as Penning or magnetron sources are also potential candidates. Accelerator ion sources must achieve typical reliability figures of 95% and above. Investigating and understanding the underlying mechanisms involved with source failure or ageing is critical when selecting the ion source technology. Plasma discharge driven surface ion sources rely on molybdenum cathodes. Deformation of the cathode surfaces is visible aftermore » extended operation periods. A metallurgical investigation of an ISIS ion source is presented. The origin of the deformation is twofold: Molybdenum sputtering by cesium ions digs few tenths of mm cavities while a growth of molybdenum is observed in the immediate vicinity. The molybdenum growth under hydrogen atmosphere is hard and loosely bound to the bulk. It is, therefore, likely to peel off and be transported within the plasma volume. The observation of the cathode, anode, and extraction electrodes of the magnetron source operated at BNL for two years are presented. A beam simulation of H{sup -}, electrons, and Cs{sup -} ions was performed with the IBSimu code package to qualitatively explain the observations. This paper describes the operation conditions of the ion sources and discusses the metallurgical analysis and beam simulation results.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Lettry, J.; Gerardin, A.; Pereira, H.
2012-02-15
Linac4 accelerator of Centre Europeen de Recherches Nucleaires is under construction and a RF-driven H{sup -} ion source is being developed. The beam current requirement for Linac4 is very challenging: 80 mA must be provided. Cesiated plasma discharge ion sources such as Penning or magnetron sources are also potential candidates. Accelerator ion sources must achieve typical reliability figures of 95% and above. Investigating and understanding the underlying mechanisms involved with source failure or ageing is critical when selecting the ion source technology. Plasma discharge driven surface ion sources rely on molybdenum cathodes. Deformation of the cathode surfaces is visible aftermore » extended operation periods. A metallurgical investigation of an ISIS ion source is presented. The origin of the deformation is twofold: Molybdenum sputtering by cesium ions digs few tenths of mm cavities while a growth of molybdenum is observed in the immediate vicinity. The molybdenum growth under hydrogen atmosphere is hard and loosely bound to the bulk. It is, therefore, likely to peel off and be transported within the plasma volume. The observation of the cathode, anode, and extraction electrodes of the magnetron source operated at BNL for two years are presented. A beam simulation of H{sup -}, electrons, and Cs{sup -} ions was performed with the IBSimu code package to qualitatively explain the observations. This paper describes the operation conditions of the ion sources and discusses the metallurgical analysis and beam simulation results.« less
NEXT Long-Duration Test After 11,570 h and 237 kg of Xenon Processed
NASA Technical Reports Server (NTRS)
Soulas, George C.; Patterson, Michael J.; Herman, Daniel A.
2009-01-01
The NASA s Evolutionary Xenon Thruster (NEXT) program is developing the next-generation ion propulsion system with significant enhancements beyond the state-of-the-art in ion propulsion to provide future NASA science missions with enhanced mission capabilities at a low total development cost. As part of a comprehensive thruster service life assessment utilizing both testing and analyses, a Long-Duration Test (LDT) was initiated to validate and qualify the NEXT propellant throughput capability to a qualification-level of 450 kg, 1.5 times the mission-derived throughput requirement of 300 kg. This wear test is being conducted with a modified, flight-representative NEXT engineering model ion thruster, designated EM3. As of September 1, 2007, the thruster has accumulated 11,570 h of operation primarily at the thruster full-input-power of 6.9 kW with 3.52 A beam current and 1800 V beam power supply voltage. The thruster has processed 237 kg of xenon surpassing the NSTAR propellant throughput demonstrated during the extended life testing of the Deep Space 1 (DS1) flight spare. The NEXT LDT has demonstrated a total impulse of 9.78 10(exp 6) N(dot)s; the highest total impulse ever demonstrated by an ion thruster. Thruster performance tests are conducted periodically over the entire NEXT throttle table with input power ranging 0.5 to 6.9 kW. Thruster performance parameters including thrust, input power, specific impulse, and thruster efficiency have been nominal with little variation to date. Lifetime-limiting component erosion rates have been consistent with the NEXT service life assessment, which predicts the earliest failure sometime after 750 kg of xenon propellant throughput; well beyond the mission-derived lifetime requirement. The NEXT wear test data confirm that the erosion of the discharge keeper orifice, enlarging of nominal-current-density accelerator grid aperture cusps at full-power, and the decrease in cold grid-gap observed during NSTAR wear testing have been mitigated in the NEXT design. NEXT grid-gap data indicate a hot grid-gap at full-power that is 60 percent of the nominal cold grid-gap. This paper presents the status of the NEXT LDT to date with emphasis on comparison to the NSTAR extended life test results.
Turbine bucket for use in gas turbine engines and methods for fabricating the same
Garcia-Crespo, Andres
2014-06-03
A turbine bucket for use with a turbine engine. The turbine bucket includes an airfoil that extends between a root end and a tip end. The airfoil includes an outer wall that defines a cavity that extends from the root end to the tip end. The outer wall includes a first ceramic matrix composite (CMC) substrate that extends a first distance from the root end to the tip end. An inner wall is positioned within the cavity. The inner wall includes a second CMC substrate that extends a second distance from the root end towards the tip end that is different than the first distance.
Multi-ion, multi-event test of ion cyclotron resonance heating
NASA Technical Reports Server (NTRS)
Persoon, Ann M.
1993-01-01
The multi-ion, multi-event study of ion cyclotron resonance heating has been funded to study ion energization through ion cyclotron resonance with low frequency broadband electromagnetic turbulence. The modeling algorithm for the ion cyclotron resonance heating (ICRH) of oxygen ions was presented in Crew et al. (1990). Crew and his co-authors developed a two-parameter representation of selected oxygen conic distributions and modelled the conic formation in terms of resonance heating. The first year of this study seeks to extend the work of Crew and his co-authors by testing the applicability of the ICRH mechanism to helium ion conic distributions, using data obtained from the Energetic Ion Composition Spectrometer and the Plasma Wave Instrument on Dynamics Explorer 1.
Communication as Part of the Engineering Skills Set
ERIC Educational Resources Information Center
Lappalainen, Pia
2009-01-01
Engineering graduates are facing changing requirements regarding their competencies, as interdisciplinarity and globalization have transformed engineering communities into collaboration arenas extending beyond uniform national, cultural, contextual and disciplinary settings and structures. Engineers no longer manage their daily tasks with plain…
Intelligent Life-Extending Controls for Aircraft Engines
NASA Technical Reports Server (NTRS)
Guo, Ten-Huei; Chen, Philip; Jaw, Link
2005-01-01
Aircraft engine controllers are designed and operated to provide desired performance and stability margins. The purpose of life-extending-control (LEC) is to study the relationship between control action and engine component life usage, and to design an intelligent control algorithm to provide proper trade-offs between performance and engine life usage. The benefit of this approach is that it is expected to maintain safety while minimizing the overall operating costs. With the advances of computer technology, engine operation models, and damage physics, it is necessary to reevaluate the control strategy fro overall operating cost consideration. This paper uses the thermo-mechanical fatigue (TMF) of a critical component to demonstrate how an intelligent engine control algorithm can drastically reduce the engine life usage with minimum sacrifice in performance. A Monte Carlo simulation is also performed to evaluate the likely engine damage accumulation under various operating conditions. The simulation results show that an optimized acceleration schedule can provide a significant life saving in selected engine components.
Radioisotope Electric Propulsion (REP): A Near-Term Approach to Nuclear Propulsion
NASA Technical Reports Server (NTRS)
Schmidt, George R.; Manzella, David H.; Kamhawi, Hani; Kremic, Tibor; Oleson, Steven R.; Dankanich, John W.; Dudzinski, Leonard A.
2009-01-01
Studies over the last decade have shown radioisotope-based nuclear electric propulsion to be enhancing and, in some cases, enabling for many potential robotic science missions. Also known as radioisotope electric propulsion (REP), the technology offers the performance advantages of traditional reactor-powered electric propulsion (i.e., high specific impulse propulsion at large distances from the Sun), but with much smaller, affordable spacecraft. Future use of REP requires development of radioisotope power sources with system specific powers well above that of current systems. The US Department of Energy and NASA have developed an advanced Stirling radioisotope generator (ASRG) engineering unit, which was subjected to rigorous flight qualification-level tests in 2008, and began extended lifetime testing later that year. This advancement, along with recent work on small ion thrusters and life extension technology for Hall thrusters, could enable missions using REP sometime during the next decade.
Brunk, Elizabeth; Ashari, Negar; Athri, Prashanth; Campomanes, Pablo; de Carvalho, F Franco; Curchod, Basile F E; Diamantis, Polydefkis; Doemer, Manuel; Garrec, Julian; Laktionov, Andrey; Micciarelli, Marco; Neri, Marilisa; Palermo, Giulia; Penfold, Thomas J; Vanni, Stefano; Tavernelli, Ivano; Rothlisberger, Ursula
2011-01-01
The Laboratory of Computational Chemistry and Biochemistry is active in the development and application of first-principles based simulations of complex chemical and biochemical phenomena. Here, we review some of our recent efforts in extending these methods to larger systems, longer time scales and increased accuracies. Their versatility is illustrated with a diverse range of applications, ranging from the determination of the gas phase structure of the cyclic decapeptide gramicidin S, to the study of G protein coupled receptors, the interaction of transition metal based anti-cancer agents with protein targets, the mechanism of action of DNA repair enzymes, the role of metal ions in neurodegenerative diseases and the computational design of dye-sensitized solar cells. Many of these projects are done in collaboration with experimental groups from the Institute of Chemical Sciences and Engineering (ISIC) at the EPFL.
Martina, E.F.
1958-04-22
An improved ion source particularly adapted to provide an intense beam of ions with minimum neutral molecule egress from the source is described. The ion source structure includes means for establishing an oscillating electron discharge, including an apertured cathode at one end of the discharge. The egress of ions from the source is in a pencil like beam. This desirable form of withdrawal of the ions from the plasma created by the discharge is achieved by shaping the field at the aperture of the cathode. A tubular insulator is extended into the plasma from the aperture and in cooperation with the electric fields at the cathode end of the discharge focuses the ions from the source,
NASA Technical Reports Server (NTRS)
Collier, Michael R.; Chornay, D.; Clemmons, J.; Keller, J. W.; Klenzing, J.; Kujawski, J.; McLain, J.; Pfaff, R.; Rowland, D.; Zettergren, M.
2015-01-01
We report initial results from the VISualizing Ion Outflow via Neutral atom imaging during a Substorm (VISIONS) rocket that flew through and near several regions of enhanced auroral activity and also sensed regions of ion outflow both remotely and directly. The observed neutral atom fluxes were largest at the lower energies and generally higher in the auroral zone than in the polar cap. In this paper, we focus on data from the latter half of the VISIONS trajectory when the rocket traversed the polar cap region. During this period, many of the energetic neutral atom spectra show a peak at 100 electronvolts. Spectra with peaks around 100 electronvolts are also observed in the Electrostatic Ion Analyzer (EIA) data consistent with these ions comprising the source population for the energetic neutral atoms. The EIA observations of this low energy population extend only over a few tens of kilometers. Furthermore, the directionality of the arriving energetic neutral atoms is consistent with either this spatially localized source of energetic ions extending from as low as about 300 kilometers up to above 600 kilometers or a larger source of energetic ions to the southwest.
Voltage sweep ion mobility spectrometry.
Davis, Eric J; Williams, Michael D; Siems, William F; Hill, Herbert H
2011-02-15
Ion mobility spectrometry (IMS) is a rapid, gas-phase separation technique that exhibits excellent separation of ions as a standalone instrument. However, IMS cannot achieve optimal separation power with both small and large ions simultaneously. Similar to the general elution problem in chromatography, fast ions are well resolved using a low electric field (50-150 V/cm), whereas slow drifting molecules are best separated using a higher electric field (250-500 V/cm). While using a low electric field, IMS systems tend to suffer from low ion transmission and low signal-to-noise ratios. Through the use a novel voltage algorithm, some of these effects can be alleviated. The electric field was swept from low to high while monitoring a specific drift time, and the resulting data were processed to create a 'voltage-sweep' spectrum. If an optimal drift time is calculated for each voltage and scanned simultaneously, a spectrum may be obtained with optimal separation throughout the mobility range. This increased the resolving power up to the theoretical maximum for every peak in the spectrum and extended the peak capacity of the IMS system, while maintaining accurate drift time measurements. These advantages may be extended to any IMS, requiring only a change in software.
Upstream energetic ions under radial IMF - A critical test of the Fermi model
NASA Technical Reports Server (NTRS)
Sarris, E. T.; Krimigis, S. M.
1988-01-01
Eight years of interplanetary magnetic field (IMF) and energetic particle observations obtained by the IMP-8 spacecraft upstream from the bow shock have been surveyed, and 63 cases when the upstream IMF remained radial for extended periods of time (greater than 1 hour) have been accumulated. Of these, two cases have been selected during which measurable fluxes of ambient solar or corotating energetic particle events were absent. These conditions provide an excellent test to the theories of the origin of upstream energetic ions. It is shown that there are extended periods with radial IMF when no upstream energetic ions were detected. It is further shown that energetic ions in the range E of between 50 keV and 1 MeV, inclusive, are not continuously present but appear in bursts of intensities varying by more than an order of magnitude under persistently radial IMF. These measurements contradict a fundamental prediction of the Fermi mechanism for the origin of the upstream energetic ions, namely that such ions should always be present on radial IMF lines. The observations are consistent with the hypothesis that energetic (greater than about 50 keV) ions leak out from, and appear in the upstream medium sporadically, following the onset of magnetic activity within the magnetosphere.
Hui, Changye; Guo, Yan; Zhang, Wen; Gao, Chaoxian; Yang, Xueqin; Chen, Yuting; Li, Limei; Huang, Xianqing
2018-04-09
Human exposure to lead mainly occurs by ingestion of contaminated food, water and soil. Blocking lead uptake in the gastrointestinal tract is a novel prevention strategy. Whole-cell biosorbent for lead was constructed with PbrR genetically engineered on the cell surface of Escherichia coli (E. coli), a predominant strain among intestinal microflora, using lipoprotein (Lpp)-OmpA as the anchoring protein. In vitro, the PbrR displayed cells had an enhanced ability for immobilizing toxic lead(II) ions from the external media at both acidic and neutral pH, and exhibited a higher specific adsorption for lead compared to other physiological two valence metal ions. In vivo, the persistence of recombinant E. coli in the murine intestinal tract and the integrity of surface displayed PbrR were confirmed. In addition, oral administration of surface-engineered E. coli was safe in mice, in which the concentrations of physiological metal ions in blood were not affected. More importantly, lead associated with PbrR-displayed E. coli was demonstrated to be less bioavailable in the experimental mouse model with exposure to oral lead. This is reflected by significantly lower blood and femur lead concentrations in PbrR-displayed E. coli groups compared to the control. These results open up the possibility for the removal of toxic metal ions in vivo using engineered microorganisms as adsorbents.
Experimental and analytical evaluation of ion thruster/spacecraft interactions
NASA Technical Reports Server (NTRS)
Carruth, M. R., Jr. (Editor)
1981-01-01
Studies were conducted to both identify the environment produced by ion thrusters and to assess the interaction of this environment on a typical spacecraft and typical science instruments. Spacecraft charging and the charge exchange that accompanies it is discussed in detail. Electromagnetic interference was characterized for ion engines. The electromagnetic compatibility of ion thrusters with spacecraft instruments was determined. The effects of ion thruster plumes on spacecraft were studied with particular emphasis on external surface currents.
NASA Technical Reports Server (NTRS)
Oglebay, J. C.
1977-01-01
A thermal analytic model for a 30-cm engineering model mercury-ion thruster was developed and calibrated using the experimental test results of tests of a pre-engineering model 30-cm thruster. A series of tests, performed later, simulated a wide range of thermal environments on an operating 30-cm engineering model thruster, which was instrumented to measure the temperature distribution within it. The modified analytic model is described and analytic and experimental results compared for various operating conditions. Based on the comparisons, it is concluded that the analytic model can be used as a preliminary design tool to predict thruster steady-state temperature distributions for stage and mission studies and to define the thermal interface bewteen the thruster and other elements of a spacecraft.
Quantum Otto engine using a single ion and a single thermal bath
NASA Astrophysics Data System (ADS)
Biswas, Asoka; Chand, Suman
2016-05-01
Quantum heat engines employ a quantum system as the working fluid, that gives rise to large work efficiency, beyond the limit for classical heat engines. Existing proposals for implementing quantum heat engines require that the system interacts with the hot bath and the cold bath (both modelled as a classical system) in an alternative fashion and therefore assumes ability to switch off the interaction with the bath during a certain stage of the heat-cycle. However, it is not possible to decouple a quantum system from its always-on interaction with the bath without use of complex pulse sequences. It is also hard to identify two different baths at two different temperatures in quantum domain, that sequentially interact with the system. Here, we show how to implement a quantum Otto engine without requiring to decouple the bath in a sequential manner. This is done by considering a single thermal bath, coupled to a single trapped ion. The electronic degree of freedom of the ion is chosen as a two-level working fluid while the vibrational degree of freedom plays the role of the cold bath. Measuring the electronic state mimics the release of heat into the cold bath. Thus, our model is fully quantum and exhibits very large work efficiency, asymptotically close to unity.
Magnetosheath Filamentary Structures Formed by Ion Acceleration at the Quasi-Parallel Bow Shock
NASA Technical Reports Server (NTRS)
Omidi, N.; Sibeck, D.; Gutynska, O.; Trattner, K. J.
2014-01-01
Results from 2.5-D electromagnetic hybrid simulations show the formation of field-aligned, filamentary plasma structures in the magnetosheath. They begin at the quasi-parallel bow shock and extend far into the magnetosheath. These structures exhibit anticorrelated, spatial oscillations in plasma density and ion temperature. Closer to the bow shock, magnetic field variations associated with density and temperature oscillations may also be present. Magnetosheath filamentary structures (MFS) form primarily in the quasi-parallel sheath; however, they may extend to the quasi-perpendicular magnetosheath. They occur over a wide range of solar wind Alfvénic Mach numbers and interplanetary magnetic field directions. At lower Mach numbers with lower levels of magnetosheath turbulence, MFS remain highly coherent over large distances. At higher Mach numbers, magnetosheath turbulence decreases the level of coherence. Magnetosheath filamentary structures result from localized ion acceleration at the quasi-parallel bow shock and the injection of energetic ions into the magnetosheath. The localized nature of ion acceleration is tied to the generation of fast magnetosonic waves at and upstream of the quasi-parallel shock. The increased pressure in flux tubes containing the shock accelerated ions results in the depletion of the thermal plasma in these flux tubes and the enhancement of density in flux tubes void of energetic ions. This results in the observed anticorrelation between ion temperature and plasma density.
Characterization of the ITER model negative ion source during long pulse operation
DOE Office of Scientific and Technical Information (OSTI.GOV)
Hemsworth, R.S.; Boilson, D.; Crowley, B.
2006-03-15
It is foreseen to operate the neutral beam system of the International Thermonuclear Experimental Reactor (ITER) for pulse lengths extending up to 1 h. The performance of the KAMABOKO III negative ion source, which is a model of the source designed for ITER, is being studied on the MANTIS test bed at Cadarache. This article reports the latest results from the characterization of the ion source, in particular electron energy distribution measurements and the comparison between positive ion and negative ion extraction from the source.
A preliminary study of extended magnetic field structures in the ionosphere
NASA Technical Reports Server (NTRS)
Sullivan, James D.; Lane, Barton G.; Post, Richard S.
1987-01-01
Several plasma phenomena which are to be expected around a magnet in LEO were identified and analyzed qualitatively. The ASTROMAG cusp magnet will create an extended field whose strength drops to the ambient level over a scale length of approx. 15 m; the combined field has a complex topology with ring nulls and open and closed field lines. The entire configuration is moving through the partially ionized F-layer of the ionosphere at a speed slow compared to the local Alfven speed but fast compared to the ion sound speed. The ambient plasma crosses the extended field structure in a time short compared to the ion Larmor period yet long relative to the electron Larmor period. Thus, electrons behave as a magnetized fluid while ions move ballistically until reflected from higher fields near the cusp. Since the Debye length is short compared to the field scale length, an electrostatic shock-like structure forms to equilibrate the flows and achieve quasi-neutrality. The ambient plasma will be excluded from a cavity near the magnet. The size and nature of the strong interaction region in which the magnet significantly perturbs the ambient flow were determined by studying ion orbits numerically. Lecture viewgraphs summarizing these results are presented.
Ion manipulation device with electrical breakdown protection
Chen, Tsung-Chi; Tang, Keqi; Ibrahim, Yehia M; Smith, Richard D; Anderson, Gordon A; Baker, Erin M
2014-12-02
An ion manipulation method and device is disclosed. The device includes a pair of substantially parallel surfaces. An array of inner electrodes is contained within, and extends substantially along the length of, each parallel surface. The device includes a first outer array of electrodes and a second outer array of electrodes. Each outer array of electrodes is positioned on either side of the inner electrodes, and is contained within and extends substantially along the length of each parallel surface. A DC voltage is applied to the first and second outer array of electrodes. A RF voltage, with a superimposed electric field, is applied to the inner electrodes by applying the DC voltages to each electrode. Ions either move between the parallel surfaces within an ion confinement area or along paths in the direction of the electric field, or can be trapped in the ion confinement area. The surfaces are housed in a chamber, and at least one electrically insulative shield is coupled to an inner surface of the chamber for increasing a mean-free-path between two adjacent electrodes in the chamber.
Conformational Space and Stability of ETD Charge Reduction Products of Ubiquitin
NASA Astrophysics Data System (ADS)
Lermyte, Frederik; Łącki, Mateusz Krzysztof; Valkenborg, Dirk; Gambin, Anna; Sobott, Frank
2017-01-01
Owing to its versatility, electron transfer dissociation (ETD) has become one of the most commonly utilized fragmentation techniques in both native and non-native top-down mass spectrometry. However, several competing reactions—primarily different forms of charge reduction—occur under ETD conditions, as evidenced by the distorted isotope patterns usually observed. In this work, we analyze these isotope patterns to compare the stability of nondissociative electron transfer (ETnoD) products, specifically noncovalent c/ z fragment complexes, across a range of ubiquitin conformational states. Using ion mobility, we find that more extended states are more prone to fragment release. We obtain evidence that for a given charge state, populations of ubiquitin ions formed either directly by electrospray ionization or through collapse of more extended states upon charge reduction, span a similar range of collision cross-sections. Products of gas-phase collapse are, however, less stabilized towards unfolding than the native conformation, indicating that the ions retain a memory of previous conformational states. Furthermore, this collapse of charge-reduced ions is promoted if the ions are `preheated' using collisional activation, with possible implications for the kinetics of gas-phase compaction.
A Course in Electrochemical and Corrosion Engineering.
ERIC Educational Resources Information Center
Van Zee, John
1985-01-01
Describes a course designed to show similarities between electrochemistry and corrosion engineering and to show graduate students that electrochemical and corrosion engineering can be accomplished by extending their knowledge of chemical engineering models. Includes course outline, textbooks selected, and teaching methods used. (JN)
Grid Gap Measurement for an NSTAR Ion Thruster
NASA Technical Reports Server (NTRS)
Diaz, Esther M.; Soulas, George C.
2006-01-01
The change in gap between the screen and accelerator grids of an engineering model NSTAR ion optics assembly was measured during thruster operation with beam extraction. The molybdenum ion optics assembly was mounted onto an engineering model NSTAR ion thruster. The measurement technique consisted of measuring the difference in height of an alumina pin relative to the downstream accelerator grid surface. The alumina pin was mechanically attached to the center aperture of the screen grid and protruded through the center aperture of the accelerator grid. The change in pin height was monitored using a long distance microscope coupled to a digital imaging system. Transient and steady-state hot grid gaps were measured at three power levels: 0.5, 1.5 and 2.3 kW. Also, the change in grid gap was measured during the transition between power levels, and during the startup with high voltage applied just prior to discharge ignition. Performance measurements, such as perveance, electron backstreaming limit and screen grid ion transparency, were also made to confirm that this ion optics assembly performed similarly to past testing. Results are compared to a prior test of 30 cm titanium ion optics.
Simplified Ion Thruster Xenon Feed System for NASA Science Missions
NASA Technical Reports Server (NTRS)
Snyder, John Steven; Randolph, Thomas M.; Hofer, Richard R.; Goebel, Dan M.
2009-01-01
The successful implementation of ion thruster technology on the Deep Space 1 technology demonstration mission paved the way for its first use on the Dawn science mission, which launched in September 2007. Both Deep Space 1 and Dawn used a "bang-bang" xenon feed system which has proven to be highly successful. This type of feed system, however, is complex with many parts and requires a significant amount of engineering work for architecture changes. A simplified feed system, with fewer parts and less engineering work for architecture changes, is desirable to reduce the feed system cost to future missions. An attractive new path for ion thruster feed systems is based on new components developed by industry in support of commercial applications of electric propulsion systems. For example, since the launch of Deep Space 1 tens of mechanical xenon pressure regulators have successfully flown on commercial spacecraft using electric propulsion. In addition, active proportional flow controllers have flown on the Hall-thruster-equipped Tacsat-2, are flying on the ion thruster GOCE mission, and will fly next year on the Advanced EHF spacecraft. This present paper briefly reviews the Dawn xenon feed system and those implemented on other xenon electric propulsion flight missions. A simplified feed system architecture is presented that is based on assembling flight-qualified components in a manner that will reduce non-recurring engineering associated with propulsion system architecture changes, and is compared to the NASA Dawn standard. The simplified feed system includes, compared to Dawn, passive high-pressure regulation, a reduced part count, reduced complexity due to cross-strapping, and reduced non-recurring engineering work required for feed system changes. A demonstration feed system was assembled using flight-like components and used to operate a laboratory NSTAR-class ion engine. Feed system components integrated into a single-string architecture successfully operated the engine over the entire NSTAR throttle range over a series of tests. Flow rates were very stable with variations of at most 0.2%, and transition times between throttle levels were typically 90 seconds or less with a maximum of 200 seconds, both significant improvements over the Dawn bang-bang feed system.
Incorporating metals into de novo proteins.
Peacock, Anna F A
2013-12-01
The de novo design of artificial metalloproteins from first-principles is a powerful strategy with which to establish the minimum structure required for function, as well as to identify the important design features for tuning the chemistry of the coordinated metal ion. Herein we describe recent contributions to this field, covering metallo-porphyrin, mononuclear and multinuclear metal ion sites engineered into de novo proteins. Using miniature artificial scaffolds these examples demonstrate that complex natural protein folds are not required to mimic naturally occurring metal ion sites in proteins. More importantly progress is being made to engineer de novo metalloproteins capable of performing functions not in the repertoire of biology. Copyright © 2013 Elsevier Ltd. All rights reserved.
Thermal Environmental Testing of NSTAR Engineering Model Ion Thrusters
NASA Technical Reports Server (NTRS)
Rawlin, Vincent K.; Patterson, Michael J.; Becker, Raymond A.
1999-01-01
NASA's New Millenium program will fly a xenon ion propulsion system on the Deep Space 1 Mission. Tests were conducted under NASA's Solar Electric Propulsion Technology Applications Readiness (NSTAR) Program with 3 different engineering model ion thrusters to determine thruster thermal characteristics over the NSTAR operating range in a variety of thermal environments. A liquid nitrogen-cooled shroud was used to cold-soak the thruster to -120 C. Initial tests were performed prior to a mature spacecraft design. Those results and the final, severe, requirements mandated by the spacecraft led to several changes to the basic thermal design. These changes were incorporated into a final design and tested over a wide range of environmental conditions.
NASA Technical Reports Server (NTRS)
Lo, C. John; Brophy, John R.; Etters, M. Andy; Ramesham, Rajeshuni; Jones, William R., Jr.; Jansen, Mark J.
2009-01-01
The Dawn Ion Propulsion System is the ninth project in NASA s Discovery Program. The Dawn spacecraft is being developed to enable the scientific investigation of the two heaviest main-belt asteroids, Vesta and Ceres. Dawn is the first mission to orbit two extraterrestrial bodies, and the first to orbit a main-belt asteroid. The mission is enabled by the onboard Ion Propulsion System (IPS) to provide the post-launch delta-V. The three Ion Engines of the IPS are mounted on Thruster Gimbal Assembly (TGA), with only one engine operating at a time for this 10-year mission. The three TGAs weigh 14.6 kg.
Measurement-induced operation of two-ion quantum heat machines
NASA Astrophysics Data System (ADS)
Chand, Suman; Biswas, Asoka
2017-03-01
We show how one can implement a quantum heat machine by using two interacting trapped ions, in presence of a thermal bath. The electronic states of the ions act like a working substance, while the vibrational mode is modelled as the cold bath. The heat exchange with the cold bath is mimicked by the projective measurement of the electronic states. We show how such measurement in a suitable basis can lead to either a quantum heat engine or a refrigerator, which undergoes a quantum Otto cycle. The local magnetic field is adiabatically changed during the heat cycle. The performance of the heat machine depends upon the interaction strength between the ions, the magnetic fields, and the measurement cost. In our model, the coupling to the hot and the cold baths is never switched off in an alternative fashion during the heat cycle, unlike other existing proposals of quantum heat engines. This makes our proposal experimentally realizable using current tapped-ion technology.
Measurement-induced operation of two-ion quantum heat machines.
Chand, Suman; Biswas, Asoka
2017-03-01
We show how one can implement a quantum heat machine by using two interacting trapped ions, in presence of a thermal bath. The electronic states of the ions act like a working substance, while the vibrational mode is modelled as the cold bath. The heat exchange with the cold bath is mimicked by the projective measurement of the electronic states. We show how such measurement in a suitable basis can lead to either a quantum heat engine or a refrigerator, which undergoes a quantum Otto cycle. The local magnetic field is adiabatically changed during the heat cycle. The performance of the heat machine depends upon the interaction strength between the ions, the magnetic fields, and the measurement cost. In our model, the coupling to the hot and the cold baths is never switched off in an alternative fashion during the heat cycle, unlike other existing proposals of quantum heat engines. This makes our proposal experimentally realizable using current tapped-ion technology.
Additional extensions to the NASCAP computer code, volume 3
NASA Technical Reports Server (NTRS)
Mandell, M. J.; Cooke, D. L.
1981-01-01
The ION computer code is designed to calculate charge exchange ion densities, electric potentials, plasma temperatures, and current densities external to a neutralized ion engine in R-Z geometry. The present version assumes the beam ion current and density to be known and specified, and the neutralizing electrons to originate from a hot-wire ring surrounding the beam orifice. The plasma is treated as being resistive, with an electron relaxation time comparable to the plasma frequency. Together with the thermal and electrical boundary conditions described below and other straightforward engine parameters, these assumptions suffice to determine the required quantities. The ION code, written in ASCII FORTRAN for UNIVAC 1100 series computers, is designed to be run interactively, although it can also be run in batch mode. The input is free-format, and the output is mainly graphical, using the machine-independent graphics developed for the NASCAP code. The executive routine calls the code's major subroutines in user-specified order, and the code allows great latitude for restart and parameter change.
Advanced Space Transportation Program (ASTP)
2003-07-21
An ion thruster is removed from a vacuum chamber at NASA's Jet Propulsion Laboratory in Pasadena, California. The thruster, a spare engine from NASA's Deep Space 1 mission, with a designed life of 8,000 hours, ran for a record 30,352 hours (nearly 5 years) giving researchers the ability to observe its performance and wear at different power levels throughout the test. This information will be vital to future missions that use ion propulsion. Ion propulsion systems can be very lightweight, rurning on just a few grams of xenon gas a day. Xenon is the same gas that is found in photo flash bulbs. This fuel efficiency can lower launch vehicle costs. The successful Deep Space 1 mission featured the first use of an ion engine as the primary means of propulsion on a NASA spacecraft. NASA's next-generation ion propulsion efforts are implemented by the Marshall Space Flight Center. The program seeks to develop advanced propulsion technologies that will significantly reduce cost, mass, or travel times.
Ion Temperature Control of the Io Plasma Torus
NASA Technical Reports Server (NTRS)
Delamere, P. A.; Schneider, N. M.; Steffl, A. J.; Robbins, S. J.
2005-01-01
We report on observational and theoretical studies of ion temperature in the Io plasma torus. Ion temperature is a critical factor for two reasons. First, ions are a major supplier of energy to the torus electrons which power the intense EUV emissions. Second, ion temperature determines the vertical extent of plasma along field lines. Higher temperatures spread plasma out, lowers the density and slows reaction rates. The combined effects can play a controlling role in torus energetics and chemistry. An unexpected tool for the study of ion temperature is the longitudinal structure in the plasma torus which often manifests itself as periodic brightness variations. Opposite sides of the torus (especially magnetic longitudes 20 and 200 degrees) have been observed on numerous occasions to have dramatically different brightness, density, composition, ionization state, electron temperature and ion temperature. These asymmetries must ultimately be driven by different energy flows on the opposite sides, presenting an opportunity to observe key torus processes operating under different conditions. The most comprehensive dataset for the study of longitudinal variations was obtained by the Cassini UVIS instrument during its Jupiter flyby. Steffl (Ph.D. thesis, 2005) identified longitudinal variations in all the quantities listed above wit the exception of ion temperature. We extend his work by undertaking the first search for such variation in the UVIS dataset. We also report on a 'square centimeter' model of the torus which extend the traditional 'cubic centimeter' models by including the controlling effects of ion temperature more completely.
Reverse Flow Engine Core Having a Ducted Fan with Integrated Secondary Flow Blades
NASA Technical Reports Server (NTRS)
Kisska, Michael K. (Inventor); Princen, Norman H. (Inventor); Kuehn, Mark S. (Inventor); Cosentino, Gary B. (Inventor)
2014-01-01
Secondary air flow is provided for a ducted fan having a reverse flow turbine engine core driving a fan blisk. The fan blisk incorporates a set of thrust fan blades extending from an outer hub and a set of integral secondary flow blades extending intermediate an inner hub and the outer hub. A nacelle provides an outer flow duct for the thrust fan blades and a secondary flow duct carries flow from the integral secondary flow blades as cooling air for components of the reverse flow turbine engine.
Boggs, David Lee; Baraszu, Daniel James; Foulkes, David Mark; Gomes, Enio Goyannes
1998-01-01
An internal combustion engine includes separated oil drain-back and crankcase ventilation passages. The oil drain-back passages extend from the cylinder head to a position below the top level of oil in the engine's crankcase. The crankcase ventilation passages extend from passages formed in the main bearing bulkheads from positions above the oil level in the crankcase and ultimately through the cylinder head. Oil dams surrounding the uppermost portions of the crankcase ventilation passages prevent oil from running downwardly through the crankcase ventilation passages.
Life-Extending Control for Aircraft Engines Studied
NASA Technical Reports Server (NTRS)
Guo, Te-Huei
2002-01-01
Current aircraft engine controllers are designed and operated to provide both performance and stability margins. However, the standard method of operation results in significant wear and tear on the engine and negatively affects the on-wing life--the time between cycles when the engine must be physically removed from the aircraft for maintenance. The NASA Glenn Research Center and its industrial and academic partners have been working together toward a new control concept that will include engine life usage as part of the control function. The resulting controller will be able to significantly extend the engine's on-wing life with little or no impact on engine performance and operability. The new controller design will utilize damage models to estimate and mitigate the rate and overall accumulation of damage to critical engine parts. The control methods will also provide a means to assess tradeoffs between performance and structural durability on the basis of mission requirements and remaining engine life. Two life-extending control methodologies were studied to reduce the overall life-cycle cost of aircraft engines. The first methodology is to modify the baseline control logic to reduce the thermomechanical fatigue (TMF) damage of cooled stators during acceleration. To accomplish this, an innovative algorithm limits the low-speed rotor acceleration command when the engine has reached a threshold close to the requested thrust. This algorithm allows a significant reduction in TMF damage with only a very small increase in the rise time to reach the commanded rotor speed. The second methodology is to reduce stress rupture/creep damage to turbine blades and uncooled stators by incorporating an engine damage model into the flight mission. Overall operation cost is reduced by an optimization among the flight time, fuel consumption, and component damages. Recent efforts have focused on applying life-extending control technology to an existing commercial turbine engine, and doing so without modifying the hardware or adding sensors. This approach makes it possible to retrofit existing engines with life-extending control technology by changing only the control software in the full-authority digital engine controller (FADEC). The significant results include demonstrating a 20- to 30-percent reduction in TMF damage to the hot section by developing and implementing smart acceleration logic during takeoff. The tradeoff is an increase, from 5.0 to 5.2 sec, in the time required to reach maximum power from ground idle. On a typical flight profile of a cruise at Mach 0.8 at an altitude of 41,000 ft, and cruise time of 104 min, the optimized system showed that a reduction in cruise speed from Mach 0.8 to 0.79 can achieve an estimated 25-to 35-percent creep/rupture damage reduction in the engine's hot section and a fuel savings of 2.1 percent. The tradeoff is an increase in flight time of 1.3 percent (1.4 min).
Performance Results for a Universal Lithium Ion Battery Management System
2012-08-01
MODELING & SIMULATION, TESTING AND VALIDATION (MSTV) MINI-SYMPOSIUM AUGUST 14-16, MICHIGAN PERFORMANCE RESULTS FOR A UNIVERSAL LITHIUM ION BATTERY MANAGEMENT...Article 3. DATES COVERED 12-08-2012 to 12-08-2012 4. TITLE AND SUBTITLE PERFORMANCE RESULTS FOR A UNIVERSAL LITHIUM ION BATTERY MANAGEMENT SYSTEM...Engineering and Technology Symposium (GVSETS) Performance Results for a Universal Lithium Ion Battery Management System UNCLASSIFIED – Page 2 of 11
DOE Office of Scientific and Technical Information (OSTI.GOV)
Farrell, John T; Kelly, Kenneth J; Duran, Adam W
Range-extended electric vehicle (EV) technology can be a viable option for reducing fuel consumption from medium-duty (MD) and heavy-duty (HD) engines by approximately 50 percent or more. Such engines have wide variations in use and duty cycles, however, and identifying the vocations/duty cycles most suitable for range-extended applications is vital for maximizing the potential benefits. This presentation provides information about NREL's research on range-extended EV technologies, with a focus on NREL's real-world data collection and analysis approach to identifying the vocations/duty cycles best suited for range-extender applications and to help guide related powertrain optimization and design requirements. The presentation alsomore » details NREL's drive cycle development process as it pertains to package delivery applications.« less
NASA Technical Reports Server (NTRS)
1972-01-01
The construction of an ion thruster module (including thruster, power conditioning, and control system) capable of operating for 10,000 hours over a five to one range at an effective specific impulse of approximately 2800 seconds is discussed. The several interrelated tasks involved in the construction of the engine are described. Performance tests of the engine and the effects of various modifications are reported. It was demonstrated that thruster performance and stability were not materially affected by reasonable changes from the nominal operating point.
Electronegative Gas Thruster - Direct Thrust Measurement Project
NASA Technical Reports Server (NTRS)
Dankanich, John (Principal Investigator); Aanesland, Ane; Polzin, Kurt; Walker, Mitchell
2015-01-01
This effort is an international collaboration and academic partnership to mature an innovative electric propulsion (EP) thruster concept to TRL 3 through direct thrust measurement. The initial target application is for Small Satellites, but can be extended to higher power. The Plasma propulsion with Electronegative GASES (PEGASES) concept simplifies ion thruster operation, eliminates a neutralizer requirement and should yield longer life capabilities and lower cost implementation over conventional gridded ion engines. The basic proof-of concept has been demonstrated and matured to TRL 2 over the past several years by researchers at the Laboratoire de Physique des Plasma in France. Due to the low maturity of the innovation, there are currently no domestic investments in electronegative gas thrusters anywhere within NASA, industry or academia. The end product of this Center Innovation Fund (CIF) project will be a validation of the proof-of-concept, maturation to TRL 3 and technology assessment report to summarize the potential for the PEGASES concept to supplant the incumbent technology. Information exchange with the foreign national will be one-way with the exception of the test results. Those test results will first go through a standard public release ITAR/export control review, and the results will be presented in a public technical forum, and the results will be presented in a public technical forum.
NASA Astrophysics Data System (ADS)
Chaudhary, Anisha; Teotia, Satish; Kumar, Rajeev; Ramesha, K.; Dhakate, Sanjay R.; Kumari, Saroj
2018-04-01
To assess the challenge of affordable technology, present synthetic strategies can be extended to new low-cost synthesis and processing methods that have potential to tailor the properties of the materials. Here we report, a novel method for the synthesis of mesocarbon microbeads (MCMB) through a pre-processing involved pyrolysis technique. The resulting MCMB is compressed into a product and effects of heat treatment temperature on different properties of MCMB is studied. The use of MCMB for the electromagnetic interference (EMI) shielding is new and hence, the effect of heat treatment temperature on EMI shielding effectiveness is studied in X-band. It is observed that EMI shielding effectiveness increases to ‑39.6 dB on increasing the heat treatment temperature. The high conductivity of MCMB plate heat treated upto 2500 °C contributes to highly conducting networks. Additionally, to investigate the electrochemical performance of MCMB as an anode material for lithium ion batteries, 2500 °C heat treated MCMB powder is used to fabricate the electrode. The MCMB electrode exhibits high discharge capacity of 345 mAh g‑1 with a stable capacity for over 50 cycles and good rate capability. Thus, MCMB synthesized by this novel approach can be used for the development of high performance anode materials for Li-ion batteries.
Transport coefficients of gaseous ions in an electric field
NASA Technical Reports Server (NTRS)
Whealton, J. H.; Mason, E. A.
1974-01-01
A general theory of ion mobility formulated by Kihara (1953) is extended to ion diffusion and to mixtures of neutral gases. The theory assumes that only binary collisions between ions and neutral particles need to be taken into account and that the velocity distribution function of the neutral particles is Maxwellian. These assumptions make it possible to use a linearized Boltzmann equation. Questions of mobility are considered along with aspects of diffusion and deviations from Fick's law of diffusion.
Instrument Suite for Vertical Characterization of the Ionosphere-Thermosphere System
NASA Technical Reports Server (NTRS)
Herrero, Federico; Jones, Hollis; Finne, Theodore; Nicholas, Andrew
2012-01-01
A document describes a suite that provides four simultaneous ion and neutral-atom measurements as a function of altitude, with variable sensitivity for neutral atmospheric species. The variable sensitivity makes it possible to extend the measurements over the altitude range of 100 to more than 700 km. The four instruments in the suite are (1) a neutral wind-temperature spectrometer (WTS), (2) an ion-drift ion-temperature spectrometer (IDTS), (3) a neutral mass spectrometer (NMS), and (4) an ion mass spectrometer (IMS).
Simulation of charge transport in ion channels and nanopores with anisotropic permittivity
Mashl, R. Jay; Lee, Kyu Il; Jakobsson, Eric; Ravaioli, Umberto
2010-01-01
Ion channels are part of nature's solution for regulating biological environments. Every ion channel consists of a chain of amino acids carrying a strong and sharply varying permanent charge, folded in such a way that it creates a nanoscopic aqueous pore spanning the otherwise mostly impermeable membranes of biological cells. These naturally occurring proteins are particularly interesting to device engineers seeking to understand how such nanoscale systems realize device-like functions. Availability of high-resolution structural information from X-ray crystallography, as well as large-scale computational resources, makes it possible to conduct realistic ion channel simulations. In general, a hierarchy of simulation methodologies is needed to study different aspects of a biological system like ion channels. Biology Monte Carlo (BioMOCA), a three-dimensional coarse-grained particle ion channel simulator, offers a powerful and general approach to study ion channel permeation. BioMOCA is based on the Boltzmann Transport Monte Carlo (BTMC) and Particle-Particle-Particle-Mesh (P3M) methodologies developed at the University of Illinois at Urbana-Champaign. In this paper we briefly discuss the various approaches to simulating ion flow in channel systems that are currently being pursued by the biophysics and engineering communities, and present the effect of having anisotropic dielectric constants on ion flow through a number of nanopores with different effective diameters. PMID:20445807
A.A.D. engine noise evaluation
NASA Technical Reports Server (NTRS)
1983-01-01
A critique of the various characteristics of engine design influencing noise and attempts to indicator areas where attention is required to obtain noise acceptable engine for automobiles are discussed. It was concluded that the engine has a potential to be quiet beccause a ion rated speed is chosen. Problems with high gas pressure, the fuel injection pump, and the expander/compressor are discussed.
A VARIABLE REACTIVITY MODEL FOR ION BINDING TO ENVIRONMENTAL SORBENTS
The conceptual and mathematical basis for a new general-composite modeling approach for ion binding to environmental sorbents is presented. The work extends the Simple Metal Sorption (SiMS) model previously presented for metal and proton binding to humic substances. A surface com...
Alloy vapor deposition using ion plating and flash evaporation
NASA Technical Reports Server (NTRS)
Spalvins, T.
1971-01-01
Method extends scope of ion plating technique to include deposition of alloy films without changing composition of plating alloy. Coatings flow with specimen material without chipping or peeling. Technique is most effective vacuum deposition method for depositing alloys for strong and lasting adherence.
Field Ion Microscopy and Atom Probe Tomography of Metamorphic Magnetite Crystals
NASA Technical Reports Server (NTRS)
Kuhlman, K.; Martens, R. L.; Kelly, T. F.; Evans, N. D.; Miller, M. K.
2001-01-01
Magnetite has been analysed using Field Ion Microscopy (FIM) and Atom Probe Tomography (APT), highly attractive techniques for the nanoanalysis of geological materials despite the difficulties inherent in analyzing semiconducting and insulating materials. Additional information is contained in the original extended abstract.
Toward laser cooling and trapping lanthanum ions
NASA Astrophysics Data System (ADS)
Olmschenk, Steven; Banner, Patrick; Hankes, Jessie; Nelson, Amanda
2017-04-01
Trapped atomic ions are a leading candidate for applications in quantum information. For scalability and applications in quantum communication, it would be advantageous to interface ions with telecom light. We present progress toward laser cooling doubly-ionized lanthanum, which should require only infrared, telecom-compatible light. Since the hyperfine structure of this ion has not been measured, we are using optogalavanic spectroscopy in a hollow cathode lamp to measure the hyperfine spectrum of transitions in lanthanum. Using laser ablation to directly produce ions from a solid target, we laser cool and trap barium ions, and explore extending this technique to lanthanum ions. This research is supported by the Army Research Office, Research Corporation for Science Advancement, and Denison University.
2015-03-02
This artist concept shows NASA Dawn spacecraft arriving at the dwarf planet Ceres. Dawn travels through space using a technology called ion propulsion, with ions glowing with blue light are accelerated out of an engine, giving the spacecraft thrust.
2009-09-30
NTR 5025703. HONORS/AWARDS/PRIZES Hollis H. Jones, NASA Goddard AETD Award for Innovative Technology Development, July 2009, Applied Engineering and Technology Directorate, NASA GSFC, Greenbelt, Maryland. 5
Graves, J P; Chapman, I T; Coda, S; Lennholm, M; Albergante, M; Jucker, M
2012-01-10
Virtually collisionless magnetic mirror-trapped energetic ion populations often partially stabilize internally driven magnetohydrodynamic disturbances in the magnetosphere and in toroidal laboratory plasma devices such as the tokamak. This results in less frequent but dangerously enlarged plasma reorganization. Unique to the toroidal magnetic configuration are confined 'circulating' energetic particles that are not mirror trapped. Here we show that a newly discovered effect from hybrid kinetic-magnetohydrodynamic theory has been exploited in sophisticated phase space engineering techniques for controlling stability in the tokamak. These theoretical predictions have been confirmed, and the technique successfully applied in the Joint European Torus. Manipulation of auxiliary ion heating systems can create an asymmetry in the distribution of energetic circulating ions in the velocity orientated along magnetic field lines. We show the first experiments in which large sawtooth collapses have been controlled by this technique, and neoclassical tearing modes avoided, in high-performance reactor-relevant plasmas.
Spacelab energetic ion mass spectrometer
NASA Technical Reports Server (NTRS)
Whalen, B. A.; Mcdiarmid, I. B.; Burrows, J. R.; Sharp, R. D.; Johnson, R. G.; Shelley, E. G.
1980-01-01
Basic design criteria are given for an ion mass spectrometer for use in studying magnetospheric ion populations. The proposed instrument is composed of an electrostatic analyzer followed by a magnetic spectrometer and simultaneously measures the energy per unit and mass per unit charge of the ion species. An electromagnet is used for momentum analysis to extend the operational energy range over a much wider domain than is possible with the permanent magnets used in previous flights. The energetic ion source regions, ion energization mechanisms, field line tracing, coordinated investigations, and orbit considerations are discussed and operations of the momentum analyzer and of the electrostatic energy analyzer are examined.
Ion funnel with extended mass range and reduced conductance limit aperture
Tolmachev, Aleksey V [Richland, WA; Smith, Richard D [Richland, WA
2008-04-01
An improved ion funnel design is disclosed that decreases the axial RF (parasite) fields at the ion funnel exit. This is achieved by addition of one or more compensation electrodes after the conductance limit electrode. Various RF voltage profiles may be applied to the various electrodes minimizing the parasite axial potential wells. The smallest RF aperture that serves as the conductance limiting electrode is further reduced over standard designs. Overall, the ion funnel improves transmission ranges of both low m/z and high m/z ions, reducing RF activation of ions and decreasing the gas load to subsequent differential pumping stages.
The influence of low-energy helium plasma on bubble formation in micro-engineered tungsten
NASA Astrophysics Data System (ADS)
Gao, Edward; Nadvornick, Warren; Doerner, Russ; Ghoniem, Nasr M.
2018-04-01
Four different types of micro-engineered tungsten surfaces were exposed to low energy helium plasma, with a planar surface as control. These samples include two surfaces covered with uniform W-coated rhenium micro-pillars; one with cylindrical pillars 1 μm in diameter and 25 μm in height, and one with dendritic conical pillars 4-10 μm in diameter and 20 μm in height. Additionally, two samples with reticulated open-cell foam geometry, one at 45 pores per inch (PPI), and the other at 80 PPI were fabricated with Chemical Vapor Deposition (CVD). The samples were exposed to helium plasma at 30-100 eV ion energy, 823-1123 K temperature, and 5 × 1025 - 2 × 1026 m-2 ion fluence. It is shown that the formation of nanometer-scale tendrils (fuzz) on micro-engineered W surfaces is greatly reduced as compared to planar surfaces. This is attributed to more significant ion backscattering and the increased effective surface area that intercept incident ions in micro-engineered W. A 20% decrease in the average ion incident angle on pillar type surfaces leads to ∼30% decrease in bubble size, down to 30 nm in diameter. W fuzz was found to be absent from pillar sides due to high ion backscattering rates from pillar sides. In foam samples, 28% higher PPI is observed to have 24.7%-36.7% taller fuzz, and 17.0%-25.0% larger subsurface bubbles. These are found to be an order of magnitude smaller than those found in planar surfaces of similar environment. The helium bubble density was found to increase with ion energy in pillars, roughly from 8.2% to 48.4%, and to increase with increasing PPI, from 36.4% to 116.2%, and with bubble concentrations up to 9.1 × 1021 m-3. Geometric shadowing effects in or near surface ligaments are observed in all foam samples, with near absence of helium bubbles or fuzz in deeper layers of the foam.
Saturn's Magnetosphere and Properties of Upstream Flow at Titan: Preliminary Results
NASA Technical Reports Server (NTRS)
Sittler, E. C., Jr.; Hartle, R. E.; Cooper, J. F.; Lipatov, A.; Bertucci, C.; Coates, A. J.; Arridge, C.; Szego, K.; Shappirio, M.; Simipson, D. G.;
2009-01-01
Using Cassini Plasma Spectrometer (CAPS) Ion Mass Spectrometer (IMS) measurements, we present the ion fluid properties and its ion composition of the upstream flow for Titan's interaction with Saturn's magnetosphere. A 3D ion moments algorithm is used which is essentially model independent with only requirement is that ion flow is within the CAPS IMS 2(pi) steradian field-of-view (FOV) and that the ion 'velocity distribution function (VDF) be gyrotropic. These results cover the period from TA flyby (2004 day 300) to T22 flyby (2006 363). Cassini's in situ measurements of Saturn's magnetic field show it is stretched out into a magnetodisc configuration for Saturn Local Times (SLT) centered about midnight local time. Under those circumstances the field is confined near the equatorial plane with Titan either above or below the magnetosphere current sheet. Similar to Jupiter's outer magnetosphere where a magnetodisc configuration applies, one expects the heavy ions within Saturn's outer magnetosphere to be confined within a few degrees of the current sheet while at higher magnetic latitudes protons should dominate. We show that when Cassini is between dusk-midnight-dawn local time and spacecraft is not within the current sheet that light ions (H, 142) tend to dominate the ion composition for the upstream flow. If true, one may expect the interaction between Saturn's magnetosphere, locally devoid of heavy ions and Titan's upper atmosphere and exosphere to be significantly different from that for Voyager 1, TA and TB when heavy ions were present in the upstream flow. We also present observational evidence for Saturn's magnetosphere interaction with Titan's extended H and H2 corona which can extend approx. 1 Rs from Titan.
The 7.5K lbf thrust engine preliminary design for Orbit Transfer Vehicle
NASA Technical Reports Server (NTRS)
Hayden, Warren R.; Sabiers, Ralph; Schneider, Judy
1994-01-01
This document summarizes the preliminary design of the Aerojet version of the Orbit Transfer Vehicle main engine. The concept of a 7500 lbf thrust LO2/GH2 engine using the dual expander cycle for optimum efficiency is validated through power balance and thermal calculations. The engine is capable of 10:1 throttling from a nominal 2000 psia to a 200 psia chamber pressure. Reservations are detailed on the feasibility of a tank head start, but the design incorporates low speed turbopumps to mitigate the problem. The mechanically separate high speed turbopumps use hydrostatic bearings to meet engine life requirements, and operate at sub-critical speed for better throttling ability. All components were successfully packaged in the restricted envelope set by the clearances for the extendible/retractable nozzle. Gimbal design uses an innovative primary and engine out gimbal system to meet the +/- 20 deg gimbal requirement. The hydrogen regenerator and LOX/GH2 heat exchanger uses the Aerojet platelet structures approach for a highly compact component design. The extendible/retractable nozzle assembly uses an electric motor driven jack-screw design and a one segment carbon-carbon or silicide coated columbium nozzle with an area ratio, when extended, of 1430:1. A reliability analysis and risk assessment concludes the report.
Hübel, Niklas; Dahlem, Markus A.
2014-01-01
The classical Hodgkin-Huxley (HH) model neglects the time-dependence of ion concentrations in spiking dynamics. The dynamics is therefore limited to a time scale of milliseconds, which is determined by the membrane capacitance multiplied by the resistance of the ion channels, and by the gating time constants. We study slow dynamics in an extended HH framework that includes time-dependent ion concentrations, pumps, and buffers. Fluxes across the neuronal membrane change intra- and extracellular ion concentrations, whereby the latter can also change through contact to reservoirs in the surroundings. Ion gain and loss of the system is identified as a bifurcation parameter whose essential importance was not realized in earlier studies. Our systematic study of the bifurcation structure and thus the phase space structure helps to understand activation and inhibition of a new excitability in ion homeostasis which emerges in such extended models. Also modulatory mechanisms that regulate the spiking rate can be explained by bifurcations. The dynamics on three distinct slow times scales is determined by the cell volume-to-surface-area ratio and the membrane permeability (seconds), the buffer time constants (tens of seconds), and the slower backward buffering (minutes to hours). The modulatory dynamics and the newly emerging excitable dynamics corresponds to pathological conditions observed in epileptiform burst activity, and spreading depression in migraine aura and stroke, respectively. PMID:25474648
Ion-photon entanglement and quantum frequency conversion with trapped Ba+ ions.
Siverns, J D; Li, X; Quraishi, Q
2017-01-20
Trapped ions are excellent candidates for quantum nodes, as they possess many desirable features of a network node including long lifetimes, on-site processing capability, and production of photonic flying qubits. However, unlike classical networks in which data may be transmitted in optical fibers and where the range of communication is readily extended with amplifiers, quantum systems often emit photons that have a limited propagation range in optical fibers and, by virtue of the nature of a quantum state, cannot be noiselessly amplified. Here, we first describe a method to extract flying qubits from a Ba+ trapped ion via shelving to a long-lived, low-lying D-state with higher entanglement probabilities compared with current strong and weak excitation methods. We show a projected fidelity of ≈89% of the ion-photon entanglement. We compare several methods of ion-photon entanglement generation, and we show how the fidelity and entanglement probability varies as a function of the photon collection optic's numerical aperture. We then outline an approach for quantum frequency conversion of the photons emitted by the Ba+ ion to the telecommunication range for long-distance networking and to 780 nm for potential entanglement with rubidium-based quantum memories. Our approach is significant for extending the range of quantum networks and for the development of hybrid quantum networks compromised of different types of quantum memories.
14 CFR 91.611 - Authorization for ferry flight with one engine inoperative.
Code of Federal Regulations, 2013 CFR
2013-01-01
... (with its propeller removed or in a configuration desired by the operator and with all other engines... with— (i) The landing gear extended; (ii) The critical engine inoperative and its propeller removed or... controlled satisfactorily with the critical engine inoperative (with its propeller removed or in a...
14 CFR 91.611 - Authorization for ferry flight with one engine inoperative.
Code of Federal Regulations, 2011 CFR
2011-01-01
... (with its propeller removed or in a configuration desired by the operator and with all other engines... with— (i) The landing gear extended; (ii) The critical engine inoperative and its propeller removed or... controlled satisfactorily with the critical engine inoperative (with its propeller removed or in a...
14 CFR 23.149 - Minimum control speed.
Code of Federal Regulations, 2012 CFR
2012-01-01
... extended; and (5) All propeller controls in the position recommended for approach with all engines... engine is suddenly made inoperative, it is possible to maintain control of the airplane with that engine... not more than 5 degrees. The method used to simulate critical engine failure must represent the most...
14 CFR 91.611 - Authorization for ferry flight with one engine inoperative.
Code of Federal Regulations, 2012 CFR
2012-01-01
... (with its propeller removed or in a configuration desired by the operator and with all other engines... with— (i) The landing gear extended; (ii) The critical engine inoperative and its propeller removed or... controlled satisfactorily with the critical engine inoperative (with its propeller removed or in a...
14 CFR 23.149 - Minimum control speed.
Code of Federal Regulations, 2014 CFR
2014-01-01
... extended; and (5) All propeller controls in the position recommended for approach with all engines... engine is suddenly made inoperative, it is possible to maintain control of the airplane with that engine... not more than 5 degrees. The method used to simulate critical engine failure must represent the most...
14 CFR 91.611 - Authorization for ferry flight with one engine inoperative.
Code of Federal Regulations, 2014 CFR
2014-01-01
... (with its propeller removed or in a configuration desired by the operator and with all other engines... with— (i) The landing gear extended; (ii) The critical engine inoperative and its propeller removed or... controlled satisfactorily with the critical engine inoperative (with its propeller removed or in a...
Status of the NEXT Long-Duration Test After 23,300 Hours of Operation
NASA Technical Reports Server (NTRS)
Herman, Daniel A.; Soulas, George C.; Patterson, Michael J.
2009-01-01
The NASA s Evolutionary Xenon Thruster (NEXT) program is developing the next-generation ion propulsion system with significant enhancements beyond the state-of-the-art in ion propulsion to provide future NASA science missions with enhanced mission capabilities at a low total development cost. As part of a comprehensive thruster service life assessment utilizing both testing and analyses, a Long-Duration Test (LDT) was initiated in June 2005, to verify the NEXT propellant throughput capability to a qualification-level of 450 kg, 1.5 times the anticipated throughput requirement of 300 kg per thruster from mission analyses. The LDT is being conducted with a modified, flight-representative NEXT engineering model ion thruster, designated EM3. As of July 2009, the thruster has accumulated 23,300 h of operation with extensive durations at the following input powers: 6.9, 4.7, 1.1, and 0.5 kW. The thruster has processed 427 kg of xenon surpassing the NSTAR propellant throughput demonstrated during the extended life testing of the Deep Space 1 flight spare ion thruster and approaching the NEXT development qualification throughput goal. The NEXT LDT has demonstrated a total impulse of 16.0 10(exp 6) N/s; the highest total impulse ever demonstrated by an ion thruster. Thruster performance tests are conducted periodically over the entire NEXT throttle table with input power ranging 0.5 to 6.9 kW. Thruster performance parameters including thrust, input power, specific impulse, and thruster efficiency have been nominal with little variation to date. The NSTAR first-failure mode, accelerator aperture erosion leading to electron backstreaming, has been mitigated in the NEXT design. The severe NSTAR discharge cathode assembly erosion has been mitigated by a graphite keeper in the NEXT thruster. Tracking of the NEXT first failure mode, charge-exchange ion impingement on the accelerator grid causing hexagonal groove erosion, is consistent with model predictions and indicates thruster life greater than or equal to 750 kg throughput. This paper presents the status, performance data, and wear characteristics of the NEXT LDT to date.
Life extending control for rocket engines
NASA Technical Reports Server (NTRS)
Lorenzo, C. F.; Saus, J. R.; Ray, A.; Carpino, M.; Wu, M.-K.
1992-01-01
The concept of life extending control is defined. A brief discussion of current fatigue life prediction methods is given and the need for an alternative life prediction model based on a continuous functional relationship is established. Two approaches to life extending control are considered: (1) the implicit approach which uses cyclic fatigue life prediction as a basis for control design; and (2) the continuous life prediction approach which requires a continuous damage law. Progress on an initial formulation of a continuous (in time) fatigue model is presented. Finally, nonlinear programming is used to develop initial results for life extension for a simplified rocket engine (model).
2011-02-04
Solid Oxide fuel cell and Lithium Ion battery (~150 watts) • Enables extended mission durations • 12 hours of full power; 30 hours of silent watch...Hybrid fuel cell system is designed to replace the existing lead-acid batteries with an upgraded Solid Oxide fuel cell and Lithium Ion battery (~250
Ya, Huiyuan; Chen, Qiufang; Wang, Weidong; Chen, Wanguang; Qin, Guangyong; Jiao, Zhen
2012-01-01
The stimulation effect that some beneficial agronomic qualities have exhibited in present-generation plants have also been observed due to ion implantation on plants. However, there is relatively little knowledge regarding the molecular mechanism of the stimulation effects of ion-beam implantation. In order to extend our current knowledge about the functional genes related to this stimulation effect, we have reported a comprehensive microarray analysis of the transcriptome features of the promoted-growth rice seedlings germinating from seeds implanted by a low-energy N+ beam. The results showed that 351 up-regulated transcripts and 470 down-regulated transcripts, including signaling proteins, kinases, plant hormones, transposable elements, transcription factors, non-coding protein RNA (including miRNA), secondary metabolites, resistance proteins, peroxidase and chromatin modification, are all involved in the stimulating effects of ion-beam implantation. The divergences of the functional catalog between the vacuum and ion implantation suggest that ion implantation is the principle cause of the ion-beam implantation biological effects, and revealed the complex molecular networks required to adapt to ion-beam implantation stress in plants, including enhanced transposition of transposable elements, promoted ABA biosynthesis and changes in chromatin modification. Our data will extend the current understanding of the molecular mechanisms and gene regulation of stimulation effects. Further research on the candidates reported in this study should provide new insights into the molecular mechanisms of biological effects induced by ion-beam implantation. PMID:22843621
Zeolite-based SCR catalysts and their use in diesel engine emission treatment
Narula, Chaitanya K.; Yang, Xiaofan
2016-08-02
A catalyst comprising a zeolite loaded with copper ions and at least one trivalent metal ion other than Al.sup.+3, wherein the catalyst decreases NO.sub.x emissions in diesel exhaust. The trivalent metal ions are selected from, for example, trivalent transition metal ions, trivalent main group metal ions, and/or trivalent lanthanide metal ions. In particular embodiments, the catalysts are selected from Cu--Fe-ZSM5, Cu--La-ZSM-5, Fe--Cu--La-ZSM5, Cu--Sc-ZSM-5, and Cu--In-ZSM5. The catalysts are placed on refractory support materials and incorporated into catalytic converters.
Zeolite-based SCR catalysts and their use in diesel engine emission treatment
Narula, Chaitanya K; Yang, Xiaofan
2015-03-24
A catalyst comprising a zeolite loaded with copper ions and at least one trivalent metal ion other than Al.sup.+3, wherein the catalyst decreases NO.sub.x emissions in diesel exhaust. The trivalent metal ions are selected from, for example, trivalent transition metal ions, trivalent main group metal ions, and/or trivalent lanthanide metal ions. In particular embodiments, the catalysts are selected from Cu--Fe-ZSM5, Cu--La-ZSM-5, Fe--Cu--La-ZSM5, Cu--Sc-ZSM-5, and Cu--In-ZSM5. The catalysts are placed on refractory support materials and incorporated into catalytic converters.
Design of Life Extending Controls Using Nonlinear Parameter Optimization
NASA Technical Reports Server (NTRS)
Lorenzo, Carl F.; Holmes, Michael S.; Ray, Asok
1998-01-01
This report presents the conceptual development of a life extending control system where the objective is to achieve high performance and structural durability of the plant. A life extending controller is designed for a reusable rocket engine via damage mitigation in both the fuel and oxidizer turbines while achieving high performance for transient responses of the combustion chamber pressure and the O2/H2 mixture ratio. This design approach makes use of a combination of linear and nonlinear controller synthesis techniques and also allows adaptation of the life extending controller module to augment a conventional performance controller of a rocket engine. The nonlinear aspect of the design is achieved using nonlinear parameter optimization of a prescribed control structure.
Li-Ion Battery and Supercapacitor Hybrid Design for Long Extravehicular Activities
NASA Technical Reports Server (NTRS)
Jeevarajan, Judith
2013-01-01
With the need for long periods of extravehicular activities (EVAs) on the Moon or Mars or a near-asteroid, the need for long-performance batteries has increased significantly. The energy requirements for the EVA suit, as well as surface systems such as rovers, have increased significantly due to the number of applications they need to power at the same time. However, even with the best state-of-the-art Li-ion batteries, it is not possible to power the suit or the rovers for the extended period of performance. Carrying a charging system along with the batteries makes it cumbersome and requires a self-contained power source for the charging system that is usually not possible. An innovative method to charge and use the Li-ion batteries for long periods seems to be necessary and hence, with the advent of the Li-ion supercapacitors, a method has been developed to extend the performance period of the Li-ion power system for future exploration applications. The Li-ion supercapacitors have a working voltage range of 3.8 to 2.5 V, and are different from a traditional supercapacitor that typically has a working voltage of 1 V. The innovation is to use this Li-ion supercapacitor to charge Liion battery systems on an as-needed basis. The supercapacitors are charged using solar arrays and have battery systems of low capacity in parallel to be able to charge any one battery system while they provide power to the application. Supercapacitors can safely take up fast charge since the electrochemical process involved is still based on charge separation rather than the intercalation process seen in Li-ion batteries, thus preventing lithium metal deposition on the anodes. The lack of intercalation and eliminating wear of the supercapacitors allows for them to be charged and discharged safely for a few tens of thousands of cycles. The Li-ion supercapacitors can be charged from the solar cells during the day during an extended EVA. The Liion battery used can be half the capacity required for a nominal EVA. The small Li-ion battery can be divided into two parallel modules with independent charging ports that would allow the supercapacitors to charge one battery while the other is providing power to the rover or suit.
Photoinduced toxicity of engineered nanomaterials
NASA Astrophysics Data System (ADS)
Jones, Philip Scott
Engineered nanomaterials including metal, metal oxide and carbon based nanomaterials are extensively used in a wide variety of applications to the extent that their presence in the environment is expected to increase dramatically over the next century. These nanomaterials may be photodegraded by solar radiation and thereby release metal ions into the environment that can produce cytotoxic and genotoxic effects. Photoinduced toxicity experiments are performed exposing human lung epithelial carcinoma cells [H1650] to engineered semiconductor nanoparticles such as CdSe quantum dots and ZnO nanoparticles after exposure to 3, 6, and 9 hours of solar simulated radiation. Cytotoxicity and genotoxicity of the metal ions are evaluated using ZnSO4 and CdCl2 solutions for the MTT assay and Comet assay respectively. The objective of the dissertation is to obtain quantitative information about the environmental transformation of engineered nanomaterials and their mechanism of toxicity. This information is critical for addressing the environmental health and safety risks of engineered nanomaterials to workers, consumers and the environment.
High Performance Pillared Vanadium Oxide Cathode for Lithium Ion Batteries
2015-04-24
As a result, two major approaches have been taken to increase electrode- electrolyte interfacial area while minimizing lithium diffusion lengths...Performance Pillared Vanadium Oxide Cathode for Lithium Ion Batteries Siu on Tung, Krista L. Hawthorne, Yi Ding, James Mainero, and Levi T. Thompson...Automotive Research Development and Engineering Center, Warren, MI 48387, USA Keywords: nanostructured materials, lithium ion batteries, cathode
Engineered long-range interactions on a 2D array of trapped ions
NASA Astrophysics Data System (ADS)
Britton, Joseph W.; Sawyer, Brian C.; Bollinger, John J.; Freericks, James K.
2014-03-01
Ising interactions are one paradigm used to model quantum magnetism in condensed matter systems. At NIST Boulder we confine and Doppler laser cool hundreds of 9Be+ ions in a Penning trap. The valence electron of each ion behaves as an ideal spin-1/2 particle and, in the limit of weak radial confinement relative to axial confinement, the ions naturally form a two-dimensional triangular lattice. A variable-range anti-ferromagnetic Ising interaction is engineered with a spin-dependent optical dipole force (ODF) through spin-dependent excitation of collective modes of ion motion. We have also exploited this spin-dependent force to perform spectroscopy and thermometry of the normal modes of the trapped ion crystal. The high spin-count and long-range spin-spin couplings achievable in the NIST Penning trap brings within reach simulation of computationally intractable problems in quantum magnetism. Examples include modeling quantum magnetic phase transitions and propagation of spin correlations resulting from a quantum quench. The Penning system may also be amenable to observation of spin-liquid behavior thought to arise in systems where the underlying lattice structure can frustrate long-range ordering. Supported by DARPA OLE and NIST.
Emission response from extended length, variable geometry gas turbine combustor
DOE Office of Scientific and Technical Information (OSTI.GOV)
Troth, D.L.; Verdouw, A.J.; Tomlinson, J.G.
1974-01-01
A program to analyze, select, and experimentally evaluate low emission combustors for aircraft gas turbine engines is conducted to demonstrate a final combustor concept having a 50 percent reduction in total mass emissions (carbon monoxide, unburnt hydrocarbons, oxides of nitrogen, and exhaust smoke) without an increase in any specific pollutant. Research conducted under an Army Contract established design concepts demonstrating significant reductions in CO and UHC emissions. Two of these concepts were an extended length intermediate zone to consume CO and UHC and variable geometry to control the primary zone fuel air ratio over varying power conditions. Emission reduction featuresmore » were identified by analytical methods employing both reaction kinetics and empirical correlations. Experimental results were obtained on a T63 component combustor rig operating at conditions simulating the engine over the complete power operating range with JP-4 fuel. A combustor incorporating both extended length and variable geometry was evaluated and the performance and emission results are reported. These results are compared on the basis of a helicopter duty cycle and the EPA 1979 turboprop regulation landing take off cycle. The 1979 EPA emission regulations for P2 class engines can be met with the extended length variable geometry combustor on the T63 turboprop engine.« less
The Need for V&V in Reuse-Based Software Engineering
NASA Technical Reports Server (NTRS)
Addy, Edward A.
1997-01-01
V&V is currently performed during application development for many systems, especially safety-critical and mission-critical systems. The V&V process is intended to discover errors, especially errors related to entire' domain or product line rather than a critical processing, as early as possible during the development process. The system application provides the context under which the software artifacts are validated. engineering. This paper describes a framework that extends V&V from an individual application system to a product line of systems that are developed within an architecture-based software engineering environment. This framework includes the activities of traditional application-level V&V, and extends these activities into the transition between domain engineering and application engineering. The framework includes descriptions of the types of activities to be performed during each of the life-cycle phases, and provides motivation for activities.
2013-03-01
effluent by ion chromatography (method described in Appendix A) Resin Separation Will remove >95% of fully exhausted resin (below mid-lateral...and retain >95% of the unexhausted resin (above the mid-lateral). 1) Mass balance on ClO4- during each cycle using ion chromatography and resin...Application Note 134, “Determination of Low Concentrations of Perchlorate in Drinking and Ground Waters Using Ion Chromatography ” and Product Note
Dramatic pressure-sensitive ion conduction in conical nanopores.
Jubin, Laetitia; Poggioli, Anthony; Siria, Alessandro; Bocquet, Lydéric
2018-04-17
Ion transporters in Nature exhibit a wealth of complex transport properties such as voltage gating, activation, and mechanosensitive behavior. When combined, such processes result in advanced ionic machines achieving active ion transport, high selectivity, or signal processing. On the artificial side, there has been much recent progress in the design and study of transport in ionic channels, but mimicking the advanced functionalities of ion transporters remains as yet out of reach. A prerequisite is the development of ionic responses sensitive to external stimuli. In the present work, we report a counterintuitive and highly nonlinear coupling between electric and pressure-driven transport in a conical nanopore, manifesting as a strong pressure dependence of the ionic conductance. This result is at odds with standard linear response theory and is akin to a mechanical transistor functionality. We fully rationalize this behavior on the basis of the coupled electrohydrodynamics in the conical pore by extending the Poisson-Nernst-Planck-Stokes framework. The model is shown to capture the subtle mechanical balance occurring within an extended spatially charged zone in the nanopore. The pronounced sensitivity to mechanical forcing offers leads in tuning ion transport by mechanical stimuli. The results presented here provide a promising avenue for the design of tailored membrane functionalities.
NASA Technical Reports Server (NTRS)
Kanik, I.; Beegle, L. W.; Hill, H. H.
2001-01-01
The potential of the high-resolution Electrospray Ionization/Ion Mobility Spectrometry (ESI/IMS) technique as analytical separation tool in analyzing bio-molecular mixtures in the search for the chemical signatures of life is demonstrated. Additional information is contained in the original extended abstract.
Silk scaffolds in bone tissue engineering: An overview.
Bhattacharjee, Promita; Kundu, Banani; Naskar, Deboki; Kim, Hae-Won; Maiti, Tapas K; Bhattacharya, Debasis; Kundu, Subhas C
2017-11-01
Bone tissue plays multiple roles in our day-to-day functionality. The frequency of accidental bone damage and disorder is increasing worldwide. Moreover, as the world population continues to grow, the percentage of the elderly population continues to grow, which results in an increased number of bone degenerative diseases. This increased elderly population pushes the need for artificial bone implants that specifically employ biocompatible materials. A vast body of literature is available on the use of silk in bone tissue engineering. The current work presents an overview of this literature from materials and fabrication perspective. As silk is an easy-to-process biopolymer; this allows silk-based biomaterials to be molded into diverse forms and architectures, which further affects the degradability. This makes silk-based scaffolds suitable for treating a variety of bone reconstruction and regeneration objectives. Silk surfaces offer active sites that aid the mineralization and/or bonding of bioactive molecules that facilitate bone regeneration. Silk has also been blended with a variety of polymers and minerals to enhance its advantageous properties or introduce new ones. Several successful works, both in vitro and in vivo, have been reported using silk-based scaffolds to regenerate bone tissues or other parts of the skeletal system such as cartilage and ligament. A growing trend is observed toward the use of mineralized and nanofibrous scaffolds along with the development of technology that allows to control scaffold architecture, its biodegradability and the sustained releasing property of scaffolds. Further development of silk-based scaffolds for bone tissue engineering, taking them up to and beyond the stage of human trials, is hoped to be achieved in the near future through a cross-disciplinary coalition of tissue engineers, material scientists and manufacturing engineers. The state-of-art of silk biomaterials in bone tissue engineering, covering their wide applications as cell scaffolding matrices to micro-nano carriers for delivering bone growth factors and therapeutic molecules to diseased or damaged sites to facilitate bone regeneration, is emphasized here. The review rationalizes that the choice of silk protein as a biomaterial is not only because of its natural polymeric nature, mechanical robustness, flexibility and wide range of cell compatibility but also because of its ability to template the growth of hydroxyapatite, the chief inorganic component of bone mineral matrix, resulting in improved osteointegration. The discussion extends to the role of inorganic ions such as Si and Ca as matrix components in combination with silk to influence bone regrowth. The effect of ions or growth factor-loaded vehicle incorporation into regenerative matrix, nanotopography is also considered. Copyright © 2017 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
System and Method for an Integrated Satellite Platform
NASA Technical Reports Server (NTRS)
Starin, Scott R. (Inventor); Sheikh, Salman I. (Inventor); Hesse, Michael (Inventor); Clagett, Charles E. (Inventor); Santos Soto, Luis H. (Inventor); Hesh, Scott V. (Inventor); Paschalidis, Nikolaos (Inventor); Ericsson, Aprille J. (Inventor); Johnson, Michael A. (Inventor)
2018-01-01
A system, method, and computer-readable storage devices for a 6U CubeSat with a magnetometer boom. The example 6U CubeSat can include an on-board computing device connected to an electrical power system, wherein the electrical power system receives power from at least one of a battery and at least one solar panel, a first fluxgate sensor attached to an extendable boom, a release mechanism for extending the extendable boom, at least one second fluxgate sensor fixed within the satellite, an ion neutral mass spectrometer, and a relativistic electron/proton telescope. The on-board computing device can receive data from the first fluxgate sensor, the at least one second fluxgate sensor, the ion neutral mass spectrometer, and the relativistic electron/proton telescope via the bus, and can then process the data via an algorithm to deduce a geophysical signal.
Finite Gyroradius Effects Observed in Pickup Oxygen Ions at Venus
NASA Technical Reports Server (NTRS)
Hartle, Richard E.; Intriligator, Devrie; Grebowsky, Joseph M.; Einaudi, Franco (Technical Monitor)
2000-01-01
On the dayside of Venus, the hot oxygen corona extending above the ionopause is the principal source of pickup oxygen ions. The ions are born here and picked up by the ionosheath plasma as it is deflected around the planet. These pickup ions have been observed by the Orbiter Plasma Analyzer (OPA) throughout the Pioneer Venus Orbiter (PVO) mission. They were observed over a region extending from their dayside source to great distances downstream (about 10 Venus radii), in the solar wind wake, as PVO passed through apoapsis. Finite gyroradius effects in the velocity distribution of the oxygen pickup ions are expected in the source region because the gyroradius is several times larger than the scale height of the hot oxygen source. Such effects are also expected in those regions of the ionosheath where the scale lengths of the magnetic field and the ambient plasma velocity field are less than the pickup ion gyroradius. While explicitly accounting for the spatial distribution of the hot oxygen source, an analytic expression for the pickup oxygen ion velocity distribution is developed to study how it is affected by finite gyroradii. The analysis demonstrates that as the gyroradius increases by factors of three to six above the hot oxygen scale height, the peak of the pickup oxygen ion flux distribution decreases 25 to 50% below the maximum allowed speed, which is twice the speed of the ambient plasma times the sine of the angle between the magnetic field and the flow velocity. The pickup oxygen ion flux distribution observed by OPA is shown to follow this behavior in the source region. It is also shown that this result is consistent with the pickup ion distributions observed in the wake, downstream of the source, where the flux peaks are usually well below the maximum allowed speed.
Numerical simulation of ion charge breeding in electron beam ion source
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zhao, L., E-mail: zhao@far-tech.com; Kim, Jin-Soo
2014-02-15
The Electron Beam Ion Source particle-in-cell code (EBIS-PIC) tracks ions in an EBIS electron beam while updating electric potential self-consistently and atomic processes by the Monte Carlo method. Recent improvements to the code are reported in this paper. The ionization module has been improved by using experimental ionization energies and shell effects. The acceptance of injected ions and the emittance of extracted ion beam are calculated by extending EBIS-PIC to the beam line transport region. An EBIS-PIC simulation is performed for a Cs charge-breeding experiment at BNL. The charge state distribution agrees well with experiments, and additional simulation results ofmore » radial profiles and velocity space distributions of the trapped ions are presented.« less
Demonstration of diesel fired coolant heaters in school bus applications : final report.
DOT National Transportation Integrated Search
2010-04-01
Engine block pre-heating can reduce fuel consumption, decrease pollution, extend engine life, and it is often necessary for reliably starting diesel engines in cold climates. This report describes the application and experience of applying 36 diesel ...
1977-09-01
On 24 June 1974 Packer applied to the St. Paul District, Corps of Engineers (Corps) for a DOA permit under Section 10 of the River and Harbor Act of...exercised jurisdiction under Section 404 of P.L. 92-500 to the ordinary high water mark of the • Mississippi River, Thu’, even though the proposed project...Corps of Engineers was to expand their regulatory IT ril ct ion under Sect ion 404 of P.l.. 92-500 ,nd to promulgate new r- ’~giiI.,t .; ill conjunct
Electrostatic propulsion beam divergence effects on spacecraft surfaces, volume 2
NASA Technical Reports Server (NTRS)
Hall, D. F.
1973-01-01
The third phase of a program to develop understanding of and tolerance-level criteria for the deleterious effects of electrostatic rocket exhaust (Cs, Cs(+), Hg, Hg(+)) and materials of rocket construction impinging on typical classes of spacecraft (S/C) surfaces was completed. Models of ion engine effluents and models describing the degradation of S/C surfaces by these effluents are presented. Experimental data from previous phases are summarized and Phase 2 data and analysis are presented in detail. The spacecraft design implications of ion engine contaminants are discussed.
NASA Technical Reports Server (NTRS)
Biess, J. J.; Inouye, L. Y.; Shank, J. H.
1974-01-01
A high-voltage, high-power LC series resonant inverter using SCRs has been developed for an Ion Engine Power Processor. The inverter operates within 200-400Vdc with a maximum output power of 2.5kW. The inverter control logic, the screen supply electrical and mechanical characteristics, the efficiency and losses in power components, regulation on the dual feedback principle, the SCR waveforms and the component weight are analyzed. Efficiency of 90.5% and weight density of 4.1kg/kW are obtained.
High-Power, High-Thrust Ion Thruster (HPHTion)
NASA Technical Reports Server (NTRS)
Peterson, Peter Y.
2015-01-01
Advances in high-power photovoltaic technology have enabled the possibility of reasonably sized, high-specific power solar arrays. At high specific powers, power levels ranging from 50 to several hundred kilowatts are feasible. Ion thrusters offer long life and overall high efficiency (typically greater than 70 percent efficiency). In Phase I, the team at ElectroDynamic Applications, Inc., built a 25-kW, 50-cm ion thruster discharge chamber and fabricated a laboratory model. This was in response to the need for a single, high-powered engine to fill the gulf between the 7-kW NASA's Evolutionary Xenon Thruster (NEXT) system and a notional 25-kW engine. The Phase II project matured the laboratory model into a protoengineering model ion thruster. This involved the evolution of the discharge chamber to a high-performance thruster by performance testing and characterization via simulated and full beam extraction testing. Through such testing, the team optimized the design and built a protoengineering model thruster. Coupled with gridded ion thruster technology, this technology can enable a wide range of missions, including ambitious near-Earth NASA missions, Department of Defense missions, and commercial satellite activities.
Lynch, William T
2015-10-01
The article examines and extends work bringing together engineering ethics and Science and Technology Studies, which had built upon Diane Vaughan's analysis of the Challenger shuttle accident as a test case. Reconsidering the use of her term "normalization of deviance," the article argues for a middle path between moralizing against and excusing away engineering practices contributing to engineering disaster. To explore an illustrative pedagogical case and to suggest avenues for constructive research developing this middle path, it examines the emergence of green chemistry and green engineering. Green chemistry began when Paul Anastas and John Warner developed a set of new rules for chemical synthesis that sought to learn from missed opportunities to avoid environmental damage in the twentieth century, an approach that was soon extended to engineering as well. Examination of tacit assumptions about historical counterfactuals in recent, interdisciplinary discussions of green chemistry illuminate competing views about the field's prospects. An integrated perspective is sought, addressing how both technical practice within chemistry and engineering and the influence of a wider "social movement" can play a role in remedying environmental problems.
NASA Technical Reports Server (NTRS)
Kobayashi, Takahisa; Simon, Donald L.; Litt, Jonathan S.
2005-01-01
An approach based on the Constant Gain Extended Kalman Filter (CGEKF) technique is investigated for the in-flight estimation of non-measurable performance parameters of aircraft engines. Performance parameters, such as thrust and stall margins, provide crucial information for operating an aircraft engine in a safe and efficient manner, but they cannot be directly measured during flight. A technique to accurately estimate these parameters is, therefore, essential for further enhancement of engine operation. In this paper, a CGEKF is developed by combining an on-board engine model and a single Kalman gain matrix. In order to make the on-board engine model adaptive to the real engine s performance variations due to degradation or anomalies, the CGEKF is designed with the ability to adjust its performance through the adjustment of artificial parameters called tuning parameters. With this design approach, the CGEKF can maintain accurate estimation performance when it is applied to aircraft engines at offnominal conditions. The performance of the CGEKF is evaluated in a simulation environment using numerous component degradation and fault scenarios at multiple operating conditions.
Experimental and analytical investigation of a modified ring cusp NSTAR engine
NASA Technical Reports Server (NTRS)
Sengupta, Anita
2005-01-01
A series of experimental measurements on a modified laboratory NSTAR engine were used to validate a zero dimensional analytical discharge performance model of a ring cusp ion thruster. The model predicts the discharge performance of a ring cusp NSTAR thruster as a function the magnetic field configuration, thruster geometry, and throttle level. Analytical formalisms for electron and ion confinement are used to predict the ionization efficiency for a given thruster design. Explicit determination of discharge loss and volume averaged plasma parameters are also obtained. The model was used to predict the performance of the nominal and modified three and four ring cusp 30-cm ion thruster configurations operating at the full power (2.3 kW) NSTAR throttle level. Experimental measurements of the modified engine configuration discharge loss compare well with the predicted value for propellant utilizations from 80 to 95%. The theory, as validated by experiment, indicates that increasing the magnetic strength of the minimum closed reduces maxwellian electron diffusion and electrostatically confines the ion population and subsequent loss to the anode wall. The theory also indicates that increasing the cusp strength and minimizing the cusp area improves primary electron confinement increasing the probability of an ionization collision prior to loss at the cusp.
1987-12-31
CuCl Excimer Si x Ge Quadropole mass spectrometer ions photoionic emission, threshold low temperature processing low energy ion beam silicon oxidation ...Etching," ECS Proceedings, 1986. C. F. Yu, M. T. Schmidt, D. V. Podlesnik, and R. M. Osgood, "Optically-Induced, Room- Temperature Oxidation of Gallium...MOS transistors with gate dielectrics obtained by ion beam oxidation at room temperature . Introduction control over the process parameters and
Electron parallel closures for various ion charge numbers
DOE Office of Scientific and Technical Information (OSTI.GOV)
Ji, Jeong-Young, E-mail: j.ji@usu.edu; Held, Eric D.; Kim, Sang-Kyeun
2016-03-15
Electron parallel closures for the ion charge number Z = 1 [J.-Y. Ji and E. D. Held, Phys. Plasmas 21, 122116 (2014)] are extended for 1 ≤ Z ≤ 10. Parameters are computed for various Z with the same form of the Z = 1 kernels adopted. The parameters are smoothly varying in Z and hence can be used to interpolate parameters and closures for noninteger, effective ion charge numbers.
2016-06-13
Aberdeen Proving Ground, MD, USA, 21005 Abstract: Lithium manganese oxide spinel is an attractive material for lithium - ion battery cathodes due to...performance allows for access to energy at extended cycling and across potential regimes. Keywords: Li- ion battery ; Lithium manganese oxide spinel...materials for lithium - ion batteries due to their affordability and low toxicity while maintaining reasonable capacity [1-3]. However, this spinel
Electric propulsion system technology
NASA Technical Reports Server (NTRS)
Brophy, John R.; Garner, Charles E.; Goodfellow, Keith D.; Pivirotto, Thomas J.; Polk, James E.
1992-01-01
The work performed in fiscal year (FY) 1991 under the Propulsion Technology Program RTOP (Research and Technology Objectives and Plans) No. (55) 506-42-31 for Low-Thrust Primary and Auxiliary Propulsion technology development is described. The objectives of this work fall under two broad categories. The first of these deals with the development of ion engines for primary propulsion in support of solar system exploration. The second with the advancement of steady-state magnetoplasmadynamic (MPD) thruster technology at 100 kW to multimegawatt input power levels. The major technology issues for ion propulsion are demonstration of adequate engine life at the 5 to 10 kW power level and scaling ion engines to power levels of tens to hundreds of kilowatts. Tests of a new technique in which the decelerator grid of a three-grid ion accelerator system is biased negative of neutralizer common potential in order to collect facility induced charge-exchange ions are described. These tests indicate that this SAND (Screen, Accelerator, Negative Decelerator) configuration may enable long duration ion engine endurance tests to be performed at vacuum chamber pressures an order of magnitude higher than previously possible. The corresponding reduction in pumping speed requirements enables endurance tests of 10 kW class ion engines to be performed within the resources of existing technology programs. The results of a successful 5,000-hr endurance of a xenon hollow cathode operating at an emission current of 25 A are described, as well as the initial tests of hollow cathodes operating on a mixture of argon and 3 percent nitrogen. Work performed on the development of carbon/carbon grids, a multi-orifice hollow cathode, and discharge chamber erosion reduction through the addition of nitrogen are also described. Critical applied-field MPD thruster technical issues remain to be resolved, including demonstration of reliable steady-state operation at input powers of hundreds to thousands of kilowatts, achievement of thruster efficiency and specific impulse levels required for missions of interest, and demonstration of adequate engine life at these input power, efficiency, and specific impulse levels. To address these issues we have designed, built, and tested a 100 kW class, radiation-cooled applied-field MPD thruster and a unique dual-beam thrust stand that enables separate measurements of the applied- and self-field thrust components. We have also initiated the development of cathode thermal and plasma sheath models that will eventually be used to guide the experimental program. In conjunction with the cathode modeling, a new cathode test facility is being constructed. This facility will support the study of cathode thermal behavior and erosion mechanisms, the diagnosis of the near-cathode plasma and the development and endurance testing of new, high-current cathode designs. To facilitate understanding of electrode surface phenomenon, we have implemented a telephoto technique to obtain photographs of the electrodes during engine operation. In order to reduce the background vacuum tank pressure during steady-state engine operation in order to obtain high fidelity anode thermal data, we have developed and are evaluating a gas-dynamic diffuser. A review of experience with alkali metal propellants for MPD thrusters led to the conclusion that alkali metals, particularly lithium, offer the potential for significant engine performance and lifetime improvements. These propellants are also condensible at room temperature, substantially reducing test facility pumping requirements. The most significant systems-level issue is the potential for spacecraft contamination. Subsequent experimental and theoretical efforts should be directed toward verifying the performance and lifetime gains and characterizing the thruster flow field to assess its impact on spacecraft surfaces. Consequently, we have begun the design and development of a new facility to study engine operation with alkali metal propellants.
Magnetic Field Would Reduce Electron Backstreaming in Ion Thrusters
NASA Technical Reports Server (NTRS)
Foster, John E.
2003-01-01
The imposition of a magnetic field has been proposed as a means of reducing the electron backstreaming problem in ion thrusters. Electron backstreaming refers to the backflow of electrons into the ion thruster. Backstreaming electrons are accelerated by the large potential difference that exists between the ion-thruster acceleration electrodes, which otherwise accelerates positive ions out of the engine to develop thrust. The energetic beam formed by the backstreaming electrons can damage the discharge cathode, as well as other discharge surfaces upstream of the acceleration electrodes. The electron-backstreaming condition occurs when the center potential of the ion accelerator grid is no longer sufficiently negative to prevent electron diffusion back into the ion thruster. This typically occurs over extended periods of operation as accelerator-grid apertures enlarge due to erosion. As a result, ion thrusters are required to operate at increasingly negative accelerator-grid voltages in order to prevent electron backstreaming. These larger negative voltages give rise to higher accelerator grid erosion rates, which in turn accelerates aperture enlargement. Electron backstreaming due to accelerator-gridhole enlargement has been identified as a failure mechanism that will limit ionthruster service lifetime. The proposed method would make it possible to not only reduce the electron backstreaming current at and below the backstreaming voltage limit, but also reduce the backstreaming voltage limit itself. This reduction in the voltage at which electron backstreaming occurs provides operating margin and thereby reduces the magnitude of negative voltage that must be placed on the accelerator grid. Such a reduction reduces accelerator- grid erosion rates. The basic idea behind the proposed method is to impose a spatially uniform magnetic field downstream of the accelerator electrode that is oriented transverse to the thruster axis. The magnetic field must be sufficiently strong to impede backstreaming electrons, but not so strong as to significantly perturb ion trajectories. An electromagnet or permanent magnetic circuit can be used to impose the transverse magnetic field downstream of the accelerator-grid electrode. For example, in the case of an accelerator grid containing straight, parallel rows of apertures, one can apply nearly uniform magnetic fields across all the apertures by the use of permanent magnets of alternating polarity connected to pole pieces laid out parallel to the rows, as shown in the left part of the figure. For low-temperature operation, the pole pieces can be replaced with bar magnets of alternating polarity. Alternatively, for the same accelerator grid, one could use an electromagnet in the form of current-carrying rods laid out parallel to the rows.
Engineering approaches and compromises in the design of small ion mobility spectrometers
NASA Technical Reports Server (NTRS)
Bradshaw, R. F. D.
1995-01-01
The engineering approaches in the design phase of small portable I.M.S.-based instruments are discussed. The choices available are described, and their effect on instrument dimensions analyzed. Possible future developments are outlined.
Charron, Richard; Pierce, Daniel
2015-08-11
A shaft cover support for a gas turbine engine is disclosed. The shaft cover support not only provides enhanced support to a shaft cover of the gas turbine engine, but also includes a cooling fluid chamber for passing fluids from a rotor air cooling supply conduit to an inner ring cooling manifold. Furthermore, the shaft cover support may include a cooling shield supply extending from the cooling fluid chamber between the radially outward inlet and the radially inward outlet on the radially extending region and in fluid communication with the cooling fluid chamber for providing cooling fluids to a transition section. The shaft cover support may also provide additional stiffness and reduce interference of the flow from the compressor. In addition, the shaft cover support accommodates a transition section extending between compressor and turbine sections of the gas turbine engine.
Metallo-supramolecular modules as a paradigm for materials science
Kurth, Dirk G.
2008-01-01
Metal ion coordination in discrete or extended metallo-supramolecular assemblies offers ample opportunity to fabricate and study devices and materials that are equally important for fundamental research and new technologies. Metal ions embedded in a specific ligand field offer diverse thermodynamic, kinetic, chemical, physical and structural properties that make these systems promising candidates for active components in functional materials. A key challenge is to improve and develop methodologies for placing these active modules in suitable device architectures, such as thin films or mesophases. This review highlights recent developments in extended, polymeric metallo-supramolecular systems and discrete polyoxometalates with an emphasis on materials science. PMID:27877929
NASA Technical Reports Server (NTRS)
Sovey, James S. (Technical Monitor); Williams, George J., Jr.
2004-01-01
Relative erosion rates and impingement ion production mechanisms have been identified for the discharge cathode of a 30 cm ion engine using laser-induced fluorescence (LIF). Mo and W erosion products as well as neutral and singly ionized xenon were interrogated. The erosion increased with both discharge current and voltage and spatially resolved measurements agreed with observed erosion patters. Ion velocity mapping identified back-flowing ions near the regions of erosion with energies potentially sufficient to generate the level of observed erosion. Ion production regions downstream of the cathode were indicated and were suggested as possible sources of the erosion causing ions.
NASA Astrophysics Data System (ADS)
Shantappa, Anil; Talukdar, Keka
2018-04-01
Ion channels are proteins forming pore inside the body of all living organisms. This potassium ion channel known as KcsA channel and it is found in the each cell and nervous system. Flow of various ions is regulated by the function of the ion channels. The nerve ion channel protein with protein data bank entry 1BL8, which is basically an ion channel protein in Streptomyces Lividans and which is taken up to form micelle-protein system and the system is analyzed by using molecular dynamics simulation. Firstly, ion channel pore is engineered by CHARMM potential and then Micelle-protein system is subjected to molecular dynamics simulation. For some specific micelle concentration, the protein unfolding is observed.
Lateral Structure Formation in Polyelectrolyte Brushes Induced by Multivalent Ions
DOE Office of Scientific and Technical Information (OSTI.GOV)
Brettmann, Blair; Pincus, Philip; Tirrell, Matthew
2017-01-13
We provide a theoretical model for the collapse of polyelectrolyte brushes in the presence of multivalent ions, focusing on the formation of lateral inhomogeneties in the collapsed state. Polyelectrolyte brushes are important in a variety of applications, including stabilizing colloidal particles and lubricating surfaces. Many uses rely on the extension of the densely grafted polymer chains from the surface in the extended brush morphology. In the presence Extended Brush of multivalent ions, brushes are significantly shorter than in monovalent ionic solutions, which greatly affects their properties. We base our theoretical analysis on an analogous collapse of polyelectrolyte brushes in amore » poor solvent, providing an energy balance representation for pinned micelles and cylindrical bundles. The equilibrium brush heights predicted for these structures are of a similar magnitude to those measured experimentally. The formation of lateral structures can open new avenues for stimuli-responsive applications that rely on nanoscale pattern formation on surfaces.« less
A Framework for Performing Verification and Validation in Reuse Based Software Engineering
NASA Technical Reports Server (NTRS)
Addy, Edward A.
1997-01-01
Verification and Validation (V&V) is currently performed during application development for many systems, especially safety-critical and mission- critical systems. The V&V process is intended to discover errors, especially errors related to critical processing, as early as possible during the development process. The system application provides the context under which the software artifacts are validated. This paper describes a framework that extends V&V from an individual application system to a product line of systems that are developed within an architecture-based software engineering environment. This framework includes the activities of traditional application-level V&V, and extends these activities into domain engineering and into the transition between domain engineering and application engineering. The framework includes descriptions of the types of activities to be performed during each of the life-cycle phases, and provides motivation for the activities.
Plasma focus ion beam-scaling laws
NASA Astrophysics Data System (ADS)
Saw, S. H.
2014-08-01
Measurements on plasma focus ion beams include various advanced techniques producing a variety of data which has yet to produce benchmark numbers. Recent numerical experiments using an extended version of the Lee Code has produced reference numbers and scaling trends for number and energy fluence of deuteron beams as functions of stored energy E0. At the pinch exit the ion number fluence (ions m-2) and energy fluence (J m-2) computed as 2.4-7.8×1020 and 2.2-33×106 respectively were found to be independent of E0 from 0.4 - 486 kJ. This work was extended to the ion beams for various gases. The results show that, for a given plasma focus, the fluence, flux, ion number and ion current decrease from the lightest to the heaviest gas except for trend-breaking higher values for Ar fluence and flux. The energy fluence, energy flux, power flow and damage factors are relatively constant from H2 to N2 but increase for Ne, Ar, Kr and Xe due to radiative cooling and collapse effects. This paper reviews this work and in a concluding section attempts to put the accumulating large amounts of data into the form of a scaling law of beam energy Ebeam versus storage energy E0 taking the form for deuteron as: {Ebeam} = 18.2{E}01.23; where Ebeam is in J and E0 is in kJ. It is hoped that the establishment of such scaling laws places on a firm footing the reference quantitative ideas for plasma focus ion beams.
On-Board Real-Time Optimization Control for Turbo-Fan Engine Life Extending
NASA Astrophysics Data System (ADS)
Zheng, Qiangang; Zhang, Haibo; Miao, Lizhen; Sun, Fengyong
2017-11-01
A real-time optimization control method is proposed to extend turbo-fan engine service life. This real-time optimization control is based on an on-board engine mode, which is devised by a MRR-LSSVR (multi-input multi-output recursive reduced least squares support vector regression method). To solve the optimization problem, a FSQP (feasible sequential quadratic programming) algorithm is utilized. The thermal mechanical fatigue is taken into account during the optimization process. Furthermore, to describe the engine life decaying, a thermal mechanical fatigue model of engine acceleration process is established. The optimization objective function not only contains the sub-item which can get fast response of the engine, but also concludes the sub-item of the total mechanical strain range which has positive relationship to engine fatigue life. Finally, the simulations of the conventional optimization control which just consider engine acceleration performance or the proposed optimization method have been conducted. The simulations demonstrate that the time of the two control methods from idle to 99.5 % of the maximum power are equal. However, the engine life using the proposed optimization method could be surprisingly increased by 36.17 % compared with that using conventional optimization control.
Unraveling halide hydration: A high dilution approach.
Migliorati, Valentina; Sessa, Francesco; Aquilanti, Giuliana; D'Angelo, Paola
2014-07-28
The hydration properties of halide aqua ions have been investigated combining classical Molecular Dynamics (MD) with Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy. Three halide-water interaction potentials recently developed [M. M. Reif and P. H. Hünenberger, J. Chem. Phys. 134, 144104 (2011)], along with three plausible choices for the value of the absolute hydration free energy of the proton (ΔG [minus sign in circle symbol]hyd[H+]), have been checked for their capability to properly describe the structural properties of halide aqueous solutions, by comparing the MD structural results with EXAFS experimental data. A very good agreement between theory and experiment has been obtained with one parameter set, namely LE, thus strengthening preliminary evidences for a ΔG [minus sign in circle symbol]hyd[H] value of -1100 kJ mol(-1) [M. M. Reif and P. H. Hünenberger, J. Chem. Phys. 134, 144104 (2011)]. The Cl(-), Br(-), and I(-) ions have been found to form an unstructured and disordered first hydration shell in aqueous solution, with a broad distribution of instantaneous coordination numbers. Conversely, the F(-) ion shows more ordered and defined first solvation shell, with only two statistically relevant coordination geometries (six and sevenfold complexes). Our thorough investigation on the effect of halide ions on the microscopic structure of water highlights that the perturbation induced by the Cl(-), Br(-), and I(-) ions does not extend beyond the ion first hydration shell, and the structure of water in the F(-) second shell is also substantially unaffected by the ion.
Heavy ions in Jupiter's environment
NASA Technical Reports Server (NTRS)
Brown, R. A.
1980-01-01
The extended atmosphere of the Jupiter system consists of atoms and ions of heavy elements. This material originates on the satellite Io. Energy is lost from the thermal plasma in collisionally excited optical and ultraviolet emission. The juxtaposition of Earth and spacecraft measurements provide insight concerning the underlying processes of particle transport and energy supply.
The objectives of the study are to develop an understanding of the electrodeposition of copper onto extended-area electrodes, and of the adsorption/desorption of copper onto ion exchange resins with a high affinity for copper. The principles elucidated in this work will pave the ...
Alternative Fuels Data Center: Electricity Related Links
-performance safe lithium-ion (Li-ion) batteries for hybrid electric vehicles (HEVs), plug-in HEVs (PHEVs) and ) manufacturers alternative energy vehicles, specializing in battery electric vehicles (BEV) and range extended (NREL) Energy Storage Project is leading the charge on battery thermal management, modeling, and systems
NASA Astrophysics Data System (ADS)
Zheng, Yuejiu; Gao, Wenkai; Ouyang, Minggao; Lu, Languang; Zhou, Long; Han, Xuebing
2018-04-01
State-of-charge (SOC) inconsistency impacts the power, durability and safety of the battery pack. Therefore, it is necessary to measure the SOC inconsistency of the battery pack with good accuracy. We explore a novel method for modeling and estimating the SOC inconsistency of lithium-ion (Li-ion) battery pack with low computation effort. In this method, a second-order RC model is selected as the cell mean model (CMM) to represent the overall performance of the battery pack. A hypothetical Rint model is employed as the cell difference model (CDM) to evaluate the SOC difference. The parameters of mean-difference model (MDM) are identified with particle swarm optimization (PSO). Subsequently, the mean SOC and the cell SOC differences are estimated by using extended Kalman filter (EKF). Finally, we conduct an experiment on a small Li-ion battery pack with twelve cells connected in series. The results show that the evaluated SOC difference is capable of tracking the changing of actual value after a quick convergence.
Failure detection and correction for turbofan engines
NASA Technical Reports Server (NTRS)
Corley, R. C.; Spang, H. A., III
1977-01-01
In this paper, a failure detection and correction strategy for turbofan engines is discussed. This strategy allows continuing control of the engines in the event of a sensor failure. An extended Kalman filter is used to provide the best estimate of the state of the engine based on currently available sensor outputs. Should a sensor failure occur the control is based on the best estimate rather than the sensor output. The extended Kalman filter consists of essentially two parts, a nonlinear model of the engine and up-date logic which causes the model to track the actual engine. Details on the model and up-date logic are presented. To allow implementation, approximations are made to the feedback gain matrix which result in a single feedback matrix which is suitable for use over the entire flight envelope. The effect of these approximations on stability and response is discussed. Results from a detailed nonlinear simulation indicate that good control can be maintained even under multiple failures.
Fuel burner and combustor assembly for a gas turbine engine
Leto, Anthony
1983-01-01
A fuel burner and combustor assembly for a gas turbine engine has a housing within the casing of the gas turbine engine which housing defines a combustion chamber and at least one fuel burner secured to one end of the housing and extending into the combustion chamber. The other end of the fuel burner is arranged to slidably engage a fuel inlet connector extending radially inwardly from the engine casing so that fuel is supplied, from a source thereof, to the fuel burner. The fuel inlet connector and fuel burner coact to anchor the housing against axial movement relative to the engine casing while allowing relative radial movement between the engine casing and the fuel burner and, at the same time, providing fuel flow to the fuel burner. For dual fuel capability, a fuel injector is provided in said fuel burner with a flexible fuel supply pipe so that the fuel injector and fuel burner form a unitary structure which moves with the fuel burner.
High-Heat-Flux Cyclic Durability of Thermal and Environmental Barrier Coatings
NASA Technical Reports Server (NTRS)
Zhu, Dongming; Ghosn, Louis L.; Miller, Robert A.
2007-01-01
Advanced ceramic thermal and environmental barrier coatings will play an increasingly important role in future gas turbine engines because of their ability to protect the engine components and further raise engine temperatures. For the supersonic vehicles currently envisioned in the NASA fundamental aeronautics program, advanced gas turbine engines will be used to provide high power density thrust during the extended supersonic flight of the aircraft, while meeting stringent low emission requirements. Advanced ceramic coating systems are critical to the performance, life and durability of the hot-section components of the engine systems. In this work, the laser and burner rig based high-heat-flux testing approaches were developed to investigate the coating cyclic response and failure mechanisms under simulated supersonic long-duration cruise mission. The accelerated coating cracking and delamination mechanism under the engine high-heat-flux, and extended supersonic cruise time conditions will be addressed. A coating life prediction framework may be realized by examining the crack initiation and propagation in conjunction with environmental degradation under high-heat-flux test conditions.
ERIC Educational Resources Information Center
Morozov, Andrew; Kilgore, Deborah; Yasuhara, Ken; Atman, Cindy
2008-01-01
There is evidence in the literature that women have lower confidence in their skills and knowledge than men, particularly in areas considered crucial for engineering, like math and science. This difference has been linked to gender gaps in engineering enrollment and persistence. This study of engineering students extends research on gender…
ERIC Educational Resources Information Center
Lord, Susan M.; Layton, Richard A.; Ohland, Matthew W.
2015-01-01
Electrical Engineering (EE) and Computer Engineering (CpE) programs have similar curricula, but different demographics and student outcomes. This paper extends earlier longitudinal studies to a larger and more diverse dataset with 90,000 first-time-in-college and 26,000 transfer students who majored in engineering at USA institutions, including…
Electromagnetic Spacecraft Propulsion Motor and a Permanent Magnet (PM-Drive) Thruster
NASA Astrophysics Data System (ADS)
Ahmadov, B. A.
2018-04-01
Ion thrusters are designed to be used for realization of a Mars Sample Return mission. The competing technologies with ion thrusters are electromagnetic spacecraft propulsion motors. I'm an engineer and engage in the creation of the new electromagnetic propulsion motors.
Glass-based integrated optical splitters: engineering oriented research
NASA Astrophysics Data System (ADS)
Hao, Yinlei; Zheng, Weiwei; Yang, Jianyi; Jiang, Xiaoqing; Wang, Minghua
2010-10-01
Optical splitter is one of most typical device heavily demanded in implementation of Fiber To The Home (FTTH) system. Due to its compatibility with optical fibers, low propagation loss, flexibility, and most distinguishingly, potentially costeffectiveness, glass-based integrated optical splitters made by ion-exchange technology promise to be very attractive in application of optical communication networks. Aiming at integrated optical splitters applied in optical communication network, glass ion-exchange waveguide process is developed, which includes two steps: thermal salts ion-exchange and field-assisted ion-diffusion. By this process, high performance optical splitters are fabricated in specially melted glass substrate. Main performance parameters of these splitters, including maximum insertion loss (IL), polarization dependence loss (PDL), and IL uniformity are all in accordance with corresponding specifications in generic requirements for optic branching components (GR-1209-CORE). In this paper, glass based integrated optical splitters manufacturing is demonstrated, after which, engineering-oriented research work results on glass-based optical splitter are presented.
2002-12-21
Kennedy Space Center, Florida. - Deep Space 1 is lifted from its work platform, giving a closeup view of the experimental solar-powered ion propulsion engine. The ion propulsion engine is the first non-chemical propulsion to be used as the primary means of propelling a spacecraft. The first flight in NASA's New Millennium Program, Deep Space 1 is designed to validate 12 new technologies for scientific space missions of the next century. Another onboard experiment includes software that tracks celestial bodies so the spacecraft can make its own navigation decisions without the intervention of ground controllers. Deep Space 1 will complete most of its mission objectives within the first two months, but may also do a flyby of a near-Earth asteroid, 1992 KD, in July 1999. Deep Space 1 will be launched aboard a Boeing Delta 7326 rocket from Launch Pad 17A, Cape Canaveral Air Station, in October. Delta II rockets are medium capacity expendable launch vehicles derived from the Delta family of rockets built and launched since 1960. Since then there have been more than 245 Delta launches. http://photojournal.jpl.nasa.gov/catalog/PIA04232
Successful completion of a cyclic ground test of a mercury ion auxiliary propulsion system
NASA Technical Reports Server (NTRS)
Francisco, David R.; Low, Charles A., Jr.; Power, John L.
1988-01-01
An engineering model Ion Auxiliary Propulsion System (IAPS) 8-cm thruster (S/N 905) has completed a life test at NASA Lewis Research Center. The mercury ion thruster successfully completed and exceeded the test goals of 2557 on/off cycles and 7057 hr of operation at full thrust. The final 1200 cycles and 3600 hr of the life test were conducted using an engineering model of the IAPS power electronics unit (PEU) and breadboard digital controller and interface unit (DCIU). This portion of the test is described in this paper with a charted history of thruster operating parameters and off-normal events. Performance and operating characteristics were constant throughout the test with only minor variations. The engineering model power electronics unit operated without malfunction; the flight software in the digital controller and interface unit was exercised and verified. Post-test inspection of the thruster revealed facility enhanced accelerator grid erosion but overall the thruster was in good condition. It was concluded that the thruster performance was not drastically degraded by time or cycles. Additional cyclic testing is currently under consideration.
Successful completion of a cyclic ground test of a mercury Ion Auxiliary Propulsion System
NASA Technical Reports Server (NTRS)
Francisco, David R.; Low, Charles A., Jr.; Power, John L.
1988-01-01
An engineering model Ion Auxiliary Propulsion System (IAPS) 8-cm thruster (S/N 905) has completed a life test at NASA Lewis Research Center. The mercury ion thruster successfully completed and exceeded the test goals of 2557 on/off cycles and 7057 hr of operation at full thrust. The final 1200 cycles and 3600 hr of the life test were conducted using an engineering model of the IAPS power electronics unit (PEU) and breadboard digital controller and interface unit (DCIU). This portion of the test is described in this paper with a charted history of thruster operating parameters and off-normal events. Performance and operating characteristics were constant throughout the test with only minor variations. The engineering model power electronics unit operated without malfunction; the flight software in the digital controller and interface unit was exercised and verified. Post-test inspection of the thruster revealed facility enhanced accelerator grid erosion but overall the thruster was in good condition. It was concluded that the thruster performance was not drastically degraded by time or cycles. Additional cyclic testing is currently under consideration.
NASA Technical Reports Server (NTRS)
Gordon, Sanford
1991-01-01
The NNEP is a general computer program for calculating aircraft engine performance. NNEP has been used extensively to calculate the design and off-design (matched) performance of a broad range of turbine engines, ranging from subsonic turboprops to variable cycle engines for supersonic transports. Recently, however, there has been increased interest in applications for which NNEP is not capable of simulating, such as the use of alternate fuels including cryogenic fuels and the inclusion of chemical dissociation effects at high temperatures. To overcome these limitations, NNEP was extended by including a general chemical equilibrium method. This permits consideration of any propellant system and the calculation of performance with dissociation effects. The new extended program is referred to as NNEP89.
Frequency-scanning MALDI linear ion trap mass spectrometer for large biomolecular ion detection.
Lu, I-Chung; Lin, Jung Lee; Lai, Szu-Hsueh; Chen, Chung-Hsuan
2011-11-01
This study presents the first report on the development of a matrix-assisted laser desorption ionization (MALDI) linear ion trap mass spectrometer for large biomolecular ion detection by frequency scan. We designed, installed, and tested this radio frequency (RF) scan linear ion trap mass spectrometer and its associated electronics to dramatically extend the mass region to be detected. The RF circuit can be adjusted from 300 to 10 kHz with a set of operation amplifiers. To trap the ions produced by MALDI, a high pressure of helium buffer gas was employed to quench extra kinetic energy of the heavy ions produced by MALDI. The successful detection of the singly charged secretory immunoglobulin A ions indicates that the detectable mass-to-charge ratio (m/z) of this system can reach ~385 000 or beyond.
Thrust vectoring of broad ion beams for spacecraft attitude control
NASA Technical Reports Server (NTRS)
Collett, C. R.; King, H. J.
1973-01-01
Thrust vectoring is shown to increase the attractiveness of ion thrusters for satellite control applications. Incorporating beam deflection into ion thrusters makes it possible to achieve attitude control without adding any thrusters. Two beam vectoring systems are described that can provide up to 10-deg beam deflection in any azimuth. Both systems have been subjected to extended life tests on a 5-cm thruster which resulted in projected life times of from 7500 to 20,000 hours.
Intelligent Life-Extending Controls for Aircraft Engines Studied
NASA Technical Reports Server (NTRS)
Guo, Ten-Huei
2005-01-01
Current aircraft engine controllers are designed and operated to provide desired performance and stability margins. Except for the hard limits for extreme conditions, engine controllers do not usually take engine component life into consideration during the controller design and operation. The end result is that aircraft pilots regularly operate engines under unnecessarily harsh conditions to strive for optimum performance. The NASA Glenn Research Center and its industrial and academic partners have been working together toward an intelligent control concept that will include engine life as part of the controller design criteria. This research includes the study of the relationship between control action and engine component life as well as the design of an intelligent control algorithm to provide proper tradeoffs between performance and engine life. This approach is expected to maintain operating safety while minimizing overall operating costs. In this study, the thermomechanical fatigue (TMF) of a critical component was selected to demonstrate how an intelligent engine control algorithm can significantly extend engine life with only a very small sacrifice in performance. An intelligent engine control scheme based on modifying the high-pressure spool speed (NH) was proposed to reduce TMF damage from ground idle to takeoff. The NH acceleration schedule was optimized to minimize the TMF damage for a given rise-time constraint, which represents the performance requirement. The intelligent engine control scheme was used to simulate a commercial short-haul aircraft engine.
Radio frequency multicusp ion source development (invited)
NASA Astrophysics Data System (ADS)
Leung, K. N.
1996-03-01
The radio-frequency (rf) driven multicusp source was originally developed for use in the Superconducting Super Collider injector. It has been demonstrated that the source can meet the H- beam current and emittance requirements for this application. By employing a porcelain-coated antenna, a clean plasma discharge with very long-life operation can be achieved. Today, the rf source is used to generate both positive and negative hydrogen ion beams and has been tested in various particle accelerator laboratories throughout the world. Applications of this ion source have been extended to other fields such as ion beam lithography, oil-well logging, ion implantation, accelerator mass spectrometry and medical therapy machines. This paper summarizes the latest rf ion source technology and development at the Lawrence Berkeley National Laboratory.
Comparison of Hall Thruster Plume Expansion Model with Experimental Data
2006-05-23
focus of this study, is a hybrid particle- in-cell ( PIC ) model that tracks particles along an unstructured tetrahedral mesh. * Research Engineer...measurements of the ion current density profile, ion energy distributions, and ion species fraction distributions using a nude Faraday probe, retarding...Vol.37 No.1. 6 Oh, D. and Hastings, D., “Three Dimensional PIC -DSMC Simulations of Hall Thruster Plumes and Analysis for Realistic Spacecraft
Power supply circuit for an ion engine sequentially operated power inverters
NASA Technical Reports Server (NTRS)
Cardwell, Jr., Gilbert I. (Inventor)
2000-01-01
A power supply circuit for an ion engine suitable for a spacecraft has a voltage bus having input line and a return line. The power supply circuit includes a pulse width modulation circuit. A plurality of bridge inverter circuits is coupled to the bus and the pulse width modulation circuit. The pulse width modulation circuit generates operating signals having a variable duty cycle. Each bridge inverter has a primary winding and a secondary winding. Each secondary winding is coupled to a rectifier bridge. Each secondary winding is coupled in series with another of the plurality of rectifier bridges.
Carbon or graphite foam as a heating element and system thereof
Ott, Ronald D [Knoxville, TN; McMillan, April D [Knoxville, TN; Choudhury, Ashok [Oak Ridge, TN
2004-05-04
A temperature regulator includes at least one electrically conductive carbon foam element. The foam element includes at least two locations adapted for receiving electrical connectors thereto for heating a fluid, such as engine oil. A combustion engine includes an engine block and at least one carbon foam element, the foam element extending into the engine block or disposed in thermal contact with at least one engine fluid.
Unified Engineering Software System
NASA Technical Reports Server (NTRS)
Purves, L. R.; Gordon, S.; Peltzman, A.; Dube, M.
1989-01-01
Collection of computer programs performs diverse functions in prototype engineering. NEXUS, NASA Engineering Extendible Unified Software system, is research set of computer programs designed to support full sequence of activities encountered in NASA engineering projects. Sequence spans preliminary design, design analysis, detailed design, manufacturing, assembly, and testing. Primarily addresses process of prototype engineering, task of getting single or small number of copies of product to work. Written in FORTRAN 77 and PROLOG.
Absolute photon-flux measurements in the vacuum ultraviolet
NASA Technical Reports Server (NTRS)
Samson, J. A. R.; Haddad, G. N.
1974-01-01
Absolute photon-flux measurements in the vacuum ultraviolet have extended to short wavelengths by use of rare-gas ionization chambers. The technique involves the measurement of the ion current as a function of the gas pressure in the ion chamber. The true value of the ion current, and hence the absolute photon flux, is obtained by extrapolating the ion current to zero gas pressure. Examples are given at 162 and 266 A. The short-wavelength limit is determined only by the sensitivity of the current-measuring apparatus and by present knowledge of the photoionization processes that occur in the rate gases.
Method of multiplexed analysis using ion mobility spectrometer
Belov, Mikhail E [Richland, WA; Smith, Richard D [Richland, WA
2009-06-02
A method for analyzing analytes from a sample introduced into a Spectrometer by generating a pseudo random sequence of a modulation bins, organizing each modulation bin as a series of submodulation bins, thereby forming an extended pseudo random sequence of submodulation bins, releasing the analytes in a series of analyte packets into a Spectrometer, thereby generating an unknown original ion signal vector, detecting the analytes at a detector, and characterizing the sample using the plurality of analyte signal subvectors. The method is advantageously applied to an Ion Mobility Spectrometer, and an Ion Mobility Spectrometer interfaced with a Time of Flight Mass Spectrometer.
NASA Astrophysics Data System (ADS)
Roder, Paden Bernard
Laser tweezers and optical trapping has provided scientists and engineers a unique way to study the wealth of phenomena that materials exhibit at the micro- and nanoscale, much of which remains mysterious. Of particular interest is the interplay between light absorption and subsequent heat generation of laser-irradiated materials, especially due to recent interest in developing nanoscale materials for use as agents for photothermal cancer treatments. An introduction to optical trapping physics and laser tweezers are given in Chapter 1 and 2 of this thesis, respectively. The remaining chapters, summarized below, describe the theoretical basis of laser heating of one-dimensional nanostructures and experiments in which optically-trapped nanostructures are studied using techniques developed for a laser tweezer. In Chapter 3, we delve into the fundamentals of laser heating of one-dimensional materials by developing an analytical model of pulsed laser heating of uniform and tapered supported nanowires and compare calculations with experimental data to comment on the effects that the material's physical, optical, and thermal parameters have on its heating and cooling rates. We then consider closed-form analytical solutions for the temperature rise within infinite circular cylinders with nanometer-scale diameters irradiated at right angles by TM-polarized continuous-wave laser sources, which allows for analysis of laser-heated nanowires in a solvated environment. The infinite nanowire analysis will then be extended to the optical heating of laser-irradiated finite nanowires in the framework of a laser tweezer, which enables predictive capabilities and direct comparison with laser trapping experiments. An effective method for determining optically-trapped particle temperatures as well as the temperature gradient in the surrounding medium will be discussed in Chapter 4. By combining laser tweezer calibration techniques, forward-scattered light power spectrum analysis, and hot Brownian motion theory, we attempt to measure realistic temperatures at the surface of an optically-trapped particle while properly accounting for inhomogeneous temperature fields generated by the optical trap. In Chapter 5, this technique is then applied to measure the temperature of engineered gold- and silicon-implanted silicon nanowires to rigorously study the effect ion implantation has on silicon nanowire photothermal efficiencies. Silicon nanowire photothermal efficiencies are shown to drastically increase by implanting with gold ions and cause superheating of water of over 200 C at the trap site, suggesting potential application as agents for photothermal cancer therapies. Chapter 6 describes the hydrothermal synthesis and optical trapping of engineered YLF nanoparticles doped with Yb(III) ions. Laser tweezer experiments using the developed temperature extraction techniques and hot Brownian motion analysis show the first observation of particles undergoing recently hypothesized cold Brownian motion and local laser refrigeration in a condensed phase via anti-Stokes photoluminescence. Furthermore, YLF nanoparticles codoped with Er(III) and Yb(III) ions are also developed and their intense visible upconversion of the NIR trapping laser is used to monitor its internal lattice temperature using ratiometric thermography. The results suggest the potential of these materials to investigate kinetics and temperature sensitivity of basic cellular processes, or to act as simultaneous theranostic-hypothermia agents to identify and treat cancerous tissues. Finally, Chapter 7 presents a summary of the salient conclusions of the reported studies. The chapter concludes with a short discussion of my personal experience with being a member of a new research group and setting up the Pauzauskie laboratory.
Existence domains of slow and fast ion-acoustic solitons in two-ion space plasmas
DOE Office of Scientific and Technical Information (OSTI.GOV)
Maharaj, S. K., E-mail: smaharaj@sansa.org.za; Bharuthram, R., E-mail: rbharuthram@uwc.ac.za; Singh, S. V., E-mail: satyavir@iigs.iigm.res.in
2015-03-15
A study of large amplitude ion-acoustic solitons is conducted for a model composed of cool and hot ions and cool and hot electrons. Using the Sagdeev pseudo-potential formalism, the scope of earlier studies is extended to consider why upper Mach number limitations arise for slow and fast ion-acoustic solitons. Treating all plasma constituents as adiabatic fluids, slow ion-acoustic solitons are limited in the order of increasing cool ion concentrations by the number densities of the cool, and then the hot ions becoming complex valued, followed by positive and then negative potential double layer regions. Only positive potentials are found formore » fast ion-acoustic solitons which are limited only by the hot ion number density having to remain real valued. The effect of neglecting as opposed to including inertial effects of the hot electrons is found to induce only minor quantitative changes in the existence regions of slow and fast ion-acoustic solitons.« less
Ion optical design of a collinear laser-negative ion beam apparatus.
Diehl, C; Wendt, K; Lindahl, A O; Andersson, P; Hanstorp, D
2011-05-01
An apparatus for photodetachment studies on atomic and molecular negative ions of medium up to heavy mass (M ≃ 500) has been designed and constructed. Laser and ion beams are merged in the apparatus in a collinear geometry and atoms, neutral molecules and negative ions are detected in the forward direction. The ion optical design and the components used to optimize the mass resolution and the transmission through the extended field-free interaction region are described. A 90° sector field magnet with 50 cm bending radius in combination with two slits is used for mass dispersion providing a resolution of M∕ΔM≅800 for molecular ions and M∕ΔM≅400 for atomic ions. The difference in mass resolution for atomic and molecular ions is attributed to different energy distributions of the sputtered ions. With 1 mm slits, transmission from the source through the interaction region to the final ion detector was determined to be about 0.14%.
Extending the frontiers of mass spectrometric instrumentation and methods
DOE Office of Scientific and Technical Information (OSTI.GOV)
Schieffer, Gregg Martin
2010-01-01
The focus of this dissertation is two-fold: developing novel analysis methods using mass spectrometry and the implementation and characterization of a novel ion mobility mass spectrometry instrumentation. The novel mass spectrometry combines ion trap for ion/ion reactions coupled to an ion mobility cell. The long term goal of this instrumentation is to use ion/ion reactions to probe the structure of gas phase biomolecule ions. The three ion source - ion trap - ion mobility - qTOF mass spectrometer (IT - IM - TOF MS) instrument is described. The analysis of the degradation products in coal (Chapter 2) and the imagingmore » plant metabolites (Appendix III) fall under the methods development category. These projects use existing commercial instrumentation (JEOL AccuTOF MS and Thermo Finnigan LCQ IT, respectively) for the mass analysis of the degraded coal products and the plant metabolites, respectively. The coal degradation paper discusses the use of the DART ion source for fast and easy sample analysis. The sample preparation consisted of a simple 50 fold dilution of the soluble coal products in water and placing the liquid in front of the heated gas stream. This is the first time the DART ion source has been used for analysis of coal. Steven Raders under the guidance of John Verkade came up with the coal degradation projects. Raders performed the coal degradation reactions, worked up the products, and sent them to me. Gregg Schieffer developed the method and wrote the paper demonstrating the use of the DART ion source for the fast and easy sample analysis. The plant metabolite imaging project extends the use of colloidal graphite as a sample coating for atmospheric pressure LDI. DC Perdian and I closely worked together to make this project work. Perdian focused on building the LDI setup whereas Schieffer focused on the MSn analysis of the metabolites. Both Perdian and I took the data featured in the paper. Perdian was the primary writer of the paper and used it as a chapter in his dissertation. Perdian and Schieffer worked together to address the revisions and publish it in Rapid Communications in Mass Spectrometry Journal.« less
Observing Planets and Small Bodies in Sputtered High Energy Atom (SHEA) Fluxes
NASA Technical Reports Server (NTRS)
Milillo, A.; Orsini, S.; Hsieh, K. C.; Baragiola, R.; Fama, M.; Johnson, R.; Mura, A.; Plainaki, Ch.; Sarantos, M.; Cassidy, T. A.;
2012-01-01
The evolution of the surfaces of bodies unprotected by either strong magnetic fields or thick atmospheres in the Solar System is caused by various processes, induced by photons, energetic ions and micrometeoroids. Among these processes, the continuous bombardment of the solar wind or energetic magnetospheric ions onto the bodies may significantly affect their surfaces, with implications for their evolution. Ion precipitation produces neutral atom releases into the exosphere through ion sputtering, with velocity distribution extending well above the particle escape limits. We refer to this component of the surface ejecta as sputtered high-energy atoms (SHEA). The use of ion sputtering emission for studying the interaction of exposed bodies (EB) with ion environments is described here. Remote sensing in SHEA in the vicinity of EB can provide mapping of the bodies exposed to ion sputtering action with temporal and mass resolution. This paper speculates on the possibility of performing remote sensing of exposed bodies using SHEA The evolution of the surfaces of bodies unprotected by either strong magnetic fields or thick atmospheres in the Solar System is caused by various processes, induced by photons, energetic ions and micrometeoroids. Among these processes, the continuous bombardment of the solar wind or energetic magnetospheric ions onto the bodies may significantly affect their surfaces, with implications for their evolution. Ion precipitation produces neutral atom releases into the exosphere through ion sputtering, with velocity distribution extending well above the particle escape limits. We refer to this component of the surface ejecta as sputtered high-energy atoms (SHEA). The use of ion sputtering emission for studying the interaction of exposed bodies (EB) with ion environments is described here. Remote sensing in SHEA in the vicinity of EB can provide mapping of the bodies exposed to ion sputtering action with temporal and mass resolution. This paper speculates on the possibility of performing remote sensing of exposed bodies using SHEA and suggests the need for quantitative results from laboratory simulations and molecular physic modeling in order to understand SHEA data from planetary missions. In the Appendix, referenced computer simulations using existing sputtering data are reviewed.
Thin film separators with ion transport properties for energy applications
NASA Astrophysics Data System (ADS)
Li, Zhongyuan
2017-09-01
Recent years, along with the increasing need of energy, energy storage also becomes a challenging problem which we need to deal with. The batterieshave a good developing prospect among energy storage system in storing energy such as wind, solar and geothermal energy. One hurdle between the lab-scale experiment and industry-scale application of the advanced batteries is the urgent need for limiting charging capacity degradation and improving cycling stability, known as the shuttle effect in lithium-sulfur batteries or electroosmotic drag coefficient in fuel-cell batteries. The microporous separator between the cathode and anode could be molecular engineered to possessesion selective permeation properties, which can greatly improves the energy efficiency and extends application range of the battery. The present review offers the fundamental fabrication methods of separator film with different material. The review also contains the chemical or physical structure of different materials which are used in making separator film. A table offers the reader a summary of properties such as ionic conductivity, ionic exchange capacity and current density etc.
Efficient and Extensible Quasi-Explicit Modular Nonlinear Multiscale Battery Model: GH-MSMD
DOE Office of Scientific and Technical Information (OSTI.GOV)
Kim, Gi-Heon; Smith, Kandler; Lawrence-Simon, Jake
Complex physics and long computation time hinder the adoption of computer aided engineering models in the design of large-format battery cells and systems. A modular, efficient battery simulation model -- the multiscale multidomain (MSMD) model -- was previously introduced to aid the scale-up of Li-ion material and electrode designs to complete cell and pack designs, capturing electrochemical interplay with 3-D electronic current pathways and thermal response. Here, this paper enhances the computational efficiency of the MSMD model using a separation of time-scales principle to decompose model field variables. The decomposition provides a quasi-explicit linkage between the multiple length-scale domains andmore » thus reduces time-consuming nested iteration when solving model equations across multiple domains. In addition to particle-, electrode- and cell-length scales treated in the previous work, the present formulation extends to bus bar- and multi-cell module-length scales. We provide example simulations for several variants of GH electrode-domain models.« less
Efficient and Extensible Quasi-Explicit Modular Nonlinear Multiscale Battery Model: GH-MSMD
Kim, Gi-Heon; Smith, Kandler; Lawrence-Simon, Jake; ...
2017-03-24
Complex physics and long computation time hinder the adoption of computer aided engineering models in the design of large-format battery cells and systems. A modular, efficient battery simulation model -- the multiscale multidomain (MSMD) model -- was previously introduced to aid the scale-up of Li-ion material and electrode designs to complete cell and pack designs, capturing electrochemical interplay with 3-D electronic current pathways and thermal response. Here, this paper enhances the computational efficiency of the MSMD model using a separation of time-scales principle to decompose model field variables. The decomposition provides a quasi-explicit linkage between the multiple length-scale domains andmore » thus reduces time-consuming nested iteration when solving model equations across multiple domains. In addition to particle-, electrode- and cell-length scales treated in the previous work, the present formulation extends to bus bar- and multi-cell module-length scales. We provide example simulations for several variants of GH electrode-domain models.« less
Solar Proton Transport Within an ICRU Sphere Surrounded by a Complex Shield: Ray-trace Geometry
NASA Technical Reports Server (NTRS)
Slaba, Tony C.; Wilson, John W.; Badavi, Francis F.; Reddell, Brandon D.; Bahadori, Amir A.
2015-01-01
A computationally efficient 3DHZETRN code with enhanced neutron and light ion (Z is less than or equal to 2) propagation was recently developed for complex, inhomogeneous shield geometry described by combinatorial objects. Comparisons were made between 3DHZETRN results and Monte Carlo (MC) simulations at locations within the combinatorial geometry, and it was shown that 3DHZETRN agrees with the MC codes to the extent they agree with each other. In the present report, the 3DHZETRN code is extended to enable analysis in ray-trace geometry. This latest extension enables the code to be used within current engineering design practices utilizing fully detailed vehicle and habitat geometries. Through convergence testing, it is shown that fidelity in an actual shield geometry can be maintained in the discrete ray-trace description by systematically increasing the number of discrete rays used. It is also shown that this fidelity is carried into transport procedures and resulting exposure quantities without sacrificing computational efficiency.
Solar proton exposure of an ICRU sphere within a complex structure part II: Ray-trace geometry.
Slaba, Tony C; Wilson, John W; Badavi, Francis F; Reddell, Brandon D; Bahadori, Amir A
2016-06-01
A computationally efficient 3DHZETRN code with enhanced neutron and light ion (Z ≤ 2) propagation was recently developed for complex, inhomogeneous shield geometry described by combinatorial objects. Comparisons were made between 3DHZETRN results and Monte Carlo (MC) simulations at locations within the combinatorial geometry, and it was shown that 3DHZETRN agrees with the MC codes to the extent they agree with each other. In the present report, the 3DHZETRN code is extended to enable analysis in ray-trace geometry. This latest extension enables the code to be used within current engineering design practices utilizing fully detailed vehicle and habitat geometries. Through convergence testing, it is shown that fidelity in an actual shield geometry can be maintained in the discrete ray-trace description by systematically increasing the number of discrete rays used. It is also shown that this fidelity is carried into transport procedures and resulting exposure quantities without sacrificing computational efficiency. Published by Elsevier Ltd.
Solar Electric Propulsion Vehicle Design Study for Cargo Transfer to Earth-moon L1
NASA Technical Reports Server (NTRS)
Sarver-Verhey, Timothy R.; Kerslake, Thomas W.; Rawlin, Vincent K.; Falck, Robert D.; Dudzinski, Leonard J.; Oleson, Steven R.
2002-01-01
A design study for a cargo transfer vehicle using solar electric propulsion was performed for NASA's Revolutionary Aerospace Systems Concepts program. Targeted for 2016, the solar electric propulsion (SEP) transfer vehicle is required to deliver a propellant supply module with a mass of approximately 36 metric tons from Low Earth Orbit to the first Earth-Moon libration point (LL1) within 270 days. Following an examination of propulsion and power technology options, a SEP transfer vehicle design was selected that incorporated large-area (approx. 2700 sq m) thin film solar arrays and a clustered engine configuration of eight 50 kW gridded ion thrusters mounted on an articulated boom. Refinement of the SEP vehicle design was performed iteratively to properly estimate the required xenon propellant load for the out-bound orbit transfer. The SEP vehicle performance, including the xenon propellant estimation, was verified via the SNAP trajectory code. Further efforts are underway to extend this system model to other orbit transfer missions.
Broadband light trapping in nanotextured thin film photovoltaic devices
NASA Astrophysics Data System (ADS)
Mennucci, Carlo; Muhammad, M. H.; Hameed, Mohamed Farhat O.; Mohamed, Shaimaa A.; Abdelkhalik, Mohamed S.; Obayya, S. S. A.; Buatier de Mongeot, Francesco
2018-07-01
Substrates with engineered roughness are studied with the aim of achieving broadband and omnidirectional photon harvesting in thin film devices. Light coupling across the interfaces of a photonic device is induced by uniaxial pseudo-periodic gratings formed in a self-organised fashion via de-focused ion beam sputtering (IBS). The optical properties of the textured interfaces are assessed both experimentally and numerically using finite difference time domain (FDTD) algorithm, quantitatively demonstrating the optimal geometries which favour broadband diffuse scattering of radiation across the Vis-NIR spectral range. Thin film amorphous silicon solar cells based on the nanostructured patterns have been numerically studied via FDTD to assess absorption enhancement in comparison to flat reference devices, finding a 25% increase of short-circuit current, in good agreement with the experiment. Similar light trapping experiments performed on prototypical solar cells employing a PTB7:PC61BM organic absorber, allow to extend the general validity of the results to a relevant class of materials in the view of photovoltaic applications.
Foam-lined hohlraums at the National Ignition Facility
NASA Astrophysics Data System (ADS)
Thomas, Cliff
2017-10-01
Indirect drive inertial confinement fusion (ICF) is made difficult by hohlraum wall motion, laser backscatter, x-ray preheat, high-energy electrons, and specular reflection of the incident laser (i.e. glint). To mitigate, we line the hohlraum with a low-density metal foam, or tamper, whose properties can be readily engineered (opacity, density, laser absorption, ion-acoustic damping, etc.). We motivate the use of low-density foams for these purposes, discuss their development, and present initial findings. Importantly, we demonstrate that we can fabricate a 200-500 um thick liner at densities of 10-100 mg/cm3 that could extend the capabilities of existing physics platforms. The goal of this work is to increase energy coupled to the capsule, and maximize the yield available to science missions at the National Ignition Facility. This work was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344.
Spectroscopic investigations of beam-plasma interactions in an ion plume
NASA Technical Reports Server (NTRS)
Ruyten, W. M.; Friedly, V. J.; Peng, X.; Celenza, J. A.; Keefer, D.
1993-01-01
We report the results of spectroscopic investigations of beam-plasma interactions in the plume from a 3 cm ion source operated on argon. Ion-electron, ion-neutral, and electron-neutral scattering are identified by studying the dependence of neutral and ion emission intensities on chamber pressure and mass flow rate, and by analyzing the emission lineshapes at a non-orthogonal angle to the plume axis. Through the Doppler shift, we are able to separate contributions from fast beam ions and fast charge-exchange neutrals on the one hand, and of slow neutrals and slow ions on the other. We discuss the application of this new technique to the characterization of beam plasma interactions in the downstream region of ion thruster engines, and its potential for identifying the processes which lead to grid erosion.
Mathematical model of the current density for the 30-cm engineering model thruster
NASA Technical Reports Server (NTRS)
Cuffel, R. F.
1975-01-01
Mathematical models are presented for both the singly and doubly charged ion current densities downstream of the 30-cm engineering model thruster with 0.5% compensated dished grids. These models are based on the experimental measurements of Vahrenkamp at a 2-amp ion beam operating condition. The cylindrically symmetric beam of constant velocity ions is modeled with continuous radial source and focusing functions across 'plane' grids with similar angular distribution functions. A computer program is used to evaluate the double integral for current densities in the near field and to obtain a far field approximation beyond 10 grid radii. The utility of the model is demonstrated for (1) calculating the directed thrust and (2) determining the impingement levels on various spacecraft surfaces from a two-axis gimballed, 2 x 3 thruster array.
14 CFR Appendix G to Part 135 - Extended Operations (ETOPS)
Code of Federal Regulations, 2010 CFR
2010-01-01
... the FAA; (b) The operation is conducted in a multi-engine transport category turbine-powered airplane... Mexico) with multi-engine transport category turbine-engine powered airplanes. The certificate holder may... speed, corrected for wind and temperature) may not exceed the time specified in the Airplane Flight...
14 CFR Appendix G to Part 135 - Extended Operations (ETOPS)
Code of Federal Regulations, 2013 CFR
2013-01-01
... the FAA; (b) The operation is conducted in a multi-engine transport category turbine-powered airplane... Mexico) with multi-engine transport category turbine-engine powered airplanes. The certificate holder may... speed, corrected for wind and temperature) may not exceed the time specified in the Airplane Flight...
14 CFR Appendix G to Part 135 - Extended Operations (ETOPS)
Code of Federal Regulations, 2012 CFR
2012-01-01
... the FAA; (b) The operation is conducted in a multi-engine transport category turbine-powered airplane... Mexico) with multi-engine transport category turbine-engine powered airplanes. The certificate holder may... speed, corrected for wind and temperature) may not exceed the time specified in the Airplane Flight...
14 CFR Appendix G to Part 135 - Extended Operations (ETOPS)
Code of Federal Regulations, 2011 CFR
2011-01-01
... the FAA; (b) The operation is conducted in a multi-engine transport category turbine-powered airplane... Mexico) with multi-engine transport category turbine-engine powered airplanes. The certificate holder may... speed, corrected for wind and temperature) may not exceed the time specified in the Airplane Flight...
14 CFR Appendix G to Part 135 - Extended Operations (ETOPS)
Code of Federal Regulations, 2014 CFR
2014-01-01
... the FAA; (b) The operation is conducted in a multi-engine transport category turbine-powered airplane... Mexico) with multi-engine transport category turbine-engine powered airplanes. The certificate holder may... speed, corrected for wind and temperature) may not exceed the time specified in the Airplane Flight...
Continuing Education for Scientists and Engineers: Delivery Systems in North Carolina.
ERIC Educational Resources Information Center
Harrell, Daniel E.; Gibbs, Rebecca F.
Focusing on the continuing education (CE) of scientists/engineers in North Carolina working in small (1-500 employees), geographically dispersed companies, this study: 1) identified and described CE resources currently being used by scientists/engineers to maintain and extend their professional competence and capabilities; 2) determined the extent…
Extending Engineering Practice Research with Shared Qualitative Data
ERIC Educational Resources Information Center
Trevelyan, James
2016-01-01
Research on engineering practice is scarce and sharing of qualitative research data can reduce the effort required for an aspiring researcher to obtain enough data from engineering workplaces to draw generalizable conclusions, both qualitative and quantitative. This paper describes how a large shareable qualitative data set on engineering…
Federal Register 2010, 2011, 2012, 2013, 2014
2013-12-09
... Operations (ETOPS) of Multi-Engine Airplanes AGENCY: Federal Aviation Administration (FAA), DOT. ACTION...-0718. Title: Extended Operations (ETOPS) of Multi-Engine Airplanes. Form Numbers: There are no FAA... that permitted certificated air carriers to operate two-engine airplanes over long-range routes and...
14 CFR 23.77 - Balked landing.
Code of Federal Regulations, 2013 CFR
2013-01-01
... reciprocating engine-powered and single engine turbine powered airplane of more than 6,000 pounds maximum weight, and multiengine turbine engine-powered airplane of 6,000 pounds or less maximum weight in the normal... of movement of the power controls from minimum flight-idle position; (2) The landing gear extended...
14 CFR 23.77 - Balked landing.
Code of Federal Regulations, 2014 CFR
2014-01-01
... reciprocating engine-powered and single engine turbine powered airplane of more than 6,000 pounds maximum weight, and multiengine turbine engine-powered airplane of 6,000 pounds or less maximum weight in the normal... of movement of the power controls from minimum flight-idle position; (2) The landing gear extended...
Energetic ion production in high current hollow cathodes
NASA Astrophysics Data System (ADS)
Foster, John; Kovach, Yao; Arthur, Neil; Viges, Eric; Davis, Chris
2015-09-01
High power Hall and gridded ion thrusters are being considered as a propulsion option supporting human operations (cargo or tug) to Mars. These engines utilize hollow cathodes for plasma production and beam neutralization. It has now been well documented that these cathodes produce energetic ions when operated at high current densities. Such ions are observed with peak energies approaching 100 eV. Because these ions can drive erosion of the cathode assembly, they represent a credible failure mode. An understanding of energetic ion production and approaches to mitigation is therefore desired. Presented here are data documenting the presence of energetic ions for both a barium oxide and a lanthanum hexaboride cathode as measured using a retarding potential analyzer. Also presented are energetic ion mitigation approaches, which are designed to eliminate the ion energy transfer mechanism. NASA SBIR Contract NNX15CP62P.
Yuan, Shuang; Liu, Yong-Bing; Xu, Dan; Ma, De-Long; Wang, Sai; Yang, Xiao-Hong; Cao, Zhan-Yi; Zhang, Xin-Bo
2015-03-01
Pure single-crystalline Na 1.1 V 3 O 7.9 nanobelts are successfully synthesized for the first time via a facile yet effective strategy. When used as cathode materials for Na-ion batteries, the novel nanobelts exhibit excellent electrochemical performance. Given the ease and effectiveness of the synthesis route as well as the very promising electrochemical performance, the results obtained may be extended to other next-generation cathode materials for Na-ion batteries.
Robust Battery Fuel Gauge Algorithm Development, Part 3: State of Charge Tracking
2014-10-19
X. Zhang, F. Sun, and J. Fan, “State-of-charge estimation of the lithium - ion battery using an adaptive extended kalman filter based on an improved...framework with ex- tended kalman filter for lithium - ion battery soc and capacity estimation,” Applied Energy, vol. 92, pp. 694–704, 2012. [16] X. Hu, F...Sun, and Y. Zou, “Estimation of state of charge of a lithium - ion battery pack for electric vehicles using an adaptive luenberger observer,” Energies
Luo, Weiwei; Cai, Wei; Xiang, Yinxiao; Wu, Wei; Shi, Bin; Jiang, Xiaojie; Zhang, Ni; Ren, Mengxin; Zhang, Xinzheng; Xu, Jingjun
2017-08-01
Graphene plasmons provide great opportunities in light-matter interactions benefiting from the extreme confinement and electrical tunability. Structured graphene cavities possess enhanced confinements in 3D and steerable plasmon resonances, potential in applications for sensing and emission control at the nanoscale. Besides graphene boundaries obtained by mask lithography, graphene defects engineered by ion beams have shown efficient plasmon reflections. In this paper, near-field responses of structured graphene achieved by ion beam direct-writing are investigated. Graphene nanoresonators are fabricated easily and precisely with a spatial resolution better than 30 nm. Breathing modes are observed in graphene disks. The amorphous carbons around weaken the response of edge modes in the resonators, but meanwhile render the isolated resonators in-plane electrical connections, where near-fields are proved gate-tunable. The realization of gate-tunable near-fields of graphene 2D resonators opens up tunable near-field couplings with matters. Moreover, graphene nonconcentric rings with engineered near-field confinement distributions are demonstrated, where the quadrupole plasmon modes are excited. Near-field mappings reveal concentrations at the scale of 3.8×10-4λ02 within certain zones which can be engineered. The realization of electrically tunable graphene nanoresonators by ion beam direct-writing is promising for active manipulation of emission and sensing at the nanoscale. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
NASA Technical Reports Server (NTRS)
Haag, Thomas W. (Technical Monitor); Shivakumar, Kunigal N.
2003-01-01
Electric ion thrusters are the preferred engines for deep space missions, because of very high specific impulse. The ion engine consists of screen and accelerator grids containing thousands of concentric very small holes. The xenon gas accelerates between the two grids, thus developing the impulse force. The dominant life-limiting mechanism in the state-of-the-art molybdenum thrusters is the xenon ion sputter erosion of the accelerator grid. Carbon/carbon composites (CCC) have shown to be have less than 1/7 the erosion rates than the molybdenum, thus for interplanetary missions CCC engines are inevitable. Early effort to develop CCC composite thrusters had a limited success because of limitations of the drilling technology and the damage caused by drilling. The proposed is an in-situ manufacturing of holes while the CCC is made. Special low CTE molds will be used along with the NC A&T s patented resin transfer molding (RTM) technology to manufacture the CCC grids. First, a manufacture process for 10-cm diameter thruster grids will be developed and verified. Quality of holes, density, CTE, tension, flexure, transverse fatigue and sputter yield properties will be measured. After establishing the acceptable quality and properties, the process will be scaled to manufacture 30-cm diameter grids. The properties of the two grid sizes are compared with each other.
Coating for prevention of titanium combustion
NASA Technical Reports Server (NTRS)
Anderson, V. G.; Funkhouser, M.; Mcdaniel, P.
1980-01-01
A limited number of coating options for titanium gas turbine engine components were explored with the objective of minimizing potential combustion initiation and propagation without adversely affecting component mechanical properties. Objectives were met by two of the coatings, ion-plated platinum plus electroplated copper plus electroplated nickel and ion vapor deposited aluminum.
Carbon-carbon grid for ion engines
NASA Technical Reports Server (NTRS)
Garner, Charles E. (Inventor)
1993-01-01
A method and apparatus of manufacturing a grid member for use in an ion discharge apparatus provides a woven carbon fiber in a matrix of carbon. The carbon fibers are orientated to provide a negatibe coefficient of thermal expansion for at least a portion of the grid member's operative range of use.
Carbon-carbon grid for ion engines
NASA Technical Reports Server (NTRS)
Garner, Charles E. (Inventor)
1995-01-01
A method and apparatus of manufacturing a grid member for use in an ion discharge apparatus provides a woven carbon fiber in a matrix of carbon. The carbon fibers are orientated to provide a negatibe coefficient of thermal expansion for at least a portion of the grid member's operative range of use.
Ion guiding in macro-size insulating capillaries: straight, tapered, and curved shapes
NASA Astrophysics Data System (ADS)
Kojima, Takao M.
2018-02-01
When keV energy ions are injected into a tilted insulating capillary, a certain fraction of the injected ions are transported through the tilt angle of the capillary. This ion guiding phenomenon is considered to be caused by a self-organizing charge distribution, where the inner wall of the capillary becomes charged by initial incoming ions. The charge distribution, which is formed, can guide following ions toward the exit of the capillary. Since the initial discovery of this effect, studies of ion guiding by insulating capillaries have been extended to various materials, and different sizes and shapes of capillaries. In recent years, some investigations of the guiding effect of macro-size curved capillaries have also been reported. In this review, relevant studies in a history of ion guiding in curved capillaries are discussed and future directions in this field are considered.
Eliminating degradation and uncovering ion-trapping dynamics in electrochromic WO3 thin films
Wen, Rui-Tao; Granqvist, Claes G.; Niklasson, Gunnar A.
2015-01-01
Amorphous WO3 thin films are of keen interest as cathodic electrodes in transmittance-modulating electrochromic devices. However, these films suffer from ion-trapping-induced degradation of optical modulation and reversibility upon extended Li+-ion exchange. Here, we demonstrate that ion-trapping-induced degradation, which is commonly believed to be irreversible, can be successfully eliminated by constant-current-driven de-trapping, i.e., WO3 films can be rejuvenated and regain their initial highly reversible electrochromic performance. Pronounced ion-trapping occurs when x exceeds ~0.65 in LixWO3 during ion insertion. We find two main kinds of Li+-ion trapping sites (intermediate and deep) in WO3, where the intermediate ones are most prevalent. Li+-ions can be completely removed from intermediate traps but are irreversibly bound in deep traps. Our results provide a general framework for developing and designing superior electrochromic materials and devices. PMID:26259104
School of Mines studying Mechanical Engineering and Computer Science, expected to graduate in 2019 lithium-ion and lithium sulfur batteries. Education B.S. Mechanical Engineering, Colorado School of Mines Gretchen Ohlhausen Photo of Gretchen Ohlhausen Gretchen Ohlhausen Undergraduate III-Mechanical
Versatile, high-sensitivity faraday cup array for ion implanters
Musket, Ronald G.; Patterson, Robert G.
2003-01-01
An improved Faraday cup array for determining the dose of ions delivered to a substrate during ion implantation and for monitoring the uniformity of the dose delivered to the substrate. The improved Faraday cup array incorporates a variable size ion beam aperture by changing only an insertable plate that defines the aperture without changing the position of the Faraday cups which are positioned for the operation of the largest ion beam aperture. The design enables the dose sensitivity range, typically 10.sup.11 -10.sup.18 ions/cm.sup.2 to be extended to below 10.sup.6 ions/cm.sup.2. The insertable plate/aperture arrangement is structurally simple and enables scaling to aperture areas between <1 cm.sup.2 and >750 cm.sup.2, and enables ultra-high vacuum (UHV) applications by incorporation of UHV-compatible materials.
Nanoscale Engineering of Heterostructured Anode Materials for Boosting Lithium-Ion Storage.
Chen, Gen; Yan, Litao; Luo, Hongmei; Guo, Shaojun
2016-09-01
Rechargeable lithium-ion batteries (LIBs), as one of the most important electrochemical energy-storage devices, currently provide the dominant power source for a range of devices, including portable electronic devices and electric vehicles, due to their high energy and power densities. The interest in exploring new electrode materials for LIBs has been drastically increasing due to the surging demands for clean energy. However, the challenging issues essential to the development of electrode materials are their low lithium capacity, poor rate ability, and low cycling stability, which strongly limit their practical applications. Recent remarkable advances in material science and nanotechnology enable rational design of heterostructured nanomaterials with optimized composition and fine nanostructure, providing new opportunities for enhancing electrochemical performance. Here, the progress as to how to design new types of heterostructured anode materials for enhancing LIBs is reviewed, in the terms of capacity, rate ability, and cycling stability: i) carbon-nanomaterials-supported heterostructured anode materials; ii) conducting-polymer-coated electrode materials; iii) inorganic transition-metal compounds with core@shell structures; and iv) combined strategies to novel heterostructures. By applying different strategies, nanoscale heterostructured anode materials with reduced size, large surfaces area, enhanced electronic conductivity, structural stability, and fast electron and ion transport, are explored for boosting LIBs in terms of high capacity, long cycling lifespan, and high rate durability. Finally, the challenges and perspectives of future materials design for high-performance LIB anodes are considered. The strategies discussed here not only provide promising electrode materials for energy storage, but also offer opportunities in being extended for making a variety of novel heterostructured nanomaterials for practical renewable energy applications. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Comparative Morphology of Mg+ and O+ Ions Made by the HIRAAS Experiment
NASA Astrophysics Data System (ADS)
Dymond, K.
2017-12-01
We present coincident observations of the spatial distribution of the Mg+ ion and O+ ions made by the High Resolution Airglow and Aurora Spectroscopy (HIRAAS) experiment that flew on the United States Air Force Advanced Research and Global Observing Satellite (ARGOS) mission during 1999-2002. The HIRAAS experiment featured two instruments that made coincident ultraviolet limb scan measurements viewing aft of the satellite. In the first year of mission operations, the Ionospheric Spectroscopy and Atmospheric Chemistry (ISAAC) instrument made observations of the Mg+ emission near 280 nm with a cadence of 100 s and altitude resolution of 5 km. The Low Resolution Airglow and Aurora Spectrograph (LORAAS) instrument made measurements of the 80-170 nm region of the Earth's airglow spectrum, including the 91.1 nm emission produced by radiative recombination of O+ and electrons, at 100 s cadence and 5 km altitude resolution. We use the recently developed Volume Emission Rate Tomography (VERT) technique to invert the UV measurements and produce the Mg+ and O+ ion distributions in the orbit plane of the satellite. We present our approach and comparisons of the distributions to each other and the International Reference Ionosphere model. Similar to previous metal ion density measurements, we see considerable variability over the globe with extended plumes of Mg+ ion density extending upward from 100 km to greater than 700 km and small compact layers. However, the O+ ion densities do not show similar structures, indicating that the Mg+ structures are likely driven by processes that act below the F-region ionosphere where O+ is a minor species. The global distribution of the Mg+ ions, which is related to the development of Sporadic-E, is of particular interest in this study.
NASA Technical Reports Server (NTRS)
Aston, G.; Wilbur, P. J.
1981-01-01
The physical processes governing ion extraction from a plasma have been examined experimentally. The screen hole plasma sheath (the transition region wherein significant ion acceleration and complete electron retardation occurs) has been defined by equipotential plots for a variety of ion accelerator system geometries and operating conditions. It was found that the screen hole plasma sheath extends over a large distance, and influences ion and electron trajectories at least 15 Debye lengths within the discharge chamber. The electron density variation within the screen hole plasma sheath satisfied a Maxwell-Boltzmann density distribution at an effective electron temperature dependent on the discharge plasma primary-to-Maxwellian electron density ratio. Plasma ion flow up to and through the sheath was predominantly one-dimensional, and the ions entered the sheath region with a modified Bohm velocity. Low values of the screen grid thickness to screen hole diameter ratio were found to give good ion focusing and high extracted ion currents because of the effect of screen webbing on ion focusing.
Reusability aspects for space transportation rocket engines: programmatic status and outlook
NASA Astrophysics Data System (ADS)
Preclik, D.; Strunz, R.; Hagemann, G.; Langel, G.
2011-09-01
Rocket propulsion systems belong to the most critical subsystems of a space launch vehicle, being illustrated in this paper by comparing different types of transportation systems. The aspect of reusability is firstly discussed for the space shuttle main engine, the only rocket engine in the world that has demonstrated multiple reuses. Initial projections are contrasted against final reusability achievements summarizing three decades of operating the space shuttle main engine. The discussion is then extended to engines employed on expendable launch vehicles with an operational life requirement typically specifying structural integrities up to 20 cycles (start-ups) and an accumulated burning time of about 6,000 s (Vulcain engine family). Today, this life potential substantially exceeds the duty cycle of an expendable engine. It is actually exploited only during the development and qualification phase of an engine when system reliability is demonstrated on ground test facilities with a reduced number of hardware sets that are subjected to an extended number of test cycles and operation time. The paper will finally evaluate the logic and effort necessary to qualify a reusable engine for a required reliability and put this result in context of possible cost savings realized from reuse operations over a time span of 25 years.
Performance of 10-kW class xenon ion thrusters
NASA Technical Reports Server (NTRS)
Patterson, Michael J.; Rawlin, Vincent K.
1988-01-01
Presented are performance data for laboratory and engineering model 30 cm-diameter ion thrusters operated with xenon propellant over a range of input power levels from approximately 2 to 20 kW. Also presented are preliminary performance results obtained from laboratory model 50 cm-diameter cusp- and divergent-field ion thrusters operating with both 30 cm- amd 50 cm-diameter ion optics up to a 20 kW input power. These data include values of discharge chamber propellant and power efficiencies, as well as values of specific impulse, thruster efficiency, thrust and power. The operation of the 30 cm- and 50 cm-diameter ion optics are also discussed.
Angiogenesis in calcium phosphate scaffolds by inorganic copper ion release.
Barralet, Jake; Gbureck, Uwe; Habibovic, Pamela; Vorndran, Elke; Gerard, Catherine; Doillon, Charles J
2009-07-01
Angiogenesis in a tissue-engineered device may be induced by incorporating growth factors (e.g., vascular endothelial growth factor [VEGF]), genetically modified cells, and=or vascular cells. It represents an important process during the formation and repair of tissue and is essential for nourishment and supply of reparative and immunological cells. Inorganic angiogenic factors, such as copper ions, are therefore of interest in the fields of regenerative medicine and tissue engineering due to their low cost, higher stability, and potentially greater safety compared with recombinant proteins or genetic engineering approaches. The purpose of this study was to compare tissue responses to 3D printed macroporous bioceramic scaffolds implanted in mice that had been loaded with either VEGF or copper sulfate. These factors were spatially localized at the end of a single macropore some 7 mm from the surface of the scaffold. Controls without angiogenic factors exhibited only poor tissue growth within the blocks; in contrast, low doses of copper sulfate led to the formation of microvessels oriented along the macropore axis. Further, wound tissue ingrowth was particularly sensitive to the quantity of copper sulfate and was enhanced at specific concentrations or in combination with VEGF. The potential to accelerate and guide angiogenesis and wound healing by copper ion release without the expense of inductive protein(s) is highly attractive in the area of tissue-engineered bone and offers significant future potential in the field of regenerative biomaterials.
Method and apparatuses for ion cyclotron spectrometry
Dahl, David A [Idaho Falls, ID; Scott, Jill R [Idaho Falls, ID; McJunkin, Timothy R [Idaho Falls, ID
2012-03-06
An ion cyclotron spectrometer may include a vacuum chamber that extends at least along a z-axis and means for producing a magnetic field within the vacuum chamber so that a magnetic field vector is generally parallel to the z-axis. The ion cyclotron spectrometer may also include means for producing a trapping electric field within the vacuum chamber. The trapping electric field may comprise a field potential that, when taken in cross-section along the z-axis, includes at least one section that is concave down and at least one section that is concave up so that ions traversing the field potential experience a net magnetron effect on a cyclotron frequency of the ions that is substantially equal to zero. Other apparatuses and a method for performing ion cyclotron spectrometry are also disclosed herein.
Method and apparatus for ion cyclotron spectrometry
Dahl, David A [Idaho Falls, ID; Scott, Jill R [Idaho Falls, ID; McJunkin, Timothy R [Idaho Falls, ID
2010-08-17
An ion cyclotron spectrometer may include a vacuum chamber that extends at least along a z-axis and means for producing a magnetic field within the vacuum chamber so that a magnetic field vector is generally parallel to the z-axis. The ion cyclotron spectrometer may also include means for producing a trapping electric field within the vacuum chamber that includes at least a first section that induces a first magnetron effect that increases a cyclotron frequency of an ion and at least a second section that induces a second magnetron effect that decreases the cyclotron frequency of an ion. The cyclotron frequency changes induced by the first and second magnetron effects substantially cancel one another so that an ion traversing the at least first and second sections will experience no net change in cyclotron frequency.
Electric propulsion system technology
NASA Technical Reports Server (NTRS)
Brophy, John R.; Garner, Charles E.; Goodfellow, Keith D.
1991-01-01
The work performed on the Ion Propulsion System Technology Task in FY90 is described. The objectives of this work fall under two broad categories. The first of these deals with issues associated with the application of xenon ion thrusters for primary propulsion of planetary spacecraft, and the second with the investigation of technologies which will facilitate the development of larger, higher power ion thrusters to support more advanced mission applications. Most of the effort was devoted to investigation of the critical issues associated with the use of ion thrusters for planetary spacecraft. These issues may be succinctly referred to as life time, system integration, and throttling. Chief among these is the engine life time. If the engines do not have sufficient life to perform the missions of interest, then the other issues become unimportant. Ion engine life time was investigated through two experimental programs: an investigation into the reduction of ion engine internal sputter erosion through the addition of small quantities of nitrogen, and a long duration cathode life test. In addition, a literature review and analysis of accelerator grid erosion were performed. The nitrogen addition tests indicated that the addition of between 0.5 and 1.0 percent of nitrogen by mass to the xenon propellant results in a reduction in the sputter erosion of discharge chamber components by a factor of between 20 and 50, with negligible reduction in thruster performance. The long duration test of a 6.35-mm dia. xenon hollow cathode is still in progress, and has accumulated more than 4,000 hours of operation at an emission current of 25 A at the time of this writing. One of the major system integration issues concerns possible interactions of the ion thruster produced charge exchange plasma with the spacecraft. A computer model originally developed to describe the behavior of mercury ion thruster charge exchange plasmas was resurrected and modified for xenon propellant. This model enables one to calculate the flow direction and local density of the charge exchange plasma, and indicates the degree to which this plasma can flow upstream of the thruster exhaust plane. A continuing effort to investigate the most desirable throttling technique for noble gas ion thrusters concentrated this year on experimentally determining the fixed flow rate throttling range of a 30-cm dia. thruster with a two-grid accelerator system. These experiments demonstrated a throttling capability which covers a 2.8 to 1 variation in input power. This throttling range is 55 percent greater than expected, and is due to better accelerator system performance at low net-to-total voltage ratios than indicated in the literature. To facilitate the development of large, higher power ion thrusters several brief studies were performed. These include the development of a technique which simulates ion thruster operation without beam extraction, the development of an optical technique to measure ion thruster grid distortion due to thermal expansion, tests of a capacitance measurement technique to quantify the accelerator system grid separation, and the development of a segmented thruster geometry which enables near term development of ion thrusters at power levels greater than 100 kW. Finally, a paper detailing the benefits of electric propulsion for the Space Exploration Initiative was written.
Li, Lei; Hong, Yu-Jian; Chen, Dong-Yang; Lin, Mei-Jin
2017-11-21
The search for high-performance electrode materials in organic rechargeable batteries remains a key challenge. Reported herein is a molecular structural modification of perylene imides, a promising class of redox-active electrode materials, for improved battery performance. The Diels-Alder extension of perylene imides at the lateral position led to the simultaneous incorporation of two electron-withdrawing carbonyl groups and extension of the π system, which is supposed to favor high specific capacity, operating voltage, and electronic conductivity. After the chiral dimerization of the extended species with 1,2-diaminocyclohexane, it was anticipated that the porosity and coulombic interactions with lithium ions would be promoted, which would be beneficial for fast reaction kinetics and long cycling life. As expected, in lithium batteries, the obtained chiral and π-extended tweezer, which features six imide groups and a porous solid-state network of 42.2 % accessible cell volume, was found to deliver a reversible capacity of 92.1 mA h g -1 at a charge/discharge rate of 1 C within an operating voltage window of 1.60-2.80 V versus Li + /Li, around 75 and 50 % of which was maintained after 100 and 300 galvanostatic cycles, respectively, much better than those of unmodified species. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Self-Assembled Films of Dendrimers and Metallophthalocyanines as FET-Based Glucose Biosensors
Vieira, Nirton C.S.; Figueiredo, Alessandra; de Queiroz, Alvaro A.A.; Zucolotto, Valtencir; Guimarães, Francisco E.G.
2011-01-01
Separative extended gate field effect transistor (SEGFET) type devices have been used as an ion sensor or biosensor as an alternative to traditional ion sensitive field effect transistors (ISFETs) due to their robustness, ease of fabrication, low cost and possibility of FET isolation from the chemical environment. The layer-by-layer technique allows the combination of different materials with suitable properties for enzyme immobilization on simple platforms such as the extended gate of SEGFET devices enabling the fabrication of biosensors. Here, glucose biosensors based on dendrimers and metallophthalocyanines (MPcs) in the form of layer-by-layer (LbL) films, assembled on indium tin oxide (ITO) as separative extended gate material, has been produced. NH3+ groups in the dendrimer allow electrostatic interactions or covalent bonds with the enzyme (glucose oxidase). Relevant parameters such as optimum pH, buffer concentration and presence of serum bovine albumin (BSA) in the immobilization process were analyzed. The relationship between the output voltage and glucose concentration shows that upon detection of a specific analyte, the sub-products of the enzymatic reaction change the pH locally, affecting the output signal of the FET transducer. In addition, dendritic layers offer a nanoporous environment, which may be permeable to H+ ions, improving the sensibility as modified electrodes for glucose biosensing. PMID:22163704
Ottosen, Lisbeth M; Christensen, Iben V; Rorig-Dalgård, Inge; Jensen, Pernille E; Hansen, Henrik K
2008-07-01
Electromigration (movement of ions in an applied electric field) is utilized for supply or extraction of ions from various porous materials within both civil and environmental engineering. In civil engineering, most research has been conducted on the removal of chlorides from concrete to hinder reinforcement corrosion while in environmental engineering remediation of heavy metal polluted soil is the issue most studied. Never the less, experiments have been conducted with utilization for several other materials and purposes within both engineering fields. Even though there are many topics of common interest in the use of electromigration for the two fields, there is no tradition for collaboration. The present paper is a review with the aim of pointing out areas of shared interest. Focus is laid on the purposes of the different processes, transport rates of various ions in different materials and on changes in the matrix itself. Desorption and dissolution of the target elements into ionic form is a key issue to most of the processes, and can be the limiting step. The removal rate is generally below 1 cm day(- 1), but it can be much less than 1 mm day(- 1) when desorption is slow and insufficient. Matrix changes occurs under the action of the applied electric field and it includes both physico-chemical and hydrological changes. Some of the solid phases is weathered and new can be formed. Increased fundamental understanding of the effects and side effects, when applying the electric field to a porous material, can lead to improvement of the known technologies and possibly to new applications.
A parametric study of the drift-tearing mode using an extended-magnetohydrodynamic model
King, Jacob R.; Kruger, S. E.
2014-10-24
The linear, collisional, constant-ψ drift-tearing mode is analyzed for different regimes of the plasma-β, ion-skin-depth parameter space with an unreduced, extended-magnetohydrodynamic model. Here, new dispersion relations are found at moderate plasma β and previous drift-tearing results are classified as applicable at small plasma β.
Space Electronic Test Engineering
NASA Technical Reports Server (NTRS)
Chambers, Rodney D.
2004-01-01
The Space Power and Propulsion Test Engineering Branch at NASA Glenn Research center has the important duty of controlling electronic test engineering services. These services include test planning and early assessment of Space projects, management and/or technical support required to safely and effectively prepare the article and facility for testing, operation of test facilities, and validation/delivery of data to customer. The Space Electronic Test Engineering Branch is assigned electronic test engineering responsibility for the GRC Space Simulation, Microgravity, Cryogenic, and Combustion Test Facilities. While working with the Space Power and Propulsion Test Engineering Branch I am working on several different assignments. My primary assignment deals with an electrical hardware unit known as Sunny Boy. Sunny Boy is a DC load Bank that is designed for solar arrays in which it is used to convert DC power form the solar arrays into AC power at 60 hertz to pump back into the electricity grid. However, there are some researchers who decided that they would like to use the Sunny Boy unit in a space simulation as a DC load bank for a space shuttle or even the International Space Station hardware. In order to do so I must create a communication link between a computer and the Sunny Boy unit so that I can preset a few of the limits (such power, set & constant voltage levels) that Sunny Boy will need to operate using the applied DC load. Apart from this assignment I am also working on a hi-tech circuit that I need to have built at a researcher s request. This is a high voltage analog to digital circuit that will be used to record data from space ion propulsion rocket booster tests. The problem that makes building this circuit so difficult is that it contains high voltage we must find a way to lower the voltage signal before the data is transferred into the computer to be read. The solution to this problem was to transport the signal using infrared light which will lower the voltage signal down low enough so that it is harmless to a computer. Along with my involvement in the Space Power and Propulsion Test Engineering Branch, I am obligated to assist all other members of the branch in their work. This will help me to strengthen and extend my knowledge of Electrical Engineering.
Federal Register 2010, 2011, 2012, 2013, 2014
2012-06-19
... System, for employees in the Scientific and Engineering career path hired into the Excepted and... Scientific and Engineering career path (classified as ``ZP''). The extended probationary period was an... period of up to three years for employees in the Scientific and Engineering career path hired into the...
Automotive Stirling engine development program: A success
NASA Technical Reports Server (NTRS)
Tabata, W. K.
1987-01-01
The original 5-yr Automotive Stirling Engine Development Program has been extended to 10 years due to reduced annual funding levels. With an estimated completion date of April 1988, the technical achievements and the prospectives of meeting the original program objectives are reviewed. Various other applications of this developed Stirling engine technology are also discussed.
Generating Alternative Engineering Designs by Integrating Desktop VR with Genetic Algorithms
ERIC Educational Resources Information Center
Chandramouli, Magesh; Bertoline, Gary; Connolly, Patrick
2009-01-01
This study proposes an innovative solution to the problem of multiobjective engineering design optimization by integrating desktop VR with genetic computing. Although, this study considers the case of construction design as an example to illustrate the framework, this method can very much be extended to other engineering design problems as well.…
Automotive Stirling engine development program - A success
NASA Technical Reports Server (NTRS)
Tabata, William K.
1987-01-01
The original 5-year Automotive Stirling Engine Development Program has been extended to 10 years due to reduced annual funding levels. With an estimated completion date of April 1988, the technical achievements and the prospectives of meeting the original program objectives are reviewed. Various other applications of this developed Stirling engine technology are also discussed.
Incorporating Critical Thinking into an Engineering Undergraduate Learning Environment
ERIC Educational Resources Information Center
Adair, Desmond; Jaeger, Martin
2016-01-01
Critical thinking extends to all aspects of professional engineering, especially in technical development, and, since the introduction of the ABET 2000 criteria, there has been an increased emphasis in engineering education on the development of critical thinking skills. What is hoped for is that the students obtain critical thinking skills to…
Human Factors Engineering. Part 2. HEDGE (Human Factors Engineering Data Guide for Evaluation)
1983-11-30
Use.Condit ions 0 7ý est Item ComoentsTask Categories EPurposes 2 ;c . INDEX TO THE INDEX MAN/ITEM TASK SHEET DETAILED DESIGN CONSIDERATION The purpose of...The use of these materials, in addition to standard Task and Design Checklists and Questionnaires, will enable you to tailor your FIFE subtest to a...specific Con item. The These materials have been prepared especially for you: I. They are intended to support test engineers not design engineers. 2
DOE Office of Scientific and Technical Information (OSTI.GOV)
Cornejo, J. M.; Colombano, M.; Doménech, J.
A special ion trap was initially built up to perform β-ν correlation experiments with radioactive ions. The trap geometry is also well suited to perform experiments with laser-cooled ions, serving for the development of a new type of Penning trap, in the framework of the project TRAPSENSOR at the University of Granada. The goal of this project is to use a single {sup 40}Ca{sup +} ion as detector for single-ion mass spectrometry. Within this project and without any modification to the initial electrode configuration, it was possible to perform Doppler cooling on {sup 40}Ca{sup +} ions, starting from large cloudsmore » and reaching single ion sensitivity. This new feature of the trap might be important also for other experiments with ions produced at radioactive ion beam facilities. In this publication, the trap and the laser system will be described, together with their performance with respect to laser cooling applied to large ion clouds down to a single ion.« less
Static seal for turbine engine
DOE Office of Scientific and Technical Information (OSTI.GOV)
Salazar, Santiago; Gisch, Andrew
2014-04-01
A seal structure for a gas turbine engine, the seal structure including first and second components located adjacent to each other and forming a barrier between high and low pressure zones. A seal cavity is defined in the first and second components, the seal cavity extending to either side of an elongated gap extending generally in a first direction between the first and second components. A seal member is positioned within the seal cavity and spans across the elongated gap. The seal member includes first and second side edges extending into each of the components in a second direction transversemore » to the first direction, and opposing longitudinal edges extending between the side edges generally parallel to the first direction. The side edges include a groove formed therein for effecting a reduction of gas flow around the seal member at the side edges.« less
Efficiency bounds for nonequilibrium heat engines
DOE Office of Scientific and Technical Information (OSTI.GOV)
Mehta, Pankaj; Polkovnikov, Anatoli, E-mail: asp@bu.edu
2013-05-15
We analyze the efficiency of thermal engines (either quantum or classical) working with a single heat reservoir like an atmosphere. The engine first gets an energy intake, which can be done in an arbitrary nonequilibrium way e.g. combustion of fuel. Then the engine performs the work and returns to the initial state. We distinguish two general classes of engines where the working body first equilibrates within itself and then performs the work (ergodic engine) or when it performs the work before equilibrating (non-ergodic engine). We show that in both cases the second law of thermodynamics limits their efficiency. For ergodicmore » engines we find a rigorous upper bound for the efficiency, which is strictly smaller than the equivalent Carnot efficiency. I.e. the Carnot efficiency can be never achieved in single reservoir heat engines. For non-ergodic engines the efficiency can be higher and can exceed the equilibrium Carnot bound. By extending the fundamental thermodynamic relation to nonequilibrium processes, we find a rigorous thermodynamic bound for the efficiency of both ergodic and non-ergodic engines and show that it is given by the relative entropy of the nonequilibrium and initial equilibrium distributions. These results suggest a new general strategy for designing more efficient engines. We illustrate our ideas by using simple examples. -- Highlights: ► Derived efficiency bounds for heat engines working with a single reservoir. ► Analyzed both ergodic and non-ergodic engines. ► Showed that non-ergodic engines can be more efficient. ► Extended fundamental thermodynamic relation to arbitrary nonequilibrium processes.« less
Plasma particle simulation of electrostatic ion thrusters
NASA Technical Reports Server (NTRS)
Peng, Xiaohang; Keefer, Dennis; Ruyten, Wilhelmus
1990-01-01
Charge exchange collisons between beam ions and neutral propellant gas can result in erosion of the accelerator grid surfaces of an ion engine. A particle in cell (PIC) is developed along with a Monte Carlo method to simulate the ion dynamics and charge exchange processes in the grid region of an ion thruster. The simulation is two-dimensional axisymmetric and uses three velocity components (2d3v) to investigate the influence of charge exchange collisions on the ion sputtering of the accelerator grid surfaces. An example calculation has been performed for an ion thruster operated on xenon propellant. The simulation shows that the greatest sputtering occurs on the downstream surface of the grid, but some sputtering can also occur on the upstream surface as well as on the interior of the grid aperture.
Green's function methods in heavy ion shielding
NASA Technical Reports Server (NTRS)
Wilson, John W.; Costen, Robert C.; Shinn, Judy L.; Badavi, Francis F.
1993-01-01
An analytic solution to the heavy ion transport in terms of Green's function is used to generate a highly efficient computer code for space applications. The efficiency of the computer code is accomplished by a nonperturbative technique extending Green's function over the solution domain. The computer code can also be applied to accelerator boundary conditions to allow code validation in laboratory experiments.
Radiochromic film diagnostics for laser-driven ion beams
NASA Astrophysics Data System (ADS)
Kaufman, J.; Margarone, Daniele; Candiano, Giacomo; Kim, I. Jong; Jeong, Tae Moon; Pšikal, Jan; Romano, F.; Cirrone, P.; Scuderi, V.; Korn, Georg
2015-05-01
Radiochromic film (RCF) based multichannel diagnostics utilizes the concept of a stack detector comprised of alternating layers of RCFs and shielding aluminium layers. An algorithm based on SRIM simulations is used to correct the accumulated dose. Among the standard information that can be obtained is the maximum ion energy and to some extend the beam energy spectrum. The main area where this detector shines though is the geometrical characterization of the beam. Whereas other detectors such as Thomson parabola spectrometer or Faraday cups detect only a fraction of the outburst cone, the RCF stack placed right behind the target absorbs the whole beam. A complete 2D and to some extend 3D imprint of the ion beam allows us to determine parameters such as divergence or beam center shift with respect to the target normal. The obvious drawback of such diagnostics is its invasive character. But considering that only a few successful shots (2-3) are needed per one kind of target to perform the analysis, the drawbacks are acceptable. In this work, we present results obtained with the RCF diagnostics using both conventional accelerators and laser-driven ion beams during 2 experimental campaigns.
Kostyukevich, Y; Kononikhin, A; Popov, I; Nikolaev, E
2017-04-01
We present the application of the extended desolvating capillaries for increasing the degree of the gas-phase hydrogen/deuterium exchange reaction at atmospheric pressure. The use of the extended capillaries results in the increase of the time that ions spend in the high pressure region, what leads to the significant improvement of the efficiency of the reaction. For the small protein ubiquitin, it was observed that for the same temperature, the number of exchanges increases with the decrease of the charge state so that the lowest charge state can exchange twice the number of hydrogen than the highest one. With the increase of the temperature, the difference decreases, and eventually, the number of exchanges equalizes for all charge states. The value of this temperature and the corresponding number of exchanges depend on the geometric parameters of the capillary. Further increase of the temperature leads to the thermal dissociation of the protein ion. The observed b/y fragments are identical to those produced by collision-induced dissociation performed in the ion trap. Copyright © 2017 John Wiley & Sons, Ltd. Copyright © 2017 John Wiley & Sons, Ltd.
NASA Astrophysics Data System (ADS)
Wang, Yujie; Zhang, Xu; Liu, Chang; Pan, Rui; Chen, Zonghai
2018-06-01
The power capability and maximum charge and discharge energy are key indicators for energy management systems, which can help the energy storage devices work in a suitable area and prevent them from over-charging and over-discharging. In this work, a model based power and energy assessment approach is proposed for the lithium-ion battery and supercapacitor hybrid system. The model framework of the lithium-ion battery and supercapacitor hybrid system is developed based on the equivalent circuit model, and the model parameters are identified by regression method. Explicit analyses of the power capability and maximum charge and discharge energy prediction with multiple constraints are elaborated. Subsequently, the extended Kalman filter is employed for on-board power capability and maximum charge and discharge energy prediction to overcome estimation error caused by system disturbance and sensor noise. The charge and discharge power capability, and the maximum charge and discharge energy are quantitatively assessed under both the dynamic stress test and the urban dynamometer driving schedule. The maximum charge and discharge energy prediction of the lithium-ion battery and supercapacitor hybrid system with different time scales are explored and discussed.
Stöhlker, T; Ma, X; Ludziejewski, T; Beyer, H F; Bosch, F; Brinzanescu, O; Dunford, R W; Eichler, J; Hagmann, S; Ichihara, A; Kozhuharov, C; Krämer, A; Liesen, D; Mokler, P H; Stachura, Z; Swiat, P; Warczak, A
2001-02-05
Radiative electron capture, the time-reversed photoionization process occurring in ion-atom collisions, provides presently the only access to photoionization studies for very highly charged ions. By applying the deceleration mode of the ESR storage ring, we studied this process in low-energy collisions of bare uranium ions with low- Z target atoms. This technique allows us to extend the current information about photoionization to much lower energies than those accessible for neutral heavy elements in the direct reaction channel. The results prove that for high- Z systems, higher-order multipole contributions and magnetic corrections persist even at energies close to the threshold.
NASA Astrophysics Data System (ADS)
Brikner, Natalya; Lozano, Paulo C.
2012-11-01
Ionic liquid ion sources produce molecular ions from micro-tip emitters wetted with room-temperature molten salts. When a single ion polarity is extracted, counterions accumulate and generate electrochemical reactions that limit the source lifetime. The dynamics of double layer formation are reviewed and distal electrode contacts are introduced to resolve detrimental electrochemical decomposition effects at the micro-tip apex. By having the emitter follow the ionic liquid potential, operation can be achieved for an extended period of time with no apparent degradation of the material, indicating that electrochemistry can be curtailed and isolated to the upstream distal electrode.
Error analysis and prevention of cosmic ion-induced soft errors in static CMOS RAMs
NASA Astrophysics Data System (ADS)
Diehl, S. E.; Ochoa, A., Jr.; Dressendorfer, P. V.; Koga, P.; Kolasinski, W. A.
1982-12-01
Cosmic ray interactions with memory cells are known to cause temporary, random, bit errors in some designs. The sensitivity of polysilicon gate CMOS static RAM designs to logic upset by impinging ions has been studied using computer simulations and experimental heavy ion bombardment. Results of the simulations are confirmed by experimental upset cross-section data. Analytical models have been extended to determine and evaluate design modifications which reduce memory cell sensitivity to cosmic ions. A simple design modification, the addition of decoupling resistance in the feedback path, is shown to produce static RAMs immune to cosmic ray-induced bit errors.
Diffusion engineering of ions and charge carriers for stable efficient perovskite solar cells
NASA Astrophysics Data System (ADS)
Bi, Enbing; Chen, Han; Xie, Fengxian; Wu, Yongzhen; Chen, Wei; Su, Yanjie; Islam, Ashraful; Grätzel, Michael; Yang, Xudong; Han, Liyuan
2017-06-01
Long-term stability is crucial for the future application of perovskite solar cells, a promising low-cost photovoltaic technology that has rapidly advanced in the recent years. Here, we designed a nanostructured carbon layer to suppress the diffusion of ions/molecules within perovskite solar cells, an important degradation process in the device. Furthermore, this nanocarbon layer benefited the diffusion of electron charge carriers to enable a high-energy conversion efficiency. Finally, the efficiency on a perovskite solar cell with an aperture area of 1.02 cm2, after a thermal aging test at 85 °C for over 500 h, or light soaking for 1,000 h, was stable of over 15% during the entire test. The present diffusion engineering of ions/molecules and photo generated charges paves a way to realizing long-term stable and highly efficient perovskite solar cells.
Status and Perspectives of Ion Track Electronics for Advanced Biosensing
NASA Astrophysics Data System (ADS)
Fink, D.; Muñoz, H. Gerardo; Alfonta, L.; Mandabi, Y.; Dias, J. F.; de Souza, C. T.; Bacakova, L. E.; Vacík, J.; Hnatowicz, V.; Kiv, A. E.; Fuks, D.; Papaleo, R. M.
New multifunctional ion irradiation-based three-dimensional electronic structures are developed for biotechnological applications, specifically for sensing of biomaterials, bacteria and mammalian cells. This is accomplished by combined micrometric surface and nanometric bulk microstructuring of insulators (specifically of polymer foils and SiO2/Si hybride structures) by adequate ion beams. Our main goal is the production of a cheap small universal generic working platform with multifunctional properties for biomedical analysis. Surface engineering of this platform enables cell bonding and its bulk engineering enables the extraction of cell secrets, for the sake of intercepting and analyzing the biomolecules used in cell communication. The exact knowledge of the spectrum of these cell-secreted signalling molecules should enable one to identify unambiguously the cell type. This knowledge will help developing strategies for preventive quorum sensing of bacteria, with the aim of fighting bacterial infections in an ecologically secure way.
Hollow Cathode Studies for the Next Generation Ion Engines in JAXA
NASA Astrophysics Data System (ADS)
Ohkawa, Yasushi; Hayakawa, Yukio; Yoshida, Hideki; Miyazaki, Katsuhiro; Kitamura, Shoji; Kajiwara, Kenichi
The current status of experimental studies of hollow cathodes for the next-generation ion engines in the Aerospace Research and Development Directorate, JAXA is described. One of the topics on the hollow cathode studies is a life test of a discharge cathode. The keeper disk, orifice plate, and cathode tube of this discharge cathode are made of "high density graphite," which possesses much higher tolerance to ion impingement compared with conventional metal materials. The life test had started in March 2006 and the cumulative operation time reached 15,600 hours in April 2008. No severe degradation has been found both in the operation voltages and electrodes so far, and the test is favorably in progress. In addition to the life test of the discharge cathode, some experiments for design optimization of neutralizer cathodes have been performed. A life test of the neutralizer cathode is being started in June 2008.
NASA Astrophysics Data System (ADS)
Swiecicki, I.; Ulysse, C.; Wolf, T.; Bernard, R.; Bergeal, N.; Briatico, J.; Faini, G.; Lesueur, J.; Villegas, Javier E.
2012-06-01
We have developed a masked ion irradiation technique to engineer the energy landscape for vortices in oxide superconductors. This approach associates the possibility to design the landscape geometry at the nanoscale with the unique capability to adjust the depth of the energy wells for vortices. This enabled us to unveil the key role of vortex channeling in modulating the amplitude of the field matching effects with the artificial energy landscape, and to make the latter govern flux dynamics over an unusually wide range of temperatures and applied fields for high-temperature superconducting films.
The effects of gas mixtures on ion engine erosion and performance
NASA Technical Reports Server (NTRS)
Garner, Charles E.; Brophy, John R.; Aston, Graeme
1987-01-01
Erosion measurements were performed on a modified J-series 30 cm ion engine operating on xenon propellant. Erosion data was obtained by measuring the trench depth etched into masked polished metal samples for test durations of up to 24 hours. The data indicates that erosion is greatest at the cathode side of the baffle, with tantalum being the material with the least erosion of all materials tested. There is a clear indication of a significant reduction in erosion of all materials tested when nitrogen is added to the propellant. The technique used in these experiments requires test samples which are extremely smooth and flat.
Multiple output power supply circuit for an ion engine with shared upper inverter
NASA Technical Reports Server (NTRS)
Cardwell, Jr., Gilbert I. (Inventor); Phelps, Thomas K. (Inventor)
2001-01-01
A power supply circuit for an ion engine suitable for a spacecraft is coupled to a bus having a bus input and a bus return. The power supply circuit has a first primary winding of a first transformer. An upper inverter circuit is coupled to the bus input and the first primary winding. The power supply circuit further includes a first lower inverter circuit coupled to the bus return and the first primary winding. The second primary winding of a second transformer is coupled to the upper inverter circuit. A second lower inverter circuit is coupled to the bus return and the second primary winding.
MEMS Micropropulsion Activities at JPL
NASA Technical Reports Server (NTRS)
Mueller, Juergen; Chakraborty, Indrani; Vargo, Stephen; Bame, David; Marrese, Colleen; Tang, William C.
1999-01-01
A status of MEMS-based micropropulsion activities conducted at JPL will be given. These activities include work conducted on the so called Vaporizing Liquid Micro-Thruster (VLM) which recently underwent proof-of-concept testing, demonstrating the ability to vaporize water propellant at 2 W and 2 V. Micro-ion engine technologies, such m field emitter arrays and micro-grids are being studied. Focus in the field emitter area is on arrays able to survive in thruster plumes and micro-ion engine plasmas to serve as neutralizers aW engine cathodes. Integrated, batch-fabricated Ion repeller grid structures are being studied as well as different emitter tip materials are being investigated to meet these goals. A micro-isolation valve is being studied to isolate microspacecraft feed system during long interplanetary cruises, avoiding leakage and prolonging lifetime and reliability of such systems. This concept relies on the melting of a thin silicon barrier. Burst pressure values as high as 2,900 psig were obtained for these valves and power requirements to melt barriers ranging between 10 - 50 microns in thickness, as determined through thermal finite element calculations, varied between 10 - 30 W to be applied over a duration of merely 0.5 ms.
Space Civil Engineering option - A progress report
NASA Technical Reports Server (NTRS)
Criswell, Marvin E.; Sadeh, Willy Z.
1992-01-01
Space Civil Engineering is an emerging engineering discipline that focuses on extending and expanding Civil Engineering to the development, operation, and maintenance of infrastructures on celestial bodies. Space Civil Engineering is presently being developed as a new discipline within the Department of Civil Engineering at Colorado State University and with support of the NASA Space Grant College Program. Academic programs geared toward creating Space Civil Engineering Options at both undergraduate and graduate levels are being formulated. Basic ideas and concepts and the current status of the curriculum in the Space Civil Engineering Option primarily at the undergraduate level are presented.
The 30-centimeter ion thrust subsystem design manual
NASA Technical Reports Server (NTRS)
1979-01-01
The principal characteristics of the 30-centimeter ion propulsion thrust subsystem technology that was developed to satisfy the propulsion needs of future planetary and early orbital missions are described. Functional requirements and descriptions, interface and performance requirements, and physical characteristics of the hardware are described at the thrust subsystem, BIMOD engine system, and component level.
Characterization of 8-cm engineering model thruster
NASA Technical Reports Server (NTRS)
Williamson, W. S.
1984-01-01
Development of 8 cm ion thruster technology which was conducted in support of the Ion Auxiliary Propulsion System (IAPS) flight contract (Contract NAS3-21055) is discussed. The work included characterization of thruster performance, stability, and control; a study of the effects of cathode aging; environmental qualification testing; and cyclic lifetesting of especially critical thruster components.
Infrared Optical Absorption in Low-spin Fe2+-doped SrTiO3
DOE Office of Scientific and Technical Information (OSTI.GOV)
Comes, Ryan B.; Kaspar, Tiffany C.; Heald, Steve M.
2016-01-06
Band gap engineering in SrTiO3 and related titanate perovskites has long been explored due to the intriguing properties of the materials for photocatalysis and photovoltaic applications. A popular approach in the materials chemistry community is to substitutionally dope aliovalent transition metal ions onto the B site in the lattice to alter the valence band. However, in such a scheme there is limited control over the dopant valence, and compensating defects often form. Here we demonstrate a novel technique to controllably synthesize Fe2+- and Fe3+-doped SrTiO3 thin films without formation of compensating defects by co-doping with La3+ ions on the Amore » site. We stabilize Fe2+-doped films by doping with two La ions for every Fe dopant, and find that the Fe ions exhibit a low-spin electronic configuration, producing optical transitions in the near infrared regime and degenerate doping. The novel electronic states observed here offer a new avenue for band gap engineering in perovskites for photocatalytic and photovoltaic applications.« less
Wittkopp, Felix; Peeck, Lars; Hafner, Mathias; Frech, Christian
2018-04-13
Process development and characterization based on mathematic modeling provides several advantages and has been applied more frequently over the last few years. In this work, a Donnan equilibrium ion exchange (DIX) model is applied for modelling and simulation of ion exchange chromatography of a monoclonal antibody in linear chromatography. Four different cation exchange resin prototypes consisting of weak, strong and mixed ligands are characterized using pH and salt gradient elution experiments applying the extended DIX model. The modelling results are compared with the results using a classic stoichiometric displacement model. The Donnan equilibrium model is able to describe all four prototype resins while the stoichiometric displacement model fails for the weak and mixed weak/strong ligands. Finally, in silico chromatogram simulations of pH and pH/salt dual gradients are performed to verify the results and to show the consistency of the developed model. Copyright © 2018 Elsevier B.V. All rights reserved.
Failure mechanisms of single-crystal silicon electrodes in lithium-ion batteries
Shi, Feifei; Song, Zhichao; Ross, Philip N.; Somorjai, Gabor A.; Ritchie, Robert O.; Komvopoulos, Kyriakos
2016-01-01
Long-term durability is a major obstacle limiting the widespread use of lithium-ion batteries in heavy-duty applications and others demanding extended lifetime. As one of the root causes of the degradation of battery performance, the electrode failure mechanisms are still unknown. In this paper, we reveal the fundamental fracture mechanisms of single-crystal silicon electrodes over extended lithiation/delithiation cycles, using electrochemical testing, microstructure characterization, fracture mechanics and finite element analysis. Anisotropic lithium invasion causes crack initiation perpendicular to the electrode surface, followed by growth through the electrode thickness. The low fracture energy of the lithiated/unlithiated silicon interface provides a weak microstructural path for crack deflection, accounting for the crack patterns and delamination observed after repeated cycling. On the basis of this physical understanding, we demonstrate how electrolyte additives can heal electrode cracks and provide strategies to enhance the fracture resistance in future lithium-ion batteries from surface chemical, electrochemical and material science perspectives. PMID:27297565
Failure mechanisms of single-crystal silicon electrodes in lithium-ion batteries
Shi, Feifei; Song, Zhichao; Ross, Philip N.; ...
2016-06-14
Long-term durability is a major obstacle limiting the widespread use of lithium-ion batteries in heavy-duty applications and others demanding extended lifetime. As one of the root causes of the degradation of battery performance, the electrode failure mechanisms are still unknown. In this paper, we reveal the fundamental fracture mechanisms of single-crystal silicon electrodes over extended lithiation/delithiation cycles, using electrochemical testing, microstructure characterization, fracture mechanics and finite element analysis. Anisotropic lithium invasion causes crack initiation perpendicular to the electrode surface, followed by growth through the electrode thickness. The low fracture energy of the lithiated/unlithiated silicon interface provides a weak microstructural pathmore » for crack deflection, accounting for the crack patterns and delamination observed after repeated cycling. On the basis of this physical understanding, we demonstrate how electrolyte additives can heal electrode cracks and provide strategies to enhance the fracture resistance in future lithium-ion batteries from surface chemical, electrochemical and material science perspectives.« less
Failure mechanisms of single-crystal silicon electrodes in lithium-ion batteries
NASA Astrophysics Data System (ADS)
Shi, Feifei; Song, Zhichao; Ross, Philip N.; Somorjai, Gabor A.; Ritchie, Robert O.; Komvopoulos, Kyriakos
2016-06-01
Long-term durability is a major obstacle limiting the widespread use of lithium-ion batteries in heavy-duty applications and others demanding extended lifetime. As one of the root causes of the degradation of battery performance, the electrode failure mechanisms are still unknown. In this paper, we reveal the fundamental fracture mechanisms of single-crystal silicon electrodes over extended lithiation/delithiation cycles, using electrochemical testing, microstructure characterization, fracture mechanics and finite element analysis. Anisotropic lithium invasion causes crack initiation perpendicular to the electrode surface, followed by growth through the electrode thickness. The low fracture energy of the lithiated/unlithiated silicon interface provides a weak microstructural path for crack deflection, accounting for the crack patterns and delamination observed after repeated cycling. On the basis of this physical understanding, we demonstrate how electrolyte additives can heal electrode cracks and provide strategies to enhance the fracture resistance in future lithium-ion batteries from surface chemical, electrochemical and material science perspectives.
Towards full-Braginskii implicit extended MHD
NASA Astrophysics Data System (ADS)
Chacon, Luis
2009-05-01
Recently, viable algorithms have been proposed for the scalable, fully-implicit temporal integration of 3D resistive MHD and cold-ion extended MHD models. While significant, these achievements must be tempered by the fact that such models lack predictive capabilities in regimes of interest for magnetic fusion. Short of including kinetic closures, a natural evolution path towards predictability starts by considering additional terms as described in Braginskii's fluid closures in the collisional regime. Here, we focus on the inclusion of two fundamental elements of relevance for fusion plasmas: anisotropic parallel electron transport, and warm-ion physics (i.e., ion finite Larmor radius effects, included via gyroviscosity). Both these elements introduce significant numerical difficulties, due to the strong anisotropy in the former, and the presence of dispersive waves in the latter. In this presentation, we will discuss progress in our fully implicit algorithmic formulation towards the inclusion of both these elements. L. Chac'on, Phys. Plasmas, 15, 056103 (2008) L. Chac'on, J. Physics: Conf. Series, 125, 012041 (2008)
Nonperturbative methods in HZE ion transport
NASA Technical Reports Server (NTRS)
Wilson, John W.; Badavi, Francis F.; Costen, Robert C.; Shinn, Judy L.
1993-01-01
A nonperturbative analytic solution of the high charge and energy (HZE) Green's function is used to implement a computer code for laboratory ion beam transport. The code is established to operate on the Langley Research Center nuclear fragmentation model used in engineering applications. Computational procedures are established to generate linear energy transfer (LET) distributions for a specified ion beam and target for comparison with experimental measurements. The code is highly efficient and compares well with the perturbation approximations.
Ionosphere of venus: first observations of the effects of dynamics on the dayside ion composition.
Taylor, H A; Brinton, H C; Bauer, S J; Hartle, R E; Cloutier, P A; Michel, F C; Daniell, R E; Donahue, T M; Maehl, R C
1979-02-23
Bennett radio-frequency ion mass spectrometers have returned the first in situ measurements of the Venus dayside ion composition, including evidence of pronounced structural variability resulting from a dynamic interaction with the solar wind. The ionospheric envelope, dominated above 200 kilometers by O(+), responds dramatically to variations in the solar wind pressure, Which is observed to compress the thermal ion distributions from heights as great as 1800 kilometers inward to 280 kilometers. At the thermal ion boundary, or ionopause, the ambient ions are swept away by the solar wind, such that a zone of accelerated suprathermnal plasma is encountered. At higher altitudes, extending outward on some orbits for thousands of kilometers to the bows shock, energetic ion currents are detected, apparently originating from the shocked solar wind plasma. Within the ionosphere, observations of pass-to-pass differences in the ion scale heights are indicative of the effects of ion convection stimlulated by the solar wind interaction.
Morphology of Block Copolymer Electrolytes: A Numerical Self-Consistent Field Theory Study
NASA Astrophysics Data System (ADS)
Hou, Kevin; Qin, Jian
Engineering the morphology of ion-containing block copolymers is imperative for the optimization of their charge-transport and mechanical properties. Existing experiments have demonstrated that the addition of ions has a dramatic effect on the morphology and thermodynamic behavior of these structured electrolytes. We have developed an efficient, symmetry-adapted algorithm to calculate the ionic interactions in the SCFT for ion-containing polymers. We present the results of a numerical SCFT study examining how dielectric heterogeneity, ion concentration, and ion solvation affect morphology, domain spacing, ion distribution, and polymer density profiles. Particular attention is given to the detailed morphological analysis of the bicontinuous gyroidal phase, as well as the relevance of the aforementioned results to ionic conductivity.
International Space Station Lithium-Ion Main Battery Thermal Runaway Propagation Test
NASA Technical Reports Server (NTRS)
Dalton, Penni J.; North, Tim
2017-01-01
In 2010, the ISS Program began the development of Lithium-Ion (Li-Ion) batteries to replace the aging Ni-H2 batteries on the primary Electric Power System (EPS). After the Boeing 787 Li-Ion battery fires, the NASA Engineering and Safety Center (NESC) Power Technical Discipline Team was tasked by ISS to investigate the possibility of Thermal Runaway Propagation (TRP) in all Li-Ion batteries used on the ISS. As part of that investigation, NESC funded a TRP test of an ISS EPS non-flight Li-Ion battery. The test was performed at NASA White Sands Test Facility in October 2016. This paper will discuss the work leading up to the test, the design of the test article, and the test results.
Transfer of Kv3.1 voltage sensor features to the isolated Ci-VSP voltage-sensing domain.
Mishina, Yukiko; Mutoh, Hiroki; Knöpfel, Thomas
2012-08-22
Membrane proteins that respond to changes in transmembrane voltage are critical in regulating the function of living cells. The voltage-sensing domains (VSDs) of voltage-gated ion channels are extensively studied to elucidate voltage-sensing mechanisms, and yet many aspects of their structure-function relationship remain elusive. Here, we transplanted homologous amino acid motifs from the tetrameric voltage-activated potassium channel Kv3.1 to the monomeric VSD of Ciona intestinalis voltage-sensitive phosphatase (Ci-VSP) to explore which portions of Kv3.1 subunits depend on the tetrameric structure of Kv channels and which properties of Kv3.1 can be transferred to the monomeric Ci-VSP scaffold. By attaching fluorescent proteins to these chimeric VSDs, we obtained an optical readout to establish membrane trafficking and kinetics of voltage-dependent structural rearrangements. We found that motifs extending from 10 to roughly 100 amino acids can be readily transplanted from Kv3.1 into Ci-VSP to form engineered VSDs that efficiently incorporate into the plasma membrane and sense voltage. Some of the functional features of these engineered VSDs are reminiscent of Kv3.1 channels, indicating that these properties do not require interactions between Kv subunits or between the voltage sensing and the pore domains of Kv channels. Copyright © 2012 Biophysical Society. Published by Elsevier Inc. All rights reserved.
DOE Office of Scientific and Technical Information (OSTI.GOV)
Oliviero, E.; David, M. L.; Beaufort, M. F.
The crystalline-to-amorphous transformation induced by lithium ion implantation at low temperature has been investigated. The resulting damage structure and its thermal evolution have been studied by a combination of Rutherford backscattering spectroscopy channelling (RBS/C) and cross sectional transmission electron microscopy (XTEM). Lithium low-fluence implantation at liquid nitrogen temperature is shown to produce a three layers structure: an amorphous layer surrounded by two highly damaged layers. A thermal treatment at 400 Degree-Sign C leads to the formation of a sharp amorphous/crystalline interfacial transition and defect annihilation of the front heavily damaged layer. After 600 Degree-Sign C annealing, complete recrystallization takes placemore » and no extended defects are left. Anomalous recrystallization rate is observed with different motion velocities of the a/c interfaces and is ascribed to lithium acting as a surfactant. Moreover, the sharp buried amorphous layer is shown to be an efficient sink for interstitials impeding interstitial supersaturation and {l_brace}311{r_brace} defect formation in case of subsequent neon implantation. This study shows that lithium implantation at liquid nitrogen temperature can be suitable to form a sharp buried amorphous layer with a well-defined crystalline front layer, thus having potential applications for defects engineering in the improvement of post-implantation layers quality and for shallow junction formation.« less
Report on the workshop on Ion Implantation and Ion Beam Assisted Deposition
NASA Astrophysics Data System (ADS)
Dearnaley, G.
1992-03-01
This workshop was organized by the Corpus Christi Army Depot (CCAD), the major helicopter repair base within AVSCOM. Previous meetings had revealed a strong interest throughout DoD in ion beam technology as a means of extending the service life of military systems by reducing wear, corrosion, fatigue, etc. The workshop opened with an account by Dr. Bruce Sartwell of the successful application of ion implantation to bearings and gears at NRL, and the checkered history of the MANTECH Project at Spire Corporation. Dr. James Hirvonen (AMTL) continued with a summary of successful applications to reduce wear in biomedical components, and he also described the processes of ion beam-assisted deposition (IBAD) for a variety of protective coatings, including diamond-like carbon (DLC).
Quantum information processing between different atomic ions
NASA Astrophysics Data System (ADS)
Zhang, Xiang; Zheng, Bo; Zhang, Junhua; Um, Mark; An, Shuoming; Zhao, Tianji; Duan, Luming; Kim, Kihwan
2012-06-01
There is increasing interest in utilizing and combining the advantages of different quantum systems. Here, we discuss the experimental generation of entanglement between the quantum states of different atomic ions through the Coulomb interaction at the same linear radio-frequency trap. This scheme would be extended to implement the teleportation of quantum information from one kind of atom to the other. Moreover, the hybrid system of trapped ions is expected to play an essential role in the realization of a large quantum system, where a quantum state of one species is used for quantum operation and that of the other is for the cooling and stabilization of the whole ion chain. Finally, we will report the experimental progress on building the hybrid trapped ion system.
NASA Astrophysics Data System (ADS)
Babaev, A. A.; Pivovarov, Yu L.
2010-04-01
Resonant coherent excitation (RCE) of relativistic hydrogen-like ions is investigated by computer simulations methods. The suggested theoretical model is applied to the simulations of recent experiments on RCE of 390 MeV/u Ar17+ ions under (220) planar channeling in a Si crystal performed by T.Azuma et al at HIMAC (Tokyo). Theoretical results are in a good agreement with these experimental data and clearly show the appearance of the doublet structure of RCE peaks. The simulations are also extended to greater ion energies in order to predict the new RCE features at the future accelerator facility FAIR OSI and as an example, RCE of II GeV/u U91+ ions is considered in detail.
Environmental Testing of the NEXT PM1 Ion Engine
NASA Technical Reports Server (NTRS)
Synder, John S.; Anderson, John R.; VanNoord, Jonathan L.; Soulas, George C.
2008-01-01
The NEXT propulsion system is an advanced ion propulsion system presently under development that is oriented towards robotic exploration of the solar system using solar electric power. The Prototype Model engine PM1 was subjected to qualification-level environmental testing to demonstrate compatibility with environments representative of anticipated mission requirements. Random vibration testing, conducted with the thruster mated to the breadboard gimbal, was executed at 10.0 Grms for 2 minutes in each of three axes. Thermal-vacuum testing included a deep cold soak of the engine to temperatures of -168 C and thermal cycling from -120 to 203 C. Although the testing was largely successful, several issues were identified including the fragmentation of potting cement on the discharge and neutralizer cathode heater terminations during vibration which led to abbreviated thermal testing, and generation of particulate contamination from manufacturing processes and engine materials. Thruster performance was nominal throughout the test program, with minor variations in some engine operating parameters likely caused by facility effects. In general, the NEXT PM1 engine and the breadboard gimbal were found to be well-designed against environmental requirements based on the results reported herein. After resolution of the findings from this test program the hardware environmental qualification program can proceed with confidence.
Apparatus and method of determining molecular weight of large molecules
Fuerstenau, S.; Benner, W.H.; Madden, N.M.; Searles, W.
1998-06-23
A mass spectrometer determines the mass of multiply charged high molecular weight molecules. This spectrometer utilizes an ion detector which is capable of simultaneously measuring the charge z and transit time of a single ion as it passes through the detector. From this transit time, the velocity of the single ion may then be derived, thus providing the mass-to-charge ratio m/z for a single ion which has been accelerated through a known potential. Given z and m/z, the mass m of the single ion can then be calculated. Electrospray ions with masses in excess of 1 MDa and charge numbers greater than 425 e{sup {minus}} are readily detected. The on-axis single ion detection configuration enables a duty cycle of nearly 100% and extends the practical application of electrospray mass spectrometry to the analysis of very large molecules with relatively inexpensive instrumentation. 14 figs.
Apparatus and method of determining molecular weight of large molecules
Fuerstenau, Stephen; Benner, W. Henry; Madden, Norman; Searles, William
1998-01-01
A mass spectrometer determines the mass of multiply charged high molecular weight molecules. This spectrometer utilizes an ion detector which is capable of simultaneously measuring the charge z and transit time of a single ion as it passes through the detector. From this transit time, the velocity of the single ion may then be derived, thus providing the mass-to-charge ratio m/z for a single ion which has been accelerated through a known potential. Given z and m/z, the mass m of the single ion can then be calculated. Electrospray ions with masses in excess of 1 MDa and charge numbers greater than 425 e.sup.- are readily detected. The on-axis single ion detection configuration enables a duty cycle of nearly 100% and extends the practical application of electrospray mass spectrometry to the analysis of very large molecules with relatively inexpensive instrumentation.
NASA Astrophysics Data System (ADS)
Takahashi, H.; Nagaoka, K.; Murakami, S.; Osakabe, M.; Nakano, H.; Ida, K.; Tsujimura, T. I.; Kubo, S.; Kobayashi, T.; Tanaka, K.; Seki, R.; Takeiri, Y.; Yokoyama, M.; Maeta, S.; Nakata, M.; Yoshinuma, M.; Yamada, I.; Yasuhara, R.; Ido, T.; Shimizu, A.; Tsuchiya, H.; Tokuzawa, T.; Goto, M.; Oishi, T.; Morita, S.; Suzuki, C.; Emoto, M.; Tsumori, K.; Ikeda, K.; Kisaki, M.; Shimozuma, T.; Yoshimura, Y.; Igami, H.; Makino, R.; Seki, T.; Kasahara, H.; Saito, K.; Kamio, S.; Nagasaki, K.; Mutoh, T.; Kaneko, O.; Morisaki, T.; the LHD Experiment Group
2017-08-01
A simultaneous high ion temperature (T i) and high electron temperature (T e) regime was successfully extended due to an optimized heating scenario in the LHD. Such high-temperature plasmas were realized by the simultaneous formation of an electron internal transport barrier (ITB) and an ion ITB by the combination of high power NBI and ECRH. Although the ion thermal confinement was degraded in the plasma core with an increase of T e/T i by the on-axis ECRH, it was found that the ion thermal confinement was improved at the plasma edge. The normalized ion thermal diffusivity {χ\\text{i}}/T\\text{i}1.5 at the plasma edge was reduced by 70%. The improvement of the ion thermal confinement at the edge led to an increase in T i in the entire plasma region, even though the core transport was degraded.
Single ion as a shot-noise-limited magnetic-field-gradient probe
DOE Office of Scientific and Technical Information (OSTI.GOV)
Walther, A.; Poschinger, U.; Ziesel, F.
2011-06-15
It is expected that ion-trap quantum computing can be made scalable through protocols that make use of transport of ion qubits between subregions within the ion trap. In this scenario, any magnetic field inhomogeneity the ion experiences during the transport may lead to dephasing and loss of fidelity. Here we demonstrate how to measure, and compensate for, magnetic field gradients inside a segmented ion trap, by transporting a single ion over variable distances. We attain a relative magnetic field sensitivity of {Delta}B/B{sub 0{approx}}5x10{sup -7} over a test distance of 140 {mu}m, which can be extended to the mm range, stillmore » with sub-{mu}m resolution. A fast experimental sequence is presented, facilitating its use as a magnetic-field-gradient calibration routine, and it is demonstrated that the main limitation is the quantum shot noise.« less
Development of an intelligent diagnostic system for reusable rocket engine control
NASA Technical Reports Server (NTRS)
Anex, R. P.; Russell, J. R.; Guo, T.-H.
1991-01-01
A description of an intelligent diagnostic system for the Space Shuttle Main Engines (SSME) is presented. This system is suitable for incorporation in an intelligent controller which implements accommodating closed-loop control to extend engine life and maximize available performance. The diagnostic system architecture is a modular, hierarchical, blackboard system which is particularly well suited for real-time implementation of a system which must be repeatedly updated and extended. The diagnostic problem is formulated as a hierarchical classification problem in which the failure hypotheses are represented in terms of predefined data patterns. The diagnostic expert system incorporates techniques for priority-based diagnostics, the combination of analytical and heuristic knowledge for diagnosis, integration of different AI systems, and the implementation of hierarchical distributed systems. A prototype reusable rocket engine diagnostic system (ReREDS) has been implemented. The prototype user interface and diagnostic performance using SSME test data are described.
Structural cooling fluid tube for supporting a turbine component and supplying cooling fluid
DOE Office of Scientific and Technical Information (OSTI.GOV)
Charron, Richard; Pierce, Daniel
2015-02-24
A shaft cover support for a gas turbine engine is disclosed. The shaft cover support not only provides enhanced support to a shaft cover of the gas turbine engine, but also includes a cooling fluid chamber for passing fluids from a rotor air cooling supply conduit to an inner ring cooling manifold. As such, the shaft cover support accomplishes in a single component what was only partially accomplished in two components in conventional configurations. The shaft cover support may also provide additional stiffness and reduce interference of the flow from the compressor. In addition, the shaft cover support accommodates amore » transition section extending between compressor and turbine sections of the engine. The shaft cover support has a radially extending region that is offset from the inlet and outlet that enables the shaft cover support to surround the transition, thereby reducing the overall length of this section of the engine.« less
Kassler, Alexander; Pittenauer, Ernst; Doerr, Nicole; Allmaier, Guenter
2014-01-15
For the qualification and quantification of antioxidants (aromatic amines and sterically hindered phenols), most of them applied as lubricant additives, two ultrahigh-performance liquid chromatography (UHPLC) electrospray ionization mass spectrometric methods applying the positive and negative ion mode have been developed for lubricant design and engineering thus allowing e.g. the study of the degradation of lubricants. Based on the different chemical properties of the two groups of antioxidants, two methods offering a fast separation (10 min) without prior derivatization were developed. In order to reach these requirements, UHPLC was coupled with an LTQ Orbitrap hybrid tandem mass spectrometer with positive and negative ion electrospray ionization for simultaneous detection of spectra from UHPLC-high-resolution (HR)-MS (full scan mode) and UHPLC-low-resolution linear ion trap MS(2) (LITMS(2)), which we term UHPLC/HRMS-LITMS(2). All 20 analytes investigated could be qualified by an UHPLC/HRMS-LITMS(2) approach consisting of simultaneous UHPLC/HRMS (elemental composition) and UHPLC/LITMS(2) (diagnostic product ions) according to EC guidelines. Quantification was based on an UHPLC/LITMS(2) approach due to increased sensitivity and selectivity compared to UHPLC/HRMS. Absolute quantification was only feasible for seven analytes with well-specified purity of references whereas relative quantification was obtainable for another nine antioxidants. All of them showed good standard deviation and repeatability. The combined methods allow qualitative and quantitative determination of a wide variety of different antioxidants including aminic/phenolic compounds applied in lubricant engineering. These data show that the developed methods will be versatile tools for further research on identification and characterization of the thermo-oxidative degradation products of antioxidants in lubricants. Copyright © 2013 John Wiley & Sons, Ltd.
Sea-level evaluation of digitally implemented turbojet engine control functions
NASA Technical Reports Server (NTRS)
Arpasi, D. J.; Cwynar, D. S.; Wallhagen, R. E.
1972-01-01
The standard hydromechanical control system of a turbojet engine was replaced with a digital control system that implemented the same control laws. A detailed discussion of the digital control system in use with the engine is presented. The engine was operated in a sea-level test stand. The effects of control update interval are defined, and a method for extending this interval by using digital compensation is discussed.
Device for installing rocket engines
NASA Technical Reports Server (NTRS)
George, T. R., Jr. (Inventor)
1976-01-01
A device for installing rocket engines is reported that is supported at a cant relative to vertical by an axially extensible, tiltable pedestal. A lifting platform supports the rocket engine at its thrust chamber exit, including a mount having a concentric base characterized by a concave bearing surface, a plurality of uniformly spaced legs extended radially from the base, and an annular receiver coaxially aligned with the base and affixed to the distal ends of said legs for receiving the thrust chamber exit. The lifting platform rests on a seat concentrically related to the pedestal and affixed to an extended end portion thereof having a convex bearing surface mated in sliding engagement with the concave bearing surface of the annular base for accommodating a rocking motion of the platform.
Turbine nozzle attachment system
Norton, Paul F.; Shaffer, James E.
1995-01-01
A nozzle guide vane assembly having a preestablished rate of thermal expansion is positioned in a gas turbine engine and being attached to conventional metallic components. The nozzle guide vane assembly includes a pair of legs extending radially outwardly from an outer shroud and a pair of mounting legs extending radially inwardly from an inner shroud. Each of the pair of legs and mounting legs have a pair of holes therein. A plurality of members attached to the gas turbine engine have a plurality of bores therein which axially align with corresponding ones of the pair of holes in the legs. A plurality of pins are positioned within the corresponding holes and bores radially positioning the nozzle guide vane assembly about a central axis of the gas turbine engine.
Turbine nozzle attachment system
Norton, P.F.; Shaffer, J.E.
1995-10-24
A nozzle guide vane assembly having a preestablished rate of thermal expansion is positioned in a gas turbine engine and is attached to conventional metallic components. The nozzle guide vane assembly includes a pair of legs extending radially outwardly from an outer shroud and a pair of mounting legs extending radially inwardly from an inner shroud. Each of the pair of legs and mounting legs have a pair of holes therein. A plurality of members attached to the gas turbine engine have a plurality of bores therein which axially align with corresponding ones of the pair of holes in the legs. A plurality of pins are positioned within the corresponding holes and bores radially positioning the nozzle guide vane assembly about a central axis of the gas turbine engine. 3 figs.
Electron cyclotron resonance ion sources in use for heavy ion cancer therapy.
Tinschert, K; Iannucci, R; Lang, R
2008-02-01
The use of electron cyclotron resonance (ECR) ion sources for producing ion beams for heavy ion cancer therapy has been established for more than ten years. After the Heavy Ion Medical Accelerator (HIMAC) at Chiba, Japan started therapy of patients with carbon ions in 1994 the first carbon ion beam for patient treatment at the accelerator facility of GSI was delivered in 1997. ECR ion sources are the perfect tool for providing the required ion beams with good stability, high reliability, and easy maintenance after long operating periods. Various investigations were performed at GSI with different combinations of working gas and auxiliary gas to define the optimal beam conditions for an extended use of further ion species for the dedicated Heidelberg Ion Beam Therapy (HIT) facility installed at the Radiological University Hospital Heidelberg, Germany. Commercially available compact all permanent magnet ECR ion sources operated at 14.5 GHz were chosen for this facility. Besides for (12)C(4+) these ion sources are used to provide beams of (1)H(3)(1+), (3)He(1+), and (16)O(6+). The final commissioning at the HIT facility could be finished at the end of 2006.
Results of a 2000 Hour Wear Tof the NEXIS Ion Engine
NASA Technical Reports Server (NTRS)
Snyder, John Steven; Goebel, Dan M.; Polk, James E.; Schneider, Analyn C; Sengupta, Anita
2005-01-01
The Nuclear Electric Xenon Ion System (NEXIS) ion thruster was developed for potential outer planet robotic missions under NASA's Prometheus program. This engine was designed to operate at power levels ranging from 16 to over 20 kWe at specific impulses of 6000 to 7500 s for burn times of up to 10 years, satisfying the requirements of nuclear electric propulsion systems such as that on the proposed Prometheus 1 mission to explore the icy moons of Jupiter. State-of-the-art performance and life assessment tools were used to design the thruster. Following the successful performance validation of a Laboratory Model thruster, Development Model hardware was fabricated and subjected to vibration and wear testing. The results of a 2000-hour wear test are reported herein. Thruster performance achieved the target requirements and was steady for the duration of the test. Ion optics performance was similarly stable. Discharge loss increases of 6 eV/ion were observed in the first 500 hours of the test and were attributed to primary electron energy decreases due to cathode insert conditioning. Relatively high recycle rates were observed and were identified to be high-voltage-to-ground arcs in the back of the thruster caused by wire insulation outgassing and electron penetration through the plasma screen. Field emission of electrons between the accelerator and screen grids was observed and attributed to evolution of field emitter sites at accelerator grid aperture edges caused by ion bombardment. Preliminary modeling and analysis indicates that the NEXIS engine can meet mission performance requirements over the required lifetime. Finally, successful validation of the NEXIS design methodology, design tools, and technologies with the results of the wear test and companion performance and vibration tests presents significant applicability of the NEXIS development effort to missions of near-term as well as long-term interest for NASA.
Results of a 2000 hour wear test of the NEXIS ion engine
NASA Technical Reports Server (NTRS)
Snyder, John Steven; Goebel, Dan M.; Polk, James E.; Schneider, Analyn C; Sengupta, Anita
2005-01-01
The Nuclear Electric Xenon Ion System (NEXIS) ion thruster was developed for potential outer planet robotic missions under NASA's Prometheus program. This engine was designed to operate at power levels ranging from 16 to over 20 kWe at specific impulses of 6000 to 7500 s for burn times of up to 10 years, satisfying the requirements of nuclear electric propulsion systems such as that on the proposed Prometheus 1 mission to explore the icy moons of Jupiter. State-of-the-art performance and life assessment tools were used to design the thruster. Following the successful performance validation of a Laboratory Model thruster, Development Model hardware was fabricated and subjected to vibration and wear testing. The results of a 2000-hour wear test are reported herein. Thruster performance achieved the target requirements and was steady for the duration of the test. Ion optics performance was similarly stable. Discharge loss increases of 6 eV/ion were observed in the first 500 hours of the test and were attributed to primary electron energy decreases due to cathode insert conditioning. Relatively high recycle rates were observed and were identified to be high-voltage-to-ground arcs in the back of the thruster caused by wire insulation outgassing and electron penetration through the plasma screen. Field emission of electrons between the accelerator and screen grids was observed and attributed to evolution of field emitter sites at accelerator grid aperture edges caused by ion bombardment. Preliminary modeling and analysis indicates that the NEXIS engine can meet mission performance requirements over the required lifetime. Finally, successful validation of the NEXIS design methodology, design tools, and technologies with the results of the wear test and companion performance and vibration tests presents significant applicability of the NEXIS development effort to missions of near-term as well as long-term interest for NASA.
2015-01-01
Tojo T, Sakurai Y. Synthesis and lithium - ion conductivity for perovskite-type Li3/8Sr7/16Ta3/4Zr1/4O3 solid electrolyte by powder-bed sintering...battery performance is limited by the electrolytic membrane, which needs high Li-ionic conductivity. Lithium lanthanum titanate (Li3xLa(2/3)-xTiO3, or...of the A-site ions and lithium ion conductivity in the perovskite solid solution La0.67-xLi3xTiO3 (x=0.11). Journal of Solid State Ionics. 1999;121
Diagnostic evaluations of a beam-shielded 8-cm mercury ion thruster
NASA Technical Reports Server (NTRS)
Nakanishi, S.
1978-01-01
An engineering model thruster fitted with a remotely actuated graphite fiber polyimide composite beam shield was tested in a 3- by 6.5-meter vacuum facility for in-situ assessment of beam shield effects on thruster performance. Accelerator drain current neutralizer floating potential and ion beam floating potential increased slightly when the shield was moved into position. A target exposed to the low density regions of the ion beam was used to map the boundaries of energetic fringe ions capable of sputtering. The particle efflux was evaluated by measurement of film deposits on cold, heated, bare, and enclosed glass slides.
Space civil engineering - A new discipline
NASA Technical Reports Server (NTRS)
Sadeh, Willy Z.; Criswell, Marvin E.
1991-01-01
Space Civil Engineering is an emerging engineering discipline that focuses on extending and expanding the Civil Engineering know-how and practice to the development and maintenance of infrastructure on celestial bodies. Space Civil Engineering is presently being developed as a new discipline within the Department of Civil Engineering at Colorado State University under a recently established NASA Space Grant College Program. Academic programs geared toward creating Space Civil Engineering Options at both undergraduate and graduate levels are being formulated. Basic ideas and concepts of the curriculum in the Space Civil Engineering Option at both undergraduate and graduate levels are presented. The role of Space Civil Engineering in the Space Program is discussed.
NASA Astrophysics Data System (ADS)
Indi Sriprisan, Sirikul; Townsend, Lawrence; Cucinotta, Francis A.; Miller, Thomas M.
Purpose: An analytical knockout-ablation-coalescence model capable of making quantitative predictions of the neutron spectra from high-energy nucleon-nucleus and nucleus-nucleus collisions is being developed for use in space radiation protection studies. The FORTRAN computer code that implements this model is called UBERNSPEC. The knockout or abrasion stage of the model is based on Glauber multiple scattering theory. The ablation part of the model uses the classical evaporation model of Weisskopf-Ewing. In earlier work, the knockout-ablation model has been extended to incorporate important coalescence effects into the formalism. Recently, alpha coalescence has been incorporated, and the ability to predict light ion spectra with the coalescence model added. The earlier versions were limited to nuclei with mass numbers less than 69. In this work, the UBERNSPEC code has been extended to make predictions of secondary neutrons and light ion production from the interactions of heavy charged particles with higher mass numbers (as large as 238). The predictions are compared with published measurements of neutron spectra and light ion energy for a variety of collision pairs. Furthermore, the predicted spectra from this work are compared with the predictions from the recently-developed heavy ion event generator incorporated in the Monte Carlo radiation transport code HETC-HEDS.
Irradiation-induced defect formation and damage accumulation in single crystal CeO 2
Graham, Joseph T.; Zhang, Yanwen; Weber, William J.
2017-11-15
Here, the accumulation of irradiation-induced disorder in single crystal CeO 2 has been investigated over a wide range of ion fluences. Room temperature irradiations of epitaxial CeO 2 thin films using 2 MeV Au 2+ ions were carried out up to a total fluence of 1.3 x 10 16 cm –2 Post-irradiation disorder was characterized using ion channeling Rutherford backscattering spectrometry (RBS/C) and confocal Raman spectroscopy. The Raman measurements were interpreted by means of a phonon confinement model, which employed rigid ion calculations to determine the phonon correlation length in the irradiated material. Comparison between the dose dependent changes inmore » correlation length of the Raman measurements and the Ce disorder fraction from RBS/C provides complementary quantitative details on the rate of point and extended defect formation on the Ce and O sub-lattices over a broad range of ion fluences. Raman measurements, which are significantly more sensitive than RBS/C at low doses, reveal that the nucleation rate of defects is highest below 0.1 displacements per atom (dpa). Comparison between Raman and RBS/C measurements suggests that between 0.1 and 10 dpa the damage evolution is characterized by modest growth of point defects and/or small clusters, while above 10 dpa the preexisting defects rapidly grow into extended clusters and/or loops.« less
Irradiation-induced defect formation and damage accumulation in single crystal CeO2
NASA Astrophysics Data System (ADS)
Graham, Joseph T.; Zhang, Yanwen; Weber, William J.
2018-01-01
The accumulation of irradiation-induced disorder in single crystal CeO2 has been investigated over a wide range of ion fluences. Room temperature irradiations of epitaxial CeO2 thin films using 2 MeV Au2+ ions were carried out up to a total fluence of 1.3 ×1016 cm-2 Post-irradiation disorder was characterized using ion channeling Rutherford backscattering spectrometry (RBS/C) and confocal Raman spectroscopy. The Raman measurements were interpreted by means of a phonon confinement model, which employed rigid ion calculations to determine the phonon correlation length in the irradiated material. Comparison between the dose dependent changes in correlation length of the Raman measurements and the Ce disorder fraction from RBS/C provides complementary quantitative details on the rate of point and extended defect formation on the Ce and O sub-lattices over a broad range of ion fluences. Raman measurements, which are significantly more sensitive than RBS/C at low doses, reveal that the nucleation rate of defects is highest below 0.1 displacements per atom (dpa). Comparison between Raman and RBS/C measurements suggests that between 0.1 and 10 dpa the damage evolution is characterized by modest growth of point defects and/or small clusters, while above 10 dpa the preexisting defects rapidly grow into extended clusters and/or loops.
Irradiation-induced defect formation and damage accumulation in single crystal CeO 2
DOE Office of Scientific and Technical Information (OSTI.GOV)
Graham, Joseph T.; Zhang, Yanwen; Weber, William J.
Here, the accumulation of irradiation-induced disorder in single crystal CeO 2 has been investigated over a wide range of ion fluences. Room temperature irradiations of epitaxial CeO 2 thin films using 2 MeV Au 2+ ions were carried out up to a total fluence of 1.3 x 10 16 cm –2 Post-irradiation disorder was characterized using ion channeling Rutherford backscattering spectrometry (RBS/C) and confocal Raman spectroscopy. The Raman measurements were interpreted by means of a phonon confinement model, which employed rigid ion calculations to determine the phonon correlation length in the irradiated material. Comparison between the dose dependent changes inmore » correlation length of the Raman measurements and the Ce disorder fraction from RBS/C provides complementary quantitative details on the rate of point and extended defect formation on the Ce and O sub-lattices over a broad range of ion fluences. Raman measurements, which are significantly more sensitive than RBS/C at low doses, reveal that the nucleation rate of defects is highest below 0.1 displacements per atom (dpa). Comparison between Raman and RBS/C measurements suggests that between 0.1 and 10 dpa the damage evolution is characterized by modest growth of point defects and/or small clusters, while above 10 dpa the preexisting defects rapidly grow into extended clusters and/or loops.« less
Modelling ion cyclotron emission from KSTAR tokamak and LHD helical device plasmas
NASA Astrophysics Data System (ADS)
Dendy, Richard; Chapman, Ben; Reman, Bernard; Chapman, Sandra; Akiyama, Tsuyoshi; Yun, Gunsu
2017-10-01
New high quality measurements of ion cyclotron emission (ICE) from KSTAR and LHD greatly extend the scope and diversity of plasma conditions under which ICE is observed. Variables include the origin (fusion reactions or neutral beam injection) and energy (sub- or super-Alfvénic) of the minority energetic ions that drive ICE; the composition of the bulk plasma (hydrogen or deuterium) which supports the modes excited; plasma density in the emitting region, and the timescale on which it changes; and toroidal magnetic field geometry (tokamak or helical device). Future exploitation of ICE as a diagnostic for energetic ion populations in JET D-T plasmas and in ITER rests on quantitative understanding of the physics of the emission. This is tested and extended by current KSTAR and LHD measurements of ICE. We report progress on direct numerical simulation using full orbit ion kinetic codes that solve the Maxwell-Lorentz equations for hundreds of millions of particles. In the saturated regime, these simulations yield excited field spectra that correspond directly to the measured ICE spectra under diverse KSTAR and LHD regimes. At early times, comparison of simulation outputs with linear analytical theory confirms the magnetoacoustic cyclotron instability as the basic driver of ICE. Supported by RCUK Energy Programme Grant EP/P012450/1, NRF Korea Grant 2014M1A7A1A03029881, NIFS budget ULHH029 and Euratom.
Extended Gate Field-Effect Transistor Biosensors for Point-Of-Care Testing of Uric Acid.
Guan, Weihua; Reed, Mark A
2017-01-01
An enzyme-free redox potential sensor using off-chip extended-gate field effect transistor (EGFET) with a ferrocenyl-alkanethiol modified gold electrode has been used to quantify uric acid concentration in human serum and urine. Hexacyanoferrate (II) and (III) ions are used as redox reagent. The potentiometric sensor measures the interface potential on the ferrocene immobilized gold electrode, which is modulated by the redox reaction between uric acid and hexacyanoferrate ions. The device shows a near Nernstian response to uric acid and is highly specific to uric acid in human serum and urine. The interference that comes from glucose, bilirubin, ascorbic acid, and hemoglobin is negligible in the normal concentration range of these interferents. The sensor also exhibits excellent long term reliability and is regenerative. This extended gate field effect transistor based sensor is promising for point-of-care detection of uric acid due to the small size, low cost, and low sample volume consumption.
Smart membranes for nitrate removal, water purification, and selective ion transportation
Wilson, William D [Pleasanton, CA; Schaldach, Charlene M [Pleasanton, CA; Bourcier, William L [Livermore, CA; Paul, Phillip H [Livermore, CA
2009-12-15
A computer designed nanoengineered membrane for separation of dissolved species. One embodiment provides an apparatus for treatment of a fluid that includes ions comprising a microengineered porous membrane, a system for producing an electrical charge across the membrane, and a series of nanopores extending through the membrane. The nanopores have a pore size such that when the fluid contacts the membrane, the nanopores will be in a condition of double layer overlap and allow passage only of ions opposite to the electrical charge across the membrane.
Progress Report on the Improved Linear Ion Trap Physics Package
NASA Technical Reports Server (NTRS)
Prestage, John D.
1995-01-01
This article describes the first operational results from the extended linear ion trap frequency standard now being developed at JPL. This new design separates the state selection/interrogation region from the more critical microwave resonance region where the multiplied local oscillator (LO) signal is compared to the stable atomic transition. Hg+ ions have been trapped, shuttled back and forth between the resonance and state selection traps. In addition, microwave transitions between the Hg+ clock levels have been driven in the resonance trap and detected in the state selection trap.
Fast ion swapping for quantum-information processing
NASA Astrophysics Data System (ADS)
Kaufmann, H.; Ruster, T.; Schmiegelow, C. T.; Luda, M. A.; Kaushal, V.; Schulz, J.; von Lindenfels, D.; Schmidt-Kaler, F.; Poschinger, U. G.
2017-05-01
We demonstrate a swap gate between laser-cooled ions in a segmented microtrap via fast physical swapping of the ion positions. This operation is used in conjunction with qubit initialization, manipulation, and readout and with other types of shuttling operations such as linear transport and crystal separation and merging. Combining these operations, we perform quantum process tomography of the swap gate, obtaining a mean process fidelity of 99.5(5)%. The swap operation is demonstrated with motional excitations below 0.05(1) quantum for all six collective modes of a two-ion crystal for a process duration of 42 μ s . Extending these techniques to three ions, we reverse the order of a three-ion crystal and reconstruct the truth table for this operation, resulting in a mean process fidelity of 99.96(13)% in the logical basis.
Electrostatic shock structures in dissipative multi-ion dusty plasmas
NASA Astrophysics Data System (ADS)
Elkamash, I. S.; Kourakis, I.
2018-06-01
A comprehensive analytical model is introduced for shock excitations in dusty bi-ion plasma mixtures, taking into account collisionality and kinematic (fluid) viscosity. A multicomponent plasma configuration is considered, consisting of positive ions, negative ions, electrons, and a massive charged component in the background (dust). The ionic dynamical scale is focused upon; thus, electrons are assumed to be thermalized, while the dust is stationary. A dissipative hybrid Korteweg-de Vries/Burgers equation is derived. An analytical solution is obtained, in the form of a shock structure (a step-shaped function for the electrostatic potential, or an electric field pulse) whose maximum amplitude in the far downstream region decays in time. The effect of relevant plasma configuration parameters, in addition to dissipation, is investigated. Our work extends earlier studies of ion-acoustic type shock waves in pure (two-component) bi-ion plasma mixtures.
14 CFR Appendix K to Part 25 - Extended Operations (ETOPS)
Code of Federal Regulations, 2014 CFR
2014-01-01
... that is time-limited. K25.1.4Propulsion systems. (a) Fuel system design. Fuel necessary to complete an... does not apply to airplanes with a required flight engineer. (b) APU design. If an APU is needed to..., whichever is lower, and run for the remainder of any flight . (c) Engine oil tank design. The engine oil...
14 CFR Appendix K to Part 25 - Extended Operations (ETOPS)
Code of Federal Regulations, 2010 CFR
2010-01-01
... that is time-limited. K25.1.4Propulsion systems. (a) Fuel system design. Fuel necessary to complete an... does not apply to airplanes with a required flight engineer. (b) APU design. If an APU is needed to..., whichever is lower, and run for the remainder of any flight . (c) Engine oil tank design. The engine oil...
14 CFR Appendix K to Part 25 - Extended Operations (ETOPS)
Code of Federal Regulations, 2013 CFR
2013-01-01
... that is time-limited. K25.1.4Propulsion systems. (a) Fuel system design. Fuel necessary to complete an... does not apply to airplanes with a required flight engineer. (b) APU design. If an APU is needed to..., whichever is lower, and run for the remainder of any flight . (c) Engine oil tank design. The engine oil...
14 CFR Appendix K to Part 25 - Extended Operations (ETOPS)
Code of Federal Regulations, 2012 CFR
2012-01-01
... that is time-limited. K25.1.4Propulsion systems. (a) Fuel system design. Fuel necessary to complete an... does not apply to airplanes with a required flight engineer. (b) APU design. If an APU is needed to..., whichever is lower, and run for the remainder of any flight . (c) Engine oil tank design. The engine oil...
Zhao, Yunshan; Liu, Dan; Chen, Jie; Zhu, Liyan; Belianinov, Alex; Ovchinnikova, Olga S; Unocic, Raymond R; Burch, Matthew J; Kim, Songkil; Hao, Hanfang; Pickard, Daniel S; Li, Baowen; Thong, John T L
2017-06-27
The ability to engineer the thermal conductivity of materials allows us to control the flow of heat and derive novel functionalities such as thermal rectification, thermal switching and thermal cloaking. While this could be achieved by making use of composites and metamaterials at bulk length-scales, engineering the thermal conductivity at micro- and nano-scale dimensions is considerably more challenging. In this work, we show that the local thermal conductivity along a single Si nanowire can be tuned to a desired value (between crystalline and amorphous limits) with high spatial resolution through selective helium ion irradiation with a well-controlled dose. The underlying mechanism is understood through molecular dynamics simulations and quantitative phonon-defect scattering rate analysis, where the behaviour of thermal conductivity with dose is attributed to the accumulation and agglomeration of scattering centres at lower doses. Beyond a threshold dose, a crystalline-amorphous transition was observed.
Pyroelectric Crystal Accelerator In The Department Of Physics And Nuclear Engineering At West Point
DOE Office of Scientific and Technical Information (OSTI.GOV)
Gillich, Don; Kovanen, Andrew; Anderson, Tom
The Nuclear Science and Engineering Research Center (NSERC), a Defense Threat Reduction Agency (DTRA) office located at the United States Military Academy (USMA), sponsors and manages cadet and faculty research in support of DTRA objectives. The NSERC has created an experimental pyroelectric crystal accelerator program to enhance undergraduate education at USMA in the Department of Physics and Nuclear Engineering. This program provides cadets with hands-on experience in designing their own experiments using an inexpensive tabletop accelerator. This device uses pyroelectric crystals to ionize and accelerate gas ions to energies of {approx}100 keV. Within the next year, cadets and faculty atmore » USMA will use this device to create neutrons through the deuterium-deuterium (D-D) fusion process, effectively creating a compact, portable neutron generator. The double crystal pyroelectric accelerator will also be used by students to investigate neutron, x-ray, and ion spectroscopy.« less
Zhao, Yunshan; Liu, Dan; Chen, Jie; Zhu, Liyan; Belianinov, Alex; Ovchinnikova, Olga S.; Unocic, Raymond R.; Burch, Matthew J.; Kim, Songkil; Hao, Hanfang; Pickard, Daniel S.; Li, Baowen; Thong, John T. L.
2017-01-01
The ability to engineer the thermal conductivity of materials allows us to control the flow of heat and derive novel functionalities such as thermal rectification, thermal switching and thermal cloaking. While this could be achieved by making use of composites and metamaterials at bulk length-scales, engineering the thermal conductivity at micro- and nano-scale dimensions is considerably more challenging. In this work, we show that the local thermal conductivity along a single Si nanowire can be tuned to a desired value (between crystalline and amorphous limits) with high spatial resolution through selective helium ion irradiation with a well-controlled dose. The underlying mechanism is understood through molecular dynamics simulations and quantitative phonon-defect scattering rate analysis, where the behaviour of thermal conductivity with dose is attributed to the accumulation and agglomeration of scattering centres at lower doses. Beyond a threshold dose, a crystalline-amorphous transition was observed. PMID:28653663
Zhao, Yunshan; Liu, Dan; Chen, Jie; ...
2017-06-27
The ability to engineer the thermal conductivity of materials allows us to control the flow of heat and derive novel functionalities such as thermal rectification, thermal switching and thermal cloaking. While this could be achieved by making use of composites and metamaterials at bulk length-scales, engineering the thermal conductivity at micro- and nano-scale dimensions is considerably more challenging. Here, we show that the local thermal conductivity along a single Si nanowire can be tuned to a desired value (between crystalline and amorphous limits) with high spatial resolution through selective helium ion irradiation with a well-controlled dose. The underlying mechanism ismore » understood through molecular dynamics simulations and quantitative phonon-defect scattering rate analysis, where the behaviour of thermal conductivity with dose is attributed to the accumulation and agglomeration of scattering centres at lower doses. Finally, we observed threshold dose beyond a crystalline-amorphous transition.« less
DOE Office of Scientific and Technical Information (OSTI.GOV)
Zhao, Yunshan; Liu, Dan; Chen, Jie
The ability to engineer the thermal conductivity of materials allows us to control the flow of heat and derive novel functionalities such as thermal rectification, thermal switching and thermal cloaking. While this could be achieved by making use of composites and metamaterials at bulk length-scales, engineering the thermal conductivity at micro- and nano-scale dimensions is considerably more challenging. Here, we show that the local thermal conductivity along a single Si nanowire can be tuned to a desired value (between crystalline and amorphous limits) with high spatial resolution through selective helium ion irradiation with a well-controlled dose. The underlying mechanism ismore » understood through molecular dynamics simulations and quantitative phonon-defect scattering rate analysis, where the behaviour of thermal conductivity with dose is attributed to the accumulation and agglomeration of scattering centres at lower doses. Finally, we observed threshold dose beyond a crystalline-amorphous transition.« less
Performance Measurements and Technology Demonstration of the VASIMR® VX-200
NASA Astrophysics Data System (ADS)
Longmier, B. W.; Bering, E. A.; Squire, J. P.; Glover, T. W.; Cassady, L. D.; Ilin, A. V.; Carter, M. D.; Olsen, C. S.; McCaskill, G. E.; Chang Díaz, F.
2010-12-01
Recent progress is discussed in the development of an advanced RF electric propulsion engine: the VAriable Specific Impulse Magnetoplasma Rocket (VASIMR®) VX-200, a 200 kW flight-technology prototype. This device is the only known industrial application of the physics of the aurora borealis. Results are presented from first stage only and first stage with booster stage experiments that were performed on the VX-200 using between 60 mg/s and 150 mg/s argon propellant. The plasma source is a helicon discharge that uses whistler mode waves near the lower hybrid frequency. The booster stage uses electromagnetic ion cyclotron wave absorption to accelerate the ions. Measurements of ion flux, ion energy, plasma density and potential gradients, and force density profiles taken in the exhaust plume of the VX-200 are made within a 150 cubic meter vacuum chamber and are presented in the context of individual stage and total engine performance. Measurements include detailed pitch angle scans of the accelerated ions and plasma parameter maps of the exhaust plume. An emphasis will be given to our ability to probe wave-particle interactions in the exhaust plume. We are now in a position to conduct more detailed auroral simulation studies and are actively seeking collaborators.
Plasma-assisted physical vapor deposition surface treatments for tribological control
NASA Technical Reports Server (NTRS)
Spalvins, Talivaldis
1990-01-01
In any mechanical or engineering system where contacting surfaces are in relative motion, adhesion, wear, and friction affect reliability and performance. With the advancement of space age transportation systems, the tribological requirements have dramatically increased. This is due to the optimized design, precision tolerance requirements, and high reliability expected for solid lubricating films in order to withstand hostile operating conditions (vacuum, high-low temperatures, high loads, and space radiation). For these problem areas the ion-assisted deposition/modification processes (plasma-based and ion beam techniques) offer the greatest potential for the synthesis of thin films and the tailoring of adherence and chemical and structural properties for optimized tribological performance. The present practices and new approaches of applying soft solid lubricant and hard wear resistant films to engineering substrates are reviewed. The ion bombardment treatments have increased film adherence, lowered friction coefficients, and enhanced wear life of the solid lubricating films such as the dichalcogenides (MoS2) and the soft metals (Au, Ag, Pb). Currently, sputtering is the preferred method of applying MoS2 films; and ion plating, the soft metallic films. Ultralow friction coefficients (less than 0.01) were achieved with sputtered MoS2. Further, new diamond-like carbon and BN lubricating films are being developed by using the ion assisted deposition techniques.
NASA Astrophysics Data System (ADS)
Park, Jang-Hoon; Kim, Ju-Myung; Lee, Chang Kee; Lee, Sang-Young
2014-10-01
Understanding and control of interfacial phenomena between electrode material and liquid electrolytes are of major scientific importance for boosting development of high-performance lithium ion batteries with reliable electrochemical/safety attributes. Here, as an innovative surface engineering approach to address the interfacial issues, a new concept of mixed ion/electron-conductive soft nanomatter-based conformal surface modification of the cathode material is presented. The soft nanomatter is comprised of an electron conductive carbonaceous (C) substance embedded in an ion conductive polyimide (PI) nanothin compliant film. In addition to its structural uniqueness, the newly proposed surface modification benefits from a simple fabrication process. The PI/carbon soft nanomatter is directly synthesized on LiCoO2 surface via one-pot thermal treatment of polyamic acid (=PI precursor) and sucrose (=carbon source) mixture, where the LiCoO2 powders are chosen as a model system to explore the feasibility of this surface engineering strategy. The resulting PI/carbon coating layer facilitates electronic conduction and also suppresses unwanted side reactions arising from the cathode material-liquid electrolyte interface. These synergistic coating effects of the multifunctional PI/carbon soft nanomatter significantly improve high-voltage cell performance and also mitigate interfacial exothermic reaction between cathode material and liquid electrolyte.
Structural characterization of UHPC waffle bridge deck and connections.
DOT National Transportation Integrated Search
2014-07-01
The AASHTO strategic plan in 2005 for bridge engineering identified extending the service life of bridges and accelerating bridge : construction as two of the grand challenges in bridge engineering. These challenges have the objective of producing sa...
Orbital Transfer Vehicle (OTV) engine study. Phase A: Extension
NASA Technical Reports Server (NTRS)
Sobin, A. J.
1980-01-01
The current Phase A-Extension of the OTV engine study program aims to provide additional expander and staged combustion cycle data that will lead to design definition of the OTV engine. The proposed program effort seeks to optimize the expander cycle engine concept (consistent with identified OTV engine requirements), investigate the feasibility of kitting the staged combustion cycle engine to provide extended thrust operation, and conduct in-depth analysis of development risk, crew safety, and reliability for both cycles. Additional tasks address the costing of a 10/K thrust expander cycle engine and support of OTV systems study contractors.
NASA Astrophysics Data System (ADS)
Sun, Yong; Ma, Zilin; Tang, Gongyou; Chen, Zheng; Zhang, Nong
2016-07-01
Since the main power source of hybrid electric vehicle(HEV) is supplied by the power battery, the predicted performance of power battery, especially the state-of-charge(SOC) estimation has attracted great attention in the area of HEV. However, the value of SOC estimation could not be greatly precise so that the running performance of HEV is greatly affected. A variable structure extended kalman filter(VSEKF)-based estimation method, which could be used to analyze the SOC of lithium-ion battery in the fixed driving condition, is presented. First, the general lower-order battery equivalent circuit model(GLM), which includes column accumulation model, open circuit voltage model and the SOC output model, is established, and the off-line and online model parameters are calculated with hybrid pulse power characteristics(HPPC) test data. Next, a VSEKF estimation method of SOC, which integrates the ampere-hour(Ah) integration method and the extended Kalman filter(EKF) method, is executed with different adaptive weighting coefficients, which are determined according to the different values of open-circuit voltage obtained in the corresponding charging or discharging processes. According to the experimental analysis, the faster convergence speed and more accurate simulating results could be obtained using the VSEKF method in the running performance of HEV. The error rate of SOC estimation with the VSEKF method is focused in the range of 5% to 10% comparing with the range of 20% to 30% using the EKF method and the Ah integration method. In Summary, the accuracy of the SOC estimation in the lithium-ion battery cell and the pack of lithium-ion battery system, which is obtained utilizing the VSEKF method has been significantly improved comparing with the Ah integration method and the EKF method. The VSEKF method utilizing in the SOC estimation in the lithium-ion pack of HEV can be widely used in practical driving conditions.
Chang, Chenchen; Huang, Rong; Yan, Yan; Ma, Hongmin; Dai, Zheng; Zhang, Benying; Deng, Zixin; Liu, Wen; Qu, Xudong
2015-04-01
Selective modification of carbon scaffolds via biosynthetic engineering is important for polyketide structural diversification. Yet, this scope is currently restricted to simple aliphatic groups due to (1) limited variety of CoA-linked extender units, which lack aromatic structures and chemical reactivity, and (2) narrow acyltransferase (AT) specificity, which is limited to aliphatic CoA-linked extender units. In this report, we uncovered and characterized the first aromatic CoA-linked extender unit benzylmalonyl-CoA from the biosynthetic pathways of splenocin and enterocin in Streptomyces sp. CNQ431. Its synthesis employs a deamination/reductive carboxylation strategy to convert phenylalanine into benzylmalonyl-CoA, providing a link between amino acid and CoA-linked extender unit synthesis. By characterization of its selection, we further validated that AT domains of splenocin, and antimycin polyketide synthases are able to select this extender unit to introduce the phenyl group into their dilactone scaffolds. The biosynthetic machinery involved in the formation of this extender unit is highly versatile and can be potentially tailored for tyrosine, histidine and aspartic acid. The disclosed aromatic extender unit, amino acid-oriented synthetic pathway, and aromatic-selective AT domains provides a systematic breakthrough toward current knowledge of polyketide extender unit formation and selection, and also opens a route for further engineering of polyketide carbon scaffolds using amino acids.